id	sid	tid	token	lemma	pos
eurjchem-385	1	1	untitled	untitle	VERB
eurjchem-385	1	2	european	european	PROPN
eurjchem-385	1	3	journal	journal	PROPN
eurjchem-385	1	4	of	of	ADP
eurjchem-385	1	5	chemistry	chemistry	NOUN
eurjchem-385	1	6	2	2	NUM
eurjchem-385	1	7	(	(	PUNCT
eurjchem-385	1	8	3	3	NUM
eurjchem-385	1	9	)	)	PUNCT
eurjchem-385	1	10	(	(	PUNCT
eurjchem-385	1	11	2011	2011	NUM
eurjchem-385	1	12	)	)	PUNCT
eurjchem-385	1	13	342‐346	342‐346	NUM
eurjchem-385	1	14	european	european	ADJ
eurjchem-385	1	15	journal	journal	PROPN
eurjchem-385	1	16	of	of	ADP
eurjchem-385	1	17	chemistry	chemistry	NOUN
eurjchem-385	1	18	issn	issn	PROPN
eurjchem-385	1	19	2153‐2249	2153‐2249	PROPN
eurjchem-385	1	20	(	(	PUNCT
eurjchem-385	1	21	print	print	NOUN
eurjchem-385	1	22	)	)	PUNCT
eurjchem-385	1	23	/	/	SYM
eurjchem-385	1	24	issn	issn	PROPN
eurjchem-385	1	25	2153‐2257	2153‐2257	NUM
eurjchem-385	1	26	(	(	PUNCT
eurjchem-385	1	27	online	online	ADJ
eurjchem-385	1	28	)	)	PUNCT
eurjchem-385	1	29			NOUN
eurjchem-385	1	30	2011	2011	NUM
eurjchem-385	1	31	eurjchem	eurjchem	PROPN
eurjchem-385	1	32	doi:10.5155	doi:10.5155	PROPN
eurjchem-385	1	33	/	/	SYM
eurjchem-385	1	34	eurjchem.2.3.342‐346.385	eurjchem.2.3.342‐346.385	PROPN
eurjchem-385	1	35	european	european	ADJ
eurjchem-385	1	36	journal	journal	PROPN
eurjchem-385	1	37	of	of	ADP
eurjchem-385	1	38	chemistry	chemistry	PROPN
eurjchem-385	1	39	journal	journal	PROPN
eurjchem-385	1	40	homepage	homepage	NOUN
eurjchem-385	1	41	:	:	PUNCT
eurjchem-385	1	42	www.eurjchem.com	www.eurjchem.com	X
eurjchem-385	1	43	kinetics	kinetic	NOUN
eurjchem-385	1	44	and	and	CCONJ
eurjchem-385	1	45	mechanism	mechanism	NOUN
eurjchem-385	1	46	of	of	ADP
eurjchem-385	1	47	oxidation	oxidation	NOUN
eurjchem-385	1	48	of	of	ADP
eurjchem-385	1	49	n‐butylamine	n‐butylamine	PUNCT
eurjchem-385	1	50	and	and	CCONJ
eurjchem-385	1	51	1,3‐propanediamine	1,3‐propanediamine	NUM
eurjchem-385	1	52	by	by	ADP
eurjchem-385	1	53	potassium	potassium	NOUN
eurjchem-385	1	54	ferrate	ferrate	NOUN
eurjchem-385	1	55	jinhuan	jinhuan	PROPN
eurjchem-385	1	56	shan	shan	PROPN
eurjchem-385	1	57	,	,	PUNCT
eurjchem-385	1	58	yafeng	yafeng	PROPN
eurjchem-385	1	59	yang	yang	PROPN
eurjchem-385	1	60	and	and	CCONJ
eurjchem-385	1	61	jinhuan	jinhuan	PROPN
eurjchem-385	1	62	shan	shan	PROPN
eurjchem-385	1	63	*	*	PROPN
eurjchem-385	1	64	college	college	NOUN
eurjchem-385	1	65	of	of	ADP
eurjchem-385	1	66	chemistry	chemistry	NOUN
eurjchem-385	1	67	and	and	CCONJ
eurjchem-385	1	68	environmental	environmental	ADJ
eurjchem-385	1	69	science	science	NOUN
eurjchem-385	1	70	,	,	PUNCT
eurjchem-385	1	71	hebei	hebei	PROPN
eurjchem-385	1	72	university	university	PROPN
eurjchem-385	1	73	,	,	PUNCT
eurjchem-385	1	74	baoding	baoding	PROPN
eurjchem-385	1	75	,	,	PUNCT
eurjchem-385	1	76	071002	071002	NUM
eurjchem-385	1	77	,	,	PUNCT
eurjchem-385	1	78	china	china	PROPN
eurjchem-385	1	79	*	*	PUNCT
eurjchem-385	1	80	corresponding	correspond	VERB
eurjchem-385	1	81	author	author	NOUN
eurjchem-385	1	82	at	at	ADP
eurjchem-385	1	83	:	:	PUNCT
eurjchem-385	1	84	college	college	NOUN
eurjchem-385	1	85	of	of	ADP
eurjchem-385	1	86	chemistry	chemistry	NOUN
eurjchem-385	1	87	and	and	CCONJ
eurjchem-385	1	88	environmental	environmental	ADJ
eurjchem-385	1	89	science	science	NOUN
eurjchem-385	1	90	,	,	PUNCT
eurjchem-385	1	91	hebei	hebei	PROPN
eurjchem-385	1	92	university	university	PROPN
eurjchem-385	1	93	,	,	PUNCT
eurjchem-385	1	94	baoding	baoding	PROPN
eurjchem-385	1	95	,	,	PUNCT
eurjchem-385	1	96	071002	071002	NUM
eurjchem-385	1	97	,	,	PUNCT
eurjchem-385	1	98	china	china	PROPN
eurjchem-385	1	99	.	.	PUNCT
eurjchem-385	2	1	tel	tel	PROPN
eurjchem-385	2	2	.	.	PUNCT
eurjchem-385	2	3	:	:	PUNCT
eurjchem-385	3	1	+86.0312.5971129	+86.0312.5971129	ADJ
eurjchem-385	3	2	;	;	PUNCT
eurjchem-385	3	3	fax	fax	NOUN
eurjchem-385	3	4	:	:	PUNCT
eurjchem-385	3	5	+86.0312.5079525	+86.0312.5079525	NOUN
eurjchem-385	3	6	.	.	PUNCT
eurjchem-385	3	7	e‐mail	e‐mail	PUNCT
eurjchem-385	4	1	address	address	NOUN
eurjchem-385	4	2	:	:	PUNCT
eurjchem-385	4	3	shanjinhuaner@yahoo.com.cn	shanjinhuaner@yahoo.com.cn	PROPN
eurjchem-385	4	4	(	(	PUNCT
eurjchem-385	4	5	j.	j.	PROPN
eurjchem-385	4	6	shan	shan	PROPN
eurjchem-385	4	7	)	)	PUNCT
eurjchem-385	4	8	.	.	PUNCT
eurjchem-385	5	1	article	article	NOUN
eurjchem-385	5	2	information	information	PROPN
eurjchem-385	5	3	abstract	abstract	ADV
eurjchem-385	5	4	received	receive	VERB
eurjchem-385	5	5	:	:	PUNCT
eurjchem-385	5	6	06	06	NUM
eurjchem-385	5	7	january	january	PROPN
eurjchem-385	5	8	2011	2011	NUM
eurjchem-385	5	9	received	receive	VERB
eurjchem-385	5	10	in	in	ADP
eurjchem-385	5	11	revised	revise	VERB
eurjchem-385	5	12	form	form	NOUN
eurjchem-385	5	13	:	:	PUNCT
eurjchem-385	5	14	01	01	NUM
eurjchem-385	5	15	march	march	PROPN
eurjchem-385	5	16	2011	2011	NUM
eurjchem-385	5	17	accepted	accept	VERB
eurjchem-385	5	18	:	:	PUNCT
eurjchem-385	5	19	18	18	NUM
eurjchem-385	5	20	april	april	PROPN
eurjchem-385	5	21	2011	2011	NUM
eurjchem-385	5	22	online	online	NOUN
eurjchem-385	5	23	:	:	PUNCT
eurjchem-385	5	24	30	30	NUM
eurjchem-385	5	25	september	september	PROPN
eurjchem-385	5	26	2011	2011	NUM
eurjchem-385	5	27	keywords	keyword	VERB
eurjchem-385	5	28	the	the	DET
eurjchem-385	5	29	kinetics	kinetic	NOUN
eurjchem-385	5	30	of	of	ADP
eurjchem-385	5	31	oxidation	oxidation	NOUN
eurjchem-385	5	32	of	of	ADP
eurjchem-385	5	33	n‐butylamine	n‐butylamine	PUNCT
eurjchem-385	5	34	and	and	CCONJ
eurjchem-385	5	35	1,3‐propanediamine	1,3‐propanediamine	NUM
eurjchem-385	5	36	by	by	ADP
eurjchem-385	5	37	home‐made	home‐made	NOUN
eurjchem-385	5	38	potassium	potassium	NOUN
eurjchem-385	5	39	ferrate(vi	ferrate(vi	NOUN
eurjchem-385	5	40	)	)	PUNCT
eurjchem-385	5	41	at	at	ADP
eurjchem-385	5	42	different	different	ADJ
eurjchem-385	5	43	conditions	condition	NOUN
eurjchem-385	5	44	has	have	AUX
eurjchem-385	5	45	been	be	AUX
eurjchem-385	5	46	studied	study	VERB
eurjchem-385	5	47	spectrophotometrically	spectrophotometrically	ADV
eurjchem-385	5	48	in	in	ADP
eurjchem-385	5	49	the	the	DET
eurjchem-385	5	50	temperature	temperature	NOUN
eurjchem-385	5	51	range	range	NOUN
eurjchem-385	5	52	of	of	ADP
eurjchem-385	5	53	283.2‐298.2	283.2‐298.2	NUM
eurjchem-385	5	54	k.	k.	NOUN
eurjchem-385	6	1	the	the	DET
eurjchem-385	6	2	results	result	NOUN
eurjchem-385	6	3	show	show	VERB
eurjchem-385	6	4	first	first	ADJ
eurjchem-385	6	5	order	order	NOUN
eurjchem-385	6	6	dependence	dependence	NOUN
eurjchem-385	6	7	on	on	ADP
eurjchem-385	6	8	potassium	potassium	NOUN
eurjchem-385	6	9	ferrate	ferrate	NOUN
eurjchem-385	6	10	(	(	PUNCT
eurjchem-385	6	11	vi	vi	NOUN
eurjchem-385	6	12	)	)	PUNCT
eurjchem-385	6	13	and	and	CCONJ
eurjchem-385	6	14	on	on	ADP
eurjchem-385	6	15	each	each	DET
eurjchem-385	6	16	reductant	reductant	NOUN
eurjchem-385	6	17	.	.	PUNCT
eurjchem-385	7	1	the	the	DET
eurjchem-385	7	2	observed	observe	VERB
eurjchem-385	7	3	rate	rate	NOUN
eurjchem-385	7	4	constant	constant	ADJ
eurjchem-385	7	5	(	(	PUNCT
eurjchem-385	7	6	kobs	kobs	PROPN
eurjchem-385	7	7	)	)	PUNCT
eurjchem-385	7	8	decreases	decrease	NOUN
eurjchem-385	7	9	with	with	ADP
eurjchem-385	7	10	the	the	DET
eurjchem-385	7	11	increase	increase	NOUN
eurjchem-385	7	12	of	of	ADP
eurjchem-385	7	13	[	[	X
eurjchem-385	7	14	oh‐	oh‐	PROPN
eurjchem-385	7	15	]	]	PUNCT
eurjchem-385	7	16	,	,	PUNCT
eurjchem-385	7	17	and	and	CCONJ
eurjchem-385	7	18	the	the	DET
eurjchem-385	7	19	reaction	reaction	NOUN
eurjchem-385	7	20	rate	rate	NOUN
eurjchem-385	7	21	has	have	VERB
eurjchem-385	7	22	a	a	DET
eurjchem-385	7	23	negative	negative	ADJ
eurjchem-385	7	24	fraction	fraction	NOUN
eurjchem-385	7	25	order	order	NOUN
eurjchem-385	7	26	with	with	ADP
eurjchem-385	7	27	respect	respect	NOUN
eurjchem-385	7	28	to	to	ADP
eurjchem-385	7	29	[	[	X
eurjchem-385	7	30	oh‐	oh‐	ADV
eurjchem-385	7	31	]	]	PUNCT
eurjchem-385	7	32	.	.	PUNCT
eurjchem-385	8	1	a	a	DET
eurjchem-385	8	2	plausible	plausible	ADJ
eurjchem-385	8	3	mechanism	mechanism	NOUN
eurjchem-385	8	4	is	be	AUX
eurjchem-385	8	5	proposed	propose	VERB
eurjchem-385	8	6	and	and	CCONJ
eurjchem-385	8	7	the	the	DET
eurjchem-385	8	8	rate	rate	NOUN
eurjchem-385	8	9	equations	equation	NOUN
eurjchem-385	8	10	derived	derive	VERB
eurjchem-385	8	11	from	from	ADP
eurjchem-385	8	12	the	the	DET
eurjchem-385	8	13	mechanism	mechanism	NOUN
eurjchem-385	8	14	was	be	AUX
eurjchem-385	8	15	shown	show	VERB
eurjchem-385	8	16	to	to	PART
eurjchem-385	8	17	fit	fit	VERB
eurjchem-385	8	18	all	all	DET
eurjchem-385	8	19	the	the	DET
eurjchem-385	8	20	experimental	experimental	ADJ
eurjchem-385	8	21	results	result	NOUN
eurjchem-385	8	22	.	.	PUNCT
eurjchem-385	9	1	the	the	DET
eurjchem-385	9	2	rate	rate	NOUN
eurjchem-385	9	3	constants	constant	NOUN
eurjchem-385	9	4	of	of	ADP
eurjchem-385	9	5	the	the	DET
eurjchem-385	9	6	rate‐determining	rate‐determining	NOUN
eurjchem-385	9	7	step	step	NOUN
eurjchem-385	9	8	and	and	CCONJ
eurjchem-385	9	9	the	the	DET
eurjchem-385	9	10	thermodynamic	thermodynamic	ADJ
eurjchem-385	9	11	activation	activation	NOUN
eurjchem-385	9	12	parameters	parameter	NOUN
eurjchem-385	9	13	are	be	AUX
eurjchem-385	9	14	calculated	calculate	VERB
eurjchem-385	9	15	.	.	PUNCT
eurjchem-385	10	1	n‐butylamine	n‐butylamine	NUM
eurjchem-385	10	2	1,3‐propanediamine	1,3‐propanediamine	NUM
eurjchem-385	10	3	potassium	potassium	NOUN
eurjchem-385	10	4	ferrate	ferrate	NOUN
eurjchem-385	10	5	kinetics	kinetic	NOUN
eurjchem-385	10	6	and	and	CCONJ
eurjchem-385	10	7	mechanism	mechanism	NOUN
eurjchem-385	10	8	oxidation	oxidation	NOUN
eurjchem-385	10	9	environmental	environmental	ADJ
eurjchem-385	10	10	protection	protection	NOUN
eurjchem-385	10	11	1	1	NUM
eurjchem-385	10	12	.	.	PUNCT
eurjchem-385	10	13	introduction	introduction	NOUN
eurjchem-385	10	14	potassium	potassium	NOUN
eurjchem-385	10	15	ferrate	ferrate	NOUN
eurjchem-385	10	16	,	,	PUNCT
eurjchem-385	10	17	which	which	PRON
eurjchem-385	10	18	is	be	AUX
eurjchem-385	10	19	an	an	DET
eurjchem-385	10	20	effective	effective	ADJ
eurjchem-385	10	21	and	and	CCONJ
eurjchem-385	10	22	multi‐	multi‐	PROPN
eurjchem-385	10	23	functional	functional	ADJ
eurjchem-385	10	24	water	water	NOUN
eurjchem-385	10	25	treatment	treatment	NOUN
eurjchem-385	10	26	agent	agent	NOUN
eurjchem-385	10	27	,	,	PUNCT
eurjchem-385	10	28	has	have	VERB
eurjchem-385	10	29	strong	strong	ADJ
eurjchem-385	10	30	oxidation	oxidation	NOUN
eurjchem-385	10	31	capacity	capacity	NOUN
eurjchem-385	10	32	in	in	ADP
eurjchem-385	10	33	aqueous	aqueous	ADJ
eurjchem-385	10	34	solutions	solution	NOUN
eurjchem-385	10	35	[	[	X
eurjchem-385	10	36	1‐4	1‐4	X
eurjchem-385	10	37	]	]	PUNCT
eurjchem-385	10	38	because	because	SCONJ
eurjchem-385	10	39	of	of	ADP
eurjchem-385	10	40	the	the	DET
eurjchem-385	10	41	unusually	unusually	ADV
eurjchem-385	10	42	high	high	ADJ
eurjchem-385	10	43	oxidation	oxidation	NOUN
eurjchem-385	10	44	state	state	NOUN
eurjchem-385	10	45	of	of	ADP
eurjchem-385	10	46	iron	iron	NOUN
eurjchem-385	10	47	.	.	PUNCT
eurjchem-385	11	1	its	its	PRON
eurjchem-385	11	2	reduction	reduction	NOUN
eurjchem-385	11	3	product	product	NOUN
eurjchem-385	11	4	fe(iii	fe(iii	NOUN
eurjchem-385	11	5	)	)	PUNCT
eurjchem-385	11	6	is	be	AUX
eurjchem-385	11	7	not	not	PART
eurjchem-385	11	8	toxic	toxic	ADJ
eurjchem-385	11	9	.	.	PUNCT
eurjchem-385	12	1	it	it	PRON
eurjchem-385	12	2	integrates	integrate	VERB
eurjchem-385	12	3	the	the	DET
eurjchem-385	12	4	properties	property	NOUN
eurjchem-385	12	5	,	,	PUNCT
eurjchem-385	12	6	such	such	ADJ
eurjchem-385	12	7	as	as	ADP
eurjchem-385	12	8	oxidizing	oxidize	VERB
eurjchem-385	12	9	sterilization	sterilization	NOUN
eurjchem-385	12	10	,	,	PUNCT
eurjchem-385	12	11	adsorption	adsorption	NOUN
eurjchem-385	12	12	,	,	PUNCT
eurjchem-385	12	13	flocculation	flocculation	NOUN
eurjchem-385	12	14	,	,	PUNCT
eurjchem-385	12	15	and	and	CCONJ
eurjchem-385	12	16	deodorization	deodorization	NOUN
eurjchem-385	12	17	,	,	PUNCT
eurjchem-385	12	18	without	without	ADP
eurjchem-385	12	19	causing	cause	VERB
eurjchem-385	12	20	secondary	secondary	ADJ
eurjchem-385	12	21	pollution	pollution	NOUN
eurjchem-385	12	22	in	in	ADP
eurjchem-385	12	23	wastewater	wastewater	NOUN
eurjchem-385	12	24	treatment	treatment	NOUN
eurjchem-385	12	25	.	.	PUNCT
eurjchem-385	13	1	as	as	SCONJ
eurjchem-385	13	2	the	the	DET
eurjchem-385	13	3	understanding	understanding	NOUN
eurjchem-385	13	4	of	of	ADP
eurjchem-385	13	5	ferrate	ferrate	NOUN
eurjchem-385	13	6	is	be	AUX
eurjchem-385	13	7	further	far	ADV
eurjchem-385	13	8	developed	develop	VERB
eurjchem-385	13	9	,	,	PUNCT
eurjchem-385	13	10	the	the	DET
eurjchem-385	13	11	study	study	NOUN
eurjchem-385	13	12	of	of	ADP
eurjchem-385	13	13	its	its	PRON
eurjchem-385	13	14	application	application	NOUN
eurjchem-385	13	15	value	value	NOUN
eurjchem-385	13	16	becomes	become	VERB
eurjchem-385	13	17	more	more	ADV
eurjchem-385	13	18	and	and	CCONJ
eurjchem-385	13	19	more	more	ADV
eurjchem-385	13	20	important	important	ADJ
eurjchem-385	13	21	.	.	PUNCT
eurjchem-385	14	1	because	because	SCONJ
eurjchem-385	14	2	of	of	ADP
eurjchem-385	14	3	its	its	PRON
eurjchem-385	14	4	strong	strong	ADJ
eurjchem-385	14	5	ability	ability	NOUN
eurjchem-385	14	6	of	of	ADP
eurjchem-385	14	7	oxidation	oxidation	NOUN
eurjchem-385	14	8	,	,	PUNCT
eurjchem-385	14	9	which	which	PRON
eurjchem-385	14	10	can	can	AUX
eurjchem-385	14	11	be	be	AUX
eurjchem-385	14	12	deduced	deduce	VERB
eurjchem-385	14	13	from	from	ADP
eurjchem-385	14	14	its	its	PRON
eurjchem-385	14	15	electrode	electrode	NOUN
eurjchem-385	14	16	potential	potential	NOUN
eurjchem-385	14	17	,	,	PUNCT
eurjchem-385	14	18	ferrate	ferrate	NOUN
eurjchem-385	14	19	can	can	AUX
eurjchem-385	14	20	oxidize	oxidize	VERB
eurjchem-385	14	21	many	many	ADJ
eurjchem-385	14	22	substances	substance	NOUN
eurjchem-385	14	23	,	,	PUNCT
eurjchem-385	14	24	including	include	VERB
eurjchem-385	14	25	inorganic	inorganic	ADJ
eurjchem-385	14	26	compounds	compound	NOUN
eurjchem-385	14	27	and	and	CCONJ
eurjchem-385	14	28	ions	ion	NOUN
eurjchem-385	14	29	such	such	ADJ
eurjchem-385	14	30	as	as	ADP
eurjchem-385	14	31	s2o42‐	s2o42‐	PROPN
eurjchem-385	14	32	,	,	PUNCT
eurjchem-385	14	33	scn‐	scn‐	PROPN
eurjchem-385	14	34	,	,	PUNCT
eurjchem-385	14	35	h2s	h2s	NOUN
eurjchem-385	14	36	etc	etc	X
eurjchem-385	14	37	.	.	PUNCT
eurjchem-385	15	1	[	[	X
eurjchem-385	15	2	5‐7	5‐7	X
eurjchem-385	15	3	]	]	PUNCT
eurjchem-385	15	4	and	and	CCONJ
eurjchem-385	15	5	organic	organic	ADJ
eurjchem-385	15	6	compounds	compound	NOUN
eurjchem-385	15	7	such	such	ADJ
eurjchem-385	15	8	as	as	ADP
eurjchem-385	15	9	alcohol	alcohol	NOUN
eurjchem-385	15	10	,	,	PUNCT
eurjchem-385	15	11	acid	acid	NOUN
eurjchem-385	15	12	,	,	PUNCT
eurjchem-385	15	13	hydroxyl	hydroxyl	NOUN
eurjchem-385	15	14	ketone	ketone	NOUN
eurjchem-385	15	15	,	,	PUNCT
eurjchem-385	15	16	hydrogen	hydrogen	NOUN
eurjchem-385	15	17	quinonoids	quinonoid	NOUN
eurjchem-385	15	18	,	,	PUNCT
eurjchem-385	15	19	benzene	benzene	NOUN
eurjchem-385	15	20	,	,	PUNCT
eurjchem-385	15	21	oxime	oxime	NOUN
eurjchem-385	15	22	etc	etc	X
eurjchem-385	15	23	.	.	PUNCT
eurjchem-385	16	1	[	[	X
eurjchem-385	16	2	8‐	8‐	NUM
eurjchem-385	16	3	10	10	NUM
eurjchem-385	16	4	]	]	PUNCT
eurjchem-385	16	5	without	without	ADP
eurjchem-385	16	6	any	any	DET
eurjchem-385	16	7	hazard	hazard	NOUN
eurjchem-385	16	8	to	to	ADP
eurjchem-385	16	9	human	human	NOUN
eurjchem-385	16	10	and	and	CCONJ
eurjchem-385	16	11	environment	environment	NOUN
eurjchem-385	16	12	.	.	PUNCT
eurjchem-385	17	1	in	in	ADP
eurjchem-385	17	2	1974	1974	NUM
eurjchem-385	17	3	,	,	PUNCT
eurjchem-385	17	4	goff	goff	PROPN
eurjchem-385	17	5	and	and	CCONJ
eurjchem-385	17	6	murmann	murmann	PROPN
eurjchem-385	17	7	published	publish	VERB
eurjchem-385	17	8	the	the	DET
eurjchem-385	17	9	first	first	ADJ
eurjchem-385	17	10	kinetic	kinetic	ADJ
eurjchem-385	17	11	study	study	NOUN
eurjchem-385	17	12	for	for	ADP
eurjchem-385	17	13	the	the	DET
eurjchem-385	17	14	ferrate	ferrate	NOUN
eurjchem-385	17	15	oxidation	oxidation	NOUN
eurjchem-385	17	16	of	of	ADP
eurjchem-385	17	17	hydrogen	hydrogen	NOUN
eurjchem-385	17	18	peroxide	peroxide	NOUN
eurjchem-385	17	19	and	and	CCONJ
eurjchem-385	17	20	sulfite	sulfite	NOUN
eurjchem-385	17	21	along	along	ADV
eurjchem-385	17	22	with	with	ADP
eurjchem-385	17	23	an	an	DET
eurjchem-385	17	24	oxygen	oxygen	NOUN
eurjchem-385	17	25	exchange	exchange	NOUN
eurjchem-385	17	26	study	study	NOUN
eurjchem-385	17	27	[	[	X
eurjchem-385	17	28	11	11	NUM
eurjchem-385	17	29	]	]	PUNCT
eurjchem-385	17	30	.	.	PUNCT
eurjchem-385	18	1	bielski	bielski	PROPN
eurjchem-385	18	2	and	and	CCONJ
eurjchem-385	18	3	sharma	sharma	PROPN
eurjchem-385	18	4	reported	report	VERB
eurjchem-385	18	5	the	the	DET
eurjchem-385	18	6	oxidation	oxidation	NOUN
eurjchem-385	18	7	of	of	ADP
eurjchem-385	18	8	amino	amino	ADJ
eurjchem-385	18	9	acids	acid	NOUN
eurjchem-385	18	10	by	by	ADP
eurjchem-385	18	11	ferrate	ferrate	NOUN
eurjchem-385	18	12	occurs	occur	VERB
eurjchem-385	18	13	via	via	ADP
eurjchem-385	18	14	one‐	one‐	PROPN
eurjchem-385	18	15	electron	electron	NOUN
eurjchem-385	18	16	radical	radical	ADJ
eurjchem-385	18	17	pathways	pathway	NOUN
eurjchem-385	19	1	[	[	X
eurjchem-385	19	2	12	12	NUM
eurjchem-385	19	3	]	]	PUNCT
eurjchem-385	19	4	.	.	PUNCT
eurjchem-385	20	1	in	in	ADP
eurjchem-385	20	2	his	his	PRON
eurjchem-385	20	3	system	system	NOUN
eurjchem-385	20	4	,	,	PUNCT
eurjchem-385	20	5	the	the	DET
eurjchem-385	20	6	oxidation	oxidation	NOUN
eurjchem-385	20	7	occurs	occur	VERB
eurjchem-385	20	8	by	by	ADP
eurjchem-385	20	9	a	a	DET
eurjchem-385	20	10	one‐electron	one‐electron	ADJ
eurjchem-385	20	11	pathway	pathway	NOUN
eurjchem-385	20	12	to	to	PART
eurjchem-385	20	13	produce	produce	VERB
eurjchem-385	20	14	fe(v	fe(v	NOUN
eurjchem-385	20	15	)	)	PUNCT
eurjchem-385	20	16	and	and	CCONJ
eurjchem-385	20	17	then	then	ADV
eurjchem-385	20	18	fe(v	fe(v	NOUN
eurjchem-385	20	19	)	)	PUNCT
eurjchem-385	20	20	rapidly	rapidly	ADV
eurjchem-385	20	21	undergoes	undergo	VERB
eurjchem-385	20	22	a	a	DET
eurjchem-385	20	23	two‐electron	two‐electron	NOUN
eurjchem-385	20	24	transfer	transfer	NOUN
eurjchem-385	20	25	to	to	PART
eurjchem-385	20	26	form	form	VERB
eurjchem-385	20	27	an	an	DET
eurjchem-385	20	28	inner‐sphere	inner‐sphere	NOUN
eurjchem-385	20	29	fe(iii	fe(iii	NOUN
eurjchem-385	20	30	)	)	PUNCT
eurjchem-385	20	31	complex	complex	NOUN
eurjchem-385	21	1	[	[	X
eurjchem-385	21	2	13	13	NUM
eurjchem-385	21	3	]	]	PUNCT
eurjchem-385	21	4	.	.	PUNCT
eurjchem-385	22	1	the	the	DET
eurjchem-385	22	2	exact	exact	ADJ
eurjchem-385	22	3	mechanism	mechanism	NOUN
eurjchem-385	22	4	by	by	ADP
eurjchem-385	22	5	which	which	PRON
eurjchem-385	22	6	this	this	PRON
eurjchem-385	22	7	occurs	occur	VERB
eurjchem-385	22	8	is	be	AUX
eurjchem-385	22	9	not	not	PART
eurjchem-385	22	10	known	know	VERB
eurjchem-385	22	11	.	.	PUNCT
eurjchem-385	23	1	in	in	ADP
eurjchem-385	23	2	contrast	contrast	NOUN
eurjchem-385	23	3	to	to	ADP
eurjchem-385	23	4	the	the	DET
eurjchem-385	23	5	one‐electron	one‐electron	ADJ
eurjchem-385	23	6	mechanisms	mechanism	NOUN
eurjchem-385	23	7	suggested	suggest	VERB
eurjchem-385	23	8	by	by	ADP
eurjchem-385	23	9	bielski	bielski	PROPN
eurjchem-385	23	10	,	,	PUNCT
eurjchem-385	23	11	johnson	johnson	PROPN
eurjchem-385	23	12	and	and	CCONJ
eurjchem-385	23	13	lee	lee	PROPN
eurjchem-385	23	14	have	have	AUX
eurjchem-385	23	15	proposed	propose	VERB
eurjchem-385	23	16	two‐electron	two‐electron	NUM
eurjchem-385	23	17	reductions	reduction	NOUN
eurjchem-385	23	18	of	of	ADP
eurjchem-385	23	19	ferrate	ferrate	NOUN
eurjchem-385	23	20	.	.	PUNCT
eurjchem-385	24	1	johnson	johnson	PROPN
eurjchem-385	24	2	favored	favor	VERB
eurjchem-385	24	3	a	a	DET
eurjchem-385	24	4	quasi‐stable	quasi‐stable	ADJ
eurjchem-385	24	5	ferrate	ferrate	NOUN
eurjchem-385	24	6	/	/	SYM
eurjchem-385	24	7	substrate	substrate	NOUN
eurjchem-385	24	8	bridged	bridge	VERB
eurjchem-385	24	9	intermediate	intermediate	ADJ
eurjchem-385	24	10	for	for	ADP
eurjchem-385	24	11	the	the	DET
eurjchem-385	24	12	reaction	reaction	NOUN
eurjchem-385	24	13	with	with	ADP
eurjchem-385	24	14	thiosulfate	thiosulfate	NOUN
eurjchem-385	24	15	[	[	X
eurjchem-385	24	16	14	14	NUM
eurjchem-385	24	17	]	]	PUNCT
eurjchem-385	24	18	.	.	PUNCT
eurjchem-385	25	1	the	the	DET
eurjchem-385	25	2	proposed	propose	VERB
eurjchem-385	25	3	bridged	bridged	ADJ
eurjchem-385	25	4	species	specie	NOUN
eurjchem-385	25	5	contains	contain	VERB
eurjchem-385	25	6	an	an	DET
eurjchem-385	25	7	ester	ester	NOUN
eurjchem-385	25	8	linked	link	VERB
eurjchem-385	25	9	,	,	PUNCT
eurjchem-385	25	10	fe‐o‐s	fe‐o‐s	ADV
eurjchem-385	25	11	moiety	moiety	NOUN
eurjchem-385	25	12	(	(	PUNCT
eurjchem-385	25	13	s	s	NOUN
eurjchem-385	25	14	=	=	NOUN
eurjchem-385	25	15	substrate	substrate	NOUN
eurjchem-385	25	16	)	)	PUNCT
eurjchem-385	25	17	accompanied	accompany	VERB
eurjchem-385	25	18	by	by	ADP
eurjchem-385	25	19	consecutive	consecutive	ADJ
eurjchem-385	25	20	two‐electron	two‐electron	NUM
eurjchem-385	25	21	reductions	reduction	NOUN
eurjchem-385	25	22	of	of	ADP
eurjchem-385	25	23	fe(vi	fe(vi	NOUN
eurjchem-385	25	24	)	)	PUNCT
eurjchem-385	25	25	that	that	PRON
eurjchem-385	25	26	results	result	VERB
eurjchem-385	25	27	in	in	ADP
eurjchem-385	25	28	fe(ii	fe(ii	PROPN
eurjchem-385	25	29	)	)	PUNCT
eurjchem-385	25	30	.	.	PUNCT
eurjchem-385	26	1	direct	direct	ADJ
eurjchem-385	26	2	oxygen	oxygen	NOUN
eurjchem-385	26	3	transfer	transfer	NOUN
eurjchem-385	26	4	was	be	AUX
eurjchem-385	26	5	observed	observe	VERB
eurjchem-385	26	6	by	by	ADP
eurjchem-385	26	7	oxygen	oxygen	NOUN
eurjchem-385	26	8	tracer	tracer	NOUN
eurjchem-385	26	9	studies	study	NOUN
eurjchem-385	26	10	thereby	thereby	ADV
eurjchem-385	26	11	supporting	support	VERB
eurjchem-385	26	12	this	this	DET
eurjchem-385	26	13	mechanism	mechanism	NOUN
eurjchem-385	26	14	.	.	PUNCT
eurjchem-385	27	1	to	to	ADP
eurjchem-385	27	2	date	date	NOUN
eurjchem-385	27	3	,	,	PUNCT
eurjchem-385	27	4	relatively	relatively	ADV
eurjchem-385	27	5	few	few	ADJ
eurjchem-385	27	6	kinetic	kinetic	ADJ
eurjchem-385	27	7	studies	study	NOUN
eurjchem-385	27	8	of	of	ADP
eurjchem-385	27	9	such	such	ADJ
eurjchem-385	27	10	systems	system	NOUN
eurjchem-385	27	11	have	have	AUX
eurjchem-385	27	12	appeared	appear	VERB
eurjchem-385	27	13	in	in	ADP
eurjchem-385	27	14	the	the	DET
eurjchem-385	27	15	literature	literature	NOUN
eurjchem-385	27	16	.	.	PUNCT
eurjchem-385	28	1	n‐butylamine	n‐butylamine	PUNCT
eurjchem-385	28	2	can	can	AUX
eurjchem-385	28	3	be	be	AUX
eurjchem-385	28	4	used	use	VERB
eurjchem-385	28	5	as	as	ADP
eurjchem-385	28	6	cracked	crack	VERB
eurjchem-385	28	7	gasoline	gasoline	NOUN
eurjchem-385	28	8	antigumagent	antigumagent	NOUN
eurjchem-385	28	9	,	,	PUNCT
eurjchem-385	28	10	petroleum	petroleum	NOUN
eurjchem-385	28	11	products	product	NOUN
eurjchem-385	28	12	additive	additive	VERB
eurjchem-385	28	13	,	,	PUNCT
eurjchem-385	28	14	chromatype	chromatype	NOUN
eurjchem-385	28	15	developer	developer	NOUN
eurjchem-385	28	16	,	,	PUNCT
eurjchem-385	28	17	emulsifier	emulsifier	NOUN
eurjchem-385	28	18	,	,	PUNCT
eurjchem-385	28	19	etc	etc	X
eurjchem-385	28	20	.	.	X
eurjchem-385	29	1	[	[	X
eurjchem-385	29	2	15	15	NUM
eurjchem-385	29	3	]	]	PUNCT
eurjchem-385	29	4	.	.	PUNCT
eurjchem-385	30	1	also	also	ADV
eurjchem-385	30	2	,	,	PUNCT
eurjchem-385	30	3	it	it	PRON
eurjchem-385	30	4	is	be	AUX
eurjchem-385	30	5	an	an	DET
eurjchem-385	30	6	intermediate	intermediate	ADJ
eurjchem-385	30	7	to	to	PART
eurjchem-385	30	8	produce	produce	VERB
eurjchem-385	30	9	drugs	drug	NOUN
eurjchem-385	30	10	and	and	CCONJ
eurjchem-385	30	11	pesticides	pesticide	NOUN
eurjchem-385	30	12	.	.	PUNCT
eurjchem-385	31	1	n‐butylamine	n‐butylamine	PUNCT
eurjchem-385	31	2	is	be	AUX
eurjchem-385	31	3	a	a	DET
eurjchem-385	31	4	toxic	toxic	ADJ
eurjchem-385	31	5	compound	compound	NOUN
eurjchem-385	31	6	,	,	PUNCT
eurjchem-385	31	7	with	with	ADP
eurjchem-385	31	8	strong	strong	ADJ
eurjchem-385	31	9	alkalinity	alkalinity	NOUN
eurjchem-385	31	10	and	and	CCONJ
eurjchem-385	31	11	corrosivity	corrosivity	NOUN
eurjchem-385	31	12	.	.	PUNCT
eurjchem-385	32	1	its	its	PRON
eurjchem-385	32	2	solution	solution	NOUN
eurjchem-385	32	3	or	or	CCONJ
eurjchem-385	32	4	vapors	vapor	NOUN
eurjchem-385	32	5	can	can	AUX
eurjchem-385	32	6	intensely	intensely	ADV
eurjchem-385	32	7	stimulate	stimulate	VERB
eurjchem-385	32	8	eyes	eye	NOUN
eurjchem-385	32	9	,	,	PUNCT
eurjchem-385	32	10	skin	skin	NOUN
eurjchem-385	32	11	and	and	CCONJ
eurjchem-385	32	12	mucous	mucous	ADJ
eurjchem-385	32	13	membrane	membrane	NOUN
eurjchem-385	32	14	.	.	PUNCT
eurjchem-385	33	1	inhaling	inhale	VERB
eurjchem-385	33	2	large	large	ADJ
eurjchem-385	33	3	amounts	amount	NOUN
eurjchem-385	33	4	of	of	ADP
eurjchem-385	33	5	its	its	PRON
eurjchem-385	33	6	vapor	vapor	NOUN
eurjchem-385	33	7	causes	cause	VERB
eurjchem-385	33	8	headache	headache	NOUN
eurjchem-385	33	9	,	,	PUNCT
eurjchem-385	33	10	nausea	nausea	NOUN
eurjchem-385	33	11	,	,	PUNCT
eurjchem-385	33	12	even	even	ADV
eurjchem-385	33	13	pulmonary	pulmonary	ADJ
eurjchem-385	33	14	edema	edema	NOUN
eurjchem-385	33	15	.	.	PUNCT
eurjchem-385	34	1	1,3‐propanediamine	1,3‐propanediamine	NUM
eurjchem-385	34	2	is	be	AUX
eurjchem-385	34	3	mainly	mainly	ADV
eurjchem-385	34	4	used	use	VERB
eurjchem-385	34	5	as	as	ADP
eurjchem-385	34	6	scavenger	scavenger	NOUN
eurjchem-385	34	7	and	and	CCONJ
eurjchem-385	34	8	intermediate	intermediate	ADJ
eurjchem-385	34	9	in	in	ADP
eurjchem-385	34	10	organic	organic	ADJ
eurjchem-385	34	11	synthesis	synthesis	NOUN
eurjchem-385	34	12	.	.	PUNCT
eurjchem-385	35	1	its	its	PRON
eurjchem-385	35	2	toxicity	toxicity	NOUN
eurjchem-385	35	3	is	be	AUX
eurjchem-385	35	4	more	more	ADJ
eurjchem-385	35	5	than	than	ADP
eurjchem-385	35	6	n‐butylamine	n‐butylamine	NUM
eurjchem-385	35	7	.	.	PUNCT
eurjchem-385	36	1	the	the	DET
eurjchem-385	36	2	inhaling	inhaling	NOUN
eurjchem-385	36	3	can	can	AUX
eurjchem-385	36	4	cause	cause	VERB
eurjchem-385	36	5	bronchial	bronchial	ADJ
eurjchem-385	36	6	spasm	spasm	NOUN
eurjchem-385	36	7	,	,	PUNCT
eurjchem-385	36	8	inflammation	inflammation	NOUN
eurjchem-385	36	9	,	,	PUNCT
eurjchem-385	36	10	edema	edema	PROPN
eurjchem-385	36	11	,	,	PUNCT
eurjchem-385	36	12	chemical	chemical	ADJ
eurjchem-385	36	13	pneumonia	pneumonia	NOUN
eurjchem-385	36	14	or	or	CCONJ
eurjchem-385	36	15	pulmonary	pulmonary	ADJ
eurjchem-385	36	16	edema	edema	NOUN
eurjchem-385	36	17	and	and	CCONJ
eurjchem-385	36	18	death	death	NOUN
eurjchem-385	36	19	.	.	PUNCT
eurjchem-385	37	1	in	in	ADP
eurjchem-385	37	2	this	this	DET
eurjchem-385	37	3	paper	paper	NOUN
eurjchem-385	37	4	,	,	PUNCT
eurjchem-385	37	5	the	the	DET
eurjchem-385	37	6	kinetics	kinetic	NOUN
eurjchem-385	37	7	and	and	CCONJ
eurjchem-385	37	8	mechanism	mechanism	NOUN
eurjchem-385	37	9	of	of	ADP
eurjchem-385	37	10	oxidation	oxidation	NOUN
eurjchem-385	37	11	of	of	ADP
eurjchem-385	37	12	n‐butylamine	n‐butylamine	PUNCT
eurjchem-385	37	13	and	and	CCONJ
eurjchem-385	37	14	1,3‐	1,3‐	NUM
eurjchem-385	37	15	propanediamine	propanediamine	NOUN
eurjchem-385	37	16	by	by	ADP
eurjchem-385	37	17	potassium	potassium	NOUN
eurjchem-385	37	18	ferrate	ferrate	NOUN
eurjchem-385	37	19	were	be	AUX
eurjchem-385	37	20	studied	study	VERB
eurjchem-385	37	21	in	in	ADP
eurjchem-385	37	22	detail	detail	NOUN
eurjchem-385	37	23	.	.	PUNCT
eurjchem-385	38	1	2	2	X
eurjchem-385	38	2	.	.	X
eurjchem-385	38	3	experimental	experimental	ADJ
eurjchem-385	38	4	2.1	2.1	NUM
eurjchem-385	38	5	.	.	PUNCT
eurjchem-385	38	6	materials	material	NOUN
eurjchem-385	38	7	,	,	PUNCT
eurjchem-385	38	8	apparatus	apparatus	NOUN
eurjchem-385	38	9	and	and	CCONJ
eurjchem-385	38	10	kinetic	kinetic	ADJ
eurjchem-385	38	11	measurements	measurement	NOUN
eurjchem-385	38	12	measurements	measurement	NOUN
eurjchem-385	38	13	of	of	ADP
eurjchem-385	38	14	the	the	DET
eurjchem-385	38	15	kinetics	kinetic	NOUN
eurjchem-385	38	16	were	be	AUX
eurjchem-385	38	17	performed	perform	VERB
eurjchem-385	38	18	using	use	VERB
eurjchem-385	38	19	a	a	DET
eurjchem-385	38	20	tu‐	tu‐	NOUN
eurjchem-385	38	21	1900	1900	NUM
eurjchem-385	38	22	spectrophotometer	spectrophotometer	NOUN
eurjchem-385	38	23	(	(	PUNCT
eurjchem-385	38	24	beijing	beijing	PROPN
eurjchem-385	38	25	puxi	puxi	PROPN
eurjchem-385	38	26	inc	inc	PROPN
eurjchem-385	38	27	.	.	PROPN
eurjchem-385	38	28	,	,	PUNCT
eurjchem-385	38	29	china	china	PROPN
eurjchem-385	38	30	)	)	PUNCT
eurjchem-385	38	31	fitted	fit	VERB
eurjchem-385	38	32	with	with	ADP
eurjchem-385	38	33	a	a	DET
eurjchem-385	38	34	dc‐2010	dc‐2010	NOUN
eurjchem-385	38	35	thermostat	thermostat	NOUN
eurjchem-385	38	36	(	(	PUNCT
eurjchem-385	38	37	±	±	NOUN
eurjchem-385	38	38	0.1	0.1	NUM
eurjchem-385	38	39	k	k	NOUN
eurjchem-385	38	40	,	,	PUNCT
eurjchem-385	38	41	baoding	baoding	PROPN
eurjchem-385	38	42	,	,	PUNCT
eurjchem-385	38	43	china	china	PROPN
eurjchem-385	38	44	)	)	PUNCT
eurjchem-385	38	45	.	.	PUNCT
eurjchem-385	39	1	all	all	DET
eurjchem-385	39	2	solutions	solution	NOUN
eurjchem-385	39	3	were	be	AUX
eurjchem-385	39	4	prepared	prepare	VERB
eurjchem-385	39	5	with	with	ADP
eurjchem-385	39	6	doubly	doubly	ADV
eurjchem-385	39	7	distilled	distil	VERB
eurjchem-385	39	8	water	water	NOUN
eurjchem-385	39	9	.	.	PUNCT
eurjchem-385	40	1	potassium	potassium	NOUN
eurjchem-385	40	2	ferrate	ferrate	NOUN
eurjchem-385	40	3	(	(	PUNCT
eurjchem-385	40	4	k2feo4	k2feo4	PROPN
eurjchem-385	40	5	)	)	PUNCT
eurjchem-385	40	6	was	be	AUX
eurjchem-385	40	7	prepared	prepare	VERB
eurjchem-385	40	8	by	by	ADP
eurjchem-385	40	9	the	the	DET
eurjchem-385	40	10	method	method	NOUN
eurjchem-385	40	11	of	of	ADP
eurjchem-385	40	12	thompson	thompson	PROPN
eurjchem-385	40	13	et	et	PROPN
eurjchem-385	40	14	al	al	PROPN
eurjchem-385	40	15	.	.	PUNCT
eurjchem-385	41	1	[	[	X
eurjchem-385	41	2	16	16	NUM
eurjchem-385	41	3	]	]	PUNCT
eurjchem-385	41	4	.	.	PUNCT
eurjchem-385	42	1	the	the	DET
eurjchem-385	42	2	concentration	concentration	NOUN
eurjchem-385	42	3	of	of	ADP
eurjchem-385	42	4	k2feo4	k2feo4	PROPN
eurjchem-385	42	5	was	be	AUX
eurjchem-385	42	6	derived	derive	VERB
eurjchem-385	42	7	from	from	ADP
eurjchem-385	42	8	its	its	PRON
eurjchem-385	42	9	absorption	absorption	NOUN
eurjchem-385	42	10	at	at	ADP
eurjchem-385	42	11	507	507	NUM
eurjchem-385	42	12	nm	nm	NOUN
eurjchem-385	42	13	(	(	PUNCT
eurjchem-385	42	14	ε	ε	PROPN
eurjchem-385	42	15	=	=	SYM
eurjchem-385	42	16	1.15×103	1.15×103	NUM
eurjchem-385	42	17	l	l	NOUN
eurjchem-385	42	18	/	/	SYM
eurjchem-385	42	19	mol·cm	mol·cm	NOUN
eurjchem-385	42	20	)	)	PUNCT
eurjchem-385	42	21	.	.	PUNCT
eurjchem-385	43	1	the	the	DET
eurjchem-385	43	2	solution	solution	NOUN
eurjchem-385	43	3	of	of	ADP
eurjchem-385	43	4	k2feo4	k2feo4	PROPN
eurjchem-385	43	5	was	be	AUX
eurjchem-385	43	6	always	always	ADV
eurjchem-385	43	7	freshly	freshly	ADV
eurjchem-385	43	8	prepared	prepare	VERB
eurjchem-385	43	9	before	before	ADP
eurjchem-385	43	10	use	use	NOUN
eurjchem-385	43	11	.	.	PUNCT
eurjchem-385	43	12	n‐butylamine	n‐butylamine	PUNCT
eurjchem-385	43	13	and	and	CCONJ
eurjchem-385	43	14	1,3‐	1,3‐	NUM
eurjchem-385	43	15	propanediamine	propanediamine	NOUN
eurjchem-385	43	16	are	be	AUX
eurjchem-385	43	17	made	make	VERB
eurjchem-385	43	18	in	in	ADP
eurjchem-385	43	19	beijing	beijing	PROPN
eurjchem-385	43	20	chemical	chemical	ADJ
eurjchem-385	43	21	reagent	reagent	ADJ
eurjchem-385	43	22	company	company	NOUN
eurjchem-385	43	23	.	.	PUNCT
eurjchem-385	44	1	the	the	DET
eurjchem-385	44	2	oxidants	oxidant	NOUN
eurjchem-385	44	3	and	and	CCONJ
eurjchem-385	44	4	reductants	reductant	NOUN
eurjchem-385	44	5	were	be	AUX
eurjchem-385	44	6	both	both	PRON
eurjchem-385	44	7	dissolved	dissolve	VERB
eurjchem-385	44	8	in	in	ADP
eurjchem-385	44	9	buffer	buffer	NOUN
eurjchem-385	44	10	solution	solution	NOUN
eurjchem-385	44	11	which	which	PRON
eurjchem-385	44	12	contained	contain	VERB
eurjchem-385	44	13	required	require	VERB
eurjchem-385	44	14	concentration	concentration	NOUN
eurjchem-385	44	15	of	of	ADP
eurjchem-385	44	16	kno3	kno3	PROPN
eurjchem-385	44	17	and	and	CCONJ
eurjchem-385	44	18	na2hpo4	na2hpo4	PROPN
eurjchem-385	44	19	to	to	PART
eurjchem-385	44	20	maintain	maintain	VERB
eurjchem-385	44	21	ionic	ionic	ADJ
eurjchem-385	44	22	strength	strength	NOUN
eurjchem-385	44	23	and	and	CCONJ
eurjchem-385	44	24	acidity	acidity	NOUN
eurjchem-385	44	25	of	of	ADP
eurjchem-385	44	26	the	the	DET
eurjchem-385	44	27	reaction	reaction	NOUN
eurjchem-385	44	28	respectively	respectively	ADV
eurjchem-385	44	29	.	.	PUNCT
eurjchem-385	45	1	the	the	DET
eurjchem-385	45	2	reaction	reaction	NOUN
eurjchem-385	45	3	was	be	AUX
eurjchem-385	45	4	initiated	initiate	VERB
eurjchem-385	45	5	by	by	ADP
eurjchem-385	45	6	mixing	mix	VERB
eurjchem-385	45	7	the	the	DET
eurjchem-385	45	8	shan	shan	NOUN
eurjchem-385	45	9	et	et	PROPN
eurjchem-385	45	10	al	al	PROPN
eurjchem-385	45	11	.	.	PUNCT
eurjchem-385	45	12	/	/	SYM
eurjchem-385	45	13	european	european	PROPN
eurjchem-385	45	14	journal	journal	PROPN
eurjchem-385	45	15	of	of	ADP
eurjchem-385	45	16	chemistry	chemistry	NOUN
eurjchem-385	45	17	2	2	NUM
eurjchem-385	45	18	(	(	PUNCT
eurjchem-385	45	19	3	3	NUM
eurjchem-385	45	20	)	)	PUNCT
eurjchem-385	45	21	(	(	PUNCT
eurjchem-385	45	22	2011	2011	NUM
eurjchem-385	45	23	)	)	PUNCT
eurjchem-385	45	24	342‐346	342‐346	NUM
eurjchem-385	45	25	343	343	NUM
eurjchem-385	45	26	fe(vi	fe(vi	NOUN
eurjchem-385	45	27	)	)	PUNCT
eurjchem-385	45	28	to	to	AUX
eurjchem-385	45	29	reductant	reductant	VERB
eurjchem-385	45	30	solution	solution	NOUN
eurjchem-385	45	31	and	and	CCONJ
eurjchem-385	45	32	the	the	DET
eurjchem-385	45	33	process	process	NOUN
eurjchem-385	45	34	was	be	AUX
eurjchem-385	45	35	monitored	monitor	VERB
eurjchem-385	45	36	the	the	DET
eurjchem-385	45	37	decrease	decrease	NOUN
eurjchem-385	45	38	in	in	ADP
eurjchem-385	45	39	concentration	concentration	NOUN
eurjchem-385	45	40	of	of	ADP
eurjchem-385	45	41	all	all	DET
eurjchem-385	45	42	the	the	DET
eurjchem-385	45	43	fe(vi	fe(vi	NOUN
eurjchem-385	45	44	)	)	PUNCT
eurjchem-385	45	45	species	specie	NOUN
eurjchem-385	45	46	with	with	ADP
eurjchem-385	45	47	time	time	NOUN
eurjchem-385	45	48	(	(	PUNCT
eurjchem-385	45	49	t	t	NOUN
eurjchem-385	45	50	)	)	PUNCT
eurjchem-385	45	51	automatically	automatically	ADV
eurjchem-385	45	52	by	by	ADP
eurjchem-385	45	53	recording	record	VERB
eurjchem-385	45	54	absorbance	absorbance	NOUN
eurjchem-385	45	55	at	at	ADP
eurjchem-385	45	56	507	507	NUM
eurjchem-385	45	57	nm	nm	NOUN
eurjchem-385	45	58	on	on	ADP
eurjchem-385	45	59	a	a	DET
eurjchem-385	45	60	tu‐	tu‐	NOUN
eurjchem-385	45	61	1900	1900	NUM
eurjchem-385	45	62	spectrophotometer	spectrophotometer	NOUN
eurjchem-385	45	63	while	while	SCONJ
eurjchem-385	45	64	other	other	ADJ
eurjchem-385	45	65	species	specie	NOUN
eurjchem-385	45	66	did	do	AUX
eurjchem-385	45	67	not	not	PART
eurjchem-385	45	68	absorb	absorb	VERB
eurjchem-385	45	69	significantly	significantly	ADV
eurjchem-385	45	70	at	at	ADP
eurjchem-385	45	71	this	this	DET
eurjchem-385	45	72	wavelength	wavelength	NOUN
eurjchem-385	45	73	(	(	PUNCT
eurjchem-385	45	74	figure	figure	NOUN
eurjchem-385	45	75	1	1	NUM
eurjchem-385	45	76	)	)	PUNCT
eurjchem-385	45	77	.	.	PUNCT
eurjchem-385	46	1	all	all	DET
eurjchem-385	46	2	kinetics	kinetic	NOUN
eurjchem-385	46	3	measurements	measurement	NOUN
eurjchem-385	46	4	were	be	AUX
eurjchem-385	46	5	carried	carry	VERB
eurjchem-385	46	6	out	out	ADP
eurjchem-385	46	7	under	under	ADP
eurjchem-385	46	8	pseudo‐first	pseudo‐first	ADJ
eurjchem-385	46	9	order	order	NOUN
eurjchem-385	46	10	conditions	condition	NOUN
eurjchem-385	46	11	.	.	PUNCT
eurjchem-385	47	1	figure	figure	NOUN
eurjchem-385	47	2	1	1	NUM
eurjchem-385	47	3	.	.	PUNCT
eurjchem-385	47	4	plots	plot	NOUN
eurjchem-385	47	5	of	of	ADP
eurjchem-385	47	6	reduction	reduction	NOUN
eurjchem-385	47	7	of	of	ADP
eurjchem-385	47	8	oxidant	oxidant	ADJ
eurjchem-385	47	9	absorption	absorption	NOUN
eurjchem-385	47	10	peak	peak	NOUN
eurjchem-385	47	11	through	through	ADP
eurjchem-385	47	12	the	the	DET
eurjchem-385	47	13	reaction	reaction	NOUN
eurjchem-385	47	14	.	.	PUNCT
eurjchem-385	48	1	[	[	X
eurjchem-385	48	2	fe(vi	fe(vi	NOUN
eurjchem-385	48	3	)	)	PUNCT
eurjchem-385	48	4	]	]	PUNCT
eurjchem-385	49	1	=	=	PUNCT
eurjchem-385	49	2	1.56×10‐4	1.56×10‐4	NUM
eurjchem-385	49	3	mol	mol	PROPN
eurjchem-385	49	4	/	/	SYM
eurjchem-385	49	5	l	l	NOUN
eurjchem-385	49	6	,	,	PUNCT
eurjchem-385	49	7	[	[	X
eurjchem-385	49	8	n‐butylamine	n‐butylamine	X
eurjchem-385	49	9	]	]	X
eurjchem-385	49	10	=	=	SYM
eurjchem-385	49	11	0.02	0.02	NUM
eurjchem-385	49	12	mol	mol	ADP
eurjchem-385	49	13	/	/	SYM
eurjchem-385	49	14	l	l	NOUN
eurjchem-385	49	15	,	,	PUNCT
eurjchem-385	49	16	[	[	X
eurjchem-385	49	17	oh‐	oh‐	X
eurjchem-385	49	18	]	]	X
eurjchem-385	49	19	=	=	SYM
eurjchem-385	49	20	1.07×10‐4	1.07×10‐4	NUM
eurjchem-385	49	21	mol	mol	PROPN
eurjchem-385	49	22	/	/	SYM
eurjchem-385	49	23	l	l	NOUN
eurjchem-385	49	24	,	,	PUNCT
eurjchem-385	49	25	i	i	PRON
eurjchem-385	49	26	=	=	PROPN
eurjchem-385	49	27	1.00	1.00	NUM
eurjchem-385	49	28	mol	mol	ADP
eurjchem-385	49	29	/	/	SYM
eurjchem-385	49	30	l	l	PROPN
eurjchem-385	49	31	,	,	PUNCT
eurjchem-385	49	32	t	t	PROPN
eurjchem-385	49	33	=	=	PUNCT
eurjchem-385	49	34	283.2	283.2	NUM
eurjchem-385	49	35	k.	k.	NOUN
eurjchem-385	49	36	2.2	2.2	NUM
eurjchem-385	49	37	.	.	PUNCT
eurjchem-385	50	1	product	product	NOUN
eurjchem-385	50	2	analysis	analysis	NOUN
eurjchem-385	50	3	determination	determination	NOUN
eurjchem-385	50	4	of	of	ADP
eurjchem-385	50	5	reduction	reduction	NOUN
eurjchem-385	50	6	product	product	NOUN
eurjchem-385	50	7	of	of	ADP
eurjchem-385	50	8	fe(vi	fe(vi	PROPN
eurjchem-385	50	9	):	):	PUNCT
eurjchem-385	50	10	the	the	DET
eurjchem-385	50	11	reduction	reduction	NOUN
eurjchem-385	50	12	product	product	NOUN
eurjchem-385	50	13	of	of	ADP
eurjchem-385	50	14	fe(vi	fe(vi	PROPN
eurjchem-385	50	15	)	)	PUNCT
eurjchem-385	50	16	was	be	AUX
eurjchem-385	50	17	identified	identify	VERB
eurjchem-385	50	18	as	as	ADP
eurjchem-385	50	19	fe(iii	fe(iii	NOUN
eurjchem-385	50	20	)	)	PUNCT
eurjchem-385	50	21	by	by	ADP
eurjchem-385	50	22	the	the	DET
eurjchem-385	50	23	color	color	NOUN
eurjchem-385	50	24	reaction	reaction	NOUN
eurjchem-385	50	25	of	of	ADP
eurjchem-385	50	26	k3fe(cn)6	k3fe(cn)6	PROPN
eurjchem-385	50	27	/k4fe(cn)6	/k4fe(cn)6	PUNCT
eurjchem-385	50	28	and	and	CCONJ
eurjchem-385	50	29	2,2‐bipyridyl	2,2‐bipyridyl	NUM
eurjchem-385	51	1	[	[	X
eurjchem-385	51	2	17	17	NUM
eurjchem-385	51	3	]	]	PUNCT
eurjchem-385	51	4	.	.	PUNCT
eurjchem-385	52	1	the	the	DET
eurjchem-385	52	2	result	result	NOUN
eurjchem-385	52	3	showed	show	VERB
eurjchem-385	52	4	no	no	DET
eurjchem-385	52	5	color	color	NOUN
eurjchem-385	52	6	change	change	NOUN
eurjchem-385	52	7	on	on	ADP
eurjchem-385	52	8	k3fe(cn)6	k3fe(cn)6	PROPN
eurjchem-385	52	9	or	or	CCONJ
eurjchem-385	52	10	2,2‐bipyridyl	2,2‐bipyridyl	NUM
eurjchem-385	52	11	but	but	CCONJ
eurjchem-385	52	12	prussian	prussian	ADJ
eurjchem-385	52	13	blue	blue	ADJ
eurjchem-385	52	14	stain	stain	NOUN
eurjchem-385	52	15	on	on	ADP
eurjchem-385	52	16	k4fe(cn)6	k4fe(cn)6	PROPN
eurjchem-385	52	17	.	.	PUNCT
eurjchem-385	53	1	determination	determination	NOUN
eurjchem-385	53	2	of	of	ADP
eurjchem-385	53	3	oxidation	oxidation	NOUN
eurjchem-385	53	4	product	product	NOUN
eurjchem-385	53	5	of	of	ADP
eurjchem-385	53	6	reductant	reductant	NOUN
eurjchem-385	53	7	:	:	PUNCT
eurjchem-385	53	8	ammonia	ammonia	NOUN
eurjchem-385	53	9	was	be	AUX
eurjchem-385	53	10	detected	detect	VERB
eurjchem-385	53	11	through	through	ADP
eurjchem-385	53	12	the	the	DET
eurjchem-385	53	13	reaction	reaction	NOUN
eurjchem-385	53	14	by	by	ADP
eurjchem-385	53	15	using	use	VERB
eurjchem-385	53	16	the	the	DET
eurjchem-385	53	17	method	method	NOUN
eurjchem-385	53	18	of	of	ADP
eurjchem-385	53	19	the	the	DET
eurjchem-385	53	20	reference	reference	NOUN
eurjchem-385	53	21	[	[	X
eurjchem-385	53	22	18	18	NUM
eurjchem-385	53	23	]	]	PUNCT
eurjchem-385	53	24	,	,	PUNCT
eurjchem-385	53	25	which	which	PRON
eurjchem-385	53	26	proves	prove	VERB
eurjchem-385	53	27	that	that	SCONJ
eurjchem-385	53	28	amino	amino	NOUN
eurjchem-385	53	29	of	of	ADP
eurjchem-385	53	30	the	the	DET
eurjchem-385	53	31	reductant	reductant	NOUN
eurjchem-385	53	32	was	be	AUX
eurjchem-385	53	33	oxidized	oxidize	VERB
eurjchem-385	53	34	to	to	ADP
eurjchem-385	53	35	ammonia	ammonia	NOUN
eurjchem-385	53	36	.	.	PUNCT
eurjchem-385	54	1	determination	determination	NOUN
eurjchem-385	54	2	of	of	ADP
eurjchem-385	54	3	reaction	reaction	NOUN
eurjchem-385	54	4	intermediate	intermediate	ADJ
eurjchem-385	54	5	:	:	PUNCT
eurjchem-385	54	6	presence	presence	NOUN
eurjchem-385	54	7	of	of	ADP
eurjchem-385	54	8	fe(ii	fe(ii	PROPN
eurjchem-385	54	9	)	)	PUNCT
eurjchem-385	54	10	was	be	AUX
eurjchem-385	54	11	confirmed	confirm	VERB
eurjchem-385	54	12	by	by	ADP
eurjchem-385	54	13	1,10‐phenanthroline	1,10‐phenanthroline	NUM
eurjchem-385	54	14	test	test	NOUN
eurjchem-385	54	15	.	.	PUNCT
eurjchem-385	55	1	the	the	DET
eurjchem-385	55	2	color	color	NOUN
eurjchem-385	55	3	change	change	NOUN
eurjchem-385	55	4	indicates	indicate	VERB
eurjchem-385	55	5	that	that	SCONJ
eurjchem-385	55	6	fe(phen)32‐	fe(phen)32‐	PROPN
eurjchem-385	55	7	was	be	AUX
eurjchem-385	55	8	generated	generate	VERB
eurjchem-385	55	9	in	in	ADP
eurjchem-385	55	10	the	the	DET
eurjchem-385	55	11	process	process	NOUN
eurjchem-385	55	12	of	of	ADP
eurjchem-385	55	13	the	the	DET
eurjchem-385	55	14	reaction	reaction	NOUN
eurjchem-385	55	15	,	,	PUNCT
eurjchem-385	55	16	which	which	PRON
eurjchem-385	55	17	proves	prove	VERB
eurjchem-385	55	18	fe(ii	fe(ii	PROPN
eurjchem-385	55	19	)	)	PUNCT
eurjchem-385	55	20	has	have	AUX
eurjchem-385	55	21	once	once	ADV
eurjchem-385	55	22	appeared	appear	VERB
eurjchem-385	55	23	[	[	X
eurjchem-385	55	24	10	10	NUM
eurjchem-385	55	25	]	]	PUNCT
eurjchem-385	55	26	.	.	PUNCT
eurjchem-385	56	1	3	3	X
eurjchem-385	56	2	.	.	NOUN
eurjchem-385	56	3	results	result	NOUN
eurjchem-385	56	4	and	and	CCONJ
eurjchem-385	56	5	discussion	discussion	NOUN
eurjchem-385	56	6	3.1	3.1	NUM
eurjchem-385	56	7	.	.	PUNCT
eurjchem-385	57	1	determination	determination	NOUN
eurjchem-385	57	2	of	of	ADP
eurjchem-385	57	3	pseudo‐first	pseudo‐first	ADJ
eurjchem-385	57	4	order	order	NOUN
eurjchem-385	57	5	rate	rate	NOUN
eurjchem-385	57	6	constants	constant	NOUN
eurjchem-385	57	7	3.1.1	3.1.1	NUM
eurjchem-385	57	8	.	.	PUNCT
eurjchem-385	58	1	rate	rate	NOUN
eurjchem-385	58	2	dependence	dependence	NOUN
eurjchem-385	58	3	on	on	ADP
eurjchem-385	58	4	[	[	X
eurjchem-385	58	5	fe(vi	fe(vi	NOUN
eurjchem-385	58	6	)	)	PUNCT
eurjchem-385	58	7	]	]	PUNCT
eurjchem-385	58	8	under	under	ADP
eurjchem-385	58	9	the	the	DET
eurjchem-385	58	10	conditions	condition	NOUN
eurjchem-385	58	11	where	where	SCONJ
eurjchem-385	58	12	[	[	X
eurjchem-385	58	13	reductant]0	reductant]0	NOUN
eurjchem-385	58	14	≫	≫	PROPN
eurjchem-385	58	15	[	[	X
eurjchem-385	58	16	fe(vi)]0	fe(vi)]0	PROPN
eurjchem-385	58	17	,	,	PUNCT
eurjchem-385	58	18	the	the	DET
eurjchem-385	58	19	plots	plot	NOUN
eurjchem-385	58	20	of	of	ADP
eurjchem-385	58	21	ln(at‐a∞	ln(at‐a∞	PROPN
eurjchem-385	58	22	)	)	PUNCT
eurjchem-385	58	23	versus	versus	ADP
eurjchem-385	58	24	time	time	NOUN
eurjchem-385	58	25	t	t	PROPN
eurjchem-385	58	26	were	be	AUX
eurjchem-385	58	27	straight	straight	ADJ
eurjchem-385	58	28	line	line	NOUN
eurjchem-385	58	29	(	(	PUNCT
eurjchem-385	58	30	figure	figure	NOUN
eurjchem-385	58	31	2	2	NUM
eurjchem-385	58	32	)	)	PUNCT
eurjchem-385	58	33	,	,	PUNCT
eurjchem-385	58	34	indicating	indicate	VERB
eurjchem-385	58	35	the	the	DET
eurjchem-385	58	36	reaction	reaction	NOUN
eurjchem-385	58	37	is	be	AUX
eurjchem-385	58	38	first	first	ADJ
eurjchem-385	58	39	order	order	NOUN
eurjchem-385	58	40	with	with	ADP
eurjchem-385	58	41	respect	respect	NOUN
eurjchem-385	58	42	to	to	ADP
eurjchem-385	58	43	the	the	DET
eurjchem-385	58	44	fe(vi	fe(vi	ADJ
eurjchem-385	58	45	)	)	PUNCT
eurjchem-385	58	46	complex	complex	NOUN
eurjchem-385	58	47	,	,	PUNCT
eurjchem-385	58	48	where	where	SCONJ
eurjchem-385	58	49	at	at	ADP
eurjchem-385	58	50	and	and	CCONJ
eurjchem-385	58	51	a∞	a∞	PROPN
eurjchem-385	58	52	are	be	AUX
eurjchem-385	58	53	the	the	DET
eurjchem-385	58	54	absorbance	absorbance	NOUN
eurjchem-385	58	55	at	at	ADP
eurjchem-385	58	56	time	time	NOUN
eurjchem-385	58	57	t	t	PROPN
eurjchem-385	58	58	and	and	CCONJ
eurjchem-385	58	59	at	at	ADP
eurjchem-385	58	60	infinite	infinite	ADJ
eurjchem-385	58	61	time	time	NOUN
eurjchem-385	58	62	respectively	respectively	ADV
eurjchem-385	58	63	.	.	PUNCT
eurjchem-385	59	1	3.1.2	3.1.2	X
eurjchem-385	59	2	.	.	PUNCT
eurjchem-385	59	3	rate	rate	NOUN
eurjchem-385	59	4	dependence	dependence	NOUN
eurjchem-385	59	5	on	on	ADP
eurjchem-385	59	6	[	[	X
eurjchem-385	59	7	reductant	reductant	NOUN
eurjchem-385	59	8	]	]	PUNCT
eurjchem-385	59	9	the	the	DET
eurjchem-385	59	10	pseudo‐first‐order	pseudo‐first‐order	NOUN
eurjchem-385	59	11	rate	rate	NOUN
eurjchem-385	59	12	constants	constant	NOUN
eurjchem-385	59	13	kobs	kobs	PROPN
eurjchem-385	59	14	were	be	AUX
eurjchem-385	59	15	calculated	calculate	VERB
eurjchem-385	59	16	by	by	ADP
eurjchem-385	59	17	the	the	DET
eurjchem-385	59	18	method	method	NOUN
eurjchem-385	59	19	of	of	ADP
eurjchem-385	59	20	least	least	ADJ
eurjchem-385	59	21	squares	square	NOUN
eurjchem-385	59	22	(	(	PUNCT
eurjchem-385	59	23	r	r	NOUN
eurjchem-385	59	24	≥	≥	NUM
eurjchem-385	59	25	0.999	0.999	NUM
eurjchem-385	59	26	)	)	PUNCT
eurjchem-385	59	27	.	.	PUNCT
eurjchem-385	60	1	the	the	DET
eurjchem-385	60	2	kobs	kobs	PROPN
eurjchem-385	60	3	values	value	NOUN
eurjchem-385	60	4	were	be	AUX
eurjchem-385	60	5	the	the	DET
eurjchem-385	60	6	average	average	ADJ
eurjchem-385	60	7	values	value	NOUN
eurjchem-385	60	8	of	of	ADP
eurjchem-385	60	9	at	at	ADV
eurjchem-385	60	10	least	least	ADV
eurjchem-385	60	11	three	three	NUM
eurjchem-385	60	12	independent	independent	ADJ
eurjchem-385	60	13	experiments	experiment	NOUN
eurjchem-385	60	14	,	,	PUNCT
eurjchem-385	60	15	and	and	CCONJ
eurjchem-385	60	16	reproducibility	reproducibility	NOUN
eurjchem-385	60	17	is	be	AUX
eurjchem-385	60	18	within	within	ADP
eurjchem-385	60	19	±	±	NUM
eurjchem-385	60	20	5	5	NUM
eurjchem-385	60	21	%	%	NOUN
eurjchem-385	60	22	.	.	PUNCT
eurjchem-385	61	1	at	at	ADP
eurjchem-385	61	2	fixed	fix	VERB
eurjchem-385	61	3	[	[	X
eurjchem-385	61	4	fe(vi	fe(vi	PROPN
eurjchem-385	61	5	)	)	PUNCT
eurjchem-385	61	6	]	]	PUNCT
eurjchem-385	61	7	,	,	PUNCT
eurjchem-385	61	8	[	[	X
eurjchem-385	61	9	oh‐	oh‐	X
eurjchem-385	61	10	]	]	PUNCT
eurjchem-385	61	11	and	and	CCONJ
eurjchem-385	61	12	ionic	ionic	ADJ
eurjchem-385	61	13	strength	strength	NOUN
eurjchem-385	61	14	i	i	PRON
eurjchem-385	61	15	,	,	PUNCT
eurjchem-385	61	16	the	the	DET
eurjchem-385	61	17	values	value	NOUN
eurjchem-385	61	18	of	of	ADP
eurjchem-385	61	19	kobs	kobs	PROPN
eurjchem-385	61	20	were	be	AUX
eurjchem-385	61	21	determined	determine	VERB
eurjchem-385	61	22	at	at	ADP
eurjchem-385	61	23	different	different	ADJ
eurjchem-385	61	24	temperatures	temperature	NOUN
eurjchem-385	61	25	.	.	PUNCT
eurjchem-385	62	1	the	the	DET
eurjchem-385	62	2	kobs	kobs	PROPN
eurjchem-385	62	3	were	be	AUX
eurjchem-385	62	4	found	find	VERB
eurjchem-385	62	5	to	to	PART
eurjchem-385	62	6	increase	increase	VERB
eurjchem-385	62	7	with	with	ADP
eurjchem-385	62	8	the	the	DET
eurjchem-385	62	9	increase	increase	NOUN
eurjchem-385	62	10	of	of	ADP
eurjchem-385	62	11	reactant	reactant	NOUN
eurjchem-385	62	12	concentration	concentration	NOUN
eurjchem-385	62	13	.	.	PUNCT
eurjchem-385	63	1	the	the	DET
eurjchem-385	63	2	plots	plot	NOUN
eurjchem-385	63	3	of	of	ADP
eurjchem-385	63	4	kobs	kobs	PROPN
eurjchem-385	63	5	versus	versus	X
eurjchem-385	63	6	[	[	X
eurjchem-385	63	7	reductant	reductant	NOUN
eurjchem-385	63	8	]	]	PUNCT
eurjchem-385	63	9	were	be	AUX
eurjchem-385	63	10	linear	linear	ADJ
eurjchem-385	63	11	.	.	PUNCT
eurjchem-385	64	1	for	for	SCONJ
eurjchem-385	64	2	the	the	DET
eurjchem-385	64	3	plots	plot	NOUN
eurjchem-385	64	4	passed	pass	VERB
eurjchem-385	64	5	through	through	ADP
eurjchem-385	64	6	the	the	DET
eurjchem-385	64	7	grid	grid	NOUN
eurjchem-385	64	8	origin	origin	NOUN
eurjchem-385	64	9	(	(	PUNCT
eurjchem-385	64	10	figure	figure	NOUN
eurjchem-385	64	11	3	3	NUM
eurjchem-385	64	12	and	and	CCONJ
eurjchem-385	64	13	4	4	NUM
eurjchem-385	64	14	)	)	PUNCT
eurjchem-385	64	15	,	,	PUNCT
eurjchem-385	64	16	the	the	DET
eurjchem-385	64	17	reaction	reaction	NOUN
eurjchem-385	64	18	was	be	AUX
eurjchem-385	64	19	first	first	ADJ
eurjchem-385	64	20	order	order	NOUN
eurjchem-385	64	21	with	with	ADP
eurjchem-385	64	22	respect	respect	NOUN
eurjchem-385	64	23	to	to	ADP
eurjchem-385	64	24	reductant	reductant	NOUN
eurjchem-385	64	25	.	.	PUNCT
eurjchem-385	65	1	figure	figure	NOUN
eurjchem-385	65	2	2	2	NUM
eurjchem-385	65	3	.	.	PUNCT
eurjchem-385	65	4	plots	plot	NOUN
eurjchem-385	65	5	of	of	ADP
eurjchem-385	65	6	ln(at‐a∞	ln(at‐a∞	PROPN
eurjchem-385	65	7	)	)	PUNCT
eurjchem-385	65	8	versus	versus	ADP
eurjchem-385	65	9	time	time	NOUN
eurjchem-385	65	10	t.	t.	PROPN
eurjchem-385	66	1	[	[	X
eurjchem-385	66	2	fe(vi	fe(vi	PROPN
eurjchem-385	66	3	)	)	PUNCT
eurjchem-385	66	4	]	]	PUNCT
eurjchem-385	67	1	=	=	PUNCT
eurjchem-385	67	2	1.56×10‐4	1.56×10‐4	NUM
eurjchem-385	67	3	mol	mol	PROPN
eurjchem-385	67	4	/	/	SYM
eurjchem-385	67	5	l	l	NOUN
eurjchem-385	67	6	,	,	PUNCT
eurjchem-385	67	7	[	[	X
eurjchem-385	67	8	1,3‐propanediamine	1,3‐propanediamine	NUM
eurjchem-385	67	9	]	]	X
eurjchem-385	67	10	=	=	SYM
eurjchem-385	67	11	0.025	0.025	NUM
eurjchem-385	67	12	mol	mol	PROPN
eurjchem-385	67	13	/	/	SYM
eurjchem-385	67	14	l	l	NOUN
eurjchem-385	67	15	,	,	PUNCT
eurjchem-385	67	16	[	[	X
eurjchem-385	67	17	oh‐	oh‐	X
eurjchem-385	67	18	]	]	X
eurjchem-385	67	19	=	=	SYM
eurjchem-385	67	20	1.17×10‐4	1.17×10‐4	NUM
eurjchem-385	67	21	mol	mol	ADP
eurjchem-385	67	22	/	/	SYM
eurjchem-385	67	23	l	l	NOUN
eurjchem-385	67	24	,	,	PUNCT
eurjchem-385	67	25	i	i	PRON
eurjchem-385	67	26	=	=	PROPN
eurjchem-385	67	27	1.00	1.00	NUM
eurjchem-385	67	28	mol	mol	ADP
eurjchem-385	67	29	/	/	SYM
eurjchem-385	67	30	l	l	PROPN
eurjchem-385	67	31	,	,	PUNCT
eurjchem-385	67	32	t	t	X
eurjchem-385	67	33	=	=	PUNCT
eurjchem-385	67	34	298.2	298.2	NUM
eurjchem-385	67	35	k	k	NOUN
eurjchem-385	67	36	(	(	PUNCT
eurjchem-385	67	37	r	r	NOUN
eurjchem-385	67	38	=	=	SYM
eurjchem-385	67	39	0.9993	0.9993	NUM
eurjchem-385	67	40	)	)	PUNCT
eurjchem-385	67	41	.	.	PUNCT
eurjchem-385	68	1	figure	figure	NOUN
eurjchem-385	68	2	3	3	NUM
eurjchem-385	68	3	.	.	PUNCT
eurjchem-385	68	4	plots	plot	NOUN
eurjchem-385	68	5	of	of	ADP
eurjchem-385	68	6	kobs	kobs	PROPN
eurjchem-385	68	7	versus	versus	ADP
eurjchem-385	68	8	[	[	X
eurjchem-385	68	9	n‐butylamine	n‐butylamine	X
eurjchem-385	68	10	]	]	X
eurjchem-385	68	11	at	at	ADP
eurjchem-385	68	12	different	different	ADJ
eurjchem-385	68	13	temperatures	temperature	NOUN
eurjchem-385	68	14	.	.	PUNCT
eurjchem-385	69	1	[	[	X
eurjchem-385	69	2	fe(vi	fe(vi	NOUN
eurjchem-385	69	3	)	)	PUNCT
eurjchem-385	69	4	]	]	PUNCT
eurjchem-385	70	1	=	=	PUNCT
eurjchem-385	70	2	1.56×10‐4	1.56×10‐4	NUM
eurjchem-385	70	3	mol	mol	PROPN
eurjchem-385	70	4	/	/	SYM
eurjchem-385	70	5	l	l	NOUN
eurjchem-385	70	6	,	,	PUNCT
eurjchem-385	70	7	[	[	X
eurjchem-385	70	8	oh‐	oh‐	X
eurjchem-385	70	9	]	]	X
eurjchem-385	70	10	=	=	SYM
eurjchem-385	70	11	1.07×10‐4	1.07×10‐4	NUM
eurjchem-385	70	12	mol	mol	PROPN
eurjchem-385	70	13	/	/	SYM
eurjchem-385	70	14	l	l	NOUN
eurjchem-385	70	15	,	,	PUNCT
eurjchem-385	70	16	i	i	PRON
eurjchem-385	70	17	=	=	PROPN
eurjchem-385	70	18	1.00	1.00	NUM
eurjchem-385	70	19	mol	mol	ADP
eurjchem-385	70	20	/	/	SYM
eurjchem-385	70	21	l	l	NOUN
eurjchem-385	70	22	(	(	PUNCT
eurjchem-385	70	23	r>0.999	r>0.999	NOUN
eurjchem-385	70	24	)	)	PUNCT
eurjchem-385	70	25	.	.	PUNCT
eurjchem-385	71	1	figure	figure	VERB
eurjchem-385	71	2	4	4	NUM
eurjchem-385	71	3	.	.	PUNCT
eurjchem-385	72	1	plots	plot	NOUN
eurjchem-385	72	2	of	of	ADP
eurjchem-385	72	3	kobs	kobs	NOUN
eurjchem-385	72	4	versus	versus	ADP
eurjchem-385	72	5	[	[	X
eurjchem-385	72	6	1,3‐propanediamine	1,3‐propanediamine	NUM
eurjchem-385	72	7	]	]	X
eurjchem-385	72	8	at	at	ADP
eurjchem-385	72	9	different	different	ADJ
eurjchem-385	72	10	temperatures	temperature	NOUN
eurjchem-385	72	11	.	.	PUNCT
eurjchem-385	73	1	[	[	X
eurjchem-385	73	2	fe(vi	fe(vi	NOUN
eurjchem-385	73	3	)	)	PUNCT
eurjchem-385	73	4	]	]	PUNCT
eurjchem-385	74	1	=	=	PUNCT
eurjchem-385	74	2	1.56×10‐4	1.56×10‐4	NUM
eurjchem-385	74	3	mol	mol	PROPN
eurjchem-385	74	4	/	/	SYM
eurjchem-385	74	5	l	l	NOUN
eurjchem-385	74	6	,	,	PUNCT
eurjchem-385	74	7	[	[	X
eurjchem-385	74	8	oh‐	oh‐	X
eurjchem-385	74	9	]	]	X
eurjchem-385	74	10	=	=	SYM
eurjchem-385	74	11	1.17×10‐4	1.17×10‐4	NUM
eurjchem-385	74	12	mol	mol	ADP
eurjchem-385	74	13	/	/	SYM
eurjchem-385	74	14	l	l	NOUN
eurjchem-385	74	15	,	,	PUNCT
eurjchem-385	74	16	i	i	PRON
eurjchem-385	74	17	=	=	PROPN
eurjchem-385	74	18	1.00	1.00	NUM
eurjchem-385	74	19	mol	mol	ADP
eurjchem-385	74	20	/	/	SYM
eurjchem-385	74	21	l	l	NOUN
eurjchem-385	74	22	(	(	PUNCT
eurjchem-385	74	23	r>0.999	r>0.999	NOUN
eurjchem-385	74	24	)	)	PUNCT
eurjchem-385	74	25	.	.	PUNCT
eurjchem-385	75	1	3.1.2	3.1.2	X
eurjchem-385	75	2	.	.	PUNCT
eurjchem-385	75	3	rate	rate	NOUN
eurjchem-385	75	4	dependence	dependence	NOUN
eurjchem-385	75	5	on	on	ADP
eurjchem-385	75	6	[	[	X
eurjchem-385	75	7	oh‐	oh‐	X
eurjchem-385	75	8	]	]	PUNCT
eurjchem-385	75	9	at	at	ADP
eurjchem-385	75	10	fixed	fix	VERB
eurjchem-385	75	11	[	[	X
eurjchem-385	75	12	fe(vi	fe(vi	PROPN
eurjchem-385	75	13	)	)	PUNCT
eurjchem-385	75	14	]	]	PUNCT
eurjchem-385	75	15	,	,	PUNCT
eurjchem-385	75	16	[	[	X
eurjchem-385	75	17	reductant	reductant	NOUN
eurjchem-385	75	18	]	]	PUNCT
eurjchem-385	75	19	,	,	PUNCT
eurjchem-385	75	20	ionic	ionic	ADJ
eurjchem-385	75	21	strength	strength	NOUN
eurjchem-385	75	22	i	i	PRON
eurjchem-385	75	23	and	and	CCONJ
eurjchem-385	75	24	temperature	temperature	NOUN
eurjchem-385	75	25	,	,	PUNCT
eurjchem-385	75	26	the	the	DET
eurjchem-385	75	27	values	value	NOUN
eurjchem-385	75	28	of	of	ADP
eurjchem-385	75	29	kobs	kobs	PROPN
eurjchem-385	75	30	decreased	decrease	VERB
eurjchem-385	75	31	with	with	ADP
eurjchem-385	75	32	the	the	DET
eurjchem-385	75	33	increase	increase	NOUN
eurjchem-385	75	34	of	of	ADP
eurjchem-385	75	35	344	344	NUM
eurjchem-385	75	36	shan	shan	NOUN
eurjchem-385	75	37	et	et	PROPN
eurjchem-385	75	38	al	al	PROPN
eurjchem-385	75	39	.	.	PUNCT
eurjchem-385	75	40	/	/	SYM
eurjchem-385	75	41	european	european	PROPN
eurjchem-385	75	42	journal	journal	PROPN
eurjchem-385	75	43	of	of	ADP
eurjchem-385	75	44	chemistry	chemistry	NOUN
eurjchem-385	75	45	2	2	NUM
eurjchem-385	75	46	(	(	PUNCT
eurjchem-385	75	47	3	3	NUM
eurjchem-385	75	48	)	)	PUNCT
eurjchem-385	75	49	(	(	PUNCT
eurjchem-385	75	50	2011	2011	NUM
eurjchem-385	75	51	)	)	PUNCT
eurjchem-385	75	52	342‐346	342‐346	NUM
eurjchem-385	76	1	[	[	X
eurjchem-385	76	2	oh‐	oh‐	VERB
eurjchem-385	76	3	]	]	PUNCT
eurjchem-385	76	4	.	.	PUNCT
eurjchem-385	77	1	the	the	DET
eurjchem-385	77	2	order	order	NOUN
eurjchem-385	77	3	with	with	ADP
eurjchem-385	77	4	respect	respect	NOUN
eurjchem-385	77	5	to	to	ADP
eurjchem-385	77	6	[	[	X
eurjchem-385	77	7	oh‐	oh‐	X
eurjchem-385	77	8	]	]	PUNCT
eurjchem-385	77	9	was	be	AUX
eurjchem-385	77	10	found	find	VERB
eurjchem-385	77	11	to	to	PART
eurjchem-385	77	12	be	be	AUX
eurjchem-385	77	13	a	a	DET
eurjchem-385	77	14	negative	negative	ADJ
eurjchem-385	77	15	fraction	fraction	NOUN
eurjchem-385	77	16	,	,	PUNCT
eurjchem-385	77	17	which	which	PRON
eurjchem-385	77	18	indicates	indicate	VERB
eurjchem-385	77	19	that	that	SCONJ
eurjchem-385	77	20	there	there	PRON
eurjchem-385	77	21	is	be	VERB
eurjchem-385	77	22	a	a	DET
eurjchem-385	77	23	balance	balance	NOUN
eurjchem-385	77	24	of	of	ADP
eurjchem-385	77	25	[	[	X
eurjchem-385	77	26	oh‐	oh‐	X
eurjchem-385	77	27	]	]	X
eurjchem-385	77	28	generation	generation	NOUN
eurjchem-385	77	29	before	before	ADP
eurjchem-385	77	30	the	the	DET
eurjchem-385	77	31	speed‐control	speed‐control	NOUN
eurjchem-385	77	32	step	step	NOUN
eurjchem-385	77	33	[	[	X
eurjchem-385	77	34	19	19	NUM
eurjchem-385	77	35	]	]	PUNCT
eurjchem-385	77	36	.	.	PUNCT
eurjchem-385	78	1	the	the	DET
eurjchem-385	78	2	trendlines	trendline	NOUN
eurjchem-385	78	3	of	of	ADP
eurjchem-385	78	4	1	1	NUM
eurjchem-385	78	5	/	/	SYM
eurjchem-385	78	6	kobs	kobs	X
eurjchem-385	78	7	versus	versus	ADP
eurjchem-385	78	8	[	[	X
eurjchem-385	78	9	oh‐	oh‐	X
eurjchem-385	78	10	]	]	PUNCT
eurjchem-385	78	11	(	(	PUNCT
eurjchem-385	78	12	figure	figure	NOUN
eurjchem-385	78	13	5	5	NUM
eurjchem-385	78	14	and	and	CCONJ
eurjchem-385	78	15	6	6	NUM
eurjchem-385	78	16	)	)	PUNCT
eurjchem-385	78	17	show	show	VERB
eurjchem-385	78	18	that	that	SCONJ
eurjchem-385	78	19	the	the	DET
eurjchem-385	78	20	plots	plot	NOUN
eurjchem-385	78	21	did	do	AUX
eurjchem-385	78	22	n’t	not	PART
eurjchem-385	78	23	pass	pass	VERB
eurjchem-385	78	24	through	through	ADP
eurjchem-385	78	25	the	the	DET
eurjchem-385	78	26	grid	grid	NOUN
eurjchem-385	78	27	origin	origin	NOUN
eurjchem-385	78	28	.	.	PUNCT
eurjchem-385	79	1	figure	figure	NOUN
eurjchem-385	79	2	6	6	NUM
eurjchem-385	79	3	.	.	PUNCT
eurjchem-385	80	1	plots	plot	NOUN
eurjchem-385	80	2	of	of	ADP
eurjchem-385	80	3	1	1	NUM
eurjchem-385	80	4	/	/	SYM
eurjchem-385	80	5	kobs	kobs	X
eurjchem-385	80	6	versus	versus	ADP
eurjchem-385	80	7	[	[	X
eurjchem-385	80	8	oh‐	oh‐	X
eurjchem-385	80	9	]	]	PUNCT
eurjchem-385	80	10	at	at	ADP
eurjchem-385	80	11	different	different	ADJ
eurjchem-385	80	12	temperatures	temperature	NOUN
eurjchem-385	80	13	.	.	PUNCT
eurjchem-385	81	1	[	[	X
eurjchem-385	81	2	fe(vi	fe(vi	NOUN
eurjchem-385	81	3	)	)	PUNCT
eurjchem-385	81	4	]	]	PUNCT
eurjchem-385	82	1	=	=	PUNCT
eurjchem-385	82	2	1.56×10‐4	1.56×10‐4	NUM
eurjchem-385	82	3	mol	mol	PROPN
eurjchem-385	82	4	/	/	SYM
eurjchem-385	82	5	l	l	NOUN
eurjchem-385	82	6	,	,	PUNCT
eurjchem-385	82	7	[	[	X
eurjchem-385	82	8	1,3‐propanediamine	1,3‐propanediamine	NUM
eurjchem-385	82	9	]	]	X
eurjchem-385	82	10	=	=	SYM
eurjchem-385	82	11	0.015	0.015	NUM
eurjchem-385	82	12	mol	mol	ADP
eurjchem-385	82	13	/	/	SYM
eurjchem-385	82	14	l	l	NOUN
eurjchem-385	82	15	,	,	PUNCT
eurjchem-385	82	16	i	i	PRON
eurjchem-385	82	17	=	=	PROPN
eurjchem-385	82	18	1.00	1.00	NUM
eurjchem-385	82	19	mol	mol	ADP
eurjchem-385	82	20	/	/	SYM
eurjchem-385	82	21	l	l	NOUN
eurjchem-385	82	22	(	(	PUNCT
eurjchem-385	82	23	r>0.996	r>0.996	NOUN
eurjchem-385	82	24	)	)	PUNCT
eurjchem-385	82	25	.	.	PUNCT
eurjchem-385	83	1	3.2	3.2	NUM
eurjchem-385	83	2	.	.	PUNCT
eurjchem-385	84	1	reaction	reaction	NOUN
eurjchem-385	84	2	mechanism	mechanism	NOUN
eurjchem-385	84	3	james	james	PROPN
eurjchem-385	84	4	carr	carr	PROPN
eurjchem-385	85	1	[	[	X
eurjchem-385	85	2	8	8	NUM
eurjchem-385	85	3	]	]	PUNCT
eurjchem-385	85	4	has	have	AUX
eurjchem-385	85	5	put	put	VERB
eurjchem-385	85	6	forward	forward	ADV
eurjchem-385	85	7	a	a	DET
eurjchem-385	85	8	rate	rate	NOUN
eurjchem-385	85	9	equation	equation	NOUN
eurjchem-385	85	10	which	which	PRON
eurjchem-385	85	11	contains	contain	VERB
eurjchem-385	85	12	three	three	NUM
eurjchem-385	85	13	terms	term	NOUN
eurjchem-385	85	14	as	as	SCONJ
eurjchem-385	85	15	follows	follow	VERB
eurjchem-385	85	16	:	:	PUNCT
eurjchem-385	85	17	rate	rate	NOUN
eurjchem-385	85	18	=	=	SYM
eurjchem-385	85	19	k1[feo42‐	k1[feo42‐	NOUN
eurjchem-385	85	20	]	]	PUNCT
eurjchem-385	85	21	+	+	CCONJ
eurjchem-385	85	22	k2[feo42‐]2	k2[feo42‐]2	VERB
eurjchem-385	85	23	+	+	X
eurjchem-385	85	24	k[feo42‐][s	k[feo42‐][s	PROPN
eurjchem-385	85	25	]	]	X
eurjchem-385	85	26	(	(	PUNCT
eurjchem-385	85	27	s	s	NOUN
eurjchem-385	85	28	=	=	NOUN
eurjchem-385	85	29	substrate	substrate	NOUN
eurjchem-385	85	30	)	)	PUNCT
eurjchem-385	85	31	(	(	PUNCT
eurjchem-385	85	32	1	1	X
eurjchem-385	85	33	)	)	PUNCT
eurjchem-385	85	34	james	james	PROPN
eurjchem-385	85	35	carr	carr	PROPN
eurjchem-385	85	36	thought	think	VERB
eurjchem-385	85	37	that	that	SCONJ
eurjchem-385	85	38	the	the	DET
eurjchem-385	85	39	first	first	ADJ
eurjchem-385	85	40	two	two	NUM
eurjchem-385	85	41	terms	term	NOUN
eurjchem-385	85	42	are	be	AUX
eurjchem-385	85	43	the	the	DET
eurjchem-385	85	44	contribution	contribution	NOUN
eurjchem-385	85	45	of	of	ADP
eurjchem-385	85	46	the	the	DET
eurjchem-385	85	47	self‐decomposition	self‐decomposition	NOUN
eurjchem-385	85	48	rate	rate	NOUN
eurjchem-385	85	49	of	of	ADP
eurjchem-385	85	50	k2feo4	k2feo4	PROPN
eurjchem-385	85	51	to	to	ADP
eurjchem-385	85	52	the	the	DET
eurjchem-385	85	53	reaction	reaction	NOUN
eurjchem-385	85	54	system	system	NOUN
eurjchem-385	85	55	when	when	SCONJ
eurjchem-385	85	56	there	there	PRON
eurjchem-385	85	57	is	be	VERB
eurjchem-385	85	58	no	no	DET
eurjchem-385	85	59	substrate	substrate	NOUN
eurjchem-385	85	60	.	.	PUNCT
eurjchem-385	86	1	under	under	ADP
eurjchem-385	86	2	the	the	DET
eurjchem-385	86	3	experimental	experimental	ADJ
eurjchem-385	86	4	conditions	condition	NOUN
eurjchem-385	86	5	presented	present	VERB
eurjchem-385	86	6	in	in	ADP
eurjchem-385	86	7	this	this	DET
eurjchem-385	86	8	paper	paper	NOUN
eurjchem-385	86	9	,	,	PUNCT
eurjchem-385	86	10	the	the	DET
eurjchem-385	86	11	self‐	self‐	ADJ
eurjchem-385	86	12	decomposition	decomposition	NOUN
eurjchem-385	86	13	rate	rate	NOUN
eurjchem-385	86	14	of	of	ADP
eurjchem-385	86	15	k2feo4	k2feo4	PROPN
eurjchem-385	86	16	is	be	AUX
eurjchem-385	86	17	far	far	ADV
eurjchem-385	86	18	less	less	ADJ
eurjchem-385	86	19	than	than	ADP
eurjchem-385	86	20	the	the	DET
eurjchem-385	86	21	oxidation	oxidation	NOUN
eurjchem-385	86	22	rate	rate	NOUN
eurjchem-385	86	23	of	of	ADP
eurjchem-385	86	24	the	the	DET
eurjchem-385	86	25	reductant	reductant	NOUN
eurjchem-385	86	26	,	,	PUNCT
eurjchem-385	86	27	so	so	SCONJ
eurjchem-385	86	28	we	we	PRON
eurjchem-385	86	29	can	can	AUX
eurjchem-385	86	30	represent	represent	VERB
eurjchem-385	86	31	the	the	DET
eurjchem-385	86	32	rate	rate	NOUN
eurjchem-385	86	33	equation	equation	NOUN
eurjchem-385	86	34	as	as	SCONJ
eurjchem-385	86	35	follows	follow	VERB
eurjchem-385	86	36	which	which	PRON
eurjchem-385	86	37	is	be	AUX
eurjchem-385	86	38	consistent	consistent	ADJ
eurjchem-385	86	39	with	with	ADP
eurjchem-385	86	40	james	james	PROPN
eurjchem-385	86	41	carr	carr	PROPN
eurjchem-385	86	42	in	in	ADP
eurjchem-385	86	43	essence	essence	NOUN
eurjchem-385	86	44	:	:	PUNCT
eurjchem-385	86	45	rate	rate	NOUN
eurjchem-385	86	46	=	=	SYM
eurjchem-385	86	47	k[feo42‐][r	k[feo42‐][r	X
eurjchem-385	86	48	]	]	X
eurjchem-385	86	49	(	(	PUNCT
eurjchem-385	86	50	r	r	NOUN
eurjchem-385	86	51	=	=	NOUN
eurjchem-385	86	52	reductant	reductant	NOUN
eurjchem-385	86	53	)	)	PUNCT
eurjchem-385	86	54	(	(	PUNCT
eurjchem-385	86	55	2	2	X
eurjchem-385	86	56	)	)	PUNCT
eurjchem-385	86	57	ferrate(vi	ferrate(vi	PROPN
eurjchem-385	86	58	)	)	PUNCT
eurjchem-385	86	59	is	be	AUX
eurjchem-385	86	60	a	a	DET
eurjchem-385	86	61	diacid	diacid	ADJ
eurjchem-385	87	1	[	[	X
eurjchem-385	87	2	20	20	NUM
eurjchem-385	87	3	]	]	PUNCT
eurjchem-385	87	4	,	,	PUNCT
eurjchem-385	87	5	where	where	SCONJ
eurjchem-385	87	6	:	:	PUNCT
eurjchem-385	87	7	h2feo4	h2feo4	PROPN
eurjchem-385	87	8	hfeo4‐	hfeo4‐	PROPN
eurjchem-385	87	9	+	+	CCONJ
eurjchem-385	87	10	h+	h+	X
eurjchem-385	87	11	pka1=3.5	pka1=3.5	X
eurjchem-385	87	12	(	(	PUNCT
eurjchem-385	87	13	3	3	X
eurjchem-385	87	14	)	)	PUNCT
eurjchem-385	87	15	hfeo4‐	hfeo4‐	NOUN
eurjchem-385	87	16	h+	h+	X
eurjchem-385	87	17	+	+	CCONJ
eurjchem-385	87	18	feo42‐	feo42‐	PROPN
eurjchem-385	87	19	pka2=7.8	pka2=7.8	NOUN
eurjchem-385	87	20	(	(	PUNCT
eurjchem-385	87	21	4	4	NUM
eurjchem-385	87	22	)	)	PUNCT
eurjchem-385	87	23	then	then	ADV
eurjchem-385	87	24	,	,	PUNCT
eurjchem-385	87	25	part	part	NOUN
eurjchem-385	87	26	of	of	ADP
eurjchem-385	87	27	feo42‐	feo42‐	PROPN
eurjchem-385	87	28	will	will	AUX
eurjchem-385	87	29	take	take	VERB
eurjchem-385	87	30	hydrolysis	hydrolysis	NOUN
eurjchem-385	87	31	as	as	SCONJ
eurjchem-385	87	32	follows	follow	VERB
eurjchem-385	87	33	:	:	PUNCT
eurjchem-385	87	34	feo42‐	feo42‐	PROPN
eurjchem-385	87	35	+	+	CCONJ
eurjchem-385	87	36	h2o	h2o	PROPN
eurjchem-385	87	37	hfeo4‐	hfeo4‐	PROPN
eurjchem-385	87	38	+	+	CCONJ
eurjchem-385	87	39	oh‐	oh‐	VERB
eurjchem-385	87	40	(	(	PUNCT
eurjchem-385	87	41	5	5	NUM
eurjchem-385	87	42	)	)	PUNCT
eurjchem-385	87	43	hence	hence	ADV
eurjchem-385	87	44	:	:	PUNCT
eurjchem-385	87	45	kw	kw	PROPN
eurjchem-385	87	46	kh	kh	PROPN
eurjchem-385	87	47	ka	ka	PROPN
eurjchem-385	87	48	‐	‐	PROPN
eurjchem-385	87	49	‐	‐	ADV
eurjchem-385	87	50	4	4	NUM
eurjchem-385	87	51	2‐	2‐	NUM
eurjchem-385	87	52	4	4	NUM
eurjchem-385	87	53	2	2	NUM
eurjchem-385	88	1	[	[	X
eurjchem-385	88	2	hfeo	hfeo	X
eurjchem-385	88	3	]	]	X
eurjchem-385	89	1	[	[	X
eurjchem-385	89	2	oh	oh	INTJ
eurjchem-385	89	3	]	]	X
eurjchem-385	89	4	=	=	PUNCT
eurjchem-385	89	5	=	=	PUNCT
eurjchem-385	90	1	[	[	X
eurjchem-385	90	2	feo	feo	X
eurjchem-385	90	3	]	]	X
eurjchem-385	90	4	=	=	SYM
eurjchem-385	90	5	6.31×10‐7	6.31×10‐7	NUM
eurjchem-385	90	6	(	(	PUNCT
eurjchem-385	90	7	6	6	NUM
eurjchem-385	90	8	)	)	PUNCT
eurjchem-385	90	9	this	this	DET
eurjchem-385	90	10	experiment	experiment	NOUN
eurjchem-385	90	11	is	be	AUX
eurjchem-385	90	12	performed	perform	VERB
eurjchem-385	90	13	at	at	ADP
eurjchem-385	90	14	ph	ph	NOUN
eurjchem-385	90	15	=	=	PROPN
eurjchem-385	90	16	10.03	10.03	NUM
eurjchem-385	90	17	and	and	CCONJ
eurjchem-385	90	18	10.07	10.07	NUM
eurjchem-385	90	19	,	,	PUNCT
eurjchem-385	90	20	then	then	ADV
eurjchem-385	90	21	there	there	PRON
eurjchem-385	90	22	is	be	VERB
eurjchem-385	90	23	kh	kh	PROPN
eurjchem-385	90	24	‐	‐	ADJ
eurjchem-385	90	25	4	4	NUM
eurjchem-385	90	26	2‐	2‐	NUM
eurjchem-385	90	27	‐	‐	ADV
eurjchem-385	90	28	4	4	NUM
eurjchem-385	91	1	[	[	X
eurjchem-385	91	2	hfeo	hfeo	X
eurjchem-385	91	3	]	]	X
eurjchem-385	91	4	=	=	PUNCT
eurjchem-385	92	1	=	=	PUNCT
eurjchem-385	93	1	[	[	X
eurjchem-385	93	2	feo	feo	X
eurjchem-385	93	3	]	]	X
eurjchem-385	94	1	[	[	X
eurjchem-385	94	2	oh	oh	INTJ
eurjchem-385	94	3	]	]	X
eurjchem-385	94	4	5.90×10‐3	5.90×10‐3	NUM
eurjchem-385	94	5	and	and	CCONJ
eurjchem-385	94	6	5.39×10‐3	5.39×10‐3	NUM
eurjchem-385	94	7	(	(	PUNCT
eurjchem-385	94	8	7	7	NUM
eurjchem-385	94	9	)	)	PUNCT
eurjchem-385	94	10	although	although	SCONJ
eurjchem-385	94	11	the	the	DET
eurjchem-385	94	12	concentration	concentration	NOUN
eurjchem-385	94	13	of	of	ADP
eurjchem-385	94	14	hfeo4‐	hfeo4‐	NOUN
eurjchem-385	94	15	is	be	AUX
eurjchem-385	94	16	very	very	ADV
eurjchem-385	94	17	small	small	ADJ
eurjchem-385	94	18	,	,	PUNCT
eurjchem-385	94	19	it	it	PRON
eurjchem-385	94	20	is	be	AUX
eurjchem-385	94	21	easy	easy	ADJ
eurjchem-385	94	22	for	for	SCONJ
eurjchem-385	94	23	it	it	PRON
eurjchem-385	94	24	to	to	PART
eurjchem-385	94	25	form	form	VERB
eurjchem-385	94	26	a	a	DET
eurjchem-385	94	27	six‐membered	six‐membere	VERB
eurjchem-385	94	28	ring	ring	NOUN
eurjchem-385	94	29	complex	complex	NOUN
eurjchem-385	94	30	with	with	ADP
eurjchem-385	94	31	the	the	DET
eurjchem-385	94	32	reductant	reductant	NOUN
eurjchem-385	94	33	in	in	ADP
eurjchem-385	94	34	the	the	DET
eurjchem-385	94	35	presence	presence	NOUN
eurjchem-385	94	36	of	of	ADP
eurjchem-385	94	37	a	a	DET
eurjchem-385	94	38	hydrogen	hydrogen	NOUN
eurjchem-385	94	39	atom	atom	NOUN
eurjchem-385	94	40	.	.	PUNCT
eurjchem-385	95	1	the	the	DET
eurjchem-385	95	2	formed	form	VERB
eurjchem-385	95	3	complex	complex	NOUN
eurjchem-385	95	4	has	have	VERB
eurjchem-385	95	5	higher	high	ADJ
eurjchem-385	95	6	activity	activity	NOUN
eurjchem-385	95	7	towards	towards	ADP
eurjchem-385	95	8	anion	anion	NOUN
eurjchem-385	95	9	[	[	X
eurjchem-385	95	10	21	21	NUM
eurjchem-385	95	11	]	]	PUNCT
eurjchem-385	95	12	.	.	PUNCT
eurjchem-385	96	1	under	under	ADP
eurjchem-385	96	2	the	the	DET
eurjchem-385	96	3	attack	attack	NOUN
eurjchem-385	96	4	of	of	ADP
eurjchem-385	96	5	hydroxyl	hydroxyl	NOUN
eurjchem-385	96	6	,	,	PUNCT
eurjchem-385	96	7	the	the	DET
eurjchem-385	96	8	complex	complex	ADJ
eurjchem-385	96	9	dissociates	dissociate	NOUN
eurjchem-385	96	10	into	into	ADP
eurjchem-385	96	11	fe(iv	fe(iv	NOUN
eurjchem-385	96	12	)	)	PUNCT
eurjchem-385	96	13	and	and	CCONJ
eurjchem-385	96	14	at	at	ADP
eurjchem-385	96	15	the	the	DET
eurjchem-385	96	16	same	same	ADJ
eurjchem-385	96	17	time	time	NOUN
eurjchem-385	96	18	releases	release	VERB
eurjchem-385	96	19	ammonia	ammonia	NOUN
eurjchem-385	96	20	.	.	PUNCT
eurjchem-385	97	1	the	the	DET
eurjchem-385	97	2	probable	probable	ADJ
eurjchem-385	97	3	reaction	reaction	NOUN
eurjchem-385	97	4	process	process	NOUN
eurjchem-385	97	5	takes	take	VERB
eurjchem-385	97	6	place	place	NOUN
eurjchem-385	97	7	as	as	SCONJ
eurjchem-385	97	8	given	give	VERB
eurjchem-385	97	9	in	in	ADP
eurjchem-385	97	10	scheme	scheme	NOUN
eurjchem-385	97	11	1	1	NUM
eurjchem-385	97	12	.	.	PUNCT
eurjchem-385	98	1	then	then	ADV
eurjchem-385	98	2	,	,	PUNCT
eurjchem-385	98	3	as	as	ADP
eurjchem-385	98	4	an	an	DET
eurjchem-385	98	5	intermediate	intermediate	ADJ
eurjchem-385	98	6	,	,	PUNCT
eurjchem-385	98	7	fe(iv	fe(iv	PROPN
eurjchem-385	98	8	)	)	PUNCT
eurjchem-385	98	9	is	be	AUX
eurjchem-385	98	10	much	much	ADV
eurjchem-385	98	11	more	more	ADV
eurjchem-385	98	12	active	active	ADJ
eurjchem-385	98	13	than	than	ADP
eurjchem-385	98	14	fe(vi	fe(vi	NOUN
eurjchem-385	98	15	)	)	PUNCT
eurjchem-385	99	1	[	[	X
eurjchem-385	99	2	21	21	NUM
eurjchem-385	99	3	]	]	PUNCT
eurjchem-385	99	4	,	,	PUNCT
eurjchem-385	99	5	and	and	CCONJ
eurjchem-385	99	6	it	it	PRON
eurjchem-385	99	7	continues	continue	VERB
eurjchem-385	99	8	to	to	PART
eurjchem-385	99	9	react	react	VERB
eurjchem-385	99	10	further	far	ADV
eurjchem-385	99	11	with	with	ADP
eurjchem-385	99	12	another	another	DET
eurjchem-385	99	13	molecule	molecule	NOUN
eurjchem-385	99	14	of	of	ADP
eurjchem-385	99	15	reductant	reductant	NOUN
eurjchem-385	99	16	to	to	PART
eurjchem-385	99	17	generate	generate	VERB
eurjchem-385	99	18	fe(ii	fe(ii	PROPN
eurjchem-385	99	19	)	)	PUNCT
eurjchem-385	99	20	.	.	PUNCT
eurjchem-385	100	1	therefore	therefore	ADV
eurjchem-385	100	2	,	,	PUNCT
eurjchem-385	100	3	the	the	DET
eurjchem-385	100	4	reaction	reaction	NOUN
eurjchem-385	100	5	takes	take	VERB
eurjchem-385	100	6	place	place	NOUN
eurjchem-385	100	7	mainly	mainly	ADV
eurjchem-385	100	8	through	through	ADP
eurjchem-385	100	9	hfeo4‐.	hfeo4‐.	NOUN
eurjchem-385	100	10	according	accord	VERB
eurjchem-385	100	11	to	to	ADP
eurjchem-385	100	12	discussion	discussion	NOUN
eurjchem-385	100	13	,	,	PUNCT
eurjchem-385	100	14	the	the	DET
eurjchem-385	100	15	following	follow	VERB
eurjchem-385	100	16	reaction	reaction	NOUN
eurjchem-385	100	17	mechanism	mechanism	NOUN
eurjchem-385	100	18	is	be	AUX
eurjchem-385	100	19	proposed	propose	VERB
eurjchem-385	100	20	:	:	PUNCT
eurjchem-385	100	21	feo42‐	feo42‐	PROPN
eurjchem-385	100	22	+	+	CCONJ
eurjchem-385	100	23	h2o	h2o	PROPN
eurjchem-385	100	24	hfeo4‐	hfeo4‐	PROPN
eurjchem-385	100	25	+	+	CCONJ
eurjchem-385	100	26	oh‐	oh‐	VERB
eurjchem-385	100	27	(	(	PUNCT
eurjchem-385	100	28	8)	8)	NUM
eurjchem-385	100	29	hfeo4‐	hfeo4‐	NOUN
eurjchem-385	100	30	+	+	CCONJ
eurjchem-385	100	31	r	r	NOUN
eurjchem-385	100	32	x	x	SYM
eurjchem-385	100	33	(	(	PUNCT
eurjchem-385	100	34	9	9	NUM
eurjchem-385	100	35	)	)	PUNCT
eurjchem-385	100	36	k3‐	k3‐	VERB
eurjchem-385	100	37	x	x	PUNCT
eurjchem-385	101	1	+	+	CCONJ
eurjchem-385	101	2	oh	oh	NUM
eurjchem-385	101	3	fe(iv	fe(iv	NOUN
eurjchem-385	101	4	)	)	PUNCT
eurjchem-385	101	5	+	+	NUM
eurjchem-385	101	6	p(product	p(product	NOUN
eurjchem-385	101	7	)	)	PUNCT
eurjchem-385	101	8	(	(	PUNCT
eurjchem-385	101	9	10	10	NUM
eurjchem-385	101	10	)	)	PUNCT
eurjchem-385	101	11	k4fe(iv	k4fe(iv	NOUN
eurjchem-385	101	12	)	)	PUNCT
eurjchem-385	102	1	+	+	CCONJ
eurjchem-385	102	2	r	r	NOUN
eurjchem-385	102	3	fe(ii	fe(ii	PROPN
eurjchem-385	102	4	)	)	PUNCT
eurjchem-385	102	5	+	+	NUM
eurjchem-385	102	6	p(product	p(product	NOUN
eurjchem-385	102	7	)	)	PUNCT
eurjchem-385	102	8	(	(	PUNCT
eurjchem-385	102	9	11	11	NUM
eurjchem-385	102	10	)	)	PUNCT
eurjchem-385	102	11	k5fe(iv	k5fe(iv	NOUN
eurjchem-385	102	12	)	)	PUNCT
eurjchem-385	102	13	+	+	NUM
eurjchem-385	102	14	fe(ii	fe(ii	PROPN
eurjchem-385	102	15	)	)	PUNCT
eurjchem-385	102	16	fe(iii	fe(iii	PROPN
eurjchem-385	102	17	)	)	PUNCT
eurjchem-385	102	18	(	(	PUNCT
eurjchem-385	102	19	12	12	NUM
eurjchem-385	102	20	)	)	PUNCT
eurjchem-385	102	21	reaction	reaction	NOUN
eurjchem-385	102	22	(	(	PUNCT
eurjchem-385	102	23	9	9	NUM
eurjchem-385	102	24	)	)	PUNCT
eurjchem-385	102	25	is	be	AUX
eurjchem-385	102	26	the	the	DET
eurjchem-385	102	27	rate‐determining	rate‐determining	NOUN
eurjchem-385	102	28	step	step	NOUN
eurjchem-385	102	29	.	.	PUNCT
eurjchem-385	103	1	as	as	SCONJ
eurjchem-385	103	2	the	the	DET
eurjchem-385	103	3	rate	rate	NOUN
eurjchem-385	103	4	of	of	ADP
eurjchem-385	103	5	the	the	DET
eurjchem-385	103	6	disappearance	disappearance	NOUN
eurjchem-385	103	7	of	of	ADP
eurjchem-385	103	8	[	[	X
eurjchem-385	103	9	feo42‐	feo42‐	PROPN
eurjchem-385	103	10	]	]	PUNCT
eurjchem-385	103	11	was	be	AUX
eurjchem-385	103	12	monitored	monitor	VERB
eurjchem-385	103	13	,	,	PUNCT
eurjchem-385	103	14	the	the	DET
eurjchem-385	103	15	rate	rate	NOUN
eurjchem-385	103	16	of	of	ADP
eurjchem-385	103	17	the	the	DET
eurjchem-385	103	18	reaction	reaction	NOUN
eurjchem-385	103	19	can	can	AUX
eurjchem-385	103	20	be	be	AUX
eurjchem-385	103	21	derived	derive	VERB
eurjchem-385	103	22	as	as	ADP
eurjchem-385	103	23	:	:	PUNCT
eurjchem-385	103	24	d	d	X
eurjchem-385	103	25	k	k	PROPN
eurjchem-385	104	1	k	k	PROPN
eurjchem-385	105	1	d	d	X
eurjchem-385	105	2	2‐	2‐	NUM
eurjchem-385	105	3	‐4	‐4	NOUN
eurjchem-385	105	4	2	2	NUM
eurjchem-385	105	5	4	4	NUM
eurjchem-385	105	6	‐2	‐2	NUM
eurjchem-385	105	7	[	[	X
eurjchem-385	105	8	feo	feo	X
eurjchem-385	105	9	]	]	PUNCT
eurjchem-385	105	10	‐	‐	NOUN
eurjchem-385	105	11	=	=	PUNCT
eurjchem-385	106	1	[	[	X
eurjchem-385	106	2	hfeo	hfeo	X
eurjchem-385	106	3	]	]	X
eurjchem-385	106	4	[	[	X
eurjchem-385	106	5	r	r	X
eurjchem-385	106	6	]	]	X
eurjchem-385	106	7	‐	‐	ADP
eurjchem-385	106	8	[	[	X
eurjchem-385	106	9	x	x	X
eurjchem-385	106	10	]	]	X
eurjchem-385	106	11	t	t	PROPN
eurjchem-385	106	12	(	(	PUNCT
eurjchem-385	106	13	13	13	NUM
eurjchem-385	106	14	)	)	PUNCT
eurjchem-385	106	15	after	after	ADP
eurjchem-385	106	16	steady‐state	steady‐state	ADJ
eurjchem-385	106	17	processing	processing	NOUN
eurjchem-385	106	18	:	:	PUNCT
eurjchem-385	106	19	k	k	PROPN
eurjchem-385	106	20	k	k	PROPN
eurjchem-385	106	21	k	k	PROPN
eurjchem-385	106	22	‐	‐	ADV
eurjchem-385	106	23	2	2	NUM
eurjchem-385	106	24	4	4	NUM
eurjchem-385	106	25	‐	‐	NOUN
eurjchem-385	106	26	‐2	‐2	NUM
eurjchem-385	106	27	3	3	NUM
eurjchem-385	106	28	[	[	X
eurjchem-385	106	29	feo	feo	X
eurjchem-385	106	30	]	]	X
eurjchem-385	106	31	[	[	X
eurjchem-385	106	32	r	r	X
eurjchem-385	106	33	]	]	X
eurjchem-385	106	34	[	[	X
eurjchem-385	106	35	x	x	X
eurjchem-385	106	36	]	]	X
eurjchem-385	106	37	=	=	PUNCT
eurjchem-385	107	1	+	+	PUNCT
eurjchem-385	108	1	[	[	X
eurjchem-385	108	2	oh	oh	INTJ
eurjchem-385	108	3	]	]	X
eurjchem-385	108	4	(	(	PUNCT
eurjchem-385	108	5	14	14	NUM
eurjchem-385	108	6	)	)	PUNCT
eurjchem-385	108	7	then	then	ADV
eurjchem-385	108	8	we	we	PRON
eurjchem-385	108	9	get	get	VERB
eurjchem-385	108	10	the	the	DET
eurjchem-385	108	11	rate	rate	NOUN
eurjchem-385	108	12	equation	equation	NOUN
eurjchem-385	108	13	:	:	PUNCT
eurjchem-385	109	1	d	d	X
eurjchem-385	109	2	d	d	X
eurjchem-385	109	3	2‐	2‐	NUM
eurjchem-385	109	4	4	4	NUM
eurjchem-385	109	5	[	[	X
eurjchem-385	109	6	feo	feo	X
eurjchem-385	109	7	]	]	PUNCT
eurjchem-385	109	8	‐	‐	ADP
eurjchem-385	109	9	t	t	PROPN
eurjchem-385	109	10	k	k	PROPN
eurjchem-385	109	11	k	k	PROPN
eurjchem-385	109	12	k	k	PROPN
eurjchem-385	109	13	k	k	PROPN
eurjchem-385	109	14	‐	‐	NOUN
eurjchem-385	109	15	‐	‐	ADV
eurjchem-385	109	16	2	2	NUM
eurjchem-385	109	17	3	3	NUM
eurjchem-385	109	18	4	4	NUM
eurjchem-385	109	19	‐	‐	NOUN
eurjchem-385	109	20	‐2	‐2	NUM
eurjchem-385	109	21	3	3	NUM
eurjchem-385	109	22	[	[	X
eurjchem-385	109	23	hfeo	hfeo	X
eurjchem-385	109	24	]	]	X
eurjchem-385	109	25	[	[	X
eurjchem-385	109	26	r][oh	r][oh	X
eurjchem-385	109	27	]	]	X
eurjchem-385	109	28	=	=	PUNCT
eurjchem-385	110	1	+	+	PUNCT
eurjchem-385	111	1	[	[	X
eurjchem-385	111	2	oh	oh	INTJ
eurjchem-385	111	3	]	]	X
eurjchem-385	111	4	(	(	PUNCT
eurjchem-385	111	5	15	15	NUM
eurjchem-385	111	6	)	)	PUNCT
eurjchem-385	111	7	equation	equation	NOUN
eurjchem-385	111	8	(	(	PUNCT
eurjchem-385	111	9	16	16	NUM
eurjchem-385	111	10	)	)	PUNCT
eurjchem-385	111	11	can	can	AUX
eurjchem-385	111	12	be	be	AUX
eurjchem-385	111	13	obtained	obtain	VERB
eurjchem-385	111	14	from	from	ADP
eurjchem-385	111	15	(	(	PUNCT
eurjchem-385	111	16	8)	8)	NUM
eurjchem-385	111	17	:	:	PUNCT
eurjchem-385	111	18	k	k	PROPN
eurjchem-385	111	19	h	h	NOUN
eurjchem-385	111	20	2‐	2‐	NUM
eurjchem-385	111	21	4‐	4‐	NOUN
eurjchem-385	111	22	4	4	NUM
eurjchem-385	111	23	‐	‐	NOUN
eurjchem-385	111	24	[	[	X
eurjchem-385	111	25	feo	feo	X
eurjchem-385	111	26	]	]	X
eurjchem-385	112	1	[	[	X
eurjchem-385	112	2	hfeo	hfeo	X
eurjchem-385	112	3	]	]	X
eurjchem-385	112	4	=	=	PUNCT
eurjchem-385	113	1	[	[	X
eurjchem-385	113	2	oh	oh	INTJ
eurjchem-385	113	3	]	]	X
eurjchem-385	113	4	(	(	PUNCT
eurjchem-385	113	5	16	16	NUM
eurjchem-385	113	6	)	)	PUNCT
eurjchem-385	113	7	figure	figure	NOUN
eurjchem-385	113	8	5	5	NUM
eurjchem-385	113	9	.	.	PUNCT
eurjchem-385	113	10	plots	plot	NOUN
eurjchem-385	113	11	of	of	ADP
eurjchem-385	113	12	1	1	NUM
eurjchem-385	113	13	/	/	SYM
eurjchem-385	113	14	kobs	kobs	X
eurjchem-385	113	15	versus	versus	ADP
eurjchem-385	113	16	[	[	X
eurjchem-385	113	17	oh‐	oh‐	X
eurjchem-385	113	18	]	]	PUNCT
eurjchem-385	113	19	at	at	ADP
eurjchem-385	113	20	different	different	ADJ
eurjchem-385	113	21	temperatures	temperature	NOUN
eurjchem-385	113	22	.	.	PUNCT
eurjchem-385	114	1	[	[	X
eurjchem-385	114	2	fe(vi	fe(vi	NOUN
eurjchem-385	114	3	)	)	PUNCT
eurjchem-385	114	4	]	]	PUNCT
eurjchem-385	115	1	=	=	PUNCT
eurjchem-385	115	2	1.56×10‐4	1.56×10‐4	NUM
eurjchem-385	115	3	mol	mol	PROPN
eurjchem-385	115	4	/	/	SYM
eurjchem-385	115	5	l	l	NOUN
eurjchem-385	115	6	,	,	PUNCT
eurjchem-385	115	7	[	[	X
eurjchem-385	115	8	n‐butylamine	n‐butylamine	X
eurjchem-385	115	9	]	]	X
eurjchem-385	115	10	=	=	SYM
eurjchem-385	115	11	0.06	0.06	NUM
eurjchem-385	115	12	mol	mol	PROPN
eurjchem-385	115	13	/	/	SYM
eurjchem-385	115	14	l	l	NOUN
eurjchem-385	115	15	,	,	PUNCT
eurjchem-385	115	16	i	i	PRON
eurjchem-385	115	17	=	=	PROPN
eurjchem-385	115	18	1.00	1.00	NUM
eurjchem-385	115	19	mol	mol	ADP
eurjchem-385	115	20	/	/	SYM
eurjchem-385	115	21	l	l	NOUN
eurjchem-385	115	22	(	(	PUNCT
eurjchem-385	115	23	r>0.999	r>0.999	NOUN
eurjchem-385	115	24	)	)	PUNCT
eurjchem-385	115	25	.	.	PUNCT
eurjchem-385	116	1	shan	shan	INTJ
eurjchem-385	116	2	et	et	PROPN
eurjchem-385	116	3	al	al	PROPN
eurjchem-385	116	4	.	.	PUNCT
eurjchem-385	116	5	/	/	SYM
eurjchem-385	116	6	european	european	PROPN
eurjchem-385	116	7	journal	journal	PROPN
eurjchem-385	116	8	of	of	ADP
eurjchem-385	116	9	chemistry	chemistry	NOUN
eurjchem-385	116	10	2	2	NUM
eurjchem-385	116	11	(	(	PUNCT
eurjchem-385	116	12	3	3	NUM
eurjchem-385	116	13	)	)	PUNCT
eurjchem-385	116	14	(	(	PUNCT
eurjchem-385	116	15	2011	2011	NUM
eurjchem-385	116	16	)	)	PUNCT
eurjchem-385	116	17	342‐346	342‐346	NUM
eurjchem-385	116	18	345	345	NUM
eurjchem-385	116	19	table	table	NOUN
eurjchem-385	116	20	1	1	NUM
eurjchem-385	116	21	.	.	PUNCT
eurjchem-385	117	1	rate	rate	NOUN
eurjchem-385	117	2	constants	constant	NOUN
eurjchem-385	117	3	(	(	PUNCT
eurjchem-385	117	4	k2	k2	NOUN
eurjchem-385	117	5	)	)	PUNCT
eurjchem-385	117	6	and	and	CCONJ
eurjchem-385	117	7	thermodynamic	thermodynamic	ADJ
eurjchem-385	117	8	activation	activation	NOUN
eurjchem-385	117	9	parameters	parameter	NOUN
eurjchem-385	117	10	of	of	ADP
eurjchem-385	117	11	the	the	DET
eurjchem-385	117	12	rate‐determining	rate‐determining	NOUN
eurjchem-385	117	13	step	step	NOUN
eurjchem-385	117	14	(	(	PUNCT
eurjchem-385	117	15	t	t	NOUN
eurjchem-385	117	16	=	=	PUNCT
eurjchem-385	117	17	298.2	298.2	NUM
eurjchem-385	117	18	k	k	NOUN
eurjchem-385	117	19	)	)	PUNCT
eurjchem-385	117	20	.	.	PUNCT
eurjchem-385	118	1	t(k	t(k	NOUN
eurjchem-385	118	2	)	)	PUNCT
eurjchem-385	119	1	283.2	283.2	NUM
eurjchem-385	119	2	288.2	288.2	NUM
eurjchem-385	119	3	293.2	293.2	NUM
eurjchem-385	119	4	298.2	298.2	NUM
eurjchem-385	119	5	k2	k2	NOUN
eurjchem-385	119	6	/	/	SYM
eurjchem-385	119	7	mol‐1.l.s‐1	mol‐1.l.s‐1	NOUN
eurjchem-385	119	8	n‐butylamine	n‐butylamine	NUM
eurjchem-385	119	9	513.38	513.38	NUM
eurjchem-385	119	10	643.89	643.89	NUM
eurjchem-385	119	11	894.03	894.03	NUM
eurjchem-385	119	12	1156.10	1156.10	NUM
eurjchem-385	119	13	1,3‐propanediamine	1,3‐propanediamine	NUM
eurjchem-385	119	14	1629.22	1629.22	NUM
eurjchem-385	119	15	2399.00	2399.00	NUM
eurjchem-385	119	16	3632.35	3632.35	NUM
eurjchem-385	119	17	5566.98	5566.98	NUM
eurjchem-385	119	18	thermodynamic	thermodynamic	ADJ
eurjchem-385	119	19	activation	activation	NOUN
eurjchem-385	119	20	parameters	parameter	NOUN
eurjchem-385	119	21	(	(	PUNCT
eurjchem-385	119	22	298.2	298.2	NUM
eurjchem-385	119	23	k	k	NOUN
eurjchem-385	119	24	)	)	PUNCT
eurjchem-385	119	25	n‐butylamine	n‐butylamine	PUNCT
eurjchem-385	119	26	ea	ea	X
eurjchem-385	119	27	=	=	SYM
eurjchem-385	119	28	38.78	38.78	NUM
eurjchem-385	119	29	kj	kj	PROPN
eurjchem-385	119	30	/	/	SYM
eurjchem-385	119	31	mol	mol	PROPN
eurjchem-385	119	32	,	,	PUNCT
eurjchem-385	119	33	δh≠	δh≠	NOUN
eurjchem-385	119	34	=	=	SYM
eurjchem-385	119	35	36.31	36.31	NUM
eurjchem-385	119	36	kj	kj	PROPN
eurjchem-385	119	37	/	/	SYM
eurjchem-385	119	38	mol	mol	PROPN
eurjchem-385	119	39	,	,	PUNCT
eurjchem-385	119	40	δs≠	δs≠	PROPN
eurjchem-385	120	1	=	=	SYM
eurjchem-385	120	2	‐64.60	‐64.60	PROPN
eurjchem-385	120	3	j	j	PROPN
eurjchem-385	120	4	/	/	SYM
eurjchem-385	120	5	k·mol	k·mol	PROPN
eurjchem-385	120	6	1,3‐propanediamine	1,3‐propanediamine	NUM
eurjchem-385	120	7	ea	ea	NOUN
eurjchem-385	120	8	=	=	NOUN
eurjchem-385	120	9	57.56	57.56	NUM
eurjchem-385	120	10	kj	kj	PROPN
eurjchem-385	120	11	/	/	SYM
eurjchem-385	120	12	mol	mol	PROPN
eurjchem-385	120	13	,	,	PUNCT
eurjchem-385	120	14	δh≠	δh≠	NOUN
eurjchem-385	121	1	=	=	SYM
eurjchem-385	121	2	55.08	55.08	NUM
eurjchem-385	121	3	kj	kj	PROPN
eurjchem-385	121	4	/	/	SYM
eurjchem-385	121	5	mol	mol	PROPN
eurjchem-385	121	6	,	,	PUNCT
eurjchem-385	121	7	δs≠	δs≠	PROPN
eurjchem-385	121	8	=	=	SYM
eurjchem-385	121	9	11.28	11.28	NUM
eurjchem-385	121	10	j	j	NOUN
eurjchem-385	121	11	/	/	SYM
eurjchem-385	121	12	k·mol	k·mol	AUX
eurjchem-385	121	13	the	the	DET
eurjchem-385	121	14	plots	plot	NOUN
eurjchem-385	121	15	of	of	ADP
eurjchem-385	121	16	ln	ln	PROPN
eurjchem-385	121	17	k2	k2	NOUN
eurjchem-385	121	18	vs.	vs.	ADP
eurjchem-385	121	19	1	1	NUM
eurjchem-385	121	20	/	/	SYM
eurjchem-385	121	21	t	t	PROPN
eurjchem-385	121	22	have	have	AUX
eurjchem-385	121	23	following	follow	VERB
eurjchem-385	121	24	intercept	intercept	NOUN
eurjchem-385	121	25	(	(	PUNCT
eurjchem-385	121	26	a	a	NOUN
eurjchem-385	121	27	)	)	PUNCT
eurjchem-385	121	28	slope	slope	NOUN
eurjchem-385	121	29	(	(	PUNCT
eurjchem-385	121	30	b	b	NOUN
eurjchem-385	121	31	)	)	PUNCT
eurjchem-385	121	32	and	and	CCONJ
eurjchem-385	121	33	relative	relative	ADJ
eurjchem-385	121	34	coefficient	coefficient	NOUN
eurjchem-385	121	35	(	(	PUNCT
eurjchem-385	121	36	r	r	NOUN
eurjchem-385	121	37	)	)	PUNCT
eurjchem-385	121	38	.	.	PUNCT
eurjchem-385	122	1	n‐butylamine	n‐butylamine	PUNCT
eurjchem-385	122	2	:	:	PUNCT
eurjchem-385	122	3	a	a	DET
eurjchem-385	122	4	=	=	SYM
eurjchem-385	122	5	22.69	22.69	NUM
eurjchem-385	122	6	,	,	PUNCT
eurjchem-385	122	7	b	b	X
eurjchem-385	122	8	=	=	SYM
eurjchem-385	122	9	‐4665.02	‐4665.02	PROPN
eurjchem-385	122	10	,	,	PUNCT
eurjchem-385	122	11	r	r	NOUN
eurjchem-385	122	12	=	=	SYM
eurjchem-385	122	13	‐0.997	‐0.997	ADJ
eurjchem-385	122	14	;	;	PUNCT
eurjchem-385	122	15	1,3‐propanediamine	1,3‐propanediamine	NUM
eurjchem-385	122	16	:	:	PUNCT
eurjchem-385	122	17	a	a	PRON
eurjchem-385	122	18	=	=	SYM
eurjchem-385	122	19	31.82	31.82	NUM
eurjchem-385	122	20	,	,	PUNCT
eurjchem-385	122	21	b	b	NOUN
eurjchem-385	122	22	=	=	PUNCT
eurjchem-385	122	23	‐6923.19	‐6923.19	NUM
eurjchem-385	122	24	,	,	PUNCT
eurjchem-385	122	25	r	r	NOUN
eurjchem-385	122	26	=	=	SYM
eurjchem-385	122	27	‐0.9993	‐0.9993	PROPN
eurjchem-385	122	28	.	.	PUNCT
eurjchem-385	122	29	table	table	NOUN
eurjchem-385	122	30	2	2	NUM
eurjchem-385	122	31	.	.	PUNCT
eurjchem-385	123	1	the	the	DET
eurjchem-385	123	2	values	value	NOUN
eurjchem-385	123	3	of	of	ADP
eurjchem-385	123	4	103×kobs	103×kobs	NUM
eurjchem-385	123	5	experimental	experimental	ADJ
eurjchem-385	123	6	and	and	CCONJ
eurjchem-385	123	7	calculated	calculate	VERB
eurjchem-385	123	8	at	at	ADP
eurjchem-385	123	9	different	different	ADJ
eurjchem-385	123	10	temperatures	temperature	NOUN
eurjchem-385	123	11	(	(	PUNCT
eurjchem-385	123	12	[	[	X
eurjchem-385	123	13	oh‐	oh‐	X
eurjchem-385	123	14	]	]	X
eurjchem-385	123	15	=	=	SYM
eurjchem-385	123	16	1.07×10‐4	1.07×10‐4	NUM
eurjchem-385	123	17	mol	mol	PROPN
eurjchem-385	123	18	/	/	SYM
eurjchem-385	123	19	l	l	NOUN
eurjchem-385	123	20	,	,	PUNCT
eurjchem-385	123	21	r=	r=	ADJ
eurjchem-385	123	22	n‐butylamine	n‐butylamine	NUM
eurjchem-385	123	23	)	)	PUNCT
eurjchem-385	123	24	.	.	PUNCT
eurjchem-385	124	1	t	t	PROPN
eurjchem-385	124	2	/	/	SYM
eurjchem-385	124	3	k	k	PROPN
eurjchem-385	124	4	c	c	X
eurjchem-385	124	5	/	/	SYM
eurjchem-385	124	6	mol·l‐1	mol·l‐1	NOUN
eurjchem-385	124	7	283.2	283.2	NUM
eurjchem-385	124	8	288.2	288.2	NUM
eurjchem-385	124	9	293.2	293.2	NUM
eurjchem-385	124	10	298.2	298.2	NUM
eurjchem-385	124	11	exp	exp	NOUN
eurjchem-385	124	12	cal	cal	NUM
eurjchem-385	124	13	exp	exp	NOUN
eurjchem-385	124	14	cal	cal	PROPN
eurjchem-385	124	15	exp	exp	NOUN
eurjchem-385	124	16	cal	cal	PROPN
eurjchem-385	124	17	exp	exp	NOUN
eurjchem-385	124	18	cal	cal	PROPN
eurjchem-385	124	19	0.02	0.02	NUM
eurjchem-385	124	20	15.58	15.58	NUM
eurjchem-385	124	21	15.60	15.60	NUM
eurjchem-385	124	22	21.26	21.26	NUM
eurjchem-385	124	23	20.20	20.20	NUM
eurjchem-385	124	24	27.18	27.18	NUM
eurjchem-385	124	25	26.27	26.27	NUM
eurjchem-385	124	26	34.04	34.04	NUM
eurjchem-385	124	27	34.90	34.90	NUM
eurjchem-385	124	28	0.04	0.04	NUM
eurjchem-385	124	29	31.83	31.83	NUM
eurjchem-385	124	30	31.19	31.19	NUM
eurjchem-385	124	31	44.38	44.38	NUM
eurjchem-385	124	32	40.41	40.41	NUM
eurjchem-385	124	33	53.73	53.73	NUM
eurjchem-385	124	34	52.55	52.55	NUM
eurjchem-385	124	35	69.75	69.75	NUM
eurjchem-385	124	36	69.81	69.81	NUM
eurjchem-385	124	37	0.06	0.06	NUM
eurjchem-385	124	38	47.87	47.87	NUM
eurjchem-385	124	39	46.79	46.79	NUM
eurjchem-385	124	40	61.68	61.68	NUM
eurjchem-385	124	41	60.61	60.61	NUM
eurjchem-385	124	42	78.75	78.75	NUM
eurjchem-385	124	43	78.82	78.82	NUM
eurjchem-385	124	44	101.09	101.09	NUM
eurjchem-385	124	45	104.71	104.71	NUM
eurjchem-385	124	46	0.08	0.08	NUM
eurjchem-385	124	47	62.91	62.91	NUM
eurjchem-385	124	48	62.39	62.39	NUM
eurjchem-385	124	49	78.59	78.59	NUM
eurjchem-385	124	50	80.81	80.81	NUM
eurjchem-385	124	51	102.24	102.24	NUM
eurjchem-385	124	52	105.09	105.09	NUM
eurjchem-385	124	53	135.32	135.32	NUM
eurjchem-385	124	54	139.62	139.62	NUM
eurjchem-385	124	55	0.10	0.10	NUM
eurjchem-385	124	56	77.69	77.69	NUM
eurjchem-385	124	57	77.98	77.98	NUM
eurjchem-385	124	58	103.06	103.06	NUM
eurjchem-385	124	59	101.02	101.02	NUM
eurjchem-385	124	60	129.94	129.94	NUM
eurjchem-385	124	61	131.36	131.36	NUM
eurjchem-385	124	62	172.14	172.14	NUM
eurjchem-385	124	63	174.52	174.52	NUM
eurjchem-385	124	64	table	table	NOUN
eurjchem-385	124	65	3	3	NUM
eurjchem-385	124	66	.	.	PUNCT
eurjchem-385	125	1	the	the	DET
eurjchem-385	125	2	values	value	NOUN
eurjchem-385	125	3	of	of	ADP
eurjchem-385	125	4	103×kobs	103×kobs	NUM
eurjchem-385	125	5	experimental	experimental	ADJ
eurjchem-385	125	6	and	and	CCONJ
eurjchem-385	125	7	calculated	calculate	VERB
eurjchem-385	125	8	at	at	ADP
eurjchem-385	125	9	different	different	ADJ
eurjchem-385	125	10	temperatures	temperature	NOUN
eurjchem-385	125	11	(	(	PUNCT
eurjchem-385	125	12	[	[	X
eurjchem-385	125	13	oh‐	oh‐	X
eurjchem-385	125	14	]	]	X
eurjchem-385	125	15	=	=	NUM
eurjchem-385	125	16	1.17×10‐4	1.17×10‐4	NUM
eurjchem-385	125	17	mol	mol	ADP
eurjchem-385	125	18	/	/	SYM
eurjchem-385	125	19	l	l	NOUN
eurjchem-385	125	20	,	,	PUNCT
eurjchem-385	125	21	r	r	NOUN
eurjchem-385	125	22	=	=	SYM
eurjchem-385	125	23	1,3‐propanediamine	1,3‐propanediamine	NUM
eurjchem-385	125	24	)	)	PUNCT
eurjchem-385	125	25	.	.	PUNCT
eurjchem-385	126	1	t	t	PROPN
eurjchem-385	126	2	/	/	SYM
eurjchem-385	126	3	k	k	PROPN
eurjchem-385	126	4	c	c	X
eurjchem-385	126	5	/	/	SYM
eurjchem-385	126	6	mol·l‐1	mol·l‐1	NOUN
eurjchem-385	126	7	283.2	283.2	NUM
eurjchem-385	126	8	288.2	288.2	NUM
eurjchem-385	126	9	293.2	293.2	NUM
eurjchem-385	126	10	298.2	298.2	NUM
eurjchem-385	126	11	exp	exp	NOUN
eurjchem-385	126	12	cal	cal	NUM
eurjchem-385	126	13	exp	exp	NOUN
eurjchem-385	126	14	cal	cal	PROPN
eurjchem-385	126	15	exp	exp	NOUN
eurjchem-385	126	16	cal	cal	PROPN
eurjchem-385	126	17	exp	exp	NOUN
eurjchem-385	126	18	cal	cal	NOUN
eurjchem-385	126	19	0.005	0.005	NUM
eurjchem-385	126	20	11.86	11.86	NUM
eurjchem-385	126	21	15.04	15.04	NUM
eurjchem-385	126	22	17.19	17.19	NUM
eurjchem-385	126	23	18.31	18.31	NUM
eurjchem-385	126	24	23.22	23.22	NUM
eurjchem-385	126	25	25.26	25.26	NUM
eurjchem-385	126	26	30.38	30.38	NUM
eurjchem-385	126	27	33.30	33.30	NUM
eurjchem-385	126	28	0.010	0.010	NUM
eurjchem-385	126	29	30.02	30.02	NUM
eurjchem-385	126	30	30.08	30.08	NUM
eurjchem-385	126	31	38.32	38.32	NUM
eurjchem-385	126	32	36.61	36.61	NUM
eurjchem-385	126	33	49.80	49.80	NUM
eurjchem-385	126	34	50.52	50.52	NUM
eurjchem-385	126	35	65.29	65.29	NUM
eurjchem-385	126	36	66.60	66.60	NUM
eurjchem-385	126	37	0.015	0.015	NUM
eurjchem-385	126	38	44.88	44.88	NUM
eurjchem-385	126	39	45.12	45.12	NUM
eurjchem-385	126	40	57.91	57.91	NUM
eurjchem-385	126	41	54.93	54.93	NUM
eurjchem-385	126	42	74.23	74.23	NUM
eurjchem-385	126	43	75.78	75.78	NUM
eurjchem-385	126	44	101.47	101.47	NUM
eurjchem-385	126	45	99.90	99.90	NUM
eurjchem-385	126	46	0.020	0.020	NUM
eurjchem-385	126	47	53.97	53.97	NUM
eurjchem-385	126	48	60.16	60.16	NUM
eurjchem-385	126	49	74.14	74.14	NUM
eurjchem-385	126	50	73.24	73.24	NUM
eurjchem-385	126	51	101.97	101.97	NUM
eurjchem-385	126	52	101.04	101.04	NUM
eurjchem-385	126	53	133.92	133.92	NUM
eurjchem-385	126	54	133.20	133.20	NUM
eurjchem-385	126	55	0.025	0.025	NUM
eurjchem-385	126	56	75.51	75.51	NUM
eurjchem-385	126	57	75.21	75.21	NUM
eurjchem-385	126	58	93.01	93.01	NUM
eurjchem-385	126	59	91.55	91.55	NUM
eurjchem-385	126	60	128.15	128.15	NUM
eurjchem-385	126	61	126.30	126.30	NUM
eurjchem-385	126	62	172.04	172.04	NUM
eurjchem-385	126	63	166.50	166.50	NUM
eurjchem-385	126	64	scheme	scheme	NOUN
eurjchem-385	126	65	1	1	NUM
eurjchem-385	126	66	substituting	substitute	VERB
eurjchem-385	126	67	equation	equation	NOUN
eurjchem-385	126	68	(	(	PUNCT
eurjchem-385	126	69	16	16	NUM
eurjchem-385	126	70	)	)	PUNCT
eurjchem-385	126	71	into	into	ADP
eurjchem-385	126	72	(	(	PUNCT
eurjchem-385	126	73	15	15	NUM
eurjchem-385	126	74	)	)	PUNCT
eurjchem-385	126	75	,	,	PUNCT
eurjchem-385	126	76	we	we	PRON
eurjchem-385	126	77	can	can	AUX
eurjchem-385	126	78	get	get	VERB
eurjchem-385	126	79	the	the	DET
eurjchem-385	126	80	following	follow	VERB
eurjchem-385	126	81	equation	equation	NOUN
eurjchem-385	126	82	:	:	PUNCT
eurjchem-385	127	1	h	h	NOUN
eurjchem-385	127	2	h	h	NOUN
eurjchem-385	128	1	k	k	PROPN
eurjchem-385	129	1	k	k	PROPN
eurjchem-385	130	1	k	k	PROPN
eurjchem-385	130	2	k	k	PROPN
eurjchem-385	130	3	k	k	PROPN
eurjchem-385	130	4	kd	kd	PROPN
eurjchem-385	130	5	d	d	PROPN
eurjchem-385	130	6	k	k	PROPN
eurjchem-385	130	7	k	k	PROPN
eurjchem-385	130	8	k	k	PROPN
eurjchem-385	130	9	k	k	PROPN
eurjchem-385	130	10	2‐2‐	2‐2‐	NUM
eurjchem-385	130	11	2‐2	2‐2	NOUN
eurjchem-385	130	12	3	3	NUM
eurjchem-385	130	13	4	4	NUM
eurjchem-385	130	14	2	2	NUM
eurjchem-385	130	15	34	34	NUM
eurjchem-385	130	16	4‐	4‐	NOUN
eurjchem-385	130	17	‐	‐	NOUN
eurjchem-385	130	18	‐2	‐2	NUM
eurjchem-385	130	19	3	3	NUM
eurjchem-385	130	20	‐2	‐2	NUM
eurjchem-385	130	21	3	3	NUM
eurjchem-385	131	1	[	[	X
eurjchem-385	131	2	feo	feo	X
eurjchem-385	131	3	]	]	X
eurjchem-385	131	4	[	[	X
eurjchem-385	131	5	r	r	X
eurjchem-385	131	6	]	]	X
eurjchem-385	131	7	[	[	X
eurjchem-385	131	8	r][feo	r][feo	NOUN
eurjchem-385	131	9	]	]	PUNCT
eurjchem-385	131	10	‐	‐	NOUN
eurjchem-385	131	11	=	=	PUNCT
eurjchem-385	131	12	=	=	PUNCT
eurjchem-385	132	1	[	[	X
eurjchem-385	132	2	feo	feo	X
eurjchem-385	132	3	]	]	X
eurjchem-385	132	4	t	t	NOUN
eurjchem-385	133	1	+	+	X
eurjchem-385	134	1	[	[	X
eurjchem-385	134	2	oh	oh	INTJ
eurjchem-385	134	3	]	]	PUNCT
eurjchem-385	134	4	+	+	CCONJ
eurjchem-385	135	1	[	[	X
eurjchem-385	135	2	oh	oh	INTJ
eurjchem-385	135	3	]	]	X
eurjchem-385	135	4	(	(	PUNCT
eurjchem-385	135	5	17	17	NUM
eurjchem-385	135	6	)	)	PUNCT
eurjchem-385	135	7	h	h	NOUN
eurjchem-385	135	8	h	h	NOUN
eurjchem-385	136	1	k	k	PROPN
eurjchem-385	137	1	k	k	PROPN
eurjchem-385	137	2	k	k	PROPN
eurjchem-385	137	3	k	k	PROPN
eurjchem-385	137	4	k	k	PROPN
eurjchem-385	137	5	k	k	PROPN
eurjchem-385	137	6	k	k	PROPN
eurjchem-385	137	7	k	k	PROPN
eurjchem-385	137	8	k	k	PROPN
eurjchem-385	137	9	k	k	PROPN
eurjchem-385	137	10	2	2	NUM
eurjchem-385	137	11	3	3	NUM
eurjchem-385	137	12	2	2	NUM
eurjchem-385	137	13	obs	obs	NOUN
eurjchem-385	137	14	‐	‐	NOUN
eurjchem-385	137	15	‐	‐	ADV
eurjchem-385	137	16	‐2	‐2	NUM
eurjchem-385	137	17	3	3	NUM
eurjchem-385	138	1	[	[	X
eurjchem-385	138	2	r	r	X
eurjchem-385	138	3	]	]	PUNCT
eurjchem-385	138	4	'	'	PUNCT
eurjchem-385	139	1	[	[	X
eurjchem-385	139	2	r	r	X
eurjchem-385	139	3	]	]	X
eurjchem-385	139	4	=	=	PUNCT
eurjchem-385	139	5	=	=	PUNCT
eurjchem-385	140	1	+	+	PUNCT
eurjchem-385	141	1	[	[	X
eurjchem-385	141	2	oh	oh	INTJ
eurjchem-385	141	3	]	]	X
eurjchem-385	141	4	1	1	NUM
eurjchem-385	141	5	+	+	CCONJ
eurjchem-385	141	6	'	'	X
eurjchem-385	141	7	[	[	X
eurjchem-385	141	8	oh	oh	INTJ
eurjchem-385	141	9	]	]	X
eurjchem-385	141	10	(	(	PUNCT
eurjchem-385	141	11	18	18	NUM
eurjchem-385	141	12	)	)	PUNCT
eurjchem-385	141	13	in	in	ADP
eurjchem-385	141	14	the	the	DET
eurjchem-385	141	15	equation	equation	NOUN
eurjchem-385	141	16	k’=k3	k’=k3	PROPN
eurjchem-385	141	17	/	/	SYM
eurjchem-385	141	18	k‐2	k‐2	PROPN
eurjchem-385	141	19	h	h	NOUN
eurjchem-385	142	1	h	h	NOUN
eurjchem-385	142	2	h	h	NOUN
eurjchem-385	143	1	k	k	PROPN
eurjchem-385	144	1	k	k	PROPN
eurjchem-385	144	2	k	k	PROPN
eurjchem-385	144	3	k	k	PROPN
eurjchem-385	144	4	k	k	PROPN
eurjchem-385	144	5	k	k	PROPN
eurjchem-385	144	6	k	k	PROPN
eurjchem-385	144	7	k	k	PROPN
eurjchem-385	144	8	k	k	PROPN
eurjchem-385	144	9	k	k	PROPN
eurjchem-385	144	10	‐	‐	PROPN
eurjchem-385	144	11	‐	‐	PUNCT
eurjchem-385	144	12	obs	obs	NOUN
eurjchem-385	144	13	2	2	NUM
eurjchem-385	144	14	2	2	NUM
eurjchem-385	144	15	2	2	NUM
eurjchem-385	144	16	1	1	NUM
eurjchem-385	144	17	1	1	NUM
eurjchem-385	144	18	+	+	NUM
eurjchem-385	144	19	'	'	PUNCT
eurjchem-385	145	1	[	[	X
eurjchem-385	145	2	oh	oh	INTJ
eurjchem-385	145	3	]	]	X
eurjchem-385	145	4	1	1	NUM
eurjchem-385	146	1	[	[	X
eurjchem-385	146	2	oh	oh	INTJ
eurjchem-385	146	3	]	]	X
eurjchem-385	146	4	=	=	PUNCT
eurjchem-385	147	1	=	=	PUNCT
eurjchem-385	147	2	+	+	NUM
eurjchem-385	147	3	'	'	PUNCT
eurjchem-385	147	4	[	[	X
eurjchem-385	147	5	r	r	X
eurjchem-385	147	6	]	]	PUNCT
eurjchem-385	147	7	'	'	PUNCT
eurjchem-385	147	8	[	[	X
eurjchem-385	147	9	r	r	X
eurjchem-385	147	10	]	]	X
eurjchem-385	147	11	[	[	X
eurjchem-385	147	12	r	r	X
eurjchem-385	147	13	]	]	X
eurjchem-385	147	14	(	(	PUNCT
eurjchem-385	147	15	19	19	NUM
eurjchem-385	147	16	)	)	PUNCT
eurjchem-385	147	17	these	these	DET
eurjchem-385	147	18	equations	equation	NOUN
eurjchem-385	147	19	indicate	indicate	VERB
eurjchem-385	147	20	that	that	SCONJ
eurjchem-385	147	21	the	the	DET
eurjchem-385	147	22	reaction	reaction	NOUN
eurjchem-385	147	23	should	should	AUX
eurjchem-385	147	24	be	be	AUX
eurjchem-385	147	25	first	first	ADJ
eurjchem-385	147	26	order	order	NOUN
eurjchem-385	147	27	both	both	CCONJ
eurjchem-385	147	28	with	with	ADP
eurjchem-385	147	29	respect	respect	NOUN
eurjchem-385	147	30	to	to	ADP
eurjchem-385	147	31	fe(vi	fe(vi	NOUN
eurjchem-385	147	32	)	)	PUNCT
eurjchem-385	147	33	and	and	CCONJ
eurjchem-385	147	34	reductant	reductant	NOUN
eurjchem-385	147	35	.	.	PUNCT
eurjchem-385	148	1	the	the	DET
eurjchem-385	148	2	plot	plot	NOUN
eurjchem-385	148	3	of	of	ADP
eurjchem-385	148	4	1	1	NUM
eurjchem-385	148	5	/	/	SYM
eurjchem-385	148	6	kobs	kobs	X
eurjchem-385	148	7	versus	versus	ADP
eurjchem-385	148	8	[	[	X
eurjchem-385	148	9	oh‐	oh‐	X
eurjchem-385	148	10	]	]	PUNCT
eurjchem-385	148	11	derives	derive	VERB
eurjchem-385	148	12	from	from	ADP
eurjchem-385	148	13	equation	equation	NOUN
eurjchem-385	148	14	(	(	PUNCT
eurjchem-385	148	15	19	19	NUM
eurjchem-385	148	16	)	)	PUNCT
eurjchem-385	148	17	at	at	ADP
eurjchem-385	148	18	constant	constant	ADJ
eurjchem-385	148	19	[	[	X
eurjchem-385	148	20	r	r	X
eurjchem-385	148	21	]	]	X
eurjchem-385	148	22	is	be	AUX
eurjchem-385	148	23	linear	linear	ADJ
eurjchem-385	148	24	with	with	ADP
eurjchem-385	148	25	positive	positive	ADJ
eurjchem-385	148	26	intercept	intercept	NOUN
eurjchem-385	148	27	.	.	PUNCT
eurjchem-385	149	1	these	these	PRON
eurjchem-385	149	2	are	be	AUX
eurjchem-385	149	3	consistent	consistent	ADJ
eurjchem-385	149	4	with	with	ADP
eurjchem-385	149	5	the	the	DET
eurjchem-385	149	6	experimental	experimental	ADJ
eurjchem-385	149	7	phenomena	phenomenon	NOUN
eurjchem-385	149	8	.	.	PUNCT
eurjchem-385	150	1	as	as	SCONJ
eurjchem-385	150	2	the	the	DET
eurjchem-385	150	3	plots	plot	NOUN
eurjchem-385	150	4	of	of	ADP
eurjchem-385	150	5	1/	1/	NUM
eurjchem-385	150	6	kobs	kob	NOUN
eurjchem-385	150	7	versus	versus	ADP
eurjchem-385	150	8	[	[	X
eurjchem-385	150	9	oh‐	oh‐	X
eurjchem-385	150	10	]	]	PUNCT
eurjchem-385	150	11	were	be	AUX
eurjchem-385	150	12	shown	show	VERB
eurjchem-385	150	13	in	in	ADP
eurjchem-385	150	14	figure	figure	NOUN
eurjchem-385	150	15	5	5	NUM
eurjchem-385	150	16	and	and	CCONJ
eurjchem-385	150	17	6	6	NUM
eurjchem-385	150	18	,	,	PUNCT
eurjchem-385	150	19	the	the	DET
eurjchem-385	150	20	rate‐determining	rate‐determining	NOUN
eurjchem-385	150	21	step	step	NOUN
eurjchem-385	150	22	rate	rate	NOUN
eurjchem-385	150	23	constants	constant	NOUN
eurjchem-385	150	24	(	(	PUNCT
eurjchem-385	150	25	k2	k2	NOUN
eurjchem-385	150	26	)	)	PUNCT
eurjchem-385	150	27	could	could	AUX
eurjchem-385	150	28	be	be	AUX
eurjchem-385	150	29	evaluated	evaluate	VERB
eurjchem-385	150	30	,	,	PUNCT
eurjchem-385	150	31	and	and	CCONJ
eurjchem-385	150	32	the	the	DET
eurjchem-385	150	33	thermodynamic	thermodynamic	ADJ
eurjchem-385	150	34	activation	activation	NOUN
eurjchem-385	150	35	parameters	parameter	NOUN
eurjchem-385	150	36	were	be	AUX
eurjchem-385	150	37	obtained	obtain	VERB
eurjchem-385	150	38	(	(	PUNCT
eurjchem-385	150	39	table	table	NOUN
eurjchem-385	150	40	1	1	NUM
eurjchem-385	150	41	)	)	PUNCT
eurjchem-385	151	1	[	[	X
eurjchem-385	151	2	22	22	NUM
eurjchem-385	151	3	]	]	PUNCT
eurjchem-385	151	4	with	with	ADP
eurjchem-385	151	5	the	the	DET
eurjchem-385	151	6	help	help	NOUN
eurjchem-385	151	7	of	of	ADP
eurjchem-385	151	8	their	their	PRON
eurjchem-385	151	9	slopes	slope	NOUN
eurjchem-385	151	10	and	and	CCONJ
eurjchem-385	151	11	equation	equation	NOUN
eurjchem-385	151	12	(	(	PUNCT
eurjchem-385	151	13	19	19	NUM
eurjchem-385	151	14	)	)	PUNCT
eurjchem-385	151	15	.	.	PUNCT
eurjchem-385	152	1	meanwhile	meanwhile	ADV
eurjchem-385	152	2	,	,	PUNCT
eurjchem-385	152	3	with	with	ADP
eurjchem-385	152	4	the	the	DET
eurjchem-385	152	5	help	help	NOUN
eurjchem-385	152	6	of	of	ADP
eurjchem-385	152	7	equation	equation	NOUN
eurjchem-385	152	8	(	(	PUNCT
eurjchem-385	152	9	19	19	NUM
eurjchem-385	152	10	)	)	PUNCT
eurjchem-385	152	11	,	,	PUNCT
eurjchem-385	152	12	the	the	DET
eurjchem-385	152	13	values	value	NOUN
eurjchem-385	152	14	of	of	ADP
eurjchem-385	152	15	k	k	NOUN
eurjchem-385	152	16	’	'	PUNCT
eurjchem-385	152	17	under	under	ADP
eurjchem-385	152	18	corresponding	correspond	VERB
eurjchem-385	152	19	temperature	temperature	NOUN
eurjchem-385	152	20	could	could	AUX
eurjchem-385	152	21	be	be	AUX
eurjchem-385	152	22	calculated	calculate	VERB
eurjchem-385	152	23	using	use	VERB
eurjchem-385	152	24	the	the	DET
eurjchem-385	152	25	slopes	slope	NOUN
eurjchem-385	152	26	and	and	CCONJ
eurjchem-385	152	27	intercepts	intercept	NOUN
eurjchem-385	152	28	of	of	ADP
eurjchem-385	152	29	figure	figure	NOUN
eurjchem-385	152	30	5	5	NUM
eurjchem-385	152	31	and	and	CCONJ
eurjchem-385	152	32	6	6	NUM
eurjchem-385	152	33	.	.	PUNCT
eurjchem-385	153	1	then	then	ADV
eurjchem-385	153	2	,	,	PUNCT
eurjchem-385	153	3	substituting	substitute	VERB
eurjchem-385	153	4	k	k	NOUN
eurjchem-385	153	5	’	'	PUNCT
eurjchem-385	153	6	,	,	PUNCT
eurjchem-385	153	7	k2	k2	PROPN
eurjchem-385	153	8	and	and	CCONJ
eurjchem-385	153	9	[	[	X
eurjchem-385	153	10	oh‐	oh‐	X
eurjchem-385	153	11	]	]	PUNCT
eurjchem-385	153	12	into	into	ADP
eurjchem-385	153	13	equation	equation	NOUN
eurjchem-385	153	14	(	(	PUNCT
eurjchem-385	153	15	18	18	NUM
eurjchem-385	153	16	)	)	PUNCT
eurjchem-385	153	17	,	,	PUNCT
eurjchem-385	153	18	we	we	PRON
eurjchem-385	153	19	can	can	AUX
eurjchem-385	153	20	calculate	calculate	VERB
eurjchem-385	153	21	the	the	DET
eurjchem-385	153	22	rate	rate	NOUN
eurjchem-385	153	23	constants	constant	NOUN
eurjchem-385	153	24	under	under	ADP
eurjchem-385	153	25	corresponding	correspond	VERB
eurjchem-385	153	26	[	[	X
eurjchem-385	153	27	r	r	X
eurjchem-385	153	28	]	]	X
eurjchem-385	153	29	,	,	PUNCT
eurjchem-385	153	30	which	which	PRON
eurjchem-385	153	31	are	be	AUX
eurjchem-385	153	32	very	very	ADV
eurjchem-385	153	33	close	close	ADJ
eurjchem-385	153	34	to	to	ADP
eurjchem-385	153	35	the	the	DET
eurjchem-385	153	36	experimental	experimental	ADJ
eurjchem-385	153	37	values	value	NOUN
eurjchem-385	153	38	(	(	PUNCT
eurjchem-385	153	39	table	table	NOUN
eurjchem-385	153	40	2	2	NUM
eurjchem-385	153	41	and	and	CCONJ
eurjchem-385	153	42	3	3	NUM
eurjchem-385	153	43	)	)	PUNCT
eurjchem-385	153	44	.	.	PUNCT
eurjchem-385	154	1	this	this	PRON
eurjchem-385	154	2	illustrates	illustrate	VERB
eurjchem-385	154	3	that	that	SCONJ
eurjchem-385	154	4	the	the	DET
eurjchem-385	154	5	equation	equation	NOUN
eurjchem-385	154	6	(	(	PUNCT
eurjchem-385	154	7	19	19	NUM
eurjchem-385	154	8	)	)	PUNCT
eurjchem-385	154	9	is	be	AUX
eurjchem-385	154	10	correct	correct	ADJ
eurjchem-385	154	11	and	and	CCONJ
eurjchem-385	154	12	the	the	DET
eurjchem-385	154	13	reaction	reaction	NOUN
eurjchem-385	154	14	mechanism	mechanism	NOUN
eurjchem-385	154	15	we	we	PRON
eurjchem-385	154	16	proposed	propose	VERB
eurjchem-385	154	17	is	be	AUX
eurjchem-385	154	18	reasonable	reasonable	ADJ
eurjchem-385	154	19	.	.	PUNCT
eurjchem-385	155	1	346	346	NUM
eurjchem-385	155	2	shan	shan	NOUN
eurjchem-385	155	3	et	et	PROPN
eurjchem-385	155	4	al	al	PROPN
eurjchem-385	155	5	.	.	PUNCT
eurjchem-385	155	6	/	/	SYM
eurjchem-385	155	7	european	european	PROPN
eurjchem-385	155	8	journal	journal	PROPN
eurjchem-385	155	9	of	of	ADP
eurjchem-385	155	10	chemistry	chemistry	NOUN
eurjchem-385	155	11	2	2	NUM
eurjchem-385	155	12	(	(	PUNCT
eurjchem-385	155	13	3	3	NUM
eurjchem-385	155	14	)	)	PUNCT
eurjchem-385	155	15	(	(	PUNCT
eurjchem-385	155	16	2011	2011	NUM
eurjchem-385	155	17	)	)	PUNCT
eurjchem-385	155	18	342‐346	342‐346	NUM
eurjchem-385	155	19	4	4	NUM
eurjchem-385	155	20	.	.	X
eurjchem-385	155	21	conclusion	conclusion	VERB
eurjchem-385	155	22	the	the	DET
eurjchem-385	155	23	discussion	discussion	NOUN
eurjchem-385	155	24	and	and	CCONJ
eurjchem-385	155	25	results	result	NOUN
eurjchem-385	155	26	presented	present	VERB
eurjchem-385	155	27	in	in	ADP
eurjchem-385	155	28	this	this	DET
eurjchem-385	155	29	paper	paper	NOUN
eurjchem-385	155	30	demonstrate	demonstrate	VERB
eurjchem-385	155	31	that	that	SCONJ
eurjchem-385	155	32	the	the	DET
eurjchem-385	155	33	reaction	reaction	NOUN
eurjchem-385	155	34	of	of	ADP
eurjchem-385	155	35	potassium	potassium	NOUN
eurjchem-385	155	36	ferrate	ferrate	NOUN
eurjchem-385	155	37	with	with	ADP
eurjchem-385	155	38	n‐butylamine	n‐butylamine	NUM
eurjchem-385	155	39	and	and	CCONJ
eurjchem-385	155	40	1,3‐propanediamine	1,3‐propanediamine	NUM
eurjchem-385	155	41	both	both	PRON
eurjchem-385	155	42	take	take	VERB
eurjchem-385	155	43	place	place	NOUN
eurjchem-385	155	44	by	by	ADP
eurjchem-385	155	45	two‐	two‐	PROPN
eurjchem-385	155	46	electron	electron	NOUN
eurjchem-385	155	47	transfer	transfer	NOUN
eurjchem-385	155	48	.	.	PUNCT
eurjchem-385	156	1	first	first	ADV
eurjchem-385	156	2	,	,	PUNCT
eurjchem-385	156	3	fe(vi	fe(vi	ADJ
eurjchem-385	156	4	)	)	PUNCT
eurjchem-385	156	5	reacts	react	VERB
eurjchem-385	156	6	with	with	ADP
eurjchem-385	156	7	a	a	DET
eurjchem-385	156	8	molecule	molecule	NOUN
eurjchem-385	156	9	of	of	ADP
eurjchem-385	156	10	reductant	reductant	NOUN
eurjchem-385	156	11	to	to	PART
eurjchem-385	156	12	form	form	VERB
eurjchem-385	156	13	fe(iv	fe(iv	NOUN
eurjchem-385	156	14	)	)	PUNCT
eurjchem-385	156	15	and	and	CCONJ
eurjchem-385	156	16	product	product	NOUN
eurjchem-385	156	17	,	,	PUNCT
eurjchem-385	156	18	then	then	ADV
eurjchem-385	156	19	fe(iv	fe(iv	NOUN
eurjchem-385	156	20	)	)	PUNCT
eurjchem-385	156	21	with	with	ADP
eurjchem-385	156	22	another	another	DET
eurjchem-385	156	23	molecule	molecule	NOUN
eurjchem-385	156	24	of	of	ADP
eurjchem-385	156	25	reductant	reductant	NOUN
eurjchem-385	156	26	react	react	VERB
eurjchem-385	156	27	further	far	ADV
eurjchem-385	156	28	to	to	PART
eurjchem-385	156	29	generate	generate	VERB
eurjchem-385	156	30	fe(ii	fe(ii	PROPN
eurjchem-385	156	31	)	)	PUNCT
eurjchem-385	156	32	and	and	CCONJ
eurjchem-385	156	33	product	product	NOUN
eurjchem-385	156	34	.	.	PUNCT
eurjchem-385	157	1	at	at	ADP
eurjchem-385	157	2	last	last	ADJ
eurjchem-385	157	3	,	,	PUNCT
eurjchem-385	157	4	fe(iv	fe(iv	NOUN
eurjchem-385	157	5	)	)	PUNCT
eurjchem-385	157	6	reacts	react	VERB
eurjchem-385	157	7	with	with	ADP
eurjchem-385	157	8	fe(ii	fe(ii	PROPN
eurjchem-385	157	9	)	)	PUNCT
eurjchem-385	157	10	to	to	PART
eurjchem-385	157	11	generate	generate	VERB
eurjchem-385	157	12	fe(iii	fe(iii	NOUN
eurjchem-385	157	13	)	)	PUNCT
eurjchem-385	157	14	.	.	PUNCT
eurjchem-385	158	1	the	the	DET
eurjchem-385	158	2	results	result	NOUN
eurjchem-385	158	3	show	show	VERB
eurjchem-385	158	4	first	first	ADJ
eurjchem-385	158	5	order	order	NOUN
eurjchem-385	158	6	dependence	dependence	NOUN
eurjchem-385	158	7	on	on	ADP
eurjchem-385	158	8	potassium	potassium	NOUN
eurjchem-385	158	9	ferrate	ferrate	NOUN
eurjchem-385	158	10	(	(	PUNCT
eurjchem-385	158	11	vi	vi	NOUN
eurjchem-385	158	12	)	)	PUNCT
eurjchem-385	158	13	and	and	CCONJ
eurjchem-385	158	14	on	on	ADP
eurjchem-385	158	15	each	each	DET
eurjchem-385	158	16	reductant	reductant	NOUN
eurjchem-385	158	17	and	and	CCONJ
eurjchem-385	158	18	the	the	DET
eurjchem-385	158	19	reaction	reaction	NOUN
eurjchem-385	158	20	is	be	AUX
eurjchem-385	158	21	negative	negative	ADJ
eurjchem-385	158	22	fraction	fraction	NOUN
eurjchem-385	158	23	order	order	NOUN
eurjchem-385	158	24	with	with	ADP
eurjchem-385	158	25	respect	respect	NOUN
eurjchem-385	158	26	to	to	ADP
eurjchem-385	158	27	[	[	X
eurjchem-385	158	28	oh‐	oh‐	ADV
eurjchem-385	158	29	]	]	PUNCT
eurjchem-385	158	30	.	.	PUNCT
eurjchem-385	159	1	at	at	ADP
eurjchem-385	159	2	the	the	DET
eurjchem-385	159	3	same	same	ADJ
eurjchem-385	159	4	time	time	NOUN
eurjchem-385	159	5	we	we	PRON
eurjchem-385	159	6	also	also	ADV
eurjchem-385	159	7	observed	observe	VERB
eurjchem-385	159	8	the	the	DET
eurjchem-385	159	9	rate	rate	NOUN
eurjchem-385	159	10	of	of	ADP
eurjchem-385	159	11	the	the	DET
eurjchem-385	159	12	rate‐determining	rate‐determining	NOUN
eurjchem-385	159	13	step	step	NOUN
eurjchem-385	159	14	of	of	ADP
eurjchem-385	159	15	1,3‐propanediamine	1,3‐propanediamine	NUM
eurjchem-385	159	16	is	be	AUX
eurjchem-385	159	17	quicker	quick	ADJ
eurjchem-385	159	18	than	than	ADP
eurjchem-385	159	19	that	that	PRON
eurjchem-385	159	20	of	of	ADP
eurjchem-385	159	21	n‐butylamine	n‐butylamine	NUM
eurjchem-385	159	22	,	,	PUNCT
eurjchem-385	159	23	and	and	CCONJ
eurjchem-385	159	24	the	the	DET
eurjchem-385	159	25	rate	rate	NOUN
eurjchem-385	159	26	constants	constant	NOUN
eurjchem-385	159	27	of	of	ADP
eurjchem-385	159	28	the	the	DET
eurjchem-385	159	29	rate‐determining	rate‐determining	NOUN
eurjchem-385	159	30	step	step	NOUN
eurjchem-385	159	31	for	for	ADP
eurjchem-385	159	32	1,3‐propanediamine	1,3‐propanediamine	NUM
eurjchem-385	159	33	is	be	AUX
eurjchem-385	159	34	larger	large	ADJ
eurjchem-385	159	35	than	than	ADP
eurjchem-385	159	36	those	those	PRON
eurjchem-385	159	37	for	for	ADP
eurjchem-385	159	38	n‐butylamine	n‐butylamine	NUM
eurjchem-385	159	39	.	.	PUNCT
eurjchem-385	160	1	the	the	DET
eurjchem-385	160	2	activation	activation	NOUN
eurjchem-385	160	3	energy	energy	NOUN
eurjchem-385	160	4	of	of	ADP
eurjchem-385	160	5	1,3‐propane‐	1,3‐propane‐	NUM
eurjchem-385	160	6	diamine	diamine	NOUN
eurjchem-385	160	7	is	be	AUX
eurjchem-385	160	8	larger	large	ADJ
eurjchem-385	160	9	than	than	ADP
eurjchem-385	160	10	n‐butylamine	n‐butylamine	PUNCT
eurjchem-385	160	11	.	.	PUNCT
eurjchem-385	161	1	the	the	DET
eurjchem-385	161	2	reason	reason	NOUN
eurjchem-385	161	3	for	for	ADP
eurjchem-385	161	4	this	this	PRON
eurjchem-385	161	5	should	should	AUX
eurjchem-385	161	6	be	be	AUX
eurjchem-385	161	7	that	that	SCONJ
eurjchem-385	161	8	the	the	DET
eurjchem-385	161	9	reaction	reaction	NOUN
eurjchem-385	161	10	between	between	ADP
eurjchem-385	161	11	1,3‐propanediamine	1,3‐propanediamine	NUM
eurjchem-385	161	12	and	and	CCONJ
eurjchem-385	161	13	fe(vi	fe(vi	PROPN
eurjchem-385	161	14	)	)	PUNCT
eurjchem-385	161	15	are	be	AUX
eurjchem-385	161	16	simultaneous	simultaneous	ADJ
eurjchem-385	161	17	on	on	ADP
eurjchem-385	161	18	both	both	DET
eurjchem-385	161	19	amino	amino	ADJ
eurjchem-385	161	20	groups	group	NOUN
eurjchem-385	161	21	,	,	PUNCT
eurjchem-385	161	22	there	there	PRON
eurjchem-385	161	23	is	be	VERB
eurjchem-385	161	24	more	more	ADJ
eurjchem-385	161	25	resistance	resistance	NOUN
eurjchem-385	161	26	.	.	PUNCT
eurjchem-385	162	1	the	the	DET
eurjchem-385	162	2	activation	activation	NOUN
eurjchem-385	162	3	parameters	parameter	NOUN
eurjchem-385	162	4	are	be	AUX
eurjchem-385	162	5	all	all	ADV
eurjchem-385	162	6	in	in	ADP
eurjchem-385	162	7	support	support	NOUN
eurjchem-385	162	8	of	of	ADP
eurjchem-385	162	9	the	the	DET
eurjchem-385	162	10	mechanism	mechanism	NOUN
eurjchem-385	162	11	and	and	CCONJ
eurjchem-385	162	12	consistent	consistent	ADJ
eurjchem-385	162	13	with	with	ADP
eurjchem-385	162	14	experimental	experimental	ADJ
eurjchem-385	162	15	phenomena	phenomenon	NOUN
eurjchem-385	162	16	.	.	PUNCT
eurjchem-385	163	1	acknowledgement	acknowledgement	NOUN
eurjchem-385	163	2	thanks	thank	NOUN
eurjchem-385	163	3	for	for	ADP
eurjchem-385	163	4	the	the	DET
eurjchem-385	163	5	supply	supply	NOUN
eurjchem-385	163	6	of	of	ADP
eurjchem-385	163	7	equipments	equipment	NOUN
eurjchem-385	163	8	and	and	CCONJ
eurjchem-385	163	9	reagents	reagent	NOUN
eurjchem-385	163	10	demanded	demand	VERB
eurjchem-385	163	11	in	in	ADP
eurjchem-385	163	12	this	this	DET
eurjchem-385	163	13	experiment	experiment	NOUN
eurjchem-385	163	14	by	by	ADP
eurjchem-385	163	15	hebei	hebei	PROPN
eurjchem-385	163	16	university	university	PROPN
eurjchem-385	163	17	.	.	PUNCT
eurjchem-385	164	1	references	reference	NOUN
eurjchem-385	164	2	[	[	X
eurjchem-385	164	3	1	1	NUM
eurjchem-385	164	4	]	]	PUNCT
eurjchem-385	164	5	.	.	PUNCT
eurjchem-385	165	1	jiang	jiang	PROPN
eurjchem-385	165	2	,	,	PUNCT
eurjchem-385	165	3	j.	j.	PROPN
eurjchem-385	165	4	q.	q.	PROPN
eurjchem-385	165	5	;	;	PUNCT
eurjchem-385	165	6	lloyd	lloyd	PROPN
eurjchem-385	165	7	,	,	PUNCT
eurjchem-385	165	8	b.	b.	PROPN
eurjchem-385	165	9	water	water	PROPN
eurjchem-385	165	10	res	re	NOUN
eurjchem-385	165	11	.	.	PUNCT
eurjchem-385	165	12	2002	2002	NUM
eurjchem-385	165	13	,	,	PUNCT
eurjchem-385	165	14	36	36	NUM
eurjchem-385	165	15	,	,	PUNCT
eurjchem-385	165	16	1397‐1408	1397‐1408	NUM
eurjchem-385	165	17	.	.	PUNCT
eurjchem-385	166	1	[	[	X
eurjchem-385	166	2	2	2	NUM
eurjchem-385	166	3	]	]	PUNCT
eurjchem-385	166	4	.	.	PUNCT
eurjchem-385	167	1	jiang	jiang	PROPN
eurjchem-385	167	2	,	,	PUNCT
eurjchem-385	167	3	j.	j.	PROPN
eurjchem-385	167	4	q.	q.	PROPN
eurjchem-385	167	5	;	;	PUNCT
eurjchem-385	167	6	alex	alex	PROPN
eurjchem-385	167	7	,	,	PUNCT
eurjchem-385	167	8	p.	p.	PROPN
eurjchem-385	167	9	;	;	PUNCT
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eurjchem-385	167	11	b.	b.	PROPN
eurjchem-385	167	12	j.	j.	PROPN
eurjchem-385	167	13	eniron	eniron	PROPN
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eurjchem-385	168	1	managem	managem	PROPN
eurjchem-385	168	2	.	.	PUNCT
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eurjchem-385	169	2	,	,	PUNCT
eurjchem-385	169	3	79(2	79(2	NUM
eurjchem-385	169	4	)	)	PUNCT
eurjchem-385	169	5	,	,	PUNCT
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eurjchem-385	169	7	.	.	PUNCT
eurjchem-385	170	1	[	[	X
eurjchem-385	170	2	3	3	NUM
eurjchem-385	170	3	]	]	PUNCT
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eurjchem-385	171	3	c.	c.	PROPN
eurjchem-385	171	4	;	;	PUNCT
eurjchem-385	171	5	li	li	PROPN
eurjchem-385	171	6	,	,	PUNCT
eurjchem-385	171	7	x.	x.	PROPN
eurjchem-385	171	8	z.	z.	PROPN
eurjchem-385	171	9	;	;	PUNCT
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eurjchem-385	171	11	n.	n.	PROPN
eurjchem-385	171	12	water	water	PROPN
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eurjchem-385	171	14	.	.	PUNCT
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eurjchem-385	171	16	,	,	PUNCT
eurjchem-385	171	17	42(1‐2	42(1‐2	NUM
eurjchem-385	171	18	)	)	PUNCT
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eurjchem-385	172	1	[	[	X
eurjchem-385	172	2	4	4	NUM
eurjchem-385	172	3	]	]	PUNCT
eurjchem-385	172	4	.	.	PUNCT
eurjchem-385	173	1	zhang	zhang	PROPN
eurjchem-385	173	2	,	,	PUNCT
eurjchem-385	173	3	j.	j.	PROPN
eurjchem-385	173	4	;	;	PUNCT
eurjchem-385	173	5	shi	shi	PROPN
eurjchem-385	173	6	,	,	PUNCT
eurjchem-385	173	7	q.	q.	PROPN
eurjchem-385	173	8	l.	l.	PROPN
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eurjchem-385	173	12	g.	g.	PROPN
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eurjchem-385	173	16	prot	prot	PROPN
eurjchem-385	173	17	.	.	PUNCT
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eurjchem-385	177	1	[	[	X
eurjchem-385	177	2	5	5	NUM
eurjchem-385	177	3	]	]	PUNCT
eurjchem-385	177	4	.	.	PUNCT
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eurjchem-385	178	2	,	,	PUNCT
eurjchem-385	178	3	v.	v.	PROPN
eurjchem-385	178	4	k.	k.	PROPN
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eurjchem-385	178	8	c.	c.	PROPN
eurjchem-385	178	9	r.	r.	PROPN
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eurjchem-385	178	13	r.	r.	PROPN
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eurjchem-385	179	7	39(10	39(10	NUM
eurjchem-385	179	8	)	)	PUNCT
eurjchem-385	179	9	,	,	PUNCT
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eurjchem-385	179	11	.	.	PUNCT
eurjchem-385	180	1	[	[	X
eurjchem-385	180	2	6	6	NUM
eurjchem-385	180	3	]	]	PUNCT
eurjchem-385	180	4	.	.	PUNCT
eurjchem-385	181	1	sharma	sharma	PROPN
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eurjchem-385	182	2	.	.	PUNCT
eurjchem-385	183	1	res	re	NOUN
eurjchem-385	183	2	.	.	PROPN
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eurjchem-385	183	6	)	)	PUNCT
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eurjchem-385	184	2	7	7	NUM
eurjchem-385	184	3	]	]	PUNCT
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eurjchem-385	184	7	v.	v.	PROPN
eurjchem-385	184	8	k.	k.	PROPN
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eurjchem-385	184	13	o.	o.	PROPN
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eurjchem-385	184	18	j.	j.	PROPN
eurjchem-385	184	19	environ	environ	PROPN
eurjchem-385	184	20	.	.	PUNCT
eurjchem-385	185	1	sci	sci	PROPN
eurjchem-385	185	2	.	.	PROPN
eurjchem-385	185	3	technol	technol	PROPN
eurjchem-385	185	4	.	.	PROPN
eurjchem-385	185	5	1997	1997	NUM
eurjchem-385	185	6	,	,	PUNCT
eurjchem-385	185	7	31	31	NUM
eurjchem-385	185	8	,	,	PUNCT
eurjchem-385	185	9	2486‐2491	2486‐2491	NUM
eurjchem-385	185	10	.	.	PUNCT
eurjchem-385	186	1	[	[	X
eurjchem-385	186	2	8	8	NUM
eurjchem-385	186	3	]	]	PUNCT
eurjchem-385	186	4	.	.	PUNCT
eurjchem-385	187	1	james	james	PROPN
eurjchem-385	187	2	,	,	PUNCT
eurjchem-385	187	3	d.	d.	PROPN
eurjchem-385	187	4	c.	c.	PROPN
eurjchem-385	187	5	environ	environ	PROPN
eurjchem-385	187	6	.	.	PUNCT
eurjchem-385	188	1	sci	sci	PROPN
eurjchem-385	188	2	.	.	PROPN
eurjchem-385	188	3	technol	technol	PROPN
eurjchem-385	188	4	.	.	PROPN
eurjchem-385	188	5	1981	1981	NUM
eurjchem-385	188	6	,	,	PUNCT
eurjchem-385	188	7	15	15	NUM
eurjchem-385	188	8	,	,	PUNCT
eurjchem-385	188	9	184‐187	184‐187	NUM
eurjchem-385	188	10	.	.	PUNCT
eurjchem-385	189	1	[	[	X
eurjchem-385	189	2	9	9	NUM
eurjchem-385	189	3	]	]	PUNCT
eurjchem-385	189	4	.	.	PUNCT
eurjchem-385	190	1	james	james	PROPN
eurjchem-385	190	2	,	,	PUNCT
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eurjchem-385	190	4	c.	c.	PROPN
eurjchem-385	190	5	trans	trans	PROPN
eurjchem-385	190	6	.	.	PUNCT
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eurjchem-385	190	9	.	.	PUNCT
eurjchem-385	191	1	1986	1986	NUM
eurjchem-385	191	2	,	,	PUNCT
eurjchem-385	191	3	11	11	NUM
eurjchem-385	191	4	,	,	PUNCT
eurjchem-385	191	5	116‐117	116‐117	NUM
eurjchem-385	191	6	.	.	PUNCT
eurjchem-385	192	1	[	[	X
eurjchem-385	192	2	10	10	NUM
eurjchem-385	192	3	]	]	PUNCT
eurjchem-385	192	4	.	.	PUNCT
eurjchem-385	193	1	james	james	PROPN
eurjchem-385	193	2	,	,	PUNCT
eurjchem-385	193	3	d.	d.	PROPN
eurjchem-385	193	4	c.	c.	PROPN
eurjchem-385	193	5	;	;	PUNCT
eurjchem-385	193	6	kelter	kelter	PROPN
eurjchem-385	193	7	,	,	PUNCT
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eurjchem-385	193	11	.	.	PUNCT
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eurjchem-385	193	13	.	.	PUNCT
eurjchem-385	194	1	1979	1979	NUM
eurjchem-385	194	2	,	,	PUNCT
eurjchem-385	194	3	51(11	51(11	NUM
eurjchem-385	194	4	)	)	PUNCT
eurjchem-385	194	5	,	,	PUNCT
eurjchem-385	194	6	1828‐1834	1828‐1834	NUM
eurjchem-385	194	7	.	.	PUNCT
eurjchem-385	195	1	[	[	X
eurjchem-385	195	2	11	11	NUM
eurjchem-385	195	3	]	]	PUNCT
eurjchem-385	195	4	.	.	PUNCT
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eurjchem-385	195	6	,	,	PUNCT
eurjchem-385	195	7	h.	h.	PROPN
eurjchem-385	195	8	;	;	PUNCT
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eurjchem-385	195	10	,	,	PUNCT
eurjchem-385	195	11	r.	r.	PROPN
eurjchem-385	195	12	k.	k.	PROPN
eurjchem-385	195	13	j.	j.	PROPN
eurjchem-385	195	14	am	am	PROPN
eurjchem-385	195	15	.	.	PUNCT
eurjchem-385	196	1	chem	chem	PROPN
eurjchem-385	196	2	.	.	PUNCT
eurjchem-385	197	1	soc	soc	PROPN
eurjchem-385	197	2	.	.	PUNCT
eurjchem-385	198	1	1971	1971	NUM
eurjchem-385	198	2	,	,	PUNCT
eurjchem-385	198	3	93	93	NUM
eurjchem-385	198	4	,	,	PUNCT
eurjchem-385	198	5	6058‐6065	6058‐6065	NOUN
eurjchem-385	198	6	.	.	PUNCT
eurjchem-385	199	1	[	[	X
eurjchem-385	199	2	12	12	NUM
eurjchem-385	199	3	]	]	PUNCT
eurjchem-385	199	4	.	.	PUNCT
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eurjchem-385	200	2	,	,	PUNCT
eurjchem-385	200	3	b.	b.	PROPN
eurjchem-385	200	4	h.	h.	PROPN
eurjchem-385	200	5	j.	j.	PROPN
eurjchem-385	200	6	;	;	PUNCT
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eurjchem-385	200	8	,	,	PUNCT
eurjchem-385	200	9	v.	v.	PROPN
eurjchem-385	200	10	k.	k.	PROPN
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eurjchem-385	200	12	.	.	PUNCT
eurjchem-385	201	1	chem	chem	PROPN
eurjchem-385	201	2	.	.	PUNCT
eurjchem-385	202	1	1991	1991	NUM
eurjchem-385	202	2	,	,	PUNCT
eurjchem-385	202	3	30	30	NUM
eurjchem-385	202	4	,	,	PUNCT
eurjchem-385	202	5	4306‐4310	4306‐4310	NUM
eurjchem-385	202	6	.	.	PUNCT
eurjchem-385	203	1	[	[	X
eurjchem-385	203	2	13	13	NUM
eurjchem-385	203	3	]	]	PUNCT
eurjchem-385	203	4	.	.	PUNCT
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eurjchem-385	204	2	,	,	PUNCT
eurjchem-385	204	3	b.	b.	PROPN
eurjchem-385	204	4	h.	h.	PROPN
eurjchem-385	204	5	j.	j.	PROPN
eurjchem-385	204	6	;	;	PUNCT
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eurjchem-385	204	8	,	,	PUNCT
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eurjchem-385	204	14	.	.	PUNCT
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eurjchem-385	204	16	,	,	PUNCT
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eurjchem-385	204	18	,	,	PUNCT
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eurjchem-385	204	20	.	.	PUNCT
eurjchem-385	205	1	[	[	X
eurjchem-385	205	2	14	14	NUM
eurjchem-385	205	3	]	]	PUNCT
eurjchem-385	205	4	.	.	PUNCT
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eurjchem-385	206	2	,	,	PUNCT
eurjchem-385	206	3	m.	m.	PROPN
eurjchem-385	206	4	d.	d.	PROPN
eurjchem-385	206	5	;	;	PUNCT
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eurjchem-385	206	7	,	,	PUNCT
eurjchem-385	206	8	j.	j.	PROPN
eurjchem-385	206	9	f.	f.	PROPN
eurjchem-385	206	10	inorg	inorg	PROPN
eurjchem-385	206	11	.	.	PUNCT
eurjchem-385	207	1	chem	chem	PROPN
eurjchem-385	207	2	.	.	PUNCT
eurjchem-385	208	1	1996	1996	NUM
eurjchem-385	208	2	,	,	PUNCT
eurjchem-385	208	3	35	35	NUM
eurjchem-385	208	4	,	,	PUNCT
eurjchem-385	208	5	6795‐6799	6795‐6799	NUM
eurjchem-385	208	6	.	.	PUNCT
eurjchem-385	209	1	[	[	X
eurjchem-385	209	2	15	15	NUM
eurjchem-385	209	3	]	]	PUNCT
eurjchem-385	209	4	.	.	PUNCT
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eurjchem-385	210	2	,	,	PUNCT
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eurjchem-385	210	4	;	;	PUNCT
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eurjchem-385	210	6	,	,	PUNCT
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eurjchem-385	210	9	;	;	PUNCT
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eurjchem-385	210	11	,	,	PUNCT
eurjchem-385	210	12	l.	l.	PROPN
eurjchem-385	210	13	g.	g.	PROPN
eurjchem-385	210	14	;	;	PUNCT
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eurjchem-385	210	16	,	,	PUNCT
eurjchem-385	210	17	y.	y.	PROPN
eurjchem-385	210	18	;	;	PUNCT
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eurjchem-385	210	20	,	,	PUNCT
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eurjchem-385	210	22	j.	j.	PROPN
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eurjchem-385	210	24	.	.	PUNCT
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eurjchem-385	211	2	.	.	PUNCT
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eurjchem-385	212	2	.	.	PROPN
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eurjchem-385	212	4	,	,	PUNCT
eurjchem-385	212	5	15(4	15(4	NUM
eurjchem-385	212	6	)	)	PUNCT
eurjchem-385	212	7	,	,	PUNCT
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eurjchem-385	212	9	.	.	PUNCT
eurjchem-385	213	1	[	[	X
eurjchem-385	213	2	16	16	NUM
eurjchem-385	213	3	]	]	PUNCT
eurjchem-385	213	4	.	.	PUNCT
eurjchem-385	214	1	thompson	thompson	PROPN
eurjchem-385	214	2	,	,	PUNCT
eurjchem-385	214	3	g.	g.	PROPN
eurjchem-385	214	4	w.	w.	PROPN
eurjchem-385	214	5	;	;	PUNCT
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eurjchem-385	214	7	,	,	PUNCT
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eurjchem-385	214	10	;	;	PUNCT
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eurjchem-385	214	17	.	.	PUNCT
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eurjchem-385	215	2	.	.	PUNCT
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eurjchem-385	216	2	.	.	PUNCT
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eurjchem-385	217	2	,	,	PUNCT
eurjchem-385	217	3	73	73	NUM
eurjchem-385	217	4	,	,	PUNCT
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eurjchem-385	217	6	.	.	PUNCT
eurjchem-385	218	1	[	[	X
eurjchem-385	218	2	17	17	NUM
eurjchem-385	218	3	]	]	PUNCT
eurjchem-385	218	4	.	.	PUNCT
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eurjchem-385	218	30	.	.	PUNCT
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eurjchem-385	219	2	.	.	PUNCT
eurjchem-385	220	1	[	[	X
eurjchem-385	220	2	18	18	NUM
eurjchem-385	220	3	]	]	PUNCT
eurjchem-385	220	4	.	.	PUNCT
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eurjchem-385	221	2	,	,	PUNCT
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eurjchem-385	221	22	.	.	PUNCT
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eurjchem-385	222	2	.	.	PUNCT
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eurjchem-385	223	2	19	19	NUM
eurjchem-385	223	3	]	]	PUNCT
eurjchem-385	223	4	.	.	PUNCT
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eurjchem-385	224	2	,	,	PUNCT
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eurjchem-385	224	7	,	,	PUNCT
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eurjchem-385	224	20	,	,	PUNCT
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eurjchem-385	225	2	20	20	NUM
eurjchem-385	225	3	]	]	PUNCT
eurjchem-385	225	4	.	.	PUNCT
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eurjchem-385	226	2	,	,	PUNCT
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eurjchem-385	226	5	;	;	PUNCT
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eurjchem-385	226	22	;	;	PUNCT
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eurjchem-385	227	8	,	,	PUNCT
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eurjchem-385	227	10	.	.	PUNCT
eurjchem-385	228	1	[	[	X
eurjchem-385	228	2	21	21	NUM
eurjchem-385	228	3	]	]	PUNCT
eurjchem-385	228	4	.	.	PUNCT
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eurjchem-385	230	2	.	.	PUNCT
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eurjchem-385	231	2	,	,	PUNCT
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eurjchem-385	231	4	.	.	PUNCT
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eurjchem-385	232	3	]	]	PUNCT
eurjchem-385	232	4	.	.	PUNCT
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eurjchem-385	233	2	,	,	PUNCT
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eurjchem-385	233	7	,	,	PUNCT
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eurjchem-385	234	2	.	.	PROPN
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eurjchem-385	234	4	,	,	PUNCT
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