id	sid	tid	token	lemma	pos
eurjchem-414	1	1	untitled	untitle	VERB
eurjchem-414	1	2	european	european	PROPN
eurjchem-414	1	3	journal	journal	PROPN
eurjchem-414	1	4	of	of	ADP
eurjchem-414	1	5	chemistry	chemistry	NOUN
eurjchem-414	1	6	2	2	NUM
eurjchem-414	1	7	(	(	PUNCT
eurjchem-414	1	8	3	3	NUM
eurjchem-414	1	9	)	)	PUNCT
eurjchem-414	1	10	(	(	PUNCT
eurjchem-414	1	11	2011	2011	NUM
eurjchem-414	1	12	)	)	PUNCT
eurjchem-414	1	13	311‐313	311‐313	PROPN
eurjchem-414	1	14	european	european	PROPN
eurjchem-414	1	15	journal	journal	PROPN
eurjchem-414	1	16	of	of	ADP
eurjchem-414	1	17	chemistry	chemistry	NOUN
eurjchem-414	1	18	issn	issn	PROPN
eurjchem-414	1	19	2153‐2249	2153‐2249	PROPN
eurjchem-414	1	20	(	(	PUNCT
eurjchem-414	1	21	print	print	NOUN
eurjchem-414	1	22	)	)	PUNCT
eurjchem-414	1	23	/	/	SYM
eurjchem-414	1	24	issn	issn	PROPN
eurjchem-414	1	25	2153‐2257	2153‐2257	NUM
eurjchem-414	1	26	(	(	PUNCT
eurjchem-414	1	27	online	online	ADJ
eurjchem-414	1	28	)	)	PUNCT
eurjchem-414	1	29			NOUN
eurjchem-414	1	30	2011	2011	NUM
eurjchem-414	1	31	eurjchem	eurjchem	PROPN
eurjchem-414	1	32	doi:10.5155	doi:10.5155	PROPN
eurjchem-414	1	33	/	/	SYM
eurjchem-414	1	34	eurjchem.2.3.311‐313.414	eurjchem.2.3.311‐313.414	PROPN
eurjchem-414	1	35	european	european	PROPN
eurjchem-414	1	36	journal	journal	PROPN
eurjchem-414	1	37	of	of	ADP
eurjchem-414	1	38	chemistry	chemistry	PROPN
eurjchem-414	1	39	journal	journal	PROPN
eurjchem-414	1	40	homepage	homepage	NOUN
eurjchem-414	1	41	:	:	PUNCT
eurjchem-414	1	42	www.eurjchem.com	www.eurjchem.com	X
eurjchem-414	1	43	synthesis	synthesis	NOUN
eurjchem-414	1	44	and	and	CCONJ
eurjchem-414	1	45	characterization	characterization	NOUN
eurjchem-414	1	46	of	of	ADP
eurjchem-414	1	47	1‐formyl‐3‐phenyl‐5‐aryl‐2‐pyrazolines	1‐formyl‐3‐phenyl‐5‐aryl‐2‐pyrazolines	PROPN
eurjchem-414	1	48	assia	assia	PROPN
eurjchem-414	1	49	sida	sida	PROPN
eurjchem-414	1	50	,	,	PUNCT
eurjchem-414	1	51	*	*	PROPN
eurjchem-414	1	52	,	,	PUNCT
eurjchem-414	1	53	kaddour	kaddour	ADJ
eurjchem-414	1	54	lamaraa	lamaraa	PROPN
eurjchem-414	1	55	,	,	PUNCT
eurjchem-414	1	56	mahieddine	mahieddine	PROPN
eurjchem-414	1	57	mokhtaria	mokhtaria	PROPN
eurjchem-414	1	58	,	,	PUNCT
eurjchem-414	1	59	nouara	nouara	PROPN
eurjchem-414	1	60	ziania	ziania	PROPN
eurjchem-414	1	61	and	and	CCONJ
eurjchem-414	1	62	paul	paul	PROPN
eurjchem-414	1	63	mossetb	mossetb	PROPN
eurjchem-414	1	64	a	a	DET
eurjchem-414	1	65	laboratory	laboratory	NOUN
eurjchem-414	1	66	of	of	ADP
eurjchem-414	1	67	applied	apply	VERB
eurjchem-414	1	68	chemistry	chemistry	NOUN
eurjchem-414	1	69	and	and	CCONJ
eurjchem-414	1	70	materials	material	NOUN
eurjchem-414	1	71	technology	technology	NOUN
eurjchem-414	1	72	,	,	PUNCT
eurjchem-414	1	73	chemistry	chemistry	NOUN
eurjchem-414	1	74	institute	institute	PROPN
eurjchem-414	1	75	,	,	PUNCT
eurjchem-414	1	76	university	university	PROPN
eurjchem-414	1	77	of	of	ADP
eurjchem-414	1	78	oum	oum	PROPN
eurjchem-414	1	79	el	el	PROPN
eurjchem-414	1	80	bouaghi	bouaghi	PROPN
eurjchem-414	1	81	,	,	PUNCT
eurjchem-414	1	82	rue	rue	X
eurjchem-414	1	83	de	de	PROPN
eurjchem-414	1	84	constantine	constantine	PROPN
eurjchem-414	1	85	,	,	PUNCT
eurjchem-414	1	86	04000	04000	NUM
eurjchem-414	1	87	,	,	PUNCT
eurjchem-414	1	88	algeria	algeria	PROPN
eurjchem-414	1	89	b	b	PROPN
eurjchem-414	1	90	université	université	PROPN
eurjchem-414	1	91	de	de	PROPN
eurjchem-414	1	92	rennes	rennes	PROPN
eurjchem-414	1	93	1	1	NUM
eurjchem-414	1	94	,	,	PUNCT
eurjchem-414	1	95	laboratoire	laboratoire	PROPN
eurjchem-414	1	96	sciences	sciences	PROPN
eurjchem-414	1	97	chimiques	chimiques	X
eurjchem-414	1	98	de	de	X
eurjchem-414	1	99	rennes	renne	NOUN
eurjchem-414	1	100	,	,	PUNCT
eurjchem-414	1	101	centre	centre	PROPN
eurjchem-414	1	102	national	national	PROPN
eurjchem-414	1	103	de	de	X
eurjchem-414	1	104	la	la	X
eurjchem-414	1	105	recherche	recherche	X
eurjchem-414	1	106	scientifique	scientifique	PROPN
eurjchem-414	1	107	,	,	PUNCT
eurjchem-414	1	108	unité	unité	PROPN
eurjchem-414	1	109	mixte	mixte	PROPN
eurjchem-414	1	110	de	de	X
eurjchem-414	1	111	recherche	recherche	X
eurjchem-414	1	112	6226	6226	NUM
eurjchem-414	1	113	,	,	PUNCT
eurjchem-414	1	114	avenue	avenue	PROPN
eurjchem-414	1	115	du	du	PROPN
eurjchem-414	1	116	général	général	PROPN
eurjchem-414	1	117	leclerc	leclerc	PROPN
eurjchem-414	1	118	,	,	PUNCT
eurjchem-414	1	119	rennes	rennes	PROPN
eurjchem-414	1	120	cedex	cedex	PROPN
eurjchem-414	1	121	,	,	PUNCT
eurjchem-414	1	122	35042	35042	NUM
eurjchem-414	1	123	,	,	PUNCT
eurjchem-414	1	124	france	france	PROPN
eurjchem-414	1	125	*	*	PUNCT
eurjchem-414	1	126	corresponding	correspond	VERB
eurjchem-414	1	127	author	author	NOUN
eurjchem-414	1	128	at	at	ADP
eurjchem-414	1	129	:	:	PUNCT
eurjchem-414	1	130	laboratory	laboratory	NOUN
eurjchem-414	1	131	of	of	ADP
eurjchem-414	1	132	applied	apply	VERB
eurjchem-414	1	133	chemistry	chemistry	NOUN
eurjchem-414	1	134	and	and	CCONJ
eurjchem-414	1	135	materials	material	NOUN
eurjchem-414	1	136	technology	technology	NOUN
eurjchem-414	1	137	,	,	PUNCT
eurjchem-414	1	138	chemistry	chemistry	NOUN
eurjchem-414	1	139	institute	institute	PROPN
eurjchem-414	1	140	,	,	PUNCT
eurjchem-414	1	141	university	university	PROPN
eurjchem-414	1	142	of	of	ADP
eurjchem-414	1	143	oum	oum	PROPN
eurjchem-414	1	144	el	el	PROPN
eurjchem-414	1	145	bouaghi	bouaghi	PROPN
eurjchem-414	1	146	,	,	PUNCT
eurjchem-414	1	147	rue	rue	X
eurjchem-414	1	148	de	de	PROPN
eurjchem-414	1	149	constantine	constantine	PROPN
eurjchem-414	1	150	,	,	PUNCT
eurjchem-414	1	151	04000	04000	NUM
eurjchem-414	1	152	,	,	PUNCT
eurjchem-414	1	153	algeria	algeria	PROPN
eurjchem-414	1	154	.	.	PUNCT
eurjchem-414	2	1	tel	tel	PROPN
eurjchem-414	2	2	.	.	PUNCT
eurjchem-414	2	3	:	:	PUNCT
eurjchem-414	3	1	+213.32421036	+213.32421036	PROPN
eurjchem-414	3	2	;	;	PUNCT
eurjchem-414	3	3	fax	fax	NOUN
eurjchem-414	3	4	:	:	PUNCT
eurjchem-414	3	5	+213.32424213	+213.32424213	PROPN
eurjchem-414	3	6	.	.	PUNCT
eurjchem-414	3	7	e‐mail	e‐mail	PUNCT
eurjchem-414	4	1	address	address	NOUN
eurjchem-414	4	2	:	:	PUNCT
eurjchem-414	4	3	madamesid9@yahoo.fr	madamesid9@yahoo.fr	X
eurjchem-414	4	4	(	(	PUNCT
eurjchem-414	4	5	a.	a.	PROPN
eurjchem-414	4	6	sid	sid	PROPN
eurjchem-414	4	7	)	)	PUNCT
eurjchem-414	4	8	.	.	PUNCT
eurjchem-414	5	1	article	article	NOUN
eurjchem-414	5	2	information	information	PROPN
eurjchem-414	5	3	abstract	abstract	ADV
eurjchem-414	5	4	received	receive	VERB
eurjchem-414	5	5	:	:	PUNCT
eurjchem-414	5	6	07	07	NUM
eurjchem-414	5	7	march	march	NOUN
eurjchem-414	5	8	2011	2011	NUM
eurjchem-414	5	9	received	receive	VERB
eurjchem-414	5	10	in	in	ADP
eurjchem-414	5	11	revised	revise	VERB
eurjchem-414	5	12	form	form	NOUN
eurjchem-414	5	13	:	:	PUNCT
eurjchem-414	5	14	19	19	NUM
eurjchem-414	5	15	april	april	PROPN
eurjchem-414	5	16	2011	2011	NUM
eurjchem-414	5	17	accepted	accept	VERB
eurjchem-414	5	18	:	:	PUNCT
eurjchem-414	5	19	17	17	NUM
eurjchem-414	5	20	may	may	PROPN
eurjchem-414	5	21	2011	2011	NUM
eurjchem-414	5	22	online	online	ADV
eurjchem-414	5	23	:	:	PUNCT
eurjchem-414	5	24	30	30	NUM
eurjchem-414	5	25	september	september	PROPN
eurjchem-414	5	26	2011	2011	NUM
eurjchem-414	5	27	keywords	keyword	VERB
eurjchem-414	5	28	reaction	reaction	NOUN
eurjchem-414	5	29	of	of	ADP
eurjchem-414	5	30	chalcone	chalcone	NOUN
eurjchem-414	5	31	derivatives	derivative	VERB
eurjchem-414	5	32	1‐4	1‐4	NUM
eurjchem-414	5	33	with	with	ADP
eurjchem-414	5	34	hydrazine	hydrazine	NOUN
eurjchem-414	5	35	hydrate	hydrate	NOUN
eurjchem-414	5	36	in	in	ADP
eurjchem-414	5	37	presence	presence	NOUN
eurjchem-414	5	38	of	of	ADP
eurjchem-414	5	39	formic	formic	PROPN
eurjchem-414	5	40	acid	acid	PROPN
eurjchem-414	5	41	yielded	yield	VERB
eurjchem-414	5	42	2‐pyrazolines	2‐pyrazolines	PROPN
eurjchem-414	5	43	5‐8	5‐8	PROPN
eurjchem-414	5	44	.	.	PUNCT
eurjchem-414	5	45	structures	structure	NOUN
eurjchem-414	5	46	of	of	ADP
eurjchem-414	5	47	these	these	DET
eurjchem-414	5	48	compounds	compound	NOUN
eurjchem-414	5	49	have	have	AUX
eurjchem-414	5	50	been	be	AUX
eurjchem-414	5	51	elucidated	elucidate	VERB
eurjchem-414	5	52	by	by	ADP
eurjchem-414	5	53	spectroscopic	spectroscopic	ADJ
eurjchem-414	5	54	methods	method	NOUN
eurjchem-414	5	55	;	;	PUNCT
eurjchem-414	5	56	ir	ir	X
eurjchem-414	5	57	,	,	PUNCT
eurjchem-414	5	58	uv	uv	PROPN
eurjchem-414	5	59	,	,	PUNCT
eurjchem-414	5	60	1h	1h	NUM
eurjchem-414	5	61	nmr	nmr	NOUN
eurjchem-414	5	62	,	,	PUNCT
eurjchem-414	5	63	13c	13c	NOUN
eurjchem-414	5	64	nmr	nmr	NOUN
eurjchem-414	5	65	.	.	PUNCT
eurjchem-414	6	1	their	their	PRON
eurjchem-414	6	2	purities	purity	NOUN
eurjchem-414	6	3	were	be	AUX
eurjchem-414	6	4	confirmed	confirm	VERB
eurjchem-414	6	5	by	by	ADP
eurjchem-414	6	6	elemental	elemental	ADJ
eurjchem-414	6	7	analyses	analysis	NOUN
eurjchem-414	6	8	.	.	PUNCT
eurjchem-414	7	1	chalcones	chalcone	VERB
eurjchem-414	7	2	formic	formic	PROPN
eurjchem-414	7	3	acid	acid	PROPN
eurjchem-414	7	4	pyrazolines	pyrazoline	NOUN
eurjchem-414	7	5	hydrazine	hydrazine	NOUN
eurjchem-414	7	6	hydrate	hydrate	NOUN
eurjchem-414	7	7	fluorescence	fluorescence	NOUN
eurjchem-414	7	8	spectroscopy	spectroscopy	NOUN
eurjchem-414	7	9	spectroscopy	spectroscopy	VERB
eurjchem-414	7	10	1	1	NUM
eurjchem-414	7	11	.	.	PUNCT
eurjchem-414	8	1	introduction	introduction	NOUN
eurjchem-414	8	2	numerous	numerous	ADJ
eurjchem-414	8	3	pyrazolines	pyrazoline	NOUN
eurjchem-414	8	4	type	type	NOUN
eurjchem-414	8	5	compounds	compound	NOUN
eurjchem-414	8	6	have	have	AUX
eurjchem-414	8	7	been	be	AUX
eurjchem-414	8	8	found	find	VERB
eurjchem-414	8	9	to	to	PART
eurjchem-414	8	10	exhibit	exhibit	VERB
eurjchem-414	8	11	bioactivities	bioactivitie	NOUN
eurjchem-414	8	12	.	.	PUNCT
eurjchem-414	9	1	pyrazolines	pyrazoline	NOUN
eurjchem-414	9	2	derivatives	derivative	NOUN
eurjchem-414	9	3	with	with	ADP
eurjchem-414	9	4	a	a	DET
eurjchem-414	9	5	phenyl	phenyl	NOUN
eurjchem-414	9	6	group	group	NOUN
eurjchem-414	9	7	at	at	ADP
eurjchem-414	9	8	the	the	DET
eurjchem-414	9	9	5‐position	5‐position	PROPN
eurjchem-414	9	10	possess	possess	VERB
eurjchem-414	9	11	good	good	ADJ
eurjchem-414	9	12	film‐forming	film‐forming	NOUN
eurjchem-414	9	13	properties	property	NOUN
eurjchem-414	9	14	,	,	PUNCT
eurjchem-414	9	15	exhibit	exhibit	VERB
eurjchem-414	9	16	excellent	excellent	ADJ
eurjchem-414	9	17	characteristics	characteristic	NOUN
eurjchem-414	9	18	of	of	ADP
eurjchem-414	9	19	blue	blue	ADJ
eurjchem-414	9	20	photoluminescence	photoluminescence	NOUN
eurjchem-414	9	21	and	and	CCONJ
eurjchem-414	9	22	electroluminescence	electroluminescence	NOUN
eurjchem-414	9	23	[	[	X
eurjchem-414	9	24	1	1	NUM
eurjchem-414	9	25	]	]	PUNCT
eurjchem-414	9	26	.	.	PUNCT
eurjchem-414	10	1	pyrazolines	pyrazoline	NOUN
eurjchem-414	10	2	are	be	AUX
eurjchem-414	10	3	also	also	ADV
eurjchem-414	10	4	used	use	VERB
eurjchem-414	10	5	as	as	ADP
eurjchem-414	10	6	optical	optical	ADJ
eurjchem-414	10	7	brighteners	brightener	NOUN
eurjchem-414	10	8	and	and	CCONJ
eurjchem-414	10	9	whiteners	whitener	NOUN
eurjchem-414	10	10	.	.	PUNCT
eurjchem-414	11	1	they	they	PRON
eurjchem-414	11	2	display	display	VERB
eurjchem-414	11	3	various	various	ADJ
eurjchem-414	11	4	biological	biological	ADJ
eurjchem-414	11	5	activities	activity	NOUN
eurjchem-414	11	6	such	such	ADJ
eurjchem-414	11	7	as	as	ADP
eurjchem-414	11	8	antimicrobial	antimicrobial	ADJ
eurjchem-414	11	9	[	[	X
eurjchem-414	11	10	2	2	NUM
eurjchem-414	11	11	]	]	PUNCT
eurjchem-414	11	12	,	,	PUNCT
eurjchem-414	11	13	antifungal	antifungal	PROPN
eurjchem-414	12	1	[	[	X
eurjchem-414	12	2	3	3	NUM
eurjchem-414	12	3	]	]	PUNCT
eurjchem-414	12	4	,	,	PUNCT
eurjchem-414	12	5	antidepressant	antidepressant	ADJ
eurjchem-414	12	6	[	[	X
eurjchem-414	12	7	4	4	NUM
eurjchem-414	12	8	]	]	PUNCT
eurjchem-414	12	9	,	,	PUNCT
eurjchem-414	12	10	immunosuppressive	immunosuppressive	ADJ
eurjchem-414	12	11	[	[	X
eurjchem-414	12	12	5	5	NUM
eurjchem-414	12	13	]	]	PUNCT
eurjchem-414	12	14	,	,	PUNCT
eurjchem-414	12	15	anticonvulsant	anticonvulsant	PROPN
eurjchem-414	12	16	[	[	X
eurjchem-414	12	17	6	6	NUM
eurjchem-414	12	18	]	]	PUNCT
eurjchem-414	12	19	,	,	PUNCT
eurjchem-414	12	20	anti‐tumor	anti‐tumor	PROPN
eurjchem-414	13	1	[	[	X
eurjchem-414	13	2	7	7	NUM
eurjchem-414	13	3	]	]	PUNCT
eurjchem-414	13	4	,	,	PUNCT
eurjchem-414	13	5	antiamoebic	antiamoebic	VERB
eurjchem-414	13	6	[	[	X
eurjchem-414	13	7	8	8	NUM
eurjchem-414	13	8	]	]	PUNCT
eurjchem-414	13	9	,	,	PUNCT
eurjchem-414	13	10	antibacterial	antibacterial	ADJ
eurjchem-414	13	11	[	[	X
eurjchem-414	13	12	9	9	NUM
eurjchem-414	13	13	]	]	PUNCT
eurjchem-414	13	14	and	and	CCONJ
eurjchem-414	13	15	anti‐	anti‐	ADV
eurjchem-414	13	16	inflammatory	inflammatory	ADJ
eurjchem-414	13	17	[	[	X
eurjchem-414	13	18	10	10	NUM
eurjchem-414	13	19	]	]	ADJ
eurjchem-414	13	20	activities	activity	NOUN
eurjchem-414	13	21	.	.	PUNCT
eurjchem-414	14	1	synthesis	synthesis	NOUN
eurjchem-414	14	2	of	of	ADP
eurjchem-414	14	3	pyrazolines	pyrazoline	NOUN
eurjchem-414	14	4	by	by	ADP
eurjchem-414	14	5	reaction	reaction	NOUN
eurjchem-414	14	6	of	of	ADP
eurjchem-414	14	7	α	α	PROPN
eurjchem-414	14	8	,	,	PUNCT
eurjchem-414	14	9	β‐unsaturated	β‐unsaturate	VERB
eurjchem-414	14	10	carbonyl	carbonyl	NOUN
eurjchem-414	14	11	compounds	compound	NOUN
eurjchem-414	14	12	with	with	ADP
eurjchem-414	14	13	diazoalkanes	diazoalkane	NOUN
eurjchem-414	14	14	[	[	X
eurjchem-414	14	15	11	11	NUM
eurjchem-414	14	16	]	]	PUNCT
eurjchem-414	14	17	or	or	CCONJ
eurjchem-414	14	18	with	with	ADP
eurjchem-414	14	19	hydrazine	hydrazine	NOUN
eurjchem-414	14	20	hydrate	hydrate	NOUN
eurjchem-414	14	21	were	be	AUX
eurjchem-414	14	22	reported	report	VERB
eurjchem-414	14	23	in	in	ADP
eurjchem-414	14	24	the	the	DET
eurjchem-414	14	25	literature	literature	NOUN
eurjchem-414	14	26	[	[	X
eurjchem-414	14	27	12,13	12,13	NUM
eurjchem-414	14	28	]	]	PUNCT
eurjchem-414	14	29	.	.	PUNCT
eurjchem-414	15	1	n‐substituted	n‐substitute	VERB
eurjchem-414	15	2	thiocarbamoyl‐3,5‐	thiocarbamoyl‐3,5‐	PROPN
eurjchem-414	15	3	diphenyl‐2‐pyrazoline	diphenyl‐2‐pyrazoline	PROPN
eurjchem-414	15	4	derivatives	derivative	NOUN
eurjchem-414	15	5	having	have	VERB
eurjchem-414	15	6	ns	ns	ADJ
eurjchem-414	15	7	donor	donor	NOUN
eurjchem-414	15	8	,	,	PUNCT
eurjchem-414	15	9	their	their	PRON
eurjchem-414	15	10	palladium	palladium	NOUN
eurjchem-414	15	11	π	π	NOUN
eurjchem-414	15	12	complexes	complexe	VERB
eurjchem-414	15	13	[	[	X
eurjchem-414	15	14	14	14	NUM
eurjchem-414	15	15	]	]	PUNCT
eurjchem-414	15	16	and	and	CCONJ
eurjchem-414	15	17	hydroxylphenyl	hydroxylphenyl	NOUN
eurjchem-414	15	18	pyrazolines	pyrazoline	NOUN
eurjchem-414	15	19	have	have	AUX
eurjchem-414	15	20	also	also	ADV
eurjchem-414	15	21	been	be	AUX
eurjchem-414	15	22	synthesised	synthesise	VERB
eurjchem-414	15	23	[	[	PUNCT
eurjchem-414	15	24	15	15	NUM
eurjchem-414	15	25	]	]	PUNCT
eurjchem-414	15	26	.	.	PUNCT
eurjchem-414	16	1	the	the	DET
eurjchem-414	16	2	reaction	reaction	NOUN
eurjchem-414	16	3	of	of	ADP
eurjchem-414	16	4	e‐arylidenes	e‐arylidene	NOUN
eurjchem-414	16	5	with	with	ADP
eurjchem-414	16	6	diazomethane	diazomethane	NOUN
eurjchem-414	16	7	affords	afford	NOUN
eurjchem-414	16	8	trans‐pyrazolines	trans‐pyrazoline	NOUN
eurjchem-414	16	9	while	while	SCONJ
eurjchem-414	16	10	z‐	z‐	ADJ
eurjchem-414	16	11	arylidenes	arylidene	NOUN
eurjchem-414	16	12	gave	give	VERB
eurjchem-414	16	13	cis‐isomers	cis‐isomer	NOUN
eurjchem-414	16	14	[	[	X
eurjchem-414	16	15	16	16	NUM
eurjchem-414	16	16	]	]	PUNCT
eurjchem-414	16	17	.	.	PUNCT
eurjchem-414	17	1	1,3‐dipolar	1,3‐dipolar	NUM
eurjchem-414	17	2	cycloaddition	cycloaddition	NOUN
eurjchem-414	17	3	of	of	ADP
eurjchem-414	17	4	exocyclic	exocyclic	ADJ
eurjchem-414	17	5	α	α	PROPN
eurjchem-414	17	6	,	,	PUNCT
eurjchem-414	17	7	β‐unsaturated	β‐unsaturate	VERB
eurjchem-414	17	8	ketones	ketone	NOUN
eurjchem-414	17	9	with	with	ADP
eurjchem-414	17	10	diazomethane	diazomethane	NOUN
eurjchem-414	17	11	has	have	AUX
eurjchem-414	17	12	also	also	ADV
eurjchem-414	17	13	been	be	AUX
eurjchem-414	17	14	studied	study	VERB
eurjchem-414	17	15	[	[	X
eurjchem-414	17	16	17‐22	17‐22	NUM
eurjchem-414	17	17	]	]	PUNCT
eurjchem-414	17	18	.	.	PUNCT
eurjchem-414	18	1	the	the	DET
eurjchem-414	18	2	present	present	ADJ
eurjchem-414	18	3	paper	paper	NOUN
eurjchem-414	18	4	deals	deal	NOUN
eurjchem-414	18	5	with	with	ADP
eurjchem-414	18	6	the	the	DET
eurjchem-414	18	7	synthesis	synthesis	NOUN
eurjchem-414	18	8	of	of	ADP
eurjchem-414	18	9	four	four	NUM
eurjchem-414	18	10	2‐	2‐	NUM
eurjchem-414	18	11	pyrazolines	pyrazoline	NOUN
eurjchem-414	18	12	derivatives	derivative	NOUN
eurjchem-414	18	13	5‐8	5‐8	PROPN
eurjchem-414	18	14	from	from	ADP
eurjchem-414	18	15	the	the	DET
eurjchem-414	18	16	reaction	reaction	NOUN
eurjchem-414	18	17	of	of	ADP
eurjchem-414	18	18	chalcone	chalcone	NOUN
eurjchem-414	18	19	derivatives	derivative	NOUN
eurjchem-414	18	20	1‐4	1‐4	NUM
eurjchem-414	18	21	and	and	CCONJ
eurjchem-414	18	22	hydrazine	hydrazine	NOUN
eurjchem-414	18	23	hydrate	hydrate	NOUN
eurjchem-414	18	24	in	in	ADP
eurjchem-414	18	25	the	the	DET
eurjchem-414	18	26	presence	presence	NOUN
eurjchem-414	18	27	of	of	ADP
eurjchem-414	18	28	formic	formic	ADJ
eurjchem-414	18	29	acid	acid	PROPN
eurjchem-414	18	30	(	(	PUNCT
eurjchem-414	18	31	scheme	scheme	NOUN
eurjchem-414	18	32	1	1	NUM
eurjchem-414	18	33	)	)	PUNCT
eurjchem-414	18	34	.	.	PUNCT
eurjchem-414	19	1	the	the	DET
eurjchem-414	19	2	structures	structure	NOUN
eurjchem-414	19	3	of	of	ADP
eurjchem-414	19	4	these	these	DET
eurjchem-414	19	5	compounds	compound	NOUN
eurjchem-414	19	6	were	be	AUX
eurjchem-414	19	7	established	establish	VERB
eurjchem-414	19	8	by	by	ADP
eurjchem-414	19	9	spectroscopic	spectroscopic	ADJ
eurjchem-414	19	10	techniques	technique	NOUN
eurjchem-414	19	11	.	.	PUNCT
eurjchem-414	20	1	2	2	X
eurjchem-414	20	2	.	.	X
eurjchem-414	20	3	experimental	experimental	ADJ
eurjchem-414	20	4	2.1	2.1	NUM
eurjchem-414	20	5	.	.	PUNCT
eurjchem-414	21	1	instrumentation	instrumentation	NOUN
eurjchem-414	21	2	melting	melting	NOUN
eurjchem-414	21	3	points	point	NOUN
eurjchem-414	21	4	were	be	AUX
eurjchem-414	21	5	determined	determine	VERB
eurjchem-414	21	6	with	with	ADP
eurjchem-414	21	7	a	a	DET
eurjchem-414	21	8	(	(	PUNCT
eurjchem-414	21	9	bransted/‐	bransted/‐	NOUN
eurjchem-414	21	10	electrothermal	electrothermal	ADJ
eurjchem-414	21	11	)	)	PUNCT
eurjchem-414	21	12	apparatus	apparatus	NOUN
eurjchem-414	21	13	and	and	CCONJ
eurjchem-414	21	14	are	be	AUX
eurjchem-414	21	15	uncorrected	uncorrecte	VERB
eurjchem-414	21	16	.	.	PUNCT
eurjchem-414	22	1	uv	uv	PROPN
eurjchem-414	22	2	spectra	spectra	PROPN
eurjchem-414	22	3	were	be	AUX
eurjchem-414	22	4	recorded	record	VERB
eurjchem-414	22	5	on	on	ADP
eurjchem-414	22	6	a	a	DET
eurjchem-414	22	7	perkin‐elmer	perkin‐elmer	NOUN
eurjchem-414	22	8	double	double	ADJ
eurjchem-414	22	9	beam	beam	NOUN
eurjchem-414	22	10	uv‐visible	uv‐visible	ADJ
eurjchem-414	22	11	spectrophotometer	spectrophotometer	NOUN
eurjchem-414	22	12	(	(	PUNCT
eurjchem-414	22	13	λ‐25	λ‐25	PROPN
eurjchem-414	22	14	)	)	PUNCT
eurjchem-414	22	15	in	in	ADP
eurjchem-414	22	16	ethanol	ethanol	NOUN
eurjchem-414	22	17	.	.	PUNCT
eurjchem-414	23	1	ir	ir	PROPN
eurjchem-414	23	2	spectra	spectra	PROPN
eurjchem-414	23	3	were	be	AUX
eurjchem-414	23	4	recorded	record	VERB
eurjchem-414	23	5	in	in	ADP
eurjchem-414	23	6	kbr	kbr	PROPN
eurjchem-414	23	7	pellets	pellet	NOUN
eurjchem-414	23	8	on	on	ADP
eurjchem-414	23	9	a	a	DET
eurjchem-414	23	10	perkin‐elmer	perkin‐elmer	X
eurjchem-414	23	11	ft‐ir‐01	ft‐ir‐01	X
eurjchem-414	23	12	spectrophotometer	spectrophotometer	NOUN
eurjchem-414	23	13	.	.	PUNCT
eurjchem-414	24	1	1h	1h	NUM
eurjchem-414	24	2	and	and	CCONJ
eurjchem-414	24	3	13c	13c	NOUN
eurjchem-414	24	4	nmr	nmr	NOUN
eurjchem-414	24	5	spectra	spectra	NOUN
eurjchem-414	24	6	were	be	AUX
eurjchem-414	24	7	obtained	obtain	VERB
eurjchem-414	24	8	in	in	ADP
eurjchem-414	24	9	cdcl3	cdcl3	NOUN
eurjchem-414	24	10	on	on	ADP
eurjchem-414	24	11	an	an	DET
eurjchem-414	24	12	avance	avance	ADJ
eurjchem-414	24	13	400	400	NUM
eurjchem-414	24	14	bruker	bruker	NOUN
eurjchem-414	24	15	spectrometer	spectrometer	NOUN
eurjchem-414	24	16	(	(	PUNCT
eurjchem-414	24	17	400.13	400.13	NUM
eurjchem-414	24	18	mhz	mhz	NOUN
eurjchem-414	24	19	in	in	ADP
eurjchem-414	24	20	1h	1h	NUM
eurjchem-414	24	21	)	)	PUNCT
eurjchem-414	24	22	using	use	VERB
eurjchem-414	24	23	tms	tms	PROPN
eurjchem-414	24	24	as	as	ADP
eurjchem-414	24	25	internal	internal	ADJ
eurjchem-414	24	26	standard	standard	NOUN
eurjchem-414	24	27	.	.	PUNCT
eurjchem-414	25	1	scheme	scheme	NOUN
eurjchem-414	25	2	1	1	NUM
eurjchem-414	25	3	2.2	2.2	NUM
eurjchem-414	25	4	.	.	PUNCT
eurjchem-414	26	1	synthesis	synthesis	NOUN
eurjchem-414	26	2	2.2.1	2.2.1	NUM
eurjchem-414	26	3	.	.	PUNCT
eurjchem-414	27	1	synthesis	synthesis	NOUN
eurjchem-414	27	2	of	of	ADP
eurjchem-414	27	3	chalcones	chalcone	NOUN
eurjchem-414	27	4	in	in	ADP
eurjchem-414	27	5	a	a	DET
eurjchem-414	27	6	round‐bottomed	round‐bottomed	ADJ
eurjchem-414	27	7	flask	flask	NOUN
eurjchem-414	27	8	,	,	PUNCT
eurjchem-414	27	9	substituted	substitute	VERB
eurjchem-414	27	10	benzaldehydes	benzaldehyde	NOUN
eurjchem-414	27	11	(	(	PUNCT
eurjchem-414	27	12	50	50	NUM
eurjchem-414	27	13	mmol	mmol	NOUN
eurjchem-414	27	14	)	)	PUNCT
eurjchem-414	27	15	and	and	CCONJ
eurjchem-414	27	16	acetophenone	acetophenone	NOUN
eurjchem-414	27	17	(	(	PUNCT
eurjchem-414	27	18	50	50	NUM
eurjchem-414	27	19	mmol	mmol	NOUN
eurjchem-414	27	20	)	)	PUNCT
eurjchem-414	27	21	were	be	AUX
eurjchem-414	27	22	dissolved	dissolve	VERB
eurjchem-414	27	23	in	in	ADP
eurjchem-414	27	24	ethanol	ethanol	NOUN
eurjchem-414	27	25	.	.	PUNCT
eurjchem-414	28	1	the	the	DET
eurjchem-414	28	2	reaction	reaction	NOUN
eurjchem-414	28	3	mixture	mixture	NOUN
eurjchem-414	28	4	was	be	AUX
eurjchem-414	28	5	cooled	cool	VERB
eurjchem-414	28	6	in	in	ADP
eurjchem-414	28	7	an	an	DET
eurjchem-414	28	8	ice	ice	NOUN
eurjchem-414	28	9	bath	bath	NOUN
eurjchem-414	28	10	and	and	CCONJ
eurjchem-414	28	11	a	a	DET
eurjchem-414	28	12	solution	solution	NOUN
eurjchem-414	28	13	of	of	ADP
eurjchem-414	28	14	10	10	NUM
eurjchem-414	28	15	%	%	NOUN
eurjchem-414	28	16	sodium	sodium	NOUN
eurjchem-414	28	17	hydroxide	hydroxide	NOUN
eurjchem-414	28	18	was	be	AUX
eurjchem-414	28	19	added	add	VERB
eurjchem-414	28	20	dropwise	dropwise	NOUN
eurjchem-414	28	21	.	.	PUNCT
eurjchem-414	29	1	the	the	DET
eurjchem-414	29	2	mixture	mixture	NOUN
eurjchem-414	29	3	was	be	AUX
eurjchem-414	29	4	stirred	stir	VERB
eurjchem-414	29	5	for	for	ADP
eurjchem-414	29	6	4	4	NUM
eurjchem-414	29	7	hours	hour	NOUN
eurjchem-414	29	8	.	.	PUNCT
eurjchem-414	30	1	the	the	DET
eurjchem-414	30	2	yellow	yellow	PROPN
eurjchem-414	30	3	precipitate	precipitate	NOUN
eurjchem-414	30	4	obtained	obtain	VERB
eurjchem-414	30	5	was	be	AUX
eurjchem-414	30	6	filtered	filter	VERB
eurjchem-414	30	7	and	and	CCONJ
eurjchem-414	30	8	washed	wash	VERB
eurjchem-414	30	9	by	by	ADP
eurjchem-414	30	10	hcl	hcl	PROPN
eurjchem-414	30	11	(	(	PUNCT
eurjchem-414	30	12	0.1	0.1	NUM
eurjchem-414	30	13	n	n	CCONJ
eurjchem-414	30	14	)	)	PUNCT
eurjchem-414	30	15	then	then	ADV
eurjchem-414	30	16	crystallised	crystallise	VERB
eurjchem-414	30	17	from	from	ADP
eurjchem-414	30	18	ethanol	ethanol	NOUN
eurjchem-414	30	19	or	or	CCONJ
eurjchem-414	30	20	ethyl	ethyl	PROPN
eurjchem-414	30	21	acetate	acetate	NOUN
eurjchem-414	30	22	to	to	PART
eurjchem-414	30	23	afford	afford	VERB
eurjchem-414	30	24	chalcone	chalcone	NOUN
eurjchem-414	30	25	derivatives	derivative	NOUN
eurjchem-414	30	26	2,3,4	2,3,4	NUM
eurjchem-414	30	27	except	except	SCONJ
eurjchem-414	30	28	for	for	ADP
eurjchem-414	30	29	the	the	DET
eurjchem-414	30	30	chalcone	chalcone	NOUN
eurjchem-414	30	31	1	1	NUM
eurjchem-414	30	32	that	that	PRON
eurjchem-414	30	33	is	be	AUX
eurjchem-414	30	34	obtained	obtain	VERB
eurjchem-414	30	35	as	as	ADP
eurjchem-414	30	36	yellow	yellow	ADJ
eurjchem-414	30	37	oil	oil	NOUN
eurjchem-414	30	38	.	.	PUNCT
eurjchem-414	31	1	the	the	DET
eurjchem-414	31	2	chalcones	chalcone	NOUN
eurjchem-414	31	3	1‐4	1‐4	NUM
eurjchem-414	31	4	312	312	NUM
eurjchem-414	31	5	sid	sid	PROPN
eurjchem-414	31	6	et	et	PROPN
eurjchem-414	31	7	al	al	PROPN
eurjchem-414	31	8	.	.	PUNCT
eurjchem-414	31	9	/	/	SYM
eurjchem-414	31	10	european	european	PROPN
eurjchem-414	31	11	journal	journal	PROPN
eurjchem-414	31	12	of	of	ADP
eurjchem-414	31	13	chemistry	chemistry	NOUN
eurjchem-414	31	14	2	2	NUM
eurjchem-414	31	15	(	(	PUNCT
eurjchem-414	31	16	3	3	NUM
eurjchem-414	31	17	)	)	PUNCT
eurjchem-414	31	18	(	(	PUNCT
eurjchem-414	31	19	2011	2011	NUM
eurjchem-414	31	20	)	)	PUNCT
eurjchem-414	31	21	311‐313	311‐313	PROPN
eurjchem-414	31	22	were	be	AUX
eurjchem-414	31	23	afforded	afford	VERB
eurjchem-414	31	24	with	with	ADP
eurjchem-414	31	25	excellent	excellent	ADJ
eurjchem-414	31	26	yields	yield	NOUN
eurjchem-414	31	27	(	(	PUNCT
eurjchem-414	31	28	85‐91	85‐91	NUM
eurjchem-414	31	29	%	%	NOUN
eurjchem-414	31	30	)	)	PUNCT
eurjchem-414	31	31	.	.	PUNCT
eurjchem-414	32	1	their	their	PRON
eurjchem-414	32	2	melting	melting	NOUN
eurjchem-414	32	3	points	point	NOUN
eurjchem-414	32	4	are	be	AUX
eurjchem-414	32	5	111	111	NUM
eurjchem-414	32	6	,	,	PUNCT
eurjchem-414	32	7	102	102	NUM
eurjchem-414	32	8	and	and	CCONJ
eurjchem-414	32	9	113	113	NUM
eurjchem-414	32	10	°	°	NOUN
eurjchem-414	32	11	c	c	NOUN
eurjchem-414	32	12	,	,	PUNCT
eurjchem-414	32	13	respectively	respectively	ADV
eurjchem-414	32	14	.	.	PUNCT
eurjchem-414	33	1	2.2.2	2.2.2	X
eurjchem-414	33	2	.	.	X
eurjchem-414	34	1	synthesis	synthesis	NOUN
eurjchem-414	34	2	of	of	ADP
eurjchem-414	34	3	pyrazolines	pyrazoline	NOUN
eurjchem-414	34	4	a	a	DET
eurjchem-414	34	5	mixture	mixture	NOUN
eurjchem-414	34	6	of	of	ADP
eurjchem-414	34	7	chalcone	chalcone	NOUN
eurjchem-414	34	8	(	(	PUNCT
eurjchem-414	34	9	10.0	10.0	NUM
eurjchem-414	34	10	mmol	mmol	NOUN
eurjchem-414	34	11	)	)	PUNCT
eurjchem-414	34	12	,	,	PUNCT
eurjchem-414	34	13	hydrazine	hydrazine	NOUN
eurjchem-414	34	14	hydrate	hydrate	NOUN
eurjchem-414	34	15	(	(	PUNCT
eurjchem-414	34	16	50.0	50.0	NUM
eurjchem-414	34	17	mmol	mmol	NOUN
eurjchem-414	34	18	)	)	PUNCT
eurjchem-414	34	19	and	and	CCONJ
eurjchem-414	34	20	formic	formic	PROPN
eurjchem-414	34	21	acid	acid	NOUN
eurjchem-414	34	22	(	(	PUNCT
eurjchem-414	34	23	40	40	NUM
eurjchem-414	34	24	ml	ml	NOUN
eurjchem-414	34	25	)	)	PUNCT
eurjchem-414	34	26	were	be	AUX
eurjchem-414	34	27	refluxed	refluxe	VERB
eurjchem-414	34	28	for	for	ADP
eurjchem-414	34	29	24	24	NUM
eurjchem-414	34	30	h.	h.	NOUN
eurjchem-414	34	31	the	the	DET
eurjchem-414	34	32	resulting	result	VERB
eurjchem-414	34	33	mixture	mixture	NOUN
eurjchem-414	34	34	was	be	AUX
eurjchem-414	34	35	poured	pour	VERB
eurjchem-414	34	36	into	into	ADP
eurjchem-414	34	37	water	water	NOUN
eurjchem-414	34	38	(	(	PUNCT
eurjchem-414	34	39	100	100	NUM
eurjchem-414	34	40	ml	ml	NOUN
eurjchem-414	34	41	)	)	PUNCT
eurjchem-414	34	42	and	and	CCONJ
eurjchem-414	34	43	allowed	allow	VERB
eurjchem-414	34	44	to	to	PART
eurjchem-414	34	45	stand	stand	VERB
eurjchem-414	34	46	.	.	PUNCT
eurjchem-414	35	1	the	the	DET
eurjchem-414	35	2	precipitate	precipitate	NOUN
eurjchem-414	35	3	that	that	PRON
eurjchem-414	35	4	has	have	AUX
eurjchem-414	35	5	formed	form	VERB
eurjchem-414	35	6	was	be	AUX
eurjchem-414	35	7	separated	separate	VERB
eurjchem-414	35	8	by	by	ADP
eurjchem-414	35	9	filtration	filtration	NOUN
eurjchem-414	35	10	,	,	PUNCT
eurjchem-414	35	11	washed	wash	VERB
eurjchem-414	35	12	with	with	ADP
eurjchem-414	35	13	cold	cold	ADJ
eurjchem-414	35	14	water	water	NOUN
eurjchem-414	35	15	and	and	CCONJ
eurjchem-414	35	16	then	then	ADV
eurjchem-414	35	17	crystallized	crystallize	VERB
eurjchem-414	35	18	from	from	ADP
eurjchem-414	35	19	a	a	DET
eurjchem-414	35	20	mixture	mixture	NOUN
eurjchem-414	35	21	of	of	ADP
eurjchem-414	35	22	ethanol	ethanol	NOUN
eurjchem-414	35	23	:	:	PUNCT
eurjchem-414	35	24	toluene	toluene	NOUN
eurjchem-414	35	25	(	(	PUNCT
eurjchem-414	35	26	1:1	1:1	NUM
eurjchem-414	35	27	)	)	PUNCT
eurjchem-414	35	28	to	to	PART
eurjchem-414	35	29	yield	yield	VERB
eurjchem-414	35	30	2‐	2‐	NUM
eurjchem-414	35	31	pyrazolines	pyrazoline	NOUN
eurjchem-414	35	32	(	(	PUNCT
eurjchem-414	35	33	scheme	scheme	NOUN
eurjchem-414	35	34	1	1	NUM
eurjchem-414	35	35	)	)	PUNCT
eurjchem-414	35	36	.	.	PUNCT
eurjchem-414	36	1	1‐formyl‐3‐phenyl‐5‐(4‐isopropylphenyl)‐2‐pyrazoline	1‐formyl‐3‐phenyl‐5‐(4‐isopropylphenyl)‐2‐pyrazoline	NUM
eurjchem-414	36	2	(	(	PUNCT
eurjchem-414	36	3	5	5	NUM
eurjchem-414	36	4	):	):	PUNCT
eurjchem-414	36	5	pale	pale	ADJ
eurjchem-414	36	6	crystals	crystal	NOUN
eurjchem-414	36	7	.	.	PUNCT
eurjchem-414	37	1	yield	yield	NOUN
eurjchem-414	37	2	:	:	PUNCT
eurjchem-414	37	3	76	76	NUM
eurjchem-414	37	4	%	%	NOUN
eurjchem-414	37	5	.	.	PUNCT
eurjchem-414	38	1	m.p	m.p	PROPN
eurjchem-414	38	2	.	.	PROPN
eurjchem-414	38	3	:	:	PUNCT
eurjchem-414	39	1	144‐145	144‐145	NUM
eurjchem-414	39	2	°	°	SYM
eurjchem-414	39	3	c	c	NOUN
eurjchem-414	39	4	.	.	PUNCT
eurjchem-414	40	1	uv	uv	NOUN
eurjchem-414	40	2	/	/	SYM
eurjchem-414	40	3	vis	vis	X
eurjchem-414	40	4	(	(	PUNCT
eurjchem-414	40	5	λmax	λmax	PROPN
eurjchem-414	40	6	,	,	PUNCT
eurjchem-414	40	7	nm	nm	NOUN
eurjchem-414	40	8	):	):	PUNCT
eurjchem-414	40	9	407	407	NUM
eurjchem-414	40	10	,	,	PUNCT
eurjchem-414	40	11	337	337	NUM
eurjchem-414	40	12	,	,	PUNCT
eurjchem-414	40	13	325	325	NUM
eurjchem-414	40	14	.	.	PUNCT
eurjchem-414	41	1	ir	ir	PROPN
eurjchem-414	41	2	(	(	PUNCT
eurjchem-414	41	3	kbr	kbr	PROPN
eurjchem-414	41	4	,	,	PUNCT
eurjchem-414	41	5	cm‐1	cm‐1	PROPN
eurjchem-414	41	6	):	):	PUNCT
eurjchem-414	41	7	1662	1662	NUM
eurjchem-414	41	8	(	(	PUNCT
eurjchem-414	41	9	c	c	NOUN
eurjchem-414	41	10	=	=	NOUN
eurjchem-414	41	11	o	o	NOUN
eurjchem-414	41	12	)	)	PUNCT
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eurjchem-414	41	16	c	c	NOUN
eurjchem-414	41	17	=	=	SYM
eurjchem-414	41	18	n	n	NUM
eurjchem-414	41	19	)	)	PUNCT
eurjchem-414	41	20	,	,	PUNCT
eurjchem-414	41	21	1224	1224	NUM
eurjchem-414	41	22	(	(	PUNCT
eurjchem-414	41	23	c‐	c‐	NOUN
eurjchem-414	41	24	n	n	CCONJ
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eurjchem-414	42	1	1h	1h	NUM
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eurjchem-414	42	3	(	(	PUNCT
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eurjchem-414	42	8	):	):	PUNCT
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eurjchem-414	42	19	,	,	PUNCT
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eurjchem-414	42	22	,	,	PUNCT
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eurjchem-414	42	25	m	m	PROPN
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eurjchem-414	42	32	,	,	PUNCT
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eurjchem-414	42	36	,	,	PUNCT
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eurjchem-414	42	40	h	h	PROPN
eurjchem-414	42	41	)	)	PUNCT
eurjchem-414	42	42	,	,	PUNCT
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eurjchem-414	42	46	,	,	PUNCT
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eurjchem-414	42	60	,	,	PUNCT
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eurjchem-414	42	75	,	,	PUNCT
eurjchem-414	42	76	ch	ch	NOUN
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eurjchem-414	42	78	,	,	PUNCT
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eurjchem-414	42	81	dd	dd	PROPN
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eurjchem-414	42	86	=	=	PROPN
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eurjchem-414	42	94	,	,	PUNCT
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eurjchem-414	42	97	dd	dd	PROPN
eurjchem-414	42	98	,	,	PUNCT
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eurjchem-414	42	102	=	=	PROPN
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eurjchem-414	42	104	,	,	PUNCT
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eurjchem-414	42	110	,	,	PUNCT
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eurjchem-414	42	113	septet	septet	PROPN
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eurjchem-414	42	117	j=	j=	ADP
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eurjchem-414	42	123	,	,	PUNCT
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eurjchem-414	42	129	,	,	PUNCT
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eurjchem-414	43	4	,	,	PUNCT
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eurjchem-414	44	3	(	(	PUNCT
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eurjchem-414	44	6	,	,	PUNCT
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eurjchem-414	44	8	):	):	PUNCT
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eurjchem-414	44	11	ch	ch	NOUN
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eurjchem-414	44	13	,	,	PUNCT
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eurjchem-414	44	16	c	c	NOUN
eurjchem-414	44	17	)	)	PUNCT
eurjchem-414	44	18	,	,	PUNCT
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eurjchem-414	44	20	(	(	PUNCT
eurjchem-414	44	21	ar‐c	ar‐c	PROPN
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eurjchem-414	44	23	,	,	PUNCT
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eurjchem-414	44	26	ar‐c	ar‐c	PROPN
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eurjchem-414	44	28	,	,	PUNCT
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eurjchem-414	44	31	ar‐c	ar‐c	PROPN
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eurjchem-414	44	40	h	h	PROPN
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eurjchem-414	44	42	,	,	PUNCT
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eurjchem-414	44	48	ar‐h	ar‐h	PROPN
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eurjchem-414	44	50	,	,	PUNCT
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eurjchem-414	44	58	,	,	PUNCT
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eurjchem-414	44	65	h	h	PROPN
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eurjchem-414	44	67	,	,	PUNCT
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eurjchem-414	44	75	,	,	PUNCT
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eurjchem-414	44	80	ch2	ch2	PROPN
eurjchem-414	44	81	)	)	PUNCT
eurjchem-414	44	82	,	,	PUNCT
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eurjchem-414	44	85	ch(ch3)2	ch(ch3)2	NOUN
eurjchem-414	44	86	)	)	PUNCT
eurjchem-414	44	87	,	,	PUNCT
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eurjchem-414	44	90	ch(ch3)2	ch(ch3)2	NOUN
eurjchem-414	44	91	)	)	PUNCT
eurjchem-414	44	92	,	,	PUNCT
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eurjchem-414	44	94	(	(	PUNCT
eurjchem-414	44	95	ch(ch3)2	ch(ch3)2	NOUN
eurjchem-414	44	96	)	)	PUNCT
eurjchem-414	44	97	.	.	PUNCT
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eurjchem-414	46	5	,	,	PUNCT
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eurjchem-414	46	13	,	,	PUNCT
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eurjchem-414	46	19	,	,	PUNCT
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eurjchem-414	46	23	,	,	PUNCT
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eurjchem-414	47	4	)	)	PUNCT
eurjchem-414	47	5	.	.	PUNCT
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eurjchem-414	49	2	:	:	PUNCT
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eurjchem-414	49	5	.	.	PUNCT
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eurjchem-414	50	2	.	.	PROPN
eurjchem-414	50	3	:	:	PUNCT
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eurjchem-414	52	8	):	):	PUNCT
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eurjchem-414	52	10	,	,	PUNCT
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eurjchem-414	53	3	kbr	kbr	PROPN
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eurjchem-414	53	9	c	c	NOUN
eurjchem-414	53	10	=	=	NOUN
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eurjchem-414	53	13	,	,	PUNCT
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eurjchem-414	53	17	=	=	SYM
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eurjchem-414	53	20	,	,	PUNCT
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eurjchem-414	53	22	(	(	PUNCT
eurjchem-414	53	23	c‐n	c‐n	PROPN
eurjchem-414	53	24	)	)	PUNCT
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eurjchem-414	54	1	1h	1h	NUM
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eurjchem-414	54	3	(	(	PUNCT
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eurjchem-414	54	6	,	,	PUNCT
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eurjchem-414	54	8	):	):	PUNCT
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eurjchem-414	54	11	d	d	PROPN
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eurjchem-414	54	22	,	,	PUNCT
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eurjchem-414	54	25	m	m	PROPN
eurjchem-414	54	26	,	,	PUNCT
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eurjchem-414	54	30	h	h	PROPN
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eurjchem-414	54	32	,	,	PUNCT
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eurjchem-414	54	40	h	h	PROPN
eurjchem-414	54	41	)	)	PUNCT
eurjchem-414	54	42	,	,	PUNCT
eurjchem-414	54	43	7.20‐7.12	7.20‐7.12	NUM
eurjchem-414	54	44	(	(	PUNCT
eurjchem-414	54	45	s	s	PROPN
eurjchem-414	54	46	,	,	PUNCT
eurjchem-414	54	47	4h	4h	NUM
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eurjchem-414	54	51	aromatic	aromatic	NOUN
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eurjchem-414	54	53	,	,	PUNCT
eurjchem-414	54	54	5.50	5.50	NUM
eurjchem-414	54	55	(	(	PUNCT
eurjchem-414	54	56	ddd	ddd	PROPN
eurjchem-414	54	57	,	,	PUNCT
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eurjchem-414	54	60	j	j	PROPN
eurjchem-414	54	61	=	=	PROPN
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eurjchem-414	54	63	,	,	PUNCT
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eurjchem-414	54	65	,	,	PUNCT
eurjchem-414	54	66	1.0	1.0	NUM
eurjchem-414	54	67	hz	hz	NOUN
eurjchem-414	54	68	,	,	PUNCT
eurjchem-414	54	69	ch	ch	NOUN
eurjchem-414	54	70	)	)	PUNCT
eurjchem-414	54	71	,	,	PUNCT
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eurjchem-414	54	74	dd	dd	PROPN
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eurjchem-414	64	69	,	,	PUNCT
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eurjchem-414	64	82	,	,	PUNCT
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eurjchem-414	66	13	,	,	PUNCT
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eurjchem-414	66	27	,	,	PUNCT
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eurjchem-414	68	2	:	:	PUNCT
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eurjchem-414	68	5	.	.	PUNCT
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eurjchem-414	69	3	:	:	PUNCT
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eurjchem-414	70	18	.	.	PUNCT
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eurjchem-414	70	35	=	=	SYM
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eurjchem-414	70	40	(	(	PUNCT
eurjchem-414	70	41	c‐n	c‐n	PROPN
eurjchem-414	70	42	)	)	PUNCT
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eurjchem-414	71	3	(	(	PUNCT
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eurjchem-414	71	8	):	):	PUNCT
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eurjchem-414	71	19	,	,	PUNCT
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eurjchem-414	71	22	,	,	PUNCT
eurjchem-414	71	23	7.44‐	7.44‐	NUM
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eurjchem-414	71	25	(	(	PUNCT
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eurjchem-414	71	27	,	,	PUNCT
eurjchem-414	71	28	2h	2h	NUM
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eurjchem-414	71	30	ar‐h	ar‐h	PROPN
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eurjchem-414	71	32	,	,	PUNCT
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eurjchem-414	71	34	(	(	PUNCT
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eurjchem-414	71	36	,	,	PUNCT
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eurjchem-414	71	39	ar‐h	ar‐h	PROPN
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eurjchem-414	71	41	,	,	PUNCT
eurjchem-414	71	42	7.18‐7.14	7.18‐7.14	NUM
eurjchem-414	71	43	(	(	PUNCT
eurjchem-414	71	44	m	m	PROPN
eurjchem-414	71	45	,	,	PUNCT
eurjchem-414	71	46	4h	4h	NOUN
eurjchem-414	71	47	,	,	PUNCT
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eurjchem-414	71	51	,	,	PUNCT
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eurjchem-414	71	54	ddd	ddd	PROPN
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eurjchem-414	71	59	=	=	PROPN
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eurjchem-414	71	61	,	,	PUNCT
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eurjchem-414	71	63	,	,	PUNCT
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eurjchem-414	71	65	hz	hz	NOUN
eurjchem-414	71	66	,	,	PUNCT
eurjchem-414	71	67	ch	ch	NOUN
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eurjchem-414	71	69	,	,	PUNCT
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eurjchem-414	71	71	(	(	PUNCT
eurjchem-414	71	72	dd	dd	PROPN
eurjchem-414	71	73	,	,	PUNCT
eurjchem-414	71	74	1h	1h	NUM
eurjchem-414	71	75	,	,	PUNCT
eurjchem-414	71	76	j	j	PROPN
eurjchem-414	71	77	=	=	SYM
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eurjchem-414	71	79	,	,	PUNCT
eurjchem-414	71	80	11.9	11.9	NUM
eurjchem-414	71	81	hz	hz	NOUN
eurjchem-414	71	82	,	,	PUNCT
eurjchem-414	71	83	ch2	ch2	PROPN
eurjchem-414	71	84	)	)	PUNCT
eurjchem-414	71	85	,	,	PUNCT
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eurjchem-414	71	88	dd	dd	PROPN
eurjchem-414	71	89	,	,	PUNCT
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eurjchem-414	71	91	,	,	PUNCT
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eurjchem-414	71	93	=	=	SYM
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eurjchem-414	71	95	,	,	PUNCT
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eurjchem-414	71	98	,	,	PUNCT
eurjchem-414	71	99	ch2	ch2	PROPN
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eurjchem-414	71	101	.	.	PUNCT
eurjchem-414	72	1	13c	13c	NOUN
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eurjchem-414	72	3	(	(	PUNCT
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eurjchem-414	72	6	,	,	PUNCT
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eurjchem-414	72	8	):	):	PUNCT
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eurjchem-414	72	10	(	(	PUNCT
eurjchem-414	72	11	ch	ch	NOUN
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eurjchem-414	72	13	,	,	PUNCT
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eurjchem-414	72	17	)	)	PUNCT
eurjchem-414	72	18	,	,	PUNCT
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eurjchem-414	72	20	(	(	PUNCT
eurjchem-414	72	21	ar‐c	ar‐c	PROPN
eurjchem-414	72	22	)	)	PUNCT
eurjchem-414	72	23	,	,	PUNCT
eurjchem-414	72	24	138.94	138.94	NUM
eurjchem-414	72	25	(	(	PUNCT
eurjchem-414	72	26	ar‐c	ar‐c	PROPN
eurjchem-414	72	27	)	)	PUNCT
eurjchem-414	72	28	,	,	PUNCT
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eurjchem-414	72	30	(	(	PUNCT
eurjchem-414	72	31	c	c	NOUN
eurjchem-414	72	32	)	)	PUNCT
eurjchem-414	72	33	,	,	PUNCT
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eurjchem-414	72	39	ar‐h	ar‐h	PROPN
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eurjchem-414	72	41	,	,	PUNCT
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eurjchem-414	72	44	2	2	NUM
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eurjchem-414	72	47	p‐c6h4‐f	p‐c6h4‐f	NOUN
eurjchem-414	72	48	)	)	PUNCT
eurjchem-414	72	49	,	,	PUNCT
eurjchem-414	72	50	127.05	127.05	NUM
eurjchem-414	72	51	(	(	PUNCT
eurjchem-414	72	52	2	2	NUM
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eurjchem-414	72	55	p‐c6h4‐f	p‐c6h4‐f	NOUN
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eurjchem-414	72	57	,	,	PUNCT
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eurjchem-414	72	59	(	(	PUNCT
eurjchem-414	72	60	2	2	NUM
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eurjchem-414	72	63	ar‐h	ar‐h	PROPN
eurjchem-414	72	64	)	)	PUNCT
eurjchem-414	72	65	,	,	PUNCT
eurjchem-414	72	66	125.61	125.61	NUM
eurjchem-414	72	67	(	(	PUNCT
eurjchem-414	72	68	2	2	NUM
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eurjchem-414	72	73	,	,	PUNCT
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eurjchem-414	72	75	(	(	PUNCT
eurjchem-414	72	76	ch	ch	NOUN
eurjchem-414	72	77	)	)	PUNCT
eurjchem-414	72	78	,	,	PUNCT
eurjchem-414	72	79	41.95	41.95	NUM
eurjchem-414	72	80	(	(	PUNCT
eurjchem-414	72	81	ch2	ch2	PROPN
eurjchem-414	72	82	)	)	PUNCT
eurjchem-414	72	83	.	.	PUNCT
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eurjchem-414	73	4	.	.	PUNCT
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eurjchem-414	74	5	c	c	NOUN
eurjchem-414	74	6	,	,	PUNCT
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eurjchem-414	74	8	,	,	PUNCT
eurjchem-414	74	9	h	h	NOUN
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eurjchem-414	74	12	,	,	PUNCT
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eurjchem-414	74	14	,	,	PUNCT
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eurjchem-414	74	18	:	:	PUNCT
eurjchem-414	74	19	c	c	X
eurjchem-414	74	20	,	,	PUNCT
eurjchem-414	74	21	60.42	60.42	NUM
eurjchem-414	74	22	,	,	PUNCT
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eurjchem-414	74	24	,	,	PUNCT
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eurjchem-414	74	26	,	,	PUNCT
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eurjchem-414	74	28	,	,	PUNCT
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eurjchem-414	75	14	,	,	PUNCT
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eurjchem-414	75	22	place	place	NOUN
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eurjchem-414	75	25	reaction	reaction	NOUN
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eurjchem-414	75	27	using	use	VERB
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eurjchem-414	75	29	[	[	X
eurjchem-414	75	30	23	23	NUM
eurjchem-414	75	31	]	]	PUNCT
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eurjchem-414	75	35	[	[	X
eurjchem-414	75	36	24	24	NUM
eurjchem-414	75	37	]	]	PUNCT
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eurjchem-414	76	1	[	[	X
eurjchem-414	76	2	25	25	NUM
eurjchem-414	76	3	]	]	PUNCT
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eurjchem-414	77	1	[	[	X
eurjchem-414	77	2	26	26	NUM
eurjchem-414	77	3	]	]	PUNCT
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eurjchem-414	77	6	.	.	PUNCT
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eurjchem-414	78	10	to	to	PART
eurjchem-414	78	11	be	be	AUX
eurjchem-414	78	12	a	a	DET
eurjchem-414	78	13	convenient	convenient	ADJ
eurjchem-414	78	14	solvent	solvent	NOUN
eurjchem-414	78	15	in	in	ADP
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eurjchem-414	78	18	.	.	PUNCT
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eurjchem-414	79	6	to	to	PART
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eurjchem-414	79	11	in	in	ADP
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eurjchem-414	79	14	acid	acid	NOUN
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eurjchem-414	79	18	(	(	PUNCT
eurjchem-414	79	19	5‐8	5‐8	NOUN
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eurjchem-414	80	4	5‐8	5‐8	PROPN
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eurjchem-414	80	9	uv	uv	PROPN
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eurjchem-414	80	16	13c	13c	NOUN
eurjchem-414	80	17	nmr	nmr	NOUN
eurjchem-414	80	18	(	(	PUNCT
eurjchem-414	80	19	2d	2d	NOUN
eurjchem-414	80	20	,	,	PUNCT
eurjchem-414	80	21	j‐mod	j‐mod	NOUN
eurjchem-414	80	22	,	,	PUNCT
eurjchem-414	80	23	hsqc	hsqc	NOUN
eurjchem-414	80	24	)	)	PUNCT
eurjchem-414	80	25	measurements	measurement	NOUN
eurjchem-414	80	26	.	.	PUNCT
eurjchem-414	81	1	their	their	PRON
eurjchem-414	81	2	spectra	spectra	NOUN
eurjchem-414	81	3	showed	show	VERB
eurjchem-414	81	4	a	a	DET
eurjchem-414	81	5	strong	strong	ADJ
eurjchem-414	81	6	band	band	NOUN
eurjchem-414	81	7	for	for	ADP
eurjchem-414	81	8	the	the	DET
eurjchem-414	81	9	carbonyl	carbonyl	NOUN
eurjchem-414	81	10	group	group	NOUN
eurjchem-414	81	11	at	at	ADP
eurjchem-414	81	12	(	(	PUNCT
eurjchem-414	81	13	1662‐1658	1662‐1658	NUM
eurjchem-414	81	14	cm‐1	cm‐1	NOUN
eurjchem-414	81	15	)	)	PUNCT
eurjchem-414	81	16	and	and	CCONJ
eurjchem-414	81	17	a	a	DET
eurjchem-414	81	18	band	band	NOUN
eurjchem-414	81	19	at	at	ADP
eurjchem-414	81	20	(	(	PUNCT
eurjchem-414	81	21	1636‐1630	1636‐1630	NUM
eurjchem-414	81	22	cm‐1	cm‐1	NOUN
eurjchem-414	81	23	)	)	PUNCT
eurjchem-414	81	24	for	for	ADP
eurjchem-414	81	25	c	c	NOUN
eurjchem-414	81	26	=	=	NOUN
eurjchem-414	81	27	n.	n.	NOUN
eurjchem-414	81	28	in	in	ADP
eurjchem-414	81	29	the	the	DET
eurjchem-414	81	30	1h	1h	NUM
eurjchem-414	81	31	nmr	nmr	NOUN
eurjchem-414	81	32	spectra	spectra	NOUN
eurjchem-414	81	33	of	of	ADP
eurjchem-414	81	34	2‐pyrazolines	2‐pyrazoline	NOUN
eurjchem-414	81	35	,	,	PUNCT
eurjchem-414	81	36	the	the	DET
eurjchem-414	81	37	three	three	NUM
eurjchem-414	81	38	hydrogen	hydrogen	NOUN
eurjchem-414	81	39	atoms	atom	NOUN
eurjchem-414	81	40	attached	attach	VERB
eurjchem-414	81	41	to	to	ADP
eurjchem-414	81	42	the	the	DET
eurjchem-414	81	43	c‐4	c‐4	NOUN
eurjchem-414	81	44	and	and	CCONJ
eurjchem-414	81	45	c‐5	c‐5	VERB
eurjchem-414	81	46	carbon	carbon	NOUN
eurjchem-414	81	47	atoms	atom	NOUN
eurjchem-414	81	48	of	of	ADP
eurjchem-414	81	49	the	the	DET
eurjchem-414	81	50	heterocyclic	heterocyclic	ADJ
eurjchem-414	81	51	ring	ring	NOUN
eurjchem-414	81	52	gave	give	VERB
eurjchem-414	81	53	an	an	DET
eurjchem-414	81	54	abx	abx	NOUN
eurjchem-414	81	55	spin	spin	NOUN
eurjchem-414	81	56	system	system	NOUN
eurjchem-414	81	57	and	and	CCONJ
eurjchem-414	81	58	a	a	DET
eurjchem-414	81	59	doublet	doublet	ADJ
eurjchem-414	81	60	signal	signal	NOUN
eurjchem-414	81	61	at	at	ADP
eurjchem-414	81	62	around	around	ADV
eurjchem-414	81	63	8.94	8.94	NUM
eurjchem-414	81	64	ppm	ppm	NOUN
eurjchem-414	81	65	,	,	PUNCT
eurjchem-414	81	66	which	which	PRON
eurjchem-414	81	67	refers	refer	VERB
eurjchem-414	81	68	to	to	ADP
eurjchem-414	81	69	the	the	DET
eurjchem-414	81	70	presence	presence	NOUN
eurjchem-414	81	71	of	of	ADP
eurjchem-414	81	72	n‐formyl	n‐formyl	PUNCT
eurjchem-414	81	73	group	group	NOUN
eurjchem-414	81	74	.	.	PUNCT
eurjchem-414	82	1	measured	measure	VERB
eurjchem-414	82	2	chemical	chemical	NOUN
eurjchem-414	82	3	shift	shift	NOUN
eurjchem-414	82	4	and	and	CCONJ
eurjchem-414	82	5	coupling	couple	VERB
eurjchem-414	82	6	constant	constant	ADJ
eurjchem-414	82	7	values	value	NOUN
eurjchem-414	82	8	prove	prove	VERB
eurjchem-414	82	9	the	the	DET
eurjchem-414	82	10	2‐	2‐	NUM
eurjchem-414	82	11	pyrazoline	pyrazoline	NOUN
eurjchem-414	82	12	structure	structure	NOUN
eurjchem-414	82	13	.	.	PUNCT
eurjchem-414	83	1	in	in	ADP
eurjchem-414	83	2	the	the	DET
eurjchem-414	83	3	13c	13c	NOUN
eurjchem-414	83	4	nmr	nmr	NOUN
eurjchem-414	83	5	spectra	spectra	NOUN
eurjchem-414	83	6	of	of	ADP
eurjchem-414	83	7	new	new	ADJ
eurjchem-414	83	8	1‐formyl‐3‐	1‐formyl‐3‐	NUM
eurjchem-414	83	9	phenyl‐5‐aryl‐2‐pyrazolines	phenyl‐5‐aryl‐2‐pyrazoline	NOUN
eurjchem-414	83	10	,	,	PUNCT
eurjchem-414	83	11	the	the	DET
eurjchem-414	83	12	chemical	chemical	NOUN
eurjchem-414	83	13	shift	shift	NOUN
eurjchem-414	83	14	values	value	NOUN
eurjchem-414	83	15	of	of	ADP
eurjchem-414	83	16	carbon	carbon	NOUN
eurjchem-414	83	17	atoms	atom	NOUN
eurjchem-414	83	18	c‐3	c‐3	NOUN
eurjchem-414	83	19	(	(	PUNCT
eurjchem-414	83	20	154‐156	154‐156	PROPN
eurjchem-414	83	21	ppm	ppm	NOUN
eurjchem-414	83	22	)	)	PUNCT
eurjchem-414	83	23	,	,	PUNCT
eurjchem-414	83	24	c‐4	c‐4	PROPN
eurjchem-414	83	25	(	(	PUNCT
eurjchem-414	83	26	41‐40	41‐40	NOUN
eurjchem-414	83	27	ppm	ppm	NOUN
eurjchem-414	83	28	)	)	PUNCT
eurjchem-414	83	29	and	and	CCONJ
eurjchem-414	83	30	c‐5	c‐5	NOUN
eurjchem-414	83	31	(	(	PUNCT
eurjchem-414	83	32	56‐58	56‐58	NOUN
eurjchem-414	83	33	ppm	ppm	NOUN
eurjchem-414	83	34	)	)	PUNCT
eurjchem-414	83	35	corroborate	corroborate	VERB
eurjchem-414	83	36	the	the	DET
eurjchem-414	83	37	2‐pyrazoline	2‐pyrazoline	NUM
eurjchem-414	83	38	structures	structure	NOUN
eurjchem-414	83	39	determined	determine	VERB
eurjchem-414	83	40	by	by	ADP
eurjchem-414	83	41	1h	1h	NUM
eurjchem-414	83	42	nmr	nmr	NOUN
eurjchem-414	83	43	spectroscopic	spectroscopic	ADJ
eurjchem-414	83	44	measurements	measurement	NOUN
eurjchem-414	83	45	.	.	PUNCT
eurjchem-414	84	1	13c	13c	NOUN
eurjchem-414	84	2	nmr	nmr	NOUN
eurjchem-414	84	3	chemical	chemical	ADJ
eurjchem-414	84	4	shifts	shift	NOUN
eurjchem-414	84	5	of	of	ADP
eurjchem-414	84	6	the	the	DET
eurjchem-414	84	7	n‐formyl	n‐formyl	PUNCT
eurjchem-414	84	8	group	group	NOUN
eurjchem-414	84	9	have	have	AUX
eurjchem-414	84	10	been	be	AUX
eurjchem-414	84	11	assigned	assign	VERB
eurjchem-414	84	12	at	at	ADP
eurjchem-414	84	13	(	(	PUNCT
eurjchem-414	84	14	159‐160	159‐160	NUM
eurjchem-414	84	15	ppm	ppm	NOUN
eurjchem-414	84	16	)	)	PUNCT
eurjchem-414	84	17	.	.	PUNCT
eurjchem-414	85	1	the	the	DET
eurjchem-414	85	2	electronic	electronic	ADJ
eurjchem-414	85	3	spectra	spectra	NOUN
eurjchem-414	85	4	of	of	ADP
eurjchem-414	85	5	the	the	DET
eurjchem-414	85	6	pyrazolines	pyrazoline	NOUN
eurjchem-414	85	7	derivatives	derivative	NOUN
eurjchem-414	85	8	(	(	PUNCT
eurjchem-414	85	9	studied	study	VERB
eurjchem-414	85	10	in	in	ADP
eurjchem-414	85	11	the	the	DET
eurjchem-414	85	12	uv	uv	NOUN
eurjchem-414	85	13	region	region	NOUN
eurjchem-414	85	14	)	)	PUNCT
eurjchem-414	85	15	in	in	ADP
eurjchem-414	85	16	ethanol	ethanol	NOUN
eurjchem-414	85	17	showed	show	VERB
eurjchem-414	85	18	three	three	NUM
eurjchem-414	85	19	absorption	absorption	NOUN
eurjchem-414	85	20	bands	band	NOUN
eurjchem-414	85	21	at	at	ADP
eurjchem-414	85	22	(	(	PUNCT
eurjchem-414	85	23	321‐325	321‐325	PROPN
eurjchem-414	85	24	nm	nm	PROPN
eurjchem-414	85	25	)	)	PUNCT
eurjchem-414	85	26	,	,	PUNCT
eurjchem-414	85	27	(	(	PUNCT
eurjchem-414	85	28	334‐337	334‐337	NOUN
eurjchem-414	85	29	nm	nm	NOUN
eurjchem-414	85	30	)	)	PUNCT
eurjchem-414	85	31	,	,	PUNCT
eurjchem-414	85	32	(	(	PUNCT
eurjchem-414	85	33	404‐409	404‐409	NUM
eurjchem-414	85	34	nm	nm	NOUN
eurjchem-414	85	35	)	)	PUNCT
eurjchem-414	85	36	assignable	assignable	ADJ
eurjchem-414	85	37	to	to	ADP
eurjchem-414	85	38	n‐π	n‐π	NOUN
eurjchem-414	85	39	*	*	PROPN
eurjchem-414	85	40	,	,	PUNCT
eurjchem-414	85	41	π‐π	π‐π	PROPN
eurjchem-414	85	42	*	*	PUNCT
eurjchem-414	85	43	and	and	CCONJ
eurjchem-414	85	44	n‐σ	n‐σ	NOUN
eurjchem-414	85	45	*	*	NOUN
eurjchem-414	85	46	transitions	transition	NOUN
eurjchem-414	85	47	.	.	PUNCT
eurjchem-414	86	1	substituted	substitute	VERB
eurjchem-414	86	2	pyrazolines	pyrazoline	NOUN
eurjchem-414	86	3	have	have	VERB
eurjchem-414	86	4	strong	strong	ADJ
eurjchem-414	86	5	fluorescence	fluorescence	NOUN
eurjchem-414	86	6	in	in	ADP
eurjchem-414	86	7	different	different	ADJ
eurjchem-414	86	8	solvents	solvent	NOUN
eurjchem-414	86	9	.	.	PUNCT
eurjchem-414	87	1	they	they	PRON
eurjchem-414	87	2	also	also	ADV
eurjchem-414	87	3	give	give	VERB
eurjchem-414	87	4	excellent	excellent	ADJ
eurjchem-414	87	5	fluorescence	fluorescence	NOUN
eurjchem-414	87	6	properties	property	NOUN
eurjchem-414	87	7	in	in	ADP
eurjchem-414	87	8	solid	solid	ADJ
eurjchem-414	87	9	state	state	NOUN
eurjchem-414	87	10	because	because	SCONJ
eurjchem-414	87	11	the	the	DET
eurjchem-414	87	12	conjugation	conjugation	NOUN
eurjchem-414	87	13	system	system	NOUN
eurjchem-414	87	14	contains	contain	VERB
eurjchem-414	87	15	two	two	NUM
eurjchem-414	87	16	nitrogen	nitrogen	NOUN
eurjchem-414	87	17	atoms	atom	NOUN
eurjchem-414	87	18	and	and	CCONJ
eurjchem-414	87	19	one	one	NUM
eurjchem-414	87	20	carbon	carbon	NOUN
eurjchem-414	87	21	atom	atom	NOUN
eurjchem-414	87	22	while	while	SCONJ
eurjchem-414	87	23	the	the	DET
eurjchem-414	87	24	other	other	ADJ
eurjchem-414	87	25	carbon	carbon	NOUN
eurjchem-414	87	26	atoms	atom	NOUN
eurjchem-414	87	27	are	be	AUX
eurjchem-414	87	28	sp3	sp3	ADV
eurjchem-414	87	29	hybridized	hybridize	VERB
eurjchem-414	87	30	.	.	PUNCT
eurjchem-414	88	1	4	4	X
eurjchem-414	88	2	.	.	X
eurjchem-414	88	3	conclusion	conclusion	NOUN
eurjchem-414	88	4	we	we	PRON
eurjchem-414	88	5	have	have	AUX
eurjchem-414	88	6	synthesized	synthesize	VERB
eurjchem-414	88	7	substituted	substitute	VERB
eurjchem-414	88	8	3‐phenyl‐5‐aryl‐2‐	3‐phenyl‐5‐aryl‐2‐	NUM
eurjchem-414	88	9	pyrazolines	pyrazoline	NOUN
eurjchem-414	88	10	by	by	ADP
eurjchem-414	88	11	the	the	DET
eurjchem-414	88	12	reaction	reaction	NOUN
eurjchem-414	88	13	of	of	ADP
eurjchem-414	88	14	hydrazine	hydrazine	NOUN
eurjchem-414	88	15	hydrate	hydrate	NOUN
eurjchem-414	88	16	and	and	CCONJ
eurjchem-414	88	17	chalcones	chalcone	NOUN
eurjchem-414	88	18	bearing	bear	VERB
eurjchem-414	88	19	a	a	DET
eurjchem-414	88	20	para‐substituted	para‐substitute	VERB
eurjchem-414	88	21	group	group	NOUN
eurjchem-414	88	22	in	in	ADP
eurjchem-414	88	23	their	their	PRON
eurjchem-414	88	24	benzaldehyde	benzaldehyde	NOUN
eurjchem-414	88	25	rings	ring	NOUN
eurjchem-414	88	26	.	.	PUNCT
eurjchem-414	89	1	these	these	DET
eurjchem-414	89	2	new	new	ADJ
eurjchem-414	89	3	substances	substance	NOUN
eurjchem-414	89	4	allow	allow	VERB
eurjchem-414	89	5	the	the	DET
eurjchem-414	89	6	investigation	investigation	NOUN
eurjchem-414	89	7	of	of	ADP
eurjchem-414	89	8	the	the	DET
eurjchem-414	89	9	possible	possible	ADJ
eurjchem-414	89	10	linkage	linkage	NOUN
eurjchem-414	89	11	of	of	ADP
eurjchem-414	89	12	the	the	DET
eurjchem-414	89	13	2‐pyrazolines	2‐pyrazoline	NOUN
eurjchem-414	89	14	to	to	ADP
eurjchem-414	89	15	various	various	ADJ
eurjchem-414	89	16	sites	site	NOUN
eurjchem-414	89	17	in	in	ADP
eurjchem-414	89	18	living	live	VERB
eurjchem-414	89	19	organisms	organism	NOUN
eurjchem-414	89	20	in	in	ADP
eurjchem-414	89	21	the	the	DET
eurjchem-414	89	22	course	course	NOUN
eurjchem-414	89	23	of	of	ADP
eurjchem-414	89	24	the	the	DET
eurjchem-414	89	25	investigation	investigation	NOUN
eurjchem-414	89	26	of	of	ADP
eurjchem-414	89	27	their	their	PRON
eurjchem-414	89	28	bioactivities	bioactivitie	NOUN
eurjchem-414	89	29	.	.	PUNCT
eurjchem-414	90	1	the	the	DET
eurjchem-414	90	2	new	new	ADJ
eurjchem-414	90	3	1‐formyl‐3‐phenyl‐5‐aryl‐2‐pyrazolines	1‐formyl‐3‐phenyl‐5‐aryl‐2‐pyrazolines	PROPN
eurjchem-414	90	4	described	describe	VERB
eurjchem-414	90	5	in	in	ADP
eurjchem-414	90	6	this	this	DET
eurjchem-414	90	7	paper	paper	NOUN
eurjchem-414	90	8	are	be	AUX
eurjchem-414	90	9	very	very	ADV
eurjchem-414	90	10	stable	stable	ADJ
eurjchem-414	90	11	compounds	compound	NOUN
eurjchem-414	90	12	,	,	PUNCT
eurjchem-414	90	13	a	a	DET
eurjchem-414	90	14	property	property	NOUN
eurjchem-414	90	15	which	which	PRON
eurjchem-414	90	16	may	may	AUX
eurjchem-414	90	17	render	render	VERB
eurjchem-414	90	18	them	they	PRON
eurjchem-414	90	19	especially	especially	ADV
eurjchem-414	90	20	useful	useful	ADJ
eurjchem-414	90	21	substances	substance	NOUN
eurjchem-414	90	22	in	in	ADP
eurjchem-414	90	23	drug	drug	NOUN
eurjchem-414	90	24	research	research	NOUN
eurjchem-414	90	25	.	.	PUNCT
eurjchem-414	91	1	acknowledgement	acknowledgement	NOUN
eurjchem-414	91	2	we	we	PRON
eurjchem-414	91	3	thank	thank	VERB
eurjchem-414	91	4	the	the	DET
eurjchem-414	91	5	director	director	NOUN
eurjchem-414	91	6	of	of	ADP
eurjchem-414	91	7	the	the	DET
eurjchem-414	91	8	laboratory	laboratory	NOUN
eurjchem-414	91	9	of	of	ADP
eurjchem-414	91	10	applied	apply	VERB
eurjchem-414	91	11	chemistry	chemistry	NOUN
eurjchem-414	91	12	and	and	CCONJ
eurjchem-414	91	13	materials	material	NOUN
eurjchem-414	91	14	technology	technology	NOUN
eurjchem-414	91	15	of	of	ADP
eurjchem-414	91	16	the	the	DET
eurjchem-414	91	17	university	university	PROPN
eurjchem-414	91	18	of	of	ADP
eurjchem-414	91	19	oum	oum	PROPN
eurjchem-414	91	20	el	el	PROPN
eurjchem-414	91	21	bouaghi	bouaghi	PROPN
eurjchem-414	91	22	for	for	ADP
eurjchem-414	91	23	his	his	PRON
eurjchem-414	91	24	support	support	NOUN
eurjchem-414	91	25	of	of	ADP
eurjchem-414	91	26	this	this	DET
eurjchem-414	91	27	work	work	NOUN
eurjchem-414	91	28	.	.	PUNCT
eurjchem-414	92	1	we	we	PRON
eurjchem-414	92	2	gratefully	gratefully	ADV
eurjchem-414	92	3	acknowledge	acknowledge	VERB
eurjchem-414	92	4	philippe	philippe	PROPN
eurjchem-414	92	5	jehan	jehan	PROPN
eurjchem-414	92	6	and	and	CCONJ
eurjchem-414	92	7	muriel	muriel	PROPN
eurjchem-414	92	8	escadeillas	escadeillas	PROPN
eurjchem-414	92	9	for	for	ADP
eurjchem-414	92	10	providing	provide	VERB
eurjchem-414	92	11	elemental	elemental	ADJ
eurjchem-414	92	12	analysis	analysis	NOUN
eurjchem-414	92	13	.	.	PUNCT
eurjchem-414	93	1	references	reference	NOUN
eurjchem-414	93	2	[	[	X
eurjchem-414	93	3	1	1	NUM
eurjchem-414	93	4	]	]	PUNCT
eurjchem-414	93	5	.	.	PUNCT
eurjchem-414	94	1	zhang	zhang	PROPN
eurjchem-414	94	2	,	,	PUNCT
eurjchem-414	94	3	x.	x.	PROPN
eurjchem-414	94	4	h.	h.	PROPN
eurjchem-414	94	5	;	;	PUNCT
eurjchem-414	94	6	wu	wu	PROPN
eurjchem-414	94	7	,	,	PUNCT
eurjchem-414	94	8	s.	s.	PROPN
eurjchem-414	94	9	k.	k.	PROPN
eurjchem-414	94	10	;	;	PUNCT
eurjchem-414	94	11	gao	gao	PROPN
eurjchem-414	94	12	,	,	PUNCT
eurjchem-414	94	13	z.	z.	PROPN
eurjchem-414	94	14	q.	q.	PROPN
eurjchem-414	94	15	;	;	PUNCT
eurjchem-414	94	16	lee	lee	PROPN
eurjchem-414	94	17	,	,	PUNCT
eurjchem-414	94	18	c.	c.	PROPN
eurjchem-414	94	19	s.	s.	PROPN
eurjchem-414	94	20	;	;	PUNCT
eurjchem-414	94	21	lee	lee	PROPN
eurjchem-414	94	22	,	,	PUNCT
eurjchem-414	94	23	s.	s.	PROPN
eurjchem-414	94	24	t.	t.	PROPN
eurjchem-414	94	25	;	;	PUNCT
eurjchem-414	94	26	kwong	kwong	PROPN
eurjchem-414	94	27	,	,	PUNCT
eurjchem-414	94	28	h.	h.	PROPN
eurjchem-414	94	29	l.	l.	PROPN
eurjchem-414	94	30	thin	thin	PROPN
eurjchem-414	94	31	solid	solid	ADJ
eurjchem-414	94	32	films	film	NOUN
eurjchem-414	94	33	2000	2000	NUM
eurjchem-414	94	34	,	,	PUNCT
eurjchem-414	94	35	371	371	NUM
eurjchem-414	94	36	,	,	PUNCT
eurjchem-414	94	37	40‐46	40‐46	NUM
eurjchem-414	94	38	.	.	PUNCT
eurjchem-414	95	1	[	[	X
eurjchem-414	95	2	2	2	NUM
eurjchem-414	95	3	]	]	PUNCT
eurjchem-414	95	4	.	.	PUNCT
eurjchem-414	95	5	ramalingam	ramalingam	PROPN
eurjchem-414	95	6	,	,	PUNCT
eurjchem-414	95	7	k.	k.	PROPN
eurjchem-414	95	8	;	;	PUNCT
eurjchem-414	95	9	thyvekikakath	thyvekikakath	NOUN
eurjchem-414	95	10	,	,	PUNCT
eurjchem-414	95	11	g.	g.	PROPN
eurjchem-414	95	12	x.	x.	PROPN
eurjchem-414	95	13	;	;	PUNCT
eurjchem-414	95	14	berlin	berlin	PROPN
eurjchem-414	95	15	,	,	PUNCT
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eurjchem-414	142	21	a.	a.	PROPN
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eurjchem-414	142	30	a.	a.	PROPN
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eurjchem-414	142	42	,	,	PUNCT
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eurjchem-414	142	46	.	.	PUNCT
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eurjchem-414	143	2	16	16	NUM
eurjchem-414	143	3	]	]	PUNCT
eurjchem-414	143	4	.	.	PUNCT
eurjchem-414	144	1	tóth	tóth	PROPN
eurjchem-414	144	2	,	,	PUNCT
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eurjchem-414	145	1	[	[	X
eurjchem-414	145	2	17	17	NUM
eurjchem-414	145	3	]	]	PUNCT
eurjchem-414	145	4	.	.	PUNCT
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eurjchem-414	146	2	,	,	PUNCT
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eurjchem-414	146	42	j.	j.	PROPN
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eurjchem-414	147	2	.	.	PUNCT
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eurjchem-414	148	2	,	,	PUNCT
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eurjchem-414	148	4	,	,	PUNCT
eurjchem-414	148	5	3254‐	3254‐	NUM
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eurjchem-414	148	7	.	.	PUNCT
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eurjchem-414	149	2	18	18	NUM
eurjchem-414	149	3	]	]	PUNCT
eurjchem-414	149	4	.	.	PUNCT
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eurjchem-414	149	8	;	;	PUNCT
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eurjchem-414	149	10	,	,	PUNCT
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eurjchem-414	149	12	;	;	PUNCT
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eurjchem-414	149	14	,	,	PUNCT
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eurjchem-414	149	22	.	.	PUNCT
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eurjchem-414	150	2	.	.	PUNCT
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eurjchem-414	151	3	.	.	PROPN
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eurjchem-414	151	6	,	,	PUNCT
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eurjchem-414	152	3	]	]	PUNCT
eurjchem-414	152	4	.	.	PUNCT
eurjchem-414	153	1	tóth	tóth	PROPN
eurjchem-414	153	2	,	,	PUNCT
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eurjchem-414	153	4	;	;	PUNCT
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eurjchem-414	153	6	,	,	PUNCT
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eurjchem-414	153	8	;	;	PUNCT
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eurjchem-414	153	10	,	,	PUNCT
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eurjchem-414	155	2	.	.	PUNCT
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eurjchem-414	156	2	,	,	PUNCT
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eurjchem-414	156	4	,	,	PUNCT
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eurjchem-414	156	6	.	.	PUNCT
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eurjchem-414	157	4	.	.	PUNCT
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eurjchem-414	158	2	,	,	PUNCT
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eurjchem-414	158	6	,	,	PUNCT
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eurjchem-414	158	8	;	;	PUNCT
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eurjchem-414	158	10	,	,	PUNCT
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eurjchem-414	158	12	;	;	PUNCT
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eurjchem-414	158	14	,	,	PUNCT
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eurjchem-414	159	4	.	.	PUNCT
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eurjchem-414	160	2	,	,	PUNCT
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eurjchem-414	160	4	;	;	PUNCT
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eurjchem-414	160	6	,	,	PUNCT
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eurjchem-414	160	8	;	;	PUNCT
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eurjchem-414	160	13	.	.	PUNCT
eurjchem-414	161	1	j.	j.	PROPN
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eurjchem-414	161	3	.	.	PUNCT
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eurjchem-414	162	2	,	,	PUNCT
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eurjchem-414	162	4	,	,	PUNCT
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eurjchem-414	162	6	.	.	PUNCT
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eurjchem-414	163	4	.	.	PUNCT
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eurjchem-414	164	2	,	,	PUNCT
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eurjchem-414	164	4	;	;	PUNCT
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eurjchem-414	164	6	,	,	PUNCT
eurjchem-414	164	7	j.	j.	PROPN
eurjchem-414	164	8	;	;	PUNCT
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eurjchem-414	164	10	,	,	PUNCT
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eurjchem-414	164	14	,	,	PUNCT
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eurjchem-414	165	4	.	.	PUNCT
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eurjchem-414	166	2	,	,	PUNCT
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eurjchem-414	166	5	;	;	PUNCT
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eurjchem-414	166	10	;	;	PUNCT
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eurjchem-414	167	2	.	.	PUNCT
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eurjchem-414	168	2	,	,	PUNCT
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eurjchem-414	168	4	,	,	PUNCT
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eurjchem-414	170	7	,	,	PUNCT
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eurjchem-414	170	10	j.	j.	PROPN
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eurjchem-414	170	12	.	.	PUNCT
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eurjchem-414	170	14	.	.	PUNCT
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eurjchem-414	171	2	,	,	PUNCT
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eurjchem-414	173	4	;	;	PUNCT
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eurjchem-414	175	2	.	.	PUNCT
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eurjchem-414	176	2	,	,	PUNCT
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eurjchem-414	176	4	,	,	PUNCT
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