id	sid	tid	token	lemma	pos
eurjchem-405	1	1	untitled	untitle	VERB
eurjchem-405	1	2	european	european	PROPN
eurjchem-405	1	3	journal	journal	PROPN
eurjchem-405	1	4	of	of	ADP
eurjchem-405	1	5	chemistry	chemistry	NOUN
eurjchem-405	1	6	2	2	NUM
eurjchem-405	1	7	(	(	PUNCT
eurjchem-405	1	8	2	2	NUM
eurjchem-405	1	9	)	)	PUNCT
eurjchem-405	1	10	(	(	PUNCT
eurjchem-405	1	11	2011	2011	NUM
eurjchem-405	1	12	)	)	PUNCT
eurjchem-405	1	13	130‐135	130‐135	PROPN
eurjchem-405	1	14	european	european	PROPN
eurjchem-405	1	15	journal	journal	PROPN
eurjchem-405	1	16	of	of	ADP
eurjchem-405	1	17	chemistry	chemistry	NOUN
eurjchem-405	1	18	issn	issn	PROPN
eurjchem-405	1	19	2153‐2249	2153‐2249	PROPN
eurjchem-405	1	20	(	(	PUNCT
eurjchem-405	1	21	print	print	NOUN
eurjchem-405	1	22	)	)	PUNCT
eurjchem-405	1	23	/	/	SYM
eurjchem-405	1	24	issn	issn	PROPN
eurjchem-405	1	25	2153‐2257	2153‐2257	NUM
eurjchem-405	1	26	(	(	PUNCT
eurjchem-405	1	27	online	online	ADJ
eurjchem-405	1	28	)	)	PUNCT
eurjchem-405	1	29			NOUN
eurjchem-405	1	30	2011	2011	NUM
eurjchem-405	1	31	eurjchem	eurjchem	PROPN
eurjchem-405	1	32	doi:10.5155	doi:10.5155	PROPN
eurjchem-405	1	33	/	/	SYM
eurjchem-405	1	34	eurjchem.2.2.130‐135.405	eurjchem.2.2.130‐135.405	PROPN
eurjchem-405	1	35	european	european	ADJ
eurjchem-405	1	36	journal	journal	PROPN
eurjchem-405	1	37	of	of	ADP
eurjchem-405	1	38	chemistry	chemistry	PROPN
eurjchem-405	1	39	journal	journal	PROPN
eurjchem-405	1	40	homepage	homepage	NOUN
eurjchem-405	1	41	:	:	PUNCT
eurjchem-405	1	42	www.eurjchem.com	www.eurjchem.com	X
eurjchem-405	1	43	detailed	detail	VERB
eurjchem-405	1	44	analysis	analysis	NOUN
eurjchem-405	1	45	for	for	ADP
eurjchem-405	1	46	the	the	DET
eurjchem-405	1	47	solvolysis	solvolysis	NOUN
eurjchem-405	1	48	of	of	ADP
eurjchem-405	1	49	isopropenyl	isopropenyl	ADJ
eurjchem-405	1	50	chloroformate	chloroformate	NOUN
eurjchem-405	1	51	malcolm	malcolm	PROPN
eurjchem-405	1	52	john	john	PROPN
eurjchem-405	1	53	d’souzaa	d’souzaa	PROPN
eurjchem-405	1	54	,	,	PUNCT
eurjchem-405	1	55	*	*	PROPN
eurjchem-405	1	56	,	,	PUNCT
eurjchem-405	1	57	kevin	kevin	PROPN
eurjchem-405	1	58	edward	edward	PROPN
eurjchem-405	1	59	shumana	shumana	PROPN
eurjchem-405	1	60	,	,	PUNCT
eurjchem-405	1	61	arnold	arnold	PROPN
eurjchem-405	1	62	ochieng	ochieng	PROPN
eurjchem-405	1	63	omondia	omondia	PROPN
eurjchem-405	1	64	and	and	CCONJ
eurjchem-405	1	65	dennis	dennis	PROPN
eurjchem-405	1	66	neil	neil	PROPN
eurjchem-405	1	67	kevillb	kevillb	PROPN
eurjchem-405	1	68	a	a	DET
eurjchem-405	1	69	department	department	NOUN
eurjchem-405	1	70	of	of	ADP
eurjchem-405	1	71	chemistry	chemistry	NOUN
eurjchem-405	1	72	,	,	PUNCT
eurjchem-405	1	73	wesley	wesley	PROPN
eurjchem-405	1	74	college	college	PROPN
eurjchem-405	1	75	,	,	PUNCT
eurjchem-405	1	76	dover	dover	PROPN
eurjchem-405	1	77	,	,	PUNCT
eurjchem-405	1	78	de	de	PROPN
eurjchem-405	1	79	,	,	PUNCT
eurjchem-405	1	80	19901	19901	NUM
eurjchem-405	1	81	,	,	PUNCT
eurjchem-405	1	82	usa	usa	PROPN
eurjchem-405	1	83	b	b	PROPN
eurjchem-405	1	84	department	department	PROPN
eurjchem-405	1	85	of	of	ADP
eurjchem-405	1	86	chemistry	chemistry	PROPN
eurjchem-405	1	87	&	&	CCONJ
eurjchem-405	1	88	biochemistry	biochemistry	NOUN
eurjchem-405	1	89	,	,	PUNCT
eurjchem-405	1	90	northern	northern	ADJ
eurjchem-405	1	91	illinois	illinois	PROPN
eurjchem-405	1	92	university	university	PROPN
eurjchem-405	1	93	,	,	PUNCT
eurjchem-405	1	94	dekalb	dekalb	PROPN
eurjchem-405	1	95	,	,	PUNCT
eurjchem-405	1	96	il	il	PROPN
eurjchem-405	1	97	,	,	PUNCT
eurjchem-405	1	98	60115	60115	NUM
eurjchem-405	1	99	,	,	PUNCT
eurjchem-405	1	100	usa	usa	PROPN
eurjchem-405	1	101	*	*	PUNCT
eurjchem-405	1	102	corresponding	correspond	VERB
eurjchem-405	1	103	author	author	NOUN
eurjchem-405	1	104	at	at	ADP
eurjchem-405	1	105	:	:	PUNCT
eurjchem-405	1	106	department	department	NOUN
eurjchem-405	1	107	of	of	ADP
eurjchem-405	1	108	chemistry	chemistry	NOUN
eurjchem-405	1	109	,	,	PUNCT
eurjchem-405	1	110	wesley	wesley	PROPN
eurjchem-405	1	111	college	college	PROPN
eurjchem-405	1	112	,	,	PUNCT
eurjchem-405	1	113	dover	dover	PROPN
eurjchem-405	1	114	,	,	PUNCT
eurjchem-405	1	115	de	de	PROPN
eurjchem-405	1	116	,	,	PUNCT
eurjchem-405	1	117	19901	19901	NUM
eurjchem-405	1	118	,	,	PUNCT
eurjchem-405	1	119	usa	usa	PROPN
eurjchem-405	1	120	.	.	PROPN
eurjchem-405	1	121	tel	tel	PROPN
eurjchem-405	1	122	.	.	PUNCT
eurjchem-405	1	123	:	:	PUNCT
eurjchem-405	2	1	+1.302.736.2528	+1.302.736.2528	NUM
eurjchem-405	2	2	;	;	PUNCT
eurjchem-405	2	3	fax	fax	NOUN
eurjchem-405	2	4	:	:	PUNCT
eurjchem-405	2	5	+1.302.736.2301	+1.302.736.2301	NUM
eurjchem-405	2	6	.	.	PUNCT
eurjchem-405	2	7	e‐mail	e‐mail	PUNCT
eurjchem-405	2	8	address	address	NOUN
eurjchem-405	2	9	:	:	PUNCT
eurjchem-405	2	10	dsouzama@wesley.edu	dsouzama@wesley.edu	PROPN
eurjchem-405	2	11	(	(	PUNCT
eurjchem-405	2	12	m.j	m.j	PROPN
eurjchem-405	2	13	.	.	PROPN
eurjchem-405	2	14	d’souza	d’souza	PROPN
eurjchem-405	2	15	)	)	PUNCT
eurjchem-405	2	16	.	.	PUNCT
eurjchem-405	3	1	article	article	NOUN
eurjchem-405	3	2	information	information	PROPN
eurjchem-405	3	3	abstract	abstract	ADV
eurjchem-405	3	4	received	receive	VERB
eurjchem-405	3	5	:	:	PUNCT
eurjchem-405	3	6	10	10	NUM
eurjchem-405	3	7	february	february	NOUN
eurjchem-405	3	8	2011	2011	NUM
eurjchem-405	3	9	received	receive	VERB
eurjchem-405	3	10	in	in	ADP
eurjchem-405	3	11	revised	revise	VERB
eurjchem-405	3	12	form	form	NOUN
eurjchem-405	3	13	:	:	PUNCT
eurjchem-405	3	14	24	24	NUM
eurjchem-405	3	15	february	february	NOUN
eurjchem-405	3	16	2011	2011	NUM
eurjchem-405	3	17	accepted	accept	VERB
eurjchem-405	3	18	:	:	PUNCT
eurjchem-405	3	19	28	28	NUM
eurjchem-405	3	20	february	february	PROPN
eurjchem-405	3	21	2011	2011	NUM
eurjchem-405	3	22	online	online	NOUN
eurjchem-405	3	23	:	:	PUNCT
eurjchem-405	3	24	30	30	NUM
eurjchem-405	3	25	june	june	PROPN
eurjchem-405	3	26	2011	2011	NUM
eurjchem-405	3	27	keywords	keyword	VERB
eurjchem-405	3	28	the	the	DET
eurjchem-405	3	29	specific	specific	ADJ
eurjchem-405	3	30	rates	rate	NOUN
eurjchem-405	3	31	of	of	ADP
eurjchem-405	3	32	solvolysis	solvolysis	NOUN
eurjchem-405	3	33	(	(	PUNCT
eurjchem-405	3	34	including	include	VERB
eurjchem-405	3	35	those	those	PRON
eurjchem-405	3	36	obtained	obtain	VERB
eurjchem-405	3	37	from	from	ADP
eurjchem-405	3	38	the	the	DET
eurjchem-405	3	39	literature	literature	NOUN
eurjchem-405	3	40	)	)	PUNCT
eurjchem-405	3	41	of	of	ADP
eurjchem-405	3	42	isopropenyl	isopropenyl	ADJ
eurjchem-405	3	43	chloroformate	chloroformate	NOUN
eurjchem-405	3	44	(	(	PUNCT
eurjchem-405	3	45	1	1	NUM
eurjchem-405	3	46	)	)	PUNCT
eurjchem-405	3	47	are	be	AUX
eurjchem-405	3	48	analyzed	analyze	VERB
eurjchem-405	3	49	using	use	VERB
eurjchem-405	3	50	the	the	DET
eurjchem-405	3	51	extended	extended	ADJ
eurjchem-405	3	52	grunwald‐winstein	grunwald‐winstein	ADJ
eurjchem-405	3	53	equation	equation	NOUN
eurjchem-405	3	54	,	,	PUNCT
eurjchem-405	3	55	involving	involve	VERB
eurjchem-405	3	56	the	the	DET
eurjchem-405	3	57	nt	nt	ADJ
eurjchem-405	3	58	scale	scale	NOUN
eurjchem-405	3	59	of	of	ADP
eurjchem-405	3	60	solvent	solvent	ADJ
eurjchem-405	3	61	nucleophilicity	nucleophilicity	NOUN
eurjchem-405	3	62	(	(	PUNCT
eurjchem-405	3	63	s‐methyldibenzothiophenium	s‐methyldibenzothiophenium	NOUN
eurjchem-405	3	64	ion	ion	NOUN
eurjchem-405	3	65	)	)	PUNCT
eurjchem-405	3	66	combined	combine	VERB
eurjchem-405	3	67	with	with	ADP
eurjchem-405	3	68	a	a	DET
eurjchem-405	3	69	ycl	ycl	NOUN
eurjchem-405	3	70	scale	scale	NOUN
eurjchem-405	3	71	based	base	VERB
eurjchem-405	3	72	on	on	ADP
eurjchem-405	3	73	1‐adamantyl	1‐adamantyl	NUM
eurjchem-405	3	74	chloride	chloride	NOUN
eurjchem-405	3	75	solvolysis	solvolysis	NOUN
eurjchem-405	3	76	.	.	PUNCT
eurjchem-405	4	1	a	a	DET
eurjchem-405	4	2	similarity	similarity	NOUN
eurjchem-405	4	3	model	model	NOUN
eurjchem-405	4	4	approach	approach	NOUN
eurjchem-405	4	5	,	,	PUNCT
eurjchem-405	4	6	using	use	VERB
eurjchem-405	4	7	phenyl	phenyl	NOUN
eurjchem-405	4	8	chloroformate	chloroformate	NOUN
eurjchem-405	4	9	solvolyses	solvolyse	NOUN
eurjchem-405	4	10	for	for	ADP
eurjchem-405	4	11	comparison	comparison	NOUN
eurjchem-405	4	12	,	,	PUNCT
eurjchem-405	4	13	indicated	indicate	VERB
eurjchem-405	4	14	a	a	DET
eurjchem-405	4	15	dominant	dominant	ADJ
eurjchem-405	4	16	bimolecular	bimolecular	ADJ
eurjchem-405	4	17	carbonyl‐addition	carbonyl‐addition	NOUN
eurjchem-405	4	18	mechanism	mechanism	NOUN
eurjchem-405	4	19	for	for	ADP
eurjchem-405	4	20	the	the	DET
eurjchem-405	4	21	solvolyses	solvolyse	NOUN
eurjchem-405	4	22	of	of	ADP
eurjchem-405	4	23	1	1	NUM
eurjchem-405	4	24	in	in	ADP
eurjchem-405	4	25	all	all	DET
eurjchem-405	4	26	solvents	solvent	NOUN
eurjchem-405	4	27	except	except	SCONJ
eurjchem-405	4	28	97	97	NUM
eurjchem-405	4	29	%	%	NOUN
eurjchem-405	4	30	1,1,1,3,3,3‐hexafluoro‐2‐	1,1,1,3,3,3‐hexafluoro‐2‐	NUM
eurjchem-405	4	31	propanol	propanol	NOUN
eurjchem-405	4	32	(	(	PUNCT
eurjchem-405	4	33	hfip	hfip	PROPN
eurjchem-405	4	34	)	)	PUNCT
eurjchem-405	4	35	.	.	PUNCT
eurjchem-405	5	1	an	an	DET
eurjchem-405	5	2	extensive	extensive	ADJ
eurjchem-405	5	3	evaluation	evaluation	NOUN
eurjchem-405	5	4	of	of	ADP
eurjchem-405	5	5	the	the	DET
eurjchem-405	5	6	outcomes	outcome	NOUN
eurjchem-405	5	7	acquired	acquire	VERB
eurjchem-405	5	8	through	through	ADP
eurjchem-405	5	9	the	the	DET
eurjchem-405	5	10	application	application	NOUN
eurjchem-405	5	11	of	of	ADP
eurjchem-405	5	12	the	the	DET
eurjchem-405	5	13	extended	extended	ADJ
eurjchem-405	5	14	grunwald‐winstein	grunwald‐winstein	ADJ
eurjchem-405	5	15	equation	equation	NOUN
eurjchem-405	5	16	resulted	result	VERB
eurjchem-405	5	17	in	in	ADP
eurjchem-405	5	18	the	the	DET
eurjchem-405	5	19	proposal	proposal	NOUN
eurjchem-405	5	20	of	of	ADP
eurjchem-405	5	21	an	an	DET
eurjchem-405	5	22	addition‐elimination	addition‐elimination	NOUN
eurjchem-405	5	23	mechanism	mechanism	NOUN
eurjchem-405	5	24	dominating	dominate	VERB
eurjchem-405	5	25	in	in	ADP
eurjchem-405	5	26	most	most	ADJ
eurjchem-405	5	27	of	of	ADP
eurjchem-405	5	28	the	the	DET
eurjchem-405	5	29	solvents	solvent	NOUN
eurjchem-405	5	30	,	,	PUNCT
eurjchem-405	5	31	but	but	CCONJ
eurjchem-405	5	32	it	it	PRON
eurjchem-405	5	33	is	be	AUX
eurjchem-405	5	34	proposed	propose	VERB
eurjchem-405	5	35	that	that	SCONJ
eurjchem-405	5	36	a	a	DET
eurjchem-405	5	37	superimposed	superimpose	VERB
eurjchem-405	5	38	unimolecular	unimolecular	ADJ
eurjchem-405	5	39	(	(	PUNCT
eurjchem-405	5	40	sn1	sn1	PROPN
eurjchem-405	5	41	)	)	PUNCT
eurjchem-405	5	42	type	type	NOUN
eurjchem-405	5	43	ionization	ionization	NOUN
eurjchem-405	5	44	is	be	AUX
eurjchem-405	5	45	making	make	VERB
eurjchem-405	5	46	a	a	DET
eurjchem-405	5	47	significant	significant	ADJ
eurjchem-405	5	48	contribution	contribution	NOUN
eurjchem-405	5	49	in	in	ADP
eurjchem-405	5	50	97‐70	97‐70	NUM
eurjchem-405	5	51	%	%	NOUN
eurjchem-405	5	52	hfip	hfip	NOUN
eurjchem-405	5	53	,	,	PUNCT
eurjchem-405	5	54	and	and	CCONJ
eurjchem-405	5	55	97	97	NUM
eurjchem-405	5	56	%	%	NOUN
eurjchem-405	5	57	2,2,2‐trifluoroethanol	2,2,2‐trifluoroethanol	NUM
eurjchem-405	5	58	(	(	PUNCT
eurjchem-405	5	59	tfe	tfe	NOUN
eurjchem-405	5	60	)	)	PUNCT
eurjchem-405	5	61	.	.	PUNCT
eurjchem-405	6	1	solvolysis	solvolysis	NOUN
eurjchem-405	6	2	grunwald‐winstein	grunwald‐winstein	ADJ
eurjchem-405	6	3	equations	equation	NOUN
eurjchem-405	6	4	isopropenyl	isopropenyl	NOUN
eurjchem-405	6	5	chloroformate	chloroformate	VERB
eurjchem-405	6	6	chlorocarbonate	chlorocarbonate	ADJ
eurjchem-405	6	7	addition‐elimination	addition‐elimination	NOUN
eurjchem-405	6	8	ionization	ionization	NOUN
eurjchem-405	6	9	1	1	NUM
eurjchem-405	6	10	.	.	PUNCT
eurjchem-405	6	11	introduction	introduction	NOUN
eurjchem-405	6	12	the	the	DET
eurjchem-405	6	13	two‐term	two‐term	NOUN
eurjchem-405	6	14	extended	extend	VERB
eurjchem-405	6	15	[	[	X
eurjchem-405	6	16	1	1	NUM
eurjchem-405	6	17	]	]	X
eurjchem-405	6	18	grunwald‐winstein	grunwald‐winstein	ADJ
eurjchem-405	6	19	equation	equation	NOUN
eurjchem-405	6	20	was	be	AUX
eurjchem-405	6	21	found	find	VERB
eurjchem-405	6	22	to	to	PART
eurjchem-405	6	23	be	be	AUX
eurjchem-405	6	24	very	very	ADV
eurjchem-405	6	25	efficient	efficient	ADJ
eurjchem-405	6	26	[	[	X
eurjchem-405	6	27	2	2	NUM
eurjchem-405	6	28	]	]	PUNCT
eurjchem-405	6	29	in	in	ADP
eurjchem-405	6	30	correlation	correlation	NOUN
eurjchem-405	6	31	studies	study	NOUN
eurjchem-405	6	32	for	for	ADP
eurjchem-405	6	33	elucidating	elucidate	VERB
eurjchem-405	6	34	solvolytic	solvolytic	ADJ
eurjchem-405	6	35	mechanisms	mechanism	NOUN
eurjchem-405	6	36	of	of	ADP
eurjchem-405	6	37	reaction	reaction	NOUN
eurjchem-405	6	38	for	for	ADP
eurjchem-405	6	39	a	a	DET
eurjchem-405	6	40	variety	variety	NOUN
eurjchem-405	6	41	of	of	ADP
eurjchem-405	6	42	chloroformate	chloroformate	ADJ
eurjchem-405	6	43	esters	ester	NOUN
eurjchem-405	6	44	(	(	PUNCT
eurjchem-405	6	45	rococl	rococl	NOUN
eurjchem-405	6	46	)	)	PUNCT
eurjchem-405	7	1	[	[	X
eurjchem-405	7	2	2‐28	2‐28	NUM
eurjchem-405	7	3	]	]	X
eurjchem-405	7	4	,	,	PUNCT
eurjchem-405	7	5	and	and	CCONJ
eurjchem-405	7	6	their	their	PRON
eurjchem-405	7	7	corresponding	corresponding	ADJ
eurjchem-405	7	8	sulfur‐for‐oxygen	sulfur‐for‐oxygen	PROPN
eurjchem-405	7	9	substituted	substitute	VERB
eurjchem-405	7	10	analogs	analog	NOUN
eurjchem-405	7	11	(	(	PUNCT
eurjchem-405	7	12	rscocl	rscocl	PROPN
eurjchem-405	7	13	,	,	PUNCT
eurjchem-405	7	14	rocscl	rocscl	NOUN
eurjchem-405	7	15	,	,	PUNCT
eurjchem-405	7	16	and	and	CCONJ
eurjchem-405	7	17	rscscl	rscscl	PROPN
eurjchem-405	7	18	)	)	PUNCT
eurjchem-405	8	1	[	[	X
eurjchem-405	8	2	2,23,26,29‐34	2,23,26,29‐34	PROPN
eurjchem-405	8	3	]	]	PUNCT
eurjchem-405	8	4	.	.	PUNCT
eurjchem-405	9	1	in	in	ADP
eurjchem-405	9	2	the	the	DET
eurjchem-405	9	3	extended	extended	ADJ
eurjchem-405	9	4	(	(	PUNCT
eurjchem-405	9	5	equation	equation	NOUN
eurjchem-405	9	6	1	1	NUM
eurjchem-405	9	7	)	)	PUNCT
eurjchem-405	9	8	grunwald‐winstein	grunwald‐winstein	ADJ
eurjchem-405	9	9	equation	equation	NOUN
eurjchem-405	9	10	[	[	X
eurjchem-405	9	11	1	1	NUM
eurjchem-405	9	12	]	]	PUNCT
eurjchem-405	9	13	,	,	PUNCT
eurjchem-405	9	14	k	k	PROPN
eurjchem-405	9	15	and	and	CCONJ
eurjchem-405	9	16	ko	ko	PROPN
eurjchem-405	9	17	are	be	AUX
eurjchem-405	9	18	the	the	DET
eurjchem-405	9	19	specific	specific	ADJ
eurjchem-405	9	20	rates	rate	NOUN
eurjchem-405	9	21	of	of	ADP
eurjchem-405	9	22	solvolysis	solvolysis	NOUN
eurjchem-405	9	23	in	in	ADP
eurjchem-405	9	24	a	a	DET
eurjchem-405	9	25	given	give	VERB
eurjchem-405	9	26	solvent	solvent	NOUN
eurjchem-405	9	27	and	and	CCONJ
eurjchem-405	9	28	in	in	ADP
eurjchem-405	9	29	the	the	DET
eurjchem-405	9	30	standard	standard	ADJ
eurjchem-405	9	31	solvent	solvent	NOUN
eurjchem-405	9	32	(	(	PUNCT
eurjchem-405	9	33	80	80	NUM
eurjchem-405	9	34	%	%	NOUN
eurjchem-405	9	35	ethanol	ethanol	NOUN
eurjchem-405	9	36	)	)	PUNCT
eurjchem-405	9	37	,	,	PUNCT
eurjchem-405	9	38	respectively	respectively	ADV
eurjchem-405	9	39	,	,	PUNCT
eurjchem-405	9	40	l	l	NOUN
eurjchem-405	9	41	governs	govern	VERB
eurjchem-405	9	42	the	the	DET
eurjchem-405	9	43	sensitivity	sensitivity	NOUN
eurjchem-405	9	44	to	to	ADP
eurjchem-405	9	45	changes	change	NOUN
eurjchem-405	9	46	in	in	ADP
eurjchem-405	9	47	solvent	solvent	ADJ
eurjchem-405	9	48	nucleophilicity	nucleophilicity	NOUN
eurjchem-405	9	49	(	(	PUNCT
eurjchem-405	9	50	n	n	CCONJ
eurjchem-405	9	51	)	)	PUNCT
eurjchem-405	9	52	,	,	PUNCT
eurjchem-405	9	53	m	m	VERB
eurjchem-405	9	54	represents	represent	VERB
eurjchem-405	9	55	the	the	DET
eurjchem-405	9	56	sensitivity	sensitivity	NOUN
eurjchem-405	9	57	to	to	AUX
eurjchem-405	9	58	changes	change	NOUN
eurjchem-405	9	59	in	in	ADP
eurjchem-405	9	60	the	the	DET
eurjchem-405	9	61	solvent	solvent	NOUN
eurjchem-405	9	62	ionizing	ionizing	NOUN
eurjchem-405	9	63	power	power	NOUN
eurjchem-405	9	64	y	y	PROPN
eurjchem-405	9	65	(	(	PUNCT
eurjchem-405	9	66	initially	initially	ADV
eurjchem-405	9	67	set	set	VERB
eurjchem-405	9	68	at	at	ADP
eurjchem-405	9	69	unity	unity	NOUN
eurjchem-405	9	70	for	for	ADP
eurjchem-405	9	71	tert‐butyl	tert‐butyl	X
eurjchem-405	9	72	chloride	chloride	NOUN
eurjchem-405	9	73	solvolyses	solvolyse	NOUN
eurjchem-405	9	74	)	)	PUNCT
eurjchem-405	9	75	,	,	PUNCT
eurjchem-405	9	76	and	and	CCONJ
eurjchem-405	9	77	c	c	NOUN
eurjchem-405	9	78	is	be	AUX
eurjchem-405	9	79	a	a	DET
eurjchem-405	9	80	constant	constant	ADJ
eurjchem-405	9	81	(	(	PUNCT
eurjchem-405	9	82	residual	residual	ADJ
eurjchem-405	9	83	)	)	PUNCT
eurjchem-405	9	84	term	term	NOUN
eurjchem-405	10	1	[	[	X
eurjchem-405	10	2	2	2	NUM
eurjchem-405	10	3	]	]	PUNCT
eurjchem-405	10	4	.	.	PUNCT
eurjchem-405	11	1	log	log	NOUN
eurjchem-405	11	2	(	(	PUNCT
eurjchem-405	11	3	k	k	NOUN
eurjchem-405	11	4	/	/	SYM
eurjchem-405	11	5	ko	ko	PROPN
eurjchem-405	11	6	)	)	PUNCT
eurjchem-405	11	7	=	=	PUNCT
eurjchem-405	12	1	ln	ln	NOUN
eurjchem-405	13	1	+	+	CCONJ
eurjchem-405	13	2	my	my	PRON
eurjchem-405	13	3	+	+	X
eurjchem-405	13	4	c	c	X
eurjchem-405	13	5	(	(	PUNCT
eurjchem-405	13	6	1	1	NUM
eurjchem-405	13	7	)	)	PUNCT
eurjchem-405	13	8	nt	not	PART
eurjchem-405	13	9	scales	scale	NOUN
eurjchem-405	13	10	based	base	VERB
eurjchem-405	13	11	on	on	ADP
eurjchem-405	13	12	the	the	DET
eurjchem-405	13	13	solvolyses	solvolyse	NOUN
eurjchem-405	13	14	of	of	ADP
eurjchem-405	13	15	the	the	DET
eurjchem-405	13	16	s‐methyl‐	s‐methyl‐	NOUN
eurjchem-405	13	17	dibenzothiophenium	dibenzothiophenium	NOUN
eurjchem-405	13	18	ion	ion	NOUN
eurjchem-405	13	19	[	[	X
eurjchem-405	13	20	35,36	35,36	X
eurjchem-405	13	21	]	]	PUNCT
eurjchem-405	13	22	have	have	AUX
eurjchem-405	13	23	now	now	ADV
eurjchem-405	13	24	become	become	VERB
eurjchem-405	13	25	the	the	DET
eurjchem-405	13	26	recognized	recognize	VERB
eurjchem-405	13	27	standards	standard	NOUN
eurjchem-405	13	28	for	for	ADP
eurjchem-405	13	29	considerations	consideration	NOUN
eurjchem-405	13	30	of	of	ADP
eurjchem-405	13	31	solvent	solvent	NOUN
eurjchem-405	13	32	nucleo‐	nucleo‐	ADP
eurjchem-405	13	33	philicity	philicity	NOUN
eurjchem-405	13	34	and	and	CCONJ
eurjchem-405	13	35	it	it	PRON
eurjchem-405	13	36	has	have	AUX
eurjchem-405	13	37	been	be	AUX
eurjchem-405	13	38	previously	previously	ADV
eurjchem-405	13	39	shown	show	VERB
eurjchem-405	13	40	[	[	PUNCT
eurjchem-405	13	41	37,38	37,38	NOUN
eurjchem-405	13	42	]	]	PUNCT
eurjchem-405	13	43	that	that	PRON
eurjchem-405	13	44	adamantyl	adamantyl	ADJ
eurjchem-405	13	45	derivatives	derivative	NOUN
eurjchem-405	13	46	provide	provide	VERB
eurjchem-405	13	47	better	well	ADJ
eurjchem-405	13	48	standard	standard	ADJ
eurjchem-405	13	49	substrates	substrate	NOUN
eurjchem-405	13	50	for	for	ADP
eurjchem-405	13	51	a	a	DET
eurjchem-405	13	52	leaving	leave	VERB
eurjchem-405	13	53	group	group	NOUN
eurjchem-405	13	54	x.	x.	NOUN
eurjchem-405	13	55	hence	hence	ADV
eurjchem-405	13	56	,	,	PUNCT
eurjchem-405	13	57	a	a	DET
eurjchem-405	13	58	series	series	NOUN
eurjchem-405	13	59	of	of	ADP
eurjchem-405	13	60	yx	yx	PROPN
eurjchem-405	13	61	scales	scale	NOUN
eurjchem-405	13	62	[	[	X
eurjchem-405	13	63	37‐43	37‐43	NOUN
eurjchem-405	13	64	]	]	PUNCT
eurjchem-405	13	65	are	be	AUX
eurjchem-405	13	66	now	now	ADV
eurjchem-405	13	67	available	available	ADJ
eurjchem-405	13	68	.	.	PUNCT
eurjchem-405	14	1	whenever	whenever	SCONJ
eurjchem-405	14	2	the	the	DET
eurjchem-405	14	3	reaction	reaction	NOUN
eurjchem-405	14	4	center	center	NOUN
eurjchem-405	14	5	is	be	AUX
eurjchem-405	14	6	adjacent	adjacent	ADJ
eurjchem-405	14	7	to	to	ADP
eurjchem-405	14	8	a	a	DET
eurjchem-405	14	9	π‐	π‐	ADJ
eurjchem-405	14	10	system	system	NOUN
eurjchem-405	14	11	[	[	X
eurjchem-405	14	12	44,45	44,45	X
eurjchem-405	14	13	]	]	X
eurjchem-405	14	14	,	,	PUNCT
eurjchem-405	14	15	or	or	CCONJ
eurjchem-405	14	16	in	in	ADP
eurjchem-405	14	17	α‐haloalkyl	α‐haloalkyl	ADJ
eurjchem-405	14	18	aryl	aryl	NOUN
eurjchem-405	14	19	compounds	compound	NOUN
eurjchem-405	14	20	that	that	PRON
eurjchem-405	14	21	proceed	proceed	VERB
eurjchem-405	14	22	via	via	ADP
eurjchem-405	14	23	anchimeric	anchimeric	ADJ
eurjchem-405	14	24	assistance	assistance	NOUN
eurjchem-405	14	25	(	(	PUNCT
eurjchem-405	14	26	k∆	k∆	NOUN
eurjchem-405	14	27	)	)	PUNCT
eurjchem-405	15	1	[	[	X
eurjchem-405	15	2	46	46	NUM
eurjchem-405	15	3	]	]	PUNCT
eurjchem-405	15	4	,	,	PUNCT
eurjchem-405	15	5	kevill	kevill	NOUN
eurjchem-405	15	6	and	and	CCONJ
eurjchem-405	15	7	d’souza	d’souza	NOUN
eurjchem-405	15	8	recommended	recommend	VERB
eurjchem-405	15	9	[	[	X
eurjchem-405	15	10	2,47‐50	2,47‐50	NUM
eurjchem-405	15	11	]	]	X
eurjchem-405	15	12	the	the	DET
eurjchem-405	15	13	addition	addition	NOUN
eurjchem-405	15	14	of	of	ADP
eurjchem-405	15	15	an	an	DET
eurjchem-405	15	16	additional	additional	ADJ
eurjchem-405	15	17	aromatic	aromatic	ADJ
eurjchem-405	15	18	ring	ring	NOUN
eurjchem-405	15	19	parameter	parameter	NOUN
eurjchem-405	15	20	(	(	PUNCT
eurjchem-405	15	21	hi	hi	INTJ
eurjchem-405	15	22	)	)	PUNCT
eurjchem-405	15	23	term	term	NOUN
eurjchem-405	15	24	to	to	ADP
eurjchem-405	15	25	equation	equation	NOUN
eurjchem-405	15	26	1	1	NUM
eurjchem-405	15	27	give	give	VERB
eurjchem-405	15	28	equation	equation	NOUN
eurjchem-405	15	29	2	2	NUM
eurjchem-405	15	30	.	.	PUNCT
eurjchem-405	15	31	in	in	ADP
eurjchem-405	15	32	equation	equation	NOUN
eurjchem-405	15	33	2	2	NUM
eurjchem-405	15	34	,	,	PUNCT
eurjchem-405	15	35	h	h	NOUN
eurjchem-405	15	36	represents	represent	VERB
eurjchem-405	15	37	the	the	DET
eurjchem-405	15	38	sensitivity	sensitivity	NOUN
eurjchem-405	15	39	of	of	ADP
eurjchem-405	15	40	solvolyses	solvolyse	NOUN
eurjchem-405	15	41	to	to	PART
eurjchem-405	15	42	changes	change	NOUN
eurjchem-405	15	43	in	in	ADP
eurjchem-405	15	44	the	the	DET
eurjchem-405	15	45	aromatic	aromatic	ADJ
eurjchem-405	15	46	ring	ring	NOUN
eurjchem-405	15	47	parameter	parameter	NOUN
eurjchem-405	15	48	i.	i.	PROPN
eurjchem-405	15	49	log	log	PROPN
eurjchem-405	15	50	(	(	PUNCT
eurjchem-405	15	51	k	k	NOUN
eurjchem-405	15	52	/	/	SYM
eurjchem-405	15	53	ko	ko	PROPN
eurjchem-405	15	54	)	)	PUNCT
eurjchem-405	15	55	=	=	PUNCT
eurjchem-405	16	1	ln	ln	NOUN
eurjchem-405	17	1	+	+	CCONJ
eurjchem-405	17	2	my	my	PRON
eurjchem-405	17	3	+	+	NOUN
eurjchem-405	17	4	hi	hi	INTJ
eurjchem-405	18	1	+	+	X
eurjchem-405	18	2	c	c	X
eurjchem-405	18	3	(	(	PUNCT
eurjchem-405	18	4	2	2	NUM
eurjchem-405	18	5	)	)	PUNCT
eurjchem-405	18	6	due	due	ADP
eurjchem-405	18	7	to	to	ADP
eurjchem-405	18	8	increased	increase	VERB
eurjchem-405	18	9	initial	initial	ADJ
eurjchem-405	18	10	resonance	resonance	NOUN
eurjchem-405	18	11	ground	grind	VERB
eurjchem-405	18	12	state‐	state‐	NOUN
eurjchem-405	18	13	stabilization	stabilization	NOUN
eurjchem-405	19	1	[	[	X
eurjchem-405	19	2	26,51‐56	26,51‐56	NUM
eurjchem-405	19	3	]	]	PUNCT
eurjchem-405	19	4	,	,	PUNCT
eurjchem-405	19	5	chloroformate	chloroformate	ADJ
eurjchem-405	19	6	esters	ester	NOUN
eurjchem-405	19	7	were	be	AUX
eurjchem-405	19	8	found	find	VERB
eurjchem-405	19	9	to	to	PART
eurjchem-405	19	10	be	be	AUX
eurjchem-405	19	11	much	much	ADV
eurjchem-405	19	12	less	less	ADV
eurjchem-405	19	13	reactive	reactive	ADJ
eurjchem-405	19	14	than	than	ADP
eurjchem-405	19	15	acyl	acyl	NOUN
eurjchem-405	19	16	chlorides	chloride	NOUN
eurjchem-405	19	17	.	.	PUNCT
eurjchem-405	20	1	hence	hence	ADV
eurjchem-405	20	2	,	,	PUNCT
eurjchem-405	20	3	they	they	PRON
eurjchem-405	20	4	are	be	AUX
eurjchem-405	20	5	widely	widely	ADV
eurjchem-405	20	6	employed	employ	VERB
eurjchem-405	20	7	[	[	X
eurjchem-405	20	8	57,58	57,58	NOUN
eurjchem-405	20	9	]	]	PUNCT
eurjchem-405	20	10	as	as	SCONJ
eurjchem-405	20	11	precursors	precursor	NOUN
eurjchem-405	20	12	to	to	PART
eurjchem-405	20	13	produce	produce	VERB
eurjchem-405	20	14	commercially	commercially	ADV
eurjchem-405	20	15	useful	useful	ADJ
eurjchem-405	20	16	pharmaceutical	pharmaceutical	ADJ
eurjchem-405	20	17	and	and	CCONJ
eurjchem-405	20	18	agricultural	agricultural	ADJ
eurjchem-405	20	19	products	product	NOUN
eurjchem-405	20	20	.	.	PUNCT
eurjchem-405	21	1	lee	lee	PROPN
eurjchem-405	21	2	’s	’s	PART
eurjchem-405	21	3	original	original	ADJ
eurjchem-405	21	4	proposal	proposal	NOUN
eurjchem-405	21	5	[	[	X
eurjchem-405	21	6	59	59	NUM
eurjchem-405	21	7	]	]	PUNCT
eurjchem-405	21	8	of	of	ADP
eurjchem-405	21	9	the	the	DET
eurjchem-405	21	10	existence	existence	NOUN
eurjchem-405	21	11	of	of	ADP
eurjchem-405	21	12	a	a	DET
eurjchem-405	21	13	syn	syn	NOUN
eurjchem-405	21	14	geometry	geometry	NOUN
eurjchem-405	21	15	in	in	ADP
eurjchem-405	21	16	haloformate	haloformate	ADJ
eurjchem-405	21	17	esters	ester	NOUN
eurjchem-405	21	18	was	be	AUX
eurjchem-405	21	19	confirmed	confirm	VERB
eurjchem-405	21	20	[	[	X
eurjchem-405	21	21	55,60‐66	55,60‐66	NUM
eurjchem-405	21	22	]	]	X
eurjchem-405	21	23	in	in	ADP
eurjchem-405	21	24	recent	recent	ADJ
eurjchem-405	21	25	computational	computational	ADJ
eurjchem-405	21	26	and	and	CCONJ
eurjchem-405	21	27	experimental	experimental	ADJ
eurjchem-405	21	28	studies	study	NOUN
eurjchem-405	21	29	and	and	CCONJ
eurjchem-405	21	30	crystal	crystal	NOUN
eurjchem-405	21	31	structure	structure	NOUN
eurjchem-405	21	32	analysis	analysis	NOUN
eurjchem-405	21	33	.	.	PUNCT
eurjchem-405	22	1	in	in	ADP
eurjchem-405	22	2	figure	figure	NOUN
eurjchem-405	22	3	1	1	NUM
eurjchem-405	22	4	,	,	PUNCT
eurjchem-405	22	5	s‐isopropenyl	s‐isopropenyl	PUNCT
eurjchem-405	22	6	chloroformate	chloroformate	VERB
eurjchem-405	22	7	(	(	PUNCT
eurjchem-405	22	8	1	1	NUM
eurjchem-405	22	9	,	,	PUNCT
eurjchem-405	22	10	i‐propenylococl	i‐propenylococl	NUM
eurjchem-405	22	11	)	)	PUNCT
eurjchem-405	22	12	,	,	PUNCT
eurjchem-405	22	13	s‐isopropyl	s‐isopropyl	PROPN
eurjchem-405	22	14	chloroformate	chloroformate	NOUN
eurjchem-405	22	15	(	(	PUNCT
eurjchem-405	22	16	2	2	NUM
eurjchem-405	22	17	,	,	PUNCT
eurjchem-405	22	18	i‐prococl	i‐prococl	ADJ
eurjchem-405	22	19	)	)	PUNCT
eurjchem-405	22	20	,	,	PUNCT
eurjchem-405	22	21	and	and	CCONJ
eurjchem-405	22	22	s‐phenyl	s‐phenyl	X
eurjchem-405	22	23	chloroformate	chloroformate	VERB
eurjchem-405	22	24	(	(	PUNCT
eurjchem-405	22	25	3	3	NUM
eurjchem-405	22	26	,	,	PUNCT
eurjchem-405	22	27	phococl	phococl	NOUN
eurjchem-405	22	28	)	)	PUNCT
eurjchem-405	22	29	are	be	AUX
eurjchem-405	22	30	shown	show	VERB
eurjchem-405	22	31	with	with	ADP
eurjchem-405	22	32	the	the	DET
eurjchem-405	22	33	halogen	halogen	NOUN
eurjchem-405	22	34	atom	atom	NOUN
eurjchem-405	22	35	in	in	ADP
eurjchem-405	22	36	a	a	DET
eurjchem-405	22	37	trans	trans	NOUN
eurjchem-405	22	38	position	position	NOUN
eurjchem-405	22	39	to	to	ADP
eurjchem-405	22	40	the	the	DET
eurjchem-405	22	41	alkenyl	alkenyl	NOUN
eurjchem-405	22	42	,	,	PUNCT
eurjchem-405	22	43	alkyl	alkyl	NOUN
eurjchem-405	22	44	or	or	CCONJ
eurjchem-405	22	45	aryl	aryl	NOUN
eurjchem-405	22	46	group	group	NOUN
eurjchem-405	22	47	,	,	PUNCT
eurjchem-405	22	48	i.e.	i.e.	X
eurjchem-405	22	49	in	in	ADP
eurjchem-405	22	50	syn‐geometry	syn‐geometry	PROPN
eurjchem-405	22	51	.	.	PUNCT
eurjchem-405	23	1	figure	figure	VERB
eurjchem-405	23	2	1.molecular	1.molecular	NUM
eurjchem-405	23	3	structures	structure	NOUN
eurjchem-405	23	4	of	of	ADP
eurjchem-405	23	5	s‐isopropenyl	s‐isopropenyl	PUNCT
eurjchem-405	23	6	chloroformate	chloroformate	NOUN
eurjchem-405	23	7	(	(	PUNCT
eurjchem-405	23	8	1	1	NUM
eurjchem-405	23	9	)	)	PUNCT
eurjchem-405	23	10	,	,	PUNCT
eurjchem-405	23	11	s‐isopropyl	s‐isopropyl	PUNCT
eurjchem-405	23	12	chloroformate	chloroformate	NOUN
eurjchem-405	23	13	(	(	PUNCT
eurjchem-405	23	14	2	2	NUM
eurjchem-405	23	15	)	)	PUNCT
eurjchem-405	23	16	,	,	PUNCT
eurjchem-405	23	17	and	and	CCONJ
eurjchem-405	23	18	s‐phenyl	s‐phenyl	X
eurjchem-405	23	19	chloroformate	chloroformate	VERB
eurjchem-405	23	20	(	(	PUNCT
eurjchem-405	23	21	3	3	NUM
eurjchem-405	23	22	)	)	PUNCT
eurjchem-405	23	23	.	.	PUNCT
eurjchem-405	24	1	since	since	SCONJ
eurjchem-405	24	2	world	world	NOUN
eurjchem-405	24	3	war	war	NOUN
eurjchem-405	24	4	i	i	PRON
eurjchem-405	24	5	,	,	PUNCT
eurjchem-405	24	6	there	there	PRON
eurjchem-405	24	7	has	have	AUX
eurjchem-405	24	8	been	be	AUX
eurjchem-405	24	9	significant	significant	ADJ
eurjchem-405	24	10	interest	interest	NOUN
eurjchem-405	24	11	in	in	ADP
eurjchem-405	24	12	1	1	NUM
eurjchem-405	24	13	due	due	ADP
eurjchem-405	24	14	to	to	ADP
eurjchem-405	24	15	its	its	PRON
eurjchem-405	24	16	ability	ability	NOUN
eurjchem-405	24	17	to	to	PART
eurjchem-405	24	18	cause	cause	VERB
eurjchem-405	24	19	sharp	sharp	ADJ
eurjchem-405	24	20	pain	pain	NOUN
eurjchem-405	24	21	in	in	ADP
eurjchem-405	24	22	the	the	DET
eurjchem-405	24	23	eyes	eye	NOUN
eurjchem-405	24	24	upon	upon	SCONJ
eurjchem-405	24	25	exposure	exposure	NOUN
eurjchem-405	24	26	to	to	ADP
eurjchem-405	24	27	the	the	DET
eurjchem-405	24	28	evaporating	evaporate	VERB
eurjchem-405	24	29	gas	gas	NOUN
eurjchem-405	24	30	[	[	X
eurjchem-405	24	31	67	67	NUM
eurjchem-405	24	32	]	]	PUNCT
eurjchem-405	24	33	.	.	PUNCT
eurjchem-405	25	1	in	in	ADP
eurjchem-405	25	2	1915	1915	NUM
eurjchem-405	25	3	,	,	PUNCT
eurjchem-405	25	4	phosgene	phosgene	NOUN
eurjchem-405	25	5	was	be	AUX
eurjchem-405	25	6	first	first	ADV
eurjchem-405	25	7	employed	employ	VERB
eurjchem-405	25	8	[	[	X
eurjchem-405	25	9	67	67	NUM
eurjchem-405	25	10	]	]	PUNCT
eurjchem-405	25	11	as	as	ADP
eurjchem-405	25	12	a	a	DET
eurjchem-405	25	13	war	war	NOUN
eurjchem-405	25	14	gas	gas	NOUN
eurjchem-405	25	15	because	because	SCONJ
eurjchem-405	25	16	it	it	PRON
eurjchem-405	25	17	was	be	AUX
eurjchem-405	25	18	claimed	claim	VERB
eurjchem-405	25	19	to	to	PART
eurjchem-405	25	20	readily	readily	ADV
eurjchem-405	25	21	dissolve	dissolve	VERB
eurjchem-405	25	22	in	in	ADP
eurjchem-405	25	23	acetone	acetone	NOUN
eurjchem-405	25	24	to	to	PART
eurjchem-405	25	25	form	form	VERB
eurjchem-405	25	26	1	1	NUM
eurjchem-405	25	27	,	,	PUNCT
eurjchem-405	25	28	which	which	PRON
eurjchem-405	25	29	then	then	ADV
eurjchem-405	25	30	underwent	undergo	VERB
eurjchem-405	25	31	rapid	rapid	ADJ
eurjchem-405	25	32	hydrolysis	hydrolysis	NOUN
eurjchem-405	25	33	to	to	PART
eurjchem-405	25	34	produce	produce	VERB
eurjchem-405	25	35	corrosive	corrosive	ADJ
eurjchem-405	25	36	hcl	hcl	PROPN
eurjchem-405	25	37	(	(	PUNCT
eurjchem-405	25	38	scheme	scheme	NOUN
eurjchem-405	25	39	1	1	NUM
eurjchem-405	25	40	)	)	PUNCT
eurjchem-405	25	41	.	.	PUNCT
eurjchem-405	26	1	however	however	ADV
eurjchem-405	26	2	,	,	PUNCT
eurjchem-405	26	3	this	this	DET
eurjchem-405	26	4	enol	enol	NOUN
eurjchem-405	26	5	acylation	acylation	NOUN
eurjchem-405	26	6	could	could	AUX
eurjchem-405	26	7	not	not	PART
eurjchem-405	26	8	be	be	AUX
eurjchem-405	26	9	reproduced	reproduce	VERB
eurjchem-405	26	10	and	and	CCONJ
eurjchem-405	26	11	has	have	AUX
eurjchem-405	26	12	since	since	ADV
eurjchem-405	26	13	been	be	AUX
eurjchem-405	26	14	disproved	disprove	VERB
eurjchem-405	26	15	[	[	PUNCT
eurjchem-405	26	16	68	68	NUM
eurjchem-405	26	17	]	]	PUNCT
eurjchem-405	26	18	.	.	PUNCT
eurjchem-405	27	1	d’souza	d’souza	NOUN
eurjchem-405	27	2	et	et	PROPN
eurjchem-405	27	3	al	al	PROPN
eurjchem-405	27	4	.	.	PUNCT
eurjchem-405	27	5	/	/	SYM
eurjchem-405	27	6	european	european	PROPN
eurjchem-405	27	7	journal	journal	PROPN
eurjchem-405	27	8	of	of	ADP
eurjchem-405	27	9	chemistry	chemistry	NOUN
eurjchem-405	27	10	2	2	NUM
eurjchem-405	27	11	(	(	PUNCT
eurjchem-405	27	12	2	2	NUM
eurjchem-405	27	13	)	)	PUNCT
eurjchem-405	27	14	(	(	PUNCT
eurjchem-405	27	15	2011	2011	NUM
eurjchem-405	27	16	)	)	PUNCT
eurjchem-405	27	17	130‐135	130‐135	NOUN
eurjchem-405	27	18	131	131	NUM
eurjchem-405	27	19	scheme	scheme	NOUN
eurjchem-405	27	20	1	1	NUM
eurjchem-405	27	21	recent	recent	ADJ
eurjchem-405	27	22	applications	application	NOUN
eurjchem-405	28	1	[	[	X
eurjchem-405	28	2	69	69	NUM
eurjchem-405	28	3	]	]	PUNCT
eurjchem-405	28	4	of	of	ADP
eurjchem-405	28	5	1	1	NUM
eurjchem-405	28	6	include	include	VERB
eurjchem-405	28	7	its	its	PRON
eurjchem-405	28	8	use	use	NOUN
eurjchem-405	28	9	in	in	ADP
eurjchem-405	28	10	the	the	DET
eurjchem-405	28	11	synthesis	synthesis	NOUN
eurjchem-405	28	12	of	of	ADP
eurjchem-405	28	13	protective	protective	ADJ
eurjchem-405	28	14	groups	group	NOUN
eurjchem-405	28	15	for	for	ADP
eurjchem-405	28	16	amino	amino	ADJ
eurjchem-405	28	17	acids	acid	NOUN
eurjchem-405	28	18	and	and	CCONJ
eurjchem-405	28	19	peptides	peptide	NOUN
eurjchem-405	28	20	.	.	PUNCT
eurjchem-405	29	1	ryu	ryu	NOUN
eurjchem-405	29	2	and	and	CCONJ
eurjchem-405	29	3	coworkers	coworker	NOUN
eurjchem-405	30	1	[	[	X
eurjchem-405	30	2	22	22	NUM
eurjchem-405	30	3	]	]	PUNCT
eurjchem-405	30	4	using	use	VERB
eurjchem-405	30	5	equation	equation	NOUN
eurjchem-405	30	6	1	1	NUM
eurjchem-405	30	7	,	,	PUNCT
eurjchem-405	30	8	analyzed	analyze	VERB
eurjchem-405	30	9	the	the	DET
eurjchem-405	30	10	kinetic	kinetic	ADJ
eurjchem-405	30	11	data	datum	NOUN
eurjchem-405	30	12	of	of	ADP
eurjchem-405	30	13	1	1	NUM
eurjchem-405	30	14	in	in	ADP
eurjchem-405	30	15	40	40	NUM
eurjchem-405	30	16	solvents	solvent	NOUN
eurjchem-405	30	17	of	of	ADP
eurjchem-405	30	18	varying	vary	VERB
eurjchem-405	30	19	nucleophilicity	nucleophilicity	NOUN
eurjchem-405	30	20	and	and	CCONJ
eurjchem-405	30	21	ionizing	ionize	VERB
eurjchem-405	30	22	power	power	NOUN
eurjchem-405	30	23	at	at	ADP
eurjchem-405	30	24	10.0	10.0	NUM
eurjchem-405	30	25	oc	oc	NOUN
eurjchem-405	30	26	,	,	PUNCT
eurjchem-405	30	27	its	its	PRON
eurjchem-405	30	28	kinetic	kinetic	ADJ
eurjchem-405	30	29	solvent	solvent	NOUN
eurjchem-405	30	30	isotope	isotope	NOUN
eurjchem-405	30	31	effects	effect	NOUN
eurjchem-405	30	32	(	(	PUNCT
eurjchem-405	30	33	ksie	ksie	NOUN
eurjchem-405	30	34	)	)	PUNCT
eurjchem-405	30	35	in	in	ADP
eurjchem-405	30	36	methanol	methanol	NOUN
eurjchem-405	30	37	and	and	CCONJ
eurjchem-405	30	38	water	water	NOUN
eurjchem-405	30	39	,	,	PUNCT
eurjchem-405	30	40	and	and	CCONJ
eurjchem-405	30	41	after	after	ADP
eurjchem-405	30	42	studying	study	VERB
eurjchem-405	30	43	the	the	DET
eurjchem-405	30	44	previously	previously	ADV
eurjchem-405	30	45	reported	report	VERB
eurjchem-405	30	46	data	datum	NOUN
eurjchem-405	30	47	on	on	ADP
eurjchem-405	30	48	steric	steric	ADJ
eurjchem-405	30	49	effects	effect	NOUN
eurjchem-405	30	50	[	[	X
eurjchem-405	30	51	51‐53	51‐53	X
eurjchem-405	30	52	]	]	PUNCT
eurjchem-405	30	53	,	,	PUNCT
eurjchem-405	30	54	proposed	propose	VERB
eurjchem-405	30	55	a	a	DET
eurjchem-405	30	56	third	third	ADJ
eurjchem-405	30	57	order	order	NOUN
eurjchem-405	30	58	reaction	reaction	NOUN
eurjchem-405	30	59	mechanism	mechanism	NOUN
eurjchem-405	30	60	with	with	ADP
eurjchem-405	30	61	four	four	NUM
eurjchem-405	30	62	competing	compete	VERB
eurjchem-405	30	63	reaction‐channels	reaction‐channel	NOUN
eurjchem-405	30	64	in	in	ADP
eurjchem-405	30	65	the	the	DET
eurjchem-405	30	66	aqueous	aqueous	ADJ
eurjchem-405	30	67	alcohol	alcohol	NOUN
eurjchem-405	30	68	solvent	solvent	NOUN
eurjchem-405	30	69	systems	system	NOUN
eurjchem-405	30	70	.	.	PUNCT
eurjchem-405	31	1	koh	koh	PROPN
eurjchem-405	31	2	and	and	CCONJ
eurjchem-405	31	3	kang	kang	PROPN
eurjchem-405	32	1	[	[	X
eurjchem-405	32	2	70	70	NUM
eurjchem-405	32	3	]	]	PUNCT
eurjchem-405	32	4	recently	recently	ADV
eurjchem-405	32	5	proposed	propose	VERB
eurjchem-405	32	6	that	that	SCONJ
eurjchem-405	32	7	1	1	NUM
eurjchem-405	32	8	undergoes	undergoe	NOUN
eurjchem-405	32	9	solvolysis	solvolysis	NOUN
eurjchem-405	32	10	by	by	ADP
eurjchem-405	32	11	a	a	DET
eurjchem-405	32	12	rate‐limiting	rate‐limiting	NOUN
eurjchem-405	32	13	addition	addition	NOUN
eurjchem-405	32	14	in	in	ADP
eurjchem-405	32	15	an	an	DET
eurjchem-405	32	16	addition‐elimination	addition‐elimination	NOUN
eurjchem-405	32	17	pathway	pathway	NOUN
eurjchem-405	32	18	coupled	couple	VERB
eurjchem-405	32	19	with	with	ADP
eurjchem-405	32	20	general	general	ADJ
eurjchem-405	32	21	base	base	NOUN
eurjchem-405	32	22	catalysis	catalysis	NOUN
eurjchem-405	32	23	being	be	AUX
eurjchem-405	32	24	superimposed	superimpose	VERB
eurjchem-405	32	25	upon	upon	SCONJ
eurjchem-405	32	26	the	the	DET
eurjchem-405	32	27	bimolecular	bimolecular	ADJ
eurjchem-405	32	28	process	process	NOUN
eurjchem-405	32	29	.	.	PUNCT
eurjchem-405	33	1	o	o	X
eurjchem-405	33	2	o	o	X
eurjchem-405	33	3	cl	cl	NOUN
eurjchem-405	33	4	co2	co2	NOUN
eurjchem-405	33	5	cl	cl	NOUN
eurjchem-405	33	6	cl	cl	NOUN
eurjchem-405	33	7	os	os	NOUN
eurjchem-405	34	1	+	+	CCONJ
eurjchem-405	34	2	soh2	soh2	NOUN
eurjchem-405	34	3	+	+	SYM
eurjchem-405	34	4	+	+	CCONJ
eurjchem-405	34	5	cl2soh	cl2soh	ADJ
eurjchem-405	34	6	scheme	scheme	NOUN
eurjchem-405	34	7	2	2	NUM
eurjchem-405	34	8	on	on	ADP
eurjchem-405	34	9	the	the	DET
eurjchem-405	34	10	other	other	ADJ
eurjchem-405	34	11	hand	hand	NOUN
eurjchem-405	34	12	,	,	PUNCT
eurjchem-405	34	13	dissecting	dissect	VERB
eurjchem-405	34	14	the	the	DET
eurjchem-405	34	15	data	datum	NOUN
eurjchem-405	34	16	obtained	obtain	VERB
eurjchem-405	34	17	from	from	ADP
eurjchem-405	34	18	extensive	extensive	ADJ
eurjchem-405	34	19	correlation	correlation	NOUN
eurjchem-405	34	20	analysis	analysis	NOUN
eurjchem-405	34	21	results	result	NOUN
eurjchem-405	34	22	[	[	X
eurjchem-405	34	23	17,27	17,27	NUM
eurjchem-405	34	24	]	]	PUNCT
eurjchem-405	34	25	,	,	PUNCT
eurjchem-405	34	26	using	use	VERB
eurjchem-405	34	27	equation	equation	NOUN
eurjchem-405	34	28	1	1	NUM
eurjchem-405	34	29	,	,	PUNCT
eurjchem-405	34	30	for	for	ADP
eurjchem-405	34	31	1	1	NUM
eurjchem-405	34	32	’s	’s	PART
eurjchem-405	34	33	alkyl	alkyl	ADJ
eurjchem-405	34	34	analog	analog	NOUN
eurjchem-405	34	35	isopropyl	isopropyl	NOUN
eurjchem-405	34	36	chloroformate	chloroformate	NOUN
eurjchem-405	34	37	(	(	PUNCT
eurjchem-405	34	38	i‐prococl	i‐prococl	ADV
eurjchem-405	34	39	,	,	PUNCT
eurjchem-405	34	40	2	2	NUM
eurjchem-405	34	41	)	)	PUNCT
eurjchem-405	34	42	,	,	PUNCT
eurjchem-405	34	43	the	the	DET
eurjchem-405	34	44	observed	observed	ADJ
eurjchem-405	34	45	[	[	X
eurjchem-405	34	46	15,27,61	15,27,61	X
eurjchem-405	34	47	]	]	X
eurjchem-405	34	48	k2	k2	PROPN
eurjchem-405	34	49	/	/	SYM
eurjchem-405	34	50	ki‐procof	ki‐procof	PROPN
eurjchem-405	34	51	rate	rate	NOUN
eurjchem-405	34	52	ratio	ratio	NOUN
eurjchem-405	34	53	,	,	PUNCT
eurjchem-405	34	54	and	and	CCONJ
eurjchem-405	34	55	a	a	DET
eurjchem-405	34	56	consideration	consideration	NOUN
eurjchem-405	34	57	of	of	ADP
eurjchem-405	34	58	a	a	DET
eurjchem-405	34	59	previously	previously	ADV
eurjchem-405	34	60	reported	report	VERB
eurjchem-405	34	61	ksie	ksie	ADJ
eurjchem-405	34	62	value	value	NOUN
eurjchem-405	34	63	[	[	X
eurjchem-405	34	64	51	51	NUM
eurjchem-405	34	65	]	]	PUNCT
eurjchem-405	34	66	of	of	ADP
eurjchem-405	34	67	1.25	1.25	NUM
eurjchem-405	34	68	in	in	ADP
eurjchem-405	34	69	water	water	NOUN
eurjchem-405	34	70	,	,	PUNCT
eurjchem-405	34	71	it	it	PRON
eurjchem-405	34	72	was	be	AUX
eurjchem-405	34	73	shown	show	VERB
eurjchem-405	34	74	[	[	PUNCT
eurjchem-405	34	75	27	27	NUM
eurjchem-405	34	76	]	]	PUNCT
eurjchem-405	34	77	that	that	SCONJ
eurjchem-405	34	78	2	2	NUM
eurjchem-405	34	79	solvolyzes	solvolyze	NOUN
eurjchem-405	34	80	by	by	ADP
eurjchem-405	34	81	dual	dual	ADJ
eurjchem-405	34	82	channels	channel	NOUN
eurjchem-405	34	83	;	;	PUNCT
eurjchem-405	34	84	with	with	ADP
eurjchem-405	34	85	an	an	DET
eurjchem-405	34	86	addition‐elimination	addition‐elimination	NOUN
eurjchem-405	34	87	pathway	pathway	NOUN
eurjchem-405	34	88	being	be	AUX
eurjchem-405	34	89	dominant	dominant	ADJ
eurjchem-405	34	90	in	in	ADP
eurjchem-405	34	91	the	the	DET
eurjchem-405	34	92	more	more	ADV
eurjchem-405	34	93	nucleophilic	nucleophilic	ADJ
eurjchem-405	34	94	solvents	solvent	NOUN
eurjchem-405	34	95	and	and	CCONJ
eurjchem-405	34	96	a	a	DET
eurjchem-405	34	97	fragmentation‐ionization	fragmentation‐ionization	NOUN
eurjchem-405	34	98	mechanism	mechanism	NOUN
eurjchem-405	34	99	(	(	PUNCT
eurjchem-405	34	100	scheme	scheme	NOUN
eurjchem-405	34	101	2	2	NUM
eurjchem-405	34	102	)	)	PUNCT
eurjchem-405	34	103	proceeding	proceeding	NOUN
eurjchem-405	34	104	in	in	ADP
eurjchem-405	34	105	the	the	DET
eurjchem-405	34	106	strongly	strongly	ADV
eurjchem-405	34	107	hydrogen‐	hydrogen‐	NOUN
eurjchem-405	34	108	bonding	bonding	NOUN
eurjchem-405	34	109	(	(	PUNCT
eurjchem-405	34	110	ionizing	ionizing	NOUN
eurjchem-405	34	111	)	)	PUNCT
eurjchem-405	34	112	fluoroalcohols	fluoroalcohol	NOUN
eurjchem-405	34	113	.	.	PUNCT
eurjchem-405	35	1	replacement	replacement	NOUN
eurjchem-405	35	2	of	of	ADP
eurjchem-405	35	3	the	the	DET
eurjchem-405	35	4	ether	ether	ADJ
eurjchem-405	35	5	oxygen	oxygen	NOUN
eurjchem-405	35	6	in	in	ADP
eurjchem-405	35	7	2	2	NUM
eurjchem-405	35	8	with	with	ADP
eurjchem-405	35	9	sulfur	sulfur	NOUN
eurjchem-405	35	10	yields	yield	NOUN
eurjchem-405	35	11	isopropyl	isopropyl	NOUN
eurjchem-405	35	12	chlorothioformate	chlorothioformate	NOUN
eurjchem-405	35	13	(	(	PUNCT
eurjchem-405	35	14	i‐prscocl	i‐prscocl	NOUN
eurjchem-405	35	15	)	)	PUNCT
eurjchem-405	35	16	,	,	PUNCT
eurjchem-405	35	17	that	that	PRON
eurjchem-405	35	18	was	be	AUX
eurjchem-405	35	19	recently	recently	ADV
eurjchem-405	35	20	shown	show	VERB
eurjchem-405	35	21	[	[	PUNCT
eurjchem-405	35	22	34	34	NUM
eurjchem-405	35	23	]	]	PUNCT
eurjchem-405	35	24	to	to	PART
eurjchem-405	35	25	solvolyze	solvolyze	VERB
eurjchem-405	35	26	by	by	ADP
eurjchem-405	35	27	a	a	DET
eurjchem-405	35	28	dominant	dominant	ADJ
eurjchem-405	35	29	stepwise	stepwise	PROPN
eurjchem-405	35	30	sn1	sn1	PROPN
eurjchem-405	35	31	mechanism	mechanism	NOUN
eurjchem-405	35	32	with	with	ADP
eurjchem-405	35	33	moderate	moderate	ADJ
eurjchem-405	35	34	rear‐side	rear‐side	NOUN
eurjchem-405	35	35	nucleophilic	nucleophilic	ADJ
eurjchem-405	35	36	solvation	solvation	NOUN
eurjchem-405	35	37	of	of	ADP
eurjchem-405	35	38	the	the	DET
eurjchem-405	35	39	developing	develop	VERB
eurjchem-405	35	40	acylium	acylium	NOUN
eurjchem-405	35	41	ion	ion	NOUN
eurjchem-405	35	42	.	.	PUNCT
eurjchem-405	36	1	this	this	DET
eurjchem-405	36	2	conclusion	conclusion	NOUN
eurjchem-405	36	3	[	[	X
eurjchem-405	36	4	34	34	NUM
eurjchem-405	36	5	]	]	PUNCT
eurjchem-405	36	6	,	,	PUNCT
eurjchem-405	36	7	for	for	ADP
eurjchem-405	36	8	a	a	DET
eurjchem-405	36	9	dominant	dominant	ADJ
eurjchem-405	36	10	unimolecular	unimolecular	ADJ
eurjchem-405	36	11	pathway	pathway	NOUN
eurjchem-405	36	12	for	for	ADP
eurjchem-405	36	13	i‐prscocl	i‐prscocl	NOUN
eurjchem-405	36	14	in	in	ADP
eurjchem-405	36	15	all	all	DET
eurjchem-405	36	16	solvents	solvent	NOUN
eurjchem-405	36	17	except	except	SCONJ
eurjchem-405	36	18	100	100	NUM
eurjchem-405	36	19	%	%	NOUN
eurjchem-405	36	20	etoh	etoh	NOUN
eurjchem-405	36	21	,	,	PUNCT
eurjchem-405	36	22	occurred	occur	VERB
eurjchem-405	36	23	with	with	ADP
eurjchem-405	36	24	no	no	DET
eurjchem-405	36	25	alkyl‐sulfur	alkyl‐sulfur	NOUN
eurjchem-405	36	26	bond	bond	NOUN
eurjchem-405	36	27	fission	fission	NOUN
eurjchem-405	36	28	.	.	PUNCT
eurjchem-405	37	1	this	this	DET
eurjchem-405	37	2	proposal	proposal	NOUN
eurjchem-405	37	3	resulted	result	VERB
eurjchem-405	37	4	from	from	ADP
eurjchem-405	37	5	(	(	PUNCT
eurjchem-405	37	6	i	i	NOUN
eurjchem-405	37	7	)	)	PUNCT
eurjchem-405	37	8	a	a	DET
eurjchem-405	37	9	consideration	consideration	NOUN
eurjchem-405	37	10	that	that	PRON
eurjchem-405	37	11	queen	queen	NOUN
eurjchem-405	37	12	et	et	NOUN
eurjchem-405	37	13	al	al	PROPN
eurjchem-405	37	14	.	.	PUNCT
eurjchem-405	38	1	[	[	X
eurjchem-405	38	2	52	52	NUM
eurjchem-405	38	3	]	]	PUNCT
eurjchem-405	38	4	found	find	VERB
eurjchem-405	38	5	2‐propanethiol	2‐propanethiol	ADJ
eurjchem-405	38	6	as	as	ADP
eurjchem-405	38	7	the	the	DET
eurjchem-405	38	8	only	only	ADJ
eurjchem-405	38	9	product	product	NOUN
eurjchem-405	38	10	in	in	ADP
eurjchem-405	38	11	the	the	DET
eurjchem-405	38	12	hydrolysis	hydrolysis	NOUN
eurjchem-405	38	13	of	of	ADP
eurjchem-405	38	14	i‐prscocl	i‐prscocl	NUM
eurjchem-405	38	15	,	,	PUNCT
eurjchem-405	38	16	(	(	PUNCT
eurjchem-405	38	17	ii	ii	NOUN
eurjchem-405	38	18	)	)	PUNCT
eurjchem-405	38	19	the	the	DET
eurjchem-405	38	20	interpretation	interpretation	NOUN
eurjchem-405	38	21	of	of	ADP
eurjchem-405	38	22	the	the	DET
eurjchem-405	38	23	results	result	NOUN
eurjchem-405	38	24	obtained	obtain	VERB
eurjchem-405	38	25	from	from	ADP
eurjchem-405	38	26	the	the	DET
eurjchem-405	38	27	correlation	correlation	NOUN
eurjchem-405	38	28	analysis	analysis	NOUN
eurjchem-405	38	29	of	of	ADP
eurjchem-405	38	30	its	its	PRON
eurjchem-405	38	31	specific	specific	ADJ
eurjchem-405	38	32	rates	rate	NOUN
eurjchem-405	38	33	of	of	ADP
eurjchem-405	38	34	solvolysis	solvolysis	NOUN
eurjchem-405	38	35	using	use	VERB
eurjchem-405	38	36	equation	equation	NOUN
eurjchem-405	38	37	1	1	NUM
eurjchem-405	38	38	,	,	PUNCT
eurjchem-405	38	39	and	and	CCONJ
eurjchem-405	38	40	(	(	PUNCT
eurjchem-405	38	41	iii	iii	X
eurjchem-405	38	42	)	)	PUNCT
eurjchem-405	38	43	the	the	DET
eurjchem-405	38	44	responses	response	NOUN
eurjchem-405	38	45	of	of	ADP
eurjchem-405	38	46	the	the	DET
eurjchem-405	38	47	rscocl	rscocl	NOUN
eurjchem-405	38	48	/	/	SYM
eurjchem-405	38	49	rococl	rococl	NOUN
eurjchem-405	38	50	rate	rate	NOUN
eurjchem-405	38	51	ratios	ratio	NOUN
eurjchem-405	38	52	to	to	ADP
eurjchem-405	38	53	changes	change	NOUN
eurjchem-405	38	54	in	in	ADP
eurjchem-405	38	55	the	the	DET
eurjchem-405	38	56	r	r	NOUN
eurjchem-405	38	57	group	group	NOUN
eurjchem-405	38	58	.	.	PUNCT
eurjchem-405	39	1	phenyl	phenyl	NOUN
eurjchem-405	39	2	chloroformate	chloroformate	NOUN
eurjchem-405	39	3	(	(	PUNCT
eurjchem-405	39	4	3	3	NUM
eurjchem-405	39	5	,	,	PUNCT
eurjchem-405	39	6	phococl	phococl	NOUN
eurjchem-405	39	7	)	)	PUNCT
eurjchem-405	39	8	is	be	AUX
eurjchem-405	39	9	well	well	ADV
eurjchem-405	39	10	established	establish	VERB
eurjchem-405	39	11	[	[	PUNCT
eurjchem-405	39	12	2‐	2‐	NUM
eurjchem-405	39	13	34	34	NUM
eurjchem-405	39	14	]	]	PUNCT
eurjchem-405	39	15	as	as	SCONJ
eurjchem-405	39	16	undergoing	undergo	VERB
eurjchem-405	39	17	solvolysis	solvolysis	NOUN
eurjchem-405	39	18	proceeding	proceeding	NOUN
eurjchem-405	39	19	by	by	ADP
eurjchem-405	39	20	the	the	DET
eurjchem-405	39	21	addition‐	addition‐	ADJ
eurjchem-405	39	22	elimination	elimination	NOUN
eurjchem-405	39	23	(	(	PUNCT
eurjchem-405	39	24	tetrahedral	tetrahedral	ADJ
eurjchem-405	39	25	intermediate	intermediate	ADJ
eurjchem-405	39	26	)	)	PUNCT
eurjchem-405	39	27	type	type	NOUN
eurjchem-405	39	28	mechanism	mechanism	NOUN
eurjchem-405	39	29	with	with	ADP
eurjchem-405	39	30	the	the	DET
eurjchem-405	39	31	addition	addition	NOUN
eurjchem-405	39	32	step	step	NOUN
eurjchem-405	39	33	being	be	AUX
eurjchem-405	39	34	rate‐determining	rate‐determine	VERB
eurjchem-405	39	35	.	.	PUNCT
eurjchem-405	40	1	the	the	DET
eurjchem-405	40	2	observed	observed	ADJ
eurjchem-405	40	3	[	[	X
eurjchem-405	40	4	9,23	9,23	NOUN
eurjchem-405	40	5	]	]	X
eurjchem-405	40	6	l	l	NOUN
eurjchem-405	40	7	and	and	CCONJ
eurjchem-405	40	8	m	m	PROPN
eurjchem-405	40	9	values	value	NOUN
eurjchem-405	40	10	of	of	ADP
eurjchem-405	40	11	1.66	1.66	NUM
eurjchem-405	40	12	and	and	CCONJ
eurjchem-405	40	13	0.56	0.56	NUM
eurjchem-405	40	14	,	,	PUNCT
eurjchem-405	40	15	respectively	respectively	ADV
eurjchem-405	40	16	,	,	PUNCT
eurjchem-405	40	17	for	for	ADP
eurjchem-405	40	18	3	3	NUM
eurjchem-405	40	19	using	use	VERB
eurjchem-405	40	20	equation	equation	NOUN
eurjchem-405	40	21	1	1	NUM
eurjchem-405	40	22	,	,	PUNCT
eurjchem-405	40	23	are	be	AUX
eurjchem-405	40	24	now	now	ADV
eurjchem-405	40	25	recommended	recommend	VERB
eurjchem-405	40	26	as	as	ADP
eurjchem-405	40	27	standard	standard	ADJ
eurjchem-405	40	28	sensitivities	sensitivity	NOUN
eurjchem-405	40	29	[	[	X
eurjchem-405	40	30	2	2	X
eurjchem-405	40	31	]	]	PUNCT
eurjchem-405	40	32	for	for	ADP
eurjchem-405	40	33	attack	attack	NOUN
eurjchem-405	40	34	at	at	ADP
eurjchem-405	40	35	an	an	DET
eurjchem-405	40	36	sp2	sp2	NOUN
eurjchem-405	40	37	carbon	carbon	NOUN
eurjchem-405	40	38	(	(	PUNCT
eurjchem-405	40	39	acyl	acyl	NOUN
eurjchem-405	40	40	)	)	PUNCT
eurjchem-405	40	41	proceeding	proceeding	NOUN
eurjchem-405	40	42	by	by	ADP
eurjchem-405	40	43	the	the	DET
eurjchem-405	40	44	addition‐	addition‐	ADJ
eurjchem-405	40	45	elimination	elimination	NOUN
eurjchem-405	40	46	(	(	PUNCT
eurjchem-405	40	47	association‐dissociation	association‐dissociation	NOUN
eurjchem-405	40	48	)	)	PUNCT
eurjchem-405	40	49	mechanism	mechanism	NOUN
eurjchem-405	40	50	.	.	PUNCT
eurjchem-405	41	1	replacing	replace	VERB
eurjchem-405	41	2	both	both	CCONJ
eurjchem-405	41	3	electronegative	electronegative	ADJ
eurjchem-405	41	4	oxygens	oxygen	NOUN
eurjchem-405	41	5	in	in	ADP
eurjchem-405	41	6	3	3	NUM
eurjchem-405	41	7	with	with	ADP
eurjchem-405	41	8	a	a	DET
eurjchem-405	41	9	more	more	ADV
eurjchem-405	41	10	electropositive	electropositive	ADJ
eurjchem-405	41	11	sulfur	sulfur	NOUN
eurjchem-405	41	12	yields	yield	NOUN
eurjchem-405	41	13	phenyl	phenyl	NOUN
eurjchem-405	41	14	chlorodithioformate	chlorodithioformate	NOUN
eurjchem-405	41	15	(	(	PUNCT
eurjchem-405	41	16	phscscl	phscscl	PROPN
eurjchem-405	41	17	)	)	PUNCT
eurjchem-405	41	18	,	,	PUNCT
eurjchem-405	41	19	that	that	PRON
eurjchem-405	41	20	was	be	AUX
eurjchem-405	41	21	recently	recently	ADV
eurjchem-405	41	22	shown	show	VERB
eurjchem-405	41	23	to	to	PART
eurjchem-405	41	24	solvolyze	solvolyze	VERB
eurjchem-405	41	25	by	by	ADP
eurjchem-405	41	26	a	a	DET
eurjchem-405	41	27	dominant	dominant	ADJ
eurjchem-405	41	28	stepwise	stepwise	ADJ
eurjchem-405	41	29	unimolecular	unimolecular	ADJ
eurjchem-405	41	30	pathway	pathway	NOUN
eurjchem-405	41	31	(	(	PUNCT
eurjchem-405	41	32	sn1	sn1	PROPN
eurjchem-405	41	33	)	)	PUNCT
eurjchem-405	41	34	in	in	ADP
eurjchem-405	41	35	all	all	PRON
eurjchem-405	41	36	of	of	ADP
eurjchem-405	41	37	the	the	DET
eurjchem-405	41	38	solvents	solvent	NOUN
eurjchem-405	41	39	studied	study	VERB
eurjchem-405	41	40	[	[	X
eurjchem-405	41	41	23,30	23,30	NUM
eurjchem-405	41	42	]	]	PUNCT
eurjchem-405	41	43	.	.	PUNCT
eurjchem-405	42	1	using	use	VERB
eurjchem-405	42	2	equations	equation	NOUN
eurjchem-405	42	3	1	1	NUM
eurjchem-405	42	4	and	and	CCONJ
eurjchem-405	42	5	2	2	NUM
eurjchem-405	42	6	,	,	PUNCT
eurjchem-405	42	7	large	large	ADJ
eurjchem-405	42	8	sensitivities	sensitivity	NOUN
eurjchem-405	42	9	for	for	ADP
eurjchem-405	42	10	solvent	solvent	ADJ
eurjchem-405	42	11	nucleophilicity	nucleophilicity	NOUN
eurjchem-405	42	12	l	l	NOUN
eurjchem-405	42	13	of	of	ADP
eurjchem-405	42	14	0.69	0.69	NUM
eurjchem-405	42	15	and	and	CCONJ
eurjchem-405	42	16	0.80	0.80	NUM
eurjchem-405	42	17	were	be	AUX
eurjchem-405	42	18	obtained	obtain	VERB
eurjchem-405	42	19	,	,	PUNCT
eurjchem-405	42	20	and	and	CCONJ
eurjchem-405	42	21	values	value	NOUN
eurjchem-405	42	22	of	of	ADP
eurjchem-405	42	23	0.95	0.95	NUM
eurjchem-405	42	24	and	and	CCONJ
eurjchem-405	42	25	1.02	1.02	NUM
eurjchem-405	42	26	were	be	AUX
eurjchem-405	42	27	acquired	acquire	VERB
eurjchem-405	42	28	for	for	ADP
eurjchem-405	42	29	m	m	PROPN
eurjchem-405	42	30	[	[	X
eurjchem-405	42	31	23,30	23,30	NUM
eurjchem-405	42	32	]	]	X
eurjchem-405	42	33	.	.	PUNCT
eurjchem-405	43	1	furthermore	furthermore	ADV
eurjchem-405	43	2	,	,	PUNCT
eurjchem-405	43	3	with	with	ADP
eurjchem-405	43	4	equation	equation	NOUN
eurjchem-405	43	5	2	2	NUM
eurjchem-405	43	6	,	,	PUNCT
eurjchem-405	43	7	an	an	DET
eurjchem-405	43	8	h	h	NOUN
eurjchem-405	43	9	value	value	NOUN
eurjchem-405	43	10	of	of	ADP
eurjchem-405	43	11	0.42	0.42	NUM
eurjchem-405	43	12	±	±	NUM
eurjchem-405	43	13	0.15	0.15	NUM
eurjchem-405	43	14	signified	signify	VERB
eurjchem-405	43	15	that	that	SCONJ
eurjchem-405	43	16	there	there	PRON
eurjchem-405	43	17	was	be	VERB
eurjchem-405	43	18	minimal	minimal	ADJ
eurjchem-405	43	19	charge	charge	NOUN
eurjchem-405	43	20	dispersion	dispersion	NOUN
eurjchem-405	43	21	into	into	ADP
eurjchem-405	43	22	the	the	DET
eurjchem-405	43	23	aromatic	aromatic	ADJ
eurjchem-405	43	24	ring	ring	NOUN
eurjchem-405	43	25	during	during	ADP
eurjchem-405	43	26	the	the	DET
eurjchem-405	43	27	formation	formation	NOUN
eurjchem-405	43	28	of	of	ADP
eurjchem-405	43	29	the	the	DET
eurjchem-405	43	30	thioacylium	thioacylium	ADJ
eurjchem-405	43	31	transition	transition	NOUN
eurjchem-405	43	32	state	state	NOUN
eurjchem-405	43	33	that	that	PRON
eurjchem-405	43	34	was	be	AUX
eurjchem-405	43	35	stabilized	stabilize	VERB
eurjchem-405	43	36	by	by	ADP
eurjchem-405	43	37	intense	intense	ADJ
eurjchem-405	43	38	rear‐side	rear‐side	NOUN
eurjchem-405	43	39	nucleophilic	nucleophilic	ADJ
eurjchem-405	43	40	solvation	solvation	NOUN
eurjchem-405	43	41	(	(	PUNCT
eurjchem-405	43	42	as	as	SCONJ
eurjchem-405	43	43	indicated	indicate	VERB
eurjchem-405	43	44	by	by	ADP
eurjchem-405	43	45	the	the	DET
eurjchem-405	43	46	large	large	ADJ
eurjchem-405	43	47	l	l	NOUN
eurjchem-405	43	48	value	value	NOUN
eurjchem-405	43	49	)	)	PUNCT
eurjchem-405	43	50	.	.	PUNCT
eurjchem-405	44	1	these	these	DET
eurjchem-405	44	2	sensitivity	sensitivity	NOUN
eurjchem-405	44	3	values	value	NOUN
eurjchem-405	44	4	are	be	AUX
eurjchem-405	44	5	now	now	ADV
eurjchem-405	44	6	considered	consider	VERB
eurjchem-405	44	7	typical	typical	ADJ
eurjchem-405	44	8	[	[	X
eurjchem-405	44	9	2,7,23,27,29,30,33,34,49,56	2,7,23,27,29,30,33,34,49,56	NUM
eurjchem-405	44	10	]	]	PUNCT
eurjchem-405	44	11	for	for	ADP
eurjchem-405	44	12	substrates	substrate	NOUN
eurjchem-405	44	13	that	that	PRON
eurjchem-405	44	14	are	be	AUX
eurjchem-405	44	15	believed	believe	VERB
eurjchem-405	44	16	to	to	PART
eurjchem-405	44	17	solvolyze	solvolyze	VERB
eurjchem-405	44	18	with	with	ADP
eurjchem-405	44	19	the	the	DET
eurjchem-405	44	20	formation	formation	NOUN
eurjchem-405	44	21	of	of	ADP
eurjchem-405	44	22	an	an	DET
eurjchem-405	44	23	acylium	acylium	NOUN
eurjchem-405	44	24	or	or	CCONJ
eurjchem-405	44	25	a	a	DET
eurjchem-405	44	26	thioacylium	thioacylium	ADJ
eurjchem-405	44	27	ion	ion	NOUN
eurjchem-405	44	28	in	in	ADP
eurjchem-405	44	29	the	the	DET
eurjchem-405	44	30	transition	transition	NOUN
eurjchem-405	44	31	state	state	NOUN
eurjchem-405	44	32	.	.	PUNCT
eurjchem-405	45	1	the	the	DET
eurjchem-405	45	2	simplest	simple	ADJ
eurjchem-405	45	3	alkyl	alkyl	NOUN
eurjchem-405	45	4	chloroformate	chloroformate	NOUN
eurjchem-405	45	5	,	,	PUNCT
eurjchem-405	45	6	methyl	methyl	NOUN
eurjchem-405	45	7	chloroformate	chloroformate	NOUN
eurjchem-405	45	8	[	[	X
eurjchem-405	45	9	14	14	NUM
eurjchem-405	45	10	]	]	PUNCT
eurjchem-405	45	11	,	,	PUNCT
eurjchem-405	45	12	was	be	AUX
eurjchem-405	45	13	believed	believe	VERB
eurjchem-405	45	14	to	to	PART
eurjchem-405	45	15	solvolyze	solvolyze	VERB
eurjchem-405	45	16	by	by	ADP
eurjchem-405	45	17	a	a	DET
eurjchem-405	45	18	dominant	dominant	ADJ
eurjchem-405	45	19	bimolecular	bimolecular	ADJ
eurjchem-405	45	20	pathway	pathway	NOUN
eurjchem-405	45	21	(	(	PUNCT
eurjchem-405	45	22	addition‐elimination	addition‐elimination	NOUN
eurjchem-405	45	23	)	)	PUNCT
eurjchem-405	45	24	in	in	ADP
eurjchem-405	45	25	all	all	DET
eurjchem-405	45	26	solvents	solvent	NOUN
eurjchem-405	45	27	except	except	SCONJ
eurjchem-405	45	28	90	90	NUM
eurjchem-405	45	29	%	%	NOUN
eurjchem-405	45	30	hfip	hfip	NOUN
eurjchem-405	45	31	,	,	PUNCT
eurjchem-405	45	32	where	where	SCONJ
eurjchem-405	45	33	a	a	DET
eurjchem-405	45	34	superimposed	superimpose	VERB
eurjchem-405	45	35	ionization	ionization	NOUN
eurjchem-405	45	36	channel	channel	NOUN
eurjchem-405	45	37	was	be	AUX
eurjchem-405	45	38	proposed	propose	VERB
eurjchem-405	45	39	.	.	PUNCT
eurjchem-405	46	1	superimposed	superimpose	VERB
eurjchem-405	46	2	mechanisms	mechanism	NOUN
eurjchem-405	46	3	are	be	AUX
eurjchem-405	46	4	also	also	ADV
eurjchem-405	46	5	observed	observe	VERB
eurjchem-405	46	6	in	in	ADP
eurjchem-405	46	7	a	a	DET
eurjchem-405	46	8	wider	wide	ADJ
eurjchem-405	46	9	range	range	NOUN
eurjchem-405	46	10	of	of	ADP
eurjchem-405	46	11	solvents	solvent	NOUN
eurjchem-405	46	12	for	for	ADP
eurjchem-405	46	13	ethyl	ethyl	PROPN
eurjchem-405	47	1	[	[	X
eurjchem-405	47	2	12	12	NUM
eurjchem-405	47	3	]	]	PUNCT
eurjchem-405	47	4	,	,	PUNCT
eurjchem-405	47	5	n‐propyl	n‐propyl	PUNCT
eurjchem-405	48	1	[	[	X
eurjchem-405	48	2	20	20	NUM
eurjchem-405	48	3	]	]	PUNCT
eurjchem-405	48	4	,	,	PUNCT
eurjchem-405	48	5	and	and	CCONJ
eurjchem-405	48	6	n‐octyl	n‐octyl	PUNCT
eurjchem-405	49	1	[	[	X
eurjchem-405	49	2	18	18	NUM
eurjchem-405	49	3	]	]	PUNCT
eurjchem-405	49	4	chloroformate	chloroformate	ADJ
eurjchem-405	49	5	esters	ester	NOUN
eurjchem-405	49	6	.	.	PUNCT
eurjchem-405	50	1	scheme	scheme	NOUN
eurjchem-405	50	2	3	3	NUM
eurjchem-405	50	3	in	in	ADP
eurjchem-405	50	4	theory	theory	NOUN
eurjchem-405	50	5	,	,	PUNCT
eurjchem-405	50	6	it	it	PRON
eurjchem-405	50	7	should	should	AUX
eurjchem-405	50	8	be	be	AUX
eurjchem-405	50	9	possible	possible	ADJ
eurjchem-405	50	10	for	for	SCONJ
eurjchem-405	50	11	1	1	NUM
eurjchem-405	50	12	to	to	PART
eurjchem-405	50	13	undergo	undergo	VERB
eurjchem-405	50	14	solvolytic	solvolytic	ADJ
eurjchem-405	50	15	displacement	displacement	NOUN
eurjchem-405	50	16	in	in	ADP
eurjchem-405	50	17	a	a	DET
eurjchem-405	50	18	stepwise	stepwise	ADJ
eurjchem-405	50	19	unimolecular	unimolecular	NOUN
eurjchem-405	50	20	(	(	PUNCT
eurjchem-405	50	21	sn1	sn1	PROPN
eurjchem-405	50	22	)	)	PUNCT
eurjchem-405	50	23	fashion	fashion	NOUN
eurjchem-405	50	24	with	with	ADP
eurjchem-405	50	25	the	the	DET
eurjchem-405	50	26	formation	formation	NOUN
eurjchem-405	50	27	of	of	ADP
eurjchem-405	50	28	a	a	DET
eurjchem-405	50	29	resonance	resonance	NOUN
eurjchem-405	50	30	stabilized	stabilize	VERB
eurjchem-405	50	31	sp‐hybridized	sp‐hybridize	VERB
eurjchem-405	50	32	acylium	acylium	NOUN
eurjchem-405	50	33	ion	ion	NOUN
eurjchem-405	50	34	intermediate	intermediate	ADJ
eurjchem-405	50	35	(	(	PUNCT
eurjchem-405	50	36	scheme	scheme	NOUN
eurjchem-405	50	37	3	3	NUM
eurjchem-405	50	38	)	)	PUNCT
eurjchem-405	50	39	.	.	PUNCT
eurjchem-405	51	1	also	also	ADV
eurjchem-405	51	2	,	,	PUNCT
eurjchem-405	51	3	it	it	PRON
eurjchem-405	51	4	was	be	AUX
eurjchem-405	51	5	demonstrated	demonstrate	VERB
eurjchem-405	51	6	[	[	X
eurjchem-405	51	7	2,12,14,15,18,20,21,23‐27	2,12,14,15,18,20,21,23‐27	X
eurjchem-405	51	8	]	]	X
eurjchem-405	51	9	that	that	SCONJ
eurjchem-405	51	10	dual	dual	ADJ
eurjchem-405	51	11	reaction	reaction	NOUN
eurjchem-405	51	12	channels	channel	NOUN
eurjchem-405	51	13	occurring	occur	VERB
eurjchem-405	51	14	simultaneously	simultaneously	ADV
eurjchem-405	51	15	in	in	ADP
eurjchem-405	51	16	a	a	DET
eurjchem-405	51	17	side‐by‐side	side‐by‐side	ADJ
eurjchem-405	51	18	fashion	fashion	NOUN
eurjchem-405	51	19	are	be	AUX
eurjchem-405	51	20	possible	possible	ADJ
eurjchem-405	51	21	in	in	ADP
eurjchem-405	51	22	some	some	DET
eurjchem-405	51	23	alkyl	alkyl	NOUN
eurjchem-405	51	24	and	and	CCONJ
eurjchem-405	51	25	aryl	aryl	NOUN
eurjchem-405	51	26	chloroformate	chloroformate	NOUN
eurjchem-405	51	27	esters	ester	NOUN
eurjchem-405	51	28	,	,	PUNCT
eurjchem-405	51	29	and	and	CCONJ
eurjchem-405	51	30	that	that	SCONJ
eurjchem-405	51	31	the	the	DET
eurjchem-405	51	32	highly	highly	ADV
eurjchem-405	51	33	ionizing	ionizing	ADJ
eurjchem-405	51	34	aqueous	aqueous	ADJ
eurjchem-405	51	35	2,2,2,‐trifluoethanol	2,2,2,‐trifluoethanol	NOUN
eurjchem-405	51	36	(	(	PUNCT
eurjchem-405	51	37	tfe	tfe	NOUN
eurjchem-405	51	38	)	)	PUNCT
eurjchem-405	51	39	and	and	CCONJ
eurjchem-405	51	40	1,1,1,3,3,3,‐	1,1,1,3,3,3,‐	NUM
eurjchem-405	51	41	hexafluoro‐2‐propanol	hexafluoro‐2‐propanol	PROPN
eurjchem-405	51	42	(	(	PUNCT
eurjchem-405	51	43	hfip	hfip	NOUN
eurjchem-405	51	44	)	)	PUNCT
eurjchem-405	51	45	mixtures	mixture	NOUN
eurjchem-405	51	46	are	be	AUX
eurjchem-405	51	47	shown	show	VERB
eurjchem-405	51	48	[	[	PUNCT
eurjchem-405	51	49	2,3,6‐	2,3,6‐	NUM
eurjchem-405	51	50	49,55,56,71‐74	49,55,56,71‐74	NUM
eurjchem-405	51	51	]	]	PUNCT
eurjchem-405	51	52	to	to	PART
eurjchem-405	51	53	be	be	AUX
eurjchem-405	51	54	extremely	extremely	ADV
eurjchem-405	51	55	important	important	ADJ
eurjchem-405	51	56	for	for	ADP
eurjchem-405	51	57	meaningful	meaningful	ADJ
eurjchem-405	51	58	treatments	treatment	NOUN
eurjchem-405	51	59	leading	lead	VERB
eurjchem-405	51	60	to	to	ADP
eurjchem-405	51	61	analyses	analysis	NOUN
eurjchem-405	51	62	using	use	VERB
eurjchem-405	51	63	the	the	DET
eurjchem-405	51	64	grunwald‐winstein	grunwald‐winstein	ADJ
eurjchem-405	51	65	equations	equation	NOUN
eurjchem-405	51	66	.	.	PUNCT
eurjchem-405	52	1	to	to	PART
eurjchem-405	52	2	probe	probe	VERB
eurjchem-405	52	3	the	the	DET
eurjchem-405	52	4	possibility	possibility	NOUN
eurjchem-405	52	5	of	of	ADP
eurjchem-405	52	6	an	an	DET
eurjchem-405	52	7	ionization	ionization	NOUN
eurjchem-405	52	8	pathway	pathway	NOUN
eurjchem-405	52	9	for	for	ADP
eurjchem-405	52	10	1	1	NUM
eurjchem-405	52	11	,	,	PUNCT
eurjchem-405	52	12	we	we	PRON
eurjchem-405	52	13	have	have	AUX
eurjchem-405	52	14	raised	raise	VERB
eurjchem-405	52	15	the	the	DET
eurjchem-405	52	16	temperatures	temperature	NOUN
eurjchem-405	52	17	(	(	PUNCT
eurjchem-405	52	18	so	so	SCONJ
eurjchem-405	52	19	that	that	SCONJ
eurjchem-405	52	20	the	the	DET
eurjchem-405	52	21	kinetic	kinetic	NOUN
eurjchem-405	52	22	runs	run	NOUN
eurjchem-405	52	23	could	could	AUX
eurjchem-405	52	24	be	be	AUX
eurjchem-405	52	25	followed	follow	VERB
eurjchem-405	52	26	within	within	ADP
eurjchem-405	52	27	a	a	DET
eurjchem-405	52	28	reasonable	reasonable	ADJ
eurjchem-405	52	29	time	time	NOUN
eurjchem-405	52	30	frame	frame	NOUN
eurjchem-405	52	31	)	)	PUNCT
eurjchem-405	52	32	and	and	CCONJ
eurjchem-405	52	33	have	have	AUX
eurjchem-405	52	34	included	include	VERB
eurjchem-405	52	35	16	16	NUM
eurjchem-405	52	36	specific	specific	ADJ
eurjchem-405	52	37	rates	rate	NOUN
eurjchem-405	52	38	of	of	ADP
eurjchem-405	52	39	solvolysis	solvolysis	NOUN
eurjchem-405	52	40	in	in	ADP
eurjchem-405	52	41	six	six	NUM
eurjchem-405	52	42	solvents	solvent	NOUN
eurjchem-405	52	43	with	with	ADP
eurjchem-405	52	44	strong	strong	ADJ
eurjchem-405	52	45	hydrogen	hydrogen	NOUN
eurjchem-405	52	46	bonding	bonding	NOUN
eurjchem-405	52	47	(	(	PUNCT
eurjchem-405	52	48	highly	highly	ADV
eurjchem-405	52	49	ionizing	ionizing	NOUN
eurjchem-405	52	50	)	)	PUNCT
eurjchem-405	52	51	fluoroalcohol	fluoroalcohol	ADJ
eurjchem-405	52	52	components	component	NOUN
eurjchem-405	52	53	in	in	ADP
eurjchem-405	52	54	table	table	NOUN
eurjchem-405	52	55	1	1	NUM
eurjchem-405	52	56	.	.	PUNCT
eurjchem-405	53	1	additionally	additionally	ADV
eurjchem-405	53	2	,	,	PUNCT
eurjchem-405	53	3	we	we	PRON
eurjchem-405	53	4	report	report	VERB
eurjchem-405	53	5	the	the	DET
eurjchem-405	53	6	arrhenius	arrhenius	NOUN
eurjchem-405	53	7	activation	activation	NOUN
eurjchem-405	53	8	parameters	parameter	NOUN
eurjchem-405	53	9	(	(	PUNCT
eurjchem-405	53	10	∆h≠	∆h≠	PROPN
eurjchem-405	53	11	,	,	PUNCT
eurjchem-405	53	12	∆s≠	∆s≠	PROPN
eurjchem-405	53	13	)	)	PUNCT
eurjchem-405	53	14	at	at	ADP
eurjchem-405	53	15	25.0	25.0	NUM
eurjchem-405	53	16	oc	oc	NOUN
eurjchem-405	53	17	for	for	ADP
eurjchem-405	53	18	5	5	NUM
eurjchem-405	53	19	of	of	ADP
eurjchem-405	53	20	the	the	DET
eurjchem-405	53	21	fluoroalcohol	fluoroalcohol	ADJ
eurjchem-405	53	22	mixtures	mixture	NOUN
eurjchem-405	53	23	studied	study	VERB
eurjchem-405	53	24	,	,	PUNCT
eurjchem-405	53	25	and	and	CCONJ
eurjchem-405	53	26	a	a	DET
eurjchem-405	53	27	further	further	ADJ
eurjchem-405	53	28	eight	eight	NUM
eurjchem-405	53	29	additional	additional	ADJ
eurjchem-405	53	30	specific	specific	ADJ
eurjchem-405	53	31	rates	rate	NOUN
eurjchem-405	53	32	of	of	ADP
eurjchem-405	53	33	solvolysis	solvolysis	NOUN
eurjchem-405	53	34	in	in	ADP
eurjchem-405	53	35	aqueous	aqueous	ADJ
eurjchem-405	53	36	alcohols	alcohol	NOUN
eurjchem-405	53	37	.	.	PUNCT
eurjchem-405	54	1	2	2	X
eurjchem-405	54	2	.	.	X
eurjchem-405	54	3	experimental	experimental	ADJ
eurjchem-405	54	4	the	the	DET
eurjchem-405	54	5	isopropenyl	isopropenyl	ADJ
eurjchem-405	54	6	chloroformate	chloroformate	NOUN
eurjchem-405	54	7	(	(	PUNCT
eurjchem-405	54	8	95	95	NUM
eurjchem-405	54	9	%	%	NOUN
eurjchem-405	54	10	,	,	PUNCT
eurjchem-405	54	11	sigma‐aldrich	sigma‐aldrich	PRON
eurjchem-405	54	12	)	)	PUNCT
eurjchem-405	54	13	was	be	AUX
eurjchem-405	54	14	used	use	VERB
eurjchem-405	54	15	as	as	SCONJ
eurjchem-405	54	16	received	receive	VERB
eurjchem-405	54	17	.	.	PUNCT
eurjchem-405	55	1	solvents	solvent	NOUN
eurjchem-405	55	2	were	be	AUX
eurjchem-405	55	3	purified	purify	VERB
eurjchem-405	55	4	and	and	CCONJ
eurjchem-405	55	5	the	the	DET
eurjchem-405	55	6	kinetic	kinetic	ADJ
eurjchem-405	55	7	runs	run	NOUN
eurjchem-405	55	8	carried	carry	VERB
eurjchem-405	55	9	out	out	ADP
eurjchem-405	55	10	as	as	SCONJ
eurjchem-405	55	11	described	describe	VERB
eurjchem-405	55	12	previously	previously	ADV
eurjchem-405	55	13	[	[	X
eurjchem-405	55	14	9	9	NUM
eurjchem-405	55	15	]	]	PUNCT
eurjchem-405	55	16	.	.	PUNCT
eurjchem-405	56	1	a	a	DET
eurjchem-405	56	2	substrate	substrate	NOUN
eurjchem-405	56	3	concentration	concentration	NOUN
eurjchem-405	56	4	of	of	ADP
eurjchem-405	56	5	approximately	approximately	ADV
eurjchem-405	56	6	0.005	0.005	NUM
eurjchem-405	56	7	m	m	NOUN
eurjchem-405	56	8	in	in	ADP
eurjchem-405	56	9	a	a	DET
eurjchem-405	56	10	variety	variety	NOUN
eurjchem-405	56	11	of	of	ADP
eurjchem-405	56	12	solvents	solvent	NOUN
eurjchem-405	56	13	was	be	AUX
eurjchem-405	56	14	employed	employ	VERB
eurjchem-405	56	15	.	.	PUNCT
eurjchem-405	57	1	for	for	SCONJ
eurjchem-405	57	2	some	some	PRON
eurjchem-405	57	3	of	of	ADP
eurjchem-405	57	4	the	the	DET
eurjchem-405	57	5	runs	run	NOUN
eurjchem-405	57	6	,	,	PUNCT
eurjchem-405	57	7	calculation	calculation	NOUN
eurjchem-405	57	8	of	of	ADP
eurjchem-405	57	9	the	the	DET
eurjchem-405	57	10	specific	specific	ADJ
eurjchem-405	57	11	rates	rate	NOUN
eurjchem-405	57	12	of	of	ADP
eurjchem-405	57	13	solvolysis	solvolysis	NOUN
eurjchem-405	57	14	(	(	PUNCT
eurjchem-405	57	15	first‐order	first‐order	NOUN
eurjchem-405	57	16	rate	rate	NOUN
eurjchem-405	57	17	coefficients	coefficient	NOUN
eurjchem-405	57	18	)	)	PUNCT
eurjchem-405	57	19	was	be	AUX
eurjchem-405	57	20	carried	carry	VERB
eurjchem-405	57	21	out	out	ADP
eurjchem-405	57	22	by	by	ADP
eurjchem-405	57	23	a	a	DET
eurjchem-405	57	24	process	process	NOUN
eurjchem-405	57	25	in	in	ADP
eurjchem-405	57	26	which	which	PRON
eurjchem-405	57	27	the	the	DET
eurjchem-405	57	28	conventional	conventional	ADJ
eurjchem-405	57	29	guggenheim	guggenheim	PROPN
eurjchem-405	57	30	treatment	treatment	NOUN
eurjchem-405	57	31	was	be	AUX
eurjchem-405	57	32	modified	modify	VERB
eurjchem-405	57	33	so	so	SCONJ
eurjchem-405	57	34	as	as	SCONJ
eurjchem-405	57	35	to	to	PART
eurjchem-405	57	36	give	give	VERB
eurjchem-405	57	37	an	an	DET
eurjchem-405	57	38	estimate	estimate	NOUN
eurjchem-405	57	39	of	of	ADP
eurjchem-405	57	40	the	the	DET
eurjchem-405	57	41	infinity	infinity	NOUN
eurjchem-405	57	42	titer	titer	NOUN
eurjchem-405	57	43	,	,	PUNCT
eurjchem-405	57	44	which	which	PRON
eurjchem-405	57	45	was	be	AUX
eurjchem-405	57	46	then	then	ADV
eurjchem-405	57	47	used	use	VERB
eurjchem-405	57	48	to	to	PART
eurjchem-405	57	49	calculate	calculate	VERB
eurjchem-405	57	50	for	for	ADP
eurjchem-405	57	51	each	each	DET
eurjchem-405	57	52	run	run	NOUN
eurjchem-405	57	53	a	a	DET
eurjchem-405	57	54	series	series	NOUN
eurjchem-405	57	55	of	of	ADP
eurjchem-405	57	56	integrated	integrate	VERB
eurjchem-405	57	57	rate	rate	NOUN
eurjchem-405	57	58	coefficients	coefficient	NOUN
eurjchem-405	57	59	[	[	X
eurjchem-405	57	60	25	25	NUM
eurjchem-405	57	61	]	]	PUNCT
eurjchem-405	57	62	.	.	PUNCT
eurjchem-405	58	1	the	the	DET
eurjchem-405	58	2	specific	specific	ADJ
eurjchem-405	58	3	rates	rate	NOUN
eurjchem-405	58	4	and	and	CCONJ
eurjchem-405	58	5	associated	associate	VERB
eurjchem-405	58	6	standard	standard	ADJ
eurjchem-405	58	7	deviations	deviation	NOUN
eurjchem-405	58	8	,	,	PUNCT
eurjchem-405	58	9	as	as	SCONJ
eurjchem-405	58	10	presented	present	VERB
eurjchem-405	58	11	in	in	ADP
eurjchem-405	58	12	table	table	NOUN
eurjchem-405	58	13	1	1	NUM
eurjchem-405	58	14	,	,	PUNCT
eurjchem-405	58	15	are	be	AUX
eurjchem-405	58	16	obtained	obtain	VERB
eurjchem-405	58	17	by	by	ADP
eurjchem-405	58	18	averaging	average	VERB
eurjchem-405	58	19	all	all	PRON
eurjchem-405	58	20	of	of	ADP
eurjchem-405	58	21	the	the	DET
eurjchem-405	58	22	values	value	NOUN
eurjchem-405	58	23	from	from	ADP
eurjchem-405	58	24	,	,	PUNCT
eurjchem-405	58	25	at	at	ADP
eurjchem-405	58	26	least	least	ADJ
eurjchem-405	58	27	,	,	PUNCT
eurjchem-405	58	28	duplicate	duplicate	ADJ
eurjchem-405	58	29	runs	run	NOUN
eurjchem-405	58	30	.	.	PUNCT
eurjchem-405	59	1	multiple	multiple	ADJ
eurjchem-405	59	2	regression	regression	NOUN
eurjchem-405	59	3	analyses	analysis	NOUN
eurjchem-405	59	4	were	be	AUX
eurjchem-405	59	5	carried	carry	VERB
eurjchem-405	59	6	out	out	ADP
eurjchem-405	59	7	using	use	VERB
eurjchem-405	59	8	the	the	DET
eurjchem-405	59	9	excel	excel	PROPN
eurjchem-405	59	10	2007	2007	NUM
eurjchem-405	59	11	package	package	NOUN
eurjchem-405	59	12	from	from	ADP
eurjchem-405	59	13	the	the	DET
eurjchem-405	59	14	microsoft	microsoft	PROPN
eurjchem-405	59	15	corporation	corporation	NOUN
eurjchem-405	59	16	,	,	PUNCT
eurjchem-405	59	17	and	and	CCONJ
eurjchem-405	59	18	the	the	DET
eurjchem-405	59	19	sigmaplot	sigmaplot	ADJ
eurjchem-405	59	20	9.0	9.0	NUM
eurjchem-405	59	21	software	software	NOUN
eurjchem-405	59	22	version	version	NOUN
eurjchem-405	59	23	from	from	ADP
eurjchem-405	59	24	systat	systat	PROPN
eurjchem-405	59	25	software	software	PROPN
eurjchem-405	59	26	,	,	PUNCT
eurjchem-405	59	27	inc	inc	PROPN
eurjchem-405	59	28	.	.	PROPN
eurjchem-405	59	29	,	,	PUNCT
eurjchem-405	59	30	san	san	PROPN
eurjchem-405	59	31	jose	jose	PROPN
eurjchem-405	59	32	,	,	PUNCT
eurjchem-405	59	33	ca	ca	PROPN
eurjchem-405	59	34	,	,	PUNCT
eurjchem-405	59	35	was	be	AUX
eurjchem-405	59	36	used	use	VERB
eurjchem-405	59	37	for	for	ADP
eurjchem-405	59	38	the	the	DET
eurjchem-405	59	39	guggenheim	guggenheim	PROPN
eurjchem-405	59	40	treatments	treatment	NOUN
eurjchem-405	59	41	.	.	PUNCT
eurjchem-405	60	1	3	3	X
eurjchem-405	60	2	.	.	NOUN
eurjchem-405	60	3	results	result	NOUN
eurjchem-405	60	4	and	and	CCONJ
eurjchem-405	60	5	discussion	discussion	VERB
eurjchem-405	60	6	the	the	DET
eurjchem-405	60	7	solvolytic	solvolytic	ADJ
eurjchem-405	60	8	rate	rate	NOUN
eurjchem-405	60	9	constants	constant	NOUN
eurjchem-405	60	10	for	for	ADP
eurjchem-405	60	11	1	1	NUM
eurjchem-405	60	12	in	in	ADP
eurjchem-405	60	13	100‐80	100‐80	NUM
eurjchem-405	60	14	%	%	NOUN
eurjchem-405	60	15	meoh	meoh	NOUN
eurjchem-405	60	16	and	and	CCONJ
eurjchem-405	60	17	100‐80	100‐80	ADJ
eurjchem-405	60	18	%	%	NOUN
eurjchem-405	60	19	etoh	etoh	NOUN
eurjchem-405	60	20	at	at	ADP
eurjchem-405	60	21	10.0	10.0	NUM
eurjchem-405	60	22	oc	oc	PRON
eurjchem-405	60	23	reported	report	VERB
eurjchem-405	60	24	in	in	ADP
eurjchem-405	60	25	table	table	NOUN
eurjchem-405	60	26	1	1	NUM
eurjchem-405	60	27	are	be	AUX
eurjchem-405	60	28	within	within	ADP
eurjchem-405	60	29	the	the	DET
eurjchem-405	60	30	threshold	threshold	NOUN
eurjchem-405	60	31	of	of	ADP
eurjchem-405	60	32	acceptable	acceptable	ADJ
eurjchem-405	60	33	experimental	experimental	ADJ
eurjchem-405	60	34	error	error	NOUN
eurjchem-405	60	35	from	from	ADP
eurjchem-405	60	36	the	the	DET
eurjchem-405	60	37	previously	previously	ADV
eurjchem-405	60	38	reported	report	VERB
eurjchem-405	60	39	[	[	X
eurjchem-405	60	40	22	22	NUM
eurjchem-405	60	41	]	]	PUNCT
eurjchem-405	60	42	rate	rate	NOUN
eurjchem-405	60	43	values	value	NOUN
eurjchem-405	60	44	of	of	ADP
eurjchem-405	60	45	1	1	NUM
eurjchem-405	60	46	in	in	ADP
eurjchem-405	60	47	these	these	DET
eurjchem-405	60	48	solvents	solvent	NOUN
eurjchem-405	60	49	.	.	PUNCT
eurjchem-405	61	1	additional	additional	ADJ
eurjchem-405	61	2	alcoholysis	alcoholysis	NOUN
eurjchem-405	61	3	values	value	NOUN
eurjchem-405	61	4	at	at	ADP
eurjchem-405	61	5	25.0	25.0	NUM
eurjchem-405	61	6	oc	oc	NOUN
eurjchem-405	61	7	were	be	AUX
eurjchem-405	61	8	obtained	obtain	VERB
eurjchem-405	61	9	for	for	ADP
eurjchem-405	61	10	meoh	meoh	NOUN
eurjchem-405	61	11	and	and	CCONJ
eurjchem-405	61	12	etoh	etoh	NOUN
eurjchem-405	61	13	,	,	PUNCT
eurjchem-405	61	14	132	132	NUM
eurjchem-405	61	15	d’souza	d’souza	NOUN
eurjchem-405	61	16	et	et	PROPN
eurjchem-405	61	17	al	al	PROPN
eurjchem-405	61	18	.	.	PUNCT
eurjchem-405	61	19	/	/	SYM
eurjchem-405	61	20	european	european	PROPN
eurjchem-405	61	21	journal	journal	PROPN
eurjchem-405	61	22	of	of	ADP
eurjchem-405	61	23	chemistry	chemistry	NOUN
eurjchem-405	61	24	2	2	NUM
eurjchem-405	61	25	(	(	PUNCT
eurjchem-405	61	26	2	2	NUM
eurjchem-405	61	27	)	)	PUNCT
eurjchem-405	61	28	(	(	PUNCT
eurjchem-405	61	29	2011	2011	NUM
eurjchem-405	61	30	)	)	PUNCT
eurjchem-405	61	31	130‐135	130‐135	NOUN
eurjchem-405	61	32	table	table	NOUN
eurjchem-405	61	33	1	1	NUM
eurjchem-405	61	34	.	.	PUNCT
eurjchem-405	61	35	specific	specific	ADJ
eurjchem-405	61	36	rates	rate	NOUN
eurjchem-405	61	37	of	of	ADP
eurjchem-405	61	38	solvolysis	solvolysis	NOUN
eurjchem-405	61	39	(	(	PUNCT
eurjchem-405	61	40	k	k	NOUN
eurjchem-405	61	41	)	)	PUNCT
eurjchem-405	61	42	of	of	ADP
eurjchem-405	61	43	1	1	NUM
eurjchem-405	61	44	,	,	PUNCT
eurjchem-405	61	45	in	in	ADP
eurjchem-405	61	46	several	several	ADJ
eurjchem-405	61	47	pure	pure	ADJ
eurjchem-405	61	48	and	and	CCONJ
eurjchem-405	61	49	binary	binary	ADJ
eurjchem-405	61	50	solvents	solvent	NOUN
eurjchem-405	61	51	at	at	ADP
eurjchem-405	61	52	10.0	10.0	NUM
eurjchem-405	61	53	oc	oc	NOUN
eurjchem-405	61	54	,	,	PUNCT
eurjchem-405	61	55	25.0	25.0	NUM
eurjchem-405	61	56	oc	oc	NOUN
eurjchem-405	61	57	,	,	PUNCT
eurjchem-405	61	58	45.0	45.0	NUM
eurjchem-405	61	59	oc	oc	NOUN
eurjchem-405	61	60	,	,	PUNCT
eurjchem-405	61	61	55.0	55.0	NUM
eurjchem-405	61	62	oc	oc	NOUN
eurjchem-405	61	63	,	,	PUNCT
eurjchem-405	61	64	and	and	CCONJ
eurjchem-405	61	65	65.0	65.0	NUM
eurjchem-405	61	66	oc	oc	NOUN
eurjchem-405	61	67	.	.	PUNCT
eurjchem-405	61	68	solvent	solvent	NOUN
eurjchem-405	61	69	(	(	PUNCT
eurjchem-405	61	70	%	%	INTJ
eurjchem-405	61	71	)	)	PUNCT
eurjchem-405	61	72	a	a	DET
eurjchem-405	61	73	1	1	NUM
eurjchem-405	61	74	@	@	ADP
eurjchem-405	61	75	10.0	10.0	NUM
eurjchem-405	61	76	oc	oc	NOUN
eurjchem-405	61	77	;	;	PUNCT
eurjchem-405	61	78	105k	105k	PROPN
eurjchem-405	61	79	,	,	PUNCT
eurjchem-405	61	80	s‐1b	s‐1b	PROPN
eurjchem-405	61	81	1	1	NUM
eurjchem-405	61	82	@	@	ADP
eurjchem-405	61	83	25.0	25.0	NUM
eurjchem-405	61	84	oc	oc	NOUN
eurjchem-405	61	85	;	;	PUNCT
eurjchem-405	61	86	105k	105k	PROPN
eurjchem-405	61	87	,	,	PUNCT
eurjchem-405	61	88	s‐1b	s‐1b	PROPN
eurjchem-405	61	89	1	1	NUM
eurjchem-405	61	90	@	@	ADP
eurjchem-405	61	91	45.0	45.0	NUM
eurjchem-405	61	92	oc	oc	NOUN
eurjchem-405	61	93	;	;	PUNCT
eurjchem-405	61	94	105k	105k	PROPN
eurjchem-405	61	95	,	,	PUNCT
eurjchem-405	61	96	s‐1b	s‐1b	PROPN
eurjchem-405	61	97	1	1	NUM
eurjchem-405	61	98	@	@	ADP
eurjchem-405	61	99	55.0	55.0	NUM
eurjchem-405	61	100	oc	oc	NOUN
eurjchem-405	61	101	;	;	PUNCT
eurjchem-405	61	102	105k	105k	PROPN
eurjchem-405	61	103	,	,	PUNCT
eurjchem-405	61	104	s‐1b	s‐1b	PROPN
eurjchem-405	61	105	1	1	NUM
eurjchem-405	61	106	@	@	ADP
eurjchem-405	61	107	65.0	65.0	NUM
eurjchem-405	61	108	oc	oc	NOUN
eurjchem-405	61	109	;	;	PUNCT
eurjchem-405	61	110	105k	105k	PROPN
eurjchem-405	61	111	,	,	PUNCT
eurjchem-405	61	112	s‐1b	s‐1b	PROPN
eurjchem-405	61	113	100	100	NUM
eurjchem-405	61	114	%	%	NOUN
eurjchem-405	61	115	meohc	meohc	NOUN
eurjchem-405	61	116	69.2	69.2	NUM
eurjchem-405	61	117	±	±	NUM
eurjchem-405	61	118	3.7	3.7	NUM
eurjchem-405	61	119	210	210	NUM
eurjchem-405	61	120	±	±	NUM
eurjchem-405	61	121	8	8	NUM
eurjchem-405	61	122	90	90	NUM
eurjchem-405	61	123	%	%	NOUN
eurjchem-405	61	124	meohd	meohd	NOUN
eurjchem-405	61	125	146	146	NUM
eurjchem-405	61	126	±	±	NUM
eurjchem-405	61	127	5	5	NUM
eurjchem-405	61	128	80	80	NUM
eurjchem-405	61	129	%	%	NOUN
eurjchem-405	61	130	meohe	meohe	ADJ
eurjchem-405	61	131	149	149	NUM
eurjchem-405	61	132	±	±	NUM
eurjchem-405	61	133	7	7	NUM
eurjchem-405	61	134	100	100	NUM
eurjchem-405	61	135	%	%	NOUN
eurjchem-405	61	136	etohf	etohf	NOUN
eurjchem-405	61	137	110	110	NUM
eurjchem-405	61	138	±	±	NUM
eurjchem-405	61	139	6	6	NUM
eurjchem-405	61	140	90	90	NUM
eurjchem-405	61	141	%	%	NOUN
eurjchem-405	61	142	etohg	etohg	NOUN
eurjchem-405	61	143	45.6	45.6	NUM
eurjchem-405	61	144	±	±	NUM
eurjchem-405	61	145	2.2	2.2	NUM
eurjchem-405	61	146	80	80	NUM
eurjchem-405	61	147	%	%	NOUN
eurjchem-405	61	148	etohh	etohh	ADV
eurjchem-405	62	1	49.8	49.8	NUM
eurjchem-405	62	2	±	±	NUM
eurjchem-405	62	3	1.3	1.3	NUM
eurjchem-405	62	4	97	97	NUM
eurjchem-405	62	5	%	%	NOUN
eurjchem-405	62	6	tfe	tfe	NOUN
eurjchem-405	62	7	(	(	PUNCT
eurjchem-405	62	8	w	w	NOUN
eurjchem-405	62	9	/	/	SYM
eurjchem-405	62	10	w)i	w)i	NOUN
eurjchem-405	62	11	0.0242j	0.0242j	NOUN
eurjchem-405	62	12	0.173	0.173	NUM
eurjchem-405	62	13	±	±	NUM
eurjchem-405	62	14	0.023	0.023	NUM
eurjchem-405	62	15	0.483	0.483	NUM
eurjchem-405	62	16	±	±	NUM
eurjchem-405	62	17	0.009	0.009	NUM
eurjchem-405	62	18	90	90	NUM
eurjchem-405	62	19	%	%	NOUN
eurjchem-405	62	20	tfe	tfe	NOUN
eurjchem-405	62	21	(	(	PUNCT
eurjchem-405	62	22	w	w	PROPN
eurjchem-405	62	23	/	/	SYM
eurjchem-405	62	24	w	w	NOUN
eurjchem-405	62	25	)	)	PUNCT
eurjchem-405	62	26	0.102	0.102	NUM
eurjchem-405	62	27	±	±	NUM
eurjchem-405	62	28	0.049	0.049	NUM
eurjchem-405	62	29	97%hfip	97%hfip	PROPN
eurjchem-405	62	30	(	(	PUNCT
eurjchem-405	62	31	w	w	NOUN
eurjchem-405	62	32	/	/	SYM
eurjchem-405	62	33	w)k	w)k	NOUN
eurjchem-405	62	34	0.00914l	0.00914l	PROPN
eurjchem-405	62	35	0.301	0.301	NUM
eurjchem-405	62	36	±	±	NUM
eurjchem-405	62	37	0.018	0.018	NUM
eurjchem-405	62	38	0.537	0.537	NUM
eurjchem-405	62	39	±	±	NUM
eurjchem-405	62	40	0.003	0.003	NUM
eurjchem-405	62	41	90%hfip	90%hfip	PROPN
eurjchem-405	62	42	(	(	PUNCT
eurjchem-405	62	43	w	w	PROPN
eurjchem-405	62	44	/	/	SYM
eurjchem-405	62	45	w)m	w)m	NOUN
eurjchem-405	62	46	0.0553n	0.0553n	ADJ
eurjchem-405	62	47	0.705	0.705	NUM
eurjchem-405	62	48	±	±	NUM
eurjchem-405	62	49	0.023	0.023	NUM
eurjchem-405	62	50	1.29	1.29	NUM
eurjchem-405	62	51	±	±	NUM
eurjchem-405	62	52	0.13	0.13	NUM
eurjchem-405	62	53	2.37	2.37	NUM
eurjchem-405	62	54	±	±	NUM
eurjchem-405	62	55	0.25	0.25	NUM
eurjchem-405	62	56	70%hfip	70%hfip	PROPN
eurjchem-405	62	57	(	(	PUNCT
eurjchem-405	62	58	w	w	NOUN
eurjchem-405	62	59	/	/	SYM
eurjchem-405	62	60	w)o	w)o	X
eurjchem-405	62	61	0.532p	0.532p	NOUN
eurjchem-405	62	62	2.54	2.54	NUM
eurjchem-405	62	63	±	±	NUM
eurjchem-405	62	64	0.09	0.09	NUM
eurjchem-405	62	65	20.5	20.5	NUM
eurjchem-405	62	66	±	±	NUM
eurjchem-405	62	67	3.0	3.0	NUM
eurjchem-405	62	68	38.4	38.4	NUM
eurjchem-405	62	69	±	±	NUM
eurjchem-405	62	70	1.2	1.2	NUM
eurjchem-405	62	71	50	50	NUM
eurjchem-405	62	72	%	%	NOUN
eurjchem-405	62	73	hfip	hfip	NOUN
eurjchem-405	62	74	(	(	PUNCT
eurjchem-405	62	75	w	w	NOUN
eurjchem-405	62	76	/	/	SYM
eurjchem-405	62	77	w)q	w)q	NOUN
eurjchem-405	62	78	18.5r	18.5r	NUM
eurjchem-405	62	79	35.2	35.2	NUM
eurjchem-405	62	80	±	±	NUM
eurjchem-405	62	81	3.1	3.1	NUM
eurjchem-405	62	82	65.2	65.2	NUM
eurjchem-405	62	83	±	±	NUM
eurjchem-405	62	84	2.1	2.1	NUM
eurjchem-405	62	85	105	105	NUM
eurjchem-405	62	86	±	±	NUM
eurjchem-405	62	87	12	12	NUM
eurjchem-405	62	88	asubstrate	asubstrate	ADJ
eurjchem-405	62	89	concentration	concentration	NOUN
eurjchem-405	62	90	of	of	ADP
eurjchem-405	62	91	ca	ca	NOUN
eurjchem-405	62	92	.	.	PUNCT
eurjchem-405	63	1	0.0052	0.0052	NUM
eurjchem-405	63	2	m	m	NOUN
eurjchem-405	63	3	;	;	PUNCT
eurjchem-405	63	4	binary	binary	ADJ
eurjchem-405	63	5	solvents	solvent	NOUN
eurjchem-405	63	6	on	on	ADP
eurjchem-405	63	7	a	a	DET
eurjchem-405	63	8	volume‐volume	volume‐volume	NOUN
eurjchem-405	63	9	basis	basis	NOUN
eurjchem-405	63	10	at	at	ADP
eurjchem-405	63	11	the	the	DET
eurjchem-405	63	12	temperature	temperature	NOUN
eurjchem-405	63	13	studied	study	VERB
eurjchem-405	63	14	,	,	PUNCT
eurjchem-405	63	15	except	except	SCONJ
eurjchem-405	63	16	for	for	ADP
eurjchem-405	63	17	tfe‐h2o	tfe‐h2o	NOUN
eurjchem-405	63	18	and	and	CCONJ
eurjchem-405	63	19	hfip‐h2o	hfip‐h2o	NOUN
eurjchem-405	63	20	solvents	solvent	NOUN
eurjchem-405	63	21	which	which	PRON
eurjchem-405	63	22	are	be	AUX
eurjchem-405	63	23	on	on	ADP
eurjchem-405	63	24	a	a	DET
eurjchem-405	63	25	weight‐weight	weight‐weight	ADJ
eurjchem-405	63	26	basis	basis	NOUN
eurjchem-405	63	27	.	.	PUNCT
eurjchem-405	64	1	t‐e	t‐e	PUNCT
eurjchem-405	64	2	are	be	AUX
eurjchem-405	64	3	tfe‐ethanol	tfe‐ethanol	ADJ
eurjchem-405	64	4	mixtures	mixture	NOUN
eurjchem-405	64	5	.	.	PUNCT
eurjchem-405	65	1	b	b	X
eurjchem-405	65	2	with	with	ADP
eurjchem-405	65	3	associated	associated	ADJ
eurjchem-405	65	4	standard	standard	ADJ
eurjchem-405	65	5	deviation	deviation	NOUN
eurjchem-405	65	6	.	.	PUNCT
eurjchem-405	66	1	ca	can	AUX
eurjchem-405	66	2	value	value	VERB
eurjchem-405	66	3	of	of	ADP
eurjchem-405	66	4	74.0	74.0	NUM
eurjchem-405	66	5	(	(	PUNCT
eurjchem-405	66	6	±	±	X
eurjchem-405	66	7	0.6	0.6	NUM
eurjchem-405	66	8	)	)	PUNCT
eurjchem-405	66	9	x10‐5	x10‐5	NOUN
eurjchem-405	66	10	s‐1	s‐1	PROPN
eurjchem-405	66	11	is	be	AUX
eurjchem-405	66	12	reported	report	VERB
eurjchem-405	66	13	in	in	ADP
eurjchem-405	66	14	ref	ref	NOUN
eurjchem-405	66	15	.	.	PUNCT
eurjchem-405	67	1	[	[	X
eurjchem-405	67	2	22	22	NUM
eurjchem-405	67	3	]	]	PUNCT
eurjchem-405	67	4	.	.	PUNCT
eurjchem-405	68	1	d	d	X
eurjchem-405	68	2	a	a	DET
eurjchem-405	68	3	value	value	NOUN
eurjchem-405	68	4	of	of	ADP
eurjchem-405	68	5	127	127	NUM
eurjchem-405	68	6	(	(	PUNCT
eurjchem-405	68	7	±	±	NOUN
eurjchem-405	68	8	3	3	NUM
eurjchem-405	68	9	)	)	PUNCT
eurjchem-405	68	10	x10‐5	x10‐5	PROPN
eurjchem-405	68	11	s‐1	s‐1	PROPN
eurjchem-405	68	12	is	be	AUX
eurjchem-405	68	13	reported	report	VERB
eurjchem-405	68	14	in	in	ADP
eurjchem-405	68	15	ref	ref	NOUN
eurjchem-405	68	16	.	.	PUNCT
eurjchem-405	69	1	[	[	X
eurjchem-405	69	2	22	22	NUM
eurjchem-405	69	3	]	]	PUNCT
eurjchem-405	69	4	.	.	PUNCT
eurjchem-405	69	5	ea	ea	NOUN
eurjchem-405	69	6	value	value	NOUN
eurjchem-405	69	7	of	of	ADP
eurjchem-405	69	8	158	158	NUM
eurjchem-405	69	9	(	(	PUNCT
eurjchem-405	69	10	±	±	NOUN
eurjchem-405	69	11	3	3	NUM
eurjchem-405	69	12	)	)	PUNCT
eurjchem-405	69	13	x10‐5	x10‐5	PROPN
eurjchem-405	69	14	s‐1	s‐1	PROPN
eurjchem-405	69	15	is	be	AUX
eurjchem-405	69	16	reported	report	VERB
eurjchem-405	69	17	in	in	ADP
eurjchem-405	69	18	ref	ref	NOUN
eurjchem-405	69	19	.	.	PUNCT
eurjchem-405	70	1	[	[	X
eurjchem-405	70	2	22	22	NUM
eurjchem-405	70	3	]	]	PUNCT
eurjchem-405	70	4	.	.	PUNCT
eurjchem-405	71	1	fa	fa	NOUN
eurjchem-405	71	2	value	value	NOUN
eurjchem-405	71	3	of	of	ADP
eurjchem-405	71	4	72.3	72.3	NUM
eurjchem-405	71	5	(	(	PUNCT
eurjchem-405	71	6	±	±	NOUN
eurjchem-405	71	7	2.1	2.1	NUM
eurjchem-405	71	8	)	)	PUNCT
eurjchem-405	71	9	x10‐5	x10‐5	NOUN
eurjchem-405	71	10	s‐1	s‐1	PROPN
eurjchem-405	71	11	was	be	AUX
eurjchem-405	71	12	obtained	obtain	VERB
eurjchem-405	71	13	at	at	ADP
eurjchem-405	71	14	21.0	21.0	NUM
eurjchem-405	71	15	oc	oc	NOUN
eurjchem-405	71	16	.	.	PUNCT
eurjchem-405	72	1	ga	ga	NOUN
eurjchem-405	72	2	value	value	NOUN
eurjchem-405	72	3	of	of	ADP
eurjchem-405	72	4	39.2	39.2	NUM
eurjchem-405	72	5	(	(	PUNCT
eurjchem-405	72	6	±	±	NOUN
eurjchem-405	72	7	0.05	0.05	NUM
eurjchem-405	72	8	)	)	PUNCT
eurjchem-405	72	9	x	x	SYM
eurjchem-405	73	1	10‐5	10‐5	NUM
eurjchem-405	73	2	s‐1	s‐1	VERB
eurjchem-405	73	3	is	be	AUX
eurjchem-405	73	4	reported	report	VERB
eurjchem-405	73	5	in	in	ADP
eurjchem-405	73	6	ref	ref	NOUN
eurjchem-405	73	7	[	[	X
eurjchem-405	73	8	22	22	NUM
eurjchem-405	73	9	]	]	PUNCT
eurjchem-405	73	10	.	.	PUNCT
eurjchem-405	74	1	h	h	PROPN
eurjchem-405	74	2	a	a	DET
eurjchem-405	74	3	value	value	NOUN
eurjchem-405	74	4	of	of	ADP
eurjchem-405	74	5	46.8	46.8	NUM
eurjchem-405	74	6	(	(	PUNCT
eurjchem-405	74	7	±	±	NOUN
eurjchem-405	74	8	0.03	0.03	NUM
eurjchem-405	74	9	)	)	PUNCT
eurjchem-405	74	10	x	x	SYM
eurjchem-405	75	1	10‐5	10‐5	NUM
eurjchem-405	75	2	s‐1	s‐1	VERB
eurjchem-405	75	3	is	be	AUX
eurjchem-405	75	4	reported	report	VERB
eurjchem-405	75	5	in	in	ADP
eurjchem-405	75	6	ref	ref	NOUN
eurjchem-405	75	7	.	.	PUNCT
eurjchem-405	76	1	[	[	X
eurjchem-405	76	2	22	22	NUM
eurjchem-405	76	3	]	]	PUNCT
eurjchem-405	76	4	.	.	PUNCT
eurjchem-405	77	1	i	i	PRON
eurjchem-405	77	2	a	a	DET
eurjchem-405	77	3	value	value	NOUN
eurjchem-405	77	4	of	of	ADP
eurjchem-405	77	5	0.0856	0.0856	NUM
eurjchem-405	77	6	(	(	PUNCT
eurjchem-405	77	7	±	±	NOUN
eurjchem-405	77	8	0.005	0.005	NUM
eurjchem-405	77	9	)	)	PUNCT
eurjchem-405	77	10	x	x	SYM
eurjchem-405	77	11	10‐5	10‐5	NUM
eurjchem-405	77	12	s‐1	s‐1	NUM
eurjchem-405	77	13	was	be	AUX
eurjchem-405	77	14	obtained	obtain	VERB
eurjchem-405	77	15	at	at	ADP
eurjchem-405	77	16	35.0	35.0	NUM
eurjchem-405	77	17	oc	oc	NOUN
eurjchem-405	77	18	.	.	PUNCT
eurjchem-405	77	19	δh≠	δh≠	X
eurjchem-405	78	1	=	=	SYM
eurjchem-405	78	2	16.7	16.7	NUM
eurjchem-405	78	3	kcal	kcal	NOUN
eurjchem-405	78	4	/	/	SYM
eurjchem-405	78	5	mol	mol	PROPN
eurjchem-405	78	6	,	,	PUNCT
eurjchem-405	78	7	δs≠	δs≠	X
eurjchem-405	78	8	=	=	SYM
eurjchem-405	78	9	‐32.1	‐32.1	NUM
eurjchem-405	78	10	cal	cal	NUM
eurjchem-405	78	11	mol‐1	mol‐1	NOUN
eurjchem-405	78	12	k‐1	k‐1	NOUN
eurjchem-405	78	13	at	at	ADP
eurjchem-405	78	14	25.0	25.0	NUM
eurjchem-405	78	15	oc	oc	NOUN
eurjchem-405	78	16	.	.	PUNCT
eurjchem-405	79	1	j	j	PROPN
eurjchem-405	79	2	value	value	NOUN
eurjchem-405	79	3	calculated	calculate	VERB
eurjchem-405	79	4	using	use	VERB
eurjchem-405	79	5	arrhenius	arrhenius	NOUN
eurjchem-405	79	6	equation	equation	NOUN
eurjchem-405	79	7	.	.	PUNCT
eurjchem-405	80	1	ka	ka	PROPN
eurjchem-405	80	2	value	value	NOUN
eurjchem-405	80	3	of	of	ADP
eurjchem-405	80	4	0.199	0.199	NUM
eurjchem-405	80	5	(	(	PUNCT
eurjchem-405	80	6	±	±	NOUN
eurjchem-405	80	7	0.006	0.006	NUM
eurjchem-405	80	8	)	)	PUNCT
eurjchem-405	80	9	x	x	SYM
eurjchem-405	81	1	10‐5	10‐5	NUM
eurjchem-405	81	2	s‐1	s‐1	NUM
eurjchem-405	81	3	was	be	AUX
eurjchem-405	81	4	obtained	obtain	VERB
eurjchem-405	81	5	at	at	ADP
eurjchem-405	81	6	50.0	50.0	NUM
eurjchem-405	81	7	oc	oc	NOUN
eurjchem-405	81	8	.	.	PUNCT
eurjchem-405	81	9	δh≠	δh≠	X
eurjchem-405	82	1	=	=	SYM
eurjchem-405	82	2	13.5	13.5	NUM
eurjchem-405	82	3	kcal	kcal	NOUN
eurjchem-405	82	4	/	/	SYM
eurjchem-405	82	5	mol	mol	PROPN
eurjchem-405	82	6	,	,	PUNCT
eurjchem-405	82	7	δs≠	δs≠	PROPN
eurjchem-405	82	8	=	=	SYM
eurjchem-405	82	9	‐42.8	‐42.8	NUM
eurjchem-405	82	10	cal	cal	NUM
eurjchem-405	82	11	mol‐1	mol‐1	NOUN
eurjchem-405	82	12	k‐1	k‐1	NOUN
eurjchem-405	82	13	at	at	ADP
eurjchem-405	82	14	25.0	25.0	NUM
eurjchem-405	82	15	oc	oc	NOUN
eurjchem-405	82	16	.	.	PUNCT
eurjchem-405	82	17	l	l	NOUN
eurjchem-405	82	18	value	value	NOUN
eurjchem-405	82	19	calculated	calculate	VERB
eurjchem-405	82	20	using	use	VERB
eurjchem-405	82	21	arrhenius	arrhenius	NOUN
eurjchem-405	82	22	equation	equation	NOUN
eurjchem-405	82	23	.	.	PUNCT
eurjchem-405	83	1	m	m	VERB
eurjchem-405	83	2	δh≠	δh≠	PUNCT
eurjchem-405	84	1	=	=	SYM
eurjchem-405	84	2	12.4	12.4	NUM
eurjchem-405	84	3	kcal	kcal	NOUN
eurjchem-405	84	4	/	/	SYM
eurjchem-405	84	5	mol	mol	PROPN
eurjchem-405	84	6	,	,	PUNCT
eurjchem-405	84	7	δs≠	δs≠	X
eurjchem-405	84	8	=	=	SYM
eurjchem-405	84	9	‐43.3	‐43.3	NUM
eurjchem-405	84	10	cal	cal	ADJ
eurjchem-405	84	11	mol‐1	mol‐1	NOUN
eurjchem-405	84	12	k‐1	k‐1	NOUN
eurjchem-405	84	13	at	at	ADP
eurjchem-405	84	14	25.0	25.0	NUM
eurjchem-405	84	15	oc	oc	NOUN
eurjchem-405	84	16	.	.	PUNCT
eurjchem-405	85	1	n	n	DET
eurjchem-405	85	2	value	value	NOUN
eurjchem-405	85	3	calculated	calculate	VERB
eurjchem-405	85	4	using	use	VERB
eurjchem-405	85	5	arrhenius	arrhenius	NOUN
eurjchem-405	85	6	equation	equation	NOUN
eurjchem-405	85	7	.	.	PUNCT
eurjchem-405	86	1	o	o	X
eurjchem-405	86	2	δh≠	δh≠	PUNCT
eurjchem-405	87	1	=	=	SYM
eurjchem-405	87	2	17.3	17.3	NUM
eurjchem-405	87	3	kcal	kcal	NOUN
eurjchem-405	87	4	/	/	SYM
eurjchem-405	87	5	mol	mol	PROPN
eurjchem-405	87	6	,	,	PUNCT
eurjchem-405	87	7	δs≠	δs≠	PROPN
eurjchem-405	87	8	=	=	SYM
eurjchem-405	87	9	‐21.3	‐21.3	NUM
eurjchem-405	87	10	cal	cal	ADJ
eurjchem-405	87	11	mol‐1	mol‐1	NOUN
eurjchem-405	87	12	k‐1	k‐1	NOUN
eurjchem-405	87	13	at	at	ADP
eurjchem-405	87	14	25.0	25.0	NUM
eurjchem-405	87	15	oc	oc	NOUN
eurjchem-405	87	16	.	.	PUNCT
eurjchem-405	88	1	p	p	NOUN
eurjchem-405	88	2	value	value	NOUN
eurjchem-405	88	3	calculated	calculate	VERB
eurjchem-405	88	4	using	use	VERB
eurjchem-405	88	5	arrhenius	arrhenius	NOUN
eurjchem-405	88	6	equation	equation	NOUN
eurjchem-405	88	7	.	.	PUNCT
eurjchem-405	89	1	q	q	PUNCT
eurjchem-405	90	1	δh≠	δh≠	PUNCT
eurjchem-405	90	2	=	=	SYM
eurjchem-405	90	3	6.3	6.3	NUM
eurjchem-405	90	4	kcal	kcal	NOUN
eurjchem-405	90	5	/	/	SYM
eurjchem-405	90	6	mol	mol	PROPN
eurjchem-405	90	7	,	,	PUNCT
eurjchem-405	90	8	δs≠	δs≠	X
eurjchem-405	90	9	=	=	NUM
eurjchem-405	90	10	‐53.3	‐53.3	X
eurjchem-405	90	11	cal	cal	ADJ
eurjchem-405	90	12	mol‐1	mol‐1	NOUN
eurjchem-405	90	13	k‐1	k‐1	NOUN
eurjchem-405	90	14	at	at	ADP
eurjchem-405	90	15	25.0	25.0	NUM
eurjchem-405	90	16	oc	oc	NOUN
eurjchem-405	90	17	.	.	PUNCT
eurjchem-405	91	1	r	r	NOUN
eurjchem-405	91	2	value	value	NOUN
eurjchem-405	91	3	calculated	calculate	VERB
eurjchem-405	91	4	using	use	VERB
eurjchem-405	91	5	arrhenius	arrhenius	NOUN
eurjchem-405	91	6	equation	equation	NOUN
eurjchem-405	91	7	.	.	PUNCT
eurjchem-405	92	1	and	and	CCONJ
eurjchem-405	92	2	one	one	NUM
eurjchem-405	92	3	more	more	ADJ
eurjchem-405	92	4	rate	rate	NOUN
eurjchem-405	92	5	constant	constant	ADJ
eurjchem-405	92	6	at	at	ADP
eurjchem-405	92	7	21.0	21.0	NUM
eurjchem-405	92	8	oc	oc	NOUN
eurjchem-405	92	9	was	be	AUX
eurjchem-405	92	10	determined	determine	VERB
eurjchem-405	92	11	for	for	ADP
eurjchem-405	92	12	pure	pure	ADJ
eurjchem-405	92	13	etoh	etoh	NOUN
eurjchem-405	92	14	.	.	PUNCT
eurjchem-405	93	1	using	use	VERB
eurjchem-405	93	2	the	the	DET
eurjchem-405	93	3	specific	specific	ADJ
eurjchem-405	93	4	rates	rate	NOUN
eurjchem-405	93	5	of	of	ADP
eurjchem-405	93	6	solvolysis	solvolysis	NOUN
eurjchem-405	93	7	values	value	NOUN
eurjchem-405	93	8	that	that	PRON
eurjchem-405	93	9	were	be	AUX
eurjchem-405	93	10	obtained	obtain	VERB
eurjchem-405	93	11	at	at	ADP
eurjchem-405	93	12	several	several	ADJ
eurjchem-405	93	13	other	other	ADJ
eurjchem-405	93	14	temperatures	temperature	NOUN
eurjchem-405	93	15	(	(	PUNCT
eurjchem-405	93	16	listed	list	VERB
eurjchem-405	93	17	in	in	ADP
eurjchem-405	93	18	table	table	NOUN
eurjchem-405	93	19	1	1	NUM
eurjchem-405	93	20	)	)	PUNCT
eurjchem-405	93	21	in	in	ADP
eurjchem-405	93	22	97	97	NUM
eurjchem-405	93	23	%	%	NOUN
eurjchem-405	93	24	tfe	tfe	NOUN
eurjchem-405	93	25	,	,	PUNCT
eurjchem-405	93	26	97	97	NUM
eurjchem-405	93	27	%	%	NOUN
eurjchem-405	93	28	hfip	hfip	NOUN
eurjchem-405	93	29	,	,	PUNCT
eurjchem-405	93	30	70	70	NUM
eurjchem-405	93	31	%	%	NOUN
eurjchem-405	93	32	hfip	hfip	NOUN
eurjchem-405	93	33	,	,	PUNCT
eurjchem-405	93	34	and	and	CCONJ
eurjchem-405	93	35	50	50	NUM
eurjchem-405	93	36	%	%	NOUN
eurjchem-405	93	37	hfip	hfip	NOUN
eurjchem-405	93	38	,	,	PUNCT
eurjchem-405	93	39	we	we	PRON
eurjchem-405	93	40	calculate	calculate	VERB
eurjchem-405	93	41	and	and	CCONJ
eurjchem-405	93	42	report	report	VERB
eurjchem-405	93	43	the	the	DET
eurjchem-405	93	44	estimated	estimate	VERB
eurjchem-405	93	45	rate	rate	NOUN
eurjchem-405	93	46	constants	constant	NOUN
eurjchem-405	93	47	for	for	ADP
eurjchem-405	93	48	these	these	DET
eurjchem-405	93	49	solvents	solvent	NOUN
eurjchem-405	93	50	at	at	ADP
eurjchem-405	93	51	10.0	10.0	NUM
eurjchem-405	93	52	oc	oc	NOUN
eurjchem-405	93	53	using	use	VERB
eurjchem-405	93	54	the	the	DET
eurjchem-405	93	55	arrhenius	arrhenius	NOUN
eurjchem-405	93	56	equation	equation	NOUN
eurjchem-405	93	57	.	.	PUNCT
eurjchem-405	94	1	in	in	ADP
eurjchem-405	94	2	this	this	DET
eurjchem-405	94	3	table	table	NOUN
eurjchem-405	94	4	,	,	PUNCT
eurjchem-405	94	5	we	we	PRON
eurjchem-405	94	6	also	also	ADV
eurjchem-405	94	7	report	report	VERB
eurjchem-405	94	8	a	a	DET
eurjchem-405	94	9	specific	specific	ADJ
eurjchem-405	94	10	rate	rate	NOUN
eurjchem-405	94	11	value	value	NOUN
eurjchem-405	94	12	for	for	ADP
eurjchem-405	94	13	90	90	NUM
eurjchem-405	94	14	%	%	NOUN
eurjchem-405	94	15	tfe	tfe	NOUN
eurjchem-405	94	16	that	that	PRON
eurjchem-405	94	17	was	be	AUX
eurjchem-405	94	18	determined	determine	VERB
eurjchem-405	94	19	at	at	ADP
eurjchem-405	94	20	10.0	10.0	NUM
eurjchem-405	94	21	oc	oc	NOUN
eurjchem-405	94	22	.	.	PUNCT
eurjchem-405	95	1	for	for	ADP
eurjchem-405	95	2	studies	study	NOUN
eurjchem-405	95	3	in	in	ADP
eurjchem-405	95	4	the	the	DET
eurjchem-405	95	5	5	5	NUM
eurjchem-405	95	6	fluoroalcohols	fluoroalcohol	NOUN
eurjchem-405	95	7	that	that	PRON
eurjchem-405	95	8	were	be	AUX
eurjchem-405	95	9	carried	carry	VERB
eurjchem-405	95	10	out	out	ADP
eurjchem-405	95	11	over	over	ADP
eurjchem-405	95	12	several	several	ADJ
eurjchem-405	95	13	temperatures	temperature	NOUN
eurjchem-405	95	14	,	,	PUNCT
eurjchem-405	95	15	we	we	PRON
eurjchem-405	95	16	determined	determine	VERB
eurjchem-405	95	17	the	the	DET
eurjchem-405	95	18	arrhenius	arrhenius	PROPN
eurjchem-405	95	19	parameters	parameter	NOUN
eurjchem-405	95	20	at	at	ADP
eurjchem-405	95	21	25.0	25.0	NUM
eurjchem-405	95	22	oc	oc	NOUN
eurjchem-405	95	23	and	and	CCONJ
eurjchem-405	95	24	report	report	VERB
eurjchem-405	95	25	the	the	DET
eurjchem-405	95	26	∆h≠	∆h≠	PROPN
eurjchem-405	95	27	,	,	PUNCT
eurjchem-405	95	28	∆s≠	∆s≠	VERB
eurjchem-405	95	29	values	value	NOUN
eurjchem-405	95	30	in	in	ADP
eurjchem-405	95	31	the	the	DET
eurjchem-405	95	32	footnotes	footnote	NOUN
eurjchem-405	95	33	of	of	ADP
eurjchem-405	95	34	table	table	NOUN
eurjchem-405	95	35	1	1	NUM
eurjchem-405	95	36	.	.	PUNCT
eurjchem-405	96	1	the	the	DET
eurjchem-405	96	2	rate	rate	NOUN
eurjchem-405	96	3	constants	constant	NOUN
eurjchem-405	96	4	summarized	summarize	VERB
eurjchem-405	96	5	in	in	ADP
eurjchem-405	96	6	table	table	NOUN
eurjchem-405	96	7	1	1	NUM
eurjchem-405	96	8	for	for	ADP
eurjchem-405	96	9	the	the	DET
eurjchem-405	96	10	solvolyses	solvolyse	NOUN
eurjchem-405	96	11	of	of	ADP
eurjchem-405	96	12	1	1	NUM
eurjchem-405	96	13	at	at	ADP
eurjchem-405	96	14	10.0	10.0	NUM
eurjchem-405	96	15	oc	oc	NOUN
eurjchem-405	96	16	,	,	PUNCT
eurjchem-405	96	17	are	be	AUX
eurjchem-405	96	18	combined	combine	VERB
eurjchem-405	96	19	with	with	ADP
eurjchem-405	96	20	the	the	DET
eurjchem-405	96	21	available	available	ADJ
eurjchem-405	96	22	literature	literature	NOUN
eurjchem-405	96	23	values	value	NOUN
eurjchem-405	96	24	for	for	ADP
eurjchem-405	96	25	the	the	DET
eurjchem-405	96	26	correlation	correlation	NOUN
eurjchem-405	96	27	analysis	analysis	NOUN
eurjchem-405	96	28	using	use	VERB
eurjchem-405	96	29	equation	equation	NOUN
eurjchem-405	96	30	1	1	NUM
eurjchem-405	96	31	and	and	CCONJ
eurjchem-405	96	32	the	the	DET
eurjchem-405	96	33	correlation	correlation	NOUN
eurjchem-405	96	34	data	datum	NOUN
eurjchem-405	96	35	are	be	AUX
eurjchem-405	96	36	reported	report	VERB
eurjchem-405	96	37	in	in	ADP
eurjchem-405	96	38	table	table	NOUN
eurjchem-405	96	39	2	2	NUM
eurjchem-405	96	40	.	.	PUNCT
eurjchem-405	97	1	the	the	DET
eurjchem-405	97	2	combined	combine	VERB
eurjchem-405	97	3	51	51	NUM
eurjchem-405	97	4	solvents	solvent	NOUN
eurjchem-405	97	5	now	now	ADV
eurjchem-405	97	6	provide	provide	VERB
eurjchem-405	97	7	for	for	ADP
eurjchem-405	97	8	the	the	DET
eurjchem-405	97	9	first	first	ADJ
eurjchem-405	97	10	extensive	extensive	ADJ
eurjchem-405	97	11	inquiry	inquiry	NOUN
eurjchem-405	97	12	into	into	ADP
eurjchem-405	97	13	the	the	DET
eurjchem-405	97	14	possible	possible	ADJ
eurjchem-405	97	15	mechanism	mechanism	NOUN
eurjchem-405	97	16	of	of	ADP
eurjchem-405	97	17	solvolysis	solvolysis	NOUN
eurjchem-405	97	18	of	of	ADP
eurjchem-405	97	19	1	1	NUM
eurjchem-405	97	20	over	over	ADP
eurjchem-405	97	21	an	an	DET
eurjchem-405	97	22	extensive	extensive	ADJ
eurjchem-405	97	23	range	range	NOUN
eurjchem-405	97	24	of	of	ADP
eurjchem-405	97	25	solvents	solvent	NOUN
eurjchem-405	97	26	with	with	ADP
eurjchem-405	97	27	widely	widely	ADV
eurjchem-405	97	28	varying	vary	VERB
eurjchem-405	97	29	nucleophilicity	nucleophilicity	NOUN
eurjchem-405	97	30	and	and	CCONJ
eurjchem-405	97	31	ionizing	ionizing	NOUN
eurjchem-405	97	32	ability	ability	NOUN
eurjchem-405	97	33	.	.	PUNCT
eurjchem-405	98	1	the	the	DET
eurjchem-405	98	2	observed	observed	ADJ
eurjchem-405	98	3	trend	trend	NOUN
eurjchem-405	98	4	is	be	AUX
eurjchem-405	98	5	for	for	ADP
eurjchem-405	98	6	a	a	DET
eurjchem-405	98	7	gradual	gradual	ADJ
eurjchem-405	98	8	rate	rate	NOUN
eurjchem-405	98	9	upturn	upturn	NOUN
eurjchem-405	98	10	coinciding	coincide	VERB
eurjchem-405	98	11	with	with	ADP
eurjchem-405	98	12	the	the	DET
eurjchem-405	98	13	increase	increase	NOUN
eurjchem-405	98	14	in	in	ADP
eurjchem-405	98	15	water	water	NOUN
eurjchem-405	98	16	content	content	NOUN
eurjchem-405	98	17	of	of	ADP
eurjchem-405	98	18	the	the	DET
eurjchem-405	98	19	binary	binary	ADJ
eurjchem-405	98	20	mixtures	mixture	NOUN
eurjchem-405	98	21	in	in	ADP
eurjchem-405	98	22	ethanol	ethanol	NOUN
eurjchem-405	98	23	,	,	PUNCT
eurjchem-405	98	24	methanol	methanol	NOUN
eurjchem-405	98	25	,	,	PUNCT
eurjchem-405	98	26	acetone	acetone	NOUN
eurjchem-405	98	27	and	and	CCONJ
eurjchem-405	98	28	tfe	tfe	NOUN
eurjchem-405	98	29	,	,	PUNCT
eurjchem-405	98	30	or	or	CCONJ
eurjchem-405	98	31	an	an	DET
eurjchem-405	98	32	increase	increase	NOUN
eurjchem-405	98	33	in	in	ADP
eurjchem-405	98	34	ethanol	ethanol	NOUN
eurjchem-405	98	35	content	content	NOUN
eurjchem-405	98	36	in	in	ADP
eurjchem-405	98	37	the	the	DET
eurjchem-405	98	38	tfe‐etoh	tfe‐etoh	NUM
eurjchem-405	98	39	mixtures	mixture	NOUN
eurjchem-405	98	40	.	.	PUNCT
eurjchem-405	99	1	in	in	ADP
eurjchem-405	99	2	hfip	hfip	PROPN
eurjchem-405	99	3	,	,	PUNCT
eurjchem-405	99	4	a	a	DET
eurjchem-405	99	5	substantial	substantial	ADJ
eurjchem-405	99	6	rate	rate	NOUN
eurjchem-405	99	7	surge	surge	NOUN
eurjchem-405	99	8	is	be	AUX
eurjchem-405	99	9	observed	observe	VERB
eurjchem-405	99	10	as	as	ADP
eurjchem-405	99	11	the	the	DET
eurjchem-405	99	12	water	water	NOUN
eurjchem-405	99	13	content	content	NOUN
eurjchem-405	99	14	in	in	ADP
eurjchem-405	99	15	this	this	DET
eurjchem-405	99	16	highly	highly	ADV
eurjchem-405	99	17	ionizing	ionize	VERB
eurjchem-405	99	18	fluoroalcohol	fluoroalcohol	NOUN
eurjchem-405	99	19	mixture	mixture	NOUN
eurjchem-405	99	20	increases	increase	NOUN
eurjchem-405	99	21	.	.	PUNCT
eurjchem-405	100	1	on	on	ADP
eurjchem-405	100	2	the	the	DET
eurjchem-405	100	3	other	other	ADJ
eurjchem-405	100	4	hand	hand	NOUN
eurjchem-405	100	5	in	in	ADP
eurjchem-405	100	6	2	2	NUM
eurjchem-405	100	7	,	,	PUNCT
eurjchem-405	100	8	the	the	DET
eurjchem-405	100	9	rates	rate	NOUN
eurjchem-405	100	10	decrease	decrease	VERB
eurjchem-405	100	11	[	[	X
eurjchem-405	100	12	24	24	NUM
eurjchem-405	100	13	]	]	PUNCT
eurjchem-405	100	14	with	with	ADP
eurjchem-405	100	15	an	an	DET
eurjchem-405	100	16	increase	increase	NOUN
eurjchem-405	100	17	in	in	ADP
eurjchem-405	100	18	water	water	NOUN
eurjchem-405	100	19	content	content	NOUN
eurjchem-405	100	20	in	in	ADP
eurjchem-405	100	21	the	the	DET
eurjchem-405	100	22	aqueous	aqueous	ADJ
eurjchem-405	100	23	hfip	hfip	PROPN
eurjchem-405	100	24	mixtures	mixture	NOUN
eurjchem-405	100	25	.	.	PUNCT
eurjchem-405	101	1	this	this	PRON
eurjchem-405	101	2	signals	signal	VERB
eurjchem-405	101	3	the	the	DET
eurjchem-405	101	4	importance	importance	NOUN
eurjchem-405	101	5	of	of	ADP
eurjchem-405	101	6	solvent	solvent	ADJ
eurjchem-405	101	7	nucleophilicity	nucleophilicity	NOUN
eurjchem-405	101	8	in	in	ADP
eurjchem-405	101	9	the	the	DET
eurjchem-405	101	10	rate‐determining	rate‐determining	NOUN
eurjchem-405	101	11	step	step	NOUN
eurjchem-405	101	12	of	of	ADP
eurjchem-405	101	13	the	the	DET
eurjchem-405	101	14	solvolyses	solvolyse	NOUN
eurjchem-405	101	15	of	of	ADP
eurjchem-405	101	16	1	1	NUM
eurjchem-405	101	17	.	.	PUNCT
eurjchem-405	102	1	since	since	SCONJ
eurjchem-405	102	2	the	the	DET
eurjchem-405	102	3	rate	rate	NOUN
eurjchem-405	102	4	trends	trend	NOUN
eurjchem-405	102	5	observed	observe	VERB
eurjchem-405	102	6	for	for	ADP
eurjchem-405	102	7	1	1	NUM
eurjchem-405	102	8	are	be	AUX
eurjchem-405	102	9	similar	similar	ADJ
eurjchem-405	102	10	to	to	ADP
eurjchem-405	102	11	those	those	PRON
eurjchem-405	102	12	seen	see	VERB
eurjchem-405	102	13	in	in	ADP
eurjchem-405	102	14	the	the	DET
eurjchem-405	102	15	specific	specific	ADJ
eurjchem-405	102	16	rates	rate	NOUN
eurjchem-405	102	17	of	of	ADP
eurjchem-405	102	18	solvolysis	solvolysis	NOUN
eurjchem-405	102	19	of	of	ADP
eurjchem-405	102	20	3	3	NUM
eurjchem-405	102	21	[	[	X
eurjchem-405	102	22	9	9	NUM
eurjchem-405	102	23	]	]	PUNCT
eurjchem-405	102	24	,	,	PUNCT
eurjchem-405	102	25	the	the	DET
eurjchem-405	102	26	prediction	prediction	NOUN
eurjchem-405	102	27	is	be	AUX
eurjchem-405	102	28	for	for	ADP
eurjchem-405	102	29	a	a	DET
eurjchem-405	102	30	mechanism	mechanism	NOUN
eurjchem-405	102	31	similar	similar	ADJ
eurjchem-405	102	32	to	to	ADP
eurjchem-405	102	33	the	the	DET
eurjchem-405	102	34	well	well	ADV
eurjchem-405	102	35	established	establish	VERB
eurjchem-405	102	36	carbonyl	carbonyl	NOUN
eurjchem-405	102	37	addition‐elimination	addition‐elimination	NOUN
eurjchem-405	102	38	[	[	X
eurjchem-405	102	39	9,23	9,23	NOUN
eurjchem-405	102	40	]	]	X
eurjchem-405	102	41	solvolysis	solvolysis	NOUN
eurjchem-405	102	42	for	for	ADP
eurjchem-405	102	43	3	3	NUM
eurjchem-405	102	44	.	.	PUNCT
eurjchem-405	103	1	in	in	ADP
eurjchem-405	103	2	table	table	NOUN
eurjchem-405	103	3	2	2	NUM
eurjchem-405	103	4	,	,	PUNCT
eurjchem-405	103	5	a	a	DET
eurjchem-405	103	6	comprehensive	comprehensive	ADJ
eurjchem-405	103	7	analysis	analysis	NOUN
eurjchem-405	103	8	using	use	VERB
eurjchem-405	103	9	equation	equation	NOUN
eurjchem-405	103	10	1	1	NUM
eurjchem-405	103	11	with	with	ADP
eurjchem-405	103	12	all	all	DET
eurjchem-405	103	13	51	51	NUM
eurjchem-405	103	14	solvents	solvent	NOUN
eurjchem-405	103	15	results	result	NOUN
eurjchem-405	103	16	in	in	ADP
eurjchem-405	103	17	a	a	DET
eurjchem-405	103	18	l	l	NOUN
eurjchem-405	103	19	value	value	NOUN
eurjchem-405	103	20	of	of	ADP
eurjchem-405	103	21	1.40	1.40	NUM
eurjchem-405	103	22	±	±	NOUN
eurjchem-405	103	23	0.06	0.06	NUM
eurjchem-405	103	24	,	,	PUNCT
eurjchem-405	103	25	a	a	DET
eurjchem-405	103	26	m	m	NOUN
eurjchem-405	103	27	value	value	NOUN
eurjchem-405	103	28	of	of	ADP
eurjchem-405	103	29	0.51	0.51	NUM
eurjchem-405	103	30	±	±	NUM
eurjchem-405	103	31	0.03	0.03	NUM
eurjchem-405	103	32	,	,	PUNCT
eurjchem-405	103	33	r	r	NOUN
eurjchem-405	103	34	=	=	PUNCT
eurjchem-405	103	35	0.962	0.962	NUM
eurjchem-405	103	36	,	,	PUNCT
eurjchem-405	103	37	f‐test	f‐test	PUNCT
eurjchem-405	103	38	=	=	SYM
eurjchem-405	103	39	294	294	NUM
eurjchem-405	103	40	,	,	PUNCT
eurjchem-405	103	41	and	and	CCONJ
eurjchem-405	103	42	a	a	DET
eurjchem-405	103	43	c	c	NOUN
eurjchem-405	103	44	value	value	NOUN
eurjchem-405	103	45	of	of	ADP
eurjchem-405	103	46	‐0.02	‐0.02	NUM
eurjchem-405	103	47	±	±	NUM
eurjchem-405	103	48	0.07	0.07	NUM
eurjchem-405	103	49	.	.	PUNCT
eurjchem-405	104	1	a	a	DET
eurjchem-405	104	2	plot	plot	NOUN
eurjchem-405	104	3	of	of	ADP
eurjchem-405	104	4	log	log	NOUN
eurjchem-405	104	5	(	(	PUNCT
eurjchem-405	104	6	k	k	NOUN
eurjchem-405	104	7	/	/	SYM
eurjchem-405	104	8	ko)1	ko)1	NOUN
eurjchem-405	104	9	versus	versus	ADP
eurjchem-405	104	10	log	log	NOUN
eurjchem-405	104	11	(	(	PUNCT
eurjchem-405	104	12	k	k	X
eurjchem-405	104	13	/	/	SYM
eurjchem-405	104	14	ko)3	ko)3	PROPN
eurjchem-405	104	15	in	in	ADP
eurjchem-405	104	16	figure	figure	NOUN
eurjchem-405	104	17	2	2	NUM
eurjchem-405	104	18	,	,	PUNCT
eurjchem-405	104	19	points	point	VERB
eurjchem-405	104	20	to	to	ADP
eurjchem-405	104	21	a	a	DET
eurjchem-405	104	22	good	good	ADJ
eurjchem-405	104	23	linear	linear	NOUN
eurjchem-405	104	24	relationship	relationship	NOUN
eurjchem-405	104	25	between	between	ADP
eurjchem-405	104	26	the	the	DET
eurjchem-405	104	27	solvolysis	solvolysis	NOUN
eurjchem-405	104	28	of	of	ADP
eurjchem-405	104	29	1	1	NUM
eurjchem-405	104	30	and	and	CCONJ
eurjchem-405	104	31	3	3	NUM
eurjchem-405	104	32	in	in	ADP
eurjchem-405	104	33	47	47	NUM
eurjchem-405	104	34	common	common	ADJ
eurjchem-405	104	35	solvents	solvent	NOUN
eurjchem-405	104	36	,	,	PUNCT
eurjchem-405	104	37	with	with	ADP
eurjchem-405	104	38	a	a	DET
eurjchem-405	104	39	correlation	correlation	NOUN
eurjchem-405	104	40	coefficient	coefficient	NOUN
eurjchem-405	104	41	0.979	0.979	NUM
eurjchem-405	104	42	,	,	PUNCT
eurjchem-405	104	43	f‐	f‐	NOUN
eurjchem-405	104	44	test	test	NOUN
eurjchem-405	104	45	value	value	NOUN
eurjchem-405	104	46	of	of	ADP
eurjchem-405	104	47	1046	1046	NUM
eurjchem-405	104	48	,	,	PUNCT
eurjchem-405	104	49	a	a	DET
eurjchem-405	104	50	slope	slope	NOUN
eurjchem-405	104	51	of	of	ADP
eurjchem-405	104	52	0.86	0.86	NUM
eurjchem-405	104	53	±	±	NUM
eurjchem-405	104	54	0.03	0.03	NUM
eurjchem-405	104	55	,	,	PUNCT
eurjchem-405	104	56	and	and	CCONJ
eurjchem-405	104	57	a	a	DET
eurjchem-405	104	58	c	c	NOUN
eurjchem-405	104	59	value	value	NOUN
eurjchem-405	104	60	of	of	ADP
eurjchem-405	104	61	‐0.04	‐0.04	NOUN
eurjchem-405	104	62	±	±	NUM
eurjchem-405	104	63	0.04	0.04	NUM
eurjchem-405	104	64	.	.	PUNCT
eurjchem-405	105	1	figure	figure	NOUN
eurjchem-405	105	2	2	2	NUM
eurjchem-405	105	3	.	.	PUNCT
eurjchem-405	106	1	the	the	DET
eurjchem-405	106	2	plot	plot	NOUN
eurjchem-405	106	3	of	of	ADP
eurjchem-405	106	4	log	log	NOUN
eurjchem-405	106	5	(	(	PUNCT
eurjchem-405	106	6	k	k	NOUN
eurjchem-405	106	7	/	/	SYM
eurjchem-405	106	8	ko	ko	PROPN
eurjchem-405	106	9	)	)	PUNCT
eurjchem-405	106	10	for	for	ADP
eurjchem-405	106	11	isopropenyl	isopropenyl	ADJ
eurjchem-405	106	12	chloroformate	chloroformate	NOUN
eurjchem-405	106	13	(	(	PUNCT
eurjchem-405	106	14	1	1	NUM
eurjchem-405	106	15	)	)	PUNCT
eurjchem-405	106	16	against	against	ADP
eurjchem-405	106	17	log	log	NOUN
eurjchem-405	106	18	(	(	PUNCT
eurjchem-405	106	19	k	k	NOUN
eurjchem-405	106	20	/	/	SYM
eurjchem-405	106	21	ko	ko	PROPN
eurjchem-405	106	22	)	)	PUNCT
eurjchem-405	106	23	for	for	ADP
eurjchem-405	106	24	phenyl	phenyl	NOUN
eurjchem-405	106	25	chloroformate	chloroformate	NOUN
eurjchem-405	106	26	(	(	PUNCT
eurjchem-405	106	27	3	3	NUM
eurjchem-405	106	28	)	)	PUNCT
eurjchem-405	106	29	.	.	PUNCT
eurjchem-405	107	1	the	the	DET
eurjchem-405	107	2	goodness‐of‐fit	goodness‐of‐fit	PROPN
eurjchem-405	107	3	parameters	parameter	NOUN
eurjchem-405	107	4	improve	improve	VERB
eurjchem-405	107	5	substantially	substantially	ADV
eurjchem-405	107	6	on	on	ADP
eurjchem-405	107	7	removal	removal	NOUN
eurjchem-405	107	8	of	of	ADP
eurjchem-405	107	9	the	the	DET
eurjchem-405	107	10	97	97	NUM
eurjchem-405	107	11	%	%	NOUN
eurjchem-405	107	12	hfip	hfip	NOUN
eurjchem-405	107	13	value	value	NOUN
eurjchem-405	107	14	(	(	PUNCT
eurjchem-405	107	15	46	46	NUM
eurjchem-405	107	16	solvents	solvent	NOUN
eurjchem-405	107	17	)	)	PUNCT
eurjchem-405	107	18	,	,	PUNCT
eurjchem-405	107	19	with	with	ADP
eurjchem-405	107	20	r	r	NOUN
eurjchem-405	107	21	=	=	PUNCT
eurjchem-405	107	22	0.991	0.991	NUM
eurjchem-405	107	23	,	,	PUNCT
eurjchem-405	107	24	f‐test	f‐test	X
eurjchem-405	107	25	=	=	SYM
eurjchem-405	107	26	2298	2298	NUM
eurjchem-405	107	27	,	,	PUNCT
eurjchem-405	107	28	slope	slope	NOUN
eurjchem-405	107	29	=	=	NOUN
eurjchem-405	107	30	0.95	0.95	NUM
eurjchem-405	107	31	±	±	NUM
eurjchem-405	107	32	0.02	0.02	NUM
eurjchem-405	107	33	,	,	PUNCT
eurjchem-405	107	34	and	and	CCONJ
eurjchem-405	107	35	c	c	X
eurjchem-405	107	36	=	=	SYM
eurjchem-405	107	37	‐0.03	‐0.03	PROPN
eurjchem-405	107	38	±	±	NUM
eurjchem-405	107	39	0.02	0.02	NUM
eurjchem-405	107	40	.	.	PUNCT
eurjchem-405	108	1	using	use	VERB
eurjchem-405	108	2	equation	equation	NOUN
eurjchem-405	108	3	1	1	NUM
eurjchem-405	108	4	without	without	ADP
eurjchem-405	108	5	the	the	DET
eurjchem-405	108	6	97	97	NUM
eurjchem-405	108	7	%	%	NOUN
eurjchem-405	108	8	hfip	hfip	NOUN
eurjchem-405	108	9	value	value	NOUN
eurjchem-405	108	10	,	,	PUNCT
eurjchem-405	108	11	the	the	DET
eurjchem-405	108	12	correlation	correlation	NOUN
eurjchem-405	108	13	and	and	CCONJ
eurjchem-405	108	14	f‐	f‐	NOUN
eurjchem-405	108	15	test	test	NOUN
eurjchem-405	108	16	values	value	NOUN
eurjchem-405	108	17	are	be	AUX
eurjchem-405	108	18	improved	improve	VERB
eurjchem-405	108	19	slightly	slightly	ADV
eurjchem-405	108	20	to	to	ADP
eurjchem-405	108	21	0.968	0.968	NUM
eurjchem-405	108	22	and	and	CCONJ
eurjchem-405	108	23	347	347	NUM
eurjchem-405	108	24	,	,	PUNCT
eurjchem-405	108	25	respectively	respectively	ADV
eurjchem-405	108	26	,	,	PUNCT
eurjchem-405	108	27	the	the	DET
eurjchem-405	108	28	l	l	NOUN
eurjchem-405	108	29	value	value	NOUN
eurjchem-405	108	30	increases	increase	VERB
eurjchem-405	108	31	to	to	ADP
eurjchem-405	108	32	1.54	1.54	NUM
eurjchem-405	108	33	±	±	NUM
eurjchem-405	108	34	0.06	0.06	NUM
eurjchem-405	108	35	,	,	PUNCT
eurjchem-405	108	36	the	the	DET
eurjchem-405	108	37	m	m	NOUN
eurjchem-405	108	38	value	value	NOUN
eurjchem-405	108	39	is	be	AUX
eurjchem-405	108	40	0.54	0.54	NUM
eurjchem-405	108	41	±	±	NUM
eurjchem-405	108	42	0.03	0.03	NUM
eurjchem-405	108	43	,	,	PUNCT
eurjchem-405	108	44	and	and	CCONJ
eurjchem-405	108	45	c	c	X
eurjchem-405	108	46	=	=	SYM
eurjchem-405	108	47	0.05	0.05	NUM
eurjchem-405	108	48	±	±	NUM
eurjchem-405	108	49	0.06	0.06	NUM
eurjchem-405	108	50	for	for	ADP
eurjchem-405	108	51	1	1	NUM
eurjchem-405	108	52	.	.	PUNCT
eurjchem-405	109	1	furthermore	furthermore	ADV
eurjchem-405	109	2	,	,	PUNCT
eurjchem-405	109	3	a	a	DET
eurjchem-405	109	4	comparison	comparison	NOUN
eurjchem-405	109	5	of	of	ADP
eurjchem-405	109	6	1	1	NUM
eurjchem-405	109	7	and	and	CCONJ
eurjchem-405	109	8	3	3	NUM
eurjchem-405	109	9	in	in	ADP
eurjchem-405	109	10	46	46	NUM
eurjchem-405	109	11	identical	identical	ADJ
eurjchem-405	109	12	common	common	ADJ
eurjchem-405	109	13	solvents	solvent	NOUN
eurjchem-405	109	14	yield	yield	VERB
eurjchem-405	109	15	very	very	ADV
eurjchem-405	109	16	similar	similar	ADJ
eurjchem-405	109	17	l	l	NOUN
eurjchem-405	109	18	and	and	CCONJ
eurjchem-405	109	19	m	m	PROPN
eurjchem-405	109	20	values	value	NOUN
eurjchem-405	109	21	(	(	PUNCT
eurjchem-405	109	22	as	as	SCONJ
eurjchem-405	109	23	shown	show	VERB
eurjchem-405	109	24	in	in	ADP
eurjchem-405	109	25	table	table	NOUN
eurjchem-405	109	26	1	1	NUM
eurjchem-405	109	27	)	)	PUNCT
eurjchem-405	109	28	.	.	PUNCT
eurjchem-405	110	1	d’souza	d’souza	NOUN
eurjchem-405	110	2	et	et	PROPN
eurjchem-405	110	3	al	al	PROPN
eurjchem-405	110	4	.	.	PUNCT
eurjchem-405	110	5	/	/	SYM
eurjchem-405	110	6	european	european	PROPN
eurjchem-405	110	7	journal	journal	PROPN
eurjchem-405	110	8	of	of	ADP
eurjchem-405	110	9	chemistry	chemistry	NOUN
eurjchem-405	110	10	2	2	NUM
eurjchem-405	110	11	(	(	PUNCT
eurjchem-405	110	12	2	2	NUM
eurjchem-405	110	13	)	)	PUNCT
eurjchem-405	110	14	(	(	PUNCT
eurjchem-405	110	15	2011	2011	NUM
eurjchem-405	110	16	)	)	PUNCT
eurjchem-405	110	17	130‐135	130‐135	NOUN
eurjchem-405	111	1	133	133	NUM
eurjchem-405	111	2	table	table	NOUN
eurjchem-405	111	3	2	2	NUM
eurjchem-405	111	4	.	.	PUNCT
eurjchem-405	111	5	correlation	correlation	NOUN
eurjchem-405	111	6	of	of	ADP
eurjchem-405	111	7	the	the	DET
eurjchem-405	111	8	specific	specific	ADJ
eurjchem-405	111	9	rates	rate	NOUN
eurjchem-405	111	10	of	of	ADP
eurjchem-405	111	11	reaction	reaction	NOUN
eurjchem-405	111	12	of	of	ADP
eurjchem-405	111	13	a	a	DET
eurjchem-405	111	14	variety	variety	NOUN
eurjchem-405	111	15	of	of	ADP
eurjchem-405	111	16	rococl	rococl	NOUN
eurjchem-405	111	17	substrates	substrate	NOUN
eurjchem-405	111	18	using	use	VERB
eurjchem-405	111	19	the	the	DET
eurjchem-405	111	20	extended	extended	ADJ
eurjchem-405	111	21	grunwald‐winstein	grunwald‐winstein	ADJ
eurjchem-405	111	22	equation	equation	NOUN
eurjchem-405	111	23	(	(	PUNCT
eurjchem-405	111	24	equation	equation	NOUN
eurjchem-405	111	25	1	1	NUM
eurjchem-405	111	26	)	)	PUNCT
eurjchem-405	111	27	.	.	PUNCT
eurjchem-405	112	1	substrate	substrate	NOUN
eurjchem-405	112	2	na	na	ADP
eurjchem-405	112	3	lb	lb	NUM
eurjchem-405	112	4	mb	mb	PROPN
eurjchem-405	112	5	cc	cc	PROPN
eurjchem-405	112	6	rd	rd	PROPN
eurjchem-405	112	7	fe	fe	PROPN
eurjchem-405	112	8	mechanism	mechanism	NOUN
eurjchem-405	112	9	3f	3f	PROPN
eurjchem-405	112	10	49	49	NUM
eurjchem-405	112	11	1.66	1.66	NUM
eurjchem-405	112	12	±	±	NUM
eurjchem-405	112	13	0.05	0.05	NUM
eurjchem-405	112	14	0.56	0.56	NUM
eurjchem-405	112	15	±	±	NUM
eurjchem-405	112	16	0.03	0.03	NUM
eurjchem-405	112	17	0.15	0.15	NUM
eurjchem-405	112	18	±	±	NUM
eurjchem-405	112	19	0.07	0.07	NUM
eurjchem-405	112	20	0.980	0.980	NUM
eurjchem-405	112	21	568	568	NUM
eurjchem-405	112	22	a‐e	a‐e	PROPN
eurjchem-405	112	23	meococlg	meococlg	VERB
eurjchem-405	112	24	19	19	NUM
eurjchem-405	112	25	1.59	1.59	NUM
eurjchem-405	112	26	±	±	NUM
eurjchem-405	112	27	0.09	0.09	NUM
eurjchem-405	112	28	0.58	0.58	NUM
eurjchem-405	112	29	±	±	NUM
eurjchem-405	112	30	0.05	0.05	NUM
eurjchem-405	112	31	0.16	0.16	NUM
eurjchem-405	112	32	±	±	NUM
eurjchem-405	112	33	0.07	0.07	NUM
eurjchem-405	112	34	0.977	0.977	NUM
eurjchem-405	112	35	a‐e	a‐e	PROPN
eurjchem-405	112	36	etococlh	etococlh	PROPN
eurjchem-405	112	37	28	28	NUM
eurjchem-405	112	38	1.56	1.56	NUM
eurjchem-405	112	39	±	±	NUM
eurjchem-405	112	40	0.09	0.09	NUM
eurjchem-405	112	41	0.55	0.55	NUM
eurjchem-405	112	42	±	±	NUM
eurjchem-405	112	43	0.03	0.03	NUM
eurjchem-405	112	44	0.19	0.19	NUM
eurjchem-405	112	45	±	±	NUM
eurjchem-405	112	46	0.24	0.24	NUM
eurjchem-405	112	47	0.967	0.967	NUM
eurjchem-405	112	48	179	179	NUM
eurjchem-405	113	1	a‐e	a‐e	PROPN
eurjchem-405	113	2	7	7	NUM
eurjchem-405	113	3	0.69	0.69	NUM
eurjchem-405	113	4	±	±	NUM
eurjchem-405	113	5	0.13	0.13	NUM
eurjchem-405	113	6	0.82	0.82	NUM
eurjchem-405	113	7	±	±	NUM
eurjchem-405	113	8	0.16	0.16	NUM
eurjchem-405	113	9	‐2.40	‐2.40	PUNCT
eurjchem-405	113	10	±	±	NUM
eurjchem-405	113	11	0.27	0.27	NUM
eurjchem-405	113	12	0.946	0.946	NUM
eurjchem-405	113	13	17	17	NUM
eurjchem-405	113	14	sn1	sn1	PROPN
eurjchem-405	113	15	2i	2i	NUM
eurjchem-405	113	16	9	9	NUM
eurjchem-405	113	17	1.35	1.35	NUM
eurjchem-405	113	18	±	±	NUM
eurjchem-405	113	19	0.22	0.22	NUM
eurjchem-405	113	20	0.40	0.40	NUM
eurjchem-405	113	21	±	±	NUM
eurjchem-405	113	22	0.05	0.05	NUM
eurjchem-405	113	23	0.18	0.18	NUM
eurjchem-405	113	24	±	±	NUM
eurjchem-405	113	25	0.07	0.07	NUM
eurjchem-405	113	26	0.960	0.960	NUM
eurjchem-405	113	27	35	35	NUM
eurjchem-405	113	28	a‐e	a‐e	PROPN
eurjchem-405	113	29	16	16	NUM
eurjchem-405	113	30	0.28	0.28	NUM
eurjchem-405	113	31	±	±	NUM
eurjchem-405	113	32	0.04	0.04	NUM
eurjchem-405	113	33	0.59	0.59	NUM
eurjchem-405	113	34	±	±	NUM
eurjchem-405	113	35	0.04	0.04	NUM
eurjchem-405	113	36	‐0.32	‐0.32	NUM
eurjchem-405	113	37	±	±	NUM
eurjchem-405	113	38	0.06	0.06	NUM
eurjchem-405	113	39	0.982	0.982	NUM
eurjchem-405	113	40	176	176	NUM
eurjchem-405	113	41	fragmentation‐ionization	fragmentation‐ionization	NOUN
eurjchem-405	113	42	n‐prococlj	n‐prococlj	NUM
eurjchem-405	113	43	19	19	NUM
eurjchem-405	113	44	0.45	0.45	NUM
eurjchem-405	113	45	±	±	NUM
eurjchem-405	113	46	0.12	0.12	NUM
eurjchem-405	113	47	0.78	0.78	NUM
eurjchem-405	113	48	±	±	NOUN
eurjchem-405	113	49	0.09	0.09	NUM
eurjchem-405	113	50	‐0.26	‐0.26	NOUN
eurjchem-405	113	51	±	±	NUM
eurjchem-405	113	52	0.11	0.11	NUM
eurjchem-405	113	53	0.960	0.960	NUM
eurjchem-405	113	54	93	93	NUM
eurjchem-405	113	55	sn1	sn1	PROPN
eurjchem-405	113	56	1	1	NUM
eurjchem-405	113	57	51k	51k	PROPN
eurjchem-405	113	58	1.40	1.40	NUM
eurjchem-405	113	59	±	±	NUM
eurjchem-405	113	60	0.06	0.06	NUM
eurjchem-405	113	61	0.51	0.51	NUM
eurjchem-405	113	62	±	±	NUM
eurjchem-405	113	63	0.03	0.03	NUM
eurjchem-405	113	64	‐0.02	‐0.02	NOUN
eurjchem-405	113	65	±	±	NOUN
eurjchem-405	113	66	0.07	0.07	NUM
eurjchem-405	113	67	0.962	0.962	NUM
eurjchem-405	113	68	294	294	NUM
eurjchem-405	113	69	50l	50l	NUM
eurjchem-405	113	70	1.54	1.54	NUM
eurjchem-405	113	71	±	±	NUM
eurjchem-405	113	72	0.06	0.06	NUM
eurjchem-405	113	73	0.54	0.54	NUM
eurjchem-405	113	74	±	±	NUM
eurjchem-405	113	75	0.03	0.03	NUM
eurjchem-405	113	76	0.05	0.05	NUM
eurjchem-405	113	77	±	±	NUM
eurjchem-405	113	78	0.06	0.06	NUM
eurjchem-405	113	79	0.968	0.968	NUM
eurjchem-405	113	80	347	347	NUM
eurjchem-405	113	81	a‐e	a‐e	PROPN
eurjchem-405	113	82	1	1	NUM
eurjchem-405	113	83	46	46	NUM
eurjchem-405	113	84	m	m	NUM
eurjchem-405	113	85	1.52	1.52	NUM
eurjchem-405	113	86	±	±	NUM
eurjchem-405	113	87	0.06	0.06	NUM
eurjchem-405	113	88	0.53	0.53	NUM
eurjchem-405	113	89	±	±	NUM
eurjchem-405	113	90	0.03	0.03	NUM
eurjchem-405	113	91	0.08	0.08	NUM
eurjchem-405	113	92	±	±	NUM
eurjchem-405	113	93	0.06	0.06	NUM
eurjchem-405	113	94	0.971	0.971	NUM
eurjchem-405	113	95	356	356	NUM
eurjchem-405	113	96	3	3	NUM
eurjchem-405	113	97	46n	46n	NUM
eurjchem-405	113	98	1.58	1.58	NUM
eurjchem-405	113	99	±	±	NUM
eurjchem-405	113	100	0.06	0.06	NUM
eurjchem-405	113	101	0.54	0.54	NUM
eurjchem-405	113	102	±	±	NUM
eurjchem-405	113	103	0.03	0.03	NUM
eurjchem-405	113	104	0.14	0.14	NUM
eurjchem-405	113	105	±	±	NUM
eurjchem-405	113	106	0.06	0.06	NUM
eurjchem-405	113	107	0.970	0.970	NUM
eurjchem-405	113	108	336	336	NUM
eurjchem-405	113	109	a	a	DET
eurjchem-405	113	110	n	n	NOUN
eurjchem-405	113	111	is	be	AUX
eurjchem-405	113	112	the	the	DET
eurjchem-405	113	113	number	number	NOUN
eurjchem-405	113	114	of	of	ADP
eurjchem-405	113	115	solvents	solvent	NOUN
eurjchem-405	113	116	.	.	PUNCT
eurjchem-405	114	1	b	b	X
eurjchem-405	114	2	with	with	ADP
eurjchem-405	114	3	associated	associated	ADJ
eurjchem-405	114	4	standard	standard	ADJ
eurjchem-405	114	5	error	error	NOUN
eurjchem-405	114	6	.	.	PUNCT
eurjchem-405	115	1	c	c	NOUN
eurjchem-405	115	2	the	the	DET
eurjchem-405	115	3	earlier	early	ADJ
eurjchem-405	115	4	values	value	NOUN
eurjchem-405	115	5	are	be	AUX
eurjchem-405	115	6	accompanied	accompany	VERB
eurjchem-405	115	7	by	by	ADP
eurjchem-405	115	8	standard	standard	ADJ
eurjchem-405	115	9	error	error	NOUN
eurjchem-405	115	10	of	of	ADP
eurjchem-405	115	11	the	the	DET
eurjchem-405	115	12	estimate	estimate	NOUN
eurjchem-405	115	13	.	.	PUNCT
eurjchem-405	116	1	d	d	PRON
eurjchem-405	116	2	correlation	correlation	NOUN
eurjchem-405	116	3	coefficient	coefficient	NOUN
eurjchem-405	116	4	.	.	PUNCT
eurjchem-405	117	1	e	e	X
eurjchem-405	117	2	f‐test	f‐test	PUNCT
eurjchem-405	117	3	value	value	NOUN
eurjchem-405	117	4	.	.	PUNCT
eurjchem-405	118	1	f	f	PROPN
eurjchem-405	118	2	values	value	NOUN
eurjchem-405	118	3	taken	take	VERB
eurjchem-405	118	4	from	from	ADP
eurjchem-405	118	5	ref	ref	NOUN
eurjchem-405	118	6	.	.	PUNCT
eurjchem-405	119	1	[	[	X
eurjchem-405	119	2	23	23	NUM
eurjchem-405	119	3	]	]	PUNCT
eurjchem-405	119	4	.	.	PUNCT
eurjchem-405	120	1	g	g	NOUN
eurjchem-405	120	2	values	value	NOUN
eurjchem-405	120	3	taken	take	VERB
eurjchem-405	120	4	from	from	ADP
eurjchem-405	120	5	ref	ref	NOUN
eurjchem-405	120	6	.	.	PUNCT
eurjchem-405	121	1	[	[	X
eurjchem-405	121	2	14	14	NUM
eurjchem-405	121	3	]	]	PUNCT
eurjchem-405	121	4	.	.	PUNCT
eurjchem-405	122	1	h	h	NOUN
eurjchem-405	122	2	values	value	NOUN
eurjchem-405	122	3	taken	take	VERB
eurjchem-405	122	4	from	from	ADP
eurjchem-405	122	5	ref	ref	NOUN
eurjchem-405	122	6	.	.	PUNCT
eurjchem-405	123	1	[	[	X
eurjchem-405	123	2	12	12	NUM
eurjchem-405	123	3	]	]	PUNCT
eurjchem-405	123	4	.	.	PUNCT
eurjchem-405	124	1	i	i	PRON
eurjchem-405	124	2	values	value	NOUN
eurjchem-405	124	3	taken	take	VERB
eurjchem-405	124	4	from	from	ADP
eurjchem-405	124	5	ref	ref	NOUN
eurjchem-405	124	6	.	.	PUNCT
eurjchem-405	125	1	[	[	X
eurjchem-405	125	2	27	27	NUM
eurjchem-405	125	3	]	]	PUNCT
eurjchem-405	125	4	.	.	PUNCT
eurjchem-405	126	1	j	j	PROPN
eurjchem-405	126	2	values	value	NOUN
eurjchem-405	126	3	taken	take	VERB
eurjchem-405	126	4	from	from	ADP
eurjchem-405	126	5	ref	ref	NOUN
eurjchem-405	126	6	.	.	PUNCT
eurjchem-405	127	1	[	[	X
eurjchem-405	127	2	20	20	NUM
eurjchem-405	127	3	]	]	PUNCT
eurjchem-405	127	4	.	.	PUNCT
eurjchem-405	128	1	k	k	PROPN
eurjchem-405	128	2	all	all	PRON
eurjchem-405	128	3	available	available	ADJ
eurjchem-405	128	4	solvents	solvent	NOUN
eurjchem-405	128	5	at	at	ADP
eurjchem-405	128	6	10.0	10.0	NUM
eurjchem-405	128	7	oc	oc	NOUN
eurjchem-405	128	8	;	;	PUNCT
eurjchem-405	128	9	including	include	VERB
eurjchem-405	128	10	the	the	DET
eurjchem-405	128	11	eleven	eleven	NUM
eurjchem-405	128	12	listed	list	VERB
eurjchem-405	128	13	in	in	ADP
eurjchem-405	128	14	table	table	NOUN
eurjchem-405	128	15	1	1	NUM
eurjchem-405	128	16	plus	plus	CCONJ
eurjchem-405	128	17	40	40	NUM
eurjchem-405	128	18	from	from	ADP
eurjchem-405	128	19	ref	ref	NOUN
eurjchem-405	128	20	.	.	PUNCT
eurjchem-405	129	1	[	[	X
eurjchem-405	129	2	23	23	NUM
eurjchem-405	129	3	]	]	PUNCT
eurjchem-405	129	4	.	.	PUNCT
eurjchem-405	130	1	l	l	NOUN
eurjchem-405	131	1	no	no	DET
eurjchem-405	131	2	97	97	NUM
eurjchem-405	131	3	hfip	hfip	NOUN
eurjchem-405	131	4	.	.	PUNCT
eurjchem-405	132	1	m	m	AUX
eurjchem-405	132	2	to	to	PART
eurjchem-405	132	3	compare	compare	VERB
eurjchem-405	132	4	with	with	ADP
eurjchem-405	132	5	3	3	NUM
eurjchem-405	132	6	in	in	ADP
eurjchem-405	132	7	identical	identical	ADJ
eurjchem-405	132	8	solvents	solvent	NOUN
eurjchem-405	132	9	.	.	PUNCT
eurjchem-405	133	1	n	n	PRON
eurjchem-405	133	2	to	to	PART
eurjchem-405	133	3	compare	compare	VERB
eurjchem-405	133	4	with	with	ADP
eurjchem-405	133	5	1	1	NUM
eurjchem-405	133	6	in	in	ADP
eurjchem-405	133	7	identical	identical	ADJ
eurjchem-405	133	8	solvents	solvent	NOUN
eurjchem-405	133	9	.	.	PUNCT
eurjchem-405	134	1	figure	figure	VERB
eurjchem-405	134	2	3	3	NUM
eurjchem-405	134	3	.	.	PUNCT
eurjchem-405	135	1	the	the	DET
eurjchem-405	135	2	plot	plot	NOUN
eurjchem-405	135	3	of	of	ADP
eurjchem-405	135	4	log	log	NOUN
eurjchem-405	135	5	(	(	PUNCT
eurjchem-405	135	6	k	k	NOUN
eurjchem-405	135	7	/	/	SYM
eurjchem-405	135	8	ko	ko	PROPN
eurjchem-405	135	9	)	)	PUNCT
eurjchem-405	135	10	for	for	ADP
eurjchem-405	135	11	isopropenyl	isopropenyl	ADJ
eurjchem-405	135	12	chloroformate	chloroformate	NOUN
eurjchem-405	135	13	(	(	PUNCT
eurjchem-405	135	14	1	1	NUM
eurjchem-405	135	15	)	)	PUNCT
eurjchem-405	135	16	against	against	ADP
eurjchem-405	135	17	1.54	1.54	NUM
eurjchem-405	135	18	nt	not	PART
eurjchem-405	135	19	+	+	NUM
eurjchem-405	135	20	0.54	0.54	NUM
eurjchem-405	135	21	ycl	ycl	NOUN
eurjchem-405	135	22	in	in	ADP
eurjchem-405	135	23	the	the	DET
eurjchem-405	135	24	51	51	NUM
eurjchem-405	135	25	common	common	ADJ
eurjchem-405	135	26	pure	pure	ADJ
eurjchem-405	135	27	and	and	CCONJ
eurjchem-405	135	28	binary	binary	ADJ
eurjchem-405	135	29	solvents	solvent	NOUN
eurjchem-405	135	30	studied	study	VERB
eurjchem-405	135	31	.	.	PUNCT
eurjchem-405	136	1	an	an	DET
eurjchem-405	136	2	examination	examination	NOUN
eurjchem-405	136	3	of	of	ADP
eurjchem-405	136	4	the	the	DET
eurjchem-405	136	5	l	l	PROPN
eurjchem-405	136	6	/	/	SYM
eurjchem-405	136	7	m	m	NOUN
eurjchem-405	136	8	ratios	ratio	NOUN
eurjchem-405	136	9	(	(	PUNCT
eurjchem-405	136	10	2.87	2.87	NUM
eurjchem-405	136	11	for	for	ADP
eurjchem-405	136	12	1	1	NUM
eurjchem-405	136	13	and	and	CCONJ
eurjchem-405	136	14	2.93	2.93	NUM
eurjchem-405	136	15	for	for	ADP
eurjchem-405	136	16	3	3	NUM
eurjchem-405	136	17	)	)	PUNCT
eurjchem-405	136	18	implies	imply	VERB
eurjchem-405	136	19	that	that	SCONJ
eurjchem-405	136	20	the	the	DET
eurjchem-405	136	21	solvolyses	solvolyse	NOUN
eurjchem-405	136	22	of	of	ADP
eurjchem-405	136	23	1	1	NUM
eurjchem-405	136	24	proceeds	proceed	NOUN
eurjchem-405	136	25	with	with	ADP
eurjchem-405	136	26	a	a	DET
eurjchem-405	136	27	likely	likely	ADJ
eurjchem-405	136	28	very	very	ADV
eurjchem-405	136	29	similar	similar	ADJ
eurjchem-405	136	30	tetrahedral	tetrahedral	ADJ
eurjchem-405	136	31	transition	transition	NOUN
eurjchem-405	136	32	state	state	NOUN
eurjchem-405	136	33	to	to	ADP
eurjchem-405	136	34	that	that	PRON
eurjchem-405	136	35	observed	observe	VERB
eurjchem-405	136	36	in	in	ADP
eurjchem-405	136	37	3	3	NUM
eurjchem-405	136	38	in	in	ADP
eurjchem-405	136	39	all	all	DET
eurjchem-405	136	40	solvents	solvent	NOUN
eurjchem-405	136	41	except	except	SCONJ
eurjchem-405	136	42	97	97	NUM
eurjchem-405	136	43	%	%	NOUN
eurjchem-405	136	44	hfip	hfip	NOUN
eurjchem-405	136	45	.	.	PUNCT
eurjchem-405	137	1	the	the	DET
eurjchem-405	137	2	very	very	ADV
eurjchem-405	137	3	large	large	ADJ
eurjchem-405	137	4	sensitivity	sensitivity	NOUN
eurjchem-405	137	5	(	(	PUNCT
eurjchem-405	137	6	l	l	NOUN
eurjchem-405	137	7	value	value	NOUN
eurjchem-405	137	8	of	of	ADP
eurjchem-405	137	9	1.54	1.54	NUM
eurjchem-405	137	10	)	)	PUNCT
eurjchem-405	137	11	to	to	ADP
eurjchem-405	137	12	changes	change	NOUN
eurjchem-405	137	13	in	in	ADP
eurjchem-405	137	14	solvent	solvent	ADJ
eurjchem-405	137	15	nucleophilicity	nucleophilicity	NOUN
eurjchem-405	137	16	suggests	suggest	VERB
eurjchem-405	137	17	a	a	DET
eurjchem-405	137	18	very	very	ADV
eurjchem-405	137	19	pronounced	pronounced	ADJ
eurjchem-405	137	20	involvement	involvement	NOUN
eurjchem-405	137	21	of	of	ADP
eurjchem-405	137	22	the	the	DET
eurjchem-405	137	23	solvent	solvent	NOUN
eurjchem-405	137	24	as	as	ADP
eurjchem-405	137	25	a	a	DET
eurjchem-405	137	26	nucleophile	nucleophile	NOUN
eurjchem-405	137	27	in	in	ADP
eurjchem-405	137	28	the	the	DET
eurjchem-405	137	29	rate‐determining	rate‐determining	NOUN
eurjchem-405	137	30	step	step	NOUN
eurjchem-405	137	31	,	,	PUNCT
eurjchem-405	137	32	consistent	consistent	ADJ
eurjchem-405	137	33	with	with	ADP
eurjchem-405	137	34	the	the	DET
eurjchem-405	137	35	first	first	ADJ
eurjchem-405	137	36	step	step	NOUN
eurjchem-405	137	37	of	of	ADP
eurjchem-405	137	38	an	an	DET
eurjchem-405	137	39	addition	addition	NOUN
eurjchem-405	137	40	–	–	PUNCT
eurjchem-405	137	41	elimination	elimination	NOUN
eurjchem-405	137	42	mechanism	mechanism	NOUN
eurjchem-405	137	43	being	be	AUX
eurjchem-405	137	44	rate‐determining	rate‐determine	VERB
eurjchem-405	137	45	(	(	PUNCT
eurjchem-405	137	46	scheme	scheme	NOUN
eurjchem-405	137	47	4	4	NUM
eurjchem-405	137	48	)	)	PUNCT
eurjchem-405	137	49	.	.	PUNCT
eurjchem-405	138	1	the	the	DET
eurjchem-405	138	2	relatively	relatively	ADV
eurjchem-405	138	3	high	high	ADJ
eurjchem-405	138	4	kmeoh	kmeoh	NOUN
eurjchem-405	138	5	/	/	SYM
eurjchem-405	138	6	kmeod	kmeod	PROPN
eurjchem-405	138	7	(	(	PUNCT
eurjchem-405	138	8	ksie	ksie	ADJ
eurjchem-405	138	9	)	)	PUNCT
eurjchem-405	138	10	value	value	NOUN
eurjchem-405	138	11	reported	report	VERB
eurjchem-405	138	12	[	[	X
eurjchem-405	138	13	22	22	NUM
eurjchem-405	138	14	]	]	PUNCT
eurjchem-405	138	15	for	for	ADP
eurjchem-405	138	16	1	1	NUM
eurjchem-405	138	17	in	in	ADP
eurjchem-405	138	18	methanol	methanol	NOUN
eurjchem-405	138	19	(	(	PUNCT
eurjchem-405	138	20	2.33	2.33	NUM
eurjchem-405	138	21	)	)	PUNCT
eurjchem-405	138	22	,	,	PUNCT
eurjchem-405	138	23	and	and	CCONJ
eurjchem-405	138	24	the	the	DET
eurjchem-405	138	25	kh2o	kh2o	NOUN
eurjchem-405	138	26	/	/	SYM
eurjchem-405	138	27	kd2o	kd2o	NOUN
eurjchem-405	138	28	value	value	NOUN
eurjchem-405	138	29	of	of	ADP
eurjchem-405	138	30	2.08	2.08	NUM
eurjchem-405	138	31	,	,	PUNCT
eurjchem-405	138	32	are	be	AUX
eurjchem-405	138	33	similar	similar	ADJ
eurjchem-405	138	34	to	to	ADP
eurjchem-405	138	35	the	the	DET
eurjchem-405	138	36	methanolysis	methanolysis	NOUN
eurjchem-405	138	37	ksie	ksie	ADJ
eurjchem-405	138	38	values	value	NOUN
eurjchem-405	138	39	of	of	ADP
eurjchem-405	138	40	2.3‐2.5	2.3‐2.5	NUM
eurjchem-405	138	41	reported	report	VERB
eurjchem-405	138	42	[	[	X
eurjchem-405	138	43	75,76	75,76	NOUN
eurjchem-405	138	44	]	]	X
eurjchem-405	138	45	for	for	ADP
eurjchem-405	138	46	a	a	DET
eurjchem-405	138	47	series	series	NOUN
eurjchem-405	138	48	of	of	ADP
eurjchem-405	138	49	substituted	substitute	VERB
eurjchem-405	138	50	phenyl	phenyl	NOUN
eurjchem-405	138	51	chloroformates	chloroformate	NOUN
eurjchem-405	138	52	,	,	PUNCT
eurjchem-405	138	53	and	and	CCONJ
eurjchem-405	138	54	a	a	DET
eurjchem-405	138	55	ksie	ksie	ADJ
eurjchem-405	138	56	value	value	NOUN
eurjchem-405	138	57	of	of	ADP
eurjchem-405	138	58	1.79	1.79	NUM
eurjchem-405	138	59	for	for	ADP
eurjchem-405	138	60	phenyl	phenyl	NOUN
eurjchem-405	138	61	chloroformate	chloroformate	NOUN
eurjchem-405	139	1	[	[	X
eurjchem-405	139	2	51	51	NUM
eurjchem-405	139	3	]	]	PUNCT
eurjchem-405	139	4	in	in	ADP
eurjchem-405	139	5	water	water	NOUN
eurjchem-405	139	6	.	.	PUNCT
eurjchem-405	140	1	these	these	DET
eurjchem-405	140	2	values	value	NOUN
eurjchem-405	140	3	are	be	AUX
eurjchem-405	140	4	within	within	ADP
eurjchem-405	140	5	the	the	DET
eurjchem-405	140	6	range	range	NOUN
eurjchem-405	140	7	predicted	predict	VERB
eurjchem-405	140	8	for	for	ADP
eurjchem-405	140	9	a	a	DET
eurjchem-405	140	10	bimolecular	bimolecular	ADJ
eurjchem-405	140	11	solvolysis	solvolysis	NOUN
eurjchem-405	140	12	accompanied	accompany	VERB
eurjchem-405	140	13	by	by	ADP
eurjchem-405	140	14	a	a	DET
eurjchem-405	140	15	general	general	ADJ
eurjchem-405	140	16	base	base	NOUN
eurjchem-405	140	17	catalysis	catalysis	NOUN
eurjchem-405	140	18	.	.	PUNCT
eurjchem-405	141	1	using	use	VERB
eurjchem-405	141	2	the	the	DET
eurjchem-405	141	3	equation	equation	NOUN
eurjchem-405	141	4	log	log	NOUN
eurjchem-405	141	5	(	(	PUNCT
eurjchem-405	141	6	k	k	NOUN
eurjchem-405	141	7	/	/	SYM
eurjchem-405	141	8	ko	ko	PROPN
eurjchem-405	141	9	)	)	PUNCT
eurjchem-405	142	1	=	=	NOUN
eurjchem-405	142	2	1.54	1.54	NUM
eurjchem-405	142	3	nt	not	PART
eurjchem-405	142	4	+	+	NUM
eurjchem-405	142	5	0.54	0.54	NUM
eurjchem-405	142	6	ycl	ycl	NOUN
eurjchem-405	142	7	+	+	ADV
eurjchem-405	142	8	0.05	0.05	NUM
eurjchem-405	142	9	,	,	PUNCT
eurjchem-405	142	10	we	we	PRON
eurjchem-405	142	11	calculate	calculate	VERB
eurjchem-405	142	12	the	the	DET
eurjchem-405	142	13	bimolecular	bimolecular	ADJ
eurjchem-405	142	14	reaction	reaction	NOUN
eurjchem-405	142	15	rate	rate	NOUN
eurjchem-405	142	16	constant	constant	ADJ
eurjchem-405	142	17	in	in	ADP
eurjchem-405	142	18	97	97	NUM
eurjchem-405	142	19	%	%	NOUN
eurjchem-405	142	20	hfip	hfip	NOUN
eurjchem-405	142	21	to	to	PART
eurjchem-405	142	22	be	be	AUX
eurjchem-405	142	23	2.75	2.75	NUM
eurjchem-405	142	24	x	x	SYM
eurjchem-405	142	25	10‐9	10‐9	NUM
eurjchem-405	142	26	.	.	PUNCT
eurjchem-405	143	1	this	this	DET
eurjchem-405	143	2	value	value	NOUN
eurjchem-405	143	3	indicates	indicate	VERB
eurjchem-405	143	4	that	that	SCONJ
eurjchem-405	143	5	1	1	NUM
eurjchem-405	143	6	undergoes	undergo	VERB
eurjchem-405	143	7	97	97	NUM
eurjchem-405	143	8	%	%	NOUN
eurjchem-405	143	9	of	of	ADP
eurjchem-405	143	10	the	the	DET
eurjchem-405	143	11	reaction	reaction	NOUN
eurjchem-405	143	12	by	by	ADP
eurjchem-405	143	13	a	a	DET
eurjchem-405	143	14	unimolecular	unimolecular	ADJ
eurjchem-405	143	15	ionization	ionization	NOUN
eurjchem-405	143	16	(	(	PUNCT
eurjchem-405	143	17	sn1	sn1	PROPN
eurjchem-405	143	18	)	)	PUNCT
eurjchem-405	143	19	process	process	NOUN
eurjchem-405	143	20	in	in	ADP
eurjchem-405	143	21	97	97	NUM
eurjchem-405	143	22	%	%	NOUN
eurjchem-405	143	23	hfip	hfip	NOUN
eurjchem-405	143	24	.	.	PUNCT
eurjchem-405	144	1	using	use	VERB
eurjchem-405	144	2	log	log	NOUN
eurjchem-405	144	3	(	(	PUNCT
eurjchem-405	144	4	k	k	NOUN
eurjchem-405	144	5	/	/	SYM
eurjchem-405	144	6	ko	ko	PROPN
eurjchem-405	144	7	)	)	PUNCT
eurjchem-405	145	1	=	=	NOUN
eurjchem-405	145	2	1.54	1.54	NUM
eurjchem-405	146	1	nt	not	PART
eurjchem-405	146	2	+	+	NUM
eurjchem-405	146	3	0.54	0.54	NUM
eurjchem-405	146	4	ycl	ycl	NOUN
eurjchem-405	146	5	+	+	ADV
eurjchem-405	146	6	0.05	0.05	NUM
eurjchem-405	146	7	,	,	PUNCT
eurjchem-405	146	8	the	the	DET
eurjchem-405	146	9	calculated	calculate	VERB
eurjchem-405	146	10	bimolecular	bimolecular	ADJ
eurjchem-405	146	11	reaction	reaction	NOUN
eurjchem-405	146	12	rate	rate	NOUN
eurjchem-405	146	13	constants	constant	NOUN
eurjchem-405	146	14	for	for	ADP
eurjchem-405	146	15	90	90	NUM
eurjchem-405	146	16	%	%	NOUN
eurjchem-405	146	17	hfip	hfip	NOUN
eurjchem-405	146	18	,	,	PUNCT
eurjchem-405	146	19	70	70	NUM
eurjchem-405	146	20	%	%	NOUN
eurjchem-405	146	21	hfip	hfip	NOUN
eurjchem-405	146	22	,	,	PUNCT
eurjchem-405	146	23	50	50	NUM
eurjchem-405	146	24	%	%	NOUN
eurjchem-405	146	25	hfip	hfip	NOUN
eurjchem-405	146	26	,	,	PUNCT
eurjchem-405	146	27	and	and	CCONJ
eurjchem-405	146	28	97	97	NUM
eurjchem-405	146	29	%	%	NOUN
eurjchem-405	146	30	tfe	tfe	NOUN
eurjchem-405	146	31	,	,	PUNCT
eurjchem-405	146	32	are	be	AUX
eurjchem-405	146	33	1.64	1.64	NUM
eurjchem-405	146	34	x	x	SYM
eurjchem-405	146	35	10‐7	10‐7	NUM
eurjchem-405	146	36	,	,	PUNCT
eurjchem-405	146	37	1.94	1.94	NUM
eurjchem-405	146	38	x	x	SYM
eurjchem-405	146	39	10‐6	10‐6	NUM
eurjchem-405	146	40	,	,	PUNCT
eurjchem-405	146	41	9.22	9.22	NUM
eurjchem-405	146	42	x	x	SYM
eurjchem-405	146	43	10‐6	10‐6	NUM
eurjchem-405	146	44	,	,	PUNCT
eurjchem-405	146	45	and	and	CCONJ
eurjchem-405	146	46	1.56	1.56	NUM
eurjchem-405	146	47	x	x	SYM
eurjchem-405	146	48	10‐7	10‐7	NUM
eurjchem-405	146	49	,	,	PUNCT
eurjchem-405	146	50	respectively	respectively	ADV
eurjchem-405	146	51	.	.	PUNCT
eurjchem-405	147	1	the	the	DET
eurjchem-405	147	2	corresponding	corresponding	ADJ
eurjchem-405	147	3	%	%	NOUN
eurjchem-405	147	4	ionization	ionization	NOUN
eurjchem-405	147	5	values	value	NOUN
eurjchem-405	147	6	for	for	ADP
eurjchem-405	147	7	1	1	NUM
eurjchem-405	147	8	in	in	ADP
eurjchem-405	147	9	90	90	NUM
eurjchem-405	147	10	%	%	NOUN
eurjchem-405	147	11	hfip	hfip	NOUN
eurjchem-405	147	12	,	,	PUNCT
eurjchem-405	147	13	70	70	NUM
eurjchem-405	147	14	%	%	NOUN
eurjchem-405	147	15	hfip	hfip	NOUN
eurjchem-405	147	16	,	,	PUNCT
eurjchem-405	147	17	50	50	NUM
eurjchem-405	147	18	%	%	NOUN
eurjchem-405	147	19	hfip	hfip	NOUN
eurjchem-405	147	20	,	,	PUNCT
eurjchem-405	147	21	and	and	CCONJ
eurjchem-405	147	22	97	97	NUM
eurjchem-405	147	23	%	%	NOUN
eurjchem-405	147	24	tfe	tfe	NOUN
eurjchem-405	147	25	,	,	PUNCT
eurjchem-405	147	26	are	be	AUX
eurjchem-405	147	27	70	70	NUM
eurjchem-405	147	28	%	%	NOUN
eurjchem-405	147	29	,	,	PUNCT
eurjchem-405	147	30	64	64	NUM
eurjchem-405	147	31	%	%	NOUN
eurjchem-405	147	32	,	,	PUNCT
eurjchem-405	147	33	5	5	NUM
eurjchem-405	147	34	%	%	NOUN
eurjchem-405	147	35	,	,	PUNCT
eurjchem-405	147	36	and	and	CCONJ
eurjchem-405	147	37	35	35	NUM
eurjchem-405	147	38	%	%	NOUN
eurjchem-405	147	39	,	,	PUNCT
eurjchem-405	147	40	respectively	respectively	ADV
eurjchem-405	147	41	.	.	PUNCT
eurjchem-405	148	1	as	as	SCONJ
eurjchem-405	148	2	shown	show	VERB
eurjchem-405	148	3	in	in	ADP
eurjchem-405	148	4	figure	figure	NOUN
eurjchem-405	148	5	3	3	NUM
eurjchem-405	148	6	,	,	PUNCT
eurjchem-405	148	7	a	a	DET
eurjchem-405	148	8	plot	plot	NOUN
eurjchem-405	148	9	of	of	ADP
eurjchem-405	148	10	the	the	DET
eurjchem-405	148	11	log	log	NOUN
eurjchem-405	148	12	(	(	PUNCT
eurjchem-405	148	13	k	k	NOUN
eurjchem-405	148	14	/	/	SYM
eurjchem-405	148	15	ko)1	ko)1	NOUN
eurjchem-405	148	16	against	against	ADP
eurjchem-405	148	17	1.54	1.54	NUM
eurjchem-405	148	18	nt	not	PART
eurjchem-405	148	19	+	+	NUM
eurjchem-405	148	20	0.54	0.54	NUM
eurjchem-405	148	21	ycl	ycl	NOUN
eurjchem-405	148	22	shows	show	VERB
eurjchem-405	148	23	these	these	DET
eurjchem-405	148	24	solvents	solvent	NOUN
eurjchem-405	148	25	deviating	deviate	VERB
eurjchem-405	148	26	moderately	moderately	ADV
eurjchem-405	148	27	from	from	ADP
eurjchem-405	148	28	the	the	DET
eurjchem-405	148	29	line‐of‐	line‐of‐	PROPN
eurjchem-405	148	30	best‐fit	best‐fit	NOUN
eurjchem-405	148	31	.	.	PUNCT
eurjchem-405	149	1	scheme	scheme	NOUN
eurjchem-405	149	2	4	4	NUM
eurjchem-405	149	3	in	in	ADP
eurjchem-405	149	4	table	table	NOUN
eurjchem-405	149	5	3	3	NUM
eurjchem-405	149	6	,	,	PUNCT
eurjchem-405	149	7	we	we	PRON
eurjchem-405	149	8	list	list	VERB
eurjchem-405	149	9	the	the	DET
eurjchem-405	149	10	specific	specific	ADJ
eurjchem-405	149	11	rates	rate	NOUN
eurjchem-405	149	12	of	of	ADP
eurjchem-405	149	13	solvolysis	solvolysis	NOUN
eurjchem-405	149	14	for	for	ADP
eurjchem-405	149	15	1	1	NUM
eurjchem-405	149	16	,	,	PUNCT
eurjchem-405	149	17	2	2	NUM
eurjchem-405	149	18	,	,	PUNCT
eurjchem-405	149	19	and	and	CCONJ
eurjchem-405	149	20	3	3	NUM
eurjchem-405	149	21	,	,	PUNCT
eurjchem-405	149	22	in	in	ADP
eurjchem-405	149	23	meoh	meoh	NOUN
eurjchem-405	149	24	,	,	PUNCT
eurjchem-405	149	25	etoh	etoh	NOUN
eurjchem-405	149	26	,	,	PUNCT
eurjchem-405	149	27	70	70	NUM
eurjchem-405	149	28	%	%	NOUN
eurjchem-405	149	29	hfip	hfip	NOUN
eurjchem-405	149	30	and	and	CCONJ
eurjchem-405	149	31	50	50	NUM
eurjchem-405	149	32	%	%	NOUN
eurjchem-405	149	33	hfip	hfip	NOUN
eurjchem-405	149	34	,	,	PUNCT
eurjchem-405	149	35	four	four	NUM
eurjchem-405	149	36	common	common	ADJ
eurjchem-405	149	37	solvents	solvent	NOUN
eurjchem-405	149	38	studied	study	VERB
eurjchem-405	149	39	at	at	ADP
eurjchem-405	149	40	25.0	25.0	NUM
eurjchem-405	149	41	oc	oc	NOUN
eurjchem-405	149	42	.	.	PUNCT
eurjchem-405	149	43	observing	observe	VERB
eurjchem-405	149	44	the	the	DET
eurjchem-405	149	45	effect	effect	NOUN
eurjchem-405	149	46	of	of	ADP
eurjchem-405	149	47	substituent	substituent	NOUN
eurjchem-405	149	48	on	on	ADP
eurjchem-405	149	49	solvolysis	solvolysis	NOUN
eurjchem-405	149	50	rates	rate	NOUN
eurjchem-405	149	51	of	of	ADP
eurjchem-405	149	52	k3	k3	PROPN
eurjchem-405	149	53	>	>	X
eurjchem-405	149	54	k1	k1	PROPN
eurjchem-405	149	55	>	>	PROPN
eurjchem-405	149	56	>	>	X
eurjchem-405	149	57	k2	k2	PROPN
eurjchem-405	149	58	in	in	ADP
eurjchem-405	149	59	meoh	meoh	PROPN
eurjchem-405	149	60	and	and	CCONJ
eurjchem-405	149	61	etoh	etoh	PROPN
eurjchem-405	149	62	indicates	indicate	VERB
eurjchem-405	149	63	that	that	SCONJ
eurjchem-405	149	64	the	the	DET
eurjchem-405	149	65	phenoxy	phenoxy	PROPN
eurjchem-405	149	66	group	group	NOUN
eurjchem-405	149	67	has	have	VERB
eurjchem-405	149	68	a	a	DET
eurjchem-405	149	69	slightly	slightly	ADV
eurjchem-405	149	70	greater	great	ADJ
eurjchem-405	149	71	electron‐	electron‐	NOUN
eurjchem-405	149	72	withdrawing	withdraw	VERB
eurjchem-405	149	73	character	character	NOUN
eurjchem-405	149	74	than	than	ADP
eurjchem-405	149	75	the	the	DET
eurjchem-405	149	76	isopropenoxy	isopropenoxy	ADJ
eurjchem-405	149	77	group	group	NOUN
eurjchem-405	149	78	.	.	PUNCT
eurjchem-405	150	1	also	also	ADV
eurjchem-405	150	2	,	,	PUNCT
eurjchem-405	150	3	the	the	DET
eurjchem-405	150	4	rates	rate	NOUN
eurjchem-405	150	5	of	of	ADP
eurjchem-405	150	6	1	1	NUM
eurjchem-405	150	7	and	and	CCONJ
eurjchem-405	150	8	3	3	NUM
eurjchem-405	150	9	are	be	AUX
eurjchem-405	150	10	significantly	significantly	ADV
eurjchem-405	150	11	greater	great	ADJ
eurjchem-405	150	12	than	than	ADP
eurjchem-405	150	13	2	2	NUM
eurjchem-405	150	14	in	in	ADP
eurjchem-405	150	15	the	the	DET
eurjchem-405	150	16	pure	pure	ADJ
eurjchem-405	150	17	alcohols	alcohol	NOUN
eurjchem-405	150	18	where	where	SCONJ
eurjchem-405	150	19	it	it	PRON
eurjchem-405	150	20	is	be	AUX
eurjchem-405	150	21	now	now	ADV
eurjchem-405	150	22	proposed	propose	VERB
eurjchem-405	150	23	that	that	SCONJ
eurjchem-405	150	24	all	all	DET
eurjchem-405	150	25	three	three	NUM
eurjchem-405	150	26	substrates	substrate	NOUN
eurjchem-405	150	27	follow	follow	VERB
eurjchem-405	150	28	the	the	DET
eurjchem-405	150	29	addition‐elimination	addition‐elimination	NOUN
eurjchem-405	150	30	reaction	reaction	NOUN
eurjchem-405	150	31	.	.	PUNCT
eurjchem-405	151	1	this	this	DET
eurjchem-405	151	2	increase	increase	NOUN
eurjchem-405	151	3	in	in	ADP
eurjchem-405	151	4	rates	rate	NOUN
eurjchem-405	151	5	is	be	AUX
eurjchem-405	151	6	due	due	ADJ
eurjchem-405	151	7	to	to	ADP
eurjchem-405	151	8	the	the	DET
eurjchem-405	151	9	noteworthy	noteworthy	ADJ
eurjchem-405	151	10	increase	increase	NOUN
eurjchem-405	151	11	in	in	ADP
eurjchem-405	151	12	inductive	inductive	ADJ
eurjchem-405	151	13	effects	effect	NOUN
eurjchem-405	151	14	exercised	exercise	VERB
eurjchem-405	151	15	by	by	ADP
eurjchem-405	151	16	the	the	DET
eurjchem-405	151	17	phenoxy	phenoxy	PROPN
eurjchem-405	151	18	and	and	CCONJ
eurjchem-405	151	19	isopropenoxy	isopropenoxy	ADJ
eurjchem-405	151	20	groups	group	NOUN
eurjchem-405	151	21	when	when	SCONJ
eurjchem-405	151	22	compared	compare	VERB
eurjchem-405	151	23	to	to	ADP
eurjchem-405	151	24	that	that	PRON
eurjchem-405	151	25	of	of	ADP
eurjchem-405	151	26	the	the	DET
eurjchem-405	151	27	isopropoxy	isopropoxy	ADJ
eurjchem-405	151	28	group	group	NOUN
eurjchem-405	151	29	.	.	PUNCT
eurjchem-405	152	1	in	in	ADP
eurjchem-405	152	2	70	70	NUM
eurjchem-405	152	3	%	%	NOUN
eurjchem-405	152	4	hfip	hfip	NOUN
eurjchem-405	152	5	and	and	CCONJ
eurjchem-405	152	6	50	50	NUM
eurjchem-405	152	7	%	%	NOUN
eurjchem-405	152	8	hfip	hfip	NOUN
eurjchem-405	152	9	,	,	PUNCT
eurjchem-405	152	10	the	the	DET
eurjchem-405	152	11	trend	trend	NOUN
eurjchem-405	152	12	changes	change	VERB
eurjchem-405	152	13	to	to	ADP
eurjchem-405	152	14	k2	k2	PROPN
eurjchem-405	152	15	>	>	X
eurjchem-405	152	16	k3	k3	PROPN
eurjchem-405	152	17	≊	≊	NUM
eurjchem-405	152	18	k1	k1	NOUN
eurjchem-405	152	19	,	,	PUNCT
eurjchem-405	152	20	due	due	ADP
eurjchem-405	152	21	to	to	ADP
eurjchem-405	152	22	the	the	DET
eurjchem-405	152	23	fact	fact	NOUN
eurjchem-405	152	24	that	that	SCONJ
eurjchem-405	152	25	2	2	NUM
eurjchem-405	152	26	solvolyses	solvolyse	VERB
eurjchem-405	152	27	by	by	ADP
eurjchem-405	152	28	a	a	DET
eurjchem-405	152	29	fragmentation‐ionization	fragmentation‐ionization	NOUN
eurjchem-405	152	30	mechanism	mechanism	NOUN
eurjchem-405	152	31	[	[	X
eurjchem-405	152	32	27	27	NUM
eurjchem-405	152	33	]	]	PUNCT
eurjchem-405	152	34	in	in	ADP
eurjchem-405	152	35	the	the	DET
eurjchem-405	152	36	fluoro‐	fluoro‐	NOUN
eurjchem-405	152	37	alcohols	alcohol	NOUN
eurjchem-405	152	38	.	.	PUNCT
eurjchem-405	153	1	it	it	PRON
eurjchem-405	153	2	is	be	AUX
eurjchem-405	153	3	well	well	ADV
eurjchem-405	153	4	established	establish	VERB
eurjchem-405	153	5	that	that	SCONJ
eurjchem-405	153	6	the	the	DET
eurjchem-405	153	7	vinyl	vinyl	NOUN
eurjchem-405	153	8	cation	cation	NOUN
eurjchem-405	153	9	,	,	PUNCT
eurjchem-405	153	10	like	like	ADP
eurjchem-405	153	11	the	the	DET
eurjchem-405	153	12	structurally	structurally	ADV
eurjchem-405	153	13	related	related	ADJ
eurjchem-405	153	14	phenyl	phenyl	NOUN
eurjchem-405	153	15	cation	cation	NOUN
eurjchem-405	153	16	,	,	PUNCT
eurjchem-405	153	17	is	be	AUX
eurjchem-405	153	18	of	of	ADP
eurjchem-405	153	19	high	high	ADJ
eurjchem-405	153	20	energy	energy	NOUN
eurjchem-405	154	1	[	[	X
eurjchem-405	154	2	77	77	NUM
eurjchem-405	154	3	]	]	PUNCT
eurjchem-405	154	4	and	and	CCONJ
eurjchem-405	154	5	,	,	PUNCT
eurjchem-405	154	6	in	in	ADP
eurjchem-405	154	7	the	the	DET
eurjchem-405	154	8	absence	absence	NOUN
eurjchem-405	154	9	of	of	ADP
eurjchem-405	154	10	stabilizing	stabilize	VERB
eurjchem-405	154	11	factors	factor	NOUN
eurjchem-405	154	12	,	,	PUNCT
eurjchem-405	154	13	such	such	ADJ
eurjchem-405	154	14	as	as	ADP
eurjchem-405	154	15	phenyl	phenyl	NOUN
eurjchem-405	154	16	substituents	substituent	NOUN
eurjchem-405	154	17	[	[	X
eurjchem-405	154	18	78	78	NUM
eurjchem-405	154	19	]	]	PUNCT
eurjchem-405	154	20	,	,	PUNCT
eurjchem-405	154	21	it	it	PRON
eurjchem-405	154	22	will	will	AUX
eurjchem-405	154	23	not	not	PART
eurjchem-405	154	24	be	be	AUX
eurjchem-405	154	25	formed	form	VERB
eurjchem-405	154	26	under	under	ADP
eurjchem-405	154	27	normal	normal	ADJ
eurjchem-405	154	28	solvolytic	solvolytic	ADJ
eurjchem-405	154	29	conditions	condition	NOUN
eurjchem-405	154	30	[	[	X
eurjchem-405	154	31	79	79	NUM
eurjchem-405	154	32	]	]	PUNCT
eurjchem-405	154	33	.	.	PUNCT
eurjchem-405	155	1	hence	hence	ADV
eurjchem-405	155	2	,	,	PUNCT
eurjchem-405	155	3	the	the	DET
eurjchem-405	155	4	favored	favor	VERB
eurjchem-405	155	5	ionization‐fragmentation	ionization‐fragmentation	NOUN
eurjchem-405	155	6	pathway	pathway	NOUN
eurjchem-405	155	7	frequently	frequently	ADV
eurjchem-405	155	8	followed	follow	VERB
eurjchem-405	155	9	for	for	ADP
eurjchem-405	155	10	2	2	NUM
eurjchem-405	155	11	is	be	AUX
eurjchem-405	155	12	not	not	PART
eurjchem-405	155	13	operative	operative	ADJ
eurjchem-405	155	14	in	in	ADP
eurjchem-405	155	15	the	the	DET
eurjchem-405	155	16	solvolyses	solvolyse	NOUN
eurjchem-405	155	17	of	of	ADP
eurjchem-405	155	18	either	either	CCONJ
eurjchem-405	155	19	1	1	NUM
eurjchem-405	155	20	or	or	CCONJ
eurjchem-405	155	21	3	3	NUM
eurjchem-405	155	22	.	.	NOUN
eurjchem-405	155	23	134	134	NUM
eurjchem-405	155	24	d’souza	d’souza	NOUN
eurjchem-405	155	25	et	et	PROPN
eurjchem-405	155	26	al	al	PROPN
eurjchem-405	155	27	.	.	PUNCT
eurjchem-405	155	28	/	/	SYM
eurjchem-405	155	29	european	european	PROPN
eurjchem-405	155	30	journal	journal	PROPN
eurjchem-405	155	31	of	of	ADP
eurjchem-405	155	32	chemistry	chemistry	NOUN
eurjchem-405	155	33	2	2	NUM
eurjchem-405	155	34	(	(	PUNCT
eurjchem-405	155	35	2	2	NUM
eurjchem-405	155	36	)	)	PUNCT
eurjchem-405	155	37	(	(	PUNCT
eurjchem-405	155	38	2011	2011	NUM
eurjchem-405	155	39	)	)	PUNCT
eurjchem-405	155	40	130‐135	130‐135	NOUN
eurjchem-405	155	41	table	table	NOUN
eurjchem-405	156	1	3	3	NUM
eurjchem-405	156	2	.	.	PUNCT
eurjchem-405	156	3	specific	specific	ADJ
eurjchem-405	156	4	rates	rate	NOUN
eurjchem-405	156	5	of	of	ADP
eurjchem-405	156	6	solvolysis	solvolysis	NOUN
eurjchem-405	156	7	(	(	PUNCT
eurjchem-405	156	8	k	k	NOUN
eurjchem-405	156	9	)	)	PUNCT
eurjchem-405	156	10	of	of	ADP
eurjchem-405	156	11	1	1	NUM
eurjchem-405	156	12	,	,	PUNCT
eurjchem-405	156	13	2	2	NUM
eurjchem-405	156	14	,	,	PUNCT
eurjchem-405	156	15	and	and	CCONJ
eurjchem-405	156	16	3	3	NUM
eurjchem-405	156	17	,	,	PUNCT
eurjchem-405	156	18	in	in	ADP
eurjchem-405	156	19	meoh	meoh	NOUN
eurjchem-405	156	20	,	,	PUNCT
eurjchem-405	156	21	etoh	etoh	PROPN
eurjchem-405	156	22	,	,	PUNCT
eurjchem-405	156	23	70%hfip	70%hfip	PROPN
eurjchem-405	156	24	(	(	PUNCT
eurjchem-405	156	25	w	w	PROPN
eurjchem-405	156	26	/	/	SYM
eurjchem-405	156	27	w	w	NOUN
eurjchem-405	156	28	)	)	PUNCT
eurjchem-405	156	29	,	,	PUNCT
eurjchem-405	156	30	and	and	CCONJ
eurjchem-405	156	31	50	50	NUM
eurjchem-405	156	32	%	%	NOUN
eurjchem-405	156	33	hfip	hfip	NOUN
eurjchem-405	156	34	(	(	PUNCT
eurjchem-405	156	35	w	w	PROPN
eurjchem-405	156	36	/	/	SYM
eurjchem-405	156	37	w	w	NOUN
eurjchem-405	156	38	)	)	PUNCT
eurjchem-405	156	39	at	at	ADP
eurjchem-405	156	40	25.0	25.0	NUM
eurjchem-405	156	41	oc	oc	NOUN
eurjchem-405	156	42	.	.	PUNCT
eurjchem-405	157	1	solvent	solvent	NOUN
eurjchem-405	157	2	(	(	PUNCT
eurjchem-405	157	3	%	%	INTJ
eurjchem-405	157	4	)	)	PUNCT
eurjchem-405	157	5	a	a	DET
eurjchem-405	157	6	1	1	NUM
eurjchem-405	157	7	,	,	PUNCT
eurjchem-405	157	8	105	105	NUM
eurjchem-405	157	9	k	k	NOUN
eurjchem-405	157	10	,	,	PUNCT
eurjchem-405	157	11	s‐1b	s‐1b	PROPN
eurjchem-405	157	12	2	2	NUM
eurjchem-405	157	13	,	,	PUNCT
eurjchem-405	157	14	105	105	NUM
eurjchem-405	157	15	k	k	NOUN
eurjchem-405	157	16	,	,	PUNCT
eurjchem-405	157	17	s‐1c	s‐1c	VERB
eurjchem-405	157	18	3	3	NUM
eurjchem-405	157	19	,	,	PUNCT
eurjchem-405	157	20	105	105	NUM
eurjchem-405	157	21	k	k	NOUN
eurjchem-405	157	22	,	,	PUNCT
eurjchem-405	157	23	s‐1d	s‐1d	PROPN
eurjchem-405	157	24	100	100	NUM
eurjchem-405	157	25	%	%	NOUN
eurjchem-405	157	26	meoh	meoh	NOUN
eurjchem-405	157	27	210	210	NUM
eurjchem-405	157	28	±	±	NUM
eurjchem-405	157	29	8	8	NUM
eurjchem-405	157	30	4.19	4.19	NUM
eurjchem-405	157	31	±	±	NUM
eurjchem-405	157	32	0.10	0.10	NUM
eurjchem-405	157	33	695	695	NUM
eurjchem-405	157	34	±	±	NUM
eurjchem-405	157	35	9	9	NUM
eurjchem-405	157	36	100	100	NUM
eurjchem-405	157	37	%	%	NOUN
eurjchem-405	157	38	etoh	etoh	NOUN
eurjchem-405	157	39	110	110	NUM
eurjchem-405	157	40	±	±	NUM
eurjchem-405	157	41	6	6	NUM
eurjchem-405	157	42	1.09	1.09	NUM
eurjchem-405	157	43	±	±	NUM
eurjchem-405	157	44	0.04	0.04	NUM
eurjchem-405	157	45	260	260	NUM
eurjchem-405	157	46	±	±	NOUN
eurjchem-405	157	47	3	3	NUM
eurjchem-405	157	48	70%hfip	70%hfip	PROPN
eurjchem-405	157	49	(	(	PUNCT
eurjchem-405	157	50	w	w	PROPN
eurjchem-405	157	51	/	/	SYM
eurjchem-405	157	52	w	w	NOUN
eurjchem-405	157	53	)	)	PUNCT
eurjchem-405	157	54	2.54	2.54	NUM
eurjchem-405	157	55	±0.09	±0.09	PROPN
eurjchem-405	157	56	60.1	60.1	NUM
eurjchem-405	157	57	±	±	NUM
eurjchem-405	157	58	2.4	2.4	NUM
eurjchem-405	157	59	10.5	10.5	NUM
eurjchem-405	157	60	±	±	NUM
eurjchem-405	157	61	0.6	0.6	NUM
eurjchem-405	157	62	50	50	NUM
eurjchem-405	157	63	%	%	NOUN
eurjchem-405	157	64	hfip	hfip	NOUN
eurjchem-405	157	65	(	(	PUNCT
eurjchem-405	157	66	w	w	PROPN
eurjchem-405	157	67	/	/	SYM
eurjchem-405	157	68	w	w	NOUN
eurjchem-405	157	69	)	)	PUNCT
eurjchem-405	157	70	35.2	35.2	NUM
eurjchem-405	157	71	±	±	NUM
eurjchem-405	157	72	3.1	3.1	NUM
eurjchem-405	157	73	71	71	NUM
eurjchem-405	157	74	±	±	NUM
eurjchem-405	157	75	3.0	3.0	NUM
eurjchem-405	157	76	31.6	31.6	NUM
eurjchem-405	157	77	±	±	NUM
eurjchem-405	157	78	0.6	0.6	NUM
eurjchem-405	157	79	a	a	PRON
eurjchem-405	157	80	,	,	PUNCT
eurjchem-405	157	81	b	b	NOUN
eurjchem-405	157	82	see	see	VERB
eurjchem-405	157	83	footnotes	footnote	NOUN
eurjchem-405	157	84	in	in	ADP
eurjchem-405	157	85	table	table	NOUN
eurjchem-405	157	86	1	1	NUM
eurjchem-405	157	87	.	.	PUNCT
eurjchem-405	157	88	c	c	PROPN
eurjchem-405	157	89	ref	ref	NOUN
eurjchem-405	157	90	.	.	PUNCT
eurjchem-405	158	1	[	[	X
eurjchem-405	158	2	27	27	NUM
eurjchem-405	158	3	]	]	PUNCT
eurjchem-405	158	4	.	.	PUNCT
eurjchem-405	159	1	d	d	PRON
eurjchem-405	159	2	ref	ref	NOUN
eurjchem-405	159	3	.	.	PUNCT
eurjchem-405	160	1	[	[	X
eurjchem-405	160	2	9	9	NUM
eurjchem-405	160	3	]	]	PUNCT
eurjchem-405	160	4	.	.	PUNCT
eurjchem-405	161	1	a	a	DET
eurjchem-405	161	2	comparison	comparison	NOUN
eurjchem-405	161	3	of	of	ADP
eurjchem-405	161	4	k3	k3	NOUN
eurjchem-405	161	5	and	and	CCONJ
eurjchem-405	161	6	k1	k1	NOUN
eurjchem-405	161	7	in	in	ADP
eurjchem-405	161	8	the	the	DET
eurjchem-405	161	9	two	two	NUM
eurjchem-405	161	10	hfip	hfip	NOUN
eurjchem-405	161	11	mixtures	mixture	NOUN
eurjchem-405	161	12	shows	show	VERB
eurjchem-405	161	13	a	a	DET
eurjchem-405	161	14	much	much	ADV
eurjchem-405	161	15	closer	close	ADJ
eurjchem-405	161	16	range	range	NOUN
eurjchem-405	161	17	in	in	ADP
eurjchem-405	161	18	their	their	PRON
eurjchem-405	161	19	specific	specific	ADJ
eurjchem-405	161	20	rates	rate	NOUN
eurjchem-405	161	21	as	as	SCONJ
eurjchem-405	161	22	the	the	DET
eurjchem-405	161	23	inductive	inductive	ADJ
eurjchem-405	161	24	ability	ability	NOUN
eurjchem-405	161	25	of	of	ADP
eurjchem-405	161	26	the	the	DET
eurjchem-405	161	27	isopropenoxy	isopropenoxy	ADJ
eurjchem-405	161	28	group	group	NOUN
eurjchem-405	161	29	is	be	AUX
eurjchem-405	161	30	now	now	ADV
eurjchem-405	161	31	opposed	oppose	VERB
eurjchem-405	161	32	by	by	ADP
eurjchem-405	161	33	the	the	DET
eurjchem-405	161	34	conjugative	conjugative	ADJ
eurjchem-405	161	35	mesomeric	mesomeric	NOUN
eurjchem-405	161	36	electron	electron	NOUN
eurjchem-405	161	37	release	release	NOUN
eurjchem-405	161	38	of	of	ADP
eurjchem-405	161	39	the	the	DET
eurjchem-405	161	40	contributing	contribute	VERB
eurjchem-405	161	41	resonance	resonance	NOUN
eurjchem-405	161	42	hybrids	hybrid	NOUN
eurjchem-405	161	43	shown	show	VERB
eurjchem-405	161	44	in	in	ADP
eurjchem-405	161	45	scheme	scheme	NOUN
eurjchem-405	161	46	3	3	NUM
eurjchem-405	161	47	,	,	PUNCT
eurjchem-405	161	48	and	and	CCONJ
eurjchem-405	161	49	as	as	SCONJ
eurjchem-405	161	50	has	have	AUX
eurjchem-405	161	51	been	be	AUX
eurjchem-405	161	52	indicated	indicate	VERB
eurjchem-405	161	53	above	above	ADV
eurjchem-405	161	54	,	,	PUNCT
eurjchem-405	161	55	there	there	PRON
eurjchem-405	161	56	are	be	VERB
eurjchem-405	161	57	superimposed	superimpose	VERB
eurjchem-405	161	58	mechanisms	mechanism	NOUN
eurjchem-405	161	59	occurring	occur	VERB
eurjchem-405	161	60	in	in	ADP
eurjchem-405	161	61	70	70	NUM
eurjchem-405	161	62	%	%	NOUN
eurjchem-405	161	63	and	and	CCONJ
eurjchem-405	161	64	50	50	NUM
eurjchem-405	161	65	%	%	NOUN
eurjchem-405	161	66	hfip	hfip	NOUN
eurjchem-405	161	67	.	.	PUNCT
eurjchem-405	162	1	4	4	NUM
eurjchem-405	162	2	.	.	X
eurjchem-405	162	3	conclusions	conclusion	NOUN
eurjchem-405	162	4	the	the	DET
eurjchem-405	162	5	relatively	relatively	ADV
eurjchem-405	162	6	fast	fast	ADJ
eurjchem-405	162	7	reaction	reaction	NOUN
eurjchem-405	162	8	of	of	ADP
eurjchem-405	162	9	isopropenyl	isopropenyl	ADJ
eurjchem-405	162	10	chloroformate	chloroformate	NOUN
eurjchem-405	162	11	(	(	PUNCT
eurjchem-405	162	12	1	1	NUM
eurjchem-405	162	13	)	)	PUNCT
eurjchem-405	162	14	versus	versus	ADP
eurjchem-405	162	15	its	its	PRON
eurjchem-405	162	16	alkyl	alkyl	ADJ
eurjchem-405	162	17	analog	analog	NOUN
eurjchem-405	162	18	2	2	NUM
eurjchem-405	162	19	in	in	ADP
eurjchem-405	162	20	all	all	DET
eurjchem-405	162	21	solvents	solvent	NOUN
eurjchem-405	162	22	except	except	SCONJ
eurjchem-405	162	23	the	the	DET
eurjchem-405	162	24	aqueous	aqueous	ADJ
eurjchem-405	162	25	fluoroalchols	fluoroalchol	NOUN
eurjchem-405	162	26	,	,	PUNCT
eurjchem-405	162	27	shows	show	VERB
eurjchem-405	162	28	that	that	SCONJ
eurjchem-405	162	29	the	the	DET
eurjchem-405	162	30	alkenoxy	alkenoxy	ADJ
eurjchem-405	162	31	substituent	substituent	NOUN
eurjchem-405	162	32	exerts	exert	VERB
eurjchem-405	162	33	a	a	DET
eurjchem-405	162	34	powerful	powerful	ADJ
eurjchem-405	162	35	inductive	inductive	ADJ
eurjchem-405	162	36	influence	influence	NOUN
eurjchem-405	162	37	on	on	ADP
eurjchem-405	162	38	the	the	DET
eurjchem-405	162	39	electron	electron	NOUN
eurjchem-405	162	40	density	density	NOUN
eurjchem-405	162	41	at	at	ADP
eurjchem-405	162	42	the	the	DET
eurjchem-405	162	43	carbonyl	carbonyl	NOUN
eurjchem-405	162	44	atom	atom	NOUN
eurjchem-405	162	45	.	.	PUNCT
eurjchem-405	163	1	unlike	unlike	ADP
eurjchem-405	163	2	the	the	DET
eurjchem-405	163	3	solvolyses	solvolyse	NOUN
eurjchem-405	163	4	[	[	X
eurjchem-405	163	5	9,23	9,23	NOUN
eurjchem-405	163	6	]	]	PUNCT
eurjchem-405	163	7	of	of	ADP
eurjchem-405	163	8	phenyl	phenyl	NOUN
eurjchem-405	163	9	chloroformate	chloroformate	NOUN
eurjchem-405	163	10	(	(	PUNCT
eurjchem-405	163	11	3	3	NUM
eurjchem-405	163	12	)	)	PUNCT
eurjchem-405	163	13	,	,	PUNCT
eurjchem-405	163	14	where	where	SCONJ
eurjchem-405	163	15	the	the	DET
eurjchem-405	163	16	addition‐elimination	addition‐elimination	NOUN
eurjchem-405	163	17	mechanism	mechanism	NOUN
eurjchem-405	163	18	dominates	dominate	VERB
eurjchem-405	163	19	over	over	ADP
eurjchem-405	163	20	the	the	DET
eurjchem-405	163	21	full	full	ADJ
eurjchem-405	163	22	range	range	NOUN
eurjchem-405	163	23	of	of	ADP
eurjchem-405	163	24	solvent	solvent	ADJ
eurjchem-405	163	25	composition	composition	NOUN
eurjchem-405	163	26	including	include	VERB
eurjchem-405	163	27	97	97	NUM
eurjchem-405	163	28	%	%	NOUN
eurjchem-405	163	29	hfip	hfip	NOUN
eurjchem-405	163	30	,	,	PUNCT
eurjchem-405	163	31	isopropenyl	isopropenyl	NOUN
eurjchem-405	163	32	(	(	PUNCT
eurjchem-405	163	33	1	1	NUM
eurjchem-405	163	34	)	)	PUNCT
eurjchem-405	163	35	and	and	CCONJ
eurjchem-405	163	36	isopropyl	isopropyl	NOUN
eurjchem-405	163	37	(	(	PUNCT
eurjchem-405	163	38	2	2	NUM
eurjchem-405	163	39	)	)	PUNCT
eurjchem-405	163	40	[	[	X
eurjchem-405	163	41	27	27	NUM
eurjchem-405	163	42	]	]	X
eurjchem-405	163	43	chloroformates	chloroformate	NOUN
eurjchem-405	163	44	show	show	VERB
eurjchem-405	163	45	varying	vary	VERB
eurjchem-405	163	46	behavior	behavior	NOUN
eurjchem-405	163	47	as	as	SCONJ
eurjchem-405	163	48	the	the	DET
eurjchem-405	163	49	solvent	solvent	NOUN
eurjchem-405	163	50	is	be	AUX
eurjchem-405	163	51	varied	varied	ADJ
eurjchem-405	163	52	.	.	PUNCT
eurjchem-405	164	1	isopropenyl	isopropenyl	ADJ
eurjchem-405	164	2	chloroformate	chloroformate	NOUN
eurjchem-405	164	3	(	(	PUNCT
eurjchem-405	164	4	1	1	NUM
eurjchem-405	164	5	)	)	PUNCT
eurjchem-405	164	6	proceeds	proceed	NOUN
eurjchem-405	164	7	via	via	ADP
eurjchem-405	164	8	a	a	DET
eurjchem-405	164	9	dominant	dominant	ADJ
eurjchem-405	164	10	addition‐elimination	addition‐elimination	NOUN
eurjchem-405	164	11	mechanism	mechanism	NOUN
eurjchem-405	164	12	(	(	PUNCT
eurjchem-405	164	13	scheme	scheme	NOUN
eurjchem-405	164	14	4	4	NUM
eurjchem-405	164	15	)	)	PUNCT
eurjchem-405	164	16	in	in	ADP
eurjchem-405	164	17	all	all	DET
eurjchem-405	164	18	solvents	solvent	NOUN
eurjchem-405	164	19	except	except	SCONJ
eurjchem-405	164	20	in	in	ADP
eurjchem-405	164	21	the	the	DET
eurjchem-405	164	22	four	four	NUM
eurjchem-405	164	23	highly	highly	ADV
eurjchem-405	164	24	ionizing	ionizing	ADJ
eurjchem-405	164	25	hfip	hfip	NOUN
eurjchem-405	164	26	mixtures	mixture	NOUN
eurjchem-405	164	27	and	and	CCONJ
eurjchem-405	164	28	97	97	NUM
eurjchem-405	164	29	tfe	tfe	NOUN
eurjchem-405	164	30	,	,	PUNCT
eurjchem-405	164	31	where	where	SCONJ
eurjchem-405	164	32	a	a	DET
eurjchem-405	164	33	superimposed	superimpose	VERB
eurjchem-405	164	34	sn1	sn1	PROPN
eurjchem-405	164	35	contribution	contribution	NOUN
eurjchem-405	164	36	of	of	ADP
eurjchem-405	164	37	5‐97	5‐97	NUM
eurjchem-405	164	38	%	%	NOUN
eurjchem-405	164	39	is	be	AUX
eurjchem-405	164	40	estimated	estimate	VERB
eurjchem-405	164	41	.	.	PUNCT
eurjchem-405	165	1	on	on	ADP
eurjchem-405	165	2	the	the	DET
eurjchem-405	165	3	other	other	ADJ
eurjchem-405	165	4	hand	hand	NOUN
eurjchem-405	165	5	,	,	PUNCT
eurjchem-405	165	6	in	in	ADP
eurjchem-405	165	7	solvents	solvent	NOUN
eurjchem-405	165	8	of	of	ADP
eurjchem-405	165	9	low	low	ADJ
eurjchem-405	165	10	nucleophilicity	nucleophilicity	NOUN
eurjchem-405	165	11	and	and	CCONJ
eurjchem-405	165	12	high	high	ADJ
eurjchem-405	165	13	ionizing	ionizing	NOUN
eurjchem-405	165	14	power	power	NOUN
eurjchem-405	165	15	,	,	PUNCT
eurjchem-405	165	16	it	it	PRON
eurjchem-405	165	17	was	be	AUX
eurjchem-405	165	18	suggested	suggest	VERB
eurjchem-405	165	19	[	[	X
eurjchem-405	165	20	27	27	NUM
eurjchem-405	165	21	]	]	PUNCT
eurjchem-405	165	22	that	that	PRON
eurjchem-405	165	23	isopropyl	isopropyl	NOUN
eurjchem-405	165	24	chloroformate	chloroformate	NOUN
eurjchem-405	165	25	(	(	PUNCT
eurjchem-405	165	26	2	2	NUM
eurjchem-405	165	27	)	)	PUNCT
eurjchem-405	165	28	undergoes	undergo	VERB
eurjchem-405	165	29	a	a	DET
eurjchem-405	165	30	fragmentation‐ionization	fragmentation‐ionization	NOUN
eurjchem-405	165	31	mechanism	mechanism	NOUN
eurjchem-405	165	32	,	,	PUNCT
eurjchem-405	165	33	involving	involve	VERB
eurjchem-405	165	34	loss	loss	NOUN
eurjchem-405	165	35	of	of	ADP
eurjchem-405	165	36	carbon	carbon	NOUN
eurjchem-405	165	37	dioxide	dioxide	NOUN
eurjchem-405	165	38	.	.	PUNCT
eurjchem-405	166	1	this	this	DET
eurjchem-405	166	2	study	study	NOUN
eurjchem-405	166	3	has	have	AUX
eurjchem-405	166	4	further	far	ADV
eurjchem-405	166	5	demonstrated	demonstrate	VERB
eurjchem-405	166	6	that	that	SCONJ
eurjchem-405	166	7	the	the	DET
eurjchem-405	166	8	use	use	NOUN
eurjchem-405	166	9	of	of	ADP
eurjchem-405	166	10	similarity	similarity	NOUN
eurjchem-405	166	11	models	model	NOUN
eurjchem-405	166	12	for	for	ADP
eurjchem-405	166	13	the	the	DET
eurjchem-405	166	14	elucidation	elucidation	NOUN
eurjchem-405	166	15	of	of	ADP
eurjchem-405	166	16	plausible	plausible	ADJ
eurjchem-405	166	17	solvolytic	solvolytic	ADJ
eurjchem-405	166	18	mechanisms	mechanism	NOUN
eurjchem-405	166	19	can	can	AUX
eurjchem-405	166	20	be	be	AUX
eurjchem-405	166	21	useful	useful	ADJ
eurjchem-405	166	22	for	for	ADP
eurjchem-405	166	23	indicating	indicate	VERB
eurjchem-405	166	24	the	the	DET
eurjchem-405	166	25	presence	presence	NOUN
eurjchem-405	166	26	of	of	ADP
eurjchem-405	166	27	superimposed	superimpose	VERB
eurjchem-405	166	28	reaction	reaction	NOUN
eurjchem-405	166	29	channels	channel	NOUN
eurjchem-405	166	30	.	.	PUNCT
eurjchem-405	167	1	acknowledgements	acknowledgement	NOUN
eurjchem-405	167	2	this	this	DET
eurjchem-405	167	3	research	research	NOUN
eurjchem-405	167	4	was	be	AUX
eurjchem-405	167	5	supported	support	VERB
eurjchem-405	167	6	by	by	ADP
eurjchem-405	167	7	grant	grant	NOUN
eurjchem-405	167	8	number	number	NOUN
eurjchem-405	167	9	2	2	NUM
eurjchem-405	167	10	p2o	p2o	NOUN
eurjchem-405	167	11	rr016472‐010	rr016472‐010	NOUN
eurjchem-405	167	12	from	from	ADP
eurjchem-405	167	13	the	the	DET
eurjchem-405	167	14	national	national	ADJ
eurjchem-405	167	15	center	center	NOUN
eurjchem-405	167	16	for	for	ADP
eurjchem-405	167	17	research	research	NOUN
eurjchem-405	167	18	resources	resource	NOUN
eurjchem-405	167	19	(	(	PUNCT
eurjchem-405	167	20	ncrr	ncrr	ADV
eurjchem-405	167	21	)	)	PUNCT
eurjchem-405	167	22	,	,	PUNCT
eurjchem-405	167	23	a	a	DET
eurjchem-405	167	24	component	component	NOUN
eurjchem-405	167	25	of	of	ADP
eurjchem-405	167	26	the	the	DET
eurjchem-405	167	27	national	national	PROPN
eurjchem-405	167	28	institutes	institutes	PROPN
eurjchem-405	167	29	of	of	ADP
eurjchem-405	167	30	health	health	PROPN
eurjchem-405	167	31	(	(	PUNCT
eurjchem-405	167	32	nih	nih	PROPN
eurjchem-405	167	33	)	)	PUNCT
eurjchem-405	167	34	.	.	PUNCT
eurjchem-405	168	1	this	this	DET
eurjchem-405	168	2	idea	idea	NOUN
eurjchem-405	168	3	network	network	NOUN
eurjchem-405	168	4	of	of	ADP
eurjchem-405	168	5	biomedical	biomedical	ADJ
eurjchem-405	168	6	research	research	NOUN
eurjchem-405	168	7	excellence	excellence	PROPN
eurjchem-405	168	8	(	(	PUNCT
eurjchem-405	168	9	inbre	inbre	PROPN
eurjchem-405	168	10	)	)	PUNCT
eurjchem-405	168	11	grant	grant	NOUN
eurjchem-405	168	12	to	to	ADP
eurjchem-405	168	13	the	the	DET
eurjchem-405	168	14	state	state	NOUN
eurjchem-405	168	15	of	of	ADP
eurjchem-405	168	16	delaware	delaware	PROPN
eurjchem-405	168	17	(	(	PUNCT
eurjchem-405	168	18	de	de	PROPN
eurjchem-405	168	19	)	)	PUNCT
eurjchem-405	168	20	was	be	AUX
eurjchem-405	168	21	obtained	obtain	VERB
eurjchem-405	168	22	under	under	ADP
eurjchem-405	168	23	the	the	DET
eurjchem-405	168	24	leadership	leadership	NOUN
eurjchem-405	168	25	of	of	ADP
eurjchem-405	168	26	the	the	DET
eurjchem-405	168	27	university	university	PROPN
eurjchem-405	168	28	of	of	ADP
eurjchem-405	168	29	delaware	delaware	PROPN
eurjchem-405	168	30	,	,	PUNCT
eurjchem-405	168	31	and	and	CCONJ
eurjchem-405	168	32	the	the	DET
eurjchem-405	168	33	authors	author	NOUN
eurjchem-405	168	34	sincerely	sincerely	ADV
eurjchem-405	168	35	appreciate	appreciate	VERB
eurjchem-405	168	36	their	their	PRON
eurjchem-405	168	37	efforts	effort	NOUN
eurjchem-405	168	38	.	.	PUNCT
eurjchem-405	169	1	notes	notes	PROPN
eurjchem-405	169	2	kevin	kevin	PROPN
eurjchem-405	169	3	e.	e.	PROPN
eurjchem-405	169	4	shuman	shuman	PROPN
eurjchem-405	169	5	and	and	CCONJ
eurjchem-405	169	6	arnold	arnold	PROPN
eurjchem-405	169	7	o.	o.	PROPN
eurjchem-405	169	8	omondi	omondi	PROPN
eurjchem-405	169	9	,	,	PUNCT
eurjchem-405	169	10	completed	complete	VERB
eurjchem-405	169	11	this	this	DET
eurjchem-405	169	12	research	research	NOUN
eurjchem-405	169	13	under	under	ADP
eurjchem-405	169	14	the	the	DET
eurjchem-405	169	15	direction	direction	NOUN
eurjchem-405	169	16	of	of	ADP
eurjchem-405	169	17	dr	dr	PROPN
eurjchem-405	169	18	.	.	PROPN
eurjchem-405	169	19	malcolm	malcolm	PROPN
eurjchem-405	169	20	j.	j.	PROPN
eurjchem-405	169	21	d’souza	d’souza	PROPN
eurjchem-405	169	22	as	as	ADP
eurjchem-405	169	23	undergraduate	undergraduate	NOUN
eurjchem-405	169	24	research	research	NOUN
eurjchem-405	169	25	assistants	assistant	NOUN
eurjchem-405	169	26	in	in	ADP
eurjchem-405	169	27	the	the	DET
eurjchem-405	169	28	de‐inbre	de‐inbre	NOUN
eurjchem-405	169	29	sponsored	sponsor	VERB
eurjchem-405	169	30	wesley	wesley	PROPN
eurjchem-405	169	31	college	college	PROPN
eurjchem-405	169	32	directed	direct	VERB
eurjchem-405	169	33	research	research	NOUN
eurjchem-405	169	34	program	program	NOUN
eurjchem-405	169	35	.	.	PUNCT
eurjchem-405	170	1	this	this	DET
eurjchem-405	170	2	research	research	NOUN
eurjchem-405	170	3	project	project	NOUN
eurjchem-405	170	4	was	be	AUX
eurjchem-405	170	5	one	one	NUM
eurjchem-405	170	6	of	of	ADP
eurjchem-405	170	7	just	just	ADV
eurjchem-405	170	8	sixty	sixty	NUM
eurjchem-405	170	9	that	that	PRON
eurjchem-405	170	10	was	be	AUX
eurjchem-405	170	11	competitively	competitively	ADV
eurjchem-405	170	12	selected	select	VERB
eurjchem-405	170	13	from	from	ADP
eurjchem-405	170	14	across	across	ADP
eurjchem-405	170	15	the	the	DET
eurjchem-405	170	16	usa	usa	PROPN
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eurjchem-405	170	19	showcased	showcase	VERB
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eurjchem-405	170	22	poster	poster	NOUN
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eurjchem-405	170	25	2008	2008	NUM
eurjchem-405	170	26	council	council	NOUN
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eurjchem-405	170	37	event	event	NOUN
eurjchem-405	170	38	(	(	PUNCT
eurjchem-405	170	39	april	april	PROPN
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eurjchem-405	170	41	)	)	PUNCT
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eurjchem-405	171	2	[	[	X
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eurjchem-405	171	4	]	]	PUNCT
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eurjchem-405	172	4	;	;	PUNCT
eurjchem-405	172	5	grunwald	grunwald	PROPN
eurjchem-405	172	6	,	,	PUNCT
eurjchem-405	172	7	e.	e.	PROPN
eurjchem-405	172	8	;	;	PUNCT
eurjchem-405	172	9	jones	jones	PROPN
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eurjchem-405	172	12	w.	w.	PROPN
eurjchem-405	172	13	j.	j.	PROPN
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eurjchem-405	173	1	chem	chem	PROPN
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eurjchem-405	174	1	soc	soc	PROPN
eurjchem-405	174	2	.	.	PUNCT
eurjchem-405	175	1	1951	1951	NUM
eurjchem-405	175	2	,	,	PUNCT
eurjchem-405	175	3	73	73	NUM
eurjchem-405	175	4	,	,	PUNCT
eurjchem-405	175	5	2700‐2707	2700‐2707	NOUN
eurjchem-405	175	6	.	.	PUNCT
eurjchem-405	176	1	[	[	X
eurjchem-405	176	2	2	2	NUM
eurjchem-405	176	3	]	]	PUNCT
eurjchem-405	176	4	.	.	PUNCT
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eurjchem-405	176	6	,	,	PUNCT
eurjchem-405	176	7	d.	d.	PROPN
eurjchem-405	176	8	n.	n.	PROPN
eurjchem-405	176	9	;	;	PUNCT
eurjchem-405	176	10	d’souza	d’souza	PROPN
eurjchem-405	176	11	,	,	PUNCT
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eurjchem-405	176	13	j.	j.	PROPN
eurjchem-405	176	14	j.	j.	PROPN
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eurjchem-405	178	2	3	3	NUM
eurjchem-405	178	3	]	]	PUNCT
eurjchem-405	178	4	.	.	PUNCT
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eurjchem-405	179	2	,	,	PUNCT
eurjchem-405	179	3	t.	t.	PROPN
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eurjchem-405	179	5	;	;	PUNCT
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eurjchem-405	179	9	s.	s.	PROPN
eurjchem-405	179	10	j.	j.	PROPN
eurjchem-405	179	11	phys	phys	PROPN
eurjchem-405	179	12	.	.	PUNCT
eurjchem-405	180	1	org	org	PROPN
eurjchem-405	180	2	.	.	PUNCT
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eurjchem-405	181	2	,	,	PUNCT
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eurjchem-405	181	4	,	,	PUNCT
eurjchem-405	181	5	341‐349	341‐349	NOUN
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eurjchem-405	182	1	[	[	X
eurjchem-405	182	2	4	4	NUM
eurjchem-405	182	3	]	]	PUNCT
eurjchem-405	182	4	.	.	PUNCT
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eurjchem-405	183	3	s.	s.	PROPN
eurjchem-405	183	4	;	;	PUNCT
eurjchem-405	183	5	koh	koh	PROPN
eurjchem-405	183	6	,	,	PUNCT
eurjchem-405	183	7	k.	k.	PROPN
eurjchem-405	183	8	s.	s.	PROPN
eurjchem-405	183	9	;	;	PUNCT
eurjchem-405	183	10	lee	lee	PROPN
eurjchem-405	183	11	,	,	PUNCT
eurjchem-405	183	12	i.	i.	PROPN
eurjchem-405	183	13	j.	j.	PROPN
eurjchem-405	183	14	korean	korean	PROPN
eurjchem-405	183	15	chem	chem	PROPN
eurjchem-405	183	16	.	.	PUNCT
eurjchem-405	184	1	soc	soc	PROPN
eurjchem-405	184	2	.	.	PUNCT
eurjchem-405	185	1	1980	1980	NUM
eurjchem-405	185	2	,	,	PUNCT
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eurjchem-405	185	4	,	,	PUNCT
eurjchem-405	185	5	1‐7	1‐7	NUM
eurjchem-405	185	6	.	.	PUNCT
eurjchem-405	186	1	[	[	X
eurjchem-405	186	2	5	5	NUM
eurjchem-405	186	3	]	]	PUNCT
eurjchem-405	186	4	.	.	PUNCT
eurjchem-405	186	5	la	la	PROPN
eurjchem-405	186	6	,	,	PUNCT
eurjchem-405	186	7	s.	s.	PROPN
eurjchem-405	186	8	;	;	PUNCT
eurjchem-405	186	9	koh	koh	PROPN
eurjchem-405	186	10	,	,	PUNCT
eurjchem-405	186	11	k.	k.	PROPN
eurjchem-405	186	12	s.	s.	PROPN
eurjchem-405	186	13	;	;	PUNCT
eurjchem-405	186	14	lee	lee	PROPN
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eurjchem-405	186	16	i.	i.	PROPN
eurjchem-405	186	17	j.	j.	PROPN
eurjchem-405	186	18	korean	korean	PROPN
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eurjchem-405	186	20	.	.	PUNCT
eurjchem-405	187	1	soc	soc	PROPN
eurjchem-405	187	2	.	.	PUNCT
eurjchem-405	188	1	1980	1980	NUM
eurjchem-405	188	2	,	,	PUNCT
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eurjchem-405	188	4	,	,	PUNCT
eurjchem-405	188	5	8‐14	8‐14	NUM
eurjchem-405	188	6	.	.	PUNCT
eurjchem-405	189	1	[	[	X
eurjchem-405	189	2	6	6	NUM
eurjchem-405	189	3	]	]	PUNCT
eurjchem-405	189	4	.	.	PUNCT
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eurjchem-405	190	2	,	,	PUNCT
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eurjchem-405	190	4	n.	n.	PROPN
eurjchem-405	190	5	;	;	PUNCT
eurjchem-405	190	6	kyong	kyong	PROPN
eurjchem-405	190	7	,	,	PUNCT
eurjchem-405	190	8	j.	j.	PROPN
eurjchem-405	190	9	b.	b.	PROPN
eurjchem-405	190	10	;	;	PUNCT
eurjchem-405	190	11	weitl	weitl	PROPN
eurjchem-405	190	12	,	,	PUNCT
eurjchem-405	190	13	f.	f.	PROPN
eurjchem-405	190	14	l.	l.	PROPN
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eurjchem-405	190	17	.	.	PUNCT
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eurjchem-405	190	19	.	.	PUNCT
eurjchem-405	191	1	1990	1990	NUM
eurjchem-405	191	2	,	,	PUNCT
eurjchem-405	191	3	55	55	NUM
eurjchem-405	191	4	,	,	PUNCT
eurjchem-405	191	5	4304‐4311	4304‐4311	NUM
eurjchem-405	191	6	.	.	PUNCT
eurjchem-405	192	1	[	[	X
eurjchem-405	192	2	7	7	NUM
eurjchem-405	192	3	]	]	PUNCT
eurjchem-405	192	4	.	.	PUNCT
eurjchem-405	193	1	kyong	kyong	PROPN
eurjchem-405	193	2	,	,	PUNCT
eurjchem-405	193	3	j.	j.	PROPN
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eurjchem-405	193	5	;	;	PUNCT
eurjchem-405	193	6	suk	suk	PROPN
eurjchem-405	193	7	,	,	PUNCT
eurjchem-405	193	8	y.	y.	PROPN
eurjchem-405	193	9	j.	j.	PROPN
eurjchem-405	193	10	;	;	PUNCT
eurjchem-405	193	11	kevill	kevill	PROPN
eurjchem-405	193	12	,	,	PUNCT
eurjchem-405	193	13	d.	d.	PROPN
eurjchem-405	193	14	n.	n.	PROPN
eurjchem-405	193	15	j.	j.	PROPN
eurjchem-405	193	16	org	org	PROPN
eurjchem-405	193	17	.	.	PUNCT
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eurjchem-405	193	19	.	.	PUNCT
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eurjchem-405	194	2	,	,	PUNCT
eurjchem-405	194	3	68	68	NUM
eurjchem-405	194	4	,	,	PUNCT
eurjchem-405	194	5	3425‐3432	3425‐3432	NUM
eurjchem-405	194	6	.	.	PUNCT
eurjchem-405	195	1	[	[	X
eurjchem-405	195	2	8	8	NUM
eurjchem-405	195	3	]	]	PUNCT
eurjchem-405	195	4	.	.	PUNCT
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eurjchem-405	196	2	,	,	PUNCT
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eurjchem-405	196	5	;	;	PUNCT
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eurjchem-405	196	7	,	,	PUNCT
eurjchem-405	196	8	k.	k.	PROPN
eurjchem-405	196	9	;	;	PUNCT
eurjchem-405	196	10	kang	kang	PROPN
eurjchem-405	196	11	,	,	PUNCT
eurjchem-405	196	12	k.	k.	PROPN
eurjchem-405	196	13	;	;	PUNCT
eurjchem-405	196	14	oh	oh	INTJ
eurjchem-405	196	15	,	,	PUNCT
eurjchem-405	196	16	h.	h.	PROPN
eurjchem-405	196	17	k.	k.	PROPN
eurjchem-405	196	18	;	;	PUNCT
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eurjchem-405	196	20	,	,	PUNCT
eurjchem-405	196	21	i.	i.	PROPN
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eurjchem-405	196	23	.	.	PUNCT
eurjchem-405	197	1	korean	korean	ADJ
eurjchem-405	197	2	chem	chem	PROPN
eurjchem-405	197	3	.	.	PUNCT
eurjchem-405	198	1	soc	soc	PROPN
eurjchem-405	198	2	.	.	PUNCT
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eurjchem-405	199	2	,	,	PUNCT
eurjchem-405	199	3	17	17	NUM
eurjchem-405	199	4	,	,	PUNCT
eurjchem-405	199	5	520‐524	520‐524	NUM
eurjchem-405	199	6	.	.	PUNCT
eurjchem-405	200	1	[	[	X
eurjchem-405	200	2	9	9	NUM
eurjchem-405	200	3	]	]	PUNCT
eurjchem-405	200	4	.	.	PUNCT
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eurjchem-405	201	2	,	,	PUNCT
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eurjchem-405	201	4	n.	n.	PROPN
eurjchem-405	201	5	;	;	PUNCT
eurjchem-405	201	6	d’souza	d’souza	PROPN
eurjchem-405	201	7	,	,	PUNCT
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eurjchem-405	201	12	.	.	PUNCT
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eurjchem-405	202	2	.	.	PUNCT
eurjchem-405	202	3	,	,	PUNCT
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eurjchem-405	202	5	trans	trans	PROPN
eurjchem-405	202	6	.	.	PROPN
eurjchem-405	202	7	2	2	NUM
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eurjchem-405	202	9	,	,	PUNCT
eurjchem-405	202	10	1721‐	1721‐	NUM
eurjchem-405	202	11	1724	1724	NUM
eurjchem-405	202	12	.	.	PUNCT
eurjchem-405	203	1	[	[	X
eurjchem-405	203	2	10	10	NUM
eurjchem-405	203	3	]	]	PUNCT
eurjchem-405	203	4	.	.	PUNCT
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eurjchem-405	204	2	,	,	PUNCT
eurjchem-405	204	3	i.	i.	PROPN
eurjchem-405	204	4	s.	s.	PROPN
eurjchem-405	204	5	;	;	PUNCT
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eurjchem-405	204	7	,	,	PUNCT
eurjchem-405	204	8	k.	k.	PROPN
eurjchem-405	204	9	;	;	PUNCT
eurjchem-405	204	10	koo	koo	PROPN
eurjchem-405	204	11	,	,	PUNCT
eurjchem-405	204	12	j.	j.	PROPN
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eurjchem-405	204	14	;	;	PUNCT
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eurjchem-405	204	16	,	,	PUNCT
eurjchem-405	204	17	j.	j.	PROPN
eurjchem-405	204	18	–	–	PUNCT
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eurjchem-405	204	20	;	;	PUNCT
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eurjchem-405	204	22	,	,	PUNCT
eurjchem-405	204	23	i.	i.	PROPN
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eurjchem-405	204	25	.	.	PUNCT
eurjchem-405	205	1	korean	korean	ADJ
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eurjchem-405	205	3	.	.	PUNCT
eurjchem-405	206	1	soc	soc	PROPN
eurjchem-405	206	2	.	.	PUNCT
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eurjchem-405	207	2	,	,	PUNCT
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eurjchem-405	207	4	,	,	PUNCT
eurjchem-405	207	5	1017‐1021	1017‐1021	NUM
eurjchem-405	207	6	.	.	PUNCT
eurjchem-405	208	1	[	[	X
eurjchem-405	208	2	11	11	NUM
eurjchem-405	208	3	]	]	PUNCT
eurjchem-405	208	4	.	.	PUNCT
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eurjchem-405	208	6	,	,	PUNCT
eurjchem-405	208	7	i.	i.	PROPN
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eurjchem-405	208	9	;	;	PUNCT
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eurjchem-405	208	13	;	;	PUNCT
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eurjchem-405	208	15	,	,	PUNCT
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eurjchem-405	208	26	j.	j.	PROPN
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eurjchem-405	208	28	.	.	PUNCT
eurjchem-405	209	1	soc	soc	PROPN
eurjchem-405	209	2	.	.	PUNCT
eurjchem-405	209	3	,	,	PUNCT
eurjchem-405	209	4	perkin	perkin	PROPN
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eurjchem-405	209	6	2	2	NUM
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eurjchem-405	209	8	,	,	PUNCT
eurjchem-405	209	9	1179‐1183	1179‐1183	NUM
eurjchem-405	209	10	.	.	PUNCT
eurjchem-405	210	1	[	[	X
eurjchem-405	210	2	12	12	NUM
eurjchem-405	210	3	]	]	PUNCT
eurjchem-405	210	4	.	.	PUNCT
eurjchem-405	211	1	kevill	kevill	PROPN
eurjchem-405	211	2	,	,	PUNCT
eurjchem-405	211	3	d.	d.	PROPN
eurjchem-405	211	4	n.	n.	PROPN
eurjchem-405	211	5	;	;	PUNCT
eurjchem-405	211	6	d’souza	d’souza	PROPN
eurjchem-405	211	7	,	,	PUNCT
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eurjchem-405	211	10	j.	j.	PROPN
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eurjchem-405	211	12	.	.	PUNCT
eurjchem-405	211	13	chem	chem	PROPN
eurjchem-405	211	14	.	.	PUNCT
eurjchem-405	212	1	1998	1998	NUM
eurjchem-405	212	2	,	,	PUNCT
eurjchem-405	212	3	63	63	NUM
eurjchem-405	212	4	,	,	PUNCT
eurjchem-405	212	5	2120‐2124	2120‐2124	NUM
eurjchem-405	212	6	.	.	PUNCT
eurjchem-405	213	1	[	[	X
eurjchem-405	213	2	13	13	NUM
eurjchem-405	213	3	]	]	PUNCT
eurjchem-405	213	4	.	.	PUNCT
eurjchem-405	214	1	koo	koo	PROPN
eurjchem-405	214	2	,	,	PUNCT
eurjchem-405	214	3	i.	i.	PROPN
eurjchem-405	214	4	s.	s.	PROPN
eurjchem-405	214	5	;	;	PUNCT
eurjchem-405	214	6	yang	yang	PROPN
eurjchem-405	214	7	,	,	PUNCT
eurjchem-405	214	8	k.	k.	PROPN
eurjchem-405	214	9	;	;	PUNCT
eurjchem-405	214	10	kang	kang	PROPN
eurjchem-405	214	11	,	,	PUNCT
eurjchem-405	214	12	k.	k.	PROPN
eurjchem-405	214	13	;	;	PUNCT
eurjchem-405	214	14	lee	lee	PROPN
eurjchem-405	214	15	,	,	PUNCT
eurjchem-405	214	16	i.	i.	PROPN
eurjchem-405	214	17	bull	bull	PROPN
eurjchem-405	214	18	.	.	PUNCT
eurjchem-405	215	1	korean	korean	ADJ
eurjchem-405	215	2	chem	chem	PROPN
eurjchem-405	215	3	.	.	PUNCT
eurjchem-405	216	1	soc	soc	PROPN
eurjchem-405	216	2	.	.	PUNCT
eurjchem-405	217	1	1998	1998	NUM
eurjchem-405	217	2	,	,	PUNCT
eurjchem-405	217	3	19	19	NUM
eurjchem-405	217	4	,	,	PUNCT
eurjchem-405	217	5	968‐973	968‐973	NUM
eurjchem-405	217	6	.	.	PUNCT
eurjchem-405	218	1	[	[	X
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eurjchem-405	218	3	]	]	SYM
eurjchem-405	218	4	.	.	PUNCT
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eurjchem-405	219	2	,	,	PUNCT
eurjchem-405	219	3	d.	d.	PROPN
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eurjchem-405	219	5	;	;	PUNCT
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eurjchem-405	219	7	,	,	PUNCT
eurjchem-405	219	8	j.	j.	PROPN
eurjchem-405	219	9	c.	c.	PROPN
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eurjchem-405	219	13	j.	j.	PROPN
eurjchem-405	219	14	b.	b.	PROPN
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eurjchem-405	221	2	.	.	PUNCT
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eurjchem-405	222	2	,	,	PUNCT
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eurjchem-405	222	4	.	.	PUNCT
eurjchem-405	223	1	[	[	X
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eurjchem-405	223	3	]	]	PUNCT
eurjchem-405	223	4	.	.	PUNCT
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eurjchem-405	224	2	,	,	PUNCT
eurjchem-405	224	3	j.	j.	PROPN
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eurjchem-405	224	5	;	;	PUNCT
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eurjchem-405	224	7	,	,	PUNCT
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eurjchem-405	224	10	;	;	PUNCT
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eurjchem-405	224	12	,	,	PUNCT
eurjchem-405	224	13	d.	d.	PROPN
eurjchem-405	224	14	k.	k.	PROPN
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eurjchem-405	226	2	.	.	PUNCT
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eurjchem-405	227	2	,	,	PUNCT
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eurjchem-405	228	3	]	]	PUNCT
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eurjchem-405	232	2	,	,	PUNCT
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eurjchem-405	232	4	,	,	PUNCT
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eurjchem-405	233	3	]	]	PUNCT
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eurjchem-405	234	2	,	,	PUNCT
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eurjchem-405	234	7	,	,	PUNCT
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eurjchem-405	235	2	.	.	PUNCT
eurjchem-405	235	3	;	;	PUNCT
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eurjchem-405	236	2	,	,	PUNCT
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eurjchem-405	236	5	.	.	PUNCT
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eurjchem-405	237	2	,	,	PUNCT
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eurjchem-405	237	4	,	,	PUNCT
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eurjchem-405	237	6	.	.	PUNCT
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eurjchem-405	238	3	]	]	PUNCT
eurjchem-405	238	4	.	.	PUNCT
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eurjchem-405	240	2	.	.	PUNCT
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eurjchem-405	240	9	,	,	PUNCT
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eurjchem-405	242	5	;	;	PUNCT
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eurjchem-405	242	7	,	,	PUNCT
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eurjchem-405	243	2	,	,	PUNCT
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eurjchem-405	243	4	,	,	PUNCT
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eurjchem-405	243	6	.	.	PUNCT
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eurjchem-405	244	3	]	]	PUNCT
eurjchem-405	244	4	.	.	PUNCT
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eurjchem-405	245	2	,	,	PUNCT
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eurjchem-405	245	5	;	;	PUNCT
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eurjchem-405	247	2	.	.	PROPN
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eurjchem-405	247	4	,	,	PUNCT
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eurjchem-405	247	6	,	,	PUNCT
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eurjchem-405	247	8	.	.	PUNCT
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eurjchem-405	248	4	.	.	PUNCT
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eurjchem-405	249	2	,	,	PUNCT
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eurjchem-405	249	5	;	;	PUNCT
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eurjchem-405	250	20	.	.	PUNCT
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eurjchem-405	251	2	,	,	PUNCT
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eurjchem-405	251	4	,	,	PUNCT
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eurjchem-405	252	4	.	.	PUNCT
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eurjchem-405	253	2	,	,	PUNCT
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eurjchem-405	253	10	;	;	PUNCT
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eurjchem-405	255	2	.	.	PUNCT
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eurjchem-405	256	2	,	,	PUNCT
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eurjchem-405	256	4	,	,	PUNCT
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eurjchem-405	256	7	.	.	PUNCT
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eurjchem-405	258	5	;	;	PUNCT
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eurjchem-405	260	4	,	,	PUNCT
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eurjchem-405	266	5	;	;	PUNCT
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eurjchem-405	268	4	,	,	PUNCT
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eurjchem-405	268	6	,	,	PUNCT
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eurjchem-405	273	14	j.	j.	PROPN
eurjchem-405	273	15	;	;	PUNCT
eurjchem-405	273	16	kyong	kyong	PROPN
eurjchem-405	273	17	,	,	PUNCT
eurjchem-405	273	18	k.	k.	PROPN
eurjchem-405	273	19	j.	j.	PROPN
eurjchem-405	273	20	;	;	PUNCT
eurjchem-405	273	21	kevill	kevill	PROPN
eurjchem-405	273	22	,	,	PUNCT
eurjchem-405	273	23	d.	d.	PROPN
eurjchem-405	273	24	n.	n.	PROPN
eurjchem-405	273	25	int	int	PROPN
eurjchem-405	273	26	.	.	PUNCT
eurjchem-405	274	1	j.	j.	PROPN
eurjchem-405	274	2	mol	mol	PROPN
eurjchem-405	274	3	.	.	PUNCT
eurjchem-405	275	1	sci	sci	PROPN
eurjchem-405	275	2	.	.	PROPN
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eurjchem-405	275	4	,	,	PUNCT
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eurjchem-405	275	6	,	,	PUNCT
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eurjchem-405	275	8	.	.	PUNCT
eurjchem-405	276	1	[	[	X
eurjchem-405	276	2	28	28	NUM
eurjchem-405	276	3	]	]	PUNCT
eurjchem-405	276	4	.	.	PUNCT
eurjchem-405	277	1	koh	koh	PROPN
eurjchem-405	277	2	,	,	PUNCT
eurjchem-405	277	3	h.	h.	PROPN
eurjchem-405	277	4	j.	j.	PROPN
eurjchem-405	277	5	;	;	PUNCT
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eurjchem-405	277	7	,	,	PUNCT
eurjchem-405	277	8	s.	s.	PROPN
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eurjchem-405	277	10	;	;	PUNCT
eurjchem-405	277	11	kevill	kevill	PROPN
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eurjchem-405	277	13	d.	d.	PROPN
eurjchem-405	277	14	n.	n.	PROPN
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eurjchem-405	277	16	.	.	PUNCT
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eurjchem-405	279	1	soc	soc	PROPN
eurjchem-405	279	2	.	.	PUNCT
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eurjchem-405	280	2	,	,	PUNCT
eurjchem-405	280	3	31	31	NUM
eurjchem-405	280	4	,	,	PUNCT
eurjchem-405	280	5	835‐839	835‐839	NUM
eurjchem-405	280	6	.	.	PUNCT
eurjchem-405	281	1	[	[	X
eurjchem-405	281	2	29	29	NUM
eurjchem-405	281	3	]	]	PUNCT
eurjchem-405	281	4	.	.	PUNCT
eurjchem-405	282	1	kevill	kevill	PROPN
eurjchem-405	282	2	,	,	PUNCT
eurjchem-405	282	3	d.	d.	PROPN
eurjchem-405	282	4	n.	n.	PROPN
eurjchem-405	282	5	;	;	PUNCT
eurjchem-405	282	6	d’souza	d’souza	PROPN
eurjchem-405	282	7	,	,	PUNCT
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eurjchem-405	282	9	j.	j.	PROPN
eurjchem-405	282	10	j.	j.	PROPN
eurjchem-405	282	11	org	org	PROPN
eurjchem-405	282	12	.	.	PUNCT
eurjchem-405	282	13	chem	chem	PROPN
eurjchem-405	282	14	.	.	PUNCT
eurjchem-405	283	1	1997	1997	NUM
eurjchem-405	283	2	,	,	PUNCT
eurjchem-405	283	3	62	62	NUM
eurjchem-405	283	4	,	,	PUNCT
eurjchem-405	283	5	7869‐7871	7869‐7871	NUM
eurjchem-405	283	6	.	.	PUNCT
eurjchem-405	284	1	[	[	X
eurjchem-405	284	2	30	30	NUM
eurjchem-405	284	3	]	]	PUNCT
eurjchem-405	284	4	.	.	PUNCT
eurjchem-405	285	1	kevill	kevill	PROPN
eurjchem-405	285	2	,	,	PUNCT
eurjchem-405	285	3	d.	d.	PROPN
eurjchem-405	285	4	n.	n.	PROPN
eurjchem-405	285	5	;	;	PUNCT
eurjchem-405	285	6	d’souza	d’souza	PROPN
eurjchem-405	285	7	,	,	PUNCT
eurjchem-405	285	8	m.	m.	NOUN
eurjchem-405	285	9	j.	j.	PROPN
eurjchem-405	285	10	can	can	PROPN
eurjchem-405	285	11	.	.	PUNCT
eurjchem-405	286	1	j.	j.	PROPN
eurjchem-405	286	2	chem	chem	PROPN
eurjchem-405	286	3	.	.	PUNCT
eurjchem-405	287	1	1999	1999	NUM
eurjchem-405	287	2	,	,	PUNCT
eurjchem-405	287	3	77	77	NUM
eurjchem-405	287	4	,	,	PUNCT
eurjchem-405	287	5	1118‐1122	1118‐1122	NUM
eurjchem-405	287	6	.	.	PUNCT
eurjchem-405	288	1	[	[	X
eurjchem-405	288	2	31	31	NUM
eurjchem-405	288	3	]	]	PUNCT
eurjchem-405	288	4	.	.	PUNCT
eurjchem-405	289	1	koo	koo	PROPN
eurjchem-405	289	2	,	,	PUNCT
eurjchem-405	289	3	i.	i.	PROPN
eurjchem-405	289	4	s.	s.	PROPN
eurjchem-405	289	5	;	;	PUNCT
eurjchem-405	289	6	yang	yang	PROPN
eurjchem-405	289	7	,	,	PUNCT
eurjchem-405	289	8	k.	k.	PROPN
eurjchem-405	289	9	;	;	PUNCT
eurjchem-405	289	10	kang	kang	PROPN
eurjchem-405	289	11	,	,	PUNCT
eurjchem-405	289	12	d.	d.	PROPN
eurjchem-405	289	13	h.	h.	PROPN
eurjchem-405	289	14	;	;	PUNCT
eurjchem-405	289	15	park	park	PROPN
eurjchem-405	289	16	,	,	PUNCT
eurjchem-405	289	17	h.	h.	PROPN
eurjchem-405	289	18	j.	j.	PROPN
eurjchem-405	289	19	;	;	PUNCT
eurjchem-405	289	20	kang	kang	PROPN
eurjchem-405	289	21	,	,	PUNCT
eurjchem-405	289	22	k.	k.	PROPN
eurjchem-405	289	23	;	;	PUNCT
eurjchem-405	289	24	lee	lee	PROPN
eurjchem-405	289	25	,	,	PUNCT
eurjchem-405	289	26	i.	i.	PROPN
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eurjchem-405	289	28	.	.	PUNCT
eurjchem-405	290	1	korean	korean	ADJ
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eurjchem-405	290	3	.	.	PUNCT
eurjchem-405	291	1	soc	soc	PROPN
eurjchem-405	291	2	.	.	PUNCT
eurjchem-405	292	1	1999	1999	NUM
eurjchem-405	292	2	,	,	PUNCT
eurjchem-405	292	3	20	20	NUM
eurjchem-405	292	4	,	,	PUNCT
eurjchem-405	292	5	577	577	NUM
eurjchem-405	292	6	.	.	PUNCT
eurjchem-405	293	1	[	[	X
eurjchem-405	293	2	32	32	NUM
eurjchem-405	293	3	]	]	PUNCT
eurjchem-405	293	4	.	.	PUNCT
eurjchem-405	294	1	an	an	PRON
eurjchem-405	294	2	,	,	PUNCT
eurjchem-405	294	3	s.	s.	PROPN
eurjchem-405	294	4	k.	k.	PROPN
eurjchem-405	294	5	;	;	PUNCT
eurjchem-405	294	6	yang	yang	PROPN
eurjchem-405	294	7	,	,	PUNCT
eurjchem-405	294	8	j.	j.	PROPN
eurjchem-405	294	9	s.	s.	PROPN
eurjchem-405	294	10	;	;	PUNCT
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eurjchem-405	294	12	,	,	PUNCT
eurjchem-405	294	13	j.	j.	PROPN
eurjchem-405	294	14	m.	m.	PROPN
eurjchem-405	294	15	;	;	PUNCT
eurjchem-405	294	16	yang	yang	PROPN
eurjchem-405	294	17	,	,	PUNCT
eurjchem-405	294	18	k.	k.	PROPN
eurjchem-405	294	19	;	;	PUNCT
eurjchem-405	294	20	lee	lee	PROPN
eurjchem-405	294	21	,	,	PUNCT
eurjchem-405	294	22	p.	p.	PROPN
eurjchem-405	294	23	l.	l.	PROPN
eurjchem-405	294	24	;	;	PUNCT
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eurjchem-405	294	26	,	,	PUNCT
eurjchem-405	294	27	t.	t.	PROPN
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eurjchem-405	294	29	;	;	PUNCT
eurjchem-405	294	30	lee	lee	PROPN
eurjchem-405	294	31	,	,	PUNCT
eurjchem-405	294	32	i.	i.	PROPN
eurjchem-405	294	33	;	;	PUNCT
eurjchem-405	294	34	koo	koo	PROPN
eurjchem-405	294	35	,	,	PUNCT
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eurjchem-405	294	37	s.	s.	PROPN
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eurjchem-405	294	39	.	.	PUNCT
eurjchem-405	295	1	korean	korean	ADJ
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eurjchem-405	295	3	.	.	PUNCT
eurjchem-405	296	1	soc	soc	PROPN
eurjchem-405	296	2	.	.	PUNCT
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eurjchem-405	297	2	,	,	PUNCT
eurjchem-405	297	3	23	23	NUM
eurjchem-405	297	4	,	,	PUNCT
eurjchem-405	297	5	1445	1445	NUM
eurjchem-405	297	6	.	.	PUNCT
eurjchem-405	298	1	[	[	X
eurjchem-405	298	2	33	33	NUM
eurjchem-405	298	3	]	]	PUNCT
eurjchem-405	298	4	.	.	PUNCT
eurjchem-405	299	1	d’souza	d’souza	PROPN
eurjchem-405	299	2	,	,	PUNCT
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eurjchem-405	299	5	;	;	PUNCT
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eurjchem-405	299	7	,	,	PUNCT
eurjchem-405	299	8	s.	s.	PROPN
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eurjchem-405	299	10	;	;	PUNCT
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eurjchem-405	300	1	j.	j.	PROPN
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eurjchem-405	300	3	.	.	PUNCT
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eurjchem-405	301	2	.	.	PROPN
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eurjchem-405	301	4	,	,	PUNCT
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eurjchem-405	301	6	,	,	PUNCT
eurjchem-405	301	7	2253‐	2253‐	NUM
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eurjchem-405	301	9	.	.	PUNCT
eurjchem-405	302	1	[	[	X
eurjchem-405	302	2	34	34	NUM
eurjchem-405	302	3	]	]	PUNCT
eurjchem-405	302	4	.	.	PUNCT
eurjchem-405	303	1	d’souza	d’souza	PROPN
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eurjchem-405	303	3	j.	j.	PROPN
eurjchem-405	303	4	;	;	PUNCT
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eurjchem-405	303	6	,	,	PUNCT
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eurjchem-405	303	9	;	;	PUNCT
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eurjchem-405	304	1	j.	j.	PROPN
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eurjchem-405	304	3	.	.	PUNCT
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eurjchem-405	305	2	.	.	PROPN
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eurjchem-405	305	4	,	,	PUNCT
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eurjchem-405	305	8	2611	2611	NUM
eurjchem-405	305	9	.	.	PUNCT
eurjchem-405	306	1	[	[	X
eurjchem-405	306	2	35	35	NUM
eurjchem-405	306	3	]	]	SYM
eurjchem-405	306	4	.	.	PUNCT
eurjchem-405	307	1	kevill	kevill	PROPN
eurjchem-405	307	2	,	,	PUNCT
eurjchem-405	307	3	d.	d.	PROPN
eurjchem-405	307	4	n.	n.	PROPN
eurjchem-405	307	5	;	;	PUNCT
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eurjchem-405	307	7	,	,	PUNCT
eurjchem-405	307	8	s.	s.	PROPN
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eurjchem-405	307	10	j.	j.	PROPN
eurjchem-405	307	11	org	org	PROPN
eurjchem-405	307	12	.	.	PUNCT
eurjchem-405	307	13	chem	chem	PROPN
eurjchem-405	307	14	.	.	PUNCT
eurjchem-405	308	1	1991	1991	NUM
eurjchem-405	308	2	,	,	PUNCT
eurjchem-405	308	3	56	56	NUM
eurjchem-405	308	4	,	,	PUNCT
eurjchem-405	308	5	1845‐1850	1845‐1850	NUM
eurjchem-405	308	6	.	.	PUNCT
eurjchem-405	309	1	[	[	X
eurjchem-405	309	2	36	36	NUM
eurjchem-405	309	3	]	]	PUNCT
eurjchem-405	309	4	.	.	PUNCT
eurjchem-405	310	1	kevill	kevill	PROPN
eurjchem-405	310	2	,	,	PUNCT
eurjchem-405	310	3	d.	d.	PROPN
eurjchem-405	310	4	n.	n.	PROPN
eurjchem-405	310	5	development	development	PROPN
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eurjchem-405	310	13	.	.	PUNCT
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eurjchem-405	311	5	structure‐property	structure‐property	NOUN
eurjchem-405	311	6	relationships	relationship	NOUN
eurjchem-405	311	7	;	;	PUNCT
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eurjchem-405	311	9	,	,	PUNCT
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eurjchem-405	311	14	;	;	PUNCT
eurjchem-405	311	15	jai	jai	PROPN
eurjchem-405	311	16	press	press	PROPN
eurjchem-405	311	17	:	:	PUNCT
eurjchem-405	311	18	greenwich	greenwich	PROPN
eurjchem-405	311	19	,	,	PUNCT
eurjchem-405	311	20	ct	ct	PROPN
eurjchem-405	311	21	,	,	PUNCT
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eurjchem-405	311	27	.	.	PUNCT
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eurjchem-405	312	2	115	115	NUM
eurjchem-405	312	3	,	,	PUNCT
eurjchem-405	312	4	1996	1996	NUM
eurjchem-405	313	1	[	[	X
eurjchem-405	313	2	37	37	NUM
eurjchem-405	313	3	]	]	PUNCT
eurjchem-405	313	4	.	.	PUNCT
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eurjchem-405	314	5	;	;	PUNCT
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eurjchem-405	314	7	,	,	PUNCT
eurjchem-405	314	8	g.	g.	PROPN
eurjchem-405	314	9	e.	e.	PROPN
eurjchem-405	314	10	;	;	PUNCT
eurjchem-405	314	11	j.	j.	PROPN
eurjchem-405	314	12	am	am	PROPN
eurjchem-405	314	13	.	.	PUNCT
eurjchem-405	315	1	chem	chem	PROPN
eurjchem-405	315	2	.	.	PUNCT
eurjchem-405	316	1	soc	soc	PROPN
eurjchem-405	316	2	.	.	PUNCT
eurjchem-405	317	1	1982	1982	NUM
eurjchem-405	317	2	,	,	PUNCT
eurjchem-405	317	3	104	104	NUM
eurjchem-405	317	4	,	,	PUNCT
eurjchem-405	317	5	5741‐5747	5741‐5747	PROPN
eurjchem-405	317	6	.	.	PUNCT
eurjchem-405	318	1	[	[	X
eurjchem-405	318	2	38	38	NUM
eurjchem-405	318	3	]	]	PUNCT
eurjchem-405	318	4	.	.	PUNCT
eurjchem-405	319	1	bentley	bentley	PROPN
eurjchem-405	319	2	,	,	PUNCT
eurjchem-405	319	3	t.w	t.w	PROPN
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eurjchem-405	319	5	;	;	PUNCT
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eurjchem-405	319	7	,	,	PUNCT
eurjchem-405	319	8	g.	g.	PROPN
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eurjchem-405	319	10	.	.	PUNCT
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eurjchem-405	320	2	.	.	PUNCT
eurjchem-405	321	1	org	org	PROPN
eurjchem-405	321	2	.	.	PUNCT
eurjchem-405	321	3	chem	chem	PROPN
eurjchem-405	321	4	.	.	PUNCT
eurjchem-405	322	1	1990	1990	NUM
eurjchem-405	322	2	,	,	PUNCT
eurjchem-405	322	3	17	17	NUM
eurjchem-405	322	4	,	,	PUNCT
eurjchem-405	322	5	121‐158	121‐158	NUM
eurjchem-405	322	6	.	.	PUNCT
eurjchem-405	323	1	[	[	X
eurjchem-405	323	2	39	39	NUM
eurjchem-405	323	3	]	]	PUNCT
eurjchem-405	323	4	.	.	PUNCT
eurjchem-405	324	1	hawkinson	hawkinson	PROPN
eurjchem-405	324	2	,	,	PUNCT
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eurjchem-405	324	5	;	;	PUNCT
eurjchem-405	324	6	kevill	kevill	PROPN
eurjchem-405	324	7	,	,	PUNCT
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eurjchem-405	324	10	j.	j.	PROPN
eurjchem-405	324	11	org	org	PROPN
eurjchem-405	324	12	.	.	PUNCT
eurjchem-405	324	13	chem	chem	PROPN
eurjchem-405	324	14	.	.	PUNCT
eurjchem-405	325	1	1988	1988	NUM
eurjchem-405	325	2	,	,	PUNCT
eurjchem-405	325	3	53	53	NUM
eurjchem-405	325	4	,	,	PUNCT
eurjchem-405	325	5	3857‐3860	3857‐3860	NUM
eurjchem-405	325	6	.	.	PUNCT
eurjchem-405	326	1	[	[	X
eurjchem-405	326	2	40	40	NUM
eurjchem-405	326	3	]	]	PUNCT
eurjchem-405	326	4	.	.	PUNCT
eurjchem-405	327	1	kevill	kevill	PROPN
eurjchem-405	327	2	,	,	PUNCT
eurjchem-405	327	3	d.	d.	PROPN
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eurjchem-405	327	5	;	;	PUNCT
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eurjchem-405	327	7	,	,	PUNCT
eurjchem-405	327	8	d.	d.	PROPN
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eurjchem-405	327	10	j.	j.	PROPN
eurjchem-405	327	11	org	org	PROPN
eurjchem-405	327	12	.	.	PUNCT
eurjchem-405	327	13	chem	chem	PROPN
eurjchem-405	327	14	.	.	PUNCT
eurjchem-405	328	1	1989	1989	NUM
eurjchem-405	328	2	,	,	PUNCT
eurjchem-405	328	3	54	54	NUM
eurjchem-405	328	4	,	,	PUNCT
eurjchem-405	328	5	154‐158	154‐158	NUM
eurjchem-405	328	6	.	.	PUNCT
eurjchem-405	329	1	[	[	X
eurjchem-405	329	2	41	41	NUM
eurjchem-405	329	3	]	]	PUNCT
eurjchem-405	329	4	.	.	PUNCT
eurjchem-405	330	1	kevill	kevill	PROPN
eurjchem-405	330	2	,	,	PUNCT
eurjchem-405	330	3	d.	d.	PROPN
eurjchem-405	330	4	n.	n.	PROPN
eurjchem-405	330	5	;	;	PUNCT
eurjchem-405	330	6	d’souza	d’souza	PROPN
eurjchem-405	330	7	,	,	PUNCT
eurjchem-405	330	8	m.	m.	NOUN
eurjchem-405	330	9	j.	j.	PROPN
eurjchem-405	330	10	j.	j.	PROPN
eurjchem-405	330	11	chem	chem	PROPN
eurjchem-405	330	12	.	.	PUNCT
eurjchem-405	331	1	res	re	NOUN
eurjchem-405	331	2	.	.	PUNCT
eurjchem-405	332	1	synop	synop	ADJ
eurjchem-405	332	2	.	.	PUNCT
eurjchem-405	333	1	1993	1993	NUM
eurjchem-405	333	2	,	,	PUNCT
eurjchem-405	333	3	174‐175	174‐175	NUM
eurjchem-405	333	4	.	.	PUNCT
eurjchem-405	334	1	[	[	X
eurjchem-405	334	2	42	42	NUM
eurjchem-405	334	3	]	]	PUNCT
eurjchem-405	334	4	.	.	PUNCT
eurjchem-405	335	1	lomas	lomas	PROPN
eurjchem-405	335	2	,	,	PUNCT
eurjchem-405	335	3	j.	j.	PROPN
eurjchem-405	335	4	s.	s.	PROPN
eurjchem-405	335	5	;	;	PUNCT
eurjchem-405	335	6	d’souza	d’souza	PROPN
eurjchem-405	335	7	,	,	PUNCT
eurjchem-405	335	8	m.	m.	NOUN
eurjchem-405	335	9	j.	j.	PROPN
eurjchem-405	335	10	,	,	PUNCT
eurjchem-405	335	11	kevill	kevill	PROPN
eurjchem-405	335	12	,	,	PUNCT
eurjchem-405	335	13	d.	d.	PROPN
eurjchem-405	335	14	n.	n.	PROPN
eurjchem-405	335	15	j.	j.	PROPN
eurjchem-405	335	16	am	am	PROPN
eurjchem-405	335	17	.	.	PUNCT
eurjchem-405	336	1	chem	chem	NOUN
eurjchem-405	336	2	.	.	PUNCT
eurjchem-405	337	1	soc	soc	PROPN
eurjchem-405	337	2	.	.	PUNCT
eurjchem-405	338	1	1995	1995	NUM
eurjchem-405	338	2	,	,	PUNCT
eurjchem-405	338	3	117	117	NUM
eurjchem-405	338	4	,	,	PUNCT
eurjchem-405	338	5	5891‐5892	5891‐5892	NUM
eurjchem-405	338	6	.	.	PUNCT
eurjchem-405	339	1	[	[	X
eurjchem-405	339	2	43	43	NUM
eurjchem-405	339	3	]	]	PUNCT
eurjchem-405	339	4	.	.	PUNCT
eurjchem-405	340	1	kevill	kevill	PROPN
eurjchem-405	340	2	,	,	PUNCT
eurjchem-405	340	3	d.	d.	PROPN
eurjchem-405	340	4	n.	n.	PROPN
eurjchem-405	340	5	;	;	PUNCT
eurjchem-405	340	6	ryu	ryu	PROPN
eurjchem-405	340	7	,	,	PUNCT
eurjchem-405	340	8	z.	z.	PROPN
eurjchem-405	340	9	h.	h.	PROPN
eurjchem-405	340	10	int	int	PROPN
eurjchem-405	340	11	.	.	PUNCT
eurjchem-405	341	1	j.	j.	PROPN
eurjchem-405	341	2	mol	mol	PROPN
eurjchem-405	341	3	.	.	PUNCT
eurjchem-405	342	1	sci	sci	PROPN
eurjchem-405	342	2	.	.	PUNCT
eurjchem-405	342	3	2006	2006	NUM
eurjchem-405	342	4	,	,	PUNCT
eurjchem-405	342	5	7	7	NUM
eurjchem-405	342	6	,	,	PUNCT
eurjchem-405	342	7	451‐455	451‐455	NUM
eurjchem-405	342	8	.	.	PUNCT
eurjchem-405	343	1	[	[	X
eurjchem-405	343	2	44	44	NUM
eurjchem-405	343	3	]	]	PUNCT
eurjchem-405	343	4	.	.	PUNCT
eurjchem-405	344	1	bentley	bentley	PROPN
eurjchem-405	344	2	,	,	PUNCT
eurjchem-405	344	3	t.	t.	PROPN
eurjchem-405	344	4	w.	w.	PROPN
eurjchem-405	344	5	;	;	PUNCT
eurjchem-405	344	6	koo	koo	PROPN
eurjchem-405	344	7	,	,	PUNCT
eurjchem-405	344	8	i.	i.	PROPN
eurjchem-405	344	9	s.	s.	PROPN
eurjchem-405	344	10	;	;	PUNCT
eurjchem-405	344	11	norman	norman	PROPN
eurjchem-405	344	12	,	,	PUNCT
eurjchem-405	344	13	s.	s.	PROPN
eurjchem-405	344	14	j.	j.	PROPN
eurjchem-405	344	15	j.	j.	PROPN
eurjchem-405	344	16	org	org	PROPN
eurjchem-405	344	17	.	.	PUNCT
eurjchem-405	344	18	chem	chem	PROPN
eurjchem-405	344	19	.	.	PUNCT
eurjchem-405	345	1	1991	1991	NUM
eurjchem-405	345	2	,	,	PUNCT
eurjchem-405	345	3	56	56	NUM
eurjchem-405	345	4	,	,	PUNCT
eurjchem-405	345	5	1604‐	1604‐	NUM
eurjchem-405	345	6	1609	1609	NUM
eurjchem-405	345	7	.	.	PUNCT
eurjchem-405	346	1	[	[	X
eurjchem-405	346	2	45	45	NUM
eurjchem-405	346	3	]	]	PUNCT
eurjchem-405	346	4	.	.	PUNCT
eurjchem-405	347	1	liu	liu	PROPN
eurjchem-405	347	2	,	,	PUNCT
eurjchem-405	347	3	k.	k.	PROPN
eurjchem-405	347	4	t.	t.	PROPN
eurjchem-405	347	5	;	;	PUNCT
eurjchem-405	347	6	sheu	sheu	PROPN
eurjchem-405	347	7	,	,	PUNCT
eurjchem-405	347	8	h.	h.	PROPN
eurjchem-405	347	9	c.	c.	PROPN
eurjchem-405	347	10	j.	j.	PROPN
eurjchem-405	347	11	org	org	PROPN
eurjchem-405	347	12	.	.	PUNCT
eurjchem-405	347	13	chem	chem	PROPN
eurjchem-405	347	14	.	.	PUNCT
eurjchem-405	348	1	1991	1991	NUM
eurjchem-405	348	2	,	,	PUNCT
eurjchem-405	348	3	56	56	NUM
eurjchem-405	348	4	,	,	PUNCT
eurjchem-405	348	5	3021‐3025	3021‐3025	NUM
eurjchem-405	348	6	.	.	PUNCT
eurjchem-405	349	1	[	[	X
eurjchem-405	349	2	46	46	NUM
eurjchem-405	349	3	]	]	PUNCT
eurjchem-405	349	4	.	.	PUNCT
eurjchem-405	350	1	fujio	fujio	ADJ
eurjchem-405	350	2	,	,	PUNCT
eurjchem-405	350	3	m.	m.	NOUN
eurjchem-405	350	4	;	;	PUNCT
eurjchem-405	350	5	saeki	saeki	PROPN
eurjchem-405	350	6	,	,	PUNCT
eurjchem-405	350	7	y.	y.	PROPN
eurjchem-405	350	8	;	;	PUNCT
eurjchem-405	350	9	nakamoto	nakamoto	NOUN
eurjchem-405	350	10	,	,	PUNCT
eurjchem-405	350	11	k.	k.	PROPN
eurjchem-405	350	12	;	;	PUNCT
eurjchem-405	350	13	yatsugi	yatsugi	PROPN
eurjchem-405	350	14	,	,	PUNCT
eurjchem-405	350	15	k.	k.	PROPN
eurjchem-405	350	16	;	;	PUNCT
eurjchem-405	350	17	goto	goto	NOUN
eurjchem-405	350	18	,	,	PUNCT
eurjchem-405	350	19	n.	n.	PROPN
eurjchem-405	350	20	;	;	PUNCT
eurjchem-405	350	21	kim	kim	PROPN
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eurjchem-405	350	23	s.	s.	PROPN
eurjchem-405	350	24	h.	h.	PROPN
eurjchem-405	350	25	;	;	PUNCT
eurjchem-405	350	26	tsuji	tsuji	PROPN
eurjchem-405	350	27	,	,	PUNCT
eurjchem-405	350	28	y.	y.	PROPN
eurjchem-405	350	29	;	;	PUNCT
eurjchem-405	350	30	rappoport	rappoport	PROPN
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eurjchem-405	350	32	z.	z.	PROPN
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eurjchem-405	350	35	,	,	PUNCT
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eurjchem-405	350	37	bull	bull	PROPN
eurjchem-405	350	38	.	.	PUNCT
eurjchem-405	351	1	chem	chem	NOUN
eurjchem-405	351	2	.	.	PUNCT
eurjchem-405	352	1	soc	soc	PROPN
eurjchem-405	352	2	.	.	PUNCT
eurjchem-405	353	1	jpn	jpn	PROPN
eurjchem-405	353	2	.	.	PROPN
eurjchem-405	353	3	,	,	PUNCT
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eurjchem-405	353	5	,	,	PUNCT
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eurjchem-405	353	7	,	,	PUNCT
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eurjchem-405	353	9	.	.	PUNCT
eurjchem-405	354	1	[	[	X
eurjchem-405	354	2	47	47	NUM
eurjchem-405	354	3	]	]	PUNCT
eurjchem-405	354	4	.	.	PUNCT
eurjchem-405	355	1	kevill	kevill	PROPN
eurjchem-405	355	2	,	,	PUNCT
eurjchem-405	355	3	d.	d.	PROPN
eurjchem-405	355	4	n.	n.	PROPN
eurjchem-405	355	5	;	;	PUNCT
eurjchem-405	355	6	d’souza	d’souza	PROPN
eurjchem-405	355	7	,	,	PUNCT
eurjchem-405	355	8	m.	m.	NOUN
eurjchem-405	355	9	j.	j.	PROPN
eurjchem-405	355	10	cur	cur	PROPN
eurjchem-405	355	11	.	.	PUNCT
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eurjchem-405	355	13	.	.	PUNCT
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eurjchem-405	355	15	.	.	PUNCT
eurjchem-405	356	1	2010	2010	NUM
eurjchem-405	356	2	,	,	PUNCT
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eurjchem-405	356	4	,	,	PUNCT
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eurjchem-405	356	6	.	.	PUNCT
eurjchem-405	357	1	[	[	X
eurjchem-405	357	2	48	48	NUM
eurjchem-405	357	3	]	]	PUNCT
eurjchem-405	357	4	.	.	PUNCT
eurjchem-405	358	1	kevill	kevill	PROPN
eurjchem-405	358	2	,	,	PUNCT
eurjchem-405	358	3	d.	d.	PROPN
eurjchem-405	358	4	n.	n.	PROPN
eurjchem-405	358	5	;	;	PUNCT
eurjchem-405	358	6	ismail	ismail	PROPN
eurjchem-405	358	7	,	,	PUNCT
eurjchem-405	358	8	n.	n.	PROPN
eurjchem-405	358	9	hj	hj	PROPN
eurjchem-405	358	10	.	.	PROPN
eurjchem-405	358	11	;	;	PUNCT
eurjchem-405	358	12	d’souza	d’souza	PROPN
eurjchem-405	358	13	,	,	PUNCT
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eurjchem-405	358	15	j.	j.	PROPN
eurjchem-405	358	16	j.	j.	PROPN
eurjchem-405	358	17	org	org	PROPN
eurjchem-405	358	18	.	.	PUNCT
eurjchem-405	358	19	chem	chem	PROPN
eurjchem-405	358	20	.	.	PUNCT
eurjchem-405	359	1	1994	1994	NUM
eurjchem-405	359	2	,	,	PUNCT
eurjchem-405	359	3	59	59	NUM
eurjchem-405	359	4	,	,	PUNCT
eurjchem-405	359	5	6303‐	6303‐	NUM
eurjchem-405	359	6	6312	6312	NUM
eurjchem-405	359	7	.	.	PUNCT
eurjchem-405	360	1	[	[	X
eurjchem-405	360	2	49	49	NUM
eurjchem-405	360	3	]	]	PUNCT
eurjchem-405	360	4	.	.	PUNCT
eurjchem-405	361	1	d’souza	d’souza	PROPN
eurjchem-405	361	2	,	,	PUNCT
eurjchem-405	361	3	m.	m.	NOUN
eurjchem-405	361	4	j.	j.	PROPN
eurjchem-405	361	5	;	;	PUNCT
eurjchem-405	361	6	darrington	darrington	PROPN
eurjchem-405	361	7	,	,	PUNCT
eurjchem-405	361	8	a.	a.	NOUN
eurjchem-405	361	9	m.	m.	NOUN
eurjchem-405	361	10	;	;	PUNCT
eurjchem-405	361	11	kevill	kevill	NOUN
eurjchem-405	361	12	,	,	PUNCT
eurjchem-405	361	13	d.	d.	PROPN
eurjchem-405	361	14	n.	n.	PROPN
eurjchem-405	361	15	org	org	PROPN
eurjchem-405	361	16	.	.	PUNCT
eurjchem-405	362	1	chem	chem	PROPN
eurjchem-405	362	2	.	.	PUNCT
eurjchem-405	363	1	int	int	NOUN
eurjchem-405	363	2	.	.	PUNCT
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eurjchem-405	364	2	,	,	PUNCT
eurjchem-405	364	3	13050621‐13050629	13050621‐13050629	NUM
eurjchem-405	364	4	.	.	PUNCT
eurjchem-405	365	1	[	[	X
eurjchem-405	365	2	50	50	NUM
eurjchem-405	365	3	]	]	PUNCT
eurjchem-405	365	4	.	.	PUNCT
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eurjchem-405	366	2	,	,	PUNCT
eurjchem-405	366	3	d.	d.	PROPN
eurjchem-405	366	4	s.	s.	PROPN
eurjchem-405	366	5	;	;	PUNCT
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eurjchem-405	366	7	,	,	PUNCT
eurjchem-405	366	8	k.	k.	PROPN
eurjchem-405	366	9	p.	p.	PROPN
eurjchem-405	366	10	;	;	PUNCT
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eurjchem-405	366	12	,	,	PUNCT
eurjchem-405	366	13	s.	s.	PROPN
eurjchem-405	366	14	j.	j.	PROPN
eurjchem-405	366	15	phys	phys	PROPN
eurjchem-405	366	16	.	.	PUNCT
eurjchem-405	367	1	org	org	PROPN
eurjchem-405	367	2	.	.	PUNCT
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eurjchem-405	367	4	.	.	PUNCT
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eurjchem-405	368	2	,	,	PUNCT
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eurjchem-405	368	4	,	,	PUNCT
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eurjchem-405	368	6	.	.	PUNCT
eurjchem-405	369	1	[	[	X
eurjchem-405	369	2	51	51	NUM
eurjchem-405	369	3	]	]	PUNCT
eurjchem-405	369	4	.	.	PUNCT
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eurjchem-405	370	1	j.	j.	PROPN
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eurjchem-405	371	2	,	,	PUNCT
eurjchem-405	371	3	45	45	NUM
eurjchem-405	371	4	,	,	PUNCT
eurjchem-405	371	5	1619‐1629	1619‐1629	NUM
eurjchem-405	371	6	.	.	PUNCT
eurjchem-405	372	1	[	[	X
eurjchem-405	372	2	52	52	NUM
eurjchem-405	372	3	]	]	PUNCT
eurjchem-405	372	4	.	.	PUNCT
eurjchem-405	373	1	queen	queen	PROPN
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eurjchem-405	373	3	a.	a.	PROPN
eurjchem-405	373	4	;	;	PUNCT
eurjchem-405	373	5	nour	nour	PROPN
eurjchem-405	373	6	,	,	PUNCT
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eurjchem-405	373	9	;	;	PUNCT
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eurjchem-405	373	14	;	;	PUNCT
eurjchem-405	373	15	preston	preston	PROPN
eurjchem-405	373	16	,	,	PUNCT
eurjchem-405	373	17	k.	k.	PROPN
eurjchem-405	373	18	can	can	AUX
eurjchem-405	373	19	.	.	PUNCT
eurjchem-405	374	1	j.	j.	PROPN
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eurjchem-405	374	3	.	.	PUNCT
eurjchem-405	375	1	1970	1970	NUM
eurjchem-405	375	2	,	,	PUNCT
eurjchem-405	375	3	48	48	NUM
eurjchem-405	375	4	,	,	PUNCT
eurjchem-405	375	5	522‐527	522‐527	PROPN
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eurjchem-405	376	1	[	[	X
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eurjchem-405	376	3	]	]	PUNCT
eurjchem-405	376	4	.	.	PUNCT
eurjchem-405	377	1	mckinnon	mckinnon	PROPN
eurjchem-405	377	2	,	,	PUNCT
eurjchem-405	377	3	d.	d.	PROPN
eurjchem-405	377	4	m.	m.	PROPN
eurjchem-405	377	5	;	;	PUNCT
eurjchem-405	377	6	queen	queen	PROPN
eurjchem-405	377	7	,	,	PUNCT
eurjchem-405	377	8	a.	a.	NOUN
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eurjchem-405	377	10	.	.	PUNCT
eurjchem-405	378	1	j.	j.	PROPN
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eurjchem-405	378	3	.	.	PUNCT
eurjchem-405	379	1	1972	1972	NUM
eurjchem-405	379	2	,	,	PUNCT
eurjchem-405	379	3	50	50	NUM
eurjchem-405	379	4	,	,	PUNCT
eurjchem-405	379	5	1401‐1406	1401‐1406	NUM
eurjchem-405	379	6	.	.	PUNCT
eurjchem-405	380	1	[	[	X
eurjchem-405	380	2	54	54	NUM
eurjchem-405	380	3	]	]	PUNCT
eurjchem-405	380	4	.	.	PUNCT
eurjchem-405	381	1	kevill	kevill	PROPN
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eurjchem-405	385	2	,	,	PUNCT
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eurjchem-405	385	7	.	.	PUNCT
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eurjchem-405	386	2	55	55	NUM
eurjchem-405	386	3	]	]	PUNCT
eurjchem-405	386	4	.	.	PUNCT
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eurjchem-405	387	2	,	,	PUNCT
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eurjchem-405	387	5	;	;	PUNCT
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eurjchem-405	388	2	,	,	PUNCT
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eurjchem-405	388	4	,	,	PUNCT
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eurjchem-405	388	6	.	.	PUNCT
eurjchem-405	389	1	[	[	X
eurjchem-405	389	2	56	56	NUM
eurjchem-405	389	3	]	]	PUNCT
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eurjchem-405	390	8	z.	z.	PROPN
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eurjchem-405	390	10	;	;	PUNCT
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eurjchem-405	391	2	,	,	PUNCT
eurjchem-405	391	3	b.	b.	PROPN
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eurjchem-405	393	1	j.	j.	PROPN
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eurjchem-405	393	3	.	.	PUNCT
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eurjchem-405	394	2	,	,	PUNCT
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eurjchem-405	394	4	,	,	PUNCT
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eurjchem-405	394	6	.	.	PUNCT
eurjchem-405	395	1	[	[	X
eurjchem-405	395	2	57	57	NUM
eurjchem-405	395	3	]	]	PUNCT
eurjchem-405	395	4	.	.	PUNCT
eurjchem-405	396	1	olofson	olofson	PROPN
eurjchem-405	396	2	,	,	PUNCT
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eurjchem-405	396	4	a.	a.	PROPN
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eurjchem-405	396	10	.	.	PUNCT
eurjchem-405	397	1	1988	1988	NUM
eurjchem-405	397	2	,	,	PUNCT
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eurjchem-405	397	4	,	,	PUNCT
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eurjchem-405	397	6	.	.	PUNCT
eurjchem-405	398	1	[	[	X
eurjchem-405	398	2	58	58	NUM
eurjchem-405	398	3	]	]	PUNCT
eurjchem-405	398	4	.	.	PUNCT
eurjchem-405	399	1	gallou	gallou	PROPN
eurjchem-405	399	2	,	,	PUNCT
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eurjchem-405	399	4	;	;	PUNCT
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eurjchem-405	399	8	;	;	PUNCT
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eurjchem-405	399	22	.	.	PUNCT
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eurjchem-405	400	2	,	,	PUNCT
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eurjchem-405	400	4	,	,	PUNCT
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eurjchem-405	400	6	.	.	PUNCT
eurjchem-405	401	1	[	[	X
eurjchem-405	401	2	59	59	NUM
eurjchem-405	401	3	]	]	PUNCT
eurjchem-405	401	4	.	.	PUNCT
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eurjchem-405	402	2	,	,	PUNCT
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eurjchem-405	402	4	j.	j.	PROPN
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eurjchem-405	403	2	.	.	PUNCT
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eurjchem-405	404	2	,	,	PUNCT
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eurjchem-405	404	4	,	,	PUNCT
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eurjchem-405	404	6	.	.	PUNCT
eurjchem-405	405	1	[	[	X
eurjchem-405	405	2	60	60	NUM
eurjchem-405	405	3	]	]	PUNCT
eurjchem-405	405	4	.	.	PUNCT
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eurjchem-405	406	2	,	,	PUNCT
eurjchem-405	406	3	c.	c.	PROPN
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eurjchem-405	406	5	;	;	PUNCT
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eurjchem-405	406	12	,	,	PUNCT
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eurjchem-405	406	14	k.	k.	PROPN
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eurjchem-405	406	17	.	.	PUNCT
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eurjchem-405	406	19	.	.	PUNCT
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eurjchem-405	407	2	,	,	PUNCT
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eurjchem-405	407	4	,	,	PUNCT
eurjchem-405	407	5	483‐488	483‐488	NUM
eurjchem-405	407	6	.	.	PUNCT
eurjchem-405	408	1	[	[	X
eurjchem-405	408	2	61	61	NUM
eurjchem-405	408	3	]	]	PUNCT
eurjchem-405	408	4	.	.	PUNCT
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eurjchem-405	409	2	,	,	PUNCT
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eurjchem-405	409	4	;	;	PUNCT
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eurjchem-405	409	6	,	,	PUNCT
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eurjchem-405	409	8	;	;	PUNCT
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eurjchem-405	409	16	.	.	PUNCT
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eurjchem-405	410	2	,	,	PUNCT
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eurjchem-405	410	4	,	,	PUNCT
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eurjchem-405	410	6	.	.	PUNCT
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eurjchem-405	411	14	(	(	PUNCT
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eurjchem-405	412	3	]	]	PUNCT
eurjchem-405	412	4	.	.	PUNCT
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eurjchem-405	413	11	;	;	PUNCT
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eurjchem-405	413	17	;	;	PUNCT
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eurjchem-405	413	22	.	.	PUNCT
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eurjchem-405	414	2	.	.	PUNCT
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eurjchem-405	415	2	,	,	PUNCT
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eurjchem-405	415	4	,	,	PUNCT
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eurjchem-405	415	6	.	.	PUNCT
eurjchem-405	416	1	[	[	X
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eurjchem-405	416	3	]	]	PUNCT
eurjchem-405	416	4	.	.	PUNCT
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eurjchem-405	418	2	,	,	PUNCT
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eurjchem-405	418	4	,	,	PUNCT
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eurjchem-405	419	1	[	[	X
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eurjchem-405	419	3	]	]	PUNCT
eurjchem-405	419	4	.	.	PUNCT
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eurjchem-405	420	5	;	;	PUNCT
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eurjchem-405	423	4	.	.	PUNCT
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eurjchem-405	424	16	;	;	PUNCT
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eurjchem-405	424	20	;	;	PUNCT
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eurjchem-405	424	27	.	.	PUNCT
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eurjchem-405	425	2	,	,	PUNCT
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eurjchem-405	425	4	,	,	PUNCT
eurjchem-405	425	5	514‐519	514‐519	NUM
eurjchem-405	425	6	.	.	PUNCT
eurjchem-405	426	1	[	[	X
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eurjchem-405	426	3	]	]	PUNCT
eurjchem-405	426	4	.	.	PUNCT
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eurjchem-405	427	5	;	;	PUNCT
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eurjchem-405	427	25	.	.	PUNCT
eurjchem-405	428	1	chem	chem	PROPN
eurjchem-405	428	2	.	.	PUNCT
eurjchem-405	429	1	a.	a.	PROPN
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eurjchem-405	429	3	,	,	PUNCT
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eurjchem-405	430	1	[	[	X
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eurjchem-405	430	3	]	]	PUNCT
eurjchem-405	430	4	.	.	PUNCT
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eurjchem-405	431	21	,	,	PUNCT
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eurjchem-405	431	26	,	,	PUNCT
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eurjchem-405	432	2	,	,	PUNCT
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eurjchem-405	432	4	.	.	PUNCT
eurjchem-405	433	1	[	[	X
eurjchem-405	433	2	68	68	NUM
eurjchem-405	433	3	]	]	PUNCT
eurjchem-405	433	4	.	.	PUNCT
eurjchem-405	434	1	olofson	olofson	PROPN
eurjchem-405	434	2	,	,	PUNCT
eurjchem-405	434	3	r.	r.	PROPN
eurjchem-405	434	4	a.	a.	PROPN
eurjchem-405	434	5	;	;	PUNCT
eurjchem-405	434	6	bauman	bauman	PROPN
eurjchem-405	434	7	,	,	PUNCT
eurjchem-405	434	8	b.	b.	PROPN
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eurjchem-405	434	17	.	.	PUNCT
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eurjchem-405	435	2	,	,	PUNCT
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eurjchem-405	435	4	,	,	PUNCT
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eurjchem-405	435	6	.	.	PUNCT
eurjchem-405	436	1	[	[	X
eurjchem-405	436	2	69	69	NUM
eurjchem-405	436	3	]	]	PUNCT
eurjchem-405	436	4	.	.	PUNCT
eurjchem-405	437	1	zeggaf	zeggaf	PROPN
eurjchem-405	437	2	,	,	PUNCT
eurjchem-405	437	3	c.	c.	PROPN
eurjchem-405	437	4	;	;	PUNCT
eurjchem-405	437	5	poncet	poncet	PROPN
eurjchem-405	437	6	,	,	PUNCT
eurjchem-405	437	7	j.	j.	PROPN
eurjchem-405	437	8	;	;	PUNCT
eurjchem-405	437	9	jouin	jouin	PROPN
eurjchem-405	437	10	,	,	PUNCT
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eurjchem-405	437	12	;	;	PUNCT
eurjchem-405	437	13	dufour	dufour	PROPN
eurjchem-405	437	14	,	,	PUNCT
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eurjchem-405	437	19	,	,	PUNCT
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eurjchem-405	437	23	,	,	PUNCT
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eurjchem-405	437	25	,	,	PUNCT
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eurjchem-405	437	27	.	.	PUNCT
eurjchem-405	438	1	[	[	X
eurjchem-405	438	2	70	70	NUM
eurjchem-405	438	3	]	]	PUNCT
eurjchem-405	438	4	.	.	PUNCT
eurjchem-405	439	1	koh	koh	PROPN
eurjchem-405	439	2	,	,	PUNCT
eurjchem-405	439	3	h.	h.	PROPN
eurjchem-405	439	4	j.	j.	PROPN
eurjchem-405	439	5	;	;	PUNCT
eurjchem-405	439	6	kang	kang	PROPN
eurjchem-405	439	7	,	,	PUNCT
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eurjchem-405	439	9	j.	j.	PROPN
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eurjchem-405	439	11	.	.	PUNCT
eurjchem-405	440	1	korean	korean	ADJ
eurjchem-405	440	2	chem	chem	PROPN
eurjchem-405	440	3	.	.	PUNCT
eurjchem-405	441	1	soc	soc	PROPN
eurjchem-405	441	2	.	.	PUNCT
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eurjchem-405	442	2	,	,	PUNCT
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eurjchem-405	442	4	,	,	PUNCT
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eurjchem-405	442	6	.	.	PUNCT
eurjchem-405	443	1	[	[	X
eurjchem-405	443	2	71	71	NUM
eurjchem-405	443	3	]	]	SYM
eurjchem-405	443	4	.	.	PUNCT
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eurjchem-405	444	2	,	,	PUNCT
eurjchem-405	444	3	s.	s.	PROPN
eurjchem-405	444	4	h.	h.	PROPN
eurjchem-405	444	5	;	;	PUNCT
eurjchem-405	444	6	rhu	rhu	PROPN
eurjchem-405	444	7	,	,	PUNCT
eurjchem-405	444	8	c.	c.	PROPN
eurjchem-405	444	9	j.	j.	PROPN
eurjchem-405	444	10	;	;	PUNCT
eurjchem-405	444	11	kyong	kyong	PROPN
eurjchem-405	444	12	,	,	PUNCT
eurjchem-405	444	13	j.	j.	PROPN
eurjchem-405	444	14	b.	b.	PROPN
eurjchem-405	444	15	;	;	PUNCT
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eurjchem-405	444	17	,	,	PUNCT
eurjchem-405	444	18	d.	d.	PROPN
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eurjchem-405	444	20	;	;	PUNCT
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eurjchem-405	444	22	,	,	PUNCT
eurjchem-405	444	23	d.	d.	PROPN
eurjchem-405	444	24	n.	n.	PROPN
eurjchem-405	444	25	bull	bull	PROPN
eurjchem-405	444	26	.	.	PUNCT
eurjchem-405	445	1	korean	korean	ADJ
eurjchem-405	445	2	chem	chem	PROPN
eurjchem-405	445	3	.	.	PUNCT
eurjchem-405	446	1	soc	soc	PROPN
eurjchem-405	446	2	.	.	PUNCT
eurjchem-405	447	1	2007	2007	NUM
eurjchem-405	447	2	,	,	PUNCT
eurjchem-405	447	3	28	28	NUM
eurjchem-405	447	4	,	,	PUNCT
eurjchem-405	447	5	657‐661	657‐661	NUM
eurjchem-405	447	6	.	.	PUNCT
eurjchem-405	448	1	[	[	X
eurjchem-405	448	2	72	72	NUM
eurjchem-405	448	3	]	]	PUNCT
eurjchem-405	448	4	.	.	PUNCT
eurjchem-405	448	5	kevill	kevill	PROPN
eurjchem-405	448	6	,	,	PUNCT
eurjchem-405	448	7	d.	d.	PROPN
eurjchem-405	448	8	n.	n.	PROPN
eurjchem-405	448	9	;	;	PUNCT
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eurjchem-405	448	13	j.	j.	PROPN
eurjchem-405	448	14	j.	j.	PROPN
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eurjchem-405	448	16	.	.	PUNCT
eurjchem-405	448	17	org	org	PROPN
eurjchem-405	448	18	.	.	PUNCT
eurjchem-405	448	19	chem	chem	PROPN
eurjchem-405	448	20	.	.	PUNCT
eurjchem-405	449	1	2002	2002	NUM
eurjchem-405	449	2	,	,	PUNCT
eurjchem-405	449	3	15	15	NUM
eurjchem-405	449	4	,	,	PUNCT
eurjchem-405	449	5	881‐888	881‐888	NUM
eurjchem-405	449	6	.	.	PUNCT
eurjchem-405	450	1	[	[	X
eurjchem-405	450	2	73	73	NUM
eurjchem-405	450	3	]	]	PUNCT
eurjchem-405	450	4	.	.	PUNCT
eurjchem-405	451	1	d’souza	d’souza	PROPN
eurjchem-405	451	2	,	,	PUNCT
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eurjchem-405	451	4	j.	j.	PROPN
eurjchem-405	451	5	;	;	PUNCT
eurjchem-405	451	6	kevill	kevill	PROPN
eurjchem-405	451	7	,	,	PUNCT
eurjchem-405	451	8	d.	d.	PROPN
eurjchem-405	451	9	n.	n.	PROPN
eurjchem-405	451	10	;	;	PUNCT
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eurjchem-405	451	12	,	,	PUNCT
eurjchem-405	451	13	t.	t.	PROPN
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eurjchem-405	451	15	;	;	PUNCT
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eurjchem-405	451	17	,	,	PUNCT
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eurjchem-405	451	19	c.	c.	PROPN
eurjchem-405	451	20	j.	j.	PROPN
eurjchem-405	451	21	org	org	PROPN
eurjchem-405	451	22	.	.	PUNCT
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eurjchem-405	451	24	.	.	PUNCT
eurjchem-405	452	1	1995	1995	NUM
eurjchem-405	452	2	,	,	PUNCT
eurjchem-405	452	3	60	60	NUM
eurjchem-405	452	4	,	,	PUNCT
eurjchem-405	452	5	1632‐1637	1632‐1637	NUM
eurjchem-405	452	6	.	.	PUNCT
eurjchem-405	453	1	[	[	X
eurjchem-405	453	2	74	74	NUM
eurjchem-405	453	3	]	]	PUNCT
eurjchem-405	453	4	.	.	PUNCT
eurjchem-405	454	1	kaspi	kaspi	PROPN
eurjchem-405	454	2	,	,	PUNCT
eurjchem-405	454	3	j.	j.	PROPN
eurjchem-405	454	4	;	;	PUNCT
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eurjchem-405	454	6	,	,	PUNCT
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eurjchem-405	454	9	lett	lett	PROPN
eurjchem-405	454	10	.	.	PUNCT
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eurjchem-405	454	12	,	,	PUNCT
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eurjchem-405	454	14	.	.	PUNCT
eurjchem-405	455	1	[	[	X
eurjchem-405	455	2	75	75	NUM
eurjchem-405	455	3	]	]	PUNCT
eurjchem-405	455	4	.	.	PUNCT
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eurjchem-405	456	2	,	,	PUNCT
eurjchem-405	456	3	b.d	b.d	PROPN
eurjchem-405	456	4	.	.	PROPN
eurjchem-405	456	5	;	;	PUNCT
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eurjchem-405	456	7	,	,	PUNCT
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eurjchem-405	456	9	p.	p.	PROPN
eurjchem-405	456	10	j.	j.	PROPN
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eurjchem-405	456	12	.	.	PUNCT
eurjchem-405	457	1	chem	chem	NOUN
eurjchem-405	457	2	.	.	PUNCT
eurjchem-405	458	1	soc	soc	PROPN
eurjchem-405	458	2	.	.	PUNCT
eurjchem-405	459	1	1989	1989	NUM
eurjchem-405	459	2	,	,	PUNCT
eurjchem-405	459	3	111	111	NUM
eurjchem-405	459	4	,	,	PUNCT
eurjchem-405	459	5	8470‐8479	8470‐8479	NUM
eurjchem-405	459	6	.	.	PUNCT
eurjchem-405	460	1	[	[	X
eurjchem-405	460	2	76	76	NUM
eurjchem-405	460	3	]	]	PUNCT
eurjchem-405	460	4	.	.	PUNCT
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eurjchem-405	461	2	,	,	PUNCT
eurjchem-405	461	3	b.	b.	PROPN
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eurjchem-405	461	5	;	;	PUNCT
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eurjchem-405	461	7	,	,	PUNCT
eurjchem-405	461	8	w.	w.	PROPN
eurjchem-405	461	9	p.	p.	PROPN
eurjchem-405	461	10	j.	j.	PROPN
eurjchem-405	461	11	am	am	PROPN
eurjchem-405	461	12	.	.	PUNCT
eurjchem-405	462	1	chem	chem	NOUN
eurjchem-405	462	2	.	.	PUNCT
eurjchem-405	463	1	soc	soc	PROPN
eurjchem-405	463	2	.	.	PUNCT
eurjchem-405	464	1	1987	1987	NUM
eurjchem-405	464	2	,	,	PUNCT
eurjchem-405	464	3	109	109	NUM
eurjchem-405	464	4	,	,	PUNCT
eurjchem-405	464	5	3160‐3161	3160‐3161	NUM
eurjchem-405	464	6	.	.	PUNCT
eurjchem-405	465	1	[	[	X
eurjchem-405	465	2	77	77	NUM
eurjchem-405	465	3	]	]	PUNCT
eurjchem-405	465	4	.	.	PUNCT
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eurjchem-405	466	2	,	,	PUNCT
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eurjchem-405	466	4	;	;	PUNCT
eurjchem-405	466	5	hariharan	hariharan	PROPN
eurjchem-405	466	6	,	,	PUNCT
eurjchem-405	466	7	p.	p.	PROPN
eurjchem-405	466	8	c.	c.	PROPN
eurjchem-405	466	9	;	;	PUNCT
eurjchem-405	466	10	pople	pople	PROPN
eurjchem-405	466	11	,	,	PUNCT
eurjchem-405	466	12	j.	j.	PROPN
eurjchem-405	466	13	a.	a.	PROPN
eurjchem-405	466	14	;	;	PUNCT
eurjchem-405	466	15	schleyer	schleyer	PROPN
eurjchem-405	466	16	,	,	PUNCT
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eurjchem-405	466	20	j.	j.	PROPN
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eurjchem-405	466	22	.	.	PUNCT
eurjchem-405	467	1	chem	chem	PROPN
eurjchem-405	467	2	.	.	PUNCT
eurjchem-405	468	1	soc	soc	PROPN
eurjchem-405	468	2	.	.	PUNCT
eurjchem-405	469	1	1973	1973	NUM
eurjchem-405	469	2	,	,	PUNCT
eurjchem-405	469	3	95	95	NUM
eurjchem-405	469	4	,	,	PUNCT
eurjchem-405	469	5	6531‐6544	6531‐6544	NUM
eurjchem-405	469	6	.	.	PUNCT
eurjchem-405	470	1	[	[	X
eurjchem-405	470	2	78	78	NUM
eurjchem-405	470	3	]	]	PUNCT
eurjchem-405	470	4	.	.	PUNCT
eurjchem-405	471	1	imhoff	imhoff	PROPN
eurjchem-405	471	2	,	,	PUNCT
eurjchem-405	471	3	m.	m.	NOUN
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eurjchem-405	471	5	;	;	PUNCT
eurjchem-405	471	6	summerville	summerville	PROPN
eurjchem-405	471	7	,	,	PUNCT
eurjchem-405	471	8	r.	r.	PROPN
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eurjchem-405	471	10	;	;	PUNCT
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eurjchem-405	471	12	,	,	PUNCT
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eurjchem-405	471	16	;	;	PUNCT
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eurjchem-405	472	2	,	,	PUNCT
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eurjchem-405	472	5	;	;	PUNCT
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eurjchem-405	472	9	;	;	PUNCT
eurjchem-405	472	10	dueber	dueber	PROPN
eurjchem-405	472	11	,	,	PUNCT
eurjchem-405	472	12	t.	t.	PROPN
eurjchem-405	472	13	e.	e.	PROPN
eurjchem-405	472	14	;	;	PUNCT
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eurjchem-405	472	16	,	,	PUNCT
eurjchem-405	472	17	p.	p.	PROPN
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eurjchem-405	472	19	j.	j.	PROPN
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eurjchem-405	472	21	.	.	PUNCT
eurjchem-405	473	1	chem	chem	PROPN
eurjchem-405	473	2	.	.	PUNCT
eurjchem-405	474	1	soc	soc	PROPN
eurjchem-405	474	2	.	.	PUNCT
eurjchem-405	475	1	1970	1970	NUM
eurjchem-405	475	2	,	,	PUNCT
eurjchem-405	475	3	92	92	NUM
eurjchem-405	475	4	,	,	PUNCT
eurjchem-405	475	5	3802‐	3802‐	NUM
eurjchem-405	475	6	3804	3804	NUM
eurjchem-405	475	7	.	.	PUNCT
eurjchem-405	476	1	[	[	X
eurjchem-405	476	2	79	79	NUM
eurjchem-405	476	3	]	]	PUNCT
eurjchem-405	476	4	.	.	PUNCT
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eurjchem-405	477	2	m.	m.	PROPN
eurjchem-405	477	3	acc	acc	PROPN
eurjchem-405	477	4	.	.	PROPN
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eurjchem-405	477	6	.	.	PUNCT
eurjchem-405	478	1	res	re	NOUN
eurjchem-405	478	2	.	.	PROPN
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eurjchem-405	478	4	,	,	PUNCT
eurjchem-405	478	5	3	3	NUM
eurjchem-405	478	6	,	,	PUNCT
eurjchem-405	478	7	209‐216	209‐216	NUM
eurjchem-405	478	8	.	.	PUNCT