id	sid	tid	token	lemma	pos
eurjchem-597	1	1	untitled	untitle	VERB
eurjchem-597	1	2	european	european	PROPN
eurjchem-597	1	3	journal	journal	PROPN
eurjchem-597	1	4	of	of	ADP
eurjchem-597	1	5	chemistry	chemistry	NOUN
eurjchem-597	1	6	3	3	NUM
eurjchem-597	1	7	(	(	PUNCT
eurjchem-597	1	8	2	2	NUM
eurjchem-597	1	9	)	)	PUNCT
eurjchem-597	1	10	(	(	PUNCT
eurjchem-597	1	11	2012	2012	NUM
eurjchem-597	1	12	)	)	PUNCT
eurjchem-597	1	13	241‐246	241‐246	NUM
eurjchem-597	1	14	european	european	ADJ
eurjchem-597	1	15	journal	journal	PROPN
eurjchem-597	1	16	of	of	ADP
eurjchem-597	1	17	chemistry	chemistry	NOUN
eurjchem-597	1	18	issn	issn	PROPN
eurjchem-597	1	19	2153‐2249	2153‐2249	PROPN
eurjchem-597	1	20	(	(	PUNCT
eurjchem-597	1	21	print	print	NOUN
eurjchem-597	1	22	)	)	PUNCT
eurjchem-597	1	23	/	/	SYM
eurjchem-597	1	24	issn	issn	PROPN
eurjchem-597	1	25	2153‐2257	2153‐2257	NUM
eurjchem-597	1	26	(	(	PUNCT
eurjchem-597	1	27	online	online	ADJ
eurjchem-597	1	28	)	)	PUNCT
eurjchem-597	1	29			NOUN
eurjchem-597	1	30	2012	2012	NUM
eurjchem-597	1	31	eurjchem	eurjchem	PROPN
eurjchem-597	1	32	doi:10.5155	doi:10.5155	PROPN
eurjchem-597	1	33	/	/	SYM
eurjchem-597	1	34	eurjchem.3.2.241‐246.597	eurjchem.3.2.241‐246.597	ADJ
eurjchem-597	1	35	european	european	ADJ
eurjchem-597	1	36	journal	journal	PROPN
eurjchem-597	1	37	of	of	ADP
eurjchem-597	1	38	chemistry	chemistry	PROPN
eurjchem-597	1	39	journal	journal	PROPN
eurjchem-597	1	40	homepage	homepage	NOUN
eurjchem-597	1	41	:	:	PUNCT
eurjchem-597	1	42	www.eurjchem.com	www.eurjchem.com	X
eurjchem-597	1	43	synthesis	synthesis	NOUN
eurjchem-597	1	44	of	of	ADP
eurjchem-597	1	45	some	some	DET
eurjchem-597	1	46	new	new	ADJ
eurjchem-597	1	47	s‐glycosyl	s‐glycosyl	PUNCT
eurjchem-597	1	48	pyrimidine	pyrimidine	NOUN
eurjchem-597	1	49	and	and	CCONJ
eurjchem-597	1	50	condensed	condensed	ADJ
eurjchem-597	1	51	pyrimidine	pyrimidine	NOUN
eurjchem-597	1	52	derivatives	derivative	NOUN
eurjchem-597	1	53	wesam	wesam	VERB
eurjchem-597	1	54	saber	saber	NOUN
eurjchem-597	1	55	shehab	shehab	PROPN
eurjchem-597	1	56	*	*	PUNCT
eurjchem-597	1	57	and	and	CCONJ
eurjchem-597	1	58	enaiat	enaiat	PROPN
eurjchem-597	1	59	kamel	kamel	PROPN
eurjchem-597	1	60	mohamed	mohamed	PROPN
eurjchem-597	1	61	department	department	PROPN
eurjchem-597	1	62	of	of	ADP
eurjchem-597	1	63	chemistry	chemistry	NOUN
eurjchem-597	1	64	,	,	PUNCT
eurjchem-597	1	65	faculty	faculty	NOUN
eurjchem-597	1	66	of	of	ADP
eurjchem-597	1	67	science	science	NOUN
eurjchem-597	1	68	,	,	PUNCT
eurjchem-597	1	69	zagazig	zagazig	PROPN
eurjchem-597	1	70	university	university	PROPN
eurjchem-597	1	71	,	,	PUNCT
eurjchem-597	1	72	zagazig	zagazig	PROPN
eurjchem-597	1	73	,	,	PUNCT
eurjchem-597	1	74	44511	44511	NUM
eurjchem-597	1	75	,	,	PUNCT
eurjchem-597	1	76	egypt	egypt	PROPN
eurjchem-597	1	77	*	*	PUNCT
eurjchem-597	1	78	corresponding	correspond	VERB
eurjchem-597	1	79	author	author	NOUN
eurjchem-597	1	80	at	at	ADP
eurjchem-597	1	81	:	:	PUNCT
eurjchem-597	1	82	department	department	NOUN
eurjchem-597	1	83	of	of	ADP
eurjchem-597	1	84	chemistry	chemistry	NOUN
eurjchem-597	1	85	,	,	PUNCT
eurjchem-597	1	86	faculty	faculty	NOUN
eurjchem-597	1	87	of	of	ADP
eurjchem-597	1	88	science	science	NOUN
eurjchem-597	1	89	,	,	PUNCT
eurjchem-597	1	90	zagazig	zagazig	PROPN
eurjchem-597	1	91	university	university	PROPN
eurjchem-597	1	92	,	,	PUNCT
eurjchem-597	1	93	zagazig	zagazig	PROPN
eurjchem-597	1	94	,	,	PUNCT
eurjchem-597	1	95	44511	44511	NUM
eurjchem-597	1	96	,	,	PUNCT
eurjchem-597	1	97	egypt	egypt	PROPN
eurjchem-597	1	98	.	.	PUNCT
eurjchem-597	2	1	tel	tel	PROPN
eurjchem-597	2	2	.	.	PUNCT
eurjchem-597	2	3	:	:	PUNCT
eurjchem-597	3	1	+2.011.9720874	+2.011.9720874	NOUN
eurjchem-597	3	2	;	;	PUNCT
eurjchem-597	3	3	fax	fax	NOUN
eurjchem-597	3	4	:	:	PUNCT
eurjchem-597	3	5	+2.055.2285374	+2.055.2285374	PROPN
eurjchem-597	3	6	.	.	PUNCT
eurjchem-597	3	7	e‐mail	e‐mail	PUNCT
eurjchem-597	4	1	address	address	NOUN
eurjchem-597	4	2	:	:	PUNCT
eurjchem-597	4	3	dr_wesam123@yahoo.com	dr_wesam123@yahoo.com	X
eurjchem-597	4	4	(	(	PUNCT
eurjchem-597	4	5	w.	w.	PROPN
eurjchem-597	4	6	shehab	shehab	PROPN
eurjchem-597	4	7	)	)	PUNCT
eurjchem-597	4	8	.	.	PUNCT
eurjchem-597	5	1	article	article	NOUN
eurjchem-597	5	2	information	information	PROPN
eurjchem-597	5	3	abstract	abstract	ADV
eurjchem-597	5	4	received	receive	VERB
eurjchem-597	5	5	:	:	PUNCT
eurjchem-597	5	6	10	10	NUM
eurjchem-597	5	7	february	february	NOUN
eurjchem-597	5	8	2012	2012	NUM
eurjchem-597	5	9	received	receive	VERB
eurjchem-597	5	10	in	in	ADP
eurjchem-597	5	11	revised	revise	VERB
eurjchem-597	5	12	form	form	NOUN
eurjchem-597	5	13	:	:	PUNCT
eurjchem-597	5	14	05	05	NUM
eurjchem-597	5	15	march	march	PROPN
eurjchem-597	5	16	2012	2012	NUM
eurjchem-597	5	17	accepted	accept	VERB
eurjchem-597	5	18	:	:	PUNCT
eurjchem-597	5	19	22	22	NUM
eurjchem-597	5	20	march	march	PROPN
eurjchem-597	5	21	2012	2012	NUM
eurjchem-597	5	22	online	online	NOUN
eurjchem-597	5	23	:	:	PUNCT
eurjchem-597	5	24	30	30	NUM
eurjchem-597	5	25	june	june	PROPN
eurjchem-597	5	26	2012	2012	NUM
eurjchem-597	5	27	keywords	keyword	NOUN
eurjchem-597	5	28	mercaptopyrimidine	mercaptopyrimidine	VERB
eurjchem-597	5	29	(	(	PUNCT
eurjchem-597	5	30	4	4	NUM
eurjchem-597	5	31	)	)	PUNCT
eurjchem-597	5	32	was	be	AUX
eurjchem-597	5	33	synthesized	synthesize	VERB
eurjchem-597	5	34	by	by	ADP
eurjchem-597	5	35	the	the	DET
eurjchem-597	5	36	reaction	reaction	NOUN
eurjchem-597	5	37	of	of	ADP
eurjchem-597	5	38	isothiocyanate	isothiocyanate	NOUN
eurjchem-597	5	39	and	and	CCONJ
eurjchem-597	5	40	acrylate	acrylate	NOUN
eurjchem-597	5	41	(	(	PUNCT
eurjchem-597	5	42	1	1	NUM
eurjchem-597	5	43	)	)	PUNCT
eurjchem-597	5	44	.	.	PUNCT
eurjchem-597	6	1	it	it	PRON
eurjchem-597	6	2	was	be	AUX
eurjchem-597	6	3	allowed	allow	VERB
eurjchem-597	6	4	to	to	PART
eurjchem-597	6	5	react	react	VERB
eurjchem-597	6	6	with	with	ADP
eurjchem-597	6	7	preacetylated	preacetylate	VERB
eurjchem-597	6	8	sugar	sugar	NOUN
eurjchem-597	6	9	bromide	bromide	NOUN
eurjchem-597	6	10	and/or	and/or	CCONJ
eurjchem-597	6	11	halomethylene	halomethylene	PROPN
eurjchem-597	6	12	derivatives	derivative	NOUN
eurjchem-597	6	13	to	to	PART
eurjchem-597	6	14	produce	produce	VERB
eurjchem-597	6	15	alkylated	alkylate	VERB
eurjchem-597	6	16	pyrimidines	pyrimidine	NOUN
eurjchem-597	6	17	(	(	PUNCT
eurjchem-597	6	18	5,7a‐d	5,7a‐d	NUM
eurjchem-597	6	19	)	)	PUNCT
eurjchem-597	6	20	.	.	PUNCT
eurjchem-597	7	1	hydrolysis	hydrolysis	NOUN
eurjchem-597	7	2	of	of	ADP
eurjchem-597	7	3	compound	compound	NOUN
eurjchem-597	7	4	(	(	PUNCT
eurjchem-597	7	5	5	5	NUM
eurjchem-597	7	6	)	)	PUNCT
eurjchem-597	7	7	produced	produce	VERB
eurjchem-597	7	8	compound	compound	NOUN
eurjchem-597	7	9	(	(	PUNCT
eurjchem-597	7	10	6	6	NUM
eurjchem-597	7	11	)	)	PUNCT
eurjchem-597	7	12	.	.	PUNCT
eurjchem-597	8	1	interacyclization	interacyclization	NOUN
eurjchem-597	8	2	of	of	ADP
eurjchem-597	8	3	compounds	compound	NOUN
eurjchem-597	8	4	(	(	PUNCT
eurjchem-597	8	5	7a‐d	7a‐d	NOUN
eurjchem-597	8	6	)	)	PUNCT
eurjchem-597	8	7	afforded	afford	VERB
eurjchem-597	8	8	thienopyrimidines	thienopyrimidine	NOUN
eurjchem-597	8	9	(	(	PUNCT
eurjchem-597	8	10	8a‐d	8a‐d	ADV
eurjchem-597	8	11	)	)	PUNCT
eurjchem-597	8	12	.	.	PUNCT
eurjchem-597	9	1	moreover	moreover	ADV
eurjchem-597	9	2	oxidation	oxidation	NOUN
eurjchem-597	9	3	of	of	ADP
eurjchem-597	9	4	compound	compound	NOUN
eurjchem-597	9	5	(	(	PUNCT
eurjchem-597	9	6	7b	7b	NOUN
eurjchem-597	9	7	)	)	PUNCT
eurjchem-597	9	8	gave	give	VERB
eurjchem-597	9	9	the	the	DET
eurjchem-597	9	10	corresponding	correspond	VERB
eurjchem-597	9	11	thienopyrimidine	thienopyrimidine	NOUN
eurjchem-597	9	12	dioxide	dioxide	NOUN
eurjchem-597	9	13	(	(	PUNCT
eurjchem-597	9	14	9	9	NUM
eurjchem-597	9	15	)	)	PUNCT
eurjchem-597	9	16	.	.	PUNCT
eurjchem-597	10	1	cyanoethylation	cyanoethylation	NOUN
eurjchem-597	10	2	of	of	ADP
eurjchem-597	10	3	compound	compound	NOUN
eurjchem-597	10	4	(	(	PUNCT
eurjchem-597	10	5	4	4	NUM
eurjchem-597	10	6	)	)	PUNCT
eurjchem-597	10	7	afforded	afford	VERB
eurjchem-597	10	8	compound	compound	NOUN
eurjchem-597	10	9	(	(	PUNCT
eurjchem-597	10	10	10	10	NUM
eurjchem-597	10	11	)	)	PUNCT
eurjchem-597	10	12	that	that	PRON
eurjchem-597	10	13	reacted	react	VERB
eurjchem-597	10	14	with	with	ADP
eurjchem-597	10	15	hydrazine	hydrazine	NOUN
eurjchem-597	10	16	hydrate	hydrate	NOUN
eurjchem-597	10	17	to	to	PART
eurjchem-597	10	18	give	give	VERB
eurjchem-597	10	19	pyrazolopyrimidine	pyrazolopyrimidine	ADJ
eurjchem-597	10	20	(	(	PUNCT
eurjchem-597	10	21	11	11	NUM
eurjchem-597	10	22	)	)	PUNCT
eurjchem-597	10	23	.	.	PUNCT
eurjchem-597	11	1	oxidation	oxidation	NOUN
eurjchem-597	11	2	of	of	ADP
eurjchem-597	11	3	compound	compound	NOUN
eurjchem-597	11	4	4	4	NUM
eurjchem-597	11	5	afforded	afford	VERB
eurjchem-597	11	6	bisulphide	bisulphide	ADV
eurjchem-597	11	7	(	(	PUNCT
eurjchem-597	11	8	12	12	NUM
eurjchem-597	11	9	)	)	PUNCT
eurjchem-597	11	10	.	.	PUNCT
eurjchem-597	12	1	the	the	DET
eurjchem-597	12	2	cycloaddition	cycloaddition	NOUN
eurjchem-597	12	3	product	product	NOUN
eurjchem-597	12	4	(	(	PUNCT
eurjchem-597	12	5	13	13	NUM
eurjchem-597	12	6	)	)	PUNCT
eurjchem-597	12	7	was	be	AUX
eurjchem-597	12	8	obtained	obtain	VERB
eurjchem-597	12	9	by	by	ADP
eurjchem-597	12	10	reaction	reaction	NOUN
eurjchem-597	12	11	of	of	ADP
eurjchem-597	12	12	compound	compound	NOUN
eurjchem-597	12	13	4	4	NUM
eurjchem-597	12	14	with	with	ADP
eurjchem-597	12	15	maleic	maleic	VERB
eurjchem-597	12	16	anhydride	anhydride	NOUN
eurjchem-597	12	17	.	.	PUNCT
eurjchem-597	13	1	pyrimidopyrimidine	pyrimidopyrimidine	PROPN
eurjchem-597	13	2	,	,	PUNCT
eurjchem-597	13	3	pyrimidopyridazine	pyrimidopyridazine	NOUN
eurjchem-597	13	4	and	and	CCONJ
eurjchem-597	13	5	tetrazolopyriminde	tetrazolopyriminde	VERB
eurjchem-597	13	6	derivatives	derivative	NOUN
eurjchem-597	13	7	(	(	PUNCT
eurjchem-597	13	8	16‐	16‐	NUM
eurjchem-597	13	9	20	20	NUM
eurjchem-597	13	10	)	)	PUNCT
eurjchem-597	13	11	were	be	AUX
eurjchem-597	13	12	obtained	obtain	VERB
eurjchem-597	13	13	by	by	ADP
eurjchem-597	13	14	reaction	reaction	NOUN
eurjchem-597	13	15	of	of	ADP
eurjchem-597	13	16	4‐chloropyrimidine	4‐chloropyrimidine	NOUN
eurjchem-597	13	17	(	(	PUNCT
eurjchem-597	13	18	15	15	NUM
eurjchem-597	13	19	)	)	PUNCT
eurjchem-597	13	20	with	with	ADP
eurjchem-597	13	21	thiourea	thiourea	NOUN
eurjchem-597	13	22	,	,	PUNCT
eurjchem-597	13	23	benzilhydrazone	benzilhydrazone	NOUN
eurjchem-597	13	24	and	and	CCONJ
eurjchem-597	13	25	sodium	sodium	NOUN
eurjchem-597	13	26	azide	azide	NOUN
eurjchem-597	13	27	,	,	PUNCT
eurjchem-597	13	28	respectively	respectively	ADV
eurjchem-597	13	29	.	.	PUNCT
eurjchem-597	14	1	n‐alkylated	n‐alkylate	VERB
eurjchem-597	14	2	pyrazolopyrimidine	pyrazolopyrimidine	ADJ
eurjchem-597	14	3	(	(	PUNCT
eurjchem-597	14	4	21	21	NUM
eurjchem-597	14	5	)	)	PUNCT
eurjchem-597	14	6	was	be	AUX
eurjchem-597	14	7	obtained	obtain	VERB
eurjchem-597	14	8	by	by	ADP
eurjchem-597	14	9	reaction	reaction	NOUN
eurjchem-597	14	10	of	of	ADP
eurjchem-597	14	11	compound	compound	NOUN
eurjchem-597	14	12	(	(	PUNCT
eurjchem-597	14	13	15	15	NUM
eurjchem-597	14	14	)	)	PUNCT
eurjchem-597	14	15	with	with	ADP
eurjchem-597	14	16	acetophenonehydrazone	acetophenonehydrazone	NOUN
eurjchem-597	14	17	.	.	PUNCT
eurjchem-597	15	1	s‐glycosyl	s‐glycosyl	PUNCT
eurjchem-597	15	2	thienopyrimidine	thienopyrimidine	NOUN
eurjchem-597	15	3	s‐alkyl	s‐alkyl	SYM
eurjchem-597	15	4	pyrimidine	pyrimidine	NOUN
eurjchem-597	15	5	pyrimidopyrimidine	pyrimidopyrimidine	NOUN
eurjchem-597	15	6	mercaptopyrimidine	mercaptopyrimidine	PROPN
eurjchem-597	15	7	tetrazolopyrimindine	tetrazolopyrimindine	NOUN
eurjchem-597	15	8	derivatives	derivative	NOUN
eurjchem-597	15	9	1	1	NUM
eurjchem-597	15	10	.	.	PUNCT
eurjchem-597	16	1	introduction	introduction	NOUN
eurjchem-597	16	2	pyrimidines	pyrimidine	NOUN
eurjchem-597	16	3	and	and	CCONJ
eurjchem-597	16	4	heterocyclic	heterocyclic	ADJ
eurjchem-597	16	5	annulated	annulate	VERB
eurjchem-597	16	6	pyrimidines	pyrimidine	NOUN
eurjchem-597	16	7	exhibit	exhibit	VERB
eurjchem-597	16	8	interesting	interesting	ADJ
eurjchem-597	16	9	biological	biological	ADJ
eurjchem-597	16	10	activities	activity	NOUN
eurjchem-597	16	11	as	as	ADP
eurjchem-597	16	12	medicinal	medicinal	ADJ
eurjchem-597	16	13	applications	application	NOUN
eurjchem-597	16	14	[	[	X
eurjchem-597	16	15	1‐3	1‐3	X
eurjchem-597	16	16	]	]	X
eurjchem-597	16	17	.	.	PUNCT
eurjchem-597	17	1	a	a	DET
eurjchem-597	17	2	variety	variety	NOUN
eurjchem-597	17	3	of	of	ADP
eurjchem-597	17	4	anticancer	anticancer	NOUN
eurjchem-597	17	5	drugs	drug	NOUN
eurjchem-597	17	6	made	make	VERB
eurjchem-597	17	7	from	from	ADP
eurjchem-597	17	8	pyrimidine	pyrimidine	NOUN
eurjchem-597	17	9	derivatives	derivative	NOUN
eurjchem-597	17	10	have	have	VERB
eurjchem-597	17	11	clinical	clinical	ADJ
eurjchem-597	17	12	use	use	NOUN
eurjchem-597	17	13	currently	currently	ADV
eurjchem-597	17	14	,	,	PUNCT
eurjchem-597	17	15	the	the	DET
eurjchem-597	17	16	hydrazinopyrimidine‐s‐	hydrazinopyrimidine‐s‐	NOUN
eurjchem-597	17	17	carbonitrile	carbonitrile	ADJ
eurjchem-597	17	18	derivatives	derivative	NOUN
eurjchem-597	17	19	have	have	VERB
eurjchem-597	17	20	antineoplastic	antineoplastic	ADJ
eurjchem-597	17	21	activities	activity	NOUN
eurjchem-597	17	22	[	[	X
eurjchem-597	17	23	4	4	NUM
eurjchem-597	17	24	]	]	PUNCT
eurjchem-597	17	25	.	.	PUNCT
eurjchem-597	18	1	moreover	moreover	ADV
eurjchem-597	18	2	,	,	PUNCT
eurjchem-597	18	3	pyrimidines	pyrimidine	NOUN
eurjchem-597	18	4	and	and	CCONJ
eurjchem-597	18	5	condensed	condense	VERB
eurjchem-597	18	6	pyrimidines	pyrimidine	NOUN
eurjchem-597	18	7	are	be	AUX
eurjchem-597	18	8	important	important	ADJ
eurjchem-597	18	9	classes	class	NOUN
eurjchem-597	18	10	of	of	ADP
eurjchem-597	18	11	heterocyclic	heterocyclic	ADJ
eurjchem-597	18	12	compounds	compound	NOUN
eurjchem-597	18	13	that	that	PRON
eurjchem-597	18	14	exhibit	exhibit	VERB
eurjchem-597	18	15	broad	broad	ADJ
eurjchem-597	18	16	spectrum	spectrum	NOUN
eurjchem-597	18	17	of	of	ADP
eurjchem-597	18	18	biological	biological	ADJ
eurjchem-597	18	19	activities	activity	NOUN
eurjchem-597	18	20	such	such	ADJ
eurjchem-597	18	21	as	as	ADP
eurjchem-597	18	22	anticancer	anticancer	NOUN
eurjchem-597	18	23	[	[	X
eurjchem-597	18	24	5,6	5,6	NUM
eurjchem-597	18	25	]	]	PUNCT
eurjchem-597	18	26	,	,	PUNCT
eurjchem-597	18	27	anti‐	anti‐	PROPN
eurjchem-597	18	28	inflammatory	inflammatory	ADJ
eurjchem-597	18	29	,	,	PUNCT
eurjchem-597	18	30	anti	anti	ADJ
eurjchem-597	18	31	‐allergic	‐allergic	ADJ
eurjchem-597	18	32	and	and	CCONJ
eurjchem-597	18	33	analgesic	analgesic	ADJ
eurjchem-597	18	34	activity	activity	NOUN
eurjchem-597	18	35	[	[	X
eurjchem-597	18	36	7‐9	7‐9	NOUN
eurjchem-597	18	37	]	]	X
eurjchem-597	18	38	.	.	PUNCT
eurjchem-597	19	1	in	in	ADP
eurjchem-597	19	2	continuation	continuation	NOUN
eurjchem-597	19	3	of	of	ADP
eurjchem-597	19	4	our	our	PRON
eurjchem-597	19	5	efforts	effort	NOUN
eurjchem-597	19	6	in	in	ADP
eurjchem-597	19	7	this	this	DET
eurjchem-597	19	8	direction	direction	NOUN
eurjchem-597	19	9	,	,	PUNCT
eurjchem-597	19	10	we	we	PRON
eurjchem-597	19	11	synthesized	synthesize	VERB
eurjchem-597	19	12	some	some	DET
eurjchem-597	19	13	new	new	ADJ
eurjchem-597	19	14	pyrimidine	pyrimidine	NOUN
eurjchem-597	19	15	derivatives	derivative	NOUN
eurjchem-597	19	16	and	and	CCONJ
eurjchem-597	19	17	condensed	condense	VERB
eurjchem-597	19	18	pyrimidine	pyrimidine	NOUN
eurjchem-597	19	19	derivatives	derivative	NOUN
eurjchem-597	19	20	for	for	ADP
eurjchem-597	19	21	biological	biological	ADJ
eurjchem-597	19	22	evaluations	evaluation	NOUN
eurjchem-597	19	23	.	.	PUNCT
eurjchem-597	20	1	2	2	X
eurjchem-597	20	2	.	.	X
eurjchem-597	20	3	experimental	experimental	ADJ
eurjchem-597	20	4	2.1	2.1	NUM
eurjchem-597	20	5	.	.	PUNCT
eurjchem-597	21	1	instrumentation	instrumentation	NOUN
eurjchem-597	21	2	melting	melting	NOUN
eurjchem-597	21	3	points	point	NOUN
eurjchem-597	21	4	are	be	AUX
eurjchem-597	21	5	all	all	PRON
eurjchem-597	21	6	uncorrected	uncorrecte	VERB
eurjchem-597	21	7	.	.	PUNCT
eurjchem-597	22	1	the	the	DET
eurjchem-597	22	2	ir	ir	PROPN
eurjchem-597	22	3	spectra	spectra	PROPN
eurjchem-597	22	4	(	(	PUNCT
eurjchem-597	22	5	kbr	kbr	PROPN
eurjchem-597	22	6	)	)	PUNCT
eurjchem-597	22	7	discs	disc	NOUN
eurjchem-597	22	8	were	be	AUX
eurjchem-597	22	9	recorded	record	VERB
eurjchem-597	22	10	on	on	ADP
eurjchem-597	22	11	a	a	DET
eurjchem-597	22	12	perkin‐elmer	perkin‐elmer	PROPN
eurjchem-597	22	13	1650	1650	NUM
eurjchem-597	22	14	spectrometer	spectrometer	NOUN
eurjchem-597	22	15	.	.	PUNCT
eurjchem-597	23	1	1h	1h	NUM
eurjchem-597	23	2	nmr	nmr	PROPN
eurjchem-597	23	3	spectra	spectra	NOUN
eurjchem-597	23	4	was	be	AUX
eurjchem-597	23	5	determined	determine	VERB
eurjchem-597	23	6	on	on	ADP
eurjchem-597	23	7	bruker	bruker	ADJ
eurjchem-597	23	8	ac‐300	ac‐300	PROPN
eurjchem-597	23	9	mhz	mhz	NOUN
eurjchem-597	23	10	instrument	instrument	NOUN
eurjchem-597	23	11	.	.	PUNCT
eurjchem-597	24	1	chemical	chemical	ADJ
eurjchem-597	24	2	shifts	shift	NOUN
eurjchem-597	24	3	are	be	AUX
eurjchem-597	24	4	expressed	express	VERB
eurjchem-597	24	5	as	as	ADP
eurjchem-597	24	6			NUM
eurjchem-597	24	7	(	(	PUNCT
eurjchem-597	24	8	ppm	ppm	NOUN
eurjchem-597	24	9	)	)	PUNCT
eurjchem-597	24	10	relative	relative	ADJ
eurjchem-597	24	11	to	to	PART
eurjchem-597	24	12	tetramethylsilane	tetramethylsilane	VERB
eurjchem-597	24	13	(	(	PUNCT
eurjchem-597	24	14	tms	tms	PROPN
eurjchem-597	24	15	)	)	PUNCT
eurjchem-597	24	16	as	as	ADP
eurjchem-597	24	17	internal	internal	ADJ
eurjchem-597	24	18	standard	standard	NOUN
eurjchem-597	24	19	and	and	CCONJ
eurjchem-597	24	20	dmso‐d6	dmso‐d6	NOUN
eurjchem-597	24	21	as	as	ADP
eurjchem-597	24	22	solvent	solvent	VERB
eurjchem-597	24	23	.	.	PUNCT
eurjchem-597	25	1	the	the	DET
eurjchem-597	25	2	elemental	elemental	ADJ
eurjchem-597	25	3	analysis	analysis	NOUN
eurjchem-597	25	4	was	be	AUX
eurjchem-597	25	5	carried	carry	VERB
eurjchem-597	25	6	by	by	ADP
eurjchem-597	25	7	the	the	DET
eurjchem-597	25	8	micro‐	micro‐	PROPN
eurjchem-597	25	9	analytical	analytical	ADJ
eurjchem-597	25	10	center	center	NOUN
eurjchem-597	25	11	,	,	PUNCT
eurjchem-597	25	12	cairo	cairo	PROPN
eurjchem-597	25	13	university	university	PROPN
eurjchem-597	25	14	.	.	PUNCT
eurjchem-597	26	1	2.2	2.2	NUM
eurjchem-597	26	2	.	.	PUNCT
eurjchem-597	27	1	synthesis	synthesis	NOUN
eurjchem-597	27	2	2.2.1	2.2.1	NUM
eurjchem-597	27	3	.	.	PUNCT
eurjchem-597	27	4	ethyl	ethyl	PROPN
eurjchem-597	27	5	2‐(4‐chlorophenyl	2‐(4‐chlorophenyl	NUM
eurjchem-597	27	6	)	)	PUNCT
eurjchem-597	27	7	1‐4‐mercapto‐6‐phenyl	1‐4‐mercapto‐6‐phenyl	NUM
eurjchem-597	27	8	pyrimidine‐5‐carboxylate	pyrimidine‐5‐carboxylate	PROPN
eurjchem-597	27	9	(	(	PUNCT
eurjchem-597	27	10	4	4	NUM
eurjchem-597	27	11	)	)	PUNCT
eurjchem-597	27	12	a	a	DET
eurjchem-597	27	13	solution	solution	NOUN
eurjchem-597	27	14	of	of	ADP
eurjchem-597	27	15	p‐chlorobenzoylthiocyanate	p‐chlorobenzoylthiocyanate	PUNCT
eurjchem-597	27	16	(	(	PUNCT
eurjchem-597	27	17	3	3	NUM
eurjchem-597	27	18	)	)	PUNCT
eurjchem-597	27	19	(	(	PUNCT
eurjchem-597	27	20	0.01	0.01	NUM
eurjchem-597	27	21	mol	mol	NOUN
eurjchem-597	27	22	)	)	PUNCT
eurjchem-597	27	23	(	(	PUNCT
eurjchem-597	27	24	prepared	prepare	VERB
eurjchem-597	27	25	by	by	ADP
eurjchem-597	27	26	refluxing	refluxing	NOUN
eurjchem-597	27	27	p‐chlorobenzoyl	p‐chlorobenzoyl	PROPN
eurjchem-597	27	28	chloride	chloride	PROPN
eurjchem-597	27	29	(	(	PUNCT
eurjchem-597	27	30	0.01	0.01	NUM
eurjchem-597	27	31	mol	mol	NOUN
eurjchem-597	27	32	)	)	PUNCT
eurjchem-597	27	33	and	and	CCONJ
eurjchem-597	27	34	ammonium	ammonium	NOUN
eurjchem-597	27	35	isothiocyanate	isothiocyanate	NOUN
eurjchem-597	27	36	(	(	PUNCT
eurjchem-597	27	37	0.01	0.01	NUM
eurjchem-597	27	38	mol	mol	NOUN
eurjchem-597	27	39	)	)	PUNCT
eurjchem-597	27	40	in	in	ADP
eurjchem-597	27	41	dry	dry	ADJ
eurjchem-597	27	42	acetone	acetone	NOUN
eurjchem-597	27	43	(	(	PUNCT
eurjchem-597	27	44	20	20	NUM
eurjchem-597	27	45	ml	ml	NOUN
eurjchem-597	27	46	)	)	PUNCT
eurjchem-597	27	47	for	for	ADP
eurjchem-597	27	48	2	2	NUM
eurjchem-597	27	49	h.	h.	NOUN
eurjchem-597	27	50	)	)	PUNCT
eurjchem-597	27	51	was	be	AUX
eurjchem-597	27	52	added	add	VERB
eurjchem-597	27	53	to	to	ADP
eurjchem-597	27	54	ethyl‐3‐amino‐3‐	ethyl‐3‐amino‐3‐	NOUN
eurjchem-597	27	55	phenylacrylate	phenylacrylate	NOUN
eurjchem-597	27	56	(	(	PUNCT
eurjchem-597	27	57	0.01	0.01	NUM
eurjchem-597	27	58	mol	mol	NOUN
eurjchem-597	27	59	)	)	PUNCT
eurjchem-597	27	60	(	(	PUNCT
eurjchem-597	27	61	prepared	prepare	VERB
eurjchem-597	27	62	by	by	ADP
eurjchem-597	27	63	bubbling	bubble	VERB
eurjchem-597	27	64	ammonia	ammonia	ADJ
eurjchem-597	27	65	gas	gas	NOUN
eurjchem-597	27	66	into	into	ADP
eurjchem-597	27	67	ethylbenzoyl	ethylbenzoyl	ADJ
eurjchem-597	27	68	acetate	acetate	NOUN
eurjchem-597	27	69	(	(	PUNCT
eurjchem-597	27	70	0.01	0.01	NUM
eurjchem-597	27	71	mol	mol	NOUN
eurjchem-597	27	72	)	)	PUNCT
eurjchem-597	27	73	for	for	ADP
eurjchem-597	27	74	3	3	NUM
eurjchem-597	27	75	h	h	NOUN
eurjchem-597	27	76	at	at	ADP
eurjchem-597	27	77	room	room	NOUN
eurjchem-597	27	78	temperature	temperature	NOUN
eurjchem-597	27	79	)	)	PUNCT
eurjchem-597	27	80	in	in	ADP
eurjchem-597	27	81	dry	dry	ADJ
eurjchem-597	27	82	acetone	acetone	NOUN
eurjchem-597	27	83	.	.	PUNCT
eurjchem-597	28	1	the	the	DET
eurjchem-597	28	2	reaction	reaction	NOUN
eurjchem-597	28	3	mixture	mixture	NOUN
eurjchem-597	28	4	was	be	AUX
eurjchem-597	28	5	refluxed	refluxe	VERB
eurjchem-597	28	6	for	for	ADP
eurjchem-597	28	7	4	4	NUM
eurjchem-597	28	8	h	h	NOUN
eurjchem-597	28	9	filtered	filter	VERB
eurjchem-597	28	10	off	off	ADP
eurjchem-597	28	11	and	and	CCONJ
eurjchem-597	28	12	cooled	cool	VERB
eurjchem-597	28	13	.	.	PUNCT
eurjchem-597	29	1	the	the	DET
eurjchem-597	29	2	solid	solid	ADJ
eurjchem-597	29	3	obtained	obtain	VERB
eurjchem-597	29	4	was	be	AUX
eurjchem-597	29	5	filtered	filter	VERB
eurjchem-597	29	6	off	off	ADP
eurjchem-597	29	7	,	,	PUNCT
eurjchem-597	29	8	dried	dry	VERB
eurjchem-597	29	9	and	and	CCONJ
eurjchem-597	29	10	recrystallized	recrystallize	VERB
eurjchem-597	29	11	from	from	ADP
eurjchem-597	29	12	ethanol	ethanol	NOUN
eurjchem-597	29	13	95	95	NUM
eurjchem-597	29	14	%	%	NOUN
eurjchem-597	29	15	to	to	PART
eurjchem-597	29	16	give	give	VERB
eurjchem-597	29	17	yellow	yellow	ADJ
eurjchem-597	29	18	crystals	crystal	NOUN
eurjchem-597	29	19	,	,	PUNCT
eurjchem-597	29	20	4	4	NUM
eurjchem-597	29	21	(	(	PUNCT
eurjchem-597	29	22	scheme	scheme	NOUN
eurjchem-597	29	23	1	1	NUM
eurjchem-597	29	24	)	)	PUNCT
eurjchem-597	29	25	.	.	PUNCT
eurjchem-597	30	1	yield	yield	NOUN
eurjchem-597	30	2	:	:	PUNCT
eurjchem-597	30	3	92	92	NUM
eurjchem-597	30	4	%	%	NOUN
eurjchem-597	30	5	.	.	PUNCT
eurjchem-597	31	1	m.p	m.p	PROPN
eurjchem-597	31	2	.	.	PROPN
eurjchem-597	31	3	:	:	PUNCT
eurjchem-597	32	1	210‐212	210‐212	NUM
eurjchem-597	32	2	oc	oc	VERB
eurjchem-597	32	3	.	.	PROPN
eurjchem-597	32	4	ir	ir	PROPN
eurjchem-597	32	5	(	(	PUNCT
eurjchem-597	32	6	kbr	kbr	PROPN
eurjchem-597	32	7	,	,	PUNCT
eurjchem-597	32	8	ν	ν	PROPN
eurjchem-597	32	9	,	,	PUNCT
eurjchem-597	32	10	cm‐1	cm‐1	PROPN
eurjchem-597	32	11	):	):	PUNCT
eurjchem-597	32	12	3450‐3350	3450‐3350	PROPN
eurjchem-597	32	13	(	(	PUNCT
eurjchem-597	32	14	nh	nh	NOUN
eurjchem-597	32	15	)	)	PUNCT
eurjchem-597	32	16	,	,	PUNCT
eurjchem-597	32	17	1725	1725	NUM
eurjchem-597	32	18	(	(	PUNCT
eurjchem-597	32	19	c	c	NOUN
eurjchem-597	32	20	=	=	SYM
eurjchem-597	32	21	o	o	NOUN
eurjchem-597	32	22	,	,	PUNCT
eurjchem-597	32	23	ester	ester	NOUN
eurjchem-597	32	24	)	)	PUNCT
eurjchem-597	32	25	,	,	PUNCT
eurjchem-597	32	26	1200	1200	NUM
eurjchem-597	32	27	(	(	PUNCT
eurjchem-597	32	28	c	c	X
eurjchem-597	32	29	=	=	SYM
eurjchem-597	32	30	s	s	NOUN
eurjchem-597	32	31	)	)	PUNCT
eurjchem-597	32	32	.	.	PUNCT
eurjchem-597	33	1	1h	1h	NUM
eurjchem-597	33	2	nmr	nmr	NOUN
eurjchem-597	33	3	(	(	PUNCT
eurjchem-597	33	4	300	300	NUM
eurjchem-597	33	5	mhz	mhz	NOUN
eurjchem-597	33	6	,	,	PUNCT
eurjchem-597	33	7	dmso‐d6	dmso‐d6	NOUN
eurjchem-597	33	8	,	,	PUNCT
eurjchem-597	33	9			NUM
eurjchem-597	33	10	,	,	PUNCT
eurjchem-597	33	11	ppm	ppm	NUM
eurjchem-597	33	12	):	):	PUNCT
eurjchem-597	33	13	1.36	1.36	NUM
eurjchem-597	33	14	(	(	PUNCT
eurjchem-597	33	15	t	t	PROPN
eurjchem-597	33	16	,	,	PUNCT
eurjchem-597	33	17	3h	3h	NUM
eurjchem-597	33	18	,	,	PUNCT
eurjchem-597	33	19	ch3ch2	ch3ch2	PROPN
eurjchem-597	33	20	)	)	PUNCT
eurjchem-597	33	21	,	,	PUNCT
eurjchem-597	33	22	4.39	4.39	NUM
eurjchem-597	33	23	(	(	PUNCT
eurjchem-597	33	24	q	q	NOUN
eurjchem-597	33	25	,	,	PUNCT
eurjchem-597	33	26	2h	2h	NUM
eurjchem-597	33	27	,	,	PUNCT
eurjchem-597	33	28	ch3ch2	ch3ch2	NOUN
eurjchem-597	33	29	)	)	PUNCT
eurjchem-597	33	30	,	,	PUNCT
eurjchem-597	33	31	7.50‐8.39	7.50‐8.39	NUM
eurjchem-597	33	32	(	(	PUNCT
eurjchem-597	33	33	m	m	PROPN
eurjchem-597	33	34	,	,	PUNCT
eurjchem-597	33	35	9h	9h	NUM
eurjchem-597	33	36	,	,	PUNCT
eurjchem-597	33	37	ar‐h	ar‐h	NOUN
eurjchem-597	33	38	)	)	PUNCT
eurjchem-597	33	39	,	,	PUNCT
eurjchem-597	33	40	13.20	13.20	NUM
eurjchem-597	33	41	(	(	PUNCT
eurjchem-597	33	42	br	br	PROPN
eurjchem-597	33	43	,	,	PUNCT
eurjchem-597	33	44	1h	1h	NUM
eurjchem-597	33	45	,	,	PUNCT
eurjchem-597	33	46	sh	sh	PROPN
eurjchem-597	33	47	)	)	PUNCT
eurjchem-597	33	48	.	.	PUNCT
eurjchem-597	34	1	anal	anal	PROPN
eurjchem-597	34	2	.	.	PUNCT
eurjchem-597	34	3	calcd	calcd	NOUN
eurjchem-597	34	4	.	.	PUNCT
eurjchem-597	35	1	for	for	ADP
eurjchem-597	35	2	c19h15cln2o2s	c19h15cln2o2s	NOUN
eurjchem-597	35	3	:	:	PUNCT
eurjchem-597	35	4	c	c	X
eurjchem-597	35	5	,	,	PUNCT
eurjchem-597	35	6	61.53	61.53	NUM
eurjchem-597	35	7	;	;	PUNCT
eurjchem-597	35	8	h	h	NOUN
eurjchem-597	35	9	,	,	PUNCT
eurjchem-597	35	10	4.08	4.08	NUM
eurjchem-597	35	11	;	;	PUNCT
eurjchem-597	35	12	n	n	CCONJ
eurjchem-597	35	13	,	,	PUNCT
eurjchem-597	35	14	7.55	7.55	NUM
eurjchem-597	35	15	;	;	PUNCT
eurjchem-597	35	16	s	s	X
eurjchem-597	35	17	,	,	PUNCT
eurjchem-597	35	18	8.65	8.65	NUM
eurjchem-597	35	19	.	.	PUNCT
eurjchem-597	35	20	found	find	VERB
eurjchem-597	35	21	:	:	PUNCT
eurjchem-597	36	1	c	c	X
eurjchem-597	36	2	,	,	PUNCT
eurjchem-597	36	3	61.49	61.49	NUM
eurjchem-597	36	4	;	;	PUNCT
eurjchem-597	36	5	h	h	NOUN
eurjchem-597	36	6	3.98	3.98	NUM
eurjchem-597	36	7	;	;	PUNCT
eurjchem-597	36	8	n	n	CCONJ
eurjchem-597	36	9	,	,	PUNCT
eurjchem-597	36	10	7.50	7.50	NUM
eurjchem-597	36	11	;	;	PUNCT
eurjchem-597	36	12	s	s	X
eurjchem-597	36	13	,	,	PUNCT
eurjchem-597	36	14	8.59	8.59	NUM
eurjchem-597	36	15	%	%	NOUN
eurjchem-597	36	16	.	.	PUNCT
eurjchem-597	37	1	2.2.2	2.2.2	NUM
eurjchem-597	37	2	.	.	PUNCT
eurjchem-597	37	3	2‐(acetoxymethyl)‐6‐(2‐(4‐chlorophenyl)‐5‐(ethoxy	2‐(acetoxymethyl)‐6‐(2‐(4‐chlorophenyl)‐5‐(ethoxy	NUM
eurjchem-597	37	4	carbonyl)‐6‐phenylpyrimidin‐4‐ylthio)tetrahydro‐2h‐pyran‐	carbonyl)‐6‐phenylpyrimidin‐4‐ylthio)tetrahydro‐2h‐pyran‐	PROPN
eurjchem-597	37	5	3,4,5‐triyl	3,4,5‐triyl	NUM
eurjchem-597	37	6	triacetate	triacetate	NOUN
eurjchem-597	37	7	(	(	PUNCT
eurjchem-597	37	8	5	5	NUM
eurjchem-597	37	9	)	)	PUNCT
eurjchem-597	37	10	a	a	DET
eurjchem-597	37	11	solution	solution	NOUN
eurjchem-597	37	12	of	of	ADP
eurjchem-597	37	13	compound	compound	NOUN
eurjchem-597	37	14	4	4	NUM
eurjchem-597	37	15	(	(	PUNCT
eurjchem-597	37	16	0.01	0.01	NUM
eurjchem-597	37	17	mol	mol	NOUN
eurjchem-597	37	18	)	)	PUNCT
eurjchem-597	37	19	in	in	ADP
eurjchem-597	37	20	aqueous	aqueous	ADJ
eurjchem-597	37	21	potassium	potassium	NOUN
eurjchem-597	37	22	hydroxide	hydroxide	NOUN
eurjchem-597	37	23	(	(	PUNCT
eurjchem-597	37	24	0.01	0.01	NUM
eurjchem-597	37	25	mol	mol	NOUN
eurjchem-597	37	26	)	)	PUNCT
eurjchem-597	37	27	in	in	ADP
eurjchem-597	37	28	distilled	distil	VERB
eurjchem-597	37	29	water	water	NOUN
eurjchem-597	37	30	(	(	PUNCT
eurjchem-597	37	31	10	10	NUM
eurjchem-597	37	32	ml	ml	NOUN
eurjchem-597	37	33	)	)	PUNCT
eurjchem-597	37	34	was	be	AUX
eurjchem-597	37	35	added	add	VERB
eurjchem-597	37	36	to	to	ADP
eurjchem-597	37	37	a	a	DET
eurjchem-597	37	38	solution	solution	NOUN
eurjchem-597	37	39	of	of	ADP
eurjchem-597	37	40	2,3,4,6‐tetra‐o‐acetyl‐‐d‐glucopyranosyl	2,3,4,6‐tetra‐o‐acetyl‐‐d‐glucopyranosyl	NUM
eurjchem-597	37	41	bromide	bromide	NOUN
eurjchem-597	37	42	(	(	PUNCT
eurjchem-597	37	43	0.01	0.01	NUM
eurjchem-597	37	44	mol	mol	NOUN
eurjchem-597	37	45	)	)	PUNCT
eurjchem-597	37	46	in	in	ADP
eurjchem-597	37	47	acetone	acetone	NOUN
eurjchem-597	37	48	(	(	PUNCT
eurjchem-597	37	49	30	30	NUM
eurjchem-597	37	50	ml	ml	NOUN
eurjchem-597	37	51	)	)	PUNCT
eurjchem-597	37	52	.	.	PUNCT
eurjchem-597	38	1	the	the	DET
eurjchem-597	38	2	reaction	reaction	NOUN
eurjchem-597	38	3	mixture	mixture	NOUN
eurjchem-597	38	4	was	be	AUX
eurjchem-597	38	5	stirred	stir	VERB
eurjchem-597	38	6	for	for	ADP
eurjchem-597	38	7	4	4	NUM
eurjchem-597	38	8	h	h	NOUN
eurjchem-597	38	9	at	at	ADP
eurjchem-597	38	10	room	room	NOUN
eurjchem-597	38	11	temperature	temperature	NOUN
eurjchem-597	38	12	.	.	PUNCT
eurjchem-597	39	1	the	the	DET
eurjchem-597	39	2	mixture	mixture	NOUN
eurjchem-597	39	3	was	be	AUX
eurjchem-597	39	4	evaporated	evaporate	VERB
eurjchem-597	39	5	under	under	ADP
eurjchem-597	39	6	reduced	reduce	VERB
eurjchem-597	39	7	pressure	pressure	NOUN
eurjchem-597	39	8	and	and	CCONJ
eurjchem-597	39	9	the	the	DET
eurjchem-597	39	10	residue	residue	NOUN
eurjchem-597	39	11	was	be	AUX
eurjchem-597	39	12	washed	wash	VERB
eurjchem-597	39	13	with	with	ADP
eurjchem-597	39	14	distilled	distil	VERB
eurjchem-597	39	15	water	water	NOUN
eurjchem-597	39	16	to	to	PART
eurjchem-597	39	17	remove	remove	VERB
eurjchem-597	39	18	the	the	DET
eurjchem-597	39	19	potassium	potassium	NOUN
eurjchem-597	39	20	bromide	bromide	NOUN
eurjchem-597	39	21	formed	form	VERB
eurjchem-597	39	22	.	.	PUNCT
eurjchem-597	40	1	the	the	DET
eurjchem-597	40	2	solid	solid	ADJ
eurjchem-597	40	3	product	product	NOUN
eurjchem-597	40	4	was	be	AUX
eurjchem-597	40	5	dried	dry	VERB
eurjchem-597	40	6	and	and	CCONJ
eurjchem-597	40	7	recrystallized	recrystallize	VERB
eurjchem-597	40	8	from	from	ADP
eurjchem-597	40	9	ethanol	ethanol	NOUN
eurjchem-597	40	10	affording	afford	VERB
eurjchem-597	40	11	pale	pale	ADJ
eurjchem-597	40	12	gray	gray	ADJ
eurjchem-597	40	13	crystals	crystal	NOUN
eurjchem-597	40	14	(	(	PUNCT
eurjchem-597	40	15	scheme	scheme	NOUN
eurjchem-597	40	16	1	1	NUM
eurjchem-597	40	17	)	)	PUNCT
eurjchem-597	40	18	.	.	PUNCT
eurjchem-597	41	1	yield	yield	NOUN
eurjchem-597	41	2	:	:	PUNCT
eurjchem-597	41	3	35	35	NUM
eurjchem-597	41	4	%	%	NOUN
eurjchem-597	41	5	.	.	PUNCT
eurjchem-597	42	1	m.p	m.p	PROPN
eurjchem-597	42	2	.	.	PROPN
eurjchem-597	42	3	:	:	PUNCT
eurjchem-597	43	1	170‐172	170‐172	NUM
eurjchem-597	43	2	oc	oc	PROPN
eurjchem-597	43	3	.	.	PROPN
eurjchem-597	44	1	ir	ir	PROPN
eurjchem-597	44	2	(	(	PUNCT
eurjchem-597	44	3	kbr	kbr	PROPN
eurjchem-597	44	4	,	,	PUNCT
eurjchem-597	44	5	ν	ν	PROPN
eurjchem-597	44	6	,	,	PUNCT
eurjchem-597	44	7	cm‐1	cm‐1	PROPN
eurjchem-597	44	8	):	):	PUNCT
eurjchem-597	44	9	1745	1745	NUM
eurjchem-597	44	10	(	(	PUNCT
eurjchem-597	44	11	c	c	NOUN
eurjchem-597	44	12	=	=	SYM
eurjchem-597	44	13	o	o	NOUN
eurjchem-597	44	14	,	,	PUNCT
eurjchem-597	44	15	acetoxy	acetoxy	ADJ
eurjchem-597	44	16	groups	group	NOUN
eurjchem-597	44	17	)	)	PUNCT
eurjchem-597	44	18	,	,	PUNCT
eurjchem-597	44	19	1725	1725	NUM
eurjchem-597	44	20	(	(	PUNCT
eurjchem-597	44	21	c	c	NOUN
eurjchem-597	44	22	=	=	SYM
eurjchem-597	44	23	o	o	NOUN
eurjchem-597	44	24	,	,	PUNCT
eurjchem-597	44	25	ester	ester	NOUN
eurjchem-597	44	26	)	)	PUNCT
eurjchem-597	44	27	,	,	PUNCT
eurjchem-597	44	28	1636	1636	NUM
eurjchem-597	44	29	(	(	PUNCT
eurjchem-597	44	30	c	c	NOUN
eurjchem-597	44	31	=	=	SYM
eurjchem-597	44	32	n	n	NUM
eurjchem-597	44	33	)	)	PUNCT
eurjchem-597	44	34	.	.	PUNCT
eurjchem-597	45	1	1h	1h	NUM
eurjchem-597	45	2	nmr	nmr	NOUN
eurjchem-597	45	3	(	(	PUNCT
eurjchem-597	45	4	300	300	NUM
eurjchem-597	45	5	mhz	mhz	NOUN
eurjchem-597	45	6	,	,	PUNCT
eurjchem-597	45	7	dmso‐d6	dmso‐d6	NOUN
eurjchem-597	45	8	,	,	PUNCT
eurjchem-597	45	9			NUM
eurjchem-597	45	10	,	,	PUNCT
eurjchem-597	45	11	ppm	ppm	NUM
eurjchem-597	45	12	):	):	PUNCT
eurjchem-597	45	13	1.87	1.87	NUM
eurjchem-597	45	14	,	,	PUNCT
eurjchem-597	45	15	1.92	1.92	NUM
eurjchem-597	45	16	,	,	PUNCT
eurjchem-597	45	17	1.95	1.95	NUM
eurjchem-597	45	18	and	and	CCONJ
eurjchem-597	45	19	2.02	2.02	NUM
eurjchem-597	45	20	(	(	PUNCT
eurjchem-597	45	21	4s	4s	NUM
eurjchem-597	45	22	,	,	PUNCT
eurjchem-597	45	23	12h	12h	NUM
eurjchem-597	45	24	,	,	PUNCT
eurjchem-597	45	25	4ch3c	4ch3c	NUM
eurjchem-597	45	26	=	=	SYM
eurjchem-597	45	27	o	o	NOUN
eurjchem-597	45	28	)	)	PUNCT
eurjchem-597	45	29	,	,	PUNCT
eurjchem-597	45	30	1.37	1.37	NUM
eurjchem-597	45	31	(	(	PUNCT
eurjchem-597	45	32	t	t	PROPN
eurjchem-597	45	33	,	,	PUNCT
eurjchem-597	45	34	3h	3h	NUM
eurjchem-597	45	35	,	,	PUNCT
eurjchem-597	45	36	ch3ch2	ch3ch2	PROPN
eurjchem-597	45	37	)	)	PUNCT
eurjchem-597	45	38	,	,	PUNCT
eurjchem-597	45	39	4.03	4.03	NUM
eurjchem-597	45	40	(	(	PUNCT
eurjchem-597	45	41	m	m	PROPN
eurjchem-597	45	42	,	,	PUNCT
eurjchem-597	45	43	2h	2h	NUM
eurjchem-597	45	44	,	,	PUNCT
eurjchem-597	45	45	h‐5	h‐5	NOUN
eurjchem-597	45	46	'	'	PUNCT
eurjchem-597	45	47	and	and	CCONJ
eurjchem-597	45	48	h‐6	h‐6	NOUN
eurjchem-597	45	49	''	''	PUNCT
eurjchem-597	45	50	)	)	PUNCT
eurjchem-597	45	51	,	,	PUNCT
eurjchem-597	45	52	4.28	4.28	NUM
eurjchem-597	45	53	(	(	PUNCT
eurjchem-597	45	54	m	m	PROPN
eurjchem-597	45	55	,	,	PUNCT
eurjchem-597	45	56	1h	1h	NUM
eurjchem-597	45	57	,	,	PUNCT
eurjchem-597	45	58	h‐6	h‐6	NOUN
eurjchem-597	45	59	'	'	NUM
eurjchem-597	45	60	)	)	PUNCT
eurjchem-597	45	61	,	,	PUNCT
eurjchem-597	45	62	4.38	4.38	NUM
eurjchem-597	45	63	(	(	PUNCT
eurjchem-597	45	64	q	q	NOUN
eurjchem-597	45	65	,	,	PUNCT
eurjchem-597	45	66	2h	2h	NUM
eurjchem-597	45	67	,	,	PUNCT
eurjchem-597	45	68	ch3ch2	ch3ch2	PROPN
eurjchem-597	45	69	)	)	PUNCT
eurjchem-597	45	70	,	,	PUNCT
eurjchem-597	45	71	5.06	5.06	NUM
eurjchem-597	45	72	(	(	PUNCT
eurjchem-597	45	73	t	t	PROPN
eurjchem-597	45	74	,	,	PUNCT
eurjchem-597	45	75	1h	1h	NUM
eurjchem-597	45	76	,	,	PUNCT
eurjchem-597	45	77	h‐4	h‐4	NOUN
eurjchem-597	45	78	'	'	PUNCT
eurjchem-597	45	79	)	)	PUNCT
eurjchem-597	45	80	,	,	PUNCT
eurjchem-597	45	81	5.61	5.61	NUM
eurjchem-597	45	82	(	(	PUNCT
eurjchem-597	45	83	t	t	PROPN
eurjchem-597	45	84	,	,	PUNCT
eurjchem-597	45	85	1h	1h	NUM
eurjchem-597	45	86	,	,	PUNCT
eurjchem-597	45	87	h‐2	h‐2	NOUN
eurjchem-597	45	88	'	'	PUNCT
eurjchem-597	45	89	)	)	PUNCT
eurjchem-597	45	90	,	,	PUNCT
eurjchem-597	45	91	5.69	5.69	NUM
eurjchem-597	45	92	(	(	PUNCT
eurjchem-597	45	93	t	t	PROPN
eurjchem-597	45	94	,	,	PUNCT
eurjchem-597	45	95	1h	1h	NUM
eurjchem-597	45	96	,	,	PUNCT
eurjchem-597	45	97	h‐3	h‐3	NOUN
eurjchem-597	45	98	'	'	PUNCT
eurjchem-597	45	99	)	)	PUNCT
eurjchem-597	45	100	,	,	PUNCT
eurjchem-597	45	101	6.21	6.21	NUM
eurjchem-597	45	102	(	(	PUNCT
eurjchem-597	45	103	d	d	PROPN
eurjchem-597	45	104	,	,	PUNCT
eurjchem-597	45	105	1h	1h	NUM
eurjchem-597	45	106	,	,	PUNCT
eurjchem-597	45	107	h‐1	h‐1	PROPN
eurjchem-597	45	108	'	'	PUNCT
eurjchem-597	45	109	)	)	PUNCT
eurjchem-597	45	110	,	,	PUNCT
eurjchem-597	45	111	7.30‐8.41	7.30‐8.41	NUM
eurjchem-597	45	112	(	(	PUNCT
eurjchem-597	45	113	m	m	PROPN
eurjchem-597	45	114	,	,	PUNCT
eurjchem-597	45	115	9h	9h	NUM
eurjchem-597	45	116	,	,	PUNCT
eurjchem-597	45	117	ar‐h	ar‐h	NOUN
eurjchem-597	45	118	)	)	PUNCT
eurjchem-597	45	119	.	.	PUNCT
eurjchem-597	46	1	anal	anal	PROPN
eurjchem-597	46	2	.	.	PUNCT
eurjchem-597	46	3	calcd	calcd	NOUN
eurjchem-597	46	4	.	.	PUNCT
eurjchem-597	47	1	for	for	ADP
eurjchem-597	47	2	c33h33cln2o11s	c33h33cln2o11s	ADJ
eurjchem-597	47	3	:	:	PUNCT
eurjchem-597	47	4	c	c	X
eurjchem-597	47	5	,	,	PUNCT
eurjchem-597	47	6	56.53	56.53	NUM
eurjchem-597	47	7	;	;	PUNCT
eurjchem-597	47	8	h	h	NOUN
eurjchem-597	47	9	,	,	PUNCT
eurjchem-597	47	10	4.74	4.74	NUM
eurjchem-597	47	11	;	;	PUNCT
eurjchem-597	47	12	n	n	CCONJ
eurjchem-597	47	13	,	,	PUNCT
eurjchem-597	47	14	4.00	4.00	NUM
eurjchem-597	47	15	;	;	PUNCT
eurjchem-597	47	16	s	s	X
eurjchem-597	47	17	,	,	PUNCT
eurjchem-597	47	18	4.57	4.57	NUM
eurjchem-597	47	19	.	.	PUNCT
eurjchem-597	47	20	found	find	VERB
eurjchem-597	47	21	:	:	PUNCT
eurjchem-597	48	1	c	c	X
eurjchem-597	48	2	,	,	PUNCT
eurjchem-597	48	3	56.50	56.50	NUM
eurjchem-597	48	4	;	;	PUNCT
eurjchem-597	48	5	h	h	NOUN
eurjchem-597	48	6	,	,	PUNCT
eurjchem-597	48	7	4.69	4.69	NUM
eurjchem-597	48	8	;	;	PUNCT
eurjchem-597	48	9	n	n	CCONJ
eurjchem-597	48	10	,	,	PUNCT
eurjchem-597	48	11	3.98	3.98	NUM
eurjchem-597	48	12	;	;	PUNCT
eurjchem-597	48	13	s	s	X
eurjchem-597	48	14	,	,	PUNCT
eurjchem-597	48	15	4.52	4.52	NUM
eurjchem-597	48	16	%	%	NOUN
eurjchem-597	48	17	.	.	PUNCT
eurjchem-597	49	1	242	242	NUM
eurjchem-597	49	2	shehab	shehab	NOUN
eurjchem-597	49	3	and	and	CCONJ
eurjchem-597	49	4	mohamed	mohamed	PROPN
eurjchem-597	49	5	/	/	SYM
eurjchem-597	49	6	european	european	PROPN
eurjchem-597	49	7	journal	journal	PROPN
eurjchem-597	49	8	of	of	ADP
eurjchem-597	49	9	chemistry	chemistry	NOUN
eurjchem-597	49	10	3	3	NUM
eurjchem-597	49	11	(	(	PUNCT
eurjchem-597	49	12	2	2	NUM
eurjchem-597	49	13	)	)	PUNCT
eurjchem-597	49	14	(	(	PUNCT
eurjchem-597	49	15	2012	2012	NUM
eurjchem-597	49	16	)	)	PUNCT
eurjchem-597	49	17	241‐246	241‐246	NUM
eurjchem-597	49	18	cl	cl	NOUN
eurjchem-597	49	19	o	o	NOUN
eurjchem-597	49	20	oet	oet	VERB
eurjchem-597	49	21	ph	ph	PROPN
eurjchem-597	49	22	ar	ar	PROPN
eurjchem-597	49	23	c	c	PROPN
eurjchem-597	49	24	n	n	CCONJ
eurjchem-597	49	25	n	n	NOUN
eurjchem-597	49	26	h	h	NOUN
eurjchem-597	49	27	o	o	X
eurjchem-597	49	28	sc	sc	PROPN
eurjchem-597	49	29	car	car	NOUN
eurjchem-597	50	1	h2n	h2n	PROPN
eurjchem-597	51	1	o	o	INTJ
eurjchem-597	51	2	o	o	INTJ
eurjchem-597	51	3	oet	oet	INTJ
eurjchem-597	51	4	c	c	PROPN
eurjchem-597	51	5	s	s	PROPN
eurjchem-597	51	6	ar	ar	PROPN
eurjchem-597	51	7	ph	ph	PROPN
eurjchem-597	51	8	nh	nh	PROPN
eurjchem-597	51	9	aco	aco	PROPN
eurjchem-597	51	10	oac	oac	PROPN
eurjchem-597	51	11	o	o	PROPN
eurjchem-597	51	12	h	h	PROPN
eurjchem-597	51	13	oac	oac	PROPN
eurjchem-597	51	14	h	h	PROPN
eurjchem-597	51	15	oac	oac	PROPN
eurjchem-597	51	16	h	h	PROPN
eurjchem-597	51	17	br	br	NOUN
eurjchem-597	52	1	hh	hh	INTJ
eurjchem-597	53	1	o	o	PROPN
eurjchem-597	53	2	oet	oet	PROPN
eurjchem-597	53	3	c	c	PROPN
eurjchem-597	53	4	shar	shar	PROPN
eurjchem-597	53	5	ph	ph	PROPN
eurjchem-597	53	6	n	n	PRON
eurjchem-597	53	7	n	n	PRON
eurjchem-597	53	8	cooet	cooet	NOUN
eurjchem-597	53	9	shar	shar	PROPN
eurjchem-597	53	10	ph	ph	PROPN
eurjchem-597	53	11	n	n	PROPN
eurjchem-597	53	12	n	n	PRON
eurjchem-597	53	13	nh2	nh2	NOUN
eurjchem-597	53	14	o	o	NOUN
eurjchem-597	54	1	oetph	oetph	NOUN
eurjchem-597	55	1	nh3	nh3	NUM
eurjchem-597	55	2	o	o	X
eurjchem-597	55	3	o	o	X
eurjchem-597	55	4	oetph	oetph	X
eurjchem-597	55	5	ar	ar	PROPN
eurjchem-597	55	6	=	=	NOUN
eurjchem-597	55	7	6	6	NUM
eurjchem-597	55	8	5	5	NUM
eurjchem-597	55	9	meoh	meoh	NOUN
eurjchem-597	55	10	/	/	SYM
eurjchem-597	55	11	tea	tea	NOUN
eurjchem-597	55	12	dry	dry	ADJ
eurjchem-597	55	13	acetone	acetone	NOUN
eurjchem-597	55	14	4	4	NUM
eurjchem-597	55	15	acetone	acetone	NOUN
eurjchem-597	55	16	+	+	CCONJ
eurjchem-597	55	17	4	4	NUM
eurjchem-597	55	18	3	3	NUM
eurjchem-597	55	19	2	2	NUM
eurjchem-597	55	20	1	1	NUM
eurjchem-597	55	21	+	+	NUM
eurjchem-597	55	22	room	room	NOUN
eurjchem-597	55	23	temperature	temperature	NOUN
eurjchem-597	55	24	-h2o	-h2o	NOUN
eurjchem-597	55	25	n	n	CCONJ
eurjchem-597	55	26	koh	koh	PROPN
eurjchem-597	55	27	oac	oac	PROPN
eurjchem-597	55	28	o	o	PROPN
eurjchem-597	55	29	oac	oac	PROPN
eurjchem-597	55	30	hoac	hoac	PROPN
eurjchem-597	55	31	h	h	PROPN
eurjchem-597	55	32	s	s	PART
eurjchem-597	55	33	oac	oac	PROPN
eurjchem-597	55	34	h	h	NOUN
eurjchem-597	55	35	o	o	PROPN
eurjchem-597	55	36	oet	oet	VERB
eurjchem-597	55	37	ph	ph	PROPN
eurjchem-597	55	38	ar	ar	PROPN
eurjchem-597	55	39	c	c	PROPN
eurjchem-597	55	40	n	n	ADP
eurjchem-597	55	41	n	n	NOUN
eurjchem-597	55	42	h	h	NOUN
eurjchem-597	56	1	oh	oh	INTJ
eurjchem-597	56	2	o	o	INTJ
eurjchem-597	57	1	oh	oh	INTJ
eurjchem-597	57	2	hoh	hoh	INTJ
eurjchem-597	58	1	h	h	NOUN
eurjchem-597	58	2	s	s	PART
eurjchem-597	59	1	oh	oh	INTJ
eurjchem-597	59	2	h	h	NOUN
eurjchem-597	59	3	scheme	scheme	NOUN
eurjchem-597	59	4	1	1	NUM
eurjchem-597	59	5	2.2.3	2.2.3	NUM
eurjchem-597	59	6	.	.	PUNCT
eurjchem-597	60	1	ethyl	ethyl	PROPN
eurjchem-597	60	2	2‐(4‐chlorophenyl)‐4‐phenyl‐6‐(3,4,5‐trihydroxy‐	2‐(4‐chlorophenyl)‐4‐phenyl‐6‐(3,4,5‐trihydroxy‐	PROPN
eurjchem-597	60	3	6‐(hydroxymethyl	6‐(hydroxymethyl	NOUN
eurjchem-597	60	4	)	)	PUNCT
eurjchem-597	60	5	tetrahydro‐2h‐pyran‐2‐yl	tetrahydro‐2h‐pyran‐2‐yl	NOUN
eurjchem-597	60	6	thio	thio	NOUN
eurjchem-597	60	7	)	)	PUNCT
eurjchem-597	60	8	pyrimidine‐5‐carboxylate	pyrimidine‐5‐carboxylate	PROPN
eurjchem-597	60	9	(	(	PUNCT
eurjchem-597	60	10	6	6	NUM
eurjchem-597	60	11	)	)	PUNCT
eurjchem-597	60	12	a	a	DET
eurjchem-597	60	13	mixture	mixture	NOUN
eurjchem-597	60	14	of	of	ADP
eurjchem-597	60	15	compound	compound	NOUN
eurjchem-597	60	16	5	5	NUM
eurjchem-597	60	17	(	(	PUNCT
eurjchem-597	60	18	0.01	0.01	NUM
eurjchem-597	60	19	mol	mol	NOUN
eurjchem-597	60	20	)	)	PUNCT
eurjchem-597	60	21	in	in	ADP
eurjchem-597	60	22	methanol	methanol	NOUN
eurjchem-597	60	23	(	(	PUNCT
eurjchem-597	60	24	30	30	NUM
eurjchem-597	60	25	ml	ml	NOUN
eurjchem-597	60	26	)	)	PUNCT
eurjchem-597	60	27	,	,	PUNCT
eurjchem-597	60	28	1	1	NUM
eurjchem-597	60	29	ml	ml	NOUN
eurjchem-597	60	30	of	of	ADP
eurjchem-597	60	31	triethylamine	triethylamine	NOUN
eurjchem-597	60	32	(	(	PUNCT
eurjchem-597	60	33	tea	tea	NOUN
eurjchem-597	60	34	)	)	PUNCT
eurjchem-597	60	35	and	and	CCONJ
eurjchem-597	60	36	few	few	ADJ
eurjchem-597	60	37	drops	drop	NOUN
eurjchem-597	60	38	of	of	ADP
eurjchem-597	60	39	water	water	NOUN
eurjchem-597	60	40	were	be	AUX
eurjchem-597	60	41	stirred	stir	VERB
eurjchem-597	60	42	overnight	overnight	ADV
eurjchem-597	60	43	at	at	ADP
eurjchem-597	60	44	room	room	NOUN
eurjchem-597	60	45	temperature	temperature	NOUN
eurjchem-597	60	46	,	,	PUNCT
eurjchem-597	60	47	the	the	DET
eurjchem-597	60	48	solvent	solvent	NOUN
eurjchem-597	60	49	was	be	AUX
eurjchem-597	60	50	then	then	ADV
eurjchem-597	60	51	removed	remove	VERB
eurjchem-597	60	52	under	under	ADP
eurjchem-597	60	53	vacum	vacum	NOUN
eurjchem-597	60	54	,	,	PUNCT
eurjchem-597	60	55	and	and	CCONJ
eurjchem-597	60	56	the	the	DET
eurjchem-597	60	57	residue	residue	NOUN
eurjchem-597	60	58	was	be	AUX
eurjchem-597	60	59	washed	wash	VERB
eurjchem-597	60	60	with	with	ADP
eurjchem-597	60	61	chloroform	chloroform	NOUN
eurjchem-597	60	62	.	.	PUNCT
eurjchem-597	61	1	the	the	DET
eurjchem-597	61	2	remaining	remain	VERB
eurjchem-597	61	3	residue	residue	NOUN
eurjchem-597	61	4	was	be	AUX
eurjchem-597	61	5	recrystallized	recrystallize	VERB
eurjchem-597	61	6	from	from	ADP
eurjchem-597	61	7	ethanol	ethanol	NOUN
eurjchem-597	61	8	giving	give	VERB
eurjchem-597	61	9	gray	gray	ADJ
eurjchem-597	61	10	crystals	crystal	NOUN
eurjchem-597	61	11	(	(	PUNCT
eurjchem-597	61	12	scheme	scheme	NOUN
eurjchem-597	61	13	1	1	NUM
eurjchem-597	61	14	)	)	PUNCT
eurjchem-597	61	15	.	.	PUNCT
eurjchem-597	62	1	yield	yield	NOUN
eurjchem-597	62	2	:	:	PUNCT
eurjchem-597	62	3	25	25	NUM
eurjchem-597	62	4	%	%	NOUN
eurjchem-597	62	5	.	.	PUNCT
eurjchem-597	63	1	m.p	m.p	PROPN
eurjchem-597	63	2	.	.	PROPN
eurjchem-597	63	3	:	:	PUNCT
eurjchem-597	64	1	180‐	180‐	NUM
eurjchem-597	64	2	182	182	NUM
eurjchem-597	64	3	oc	oc	NOUN
eurjchem-597	64	4	.	.	PUNCT
eurjchem-597	65	1	ir	ir	PROPN
eurjchem-597	65	2	(	(	PUNCT
eurjchem-597	65	3	kbr	kbr	PROPN
eurjchem-597	65	4	,	,	PUNCT
eurjchem-597	65	5	ν	ν	PROPN
eurjchem-597	65	6	,	,	PUNCT
eurjchem-597	65	7	cm‐1	cm‐1	PROPN
eurjchem-597	65	8	):	):	PUNCT
eurjchem-597	65	9	3420‐3395	3420‐3395	NUM
eurjchem-597	65	10	(	(	PUNCT
eurjchem-597	65	11	very	very	ADV
eurjchem-597	65	12	broad	broad	ADJ
eurjchem-597	65	13	band	band	NOUN
eurjchem-597	65	14	)	)	PUNCT
eurjchem-597	65	15	(	(	PUNCT
eurjchem-597	65	16	oh	oh	INTJ
eurjchem-597	65	17	)	)	PUNCT
eurjchem-597	65	18	,	,	PUNCT
eurjchem-597	65	19	1735	1735	NUM
eurjchem-597	65	20	(	(	PUNCT
eurjchem-597	65	21	c	c	NOUN
eurjchem-597	65	22	=	=	SYM
eurjchem-597	65	23	o	o	NOUN
eurjchem-597	65	24	,	,	PUNCT
eurjchem-597	65	25	ester	ester	NOUN
eurjchem-597	65	26	)	)	PUNCT
eurjchem-597	65	27	.	.	PUNCT
eurjchem-597	66	1	1h	1h	NUM
eurjchem-597	66	2	nmr	nmr	NOUN
eurjchem-597	66	3	(	(	PUNCT
eurjchem-597	66	4	300	300	NUM
eurjchem-597	66	5	mhz	mhz	NOUN
eurjchem-597	66	6	,	,	PUNCT
eurjchem-597	66	7	dmso‐d6	dmso‐d6	NOUN
eurjchem-597	66	8	/	/	SYM
eurjchem-597	66	9	d2o	d2o	PROPN
eurjchem-597	66	10	,	,	PUNCT
eurjchem-597	66	11			NUM
eurjchem-597	66	12	,	,	PUNCT
eurjchem-597	66	13	ppm	ppm	NOUN
eurjchem-597	66	14	):	):	PUNCT
eurjchem-597	66	15	1.40	1.40	NUM
eurjchem-597	66	16	(	(	PUNCT
eurjchem-597	66	17	t	t	PROPN
eurjchem-597	66	18	,	,	PUNCT
eurjchem-597	66	19	3h	3h	NUM
eurjchem-597	66	20	,	,	PUNCT
eurjchem-597	66	21	ch3ch2	ch3ch2	PROPN
eurjchem-597	66	22	)	)	PUNCT
eurjchem-597	66	23	,	,	PUNCT
eurjchem-597	66	24	3.68	3.68	NUM
eurjchem-597	66	25	(	(	PUNCT
eurjchem-597	66	26	m	m	PROPN
eurjchem-597	66	27	,	,	PUNCT
eurjchem-597	66	28	1h	1h	NUM
eurjchem-597	66	29	,	,	PUNCT
eurjchem-597	66	30	h5	h5	PROPN
eurjchem-597	66	31	)	)	PUNCT
eurjchem-597	66	32	,	,	PUNCT
eurjchem-597	66	33	4.39	4.39	NUM
eurjchem-597	66	34	(	(	PUNCT
eurjchem-597	66	35	q	q	NOUN
eurjchem-597	66	36	,	,	PUNCT
eurjchem-597	66	37	2h	2h	NUM
eurjchem-597	66	38	,	,	PUNCT
eurjchem-597	66	39	ch3ch2	ch3ch2	PROPN
eurjchem-597	66	40	)	)	PUNCT
eurjchem-597	66	41	,	,	PUNCT
eurjchem-597	66	42	4.48	4.48	NUM
eurjchem-597	66	43	(	(	PUNCT
eurjchem-597	66	44	m	m	PROPN
eurjchem-597	66	45	,	,	PUNCT
eurjchem-597	66	46	2h	2h	NUM
eurjchem-597	66	47	,	,	PUNCT
eurjchem-597	66	48	h6'.6	h6'.6	NOUN
eurjchem-597	66	49	''	''	PUNCT
eurjchem-597	66	50	)	)	PUNCT
eurjchem-597	66	51	,	,	PUNCT
eurjchem-597	66	52	5.02	5.02	NUM
eurjchem-597	66	53	(	(	PUNCT
eurjchem-597	66	54	d	d	PROPN
eurjchem-597	66	55	,	,	PUNCT
eurjchem-597	66	56	1h	1h	NUM
eurjchem-597	66	57	,	,	PUNCT
eurjchem-597	66	58	h‐4	h‐4	NOUN
eurjchem-597	66	59	'	'	PUNCT
eurjchem-597	66	60	)	)	PUNCT
eurjchem-597	66	61	,	,	PUNCT
eurjchem-597	66	62	5.16	5.16	NUM
eurjchem-597	66	63	(	(	PUNCT
eurjchem-597	66	64	d	d	PROPN
eurjchem-597	66	65	,	,	PUNCT
eurjchem-597	66	66	1h	1h	NUM
eurjchem-597	66	67	,	,	PUNCT
eurjchem-597	66	68	h‐2	h‐2	NOUN
eurjchem-597	66	69	'	'	PUNCT
eurjchem-597	66	70	)	)	PUNCT
eurjchem-597	66	71	,	,	PUNCT
eurjchem-597	66	72	5.44	5.44	NUM
eurjchem-597	66	73	(	(	PUNCT
eurjchem-597	66	74	d	d	PROPN
eurjchem-597	66	75	,	,	PUNCT
eurjchem-597	66	76	1h	1h	NUM
eurjchem-597	66	77	,	,	PUNCT
eurjchem-597	66	78	h‐3	h‐3	NOUN
eurjchem-597	66	79	'	'	PUNCT
eurjchem-597	66	80	)	)	PUNCT
eurjchem-597	66	81	,	,	PUNCT
eurjchem-597	66	82	5.61	5.61	NUM
eurjchem-597	66	83	(	(	PUNCT
eurjchem-597	66	84	d	d	PROPN
eurjchem-597	66	85	,	,	PUNCT
eurjchem-597	66	86	1h	1h	NUM
eurjchem-597	66	87	,	,	PUNCT
eurjchem-597	66	88	h‐1	h‐1	PROPN
eurjchem-597	66	89	'	'	PUNCT
eurjchem-597	66	90	)	)	PUNCT
eurjchem-597	66	91	,	,	PUNCT
eurjchem-597	66	92	4.40‐8.41	4.40‐8.41	NUM
eurjchem-597	66	93	(	(	PUNCT
eurjchem-597	66	94	m	m	PROPN
eurjchem-597	66	95	,	,	PUNCT
eurjchem-597	66	96	9h	9h	NUM
eurjchem-597	66	97	,	,	PUNCT
eurjchem-597	66	98	ar‐h	ar‐h	NOUN
eurjchem-597	66	99	)	)	PUNCT
eurjchem-597	66	100	.	.	PUNCT
eurjchem-597	67	1	anal	anal	PROPN
eurjchem-597	67	2	.	.	PUNCT
eurjchem-597	67	3	calcd	calcd	NOUN
eurjchem-597	67	4	.	.	PUNCT
eurjchem-597	68	1	for	for	ADP
eurjchem-597	68	2	c25h25cln2o7s	c25h25cln2o7s	NOUN
eurjchem-597	68	3	:	:	PUNCT
eurjchem-597	68	4	c	c	X
eurjchem-597	68	5	,	,	PUNCT
eurjchem-597	68	6	56.34	56.34	NUM
eurjchem-597	68	7	;	;	PUNCT
eurjchem-597	69	1	h	h	NOUN
eurjchem-597	69	2	,	,	PUNCT
eurjchem-597	69	3	4.73	4.73	NUM
eurjchem-597	69	4	;	;	PUNCT
eurjchem-597	69	5	n	n	CCONJ
eurjchem-597	69	6	,	,	PUNCT
eurjchem-597	69	7	5.26	5.26	NUM
eurjchem-597	69	8	;	;	PUNCT
eurjchem-597	69	9	s	s	X
eurjchem-597	69	10	,	,	PUNCT
eurjchem-597	69	11	6.02	6.02	NUM
eurjchem-597	69	12	found	find	VERB
eurjchem-597	69	13	:	:	PUNCT
eurjchem-597	69	14	c	c	X
eurjchem-597	69	15	,	,	PUNCT
eurjchem-597	69	16	56.29	56.29	NUM
eurjchem-597	69	17	;	;	PUNCT
eurjchem-597	69	18	h	h	NOUN
eurjchem-597	69	19	,	,	PUNCT
eurjchem-597	69	20	4.70	4.70	NUM
eurjchem-597	69	21	;	;	PUNCT
eurjchem-597	69	22	n	n	CCONJ
eurjchem-597	69	23	,	,	PUNCT
eurjchem-597	69	24	5.27	5.27	NUM
eurjchem-597	69	25	;	;	PUNCT
eurjchem-597	69	26	s	s	X
eurjchem-597	69	27	,	,	PUNCT
eurjchem-597	69	28	6.00	6.00	NUM
eurjchem-597	69	29	%	%	NOUN
eurjchem-597	69	30	.	.	PUNCT
eurjchem-597	70	1	2.2.4	2.2.4	X
eurjchem-597	70	2	.	.	X
eurjchem-597	70	3	synthesis	synthesis	NOUN
eurjchem-597	70	4	of	of	ADP
eurjchem-597	70	5	compounds	compound	NOUN
eurjchem-597	70	6	7a‐d	7a‐d	VERB
eurjchem-597	70	7	a	a	DET
eurjchem-597	70	8	mixture	mixture	NOUN
eurjchem-597	70	9	of	of	ADP
eurjchem-597	70	10	compound	compound	NOUN
eurjchem-597	70	11	4	4	NUM
eurjchem-597	70	12	(	(	PUNCT
eurjchem-597	70	13	0.01	0.01	NUM
eurjchem-597	70	14	mol	mol	NOUN
eurjchem-597	70	15	)	)	PUNCT
eurjchem-597	70	16	and	and	CCONJ
eurjchem-597	70	17	appropriate	appropriate	ADJ
eurjchem-597	70	18	alkylating	alkylate	VERB
eurjchem-597	70	19	agent	agent	NOUN
eurjchem-597	70	20	(	(	PUNCT
eurjchem-597	70	21	benzyl	benzyl	NOUN
eurjchem-597	70	22	chloride	chloride	NOUN
eurjchem-597	70	23	,	,	PUNCT
eurjchem-597	70	24	ethyl	ethyl	PROPN
eurjchem-597	70	25	bromoacetate	bromoacetate	NOUN
eurjchem-597	70	26	,	,	PUNCT
eurjchem-597	70	27	chloroacetamide	chloroacetamide	NOUN
eurjchem-597	70	28	and	and	CCONJ
eurjchem-597	70	29	phenacyl	phenacyl	VERB
eurjchem-597	70	30	bromide	bromide	NOUN
eurjchem-597	70	31	)	)	PUNCT
eurjchem-597	70	32	and	and	CCONJ
eurjchem-597	70	33	triethylamine	triethylamine	NOUN
eurjchem-597	70	34	(	(	PUNCT
eurjchem-597	70	35	3	3	NUM
eurjchem-597	70	36	drops	drop	NOUN
eurjchem-597	70	37	)	)	PUNCT
eurjchem-597	70	38	in	in	ADP
eurjchem-597	70	39	ethanol	ethanol	NOUN
eurjchem-597	70	40	was	be	AUX
eurjchem-597	70	41	refluxed	refluxe	VERB
eurjchem-597	70	42	for	for	ADP
eurjchem-597	70	43	30	30	NUM
eurjchem-597	70	44	min	min	NOUN
eurjchem-597	70	45	.	.	PUNCT
eurjchem-597	71	1	the	the	DET
eurjchem-597	71	2	precipitate	precipitate	NOUN
eurjchem-597	71	3	obtained	obtain	VERB
eurjchem-597	71	4	upon	upon	SCONJ
eurjchem-597	71	5	cooling	cool	VERB
eurjchem-597	71	6	and	and	CCONJ
eurjchem-597	71	7	dilution	dilution	NOUN
eurjchem-597	71	8	with	with	ADP
eurjchem-597	71	9	water	water	NOUN
eurjchem-597	71	10	was	be	AUX
eurjchem-597	71	11	collected	collect	VERB
eurjchem-597	71	12	and	and	CCONJ
eurjchem-597	71	13	crystallized	crystallize	VERB
eurjchem-597	71	14	from	from	ADP
eurjchem-597	71	15	suitable	suitable	ADJ
eurjchem-597	71	16	solvent	solvent	NOUN
eurjchem-597	71	17	(	(	PUNCT
eurjchem-597	71	18	scheme	scheme	NOUN
eurjchem-597	71	19	2	2	NUM
eurjchem-597	71	20	)	)	PUNCT
eurjchem-597	71	21	.	.	PUNCT
eurjchem-597	72	1	ethyl	ethyl	PROPN
eurjchem-597	72	2	4‐(benzylthio)‐2‐(4chlorophenyl)‐6‐phenyl	4‐(benzylthio)‐2‐(4chlorophenyl)‐6‐phenyl	NUM
eurjchem-597	72	3	pyrimidine‐	pyrimidine‐	PROPN
eurjchem-597	72	4	5‐carboxylate	5‐carboxylate	NUM
eurjchem-597	72	5	(	(	PUNCT
eurjchem-597	72	6	7a	7a	NUM
eurjchem-597	72	7	):	):	PUNCT
eurjchem-597	72	8	a	a	DET
eurjchem-597	72	9	pale	pale	ADJ
eurjchem-597	72	10	yellow	yellow	ADJ
eurjchem-597	72	11	crystal	crystal	NOUN
eurjchem-597	72	12	.	.	PUNCT
eurjchem-597	73	1	yield	yield	NOUN
eurjchem-597	73	2	:	:	PUNCT
eurjchem-597	73	3	85	85	NUM
eurjchem-597	73	4	%	%	NOUN
eurjchem-597	73	5	.	.	PUNCT
eurjchem-597	74	1	m.p	m.p	PROPN
eurjchem-597	74	2	.	.	PROPN
eurjchem-597	74	3	:	:	PUNCT
eurjchem-597	75	1	110‐	110‐	NUM
eurjchem-597	75	2	112	112	NUM
eurjchem-597	75	3	oc	oc	NOUN
eurjchem-597	75	4	.	.	PUNCT
eurjchem-597	76	1	ir	ir	PROPN
eurjchem-597	76	2	(	(	PUNCT
eurjchem-597	76	3	kbr	kbr	PROPN
eurjchem-597	76	4	,	,	PUNCT
eurjchem-597	76	5	ν	ν	PROPN
eurjchem-597	76	6	,	,	PUNCT
eurjchem-597	76	7	cm‐1	cm‐1	PROPN
eurjchem-597	76	8	):	):	PUNCT
eurjchem-597	76	9	1738	1738	NUM
eurjchem-597	76	10	(	(	PUNCT
eurjchem-597	76	11	c	c	NOUN
eurjchem-597	76	12	=	=	SYM
eurjchem-597	76	13	o	o	NOUN
eurjchem-597	76	14	,	,	PUNCT
eurjchem-597	76	15	ester	ester	NOUN
eurjchem-597	76	16	)	)	PUNCT
eurjchem-597	76	17	.	.	PUNCT
eurjchem-597	77	1	1h	1h	NUM
eurjchem-597	77	2	nmr	nmr	NOUN
eurjchem-597	77	3	(	(	PUNCT
eurjchem-597	77	4	300	300	NUM
eurjchem-597	77	5	mhz	mhz	NOUN
eurjchem-597	77	6	,	,	PUNCT
eurjchem-597	77	7	dmso‐d6	dmso‐d6	NOUN
eurjchem-597	77	8	,	,	PUNCT
eurjchem-597	77	9			NUM
eurjchem-597	77	10	,	,	PUNCT
eurjchem-597	77	11	ppm	ppm	NUM
eurjchem-597	77	12	):	):	PUNCT
eurjchem-597	77	13	1.2	1.2	NUM
eurjchem-597	77	14	(	(	PUNCT
eurjchem-597	77	15	t	t	PROPN
eurjchem-597	77	16	,	,	PUNCT
eurjchem-597	77	17	3h	3h	NUM
eurjchem-597	77	18	,	,	PUNCT
eurjchem-597	77	19	ch3	ch3	PROPN
eurjchem-597	77	20	ch2	ch2	PROPN
eurjchem-597	77	21	)	)	PUNCT
eurjchem-597	77	22	,	,	PUNCT
eurjchem-597	77	23	4.3	4.3	NUM
eurjchem-597	77	24	(	(	PUNCT
eurjchem-597	77	25	q	q	NOUN
eurjchem-597	77	26	,	,	PUNCT
eurjchem-597	77	27	2h	2h	NUM
eurjchem-597	77	28	,	,	PUNCT
eurjchem-597	77	29	ch3ch2	ch3ch2	PROPN
eurjchem-597	77	30	)	)	PUNCT
eurjchem-597	77	31	,	,	PUNCT
eurjchem-597	77	32	4.7	4.7	NUM
eurjchem-597	77	33	(	(	PUNCT
eurjchem-597	77	34	s	s	PROPN
eurjchem-597	77	35	,	,	PUNCT
eurjchem-597	77	36	2h	2h	NUM
eurjchem-597	77	37	,	,	PUNCT
eurjchem-597	77	38	sch2	sch2	PROPN
eurjchem-597	77	39	)	)	PUNCT
eurjchem-597	77	40	,	,	PUNCT
eurjchem-597	77	41	7.0‐8.4	7.0‐8.4	NUM
eurjchem-597	77	42	(	(	PUNCT
eurjchem-597	77	43	m	m	PROPN
eurjchem-597	77	44	,	,	PUNCT
eurjchem-597	77	45	14h	14h	NUM
eurjchem-597	77	46	,	,	PUNCT
eurjchem-597	77	47	ar‐h	ar‐h	NOUN
eurjchem-597	77	48	)	)	PUNCT
eurjchem-597	77	49	.	.	PUNCT
eurjchem-597	78	1	anal	anal	PROPN
eurjchem-597	78	2	.	.	PUNCT
eurjchem-597	78	3	calcd	calcd	NOUN
eurjchem-597	78	4	.	.	PUNCT
eurjchem-597	79	1	for	for	ADP
eurjchem-597	79	2	c26h21cln2o2s	c26h21cln2o2s	NOUN
eurjchem-597	79	3	:	:	PUNCT
eurjchem-597	79	4	c	c	X
eurjchem-597	79	5	,	,	PUNCT
eurjchem-597	79	6	67.74	67.74	NUM
eurjchem-597	79	7	;	;	PUNCT
eurjchem-597	79	8	h	h	NOUN
eurjchem-597	79	9	,	,	PUNCT
eurjchem-597	79	10	4.59	4.59	NUM
eurjchem-597	79	11	;	;	PUNCT
eurjchem-597	79	12	n	n	CCONJ
eurjchem-597	79	13	,	,	PUNCT
eurjchem-597	79	14	6.08	6.08	NUM
eurjchem-597	79	15	;	;	PUNCT
eurjchem-597	79	16	s	s	X
eurjchem-597	79	17	,	,	PUNCT
eurjchem-597	79	18	6.96	6.96	NUM
eurjchem-597	79	19	.	.	PUNCT
eurjchem-597	79	20	found	find	VERB
eurjchem-597	79	21	:	:	PUNCT
eurjchem-597	80	1	c	c	X
eurjchem-597	80	2	,	,	PUNCT
eurjchem-597	80	3	67.69	67.69	NUM
eurjchem-597	80	4	;	;	PUNCT
eurjchem-597	80	5	h	h	NOUN
eurjchem-597	80	6	,	,	PUNCT
eurjchem-597	80	7	4.61	4.61	NUM
eurjchem-597	80	8	;	;	PUNCT
eurjchem-597	80	9	n	n	CCONJ
eurjchem-597	80	10	,	,	PUNCT
eurjchem-597	80	11	6.12	6.12	NUM
eurjchem-597	80	12	;	;	PUNCT
eurjchem-597	80	13	s	s	X
eurjchem-597	80	14	,	,	PUNCT
eurjchem-597	80	15	6.98	6.98	NUM
eurjchem-597	80	16	%	%	NOUN
eurjchem-597	80	17	.	.	PUNCT
eurjchem-597	81	1	ethyl	ethyl	PROPN
eurjchem-597	81	2	2‐(4‐chlorophenyl)‐4‐(2‐ethoxy‐2‐oxoethylthio)‐6‐	2‐(4‐chlorophenyl)‐4‐(2‐ethoxy‐2‐oxoethylthio)‐6‐	NUM
eurjchem-597	81	3	phenylpyrimidine‐5‐carboxylate	phenylpyrimidine‐5‐carboxylate	PROPN
eurjchem-597	81	4	(	(	PUNCT
eurjchem-597	81	5	7b	7b	NUM
eurjchem-597	81	6	):	):	PUNCT
eurjchem-597	81	7	a	a	DET
eurjchem-597	81	8	pale	pale	ADJ
eurjchem-597	81	9	yellow	yellow	ADJ
eurjchem-597	81	10	powder	powder	NOUN
eurjchem-597	81	11	.	.	PUNCT
eurjchem-597	81	12	yield	yield	NOUN
eurjchem-597	81	13	:	:	PUNCT
eurjchem-597	81	14	87	87	NUM
eurjchem-597	81	15	%	%	NOUN
eurjchem-597	81	16	.	.	PUNCT
eurjchem-597	82	1	m.p	m.p	PROPN
eurjchem-597	82	2	.	.	PROPN
eurjchem-597	82	3	:	:	PUNCT
eurjchem-597	83	1	120‐122	120‐122	NUM
eurjchem-597	83	2	oc	oc	X
eurjchem-597	83	3	.	.	PUNCT
eurjchem-597	83	4	ir	ir	PROPN
eurjchem-597	83	5	(	(	PUNCT
eurjchem-597	83	6	kbr	kbr	PROPN
eurjchem-597	83	7	,	,	PUNCT
eurjchem-597	83	8	ν	ν	PROPN
eurjchem-597	83	9	,	,	PUNCT
eurjchem-597	83	10	cm‐1	cm‐1	PROPN
eurjchem-597	83	11	):	):	PUNCT
eurjchem-597	83	12	1712	1712	NUM
eurjchem-597	83	13	(	(	PUNCT
eurjchem-597	83	14	c	c	NOUN
eurjchem-597	83	15	=	=	SYM
eurjchem-597	83	16	o	o	NOUN
eurjchem-597	83	17	,	,	PUNCT
eurjchem-597	83	18	ester	ester	NOUN
eurjchem-597	83	19	)	)	PUNCT
eurjchem-597	83	20	,	,	PUNCT
eurjchem-597	83	21	1698	1698	NUM
eurjchem-597	83	22	(	(	PUNCT
eurjchem-597	83	23	c	c	NOUN
eurjchem-597	83	24	=	=	SYM
eurjchem-597	83	25	o	o	NOUN
eurjchem-597	83	26	,	,	PUNCT
eurjchem-597	83	27	ketonic	ketonic	ADJ
eurjchem-597	83	28	)	)	PUNCT
eurjchem-597	83	29	.	.	PUNCT
eurjchem-597	84	1	1h	1h	NUM
eurjchem-597	84	2	nmr	nmr	NOUN
eurjchem-597	84	3	(	(	PUNCT
eurjchem-597	84	4	300	300	NUM
eurjchem-597	84	5	mhz	mhz	NOUN
eurjchem-597	84	6	,	,	PUNCT
eurjchem-597	84	7	dmso‐d6	dmso‐d6	NOUN
eurjchem-597	84	8	,	,	PUNCT
eurjchem-597	84	9			NUM
eurjchem-597	84	10	,	,	PUNCT
eurjchem-597	84	11	ppm	ppm	NUM
eurjchem-597	84	12	):	):	PUNCT
eurjchem-597	84	13	1.1	1.1	NUM
eurjchem-597	84	14	(	(	PUNCT
eurjchem-597	84	15	t	t	PROPN
eurjchem-597	84	16	,	,	PUNCT
eurjchem-597	84	17	3h	3h	NUM
eurjchem-597	84	18	,	,	PUNCT
eurjchem-597	84	19	ch3ch2	ch3ch2	PROPN
eurjchem-597	84	20	)	)	PUNCT
eurjchem-597	84	21	,	,	PUNCT
eurjchem-597	84	22	1.3	1.3	NUM
eurjchem-597	84	23	(	(	PUNCT
eurjchem-597	84	24	t	t	PROPN
eurjchem-597	84	25	,	,	PUNCT
eurjchem-597	84	26	3h	3h	NUM
eurjchem-597	84	27	,	,	PUNCT
eurjchem-597	84	28	ch3h2	ch3h2	PROPN
eurjchem-597	84	29	)	)	PUNCT
eurjchem-597	84	30	,	,	PUNCT
eurjchem-597	84	31	3.2	3.2	NUM
eurjchem-597	84	32	(	(	PUNCT
eurjchem-597	84	33	s	s	PROPN
eurjchem-597	84	34	,	,	PUNCT
eurjchem-597	84	35	2h	2h	NUM
eurjchem-597	84	36	,	,	PUNCT
eurjchem-597	84	37	sch2	sch2	PROPN
eurjchem-597	84	38	)	)	PUNCT
eurjchem-597	84	39	,	,	PUNCT
eurjchem-597	84	40	4.2	4.2	NUM
eurjchem-597	84	41	(	(	PUNCT
eurjchem-597	84	42	q	q	NOUN
eurjchem-597	84	43	,	,	PUNCT
eurjchem-597	84	44	2h	2h	NUM
eurjchem-597	84	45	,	,	PUNCT
eurjchem-597	84	46	ch3ch2	ch3ch2	PROPN
eurjchem-597	84	47	)	)	PUNCT
eurjchem-597	84	48	,	,	PUNCT
eurjchem-597	84	49	4.4	4.4	NUM
eurjchem-597	84	50	(	(	PUNCT
eurjchem-597	84	51	q	q	NOUN
eurjchem-597	84	52	,	,	PUNCT
eurjchem-597	84	53	2h	2h	NUM
eurjchem-597	84	54	,	,	PUNCT
eurjchem-597	84	55	ch3ch2	ch3ch2	PROPN
eurjchem-597	84	56	)	)	PUNCT
eurjchem-597	84	57	,	,	PUNCT
eurjchem-597	84	58	7.2‐8.2	7.2‐8.2	X
eurjchem-597	84	59	(	(	PUNCT
eurjchem-597	84	60	m	m	PROPN
eurjchem-597	84	61	,	,	PUNCT
eurjchem-597	84	62	9h	9h	NUM
eurjchem-597	84	63	,	,	PUNCT
eurjchem-597	84	64	ar‐h	ar‐h	NOUN
eurjchem-597	84	65	)	)	PUNCT
eurjchem-597	84	66	.	.	PUNCT
eurjchem-597	85	1	anal	anal	PROPN
eurjchem-597	85	2	.	.	PUNCT
eurjchem-597	85	3	calcd	calcd	NOUN
eurjchem-597	85	4	.	.	PUNCT
eurjchem-597	86	1	for	for	ADP
eurjchem-597	86	2	c23h2cln2o4s	c23h2cln2o4s	PROPN
eurjchem-597	86	3	:	:	PUNCT
eurjchem-597	86	4	c	c	X
eurjchem-597	86	5	,	,	PUNCT
eurjchem-597	86	6	60.46	60.46	NUM
eurjchem-597	86	7	;	;	PUNCT
eurjchem-597	86	8	h	h	NOUN
eurjchem-597	86	9	,	,	PUNCT
eurjchem-597	86	10	4.63	4.63	NUM
eurjchem-597	86	11	;	;	PUNCT
eurjchem-597	86	12	n	n	CCONJ
eurjchem-597	86	13	,	,	PUNCT
eurjchem-597	86	14	6.13	6.13	NUM
eurjchem-597	86	15	;	;	PUNCT
eurjchem-597	86	16	s	s	X
eurjchem-597	86	17	,	,	PUNCT
eurjchem-597	86	18	7.02	7.02	NUM
eurjchem-597	86	19	.	.	PUNCT
eurjchem-597	86	20	found	find	VERB
eurjchem-597	86	21	:	:	PUNCT
eurjchem-597	87	1	c	c	X
eurjchem-597	87	2	,	,	PUNCT
eurjchem-597	87	3	60.44	60.44	NUM
eurjchem-597	87	4	;	;	PUNCT
eurjchem-597	87	5	h	h	NOUN
eurjchem-597	87	6	,	,	PUNCT
eurjchem-597	87	7	4.59	4.59	NUM
eurjchem-597	87	8	;	;	PUNCT
eurjchem-597	87	9	n	n	CCONJ
eurjchem-597	87	10	,	,	PUNCT
eurjchem-597	87	11	6.11	6.11	NUM
eurjchem-597	87	12	;	;	PUNCT
eurjchem-597	87	13	s	s	X
eurjchem-597	87	14	,	,	PUNCT
eurjchem-597	87	15	7.00	7.00	NUM
eurjchem-597	87	16	%	%	NOUN
eurjchem-597	87	17	.	.	PUNCT
eurjchem-597	88	1	ethyl	ethyl	PROPN
eurjchem-597	88	2	4‐(2‐amino‐2‐oxoethylthio)‐2‐(4‐chlorophenyl)‐6‐	4‐(2‐amino‐2‐oxoethylthio)‐2‐(4‐chlorophenyl)‐6‐	PROPN
eurjchem-597	89	1	phenylpyrimidine‐5‐carboxylate	phenylpyrimidine‐5‐carboxylate	PROPN
eurjchem-597	89	2	(	(	PUNCT
eurjchem-597	89	3	7c	7c	NUM
eurjchem-597	89	4	):	):	PUNCT
eurjchem-597	89	5	yellow	yellow	ADJ
eurjchem-597	89	6	crystal	crystal	NOUN
eurjchem-597	89	7	.	.	PUNCT
eurjchem-597	89	8	yield	yield	NOUN
eurjchem-597	89	9	:	:	PUNCT
eurjchem-597	89	10	75	75	NUM
eurjchem-597	89	11	%	%	NOUN
eurjchem-597	89	12	.	.	PUNCT
eurjchem-597	90	1	m.p	m.p	PROPN
eurjchem-597	90	2	.	.	PROPN
eurjchem-597	90	3	:	:	PUNCT
eurjchem-597	91	1	130‐132	130‐132	NUM
eurjchem-597	91	2	oc	oc	PROPN
eurjchem-597	91	3	.	.	PROPN
eurjchem-597	92	1	ir	ir	PROPN
eurjchem-597	92	2	(	(	PUNCT
eurjchem-597	92	3	kbr	kbr	PROPN
eurjchem-597	92	4	,	,	PUNCT
eurjchem-597	92	5	ν	ν	PROPN
eurjchem-597	92	6	,	,	PUNCT
eurjchem-597	92	7	cm‐1	cm‐1	PROPN
eurjchem-597	92	8	):	):	PUNCT
eurjchem-597	92	9	1725	1725	NUM
eurjchem-597	92	10	(	(	PUNCT
eurjchem-597	92	11	c	c	NOUN
eurjchem-597	92	12	=	=	SYM
eurjchem-597	92	13	o	o	NOUN
eurjchem-597	92	14	,	,	PUNCT
eurjchem-597	92	15	ester	ester	NOUN
eurjchem-597	92	16	)	)	PUNCT
eurjchem-597	92	17	,	,	PUNCT
eurjchem-597	92	18	1649	1649	NUM
eurjchem-597	92	19	(	(	PUNCT
eurjchem-597	92	20	c	c	NOUN
eurjchem-597	92	21	=	=	SYM
eurjchem-597	92	22	o	o	NOUN
eurjchem-597	92	23	,	,	PUNCT
eurjchem-597	92	24	amide	amide	NOUN
eurjchem-597	92	25	)	)	PUNCT
eurjchem-597	92	26	.	.	PUNCT
eurjchem-597	93	1	1h	1h	NUM
eurjchem-597	93	2	nmr	nmr	NOUN
eurjchem-597	93	3	(	(	PUNCT
eurjchem-597	93	4	300	300	NUM
eurjchem-597	93	5	mhz	mhz	NOUN
eurjchem-597	93	6	,	,	PUNCT
eurjchem-597	93	7	dmso‐d6	dmso‐d6	NOUN
eurjchem-597	93	8	,	,	PUNCT
eurjchem-597	93	9			NUM
eurjchem-597	93	10	,	,	PUNCT
eurjchem-597	93	11	ppm	ppm	NUM
eurjchem-597	93	12	):	):	PUNCT
eurjchem-597	93	13	1.3	1.3	NUM
eurjchem-597	93	14	(	(	PUNCT
eurjchem-597	93	15	t	t	PROPN
eurjchem-597	93	16	,	,	PUNCT
eurjchem-597	93	17	3h	3h	NUM
eurjchem-597	93	18	,	,	PUNCT
eurjchem-597	93	19	ch3ch2	ch3ch2	PROPN
eurjchem-597	93	20	)	)	PUNCT
eurjchem-597	93	21	,	,	PUNCT
eurjchem-597	93	22	3.8	3.8	NUM
eurjchem-597	93	23	(	(	PUNCT
eurjchem-597	93	24	s	s	PROPN
eurjchem-597	93	25	,	,	PUNCT
eurjchem-597	93	26	2h	2h	NUM
eurjchem-597	93	27	,	,	PUNCT
eurjchem-597	93	28	sch2	sch2	PROPN
eurjchem-597	93	29	)	)	PUNCT
eurjchem-597	93	30	,	,	PUNCT
eurjchem-597	93	31	4.3	4.3	NUM
eurjchem-597	93	32	(	(	PUNCT
eurjchem-597	93	33	q	q	NOUN
eurjchem-597	93	34	,	,	PUNCT
eurjchem-597	93	35	2h	2h	NUM
eurjchem-597	93	36	,	,	PUNCT
eurjchem-597	93	37	ch3ch2	ch3ch2	PROPN
eurjchem-597	93	38	)	)	PUNCT
eurjchem-597	93	39	,	,	PUNCT
eurjchem-597	93	40	6.8	6.8	NUM
eurjchem-597	93	41	(	(	PUNCT
eurjchem-597	93	42	s	s	PROPN
eurjchem-597	93	43	,	,	PUNCT
eurjchem-597	93	44	2h	2h	NUM
eurjchem-597	93	45	,	,	PUNCT
eurjchem-597	93	46	nh2	nh2	PROPN
eurjchem-597	93	47	)	)	PUNCT
eurjchem-597	93	48	,	,	PUNCT
eurjchem-597	93	49	7.2‐8.4	7.2‐8.4	NUM
eurjchem-597	93	50	(	(	PUNCT
eurjchem-597	93	51	m	m	PROPN
eurjchem-597	93	52	,	,	PUNCT
eurjchem-597	93	53	9h	9h	NUM
eurjchem-597	93	54	,	,	PUNCT
eurjchem-597	93	55	ar‐h	ar‐h	NOUN
eurjchem-597	93	56	)	)	PUNCT
eurjchem-597	93	57	.	.	PUNCT
eurjchem-597	94	1	anal	anal	PROPN
eurjchem-597	94	2	.	.	PUNCT
eurjchem-597	94	3	calcd	calcd	NOUN
eurjchem-597	94	4	.	.	PUNCT
eurjchem-597	95	1	for	for	ADP
eurjchem-597	95	2	c21h18cln3o3s	c21h18cln3o3	NOUN
eurjchem-597	95	3	:	:	PUNCT
eurjchem-597	95	4	c	c	X
eurjchem-597	95	5	,	,	PUNCT
eurjchem-597	95	6	58.94	58.94	NUM
eurjchem-597	95	7	;	;	PUNCT
eurjchem-597	95	8	h	h	NOUN
eurjchem-597	95	9	,	,	PUNCT
eurjchem-597	95	10	4.24	4.24	NUM
eurjchem-597	95	11	;	;	PUNCT
eurjchem-597	95	12	n	n	CCONJ
eurjchem-597	95	13	,	,	PUNCT
eurjchem-597	95	14	9.82	9.82	NUM
eurjchem-597	95	15	;	;	PUNCT
eurjchem-597	95	16	s	s	X
eurjchem-597	95	17	,	,	PUNCT
eurjchem-597	95	18	7.49	7.49	NUM
eurjchem-597	95	19	.	.	PUNCT
eurjchem-597	95	20	found	find	VERB
eurjchem-597	95	21	:	:	PUNCT
eurjchem-597	96	1	c	c	X
eurjchem-597	96	2	,	,	PUNCT
eurjchem-597	96	3	58.89	58.89	NUM
eurjchem-597	96	4	;	;	PUNCT
eurjchem-597	96	5	h	h	NOUN
eurjchem-597	96	6	,	,	PUNCT
eurjchem-597	96	7	4.21	4.21	NUM
eurjchem-597	96	8	;	;	PUNCT
eurjchem-597	96	9	n	n	CCONJ
eurjchem-597	96	10	,	,	PUNCT
eurjchem-597	96	11	9.79	9.79	NUM
eurjchem-597	96	12	;	;	PUNCT
eurjchem-597	96	13	s	s	NOUN
eurjchem-597	96	14	,	,	PUNCT
eurjchem-597	96	15	7.44	7.44	NUM
eurjchem-597	96	16	%	%	NOUN
eurjchem-597	96	17	.	.	PUNCT
eurjchem-597	97	1	ethyl	ethyl	PROPN
eurjchem-597	97	2	2‐(4‐chlorophenyl)‐4‐(2‐oxo‐2‐phenylethylthio)‐6‐	2‐(4‐chlorophenyl)‐4‐(2‐oxo‐2‐phenylethylthio)‐6‐	NUM
eurjchem-597	97	3	phenylpyrimidine‐5‐carboxylate	phenylpyrimidine‐5‐carboxylate	ADJ
eurjchem-597	97	4	(	(	PUNCT
eurjchem-597	97	5	7d	7d	NUM
eurjchem-597	97	6	):	):	PUNCT
eurjchem-597	97	7	yellow	yellow	ADJ
eurjchem-597	97	8	crystal	crystal	NOUN
eurjchem-597	97	9	.	.	PUNCT
eurjchem-597	98	1	yield	yield	NOUN
eurjchem-597	98	2	:	:	PUNCT
eurjchem-597	98	3	80	80	NUM
eurjchem-597	98	4	%	%	NOUN
eurjchem-597	98	5	.	.	PUNCT
eurjchem-597	99	1	m.p	m.p	PROPN
eurjchem-597	99	2	.	.	PROPN
eurjchem-597	99	3	:	:	PUNCT
eurjchem-597	100	1	135‐138	135‐138	NUM
eurjchem-597	100	2	oc	oc	NOUN
eurjchem-597	100	3	.	.	PROPN
eurjchem-597	100	4	ir	ir	PROPN
eurjchem-597	100	5	(	(	PUNCT
eurjchem-597	100	6	kbr	kbr	PROPN
eurjchem-597	100	7	,	,	PUNCT
eurjchem-597	100	8	ν	ν	PROPN
eurjchem-597	100	9	,	,	PUNCT
eurjchem-597	100	10	cm‐1	cm‐1	PROPN
eurjchem-597	100	11	):	):	PUNCT
eurjchem-597	100	12	1712	1712	NUM
eurjchem-597	100	13	(	(	PUNCT
eurjchem-597	100	14	c	c	NOUN
eurjchem-597	100	15	=	=	SYM
eurjchem-597	100	16	o	o	NOUN
eurjchem-597	100	17	,	,	PUNCT
eurjchem-597	100	18	ketonic	ketonic	ADJ
eurjchem-597	100	19	)	)	PUNCT
eurjchem-597	100	20	,	,	PUNCT
eurjchem-597	100	21	1698	1698	NUM
eurjchem-597	100	22	(	(	PUNCT
eurjchem-597	100	23	c	c	NOUN
eurjchem-597	100	24	=	=	SYM
eurjchem-597	100	25	o	o	NOUN
eurjchem-597	100	26	,	,	PUNCT
eurjchem-597	100	27	ester	ester	NOUN
eurjchem-597	100	28	)	)	PUNCT
eurjchem-597	100	29	.	.	PUNCT
eurjchem-597	101	1	1h	1h	NUM
eurjchem-597	101	2	nmr	nmr	NOUN
eurjchem-597	101	3	(	(	PUNCT
eurjchem-597	101	4	300	300	NUM
eurjchem-597	101	5	mhz	mhz	NOUN
eurjchem-597	101	6	,	,	PUNCT
eurjchem-597	101	7	dmso‐d6	dmso‐d6	NOUN
eurjchem-597	101	8	,	,	PUNCT
eurjchem-597	101	9			NUM
eurjchem-597	101	10	,	,	PUNCT
eurjchem-597	101	11	ppm	ppm	NUM
eurjchem-597	101	12	):	):	PUNCT
eurjchem-597	101	13	1.3	1.3	NUM
eurjchem-597	101	14	(	(	PUNCT
eurjchem-597	101	15	t	t	PROPN
eurjchem-597	101	16	,	,	PUNCT
eurjchem-597	101	17	3h	3h	NUM
eurjchem-597	101	18	,	,	PUNCT
eurjchem-597	101	19	ch3ch2	ch3ch2	PROPN
eurjchem-597	101	20	)	)	PUNCT
eurjchem-597	101	21	,	,	PUNCT
eurjchem-597	101	22	4.2	4.2	NUM
eurjchem-597	101	23	(	(	PUNCT
eurjchem-597	101	24	q	q	NOUN
eurjchem-597	101	25	,	,	PUNCT
eurjchem-597	101	26	2h	2h	NUM
eurjchem-597	101	27	,	,	PUNCT
eurjchem-597	101	28	ch3ch2	ch3ch2	PROPN
eurjchem-597	101	29	)	)	PUNCT
eurjchem-597	101	30	,	,	PUNCT
eurjchem-597	101	31	4.6	4.6	NUM
eurjchem-597	101	32	(	(	PUNCT
eurjchem-597	101	33	s	s	PROPN
eurjchem-597	101	34	,	,	PUNCT
eurjchem-597	101	35	2h	2h	NUM
eurjchem-597	101	36	,	,	PUNCT
eurjchem-597	101	37	sch2	sch2	PROPN
eurjchem-597	101	38	)	)	PUNCT
eurjchem-597	101	39	,	,	PUNCT
eurjchem-597	101	40	7.0‐8.4	7.0‐8.4	NUM
eurjchem-597	101	41	(	(	PUNCT
eurjchem-597	101	42	m	m	PROPN
eurjchem-597	101	43	,	,	PUNCT
eurjchem-597	101	44	14	14	NUM
eurjchem-597	101	45	,	,	PUNCT
eurjchem-597	101	46	ar‐h	ar‐h	NOUN
eurjchem-597	101	47	)	)	PUNCT
eurjchem-597	101	48	.	.	PUNCT
eurjchem-597	102	1	anal	anal	PROPN
eurjchem-597	102	2	.	.	PUNCT
eurjchem-597	102	3	calcd	calcd	NOUN
eurjchem-597	102	4	.	.	PUNCT
eurjchem-597	103	1	for	for	ADP
eurjchem-597	103	2	c27h21cln2o3s	c27h21cln2o3s	NOUN
eurjchem-597	103	3	:	:	PUNCT
eurjchem-597	103	4	c	c	X
eurjchem-597	103	5	,	,	PUNCT
eurjchem-597	103	6	66.32	66.32	NUM
eurjchem-597	103	7	;	;	PUNCT
eurjchem-597	103	8	h	h	NOUN
eurjchem-597	103	9	,	,	PUNCT
eurjchem-597	103	10	4.33	4.33	NUM
eurjchem-597	103	11	;	;	PUNCT
eurjchem-597	103	12	n	n	CCONJ
eurjchem-597	103	13	,	,	PUNCT
eurjchem-597	103	14	5.73	5.73	NUM
eurjchem-597	103	15	;	;	PUNCT
eurjchem-597	103	16	s	s	X
eurjchem-597	103	17	,	,	PUNCT
eurjchem-597	103	18	6.56	6.56	NUM
eurjchem-597	103	19	.	.	PUNCT
eurjchem-597	103	20	found	find	VERB
eurjchem-597	103	21	:	:	PUNCT
eurjchem-597	104	1	c	c	X
eurjchem-597	104	2	,	,	PUNCT
eurjchem-597	104	3	66.21	66.21	NUM
eurjchem-597	104	4	;	;	PUNCT
eurjchem-597	105	1	h	h	NOUN
eurjchem-597	105	2	,	,	PUNCT
eurjchem-597	105	3	4.19	4.19	NUM
eurjchem-597	105	4	;	;	PUNCT
eurjchem-597	105	5	n	n	CCONJ
eurjchem-597	105	6	,	,	PUNCT
eurjchem-597	105	7	5.52	5.52	NUM
eurjchem-597	105	8	,	,	PUNCT
eurjchem-597	105	9	s	s	NOUN
eurjchem-597	105	10	,	,	PUNCT
eurjchem-597	105	11	6.41	6.41	NUM
eurjchem-597	105	12	%	%	NOUN
eurjchem-597	105	13	.	.	PUNCT
eurjchem-597	106	1	2.2.5	2.2.5	X
eurjchem-597	106	2	.	.	X
eurjchem-597	106	3	synthesis	synthesis	NOUN
eurjchem-597	106	4	of	of	ADP
eurjchem-597	106	5	compounds	compound	NOUN
eurjchem-597	106	6	8a‐d	8a‐d	ADP
eurjchem-597	106	7	a	a	DET
eurjchem-597	106	8	mixture	mixture	NOUN
eurjchem-597	106	9	of	of	ADP
eurjchem-597	106	10	appropriate	appropriate	ADJ
eurjchem-597	106	11	pyrimidine	pyrimidine	NOUN
eurjchem-597	106	12	(	(	PUNCT
eurjchem-597	106	13	7a‐d	7a‐d	NOUN
eurjchem-597	106	14	)	)	PUNCT
eurjchem-597	106	15	(	(	PUNCT
eurjchem-597	106	16	0.01	0.01	NUM
eurjchem-597	106	17	mol	mol	NOUN
eurjchem-597	106	18	)	)	PUNCT
eurjchem-597	106	19	and	and	CCONJ
eurjchem-597	106	20	sodium	sodium	NOUN
eurjchem-597	106	21	ethoxide	ethoxide	NOUN
eurjchem-597	106	22	(	(	PUNCT
eurjchem-597	106	23	0.01	0.01	NUM
eurjchem-597	106	24	mol	mol	NOUN
eurjchem-597	106	25	)	)	PUNCT
eurjchem-597	106	26	in	in	ADP
eurjchem-597	106	27	ethanol	ethanol	NOUN
eurjchem-597	106	28	(	(	PUNCT
eurjchem-597	106	29	30	30	NUM
eurjchem-597	106	30	ml	ml	NOUN
eurjchem-597	106	31	)	)	PUNCT
eurjchem-597	106	32	was	be	AUX
eurjchem-597	106	33	heated	heat	VERB
eurjchem-597	106	34	under	under	ADP
eurjchem-597	106	35	reflux	reflux	NOUN
eurjchem-597	106	36	for	for	ADP
eurjchem-597	106	37	30	30	NUM
eurjchem-597	106	38	min	min	NOUN
eurjchem-597	106	39	.	.	PUNCT
eurjchem-597	107	1	the	the	DET
eurjchem-597	107	2	precipitate	precipitate	NOUN
eurjchem-597	107	3	formed	form	VERB
eurjchem-597	107	4	after	after	ADP
eurjchem-597	107	5	cooling	cool	VERB
eurjchem-597	107	6	and	and	CCONJ
eurjchem-597	107	7	acidification	acidification	NOUN
eurjchem-597	107	8	with	with	ADP
eurjchem-597	107	9	hydrochloric	hydrochloric	ADJ
eurjchem-597	107	10	acid	acid	NOUN
eurjchem-597	107	11	(	(	PUNCT
eurjchem-597	107	12	3	3	NUM
eurjchem-597	107	13	ml	ml	NOUN
eurjchem-597	107	14	,	,	PUNCT
eurjchem-597	107	15	60	60	NUM
eurjchem-597	107	16	%	%	NOUN
eurjchem-597	107	17	)	)	PUNCT
eurjchem-597	107	18	was	be	AUX
eurjchem-597	107	19	collected	collect	VERB
eurjchem-597	107	20	and	and	CCONJ
eurjchem-597	107	21	crystallized	crystallize	VERB
eurjchem-597	107	22	from	from	ADP
eurjchem-597	107	23	suitable	suitable	ADJ
eurjchem-597	107	24	solvent	solvent	NOUN
eurjchem-597	107	25	(	(	PUNCT
eurjchem-597	107	26	scheme	scheme	NOUN
eurjchem-597	107	27	2	2	NUM
eurjchem-597	107	28	)	)	PUNCT
eurjchem-597	107	29	.	.	PUNCT
eurjchem-597	108	1	shehab	shehab	PROPN
eurjchem-597	108	2	and	and	CCONJ
eurjchem-597	108	3	mohamed	mohamed	PROPN
eurjchem-597	108	4	/	/	SYM
eurjchem-597	108	5	european	european	PROPN
eurjchem-597	108	6	journal	journal	PROPN
eurjchem-597	108	7	of	of	ADP
eurjchem-597	108	8	chemistry	chemistry	NOUN
eurjchem-597	108	9	3	3	NUM
eurjchem-597	108	10	(	(	PUNCT
eurjchem-597	108	11	2	2	NUM
eurjchem-597	108	12	)	)	PUNCT
eurjchem-597	108	13	(	(	PUNCT
eurjchem-597	108	14	2012	2012	NUM
eurjchem-597	108	15	)	)	PUNCT
eurjchem-597	108	16	241‐246	241‐246	NUM
eurjchem-597	109	1	243	243	NUM
eurjchem-597	109	2	scheme	scheme	NOUN
eurjchem-597	109	3	2	2	NUM
eurjchem-597	109	4	2‐(4‐chlorophenyl)‐4,6‐diphenylthieno	2‐(4‐chlorophenyl)‐4,6‐diphenylthieno	NOUN
eurjchem-597	110	1	[	[	X
eurjchem-597	110	2	2,3‐d	2,3‐d	X
eurjchem-597	110	3	]	]	PUNCT
eurjchem-597	110	4	pyrimidin‐5‐ol	pyrimidin‐5‐ol	X
eurjchem-597	110	5	(	(	PUNCT
eurjchem-597	110	6	8a	8a	NUM
eurjchem-597	110	7	):	):	PUNCT
eurjchem-597	110	8	a	a	DET
eurjchem-597	110	9	colorless	colorless	ADJ
eurjchem-597	110	10	crystals	crystal	NOUN
eurjchem-597	110	11	.	.	PUNCT
eurjchem-597	111	1	yield	yield	NOUN
eurjchem-597	111	2	:	:	PUNCT
eurjchem-597	111	3	42	42	NUM
eurjchem-597	111	4	%	%	NOUN
eurjchem-597	111	5	.	.	PUNCT
eurjchem-597	112	1	m.p	m.p	PROPN
eurjchem-597	112	2	.	.	PROPN
eurjchem-597	112	3	:	:	PUNCT
eurjchem-597	113	1	220‐222	220‐222	NUM
eurjchem-597	113	2	oc	oc	PROPN
eurjchem-597	113	3	.	.	PROPN
eurjchem-597	113	4	ir	ir	PROPN
eurjchem-597	113	5	(	(	PUNCT
eurjchem-597	113	6	kbr	kbr	PROPN
eurjchem-597	113	7	,	,	PUNCT
eurjchem-597	113	8	ν	ν	PROPN
eurjchem-597	113	9	,	,	PUNCT
eurjchem-597	113	10	cm‐1	cm‐1	PROPN
eurjchem-597	113	11	):	):	PUNCT
eurjchem-597	113	12	3500	3500	NUM
eurjchem-597	113	13	(	(	PUNCT
eurjchem-597	113	14	oh	oh	INTJ
eurjchem-597	113	15	)	)	PUNCT
eurjchem-597	113	16	,	,	PUNCT
eurjchem-597	113	17	1610	1610	NUM
eurjchem-597	113	18	(	(	PUNCT
eurjchem-597	113	19	c	c	NOUN
eurjchem-597	113	20	=	=	SYM
eurjchem-597	113	21	n	n	NUM
eurjchem-597	113	22	)	)	PUNCT
eurjchem-597	113	23	.	.	PUNCT
eurjchem-597	114	1	1h	1h	NUM
eurjchem-597	114	2	nmr	nmr	NOUN
eurjchem-597	114	3	(	(	PUNCT
eurjchem-597	114	4	300	300	NUM
eurjchem-597	114	5	mhz	mhz	NOUN
eurjchem-597	114	6	,	,	PUNCT
eurjchem-597	114	7	dmso‐d6	dmso‐d6	NOUN
eurjchem-597	114	8	,	,	PUNCT
eurjchem-597	114	9			NUM
eurjchem-597	114	10	,	,	PUNCT
eurjchem-597	114	11	ppm	ppm	NUM
eurjchem-597	114	12	):	):	PUNCT
eurjchem-597	114	13	7.0‐8.2	7.0‐8.2	NUM
eurjchem-597	114	14	(	(	PUNCT
eurjchem-597	114	15	m	m	PROPN
eurjchem-597	114	16	,	,	PUNCT
eurjchem-597	114	17	14h	14h	NUM
eurjchem-597	114	18	,	,	PUNCT
eurjchem-597	114	19	ar‐h	ar‐h	NOUN
eurjchem-597	114	20	)	)	PUNCT
eurjchem-597	114	21	,	,	PUNCT
eurjchem-597	114	22	10.1	10.1	NUM
eurjchem-597	114	23	(	(	PUNCT
eurjchem-597	114	24	s	s	PROPN
eurjchem-597	114	25	,	,	PUNCT
eurjchem-597	114	26	1h	1h	NUM
eurjchem-597	114	27	,	,	PUNCT
eurjchem-597	114	28	oh	oh	INTJ
eurjchem-597	114	29	)	)	PUNCT
eurjchem-597	114	30	.	.	PUNCT
eurjchem-597	115	1	anal	anal	PROPN
eurjchem-597	115	2	.	.	PUNCT
eurjchem-597	115	3	calcd	calcd	NOUN
eurjchem-597	115	4	.	.	PUNCT
eurjchem-597	116	1	for	for	ADP
eurjchem-597	116	2	c24h15cln2os	c24h15cln2os	NUM
eurjchem-597	116	3	:	:	PUNCT
eurjchem-597	116	4	c	c	X
eurjchem-597	116	5	,	,	PUNCT
eurjchem-597	116	6	69.48	69.48	NUM
eurjchem-597	116	7	;	;	PUNCT
eurjchem-597	116	8	h	h	NOUN
eurjchem-597	116	9	,	,	PUNCT
eurjchem-597	116	10	3.64	3.64	NUM
eurjchem-597	116	11	;	;	PUNCT
eurjchem-597	116	12	n	n	CCONJ
eurjchem-597	116	13	,	,	PUNCT
eurjchem-597	116	14	6.75	6.75	NUM
eurjchem-597	116	15	;	;	PUNCT
eurjchem-597	116	16	s	s	NUM
eurjchem-597	116	17	,	,	PUNCT
eurjchem-597	116	18	7.73	7.73	NUM
eurjchem-597	116	19	.	.	PUNCT
eurjchem-597	116	20	found	find	VERB
eurjchem-597	116	21	:	:	PUNCT
eurjchem-597	117	1	c	c	X
eurjchem-597	117	2	,	,	PUNCT
eurjchem-597	117	3	69.49	69.49	NUM
eurjchem-597	117	4	;	;	PUNCT
eurjchem-597	117	5	h	h	NOUN
eurjchem-597	117	6	,	,	PUNCT
eurjchem-597	117	7	3.65	3.65	NUM
eurjchem-597	117	8	;	;	PUNCT
eurjchem-597	117	9	n	n	CCONJ
eurjchem-597	117	10	,	,	PUNCT
eurjchem-597	117	11	6.76	6.76	NUM
eurjchem-597	117	12	;	;	PUNCT
eurjchem-597	117	13	s	s	NOUN
eurjchem-597	117	14	,	,	PUNCT
eurjchem-597	117	15	7.74	7.74	NUM
eurjchem-597	117	16	%	%	NOUN
eurjchem-597	117	17	.	.	PUNCT
eurjchem-597	118	1	ethyl	ethyl	PROPN
eurjchem-597	119	1	2‐(4‐chlorophenyl)‐5‐hydroxy‐4‐phenylthieno[2,3‐d	2‐(4‐chlorophenyl)‐5‐hydroxy‐4‐phenylthieno[2,3‐d	X
eurjchem-597	119	2	]	]	X
eurjchem-597	119	3	pyrimidine‐6‐carboxyate	pyrimidine‐6‐carboxyate	X
eurjchem-597	119	4	(	(	PUNCT
eurjchem-597	119	5	8b	8b	NUM
eurjchem-597	119	6	):	):	PUNCT
eurjchem-597	119	7	colorless	colorless	ADJ
eurjchem-597	119	8	crystals	crystal	NOUN
eurjchem-597	119	9	.	.	PUNCT
eurjchem-597	120	1	yield	yield	NOUN
eurjchem-597	120	2	:	:	PUNCT
eurjchem-597	120	3	50	50	NUM
eurjchem-597	120	4	%	%	NOUN
eurjchem-597	120	5	.	.	PUNCT
eurjchem-597	121	1	m.p	m.p	PROPN
eurjchem-597	121	2	.	.	PROPN
eurjchem-597	121	3	:	:	PUNCT
eurjchem-597	122	1	210‐212	210‐212	NUM
eurjchem-597	122	2	oc	oc	VERB
eurjchem-597	122	3	.	.	PROPN
eurjchem-597	122	4	ir	ir	PROPN
eurjchem-597	122	5	(	(	PUNCT
eurjchem-597	122	6	kbr	kbr	PROPN
eurjchem-597	122	7	,	,	PUNCT
eurjchem-597	122	8	ν	ν	PROPN
eurjchem-597	122	9	,	,	PUNCT
eurjchem-597	122	10	cm‐1	cm‐1	PROPN
eurjchem-597	122	11	):	):	PUNCT
eurjchem-597	122	12	3300‐3200	3300‐3200	NUM
eurjchem-597	122	13	(	(	PUNCT
eurjchem-597	122	14	oh	oh	INTJ
eurjchem-597	122	15	)	)	PUNCT
eurjchem-597	122	16	,	,	PUNCT
eurjchem-597	122	17	1725	1725	NUM
eurjchem-597	122	18	(	(	PUNCT
eurjchem-597	122	19	c	c	NOUN
eurjchem-597	122	20	=	=	SYM
eurjchem-597	122	21	o	o	NOUN
eurjchem-597	122	22	,	,	PUNCT
eurjchem-597	122	23	ester	ester	NOUN
eurjchem-597	122	24	)	)	PUNCT
eurjchem-597	122	25	,	,	PUNCT
eurjchem-597	122	26	1692	1692	NUM
eurjchem-597	122	27	(	(	PUNCT
eurjchem-597	122	28	c	c	NOUN
eurjchem-597	122	29	=	=	SYM
eurjchem-597	122	30	o	o	NOUN
eurjchem-597	122	31	,	,	PUNCT
eurjchem-597	122	32	ph	ph	PROPN
eurjchem-597	122	33	)	)	PUNCT
eurjchem-597	122	34	.	.	PUNCT
eurjchem-597	123	1	1h	1h	NUM
eurjchem-597	123	2	nmr	nmr	NOUN
eurjchem-597	123	3	(	(	PUNCT
eurjchem-597	123	4	300	300	NUM
eurjchem-597	123	5	mhz	mhz	NOUN
eurjchem-597	123	6	,	,	PUNCT
eurjchem-597	123	7	dmso‐d6	dmso‐d6	NOUN
eurjchem-597	123	8	,	,	PUNCT
eurjchem-597	123	9			NUM
eurjchem-597	123	10	,	,	PUNCT
eurjchem-597	123	11	ppm	ppm	NUM
eurjchem-597	123	12	):	):	PUNCT
eurjchem-597	123	13	1.34	1.34	NUM
eurjchem-597	123	14	(	(	PUNCT
eurjchem-597	123	15	t	t	PROPN
eurjchem-597	123	16	,	,	PUNCT
eurjchem-597	123	17	3h	3h	NUM
eurjchem-597	123	18	,	,	PUNCT
eurjchem-597	123	19	ch3ch2	ch3ch2	PROPN
eurjchem-597	123	20	)	)	PUNCT
eurjchem-597	123	21	,	,	PUNCT
eurjchem-597	123	22	4.21	4.21	NUM
eurjchem-597	123	23	(	(	PUNCT
eurjchem-597	123	24	q	q	NOUN
eurjchem-597	123	25	,	,	PUNCT
eurjchem-597	123	26	2h	2h	NUM
eurjchem-597	123	27	,	,	PUNCT
eurjchem-597	123	28	ch3ch2	ch3ch2	NOUN
eurjchem-597	123	29	)	)	PUNCT
eurjchem-597	123	30	,	,	PUNCT
eurjchem-597	123	31	7.2‐8.4	7.2‐8.4	NUM
eurjchem-597	123	32	(	(	PUNCT
eurjchem-597	123	33	m	m	PROPN
eurjchem-597	123	34	,	,	PUNCT
eurjchem-597	123	35	9h	9h	NUM
eurjchem-597	123	36	,	,	PUNCT
eurjchem-597	123	37	ar‐h	ar‐h	NOUN
eurjchem-597	123	38	)	)	PUNCT
eurjchem-597	123	39	,	,	PUNCT
eurjchem-597	123	40	10.0	10.0	NUM
eurjchem-597	123	41	(	(	PUNCT
eurjchem-597	123	42	s	s	PROPN
eurjchem-597	123	43	,	,	PUNCT
eurjchem-597	123	44	1h	1h	NUM
eurjchem-597	123	45	,	,	PUNCT
eurjchem-597	123	46	oh	oh	INTJ
eurjchem-597	123	47	)	)	PUNCT
eurjchem-597	123	48	.	.	PUNCT
eurjchem-597	124	1	anal	anal	PROPN
eurjchem-597	124	2	.	.	PUNCT
eurjchem-597	124	3	calcd	calcd	NOUN
eurjchem-597	124	4	.	.	PUNCT
eurjchem-597	125	1	for	for	ADP
eurjchem-597	125	2	c21h15cln2o3s	c21h15cln2o3s	NOUN
eurjchem-597	125	3	:	:	PUNCT
eurjchem-597	125	4	c	c	X
eurjchem-597	125	5	,	,	PUNCT
eurjchem-597	125	6	61.39	61.39	NUM
eurjchem-597	125	7	;	;	PUNCT
eurjchem-597	125	8	h	h	NOUN
eurjchem-597	125	9	,	,	PUNCT
eurjchem-597	125	10	3.68	3.68	NUM
eurjchem-597	125	11	;	;	PUNCT
eurjchem-597	125	12	n	n	CCONJ
eurjchem-597	125	13	,	,	PUNCT
eurjchem-597	125	14	6.82	6.82	NUM
eurjchem-597	125	15	;	;	PUNCT
eurjchem-597	125	16	s	s	X
eurjchem-597	125	17	,	,	PUNCT
eurjchem-597	125	18	7.80	7.80	NUM
eurjchem-597	125	19	.	.	PUNCT
eurjchem-597	125	20	found	find	VERB
eurjchem-597	125	21	:	:	PUNCT
eurjchem-597	126	1	c	c	X
eurjchem-597	126	2	,	,	PUNCT
eurjchem-597	126	3	61.35	61.35	NUM
eurjchem-597	126	4	;	;	PUNCT
eurjchem-597	126	5	h	h	X
eurjchem-597	126	6	,	,	PUNCT
eurjchem-597	126	7	3.66	3.66	NUM
eurjchem-597	126	8	;	;	PUNCT
eurjchem-597	126	9	n	n	CCONJ
eurjchem-597	126	10	,	,	PUNCT
eurjchem-597	126	11	6.80	6.80	NUM
eurjchem-597	126	12	;	;	PUNCT
eurjchem-597	126	13	s	s	NOUN
eurjchem-597	126	14	,	,	PUNCT
eurjchem-597	126	15	7.79	7.79	NUM
eurjchem-597	126	16	%	%	NOUN
eurjchem-597	126	17	.	.	PUNCT
eurjchem-597	127	1	2‐(4‐chlorophenyl)‐5‐hydroxy‐4‐phenylthieno[2,3‐d	2‐(4‐chlorophenyl)‐5‐hydroxy‐4‐phenylthieno[2,3‐d	PRON
eurjchem-597	127	2	]	]	X
eurjchem-597	127	3	pyrimidine‐6‐carboxyate	pyrimidine‐6‐carboxyate	X
eurjchem-597	127	4	(	(	PUNCT
eurjchem-597	127	5	8c	8c	NUM
eurjchem-597	127	6	):	):	PUNCT
eurjchem-597	127	7	colorless	colorless	ADJ
eurjchem-597	127	8	crystals	crystal	NOUN
eurjchem-597	127	9	.	.	PUNCT
eurjchem-597	128	1	yield	yield	NOUN
eurjchem-597	128	2	:	:	PUNCT
eurjchem-597	128	3	65	65	NUM
eurjchem-597	128	4	%	%	NOUN
eurjchem-597	128	5	.	.	PUNCT
eurjchem-597	129	1	m.p	m.p	PROPN
eurjchem-597	129	2	.	.	PROPN
eurjchem-597	129	3	:	:	PUNCT
eurjchem-597	130	1	240‐242	240‐242	PROPN
eurjchem-597	130	2	oc	oc	VERB
eurjchem-597	130	3	.	.	PROPN
eurjchem-597	130	4	ir	ir	PROPN
eurjchem-597	130	5	(	(	PUNCT
eurjchem-597	130	6	kbr	kbr	PROPN
eurjchem-597	130	7	,	,	PUNCT
eurjchem-597	130	8	ν	ν	PROPN
eurjchem-597	130	9	,	,	PUNCT
eurjchem-597	130	10	cm‐1	cm‐1	PROPN
eurjchem-597	130	11	):	):	PUNCT
eurjchem-597	130	12	3500‐3100	3500‐3100	NUM
eurjchem-597	130	13	(	(	PUNCT
eurjchem-597	130	14	oh	oh	INTJ
eurjchem-597	130	15	,	,	PUNCT
eurjchem-597	130	16	nh2	nh2	PROPN
eurjchem-597	130	17	)	)	PUNCT
eurjchem-597	130	18	,	,	PUNCT
eurjchem-597	130	19	1665	1665	NUM
eurjchem-597	130	20	(	(	PUNCT
eurjchem-597	130	21	c	c	NOUN
eurjchem-597	130	22	=	=	SYM
eurjchem-597	130	23	o	o	NOUN
eurjchem-597	130	24	,	,	PUNCT
eurjchem-597	130	25	amide	amide	NOUN
eurjchem-597	130	26	)	)	PUNCT
eurjchem-597	130	27	.	.	PUNCT
eurjchem-597	131	1	1h	1h	NUM
eurjchem-597	131	2	nmr	nmr	NOUN
eurjchem-597	131	3	(	(	PUNCT
eurjchem-597	131	4	300	300	NUM
eurjchem-597	131	5	mhz	mhz	NOUN
eurjchem-597	131	6	,	,	PUNCT
eurjchem-597	131	7	dmso‐d6	dmso‐d6	NOUN
eurjchem-597	131	8	,	,	PUNCT
eurjchem-597	131	9			NUM
eurjchem-597	131	10	,	,	PUNCT
eurjchem-597	131	11	ppm	ppm	NUM
eurjchem-597	131	12	):	):	PUNCT
eurjchem-597	131	13	3.42	3.42	NUM
eurjchem-597	131	14	(	(	PUNCT
eurjchem-597	131	15	br	br	PROPN
eurjchem-597	131	16	,	,	PUNCT
eurjchem-597	131	17	2h	2h	NUM
eurjchem-597	131	18	,	,	PUNCT
eurjchem-597	131	19	nh2	nh2	PROPN
eurjchem-597	131	20	)	)	PUNCT
eurjchem-597	131	21	,	,	PUNCT
eurjchem-597	131	22	7.56‐8.12	7.56‐8.12	NUM
eurjchem-597	131	23	(	(	PUNCT
eurjchem-597	131	24	m	m	PROPN
eurjchem-597	131	25	,	,	PUNCT
eurjchem-597	131	26	9h	9h	NUM
eurjchem-597	131	27	,	,	PUNCT
eurjchem-597	131	28	ar‐h	ar‐h	NOUN
eurjchem-597	131	29	)	)	PUNCT
eurjchem-597	131	30	,	,	PUNCT
eurjchem-597	131	31	10.2	10.2	NUM
eurjchem-597	131	32	(	(	PUNCT
eurjchem-597	131	33	s	s	PROPN
eurjchem-597	131	34	,	,	PUNCT
eurjchem-597	131	35	1h	1h	NUM
eurjchem-597	131	36	,	,	PUNCT
eurjchem-597	131	37	oh	oh	INTJ
eurjchem-597	131	38	)	)	PUNCT
eurjchem-597	131	39	.	.	PUNCT
eurjchem-597	132	1	anal	anal	PROPN
eurjchem-597	132	2	.	.	PUNCT
eurjchem-597	132	3	calcd	calcd	NOUN
eurjchem-597	132	4	.	.	PUNCT
eurjchem-597	133	1	for	for	ADP
eurjchem-597	133	2	c19h12cln3o2s	c19h12cln3o2s	NOUN
eurjchem-597	133	3	:	:	PUNCT
eurjchem-597	133	4	c	c	X
eurjchem-597	133	5	,	,	PUNCT
eurjchem-597	133	6	59.76	59.76	NUM
eurjchem-597	133	7	;	;	PUNCT
eurjchem-597	133	8	h	h	NOUN
eurjchem-597	133	9	,	,	PUNCT
eurjchem-597	133	10	3.17	3.17	NUM
eurjchem-597	133	11	;	;	PUNCT
eurjchem-597	133	12	n	n	CCONJ
eurjchem-597	133	13	,	,	PUNCT
eurjchem-597	133	14	11.00	11.00	NUM
eurjchem-597	133	15	;	;	PUNCT
eurjchem-597	133	16	s	s	X
eurjchem-597	133	17	,	,	PUNCT
eurjchem-597	133	18	8.40	8.40	NUM
eurjchem-597	133	19	.	.	PUNCT
eurjchem-597	133	20	found	find	VERB
eurjchem-597	133	21	:	:	PUNCT
eurjchem-597	134	1	c	c	X
eurjchem-597	134	2	,	,	PUNCT
eurjchem-597	134	3	59.74	59.74	NUM
eurjchem-597	134	4	;	;	PUNCT
eurjchem-597	134	5	h	h	NOUN
eurjchem-597	134	6	,	,	PUNCT
eurjchem-597	134	7	3.09	3.09	NUM
eurjchem-597	134	8	;	;	PUNCT
eurjchem-597	134	9	n	n	CCONJ
eurjchem-597	134	10	,	,	PUNCT
eurjchem-597	134	11	11.04	11.04	NUM
eurjchem-597	134	12	;	;	PUNCT
eurjchem-597	134	13	s	s	NOUN
eurjchem-597	134	14	,	,	PUNCT
eurjchem-597	134	15	8.39	8.39	NUM
eurjchem-597	134	16	%	%	NOUN
eurjchem-597	134	17	.	.	PUNCT
eurjchem-597	135	1	(	(	PUNCT
eurjchem-597	135	2	2‐(4‐chlorophenyl)‐5‐hydroxy‐4‐phenylthieno[2,3‐d	2‐(4‐chlorophenyl)‐5‐hydroxy‐4‐phenylthieno[2,3‐d	NOUN
eurjchem-597	135	3	]	]	X
eurjchem-597	135	4	pyrimidine‐6‐yl)(phenyl	pyrimidine‐6‐yl)(phenyl	X
eurjchem-597	135	5	)	)	PUNCT
eurjchem-597	135	6	methanone	methanone	NOUN
eurjchem-597	135	7	(	(	PUNCT
eurjchem-597	135	8	8d	8d	NUM
eurjchem-597	135	9	):	):	PUNCT
eurjchem-597	135	10	pale	pale	ADJ
eurjchem-597	135	11	yellow	yellow	ADJ
eurjchem-597	135	12	crystals	crystal	NOUN
eurjchem-597	135	13	.	.	PUNCT
eurjchem-597	136	1	yield	yield	NOUN
eurjchem-597	136	2	:	:	PUNCT
eurjchem-597	136	3	50	50	NUM
eurjchem-597	136	4	%	%	NOUN
eurjchem-597	136	5	.	.	PUNCT
eurjchem-597	137	1	m.p	m.p	PROPN
eurjchem-597	137	2	.	.	PROPN
eurjchem-597	137	3	:	:	PUNCT
eurjchem-597	138	1	215‐218	215‐218	NUM
eurjchem-597	138	2	oc	oc	PROPN
eurjchem-597	138	3	.	.	PROPN
eurjchem-597	138	4	ir	ir	PROPN
eurjchem-597	138	5	(	(	PUNCT
eurjchem-597	138	6	kbr	kbr	PROPN
eurjchem-597	138	7	,	,	PUNCT
eurjchem-597	138	8	ν	ν	PROPN
eurjchem-597	138	9	,	,	PUNCT
eurjchem-597	138	10	cm‐1	cm‐1	PROPN
eurjchem-597	138	11	):	):	PUNCT
eurjchem-597	138	12	3400	3400	NUM
eurjchem-597	138	13	(	(	PUNCT
eurjchem-597	138	14	oh	oh	INTJ
eurjchem-597	138	15	)	)	PUNCT
eurjchem-597	138	16	,	,	PUNCT
eurjchem-597	138	17	1720	1720	NUM
eurjchem-597	138	18	(	(	PUNCT
eurjchem-597	138	19	c	c	NOUN
eurjchem-597	138	20	=	=	NOUN
eurjchem-597	138	21	o	o	NOUN
eurjchem-597	138	22	)	)	PUNCT
eurjchem-597	138	23	.	.	PUNCT
eurjchem-597	139	1	1h	1h	NUM
eurjchem-597	139	2	nmr	nmr	NOUN
eurjchem-597	139	3	(	(	PUNCT
eurjchem-597	139	4	300	300	NUM
eurjchem-597	139	5	mhz	mhz	NOUN
eurjchem-597	139	6	,	,	PUNCT
eurjchem-597	139	7	dmso‐d6,	dmso‐d6,	X
eurjchem-597	139	8	ppm	ppm	NOUN
eurjchem-597	139	9	):	):	PUNCT
eurjchem-597	139	10	7.21‐8.70	7.21‐8.70	NUM
eurjchem-597	139	11	(	(	PUNCT
eurjchem-597	139	12	m	m	PROPN
eurjchem-597	139	13	,	,	PUNCT
eurjchem-597	139	14	14h	14h	NUM
eurjchem-597	139	15	,	,	PUNCT
eurjchem-597	139	16	ar‐h	ar‐h	NOUN
eurjchem-597	139	17	)	)	PUNCT
eurjchem-597	139	18	,	,	PUNCT
eurjchem-597	139	19	10.2	10.2	NUM
eurjchem-597	139	20	(	(	PUNCT
eurjchem-597	139	21	s	s	PROPN
eurjchem-597	139	22	,	,	PUNCT
eurjchem-597	139	23	1h	1h	NUM
eurjchem-597	139	24	,	,	PUNCT
eurjchem-597	139	25	oh	oh	INTJ
eurjchem-597	139	26	)	)	PUNCT
eurjchem-597	139	27	.	.	PUNCT
eurjchem-597	140	1	anal	anal	PROPN
eurjchem-597	140	2	.	.	PUNCT
eurjchem-597	140	3	calcd	calcd	NOUN
eurjchem-597	140	4	.	.	PUNCT
eurjchem-597	141	1	for	for	ADP
eurjchem-597	141	2	c25h15cln2o2s	c25h15cln2o2s	NOUN
eurjchem-597	141	3	:	:	PUNCT
eurjchem-597	141	4	c	c	X
eurjchem-597	141	5	,	,	PUNCT
eurjchem-597	141	6	67.79	67.79	NUM
eurjchem-597	141	7	;	;	PUNCT
eurjchem-597	141	8	h	h	X
eurjchem-597	141	9	,	,	PUNCT
eurjchem-597	141	10	3.41	3.41	NUM
eurjchem-597	141	11	;	;	PUNCT
eurjchem-597	141	12	n	n	CCONJ
eurjchem-597	141	13	,	,	PUNCT
eurjchem-597	141	14	6.32	6.32	NUM
eurjchem-597	141	15	;	;	PUNCT
eurjchem-597	141	16	s	s	X
eurjchem-597	141	17	,	,	PUNCT
eurjchem-597	141	18	7.24	7.24	NUM
eurjchem-597	141	19	.	.	PUNCT
eurjchem-597	141	20	found	find	VERB
eurjchem-597	141	21	:	:	PUNCT
eurjchem-597	142	1	c	c	X
eurjchem-597	142	2	,	,	PUNCT
eurjchem-597	142	3	67.71	67.71	NUM
eurjchem-597	142	4	;	;	PUNCT
eurjchem-597	142	5	h	h	NOUN
eurjchem-597	142	6	,	,	PUNCT
eurjchem-597	142	7	3.39	3.39	NUM
eurjchem-597	142	8	;	;	PUNCT
eurjchem-597	142	9	n	n	CCONJ
eurjchem-597	142	10	,	,	PUNCT
eurjchem-597	142	11	6.31	6.31	NUM
eurjchem-597	142	12	;	;	PUNCT
eurjchem-597	142	13	s	s	X
eurjchem-597	142	14	,	,	PUNCT
eurjchem-597	142	15	7.22	7.22	NUM
eurjchem-597	142	16	%	%	NOUN
eurjchem-597	142	17	.	.	PUNCT
eurjchem-597	143	1	2.2.6	2.2.6	X
eurjchem-597	143	2	.	.	PUNCT
eurjchem-597	144	1	6‐(4‐chlorophenyl)‐3‐hydroxy‐4‐phenylthieno[2,3‐d	6‐(4‐chlorophenyl)‐3‐hydroxy‐4‐phenylthieno[2,3‐d	NOUN
eurjchem-597	144	2	]	]	PUNCT
eurjchem-597	144	3	pyrimidine	pyrimidine	NOUN
eurjchem-597	144	4	dioxide	dioxide	NOUN
eurjchem-597	144	5	(	(	PUNCT
eurjchem-597	144	6	9	9	NUM
eurjchem-597	144	7	)	)	PUNCT
eurjchem-597	144	8	potassium	potassium	NOUN
eurjchem-597	144	9	permanganate	permanganate	NOUN
eurjchem-597	144	10	(	(	PUNCT
eurjchem-597	144	11	0.01	0.01	NUM
eurjchem-597	144	12	mol	mol	NOUN
eurjchem-597	144	13	)	)	PUNCT
eurjchem-597	144	14	was	be	AUX
eurjchem-597	144	15	added	add	VERB
eurjchem-597	144	16	in	in	ADP
eurjchem-597	144	17	portions	portion	NOUN
eurjchem-597	144	18	to	to	ADP
eurjchem-597	144	19	a	a	DET
eurjchem-597	144	20	solution	solution	NOUN
eurjchem-597	144	21	of	of	ADP
eurjchem-597	144	22	compound	compound	NOUN
eurjchem-597	144	23	7b	7b	NOUN
eurjchem-597	144	24	(	(	PUNCT
eurjchem-597	144	25	0.01	0.01	NUM
eurjchem-597	144	26	mol	mol	NOUN
eurjchem-597	144	27	)	)	PUNCT
eurjchem-597	144	28	in	in	ADP
eurjchem-597	144	29	chloroform	chloroform	NOUN
eurjchem-597	144	30	(	(	PUNCT
eurjchem-597	144	31	20	20	NUM
eurjchem-597	144	32	ml	ml	NOUN
eurjchem-597	144	33	)	)	PUNCT
eurjchem-597	144	34	and	and	CCONJ
eurjchem-597	144	35	concentrated	concentrated	ADJ
eurjchem-597	144	36	h2so4	h2so4	PROPN
eurjchem-597	144	37	(	(	PUNCT
eurjchem-597	144	38	1	1	NUM
eurjchem-597	144	39	ml	ml	NOUN
eurjchem-597	144	40	)	)	PUNCT
eurjchem-597	145	1	[	[	X
eurjchem-597	145	2	10	10	NUM
eurjchem-597	145	3	]	]	PUNCT
eurjchem-597	145	4	.	.	PUNCT
eurjchem-597	146	1	the	the	DET
eurjchem-597	146	2	reaction	reaction	NOUN
eurjchem-597	146	3	mixture	mixture	NOUN
eurjchem-597	146	4	was	be	AUX
eurjchem-597	146	5	left	leave	VERB
eurjchem-597	146	6	at	at	ADP
eurjchem-597	146	7	room	room	NOUN
eurjchem-597	146	8	temperature	temperature	NOUN
eurjchem-597	146	9	overnight	overnight	ADV
eurjchem-597	146	10	,	,	PUNCT
eurjchem-597	146	11	then	then	ADV
eurjchem-597	146	12	ethanol	ethanol	NOUN
eurjchem-597	146	13	(	(	PUNCT
eurjchem-597	146	14	10	10	NUM
eurjchem-597	146	15	ml	ml	NOUN
eurjchem-597	146	16	)	)	PUNCT
eurjchem-597	146	17	was	be	AUX
eurjchem-597	146	18	added	add	VERB
eurjchem-597	146	19	and	and	CCONJ
eurjchem-597	146	20	filtered	filter	VERB
eurjchem-597	146	21	off	off	ADP
eurjchem-597	146	22	.	.	PUNCT
eurjchem-597	147	1	the	the	DET
eurjchem-597	147	2	precipitate	precipitate	NOUN
eurjchem-597	147	3	obtained	obtain	VERB
eurjchem-597	147	4	was	be	AUX
eurjchem-597	147	5	collected	collect	VERB
eurjchem-597	147	6	by	by	ADP
eurjchem-597	147	7	filtration	filtration	NOUN
eurjchem-597	147	8	,	,	PUNCT
eurjchem-597	147	9	dried	dry	VERB
eurjchem-597	147	10	and	and	CCONJ
eurjchem-597	147	11	recrystallized	recrystallize	VERB
eurjchem-597	147	12	from	from	ADP
eurjchem-597	147	13	ethanol	ethanol	NOUN
eurjchem-597	147	14	yield	yield	NOUN
eurjchem-597	147	15	a	a	DET
eurjchem-597	147	16	colorless	colorless	ADJ
eurjchem-597	147	17	crystals	crystal	NOUN
eurjchem-597	147	18	(	(	PUNCT
eurjchem-597	147	19	scheme	scheme	NOUN
eurjchem-597	147	20	2	2	NUM
eurjchem-597	147	21	)	)	PUNCT
eurjchem-597	147	22	.	.	PUNCT
eurjchem-597	148	1	yield	yield	NOUN
eurjchem-597	148	2	:	:	PUNCT
eurjchem-597	148	3	25	25	NUM
eurjchem-597	148	4	%	%	NOUN
eurjchem-597	148	5	.	.	PUNCT
eurjchem-597	149	1	m.p	m.p	PROPN
eurjchem-597	149	2	.	.	PROPN
eurjchem-597	149	3	:	:	PUNCT
eurjchem-597	150	1	120‐122	120‐122	NUM
eurjchem-597	150	2	oc	oc	X
eurjchem-597	150	3	.	.	PUNCT
eurjchem-597	150	4	ir	ir	PROPN
eurjchem-597	150	5	(	(	PUNCT
eurjchem-597	150	6	kbr	kbr	PROPN
eurjchem-597	150	7	,	,	PUNCT
eurjchem-597	150	8	ν	ν	PROPN
eurjchem-597	150	9	,	,	PUNCT
eurjchem-597	150	10	cm‐1	cm‐1	PROPN
eurjchem-597	150	11	):	):	PUNCT
eurjchem-597	150	12	3500	3500	NUM
eurjchem-597	150	13	(	(	PUNCT
eurjchem-597	150	14	oh	oh	INTJ
eurjchem-597	150	15	)	)	PUNCT
eurjchem-597	150	16	.	.	PUNCT
eurjchem-597	151	1	1h	1h	NUM
eurjchem-597	151	2	nmr	nmr	NOUN
eurjchem-597	151	3	(	(	PUNCT
eurjchem-597	151	4	300	300	NUM
eurjchem-597	151	5	mhz	mhz	NOUN
eurjchem-597	151	6	,	,	PUNCT
eurjchem-597	151	7	dmso‐d6	dmso‐d6	NOUN
eurjchem-597	151	8	,	,	PUNCT
eurjchem-597	151	9			NUM
eurjchem-597	151	10	,	,	PUNCT
eurjchem-597	151	11	ppm	ppm	NUM
eurjchem-597	151	12	):	):	PUNCT
eurjchem-597	151	13	7.23	7.23	NUM
eurjchem-597	151	14	(	(	PUNCT
eurjchem-597	151	15	s	s	PROPN
eurjchem-597	151	16	,	,	PUNCT
eurjchem-597	151	17	1h	1h	NUM
eurjchem-597	151	18	,	,	PUNCT
eurjchem-597	151	19	thiophene	thiophene	NOUN
eurjchem-597	151	20	proton	proton	NOUN
eurjchem-597	151	21	)	)	PUNCT
eurjchem-597	151	22	,	,	PUNCT
eurjchem-597	151	23	8.28‐8.70	8.28‐8.70	NUM
eurjchem-597	151	24	(	(	PUNCT
eurjchem-597	151	25	m	m	PROPN
eurjchem-597	151	26	,	,	PUNCT
eurjchem-597	151	27	9h	9h	NUM
eurjchem-597	151	28	,	,	PUNCT
eurjchem-597	151	29	ar‐h	ar‐h	NOUN
eurjchem-597	151	30	)	)	PUNCT
eurjchem-597	151	31	,	,	PUNCT
eurjchem-597	151	32	11.52	11.52	NUM
eurjchem-597	151	33	(	(	PUNCT
eurjchem-597	151	34	br	br	PROPN
eurjchem-597	151	35	,	,	PUNCT
eurjchem-597	151	36	1h	1h	NUM
eurjchem-597	151	37	,	,	PUNCT
eurjchem-597	151	38	oh	oh	INTJ
eurjchem-597	151	39	)	)	PUNCT
eurjchem-597	151	40	.	.	PUNCT
eurjchem-597	152	1	anal	anal	PROPN
eurjchem-597	152	2	.	.	PUNCT
eurjchem-597	152	3	calcd	calcd	NOUN
eurjchem-597	152	4	.	.	PUNCT
eurjchem-597	153	1	for	for	ADP
eurjchem-597	153	2	c18h11cln2o3s	c18h11cln2o3s	NOUN
eurjchem-597	153	3	:	:	PUNCT
eurjchem-597	153	4	c	c	X
eurjchem-597	153	5	,	,	PUNCT
eurjchem-597	153	6	58.30	58.30	NUM
eurjchem-597	153	7	;	;	PUNCT
eurjchem-597	153	8	h	h	NOUN
eurjchem-597	153	9	,	,	PUNCT
eurjchem-597	153	10	2.99	2.99	NUM
eurjchem-597	153	11	;	;	PUNCT
eurjchem-597	153	12	n	n	CCONJ
eurjchem-597	153	13	,	,	PUNCT
eurjchem-597	153	14	7.55	7.55	NUM
eurjchem-597	153	15	;	;	PUNCT
eurjchem-597	153	16	s	s	X
eurjchem-597	153	17	,	,	PUNCT
eurjchem-597	153	18	5.65	5.65	NUM
eurjchem-597	153	19	.	.	PUNCT
eurjchem-597	153	20	found	find	VERB
eurjchem-597	153	21	:	:	PUNCT
eurjchem-597	154	1	c	c	X
eurjchem-597	154	2	,	,	PUNCT
eurjchem-597	154	3	58.29	58.29	NUM
eurjchem-597	154	4	;	;	PUNCT
eurjchem-597	154	5	h	h	NOUN
eurjchem-597	154	6	,	,	PUNCT
eurjchem-597	154	7	2.10	2.10	NUM
eurjchem-597	154	8	;	;	PUNCT
eurjchem-597	154	9	n	n	CCONJ
eurjchem-597	154	10	,	,	PUNCT
eurjchem-597	154	11	7.53	7.53	NUM
eurjchem-597	154	12	;	;	PUNCT
eurjchem-597	154	13	s	s	NOUN
eurjchem-597	154	14	,	,	PUNCT
eurjchem-597	154	15	8.66	8.66	NUM
eurjchem-597	154	16	%	%	NOUN
eurjchem-597	154	17	.	.	PUNCT
eurjchem-597	155	1	244	244	NUM
eurjchem-597	155	2	shehab	shehab	NOUN
eurjchem-597	155	3	and	and	CCONJ
eurjchem-597	155	4	mohamed	mohamed	PROPN
eurjchem-597	155	5	/	/	SYM
eurjchem-597	155	6	european	european	PROPN
eurjchem-597	155	7	journal	journal	PROPN
eurjchem-597	155	8	of	of	ADP
eurjchem-597	155	9	chemistry	chemistry	NOUN
eurjchem-597	155	10	3	3	NUM
eurjchem-597	155	11	(	(	PUNCT
eurjchem-597	155	12	2	2	NUM
eurjchem-597	155	13	)	)	PUNCT
eurjchem-597	155	14	(	(	PUNCT
eurjchem-597	155	15	2012	2012	NUM
eurjchem-597	155	16	)	)	PUNCT
eurjchem-597	155	17	241‐246	241‐246	NUM
eurjchem-597	155	18	scheme	scheme	NOUN
eurjchem-597	155	19	3	3	NUM
eurjchem-597	155	20	2.2.7	2.2.7	NUM
eurjchem-597	155	21	.	.	PUNCT
eurjchem-597	156	1	ethyl	ethyl	PROPN
eurjchem-597	156	2	2‐(4‐chlorophenyl)‐4‐((2‐cyanoethyl)thio)‐6‐	2‐(4‐chlorophenyl)‐4‐((2‐cyanoethyl)thio)‐6‐	NUM
eurjchem-597	156	3	phenylpyrimidine‐5‐carboxylate	phenylpyrimidine‐5‐carboxylate	ADJ
eurjchem-597	156	4	(	(	PUNCT
eurjchem-597	156	5	10	10	NUM
eurjchem-597	156	6	)	)	PUNCT
eurjchem-597	156	7	a	a	DET
eurjchem-597	156	8	mixture	mixture	NOUN
eurjchem-597	156	9	of	of	ADP
eurjchem-597	156	10	compound	compound	NOUN
eurjchem-597	156	11	4	4	NUM
eurjchem-597	156	12	(	(	PUNCT
eurjchem-597	156	13	0.01	0.01	NUM
eurjchem-597	156	14	mol	mol	NOUN
eurjchem-597	156	15	)	)	PUNCT
eurjchem-597	156	16	and	and	CCONJ
eurjchem-597	156	17	acrylonitrile	acrylonitrile	NOUN
eurjchem-597	156	18	(	(	PUNCT
eurjchem-597	156	19	0.01	0.01	NUM
eurjchem-597	156	20	mol	mol	NOUN
eurjchem-597	156	21	)	)	PUNCT
eurjchem-597	156	22	and	and	CCONJ
eurjchem-597	156	23	triethylamine	triethylamine	NOUN
eurjchem-597	156	24	(	(	PUNCT
eurjchem-597	156	25	4	4	NUM
eurjchem-597	156	26	drops	drop	NOUN
eurjchem-597	156	27	)	)	PUNCT
eurjchem-597	156	28	in	in	ADP
eurjchem-597	156	29	ethanol	ethanol	NOUN
eurjchem-597	156	30	(	(	PUNCT
eurjchem-597	156	31	20	20	NUM
eurjchem-597	156	32	ml	ml	NOUN
eurjchem-597	156	33	)	)	PUNCT
eurjchem-597	156	34	was	be	AUX
eurjchem-597	156	35	heated	heat	VERB
eurjchem-597	156	36	under	under	ADP
eurjchem-597	156	37	reflux	reflux	NOUN
eurjchem-597	156	38	for	for	ADP
eurjchem-597	156	39	2	2	NUM
eurjchem-597	156	40	h.	h.	NOUN
eurjchem-597	156	41	after	after	ADP
eurjchem-597	156	42	cooling	cool	VERB
eurjchem-597	156	43	the	the	DET
eurjchem-597	156	44	precipitate	precipitate	NOUN
eurjchem-597	156	45	was	be	AUX
eurjchem-597	156	46	collected	collect	VERB
eurjchem-597	156	47	and	and	CCONJ
eurjchem-597	156	48	crystallized	crystallize	VERB
eurjchem-597	156	49	from	from	ADP
eurjchem-597	156	50	ethanol	ethanol	NOUN
eurjchem-597	156	51	to	to	PART
eurjchem-597	156	52	give	give	VERB
eurjchem-597	156	53	white	white	ADJ
eurjchem-597	156	54	crystal	crystal	NOUN
eurjchem-597	156	55	(	(	PUNCT
eurjchem-597	156	56	scheme	scheme	NOUN
eurjchem-597	156	57	2	2	NUM
eurjchem-597	156	58	)	)	PUNCT
eurjchem-597	156	59	.	.	PUNCT
eurjchem-597	157	1	yield	yield	NOUN
eurjchem-597	157	2	:	:	PUNCT
eurjchem-597	157	3	40	40	NUM
eurjchem-597	157	4	%	%	NOUN
eurjchem-597	157	5	.	.	PUNCT
eurjchem-597	158	1	m.p	m.p	PROPN
eurjchem-597	158	2	.	.	PROPN
eurjchem-597	158	3	:	:	PUNCT
eurjchem-597	159	1	118‐120	118‐120	NUM
eurjchem-597	159	2	oc	oc	PROPN
eurjchem-597	159	3	.	.	PROPN
eurjchem-597	159	4	ir	ir	PROPN
eurjchem-597	159	5	(	(	PUNCT
eurjchem-597	159	6	kbr	kbr	PROPN
eurjchem-597	159	7	,	,	PUNCT
eurjchem-597	159	8	ν	ν	PROPN
eurjchem-597	159	9	,	,	PUNCT
eurjchem-597	159	10	cm‐1	cm‐1	PROPN
eurjchem-597	159	11	):	):	PUNCT
eurjchem-597	159	12	2220	2220	NUM
eurjchem-597	159	13	(	(	PUNCT
eurjchem-597	159	14	cn	cn	PROPN
eurjchem-597	159	15	)	)	PUNCT
eurjchem-597	159	16	,	,	PUNCT
eurjchem-597	159	17	1725	1725	NUM
eurjchem-597	159	18	(	(	PUNCT
eurjchem-597	159	19	c	c	NOUN
eurjchem-597	159	20	=	=	SYM
eurjchem-597	159	21	o	o	NOUN
eurjchem-597	159	22	,	,	PUNCT
eurjchem-597	159	23	ester	ester	NOUN
eurjchem-597	159	24	)	)	PUNCT
eurjchem-597	159	25	.	.	PUNCT
eurjchem-597	160	1	1h	1h	NUM
eurjchem-597	160	2	nmr	nmr	NOUN
eurjchem-597	160	3	(	(	PUNCT
eurjchem-597	160	4	300	300	NUM
eurjchem-597	160	5	mhz	mhz	NOUN
eurjchem-597	160	6	,	,	PUNCT
eurjchem-597	160	7	dmso‐d6	dmso‐d6	NOUN
eurjchem-597	160	8	,	,	PUNCT
eurjchem-597	160	9			NUM
eurjchem-597	160	10	,	,	PUNCT
eurjchem-597	160	11	ppm	ppm	NUM
eurjchem-597	160	12	):	):	PUNCT
eurjchem-597	160	13	1.3	1.3	NUM
eurjchem-597	160	14	(	(	PUNCT
eurjchem-597	160	15	t	t	PROPN
eurjchem-597	160	16	,	,	PUNCT
eurjchem-597	160	17	3h	3h	NUM
eurjchem-597	160	18	,	,	PUNCT
eurjchem-597	160	19	ch3ch2	ch3ch2	PROPN
eurjchem-597	160	20	)	)	PUNCT
eurjchem-597	160	21	,	,	PUNCT
eurjchem-597	160	22	4.2	4.2	NUM
eurjchem-597	160	23	(	(	PUNCT
eurjchem-597	160	24	q	q	NOUN
eurjchem-597	160	25	,	,	PUNCT
eurjchem-597	160	26	2h	2h	NUM
eurjchem-597	160	27	,	,	PUNCT
eurjchem-597	160	28	ch3ch2	ch3ch2	PROPN
eurjchem-597	160	29	)	)	PUNCT
eurjchem-597	160	30	,	,	PUNCT
eurjchem-597	160	31	4.6	4.6	NUM
eurjchem-597	160	32	(	(	PUNCT
eurjchem-597	160	33	m	m	PROPN
eurjchem-597	160	34	,	,	PUNCT
eurjchem-597	160	35	4h	4h	NOUN
eurjchem-597	160	36	,	,	PUNCT
eurjchem-597	160	37	2ch2	2ch2	NUM
eurjchem-597	160	38	)	)	PUNCT
eurjchem-597	160	39	,	,	PUNCT
eurjchem-597	160	40	7.2‐8.2	7.2‐8.2	NOUN
eurjchem-597	160	41	(	(	PUNCT
eurjchem-597	160	42	m	m	PROPN
eurjchem-597	160	43	,	,	PUNCT
eurjchem-597	160	44	9h	9h	NUM
eurjchem-597	160	45	,	,	PUNCT
eurjchem-597	160	46	ar‐h	ar‐h	NOUN
eurjchem-597	160	47	)	)	PUNCT
eurjchem-597	160	48	.	.	PUNCT
eurjchem-597	161	1	anal	anal	PROPN
eurjchem-597	161	2	.	.	PUNCT
eurjchem-597	161	3	calcd	calcd	NOUN
eurjchem-597	161	4	.	.	PUNCT
eurjchem-597	162	1	for	for	ADP
eurjchem-597	162	2	c22h18cln3o2s	c22h18cln3o2s	PROPN
eurjchem-597	162	3	:	:	PUNCT
eurjchem-597	162	4	c	c	X
eurjchem-597	162	5	,	,	PUNCT
eurjchem-597	162	6	62.33	62.33	NUM
eurjchem-597	162	7	;	;	PUNCT
eurjchem-597	162	8	h	h	X
eurjchem-597	162	9	,	,	PUNCT
eurjchem-597	162	10	4.28	4.28	NUM
eurjchem-597	162	11	;	;	PUNCT
eurjchem-597	162	12	n	n	CCONJ
eurjchem-597	162	13	,	,	PUNCT
eurjchem-597	162	14	9.91	9.91	NUM
eurjchem-597	162	15	.	.	PUNCT
eurjchem-597	162	16	found	find	VERB
eurjchem-597	162	17	:	:	PUNCT
eurjchem-597	163	1	c	c	X
eurjchem-597	163	2	,	,	PUNCT
eurjchem-597	163	3	62.40	62.40	NUM
eurjchem-597	163	4	;	;	PUNCT
eurjchem-597	163	5	h	h	X
eurjchem-597	163	6	,	,	PUNCT
eurjchem-597	163	7	4.23	4.23	NUM
eurjchem-597	163	8	;	;	PUNCT
eurjchem-597	163	9	n	n	CCONJ
eurjchem-597	163	10	,	,	PUNCT
eurjchem-597	163	11	9.90	9.90	NUM
eurjchem-597	163	12	.	.	PUNCT
eurjchem-597	164	1	2.2.8	2.2.8	NUM
eurjchem-597	164	2	.	.	PUNCT
eurjchem-597	164	3	6‐(4‐chlorophenyl)‐4‐(cyanomethylthio)‐6‐phenyl	6‐(4‐chlorophenyl)‐4‐(cyanomethylthio)‐6‐phenyl	PROPN
eurjchem-597	164	4	pyrimidine‐5‐carboxylate	pyrimidine‐5‐carboxylate	PROPN
eurjchem-597	164	5	(	(	PUNCT
eurjchem-597	164	6	11	11	NUM
eurjchem-597	164	7	)	)	PUNCT
eurjchem-597	164	8	a	a	DET
eurjchem-597	164	9	mixture	mixture	NOUN
eurjchem-597	164	10	of	of	ADP
eurjchem-597	164	11	compound	compound	NOUN
eurjchem-597	164	12	10	10	NUM
eurjchem-597	164	13	(	(	PUNCT
eurjchem-597	164	14	0.01	0.01	NUM
eurjchem-597	164	15	mol	mol	NOUN
eurjchem-597	164	16	)	)	PUNCT
eurjchem-597	164	17	and	and	CCONJ
eurjchem-597	164	18	hydrazine	hydrazine	NOUN
eurjchem-597	164	19	hydrate	hydrate	NOUN
eurjchem-597	164	20	(	(	PUNCT
eurjchem-597	164	21	0.01	0.01	NUM
eurjchem-597	164	22	mol	mol	NOUN
eurjchem-597	164	23	)	)	PUNCT
eurjchem-597	164	24	in	in	ADP
eurjchem-597	164	25	n‐butanol	n‐butanol	PROPN
eurjchem-597	164	26	(	(	PUNCT
eurjchem-597	164	27	20	20	NUM
eurjchem-597	164	28	ml	ml	NOUN
eurjchem-597	164	29	)	)	PUNCT
eurjchem-597	164	30	was	be	AUX
eurjchem-597	164	31	refluxed	refluxe	VERB
eurjchem-597	164	32	for	for	ADP
eurjchem-597	164	33	2	2	NUM
eurjchem-597	164	34	h.	h.	NOUN
eurjchem-597	164	35	the	the	DET
eurjchem-597	164	36	precipitate	precipitate	NOUN
eurjchem-597	164	37	obtained	obtain	VERB
eurjchem-597	164	38	upon	upon	SCONJ
eurjchem-597	164	39	cooling	cool	VERB
eurjchem-597	164	40	was	be	AUX
eurjchem-597	164	41	collected	collect	VERB
eurjchem-597	164	42	and	and	CCONJ
eurjchem-597	164	43	crystallized	crystallize	VERB
eurjchem-597	164	44	from	from	ADP
eurjchem-597	164	45	butanol	butanol	NOUN
eurjchem-597	164	46	to	to	PART
eurjchem-597	164	47	give	give	VERB
eurjchem-597	164	48	colorless	colorless	ADJ
eurjchem-597	164	49	crystal	crystal	NOUN
eurjchem-597	164	50	(	(	PUNCT
eurjchem-597	164	51	scheme	scheme	NOUN
eurjchem-597	164	52	2	2	NUM
eurjchem-597	164	53	)	)	PUNCT
eurjchem-597	164	54	.	.	PUNCT
eurjchem-597	165	1	yield	yield	NOUN
eurjchem-597	165	2	:	:	PUNCT
eurjchem-597	165	3	60	60	NUM
eurjchem-597	165	4	%	%	NOUN
eurjchem-597	165	5	.	.	PUNCT
eurjchem-597	166	1	m.p	m.p	PROPN
eurjchem-597	166	2	.	.	PROPN
eurjchem-597	166	3	:	:	PUNCT
eurjchem-597	167	1	230‐232	230‐232	NUM
eurjchem-597	167	2	oc	oc	PROPN
eurjchem-597	167	3	.	.	PROPN
eurjchem-597	167	4	1h	1h	NUM
eurjchem-597	167	5	nmr	nmr	NOUN
eurjchem-597	167	6	(	(	PUNCT
eurjchem-597	167	7	300	300	NUM
eurjchem-597	167	8	mhz	mhz	NOUN
eurjchem-597	167	9	,	,	PUNCT
eurjchem-597	167	10	dmso‐d6	dmso‐d6	NOUN
eurjchem-597	167	11	,	,	PUNCT
eurjchem-597	167	12			NUM
eurjchem-597	167	13	,	,	PUNCT
eurjchem-597	167	14	ppm	ppm	NUM
eurjchem-597	167	15	):	):	PUNCT
eurjchem-597	167	16	4.61	4.61	NUM
eurjchem-597	167	17	(	(	PUNCT
eurjchem-597	167	18	br	br	PROPN
eurjchem-597	167	19	,	,	PUNCT
eurjchem-597	167	20	1h	1h	NUM
eurjchem-597	167	21	,	,	PUNCT
eurjchem-597	167	22	nh	nh	PROPN
eurjchem-597	167	23	)	)	PUNCT
eurjchem-597	167	24	,	,	PUNCT
eurjchem-597	167	25	7.2‐8.38	7.2‐8.38	PROPN
eurjchem-597	167	26	(	(	PUNCT
eurjchem-597	167	27	m	m	PROPN
eurjchem-597	167	28	,	,	PUNCT
eurjchem-597	167	29	9h	9h	NUM
eurjchem-597	167	30	,	,	PUNCT
eurjchem-597	167	31	ar‐h	ar‐h	NOUN
eurjchem-597	167	32	)	)	PUNCT
eurjchem-597	167	33	,	,	PUNCT
eurjchem-597	167	34	10.91	10.91	NUM
eurjchem-597	167	35	(	(	PUNCT
eurjchem-597	167	36	br	br	PROPN
eurjchem-597	167	37	,	,	PUNCT
eurjchem-597	167	38	1h	1h	NUM
eurjchem-597	167	39	,	,	PUNCT
eurjchem-597	167	40	oh	oh	INTJ
eurjchem-597	167	41	)	)	PUNCT
eurjchem-597	167	42	.	.	PUNCT
eurjchem-597	168	1	anal	anal	PROPN
eurjchem-597	168	2	.	.	PUNCT
eurjchem-597	168	3	calcd	calcd	NOUN
eurjchem-597	168	4	.	.	PUNCT
eurjchem-597	169	1	for	for	ADP
eurjchem-597	169	2	c17h11cln4o	c17h11cln4o	NOUN
eurjchem-597	169	3	:	:	PUNCT
eurjchem-597	169	4	c	c	NOUN
eurjchem-597	169	5	,	,	PUNCT
eurjchem-597	169	6	63.26	63.26	NUM
eurjchem-597	169	7	;	;	PUNCT
eurjchem-597	169	8	h	h	X
eurjchem-597	169	9	,	,	PUNCT
eurjchem-597	169	10	3.44	3.44	NUM
eurjchem-597	169	11	;	;	PUNCT
eurjchem-597	169	12	n	n	CCONJ
eurjchem-597	169	13	,	,	PUNCT
eurjchem-597	169	14	17.36	17.36	NUM
eurjchem-597	169	15	.	.	PUNCT
eurjchem-597	169	16	found	find	VERB
eurjchem-597	169	17	:	:	PUNCT
eurjchem-597	170	1	c	c	X
eurjchem-597	170	2	,	,	PUNCT
eurjchem-597	170	3	63.24	63.24	NUM
eurjchem-597	170	4	;	;	PUNCT
eurjchem-597	170	5	h	h	NOUN
eurjchem-597	170	6	,	,	PUNCT
eurjchem-597	170	7	3.45	3.45	NUM
eurjchem-597	170	8	;	;	PUNCT
eurjchem-597	170	9	n	n	CCONJ
eurjchem-597	170	10	,	,	PUNCT
eurjchem-597	170	11	17.34	17.34	NUM
eurjchem-597	170	12	%	%	NOUN
eurjchem-597	170	13	.	.	PUNCT
eurjchem-597	171	1	2.2.9	2.2.9	X
eurjchem-597	171	2	.	.	PUNCT
eurjchem-597	171	3	diethyl	diethyl	NOUN
eurjchem-597	171	4	6,6'‐disulfanediyl	6,6'‐disulfanediyl	NUM
eurjchem-597	171	5	bis(2‐(4‐chlorophenyl)‐4‐	bis(2‐(4‐chlorophenyl)‐4‐	NOUN
eurjchem-597	171	6	phenylpyrimidine‐5‐carboxylate	phenylpyrimidine‐5‐carboxylate	NUM
eurjchem-597	171	7	(	(	PUNCT
eurjchem-597	171	8	12	12	NUM
eurjchem-597	171	9	)	)	PUNCT
eurjchem-597	171	10	iodine	iodine	NOUN
eurjchem-597	171	11	(	(	PUNCT
eurjchem-597	171	12	0.01	0.01	NUM
eurjchem-597	171	13	mol	mol	NOUN
eurjchem-597	171	14	)	)	PUNCT
eurjchem-597	171	15	was	be	AUX
eurjchem-597	171	16	added	add	VERB
eurjchem-597	171	17	to	to	ADP
eurjchem-597	171	18	a	a	DET
eurjchem-597	171	19	suspension	suspension	NOUN
eurjchem-597	171	20	solution	solution	NOUN
eurjchem-597	171	21	of	of	ADP
eurjchem-597	171	22	compound	compound	NOUN
eurjchem-597	171	23	4	4	NUM
eurjchem-597	171	24	(	(	PUNCT
eurjchem-597	171	25	0.01	0.01	NUM
eurjchem-597	171	26	mol	mol	NOUN
eurjchem-597	171	27	)	)	PUNCT
eurjchem-597	171	28	in	in	ADP
eurjchem-597	171	29	acetic	acetic	ADJ
eurjchem-597	171	30	acid	acid	NOUN
eurjchem-597	171	31	(	(	PUNCT
eurjchem-597	171	32	20	20	NUM
eurjchem-597	171	33	ml	ml	NOUN
eurjchem-597	171	34	)	)	PUNCT
eurjchem-597	171	35	and	and	CCONJ
eurjchem-597	171	36	stirred	stir	VERB
eurjchem-597	171	37	for	for	ADP
eurjchem-597	171	38	4	4	NUM
eurjchem-597	171	39	h.	h.	NOUN
eurjchem-597	171	40	the	the	DET
eurjchem-597	171	41	white	white	PROPN
eurjchem-597	171	42	solid	solid	ADJ
eurjchem-597	171	43	that	that	PRON
eurjchem-597	171	44	obtained	obtain	VERB
eurjchem-597	171	45	was	be	AUX
eurjchem-597	171	46	filtered	filter	VERB
eurjchem-597	171	47	off	off	ADP
eurjchem-597	171	48	and	and	CCONJ
eurjchem-597	171	49	recrystallized	recrystallize	VERB
eurjchem-597	171	50	from	from	ADP
eurjchem-597	171	51	benzene	benzene	NOUN
eurjchem-597	171	52	afforded	afford	VERB
eurjchem-597	171	53	a	a	DET
eurjchem-597	171	54	colourless	colourless	ADJ
eurjchem-597	171	55	crystals	crystal	NOUN
eurjchem-597	171	56	(	(	PUNCT
eurjchem-597	171	57	scheme	scheme	NOUN
eurjchem-597	171	58	2	2	NUM
eurjchem-597	171	59	)	)	PUNCT
eurjchem-597	171	60	.	.	PUNCT
eurjchem-597	172	1	yield	yield	NOUN
eurjchem-597	172	2	:	:	PUNCT
eurjchem-597	172	3	52	52	NUM
eurjchem-597	172	4	%	%	NOUN
eurjchem-597	172	5	.	.	PUNCT
eurjchem-597	173	1	m.p	m.p	PROPN
eurjchem-597	173	2	.	.	PROPN
eurjchem-597	173	3	:	:	PUNCT
eurjchem-597	174	1	140‐142	140‐142	NUM
eurjchem-597	174	2	oc	oc	PROPN
eurjchem-597	174	3	.	.	PROPN
eurjchem-597	174	4	ir	ir	PROPN
eurjchem-597	174	5	(	(	PUNCT
eurjchem-597	174	6	kbr	kbr	PROPN
eurjchem-597	174	7	,	,	PUNCT
eurjchem-597	174	8	ν	ν	PROPN
eurjchem-597	174	9	,	,	PUNCT
eurjchem-597	174	10	cm‐1	cm‐1	PROPN
eurjchem-597	174	11	):	):	PUNCT
eurjchem-597	174	12	1710	1710	NUM
eurjchem-597	174	13	(	(	PUNCT
eurjchem-597	174	14	c	c	NOUN
eurjchem-597	174	15	=	=	NOUN
eurjchem-597	174	16	o	o	NOUN
eurjchem-597	174	17	)	)	PUNCT
eurjchem-597	174	18	.	.	PUNCT
eurjchem-597	175	1	1h	1h	NUM
eurjchem-597	175	2	nmr	nmr	NOUN
eurjchem-597	175	3	(	(	PUNCT
eurjchem-597	175	4	300	300	NUM
eurjchem-597	175	5	mhz	mhz	NOUN
eurjchem-597	175	6	,	,	PUNCT
eurjchem-597	175	7	dmso‐d6	dmso‐d6	NOUN
eurjchem-597	175	8	,	,	PUNCT
eurjchem-597	175	9			NUM
eurjchem-597	175	10	,	,	PUNCT
eurjchem-597	175	11	ppm	ppm	NUM
eurjchem-597	175	12	):	):	PUNCT
eurjchem-597	175	13	1.4	1.4	NUM
eurjchem-597	175	14	(	(	PUNCT
eurjchem-597	175	15	t	t	PROPN
eurjchem-597	175	16	,	,	PUNCT
eurjchem-597	175	17	6h	6h	NUM
eurjchem-597	175	18	,	,	PUNCT
eurjchem-597	175	19	2ch3ch2	2ch3ch2	NUM
eurjchem-597	175	20	)	)	PUNCT
eurjchem-597	175	21	,	,	PUNCT
eurjchem-597	175	22	4.49	4.49	NUM
eurjchem-597	175	23	(	(	PUNCT
eurjchem-597	175	24	q	q	NOUN
eurjchem-597	175	25	,	,	PUNCT
eurjchem-597	175	26	4h	4h	NUM
eurjchem-597	175	27	,	,	PUNCT
eurjchem-597	175	28	2ch3ch2	2ch3ch2	NUM
eurjchem-597	175	29	)	)	PUNCT
eurjchem-597	175	30	,	,	PUNCT
eurjchem-597	175	31	7.34‐8.05	7.34‐8.05	NUM
eurjchem-597	175	32	(	(	PUNCT
eurjchem-597	175	33	m	m	PROPN
eurjchem-597	175	34	,	,	PUNCT
eurjchem-597	175	35	18h	18h	NUM
eurjchem-597	175	36	,	,	PUNCT
eurjchem-597	175	37	ar‐h	ar‐h	NOUN
eurjchem-597	175	38	)	)	PUNCT
eurjchem-597	175	39	.	.	PUNCT
eurjchem-597	176	1	anal	anal	PROPN
eurjchem-597	176	2	.	.	PUNCT
eurjchem-597	176	3	calcd	calcd	NOUN
eurjchem-597	176	4	.	.	PUNCT
eurjchem-597	177	1	for	for	ADP
eurjchem-597	177	2	c38h28cl2n4o4s2	c38h28cl2n4o4s2	NOUN
eurjchem-597	177	3	:	:	PUNCT
eurjchem-597	177	4	c	c	X
eurjchem-597	177	5	,	,	PUNCT
eurjchem-597	177	6	61.70	61.70	NUM
eurjchem-597	177	7	;	;	PUNCT
eurjchem-597	177	8	h	h	NOUN
eurjchem-597	177	9	,	,	PUNCT
eurjchem-597	177	10	3.82	3.82	NUM
eurjchem-597	177	11	;	;	PUNCT
eurjchem-597	177	12	n	n	CCONJ
eurjchem-597	177	13	,	,	PUNCT
eurjchem-597	177	14	7.57	7.57	NUM
eurjchem-597	177	15	;	;	PUNCT
eurjchem-597	177	16	s	s	X
eurjchem-597	177	17	,	,	PUNCT
eurjchem-597	177	18	8.67	8.67	NUM
eurjchem-597	177	19	.	.	PUNCT
eurjchem-597	177	20	found	find	VERB
eurjchem-597	177	21	:	:	PUNCT
eurjchem-597	178	1	c	c	X
eurjchem-597	178	2	,	,	PUNCT
eurjchem-597	178	3	61.69	61.69	NUM
eurjchem-597	178	4	;	;	PUNCT
eurjchem-597	178	5	h	h	NOUN
eurjchem-597	178	6	,	,	PUNCT
eurjchem-597	178	7	3.84	3.84	NUM
eurjchem-597	178	8	;	;	PUNCT
eurjchem-597	178	9	n	n	CCONJ
eurjchem-597	178	10	,	,	PUNCT
eurjchem-597	178	11	7.56	7.56	NUM
eurjchem-597	178	12	;	;	PUNCT
eurjchem-597	178	13	s	s	NOUN
eurjchem-597	178	14	,	,	PUNCT
eurjchem-597	178	15	8.65	8.65	NUM
eurjchem-597	178	16	%	%	NOUN
eurjchem-597	178	17	.	.	PUNCT
eurjchem-597	179	1	2.2.10	2.2.10	NUM
eurjchem-597	179	2	.	.	PUNCT
eurjchem-597	180	1	2'‐(4‐chlorophenyl)‐4'‐phenyl‐2h,5'h‐spiro[furan‐	2'‐(4‐chlorophenyl)‐4'‐phenyl‐2h,5'h‐spiro[furan‐	NUM
eurjchem-597	180	2	3,6'‐thieno[2,3‐d	3,6'‐thieno[2,3‐d	NOUN
eurjchem-597	180	3	]	]	X
eurjchem-597	180	4	pyrimidine]‐2,5,5'(4h)‐trione	pyrimidine]‐2,5,5'(4h)‐trione	NOUN
eurjchem-597	180	5	(	(	PUNCT
eurjchem-597	180	6	13	13	NUM
eurjchem-597	180	7	)	)	PUNCT
eurjchem-597	180	8	a	a	DET
eurjchem-597	180	9	mixture	mixture	NOUN
eurjchem-597	180	10	of	of	ADP
eurjchem-597	180	11	compound	compound	NOUN
eurjchem-597	180	12	4	4	NUM
eurjchem-597	180	13	(	(	PUNCT
eurjchem-597	180	14	0.01	0.01	NUM
eurjchem-597	180	15	mol	mol	NOUN
eurjchem-597	180	16	)	)	PUNCT
eurjchem-597	180	17	,	,	PUNCT
eurjchem-597	180	18	maleic	maleic	VERB
eurjchem-597	180	19	anhydride	anhydride	NOUN
eurjchem-597	180	20	(	(	PUNCT
eurjchem-597	180	21	0.01	0.01	NUM
eurjchem-597	180	22	mol	mol	NOUN
eurjchem-597	180	23	)	)	PUNCT
eurjchem-597	180	24	and	and	CCONJ
eurjchem-597	180	25	few	few	ADJ
eurjchem-597	180	26	drops	drop	NOUN
eurjchem-597	180	27	of	of	ADP
eurjchem-597	180	28	piperidine	piperidine	NOUN
eurjchem-597	180	29	(	(	PUNCT
eurjchem-597	180	30	pip	pip	NOUN
eurjchem-597	180	31	)	)	PUNCT
eurjchem-597	180	32	in	in	ADP
eurjchem-597	180	33	(	(	PUNCT
eurjchem-597	180	34	20	20	NUM
eurjchem-597	180	35	ml	ml	NOUN
eurjchem-597	180	36	)	)	PUNCT
eurjchem-597	180	37	xylene	xylene	NOUN
eurjchem-597	180	38	was	be	AUX
eurjchem-597	180	39	refluxed	refluxe	VERB
eurjchem-597	180	40	for	for	ADP
eurjchem-597	180	41	16	16	NUM
eurjchem-597	180	42	h.	h.	NOUN
eurjchem-597	180	43	the	the	DET
eurjchem-597	180	44	solid	solid	ADJ
eurjchem-597	180	45	product	product	NOUN
eurjchem-597	180	46	that	that	PRON
eurjchem-597	180	47	obtained	obtain	VERB
eurjchem-597	180	48	after	after	ADP
eurjchem-597	180	49	cooling	cool	VERB
eurjchem-597	180	50	was	be	AUX
eurjchem-597	180	51	collected	collect	VERB
eurjchem-597	180	52	by	by	ADP
eurjchem-597	180	53	filtration	filtration	NOUN
eurjchem-597	180	54	,	,	PUNCT
eurjchem-597	180	55	dried	dry	VERB
eurjchem-597	180	56	and	and	CCONJ
eurjchem-597	180	57	recrystallized	recrystallize	VERB
eurjchem-597	180	58	from	from	ADP
eurjchem-597	180	59	toluene	toluene	NOUN
eurjchem-597	180	60	to	to	PART
eurjchem-597	180	61	afford	afford	VERB
eurjchem-597	180	62	pale	pale	ADJ
eurjchem-597	180	63	gray	gray	ADJ
eurjchem-597	180	64	crystals	crystal	NOUN
eurjchem-597	180	65	(	(	PUNCT
eurjchem-597	180	66	scheme	scheme	NOUN
eurjchem-597	180	67	2	2	NUM
eurjchem-597	180	68	)	)	PUNCT
eurjchem-597	180	69	.	.	PUNCT
eurjchem-597	181	1	yield	yield	NOUN
eurjchem-597	181	2	:	:	PUNCT
eurjchem-597	181	3	35	35	NUM
eurjchem-597	181	4	%	%	NOUN
eurjchem-597	181	5	.	.	PUNCT
eurjchem-597	182	1	m.p	m.p	PROPN
eurjchem-597	182	2	.	.	PROPN
eurjchem-597	182	3	:	:	PUNCT
eurjchem-597	183	1	260‐262	260‐262	NUM
eurjchem-597	183	2	oc	oc	NOUN
eurjchem-597	183	3	.	.	PROPN
eurjchem-597	183	4	ir	ir	PROPN
eurjchem-597	183	5	(	(	PUNCT
eurjchem-597	183	6	kbr	kbr	PROPN
eurjchem-597	183	7	,	,	PUNCT
eurjchem-597	183	8	ν	ν	PROPN
eurjchem-597	183	9	,	,	PUNCT
eurjchem-597	183	10	cm‐1	cm‐1	PROPN
eurjchem-597	183	11	):	):	PUNCT
eurjchem-597	183	12	1810‐1702	1810‐1702	NUM
eurjchem-597	183	13	(	(	PUNCT
eurjchem-597	183	14	br	br	PROPN
eurjchem-597	183	15	)	)	PUNCT
eurjchem-597	183	16	,	,	PUNCT
eurjchem-597	183	17	(	(	PUNCT
eurjchem-597	183	18	2c	2c	NOUN
eurjchem-597	183	19	=	=	SYM
eurjchem-597	183	20	o	o	NOUN
eurjchem-597	183	21	)	)	PUNCT
eurjchem-597	183	22	anhydride	anhydride	NOUN
eurjchem-597	183	23	and	and	CCONJ
eurjchem-597	183	24	(	(	PUNCT
eurjchem-597	183	25	c	c	NOUN
eurjchem-597	183	26	=	=	NOUN
eurjchem-597	183	27	o	o	NOUN
eurjchem-597	183	28	)	)	PUNCT
eurjchem-597	183	29	.	.	PUNCT
eurjchem-597	184	1	1h	1h	NUM
eurjchem-597	184	2	nmr	nmr	NOUN
eurjchem-597	184	3	(	(	PUNCT
eurjchem-597	184	4	300	300	NUM
eurjchem-597	184	5	mhz	mhz	NOUN
eurjchem-597	184	6	,	,	PUNCT
eurjchem-597	184	7	dmso‐d6	dmso‐d6	NOUN
eurjchem-597	184	8	,	,	PUNCT
eurjchem-597	184	9			NUM
eurjchem-597	184	10	,	,	PUNCT
eurjchem-597	184	11	ppm	ppm	NUM
eurjchem-597	184	12	):	):	PUNCT
eurjchem-597	184	13	3.82	3.82	NUM
eurjchem-597	184	14	(	(	PUNCT
eurjchem-597	184	15	s	s	PROPN
eurjchem-597	184	16	,	,	PUNCT
eurjchem-597	184	17	2h	2h	NUM
eurjchem-597	184	18	,	,	PUNCT
eurjchem-597	184	19	ch2	ch2	PROPN
eurjchem-597	184	20	)	)	PUNCT
eurjchem-597	184	21	,	,	PUNCT
eurjchem-597	184	22	7.38‐7.98	7.38‐7.98	NUM
eurjchem-597	184	23	(	(	PUNCT
eurjchem-597	184	24	m	m	PROPN
eurjchem-597	184	25	,	,	PUNCT
eurjchem-597	184	26	9h	9h	NUM
eurjchem-597	184	27	,	,	PUNCT
eurjchem-597	184	28	ar‐h	ar‐h	NOUN
eurjchem-597	184	29	)	)	PUNCT
eurjchem-597	184	30	.	.	PUNCT
eurjchem-597	185	1	anal	anal	PROPN
eurjchem-597	185	2	.	.	PUNCT
eurjchem-597	185	3	calcd	calcd	NOUN
eurjchem-597	185	4	.	.	PUNCT
eurjchem-597	186	1	for	for	ADP
eurjchem-597	186	2	c21h11cln2o4s	c21h11cln2o4s	NOUN
eurjchem-597	186	3	:	:	PUNCT
eurjchem-597	186	4	c	c	X
eurjchem-597	186	5	,	,	PUNCT
eurjchem-597	186	6	59.65	59.65	NUM
eurjchem-597	186	7	;	;	PUNCT
eurjchem-597	186	8	h	h	NOUN
eurjchem-597	186	9	,	,	PUNCT
eurjchem-597	186	10	2.62	2.62	NUM
eurjchem-597	186	11	;	;	PUNCT
eurjchem-597	186	12	n	n	CCONJ
eurjchem-597	186	13	,	,	PUNCT
eurjchem-597	186	14	6.63	6.63	NUM
eurjchem-597	186	15	;	;	PUNCT
eurjchem-597	186	16	s	s	X
eurjchem-597	186	17	,	,	PUNCT
eurjchem-597	186	18	7.58	7.58	NUM
eurjchem-597	186	19	.	.	PUNCT
eurjchem-597	186	20	found	find	VERB
eurjchem-597	186	21	:	:	PUNCT
eurjchem-597	187	1	c	c	X
eurjchem-597	187	2	,	,	PUNCT
eurjchem-597	187	3	59.67	59.67	NUM
eurjchem-597	187	4	;	;	PUNCT
eurjchem-597	188	1	h	h	NOUN
eurjchem-597	188	2	,	,	PUNCT
eurjchem-597	188	3	2.61	2.61	NUM
eurjchem-597	188	4	;	;	PUNCT
eurjchem-597	188	5	n	n	CCONJ
eurjchem-597	188	6	,	,	PUNCT
eurjchem-597	188	7	6.60	6.60	NUM
eurjchem-597	188	8	;	;	PUNCT
eurjchem-597	188	9	s	s	NOUN
eurjchem-597	188	10	,	,	PUNCT
eurjchem-597	188	11	7.56	7.56	NUM
eurjchem-597	188	12	%	%	NOUN
eurjchem-597	188	13	.	.	PUNCT
eurjchem-597	189	1	2.2.11	2.2.11	NUM
eurjchem-597	189	2	.	.	PUNCT
eurjchem-597	189	3	ethyl	ethyl	PROPN
eurjchem-597	189	4	4‐chloro‐2‐(4‐chlorophenyl)‐6‐phenyl	4‐chloro‐2‐(4‐chlorophenyl)‐6‐phenyl	PROPN
eurjchem-597	189	5	pyridimine‐5‐carboxylate	pyridimine‐5‐carboxylate	NOUN
eurjchem-597	189	6	(	(	PUNCT
eurjchem-597	189	7	15	15	NUM
eurjchem-597	189	8	)	)	PUNCT
eurjchem-597	189	9	chlorine	chlorine	NOUN
eurjchem-597	189	10	gas	gas	NOUN
eurjchem-597	189	11	was	be	AUX
eurjchem-597	189	12	bubbled	bubble	VERB
eurjchem-597	189	13	through	through	ADP
eurjchem-597	189	14	a	a	DET
eurjchem-597	189	15	suspension	suspension	NOUN
eurjchem-597	189	16	of	of	ADP
eurjchem-597	189	17	compound	compound	NOUN
eurjchem-597	189	18	4	4	NUM
eurjchem-597	189	19	(	(	PUNCT
eurjchem-597	189	20	0.01	0.01	NUM
eurjchem-597	189	21	mol	mol	NOUN
eurjchem-597	189	22	)	)	PUNCT
eurjchem-597	189	23	in	in	ADP
eurjchem-597	189	24	acetic	acetic	ADJ
eurjchem-597	189	25	acid	acid	NOUN
eurjchem-597	189	26	(	(	PUNCT
eurjchem-597	189	27	20	20	NUM
eurjchem-597	189	28	ml	ml	NOUN
eurjchem-597	189	29	,	,	PUNCT
eurjchem-597	189	30	25	25	NUM
eurjchem-597	189	31	%	%	NOUN
eurjchem-597	189	32	)	)	PUNCT
eurjchem-597	189	33	for	for	ADP
eurjchem-597	189	34	about	about	ADV
eurjchem-597	189	35	4	4	NUM
eurjchem-597	189	36	h	h	NOUN
eurjchem-597	189	37	[	[	X
eurjchem-597	189	38	11	11	NUM
eurjchem-597	189	39	]	]	PUNCT
eurjchem-597	189	40	.	.	PUNCT
eurjchem-597	190	1	the	the	DET
eurjchem-597	190	2	resulting	result	VERB
eurjchem-597	190	3	product	product	NOUN
eurjchem-597	190	4	was	be	AUX
eurjchem-597	190	5	collected	collect	VERB
eurjchem-597	190	6	by	by	ADP
eurjchem-597	190	7	filtration	filtration	NOUN
eurjchem-597	190	8	,	,	PUNCT
eurjchem-597	190	9	washed	wash	VERB
eurjchem-597	190	10	with	with	ADP
eurjchem-597	190	11	water	water	NOUN
eurjchem-597	190	12	,	,	PUNCT
eurjchem-597	190	13	dried	dry	VERB
eurjchem-597	190	14	and	and	CCONJ
eurjchem-597	190	15	recrystallized	recrystallize	VERB
eurjchem-597	190	16	from	from	ADP
eurjchem-597	190	17	benzene	benzene	NOUN
eurjchem-597	190	18	as	as	ADP
eurjchem-597	190	19	a	a	DET
eurjchem-597	190	20	colorless	colorless	ADJ
eurjchem-597	190	21	crystal	crystal	NOUN
eurjchem-597	190	22	(	(	PUNCT
eurjchem-597	190	23	scheme	scheme	NOUN
eurjchem-597	190	24	3	3	NUM
eurjchem-597	190	25	)	)	PUNCT
eurjchem-597	190	26	.	.	PUNCT
eurjchem-597	191	1	yield	yield	NOUN
eurjchem-597	191	2	:	:	PUNCT
eurjchem-597	191	3	75	75	NUM
eurjchem-597	191	4	%	%	NOUN
eurjchem-597	191	5	.	.	PUNCT
eurjchem-597	192	1	m.p	m.p	PROPN
eurjchem-597	192	2	.	.	PROPN
eurjchem-597	192	3	:	:	PUNCT
eurjchem-597	193	1	100‐102	100‐102	NUM
eurjchem-597	193	2	oc	oc	VERB
eurjchem-597	193	3	.	.	PUNCT
eurjchem-597	194	1	ir	ir	PROPN
eurjchem-597	194	2	(	(	PUNCT
eurjchem-597	194	3	kbr	kbr	PROPN
eurjchem-597	194	4	,	,	PUNCT
eurjchem-597	194	5	ν	ν	PROPN
eurjchem-597	194	6	,	,	PUNCT
eurjchem-597	194	7	cm‐1	cm‐1	PROPN
eurjchem-597	194	8	):	):	PUNCT
eurjchem-597	194	9	1725	1725	NUM
eurjchem-597	194	10	(	(	PUNCT
eurjchem-597	194	11	c	c	NOUN
eurjchem-597	194	12	=	=	SYM
eurjchem-597	194	13	o	o	NOUN
eurjchem-597	194	14	,	,	PUNCT
eurjchem-597	194	15	ester	ester	NOUN
eurjchem-597	194	16	)	)	PUNCT
eurjchem-597	194	17	,	,	PUNCT
eurjchem-597	194	18	1620	1620	NUM
eurjchem-597	194	19	(	(	PUNCT
eurjchem-597	194	20	c	c	NOUN
eurjchem-597	194	21	=	=	SYM
eurjchem-597	194	22	n	n	NUM
eurjchem-597	194	23	)	)	PUNCT
eurjchem-597	194	24	.	.	PUNCT
eurjchem-597	195	1	1h	1h	NUM
eurjchem-597	195	2	nmr	nmr	NOUN
eurjchem-597	195	3	(	(	PUNCT
eurjchem-597	195	4	300	300	NUM
eurjchem-597	195	5	mhz	mhz	NOUN
eurjchem-597	195	6	,	,	PUNCT
eurjchem-597	195	7	dmso‐d6	dmso‐d6	NOUN
eurjchem-597	195	8	,	,	PUNCT
eurjchem-597	195	9			NUM
eurjchem-597	195	10	,	,	PUNCT
eurjchem-597	195	11	ppm	ppm	NUM
eurjchem-597	195	12	):	):	PUNCT
eurjchem-597	195	13	1.3	1.3	NUM
eurjchem-597	195	14	(	(	PUNCT
eurjchem-597	195	15	t	t	PROPN
eurjchem-597	195	16	,	,	PUNCT
eurjchem-597	195	17	3h	3h	NUM
eurjchem-597	195	18	,	,	PUNCT
eurjchem-597	195	19	ch3ch2	ch3ch2	PROPN
eurjchem-597	195	20	)	)	PUNCT
eurjchem-597	195	21	,	,	PUNCT
eurjchem-597	195	22	4.40	4.40	NUM
eurjchem-597	195	23	(	(	PUNCT
eurjchem-597	195	24	q	q	NOUN
eurjchem-597	195	25	,	,	PUNCT
eurjchem-597	195	26	2h	2h	NUM
eurjchem-597	195	27	,	,	PUNCT
eurjchem-597	195	28	ch3ch2	ch3ch2	PROPN
eurjchem-597	195	29	)	)	PUNCT
eurjchem-597	195	30	,	,	PUNCT
eurjchem-597	195	31	7.2‐8.0	7.2‐8.0	NUM
eurjchem-597	195	32	(	(	PUNCT
eurjchem-597	195	33	m	m	PROPN
eurjchem-597	195	34	,	,	PUNCT
eurjchem-597	195	35	9h	9h	NUM
eurjchem-597	195	36	,	,	PUNCT
eurjchem-597	195	37	ar‐h	ar‐h	NOUN
eurjchem-597	195	38	)	)	PUNCT
eurjchem-597	195	39	.	.	PUNCT
eurjchem-597	196	1	anal	anal	PROPN
eurjchem-597	196	2	.	.	PUNCT
eurjchem-597	196	3	calcd	calcd	NOUN
eurjchem-597	196	4	.	.	PUNCT
eurjchem-597	197	1	for	for	SCONJ
eurjchem-597	197	2	c19h14cl2n2o2	c19h14cl2n2o2	ADJ
eurjchem-597	197	3	:	:	PUNCT
eurjchem-597	197	4	c	c	X
eurjchem-597	197	5	,	,	PUNCT
eurjchem-597	197	6	61.14	61.14	NUM
eurjchem-597	197	7	;	;	PUNCT
eurjchem-597	197	8	h	h	NOUN
eurjchem-597	197	9	,	,	PUNCT
eurjchem-597	197	10	3.78	3.78	NUM
eurjchem-597	197	11	;	;	PUNCT
eurjchem-597	197	12	n	n	CCONJ
eurjchem-597	197	13	,	,	PUNCT
eurjchem-597	197	14	7.51	7.51	NUM
eurjchem-597	197	15	.	.	PUNCT
eurjchem-597	197	16	found	find	VERB
eurjchem-597	197	17	:	:	PUNCT
eurjchem-597	198	1	c	c	X
eurjchem-597	198	2	,	,	PUNCT
eurjchem-597	198	3	61.10	61.10	NUM
eurjchem-597	198	4	;	;	PUNCT
eurjchem-597	198	5	h	h	NOUN
eurjchem-597	198	6	,	,	PUNCT
eurjchem-597	198	7	3.77	3.77	NUM
eurjchem-597	198	8	;	;	PUNCT
eurjchem-597	198	9	n	n	CCONJ
eurjchem-597	198	10	,	,	PUNCT
eurjchem-597	198	11	7.50	7.50	NUM
eurjchem-597	198	12	%	%	NOUN
eurjchem-597	198	13	.	.	PUNCT
eurjchem-597	199	1	shehab	shehab	PROPN
eurjchem-597	199	2	and	and	CCONJ
eurjchem-597	199	3	mohamed	mohamed	PROPN
eurjchem-597	199	4	/	/	SYM
eurjchem-597	199	5	european	european	PROPN
eurjchem-597	199	6	journal	journal	PROPN
eurjchem-597	199	7	of	of	ADP
eurjchem-597	199	8	chemistry	chemistry	NOUN
eurjchem-597	199	9	3	3	NUM
eurjchem-597	199	10	(	(	PUNCT
eurjchem-597	199	11	2	2	NUM
eurjchem-597	199	12	)	)	PUNCT
eurjchem-597	199	13	(	(	PUNCT
eurjchem-597	199	14	2012	2012	NUM
eurjchem-597	199	15	)	)	PUNCT
eurjchem-597	199	16	241‐246	241‐246	NUM
eurjchem-597	199	17	245	245	NUM
eurjchem-597	199	18	scheme	scheme	NOUN
eurjchem-597	199	19	4	4	NUM
eurjchem-597	199	20	2.2.12	2.2.12	NUM
eurjchem-597	199	21	.	.	PUNCT
eurjchem-597	200	1	7‐(4‐chlorophenyl)‐2‐mercapto‐5‐phenylpyrimido	7‐(4‐chlorophenyl)‐2‐mercapto‐5‐phenylpyrimido	NUM
eurjchem-597	201	1	[	[	X
eurjchem-597	201	2	4,5‐d	4,5‐d	NOUN
eurjchem-597	201	3	]	]	X
eurjchem-597	201	4	pyrimidin‐4	pyrimidin‐4	PROPN
eurjchem-597	201	5	(	(	PUNCT
eurjchem-597	201	6	3h)‐one	3h)‐one	NOUN
eurjchem-597	201	7	(	(	PUNCT
eurjchem-597	201	8	16	16	NUM
eurjchem-597	201	9	)	)	PUNCT
eurjchem-597	201	10	a	a	DET
eurjchem-597	201	11	mixture	mixture	NOUN
eurjchem-597	201	12	of	of	ADP
eurjchem-597	201	13	compound	compound	NOUN
eurjchem-597	201	14	15	15	NUM
eurjchem-597	201	15	(	(	PUNCT
eurjchem-597	201	16	0.01	0.01	NUM
eurjchem-597	201	17	mol	mol	NOUN
eurjchem-597	201	18	)	)	PUNCT
eurjchem-597	201	19	and	and	CCONJ
eurjchem-597	201	20	thiourea	thiourea	NOUN
eurjchem-597	201	21	(	(	PUNCT
eurjchem-597	201	22	0.01	0.01	NUM
eurjchem-597	201	23	mol	mol	NOUN
eurjchem-597	201	24	)	)	PUNCT
eurjchem-597	201	25	in	in	ADP
eurjchem-597	201	26	ethanol	ethanol	NOUN
eurjchem-597	201	27	(	(	PUNCT
eurjchem-597	201	28	30	30	NUM
eurjchem-597	201	29	ml	ml	NOUN
eurjchem-597	201	30	)	)	PUNCT
eurjchem-597	201	31	in	in	ADP
eurjchem-597	201	32	the	the	DET
eurjchem-597	201	33	presence	presence	NOUN
eurjchem-597	201	34	of	of	ADP
eurjchem-597	201	35	triethylamine	triethylamine	NOUN
eurjchem-597	201	36	(	(	PUNCT
eurjchem-597	201	37	3	3	NUM
eurjchem-597	201	38	drops	drop	NOUN
eurjchem-597	201	39	)	)	PUNCT
eurjchem-597	201	40	was	be	AUX
eurjchem-597	201	41	refluxed	refluxe	VERB
eurjchem-597	201	42	for	for	ADP
eurjchem-597	201	43	3	3	NUM
eurjchem-597	201	44	h.	h.	NOUN
eurjchem-597	201	45	the	the	DET
eurjchem-597	201	46	solid	solid	ADJ
eurjchem-597	201	47	that	that	PRON
eurjchem-597	201	48	separated	separate	VERB
eurjchem-597	201	49	after	after	ADP
eurjchem-597	201	50	cooling	cool	VERB
eurjchem-597	201	51	and	and	CCONJ
eurjchem-597	201	52	pouring	pour	VERB
eurjchem-597	201	53	into	into	ADP
eurjchem-597	201	54	water	water	NOUN
eurjchem-597	201	55	was	be	AUX
eurjchem-597	201	56	collected	collect	VERB
eurjchem-597	201	57	by	by	ADP
eurjchem-597	201	58	filtration	filtration	NOUN
eurjchem-597	201	59	and	and	CCONJ
eurjchem-597	201	60	recrystallized	recrystallize	VERB
eurjchem-597	201	61	from	from	ADP
eurjchem-597	201	62	ethanol	ethanol	NOUN
eurjchem-597	201	63	to	to	PART
eurjchem-597	201	64	give	give	VERB
eurjchem-597	201	65	brown	brown	ADJ
eurjchem-597	201	66	crystals	crystal	NOUN
eurjchem-597	201	67	(	(	PUNCT
eurjchem-597	201	68	scheme	scheme	NOUN
eurjchem-597	201	69	3	3	NUM
eurjchem-597	201	70	)	)	PUNCT
eurjchem-597	201	71	.	.	PUNCT
eurjchem-597	202	1	yield	yield	NOUN
eurjchem-597	202	2	:	:	PUNCT
eurjchem-597	202	3	65	65	NUM
eurjchem-597	202	4	%	%	NOUN
eurjchem-597	202	5	.	.	PUNCT
eurjchem-597	203	1	m.p	m.p	PROPN
eurjchem-597	203	2	.	.	PROPN
eurjchem-597	203	3	:	:	PUNCT
eurjchem-597	204	1	220‐222	220‐222	NUM
eurjchem-597	204	2	oc	oc	PROPN
eurjchem-597	204	3	.	.	PROPN
eurjchem-597	204	4	ir	ir	PROPN
eurjchem-597	204	5	(	(	PUNCT
eurjchem-597	204	6	kbr	kbr	PROPN
eurjchem-597	204	7	,	,	PUNCT
eurjchem-597	204	8	ν	ν	PROPN
eurjchem-597	204	9	,	,	PUNCT
eurjchem-597	204	10	cm‐1	cm‐1	PROPN
eurjchem-597	204	11	):	):	PUNCT
eurjchem-597	204	12	3440	3440	NUM
eurjchem-597	204	13	(	(	PUNCT
eurjchem-597	204	14	nh	nh	NOUN
eurjchem-597	204	15	)	)	PUNCT
eurjchem-597	204	16	,	,	PUNCT
eurjchem-597	204	17	1665	1665	NUM
eurjchem-597	204	18	(	(	PUNCT
eurjchem-597	204	19	c	c	NOUN
eurjchem-597	204	20	=	=	NOUN
eurjchem-597	204	21	o	o	NOUN
eurjchem-597	204	22	)	)	PUNCT
eurjchem-597	204	23	,	,	PUNCT
eurjchem-597	204	24	1080	1080	NUM
eurjchem-597	204	25	(	(	PUNCT
eurjchem-597	204	26	sh	sh	PROPN
eurjchem-597	204	27	)	)	PUNCT
eurjchem-597	204	28	.	.	PUNCT
eurjchem-597	205	1	1h	1h	NUM
eurjchem-597	205	2	nmr	nmr	NOUN
eurjchem-597	205	3	(	(	PUNCT
eurjchem-597	205	4	300	300	NUM
eurjchem-597	205	5	mhz	mhz	NOUN
eurjchem-597	205	6	,	,	PUNCT
eurjchem-597	205	7	dmso‐d6	dmso‐d6	NOUN
eurjchem-597	205	8	,	,	PUNCT
eurjchem-597	205	9			NUM
eurjchem-597	205	10	,	,	PUNCT
eurjchem-597	205	11	ppm	ppm	NUM
eurjchem-597	205	12	):	):	PUNCT
eurjchem-597	205	13	7.20‐	7.20‐	NUM
eurjchem-597	205	14	8.98	8.98	NUM
eurjchem-597	205	15	(	(	PUNCT
eurjchem-597	205	16	m	m	PROPN
eurjchem-597	205	17	,	,	PUNCT
eurjchem-597	205	18	10h	10h	NUM
eurjchem-597	205	19	,	,	PUNCT
eurjchem-597	205	20	ar‐h	ar‐h	PROPN
eurjchem-597	205	21	+	+	NUM
eurjchem-597	205	22	nh	nh	PROPN
eurjchem-597	205	23	proton	proton	NOUN
eurjchem-597	205	24	)	)	PUNCT
eurjchem-597	205	25	,	,	PUNCT
eurjchem-597	205	26	12.2	12.2	NUM
eurjchem-597	205	27	(	(	PUNCT
eurjchem-597	205	28	s	s	PROPN
eurjchem-597	205	29	,	,	PUNCT
eurjchem-597	205	30	1h	1h	NUM
eurjchem-597	205	31	,	,	PUNCT
eurjchem-597	205	32	sh	sh	PROPN
eurjchem-597	205	33	)	)	PUNCT
eurjchem-597	205	34	.	.	PUNCT
eurjchem-597	206	1	anal	anal	PROPN
eurjchem-597	206	2	.	.	PUNCT
eurjchem-597	206	3	calcd	calcd	NOUN
eurjchem-597	206	4	.	.	PUNCT
eurjchem-597	207	1	for	for	ADP
eurjchem-597	207	2	c18h11cln4os	c18h11cln4o	NOUN
eurjchem-597	207	3	:	:	PUNCT
eurjchem-597	207	4	c	c	X
eurjchem-597	207	5	,	,	PUNCT
eurjchem-597	207	6	58.94	58.94	NUM
eurjchem-597	207	7	;	;	PUNCT
eurjchem-597	207	8	h	h	NOUN
eurjchem-597	207	9	,	,	PUNCT
eurjchem-597	207	10	3.02	3.02	NUM
eurjchem-597	207	11	;	;	PUNCT
eurjchem-597	207	12	n	n	CCONJ
eurjchem-597	207	13	,	,	PUNCT
eurjchem-597	207	14	15.27	15.27	NUM
eurjchem-597	207	15	;	;	PUNCT
eurjchem-597	207	16	s	s	PROPN
eurjchem-597	207	17	,	,	PUNCT
eurjchem-597	207	18	8.74	8.74	NUM
eurjchem-597	207	19	.	.	PUNCT
eurjchem-597	207	20	found	find	VERB
eurjchem-597	207	21	:	:	PUNCT
eurjchem-597	208	1	c	c	X
eurjchem-597	208	2	,	,	PUNCT
eurjchem-597	208	3	58.90	58.90	NUM
eurjchem-597	208	4	;	;	PUNCT
eurjchem-597	208	5	h	h	NOUN
eurjchem-597	208	6	,	,	PUNCT
eurjchem-597	208	7	3.00	3.00	NUM
eurjchem-597	208	8	;	;	PUNCT
eurjchem-597	208	9	n	n	CCONJ
eurjchem-597	208	10	,	,	PUNCT
eurjchem-597	208	11	15.29	15.29	NUM
eurjchem-597	208	12	;	;	PUNCT
eurjchem-597	208	13	s	s	X
eurjchem-597	208	14	,	,	PUNCT
eurjchem-597	208	15	8.70	8.70	NUM
eurjchem-597	208	16	.	.	PUNCT
eurjchem-597	208	17	2.2.13	2.2.13	NUM
eurjchem-597	208	18	.	.	PUNCT
eurjchem-597	209	1	7‐(4‐chlorophenyl)‐3,4,5‐triphenylpyrimido[4,5‐c	7‐(4‐chlorophenyl)‐3,4,5‐triphenylpyrimido[4,5‐c	NUM
eurjchem-597	209	2	]	]	X
eurjchem-597	209	3	pyridazine	pyridazine	NOUN
eurjchem-597	209	4	(	(	PUNCT
eurjchem-597	209	5	18	18	NUM
eurjchem-597	209	6	)	)	PUNCT
eurjchem-597	209	7	a	a	DET
eurjchem-597	209	8	mixture	mixture	NOUN
eurjchem-597	209	9	of	of	ADP
eurjchem-597	209	10	compound	compound	NOUN
eurjchem-597	209	11	15	15	NUM
eurjchem-597	209	12	(	(	PUNCT
eurjchem-597	209	13	0.01	0.01	NUM
eurjchem-597	209	14	mol	mol	NOUN
eurjchem-597	209	15	)	)	PUNCT
eurjchem-597	209	16	and	and	CCONJ
eurjchem-597	209	17	benzilmonohydrazone	benzilmonohydrazone	NOUN
eurjchem-597	209	18	(	(	PUNCT
eurjchem-597	209	19	0.01	0.01	NUM
eurjchem-597	209	20	mol	mol	NOUN
eurjchem-597	209	21	)	)	PUNCT
eurjchem-597	209	22	in	in	ADP
eurjchem-597	209	23	ethanol	ethanol	NOUN
eurjchem-597	209	24	(	(	PUNCT
eurjchem-597	209	25	30	30	NUM
eurjchem-597	209	26	ml	ml	NOUN
eurjchem-597	209	27	)	)	PUNCT
eurjchem-597	209	28	in	in	ADP
eurjchem-597	209	29	presence	presence	NOUN
eurjchem-597	209	30	of	of	ADP
eurjchem-597	209	31	tea	tea	NOUN
eurjchem-597	209	32	(	(	PUNCT
eurjchem-597	209	33	3	3	NUM
eurjchem-597	209	34	drops	drop	NOUN
eurjchem-597	209	35	)	)	PUNCT
eurjchem-597	209	36	was	be	AUX
eurjchem-597	209	37	refluxed	refluxe	VERB
eurjchem-597	209	38	for	for	ADP
eurjchem-597	209	39	2	2	NUM
eurjchem-597	209	40	h.	h.	NOUN
eurjchem-597	209	41	the	the	DET
eurjchem-597	209	42	solid	solid	ADJ
eurjchem-597	209	43	that	that	PRON
eurjchem-597	209	44	separated	separate	VERB
eurjchem-597	209	45	after	after	ADP
eurjchem-597	209	46	cooling	cool	VERB
eurjchem-597	209	47	and	and	CCONJ
eurjchem-597	209	48	pouring	pour	VERB
eurjchem-597	209	49	into	into	ADP
eurjchem-597	209	50	water	water	NOUN
eurjchem-597	209	51	was	be	AUX
eurjchem-597	209	52	collected	collect	VERB
eurjchem-597	209	53	by	by	ADP
eurjchem-597	209	54	filtration	filtration	NOUN
eurjchem-597	209	55	and	and	CCONJ
eurjchem-597	209	56	crystallized	crystallize	VERB
eurjchem-597	209	57	from	from	ADP
eurjchem-597	209	58	ethanol	ethanol	NOUN
eurjchem-597	209	59	to	to	PART
eurjchem-597	209	60	give	give	VERB
eurjchem-597	209	61	yellow	yellow	ADJ
eurjchem-597	209	62	crystals	crystal	NOUN
eurjchem-597	209	63	(	(	PUNCT
eurjchem-597	209	64	scheme	scheme	NOUN
eurjchem-597	209	65	3	3	NUM
eurjchem-597	209	66	)	)	PUNCT
eurjchem-597	209	67	.	.	PUNCT
eurjchem-597	210	1	yield	yield	NOUN
eurjchem-597	210	2	:	:	PUNCT
eurjchem-597	210	3	60	60	NUM
eurjchem-597	210	4	%	%	NOUN
eurjchem-597	210	5	.	.	PUNCT
eurjchem-597	211	1	m.p	m.p	PROPN
eurjchem-597	211	2	.	.	PROPN
eurjchem-597	211	3	:	:	PUNCT
eurjchem-597	212	1	200‐202	200‐202	PROPN
eurjchem-597	212	2	oc	oc	PROPN
eurjchem-597	212	3	.	.	PROPN
eurjchem-597	212	4	1h	1h	NUM
eurjchem-597	212	5	nmr	nmr	NOUN
eurjchem-597	212	6	(	(	PUNCT
eurjchem-597	212	7	300	300	NUM
eurjchem-597	212	8	mhz	mhz	NOUN
eurjchem-597	212	9	,	,	PUNCT
eurjchem-597	212	10	dmso‐d6	dmso‐d6	NOUN
eurjchem-597	212	11	,	,	PUNCT
eurjchem-597	212	12			NUM
eurjchem-597	212	13	,	,	PUNCT
eurjchem-597	212	14	ppm	ppm	ADJ
eurjchem-597	212	15	):	):	PUNCT
eurjchem-597	212	16	7.21‐8.41	7.21‐8.41	NUM
eurjchem-597	212	17	(	(	PUNCT
eurjchem-597	212	18	m	m	PROPN
eurjchem-597	212	19	,	,	PUNCT
eurjchem-597	212	20	19h	19h	X
eurjchem-597	212	21	,	,	PUNCT
eurjchem-597	212	22	ar‐h	ar‐h	PROPN
eurjchem-597	212	23	)	)	PUNCT
eurjchem-597	212	24	.	.	PUNCT
eurjchem-597	213	1	anal	anal	PROPN
eurjchem-597	213	2	.	.	PUNCT
eurjchem-597	213	3	calcd	calcd	NOUN
eurjchem-597	213	4	.	.	PUNCT
eurjchem-597	214	1	for	for	SCONJ
eurjchem-597	214	2	c30h19cln4	c30h19cln4	PROPN
eurjchem-597	214	3	:	:	PUNCT
eurjchem-597	214	4	c	c	X
eurjchem-597	214	5	,	,	PUNCT
eurjchem-597	214	6	76.51	76.51	NUM
eurjchem-597	214	7	;	;	PUNCT
eurjchem-597	214	8	h	h	X
eurjchem-597	214	9	,	,	PUNCT
eurjchem-597	214	10	4.07	4.07	NUM
eurjchem-597	214	11	;	;	PUNCT
eurjchem-597	214	12	n	n	CCONJ
eurjchem-597	214	13	,	,	PUNCT
eurjchem-597	214	14	11.90	11.90	NUM
eurjchem-597	214	15	.	.	PUNCT
eurjchem-597	214	16	found	find	VERB
eurjchem-597	214	17	:	:	PUNCT
eurjchem-597	214	18	c	c	X
eurjchem-597	214	19	,	,	PUNCT
eurjchem-597	214	20	76.50	76.50	NUM
eurjchem-597	214	21	;	;	PUNCT
eurjchem-597	214	22	h	h	NOUN
eurjchem-597	214	23	,	,	PUNCT
eurjchem-597	214	24	4.02	4.02	NUM
eurjchem-597	214	25	;	;	PUNCT
eurjchem-597	214	26	n	n	CCONJ
eurjchem-597	214	27	,	,	PUNCT
eurjchem-597	214	28	11.89	11.89	NUM
eurjchem-597	214	29	%	%	NOUN
eurjchem-597	214	30	.	.	PUNCT
eurjchem-597	215	1	2.2.14	2.2.14	X
eurjchem-597	215	2	.	.	PUNCT
eurjchem-597	216	1	ethyl	ethyl	PROPN
eurjchem-597	217	1	5‐(4‐chlorophenyl)‐7‐phenyltetrazolo	5‐(4‐chlorophenyl)‐7‐phenyltetrazolo	NUM
eurjchem-597	218	1	[	[	X
eurjchem-597	218	2	1,5‐c	1,5‐c	X
eurjchem-597	218	3	]	]	X
eurjchem-597	219	1	pyrimidine‐8‐carboxylate	pyrimidine‐8‐carboxylate	NUM
eurjchem-597	219	2	(	(	PUNCT
eurjchem-597	219	3	20	20	NUM
eurjchem-597	219	4	)	)	PUNCT
eurjchem-597	219	5	a	a	DET
eurjchem-597	219	6	mixture	mixture	NOUN
eurjchem-597	219	7	of	of	ADP
eurjchem-597	219	8	compound	compound	NOUN
eurjchem-597	219	9	15	15	NUM
eurjchem-597	219	10	(	(	PUNCT
eurjchem-597	219	11	0.01	0.01	NUM
eurjchem-597	219	12	mol	mol	NOUN
eurjchem-597	219	13	)	)	PUNCT
eurjchem-597	219	14	and	and	CCONJ
eurjchem-597	219	15	sodium	sodium	NOUN
eurjchem-597	219	16	azide	azide	NOUN
eurjchem-597	219	17	(	(	PUNCT
eurjchem-597	219	18	0.01	0.01	NUM
eurjchem-597	219	19	mol	mol	NOUN
eurjchem-597	219	20	)	)	PUNCT
eurjchem-597	219	21	in	in	ADP
eurjchem-597	219	22	ethanol	ethanol	NOUN
eurjchem-597	219	23	(	(	PUNCT
eurjchem-597	219	24	30	30	NUM
eurjchem-597	219	25	ml	ml	NOUN
eurjchem-597	219	26	)	)	PUNCT
eurjchem-597	219	27	was	be	AUX
eurjchem-597	219	28	refluxed	refluxe	VERB
eurjchem-597	219	29	for	for	ADP
eurjchem-597	219	30	4	4	NUM
eurjchem-597	219	31	h.	h.	NOUN
eurjchem-597	219	32	the	the	DET
eurjchem-597	219	33	solid	solid	ADJ
eurjchem-597	219	34	that	that	PRON
eurjchem-597	219	35	separated	separate	VERB
eurjchem-597	219	36	after	after	ADP
eurjchem-597	219	37	cooling	cool	VERB
eurjchem-597	219	38	and	and	CCONJ
eurjchem-597	219	39	pouring	pour	VERB
eurjchem-597	219	40	into	into	ADP
eurjchem-597	219	41	water	water	NOUN
eurjchem-597	219	42	was	be	AUX
eurjchem-597	219	43	collected	collect	VERB
eurjchem-597	219	44	by	by	ADP
eurjchem-597	219	45	filtration	filtration	NOUN
eurjchem-597	219	46	and	and	CCONJ
eurjchem-597	219	47	crystallized	crystallize	VERB
eurjchem-597	219	48	from	from	ADP
eurjchem-597	219	49	ethanol	ethanol	NOUN
eurjchem-597	219	50	to	to	PART
eurjchem-597	219	51	give	give	VERB
eurjchem-597	219	52	yellow	yellow	ADJ
eurjchem-597	219	53	crystals	crystal	NOUN
eurjchem-597	219	54	(	(	PUNCT
eurjchem-597	219	55	scheme	scheme	NOUN
eurjchem-597	219	56	3	3	NUM
eurjchem-597	219	57	)	)	PUNCT
eurjchem-597	219	58	.	.	PUNCT
eurjchem-597	220	1	yield	yield	NOUN
eurjchem-597	220	2	:	:	PUNCT
eurjchem-597	220	3	60	60	NUM
eurjchem-597	220	4	%	%	NOUN
eurjchem-597	220	5	.	.	PUNCT
eurjchem-597	221	1	m.p	m.p	PROPN
eurjchem-597	221	2	.	.	PROPN
eurjchem-597	221	3	:	:	PUNCT
eurjchem-597	222	1	280‐282	280‐282	PROPN
eurjchem-597	222	2	oc	oc	VERB
eurjchem-597	222	3	.	.	PUNCT
eurjchem-597	223	1	ir	ir	PROPN
eurjchem-597	223	2	(	(	PUNCT
eurjchem-597	223	3	kbr	kbr	PROPN
eurjchem-597	223	4	,	,	PUNCT
eurjchem-597	223	5	ν	ν	PROPN
eurjchem-597	223	6	,	,	PUNCT
eurjchem-597	223	7	cm‐1	cm‐1	PROPN
eurjchem-597	223	8	):	):	PUNCT
eurjchem-597	223	9	1690	1690	NUM
eurjchem-597	223	10	(	(	PUNCT
eurjchem-597	223	11	c	c	NOUN
eurjchem-597	223	12	=	=	NOUN
eurjchem-597	223	13	o	o	NOUN
eurjchem-597	223	14	)	)	PUNCT
eurjchem-597	223	15	.	.	PUNCT
eurjchem-597	224	1	1h	1h	NUM
eurjchem-597	224	2	nmr	nmr	NOUN
eurjchem-597	224	3	(	(	PUNCT
eurjchem-597	224	4	300	300	NUM
eurjchem-597	224	5	mhz	mhz	NOUN
eurjchem-597	224	6	,	,	PUNCT
eurjchem-597	224	7	dmso‐d6	dmso‐d6	NOUN
eurjchem-597	224	8	,	,	PUNCT
eurjchem-597	224	9			NUM
eurjchem-597	224	10	,	,	PUNCT
eurjchem-597	224	11	ppm	ppm	NUM
eurjchem-597	224	12	):	):	PUNCT
eurjchem-597	224	13	1.4	1.4	NUM
eurjchem-597	224	14	(	(	PUNCT
eurjchem-597	224	15	t	t	PROPN
eurjchem-597	224	16	,	,	PUNCT
eurjchem-597	224	17	3h	3h	NUM
eurjchem-597	224	18	,	,	PUNCT
eurjchem-597	224	19	ch3ch2	ch3ch2	PROPN
eurjchem-597	224	20	)	)	PUNCT
eurjchem-597	224	21	,	,	PUNCT
eurjchem-597	224	22	4.40	4.40	NUM
eurjchem-597	224	23	(	(	PUNCT
eurjchem-597	224	24	q	q	NOUN
eurjchem-597	224	25	,	,	PUNCT
eurjchem-597	224	26	2h	2h	NUM
eurjchem-597	224	27	,	,	PUNCT
eurjchem-597	224	28	ch3ch2	ch3ch2	NOUN
eurjchem-597	224	29	)	)	PUNCT
eurjchem-597	224	30	,	,	PUNCT
eurjchem-597	224	31	7.10‐8.12	7.10‐8.12	NUM
eurjchem-597	224	32	(	(	PUNCT
eurjchem-597	224	33	m	m	PROPN
eurjchem-597	224	34	,	,	PUNCT
eurjchem-597	224	35	9h	9h	NUM
eurjchem-597	224	36	,	,	PUNCT
eurjchem-597	224	37	ar‐h	ar‐h	NOUN
eurjchem-597	224	38	)	)	PUNCT
eurjchem-597	224	39	.	.	PUNCT
eurjchem-597	225	1	anal	anal	PROPN
eurjchem-597	225	2	.	.	PUNCT
eurjchem-597	225	3	calcd	calcd	NOUN
eurjchem-597	225	4	.	.	PUNCT
eurjchem-597	226	1	for	for	ADP
eurjchem-597	226	2	c19h14cln5o2	c19h14cln5o2	NOUN
eurjchem-597	226	3	:	:	PUNCT
eurjchem-597	226	4	c	c	X
eurjchem-597	226	5	,	,	PUNCT
eurjchem-597	226	6	60.09	60.09	NUM
eurjchem-597	226	7	;	;	PUNCT
eurjchem-597	226	8	h	h	NOUN
eurjchem-597	226	9	,	,	PUNCT
eurjchem-597	226	10	3.72	3.72	NUM
eurjchem-597	226	11	;	;	PUNCT
eurjchem-597	226	12	n	n	CCONJ
eurjchem-597	226	13	,	,	PUNCT
eurjchem-597	226	14	18.44	18.44	NUM
eurjchem-597	226	15	.	.	PUNCT
eurjchem-597	226	16	found	find	VERB
eurjchem-597	226	17	:	:	PUNCT
eurjchem-597	227	1	c	c	X
eurjchem-597	227	2	,	,	PUNCT
eurjchem-597	227	3	60.02	60.02	NUM
eurjchem-597	227	4	;	;	PUNCT
eurjchem-597	227	5	h	h	NOUN
eurjchem-597	227	6	,	,	PUNCT
eurjchem-597	227	7	3.71	3.71	NUM
eurjchem-597	227	8	;	;	PUNCT
eurjchem-597	227	9	n	n	CCONJ
eurjchem-597	227	10	,	,	PUNCT
eurjchem-597	227	11	18.45	18.45	NUM
eurjchem-597	227	12	%	%	NOUN
eurjchem-597	227	13	.	.	PUNCT
eurjchem-597	228	1	2.2.15	2.2.15	X
eurjchem-597	228	2	.	.	PUNCT
eurjchem-597	229	1	6‐(4‐chlorophenyl)‐4‐phenyl‐2‐(1‐phenylvinyl)‐1h‐	6‐(4‐chlorophenyl)‐4‐phenyl‐2‐(1‐phenylvinyl)‐1h‐	NUM
eurjchem-597	229	2	pyrazolo[3,4‐d]pyrimidin‐3	pyrazolo[3,4‐d]pyrimidin‐3	NOUN
eurjchem-597	229	3	(	(	PUNCT
eurjchem-597	229	4	2h)‐one	2h)‐one	NOUN
eurjchem-597	229	5	(	(	PUNCT
eurjchem-597	229	6	21	21	NUM
eurjchem-597	229	7	)	)	PUNCT
eurjchem-597	229	8	a	a	DET
eurjchem-597	229	9	mixture	mixture	NOUN
eurjchem-597	229	10	of	of	ADP
eurjchem-597	229	11	compound	compound	NOUN
eurjchem-597	229	12	15	15	NUM
eurjchem-597	229	13	(	(	PUNCT
eurjchem-597	229	14	0.01	0.01	NUM
eurjchem-597	229	15	mol	mol	NOUN
eurjchem-597	229	16	)	)	PUNCT
eurjchem-597	229	17	and	and	CCONJ
eurjchem-597	229	18	acetophenonehydrazone	acetophenonehydrazone	NOUN
eurjchem-597	229	19	(	(	PUNCT
eurjchem-597	229	20	0.01	0.01	NUM
eurjchem-597	229	21	ml	ml	NOUN
eurjchem-597	229	22	)	)	PUNCT
eurjchem-597	229	23	and	and	CCONJ
eurjchem-597	229	24	a	a	DET
eurjchem-597	229	25	drops	drop	NOUN
eurjchem-597	229	26	of	of	ADP
eurjchem-597	229	27	tea	tea	NOUN
eurjchem-597	229	28	in	in	ADP
eurjchem-597	229	29	ethanol	ethanol	NOUN
eurjchem-597	229	30	(	(	PUNCT
eurjchem-597	229	31	20	20	NUM
eurjchem-597	229	32	ml	ml	NOUN
eurjchem-597	229	33	)	)	PUNCT
eurjchem-597	229	34	was	be	AUX
eurjchem-597	229	35	refluxed	refluxe	VERB
eurjchem-597	229	36	for	for	ADP
eurjchem-597	229	37	6	6	NUM
eurjchem-597	229	38	h.	h.	NOUN
eurjchem-597	229	39	the	the	DET
eurjchem-597	229	40	reaction	reaction	NOUN
eurjchem-597	229	41	mixture	mixture	NOUN
eurjchem-597	229	42	was	be	AUX
eurjchem-597	229	43	cooled	cool	VERB
eurjchem-597	229	44	,	,	PUNCT
eurjchem-597	229	45	neutralized	neutralize	VERB
eurjchem-597	229	46	by	by	ADP
eurjchem-597	229	47	hydrochloric	hydrochloric	ADJ
eurjchem-597	229	48	acid	acid	NOUN
eurjchem-597	229	49	poured	pour	VERB
eurjchem-597	229	50	into	into	ADP
eurjchem-597	229	51	ice	ice	NOUN
eurjchem-597	229	52	water	water	NOUN
eurjchem-597	229	53	,	,	PUNCT
eurjchem-597	229	54	filtered	filter	VERB
eurjchem-597	229	55	off	off	ADP
eurjchem-597	229	56	,	,	PUNCT
eurjchem-597	229	57	dried	dry	VERB
eurjchem-597	229	58	and	and	CCONJ
eurjchem-597	229	59	recrystallized	recrystallize	VERB
eurjchem-597	229	60	from	from	ADP
eurjchem-597	229	61	ethanol	ethanol	NOUN
eurjchem-597	229	62	to	to	PART
eurjchem-597	229	63	give	give	VERB
eurjchem-597	229	64	a	a	DET
eurjchem-597	229	65	yellow	yellow	ADJ
eurjchem-597	229	66	crystal	crystal	NOUN
eurjchem-597	229	67	(	(	PUNCT
eurjchem-597	229	68	scheme	scheme	NOUN
eurjchem-597	229	69	4	4	NUM
eurjchem-597	229	70	)	)	PUNCT
eurjchem-597	229	71	.	.	PUNCT
eurjchem-597	230	1	yield	yield	NOUN
eurjchem-597	230	2	:	:	PUNCT
eurjchem-597	230	3	65	65	NUM
eurjchem-597	230	4	%	%	NOUN
eurjchem-597	230	5	.	.	PUNCT
eurjchem-597	231	1	m.p	m.p	PROPN
eurjchem-597	231	2	.	.	PROPN
eurjchem-597	231	3	:	:	PUNCT
eurjchem-597	232	1	190‐192	190‐192	NUM
eurjchem-597	232	2	oc	oc	PROPN
eurjchem-597	232	3	.	.	PROPN
eurjchem-597	232	4	ir	ir	PROPN
eurjchem-597	232	5	(	(	PUNCT
eurjchem-597	232	6	kbr	kbr	PROPN
eurjchem-597	232	7	,	,	PUNCT
eurjchem-597	232	8	ν	ν	PROPN
eurjchem-597	232	9	,	,	PUNCT
eurjchem-597	232	10	cm‐1	cm‐1	PROPN
eurjchem-597	232	11	):	):	PUNCT
eurjchem-597	232	12	3440	3440	NUM
eurjchem-597	232	13	(	(	PUNCT
eurjchem-597	232	14	nh	nh	NOUN
eurjchem-597	232	15	)	)	PUNCT
eurjchem-597	232	16	,	,	PUNCT
eurjchem-597	232	17	1675	1675	NUM
eurjchem-597	232	18	(	(	PUNCT
eurjchem-597	232	19	c	c	NOUN
eurjchem-597	232	20	=	=	NOUN
eurjchem-597	232	21	o	o	NOUN
eurjchem-597	232	22	)	)	PUNCT
eurjchem-597	232	23	.	.	PUNCT
eurjchem-597	233	1	1h	1h	NUM
eurjchem-597	233	2	nmr	nmr	NOUN
eurjchem-597	233	3	(	(	PUNCT
eurjchem-597	233	4	300	300	NUM
eurjchem-597	233	5	mhz	mhz	NOUN
eurjchem-597	233	6	,	,	PUNCT
eurjchem-597	233	7	dmso‐d6	dmso‐d6	NOUN
eurjchem-597	233	8	,	,	PUNCT
eurjchem-597	233	9			NUM
eurjchem-597	233	10	,	,	PUNCT
eurjchem-597	233	11	ppm	ppm	NUM
eurjchem-597	233	12	):	):	PUNCT
eurjchem-597	233	13	4.0	4.0	NUM
eurjchem-597	233	14	(	(	PUNCT
eurjchem-597	233	15	s	s	PROPN
eurjchem-597	233	16	,	,	PUNCT
eurjchem-597	233	17	h	h	NOUN
eurjchem-597	233	18	,	,	PUNCT
eurjchem-597	233	19	nh	nh	PROPN
eurjchem-597	233	20	)	)	PUNCT
eurjchem-597	233	21	,	,	PUNCT
eurjchem-597	233	22	4.61	4.61	NUM
eurjchem-597	233	23	(	(	PUNCT
eurjchem-597	233	24	s	s	PROPN
eurjchem-597	233	25	,	,	PUNCT
eurjchem-597	233	26	2h	2h	NUM
eurjchem-597	233	27	,	,	PUNCT
eurjchem-597	233	28	=	=	NOUN
eurjchem-597	233	29	ch2	ch2	NOUN
eurjchem-597	233	30	)	)	PUNCT
eurjchem-597	233	31	,	,	PUNCT
eurjchem-597	233	32	7.14‐7.79	7.14‐7.79	NUM
eurjchem-597	233	33	(	(	PUNCT
eurjchem-597	233	34	m	m	PROPN
eurjchem-597	233	35	,	,	PUNCT
eurjchem-597	233	36	14h	14h	NUM
eurjchem-597	233	37	,	,	PUNCT
eurjchem-597	233	38	ar‐h	ar‐h	NOUN
eurjchem-597	233	39	)	)	PUNCT
eurjchem-597	233	40	.	.	PUNCT
eurjchem-597	234	1	anal	anal	PROPN
eurjchem-597	234	2	.	.	PUNCT
eurjchem-597	234	3	calcd	calcd	NOUN
eurjchem-597	234	4	.	.	PUNCT
eurjchem-597	235	1	for	for	SCONJ
eurjchem-597	235	2	c25h17cln4o	c25h17cln4o	NOUN
eurjchem-597	235	3	:	:	PUNCT
eurjchem-597	235	4	c	c	NOUN
eurjchem-597	235	5	,	,	PUNCT
eurjchem-597	235	6	70.67	70.67	NUM
eurjchem-597	235	7	;	;	PUNCT
eurjchem-597	235	8	h	h	NOUN
eurjchem-597	235	9	,	,	PUNCT
eurjchem-597	235	10	4.03	4.03	NUM
eurjchem-597	235	11	;	;	PUNCT
eurjchem-597	235	12	n	n	CCONJ
eurjchem-597	235	13	,	,	PUNCT
eurjchem-597	235	14	13.19	13.19	NUM
eurjchem-597	235	15	.	.	PUNCT
eurjchem-597	235	16	found	find	VERB
eurjchem-597	235	17	:	:	PUNCT
eurjchem-597	236	1	c	c	X
eurjchem-597	236	2	,	,	PUNCT
eurjchem-597	236	3	70.65	70.65	NUM
eurjchem-597	236	4	;	;	PUNCT
eurjchem-597	236	5	h	h	X
eurjchem-597	236	6	,	,	PUNCT
eurjchem-597	236	7	4.01	4.01	NUM
eurjchem-597	236	8	;	;	PUNCT
eurjchem-597	236	9	n	n	CCONJ
eurjchem-597	236	10	,	,	PUNCT
eurjchem-597	236	11	13.15	13.15	NUM
eurjchem-597	236	12	%	%	NOUN
eurjchem-597	236	13	.	.	PUNCT
eurjchem-597	237	1	3	3	X
eurjchem-597	237	2	.	.	NOUN
eurjchem-597	237	3	results	result	NOUN
eurjchem-597	237	4	and	and	CCONJ
eurjchem-597	237	5	discussion	discussion	NOUN
eurjchem-597	237	6	the	the	DET
eurjchem-597	237	7	present	present	ADJ
eurjchem-597	237	8	work	work	NOUN
eurjchem-597	237	9	involves	involve	VERB
eurjchem-597	237	10	the	the	DET
eurjchem-597	237	11	synthesis	synthesis	NOUN
eurjchem-597	237	12	of	of	ADP
eurjchem-597	237	13	some	some	DET
eurjchem-597	237	14	new	new	ADJ
eurjchem-597	237	15	pyrimidine	pyrimidine	NOUN
eurjchem-597	237	16	and	and	CCONJ
eurjchem-597	237	17	condensed	condense	VERB
eurjchem-597	237	18	pyrimidine	pyrimidine	ADJ
eurjchem-597	237	19	derivatives	derivative	NOUN
eurjchem-597	237	20	.	.	PUNCT
eurjchem-597	238	1	ethyl	ethyl	PROPN
eurjchem-597	238	2	2‐(4‐	2‐(4‐	PROPN
eurjchem-597	238	3	chlorophenyl)1‐4‐mercapto‐6‐phenylpyrimidine‐5‐carboxylate	chlorophenyl)1‐4‐mercapto‐6‐phenylpyrimidine‐5‐carboxylate	NOUN
eurjchem-597	238	4	(	(	PUNCT
eurjchem-597	238	5	4	4	NUM
eurjchem-597	238	6	)	)	PUNCT
eurjchem-597	238	7	which	which	PRON
eurjchem-597	238	8	was	be	AUX
eurjchem-597	238	9	readily	readily	ADV
eurjchem-597	238	10	synthesized	synthesize	VERB
eurjchem-597	238	11	by	by	ADP
eurjchem-597	238	12	the	the	DET
eurjchem-597	238	13	interaction	interaction	NOUN
eurjchem-597	238	14	of	of	ADP
eurjchem-597	238	15	isothiocyanate	isothiocyanate	NOUN
eurjchem-597	238	16	(	(	PUNCT
eurjchem-597	238	17	2	2	NUM
eurjchem-597	238	18	)	)	PUNCT
eurjchem-597	238	19	with	with	ADP
eurjchem-597	238	20	unsaturated	unsaturated	ADJ
eurjchem-597	238	21	amino	amino	NOUN
eurjchem-597	238	22	ester	ester	NOUN
eurjchem-597	238	23	(	(	PUNCT
eurjchem-597	238	24	1	1	X
eurjchem-597	238	25	)	)	PUNCT
eurjchem-597	238	26	presumably	presumably	ADV
eurjchem-597	238	27	via	via	ADP
eurjchem-597	238	28	the	the	DET
eurjchem-597	238	29	non‐isolable	non‐isolable	ADJ
eurjchem-597	238	30	acyclic	acyclic	ADJ
eurjchem-597	238	31	compound	compound	NOUN
eurjchem-597	238	32	3	3	NUM
eurjchem-597	238	33	that	that	PRON
eurjchem-597	238	34	undergo	undergo	VERB
eurjchem-597	238	35	intramolecular	intramolecular	ADJ
eurjchem-597	238	36	cyclodehydration	cyclodehydration	NOUN
eurjchem-597	238	37	affording	afford	VERB
eurjchem-597	238	38	the	the	DET
eurjchem-597	238	39	ethyl	ethyl	PROPN
eurjchem-597	238	40	2‐	2‐	NUM
eurjchem-597	238	41	(	(	PUNCT
eurjchem-597	238	42	4‐chlorophenyl)1‐4‐mercapto‐6‐phenylpyrimidine‐5‐	4‐chlorophenyl)1‐4‐mercapto‐6‐phenylpyrimidine‐5‐	NUM
eurjchem-597	238	43	carboxylate	carboxylate	NOUN
eurjchem-597	238	44	(	(	PUNCT
eurjchem-597	238	45	4	4	NUM
eurjchem-597	238	46	)	)	PUNCT
eurjchem-597	238	47	(	(	PUNCT
eurjchem-597	238	48	scheme	scheme	NOUN
eurjchem-597	238	49	1	1	NUM
eurjchem-597	238	50	)	)	PUNCT
eurjchem-597	238	51	.	.	PUNCT
eurjchem-597	239	1	in	in	ADP
eurjchem-597	239	2	an	an	DET
eurjchem-597	239	3	attempt	attempt	NOUN
eurjchem-597	239	4	to	to	PART
eurjchem-597	239	5	prepare	prepare	VERB
eurjchem-597	239	6	nucleoside	nucleoside	NOUN
eurjchem-597	239	7	derivatives	derivative	NOUN
eurjchem-597	239	8	from	from	ADP
eurjchem-597	239	9	the	the	DET
eurjchem-597	239	10	reaction	reaction	NOUN
eurjchem-597	239	11	of	of	ADP
eurjchem-597	239	12	ethyl	ethyl	PROPN
eurjchem-597	239	13	2‐(4‐chlorophenyl)1‐4‐mercapto‐6‐	2‐(4‐chlorophenyl)1‐4‐mercapto‐6‐	NUM
eurjchem-597	239	14	phenylpyrimidine‐5‐carboxylate	phenylpyrimidine‐5‐carboxylate	NUM
eurjchem-597	239	15	(	(	PUNCT
eurjchem-597	239	16	4	4	NUM
eurjchem-597	239	17	)	)	PUNCT
eurjchem-597	239	18	and	and	CCONJ
eurjchem-597	239	19	2,3,4,6‐tetra‐o‐acetyl‐	2,3,4,6‐tetra‐o‐acetyl‐	NUM
eurjchem-597	239	20	α‐d‐glycopyranosyl	α‐d‐glycopyranosyl	PROPN
eurjchem-597	239	21	bromide	bromide	NOUN
eurjchem-597	239	22	in	in	ADP
eurjchem-597	239	23	the	the	DET
eurjchem-597	239	24	presence	presence	NOUN
eurjchem-597	239	25	of	of	ADP
eurjchem-597	239	26	aqueous	aqueous	ADJ
eurjchem-597	239	27	potassium	potassium	NOUN
eurjchem-597	239	28	hydroxide	hydroxide	NOUN
eurjchem-597	239	29	led	lead	VERB
eurjchem-597	239	30	to	to	ADP
eurjchem-597	239	31	the	the	DET
eurjchem-597	239	32	formation	formation	NOUN
eurjchem-597	239	33	of	of	ADP
eurjchem-597	239	34	s‐glycosyl	s‐glycosyl	PUNCT
eurjchem-597	239	35	derivative	derivative	ADJ
eurjchem-597	239	36	5	5	NUM
eurjchem-597	239	37	.	.	PUNCT
eurjchem-597	239	38	the	the	DET
eurjchem-597	239	39	formation	formation	NOUN
eurjchem-597	239	40	of	of	ADP
eurjchem-597	239	41	compound	compound	NOUN
eurjchem-597	239	42	5	5	NUM
eurjchem-597	239	43	is	be	AUX
eurjchem-597	239	44	proved	prove	VERB
eurjchem-597	239	45	by	by	ADP
eurjchem-597	239	46	the	the	DET
eurjchem-597	239	47	disappearance	disappearance	NOUN
eurjchem-597	239	48	of	of	ADP
eurjchem-597	239	49	ν(sh	ν(sh	NOUN
eurjchem-597	239	50	)	)	PUNCT
eurjchem-597	239	51	in	in	ADP
eurjchem-597	239	52	ir	ir	PROPN
eurjchem-597	239	53	spectra	spectra	NOUN
eurjchem-597	239	54	and	and	CCONJ
eurjchem-597	239	55	appearance	appearance	NOUN
eurjchem-597	239	56	of	of	ADP
eurjchem-597	239	57	signals	signal	NOUN
eurjchem-597	239	58	at	at	ADP
eurjchem-597	239	59	δ	δ	PROPN
eurjchem-597	239	60	1.87	1.87	NUM
eurjchem-597	239	61	,	,	PUNCT
eurjchem-597	239	62	1.92	1.92	NUM
eurjchem-597	239	63	,	,	PUNCT
eurjchem-597	239	64	1.95	1.95	NUM
eurjchem-597	239	65	,	,	PUNCT
eurjchem-597	239	66	2.02	2.02	NUM
eurjchem-597	239	67	ppm	ppm	NOUN
eurjchem-597	239	68	due	due	ADP
eurjchem-597	239	69	to	to	ADP
eurjchem-597	239	70	the	the	DET
eurjchem-597	239	71	four	four	NUM
eurjchem-597	239	72	methyl	methyl	NOUN
eurjchem-597	239	73	of	of	ADP
eurjchem-597	239	74	the	the	DET
eurjchem-597	239	75	acetyl	acetyl	NOUN
eurjchem-597	239	76	groups	group	NOUN
eurjchem-597	239	77	.	.	PUNCT
eurjchem-597	240	1	hydrolysis	hydrolysis	NOUN
eurjchem-597	240	2	of	of	ADP
eurjchem-597	240	3	compound	compound	NOUN
eurjchem-597	240	4	5	5	NUM
eurjchem-597	240	5	using	use	VERB
eurjchem-597	240	6	triethylamine	triethylamine	NOUN
eurjchem-597	240	7	in	in	ADP
eurjchem-597	240	8	methanol	methanol	NOUN
eurjchem-597	240	9	afforded	afford	VERB
eurjchem-597	240	10	the	the	DET
eurjchem-597	240	11	deacylated	deacylate	VERB
eurjchem-597	240	12	compound	compound	NOUN
eurjchem-597	240	13	6	6	NUM
eurjchem-597	240	14	which	which	PRON
eurjchem-597	240	15	showed	show	VERB
eurjchem-597	240	16	in	in	ADP
eurjchem-597	240	17	ir	ir	PROPN
eurjchem-597	240	18	spectra	spectra	NOUN
eurjchem-597	240	19	the	the	DET
eurjchem-597	240	20	disappearance	disappearance	NOUN
eurjchem-597	240	21	of	of	ADP
eurjchem-597	240	22	the	the	DET
eurjchem-597	240	23	acetyl	acetyl	NOUN
eurjchem-597	240	24	groups	group	NOUN
eurjchem-597	240	25	and	and	CCONJ
eurjchem-597	240	26	appearance	appearance	NOUN
eurjchem-597	240	27	of	of	ADP
eurjchem-597	240	28	bands	band	NOUN
eurjchem-597	240	29	at	at	ADP
eurjchem-597	240	30	3420‐3395	3420‐3395	NUM
eurjchem-597	240	31	cm‐1	cm‐1	NOUN
eurjchem-597	240	32	for	for	ADP
eurjchem-597	240	33	resulting	result	VERB
eurjchem-597	240	34	of	of	ADP
eurjchem-597	240	35	free	free	ADJ
eurjchem-597	240	36	hydroxyl	hydroxyl	NOUN
eurjchem-597	240	37	groups	group	NOUN
eurjchem-597	240	38	.	.	PUNCT
eurjchem-597	241	1	the	the	DET
eurjchem-597	241	2	synthetic	synthetic	ADJ
eurjchem-597	241	3	strategy	strategy	NOUN
eurjchem-597	241	4	toward	toward	ADP
eurjchem-597	241	5	thienopyrimidine	thienopyrimidine	NOUN
eurjchem-597	241	6	is	be	AUX
eurjchem-597	241	7	based	base	VERB
eurjchem-597	241	8	on	on	ADP
eurjchem-597	241	9	bulding	bulde	VERB
eurjchem-597	241	10	a	a	DET
eurjchem-597	241	11	thiophene	thiophene	NOUN
eurjchem-597	241	12	ring	ring	NOUN
eurjchem-597	241	13	into	into	ADP
eurjchem-597	241	14	a	a	DET
eurjchem-597	241	15	pyrimidine	pyrimidine	NOUN
eurjchem-597	241	16	ring	ring	NOUN
eurjchem-597	241	17	with	with	ADP
eurjchem-597	241	18	two	two	NUM
eurjchem-597	241	19	ortho	ortho	PROPN
eurjchem-597	241	20	substituents	substituent	NOUN
eurjchem-597	241	21	one	one	NUM
eurjchem-597	241	22	electrophilic	electrophilic	NOUN
eurjchem-597	241	23	(	(	PUNCT
eurjchem-597	241	24	c	c	NOUN
eurjchem-597	241	25	=	=	NOUN
eurjchem-597	241	26	o	o	NOUN
eurjchem-597	241	27	)	)	PUNCT
eurjchem-597	241	28	and	and	CCONJ
eurjchem-597	241	29	one	one	NUM
eurjchem-597	241	30	potentially	potentially	ADV
eurjchem-597	241	31	nucleophilic	nucleophilic	ADJ
eurjchem-597	241	32	(	(	PUNCT
eurjchem-597	241	33	sh	sh	PROPN
eurjchem-597	241	34	)	)	PUNCT
eurjchem-597	241	35	by	by	ADP
eurjchem-597	241	36	its	its	PRON
eurjchem-597	241	37	reaction	reaction	NOUN
eurjchem-597	241	38	with	with	ADP
eurjchem-597	241	39	halomethylene	halomethylene	NOUN
eurjchem-597	241	40	to	to	PART
eurjchem-597	241	41	form	form	VERB
eurjchem-597	241	42	a	a	DET
eurjchem-597	241	43	thiophene	thiophene	NOUN
eurjchem-597	241	44	ring	ring	NOUN
eurjchem-597	241	45	with	with	ADP
eurjchem-597	241	46	appropriate	appropriate	ADJ
eurjchem-597	241	47	functionalities	functionality	NOUN
eurjchem-597	241	48	.	.	PUNCT
eurjchem-597	242	1	this	this	DET
eurjchem-597	242	2	result	result	NOUN
eurjchem-597	242	3	is	be	AUX
eurjchem-597	242	4	usually	usually	ADV
eurjchem-597	242	5	achieved	achieve	VERB
eurjchem-597	242	6	in	in	ADP
eurjchem-597	242	7	one	one	NUM
eurjchem-597	242	8	operation	operation	NOUN
eurjchem-597	242	9	by	by	ADP
eurjchem-597	242	10	a	a	DET
eurjchem-597	242	11	series	series	NOUN
eurjchem-597	242	12	of	of	ADP
eurjchem-597	242	13	constitutive	constitutive	ADJ
eurjchem-597	242	14	reactions	reaction	NOUN
eurjchem-597	242	15	,	,	PUNCT
eurjchem-597	242	16	alkylation	alkylation	NOUN
eurjchem-597	242	17	followed	follow	VERB
eurjchem-597	242	18	by	by	ADP
eurjchem-597	242	19	ring	re	VERB
eurjchem-597	242	20	closure	closure	NOUN
eurjchem-597	242	21	at	at	ADP
eurjchem-597	242	22	the	the	DET
eurjchem-597	242	23	electrophilic	electrophilic	ADJ
eurjchem-597	242	24	center	center	NOUN
eurjchem-597	242	25	and	and	CCONJ
eurjchem-597	242	26	subsequent	subsequent	ADJ
eurjchem-597	242	27	aromatization	aromatization	NOUN
eurjchem-597	242	28	(	(	PUNCT
eurjchem-597	242	29	8a‐d	8a‐d	ADV
eurjchem-597	242	30	)	)	PUNCT
eurjchem-597	242	31	.	.	PUNCT
eurjchem-597	243	1	thus	thus	ADV
eurjchem-597	243	2	,	,	PUNCT
eurjchem-597	243	3	when	when	SCONJ
eurjchem-597	243	4	ethyl	ethyl	PROPN
eurjchem-597	243	5	2‐(4‐chlorophenyl	2‐(4‐chlorophenyl	NUM
eurjchem-597	243	6	)	)	PUNCT
eurjchem-597	243	7	1‐4‐mercapto‐6‐	1‐4‐mercapto‐6‐	NOUN
eurjchem-597	243	8	phenylpyrimidine‐5‐carboxylate	phenylpyrimidine‐5‐carboxylate	NUM
eurjchem-597	243	9	(	(	PUNCT
eurjchem-597	243	10	4	4	NUM
eurjchem-597	243	11	)	)	PUNCT
eurjchem-597	243	12	was	be	AUX
eurjchem-597	243	13	allowed	allow	VERB
eurjchem-597	243	14	to	to	PART
eurjchem-597	243	15	react	react	VERB
eurjchem-597	243	16	with	with	ADP
eurjchem-597	243	17	activated	activate	VERB
eurjchem-597	243	18	halomethylene	halomethylene	NOUN
eurjchem-597	243	19	compounds	compound	NOUN
eurjchem-597	243	20	(	(	PUNCT
eurjchem-597	243	21	benzyl	benzyl	NOUN
eurjchem-597	243	22	chloride	chloride	NOUN
eurjchem-597	243	23	,	,	PUNCT
eurjchem-597	243	24	ethyl	ethyl	PROPN
eurjchem-597	243	25	bromoacetate	bromoacetate	NOUN
eurjchem-597	243	26	,	,	PUNCT
eurjchem-597	243	27	chloroacetamide	chloroacetamide	NOUN
eurjchem-597	243	28	and/or	and/or	CCONJ
eurjchem-597	243	29	phenacyl	phenacyl	PROPN
eurjchem-597	243	30	bromide	bromide	NOUN
eurjchem-597	243	31	)	)	PUNCT
eurjchem-597	243	32	afforded	afford	VERB
eurjchem-597	243	33	the	the	DET
eurjchem-597	243	34	corresponding	correspond	VERB
eurjchem-597	243	35	4‐alkylthiopyrimidine	4‐alkylthiopyrimidine	NUM
eurjchem-597	243	36	derivatives	derivative	NOUN
eurjchem-597	243	37	(	(	PUNCT
eurjchem-597	243	38	7a‐d	7a‐d	NOUN
eurjchem-597	243	39	)	)	PUNCT
eurjchem-597	243	40	which	which	PRON
eurjchem-597	243	41	converted	convert	VERB
eurjchem-597	243	42	to	to	ADP
eurjchem-597	243	43	thienopyrimidine	thienopyrimidine	NOUN
eurjchem-597	243	44	(	(	PUNCT
eurjchem-597	243	45	8a‐d	8a‐d	ADV
eurjchem-597	243	46	)	)	PUNCT
eurjchem-597	243	47	upon	upon	SCONJ
eurjchem-597	243	48	refluxing	refluxe	VERB
eurjchem-597	243	49	in	in	ADP
eurjchem-597	243	50	basic	basic	ADJ
eurjchem-597	243	51	medium	medium	NOUN
eurjchem-597	243	52	.	.	PUNCT
eurjchem-597	243	53	oxidative	oxidative	ADJ
eurjchem-597	243	54	cyclization	cyclization	NOUN
eurjchem-597	243	55	of	of	ADP
eurjchem-597	243	56	compound	compound	NOUN
eurjchem-597	243	57	7b	7b	NOUN
eurjchem-597	243	58	using	use	VERB
eurjchem-597	243	59	potassium	potassium	NOUN
eurjchem-597	243	60	permengenate	permengenate	NOUN
eurjchem-597	243	61	in	in	ADP
eurjchem-597	243	62	acidic	acidic	ADJ
eurjchem-597	243	63	medium	medium	NOUN
eurjchem-597	243	64	afforded	afford	VERB
eurjchem-597	243	65	thienopyrimidine	thienopyrimidine	NOUN
eurjchem-597	243	66	dioxide	dioxide	NOUN
eurjchem-597	243	67	(	(	PUNCT
eurjchem-597	243	68	9	9	NUM
eurjchem-597	243	69	)	)	PUNCT
eurjchem-597	243	70	.	.	PUNCT
eurjchem-597	244	1	while	while	SCONJ
eurjchem-597	244	2	,	,	PUNCT
eurjchem-597	244	3	alkylation	alkylation	NOUN
eurjchem-597	244	4	of	of	ADP
eurjchem-597	244	5	ethyl	ethyl	PROPN
eurjchem-597	244	6	2‐(4‐chlorophenyl	2‐(4‐chlorophenyl	NUM
eurjchem-597	244	7	)	)	PUNCT
eurjchem-597	244	8	1‐4‐	1‐4‐	NUM
eurjchem-597	244	9	246	246	NUM
eurjchem-597	244	10	shehab	shehab	NOUN
eurjchem-597	244	11	and	and	CCONJ
eurjchem-597	244	12	mohamed	mohamed	PROPN
eurjchem-597	244	13	/	/	SYM
eurjchem-597	244	14	european	european	PROPN
eurjchem-597	244	15	journal	journal	PROPN
eurjchem-597	244	16	of	of	ADP
eurjchem-597	244	17	chemistry	chemistry	NOUN
eurjchem-597	244	18	3	3	NUM
eurjchem-597	244	19	(	(	PUNCT
eurjchem-597	244	20	2	2	NUM
eurjchem-597	244	21	)	)	PUNCT
eurjchem-597	244	22	(	(	PUNCT
eurjchem-597	244	23	2012	2012	NUM
eurjchem-597	244	24	)	)	PUNCT
eurjchem-597	244	25	241‐246	241‐246	NUM
eurjchem-597	244	26	mercapto‐6‐phenylpyrimidine‐5‐carboxylate	mercapto‐6‐phenylpyrimidine‐5‐carboxylate	NOUN
eurjchem-597	244	27	(	(	PUNCT
eurjchem-597	244	28	4	4	NUM
eurjchem-597	244	29	)	)	PUNCT
eurjchem-597	244	30	with	with	ADP
eurjchem-597	244	31	acrylonitrile	acrylonitrile	NOUN
eurjchem-597	244	32	in	in	ADP
eurjchem-597	244	33	pyrimidine	pyrimidine	NOUN
eurjchem-597	244	34	afforded	afford	VERB
eurjchem-597	244	35	4‐cyanoethylmercapto	4‐cyanoethylmercapto	NUM
eurjchem-597	244	36	pyrimidine	pyrimidine	NOUN
eurjchem-597	244	37	derivative	derivative	NOUN
eurjchem-597	244	38	(	(	PUNCT
eurjchem-597	244	39	10	10	NUM
eurjchem-597	244	40	)	)	PUNCT
eurjchem-597	244	41	which	which	PRON
eurjchem-597	244	42	proved	prove	VERB
eurjchem-597	244	43	its	its	PRON
eurjchem-597	244	44	structure	structure	NOUN
eurjchem-597	244	45	by	by	ADP
eurjchem-597	244	46	reaction	reaction	NOUN
eurjchem-597	244	47	with	with	ADP
eurjchem-597	244	48	hydrazine	hydrazine	NOUN
eurjchem-597	244	49	hydrate	hydrate	NOUN
eurjchem-597	244	50	[	[	X
eurjchem-597	244	51	12	12	NUM
eurjchem-597	244	52	]	]	X
eurjchem-597	244	53	giving	give	VERB
eurjchem-597	244	54	pyrazolo‐	pyrazolo‐	NOUN
eurjchem-597	244	55	pyrimidine	pyrimidine	NOUN
eurjchem-597	244	56	(	(	PUNCT
eurjchem-597	244	57	11).the	11).the	DET
eurjchem-597	244	58	ir	ir	PROPN
eurjchem-597	244	59	spectra	spectra	NOUN
eurjchem-597	244	60	of	of	ADP
eurjchem-597	244	61	compound	compound	NOUN
eurjchem-597	244	62	11	11	NUM
eurjchem-597	244	63	showed	show	VERB
eurjchem-597	244	64	the	the	DET
eurjchem-597	244	65	disappearance	disappearance	NOUN
eurjchem-597	244	66	of	of	ADP
eurjchem-597	244	67	the	the	DET
eurjchem-597	244	68	(	(	PUNCT
eurjchem-597	244	69	c	c	NOUN
eurjchem-597	244	70	=	=	NOUN
eurjchem-597	244	71	o	o	NOUN
eurjchem-597	244	72	)	)	PUNCT
eurjchem-597	244	73	group	group	NOUN
eurjchem-597	244	74	and	and	CCONJ
eurjchem-597	244	75	the	the	DET
eurjchem-597	244	76	(	(	PUNCT
eurjchem-597	244	77	cn	cn	PROPN
eurjchem-597	244	78	)	)	PUNCT
eurjchem-597	244	79	group	group	NOUN
eurjchem-597	244	80	.	.	PUNCT
eurjchem-597	245	1	1h	1h	NUM
eurjchem-597	245	2	nmr	nmr	NOUN
eurjchem-597	245	3	of	of	ADP
eurjchem-597	245	4	compound	compound	NOUN
eurjchem-597	245	5	11	11	NUM
eurjchem-597	245	6	showed	show	VERB
eurjchem-597	245	7	a	a	DET
eurjchem-597	245	8	signal	signal	NOUN
eurjchem-597	245	9	at	at	ADP
eurjchem-597	245	10			NUM
eurjchem-597	245	11	6.41	6.41	NUM
eurjchem-597	245	12	ppm	ppm	NOUN
eurjchem-597	245	13	characterized	characterize	VERB
eurjchem-597	245	14	for	for	ADP
eurjchem-597	245	15	nh	nh	PROPN
eurjchem-597	245	16	group	group	NOUN
eurjchem-597	245	17	of	of	ADP
eurjchem-597	245	18	pyrazole	pyrazole	NOUN
eurjchem-597	245	19	ring	ring	NOUN
eurjchem-597	245	20	.	.	PUNCT
eurjchem-597	246	1	oxidation	oxidation	NOUN
eurjchem-597	246	2	of	of	ADP
eurjchem-597	246	3	ethyl	ethyl	PROPN
eurjchem-597	246	4	2‐(4‐	2‐(4‐	PROPN
eurjchem-597	246	5	chlorophenyl	chlorophenyl	PROPN
eurjchem-597	246	6	)	)	PUNCT
eurjchem-597	246	7	1‐4‐mercapto‐6‐phenylpyrimidine‐5‐carboxy‐	1‐4‐mercapto‐6‐phenylpyrimidine‐5‐carboxy‐	NUM
eurjchem-597	246	8	late	late	ADJ
eurjchem-597	246	9	(	(	PUNCT
eurjchem-597	246	10	4	4	X
eurjchem-597	246	11	)	)	PUNCT
eurjchem-597	246	12	using	use	VERB
eurjchem-597	246	13	iodine	iodine	NOUN
eurjchem-597	246	14	in	in	ADP
eurjchem-597	246	15	acetic	acetic	ADJ
eurjchem-597	246	16	acid	acid	NOUN
eurjchem-597	247	1	[	[	X
eurjchem-597	247	2	13	13	NUM
eurjchem-597	247	3	]	]	PUNCT
eurjchem-597	247	4	gives	give	VERB
eurjchem-597	247	5	disulphide	disulphide	ADV
eurjchem-597	247	6	(	(	PUNCT
eurjchem-597	247	7	12	12	NUM
eurjchem-597	247	8	)	)	PUNCT
eurjchem-597	247	9	.	.	PUNCT
eurjchem-597	248	1	spiro	spiro	NOUN
eurjchem-597	248	2	compound	compound	NOUN
eurjchem-597	248	3	13	13	NUM
eurjchem-597	248	4	was	be	AUX
eurjchem-597	248	5	also	also	ADV
eurjchem-597	248	6	obtained	obtain	VERB
eurjchem-597	248	7	by	by	ADP
eurjchem-597	248	8	addition	addition	NOUN
eurjchem-597	248	9	of	of	ADP
eurjchem-597	248	10	compound	compound	NOUN
eurjchem-597	248	11	4	4	NUM
eurjchem-597	248	12	to	to	ADP
eurjchem-597	248	13	maleic	maleic	VERB
eurjchem-597	248	14	anhydride	anhydride	NOUN
eurjchem-597	248	15	in	in	ADP
eurjchem-597	248	16	refluxing	refluxing	NOUN
eurjchem-597	248	17	xylene	xylene	NOUN
eurjchem-597	248	18	and	and	CCONJ
eurjchem-597	248	19	few	few	ADJ
eurjchem-597	248	20	drops	drop	NOUN
eurjchem-597	248	21	of	of	ADP
eurjchem-597	248	22	piperdine	piperdine	NOUN
eurjchem-597	248	23	(	(	PUNCT
eurjchem-597	248	24	scheme	scheme	NOUN
eurjchem-597	248	25	2	2	NUM
eurjchem-597	248	26	)	)	PUNCT
eurjchem-597	248	27	.	.	PUNCT
eurjchem-597	249	1	reaction	reaction	NOUN
eurjchem-597	249	2	of	of	ADP
eurjchem-597	249	3	compound	compound	NOUN
eurjchem-597	249	4	4	4	NUM
eurjchem-597	249	5	with	with	ADP
eurjchem-597	249	6	chlorine	chlorine	NOUN
eurjchem-597	249	7	gas	gas	NOUN
eurjchem-597	249	8	in	in	ADP
eurjchem-597	249	9	acetic	acetic	ADJ
eurjchem-597	249	10	acid	acid	NOUN
eurjchem-597	250	1	[	[	X
eurjchem-597	250	2	14,15	14,15	NUM
eurjchem-597	250	3	]	]	PUNCT
eurjchem-597	250	4	gave	give	VERB
eurjchem-597	250	5	chloropyrimidine	chloropyrimidine	NOUN
eurjchem-597	250	6	(	(	PUNCT
eurjchem-597	250	7	15	15	NUM
eurjchem-597	250	8	)	)	PUNCT
eurjchem-597	250	9	.	.	PUNCT
eurjchem-597	251	1	the	the	DET
eurjchem-597	251	2	conversion	conversion	NOUN
eurjchem-597	251	3	of	of	ADP
eurjchem-597	251	4	compound	compound	NOUN
eurjchem-597	251	5	4	4	NUM
eurjchem-597	251	6	into	into	ADP
eurjchem-597	251	7	compound	compound	NOUN
eurjchem-597	251	8	15	15	NUM
eurjchem-597	251	9	may	may	AUX
eurjchem-597	251	10	be	be	AUX
eurjchem-597	251	11	proceed	procee	VERB
eurjchem-597	251	12	through	through	ADP
eurjchem-597	251	13	the	the	DET
eurjchem-597	251	14	formation	formation	NOUN
eurjchem-597	251	15	of	of	ADP
eurjchem-597	251	16	pyrimidine‐4‐sulphonyl	pyrimidine‐4‐sulphonyl	NOUN
eurjchem-597	251	17	chloride	chloride	NOUN
eurjchem-597	251	18	(	(	PUNCT
eurjchem-597	251	19	14	14	NUM
eurjchem-597	251	20	)	)	PUNCT
eurjchem-597	251	21	which	which	PRON
eurjchem-597	251	22	liberated	liberate	VERB
eurjchem-597	251	23	sulfurdioxide	sulfurdioxide	ADV
eurjchem-597	251	24	to	to	PART
eurjchem-597	251	25	give	give	VERB
eurjchem-597	251	26	compound	compound	NOUN
eurjchem-597	251	27	15	15	NUM
eurjchem-597	251	28	which	which	PRON
eurjchem-597	251	29	reacted	react	VERB
eurjchem-597	251	30	with	with	ADP
eurjchem-597	251	31	thiourea	thiourea	NOUN
eurjchem-597	251	32	affording	afford	VERB
eurjchem-597	251	33	the	the	DET
eurjchem-597	251	34	pyrimidopyrimidine	pyrimidopyrimidine	NOUN
eurjchem-597	251	35	(	(	PUNCT
eurjchem-597	251	36	16	16	NUM
eurjchem-597	251	37	)	)	PUNCT
eurjchem-597	251	38	,	,	PUNCT
eurjchem-597	251	39	while	while	SCONJ
eurjchem-597	251	40	the	the	DET
eurjchem-597	251	41	condensation	condensation	NOUN
eurjchem-597	251	42	of	of	ADP
eurjchem-597	251	43	compound	compound	NOUN
eurjchem-597	251	44	15	15	NUM
eurjchem-597	251	45	with	with	ADP
eurjchem-597	251	46	benzilmonohydrazone	benzilmonohydrazone	NOUN
eurjchem-597	251	47	gave	give	VERB
eurjchem-597	251	48	the	the	DET
eurjchem-597	251	49	corresponding	corresponding	ADJ
eurjchem-597	251	50	pyrimidopyridazine	pyrimidopyridazine	NOUN
eurjchem-597	251	51	(	(	PUNCT
eurjchem-597	251	52	18	18	NUM
eurjchem-597	251	53	)	)	PUNCT
eurjchem-597	251	54	via	via	ADP
eurjchem-597	251	55	the	the	DET
eurjchem-597	251	56	initial	initial	ADJ
eurjchem-597	251	57	formation	formation	NOUN
eurjchem-597	251	58	of	of	ADP
eurjchem-597	251	59	non‐isolated	non‐isolated	ADJ
eurjchem-597	251	60	open	open	ADJ
eurjchem-597	251	61	form	form	NOUN
eurjchem-597	251	62	(	(	PUNCT
eurjchem-597	251	63	17	17	NUM
eurjchem-597	251	64	)	)	PUNCT
eurjchem-597	251	65	that	that	PRON
eurjchem-597	251	66	underwent	undergo	VERB
eurjchem-597	251	67	intramolecular	intramolecular	ADJ
eurjchem-597	251	68	cyclocondensation	cyclocondensation	NOUN
eurjchem-597	252	1	[	[	X
eurjchem-597	252	2	16‐18	16‐18	NOUN
eurjchem-597	252	3	]	]	PUNCT
eurjchem-597	252	4	.	.	PUNCT
eurjchem-597	253	1	the	the	DET
eurjchem-597	253	2	reaction	reaction	NOUN
eurjchem-597	253	3	of	of	ADP
eurjchem-597	253	4	compound	compound	NOUN
eurjchem-597	253	5	15	15	NUM
eurjchem-597	253	6	with	with	ADP
eurjchem-597	253	7	sodium	sodium	NOUN
eurjchem-597	253	8	azide	azide	NOUN
eurjchem-597	253	9	gave	give	VERB
eurjchem-597	253	10	the	the	DET
eurjchem-597	253	11	corresponding	correspond	VERB
eurjchem-597	253	12	tetrazolopyrimidine	tetrazolopyrimidine	NOUN
eurjchem-597	253	13	(	(	PUNCT
eurjchem-597	253	14	20	20	NUM
eurjchem-597	253	15	)	)	PUNCT
eurjchem-597	253	16	presumably	presumably	ADV
eurjchem-597	253	17	via	via	ADP
eurjchem-597	253	18	the	the	DET
eurjchem-597	253	19	formation	formation	NOUN
eurjchem-597	253	20	of	of	ADP
eurjchem-597	253	21	azide	azide	NOUN
eurjchem-597	253	22	form	form	NOUN
eurjchem-597	253	23	(	(	PUNCT
eurjchem-597	253	24	19	19	NUM
eurjchem-597	253	25	)	)	PUNCT
eurjchem-597	253	26	.	.	PUNCT
eurjchem-597	254	1	the	the	DET
eurjchem-597	254	2	structure	structure	NOUN
eurjchem-597	254	3	of	of	ADP
eurjchem-597	254	4	compound	compound	NOUN
eurjchem-597	254	5	20	20	NUM
eurjchem-597	254	6	was	be	AUX
eurjchem-597	254	7	proved	prove	VERB
eurjchem-597	254	8	by	by	ADP
eurjchem-597	254	9	the	the	DET
eurjchem-597	254	10	disappearance	disappearance	NOUN
eurjchem-597	254	11	of	of	ADP
eurjchem-597	254	12	azido	azido	ADJ
eurjchem-597	254	13	group	group	NOUN
eurjchem-597	254	14	in	in	ADP
eurjchem-597	254	15	ir	ir	PROPN
eurjchem-597	254	16	spectrum	spectrum	PROPN
eurjchem-597	254	17	(	(	PUNCT
eurjchem-597	254	18	scheme	scheme	NOUN
eurjchem-597	254	19	3	3	NUM
eurjchem-597	254	20	)	)	PUNCT
eurjchem-597	254	21	.	.	PUNCT
eurjchem-597	255	1	finally	finally	ADV
eurjchem-597	255	2	,	,	PUNCT
eurjchem-597	255	3	synthesis	synthesis	NOUN
eurjchem-597	255	4	of	of	ADP
eurjchem-597	255	5	6‐(4‐chlorophenyl)‐4‐phenyl‐2‐(1‐	6‐(4‐chlorophenyl)‐4‐phenyl‐2‐(1‐	NUM
eurjchem-597	255	6	phenylvinyl)‐1h‐pyrazolo[3,4‐d]pyrimidine‐3(2h)‐one	phenylvinyl)‐1h‐pyrazolo[3,4‐d]pyrimidine‐3(2h)‐one	NOUN
eurjchem-597	255	7	(	(	PUNCT
eurjchem-597	255	8	21	21	NUM
eurjchem-597	255	9	)	)	PUNCT
eurjchem-597	255	10	was	be	AUX
eurjchem-597	255	11	achieved	achieve	VERB
eurjchem-597	255	12	by	by	ADP
eurjchem-597	255	13	refluxing	refluxing	NOUN
eurjchem-597	255	14	chloropyrimidine	chloropyrimidine	NOUN
eurjchem-597	255	15	(	(	PUNCT
eurjchem-597	255	16	15	15	NUM
eurjchem-597	255	17	)	)	PUNCT
eurjchem-597	255	18	with	with	ADP
eurjchem-597	255	19	acetophenonehydrazone	acetophenonehydrazone	NOUN
eurjchem-597	255	20	in	in	ADP
eurjchem-597	255	21	ethanol	ethanol	NOUN
eurjchem-597	255	22	in	in	ADP
eurjchem-597	255	23	the	the	DET
eurjchem-597	255	24	presence	presence	NOUN
eurjchem-597	255	25	of	of	ADP
eurjchem-597	255	26	tea	tea	NOUN
eurjchem-597	255	27	(	(	PUNCT
eurjchem-597	255	28	scheme	scheme	NOUN
eurjchem-597	255	29	4	4	NUM
eurjchem-597	255	30	)	)	PUNCT
eurjchem-597	255	31	.	.	PUNCT
eurjchem-597	256	1	the	the	DET
eurjchem-597	256	2	reaction	reaction	NOUN
eurjchem-597	256	3	may	may	AUX
eurjchem-597	256	4	be	be	AUX
eurjchem-597	256	5	proceeding	proceed	VERB
eurjchem-597	256	6	via	via	ADP
eurjchem-597	256	7	the	the	DET
eurjchem-597	256	8	formation	formation	NOUN
eurjchem-597	256	9	of	of	ADP
eurjchem-597	256	10	acyclic	acyclic	ADJ
eurjchem-597	256	11	intermediate	intermediate	ADJ
eurjchem-597	256	12	,	,	PUNCT
eurjchem-597	256	13	followed	follow	VERB
eurjchem-597	256	14	by	by	ADP
eurjchem-597	256	15	ene‐rearrangement	ene‐rearrangement	NUM
eurjchem-597	256	16	then	then	ADV
eurjchem-597	256	17	ring	ring	NOUN
eurjchem-597	256	18	cyclization	cyclization	NOUN
eurjchem-597	256	19	as	as	SCONJ
eurjchem-597	256	20	shown	show	VERB
eurjchem-597	256	21	in	in	ADP
eurjchem-597	256	22	the	the	DET
eurjchem-597	256	23	following	follow	VERB
eurjchem-597	256	24	mechanism	mechanism	NOUN
eurjchem-597	256	25	.	.	PUNCT
eurjchem-597	257	1	references	reference	NOUN
eurjchem-597	257	2	[	[	X
eurjchem-597	257	3	1	1	NUM
eurjchem-597	257	4	]	]	PUNCT
eurjchem-597	257	5	.	.	PUNCT
eurjchem-597	258	1	padmaja	padmaja	PROPN
eurjchem-597	258	2	,	,	PUNCT
eurjchem-597	258	3	a.	a.	NOUN
eurjchem-597	258	4	;	;	PUNCT
eurjchem-597	258	5	payani	payani	PROPN
eurjchem-597	258	6	,	,	PUNCT
eurjchem-597	258	7	t.	t.	PROPN
eurjchem-597	258	8	;	;	PUNCT
eurjchem-597	258	9	diunneswra	diunneswra	PROPN
eurjchem-597	258	10	reddy	reddy	PROPN
eurjchem-597	258	11	,	,	PUNCT
eurjchem-597	258	12	g.	g.	PROPN
eurjchem-597	258	13	;	;	PUNCT
eurjchem-597	258	14	padmavahi	padmavahi	PROPN
eurjchem-597	258	15	,	,	PUNCT
eurjchem-597	258	16	v.	v.	CCONJ
eurjchem-597	258	17	eur	eur	PROPN
eurjchem-597	258	18	.	.	PUNCT
eurjchem-597	259	1	j.	j.	PROPN
eurjchem-597	259	2	med	med	PROPN
eurjchem-597	259	3	.	.	PROPN
eurjchem-597	259	4	chem	chem	PROPN
eurjchem-597	259	5	.	.	PUNCT
eurjchem-597	260	1	2009	2009	NUM
eurjchem-597	260	2	,	,	PUNCT
eurjchem-597	260	3	44	44	NUM
eurjchem-597	260	4	,	,	PUNCT
eurjchem-597	260	5	4557‐4566	4557‐4566	NUM
eurjchem-597	260	6	.	.	PUNCT
eurjchem-597	261	1	[	[	X
eurjchem-597	261	2	2	2	NUM
eurjchem-597	261	3	]	]	PUNCT
eurjchem-597	261	4	.	.	PUNCT
eurjchem-597	262	1	sondhi	sondhi	PROPN
eurjchem-597	262	2	,	,	PUNCT
eurjchem-597	262	3	s.	s.	PROPN
eurjchem-597	262	4	m.	m.	PROPN
eurjchem-597	262	5	;	;	PUNCT
eurjchem-597	262	6	singh	singh	PROPN
eurjchem-597	262	7	,	,	PUNCT
eurjchem-597	262	8	n.	n.	NOUN
eurjchem-597	262	9	;	;	PUNCT
eurjchem-597	262	10	johar	johar	PROPN
eurjchem-597	262	11	,	,	PUNCT
eurjchem-597	262	12	m.	m.	NOUN
eurjchem-597	262	13	;	;	PUNCT
eurjchem-597	262	14	kumar	kumar	PROPN
eurjchem-597	262	15	,	,	PUNCT
eurjchem-597	262	16	b.	b.	PROPN
eurjchem-597	262	17	bioorg	bioorg	PROPN
eurjchem-597	262	18	.	.	PUNCT
eurjchem-597	263	1	med	med	PROPN
eurjchem-597	263	2	.	.	PROPN
eurjchem-597	263	3	chem	chem	PROPN
eurjchem-597	263	4	.	.	PUNCT
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eurjchem-597	264	2	,	,	PUNCT
eurjchem-597	264	3	13	13	NUM
eurjchem-597	264	4	,	,	PUNCT
eurjchem-597	264	5	6158‐6166	6158‐6166	NUM
eurjchem-597	264	6	.	.	PUNCT
eurjchem-597	265	1	[	[	X
eurjchem-597	265	2	3	3	NUM
eurjchem-597	265	3	]	]	PUNCT
eurjchem-597	265	4	.	.	PUNCT
eurjchem-597	266	1	sondhi	sondhi	PROPN
eurjchem-597	266	2	,	,	PUNCT
eurjchem-597	266	3	s.	s.	PROPN
eurjchem-597	266	4	m.	m.	PROPN
eurjchem-597	266	5	;	;	PUNCT
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eurjchem-597	266	7	,	,	PUNCT
eurjchem-597	266	8	s.	s.	PROPN
eurjchem-597	266	9	;	;	PUNCT
eurjchem-597	266	10	dinodia	dinodia	NOUN
eurjchem-597	266	11	,	,	PUNCT
eurjchem-597	266	12	m.	m.	NOUN
eurjchem-597	266	13	;	;	PUNCT
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eurjchem-597	266	15	,	,	PUNCT
eurjchem-597	266	16	r.	r.	PROPN
eurjchem-597	266	17	;	;	PUNCT
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eurjchem-597	266	20	r.	r.	PROPN
eurjchem-597	266	21	bioorg	bioorg	PROPN
eurjchem-597	266	22	.	.	PUNCT
eurjchem-597	267	1	med	med	PROPN
eurjchem-597	267	2	.	.	PROPN
eurjchem-597	267	3	chem	chem	PROPN
eurjchem-597	267	4	.	.	PUNCT
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eurjchem-597	268	2	,	,	PUNCT
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eurjchem-597	268	4	,	,	PUNCT
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eurjchem-597	268	6	.	.	PUNCT
eurjchem-597	269	1	[	[	X
eurjchem-597	269	2	4	4	NUM
eurjchem-597	269	3	]	]	PUNCT
eurjchem-597	269	4	.	.	PUNCT
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eurjchem-597	270	2	,	,	PUNCT
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eurjchem-597	270	4	;	;	PUNCT
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eurjchem-597	270	7	s.	s.	PROPN
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eurjchem-597	270	9	;	;	PUNCT
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eurjchem-597	270	11	,	,	PUNCT
eurjchem-597	270	12	h.	h.	PROPN
eurjchem-597	270	13	;	;	PUNCT
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eurjchem-597	270	15	,	,	PUNCT
eurjchem-597	270	16	m.	m.	PROPN
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eurjchem-597	270	18	;	;	PUNCT
eurjchem-597	270	19	debnath	debnath	PROPN
eurjchem-597	270	20	,	,	PUNCT
eurjchem-597	270	21	a.	a.	PROPN
eurjchem-597	270	22	k.	k.	PROPN
eurjchem-597	270	23	;	;	PUNCT
eurjchem-597	270	24	hansch	hansch	PROPN
eurjchem-597	270	25	,	,	PUNCT
eurjchem-597	270	26	c.	c.	PROPN
eurjchem-597	270	27	chem	chem	PROPN
eurjchem-597	270	28	.	.	PUNCT
eurjchem-597	271	1	rev	rev	PROPN
eurjchem-597	271	2	.	.	PROPN
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eurjchem-597	271	4	,	,	PUNCT
eurjchem-597	271	5	99	99	NUM
eurjchem-597	271	6	,	,	PUNCT
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eurjchem-597	271	8	.	.	PUNCT
eurjchem-597	272	1	[	[	X
eurjchem-597	272	2	5	5	NUM
eurjchem-597	272	3	]	]	PUNCT
eurjchem-597	272	4	.	.	PUNCT
eurjchem-597	273	1	amr	amr	PROPN
eurjchem-597	273	2	,	,	PUNCT
eurjchem-597	273	3	a.	a.	PROPN
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eurjchem-597	273	5	;	;	PUNCT
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eurjchem-597	273	13	s.	s.	PROPN
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eurjchem-597	273	15	;	;	PUNCT
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eurjchem-597	273	17	,	,	PUNCT
eurjchem-597	273	18	n.	n.	PROPN
eurjchem-597	273	19	a.	a.	PROPN
eurjchem-597	273	20	;	;	PUNCT
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eurjchem-597	273	22	,	,	PUNCT
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eurjchem-597	273	24	g.	g.	PROPN
eurjchem-597	273	25	bioorg	bioorg	PROPN
eurjchem-597	273	26	.	.	PUNCT
eurjchem-597	274	1	med	med	PROPN
eurjchem-597	274	2	.	.	PROPN
eurjchem-597	274	3	chem	chem	PROPN
eurjchem-597	274	4	.	.	PUNCT
eurjchem-597	275	1	2006	2006	NUM
eurjchem-597	275	2	,	,	PUNCT
eurjchem-597	275	3	14	14	NUM
eurjchem-597	275	4	,	,	PUNCT
eurjchem-597	275	5	5481‐5488	5481‐5488	NUM
eurjchem-597	275	6	.	.	PUNCT
eurjchem-597	276	1	[	[	X
eurjchem-597	276	2	6	6	NUM
eurjchem-597	276	3	]	]	PUNCT
eurjchem-597	276	4	.	.	PUNCT
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eurjchem-597	276	6	,	,	PUNCT
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eurjchem-597	276	9	;	;	PUNCT
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eurjchem-597	276	17	s.	s.	PROPN
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eurjchem-597	276	19	;	;	PUNCT
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eurjchem-597	276	21	,	,	PUNCT
eurjchem-597	276	22	a.	a.	NOUN
eurjchem-597	276	23	m.	m.	NOUN
eurjchem-597	276	24	;	;	PUNCT
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eurjchem-597	276	26	,	,	PUNCT
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eurjchem-597	277	1	j.	j.	PROPN
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eurjchem-597	277	5	.	.	PUNCT
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eurjchem-597	278	2	,	,	PUNCT
eurjchem-597	278	3	45	45	NUM
eurjchem-597	278	4	,	,	PUNCT
eurjchem-597	278	5	171‐178	171‐178	NUM
eurjchem-597	278	6	.	.	PUNCT
eurjchem-597	279	1	[	[	X
eurjchem-597	279	2	7	7	NUM
eurjchem-597	279	3	]	]	PUNCT
eurjchem-597	279	4	.	.	PUNCT
eurjchem-597	280	1	breoutt	breoutt	PROPN
eurjchem-597	280	2	,	,	PUNCT
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eurjchem-597	280	5	;	;	PUNCT
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eurjchem-597	280	7	,	,	PUNCT
eurjchem-597	280	8	j.	j.	PROPN
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eurjchem-597	280	10	;	;	PUNCT
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eurjchem-597	280	12	.	.	PUNCT
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eurjchem-597	281	2	.	.	PUNCT
eurjchem-597	282	1	appl	appl	PROPN
eurjchem-597	282	2	.	.	PROPN
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eurjchem-597	283	3	.	.	PUNCT
eurjchem-597	284	1	chem	chem	NOUN
eurjchem-597	284	2	.	.	PUNCT
eurjchem-597	285	1	abstr	abstr	PROPN
eurjchem-597	285	2	.	.	PUNCT
eurjchem-597	286	1	2000	2000	NUM
eurjchem-597	286	2	,	,	PUNCT
eurjchem-597	286	3	132	132	NUM
eurjchem-597	286	4	,	,	PUNCT
eurjchem-597	286	5	194385	194385	NUM
eurjchem-597	286	6	.	.	PUNCT
eurjchem-597	287	1	[	[	X
eurjchem-597	287	2	8	8	NUM
eurjchem-597	287	3	]	]	PUNCT
eurjchem-597	287	4	.	.	PUNCT
eurjchem-597	288	1	zhikareva	zhikareva	PROPN
eurjchem-597	288	2	,	,	PUNCT
eurjchem-597	288	3	g.	g.	PROPN
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eurjchem-597	288	5	;	;	PUNCT
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eurjchem-597	288	7	,	,	PUNCT
eurjchem-597	288	8	l.	l.	PROPN
eurjchem-597	288	9	i.	i.	PROPN
eurjchem-597	288	10	;	;	PUNCT
eurjchem-597	288	11	evstratova	evstratova	PROPN
eurjchem-597	288	12	,	,	PUNCT
eurjchem-597	288	13	m.	m.	NOUN
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eurjchem-597	288	15	;	;	PUNCT
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eurjchem-597	288	19	m.	m.	PROPN
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eurjchem-597	288	24	v.	v.	PROPN
eurjchem-597	288	25	;	;	PUNCT
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eurjchem-597	288	27	,	,	PUNCT
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eurjchem-597	288	30	;	;	PUNCT
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eurjchem-597	288	37	.	.	PUNCT
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eurjchem-597	289	2	.	.	PUNCT
eurjchem-597	290	1	zh	zh	PROPN
eurjchem-597	290	2	.	.	PROPN
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eurjchem-597	291	1	[	[	X
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eurjchem-597	291	4	.	.	PUNCT
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eurjchem-597	292	7	,	,	PUNCT
eurjchem-597	292	8	n.	n.	PROPN
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eurjchem-597	292	10	;	;	PUNCT
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eurjchem-597	292	18	.	.	PUNCT
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eurjchem-597	293	2	,	,	PUNCT
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eurjchem-597	293	4	,	,	PUNCT
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eurjchem-597	293	6	.	.	PUNCT
eurjchem-597	294	1	[	[	X
eurjchem-597	294	2	10	10	NUM
eurjchem-597	294	3	]	]	PUNCT
eurjchem-597	294	4	.	.	PUNCT
eurjchem-597	295	1	assy	assy	NOUN
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eurjchem-597	295	5	;	;	PUNCT
eurjchem-597	295	6	hassamine	hassamine	NOUN
eurjchem-597	295	7	,	,	PUNCT
eurjchem-597	295	8	g.	g.	PROPN
eurjchem-597	295	9	a.	a.	NOUN
eurjchem-597	295	10	phosphorus	phosphorus	NOUN
eurjchem-597	295	11	sulfur	sulfur	NOUN
eurjchem-597	295	12	1995	1995	NUM
eurjchem-597	295	13	,	,	PUNCT
eurjchem-597	295	14	102	102	NUM
eurjchem-597	295	15	,	,	PUNCT
eurjchem-597	295	16	95‐102	95‐102	NUM
eurjchem-597	295	17	.	.	PUNCT
eurjchem-597	296	1	[	[	X
eurjchem-597	296	2	11	11	NUM
eurjchem-597	296	3	]	]	PUNCT
eurjchem-597	296	4	.	.	PUNCT
eurjchem-597	297	1	assy	assy	NOUN
eurjchem-597	297	2	,	,	PUNCT
eurjchem-597	297	3	m.	m.	NOUN
eurjchem-597	297	4	g.	g.	PROPN
eurjchem-597	297	5	sulfur	sulfur	PROPN
eurjchem-597	297	6	lett	lett	PROPN
eurjchem-597	297	7	.	.	PUNCT
eurjchem-597	298	1	1990	1990	NUM
eurjchem-597	298	2	,	,	PUNCT
eurjchem-597	298	3	11	11	NUM
eurjchem-597	298	4	,	,	PUNCT
eurjchem-597	298	5	75‐80	75‐80	NOUN
eurjchem-597	298	6	.	.	PUNCT
eurjchem-597	299	1	[	[	X
eurjchem-597	299	2	12	12	NUM
eurjchem-597	299	3	]	]	PUNCT
eurjchem-597	299	4	.	.	PUNCT
eurjchem-597	300	1	drobinca	drobinca	PROPN
eurjchem-597	300	2	,	,	PUNCT
eurjchem-597	300	3	k.	k.	PROPN
eurjchem-597	300	4	;	;	PUNCT
eurjchem-597	300	5	augustin	augustin	PROPN
eurjchem-597	300	6	,	,	PUNCT
eurjchem-597	300	7	j.	j.	PROPN
eurjchem-597	300	8	;	;	PUNCT
eurjchem-597	300	9	patai	patai	PROPN
eurjchem-597	300	10	,	,	PUNCT
eurjchem-597	300	11	s.	s.	PROPN
eurjchem-597	300	12	22	22	NUM
eurjchem-597	300	13	edn	edn	NOUN
eurjchem-597	300	14	.	.	PUNCT
eurjchem-597	300	15	,	,	PUNCT
eurjchem-597	300	16	wiley	wiley	NOUN
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eurjchem-597	300	18	sons	son	NOUN
eurjchem-597	300	19	;	;	PUNCT
eurjchem-597	300	20	new	new	PROPN
eurjchem-597	300	21	york	york	PROPN
eurjchem-597	300	22	1977	1977	NUM
eurjchem-597	300	23	.	.	PUNCT
eurjchem-597	301	1	[	[	X
eurjchem-597	301	2	13	13	NUM
eurjchem-597	301	3	]	]	PUNCT
eurjchem-597	301	4	.	.	PUNCT
eurjchem-597	302	1	el‐dean	el‐dean	ADJ
eurjchem-597	302	2	,	,	PUNCT
eurjchem-597	302	3	a.	a.	NOUN
eurjchem-597	302	4	m.	m.	PROPN
eurjchem-597	302	5	k.	k.	PROPN
eurjchem-597	302	6	;	;	PUNCT
eurjchem-597	302	7	abdel‐moneam	abdel‐moneam	PROPN
eurjchem-597	302	8	,	,	PUNCT
eurjchem-597	302	9	m.	m.	PROPN
eurjchem-597	302	10	e.	e.	PROPN
eurjchem-597	302	11	j.	j.	PROPN
eurjchem-597	302	12	chinese	chinese	PROPN
eurjchem-597	302	13	chem	chem	PROPN
eurjchem-597	302	14	.	.	PUNCT
eurjchem-597	303	1	soc	soc	PROPN
eurjchem-597	303	2	.	.	PUNCT
eurjchem-597	304	1	2002	2002	NUM
eurjchem-597	304	2	,	,	PUNCT
eurjchem-597	304	3	49	49	NUM
eurjchem-597	304	4	,	,	PUNCT
eurjchem-597	304	5	1057‐1060	1057‐1060	NUM
eurjchem-597	304	6	.	.	PUNCT
eurjchem-597	305	1	[	[	X
eurjchem-597	305	2	14	14	NUM
eurjchem-597	305	3	]	]	SYM
eurjchem-597	305	4	.	.	PUNCT
eurjchem-597	306	1	el‐dean	el‐dean	ADJ
eurjchem-597	306	2	,	,	PUNCT
eurjchem-597	306	3	a.	a.	NOUN
eurjchem-597	306	4	m.	m.	PROPN
eurjchem-597	306	5	k.	k.	PROPN
eurjchem-597	306	6	;	;	PUNCT
eurjchem-597	306	7	abdel‐moneam	abdel‐moneam	PROPN
eurjchem-597	306	8	,	,	PUNCT
eurjchem-597	306	9	m.	m.	PROPN
eurjchem-597	306	10	e.	e.	PROPN
eurjchem-597	306	11	phosphorus	phosphorus	PROPN
eurjchem-597	306	12	sulfur	sulfur	NOUN
eurjchem-597	306	13	2002	2002	NUM
eurjchem-597	306	14	,	,	PUNCT
eurjchem-597	306	15	177	177	NUM
eurjchem-597	306	16	,	,	PUNCT
eurjchem-597	306	17	2745‐2751	2745‐2751	NUM
eurjchem-597	306	18	.	.	PUNCT
eurjchem-597	307	1	[	[	X
eurjchem-597	307	2	15	15	NUM
eurjchem-597	307	3	]	]	PUNCT
eurjchem-597	307	4	.	.	PUNCT
eurjchem-597	308	1	el‐bahaie	el‐bahaie	PROPN
eurjchem-597	308	2	,	,	PUNCT
eurjchem-597	308	3	s.	s.	PROPN
eurjchem-597	308	4	;	;	PUNCT
eurjchem-597	308	5	assy	assy	NOUN
eurjchem-597	308	6	,	,	PUNCT
eurjchem-597	308	7	m.	m.	NOUN
eurjchem-597	308	8	g.	g.	PROPN
eurjchem-597	308	9	;	;	PUNCT
eurjchem-597	308	10	ibrahim	ibrahim	PROPN
eurjchem-597	308	11	,	,	PUNCT
eurjchem-597	308	12	y.	y.	NOUN
eurjchem-597	308	13	a.	a.	NOUN
eurjchem-597	308	14	sulfur	sulfur	PROPN
eurjchem-597	308	15	lett	lett	PROPN
eurjchem-597	308	16	.	.	PUNCT
eurjchem-597	308	17	1989	1989	NUM
eurjchem-597	308	18	,	,	PUNCT
eurjchem-597	308	19	9	9	NUM
eurjchem-597	308	20	,	,	PUNCT
eurjchem-597	308	21	201‐208	201‐208	NUM
eurjchem-597	308	22	.	.	PUNCT
eurjchem-597	309	1	[	[	X
eurjchem-597	309	2	16	16	NUM
eurjchem-597	309	3	]	]	PUNCT
eurjchem-597	309	4	.	.	PUNCT
eurjchem-597	310	1	cumha	cumha	PROPN
eurjchem-597	310	2	,	,	PUNCT
eurjchem-597	310	3	s.	s.	PROPN
eurjchem-597	310	4	;	;	PUNCT
eurjchem-597	310	5	bastos	bastos	PROPN
eurjchem-597	310	6	,	,	PUNCT
eurjchem-597	310	7	r.	r.	PROPN
eurjchem-597	310	8	m.	m.	PROPN
eurjchem-597	310	9	;	;	PUNCT
eurjchem-597	310	10	silva	silva	PROPN
eurjchem-597	310	11	,	,	PUNCT
eurjchem-597	310	12	p.	p.	PROPN
eurjchem-597	310	13	de	de	PROPN
eurjchem-597	310	14	o.	o.	PROPN
eurjchem-597	310	15	;	;	PUNCT
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eurjchem-597	310	17	,	,	PUNCT
eurjchem-597	310	18	c.	c.	PROPN
eurjchem-597	310	19	;	;	PUNCT
eurjchem-597	310	20	giselle	giselle	PROPN
eurjchem-597	310	21	,	,	PUNCT
eurjchem-597	310	22	a.	a.	PROPN
eurjchem-597	310	23	;	;	PUNCT
eurjchem-597	310	24	vencato	vencato	PROPN
eurjchem-597	310	25	,	,	PUNCT
eurjchem-597	310	26	i.	i.	NOUN
eurjchem-597	310	27	;	;	PUNCT
eurjchem-597	310	28	lariucci	lariucci	PROPN
eurjchem-597	310	29	,	,	PUNCT
eurjchem-597	310	30	g.	g.	PROPN
eurjchem-597	310	31	;	;	PUNCT
eurjchem-597	310	32	napolitano	napolitano	PROPN
eurjchem-597	310	33	,	,	PUNCT
eurjchem-597	310	34	h.	h.	PROPN
eurjchem-597	310	35	b.	b.	PROPN
eurjchem-597	310	36	;	;	PUNCT
eurjchem-597	310	37	deoiveria	deoiveria	PROPN
eurjchem-597	310	38	,	,	PUNCT
eurjchem-597	310	39	c.	c.	PROPN
eurjchem-597	310	40	a.	a.	PROPN
eurjchem-597	310	41	;	;	PUNCT
eurjchem-597	310	42	kato	kato	PROPN
eurjchem-597	310	43	,	,	PUNCT
eurjchem-597	310	44	l.	l.	PROPN
eurjchem-597	310	45	;	;	PUNCT
eurjchem-597	310	46	dasilva	dasilva	PROPN
eurjchem-597	310	47	,	,	PUNCT
eurjchem-597	310	48	c.	c.	PROPN
eurjchem-597	310	49	c.	c.	PROPN
eurjchem-597	310	50	moatsh	moatsh	PROPN
eurjchem-597	310	51	.	.	PUNCT
eurjchem-597	311	1	furchem	furchem	PROPN
eurjchem-597	311	2	.	.	PUNCT
eurjchem-597	312	1	2007	2007	NUM
eurjchem-597	312	2	,	,	PUNCT
eurjchem-597	312	3	138	138	NUM
eurjchem-597	312	4	,	,	PUNCT
eurjchem-597	312	5	111‐119	111‐119	NUM
eurjchem-597	312	6	.	.	PUNCT
eurjchem-597	313	1	[	[	X
eurjchem-597	313	2	17	17	NUM
eurjchem-597	313	3	]	]	PUNCT
eurjchem-597	313	4	.	.	PUNCT
eurjchem-597	313	5	assy	assy	PROPN
eurjchem-597	313	6	,	,	PUNCT
eurjchem-597	313	7	m.	m.	NOUN
eurjchem-597	313	8	g.	g.	PROPN
eurjchem-597	313	9	;	;	PUNCT
eurjchem-597	313	10	el‐bahaie	el‐bahaie	PROPN
eurjchem-597	313	11	,	,	PUNCT
eurjchem-597	313	12	s.	s.	PROPN
eurjchem-597	313	13	;	;	PUNCT
eurjchem-597	313	14	ibrahim	ibrahim	PROPN
eurjchem-597	313	15	,	,	PUNCT
eurjchem-597	313	16	m.	m.	PROPN
eurjchem-597	313	17	r.	r.	PROPN
eurjchem-597	313	18	;	;	PUNCT
eurjchem-597	313	19	ibrahim	ibrahim	PROPN
eurjchem-597	313	20	,	,	PUNCT
eurjchem-597	313	21	y.	y.	PROPN
eurjchem-597	313	22	a.	a.	PROPN
eurjchem-597	313	23	indian	indian	PROPN
eurjchem-597	313	24	j.	j.	PROPN
eurjchem-597	313	25	chem	chem	PROPN
eurjchem-597	313	26	.	.	PUNCT
eurjchem-597	314	1	soc	soc	PROPN
eurjchem-597	314	2	.	.	PUNCT
eurjchem-597	315	1	b	b	NOUN
eurjchem-597	315	2	1996	1996	NUM
eurjchem-597	315	3	,	,	PUNCT
eurjchem-597	315	4	35(6	35(6	NUM
eurjchem-597	315	5	)	)	PUNCT
eurjchem-597	315	6	,	,	PUNCT
eurjchem-597	315	7	598‐601	598‐601	NUM
eurjchem-597	315	8	.	.	PUNCT
eurjchem-597	316	1	[	[	X
eurjchem-597	316	2	18	18	NUM
eurjchem-597	316	3	]	]	PUNCT
eurjchem-597	316	4	.	.	PUNCT
eurjchem-597	317	1	amisworth	amisworth	PROPN
eurjchem-597	317	2	,	,	PUNCT
eurjchem-597	317	3	g.	g.	PROPN
eurjchem-597	317	4	;	;	PUNCT
eurjchem-597	317	5	yanes	yane	NOUN
eurjchem-597	317	6	,	,	PUNCT
eurjchem-597	317	7	r.	r.	PROPN
eurjchem-597	317	8	g.	g.	PROPN
eurjchem-597	317	9	j.	j.	PROPN
eurjchem-597	317	10	am	am	PROPN
eurjchem-597	317	11	.	.	PUNCT
eurjchem-597	318	1	chem	chem	NOUN
eurjchem-597	318	2	.	.	PUNCT
eurjchem-597	319	1	soc	soc	PROPN
eurjchem-597	319	2	.	.	PUNCT
eurjchem-597	320	1	1953	1953	NUM
eurjchem-597	320	2	,	,	PUNCT
eurjchem-597	320	3	75	75	NUM
eurjchem-597	320	4	,	,	PUNCT
eurjchem-597	320	5	4915‐4922	4915‐4922	NUM
eurjchem-597	320	6	.	.	PUNCT