id	sid	tid	token	lemma	pos
eurjchem-411	1	1	untitled	untitle	VERB
eurjchem-411	1	2	european	european	PROPN
eurjchem-411	1	3	journal	journal	PROPN
eurjchem-411	1	4	of	of	ADP
eurjchem-411	1	5	chemistry	chemistry	NOUN
eurjchem-411	1	6	2	2	NUM
eurjchem-411	1	7	(	(	PUNCT
eurjchem-411	1	8	2	2	NUM
eurjchem-411	1	9	)	)	PUNCT
eurjchem-411	1	10	(	(	PUNCT
eurjchem-411	1	11	2011	2011	NUM
eurjchem-411	1	12	)	)	PUNCT
eurjchem-411	1	13	214‐222	214‐222	NUM
eurjchem-411	1	14	european	european	ADJ
eurjchem-411	1	15	journal	journal	NOUN
eurjchem-411	1	16	of	of	ADP
eurjchem-411	1	17	chemistry	chemistry	NOUN
eurjchem-411	1	18	issn	issn	PROPN
eurjchem-411	1	19	2153‐2249	2153‐2249	PROPN
eurjchem-411	1	20	(	(	PUNCT
eurjchem-411	1	21	print	print	NOUN
eurjchem-411	1	22	)	)	PUNCT
eurjchem-411	1	23	/	/	SYM
eurjchem-411	1	24	issn	issn	PROPN
eurjchem-411	1	25	2153‐2257	2153‐2257	NUM
eurjchem-411	1	26	(	(	PUNCT
eurjchem-411	1	27	online	online	ADJ
eurjchem-411	1	28	)	)	PUNCT
eurjchem-411	1	29			NOUN
eurjchem-411	1	30	2011	2011	NUM
eurjchem-411	1	31	eurjchem	eurjchem	PROPN
eurjchem-411	1	32	doi:10.5155	doi:10.5155	PROPN
eurjchem-411	1	33	/	/	SYM
eurjchem-411	1	34	eurjchem.2.2.214‐222.411	eurjchem.2.2.214‐222.411	ADJ
eurjchem-411	1	35	european	european	ADJ
eurjchem-411	1	36	journal	journal	PROPN
eurjchem-411	1	37	of	of	ADP
eurjchem-411	1	38	chemistry	chemistry	PROPN
eurjchem-411	1	39	journal	journal	PROPN
eurjchem-411	1	40	homepage	homepage	NOUN
eurjchem-411	1	41	:	:	PUNCT
eurjchem-411	1	42	www.eurjchem.com	www.eurjchem.com	X
eurjchem-411	1	43	regioselective	regioselective	ADJ
eurjchem-411	1	44	synthesis	synthesis	NOUN
eurjchem-411	1	45	and	and	CCONJ
eurjchem-411	1	46	biological	biological	ADJ
eurjchem-411	1	47	evaluation	evaluation	NOUN
eurjchem-411	1	48	of	of	ADP
eurjchem-411	1	49	some	some	DET
eurjchem-411	1	50	novel	novel	NOUN
eurjchem-411	1	51	thiophene‐	thiophene‐	NOUN
eurjchem-411	1	52	containing	contain	VERB
eurjchem-411	1	53	heterocyclic	heterocyclic	ADJ
eurjchem-411	1	54	scaffolds	scaffold	NOUN
eurjchem-411	1	55	as	as	ADP
eurjchem-411	1	56	potential	potential	ADJ
eurjchem-411	1	57	chemotherapeutic	chemotherapeutic	ADJ
eurjchem-411	1	58	agents	agent	NOUN
eurjchem-411	1	59	hatem	hatem	PROPN
eurjchem-411	1	60	moustafa	moustafa	PROPN
eurjchem-411	1	61	gabera	gabera	PROPN
eurjchem-411	1	62	,	,	PUNCT
eurjchem-411	1	63	*	*	PUNCT
eurjchem-411	1	64	and	and	CCONJ
eurjchem-411	1	65	mark	mark	PROPN
eurjchem-411	1	66	christopher	christopher	PROPN
eurjchem-411	1	67	bagleyb	bagleyb	PROPN
eurjchem-411	1	68	a	a	DET
eurjchem-411	1	69	national	national	ADJ
eurjchem-411	1	70	organization	organization	NOUN
eurjchem-411	1	71	for	for	ADP
eurjchem-411	1	72	drug	drug	NOUN
eurjchem-411	1	73	control	control	NOUN
eurjchem-411	1	74	and	and	CCONJ
eurjchem-411	1	75	research	research	NOUN
eurjchem-411	1	76	(	(	PUNCT
eurjchem-411	1	77	nodcar	nodcar	NOUN
eurjchem-411	1	78	)	)	PUNCT
eurjchem-411	1	79	,	,	PUNCT
eurjchem-411	1	80	cairo	cairo	PROPN
eurjchem-411	1	81	12553	12553	NUM
eurjchem-411	1	82	,	,	PUNCT
eurjchem-411	1	83	egypt	egypt	PROPN
eurjchem-411	1	84	b	b	PROPN
eurjchem-411	1	85	school	school	NOUN
eurjchem-411	1	86	of	of	ADP
eurjchem-411	1	87	chemistry	chemistry	NOUN
eurjchem-411	1	88	,	,	PUNCT
eurjchem-411	1	89	cardiff	cardiff	NOUN
eurjchem-411	1	90	university	university	NOUN
eurjchem-411	1	91	,	,	PUNCT
eurjchem-411	1	92	cardiff	cardiff	NOUN
eurjchem-411	1	93	,	,	PUNCT
eurjchem-411	1	94	cf10	cf10	PROPN
eurjchem-411	1	95	3at	3at	NOUN
eurjchem-411	1	96	,	,	PUNCT
eurjchem-411	1	97	u.k	u.k	PROPN
eurjchem-411	1	98	.	.	PROPN
eurjchem-411	1	99	*	*	PUNCT
eurjchem-411	1	100	corresponding	correspond	VERB
eurjchem-411	1	101	author	author	NOUN
eurjchem-411	1	102	at	at	ADP
eurjchem-411	1	103	:	:	PUNCT
eurjchem-411	1	104	national	national	ADJ
eurjchem-411	1	105	organization	organization	NOUN
eurjchem-411	1	106	for	for	ADP
eurjchem-411	1	107	drug	drug	NOUN
eurjchem-411	1	108	control	control	NOUN
eurjchem-411	1	109	and	and	CCONJ
eurjchem-411	1	110	research	research	NOUN
eurjchem-411	1	111	(	(	PUNCT
eurjchem-411	1	112	nodcar	nodcar	NOUN
eurjchem-411	1	113	)	)	PUNCT
eurjchem-411	1	114	,	,	PUNCT
eurjchem-411	1	115	cairo	cairo	PROPN
eurjchem-411	1	116	12553	12553	NUM
eurjchem-411	1	117	,	,	PUNCT
eurjchem-411	1	118	egypt	egypt	PROPN
eurjchem-411	1	119	.	.	PUNCT
eurjchem-411	2	1	tel	tel	PROPN
eurjchem-411	2	2	.	.	PUNCT
eurjchem-411	2	3	:	:	PUNCT
eurjchem-411	3	1	+2.016.4703765	+2.016.4703765	ADV
eurjchem-411	3	2	;	;	PUNCT
eurjchem-411	3	3	fax	fax	NOUN
eurjchem-411	3	4	:	:	PUNCT
eurjchem-411	3	5	+2.02.35728843	+2.02.35728843	PROPN
eurjchem-411	3	6	.	.	PUNCT
eurjchem-411	3	7	e‐mail	e‐mail	PUNCT
eurjchem-411	3	8	address	address	NOUN
eurjchem-411	3	9	:	:	PUNCT
eurjchem-411	3	10	hatem.gaber@yahoo.com	hatem.gaber@yahoo.com	X
eurjchem-411	3	11	(	(	PUNCT
eurjchem-411	3	12	h.	h.	PROPN
eurjchem-411	3	13	gaber	gaber	PROPN
eurjchem-411	3	14	)	)	PUNCT
eurjchem-411	3	15	.	.	PUNCT
eurjchem-411	4	1	article	article	NOUN
eurjchem-411	4	2	information	information	PROPN
eurjchem-411	4	3	abstract	abstract	ADV
eurjchem-411	4	4	received	receive	VERB
eurjchem-411	4	5	:	:	PUNCT
eurjchem-411	4	6	24	24	NUM
eurjchem-411	4	7	february	february	NOUN
eurjchem-411	4	8	2011	2011	NUM
eurjchem-411	4	9	received	receive	VERB
eurjchem-411	4	10	in	in	ADP
eurjchem-411	4	11	revised	revise	VERB
eurjchem-411	4	12	form	form	NOUN
eurjchem-411	4	13	:	:	PUNCT
eurjchem-411	4	14	29	29	NUM
eurjchem-411	4	15	march	march	NOUN
eurjchem-411	4	16	2011	2011	NUM
eurjchem-411	4	17	accepted	accept	VERB
eurjchem-411	4	18	:	:	PUNCT
eurjchem-411	4	19	29	29	NUM
eurjchem-411	4	20	march	march	PROPN
eurjchem-411	4	21	2011	2011	NUM
eurjchem-411	4	22	online	online	NOUN
eurjchem-411	4	23	:	:	PUNCT
eurjchem-411	4	24	30	30	NUM
eurjchem-411	4	25	june	june	PROPN
eurjchem-411	4	26	2011	2011	NUM
eurjchem-411	4	27	keywords	keyword	NOUN
eurjchem-411	4	28	in	in	ADP
eurjchem-411	4	29	the	the	DET
eurjchem-411	4	30	reaction	reaction	NOUN
eurjchem-411	4	31	of	of	ADP
eurjchem-411	4	32	2‐amino‐3‐carbethoxythiophene	2‐amino‐3‐carbethoxythiophene	NUM
eurjchem-411	4	33	derivative	derivative	ADJ
eurjchem-411	4	34	2b	2b	NOUN
eurjchem-411	4	35	with	with	ADP
eurjchem-411	4	36	hydrazine	hydrazine	NOUN
eurjchem-411	4	37	hydrate	hydrate	NOUN
eurjchem-411	4	38	the	the	DET
eurjchem-411	4	39	respective	respective	ADJ
eurjchem-411	4	40	aminocarbohydrazide	aminocarbohydrazide	NOUN
eurjchem-411	4	41	3	3	NUM
eurjchem-411	4	42	was	be	AUX
eurjchem-411	4	43	isolated	isolate	VERB
eurjchem-411	4	44	.	.	PUNCT
eurjchem-411	5	1	treatment	treatment	NOUN
eurjchem-411	5	2	of	of	ADP
eurjchem-411	5	3	the	the	DET
eurjchem-411	5	4	latter	latter	ADJ
eurjchem-411	5	5	product	product	NOUN
eurjchem-411	5	6	with	with	ADP
eurjchem-411	5	7	carbon	carbon	NOUN
eurjchem-411	5	8	disulfide	disulfide	NOUN
eurjchem-411	5	9	in	in	ADP
eurjchem-411	5	10	alkaline	alkaline	NOUN
eurjchem-411	5	11	medium	medium	NOUN
eurjchem-411	5	12	caused	cause	VERB
eurjchem-411	5	13	a	a	DET
eurjchem-411	5	14	heterocyclization	heterocyclization	NOUN
eurjchem-411	5	15	to	to	PART
eurjchem-411	5	16	give	give	VERB
eurjchem-411	5	17	1,3,4‐oxadiazole‐2‐thione	1,3,4‐oxadiazole‐2‐thione	NUM
eurjchem-411	5	18	5	5	NUM
eurjchem-411	5	19	rather	rather	ADV
eurjchem-411	5	20	than	than	ADP
eurjchem-411	5	21	3‐amino‐2‐thioxothieno[2,3‐d]pyrimidin‐4‐one	3‐amino‐2‐thioxothieno[2,3‐d]pyrimidin‐4‐one	NUM
eurjchem-411	5	22	4	4	NUM
eurjchem-411	5	23	,	,	PUNCT
eurjchem-411	5	24	which	which	PRON
eurjchem-411	5	25	could	could	AUX
eurjchem-411	5	26	be	be	AUX
eurjchem-411	5	27	obtained	obtain	VERB
eurjchem-411	5	28	on	on	ADP
eurjchem-411	5	29	treatment	treatment	NOUN
eurjchem-411	5	30	of	of	ADP
eurjchem-411	5	31	carbohydrazide	carbohydrazide	NOUN
eurjchem-411	5	32	3	3	NUM
eurjchem-411	5	33	with	with	ADP
eurjchem-411	5	34	thiourea	thiourea	NOUN
eurjchem-411	5	35	.	.	PUNCT
eurjchem-411	6	1	the	the	DET
eurjchem-411	6	2	structure	structure	NOUN
eurjchem-411	6	3	of	of	ADP
eurjchem-411	6	4	products	product	NOUN
eurjchem-411	6	5	4	4	NUM
eurjchem-411	6	6	and	and	CCONJ
eurjchem-411	6	7	5	5	NUM
eurjchem-411	6	8	was	be	AUX
eurjchem-411	6	9	proved	prove	VERB
eurjchem-411	6	10	by	by	ADP
eurjchem-411	6	11	spectroscopic	spectroscopic	ADJ
eurjchem-411	6	12	methods	method	NOUN
eurjchem-411	6	13	and	and	CCONJ
eurjchem-411	6	14	chemical	chemical	NOUN
eurjchem-411	6	15	transformations	transformation	NOUN
eurjchem-411	6	16	.	.	PUNCT
eurjchem-411	7	1	derivatization	derivatization	NOUN
eurjchem-411	7	2	led	lead	VERB
eurjchem-411	7	3	to	to	ADP
eurjchem-411	7	4	two	two	NUM
eurjchem-411	7	5	novel	novel	ADJ
eurjchem-411	7	6	series	series	NOUN
eurjchem-411	7	7	of	of	ADP
eurjchem-411	7	8	condensed	condensed	ADJ
eurjchem-411	7	9	and	and	CCONJ
eurjchem-411	7	10	uncondensed	uncondensed	ADJ
eurjchem-411	7	11	thiophenes	thiophene	NOUN
eurjchem-411	7	12	,	,	PUNCT
eurjchem-411	7	13	which	which	PRON
eurjchem-411	7	14	were	be	AUX
eurjchem-411	7	15	of	of	ADP
eurjchem-411	7	16	significant	significant	ADJ
eurjchem-411	7	17	interest	interest	NOUN
eurjchem-411	7	18	for	for	ADP
eurjchem-411	7	19	biological	biological	ADJ
eurjchem-411	7	20	study	study	NOUN
eurjchem-411	7	21	.	.	PUNCT
eurjchem-411	8	1	since	since	SCONJ
eurjchem-411	8	2	compound	compound	NOUN
eurjchem-411	8	3	4	4	NUM
eurjchem-411	8	4	contains	contain	VERB
eurjchem-411	8	5	two	two	NUM
eurjchem-411	8	6	adjacent	adjacent	ADJ
eurjchem-411	8	7	reactive	reactive	ADJ
eurjchem-411	8	8	functional	functional	ADJ
eurjchem-411	8	9	groups	group	NOUN
eurjchem-411	8	10	,	,	PUNCT
eurjchem-411	8	11	it	it	PRON
eurjchem-411	8	12	reacted	react	VERB
eurjchem-411	8	13	readily	readily	ADV
eurjchem-411	8	14	with	with	ADP
eurjchem-411	8	15	different	different	ADJ
eurjchem-411	8	16	electrophilic	electrophilic	ADJ
eurjchem-411	8	17	reagents	reagent	NOUN
eurjchem-411	8	18	to	to	PART
eurjchem-411	8	19	provide	provide	VERB
eurjchem-411	8	20	a	a	DET
eurjchem-411	8	21	series	series	NOUN
eurjchem-411	8	22	of	of	ADP
eurjchem-411	8	23	thieno[2,3‐	thieno[2,3‐	PROPN
eurjchem-411	8	24	d]pyrimidin‐4‐one	d]pyrimidin‐4‐one	NOUN
eurjchem-411	8	25	derivatives	derivative	NOUN
eurjchem-411	8	26	with	with	ADP
eurjchem-411	8	27	annelated	annelate	VERB
eurjchem-411	8	28	bridgehead	bridgehead	NOUN
eurjchem-411	8	29	nitrogen	nitrogen	NOUN
eurjchem-411	8	30	heterocycles	heterocycle	NOUN
eurjchem-411	8	31	8‐11	8‐11	NUM
eurjchem-411	8	32	,	,	PUNCT
eurjchem-411	8	33	whereas	whereas	SCONJ
eurjchem-411	8	34	a	a	DET
eurjchem-411	8	35	second	second	ADJ
eurjchem-411	8	36	series	series	NOUN
eurjchem-411	8	37	of	of	ADP
eurjchem-411	8	38	3‐heteroaryl‐substituted	3‐heteroaryl‐substitute	VERB
eurjchem-411	8	39	thiophenes	thiophene	NOUN
eurjchem-411	8	40	13‐17	13‐17	NUM
eurjchem-411	8	41	was	be	AUX
eurjchem-411	8	42	obtained	obtain	VERB
eurjchem-411	8	43	by	by	ADP
eurjchem-411	8	44	thioamide	thioamide	ADJ
eurjchem-411	8	45	functionalization	functionalization	NOUN
eurjchem-411	8	46	in	in	ADP
eurjchem-411	8	47	1,3,4‐oxadiazole	1,3,4‐oxadiazole	NUM
eurjchem-411	8	48	derivative	derivative	ADJ
eurjchem-411	8	49	5	5	NUM
eurjchem-411	8	50	using	use	VERB
eurjchem-411	8	51	various	various	ADJ
eurjchem-411	8	52	chemical	chemical	ADJ
eurjchem-411	8	53	reagents	reagent	NOUN
eurjchem-411	8	54	.	.	PUNCT
eurjchem-411	9	1	the	the	DET
eurjchem-411	9	2	new	new	ADJ
eurjchem-411	9	3	thiophene‐based	thiophene‐base	VERB
eurjchem-411	9	4	derivatives	derivative	NOUN
eurjchem-411	9	5	were	be	AUX
eurjchem-411	9	6	evaluated	evaluate	VERB
eurjchem-411	9	7	for	for	ADP
eurjchem-411	9	8	their	their	PRON
eurjchem-411	9	9	preliminary	preliminary	ADJ
eurjchem-411	9	10	antimicrobial	antimicrobial	ADJ
eurjchem-411	9	11	activity	activity	NOUN
eurjchem-411	9	12	against	against	ADP
eurjchem-411	9	13	a	a	DET
eurjchem-411	9	14	representative	representative	ADJ
eurjchem-411	9	15	panel	panel	NOUN
eurjchem-411	9	16	of	of	ADP
eurjchem-411	9	17	gram‐positive	gram‐positive	ADJ
eurjchem-411	9	18	and	and	CCONJ
eurjchem-411	9	19	gram‐negative	gram‐negative	ADJ
eurjchem-411	9	20	bacteria	bacteria	NOUN
eurjchem-411	9	21	as	as	ADV
eurjchem-411	9	22	well	well	ADV
eurjchem-411	9	23	as	as	ADP
eurjchem-411	9	24	fungi	fungus	NOUN
eurjchem-411	9	25	strains	strain	NOUN
eurjchem-411	9	26	.	.	PUNCT
eurjchem-411	10	1	the	the	DET
eurjchem-411	10	2	compounds	compound	NOUN
eurjchem-411	10	3	tested	test	VERB
eurjchem-411	10	4	displayed	display	VERB
eurjchem-411	10	5	different	different	ADJ
eurjchem-411	10	6	levels	level	NOUN
eurjchem-411	10	7	of	of	ADP
eurjchem-411	10	8	inhibitory	inhibitory	ADJ
eurjchem-411	10	9	effects	effect	NOUN
eurjchem-411	10	10	,	,	PUNCT
eurjchem-411	10	11	with	with	ADP
eurjchem-411	10	12	the	the	DET
eurjchem-411	10	13	assays	assay	NOUN
eurjchem-411	10	14	carried	carry	VERB
eurjchem-411	10	15	out	out	ADP
eurjchem-411	10	16	on	on	ADP
eurjchem-411	10	17	two	two	NUM
eurjchem-411	10	18	pathogenic	pathogenic	ADJ
eurjchem-411	10	19	bacteria	bacteria	NOUN
eurjchem-411	10	20	and	and	CCONJ
eurjchem-411	10	21	two	two	NUM
eurjchem-411	10	22	pathogenic	pathogenic	ADJ
eurjchem-411	10	23	fungi	fungus	NOUN
eurjchem-411	10	24	.	.	PUNCT
eurjchem-411	11	1	of	of	ADP
eurjchem-411	11	2	these	these	DET
eurjchem-411	11	3	compounds	compound	NOUN
eurjchem-411	11	4	,	,	PUNCT
eurjchem-411	11	5	the	the	DET
eurjchem-411	11	6	monocyclic	monocyclic	PROPN
eurjchem-411	11	7	aminothiophene	aminothiophene	NOUN
eurjchem-411	11	8	derivative	derivative	NOUN
eurjchem-411	11	9	15	15	NUM
eurjchem-411	11	10	showed	show	VERB
eurjchem-411	11	11	the	the	DET
eurjchem-411	11	12	highest	high	ADJ
eurjchem-411	11	13	effect	effect	NOUN
eurjchem-411	11	14	on	on	ADP
eurjchem-411	11	15	pathogenic	pathogenic	ADJ
eurjchem-411	11	16	bacteria	bacteria	NOUN
eurjchem-411	11	17	,	,	PUNCT
eurjchem-411	11	18	while	while	SCONJ
eurjchem-411	11	19	the	the	DET
eurjchem-411	11	20	tricyclic	tricyclic	NOUN
eurjchem-411	11	21	condensed	condense	VERB
eurjchem-411	11	22	thiophene	thiophene	NOUN
eurjchem-411	11	23	derivative	derivative	ADJ
eurjchem-411	11	24	8	8	NUM
eurjchem-411	11	25	was	be	AUX
eurjchem-411	11	26	observed	observe	VERB
eurjchem-411	11	27	to	to	PART
eurjchem-411	11	28	have	have	VERB
eurjchem-411	11	29	the	the	DET
eurjchem-411	11	30	same	same	ADJ
eurjchem-411	11	31	inhibitory	inhibitory	ADJ
eurjchem-411	11	32	effect	effect	NOUN
eurjchem-411	11	33	against	against	ADP
eurjchem-411	11	34	pathogenic	pathogenic	ADJ
eurjchem-411	11	35	mould	mould	NOUN
eurjchem-411	11	36	(	(	PUNCT
eurjchem-411	11	37	aspergillus	aspergillus	NOUN
eurjchem-411	11	38	flavus	flavus	NOUN
eurjchem-411	11	39	)	)	PUNCT
eurjchem-411	11	40	as	as	ADP
eurjchem-411	11	41	the	the	DET
eurjchem-411	11	42	reference	reference	NOUN
eurjchem-411	11	43	drug	drug	NOUN
eurjchem-411	11	44	amphotericin	amphotericin	ADP
eurjchem-411	11	45	b.	b.	NOUN
eurjchem-411	11	46	for	for	ADP
eurjchem-411	11	47	those	those	DET
eurjchem-411	11	48	derivatives	derivative	NOUN
eurjchem-411	11	49	belonging	belong	VERB
eurjchem-411	11	50	to	to	ADP
eurjchem-411	11	51	first	first	ADJ
eurjchem-411	11	52	series	series	NOUN
eurjchem-411	11	53	of	of	ADP
eurjchem-411	11	54	condensed	condense	VERB
eurjchem-411	11	55	thiophenes	thiophene	NOUN
eurjchem-411	11	56	with	with	ADP
eurjchem-411	11	57	annelated	annelated	ADJ
eurjchem-411	11	58	bridgehead	bridgehead	ADJ
eurjchem-411	11	59	nitrogen	nitrogen	NOUN
eurjchem-411	11	60	heterocycles	heterocycle	NOUN
eurjchem-411	11	61	,	,	PUNCT
eurjchem-411	11	62	it	it	PRON
eurjchem-411	11	63	has	have	AUX
eurjchem-411	11	64	been	be	AUX
eurjchem-411	11	65	observed	observe	VERB
eurjchem-411	11	66	that	that	SCONJ
eurjchem-411	11	67	the	the	DET
eurjchem-411	11	68	antibacterial	antibacterial	ADJ
eurjchem-411	11	69	effect	effect	NOUN
eurjchem-411	11	70	was	be	AUX
eurjchem-411	11	71	in	in	ADP
eurjchem-411	11	72	general	general	ADJ
eurjchem-411	11	73	found	find	VERB
eurjchem-411	11	74	to	to	PART
eurjchem-411	11	75	be	be	AUX
eurjchem-411	11	76	significantly	significantly	ADV
eurjchem-411	11	77	higher	high	ADJ
eurjchem-411	11	78	than	than	ADP
eurjchem-411	11	79	the	the	DET
eurjchem-411	11	80	corresponding	corresponding	ADJ
eurjchem-411	11	81	uncondensed	uncondensed	ADJ
eurjchem-411	11	82	analogues	analogue	NOUN
eurjchem-411	11	83	.	.	PUNCT
eurjchem-411	12	1	although	although	SCONJ
eurjchem-411	12	2	most	most	ADJ
eurjchem-411	12	3	of	of	ADP
eurjchem-411	12	4	the	the	DET
eurjchem-411	12	5	condensed	condensed	ADJ
eurjchem-411	12	6	and	and	CCONJ
eurjchem-411	12	7	uncondensed	uncondensed	ADJ
eurjchem-411	12	8	thiophenes	thiophene	NOUN
eurjchem-411	12	9	under	under	ADP
eurjchem-411	12	10	investigation	investigation	NOUN
eurjchem-411	12	11	showed	show	VERB
eurjchem-411	12	12	generally	generally	ADV
eurjchem-411	12	13	remarkable	remarkable	ADJ
eurjchem-411	12	14	in	in	ADP
eurjchem-411	12	15	vitro	vitro	X
eurjchem-411	12	16	antibacterial	antibacterial	ADJ
eurjchem-411	12	17	activity	activity	NOUN
eurjchem-411	12	18	,	,	PUNCT
eurjchem-411	12	19	unfortunately	unfortunately	ADV
eurjchem-411	12	20	,	,	PUNCT
eurjchem-411	12	21	no	no	DET
eurjchem-411	12	22	significant	significant	ADJ
eurjchem-411	12	23	antifungal	antifungal	ADJ
eurjchem-411	12	24	activity	activity	NOUN
eurjchem-411	12	25	was	be	AUX
eurjchem-411	12	26	observed	observe	VERB
eurjchem-411	12	27	with	with	ADP
eurjchem-411	12	28	any	any	PRON
eurjchem-411	12	29	of	of	ADP
eurjchem-411	12	30	the	the	DET
eurjchem-411	12	31	compounds	compound	NOUN
eurjchem-411	12	32	tested	test	VERB
eurjchem-411	12	33	except	except	SCONJ
eurjchem-411	12	34	for	for	ADP
eurjchem-411	12	35	8	8	NUM
eurjchem-411	12	36	.	.	PUNCT
eurjchem-411	13	1	surprisingly	surprisingly	ADV
eurjchem-411	13	2	,	,	PUNCT
eurjchem-411	13	3	compound	compound	NOUN
eurjchem-411	13	4	8	8	NUM
eurjchem-411	13	5	displayed	display	VERB
eurjchem-411	13	6	an	an	DET
eurjchem-411	13	7	excellent	excellent	ADJ
eurjchem-411	13	8	effect	effect	NOUN
eurjchem-411	13	9	on	on	ADP
eurjchem-411	13	10	fungus	fungus	PROPN
eurjchem-411	13	11	(	(	PUNCT
eurjchem-411	13	12	a.	a.	NOUN
eurjchem-411	13	13	flavus	flavus	PROPN
eurjchem-411	13	14	)	)	PUNCT
eurjchem-411	13	15	on	on	ADP
eurjchem-411	13	16	the	the	DET
eurjchem-411	13	17	one	one	NUM
eurjchem-411	13	18	hand	hand	NOUN
eurjchem-411	13	19	,	,	PUNCT
eurjchem-411	13	20	whereas	whereas	SCONJ
eurjchem-411	13	21	the	the	DET
eurjchem-411	13	22	lowest	low	ADJ
eurjchem-411	13	23	effect	effect	NOUN
eurjchem-411	13	24	on	on	ADP
eurjchem-411	13	25	bacteria	bacteria	NOUN
eurjchem-411	13	26	on	on	ADP
eurjchem-411	13	27	the	the	DET
eurjchem-411	13	28	other	other	ADJ
eurjchem-411	13	29	.	.	PUNCT
eurjchem-411	14	1	the	the	DET
eurjchem-411	14	2	attachment	attachment	NOUN
eurjchem-411	14	3	of	of	ADP
eurjchem-411	14	4	a	a	DET
eurjchem-411	14	5	triazolothiadiazine	triazolothiadiazine	NOUN
eurjchem-411	14	6	moiety	moiety	NOUN
eurjchem-411	14	7	to	to	ADP
eurjchem-411	14	8	a	a	DET
eurjchem-411	14	9	thiophene	thiophene	NOUN
eurjchem-411	14	10	ring	ring	NOUN
eurjchem-411	14	11	could	could	AUX
eurjchem-411	14	12	be	be	AUX
eurjchem-411	14	13	considered	consider	VERB
eurjchem-411	14	14	as	as	ADP
eurjchem-411	14	15	a	a	DET
eurjchem-411	14	16	promising	promising	ADJ
eurjchem-411	14	17	strategy	strategy	NOUN
eurjchem-411	14	18	for	for	ADP
eurjchem-411	14	19	the	the	DET
eurjchem-411	14	20	development	development	NOUN
eurjchem-411	14	21	of	of	ADP
eurjchem-411	14	22	new	new	ADJ
eurjchem-411	14	23	therapeutic	therapeutic	ADJ
eurjchem-411	14	24	antibacterial	antibacterial	ADJ
eurjchem-411	14	25	agents	agent	NOUN
eurjchem-411	14	26	related	relate	VERB
eurjchem-411	14	27	to	to	ADP
eurjchem-411	14	28	the	the	DET
eurjchem-411	14	29	aminothiophene	aminothiophene	NOUN
eurjchem-411	14	30	system	system	NOUN
eurjchem-411	14	31	.	.	PUNCT
eurjchem-411	15	1	thienopyrimidinone	thienopyrimidinone	VERB
eurjchem-411	15	2	cyclocondensation	cyclocondensation	NOUN
eurjchem-411	15	3	cyclodesulfurization	cyclodesulfurization	NOUN
eurjchem-411	15	4	hydrazinolysis	hydrazinolysis	NOUN
eurjchem-411	15	5	alkylation	alkylation	NOUN
eurjchem-411	15	6	antimicrobial	antimicrobial	ADJ
eurjchem-411	15	7	activity	activity	NOUN
eurjchem-411	15	8	1	1	NUM
eurjchem-411	15	9	.	.	PUNCT
eurjchem-411	15	10	introduction	introduction	NOUN
eurjchem-411	15	11	as	as	ADP
eurjchem-411	15	12	a	a	DET
eurjchem-411	15	13	result	result	NOUN
eurjchem-411	15	14	of	of	ADP
eurjchem-411	15	15	the	the	DET
eurjchem-411	15	16	dramatic	dramatic	ADJ
eurjchem-411	15	17	increase	increase	NOUN
eurjchem-411	15	18	in	in	ADP
eurjchem-411	15	19	microbial	microbial	ADJ
eurjchem-411	15	20	infections	infection	NOUN
eurjchem-411	15	21	,	,	PUNCT
eurjchem-411	15	22	serious	serious	ADJ
eurjchem-411	15	23	attention	attention	NOUN
eurjchem-411	15	24	has	have	AUX
eurjchem-411	15	25	been	be	AUX
eurjchem-411	15	26	directed	direct	VERB
eurjchem-411	15	27	in	in	ADP
eurjchem-411	15	28	recent	recent	ADJ
eurjchem-411	15	29	years	year	NOUN
eurjchem-411	15	30	towards	towards	ADP
eurjchem-411	15	31	the	the	DET
eurjchem-411	15	32	discovery	discovery	NOUN
eurjchem-411	15	33	and	and	CCONJ
eurjchem-411	15	34	development	development	NOUN
eurjchem-411	15	35	of	of	ADP
eurjchem-411	15	36	new	new	ADJ
eurjchem-411	15	37	antimicrobial	antimicrobial	ADJ
eurjchem-411	15	38	drugs	drug	NOUN
eurjchem-411	15	39	.	.	PUNCT
eurjchem-411	16	1	fungal	fungal	ADJ
eurjchem-411	16	2	infections	infection	NOUN
eurjchem-411	16	3	,	,	PUNCT
eurjchem-411	16	4	mostly	mostly	ADV
eurjchem-411	16	5	caused	cause	VERB
eurjchem-411	16	6	by	by	ADP
eurjchem-411	16	7	candida	candida	NOUN
eurjchem-411	16	8	albicans	albican	NOUN
eurjchem-411	16	9	,	,	PUNCT
eurjchem-411	16	10	are	be	AUX
eurjchem-411	16	11	often	often	ADV
eurjchem-411	16	12	aggravated	aggravate	VERB
eurjchem-411	16	13	through	through	ADP
eurjchem-411	16	14	the	the	DET
eurjchem-411	16	15	widespread	widespread	ADJ
eurjchem-411	16	16	use	use	NOUN
eurjchem-411	16	17	of	of	ADP
eurjchem-411	16	18	broad‐spectrum	broad‐spectrum	NOUN
eurjchem-411	16	19	antibiotics	antibiotic	NOUN
eurjchem-411	16	20	,	,	PUNCT
eurjchem-411	16	21	immunosuppressive	immunosuppressive	ADJ
eurjchem-411	16	22	agents	agent	NOUN
eurjchem-411	16	23	,	,	PUNCT
eurjchem-411	16	24	anticancer	anticancer	NOUN
eurjchem-411	16	25	and	and	CCONJ
eurjchem-411	16	26	anti‐	anti‐	PROPN
eurjchem-411	16	27	aids	aids	PROPN
eurjchem-411	16	28	drugs	drug	NOUN
eurjchem-411	17	1	[	[	X
eurjchem-411	17	2	1,2	1,2	NUM
eurjchem-411	17	3	]	]	PUNCT
eurjchem-411	17	4	.	.	PUNCT
eurjchem-411	18	1	despite	despite	SCONJ
eurjchem-411	18	2	advances	advance	NOUN
eurjchem-411	18	3	in	in	ADP
eurjchem-411	18	4	antimicrobial	antimicrobial	ADJ
eurjchem-411	18	5	therapy	therapy	NOUN
eurjchem-411	18	6	,	,	PUNCT
eurjchem-411	18	7	many	many	ADJ
eurjchem-411	18	8	problems	problem	NOUN
eurjchem-411	18	9	remain	remain	VERB
eurjchem-411	18	10	to	to	PART
eurjchem-411	18	11	be	be	AUX
eurjchem-411	18	12	solved	solve	VERB
eurjchem-411	18	13	for	for	ADP
eurjchem-411	18	14	a	a	DET
eurjchem-411	18	15	new	new	ADJ
eurjchem-411	18	16	generation	generation	NOUN
eurjchem-411	18	17	of	of	ADP
eurjchem-411	18	18	antimicrobial	antimicrobial	ADJ
eurjchem-411	18	19	agents	agent	NOUN
eurjchem-411	18	20	.	.	PUNCT
eurjchem-411	19	1	the	the	DET
eurjchem-411	19	2	main	main	ADJ
eurjchem-411	19	3	problem	problem	NOUN
eurjchem-411	19	4	in	in	ADP
eurjchem-411	19	5	the	the	DET
eurjchem-411	19	6	treatment	treatment	NOUN
eurjchem-411	19	7	of	of	ADP
eurjchem-411	19	8	microbial	microbial	ADJ
eurjchem-411	19	9	infections	infection	NOUN
eurjchem-411	19	10	is	be	AUX
eurjchem-411	19	11	the	the	DET
eurjchem-411	19	12	increasing	increase	VERB
eurjchem-411	19	13	prevalence	prevalence	NOUN
eurjchem-411	19	14	of	of	ADP
eurjchem-411	19	15	drug	drug	NOUN
eurjchem-411	19	16	resistance	resistance	NOUN
eurjchem-411	19	17	especially	especially	ADV
eurjchem-411	19	18	in	in	ADP
eurjchem-411	19	19	patients	patient	NOUN
eurjchem-411	19	20	chronically	chronically	ADV
eurjchem-411	19	21	subjected	subject	VERB
eurjchem-411	19	22	to	to	ADP
eurjchem-411	19	23	antimycotic	antimycotic	ADJ
eurjchem-411	19	24	therapy	therapy	NOUN
eurjchem-411	19	25	such	such	ADJ
eurjchem-411	19	26	as	as	ADP
eurjchem-411	19	27	persons	person	NOUN
eurjchem-411	19	28	infected	infect	VERB
eurjchem-411	19	29	with	with	ADP
eurjchem-411	19	30	hiv	hiv	PROPN
eurjchem-411	19	31	[	[	X
eurjchem-411	19	32	2,3	2,3	NUM
eurjchem-411	19	33	]	]	PUNCT
eurjchem-411	19	34	.	.	PUNCT
eurjchem-411	20	1	therefore	therefore	ADV
eurjchem-411	20	2	,	,	PUNCT
eurjchem-411	20	3	the	the	DET
eurjchem-411	20	4	development	development	NOUN
eurjchem-411	20	5	of	of	ADP
eurjchem-411	20	6	new	new	ADJ
eurjchem-411	20	7	and	and	CCONJ
eurjchem-411	20	8	efficacious	efficacious	ADJ
eurjchem-411	20	9	antimicrobial	antimicrobial	ADJ
eurjchem-411	20	10	drugs	drug	NOUN
eurjchem-411	20	11	is	be	AUX
eurjchem-411	20	12	a	a	DET
eurjchem-411	20	13	very	very	ADV
eurjchem-411	20	14	important	important	ADJ
eurjchem-411	20	15	goal	goal	NOUN
eurjchem-411	20	16	,	,	PUNCT
eurjchem-411	20	17	and	and	CCONJ
eurjchem-411	20	18	most	most	ADJ
eurjchem-411	20	19	of	of	ADP
eurjchem-411	20	20	the	the	DET
eurjchem-411	20	21	research	research	NOUN
eurjchem-411	20	22	efforts	effort	NOUN
eurjchem-411	20	23	in	in	ADP
eurjchem-411	20	24	this	this	DET
eurjchem-411	20	25	field	field	NOUN
eurjchem-411	20	26	are	be	AUX
eurjchem-411	20	27	directed	direct	VERB
eurjchem-411	20	28	towards	towards	ADP
eurjchem-411	20	29	the	the	DET
eurjchem-411	20	30	design	design	NOUN
eurjchem-411	20	31	of	of	ADP
eurjchem-411	20	32	new	new	ADJ
eurjchem-411	20	33	agents	agent	NOUN
eurjchem-411	20	34	.	.	PUNCT
eurjchem-411	21	1	a	a	DET
eurjchem-411	21	2	review	review	NOUN
eurjchem-411	21	3	of	of	ADP
eurjchem-411	21	4	the	the	DET
eurjchem-411	21	5	recent	recent	ADJ
eurjchem-411	21	6	literature	literature	NOUN
eurjchem-411	21	7	shows	show	VERB
eurjchem-411	21	8	that	that	SCONJ
eurjchem-411	21	9	many	many	ADJ
eurjchem-411	21	10	effective	effective	ADJ
eurjchem-411	21	11	antimicrobial	antimicrobial	ADJ
eurjchem-411	21	12	agents	agent	NOUN
eurjchem-411	21	13	contain	contain	VERB
eurjchem-411	21	14	a	a	DET
eurjchem-411	21	15	heterocyclic	heterocyclic	ADJ
eurjchem-411	21	16	moiety	moiety	NOUN
eurjchem-411	21	17	within	within	ADP
eurjchem-411	21	18	their	their	PRON
eurjchem-411	21	19	structure	structure	NOUN
eurjchem-411	21	20	[	[	X
eurjchem-411	21	21	4,5	4,5	X
eurjchem-411	21	22	]	]	PUNCT
eurjchem-411	21	23	with	with	ADP
eurjchem-411	21	24	special	special	ADJ
eurjchem-411	21	25	emphasis	emphasis	NOUN
eurjchem-411	21	26	on	on	ADP
eurjchem-411	21	27	those	those	DET
eurjchem-411	21	28	agents	agent	NOUN
eurjchem-411	21	29	incorporating	incorporate	VERB
eurjchem-411	21	30	a	a	DET
eurjchem-411	21	31	thiophene	thiophene	NOUN
eurjchem-411	21	32	moiety	moiety	NOUN
eurjchem-411	21	33	[	[	X
eurjchem-411	21	34	6‐10	6‐10	NUM
eurjchem-411	21	35	]	]	PUNCT
eurjchem-411	21	36	.	.	PUNCT
eurjchem-411	22	1	the	the	DET
eurjchem-411	22	2	thiophene	thiophene	NOUN
eurjchem-411	22	3	ring	ring	NOUN
eurjchem-411	22	4	system	system	NOUN
eurjchem-411	22	5	is	be	AUX
eurjchem-411	22	6	notably	notably	ADV
eurjchem-411	22	7	a	a	DET
eurjchem-411	22	8	structural	structural	ADJ
eurjchem-411	22	9	component	component	NOUN
eurjchem-411	22	10	of	of	ADP
eurjchem-411	22	11	the	the	DET
eurjchem-411	22	12	commercial	commercial	ADJ
eurjchem-411	22	13	imidazole	imidazole	NOUN
eurjchem-411	22	14	antifungal	antifungal	ADJ
eurjchem-411	22	15	agent	agent	NOUN
eurjchem-411	22	16	sertaconazole	sertaconazole	NOUN
eurjchem-411	23	1	[	[	X
eurjchem-411	23	2	11	11	NUM
eurjchem-411	23	3	]	]	PUNCT
eurjchem-411	23	4	.	.	PUNCT
eurjchem-411	24	1	in	in	ADP
eurjchem-411	24	2	addition	addition	NOUN
eurjchem-411	24	3	,	,	PUNCT
eurjchem-411	24	4	the	the	DET
eurjchem-411	24	5	antimicrobial	antimicrobial	ADJ
eurjchem-411	24	6	profile	profile	NOUN
eurjchem-411	24	7	of	of	ADP
eurjchem-411	24	8	condensed	condense	VERB
eurjchem-411	24	9	thiophenes	thiophene	NOUN
eurjchem-411	24	10	,	,	PUNCT
eurjchem-411	24	11	particularly	particularly	ADV
eurjchem-411	24	12	their	their	PRON
eurjchem-411	24	13	thieno[2,3‐d]pyrimidin‐4‐one	thieno[2,3‐d]pyrimidin‐4‐one	NOUN
eurjchem-411	24	14	analogues	analogue	NOUN
eurjchem-411	24	15	,	,	PUNCT
eurjchem-411	24	16	is	be	AUX
eurjchem-411	24	17	also	also	ADV
eurjchem-411	24	18	well	well	ADV
eurjchem-411	24	19	categorized	categorize	VERB
eurjchem-411	24	20	in	in	ADP
eurjchem-411	24	21	the	the	DET
eurjchem-411	24	22	literature	literature	NOUN
eurjchem-411	24	23	[	[	X
eurjchem-411	24	24	12‐14	12‐14	X
eurjchem-411	24	25	]	]	PUNCT
eurjchem-411	24	26	.	.	PUNCT
eurjchem-411	25	1	in	in	ADP
eurjchem-411	25	2	searching	search	VERB
eurjchem-411	25	3	for	for	ADP
eurjchem-411	25	4	new	new	ADJ
eurjchem-411	25	5	compounds	compound	NOUN
eurjchem-411	25	6	with	with	ADP
eurjchem-411	25	7	a	a	DET
eurjchem-411	25	8	promising	promising	ADJ
eurjchem-411	25	9	antimicrobial	antimicrobial	ADJ
eurjchem-411	25	10	profile	profile	NOUN
eurjchem-411	25	11	and	and	CCONJ
eurjchem-411	25	12	as	as	ADP
eurjchem-411	25	13	part	part	NOUN
eurjchem-411	25	14	of	of	ADP
eurjchem-411	25	15	our	our	PRON
eurjchem-411	25	16	ongoing	ongoing	ADJ
eurjchem-411	25	17	studies	study	NOUN
eurjchem-411	25	18	in	in	ADP
eurjchem-411	25	19	the	the	DET
eurjchem-411	25	20	development	development	NOUN
eurjchem-411	25	21	of	of	ADP
eurjchem-411	25	22	new	new	ADJ
eurjchem-411	25	23	chemotherapeutic	chemotherapeutic	ADJ
eurjchem-411	25	24	agents	agent	NOUN
eurjchem-411	25	25	[	[	X
eurjchem-411	25	26	15‐17	15‐17	NUM
eurjchem-411	25	27	]	]	PUNCT
eurjchem-411	25	28	,	,	PUNCT
eurjchem-411	25	29	we	we	PRON
eurjchem-411	25	30	embarked	embark	VERB
eurjchem-411	25	31	upon	upon	SCONJ
eurjchem-411	25	32	the	the	DET
eurjchem-411	25	33	synthesis	synthesis	NOUN
eurjchem-411	25	34	of	of	ADP
eurjchem-411	25	35	a	a	DET
eurjchem-411	25	36	series	series	NOUN
eurjchem-411	25	37	of	of	ADP
eurjchem-411	25	38	novel	novel	NOUN
eurjchem-411	25	39	condensed	condense	VERB
eurjchem-411	25	40	tricyclic	tricyclic	ADJ
eurjchem-411	25	41	thiophene	thiophene	NOUN
eurjchem-411	25	42	derivatives	derivative	NOUN
eurjchem-411	25	43	containing	contain	VERB
eurjchem-411	25	44	a	a	DET
eurjchem-411	25	45	thieno[2,3‐	thieno[2,3‐	PROPN
eurjchem-411	25	46	d]pyrimidin‐4‐one	d]pyrimidin‐4‐one	NOUN
eurjchem-411	25	47	core	core	NOUN
eurjchem-411	25	48	fused	fuse	VERB
eurjchem-411	25	49	through	through	ADP
eurjchem-411	25	50	n‐3	n‐3	NOUN
eurjchem-411	25	51	and	and	CCONJ
eurjchem-411	25	52	a	a	DET
eurjchem-411	25	53	second	second	ADJ
eurjchem-411	25	54	series	series	NOUN
eurjchem-411	25	55	of	of	ADP
eurjchem-411	25	56	novel	novel	ADJ
eurjchem-411	25	57	uncondensed	uncondensed	ADJ
eurjchem-411	25	58	derivatives	derivative	NOUN
eurjchem-411	25	59	bearing	bear	VERB
eurjchem-411	25	60	the	the	DET
eurjchem-411	25	61	same	same	ADJ
eurjchem-411	25	62	thiophene	thiophene	NOUN
eurjchem-411	25	63	pharmacophore	pharmacophore	NOUN
eurjchem-411	25	64	substituted	substitute	VERB
eurjchem-411	25	65	with	with	ADP
eurjchem-411	25	66	different	different	ADJ
eurjchem-411	25	67	heterocyclic	heterocyclic	ADJ
eurjchem-411	25	68	gaber	gaber	PROPN
eurjchem-411	25	69	and	and	CCONJ
eurjchem-411	25	70	bagley	bagley	PROPN
eurjchem-411	25	71	/	/	SYM
eurjchem-411	25	72	european	european	PROPN
eurjchem-411	25	73	journal	journal	PROPN
eurjchem-411	25	74	of	of	ADP
eurjchem-411	25	75	chemistry	chemistry	NOUN
eurjchem-411	25	76	2	2	NUM
eurjchem-411	25	77	(	(	PUNCT
eurjchem-411	25	78	2	2	NUM
eurjchem-411	25	79	)	)	PUNCT
eurjchem-411	25	80	(	(	PUNCT
eurjchem-411	25	81	2011	2011	NUM
eurjchem-411	25	82	)	)	PUNCT
eurjchem-411	25	83	214‐222	214‐222	NOUN
eurjchem-411	25	84	215	215	NUM
eurjchem-411	25	85	fragments	fragment	NOUN
eurjchem-411	25	86	at	at	ADP
eurjchem-411	25	87	c‐3	c‐3	NOUN
eurjchem-411	25	88	in	in	ADP
eurjchem-411	25	89	anticipation	anticipation	NOUN
eurjchem-411	25	90	of	of	ADP
eurjchem-411	25	91	the	the	DET
eurjchem-411	25	92	development	development	NOUN
eurjchem-411	25	93	of	of	ADP
eurjchem-411	25	94	new	new	ADJ
eurjchem-411	25	95	broad	broad	ADJ
eurjchem-411	25	96	spectrum	spectrum	NOUN
eurjchem-411	25	97	antimicrobial	antimicrobial	ADJ
eurjchem-411	25	98	agents	agent	NOUN
eurjchem-411	25	99	which	which	PRON
eurjchem-411	25	100	are	be	AUX
eurjchem-411	25	101	devoid	devoid	ADJ
eurjchem-411	25	102	of	of	ADP
eurjchem-411	25	103	the	the	DET
eurjchem-411	25	104	side	side	NOUN
eurjchem-411	25	105	effects	effect	NOUN
eurjchem-411	25	106	associated	associate	VERB
eurjchem-411	25	107	with	with	ADP
eurjchem-411	25	108	current	current	ADJ
eurjchem-411	25	109	therapeutic	therapeutic	ADJ
eurjchem-411	25	110	regimes	regime	NOUN
eurjchem-411	25	111	.	.	PUNCT
eurjchem-411	26	1	2	2	X
eurjchem-411	26	2	.	.	X
eurjchem-411	26	3	experimental	experimental	ADJ
eurjchem-411	26	4	2.1	2.1	NUM
eurjchem-411	26	5	.	.	PUNCT
eurjchem-411	27	1	instrumentation	instrumentation	NOUN
eurjchem-411	27	2	melting	melting	NOUN
eurjchem-411	27	3	points	point	NOUN
eurjchem-411	27	4	are	be	AUX
eurjchem-411	27	5	uncorrected	uncorrecte	VERB
eurjchem-411	27	6	.	.	PUNCT
eurjchem-411	28	1	ir	ir	PROPN
eurjchem-411	28	2	spectra	spectra	PROPN
eurjchem-411	28	3	were	be	AUX
eurjchem-411	28	4	recorded	record	VERB
eurjchem-411	28	5	(	(	PUNCT
eurjchem-411	28	6	kbr	kbr	PROPN
eurjchem-411	28	7	)	)	PUNCT
eurjchem-411	28	8	on	on	ADP
eurjchem-411	28	9	a	a	DET
eurjchem-411	28	10	pye	pye	NOUN
eurjchem-411	28	11	unicam	unicam	ADJ
eurjchem-411	28	12	sp‐1000	sp‐1000	PROPN
eurjchem-411	28	13	spectrophotometer	spectrophotometer	NOUN
eurjchem-411	28	14	.	.	PUNCT
eurjchem-411	29	1	nmr	nmr	NOUN
eurjchem-411	29	2	spectra	spectra	NOUN
eurjchem-411	29	3	were	be	AUX
eurjchem-411	29	4	obtained	obtain	VERB
eurjchem-411	29	5	on	on	ADP
eurjchem-411	29	6	a	a	DET
eurjchem-411	29	7	varian	varian	PROPN
eurjchem-411	29	8	gemini	gemini	PROPN
eurjchem-411	29	9	300	300	NUM
eurjchem-411	29	10	mhz	mhz	NOUN
eurjchem-411	29	11	spectrometer	spectrometer	NOUN
eurjchem-411	29	12	in	in	ADP
eurjchem-411	29	13	dmso‐d6	dmso‐d6	PROPN
eurjchem-411	29	14	as	as	ADP
eurjchem-411	29	15	solvent	solvent	ADJ
eurjchem-411	29	16	and	and	CCONJ
eurjchem-411	29	17	tms	tms	PROPN
eurjchem-411	29	18	as	as	ADP
eurjchem-411	29	19	internal	internal	ADJ
eurjchem-411	29	20	reference	reference	NOUN
eurjchem-411	29	21	.	.	PUNCT
eurjchem-411	30	1	chemical	chemical	ADJ
eurjchem-411	30	2	shifts	shift	NOUN
eurjchem-411	30	3	are	be	AUX
eurjchem-411	30	4	expressed	express	VERB
eurjchem-411	30	5	in	in	ADP
eurjchem-411	30	6	δ	δ	PROPN
eurjchem-411	30	7	ppm	ppm	NOUN
eurjchem-411	30	8	.	.	PUNCT
eurjchem-411	31	1	splitting	splitting	NOUN
eurjchem-411	31	2	patterns	pattern	NOUN
eurjchem-411	31	3	were	be	AUX
eurjchem-411	31	4	designated	designate	VERB
eurjchem-411	31	5	as	as	SCONJ
eurjchem-411	31	6	follows	follow	VERB
eurjchem-411	31	7	:	:	PUNCT
eurjchem-411	31	8	s	s	X
eurjchem-411	31	9	:	:	PUNCT
eurjchem-411	31	10	singlet	singlet	VERB
eurjchem-411	31	11	;	;	PUNCT
eurjchem-411	31	12	d	d	X
eurjchem-411	31	13	:	:	PUNCT
eurjchem-411	31	14	doublet	doublet	PROPN
eurjchem-411	31	15	;	;	PUNCT
eurjchem-411	31	16	t	t	NUM
eurjchem-411	31	17	:	:	PUNCT
eurjchem-411	31	18	triplet	triplet	NOUN
eurjchem-411	31	19	;	;	PUNCT
eurjchem-411	31	20	q	q	ADJ
eurjchem-411	31	21	:	:	PUNCT
eurjchem-411	31	22	quartet	quartet	NOUN
eurjchem-411	31	23	;	;	PUNCT
eurjchem-411	31	24	m	m	PROPN
eurjchem-411	31	25	:	:	PUNCT
eurjchem-411	31	26	multiplet	multiplet	NOUN
eurjchem-411	31	27	.	.	PUNCT
eurjchem-411	32	1	ei	ei	X
eurjchem-411	32	2	mass	mass	PROPN
eurjchem-411	32	3	spectra	spectra	PROPN
eurjchem-411	32	4	were	be	AUX
eurjchem-411	32	5	recorded	record	VERB
eurjchem-411	32	6	on	on	ADP
eurjchem-411	32	7	a	a	DET
eurjchem-411	32	8	shimadzu	shimadzu	ADJ
eurjchem-411	32	9	gc	gc	PROPN
eurjchem-411	32	10	ms‐qp	ms‐qp	X
eurjchem-411	32	11	1000	1000	NUM
eurjchem-411	32	12	ei	ei	NOUN
eurjchem-411	32	13	mass	mass	ADJ
eurjchem-411	32	14	spectrometer	spectrometer	NOUN
eurjchem-411	32	15	at	at	ADP
eurjchem-411	32	16	70	70	NUM
eurjchem-411	32	17	ev	ev	NOUN
eurjchem-411	32	18	.	.	PROPN
eurjchem-411	32	19	microanalytical	microanalytical	ADJ
eurjchem-411	32	20	data	datum	NOUN
eurjchem-411	32	21	were	be	AUX
eurjchem-411	32	22	found	find	VERB
eurjchem-411	32	23	to	to	PART
eurjchem-411	32	24	be	be	AUX
eurjchem-411	32	25	in	in	ADP
eurjchem-411	32	26	satisfactory	satisfactory	ADJ
eurjchem-411	32	27	agreement	agreement	NOUN
eurjchem-411	32	28	with	with	ADP
eurjchem-411	32	29	the	the	DET
eurjchem-411	32	30	theoretical	theoretical	ADJ
eurjchem-411	32	31	values	value	NOUN
eurjchem-411	32	32	.	.	PUNCT
eurjchem-411	33	1	the	the	DET
eurjchem-411	33	2	biological	biological	ADJ
eurjchem-411	33	3	evaluation	evaluation	NOUN
eurjchem-411	33	4	of	of	ADP
eurjchem-411	33	5	the	the	DET
eurjchem-411	33	6	products	product	NOUN
eurjchem-411	33	7	was	be	AUX
eurjchem-411	33	8	carried	carry	VERB
eurjchem-411	33	9	out	out	ADP
eurjchem-411	33	10	at	at	ADP
eurjchem-411	33	11	the	the	DET
eurjchem-411	33	12	micro	micro	ADJ
eurjchem-411	33	13	analytical	analytical	ADJ
eurjchem-411	33	14	center	center	NOUN
eurjchem-411	33	15	in	in	ADP
eurjchem-411	33	16	cairo	cairo	PROPN
eurjchem-411	33	17	university	university	PROPN
eurjchem-411	33	18	,	,	PUNCT
eurjchem-411	33	19	cairo	cairo	PROPN
eurjchem-411	33	20	,	,	PUNCT
eurjchem-411	33	21	egypt	egypt	PROPN
eurjchem-411	33	22	.	.	PUNCT
eurjchem-411	34	1	compounds	compound	VERB
eurjchem-411	34	2	1	1	NUM
eurjchem-411	35	1	[	[	X
eurjchem-411	35	2	18‐22	18‐22	NUM
eurjchem-411	35	3	]	]	PUNCT
eurjchem-411	35	4	and	and	CCONJ
eurjchem-411	35	5	2a	2a	NUM
eurjchem-411	36	1	[	[	X
eurjchem-411	36	2	23	23	NUM
eurjchem-411	36	3	]	]	PUNCT
eurjchem-411	36	4	were	be	AUX
eurjchem-411	36	5	prepared	prepare	VERB
eurjchem-411	36	6	according	accord	VERB
eurjchem-411	36	7	to	to	ADP
eurjchem-411	36	8	known	know	VERB
eurjchem-411	36	9	methods	method	NOUN
eurjchem-411	36	10	(	(	PUNCT
eurjchem-411	36	11	scheme	scheme	NOUN
eurjchem-411	36	12	1	1	NUM
eurjchem-411	36	13	)	)	PUNCT
eurjchem-411	36	14	.	.	PUNCT
eurjchem-411	37	1	2.2	2.2	NUM
eurjchem-411	37	2	.	.	PUNCT
eurjchem-411	37	3	synthesis	synthesis	NOUN
eurjchem-411	37	4	2.2.1	2.2.1	NUM
eurjchem-411	37	5	.	.	PUNCT
eurjchem-411	37	6	general	general	ADJ
eurjchem-411	37	7	procedure	procedure	NOUN
eurjchem-411	37	8	for	for	ADP
eurjchem-411	37	9	the	the	DET
eurjchem-411	37	10	synthesis	synthesis	NOUN
eurjchem-411	37	11	of	of	ADP
eurjchem-411	37	12	ethyl	ethyl	PROPN
eurjchem-411	37	13	5‐subs‐	5‐subs‐	NUM
eurjchem-411	37	14	tituted‐2‐amino‐4‐phenylthiophene‐3‐carboxylates	tituted‐2‐amino‐4‐phenylthiophene‐3‐carboxylate	NOUN
eurjchem-411	37	15	(	(	PUNCT
eurjchem-411	37	16	2b‐d	2b‐d	NOUN
eurjchem-411	37	17	)	)	PUNCT
eurjchem-411	37	18	either	either	CCONJ
eurjchem-411	37	19	aryl	aryl	NOUN
eurjchem-411	37	20	amine	amine	ADJ
eurjchem-411	37	21	or	or	CCONJ
eurjchem-411	37	22	heteroaryl	heteroaryl	NOUN
eurjchem-411	37	23	amine	amine	NOUN
eurjchem-411	37	24	(	(	PUNCT
eurjchem-411	37	25	0.0025	0.0025	NUM
eurjchem-411	37	26	mol	mol	NOUN
eurjchem-411	37	27	)	)	PUNCT
eurjchem-411	37	28	was	be	AUX
eurjchem-411	37	29	dissolved	dissolve	VERB
eurjchem-411	37	30	in	in	ADP
eurjchem-411	37	31	concentrated	concentrated	ADJ
eurjchem-411	37	32	hydrochloric	hydrochloric	ADJ
eurjchem-411	37	33	acid	acid	NOUN
eurjchem-411	37	34	(	(	PUNCT
eurjchem-411	37	35	5	5	NUM
eurjchem-411	37	36	ml	ml	NOUN
eurjchem-411	37	37	)	)	PUNCT
eurjchem-411	37	38	by	by	ADP
eurjchem-411	37	39	warming	warm	VERB
eurjchem-411	37	40	,	,	PUNCT
eurjchem-411	37	41	and	and	CCONJ
eurjchem-411	37	42	the	the	DET
eurjchem-411	37	43	solution	solution	NOUN
eurjchem-411	37	44	was	be	AUX
eurjchem-411	37	45	stirred	stir	VERB
eurjchem-411	37	46	overnight	overnight	ADV
eurjchem-411	37	47	at	at	ADP
eurjchem-411	37	48	room	room	NOUN
eurjchem-411	37	49	temperature	temperature	NOUN
eurjchem-411	37	50	.	.	PUNCT
eurjchem-411	38	1	the	the	DET
eurjchem-411	38	2	solution	solution	NOUN
eurjchem-411	38	3	was	be	AUX
eurjchem-411	38	4	then	then	ADV
eurjchem-411	38	5	cooled	cool	VERB
eurjchem-411	38	6	to	to	ADP
eurjchem-411	38	7	0‐5	0‐5	PROPN
eurjchem-411	38	8	oc	oc	PROPN
eurjchem-411	38	9	,	,	PUNCT
eurjchem-411	38	10	a	a	DET
eurjchem-411	38	11	well	well	ADV
eurjchem-411	38	12	cooled	cool	VERB
eurjchem-411	38	13	saturated	saturate	VERB
eurjchem-411	38	14	solution	solution	NOUN
eurjchem-411	38	15	of	of	ADP
eurjchem-411	38	16	sodium	sodium	NOUN
eurjchem-411	38	17	nitrite	nitrite	NOUN
eurjchem-411	38	18	(	(	PUNCT
eurjchem-411	38	19	0.0026	0.0026	NUM
eurjchem-411	38	20	mol	mol	NOUN
eurjchem-411	38	21	)	)	PUNCT
eurjchem-411	38	22	was	be	AUX
eurjchem-411	38	23	added	add	VERB
eurjchem-411	38	24	portionwise	portionwise	ADV
eurjchem-411	38	25	at	at	ADP
eurjchem-411	38	26	5‐10	5‐10	NUM
eurjchem-411	38	27	oc	oc	NOUN
eurjchem-411	38	28	,	,	PUNCT
eurjchem-411	38	29	and	and	CCONJ
eurjchem-411	38	30	the	the	DET
eurjchem-411	38	31	reaction	reaction	NOUN
eurjchem-411	38	32	content	content	NOUN
eurjchem-411	38	33	was	be	AUX
eurjchem-411	38	34	stirred	stir	VERB
eurjchem-411	38	35	for	for	ADP
eurjchem-411	38	36	a	a	DET
eurjchem-411	38	37	further	further	ADJ
eurjchem-411	38	38	1	1	NUM
eurjchem-411	38	39	h	h	NOUN
eurjchem-411	38	40	at	at	ADP
eurjchem-411	38	41	the	the	DET
eurjchem-411	38	42	same	same	ADJ
eurjchem-411	38	43	temperature	temperature	NOUN
eurjchem-411	38	44	.	.	PUNCT
eurjchem-411	39	1	excess	excess	ADJ
eurjchem-411	39	2	nitrous	nitrous	ADJ
eurjchem-411	39	3	acid	acid	NOUN
eurjchem-411	39	4	was	be	AUX
eurjchem-411	39	5	decomposed	decompose	VERB
eurjchem-411	39	6	by	by	ADP
eurjchem-411	39	7	the	the	DET
eurjchem-411	39	8	addition	addition	NOUN
eurjchem-411	39	9	of	of	ADP
eurjchem-411	39	10	urea	urea	NOUN
eurjchem-411	39	11	,	,	PUNCT
eurjchem-411	39	12	and	and	CCONJ
eurjchem-411	39	13	the	the	DET
eurjchem-411	39	14	solution	solution	NOUN
eurjchem-411	39	15	was	be	AUX
eurjchem-411	39	16	cooled	cool	VERB
eurjchem-411	39	17	to	to	ADP
eurjchem-411	39	18	0‐5	0‐5	NOUN
eurjchem-411	39	19	oc	oc	PROPN
eurjchem-411	39	20	.	.	PUNCT
eurjchem-411	40	1	the	the	DET
eurjchem-411	40	2	resulting	result	VERB
eurjchem-411	40	3	clear	clear	ADJ
eurjchem-411	40	4	diazonium	diazonium	NOUN
eurjchem-411	40	5	salt	salt	NOUN
eurjchem-411	40	6	solution	solution	NOUN
eurjchem-411	40	7	was	be	AUX
eurjchem-411	40	8	then	then	ADV
eurjchem-411	40	9	added	add	VERB
eurjchem-411	40	10	dropwise	dropwise	NOUN
eurjchem-411	40	11	over	over	ADP
eurjchem-411	40	12	20	20	NUM
eurjchem-411	40	13	min	min	NOUN
eurjchem-411	40	14	with	with	ADP
eurjchem-411	40	15	constant	constant	ADJ
eurjchem-411	40	16	stirring	stirring	NOUN
eurjchem-411	40	17	and	and	CCONJ
eurjchem-411	40	18	with	with	ADP
eurjchem-411	40	19	frequent	frequent	ADJ
eurjchem-411	40	20	addition	addition	NOUN
eurjchem-411	40	21	of	of	ADP
eurjchem-411	40	22	ice	ice	NOUN
eurjchem-411	40	23	to	to	ADP
eurjchem-411	40	24	a	a	DET
eurjchem-411	40	25	cold	cold	ADJ
eurjchem-411	40	26	(	(	PUNCT
eurjchem-411	40	27	0‐5	0‐5	ADJ
eurjchem-411	40	28	oc	oc	NOUN
eurjchem-411	40	29	)	)	PUNCT
eurjchem-411	40	30	stirred	stir	VERB
eurjchem-411	40	31	solution	solution	NOUN
eurjchem-411	40	32	of	of	ADP
eurjchem-411	40	33	coupling	couple	VERB
eurjchem-411	40	34	component	component	NOUN
eurjchem-411	40	35	aminoester	aminoester	NOUN
eurjchem-411	40	36	1	1	NUM
eurjchem-411	40	37	(	(	PUNCT
eurjchem-411	40	38	0.0023	0.0023	NUM
eurjchem-411	40	39	mol	mol	NOUN
eurjchem-411	40	40	)	)	PUNCT
eurjchem-411	40	41	dissolved	dissolve	VERB
eurjchem-411	40	42	in	in	ADP
eurjchem-411	40	43	20	20	NUM
eurjchem-411	40	44	ml	ml	NOUN
eurjchem-411	40	45	of	of	ADP
eurjchem-411	40	46	ethanol	ethanol	NOUN
eurjchem-411	40	47	containing	contain	VERB
eurjchem-411	40	48	sodium	sodium	NOUN
eurjchem-411	40	49	acetate	acetate	NOUN
eurjchem-411	40	50	(	(	PUNCT
eurjchem-411	40	51	0.013	0.013	NUM
eurjchem-411	40	52	mol	mol	NOUN
eurjchem-411	40	53	)	)	PUNCT
eurjchem-411	40	54	whilst	whilst	SCONJ
eurjchem-411	40	55	maintaining	maintain	VERB
eurjchem-411	40	56	a	a	DET
eurjchem-411	40	57	temperature	temperature	NOUN
eurjchem-411	40	58	at	at	ADP
eurjchem-411	40	59	0‐5	0‐5	NUM
eurjchem-411	40	60	oc	oc	VERB
eurjchem-411	40	61	.	.	PUNCT
eurjchem-411	41	1	after	after	ADP
eurjchem-411	41	2	addition	addition	NOUN
eurjchem-411	41	3	of	of	ADP
eurjchem-411	41	4	the	the	DET
eurjchem-411	41	5	diazonium	diazonium	NOUN
eurjchem-411	41	6	salt	salt	NOUN
eurjchem-411	41	7	,	,	PUNCT
eurjchem-411	41	8	the	the	DET
eurjchem-411	41	9	mixture	mixture	NOUN
eurjchem-411	41	10	was	be	AUX
eurjchem-411	41	11	stirred	stir	VERB
eurjchem-411	41	12	for	for	ADP
eurjchem-411	41	13	an	an	DET
eurjchem-411	41	14	additional	additional	ADJ
eurjchem-411	41	15	3	3	NUM
eurjchem-411	41	16	h	h	NOUN
eurjchem-411	41	17	at	at	ADP
eurjchem-411	41	18	5‐10	5‐10	NUM
eurjchem-411	41	19	oc	oc	NOUN
eurjchem-411	41	20	.	.	PUNCT
eurjchem-411	42	1	the	the	DET
eurjchem-411	42	2	precipitated	precipitate	VERB
eurjchem-411	42	3	product	product	NOUN
eurjchem-411	42	4	,	,	PUNCT
eurjchem-411	42	5	in	in	ADP
eurjchem-411	42	6	each	each	DET
eurjchem-411	42	7	case	case	NOUN
eurjchem-411	42	8	,	,	PUNCT
eurjchem-411	42	9	separated	separate	VERB
eurjchem-411	42	10	upon	upon	SCONJ
eurjchem-411	42	11	dilution	dilution	NOUN
eurjchem-411	42	12	with	with	ADP
eurjchem-411	42	13	cold	cold	ADJ
eurjchem-411	42	14	water	water	NOUN
eurjchem-411	42	15	(	(	PUNCT
eurjchem-411	42	16	30	30	NUM
eurjchem-411	42	17	ml	ml	NOUN
eurjchem-411	42	18	)	)	PUNCT
eurjchem-411	42	19	was	be	AUX
eurjchem-411	42	20	filtered	filter	VERB
eurjchem-411	42	21	off	off	ADP
eurjchem-411	42	22	,	,	PUNCT
eurjchem-411	42	23	washed	wash	VERB
eurjchem-411	42	24	with	with	ADP
eurjchem-411	42	25	hot	hot	ADJ
eurjchem-411	42	26	water	water	NOUN
eurjchem-411	42	27	and	and	CCONJ
eurjchem-411	42	28	with	with	ADP
eurjchem-411	42	29	cold	cold	ADJ
eurjchem-411	42	30	water	water	NOUN
eurjchem-411	42	31	,	,	PUNCT
eurjchem-411	42	32	and	and	CCONJ
eurjchem-411	42	33	dried	dry	VERB
eurjchem-411	42	34	.	.	PUNCT
eurjchem-411	43	1	recrystallization	recrystallization	NOUN
eurjchem-411	43	2	from	from	ADP
eurjchem-411	43	3	the	the	DET
eurjchem-411	43	4	appropriate	appropriate	ADJ
eurjchem-411	43	5	solvents	solvent	NOUN
eurjchem-411	43	6	gave	give	VERB
eurjchem-411	43	7	the	the	DET
eurjchem-411	43	8	azo	azo	NOUN
eurjchem-411	43	9	derivatives	derivative	NOUN
eurjchem-411	43	10	2b	2b	NOUN
eurjchem-411	43	11	(	(	PUNCT
eurjchem-411	43	12	0.62	0.62	NUM
eurjchem-411	43	13	g	g	NOUN
eurjchem-411	43	14	;	;	PUNCT
eurjchem-411	43	15	71	71	NUM
eurjchem-411	43	16	%	%	NOUN
eurjchem-411	43	17	)	)	PUNCT
eurjchem-411	43	18	,	,	PUNCT
eurjchem-411	43	19	2c	2c	NUM
eurjchem-411	43	20	(	(	PUNCT
eurjchem-411	43	21	0.59	0.59	NUM
eurjchem-411	43	22	g	g	NOUN
eurjchem-411	43	23	;	;	PUNCT
eurjchem-411	43	24	59	59	NUM
eurjchem-411	43	25	%	%	NOUN
eurjchem-411	43	26	)	)	PUNCT
eurjchem-411	43	27	and	and	CCONJ
eurjchem-411	43	28	2d	2d	NUM
eurjchem-411	43	29	(	(	PUNCT
eurjchem-411	43	30	0.47	0.47	NUM
eurjchem-411	43	31	g	g	NOUN
eurjchem-411	43	32	;	;	PUNCT
eurjchem-411	43	33	42	42	NUM
eurjchem-411	43	34	%	%	NOUN
eurjchem-411	43	35	)	)	PUNCT
eurjchem-411	43	36	,	,	PUNCT
eurjchem-411	43	37	respectively	respectively	ADV
eurjchem-411	43	38	(	(	PUNCT
eurjchem-411	43	39	scheme	scheme	NOUN
eurjchem-411	43	40	1	1	NUM
eurjchem-411	43	41	)	)	PUNCT
eurjchem-411	43	42	.	.	PUNCT
eurjchem-411	44	1	2.2.1.1	2.2.1.1	NUM
eurjchem-411	44	2	.	.	PUNCT
eurjchem-411	44	3	ethyl	ethyl	PROPN
eurjchem-411	44	4	2‐amino‐5‐(4‐methoxyphenylazo)‐4‐phenyl	2‐amino‐5‐(4‐methoxyphenylazo)‐4‐phenyl	NUM
eurjchem-411	44	5	thiophene‐3‐carboxylate	thiophene‐3‐carboxylate	NUM
eurjchem-411	44	6	(	(	PUNCT
eurjchem-411	44	7	2b	2b	NUM
eurjchem-411	44	8	)	)	PUNCT
eurjchem-411	44	9	this	this	DET
eurjchem-411	44	10	compound	compound	NOUN
eurjchem-411	44	11	was	be	AUX
eurjchem-411	44	12	obtained	obtain	VERB
eurjchem-411	44	13	as	as	ADP
eurjchem-411	44	14	a	a	DET
eurjchem-411	44	15	pale	pale	ADJ
eurjchem-411	44	16	yellow	yellow	ADJ
eurjchem-411	44	17	solid	solid	ADJ
eurjchem-411	44	18	(	(	PUNCT
eurjchem-411	44	19	etoh	etoh	NOUN
eurjchem-411	44	20	)	)	PUNCT
eurjchem-411	44	21	.	.	PUNCT
eurjchem-411	45	1	m.p	m.p	PROPN
eurjchem-411	45	2	.	.	PROPN
eurjchem-411	45	3	:	:	PUNCT
eurjchem-411	46	1	141‐142	141‐142	PROPN
eurjchem-411	46	2	c	c	ADJ
eurjchem-411	46	3	.	.	PUNCT
eurjchem-411	47	1	ir	ir	PROPN
eurjchem-411	47	2	(	(	PUNCT
eurjchem-411	47	3	ν	ν	NOUN
eurjchem-411	47	4	/	/	SYM
eurjchem-411	47	5	cm‐1	cm‐1	NOUN
eurjchem-411	47	6	):	):	PUNCT
eurjchem-411	47	7	3470	3470	NUM
eurjchem-411	47	8	,	,	PUNCT
eurjchem-411	47	9	3338	3338	NUM
eurjchem-411	47	10	(	(	PUNCT
eurjchem-411	47	11	nh2	nh2	PROPN
eurjchem-411	47	12	)	)	PUNCT
eurjchem-411	47	13	,	,	PUNCT
eurjchem-411	47	14	3046	3046	NUM
eurjchem-411	47	15	(	(	PUNCT
eurjchem-411	47	16	arom	arom	NOUN
eurjchem-411	47	17	ch	ch	NOUN
eurjchem-411	47	18	)	)	PUNCT
eurjchem-411	47	19	,	,	PUNCT
eurjchem-411	47	20	1672	1672	NUM
eurjchem-411	47	21	(	(	PUNCT
eurjchem-411	47	22	co	co	NOUN
eurjchem-411	47	23	)	)	PUNCT
eurjchem-411	47	24	.	.	PUNCT
eurjchem-411	48	1	1h	1h	NUM
eurjchem-411	48	2	nmr	nmr	NOUN
eurjchem-411	48	3	(	(	PUNCT
eurjchem-411	48	4	δ	δ	PROPN
eurjchem-411	48	5	ppm	ppm	PROPN
eurjchem-411	48	6	):	):	PUNCT
eurjchem-411	48	7	0.96	0.96	NUM
eurjchem-411	48	8	(	(	PUNCT
eurjchem-411	48	9	t	t	PROPN
eurjchem-411	48	10	,	,	PUNCT
eurjchem-411	48	11	3h	3h	NUM
eurjchem-411	48	12	,	,	PUNCT
eurjchem-411	48	13	j	j	PROPN
eurjchem-411	48	14	=	=	SYM
eurjchem-411	48	15	7.2	7.2	NUM
eurjchem-411	48	16	hz	hz	VERB
eurjchem-411	48	17	,	,	PUNCT
eurjchem-411	48	18	ester	ester	NOUN
eurjchem-411	48	19	me	i	PRON
eurjchem-411	48	20	)	)	PUNCT
eurjchem-411	48	21	,	,	PUNCT
eurjchem-411	48	22	3.85	3.85	NUM
eurjchem-411	48	23	(	(	PUNCT
eurjchem-411	48	24	s	s	PROPN
eurjchem-411	48	25	,	,	PUNCT
eurjchem-411	48	26	3h	3h	NUM
eurjchem-411	48	27	,	,	PUNCT
eurjchem-411	48	28	ome	ome	PROPN
eurjchem-411	48	29	)	)	PUNCT
eurjchem-411	48	30	,	,	PUNCT
eurjchem-411	48	31	4.16	4.16	NUM
eurjchem-411	48	32	(	(	PUNCT
eurjchem-411	48	33	q	q	NOUN
eurjchem-411	48	34	,	,	PUNCT
eurjchem-411	48	35	2h	2h	NUM
eurjchem-411	48	36	,	,	PUNCT
eurjchem-411	48	37	j	j	PROPN
eurjchem-411	48	38	=	=	SYM
eurjchem-411	48	39	7.2	7.2	NUM
eurjchem-411	48	40	hz	hz	NOUN
eurjchem-411	48	41	,	,	PUNCT
eurjchem-411	48	42	ester	ester	NOUN
eurjchem-411	48	43	ch2	ch2	PROPN
eurjchem-411	48	44	)	)	PUNCT
eurjchem-411	48	45	,	,	PUNCT
eurjchem-411	48	46	5.91	5.91	NUM
eurjchem-411	48	47	(	(	PUNCT
eurjchem-411	48	48	s	s	PROPN
eurjchem-411	48	49	,	,	PUNCT
eurjchem-411	48	50	br	br	PROPN
eurjchem-411	48	51	,	,	PUNCT
eurjchem-411	48	52	2h	2h	NUM
eurjchem-411	48	53	,	,	PUNCT
eurjchem-411	48	54	nh2	nh2	PROPN
eurjchem-411	48	55	,	,	PUNCT
eurjchem-411	48	56	d2o‐exchangeable	d2o‐exchangeable	PROPN
eurjchem-411	48	57	)	)	PUNCT
eurjchem-411	48	58	,	,	PUNCT
eurjchem-411	48	59	7.09‐7.46	7.09‐7.46	NUM
eurjchem-411	48	60	(	(	PUNCT
eurjchem-411	48	61	m	m	PROPN
eurjchem-411	48	62	,	,	PUNCT
eurjchem-411	48	63	9h	9h	NUM
eurjchem-411	48	64	,	,	PUNCT
eurjchem-411	48	65	phh	phh	PROPN
eurjchem-411	48	66	,	,	PUNCT
eurjchem-411	48	67	arh	arh	PROPN
eurjchem-411	48	68	)	)	PUNCT
eurjchem-411	48	69	.	.	PUNCT
eurjchem-411	49	1	anal	anal	PROPN
eurjchem-411	49	2	.	.	PUNCT
eurjchem-411	49	3	calcd	calcd	NOUN
eurjchem-411	49	4	.	.	PUNCT
eurjchem-411	50	1	for	for	SCONJ
eurjchem-411	50	2	c20h19n3o3s	c20h19n3o3s	NUM
eurjchem-411	50	3	(	(	PUNCT
eurjchem-411	50	4	381.448	381.448	NUM
eurjchem-411	50	5	):	):	PUNCT
eurjchem-411	50	6	c	c	X
eurjchem-411	50	7	,	,	PUNCT
eurjchem-411	50	8	62.97	62.97	NUM
eurjchem-411	50	9	;	;	PUNCT
eurjchem-411	50	10	h	h	NOUN
eurjchem-411	50	11	,	,	PUNCT
eurjchem-411	50	12	5.02	5.02	NUM
eurjchem-411	50	13	;	;	PUNCT
eurjchem-411	50	14	n	n	CCONJ
eurjchem-411	50	15	,	,	PUNCT
eurjchem-411	50	16	11.02	11.02	NUM
eurjchem-411	50	17	;	;	PUNCT
eurjchem-411	50	18	s	s	X
eurjchem-411	50	19	,	,	PUNCT
eurjchem-411	50	20	8.41	8.41	NUM
eurjchem-411	50	21	.	.	PUNCT
eurjchem-411	50	22	found	find	VERB
eurjchem-411	50	23	:	:	PUNCT
eurjchem-411	51	1	c	c	X
eurjchem-411	51	2	,	,	PUNCT
eurjchem-411	51	3	62.73	62.73	NUM
eurjchem-411	51	4	;	;	PUNCT
eurjchem-411	51	5	h	h	X
eurjchem-411	51	6	,	,	PUNCT
eurjchem-411	51	7	4.91	4.91	NUM
eurjchem-411	51	8	;	;	PUNCT
eurjchem-411	51	9	n	n	CCONJ
eurjchem-411	51	10	,	,	PUNCT
eurjchem-411	51	11	10.79	10.79	NUM
eurjchem-411	51	12	;	;	PUNCT
eurjchem-411	51	13	s	s	NOUN
eurjchem-411	51	14	,	,	PUNCT
eurjchem-411	51	15	8.32	8.32	NUM
eurjchem-411	51	16	%	%	NOUN
eurjchem-411	51	17	.	.	PUNCT
eurjchem-411	52	1	2.2.1.2	2.2.1.2	NUM
eurjchem-411	52	2	.	.	PUNCT
eurjchem-411	52	3	ethyl	ethyl	PROPN
eurjchem-411	52	4	2‐amino‐5‐[(3‐cyano‐4,5,6,7‐tetrahydrobenzo	2‐amino‐5‐[(3‐cyano‐4,5,6,7‐tetrahydrobenzo	NUM
eurjchem-411	53	1	[	[	X
eurjchem-411	53	2	b]thiophen‐2‐yl)azo]‐4‐phenylthiophene‐3‐carboxylate	b]thiophen‐2‐yl)azo]‐4‐phenylthiophene‐3‐carboxylate	NOUN
eurjchem-411	53	3	(	(	PUNCT
eurjchem-411	53	4	2c	2c	NUM
eurjchem-411	53	5	)	)	PUNCT
eurjchem-411	53	6	this	this	DET
eurjchem-411	53	7	compound	compound	NOUN
eurjchem-411	53	8	was	be	AUX
eurjchem-411	53	9	obtained	obtain	VERB
eurjchem-411	53	10	as	as	ADP
eurjchem-411	53	11	a	a	DET
eurjchem-411	53	12	brown	brown	ADJ
eurjchem-411	53	13	solid	solid	ADJ
eurjchem-411	53	14	(	(	PUNCT
eurjchem-411	53	15	dmf	dmf	PROPN
eurjchem-411	53	16	/	/	SYM
eurjchem-411	53	17	h2o	h2o	PROPN
eurjchem-411	53	18	)	)	PUNCT
eurjchem-411	53	19	.	.	PUNCT
eurjchem-411	54	1	m.p	m.p	PROPN
eurjchem-411	54	2	.	.	PROPN
eurjchem-411	54	3	:	:	PUNCT
eurjchem-411	55	1	185‐187	185‐187	NUM
eurjchem-411	55	2	c	c	NUM
eurjchem-411	55	3	.	.	PUNCT
eurjchem-411	56	1	ir	ir	PROPN
eurjchem-411	56	2	(	(	PUNCT
eurjchem-411	56	3	ν	ν	NOUN
eurjchem-411	56	4	/	/	SYM
eurjchem-411	56	5	cm‐1	cm‐1	NUM
eurjchem-411	56	6	):	):	PUNCT
eurjchem-411	56	7	3457	3457	NUM
eurjchem-411	56	8	,	,	PUNCT
eurjchem-411	56	9	3332	3332	NUM
eurjchem-411	56	10	(	(	PUNCT
eurjchem-411	56	11	nh2	nh2	PROPN
eurjchem-411	56	12	)	)	PUNCT
eurjchem-411	56	13	,	,	PUNCT
eurjchem-411	56	14	3050	3050	NUM
eurjchem-411	56	15	(	(	PUNCT
eurjchem-411	56	16	arom	arom	NOUN
eurjchem-411	56	17	ch	ch	NOUN
eurjchem-411	56	18	)	)	PUNCT
eurjchem-411	56	19	,	,	PUNCT
eurjchem-411	56	20	2227	2227	NUM
eurjchem-411	56	21	(	(	PUNCT
eurjchem-411	56	22	cn	cn	PROPN
eurjchem-411	56	23	)	)	PUNCT
eurjchem-411	56	24	,	,	PUNCT
eurjchem-411	56	25	1674	1674	NUM
eurjchem-411	56	26	(	(	PUNCT
eurjchem-411	56	27	co	co	NOUN
eurjchem-411	56	28	)	)	PUNCT
eurjchem-411	56	29	.	.	PUNCT
eurjchem-411	57	1	1h	1h	NUM
eurjchem-411	57	2	nmr	nmr	NOUN
eurjchem-411	57	3	(	(	PUNCT
eurjchem-411	57	4	δ	δ	PROPN
eurjchem-411	57	5	ppm	ppm	PROPN
eurjchem-411	57	6	):	):	PUNCT
eurjchem-411	57	7	1.13	1.13	NUM
eurjchem-411	57	8	(	(	PUNCT
eurjchem-411	57	9	t	t	PROPN
eurjchem-411	57	10	,	,	PUNCT
eurjchem-411	57	11	3h	3h	NUM
eurjchem-411	57	12	,	,	PUNCT
eurjchem-411	57	13	j	j	PROPN
eurjchem-411	57	14	=	=	SYM
eurjchem-411	57	15	7.2	7.2	NUM
eurjchem-411	57	16	hz	hz	VERB
eurjchem-411	57	17	,	,	PUNCT
eurjchem-411	57	18	ester	ester	NOUN
eurjchem-411	57	19	me	i	PRON
eurjchem-411	57	20	)	)	PUNCT
eurjchem-411	57	21	,	,	PUNCT
eurjchem-411	57	22	1.71‐1.85	1.71‐1.85	NUM
eurjchem-411	57	23	(	(	PUNCT
eurjchem-411	57	24	m	m	PROPN
eurjchem-411	57	25	,	,	PUNCT
eurjchem-411	57	26	4h	4h	NUM
eurjchem-411	57	27	,	,	PUNCT
eurjchem-411	57	28	2h‐5	2h‐5	NUM
eurjchem-411	57	29	,	,	PUNCT
eurjchem-411	57	30	2h‐6	2h‐6	NUM
eurjchem-411	57	31	)	)	PUNCT
eurjchem-411	57	32	,	,	PUNCT
eurjchem-411	57	33	2.44‐2.56	2.44‐2.56	NUM
eurjchem-411	57	34	(	(	PUNCT
eurjchem-411	57	35	m	m	PROPN
eurjchem-411	57	36	,	,	PUNCT
eurjchem-411	57	37	4h	4h	NUM
eurjchem-411	57	38	,	,	PUNCT
eurjchem-411	57	39	2h‐4	2h‐4	NUM
eurjchem-411	57	40	,	,	PUNCT
eurjchem-411	57	41	2h‐7	2h‐7	NOUN
eurjchem-411	57	42	)	)	PUNCT
eurjchem-411	57	43	,	,	PUNCT
eurjchem-411	57	44	4.09	4.09	NUM
eurjchem-411	57	45	(	(	PUNCT
eurjchem-411	57	46	q	q	NOUN
eurjchem-411	57	47	,	,	PUNCT
eurjchem-411	57	48	2h	2h	NUM
eurjchem-411	57	49	,	,	PUNCT
eurjchem-411	57	50	j	j	PROPN
eurjchem-411	57	51	=	=	SYM
eurjchem-411	57	52	7.2	7.2	NUM
eurjchem-411	57	53	hz	hz	NOUN
eurjchem-411	57	54	,	,	PUNCT
eurjchem-411	57	55	ester	ester	NOUN
eurjchem-411	57	56	ch2	ch2	PROPN
eurjchem-411	57	57	)	)	PUNCT
eurjchem-411	57	58	,	,	PUNCT
eurjchem-411	57	59	6.10	6.10	NUM
eurjchem-411	57	60	(	(	PUNCT
eurjchem-411	57	61	s	s	PROPN
eurjchem-411	57	62	,	,	PUNCT
eurjchem-411	57	63	br	br	PROPN
eurjchem-411	57	64	,	,	PUNCT
eurjchem-411	57	65	2h	2h	NUM
eurjchem-411	57	66	,	,	PUNCT
eurjchem-411	57	67	nh2	nh2	PROPN
eurjchem-411	57	68	,	,	PUNCT
eurjchem-411	57	69	d2o‐exchangeable	d2o‐exchangeable	PROPN
eurjchem-411	57	70	)	)	PUNCT
eurjchem-411	57	71	,	,	PUNCT
eurjchem-411	57	72	7.28‐7.39	7.28‐7.39	PROPN
eurjchem-411	57	73	(	(	PUNCT
eurjchem-411	57	74	m	m	PROPN
eurjchem-411	57	75	,	,	PUNCT
eurjchem-411	57	76	5h	5h	NUM
eurjchem-411	57	77	,	,	PUNCT
eurjchem-411	57	78	phh	phh	PROPN
eurjchem-411	57	79	)	)	PUNCT
eurjchem-411	57	80	.	.	PUNCT
eurjchem-411	58	1	anal	anal	PROPN
eurjchem-411	58	2	.	.	PUNCT
eurjchem-411	58	3	calcd	calcd	NOUN
eurjchem-411	58	4	.	.	PUNCT
eurjchem-411	59	1	for	for	ADP
eurjchem-411	59	2	c22h20n4o2s2	c22h20n4o2s2	NOUN
eurjchem-411	59	3	(	(	PUNCT
eurjchem-411	59	4	436.550	436.550	NUM
eurjchem-411	59	5	):	):	PUNCT
eurjchem-411	59	6	c	c	NOUN
eurjchem-411	59	7	,	,	PUNCT
eurjchem-411	59	8	60.53	60.53	NUM
eurjchem-411	59	9	;	;	PUNCT
eurjchem-411	59	10	h	h	NOUN
eurjchem-411	59	11	,	,	PUNCT
eurjchem-411	59	12	4.62	4.62	NUM
eurjchem-411	59	13	;	;	PUNCT
eurjchem-411	59	14	n	n	CCONJ
eurjchem-411	59	15	,	,	PUNCT
eurjchem-411	59	16	12.83	12.83	NUM
eurjchem-411	59	17	;	;	PUNCT
eurjchem-411	59	18	s	s	X
eurjchem-411	59	19	,	,	PUNCT
eurjchem-411	59	20	14.69	14.69	NUM
eurjchem-411	59	21	.	.	PUNCT
eurjchem-411	59	22	found	find	VERB
eurjchem-411	59	23	:	:	PUNCT
eurjchem-411	60	1	c	c	X
eurjchem-411	60	2	,	,	PUNCT
eurjchem-411	60	3	60.28	60.28	NUM
eurjchem-411	60	4	;	;	PUNCT
eurjchem-411	60	5	h	h	X
eurjchem-411	60	6	,	,	PUNCT
eurjchem-411	60	7	4.50	4.50	NUM
eurjchem-411	60	8	;	;	PUNCT
eurjchem-411	60	9	n	n	CCONJ
eurjchem-411	60	10	,	,	PUNCT
eurjchem-411	60	11	12.61	12.61	NUM
eurjchem-411	60	12	;	;	PUNCT
eurjchem-411	60	13	s	s	NOUN
eurjchem-411	60	14	,	,	PUNCT
eurjchem-411	60	15	14.52	14.52	NUM
eurjchem-411	60	16	%	%	NOUN
eurjchem-411	60	17	.	.	PUNCT
eurjchem-411	61	1	2.2.1.3	2.2.1.3	PROPN
eurjchem-411	61	2	.	.	PUNCT
eurjchem-411	62	1	ethyl	ethyl	PROPN
eurjchem-411	62	2	2‐[(5‐amino‐4‐(ethoxycarbonyl)‐3‐phenyl	2‐[(5‐amino‐4‐(ethoxycarbonyl)‐3‐phenyl	NUM
eurjchem-411	62	3	thiophen‐2‐yl)azo]‐4,5,6,7‐tetrahydrobenzo[b]thiophene‐3‐	thiophen‐2‐yl)azo]‐4,5,6,7‐tetrahydrobenzo[b]thiophene‐3‐	PROPN
eurjchem-411	62	4	carboxylate	carboxylate	NOUN
eurjchem-411	62	5	(	(	PUNCT
eurjchem-411	62	6	2d	2d	NOUN
eurjchem-411	62	7	)	)	PUNCT
eurjchem-411	62	8	this	this	DET
eurjchem-411	62	9	compound	compound	NOUN
eurjchem-411	62	10	was	be	AUX
eurjchem-411	62	11	obtained	obtain	VERB
eurjchem-411	62	12	as	as	ADP
eurjchem-411	62	13	a	a	DET
eurjchem-411	62	14	reddish	reddish	ADJ
eurjchem-411	62	15	brown	brown	ADJ
eurjchem-411	62	16	solid	solid	ADJ
eurjchem-411	62	17	(	(	PUNCT
eurjchem-411	62	18	1,4‐	1,4‐	NUM
eurjchem-411	62	19	dioxane	dioxane	NOUN
eurjchem-411	62	20	)	)	PUNCT
eurjchem-411	62	21	.	.	PUNCT
eurjchem-411	63	1	m.p	m.p	PROPN
eurjchem-411	63	2	.	.	PROPN
eurjchem-411	63	3	:	:	PUNCT
eurjchem-411	64	1	162	162	NUM
eurjchem-411	64	2	c	c	VERB
eurjchem-411	64	3	.	.	PUNCT
eurjchem-411	65	1	ir	ir	PROPN
eurjchem-411	65	2	(	(	PUNCT
eurjchem-411	65	3	ν	ν	NOUN
eurjchem-411	65	4	/	/	SYM
eurjchem-411	65	5	cm‐1	cm‐1	NUM
eurjchem-411	65	6	):	):	PUNCT
eurjchem-411	65	7	3463	3463	NUM
eurjchem-411	65	8	,	,	PUNCT
eurjchem-411	65	9	3345	3345	NUM
eurjchem-411	65	10	(	(	PUNCT
eurjchem-411	65	11	nh2	nh2	PROPN
eurjchem-411	65	12	)	)	PUNCT
eurjchem-411	65	13	,	,	PUNCT
eurjchem-411	65	14	3041	3041	NUM
eurjchem-411	65	15	(	(	PUNCT
eurjchem-411	65	16	arom	arom	NOUN
eurjchem-411	65	17	ch	ch	NOUN
eurjchem-411	65	18	)	)	PUNCT
eurjchem-411	65	19	,	,	PUNCT
eurjchem-411	65	20	1712	1712	NUM
eurjchem-411	65	21	,	,	PUNCT
eurjchem-411	65	22	1674	1674	NUM
eurjchem-411	65	23	(	(	PUNCT
eurjchem-411	65	24	2co	2co	NOUN
eurjchem-411	65	25	)	)	PUNCT
eurjchem-411	65	26	.	.	PUNCT
eurjchem-411	66	1	1h	1h	NUM
eurjchem-411	66	2	nmr	nmr	NOUN
eurjchem-411	66	3	(	(	PUNCT
eurjchem-411	66	4	δ	δ	PROPN
eurjchem-411	66	5	ppm	ppm	PROPN
eurjchem-411	66	6	):	):	PUNCT
eurjchem-411	66	7	1.07	1.07	NUM
eurjchem-411	66	8	(	(	PUNCT
eurjchem-411	66	9	t	t	PROPN
eurjchem-411	66	10	,	,	PUNCT
eurjchem-411	66	11	3h	3h	NUM
eurjchem-411	66	12	,	,	PUNCT
eurjchem-411	66	13	j	j	PROPN
eurjchem-411	66	14	=	=	SYM
eurjchem-411	66	15	7.2	7.2	NUM
eurjchem-411	66	16	hz	hz	VERB
eurjchem-411	66	17	,	,	PUNCT
eurjchem-411	66	18	ester	ester	NOUN
eurjchem-411	66	19	me	i	PRON
eurjchem-411	66	20	)	)	PUNCT
eurjchem-411	66	21	,	,	PUNCT
eurjchem-411	66	22	1.41	1.41	NUM
eurjchem-411	66	23	(	(	PUNCT
eurjchem-411	66	24	t	t	PROPN
eurjchem-411	66	25	,	,	PUNCT
eurjchem-411	66	26	3h	3h	NUM
eurjchem-411	66	27	,	,	PUNCT
eurjchem-411	66	28	j	j	PROPN
eurjchem-411	66	29	=	=	SYM
eurjchem-411	66	30	7.5	7.5	NUM
eurjchem-411	66	31	hz	hz	ADJ
eurjchem-411	66	32	,	,	PUNCT
eurjchem-411	66	33	ester	ester	NOUN
eurjchem-411	66	34	me	i	PRON
eurjchem-411	66	35	)	)	PUNCT
eurjchem-411	66	36	,	,	PUNCT
eurjchem-411	66	37	1.66‐1.79	1.66‐1.79	NUM
eurjchem-411	66	38	(	(	PUNCT
eurjchem-411	66	39	m	m	PROPN
eurjchem-411	66	40	,	,	PUNCT
eurjchem-411	66	41	4h	4h	NUM
eurjchem-411	66	42	,	,	PUNCT
eurjchem-411	66	43	2h‐5	2h‐5	NUM
eurjchem-411	66	44	,	,	PUNCT
eurjchem-411	66	45	2h‐6	2h‐6	NUM
eurjchem-411	66	46	)	)	PUNCT
eurjchem-411	66	47	,	,	PUNCT
eurjchem-411	66	48	2.45‐2.50	2.45‐2.50	NUM
eurjchem-411	66	49	(	(	PUNCT
eurjchem-411	66	50	m	m	PROPN
eurjchem-411	66	51	,	,	PUNCT
eurjchem-411	66	52	2h	2h	NUM
eurjchem-411	66	53	,	,	PUNCT
eurjchem-411	66	54	2h‐4	2h‐4	NUM
eurjchem-411	66	55	)	)	PUNCT
eurjchem-411	66	56	,	,	PUNCT
eurjchem-411	66	57	2.67‐2.72	2.67‐2.72	NUM
eurjchem-411	66	58	(	(	PUNCT
eurjchem-411	66	59	m	m	PROPN
eurjchem-411	66	60	,	,	PUNCT
eurjchem-411	66	61	2h	2h	NUM
eurjchem-411	66	62	,	,	PUNCT
eurjchem-411	66	63	2h‐	2h‐	NUM
eurjchem-411	66	64	7	7	NUM
eurjchem-411	66	65	)	)	PUNCT
eurjchem-411	66	66	,	,	PUNCT
eurjchem-411	66	67	4.13	4.13	NUM
eurjchem-411	66	68	(	(	PUNCT
eurjchem-411	66	69	q	q	NOUN
eurjchem-411	66	70	,	,	PUNCT
eurjchem-411	66	71	2h	2h	NUM
eurjchem-411	66	72	,	,	PUNCT
eurjchem-411	66	73	j	j	PROPN
eurjchem-411	66	74	=	=	SYM
eurjchem-411	66	75	7.2	7.2	NUM
eurjchem-411	66	76	hz	hz	NOUN
eurjchem-411	66	77	,	,	PUNCT
eurjchem-411	66	78	ester	ester	NOUN
eurjchem-411	66	79	ch2	ch2	PROPN
eurjchem-411	66	80	)	)	PUNCT
eurjchem-411	66	81	,	,	PUNCT
eurjchem-411	66	82	4.28	4.28	NUM
eurjchem-411	66	83	(	(	PUNCT
eurjchem-411	66	84	q	q	NOUN
eurjchem-411	66	85	,	,	PUNCT
eurjchem-411	66	86	2h	2h	NUM
eurjchem-411	66	87	,	,	PUNCT
eurjchem-411	66	88	j	j	PROPN
eurjchem-411	67	1	=	=	SYM
eurjchem-411	67	2	7.5	7.5	NUM
eurjchem-411	67	3	hz	hz	ADJ
eurjchem-411	67	4	,	,	PUNCT
eurjchem-411	67	5	ester	ester	NOUN
eurjchem-411	67	6	ch2	ch2	PROPN
eurjchem-411	67	7	)	)	PUNCT
eurjchem-411	67	8	,	,	PUNCT
eurjchem-411	67	9	5.82	5.82	NUM
eurjchem-411	67	10	(	(	PUNCT
eurjchem-411	67	11	s	s	PROPN
eurjchem-411	67	12	,	,	PUNCT
eurjchem-411	67	13	br	br	PROPN
eurjchem-411	67	14	,	,	PUNCT
eurjchem-411	67	15	2h	2h	NUM
eurjchem-411	67	16	,	,	PUNCT
eurjchem-411	67	17	nh2	nh2	PROPN
eurjchem-411	67	18	,	,	PUNCT
eurjchem-411	67	19	d2o‐exchangeable	d2o‐exchangeable	PROPN
eurjchem-411	67	20	)	)	PUNCT
eurjchem-411	67	21	,	,	PUNCT
eurjchem-411	67	22	7.26‐7.39	7.26‐7.39	NUM
eurjchem-411	67	23	(	(	PUNCT
eurjchem-411	67	24	m	m	PROPN
eurjchem-411	67	25	,	,	PUNCT
eurjchem-411	67	26	5h	5h	NUM
eurjchem-411	67	27	,	,	PUNCT
eurjchem-411	67	28	phh	phh	PROPN
eurjchem-411	67	29	)	)	PUNCT
eurjchem-411	67	30	.	.	PUNCT
eurjchem-411	68	1	anal	anal	PROPN
eurjchem-411	68	2	.	.	PUNCT
eurjchem-411	68	3	calcd	calcd	NOUN
eurjchem-411	68	4	.	.	PUNCT
eurjchem-411	69	1	for	for	ADP
eurjchem-411	69	2	c24h25n3o4s2	c24h25n3o4s2	NOUN
eurjchem-411	69	3	(	(	PUNCT
eurjchem-411	69	4	483.603	483.603	NUM
eurjchem-411	69	5	):	):	PUNCT
eurjchem-411	69	6	c	c	NOUN
eurjchem-411	69	7	,	,	PUNCT
eurjchem-411	69	8	59.61	59.61	NUM
eurjchem-411	69	9	;	;	PUNCT
eurjchem-411	69	10	h	h	NOUN
eurjchem-411	69	11	,	,	PUNCT
eurjchem-411	69	12	5.21	5.21	NUM
eurjchem-411	69	13	;	;	PUNCT
eurjchem-411	69	14	n	n	CCONJ
eurjchem-411	69	15	,	,	PUNCT
eurjchem-411	69	16	8.69	8.69	NUM
eurjchem-411	69	17	;	;	PUNCT
eurjchem-411	69	18	s	s	X
eurjchem-411	69	19	,	,	PUNCT
eurjchem-411	69	20	13.26	13.26	NUM
eurjchem-411	69	21	.	.	PUNCT
eurjchem-411	69	22	found	find	VERB
eurjchem-411	69	23	:	:	PUNCT
eurjchem-411	70	1	c	c	X
eurjchem-411	70	2	,	,	PUNCT
eurjchem-411	70	3	59.41	59.41	NUM
eurjchem-411	70	4	;	;	PUNCT
eurjchem-411	70	5	h	h	NOUN
eurjchem-411	70	6	,	,	PUNCT
eurjchem-411	70	7	5.06	5.06	NUM
eurjchem-411	70	8	;	;	PUNCT
eurjchem-411	70	9	n	n	CCONJ
eurjchem-411	70	10	,	,	PUNCT
eurjchem-411	70	11	8.51	8.51	NUM
eurjchem-411	70	12	;	;	PUNCT
eurjchem-411	70	13	s	s	X
eurjchem-411	70	14	,	,	PUNCT
eurjchem-411	70	15	13.03	13.03	NUM
eurjchem-411	70	16	%	%	NOUN
eurjchem-411	70	17	.	.	PUNCT
eurjchem-411	71	1	2.2.2	2.2.2	X
eurjchem-411	71	2	.	.	X
eurjchem-411	71	3	synthesis	synthesis	NOUN
eurjchem-411	71	4	of	of	ADP
eurjchem-411	71	5	2‐amino‐5‐(4‐methoxyphenylazo)‐4‐	2‐amino‐5‐(4‐methoxyphenylazo)‐4‐	NUM
eurjchem-411	71	6	phenylthiophene‐3‐carbohydrazide	phenylthiophene‐3‐carbohydrazide	NOUN
eurjchem-411	71	7	(	(	PUNCT
eurjchem-411	71	8	3	3	X
eurjchem-411	71	9	)	)	PUNCT
eurjchem-411	71	10	hydrazine	hydrazine	NOUN
eurjchem-411	71	11	hydrate	hydrate	NOUN
eurjchem-411	71	12	(	(	PUNCT
eurjchem-411	71	13	0.015	0.015	NUM
eurjchem-411	71	14	mol	mol	NOUN
eurjchem-411	71	15	)	)	PUNCT
eurjchem-411	71	16	was	be	AUX
eurjchem-411	71	17	added	add	VERB
eurjchem-411	71	18	to	to	ADP
eurjchem-411	71	19	a	a	DET
eurjchem-411	71	20	solution	solution	NOUN
eurjchem-411	71	21	of	of	ADP
eurjchem-411	71	22	compound	compound	NOUN
eurjchem-411	71	23	2b	2b	NOUN
eurjchem-411	71	24	(	(	PUNCT
eurjchem-411	71	25	0.003	0.003	NUM
eurjchem-411	71	26	mol	mol	NOUN
eurjchem-411	71	27	)	)	PUNCT
eurjchem-411	71	28	in	in	ADP
eurjchem-411	71	29	absolute	absolute	ADJ
eurjchem-411	71	30	ethanol	ethanol	NOUN
eurjchem-411	71	31	(	(	PUNCT
eurjchem-411	71	32	20	20	NUM
eurjchem-411	71	33	ml	ml	NOUN
eurjchem-411	71	34	)	)	PUNCT
eurjchem-411	71	35	.	.	PUNCT
eurjchem-411	72	1	the	the	DET
eurjchem-411	72	2	reaction	reaction	NOUN
eurjchem-411	72	3	mixture	mixture	NOUN
eurjchem-411	72	4	was	be	AUX
eurjchem-411	72	5	refluxed	refluxe	VERB
eurjchem-411	72	6	for	for	ADP
eurjchem-411	72	7	4	4	NUM
eurjchem-411	72	8	h	h	NOUN
eurjchem-411	72	9	,	,	PUNCT
eurjchem-411	72	10	concentrated	concentrate	VERB
eurjchem-411	72	11	in	in	ADP
eurjchem-411	72	12	vacuo	vacuo	PROPN
eurjchem-411	72	13	,	,	PUNCT
eurjchem-411	72	14	cooled	cool	VERB
eurjchem-411	72	15	and	and	CCONJ
eurjchem-411	72	16	diluted	dilute	VERB
eurjchem-411	72	17	with	with	ADP
eurjchem-411	72	18	water	water	NOUN
eurjchem-411	72	19	.	.	PUNCT
eurjchem-411	73	1	the	the	DET
eurjchem-411	73	2	obtained	obtain	VERB
eurjchem-411	73	3	precipitate	precipitate	NOUN
eurjchem-411	73	4	was	be	AUX
eurjchem-411	73	5	collected	collect	VERB
eurjchem-411	73	6	by	by	ADP
eurjchem-411	73	7	filtration	filtration	NOUN
eurjchem-411	73	8	,	,	PUNCT
eurjchem-411	73	9	washed	wash	VERB
eurjchem-411	73	10	with	with	ADP
eurjchem-411	73	11	cold	cold	ADJ
eurjchem-411	73	12	water	water	NOUN
eurjchem-411	73	13	,	,	PUNCT
eurjchem-411	73	14	dried	dry	VERB
eurjchem-411	73	15	and	and	CCONJ
eurjchem-411	73	16	purified	purify	VERB
eurjchem-411	73	17	by	by	ADP
eurjchem-411	73	18	recrystallization	recrystallization	NOUN
eurjchem-411	73	19	from	from	ADP
eurjchem-411	73	20	methanol	methanol	NOUN
eurjchem-411	73	21	to	to	PART
eurjchem-411	73	22	give	give	VERB
eurjchem-411	73	23	yellow	yellow	ADJ
eurjchem-411	73	24	crystals	crystal	NOUN
eurjchem-411	73	25	of	of	ADP
eurjchem-411	73	26	the	the	DET
eurjchem-411	73	27	title	title	NOUN
eurjchem-411	73	28	compound	compound	NOUN
eurjchem-411	73	29	3	3	NUM
eurjchem-411	73	30	(	(	PUNCT
eurjchem-411	73	31	0.71	0.71	NUM
eurjchem-411	73	32	g	g	NOUN
eurjchem-411	73	33	;	;	PUNCT
eurjchem-411	73	34	64	64	NUM
eurjchem-411	73	35	%	%	NOUN
eurjchem-411	73	36	)	)	PUNCT
eurjchem-411	73	37	(	(	PUNCT
eurjchem-411	73	38	scheme	scheme	NOUN
eurjchem-411	73	39	1	1	NUM
eurjchem-411	73	40	)	)	PUNCT
eurjchem-411	73	41	.	.	PUNCT
eurjchem-411	74	1	m.p	m.p	PROPN
eurjchem-411	74	2	.	.	PROPN
eurjchem-411	74	3	:	:	PUNCT
eurjchem-411	75	1	193‐194	193‐194	NUM
eurjchem-411	75	2	c	c	ADJ
eurjchem-411	75	3	.	.	PUNCT
eurjchem-411	76	1	ir	ir	PROPN
eurjchem-411	76	2	(	(	PUNCT
eurjchem-411	76	3	ν	ν	NOUN
eurjchem-411	76	4	/	/	SYM
eurjchem-411	76	5	cm‐1	cm‐1	NUM
eurjchem-411	76	6	):	):	PUNCT
eurjchem-411	76	7	3382‐3175	3382‐3175	PROPN
eurjchem-411	76	8	(	(	PUNCT
eurjchem-411	76	9	nh	nh	PROPN
eurjchem-411	76	10	,	,	PUNCT
eurjchem-411	76	11	nh2	nh2	PROPN
eurjchem-411	76	12	)	)	PUNCT
eurjchem-411	76	13	,	,	PUNCT
eurjchem-411	76	14	3056	3056	NUM
eurjchem-411	76	15	(	(	PUNCT
eurjchem-411	76	16	arom	arom	NOUN
eurjchem-411	76	17	ch	ch	NOUN
eurjchem-411	76	18	)	)	PUNCT
eurjchem-411	76	19	,	,	PUNCT
eurjchem-411	76	20	1660	1660	NUM
eurjchem-411	76	21	(	(	PUNCT
eurjchem-411	76	22	hydrazide	hydrazide	ADV
eurjchem-411	76	23	co	co	NOUN
eurjchem-411	76	24	)	)	PUNCT
eurjchem-411	76	25	.	.	PUNCT
eurjchem-411	77	1	1h	1h	NUM
eurjchem-411	77	2	nmr	nmr	NOUN
eurjchem-411	77	3	(	(	PUNCT
eurjchem-411	77	4	δ	δ	PROPN
eurjchem-411	77	5	ppm	ppm	PROPN
eurjchem-411	77	6	):	):	PUNCT
eurjchem-411	77	7	3.90	3.90	NUM
eurjchem-411	77	8	(	(	PUNCT
eurjchem-411	77	9	s	s	PROPN
eurjchem-411	77	10	,	,	PUNCT
eurjchem-411	77	11	3h	3h	NUM
eurjchem-411	77	12	,	,	PUNCT
eurjchem-411	77	13	ome	ome	PROPN
eurjchem-411	77	14	)	)	PUNCT
eurjchem-411	77	15	,	,	PUNCT
eurjchem-411	77	16	4.57	4.57	NUM
eurjchem-411	77	17	(	(	PUNCT
eurjchem-411	77	18	s	s	PROPN
eurjchem-411	77	19	,	,	PUNCT
eurjchem-411	77	20	2h	2h	NUM
eurjchem-411	77	21	,	,	PUNCT
eurjchem-411	77	22	hydrazide	hydrazide	ADJ
eurjchem-411	77	23	nh2	nh2	PROPN
eurjchem-411	77	24	,	,	PUNCT
eurjchem-411	77	25	d2o‐exchangeable	d2o‐exchangeable	PROPN
eurjchem-411	77	26	)	)	PUNCT
eurjchem-411	77	27	,	,	PUNCT
eurjchem-411	77	28	6.85	6.85	NUM
eurjchem-411	77	29	(	(	PUNCT
eurjchem-411	77	30	s	s	PROPN
eurjchem-411	77	31	,	,	PUNCT
eurjchem-411	77	32	2h	2h	NUM
eurjchem-411	77	33	,	,	PUNCT
eurjchem-411	77	34	nh2	nh2	PROPN
eurjchem-411	77	35	,	,	PUNCT
eurjchem-411	77	36	d2o‐exchangeable	d2o‐exchangeable	PROPN
eurjchem-411	77	37	)	)	PUNCT
eurjchem-411	77	38	,	,	PUNCT
eurjchem-411	77	39	7.14‐7.49	7.14‐7.49	NUM
eurjchem-411	77	40	(	(	PUNCT
eurjchem-411	77	41	m	m	PROPN
eurjchem-411	77	42	,	,	PUNCT
eurjchem-411	77	43	9h	9h	NUM
eurjchem-411	77	44	,	,	PUNCT
eurjchem-411	77	45	phh	phh	PROPN
eurjchem-411	77	46	,	,	PUNCT
eurjchem-411	77	47	arh	arh	PROPN
eurjchem-411	77	48	)	)	PUNCT
eurjchem-411	77	49	,	,	PUNCT
eurjchem-411	77	50	9.36	9.36	NUM
eurjchem-411	77	51	(	(	PUNCT
eurjchem-411	77	52	s	s	PROPN
eurjchem-411	77	53	,	,	PUNCT
eurjchem-411	77	54	1h	1h	NUM
eurjchem-411	77	55	,	,	PUNCT
eurjchem-411	77	56	nh	nh	PROPN
eurjchem-411	77	57	,	,	PUNCT
eurjchem-411	77	58	d2o‐exchangeable	d2o‐exchangeable	PROPN
eurjchem-411	77	59	)	)	PUNCT
eurjchem-411	77	60	.	.	PUNCT
eurjchem-411	78	1	ms	ms	NOUN
eurjchem-411	78	2	(	(	PUNCT
eurjchem-411	78	3	m	m	PROPN
eurjchem-411	78	4	/	/	SYM
eurjchem-411	78	5	z	z	NOUN
eurjchem-411	78	6	(	(	PUNCT
eurjchem-411	78	7	%	%	NOUN
eurjchem-411	78	8	)	)	PUNCT
eurjchem-411	78	9	):	):	PUNCT
eurjchem-411	78	10	367	367	NUM
eurjchem-411	78	11	(	(	PUNCT
eurjchem-411	78	12	m+	m+	NUM
eurjchem-411	78	13	,	,	PUNCT
eurjchem-411	78	14	17	17	NUM
eurjchem-411	78	15	%	%	NOUN
eurjchem-411	78	16	)	)	PUNCT
eurjchem-411	78	17	.	.	PUNCT
eurjchem-411	79	1	anal	anal	PROPN
eurjchem-411	79	2	.	.	PUNCT
eurjchem-411	79	3	calcd	calcd	NOUN
eurjchem-411	79	4	.	.	PUNCT
eurjchem-411	80	1	for	for	SCONJ
eurjchem-411	80	2	c18h17n5o2s	c18h17n5o2s	PROPN
eurjchem-411	80	3	(	(	PUNCT
eurjchem-411	80	4	367.425	367.425	NUM
eurjchem-411	80	5	):	):	PUNCT
eurjchem-411	80	6	c	c	NOUN
eurjchem-411	80	7	,	,	PUNCT
eurjchem-411	80	8	58.84	58.84	NUM
eurjchem-411	80	9	;	;	PUNCT
eurjchem-411	80	10	h	h	NOUN
eurjchem-411	80	11	,	,	PUNCT
eurjchem-411	80	12	4.66	4.66	NUM
eurjchem-411	80	13	;	;	PUNCT
eurjchem-411	80	14	n	n	CCONJ
eurjchem-411	80	15	,	,	PUNCT
eurjchem-411	80	16	19.06	19.06	NUM
eurjchem-411	80	17	;	;	PUNCT
eurjchem-411	80	18	s	s	X
eurjchem-411	80	19	,	,	PUNCT
eurjchem-411	80	20	8.73	8.73	NUM
eurjchem-411	80	21	.	.	PUNCT
eurjchem-411	80	22	found	find	VERB
eurjchem-411	80	23	:	:	PUNCT
eurjchem-411	81	1	c	c	X
eurjchem-411	81	2	,	,	PUNCT
eurjchem-411	81	3	58.62	58.62	NUM
eurjchem-411	81	4	;	;	PUNCT
eurjchem-411	81	5	h	h	NOUN
eurjchem-411	81	6	,	,	PUNCT
eurjchem-411	81	7	4.50	4.50	NUM
eurjchem-411	81	8	;	;	PUNCT
eurjchem-411	81	9	n	n	CCONJ
eurjchem-411	81	10	,	,	PUNCT
eurjchem-411	81	11	18.86	18.86	NUM
eurjchem-411	81	12	;	;	PUNCT
eurjchem-411	81	13	s	s	NOUN
eurjchem-411	81	14	,	,	PUNCT
eurjchem-411	81	15	8.61	8.61	NUM
eurjchem-411	81	16	%	%	NOUN
eurjchem-411	81	17	.	.	PUNCT
eurjchem-411	82	1	2.2.3	2.2.3	X
eurjchem-411	82	2	.	.	X
eurjchem-411	83	1	synthesis	synthesis	NOUN
eurjchem-411	83	2	of	of	ADP
eurjchem-411	83	3	3‐amino‐6‐(4‐methoxyphenylazo)‐5‐	3‐amino‐6‐(4‐methoxyphenylazo)‐5‐	NUM
eurjchem-411	83	4	phenyl‐2‐thioxo‐2,3‐dihydrothieno[2,3‐d]pyrimidin‐4(1h)‐	phenyl‐2‐thioxo‐2,3‐dihydrothieno[2,3‐d]pyrimidin‐4(1h)‐	NOUN
eurjchem-411	83	5	one	one	NUM
eurjchem-411	83	6	(	(	PUNCT
eurjchem-411	83	7	4	4	NUM
eurjchem-411	83	8	)	)	PUNCT
eurjchem-411	83	9	a	a	DET
eurjchem-411	83	10	mixture	mixture	NOUN
eurjchem-411	83	11	of	of	ADP
eurjchem-411	83	12	aminocarbohydrazide	aminocarbohydrazide	NOUN
eurjchem-411	83	13	3	3	NUM
eurjchem-411	83	14	(	(	PUNCT
eurjchem-411	83	15	0.002	0.002	NUM
eurjchem-411	83	16	mol	mol	NOUN
eurjchem-411	83	17	)	)	PUNCT
eurjchem-411	83	18	and	and	CCONJ
eurjchem-411	83	19	thiourea	thiourea	NOUN
eurjchem-411	83	20	(	(	PUNCT
eurjchem-411	83	21	1.0	1.0	NUM
eurjchem-411	83	22	g	g	NOUN
eurjchem-411	83	23	)	)	PUNCT
eurjchem-411	83	24	was	be	AUX
eurjchem-411	83	25	dissolved	dissolve	VERB
eurjchem-411	83	26	in	in	ADP
eurjchem-411	83	27	dimethylformamide	dimethylformamide	NOUN
eurjchem-411	83	28	(	(	PUNCT
eurjchem-411	83	29	30	30	NUM
eurjchem-411	83	30	ml	ml	NOUN
eurjchem-411	83	31	)	)	PUNCT
eurjchem-411	83	32	and	and	CCONJ
eurjchem-411	83	33	refluxed	refluxe	VERB
eurjchem-411	83	34	for	for	ADP
eurjchem-411	83	35	4	4	NUM
eurjchem-411	83	36	h.	h.	NOUN
eurjchem-411	83	37	after	after	ADP
eurjchem-411	83	38	cooling	cool	VERB
eurjchem-411	83	39	to	to	ADP
eurjchem-411	83	40	room	room	NOUN
eurjchem-411	83	41	temperature	temperature	NOUN
eurjchem-411	83	42	,	,	PUNCT
eurjchem-411	83	43	the	the	DET
eurjchem-411	83	44	reaction	reaction	NOUN
eurjchem-411	83	45	mixture	mixture	NOUN
eurjchem-411	83	46	was	be	AUX
eurjchem-411	83	47	poured	pour	VERB
eurjchem-411	83	48	over	over	ADP
eurjchem-411	83	49	iced	iced	ADJ
eurjchem-411	83	50	water	water	NOUN
eurjchem-411	83	51	.	.	PUNCT
eurjchem-411	84	1	the	the	DET
eurjchem-411	84	2	resulting	result	VERB
eurjchem-411	84	3	precipitate	precipitate	NOUN
eurjchem-411	84	4	of	of	ADP
eurjchem-411	84	5	solid	solid	ADJ
eurjchem-411	84	6	product	product	NOUN
eurjchem-411	84	7	was	be	AUX
eurjchem-411	84	8	collected	collect	VERB
eurjchem-411	84	9	by	by	ADP
eurjchem-411	84	10	filtration	filtration	NOUN
eurjchem-411	84	11	and	and	CCONJ
eurjchem-411	84	12	recrystallized	recrystallize	VERB
eurjchem-411	84	13	from	from	ADP
eurjchem-411	84	14	aqueous	aqueous	ADJ
eurjchem-411	84	15	dimethylformamide	dimethylformamide	NOUN
eurjchem-411	84	16	to	to	PART
eurjchem-411	84	17	give	give	VERB
eurjchem-411	84	18	the	the	DET
eurjchem-411	84	19	corresponding	correspond	VERB
eurjchem-411	84	20	thienopyrimidinone	thienopyrimidinone	ADJ
eurjchem-411	84	21	derivative	derivative	ADJ
eurjchem-411	84	22	4	4	NUM
eurjchem-411	84	23	as	as	ADP
eurjchem-411	84	24	a	a	DET
eurjchem-411	84	25	light	light	ADJ
eurjchem-411	84	26	brown	brown	ADJ
eurjchem-411	84	27	solid	solid	ADJ
eurjchem-411	84	28	(	(	PUNCT
eurjchem-411	84	29	0.63	0.63	NUM
eurjchem-411	84	30	g	g	NOUN
eurjchem-411	84	31	;	;	PUNCT
eurjchem-411	84	32	77	77	NUM
eurjchem-411	84	33	%	%	NOUN
eurjchem-411	84	34	)	)	PUNCT
eurjchem-411	84	35	(	(	PUNCT
eurjchem-411	84	36	scheme	scheme	NOUN
eurjchem-411	84	37	1	1	NUM
eurjchem-411	84	38	)	)	PUNCT
eurjchem-411	84	39	.	.	PUNCT
eurjchem-411	85	1	m.p	m.p	PROPN
eurjchem-411	85	2	.	.	PROPN
eurjchem-411	85	3	:	:	PUNCT
eurjchem-411	86	1	219‐221	219‐221	NUM
eurjchem-411	86	2	c	c	ADJ
eurjchem-411	86	3	.	.	PUNCT
eurjchem-411	87	1	ir	ir	PROPN
eurjchem-411	87	2	(	(	PUNCT
eurjchem-411	87	3	ν	ν	NOUN
eurjchem-411	87	4	/	/	SYM
eurjchem-411	87	5	cm‐1	cm‐1	NUM
eurjchem-411	87	6	):	):	PUNCT
eurjchem-411	87	7	3310‐3204	3310‐3204	PROPN
eurjchem-411	87	8	(	(	PUNCT
eurjchem-411	87	9	nh	nh	PROPN
eurjchem-411	87	10	,	,	PUNCT
eurjchem-411	87	11	nh2	nh2	PROPN
eurjchem-411	87	12	)	)	PUNCT
eurjchem-411	87	13	,	,	PUNCT
eurjchem-411	87	14	3059	3059	NUM
eurjchem-411	87	15	(	(	PUNCT
eurjchem-411	87	16	arom	arom	NOUN
eurjchem-411	87	17	ch	ch	NOUN
eurjchem-411	87	18	)	)	PUNCT
eurjchem-411	87	19	,	,	PUNCT
eurjchem-411	87	20	1687	1687	NUM
eurjchem-411	87	21	(	(	PUNCT
eurjchem-411	87	22	co	co	NOUN
eurjchem-411	87	23	)	)	PUNCT
eurjchem-411	87	24	,	,	PUNCT
eurjchem-411	87	25	1425	1425	NUM
eurjchem-411	87	26	(	(	PUNCT
eurjchem-411	87	27	cs	cs	PROPN
eurjchem-411	87	28	)	)	PUNCT
eurjchem-411	87	29	.	.	PUNCT
eurjchem-411	88	1	1h	1h	NUM
eurjchem-411	88	2	nmr	nmr	NOUN
eurjchem-411	88	3	(	(	PUNCT
eurjchem-411	88	4	δ	δ	PROPN
eurjchem-411	88	5	ppm	ppm	PROPN
eurjchem-411	88	6	):	):	PUNCT
eurjchem-411	88	7	3.87	3.87	NUM
eurjchem-411	88	8	(	(	PUNCT
eurjchem-411	88	9	s	s	PROPN
eurjchem-411	88	10	,	,	PUNCT
eurjchem-411	88	11	3h	3h	NUM
eurjchem-411	88	12	,	,	PUNCT
eurjchem-411	88	13	ome	ome	PROPN
eurjchem-411	88	14	)	)	PUNCT
eurjchem-411	88	15	,	,	PUNCT
eurjchem-411	88	16	6.20	6.20	NUM
eurjchem-411	88	17	(	(	PUNCT
eurjchem-411	88	18	s	s	PROPN
eurjchem-411	88	19	,	,	PUNCT
eurjchem-411	88	20	2h	2h	NUM
eurjchem-411	88	21	,	,	PUNCT
eurjchem-411	88	22	nh2	nh2	PROPN
eurjchem-411	88	23	,	,	PUNCT
eurjchem-411	88	24	d2o‐exchangeable	d2o‐exchangeable	PROPN
eurjchem-411	88	25	)	)	PUNCT
eurjchem-411	88	26	,	,	PUNCT
eurjchem-411	88	27	7.20‐7.51	7.20‐7.51	PROPN
eurjchem-411	88	28	(	(	PUNCT
eurjchem-411	88	29	m	m	PROPN
eurjchem-411	88	30	,	,	PUNCT
eurjchem-411	88	31	9h	9h	NUM
eurjchem-411	88	32	,	,	PUNCT
eurjchem-411	88	33	phh	phh	PROPN
eurjchem-411	88	34	,	,	PUNCT
eurjchem-411	88	35	arh	arh	PROPN
eurjchem-411	88	36	)	)	PUNCT
eurjchem-411	88	37	,	,	PUNCT
eurjchem-411	88	38	12.58	12.58	NUM
eurjchem-411	88	39	(	(	PUNCT
eurjchem-411	88	40	s	s	PROPN
eurjchem-411	88	41	,	,	PUNCT
eurjchem-411	88	42	br	br	PROPN
eurjchem-411	88	43	,	,	PUNCT
eurjchem-411	88	44	1h	1h	NUM
eurjchem-411	88	45	,	,	PUNCT
eurjchem-411	88	46	nh	nh	PROPN
eurjchem-411	88	47	,	,	PUNCT
eurjchem-411	88	48	d2o‐exchangeable	d2o‐exchangeable	PROPN
eurjchem-411	88	49	)	)	PUNCT
eurjchem-411	88	50	.	.	PUNCT
eurjchem-411	89	1	13c	13c	NOUN
eurjchem-411	89	2	nmr	nmr	NOUN
eurjchem-411	89	3	(	(	PUNCT
eurjchem-411	89	4	δ	δ	PROPN
eurjchem-411	89	5	ppm	ppm	NOUN
eurjchem-411	89	6	):	):	PUNCT
eurjchem-411	89	7	54.7	54.7	NUM
eurjchem-411	89	8	(	(	PUNCT
eurjchem-411	89	9	ome	ome	PROPN
eurjchem-411	89	10	)	)	PUNCT
eurjchem-411	89	11	,	,	PUNCT
eurjchem-411	89	12	115.1	115.1	NUM
eurjchem-411	89	13	,	,	PUNCT
eurjchem-411	89	14	118.7	118.7	NUM
eurjchem-411	89	15	,	,	PUNCT
eurjchem-411	89	16	125.1	125.1	NUM
eurjchem-411	89	17	,	,	PUNCT
eurjchem-411	89	18	127.3	127.3	NUM
eurjchem-411	89	19	,	,	PUNCT
eurjchem-411	89	20	128.9	128.9	NUM
eurjchem-411	89	21	,	,	PUNCT
eurjchem-411	89	22	129.5	129.5	NUM
eurjchem-411	89	23	,	,	PUNCT
eurjchem-411	89	24	132.5	132.5	NUM
eurjchem-411	89	25	,	,	PUNCT
eurjchem-411	89	26	134.6	134.6	NUM
eurjchem-411	89	27	,	,	PUNCT
eurjchem-411	89	28	140.7	140.7	NUM
eurjchem-411	89	29	,	,	PUNCT
eurjchem-411	89	30	152.8	152.8	NUM
eurjchem-411	89	31	,	,	PUNCT
eurjchem-411	89	32	153.2	153.2	NUM
eurjchem-411	89	33	,	,	PUNCT
eurjchem-411	89	34	158.3	158.3	NUM
eurjchem-411	89	35	(	(	PUNCT
eurjchem-411	89	36	co	co	NOUN
eurjchem-411	89	37	)	)	PUNCT
eurjchem-411	89	38	,	,	PUNCT
eurjchem-411	89	39	159.2	159.2	NUM
eurjchem-411	89	40	(	(	PUNCT
eurjchem-411	89	41	c‐ome	c‐ome	PROPN
eurjchem-411	89	42	)	)	PUNCT
eurjchem-411	89	43	,	,	PUNCT
eurjchem-411	89	44	172.6	172.6	NUM
eurjchem-411	89	45	(	(	PUNCT
eurjchem-411	89	46	cs	cs	PROPN
eurjchem-411	89	47	)	)	PUNCT
eurjchem-411	89	48	.	.	PUNCT
eurjchem-411	90	1	anal	anal	PROPN
eurjchem-411	90	2	.	.	PUNCT
eurjchem-411	90	3	calcd	calcd	NOUN
eurjchem-411	90	4	.	.	PUNCT
eurjchem-411	91	1	for	for	ADP
eurjchem-411	91	2	c19h15n5o2s2	c19h15n5o2s2	PROPN
eurjchem-411	91	3	(	(	PUNCT
eurjchem-411	91	4	409.485	409.485	NUM
eurjchem-411	91	5	):	):	PUNCT
eurjchem-411	91	6	c	c	NOUN
eurjchem-411	91	7	,	,	PUNCT
eurjchem-411	91	8	55.73	55.73	NUM
eurjchem-411	91	9	;	;	PUNCT
eurjchem-411	91	10	h	h	NOUN
eurjchem-411	91	11	,	,	PUNCT
eurjchem-411	91	12	3.69	3.69	NUM
eurjchem-411	91	13	;	;	PUNCT
eurjchem-411	91	14	n	n	CCONJ
eurjchem-411	91	15	,	,	PUNCT
eurjchem-411	91	16	17.10	17.10	NUM
eurjchem-411	91	17	;	;	PUNCT
eurjchem-411	91	18	s	s	NUM
eurjchem-411	91	19	,	,	PUNCT
eurjchem-411	91	20	15.66	15.66	NUM
eurjchem-411	91	21	.	.	PUNCT
eurjchem-411	92	1	found	find	VERB
eurjchem-411	92	2	:	:	PUNCT
eurjchem-411	93	1	c	c	X
eurjchem-411	93	2	,	,	PUNCT
eurjchem-411	93	3	55.56	55.56	NUM
eurjchem-411	93	4	;	;	PUNCT
eurjchem-411	93	5	h	h	NOUN
eurjchem-411	93	6	,	,	PUNCT
eurjchem-411	93	7	3.50	3.50	NUM
eurjchem-411	93	8	;	;	PUNCT
eurjchem-411	93	9	n	n	CCONJ
eurjchem-411	93	10	,	,	PUNCT
eurjchem-411	93	11	16.89	16.89	NUM
eurjchem-411	93	12	;	;	PUNCT
eurjchem-411	93	13	s	s	NOUN
eurjchem-411	93	14	,	,	PUNCT
eurjchem-411	93	15	15.52	15.52	NUM
eurjchem-411	93	16	%	%	NOUN
eurjchem-411	93	17	.	.	PUNCT
eurjchem-411	94	1	2.2.4	2.2.4	X
eurjchem-411	94	2	.	.	X
eurjchem-411	94	3	synthesis	synthesis	NOUN
eurjchem-411	94	4	of	of	ADP
eurjchem-411	94	5	5‐[2‐amino‐5‐(4‐methoxyphenylazo)‐4‐	5‐[2‐amino‐5‐(4‐methoxyphenylazo)‐4‐	NUM
eurjchem-411	94	6	phenylthiophen‐3‐yl]‐1,3,4‐oxadiazole‐2(3h)‐thione	phenylthiophen‐3‐yl]‐1,3,4‐oxadiazole‐2(3h)‐thione	NOUN
eurjchem-411	94	7	(	(	PUNCT
eurjchem-411	94	8	5	5	NUM
eurjchem-411	94	9	)	)	PUNCT
eurjchem-411	94	10	potassium	potassium	NOUN
eurjchem-411	94	11	hydroxide	hydroxide	NOUN
eurjchem-411	94	12	(	(	PUNCT
eurjchem-411	94	13	0.005	0.005	NUM
eurjchem-411	94	14	mol	mol	NOUN
eurjchem-411	94	15	)	)	PUNCT
eurjchem-411	94	16	was	be	AUX
eurjchem-411	94	17	dissolved	dissolve	VERB
eurjchem-411	94	18	in	in	ADP
eurjchem-411	94	19	ethanol	ethanol	NOUN
eurjchem-411	94	20	(	(	PUNCT
eurjchem-411	94	21	5	5	NUM
eurjchem-411	94	22	ml	ml	NOUN
eurjchem-411	94	23	)	)	PUNCT
eurjchem-411	94	24	and	and	CCONJ
eurjchem-411	94	25	carbon	carbon	NOUN
eurjchem-411	94	26	disulfide	disulfide	NOUN
eurjchem-411	94	27	(	(	PUNCT
eurjchem-411	94	28	0.017	0.017	NUM
eurjchem-411	94	29	mol	mol	NOUN
eurjchem-411	94	30	)	)	PUNCT
eurjchem-411	94	31	was	be	AUX
eurjchem-411	94	32	added	add	VERB
eurjchem-411	94	33	to	to	ADP
eurjchem-411	94	34	the	the	DET
eurjchem-411	94	35	solution	solution	NOUN
eurjchem-411	94	36	,	,	PUNCT
eurjchem-411	94	37	and	and	CCONJ
eurjchem-411	94	38	the	the	DET
eurjchem-411	94	39	reaction	reaction	NOUN
eurjchem-411	94	40	content	content	NOUN
eurjchem-411	94	41	was	be	AUX
eurjchem-411	94	42	stirred	stir	VERB
eurjchem-411	94	43	at	at	ADP
eurjchem-411	94	44	room	room	NOUN
eurjchem-411	94	45	temperature	temperature	NOUN
eurjchem-411	94	46	for	for	ADP
eurjchem-411	94	47	15	15	NUM
eurjchem-411	94	48	min	min	NOUN
eurjchem-411	94	49	.	.	PROPN
eurjchem-411	95	1	then	then	ADV
eurjchem-411	95	2	,	,	PUNCT
eurjchem-411	95	3	hydrazide	hydrazide	ADV
eurjchem-411	95	4	3	3	NUM
eurjchem-411	95	5	(	(	PUNCT
eurjchem-411	95	6	0.005	0.005	NUM
eurjchem-411	95	7	mol	mol	NOUN
eurjchem-411	95	8	)	)	PUNCT
eurjchem-411	95	9	in	in	ADP
eurjchem-411	95	10	ethanol	ethanol	NOUN
eurjchem-411	95	11	(	(	PUNCT
eurjchem-411	95	12	5	5	NUM
eurjchem-411	95	13	ml	ml	NOUN
eurjchem-411	95	14	)	)	PUNCT
eurjchem-411	95	15	was	be	AUX
eurjchem-411	95	16	added	add	VERB
eurjchem-411	95	17	and	and	CCONJ
eurjchem-411	95	18	the	the	DET
eurjchem-411	95	19	reaction	reaction	NOUN
eurjchem-411	95	20	mixture	mixture	NOUN
eurjchem-411	95	21	was	be	AUX
eurjchem-411	95	22	heated	heat	VERB
eurjchem-411	95	23	under	under	ADP
eurjchem-411	95	24	reflux	reflux	NOUN
eurjchem-411	95	25	with	with	ADP
eurjchem-411	95	26	stirring	stir	VERB
eurjchem-411	95	27	until	until	ADP
eurjchem-411	95	28	the	the	DET
eurjchem-411	95	29	evolution	evolution	NOUN
eurjchem-411	95	30	of	of	ADP
eurjchem-411	95	31	hydrogen	hydrogen	NOUN
eurjchem-411	95	32	216	216	NUM
eurjchem-411	95	33	gaber	gaber	NOUN
eurjchem-411	95	34	and	and	CCONJ
eurjchem-411	95	35	bagley	bagley	NOUN
eurjchem-411	95	36	/	/	SYM
eurjchem-411	95	37	european	european	PROPN
eurjchem-411	95	38	journal	journal	PROPN
eurjchem-411	95	39	of	of	ADP
eurjchem-411	95	40	chemistry	chemistry	NOUN
eurjchem-411	95	41	2	2	NUM
eurjchem-411	95	42	(	(	PUNCT
eurjchem-411	95	43	2	2	NUM
eurjchem-411	95	44	)	)	PUNCT
eurjchem-411	95	45	(	(	PUNCT
eurjchem-411	95	46	2011	2011	NUM
eurjchem-411	95	47	)	)	PUNCT
eurjchem-411	95	48	214‐222	214‐222	PROPN
eurjchem-411	95	49	s	s	PART
eurjchem-411	95	50	co2etph	co2etph	PROPN
eurjchem-411	95	51	nh2	nh2	PROPN
eurjchem-411	95	52	s	s	PART
eurjchem-411	95	53	co2etph	co2etph	PROPN
eurjchem-411	95	54	nh2n	nh2n	PROPN
eurjchem-411	95	55	s	s	PART
eurjchem-411	95	56	conhnh2ph	conhnh2ph	NOUN
eurjchem-411	95	57	nh2r	nh2r	PROPN
eurjchem-411	95	58	1	1	NUM
eurjchem-411	95	59	3	3	NUM
eurjchem-411	95	60	reagents	reagent	NOUN
eurjchem-411	95	61	and	and	CCONJ
eurjchem-411	95	62	conditions	condition	NOUN
eurjchem-411	95	63	:	:	PUNCT
eurjchem-411	95	64	(	(	PUNCT
eurjchem-411	95	65	a	a	X
eurjchem-411	95	66	)	)	PUNCT
eurjchem-411	95	67	arn2cl	arn2cl	PROPN
eurjchem-411	95	68	/	/	SYM
eurjchem-411	95	69	etoh	etoh	NOUN
eurjchem-411	95	70	/	/	SYM
eurjchem-411	95	71	acona/0	acona/0	NOUN
eurjchem-411	95	72	-	-	SYM
eurjchem-411	95	73	5	5	NUM
eurjchem-411	95	74	oc	oc	NOUN
eurjchem-411	95	75	;	;	PUNCT
eurjchem-411	95	76	(	(	PUNCT
eurjchem-411	95	77	b	b	X
eurjchem-411	95	78	)	)	PUNCT
eurjchem-411	95	79	n2h4.h2o	n2h4.h2o	NOUN
eurjchem-411	95	80	/	/	SYM
eurjchem-411	95	81	etoh/	etoh/	NUM
eurjchem-411	95	82	;	;	PUNCT
eurjchem-411	95	83	(	(	PUNCT
eurjchem-411	95	84	c	c	X
eurjchem-411	95	85	)	)	PUNCT
eurjchem-411	95	86	cs2	cs2	NOUN
eurjchem-411	95	87	/	/	SYM
eurjchem-411	95	88	koh	koh	PROPN
eurjchem-411	95	89	/	/	SYM
eurjchem-411	95	90	etoh/	etoh/	PROPN
eurjchem-411	95	91	then	then	ADV
eurjchem-411	95	92	hcl	hcl	PROPN
eurjchem-411	95	93	;	;	PUNCT
eurjchem-411	95	94	(	(	PUNCT
eurjchem-411	95	95	d	d	X
eurjchem-411	95	96	)	)	PUNCT
eurjchem-411	95	97	cs(nh2)2	cs(nh2)2	NOUN
eurjchem-411	95	98	/	/	SYM
eurjchem-411	95	99	dmf/	dmf/	PROPN
eurjchem-411	95	100	d	d	NOUN
eurjchem-411	95	101	2a	2a	NUM
eurjchem-411	95	102	-	-	SYM
eurjchem-411	95	103	d	d	X
eurjchem-411	95	104	2b	2b	NUM
eurjchem-411	95	105	b	b	NOUN
eurjchem-411	95	106	r	r	NOUN
eurjchem-411	95	107	=	=	NOUN
eurjchem-411	95	108	nmeo	nmeo	NOUN
eurjchem-411	95	109	n	n	NOUN
eurjchem-411	95	110	s	s	PART
eurjchem-411	95	111	cn	cn	PROPN
eurjchem-411	95	112	s	s	PROPN
eurjchem-411	95	113	co2et	co2et	VERB
eurjchem-411	95	114	b	b	NOUN
eurjchem-411	95	115	,	,	PUNCT
eurjchem-411	95	116	ar	ar	PROPN
eurjchem-411	95	117	=	=	SYM
eurjchem-411	95	118	p	p	PROPN
eurjchem-411	95	119	-	-	PUNCT
eurjchem-411	95	120	meoph	meoph	ADJ
eurjchem-411	95	121	c	c	NOUN
eurjchem-411	95	122	,	,	PUNCT
eurjchem-411	95	123	ar	ar	PROPN
eurjchem-411	95	124	=	=	SYM
eurjchem-411	95	125	d	d	PROPN
eurjchem-411	95	126	,	,	PUNCT
eurjchem-411	95	127	ar	ar	PROPN
eurjchem-411	95	128	=	=	NOUN
eurjchem-411	95	129	;	;	PUNCT
eurjchem-411	95	130	;	;	PUNCT
eurjchem-411	95	131	4	4	NUM
eurjchem-411	95	132	5	5	NUM
eurjchem-411	95	133	s	s	PART
eurjchem-411	95	134	ph	ph	NOUN
eurjchem-411	95	135	nh2r	nh2r	PROPN
eurjchem-411	95	136	o	o	NOUN
eurjchem-411	95	137	h	h	NOUN
eurjchem-411	95	138	n	n	CCONJ
eurjchem-411	95	139	n	n	PROPN
eurjchem-411	95	140	s	s	NOUN
eurjchem-411	95	141	s	s	NOUN
eurjchem-411	95	142	ph	ph	NOUN
eurjchem-411	95	143	r	r	NOUN
eurjchem-411	95	144	n	n	NOUN
eurjchem-411	95	145	h	h	NOUN
eurjchem-411	95	146	n	n	ADV
eurjchem-411	95	147	o	o	NOUN
eurjchem-411	95	148	nh2	nh2	PROPN
eurjchem-411	95	149	s	s	VERB
eurjchem-411	95	150	a	a	PRON
eurjchem-411	95	151	3	3	NUM
eurjchem-411	95	152	cc	cc	NOUN
eurjchem-411	95	153	a	a	PRON
eurjchem-411	95	154	,	,	PUNCT
eurjchem-411	95	155	ar	ar	NOUN
eurjchem-411	95	156	=	=	NOUN
eurjchem-411	95	157	ph	ph	ADJ
eurjchem-411	95	158	;	;	PUNCT
eurjchem-411	95	159	nar	nar	NOUN
eurjchem-411	95	160	scheme	scheme	NOUN
eurjchem-411	95	161	1	1	NUM
eurjchem-411	95	162	sulfide	sulfide	NOUN
eurjchem-411	95	163	stopped	stop	VERB
eurjchem-411	95	164	(	(	PUNCT
eurjchem-411	95	165	~12	~12	NUM
eurjchem-411	95	166	h	h	NOUN
eurjchem-411	95	167	)	)	PUNCT
eurjchem-411	95	168	.	.	PUNCT
eurjchem-411	96	1	most	most	ADJ
eurjchem-411	96	2	of	of	ADP
eurjchem-411	96	3	the	the	DET
eurjchem-411	96	4	solvent	solvent	NOUN
eurjchem-411	96	5	was	be	AUX
eurjchem-411	96	6	removed	remove	VERB
eurjchem-411	96	7	under	under	ADP
eurjchem-411	96	8	reduced	reduce	VERB
eurjchem-411	96	9	pressure	pressure	NOUN
eurjchem-411	96	10	and	and	CCONJ
eurjchem-411	96	11	the	the	DET
eurjchem-411	96	12	residue	residue	NOUN
eurjchem-411	96	13	was	be	AUX
eurjchem-411	96	14	dissolved	dissolve	VERB
eurjchem-411	96	15	in	in	ADP
eurjchem-411	96	16	water	water	NOUN
eurjchem-411	96	17	(	(	PUNCT
eurjchem-411	96	18	2	2	NUM
eurjchem-411	96	19	ml	ml	NOUN
eurjchem-411	96	20	)	)	PUNCT
eurjchem-411	96	21	and	and	CCONJ
eurjchem-411	96	22	carefully	carefully	ADV
eurjchem-411	96	23	acidified	acidify	VERB
eurjchem-411	96	24	with	with	ADP
eurjchem-411	96	25	concentrated	concentrated	ADJ
eurjchem-411	96	26	hydrochloric	hydrochloric	ADJ
eurjchem-411	96	27	acid	acid	NOUN
eurjchem-411	96	28	(	(	PUNCT
eurjchem-411	96	29	0.5	0.5	NUM
eurjchem-411	96	30	ml	ml	NOUN
eurjchem-411	96	31	)	)	PUNCT
eurjchem-411	96	32	.	.	PUNCT
eurjchem-411	97	1	the	the	DET
eurjchem-411	97	2	resulting	result	VERB
eurjchem-411	97	3	precipitate	precipitate	NOUN
eurjchem-411	97	4	was	be	AUX
eurjchem-411	97	5	collected	collect	VERB
eurjchem-411	97	6	by	by	ADP
eurjchem-411	97	7	filtration	filtration	NOUN
eurjchem-411	97	8	,	,	PUNCT
eurjchem-411	97	9	washed	wash	VERB
eurjchem-411	97	10	with	with	ADP
eurjchem-411	97	11	cold	cold	ADJ
eurjchem-411	97	12	water	water	NOUN
eurjchem-411	97	13	and	and	CCONJ
eurjchem-411	97	14	air‐dried	air‐drie	VERB
eurjchem-411	97	15	.	.	PUNCT
eurjchem-411	98	1	recrystallization	recrystallization	NOUN
eurjchem-411	98	2	from	from	ADP
eurjchem-411	98	3	ethanol	ethanol	NOUN
eurjchem-411	98	4	gave	give	VERB
eurjchem-411	98	5	the	the	DET
eurjchem-411	98	6	1,3,4‐oxadiazole‐2‐	1,3,4‐oxadiazole‐2‐	NUM
eurjchem-411	98	7	thione	thione	NOUN
eurjchem-411	98	8	derivative	derivative	ADJ
eurjchem-411	98	9	5	5	NUM
eurjchem-411	98	10	as	as	ADP
eurjchem-411	98	11	a	a	DET
eurjchem-411	98	12	yellow	yellow	ADJ
eurjchem-411	98	13	solid	solid	ADJ
eurjchem-411	98	14	(	(	PUNCT
eurjchem-411	98	15	0.82	0.82	NUM
eurjchem-411	98	16	g	g	NOUN
eurjchem-411	98	17	;	;	PUNCT
eurjchem-411	98	18	40	40	NUM
eurjchem-411	98	19	%	%	NOUN
eurjchem-411	98	20	)	)	PUNCT
eurjchem-411	98	21	(	(	PUNCT
eurjchem-411	98	22	scheme	scheme	NOUN
eurjchem-411	98	23	1	1	NUM
eurjchem-411	98	24	)	)	PUNCT
eurjchem-411	98	25	.	.	PUNCT
eurjchem-411	99	1	m.p	m.p	PROPN
eurjchem-411	99	2	.	.	PROPN
eurjchem-411	99	3	:	:	PUNCT
eurjchem-411	99	4	171‐172	171‐172	NUM
eurjchem-411	99	5	c	c	VERB
eurjchem-411	99	6	.	.	PUNCT
eurjchem-411	100	1	ir	ir	PROPN
eurjchem-411	100	2	(	(	PUNCT
eurjchem-411	100	3	ν	ν	NOUN
eurjchem-411	100	4	/	/	SYM
eurjchem-411	100	5	cm‐1	cm‐1	NOUN
eurjchem-411	100	6	):	):	PUNCT
eurjchem-411	100	7	3300‐3136	3300‐3136	NUM
eurjchem-411	100	8	(	(	PUNCT
eurjchem-411	100	9	nh	nh	PROPN
eurjchem-411	100	10	,	,	PUNCT
eurjchem-411	100	11	nh2	nh2	PROPN
eurjchem-411	100	12	)	)	PUNCT
eurjchem-411	100	13	,	,	PUNCT
eurjchem-411	100	14	3060	3060	NUM
eurjchem-411	100	15	(	(	PUNCT
eurjchem-411	100	16	arom	arom	NOUN
eurjchem-411	100	17	ch	ch	NOUN
eurjchem-411	100	18	)	)	PUNCT
eurjchem-411	100	19	,	,	PUNCT
eurjchem-411	100	20	1471	1471	NUM
eurjchem-411	100	21	(	(	PUNCT
eurjchem-411	100	22	cs	cs	PROPN
eurjchem-411	100	23	)	)	PUNCT
eurjchem-411	100	24	,	,	PUNCT
eurjchem-411	100	25	1070	1070	NUM
eurjchem-411	100	26	(	(	PUNCT
eurjchem-411	100	27	c‐o‐c	c‐o‐c	NOUN
eurjchem-411	100	28	)	)	PUNCT
eurjchem-411	100	29	.	.	PUNCT
eurjchem-411	101	1	1h	1h	NUM
eurjchem-411	101	2	nmr	nmr	NOUN
eurjchem-411	101	3	(	(	PUNCT
eurjchem-411	101	4	δ	δ	PROPN
eurjchem-411	101	5	ppm	ppm	PROPN
eurjchem-411	101	6	):	):	PUNCT
eurjchem-411	101	7	3.88	3.88	NUM
eurjchem-411	101	8	(	(	PUNCT
eurjchem-411	101	9	s	s	PROPN
eurjchem-411	101	10	,	,	PUNCT
eurjchem-411	101	11	3h	3h	NUM
eurjchem-411	101	12	,	,	PUNCT
eurjchem-411	101	13	ome	ome	PROPN
eurjchem-411	101	14	)	)	PUNCT
eurjchem-411	101	15	,	,	PUNCT
eurjchem-411	101	16	6.34	6.34	NUM
eurjchem-411	101	17	(	(	PUNCT
eurjchem-411	101	18	s	s	PROPN
eurjchem-411	101	19	,	,	PUNCT
eurjchem-411	101	20	2h	2h	NUM
eurjchem-411	101	21	,	,	PUNCT
eurjchem-411	101	22	nh2	nh2	PROPN
eurjchem-411	101	23	,	,	PUNCT
eurjchem-411	101	24	d2o‐exchangeable	d2o‐exchangeable	PROPN
eurjchem-411	101	25	)	)	PUNCT
eurjchem-411	101	26	,	,	PUNCT
eurjchem-411	101	27	7.12‐7.45	7.12‐7.45	NUM
eurjchem-411	101	28	(	(	PUNCT
eurjchem-411	101	29	m	m	PROPN
eurjchem-411	101	30	,	,	PUNCT
eurjchem-411	101	31	9h	9h	NUM
eurjchem-411	101	32	,	,	PUNCT
eurjchem-411	101	33	phh	phh	PROPN
eurjchem-411	101	34	,	,	PUNCT
eurjchem-411	101	35	arh	arh	PROPN
eurjchem-411	101	36	)	)	PUNCT
eurjchem-411	101	37	,	,	PUNCT
eurjchem-411	101	38	13.65	13.65	NUM
eurjchem-411	101	39	(	(	PUNCT
eurjchem-411	101	40	s	s	PROPN
eurjchem-411	101	41	,	,	PUNCT
eurjchem-411	101	42	br	br	PROPN
eurjchem-411	101	43	,	,	PUNCT
eurjchem-411	101	44	1h	1h	NUM
eurjchem-411	101	45	,	,	PUNCT
eurjchem-411	101	46	nh	nh	PROPN
eurjchem-411	101	47	,	,	PUNCT
eurjchem-411	101	48	d2o‐exchangeable	d2o‐exchangeable	PROPN
eurjchem-411	101	49	)	)	PUNCT
eurjchem-411	101	50	.	.	PUNCT
eurjchem-411	102	1	13c	13c	NOUN
eurjchem-411	102	2	nmr	nmr	NOUN
eurjchem-411	102	3	(	(	PUNCT
eurjchem-411	102	4	δ	δ	PROPN
eurjchem-411	102	5	ppm	ppm	PROPN
eurjchem-411	102	6	):	):	PUNCT
eurjchem-411	102	7	55.0	55.0	NUM
eurjchem-411	102	8	(	(	PUNCT
eurjchem-411	102	9	ome	ome	PROPN
eurjchem-411	102	10	)	)	PUNCT
eurjchem-411	102	11	,	,	PUNCT
eurjchem-411	102	12	111.3	111.3	NUM
eurjchem-411	102	13	,	,	PUNCT
eurjchem-411	102	14	114.8	114.8	NUM
eurjchem-411	102	15	,	,	PUNCT
eurjchem-411	102	16	125.2	125.2	NUM
eurjchem-411	102	17	,	,	PUNCT
eurjchem-411	102	18	127.4	127.4	NUM
eurjchem-411	102	19	,	,	PUNCT
eurjchem-411	102	20	128.7	128.7	NUM
eurjchem-411	102	21	,	,	PUNCT
eurjchem-411	102	22	129.4	129.4	NUM
eurjchem-411	102	23	,	,	PUNCT
eurjchem-411	102	24	131.7	131.7	NUM
eurjchem-411	102	25	,	,	PUNCT
eurjchem-411	102	26	134.9	134.9	NUM
eurjchem-411	102	27	,	,	PUNCT
eurjchem-411	102	28	140.5	140.5	NUM
eurjchem-411	102	29	,	,	PUNCT
eurjchem-411	102	30	153.0	153.0	NUM
eurjchem-411	102	31	,	,	PUNCT
eurjchem-411	102	32	159.1	159.1	NUM
eurjchem-411	102	33	(	(	PUNCT
eurjchem-411	102	34	c‐ome	c‐ome	NOUN
eurjchem-411	102	35	)	)	PUNCT
eurjchem-411	102	36	,	,	PUNCT
eurjchem-411	102	37	160.8	160.8	NUM
eurjchem-411	102	38	,	,	PUNCT
eurjchem-411	102	39	161.3	161.3	NUM
eurjchem-411	102	40	(	(	PUNCT
eurjchem-411	102	41	thiophene	thiophene	NOUN
eurjchem-411	102	42	c‐2	c‐2	NOUN
eurjchem-411	102	43	,	,	PUNCT
eurjchem-411	102	44	oxadiazole	oxadiazole	NOUN
eurjchem-411	102	45	c‐5	c‐5	NOUN
eurjchem-411	102	46	)	)	PUNCT
eurjchem-411	102	47	,	,	PUNCT
eurjchem-411	102	48	177.5	177.5	NUM
eurjchem-411	102	49	(	(	PUNCT
eurjchem-411	102	50	cs	cs	PROPN
eurjchem-411	102	51	)	)	PUNCT
eurjchem-411	102	52	.	.	PUNCT
eurjchem-411	103	1	anal	anal	PROPN
eurjchem-411	103	2	.	.	PUNCT
eurjchem-411	103	3	calcd	calcd	NOUN
eurjchem-411	103	4	.	.	PUNCT
eurjchem-411	104	1	for	for	ADP
eurjchem-411	104	2	c19h15n5o2s2	c19h15n5o2s2	PROPN
eurjchem-411	104	3	(	(	PUNCT
eurjchem-411	104	4	409.485	409.485	NUM
eurjchem-411	104	5	):	):	PUNCT
eurjchem-411	104	6	c	c	NOUN
eurjchem-411	104	7	,	,	PUNCT
eurjchem-411	104	8	55.73	55.73	NUM
eurjchem-411	104	9	;	;	PUNCT
eurjchem-411	104	10	h	h	NOUN
eurjchem-411	104	11	,	,	PUNCT
eurjchem-411	104	12	3.69	3.69	NUM
eurjchem-411	104	13	;	;	PUNCT
eurjchem-411	104	14	n	n	CCONJ
eurjchem-411	104	15	,	,	PUNCT
eurjchem-411	104	16	17.10	17.10	NUM
eurjchem-411	104	17	;	;	PUNCT
eurjchem-411	104	18	s	s	NUM
eurjchem-411	104	19	,	,	PUNCT
eurjchem-411	104	20	15.66	15.66	NUM
eurjchem-411	104	21	.	.	PUNCT
eurjchem-411	105	1	found	find	VERB
eurjchem-411	105	2	:	:	PUNCT
eurjchem-411	106	1	c	c	X
eurjchem-411	106	2	,	,	PUNCT
eurjchem-411	106	3	55.49	55.49	NUM
eurjchem-411	106	4	;	;	PUNCT
eurjchem-411	106	5	h	h	NOUN
eurjchem-411	106	6	,	,	PUNCT
eurjchem-411	106	7	3.46	3.46	NUM
eurjchem-411	106	8	;	;	PUNCT
eurjchem-411	106	9	n	n	CCONJ
eurjchem-411	106	10	,	,	PUNCT
eurjchem-411	106	11	16.94	16.94	NUM
eurjchem-411	106	12	;	;	PUNCT
eurjchem-411	106	13	s	s	PROPN
eurjchem-411	106	14	,	,	PUNCT
eurjchem-411	106	15	15.49	15.49	NUM
eurjchem-411	106	16	%	%	NOUN
eurjchem-411	106	17	.	.	PUNCT
eurjchem-411	107	1	2.2.5	2.2.5	X
eurjchem-411	107	2	.	.	X
eurjchem-411	108	1	synthesis	synthesis	NOUN
eurjchem-411	108	2	of	of	ADP
eurjchem-411	108	3	6‐(4‐methoxyphenylazo)‐3,7‐diphenyl‐2‐	6‐(4‐methoxyphenylazo)‐3,7‐diphenyl‐2‐	NUM
eurjchem-411	108	4	thioxo‐2,3‐dihydrothieno[2,3‐d][1,2,4]triazolo[1,5‐a	thioxo‐2,3‐dihydrothieno[2,3‐d][1,2,4]triazolo[1,5‐a	NOUN
eurjchem-411	108	5	]	]	X
eurjchem-411	108	6	pyrimidin‐8(1h)‐one	pyrimidin‐8(1h)‐one	NOUN
eurjchem-411	108	7	(	(	PUNCT
eurjchem-411	108	8	8)	8)	NUM
eurjchem-411	108	9	to	to	ADP
eurjchem-411	108	10	a	a	DET
eurjchem-411	108	11	solution	solution	NOUN
eurjchem-411	108	12	of	of	ADP
eurjchem-411	108	13	compound	compound	NOUN
eurjchem-411	108	14	4	4	NUM
eurjchem-411	108	15	(	(	PUNCT
eurjchem-411	108	16	0.002	0.002	NUM
eurjchem-411	108	17	mol	mol	NOUN
eurjchem-411	108	18	)	)	PUNCT
eurjchem-411	108	19	in	in	ADP
eurjchem-411	108	20	ethanolic	ethanolic	ADJ
eurjchem-411	108	21	sodium	sodium	NOUN
eurjchem-411	108	22	ethoxide	ethoxide	NOUN
eurjchem-411	108	23	[	[	X
eurjchem-411	108	24	prepared	prepare	VERB
eurjchem-411	108	25	by	by	ADP
eurjchem-411	108	26	dissolving	dissolve	VERB
eurjchem-411	108	27	sodium	sodium	NOUN
eurjchem-411	108	28	metal	metal	NOUN
eurjchem-411	108	29	(	(	PUNCT
eurjchem-411	108	30	0.002	0.002	NUM
eurjchem-411	108	31	mol	mol	NOUN
eurjchem-411	108	32	)	)	PUNCT
eurjchem-411	108	33	in	in	ADP
eurjchem-411	108	34	absolute	absolute	ADJ
eurjchem-411	108	35	ethanol	ethanol	NOUN
eurjchem-411	108	36	(	(	PUNCT
eurjchem-411	108	37	25	25	NUM
eurjchem-411	108	38	ml	ml	NOUN
eurjchem-411	108	39	)	)	PUNCT
eurjchem-411	108	40	]	]	PUNCT
eurjchem-411	108	41	,	,	PUNCT
eurjchem-411	108	42	phenyl	phenyl	NOUN
eurjchem-411	108	43	isothiocyanate	isothiocyanate	NOUN
eurjchem-411	108	44	(	(	PUNCT
eurjchem-411	108	45	0.002	0.002	NUM
eurjchem-411	108	46	mol	mol	NOUN
eurjchem-411	108	47	)	)	PUNCT
eurjchem-411	108	48	was	be	AUX
eurjchem-411	108	49	added	add	VERB
eurjchem-411	108	50	dropwise	dropwise	NOUN
eurjchem-411	108	51	.	.	PUNCT
eurjchem-411	109	1	the	the	DET
eurjchem-411	109	2	mixture	mixture	NOUN
eurjchem-411	109	3	was	be	AUX
eurjchem-411	109	4	refluxed	refluxe	VERB
eurjchem-411	109	5	with	with	ADP
eurjchem-411	109	6	stirring	stir	VERB
eurjchem-411	109	7	for	for	ADP
eurjchem-411	109	8	10	10	NUM
eurjchem-411	109	9	h	h	NOUN
eurjchem-411	109	10	and	and	CCONJ
eurjchem-411	109	11	then	then	ADV
eurjchem-411	109	12	left	leave	VERB
eurjchem-411	109	13	to	to	PART
eurjchem-411	109	14	cool	cool	VERB
eurjchem-411	109	15	to	to	PART
eurjchem-411	109	16	room	room	VERB
eurjchem-411	109	17	temperature	temperature	NOUN
eurjchem-411	109	18	overnight	overnight	ADV
eurjchem-411	109	19	under	under	ADP
eurjchem-411	109	20	stirring	stirring	NOUN
eurjchem-411	109	21	.	.	PUNCT
eurjchem-411	110	1	the	the	DET
eurjchem-411	110	2	reaction	reaction	NOUN
eurjchem-411	110	3	mixture	mixture	NOUN
eurjchem-411	110	4	was	be	AUX
eurjchem-411	110	5	then	then	ADV
eurjchem-411	110	6	poured	pour	VERB
eurjchem-411	110	7	onto	onto	ADP
eurjchem-411	110	8	iced	iced	ADJ
eurjchem-411	110	9	water	water	NOUN
eurjchem-411	110	10	and	and	CCONJ
eurjchem-411	110	11	neutralized	neutralize	VERB
eurjchem-411	110	12	with	with	ADP
eurjchem-411	110	13	dilute	dilute	VERB
eurjchem-411	110	14	hydrochloric	hydrochloric	ADJ
eurjchem-411	110	15	acid	acid	NOUN
eurjchem-411	110	16	,	,	PUNCT
eurjchem-411	110	17	whereby	whereby	SCONJ
eurjchem-411	110	18	the	the	DET
eurjchem-411	110	19	resulting	result	VERB
eurjchem-411	110	20	solid	solid	ADJ
eurjchem-411	110	21	product	product	NOUN
eurjchem-411	110	22	was	be	AUX
eurjchem-411	110	23	filtered	filter	VERB
eurjchem-411	110	24	off	off	ADP
eurjchem-411	110	25	,	,	PUNCT
eurjchem-411	110	26	dried	dry	VERB
eurjchem-411	110	27	and	and	CCONJ
eurjchem-411	110	28	recrystallized	recrystallize	VERB
eurjchem-411	110	29	from	from	ADP
eurjchem-411	110	30	dimethylformamide	dimethylformamide	NOUN
eurjchem-411	110	31	to	to	PART
eurjchem-411	110	32	give	give	VERB
eurjchem-411	110	33	the	the	DET
eurjchem-411	110	34	triazole‐2‐	triazole‐2‐	NOUN
eurjchem-411	110	35	thione	thione	NOUN
eurjchem-411	110	36	derivative	derivative	ADJ
eurjchem-411	110	37	8	8	NUM
eurjchem-411	110	38	as	as	ADP
eurjchem-411	110	39	a	a	DET
eurjchem-411	110	40	dark	dark	ADJ
eurjchem-411	110	41	brown	brown	ADJ
eurjchem-411	110	42	solid	solid	ADJ
eurjchem-411	110	43	(	(	PUNCT
eurjchem-411	110	44	0.57	0.57	NUM
eurjchem-411	110	45	g	g	NOUN
eurjchem-411	110	46	;	;	PUNCT
eurjchem-411	110	47	56	56	NUM
eurjchem-411	110	48	%	%	NOUN
eurjchem-411	110	49	)	)	PUNCT
eurjchem-411	110	50	(	(	PUNCT
eurjchem-411	110	51	scheme	scheme	NOUN
eurjchem-411	110	52	2	2	NUM
eurjchem-411	110	53	)	)	PUNCT
eurjchem-411	110	54	.	.	PUNCT
eurjchem-411	111	1	m.p	m.p	PROPN
eurjchem-411	111	2	.	.	PROPN
eurjchem-411	111	3	:	:	PUNCT
eurjchem-411	111	4	270‐271	270‐271	NUM
eurjchem-411	111	5	c	c	ADJ
eurjchem-411	111	6	.	.	PUNCT
eurjchem-411	112	1	ir	ir	PROPN
eurjchem-411	112	2	(	(	PUNCT
eurjchem-411	112	3	ν	ν	NOUN
eurjchem-411	112	4	/	/	SYM
eurjchem-411	112	5	cm‐1	cm‐1	NUM
eurjchem-411	112	6	):	):	PUNCT
eurjchem-411	112	7	3207	3207	NUM
eurjchem-411	112	8	(	(	PUNCT
eurjchem-411	112	9	nh	nh	NOUN
eurjchem-411	112	10	)	)	PUNCT
eurjchem-411	112	11	,	,	PUNCT
eurjchem-411	112	12	3066	3066	NUM
eurjchem-411	112	13	(	(	PUNCT
eurjchem-411	112	14	arom	arom	NOUN
eurjchem-411	112	15	ch	ch	NOUN
eurjchem-411	112	16	)	)	PUNCT
eurjchem-411	112	17	,	,	PUNCT
eurjchem-411	112	18	1685	1685	NUM
eurjchem-411	112	19	(	(	PUNCT
eurjchem-411	112	20	co	co	NOUN
eurjchem-411	112	21	)	)	PUNCT
eurjchem-411	112	22	,	,	PUNCT
eurjchem-411	112	23	1397	1397	NUM
eurjchem-411	112	24	(	(	PUNCT
eurjchem-411	112	25	cs	cs	PROPN
eurjchem-411	112	26	)	)	PUNCT
eurjchem-411	112	27	cm‐1	cm‐1	PROPN
eurjchem-411	112	28	.	.	PUNCT
eurjchem-411	113	1	1h	1h	NUM
eurjchem-411	113	2	nmr	nmr	NOUN
eurjchem-411	113	3	(	(	PUNCT
eurjchem-411	113	4	δ	δ	PROPN
eurjchem-411	113	5	ppm	ppm	PROPN
eurjchem-411	113	6	):	):	PUNCT
eurjchem-411	113	7	3.87	3.87	NUM
eurjchem-411	113	8	(	(	PUNCT
eurjchem-411	113	9	s	s	PROPN
eurjchem-411	113	10	,	,	PUNCT
eurjchem-411	113	11	3h	3h	NUM
eurjchem-411	113	12	,	,	PUNCT
eurjchem-411	113	13	ome	ome	PROPN
eurjchem-411	113	14	)	)	PUNCT
eurjchem-411	113	15	,	,	PUNCT
eurjchem-411	113	16	6.91‐7.56	6.91‐7.56	NUM
eurjchem-411	113	17	(	(	PUNCT
eurjchem-411	113	18	m	m	PROPN
eurjchem-411	113	19	,	,	PUNCT
eurjchem-411	113	20	14h	14h	NUM
eurjchem-411	113	21	,	,	PUNCT
eurjchem-411	113	22	2phh	2phh	PROPN
eurjchem-411	113	23	,	,	PUNCT
eurjchem-411	113	24	arh	arh	ADJ
eurjchem-411	113	25	)	)	PUNCT
eurjchem-411	113	26	,	,	PUNCT
eurjchem-411	113	27	13.97	13.97	NUM
eurjchem-411	113	28	(	(	PUNCT
eurjchem-411	113	29	s	s	PROPN
eurjchem-411	113	30	,	,	PUNCT
eurjchem-411	113	31	1h	1h	NUM
eurjchem-411	113	32	,	,	PUNCT
eurjchem-411	113	33	nh	nh	PROPN
eurjchem-411	113	34	,	,	PUNCT
eurjchem-411	113	35	d2o‐exchangeable	d2o‐exchangeable	PROPN
eurjchem-411	113	36	)	)	PUNCT
eurjchem-411	113	37	.	.	PUNCT
eurjchem-411	114	1	13c	13c	NOUN
eurjchem-411	114	2	nmr	nmr	NOUN
eurjchem-411	114	3	(	(	PUNCT
eurjchem-411	114	4	δ	δ	PROPN
eurjchem-411	114	5	ppm	ppm	NOUN
eurjchem-411	114	6	):	):	PUNCT
eurjchem-411	114	7	54.7	54.7	NUM
eurjchem-411	114	8	(	(	PUNCT
eurjchem-411	114	9	ome	ome	PROPN
eurjchem-411	114	10	)	)	PUNCT
eurjchem-411	114	11	,	,	PUNCT
eurjchem-411	114	12	114.6	114.6	NUM
eurjchem-411	114	13	,	,	PUNCT
eurjchem-411	114	14	119.0	119.0	NUM
eurjchem-411	114	15	,	,	PUNCT
eurjchem-411	114	16	125.4	125.4	NUM
eurjchem-411	114	17	,	,	PUNCT
eurjchem-411	114	18	127.2	127.2	NUM
eurjchem-411	114	19	,	,	PUNCT
eurjchem-411	114	20	127.6	127.6	NUM
eurjchem-411	114	21	,	,	PUNCT
eurjchem-411	114	22	128.5	128.5	NUM
eurjchem-411	114	23	,	,	PUNCT
eurjchem-411	114	24	128.8	128.8	NUM
eurjchem-411	114	25	,	,	PUNCT
eurjchem-411	114	26	129.1	129.1	NUM
eurjchem-411	114	27	,	,	PUNCT
eurjchem-411	114	28	129.6	129.6	NUM
eurjchem-411	114	29	,	,	PUNCT
eurjchem-411	114	30	132.5	132.5	NUM
eurjchem-411	114	31	,	,	PUNCT
eurjchem-411	114	32	133.1	133.1	NUM
eurjchem-411	114	33	,	,	PUNCT
eurjchem-411	114	34	134.7	134.7	NUM
eurjchem-411	114	35	,	,	PUNCT
eurjchem-411	114	36	140.8	140.8	NUM
eurjchem-411	114	37	,	,	PUNCT
eurjchem-411	114	38	152.6	152.6	NUM
eurjchem-411	114	39	,	,	PUNCT
eurjchem-411	114	40	153.3	153.3	NUM
eurjchem-411	114	41	,	,	PUNCT
eurjchem-411	114	42	157.0	157.0	NUM
eurjchem-411	114	43	,	,	PUNCT
eurjchem-411	114	44	158.7	158.7	NUM
eurjchem-411	114	45	(	(	PUNCT
eurjchem-411	114	46	co	co	NOUN
eurjchem-411	114	47	)	)	PUNCT
eurjchem-411	114	48	,	,	PUNCT
eurjchem-411	114	49	159.5	159.5	NUM
eurjchem-411	114	50	(	(	PUNCT
eurjchem-411	114	51	c‐ome	c‐ome	NOUN
eurjchem-411	114	52	)	)	PUNCT
eurjchem-411	114	53	,	,	PUNCT
eurjchem-411	114	54	173.2	173.2	NUM
eurjchem-411	114	55	(	(	PUNCT
eurjchem-411	114	56	cs	cs	PROPN
eurjchem-411	114	57	)	)	PUNCT
eurjchem-411	114	58	.	.	PUNCT
eurjchem-411	115	1	anal	anal	PROPN
eurjchem-411	115	2	.	.	PUNCT
eurjchem-411	115	3	calcd	calcd	NOUN
eurjchem-411	115	4	.	.	PUNCT
eurjchem-411	116	1	for	for	ADP
eurjchem-411	116	2	c26h18n6o2s2	c26h18n6o2s2	NOUN
eurjchem-411	116	3	(	(	PUNCT
eurjchem-411	116	4	510.590	510.590	NUM
eurjchem-411	116	5	):	):	PUNCT
eurjchem-411	116	6	c	c	NOUN
eurjchem-411	116	7	,	,	PUNCT
eurjchem-411	116	8	61.16	61.16	NUM
eurjchem-411	116	9	;	;	PUNCT
eurjchem-411	116	10	h	h	NOUN
eurjchem-411	116	11	,	,	PUNCT
eurjchem-411	116	12	3.55	3.55	NUM
eurjchem-411	116	13	;	;	PUNCT
eurjchem-411	116	14	n	n	CCONJ
eurjchem-411	116	15	,	,	PUNCT
eurjchem-411	116	16	16.46	16.46	NUM
eurjchem-411	116	17	;	;	PUNCT
eurjchem-411	116	18	s	s	PROPN
eurjchem-411	116	19	,	,	PUNCT
eurjchem-411	116	20	12.56	12.56	NUM
eurjchem-411	116	21	.	.	PUNCT
eurjchem-411	117	1	found	find	VERB
eurjchem-411	117	2	:	:	PUNCT
eurjchem-411	118	1	c	c	X
eurjchem-411	118	2	,	,	PUNCT
eurjchem-411	118	3	60.96	60.96	NUM
eurjchem-411	118	4	;	;	PUNCT
eurjchem-411	118	5	h	h	NOUN
eurjchem-411	118	6	,	,	PUNCT
eurjchem-411	118	7	3.41	3.41	NUM
eurjchem-411	118	8	;	;	PUNCT
eurjchem-411	118	9	n	n	CCONJ
eurjchem-411	118	10	,	,	PUNCT
eurjchem-411	118	11	16.29	16.29	NUM
eurjchem-411	118	12	;	;	PUNCT
eurjchem-411	118	13	s	s	PROPN
eurjchem-411	118	14	,	,	PUNCT
eurjchem-411	118	15	12.41	12.41	NUM
eurjchem-411	118	16	%	%	NOUN
eurjchem-411	118	17	.	.	PUNCT
eurjchem-411	119	1	2.2.6	2.2.6	X
eurjchem-411	119	2	.	.	PUNCT
eurjchem-411	120	1	synthesis	synthesis	NOUN
eurjchem-411	120	2	of	of	ADP
eurjchem-411	120	3	7‐(4‐methoxyphenylazo)‐2,8‐diphenyl‐3h‐	7‐(4‐methoxyphenylazo)‐2,8‐diphenyl‐3h‐	NUM
eurjchem-411	120	4	thieno[2',3':4,5]pyrimidino[2,1‐b][1,3,4]thiadiazin‐9‐one	thieno[2',3':4,5]pyrimidino[2,1‐b][1,3,4]thiadiazin‐9‐one	NOUN
eurjchem-411	120	5	(	(	PUNCT
eurjchem-411	120	6	9	9	NUM
eurjchem-411	120	7	)	)	PUNCT
eurjchem-411	120	8	a	a	DET
eurjchem-411	120	9	solution	solution	NOUN
eurjchem-411	120	10	of	of	ADP
eurjchem-411	120	11	phenacyl	phenacyl	NOUN
eurjchem-411	120	12	bromide	bromide	NOUN
eurjchem-411	120	13	(	(	PUNCT
eurjchem-411	120	14	0.004	0.004	NUM
eurjchem-411	120	15	mol	mol	NOUN
eurjchem-411	120	16	)	)	PUNCT
eurjchem-411	120	17	in	in	ADP
eurjchem-411	120	18	ethanol	ethanol	NOUN
eurjchem-411	120	19	(	(	PUNCT
eurjchem-411	120	20	2	2	NUM
eurjchem-411	120	21	ml	ml	NOUN
eurjchem-411	120	22	)	)	PUNCT
eurjchem-411	120	23	was	be	AUX
eurjchem-411	120	24	added	add	VERB
eurjchem-411	120	25	to	to	ADP
eurjchem-411	120	26	a	a	DET
eurjchem-411	120	27	solution	solution	NOUN
eurjchem-411	120	28	of	of	ADP
eurjchem-411	120	29	compound	compound	NOUN
eurjchem-411	120	30	4	4	NUM
eurjchem-411	120	31	(	(	PUNCT
eurjchem-411	120	32	0.004	0.004	NUM
eurjchem-411	120	33	mol	mol	NOUN
eurjchem-411	120	34	)	)	PUNCT
eurjchem-411	120	35	and	and	CCONJ
eurjchem-411	120	36	potassium	potassium	NOUN
eurjchem-411	120	37	hydroxide	hydroxide	NOUN
eurjchem-411	120	38	(	(	PUNCT
eurjchem-411	120	39	0.004	0.004	NUM
eurjchem-411	120	40	mol	mol	NOUN
eurjchem-411	120	41	)	)	PUNCT
eurjchem-411	120	42	in	in	ADP
eurjchem-411	120	43	ethanol	ethanol	NOUN
eurjchem-411	120	44	(	(	PUNCT
eurjchem-411	120	45	8	8	NUM
eurjchem-411	120	46	ml	ml	NOUN
eurjchem-411	120	47	)	)	PUNCT
eurjchem-411	120	48	,	,	PUNCT
eurjchem-411	120	49	and	and	CCONJ
eurjchem-411	120	50	the	the	DET
eurjchem-411	120	51	reaction	reaction	NOUN
eurjchem-411	120	52	content	content	NOUN
eurjchem-411	120	53	was	be	AUX
eurjchem-411	120	54	heated	heat	VERB
eurjchem-411	120	55	for	for	ADP
eurjchem-411	120	56	30	30	NUM
eurjchem-411	120	57	min	min	NOUN
eurjchem-411	120	58	under	under	ADP
eurjchem-411	120	59	reflux	reflux	NOUN
eurjchem-411	120	60	.	.	PUNCT
eurjchem-411	121	1	the	the	DET
eurjchem-411	121	2	reaction	reaction	NOUN
eurjchem-411	121	3	mixture	mixture	NOUN
eurjchem-411	121	4	was	be	AUX
eurjchem-411	121	5	cooled	cool	VERB
eurjchem-411	121	6	and	and	CCONJ
eurjchem-411	121	7	diluted	dilute	VERB
eurjchem-411	121	8	with	with	ADP
eurjchem-411	121	9	water	water	NOUN
eurjchem-411	121	10	(	(	PUNCT
eurjchem-411	121	11	20	20	NUM
eurjchem-411	121	12	ml	ml	NOUN
eurjchem-411	121	13	)	)	PUNCT
eurjchem-411	121	14	,	,	PUNCT
eurjchem-411	121	15	whereby	whereby	SCONJ
eurjchem-411	121	16	the	the	DET
eurjchem-411	121	17	precipitate	precipitate	NOUN
eurjchem-411	121	18	of	of	ADP
eurjchem-411	121	19	solid	solid	ADJ
eurjchem-411	121	20	product	product	NOUN
eurjchem-411	121	21	was	be	AUX
eurjchem-411	121	22	collected	collect	VERB
eurjchem-411	121	23	by	by	ADP
eurjchem-411	121	24	filtration	filtration	NOUN
eurjchem-411	121	25	and	and	CCONJ
eurjchem-411	121	26	dried	dry	VERB
eurjchem-411	121	27	.	.	PUNCT
eurjchem-411	122	1	the	the	DET
eurjchem-411	122	2	residue	residue	NOUN
eurjchem-411	122	3	was	be	AUX
eurjchem-411	122	4	purified	purify	VERB
eurjchem-411	122	5	by	by	ADP
eurjchem-411	122	6	recrystallization	recrystallization	NOUN
eurjchem-411	122	7	from	from	ADP
eurjchem-411	122	8	ethanol	ethanol	NOUN
eurjchem-411	122	9	to	to	PART
eurjchem-411	122	10	obtain	obtain	VERB
eurjchem-411	122	11	the	the	DET
eurjchem-411	122	12	tricyclic	tricyclic	NOUN
eurjchem-411	122	13	thiadiazine	thiadiazine	NOUN
eurjchem-411	122	14	derivative	derivative	ADJ
eurjchem-411	122	15	9	9	NUM
eurjchem-411	122	16	as	as	ADP
eurjchem-411	122	17	a	a	DET
eurjchem-411	122	18	canary	canary	ADJ
eurjchem-411	122	19	yellow	yellow	NOUN
eurjchem-411	122	20	solid	solid	ADJ
eurjchem-411	122	21	(	(	PUNCT
eurjchem-411	122	22	0.65	0.65	NUM
eurjchem-411	122	23	g	g	NOUN
eurjchem-411	122	24	;	;	PUNCT
eurjchem-411	122	25	32	32	NUM
eurjchem-411	122	26	%	%	NOUN
eurjchem-411	122	27	)	)	PUNCT
eurjchem-411	122	28	(	(	PUNCT
eurjchem-411	122	29	scheme	scheme	NOUN
eurjchem-411	122	30	2	2	NUM
eurjchem-411	122	31	)	)	PUNCT
eurjchem-411	122	32	.	.	PUNCT
eurjchem-411	123	1	m.p	m.p	PROPN
eurjchem-411	123	2	.	.	PROPN
eurjchem-411	123	3	:	:	PUNCT
eurjchem-411	124	1	253‐256	253‐256	NUM
eurjchem-411	124	2	c	c	ADJ
eurjchem-411	124	3	.	.	PUNCT
eurjchem-411	125	1	ir	ir	PROPN
eurjchem-411	125	2	(	(	PUNCT
eurjchem-411	125	3	ν	ν	NOUN
eurjchem-411	125	4	/	/	SYM
eurjchem-411	125	5	cm‐1	cm‐1	NUM
eurjchem-411	125	6	):	):	PUNCT
eurjchem-411	125	7	3071	3071	NUM
eurjchem-411	125	8	(	(	PUNCT
eurjchem-411	125	9	arom	arom	PROPN
eurjchem-411	125	10	ch	ch	NOUN
eurjchem-411	125	11	)	)	PUNCT
eurjchem-411	125	12	,	,	PUNCT
eurjchem-411	125	13	1710	1710	NUM
eurjchem-411	125	14	(	(	PUNCT
eurjchem-411	125	15	co	co	NOUN
eurjchem-411	125	16	)	)	PUNCT
eurjchem-411	125	17	.	.	PUNCT
eurjchem-411	126	1	1h	1h	NUM
eurjchem-411	126	2	nmr	nmr	NOUN
eurjchem-411	126	3	(	(	PUNCT
eurjchem-411	126	4	δ	δ	PROPN
eurjchem-411	126	5	ppm	ppm	PROPN
eurjchem-411	126	6	):	):	PUNCT
eurjchem-411	126	7	3.90	3.90	NUM
eurjchem-411	126	8	(	(	PUNCT
eurjchem-411	126	9	s	s	PROPN
eurjchem-411	126	10	,	,	PUNCT
eurjchem-411	126	11	3h	3h	NUM
eurjchem-411	126	12	,	,	PUNCT
eurjchem-411	126	13	ome	ome	PROPN
eurjchem-411	126	14	)	)	PUNCT
eurjchem-411	126	15	,	,	PUNCT
eurjchem-411	126	16	4.43	4.43	NUM
eurjchem-411	126	17	(	(	PUNCT
eurjchem-411	126	18	s	s	PROPN
eurjchem-411	126	19	,	,	PUNCT
eurjchem-411	126	20	2h	2h	NUM
eurjchem-411	126	21	,	,	PUNCT
eurjchem-411	126	22	sch2	sch2	PROPN
eurjchem-411	126	23	)	)	PUNCT
eurjchem-411	126	24	,	,	PUNCT
eurjchem-411	126	25	7.12‐7.74	7.12‐7.74	NUM
eurjchem-411	126	26	(	(	PUNCT
eurjchem-411	126	27	m	m	PROPN
eurjchem-411	126	28	,	,	PUNCT
eurjchem-411	126	29	14h	14h	NUM
eurjchem-411	126	30	,	,	PUNCT
eurjchem-411	126	31	2phh	2phh	PROPN
eurjchem-411	126	32	,	,	PUNCT
eurjchem-411	126	33	arh	arh	ADJ
eurjchem-411	126	34	)	)	PUNCT
eurjchem-411	126	35	.	.	PUNCT
eurjchem-411	127	1	anal	anal	PROPN
eurjchem-411	127	2	.	.	PUNCT
eurjchem-411	127	3	calcd	calcd	NOUN
eurjchem-411	127	4	.	.	PUNCT
eurjchem-411	128	1	for	for	ADP
eurjchem-411	128	2	c27h19n5o2s2	c27h19n5o2s2	NOUN
eurjchem-411	128	3	(	(	PUNCT
eurjchem-411	128	4	509.602	509.602	NUM
eurjchem-411	128	5	):	):	PUNCT
eurjchem-411	128	6	c	c	X
eurjchem-411	128	7	,	,	PUNCT
eurjchem-411	128	8	63.64	63.64	NUM
eurjchem-411	128	9	;	;	PUNCT
eurjchem-411	128	10	h	h	NOUN
eurjchem-411	128	11	,	,	PUNCT
eurjchem-411	128	12	3.76	3.76	NUM
eurjchem-411	128	13	;	;	PUNCT
eurjchem-411	128	14	n	n	CCONJ
eurjchem-411	128	15	,	,	PUNCT
eurjchem-411	128	16	13.74	13.74	NUM
eurjchem-411	128	17	;	;	PUNCT
eurjchem-411	128	18	s	s	PROPN
eurjchem-411	128	19	,	,	PUNCT
eurjchem-411	128	20	12.58	12.58	NUM
eurjchem-411	128	21	.	.	PUNCT
eurjchem-411	128	22	found	find	VERB
eurjchem-411	128	23	:	:	PUNCT
eurjchem-411	129	1	c	c	X
eurjchem-411	129	2	,	,	PUNCT
eurjchem-411	129	3	63.39	63.39	NUM
eurjchem-411	129	4	;	;	PUNCT
eurjchem-411	129	5	h	h	NOUN
eurjchem-411	129	6	,	,	PUNCT
eurjchem-411	129	7	3.61	3.61	NUM
eurjchem-411	129	8	;	;	PUNCT
eurjchem-411	129	9	n	n	CCONJ
eurjchem-411	129	10	,	,	PUNCT
eurjchem-411	129	11	13.56	13.56	NUM
eurjchem-411	129	12	;	;	PUNCT
eurjchem-411	129	13	s	s	X
eurjchem-411	129	14	,	,	PUNCT
eurjchem-411	129	15	12.37	12.37	NUM
eurjchem-411	129	16	%	%	NOUN
eurjchem-411	129	17	.	.	PUNCT
eurjchem-411	130	1	2.2.7	2.2.7	X
eurjchem-411	130	2	.	.	PUNCT
eurjchem-411	131	1	synthesis	synthesis	NOUN
eurjchem-411	131	2	of	of	ADP
eurjchem-411	131	3	7‐(4‐methoxyphenylazo)‐8‐phenyl‐1h,3h‐	7‐(4‐methoxyphenylazo)‐8‐phenyl‐1h,3h‐	NUM
eurjchem-411	131	4	thieno[2',3':4,5]pyrimidino[2,1‐b][1,3,4]thiadiazin‐2,9‐dione	thieno[2',3':4,5]pyrimidino[2,1‐b][1,3,4]thiadiazin‐2,9‐dione	NOUN
eurjchem-411	131	5	(	(	PUNCT
eurjchem-411	131	6	10	10	NUM
eurjchem-411	131	7	)	)	PUNCT
eurjchem-411	131	8	2.2.7.1	2.2.7.1	PROPN
eurjchem-411	131	9	.	.	PROPN
eurjchem-411	131	10	method	method	VERB
eurjchem-411	131	11	a	a	DET
eurjchem-411	131	12	a	a	DET
eurjchem-411	131	13	mixture	mixture	NOUN
eurjchem-411	131	14	of	of	ADP
eurjchem-411	131	15	compound	compound	NOUN
eurjchem-411	131	16	4	4	NUM
eurjchem-411	131	17	(	(	PUNCT
eurjchem-411	131	18	0.002	0.002	NUM
eurjchem-411	131	19	mol	mol	NOUN
eurjchem-411	131	20	)	)	PUNCT
eurjchem-411	131	21	,	,	PUNCT
eurjchem-411	131	22	chloroacetic	chloroacetic	ADJ
eurjchem-411	131	23	acid	acid	NOUN
eurjchem-411	131	24	(	(	PUNCT
eurjchem-411	131	25	0.002	0.002	NUM
eurjchem-411	131	26	mol	mol	NOUN
eurjchem-411	131	27	)	)	PUNCT
eurjchem-411	131	28	and	and	CCONJ
eurjchem-411	131	29	anhydrous	anhydrous	ADJ
eurjchem-411	131	30	sodium	sodium	NOUN
eurjchem-411	131	31	acetate	acetate	NOUN
eurjchem-411	131	32	(	(	PUNCT
eurjchem-411	131	33	0.002	0.002	NUM
eurjchem-411	131	34	mol	mol	NOUN
eurjchem-411	131	35	)	)	PUNCT
eurjchem-411	131	36	in	in	ADP
eurjchem-411	131	37	absolute	absolute	ADJ
eurjchem-411	131	38	ethanol	ethanol	NOUN
eurjchem-411	131	39	(	(	PUNCT
eurjchem-411	131	40	15	15	NUM
eurjchem-411	131	41	ml	ml	NOUN
eurjchem-411	131	42	)	)	PUNCT
eurjchem-411	131	43	was	be	AUX
eurjchem-411	131	44	refluxed	refluxe	VERB
eurjchem-411	131	45	on	on	ADP
eurjchem-411	131	46	a	a	DET
eurjchem-411	131	47	steam	steam	NOUN
eurjchem-411	131	48	bath	bath	NOUN
eurjchem-411	131	49	for	for	ADP
eurjchem-411	131	50	6	6	NUM
eurjchem-411	131	51	h	h	NOUN
eurjchem-411	131	52	,	,	PUNCT
eurjchem-411	131	53	then	then	ADV
eurjchem-411	131	54	cooled	cool	VERB
eurjchem-411	131	55	and	and	CCONJ
eurjchem-411	131	56	poured	pour	VERB
eurjchem-411	131	57	onto	onto	ADP
eurjchem-411	131	58	cold	cold	ADJ
eurjchem-411	131	59	water	water	NOUN
eurjchem-411	131	60	.	.	PUNCT
eurjchem-411	132	1	the	the	DET
eurjchem-411	132	2	separated	separate	VERB
eurjchem-411	132	3	solid	solid	ADJ
eurjchem-411	132	4	product	product	NOUN
eurjchem-411	132	5	was	be	AUX
eurjchem-411	132	6	collected	collect	VERB
eurjchem-411	132	7	by	by	ADP
eurjchem-411	132	8	filtration	filtration	NOUN
eurjchem-411	132	9	,	,	PUNCT
eurjchem-411	132	10	washed	wash	VERB
eurjchem-411	132	11	repeatedly	repeatedly	ADV
eurjchem-411	132	12	with	with	ADP
eurjchem-411	132	13	water	water	NOUN
eurjchem-411	132	14	,	,	PUNCT
eurjchem-411	132	15	dried	dry	VERB
eurjchem-411	132	16	and	and	CCONJ
eurjchem-411	132	17	recrystallized	recrystallize	VERB
eurjchem-411	132	18	from	from	ADP
eurjchem-411	132	19	a	a	DET
eurjchem-411	132	20	mixture	mixture	NOUN
eurjchem-411	132	21	of	of	ADP
eurjchem-411	132	22	1,4‐dioxane	1,4‐dioxane	NUM
eurjchem-411	132	23	and	and	CCONJ
eurjchem-411	132	24	water	water	NOUN
eurjchem-411	132	25	to	to	PART
eurjchem-411	132	26	give	give	VERB
eurjchem-411	132	27	the	the	DET
eurjchem-411	132	28	respective	respective	ADJ
eurjchem-411	132	29	thiadiazinone	thiadiazinone	NOUN
eurjchem-411	132	30	derivative	derivative	NOUN
eurjchem-411	132	31	10	10	NUM
eurjchem-411	132	32	as	as	ADP
eurjchem-411	132	33	a	a	DET
eurjchem-411	132	34	brown	brown	ADJ
eurjchem-411	132	35	solid	solid	ADJ
eurjchem-411	132	36	(	(	PUNCT
eurjchem-411	132	37	0.49	0.49	NUM
eurjchem-411	132	38	g	g	NOUN
eurjchem-411	132	39	;	;	PUNCT
eurjchem-411	132	40	55	55	NUM
eurjchem-411	132	41	%	%	NOUN
eurjchem-411	132	42	)	)	PUNCT
eurjchem-411	132	43	(	(	PUNCT
eurjchem-411	132	44	scheme	scheme	NOUN
eurjchem-411	132	45	2	2	NUM
eurjchem-411	132	46	)	)	PUNCT
eurjchem-411	132	47	.	.	PUNCT
eurjchem-411	133	1	m.p	m.p	PROPN
eurjchem-411	133	2	.	.	PROPN
eurjchem-411	133	3	:	:	PUNCT
eurjchem-411	134	1	>	>	X
eurjchem-411	134	2	300	300	NUM
eurjchem-411	134	3	c	c	VERB
eurjchem-411	134	4	.	.	PUNCT
eurjchem-411	135	1	ir	ir	PROPN
eurjchem-411	135	2	(	(	PUNCT
eurjchem-411	135	3	ν	ν	NOUN
eurjchem-411	135	4	/	/	SYM
eurjchem-411	135	5	cm‐1	cm‐1	NUM
eurjchem-411	135	6	):	):	PUNCT
eurjchem-411	135	7	3167	3167	NUM
eurjchem-411	135	8	(	(	PUNCT
eurjchem-411	135	9	nh	nh	NOUN
eurjchem-411	135	10	)	)	PUNCT
eurjchem-411	135	11	,	,	PUNCT
eurjchem-411	135	12	3071	3071	NUM
eurjchem-411	135	13	(	(	PUNCT
eurjchem-411	135	14	arom	arom	NOUN
eurjchem-411	135	15	ch	ch	NOUN
eurjchem-411	135	16	)	)	PUNCT
eurjchem-411	135	17	,	,	PUNCT
eurjchem-411	135	18	1705	1705	NUM
eurjchem-411	135	19	,	,	PUNCT
eurjchem-411	135	20	1684	1684	NUM
eurjchem-411	135	21	(	(	PUNCT
eurjchem-411	135	22	2co	2co	NOUN
eurjchem-411	135	23	)	)	PUNCT
eurjchem-411	135	24	.	.	PUNCT
eurjchem-411	136	1	1h	1h	NUM
eurjchem-411	136	2	nmr	nmr	NOUN
eurjchem-411	136	3	(	(	PUNCT
eurjchem-411	136	4	δ	δ	PROPN
eurjchem-411	136	5	ppm	ppm	PROPN
eurjchem-411	136	6	):	):	PUNCT
eurjchem-411	136	7	3.85	3.85	NUM
eurjchem-411	136	8	(	(	PUNCT
eurjchem-411	136	9	s	s	PROPN
eurjchem-411	136	10	,	,	PUNCT
eurjchem-411	136	11	3h	3h	NUM
eurjchem-411	136	12	,	,	PUNCT
eurjchem-411	136	13	ome	ome	PROPN
eurjchem-411	136	14	)	)	PUNCT
eurjchem-411	136	15	,	,	PUNCT
eurjchem-411	136	16	3.94	3.94	NUM
eurjchem-411	136	17	(	(	PUNCT
eurjchem-411	136	18	s	s	PROPN
eurjchem-411	136	19	,	,	PUNCT
eurjchem-411	136	20	2h	2h	NUM
eurjchem-411	136	21	,	,	PUNCT
eurjchem-411	136	22	sch2	sch2	PROPN
eurjchem-411	136	23	)	)	PUNCT
eurjchem-411	136	24	,	,	PUNCT
eurjchem-411	136	25	7.15‐7.46	7.15‐7.46	NUM
eurjchem-411	136	26	(	(	PUNCT
eurjchem-411	136	27	m	m	PROPN
eurjchem-411	136	28	,	,	PUNCT
eurjchem-411	136	29	9h	9h	NUM
eurjchem-411	136	30	,	,	PUNCT
eurjchem-411	136	31	phh	phh	PROPN
eurjchem-411	136	32	,	,	PUNCT
eurjchem-411	136	33	arh	arh	PROPN
eurjchem-411	136	34	)	)	PUNCT
eurjchem-411	136	35	,	,	PUNCT
eurjchem-411	136	36	11.59	11.59	NUM
eurjchem-411	136	37	(	(	PUNCT
eurjchem-411	136	38	s	s	PROPN
eurjchem-411	136	39	,	,	PUNCT
eurjchem-411	136	40	1h	1h	NUM
eurjchem-411	136	41	,	,	PUNCT
eurjchem-411	136	42	nh	nh	PROPN
eurjchem-411	136	43	,	,	PUNCT
eurjchem-411	136	44	d2o‐exchangeable	d2o‐exchangeable	PROPN
eurjchem-411	136	45	)	)	PUNCT
eurjchem-411	136	46	.	.	PUNCT
eurjchem-411	137	1	ms	ms	NOUN
eurjchem-411	137	2	(	(	PUNCT
eurjchem-411	137	3	m	m	PROPN
eurjchem-411	137	4	/	/	SYM
eurjchem-411	137	5	z	z	NOUN
eurjchem-411	137	6	(	(	PUNCT
eurjchem-411	137	7	%	%	NOUN
eurjchem-411	137	8	)	)	PUNCT
eurjchem-411	137	9	):	):	PUNCT
eurjchem-411	137	10	449	449	NUM
eurjchem-411	137	11	(	(	PUNCT
eurjchem-411	137	12	m+	m+	NUM
eurjchem-411	137	13	,	,	PUNCT
eurjchem-411	137	14	29	29	NUM
eurjchem-411	137	15	%	%	NOUN
eurjchem-411	137	16	)	)	PUNCT
eurjchem-411	137	17	.	.	PUNCT
eurjchem-411	138	1	anal	anal	PROPN
eurjchem-411	138	2	.	.	PUNCT
eurjchem-411	138	3	calcd	calcd	NOUN
eurjchem-411	138	4	.	.	PUNCT
eurjchem-411	139	1	for	for	SCONJ
eurjchem-411	139	2	c21h15n5o3s2	c21h15n5o3s2	NOUN
eurjchem-411	139	3	(	(	PUNCT
eurjchem-411	139	4	449.505	449.505	NUM
eurjchem-411	139	5	):	):	PUNCT
eurjchem-411	139	6	c	c	NOUN
eurjchem-411	139	7	,	,	PUNCT
eurjchem-411	139	8	56.11	56.11	NUM
eurjchem-411	139	9	;	;	PUNCT
eurjchem-411	139	10	h	h	NOUN
eurjchem-411	139	11	,	,	PUNCT
eurjchem-411	139	12	3.36	3.36	NUM
eurjchem-411	139	13	;	;	PUNCT
eurjchem-411	139	14	n	n	CCONJ
eurjchem-411	139	15	,	,	PUNCT
eurjchem-411	139	16	15.58	15.58	NUM
eurjchem-411	139	17	;	;	PUNCT
eurjchem-411	139	18	s	s	PROPN
eurjchem-411	139	19	,	,	PUNCT
eurjchem-411	139	20	14.27	14.27	NUM
eurjchem-411	139	21	.	.	PUNCT
eurjchem-411	139	22	found	find	VERB
eurjchem-411	139	23	:	:	PUNCT
eurjchem-411	140	1	c	c	X
eurjchem-411	140	2	,	,	PUNCT
eurjchem-411	140	3	55.88	55.88	NUM
eurjchem-411	140	4	;	;	PUNCT
eurjchem-411	140	5	h	h	NOUN
eurjchem-411	140	6	,	,	PUNCT
eurjchem-411	140	7	3.21	3.21	NUM
eurjchem-411	140	8	;	;	PUNCT
eurjchem-411	140	9	n	n	CCONJ
eurjchem-411	140	10	,	,	PUNCT
eurjchem-411	140	11	15.36	15.36	NUM
eurjchem-411	140	12	;	;	PUNCT
eurjchem-411	140	13	s	s	NOUN
eurjchem-411	140	14	,	,	PUNCT
eurjchem-411	140	15	14.08	14.08	NUM
eurjchem-411	140	16	%	%	NOUN
eurjchem-411	140	17	.	.	PUNCT
eurjchem-411	141	1	gaber	gaber	PROPN
eurjchem-411	141	2	and	and	CCONJ
eurjchem-411	141	3	bagley	bagley	PROPN
eurjchem-411	141	4	/	/	SYM
eurjchem-411	141	5	european	european	PROPN
eurjchem-411	141	6	journal	journal	PROPN
eurjchem-411	141	7	of	of	ADP
eurjchem-411	141	8	chemistry	chemistry	NOUN
eurjchem-411	141	9	2	2	NUM
eurjchem-411	141	10	(	(	PUNCT
eurjchem-411	141	11	2	2	NUM
eurjchem-411	141	12	)	)	PUNCT
eurjchem-411	141	13	(	(	PUNCT
eurjchem-411	141	14	2011	2011	NUM
eurjchem-411	141	15	)	)	PUNCT
eurjchem-411	141	16	214‐222	214‐222	PROPN
eurjchem-411	141	17	217	217	NUM
eurjchem-411	141	18	scheme	scheme	NOUN
eurjchem-411	141	19	2	2	NUM
eurjchem-411	141	20	2.2.7.2	2.2.7.2	NUM
eurjchem-411	141	21	.	.	PUNCT
eurjchem-411	142	1	method	method	PROPN
eurjchem-411	142	2	b	b	PROPN
eurjchem-411	142	3	a	a	DET
eurjchem-411	142	4	mixture	mixture	NOUN
eurjchem-411	142	5	of	of	ADP
eurjchem-411	142	6	compound	compound	NOUN
eurjchem-411	142	7	4	4	NUM
eurjchem-411	142	8	(	(	PUNCT
eurjchem-411	142	9	0.002	0.002	NUM
eurjchem-411	142	10	mol	mol	NOUN
eurjchem-411	142	11	)	)	PUNCT
eurjchem-411	142	12	and	and	CCONJ
eurjchem-411	142	13	ethyl	ethyl	PROPN
eurjchem-411	142	14	chloroacetate	chloroacetate	NOUN
eurjchem-411	142	15	(	(	PUNCT
eurjchem-411	142	16	0.002	0.002	NUM
eurjchem-411	142	17	mol	mol	NOUN
eurjchem-411	142	18	)	)	PUNCT
eurjchem-411	142	19	,	,	PUNCT
eurjchem-411	142	20	was	be	AUX
eurjchem-411	142	21	added	add	VERB
eurjchem-411	142	22	with	with	ADP
eurjchem-411	142	23	stirring	stir	VERB
eurjchem-411	142	24	to	to	ADP
eurjchem-411	142	25	sodium	sodium	NOUN
eurjchem-411	142	26	ethoxide	ethoxide	NOUN
eurjchem-411	142	27	[	[	X
eurjchem-411	142	28	obtained	obtain	VERB
eurjchem-411	142	29	from	from	ADP
eurjchem-411	142	30	0.046	0.046	NUM
eurjchem-411	142	31	g	g	PROPN
eurjchem-411	142	32	(	(	PUNCT
eurjchem-411	142	33	0.002	0.002	NUM
eurjchem-411	142	34	mol	mol	NOUN
eurjchem-411	142	35	)	)	PUNCT
eurjchem-411	142	36	of	of	ADP
eurjchem-411	142	37	metallic	metallic	ADJ
eurjchem-411	142	38	sodium	sodium	NOUN
eurjchem-411	142	39	and	and	CCONJ
eurjchem-411	142	40	15	15	NUM
eurjchem-411	142	41	ml	ml	NOUN
eurjchem-411	142	42	of	of	ADP
eurjchem-411	142	43	absolute	absolute	ADJ
eurjchem-411	142	44	ethanol	ethanol	NOUN
eurjchem-411	142	45	]	]	PUNCT
eurjchem-411	142	46	.	.	PUNCT
eurjchem-411	143	1	the	the	DET
eurjchem-411	143	2	reaction	reaction	NOUN
eurjchem-411	143	3	content	content	NOUN
eurjchem-411	143	4	was	be	AUX
eurjchem-411	143	5	refluxed	refluxe	VERB
eurjchem-411	143	6	with	with	ADP
eurjchem-411	143	7	stirring	stir	VERB
eurjchem-411	143	8	for	for	ADP
eurjchem-411	143	9	3	3	NUM
eurjchem-411	143	10	h.	h.	NOUN
eurjchem-411	143	11	the	the	DET
eurjchem-411	143	12	solvent	solvent	NOUN
eurjchem-411	143	13	was	be	AUX
eurjchem-411	143	14	distilled	distil	VERB
eurjchem-411	143	15	off	off	ADP
eurjchem-411	143	16	and	and	CCONJ
eurjchem-411	143	17	water	water	NOUN
eurjchem-411	143	18	was	be	AUX
eurjchem-411	143	19	added	add	VERB
eurjchem-411	143	20	.	.	PUNCT
eurjchem-411	144	1	the	the	DET
eurjchem-411	144	2	precipitate	precipitate	NOUN
eurjchem-411	144	3	was	be	AUX
eurjchem-411	144	4	filtered	filter	VERB
eurjchem-411	144	5	off	off	ADP
eurjchem-411	144	6	,	,	PUNCT
eurjchem-411	144	7	dried	dry	VERB
eurjchem-411	144	8	and	and	CCONJ
eurjchem-411	144	9	recrystallized	recrystallize	VERB
eurjchem-411	144	10	from	from	ADP
eurjchem-411	144	11	1,4‐dioxane	1,4‐dioxane	NUM
eurjchem-411	144	12	/	/	SYM
eurjchem-411	144	13	water	water	NOUN
eurjchem-411	144	14	to	to	PART
eurjchem-411	144	15	give	give	VERB
eurjchem-411	144	16	a	a	DET
eurjchem-411	144	17	solid	solid	ADJ
eurjchem-411	144	18	product	product	NOUN
eurjchem-411	144	19	,	,	PUNCT
eurjchem-411	144	20	in	in	ADP
eurjchem-411	144	21	43	43	NUM
eurjchem-411	144	22	%	%	NOUN
eurjchem-411	144	23	yield	yield	NOUN
eurjchem-411	144	24	,	,	PUNCT
eurjchem-411	144	25	identical	identical	ADJ
eurjchem-411	144	26	in	in	ADP
eurjchem-411	144	27	all	all	DET
eurjchem-411	144	28	aspects	aspect	NOUN
eurjchem-411	144	29	(	(	PUNCT
eurjchem-411	144	30	mp	mp	NOUN
eurjchem-411	144	31	,	,	PUNCT
eurjchem-411	144	32	mixed	mixed	ADJ
eurjchem-411	144	33	mp	mp	PROPN
eurjchem-411	144	34	and	and	CCONJ
eurjchem-411	144	35	ir	ir	PROPN
eurjchem-411	144	36	data	data	PROPN
eurjchem-411	144	37	)	)	PUNCT
eurjchem-411	144	38	to	to	ADP
eurjchem-411	144	39	that	that	PRON
eurjchem-411	144	40	obtained	obtain	VERB
eurjchem-411	144	41	above	above	ADV
eurjchem-411	144	42	from	from	ADP
eurjchem-411	144	43	method	method	NOUN
eurjchem-411	144	44	a.	a.	NOUN
eurjchem-411	144	45	2.2.8	2.2.8	NUM
eurjchem-411	144	46	.	.	PUNCT
eurjchem-411	145	1	synthesis	synthesis	NOUN
eurjchem-411	145	2	of	of	ADP
eurjchem-411	145	3	6‐(4‐methoxyphenylazo)‐2,7‐diphenyl‐8h‐	6‐(4‐methoxyphenylazo)‐2,7‐diphenyl‐8h‐	NUM
eurjchem-411	145	4	[	[	X
eurjchem-411	145	5	1,3,4]thiadiazolo[3,2‐a]thieno[2,3‐d]pyrimidin‐8‐one	1,3,4]thiadiazolo[3,2‐a]thieno[2,3‐d]pyrimidin‐8‐one	NUM
eurjchem-411	145	6	(	(	PUNCT
eurjchem-411	145	7	11	11	NUM
eurjchem-411	145	8	)	)	PUNCT
eurjchem-411	145	9	a	a	DET
eurjchem-411	145	10	mixture	mixture	NOUN
eurjchem-411	145	11	of	of	ADP
eurjchem-411	145	12	compound	compound	NOUN
eurjchem-411	145	13	4	4	NUM
eurjchem-411	145	14	(	(	PUNCT
eurjchem-411	145	15	0.002	0.002	NUM
eurjchem-411	145	16	mol	mol	NOUN
eurjchem-411	145	17	)	)	PUNCT
eurjchem-411	145	18	and	and	CCONJ
eurjchem-411	145	19	benzoic	benzoic	ADJ
eurjchem-411	145	20	acid	acid	NOUN
eurjchem-411	145	21	(	(	PUNCT
eurjchem-411	145	22	0.004	0.004	NUM
eurjchem-411	145	23	mol	mol	NOUN
eurjchem-411	145	24	)	)	PUNCT
eurjchem-411	145	25	in	in	ADP
eurjchem-411	145	26	phosphorus	phosphorus	NOUN
eurjchem-411	145	27	oxychloride	oxychloride	NOUN
eurjchem-411	145	28	(	(	PUNCT
eurjchem-411	145	29	10	10	NUM
eurjchem-411	145	30	ml	ml	NOUN
eurjchem-411	145	31	)	)	PUNCT
eurjchem-411	145	32	was	be	AUX
eurjchem-411	145	33	refluxed	refluxe	VERB
eurjchem-411	145	34	for	for	ADP
eurjchem-411	145	35	1	1	NUM
eurjchem-411	145	36	h.	h.	NOUN
eurjchem-411	145	37	the	the	DET
eurjchem-411	145	38	reaction	reaction	NOUN
eurjchem-411	145	39	mixture	mixture	NOUN
eurjchem-411	145	40	was	be	AUX
eurjchem-411	145	41	concentrated	concentrate	VERB
eurjchem-411	145	42	to	to	ADP
eurjchem-411	145	43	third	third	ADJ
eurjchem-411	145	44	its	its	PRON
eurjchem-411	145	45	volume	volume	NOUN
eurjchem-411	145	46	under	under	ADP
eurjchem-411	145	47	reduced	reduce	VERB
eurjchem-411	145	48	pressure	pressure	NOUN
eurjchem-411	145	49	and	and	CCONJ
eurjchem-411	145	50	left	leave	VERB
eurjchem-411	145	51	to	to	PART
eurjchem-411	145	52	cool	cool	ADJ
eurjchem-411	145	53	.	.	PUNCT
eurjchem-411	146	1	the	the	DET
eurjchem-411	146	2	mixture	mixture	NOUN
eurjchem-411	146	3	was	be	AUX
eurjchem-411	146	4	then	then	ADV
eurjchem-411	146	5	poured	pour	VERB
eurjchem-411	146	6	gradually	gradually	ADV
eurjchem-411	146	7	onto	onto	ADP
eurjchem-411	146	8	a	a	DET
eurjchem-411	146	9	stirred	stir	VERB
eurjchem-411	146	10	ice	ice	NOUN
eurjchem-411	146	11	cold	cold	ADJ
eurjchem-411	146	12	sodium	sodium	NOUN
eurjchem-411	146	13	hydroxide	hydroxide	NOUN
eurjchem-411	146	14	solution	solution	NOUN
eurjchem-411	146	15	to	to	PART
eurjchem-411	146	16	remove	remove	VERB
eurjchem-411	146	17	unreacted	unreacted	ADJ
eurjchem-411	146	18	materials	material	NOUN
eurjchem-411	146	19	.	.	PUNCT
eurjchem-411	147	1	the	the	DET
eurjchem-411	147	2	obtained	obtain	VERB
eurjchem-411	147	3	precipitate	precipitate	NOUN
eurjchem-411	147	4	was	be	AUX
eurjchem-411	147	5	collected	collect	VERB
eurjchem-411	147	6	by	by	ADP
eurjchem-411	147	7	filtration	filtration	NOUN
eurjchem-411	147	8	,	,	PUNCT
eurjchem-411	147	9	washed	wash	VERB
eurjchem-411	147	10	thoroughly	thoroughly	ADV
eurjchem-411	147	11	with	with	ADP
eurjchem-411	147	12	water	water	NOUN
eurjchem-411	147	13	,	,	PUNCT
eurjchem-411	147	14	dried	dry	VERB
eurjchem-411	147	15	and	and	CCONJ
eurjchem-411	147	16	purified	purify	VERB
eurjchem-411	147	17	by	by	ADP
eurjchem-411	147	18	recrystallization	recrystallization	NOUN
eurjchem-411	147	19	from	from	ADP
eurjchem-411	147	20	acetic	acetic	ADJ
eurjchem-411	147	21	acid	acid	NOUN
eurjchem-411	147	22	to	to	PART
eurjchem-411	147	23	give	give	VERB
eurjchem-411	147	24	light	light	ADJ
eurjchem-411	147	25	brown	brown	ADJ
eurjchem-411	147	26	crystals	crystal	NOUN
eurjchem-411	147	27	of	of	ADP
eurjchem-411	147	28	the	the	DET
eurjchem-411	147	29	title	title	NOUN
eurjchem-411	147	30	compound	compound	NOUN
eurjchem-411	147	31	11	11	NUM
eurjchem-411	147	32	(	(	PUNCT
eurjchem-411	147	33	0.59	0.59	NUM
eurjchem-411	147	34	g	g	NOUN
eurjchem-411	147	35	;	;	PUNCT
eurjchem-411	147	36	60	60	NUM
eurjchem-411	147	37	%	%	NOUN
eurjchem-411	147	38	)	)	PUNCT
eurjchem-411	147	39	(	(	PUNCT
eurjchem-411	147	40	scheme	scheme	NOUN
eurjchem-411	147	41	2	2	NUM
eurjchem-411	147	42	)	)	PUNCT
eurjchem-411	147	43	.	.	PUNCT
eurjchem-411	148	1	m.p	m.p	PROPN
eurjchem-411	148	2	.	.	PROPN
eurjchem-411	148	3	:	:	PUNCT
eurjchem-411	148	4	263	263	NUM
eurjchem-411	148	5	c	c	NUM
eurjchem-411	148	6	.	.	PUNCT
eurjchem-411	149	1	ir	ir	PROPN
eurjchem-411	149	2	(	(	PUNCT
eurjchem-411	149	3	ν	ν	NOUN
eurjchem-411	149	4	/	/	SYM
eurjchem-411	149	5	cm‐	cm‐	NOUN
eurjchem-411	149	6	1	1	NUM
eurjchem-411	149	7	):	):	PUNCT
eurjchem-411	149	8	3065	3065	NUM
eurjchem-411	149	9	(	(	PUNCT
eurjchem-411	149	10	arom	arom	NOUN
eurjchem-411	149	11	ch	ch	NOUN
eurjchem-411	149	12	)	)	PUNCT
eurjchem-411	149	13	,	,	PUNCT
eurjchem-411	149	14	1714	1714	NUM
eurjchem-411	149	15	(	(	PUNCT
eurjchem-411	149	16	co	co	NOUN
eurjchem-411	149	17	)	)	PUNCT
eurjchem-411	149	18	.	.	PUNCT
eurjchem-411	150	1	1h	1h	NUM
eurjchem-411	150	2	nmr	nmr	NOUN
eurjchem-411	150	3	(	(	PUNCT
eurjchem-411	150	4	δ	δ	PROPN
eurjchem-411	150	5	ppm	ppm	PROPN
eurjchem-411	150	6	):	):	PUNCT
eurjchem-411	150	7	3.86	3.86	NUM
eurjchem-411	150	8	(	(	PUNCT
eurjchem-411	150	9	s	s	PROPN
eurjchem-411	150	10	,	,	PUNCT
eurjchem-411	150	11	3h	3h	NUM
eurjchem-411	150	12	,	,	PUNCT
eurjchem-411	150	13	ome	ome	PROPN
eurjchem-411	150	14	)	)	PUNCT
eurjchem-411	150	15	,	,	PUNCT
eurjchem-411	150	16	7.18‐7.64	7.18‐7.64	NUM
eurjchem-411	150	17	(	(	PUNCT
eurjchem-411	150	18	m	m	PROPN
eurjchem-411	150	19	,	,	PUNCT
eurjchem-411	150	20	14h	14h	NUM
eurjchem-411	150	21	,	,	PUNCT
eurjchem-411	150	22	2phh	2phh	PROPN
eurjchem-411	150	23	,	,	PUNCT
eurjchem-411	150	24	arh	arh	ADJ
eurjchem-411	150	25	)	)	PUNCT
eurjchem-411	150	26	.	.	PUNCT
eurjchem-411	151	1	ms	ms	NOUN
eurjchem-411	151	2	(	(	PUNCT
eurjchem-411	151	3	m	m	PROPN
eurjchem-411	151	4	/	/	SYM
eurjchem-411	151	5	z	z	NOUN
eurjchem-411	151	6	(	(	PUNCT
eurjchem-411	151	7	%	%	NOUN
eurjchem-411	151	8	)	)	PUNCT
eurjchem-411	151	9	):	):	PUNCT
eurjchem-411	151	10	495	495	NUM
eurjchem-411	151	11	(	(	PUNCT
eurjchem-411	151	12	m+	m+	NUM
eurjchem-411	151	13	,	,	PUNCT
eurjchem-411	151	14	21	21	NUM
eurjchem-411	151	15	%	%	NOUN
eurjchem-411	151	16	)	)	PUNCT
eurjchem-411	151	17	.	.	PUNCT
eurjchem-411	152	1	anal	anal	PROPN
eurjchem-411	152	2	.	.	PUNCT
eurjchem-411	152	3	calcd	calcd	NOUN
eurjchem-411	152	4	.	.	PUNCT
eurjchem-411	153	1	for	for	SCONJ
eurjchem-411	153	2	c26h17n5o2s2	c26h17n5o2s2	PROPN
eurjchem-411	153	3	(	(	PUNCT
eurjchem-411	153	4	495.575	495.575	NUM
eurjchem-411	153	5	):	):	PUNCT
eurjchem-411	153	6	c	c	NOUN
eurjchem-411	153	7	,	,	PUNCT
eurjchem-411	153	8	63.01	63.01	NUM
eurjchem-411	153	9	;	;	PUNCT
eurjchem-411	153	10	h	h	NOUN
eurjchem-411	153	11	,	,	PUNCT
eurjchem-411	153	12	3.46	3.46	NUM
eurjchem-411	153	13	;	;	PUNCT
eurjchem-411	153	14	n	n	CCONJ
eurjchem-411	153	15	,	,	PUNCT
eurjchem-411	153	16	14.13	14.13	NUM
eurjchem-411	153	17	;	;	PUNCT
eurjchem-411	153	18	s	s	X
eurjchem-411	153	19	,	,	PUNCT
eurjchem-411	153	20	12.94	12.94	NUM
eurjchem-411	153	21	.	.	PUNCT
eurjchem-411	153	22	found	find	VERB
eurjchem-411	153	23	:	:	PUNCT
eurjchem-411	154	1	c	c	X
eurjchem-411	154	2	,	,	PUNCT
eurjchem-411	154	3	62.83	62.83	NUM
eurjchem-411	154	4	;	;	PUNCT
eurjchem-411	154	5	h	h	NOUN
eurjchem-411	154	6	,	,	PUNCT
eurjchem-411	154	7	3.25	3.25	NUM
eurjchem-411	154	8	;	;	PUNCT
eurjchem-411	154	9	n	n	CCONJ
eurjchem-411	154	10	,	,	PUNCT
eurjchem-411	154	11	13.96	13.96	NUM
eurjchem-411	154	12	;	;	PUNCT
eurjchem-411	154	13	s	s	X
eurjchem-411	154	14	,	,	PUNCT
eurjchem-411	154	15	12.70	12.70	NUM
eurjchem-411	154	16	%	%	NOUN
eurjchem-411	154	17	.	.	PUNCT
eurjchem-411	155	1	2.2.9	2.2.9	X
eurjchem-411	155	2	.	.	PUNCT
eurjchem-411	156	1	synthesis	synthesis	NOUN
eurjchem-411	156	2	of	of	ADP
eurjchem-411	156	3	4‐amino‐3‐[2‐amino‐5‐(4‐methoxy	4‐amino‐3‐[2‐amino‐5‐(4‐methoxy	NUM
eurjchem-411	156	4	phenylazo)‐4‐phenylthiophen‐3‐yl]‐1h‐1,2,4‐triazole‐5(4h)‐	phenylazo)‐4‐phenylthiophen‐3‐yl]‐1h‐1,2,4‐triazole‐5(4h)‐	PROPN
eurjchem-411	156	5	thione	thione	NOUN
eurjchem-411	156	6	(	(	PUNCT
eurjchem-411	156	7	13	13	NUM
eurjchem-411	156	8	)	)	PUNCT
eurjchem-411	156	9	to	to	ADP
eurjchem-411	156	10	a	a	DET
eurjchem-411	156	11	suspension	suspension	NOUN
eurjchem-411	156	12	of	of	ADP
eurjchem-411	156	13	compound	compound	NOUN
eurjchem-411	156	14	5	5	NUM
eurjchem-411	156	15	(	(	PUNCT
eurjchem-411	156	16	0.003	0.003	NUM
eurjchem-411	156	17	mol	mol	NOUN
eurjchem-411	156	18	)	)	PUNCT
eurjchem-411	156	19	in	in	ADP
eurjchem-411	156	20	ethanol	ethanol	NOUN
eurjchem-411	156	21	(	(	PUNCT
eurjchem-411	156	22	10	10	NUM
eurjchem-411	156	23	ml	ml	NOUN
eurjchem-411	156	24	)	)	PUNCT
eurjchem-411	156	25	,	,	PUNCT
eurjchem-411	156	26	hydrazine	hydrazine	NOUN
eurjchem-411	156	27	hydrate	hydrate	NOUN
eurjchem-411	156	28	(	(	PUNCT
eurjchem-411	156	29	0.0095	0.0095	NUM
eurjchem-411	156	30	mol	mol	NOUN
eurjchem-411	156	31	)	)	PUNCT
eurjchem-411	156	32	was	be	AUX
eurjchem-411	156	33	added	add	VERB
eurjchem-411	156	34	dropwise	dropwise	NOUN
eurjchem-411	156	35	.	.	PUNCT
eurjchem-411	157	1	the	the	DET
eurjchem-411	157	2	reaction	reaction	NOUN
eurjchem-411	157	3	content	content	NOUN
eurjchem-411	157	4	was	be	AUX
eurjchem-411	157	5	heated	heat	VERB
eurjchem-411	157	6	at	at	ADP
eurjchem-411	157	7	reflux	reflux	NOUN
eurjchem-411	157	8	for	for	ADP
eurjchem-411	157	9	7	7	NUM
eurjchem-411	157	10	h	h	NOUN
eurjchem-411	157	11	,	,	PUNCT
eurjchem-411	157	12	then	then	ADV
eurjchem-411	157	13	left	leave	VERB
eurjchem-411	157	14	to	to	PART
eurjchem-411	157	15	cool	cool	VERB
eurjchem-411	157	16	and	and	CCONJ
eurjchem-411	157	17	poured	pour	VERB
eurjchem-411	157	18	onto	onto	ADP
eurjchem-411	157	19	crushed	crush	VERB
eurjchem-411	157	20	ice	ice	NOUN
eurjchem-411	157	21	.	.	PUNCT
eurjchem-411	158	1	the	the	DET
eurjchem-411	158	2	reaction	reaction	NOUN
eurjchem-411	158	3	mixture	mixture	NOUN
eurjchem-411	158	4	was	be	AUX
eurjchem-411	158	5	acidified	acidify	VERB
eurjchem-411	158	6	with	with	ADP
eurjchem-411	158	7	dilute	dilute	ADJ
eurjchem-411	158	8	hydrochloric	hydrochloric	ADJ
eurjchem-411	158	9	acid	acid	NOUN
eurjchem-411	158	10	.	.	PUNCT
eurjchem-411	159	1	the	the	DET
eurjchem-411	159	2	formed	form	VERB
eurjchem-411	159	3	precipitate	precipitate	NOUN
eurjchem-411	159	4	was	be	AUX
eurjchem-411	159	5	collected	collect	VERB
eurjchem-411	159	6	by	by	ADP
eurjchem-411	159	7	filtration	filtration	NOUN
eurjchem-411	159	8	,	,	PUNCT
eurjchem-411	159	9	washed	wash	VERB
eurjchem-411	159	10	with	with	ADP
eurjchem-411	159	11	water	water	NOUN
eurjchem-411	159	12	and	and	CCONJ
eurjchem-411	159	13	dried	dry	VERB
eurjchem-411	159	14	.	.	PUNCT
eurjchem-411	160	1	recrystallization	recrystallization	NOUN
eurjchem-411	160	2	from	from	ADP
eurjchem-411	160	3	aqueous	aqueous	ADJ
eurjchem-411	160	4	dimethylformamide	dimethylformamide	NOUN
eurjchem-411	160	5	gave	give	VERB
eurjchem-411	160	6	the	the	DET
eurjchem-411	160	7	n‐	n‐	NOUN
eurjchem-411	160	8	amino	amino	NOUN
eurjchem-411	160	9	compound	compound	PROPN
eurjchem-411	160	10	13	13	NUM
eurjchem-411	160	11	as	as	ADP
eurjchem-411	160	12	a	a	DET
eurjchem-411	160	13	yellowish	yellowish	ADJ
eurjchem-411	160	14	white	white	ADJ
eurjchem-411	160	15	solid	solid	ADJ
eurjchem-411	160	16	(	(	PUNCT
eurjchem-411	160	17	0.99	0.99	NUM
eurjchem-411	160	18	g	g	NOUN
eurjchem-411	160	19	;	;	PUNCT
eurjchem-411	160	20	78	78	NUM
eurjchem-411	160	21	%	%	NOUN
eurjchem-411	160	22	)	)	PUNCT
eurjchem-411	160	23	(	(	PUNCT
eurjchem-411	160	24	scheme	scheme	NOUN
eurjchem-411	160	25	3	3	NUM
eurjchem-411	160	26	)	)	PUNCT
eurjchem-411	160	27	.	.	PUNCT
eurjchem-411	161	1	m.p	m.p	PROPN
eurjchem-411	161	2	.	.	PROPN
eurjchem-411	161	3	:	:	PUNCT
eurjchem-411	162	1	233‐236	233‐236	NUM
eurjchem-411	162	2	c	c	ADJ
eurjchem-411	162	3	.	.	PUNCT
eurjchem-411	163	1	ir	ir	PROPN
eurjchem-411	163	2	(	(	PUNCT
eurjchem-411	163	3	ν	ν	NOUN
eurjchem-411	163	4	/	/	SYM
eurjchem-411	163	5	cm‐1	cm‐1	NUM
eurjchem-411	163	6	):	):	PUNCT
eurjchem-411	163	7	3340‐3112	3340‐3112	PROPN
eurjchem-411	163	8	(	(	PUNCT
eurjchem-411	163	9	nh	nh	PROPN
eurjchem-411	163	10	,	,	PUNCT
eurjchem-411	163	11	nh2	nh2	PROPN
eurjchem-411	163	12	)	)	PUNCT
eurjchem-411	163	13	,	,	PUNCT
eurjchem-411	163	14	3061	3061	NUM
eurjchem-411	163	15	(	(	PUNCT
eurjchem-411	163	16	arom	arom	NOUN
eurjchem-411	163	17	ch	ch	NOUN
eurjchem-411	163	18	)	)	PUNCT
eurjchem-411	163	19	,	,	PUNCT
eurjchem-411	163	20	1462	1462	NUM
eurjchem-411	163	21	(	(	PUNCT
eurjchem-411	163	22	cs	cs	PROPN
eurjchem-411	163	23	)	)	PUNCT
eurjchem-411	163	24	.	.	PUNCT
eurjchem-411	164	1	1h	1h	NUM
eurjchem-411	164	2	nmr	nmr	NOUN
eurjchem-411	164	3	(	(	PUNCT
eurjchem-411	164	4	δ	δ	PROPN
eurjchem-411	164	5	ppm	ppm	PROPN
eurjchem-411	164	6	):	):	PUNCT
eurjchem-411	164	7	3.88	3.88	NUM
eurjchem-411	164	8	(	(	PUNCT
eurjchem-411	164	9	s	s	PROPN
eurjchem-411	164	10	,	,	PUNCT
eurjchem-411	164	11	3h	3h	NUM
eurjchem-411	164	12	,	,	PUNCT
eurjchem-411	164	13	ome	ome	PROPN
eurjchem-411	164	14	)	)	PUNCT
eurjchem-411	164	15	,	,	PUNCT
eurjchem-411	164	16	5.72	5.72	NUM
eurjchem-411	164	17	(	(	PUNCT
eurjchem-411	164	18	s	s	PROPN
eurjchem-411	164	19	,	,	PUNCT
eurjchem-411	164	20	2h	2h	NUM
eurjchem-411	164	21	,	,	PUNCT
eurjchem-411	164	22	n‐nh2	n‐nh2	PROPN
eurjchem-411	164	23	,	,	PUNCT
eurjchem-411	164	24	d2o‐exchangeable	d2o‐exchangeable	PROPN
eurjchem-411	164	25	)	)	PUNCT
eurjchem-411	164	26	,	,	PUNCT
eurjchem-411	164	27	6.50	6.50	NUM
eurjchem-411	164	28	(	(	PUNCT
eurjchem-411	164	29	s	s	NOUN
eurjchem-411	164	30	,	,	PUNCT
eurjchem-411	164	31	2h	2h	NUM
eurjchem-411	164	32	,	,	PUNCT
eurjchem-411	164	33	nh2	nh2	PROPN
eurjchem-411	164	34	,	,	PUNCT
eurjchem-411	164	35	d2o‐exchangeable	d2o‐exchangeable	PROPN
eurjchem-411	164	36	)	)	PUNCT
eurjchem-411	164	37	,	,	PUNCT
eurjchem-411	164	38	7.21‐7.55	7.21‐7.55	NUM
eurjchem-411	164	39	(	(	PUNCT
eurjchem-411	164	40	m	m	PROPN
eurjchem-411	164	41	,	,	PUNCT
eurjchem-411	164	42	9h	9h	NUM
eurjchem-411	164	43	,	,	PUNCT
eurjchem-411	164	44	phh	phh	PROPN
eurjchem-411	164	45	,	,	PUNCT
eurjchem-411	164	46	arh	arh	PROPN
eurjchem-411	164	47	)	)	PUNCT
eurjchem-411	164	48	,	,	PUNCT
eurjchem-411	164	49	13.24	13.24	NUM
eurjchem-411	164	50	(	(	PUNCT
eurjchem-411	164	51	s	s	PROPN
eurjchem-411	164	52	,	,	PUNCT
eurjchem-411	164	53	br	br	PROPN
eurjchem-411	164	54	,	,	PUNCT
eurjchem-411	164	55	1h	1h	NUM
eurjchem-411	164	56	,	,	PUNCT
eurjchem-411	164	57	nh	nh	PROPN
eurjchem-411	164	58	,	,	PUNCT
eurjchem-411	164	59	d2o‐exchangeable	d2o‐exchangeable	PROPN
eurjchem-411	164	60	)	)	PUNCT
eurjchem-411	164	61	.	.	PUNCT
eurjchem-411	165	1	ms	ms	NOUN
eurjchem-411	165	2	(	(	PUNCT
eurjchem-411	165	3	m	m	PROPN
eurjchem-411	165	4	/	/	SYM
eurjchem-411	165	5	z	z	NOUN
eurjchem-411	165	6	(	(	PUNCT
eurjchem-411	165	7	%	%	NOUN
eurjchem-411	165	8	)	)	PUNCT
eurjchem-411	165	9	):	):	PUNCT
eurjchem-411	165	10	423	423	NUM
eurjchem-411	165	11	(	(	PUNCT
eurjchem-411	165	12	m+	m+	NUM
eurjchem-411	165	13	,	,	PUNCT
eurjchem-411	165	14	14	14	NUM
eurjchem-411	165	15	%	%	NOUN
eurjchem-411	165	16	)	)	PUNCT
eurjchem-411	165	17	.	.	PUNCT
eurjchem-411	166	1	anal	anal	PROPN
eurjchem-411	166	2	.	.	PUNCT
eurjchem-411	166	3	calcd	calcd	NOUN
eurjchem-411	166	4	.	.	PUNCT
eurjchem-411	167	1	for	for	SCONJ
eurjchem-411	167	2	c19h17n7os2	c19h17n7os2	PROPN
eurjchem-411	167	3	(	(	PUNCT
eurjchem-411	167	4	423.515	423.515	NUM
eurjchem-411	167	5	):	):	PUNCT
eurjchem-411	167	6	c	c	NOUN
eurjchem-411	167	7	,	,	PUNCT
eurjchem-411	167	8	53.88	53.88	NUM
eurjchem-411	167	9	;	;	PUNCT
eurjchem-411	167	10	h	h	NOUN
eurjchem-411	167	11	,	,	PUNCT
eurjchem-411	167	12	4.05	4.05	NUM
eurjchem-411	167	13	;	;	PUNCT
eurjchem-411	167	14	n	n	CCONJ
eurjchem-411	167	15	,	,	PUNCT
eurjchem-411	167	16	23.15	23.15	NUM
eurjchem-411	167	17	;	;	PUNCT
eurjchem-411	167	18	s	s	PROPN
eurjchem-411	167	19	,	,	PUNCT
eurjchem-411	167	20	15.14	15.14	NUM
eurjchem-411	167	21	.	.	PUNCT
eurjchem-411	167	22	found	find	VERB
eurjchem-411	167	23	:	:	PUNCT
eurjchem-411	168	1	c	c	X
eurjchem-411	168	2	,	,	PUNCT
eurjchem-411	168	3	53.69	53.69	NUM
eurjchem-411	168	4	;	;	PUNCT
eurjchem-411	168	5	h	h	NOUN
eurjchem-411	168	6	,	,	PUNCT
eurjchem-411	168	7	3.89	3.89	NUM
eurjchem-411	168	8	;	;	PUNCT
eurjchem-411	168	9	n	n	CCONJ
eurjchem-411	168	10	,	,	PUNCT
eurjchem-411	168	11	22.92	22.92	NUM
eurjchem-411	168	12	;	;	PUNCT
eurjchem-411	168	13	s	s	NUM
eurjchem-411	168	14	,	,	PUNCT
eurjchem-411	168	15	14.97	14.97	NUM
eurjchem-411	168	16	%	%	NOUN
eurjchem-411	168	17	.	.	PUNCT
eurjchem-411	169	1	2.2.10	2.2.10	NUM
eurjchem-411	169	2	.	.	PUNCT
eurjchem-411	170	1	synthesis	synthesis	NOUN
eurjchem-411	170	2	of	of	ADP
eurjchem-411	170	3	5‐substituted‐2‐[2‐amino‐5‐(4‐methoxy	5‐substituted‐2‐[2‐amino‐5‐(4‐methoxy	NUM
eurjchem-411	170	4	phenylazo)‐4‐phenylthiophen‐3‐yl]‐1,3,4‐oxadiazoles	phenylazo)‐4‐phenylthiophen‐3‐yl]‐1,3,4‐oxadiazole	NOUN
eurjchem-411	170	5	(	(	PUNCT
eurjchem-411	170	6	14a	14a	NOUN
eurjchem-411	170	7	,	,	PUNCT
eurjchem-411	170	8	b	b	NOUN
eurjchem-411	170	9	)	)	PUNCT
eurjchem-411	170	10	a	a	DET
eurjchem-411	170	11	solution	solution	NOUN
eurjchem-411	170	12	of	of	ADP
eurjchem-411	170	13	methyl	methyl	NOUN
eurjchem-411	170	14	iodide	iodide	NOUN
eurjchem-411	170	15	or	or	CCONJ
eurjchem-411	170	16	phenacyl	phenacyl	NOUN
eurjchem-411	170	17	bromide	bromide	NOUN
eurjchem-411	170	18	(	(	PUNCT
eurjchem-411	170	19	0.005	0.005	NUM
eurjchem-411	170	20	mol	mol	NOUN
eurjchem-411	170	21	)	)	PUNCT
eurjchem-411	170	22	in	in	ADP
eurjchem-411	170	23	ethanol	ethanol	NOUN
eurjchem-411	170	24	(	(	PUNCT
eurjchem-411	170	25	2.5	2.5	NUM
eurjchem-411	170	26	ml	ml	NOUN
eurjchem-411	170	27	)	)	PUNCT
eurjchem-411	170	28	was	be	AUX
eurjchem-411	170	29	added	add	VERB
eurjchem-411	170	30	to	to	ADP
eurjchem-411	170	31	a	a	DET
eurjchem-411	170	32	solution	solution	NOUN
eurjchem-411	170	33	of	of	ADP
eurjchem-411	170	34	compound	compound	NOUN
eurjchem-411	170	35	5	5	NUM
eurjchem-411	170	36	(	(	PUNCT
eurjchem-411	170	37	0.005	0.005	NUM
eurjchem-411	170	38	mol	mol	NOUN
eurjchem-411	170	39	)	)	PUNCT
eurjchem-411	170	40	and	and	CCONJ
eurjchem-411	170	41	potassium	potassium	NOUN
eurjchem-411	170	42	hydroxide	hydroxide	NOUN
eurjchem-411	170	43	in	in	ADP
eurjchem-411	170	44	ethanol	ethanol	NOUN
eurjchem-411	170	45	(	(	PUNCT
eurjchem-411	170	46	10	10	NUM
eurjchem-411	170	47	ml	ml	NOUN
eurjchem-411	170	48	)	)	PUNCT
eurjchem-411	170	49	.	.	PUNCT
eurjchem-411	171	1	the	the	DET
eurjchem-411	171	2	reaction	reaction	NOUN
eurjchem-411	171	3	content	content	NOUN
eurjchem-411	171	4	was	be	AUX
eurjchem-411	171	5	heated	heat	VERB
eurjchem-411	171	6	for	for	ADP
eurjchem-411	171	7	30	30	NUM
eurjchem-411	171	8	min	min	NOUN
eurjchem-411	171	9	under	under	ADP
eurjchem-411	171	10	reflux	reflux	NOUN
eurjchem-411	171	11	.	.	PUNCT
eurjchem-411	172	1	and	and	CCONJ
eurjchem-411	172	2	then	then	ADV
eurjchem-411	172	3	ice	ice	NOUN
eurjchem-411	172	4	/	/	SYM
eurjchem-411	172	5	water	water	NOUN
eurjchem-411	172	6	mixture	mixture	NOUN
eurjchem-411	172	7	was	be	AUX
eurjchem-411	172	8	added	add	VERB
eurjchem-411	172	9	to	to	ADP
eurjchem-411	172	10	the	the	DET
eurjchem-411	172	11	reaction	reaction	NOUN
eurjchem-411	172	12	mixture	mixture	NOUN
eurjchem-411	172	13	to	to	PART
eurjchem-411	172	14	form	form	VERB
eurjchem-411	172	15	precipitates	precipitate	NOUN
eurjchem-411	172	16	,	,	PUNCT
eurjchem-411	172	17	which	which	PRON
eurjchem-411	172	18	were	be	AUX
eurjchem-411	172	19	collected	collect	VERB
eurjchem-411	172	20	by	by	ADP
eurjchem-411	172	21	filtration	filtration	NOUN
eurjchem-411	172	22	,	,	PUNCT
eurjchem-411	172	23	dried	dry	VERB
eurjchem-411	172	24	and	and	CCONJ
eurjchem-411	172	25	recrystallized	recrystallize	VERB
eurjchem-411	172	26	from	from	ADP
eurjchem-411	172	27	the	the	DET
eurjchem-411	172	28	proper	proper	ADJ
eurjchem-411	172	29	solvents	solvent	NOUN
eurjchem-411	172	30	to	to	PART
eurjchem-411	172	31	obtain	obtain	VERB
eurjchem-411	172	32	the	the	DET
eurjchem-411	172	33	title	title	NOUN
eurjchem-411	172	34	compounds	compound	VERB
eurjchem-411	172	35	14a	14a	NOUN
eurjchem-411	172	36	(	(	PUNCT
eurjchem-411	172	37	0.85	0.85	NUM
eurjchem-411	172	38	g	g	NOUN
eurjchem-411	172	39	;	;	PUNCT
eurjchem-411	172	40	40	40	NUM
eurjchem-411	172	41	%	%	NOUN
eurjchem-411	172	42	)	)	PUNCT
eurjchem-411	172	43	and	and	CCONJ
eurjchem-411	172	44	14b	14b	NUM
eurjchem-411	172	45	(	(	PUNCT
eurjchem-411	172	46	0.87	0.87	NUM
eurjchem-411	172	47	g	g	NOUN
eurjchem-411	172	48	;	;	PUNCT
eurjchem-411	172	49	33	33	NUM
eurjchem-411	172	50	%	%	NOUN
eurjchem-411	172	51	)	)	PUNCT
eurjchem-411	172	52	,	,	PUNCT
eurjchem-411	172	53	respectively	respectively	ADV
eurjchem-411	172	54	(	(	PUNCT
eurjchem-411	172	55	scheme	scheme	NOUN
eurjchem-411	172	56	3	3	NUM
eurjchem-411	172	57	)	)	PUNCT
eurjchem-411	172	58	.	.	PUNCT
eurjchem-411	173	1	2.2.11	2.2.11	NUM
eurjchem-411	173	2	.	.	X
eurjchem-411	174	1	2‐[2‐amino‐5‐(4‐methoxyphenylazo)‐4‐phenyl	2‐[2‐amino‐5‐(4‐methoxyphenylazo)‐4‐phenyl	NUM
eurjchem-411	174	2	thiophen‐3‐yl]‐5‐methylthio‐1,3,4‐oxadiazole	thiophen‐3‐yl]‐5‐methylthio‐1,3,4‐oxadiazole	PROPN
eurjchem-411	174	3	(	(	PUNCT
eurjchem-411	174	4	14a	14a	NOUN
eurjchem-411	174	5	)	)	PUNCT
eurjchem-411	174	6	this	this	DET
eurjchem-411	174	7	compound	compound	NOUN
eurjchem-411	174	8	was	be	AUX
eurjchem-411	174	9	obtained	obtain	VERB
eurjchem-411	174	10	as	as	ADP
eurjchem-411	174	11	a	a	DET
eurjchem-411	174	12	brown	brown	ADJ
eurjchem-411	174	13	solid	solid	ADJ
eurjchem-411	174	14	(	(	PUNCT
eurjchem-411	174	15	meoh	meoh	PROPN
eurjchem-411	174	16	)	)	PUNCT
eurjchem-411	174	17	(	(	PUNCT
eurjchem-411	174	18	scheme	scheme	NOUN
eurjchem-411	174	19	3	3	NUM
eurjchem-411	174	20	)	)	PUNCT
eurjchem-411	174	21	.	.	PUNCT
eurjchem-411	175	1	m.p	m.p	PROPN
eurjchem-411	175	2	.	.	PROPN
eurjchem-411	175	3	:	:	PUNCT
eurjchem-411	176	1	120‐121	120‐121	NUM
eurjchem-411	176	2	c	c	VERB
eurjchem-411	176	3	.	.	PUNCT
eurjchem-411	177	1	ir	ir	PROPN
eurjchem-411	177	2	(	(	PUNCT
eurjchem-411	177	3	ν	ν	NOUN
eurjchem-411	177	4	/	/	SYM
eurjchem-411	177	5	cm‐1	cm‐1	NUM
eurjchem-411	177	6	):	):	PUNCT
eurjchem-411	177	7	3450	3450	NUM
eurjchem-411	177	8	,	,	PUNCT
eurjchem-411	177	9	3341	3341	NUM
eurjchem-411	177	10	(	(	PUNCT
eurjchem-411	177	11	nh2	nh2	PROPN
eurjchem-411	177	12	)	)	PUNCT
eurjchem-411	177	13	,	,	PUNCT
eurjchem-411	177	14	3060	3060	NUM
eurjchem-411	177	15	(	(	PUNCT
eurjchem-411	177	16	arom	arom	NOUN
eurjchem-411	177	17	ch	ch	NOUN
eurjchem-411	177	18	)	)	PUNCT
eurjchem-411	177	19	,	,	PUNCT
eurjchem-411	177	20	1064	1064	NUM
eurjchem-411	177	21	(	(	PUNCT
eurjchem-411	177	22	c‐o‐c	c‐o‐c	NOUN
eurjchem-411	177	23	)	)	PUNCT
eurjchem-411	177	24	.	.	PUNCT
eurjchem-411	178	1	1h	1h	NUM
eurjchem-411	178	2	nmr	nmr	NOUN
eurjchem-411	178	3	(	(	PUNCT
eurjchem-411	178	4	δ	δ	PROPN
eurjchem-411	178	5	ppm	ppm	PROPN
eurjchem-411	178	6	):	):	PUNCT
eurjchem-411	178	7	2.73	2.73	NUM
eurjchem-411	178	8	(	(	PUNCT
eurjchem-411	178	9	s	s	PROPN
eurjchem-411	178	10	,	,	PUNCT
eurjchem-411	178	11	3h	3h	NUM
eurjchem-411	178	12	,	,	PUNCT
eurjchem-411	178	13	sme	sme	NOUN
eurjchem-411	178	14	)	)	PUNCT
eurjchem-411	178	15	,	,	PUNCT
eurjchem-411	178	16	3.85	3.85	NUM
eurjchem-411	178	17	(	(	PUNCT
eurjchem-411	178	18	s	s	PROPN
eurjchem-411	178	19	,	,	PUNCT
eurjchem-411	178	20	3h	3h	NUM
eurjchem-411	178	21	,	,	PUNCT
eurjchem-411	178	22	ome	ome	PROPN
eurjchem-411	178	23	)	)	PUNCT
eurjchem-411	178	24	,	,	PUNCT
eurjchem-411	178	25	6.29	6.29	NUM
eurjchem-411	178	26	(	(	PUNCT
eurjchem-411	178	27	s	s	PROPN
eurjchem-411	178	28	,	,	PUNCT
eurjchem-411	178	29	2h	2h	NUM
eurjchem-411	178	30	,	,	PUNCT
eurjchem-411	178	31	nh2	nh2	PROPN
eurjchem-411	178	32	,	,	PUNCT
eurjchem-411	178	33	d2o‐exchangeable	d2o‐exchangeable	PROPN
eurjchem-411	178	34	)	)	PUNCT
eurjchem-411	178	35	,	,	PUNCT
eurjchem-411	178	36	7.08‐7.40	7.08‐7.40	PROPN
eurjchem-411	178	37	(	(	PUNCT
eurjchem-411	178	38	m	m	PROPN
eurjchem-411	178	39	,	,	PUNCT
eurjchem-411	178	40	9h	9h	NUM
eurjchem-411	178	41	,	,	PUNCT
eurjchem-411	178	42	phh	phh	PROPN
eurjchem-411	178	43	,	,	PUNCT
eurjchem-411	178	44	arh	arh	PROPN
eurjchem-411	178	45	)	)	PUNCT
eurjchem-411	178	46	.	.	PUNCT
eurjchem-411	179	1	anal	anal	PROPN
eurjchem-411	179	2	.	.	PUNCT
eurjchem-411	179	3	calcd	calcd	NOUN
eurjchem-411	179	4	.	.	PUNCT
eurjchem-411	180	1	for	for	ADP
eurjchem-411	180	2	c20h17n5o2s2	c20h17n5o2s2	NOUN
eurjchem-411	180	3	(	(	PUNCT
eurjchem-411	180	4	423.511	423.511	NUM
eurjchem-411	180	5	):	):	PUNCT
eurjchem-411	180	6	c	c	NOUN
eurjchem-411	180	7	,	,	PUNCT
eurjchem-411	180	8	56.72	56.72	NUM
eurjchem-411	180	9	;	;	PUNCT
eurjchem-411	180	10	h	h	NOUN
eurjchem-411	180	11	,	,	PUNCT
eurjchem-411	180	12	4.05	4.05	NUM
eurjchem-411	180	13	;	;	PUNCT
eurjchem-411	180	14	n	n	CCONJ
eurjchem-411	180	15	,	,	PUNCT
eurjchem-411	180	16	16.54	16.54	NUM
eurjchem-411	180	17	;	;	PUNCT
eurjchem-411	180	18	s	s	X
eurjchem-411	180	19	,	,	PUNCT
eurjchem-411	180	20	15.14	15.14	NUM
eurjchem-411	180	21	.	.	PUNCT
eurjchem-411	180	22	found	find	VERB
eurjchem-411	180	23	:	:	PUNCT
eurjchem-411	181	1	c	c	X
eurjchem-411	181	2	,	,	PUNCT
eurjchem-411	181	3	56.48	56.48	NUM
eurjchem-411	181	4	;	;	PUNCT
eurjchem-411	181	5	h	h	X
eurjchem-411	181	6	,	,	PUNCT
eurjchem-411	181	7	3.91	3.91	NUM
eurjchem-411	181	8	;	;	PUNCT
eurjchem-411	181	9	n	n	CCONJ
eurjchem-411	181	10	,	,	PUNCT
eurjchem-411	181	11	16.37	16.37	NUM
eurjchem-411	181	12	;	;	PUNCT
eurjchem-411	181	13	s	s	NUM
eurjchem-411	181	14	,	,	PUNCT
eurjchem-411	181	15	14.94	14.94	NUM
eurjchem-411	181	16	%	%	NOUN
eurjchem-411	181	17	.	.	PUNCT
eurjchem-411	182	1	218	218	NUM
eurjchem-411	182	2	gaber	gaber	NOUN
eurjchem-411	182	3	and	and	CCONJ
eurjchem-411	182	4	bagley	bagley	PROPN
eurjchem-411	182	5	/	/	SYM
eurjchem-411	182	6	european	european	PROPN
eurjchem-411	182	7	journal	journal	PROPN
eurjchem-411	182	8	of	of	ADP
eurjchem-411	182	9	chemistry	chemistry	NOUN
eurjchem-411	182	10	2	2	NUM
eurjchem-411	182	11	(	(	PUNCT
eurjchem-411	182	12	2	2	NUM
eurjchem-411	182	13	)	)	PUNCT
eurjchem-411	182	14	(	(	PUNCT
eurjchem-411	182	15	2011	2011	NUM
eurjchem-411	182	16	)	)	PUNCT
eurjchem-411	182	17	214‐222	214‐222	NUM
eurjchem-411	182	18	scheme	scheme	NOUN
eurjchem-411	182	19	3	3	NUM
eurjchem-411	182	20	2.2.12	2.2.12	NUM
eurjchem-411	182	21	.	.	PUNCT
eurjchem-411	183	1	2‐[2‐amino‐5‐(4‐methoxyphenylazo)‐4‐phenyl	2‐[2‐amino‐5‐(4‐methoxyphenylazo)‐4‐phenyl	NUM
eurjchem-411	183	2	thiophen‐3‐yl]‐5‐phenacylthio‐1,3,4‐oxadiazole	thiophen‐3‐yl]‐5‐phenacylthio‐1,3,4‐oxadiazole	NOUN
eurjchem-411	183	3	(	(	PUNCT
eurjchem-411	183	4	14b	14b	NUM
eurjchem-411	183	5	)	)	PUNCT
eurjchem-411	183	6	this	this	DET
eurjchem-411	183	7	compound	compound	NOUN
eurjchem-411	183	8	was	be	AUX
eurjchem-411	183	9	obtained	obtain	VERB
eurjchem-411	183	10	as	as	ADP
eurjchem-411	183	11	a	a	DET
eurjchem-411	183	12	pale	pale	ADJ
eurjchem-411	183	13	yellow	yellow	ADJ
eurjchem-411	183	14	solid	solid	ADJ
eurjchem-411	183	15	(	(	PUNCT
eurjchem-411	183	16	etoh	etoh	NOUN
eurjchem-411	183	17	)	)	PUNCT
eurjchem-411	183	18	(	(	PUNCT
eurjchem-411	183	19	scheme	scheme	NOUN
eurjchem-411	183	20	3	3	NUM
eurjchem-411	183	21	)	)	PUNCT
eurjchem-411	183	22	.	.	PUNCT
eurjchem-411	184	1	m.p	m.p	PROPN
eurjchem-411	184	2	.	.	PROPN
eurjchem-411	184	3	:	:	PUNCT
eurjchem-411	185	1	213‐215	213‐215	NUM
eurjchem-411	185	2	c	c	ADJ
eurjchem-411	185	3	.	.	PUNCT
eurjchem-411	186	1	ir	ir	PROPN
eurjchem-411	186	2	(	(	PUNCT
eurjchem-411	186	3	ν	ν	NOUN
eurjchem-411	186	4	/	/	SYM
eurjchem-411	186	5	cm‐1	cm‐1	NUM
eurjchem-411	186	6	):	):	PUNCT
eurjchem-411	186	7	3441	3441	NUM
eurjchem-411	186	8	,	,	PUNCT
eurjchem-411	186	9	3335	3335	NUM
eurjchem-411	186	10	(	(	PUNCT
eurjchem-411	186	11	nh2	nh2	PROPN
eurjchem-411	186	12	)	)	PUNCT
eurjchem-411	186	13	,	,	PUNCT
eurjchem-411	186	14	3064	3064	NUM
eurjchem-411	186	15	(	(	PUNCT
eurjchem-411	186	16	arom	arom	NOUN
eurjchem-411	186	17	ch	ch	NOUN
eurjchem-411	186	18	)	)	PUNCT
eurjchem-411	186	19	,	,	PUNCT
eurjchem-411	186	20	1692	1692	NUM
eurjchem-411	186	21	(	(	PUNCT
eurjchem-411	186	22	co	co	NOUN
eurjchem-411	186	23	)	)	PUNCT
eurjchem-411	186	24	,	,	PUNCT
eurjchem-411	186	25	1062	1062	NUM
eurjchem-411	186	26	(	(	PUNCT
eurjchem-411	186	27	c‐o‐c	c‐o‐c	NOUN
eurjchem-411	186	28	)	)	PUNCT
eurjchem-411	186	29	.	.	PUNCT
eurjchem-411	187	1	1h	1h	NUM
eurjchem-411	187	2	nmr	nmr	NOUN
eurjchem-411	187	3	(	(	PUNCT
eurjchem-411	187	4	δ	δ	PROPN
eurjchem-411	187	5	ppm	ppm	PROPN
eurjchem-411	187	6	):	):	PUNCT
eurjchem-411	187	7	3.85	3.85	NUM
eurjchem-411	187	8	(	(	PUNCT
eurjchem-411	187	9	s	s	PROPN
eurjchem-411	187	10	,	,	PUNCT
eurjchem-411	187	11	3h	3h	NUM
eurjchem-411	187	12	,	,	PUNCT
eurjchem-411	187	13	ome	ome	PROPN
eurjchem-411	187	14	)	)	PUNCT
eurjchem-411	187	15	,	,	PUNCT
eurjchem-411	187	16	4.91	4.91	NUM
eurjchem-411	187	17	(	(	PUNCT
eurjchem-411	187	18	s	s	PROPN
eurjchem-411	187	19	,	,	PUNCT
eurjchem-411	187	20	2h	2h	NUM
eurjchem-411	187	21	,	,	PUNCT
eurjchem-411	187	22	sch2	sch2	PROPN
eurjchem-411	187	23	)	)	PUNCT
eurjchem-411	187	24	,	,	PUNCT
eurjchem-411	187	25	6.44	6.44	NUM
eurjchem-411	187	26	(	(	PUNCT
eurjchem-411	187	27	s	s	NOUN
eurjchem-411	187	28	,	,	PUNCT
eurjchem-411	187	29	2h	2h	NUM
eurjchem-411	187	30	,	,	PUNCT
eurjchem-411	187	31	nh2	nh2	PROPN
eurjchem-411	187	32	,	,	PUNCT
eurjchem-411	187	33	d2o‐	d2o‐	PROPN
eurjchem-411	187	34	exchangeable	exchangeable	ADJ
eurjchem-411	187	35	)	)	PUNCT
eurjchem-411	187	36	,	,	PUNCT
eurjchem-411	187	37	7.26‐7.84	7.26‐7.84	NUM
eurjchem-411	187	38	(	(	PUNCT
eurjchem-411	187	39	m	m	PROPN
eurjchem-411	187	40	,	,	PUNCT
eurjchem-411	187	41	14h	14h	NUM
eurjchem-411	187	42	,	,	PUNCT
eurjchem-411	187	43	2phh	2phh	PROPN
eurjchem-411	187	44	,	,	PUNCT
eurjchem-411	187	45	arh	arh	ADJ
eurjchem-411	187	46	)	)	PUNCT
eurjchem-411	187	47	.	.	PUNCT
eurjchem-411	188	1	anal	anal	PROPN
eurjchem-411	188	2	.	.	PUNCT
eurjchem-411	188	3	calcd	calcd	NOUN
eurjchem-411	188	4	.	.	PUNCT
eurjchem-411	189	1	for	for	ADP
eurjchem-411	189	2	c27h21n5o3s2	c27h21n5o3s2	NOUN
eurjchem-411	189	3	(	(	PUNCT
eurjchem-411	189	4	527.617	527.617	NUM
eurjchem-411	189	5	):	):	PUNCT
eurjchem-411	189	6	c	c	NOUN
eurjchem-411	189	7	,	,	PUNCT
eurjchem-411	189	8	61.46	61.46	NUM
eurjchem-411	189	9	;	;	PUNCT
eurjchem-411	189	10	h	h	NOUN
eurjchem-411	189	11	,	,	PUNCT
eurjchem-411	189	12	4.01	4.01	NUM
eurjchem-411	189	13	;	;	PUNCT
eurjchem-411	189	14	n	n	CCONJ
eurjchem-411	189	15	,	,	PUNCT
eurjchem-411	189	16	13.27	13.27	NUM
eurjchem-411	189	17	;	;	PUNCT
eurjchem-411	189	18	s	s	PROPN
eurjchem-411	189	19	,	,	PUNCT
eurjchem-411	189	20	12.15	12.15	NUM
eurjchem-411	189	21	.	.	PUNCT
eurjchem-411	190	1	found	find	VERB
eurjchem-411	190	2	:	:	PUNCT
eurjchem-411	191	1	c	c	X
eurjchem-411	191	2	,	,	PUNCT
eurjchem-411	191	3	61.24	61.24	NUM
eurjchem-411	191	4	;	;	PUNCT
eurjchem-411	191	5	h	h	NOUN
eurjchem-411	191	6	,	,	PUNCT
eurjchem-411	191	7	3.90	3.90	NUM
eurjchem-411	191	8	;	;	PUNCT
eurjchem-411	191	9	n	n	CCONJ
eurjchem-411	191	10	,	,	PUNCT
eurjchem-411	191	11	13.04	13.04	NUM
eurjchem-411	191	12	;	;	PUNCT
eurjchem-411	191	13	s	s	NOUN
eurjchem-411	191	14	,	,	PUNCT
eurjchem-411	191	15	11.96	11.96	NUM
eurjchem-411	191	16	%	%	NOUN
eurjchem-411	191	17	.	.	PUNCT
eurjchem-411	192	1	2.2.13	2.2.13	NUM
eurjchem-411	192	2	.	.	PUNCT
eurjchem-411	193	1	synthesis	synthesis	NOUN
eurjchem-411	193	2	of	of	ADP
eurjchem-411	193	3	2‐[2‐amino‐5‐(4‐methoxyphenylazo)‐4‐	2‐[2‐amino‐5‐(4‐methoxyphenylazo)‐4‐	NUM
eurjchem-411	193	4	phenylthiophen‐3‐yl]‐5‐hydrazino‐1,3,4‐oxadiazole	phenylthiophen‐3‐yl]‐5‐hydrazino‐1,3,4‐oxadiazole	PROPN
eurjchem-411	193	5	(	(	PUNCT
eurjchem-411	193	6	14c	14c	NOUN
eurjchem-411	193	7	)	)	PUNCT
eurjchem-411	193	8	compound	compound	NOUN
eurjchem-411	193	9	14a	14a	NOUN
eurjchem-411	193	10	(	(	PUNCT
eurjchem-411	193	11	0.002	0.002	NUM
eurjchem-411	193	12	mol	mol	NOUN
eurjchem-411	193	13	)	)	PUNCT
eurjchem-411	193	14	was	be	AUX
eurjchem-411	193	15	mixed	mix	VERB
eurjchem-411	193	16	with	with	ADP
eurjchem-411	193	17	hydrazine	hydrazine	NOUN
eurjchem-411	193	18	hydrate	hydrate	NOUN
eurjchem-411	193	19	(	(	PUNCT
eurjchem-411	193	20	1	1	NUM
eurjchem-411	193	21	ml	ml	NOUN
eurjchem-411	193	22	,	,	PUNCT
eurjchem-411	193	23	0.02	0.02	NUM
eurjchem-411	193	24	mol	mol	NOUN
eurjchem-411	193	25	)	)	PUNCT
eurjchem-411	193	26	in	in	ADP
eurjchem-411	193	27	absolute	absolute	ADJ
eurjchem-411	193	28	ethanol	ethanol	NOUN
eurjchem-411	193	29	(	(	PUNCT
eurjchem-411	193	30	8	8	NUM
eurjchem-411	193	31	ml	ml	NOUN
eurjchem-411	193	32	)	)	PUNCT
eurjchem-411	193	33	.	.	PUNCT
eurjchem-411	194	1	the	the	DET
eurjchem-411	194	2	reaction	reaction	NOUN
eurjchem-411	194	3	content	content	NOUN
eurjchem-411	194	4	was	be	AUX
eurjchem-411	194	5	heated	heat	VERB
eurjchem-411	194	6	at	at	ADP
eurjchem-411	194	7	reflux	reflux	NOUN
eurjchem-411	194	8	for	for	ADP
eurjchem-411	194	9	5	5	NUM
eurjchem-411	194	10	h	h	NOUN
eurjchem-411	194	11	and	and	CCONJ
eurjchem-411	194	12	then	then	ADV
eurjchem-411	194	13	held	hold	VERB
eurjchem-411	194	14	overnight	overnight	ADV
eurjchem-411	194	15	at	at	ADP
eurjchem-411	194	16	room	room	NOUN
eurjchem-411	194	17	temperature	temperature	NOUN
eurjchem-411	194	18	.	.	PUNCT
eurjchem-411	195	1	after	after	ADP
eurjchem-411	195	2	cooling	cool	VERB
eurjchem-411	195	3	and	and	CCONJ
eurjchem-411	195	4	dilution	dilution	NOUN
eurjchem-411	195	5	with	with	ADP
eurjchem-411	195	6	water	water	NOUN
eurjchem-411	195	7	,	,	PUNCT
eurjchem-411	195	8	the	the	DET
eurjchem-411	195	9	obtained	obtain	VERB
eurjchem-411	195	10	precipitate	precipitate	NOUN
eurjchem-411	195	11	was	be	AUX
eurjchem-411	195	12	filtered	filter	VERB
eurjchem-411	195	13	off	off	ADP
eurjchem-411	195	14	,	,	PUNCT
eurjchem-411	195	15	dried	dry	VERB
eurjchem-411	195	16	and	and	CCONJ
eurjchem-411	195	17	purified	purify	VERB
eurjchem-411	195	18	by	by	ADP
eurjchem-411	195	19	recrystallization	recrystallization	NOUN
eurjchem-411	195	20	from	from	ADP
eurjchem-411	195	21	an	an	DET
eurjchem-411	195	22	ethanol	ethanol	NOUN
eurjchem-411	195	23	and	and	CCONJ
eurjchem-411	195	24	dimethylformamide	dimethylformamide	NOUN
eurjchem-411	195	25	mixture	mixture	NOUN
eurjchem-411	195	26	(	(	PUNCT
eurjchem-411	195	27	2:1	2:1	NUM
eurjchem-411	195	28	)	)	PUNCT
eurjchem-411	195	29	to	to	PART
eurjchem-411	195	30	give	give	VERB
eurjchem-411	195	31	reddish	reddish	ADJ
eurjchem-411	195	32	brown	brown	ADJ
eurjchem-411	195	33	crystals	crystal	NOUN
eurjchem-411	195	34	of	of	ADP
eurjchem-411	195	35	the	the	DET
eurjchem-411	195	36	title	title	NOUN
eurjchem-411	195	37	compound	compound	NOUN
eurjchem-411	195	38	14c	14c	NUM
eurjchem-411	195	39	(	(	PUNCT
eurjchem-411	195	40	0.40	0.40	NUM
eurjchem-411	195	41	g	g	NOUN
eurjchem-411	195	42	;	;	PUNCT
eurjchem-411	195	43	49	49	NUM
eurjchem-411	195	44	%	%	NOUN
eurjchem-411	195	45	)	)	PUNCT
eurjchem-411	195	46	(	(	PUNCT
eurjchem-411	195	47	scheme	scheme	NOUN
eurjchem-411	195	48	3	3	NUM
eurjchem-411	195	49	)	)	PUNCT
eurjchem-411	195	50	.	.	PUNCT
eurjchem-411	196	1	m.p	m.p	PROPN
eurjchem-411	196	2	.	.	PROPN
eurjchem-411	196	3	:	:	PUNCT
eurjchem-411	197	1	227‐228	227‐228	PROPN
eurjchem-411	197	2	c	c	PROPN
eurjchem-411	197	3	.	.	PUNCT
eurjchem-411	198	1	ir	ir	PROPN
eurjchem-411	198	2	(	(	PUNCT
eurjchem-411	198	3	ν	ν	NOUN
eurjchem-411	198	4	/	/	SYM
eurjchem-411	198	5	cm‐1	cm‐1	NOUN
eurjchem-411	198	6	):	):	PUNCT
eurjchem-411	198	7	3410‐3202	3410‐3202	PROPN
eurjchem-411	198	8	(	(	PUNCT
eurjchem-411	198	9	nh	nh	PROPN
eurjchem-411	198	10	,	,	PUNCT
eurjchem-411	198	11	nh2	nh2	PROPN
eurjchem-411	198	12	)	)	PUNCT
eurjchem-411	198	13	,	,	PUNCT
eurjchem-411	198	14	3053	3053	NUM
eurjchem-411	198	15	(	(	PUNCT
eurjchem-411	198	16	arom	arom	NOUN
eurjchem-411	198	17	ch	ch	NOUN
eurjchem-411	198	18	)	)	PUNCT
eurjchem-411	198	19	,	,	PUNCT
eurjchem-411	198	20	1071	1071	NUM
eurjchem-411	198	21	(	(	PUNCT
eurjchem-411	198	22	c‐o‐c	c‐o‐c	NOUN
eurjchem-411	198	23	)	)	PUNCT
eurjchem-411	198	24	.	.	PUNCT
eurjchem-411	199	1	1h	1h	NUM
eurjchem-411	199	2	nmr	nmr	NOUN
eurjchem-411	199	3	(	(	PUNCT
eurjchem-411	199	4	δ	δ	PROPN
eurjchem-411	199	5	ppm	ppm	PROPN
eurjchem-411	199	6	):	):	PUNCT
eurjchem-411	199	7	3.87	3.87	NUM
eurjchem-411	199	8	(	(	PUNCT
eurjchem-411	199	9	s	s	PROPN
eurjchem-411	199	10	,	,	PUNCT
eurjchem-411	199	11	3h	3h	NUM
eurjchem-411	199	12	,	,	PUNCT
eurjchem-411	199	13	ome	ome	PROPN
eurjchem-411	199	14	)	)	PUNCT
eurjchem-411	199	15	,	,	PUNCT
eurjchem-411	199	16	4.83	4.83	NUM
eurjchem-411	199	17	(	(	PUNCT
eurjchem-411	199	18	s	s	PROPN
eurjchem-411	199	19	,	,	PUNCT
eurjchem-411	199	20	br	br	PROPN
eurjchem-411	199	21	,	,	PUNCT
eurjchem-411	199	22	2h	2h	NUM
eurjchem-411	199	23	,	,	PUNCT
eurjchem-411	199	24	nh2	nh2	PROPN
eurjchem-411	199	25	,	,	PUNCT
eurjchem-411	199	26	d2o‐exchangeable	d2o‐exchangeable	PROPN
eurjchem-411	199	27	)	)	PUNCT
eurjchem-411	199	28	,	,	PUNCT
eurjchem-411	199	29	6.57	6.57	NUM
eurjchem-411	199	30	(	(	PUNCT
eurjchem-411	199	31	s	s	PROPN
eurjchem-411	199	32	,	,	PUNCT
eurjchem-411	199	33	2h	2h	NUM
eurjchem-411	199	34	,	,	PUNCT
eurjchem-411	199	35	nh2	nh2	PROPN
eurjchem-411	199	36	,	,	PUNCT
eurjchem-411	199	37	d2o‐	d2o‐	PROPN
eurjchem-411	199	38	exchangeable	exchangeable	ADJ
eurjchem-411	199	39	)	)	PUNCT
eurjchem-411	199	40	,	,	PUNCT
eurjchem-411	199	41	7.10‐7.44	7.10‐7.44	PROPN
eurjchem-411	199	42	(	(	PUNCT
eurjchem-411	199	43	m	m	PROPN
eurjchem-411	199	44	,	,	PUNCT
eurjchem-411	199	45	9h	9h	NUM
eurjchem-411	199	46	,	,	PUNCT
eurjchem-411	199	47	phh	phh	PROPN
eurjchem-411	199	48	,	,	PUNCT
eurjchem-411	199	49	arh	arh	PROPN
eurjchem-411	199	50	)	)	PUNCT
eurjchem-411	199	51	,	,	PUNCT
eurjchem-411	199	52	10.35	10.35	NUM
eurjchem-411	199	53	(	(	PUNCT
eurjchem-411	199	54	s	s	PROPN
eurjchem-411	199	55	,	,	PUNCT
eurjchem-411	199	56	br	br	PROPN
eurjchem-411	199	57	,	,	PUNCT
eurjchem-411	199	58	1h	1h	NUM
eurjchem-411	199	59	,	,	PUNCT
eurjchem-411	199	60	nh	nh	PROPN
eurjchem-411	199	61	,	,	PUNCT
eurjchem-411	199	62	d2o‐exchangeable	d2o‐exchangeable	PROPN
eurjchem-411	199	63	)	)	PUNCT
eurjchem-411	199	64	.	.	PUNCT
eurjchem-411	200	1	ms(m	ms(m	PROPN
eurjchem-411	200	2	/	/	SYM
eurjchem-411	200	3	z	z	PROPN
eurjchem-411	200	4	(	(	PUNCT
eurjchem-411	200	5	%	%	NOUN
eurjchem-411	200	6	)	)	PUNCT
eurjchem-411	200	7	):	):	PUNCT
eurjchem-411	200	8	407	407	NUM
eurjchem-411	200	9	(	(	PUNCT
eurjchem-411	200	10	m+	m+	NUM
eurjchem-411	200	11	,	,	PUNCT
eurjchem-411	200	12	25	25	NUM
eurjchem-411	200	13	%	%	NOUN
eurjchem-411	200	14	)	)	PUNCT
eurjchem-411	200	15	.	.	PUNCT
eurjchem-411	201	1	anal	anal	PROPN
eurjchem-411	201	2	.	.	PUNCT
eurjchem-411	201	3	calcd	calcd	NOUN
eurjchem-411	201	4	.	.	PUNCT
eurjchem-411	202	1	for	for	ADP
eurjchem-411	202	2	c19h17n7o2s	c19h17n7o2s	PROPN
eurjchem-411	202	3	(	(	PUNCT
eurjchem-411	202	4	407.449	407.449	NUM
eurjchem-411	202	5	):	):	PUNCT
eurjchem-411	202	6	c	c	X
eurjchem-411	202	7	,	,	PUNCT
eurjchem-411	202	8	56.01	56.01	NUM
eurjchem-411	202	9	;	;	PUNCT
eurjchem-411	202	10	h	h	NOUN
eurjchem-411	202	11	,	,	PUNCT
eurjchem-411	202	12	4.21	4.21	NUM
eurjchem-411	202	13	;	;	PUNCT
eurjchem-411	202	14	n	n	CCONJ
eurjchem-411	202	15	,	,	PUNCT
eurjchem-411	202	16	24.06	24.06	NUM
eurjchem-411	202	17	;	;	PUNCT
eurjchem-411	202	18	s	s	X
eurjchem-411	202	19	,	,	PUNCT
eurjchem-411	202	20	7.87	7.87	NUM
eurjchem-411	202	21	.	.	PUNCT
eurjchem-411	202	22	found	find	VERB
eurjchem-411	202	23	:	:	PUNCT
eurjchem-411	203	1	c	c	X
eurjchem-411	203	2	,	,	PUNCT
eurjchem-411	203	3	55.76	55.76	NUM
eurjchem-411	203	4	;	;	PUNCT
eurjchem-411	203	5	h	h	NOUN
eurjchem-411	203	6	,	,	PUNCT
eurjchem-411	203	7	4.01	4.01	NUM
eurjchem-411	203	8	;	;	PUNCT
eurjchem-411	203	9	n	n	CCONJ
eurjchem-411	203	10	,	,	PUNCT
eurjchem-411	203	11	23.87	23.87	NUM
eurjchem-411	203	12	;	;	PUNCT
eurjchem-411	203	13	s	s	X
eurjchem-411	203	14	,	,	PUNCT
eurjchem-411	203	15	7.75	7.75	NUM
eurjchem-411	203	16	%	%	NOUN
eurjchem-411	203	17	.	.	PUNCT
eurjchem-411	204	1	2.2.14	2.2.14	X
eurjchem-411	204	2	.	.	PUNCT
eurjchem-411	205	1	synthesis	synthesis	NOUN
eurjchem-411	205	2	of	of	ADP
eurjchem-411	205	3	3‐[2‐amino‐5‐(4‐methoxyphenylazo)‐4‐	3‐[2‐amino‐5‐(4‐methoxyphenylazo)‐4‐	NUM
eurjchem-411	205	4	phenylthiophen‐3‐yl]‐6‐phenyl‐7h‐1,2,4‐triazolo[3,4‐b]‐	phenylthiophen‐3‐yl]‐6‐phenyl‐7h‐1,2,4‐triazolo[3,4‐b]‐	NOUN
eurjchem-411	205	5	1,3,4‐thiadiazine	1,3,4‐thiadiazine	NUM
eurjchem-411	205	6	(	(	PUNCT
eurjchem-411	205	7	15	15	NUM
eurjchem-411	205	8	)	)	PUNCT
eurjchem-411	205	9	2.2.14.1	2.2.14.1	NUM
eurjchem-411	205	10	.	.	PUNCT
eurjchem-411	205	11	method	method	VERB
eurjchem-411	205	12	a	a	DET
eurjchem-411	205	13	a	a	DET
eurjchem-411	205	14	solution	solution	NOUN
eurjchem-411	205	15	of	of	ADP
eurjchem-411	205	16	phenacyl	phenacyl	NOUN
eurjchem-411	205	17	bromide	bromide	NOUN
eurjchem-411	205	18	(	(	PUNCT
eurjchem-411	205	19	0.004	0.004	NUM
eurjchem-411	205	20	mol	mol	NOUN
eurjchem-411	205	21	)	)	PUNCT
eurjchem-411	205	22	in	in	ADP
eurjchem-411	205	23	ethanol	ethanol	NOUN
eurjchem-411	205	24	(	(	PUNCT
eurjchem-411	205	25	2	2	NUM
eurjchem-411	205	26	ml	ml	NOUN
eurjchem-411	205	27	)	)	PUNCT
eurjchem-411	205	28	was	be	AUX
eurjchem-411	205	29	added	add	VERB
eurjchem-411	205	30	to	to	ADP
eurjchem-411	205	31	a	a	DET
eurjchem-411	205	32	solution	solution	NOUN
eurjchem-411	205	33	of	of	ADP
eurjchem-411	205	34	4‐aminotriazole‐2‐thione	4‐aminotriazole‐2‐thione	NUM
eurjchem-411	205	35	derivative	derivative	ADJ
eurjchem-411	205	36	13	13	NUM
eurjchem-411	205	37	(	(	PUNCT
eurjchem-411	205	38	0.004	0.004	NUM
eurjchem-411	205	39	mol	mol	NOUN
eurjchem-411	205	40	)	)	PUNCT
eurjchem-411	205	41	and	and	CCONJ
eurjchem-411	205	42	potassium	potassium	NOUN
eurjchem-411	205	43	hydroxide	hydroxide	NOUN
eurjchem-411	205	44	(	(	PUNCT
eurjchem-411	205	45	0.004	0.004	NUM
eurjchem-411	205	46	mol	mol	NOUN
eurjchem-411	205	47	)	)	PUNCT
eurjchem-411	205	48	in	in	ADP
eurjchem-411	205	49	ethanol	ethanol	NOUN
eurjchem-411	205	50	(	(	PUNCT
eurjchem-411	205	51	8	8	NUM
eurjchem-411	205	52	ml	ml	NOUN
eurjchem-411	205	53	)	)	PUNCT
eurjchem-411	205	54	.	.	PUNCT
eurjchem-411	206	1	the	the	DET
eurjchem-411	206	2	reaction	reaction	NOUN
eurjchem-411	206	3	mixture	mixture	NOUN
eurjchem-411	206	4	was	be	AUX
eurjchem-411	206	5	processed	process	VERB
eurjchem-411	206	6	as	as	SCONJ
eurjchem-411	206	7	described	describe	VERB
eurjchem-411	206	8	before	before	ADV
eurjchem-411	206	9	for	for	ADP
eurjchem-411	206	10	the	the	DET
eurjchem-411	206	11	synthesis	synthesis	NOUN
eurjchem-411	206	12	of	of	ADP
eurjchem-411	206	13	9	9	NUM
eurjchem-411	206	14	.	.	PUNCT
eurjchem-411	207	1	it	it	PRON
eurjchem-411	207	2	was	be	AUX
eurjchem-411	207	3	purified	purify	VERB
eurjchem-411	207	4	by	by	ADP
eurjchem-411	207	5	recrystallization	recrystallization	NOUN
eurjchem-411	207	6	from	from	ADP
eurjchem-411	207	7	a	a	DET
eurjchem-411	207	8	mixture	mixture	NOUN
eurjchem-411	207	9	of	of	ADP
eurjchem-411	207	10	ethanol	ethanol	NOUN
eurjchem-411	207	11	and	and	CCONJ
eurjchem-411	207	12	dimethylformamide	dimethylformamide	NOUN
eurjchem-411	207	13	to	to	PART
eurjchem-411	207	14	obtain	obtain	VERB
eurjchem-411	207	15	compound	compound	NOUN
eurjchem-411	207	16	15	15	NUM
eurjchem-411	207	17	as	as	ADP
eurjchem-411	207	18	a	a	DET
eurjchem-411	207	19	dark	dark	ADJ
eurjchem-411	207	20	brown	brown	ADJ
eurjchem-411	207	21	solid	solid	ADJ
eurjchem-411	207	22	(	(	PUNCT
eurjchem-411	207	23	0.73	0.73	NUM
eurjchem-411	207	24	g	g	NOUN
eurjchem-411	207	25	;	;	PUNCT
eurjchem-411	207	26	35	35	NUM
eurjchem-411	207	27	%	%	NOUN
eurjchem-411	207	28	)	)	PUNCT
eurjchem-411	207	29	(	(	PUNCT
eurjchem-411	207	30	scheme	scheme	NOUN
eurjchem-411	207	31	3	3	NUM
eurjchem-411	207	32	)	)	PUNCT
eurjchem-411	207	33	.	.	PUNCT
eurjchem-411	208	1	m.p	m.p	PROPN
eurjchem-411	208	2	.	.	PROPN
eurjchem-411	208	3	:	:	PUNCT
eurjchem-411	209	1	>	>	X
eurjchem-411	209	2	300	300	NUM
eurjchem-411	209	3	c	c	VERB
eurjchem-411	209	4	.	.	PUNCT
eurjchem-411	210	1	ir	ir	PROPN
eurjchem-411	210	2	(	(	PUNCT
eurjchem-411	210	3	ν	ν	NOUN
eurjchem-411	210	4	/	/	SYM
eurjchem-411	210	5	cm‐1	cm‐1	NUM
eurjchem-411	210	6	):	):	PUNCT
eurjchem-411	210	7	3437	3437	NUM
eurjchem-411	210	8	,	,	PUNCT
eurjchem-411	210	9	3346	3346	NUM
eurjchem-411	210	10	(	(	PUNCT
eurjchem-411	210	11	nh2	nh2	PROPN
eurjchem-411	210	12	)	)	PUNCT
eurjchem-411	210	13	,	,	PUNCT
eurjchem-411	210	14	3060	3060	NUM
eurjchem-411	210	15	(	(	PUNCT
eurjchem-411	210	16	ch	ch	NOUN
eurjchem-411	210	17	arom	arom	NOUN
eurjchem-411	210	18	)	)	PUNCT
eurjchem-411	210	19	.	.	PUNCT
eurjchem-411	211	1	1h	1h	NUM
eurjchem-411	211	2	nmr	nmr	NOUN
eurjchem-411	211	3	(	(	PUNCT
eurjchem-411	211	4	δ	δ	PROPN
eurjchem-411	211	5	ppm	ppm	PROPN
eurjchem-411	211	6	):	):	PUNCT
eurjchem-411	211	7	3.91	3.91	NUM
eurjchem-411	211	8	(	(	PUNCT
eurjchem-411	211	9	s	s	PROPN
eurjchem-411	211	10	,	,	PUNCT
eurjchem-411	211	11	3h	3h	NUM
eurjchem-411	211	12	,	,	PUNCT
eurjchem-411	211	13	ome	ome	PROPN
eurjchem-411	211	14	)	)	PUNCT
eurjchem-411	211	15	,	,	PUNCT
eurjchem-411	211	16	4.52	4.52	NUM
eurjchem-411	211	17	(	(	PUNCT
eurjchem-411	211	18	s	s	PROPN
eurjchem-411	211	19	,	,	PUNCT
eurjchem-411	211	20	2h	2h	NUM
eurjchem-411	211	21	,	,	PUNCT
eurjchem-411	211	22	sch2	sch2	PROPN
eurjchem-411	211	23	)	)	PUNCT
eurjchem-411	211	24	,	,	PUNCT
eurjchem-411	211	25	6.63	6.63	NUM
eurjchem-411	211	26	(	(	PUNCT
eurjchem-411	211	27	s	s	PROPN
eurjchem-411	211	28	,	,	PUNCT
eurjchem-411	211	29	2h	2h	NUM
eurjchem-411	211	30	,	,	PUNCT
eurjchem-411	211	31	nh2	nh2	PROPN
eurjchem-411	211	32	,	,	PUNCT
eurjchem-411	211	33	d2o‐	d2o‐	PROPN
eurjchem-411	211	34	exchangeable	exchangeable	ADJ
eurjchem-411	211	35	)	)	PUNCT
eurjchem-411	211	36	,	,	PUNCT
eurjchem-411	211	37	7.25‐7.78	7.25‐7.78	NUM
eurjchem-411	211	38	(	(	PUNCT
eurjchem-411	211	39	m	m	PROPN
eurjchem-411	211	40	,	,	PUNCT
eurjchem-411	211	41	14h	14h	NUM
eurjchem-411	211	42	,	,	PUNCT
eurjchem-411	211	43	2phh	2phh	PROPN
eurjchem-411	211	44	,	,	PUNCT
eurjchem-411	211	45	arh	arh	ADJ
eurjchem-411	211	46	)	)	PUNCT
eurjchem-411	211	47	.	.	PUNCT
eurjchem-411	212	1	anal	anal	PROPN
eurjchem-411	212	2	.	.	PUNCT
eurjchem-411	212	3	calcd	calcd	NOUN
eurjchem-411	212	4	.	.	PUNCT
eurjchem-411	213	1	for	for	ADP
eurjchem-411	213	2	c27h21n7os2	c27h21n7os2	NOUN
eurjchem-411	213	3	(	(	PUNCT
eurjchem-411	213	4	523.632	523.632	NUM
eurjchem-411	213	5	):	):	PUNCT
eurjchem-411	213	6	c	c	NOUN
eurjchem-411	213	7	,	,	PUNCT
eurjchem-411	213	8	61.93	61.93	NUM
eurjchem-411	213	9	;	;	PUNCT
eurjchem-411	213	10	h	h	X
eurjchem-411	213	11	,	,	PUNCT
eurjchem-411	213	12	4.04	4.04	NUM
eurjchem-411	213	13	;	;	PUNCT
eurjchem-411	213	14	n	n	CCONJ
eurjchem-411	213	15	,	,	PUNCT
eurjchem-411	213	16	18.72	18.72	NUM
eurjchem-411	213	17	;	;	PUNCT
eurjchem-411	213	18	s	s	PROPN
eurjchem-411	213	19	,	,	PUNCT
eurjchem-411	213	20	12.25	12.25	NUM
eurjchem-411	213	21	.	.	PUNCT
eurjchem-411	213	22	found	find	VERB
eurjchem-411	213	23	:	:	PUNCT
eurjchem-411	214	1	c	c	X
eurjchem-411	214	2	,	,	PUNCT
eurjchem-411	214	3	61.76	61.76	NUM
eurjchem-411	214	4	;	;	PUNCT
eurjchem-411	214	5	h	h	NOUN
eurjchem-411	214	6	,	,	PUNCT
eurjchem-411	214	7	3.94	3.94	NUM
eurjchem-411	214	8	;	;	PUNCT
eurjchem-411	214	9	n	n	CCONJ
eurjchem-411	214	10	,	,	PUNCT
eurjchem-411	214	11	18.48	18.48	NUM
eurjchem-411	214	12	;	;	PUNCT
eurjchem-411	214	13	s	s	NUM
eurjchem-411	214	14	,	,	PUNCT
eurjchem-411	214	15	12.03	12.03	NUM
eurjchem-411	214	16	%	%	NOUN
eurjchem-411	214	17	.	.	PUNCT
eurjchem-411	215	1	2.2.14.2	2.2.14.2	X
eurjchem-411	215	2	.	.	PUNCT
eurjchem-411	216	1	method	method	PROPN
eurjchem-411	216	2	b	b	PROPN
eurjchem-411	216	3	the	the	DET
eurjchem-411	216	4	same	same	ADJ
eurjchem-411	216	5	product	product	NOUN
eurjchem-411	216	6	was	be	AUX
eurjchem-411	216	7	synthesized	synthesize	VERB
eurjchem-411	216	8	from	from	ADP
eurjchem-411	216	9	compound	compound	NOUN
eurjchem-411	216	10	14b	14b	NUM
eurjchem-411	216	11	(	(	PUNCT
eurjchem-411	216	12	0.002	0.002	NUM
eurjchem-411	216	13	mol	mol	NOUN
eurjchem-411	216	14	)	)	PUNCT
eurjchem-411	216	15	and	and	CCONJ
eurjchem-411	216	16	hydrazine	hydrazine	NOUN
eurjchem-411	216	17	hydrate	hydrate	NOUN
eurjchem-411	216	18	(	(	PUNCT
eurjchem-411	216	19	0.005	0.005	NUM
eurjchem-411	216	20	mol	mol	NOUN
eurjchem-411	216	21	)	)	PUNCT
eurjchem-411	216	22	in	in	ADP
eurjchem-411	216	23	a	a	DET
eurjchem-411	216	24	manner	manner	NOUN
eurjchem-411	216	25	similar	similar	ADJ
eurjchem-411	216	26	to	to	ADP
eurjchem-411	216	27	that	that	PRON
eurjchem-411	216	28	described	describe	VERB
eurjchem-411	216	29	before	before	ADV
eurjchem-411	216	30	for	for	ADP
eurjchem-411	216	31	the	the	DET
eurjchem-411	216	32	synthesis	synthesis	NOUN
eurjchem-411	216	33	of	of	ADP
eurjchem-411	216	34	compound	compound	NOUN
eurjchem-411	216	35	13	13	NUM
eurjchem-411	216	36	(	(	PUNCT
eurjchem-411	216	37	reaction	reaction	NOUN
eurjchem-411	216	38	time	time	NOUN
eurjchem-411	216	39	:	:	PUNCT
eurjchem-411	216	40	12	12	NUM
eurjchem-411	216	41	h	h	NOUN
eurjchem-411	216	42	)	)	PUNCT
eurjchem-411	216	43	.	.	PUNCT
eurjchem-411	217	1	it	it	PRON
eurjchem-411	217	2	was	be	AUX
eurjchem-411	217	3	recrystallized	recrystallize	VERB
eurjchem-411	217	4	from	from	ADP
eurjchem-411	217	5	an	an	DET
eurjchem-411	217	6	ethanol	ethanol	NOUN
eurjchem-411	217	7	and	and	CCONJ
eurjchem-411	217	8	dimethylformamide	dimethylformamide	NOUN
eurjchem-411	217	9	mixture	mixture	NOUN
eurjchem-411	217	10	to	to	PART
eurjchem-411	217	11	give	give	VERB
eurjchem-411	217	12	a	a	DET
eurjchem-411	217	13	solid	solid	ADJ
eurjchem-411	217	14	product	product	NOUN
eurjchem-411	217	15	,	,	PUNCT
eurjchem-411	217	16	in	in	ADP
eurjchem-411	217	17	42	42	NUM
eurjchem-411	217	18	%	%	NOUN
eurjchem-411	217	19	yield	yield	NOUN
eurjchem-411	217	20	,	,	PUNCT
eurjchem-411	217	21	identical	identical	ADJ
eurjchem-411	217	22	in	in	ADP
eurjchem-411	217	23	all	all	DET
eurjchem-411	217	24	respects	respect	NOUN
eurjchem-411	217	25	(	(	PUNCT
eurjchem-411	217	26	mp	mp	NOUN
eurjchem-411	217	27	,	,	PUNCT
eurjchem-411	217	28	mixed	mixed	ADJ
eurjchem-411	217	29	mp	mp	PROPN
eurjchem-411	217	30	and	and	CCONJ
eurjchem-411	217	31	ir	ir	PROPN
eurjchem-411	217	32	data	data	PROPN
eurjchem-411	217	33	)	)	PUNCT
eurjchem-411	217	34	to	to	ADP
eurjchem-411	217	35	the	the	DET
eurjchem-411	217	36	n‐amino	n‐amino	PUNCT
eurjchem-411	217	37	compound	compound	NOUN
eurjchem-411	217	38	15	15	NUM
eurjchem-411	217	39	(	(	PUNCT
eurjchem-411	217	40	scheme	scheme	NOUN
eurjchem-411	217	41	3	3	NUM
eurjchem-411	217	42	)	)	PUNCT
eurjchem-411	217	43	.	.	PUNCT
eurjchem-411	218	1	2.2.15	2.2.15	X
eurjchem-411	218	2	.	.	PUNCT
eurjchem-411	218	3	synthesis	synthesis	NOUN
eurjchem-411	218	4	of	of	ADP
eurjchem-411	218	5	2‐[2‐n‐acetylamino‐5‐(4‐methoxy	2‐[2‐n‐acetylamino‐5‐(4‐methoxy	NUM
eurjchem-411	218	6	phenylazo)‐4‐phenylthiophen‐3‐yl]‐5‐methylthio‐1,3,4‐	phenylazo)‐4‐phenylthiophen‐3‐yl]‐5‐methylthio‐1,3,4‐	NOUN
eurjchem-411	218	7	oxadiazole	oxadiazole	NOUN
eurjchem-411	218	8	(	(	PUNCT
eurjchem-411	218	9	17	17	NUM
eurjchem-411	218	10	)	)	PUNCT
eurjchem-411	218	11	a	a	DET
eurjchem-411	218	12	stirred	stir	VERB
eurjchem-411	218	13	solution	solution	NOUN
eurjchem-411	218	14	of	of	ADP
eurjchem-411	218	15	compound	compound	NOUN
eurjchem-411	218	16	14a	14a	NOUN
eurjchem-411	218	17	(	(	PUNCT
eurjchem-411	218	18	0.003	0.003	NUM
eurjchem-411	218	19	mol	mol	NOUN
eurjchem-411	218	20	)	)	PUNCT
eurjchem-411	218	21	in	in	ADP
eurjchem-411	218	22	dry	dry	ADJ
eurjchem-411	218	23	pyridine	pyridine	NOUN
eurjchem-411	218	24	(	(	PUNCT
eurjchem-411	218	25	10	10	NUM
eurjchem-411	218	26	ml	ml	NOUN
eurjchem-411	218	27	)	)	PUNCT
eurjchem-411	218	28	,	,	PUNCT
eurjchem-411	218	29	was	be	AUX
eurjchem-411	218	30	treated	treat	VERB
eurjchem-411	218	31	with	with	ADP
eurjchem-411	218	32	acetic	acetic	ADJ
eurjchem-411	218	33	anhydride	anhydride	NOUN
eurjchem-411	218	34	(	(	PUNCT
eurjchem-411	218	35	8	8	NUM
eurjchem-411	218	36	ml	ml	NOUN
eurjchem-411	218	37	)	)	PUNCT
eurjchem-411	218	38	.	.	PUNCT
eurjchem-411	219	1	the	the	DET
eurjchem-411	219	2	reaction	reaction	NOUN
eurjchem-411	219	3	content	content	NOUN
eurjchem-411	219	4	was	be	AUX
eurjchem-411	219	5	kept	keep	VERB
eurjchem-411	219	6	for	for	ADP
eurjchem-411	219	7	48	48	NUM
eurjchem-411	219	8	h	h	NOUN
eurjchem-411	219	9	at	at	ADP
eurjchem-411	219	10	room	room	NOUN
eurjchem-411	219	11	temperature	temperature	NOUN
eurjchem-411	219	12	with	with	ADP
eurjchem-411	219	13	occasional	occasional	ADJ
eurjchem-411	219	14	stirring	stirring	NOUN
eurjchem-411	219	15	and	and	CCONJ
eurjchem-411	219	16	then	then	ADV
eurjchem-411	219	17	poured	pour	VERB
eurjchem-411	219	18	onto	onto	ADP
eurjchem-411	219	19	cruched	cruche	VERB
eurjchem-411	219	20	ice	ice	NOUN
eurjchem-411	219	21	.	.	PUNCT
eurjchem-411	220	1	the	the	DET
eurjchem-411	220	2	material	material	NOUN
eurjchem-411	220	3	which	which	PRON
eurjchem-411	220	4	separated	separate	VERB
eurjchem-411	220	5	out	out	ADP
eurjchem-411	220	6	was	be	AUX
eurjchem-411	220	7	isolated	isolate	VERB
eurjchem-411	220	8	by	by	ADP
eurjchem-411	220	9	filtration	filtration	NOUN
eurjchem-411	220	10	,	,	PUNCT
eurjchem-411	220	11	washed	wash	VERB
eurjchem-411	220	12	with	with	ADP
eurjchem-411	220	13	water	water	NOUN
eurjchem-411	220	14	and	and	CCONJ
eurjchem-411	220	15	dried	dry	VERB
eurjchem-411	220	16	.	.	PUNCT
eurjchem-411	221	1	the	the	DET
eurjchem-411	221	2	residue	residue	NOUN
eurjchem-411	221	3	was	be	AUX
eurjchem-411	221	4	recrystallized	recrystallize	VERB
eurjchem-411	221	5	from	from	ADP
eurjchem-411	221	6	ethanol	ethanol	NOUN
eurjchem-411	221	7	to	to	PART
eurjchem-411	221	8	give	give	VERB
eurjchem-411	221	9	the	the	DET
eurjchem-411	221	10	corresponding	correspond	VERB
eurjchem-411	221	11	2‐acetylamino	2‐acetylamino	NUM
eurjchem-411	221	12	derivative	derivative	ADJ
eurjchem-411	221	13	17	17	NUM
eurjchem-411	221	14	gaber	gaber	NOUN
eurjchem-411	221	15	and	and	CCONJ
eurjchem-411	221	16	bagley	bagley	PROPN
eurjchem-411	221	17	/	/	SYM
eurjchem-411	221	18	european	european	PROPN
eurjchem-411	221	19	journal	journal	PROPN
eurjchem-411	221	20	of	of	ADP
eurjchem-411	221	21	chemistry	chemistry	NOUN
eurjchem-411	221	22	2	2	NUM
eurjchem-411	221	23	(	(	PUNCT
eurjchem-411	221	24	2	2	NUM
eurjchem-411	221	25	)	)	PUNCT
eurjchem-411	221	26	(	(	PUNCT
eurjchem-411	221	27	2011	2011	NUM
eurjchem-411	221	28	)	)	PUNCT
eurjchem-411	221	29	214‐222	214‐222	NOUN
eurjchem-411	221	30	219	219	NUM
eurjchem-411	221	31	as	as	ADP
eurjchem-411	221	32	a	a	DET
eurjchem-411	221	33	canary	canary	ADJ
eurjchem-411	221	34	yellow	yellow	NOUN
eurjchem-411	221	35	solid	solid	ADJ
eurjchem-411	221	36	(	(	PUNCT
eurjchem-411	221	37	0.50	0.50	NUM
eurjchem-411	221	38	g	g	NOUN
eurjchem-411	221	39	;	;	PUNCT
eurjchem-411	221	40	36	36	NUM
eurjchem-411	221	41	%	%	NOUN
eurjchem-411	221	42	)	)	PUNCT
eurjchem-411	221	43	(	(	PUNCT
eurjchem-411	221	44	scheme	scheme	NOUN
eurjchem-411	221	45	3	3	NUM
eurjchem-411	221	46	)	)	PUNCT
eurjchem-411	221	47	.	.	PUNCT
eurjchem-411	222	1	m.p	m.p	PROPN
eurjchem-411	222	2	.	.	PROPN
eurjchem-411	222	3	:	:	PUNCT
eurjchem-411	223	1	154‐	154‐	NUM
eurjchem-411	223	2	155	155	NUM
eurjchem-411	223	3	c	c	NUM
eurjchem-411	223	4	.	.	PUNCT
eurjchem-411	224	1	ir	ir	PROPN
eurjchem-411	224	2	(	(	PUNCT
eurjchem-411	224	3	ν	ν	NOUN
eurjchem-411	224	4	/	/	SYM
eurjchem-411	224	5	cm‐1	cm‐1	NUM
eurjchem-411	224	6	):	):	PUNCT
eurjchem-411	224	7	3270	3270	NUM
eurjchem-411	224	8	(	(	PUNCT
eurjchem-411	224	9	nh	nh	NOUN
eurjchem-411	224	10	)	)	PUNCT
eurjchem-411	224	11	,	,	PUNCT
eurjchem-411	224	12	3065	3065	NUM
eurjchem-411	224	13	(	(	PUNCT
eurjchem-411	224	14	arom	arom	NOUN
eurjchem-411	224	15	ch	ch	NOUN
eurjchem-411	224	16	)	)	PUNCT
eurjchem-411	224	17	,	,	PUNCT
eurjchem-411	224	18	1681	1681	NUM
eurjchem-411	224	19	(	(	PUNCT
eurjchem-411	224	20	co	co	NOUN
eurjchem-411	224	21	)	)	PUNCT
eurjchem-411	224	22	,	,	PUNCT
eurjchem-411	224	23	1064	1064	NUM
eurjchem-411	224	24	(	(	PUNCT
eurjchem-411	224	25	c‐o‐c	c‐o‐c	NOUN
eurjchem-411	224	26	)	)	PUNCT
eurjchem-411	224	27	.	.	PUNCT
eurjchem-411	225	1	1h	1h	NUM
eurjchem-411	225	2	nmr	nmr	NOUN
eurjchem-411	225	3	(	(	PUNCT
eurjchem-411	225	4	δ	δ	PROPN
eurjchem-411	225	5	ppm	ppm	PROPN
eurjchem-411	225	6	):	):	PUNCT
eurjchem-411	225	7	2.18	2.18	NUM
eurjchem-411	225	8	(	(	PUNCT
eurjchem-411	225	9	s	s	PROPN
eurjchem-411	225	10	,	,	PUNCT
eurjchem-411	225	11	3h	3h	NUM
eurjchem-411	225	12	,	,	PUNCT
eurjchem-411	225	13	come	come	NOUN
eurjchem-411	225	14	)	)	PUNCT
eurjchem-411	225	15	,	,	PUNCT
eurjchem-411	225	16	2.76	2.76	NUM
eurjchem-411	225	17	(	(	PUNCT
eurjchem-411	225	18	s	s	PROPN
eurjchem-411	225	19	,	,	PUNCT
eurjchem-411	225	20	3h	3h	NUM
eurjchem-411	225	21	,	,	PUNCT
eurjchem-411	225	22	sme	sme	NOUN
eurjchem-411	225	23	)	)	PUNCT
eurjchem-411	225	24	,	,	PUNCT
eurjchem-411	225	25	3.85	3.85	NUM
eurjchem-411	225	26	(	(	PUNCT
eurjchem-411	225	27	s	s	PROPN
eurjchem-411	225	28	,	,	PUNCT
eurjchem-411	225	29	3h	3h	NUM
eurjchem-411	225	30	,	,	PUNCT
eurjchem-411	225	31	ome	ome	PROPN
eurjchem-411	225	32	)	)	PUNCT
eurjchem-411	225	33	,	,	PUNCT
eurjchem-411	225	34	7.13‐7.42	7.13‐7.42	NUM
eurjchem-411	225	35	(	(	PUNCT
eurjchem-411	225	36	m	m	PROPN
eurjchem-411	225	37	,	,	PUNCT
eurjchem-411	225	38	9h	9h	NUM
eurjchem-411	225	39	,	,	PUNCT
eurjchem-411	225	40	phh	phh	PROPN
eurjchem-411	225	41	,	,	PUNCT
eurjchem-411	225	42	arh	arh	PROPN
eurjchem-411	225	43	)	)	PUNCT
eurjchem-411	225	44	,	,	PUNCT
eurjchem-411	225	45	10.54	10.54	NUM
eurjchem-411	225	46	(	(	PUNCT
eurjchem-411	225	47	s	s	PROPN
eurjchem-411	225	48	,	,	PUNCT
eurjchem-411	225	49	1h	1h	NUM
eurjchem-411	225	50	,	,	PUNCT
eurjchem-411	225	51	nh	nh	PROPN
eurjchem-411	225	52	,	,	PUNCT
eurjchem-411	225	53	d2o‐exchangeable	d2o‐exchangeable	PROPN
eurjchem-411	225	54	)	)	PUNCT
eurjchem-411	225	55	.	.	PUNCT
eurjchem-411	226	1	ms	ms	NOUN
eurjchem-411	226	2	(	(	PUNCT
eurjchem-411	226	3	m	m	PROPN
eurjchem-411	226	4	/	/	SYM
eurjchem-411	226	5	z	z	NOUN
eurjchem-411	226	6	(	(	PUNCT
eurjchem-411	226	7	%	%	NOUN
eurjchem-411	226	8	)	)	PUNCT
eurjchem-411	226	9	):	):	PUNCT
eurjchem-411	226	10	465	465	NUM
eurjchem-411	226	11	(	(	PUNCT
eurjchem-411	226	12	m+	m+	NUM
eurjchem-411	226	13	,	,	PUNCT
eurjchem-411	226	14	19	19	NUM
eurjchem-411	226	15	%	%	NOUN
eurjchem-411	226	16	)	)	PUNCT
eurjchem-411	226	17	.	.	PUNCT
eurjchem-411	227	1	anal	anal	PROPN
eurjchem-411	227	2	.	.	PUNCT
eurjchem-411	227	3	calcd	calcd	NOUN
eurjchem-411	227	4	.	.	PUNCT
eurjchem-411	228	1	for	for	ADP
eurjchem-411	228	2	c22h19n5o3s2	c22h19n5o3s2	NOUN
eurjchem-411	228	3	(	(	PUNCT
eurjchem-411	228	4	465.548	465.548	NUM
eurjchem-411	228	5	):	):	PUNCT
eurjchem-411	228	6	c	c	X
eurjchem-411	228	7	,	,	PUNCT
eurjchem-411	228	8	56.76	56.76	NUM
eurjchem-411	228	9	;	;	PUNCT
eurjchem-411	228	10	h	h	NOUN
eurjchem-411	228	11	,	,	PUNCT
eurjchem-411	228	12	4.11	4.11	NUM
eurjchem-411	228	13	;	;	PUNCT
eurjchem-411	228	14	n	n	CCONJ
eurjchem-411	228	15	,	,	PUNCT
eurjchem-411	228	16	15.04	15.04	NUM
eurjchem-411	228	17	;	;	PUNCT
eurjchem-411	228	18	s	s	X
eurjchem-411	228	19	,	,	PUNCT
eurjchem-411	228	20	13.78	13.78	NUM
eurjchem-411	228	21	.	.	PUNCT
eurjchem-411	228	22	found	find	VERB
eurjchem-411	228	23	:	:	PUNCT
eurjchem-411	229	1	c	c	X
eurjchem-411	229	2	,	,	PUNCT
eurjchem-411	229	3	56.54	56.54	NUM
eurjchem-411	229	4	;	;	PUNCT
eurjchem-411	229	5	h	h	NOUN
eurjchem-411	229	6	,	,	PUNCT
eurjchem-411	229	7	3.99	3.99	NUM
eurjchem-411	229	8	;	;	PUNCT
eurjchem-411	229	9	n	n	CCONJ
eurjchem-411	229	10	,	,	PUNCT
eurjchem-411	229	11	14.83	14.83	NUM
eurjchem-411	229	12	;	;	PUNCT
eurjchem-411	229	13	s	s	NOUN
eurjchem-411	229	14	,	,	PUNCT
eurjchem-411	229	15	13.60	13.60	NUM
eurjchem-411	229	16	%	%	NOUN
eurjchem-411	229	17	.	.	PUNCT
eurjchem-411	230	1	2.3	2.3	NUM
eurjchem-411	230	2	.	.	PUNCT
eurjchem-411	231	1	microbiology	microbiology	NOUN
eurjchem-411	231	2	2.3.1	2.3.1	NUM
eurjchem-411	231	3	.	.	PUNCT
eurjchem-411	231	4	antimicrobial	antimicrobial	ADJ
eurjchem-411	231	5	activity	activity	NOUN
eurjchem-411	231	6	the	the	DET
eurjchem-411	231	7	preliminary	preliminary	ADJ
eurjchem-411	231	8	antimicrobial	antimicrobial	ADJ
eurjchem-411	231	9	activity	activity	NOUN
eurjchem-411	231	10	was	be	AUX
eurjchem-411	231	11	investigated	investigate	VERB
eurjchem-411	231	12	on	on	ADP
eurjchem-411	231	13	four	four	NUM
eurjchem-411	231	14	newly‐obtained	newly‐obtaine	VERB
eurjchem-411	231	15	condensed	condense	VERB
eurjchem-411	231	16	thiophenes	thiophene	NOUN
eurjchem-411	231	17	containing	contain	VERB
eurjchem-411	231	18	different	different	ADJ
eurjchem-411	231	19	n‐heterocyclic	n‐heterocyclic	PUNCT
eurjchem-411	231	20	moieties	moiety	NOUN
eurjchem-411	231	21	as	as	ADV
eurjchem-411	231	22	well	well	ADV
eurjchem-411	231	23	as	as	ADP
eurjchem-411	231	24	six	six	NUM
eurjchem-411	231	25	new	new	ADJ
eurjchem-411	231	26	uncondensed	uncondensed	ADJ
eurjchem-411	231	27	thiophenes	thiophene	NOUN
eurjchem-411	231	28	having	have	VERB
eurjchem-411	231	29	various	various	ADJ
eurjchem-411	231	30	heterocycles	heterocycle	NOUN
eurjchem-411	231	31	at	at	ADP
eurjchem-411	231	32	position	position	NOUN
eurjchem-411	231	33	3	3	NUM
eurjchem-411	231	34	in	in	ADP
eurjchem-411	231	35	order	order	NOUN
eurjchem-411	231	36	to	to	PART
eurjchem-411	231	37	increase	increase	VERB
eurjchem-411	231	38	the	the	DET
eurjchem-411	231	39	selectivity	selectivity	NOUN
eurjchem-411	231	40	of	of	ADP
eurjchem-411	231	41	these	these	DET
eurjchem-411	231	42	derivatives	derivative	NOUN
eurjchem-411	231	43	towards	towards	ADP
eurjchem-411	231	44	test	test	NOUN
eurjchem-411	231	45	microorganisms	microorganism	NOUN
eurjchem-411	231	46	.	.	PUNCT
eurjchem-411	232	1	screening	screen	VERB
eurjchem-411	232	2	results	result	NOUN
eurjchem-411	232	3	are	be	AUX
eurjchem-411	232	4	summarized	summarize	VERB
eurjchem-411	232	5	in	in	ADP
eurjchem-411	232	6	table	table	NOUN
eurjchem-411	232	7	1	1	NUM
eurjchem-411	232	8	.	.	PUNCT
eurjchem-411	232	9	table	table	NOUN
eurjchem-411	232	10	1	1	NUM
eurjchem-411	232	11	.	.	PUNCT
eurjchem-411	233	1	in	in	ADP
eurjchem-411	233	2	vitro	vitro	X
eurjchem-411	233	3	antimicrobial	antimicrobial	ADJ
eurjchem-411	233	4	activity	activity	NOUN
eurjchem-411	233	5	of	of	ADP
eurjchem-411	233	6	test	test	NOUN
eurjchem-411	233	7	compoundsa	compoundsa	PROPN
eurjchem-411	233	8	compd	compd	PROPN
eurjchem-411	233	9	.	.	PUNCT
eurjchem-411	234	1	izdb	izdb	PROPN
eurjchem-411	234	2	(	(	PUNCT
eurjchem-411	234	3	mm	mm	NOUN
eurjchem-411	234	4	)	)	PUNCT
eurjchem-411	234	5	bacteria	bacteria	NOUN
eurjchem-411	234	6	fungi	fungi	PROPN
eurjchem-411	234	7	e.	e.	PROPN
eurjchem-411	234	8	colic	colic	PROPN
eurjchem-411	234	9	s.	s.	PROPN
eurjchem-411	234	10	aureusd	aureusd	PROPN
eurjchem-411	234	11	a.	a.	PROPN
eurjchem-411	234	12	flavus	flavus	PROPN
eurjchem-411	234	13	c.	c.	PROPN
eurjchem-411	234	14	albicans	albican	VERB
eurjchem-411	234	15	5	5	NUM
eurjchem-411	234	16	12	12	NUM
eurjchem-411	234	17	12	12	NUM
eurjchem-411	234	18	0.0	0.0	NUM
eurjchem-411	234	19	0.0	0.0	NUM
eurjchem-411	234	20	8	8	NUM
eurjchem-411	234	21	12	12	NUM
eurjchem-411	234	22	12	12	NUM
eurjchem-411	234	23	18	18	NUM
eurjchem-411	234	24	0.0	0.0	NUM
eurjchem-411	234	25	9	9	NUM
eurjchem-411	234	26	13	13	NUM
eurjchem-411	234	27	14	14	NUM
eurjchem-411	234	28	0.0	0.0	NUM
eurjchem-411	234	29	0.0	0.0	NUM
eurjchem-411	234	30	10	10	NUM
eurjchem-411	234	31	13	13	NUM
eurjchem-411	234	32	15	15	NUM
eurjchem-411	234	33	0.0	0.0	NUM
eurjchem-411	234	34	0.0	0.0	NUM
eurjchem-411	234	35	11	11	NUM
eurjchem-411	234	36	13	13	NUM
eurjchem-411	234	37	14	14	NUM
eurjchem-411	234	38	0.0	0.0	NUM
eurjchem-411	234	39	0.0	0.0	NUM
eurjchem-411	234	40	13	13	NUM
eurjchem-411	234	41	13	13	NUM
eurjchem-411	234	42	13	13	NUM
eurjchem-411	234	43	0.0	0.0	NUM
eurjchem-411	234	44	0.0	0.0	NUM
eurjchem-411	234	45	14a	14a	NOUN
eurjchem-411	234	46	12	12	NUM
eurjchem-411	234	47	12	12	NUM
eurjchem-411	234	48	0.0	0.0	NUM
eurjchem-411	234	49	0.0	0.0	NUM
eurjchem-411	234	50	14b	14b	NUM
eurjchem-411	234	51	13	13	NUM
eurjchem-411	234	52	13	13	NUM
eurjchem-411	234	53	0.0	0.0	NUM
eurjchem-411	234	54	0.0	0.0	NUM
eurjchem-411	234	55	14c	14c	NOUN
eurjchem-411	234	56	12	12	NUM
eurjchem-411	234	57	13	13	NUM
eurjchem-411	234	58	0.0	0.0	NUM
eurjchem-411	234	59	0.0	0.0	NUM
eurjchem-411	234	60	15	15	NUM
eurjchem-411	234	61	14	14	NUM
eurjchem-411	234	62	15	15	NUM
eurjchem-411	234	63	0.0	0.0	NUM
eurjchem-411	234	64	0.0	0.0	NUM
eurjchem-411	234	65	standarde	standarde	VERB
eurjchem-411	234	66	29	29	NUM
eurjchem-411	234	67	28	28	NUM
eurjchem-411	234	68	ntf	ntf	PROPN
eurjchem-411	234	69	ntf	ntf	PROPN
eurjchem-411	234	70	standardg	standardg	PROPN
eurjchem-411	234	71	ntf	ntf	PROPN
eurjchem-411	234	72	ntf	ntf	PROPN
eurjchem-411	234	73	18	18	NUM
eurjchem-411	234	74	20	20	NUM
eurjchem-411	234	75	a	a	DET
eurjchem-411	234	76	dmso	dmso	NOUN
eurjchem-411	234	77	has	have	VERB
eurjchem-411	234	78	no	no	DET
eurjchem-411	234	79	antimicrobial	antimicrobial	ADJ
eurjchem-411	234	80	activity	activity	NOUN
eurjchem-411	234	81	at	at	ADP
eurjchem-411	234	82	the	the	DET
eurjchem-411	234	83	concentration	concentration	NOUN
eurjchem-411	234	84	used	use	VERB
eurjchem-411	234	85	to	to	PART
eurjchem-411	234	86	dissolve	dissolve	VERB
eurjchem-411	234	87	the	the	DET
eurjchem-411	234	88	test	test	NOUN
eurjchem-411	234	89	compounds	compound	NOUN
eurjchem-411	234	90	b	b	NOUN
eurjchem-411	234	91	izd	izd	PRON
eurjchem-411	234	92	:	:	PUNCT
eurjchem-411	234	93	inhibition	inhibition	NOUN
eurjchem-411	234	94	zone	zone	NOUN
eurjchem-411	234	95	diameter	diameter	NOUN
eurjchem-411	234	96	c	c	PROPN
eurjchem-411	234	97	gram‐	gram‐	PROPN
eurjchem-411	234	98	negative	negative	ADJ
eurjchem-411	234	99	d	d	PROPN
eurjchem-411	234	100	gram‐	gram‐	PROPN
eurjchem-411	234	101	positive	positive	ADJ
eurjchem-411	234	102	e	e	NOUN
eurjchem-411	234	103	standard	standard	NOUN
eurjchem-411	234	104	for	for	ADP
eurjchem-411	234	105	bacteria	bacteria	NOUN
eurjchem-411	234	106	:	:	PUNCT
eurjchem-411	234	107	tetracycline	tetracycline	PROPN
eurjchem-411	234	108	f	f	PROPN
eurjchem-411	234	109	not	not	PART
eurjchem-411	234	110	tested	test	VERB
eurjchem-411	234	111	g	g	PROPN
eurjchem-411	234	112	standard	standard	NOUN
eurjchem-411	234	113	for	for	ADP
eurjchem-411	234	114	fungi	fungi	PROPN
eurjchem-411	234	115	:	:	PUNCT
eurjchem-411	234	116	amphotericin	amphotericin	ADP
eurjchem-411	234	117	b	b	PROPN
eurjchem-411	234	118	2.3.2	2.3.2	NUM
eurjchem-411	234	119	.	.	PUNCT
eurjchem-411	235	1	materials	material	NOUN
eurjchem-411	235	2	escherichia	escherichia	NOUN
eurjchem-411	235	3	coli	coli	NOUN
eurjchem-411	235	4	,	,	PUNCT
eurjchem-411	235	5	staphylococcus	staphylococcus	NOUN
eurjchem-411	235	6	aureus	aureus	NOUN
eurjchem-411	235	7	,	,	PUNCT
eurjchem-411	235	8	aspergillus	aspergillus	NOUN
eurjchem-411	235	9	flavus	flavus	NOUN
eurjchem-411	235	10	and	and	CCONJ
eurjchem-411	235	11	candida	candida	NOUN
eurjchem-411	235	12	albicans	albican	NOUN
eurjchem-411	235	13	were	be	AUX
eurjchem-411	235	14	used	use	VERB
eurjchem-411	235	15	against	against	ADP
eurjchem-411	235	16	the	the	DET
eurjchem-411	235	17	test	test	NOUN
eurjchem-411	235	18	compounds	compound	NOUN
eurjchem-411	235	19	and	and	CCONJ
eurjchem-411	235	20	were	be	AUX
eurjchem-411	235	21	obtained	obtain	VERB
eurjchem-411	235	22	from	from	ADP
eurjchem-411	235	23	the	the	DET
eurjchem-411	235	24	micro	micro	ADJ
eurjchem-411	235	25	analytical	analytical	ADJ
eurjchem-411	235	26	center	center	NOUN
eurjchem-411	235	27	in	in	ADP
eurjchem-411	235	28	cairo	cairo	PROPN
eurjchem-411	235	29	university	university	PROPN
eurjchem-411	235	30	,	,	PUNCT
eurjchem-411	235	31	cairo	cairo	PROPN
eurjchem-411	235	32	,	,	PUNCT
eurjchem-411	235	33	egypt	egypt	PROPN
eurjchem-411	235	34	.	.	PUNCT
eurjchem-411	235	35	tetracycline	tetracycline	PROPN
eurjchem-411	235	36	and	and	CCONJ
eurjchem-411	235	37	amphotericin	amphotericin	VERB
eurjchem-411	235	38	b	b	NOUN
eurjchem-411	235	39	were	be	AUX
eurjchem-411	235	40	used	use	VERB
eurjchem-411	235	41	as	as	ADP
eurjchem-411	235	42	reference	reference	NOUN
eurjchem-411	235	43	drugs	drug	NOUN
eurjchem-411	235	44	and	and	CCONJ
eurjchem-411	235	45	were	be	AUX
eurjchem-411	235	46	also	also	ADV
eurjchem-411	235	47	obtained	obtain	VERB
eurjchem-411	235	48	from	from	ADP
eurjchem-411	235	49	the	the	DET
eurjchem-411	235	50	same	same	ADJ
eurjchem-411	235	51	source	source	NOUN
eurjchem-411	235	52	.	.	PUNCT
eurjchem-411	236	1	2.3.3	2.3.3	NUM
eurjchem-411	236	2	.	.	X
eurjchem-411	236	3	method	method	VERB
eurjchem-411	236	4	the	the	DET
eurjchem-411	236	5	antimicrobial	antimicrobial	ADJ
eurjchem-411	236	6	profile	profile	NOUN
eurjchem-411	236	7	was	be	AUX
eurjchem-411	236	8	tested	test	VERB
eurjchem-411	236	9	against	against	ADP
eurjchem-411	236	10	gram‐negative	gram‐negative	PROPN
eurjchem-411	236	11	,	,	PUNCT
eurjchem-411	236	12	gram‐positive	gram‐positive	ADJ
eurjchem-411	236	13	bacteria	bacteria	NOUN
eurjchem-411	236	14	,	,	PUNCT
eurjchem-411	236	15	mould	mould	NOUN
eurjchem-411	236	16	and	and	CCONJ
eurjchem-411	236	17	yeast	yeast	NOUN
eurjchem-411	236	18	using	use	VERB
eurjchem-411	236	19	a	a	DET
eurjchem-411	236	20	modified	modify	VERB
eurjchem-411	236	21	kirby‐bauer	kirby‐bauer	NOUN
eurjchem-411	236	22	disc	disc	NOUN
eurjchem-411	236	23	diffusion	diffusion	NOUN
eurjchem-411	236	24	method	method	NOUN
eurjchem-411	236	25	[	[	X
eurjchem-411	236	26	24,25	24,25	NUM
eurjchem-411	236	27	]	]	PUNCT
eurjchem-411	236	28	.	.	PUNCT
eurjchem-411	237	1	the	the	DET
eurjchem-411	237	2	resulting	result	VERB
eurjchem-411	237	3	inhibition	inhibition	NOUN
eurjchem-411	237	4	zone	zone	NOUN
eurjchem-411	237	5	diameters	diameter	NOUN
eurjchem-411	237	6	(	(	PUNCT
eurjchem-411	237	7	izds	izd	VERB
eurjchem-411	237	8	)	)	PUNCT
eurjchem-411	237	9	were	be	AUX
eurjchem-411	237	10	measured	measure	VERB
eurjchem-411	237	11	in	in	ADP
eurjchem-411	237	12	millimeters	millimeter	NOUN
eurjchem-411	237	13	and	and	CCONJ
eurjchem-411	237	14	used	use	VERB
eurjchem-411	237	15	as	as	ADP
eurjchem-411	237	16	criterion	criterion	NOUN
eurjchem-411	237	17	for	for	ADP
eurjchem-411	237	18	the	the	DET
eurjchem-411	237	19	antimicrobial	antimicrobial	ADJ
eurjchem-411	237	20	activity	activity	NOUN
eurjchem-411	237	21	[	[	X
eurjchem-411	237	22	24	24	NUM
eurjchem-411	237	23	]	]	PUNCT
eurjchem-411	237	24	.	.	PUNCT
eurjchem-411	238	1	the	the	DET
eurjchem-411	238	2	size	size	NOUN
eurjchem-411	238	3	of	of	ADP
eurjchem-411	238	4	the	the	DET
eurjchem-411	238	5	clear	clear	ADJ
eurjchem-411	238	6	zone	zone	NOUN
eurjchem-411	238	7	is	be	AUX
eurjchem-411	238	8	proportional	proportional	ADJ
eurjchem-411	238	9	to	to	ADP
eurjchem-411	238	10	the	the	DET
eurjchem-411	238	11	inhibitory	inhibitory	ADJ
eurjchem-411	238	12	action	action	NOUN
eurjchem-411	238	13	of	of	ADP
eurjchem-411	238	14	the	the	DET
eurjchem-411	238	15	compound	compound	NOUN
eurjchem-411	238	16	under	under	ADP
eurjchem-411	238	17	investigation	investigation	NOUN
eurjchem-411	238	18	.	.	PUNCT
eurjchem-411	239	1	2.3.3.1	2.3.3.1	NUM
eurjchem-411	239	2	.	.	PUNCT
eurjchem-411	239	3	preparation	preparation	NOUN
eurjchem-411	239	4	of	of	ADP
eurjchem-411	239	5	solutions	solution	NOUN
eurjchem-411	239	6	of	of	ADP
eurjchem-411	239	7	the	the	DET
eurjchem-411	239	8	compounds	compound	NOUN
eurjchem-411	239	9	tested	test	VERB
eurjchem-411	239	10	and	and	CCONJ
eurjchem-411	239	11	reference	reference	NOUN
eurjchem-411	239	12	drugs	drug	NOUN
eurjchem-411	239	13	standard	standard	ADJ
eurjchem-411	239	14	discs	disc	NOUN
eurjchem-411	239	15	of	of	ADP
eurjchem-411	239	16	the	the	DET
eurjchem-411	239	17	bactericide	bactericide	NOUN
eurjchem-411	239	18	tetracycline	tetracycline	NOUN
eurjchem-411	239	19	and	and	CCONJ
eurjchem-411	239	20	the	the	DET
eurjchem-411	239	21	fungicide	fungicide	NOUN
eurjchem-411	239	22	amphotericin	amphotericin	ADP
eurjchem-411	239	23	b	b	NOUN
eurjchem-411	239	24	served	serve	VERB
eurjchem-411	239	25	as	as	ADP
eurjchem-411	239	26	positive	positive	ADJ
eurjchem-411	239	27	controls	control	NOUN
eurjchem-411	239	28	for	for	ADP
eurjchem-411	239	29	antimicrobial	antimicrobial	ADJ
eurjchem-411	239	30	activity	activity	NOUN
eurjchem-411	239	31	but	but	CCONJ
eurjchem-411	239	32	filter	filter	NOUN
eurjchem-411	239	33	discs	disc	NOUN
eurjchem-411	239	34	impregnated	impregnate	VERB
eurjchem-411	239	35	with	with	ADP
eurjchem-411	239	36	10	10	NUM
eurjchem-411	239	37	µl	µl	NOUN
eurjchem-411	239	38	of	of	ADP
eurjchem-411	239	39	solvent	solvent	NOUN
eurjchem-411	239	40	(	(	PUNCT
eurjchem-411	239	41	distilled	distil	VERB
eurjchem-411	239	42	water	water	NOUN
eurjchem-411	239	43	,	,	PUNCT
eurjchem-411	239	44	chloroform	chloroform	NOUN
eurjchem-411	239	45	,	,	PUNCT
eurjchem-411	239	46	dmso	dmso	NOUN
eurjchem-411	239	47	)	)	PUNCT
eurjchem-411	239	48	were	be	AUX
eurjchem-411	239	49	used	use	VERB
eurjchem-411	239	50	as	as	ADP
eurjchem-411	239	51	a	a	DET
eurjchem-411	239	52	negative	negative	ADJ
eurjchem-411	239	53	control	control	NOUN
eurjchem-411	239	54	.	.	PUNCT
eurjchem-411	240	1	solvent	solvent	ADJ
eurjchem-411	240	2	controls	control	NOUN
eurjchem-411	240	3	showed	show	VERB
eurjchem-411	240	4	no	no	DET
eurjchem-411	240	5	inhibition	inhibition	NOUN
eurjchem-411	240	6	zones	zone	NOUN
eurjchem-411	240	7	,	,	PUNCT
eurjchem-411	240	8	confirming	confirm	VERB
eurjchem-411	240	9	that	that	SCONJ
eurjchem-411	240	10	they	they	PRON
eurjchem-411	240	11	have	have	VERB
eurjchem-411	240	12	no	no	DET
eurjchem-411	240	13	influence	influence	NOUN
eurjchem-411	240	14	on	on	ADP
eurjchem-411	240	15	growth	growth	NOUN
eurjchem-411	240	16	of	of	ADP
eurjchem-411	240	17	the	the	DET
eurjchem-411	240	18	tested	test	VERB
eurjchem-411	240	19	microoganisms	microoganism	NOUN
eurjchem-411	240	20	.	.	PUNCT
eurjchem-411	241	1	2.3.3.2	2.3.3.2	X
eurjchem-411	241	2	.	.	PUNCT
eurjchem-411	242	1	determination	determination	NOUN
eurjchem-411	242	2	of	of	ADP
eurjchem-411	242	3	minimum	minimum	ADJ
eurjchem-411	242	4	inhibitory	inhibitory	ADJ
eurjchem-411	242	5	concentration	concentration	NOUN
eurjchem-411	242	6	determination	determination	NOUN
eurjchem-411	242	7	of	of	ADP
eurjchem-411	242	8	the	the	DET
eurjchem-411	242	9	minimum	minimum	ADJ
eurjchem-411	242	10	inhibitory	inhibitory	ADJ
eurjchem-411	242	11	concentration	concentration	NOUN
eurjchem-411	242	12	(	(	PUNCT
eurjchem-411	242	13	mic	mic	NOUN
eurjchem-411	242	14	)	)	PUNCT
eurjchem-411	242	15	of	of	ADP
eurjchem-411	242	16	compound	compound	NOUN
eurjchem-411	242	17	15	15	NUM
eurjchem-411	242	18	against	against	ADP
eurjchem-411	242	19	s.	s.	PROPN
eurjchem-411	242	20	aureus	aureus	PROPN
eurjchem-411	242	21	was	be	AUX
eurjchem-411	242	22	carried	carry	VERB
eurjchem-411	242	23	out	out	ADP
eurjchem-411	242	24	using	use	VERB
eurjchem-411	242	25	the	the	DET
eurjchem-411	242	26	agar	agar	NOUN
eurjchem-411	242	27	dilution	dilution	NOUN
eurjchem-411	242	28	method	method	NOUN
eurjchem-411	242	29	,	,	PUNCT
eurjchem-411	242	30	according	accord	VERB
eurjchem-411	242	31	to	to	ADP
eurjchem-411	242	32	nccls	nccls	NOUN
eurjchem-411	242	33	guidelines	guideline	NOUN
eurjchem-411	242	34	[	[	X
eurjchem-411	242	35	26	26	NUM
eurjchem-411	242	36	]	]	PUNCT
eurjchem-411	242	37	.	.	PUNCT
eurjchem-411	243	1	mic	mic	ADJ
eurjchem-411	243	2	value	value	NOUN
eurjchem-411	243	3	was	be	AUX
eurjchem-411	243	4	given	give	VERB
eurjchem-411	243	5	in	in	ADP
eurjchem-411	243	6	µg	µg	ADV
eurjchem-411	243	7	/	/	SYM
eurjchem-411	243	8	ml	ml	NOUN
eurjchem-411	243	9	and	and	CCONJ
eurjchem-411	243	10	was	be	AUX
eurjchem-411	243	11	compared	compare	VERB
eurjchem-411	243	12	to	to	ADP
eurjchem-411	243	13	mic	mic	ADJ
eurjchem-411	243	14	value	value	NOUN
eurjchem-411	243	15	for	for	ADP
eurjchem-411	243	16	the	the	DET
eurjchem-411	243	17	standard	standard	ADJ
eurjchem-411	243	18	antibacterial	antibacterial	ADJ
eurjchem-411	243	19	drug	drug	NOUN
eurjchem-411	243	20	tetracycline	tetracycline	NOUN
eurjchem-411	243	21	.	.	PUNCT
eurjchem-411	244	1	screening	screen	VERB
eurjchem-411	244	2	result	result	NOUN
eurjchem-411	244	3	is	be	AUX
eurjchem-411	244	4	summarized	summarize	VERB
eurjchem-411	244	5	in	in	ADP
eurjchem-411	244	6	table	table	NOUN
eurjchem-411	244	7	2	2	NUM
eurjchem-411	244	8	.	.	PUNCT
eurjchem-411	245	1	on	on	ADP
eurjchem-411	245	2	the	the	DET
eurjchem-411	245	3	other	other	ADJ
eurjchem-411	245	4	hand	hand	NOUN
eurjchem-411	245	5	,	,	PUNCT
eurjchem-411	245	6	the	the	DET
eurjchem-411	245	7	mic	mic	ADJ
eurjchem-411	245	8	determination	determination	NOUN
eurjchem-411	245	9	of	of	ADP
eurjchem-411	245	10	compound	compound	NOUN
eurjchem-411	245	11	8	8	NUM
eurjchem-411	245	12	against	against	ADP
eurjchem-411	245	13	a.	a.	NOUN
eurjchem-411	245	14	flavus	flavus	NOUN
eurjchem-411	245	15	was	be	AUX
eurjchem-411	245	16	achieved	achieve	VERB
eurjchem-411	245	17	by	by	ADP
eurjchem-411	245	18	the	the	DET
eurjchem-411	245	19	broth	broth	NOUN
eurjchem-411	245	20	microdilution	microdilution	NOUN
eurjchem-411	245	21	method	method	NOUN
eurjchem-411	245	22	[	[	X
eurjchem-411	245	23	27	27	NUM
eurjchem-411	245	24	]	]	PUNCT
eurjchem-411	245	25	.	.	PUNCT
eurjchem-411	246	1	interestingly	interestingly	ADV
eurjchem-411	246	2	,	,	PUNCT
eurjchem-411	246	3	the	the	DET
eurjchem-411	246	4	mic	mic	NOUN
eurjchem-411	246	5	of	of	ADP
eurjchem-411	246	6	test	test	NOUN
eurjchem-411	246	7	compound	compound	NOUN
eurjchem-411	246	8	8	8	NUM
eurjchem-411	246	9	was	be	AUX
eurjchem-411	246	10	found	find	VERB
eurjchem-411	246	11	almost	almost	ADV
eurjchem-411	246	12	similar	similar	ADJ
eurjchem-411	246	13	to	to	ADP
eurjchem-411	246	14	mic	mic	ADJ
eurjchem-411	246	15	value	value	NOUN
eurjchem-411	246	16	for	for	ADP
eurjchem-411	246	17	the	the	DET
eurjchem-411	246	18	standard	standard	ADJ
eurjchem-411	246	19	antifungal	antifungal	ADJ
eurjchem-411	246	20	drug	drug	NOUN
eurjchem-411	246	21	amphotericin	amphotericin	ADP
eurjchem-411	246	22	b	b	NOUN
eurjchem-411	246	23	(	(	PUNCT
eurjchem-411	246	24	table	table	NOUN
eurjchem-411	246	25	3	3	NUM
eurjchem-411	246	26	)	)	PUNCT
eurjchem-411	246	27	.	.	PUNCT
eurjchem-411	247	1	table	table	NOUN
eurjchem-411	247	2	2	2	NUM
eurjchem-411	247	3	.	.	PUNCT
eurjchem-411	248	1	mic	mic	NOUN
eurjchem-411	248	2	of	of	ADP
eurjchem-411	248	3	compound	compound	NOUN
eurjchem-411	248	4	15	15	NUM
eurjchem-411	248	5	and	and	CCONJ
eurjchem-411	248	6	standard	standard	ADJ
eurjchem-411	248	7	antibacterial	antibacterial	ADJ
eurjchem-411	248	8	drug	drug	NOUN
eurjchem-411	248	9	against	against	ADP
eurjchem-411	248	10	s.	s.	PROPN
eurjchem-411	248	11	aureus	aureus	PROPN
eurjchem-411	248	12	.	.	PUNCT
eurjchem-411	249	1	compd	compd	PROPN
eurjchem-411	249	2	.	.	PUNCT
eurjchem-411	250	1	mica	mica	NOUN
eurjchem-411	250	2	(	(	PUNCT
eurjchem-411	250	3	µg	µg	NOUN
eurjchem-411	250	4	/	/	SYM
eurjchem-411	250	5	ml	ml	NOUN
eurjchem-411	250	6	)	)	PUNCT
eurjchem-411	250	7	s.	s.	PROPN
eurjchem-411	250	8	aureus	aureus	PROPN
eurjchem-411	250	9	(	(	PUNCT
eurjchem-411	250	10	bacteria	bacteria	NOUN
eurjchem-411	250	11	)	)	PUNCT
eurjchem-411	250	12	15	15	NUM
eurjchem-411	250	13	230	230	NUM
eurjchem-411	250	14	standardb	standardb	NOUN
eurjchem-411	250	15	82	82	NUM
eurjchem-411	250	16	a	a	DET
eurjchem-411	250	17	mic	mic	NOUN
eurjchem-411	250	18	:	:	PUNCT
eurjchem-411	250	19	minimum	minimum	ADJ
eurjchem-411	250	20	inhibitory	inhibitory	ADJ
eurjchem-411	250	21	concentration	concentration	NOUN
eurjchem-411	250	22	b	b	PROPN
eurjchem-411	250	23	standard	standard	NOUN
eurjchem-411	250	24	for	for	ADP
eurjchem-411	250	25	bacteria	bacteria	NOUN
eurjchem-411	250	26	:	:	PUNCT
eurjchem-411	250	27	tetracycline	tetracycline	NOUN
eurjchem-411	250	28	table	table	NOUN
eurjchem-411	250	29	3	3	X
eurjchem-411	250	30	.	.	PUNCT
eurjchem-411	251	1	mic	mic	NOUN
eurjchem-411	251	2	of	of	ADP
eurjchem-411	251	3	compound	compound	NOUN
eurjchem-411	251	4	8	8	NUM
eurjchem-411	251	5	and	and	CCONJ
eurjchem-411	251	6	standard	standard	ADJ
eurjchem-411	251	7	antifungal	antifungal	ADJ
eurjchem-411	251	8	drug	drug	NOUN
eurjchem-411	251	9	against	against	ADP
eurjchem-411	251	10	a.	a.	NOUN
eurjchem-411	251	11	flavus	flavus	NOUN
eurjchem-411	251	12	.	.	PUNCT
eurjchem-411	252	1	compd	compd	PROPN
eurjchem-411	252	2	.	.	PUNCT
eurjchem-411	253	1	mica	mica	NOUN
eurjchem-411	253	2	(	(	PUNCT
eurjchem-411	253	3	µg	µg	NOUN
eurjchem-411	253	4	/	/	SYM
eurjchem-411	253	5	ml	ml	NOUN
eurjchem-411	253	6	)	)	PUNCT
eurjchem-411	253	7	a.	a.	NOUN
eurjchem-411	253	8	flavus	flavus	NOUN
eurjchem-411	253	9	(	(	PUNCT
eurjchem-411	253	10	fungus	fungus	NOUN
eurjchem-411	253	11	)	)	PUNCT
eurjchem-411	253	12	8	8	NUM
eurjchem-411	253	13	168	168	NUM
eurjchem-411	253	14	standardb	standardb	NOUN
eurjchem-411	253	15	156	156	NUM
eurjchem-411	253	16	a	a	DET
eurjchem-411	253	17	mic	mic	NOUN
eurjchem-411	253	18	:	:	PUNCT
eurjchem-411	253	19	minimum	minimum	ADJ
eurjchem-411	253	20	inhibitory	inhibitory	ADJ
eurjchem-411	253	21	concentration	concentration	NOUN
eurjchem-411	253	22	b	b	PROPN
eurjchem-411	253	23	standard	standard	NOUN
eurjchem-411	253	24	for	for	ADP
eurjchem-411	253	25	fungi	fungi	PROPN
eurjchem-411	253	26	:	:	PUNCT
eurjchem-411	253	27	amphotericin	amphotericin	ADP
eurjchem-411	253	28	b	b	PROPN
eurjchem-411	253	29	3	3	NUM
eurjchem-411	253	30	.	.	NOUN
eurjchem-411	253	31	results	result	NOUN
eurjchem-411	253	32	and	and	CCONJ
eurjchem-411	253	33	discussion	discussion	NOUN
eurjchem-411	253	34	3.1	3.1	NUM
eurjchem-411	253	35	.	.	PUNCT
eurjchem-411	254	1	chemistry	chemistry	NOUN
eurjchem-411	254	2	the	the	DET
eurjchem-411	254	3	diazo	diazo	NOUN
eurjchem-411	254	4	coupling	coupling	NOUN
eurjchem-411	254	5	reaction	reaction	NOUN
eurjchem-411	254	6	of	of	ADP
eurjchem-411	254	7	the	the	DET
eurjchem-411	254	8	starting	start	VERB
eurjchem-411	254	9	ethyl	ethyl	PROPN
eurjchem-411	254	10	2‐amino‐4‐	2‐amino‐4‐	NUM
eurjchem-411	254	11	phenylthiophene‐3‐carboxylate	phenylthiophene‐3‐carboxylate	PROPN
eurjchem-411	254	12	(	(	PUNCT
eurjchem-411	254	13	1	1	NUM
eurjchem-411	254	14	)	)	PUNCT
eurjchem-411	255	1	[	[	X
eurjchem-411	255	2	18‐22	18‐22	NUM
eurjchem-411	255	3	]	]	PUNCT
eurjchem-411	255	4	with	with	ADP
eurjchem-411	255	5	diazotized	diazotize	VERB
eurjchem-411	255	6	aromatic	aromatic	ADJ
eurjchem-411	255	7	and	and	CCONJ
eurjchem-411	255	8	heterocyclic	heterocyclic	ADJ
eurjchem-411	255	9	amines	amine	NOUN
eurjchem-411	255	10	resulted	result	VERB
eurjchem-411	255	11	in	in	ADP
eurjchem-411	255	12	the	the	DET
eurjchem-411	255	13	formation	formation	NOUN
eurjchem-411	255	14	of	of	ADP
eurjchem-411	255	15	the	the	DET
eurjchem-411	255	16	corresponding	correspond	VERB
eurjchem-411	255	17	5‐aryl‐	5‐aryl‐	NUM
eurjchem-411	255	18	and	and	CCONJ
eurjchem-411	255	19	5‐heteroarylazo	5‐heteroarylazo	NUM
eurjchem-411	255	20	derivatives	derivative	NOUN
eurjchem-411	255	21	2a‐d	2a‐d	NOUN
eurjchem-411	255	22	(	(	PUNCT
eurjchem-411	255	23	scheme	scheme	NOUN
eurjchem-411	255	24	1	1	NUM
eurjchem-411	255	25	)	)	PUNCT
eurjchem-411	255	26	.	.	PUNCT
eurjchem-411	256	1	hydrazinolysis	hydrazinolysis	NOUN
eurjchem-411	256	2	of	of	ADP
eurjchem-411	256	3	4‐methoxyphenylazo	4‐methoxyphenylazo	NUM
eurjchem-411	256	4	derivative	derivative	ADJ
eurjchem-411	256	5	2b	2b	NOUN
eurjchem-411	256	6	in	in	ADP
eurjchem-411	256	7	ethanol	ethanol	NOUN
eurjchem-411	256	8	provided	provide	VERB
eurjchem-411	256	9	the	the	DET
eurjchem-411	256	10	target	target	NOUN
eurjchem-411	256	11	aminocarbohydrazide	aminocarbohydrazide	ADP
eurjchem-411	256	12	3	3	NUM
eurjchem-411	256	13	,	,	PUNCT
eurjchem-411	256	14	whose	whose	DET
eurjchem-411	256	15	structure	structure	NOUN
eurjchem-411	256	16	was	be	AUX
eurjchem-411	256	17	confirmed	confirm	VERB
eurjchem-411	256	18	by	by	ADP
eurjchem-411	256	19	examining	examine	VERB
eurjchem-411	256	20	spectroscopic	spectroscopic	ADJ
eurjchem-411	256	21	data	datum	NOUN
eurjchem-411	256	22	and	and	CCONJ
eurjchem-411	256	23	elemental	elemental	ADJ
eurjchem-411	256	24	analysis	analysis	NOUN
eurjchem-411	256	25	.	.	PUNCT
eurjchem-411	257	1	heterocyclization	heterocyclization	NOUN
eurjchem-411	257	2	of	of	ADP
eurjchem-411	257	3	carbo‐	carbo‐	ADJ
eurjchem-411	257	4	hydrazide	hydrazide	NOUN
eurjchem-411	257	5	3	3	NUM
eurjchem-411	257	6	with	with	ADP
eurjchem-411	257	7	carbon	carbon	NOUN
eurjchem-411	257	8	disulfide	disulfide	NOUN
eurjchem-411	257	9	in	in	ADP
eurjchem-411	257	10	the	the	DET
eurjchem-411	257	11	presence	presence	NOUN
eurjchem-411	257	12	of	of	ADP
eurjchem-411	257	13	potassium	potassium	NOUN
eurjchem-411	257	14	hydroxide	hydroxide	NOUN
eurjchem-411	257	15	in	in	ADP
eurjchem-411	257	16	ethanol	ethanol	NOUN
eurjchem-411	257	17	led	lead	VERB
eurjchem-411	257	18	to	to	ADP
eurjchem-411	257	19	one	one	NUM
eurjchem-411	257	20	isolable	isolable	ADJ
eurjchem-411	257	21	product	product	NOUN
eurjchem-411	257	22	with	with	ADP
eurjchem-411	257	23	molecular	molecular	ADJ
eurjchem-411	257	24	formula	formula	NOUN
eurjchem-411	257	25	c19h15n5o2s2	c19h15n5o2s2	PROPN
eurjchem-411	257	26	,	,	PUNCT
eurjchem-411	257	27	which	which	PRON
eurjchem-411	257	28	may	may	AUX
eurjchem-411	257	29	be	be	AUX
eurjchem-411	257	30	formulated	formulate	VERB
eurjchem-411	257	31	as	as	ADP
eurjchem-411	257	32	thieno[2,3‐	thieno[2,3‐	PROPN
eurjchem-411	257	33	d]pyrimidin‐4‐one	d]pyrimidin‐4‐one	NOUN
eurjchem-411	257	34	4	4	NUM
eurjchem-411	257	35	or	or	CCONJ
eurjchem-411	257	36	1,3,4‐oxadiazole‐2‐thione	1,3,4‐oxadiazole‐2‐thione	NUM
eurjchem-411	257	37	5	5	NUM
eurjchem-411	257	38	.	.	PUNCT
eurjchem-411	258	1	in	in	ADP
eurjchem-411	258	2	the	the	DET
eurjchem-411	258	3	reaction	reaction	NOUN
eurjchem-411	258	4	of	of	ADP
eurjchem-411	258	5	hydrazide	hydrazide	ADJ
eurjchem-411	258	6	3	3	NUM
eurjchem-411	258	7	with	with	ADP
eurjchem-411	258	8	thiourea	thiourea	NOUN
eurjchem-411	258	9	in	in	ADP
eurjchem-411	258	10	dimethylformamide	dimethylformamide	NOUN
eurjchem-411	258	11	we	we	PRON
eurjchem-411	258	12	isolated	isolate	VERB
eurjchem-411	258	13	a	a	DET
eurjchem-411	258	14	product	product	NOUN
eurjchem-411	258	15	whose	whose	DET
eurjchem-411	258	16	analytical	analytical	ADJ
eurjchem-411	258	17	sample	sample	NOUN
eurjchem-411	258	18	exhibited	exhibit	VERB
eurjchem-411	258	19	a	a	DET
eurjchem-411	258	20	different	different	ADJ
eurjchem-411	258	21	melting	melting	NOUN
eurjchem-411	258	22	point	point	NOUN
eurjchem-411	258	23	from	from	ADP
eurjchem-411	258	24	that	that	PRON
eurjchem-411	258	25	obtained	obtain	VERB
eurjchem-411	258	26	by	by	ADP
eurjchem-411	258	27	the	the	DET
eurjchem-411	258	28	former	former	ADJ
eurjchem-411	258	29	route	route	NOUN
eurjchem-411	258	30	and	and	CCONJ
eurjchem-411	258	31	their	their	PRON
eurjchem-411	258	32	mixture	mixture	NOUN
eurjchem-411	258	33	showed	show	VERB
eurjchem-411	258	34	a	a	DET
eurjchem-411	258	35	depression	depression	NOUN
eurjchem-411	258	36	of	of	ADP
eurjchem-411	258	37	the	the	DET
eurjchem-411	258	38	melting	melting	NOUN
eurjchem-411	258	39	point	point	NOUN
eurjchem-411	258	40	although	although	SCONJ
eurjchem-411	258	41	,	,	PUNCT
eurjchem-411	258	42	according	accord	VERB
eurjchem-411	258	43	to	to	ADP
eurjchem-411	258	44	elemental	elemental	ADJ
eurjchem-411	258	45	analysis	analysis	NOUN
eurjchem-411	258	46	data	datum	NOUN
eurjchem-411	258	47	,	,	PUNCT
eurjchem-411	258	48	both	both	DET
eurjchem-411	258	49	products	product	NOUN
eurjchem-411	258	50	had	have	VERB
eurjchem-411	258	51	the	the	DET
eurjchem-411	258	52	composition	composition	NOUN
eurjchem-411	258	53	c19h15n5o2s2	c19h15n5o2s2	NOUN
eurjchem-411	258	54	.	.	PUNCT
eurjchem-411	259	1	nmr	nmr	NOUN
eurjchem-411	259	2	spectroscopic	spectroscopic	ADJ
eurjchem-411	259	3	analyses	analysis	NOUN
eurjchem-411	259	4	were	be	AUX
eurjchem-411	259	5	not	not	PART
eurjchem-411	259	6	completely	completely	ADV
eurjchem-411	259	7	informative	informative	ADJ
eurjchem-411	259	8	from	from	ADP
eurjchem-411	259	9	the	the	DET
eurjchem-411	259	10	standpoint	standpoint	NOUN
eurjchem-411	259	11	of	of	ADP
eurjchem-411	259	12	choosing	choose	VERB
eurjchem-411	259	13	between	between	ADP
eurjchem-411	259	14	the	the	DET
eurjchem-411	259	15	two	two	NUM
eurjchem-411	259	16	isomeric	isomeric	ADJ
eurjchem-411	259	17	structures	structure	NOUN
eurjchem-411	259	18	4	4	NUM
eurjchem-411	259	19	and	and	CCONJ
eurjchem-411	259	20	5	5	NUM
eurjchem-411	259	21	,	,	PUNCT
eurjchem-411	259	22	where	where	SCONJ
eurjchem-411	259	23	the	the	DET
eurjchem-411	259	24	1h	1h	NUM
eurjchem-411	259	25	nmr	nmr	NOUN
eurjchem-411	259	26	spectra	spectra	NOUN
eurjchem-411	259	27	were	be	AUX
eurjchem-411	259	28	similar	similar	ADJ
eurjchem-411	259	29	in	in	ADP
eurjchem-411	259	30	signal	signal	ADJ
eurjchem-411	259	31	positions	position	NOUN
eurjchem-411	259	32	and	and	CCONJ
eurjchem-411	259	33	intensities	intensity	NOUN
eurjchem-411	259	34	.	.	PUNCT
eurjchem-411	260	1	the	the	DET
eurjchem-411	260	2	spectra	spectra	NOUN
eurjchem-411	260	3	contained	contain	VERB
eurjchem-411	260	4	resonances	resonance	NOUN
eurjchem-411	260	5	,	,	PUNCT
eurjchem-411	260	6	which	which	PRON
eurjchem-411	260	7	may	may	AUX
eurjchem-411	260	8	be	be	AUX
eurjchem-411	260	9	assigned	assign	VERB
eurjchem-411	260	10	to	to	ADP
eurjchem-411	260	11	amino	amino	NOUN
eurjchem-411	260	12	groups	group	NOUN
eurjchem-411	260	13	(	(	PUNCT
eurjchem-411	260	14	δh	δh	INTJ
eurjchem-411	260	15	6.20‐6.34	6.20‐6.34	NUM
eurjchem-411	260	16	ppm	ppm	NOUN
eurjchem-411	260	17	)	)	PUNCT
eurjchem-411	260	18	and	and	CCONJ
eurjchem-411	260	19	thioamidic	thioamidic	ADJ
eurjchem-411	260	20	protons	proton	NOUN
eurjchem-411	260	21	(	(	PUNCT
eurjchem-411	260	22	δh	δh	INTJ
eurjchem-411	260	23	12.58‐13.65	12.58‐13.65	NUM
eurjchem-411	260	24	ppm	ppm	NOUN
eurjchem-411	260	25	)	)	PUNCT
eurjchem-411	260	26	,	,	PUNCT
eurjchem-411	260	27	besides	besides	SCONJ
eurjchem-411	260	28	aromatic	aromatic	ADJ
eurjchem-411	260	29	protons	proton	NOUN
eurjchem-411	260	30	.	.	PUNCT
eurjchem-411	261	1	similarly	similarly	ADV
eurjchem-411	261	2	,	,	PUNCT
eurjchem-411	261	3	the	the	DET
eurjchem-411	261	4	13c	13c	NOUN
eurjchem-411	261	5	nmr	nmr	NOUN
eurjchem-411	261	6	spectra	spectra	NOUN
eurjchem-411	261	7	indicated	indicate	VERB
eurjchem-411	261	8	the	the	DET
eurjchem-411	261	9	presence	presence	NOUN
eurjchem-411	261	10	of	of	ADP
eurjchem-411	261	11	fifteen	fifteen	NUM
eurjchem-411	261	12	distinct	distinct	ADJ
eurjchem-411	261	13	carbon	carbon	NOUN
eurjchem-411	261	14	resonances	resonance	NOUN
eurjchem-411	261	15	in	in	ADP
eurjchem-411	261	16	both	both	DET
eurjchem-411	261	17	compounds	compound	NOUN
eurjchem-411	261	18	.	.	PUNCT
eurjchem-411	262	1	however	however	ADV
eurjchem-411	262	2	,	,	PUNCT
eurjchem-411	262	3	ir	ir	PROPN
eurjchem-411	262	4	spectra	spectra	NOUN
eurjchem-411	262	5	of	of	ADP
eurjchem-411	262	6	both	both	DET
eurjchem-411	262	7	compounds	compound	NOUN
eurjchem-411	262	8	were	be	AUX
eurjchem-411	262	9	unambiguously	unambiguously	ADV
eurjchem-411	262	10	able	able	ADJ
eurjchem-411	262	11	to	to	PART
eurjchem-411	262	12	discriminate	discriminate	VERB
eurjchem-411	262	13	between	between	ADP
eurjchem-411	262	14	structures	structure	NOUN
eurjchem-411	262	15	4	4	NUM
eurjchem-411	262	16	and	and	CCONJ
eurjchem-411	262	17	5	5	NUM
eurjchem-411	262	18	,	,	PUNCT
eurjchem-411	262	19	by	by	ADP
eurjchem-411	262	20	the	the	DET
eurjchem-411	262	21	observation	observation	NOUN
eurjchem-411	262	22	of	of	ADP
eurjchem-411	262	23	absorption	absorption	NOUN
eurjchem-411	262	24	bands	band	NOUN
eurjchem-411	262	25	belonging	belong	VERB
eurjchem-411	262	26	to	to	ADP
eurjchem-411	262	27	stretching	stretch	VERB
eurjchem-411	262	28	vibrations	vibration	NOUN
eurjchem-411	262	29	of	of	ADP
eurjchem-411	262	30	nh	nh	PROPN
eurjchem-411	262	31	,	,	PUNCT
eurjchem-411	262	32	nh2	nh2	PROPN
eurjchem-411	262	33	and	and	CCONJ
eurjchem-411	262	34	cs	cs	PROPN
eurjchem-411	262	35	,	,	PUNCT
eurjchem-411	262	36	which	which	PRON
eurjchem-411	262	37	are	be	AUX
eurjchem-411	262	38	characteristic	characteristic	ADJ
eurjchem-411	262	39	for	for	ADP
eurjchem-411	262	40	both	both	DET
eurjchem-411	262	41	structures	structure	NOUN
eurjchem-411	262	42	,	,	PUNCT
eurjchem-411	262	43	and	and	CCONJ
eurjchem-411	262	44	a	a	DET
eurjchem-411	262	45	diagnostically	diagnostically	ADV
eurjchem-411	262	46	important	important	ADJ
eurjchem-411	262	47	band	band	NOUN
eurjchem-411	262	48	at	at	ADP
eurjchem-411	262	49	ν	ν	PROPN
eurjchem-411	262	50	1687	1687	NUM
eurjchem-411	262	51	cm‐1	cm‐1	NOUN
eurjchem-411	262	52	arising	arise	VERB
eurjchem-411	262	53	from	from	ADP
eurjchem-411	262	54	the	the	DET
eurjchem-411	262	55	carbonyl	carbonyl	NOUN
eurjchem-411	262	56	function	function	NOUN
eurjchem-411	262	57	,	,	PUNCT
eurjchem-411	262	58	which	which	PRON
eurjchem-411	262	59	is	be	AUX
eurjchem-411	262	60	characteristic	characteristic	ADJ
eurjchem-411	262	61	only	only	ADV
eurjchem-411	262	62	for	for	ADP
eurjchem-411	262	63	structure	structure	NOUN
eurjchem-411	262	64	4	4	NUM
eurjchem-411	262	65	but	but	CCONJ
eurjchem-411	262	66	not	not	PART
eurjchem-411	262	67	for	for	ADP
eurjchem-411	262	68	5	5	NUM
eurjchem-411	262	69	.	.	PUNCT
eurjchem-411	263	1	on	on	ADP
eurjchem-411	263	2	the	the	DET
eurjchem-411	263	3	basis	basis	NOUN
eurjchem-411	263	4	of	of	ADP
eurjchem-411	263	5	such	such	ADJ
eurjchem-411	263	6	data	datum	NOUN
eurjchem-411	263	7	,	,	PUNCT
eurjchem-411	263	8	it	it	PRON
eurjchem-411	263	9	is	be	AUX
eurjchem-411	263	10	not	not	PART
eurjchem-411	263	11	unreasonable	unreasonable	ADJ
eurjchem-411	263	12	to	to	PART
eurjchem-411	263	13	conclude	conclude	VERB
eurjchem-411	263	14	that	that	SCONJ
eurjchem-411	263	15	the	the	DET
eurjchem-411	263	16	studied	study	VERB
eurjchem-411	263	17	reactions	reaction	NOUN
eurjchem-411	263	18	are	be	AUX
eurjchem-411	263	19	completely	completely	ADV
eurjchem-411	263	20	220	220	NUM
eurjchem-411	263	21	gaber	gaber	NOUN
eurjchem-411	263	22	and	and	CCONJ
eurjchem-411	263	23	bagley	bagley	NOUN
eurjchem-411	263	24	/	/	SYM
eurjchem-411	263	25	european	european	PROPN
eurjchem-411	263	26	journal	journal	PROPN
eurjchem-411	263	27	of	of	ADP
eurjchem-411	263	28	chemistry	chemistry	NOUN
eurjchem-411	263	29	2	2	NUM
eurjchem-411	263	30	(	(	PUNCT
eurjchem-411	263	31	2	2	NUM
eurjchem-411	263	32	)	)	PUNCT
eurjchem-411	263	33	(	(	PUNCT
eurjchem-411	263	34	2011	2011	NUM
eurjchem-411	263	35	)	)	PUNCT
eurjchem-411	263	36	214‐222	214‐222	NOUN
eurjchem-411	263	37	regioselective	regioselective	ADJ
eurjchem-411	263	38	and	and	CCONJ
eurjchem-411	263	39	accordingly	accordingly	ADV
eurjchem-411	263	40	1,3,4‐oxadiazole	1,3,4‐oxadiazole	ADJ
eurjchem-411	263	41	5	5	NUM
eurjchem-411	263	42	is	be	AUX
eurjchem-411	263	43	isolated	isolate	VERB
eurjchem-411	263	44	as	as	ADP
eurjchem-411	263	45	the	the	DET
eurjchem-411	263	46	sole	sole	ADJ
eurjchem-411	263	47	product	product	NOUN
eurjchem-411	263	48	by	by	ADP
eurjchem-411	263	49	reaction	reaction	NOUN
eurjchem-411	263	50	of	of	ADP
eurjchem-411	263	51	hydrazide	hydrazide	ADJ
eurjchem-411	263	52	3	3	NUM
eurjchem-411	263	53	with	with	ADP
eurjchem-411	263	54	carbon	carbon	NOUN
eurjchem-411	263	55	disulfide	disulfide	NOUN
eurjchem-411	263	56	,	,	PUNCT
eurjchem-411	263	57	whereas	whereas	SCONJ
eurjchem-411	263	58	the	the	DET
eurjchem-411	263	59	alternative	alternative	ADJ
eurjchem-411	263	60	site	site	NOUN
eurjchem-411	263	61	of	of	ADP
eurjchem-411	263	62	cyclization	cyclization	NOUN
eurjchem-411	263	63	to	to	ADP
eurjchem-411	263	64	the	the	DET
eurjchem-411	263	65	corresponding	corresponding	ADJ
eurjchem-411	263	66	thienopyrimidinone	thienopyrimidinone	ADJ
eurjchem-411	263	67	4	4	NUM
eurjchem-411	263	68	results	result	NOUN
eurjchem-411	263	69	from	from	ADP
eurjchem-411	263	70	the	the	DET
eurjchem-411	263	71	reaction	reaction	NOUN
eurjchem-411	263	72	of	of	ADP
eurjchem-411	263	73	compound	compound	NOUN
eurjchem-411	263	74	3	3	NUM
eurjchem-411	263	75	with	with	ADP
eurjchem-411	263	76	thiourea	thiourea	NOUN
eurjchem-411	263	77	.	.	PUNCT
eurjchem-411	264	1	this	this	DET
eurjchem-411	264	2	observation	observation	NOUN
eurjchem-411	264	3	is	be	AUX
eurjchem-411	264	4	in	in	ADP
eurjchem-411	264	5	complete	complete	ADJ
eurjchem-411	264	6	agreement	agreement	NOUN
eurjchem-411	264	7	with	with	ADP
eurjchem-411	264	8	previous	previous	ADJ
eurjchem-411	264	9	literature	literature	NOUN
eurjchem-411	264	10	reports	report	NOUN
eurjchem-411	264	11	on	on	ADP
eurjchem-411	264	12	the	the	DET
eurjchem-411	264	13	well‐	well‐	NUM
eurjchem-411	264	14	established	establish	VERB
eurjchem-411	264	15	formation	formation	NOUN
eurjchem-411	264	16	of	of	ADP
eurjchem-411	264	17	1,3,4‐oxadiazoles	1,3,4‐oxadiazoles	NUM
eurjchem-411	264	18	by	by	ADP
eurjchem-411	264	19	heating	heating	NOUN
eurjchem-411	264	20	hydrazides	hydrazide	NOUN
eurjchem-411	264	21	with	with	ADP
eurjchem-411	264	22	carbon	carbon	NOUN
eurjchem-411	264	23	disulfide	disulfide	NOUN
eurjchem-411	264	24	in	in	ADP
eurjchem-411	264	25	the	the	DET
eurjchem-411	264	26	presence	presence	NOUN
eurjchem-411	264	27	of	of	ADP
eurjchem-411	264	28	bases	basis	NOUN
eurjchem-411	264	29	[	[	X
eurjchem-411	264	30	28‐	28‐	NUM
eurjchem-411	264	31	30	30	NUM
eurjchem-411	264	32	]	]	PUNCT
eurjchem-411	264	33	.	.	PUNCT
eurjchem-411	265	1	in	in	ADP
eurjchem-411	265	2	order	order	NOUN
eurjchem-411	265	3	to	to	PART
eurjchem-411	265	4	finally	finally	ADV
eurjchem-411	265	5	confirm	confirm	VERB
eurjchem-411	265	6	the	the	DET
eurjchem-411	265	7	structure	structure	NOUN
eurjchem-411	265	8	of	of	ADP
eurjchem-411	265	9	compounds	compound	NOUN
eurjchem-411	265	10	4	4	NUM
eurjchem-411	265	11	and	and	CCONJ
eurjchem-411	265	12	5	5	NUM
eurjchem-411	265	13	,	,	PUNCT
eurjchem-411	265	14	they	they	PRON
eurjchem-411	265	15	were	be	AUX
eurjchem-411	265	16	subjected	subject	VERB
eurjchem-411	265	17	to	to	ADP
eurjchem-411	265	18	a	a	DET
eurjchem-411	265	19	variety	variety	NOUN
eurjchem-411	265	20	of	of	ADP
eurjchem-411	265	21	chemical	chemical	NOUN
eurjchem-411	265	22	transformations	transformation	NOUN
eurjchem-411	265	23	as	as	SCONJ
eurjchem-411	265	24	illustrated	illustrate	VERB
eurjchem-411	265	25	in	in	ADP
eurjchem-411	265	26	schemes	scheme	NOUN
eurjchem-411	265	27	2	2	NUM
eurjchem-411	265	28	and	and	CCONJ
eurjchem-411	265	29	3	3	NUM
eurjchem-411	265	30	.	.	X
eurjchem-411	266	1	thienopyrimidin‐4‐one	thienopyrimidin‐4‐one	NOUN
eurjchem-411	266	2	4	4	NUM
eurjchem-411	266	3	reacted	react	VERB
eurjchem-411	266	4	with	with	ADP
eurjchem-411	266	5	phenyl	phenyl	NOUN
eurjchem-411	266	6	isothiocyanate	isothiocyanate	NOUN
eurjchem-411	266	7	to	to	PART
eurjchem-411	266	8	produce	produce	VERB
eurjchem-411	266	9	the	the	DET
eurjchem-411	266	10	product	product	NOUN
eurjchem-411	266	11	of	of	ADP
eurjchem-411	266	12	addition	addition	NOUN
eurjchem-411	266	13	/	/	SYM
eurjchem-411	266	14	cyclodesulfurization	cyclodesulfurization	NOUN
eurjchem-411	266	15	for	for	ADP
eurjchem-411	266	16	which	which	PRON
eurjchem-411	266	17	two	two	NUM
eurjchem-411	266	18	isomeric	isomeric	ADJ
eurjchem-411	266	19	structures	structure	NOUN
eurjchem-411	266	20	7	7	NUM
eurjchem-411	266	21	and	and	CCONJ
eurjchem-411	266	22	8	8	NUM
eurjchem-411	266	23	can	can	AUX
eurjchem-411	266	24	be	be	AUX
eurjchem-411	266	25	formulated	formulate	VERB
eurjchem-411	266	26	.	.	PUNCT
eurjchem-411	267	1	the	the	DET
eurjchem-411	267	2	signal	signal	NOUN
eurjchem-411	267	3	of	of	ADP
eurjchem-411	267	4	the	the	DET
eurjchem-411	267	5	n‐amino	n‐amino	PUNCT
eurjchem-411	267	6	group	group	NOUN
eurjchem-411	267	7	,	,	PUNCT
eurjchem-411	267	8	present	present	ADJ
eurjchem-411	267	9	in	in	ADP
eurjchem-411	267	10	the	the	DET
eurjchem-411	267	11	1h	1h	NUM
eurjchem-411	267	12	nmr	nmr	NOUN
eurjchem-411	267	13	spectrum	spectrum	NOUN
eurjchem-411	267	14	of	of	ADP
eurjchem-411	267	15	4	4	NUM
eurjchem-411	267	16	,	,	PUNCT
eurjchem-411	267	17	was	be	AUX
eurjchem-411	267	18	not	not	PART
eurjchem-411	267	19	detectable	detectable	ADJ
eurjchem-411	267	20	for	for	ADP
eurjchem-411	267	21	the	the	DET
eurjchem-411	267	22	isolated	isolated	ADJ
eurjchem-411	267	23	product	product	NOUN
eurjchem-411	267	24	,	,	PUNCT
eurjchem-411	267	25	demonstrating	demonstrate	VERB
eurjchem-411	267	26	the	the	DET
eurjchem-411	267	27	disappearance	disappearance	NOUN
eurjchem-411	267	28	of	of	ADP
eurjchem-411	267	29	this	this	DET
eurjchem-411	267	30	group	group	NOUN
eurjchem-411	267	31	on	on	ADP
eurjchem-411	267	32	ring	ring	NOUN
eurjchem-411	267	33	closure	closure	NOUN
eurjchem-411	267	34	.	.	PUNCT
eurjchem-411	268	1	elemental	elemental	ADJ
eurjchem-411	268	2	analysis	analysis	NOUN
eurjchem-411	268	3	data	datum	NOUN
eurjchem-411	268	4	could	could	AUX
eurjchem-411	268	5	not	not	PART
eurjchem-411	268	6	discriminate	discriminate	VERB
eurjchem-411	268	7	between	between	ADP
eurjchem-411	268	8	the	the	DET
eurjchem-411	268	9	two	two	NUM
eurjchem-411	268	10	isomeric	isomeric	ADJ
eurjchem-411	268	11	structures	structure	NOUN
eurjchem-411	268	12	7	7	NUM
eurjchem-411	268	13	and	and	CCONJ
eurjchem-411	268	14	8	8	NUM
eurjchem-411	268	15	.	.	PUNCT
eurjchem-411	269	1	however	however	ADV
eurjchem-411	269	2	,	,	PUNCT
eurjchem-411	269	3	the	the	DET
eurjchem-411	269	4	structure	structure	NOUN
eurjchem-411	269	5	of	of	ADP
eurjchem-411	269	6	the	the	DET
eurjchem-411	269	7	isolated	isolated	ADJ
eurjchem-411	269	8	product	product	NOUN
eurjchem-411	269	9	was	be	AUX
eurjchem-411	269	10	considered	consider	VERB
eurjchem-411	269	11	to	to	PART
eurjchem-411	269	12	be	be	AUX
eurjchem-411	269	13	triazoline	triazoline	ADJ
eurjchem-411	269	14	structure	structure	NOUN
eurjchem-411	269	15	8	8	NUM
eurjchem-411	269	16	rather	rather	ADV
eurjchem-411	269	17	than	than	ADP
eurjchem-411	269	18	the	the	DET
eurjchem-411	269	19	alternative	alternative	ADJ
eurjchem-411	269	20	thiadiazole	thiadiazole	NOUN
eurjchem-411	269	21	7	7	NUM
eurjchem-411	269	22	as	as	SCONJ
eurjchem-411	269	23	evidenced	evidence	VERB
eurjchem-411	269	24	by	by	ADP
eurjchem-411	269	25	spectroscopic	spectroscopic	ADJ
eurjchem-411	269	26	studies	study	NOUN
eurjchem-411	269	27	.	.	PUNCT
eurjchem-411	270	1	in	in	ADP
eurjchem-411	270	2	the	the	DET
eurjchem-411	270	3	1h	1h	NUM
eurjchem-411	270	4	nmr	nmr	NOUN
eurjchem-411	270	5	spectrum	spectrum	NOUN
eurjchem-411	270	6	of	of	ADP
eurjchem-411	270	7	the	the	DET
eurjchem-411	270	8	reaction	reaction	NOUN
eurjchem-411	270	9	product	product	NOUN
eurjchem-411	270	10	,	,	PUNCT
eurjchem-411	270	11	the	the	DET
eurjchem-411	270	12	signal	signal	NOUN
eurjchem-411	270	13	associated	associate	VERB
eurjchem-411	270	14	with	with	ADP
eurjchem-411	270	15	the	the	DET
eurjchem-411	270	16	nh	nh	PROPN
eurjchem-411	270	17	proton	proton	NOUN
eurjchem-411	270	18	was	be	AUX
eurjchem-411	270	19	displayed	display	VERB
eurjchem-411	270	20	at	at	ADP
eurjchem-411	270	21	the	the	DET
eurjchem-411	270	22	typical	typical	ADJ
eurjchem-411	270	23	downfield	downfield	NOUN
eurjchem-411	270	24	shift	shift	NOUN
eurjchem-411	270	25	(	(	PUNCT
eurjchem-411	270	26	δh	δh	ADP
eurjchem-411	270	27	13.97	13.97	NUM
eurjchem-411	270	28	ppm	ppm	NOUN
eurjchem-411	270	29	)	)	PUNCT
eurjchem-411	270	30	as	as	ADP
eurjchem-411	270	31	a	a	DET
eurjchem-411	270	32	singlet	singlet	NOUN
eurjchem-411	270	33	which	which	PRON
eurjchem-411	270	34	disappeared	disappear	VERB
eurjchem-411	270	35	upon	upon	SCONJ
eurjchem-411	270	36	addition	addition	NOUN
eurjchem-411	270	37	of	of	ADP
eurjchem-411	270	38	deuterium	deuterium	NOUN
eurjchem-411	270	39	oxide	oxide	NOUN
eurjchem-411	270	40	.	.	PUNCT
eurjchem-411	271	1	this	this	DET
eurjchem-411	271	2	downfield	downfield	VERB
eurjchem-411	271	3	nh	nh	PROPN
eurjchem-411	271	4	resonance	resonance	NOUN
eurjchem-411	271	5	in	in	ADP
eurjchem-411	271	6	the	the	DET
eurjchem-411	271	7	isolated	isolated	ADJ
eurjchem-411	271	8	product	product	NOUN
eurjchem-411	271	9	from	from	ADP
eurjchem-411	271	10	the	the	DET
eurjchem-411	271	11	studied	study	VERB
eurjchem-411	271	12	reaction	reaction	NOUN
eurjchem-411	271	13	can	can	AUX
eurjchem-411	271	14	be	be	AUX
eurjchem-411	271	15	rationalized	rationalize	VERB
eurjchem-411	271	16	in	in	ADP
eurjchem-411	271	17	terms	term	NOUN
eurjchem-411	271	18	of	of	ADP
eurjchem-411	271	19	the	the	DET
eurjchem-411	271	20	presence	presence	NOUN
eurjchem-411	271	21	of	of	ADP
eurjchem-411	271	22	the	the	DET
eurjchem-411	271	23	thione	thione	NOUN
eurjchem-411	271	24	group	group	NOUN
eurjchem-411	271	25	attached	attach	VERB
eurjchem-411	271	26	to	to	ADP
eurjchem-411	271	27	the	the	DET
eurjchem-411	271	28	nitrogen	nitrogen	NOUN
eurjchem-411	271	29	atom	atom	NOUN
eurjchem-411	271	30	linked	link	VERB
eurjchem-411	271	31	to	to	ADP
eurjchem-411	271	32	the	the	DET
eurjchem-411	271	33	thioamide	thioamide	ADJ
eurjchem-411	271	34	proton	proton	NOUN
eurjchem-411	271	35	and	and	CCONJ
eurjchem-411	271	36	as	as	ADP
eurjchem-411	271	37	a	a	DET
eurjchem-411	271	38	result	result	NOUN
eurjchem-411	271	39	this	this	DET
eurjchem-411	271	40	proton	proton	NOUN
eurjchem-411	271	41	is	be	AUX
eurjchem-411	271	42	deshielded	deshielde	VERB
eurjchem-411	271	43	by	by	ADP
eurjchem-411	271	44	the	the	DET
eurjchem-411	271	45	thione	thione	NOUN
eurjchem-411	271	46	group	group	NOUN
eurjchem-411	271	47	and	and	CCONJ
eurjchem-411	271	48	appears	appear	VERB
eurjchem-411	271	49	around	around	ADP
eurjchem-411	271	50	that	that	DET
eurjchem-411	271	51	chemical	chemical	ADJ
eurjchem-411	271	52	shift	shift	NOUN
eurjchem-411	271	53	value	value	NOUN
eurjchem-411	271	54	.	.	PUNCT
eurjchem-411	272	1	this	this	DET
eurjchem-411	272	2	assignment	assignment	NOUN
eurjchem-411	272	3	is	be	AUX
eurjchem-411	272	4	in	in	ADP
eurjchem-411	272	5	line	line	NOUN
eurjchem-411	272	6	with	with	ADP
eurjchem-411	272	7	literature	literature	NOUN
eurjchem-411	272	8	assignments	assignment	NOUN
eurjchem-411	272	9	,	,	PUNCT
eurjchem-411	272	10	that	that	PRON
eurjchem-411	272	11	predict	predict	VERB
eurjchem-411	272	12	this	this	DET
eurjchem-411	272	13	signal	signal	NOUN
eurjchem-411	272	14	would	would	AUX
eurjchem-411	272	15	appear	appear	VERB
eurjchem-411	272	16	typically	typically	ADV
eurjchem-411	272	17	in	in	ADP
eurjchem-411	272	18	the	the	DET
eurjchem-411	272	19	range	range	NOUN
eurjchem-411	272	20	δh	δh	ADP
eurjchem-411	272	21	~	~	PUNCT
eurjchem-411	272	22	13.00‐14.00	13.00‐14.00	NUM
eurjchem-411	272	23	ppm	ppm	NOUN
eurjchem-411	272	24	by	by	ADP
eurjchem-411	272	25	analogy	analogy	NOUN
eurjchem-411	272	26	with	with	ADP
eurjchem-411	272	27	related	relate	VERB
eurjchem-411	272	28	heterocyclic	heterocyclic	ADJ
eurjchem-411	272	29	thioamides	thioamide	NOUN
eurjchem-411	272	30	[	[	X
eurjchem-411	272	31	31‐37	31‐37	NOUN
eurjchem-411	272	32	]	]	PUNCT
eurjchem-411	272	33	.	.	PUNCT
eurjchem-411	273	1	on	on	ADP
eurjchem-411	273	2	the	the	DET
eurjchem-411	273	3	contrary	contrary	NOUN
eurjchem-411	273	4	,	,	PUNCT
eurjchem-411	273	5	the	the	DET
eurjchem-411	273	6	isomeric	isomeric	ADJ
eurjchem-411	273	7	structure	structure	NOUN
eurjchem-411	273	8	7	7	NUM
eurjchem-411	273	9	,	,	PUNCT
eurjchem-411	273	10	if	if	SCONJ
eurjchem-411	273	11	isolated	isolate	VERB
eurjchem-411	273	12	,	,	PUNCT
eurjchem-411	273	13	would	would	AUX
eurjchem-411	273	14	be	be	AUX
eurjchem-411	273	15	expected	expect	VERB
eurjchem-411	273	16	to	to	PART
eurjchem-411	273	17	display	display	VERB
eurjchem-411	273	18	an	an	DET
eurjchem-411	273	19	upfield	upfield	NOUN
eurjchem-411	273	20	shift	shift	NOUN
eurjchem-411	273	21	for	for	ADP
eurjchem-411	273	22	the	the	DET
eurjchem-411	273	23	nh	nh	PROPN
eurjchem-411	273	24	proton	proton	NOUN
eurjchem-411	273	25	due	due	ADP
eurjchem-411	273	26	to	to	ADP
eurjchem-411	273	27	the	the	DET
eurjchem-411	273	28	absence	absence	NOUN
eurjchem-411	273	29	of	of	ADP
eurjchem-411	273	30	deshielding	deshielde	VERB
eurjchem-411	273	31	thione	thione	NOUN
eurjchem-411	273	32	group	group	NOUN
eurjchem-411	273	33	.	.	PUNCT
eurjchem-411	274	1	conclusive	conclusive	ADJ
eurjchem-411	274	2	evidence	evidence	NOUN
eurjchem-411	274	3	for	for	ADP
eurjchem-411	274	4	the	the	DET
eurjchem-411	274	5	proposed	propose	VERB
eurjchem-411	274	6	structure	structure	NOUN
eurjchem-411	274	7	8	8	NUM
eurjchem-411	274	8	was	be	AUX
eurjchem-411	274	9	provided	provide	VERB
eurjchem-411	274	10	by	by	ADP
eurjchem-411	274	11	the	the	DET
eurjchem-411	274	12	13c	13c	NOUN
eurjchem-411	274	13	nmr	nmr	NOUN
eurjchem-411	274	14	spectrum	spectrum	NOUN
eurjchem-411	274	15	of	of	ADP
eurjchem-411	274	16	the	the	DET
eurjchem-411	274	17	isolated	isolated	ADJ
eurjchem-411	274	18	product	product	NOUN
eurjchem-411	274	19	,	,	PUNCT
eurjchem-411	274	20	where	where	SCONJ
eurjchem-411	274	21	a	a	DET
eurjchem-411	274	22	diagnostic	diagnostic	ADJ
eurjchem-411	274	23	signal	signal	NOUN
eurjchem-411	274	24	in	in	ADP
eurjchem-411	274	25	the	the	DET
eurjchem-411	274	26	downfield	downfield	NOUN
eurjchem-411	274	27	region	region	NOUN
eurjchem-411	274	28	typically	typically	ADV
eurjchem-411	274	29	at	at	ADP
eurjchem-411	274	30	δc	δc	PRON
eurjchem-411	274	31	173.2	173.2	NUM
eurjchem-411	274	32	ppm	ppm	NOUN
eurjchem-411	274	33	was	be	AUX
eurjchem-411	274	34	detected	detect	VERB
eurjchem-411	274	35	.	.	PUNCT
eurjchem-411	275	1	such	such	DET
eurjchem-411	275	2	a	a	DET
eurjchem-411	275	3	downfield	downfield	NOUN
eurjchem-411	275	4	signal	signal	NOUN
eurjchem-411	275	5	can	can	AUX
eurjchem-411	275	6	be	be	AUX
eurjchem-411	275	7	assigned	assign	VERB
eurjchem-411	275	8	only	only	ADV
eurjchem-411	275	9	to	to	ADP
eurjchem-411	275	10	the	the	DET
eurjchem-411	275	11	thioamide	thioamide	NOUN
eurjchem-411	275	12	cs	cs	PROPN
eurjchem-411	275	13	carbon	carbon	NOUN
eurjchem-411	275	14	atom	atom	NOUN
eurjchem-411	275	15	,	,	PUNCT
eurjchem-411	275	16	which	which	PRON
eurjchem-411	275	17	was	be	AUX
eurjchem-411	275	18	reported	report	VERB
eurjchem-411	275	19	to	to	PART
eurjchem-411	275	20	appear	appear	VERB
eurjchem-411	275	21	at	at	ADP
eurjchem-411	275	22	δc	δc	NOUN
eurjchem-411	275	23	value	value	NOUN
eurjchem-411	275	24	greater	great	ADJ
eurjchem-411	275	25	than	than	ADP
eurjchem-411	275	26	169	169	NUM
eurjchem-411	275	27	ppm	ppm	NOUN
eurjchem-411	275	28	in	in	ADP
eurjchem-411	275	29	related	related	ADJ
eurjchem-411	275	30	systems	system	NOUN
eurjchem-411	275	31	[	[	X
eurjchem-411	275	32	37‐40	37‐40	NOUN
eurjchem-411	275	33	]	]	PUNCT
eurjchem-411	275	34	.	.	PUNCT
eurjchem-411	276	1	it	it	PRON
eurjchem-411	276	2	is	be	AUX
eurjchem-411	276	3	worthwhile	worthwhile	ADJ
eurjchem-411	276	4	to	to	PART
eurjchem-411	276	5	report	report	VERB
eurjchem-411	276	6	here	here	ADV
eurjchem-411	276	7	that	that	SCONJ
eurjchem-411	276	8	the	the	DET
eurjchem-411	276	9	thione	thione	NOUN
eurjchem-411	276	10	form	form	NOUN
eurjchem-411	276	11	is	be	AUX
eurjchem-411	276	12	the	the	DET
eurjchem-411	276	13	stable	stable	ADJ
eurjchem-411	276	14	form	form	NOUN
eurjchem-411	276	15	in	in	ADP
eurjchem-411	276	16	which	which	PRON
eurjchem-411	276	17	compound	compound	NOUN
eurjchem-411	276	18	8	8	NUM
eurjchem-411	276	19	mainly	mainly	ADV
eurjchem-411	276	20	exists	exist	VERB
eurjchem-411	276	21	since	since	SCONJ
eurjchem-411	276	22	its	its	PRON
eurjchem-411	276	23	ir	ir	PROPN
eurjchem-411	276	24	spectrum	spectrum	NOUN
eurjchem-411	276	25	revealed	reveal	VERB
eurjchem-411	276	26	no	no	DET
eurjchem-411	276	27	absorption	absorption	NOUN
eurjchem-411	276	28	band	band	NOUN
eurjchem-411	276	29	at	at	ADP
eurjchem-411	276	30	around	around	ADP
eurjchem-411	276	31	ν	ν	PRON
eurjchem-411	276	32	2600‐2550	2600‐2550	NUM
eurjchem-411	276	33	cm‐1	cm‐1	NOUN
eurjchem-411	276	34	,	,	PUNCT
eurjchem-411	276	35	which	which	PRON
eurjchem-411	276	36	is	be	AUX
eurjchem-411	276	37	indicative	indicative	ADJ
eurjchem-411	276	38	of	of	ADP
eurjchem-411	276	39	the	the	DET
eurjchem-411	276	40	thiol	thiol	ADJ
eurjchem-411	276	41	form	form	NOUN
eurjchem-411	277	1	[	[	X
eurjchem-411	277	2	35,36,41‐43	35,36,41‐43	NOUN
eurjchem-411	277	3	]	]	X
eurjchem-411	277	4	.	.	PUNCT
eurjchem-411	278	1	in	in	ADP
eurjchem-411	278	2	the	the	DET
eurjchem-411	278	3	1h	1h	NUM
eurjchem-411	278	4	nmr	nmr	NOUN
eurjchem-411	278	5	spectrum	spectrum	NOUN
eurjchem-411	278	6	of	of	ADP
eurjchem-411	278	7	8	8	NUM
eurjchem-411	278	8	,	,	PUNCT
eurjchem-411	278	9	the	the	DET
eurjchem-411	278	10	absence	absence	NOUN
eurjchem-411	278	11	of	of	ADP
eurjchem-411	278	12	a	a	DET
eurjchem-411	278	13	signal	signal	NOUN
eurjchem-411	278	14	due	due	ADP
eurjchem-411	278	15	to	to	ADP
eurjchem-411	278	16	the	the	DET
eurjchem-411	278	17	sh	sh	PROPN
eurjchem-411	278	18	proton	proton	NOUN
eurjchem-411	278	19	that	that	PRON
eurjchem-411	278	20	would	would	AUX
eurjchem-411	278	21	be	be	AUX
eurjchem-411	278	22	expected	expect	VERB
eurjchem-411	278	23	to	to	PART
eurjchem-411	278	24	resonate	resonate	VERB
eurjchem-411	278	25	in	in	ADP
eurjchem-411	278	26	the	the	DET
eurjchem-411	278	27	range	range	NOUN
eurjchem-411	278	28	δh	δh	ADP
eurjchem-411	278	29	1.6‐	1.6‐	NUM
eurjchem-411	278	30	4.0	4.0	NUM
eurjchem-411	278	31	ppm	ppm	NOUN
eurjchem-411	279	1	[	[	X
eurjchem-411	279	2	35,37	35,37	NOUN
eurjchem-411	279	3	]	]	PUNCT
eurjchem-411	279	4	also	also	ADV
eurjchem-411	279	5	provided	provide	VERB
eurjchem-411	279	6	confirmatory	confirmatory	ADJ
eurjchem-411	279	7	evidence	evidence	NOUN
eurjchem-411	279	8	for	for	ADP
eurjchem-411	279	9	thione	thione	ADJ
eurjchem-411	279	10	formation	formation	NOUN
eurjchem-411	279	11	.	.	PUNCT
eurjchem-411	280	1	the	the	DET
eurjchem-411	280	2	prevalence	prevalence	NOUN
eurjchem-411	280	3	of	of	ADP
eurjchem-411	280	4	the	the	DET
eurjchem-411	280	5	thione	thione	NOUN
eurjchem-411	280	6	rather	rather	ADV
eurjchem-411	280	7	than	than	ADP
eurjchem-411	280	8	the	the	DET
eurjchem-411	280	9	thiol	thiol	ADJ
eurjchem-411	280	10	form	form	NOUN
eurjchem-411	280	11	in	in	ADP
eurjchem-411	280	12	a	a	DET
eurjchem-411	280	13	number	number	NOUN
eurjchem-411	280	14	of	of	ADP
eurjchem-411	280	15	heterocyclic	heterocyclic	ADJ
eurjchem-411	280	16	systems	system	NOUN
eurjchem-411	280	17	is	be	AUX
eurjchem-411	280	18	well‐established	well‐establishe	VERB
eurjchem-411	280	19	[	[	X
eurjchem-411	280	20	44‐46	44‐46	X
eurjchem-411	280	21	]	]	X
eurjchem-411	280	22	.	.	PUNCT
eurjchem-411	281	1	the	the	DET
eurjchem-411	281	2	preferred	preferred	ADJ
eurjchem-411	281	3	formation	formation	NOUN
eurjchem-411	281	4	of	of	ADP
eurjchem-411	281	5	the	the	DET
eurjchem-411	281	6	triazoline	triazoline	NOUN
eurjchem-411	281	7	ring	ring	NOUN
eurjchem-411	281	8	under	under	ADP
eurjchem-411	281	9	alkaline	alkaline	NOUN
eurjchem-411	281	10	conditions	condition	NOUN
eurjchem-411	281	11	may	may	AUX
eurjchem-411	281	12	be	be	AUX
eurjchem-411	281	13	due	due	ADJ
eurjchem-411	281	14	to	to	ADP
eurjchem-411	281	15	the	the	DET
eurjchem-411	281	16	enhanced	enhanced	ADJ
eurjchem-411	281	17	nucleophilicity	nucleophilicity	NOUN
eurjchem-411	281	18	of	of	ADP
eurjchem-411	281	19	the	the	DET
eurjchem-411	281	20	nitrogen	nitrogen	NOUN
eurjchem-411	281	21	atom	atom	NOUN
eurjchem-411	281	22	attached	attach	VERB
eurjchem-411	281	23	to	to	ADP
eurjchem-411	281	24	phenyl	phenyl	NOUN
eurjchem-411	281	25	group	group	NOUN
eurjchem-411	281	26	of	of	ADP
eurjchem-411	281	27	the	the	DET
eurjchem-411	281	28	n‐	n‐	PROPN
eurjchem-411	281	29	phenylthiourea	phenylthiourea	PROPN
eurjchem-411	281	30	moiety	moiety	PROPN
eurjchem-411	281	31	in	in	ADP
eurjchem-411	281	32	the	the	DET
eurjchem-411	281	33	acyclic	acyclic	ADJ
eurjchem-411	281	34	adduct	adduct	VERB
eurjchem-411	281	35	6	6	NUM
eurjchem-411	281	36	in	in	ADP
eurjchem-411	281	37	reaction	reaction	NOUN
eurjchem-411	281	38	with	with	ADP
eurjchem-411	281	39	the	the	DET
eurjchem-411	281	40	thione	thione	NOUN
eurjchem-411	281	41	carbon	carbon	NOUN
eurjchem-411	281	42	,	,	PUNCT
eurjchem-411	281	43	particularly	particularly	ADV
eurjchem-411	281	44	on	on	ADP
eurjchem-411	281	45	deprotonation	deprotonation	NOUN
eurjchem-411	281	46	,	,	PUNCT
eurjchem-411	281	47	followed	follow	VERB
eurjchem-411	281	48	by	by	ADP
eurjchem-411	281	49	cyclodesulfurization	cyclodesulfurization	NOUN
eurjchem-411	281	50	[	[	X
eurjchem-411	281	51	47	47	NUM
eurjchem-411	281	52	]	]	PUNCT
eurjchem-411	281	53	.	.	PUNCT
eurjchem-411	282	1	as	as	ADP
eurjchem-411	282	2	a	a	DET
eurjchem-411	282	3	result	result	NOUN
eurjchem-411	282	4	,	,	PUNCT
eurjchem-411	282	5	triazoline‐2‐thione	triazoline‐2‐thione	NOUN
eurjchem-411	282	6	derivative	derivative	ADJ
eurjchem-411	282	7	8	8	NUM
eurjchem-411	282	8	was	be	AUX
eurjchem-411	282	9	isolated	isolate	VERB
eurjchem-411	282	10	as	as	ADP
eurjchem-411	282	11	the	the	DET
eurjchem-411	282	12	sole	sole	ADJ
eurjchem-411	282	13	product	product	NOUN
eurjchem-411	282	14	(	(	PUNCT
eurjchem-411	282	15	scheme	scheme	NOUN
eurjchem-411	282	16	2	2	NUM
eurjchem-411	282	17	)	)	PUNCT
eurjchem-411	282	18	.	.	PUNCT
eurjchem-411	283	1	this	this	DET
eurjchem-411	283	2	protocol	protocol	NOUN
eurjchem-411	283	3	was	be	AUX
eurjchem-411	283	4	also	also	ADV
eurjchem-411	283	5	suitable	suitable	ADJ
eurjchem-411	283	6	for	for	ADP
eurjchem-411	283	7	the	the	DET
eurjchem-411	283	8	synthesis	synthesis	NOUN
eurjchem-411	283	9	of	of	ADP
eurjchem-411	283	10	tricyclic	tricyclic	ADJ
eurjchem-411	283	11	thiadiazines	thiadiazine	NOUN
eurjchem-411	283	12	,	,	PUNCT
eurjchem-411	283	13	where	where	SCONJ
eurjchem-411	283	14	alkylation	alkylation	NOUN
eurjchem-411	283	15	of	of	ADP
eurjchem-411	283	16	thienopyrimidin‐4‐one	thienopyrimidin‐4‐one	NOUN
eurjchem-411	283	17	4	4	NUM
eurjchem-411	283	18	with	with	ADP
eurjchem-411	283	19	phenacyl	phenacyl	NOUN
eurjchem-411	283	20	bromide	bromide	NOUN
eurjchem-411	283	21	in	in	ADP
eurjchem-411	283	22	alkaline	alkaline	NOUN
eurjchem-411	283	23	medium	medium	NOUN
eurjchem-411	283	24	led	lead	VERB
eurjchem-411	283	25	to	to	ADP
eurjchem-411	283	26	the	the	DET
eurjchem-411	283	27	thiadiazine	thiadiazine	NOUN
eurjchem-411	283	28	derivative	derivative	ADJ
eurjchem-411	283	29	9	9	NUM
eurjchem-411	283	30	,	,	PUNCT
eurjchem-411	283	31	whereas	whereas	SCONJ
eurjchem-411	283	32	with	with	ADP
eurjchem-411	283	33	chloroacetic	chloroacetic	ADJ
eurjchem-411	283	34	acid	acid	NOUN
eurjchem-411	283	35	in	in	ADP
eurjchem-411	283	36	the	the	DET
eurjchem-411	283	37	presence	presence	NOUN
eurjchem-411	283	38	of	of	ADP
eurjchem-411	283	39	sodium	sodium	NOUN
eurjchem-411	283	40	acetate	acetate	NOUN
eurjchem-411	283	41	the	the	DET
eurjchem-411	283	42	product	product	NOUN
eurjchem-411	283	43	was	be	AUX
eurjchem-411	283	44	identified	identify	VERB
eurjchem-411	283	45	as	as	ADP
eurjchem-411	283	46	thiadiazinone	thiadiazinone	NOUN
eurjchem-411	283	47	derivative	derivative	ADJ
eurjchem-411	283	48	10	10	NUM
eurjchem-411	283	49	.	.	PUNCT
eurjchem-411	284	1	moreover	moreover	ADV
eurjchem-411	284	2	,	,	PUNCT
eurjchem-411	284	3	compound	compound	NOUN
eurjchem-411	284	4	10	10	NUM
eurjchem-411	284	5	could	could	AUX
eurjchem-411	284	6	be	be	AUX
eurjchem-411	284	7	also	also	ADV
eurjchem-411	284	8	obtained	obtain	VERB
eurjchem-411	284	9	by	by	ADP
eurjchem-411	284	10	an	an	DET
eurjchem-411	284	11	alternative	alternative	ADJ
eurjchem-411	284	12	method	method	NOUN
eurjchem-411	284	13	utilizing	utilize	VERB
eurjchem-411	284	14	the	the	DET
eurjchem-411	284	15	reaction	reaction	NOUN
eurjchem-411	284	16	of	of	ADP
eurjchem-411	284	17	pyrimidinone	pyrimidinone	NOUN
eurjchem-411	284	18	derivative	derivative	ADJ
eurjchem-411	284	19	4	4	NUM
eurjchem-411	284	20	with	with	ADP
eurjchem-411	284	21	ethyl	ethyl	PROPN
eurjchem-411	284	22	chloroacetate	chloroacetate	NOUN
eurjchem-411	284	23	in	in	ADP
eurjchem-411	284	24	ethanolic	ethanolic	ADJ
eurjchem-411	284	25	sodium	sodium	NOUN
eurjchem-411	284	26	ethoxide	ethoxide	NOUN
eurjchem-411	284	27	solution	solution	NOUN
eurjchem-411	284	28	.	.	PUNCT
eurjchem-411	285	1	the	the	DET
eurjchem-411	285	2	latter	latter	ADJ
eurjchem-411	285	3	products	product	NOUN
eurjchem-411	285	4	9	9	NUM
eurjchem-411	285	5	and	and	CCONJ
eurjchem-411	285	6	10	10	NUM
eurjchem-411	285	7	are	be	AUX
eurjchem-411	285	8	assumed	assume	VERB
eurjchem-411	285	9	to	to	PART
eurjchem-411	285	10	be	be	AUX
eurjchem-411	285	11	formed	form	VERB
eurjchem-411	285	12	via	via	ADP
eurjchem-411	285	13	initial	initial	ADJ
eurjchem-411	285	14	s‐alkylation	s‐alkylation	NUM
eurjchem-411	285	15	of	of	ADP
eurjchem-411	285	16	amino‐thioxo	amino‐thioxo	PROPN
eurjchem-411	285	17	derivative	derivative	ADJ
eurjchem-411	285	18	4	4	NUM
eurjchem-411	285	19	,	,	PUNCT
eurjchem-411	285	20	followed	follow	VERB
eurjchem-411	285	21	by	by	ADP
eurjchem-411	285	22	cyclocondensation	cyclocondensation	NOUN
eurjchem-411	285	23	in	in	ADP
eurjchem-411	285	24	a	a	DET
eurjchem-411	285	25	fashion	fashion	NOUN
eurjchem-411	285	26	similar	similar	ADJ
eurjchem-411	285	27	to	to	ADP
eurjchem-411	285	28	established	establish	VERB
eurjchem-411	285	29	α‐aminothione	α‐aminothione	NUM
eurjchem-411	285	30	derivatizations	derivatization	NOUN
eurjchem-411	285	31	[	[	X
eurjchem-411	285	32	48‐50	48‐50	NUM
eurjchem-411	285	33	]	]	PUNCT
eurjchem-411	285	34	.	.	PUNCT
eurjchem-411	286	1	by	by	ADP
eurjchem-411	286	2	reaction	reaction	NOUN
eurjchem-411	286	3	of	of	ADP
eurjchem-411	286	4	compound	compound	NOUN
eurjchem-411	286	5	4	4	NUM
eurjchem-411	286	6	with	with	ADP
eurjchem-411	286	7	benzoic	benzoic	ADJ
eurjchem-411	286	8	acid	acid	NOUN
eurjchem-411	286	9	in	in	ADP
eurjchem-411	286	10	the	the	DET
eurjchem-411	286	11	presence	presence	NOUN
eurjchem-411	286	12	of	of	ADP
eurjchem-411	286	13	phosphorus	phosphorus	NOUN
eurjchem-411	286	14	oxychloride	oxychloride	NOUN
eurjchem-411	286	15	we	we	PRON
eurjchem-411	286	16	obtained	obtain	VERB
eurjchem-411	286	17	the	the	DET
eurjchem-411	286	18	thiadiazole	thiadiazole	NOUN
eurjchem-411	286	19	derivative	derivative	ADJ
eurjchem-411	286	20	11	11	NUM
eurjchem-411	286	21	via	via	ADP
eurjchem-411	286	22	dehydrative	dehydrative	ADJ
eurjchem-411	286	23	cyclization	cyclization	NOUN
eurjchem-411	286	24	,	,	PUNCT
eurjchem-411	286	25	in	in	ADP
eurjchem-411	286	26	accordance	accordance	NOUN
eurjchem-411	286	27	with	with	ADP
eurjchem-411	286	28	the	the	DET
eurjchem-411	286	29	findings	finding	NOUN
eurjchem-411	286	30	of	of	ADP
eurjchem-411	286	31	related	related	ADJ
eurjchem-411	286	32	reports	report	NOUN
eurjchem-411	286	33	[	[	X
eurjchem-411	286	34	50‐53	50‐53	X
eurjchem-411	286	35	]	]	X
eurjchem-411	286	36	.	.	PUNCT
eurjchem-411	287	1	nevertheless	nevertheless	ADV
eurjchem-411	287	2	,	,	PUNCT
eurjchem-411	287	3	the	the	DET
eurjchem-411	287	4	outcome	outcome	NOUN
eurjchem-411	287	5	of	of	ADP
eurjchem-411	287	6	reactions	reaction	NOUN
eurjchem-411	287	7	of	of	ADP
eurjchem-411	287	8	compound	compound	NOUN
eurjchem-411	287	9	4	4	NUM
eurjchem-411	287	10	with	with	ADP
eurjchem-411	287	11	various	various	ADJ
eurjchem-411	287	12	electrophilic	electrophilic	ADJ
eurjchem-411	287	13	reagents	reagent	NOUN
eurjchem-411	287	14	,	,	PUNCT
eurjchem-411	287	15	as	as	SCONJ
eurjchem-411	287	16	shown	show	VERB
eurjchem-411	287	17	in	in	ADP
eurjchem-411	287	18	scheme	scheme	NOUN
eurjchem-411	287	19	2	2	NUM
eurjchem-411	287	20	,	,	PUNCT
eurjchem-411	287	21	can	can	AUX
eurjchem-411	287	22	be	be	AUX
eurjchem-411	287	23	regarded	regard	VERB
eurjchem-411	287	24	as	as	ADP
eurjchem-411	287	25	a	a	DET
eurjchem-411	287	26	rigorous	rigorous	ADJ
eurjchem-411	287	27	proof	proof	NOUN
eurjchem-411	287	28	for	for	ADP
eurjchem-411	287	29	constitution	constitution	NOUN
eurjchem-411	287	30	of	of	ADP
eurjchem-411	287	31	thienopyrimidin‐4‐one	thienopyrimidin‐4‐one	PROPN
eurjchem-411	287	32	4	4	NUM
eurjchem-411	287	33	,	,	PUNCT
eurjchem-411	287	34	locating	locate	VERB
eurjchem-411	287	35	the	the	DET
eurjchem-411	287	36	amino	amino	NOUN
eurjchem-411	287	37	and	and	CCONJ
eurjchem-411	287	38	thioxo	thioxo	ADJ
eurjchem-411	287	39	groups	group	NOUN
eurjchem-411	287	40	in	in	ADP
eurjchem-411	287	41	positions	position	NOUN
eurjchem-411	287	42	3	3	NUM
eurjchem-411	287	43	and	and	CCONJ
eurjchem-411	287	44	2	2	NUM
eurjchem-411	287	45	,	,	PUNCT
eurjchem-411	287	46	respectively	respectively	ADV
eurjchem-411	287	47	.	.	PUNCT
eurjchem-411	288	1	on	on	ADP
eurjchem-411	288	2	the	the	DET
eurjchem-411	288	3	other	other	ADJ
eurjchem-411	288	4	hand	hand	NOUN
eurjchem-411	288	5	,	,	PUNCT
eurjchem-411	288	6	1,3,4‐oxadiazole‐2‐thione	1,3,4‐oxadiazole‐2‐thione	NUM
eurjchem-411	288	7	5	5	NUM
eurjchem-411	288	8	was	be	AUX
eurjchem-411	288	9	also	also	ADV
eurjchem-411	288	10	submitted	submit	VERB
eurjchem-411	288	11	to	to	ADP
eurjchem-411	288	12	a	a	DET
eurjchem-411	288	13	series	series	NOUN
eurjchem-411	288	14	of	of	ADP
eurjchem-411	288	15	transformations	transformation	NOUN
eurjchem-411	288	16	that	that	PRON
eurjchem-411	288	17	served	serve	VERB
eurjchem-411	288	18	as	as	ADP
eurjchem-411	288	19	an	an	DET
eurjchem-411	288	20	additional	additional	ADJ
eurjchem-411	288	21	means	mean	NOUN
eurjchem-411	288	22	of	of	ADP
eurjchem-411	288	23	confirmation	confirmation	NOUN
eurjchem-411	288	24	of	of	ADP
eurjchem-411	288	25	compound	compound	NOUN
eurjchem-411	288	26	identity	identity	NOUN
eurjchem-411	288	27	(	(	PUNCT
eurjchem-411	288	28	scheme	scheme	NOUN
eurjchem-411	288	29	3	3	NUM
eurjchem-411	288	30	)	)	PUNCT
eurjchem-411	288	31	.	.	PUNCT
eurjchem-411	289	1	thus	thus	ADV
eurjchem-411	289	2	,	,	PUNCT
eurjchem-411	289	3	treating	treat	VERB
eurjchem-411	289	4	compound	compound	NOUN
eurjchem-411	289	5	5	5	NUM
eurjchem-411	289	6	with	with	ADP
eurjchem-411	289	7	hydrazine	hydrazine	NOUN
eurjchem-411	289	8	hydrate	hydrate	NOUN
eurjchem-411	289	9	produced	produce	VERB
eurjchem-411	289	10	only	only	ADV
eurjchem-411	289	11	one	one	NUM
eurjchem-411	289	12	isolable	isolable	ADJ
eurjchem-411	289	13	product	product	NOUN
eurjchem-411	289	14	(	(	PUNCT
eurjchem-411	289	15	by	by	ADP
eurjchem-411	289	16	tlc	tlc	NOUN
eurjchem-411	289	17	analysis	analysis	NOUN
eurjchem-411	289	18	)	)	PUNCT
eurjchem-411	289	19	that	that	PRON
eurjchem-411	289	20	was	be	AUX
eurjchem-411	289	21	identified	identify	VERB
eurjchem-411	289	22	as	as	ADP
eurjchem-411	289	23	4‐aminotriazolethione	4‐aminotriazolethione	NUM
eurjchem-411	289	24	derivative	derivative	ADJ
eurjchem-411	289	25	13	13	NUM
eurjchem-411	289	26	,	,	PUNCT
eurjchem-411	289	27	according	accord	VERB
eurjchem-411	289	28	to	to	ADP
eurjchem-411	289	29	its	its	PRON
eurjchem-411	289	30	elemental	elemental	ADJ
eurjchem-411	289	31	analysis	analysis	NOUN
eurjchem-411	289	32	and	and	CCONJ
eurjchem-411	289	33	spectral	spectral	ADJ
eurjchem-411	289	34	data	datum	NOUN
eurjchem-411	289	35	besides	besides	SCONJ
eurjchem-411	289	36	chemical	chemical	NOUN
eurjchem-411	289	37	proof	proof	NOUN
eurjchem-411	289	38	,	,	PUNCT
eurjchem-411	289	39	and	and	CCONJ
eurjchem-411	289	40	not	not	PART
eurjchem-411	289	41	the	the	DET
eurjchem-411	289	42	other	other	ADJ
eurjchem-411	289	43	possible	possible	ADJ
eurjchem-411	289	44	5‐hydrazino‐1,3,4‐oxadiazole	5‐hydrazino‐1,3,4‐oxadiazole	NUM
eurjchem-411	289	45	product	product	NOUN
eurjchem-411	289	46	14c	14c	NOUN
eurjchem-411	289	47	.	.	PUNCT
eurjchem-411	290	1	mass	mass	ADJ
eurjchem-411	290	2	spectrometry	spectrometry	NOUN
eurjchem-411	290	3	provided	provide	VERB
eurjchem-411	290	4	a	a	DET
eurjchem-411	290	5	powerful	powerful	ADJ
eurjchem-411	290	6	tool	tool	NOUN
eurjchem-411	290	7	for	for	ADP
eurjchem-411	290	8	distinguishing	distinguish	VERB
eurjchem-411	290	9	between	between	ADP
eurjchem-411	290	10	the	the	DET
eurjchem-411	290	11	possible	possible	ADJ
eurjchem-411	290	12	structures	structure	NOUN
eurjchem-411	290	13	13	13	NUM
eurjchem-411	290	14	and	and	CCONJ
eurjchem-411	290	15	14c	14c	NOUN
eurjchem-411	290	16	as	as	SCONJ
eurjchem-411	290	17	it	it	PRON
eurjchem-411	290	18	was	be	AUX
eurjchem-411	290	19	shown	show	VERB
eurjchem-411	290	20	,	,	PUNCT
eurjchem-411	290	21	in	in	ADP
eurjchem-411	290	22	the	the	DET
eurjchem-411	290	23	mass	mass	NOUN
eurjchem-411	290	24	spectrum	spectrum	NOUN
eurjchem-411	290	25	of	of	ADP
eurjchem-411	290	26	the	the	DET
eurjchem-411	290	27	isolated	isolated	ADJ
eurjchem-411	290	28	product	product	NOUN
eurjchem-411	290	29	,	,	PUNCT
eurjchem-411	290	30	a	a	DET
eurjchem-411	290	31	molecular	molecular	ADJ
eurjchem-411	290	32	ion	ion	NOUN
eurjchem-411	290	33	peak	peak	NOUN
eurjchem-411	290	34	at	at	ADP
eurjchem-411	290	35	m	m	PROPN
eurjchem-411	290	36	/	/	SYM
eurjchem-411	290	37	z	z	PROPN
eurjchem-411	290	38	423	423	NUM
eurjchem-411	290	39	.	.	PUNCT
eurjchem-411	291	1	this	this	DET
eurjchem-411	291	2	peak	peak	NOUN
eurjchem-411	291	3	is	be	AUX
eurjchem-411	291	4	compatable	compatable	ADJ
eurjchem-411	291	5	with	with	ADP
eurjchem-411	291	6	the	the	DET
eurjchem-411	291	7	molecular	molecular	ADJ
eurjchem-411	291	8	formula	formula	NOUN
eurjchem-411	291	9	of	of	ADP
eurjchem-411	291	10	13	13	NUM
eurjchem-411	291	11	but	but	CCONJ
eurjchem-411	291	12	not	not	PART
eurjchem-411	291	13	14c	14c	NUM
eurjchem-411	291	14	.	.	PUNCT
eurjchem-411	292	1	in	in	ADP
eurjchem-411	292	2	the	the	DET
eurjchem-411	292	3	1h	1h	NUM
eurjchem-411	292	4	nmr	nmr	NOUN
eurjchem-411	292	5	spectrum	spectrum	NOUN
eurjchem-411	292	6	of	of	ADP
eurjchem-411	292	7	the	the	DET
eurjchem-411	292	8	same	same	ADJ
eurjchem-411	292	9	product	product	NOUN
eurjchem-411	292	10	,	,	PUNCT
eurjchem-411	292	11	the	the	DET
eurjchem-411	292	12	presence	presence	NOUN
eurjchem-411	292	13	of	of	ADP
eurjchem-411	292	14	three	three	NUM
eurjchem-411	292	15	d2o‐	d2o‐	ADJ
eurjchem-411	292	16	exchangeable	exchangeable	ADJ
eurjchem-411	292	17	singlet	singlet	NOUN
eurjchem-411	292	18	signals	signal	NOUN
eurjchem-411	292	19	,	,	PUNCT
eurjchem-411	292	20	one	one	NUM
eurjchem-411	292	21	of	of	ADP
eurjchem-411	292	22	them	they	PRON
eurjchem-411	292	23	detected	detect	VERB
eurjchem-411	292	24	at	at	ADP
eurjchem-411	292	25	the	the	DET
eurjchem-411	292	26	typical	typical	ADJ
eurjchem-411	292	27	lowfield	lowfield	NOUN
eurjchem-411	292	28	shift	shift	NOUN
eurjchem-411	292	29	(	(	PUNCT
eurjchem-411	292	30	δh	δh	ADP
eurjchem-411	292	31	13.24	13.24	NUM
eurjchem-411	292	32	ppm	ppm	NOUN
eurjchem-411	292	33	)	)	PUNCT
eurjchem-411	292	34	characteristic	characteristic	NOUN
eurjchem-411	292	35	for	for	ADP
eurjchem-411	292	36	the	the	DET
eurjchem-411	292	37	highly	highly	ADV
eurjchem-411	292	38	deshielded	deshielde	VERB
eurjchem-411	292	39	thioamidic	thioamidic	ADJ
eurjchem-411	292	40	hydrogen	hydrogen	NOUN
eurjchem-411	292	41	,	,	PUNCT
eurjchem-411	292	42	was	be	AUX
eurjchem-411	292	43	also	also	ADV
eurjchem-411	292	44	confirmatory	confirmatory	ADJ
eurjchem-411	292	45	evidence	evidence	NOUN
eurjchem-411	292	46	in	in	ADP
eurjchem-411	292	47	favor	favor	NOUN
eurjchem-411	292	48	of	of	ADP
eurjchem-411	292	49	structure	structure	NOUN
eurjchem-411	292	50	13	13	NUM
eurjchem-411	292	51	.	.	PUNCT
eurjchem-411	293	1	other	other	ADJ
eurjchem-411	293	2	resonances	resonance	NOUN
eurjchem-411	293	3	were	be	AUX
eurjchem-411	293	4	observed	observe	VERB
eurjchem-411	293	5	as	as	SCONJ
eurjchem-411	293	6	expected	expect	VERB
eurjchem-411	293	7	and	and	CCONJ
eurjchem-411	293	8	are	be	AUX
eurjchem-411	293	9	recorded	record	VERB
eurjchem-411	293	10	in	in	ADP
eurjchem-411	293	11	the	the	DET
eurjchem-411	293	12	experimental	experimental	ADJ
eurjchem-411	293	13	section	section	NOUN
eurjchem-411	293	14	.	.	PUNCT
eurjchem-411	294	1	thus	thus	ADV
eurjchem-411	294	2	,	,	PUNCT
eurjchem-411	294	3	the	the	DET
eurjchem-411	294	4	analytical	analytical	ADJ
eurjchem-411	294	5	and	and	CCONJ
eurjchem-411	294	6	spectroscopic	spectroscopic	ADJ
eurjchem-411	294	7	data	datum	NOUN
eurjchem-411	294	8	led	lead	VERB
eurjchem-411	294	9	us	we	PRON
eurjchem-411	294	10	to	to	PART
eurjchem-411	294	11	presume	presume	VERB
eurjchem-411	294	12	that	that	SCONJ
eurjchem-411	294	13	the	the	DET
eurjchem-411	294	14	obtained	obtain	VERB
eurjchem-411	294	15	product	product	NOUN
eurjchem-411	294	16	from	from	ADP
eurjchem-411	294	17	the	the	DET
eurjchem-411	294	18	heteroannelation	heteroannelation	NOUN
eurjchem-411	294	19	reaction	reaction	NOUN
eurjchem-411	294	20	was	be	AUX
eurjchem-411	294	21	not	not	PART
eurjchem-411	294	22	the	the	DET
eurjchem-411	294	23	5‐hydrazino‐1,3,4‐oxadiazole	5‐hydrazino‐1,3,4‐oxadiazole	NUM
eurjchem-411	294	24	derivative	derivative	ADJ
eurjchem-411	294	25	14c	14c	NOUN
eurjchem-411	294	26	and	and	CCONJ
eurjchem-411	294	27	instead	instead	ADV
eurjchem-411	294	28	the	the	DET
eurjchem-411	294	29	4‐aminotriazole‐5‐thione	4‐aminotriazole‐5‐thione	NUM
eurjchem-411	294	30	derivative	derivative	ADJ
eurjchem-411	294	31	13	13	NUM
eurjchem-411	294	32	was	be	AUX
eurjchem-411	294	33	isolated	isolate	VERB
eurjchem-411	294	34	.	.	PUNCT
eurjchem-411	295	1	the	the	DET
eurjchem-411	295	2	pathway	pathway	NOUN
eurjchem-411	295	3	of	of	ADP
eurjchem-411	295	4	the	the	DET
eurjchem-411	295	5	studied	study	VERB
eurjchem-411	295	6	reaction	reaction	NOUN
eurjchem-411	295	7	may	may	AUX
eurjchem-411	295	8	involve	involve	VERB
eurjchem-411	295	9	initial	initial	ADJ
eurjchem-411	295	10	nucleophilic	nucleophilic	ADJ
eurjchem-411	295	11	attack	attack	NOUN
eurjchem-411	295	12	by	by	ADP
eurjchem-411	295	13	the	the	DET
eurjchem-411	295	14	amino	amino	NOUN
eurjchem-411	295	15	group	group	NOUN
eurjchem-411	295	16	of	of	ADP
eurjchem-411	295	17	hydrazine	hydrazine	NOUN
eurjchem-411	295	18	hydrate	hydrate	NOUN
eurjchem-411	295	19	on	on	ADP
eurjchem-411	295	20	the	the	DET
eurjchem-411	295	21	thione	thione	ADJ
eurjchem-411	295	22	carbon	carbon	NOUN
eurjchem-411	295	23	atom	atom	NOUN
eurjchem-411	295	24	with	with	ADP
eurjchem-411	295	25	subsequent	subsequent	ADJ
eurjchem-411	295	26	cleavage	cleavage	NOUN
eurjchem-411	295	27	of	of	ADP
eurjchem-411	295	28	the	the	DET
eurjchem-411	295	29	c‐o	c‐o	NOUN
eurjchem-411	295	30	bond	bond	NOUN
eurjchem-411	295	31	and	and	CCONJ
eurjchem-411	295	32	as	as	ADP
eurjchem-411	295	33	a	a	DET
eurjchem-411	295	34	result	result	NOUN
eurjchem-411	295	35	the	the	DET
eurjchem-411	295	36	oxadiazole	oxadiazole	NOUN
eurjchem-411	295	37	ring	ring	NOUN
eurjchem-411	295	38	opening	opening	NOUN
eurjchem-411	295	39	results	result	NOUN
eurjchem-411	295	40	in	in	ADP
eurjchem-411	295	41	the	the	DET
eurjchem-411	295	42	intermediate	intermediate	ADJ
eurjchem-411	295	43	formation	formation	NOUN
eurjchem-411	295	44	of	of	ADP
eurjchem-411	295	45	acyclic	acyclic	ADJ
eurjchem-411	295	46	adduct	adduct	NOUN
eurjchem-411	295	47	12	12	NUM
eurjchem-411	295	48	.	.	PUNCT
eurjchem-411	296	1	subsequent	subsequent	ADJ
eurjchem-411	296	2	recyclization	recyclization	NOUN
eurjchem-411	296	3	could	could	AUX
eurjchem-411	296	4	then	then	ADV
eurjchem-411	296	5	take	take	VERB
eurjchem-411	296	6	place	place	NOUN
eurjchem-411	296	7	via	via	ADP
eurjchem-411	296	8	nucleophilic	nucleophilic	ADJ
eurjchem-411	296	9	attack	attack	NOUN
eurjchem-411	296	10	by	by	ADP
eurjchem-411	296	11	the	the	DET
eurjchem-411	296	12	carbothiohydrazide	carbothiohydrazide	PROPN
eurjchem-411	296	13	nh	nh	PROPN
eurjchem-411	296	14	moiety	moiety	PROPN
eurjchem-411	296	15	on	on	ADP
eurjchem-411	296	16	the	the	DET
eurjchem-411	296	17	amidic	amidic	ADJ
eurjchem-411	296	18	carbonyl	carbonyl	NOUN
eurjchem-411	296	19	group	group	NOUN
eurjchem-411	296	20	.	.	PUNCT
eurjchem-411	297	1	this	this	PRON
eurjchem-411	297	2	would	would	AUX
eurjchem-411	297	3	be	be	AUX
eurjchem-411	297	4	accompanied	accompany	VERB
eurjchem-411	297	5	by	by	ADP
eurjchem-411	297	6	cyclodehydration	cyclodehydration	NOUN
eurjchem-411	297	7	,	,	PUNCT
eurjchem-411	297	8	leading	lead	VERB
eurjchem-411	297	9	eventually	eventually	ADV
eurjchem-411	297	10	to	to	ADP
eurjchem-411	297	11	the	the	DET
eurjchem-411	297	12	aminotriazoline	aminotriazoline	NOUN
eurjchem-411	297	13	derivative	derivative	ADJ
eurjchem-411	297	14	13	13	NUM
eurjchem-411	297	15	.	.	PUNCT
eurjchem-411	298	1	this	this	DET
eurjchem-411	298	2	hypothesis	hypothesis	NOUN
eurjchem-411	298	3	is	be	AUX
eurjchem-411	298	4	consistent	consistent	ADJ
eurjchem-411	298	5	with	with	ADP
eurjchem-411	298	6	our	our	PRON
eurjchem-411	298	7	earlier	early	ADJ
eurjchem-411	298	8	report	report	NOUN
eurjchem-411	298	9	[	[	X
eurjchem-411	298	10	54	54	NUM
eurjchem-411	298	11	]	]	PUNCT
eurjchem-411	298	12	and	and	CCONJ
eurjchem-411	298	13	with	with	ADP
eurjchem-411	298	14	other	other	ADJ
eurjchem-411	298	15	similar	similar	ADJ
eurjchem-411	298	16	observations	observation	NOUN
eurjchem-411	298	17	[	[	X
eurjchem-411	298	18	55‐57	55‐57	X
eurjchem-411	298	19	]	]	PUNCT
eurjchem-411	298	20	.	.	PUNCT
eurjchem-411	299	1	in	in	ADP
eurjchem-411	299	2	support	support	NOUN
eurjchem-411	299	3	of	of	ADP
eurjchem-411	299	4	this	this	DET
eurjchem-411	299	5	hypothesis	hypothesis	NOUN
eurjchem-411	299	6	,	,	PUNCT
eurjchem-411	299	7	the	the	DET
eurjchem-411	299	8	discrimination	discrimination	NOUN
eurjchem-411	299	9	between	between	ADP
eurjchem-411	299	10	structures	structure	NOUN
eurjchem-411	299	11	13	13	NUM
eurjchem-411	299	12	and	and	CCONJ
eurjchem-411	299	13	14c	14c	NOUN
eurjchem-411	299	14	was	be	AUX
eurjchem-411	299	15	further	far	ADV
eurjchem-411	299	16	proved	prove	VERB
eurjchem-411	299	17	chemically	chemically	ADV
eurjchem-411	299	18	via	via	ADP
eurjchem-411	299	19	the	the	DET
eurjchem-411	299	20	synthesis	synthesis	NOUN
eurjchem-411	299	21	of	of	ADP
eurjchem-411	299	22	compound	compound	NOUN
eurjchem-411	299	23	14c	14c	NUM
eurjchem-411	299	24	by	by	ADP
eurjchem-411	299	25	an	an	DET
eurjchem-411	299	26	unambiguous	unambiguous	ADJ
eurjchem-411	299	27	method	method	NOUN
eurjchem-411	299	28	involving	involve	VERB
eurjchem-411	299	29	initial	initial	ADJ
eurjchem-411	299	30	alkylation	alkylation	NOUN
eurjchem-411	299	31	of	of	ADP
eurjchem-411	299	32	5	5	NUM
eurjchem-411	299	33	with	with	ADP
eurjchem-411	299	34	methyl	methyl	NOUN
eurjchem-411	299	35	iodide	iodide	NOUN
eurjchem-411	299	36	and	and	CCONJ
eurjchem-411	299	37	subsequent	subsequent	ADJ
eurjchem-411	299	38	treatment	treatment	NOUN
eurjchem-411	299	39	of	of	ADP
eurjchem-411	299	40	the	the	DET
eurjchem-411	299	41	formed	form	VERB
eurjchem-411	299	42	methylthio	methylthio	NOUN
eurjchem-411	299	43	derivative	derivative	ADJ
eurjchem-411	299	44	14a	14a	NOUN
eurjchem-411	299	45	with	with	ADP
eurjchem-411	299	46	hydrazine	hydrazine	NOUN
eurjchem-411	299	47	hydrate	hydrate	NOUN
eurjchem-411	299	48	,	,	PUNCT
eurjchem-411	299	49	yielding	yield	VERB
eurjchem-411	299	50	the	the	DET
eurjchem-411	299	51	respective	respective	ADJ
eurjchem-411	299	52	hydrazino	hydrazino	NOUN
eurjchem-411	299	53	derivative	derivative	PROPN
eurjchem-411	299	54	14c	14c	NOUN
eurjchem-411	299	55	.	.	PUNCT
eurjchem-411	300	1	compound	compound	NOUN
eurjchem-411	300	2	14c	14c	NOUN
eurjchem-411	300	3	prepared	prepare	VERB
eurjchem-411	300	4	by	by	ADP
eurjchem-411	300	5	this	this	DET
eurjchem-411	300	6	sequence	sequence	NOUN
eurjchem-411	300	7	of	of	ADP
eurjchem-411	300	8	reactions	reaction	NOUN
eurjchem-411	300	9	proved	prove	VERB
eurjchem-411	300	10	to	to	PART
eurjchem-411	300	11	be	be	AUX
eurjchem-411	300	12	different	different	ADJ
eurjchem-411	300	13	from	from	ADP
eurjchem-411	300	14	the	the	DET
eurjchem-411	300	15	previously	previously	ADV
eurjchem-411	300	16	isolated	isolate	VERB
eurjchem-411	300	17	sample	sample	NOUN
eurjchem-411	300	18	13	13	NUM
eurjchem-411	300	19	as	as	SCONJ
eurjchem-411	300	20	indicated	indicate	VERB
eurjchem-411	300	21	by	by	ADP
eurjchem-411	300	22	tlc	tlc	NOUN
eurjchem-411	300	23	analysis	analysis	NOUN
eurjchem-411	300	24	,	,	PUNCT
eurjchem-411	300	25	m.p	m.p	PROPN
eurjchem-411	300	26	.	.	PROPN
eurjchem-411	300	27	,	,	PUNCT
eurjchem-411	300	28	mixed	mixed	ADJ
eurjchem-411	300	29	m.p	m.p	PROPN
eurjchem-411	300	30	.	.	PROPN
eurjchem-411	301	1	and	and	CCONJ
eurjchem-411	301	2	ir	ir	PROPN
eurjchem-411	301	3	data	datum	NOUN
eurjchem-411	301	4	of	of	ADP
eurjchem-411	301	5	the	the	DET
eurjchem-411	301	6	reaction	reaction	NOUN
eurjchem-411	301	7	product	product	NOUN
eurjchem-411	301	8	in	in	ADP
eurjchem-411	301	9	each	each	DET
eurjchem-411	301	10	case	case	NOUN
eurjchem-411	301	11	.	.	PUNCT
eurjchem-411	302	1	in	in	ADP
eurjchem-411	302	2	the	the	DET
eurjchem-411	302	3	1h	1h	NUM
eurjchem-411	302	4	nmr	nmr	NOUN
eurjchem-411	302	5	spectrum	spectrum	NOUN
eurjchem-411	302	6	of	of	ADP
eurjchem-411	302	7	hydrazino	hydrazino	PROPN
eurjchem-411	302	8	compound	compound	PROPN
eurjchem-411	302	9	14c	14c	PROPN
eurjchem-411	302	10	,	,	PUNCT
eurjchem-411	302	11	the	the	DET
eurjchem-411	302	12	resonance	resonance	NOUN
eurjchem-411	302	13	of	of	ADP
eurjchem-411	302	14	the	the	DET
eurjchem-411	302	15	nh	nh	PROPN
eurjchem-411	302	16	proton	proton	NOUN
eurjchem-411	302	17	was	be	AUX
eurjchem-411	302	18	shifted	shift	VERB
eurjchem-411	302	19	upfield	upfield	ADV
eurjchem-411	302	20	to	to	ADP
eurjchem-411	302	21	10.35	10.35	NUM
eurjchem-411	302	22	ppm	ppm	NOUN
eurjchem-411	302	23	,	,	PUNCT
eurjchem-411	302	24	indicating	indicate	VERB
eurjchem-411	302	25	the	the	DET
eurjchem-411	302	26	disappearance	disappearance	NOUN
eurjchem-411	302	27	of	of	ADP
eurjchem-411	302	28	the	the	DET
eurjchem-411	302	29	deshielding	deshielding	NOUN
eurjchem-411	302	30	thione	thione	NOUN
eurjchem-411	302	31	group	group	NOUN
eurjchem-411	302	32	.	.	PUNCT
eurjchem-411	303	1	the	the	DET
eurjchem-411	303	2	remaining	remain	VERB
eurjchem-411	303	3	resonances	resonance	NOUN
eurjchem-411	303	4	were	be	AUX
eurjchem-411	303	5	also	also	ADV
eurjchem-411	303	6	observed	observe	VERB
eurjchem-411	303	7	at	at	ADP
eurjchem-411	303	8	the	the	DET
eurjchem-411	303	9	expected	expect	VERB
eurjchem-411	303	10	frequencies	frequency	NOUN
eurjchem-411	303	11	(	(	PUNCT
eurjchem-411	303	12	see	see	VERB
eurjchem-411	303	13	experimental	experimental	ADJ
eurjchem-411	303	14	section	section	NOUN
eurjchem-411	303	15	)	)	PUNCT
eurjchem-411	303	16	.	.	PUNCT
eurjchem-411	304	1	the	the	DET
eurjchem-411	304	2	constitution	constitution	NOUN
eurjchem-411	304	3	of	of	ADP
eurjchem-411	304	4	n‐amino	n‐amino	PUNCT
eurjchem-411	304	5	compound	compound	NOUN
eurjchem-411	304	6	13	13	NUM
eurjchem-411	304	7	was	be	AUX
eurjchem-411	304	8	well	well	ADV
eurjchem-411	304	9	supported	support	VERB
eurjchem-411	304	10	as	as	SCONJ
eurjchem-411	304	11	it	it	PRON
eurjchem-411	304	12	afforded	afford	VERB
eurjchem-411	304	13	the	the	DET
eurjchem-411	304	14	corresponding	corresponding	ADJ
eurjchem-411	304	15	triazolothiadiazine	triazolothiadiazine	NOUN
eurjchem-411	304	16	derivative	derivative	ADJ
eurjchem-411	304	17	15	15	NUM
eurjchem-411	304	18	on	on	ADP
eurjchem-411	304	19	alkylation	alkylation	NOUN
eurjchem-411	304	20	with	with	ADP
eurjchem-411	304	21	phenacyl	phenacyl	NOUN
eurjchem-411	304	22	bromide	bromide	NOUN
eurjchem-411	304	23	(	(	PUNCT
eurjchem-411	304	24	scheme	scheme	NOUN
eurjchem-411	304	25	3	3	NUM
eurjchem-411	304	26	)	)	PUNCT
eurjchem-411	304	27	.	.	PUNCT
eurjchem-411	305	1	by	by	ADP
eurjchem-411	305	2	using	use	VERB
eurjchem-411	305	3	the	the	DET
eurjchem-411	305	4	synthetic	synthetic	ADJ
eurjchem-411	305	5	sequence	sequence	NOUN
eurjchem-411	305	6	as	as	SCONJ
eurjchem-411	305	7	was	be	AUX
eurjchem-411	305	8	suggested	suggest	VERB
eurjchem-411	305	9	for	for	ADP
eurjchem-411	305	10	the	the	DET
eurjchem-411	305	11	synthesis	synthesis	NOUN
eurjchem-411	305	12	of	of	ADP
eurjchem-411	305	13	hydrazino	hydrazino	PROPN
eurjchem-411	305	14	derivative	derivative	PROPN
eurjchem-411	305	15	14c	14c	NOUN
eurjchem-411	305	16	,	,	PUNCT
eurjchem-411	305	17	interestingly	interestingly	ADV
eurjchem-411	305	18	,	,	PUNCT
eurjchem-411	305	19	product	product	NOUN
eurjchem-411	305	20	15	15	NUM
eurjchem-411	305	21	was	be	AUX
eurjchem-411	305	22	again	again	ADV
eurjchem-411	305	23	formed	form	VERB
eurjchem-411	305	24	via	via	ADP
eurjchem-411	305	25	initial	initial	ADJ
eurjchem-411	305	26	alkylation	alkylation	NOUN
eurjchem-411	305	27	of	of	ADP
eurjchem-411	305	28	compound	compound	NOUN
eurjchem-411	305	29	5	5	NUM
eurjchem-411	305	30	with	with	ADP
eurjchem-411	305	31	phenacyl	phenacyl	NOUN
eurjchem-411	305	32	bromide	bromide	NOUN
eurjchem-411	305	33	in	in	ADP
eurjchem-411	305	34	alkaline	alkaline	NOUN
eurjchem-411	305	35	medium	medium	NOUN
eurjchem-411	305	36	to	to	PART
eurjchem-411	305	37	provide	provide	VERB
eurjchem-411	305	38	the	the	DET
eurjchem-411	305	39	corresponding	corresponding	ADJ
eurjchem-411	305	40	phenacylthio	phenacylthio	NOUN
eurjchem-411	305	41	derivative	derivative	NOUN
eurjchem-411	305	42	14b	14b	NUM
eurjchem-411	305	43	.	.	PUNCT
eurjchem-411	306	1	following	follow	VERB
eurjchem-411	306	2	this	this	DET
eurjchem-411	306	3	step	step	NOUN
eurjchem-411	306	4	,	,	PUNCT
eurjchem-411	306	5	the	the	DET
eurjchem-411	306	6	alkylated	alkylate	VERB
eurjchem-411	306	7	product	product	NOUN
eurjchem-411	306	8	14b	14b	NUM
eurjchem-411	306	9	was	be	AUX
eurjchem-411	306	10	treated	treat	VERB
eurjchem-411	306	11	with	with	ADP
eurjchem-411	306	12	hydrazine	hydrazine	NOUN
eurjchem-411	306	13	hydrate	hydrate	NOUN
eurjchem-411	306	14	.	.	PUNCT
eurjchem-411	307	1	the	the	DET
eurjchem-411	307	2	final	final	ADJ
eurjchem-411	307	3	product	product	NOUN
eurjchem-411	307	4	of	of	ADP
eurjchem-411	307	5	this	this	DET
eurjchem-411	307	6	synthetic	synthetic	ADJ
eurjchem-411	307	7	sequence	sequence	NOUN
eurjchem-411	307	8	was	be	AUX
eurjchem-411	307	9	identified	identify	VERB
eurjchem-411	307	10	as	as	ADP
eurjchem-411	307	11	triazolothiadiazine	triazolothiadiazine	NOUN
eurjchem-411	307	12	derivative	derivative	ADJ
eurjchem-411	307	13	15	15	NUM
eurjchem-411	307	14	according	accord	VERB
eurjchem-411	307	15	to	to	ADP
eurjchem-411	307	16	tlc	tlc	NOUN
eurjchem-411	307	17	analysis	analysis	NOUN
eurjchem-411	307	18	,	,	PUNCT
eurjchem-411	307	19	m.p	m.p	PROPN
eurjchem-411	307	20	.	.	PROPN
eurjchem-411	307	21	,	,	PUNCT
eurjchem-411	307	22	mixed	mixed	ADJ
eurjchem-411	307	23	m.p	m.p	PROPN
eurjchem-411	307	24	.	.	PROPN
eurjchem-411	307	25	and	and	CCONJ
eurjchem-411	307	26	ir	ir	PROPN
eurjchem-411	307	27	data	datum	NOUN
eurjchem-411	307	28	of	of	ADP
eurjchem-411	307	29	the	the	DET
eurjchem-411	307	30	isolated	isolated	ADJ
eurjchem-411	307	31	material	material	NOUN
eurjchem-411	307	32	.	.	PUNCT
eurjchem-411	308	1	the	the	DET
eurjchem-411	308	2	formation	formation	NOUN
eurjchem-411	308	3	of	of	ADP
eurjchem-411	308	4	compound	compound	NOUN
eurjchem-411	308	5	15	15	NUM
eurjchem-411	308	6	in	in	ADP
eurjchem-411	308	7	this	this	DET
eurjchem-411	308	8	case	case	NOUN
eurjchem-411	308	9	could	could	AUX
eurjchem-411	308	10	proceed	proceed	VERB
eurjchem-411	308	11	via	via	ADP
eurjchem-411	308	12	initial	initial	ADJ
eurjchem-411	308	13	oxadiazole	oxadiazole	NOUN
eurjchem-411	308	14	ring	ring	NOUN
eurjchem-411	308	15	opening	opening	NOUN
eurjchem-411	308	16	with	with	ADP
eurjchem-411	308	17	subsequent	subsequent	ADJ
eurjchem-411	308	18	gaber	gaber	PROPN
eurjchem-411	308	19	and	and	CCONJ
eurjchem-411	308	20	bagley	bagley	PROPN
eurjchem-411	308	21	/	/	SYM
eurjchem-411	308	22	european	european	PROPN
eurjchem-411	308	23	journal	journal	PROPN
eurjchem-411	308	24	of	of	ADP
eurjchem-411	308	25	chemistry	chemistry	NOUN
eurjchem-411	308	26	2	2	NUM
eurjchem-411	308	27	(	(	PUNCT
eurjchem-411	308	28	2	2	NUM
eurjchem-411	308	29	)	)	PUNCT
eurjchem-411	308	30	(	(	PUNCT
eurjchem-411	308	31	2011	2011	NUM
eurjchem-411	308	32	)	)	PUNCT
eurjchem-411	308	33	214‐222	214‐222	PROPN
eurjchem-411	308	34	221	221	NUM
eurjchem-411	308	35	heterocondensation	heterocondensation	NOUN
eurjchem-411	308	36	and	and	CCONJ
eurjchem-411	308	37	spontaneous	spontaneous	ADJ
eurjchem-411	308	38	cyclodehydration	cyclodehydration	NOUN
eurjchem-411	308	39	.	.	PUNCT
eurjchem-411	309	1	this	this	DET
eurjchem-411	309	2	fact	fact	NOUN
eurjchem-411	309	3	gives	give	VERB
eurjchem-411	309	4	added	add	VERB
eurjchem-411	309	5	proof	proof	NOUN
eurjchem-411	309	6	for	for	ADP
eurjchem-411	309	7	the	the	DET
eurjchem-411	309	8	structure	structure	NOUN
eurjchem-411	309	9	of	of	ADP
eurjchem-411	309	10	the	the	DET
eurjchem-411	309	11	previously	previously	ADV
eurjchem-411	309	12	obtained	obtain	VERB
eurjchem-411	309	13	sample	sample	NOUN
eurjchem-411	309	14	15	15	NUM
eurjchem-411	309	15	by	by	ADP
eurjchem-411	309	16	the	the	DET
eurjchem-411	309	17	former	former	ADJ
eurjchem-411	309	18	route	route	NOUN
eurjchem-411	309	19	.	.	PUNCT
eurjchem-411	310	1	in	in	ADP
eurjchem-411	310	2	contrast	contrast	NOUN
eurjchem-411	310	3	to	to	ADP
eurjchem-411	310	4	the	the	DET
eurjchem-411	310	5	reactivity	reactivity	NOUN
eurjchem-411	310	6	of	of	ADP
eurjchem-411	310	7	thienopyrimidin‐4‐one	thienopyrimidin‐4‐one	NOUN
eurjchem-411	310	8	4	4	NUM
eurjchem-411	310	9	towards	towards	ADP
eurjchem-411	310	10	phenyl	phenyl	NOUN
eurjchem-411	310	11	isothiocyanate	isothiocyanate	NOUN
eurjchem-411	310	12	,	,	PUNCT
eurjchem-411	310	13	oxadiazole‐2‐thione	oxadiazole‐2‐thione	PROPN
eurjchem-411	310	14	5	5	NUM
eurjchem-411	310	15	failed	fail	VERB
eurjchem-411	310	16	to	to	PART
eurjchem-411	310	17	react	react	VERB
eurjchem-411	310	18	with	with	ADP
eurjchem-411	310	19	phenyl	phenyl	NOUN
eurjchem-411	310	20	isothiocyanate	isothiocyanate	NOUN
eurjchem-411	310	21	,	,	PUNCT
eurjchem-411	310	22	using	use	VERB
eurjchem-411	310	23	different	different	ADJ
eurjchem-411	310	24	solvents	solvent	NOUN
eurjchem-411	310	25	and	and	CCONJ
eurjchem-411	310	26	catalysts	catalyst	NOUN
eurjchem-411	310	27	,	,	PUNCT
eurjchem-411	310	28	in	in	ADP
eurjchem-411	310	29	an	an	DET
eurjchem-411	310	30	attempt	attempt	NOUN
eurjchem-411	310	31	to	to	PART
eurjchem-411	310	32	prepare	prepare	VERB
eurjchem-411	310	33	n‐phenylthiourea	n‐phenylthiourea	PUNCT
eurjchem-411	310	34	derivative	derivative	ADJ
eurjchem-411	310	35	16	16	NUM
eurjchem-411	310	36	.	.	PUNCT
eurjchem-411	311	1	this	this	DET
eurjchem-411	311	2	result	result	NOUN
eurjchem-411	311	3	may	may	AUX
eurjchem-411	311	4	be	be	AUX
eurjchem-411	311	5	because	because	SCONJ
eurjchem-411	311	6	of	of	ADP
eurjchem-411	311	7	steric	steric	ADJ
eurjchem-411	311	8	hindrance	hindrance	NOUN
eurjchem-411	311	9	created	create	VERB
eurjchem-411	311	10	by	by	ADP
eurjchem-411	311	11	the	the	DET
eurjchem-411	311	12	ortho	ortho	PROPN
eurjchem-411	311	13	orientated	orientate	VERB
eurjchem-411	311	14	oxadiazole	oxadiazole	NOUN
eurjchem-411	311	15	ring	ring	NOUN
eurjchem-411	311	16	or	or	CCONJ
eurjchem-411	311	17	the	the	DET
eurjchem-411	311	18	reduced	reduced	ADJ
eurjchem-411	311	19	nucleophilicity	nucleophilicity	NOUN
eurjchem-411	311	20	of	of	ADP
eurjchem-411	311	21	the	the	DET
eurjchem-411	311	22	(	(	PUNCT
eurjchem-411	311	23	oxadiazolyl)thiophenylamine	oxadiazolyl)thiophenylamine	NOUN
eurjchem-411	311	24	.	.	NOUN
eurjchem-411	312	1	on	on	ADP
eurjchem-411	312	2	the	the	DET
eurjchem-411	312	3	other	other	ADJ
eurjchem-411	312	4	hand	hand	NOUN
eurjchem-411	312	5	,	,	PUNCT
eurjchem-411	312	6	the	the	DET
eurjchem-411	312	7	acetylation	acetylation	NOUN
eurjchem-411	312	8	of	of	ADP
eurjchem-411	312	9	methylthio	methylthio	NOUN
eurjchem-411	312	10	derivative	derivative	ADJ
eurjchem-411	312	11	14a	14a	NOUN
eurjchem-411	312	12	with	with	ADP
eurjchem-411	312	13	acetic	acetic	ADJ
eurjchem-411	312	14	anhydride	anhydride	NOUN
eurjchem-411	312	15	readily	readily	ADV
eurjchem-411	312	16	occurred	occur	VERB
eurjchem-411	312	17	to	to	PART
eurjchem-411	312	18	give	give	VERB
eurjchem-411	312	19	the	the	DET
eurjchem-411	312	20	corresponding	correspond	VERB
eurjchem-411	312	21	2‐	2‐	NUM
eurjchem-411	312	22	acetylamino	acetylamino	NOUN
eurjchem-411	312	23	derivative	derivative	ADJ
eurjchem-411	312	24	17	17	NUM
eurjchem-411	312	25	(	(	PUNCT
eurjchem-411	312	26	scheme	scheme	NOUN
eurjchem-411	312	27	3	3	NUM
eurjchem-411	312	28	)	)	PUNCT
eurjchem-411	312	29	.	.	PUNCT
eurjchem-411	313	1	elucidation	elucidation	NOUN
eurjchem-411	313	2	of	of	ADP
eurjchem-411	313	3	structure	structure	NOUN
eurjchem-411	313	4	for	for	ADP
eurjchem-411	313	5	the	the	DET
eurjchem-411	313	6	latter	latter	ADJ
eurjchem-411	313	7	product	product	NOUN
eurjchem-411	313	8	was	be	AUX
eurjchem-411	313	9	established	establish	VERB
eurjchem-411	313	10	on	on	ADP
eurjchem-411	313	11	the	the	DET
eurjchem-411	313	12	basis	basis	NOUN
eurjchem-411	313	13	of	of	ADP
eurjchem-411	313	14	elemental	elemental	ADJ
eurjchem-411	313	15	and	and	CCONJ
eurjchem-411	313	16	spectroscopic	spectroscopic	ADJ
eurjchem-411	313	17	analyses	analysis	NOUN
eurjchem-411	313	18	(	(	PUNCT
eurjchem-411	313	19	see	see	VERB
eurjchem-411	313	20	experimental	experimental	ADJ
eurjchem-411	313	21	section	section	NOUN
eurjchem-411	313	22	)	)	PUNCT
eurjchem-411	313	23	.	.	PUNCT
eurjchem-411	314	1	3.2	3.2	NUM
eurjchem-411	314	2	.	.	PUNCT
eurjchem-411	314	3	antimicrobial	antimicrobial	ADJ
eurjchem-411	314	4	evaluation	evaluation	NOUN
eurjchem-411	314	5	the	the	DET
eurjchem-411	314	6	biological	biological	ADJ
eurjchem-411	314	7	evaluation	evaluation	NOUN
eurjchem-411	314	8	of	of	ADP
eurjchem-411	314	9	antibacterial	antibacterial	ADJ
eurjchem-411	314	10	and	and	CCONJ
eurjchem-411	314	11	antifungal	antifungal	ADJ
eurjchem-411	314	12	effects	effect	NOUN
eurjchem-411	314	13	are	be	AUX
eurjchem-411	314	14	summarized	summarize	VERB
eurjchem-411	314	15	in	in	ADP
eurjchem-411	314	16	table	table	NOUN
eurjchem-411	314	17	1	1	NUM
eurjchem-411	314	18	.	.	PUNCT
eurjchem-411	314	19	as	as	SCONJ
eurjchem-411	314	20	shown	show	VERB
eurjchem-411	314	21	by	by	ADP
eurjchem-411	314	22	these	these	DET
eurjchem-411	314	23	results	result	NOUN
eurjchem-411	314	24	,	,	PUNCT
eurjchem-411	314	25	the	the	DET
eurjchem-411	314	26	new	new	ADJ
eurjchem-411	314	27	thiophene‐based	thiophene‐base	VERB
eurjchem-411	314	28	derivatives	derivative	NOUN
eurjchem-411	314	29	under	under	ADP
eurjchem-411	314	30	investigation	investigation	NOUN
eurjchem-411	314	31	displayed	display	VERB
eurjchem-411	314	32	variable	variable	NOUN
eurjchem-411	314	33	in	in	ADP
eurjchem-411	314	34	vitro	vitro	X
eurjchem-411	314	35	antibacterial	antibacterial	ADJ
eurjchem-411	314	36	and	and	CCONJ
eurjchem-411	314	37	antifungal	antifungal	ADJ
eurjchem-411	314	38	actions	action	NOUN
eurjchem-411	314	39	.	.	PUNCT
eurjchem-411	315	1	in	in	ADP
eurjchem-411	315	2	general	general	ADJ
eurjchem-411	315	3	,	,	PUNCT
eurjchem-411	315	4	the	the	DET
eurjchem-411	315	5	chemical	chemical	NOUN
eurjchem-411	315	6	structure	structure	NOUN
eurjchem-411	315	7	,	,	PUNCT
eurjchem-411	315	8	comprising	comprise	VERB
eurjchem-411	315	9	the	the	DET
eurjchem-411	315	10	nature	nature	NOUN
eurjchem-411	315	11	of	of	ADP
eurjchem-411	315	12	the	the	DET
eurjchem-411	315	13	heterocyclic	heterocyclic	ADJ
eurjchem-411	315	14	system	system	NOUN
eurjchem-411	315	15	as	as	ADV
eurjchem-411	315	16	well	well	ADV
eurjchem-411	315	17	as	as	ADP
eurjchem-411	315	18	the	the	DET
eurjchem-411	315	19	substituted	substitute	VERB
eurjchem-411	315	20	function	function	NOUN
eurjchem-411	315	21	present	present	ADJ
eurjchem-411	315	22	in	in	ADP
eurjchem-411	315	23	the	the	DET
eurjchem-411	315	24	heterocyclic	heterocyclic	ADJ
eurjchem-411	315	25	ring	ring	NOUN
eurjchem-411	315	26	,	,	PUNCT
eurjchem-411	315	27	has	have	VERB
eurjchem-411	315	28	a	a	DET
eurjchem-411	315	29	pronounced	pronounced	ADJ
eurjchem-411	315	30	effect	effect	NOUN
eurjchem-411	315	31	on	on	ADP
eurjchem-411	315	32	antimicrobial	antimicrobial	ADJ
eurjchem-411	315	33	activity	activity	NOUN
eurjchem-411	315	34	.	.	PUNCT
eurjchem-411	316	1	in	in	ADP
eurjchem-411	316	2	particular	particular	ADJ
eurjchem-411	316	3	,	,	PUNCT
eurjchem-411	316	4	it	it	PRON
eurjchem-411	316	5	has	have	AUX
eurjchem-411	316	6	been	be	AUX
eurjchem-411	316	7	found	find	VERB
eurjchem-411	316	8	that	that	SCONJ
eurjchem-411	316	9	antimicrobial	antimicrobial	ADJ
eurjchem-411	316	10	activity	activity	NOUN
eurjchem-411	316	11	was	be	AUX
eurjchem-411	316	12	relatively	relatively	ADV
eurjchem-411	316	13	dependent	dependent	ADJ
eurjchem-411	316	14	on	on	ADP
eurjchem-411	316	15	the	the	DET
eurjchem-411	316	16	substituent	substituent	NOUN
eurjchem-411	316	17	at	at	ADP
eurjchem-411	316	18	the	the	DET
eurjchem-411	316	19	3‐position	3‐position	NUM
eurjchem-411	316	20	of	of	ADP
eurjchem-411	316	21	thiophene	thiophene	NOUN
eurjchem-411	316	22	ring	ring	NOUN
eurjchem-411	316	23	.	.	PUNCT
eurjchem-411	317	1	it	it	PRON
eurjchem-411	317	2	was	be	AUX
eurjchem-411	317	3	observed	observe	VERB
eurjchem-411	317	4	that	that	SCONJ
eurjchem-411	317	5	compounds	compound	NOUN
eurjchem-411	317	6	substituted	substitute	VERB
eurjchem-411	317	7	with	with	ADP
eurjchem-411	317	8	a	a	DET
eurjchem-411	317	9	triazolothiadiazine	triazolothiadiazine	NOUN
eurjchem-411	317	10	moiety	moiety	NOUN
eurjchem-411	317	11	at	at	ADP
eurjchem-411	317	12	the	the	DET
eurjchem-411	317	13	3‐position	3‐position	NUM
eurjchem-411	317	14	of	of	ADP
eurjchem-411	317	15	the	the	DET
eurjchem-411	317	16	heterocyclic	heterocyclic	ADJ
eurjchem-411	317	17	nucleus	nucleus	PROPN
eurjchem-411	317	18	showed	show	VERB
eurjchem-411	317	19	promising	promise	VERB
eurjchem-411	317	20	antibacterial	antibacterial	ADJ
eurjchem-411	317	21	activity	activity	NOUN
eurjchem-411	317	22	especially	especially	ADV
eurjchem-411	317	23	against	against	ADP
eurjchem-411	317	24	the	the	DET
eurjchem-411	317	25	gram‐positive	gram‐positive	ADJ
eurjchem-411	317	26	strain	strain	NOUN
eurjchem-411	317	27	.	.	PUNCT
eurjchem-411	318	1	on	on	ADP
eurjchem-411	318	2	the	the	DET
eurjchem-411	318	3	contrary	contrary	NOUN
eurjchem-411	318	4	,	,	PUNCT
eurjchem-411	318	5	there	there	PRON
eurjchem-411	318	6	was	be	VERB
eurjchem-411	318	7	no	no	DET
eurjchem-411	318	8	essential	essential	ADJ
eurjchem-411	318	9	in	in	ADP
eurjchem-411	318	10	vitro	vitro	X
eurjchem-411	318	11	antifungal	antifungal	ADJ
eurjchem-411	318	12	profile	profile	NOUN
eurjchem-411	318	13	of	of	ADP
eurjchem-411	318	14	the	the	DET
eurjchem-411	318	15	compounds	compound	NOUN
eurjchem-411	318	16	under	under	ADP
eurjchem-411	318	17	investigation	investigation	NOUN
eurjchem-411	318	18	against	against	ADP
eurjchem-411	318	19	test	test	NOUN
eurjchem-411	318	20	fungi	fungus	NOUN
eurjchem-411	318	21	isolates	isolate	NOUN
eurjchem-411	318	22	except	except	SCONJ
eurjchem-411	318	23	for	for	ADP
eurjchem-411	318	24	condensed	condensed	ADJ
eurjchem-411	318	25	thiophene	thiophene	NOUN
eurjchem-411	318	26	derivative	derivative	ADJ
eurjchem-411	318	27	8	8	NUM
eurjchem-411	318	28	,	,	PUNCT
eurjchem-411	318	29	which	which	PRON
eurjchem-411	318	30	was	be	AUX
eurjchem-411	318	31	found	find	VERB
eurjchem-411	318	32	to	to	PART
eurjchem-411	318	33	be	be	AUX
eurjchem-411	318	34	as	as	ADV
eurjchem-411	318	35	effective	effective	ADJ
eurjchem-411	318	36	as	as	ADP
eurjchem-411	318	37	amphotericin	amphotericin	ADP
eurjchem-411	318	38	b	b	NOUN
eurjchem-411	318	39	with	with	ADP
eurjchem-411	318	40	the	the	DET
eurjchem-411	318	41	same	same	ADJ
eurjchem-411	318	42	inhibition	inhibition	NOUN
eurjchem-411	318	43	zone	zone	NOUN
eurjchem-411	318	44	diameter	diameter	NOUN
eurjchem-411	318	45	(	(	PUNCT
eurjchem-411	318	46	izd	izd	ADJ
eurjchem-411	318	47	)	)	PUNCT
eurjchem-411	318	48	value	value	NOUN
eurjchem-411	318	49	against	against	ADP
eurjchem-411	318	50	aspergillus	aspergillus	NOUN
eurjchem-411	318	51	flavus	flavus	NOUN
eurjchem-411	318	52	(	(	PUNCT
eurjchem-411	318	53	table	table	NOUN
eurjchem-411	318	54	1	1	NUM
eurjchem-411	318	55	)	)	PUNCT
eurjchem-411	318	56	.	.	PUNCT
eurjchem-411	319	1	based	base	VERB
eurjchem-411	319	2	on	on	ADP
eurjchem-411	319	3	the	the	DET
eurjchem-411	319	4	antimicrobial	antimicrobial	ADJ
eurjchem-411	319	5	evaluation	evaluation	NOUN
eurjchem-411	319	6	,	,	PUNCT
eurjchem-411	319	7	compounds	compound	VERB
eurjchem-411	319	8	8	8	NUM
eurjchem-411	319	9	and	and	CCONJ
eurjchem-411	319	10	15	15	NUM
eurjchem-411	319	11	were	be	AUX
eurjchem-411	319	12	selected	select	VERB
eurjchem-411	319	13	for	for	ADP
eurjchem-411	319	14	further	further	ADJ
eurjchem-411	319	15	assessment	assessment	NOUN
eurjchem-411	319	16	.	.	PUNCT
eurjchem-411	320	1	the	the	DET
eurjchem-411	320	2	minimum	minimum	ADJ
eurjchem-411	320	3	inhibitory	inhibitory	ADJ
eurjchem-411	320	4	concentration	concentration	NOUN
eurjchem-411	320	5	(	(	PUNCT
eurjchem-411	320	6	mic	mic	NOUN
eurjchem-411	320	7	)	)	PUNCT
eurjchem-411	320	8	of	of	ADP
eurjchem-411	320	9	uncondensed	uncondensed	ADJ
eurjchem-411	320	10	thiophene	thiophene	NOUN
eurjchem-411	320	11	derivative	derivative	ADJ
eurjchem-411	320	12	15	15	NUM
eurjchem-411	320	13	against	against	ADP
eurjchem-411	320	14	s.	s.	PROPN
eurjchem-411	320	15	aureus	aureus	PROPN
eurjchem-411	320	16	was	be	AUX
eurjchem-411	320	17	230	230	NUM
eurjchem-411	320	18	µg	µg	NOUN
eurjchem-411	320	19	/	/	SYM
eurjchem-411	320	20	ml	ml	NOUN
eurjchem-411	320	21	,	,	PUNCT
eurjchem-411	320	22	which	which	PRON
eurjchem-411	320	23	is	be	AUX
eurjchem-411	320	24	higher	high	ADJ
eurjchem-411	320	25	than	than	ADP
eurjchem-411	320	26	that	that	PRON
eurjchem-411	320	27	of	of	ADP
eurjchem-411	320	28	tetracycline	tetracycline	NOUN
eurjchem-411	320	29	as	as	ADP
eurjchem-411	320	30	a	a	DET
eurjchem-411	320	31	reference	reference	NOUN
eurjchem-411	320	32	antibacterial	antibacterial	ADJ
eurjchem-411	320	33	drug	drug	NOUN
eurjchem-411	320	34	as	as	SCONJ
eurjchem-411	320	35	depicted	depict	VERB
eurjchem-411	320	36	in	in	ADP
eurjchem-411	320	37	table	table	NOUN
eurjchem-411	320	38	2	2	NUM
eurjchem-411	320	39	.	.	PUNCT
eurjchem-411	321	1	in	in	ADP
eurjchem-411	321	2	contrast	contrast	NOUN
eurjchem-411	321	3	,	,	PUNCT
eurjchem-411	321	4	the	the	DET
eurjchem-411	321	5	mic	mic	NOUN
eurjchem-411	321	6	of	of	ADP
eurjchem-411	321	7	condensed	condensed	ADJ
eurjchem-411	321	8	thiophene	thiophene	NOUN
eurjchem-411	321	9	derivative	derivative	ADJ
eurjchem-411	321	10	8	8	NUM
eurjchem-411	321	11	against	against	ADP
eurjchem-411	321	12	a.	a.	NOUN
eurjchem-411	321	13	flavus	flavus	NOUN
eurjchem-411	321	14	was	be	AUX
eurjchem-411	321	15	168	168	NUM
eurjchem-411	321	16	µg	µg	NOUN
eurjchem-411	321	17	/	/	SYM
eurjchem-411	321	18	ml	ml	NOUN
eurjchem-411	321	19	,	,	PUNCT
eurjchem-411	321	20	which	which	PRON
eurjchem-411	321	21	is	be	AUX
eurjchem-411	321	22	very	very	ADV
eurjchem-411	321	23	close	close	ADJ
eurjchem-411	321	24	to	to	ADP
eurjchem-411	321	25	that	that	PRON
eurjchem-411	321	26	of	of	ADP
eurjchem-411	321	27	amphotericin	amphotericin	ADP
eurjchem-411	321	28	b	b	X
eurjchem-411	321	29	as	as	ADP
eurjchem-411	321	30	a	a	DET
eurjchem-411	321	31	reference	reference	NOUN
eurjchem-411	321	32	antifungal	antifungal	ADJ
eurjchem-411	321	33	drug	drug	NOUN
eurjchem-411	321	34	(	(	PUNCT
eurjchem-411	321	35	table	table	NOUN
eurjchem-411	321	36	3	3	NUM
eurjchem-411	321	37	)	)	PUNCT
eurjchem-411	321	38	.	.	PUNCT
eurjchem-411	322	1	from	from	ADP
eurjchem-411	322	2	the	the	DET
eurjchem-411	322	3	structure‐	structure‐	NOUN
eurjchem-411	322	4	activity	activity	NOUN
eurjchem-411	322	5	relationship	relationship	NOUN
eurjchem-411	322	6	(	(	PUNCT
eurjchem-411	322	7	sar	sar	PROPN
eurjchem-411	322	8	)	)	PUNCT
eurjchem-411	322	9	,	,	PUNCT
eurjchem-411	322	10	we	we	PRON
eurjchem-411	322	11	can	can	AUX
eurjchem-411	322	12	conclude	conclude	VERB
eurjchem-411	322	13	that	that	SCONJ
eurjchem-411	322	14	the	the	DET
eurjchem-411	322	15	triazolothiadiazine	triazolothiadiazine	NOUN
eurjchem-411	322	16	moiety	moiety	NOUN
eurjchem-411	322	17	is	be	AUX
eurjchem-411	322	18	essential	essential	ADJ
eurjchem-411	322	19	for	for	ADP
eurjchem-411	322	20	antibacterial	antibacterial	ADJ
eurjchem-411	322	21	activity	activity	NOUN
eurjchem-411	322	22	especially	especially	ADV
eurjchem-411	322	23	against	against	ADP
eurjchem-411	322	24	the	the	DET
eurjchem-411	322	25	gram‐positive	gram‐positive	ADJ
eurjchem-411	322	26	strain	strain	NOUN
eurjchem-411	322	27	.	.	PUNCT
eurjchem-411	323	1	in	in	ADP
eurjchem-411	323	2	addition	addition	NOUN
eurjchem-411	323	3	,	,	PUNCT
eurjchem-411	323	4	heteroannelation	heteroannelation	NOUN
eurjchem-411	323	5	of	of	ADP
eurjchem-411	323	6	thienopyrimidinone	thienopyrimidinone	NOUN
eurjchem-411	323	7	to	to	ADP
eurjchem-411	323	8	a	a	DET
eurjchem-411	323	9	triazole‐thione	triazole‐thione	NOUN
eurjchem-411	323	10	moiety	moiety	NOUN
eurjchem-411	323	11	can	can	AUX
eurjchem-411	323	12	improve	improve	VERB
eurjchem-411	323	13	antifungal	antifungal	ADJ
eurjchem-411	323	14	activity	activity	NOUN
eurjchem-411	323	15	as	as	SCONJ
eurjchem-411	323	16	observed	observe	VERB
eurjchem-411	323	17	for	for	ADP
eurjchem-411	323	18	compound	compound	NOUN
eurjchem-411	323	19	8	8	NUM
eurjchem-411	323	20	,	,	PUNCT
eurjchem-411	323	21	which	which	PRON
eurjchem-411	323	22	can	can	AUX
eurjchem-411	323	23	be	be	AUX
eurjchem-411	323	24	considered	consider	VERB
eurjchem-411	323	25	as	as	ADP
eurjchem-411	323	26	a	a	DET
eurjchem-411	323	27	lead	lead	NOUN
eurjchem-411	323	28	compound	compound	NOUN
eurjchem-411	323	29	in	in	ADP
eurjchem-411	323	30	this	this	DET
eurjchem-411	323	31	field	field	NOUN
eurjchem-411	323	32	.	.	PUNCT
eurjchem-411	324	1	further	further	ADJ
eurjchem-411	324	2	studies	study	NOUN
eurjchem-411	324	3	are	be	AUX
eurjchem-411	324	4	in	in	ADP
eurjchem-411	324	5	progress	progress	NOUN
eurjchem-411	324	6	on	on	ADP
eurjchem-411	324	7	both	both	DET
eurjchem-411	324	8	compounds	compound	NOUN
eurjchem-411	324	9	to	to	PART
eurjchem-411	324	10	increase	increase	VERB
eurjchem-411	324	11	their	their	PRON
eurjchem-411	324	12	efficacy	efficacy	NOUN
eurjchem-411	324	13	and	and	CCONJ
eurjchem-411	324	14	understand	understand	VERB
eurjchem-411	324	15	their	their	PRON
eurjchem-411	324	16	qsar	qsar	NOUN
eurjchem-411	324	17	.	.	PUNCT
eurjchem-411	325	1	the	the	DET
eurjchem-411	325	2	overall	overall	ADJ
eurjchem-411	325	3	results	result	NOUN
eurjchem-411	325	4	of	of	ADP
eurjchem-411	325	5	the	the	DET
eurjchem-411	325	6	present	present	ADJ
eurjchem-411	325	7	study	study	NOUN
eurjchem-411	325	8	can	can	AUX
eurjchem-411	325	9	be	be	AUX
eurjchem-411	325	10	considered	consider	VERB
eurjchem-411	325	11	promising	promise	VERB
eurjchem-411	325	12	in	in	ADP
eurjchem-411	325	13	the	the	DET
eurjchem-411	325	14	perspective	perspective	NOUN
eurjchem-411	325	15	of	of	ADP
eurjchem-411	325	16	new	new	ADJ
eurjchem-411	325	17	antifungal	antifungal	ADJ
eurjchem-411	325	18	drug	drug	NOUN
eurjchem-411	325	19	discovery	discovery	NOUN
eurjchem-411	325	20	,	,	PUNCT
eurjchem-411	325	21	considering	consider	VERB
eurjchem-411	325	22	the	the	DET
eurjchem-411	325	23	clinical	clinical	ADJ
eurjchem-411	325	24	importance	importance	NOUN
eurjchem-411	325	25	of	of	ADP
eurjchem-411	325	26	the	the	DET
eurjchem-411	325	27	tested	test	VERB
eurjchem-411	325	28	microorganisms	microorganism	NOUN
eurjchem-411	325	29	.	.	PUNCT
eurjchem-411	326	1	of	of	ADP
eurjchem-411	326	2	particular	particular	ADJ
eurjchem-411	326	3	interest	interest	NOUN
eurjchem-411	326	4	,	,	PUNCT
eurjchem-411	326	5	s.	s.	PROPN
eurjchem-411	326	6	aureus	aureus	PROPN
eurjchem-411	326	7	may	may	AUX
eurjchem-411	326	8	occur	occur	VERB
eurjchem-411	326	9	as	as	ADP
eurjchem-411	326	10	a	a	DET
eurjchem-411	326	11	commensal	commensal	NOUN
eurjchem-411	326	12	on	on	ADP
eurjchem-411	326	13	skin	skin	NOUN
eurjchem-411	326	14	;	;	PUNCT
eurjchem-411	326	15	it	it	PRON
eurjchem-411	326	16	also	also	ADV
eurjchem-411	326	17	occurs	occur	VERB
eurjchem-411	326	18	in	in	ADP
eurjchem-411	326	19	the	the	DET
eurjchem-411	326	20	nose	nose	NOUN
eurjchem-411	326	21	frequently	frequently	ADV
eurjchem-411	326	22	(	(	PUNCT
eurjchem-411	326	23	in	in	ADP
eurjchem-411	326	24	about	about	ADV
eurjchem-411	326	25	a	a	DET
eurjchem-411	326	26	third	third	NOUN
eurjchem-411	326	27	of	of	ADP
eurjchem-411	326	28	the	the	DET
eurjchem-411	326	29	population	population	NOUN
eurjchem-411	326	30	)	)	PUNCT
eurjchem-411	327	1	[	[	X
eurjchem-411	327	2	58	58	NUM
eurjchem-411	327	3	]	]	PUNCT
eurjchem-411	327	4	and	and	CCONJ
eurjchem-411	327	5	throat	throat	VERB
eurjchem-411	327	6	less	less	ADV
eurjchem-411	327	7	commonly	commonly	ADV
eurjchem-411	327	8	.	.	PUNCT
eurjchem-411	328	1	the	the	DET
eurjchem-411	328	2	occurrence	occurrence	NOUN
eurjchem-411	328	3	of	of	ADP
eurjchem-411	328	4	s.	s.	PROPN
eurjchem-411	328	5	aureus	aureus	PROPN
eurjchem-411	328	6	under	under	ADP
eurjchem-411	328	7	these	these	DET
eurjchem-411	328	8	circumstances	circumstance	NOUN
eurjchem-411	328	9	does	do	AUX
eurjchem-411	328	10	not	not	PART
eurjchem-411	328	11	always	always	ADV
eurjchem-411	328	12	indicate	indicate	VERB
eurjchem-411	328	13	infection	infection	NOUN
eurjchem-411	328	14	and	and	CCONJ
eurjchem-411	328	15	therefore	therefore	ADV
eurjchem-411	328	16	does	do	AUX
eurjchem-411	328	17	not	not	PART
eurjchem-411	328	18	always	always	ADV
eurjchem-411	328	19	require	require	VERB
eurjchem-411	328	20	treatment	treatment	NOUN
eurjchem-411	328	21	.	.	PUNCT
eurjchem-411	329	1	in	in	ADP
eurjchem-411	329	2	infants	infant	NOUN
eurjchem-411	329	3	,	,	PUNCT
eurjchem-411	329	4	s.	s.	PROPN
eurjchem-411	329	5	aureus	aureus	PROPN
eurjchem-411	329	6	infection	infection	NOUN
eurjchem-411	329	7	can	can	AUX
eurjchem-411	329	8	cause	cause	VERB
eurjchem-411	329	9	a	a	DET
eurjchem-411	329	10	severe	severe	ADJ
eurjchem-411	329	11	disease	disease	NOUN
eurjchem-411	329	12	staphylococcal	staphylococcal	ADP
eurjchem-411	329	13	scalded	scald	VERB
eurjchem-411	329	14	skin	skin	NOUN
eurjchem-411	329	15	syndrome	syndrome	NOUN
eurjchem-411	329	16	(	(	PUNCT
eurjchem-411	329	17	ssss	ssss	NOUN
eurjchem-411	329	18	)	)	PUNCT
eurjchem-411	330	1	[	[	X
eurjchem-411	330	2	59	59	NUM
eurjchem-411	330	3	]	]	PUNCT
eurjchem-411	330	4	.	.	PUNCT
eurjchem-411	331	1	this	this	DET
eurjchem-411	331	2	pathogen	pathogen	NOUN
eurjchem-411	331	3	was	be	AUX
eurjchem-411	331	4	found	find	VERB
eurjchem-411	331	5	to	to	PART
eurjchem-411	331	6	be	be	AUX
eurjchem-411	331	7	sensitive	sensitive	ADJ
eurjchem-411	331	8	to	to	ADP
eurjchem-411	331	9	most	most	ADJ
eurjchem-411	331	10	of	of	ADP
eurjchem-411	331	11	the	the	DET
eurjchem-411	331	12	test	test	NOUN
eurjchem-411	331	13	compounds	compound	NOUN
eurjchem-411	331	14	especially	especially	ADV
eurjchem-411	331	15	compounds	compound	VERB
eurjchem-411	331	16	10	10	NUM
eurjchem-411	331	17	and	and	CCONJ
eurjchem-411	331	18	15	15	NUM
eurjchem-411	331	19	(	(	PUNCT
eurjchem-411	331	20	table	table	NOUN
eurjchem-411	331	21	1	1	NUM
eurjchem-411	331	22	)	)	PUNCT
eurjchem-411	331	23	.	.	PUNCT
eurjchem-411	332	1	aspergillus	aspergillus	NOUN
eurjchem-411	332	2	causes	cause	VERB
eurjchem-411	332	3	chronic	chronic	ADJ
eurjchem-411	332	4	necrotizing	necrotizing	NOUN
eurjchem-411	332	5	pulmonary	pulmonary	ADJ
eurjchem-411	332	6	aspergillosis	aspergillosis	NOUN
eurjchem-411	332	7	(	(	PUNCT
eurjchem-411	332	8	cnpa	cnpa	NOUN
eurjchem-411	332	9	)	)	PUNCT
eurjchem-411	333	1	[	[	X
eurjchem-411	333	2	60	60	NUM
eurjchem-411	333	3	]	]	PUNCT
eurjchem-411	333	4	,	,	PUNCT
eurjchem-411	333	5	which	which	PRON
eurjchem-411	333	6	is	be	AUX
eurjchem-411	333	7	a	a	DET
eurjchem-411	333	8	subacute	subacute	ADJ
eurjchem-411	333	9	infection	infection	NOUN
eurjchem-411	333	10	seen	see	VERB
eurjchem-411	333	11	in	in	ADP
eurjchem-411	333	12	patients	patient	NOUN
eurjchem-411	333	13	with	with	ADP
eurjchem-411	333	14	an	an	DET
eurjchem-411	333	15	underlying	underlie	VERB
eurjchem-411	333	16	lung	lung	NOUN
eurjchem-411	333	17	disease	disease	NOUN
eurjchem-411	333	18	.	.	PUNCT
eurjchem-411	334	1	about	about	ADV
eurjchem-411	334	2	50	50	NUM
eurjchem-411	334	3	%	%	NOUN
eurjchem-411	334	4	of	of	ADP
eurjchem-411	334	5	reported	report	VERB
eurjchem-411	334	6	cases	case	NOUN
eurjchem-411	334	7	have	have	AUX
eurjchem-411	334	8	shown	show	VERB
eurjchem-411	334	9	no	no	DET
eurjchem-411	334	10	response	response	NOUN
eurjchem-411	334	11	to	to	ADP
eurjchem-411	334	12	amphotericin	amphotericin	VERB
eurjchem-411	334	13	b	b	NOUN
eurjchem-411	334	14	[	[	X
eurjchem-411	334	15	61	61	NUM
eurjchem-411	334	16	]	]	PUNCT
eurjchem-411	334	17	.	.	PUNCT
eurjchem-411	335	1	the	the	DET
eurjchem-411	335	2	most	most	ADV
eurjchem-411	335	3	common	common	ADJ
eurjchem-411	335	4	subtype	subtype	NOUN
eurjchem-411	335	5	among	among	ADP
eurjchem-411	335	6	paranasal	paranasal	ADJ
eurjchem-411	335	7	sinus	sinus	NOUN
eurjchem-411	335	8	infections	infection	NOUN
eurjchem-411	335	9	associated	associate	VERB
eurjchem-411	335	10	with	with	ADP
eurjchem-411	335	11	aspergillosis	aspergillosis	NOUN
eurjchem-411	335	12	is	be	AUX
eurjchem-411	335	13	aspergillus	aspergillus	ADJ
eurjchem-411	335	14	fumigatus	fumigatus	NOUN
eurjchem-411	336	1	[	[	X
eurjchem-411	336	2	62	62	NUM
eurjchem-411	336	3	]	]	PUNCT
eurjchem-411	336	4	.	.	PUNCT
eurjchem-411	337	1	the	the	DET
eurjchem-411	337	2	symptoms	symptom	NOUN
eurjchem-411	337	3	include	include	VERB
eurjchem-411	337	4	fever	fever	NOUN
eurjchem-411	337	5	,	,	PUNCT
eurjchem-411	337	6	cough	cough	NOUN
eurjchem-411	337	7	,	,	PUNCT
eurjchem-411	337	8	chest	chest	NOUN
eurjchem-411	337	9	pain	pain	NOUN
eurjchem-411	337	10	or	or	CCONJ
eurjchem-411	337	11	breathlessness	breathlessness	NOUN
eurjchem-411	337	12	,	,	PUNCT
eurjchem-411	337	13	which	which	PRON
eurjchem-411	337	14	also	also	ADV
eurjchem-411	337	15	occur	occur	VERB
eurjchem-411	337	16	in	in	ADP
eurjchem-411	337	17	many	many	ADJ
eurjchem-411	337	18	other	other	ADJ
eurjchem-411	337	19	illnesses	illness	NOUN
eurjchem-411	337	20	so	so	SCONJ
eurjchem-411	337	21	diagnosis	diagnosis	NOUN
eurjchem-411	337	22	can	can	AUX
eurjchem-411	337	23	be	be	AUX
eurjchem-411	337	24	difficult	difficult	ADJ
eurjchem-411	337	25	.	.	PUNCT
eurjchem-411	338	1	such	such	DET
eurjchem-411	338	2	a	a	DET
eurjchem-411	338	3	pathogen	pathogen	NOUN
eurjchem-411	338	4	was	be	AUX
eurjchem-411	338	5	found	find	VERB
eurjchem-411	338	6	to	to	PART
eurjchem-411	338	7	be	be	AUX
eurjchem-411	338	8	highly	highly	ADV
eurjchem-411	338	9	sensitive	sensitive	ADJ
eurjchem-411	338	10	to	to	PART
eurjchem-411	338	11	compound	compound	VERB
eurjchem-411	338	12	8	8	NUM
eurjchem-411	338	13	(	(	PUNCT
eurjchem-411	338	14	table	table	NOUN
eurjchem-411	338	15	1	1	NUM
eurjchem-411	338	16	)	)	PUNCT
eurjchem-411	338	17	.	.	PUNCT
eurjchem-411	339	1	candida	candida	NOUN
eurjchem-411	339	2	albicans	albican	NOUN
eurjchem-411	339	3	has	have	AUX
eurjchem-411	339	4	been	be	AUX
eurjchem-411	339	5	identified	identify	VERB
eurjchem-411	339	6	as	as	ADP
eurjchem-411	339	7	the	the	DET
eurjchem-411	339	8	major	major	ADJ
eurjchem-411	339	9	opportunistic	opportunistic	ADJ
eurjchem-411	339	10	pathogen	pathogen	NOUN
eurjchem-411	339	11	in	in	ADP
eurjchem-411	339	12	the	the	DET
eurjchem-411	339	13	etiology	etiology	NOUN
eurjchem-411	339	14	of	of	ADP
eurjchem-411	339	15	fungal	fungal	ADJ
eurjchem-411	339	16	infections	infection	NOUN
eurjchem-411	339	17	[	[	X
eurjchem-411	339	18	63	63	NUM
eurjchem-411	339	19	]	]	PUNCT
eurjchem-411	339	20	.	.	PUNCT
eurjchem-411	340	1	candidiasis	candidiasis	NOUN
eurjchem-411	340	2	is	be	AUX
eurjchem-411	340	3	an	an	DET
eurjchem-411	340	4	increasingly	increasingly	ADV
eurjchem-411	340	5	important	important	ADJ
eurjchem-411	340	6	desease	desease	NOUN
eurjchem-411	340	7	,	,	PUNCT
eurjchem-411	340	8	which	which	PRON
eurjchem-411	340	9	is	be	AUX
eurjchem-411	340	10	distributed	distribute	VERB
eurjchem-411	340	11	worldwide	worldwide	ADV
eurjchem-411	340	12	because	because	SCONJ
eurjchem-411	340	13	of	of	ADP
eurjchem-411	340	14	this	this	DET
eurjchem-411	340	15	opportunistic	opportunistic	ADJ
eurjchem-411	340	16	pathogen	pathogen	NOUN
eurjchem-411	340	17	and	and	CCONJ
eurjchem-411	340	18	other	other	ADJ
eurjchem-411	340	19	candida	candida	PROPN
eurjchem-411	340	20	species	specie	NOUN
eurjchem-411	340	21	.	.	PUNCT
eurjchem-411	341	1	candidiasis	candidiasis	NOUN
eurjchem-411	341	2	is	be	AUX
eurjchem-411	341	3	often	often	ADV
eurjchem-411	341	4	observed	observe	VERB
eurjchem-411	341	5	in	in	ADP
eurjchem-411	341	6	immunocompromised	immunocompromise	VERB
eurjchem-411	341	7	individuals	individual	NOUN
eurjchem-411	341	8	such	such	ADJ
eurjchem-411	341	9	as	as	ADP
eurjchem-411	341	10	hiv‐positive	hiv‐positive	ADJ
eurjchem-411	341	11	and	and	CCONJ
eurjchem-411	341	12	aids	aid	NOUN
eurjchem-411	341	13	patients	patient	NOUN
eurjchem-411	341	14	[	[	X
eurjchem-411	341	15	61	61	NUM
eurjchem-411	341	16	]	]	PUNCT
eurjchem-411	341	17	.	.	PUNCT
eurjchem-411	342	1	unfortunately	unfortunately	ADV
eurjchem-411	342	2	,	,	PUNCT
eurjchem-411	342	3	this	this	DET
eurjchem-411	342	4	fungus	fungus	NOUN
eurjchem-411	342	5	was	be	AUX
eurjchem-411	342	6	not	not	PART
eurjchem-411	342	7	found	find	VERB
eurjchem-411	342	8	to	to	PART
eurjchem-411	342	9	be	be	AUX
eurjchem-411	342	10	sensitive	sensitive	ADJ
eurjchem-411	342	11	to	to	ADP
eurjchem-411	342	12	any	any	PRON
eurjchem-411	342	13	of	of	ADP
eurjchem-411	342	14	the	the	DET
eurjchem-411	342	15	synthesized	synthesize	VERB
eurjchem-411	342	16	compounds	compound	NOUN
eurjchem-411	342	17	(	(	PUNCT
eurjchem-411	342	18	table	table	NOUN
eurjchem-411	342	19	1	1	NUM
eurjchem-411	342	20	)	)	PUNCT
eurjchem-411	342	21	.	.	PUNCT
eurjchem-411	343	1	4	4	X
eurjchem-411	343	2	.	.	X
eurjchem-411	343	3	conclusion	conclusion	NOUN
eurjchem-411	343	4	in	in	ADP
eurjchem-411	343	5	conclusion	conclusion	NOUN
eurjchem-411	343	6	,	,	PUNCT
eurjchem-411	343	7	we	we	PRON
eurjchem-411	343	8	have	have	AUX
eurjchem-411	343	9	unambiguously	unambiguously	ADV
eurjchem-411	343	10	proved	prove	VERB
eurjchem-411	343	11	in	in	ADP
eurjchem-411	343	12	the	the	DET
eurjchem-411	343	13	present	present	ADJ
eurjchem-411	343	14	study	study	NOUN
eurjchem-411	343	15	by	by	ADP
eurjchem-411	343	16	spectroscopic	spectroscopic	ADJ
eurjchem-411	343	17	methods	method	NOUN
eurjchem-411	343	18	and	and	CCONJ
eurjchem-411	343	19	chemical	chemical	NOUN
eurjchem-411	343	20	transformations	transformation	NOUN
eurjchem-411	343	21	that	that	SCONJ
eurjchem-411	343	22	reaction	reaction	NOUN
eurjchem-411	343	23	of	of	ADP
eurjchem-411	343	24	carbohydrazide	carbohydrazide	NOUN
eurjchem-411	343	25	3	3	NUM
eurjchem-411	343	26	with	with	ADP
eurjchem-411	343	27	carbon	carbon	NOUN
eurjchem-411	343	28	disulfide	disulfide	NOUN
eurjchem-411	343	29	in	in	ADP
eurjchem-411	343	30	alkaline	alkaline	NOUN
eurjchem-411	343	31	medium	medium	ADJ
eurjchem-411	343	32	yields	yield	NOUN
eurjchem-411	343	33	the	the	DET
eurjchem-411	343	34	1,3,4‐oxadiazole‐2‐	1,3,4‐oxadiazole‐2‐	NUM
eurjchem-411	343	35	thione	thione	NOUN
eurjchem-411	343	36	derivative	derivative	ADJ
eurjchem-411	343	37	5	5	NUM
eurjchem-411	343	38	,	,	PUNCT
eurjchem-411	343	39	while	while	SCONJ
eurjchem-411	343	40	the	the	DET
eurjchem-411	343	41	alternative	alternative	NOUN
eurjchem-411	343	42	thienopyrimidin‐4‐	thienopyrimidin‐4‐	PUNCT
eurjchem-411	343	43	one	one	NUM
eurjchem-411	343	44	structure	structure	NOUN
eurjchem-411	343	45	4	4	NUM
eurjchem-411	343	46	is	be	AUX
eurjchem-411	343	47	the	the	DET
eurjchem-411	343	48	product	product	NOUN
eurjchem-411	343	49	of	of	ADP
eurjchem-411	343	50	the	the	DET
eurjchem-411	343	51	reaction	reaction	NOUN
eurjchem-411	343	52	of	of	ADP
eurjchem-411	343	53	hydrazide	hydrazide	ADJ
eurjchem-411	343	54	3	3	NUM
eurjchem-411	343	55	with	with	ADP
eurjchem-411	343	56	thiourea	thiourea	NOUN
eurjchem-411	343	57	.	.	PUNCT
eurjchem-411	344	1	heterocyclization	heterocyclization	NOUN
eurjchem-411	344	2	of	of	ADP
eurjchem-411	344	3	compounds	compound	NOUN
eurjchem-411	344	4	4	4	NUM
eurjchem-411	344	5	and	and	CCONJ
eurjchem-411	344	6	5	5	NUM
eurjchem-411	344	7	provided	provide	VERB
eurjchem-411	344	8	an	an	DET
eurjchem-411	344	9	easy	easy	ADJ
eurjchem-411	344	10	and	and	CCONJ
eurjchem-411	344	11	versatile	versatile	ADJ
eurjchem-411	344	12	access	access	NOUN
eurjchem-411	344	13	to	to	ADP
eurjchem-411	344	14	a	a	DET
eurjchem-411	344	15	variety	variety	NOUN
eurjchem-411	344	16	of	of	ADP
eurjchem-411	344	17	condensed	condensed	ADJ
eurjchem-411	344	18	and	and	CCONJ
eurjchem-411	344	19	uncondensed	uncondensed	ADJ
eurjchem-411	344	20	thiophenes	thiophene	NOUN
eurjchem-411	344	21	of	of	ADP
eurjchem-411	344	22	potential	potential	ADJ
eurjchem-411	344	23	biological	biological	ADJ
eurjchem-411	344	24	interest	interest	NOUN
eurjchem-411	344	25	.	.	PUNCT
eurjchem-411	345	1	the	the	DET
eurjchem-411	345	2	biological	biological	ADJ
eurjchem-411	345	3	potential	potential	NOUN
eurjchem-411	345	4	of	of	ADP
eurjchem-411	345	5	the	the	DET
eurjchem-411	345	6	new	new	ADJ
eurjchem-411	345	7	thiophene‐based	thiophene‐base	VERB
eurjchem-411	345	8	derivatives	derivative	NOUN
eurjchem-411	345	9	was	be	AUX
eurjchem-411	345	10	further	far	ADV
eurjchem-411	345	11	investigated	investigate	VERB
eurjchem-411	345	12	by	by	ADP
eurjchem-411	345	13	screening	screen	VERB
eurjchem-411	345	14	their	their	PRON
eurjchem-411	345	15	antimicrobial	antimicrobial	ADJ
eurjchem-411	345	16	activity	activity	NOUN
eurjchem-411	345	17	against	against	ADP
eurjchem-411	345	18	two	two	NUM
eurjchem-411	345	19	pathogenic	pathogenic	ADJ
eurjchem-411	345	20	bacteria	bacteria	NOUN
eurjchem-411	345	21	and	and	CCONJ
eurjchem-411	345	22	two	two	NUM
eurjchem-411	345	23	pathogenic	pathogenic	ADJ
eurjchem-411	345	24	fungi	fungus	NOUN
eurjchem-411	345	25	.	.	PUNCT
eurjchem-411	346	1	biological	biological	ADJ
eurjchem-411	346	2	study	study	NOUN
eurjchem-411	346	3	of	of	ADP
eurjchem-411	346	4	the	the	DET
eurjchem-411	346	5	compounds	compound	NOUN
eurjchem-411	346	6	under	under	ADP
eurjchem-411	346	7	investigation	investigation	NOUN
eurjchem-411	346	8	indicated	indicate	VERB
eurjchem-411	346	9	that	that	SCONJ
eurjchem-411	346	10	the	the	DET
eurjchem-411	346	11	most	most	ADV
eurjchem-411	346	12	prominent	prominent	ADJ
eurjchem-411	346	13	and	and	CCONJ
eurjchem-411	346	14	consistent	consistent	ADJ
eurjchem-411	346	15	antibacterial	antibacterial	ADJ
eurjchem-411	346	16	activity	activity	NOUN
eurjchem-411	346	17	was	be	AUX
eurjchem-411	346	18	obtained	obtain	VERB
eurjchem-411	346	19	with	with	ADP
eurjchem-411	346	20	compound	compound	NOUN
eurjchem-411	346	21	15	15	NUM
eurjchem-411	346	22	carrying	carry	VERB
eurjchem-411	346	23	a	a	DET
eurjchem-411	346	24	triazolothiadiazine	triazolothiadiazine	NOUN
eurjchem-411	346	25	moiety	moiety	NOUN
eurjchem-411	346	26	attached	attach	VERB
eurjchem-411	346	27	to	to	ADP
eurjchem-411	346	28	the	the	DET
eurjchem-411	346	29	thiophene	thiophene	NOUN
eurjchem-411	346	30	ring	ring	NOUN
eurjchem-411	346	31	at	at	ADP
eurjchem-411	346	32	the	the	DET
eurjchem-411	346	33	3‐position	3‐position	NOUN
eurjchem-411	346	34	.	.	PUNCT
eurjchem-411	347	1	compound	compound	NOUN
eurjchem-411	347	2	8	8	NUM
eurjchem-411	347	3	showed	show	VERB
eurjchem-411	347	4	an	an	DET
eurjchem-411	347	5	appreciable	appreciable	ADJ
eurjchem-411	347	6	antifungal	antifungal	ADJ
eurjchem-411	347	7	action	action	NOUN
eurjchem-411	347	8	against	against	ADP
eurjchem-411	347	9	a.	a.	NOUN
eurjchem-411	347	10	flavus	flavus	NOUN
eurjchem-411	347	11	similar	similar	ADJ
eurjchem-411	347	12	to	to	ADP
eurjchem-411	347	13	that	that	PRON
eurjchem-411	347	14	of	of	ADP
eurjchem-411	347	15	the	the	DET
eurjchem-411	347	16	reference	reference	NOUN
eurjchem-411	347	17	drug	drug	NOUN
eurjchem-411	347	18	.	.	PUNCT
eurjchem-411	348	1	its	its	PRON
eurjchem-411	348	2	mic	mic	ADJ
eurjchem-411	348	3	value	value	NOUN
eurjchem-411	348	4	towards	towards	ADP
eurjchem-411	348	5	a.	a.	NOUN
eurjchem-411	348	6	flavus	flavus	NOUN
eurjchem-411	348	7	is	be	AUX
eurjchem-411	348	8	very	very	ADV
eurjchem-411	348	9	significant	significant	ADJ
eurjchem-411	348	10	.	.	PUNCT
eurjchem-411	349	1	in	in	ADP
eurjchem-411	349	2	light	light	NOUN
eurjchem-411	349	3	of	of	ADP
eurjchem-411	349	4	the	the	DET
eurjchem-411	349	5	results	result	NOUN
eurjchem-411	349	6	presented	present	VERB
eurjchem-411	349	7	in	in	ADP
eurjchem-411	349	8	this	this	DET
eurjchem-411	349	9	work	work	NOUN
eurjchem-411	349	10	and	and	CCONJ
eurjchem-411	349	11	taking	take	VERB
eurjchem-411	349	12	into	into	ADP
eurjchem-411	349	13	account	account	NOUN
eurjchem-411	349	14	that	that	SCONJ
eurjchem-411	349	15	this	this	DET
eurjchem-411	349	16	preliminary	preliminary	ADJ
eurjchem-411	349	17	study	study	NOUN
eurjchem-411	349	18	does	do	AUX
eurjchem-411	349	19	not	not	PART
eurjchem-411	349	20	produce	produce	VERB
eurjchem-411	349	21	conclusive	conclusive	ADJ
eurjchem-411	349	22	evidence	evidence	NOUN
eurjchem-411	349	23	regarding	regard	VERB
eurjchem-411	349	24	structure‐antimicrobial	structure‐antimicrobial	ADJ
eurjchem-411	349	25	relationships	relationship	NOUN
eurjchem-411	349	26	,	,	PUNCT
eurjchem-411	349	27	we	we	PRON
eurjchem-411	349	28	have	have	AUX
eurjchem-411	349	29	focused	focus	VERB
eurjchem-411	349	30	our	our	PRON
eurjchem-411	349	31	attention	attention	NOUN
eurjchem-411	349	32	on	on	ADP
eurjchem-411	349	33	the	the	DET
eurjchem-411	349	34	most	most	ADV
eurjchem-411	349	35	promising	promising	ADJ
eurjchem-411	349	36	compounds	compound	NOUN
eurjchem-411	349	37	8	8	NUM
eurjchem-411	349	38	and	and	CCONJ
eurjchem-411	349	39	15	15	NUM
eurjchem-411	349	40	as	as	ADP
eurjchem-411	349	41	an	an	DET
eurjchem-411	349	42	interesting	interesting	ADJ
eurjchem-411	349	43	starting	starting	NOUN
eurjchem-411	349	44	point	point	NOUN
eurjchem-411	349	45	for	for	ADP
eurjchem-411	349	46	the	the	DET
eurjchem-411	349	47	development	development	NOUN
eurjchem-411	349	48	of	of	ADP
eurjchem-411	349	49	a	a	DET
eurjchem-411	349	50	new	new	ADJ
eurjchem-411	349	51	class	class	NOUN
eurjchem-411	349	52	of	of	ADP
eurjchem-411	349	53	antimicrobial	antimicrobial	ADJ
eurjchem-411	349	54	agents	agent	NOUN
eurjchem-411	349	55	.	.	PUNCT
eurjchem-411	350	1	further	further	ADJ
eurjchem-411	350	2	structural	structural	ADJ
eurjchem-411	350	3	modifications	modification	NOUN
eurjchem-411	350	4	of	of	ADP
eurjchem-411	350	5	these	these	DET
eurjchem-411	350	6	type	type	NOUN
eurjchem-411	350	7	of	of	ADP
eurjchem-411	350	8	molecules	molecule	NOUN
eurjchem-411	350	9	might	might	AUX
eurjchem-411	350	10	lead	lead	VERB
eurjchem-411	350	11	to	to	ADP
eurjchem-411	350	12	the	the	DET
eurjchem-411	350	13	discovery	discovery	NOUN
eurjchem-411	350	14	of	of	ADP
eurjchem-411	350	15	more	more	ADV
eurjchem-411	350	16	potent	potent	ADJ
eurjchem-411	350	17	antimicrobial	antimicrobial	ADJ
eurjchem-411	350	18	agents	agent	NOUN
eurjchem-411	350	19	and	and	CCONJ
eurjchem-411	350	20	this	this	DET
eurjchem-411	350	21	work	work	NOUN
eurjchem-411	350	22	is	be	AUX
eurjchem-411	350	23	in	in	ADP
eurjchem-411	350	24	progress	progress	NOUN
eurjchem-411	350	25	.	.	PUNCT
eurjchem-411	351	1	we	we	PRON
eurjchem-411	351	2	believe	believe	VERB
eurjchem-411	351	3	that	that	SCONJ
eurjchem-411	351	4	research	research	NOUN
eurjchem-411	351	5	in	in	ADP
eurjchem-411	351	6	this	this	DET
eurjchem-411	351	7	direction	direction	NOUN
eurjchem-411	351	8	should	should	AUX
eurjchem-411	351	9	be	be	AUX
eurjchem-411	351	10	encouraged	encourage	VERB
eurjchem-411	351	11	in	in	ADP
eurjchem-411	351	12	order	order	NOUN
eurjchem-411	351	13	to	to	PART
eurjchem-411	351	14	broaden	broaden	VERB
eurjchem-411	351	15	the	the	DET
eurjchem-411	351	16	applicability	applicability	NOUN
eurjchem-411	351	17	of	of	ADP
eurjchem-411	351	18	these	these	DET
eurjchem-411	351	19	new	new	ADJ
eurjchem-411	351	20	heterocyclic	heterocyclic	ADJ
eurjchem-411	351	21	frameworks	framework	NOUN
eurjchem-411	351	22	to	to	PART
eurjchem-411	351	23	serve	serve	VERB
eurjchem-411	351	24	as	as	ADP
eurjchem-411	351	25	leads	lead	NOUN
eurjchem-411	351	26	for	for	ADP
eurjchem-411	351	27	designing	design	VERB
eurjchem-411	351	28	novel	novel	ADJ
eurjchem-411	351	29	chemotherapeutic	chemotherapeutic	ADJ
eurjchem-411	351	30	agents	agent	NOUN
eurjchem-411	351	31	.	.	PUNCT
eurjchem-411	352	1	acknowledgements	acknowledgement	NOUN
eurjchem-411	352	2	one	one	NUM
eurjchem-411	352	3	of	of	ADP
eurjchem-411	352	4	the	the	DET
eurjchem-411	352	5	authors	author	NOUN
eurjchem-411	352	6	(	(	PUNCT
eurjchem-411	352	7	h.	h.	PROPN
eurjchem-411	352	8	m.	m.	PROPN
eurjchem-411	352	9	gaber	gaber	PROPN
eurjchem-411	352	10	)	)	PUNCT
eurjchem-411	352	11	would	would	AUX
eurjchem-411	352	12	like	like	VERB
eurjchem-411	352	13	to	to	PART
eurjchem-411	352	14	express	express	VERB
eurjchem-411	352	15	his	his	PRON
eurjchem-411	352	16	sincere	sincere	ADJ
eurjchem-411	352	17	gratitude	gratitude	NOUN
eurjchem-411	352	18	to	to	ADP
eurjchem-411	352	19	the	the	DET
eurjchem-411	352	20	school	school	NOUN
eurjchem-411	352	21	of	of	ADP
eurjchem-411	352	22	chemistry	chemistry	NOUN
eurjchem-411	352	23	,	,	PUNCT
eurjchem-411	352	24	cardiff	cardiff	PROPN
eurjchem-411	352	25	university	university	PROPN
eurjchem-411	352	26	,	,	PUNCT
eurjchem-411	352	27	u.k	u.k	PROPN
eurjchem-411	352	28	.	.	PROPN
eurjchem-411	352	29	,	,	PUNCT
eurjchem-411	352	30	for	for	ADP
eurjchem-411	352	31	granting	grant	VERB
eurjchem-411	352	32	him	he	PRON
eurjchem-411	352	33	a	a	DET
eurjchem-411	352	34	research	research	NOUN
eurjchem-411	352	35	fellowship	fellowship	NOUN
eurjchem-411	352	36	and	and	CCONJ
eurjchem-411	352	37	for	for	ADP
eurjchem-411	352	38	all	all	DET
eurjchem-411	352	39	facilities	facility	NOUN
eurjchem-411	352	40	provided	provide	VERB
eurjchem-411	352	41	to	to	ADP
eurjchem-411	352	42	this	this	DET
eurjchem-411	352	43	fellowship	fellowship	NOUN
eurjchem-411	352	44	.	.	PUNCT
eurjchem-411	353	1	financial	financial	ADJ
eurjchem-411	353	2	support	support	NOUN
eurjchem-411	353	3	from	from	ADP
eurjchem-411	353	4	cardiff	cardiff	PROPN
eurjchem-411	353	5	university	university	NOUN
eurjchem-411	353	6	,	,	PUNCT
eurjchem-411	353	7	the	the	DET
eurjchem-411	353	8	engineering	engineering	NOUN
eurjchem-411	353	9	and	and	CCONJ
eurjchem-411	353	10	physical	physical	PROPN
eurjchem-411	353	11	sciences	sciences	PROPN
eurjchem-411	353	12	research	research	PROPN
eurjchem-411	353	13	council	council	PROPN
eurjchem-411	353	14	(	(	PUNCT
eurjchem-411	353	15	epsrc	epsrc	PROPN
eurjchem-411	353	16	)	)	PUNCT
eurjchem-411	353	17	and	and	CCONJ
eurjchem-411	353	18	the	the	DET
eurjchem-411	353	19	biotechnology	biotechnology	NOUN
eurjchem-411	353	20	and	and	CCONJ
eurjchem-411	353	21	biological	biological	ADJ
eurjchem-411	353	22	sciences	sciences	PROPN
eurjchem-411	353	23	research	research	PROPN
eurjchem-411	353	24	council	council	PROPN
eurjchem-411	353	25	(	(	PUNCT
eurjchem-411	353	26	bbsrc	bbsrc	PROPN
eurjchem-411	353	27	)	)	PUNCT
eurjchem-411	353	28	,	,	PUNCT
eurjchem-411	353	29	in	in	ADP
eurjchem-411	353	30	collaboration	collaboration	NOUN
eurjchem-411	353	31	with	with	ADP
eurjchem-411	353	32	the	the	DET
eurjchem-411	353	33	university	university	PROPN
eurjchem-411	353	34	of	of	ADP
eurjchem-411	353	35	wales	wales	PROPN
eurjchem-411	353	36	college	college	PROPN
eurjchem-411	353	37	of	of	ADP
eurjchem-411	353	38	medicine	medicine	NOUN
eurjchem-411	353	39	,	,	PUNCT
eurjchem-411	353	40	uk	uk	PROPN
eurjchem-411	353	41	,	,	PUNCT
eurjchem-411	353	42	is	be	AUX
eurjchem-411	353	43	gratefully	gratefully	ADV
eurjchem-411	353	44	acknowledged	acknowledge	VERB
eurjchem-411	353	45	.	.	PUNCT
eurjchem-411	354	1	references	reference	NOUN
eurjchem-411	354	2	[	[	X
eurjchem-411	354	3	1	1	NUM
eurjchem-411	354	4	]	]	PUNCT
eurjchem-411	354	5	.	.	PUNCT
eurjchem-411	355	1	weinberg	weinberg	PROPN
eurjchem-411	355	2	,	,	PUNCT
eurjchem-411	355	3	e.	e.	PROPN
eurjchem-411	355	4	d.	d.	PROPN
eurjchem-411	355	5	antifungal	antifungal	PROPN
eurjchem-411	355	6	agents	agent	NOUN
eurjchem-411	355	7	.	.	PUNCT
eurjchem-411	356	1	in	in	ADP
eurjchem-411	356	2	burger	burger	NOUN
eurjchem-411	356	3	's	's	PART
eurjchem-411	356	4	medicinal	medicinal	ADJ
eurjchem-411	356	5	chemisrty	chemisrty	NOUN
eurjchem-411	356	6	and	and	CCONJ
eurjchem-411	356	7	drug	drug	NOUN
eurjchem-411	356	8	discovery	discovery	NOUN
eurjchem-411	356	9	,	,	PUNCT
eurjchem-411	356	10	fifth	fifth	ADJ
eurjchem-411	356	11	ed	ed	NOUN
eurjchem-411	356	12	.	.	PUNCT
eurjchem-411	356	13	,	,	PUNCT
eurjchem-411	356	14	wiley‐interscience	wiley‐interscience	ADV
eurjchem-411	356	15	:	:	PUNCT
eurjchem-411	356	16	new	new	PROPN
eurjchem-411	356	17	york	york	PROPN
eurjchem-411	356	18	,	,	PUNCT
eurjchem-411	356	19	1996	1996	NUM
eurjchem-411	356	20	;	;	PUNCT
eurjchem-411	356	21	vol	vol	NOUN
eurjchem-411	356	22	.	.	NOUN
eurjchem-411	356	23	2	2	NUM
eurjchem-411	356	24	,	,	PUNCT
eurjchem-411	356	25	pp	pp	PROPN
eurjchem-411	356	26	.	.	PUNCT
eurjchem-411	357	1	637‐652	637‐652	PROPN
eurjchem-411	357	2	.	.	PUNCT
eurjchem-411	358	1	[	[	X
eurjchem-411	358	2	2	2	NUM
eurjchem-411	358	3	]	]	PUNCT
eurjchem-411	358	4	.	.	PUNCT
eurjchem-411	359	1	petrov	petrov	PROPN
eurjchem-411	359	2	,	,	PUNCT
eurjchem-411	359	3	o.	o.	PROPN
eurjchem-411	359	4	;	;	PUNCT
eurjchem-411	359	5	gerova	gerova	NOUN
eurjchem-411	359	6	,	,	PUNCT
eurjchem-411	359	7	m.	m.	NOUN
eurjchem-411	359	8	;	;	PUNCT
eurjchem-411	359	9	petrova	petrova	PROPN
eurjchem-411	359	10	,	,	PUNCT
eurjchem-411	359	11	k.	k.	PROPN
eurjchem-411	359	12	;	;	PUNCT
eurjchem-411	359	13	ivanova	ivanova	PROPN
eurjchem-411	359	14	,	,	PUNCT
eurjchem-411	359	15	y.	y.	PROPN
eurjchem-411	359	16	j.	j.	PROPN
eurjchem-411	359	17	heterocyclic	heterocyclic	PROPN
eurjchem-411	359	18	chem	chem	PROPN
eurjchem-411	359	19	.	.	PUNCT
eurjchem-411	360	1	2009	2009	NUM
eurjchem-411	360	2	,	,	PUNCT
eurjchem-411	360	3	46	46	NUM
eurjchem-411	360	4	,	,	PUNCT
eurjchem-411	360	5	44‐48	44‐48	NUM
eurjchem-411	360	6	.	.	PUNCT
eurjchem-411	361	1	[	[	X
eurjchem-411	361	2	3	3	NUM
eurjchem-411	361	3	]	]	PUNCT
eurjchem-411	361	4	.	.	PUNCT
eurjchem-411	362	1	wildfeuer	wildfeuer	PROPN
eurjchem-411	362	2	,	,	PUNCT
eurjchem-411	362	3	a.	a.	NOUN
eurjchem-411	362	4	;	;	PUNCT
eurjchem-411	362	5	seidl	seidl	PROPN
eurjchem-411	362	6	,	,	PUNCT
eurjchem-411	362	7	h.	h.	PROPN
eurjchem-411	362	8	p.	p.	PROPN
eurjchem-411	362	9	;	;	PUNCT
eurjchem-411	362	10	paule	paule	PROPN
eurjchem-411	362	11	,	,	PUNCT
eurjchem-411	362	12	i.	i.	PROPN
eurjchem-411	362	13	;	;	PUNCT
eurjchem-411	362	14	haberreiter	haberreiter	NOUN
eurjchem-411	362	15	,	,	PUNCT
eurjchem-411	362	16	a.	a.	NOUN
eurjchem-411	362	17	mycoses	mycose	NOUN
eurjchem-411	362	18	1998	1998	NUM
eurjchem-411	362	19	,	,	PUNCT
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eurjchem-411	362	21	,	,	PUNCT
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eurjchem-411	362	23	.	.	PUNCT
eurjchem-411	363	1	[	[	X
eurjchem-411	363	2	4	4	NUM
eurjchem-411	363	3	]	]	PUNCT
eurjchem-411	363	4	.	.	PUNCT
eurjchem-411	364	1	daidone	daidone	PROPN
eurjchem-411	364	2	,	,	PUNCT
eurjchem-411	364	3	g.	g.	PROPN
eurjchem-411	364	4	;	;	PUNCT
eurjchem-411	364	5	maggio	maggio	PROPN
eurjchem-411	364	6	,	,	PUNCT
eurjchem-411	364	7	b.	b.	PROPN
eurjchem-411	364	8	;	;	PUNCT
eurjchem-411	364	9	schillaci	schillaci	PROPN
eurjchem-411	364	10	,	,	PUNCT
eurjchem-411	364	11	d.	d.	PROPN
eurjchem-411	364	12	pharmazie	pharmazie	PROPN
eurjchem-411	364	13	1990	1990	NUM
eurjchem-411	364	14	,	,	PUNCT
eurjchem-411	364	15	45	45	NUM
eurjchem-411	364	16	,	,	PUNCT
eurjchem-411	364	17	441‐442	441‐442	NUM
eurjchem-411	364	18	.	.	PUNCT
eurjchem-411	365	1	222	222	NUM
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eurjchem-411	365	3	and	and	CCONJ
eurjchem-411	365	4	bagley	bagley	PROPN
eurjchem-411	365	5	/	/	SYM
eurjchem-411	365	6	european	european	PROPN
eurjchem-411	365	7	journal	journal	PROPN
eurjchem-411	365	8	of	of	ADP
eurjchem-411	365	9	chemistry	chemistry	NOUN
eurjchem-411	365	10	2	2	NUM
eurjchem-411	365	11	(	(	PUNCT
eurjchem-411	365	12	2	2	NUM
eurjchem-411	365	13	)	)	PUNCT
eurjchem-411	365	14	(	(	PUNCT
eurjchem-411	365	15	2011	2011	NUM
eurjchem-411	365	16	)	)	PUNCT
eurjchem-411	365	17	214‐222	214‐222	NUM
eurjchem-411	366	1	[	[	X
eurjchem-411	366	2	5	5	NUM
eurjchem-411	366	3	]	]	PUNCT
eurjchem-411	366	4	.	.	PUNCT
eurjchem-411	367	1	franchini	franchini	PROPN
eurjchem-411	367	2	,	,	PUNCT
eurjchem-411	367	3	c.	c.	PROPN
eurjchem-411	367	4	;	;	PUNCT
eurjchem-411	367	5	muraglia	muraglia	PROPN
eurjchem-411	367	6	,	,	PUNCT
eurjchem-411	367	7	m.	m.	NOUN
eurjchem-411	367	8	;	;	PUNCT
eurjchem-411	367	9	corbo	corbo	PROPN
eurjchem-411	367	10	,	,	PUNCT
eurjchem-411	367	11	f.	f.	PROPN
eurjchem-411	367	12	;	;	PUNCT
eurjchem-411	367	13	florio	florio	PROPN
eurjchem-411	367	14	,	,	PUNCT
eurjchem-411	367	15	m.	m.	NOUN
eurjchem-411	367	16	a.	a.	PROPN
eurjchem-411	367	17	;	;	PUNCT
eurjchem-411	367	18	mola	mola	PROPN
eurjchem-411	367	19	,	,	PUNCT
eurjchem-411	367	20	a.	a.	PROPN
eurjchem-411	367	21	d.	d.	PROPN
eurjchem-411	367	22	;	;	PUNCT
eurjchem-411	367	23	rosato	rosato	PROPN
eurjchem-411	367	24	,	,	PUNCT
eurjchem-411	367	25	a.	a.	NOUN
eurjchem-411	367	26	;	;	PUNCT
eurjchem-411	367	27	matucci	matucci	PROPN
eurjchem-411	367	28	,	,	PUNCT
eurjchem-411	367	29	r.	r.	PROPN
eurjchem-411	367	30	;	;	PUNCT
eurjchem-411	367	31	nesi	nesi	PROPN
eurjchem-411	367	32	,	,	PUNCT
eurjchem-411	367	33	m.	m.	NOUN
eurjchem-411	367	34	;	;	PUNCT
eurjchem-411	367	35	bambeke	bambeke	PROPN
eurjchem-411	367	36	,	,	PUNCT
eurjchem-411	367	37	f.	f.	PROPN
eurjchem-411	367	38	v.	v.	PROPN
eurjchem-411	367	39	;	;	PUNCT
eurjchem-411	367	40	vitali	vitali	PROPN
eurjchem-411	367	41	,	,	PUNCT
eurjchem-411	367	42	c.	c.	PROPN
eurjchem-411	367	43	arch	arch	NOUN
eurjchem-411	367	44	.	.	PUNCT
eurjchem-411	368	1	pharm	pharm	NOUN
eurjchem-411	368	2	.	.	PUNCT
eurjchem-411	369	1	chem	chem	PROPN
eurjchem-411	369	2	.	.	PUNCT
eurjchem-411	370	1	life	life	PROPN
eurjchem-411	370	2	sci	sci	PROPN
eurjchem-411	370	3	.	.	PROPN
eurjchem-411	370	4	2009	2009	NUM
eurjchem-411	370	5	,	,	PUNCT
eurjchem-411	370	6	342	342	NUM
eurjchem-411	370	7	,	,	PUNCT
eurjchem-411	370	8	605‐613	605‐613	NUM
eurjchem-411	370	9	.	.	PUNCT
eurjchem-411	371	1	[	[	X
eurjchem-411	371	2	6	6	NUM
eurjchem-411	371	3	]	]	PUNCT
eurjchem-411	371	4	.	.	PUNCT
eurjchem-411	372	1	pinto	pinto	NOUN
eurjchem-411	372	2	,	,	PUNCT
eurjchem-411	372	3	e.	e.	PROPN
eurjchem-411	372	4	;	;	PUNCT
eurjchem-411	372	5	queiroz	queiroz	ADV
eurjchem-411	372	6	,	,	PUNCT
eurjchem-411	372	7	m.‐j	m.‐j	PROPN
eurjchem-411	372	8	.	.	PUNCT
eurjchem-411	373	1	r.	r.	PROPN
eurjchem-411	373	2	p.	p.	PROPN
eurjchem-411	373	3	;	;	PUNCT
eurjchem-411	373	4	vale‐silva	vale‐silva	PROPN
eurjchem-411	373	5	,	,	PUNCT
eurjchem-411	373	6	l.	l.	PROPN
eurjchem-411	373	7	a.	a.	PROPN
eurjchem-411	373	8	;	;	PUNCT
eurjchem-411	373	9	oliveira	oliveira	PROPN
eurjchem-411	373	10	,	,	PUNCT
eurjchem-411	373	11	j.	j.	PROPN
eurjchem-411	373	12	f.	f.	PROPN
eurjchem-411	373	13	;	;	PUNCT
eurjchem-411	373	14	begouin	begouin	PROPN
eurjchem-411	373	15	,	,	PUNCT
eurjchem-411	373	16	a.	a.	NOUN
eurjchem-411	373	17	;	;	PUNCT
eurjchem-411	373	18	begouin	begouin	NOUN
eurjchem-411	373	19	,	,	PUNCT
eurjchem-411	373	20	j.‐m	j.‐m	PROPN
eurjchem-411	373	21	.	.	PROPN
eurjchem-411	373	22	;	;	PUNCT
eurjchem-411	373	23	kirsch	kirsch	PROPN
eurjchem-411	373	24	,	,	PUNCT
eurjchem-411	373	25	g.	g.	PROPN
eurjchem-411	373	26	bioorg	bioorg	PROPN
eurjchem-411	373	27	.	.	PUNCT
eurjchem-411	374	1	med	med	PROPN
eurjchem-411	374	2	.	.	PROPN
eurjchem-411	374	3	chem	chem	PROPN
eurjchem-411	374	4	.	.	PUNCT
eurjchem-411	375	1	2008	2008	NUM
eurjchem-411	375	2	,	,	PUNCT
eurjchem-411	375	3	16	16	NUM
eurjchem-411	375	4	,	,	PUNCT
eurjchem-411	375	5	8172‐8177	8172‐8177	NUM
eurjchem-411	375	6	.	.	PUNCT
eurjchem-411	376	1	[	[	X
eurjchem-411	376	2	7	7	NUM
eurjchem-411	376	3	]	]	PUNCT
eurjchem-411	376	4	.	.	PUNCT
eurjchem-411	377	1	daniel	daniel	PROPN
eurjchem-411	377	2	,	,	PUNCT
eurjchem-411	377	3	v.	v.	PROPN
eurjchem-411	377	4	p.	p.	PROPN
eurjchem-411	377	5	;	;	PUNCT
eurjchem-411	377	6	murukan	murukan	PROPN
eurjchem-411	377	7	,	,	PUNCT
eurjchem-411	377	8	b.	b.	PROPN
eurjchem-411	377	9	;	;	PUNCT
eurjchem-411	377	10	kumari	kumari	PROPN
eurjchem-411	377	11	,	,	PUNCT
eurjchem-411	377	12	b.	b.	PROPN
eurjchem-411	377	13	s.	s.	PROPN
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eurjchem-411	377	15	mohanan	mohanan	PROPN
eurjchem-411	377	16	,	,	PUNCT
eurjchem-411	377	17	k.	k.	PROPN
eurjchem-411	377	18	spectrochim	spectrochim	PROPN
eurjchem-411	377	19	.	.	PUNCT
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eurjchem-411	378	4	,	,	PUNCT
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eurjchem-411	378	6	,	,	PUNCT
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eurjchem-411	378	8	.	.	PUNCT
eurjchem-411	379	1	[	[	X
eurjchem-411	379	2	8	8	NUM
eurjchem-411	379	3	]	]	PUNCT
eurjchem-411	379	4	.	.	PUNCT
eurjchem-411	379	5	ghorab	ghorab	PROPN
eurjchem-411	379	6	,	,	PUNCT
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eurjchem-411	379	9	;	;	PUNCT
eurjchem-411	379	10	amin	amin	PROPN
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eurjchem-411	379	12	n.	n.	PROPN
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eurjchem-411	379	15	el	el	PROPN
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eurjchem-411	379	28	shehab	shehab	PROPN
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eurjchem-411	379	30	m.	m.	NOUN
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eurjchem-411	379	42	relat	relat	PROPN
eurjchem-411	379	43	.	.	PUNCT
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eurjchem-411	380	2	.	.	PUNCT
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eurjchem-411	381	2	,	,	PUNCT
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eurjchem-411	381	4	,	,	PUNCT
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eurjchem-411	381	6	.	.	PUNCT
eurjchem-411	382	1	[	[	X
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eurjchem-411	382	3	]	]	PUNCT
eurjchem-411	382	4	.	.	PUNCT
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eurjchem-411	383	2	,	,	PUNCT
eurjchem-411	383	3	e.	e.	PROPN
eurjchem-411	383	4	s.	s.	PROPN
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eurjchem-411	383	7	,	,	PUNCT
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eurjchem-411	383	9	,	,	PUNCT
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eurjchem-411	384	1	[	[	X
eurjchem-411	384	2	10	10	NUM
eurjchem-411	384	3	]	]	PUNCT
eurjchem-411	384	4	.	.	PUNCT
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eurjchem-411	385	2	,	,	PUNCT
eurjchem-411	385	3	m.	m.	PROPN
eurjchem-411	385	4	j.	j.	PROPN
eurjchem-411	385	5	r.	r.	PROPN
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eurjchem-411	385	7	;	;	PUNCT
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eurjchem-411	385	9	,	,	PUNCT
eurjchem-411	385	10	i.	i.	PROPN
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eurjchem-411	385	14	;	;	PUNCT
eurjchem-411	385	15	de	de	X
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eurjchem-411	385	17	,	,	PUNCT
eurjchem-411	385	18	y.	y.	PROPN
eurjchem-411	385	19	;	;	PUNCT
eurjchem-411	385	20	kirsch	kirsch	PROPN
eurjchem-411	385	21	,	,	PUNCT
eurjchem-411	385	22	g.	g.	PROPN
eurjchem-411	385	23	;	;	PUNCT
eurjchem-411	385	24	calhelha	calhelha	NOUN
eurjchem-411	385	25	,	,	PUNCT
eurjchem-411	385	26	r.	r.	PROPN
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eurjchem-411	385	28	;	;	PUNCT
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eurjchem-411	385	30	,	,	PUNCT
eurjchem-411	385	31	l.	l.	PROPN
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eurjchem-411	385	34	.	.	PUNCT
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eurjchem-411	386	2	.	.	PROPN
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eurjchem-411	386	4	.	.	PUNCT
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eurjchem-411	387	2	,	,	PUNCT
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eurjchem-411	387	4	,	,	PUNCT
eurjchem-411	387	5	6827‐	6827‐	PROPN
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eurjchem-411	387	7	.	.	PUNCT
eurjchem-411	388	1	[	[	X
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eurjchem-411	388	3	]	]	PUNCT
eurjchem-411	388	4	.	.	PUNCT
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eurjchem-411	388	6	,	,	PUNCT
eurjchem-411	388	7	a.	a.	PROPN
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eurjchem-411	388	9	;	;	PUNCT
eurjchem-411	388	10	giusiano	giusiano	PROPN
eurjchem-411	388	11	,	,	PUNCT
eurjchem-411	388	12	g.	g.	PROPN
eurjchem-411	388	13	;	;	PUNCT
eurjchem-411	388	14	ezkurra	ezkurra	PROPN
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eurjchem-411	388	18	;	;	PUNCT
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eurjchem-411	389	2	.	.	PUNCT
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eurjchem-411	390	2	.	.	PUNCT
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eurjchem-411	391	2	,	,	PUNCT
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eurjchem-411	391	4	,	,	PUNCT
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eurjchem-411	391	6	.	.	PUNCT
eurjchem-411	392	1	[	[	X
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eurjchem-411	392	3	]	]	PUNCT
eurjchem-411	392	4	.	.	PUNCT
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eurjchem-411	393	2	,	,	PUNCT
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eurjchem-411	393	5	;	;	PUNCT
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eurjchem-411	393	7	,	,	PUNCT
eurjchem-411	393	8	b.	b.	PROPN
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eurjchem-411	393	10	;	;	PUNCT
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eurjchem-411	393	12	,	,	PUNCT
eurjchem-411	393	13	a.	a.	PROPN
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eurjchem-411	393	15	;	;	PUNCT
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eurjchem-411	393	17	,	,	PUNCT
eurjchem-411	393	18	r.	r.	PROPN
eurjchem-411	393	19	h.	h.	PROPN
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eurjchem-411	393	21	.	.	PUNCT
eurjchem-411	394	1	j.	j.	PROPN
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eurjchem-411	394	5	.	.	PUNCT
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eurjchem-411	395	2	,	,	PUNCT
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eurjchem-411	395	4	,	,	PUNCT
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eurjchem-411	395	6	.	.	PUNCT
eurjchem-411	396	1	[	[	X
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eurjchem-411	396	3	]	]	PUNCT
eurjchem-411	396	4	.	.	PUNCT
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eurjchem-411	397	2	,	,	PUNCT
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eurjchem-411	397	7	;	;	PUNCT
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eurjchem-411	398	4	a.	a.	PROPN
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eurjchem-411	398	6	;	;	PUNCT
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eurjchem-411	398	13	;	;	PUNCT
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eurjchem-411	398	21	relat	relat	PROPN
eurjchem-411	398	22	.	.	PUNCT
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eurjchem-411	399	2	.	.	PUNCT
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eurjchem-411	400	2	,	,	PUNCT
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eurjchem-411	400	4	,	,	PUNCT
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eurjchem-411	400	6	.	.	PUNCT
eurjchem-411	401	1	[	[	X
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eurjchem-411	401	3	]	]	SYM
eurjchem-411	401	4	.	.	PUNCT
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eurjchem-411	402	2	,	,	PUNCT
eurjchem-411	402	3	m.	m.	NOUN
eurjchem-411	402	4	a.	a.	PROPN
eurjchem-411	402	5	;	;	PUNCT
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eurjchem-411	402	8	m.	m.	PROPN
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eurjchem-411	402	10	;	;	PUNCT
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eurjchem-411	402	13	h.	h.	PROPN
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eurjchem-411	402	20	;	;	PUNCT
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eurjchem-411	403	1	j.	j.	PROPN
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eurjchem-411	403	5	.	.	PUNCT
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eurjchem-411	404	2	,	,	PUNCT
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eurjchem-411	404	4	,	,	PUNCT
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eurjchem-411	404	6	.	.	PUNCT
eurjchem-411	405	1	[	[	X
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eurjchem-411	405	3	]	]	PUNCT
eurjchem-411	405	4	.	.	PUNCT
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eurjchem-411	407	4	.	.	PUNCT
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eurjchem-411	408	7	,	,	PUNCT
eurjchem-411	408	8	h.	h.	PROPN
eurjchem-411	408	9	;	;	PUNCT
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eurjchem-411	408	14	;	;	PUNCT
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eurjchem-411	409	1	j.	j.	PROPN
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eurjchem-411	409	3	.	.	PUNCT
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eurjchem-411	409	5	.	.	PUNCT
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eurjchem-411	410	2	,	,	PUNCT
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eurjchem-411	410	4	,	,	PUNCT
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eurjchem-411	410	6	.	.	PUNCT
eurjchem-411	411	1	[	[	X
eurjchem-411	411	2	17	17	NUM
eurjchem-411	411	3	]	]	PUNCT
eurjchem-411	411	4	.	.	PUNCT
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eurjchem-411	412	3	h.	h.	PROPN
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eurjchem-411	412	5	;	;	PUNCT
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eurjchem-411	412	9	e.	e.	PROPN
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eurjchem-411	412	11	;	;	PUNCT
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eurjchem-411	412	13	,	,	PUNCT
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eurjchem-411	412	16	;	;	PUNCT
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eurjchem-411	412	22	.	.	PUNCT
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eurjchem-411	413	2	.	.	PUNCT
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eurjchem-411	414	2	,	,	PUNCT
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eurjchem-411	414	4	,	,	PUNCT
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eurjchem-411	414	6	.	.	PUNCT
eurjchem-411	415	1	[	[	X
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eurjchem-411	415	4	.	.	PUNCT
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eurjchem-411	416	4	;	;	PUNCT
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eurjchem-411	416	6	,	,	PUNCT
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eurjchem-411	416	8	;	;	PUNCT
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eurjchem-411	416	13	.	.	PUNCT
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eurjchem-411	417	2	.	.	PUNCT
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eurjchem-411	418	2	,	,	PUNCT
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eurjchem-411	418	6	.	.	PUNCT
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eurjchem-411	419	3	]	]	PUNCT
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eurjchem-411	419	7	m.	m.	NOUN
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eurjchem-411	419	9	duc	duc	PROPN
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eurjchem-411	419	14	narcisse	narcisse	PROPN
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eurjchem-411	419	16	g.	g.	PROPN
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eurjchem-411	419	18	bakri‐logeais	bakri‐logeais	PROPN
eurjchem-411	419	19	,	,	PUNCT
eurjchem-411	419	20	f.	f.	PROPN
eurjchem-411	419	21	;	;	PUNCT
eurjchem-411	419	22	huguet	huguet	PROPN
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eurjchem-411	419	24	f.	f.	PROPN
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eurjchem-411	421	2	,	,	PUNCT
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eurjchem-411	421	4	,	,	PUNCT
eurjchem-411	421	5	563‐565	563‐565	NUM
eurjchem-411	421	6	.	.	PUNCT
eurjchem-411	422	1	[	[	X
eurjchem-411	422	2	20	20	NUM
eurjchem-411	422	3	]	]	PUNCT
eurjchem-411	422	4	.	.	PUNCT
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eurjchem-411	423	2	,	,	PUNCT
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eurjchem-411	423	4	;	;	PUNCT
eurjchem-411	423	5	choi	choi	NOUN
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eurjchem-411	423	7	j.‐h	j.‐h	PROPN
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eurjchem-411	423	12	,	,	PUNCT
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eurjchem-411	423	14	,	,	PUNCT
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eurjchem-411	424	1	[	[	X
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eurjchem-411	424	3	]	]	PUNCT
eurjchem-411	424	4	.	.	PUNCT
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eurjchem-411	425	2	,	,	PUNCT
eurjchem-411	425	3	r.	r.	PROPN
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eurjchem-411	425	5	;	;	PUNCT
eurjchem-411	425	6	needham	needham	PROPN
eurjchem-411	425	7	,	,	PUNCT
eurjchem-411	425	8	l.	l.	PROPN
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eurjchem-411	425	11	blanton	blanton	PROPN
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eurjchem-411	425	13	jr	jr	PROPN
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eurjchem-411	425	18	j.	j.	PROPN
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eurjchem-411	425	22	.	.	PUNCT
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eurjchem-411	426	2	,	,	PUNCT
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eurjchem-411	426	4	,	,	PUNCT
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eurjchem-411	426	6	.	.	PUNCT
eurjchem-411	427	1	[	[	X
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eurjchem-411	427	3	]	]	PUNCT
eurjchem-411	427	4	.	.	PUNCT
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eurjchem-411	428	2	,	,	PUNCT
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eurjchem-411	428	5	;	;	PUNCT
eurjchem-411	428	6	trukhin	trukhin	PROPN
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eurjchem-411	428	8	d.	d.	PROPN
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eurjchem-411	428	10	;	;	PUNCT
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eurjchem-411	428	12	,	,	PUNCT
eurjchem-411	428	13	o.	o.	PROPN
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eurjchem-411	428	20	;	;	PUNCT
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eurjchem-411	428	25	;	;	PUNCT
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eurjchem-411	429	3	]	]	PUNCT
eurjchem-411	429	4	.	.	PUNCT
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eurjchem-411	430	2	,	,	PUNCT
eurjchem-411	430	3	k.	k.	PROPN
eurjchem-411	430	4	;	;	PUNCT
eurjchem-411	430	5	gruner	gruner	PROPN
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eurjchem-411	430	8	;	;	PUNCT
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eurjchem-411	430	12	;	;	PUNCT
eurjchem-411	430	13	sueptitz	sueptitz	PROPN
eurjchem-411	430	14	,	,	PUNCT
eurjchem-411	430	15	g.	g.	PROPN
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eurjchem-411	430	17	.	.	PUNCT
eurjchem-411	431	1	chem	chem	PROPN
eurjchem-411	431	2	.	.	PUNCT
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eurjchem-411	432	2	,	,	PUNCT
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eurjchem-411	432	4	,	,	PUNCT
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eurjchem-411	432	6	.	.	PUNCT
eurjchem-411	433	1	[	[	X
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eurjchem-411	433	3	]	]	PUNCT
eurjchem-411	433	4	.	.	PUNCT
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eurjchem-411	434	2	,	,	PUNCT
eurjchem-411	434	3	a.	a.	PROPN
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eurjchem-411	434	5	;	;	PUNCT
eurjchem-411	434	6	kirby	kirby	PROPN
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eurjchem-411	434	8	w.	w.	PROPN
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eurjchem-411	434	11	;	;	PUNCT
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eurjchem-411	436	2	.	.	PUNCT
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eurjchem-411	437	2	,	,	PUNCT
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eurjchem-411	437	4	,	,	PUNCT
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eurjchem-411	437	6	.	.	PUNCT
eurjchem-411	438	1	[	[	X
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eurjchem-411	438	3	]	]	PUNCT
eurjchem-411	438	4	.	.	PUNCT
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eurjchem-411	439	5	;	;	PUNCT
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eurjchem-411	440	2	.	.	PUNCT
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eurjchem-411	441	2	,	,	PUNCT
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eurjchem-411	441	6	.	.	PUNCT
eurjchem-411	442	1	[	[	X
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eurjchem-411	442	3	]	]	PUNCT
eurjchem-411	442	4	.	.	PUNCT
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eurjchem-411	445	1	[	[	X
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eurjchem-411	445	3	]	]	PUNCT
eurjchem-411	445	4	.	.	PUNCT
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eurjchem-411	446	2	,	,	PUNCT
eurjchem-411	446	3	l.	l.	PROPN
eurjchem-411	446	4	;	;	PUNCT
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eurjchem-411	446	8	;	;	PUNCT
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eurjchem-411	447	3	]	]	PUNCT
eurjchem-411	447	4	.	.	PUNCT
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eurjchem-411	449	2	.	.	PUNCT
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eurjchem-411	450	2	.	.	PUNCT
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eurjchem-411	451	2	,	,	PUNCT
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eurjchem-411	452	1	[	[	X
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eurjchem-411	452	3	]	]	PUNCT
eurjchem-411	452	4	.	.	PUNCT
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eurjchem-411	453	5	;	;	PUNCT
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eurjchem-411	455	2	,	,	PUNCT
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eurjchem-411	456	3	]	]	PUNCT
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eurjchem-411	458	2	.	.	PUNCT
eurjchem-411	459	1	life	life	PROPN
eurjchem-411	459	2	sci	sci	PROPN
eurjchem-411	459	3	.	.	PROPN
eurjchem-411	459	4	2006	2006	NUM
eurjchem-411	459	5	,	,	PUNCT
eurjchem-411	459	6	339	339	NUM
eurjchem-411	459	7	,	,	PUNCT
eurjchem-411	459	8	378‐387	378‐387	NUM
eurjchem-411	459	9	.	.	PUNCT
eurjchem-411	460	1	[	[	X
eurjchem-411	460	2	31	31	NUM
eurjchem-411	460	3	]	]	PUNCT
eurjchem-411	460	4	.	.	PUNCT
eurjchem-411	461	1	küçükgüzel	küçükgüzel	PROPN
eurjchem-411	461	2	,	,	PUNCT
eurjchem-411	461	3	i̇.	i̇.	PROPN
eurjchem-411	461	4	;	;	PUNCT
eurjchem-411	461	5	küçükgüzel	küçükgüzel	ADJ
eurjchem-411	461	6	,	,	PUNCT
eurjchem-411	461	7	ş	ş	X
eurjchem-411	461	8	.	.	PUNCT
eurjchem-411	461	9	g.	g.	PROPN
eurjchem-411	461	10	;	;	PUNCT
eurjchem-411	461	11	rollas	rollas	PROPN
eurjchem-411	461	12	,	,	PUNCT
eurjchem-411	461	13	s.	s.	PROPN
eurjchem-411	461	14	;	;	PUNCT
eurjchem-411	461	15	ötük‐saniş	ötük‐saniş	NUM
eurjchem-411	461	16	,	,	PUNCT
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eurjchem-411	461	18	;	;	PUNCT
eurjchem-411	461	19	özdemir	özdemir	NOUN
eurjchem-411	461	20	,	,	PUNCT
eurjchem-411	461	21	o.	o.	PROPN
eurjchem-411	461	22	;	;	PUNCT
eurjchem-411	461	23	bayrak	bayrak	PROPN
eurjchem-411	461	24	,	,	PUNCT
eurjchem-411	461	25	i̇.	i̇.	PROPN
eurjchem-411	461	26	;	;	PUNCT
eurjchem-411	461	27	altuğ	altuğ	ADJ
eurjchem-411	461	28	,	,	PUNCT
eurjchem-411	461	29	t.	t.	PROPN
eurjchem-411	461	30	;	;	PUNCT
eurjchem-411	461	31	stables	stable	NOUN
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eurjchem-411	461	33	j.	j.	PROPN
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eurjchem-411	461	37	,	,	PUNCT
eurjchem-411	461	38	59	59	NUM
eurjchem-411	461	39	,	,	PUNCT
eurjchem-411	461	40	893‐901	893‐901	NUM
eurjchem-411	461	41	.	.	PUNCT
eurjchem-411	462	1	[	[	X
eurjchem-411	462	2	32	32	NUM
eurjchem-411	462	3	]	]	PUNCT
eurjchem-411	462	4	.	.	PUNCT
eurjchem-411	463	1	oruç	oruç	PROPN
eurjchem-411	463	2	,	,	PUNCT
eurjchem-411	463	3	e.	e.	PROPN
eurjchem-411	463	4	e.	e.	PROPN
eurjchem-411	463	5	;	;	PUNCT
eurjchem-411	463	6	koçyigit‐kaymakçioglu	koçyigit‐kaymakçioglu	PROPN
eurjchem-411	463	7	,	,	PUNCT
eurjchem-411	463	8	b.	b.	PROPN
eurjchem-411	463	9	;	;	PUNCT
eurjchem-411	463	10	oral	oral	ADJ
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eurjchem-411	463	12	b.	b.	PROPN
eurjchem-411	463	13	;	;	PUNCT
eurjchem-411	463	14	altunbas‐toklu	altunbas‐toklu	PROPN
eurjchem-411	463	15	,	,	PUNCT
eurjchem-411	463	16	h.	h.	PROPN
eurjchem-411	463	17	z.	z.	PROPN
eurjchem-411	463	18	;	;	PUNCT
eurjchem-411	463	19	kabasakal	kabasakal	PROPN
eurjchem-411	463	20	,	,	PUNCT
eurjchem-411	463	21	l.	l.	PROPN
eurjchem-411	463	22	;	;	PUNCT
eurjchem-411	463	23	rollas	rollas	PROPN
eurjchem-411	463	24	,	,	PUNCT
eurjchem-411	463	25	s.	s.	PROPN
eurjchem-411	463	26	arch	arch	PROPN
eurjchem-411	463	27	.	.	PUNCT
eurjchem-411	464	1	pharm	pharm	NOUN
eurjchem-411	464	2	.	.	PUNCT
eurjchem-411	465	1	chem	chem	PROPN
eurjchem-411	465	2	.	.	PUNCT
eurjchem-411	466	1	life	life	PROPN
eurjchem-411	466	2	sci	sci	PROPN
eurjchem-411	466	3	.	.	PROPN
eurjchem-411	466	4	2006	2006	NUM
eurjchem-411	466	5	,	,	PUNCT
eurjchem-411	466	6	339	339	NUM
eurjchem-411	466	7	,	,	PUNCT
eurjchem-411	466	8	267‐	267‐	NUM
eurjchem-411	466	9	272	272	NUM
eurjchem-411	466	10	.	.	PUNCT
eurjchem-411	467	1	[	[	X
eurjchem-411	467	2	33	33	NUM
eurjchem-411	467	3	]	]	PUNCT
eurjchem-411	467	4	.	.	PUNCT
eurjchem-411	468	1	güzeldemirci	güzeldemirci	PROPN
eurjchem-411	468	2	,	,	PUNCT
eurjchem-411	468	3	n.	n.	PROPN
eurjchem-411	468	4	u.	u.	PROPN
eurjchem-411	468	5	;	;	PUNCT
eurjchem-411	468	6	küçükbasmaci	küçükbasmaci	PROPN
eurjchem-411	468	7	,	,	PUNCT
eurjchem-411	468	8	ö.	ö.	PROPN
eurjchem-411	468	9	eur	eur	PROPN
eurjchem-411	468	10	.	.	PUNCT
eurjchem-411	469	1	j.	j.	PROPN
eurjchem-411	469	2	med	med	PROPN
eurjchem-411	469	3	.	.	PROPN
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eurjchem-411	469	5	.	.	PUNCT
eurjchem-411	470	1	2010	2010	NUM
eurjchem-411	470	2	,	,	PUNCT
eurjchem-411	470	3	45	45	NUM
eurjchem-411	470	4	,	,	PUNCT
eurjchem-411	470	5	63‐	63‐	NUM
eurjchem-411	470	6	68	68	NUM
eurjchem-411	470	7	.	.	PUNCT
eurjchem-411	471	1	[	[	X
eurjchem-411	471	2	34	34	NUM
eurjchem-411	471	3	]	]	PUNCT
eurjchem-411	471	4	.	.	PUNCT
eurjchem-411	472	1	küçükgüzel	küçükgüzel	PROPN
eurjchem-411	472	2	,	,	PUNCT
eurjchem-411	472	3	i̇.	i̇.	PROPN
eurjchem-411	472	4	;	;	PUNCT
eurjchem-411	472	5	küçükgüzel	küçükgüzel	ADJ
eurjchem-411	472	6	,	,	PUNCT
eurjchem-411	472	7	ş	ş	X
eurjchem-411	472	8	.	.	PUNCT
eurjchem-411	472	9	g.	g.	PROPN
eurjchem-411	472	10	;	;	PUNCT
eurjchem-411	472	11	rollas	rollas	PROPN
eurjchem-411	472	12	,	,	PUNCT
eurjchem-411	472	13	s.	s.	PROPN
eurjchem-411	472	14	;	;	PUNCT
eurjchem-411	472	15	kiraz	kiraz	PROPN
eurjchem-411	472	16	,	,	PUNCT
eurjchem-411	472	17	m.	m.	NOUN
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eurjchem-411	472	19	.	.	PUNCT
eurjchem-411	473	1	med	med	PROPN
eurjchem-411	473	2	.	.	PROPN
eurjchem-411	473	3	chem	chem	PROPN
eurjchem-411	473	4	.	.	PUNCT
eurjchem-411	474	1	lett	lett	PROPN
eurjchem-411	474	2	.	.	PUNCT
eurjchem-411	475	1	2001	2001	NUM
eurjchem-411	475	2	,	,	PUNCT
eurjchem-411	475	3	11	11	NUM
eurjchem-411	475	4	,	,	PUNCT
eurjchem-411	475	5	1703‐1707	1703‐1707	NUM
eurjchem-411	475	6	.	.	PUNCT
eurjchem-411	476	1	[	[	X
eurjchem-411	476	2	35	35	NUM
eurjchem-411	476	3	]	]	SYM
eurjchem-411	476	4	.	.	PUNCT
eurjchem-411	477	1	gürsoy	gürsoy	NOUN
eurjchem-411	477	2	,	,	PUNCT
eurjchem-411	477	3	a.	a.	NOUN
eurjchem-411	477	4	;	;	PUNCT
eurjchem-411	477	5	demirayak	demirayak	PROPN
eurjchem-411	477	6	,	,	PUNCT
eurjchem-411	477	7	ş	ş	X
eurjchem-411	477	8	.	.	PUNCT
eurjchem-411	477	9	;	;	PUNCT
eurjchem-411	477	10	cesur	cesur	PROPN
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eurjchem-411	477	13	;	;	PUNCT
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eurjchem-411	477	15	,	,	PUNCT
eurjchem-411	477	16	j.	j.	PROPN
eurjchem-411	477	17	;	;	PUNCT
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eurjchem-411	477	19	,	,	PUNCT
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eurjchem-411	477	23	,	,	PUNCT
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eurjchem-411	477	25	,	,	PUNCT
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eurjchem-411	477	27	.	.	PUNCT
eurjchem-411	478	1	[	[	X
eurjchem-411	478	2	36	36	NUM
eurjchem-411	478	3	]	]	PUNCT
eurjchem-411	478	4	.	.	PUNCT
eurjchem-411	479	1	rollas	rollas	PROPN
eurjchem-411	479	2	,	,	PUNCT
eurjchem-411	479	3	s.	s.	PROPN
eurjchem-411	479	4	;	;	PUNCT
eurjchem-411	479	5	kalyoncuoğlu	kalyoncuoğlu	NOUN
eurjchem-411	479	6	,	,	PUNCT
eurjchem-411	479	7	n.	n.	NOUN
eurjchem-411	479	8	;	;	PUNCT
eurjchem-411	479	9	sur‐altiner	sur‐altiner	NUM
eurjchem-411	479	10	,	,	PUNCT
eurjchem-411	479	11	d.	d.	PROPN
eurjchem-411	479	12	;	;	PUNCT
eurjchem-411	479	13	yeğenoğlu	yeğenoğlu	ADJ
eurjchem-411	479	14	,	,	PUNCT
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eurjchem-411	479	18	,	,	PUNCT
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eurjchem-411	479	20	,	,	PUNCT
eurjchem-411	479	21	308‐309	308‐309	NUM
eurjchem-411	479	22	.	.	PUNCT
eurjchem-411	480	1	[	[	X
eurjchem-411	480	2	37	37	NUM
eurjchem-411	480	3	]	]	PUNCT
eurjchem-411	480	4	.	.	PUNCT
eurjchem-411	481	1	cho	cho	PROPN
eurjchem-411	481	2	,	,	PUNCT
eurjchem-411	481	3	n.	n.	PROPN
eurjchem-411	481	4	s.	s.	PROPN
eurjchem-411	481	5	;	;	PUNCT
eurjchem-411	481	6	kim	kim	PROPN
eurjchem-411	481	7	,	,	PUNCT
eurjchem-411	481	8	g.	g.	PROPN
eurjchem-411	481	9	n.	n.	PROPN
eurjchem-411	481	10	;	;	PUNCT
eurjchem-411	481	11	parkanyi	parkanyi	PROPN
eurjchem-411	481	12	,	,	PUNCT
eurjchem-411	481	13	c.	c.	PROPN
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eurjchem-411	481	17	.	.	PUNCT
eurjchem-411	482	1	1993	1993	NUM
eurjchem-411	482	2	,	,	PUNCT
eurjchem-411	482	3	30	30	NUM
eurjchem-411	482	4	,	,	PUNCT
eurjchem-411	482	5	397‐	397‐	NUM
eurjchem-411	482	6	401	401	NUM
eurjchem-411	482	7	.	.	PUNCT
eurjchem-411	483	1	[	[	X
eurjchem-411	483	2	38	38	NUM
eurjchem-411	483	3	]	]	PUNCT
eurjchem-411	483	4	.	.	PUNCT
eurjchem-411	483	5	elmoghayar	elmoghayar	PROPN
eurjchem-411	483	6	,	,	PUNCT
eurjchem-411	483	7	m.	m.	PROPN
eurjchem-411	483	8	r.	r.	PROPN
eurjchem-411	483	9	h.	h.	PROPN
eurjchem-411	483	10	;	;	PUNCT
eurjchem-411	483	11	ghali	ghali	PROPN
eurjchem-411	483	12	,	,	PUNCT
eurjchem-411	483	13	e.	e.	PROPN
eurjchem-411	483	14	a.	a.	PROPN
eurjchem-411	483	15	;	;	PUNCT
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eurjchem-411	483	17	,	,	PUNCT
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eurjchem-411	483	19	m.	m.	NOUN
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eurjchem-411	483	21	;	;	PUNCT
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eurjchem-411	483	23	,	,	PUNCT
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eurjchem-411	483	28	.	.	PROPN
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eurjchem-411	483	30	.	.	PUNCT
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eurjchem-411	484	2	,	,	PUNCT
eurjchem-411	484	3	10	10	NUM
eurjchem-411	484	4	,	,	PUNCT
eurjchem-411	484	5	1962‐1968	1962‐1968	NUM
eurjchem-411	484	6	.	.	PUNCT
eurjchem-411	485	1	[	[	X
eurjchem-411	485	2	39	39	NUM
eurjchem-411	485	3	]	]	PUNCT
eurjchem-411	485	4	.	.	PUNCT
eurjchem-411	486	1	bartels‐keith	bartels‐keith	PROPN
eurjchem-411	486	2	,	,	PUNCT
eurjchem-411	486	3	j.	j.	PROPN
eurjchem-411	486	4	r.	r.	PROPN
eurjchem-411	486	5	;	;	PUNCT
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eurjchem-411	486	7	,	,	PUNCT
eurjchem-411	486	8	m.	m.	NOUN
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eurjchem-411	486	10	;	;	PUNCT
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eurjchem-411	486	13	j.	j.	PROPN
eurjchem-411	486	14	m.	m.	PROPN
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eurjchem-411	486	17	.	.	PUNCT
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eurjchem-411	486	19	.	.	PUNCT
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eurjchem-411	487	2	,	,	PUNCT
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eurjchem-411	487	4	,	,	PUNCT
eurjchem-411	487	5	3725‐3731	3725‐3731	NUM
eurjchem-411	487	6	.	.	PUNCT
eurjchem-411	488	1	[	[	X
eurjchem-411	488	2	40	40	NUM
eurjchem-411	488	3	]	]	PUNCT
eurjchem-411	488	4	.	.	PUNCT
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eurjchem-411	489	2	,	,	PUNCT
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eurjchem-411	489	4	;	;	PUNCT
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eurjchem-411	489	6	,	,	PUNCT
eurjchem-411	489	7	f.	f.	PROPN
eurjchem-411	489	8	;	;	PUNCT
eurjchem-411	489	9	tringali	tringali	PROPN
eurjchem-411	489	10	,	,	PUNCT
eurjchem-411	489	11	c.	c.	PROPN
eurjchem-411	489	12	j.	j.	PROPN
eurjchem-411	489	13	org	org	PROPN
eurjchem-411	489	14	.	.	PUNCT
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eurjchem-411	489	16	.	.	PUNCT
eurjchem-411	490	1	1987	1987	NUM
eurjchem-411	490	2	,	,	PUNCT
eurjchem-411	490	3	52	52	NUM
eurjchem-411	490	4	,	,	PUNCT
eurjchem-411	490	5	405‐412	405‐412	NUM
eurjchem-411	490	6	.	.	PUNCT
eurjchem-411	491	1	[	[	X
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eurjchem-411	491	3	]	]	SYM
eurjchem-411	491	4	.	.	PUNCT
eurjchem-411	492	1	ram	ram	PROPN
eurjchem-411	492	2	,	,	PUNCT
eurjchem-411	492	3	v.	v.	PROPN
eurjchem-411	492	4	j.	j.	PROPN
eurjchem-411	492	5	;	;	PUNCT
eurjchem-411	492	6	mishra	mishra	PROPN
eurjchem-411	492	7	,	,	PUNCT
eurjchem-411	492	8	l.	l.	PROPN
eurjchem-411	492	9	;	;	PUNCT
eurjchem-411	492	10	pandey	pandey	PROPN
eurjchem-411	492	11	,	,	PUNCT
eurjchem-411	492	12	n.	n.	PROPN
eurjchem-411	492	13	h.	h.	PROPN
eurjchem-411	492	14	;	;	PUNCT
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eurjchem-411	492	16	,	,	PUNCT
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eurjchem-411	492	18	s.	s.	PROPN
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eurjchem-411	492	22	.	.	PUNCT
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eurjchem-411	493	2	,	,	PUNCT
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eurjchem-411	493	4	,	,	PUNCT
eurjchem-411	493	5	351‐355	351‐355	NUM
eurjchem-411	493	6	.	.	PUNCT
eurjchem-411	494	1	[	[	X
eurjchem-411	494	2	42	42	NUM
eurjchem-411	494	3	]	]	PUNCT
eurjchem-411	494	4	.	.	PUNCT
eurjchem-411	495	1	ergenc	ergenc	PROPN
eurjchem-411	495	2	,	,	PUNCT
eurjchem-411	495	3	n.	n.	NOUN
eurjchem-411	495	4	;	;	PUNCT
eurjchem-411	495	5	ilhan	ilhan	PROPN
eurjchem-411	495	6	,	,	PUNCT
eurjchem-411	495	7	e.	e.	PROPN
eurjchem-411	495	8	;	;	PUNCT
eurjchem-411	495	9	ötük	ötük	NOUN
eurjchem-411	495	10	,	,	PUNCT
eurjchem-411	495	11	g.	g.	PROPN
eurjchem-411	495	12	pharmazie	pharmazie	PROPN
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eurjchem-411	495	14	,	,	PUNCT
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eurjchem-411	495	16	,	,	PUNCT
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eurjchem-411	495	18	.	.	PUNCT
eurjchem-411	496	1	[	[	X
eurjchem-411	496	2	43	43	NUM
eurjchem-411	496	3	]	]	PUNCT
eurjchem-411	496	4	.	.	PUNCT
eurjchem-411	497	1	shaker	shaker	PROPN
eurjchem-411	497	2	,	,	PUNCT
eurjchem-411	497	3	r.	r.	PROPN
eurjchem-411	497	4	m.	m.	PROPN
eurjchem-411	497	5	;	;	PUNCT
eurjchem-411	497	6	mahmoud	mahmoud	PROPN
eurjchem-411	497	7	,	,	PUNCT
eurjchem-411	497	8	a.	a.	PROPN
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eurjchem-411	497	10	;	;	PUNCT
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eurjchem-411	497	12	,	,	PUNCT
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eurjchem-411	497	20	.	.	PUNCT
eurjchem-411	498	1	elem	elem	NOUN
eurjchem-411	498	2	.	.	PUNCT
eurjchem-411	499	1	2005	2005	NUM
eurjchem-411	499	2	,	,	PUNCT
eurjchem-411	499	3	180	180	NUM
eurjchem-411	499	4	,	,	PUNCT
eurjchem-411	499	5	397‐406	397‐406	NUM
eurjchem-411	499	6	.	.	PUNCT
eurjchem-411	500	1	[	[	X
eurjchem-411	500	2	44	44	NUM
eurjchem-411	500	3	]	]	PUNCT
eurjchem-411	500	4	.	.	PUNCT
eurjchem-411	501	1	sandström	sandström	PROPN
eurjchem-411	501	2	,	,	PUNCT
eurjchem-411	501	3	j.	j.	PROPN
eurjchem-411	501	4	;	;	PUNCT
eurjchem-411	501	5	wennerbeck	wennerbeck	PROPN
eurjchem-411	501	6	,	,	PUNCT
eurjchem-411	501	7	i.	i.	PROPN
eurjchem-411	501	8	acta	acta	PROPN
eurjchem-411	501	9	chem	chem	PROPN
eurjchem-411	501	10	.	.	PUNCT
eurjchem-411	502	1	scand	scand	PROPN
eurjchem-411	502	2	.	.	PROPN
eurjchem-411	503	1	1966	1966	NUM
eurjchem-411	503	2	,	,	PUNCT
eurjchem-411	503	3	20	20	NUM
eurjchem-411	503	4	,	,	PUNCT
eurjchem-411	503	5	57‐71	57‐71	NUM
eurjchem-411	503	6	.	.	PUNCT
eurjchem-411	504	1	[	[	X
eurjchem-411	504	2	45	45	NUM
eurjchem-411	504	3	]	]	PUNCT
eurjchem-411	504	4	.	.	PUNCT
eurjchem-411	505	1	still	still	ADV
eurjchem-411	505	2	,	,	PUNCT
eurjchem-411	505	3	i.	i.	PROPN
eurjchem-411	505	4	w.	w.	PROPN
eurjchem-411	505	5	j.	j.	PROPN
eurjchem-411	505	6	;	;	PUNCT
eurjchem-411	505	7	plavac	plavac	PROPN
eurjchem-411	505	8	,	,	PUNCT
eurjchem-411	505	9	n.	n.	NOUN
eurjchem-411	505	10	;	;	PUNCT
eurjchem-411	505	11	mckinnon	mckinnon	PROPN
eurjchem-411	505	12	,	,	PUNCT
eurjchem-411	505	13	d.	d.	PROPN
eurjchem-411	505	14	m.	m.	PROPN
eurjchem-411	505	15	;	;	PUNCT
eurjchem-411	505	16	chauhan	chauhan	PROPN
eurjchem-411	505	17	,	,	PUNCT
eurjchem-411	505	18	m.	m.	PROPN
eurjchem-411	505	19	s.	s.	PROPN
eurjchem-411	505	20	can	can	AUX
eurjchem-411	505	21	.	.	PUNCT
eurjchem-411	506	1	j.	j.	PROPN
eurjchem-411	506	2	chem	chem	PROPN
eurjchem-411	506	3	.	.	PUNCT
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eurjchem-411	507	2	,	,	PUNCT
eurjchem-411	507	3	54	54	NUM
eurjchem-411	507	4	,	,	PUNCT
eurjchem-411	507	5	280‐289	280‐289	NUM
eurjchem-411	507	6	.	.	PUNCT
eurjchem-411	508	1	[	[	X
eurjchem-411	508	2	46	46	NUM
eurjchem-411	508	3	]	]	PUNCT
eurjchem-411	508	4	.	.	PUNCT
eurjchem-411	509	1	still	still	ADV
eurjchem-411	509	2	,	,	PUNCT
eurjchem-411	509	3	i.	i.	PROPN
eurjchem-411	509	4	w.	w.	PROPN
eurjchem-411	509	5	j.	j.	PROPN
eurjchem-411	509	6	;	;	PUNCT
eurjchem-411	509	7	plavac	plavac	PROPN
eurjchem-411	509	8	,	,	PUNCT
eurjchem-411	509	9	n.	n.	NOUN
eurjchem-411	509	10	;	;	PUNCT
eurjchem-411	509	11	mckinnon	mckinnon	PROPN
eurjchem-411	509	12	,	,	PUNCT
eurjchem-411	509	13	d.	d.	PROPN
eurjchem-411	509	14	m.	m.	PROPN
eurjchem-411	509	15	;	;	PUNCT
eurjchem-411	509	16	chauhan	chauhan	PROPN
eurjchem-411	509	17	,	,	PUNCT
eurjchem-411	509	18	m.	m.	PROPN
eurjchem-411	509	19	s.	s.	PROPN
eurjchem-411	509	20	can	can	AUX
eurjchem-411	509	21	.	.	PUNCT
eurjchem-411	510	1	j.	j.	PROPN
eurjchem-411	510	2	chem	chem	PROPN
eurjchem-411	510	3	.	.	PUNCT
eurjchem-411	511	1	1976	1976	NUM
eurjchem-411	511	2	,	,	PUNCT
eurjchem-411	511	3	54	54	NUM
eurjchem-411	511	4	,	,	PUNCT
eurjchem-411	511	5	1660‐1664	1660‐1664	NUM
eurjchem-411	511	6	.	.	PUNCT
eurjchem-411	512	1	[	[	X
eurjchem-411	512	2	47	47	NUM
eurjchem-411	512	3	]	]	PUNCT
eurjchem-411	512	4	.	.	PUNCT
eurjchem-411	513	1	el‐essawy	el‐essawy	PROPN
eurjchem-411	513	2	,	,	PUNCT
eurjchem-411	513	3	f.	f.	PROPN
eurjchem-411	513	4	a.	a.	PROPN
eurjchem-411	513	5	;	;	PUNCT
eurjchem-411	513	6	khattab	khattab	NOUN
eurjchem-411	513	7	,	,	PUNCT
eurjchem-411	513	8	a.	a.	PROPN
eurjchem-411	513	9	f.	f.	PROPN
eurjchem-411	513	10	;	;	PUNCT
eurjchem-411	513	11	abdel‐rahman	abdel‐rahman	NOUN
eurjchem-411	513	12	,	,	PUNCT
eurjchem-411	513	13	a.	a.	PROPN
eurjchem-411	513	14	a.	a.	PROPN
eurjchem-411	513	15	h.	h.	PROPN
eurjchem-411	513	16	monatsh	monatsh	PROPN
eurjchem-411	513	17	.	.	PUNCT
eurjchem-411	513	18	chem	chem	PROPN
eurjchem-411	513	19	.	.	PUNCT
eurjchem-411	514	1	2007	2007	NUM
eurjchem-411	514	2	,	,	PUNCT
eurjchem-411	514	3	138	138	NUM
eurjchem-411	514	4	,	,	PUNCT
eurjchem-411	514	5	777‐785	777‐785	NUM
eurjchem-411	514	6	.	.	PUNCT
eurjchem-411	515	1	[	[	X
eurjchem-411	515	2	48	48	NUM
eurjchem-411	515	3	]	]	PUNCT
eurjchem-411	515	4	.	.	PUNCT
eurjchem-411	516	1	nawrocka	nawrocka	NOUN
eurjchem-411	516	2	,	,	PUNCT
eurjchem-411	516	3	w.	w.	PROPN
eurjchem-411	516	4	;	;	PUNCT
eurjchem-411	516	5	zimecki	zimecki	PROPN
eurjchem-411	516	6	,	,	PUNCT
eurjchem-411	516	7	m.	m.	NOUN
eurjchem-411	516	8	arch	arch	NOUN
eurjchem-411	516	9	.	.	PUNCT
eurjchem-411	517	1	pharm	pharm	NOUN
eurjchem-411	517	2	.	.	PUNCT
eurjchem-411	518	1	pharm	pharm	PROPN
eurjchem-411	518	2	.	.	PUNCT
eurjchem-411	519	1	med	med	PROPN
eurjchem-411	519	2	.	.	PROPN
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eurjchem-411	519	4	.	.	PUNCT
eurjchem-411	520	1	1997	1997	NUM
eurjchem-411	520	2	,	,	PUNCT
eurjchem-411	520	3	330	330	NUM
eurjchem-411	520	4	,	,	PUNCT
eurjchem-411	520	5	399‐405	399‐405	NUM
eurjchem-411	520	6	.	.	PUNCT
eurjchem-411	521	1	[	[	X
eurjchem-411	521	2	49	49	NUM
eurjchem-411	521	3	]	]	PUNCT
eurjchem-411	521	4	.	.	PUNCT
eurjchem-411	522	1	britsun	britsun	PROPN
eurjchem-411	522	2	,	,	PUNCT
eurjchem-411	522	3	v.	v.	ADP
eurjchem-411	522	4	n.	n.	NOUN
eurjchem-411	522	5	;	;	PUNCT
eurjchem-411	522	6	esipenko	esipenko	ADJ
eurjchem-411	522	7	,	,	PUNCT
eurjchem-411	522	8	a.	a.	NOUN
eurjchem-411	522	9	n.	n.	NOUN
eurjchem-411	522	10	;	;	PUNCT
eurjchem-411	522	11	kudryavtsev	kudryavtsev	PROPN
eurjchem-411	522	12	,	,	PUNCT
eurjchem-411	522	13	a.	a.	NOUN
eurjchem-411	522	14	a.	a.	NOUN
eurjchem-411	522	15	;	;	PUNCT
eurjchem-411	522	16	lozinskii	lozinskii	PROPN
eurjchem-411	522	17	,	,	PUNCT
eurjchem-411	522	18	m.	m.	NOUN
eurjchem-411	522	19	o.	o.	PROPN
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eurjchem-411	522	21	.	.	PUNCT
eurjchem-411	523	1	j.	j.	PROPN
eurjchem-411	523	2	org	org	PROPN
eurjchem-411	523	3	.	.	PUNCT
eurjchem-411	523	4	chem	chem	PROPN
eurjchem-411	523	5	.	.	PUNCT
eurjchem-411	524	1	2005	2005	NUM
eurjchem-411	524	2	,	,	PUNCT
eurjchem-411	524	3	41	41	NUM
eurjchem-411	524	4	,	,	PUNCT
eurjchem-411	524	5	1333‐1336	1333‐1336	NOUN
eurjchem-411	524	6	.	.	PUNCT
eurjchem-411	525	1	[	[	X
eurjchem-411	525	2	50	50	NUM
eurjchem-411	525	3	]	]	PUNCT
eurjchem-411	525	4	.	.	PUNCT
eurjchem-411	526	1	gogol	gogol	NOUN
eurjchem-411	526	2	,	,	PUNCT
eurjchem-411	526	3	p.	p.	PROPN
eurjchem-411	526	4	c.	c.	PROPN
eurjchem-411	526	5	;	;	PUNCT
eurjchem-411	526	6	kataky	kataky	PROPN
eurjchem-411	526	7	,	,	PUNCT
eurjchem-411	526	8	j.	j.	PROPN
eurjchem-411	526	9	c.	c.	PROPN
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eurjchem-411	526	13	,	,	PUNCT
eurjchem-411	526	14	31	31	NUM
eurjchem-411	526	15	,	,	PUNCT
eurjchem-411	526	16	2147‐2152	2147‐2152	NUM
eurjchem-411	526	17	.	.	PUNCT
eurjchem-411	527	1	[	[	X
eurjchem-411	527	2	51	51	NUM
eurjchem-411	527	3	]	]	PUNCT
eurjchem-411	527	4	.	.	PUNCT
eurjchem-411	527	5	ilango	ilango	PROPN
eurjchem-411	527	6	,	,	PUNCT
eurjchem-411	527	7	k.	k.	PROPN
eurjchem-411	527	8	;	;	PUNCT
eurjchem-411	527	9	valentina	valentina	PROPN
eurjchem-411	527	10	,	,	PUNCT
eurjchem-411	527	11	p.	p.	PROPN
eurjchem-411	527	12	eur	eur	PROPN
eurjchem-411	527	13	.	.	PUNCT
eurjchem-411	528	1	j.	j.	PROPN
eurjchem-411	528	2	chem	chem	PROPN
eurjchem-411	528	3	.	.	PUNCT
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eurjchem-411	529	2	,	,	PUNCT
eurjchem-411	529	3	1	1	NUM
eurjchem-411	529	4	,	,	PUNCT
eurjchem-411	529	5	50‐53	50‐53	NOUN
eurjchem-411	529	6	.	.	PUNCT
eurjchem-411	530	1	[	[	X
eurjchem-411	530	2	52	52	NUM
eurjchem-411	530	3	]	]	PUNCT
eurjchem-411	530	4	.	.	PUNCT
eurjchem-411	531	1	golgolab	golgolab	PROPN
eurjchem-411	531	2	,	,	PUNCT
eurjchem-411	531	3	h.	h.	PROPN
eurjchem-411	531	4	;	;	PUNCT
eurjchem-411	531	5	lalezari	lalezari	X
eurjchem-411	531	6	,	,	PUNCT
eurjchem-411	531	7	i.	i.	NOUN
eurjchem-411	531	8	;	;	PUNCT
eurjchem-411	531	9	hosseini‐gohari	hosseini‐gohari	PROPN
eurjchem-411	531	10	,	,	PUNCT
eurjchem-411	531	11	l.	l.	PROPN
eurjchem-411	531	12	j.	j.	PROPN
eurjchem-411	531	13	heterocyclic	heterocyclic	PROPN
eurjchem-411	531	14	chem	chem	PROPN
eurjchem-411	531	15	.	.	PUNCT
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eurjchem-411	532	2	,	,	PUNCT
eurjchem-411	532	3	10	10	NUM
eurjchem-411	532	4	,	,	PUNCT
eurjchem-411	532	5	387‐390	387‐390	NUM
eurjchem-411	532	6	.	.	PUNCT
eurjchem-411	533	1	[	[	X
eurjchem-411	533	2	53	53	NUM
eurjchem-411	533	3	]	]	PUNCT
eurjchem-411	533	4	.	.	PUNCT
eurjchem-411	534	1	ibrahim	ibrahim	PROPN
eurjchem-411	534	2	,	,	PUNCT
eurjchem-411	534	3	d.	d.	PROPN
eurjchem-411	534	4	a.	a.	PROPN
eurjchem-411	534	5	eur	eur	PROPN
eurjchem-411	534	6	.	.	PUNCT
eurjchem-411	535	1	j.	j.	PROPN
eurjchem-411	535	2	med	med	PROPN
eurjchem-411	535	3	.	.	PROPN
eurjchem-411	535	4	chem	chem	PROPN
eurjchem-411	535	5	.	.	PUNCT
eurjchem-411	536	1	2009	2009	NUM
eurjchem-411	536	2	,	,	PUNCT
eurjchem-411	536	3	44	44	NUM
eurjchem-411	536	4	,	,	PUNCT
eurjchem-411	536	5	2776‐2781	2776‐2781	NUM
eurjchem-411	536	6	.	.	PUNCT
eurjchem-411	537	1	[	[	X
eurjchem-411	537	2	54	54	NUM
eurjchem-411	537	3	]	]	PUNCT
eurjchem-411	537	4	.	.	PUNCT
eurjchem-411	538	1	anwar	anwar	PROPN
eurjchem-411	538	2	,	,	PUNCT
eurjchem-411	538	3	h.	h.	PROPN
eurjchem-411	538	4	f.	f.	PROPN
eurjchem-411	538	5	;	;	PUNCT
eurjchem-411	538	6	metwally	metwally	ADV
eurjchem-411	538	7	,	,	PUNCT
eurjchem-411	538	8	n.	n.	PROPN
eurjchem-411	538	9	h.	h.	PROPN
eurjchem-411	538	10	;	;	PUNCT
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eurjchem-411	538	12	,	,	PUNCT
eurjchem-411	538	13	h.	h.	PROPN
eurjchem-411	538	14	;	;	PUNCT
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eurjchem-411	538	16	,	,	PUNCT
eurjchem-411	538	17	m.	m.	NOUN
eurjchem-411	538	18	h.	h.	PROPN
eurjchem-411	538	19	j.	j.	PROPN
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eurjchem-411	538	21	.	.	PUNCT
eurjchem-411	539	1	research	research	NOUN
eurjchem-411	539	2	2005	2005	NUM
eurjchem-411	539	3	,	,	PUNCT
eurjchem-411	539	4	1	1	NUM
eurjchem-411	539	5	,	,	PUNCT
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eurjchem-411	539	7	.	.	PUNCT
eurjchem-411	540	1	[	[	X
eurjchem-411	540	2	55	55	NUM
eurjchem-411	540	3	]	]	PUNCT
eurjchem-411	540	4	.	.	PUNCT
eurjchem-411	541	1	vainilavicius	vainilavicius	NOUN
eurjchem-411	541	2	,	,	PUNCT
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eurjchem-411	541	4	;	;	PUNCT
eurjchem-411	541	5	smicius	smicius	PROPN
eurjchem-411	541	6	,	,	PUNCT
eurjchem-411	541	7	r.	r.	PROPN
eurjchem-411	541	8	;	;	PUNCT
eurjchem-411	541	9	jakubkiene	jakubkiene	NOUN
eurjchem-411	541	10	,	,	PUNCT
eurjchem-411	541	11	v.	v.	ADV
eurjchem-411	541	12	;	;	PUNCT
eurjchem-411	541	13	tumkevicius	tumkevicius	NOUN
eurjchem-411	541	14	,	,	PUNCT
eurjchem-411	541	15	s.	s.	PROPN
eurjchem-411	541	16	monatsh	monatsh	PROPN
eurjchem-411	541	17	.	.	PUNCT
eurjchem-411	542	1	chem	chem	PROPN
eurjchem-411	542	2	.	.	PUNCT
eurjchem-411	543	1	2001	2001	NUM
eurjchem-411	543	2	,	,	PUNCT
eurjchem-411	543	3	132	132	NUM
eurjchem-411	543	4	,	,	PUNCT
eurjchem-411	543	5	825‐831	825‐831	NUM
eurjchem-411	543	6	.	.	PUNCT
eurjchem-411	544	1	[	[	X
eurjchem-411	544	2	56	56	NUM
eurjchem-411	544	3	]	]	SYM
eurjchem-411	544	4	.	.	PUNCT
eurjchem-411	544	5	elkholy	elkholy	ADJ
eurjchem-411	544	6	,	,	PUNCT
eurjchem-411	544	7	y.	y.	PROPN
eurjchem-411	544	8	m.	m.	PROPN
eurjchem-411	544	9	;	;	PUNCT
eurjchem-411	544	10	ali	ali	PROPN
eurjchem-411	544	11	,	,	PUNCT
eurjchem-411	544	12	k.	k.	PROPN
eurjchem-411	544	13	a.	a.	PROPN
eurjchem-411	544	14	;	;	PUNCT
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eurjchem-411	544	16	,	,	PUNCT
eurjchem-411	544	17	a.	a.	NOUN
eurjchem-411	544	18	m.	m.	PROPN
eurjchem-411	544	19	j.	j.	PROPN
eurjchem-411	544	20	heterocyclic	heterocyclic	PROPN
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eurjchem-411	544	22	.	.	PUNCT
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eurjchem-411	545	2	,	,	PUNCT
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eurjchem-411	545	4	,	,	PUNCT
eurjchem-411	545	5	1183‐1188	1183‐1188	NUM
eurjchem-411	545	6	.	.	PUNCT
eurjchem-411	546	1	[	[	X
eurjchem-411	546	2	57	57	NUM
eurjchem-411	546	3	]	]	PUNCT
eurjchem-411	546	4	.	.	PUNCT
eurjchem-411	547	1	almasirad	almasirad	PROPN
eurjchem-411	547	2	,	,	PUNCT
eurjchem-411	547	3	a.	a.	PROPN
eurjchem-411	547	4	;	;	PUNCT
eurjchem-411	547	5	vousooghi	vousooghi	PROPN
eurjchem-411	547	6	,	,	PUNCT
eurjchem-411	547	7	n.	n.	NOUN
eurjchem-411	547	8	;	;	PUNCT
eurjchem-411	547	9	tabatabai	tabatabai	PROPN
eurjchem-411	547	10	,	,	PUNCT
eurjchem-411	547	11	s.	s.	PROPN
eurjchem-411	547	12	a.	a.	PROPN
eurjchem-411	547	13	;	;	PUNCT
eurjchem-411	548	1	kebriaeezadeh	kebriaeezadeh	PROPN
eurjchem-411	548	2	,	,	PUNCT
eurjchem-411	548	3	a.	a.	NOUN
eurjchem-411	548	4	;	;	PUNCT
eurjchem-411	548	5	shafiee	shafiee	PROPN
eurjchem-411	548	6	,	,	PUNCT
eurjchem-411	548	7	a.	a.	PROPN
eurjchem-411	548	8	acta	acta	PROPN
eurjchem-411	548	9	chim	chim	PROPN
eurjchem-411	548	10	.	.	PUNCT
eurjchem-411	548	11	slov	slov	PROPN
eurjchem-411	548	12	.	.	PUNCT
eurjchem-411	549	1	2007	2007	NUM
eurjchem-411	549	2	,	,	PUNCT
eurjchem-411	549	3	54	54	NUM
eurjchem-411	549	4	,	,	PUNCT
eurjchem-411	549	5	317‐324	317‐324	NUM
eurjchem-411	549	6	.	.	PUNCT
eurjchem-411	550	1	[	[	X
eurjchem-411	550	2	58	58	NUM
eurjchem-411	550	3	]	]	PUNCT
eurjchem-411	550	4	.	.	PUNCT
eurjchem-411	551	1	salyers	salyer	NOUN
eurjchem-411	551	2	,	,	PUNCT
eurjchem-411	551	3	a.	a.	NOUN
eurjchem-411	551	4	a.	a.	NOUN
eurjchem-411	551	5	;	;	PUNCT
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eurjchem-411	551	7	,	,	PUNCT
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eurjchem-411	551	10	bacterial	bacterial	PROPN
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eurjchem-411	551	12	:	:	PUNCT
eurjchem-411	551	13	a	a	DET
eurjchem-411	551	14	molecular	molecular	ADJ
eurjchem-411	551	15	approach	approach	NOUN
eurjchem-411	551	16	;	;	PUNCT
eurjchem-411	551	17	second	second	ADJ
eurjchem-411	551	18	ed	ed	NOUN
eurjchem-411	551	19	.	.	PUNCT
eurjchem-411	551	20	,	,	PUNCT
eurjchem-411	551	21	asm	asm	NOUN
eurjchem-411	551	22	press	press	NOUN
eurjchem-411	551	23	:	:	PUNCT
eurjchem-411	551	24	washington	washington	PROPN
eurjchem-411	551	25	,	,	PUNCT
eurjchem-411	551	26	d.	d.	PROPN
eurjchem-411	551	27	c.	c.	PROPN
eurjchem-411	551	28	,	,	PUNCT
eurjchem-411	551	29	usa	usa	PROPN
eurjchem-411	551	30	,	,	PUNCT
eurjchem-411	551	31	2002	2002	NUM
eurjchem-411	551	32	,	,	PUNCT
eurjchem-411	551	33	pp	pp	ADJ
eurjchem-411	551	34	.	.	PUNCT
eurjchem-411	552	1	539	539	X
eurjchem-411	552	2	.	.	PUNCT
eurjchem-411	553	1	isbn	isbn	PROPN
eurjchem-411	553	2	1‐55581‐171‐x	1‐55581‐171‐x	NUM
eurjchem-411	553	3	.	.	PUNCT
eurjchem-411	554	1	[	[	X
eurjchem-411	554	2	59	59	NUM
eurjchem-411	554	3	]	]	PUNCT
eurjchem-411	554	4	.	.	PUNCT
eurjchem-411	555	1	curran	curran	PROPN
eurjchem-411	555	2	,	,	PUNCT
eurjchem-411	555	3	j.	j.	PROPN
eurjchem-411	555	4	p.	p.	PROPN
eurjchem-411	555	5	;	;	PUNCT
eurjchem-411	555	6	al‐salihi	al‐salihi	PROPN
eurjchem-411	555	7	,	,	PUNCT
eurjchem-411	555	8	f.	f.	PROPN
eurjchem-411	555	9	l.	l.	PROPN
eurjchem-411	555	10	pediatrics	pediatric	NOUN
eurjchem-411	555	11	1980	1980	NUM
eurjchem-411	555	12	,	,	PUNCT
eurjchem-411	555	13	66	66	NUM
eurjchem-411	555	14	,	,	PUNCT
eurjchem-411	555	15	285‐290	285‐290	NUM
eurjchem-411	555	16	.	.	PUNCT
eurjchem-411	556	1	[	[	X
eurjchem-411	556	2	60	60	NUM
eurjchem-411	556	3	]	]	PUNCT
eurjchem-411	556	4	.	.	PUNCT
eurjchem-411	557	1	saraceno	saraceno	PROPN
eurjchem-411	557	2	,	,	PUNCT
eurjchem-411	557	3	j.	j.	PROPN
eurjchem-411	557	4	l.	l.	PROPN
eurjchem-411	557	5	;	;	PUNCT
eurjchem-411	557	6	phelps	phelps	PROPN
eurjchem-411	557	7	,	,	PUNCT
eurjchem-411	557	8	d.	d.	PROPN
eurjchem-411	557	9	t.	t.	PROPN
eurjchem-411	557	10	;	;	PUNCT
eurjchem-411	557	11	ferro	ferro	NOUN
eurjchem-411	557	12	,	,	PUNCT
eurjchem-411	557	13	t.	t.	PROPN
eurjchem-411	557	14	j.	j.	PROPN
eurjchem-411	557	15	;	;	PUNCT
eurjchem-411	557	16	futerfas	futerfas	PROPN
eurjchem-411	557	17	,	,	PUNCT
eurjchem-411	557	18	r.	r.	PROPN
eurjchem-411	557	19	;	;	PUNCT
eurjchem-411	557	20	schwartz	schwartz	PROPN
eurjchem-411	557	21	,	,	PUNCT
eurjchem-411	557	22	d.	d.	PROPN
eurjchem-411	557	23	b.	b.	PROPN
eurjchem-411	557	24	chest	chest	PROPN
eurjchem-411	557	25	1997	1997	NUM
eurjchem-411	557	26	,	,	PUNCT
eurjchem-411	557	27	112	112	NUM
eurjchem-411	557	28	,	,	PUNCT
eurjchem-411	557	29	541‐548	541‐548	NUM
eurjchem-411	557	30	.	.	PUNCT
eurjchem-411	558	1	[	[	X
eurjchem-411	558	2	61	61	NUM
eurjchem-411	558	3	]	]	PUNCT
eurjchem-411	558	4	.	.	PUNCT
eurjchem-411	559	1	cowan	cowan	PROPN
eurjchem-411	559	2	,	,	PUNCT
eurjchem-411	559	3	m.	m.	NOUN
eurjchem-411	559	4	m.	m.	PROPN
eurjchem-411	559	5	clin	clin	PROPN
eurjchem-411	559	6	.	.	PUNCT
eurjchem-411	560	1	microbiol	microbiol	PROPN
eurjchem-411	560	2	.	.	PUNCT
eurjchem-411	561	1	rev	rev	PROPN
eurjchem-411	561	2	.	.	PROPN
eurjchem-411	561	3	1999	1999	NUM
eurjchem-411	561	4	,	,	PUNCT
eurjchem-411	561	5	12	12	NUM
eurjchem-411	561	6	,	,	PUNCT
eurjchem-411	561	7	564‐582	564‐582	NUM
eurjchem-411	561	8	.	.	PUNCT
eurjchem-411	562	1	[	[	X
eurjchem-411	562	2	62	62	NUM
eurjchem-411	562	3	]	]	PUNCT
eurjchem-411	562	4	.	.	PUNCT
eurjchem-411	562	5	bozkurt	bozkurt	PROPN
eurjchem-411	562	6	,	,	PUNCT
eurjchem-411	562	7	m.	m.	PROPN
eurjchem-411	562	8	k.	k.	PROPN
eurjchem-411	562	9	;	;	PUNCT
eurjchem-411	562	10	ozçelik	ozçelik	PROPN
eurjchem-411	562	11	,	,	PUNCT
eurjchem-411	562	12	t.	t.	PROPN
eurjchem-411	562	13	;	;	PUNCT
eurjchem-411	562	14	saydam	saydam	PROPN
eurjchem-411	562	15	,	,	PUNCT
eurjchem-411	562	16	l.	l.	PROPN
eurjchem-411	562	17	;	;	PUNCT
eurjchem-411	562	18	kutluay	kutluay	PROPN
eurjchem-411	562	19	,	,	PUNCT
eurjchem-411	562	20	l.	l.	PROPN
eurjchem-411	562	21	kulak	kulak	PROPN
eurjchem-411	562	22	burun	burun	PROPN
eurjchem-411	562	23	bogaz	bogaz	PROPN
eurjchem-411	562	24	ihtis	ihtis	PROPN
eurjchem-411	562	25	.	.	PUNCT
eurjchem-411	563	1	derg	derg	PROPN
eurjchem-411	563	2	.	.	PUNCT
eurjchem-411	564	1	2008	2008	NUM
eurjchem-411	564	2	,	,	PUNCT
eurjchem-411	564	3	18	18	NUM
eurjchem-411	564	4	,	,	PUNCT
eurjchem-411	564	5	53‐55	53‐55	NUM
eurjchem-411	564	6	.	.	PUNCT
eurjchem-411	565	1	[	[	X
eurjchem-411	565	2	63	63	NUM
eurjchem-411	565	3	]	]	PUNCT
eurjchem-411	565	4	.	.	PUNCT
eurjchem-411	565	5	di	di	PROPN
eurjchem-411	565	6	santo	santo	PROPN
eurjchem-411	565	7	,	,	PUNCT
eurjchem-411	565	8	r.	r.	PROPN
eurjchem-411	565	9	;	;	PUNCT
eurjchem-411	565	10	tafi	tafi	PROPN
eurjchem-411	565	11	,	,	PUNCT
eurjchem-411	565	12	a.	a.	NOUN
eurjchem-411	565	13	;	;	PUNCT
eurjchem-411	565	14	costi	costi	PROPN
eurjchem-411	565	15	,	,	PUNCT
eurjchem-411	565	16	r.	r.	PROPN
eurjchem-411	565	17	;	;	PUNCT
eurjchem-411	565	18	botta	botta	PROPN
eurjchem-411	565	19	,	,	PUNCT
eurjchem-411	565	20	m.	m.	NOUN
eurjchem-411	565	21	;	;	PUNCT
eurjchem-411	565	22	artico	artico	PROPN
eurjchem-411	565	23	,	,	PUNCT
eurjchem-411	565	24	m.	m.	NOUN
eurjchem-411	565	25	;	;	PUNCT
eurjchem-411	565	26	corelli	corelli	PROPN
eurjchem-411	565	27	,	,	PUNCT
eurjchem-411	565	28	f.	f.	PROPN
eurjchem-411	565	29	;	;	PUNCT
eurjchem-411	565	30	forte	forte	NOUN
eurjchem-411	565	31	,	,	PUNCT
eurjchem-411	565	32	m.	m.	NOUN
eurjchem-411	565	33	;	;	PUNCT
eurjchem-411	565	34	caporuscio	caporuscio	PROPN
eurjchem-411	565	35	,	,	PUNCT
eurjchem-411	565	36	f.	f.	PROPN
eurjchem-411	565	37	;	;	PUNCT
eurjchem-411	565	38	angiolella	angiolella	PROPN
eurjchem-411	565	39	,	,	PUNCT
eurjchem-411	565	40	l.	l.	PROPN
eurjchem-411	565	41	;	;	PUNCT
eurjchem-411	565	42	palamara	palamara	PROPN
eurjchem-411	565	43	,	,	PUNCT
eurjchem-411	565	44	a.	a.	PROPN
eurjchem-411	565	45	t.	t.	PROPN
eurjchem-411	565	46	j.	j.	PROPN
eurjchem-411	565	47	med	med	PROPN
eurjchem-411	565	48	.	.	PROPN
eurjchem-411	565	49	chem	chem	PROPN
eurjchem-411	565	50	.	.	PUNCT
eurjchem-411	566	1	2005	2005	NUM
eurjchem-411	566	2	,	,	PUNCT
eurjchem-411	566	3	48	48	NUM
eurjchem-411	566	4	,	,	PUNCT
eurjchem-411	566	5	5140‐5153	5140‐5153	NUM
eurjchem-411	566	6	.	.	PUNCT