id	sid	tid	token	lemma	pos
eurjchem-604	1	1	untitled	untitle	VERB
eurjchem-604	1	2	european	european	PROPN
eurjchem-604	1	3	journal	journal	PROPN
eurjchem-604	1	4	of	of	ADP
eurjchem-604	1	5	chemistry	chemistry	NOUN
eurjchem-604	1	6	3	3	NUM
eurjchem-604	1	7	(	(	PUNCT
eurjchem-604	1	8	3	3	NUM
eurjchem-604	1	9	)	)	PUNCT
eurjchem-604	1	10	(	(	PUNCT
eurjchem-604	1	11	2012	2012	NUM
eurjchem-604	1	12	)	)	PUNCT
eurjchem-604	1	13	367‐394	367‐394	PROPN
eurjchem-604	1	14	european	european	PROPN
eurjchem-604	1	15	journal	journal	PROPN
eurjchem-604	1	16	of	of	ADP
eurjchem-604	1	17	chemistry	chemistry	NOUN
eurjchem-604	1	18	issn	issn	PROPN
eurjchem-604	1	19	2153‐2249	2153‐2249	PROPN
eurjchem-604	1	20	(	(	PUNCT
eurjchem-604	1	21	print	print	NOUN
eurjchem-604	1	22	)	)	PUNCT
eurjchem-604	1	23	/	/	SYM
eurjchem-604	1	24	issn	issn	PROPN
eurjchem-604	1	25	2153‐2257	2153‐2257	NUM
eurjchem-604	1	26	(	(	PUNCT
eurjchem-604	1	27	online	online	ADJ
eurjchem-604	1	28	)	)	PUNCT
eurjchem-604	1	29			NOUN
eurjchem-604	1	30	2012	2012	NUM
eurjchem-604	1	31	eurjchem	eurjchem	PROPN
eurjchem-604	1	32	doi:10.5155	doi:10.5155	PROPN
eurjchem-604	1	33	/	/	SYM
eurjchem-604	1	34	eurjchem.3.3.367‐394.604	eurjchem.3.3.367‐394.604	PROPN
eurjchem-604	1	35	european	european	PROPN
eurjchem-604	1	36	journal	journal	PROPN
eurjchem-604	1	37	of	of	ADP
eurjchem-604	1	38	chemistry	chemistry	PROPN
eurjchem-604	1	39	journal	journal	PROPN
eurjchem-604	1	40	homepage	homepage	NOUN
eurjchem-604	1	41	:	:	PUNCT
eurjchem-604	1	42	www.eurjchem.com	www.eurjchem.com	X
eurjchem-604	2	1	the	the	DET
eurjchem-604	2	2	chemistry	chemistry	NOUN
eurjchem-604	2	3	of	of	ADP
eurjchem-604	2	4	group‐vib	group‐vib	NOUN
eurjchem-604	2	5	metal	metal	NOUN
eurjchem-604	2	6	carbonyls	carbonyls	NOUN
eurjchem-604	2	7	manish	manish	PROPN
eurjchem-604	2	8	kaushika	kaushika	PROPN
eurjchem-604	2	9	,	,	PUNCT
eurjchem-604	2	10	*	*	PROPN
eurjchem-604	2	11	,	,	PUNCT
eurjchem-604	2	12	ayodhya	ayodhya	NOUN
eurjchem-604	2	13	singhb	singhb	NOUN
eurjchem-604	2	14	and	and	CCONJ
eurjchem-604	2	15	munesh	munesh	NOUN
eurjchem-604	2	16	kumara	kumara	VERB
eurjchem-604	2	17	a	a	DET
eurjchem-604	2	18	department	department	NOUN
eurjchem-604	2	19	of	of	ADP
eurjchem-604	2	20	chemistry	chemistry	NOUN
eurjchem-604	2	21	,	,	PUNCT
eurjchem-604	2	22	durga	durga	PROPN
eurjchem-604	2	23	prasad	prasad	PROPN
eurjchem-604	2	24	baljeet	baljeet	PROPN
eurjchem-604	2	25	singh	singh	PROPN
eurjchem-604	2	26	post	post	PROPN
eurjchem-604	2	27	graduate	graduate	PROPN
eurjchem-604	2	28	college	college	PROPN
eurjchem-604	2	29	,	,	PUNCT
eurjchem-604	2	30	anoopshahr	anoopshahr	PROPN
eurjchem-604	2	31	,	,	PUNCT
eurjchem-604	2	32	bulandshahr	bulandshahr	PROPN
eurjchem-604	2	33	,	,	PUNCT
eurjchem-604	2	34	uttar	uttar	PROPN
eurjchem-604	2	35	pradesh	pradesh	PROPN
eurjchem-604	2	36	,	,	PUNCT
eurjchem-604	2	37	202390	202390	NUM
eurjchem-604	2	38	,	,	PUNCT
eurjchem-604	2	39	india	india	PROPN
eurjchem-604	2	40	b	b	PROPN
eurjchem-604	2	41	department	department	PROPN
eurjchem-604	2	42	of	of	ADP
eurjchem-604	2	43	chemistry	chemistry	NOUN
eurjchem-604	2	44	,	,	PUNCT
eurjchem-604	2	45	mahanand	mahanand	NOUN
eurjchem-604	2	46	mission	mission	PROPN
eurjchem-604	2	47	harijan	harijan	PROPN
eurjchem-604	2	48	college	college	PROPN
eurjchem-604	2	49	,	,	PUNCT
eurjchem-604	2	50	ghaziabad	ghaziabad	PROPN
eurjchem-604	2	51	,	,	PUNCT
eurjchem-604	2	52	uttar	uttar	PROPN
eurjchem-604	2	53	pradesh	pradesh	PROPN
eurjchem-604	2	54	,	,	PUNCT
eurjchem-604	2	55	201001	201001	NUM
eurjchem-604	2	56	,	,	PUNCT
eurjchem-604	2	57	india	india	PROPN
eurjchem-604	2	58	*	*	PUNCT
eurjchem-604	2	59	corresponding	correspond	VERB
eurjchem-604	2	60	author	author	NOUN
eurjchem-604	2	61	at	at	ADP
eurjchem-604	2	62	:	:	PUNCT
eurjchem-604	2	63	department	department	NOUN
eurjchem-604	2	64	of	of	ADP
eurjchem-604	2	65	chemistry	chemistry	NOUN
eurjchem-604	2	66	,	,	PUNCT
eurjchem-604	2	67	durga	durga	PROPN
eurjchem-604	2	68	prasad	prasad	PROPN
eurjchem-604	2	69	baljeet	baljeet	PROPN
eurjchem-604	2	70	singh	singh	PROPN
eurjchem-604	2	71	post	post	PROPN
eurjchem-604	2	72	graduate	graduate	PROPN
eurjchem-604	2	73	college	college	PROPN
eurjchem-604	2	74	,	,	PUNCT
eurjchem-604	2	75	anoopshahr	anoopshahr	PROPN
eurjchem-604	2	76	,	,	PUNCT
eurjchem-604	2	77	bulandshahr	bulandshahr	PROPN
eurjchem-604	2	78	,	,	PUNCT
eurjchem-604	2	79	uttar	uttar	PROPN
eurjchem-604	2	80	pradesh	pradesh	PROPN
eurjchem-604	2	81	,	,	PUNCT
eurjchem-604	2	82	202390	202390	NUM
eurjchem-604	2	83	,	,	PUNCT
eurjchem-604	2	84	india	india	PROPN
eurjchem-604	2	85	.	.	PUNCT
eurjchem-604	3	1	tel	tel	PROPN
eurjchem-604	3	2	.	.	PUNCT
eurjchem-604	3	3	:	:	PUNCT
eurjchem-604	4	1	+91.120.2328234	+91.120.2328234	NUM
eurjchem-604	4	2	;	;	PUNCT
eurjchem-604	4	3	fax	fax	NOUN
eurjchem-604	4	4	:	:	PUNCT
eurjchem-604	4	5	+91.120.2320355	+91.120.2320355	NUM
eurjchem-604	4	6	.	.	PUNCT
eurjchem-604	4	7	e‐mail	e‐mail	PUNCT
eurjchem-604	4	8	address	address	NOUN
eurjchem-604	4	9	:	:	PUNCT
eurjchem-604	4	10	manish.kaushik@sify.com	manish.kaushik@sify.com	X
eurjchem-604	4	11	(	(	PUNCT
eurjchem-604	4	12	m.	m.	NOUN
eurjchem-604	4	13	kaushik	kaushik	PROPN
eurjchem-604	4	14	)	)	PUNCT
eurjchem-604	4	15	.	.	PUNCT
eurjchem-604	5	1	review	review	VERB
eurjchem-604	5	2	information	information	NOUN
eurjchem-604	5	3	abstract	abstract	ADJ
eurjchem-604	5	4	received	receive	VERB
eurjchem-604	5	5	:	:	PUNCT
eurjchem-604	5	6	28	28	NUM
eurjchem-604	5	7	february	february	NOUN
eurjchem-604	5	8	2012	2012	NUM
eurjchem-604	5	9	received	receive	VERB
eurjchem-604	5	10	in	in	ADP
eurjchem-604	5	11	revised	revise	VERB
eurjchem-604	5	12	form	form	NOUN
eurjchem-604	5	13	:	:	PUNCT
eurjchem-604	5	14	17	17	NUM
eurjchem-604	5	15	april	april	PROPN
eurjchem-604	5	16	2012	2012	NUM
eurjchem-604	5	17	accepted	accept	VERB
eurjchem-604	5	18	:	:	PUNCT
eurjchem-604	5	19	19	19	NUM
eurjchem-604	5	20	may	may	PROPN
eurjchem-604	5	21	2012	2012	NUM
eurjchem-604	5	22	online	online	NOUN
eurjchem-604	5	23	:	:	PUNCT
eurjchem-604	5	24	30	30	NUM
eurjchem-604	5	25	september	september	PROPN
eurjchem-604	5	26	2012	2012	NUM
eurjchem-604	5	27	keywords	keyword	VERB
eurjchem-604	5	28	the	the	DET
eurjchem-604	5	29	special	special	ADJ
eurjchem-604	5	30	interest	interest	NOUN
eurjchem-604	5	31	attached	attach	VERB
eurjchem-604	5	32	to	to	ADP
eurjchem-604	5	33	the	the	DET
eurjchem-604	5	34	chemistry	chemistry	NOUN
eurjchem-604	5	35	of	of	ADP
eurjchem-604	5	36	metal	metal	NOUN
eurjchem-604	5	37	carbonyls	carbonyls	NOUN
eurjchem-604	5	38	arises	arise	VERB
eurjchem-604	5	39	from	from	ADP
eurjchem-604	5	40	several	several	ADJ
eurjchem-604	5	41	causes	cause	NOUN
eurjchem-604	5	42	.	.	PUNCT
eurjchem-604	6	1	while	while	SCONJ
eurjchem-604	6	2	quite	quite	ADV
eurjchem-604	6	3	distinct	distinct	ADJ
eurjchem-604	6	4	from	from	ADP
eurjchem-604	6	5	the	the	DET
eurjchem-604	6	6	metal	metal	NOUN
eurjchem-604	6	7	carbonyls	carbonyls	NOUN
eurjchem-604	6	8	in	in	ADP
eurjchem-604	6	9	the	the	DET
eurjchem-604	6	10	organometallic	organometallic	ADJ
eurjchem-604	6	11	compounds	compound	NOUN
eurjchem-604	6	12	,	,	PUNCT
eurjchem-604	6	13	they	they	PRON
eurjchem-604	6	14	differ	differ	VERB
eurjchem-604	6	15	in	in	ADP
eurjchem-604	6	16	physical	physical	ADJ
eurjchem-604	6	17	properties	property	NOUN
eurjchem-604	6	18	(	(	PUNCT
eurjchem-604	6	19	e.g.	e.g.	ADV
eurjchem-604	6	20	,	,	PUNCT
eurjchem-604	6	21	their	their	PRON
eurjchem-604	6	22	volatility	volatility	NOUN
eurjchem-604	6	23	)	)	PUNCT
eurjchem-604	6	24	from	from	ADP
eurjchem-604	6	25	all	all	DET
eurjchem-604	6	26	other	other	ADJ
eurjchem-604	6	27	compounds	compound	NOUN
eurjchem-604	6	28	of	of	ADP
eurjchem-604	6	29	the	the	DET
eurjchem-604	6	30	transition	transition	NOUN
eurjchem-604	6	31	metals	metal	NOUN
eurjchem-604	6	32	.	.	PUNCT
eurjchem-604	7	1	chemically	chemically	ADV
eurjchem-604	7	2	,	,	PUNCT
eurjchem-604	7	3	they	they	PRON
eurjchem-604	7	4	constitute	constitute	VERB
eurjchem-604	7	5	a	a	DET
eurjchem-604	7	6	group	group	NOUN
eurjchem-604	7	7	of	of	ADP
eurjchem-604	7	8	compounds	compound	NOUN
eurjchem-604	7	9	in	in	ADP
eurjchem-604	7	10	which	which	PRON
eurjchem-604	7	11	the	the	DET
eurjchem-604	7	12	formal	formal	ADJ
eurjchem-604	7	13	valency	valency	NOUN
eurjchem-604	7	14	of	of	ADP
eurjchem-604	7	15	the	the	DET
eurjchem-604	7	16	metal	metal	NOUN
eurjchem-604	7	17	atoms	atom	NOUN
eurjchem-604	7	18	is	be	AUX
eurjchem-604	7	19	zero	zero	NUM
eurjchem-604	7	20	,	,	PUNCT
eurjchem-604	7	21	and	and	CCONJ
eurjchem-604	7	22	in	in	ADP
eurjchem-604	7	23	this	this	DET
eurjchem-604	7	24	respect	respect	NOUN
eurjchem-604	7	25	(	(	PUNCT
eurjchem-604	7	26	apart	apart	ADV
eurjchem-604	7	27	,	,	PUNCT
eurjchem-604	7	28	perhaps	perhaps	ADV
eurjchem-604	7	29	,	,	PUNCT
eurjchem-604	7	30	from	from	ADP
eurjchem-604	7	31	the	the	DET
eurjchem-604	7	32	ammoniates	ammoniate	NOUN
eurjchem-604	7	33	of	of	ADP
eurjchem-604	7	34	the	the	DET
eurjchem-604	7	35	alkali	alkali	ADJ
eurjchem-604	7	36	metals	metal	NOUN
eurjchem-604	7	37	)	)	PUNCT
eurjchem-604	7	38	they	they	PRON
eurjchem-604	7	39	are	be	AUX
eurjchem-604	7	40	comparable	comparable	ADJ
eurjchem-604	7	41	only	only	ADV
eurjchem-604	7	42	with	with	ADP
eurjchem-604	7	43	the	the	DET
eurjchem-604	7	44	recently	recently	ADV
eurjchem-604	7	45	discovered	discover	VERB
eurjchem-604	7	46	compounds	compound	NOUN
eurjchem-604	7	47	.	.	PUNCT
eurjchem-604	8	1	as	as	ADP
eurjchem-604	8	2	a	a	DET
eurjchem-604	8	3	class	class	NOUN
eurjchem-604	8	4	,	,	PUNCT
eurjchem-604	8	5	the	the	DET
eurjchem-604	8	6	carbonyls	carbonyls	NOUN
eurjchem-604	8	7	are	be	AUX
eurjchem-604	8	8	reactive	reactive	ADJ
eurjchem-604	8	9	compounds	compound	NOUN
eurjchem-604	8	10	,	,	PUNCT
eurjchem-604	8	11	and	and	CCONJ
eurjchem-604	8	12	a	a	DET
eurjchem-604	8	13	number	number	NOUN
eurjchem-604	8	14	of	of	ADP
eurjchem-604	8	15	new	new	ADJ
eurjchem-604	8	16	types	type	NOUN
eurjchem-604	8	17	of	of	ADP
eurjchem-604	8	18	inorganic	inorganic	ADJ
eurjchem-604	8	19	compounds	compound	NOUN
eurjchem-604	8	20	have	have	AUX
eurjchem-604	8	21	been	be	AUX
eurjchem-604	8	22	discovered	discover	VERB
eurjchem-604	8	23	.	.	PUNCT
eurjchem-604	9	1	in	in	ADP
eurjchem-604	9	2	the	the	DET
eurjchem-604	9	3	concepts	concept	NOUN
eurjchem-604	9	4	for	for	ADP
eurjchem-604	9	5	new	new	ADJ
eurjchem-604	9	6	products	product	NOUN
eurjchem-604	9	7	,	,	PUNCT
eurjchem-604	9	8	performance	performance	NOUN
eurjchem-604	9	9	,	,	PUNCT
eurjchem-604	9	10	product	product	NOUN
eurjchem-604	9	11	safety	safety	NOUN
eurjchem-604	9	12	,	,	PUNCT
eurjchem-604	9	13	and	and	CCONJ
eurjchem-604	9	14	product	product	NOUN
eurjchem-604	9	15	economy	economy	NOUN
eurjchem-604	9	16	criteria	criterion	NOUN
eurjchem-604	9	17	are	be	AUX
eurjchem-604	9	18	equally	equally	ADV
eurjchem-604	9	19	important	important	ADJ
eurjchem-604	9	20	.	.	PUNCT
eurjchem-604	10	1	they	they	PRON
eurjchem-604	10	2	are	be	AUX
eurjchem-604	10	3	taken	take	VERB
eurjchem-604	10	4	into	into	ADP
eurjchem-604	10	5	account	account	NOUN
eurjchem-604	10	6	already	already	ADV
eurjchem-604	10	7	when	when	SCONJ
eurjchem-604	10	8	the	the	DET
eurjchem-604	10	9	raw	raw	ADJ
eurjchem-604	10	10	material	material	NOUN
eurjchem-604	10	11	base	base	NOUN
eurjchem-604	10	12	for	for	ADP
eurjchem-604	10	13	a	a	DET
eurjchem-604	10	14	new	new	ADJ
eurjchem-604	10	15	industrial	industrial	ADJ
eurjchem-604	10	16	product	product	NOUN
eurjchem-604	10	17	development	development	NOUN
eurjchem-604	10	18	is	be	AUX
eurjchem-604	10	19	defined	define	VERB
eurjchem-604	10	20	.	.	PUNCT
eurjchem-604	11	1	since	since	SCONJ
eurjchem-604	11	2	the	the	DET
eurjchem-604	11	3	discovery	discovery	NOUN
eurjchem-604	11	4	of	of	ADP
eurjchem-604	11	5	nickel	nickel	NOUN
eurjchem-604	11	6	carbonyl	carbonyl	NOUN
eurjchem-604	11	7	by	by	ADP
eurjchem-604	11	8	mond	mond	NOUN
eurjchem-604	11	9	and	and	CCONJ
eurjchem-604	11	10	langer	langer	NOUN
eurjchem-604	11	11	in	in	ADP
eurjchem-604	11	12	1888	1888	NUM
eurjchem-604	11	13	,	,	PUNCT
eurjchem-604	11	14	the	the	DET
eurjchem-604	11	15	carbonyls	carbonyls	NOUN
eurjchem-604	11	16	of	of	ADP
eurjchem-604	11	17	the	the	DET
eurjchem-604	11	18	iron	iron	NOUN
eurjchem-604	11	19	group	group	NOUN
eurjchem-604	11	20	and	and	CCONJ
eurjchem-604	11	21	of	of	ADP
eurjchem-604	11	22	chromium	chromium	NOUN
eurjchem-604	11	23	,	,	PUNCT
eurjchem-604	11	24	molybdenum	molybdenum	NOUN
eurjchem-604	11	25	and	and	CCONJ
eurjchem-604	11	26	tungsten	tungsten	NOUN
eurjchem-604	11	27	have	have	AUX
eurjchem-604	11	28	found	find	VERB
eurjchem-604	11	29	important	important	ADJ
eurjchem-604	11	30	technical	technical	ADJ
eurjchem-604	11	31	applications	application	NOUN
eurjchem-604	11	32	,	,	PUNCT
eurjchem-604	11	33	e.g.	e.g.	ADV
eurjchem-604	11	34	,	,	PUNCT
eurjchem-604	11	35	in	in	ADP
eurjchem-604	11	36	the	the	DET
eurjchem-604	11	37	mond	mond	NOUN
eurjchem-604	11	38	nickel	nickel	NOUN
eurjchem-604	11	39	process	process	NOUN
eurjchem-604	11	40	,	,	PUNCT
eurjchem-604	11	41	and	and	CCONJ
eurjchem-604	11	42	for	for	ADP
eurjchem-604	11	43	the	the	DET
eurjchem-604	11	44	preparation	preparation	NOUN
eurjchem-604	11	45	of	of	ADP
eurjchem-604	11	46	the	the	DET
eurjchem-604	11	47	metals	metal	NOUN
eurjchem-604	11	48	in	in	ADP
eurjchem-604	11	49	a	a	DET
eurjchem-604	11	50	state	state	NOUN
eurjchem-604	11	51	of	of	ADP
eurjchem-604	11	52	subdivision	subdivision	NOUN
eurjchem-604	11	53	and	and	CCONJ
eurjchem-604	11	54	of	of	ADP
eurjchem-604	11	55	purity	purity	NOUN
eurjchem-604	11	56	suitable	suitable	ADJ
eurjchem-604	11	57	for	for	ADP
eurjchem-604	11	58	powder	powder	NOUN
eurjchem-604	11	59	metallurgy	metallurgy	NOUN
eurjchem-604	11	60	,	,	PUNCT
eurjchem-604	11	61	for	for	ADP
eurjchem-604	11	62	catalysts	catalyst	NOUN
eurjchem-604	11	63	,	,	PUNCT
eurjchem-604	11	64	etc	etc	X
eurjchem-604	11	65	.	.	X
eurjchem-604	12	1	the	the	DET
eurjchem-604	12	2	reaction	reaction	NOUN
eurjchem-604	12	3	mechanism	mechanism	NOUN
eurjchem-604	12	4	of	of	ADP
eurjchem-604	12	5	the	the	DET
eurjchem-604	12	6	processes	process	NOUN
eurjchem-604	12	7	developed	develop	VERB
eurjchem-604	12	8	for	for	ADP
eurjchem-604	12	9	producing	produce	VERB
eurjchem-604	12	10	the	the	DET
eurjchem-604	12	11	carbonyls	carbonyls	NOUN
eurjchem-604	12	12	technically	technically	ADV
eurjchem-604	12	13	has	have	AUX
eurjchem-604	12	14	only	only	ADV
eurjchem-604	12	15	recently	recently	ADV
eurjchem-604	12	16	received	receive	VERB
eurjchem-604	12	17	its	its	PRON
eurjchem-604	12	18	interpretations	interpretation	NOUN
eurjchem-604	12	19	.	.	PUNCT
eurjchem-604	13	1	within	within	ADP
eurjchem-604	13	2	the	the	DET
eurjchem-604	13	3	space	space	NOUN
eurjchem-604	13	4	of	of	ADP
eurjchem-604	13	5	review	review	NOUN
eurjchem-604	13	6	it	it	PRON
eurjchem-604	13	7	is	be	AUX
eurjchem-604	13	8	necessary	necessary	ADJ
eurjchem-604	13	9	to	to	PART
eurjchem-604	13	10	limit	limit	VERB
eurjchem-604	13	11	discussion	discussion	NOUN
eurjchem-604	13	12	to	to	ADP
eurjchem-604	13	13	a	a	DET
eurjchem-604	13	14	few	few	ADJ
eurjchem-604	13	15	topics	topic	NOUN
eurjchem-604	13	16	.	.	PUNCT
eurjchem-604	14	1	particular	particular	ADJ
eurjchem-604	14	2	stress	stress	NOUN
eurjchem-604	14	3	has	have	AUX
eurjchem-604	14	4	accordingly	accordingly	ADV
eurjchem-604	14	5	laid	lay	VERB
eurjchem-604	14	6	upon	upon	SCONJ
eurjchem-604	14	7	(	(	PUNCT
eurjchem-604	14	8	a	a	X
eurjchem-604	14	9	)	)	PUNCT
eurjchem-604	14	10	the	the	DET
eurjchem-604	14	11	chemical	chemical	NOUN
eurjchem-604	14	12	bonding	bonding	NOUN
eurjchem-604	14	13	in	in	ADP
eurjchem-604	14	14	metal	metal	NOUN
eurjchem-604	14	15	carbonyls	carbonyls	NOUN
eurjchem-604	14	16	,	,	PUNCT
eurjchem-604	14	17	(	(	PUNCT
eurjchem-604	14	18	b	b	X
eurjchem-604	14	19	)	)	PUNCT
eurjchem-604	14	20	importance	importance	NOUN
eurjchem-604	14	21	of	of	ADP
eurjchem-604	14	22	ir	ir	PROPN
eurjchem-604	14	23	and	and	CCONJ
eurjchem-604	14	24	nmr	nmr	NOUN
eurjchem-604	14	25	spectroscopy	spectroscopy	VERB
eurjchem-604	14	26	in	in	ADP
eurjchem-604	14	27	characterization	characterization	NOUN
eurjchem-604	14	28	of	of	ADP
eurjchem-604	14	29	metal	metal	NOUN
eurjchem-604	14	30	carbonyls	carbonyl	VERB
eurjchem-604	14	31	,	,	PUNCT
eurjchem-604	14	32	(	(	PUNCT
eurjchem-604	14	33	c	c	NOUN
eurjchem-604	14	34	)	)	PUNCT
eurjchem-604	14	35	substitution	substitution	NOUN
eurjchem-604	14	36	reactions	reaction	NOUN
eurjchem-604	14	37	of	of	ADP
eurjchem-604	14	38	g‐vib	g‐vib	PROPN
eurjchem-604	14	39	metal	metal	NOUN
eurjchem-604	14	40	carbonyls	carbonyl	VERB
eurjchem-604	14	41	,	,	PUNCT
eurjchem-604	14	42	(	(	PUNCT
eurjchem-604	14	43	d	d	X
eurjchem-604	14	44	)	)	PUNCT
eurjchem-604	14	45	kinetics	kinetic	NOUN
eurjchem-604	14	46	and	and	CCONJ
eurjchem-604	14	47	mechanism	mechanism	NOUN
eurjchem-604	14	48	of	of	ADP
eurjchem-604	14	49	substitution	substitution	NOUN
eurjchem-604	14	50	reactions	reaction	NOUN
eurjchem-604	14	51	in	in	ADP
eurjchem-604	14	52	metal	metal	NOUN
eurjchem-604	14	53	carbonyls	carbonyls	NOUN
eurjchem-604	14	54	,	,	PUNCT
eurjchem-604	14	55	(	(	PUNCT
eurjchem-604	14	56	e	e	NOUN
eurjchem-604	14	57	)	)	PUNCT
eurjchem-604	14	58	substituted	substitute	VERB
eurjchem-604	14	59	complexes	complex	NOUN
eurjchem-604	14	60	of	of	ADP
eurjchem-604	14	61	g‐vib	g‐vib	ADJ
eurjchem-604	14	62	metal	metal	NOUN
eurjchem-604	14	63	carbonyl	carbonyl	NOUN
eurjchem-604	14	64	,	,	PUNCT
eurjchem-604	14	65	(	(	PUNCT
eurjchem-604	14	66	f	f	X
eurjchem-604	14	67	)	)	PUNCT
eurjchem-604	14	68	chelate	chelate	NOUN
eurjchem-604	14	69	complexes	complex	NOUN
eurjchem-604	14	70	of	of	ADP
eurjchem-604	14	71	g‐vib	g‐vib	ADJ
eurjchem-604	14	72	metal	metal	NOUN
eurjchem-604	14	73	carbonyls	carbonyl	VERB
eurjchem-604	14	74	,	,	PUNCT
eurjchem-604	14	75	(	(	PUNCT
eurjchem-604	14	76	g	g	NOUN
eurjchem-604	14	77	)	)	PUNCT
eurjchem-604	14	78	uses	use	NOUN
eurjchem-604	14	79	of	of	ADP
eurjchem-604	14	80	g‐vib	g‐vib	ADJ
eurjchem-604	14	81	metal	metal	NOUN
eurjchem-604	14	82	carbonyl	carbonyl	NOUN
eurjchem-604	14	83	complexes	complex	NOUN
eurjchem-604	14	84	and	and	CCONJ
eurjchem-604	14	85	(	(	PUNCT
eurjchem-604	14	86	h	h	NOUN
eurjchem-604	14	87	)	)	PUNCT
eurjchem-604	14	88	studies	study	NOUN
eurjchem-604	14	89	done	do	VERB
eurjchem-604	14	90	on	on	ADP
eurjchem-604	14	91	g‐vib	g‐vib	PROPN
eurjchem-604	14	92	metal	metal	NOUN
eurjchem-604	14	93	carbonyls	carbonyls	NOUN
eurjchem-604	14	94	.	.	PUNCT
eurjchem-604	15	1	complexes	complex	NOUN
eurjchem-604	15	2	metal	metal	NOUN
eurjchem-604	15	3	carbonyl	carbonyl	NOUN
eurjchem-604	15	4	complexation	complexation	NOUN
eurjchem-604	15	5	agents	agent	NOUN
eurjchem-604	15	6	homonuclear	homonuclear	VERB
eurjchem-604	15	7	clusters	cluster	NOUN
eurjchem-604	15	8	substitution	substitution	NOUN
eurjchem-604	15	9	reactions	reaction	NOUN
eurjchem-604	15	10	heteronuclear	heteronuclear	VERB
eurjchem-604	15	11	clusters	cluster	NOUN
eurjchem-604	15	12	1	1	NUM
eurjchem-604	15	13	.	.	PUNCT
eurjchem-604	16	1	introduction	introduction	NOUN
eurjchem-604	16	2	binary	binary	ADJ
eurjchem-604	16	3	metal	metal	NOUN
eurjchem-604	16	4	carbonyl	carbonyl	NOUN
eurjchem-604	16	5	compounds	compound	NOUN
eurjchem-604	16	6	that	that	PRON
eurjchem-604	16	7	consist	consist	VERB
eurjchem-604	16	8	only	only	ADV
eurjchem-604	16	9	of	of	ADP
eurjchem-604	16	10	a	a	DET
eurjchem-604	16	11	metal	metal	NOUN
eurjchem-604	16	12	and	and	CCONJ
eurjchem-604	16	13	carbon	carbon	NOUN
eurjchem-604	16	14	monoxide	monoxide	NOUN
eurjchem-604	16	15	(	(	PUNCT
eurjchem-604	16	16	co	co	NOUN
eurjchem-604	16	17	)	)	PUNCT
eurjchem-604	16	18	ligands	ligand	NOUN
eurjchem-604	16	19	are	be	AUX
eurjchem-604	16	20	usually	usually	ADV
eurjchem-604	16	21	prepared	prepare	VERB
eurjchem-604	16	22	by	by	ADP
eurjchem-604	16	23	direct	direct	ADJ
eurjchem-604	16	24	reaction	reaction	NOUN
eurjchem-604	16	25	of	of	ADP
eurjchem-604	16	26	the	the	DET
eurjchem-604	16	27	powder	powder	NOUN
eurjchem-604	16	28	of	of	ADP
eurjchem-604	16	29	a	a	DET
eurjchem-604	16	30	highly	highly	ADV
eurjchem-604	16	31	reactive	reactive	ADJ
eurjchem-604	16	32	metal	metal	NOUN
eurjchem-604	16	33	and	and	CCONJ
eurjchem-604	16	34	carbon	carbon	NOUN
eurjchem-604	16	35	monoxide	monoxide	NOUN
eurjchem-604	16	36	,	,	PUNCT
eurjchem-604	16	37	or	or	CCONJ
eurjchem-604	16	38	by	by	ADP
eurjchem-604	16	39	the	the	DET
eurjchem-604	16	40	reduction	reduction	NOUN
eurjchem-604	16	41	of	of	ADP
eurjchem-604	16	42	a	a	DET
eurjchem-604	16	43	metal	metal	NOUN
eurjchem-604	16	44	salt	salt	NOUN
eurjchem-604	16	45	to	to	ADP
eurjchem-604	16	46	zero	zero	NUM
eurjchem-604	16	47	valance	valance	NOUN
eurjchem-604	16	48	followed	follow	VERB
eurjchem-604	16	49	by	by	ADP
eurjchem-604	16	50	reaction	reaction	NOUN
eurjchem-604	16	51	with	with	ADP
eurjchem-604	16	52	high‐pressure	high‐pressure	NOUN
eurjchem-604	16	53	carbon	carbon	NOUN
eurjchem-604	16	54	monoxide	monoxide	NOUN
eurjchem-604	16	55	.	.	PUNCT
eurjchem-604	17	1	however	however	ADV
eurjchem-604	17	2	,	,	PUNCT
eurjchem-604	17	3	tetracarbonyl	tetracarbonyl	VERB
eurjchem-604	17	4	nickel	nickel	NOUN
eurjchem-604	17	5	first	first	ADV
eurjchem-604	17	6	discovered	discover	VERB
eurjchem-604	17	7	at	at	ADP
eurjchem-604	17	8	the	the	DET
eurjchem-604	17	9	end	end	NOUN
eurjchem-604	17	10	of	of	ADP
eurjchem-604	17	11	the	the	DET
eurjchem-604	17	12	19thcentury	19thcentury	NUM
eurjchem-604	17	13	,	,	PUNCT
eurjchem-604	17	14	forms	form	NOUN
eurjchem-604	17	15	by	by	ADP
eurjchem-604	17	16	the	the	DET
eurjchem-604	17	17	reaction	reaction	NOUN
eurjchem-604	17	18	of	of	ADP
eurjchem-604	17	19	nickel	nickel	NOUN
eurjchem-604	17	20	metal	metal	NOUN
eurjchem-604	17	21	and	and	CCONJ
eurjchem-604	17	22	carbon	carbon	NOUN
eurjchem-604	17	23	monoxide	monoxide	NOUN
eurjchem-604	17	24	under	under	ADP
eurjchem-604	17	25	atmospheric	atmospheric	ADJ
eurjchem-604	17	26	pressure	pressure	NOUN
eurjchem-604	17	27	and	and	CCONJ
eurjchem-604	17	28	at	at	ADP
eurjchem-604	17	29	room	room	NOUN
eurjchem-604	17	30	temperature	temperature	NOUN
eurjchem-604	17	31	.	.	PUNCT
eurjchem-604	18	1	the	the	DET
eurjchem-604	18	2	preparation	preparation	NOUN
eurjchem-604	18	3	of	of	ADP
eurjchem-604	18	4	other	other	ADJ
eurjchem-604	18	5	metal	metal	NOUN
eurjchem-604	18	6	carbonyl	carbonyl	NOUN
eurjchem-604	18	7	compounds	compound	NOUN
eurjchem-604	18	8	,	,	PUNCT
eurjchem-604	18	9	on	on	ADP
eurjchem-604	18	10	the	the	DET
eurjchem-604	18	11	other	other	ADJ
eurjchem-604	18	12	hand	hand	NOUN
eurjchem-604	18	13	,	,	PUNCT
eurjchem-604	18	14	requires	require	VERB
eurjchem-604	18	15	high	high	ADJ
eurjchem-604	18	16	temperatures	temperature	NOUN
eurjchem-604	18	17	and	and	CCONJ
eurjchem-604	18	18	high	high	ADJ
eurjchem-604	18	19	pressures	pressure	NOUN
eurjchem-604	18	20	.	.	PUNCT
eurjchem-604	19	1	carbonyl	carbonyl	NOUN
eurjchem-604	19	2	groups	group	NOUN
eurjchem-604	19	3	are	be	AUX
eurjchem-604	19	4	the	the	DET
eurjchem-604	19	5	functional	functional	ADJ
eurjchem-604	19	6	group	group	NOUN
eurjchem-604	19	7	consisting	consist	VERB
eurjchem-604	19	8	of	of	ADP
eurjchem-604	19	9	a	a	DET
eurjchem-604	19	10	carbon	carbon	NOUN
eurjchem-604	19	11	atom	atom	NOUN
eurjchem-604	19	12	bonded	bond	VERB
eurjchem-604	19	13	to	to	ADP
eurjchem-604	19	14	an	an	DET
eurjchem-604	19	15	oxygen	oxygen	NOUN
eurjchem-604	19	16	atom	atom	NOUN
eurjchem-604	19	17	through	through	ADP
eurjchem-604	19	18	a	a	DET
eurjchem-604	19	19	double	double	ADJ
eurjchem-604	19	20	bond	bond	NOUN
eurjchem-604	19	21	.	.	PUNCT
eurjchem-604	20	1	in	in	ADP
eurjchem-604	20	2	certain	certain	ADJ
eurjchem-604	20	3	other	other	ADJ
eurjchem-604	20	4	carbonyl	carbonyl	NOUN
eurjchem-604	20	5	compounds	compound	NOUN
eurjchem-604	20	6	,	,	PUNCT
eurjchem-604	20	7	where	where	SCONJ
eurjchem-604	20	8	carbon	carbon	NOUN
eurjchem-604	20	9	monoxide	monoxide	NOUN
eurjchem-604	20	10	functions	function	NOUN
eurjchem-604	20	11	as	as	ADP
eurjchem-604	20	12	a	a	DET
eurjchem-604	20	13	ligand	ligand	NOUN
eurjchem-604	20	14	in	in	ADP
eurjchem-604	20	15	some	some	DET
eurjchem-604	20	16	inorganic	inorganic	ADJ
eurjchem-604	20	17	and	and	CCONJ
eurjchem-604	20	18	organometallic	organometallic	ADJ
eurjchem-604	20	19	complexes	complex	NOUN
eurjchem-604	20	20	,	,	PUNCT
eurjchem-604	20	21	carbon	carbon	NOUN
eurjchem-604	20	22	is	be	AUX
eurjchem-604	20	23	bonded	bond	VERB
eurjchem-604	20	24	to	to	PART
eurjchem-604	20	25	oxygen	oxygen	VERB
eurjchem-604	20	26	through	through	ADP
eurjchem-604	20	27	a	a	DET
eurjchem-604	20	28	triple	triple	ADJ
eurjchem-604	20	29	bond	bond	NOUN
eurjchem-604	20	30	(	(	PUNCT
eurjchem-604	20	31	c≡o	c≡o	PROPN
eurjchem-604	20	32	)	)	PUNCT
eurjchem-604	20	33	.	.	PUNCT
eurjchem-604	21	1	in	in	ADP
eurjchem-604	21	2	metal	metal	NOUN
eurjchem-604	21	3	carbonyl	carbonyl	NOUN
eurjchem-604	21	4	a	a	DET
eurjchem-604	21	5	transition	transition	NOUN
eurjchem-604	21	6	metal	metal	NOUN
eurjchem-604	21	7	is	be	AUX
eurjchem-604	21	8	bonded	bond	VERB
eurjchem-604	21	9	to	to	AUX
eurjchem-604	21	10	co.	co.	PROPN
eurjchem-604	21	11	elements	element	NOUN
eurjchem-604	21	12	from	from	ADP
eurjchem-604	21	13	d‐block	d‐block	PUNCT
eurjchem-604	21	14	of	of	ADP
eurjchem-604	21	15	the	the	DET
eurjchem-604	21	16	periodic	periodic	ADJ
eurjchem-604	21	17	table	table	NOUN
eurjchem-604	21	18	are	be	AUX
eurjchem-604	21	19	usually	usually	ADV
eurjchem-604	21	20	referred	refer	VERB
eurjchem-604	21	21	to	to	ADP
eurjchem-604	21	22	as	as	ADP
eurjchem-604	21	23	transition	transition	NOUN
eurjchem-604	21	24	metals	metal	NOUN
eurjchem-604	21	25	as	as	SCONJ
eurjchem-604	21	26	they	they	PRON
eurjchem-604	21	27	contain	contain	VERB
eurjchem-604	21	28	an	an	DET
eurjchem-604	21	29	incomplete	incomplete	ADJ
eurjchem-604	21	30	d	d	NOUN
eurjchem-604	21	31	sub‐	sub‐	ADJ
eurjchem-604	21	32	shell	shell	ADJ
eurjchem-604	21	33	.	.	PUNCT
eurjchem-604	22	1	co	co	PUNCT
eurjchem-604	22	2	forms	form	VERB
eurjchem-604	22	3	bonds	bond	NOUN
eurjchem-604	22	4	with	with	ADP
eurjchem-604	22	5	metal	metal	NOUN
eurjchem-604	22	6	ions	ion	NOUN
eurjchem-604	22	7	through	through	ADP
eurjchem-604	22	8	π‐backbonding	π‐backbonde	VERB
eurjchem-604	22	9	.	.	PUNCT
eurjchem-604	23	1	metal	metal	NOUN
eurjchem-604	23	2	carbonyls	carbonyl	NOUN
eurjchem-604	23	3	are	be	AUX
eurjchem-604	23	4	most	most	ADJ
eurjchem-604	23	5	of	of	ADP
eurjchem-604	23	6	the	the	DET
eurjchem-604	23	7	times	time	NOUN
eurjchem-604	23	8	non‐polar	non‐polar	ADJ
eurjchem-604	23	9	and	and	CCONJ
eurjchem-604	23	10	electrically	electrically	ADV
eurjchem-604	23	11	neutral	neutral	ADJ
eurjchem-604	23	12	compounds	compound	NOUN
eurjchem-604	23	13	and	and	CCONJ
eurjchem-604	23	14	demonstrates	demonstrate	VERB
eurjchem-604	23	15	physical	physical	ADJ
eurjchem-604	23	16	properties	property	NOUN
eurjchem-604	23	17	of	of	ADP
eurjchem-604	23	18	organic	organic	ADJ
eurjchem-604	23	19	compounds	compound	NOUN
eurjchem-604	23	20	.	.	PUNCT
eurjchem-604	24	1	the	the	DET
eurjchem-604	24	2	general	general	ADJ
eurjchem-604	24	3	formula	formula	NOUN
eurjchem-604	24	4	of	of	ADP
eurjchem-604	24	5	metal	metal	NOUN
eurjchem-604	24	6	carbonyls	carbonyls	NOUN
eurjchem-604	24	7	is	be	AUX
eurjchem-604	24	8	mx(co)y	mx(co)y	PROPN
eurjchem-604	24	9	.	.	PUNCT
eurjchem-604	25	1	these	these	DET
eurjchem-604	25	2	complexes	complex	NOUN
eurjchem-604	25	3	may	may	AUX
eurjchem-604	25	4	be	be	AUX
eurjchem-604	25	5	homoleptic	homoleptic	ADJ
eurjchem-604	25	6	,	,	PUNCT
eurjchem-604	25	7	that	that	PRON
eurjchem-604	25	8	is	be	AUX
eurjchem-604	25	9	containing	contain	VERB
eurjchem-604	25	10	only	only	ADV
eurjchem-604	25	11	co	co	NOUN
eurjchem-604	25	12	ligands	ligand	NOUN
eurjchem-604	25	13	,	,	PUNCT
eurjchem-604	25	14	such	such	ADJ
eurjchem-604	25	15	as	as	ADP
eurjchem-604	25	16	nickel	nickel	NOUN
eurjchem-604	25	17	carbonyl	carbonyl	NOUN
eurjchem-604	25	18	(	(	PUNCT
eurjchem-604	25	19	ni(co)4	ni(co)4	ADV
eurjchem-604	25	20	)	)	PUNCT
eurjchem-604	25	21	,	,	PUNCT
eurjchem-604	25	22	but	but	CCONJ
eurjchem-604	25	23	more	more	ADV
eurjchem-604	25	24	commonly	commonly	ADV
eurjchem-604	25	25	metal	metal	NOUN
eurjchem-604	25	26	carbonyls	carbonyl	NOUN
eurjchem-604	25	27	contain	contain	VERB
eurjchem-604	25	28	a	a	DET
eurjchem-604	25	29	mix	mix	NOUN
eurjchem-604	25	30	of	of	ADP
eurjchem-604	25	31	ligands	ligand	NOUN
eurjchem-604	25	32	,	,	PUNCT
eurjchem-604	25	33	such	such	ADJ
eurjchem-604	25	34	as	as	ADP
eurjchem-604	25	35	re(co)3(2,2'‐bipyridine)cl	re(co)3(2,2'‐bipyridine)cl	NOUN
eurjchem-604	25	36	.	.	PROPN
eurjchem-604	25	37	carbon	carbon	NOUN
eurjchem-604	25	38	monoxide	monoxide	NOUN
eurjchem-604	25	39	is	be	AUX
eurjchem-604	25	40	an	an	DET
eurjchem-604	25	41	important	important	ADJ
eurjchem-604	25	42	building	building	NOUN
eurjchem-604	25	43	block	block	NOUN
eurjchem-604	25	44	for	for	ADP
eurjchem-604	25	45	the	the	DET
eurjchem-604	25	46	synthesis	synthesis	NOUN
eurjchem-604	25	47	of	of	ADP
eurjchem-604	25	48	many	many	ADJ
eurjchem-604	25	49	compounds	compound	NOUN
eurjchem-604	25	50	,	,	PUNCT
eurjchem-604	25	51	for	for	ADP
eurjchem-604	25	52	example	example	NOUN
eurjchem-604	25	53	hydro	hydro	NOUN
eurjchem-604	25	54	formylation	formylation	NOUN
eurjchem-604	25	55	,	,	PUNCT
eurjchem-604	25	56	and	and	CCONJ
eurjchem-604	25	57	metal	metal	NOUN
eurjchem-604	25	58	carbonyl	carbonyl	NOUN
eurjchem-604	25	59	catalysts	catalyst	NOUN
eurjchem-604	25	60	are	be	AUX
eurjchem-604	25	61	central	central	ADJ
eurjchem-604	25	62	to	to	ADP
eurjchem-604	25	63	its	its	PRON
eurjchem-604	25	64	utilization	utilization	NOUN
eurjchem-604	25	65	.	.	PUNCT
eurjchem-604	26	1	metal	metal	NOUN
eurjchem-604	26	2	carbonyls	carbonyl	NOUN
eurjchem-604	26	3	are	be	AUX
eurjchem-604	26	4	toxic	toxic	ADJ
eurjchem-604	26	5	,	,	PUNCT
eurjchem-604	26	6	in	in	ADP
eurjchem-604	26	7	part	part	NOUN
eurjchem-604	26	8	because	because	SCONJ
eurjchem-604	26	9	of	of	ADP
eurjchem-604	26	10	their	their	PRON
eurjchem-604	26	11	ability	ability	NOUN
eurjchem-604	26	12	to	to	PART
eurjchem-604	26	13	carbonylate	carbonylate	VERB
eurjchem-604	26	14	hemoglobin	hemoglobin	NOUN
eurjchem-604	26	15	to	to	PART
eurjchem-604	26	16	give	give	VERB
eurjchem-604	26	17	carboxy	carboxy	ADJ
eurjchem-604	26	18	hemoglobin	hemoglobin	NOUN
eurjchem-604	26	19	,	,	PUNCT
eurjchem-604	26	20	which	which	PRON
eurjchem-604	26	21	will	will	AUX
eurjchem-604	26	22	not	not	PART
eurjchem-604	26	23	bind	bind	VERB
eurjchem-604	26	24	o2	o2	PROPN
eurjchem-604	26	25	[	[	X
eurjchem-604	26	26	1	1	NUM
eurjchem-604	26	27	]	]	PUNCT
eurjchem-604	26	28	.	.	PUNCT
eurjchem-604	27	1	most	most	ADJ
eurjchem-604	27	2	of	of	ADP
eurjchem-604	27	3	metal	metal	NOUN
eurjchem-604	27	4	carbonyls	carbonyl	NOUN
eurjchem-604	27	5	are	be	AUX
eurjchem-604	27	6	solid	solid	ADJ
eurjchem-604	27	7	at	at	ADP
eurjchem-604	27	8	ordinary	ordinary	ADJ
eurjchem-604	27	9	temperatures	temperature	NOUN
eurjchem-604	27	10	,	,	PUNCT
eurjchem-604	27	11	but	but	CCONJ
eurjchem-604	27	12	nickel	nickel	NOUN
eurjchem-604	27	13	carbonyl	carbonyl	NOUN
eurjchem-604	27	14	,	,	PUNCT
eurjchem-604	27	15	iron	iron	NOUN
eurjchem-604	27	16	pentacarbonyl	pentacarbonyl	NOUN
eurjchem-604	27	17	and	and	CCONJ
eurjchem-604	27	18	ruthenium	ruthenium	NOUN
eurjchem-604	27	19	pantacarbonyls	pantacarbonyls	NOUN
eurjchem-604	27	20	are	be	AUX
eurjchem-604	27	21	liquid	liquid	ADJ
eurjchem-604	27	22	,	,	PUNCT
eurjchem-604	27	23	and	and	CCONJ
eurjchem-604	27	24	cobalt	cobalt	NOUN
eurjchem-604	27	25	hydrocarbonyl	hydrocarbonyl	NOUN
eurjchem-604	27	26	is	be	AUX
eurjchem-604	27	27	gas	gas	NOUN
eurjchem-604	27	28	.	.	PUNCT
eurjchem-604	28	1	most	most	ADJ
eurjchem-604	28	2	metal	metal	NOUN
eurjchem-604	28	3	carbonyl	carbonyl	NOUN
eurjchem-604	28	4	reacts	react	VERB
eurjchem-604	28	5	vigorously	vigorously	ADV
eurjchem-604	28	6	with	with	ADP
eurjchem-604	28	7	oxygen	oxygen	NOUN
eurjchem-604	28	8	and	and	CCONJ
eurjchem-604	28	9	oxidizing	oxidize	VERB
eurjchem-604	28	10	substances	substance	NOUN
eurjchem-604	28	11	,	,	PUNCT
eurjchem-604	28	12	and	and	CCONJ
eurjchem-604	28	13	some	some	PRON
eurjchem-604	28	14	ignite	ignite	VERB
eurjchem-604	28	15	spontaneously	spontaneously	ADV
eurjchem-604	28	16	.	.	PUNCT
eurjchem-604	29	1	metal	metal	NOUN
eurjchem-604	29	2	carbonyls	carbonyls	NOUN
eurjchem-604	29	3	include	include	VERB
eurjchem-604	29	4	solubility	solubility	NOUN
eurjchem-604	29	5	in	in	ADP
eurjchem-604	29	6	only	only	ADJ
eurjchem-604	29	7	organic	organic	ADJ
eurjchem-604	29	8	solvent	solvent	NOUN
eurjchem-604	29	9	but	but	CCONJ
eurjchem-604	29	10	have	have	VERB
eurjchem-604	29	11	poor	poor	ADJ
eurjchem-604	29	12	solubility	solubility	NOUN
eurjchem-604	29	13	with	with	ADP
eurjchem-604	29	14	water	water	NOUN
eurjchem-604	29	15	,	,	PUNCT
eurjchem-604	29	16	highly	highly	ADV
eurjchem-604	29	17	toxic	toxic	ADJ
eurjchem-604	29	18	nature	nature	NOUN
eurjchem-604	29	19	,	,	PUNCT
eurjchem-604	29	20	volatile	volatile	ADJ
eurjchem-604	29	21	solid	solid	ADJ
eurjchem-604	29	22	or	or	CCONJ
eurjchem-604	29	23	liquid	liquid	ADJ
eurjchem-604	29	24	appearance	appearance	NOUN
eurjchem-604	29	25	at	at	ADP
eurjchem-604	29	26	room	room	NOUN
eurjchem-604	29	27	temperature	temperature	NOUN
eurjchem-604	29	28	.	.	PUNCT
eurjchem-604	30	1	1.1	1.1	NUM
eurjchem-604	30	2	.	.	PUNCT
eurjchem-604	31	1	bonding	bonding	NOUN
eurjchem-604	31	2	in	in	ADP
eurjchem-604	31	3	metal	metal	NOUN
eurjchem-604	31	4	carbonyls	carbonyls	NOUN
eurjchem-604	31	5	a	a	DET
eurjchem-604	31	6	simple	simple	ADJ
eurjchem-604	31	7	molecular	molecular	ADJ
eurjchem-604	31	8	orbital	orbital	ADJ
eurjchem-604	31	9	(	(	PUNCT
eurjchem-604	31	10	mo	mo	NOUN
eurjchem-604	31	11	)	)	PUNCT
eurjchem-604	31	12	diagram	diagram	NOUN
eurjchem-604	31	13	for	for	ADP
eurjchem-604	31	14	co	co	NOUN
eurjchem-604	31	15	is	be	AUX
eurjchem-604	31	16	shown	show	VERB
eurjchem-604	31	17	below	below	ADV
eurjchem-604	31	18	(	(	PUNCT
eurjchem-604	31	19	figure	figure	NOUN
eurjchem-604	31	20	1	1	NUM
eurjchem-604	31	21	)	)	PUNCT
eurjchem-604	31	22	.	.	PUNCT
eurjchem-604	32	1	the	the	DET
eurjchem-604	32	2	highest	high	ADJ
eurjchem-604	32	3	occupied	occupy	VERB
eurjchem-604	32	4	molecular	molecular	ADJ
eurjchem-604	32	5	orbital	orbital	ADJ
eurjchem-604	32	6	(	(	PUNCT
eurjchem-604	32	7	homo	homo	NOUN
eurjchem-604	32	8	)	)	PUNCT
eurjchem-604	32	9	is	be	AUX
eurjchem-604	32	10	indicated	indicate	VERB
eurjchem-604	32	11	by	by	ADP
eurjchem-604	32	12	the	the	DET
eurjchem-604	32	13	pair	pair	NOUN
eurjchem-604	32	14	of	of	ADP
eurjchem-604	32	15	electrons	electron	NOUN
eurjchem-604	32	16	.	.	PUNCT
eurjchem-604	33	1	this	this	PRON
eurjchem-604	33	2	is	be	AUX
eurjchem-604	33	3	the	the	DET
eurjchem-604	33	4	5σ	5σ	ADJ
eurjchem-604	33	5	lone	lone	ADJ
eurjchem-604	33	6	pair	pair	NOUN
eurjchem-604	33	7	orbital	orbital	NOUN
eurjchem-604	33	8	mainly	mainly	ADV
eurjchem-604	33	9	centered	center	VERB
eurjchem-604	33	10	on	on	ADP
eurjchem-604	33	11	the	the	DET
eurjchem-604	33	12	carbon	carbon	NOUN
eurjchem-604	33	13	and	and	CCONJ
eurjchem-604	33	14	weakly	weakly	ADJ
eurjchem-604	33	15	anti	anti	ADJ
eurjchem-604	33	16	bonding	bonding	NOUN
eurjchem-604	33	17	with	with	ADP
eurjchem-604	33	18	respect	respect	NOUN
eurjchem-604	33	19	to	to	ADP
eurjchem-604	33	20	the	the	DET
eurjchem-604	33	21	c‐o	c‐o	PROPN
eurjchem-604	33	22	bond	bond	NOUN
eurjchem-604	33	23	.	.	PUNCT
eurjchem-604	34	1	retracted	retract	VERB
eurjchem-604	34	2	368	368	NUM
eurjchem-604	34	3	kaushik	kaushik	NOUN
eurjchem-604	34	4	et	et	PROPN
eurjchem-604	34	5	al	al	PROPN
eurjchem-604	34	6	.	.	PUNCT
eurjchem-604	34	7	/	/	SYM
eurjchem-604	34	8	european	european	PROPN
eurjchem-604	34	9	journal	journal	PROPN
eurjchem-604	34	10	of	of	ADP
eurjchem-604	34	11	chemistry	chemistry	NOUN
eurjchem-604	34	12	3	3	NUM
eurjchem-604	34	13	(	(	PUNCT
eurjchem-604	34	14	3	3	NUM
eurjchem-604	34	15	)	)	PUNCT
eurjchem-604	34	16	(	(	PUNCT
eurjchem-604	34	17	2012	2012	NUM
eurjchem-604	34	18	)	)	PUNCT
eurjchem-604	34	19	367‐394	367‐394	NUM
eurjchem-604	34	20	figure	figure	NOUN
eurjchem-604	34	21	1	1	NUM
eurjchem-604	34	22	.	.	X
eurjchem-604	35	1	molecular	molecular	ADJ
eurjchem-604	35	2	orbital	orbital	ADJ
eurjchem-604	35	3	diagram	diagram	NOUN
eurjchem-604	35	4	of	of	ADP
eurjchem-604	35	5	co.	co.	PROPN
eurjchem-604	35	6	figure	figure	NOUN
eurjchem-604	35	7	2	2	NUM
eurjchem-604	35	8	.	.	PUNCT
eurjchem-604	35	9	π*‐acceptor	π*‐acceptor	NOUN
eurjchem-604	35	10	orbitals	orbital	NOUN
eurjchem-604	35	11	on	on	ADP
eurjchem-604	35	12	carbonyl	carbonyl	NOUN
eurjchem-604	35	13	.	.	PUNCT
eurjchem-604	36	1	the	the	DET
eurjchem-604	36	2	weak	weak	ADJ
eurjchem-604	36	3	c‐o	c‐o	NOUN
eurjchem-604	36	4	antibonding	antibonde	VERB
eurjchem-604	36	5	nature	nature	NOUN
eurjchem-604	36	6	of	of	ADP
eurjchem-604	36	7	this	this	DET
eurjchem-604	36	8	mo	mo	NOUN
eurjchem-604	36	9	,	,	PUNCT
eurjchem-604	36	10	however	however	ADV
eurjchem-604	36	11	,	,	PUNCT
eurjchem-604	36	12	is	be	AUX
eurjchem-604	36	13	clearly	clearly	ADV
eurjchem-604	36	14	seen	see	VERB
eurjchem-604	36	15	in	in	ADP
eurjchem-604	36	16	the	the	DET
eurjchem-604	36	17	experimental	experimental	ADJ
eurjchem-604	36	18	data	datum	NOUN
eurjchem-604	36	19	presented	present	VERB
eurjchem-604	36	20	below	below	ADV
eurjchem-604	36	21	.	.	PUNCT
eurjchem-604	37	1	the	the	DET
eurjchem-604	37	2	lumo	lumo	NOUN
eurjchem-604	37	3	is	be	AUX
eurjchem-604	37	4	strongly	strongly	ADV
eurjchem-604	37	5	π	π	X
eurjchem-604	37	6	*	*	PUNCT
eurjchem-604	37	7	antibonding	antibonde	VERB
eurjchem-604	37	8	and	and	CCONJ
eurjchem-604	37	9	is	be	AUX
eurjchem-604	37	10	low	low	ADJ
eurjchem-604	37	11	enough	enough	ADV
eurjchem-604	37	12	in	in	ADP
eurjchem-604	37	13	energy	energy	NOUN
eurjchem-604	37	14	to	to	PART
eurjchem-604	37	15	act	act	VERB
eurjchem-604	37	16	as	as	ADP
eurjchem-604	37	17	a	a	DET
eurjchem-604	37	18	good	good	ADJ
eurjchem-604	37	19	acceptor	acceptor	NOUN
eurjchem-604	37	20	orbital	orbital	NOUN
eurjchem-604	37	21	for	for	ADP
eurjchem-604	37	22	interacting	interact	VERB
eurjchem-604	37	23	with	with	ADP
eurjchem-604	37	24	filled	fill	VERB
eurjchem-604	37	25	d‐	d‐	ADJ
eurjchem-604	37	26	orbitals	orbital	NOUN
eurjchem-604	37	27	on	on	ADP
eurjchem-604	37	28	metals	metal	NOUN
eurjchem-604	37	29	.	.	PUNCT
eurjchem-604	38	1	co	co	NOUN
eurjchem-604	38	2	forms	form	VERB
eurjchem-604	38	3	bonds	bond	NOUN
eurjchem-604	38	4	with	with	ADP
eurjchem-604	38	5	metal	metal	NOUN
eurjchem-604	38	6	ions	ion	NOUN
eurjchem-604	38	7	through	through	ADP
eurjchem-604	38	8	π‐back	π‐back	PUNCT
eurjchem-604	38	9	bonding	bonding	NOUN
eurjchem-604	38	10	.	.	PUNCT
eurjchem-604	39	1	as	as	ADP
eurjchem-604	39	2	a	a	DET
eurjchem-604	39	3	result	result	NOUN
eurjchem-604	39	4	of	of	ADP
eurjchem-604	39	5	π‐back	π‐back	PUNCT
eurjchem-604	39	6	bonding	bonding	NOUN
eurjchem-604	39	7	,	,	PUNCT
eurjchem-604	39	8	the	the	DET
eurjchem-604	39	9	transition	transition	NOUN
eurjchem-604	39	10	metal	metal	NOUN
eurjchem-604	39	11	attains	attain	NOUN
eurjchem-604	39	12	nearer	nearer	ADP
eurjchem-604	39	13	inert	inert	ADJ
eurjchem-604	39	14	gas	gas	NOUN
eurjchem-604	39	15	electron	electron	NOUN
eurjchem-604	39	16	configuration	configuration	NOUN
eurjchem-604	39	17	.	.	PUNCT
eurjchem-604	40	1	co	co	PUNCT
eurjchem-604	40	2	contains	contain	VERB
eurjchem-604	40	3	lone	lone	ADJ
eurjchem-604	40	4	pairs	pair	NOUN
eurjchem-604	40	5	of	of	ADP
eurjchem-604	40	6	electrons	electron	NOUN
eurjchem-604	40	7	on	on	ADP
eurjchem-604	40	8	carbon	carbon	NOUN
eurjchem-604	40	9	atom	atom	NOUN
eurjchem-604	40	10	and	and	CCONJ
eurjchem-604	40	11	forms	form	NOUN
eurjchem-604	40	12	sigma	sigma	VERB
eurjchem-604	40	13	bond	bond	NOUN
eurjchem-604	40	14	to	to	ADP
eurjchem-604	40	15	the	the	DET
eurjchem-604	40	16	metal	metal	NOUN
eurjchem-604	40	17	.	.	PUNCT
eurjchem-604	41	1	the	the	DET
eurjchem-604	41	2	metal	metal	NOUN
eurjchem-604	41	3	atom	atom	NOUN
eurjchem-604	41	4	inturn	inturn	NOUN
eurjchem-604	41	5	donates	donate	VERB
eurjchem-604	41	6	electrons	electron	NOUN
eurjchem-604	41	7	from	from	ADP
eurjchem-604	41	8	its	its	PRON
eurjchem-604	41	9	valence	valence	NOUN
eurjchem-604	41	10	d‐	d‐	DET
eurjchem-604	41	11	shell	shell	NOUN
eurjchem-604	41	12	to	to	ADP
eurjchem-604	41	13	π	π	PROPN
eurjchem-604	41	14	orbitals	orbital	NOUN
eurjchem-604	41	15	of	of	ADP
eurjchem-604	41	16	co	co	PROPN
eurjchem-604	41	17	(	(	PUNCT
eurjchem-604	41	18	figure	figure	NOUN
eurjchem-604	41	19	2	2	NUM
eurjchem-604	41	20	)	)	PUNCT
eurjchem-604	41	21	and	and	CCONJ
eurjchem-604	41	22	metal	metal	NOUN
eurjchem-604	41	23	atom	atom	NOUN
eurjchem-604	41	24	attains	attain	NOUN
eurjchem-604	41	25	inert	inert	ADJ
eurjchem-604	41	26	gas	gas	NOUN
eurjchem-604	41	27	configuration	configuration	NOUN
eurjchem-604	41	28	due	due	ADP
eurjchem-604	41	29	to	to	ADP
eurjchem-604	41	30	this	this	DET
eurjchem-604	41	31	donation	donation	NOUN
eurjchem-604	41	32	of	of	ADP
eurjchem-604	41	33	valence	valence	NOUN
eurjchem-604	41	34	electrons	electron	NOUN
eurjchem-604	41	35	(	(	PUNCT
eurjchem-604	41	36	figure	figure	NOUN
eurjchem-604	41	37	3	3	NUM
eurjchem-604	41	38	)	)	PUNCT
eurjchem-604	41	39	.	.	PUNCT
eurjchem-604	42	1	figure	figure	VERB
eurjchem-604	42	2	3	3	NUM
eurjchem-604	42	3	.	.	PUNCT
eurjchem-604	42	4	π‐back	π‐back	PUNCT
eurjchem-604	43	1	bonding	bond	VERB
eurjchem-604	43	2	between	between	ADP
eurjchem-604	43	3	metal	metal	NOUN
eurjchem-604	43	4	and	and	CCONJ
eurjchem-604	43	5	co	co	NOUN
eurjchem-604	43	6	group	group	NOUN
eurjchem-604	43	7	.	.	PUNCT
eurjchem-604	44	1	for	for	ADP
eurjchem-604	44	2	an	an	DET
eurjchem-604	44	3	example	example	NOUN
eurjchem-604	44	4	,	,	PUNCT
eurjchem-604	44	5	in	in	ADP
eurjchem-604	44	6	chromium	chromium	NOUN
eurjchem-604	44	7	hexacarbonyl	hexacarbonyl	NOUN
eurjchem-604	45	1	[	[	X
eurjchem-604	45	2	cr(co)6	cr(co)6	X
eurjchem-604	45	3	]	]	X
eurjchem-604	45	4	,	,	PUNCT
eurjchem-604	45	5	elemental	elemental	ADJ
eurjchem-604	45	6	chromium	chromium	NOUN
eurjchem-604	45	7	contains	contain	VERB
eurjchem-604	45	8	six	six	NUM
eurjchem-604	45	9	valence	valence	NOUN
eurjchem-604	45	10	electrons	electron	NOUN
eurjchem-604	45	11	hence	hence	ADV
eurjchem-604	45	12	combines	combine	VERB
eurjchem-604	45	13	with	with	ADP
eurjchem-604	45	14	six	six	NUM
eurjchem-604	45	15	co	co	NOUN
eurjchem-604	45	16	molecules	molecule	NOUN
eurjchem-604	45	17	and	and	CCONJ
eurjchem-604	45	18	attains	attain	NOUN
eurjchem-604	45	19	isoelectronic	isoelectronic	ADJ
eurjchem-604	45	20	configuration	configuration	NOUN
eurjchem-604	45	21	with	with	ADP
eurjchem-604	45	22	nearer	near	ADJ
eurjchem-604	45	23	inert	inert	ADJ
eurjchem-604	45	24	gas	gas	NOUN
eurjchem-604	45	25	krypton	krypton	NOUN
eurjchem-604	45	26	(	(	PUNCT
eurjchem-604	45	27	kr	kr	PROPN
eurjchem-604	45	28	)	)	PUNCT
eurjchem-604	45	29	.	.	PUNCT
eurjchem-604	46	1	1.2	1.2	NUM
eurjchem-604	46	2	.	.	PUNCT
eurjchem-604	46	3	bonding	bonding	NOUN
eurjchem-604	46	4	modes	mode	NOUN
eurjchem-604	46	5	in	in	ADP
eurjchem-604	46	6	clusters	cluster	NOUN
eurjchem-604	46	7	the	the	DET
eurjchem-604	46	8	carbonyl	carbonyl	NOUN
eurjchem-604	46	9	ligand	ligand	NOUN
eurjchem-604	46	10	engages	engage	VERB
eurjchem-604	46	11	in	in	ADP
eurjchem-604	46	12	three	three	NUM
eurjchem-604	46	13	types	type	NOUN
eurjchem-604	46	14	of	of	ADP
eurjchem-604	46	15	bonding	bonding	NOUN
eurjchem-604	46	16	modes	mode	NOUN
eurjchem-604	46	17	in	in	ADP
eurjchem-604	46	18	metal	metal	NOUN
eurjchem-604	46	19	carbonyl	carbonyl	NOUN
eurjchem-604	46	20	cluster	cluster	NOUN
eurjchem-604	46	21	chemistry	chemistry	NOUN
eurjchem-604	46	22	[	[	X
eurjchem-604	46	23	1,2	1,2	NUM
eurjchem-604	46	24	]	]	PUNCT
eurjchem-604	46	25	.	.	PUNCT
eurjchem-604	47	1	most	most	ADV
eurjchem-604	47	2	frequently	frequently	ADV
eurjchem-604	47	3	,	,	PUNCT
eurjchem-604	47	4	co	co	VERB
eurjchem-604	47	5	binds	bind	VERB
eurjchem-604	47	6	in	in	ADP
eurjchem-604	47	7	the	the	DET
eurjchem-604	47	8	familiar	familiar	ADJ
eurjchem-604	47	9	terminal	terminal	ADJ
eurjchem-604	47	10	mode	mode	NOUN
eurjchem-604	47	11	,	,	PUNCT
eurjchem-604	47	12	but	but	CCONJ
eurjchem-604	47	13	co	co	X
eurjchem-604	47	14	is	be	AUX
eurjchem-604	47	15	often	often	ADV
eurjchem-604	47	16	bridges	bridge	NOUN
eurjchem-604	47	17	between	between	ADP
eurjchem-604	47	18	two	two	NUM
eurjchem-604	47	19	(	(	PUNCT
eurjchem-604	47	20	μ2	μ2	NOUN
eurjchem-604	47	21	)	)	PUNCT
eurjchem-604	47	22	or	or	CCONJ
eurjchem-604	47	23	three	three	NUM
eurjchem-604	47	24	(	(	PUNCT
eurjchem-604	47	25	μ3	μ3	ADJ
eurjchem-604	47	26	)	)	PUNCT
eurjchem-604	47	27	metals	metal	NOUN
eurjchem-604	47	28	(	(	PUNCT
eurjchem-604	47	29	figure	figure	NOUN
eurjchem-604	47	30	4	4	NUM
eurjchem-604	47	31	)	)	PUNCT
eurjchem-604	47	32	.	.	PUNCT
eurjchem-604	48	1	much	much	ADV
eurjchem-604	48	2	less	less	ADV
eurjchem-604	48	3	common	common	ADJ
eurjchem-604	48	4	are	be	AUX
eurjchem-604	48	5	bonding	bond	VERB
eurjchem-604	48	6	modes	mode	NOUN
eurjchem-604	48	7	in	in	ADP
eurjchem-604	48	8	which	which	PRON
eurjchem-604	48	9	both	both	DET
eurjchem-604	48	10	c	c	PROPN
eurjchem-604	48	11	and	and	CCONJ
eurjchem-604	48	12	o	o	PROPN
eurjchem-604	48	13	bond	bond	NOUN
eurjchem-604	48	14	to	to	ADP
eurjchem-604	48	15	the	the	DET
eurjchem-604	48	16	metal	metal	NOUN
eurjchem-604	48	17	,	,	PUNCT
eurjchem-604	48	18	e.	e.	PROPN
eurjchem-604	48	19	g.	g.	PROPN
eurjchem-604	48	20	μ3‐η2	μ3‐η2	PROPN
eurjchem-604	48	21	.	.	PUNCT
eurjchem-604	49	1	the	the	DET
eurjchem-604	49	2	increased	increase	VERB
eurjchem-604	49	3	π‐bonding	π‐bonde	VERB
eurjchem-604	49	4	due	due	ADP
eurjchem-604	49	5	to	to	ADP
eurjchem-604	49	6	back‐donation	back‐donation	NOUN
eurjchem-604	49	7	from	from	ADP
eurjchem-604	49	8	multiple	multiple	ADJ
eurjchem-604	49	9	metal	metal	NOUN
eurjchem-604	49	10	centers	center	NOUN
eurjchem-604	49	11	results	result	VERB
eurjchem-604	49	12	in	in	ADP
eurjchem-604	49	13	further	further	ADJ
eurjchem-604	49	14	weakening	weakening	NOUN
eurjchem-604	49	15	of	of	ADP
eurjchem-604	49	16	the	the	DET
eurjchem-604	49	17	c‐o	c‐o	PROPN
eurjchem-604	49	18	bond	bond	NOUN
eurjchem-604	49	19	.	.	PUNCT
eurjchem-604	50	1	figure	figure	NOUN
eurjchem-604	50	2	4	4	NUM
eurjchem-604	50	3	.	.	NOUN
eurjchem-604	50	4	standard	standard	ADJ
eurjchem-604	50	5	co	co	ADJ
eurjchem-604	50	6	bonding	bonding	NOUN
eurjchem-604	50	7	modes	mode	NOUN
eurjchem-604	50	8	in	in	ADP
eurjchem-604	50	9	metal	metal	NOUN
eurjchem-604	50	10	carbonyl	carbonyl	NOUN
eurjchem-604	50	11	clusters	cluster	NOUN
eurjchem-604	50	12	.	.	PUNCT
eurjchem-604	51	1	1.3	1.3	NUM
eurjchem-604	51	2	.	.	PUNCT
eurjchem-604	51	3	chromium	chromium	NOUN
eurjchem-604	51	4	hexacarbonyl	hexacarbonyl	NOUN
eurjchem-604	51	5	chromium	chromium	NOUN
eurjchem-604	51	6	carbonyl	carbonyl	NOUN
eurjchem-604	51	7	,	,	PUNCT
eurjchem-604	51	8	also	also	ADV
eurjchem-604	51	9	known	know	VERB
eurjchem-604	51	10	as	as	ADP
eurjchem-604	51	11	chromium	chromium	NOUN
eurjchem-604	51	12	hexacarbonyl	hexacarbonyl	NOUN
eurjchem-604	51	13	,	,	PUNCT
eurjchem-604	51	14	is	be	AUX
eurjchem-604	51	15	the	the	DET
eurjchem-604	51	16	chemical	chemical	NOUN
eurjchem-604	51	17	compound	compound	NOUN
eurjchem-604	51	18	with	with	ADP
eurjchem-604	51	19	the	the	DET
eurjchem-604	51	20	formula	formula	NOUN
eurjchem-604	51	21	cr(co)6	cr(co)6	NOUN
eurjchem-604	51	22	(	(	PUNCT
eurjchem-604	51	23	scheme	scheme	NOUN
eurjchem-604	51	24	1	1	NUM
eurjchem-604	51	25	)	)	PUNCT
eurjchem-604	51	26	.	.	PUNCT
eurjchem-604	52	1	at	at	ADP
eurjchem-604	52	2	room	room	NOUN
eurjchem-604	52	3	temperature	temperature	NOUN
eurjchem-604	52	4	the	the	DET
eurjchem-604	52	5	solid	solid	NOUN
eurjchem-604	52	6	is	be	AUX
eurjchem-604	52	7	stable	stable	ADJ
eurjchem-604	52	8	to	to	ADP
eurjchem-604	52	9	air	air	NOUN
eurjchem-604	52	10	,	,	PUNCT
eurjchem-604	52	11	although	although	SCONJ
eurjchem-604	52	12	it	it	PRON
eurjchem-604	52	13	does	do	AUX
eurjchem-604	52	14	have	have	VERB
eurjchem-604	52	15	a	a	DET
eurjchem-604	52	16	high	high	ADJ
eurjchem-604	52	17	vapor	vapor	NOUN
eurjchem-604	52	18	pressure	pressure	NOUN
eurjchem-604	52	19	and	and	CCONJ
eurjchem-604	52	20	sublimes	sublime	NOUN
eurjchem-604	52	21	readily	readily	ADV
eurjchem-604	52	22	.	.	PUNCT
eurjchem-604	53	1	cr(co)6	cr(co)6	PROPN
eurjchem-604	53	2	is	be	AUX
eurjchem-604	53	3	zero	zero	NUM
eurjchem-604	53	4	valent	valent	NOUN
eurjchem-604	53	5	,	,	PUNCT
eurjchem-604	53	6	meaning	mean	VERB
eurjchem-604	53	7	that	that	SCONJ
eurjchem-604	53	8	cr	cr	PROPN
eurjchem-604	53	9	has	have	VERB
eurjchem-604	53	10	a	a	DET
eurjchem-604	53	11	formal	formal	ADJ
eurjchem-604	53	12	charge	charge	NOUN
eurjchem-604	53	13	of	of	ADP
eurjchem-604	53	14	zero	zero	NUM
eurjchem-604	53	15	,	,	PUNCT
eurjchem-604	53	16	and	and	CCONJ
eurjchem-604	53	17	it	it	PRON
eurjchem-604	53	18	is	be	AUX
eurjchem-604	53	19	called	call	VERB
eurjchem-604	53	20	a	a	DET
eurjchem-604	53	21	homoleptic	homoleptic	ADJ
eurjchem-604	53	22	complex	complex	NOUN
eurjchem-604	53	23	,	,	PUNCT
eurjchem-604	53	24	which	which	PRON
eurjchem-604	53	25	means	mean	VERB
eurjchem-604	53	26	that	that	SCONJ
eurjchem-604	53	27	all	all	DET
eurjchem-604	53	28	the	the	DET
eurjchem-604	53	29	ligands	ligand	NOUN
eurjchem-604	53	30	are	be	AUX
eurjchem-604	53	31	the	the	DET
eurjchem-604	53	32	same	same	ADJ
eurjchem-604	53	33	.	.	PUNCT
eurjchem-604	54	1	scheme	scheme	NOUN
eurjchem-604	54	2	1	1	NUM
eurjchem-604	54	3	1.3.1	1.3.1	NUM
eurjchem-604	54	4	.	.	PUNCT
eurjchem-604	55	1	structure	structure	NOUN
eurjchem-604	55	2	the	the	DET
eurjchem-604	55	3	complex	complex	NOUN
eurjchem-604	55	4	is	be	AUX
eurjchem-604	55	5	octahedral	octahedral	ADJ
eurjchem-604	55	6	with	with	ADP
eurjchem-604	55	7	cr‐c	cr‐c	PROPN
eurjchem-604	55	8	and	and	CCONJ
eurjchem-604	55	9	c‐o	c‐o	NOUN
eurjchem-604	55	10	distances	distance	NOUN
eurjchem-604	55	11	of	of	ADP
eurjchem-604	55	12	1.92	1.92	NUM
eurjchem-604	55	13	and	and	CCONJ
eurjchem-604	55	14	1.17	1.17	NUM
eurjchem-604	55	15	å	å	NOUN
eurjchem-604	55	16	,	,	PUNCT
eurjchem-604	55	17	respectively	respectively	ADV
eurjchem-604	55	18	(	(	PUNCT
eurjchem-604	55	19	scheme	scheme	NOUN
eurjchem-604	55	20	1	1	NUM
eurjchem-604	55	21	)	)	PUNCT
eurjchem-604	56	1	[	[	X
eurjchem-604	56	2	3	3	NUM
eurjchem-604	56	3	]	]	PUNCT
eurjchem-604	56	4	.	.	PUNCT
eurjchem-604	57	1	1.3.2	1.3.2	X
eurjchem-604	57	2	.	.	PUNCT
eurjchem-604	57	3	properties	property	NOUN
eurjchem-604	57	4	chromium	chromium	NOUN
eurjchem-604	57	5	hexacarbonyl	hexacarbonyl	NOUN
eurjchem-604	57	6	is	be	AUX
eurjchem-604	57	7	white	white	ADJ
eurjchem-604	57	8	crystals	crystal	NOUN
eurjchem-604	57	9	or	or	CCONJ
eurjchem-604	57	10	powder	powder	NOUN
eurjchem-604	57	11	.	.	PUNCT
eurjchem-604	58	1	it	it	PRON
eurjchem-604	58	2	is	be	AUX
eurjchem-604	58	3	white	white	ADJ
eurjchem-604	58	4	crystalline	crystalline	NOUN
eurjchem-604	58	5	or	or	CCONJ
eurjchem-604	58	6	granular	granular	ADJ
eurjchem-604	58	7	solid	solid	ADJ
eurjchem-604	58	8	which	which	PRON
eurjchem-604	58	9	sublimes	sublime	NOUN
eurjchem-604	58	10	at	at	ADP
eurjchem-604	58	11	room	room	NOUN
eurjchem-604	58	12	temperature	temperature	NOUN
eurjchem-604	58	13	and	and	CCONJ
eurjchem-604	58	14	burns	burn	VERB
eurjchem-604	58	15	with	with	ADP
eurjchem-604	58	16	a	a	DET
eurjchem-604	58	17	luminous	luminous	ADJ
eurjchem-604	58	18	flame	flame	NOUN
eurjchem-604	58	19	.	.	PUNCT
eurjchem-604	59	1	retracted	retract	VERB
eurjchem-604	59	2	kaushik	kaushik	PROPN
eurjchem-604	59	3	et	et	PROPN
eurjchem-604	59	4	al	al	PROPN
eurjchem-604	59	5	.	.	PUNCT
eurjchem-604	59	6	/	/	SYM
eurjchem-604	59	7	european	european	PROPN
eurjchem-604	59	8	journal	journal	PROPN
eurjchem-604	59	9	of	of	ADP
eurjchem-604	59	10	chemistry	chemistry	NOUN
eurjchem-604	59	11	3	3	NUM
eurjchem-604	59	12	(	(	PUNCT
eurjchem-604	59	13	3	3	NUM
eurjchem-604	59	14	)	)	PUNCT
eurjchem-604	59	15	(	(	PUNCT
eurjchem-604	59	16	2012	2012	NUM
eurjchem-604	59	17	)	)	PUNCT
eurjchem-604	59	18	367‐394	367‐394	NOUN
eurjchem-604	59	19	369	369	NUM
eurjchem-604	59	20	chromium	chromium	NOUN
eurjchem-604	59	21	hexacarbonyl	hexacarbonyl	NOUN
eurjchem-604	59	22	is	be	AUX
eurjchem-604	59	23	insoluble	insoluble	ADJ
eurjchem-604	59	24	in	in	ADP
eurjchem-604	59	25	water	water	NOUN
eurjchem-604	59	26	and	and	CCONJ
eurjchem-604	59	27	alcohol	alcohol	NOUN
eurjchem-604	59	28	but	but	CCONJ
eurjchem-604	59	29	soluble	soluble	ADJ
eurjchem-604	59	30	in	in	ADP
eurjchem-604	59	31	most	most	ADJ
eurjchem-604	59	32	of	of	ADP
eurjchem-604	59	33	organic	organic	ADJ
eurjchem-604	59	34	solvents	solvent	NOUN
eurjchem-604	59	35	.	.	PUNCT
eurjchem-604	60	1	chromium	chromium	NOUN
eurjchem-604	60	2	hexacarbonyl	hexacarbonyl	NOUN
eurjchem-604	60	3	decomposes	decompose	VERB
eurjchem-604	60	4	violently	violently	ADV
eurjchem-604	60	5	at	at	ADP
eurjchem-604	60	6	210	210	NUM
eurjchem-604	60	7	oc	oc	NOUN
eurjchem-604	60	8	.	.	PUNCT
eurjchem-604	61	1	chromium	chromium	NOUN
eurjchem-604	61	2	hexacarbonyl	hexacarbonyl	NOUN
eurjchem-604	61	3	is	be	AUX
eurjchem-604	61	4	decomposed	decompose	VERB
eurjchem-604	61	5	by	by	ADP
eurjchem-604	61	6	chlorine	chlorine	NOUN
eurjchem-604	61	7	and	and	CCONJ
eurjchem-604	61	8	fuming	fume	VERB
eurjchem-604	61	9	nitric	nitric	ADJ
eurjchem-604	61	10	acid	acid	NOUN
eurjchem-604	61	11	,	,	PUNCT
eurjchem-604	61	12	chromium	chromium	NOUN
eurjchem-604	61	13	hexacarbonyl	hexacarbonyl	NOUN
eurjchem-604	61	14	is	be	AUX
eurjchem-604	61	15	incompatible	incompatible	ADJ
eurjchem-604	61	16	with	with	ADP
eurjchem-604	61	17	oxidizing	oxidize	VERB
eurjchem-604	61	18	agents	agent	NOUN
eurjchem-604	61	19	.	.	PUNCT
eurjchem-604	62	1	flash	flash	NOUN
eurjchem-604	62	2	point	point	NOUN
eurjchem-604	62	3	for	for	ADP
eurjchem-604	62	4	chromium	chromium	NOUN
eurjchem-604	62	5	hexacarbonyl	hexacarbonyl	NOUN
eurjchem-604	62	6	is	be	AUX
eurjchem-604	62	7	210	210	NUM
eurjchem-604	62	8	oc	oc	NOUN
eurjchem-604	62	9	,	,	PUNCT
eurjchem-604	62	10	however	however	ADV
eurjchem-604	62	11	,	,	PUNCT
eurjchem-604	62	12	it	it	PRON
eurjchem-604	62	13	is	be	AUX
eurjchem-604	62	14	probably	probably	ADV
eurjchem-604	62	15	combustible	combustible	ADJ
eurjchem-604	62	16	[	[	X
eurjchem-604	62	17	4	4	NUM
eurjchem-604	62	18	]	]	PUNCT
eurjchem-604	62	19	.	.	PUNCT
eurjchem-604	63	1	1.3.3	1.3.3	NUM
eurjchem-604	63	2	.	.	PUNCT
eurjchem-604	63	3	preparation	preparation	NOUN
eurjchem-604	63	4	the	the	DET
eurjchem-604	63	5	chromium	chromium	NOUN
eurjchem-604	63	6	hexacarbonyls	hexacarbonyls	NOUN
eurjchem-604	63	7	can	can	AUX
eurjchem-604	63	8	be	be	AUX
eurjchem-604	63	9	prepared	prepare	VERB
eurjchem-604	63	10	by	by	ADP
eurjchem-604	63	11	any	any	DET
eurjchem-604	63	12	one	one	NUM
eurjchem-604	63	13	of	of	ADP
eurjchem-604	63	14	the	the	DET
eurjchem-604	63	15	following	follow	VERB
eurjchem-604	63	16	methods	method	NOUN
eurjchem-604	63	17	.	.	PUNCT
eurjchem-604	64	1	chromium	chromium	NOUN
eurjchem-604	64	2	hexacarbonyl	hexacarbonyl	NOUN
eurjchem-604	64	3	has	have	AUX
eurjchem-604	64	4	been	be	AUX
eurjchem-604	64	5	prepared	prepare	VERB
eurjchem-604	64	6	by	by	ADP
eurjchem-604	64	7	reacting	react	VERB
eurjchem-604	64	8	chromic	chromic	ADJ
eurjchem-604	64	9	chloride	chloride	NOUN
eurjchem-604	64	10	with	with	ADP
eurjchem-604	64	11	phenyl	phenyl	NOUN
eurjchem-604	64	12	magnesium	magnesium	NOUN
eurjchem-604	64	13	bromide	bromide	NOUN
eurjchem-604	64	14	(	(	PUNCT
eurjchem-604	64	15	grignard	grignard	ADJ
eurjchem-604	64	16	reagent	reagent	NOUN
eurjchem-604	64	17	)	)	PUNCT
eurjchem-604	64	18	and	and	CCONJ
eurjchem-604	64	19	carbon	carbon	NOUN
eurjchem-604	64	20	monoxide	monoxide	NOUN
eurjchem-604	64	21	in	in	ADP
eurjchem-604	64	22	an	an	DET
eurjchem-604	64	23	ethereal	ethereal	ADJ
eurjchem-604	64	24	solution	solution	NOUN
eurjchem-604	64	25	.	.	PUNCT
eurjchem-604	65	1	a	a	DET
eurjchem-604	65	2	carbon	carbon	NOUN
eurjchem-604	65	3	monoxide	monoxide	NOUN
eurjchem-604	65	4	pressure	pressure	NOUN
eurjchem-604	65	5	of	of	ADP
eurjchem-604	65	6	one	one	NUM
eurjchem-604	65	7	atmosphere	atmosphere	NOUN
eurjchem-604	65	8	or	or	CCONJ
eurjchem-604	65	9	somewhat	somewhat	ADV
eurjchem-604	65	10	higher	high	ADJ
eurjchem-604	65	11	is	be	AUX
eurjchem-604	65	12	required	require	VERB
eurjchem-604	65	13	.	.	PUNCT
eurjchem-604	66	1	this	this	DET
eurjchem-604	66	2	process	process	NOUN
eurjchem-604	66	3	requires	require	VERB
eurjchem-604	66	4	a	a	DET
eurjchem-604	66	5	large	large	ADJ
eurjchem-604	66	6	amount	amount	NOUN
eurjchem-604	66	7	of	of	ADP
eurjchem-604	66	8	phenyl	phenyl	NOUN
eurjchem-604	66	9	magnesium	magnesium	NOUN
eurjchem-604	66	10	bromide	bromide	NOUN
eurjchem-604	66	11	(	(	PUNCT
eurjchem-604	66	12	grignard	grignard	ADJ
eurjchem-604	66	13	reagent	reagent	NOUN
eurjchem-604	66	14	)	)	PUNCT
eurjchem-604	66	15	therefore	therefore	ADV
eurjchem-604	66	16	is	be	AUX
eurjchem-604	66	17	impractical	impractical	ADJ
eurjchem-604	66	18	for	for	ADP
eurjchem-604	66	19	technical	technical	ADJ
eurjchem-604	66	20	preparation	preparation	NOUN
eurjchem-604	66	21	of	of	ADP
eurjchem-604	66	22	chromium	chromium	NOUN
eurjchem-604	66	23	hexacarbonyl	hexacarbonyl	NOUN
eurjchem-604	66	24	.	.	PUNCT
eurjchem-604	67	1	brimm	brimm	VERB
eurjchem-604	67	2	et	et	PROPN
eurjchem-604	67	3	al	al	PROPN
eurjchem-604	67	4	.	.	PROPN
eurjchem-604	67	5	found	find	VERB
eurjchem-604	67	6	a	a	DET
eurjchem-604	67	7	alternate	alternate	ADJ
eurjchem-604	67	8	method	method	NOUN
eurjchem-604	67	9	for	for	ADP
eurjchem-604	67	10	preparation	preparation	NOUN
eurjchem-604	67	11	of	of	ADP
eurjchem-604	67	12	chromium	chromium	NOUN
eurjchem-604	67	13	hexacarbonyls	hexacarbonyls	NOUN
eurjchem-604	67	14	by	by	ADP
eurjchem-604	67	15	reacting	react	VERB
eurjchem-604	67	16	anhydrous	anhydrous	ADJ
eurjchem-604	67	17	chromium	chromium	NOUN
eurjchem-604	67	18	chloride	chloride	NOUN
eurjchem-604	67	19	with	with	ADP
eurjchem-604	67	20	carbon	carbon	NOUN
eurjchem-604	67	21	monoxide	monoxide	NOUN
eurjchem-604	67	22	in	in	ADP
eurjchem-604	67	23	the	the	DET
eurjchem-604	67	24	presence	presence	NOUN
eurjchem-604	67	25	of	of	ADP
eurjchem-604	67	26	an	an	DET
eurjchem-604	67	27	aromatic	aromatic	ADJ
eurjchem-604	67	28	solvent	solvent	NOUN
eurjchem-604	67	29	compound	compound	NOUN
eurjchem-604	67	30	,	,	PUNCT
eurjchem-604	67	31	a	a	DET
eurjchem-604	67	32	friedel‐craft	friedel‐craft	NOUN
eurjchem-604	67	33	catalyst	catalyst	NOUN
eurjchem-604	67	34	alcl3	alcl3	PROPN
eurjchem-604	67	35	and	and	CCONJ
eurjchem-604	67	36	al	al	PROPN
eurjchem-604	67	37	as	as	ADP
eurjchem-604	67	38	reducing	reduce	VERB
eurjchem-604	67	39	agent	agent	NOUN
eurjchem-604	67	40	under	under	ADP
eurjchem-604	67	41	pressure	pressure	NOUN
eurjchem-604	67	42	at	at	ADP
eurjchem-604	67	43	140oc	140oc	PROPN
eurjchem-604	67	44	temperature	temperature	NOUN
eurjchem-604	67	45	[	[	X
eurjchem-604	67	46	5	5	NUM
eurjchem-604	67	47	]	]	PUNCT
eurjchem-604	67	48	(	(	PUNCT
eurjchem-604	67	49	scheme	scheme	NOUN
eurjchem-604	67	50	2	2	NUM
eurjchem-604	67	51	)	)	PUNCT
eurjchem-604	67	52	.	.	PUNCT
eurjchem-604	68	1	crcl3	crcl3	PROPN
eurjchem-604	69	1	+	+	CCONJ
eurjchem-604	69	2	al	al	PROPN
eurjchem-604	69	3	+	+	CCONJ
eurjchem-604	69	4	6co	6co	ADJ
eurjchem-604	69	5	cr(co)6	cr(co)6	NOUN
eurjchem-604	69	6	+	+	CCONJ
eurjchem-604	69	7	alcl3	alcl3	X
eurjchem-604	69	8	alcl3	alcl3	X
eurjchem-604	70	1	c6h6	c6h6	AUX
eurjchem-604	70	2	scheme	scheme	NOUN
eurjchem-604	70	3	2	2	NUM
eurjchem-604	70	4	1.3.4	1.3.4	NUM
eurjchem-604	70	5	.	.	PUNCT
eurjchem-604	71	1	applications	application	NOUN
eurjchem-604	71	2	in	in	ADP
eurjchem-604	71	3	inorganic	inorganic	ADJ
eurjchem-604	71	4	and	and	CCONJ
eurjchem-604	71	5	organometallic	organometallic	ADJ
eurjchem-604	71	6	chemistry	chemistry	NOUN
eurjchem-604	71	7	chromium	chromium	NOUN
eurjchem-604	71	8	hexacarbonyl	hexacarbonyl	NOUN
eurjchem-604	71	9	is	be	AUX
eurjchem-604	71	10	useful	useful	ADJ
eurjchem-604	71	11	in	in	ADP
eurjchem-604	71	12	serving	serve	VERB
eurjchem-604	71	13	as	as	ADP
eurjchem-604	71	14	a	a	DET
eurjchem-604	71	15	decomposable	decomposable	ADJ
eurjchem-604	71	16	material	material	NOUN
eurjchem-604	71	17	in	in	ADP
eurjchem-604	71	18	the	the	DET
eurjchem-604	71	19	production	production	NOUN
eurjchem-604	71	20	of	of	ADP
eurjchem-604	71	21	metallic	metallic	ADJ
eurjchem-604	71	22	coatings	coating	NOUN
eurjchem-604	71	23	,	,	PUNCT
eurjchem-604	71	24	such	such	ADJ
eurjchem-604	71	25	as	as	ADP
eurjchem-604	71	26	for	for	ADP
eurjchem-604	71	27	mirrors	mirror	NOUN
eurjchem-604	71	28	,	,	PUNCT
eurjchem-604	71	29	as	as	ADP
eurjchem-604	71	30	a	a	DET
eurjchem-604	71	31	catalyst	catalyst	NOUN
eurjchem-604	71	32	and	and	CCONJ
eurjchem-604	71	33	as	as	ADP
eurjchem-604	71	34	a	a	DET
eurjchem-604	71	35	chemical	chemical	NOUN
eurjchem-604	71	36	intermediate	intermediate	ADJ
eurjchem-604	71	37	.	.	PUNCT
eurjchem-604	72	1	it	it	PRON
eurjchem-604	72	2	is	be	AUX
eurjchem-604	72	3	used	use	VERB
eurjchem-604	72	4	as	as	ADP
eurjchem-604	72	5	a	a	DET
eurjchem-604	72	6	catalyst	catalyst	NOUN
eurjchem-604	72	7	for	for	ADP
eurjchem-604	72	8	polymerization	polymerization	NOUN
eurjchem-604	72	9	and	and	CCONJ
eurjchem-604	72	10	isomerization	isomerization	NOUN
eurjchem-604	72	11	of	of	ADP
eurjchem-604	72	12	olefins	olefin	NOUN
eurjchem-604	72	13	.	.	PUNCT
eurjchem-604	73	1	when	when	SCONJ
eurjchem-604	73	2	heated	heated	ADJ
eurjchem-604	73	3	or	or	CCONJ
eurjchem-604	73	4	photolyzed	photolyze	VERB
eurjchem-604	73	5	in	in	ADP
eurjchem-604	73	6	tetrahydrofuran	tetrahydrofuran	NOUN
eurjchem-604	73	7	(	(	PUNCT
eurjchem-604	73	8	thf	thf	NOUN
eurjchem-604	73	9	)	)	PUNCT
eurjchem-604	73	10	solution	solution	NOUN
eurjchem-604	73	11	,	,	PUNCT
eurjchem-604	73	12	cr(co)6	cr(co)6	PROPN
eurjchem-604	73	13	converts	convert	NOUN
eurjchem-604	73	14	to	to	ADP
eurjchem-604	73	15	cr(co)5	cr(co)5	ADJ
eurjchem-604	73	16	(	(	PUNCT
eurjchem-604	73	17	thf	thf	NOUN
eurjchem-604	73	18	)	)	PUNCT
eurjchem-604	73	19	with	with	ADP
eurjchem-604	73	20	loss	loss	NOUN
eurjchem-604	73	21	of	of	ADP
eurjchem-604	73	22	one	one	NUM
eurjchem-604	73	23	co	co	NOUN
eurjchem-604	73	24	ligand	ligand	NOUN
eurjchem-604	73	25	.	.	PUNCT
eurjchem-604	74	1	similarly	similarly	ADV
eurjchem-604	74	2	,	,	PUNCT
eurjchem-604	74	3	heating	heat	VERB
eurjchem-604	74	4	a	a	DET
eurjchem-604	74	5	solution	solution	NOUN
eurjchem-604	74	6	of	of	ADP
eurjchem-604	74	7	cr(co)6	cr(co)6	NOUN
eurjchem-604	74	8	in	in	ADP
eurjchem-604	74	9	an	an	DET
eurjchem-604	74	10	aromatic	aromatic	ADJ
eurjchem-604	74	11	solvent	solvent	NOUN
eurjchem-604	74	12	results	result	NOUN
eurjchem-604	74	13	in	in	ADP
eurjchem-604	74	14	replacement	replacement	NOUN
eurjchem-604	74	15	of	of	ADP
eurjchem-604	74	16	three	three	NUM
eurjchem-604	74	17	co	co	NOUN
eurjchem-604	74	18	ligands	ligand	NOUN
eurjchem-604	74	19	(	(	PUNCT
eurjchem-604	74	20	scheme	scheme	NOUN
eurjchem-604	74	21	3	3	NUM
eurjchem-604	74	22	)	)	PUNCT
eurjchem-604	74	23	.	.	PUNCT
eurjchem-604	75	1	scheme	scheme	NOUN
eurjchem-604	75	2	3	3	NUM
eurjchem-604	75	3	such	such	ADJ
eurjchem-604	75	4	reactions	reaction	NOUN
eurjchem-604	75	5	proceed	proceed	VERB
eurjchem-604	75	6	particularly	particularly	ADV
eurjchem-604	75	7	well	well	ADV
eurjchem-604	75	8	with	with	ADP
eurjchem-604	75	9	electron‐rich	electron‐rich	NOUN
eurjchem-604	75	10	arenes	arene	NOUN
eurjchem-604	75	11	such	such	ADJ
eurjchem-604	75	12	as	as	ADP
eurjchem-604	75	13	anisole	anisole	NOUN
eurjchem-604	75	14	,	,	PUNCT
eurjchem-604	75	15	either	either	CCONJ
eurjchem-604	75	16	as	as	ADP
eurjchem-604	75	17	the	the	DET
eurjchem-604	75	18	neat	neat	ADJ
eurjchem-604	75	19	reagent	reagent	NOUN
eurjchem-604	75	20	or	or	CCONJ
eurjchem-604	75	21	using	use	VERB
eurjchem-604	75	22	a	a	DET
eurjchem-604	75	23	mixture	mixture	NOUN
eurjchem-604	75	24	of	of	ADP
eurjchem-604	75	25	thf	thf	NOUN
eurjchem-604	75	26	and	and	CCONJ
eurjchem-604	75	27	dibutyl	dibutyl	ADJ
eurjchem-604	75	28	ether	ether	NOUN
eurjchem-604	75	29	,	,	PUNCT
eurjchem-604	75	30	the	the	DET
eurjchem-604	75	31	latter	latter	ADJ
eurjchem-604	75	32	to	to	PART
eurjchem-604	75	33	increase	increase	VERB
eurjchem-604	75	34	the	the	DET
eurjchem-604	75	35	boiling	boiling	NOUN
eurjchem-604	75	36	point	point	NOUN
eurjchem-604	75	37	of	of	ADP
eurjchem-604	75	38	the	the	DET
eurjchem-604	75	39	mixture	mixture	NOUN
eurjchem-604	75	40	.	.	PUNCT
eurjchem-604	76	1	the	the	DET
eurjchem-604	76	2	products	product	NOUN
eurjchem-604	76	3	adopt	adopt	VERB
eurjchem-604	76	4	a	a	DET
eurjchem-604	76	5	"	"	PUNCT
eurjchem-604	76	6	piano‐stool	piano‐stool	ADJ
eurjchem-604	76	7	"	"	PUNCT
eurjchem-604	76	8	structure	structure	NOUN
eurjchem-604	76	9	.	.	PUNCT
eurjchem-604	77	1	these	these	DET
eurjchem-604	77	2	species	specie	NOUN
eurjchem-604	77	3	are	be	AUX
eurjchem-604	77	4	typically	typically	ADV
eurjchem-604	77	5	yellow	yellow	ADJ
eurjchem-604	77	6	solids	solid	NOUN
eurjchem-604	77	7	,	,	PUNCT
eurjchem-604	77	8	which	which	PRON
eurjchem-604	77	9	dissolve	dissolve	VERB
eurjchem-604	77	10	well	well	ADV
eurjchem-604	77	11	in	in	ADP
eurjchem-604	77	12	common	common	ADJ
eurjchem-604	77	13	organic	organic	ADJ
eurjchem-604	77	14	solvents	solvent	NOUN
eurjchem-604	77	15	.	.	PUNCT
eurjchem-604	78	1	the	the	DET
eurjchem-604	78	2	arene	arene	NOUN
eurjchem-604	78	3	can	can	AUX
eurjchem-604	78	4	be	be	AUX
eurjchem-604	78	5	liberated	liberate	VERB
eurjchem-604	78	6	from	from	ADP
eurjchem-604	78	7	the	the	DET
eurjchem-604	78	8	chromium	chromium	NOUN
eurjchem-604	78	9	with	with	ADP
eurjchem-604	78	10	iodine	iodine	NOUN
eurjchem-604	78	11	or	or	CCONJ
eurjchem-604	78	12	by	by	ADP
eurjchem-604	78	13	photolysis	photolysis	NOUN
eurjchem-604	78	14	in	in	ADP
eurjchem-604	78	15	air	air	NOUN
eurjchem-604	78	16	.	.	PUNCT
eurjchem-604	79	1	in	in	ADP
eurjchem-604	79	2	general	general	ADJ
eurjchem-604	79	3	,	,	PUNCT
eurjchem-604	79	4	substituted	substitute	VERB
eurjchem-604	79	5	derivatives	derivative	NOUN
eurjchem-604	79	6	of	of	ADP
eurjchem-604	79	7	cr(co)6	cr(co)6	PROPN
eurjchem-604	79	8	decompose	decompose	NOUN
eurjchem-604	79	9	upon	upon	SCONJ
eurjchem-604	79	10	exposure	exposure	NOUN
eurjchem-604	79	11	to	to	ADP
eurjchem-604	79	12	air	air	NOUN
eurjchem-604	79	13	.	.	PUNCT
eurjchem-604	80	1	alkyl	alkyl	NOUN
eurjchem-604	80	2	and	and	CCONJ
eurjchem-604	80	3	aryl	aryl	NOUN
eurjchem-604	80	4	organolithium	organolithium	NOUN
eurjchem-604	80	5	reagents	reagent	NOUN
eurjchem-604	80	6	rli	rli	NOUN
eurjchem-604	80	7	add	add	VERB
eurjchem-604	80	8	to	to	ADP
eurjchem-604	80	9	a	a	DET
eurjchem-604	80	10	carbonyl	carbonyl	NOUN
eurjchem-604	80	11	ligand	ligand	NOUN
eurjchem-604	80	12	to	to	PART
eurjchem-604	80	13	give	give	VERB
eurjchem-604	80	14	anionic	anionic	ADJ
eurjchem-604	80	15	acyl	acyl	NOUN
eurjchem-604	80	16	complexes	complex	NOUN
eurjchem-604	80	17	[	[	X
eurjchem-604	80	18	1	1	NUM
eurjchem-604	80	19	]	]	PUNCT
eurjchem-604	80	20	.	.	PUNCT
eurjchem-604	81	1	these	these	DET
eurjchem-604	81	2	species	specie	NOUN
eurjchem-604	81	3	react	react	VERB
eurjchem-604	81	4	with	with	ADP
eurjchem-604	81	5	alkylating	alkylate	VERB
eurjchem-604	81	6	agents	agent	NOUN
eurjchem-604	81	7	such	such	ADJ
eurjchem-604	81	8	as	as	ADP
eurjchem-604	81	9	me3o+	me3o+	PROPN
eurjchem-604	81	10	to	to	PART
eurjchem-604	81	11	form	form	VERB
eurjchem-604	81	12	(	(	PUNCT
eurjchem-604	81	13	oc)5cr	oc)5cr	PROPN
eurjchem-604	81	14	=	=	SYM
eurjchem-604	81	15	c(ome)r	c(ome)r	NOUN
eurjchem-604	81	16	,	,	PUNCT
eurjchem-604	81	17	an	an	DET
eurjchem-604	81	18	example	example	NOUN
eurjchem-604	81	19	of	of	ADP
eurjchem-604	81	20	a	a	DET
eurjchem-604	81	21	fischer	fischer	NOUN
eurjchem-604	81	22	carbene	carbene	NOUN
eurjchem-604	81	23	.	.	PUNCT
eurjchem-604	82	1	if	if	SCONJ
eurjchem-604	82	2	the	the	DET
eurjchem-604	82	3	r	r	NOUN
eurjchem-604	82	4	group	group	NOUN
eurjchem-604	82	5	is	be	AUX
eurjchem-604	82	6	a	a	DET
eurjchem-604	82	7	vinyl	vinyl	NOUN
eurjchem-604	82	8	or	or	CCONJ
eurjchem-604	82	9	an	an	DET
eurjchem-604	82	10	aryl	aryl	NOUN
eurjchem-604	82	11	group	group	NOUN
eurjchem-604	82	12	,	,	PUNCT
eurjchem-604	82	13	then	then	ADV
eurjchem-604	82	14	the	the	DET
eurjchem-604	82	15	resulting	result	VERB
eurjchem-604	82	16	carbene	carbene	NOUN
eurjchem-604	82	17	complex	complex	NOUN
eurjchem-604	82	18	can	can	AUX
eurjchem-604	82	19	react	react	VERB
eurjchem-604	82	20	with	with	ADP
eurjchem-604	82	21	an	an	DET
eurjchem-604	82	22	acetylene	acetylene	NOUN
eurjchem-604	82	23	to	to	PART
eurjchem-604	82	24	form	form	VERB
eurjchem-604	82	25	a	a	DET
eurjchem-604	82	26	new	new	ADJ
eurjchem-604	82	27	benzene	benzene	NOUN
eurjchem-604	82	28	ring	ring	NOUN
eurjchem-604	82	29	to	to	PART
eurjchem-604	82	30	which	which	PRON
eurjchem-604	82	31	is	be	AUX
eurjchem-604	82	32	bonded	bond	VERB
eurjchem-604	82	33	the	the	DET
eurjchem-604	82	34	chromium	chromium	NOUN
eurjchem-604	82	35	tricarbonyl	tricarbonyl	NOUN
eurjchem-604	82	36	fragment	fragment	NOUN
eurjchem-604	82	37	.	.	PUNCT
eurjchem-604	83	1	the	the	DET
eurjchem-604	83	2	two	two	NUM
eurjchem-604	83	3	acetylene	acetylene	NOUN
eurjchem-604	83	4	carbon	carbon	NOUN
eurjchem-604	83	5	atoms	atom	NOUN
eurjchem-604	83	6	become	become	VERB
eurjchem-604	83	7	part	part	NOUN
eurjchem-604	83	8	of	of	ADP
eurjchem-604	83	9	the	the	DET
eurjchem-604	83	10	new	new	ADJ
eurjchem-604	83	11	ring	ring	NOUN
eurjchem-604	83	12	,	,	PUNCT
eurjchem-604	83	13	as	as	SCONJ
eurjchem-604	83	14	does	do	VERB
eurjchem-604	83	15	a	a	DET
eurjchem-604	83	16	carbon	carbon	NOUN
eurjchem-604	83	17	from	from	ADP
eurjchem-604	83	18	one	one	NUM
eurjchem-604	83	19	of	of	ADP
eurjchem-604	83	20	the	the	DET
eurjchem-604	83	21	carbonyl	carbonyl	NOUN
eurjchem-604	83	22	ligands	ligand	NOUN
eurjchem-604	83	23	.	.	PUNCT
eurjchem-604	84	1	also	also	ADV
eurjchem-604	84	2	the	the	DET
eurjchem-604	84	3	three	three	NUM
eurjchem-604	84	4	carbons	carbon	NOUN
eurjchem-604	84	5	from	from	ADP
eurjchem-604	84	6	the	the	DET
eurjchem-604	84	7	vinyl	vinyl	NOUN
eurjchem-604	84	8	carbene	carbene	NOUN
eurjchem-604	84	9	become	become	VERB
eurjchem-604	84	10	part	part	NOUN
eurjchem-604	84	11	of	of	ADP
eurjchem-604	84	12	the	the	DET
eurjchem-604	84	13	new	new	ADJ
eurjchem-604	84	14	benzene	benzene	NOUN
eurjchem-604	84	15	ring	ring	NOUN
eurjchem-604	84	16	.	.	PUNCT
eurjchem-604	85	1	1.3.5	1.3.5	NUM
eurjchem-604	85	2	.	.	PUNCT
eurjchem-604	86	1	safety	safety	NOUN
eurjchem-604	86	2	and	and	CCONJ
eurjchem-604	86	3	handling	handling	NOUN
eurjchem-604	86	4	in	in	ADP
eurjchem-604	86	5	common	common	ADJ
eurjchem-604	86	6	with	with	ADP
eurjchem-604	86	7	many	many	ADJ
eurjchem-604	86	8	of	of	ADP
eurjchem-604	86	9	the	the	DET
eurjchem-604	86	10	other	other	ADJ
eurjchem-604	86	11	homoleptic	homoleptic	ADJ
eurjchem-604	86	12	metal	metal	NOUN
eurjchem-604	86	13	carbonyls	carbonyls	NOUN
eurjchem-604	86	14	(	(	PUNCT
eurjchem-604	86	15	e.	e.	PROPN
eurjchem-604	86	16	g.	g.	PROPN
eurjchem-604	86	17	nickel	nickel	NOUN
eurjchem-604	86	18	carbonyl	carbonyl	NOUN
eurjchem-604	86	19	and	and	CCONJ
eurjchem-604	86	20	iron	iron	NOUN
eurjchem-604	86	21	carbonyl	carbonyl	NOUN
eurjchem-604	86	22	)	)	PUNCT
eurjchem-604	86	23	,	,	PUNCT
eurjchem-604	86	24	chromium	chromium	NOUN
eurjchem-604	86	25	hexacarbonyl	hexacarbonyl	NOUN
eurjchem-604	86	26	is	be	AUX
eurjchem-604	86	27	toxic	toxic	ADJ
eurjchem-604	86	28	and	and	CCONJ
eurjchem-604	86	29	thought	think	VERB
eurjchem-604	86	30	to	to	PART
eurjchem-604	86	31	be	be	AUX
eurjchem-604	86	32	carcinogenic	carcinogenic	ADJ
eurjchem-604	86	33	.	.	PUNCT
eurjchem-604	87	1	its	its	PRON
eurjchem-604	87	2	vapor	vapor	NOUN
eurjchem-604	87	3	pressure	pressure	NOUN
eurjchem-604	87	4	is	be	AUX
eurjchem-604	87	5	relatively	relatively	ADV
eurjchem-604	87	6	high	high	ADJ
eurjchem-604	87	7	for	for	ADP
eurjchem-604	87	8	a	a	DET
eurjchem-604	87	9	metal	metal	NOUN
eurjchem-604	87	10	complex	complex	NOUN
eurjchem-604	87	11	,	,	PUNCT
eurjchem-604	87	12	1	1	NUM
eurjchem-604	87	13	mm	mm	NUM
eurjchem-604	87	14	hg	hg	NOUN
eurjchem-604	87	15	(	(	PUNCT
eurjchem-604	87	16	36	36	NUM
eurjchem-604	87	17	°	°	NOUN
eurjchem-604	87	18	c	c	NOUN
eurjchem-604	87	19	)	)	PUNCT
eurjchem-604	88	1	[	[	X
eurjchem-604	88	2	6	6	NUM
eurjchem-604	88	3	]	]	PUNCT
eurjchem-604	88	4	.	.	PUNCT
eurjchem-604	89	1	safety	safety	NOUN
eurjchem-604	89	2	information	information	NOUN
eurjchem-604	89	3	for	for	ADP
eurjchem-604	89	4	chromium	chromium	NOUN
eurjchem-604	89	5	hexacarbonyl	hexacarbonyl	NOUN
eurjchem-604	89	6	is	be	AUX
eurjchem-604	89	7	given	give	VERB
eurjchem-604	89	8	in	in	ADP
eurjchem-604	89	9	table	table	NOUN
eurjchem-604	89	10	1[7	1[7	NUM
eurjchem-604	89	11	]	]	PUNCT
eurjchem-604	89	12	.	.	PUNCT
eurjchem-604	90	1	table	table	NOUN
eurjchem-604	90	2	1	1	NUM
eurjchem-604	90	3	.	.	PUNCT
eurjchem-604	91	1	safety	safety	NOUN
eurjchem-604	91	2	information	information	NOUN
eurjchem-604	91	3	of	of	ADP
eurjchem-604	91	4	chromium	chromium	NOUN
eurjchem-604	91	5	hexacarbonyl	hexacarbonyl	NOUN
eurjchem-604	91	6	.	.	PUNCT
eurjchem-604	92	1	safety	safety	NOUN
eurjchem-604	92	2	parameter	parameter	PROPN
eurjchem-604	92	3	safety	safety	PROPN
eurjchem-604	92	4	data	datum	NOUN
eurjchem-604	92	5	explanation	explanation	NOUN
eurjchem-604	92	6	symbol	symbol	NOUN
eurjchem-604	92	7	ghs06	ghs06	PROPN
eurjchem-604	92	8	acute	acute	NOUN
eurjchem-604	92	9	toxicity	toxicity	NOUN
eurjchem-604	92	10	(	(	PUNCT
eurjchem-604	92	11	oral	oral	ADJ
eurjchem-604	92	12	,	,	PUNCT
eurjchem-604	92	13	dermal	dermal	ADJ
eurjchem-604	92	14	,	,	PUNCT
eurjchem-604	92	15	inhalation	inhalation	NOUN
eurjchem-604	92	16	)	)	PUNCT
eurjchem-604	92	17	,	,	PUNCT
eurjchem-604	92	18	categories	category	NOUN
eurjchem-604	92	19	1,2,3	1,2,3	NUM
eurjchem-604	92	20	signal	signal	NOUN
eurjchem-604	92	21	word	word	NOUN
eurjchem-604	92	22	danger	danger	NOUN
eurjchem-604	92	23	‐	‐	ADP
eurjchem-604	92	24	hazard	hazard	NOUN
eurjchem-604	92	25	statement	statement	NOUN
eurjchem-604	92	26	h301	h301	NUM
eurjchem-604	92	27	a.	a.	NOUN
eurjchem-604	92	28	letter	letter	NOUN
eurjchem-604	92	29	"	"	PUNCT
eurjchem-604	92	30	h	h	NOUN
eurjchem-604	92	31	"	"	PUNCT
eurjchem-604	92	32	(	(	PUNCT
eurjchem-604	92	33	for	for	ADP
eurjchem-604	92	34	"	"	PUNCT
eurjchem-604	92	35	hazard	hazard	NOUN
eurjchem-604	92	36	statement	statement	NOUN
eurjchem-604	92	37	"	"	PUNCT
eurjchem-604	92	38	)	)	PUNCT
eurjchem-604	92	39	.	.	PUNCT
eurjchem-604	93	1	b.	b.	PROPN
eurjchem-604	94	1	a	a	DET
eurjchem-604	94	2	number	number	NOUN
eurjchem-604	94	3	‘	'	PUNCT
eurjchem-604	94	4	3	3	NUM
eurjchem-604	94	5	’	'	PUNCT
eurjchem-604	94	6	for	for	ADP
eurjchem-604	94	7	health	health	NOUN
eurjchem-604	94	8	hazard	hazard	NOUN
eurjchem-604	94	9	.	.	PUNCT
eurjchem-604	95	1	c.	c.	NOUN
eurjchem-604	95	2	two	two	NUM
eurjchem-604	95	3	numbers	number	NOUN
eurjchem-604	95	4	‘	'	PUNCT
eurjchem-604	95	5	01	01	NUM
eurjchem-604	95	6	’	'	PUNCT
eurjchem-604	95	7	for	for	ADP
eurjchem-604	95	8	explosive	explosive	ADJ
eurjchem-604	95	9	properties	property	NOUN
eurjchem-604	95	10	(	(	PUNCT
eurjchem-604	95	11	00‐10	00‐10	NUM
eurjchem-604	95	12	)	)	PUNCT
eurjchem-604	95	13	.	.	PUNCT
eurjchem-604	96	1	precautionary	precautionary	ADJ
eurjchem-604	96	2	statements	statement	NOUN
eurjchem-604	96	3	p301	p301	PROPN
eurjchem-604	96	4	+	+	NUM
eurjchem-604	96	5	p310	p310	PROPN
eurjchem-604	97	1	p301	p301	PROPN
eurjchem-604	97	2	if	if	SCONJ
eurjchem-604	97	3	swallowed	swallow	VERB
eurjchem-604	97	4	:	:	PUNCT
eurjchem-604	97	5	p310	p310	PROPN
eurjchem-604	97	6	immediately	immediately	ADV
eurjchem-604	97	7	call	call	VERB
eurjchem-604	97	8	a	a	DET
eurjchem-604	97	9	poison	poison	NOUN
eurjchem-604	97	10	center	center	NOUN
eurjchem-604	97	11	or	or	CCONJ
eurjchem-604	97	12	doctor	doctor	NOUN
eurjchem-604	97	13	/	/	SYM
eurjchem-604	97	14	physician	physician	NOUN
eurjchem-604	97	15	.	.	PUNCT
eurjchem-604	98	1	hazard	hazard	NOUN
eurjchem-604	98	2	code	code	PROPN
eurjchem-604	98	3	t	t	PROPN
eurjchem-604	98	4	for	for	ADP
eurjchem-604	98	5	‘	'	PUNCT
eurjchem-604	98	6	toxic	toxic	ADJ
eurjchem-604	98	7	’	'	PUNCT
eurjchem-604	98	8	risk	risk	NOUN
eurjchem-604	98	9	statements	statement	NOUN
eurjchem-604	98	10	22	22	NUM
eurjchem-604	98	11	harmful	harmful	ADJ
eurjchem-604	98	12	if	if	SCONJ
eurjchem-604	98	13	swallowed	swallow	VERB
eurjchem-604	98	14	1.4	1.4	NUM
eurjchem-604	98	15	.	.	PUNCT
eurjchem-604	99	1	molybdenum	molybdenum	NOUN
eurjchem-604	99	2	hexacarbonyl	hexacarbonyl	PROPN
eurjchem-604	99	3	molybdenum	molybdenum	PROPN
eurjchem-604	99	4	hexacarbonyl	hexacarbonyl	NOUN
eurjchem-604	99	5	(	(	PUNCT
eurjchem-604	99	6	also	also	ADV
eurjchem-604	99	7	called	call	VERB
eurjchem-604	99	8	molybdenum	molybdenum	NOUN
eurjchem-604	99	9	carbonyl	carbonyl	NOUN
eurjchem-604	99	10	)	)	PUNCT
eurjchem-604	99	11	is	be	AUX
eurjchem-604	99	12	the	the	DET
eurjchem-604	99	13	chemical	chemical	NOUN
eurjchem-604	99	14	compound	compound	NOUN
eurjchem-604	99	15	with	with	ADP
eurjchem-604	99	16	the	the	DET
eurjchem-604	99	17	formula	formula	NOUN
eurjchem-604	99	18	mo(co)6	mo(co)6	X
eurjchem-604	99	19	(	(	PUNCT
eurjchem-604	99	20	scheme	scheme	NOUN
eurjchem-604	99	21	4	4	NUM
eurjchem-604	99	22	)	)	PUNCT
eurjchem-604	99	23	.	.	PUNCT
eurjchem-604	100	1	this	this	DET
eurjchem-604	100	2	colorless	colorless	ADV
eurjchem-604	100	3	solid	solid	ADJ
eurjchem-604	100	4	,	,	PUNCT
eurjchem-604	100	5	like	like	ADP
eurjchem-604	100	6	its	its	PRON
eurjchem-604	100	7	chromium	chromium	NOUN
eurjchem-604	100	8	and	and	CCONJ
eurjchem-604	100	9	tungsten	tungsten	NOUN
eurjchem-604	100	10	analogues	analogue	NOUN
eurjchem-604	100	11	,	,	PUNCT
eurjchem-604	100	12	is	be	AUX
eurjchem-604	100	13	noteworthy	noteworthy	ADJ
eurjchem-604	100	14	as	as	ADP
eurjchem-604	100	15	a	a	DET
eurjchem-604	100	16	volatile	volatile	ADJ
eurjchem-604	100	17	,	,	PUNCT
eurjchem-604	100	18	air‐stable	air‐stable	ADJ
eurjchem-604	100	19	derivative	derivative	NOUN
eurjchem-604	100	20	of	of	ADP
eurjchem-604	100	21	a	a	DET
eurjchem-604	100	22	metal	metal	NOUN
eurjchem-604	100	23	in	in	ADP
eurjchem-604	100	24	its	its	PRON
eurjchem-604	100	25	zero	zero	NUM
eurjchem-604	100	26	oxidation	oxidation	NOUN
eurjchem-604	100	27	state	state	NOUN
eurjchem-604	100	28	.	.	PUNCT
eurjchem-604	101	1	1.4.1	1.4.1	X
eurjchem-604	101	2	.	.	X
eurjchem-604	101	3	structure	structure	NOUN
eurjchem-604	101	4	mo(co)6	mo(co)6	PROPN
eurjchem-604	101	5	adopts	adopt	VERB
eurjchem-604	101	6	an	an	DET
eurjchem-604	101	7	octahedral	octahedral	ADJ
eurjchem-604	101	8	geometry	geometry	NOUN
eurjchem-604	101	9	consisting	consist	VERB
eurjchem-604	101	10	of	of	ADP
eurjchem-604	101	11	six	six	NUM
eurjchem-604	101	12	rod‐like	rod‐like	PROPN
eurjchem-604	101	13	co	co	X
eurjchem-604	101	14	ligands	ligand	NOUN
eurjchem-604	101	15	radiating	radiate	VERB
eurjchem-604	101	16	from	from	ADP
eurjchem-604	101	17	the	the	DET
eurjchem-604	101	18	central	central	ADJ
eurjchem-604	101	19	mo	mo	PROPN
eurjchem-604	101	20	atom	atom	NOUN
eurjchem-604	101	21	(	(	PUNCT
eurjchem-604	101	22	scheme	scheme	NOUN
eurjchem-604	101	23	4	4	NUM
eurjchem-604	101	24	)	)	PUNCT
eurjchem-604	101	25	.	.	PUNCT
eurjchem-604	102	1	a	a	DET
eurjchem-604	102	2	recurring	recur	VERB
eurjchem-604	102	3	minor	minor	ADJ
eurjchem-604	102	4	debate	debate	NOUN
eurjchem-604	102	5	in	in	ADP
eurjchem-604	102	6	some	some	DET
eurjchem-604	102	7	chemical	chemical	NOUN
eurjchem-604	102	8	circles	circle	NOUN
eurjchem-604	102	9	concerns	concern	VERB
eurjchem-604	102	10	the	the	DET
eurjchem-604	102	11	definition	definition	NOUN
eurjchem-604	102	12	of	of	ADP
eurjchem-604	102	13	an	an	DET
eurjchem-604	102	14	"	"	PUNCT
eurjchem-604	102	15	organometallic	organometallic	ADJ
eurjchem-604	102	16	"	"	PUNCT
eurjchem-604	102	17	compound	compound	NOUN
eurjchem-604	102	18	.	.	PUNCT
eurjchem-604	103	1	usually	usually	ADV
eurjchem-604	103	2	,	,	PUNCT
eurjchem-604	103	3	organometallic	organometallic	ADJ
eurjchem-604	103	4	indicates	indicate	VERB
eurjchem-604	103	5	the	the	DET
eurjchem-604	103	6	presence	presence	NOUN
eurjchem-604	103	7	of	of	ADP
eurjchem-604	103	8	a	a	DET
eurjchem-604	103	9	metal	metal	NOUN
eurjchem-604	103	10	directly	directly	ADV
eurjchem-604	103	11	bonded	bond	VERB
eurjchem-604	103	12	via	via	ADP
eurjchem-604	103	13	a	a	DET
eurjchem-604	103	14	m‐c	m‐c	PROPN
eurjchem-604	103	15	bond	bond	NOUN
eurjchem-604	103	16	to	to	ADP
eurjchem-604	103	17	an	an	DET
eurjchem-604	103	18	organic	organic	ADJ
eurjchem-604	103	19	fragment	fragment	NOUN
eurjchem-604	103	20	,	,	PUNCT
eurjchem-604	103	21	which	which	PRON
eurjchem-604	103	22	must	must	AUX
eurjchem-604	103	23	in	in	ADP
eurjchem-604	103	24	turn	turn	NOUN
eurjchem-604	103	25	have	have	VERB
eurjchem-604	103	26	a	a	DET
eurjchem-604	103	27	c‐h	c‐h	PROPN
eurjchem-604	103	28	bond	bond	NOUN
eurjchem-604	103	29	.	.	PUNCT
eurjchem-604	104	1	by	by	ADP
eurjchem-604	104	2	this	this	DET
eurjchem-604	104	3	strict	strict	ADJ
eurjchem-604	104	4	definition	definition	NOUN
eurjchem-604	104	5	,	,	PUNCT
eurjchem-604	104	6	mo(co)6	mo(co)6	PROPN
eurjchem-604	104	7	is	be	AUX
eurjchem-604	104	8	not	not	PART
eurjchem-604	104	9	organometallic	organometallic	ADJ
eurjchem-604	104	10	.	.	PUNCT
eurjchem-604	105	1	scheme	scheme	NOUN
eurjchem-604	105	2	4	4	NUM
eurjchem-604	105	3	1.4.2	1.4.2	NUM
eurjchem-604	105	4	.	.	PUNCT
eurjchem-604	106	1	properties	property	NOUN
eurjchem-604	106	2	mo(co)6	mo(co)6	PROPN
eurjchem-604	106	3	is	be	AUX
eurjchem-604	106	4	a	a	DET
eurjchem-604	106	5	white	white	ADJ
eurjchem-604	106	6	crystalline	crystalline	NOUN
eurjchem-604	106	7	solid	solid	NOUN
eurjchem-604	106	8	;	;	PUNCT
eurjchem-604	106	9	melts	melt	NOUN
eurjchem-604	106	10	at	at	ADP
eurjchem-604	106	11	150	150	NUM
eurjchem-604	106	12	oc	oc	NOUN
eurjchem-604	106	13	;	;	PUNCT
eurjchem-604	106	14	insoluble	insoluble	ADJ
eurjchem-604	106	15	in	in	ADP
eurjchem-604	106	16	water	water	NOUN
eurjchem-604	106	17	,	,	PUNCT
eurjchem-604	106	18	soluble	soluble	ADJ
eurjchem-604	106	19	in	in	ADP
eurjchem-604	106	20	most	most	ADJ
eurjchem-604	106	21	organic	organic	ADJ
eurjchem-604	106	22	solvents	solvent	NOUN
eurjchem-604	106	23	.	.	PUNCT
eurjchem-604	107	1	1.4.3	1.4.3	X
eurjchem-604	107	2	.	.	PUNCT
eurjchem-604	107	3	preparation	preparation	NOUN
eurjchem-604	107	4	mo(co)6	mo(co)6	PROPN
eurjchem-604	107	5	is	be	AUX
eurjchem-604	107	6	prepared	prepare	VERB
eurjchem-604	107	7	by	by	ADP
eurjchem-604	107	8	the	the	DET
eurjchem-604	107	9	reduction	reduction	NOUN
eurjchem-604	107	10	of	of	ADP
eurjchem-604	107	11	molybdenum	molybdenum	NOUN
eurjchem-604	107	12	chlorides	chloride	NOUN
eurjchem-604	107	13	or	or	CCONJ
eurjchem-604	107	14	oxides	oxide	NOUN
eurjchem-604	107	15	under	under	ADP
eurjchem-604	107	16	a	a	DET
eurjchem-604	107	17	pressure	pressure	NOUN
eurjchem-604	107	18	of	of	ADP
eurjchem-604	107	19	carbon	carbon	NOUN
eurjchem-604	107	20	monoxide	monoxide	NOUN
eurjchem-604	107	21	,	,	PUNCT
eurjchem-604	107	22	although	although	SCONJ
eurjchem-604	107	23	it	it	PRON
eurjchem-604	107	24	would	would	AUX
eurjchem-604	107	25	be	be	AUX
eurjchem-604	107	26	unusual	unusual	ADJ
eurjchem-604	107	27	to	to	PART
eurjchem-604	107	28	prepare	prepare	VERB
eurjchem-604	107	29	this	this	DET
eurjchem-604	107	30	inexpensive	inexpensive	ADJ
eurjchem-604	107	31	compound	compound	NOUN
eurjchem-604	107	32	in	in	ADP
eurjchem-604	107	33	the	the	DET
eurjchem-604	107	34	laboratory	laboratory	NOUN
eurjchem-604	107	35	.	.	PUNCT
eurjchem-604	108	1	the	the	DET
eurjchem-604	108	2	compound	compound	NOUN
eurjchem-604	108	3	is	be	AUX
eurjchem-604	108	4	somewhat	somewhat	ADV
eurjchem-604	108	5	air‐	air‐	NOUN
eurjchem-604	108	6	stable	stable	ADJ
eurjchem-604	108	7	and	and	CCONJ
eurjchem-604	108	8	sparingly	sparingly	ADV
eurjchem-604	108	9	soluble	soluble	ADJ
eurjchem-604	108	10	in	in	ADP
eurjchem-604	108	11	nonpolar	nonpolar	ADJ
eurjchem-604	108	12	organic	organic	ADJ
eurjchem-604	108	13	solvents	solvent	NOUN
eurjchem-604	108	14	.	.	PUNCT
eurjchem-604	109	1	molybdenum	molybdenum	NOUN
eurjchem-604	109	2	hexachloride	hexachloride	NOUN
eurjchem-604	109	3	is	be	AUX
eurjchem-604	109	4	reacted	react	VERB
eurjchem-604	109	5	with	with	ADP
eurjchem-604	109	6	carbon	carbon	NOUN
eurjchem-604	109	7	monoxide	monoxide	NOUN
eurjchem-604	109	8	under	under	ADP
eurjchem-604	109	9	pressure	pressure	NOUN
eurjchem-604	109	10	in	in	ADP
eurjchem-604	109	11	the	the	DET
eurjchem-604	109	12	presence	presence	NOUN
eurjchem-604	109	13	of	of	ADP
eurjchem-604	109	14	zinc	zinc	NOUN
eurjchem-604	109	15	or	or	CCONJ
eurjchem-604	109	16	aluminum	aluminum	NOUN
eurjchem-604	109	17	powder	powder	NOUN
eurjchem-604	109	18	in	in	ADP
eurjchem-604	109	19	anhydrous	anhydrous	ADJ
eurjchem-604	109	20	ether	ether	NOUN
eurjchem-604	109	21	at	at	ADP
eurjchem-604	109	22	150	150	NUM
eurjchem-604	109	23	oc	oc	NOUN
eurjchem-604	109	24	[	[	X
eurjchem-604	109	25	8	8	NUM
eurjchem-604	109	26	]	]	PUNCT
eurjchem-604	109	27	.	.	PUNCT
eurjchem-604	110	1	retracted	retract	VERB
eurjchem-604	110	2	370	370	NUM
eurjchem-604	110	3	kaushik	kaushik	PROPN
eurjchem-604	110	4	et	et	PROPN
eurjchem-604	110	5	al	al	PROPN
eurjchem-604	110	6	.	.	PUNCT
eurjchem-604	110	7	/	/	SYM
eurjchem-604	110	8	european	european	PROPN
eurjchem-604	110	9	journal	journal	PROPN
eurjchem-604	110	10	of	of	ADP
eurjchem-604	110	11	chemistry	chemistry	NOUN
eurjchem-604	110	12	3	3	NUM
eurjchem-604	110	13	(	(	PUNCT
eurjchem-604	110	14	3	3	NUM
eurjchem-604	110	15	)	)	PUNCT
eurjchem-604	110	16	(	(	PUNCT
eurjchem-604	110	17	2012	2012	NUM
eurjchem-604	110	18	)	)	PUNCT
eurjchem-604	110	19	367‐394	367‐394	NOUN
eurjchem-604	110	20	1.4.4	1.4.4	NUM
eurjchem-604	110	21	.	.	PUNCT
eurjchem-604	111	1	applications	application	NOUN
eurjchem-604	111	2	in	in	ADP
eurjchem-604	111	3	inorganic	inorganic	ADJ
eurjchem-604	111	4	and	and	CCONJ
eurjchem-604	111	5	organometallic	organometallic	ADJ
eurjchem-604	111	6	synthesis	synthesis	NOUN
eurjchem-604	111	7	molybdenum	molybdenum	NOUN
eurjchem-604	111	8	hexacarbonyl	hexacarbonyl	NOUN
eurjchem-604	111	9	is	be	AUX
eurjchem-604	111	10	widely	widely	ADV
eurjchem-604	111	11	used	use	VERB
eurjchem-604	111	12	in	in	ADP
eurjchem-604	111	13	electron	electron	NOUN
eurjchem-604	111	14	beam‐induced	beam‐induce	VERB
eurjchem-604	111	15	deposition	deposition	NOUN
eurjchem-604	111	16	technique	technique	NOUN
eurjchem-604	111	17	.	.	PUNCT
eurjchem-604	112	1	it	it	PRON
eurjchem-604	112	2	is	be	AUX
eurjchem-604	112	3	easily	easily	ADV
eurjchem-604	112	4	vaporized	vaporize	VERB
eurjchem-604	112	5	and	and	CCONJ
eurjchem-604	112	6	decomposed	decompose	VERB
eurjchem-604	112	7	by	by	ADP
eurjchem-604	112	8	the	the	DET
eurjchem-604	112	9	electron	electron	NOUN
eurjchem-604	112	10	beam	beam	NOUN
eurjchem-604	112	11	providing	provide	VERB
eurjchem-604	112	12	a	a	DET
eurjchem-604	112	13	convenient	convenient	ADJ
eurjchem-604	112	14	source	source	NOUN
eurjchem-604	112	15	of	of	ADP
eurjchem-604	112	16	molybdenum	molybdenum	NOUN
eurjchem-604	112	17	atoms	atom	NOUN
eurjchem-604	112	18	[	[	X
eurjchem-604	112	19	9	9	NUM
eurjchem-604	112	20	]	]	PUNCT
eurjchem-604	112	21	mo(co)6	mo(co)6	X
eurjchem-604	112	22	is	be	AUX
eurjchem-604	112	23	also	also	ADV
eurjchem-604	112	24	a	a	DET
eurjchem-604	112	25	popular	popular	ADJ
eurjchem-604	112	26	reagent	reagent	NOUN
eurjchem-604	112	27	in	in	ADP
eurjchem-604	112	28	organometallic	organometallic	ADJ
eurjchem-604	112	29	synthesis	synthesis	NOUN
eurjchem-604	113	1	[	[	X
eurjchem-604	113	2	10	10	NUM
eurjchem-604	113	3	]	]	PUNCT
eurjchem-604	113	4	because	because	SCONJ
eurjchem-604	113	5	one	one	NUM
eurjchem-604	113	6	or	or	CCONJ
eurjchem-604	113	7	more	more	ADJ
eurjchem-604	113	8	co	co	NOUN
eurjchem-604	113	9	ligands	ligand	NOUN
eurjchem-604	113	10	can	can	AUX
eurjchem-604	113	11	be	be	AUX
eurjchem-604	113	12	displaced	displace	VERB
eurjchem-604	113	13	by	by	ADP
eurjchem-604	113	14	other	other	ADJ
eurjchem-604	113	15	donor	donor	NOUN
eurjchem-604	113	16	ligands	ligand	NOUN
eurjchem-604	114	1	[	[	X
eurjchem-604	114	2	11	11	NUM
eurjchem-604	114	3	]	]	PUNCT
eurjchem-604	114	4	.	.	PUNCT
eurjchem-604	115	1	for	for	ADP
eurjchem-604	115	2	example	example	NOUN
eurjchem-604	115	3	,	,	PUNCT
eurjchem-604	115	4	mo(co)6	mo(co)6	PROPN
eurjchem-604	115	5	reacts	react	VERB
eurjchem-604	115	6	with	with	ADP
eurjchem-604	115	7	2,2'‐bipyridine	2,2'‐bipyridine	NUM
eurjchem-604	115	8	to	to	PART
eurjchem-604	115	9	afford	afford	VERB
eurjchem-604	115	10	mo(co)4(bipy	mo(co)4(bipy	PROPN
eurjchem-604	115	11	)	)	PUNCT
eurjchem-604	115	12	.	.	PUNCT
eurjchem-604	116	1	uv‐photolysis	uv‐photolysis	NOUN
eurjchem-604	116	2	of	of	ADP
eurjchem-604	116	3	a	a	DET
eurjchem-604	116	4	thf	thf	NOUN
eurjchem-604	116	5	solution	solution	NOUN
eurjchem-604	116	6	of	of	ADP
eurjchem-604	116	7	mo(co)6	mo(co)6	PROPN
eurjchem-604	116	8	gives	give	VERB
eurjchem-604	116	9	mo(co)5(thf	mo(co)5(thf	NOUN
eurjchem-604	116	10	)	)	PUNCT
eurjchem-604	116	11	.	.	PUNCT
eurjchem-604	117	1	many	many	ADJ
eurjchem-604	117	2	metal	metal	NOUN
eurjchem-604	117	3	carbonyls	carbonyl	NOUN
eurjchem-604	117	4	are	be	AUX
eurjchem-604	117	5	similarly	similarly	ADV
eurjchem-604	117	6	photo‐	photo‐	X
eurjchem-604	117	7	activatable	activatable	ADJ
eurjchem-604	117	8	.	.	PUNCT
eurjchem-604	118	1	mo(co)6	mo(co)6	PROPN
eurjchem-604	118	2	,	,	PUNCT
eurjchem-604	119	1	[	[	X
eurjchem-604	119	2	mo(co)3(mecn)3	mo(co)3(mecn)3	NOUN
eurjchem-604	119	3	]	]	X
eurjchem-604	119	4	,	,	PUNCT
eurjchem-604	119	5	and	and	CCONJ
eurjchem-604	119	6	related	related	ADJ
eurjchem-604	119	7	derivatives	derivative	NOUN
eurjchem-604	119	8	are	be	AUX
eurjchem-604	119	9	employed	employ	VERB
eurjchem-604	119	10	as	as	ADP
eurjchem-604	119	11	catalysts	catalyst	NOUN
eurjchem-604	119	12	in	in	ADP
eurjchem-604	119	13	organic	organic	ADJ
eurjchem-604	119	14	synthesis	synthesis	NOUN
eurjchem-604	119	15	.	.	PUNCT
eurjchem-604	120	1	for	for	ADP
eurjchem-604	120	2	example	example	NOUN
eurjchem-604	120	3	,	,	PUNCT
eurjchem-604	120	4	these	these	DET
eurjchem-604	120	5	catalysts	catalyst	NOUN
eurjchem-604	120	6	can	can	AUX
eurjchem-604	120	7	be	be	AUX
eurjchem-604	120	8	used	use	VERB
eurjchem-604	120	9	for	for	ADP
eurjchem-604	120	10	alkyne	alkyne	ADJ
eurjchem-604	120	11	metathesis	metathesis	NOUN
eurjchem-604	120	12	and	and	CCONJ
eurjchem-604	120	13	the	the	DET
eurjchem-604	120	14	pauson‐	pauson‐	ADJ
eurjchem-604	120	15	khand	khand	PROPN
eurjchem-604	120	16	reaction	reaction	NOUN
eurjchem-604	120	17	.	.	PUNCT
eurjchem-604	121	1	1.4.5	1.4.5	X
eurjchem-604	121	2	.	.	PUNCT
eurjchem-604	122	1	safety	safety	NOUN
eurjchem-604	122	2	and	and	CCONJ
eurjchem-604	122	3	handling	handle	VERB
eurjchem-604	122	4	like	like	ADP
eurjchem-604	122	5	all	all	DET
eurjchem-604	122	6	metal	metal	NOUN
eurjchem-604	122	7	carbonyls	carbonyls	NOUN
eurjchem-604	122	8	,	,	PUNCT
eurjchem-604	122	9	mo(co)6	mo(co)6	PROPN
eurjchem-604	122	10	is	be	AUX
eurjchem-604	122	11	dangerous	dangerous	ADJ
eurjchem-604	122	12	source	source	NOUN
eurjchem-604	122	13	of	of	ADP
eurjchem-604	122	14	volatile	volatile	ADJ
eurjchem-604	122	15	metal	metal	NOUN
eurjchem-604	122	16	as	as	ADV
eurjchem-604	122	17	well	well	ADV
eurjchem-604	122	18	as	as	ADP
eurjchem-604	122	19	co.	co.	PROPN
eurjchem-604	122	20	it	it	PRON
eurjchem-604	122	21	diffuses	diffuse	VERB
eurjchem-604	122	22	readily	readily	ADV
eurjchem-604	122	23	into	into	ADP
eurjchem-604	122	24	plastic	plastic	ADJ
eurjchem-604	122	25	stoppers	stopper	NOUN
eurjchem-604	122	26	[	[	X
eurjchem-604	122	27	12‐14	12‐14	X
eurjchem-604	122	28	]	]	PUNCT
eurjchem-604	122	29	.	.	PUNCT
eurjchem-604	123	1	safety	safety	NOUN
eurjchem-604	123	2	information	information	NOUN
eurjchem-604	123	3	for	for	ADP
eurjchem-604	123	4	molybdenum	molybdenum	NOUN
eurjchem-604	123	5	hexacarbonyl	hexacarbonyl	NOUN
eurjchem-604	123	6	is	be	AUX
eurjchem-604	123	7	given	give	VERB
eurjchem-604	123	8	in	in	ADP
eurjchem-604	123	9	table	table	NOUN
eurjchem-604	123	10	2	2	NUM
eurjchem-604	123	11	.	.	NOUN
eurjchem-604	123	12	1.5	1.5	NUM
eurjchem-604	123	13	.	.	PUNCT
eurjchem-604	124	1	tungsten	tungsten	VERB
eurjchem-604	124	2	hexacarbonyl	hexacarbonyl	NOUN
eurjchem-604	124	3	tungsten	tungsten	NOUN
eurjchem-604	124	4	hexacarbonyl	hexacarbonyl	NOUN
eurjchem-604	124	5	(	(	PUNCT
eurjchem-604	124	6	also	also	ADV
eurjchem-604	124	7	called	call	VERB
eurjchem-604	124	8	tungsten	tungsten	ADJ
eurjchem-604	124	9	carbonyl	carbonyl	NOUN
eurjchem-604	124	10	)	)	PUNCT
eurjchem-604	124	11	is	be	AUX
eurjchem-604	124	12	the	the	DET
eurjchem-604	124	13	chemical	chemical	NOUN
eurjchem-604	124	14	compound	compound	NOUN
eurjchem-604	124	15	with	with	ADP
eurjchem-604	124	16	the	the	DET
eurjchem-604	124	17	formula	formula	NOUN
eurjchem-604	124	18	w(co)6	w(co)6	PROPN
eurjchem-604	124	19	(	(	PUNCT
eurjchem-604	124	20	scheme	scheme	NOUN
eurjchem-604	124	21	5	5	NUM
eurjchem-604	124	22	)	)	PUNCT
eurjchem-604	124	23	.	.	PUNCT
eurjchem-604	125	1	this	this	DET
eurjchem-604	125	2	complex	complex	NOUN
eurjchem-604	125	3	gave	give	VERB
eurjchem-604	125	4	rise	rise	NOUN
eurjchem-604	125	5	to	to	ADP
eurjchem-604	125	6	the	the	DET
eurjchem-604	125	7	first	first	ADJ
eurjchem-604	125	8	example	example	NOUN
eurjchem-604	125	9	of	of	ADP
eurjchem-604	125	10	a	a	DET
eurjchem-604	125	11	dihydrogen	dihydrogen	NOUN
eurjchem-604	125	12	complex	complex	NOUN
eurjchem-604	125	13	[	[	X
eurjchem-604	125	14	15	15	NUM
eurjchem-604	125	15	]	]	SYM
eurjchem-604	125	16	.	.	PUNCT
eurjchem-604	126	1	1.5.1	1.5.1	X
eurjchem-604	126	2	.	.	PUNCT
eurjchem-604	126	3	structure	structure	NOUN
eurjchem-604	126	4	w(co)6	w(co)6	PROPN
eurjchem-604	126	5	adopts	adopt	VERB
eurjchem-604	126	6	an	an	DET
eurjchem-604	126	7	octahedral	octahedral	ADJ
eurjchem-604	126	8	geometry	geometry	NOUN
eurjchem-604	126	9	consisting	consist	VERB
eurjchem-604	126	10	of	of	ADP
eurjchem-604	126	11	six	six	NUM
eurjchem-604	126	12	rod‐like	rod‐like	PROPN
eurjchem-604	126	13	co	co	X
eurjchem-604	126	14	ligands	ligand	NOUN
eurjchem-604	126	15	radiating	radiate	VERB
eurjchem-604	126	16	from	from	ADP
eurjchem-604	126	17	the	the	DET
eurjchem-604	126	18	central	central	ADJ
eurjchem-604	126	19	w	w	PROPN
eurjchem-604	126	20	atom	atom	NOUN
eurjchem-604	126	21	with	with	ADP
eurjchem-604	126	22	dipole	dipole	NOUN
eurjchem-604	126	23	moment	moment	NOUN
eurjchem-604	126	24	0.0	0.0	NUM
eurjchem-604	126	25	d	d	NOUN
eurjchem-604	126	26	(	(	PUNCT
eurjchem-604	126	27	scheme	scheme	NOUN
eurjchem-604	126	28	5	5	NUM
eurjchem-604	126	29	)	)	PUNCT
eurjchem-604	126	30	.	.	PUNCT
eurjchem-604	127	1	table	table	NOUN
eurjchem-604	127	2	2	2	NUM
eurjchem-604	127	3	.	.	PUNCT
eurjchem-604	127	4	safety	safety	NOUN
eurjchem-604	127	5	information	information	NOUN
eurjchem-604	127	6	of	of	ADP
eurjchem-604	127	7	molybdenum	molybdenum	NOUN
eurjchem-604	127	8	hexacarbonyl	hexacarbonyl	PROPN
eurjchem-604	127	9	.	.	PUNCT
eurjchem-604	128	1	safety	safety	NOUN
eurjchem-604	128	2	parameter	parameter	PROPN
eurjchem-604	128	3	safety	safety	PROPN
eurjchem-604	128	4	data	datum	NOUN
eurjchem-604	128	5	explanation	explanation	NOUN
eurjchem-604	128	6	symbol	symbol	NOUN
eurjchem-604	128	7	ghs06	ghs06	PROPN
eurjchem-604	128	8	acute	acute	NOUN
eurjchem-604	128	9	toxicity	toxicity	NOUN
eurjchem-604	128	10	(	(	PUNCT
eurjchem-604	128	11	oral	oral	ADJ
eurjchem-604	128	12	,	,	PUNCT
eurjchem-604	128	13	dermal	dermal	ADJ
eurjchem-604	128	14	,	,	PUNCT
eurjchem-604	128	15	inhalation	inhalation	NOUN
eurjchem-604	128	16	)	)	PUNCT
eurjchem-604	128	17	,	,	PUNCT
eurjchem-604	128	18	categories	category	NOUN
eurjchem-604	128	19	1,2,3	1,2,3	NUM
eurjchem-604	128	20	signal	signal	NOUN
eurjchem-604	128	21	word	word	NOUN
eurjchem-604	128	22	danger	danger	NOUN
eurjchem-604	128	23	‐	‐	ADP
eurjchem-604	128	24	hazard	hazard	NOUN
eurjchem-604	128	25	statement	statement	NOUN
eurjchem-604	128	26	h300‐h310‐h330	h300‐h310‐h330	PROPN
eurjchem-604	128	27	a.	a.	NOUN
eurjchem-604	128	28	letter	letter	NOUN
eurjchem-604	128	29	"	"	PUNCT
eurjchem-604	128	30	h	h	NOUN
eurjchem-604	128	31	"	"	PUNCT
eurjchem-604	128	32	(	(	PUNCT
eurjchem-604	128	33	for	for	ADP
eurjchem-604	128	34	"	"	PUNCT
eurjchem-604	128	35	hazard	hazard	NOUN
eurjchem-604	128	36	statement	statement	NOUN
eurjchem-604	128	37	"	"	PUNCT
eurjchem-604	128	38	)	)	PUNCT
eurjchem-604	128	39	.	.	PUNCT
eurjchem-604	129	1	b.	b.	PROPN
eurjchem-604	130	1	a	a	DET
eurjchem-604	130	2	number	number	NOUN
eurjchem-604	130	3	‘	'	PUNCT
eurjchem-604	130	4	3	3	NUM
eurjchem-604	130	5	’	'	PUNCT
eurjchem-604	130	6	for	for	ADP
eurjchem-604	130	7	health	health	NOUN
eurjchem-604	130	8	hazard	hazard	NOUN
eurjchem-604	130	9	.	.	PUNCT
eurjchem-604	131	1	c.	c.	NOUN
eurjchem-604	131	2	two	two	NUM
eurjchem-604	131	3	numbers	number	NOUN
eurjchem-604	131	4	‘	'	PUNCT
eurjchem-604	131	5	01	01	NUM
eurjchem-604	131	6	’	'	PUNCT
eurjchem-604	131	7	for	for	ADP
eurjchem-604	131	8	explosive	explosive	ADJ
eurjchem-604	131	9	properties	property	NOUN
eurjchem-604	131	10	(	(	PUNCT
eurjchem-604	131	11	codes	code	NOUN
eurjchem-604	131	12	from	from	ADP
eurjchem-604	131	13	00‐10	00‐10	NUM
eurjchem-604	131	14	)	)	PUNCT
eurjchem-604	131	15	.	.	PUNCT
eurjchem-604	132	1	d.	d.	PROPN
eurjchem-604	132	2	two	two	NUM
eurjchem-604	132	3	numbers	number	NOUN
eurjchem-604	132	4	‘	'	PUNCT
eurjchem-604	132	5	30	30	NUM
eurjchem-604	132	6	’	'	PUNCT
eurjchem-604	132	7	for	for	ADP
eurjchem-604	132	8	flammability	flammability	NOUN
eurjchem-604	132	9	(	(	PUNCT
eurjchem-604	132	10	codes	code	NOUN
eurjchem-604	132	11	from	from	ADP
eurjchem-604	132	12	20	20	NUM
eurjchem-604	132	13	to	to	PART
eurjchem-604	132	14	30	30	NUM
eurjchem-604	132	15	)	)	PUNCT
eurjchem-604	132	16	.	.	PUNCT
eurjchem-604	133	1	precautionary	precautionary	ADJ
eurjchem-604	133	2	statements	statement	NOUN
eurjchem-604	133	3	p260‐p264‐p280‐	p260‐p264‐p280‐	NUM
eurjchem-604	133	4	p284‐p301	p284‐p301	PROPN
eurjchem-604	133	5	+	+	CCONJ
eurjchem-604	133	6	p310‐	p310‐	PROPN
eurjchem-604	133	7	p302	p302	PROPN
eurjchem-604	133	8	+	+	CCONJ
eurjchem-604	133	9	p350	p350	PROPN
eurjchem-604	133	10	p260	p260	PROPN
eurjchem-604	133	11	do	do	AUX
eurjchem-604	133	12	not	not	PART
eurjchem-604	133	13	breathe	breathe	VERB
eurjchem-604	133	14	dust	dust	NOUN
eurjchem-604	133	15	/	/	SYM
eurjchem-604	133	16	fume	fume	NOUN
eurjchem-604	133	17	/	/	SYM
eurjchem-604	133	18	gas	gas	NOUN
eurjchem-604	133	19	/	/	SYM
eurjchem-604	133	20	mist	mist	NOUN
eurjchem-604	133	21	/	/	SYM
eurjchem-604	133	22	vapours	vapour	NOUN
eurjchem-604	133	23	/	/	SYM
eurjchem-604	133	24	spray	spray	NOUN
eurjchem-604	133	25	.	.	PUNCT
eurjchem-604	134	1	p264	p264	NOUN
eurjchem-604	134	2	wash	wash	VERB
eurjchem-604	134	3	hands	hand	NOUN
eurjchem-604	134	4	thoroughly	thoroughly	ADV
eurjchem-604	134	5	after	after	ADP
eurjchem-604	134	6	handling	handle	VERB
eurjchem-604	134	7	.	.	PUNCT
eurjchem-604	135	1	p280	p280	NUM
eurjchem-604	135	2	wear	wear	VERB
eurjchem-604	135	3	protective	protective	ADJ
eurjchem-604	135	4	gloves	glove	NOUN
eurjchem-604	135	5	/	/	SYM
eurjchem-604	135	6	protective	protective	ADJ
eurjchem-604	135	7	clothing	clothing	NOUN
eurjchem-604	135	8	/	/	SYM
eurjchem-604	135	9	eye	eye	NOUN
eurjchem-604	135	10	protection	protection	NOUN
eurjchem-604	135	11	/	/	SYM
eurjchem-604	135	12	face	face	NOUN
eurjchem-604	135	13	protection	protection	NOUN
eurjchem-604	135	14	.	.	PUNCT
eurjchem-604	136	1	p284	p284	NUM
eurjchem-604	136	2	wear	wear	VERB
eurjchem-604	136	3	respiratory	respiratory	ADJ
eurjchem-604	136	4	protection	protection	NOUN
eurjchem-604	136	5	.	.	PUNCT
eurjchem-604	137	1	p301	p301	PROPN
eurjchem-604	137	2	if	if	SCONJ
eurjchem-604	137	3	swallowed	swallow	VERB
eurjchem-604	137	4	:	:	PUNCT
eurjchem-604	137	5	p310	p310	PROPN
eurjchem-604	137	6	immediately	immediately	ADV
eurjchem-604	137	7	call	call	VERB
eurjchem-604	137	8	a	a	DET
eurjchem-604	137	9	poison	poison	NOUN
eurjchem-604	137	10	center	center	NOUN
eurjchem-604	137	11	or	or	CCONJ
eurjchem-604	137	12	doctor	doctor	NOUN
eurjchem-604	137	13	/	/	SYM
eurjchem-604	137	14	physician	physician	NOUN
eurjchem-604	137	15	.	.	PUNCT
eurjchem-604	138	1	p302	p302	PROPN
eurjchem-604	139	1	if	if	SCONJ
eurjchem-604	139	2	on	on	ADP
eurjchem-604	139	3	skin	skin	NOUN
eurjchem-604	139	4	:	:	PUNCT
eurjchem-604	139	5	p350	p350	PROPN
eurjchem-604	139	6	gently	gently	ADV
eurjchem-604	139	7	wash	wash	VERB
eurjchem-604	139	8	with	with	ADP
eurjchem-604	139	9	plenty	plenty	NOUN
eurjchem-604	139	10	of	of	ADP
eurjchem-604	139	11	soap	soap	NOUN
eurjchem-604	139	12	and	and	CCONJ
eurjchem-604	139	13	water	water	NOUN
eurjchem-604	139	14	.	.	PUNCT
eurjchem-604	140	1	hazard	hazard	NOUN
eurjchem-604	140	2	code	code	PROPN
eurjchem-604	140	3	t+	t+	PUNCT
eurjchem-604	140	4	for	for	ADP
eurjchem-604	140	5	‘	'	PUNCT
eurjchem-604	140	6	very	very	ADV
eurjchem-604	140	7	toxic	toxic	ADJ
eurjchem-604	140	8	’	'	PUNCT
eurjchem-604	140	9	risk	risk	NOUN
eurjchem-604	140	10	statements	statement	NOUN
eurjchem-604	140	11	26/27/28	26/27/28	NUM
eurjchem-604	140	12	26	26	NUM
eurjchem-604	140	13	:	:	PUNCT
eurjchem-604	140	14	very	very	ADV
eurjchem-604	140	15	toxic	toxic	ADJ
eurjchem-604	140	16	by	by	ADP
eurjchem-604	140	17	inhalation	inhalation	NOUN
eurjchem-604	140	18	27	27	NUM
eurjchem-604	140	19	:	:	PUNCT
eurjchem-604	140	20	very	very	ADV
eurjchem-604	140	21	toxic	toxic	ADJ
eurjchem-604	140	22	in	in	ADP
eurjchem-604	140	23	contact	contact	NOUN
eurjchem-604	140	24	with	with	ADP
eurjchem-604	140	25	skin	skin	NOUN
eurjchem-604	140	26	28	28	NUM
eurjchem-604	140	27	:	:	PUNCT
eurjchem-604	140	28	very	very	ADV
eurjchem-604	140	29	toxic	toxic	ADJ
eurjchem-604	140	30	if	if	SCONJ
eurjchem-604	140	31	swallowed	swallow	VERB
eurjchem-604	140	32	scheme	scheme	NOUN
eurjchem-604	140	33	5	5	NUM
eurjchem-604	140	34	1.5.2	1.5.2	NUM
eurjchem-604	140	35	.	.	PUNCT
eurjchem-604	141	1	properties	property	NOUN
eurjchem-604	141	2	this	this	DET
eurjchem-604	141	3	colorless	colorless	ADJ
eurjchem-604	141	4	compound	compound	NOUN
eurjchem-604	141	5	,	,	PUNCT
eurjchem-604	141	6	like	like	ADP
eurjchem-604	141	7	its	its	PRON
eurjchem-604	141	8	chromium	chromium	NOUN
eurjchem-604	141	9	and	and	CCONJ
eurjchem-604	141	10	molybdenum	molybdenum	NOUN
eurjchem-604	141	11	analogs	analog	NOUN
eurjchem-604	141	12	,	,	PUNCT
eurjchem-604	141	13	is	be	AUX
eurjchem-604	141	14	noteworthy	noteworthy	ADJ
eurjchem-604	141	15	as	as	ADP
eurjchem-604	141	16	a	a	DET
eurjchem-604	141	17	volatile	volatile	ADJ
eurjchem-604	141	18	,	,	PUNCT
eurjchem-604	141	19	air‐stable	air‐stable	ADJ
eurjchem-604	141	20	derivative	derivative	NOUN
eurjchem-604	141	21	of	of	ADP
eurjchem-604	141	22	tungsten	tungsten	NOUN
eurjchem-604	141	23	in	in	ADP
eurjchem-604	141	24	its	its	PRON
eurjchem-604	141	25	zero	zero	NUM
eurjchem-604	141	26	oxidation	oxidation	NOUN
eurjchem-604	141	27	state	state	NOUN
eurjchem-604	141	28	.	.	PUNCT
eurjchem-604	142	1	w(co)6	w(co)6	PROPN
eurjchem-604	142	2	is	be	AUX
eurjchem-604	142	3	a	a	DET
eurjchem-604	142	4	white	white	ADJ
eurjchem-604	142	5	crystalline	crystalline	NOUN
eurjchem-604	142	6	solid	solid	NOUN
eurjchem-604	142	7	;	;	PUNCT
eurjchem-604	142	8	melts	melt	NOUN
eurjchem-604	142	9	at	at	ADP
eurjchem-604	142	10	170	170	NUM
eurjchem-604	142	11	oc	oc	NOUN
eurjchem-604	142	12	;	;	PUNCT
eurjchem-604	142	13	sublimes	sublime	NOUN
eurjchem-604	142	14	;	;	PUNCT
eurjchem-604	142	15	boil	boil	VERB
eurjchem-604	142	16	at	at	ADP
eurjchem-604	142	17	175	175	NUM
eurjchem-604	142	18	oc	oc	NOUN
eurjchem-604	142	19	.	.	PUNCT
eurjchem-604	143	1	it	it	PRON
eurjchem-604	143	2	is	be	AUX
eurjchem-604	143	3	insoluble	insoluble	ADJ
eurjchem-604	143	4	in	in	ADP
eurjchem-604	143	5	water	water	NOUN
eurjchem-604	143	6	and	and	CCONJ
eurjchem-604	143	7	alcohol	alcohol	NOUN
eurjchem-604	143	8	;	;	PUNCT
eurjchem-604	143	9	soluble	soluble	ADJ
eurjchem-604	143	10	in	in	ADP
eurjchem-604	143	11	fuming	fume	VERB
eurjchem-604	143	12	nitric	nitric	ADJ
eurjchem-604	143	13	acid	acid	NOUN
eurjchem-604	143	14	and	and	CCONJ
eurjchem-604	143	15	most	most	ADJ
eurjchem-604	143	16	organic	organic	ADJ
eurjchem-604	143	17	solvents	solvent	NOUN
eurjchem-604	143	18	.	.	PUNCT
eurjchem-604	144	1	1.5.3	1.5.3	X
eurjchem-604	144	2	.	.	PUNCT
eurjchem-604	144	3	preparation	preparation	NOUN
eurjchem-604	144	4	w(co)6	w(co)6	PROPN
eurjchem-604	144	5	is	be	AUX
eurjchem-604	144	6	prepared	prepare	VERB
eurjchem-604	144	7	by	by	ADP
eurjchem-604	144	8	the	the	DET
eurjchem-604	144	9	reduction	reduction	NOUN
eurjchem-604	144	10	of	of	ADP
eurjchem-604	144	11	wcl6	wcl6	NOUN
eurjchem-604	144	12	under	under	ADP
eurjchem-604	144	13	a	a	DET
eurjchem-604	144	14	pressure	pressure	NOUN
eurjchem-604	144	15	of	of	ADP
eurjchem-604	144	16	carbon	carbon	NOUN
eurjchem-604	144	17	monoxide	monoxide	NOUN
eurjchem-604	144	18	.	.	PUNCT
eurjchem-604	145	1	it	it	PRON
eurjchem-604	145	2	would	would	AUX
eurjchem-604	145	3	be	be	AUX
eurjchem-604	145	4	rare	rare	ADJ
eurjchem-604	145	5	to	to	PART
eurjchem-604	145	6	prepare	prepare	VERB
eurjchem-604	145	7	this	this	DET
eurjchem-604	145	8	inexpensive	inexpensive	ADJ
eurjchem-604	145	9	compound	compound	NOUN
eurjchem-604	145	10	in	in	ADP
eurjchem-604	145	11	the	the	DET
eurjchem-604	145	12	laboratory	laboratory	NOUN
eurjchem-604	145	13	because	because	SCONJ
eurjchem-604	145	14	the	the	DET
eurjchem-604	145	15	apparatus	apparatus	NOUN
eurjchem-604	145	16	is	be	AUX
eurjchem-604	145	17	expensive	expensive	ADJ
eurjchem-604	145	18	and	and	CCONJ
eurjchem-604	145	19	the	the	DET
eurjchem-604	145	20	compound	compound	NOUN
eurjchem-604	145	21	can	can	AUX
eurjchem-604	145	22	be	be	AUX
eurjchem-604	145	23	purchased	purchase	VERB
eurjchem-604	145	24	cheaply	cheaply	ADV
eurjchem-604	145	25	.	.	PUNCT
eurjchem-604	146	1	dallas	dallas	PROPN
eurjchem-604	146	2	t.	t.	PROPN
eurjchem-604	146	3	hurd	hurd	PROPN
eurjchem-604	146	4	prepared	prepare	VERB
eurjchem-604	146	5	tungsten	tungsten	NOUN
eurjchem-604	146	6	hexacarbonyl	hexacarbonyl	PROPN
eurjchem-604	146	7	when	when	SCONJ
eurjchem-604	146	8	tungsten	tungsten	ADJ
eurjchem-604	146	9	hexachloride	hexachloride	NOUN
eurjchem-604	146	10	is	be	AUX
eurjchem-604	146	11	reacted	react	VERB
eurjchem-604	146	12	with	with	ADP
eurjchem-604	146	13	carbon	carbon	NOUN
eurjchem-604	146	14	monoxide	monoxide	NOUN
eurjchem-604	146	15	under	under	ADP
eurjchem-604	146	16	pressure	pressure	NOUN
eurjchem-604	146	17	in	in	ADP
eurjchem-604	146	18	the	the	DET
eurjchem-604	146	19	presence	presence	NOUN
eurjchem-604	146	20	of	of	ADP
eurjchem-604	146	21	zinc	zinc	NOUN
eurjchem-604	146	22	or	or	CCONJ
eurjchem-604	146	23	aluminum	aluminum	NOUN
eurjchem-604	146	24	powder	powder	NOUN
eurjchem-604	146	25	in	in	ADP
eurjchem-604	146	26	anhydrous	anhydrous	ADJ
eurjchem-604	146	27	ether	ether	NOUN
eurjchem-604	146	28	at	at	ADP
eurjchem-604	146	29	100	100	NUM
eurjchem-604	146	30	oc	oc	NOUN
eurjchem-604	147	1	[	[	X
eurjchem-604	147	2	8	8	NUM
eurjchem-604	147	3	]	]	PUNCT
eurjchem-604	147	4	.	.	PUNCT
eurjchem-604	148	1	1.5.4	1.5.4	X
eurjchem-604	148	2	.	.	PUNCT
eurjchem-604	148	3	applications	application	NOUN
eurjchem-604	148	4	in	in	ADP
eurjchem-604	148	5	inorganic	inorganic	ADJ
eurjchem-604	148	6	and	and	CCONJ
eurjchem-604	148	7	organometallic	organometallic	ADJ
eurjchem-604	148	8	synthesis	synthesis	NOUN
eurjchem-604	148	9	all	all	DET
eurjchem-604	148	10	reactions	reaction	NOUN
eurjchem-604	148	11	of	of	ADP
eurjchem-604	148	12	w(co)6	w(co)6	PROPN
eurjchem-604	148	13	commence	commence	NOUN
eurjchem-604	148	14	with	with	ADP
eurjchem-604	148	15	displacement	displacement	NOUN
eurjchem-604	148	16	of	of	ADP
eurjchem-604	148	17	some	some	DET
eurjchem-604	148	18	co	co	NOUN
eurjchem-604	148	19	ligands	ligand	NOUN
eurjchem-604	148	20	in	in	ADP
eurjchem-604	148	21	w(co)6	w(co)6	PROPN
eurjchem-604	148	22	.	.	PUNCT
eurjchem-604	149	1	w(co)6	w(co)6	PROPN
eurjchem-604	149	2	behaves	behave	VERB
eurjchem-604	149	3	similarly	similarly	ADV
eurjchem-604	149	4	to	to	ADP
eurjchem-604	149	5	the	the	DET
eurjchem-604	149	6	mo(co)6	mo(co)6	NOUN
eurjchem-604	149	7	but	but	CCONJ
eurjchem-604	149	8	tends	tend	VERB
eurjchem-604	149	9	to	to	PART
eurjchem-604	149	10	form	form	VERB
eurjchem-604	149	11	compounds	compound	NOUN
eurjchem-604	149	12	that	that	PRON
eurjchem-604	149	13	are	be	AUX
eurjchem-604	149	14	kinetically	kinetically	ADV
eurjchem-604	149	15	more	more	ADV
eurjchem-604	149	16	robust	robust	ADJ
eurjchem-604	149	17	.	.	PUNCT
eurjchem-604	150	1	one	one	NUM
eurjchem-604	150	2	derivative	derivative	NOUN
eurjchem-604	150	3	is	be	AUX
eurjchem-604	150	4	the	the	DET
eurjchem-604	150	5	dihydrogen	dihydrogen	NOUN
eurjchem-604	150	6	complex	complex	NOUN
eurjchem-604	150	7	w(co)3	w(co)3	NUM
eurjchem-604	150	8	[	[	PUNCT
eurjchem-604	150	9	p(c6h11)3]2(h2	p(c6h11)3]2(h2	NOUN
eurjchem-604	150	10	)	)	PUNCT
eurjchem-604	150	11	reported	report	VERB
eurjchem-604	150	12	in	in	ADP
eurjchem-604	150	13	1982	1982	NUM
eurjchem-604	150	14	by	by	ADP
eurjchem-604	150	15	kubas	kubas	PROPN
eurjchem-604	150	16	[	[	X
eurjchem-604	150	17	15	15	NUM
eurjchem-604	150	18	]	]	SYM
eurjchem-604	150	19	three	three	NUM
eurjchem-604	150	20	of	of	ADP
eurjchem-604	150	21	these	these	DET
eurjchem-604	150	22	co	co	NOUN
eurjchem-604	150	23	ligands	ligand	NOUN
eurjchem-604	150	24	can	can	AUX
eurjchem-604	150	25	be	be	AUX
eurjchem-604	150	26	displaced	displace	VERB
eurjchem-604	150	27	by	by	ADP
eurjchem-604	150	28	acetonitrile	acetonitrile	NOUN
eurjchem-604	151	1	[	[	X
eurjchem-604	151	2	16	16	NUM
eurjchem-604	151	3	]	]	PUNCT
eurjchem-604	151	4	.	.	PUNCT
eurjchem-604	152	1	w(co)6	w(co)6	PROPN
eurjchem-604	152	2	has	have	AUX
eurjchem-604	152	3	been	be	AUX
eurjchem-604	152	4	used	use	VERB
eurjchem-604	152	5	to	to	PART
eurjchem-604	152	6	desulfurize	desulfurize	VERB
eurjchem-604	152	7	organosulfur	organosulfur	NOUN
eurjchem-604	152	8	compounds	compound	NOUN
eurjchem-604	152	9	and	and	CCONJ
eurjchem-604	152	10	as	as	ADP
eurjchem-604	152	11	a	a	DET
eurjchem-604	152	12	precursor	precursor	NOUN
eurjchem-604	152	13	to	to	ADP
eurjchem-604	152	14	catalysts	catalyst	NOUN
eurjchem-604	152	15	for	for	ADP
eurjchem-604	152	16	alkene	alkene	ADJ
eurjchem-604	152	17	metathesis	metathesis	NOUN
eurjchem-604	152	18	.	.	PUNCT
eurjchem-604	153	1	1.5.5	1.5.5	X
eurjchem-604	153	2	.	.	X
eurjchem-604	153	3	safety	safety	NOUN
eurjchem-604	153	4	and	and	CCONJ
eurjchem-604	153	5	handling	handle	VERB
eurjchem-604	153	6	like	like	ADP
eurjchem-604	153	7	all	all	DET
eurjchem-604	153	8	metal	metal	NOUN
eurjchem-604	153	9	carbonyls	carbonyls	NOUN
eurjchem-604	153	10	,	,	PUNCT
eurjchem-604	153	11	w(co)6	w(co)6	PROPN
eurjchem-604	153	12	is	be	AUX
eurjchem-604	153	13	dangerous	dangerous	ADJ
eurjchem-604	153	14	source	source	NOUN
eurjchem-604	153	15	of	of	ADP
eurjchem-604	153	16	volatile	volatile	ADJ
eurjchem-604	153	17	metal	metal	NOUN
eurjchem-604	153	18	as	as	ADV
eurjchem-604	153	19	well	well	ADV
eurjchem-604	153	20	as	as	ADP
eurjchem-604	153	21	co	co	NOUN
eurjchem-604	153	22	[	[	X
eurjchem-604	153	23	9,17	9,17	NOUN
eurjchem-604	153	24	]	]	PUNCT
eurjchem-604	153	25	.	.	PUNCT
eurjchem-604	154	1	safety	safety	NOUN
eurjchem-604	154	2	information	information	NOUN
eurjchem-604	154	3	for	for	ADP
eurjchem-604	154	4	tungsten	tungsten	NOUN
eurjchem-604	154	5	hexacarbonyl	hexacarbonyl	NOUN
eurjchem-604	154	6	is	be	AUX
eurjchem-604	154	7	given	give	VERB
eurjchem-604	154	8	in	in	ADP
eurjchem-604	154	9	table	table	NOUN
eurjchem-604	154	10	3	3	NUM
eurjchem-604	154	11	.	.	NOUN
eurjchem-604	154	12	1.6	1.6	NUM
eurjchem-604	154	13	.	.	PUNCT
eurjchem-604	155	1	importance	importance	NOUN
eurjchem-604	155	2	of	of	ADP
eurjchem-604	155	3	ir	ir	PROPN
eurjchem-604	155	4	spectroscopy	spectroscopy	VERB
eurjchem-604	155	5	in	in	ADP
eurjchem-604	155	6	characterizing	characterize	VERB
eurjchem-604	155	7	metal	metal	NOUN
eurjchem-604	155	8	carbonyls	carbonyls	NOUN
eurjchem-604	155	9	the	the	DET
eurjchem-604	155	10	most	most	ADV
eurjchem-604	155	11	important	important	ADJ
eurjchem-604	155	12	technique	technique	NOUN
eurjchem-604	155	13	for	for	ADP
eurjchem-604	155	14	characterizing	characterize	VERB
eurjchem-604	155	15	metal	metal	NOUN
eurjchem-604	155	16	carbonyls	carbonyls	NOUN
eurjchem-604	155	17	is	be	AUX
eurjchem-604	155	18	infra‐red	infra‐re	VERB
eurjchem-604	155	19	spectroscopy	spectroscopy	NOUN
eurjchem-604	155	20	.	.	PUNCT
eurjchem-604	156	1	the	the	DET
eurjchem-604	156	2	c‐o	c‐o	PROPN
eurjchem-604	156	3	vibration	vibration	NOUN
eurjchem-604	156	4	,	,	PUNCT
eurjchem-604	156	5	typically	typically	ADV
eurjchem-604	156	6	called	call	VERB
eurjchem-604	156	7	νco	νco	NOUN
eurjchem-604	156	8	,	,	PUNCT
eurjchem-604	156	9	occurs	occur	VERB
eurjchem-604	156	10	at	at	ADP
eurjchem-604	156	11	2143	2143	NUM
eurjchem-604	156	12	cm‐1	cm‐1	PROPN
eurjchem-604	156	13	for	for	ADP
eurjchem-604	156	14	co	co	NOUN
eurjchem-604	156	15	gas	gas	NOUN
eurjchem-604	156	16	.	.	PUNCT
eurjchem-604	157	1	the	the	DET
eurjchem-604	157	2	positions	position	NOUN
eurjchem-604	157	3	of	of	ADP
eurjchem-604	157	4	the	the	DET
eurjchem-604	157	5	νco	νco	NOUN
eurjchem-604	157	6	band(s	band(s	NOUN
eurjchem-604	157	7	)	)	PUNCT
eurjchem-604	157	8	for	for	ADP
eurjchem-604	157	9	the	the	DET
eurjchem-604	157	10	metal	metal	NOUN
eurjchem-604	157	11	carbonyls	carbonyls	NOUN
eurjchem-604	157	12	are	be	AUX
eurjchem-604	157	13	inversely	inversely	ADV
eurjchem-604	157	14	correlated	correlate	VERB
eurjchem-604	157	15	with	with	ADP
eurjchem-604	157	16	the	the	DET
eurjchem-604	157	17	strength	strength	NOUN
eurjchem-604	157	18	of	of	ADP
eurjchem-604	157	19	the	the	DET
eurjchem-604	157	20	π‐bonding	π‐bonde	VERB
eurjchem-604	157	21	between	between	ADP
eurjchem-604	157	22	the	the	DET
eurjchem-604	157	23	metal	metal	NOUN
eurjchem-604	157	24	and	and	CCONJ
eurjchem-604	157	25	the	the	DET
eurjchem-604	157	26	carbon	carbon	NOUN
eurjchem-604	157	27	.	.	PUNCT
eurjchem-604	158	1	in	in	ADP
eurjchem-604	158	2	addition	addition	NOUN
eurjchem-604	158	3	to	to	ADP
eurjchem-604	158	4	their	their	PRON
eurjchem-604	158	5	frequency	frequency	NOUN
eurjchem-604	158	6	,	,	PUNCT
eurjchem-604	158	7	the	the	DET
eurjchem-604	158	8	number	number	NOUN
eurjchem-604	158	9	of	of	ADP
eurjchem-604	158	10	the	the	DET
eurjchem-604	158	11	νco	νco	NOUN
eurjchem-604	158	12	bands	band	NOUN
eurjchem-604	158	13	is	be	AUX
eurjchem-604	158	14	diagnostic	diagnostic	ADJ
eurjchem-604	158	15	of	of	ADP
eurjchem-604	158	16	structure	structure	NOUN
eurjchem-604	158	17	of	of	ADP
eurjchem-604	158	18	the	the	DET
eurjchem-604	158	19	complex	complex	ADJ
eurjchem-604	158	20	.	.	PUNCT
eurjchem-604	159	1	octahedral	octahedral	ADJ
eurjchem-604	159	2	complexes	complex	NOUN
eurjchem-604	159	3	,	,	PUNCT
eurjchem-604	159	4	e.g.	e.g.	ADV
eurjchem-604	159	5	cr(co)6	cr(co)6	X
eurjchem-604	159	6	,	,	PUNCT
eurjchem-604	159	7	exhibits	exhibit	VERB
eurjchem-604	159	8	only	only	ADV
eurjchem-604	159	9	a	a	DET
eurjchem-604	159	10	single	single	ADJ
eurjchem-604	159	11	νco	νco	NOUN
eurjchem-604	159	12	band	band	NOUN
eurjchem-604	159	13	in	in	ADP
eurjchem-604	159	14	its	its	PRON
eurjchem-604	159	15	ir	ir	NOUN
eurjchem-604	159	16	spectrum	spectrum	NOUN
eurjchem-604	159	17	.	.	PUNCT
eurjchem-604	160	1	spectra	spectra	PROPN
eurjchem-604	160	2	for	for	ADP
eurjchem-604	160	3	complexes	complex	NOUN
eurjchem-604	160	4	of	of	ADP
eurjchem-604	160	5	lower	low	ADJ
eurjchem-604	160	6	symmetry	symmetry	NOUN
eurjchem-604	160	7	are	be	AUX
eurjchem-604	160	8	more	more	ADV
eurjchem-604	160	9	complex	complex	ADJ
eurjchem-604	160	10	.	.	PUNCT
eurjchem-604	161	1	for	for	ADP
eurjchem-604	161	2	example	example	NOUN
eurjchem-604	161	3	,	,	PUNCT
eurjchem-604	161	4	the	the	DET
eurjchem-604	161	5	ir	ir	PROPN
eurjchem-604	161	6	spectrum	spectrum	NOUN
eurjchem-604	161	7	of	of	ADP
eurjchem-604	161	8	fe2(co)9displays	fe2(co)9display	NOUN
eurjchem-604	161	9	co	co	NOUN
eurjchem-604	161	10	bands	band	NOUN
eurjchem-604	161	11	at	at	ADP
eurjchem-604	161	12	2082	2082	NUM
eurjchem-604	161	13	,	,	PUNCT
eurjchem-604	161	14	2019	2019	NUM
eurjchem-604	161	15	and	and	CCONJ
eurjchem-604	161	16	1829	1829	NUM
eurjchem-604	161	17	cm‐1	cm‐1	NOUN
eurjchem-604	161	18	.	.	PUNCT
eurjchem-604	162	1	in	in	ADP
eurjchem-604	162	2	cluster	cluster	NOUN
eurjchem-604	162	3	carbonyls	carbonyls	NOUN
eurjchem-604	162	4	,	,	PUNCT
eurjchem-604	162	5	νco	νco	X
eurjchem-604	162	6	is	be	AUX
eurjchem-604	162	7	a	a	DET
eurjchem-604	162	8	sensitive	sensitive	ADJ
eurjchem-604	162	9	probe	probe	NOUN
eurjchem-604	162	10	for	for	ADP
eurjchem-604	162	11	the	the	DET
eurjchem-604	162	12	co	co	PROPN
eurjchem-604	162	13	coordination	coordination	PROPN
eurjchem-604	162	14	geometry	geometry	NOUN
eurjchem-604	162	15	.	.	PUNCT
eurjchem-604	163	1	for	for	ADP
eurjchem-604	163	2	bridging	bridging	NOUN
eurjchem-604	163	3	(	(	PUNCT
eurjchem-604	163	4	μ2	μ2	NOUN
eurjchem-604	163	5	)	)	PUNCT
eurjchem-604	163	6	ligands	ligand	NOUN
eurjchem-604	163	7	νco	νco	X
eurjchem-604	163	8	is	be	AUX
eurjchem-604	163	9	usually	usually	ADV
eurjchem-604	163	10	shifted	shift	VERB
eurjchem-604	163	11	by	by	ADP
eurjchem-604	163	12	100‐200	100‐200	PROPN
eurjchem-604	163	13	cm‐1	cm‐1	NOUN
eurjchem-604	163	14	to	to	PART
eurjchem-604	163	15	lower	low	ADJ
eurjchem-604	163	16	wavenumbers	wavenumber	NOUN
eurjchem-604	163	17	compared	compare	VERB
eurjchem-604	163	18	to	to	ADP
eurjchem-604	163	19	the	the	DET
eurjchem-604	163	20	signatures	signature	NOUN
eurjchem-604	163	21	of	of	ADP
eurjchem-604	163	22	μ1‐co	μ1‐co	PROPN
eurjchem-604	163	23	.	.	PUNCT
eurjchem-604	164	1	bands	band	NOUN
eurjchem-604	164	2	for	for	ADP
eurjchem-604	164	3	face	face	NOUN
eurjchem-604	164	4	capping	capping	NOUN
eurjchem-604	164	5	(	(	PUNCT
eurjchem-604	164	6	μ3	μ3	ADJ
eurjchem-604	164	7	)	)	PUNCT
eurjchem-604	164	8	co	co	NOUN
eurjchem-604	164	9	ligands	ligand	NOUN
eurjchem-604	164	10	appear	appear	VERB
eurjchem-604	164	11	at	at	ADP
eurjchem-604	164	12	even	even	ADV
eurjchem-604	164	13	lower	low	ADJ
eurjchem-604	164	14	energies	energy	NOUN
eurjchem-604	164	15	.	.	PUNCT
eurjchem-604	165	1	typical	typical	ADJ
eurjchem-604	165	2	values	value	NOUN
eurjchem-604	165	3	for	for	ADP
eurjchem-604	165	4	ir	ir	PROPN
eurjchem-604	165	5	bands	band	NOUN
eurjchem-604	165	6	in	in	ADP
eurjchem-604	165	7	cluster	cluster	NOUN
eurjchem-604	165	8	carbonyls	carbonyls	NOUN
eurjchem-604	165	9	are	be	AUX
eurjchem-604	165	10	given	give	VERB
eurjchem-604	165	11	in	in	ADP
eurjchem-604	165	12	table	table	NOUN
eurjchem-604	165	13	4	4	NUM
eurjchem-604	165	14	[	[	SYM
eurjchem-604	165	15	18	18	NUM
eurjchem-604	165	16	]	]	PUNCT
eurjchem-604	165	17	.	.	PUNCT
eurjchem-604	166	1	retracted	retract	VERB
eurjchem-604	166	2	kaushik	kaushik	PROPN
eurjchem-604	166	3	et	et	PROPN
eurjchem-604	166	4	al	al	PROPN
eurjchem-604	166	5	.	.	PUNCT
eurjchem-604	166	6	/	/	SYM
eurjchem-604	166	7	european	european	PROPN
eurjchem-604	166	8	journal	journal	PROPN
eurjchem-604	166	9	of	of	ADP
eurjchem-604	166	10	chemistry	chemistry	NOUN
eurjchem-604	166	11	3	3	NUM
eurjchem-604	166	12	(	(	PUNCT
eurjchem-604	166	13	3	3	NUM
eurjchem-604	166	14	)	)	PUNCT
eurjchem-604	166	15	(	(	PUNCT
eurjchem-604	166	16	2012	2012	NUM
eurjchem-604	166	17	)	)	PUNCT
eurjchem-604	166	18	367‐394	367‐394	NOUN
eurjchem-604	166	19	371	371	NUM
eurjchem-604	166	20	table	table	NOUN
eurjchem-604	166	21	3	3	NUM
eurjchem-604	166	22	.	.	PUNCT
eurjchem-604	166	23	safety	safety	NOUN
eurjchem-604	166	24	information	information	NOUN
eurjchem-604	166	25	of	of	ADP
eurjchem-604	166	26	tungsten	tungsten	NOUN
eurjchem-604	166	27	hexacarbonyl	hexacarbonyl	NOUN
eurjchem-604	166	28	.	.	PUNCT
eurjchem-604	167	1	safety	safety	NOUN
eurjchem-604	167	2	parameter	parameter	PROPN
eurjchem-604	167	3	safety	safety	PROPN
eurjchem-604	167	4	data	datum	NOUN
eurjchem-604	167	5	explanation	explanation	NOUN
eurjchem-604	167	6	symbol	symbol	NOUN
eurjchem-604	167	7	ghs06	ghs06	PROPN
eurjchem-604	167	8	acute	acute	NOUN
eurjchem-604	167	9	toxicity	toxicity	NOUN
eurjchem-604	167	10	(	(	PUNCT
eurjchem-604	167	11	oral	oral	ADJ
eurjchem-604	167	12	,	,	PUNCT
eurjchem-604	167	13	dermal	dermal	ADJ
eurjchem-604	167	14	,	,	PUNCT
eurjchem-604	167	15	inhalation	inhalation	NOUN
eurjchem-604	167	16	)	)	PUNCT
eurjchem-604	167	17	,	,	PUNCT
eurjchem-604	167	18	categories	category	NOUN
eurjchem-604	167	19	1,2,3	1,2,3	NUM
eurjchem-604	167	20	signal	signal	NOUN
eurjchem-604	167	21	word	word	NOUN
eurjchem-604	167	22	danger	danger	NOUN
eurjchem-604	167	23	hazard	hazard	NOUN
eurjchem-604	167	24	statement	statement	NOUN
eurjchem-604	167	25	h301‐h311‐h331	h301‐h311‐h331	PROPN
eurjchem-604	167	26	a.	a.	NOUN
eurjchem-604	167	27	letter	letter	NOUN
eurjchem-604	167	28	"	"	PUNCT
eurjchem-604	167	29	h	h	NOUN
eurjchem-604	167	30	"	"	PUNCT
eurjchem-604	167	31	(	(	PUNCT
eurjchem-604	167	32	for	for	ADP
eurjchem-604	167	33	"	"	PUNCT
eurjchem-604	167	34	hazard	hazard	NOUN
eurjchem-604	167	35	statement	statement	NOUN
eurjchem-604	167	36	"	"	PUNCT
eurjchem-604	167	37	)	)	PUNCT
eurjchem-604	167	38	.	.	PUNCT
eurjchem-604	168	1	b.	b.	PROPN
eurjchem-604	169	1	a	a	DET
eurjchem-604	169	2	number	number	NOUN
eurjchem-604	169	3	‘	'	PUNCT
eurjchem-604	169	4	3	3	NUM
eurjchem-604	169	5	’	'	PUNCT
eurjchem-604	169	6	for	for	ADP
eurjchem-604	169	7	health	health	NOUN
eurjchem-604	169	8	hazard	hazard	NOUN
eurjchem-604	169	9	.	.	PUNCT
eurjchem-604	170	1	c.	c.	NOUN
eurjchem-604	170	2	two	two	NUM
eurjchem-604	170	3	numbers	number	NOUN
eurjchem-604	170	4	‘	'	PUNCT
eurjchem-604	170	5	01	01	NUM
eurjchem-604	170	6	’	'	PUNCT
eurjchem-604	170	7	for	for	ADP
eurjchem-604	170	8	explosive	explosive	ADJ
eurjchem-604	170	9	properties	property	NOUN
eurjchem-604	170	10	(	(	PUNCT
eurjchem-604	170	11	00‐10	00‐10	NUM
eurjchem-604	170	12	)	)	PUNCT
eurjchem-604	170	13	.	.	PUNCT
eurjchem-604	171	1	d.	d.	PROPN
eurjchem-604	171	2	two	two	NUM
eurjchem-604	171	3	numbers	number	NOUN
eurjchem-604	171	4	‘	'	PUNCT
eurjchem-604	171	5	11	11	NUM
eurjchem-604	171	6	’	'	PUNCT
eurjchem-604	171	7	for	for	ADP
eurjchem-604	171	8	acute	acute	NOUN
eurjchem-604	171	9	toxicity	toxicity	NOUN
eurjchem-604	171	10	properties	property	NOUN
eurjchem-604	171	11	(	(	PUNCT
eurjchem-604	171	12	10‐13	10‐13	NOUN
eurjchem-604	171	13	)	)	PUNCT
eurjchem-604	171	14	.	.	PUNCT
eurjchem-604	172	1	e.	e.	PROPN
eurjchem-604	172	2	two	two	NUM
eurjchem-604	172	3	numbers	number	NOUN
eurjchem-604	172	4	‘	'	PUNCT
eurjchem-604	172	5	31	31	NUM
eurjchem-604	172	6	’	'	PUNCT
eurjchem-604	172	7	for	for	ADP
eurjchem-604	172	8	flammability	flammability	NOUN
eurjchem-604	172	9	(	(	PUNCT
eurjchem-604	172	10	codes	code	NOUN
eurjchem-604	172	11	from	from	ADP
eurjchem-604	172	12	20	20	NUM
eurjchem-604	172	13	to	to	PART
eurjchem-604	172	14	30	30	NUM
eurjchem-604	172	15	)	)	PUNCT
eurjchem-604	172	16	.	.	PUNCT
eurjchem-604	173	1	precautionary	precautionary	ADJ
eurjchem-604	173	2	statements	statement	NOUN
eurjchem-604	173	3	p261‐p280‐p301	p261‐p280‐p301	PROPN
eurjchem-604	173	4	+	+	CCONJ
eurjchem-604	173	5	p310‐p311	p310‐p311	PROPN
eurjchem-604	173	6	p261	p261	PROPN
eurjchem-604	173	7	avoid	avoid	VERB
eurjchem-604	173	8	breathing	breathe	VERB
eurjchem-604	173	9	dust	dust	NOUN
eurjchem-604	173	10	/	/	SYM
eurjchem-604	173	11	fume	fume	NOUN
eurjchem-604	173	12	/	/	SYM
eurjchem-604	173	13	gas	gas	NOUN
eurjchem-604	173	14	/	/	SYM
eurjchem-604	173	15	mist	mist	NOUN
eurjchem-604	173	16	/	/	SYM
eurjchem-604	173	17	vapours	vapour	NOUN
eurjchem-604	173	18	/	/	SYM
eurjchem-604	173	19	spray	spray	NOUN
eurjchem-604	173	20	p280	p280	PROPN
eurjchem-604	173	21	wear	wear	VERB
eurjchem-604	173	22	protective	protective	ADJ
eurjchem-604	173	23	gloves	glove	NOUN
eurjchem-604	173	24	/	/	SYM
eurjchem-604	173	25	protective	protective	ADJ
eurjchem-604	173	26	clothing	clothing	NOUN
eurjchem-604	173	27	/	/	SYM
eurjchem-604	173	28	eye	eye	NOUN
eurjchem-604	173	29	protection	protection	NOUN
eurjchem-604	173	30	/	/	SYM
eurjchem-604	173	31	face	face	NOUN
eurjchem-604	173	32	protection	protection	NOUN
eurjchem-604	173	33	.	.	PUNCT
eurjchem-604	174	1	p301	p301	PROPN
eurjchem-604	174	2	if	if	SCONJ
eurjchem-604	174	3	swallowed	swallow	VERB
eurjchem-604	174	4	:	:	PUNCT
eurjchem-604	174	5	p310	p310	PROPN
eurjchem-604	174	6	immediately	immediately	ADV
eurjchem-604	174	7	call	call	VERB
eurjchem-604	174	8	a	a	DET
eurjchem-604	174	9	poison	poison	NOUN
eurjchem-604	174	10	center	center	NOUN
eurjchem-604	174	11	or	or	CCONJ
eurjchem-604	174	12	doctor	doctor	NOUN
eurjchem-604	174	13	/	/	SYM
eurjchem-604	174	14	physician	physician	NOUN
eurjchem-604	174	15	.	.	PUNCT
eurjchem-604	175	1	p311	p311	PROPN
eurjchem-604	175	2	call	call	VERB
eurjchem-604	175	3	a	a	DET
eurjchem-604	175	4	poison	poison	NOUN
eurjchem-604	175	5	center	center	NOUN
eurjchem-604	175	6	or	or	CCONJ
eurjchem-604	175	7	doctor	doctor	NOUN
eurjchem-604	175	8	/	/	SYM
eurjchem-604	175	9	physician	physician	NOUN
eurjchem-604	175	10	.	.	PUNCT
eurjchem-604	176	1	hazard	hazard	NOUN
eurjchem-604	176	2	code	code	PROPN
eurjchem-604	176	3	t	t	PROPN
eurjchem-604	176	4	for	for	ADP
eurjchem-604	176	5	‘	'	PUNCT
eurjchem-604	176	6	toxic	toxic	ADJ
eurjchem-604	176	7	’	'	PUNCT
eurjchem-604	176	8	risk	risk	NOUN
eurjchem-604	176	9	statements	statement	NOUN
eurjchem-604	176	10	23/24/25	23/24/25	ADP
eurjchem-604	176	11	23	23	NUM
eurjchem-604	176	12	:	:	PUNCT
eurjchem-604	176	13	toxic	toxic	ADJ
eurjchem-604	176	14	by	by	ADP
eurjchem-604	176	15	inhalation	inhalation	NOUN
eurjchem-604	176	16	24	24	NUM
eurjchem-604	176	17	:	:	PUNCT
eurjchem-604	176	18	toxic	toxic	ADJ
eurjchem-604	176	19	in	in	ADP
eurjchem-604	176	20	contact	contact	NOUN
eurjchem-604	176	21	with	with	ADP
eurjchem-604	176	22	skin	skin	NOUN
eurjchem-604	176	23	25	25	NUM
eurjchem-604	176	24	:	:	SYM
eurjchem-604	176	25	toxic	toxic	ADJ
eurjchem-604	176	26	if	if	SCONJ
eurjchem-604	176	27	swallowed	swallow	VERB
eurjchem-604	176	28	safety	safety	NOUN
eurjchem-604	176	29	statements	statement	NOUN
eurjchem-604	176	30	36/37‐45	36/37‐45	NUM
eurjchem-604	176	31	36	36	NUM
eurjchem-604	176	32	:	:	PUNCT
eurjchem-604	176	33	wear	wear	VERB
eurjchem-604	176	34	suitable	suitable	ADJ
eurjchem-604	176	35	protective	protective	ADJ
eurjchem-604	176	36	clothing	clothing	NOUN
eurjchem-604	176	37	37	37	NUM
eurjchem-604	176	38	:	:	PUNCT
eurjchem-604	176	39	wear	wear	VERB
eurjchem-604	176	40	suitable	suitable	ADJ
eurjchem-604	176	41	gloves	glove	NOUN
eurjchem-604	176	42	45	45	NUM
eurjchem-604	176	43	:	:	PUNCT
eurjchem-604	176	44	in	in	ADP
eurjchem-604	176	45	case	case	NOUN
eurjchem-604	176	46	of	of	ADP
eurjchem-604	176	47	accident	accident	NOUN
eurjchem-604	176	48	or	or	CCONJ
eurjchem-604	176	49	if	if	SCONJ
eurjchem-604	176	50	you	you	PRON
eurjchem-604	176	51	feel	feel	VERB
eurjchem-604	176	52	unwell	unwell	ADJ
eurjchem-604	176	53	,	,	PUNCT
eurjchem-604	176	54	seek	seek	VERB
eurjchem-604	176	55	medical	medical	ADJ
eurjchem-604	176	56	advice	advice	NOUN
eurjchem-604	176	57	immediately	immediately	ADV
eurjchem-604	176	58	(	(	PUNCT
eurjchem-604	176	59	show	show	VERB
eurjchem-604	176	60	label	label	NOUN
eurjchem-604	176	61	where	where	SCONJ
eurjchem-604	176	62	possible	possible	ADJ
eurjchem-604	176	63	)	)	PUNCT
eurjchem-604	176	64	table	table	NOUN
eurjchem-604	176	65	4	4	NUM
eurjchem-604	176	66	.	.	PUNCT
eurjchem-604	176	67	typical	typical	ADJ
eurjchem-604	176	68	ir‐bands	ir‐band	NOUN
eurjchem-604	176	69	for	for	ADP
eurjchem-604	176	70	νco	νco	NOUN
eurjchem-604	176	71	in	in	ADP
eurjchem-604	176	72	cluster	cluster	NOUN
eurjchem-604	176	73	carbonyls	carbonyls	NOUN
eurjchem-604	176	74	.	.	PUNCT
eurjchem-604	177	1	compound	compound	NOUN
eurjchem-604	177	2	νco	νco	NOUN
eurjchem-604	177	3	(	(	PUNCT
eurjchem-604	177	4	cm‐1	cm‐1	NOUN
eurjchem-604	177	5	)	)	PUNCT
eurjchem-604	177	6	co	co	NOUN
eurjchem-604	177	7	2143	2143	NUM
eurjchem-604	178	1	[	[	X
eurjchem-604	178	2	ti(co)6]‐2	ti(co)6]‐2	PROPN
eurjchem-604	178	3	1748	1748	NUM
eurjchem-604	178	4	[	[	X
eurjchem-604	178	5	v(co)6]‐	v(co)6]‐	NOUN
eurjchem-604	178	6	1859	1859	NUM
eurjchem-604	178	7	[	[	X
eurjchem-604	178	8	cr(co)6	cr(co)6	X
eurjchem-604	178	9	]	]	PUNCT
eurjchem-604	178	10	2000	2000	NUM
eurjchem-604	179	1	[	[	X
eurjchem-604	179	2	mn(co)6]+	mn(co)6]+	NOUN
eurjchem-604	179	3	2100	2100	NUM
eurjchem-604	179	4	[	[	X
eurjchem-604	179	5	fe(co)6]2	fe(co)6]2	X
eurjchem-604	179	6	+	+	CCONJ
eurjchem-604	179	7	2204	2204	NUM
eurjchem-604	179	8	[	[	X
eurjchem-604	179	9	fe(co)5	fe(co)5	X
eurjchem-604	179	10	]	]	X
eurjchem-604	179	11	2022	2022	NUM
eurjchem-604	179	12	,	,	PUNCT
eurjchem-604	179	13	2000	2000	NUM
eurjchem-604	179	14	as	as	SCONJ
eurjchem-604	179	15	one	one	PRON
eurjchem-604	179	16	goes	go	VERB
eurjchem-604	179	17	from	from	ADP
eurjchem-604	179	18	a	a	DET
eurjchem-604	179	19	terminal	terminal	ADJ
eurjchem-604	179	20	co‐bonding	co‐bonde	VERB
eurjchem-604	179	21	mode	mode	NOUN
eurjchem-604	179	22	to	to	ADP
eurjchem-604	179	23	2‐	2‐	NUM
eurjchem-604	179	24	bridging	bridging	NOUN
eurjchem-604	179	25	and	and	CCONJ
eurjchem-604	179	26	finally	finally	ADV
eurjchem-604	179	27	3‐bridging	3‐bridge	VERB
eurjchem-604	179	28	,	,	PUNCT
eurjchem-604	179	29	there	there	PRON
eurjchem-604	179	30	is	be	VERB
eurjchem-604	179	31	a	a	DET
eurjchem-604	179	32	relatively	relatively	ADV
eurjchem-604	179	33	dramatic	dramatic	ADJ
eurjchem-604	179	34	drop	drop	NOUN
eurjchem-604	179	35	in	in	ADP
eurjchem-604	179	36	the	the	DET
eurjchem-604	179	37	co	co	X
eurjchem-604	179	38	stretching	stretch	VERB
eurjchem-604	179	39	frequency	frequency	NOUN
eurjchem-604	179	40	seen	see	VERB
eurjchem-604	179	41	in	in	ADP
eurjchem-604	179	42	the	the	DET
eurjchem-604	179	43	ir	ir	PROPN
eurjchem-604	179	44	.	.	PROPN
eurjchem-604	179	45	note	note	VERB
eurjchem-604	179	46	that	that	SCONJ
eurjchem-604	179	47	these	these	DET
eurjchem-604	179	48	ranges	range	NOUN
eurjchem-604	179	49	are	be	AUX
eurjchem-604	179	50	typical	typical	ADJ
eurjchem-604	179	51	for	for	ADP
eurjchem-604	179	52	“	"	PUNCT
eurjchem-604	179	53	neutral	neutral	ADJ
eurjchem-604	179	54	”	"	PUNCT
eurjchem-604	179	55	transition	transition	NOUN
eurjchem-604	179	56	metal	metal	NOUN
eurjchem-604	179	57	complexes	complex	NOUN
eurjchem-604	179	58	with	with	ADP
eurjchem-604	179	59	an	an	DET
eurjchem-604	179	60	average	average	ADJ
eurjchem-604	179	61	amount	amount	NOUN
eurjchem-604	179	62	of	of	ADP
eurjchem-604	179	63	electron	electron	NOUN
eurjchem-604	179	64	density	density	NOUN
eurjchem-604	179	65	on	on	ADP
eurjchem-604	179	66	the	the	DET
eurjchem-604	179	67	metal	metal	NOUN
eurjchem-604	179	68	center	center	NOUN
eurjchem-604	179	69	(	(	PUNCT
eurjchem-604	179	70	table	table	NOUN
eurjchem-604	179	71	5	5	NUM
eurjchem-604	179	72	)	)	PUNCT
eurjchem-604	179	73	.	.	PUNCT
eurjchem-604	180	1	bridging	bridge	VERB
eurjchem-604	180	2	carbonyls	carbonyls	NOUN
eurjchem-604	180	3	tend	tend	VERB
eurjchem-604	180	4	to	to	PART
eurjchem-604	180	5	have	have	VERB
eurjchem-604	180	6	weaker	weak	ADJ
eurjchem-604	180	7	and	and	CCONJ
eurjchem-604	180	8	broader	broad	ADJ
eurjchem-604	180	9	ir	ir	PROPN
eurjchem-604	180	10	bands	band	NOUN
eurjchem-604	180	11	.	.	PUNCT
eurjchem-604	181	1	table	table	NOUN
eurjchem-604	181	2	5	5	NUM
eurjchem-604	181	3	.	.	PUNCT
eurjchem-604	182	1	detecting	detect	VERB
eurjchem-604	182	2	effect	effect	NOUN
eurjchem-604	182	3	of	of	ADP
eurjchem-604	182	4	electron	electron	NOUN
eurjchem-604	182	5	density	density	NOUN
eurjchem-604	182	6	on	on	ADP
eurjchem-604	182	7	metal	metal	NOUN
eurjchem-604	182	8	.	.	PUNCT
eurjchem-604	183	1	dx	dx	PROPN
eurjchem-604	183	2	complex	complex	ADJ
eurjchem-604	183	3	νco(cm‐1	νco(cm‐1	NOUN
eurjchem-604	183	4	)	)	PUNCT
eurjchem-604	183	5	free	free	ADJ
eurjchem-604	183	6	co	co	NOUN
eurjchem-604	183	7	2143	2143	PROPN
eurjchem-604	183	8	d10	d10	PROPN
eurjchem-604	184	1	[	[	X
eurjchem-604	184	2	ag(co)]+	ag(co)]+	X
eurjchem-604	184	3	2204	2204	NUM
eurjchem-604	184	4	[	[	X
eurjchem-604	184	5	ni(co)4	ni(co)4	X
eurjchem-604	184	6	]	]	X
eurjchem-604	184	7	2060	2060	NUM
eurjchem-604	185	1	[	[	X
eurjchem-604	185	2	co(co)4]‐	co(co)4]‐	PROPN
eurjchem-604	185	3	1890	1890	NUM
eurjchem-604	186	1	[	[	X
eurjchem-604	186	2	fe(co)4]2‐	fe(co)4]2‐	NOUN
eurjchem-604	186	3	1790	1790	NUM
eurjchem-604	186	4	[	[	X
eurjchem-604	186	5	mn(co)6]+	mn(co)6]+	NOUN
eurjchem-604	186	6	2090	2090	NUM
eurjchem-604	186	7	d6	d6	NOUN
eurjchem-604	186	8	[	[	X
eurjchem-604	186	9	cr(co)6	cr(co)6	X
eurjchem-604	186	10	]	]	PUNCT
eurjchem-604	186	11	2000	2000	NUM
eurjchem-604	187	1	[	[	X
eurjchem-604	187	2	v(co)6]‐	v(co)6]‐	X
eurjchem-604	187	3	1860	1860	NUM
eurjchem-604	187	4	as	as	ADP
eurjchem-604	187	5	the	the	DET
eurjchem-604	187	6	electron	electron	NOUN
eurjchem-604	187	7	density	density	NOUN
eurjchem-604	187	8	on	on	ADP
eurjchem-604	187	9	a	a	DET
eurjchem-604	187	10	metal	metal	NOUN
eurjchem-604	187	11	center	center	NOUN
eurjchem-604	187	12	increases	increase	NOUN
eurjchem-604	187	13	,	,	PUNCT
eurjchem-604	187	14	more	more	ADV
eurjchem-604	187	15	π‐	π‐	ADJ
eurjchem-604	187	16	back	back	ADV
eurjchem-604	187	17	bonding	bonding	NOUN
eurjchem-604	187	18	to	to	ADP
eurjchem-604	187	19	the	the	DET
eurjchem-604	187	20	co	co	ADJ
eurjchem-604	187	21	ligand(s	ligand(s	PROPN
eurjchem-604	187	22	)	)	PUNCT
eurjchem-604	187	23	takes	take	VERB
eurjchem-604	187	24	place	place	NOUN
eurjchem-604	187	25	.	.	PUNCT
eurjchem-604	188	1	this	this	DET
eurjchem-604	188	2	futher	futher	NOUN
eurjchem-604	188	3	weakens	weaken	VERB
eurjchem-604	188	4	the	the	DET
eurjchem-604	188	5	c‐o	c‐o	NOUN
eurjchem-604	188	6	bond	bond	NOUN
eurjchem-604	188	7	by	by	ADP
eurjchem-604	188	8	pumping	pump	VERB
eurjchem-604	188	9	more	more	ADJ
eurjchem-604	188	10	electron	electron	NOUN
eurjchem-604	188	11	density	density	NOUN
eurjchem-604	188	12	into	into	ADP
eurjchem-604	188	13	the	the	DET
eurjchem-604	188	14	formally	formally	ADV
eurjchem-604	188	15	empty	empty	ADJ
eurjchem-604	188	16	carbonyl	carbonyl	NOUN
eurjchem-604	188	17	π	π	PROPN
eurjchem-604	188	18	*	*	NOUN
eurjchem-604	188	19	orbital	orbital	ADJ
eurjchem-604	188	20	.	.	PUNCT
eurjchem-604	189	1	this	this	PRON
eurjchem-604	189	2	increases	increase	VERB
eurjchem-604	189	3	the	the	DET
eurjchem-604	189	4	m‐co	m‐co	PROPN
eurjchem-604	189	5	bond	bond	NOUN
eurjchem-604	189	6	strength	strength	NOUN
eurjchem-604	189	7	making	make	VERB
eurjchem-604	189	8	it	it	PRON
eurjchem-604	189	9	more	more	ADV
eurjchem-604	189	10	double‐bond‐like	double‐bond‐like	ADJ
eurjchem-604	189	11	,	,	PUNCT
eurjchem-604	189	12	i.e.	i.e.	X
eurjchem-604	189	13	,	,	PUNCT
eurjchem-604	189	14	the	the	DET
eurjchem-604	189	15	resonance	resonance	NOUN
eurjchem-604	189	16	structure	structure	NOUN
eurjchem-604	189	17	m	m	PROPN
eurjchem-604	189	18	=	=	NOUN
eurjchem-604	189	19	c	c	AUX
eurjchem-604	189	20	=	=	NOUN
eurjchem-604	189	21	o	o	NOUN
eurjchem-604	189	22	assumes	assume	VERB
eurjchem-604	189	23	more	more	ADJ
eurjchem-604	189	24	importance	importance	NOUN
eurjchem-604	189	25	.	.	PUNCT
eurjchem-604	190	1	this	this	PRON
eurjchem-604	190	2	can	can	AUX
eurjchem-604	190	3	clearly	clearly	ADV
eurjchem-604	190	4	be	be	AUX
eurjchem-604	190	5	seen	see	VERB
eurjchem-604	190	6	on	on	ADP
eurjchem-604	190	7	table	table	NOUN
eurjchem-604	190	8	6	6	NUM
eurjchem-604	190	9	that	that	PRON
eurjchem-604	190	10	illustrates	illustrate	VERB
eurjchem-604	190	11	the	the	DET
eurjchem-604	190	12	effect	effect	NOUN
eurjchem-604	190	13	of	of	ADP
eurjchem-604	190	14	charge	charge	NOUN
eurjchem-604	190	15	and	and	CCONJ
eurjchem-604	190	16	electronegativity	electronegativity	NOUN
eurjchem-604	190	17	on	on	ADP
eurjchem-604	190	18	the	the	DET
eurjchem-604	190	19	amount	amount	NOUN
eurjchem-604	190	20	of	of	ADP
eurjchem-604	190	21	metal	metal	NOUN
eurjchem-604	190	22	to	to	PART
eurjchem-604	190	23	co	co	VERB
eurjchem-604	190	24	π‐	π‐	VERB
eurjchem-604	190	25	back	back	ADP
eurjchem-604	190	26	bonding	bonding	NOUN
eurjchem-604	190	27	and	and	CCONJ
eurjchem-604	190	28	the	the	DET
eurjchem-604	190	29	co	co	ADJ
eurjchem-604	190	30	ir	ir	PROPN
eurjchem-604	190	31	stretching	stretch	VERB
eurjchem-604	190	32	frequency	frequency	NOUN
eurjchem-604	190	33	.	.	PUNCT
eurjchem-604	191	1	table	table	NOUN
eurjchem-604	191	2	6	6	NUM
eurjchem-604	191	3	.	.	PUNCT
eurjchem-604	192	1	detection	detection	NOUN
eurjchem-604	192	2	of	of	ADP
eurjchem-604	192	3	ligand	ligand	ADJ
eurjchem-604	192	4	donation	donation	NOUN
eurjchem-604	192	5	effects	effect	NOUN
eurjchem-604	192	6	.	.	PUNCT
eurjchem-604	193	1	complex	complex	ADJ
eurjchem-604	193	2	νco(cm‐1	νco(cm‐1	NOUN
eurjchem-604	193	3	)	)	PUNCT
eurjchem-604	193	4	mo(co)3(pf3)3	mo(co)3(pf3)3	VERB
eurjchem-604	193	5	2090	2090	NUM
eurjchem-604	193	6	,	,	PUNCT
eurjchem-604	193	7	2055	2055	NUM
eurjchem-604	193	8	mo(co)3(pcl3)3	mo(co)3(pcl3)3	NOUN
eurjchem-604	193	9	2040	2040	NUM
eurjchem-604	193	10	,	,	PUNCT
eurjchem-604	193	11	1991	1991	NUM
eurjchem-604	193	12	mo(co)3	mo(co)3	NOUN
eurjchem-604	194	1	[	[	X
eurjchem-604	194	2	p(ome)3]3	p(ome)3]3	ADJ
eurjchem-604	194	3	1977	1977	NUM
eurjchem-604	194	4	,	,	PUNCT
eurjchem-604	194	5	1888	1888	NUM
eurjchem-604	194	6	mo(co)3(pph3)3	mo(co)3(pph3)3	ADJ
eurjchem-604	194	7	1934	1934	NUM
eurjchem-604	194	8	,	,	PUNCT
eurjchem-604	194	9	1835	1835	NUM
eurjchem-604	194	10	mo(co)3(ncch3)3	mo(co)3(ncch3)3	VERB
eurjchem-604	194	11	1915	1915	NUM
eurjchem-604	194	12	,	,	PUNCT
eurjchem-604	194	13	1783	1783	NUM
eurjchem-604	194	14	mo(co)3(triamine)3	mo(co)3(triamine)3	PROPN
eurjchem-604	194	15	1898	1898	NUM
eurjchem-604	194	16	,	,	PUNCT
eurjchem-604	194	17	1758	1758	NUM
eurjchem-604	194	18	mo(co)3(pyridine)3	mo(co)3(pyridine)3	PROPN
eurjchem-604	194	19	1888	1888	NUM
eurjchem-604	194	20	,	,	PUNCT
eurjchem-604	194	21	1746	1746	NUM
eurjchem-604	194	22	the	the	DET
eurjchem-604	194	23	ability	ability	NOUN
eurjchem-604	194	24	of	of	ADP
eurjchem-604	194	25	the	the	DET
eurjchem-604	194	26	ligands	ligand	NOUN
eurjchem-604	194	27	on	on	ADP
eurjchem-604	194	28	a	a	DET
eurjchem-604	194	29	metal	metal	NOUN
eurjchem-604	194	30	to	to	PART
eurjchem-604	194	31	donate	donate	VERB
eurjchem-604	194	32	electron	electron	NOUN
eurjchem-604	194	33	density	density	NOUN
eurjchem-604	194	34	to	to	ADP
eurjchem-604	194	35	the	the	DET
eurjchem-604	194	36	metal	metal	NOUN
eurjchem-604	194	37	center	center	NOUN
eurjchem-604	194	38	certainly	certainly	ADV
eurjchem-604	194	39	has	have	VERB
eurjchem-604	194	40	considerable	considerable	ADJ
eurjchem-604	194	41	effect	effect	NOUN
eurjchem-604	194	42	on	on	ADP
eurjchem-604	194	43	the	the	DET
eurjchem-604	194	44	absolute	absolute	ADJ
eurjchem-604	194	45	amount	amount	NOUN
eurjchem-604	194	46	of	of	ADP
eurjchem-604	194	47	electron	electron	NOUN
eurjchem-604	194	48	density	density	NOUN
eurjchem-604	194	49	on	on	ADP
eurjchem-604	194	50	that	that	DET
eurjchem-604	194	51	metal	metal	NOUN
eurjchem-604	194	52	.	.	PUNCT
eurjchem-604	195	1	this	this	PRON
eurjchem-604	195	2	,	,	PUNCT
eurjchem-604	195	3	in	in	ADP
eurjchem-604	195	4	turn	turn	NOUN
eurjchem-604	195	5	,	,	PUNCT
eurjchem-604	195	6	naturally	naturally	ADV
eurjchem-604	195	7	affects	affect	VERB
eurjchem-604	195	8	the	the	PRON
eurjchem-604	195	9	π	π	PROPN
eurjchem-604	195	10	co	co	ADJ
eurjchem-604	195	11	ir	ir	AUX
eurjchem-604	195	12	stretching	stretch	VERB
eurjchem-604	195	13	frequencies	frequency	NOUN
eurjchem-604	195	14	in	in	ADP
eurjchem-604	195	15	metal	metal	NOUN
eurjchem-604	195	16	carbonyl	carbonyl	NOUN
eurjchem-604	195	17	complexes	complex	NOUN
eurjchem-604	195	18	.	.	PUNCT
eurjchem-604	196	1	ligands	ligand	NOUN
eurjchem-604	196	2	that	that	PRON
eurjchem-604	196	3	are	be	AUX
eurjchem-604	196	4	trans	tran	NOUN
eurjchem-604	196	5	to	to	ADP
eurjchem-604	196	6	a	a	DET
eurjchem-604	196	7	carbonyl	carbonyl	NOUN
eurjchem-604	196	8	can	can	AUX
eurjchem-604	196	9	have	have	VERB
eurjchem-604	196	10	a	a	DET
eurjchem-604	196	11	particularly	particularly	ADV
eurjchem-604	196	12	large	large	ADJ
eurjchem-604	196	13	effect	effect	NOUN
eurjchem-604	196	14	on	on	ADP
eurjchem-604	196	15	the	the	DET
eurjchem-604	196	16	ability	ability	NOUN
eurjchem-604	196	17	of	of	ADP
eurjchem-604	196	18	the	the	DET
eurjchem-604	196	19	co	co	PROPN
eurjchem-604	196	20	ligand	ligand	NOUN
eurjchem-604	196	21	to	to	ADP
eurjchem-604	196	22	effectively	effectively	ADV
eurjchem-604	196	23	π	π	PROPN
eurjchem-604	196	24	–	–	PUNCT
eurjchem-604	196	25	back	back	ADJ
eurjchem-604	196	26	bond	bond	NOUN
eurjchem-604	196	27	to	to	ADP
eurjchem-604	196	28	the	the	DET
eurjchem-604	196	29	metal	metal	NOUN
eurjchem-604	196	30	.	.	PUNCT
eurjchem-604	197	1	for	for	ADP
eurjchem-604	197	2	example	example	NOUN
eurjchem-604	197	3	2	2	NUM
eurjchem-604	197	4	transπ‐back	transπ‐back	NOUN
eurjchem-604	197	5	bonding	bonding	NOUN
eurjchem-604	197	6	ligands	ligand	NOUN
eurjchem-604	197	7	will	will	AUX
eurjchem-604	197	8	partially	partially	ADV
eurjchem-604	197	9	compete	compete	VERB
eurjchem-604	197	10	for	for	ADP
eurjchem-604	197	11	the	the	DET
eurjchem-604	197	12	same	same	ADJ
eurjchem-604	197	13	d‐orbital	d‐orbital	PUNCT
eurjchem-604	197	14	electron	electron	NOUN
eurjchem-604	197	15	density	density	NOUN
eurjchem-604	197	16	,	,	PUNCT
eurjchem-604	197	17	weakening	weaken	VERB
eurjchem-604	197	18	each	each	DET
eurjchem-604	197	19	others	other	NOUN
eurjchem-604	197	20	net	net	ADJ
eurjchem-604	197	21	m‐l	m‐l	PROPN
eurjchem-604	197	22	π‐back	π‐back	X
eurjchem-604	197	23	bonding	bonding	NOUN
eurjchem-604	197	24	(	(	PUNCT
eurjchem-604	197	25	figure	figure	NOUN
eurjchem-604	197	26	5	5	NUM
eurjchem-604	197	27	)	)	PUNCT
eurjchem-604	197	28	.	.	PUNCT
eurjchem-604	198	1	figure	figure	NOUN
eurjchem-604	198	2	5	5	NUM
eurjchem-604	198	3	.	.	PUNCT
eurjchem-604	198	4	π‐back	π‐back	PUNCT
eurjchem-604	199	1	bonding	bond	VERB
eurjchem-604	199	2	between	between	ADP
eurjchem-604	199	3	metal	metal	NOUN
eurjchem-604	199	4	and	and	CCONJ
eurjchem-604	199	5	co	co	NOUN
eurjchem-604	199	6	ligand	ligand	NOUN
eurjchem-604	199	7	.	.	PUNCT
eurjchem-604	200	1	when	when	SCONJ
eurjchem-604	200	2	the	the	DET
eurjchem-604	200	3	trans	trans	PROPN
eurjchem-604	200	4	ligand	ligand	NOUN
eurjchem-604	200	5	is	be	AUX
eurjchem-604	200	6	a	a	DET
eurjchem-604	200	7	π‐donating	π‐donate	VERB
eurjchem-604	200	8	ligand	ligand	NOUN
eurjchem-604	200	9	,	,	PUNCT
eurjchem-604	200	10	this	this	PRON
eurjchem-604	200	11	can	can	AUX
eurjchem-604	200	12	increase	increase	VERB
eurjchem-604	200	13	the	the	DET
eurjchem-604	200	14	m‐co	m‐co	PROPN
eurjchem-604	200	15	bond	bond	NOUN
eurjchem-604	200	16	strength	strength	NOUN
eurjchem-604	200	17	(	(	PUNCT
eurjchem-604	200	18	more	more	ADJ
eurjchem-604	200	19	m	m	NOUN
eurjchem-604	200	20	=	=	ADJ
eurjchem-604	200	21	c	c	NOUN
eurjchem-604	200	22	=	=	ADJ
eurjchem-604	200	23	o	o	NOUN
eurjchem-604	200	24	character	character	NOUN
eurjchem-604	200	25	)	)	PUNCT
eurjchem-604	200	26	by	by	ADP
eurjchem-604	200	27	allowing	allow	VERB
eurjchem-604	200	28	unimpeded	unimpeded	ADJ
eurjchem-604	200	29	metal	metal	NOUN
eurjchem-604	200	30	to	to	PART
eurjchem-604	200	31	co	co	VERB
eurjchem-604	200	32	π‐back	π‐back	X
eurjchem-604	200	33	bonding	bond	VERB
eurjchem-604	200	34	.	.	PUNCT
eurjchem-604	201	1	pyridine	pyridine	NOUN
eurjchem-604	201	2	and	and	CCONJ
eurjchem-604	201	3	amines	amine	NOUN
eurjchem-604	201	4	are	be	AUX
eurjchem-604	201	5	not	not	PART
eurjchem-604	201	6	that	that	ADV
eurjchem-604	201	7	strong	strong	ADJ
eurjchem-604	201	8	π‐donors	π‐donors	PUNCT
eurjchem-604	201	9	,	,	PUNCT
eurjchem-604	201	10	but	but	CCONJ
eurjchem-604	201	11	they	they	PRON
eurjchem-604	201	12	are	be	AUX
eurjchem-604	201	13	even	even	ADV
eurjchem-604	201	14	worse	bad	ADJ
eurjchem-604	201	15	π	π	PROPN
eurjchem-604	201	16	‐backbonding	‐backbonde	VERB
eurjchem-604	201	17	ligands	ligand	NOUN
eurjchem-604	201	18	.	.	PUNCT
eurjchem-604	202	1	so	so	ADV
eurjchem-604	202	2	the	the	DET
eurjchem-604	202	3	co	co	NOUN
eurjchem-604	202	4	has	have	VERB
eurjchem-604	202	5	virtually	virtually	ADV
eurjchem-604	202	6	no	no	DET
eurjchem-604	202	7	competition	competition	NOUN
eurjchem-604	202	8	for	for	ADP
eurjchem-604	202	9	π‐back	π‐back	NOUN
eurjchem-604	202	10	donation	donation	NOUN
eurjchem-604	202	11	.	.	PUNCT
eurjchem-604	203	1	based	base	VERB
eurjchem-604	203	2	on	on	ADP
eurjchem-604	203	3	co	co	INTJ
eurjchem-604	203	4	ir	ir	PROPN
eurjchem-604	203	5	stretching	stretch	VERB
eurjchem-604	203	6	frequencies	frequency	NOUN
eurjchem-604	203	7	,	,	PUNCT
eurjchem-604	203	8	the	the	DET
eurjchem-604	203	9	following	follow	VERB
eurjchem-604	203	10	ligands	ligand	NOUN
eurjchem-604	203	11	can	can	AUX
eurjchem-604	203	12	be	be	AUX
eurjchem-604	203	13	ranked	rank	VERB
eurjchem-604	203	14	from	from	ADP
eurjchem-604	203	15	best	good	ADJ
eurjchem-604	203	16	π‐acceptor	π‐acceptor	PUNCT
eurjchem-604	203	17	to	to	PART
eurjchem-604	203	18	worst	worst	ADV
eurjchem-604	203	19	:	:	PUNCT
eurjchem-604	203	20	no+	no+	X
eurjchem-604	203	21	>	>	X
eurjchem-604	203	22	co	co	X
eurjchem-604	203	23	>	>	X
eurjchem-604	203	24	pf3	pf3	X
eurjchem-604	203	25	>	>	X
eurjchem-604	203	26	rn≡c	rn≡c	PROPN
eurjchem-604	203	27	>	>	X
eurjchem-604	203	28	pcl3	pcl3	PROPN
eurjchem-604	203	29	>	>	X
eurjchem-604	203	30	p(or)3	p(or)3	PUNCT
eurjchem-604	203	31	>	>	X
eurjchem-604	203	32	pr3	pr3	X
eurjchem-604	203	33	>	>	X
eurjchem-604	203	34	rc≡n	rc≡n	X
eurjchem-604	203	35	>	>	X
eurjchem-604	203	36	nh3	nh3	NUM
eurjchem-604	203	37	metal	metal	NOUN
eurjchem-604	203	38	carbonyls	carbonyls	NOUN
eurjchem-604	203	39	have	have	VERB
eurjchem-604	203	40	the	the	DET
eurjchem-604	203	41	general	general	ADJ
eurjchem-604	203	42	formula	formula	NOUN
eurjchem-604	203	43	mex(co)y	mex(co)y	PROPN
eurjchem-604	203	44	,	,	PUNCT
eurjchem-604	203	45	and	and	CCONJ
eurjchem-604	203	46	are	be	AUX
eurjchem-604	203	47	formed	form	VERB
eurjchem-604	203	48	by	by	ADP
eurjchem-604	203	49	combination	combination	NOUN
eurjchem-604	203	50	of	of	ADP
eurjchem-604	203	51	the	the	DET
eurjchem-604	203	52	metal	metal	NOUN
eurjchem-604	203	53	(	(	PUNCT
eurjchem-604	203	54	me	i	PRON
eurjchem-604	203	55	)	)	PUNCT
eurjchem-604	203	56	with	with	ADP
eurjchem-604	203	57	carbon	carbon	NOUN
eurjchem-604	203	58	monoxide	monoxide	NOUN
eurjchem-604	203	59	(	(	PUNCT
eurjchem-604	203	60	co	co	NOUN
eurjchem-604	203	61	)	)	PUNCT
eurjchem-604	203	62	.	.	PUNCT
eurjchem-604	204	1	most	most	ADJ
eurjchem-604	204	2	are	be	AUX
eurjchem-604	204	3	solids	solid	NOUN
eurjchem-604	204	4	at	at	ADP
eurjchem-604	204	5	ordinary	ordinary	ADJ
eurjchem-604	204	6	temperatures	temperature	NOUN
eurjchem-604	204	7	,	,	PUNCT
eurjchem-604	204	8	but	but	CCONJ
eurjchem-604	204	9	nickel	nickel	NOUN
eurjchem-604	204	10	carbonyl	carbonyl	NOUN
eurjchem-604	204	11	,	,	PUNCT
eurjchem-604	204	12	iron	iron	NOUN
eurjchem-604	204	13	pentacarbonyl	pentacarbonyl	NOUN
eurjchem-604	204	14	and	and	CCONJ
eurjchem-604	204	15	ruthenium	ruthenium	NOUN
eurjchem-604	204	16	pentacarbonyl	pentacarbonyl	NOUN
eurjchem-604	204	17	are	be	AUX
eurjchem-604	204	18	liquids	liquid	NOUN
eurjchem-604	204	19	,	,	PUNCT
eurjchem-604	204	20	and	and	CCONJ
eurjchem-604	204	21	cobalt	cobalt	NOUN
eurjchem-604	204	22	hydrocarbonyl	hydrocarbonyl	NOUN
eurjchem-604	204	23	is	be	AUX
eurjchem-604	204	24	a	a	DET
eurjchem-604	204	25	gas	gas	NOUN
eurjchem-604	204	26	.	.	PUNCT
eurjchem-604	205	1	most	most	ADJ
eurjchem-604	205	2	metal	metal	NOUN
eurjchem-604	205	3	carbonyls	carbonyls	NOUN
eurjchem-604	205	4	react	react	VERB
eurjchem-604	205	5	vigorously	vigorously	ADV
eurjchem-604	205	6	with	with	ADP
eurjchem-604	205	7	oxygen	oxygen	NOUN
eurjchem-604	205	8	and	and	CCONJ
eurjchem-604	205	9	oxidizing	oxidize	VERB
eurjchem-604	205	10	substances	substance	NOUN
eurjchem-604	205	11	,	,	PUNCT
eurjchem-604	205	12	and	and	CCONJ
eurjchem-604	205	13	some	some	PRON
eurjchem-604	205	14	ignite	ignite	VERB
eurjchem-604	205	15	spontaneously	spontaneously	ADV
eurjchem-604	205	16	.	.	PUNCT
eurjchem-604	206	1	1.7	1.7	NUM
eurjchem-604	206	2	.	.	PUNCT
eurjchem-604	206	3	importance	importance	NOUN
eurjchem-604	206	4	of	of	ADP
eurjchem-604	206	5	nmr	nmr	NOUN
eurjchem-604	206	6	spectroscopy	spectroscopy	VERB
eurjchem-604	206	7	in	in	ADP
eurjchem-604	206	8	investigation	investigation	NOUN
eurjchem-604	206	9	of	of	ADP
eurjchem-604	206	10	metal	metal	NOUN
eurjchem-604	206	11	carbonyl	carbonyl	NOUN
eurjchem-604	206	12	complexes	complex	NOUN
eurjchem-604	206	13	nmr	nmr	NOUN
eurjchem-604	206	14	spectroscopy	spectroscopy	NOUN
eurjchem-604	206	15	is	be	AUX
eurjchem-604	206	16	useful	useful	ADJ
eurjchem-604	206	17	for	for	ADP
eurjchem-604	206	18	investigating	investigate	VERB
eurjchem-604	206	19	complexes	complex	NOUN
eurjchem-604	206	20	containing	contain	VERB
eurjchem-604	206	21	spin‐spin	spin‐spin	ADJ
eurjchem-604	206	22	active	active	ADJ
eurjchem-604	206	23	nuclei	nucleus	NOUN
eurjchem-604	206	24	(	(	PUNCT
eurjchem-604	206	25	1h	1h	NUM
eurjchem-604	206	26	,	,	PUNCT
eurjchem-604	206	27	13c	13c	NOUN
eurjchem-604	206	28	,	,	PUNCT
eurjchem-604	206	29	31p	31p	NUM
eurjchem-604	206	30	and19f	and19f	X
eurjchem-604	206	31	etc	etc	X
eurjchem-604	206	32	.	.	X
eurjchem-604	206	33	)	)	PUNCT
eurjchem-604	206	34	.	.	PUNCT
eurjchem-604	207	1	nmr	nmr	NOUN
eurjchem-604	207	2	spectroscopy	spectroscopy	NOUN
eurjchem-604	207	3	is	be	AUX
eurjchem-604	207	4	also	also	ADV
eurjchem-604	207	5	useful	useful	ADJ
eurjchem-604	207	6	in	in	ADP
eurjchem-604	207	7	confirmation	confirmation	NOUN
eurjchem-604	207	8	of	of	ADP
eurjchem-604	207	9	ligands	ligand	NOUN
eurjchem-604	207	10	having	have	VERB
eurjchem-604	207	11	p	p	NOUN
eurjchem-604	207	12	and	and	CCONJ
eurjchem-604	207	13	f	f	PROPN
eurjchem-604	207	14	atoms	atom	NOUN
eurjchem-604	207	15	.	.	PUNCT
eurjchem-604	208	1	nmr	nmr	NOUN
eurjchem-604	208	2	spectroscopy	spectroscopy	NOUN
eurjchem-604	208	3	is	be	AUX
eurjchem-604	208	4	also	also	ADV
eurjchem-604	208	5	useful	useful	ADJ
eurjchem-604	208	6	in	in	ADP
eurjchem-604	208	7	differentiating	differentiate	VERB
eurjchem-604	208	8	the	the	DET
eurjchem-604	208	9	ligands	ligand	NOUN
eurjchem-604	208	10	based	base	VERB
eurjchem-604	208	11	on	on	ADP
eurjchem-604	208	12	alkyl	alkyl	ADJ
eurjchem-604	208	13	/	/	SYM
eurjchem-604	208	14	aryl	aryl	NOUN
eurjchem-604	208	15	groups	group	NOUN
eurjchem-604	208	16	.	.	PUNCT
eurjchem-604	209	1	2	2	X
eurjchem-604	209	2	.	.	X
eurjchem-604	209	3	substitution	substitution	NOUN
eurjchem-604	209	4	reactions	reaction	NOUN
eurjchem-604	209	5	of	of	ADP
eurjchem-604	209	6	metal	metal	NOUN
eurjchem-604	209	7	carbonyl	carbonyl	NOUN
eurjchem-604	209	8	complexes	complex	NOUN
eurjchem-604	209	9	ligand	ligand	NOUN
eurjchem-604	209	10	substitution	substitution	NOUN
eurjchem-604	209	11	reactions	reaction	NOUN
eurjchem-604	209	12	are	be	AUX
eurjchem-604	209	13	essential	essential	ADJ
eurjchem-604	209	14	for	for	ADP
eurjchem-604	209	15	the	the	DET
eurjchem-604	209	16	use	use	NOUN
eurjchem-604	209	17	of	of	ADP
eurjchem-604	209	18	transition	transition	NOUN
eurjchem-604	209	19	metal	metal	NOUN
eurjchem-604	209	20	organometallic	organometallic	ADJ
eurjchem-604	209	21	compounds	compound	NOUN
eurjchem-604	209	22	.	.	PUNCT
eurjchem-604	210	1	therefore	therefore	ADV
eurjchem-604	210	2	,	,	PUNCT
eurjchem-604	210	3	it	it	PRON
eurjchem-604	210	4	is	be	AUX
eurjchem-604	210	5	important	important	ADJ
eurjchem-604	210	6	that	that	SCONJ
eurjchem-604	210	7	we	we	PRON
eurjchem-604	210	8	know	know	VERB
eurjchem-604	210	9	what	what	PRON
eurjchem-604	210	10	factors	factor	NOUN
eurjchem-604	210	11	affect	affect	VERB
eurjchem-604	210	12	the	the	DET
eurjchem-604	210	13	rates	rate	NOUN
eurjchem-604	210	14	of	of	ADP
eurjchem-604	210	15	reaction	reaction	NOUN
eurjchem-604	210	16	and	and	CCONJ
eurjchem-604	210	17	why	why	SCONJ
eurjchem-604	210	18	.	.	PUNCT
eurjchem-604	211	1	much	much	ADJ
eurjchem-604	211	2	information	information	NOUN
eurjchem-604	211	3	,	,	PUNCT
eurjchem-604	211	4	both	both	PRON
eurjchem-604	211	5	qualitative	qualitative	ADJ
eurjchem-604	211	6	and	and	CCONJ
eurjchem-604	211	7	quantitative	quantitative	ADJ
eurjchem-604	211	8	,	,	PUNCT
eurjchem-604	211	9	is	be	AUX
eurjchem-604	211	10	available	available	ADJ
eurjchem-604	211	11	on	on	ADP
eurjchem-604	211	12	the	the	DET
eurjchem-604	211	13	reactivity	reactivity	NOUN
eurjchem-604	211	14	of	of	ADP
eurjchem-604	211	15	organometallic	organometallic	ADJ
eurjchem-604	211	16	compounds	compound	NOUN
eurjchem-604	211	17	[	[	X
eurjchem-604	211	18	19	19	NUM
eurjchem-604	211	19	]	]	PUNCT
eurjchem-604	211	20	.	.	PUNCT
eurjchem-604	212	1	what	what	PRON
eurjchem-604	212	2	is	be	AUX
eurjchem-604	212	3	needed	need	VERB
eurjchem-604	212	4	are	be	AUX
eurjchem-604	212	5	more	more	ADV
eurjchem-604	212	6	detailed	detailed	ADJ
eurjchem-604	212	7	kinetic	kinetic	ADJ
eurjchem-604	212	8	studies	study	NOUN
eurjchem-604	212	9	that	that	PRON
eurjchem-604	212	10	give	give	VERB
eurjchem-604	212	11	information	information	NOUN
eurjchem-604	212	12	on	on	ADP
eurjchem-604	212	13	the	the	DET
eurjchem-604	212	14	mechanisms	mechanism	NOUN
eurjchem-604	212	15	of	of	ADP
eurjchem-604	212	16	ligand	ligand	ADJ
eurjchem-604	212	17	substitution	substitution	NOUN
eurjchem-604	212	18	,	,	PUNCT
eurjchem-604	212	19	and	and	CCONJ
eurjchem-604	212	20	on	on	ADP
eurjchem-604	212	21	what	what	DET
eurjchem-604	212	22	factors	factor	NOUN
eurjchem-604	212	23	contribute	contribute	VERB
eurjchem-604	212	24	to	to	ADP
eurjchem-604	212	25	rates	rate	NOUN
eurjchem-604	212	26	of	of	ADP
eurjchem-604	212	27	reaction	reaction	NOUN
eurjchem-604	212	28	in	in	ADP
eurjchem-604	212	29	these	these	DET
eurjchem-604	212	30	systems	system	NOUN
eurjchem-604	212	31	.	.	PUNCT
eurjchem-604	213	1	studies	study	NOUN
eurjchem-604	213	2	on	on	ADP
eurjchem-604	213	3	different	different	ADJ
eurjchem-604	213	4	types	type	NOUN
eurjchem-604	213	5	of	of	ADP
eurjchem-604	213	6	metal	metal	NOUN
eurjchem-604	213	7	carbonyl	carbonyl	NOUN
eurjchem-604	213	8	substituted	substitute	VERB
eurjchem-604	213	9	systems	system	NOUN
eurjchem-604	213	10	are	be	AUX
eurjchem-604	213	11	described	describe	VERB
eurjchem-604	213	12	here	here	ADV
eurjchem-604	213	13	.	.	PUNCT
eurjchem-604	214	1	retracted	retract	VERB
eurjchem-604	214	2	372	372	NUM
eurjchem-604	214	3	kaushik	kaushik	PROPN
eurjchem-604	214	4	et	et	PROPN
eurjchem-604	214	5	al	al	PROPN
eurjchem-604	214	6	.	.	PUNCT
eurjchem-604	214	7	/	/	SYM
eurjchem-604	214	8	european	european	PROPN
eurjchem-604	214	9	journal	journal	PROPN
eurjchem-604	214	10	of	of	ADP
eurjchem-604	214	11	chemistry	chemistry	NOUN
eurjchem-604	214	12	3	3	NUM
eurjchem-604	214	13	(	(	PUNCT
eurjchem-604	214	14	3	3	NUM
eurjchem-604	214	15	)	)	PUNCT
eurjchem-604	214	16	(	(	PUNCT
eurjchem-604	214	17	2012	2012	NUM
eurjchem-604	214	18	)	)	PUNCT
eurjchem-604	214	19	367‐394	367‐394	NUM
eurjchem-604	214	20	m(co)6	m(co)6	NOUN
eurjchem-604	214	21	are	be	AUX
eurjchem-604	214	22	also	also	ADV
eurjchem-604	214	23	a	a	DET
eurjchem-604	214	24	popular	popular	ADJ
eurjchem-604	214	25	reagent	reagent	NOUN
eurjchem-604	214	26	in	in	ADP
eurjchem-604	214	27	organometallic	organometallic	ADJ
eurjchem-604	214	28	synthesis	synthesis	NOUN
eurjchem-604	215	1	[	[	X
eurjchem-604	215	2	20	20	NUM
eurjchem-604	215	3	]	]	PUNCT
eurjchem-604	215	4	because	because	SCONJ
eurjchem-604	215	5	one	one	NUM
eurjchem-604	215	6	or	or	CCONJ
eurjchem-604	215	7	more	more	ADJ
eurjchem-604	215	8	co	co	NOUN
eurjchem-604	215	9	ligands	ligand	NOUN
eurjchem-604	215	10	can	can	AUX
eurjchem-604	215	11	be	be	AUX
eurjchem-604	215	12	displaced	displace	VERB
eurjchem-604	215	13	by	by	ADP
eurjchem-604	215	14	other	other	ADJ
eurjchem-604	215	15	donor	donor	NOUN
eurjchem-604	215	16	ligands	ligand	NOUN
eurjchem-604	215	17	[	[	X
eurjchem-604	215	18	21	21	NUM
eurjchem-604	215	19	]	]	PUNCT
eurjchem-604	215	20	.	.	PUNCT
eurjchem-604	216	1	subasi	subasi	PROPN
eurjchem-604	216	2	et	et	PROPN
eurjchem-604	216	3	.	.	PUNCT
eurjchem-604	217	1	al	al	PROPN
eurjchem-604	217	2	.	.	PROPN
eurjchem-604	217	3	done	do	VERB
eurjchem-604	217	4	substitution	substitution	NOUN
eurjchem-604	217	5	of	of	ADP
eurjchem-604	217	6	co	co	ADJ
eurjchem-604	217	7	ligand	ligand	NOUN
eurjchem-604	217	8	by	by	ADP
eurjchem-604	217	9	the	the	DET
eurjchem-604	217	10	reaction	reaction	NOUN
eurjchem-604	217	11	of	of	ADP
eurjchem-604	217	12	m(co)5br	m(co)5br	NUM
eurjchem-604	217	13	with	with	ADP
eurjchem-604	217	14	a	a	DET
eurjchem-604	217	15	ligand	ligand	NOUN
eurjchem-604	217	16	(	(	PUNCT
eurjchem-604	217	17	l	l	NOUN
eurjchem-604	217	18	)	)	PUNCT
eurjchem-604	217	19	the	the	DET
eurjchem-604	217	20	products	product	NOUN
eurjchem-604	217	21	of	of	ADP
eurjchem-604	217	22	type	type	NOUN
eurjchem-604	217	23	m(co)4(l)br	m(co)4(l)br	PROPN
eurjchem-604	217	24	formed	form	VERB
eurjchem-604	217	25	which	which	PRON
eurjchem-604	217	26	confirms	confirm	VERB
eurjchem-604	217	27	that	that	SCONJ
eurjchem-604	217	28	the	the	DET
eurjchem-604	217	29	coming	come	VERB
eurjchem-604	217	30	ligand	ligand	NOUN
eurjchem-604	217	31	substitute	substitute	NOUN
eurjchem-604	217	32	the	the	DET
eurjchem-604	217	33	co	co	NOUN
eurjchem-604	217	34	[	[	X
eurjchem-604	217	35	22	22	NUM
eurjchem-604	217	36	]	]	PUNCT
eurjchem-604	217	37	.	.	PUNCT
eurjchem-604	218	1	photolysis	photolysis	NOUN
eurjchem-604	218	2	of	of	ADP
eurjchem-604	218	3	the	the	DET
eurjchem-604	218	4	allenylidene	allenylidene	NOUN
eurjchem-604	218	5	pentacarbonyl	pentacarbonyl	NOUN
eurjchem-604	218	6	chromium	chromium	NOUN
eurjchem-604	218	7	complexes	complex	NOUN
eurjchem-604	218	8	[	[	X
eurjchem-604	218	9	(	(	PUNCT
eurjchem-604	218	10	co)5cr	co)5cr	NOUN
eurjchem-604	218	11	=	=	SYM
eurjchem-604	218	12	c	c	NOUN
eurjchem-604	218	13	=	=	SYM
eurjchem-604	218	14	c	c	NOUN
eurjchem-604	218	15	=	=	NOUN
eurjchem-604	218	16	c(r1)r2	c(r1)r2	NOUN
eurjchem-604	218	17	]	]	PUNCT
eurjchem-604	218	18	(	(	PUNCT
eurjchem-604	218	19	r1	r1	PROPN
eurjchem-604	218	20	=	=	SYM
eurjchem-604	218	21	nme2	nme2	PROPN
eurjchem-604	218	22	,	,	PUNCT
eurjchem-604	218	23	nph2	nph2	PROPN
eurjchem-604	218	24	;	;	PUNCT
eurjchem-604	218	25	r2	r2	PROPN
eurjchem-604	218	26	=	=	SYM
eurjchem-604	218	27	nme2	nme2	PROPN
eurjchem-604	218	28	,	,	PUNCT
eurjchem-604	218	29	ome	ome	PROPN
eurjchem-604	218	30	,	,	PUNCT
eurjchem-604	218	31	ph	ph	NOUN
eurjchem-604	218	32	)	)	PUNCT
eurjchem-604	218	33	in	in	ADP
eurjchem-604	218	34	thf	thf	NOUN
eurjchem-604	218	35	in	in	ADP
eurjchem-604	218	36	the	the	DET
eurjchem-604	218	37	presence	presence	NOUN
eurjchem-604	218	38	of	of	ADP
eurjchem-604	218	39	equimolar	equimolar	NOUN
eurjchem-604	218	40	amounts	amount	NOUN
eurjchem-604	218	41	of	of	ADP
eurjchem-604	218	42	xr3	xr3	PROPN
eurjchem-604	218	43	(	(	PUNCT
eurjchem-604	218	44	xr3	xr3	PROPN
eurjchem-604	218	45	=	=	ADJ
eurjchem-604	218	46	various	various	ADJ
eurjchem-604	218	47	phosphanes	phosphane	NOUN
eurjchem-604	218	48	,	,	PUNCT
eurjchem-604	218	49	p(ome)3	p(ome)3	PROPN
eurjchem-604	218	50	,	,	PUNCT
eurjchem-604	218	51	asph3	asph3	PROPN
eurjchem-604	218	52	,	,	PUNCT
eurjchem-604	218	53	sbph3	sbph3	NOUN
eurjchem-604	218	54	)	)	PUNCT
eurjchem-604	218	55	affords	afford	NOUN
eurjchem-604	218	56	cis‐allenylidene	cis‐allenylidene	NOUN
eurjchem-604	218	57	tetracarbonyl	tetracarbonyl	VERB
eurjchem-604	218	58	xr3	xr3	NOUN
eurjchem-604	218	59	complexes	complex	NOUN
eurjchem-604	218	60	,	,	PUNCT
eurjchem-604	218	61	cis‐	cis‐	NOUN
eurjchem-604	219	1	[	[	X
eurjchem-604	219	2	(	(	PUNCT
eurjchem-604	219	3	co)4(xr3)cr	co)4(xr3)cr	NOUN
eurjchem-604	219	4	=	=	NOUN
eurjchem-604	219	5	c	c	NOUN
eurjchem-604	219	6	=	=	SYM
eurjchem-604	219	7	c	c	NOUN
eurjchem-604	219	8	=	=	NOUN
eurjchem-604	219	9	c(r1)r2	c(r1)r2	NOUN
eurjchem-604	219	10	]	]	PUNCT
eurjchem-604	220	1	[	[	X
eurjchem-604	220	2	23	23	NUM
eurjchem-604	220	3	]	]	PUNCT
eurjchem-604	220	4	.	.	PUNCT
eurjchem-604	221	1	the	the	DET
eurjchem-604	221	2	interaction	interaction	NOUN
eurjchem-604	221	3	between	between	ADP
eurjchem-604	221	4	the	the	DET
eurjchem-604	221	5	cavitands	cavitand	NOUN
eurjchem-604	221	6	,	,	PUNCT
eurjchem-604	221	7	p(iii)‐	p(iii)‐	NUM
eurjchem-604	221	8	phosphocavitands	phosphocavitand	NOUN
eurjchem-604	221	9	,	,	PUNCT
eurjchem-604	221	10	and	and	CCONJ
eurjchem-604	221	11	the	the	DET
eurjchem-604	221	12	cr	cr	PROPN
eurjchem-604	221	13	,	,	PUNCT
eurjchem-604	221	14	mo	mo	PROPN
eurjchem-604	221	15	,	,	PUNCT
eurjchem-604	221	16	w	w	PROPN
eurjchem-604	221	17	,	,	PUNCT
eurjchem-604	221	18	and	and	CCONJ
eurjchem-604	221	19	mn	mn	PROPN
eurjchem-604	221	20	carbonyl	carbonyl	NOUN
eurjchem-604	221	21	complexes	complex	NOUN
eurjchem-604	221	22	found	find	VERB
eurjchem-604	221	23	possibility	possibility	NOUN
eurjchem-604	221	24	of	of	ADP
eurjchem-604	221	25	the	the	DET
eurjchem-604	221	26	directed	direct	VERB
eurjchem-604	221	27	coordination	coordination	NOUN
eurjchem-604	221	28	of	of	ADP
eurjchem-604	221	29	all	all	DET
eurjchem-604	221	30	or	or	CCONJ
eurjchem-604	221	31	some	some	PRON
eurjchem-604	221	32	phosphorus	phosphorus	NOUN
eurjchem-604	221	33	atoms	atom	NOUN
eurjchem-604	221	34	of	of	ADP
eurjchem-604	221	35	the	the	DET
eurjchem-604	221	36	cavitand	cavitand	NOUN
eurjchem-604	221	37	molecules	molecule	NOUN
eurjchem-604	221	38	with	with	ADP
eurjchem-604	221	39	metals	metal	NOUN
eurjchem-604	221	40	(	(	PUNCT
eurjchem-604	221	41	figure	figure	NOUN
eurjchem-604	221	42	6	6	NUM
eurjchem-604	221	43	)	)	PUNCT
eurjchem-604	222	1	[	[	X
eurjchem-604	222	2	24	24	NUM
eurjchem-604	222	3	]	]	PUNCT
eurjchem-604	222	4	.	.	PUNCT
eurjchem-604	223	1	figure	figure	NOUN
eurjchem-604	223	2	6	6	NUM
eurjchem-604	223	3	.	.	PUNCT
eurjchem-604	224	1	the	the	DET
eurjchem-604	224	2	figure	figure	NOUN
eurjchem-604	224	3	illustrating	illustrate	VERB
eurjchem-604	224	4	the	the	DET
eurjchem-604	224	5	formation	formation	NOUN
eurjchem-604	224	6	of	of	ADP
eurjchem-604	224	7	the	the	DET
eurjchem-604	224	8	intramolecular	intramolecular	ADJ
eurjchem-604	224	9	co⋯ph	co⋯ph	ADJ
eurjchem-604	224	10	contact	contact	NOUN
eurjchem-604	224	11	in	in	ADP
eurjchem-604	224	12	phosphocavit	phosphocavit	NOUN
eurjchem-604	224	13	and	and	CCONJ
eurjchem-604	224	14	complex	complex	NOUN
eurjchem-604	224	15	of	of	ADP
eurjchem-604	224	16	molybdenum	molybdenum	NOUN
eurjchem-604	224	17	hexacarbonyl	hexacarbonyl	NOUN
eurjchem-604	225	1	[	[	X
eurjchem-604	225	2	24	24	NUM
eurjchem-604	225	3	]	]	PUNCT
eurjchem-604	225	4	.	.	PUNCT
eurjchem-604	226	1	some	some	DET
eurjchem-604	226	2	ligand‐ligand	ligand‐ligand	NOUN
eurjchem-604	226	3	substitution	substitution	NOUN
eurjchem-604	226	4	reaction	reaction	NOUN
eurjchem-604	226	5	also	also	ADV
eurjchem-604	226	6	been	be	AUX
eurjchem-604	226	7	observed	observe	VERB
eurjchem-604	226	8	.	.	PUNCT
eurjchem-604	227	1	the	the	DET
eurjchem-604	227	2	reaction	reaction	NOUN
eurjchem-604	227	3	of	of	ADP
eurjchem-604	227	4	[	[	X
eurjchem-604	227	5	m(co)4(η2‐c2h2	m(co)4(η2‐c2h2	NOUN
eurjchem-604	227	6	)	)	PUNCT
eurjchem-604	227	7	]	]	PUNCT
eurjchem-604	227	8	(	(	PUNCT
eurjchem-604	227	9	m	m	NOUN
eurjchem-604	227	10	=	=	NOUN
eurjchem-604	227	11	fe	fe	X
eurjchem-604	227	12	,	,	PUNCT
eurjchem-604	227	13	os	os	NOUN
eurjchem-604	227	14	)	)	PUNCT
eurjchem-604	227	15	compounds	compound	VERB
eurjchem-604	227	16	with	with	ADP
eurjchem-604	227	17	[	[	X
eurjchem-604	227	18	(	(	PUNCT
eurjchem-604	227	19	η5‐c5h5)(co)2w≡cc6h5	η5‐c5h5)(co)2w≡cc6h5	ADJ
eurjchem-604	227	20	]	]	PUNCT
eurjchem-604	227	21	proceeds	proceed	NOUN
eurjchem-604	227	22	by	by	ADP
eurjchem-604	227	23	unexpected	unexpected	ADJ
eurjchem-604	227	24	substitution	substitution	NOUN
eurjchem-604	227	25	of	of	ADP
eurjchem-604	227	26	the	the	DET
eurjchem-604	227	27	acetylene	acetylene	NOUN
eurjchem-604	227	28	ligand	ligand	NOUN
eurjchem-604	227	29	by	by	ADP
eurjchem-604	227	30	the	the	DET
eurjchem-604	227	31	w≡cc6h5	w≡cc6h5	PROPN
eurjchem-604	227	32	pseudo‐alkyne	pseudo‐alkyne	ADJ
eurjchem-604	227	33	unit	unit	NOUN
eurjchem-604	227	34	and	and	CCONJ
eurjchem-604	227	35	formation	formation	NOUN
eurjchem-604	227	36	of	of	ADP
eurjchem-604	227	37	[	[	X
eurjchem-604	227	38	mw(μ‐	mw(μ‐	NOUN
eurjchem-604	227	39	cc6h5)(co)6(η5‐c5h5	cc6h5)(co)6(η5‐c5h5	NOUN
eurjchem-604	227	40	)	)	PUNCT
eurjchem-604	227	41	]	]	PUNCT
eurjchem-604	228	1	(	(	PUNCT
eurjchem-604	228	2	m	m	NOUN
eurjchem-604	228	3	=	=	NOUN
eurjchem-604	228	4	fe	fe	X
eurjchem-604	228	5	,	,	PUNCT
eurjchem-604	228	6	1	1	NUM
eurjchem-604	228	7	;	;	PUNCT
eurjchem-604	228	8	os	os	NOUN
eurjchem-604	228	9	,	,	PUNCT
eurjchem-604	228	10	2	2	X
eurjchem-604	228	11	)	)	PUNCT
eurjchem-604	229	1	[	[	X
eurjchem-604	229	2	25	25	NUM
eurjchem-604	229	3	]	]	PUNCT
eurjchem-604	229	4	.	.	PUNCT
eurjchem-604	230	1	the	the	DET
eurjchem-604	230	2	labile	labile	ADJ
eurjchem-604	230	3	complex	complex	NOUN
eurjchem-604	230	4	w(co)5(η2‐btmse	w(co)5(η2‐btmse	NOUN
eurjchem-604	230	5	)	)	PUNCT
eurjchem-604	230	6	undergoes	undergo	VERB
eurjchem-604	230	7	replacement	replacement	NOUN
eurjchem-604	230	8	of	of	ADP
eurjchem-604	230	9	bis(trimethyl	bis(trimethyl	PROPN
eurjchem-604	230	10	silyl)ethyne	silyl)ethyne	PROPN
eurjchem-604	230	11	,	,	PUNCT
eurjchem-604	230	12	btmse	btmse	PROPN
eurjchem-604	230	13	,	,	PUNCT
eurjchem-604	230	14	by	by	ADP
eurjchem-604	230	15	triphenylbismuthine	triphenylbismuthine	NOUN
eurjchem-604	230	16	in	in	ADP
eurjchem-604	230	17	cyclohexane	cyclohexane	NOUN
eurjchem-604	230	18	solution	solution	NOUN
eurjchem-604	230	19	at	at	ADP
eurjchem-604	230	20	an	an	DET
eurjchem-604	230	21	observable	observable	ADJ
eurjchem-604	230	22	rate	rate	NOUN
eurjchem-604	230	23	in	in	ADP
eurjchem-604	230	24	the	the	DET
eurjchem-604	230	25	temperature	temperature	NOUN
eurjchem-604	230	26	range	range	NOUN
eurjchem-604	230	27	of	of	ADP
eurjchem-604	230	28	35‐	35‐	NUM
eurjchem-604	230	29	50	50	NUM
eurjchem-604	230	30	°	°	ADP
eurjchem-604	230	31	c	c	NOUN
eurjchem-604	230	32	yielding	yield	VERB
eurjchem-604	230	33	almost	almost	ADV
eurjchem-604	230	34	solely	solely	ADV
eurjchem-604	230	35	w(co)5(biph3	w(co)5(biph3	NUM
eurjchem-604	230	36	)	)	PUNCT
eurjchem-604	230	37	as	as	ADP
eurjchem-604	230	38	the	the	DET
eurjchem-604	230	39	final	final	ADJ
eurjchem-604	230	40	product	product	NOUN
eurjchem-604	230	41	[	[	X
eurjchem-604	230	42	26	26	NUM
eurjchem-604	230	43	]	]	PUNCT
eurjchem-604	230	44	.	.	PUNCT
eurjchem-604	231	1	2.1	2.1	NUM
eurjchem-604	231	2	.	.	PUNCT
eurjchem-604	231	3	substitution	substitution	NOUN
eurjchem-604	231	4	reactions	reaction	NOUN
eurjchem-604	231	5	of	of	ADP
eurjchem-604	231	6	metal	metal	NOUN
eurjchem-604	231	7	carbonyls	carbonyls	NOUN
eurjchem-604	231	8	in	in	ADP
eurjchem-604	231	9	presence	presence	NOUN
eurjchem-604	231	10	of	of	ADP
eurjchem-604	231	11	decarbonylating	decarbonylate	VERB
eurjchem-604	231	12	agents	agent	NOUN
eurjchem-604	231	13	in	in	ADP
eurjchem-604	231	14	organometallic	organometallic	ADJ
eurjchem-604	231	15	chemistry	chemistry	NOUN
eurjchem-604	231	16	,	,	PUNCT
eurjchem-604	231	17	me3no	me3no	VERB
eurjchem-604	231	18	is	be	AUX
eurjchem-604	231	19	employed	employ	VERB
eurjchem-604	231	20	as	as	ADP
eurjchem-604	231	21	a	a	DET
eurjchem-604	231	22	decarbonylating	decarbonylate	VERB
eurjchem-604	231	23	agent	agent	NOUN
eurjchem-604	231	24	according	accord	VERB
eurjchem-604	231	25	to	to	ADP
eurjchem-604	231	26	the	the	DET
eurjchem-604	231	27	following	follow	VERB
eurjchem-604	231	28	stoichiometry	stoichiometry	NOUN
eurjchem-604	231	29	(	(	PUNCT
eurjchem-604	231	30	scheme	scheme	NOUN
eurjchem-604	231	31	6	6	NUM
eurjchem-604	231	32	)	)	PUNCT
eurjchem-604	231	33	.	.	PUNCT
eurjchem-604	232	1	scheme	scheme	NOUN
eurjchem-604	232	2	6	6	NUM
eurjchem-604	232	3	this	this	DET
eurjchem-604	232	4	reaction	reaction	NOUN
eurjchem-604	232	5	is	be	AUX
eurjchem-604	232	6	used	use	VERB
eurjchem-604	232	7	to	to	PART
eurjchem-604	232	8	decomplex	decomplex	VERB
eurjchem-604	232	9	organic	organic	ADJ
eurjchem-604	232	10	ligands	ligand	NOUN
eurjchem-604	232	11	from	from	ADP
eurjchem-604	232	12	metals	metal	NOUN
eurjchem-604	232	13	,	,	PUNCT
eurjchem-604	232	14	e.	e.	PROPN
eurjchem-604	232	15	g.	g.	PROPN
eurjchem-604	232	16	from	from	ADP
eurjchem-604	232	17	(	(	PUNCT
eurjchem-604	232	18	diene)fe(co)3	diene)fe(co)3	PROPN
eurjchem-604	232	19	[	[	X
eurjchem-604	232	20	27	27	NUM
eurjchem-604	232	21	]	]	PUNCT
eurjchem-604	232	22	.	.	PUNCT
eurjchem-604	233	1	it	it	PRON
eurjchem-604	233	2	is	be	AUX
eurjchem-604	233	3	also	also	ADV
eurjchem-604	233	4	used	use	VERB
eurjchem-604	233	5	in	in	ADP
eurjchem-604	233	6	certain	certain	ADJ
eurjchem-604	233	7	oxidation	oxidation	NOUN
eurjchem-604	233	8	reactions	reaction	NOUN
eurjchem-604	233	9	,	,	PUNCT
eurjchem-604	233	10	e.	e.	PROPN
eurjchem-604	233	11	g.	g.	PROPN
eurjchem-604	233	12	the	the	DET
eurjchem-604	233	13	conversion	conversion	NOUN
eurjchem-604	233	14	of	of	ADP
eurjchem-604	233	15	alkyl	alkyl	ADJ
eurjchem-604	233	16	iodides	iodide	NOUN
eurjchem-604	233	17	to	to	ADP
eurjchem-604	233	18	the	the	DET
eurjchem-604	233	19	aldehyde	aldehyde	NOUN
eurjchem-604	233	20	[	[	X
eurjchem-604	233	21	28	28	NUM
eurjchem-604	233	22	]	]	PUNCT
eurjchem-604	233	23	.	.	PUNCT
eurjchem-604	234	1	me3no	me3no	VERB
eurjchem-604	234	2	induced	induce	VERB
eurjchem-604	234	3	substitution	substitution	NOUN
eurjchem-604	234	4	reactions	reaction	NOUN
eurjchem-604	234	5	of	of	ADP
eurjchem-604	234	6	(	(	PUNCT
eurjchem-604	234	7	ƞ5‐	ƞ5‐	NOUN
eurjchem-604	234	8	c5h5)momn(co)8	c5h5)momn(co)8	NOUN
eurjchem-604	234	9	with	with	ADP
eurjchem-604	234	10	p(ome)3	p(ome)3	PROPN
eurjchem-604	234	11	and	and	CCONJ
eurjchem-604	234	12	t‐bunc	t‐bunc	PUNCT
eurjchem-604	234	13	results	result	NOUN
eurjchem-604	234	14	in	in	ADP
eurjchem-604	234	15	facile	facile	ADJ
eurjchem-604	234	16	mo‐	mo‐	ADJ
eurjchem-604	234	17	‐‐mn	‐‐mn	NUM
eurjchem-604	234	18	bond	bond	NOUN
eurjchem-604	234	19	cleavage	cleavage	NOUN
eurjchem-604	234	20	products	product	NOUN
eurjchem-604	234	21	as	as	ADV
eurjchem-604	234	22	well	well	ADV
eurjchem-604	234	23	as	as	ADP
eurjchem-604	234	24	the	the	DET
eurjchem-604	234	25	synthesis	synthesis	NOUN
eurjchem-604	234	26	of	of	ADP
eurjchem-604	234	27	(	(	PUNCT
eurjchem-604	234	28	ƞ5‐	ƞ5‐	NOUN
eurjchem-604	234	29	c5h5)mo(co)3mn(co)4	c5h5)mo(co)3mn(co)4	NOUN
eurjchem-604	234	30	[	[	X
eurjchem-604	234	31	p(ome)3	p(ome)3	X
eurjchem-604	234	32	]	]	PUNCT
eurjchem-604	234	33	in	in	ADP
eurjchem-604	234	34	which	which	PRON
eurjchem-604	234	35	p(ome)3	p(ome)3	PRON
eurjchem-604	234	36	occupies	occupy	VERB
eurjchem-604	234	37	a	a	DET
eurjchem-604	234	38	site	site	NOUN
eurjchem-604	234	39	trans	tran	NOUN
eurjchem-604	234	40	to	to	ADP
eurjchem-604	234	41	the	the	DET
eurjchem-604	234	42	mo‐‐‐mn	mo‐‐‐mn	ADJ
eurjchem-604	234	43	bond	bond	NOUN
eurjchem-604	234	44	[	[	X
eurjchem-604	234	45	29	29	NUM
eurjchem-604	234	46	]	]	PUNCT
eurjchem-604	234	47	.	.	PUNCT
eurjchem-604	235	1	2.2	2.2	NUM
eurjchem-604	235	2	.	.	PUNCT
eurjchem-604	235	3	photochemically	photochemically	ADV
eurjchem-604	235	4	induced	induce	VERB
eurjchem-604	235	5	substitution	substitution	NOUN
eurjchem-604	235	6	reactions	reaction	NOUN
eurjchem-604	235	7	of	of	ADP
eurjchem-604	235	8	metal	metal	NOUN
eurjchem-604	235	9	carbonyls	carbonyls	NOUN
eurjchem-604	235	10	during	during	ADP
eurjchem-604	235	11	early	early	ADJ
eurjchem-604	235	12	1960	1960	NUM
eurjchem-604	235	13	’s	’s	PART
eurjchem-604	235	14	strohmeier	strohmeier	NOUN
eurjchem-604	236	1	[	[	X
eurjchem-604	236	2	30	30	NUM
eurjchem-604	236	3	]	]	PUNCT
eurjchem-604	236	4	published	publish	VERB
eurjchem-604	236	5	several	several	ADJ
eurjchem-604	236	6	papers	paper	NOUN
eurjchem-604	236	7	on	on	ADP
eurjchem-604	236	8	photochemical	photochemical	ADJ
eurjchem-604	236	9	substitution	substitution	NOUN
eurjchem-604	236	10	reaction	reaction	NOUN
eurjchem-604	236	11	of	of	ADP
eurjchem-604	236	12	metal	metal	NOUN
eurjchem-604	236	13	carbonyls	carbonyls	NOUN
eurjchem-604	236	14	with	with	ADP
eurjchem-604	236	15	their	their	PRON
eurjchem-604	236	16	derivatives	derivative	NOUN
eurjchem-604	236	17	.	.	PUNCT
eurjchem-604	237	1	later	later	ADV
eurjchem-604	237	2	additional	additional	ADJ
eurjchem-604	237	3	interest	interest	NOUN
eurjchem-604	237	4	in	in	ADP
eurjchem-604	237	5	photolysis	photolysis	NOUN
eurjchem-604	237	6	of	of	ADP
eurjchem-604	237	7	group	group	NOUN
eurjchem-604	237	8	vi	vi	PROPN
eurjchem-604	237	9	metal	metal	NOUN
eurjchem-604	237	10	carbonyls	carbonyls	NOUN
eurjchem-604	237	11	developed	develop	VERB
eurjchem-604	237	12	among	among	ADP
eurjchem-604	237	13	various	various	ADJ
eurjchem-604	237	14	scientists	scientist	NOUN
eurjchem-604	237	15	[	[	X
eurjchem-604	237	16	31‐37	31‐37	NOUN
eurjchem-604	237	17	]	]	PUNCT
eurjchem-604	237	18	.	.	PUNCT
eurjchem-604	238	1	most	most	ADJ
eurjchem-604	238	2	of	of	ADP
eurjchem-604	238	3	these	these	DET
eurjchem-604	238	4	studies	study	NOUN
eurjchem-604	238	5	have	have	AUX
eurjchem-604	238	6	centered	center	VERB
eurjchem-604	238	7	around	around	ADP
eurjchem-604	238	8	the	the	DET
eurjchem-604	238	9	photolysis	photolysis	NOUN
eurjchem-604	238	10	of	of	ADP
eurjchem-604	238	11	parent	parent	NOUN
eurjchem-604	238	12	hexacarbonyls	hexacarbonyls	NOUN
eurjchem-604	238	13	and	and	CCONJ
eurjchem-604	238	14	the	the	DET
eurjchem-604	238	15	nature	nature	NOUN
eurjchem-604	238	16	of	of	ADP
eurjchem-604	238	17	the	the	DET
eurjchem-604	238	18	species	specie	NOUN
eurjchem-604	238	19	m(co)5	m(co)5	PROPN
eurjchem-604	238	20	generated	generate	VERB
eurjchem-604	238	21	in	in	ADP
eurjchem-604	238	22	these	these	DET
eurjchem-604	238	23	reactions	reaction	NOUN
eurjchem-604	238	24	.	.	PUNCT
eurjchem-604	239	1	the	the	DET
eurjchem-604	239	2	metal	metal	NOUN
eurjchem-604	239	3	carbonyl	carbonyl	NOUN
eurjchem-604	239	4	complexes	complex	NOUN
eurjchem-604	239	5	show	show	VERB
eurjchem-604	239	6	photochemical	photochemical	ADJ
eurjchem-604	239	7	substitution	substitution	NOUN
eurjchem-604	239	8	reaction	reaction	NOUN
eurjchem-604	239	9	proved	prove	VERB
eurjchem-604	239	10	earlier	early	ADV
eurjchem-604	239	11	[	[	X
eurjchem-604	239	12	38	38	NUM
eurjchem-604	239	13	]	]	PUNCT
eurjchem-604	239	14	.	.	PUNCT
eurjchem-604	240	1	it	it	PRON
eurjchem-604	240	2	has	have	AUX
eurjchem-604	240	3	long	long	ADV
eurjchem-604	240	4	been	be	AUX
eurjchem-604	240	5	known	know	VERB
eurjchem-604	240	6	that	that	SCONJ
eurjchem-604	240	7	metal	metal	NOUN
eurjchem-604	240	8	carbonyl	carbonyl	NOUN
eurjchem-604	240	9	compounds	compound	NOUN
eurjchem-604	240	10	eliminate	eliminate	VERB
eurjchem-604	240	11	a	a	DET
eurjchem-604	240	12	co	co	NOUN
eurjchem-604	240	13	group	group	NOUN
eurjchem-604	240	14	on	on	ADP
eurjchem-604	240	15	photolysis	photolysis	NOUN
eurjchem-604	240	16	in	in	ADP
eurjchem-604	240	17	uv	uv	NOUN
eurjchem-604	240	18	[	[	X
eurjchem-604	240	19	39	39	NUM
eurjchem-604	240	20	]	]	PUNCT
eurjchem-604	240	21	.	.	PUNCT
eurjchem-604	241	1	many	many	ADJ
eurjchem-604	241	2	metal	metal	NOUN
eurjchem-604	241	3	carbonyls	carbonyls	NOUN
eurjchem-604	241	4	are	be	AUX
eurjchem-604	241	5	photo‐activatable	photo‐activatable	ADJ
eurjchem-604	241	6	.	.	PUNCT
eurjchem-604	242	1	the	the	DET
eurjchem-604	242	2	hitherto	hitherto	NOUN
eurjchem-604	242	3	unknown	unknown	ADJ
eurjchem-604	242	4	complexes	complex	NOUN
eurjchem-604	242	5	,	,	PUNCT
eurjchem-604	242	6	[	[	X
eurjchem-604	242	7	m(co)4(ƞ2‐h2l	m(co)4(ƞ2‐h2l	ADJ
eurjchem-604	242	8	)	)	PUNCT
eurjchem-604	242	9	]	]	PUNCT
eurjchem-604	242	10	,	,	PUNCT
eurjchem-604	242	11	[	[	X
eurjchem-604	242	12	m	m	NOUN
eurjchem-604	242	13	=	=	NOUN
eurjchem-604	242	14	cr	cr	ADJ
eurjchem-604	242	15	;	;	PUNCT
eurjchem-604	242	16	1	1	NUM
eurjchem-604	242	17	,	,	PUNCT
eurjchem-604	242	18	mo	mo	NOUN
eurjchem-604	242	19	;	;	PUNCT
eurjchem-604	242	20	2	2	NUM
eurjchem-604	242	21	,	,	PUNCT
eurjchem-604	242	22	w	w	PROPN
eurjchem-604	242	23	;	;	PUNCT
eurjchem-604	242	24	3	3	NUM
eurjchem-604	242	25	]	]	PUNCT
eurjchem-604	242	26	;	;	PUNCT
eurjchem-604	242	27	have	have	AUX
eurjchem-604	242	28	been	be	AUX
eurjchem-604	242	29	synthesized	synthesize	VERB
eurjchem-604	242	30	by	by	ADP
eurjchem-604	242	31	the	the	DET
eurjchem-604	242	32	photochemical	photochemical	ADJ
eurjchem-604	242	33	reactions	reaction	NOUN
eurjchem-604	242	34	of	of	ADP
eurjchem-604	242	35	vib	vib	NOUN
eurjchem-604	242	36	metal	metal	NOUN
eurjchem-604	242	37	carbonyls	carbonyls	NOUN
eurjchem-604	242	38	[	[	X
eurjchem-604	242	39	m(co)6	m(co)6	X
eurjchem-604	242	40	]	]	X
eurjchem-604	243	1	[	[	X
eurjchem-604	243	2	m	m	NOUN
eurjchem-604	243	3	=	=	ADJ
eurjchem-604	243	4	cr	cr	PROPN
eurjchem-604	243	5	,	,	PUNCT
eurjchem-604	243	6	mo	mo	PROPN
eurjchem-604	243	7	,	,	PUNCT
eurjchem-604	243	8	w	w	PROPN
eurjchem-604	243	9	]	]	X
eurjchem-604	243	10	,	,	PUNCT
eurjchem-604	243	11	with	with	ADP
eurjchem-604	243	12	chiral	chiral	ADJ
eurjchem-604	243	13	schiff	schiff	NOUN
eurjchem-604	243	14	base	base	NOUN
eurjchem-604	243	15	n	n	CCONJ
eurjchem-604	243	16	,	,	PUNCT
eurjchem-604	243	17	n'‐bis‐(2‐hydroxynaphthalene‐1‐carbaldehydene)‐(1r,2r)‐(‐	n'‐bis‐(2‐hydroxynaphthalene‐1‐carbaldehydene)‐(1r,2r)‐(‐	ADJ
eurjchem-604	243	18	)	)	PUNCT
eurjchem-604	243	19	‐diaminocyclohexane	‐diaminocyclohexane	NOUN
eurjchem-604	243	20	(	(	PUNCT
eurjchem-604	243	21	h2l	h2l	PROPN
eurjchem-604	243	22	)	)	PUNCT
eurjchem-604	243	23	in	in	ADP
eurjchem-604	243	24	thf	thf	NOUN
eurjchem-604	243	25	(	(	PUNCT
eurjchem-604	243	26	scheme	scheme	NOUN
eurjchem-604	243	27	7	7	NUM
eurjchem-604	243	28	)	)	PUNCT
eurjchem-604	244	1	[	[	X
eurjchem-604	244	2	40	40	NUM
eurjchem-604	244	3	]	]	PUNCT
eurjchem-604	244	4	.	.	PUNCT
eurjchem-604	245	1	hc	hc	PROPN
eurjchem-604	245	2	n	n	ADP
eurjchem-604	245	3	h	h	NOUN
eurjchem-604	245	4	n	n	NOUN
eurjchem-604	245	5	ch	ch	NOUN
eurjchem-604	245	6	h	h	NOUN
eurjchem-604	246	1	oh	oh	INTJ
eurjchem-604	246	2	ho	ho	PROPN
eurjchem-604	246	3	m(co)6	m(co)6	PROPN
eurjchem-604	247	1	[	[	X
eurjchem-604	247	2	m	m	NOUN
eurjchem-604	247	3	=	=	ADJ
eurjchem-604	247	4	cr	cr	PROPN
eurjchem-604	247	5	,	,	PUNCT
eurjchem-604	247	6	mo	mo	PROPN
eurjchem-604	247	7	,	,	PUNCT
eurjchem-604	247	8	w	w	PROPN
eurjchem-604	247	9	]	]	X
eurjchem-604	247	10	h	h	NOUN
eurjchem-604	247	11	in	in	ADP
eurjchem-604	247	12	thf	thf	NOUN
eurjchem-604	247	13	2	2	NUM
eurjchem-604	247	14	co	co	NOUN
eurjchem-604	247	15	hc	hc	PROPN
eurjchem-604	247	16	n	n	PROPN
eurjchem-604	247	17	h	h	NOUN
eurjchem-604	247	18	n	n	ADV
eurjchem-604	247	19	ch	ch	NOUN
eurjchem-604	247	20	h	h	NOUN
eurjchem-604	247	21	m	m	AUX
eurjchem-604	247	22	co	co	ADJ
eurjchem-604	247	23	oc	oc	PART
eurjchem-604	247	24	co	co	VERB
eurjchem-604	247	25	oh	oh	INTJ
eurjchem-604	247	26	ohco	ohco	ADV
eurjchem-604	247	27	scheme	scheme	VERB
eurjchem-604	247	28	7	7	NUM
eurjchem-604	247	29	many	many	ADJ
eurjchem-604	247	30	complexes	complex	NOUN
eurjchem-604	247	31	based	base	VERB
eurjchem-604	247	32	on	on	ADP
eurjchem-604	247	33	above	above	ADP
eurjchem-604	247	34	hypothesis	hypothesis	NOUN
eurjchem-604	247	35	have	have	AUX
eurjchem-604	247	36	been	be	AUX
eurjchem-604	247	37	prepared	prepare	VERB
eurjchem-604	247	38	.	.	PUNCT
eurjchem-604	248	1	photochemical	photochemical	ADJ
eurjchem-604	248	2	synthesis	synthesis	NOUN
eurjchem-604	248	3	of	of	ADP
eurjchem-604	248	4	metal	metal	NOUN
eurjchem-604	248	5	carbonyl	carbonyl	NOUN
eurjchem-604	248	6	complexes	complex	NOUN
eurjchem-604	248	7	of	of	ADP
eurjchem-604	248	8	tetraalkyldiphosphine	tetraalkyldiphosphine	NOUN
eurjchem-604	248	9	disulfides	disulfide	NOUN
eurjchem-604	248	10	,	,	PUNCT
eurjchem-604	248	11	[	[	X
eurjchem-604	248	12	m2(co)10(μ‐	m2(co)10(μ‐	NOUN
eurjchem-604	248	13	r2p(s)p(s)r2	r2p(s)p(s)r2	NOUN
eurjchem-604	248	14	)	)	PUNCT
eurjchem-604	248	15	]	]	PUNCT
eurjchem-604	248	16	and	and	CCONJ
eurjchem-604	248	17	[	[	X
eurjchem-604	248	18	m(co)4(μ‐r2p(s)p(s)r2)](m	m(co)4(μ‐r2p(s)p(s)r2)](m	X
eurjchem-604	248	19	=	=	SYM
eurjchem-604	248	20	mo	mo	PROPN
eurjchem-604	248	21	,	,	PUNCT
eurjchem-604	248	22	w	w	PROPN
eurjchem-604	248	23	;	;	PUNCT
eurjchem-604	248	24	r	r	X
eurjchem-604	248	25	=	=	PUNCT
eurjchem-604	248	26	me	i	PRON
eurjchem-604	248	27	)	)	PUNCT
eurjchem-604	249	1	[	[	X
eurjchem-604	249	2	41	41	NUM
eurjchem-604	249	3	]	]	PUNCT
eurjchem-604	249	4	and	and	CCONJ
eurjchem-604	249	5	metal	metal	NOUN
eurjchem-604	249	6	carbonyl	carbonyl	NOUN
eurjchem-604	249	7	complexes	complex	NOUN
eurjchem-604	249	8	of	of	ADP
eurjchem-604	249	9	m(co)6	m(co)6	PROPN
eurjchem-604	249	10	(	(	PUNCT
eurjchem-604	249	11	m	m	PROPN
eurjchem-604	249	12	=	=	SYM
eurjchem-604	249	13	cr	cr	PROPN
eurjchem-604	249	14	,	,	PUNCT
eurjchem-604	249	15	mo	mo	PROPN
eurjchem-604	249	16	,	,	PUNCT
eurjchem-604	249	17	and	and	CCONJ
eurjchem-604	249	18	w	w	X
eurjchem-604	249	19	)	)	PUNCT
eurjchem-604	249	20	with	with	ADP
eurjchem-604	249	21	acetonemethanesulfonylhydrazone	acetonemethanesulfonylhydrazone	NOUN
eurjchem-604	249	22	(	(	PUNCT
eurjchem-604	249	23	amsh	amsh	NOUN
eurjchem-604	249	24	)	)	PUNCT
eurjchem-604	249	25	and	and	CCONJ
eurjchem-604	249	26	methanesulfonylhydrazone	methanesulfonylhydrazone	NOUN
eurjchem-604	249	27	(	(	PUNCT
eurjchem-604	249	28	msh	msh	PROPN
eurjchem-604	249	29	)	)	PUNCT
eurjchem-604	250	1	[	[	X
eurjchem-604	250	2	42	42	NUM
eurjchem-604	250	3	]	]	PUNCT
eurjchem-604	250	4	have	have	AUX
eurjchem-604	250	5	been	be	AUX
eurjchem-604	250	6	done	do	VERB
eurjchem-604	250	7	successfully	successfully	ADV
eurjchem-604	250	8	(	(	PUNCT
eurjchem-604	250	9	scheme	scheme	NOUN
eurjchem-604	250	10	8)	8)	NUM
eurjchem-604	250	11	.	.	PUNCT
eurjchem-604	251	1	scheme	scheme	NOUN
eurjchem-604	251	2	8	8	NUM
eurjchem-604	251	3	photolytic	photolytic	ADJ
eurjchem-604	251	4	reaction	reaction	NOUN
eurjchem-604	251	5	of	of	ADP
eurjchem-604	251	6	the	the	DET
eurjchem-604	251	7	free	free	ADJ
eurjchem-604	251	8	carbene	carbene	NOUN
eurjchem-604	251	9	(	(	PUNCT
eurjchem-604	251	10	l	l	NOUN
eurjchem-604	251	11	=	=	SYM
eurjchem-604	251	12	1,3,4‐triphenyl‐	1,3,4‐triphenyl‐	NUM
eurjchem-604	251	13	4,5‐dihydro‐1h‐1,2,4‐triazolin‐5‐ylidene	4,5‐dihydro‐1h‐1,2,4‐triazolin‐5‐ylidene	NUM
eurjchem-604	251	14	)	)	PUNCT
eurjchem-604	251	15	with	with	ADP
eurjchem-604	251	16	the	the	DET
eurjchem-604	251	17	hexa‐	hexa‐	PROPN
eurjchem-604	251	18	carbonyls	carbonyls	NOUN
eurjchem-604	251	19	of	of	ADP
eurjchem-604	251	20	cr	cr	PROPN
eurjchem-604	251	21	,	,	PUNCT
eurjchem-604	251	22	mo	mo	PROPN
eurjchem-604	251	23	and	and	CCONJ
eurjchem-604	251	24	w	w	ADP
eurjchem-604	251	25	the	the	DET
eurjchem-604	251	26	corresponding	corresponding	ADJ
eurjchem-604	251	27	m(l)(co)5	m(l)(co)5	PROPN
eurjchem-604	251	28	complexes	complex	NOUN
eurjchem-604	251	29	are	be	AUX
eurjchem-604	251	30	generated	generate	VERB
eurjchem-604	251	31	.	.	PUNCT
eurjchem-604	252	1	depending	depend	VERB
eurjchem-604	252	2	on	on	ADP
eurjchem-604	252	3	an	an	DET
eurjchem-604	252	4	excess	excess	NOUN
eurjchem-604	252	5	of	of	ADP
eurjchem-604	252	6	carbene	carbene	NOUN
eurjchem-604	252	7	also	also	ADV
eurjchem-604	252	8	the	the	DET
eurjchem-604	252	9	cis‐(l)2mo(co)4	cis‐(l)2mo(co)4	PROPN
eurjchem-604	252	10	complex	complex	NOUN
eurjchem-604	252	11	was	be	AUX
eurjchem-604	252	12	obtained	obtain	VERB
eurjchem-604	252	13	[	[	X
eurjchem-604	252	14	43	43	NUM
eurjchem-604	252	15	]	]	PUNCT
eurjchem-604	252	16	.	.	PUNCT
eurjchem-604	253	1	photolysis	photolysis	NOUN
eurjchem-604	253	2	of	of	ADP
eurjchem-604	253	3	m(co)6	m(co)6	PROPN
eurjchem-604	253	4	(	(	PUNCT
eurjchem-604	253	5	m	m	NOUN
eurjchem-604	253	6	=	=	SYM
eurjchem-604	253	7	cr	cr	PROPN
eurjchem-604	253	8	,	,	PUNCT
eurjchem-604	253	9	mo	mo	PROPN
eurjchem-604	253	10	,	,	PUNCT
eurjchem-604	253	11	w	w	PROPN
eurjchem-604	253	12	)	)	PUNCT
eurjchem-604	253	13	in	in	ADP
eurjchem-604	253	14	the	the	DET
eurjchem-604	253	15	presence	presence	NOUN
eurjchem-604	253	16	of	of	ADP
eurjchem-604	253	17	vinyl	vinyl	NOUN
eurjchem-604	253	18	ferrocene	ferrocene	NOUN
eurjchem-604	253	19	in	in	ADP
eurjchem-604	253	20	an	an	DET
eurjchem-604	253	21	n‐hexane	n‐hexane	NOUN
eurjchem-604	253	22	solution	solution	NOUN
eurjchem-604	253	23	at	at	ADP
eurjchem-604	253	24	‐15	‐15	PROPN
eurjchem-604	253	25	°	°	ADP
eurjchem-604	253	26	c	c	NOUN
eurjchem-604	253	27	yields	yield	NOUN
eurjchem-604	253	28	m(co5)(η2‐	m(co5)(η2‐	PROPN
eurjchem-604	253	29	vinylferrocene)metal(0	vinylferrocene)metal(0	NOUN
eurjchem-604	253	30	)	)	PUNCT
eurjchem-604	253	31	complexes	complex	NOUN
eurjchem-604	253	32	as	as	ADP
eurjchem-604	253	33	the	the	DET
eurjchem-604	253	34	sole	sole	ADJ
eurjchem-604	253	35	product	product	NOUN
eurjchem-604	253	36	(	(	PUNCT
eurjchem-604	253	37	scheme	scheme	NOUN
eurjchem-604	253	38	9	9	NUM
eurjchem-604	253	39	)	)	PUNCT
eurjchem-604	253	40	,	,	PUNCT
eurjchem-604	253	41	which	which	PRON
eurjchem-604	253	42	could	could	AUX
eurjchem-604	253	43	be	be	AUX
eurjchem-604	253	44	isolated	isolate	VERB
eurjchem-604	253	45	and	and	CCONJ
eurjchem-604	253	46	characterized	characterize	VERB
eurjchem-604	253	47	by	by	ADP
eurjchem-604	253	48	spectroscopic	spectroscopic	ADJ
eurjchem-604	253	49	techniques	technique	NOUN
eurjchem-604	253	50	.	.	PUNCT
eurjchem-604	254	1	the	the	DET
eurjchem-604	254	2	complexes	complex	NOUN
eurjchem-604	254	3	were	be	AUX
eurjchem-604	254	4	found	find	VERB
eurjchem-604	254	5	to	to	PART
eurjchem-604	254	6	be	be	AUX
eurjchem-604	254	7	not	not	PART
eurjchem-604	254	8	very	very	ADV
eurjchem-604	254	9	stable	stable	ADJ
eurjchem-604	254	10	and	and	CCONJ
eurjchem-604	254	11	their	their	PRON
eurjchem-604	254	12	stability	stability	NOUN
eurjchem-604	254	13	increases	increase	VERB
eurjchem-604	254	14	in	in	ADP
eurjchem-604	254	15	the	the	DET
eurjchem-604	254	16	order	order	NOUN
eurjchem-604	254	17	cr	cr	X
eurjchem-604	254	18	<	<	X
eurjchem-604	254	19	mo	mo	PROPN
eurjchem-604	254	20	<	<	PROPN
eurjchem-604	254	21	w.	w.	PROPN
eurjchem-604	254	22	retracted	retract	VERB
eurjchem-604	254	23	kaushik	kaushik	PROPN
eurjchem-604	254	24	et	et	PROPN
eurjchem-604	254	25	al	al	PROPN
eurjchem-604	254	26	.	.	PUNCT
eurjchem-604	254	27	/	/	SYM
eurjchem-604	254	28	european	european	PROPN
eurjchem-604	254	29	journal	journal	PROPN
eurjchem-604	254	30	of	of	ADP
eurjchem-604	254	31	chemistry	chemistry	NOUN
eurjchem-604	254	32	3	3	NUM
eurjchem-604	254	33	(	(	PUNCT
eurjchem-604	254	34	3	3	NUM
eurjchem-604	254	35	)	)	PUNCT
eurjchem-604	254	36	(	(	PUNCT
eurjchem-604	254	37	2012	2012	NUM
eurjchem-604	254	38	)	)	PUNCT
eurjchem-604	254	39	367‐394	367‐394	NOUN
eurjchem-604	254	40	373	373	NUM
eurjchem-604	254	41	the	the	DET
eurjchem-604	254	42	relatively	relatively	ADV
eurjchem-604	254	43	stable	stable	ADJ
eurjchem-604	254	44	w(co)5(η2‐vinylferrocene	w(co)5(η2‐vinylferrocene	NOUN
eurjchem-604	254	45	)	)	PUNCT
eurjchem-604	254	46	could	could	AUX
eurjchem-604	254	47	be	be	AUX
eurjchem-604	254	48	isolated	isolate	VERB
eurjchem-604	254	49	as	as	ADP
eurjchem-604	254	50	a	a	DET
eurjchem-604	254	51	pure	pure	ADJ
eurjchem-604	254	52	solid	solid	ADJ
eurjchem-604	255	1	[	[	X
eurjchem-604	255	2	44	44	NUM
eurjchem-604	255	3	]	]	PUNCT
eurjchem-604	255	4	.	.	PUNCT
eurjchem-604	256	1	scheme	scheme	NOUN
eurjchem-604	256	2	9	9	NUM
eurjchem-604	256	3	john	john	PROPN
eurjchem-604	256	4	k.	k.	PROPN
eurjchem-604	256	5	ruff	ruff	PROPN
eurjchem-604	256	6	and	and	CCONJ
eurjchem-604	256	7	max	max	PROPN
eurjchem-604	256	8	lustig	lustig	PROPN
eurjchem-604	256	9	found	find	VERB
eurjchem-604	256	10	that	that	SCONJ
eurjchem-604	256	11	the	the	DET
eurjchem-604	256	12	addition	addition	NOUN
eurjchem-604	256	13	of	of	ADP
eurjchem-604	256	14	the	the	DET
eurjchem-604	256	15	difluorodithiophosphate	difluorodithiophosphate	ADJ
eurjchem-604	256	16	anion	anion	NOUN
eurjchem-604	256	17	to	to	ADP
eurjchem-604	256	18	a	a	DET
eurjchem-604	256	19	solution	solution	NOUN
eurjchem-604	256	20	of	of	ADP
eurjchem-604	256	21	cr(co)5thf	cr(co)5thf	ADP
eurjchem-604	256	22	in	in	ADP
eurjchem-604	256	23	the	the	DET
eurjchem-604	256	24	absence	absence	NOUN
eurjchem-604	256	25	of	of	ADP
eurjchem-604	256	26	light	light	NOUN
eurjchem-604	256	27	produces	produce	VERB
eurjchem-604	256	28	only	only	ADV
eurjchem-604	256	29	trace	trace	NOUN
eurjchem-604	256	30	amounts	amount	NOUN
eurjchem-604	256	31	of	of	ADP
eurjchem-604	256	32	the	the	DET
eurjchem-604	256	33	product	product	NOUN
eurjchem-604	256	34	[	[	X
eurjchem-604	256	35	45	45	NUM
eurjchem-604	256	36	]	]	PUNCT
eurjchem-604	256	37	.	.	PUNCT
eurjchem-604	257	1	2.3	2.3	NUM
eurjchem-604	257	2	.	.	PUNCT
eurjchem-604	257	3	substitution	substitution	NOUN
eurjchem-604	257	4	reactions	reaction	NOUN
eurjchem-604	257	5	of	of	ADP
eurjchem-604	257	6	metal	metal	NOUN
eurjchem-604	257	7	carbonyls	carbonyls	NOUN
eurjchem-604	257	8	in	in	ADP
eurjchem-604	257	9	presence	presence	NOUN
eurjchem-604	257	10	of	of	ADP
eurjchem-604	257	11	complexation	complexation	NOUN
eurjchem-604	257	12	agents	agent	NOUN
eurjchem-604	257	13	complexation	complexation	NOUN
eurjchem-604	257	14	agent	agent	NOUN
eurjchem-604	257	15	or	or	CCONJ
eurjchem-604	257	16	ligand	ligand	NOUN
eurjchem-604	257	17	is	be	AUX
eurjchem-604	257	18	an	an	DET
eurjchem-604	257	19	ion	ion	NOUN
eurjchem-604	257	20	or	or	CCONJ
eurjchem-604	257	21	molecule	molecule	NOUN
eurjchem-604	257	22	that	that	PRON
eurjchem-604	257	23	binds	bind	VERB
eurjchem-604	257	24	to	to	ADP
eurjchem-604	257	25	a	a	DET
eurjchem-604	257	26	central	central	ADJ
eurjchem-604	257	27	metal	metal	NOUN
eurjchem-604	257	28	atom	atom	NOUN
eurjchem-604	257	29	to	to	PART
eurjchem-604	257	30	form	form	VERB
eurjchem-604	257	31	a	a	DET
eurjchem-604	257	32	coordination	coordination	NOUN
eurjchem-604	257	33	complex	complex	NOUN
eurjchem-604	257	34	[	[	X
eurjchem-604	257	35	46,47	46,47	NUM
eurjchem-604	257	36	]	]	X
eurjchem-604	257	37	.	.	PUNCT
eurjchem-604	258	1	although	although	SCONJ
eurjchem-604	258	2	the	the	DET
eurjchem-604	258	3	ligands	ligand	NOUN
eurjchem-604	258	4	can	can	AUX
eurjchem-604	258	5	directly	directly	ADV
eurjchem-604	258	6	react	react	VERB
eurjchem-604	258	7	with	with	ADP
eurjchem-604	258	8	metal	metal	NOUN
eurjchem-604	258	9	carbonyls	carbonyls	NOUN
eurjchem-604	258	10	to	to	PART
eurjchem-604	258	11	form	form	VERB
eurjchem-604	258	12	metal	metal	NOUN
eurjchem-604	258	13	carbonyl	carbonyl	NOUN
eurjchem-604	258	14	complexes	complex	NOUN
eurjchem-604	258	15	,	,	PUNCT
eurjchem-604	258	16	but	but	CCONJ
eurjchem-604	258	17	the	the	DET
eurjchem-604	258	18	reaction	reaction	NOUN
eurjchem-604	258	19	becomes	become	VERB
eurjchem-604	258	20	more	more	ADV
eurjchem-604	258	21	easy	easy	ADJ
eurjchem-604	258	22	and	and	CCONJ
eurjchem-604	258	23	gives	give	VERB
eurjchem-604	258	24	higher	high	ADJ
eurjchem-604	258	25	yields	yield	NOUN
eurjchem-604	258	26	when	when	SCONJ
eurjchem-604	258	27	a	a	DET
eurjchem-604	258	28	m(co)x	m(co)x	PROPN
eurjchem-604	258	29	transfer	transfer	NOUN
eurjchem-604	258	30	reagent	reagent	NOUN
eurjchem-604	258	31	is	be	AUX
eurjchem-604	258	32	available	available	ADJ
eurjchem-604	258	33	.	.	PUNCT
eurjchem-604	259	1	many	many	ADJ
eurjchem-604	259	2	m(co)x	m(co)x	ADJ
eurjchem-604	259	3	transfer	transfer	NOUN
eurjchem-604	259	4	reagents	reagent	NOUN
eurjchem-604	259	5	are	be	AUX
eurjchem-604	259	6	known	know	VERB
eurjchem-604	259	7	few	few	ADJ
eurjchem-604	259	8	of	of	ADP
eurjchem-604	259	9	them	they	PRON
eurjchem-604	259	10	are	be	AUX
eurjchem-604	259	11	discussed	discuss	VERB
eurjchem-604	259	12	below	below	ADV
eurjchem-604	259	13	.	.	PUNCT
eurjchem-604	260	1	2.3.1	2.3.1	NUM
eurjchem-604	260	2	.	.	PUNCT
eurjchem-604	260	3	m(co)5	m(co)5	NOUN
eurjchem-604	260	4	transfer	transfer	NOUN
eurjchem-604	260	5	reagents	reagent	NOUN
eurjchem-604	260	6	the	the	DET
eurjchem-604	260	7	monodentate	monodentate	ADJ
eurjchem-604	260	8	ligands	ligand	NOUN
eurjchem-604	260	9	which	which	PRON
eurjchem-604	260	10	easily	easily	ADV
eurjchem-604	260	11	get	get	AUX
eurjchem-604	260	12	replaced	replace	VERB
eurjchem-604	260	13	with	with	ADP
eurjchem-604	260	14	incoming	incoming	ADJ
eurjchem-604	260	15	ligands	ligand	NOUN
eurjchem-604	260	16	are	be	AUX
eurjchem-604	260	17	termed	term	VERB
eurjchem-604	260	18	as	as	ADP
eurjchem-604	260	19	m(co)5	m(co)5	NUM
eurjchem-604	260	20	transfer	transfer	NOUN
eurjchem-604	260	21	reagents	reagent	NOUN
eurjchem-604	260	22	.	.	PUNCT
eurjchem-604	261	1	2.3.1.1	2.3.1.1	NUM
eurjchem-604	261	2	.	.	PUNCT
eurjchem-604	261	3	m(co)5thf	m(co)5thf	NOUN
eurjchem-604	261	4	uv‐photolysis	uv‐photolysis	NOUN
eurjchem-604	261	5	of	of	ADP
eurjchem-604	261	6	a	a	DET
eurjchem-604	261	7	thf	thf	NOUN
eurjchem-604	261	8	solution	solution	NOUN
eurjchem-604	261	9	of	of	ADP
eurjchem-604	261	10	mo(co)6	mo(co)6	PROPN
eurjchem-604	261	11	gives	give	VERB
eurjchem-604	261	12	mo(co)5(thf	mo(co)5(thf	NOUN
eurjchem-604	261	13	)	)	PUNCT
eurjchem-604	261	14	.	.	PUNCT
eurjchem-604	262	1	a	a	DET
eurjchem-604	262	2	thf	thf	NOUN
eurjchem-604	262	3	solution	solution	NOUN
eurjchem-604	262	4	(	(	PUNCT
eurjchem-604	262	5	150	150	NUM
eurjchem-604	262	6	ml	ml	NOUN
eurjchem-604	262	7	)	)	PUNCT
eurjchem-604	262	8	of	of	ADP
eurjchem-604	262	9	m(co)6	m(co)6	NOUN
eurjchem-604	262	10	(	(	PUNCT
eurjchem-604	262	11	0.71	0.71	NUM
eurjchem-604	262	12	mmol	mmol	NOUN
eurjchem-604	262	13	)	)	PUNCT
eurjchem-604	262	14	was	be	AUX
eurjchem-604	262	15	irradiated	irradiate	VERB
eurjchem-604	262	16	with	with	ADP
eurjchem-604	262	17	uv	uv	NOUN
eurjchem-604	262	18	light	light	NOUN
eurjchem-604	262	19	under	under	ADP
eurjchem-604	262	20	n2	n2	ADJ
eurjchem-604	262	21	stream	stream	NOUN
eurjchem-604	262	22	at	at	ADP
eurjchem-604	262	23	room	room	NOUN
eurjchem-604	262	24	temperature	temperature	NOUN
eurjchem-604	262	25	for	for	ADP
eurjchem-604	262	26	2	2	NUM
eurjchem-604	262	27	h	h	NOUN
eurjchem-604	262	28	to	to	PART
eurjchem-604	262	29	generate	generate	VERB
eurjchem-604	262	30	the	the	DET
eurjchem-604	262	31	m(co)5thf	m(co)5thf	NOUN
eurjchem-604	262	32	intermediate	intermediate	ADJ
eurjchem-604	263	1	[	[	X
eurjchem-604	263	2	48	48	NUM
eurjchem-604	263	3	]	]	PUNCT
eurjchem-604	263	4	.	.	PUNCT
eurjchem-604	264	1	the	the	DET
eurjchem-604	264	2	allenylphosphine	allenylphosphine	NOUN
eurjchem-604	264	3	(	(	PUNCT
eurjchem-604	264	4	l	l	NOUN
eurjchem-604	264	5	)	)	PUNCT
eurjchem-604	264	6	,	,	PUNCT
eurjchem-604	264	7	reacts	react	VERB
eurjchem-604	264	8	with	with	ADP
eurjchem-604	264	9	(	(	PUNCT
eurjchem-604	264	10	thf)cr(co)5	thf)cr(co)5	NOUN
eurjchem-604	264	11	to	to	PART
eurjchem-604	264	12	form	form	VERB
eurjchem-604	264	13	the	the	DET
eurjchem-604	264	14	complexes	complex	NOUN
eurjchem-604	264	15	(	(	PUNCT
eurjchem-604	264	16	l)‐cr(co)5[31	l)‐cr(co)5[31	PROPN
eurjchem-604	264	17	]	]	X
eurjchem-604	264	18	.	.	PUNCT
eurjchem-604	265	1	the	the	DET
eurjchem-604	265	2	complexes	complex	NOUN
eurjchem-604	265	3	[	[	X
eurjchem-604	265	4	et4n	et4n	X
eurjchem-604	265	5	]	]	X
eurjchem-604	265	6	[	[	X
eurjchem-604	265	7	m(co)5scph3	m(co)5scph3	X
eurjchem-604	265	8	]	]	X
eurjchem-604	265	9	(	(	PUNCT
eurjchem-604	265	10	m	m	PROPN
eurjchem-604	265	11	=	=	SYM
eurjchem-604	265	12	mo	mo	PROPN
eurjchem-604	265	13	,	,	PUNCT
eurjchem-604	265	14	w	w	NOUN
eurjchem-604	265	15	)	)	PUNCT
eurjchem-604	265	16	were	be	AUX
eurjchem-604	265	17	prepared	prepare	VERB
eurjchem-604	265	18	by	by	ADP
eurjchem-604	265	19	the	the	DET
eurjchem-604	265	20	reaction	reaction	NOUN
eurjchem-604	265	21	of	of	ADP
eurjchem-604	265	22	[	[	X
eurjchem-604	265	23	et4n][scph3	et4n][scph3	NOUN
eurjchem-604	265	24	]	]	PUNCT
eurjchem-604	265	25	with	with	ADP
eurjchem-604	265	26	the	the	DET
eurjchem-604	265	27	photogenerated	photogenerate	VERB
eurjchem-604	265	28	m(co)5thf	m(co)5thf	NOUN
eurjchem-604	265	29	intermediate	intermediate	VERB
eurjchem-604	265	30	at	at	ADP
eurjchem-604	265	31	ambient	ambient	ADJ
eurjchem-604	265	32	temperatures	temperature	NOUN
eurjchem-604	265	33	.	.	PUNCT
eurjchem-604	266	1	thf	thf	NOUN
eurjchem-604	266	2	is	be	AUX
eurjchem-604	266	3	substituted	substitute	VERB
eurjchem-604	266	4	by	by	ADP
eurjchem-604	266	5	reaction	reaction	NOUN
eurjchem-604	266	6	of	of	ADP
eurjchem-604	266	7	m(co)5thf	m(co)5thf	NOUN
eurjchem-604	266	8	with	with	ADP
eurjchem-604	266	9	a	a	DET
eurjchem-604	266	10	monodentate	monodentate	ADJ
eurjchem-604	266	11	ligand	ligand	NOUN
eurjchem-604	266	12	(	(	PUNCT
eurjchem-604	266	13	scheme	scheme	NOUN
eurjchem-604	266	14	10	10	NUM
eurjchem-604	266	15	)	)	PUNCT
eurjchem-604	267	1	[	[	X
eurjchem-604	267	2	49	49	NUM
eurjchem-604	267	3	]	]	PUNCT
eurjchem-604	267	4	.	.	PUNCT
eurjchem-604	268	1	scheme	scheme	NOUN
eurjchem-604	268	2	10	10	NUM
eurjchem-604	268	3	reaction	reaction	NOUN
eurjchem-604	268	4	of	of	ADP
eurjchem-604	268	5	1h‐1,3‐benzazaphospholes	1h‐1,3‐benzazaphospholes	NUM
eurjchem-604	268	6	with	with	ADP
eurjchem-604	268	7	m(co)5	m(co)5	PROPN
eurjchem-604	268	8	(	(	PUNCT
eurjchem-604	268	9	thf	thf	NOUN
eurjchem-604	268	10	)	)	PUNCT
eurjchem-604	268	11	yields	yield	VERB
eurjchem-604	268	12	the	the	DET
eurjchem-604	268	13	respective´1(p)‐metal	respective´1(p)‐metal	ADJ
eurjchem-604	268	14	carbonyl	carbonyl	NOUN
eurjchem-604	268	15	complexes	complex	NOUN
eurjchem-604	268	16	(	(	PUNCT
eurjchem-604	268	17	scheme	scheme	NOUN
eurjchem-604	268	18	11	11	NUM
eurjchem-604	268	19	)	)	PUNCT
eurjchem-604	269	1	[	[	X
eurjchem-604	269	2	50	50	NUM
eurjchem-604	269	3	]	]	PUNCT
eurjchem-604	269	4	.	.	PUNCT
eurjchem-604	270	1	scheme	scheme	VERB
eurjchem-604	270	2	11	11	NUM
eurjchem-604	270	3	the	the	DET
eurjchem-604	270	4	reaction	reaction	NOUN
eurjchem-604	270	5	of	of	ADP
eurjchem-604	270	6	β‐ethynyl	β‐ethynyl	PUNCT
eurjchem-604	270	7	α	α	PROPN
eurjchem-604	270	8	,	,	PUNCT
eurjchem-604	270	9	β‐unsaturated	β‐unsaturate	VERB
eurjchem-604	270	10	esters	ester	NOUN
eurjchem-604	270	11	or	or	CCONJ
eurjchem-604	270	12	amides	amide	NOUN
eurjchem-604	270	13	with	with	ADP
eurjchem-604	270	14	cr(co)5(l	cr(co)5(l	NOUN
eurjchem-604	270	15	)	)	PUNCT
eurjchem-604	270	16	(	(	PUNCT
eurjchem-604	270	17	l=	l=	ADJ
eurjchem-604	270	18	thf	thf	NOUN
eurjchem-604	270	19	)	)	PUNCT
eurjchem-604	270	20	,	,	PUNCT
eurjchem-604	270	21	derived	derive	VERB
eurjchem-604	270	22	from	from	ADP
eurjchem-604	270	23	chromium	chromium	NOUN
eurjchem-604	270	24	hexacarbonyl	hexacarbonyl	NOUN
eurjchem-604	270	25	,	,	PUNCT
eurjchem-604	270	26	gives	give	VERB
eurjchem-604	270	27	2‐pyranylidene‐chromium	2‐pyranylidene‐chromium	NUM
eurjchem-604	270	28	complexes	complex	NOUN
eurjchem-604	270	29	in	in	ADP
eurjchem-604	270	30	good	good	ADJ
eurjchem-604	270	31	yields	yield	NOUN
eurjchem-604	270	32	(	(	PUNCT
eurjchem-604	270	33	scheme	scheme	NOUN
eurjchem-604	270	34	12	12	NUM
eurjchem-604	270	35	)	)	PUNCT
eurjchem-604	271	1	[	[	X
eurjchem-604	271	2	51	51	NUM
eurjchem-604	271	3	]	]	PUNCT
eurjchem-604	271	4	.	.	PUNCT
eurjchem-604	272	1	scheme	scheme	NOUN
eurjchem-604	272	2	12	12	NUM
eurjchem-604	272	3	subasi	subasi	NOUN
eurjchem-604	272	4	et	et	PROPN
eurjchem-604	272	5	al	al	PROPN
eurjchem-604	272	6	.	.	PROPN
eurjchem-604	273	1	prepared	prepared	ADJ
eurjchem-604	273	2	complexes	complex	NOUN
eurjchem-604	273	3	,	,	PUNCT
eurjchem-604	273	4	[	[	X
eurjchem-604	273	5	(	(	PUNCT
eurjchem-604	273	6	μ	μ	NOUN
eurjchem-604	273	7	‐co)2cr2(η4‐h2l)2	‐co)2cr2(η4‐h2l)2	PROPN
eurjchem-604	273	8	]	]	PUNCT
eurjchem-604	273	9	;	;	PUNCT
eurjchem-604	273	10	[	[	X
eurjchem-604	273	11	(	(	PUNCT
eurjchem-604	273	12	μ	μ	PROPN
eurjchem-604	273	13	‐co)m2(co)2(η4‐h2l)2	‐co)m2(co)2(η4‐h2l)2	PROPN
eurjchem-604	273	14	]	]	PUNCT
eurjchem-604	273	15	,	,	PUNCT
eurjchem-604	274	1	[	[	X
eurjchem-604	274	2	m	m	X
eurjchem-604	274	3	=	=	SYM
eurjchem-604	274	4	mo	mo	PROPN
eurjchem-604	274	5	;	;	PUNCT
eurjchem-604	274	6	w	w	NOUN
eurjchem-604	274	7	]	]	X
eurjchem-604	274	8	;	;	PUNCT
eurjchem-604	274	9	[	[	X
eurjchem-604	274	10	(	(	PUNCT
eurjchem-604	274	11	μ	μ	PROPN
eurjchem-604	274	12	‐co)2cr2(η4‐	‐co)2cr2(η4‐	PROPN
eurjchem-604	275	1	h2l′)2	h2l′)2	PROPN
eurjchem-604	275	2	]	]	X
eurjchem-604	275	3	,	,	PUNCT
eurjchem-604	275	4	and	and	CCONJ
eurjchem-604	275	5	[	[	X
eurjchem-604	275	6	(	(	PUNCT
eurjchem-604	275	7	μ	μ	PROPN
eurjchem-604	275	8	‐co)m2(co)2(η4‐h2l′)2	‐co)m2(co)2(η4‐h2l′)2	PROPN
eurjchem-604	275	9	]	]	PUNCT
eurjchem-604	275	10	,	,	PUNCT
eurjchem-604	275	11	[	[	X
eurjchem-604	275	12	m	m	X
eurjchem-604	275	13	=	=	SYM
eurjchem-604	275	14	mo	mo	PROPN
eurjchem-604	275	15	;	;	PUNCT
eurjchem-604	275	16	w	w	X
eurjchem-604	275	17	]	]	PUNCT
eurjchem-604	275	18	have	have	AUX
eurjchem-604	275	19	been	be	AUX
eurjchem-604	275	20	synthesized	synthesize	VERB
eurjchem-604	275	21	by	by	ADP
eurjchem-604	275	22	the	the	DET
eurjchem-604	275	23	photochemical	photochemical	ADJ
eurjchem-604	275	24	reactions	reaction	NOUN
eurjchem-604	275	25	of	of	ADP
eurjchem-604	275	26	photogenerated	photogenerated	ADJ
eurjchem-604	275	27	intermediate	intermediate	ADJ
eurjchem-604	275	28	,	,	PUNCT
eurjchem-604	275	29	m(co)5thf	m(co)5thf	X
eurjchem-604	276	1	(	(	PUNCT
eurjchem-604	276	2	m	m	PROPN
eurjchem-604	276	3	=	=	SYM
eurjchem-604	276	4	cr	cr	PROPN
eurjchem-604	276	5	,	,	PUNCT
eurjchem-604	276	6	mo	mo	PROPN
eurjchem-604	276	7	,	,	PUNCT
eurjchem-604	276	8	w	w	PROPN
eurjchem-604	276	9	)	)	PUNCT
eurjchem-604	276	10	with	with	ADP
eurjchem-604	276	11	two	two	NUM
eurjchem-604	276	12	oxygen	oxygen	NOUN
eurjchem-604	276	13	and	and	CCONJ
eurjchem-604	276	14	nitrogen	nitrogen	NOUN
eurjchem-604	276	15	donor	donor	NOUN
eurjchem-604	276	16	schiff	schiff	NOUN
eurjchem-604	276	17	base	base	NOUN
eurjchem-604	276	18	ligands	ligand	NOUN
eurjchem-604	276	19	,	,	PUNCT
eurjchem-604	276	20	n	n	CCONJ
eurjchem-604	276	21	,	,	PUNCT
eurjchem-604	276	22	n′‐bis(2‐	n′‐bis(2‐	ADJ
eurjchem-604	276	23	hydroxynaphtalin‐1‐carbaldehydene)‐1,2‐bis(p‐aminophe‐	hydroxynaphtalin‐1‐carbaldehydene)‐1,2‐bis(p‐aminophe‐	NOUN
eurjchem-604	277	1	noxy)ethane	noxy)ethane	PROPN
eurjchem-604	277	2	(	(	PUNCT
eurjchem-604	277	3	h2l	h2l	PROPN
eurjchem-604	277	4	)	)	PUNCT
eurjchem-604	277	5	and	and	CCONJ
eurjchem-604	277	6	n	n	CCONJ
eurjchem-604	277	7	,	,	PUNCT
eurjchem-604	277	8	n′‐bis(2‐hydroxynaphtalin‐1‐	n′‐bis(2‐hydroxynaphtalin‐1‐	PROPN
eurjchem-604	277	9	carbalde‐hydene)‐1,4‐bis(p‐aminophenoxy)butane	carbalde‐hydene)‐1,4‐bis(p‐aminophenoxy)butane	PROPN
eurjchem-604	277	10	(	(	PUNCT
eurjchem-604	277	11	h2	h2	PROPN
eurjchem-604	277	12	l′	l′	NOUN
eurjchem-604	277	13	)	)	PUNCT
eurjchem-604	278	1	[	[	X
eurjchem-604	278	2	52	52	NUM
eurjchem-604	278	3	]	]	PUNCT
eurjchem-604	278	4	.	.	PUNCT
eurjchem-604	279	1	they	they	PRON
eurjchem-604	279	2	also	also	ADV
eurjchem-604	279	3	report	report	VERB
eurjchem-604	279	4	the	the	DET
eurjchem-604	279	5	complexes	complex	NOUN
eurjchem-604	279	6	,	,	PUNCT
eurjchem-604	279	7	cis‐	cis‐	NOUN
eurjchem-604	279	8	[	[	X
eurjchem-604	279	9	m(co)2(η4‐h2l	m(co)2(η4‐h2l	NUM
eurjchem-604	279	10	'	'	NUM
eurjchem-604	279	11	)	)	PUNCT
eurjchem-604	279	12	]	]	PUNCT
eurjchem-604	279	13	,	,	PUNCT
eurjchem-604	280	1	[	[	X
eurjchem-604	280	2	m	m	X
eurjchem-604	280	3	=	=	ADJ
eurjchem-604	280	4	cr	cr	PROPN
eurjchem-604	280	5	;	;	PUNCT
eurjchem-604	280	6	mo	mo	PROPN
eurjchem-604	280	7	;	;	PUNCT
eurjchem-604	280	8	w	w	NOUN
eurjchem-604	280	9	]	]	PUNCT
eurjchem-604	280	10	and	and	CCONJ
eurjchem-604	280	11	cis‐	cis‐	NOUN
eurjchem-604	280	12	[	[	X
eurjchem-604	280	13	m(co)2(η4‐h2l	m(co)2(η4‐h2l	NUM
eurjchem-604	280	14	”	"	PUNCT
eurjchem-604	280	15	)	)	PUNCT
eurjchem-604	280	16	]	]	PUNCT
eurjchem-604	280	17	,	,	PUNCT
eurjchem-604	281	1	[	[	X
eurjchem-604	281	2	m	m	X
eurjchem-604	281	3	=	=	ADJ
eurjchem-604	281	4	cr	cr	PROPN
eurjchem-604	281	5	;	;	PUNCT
eurjchem-604	281	6	mo	mo	PROPN
eurjchem-604	281	7	;	;	PUNCT
eurjchem-604	281	8	w	w	PROPN
eurjchem-604	281	9	]	]	PUNCT
eurjchem-604	281	10	synthesized	synthesize	VERB
eurjchem-604	281	11	by	by	ADP
eurjchem-604	281	12	the	the	DET
eurjchem-604	281	13	photochemical	photochemical	ADJ
eurjchem-604	281	14	reactions	reaction	NOUN
eurjchem-604	281	15	of	of	ADP
eurjchem-604	281	16	photogenerated	photogenerated	ADJ
eurjchem-604	281	17	intermediate	intermediate	ADJ
eurjchem-604	281	18	,	,	PUNCT
eurjchem-604	281	19	m(co)5thf	m(co)5thf	X
eurjchem-604	281	20	(	(	PUNCT
eurjchem-604	281	21	m	m	PROPN
eurjchem-604	281	22	=	=	SYM
eurjchem-604	281	23	cr	cr	PROPN
eurjchem-604	281	24	,	,	PUNCT
eurjchem-604	281	25	mo	mo	PROPN
eurjchem-604	281	26	,	,	PUNCT
eurjchem-604	281	27	w	w	PROPN
eurjchem-604	281	28	)	)	PUNCT
eurjchem-604	281	29	with	with	ADP
eurjchem-604	281	30	salen	salen	PROPN
eurjchem-604	281	31	type	type	NOUN
eurjchem-604	281	32	schiff	schiff	NOUN
eurjchem-604	281	33	base	base	NOUN
eurjchem-604	281	34	ligands	ligand	NOUN
eurjchem-604	281	35	,	,	PUNCT
eurjchem-604	281	36	n	n	CCONJ
eurjchem-604	281	37	,	,	PUNCT
eurjchem-604	281	38	n'‐bis(salicylidene)‐1,4‐diaminobutane	n'‐bis(salicylidene)‐1,4‐diaminobutane	NOUN
eurjchem-604	281	39	(	(	PUNCT
eurjchem-604	281	40	h2l	h2l	PROPN
eurjchem-604	281	41	'	'	NUM
eurjchem-604	281	42	)	)	PUNCT
eurjchem-604	281	43	and	and	CCONJ
eurjchem-604	281	44	n	n	CCONJ
eurjchem-604	281	45	,	,	PUNCT
eurjchem-604	281	46	n'‐bis(2‐hydroxy‐3‐methoxybenzylidene)ethylene	n'‐bis(2‐hydroxy‐3‐methoxybenzylidene)ethylene	ADJ
eurjchem-604	281	47	diamine	diamine	NOUN
eurjchem-604	281	48	(	(	PUNCT
eurjchem-604	281	49	h2l	h2l	X
eurjchem-604	281	50	”	"	PUNCT
eurjchem-604	281	51	)	)	PUNCT
eurjchem-604	282	1	[	[	X
eurjchem-604	282	2	53	53	NUM
eurjchem-604	282	3	]	]	PUNCT
eurjchem-604	282	4	.	.	PUNCT
eurjchem-604	283	1	the	the	DET
eurjchem-604	283	2	reactions	reaction	NOUN
eurjchem-604	283	3	of	of	ADP
eurjchem-604	283	4	m(co)6	m(co)6	NUM
eurjchem-604	283	5	with	with	ADP
eurjchem-604	283	6	ligands	ligand	NOUN
eurjchem-604	283	7	using	use	VERB
eurjchem-604	283	8	thf	thf	NOUN
eurjchem-604	283	9	as	as	ADP
eurjchem-604	283	10	solvent	solvent	NOUN
eurjchem-604	283	11	also	also	ADV
eurjchem-604	283	12	give	give	VERB
eurjchem-604	283	13	same	same	ADJ
eurjchem-604	283	14	results	result	NOUN
eurjchem-604	283	15	as	as	SCONJ
eurjchem-604	283	16	found	find	VERB
eurjchem-604	283	17	by	by	ADP
eurjchem-604	283	18	reactions	reaction	NOUN
eurjchem-604	283	19	of	of	ADP
eurjchem-604	283	20	m(co)5thf	m(co)5thf	NOUN
eurjchem-604	283	21	and	and	CCONJ
eurjchem-604	283	22	ligand	ligand	NOUN
eurjchem-604	283	23	.	.	PUNCT
eurjchem-604	284	1	reaction	reaction	NOUN
eurjchem-604	284	2	of	of	ADP
eurjchem-604	284	3	m(co)6	m(co)6	PROPN
eurjchem-604	284	4	with	with	ADP
eurjchem-604	284	5	3,5‐dimethyl‐4‐	3,5‐dimethyl‐4‐	NUM
eurjchem-604	284	6	ferrocenylmethylpyrazole	ferrocenylmethylpyrazole	NOUN
eurjchem-604	284	7	under	under	ADP
eurjchem-604	284	8	uv	uv	NOUN
eurjchem-604	284	9	irradiation	irradiation	NOUN
eurjchem-604	284	10	using	use	VERB
eurjchem-604	284	11	thf	thf	NOUN
eurjchem-604	284	12	as	as	SCONJ
eurjchem-604	284	13	solvent	solvent	NOUN
eurjchem-604	284	14	yields	yield	NOUN
eurjchem-604	284	15	monosubstituted	monosubstitute	VERB
eurjchem-604	284	16	group	group	NOUN
eurjchem-604	284	17	6	6	NUM
eurjchem-604	284	18	metalcarbonyl	metalcarbonyl	NOUN
eurjchem-604	284	19	complexes	complex	NOUN
eurjchem-604	284	20	m(co)5l	m(co)5l	INTJ
eurjchem-604	284	21	(	(	PUNCT
eurjchem-604	284	22	m	m	PROPN
eurjchem-604	284	23	=	=	SYM
eurjchem-604	284	24	cr	cr	PROPN
eurjchem-604	284	25	,	,	PUNCT
eurjchem-604	284	26	mo	mo	PROPN
eurjchem-604	284	27	or	or	CCONJ
eurjchem-604	284	28	w	w	NOUN
eurjchem-604	284	29	;	;	PUNCT
eurjchem-604	284	30	l	l	NOUN
eurjchem-604	284	31	=	=	SYM
eurjchem-604	284	32	3,5‐dimethyl‐4‐	3,5‐dimethyl‐4‐	NUM
eurjchem-604	284	33	ferrocenylmethylpyrazole	ferrocenylmethylpyrazole	NOUN
eurjchem-604	284	34	)	)	PUNCT
eurjchem-604	284	35	(	(	PUNCT
eurjchem-604	284	36	scheme	scheme	NOUN
eurjchem-604	284	37	13	13	NUM
eurjchem-604	284	38	)	)	PUNCT
eurjchem-604	285	1	[	[	X
eurjchem-604	285	2	54	54	NUM
eurjchem-604	285	3	]	]	PUNCT
eurjchem-604	285	4	.	.	PUNCT
eurjchem-604	286	1	the	the	DET
eurjchem-604	286	2	anionic	anionic	ADJ
eurjchem-604	286	3	complexes	complex	NOUN
eurjchem-604	286	4	[	[	X
eurjchem-604	286	5	et4n	et4n	X
eurjchem-604	286	6	]	]	X
eurjchem-604	287	1	[	[	X
eurjchem-604	287	2	m(co)5scph3	m(co)5scph3	X
eurjchem-604	287	3	]	]	X
eurjchem-604	287	4	(	(	PUNCT
eurjchem-604	287	5	m	m	PROPN
eurjchem-604	287	6	=	=	SYM
eurjchem-604	287	7	mo	mo	PROPN
eurjchem-604	287	8	,	,	PUNCT
eurjchem-604	287	9	w	w	NOUN
eurjchem-604	287	10	)	)	PUNCT
eurjchem-604	287	11	were	be	AUX
eurjchem-604	287	12	also	also	ADV
eurjchem-604	287	13	prepared	prepare	VERB
eurjchem-604	287	14	by	by	ADP
eurjchem-604	287	15	direct	direct	ADJ
eurjchem-604	287	16	thermal	thermal	ADJ
eurjchem-604	287	17	reaction	reaction	NOUN
eurjchem-604	287	18	of	of	ADP
eurjchem-604	287	19	equimolar	equimolar	NOUN
eurjchem-604	287	20	amounts	amount	NOUN
eurjchem-604	287	21	of	of	ADP
eurjchem-604	287	22	[	[	X
eurjchem-604	287	23	et4n	et4n	X
eurjchem-604	287	24	]	]	X
eurjchem-604	287	25	[	[	X
eurjchem-604	287	26	scph3	scph3	NOUN
eurjchem-604	287	27	]	]	PUNCT
eurjchem-604	287	28	and	and	CCONJ
eurjchem-604	287	29	the	the	DET
eurjchem-604	287	30	hexacarbonyl	hexacarbonyl	ADJ
eurjchem-604	287	31	parent	parent	NOUN
eurjchem-604	287	32	,	,	PUNCT
eurjchem-604	287	33	m(co)6	m(co)6	PROPN
eurjchem-604	287	34	,	,	PUNCT
eurjchem-604	287	35	in	in	ADP
eurjchem-604	287	36	thf	thf	NOUN
eurjchem-604	287	37	solutions	solution	NOUN
eurjchem-604	287	38	[	[	X
eurjchem-604	287	39	38	38	NUM
eurjchem-604	287	40	]	]	PUNCT
eurjchem-604	287	41	.	.	PUNCT
eurjchem-604	288	1	fcch2	fcch2	PROPN
eurjchem-604	288	2	n	n	PROPN
eurjchem-604	288	3	nh	nh	PROPN
eurjchem-604	288	4	m(co)6	m(co)6	NUM
eurjchem-604	288	5	thf	thf	NOUN
eurjchem-604	288	6	,	,	PUNCT
eurjchem-604	288	7	h	h	NOUN
eurjchem-604	288	8	fcch2	fcch2	PROPN
eurjchem-604	288	9	n	n	PROPN
eurjchem-604	288	10	nh	nh	PROPN
eurjchem-604	288	11	m(co)5	m(co)5	PROPN
eurjchem-604	288	12	scheme	scheme	NOUN
eurjchem-604	288	13	13	13	NUM
eurjchem-604	288	14	2.3.1.2	2.3.1.2	NUM
eurjchem-604	288	15	m(co)5c60	m(co)5c60	NOUN
eurjchem-604	288	16	fullerene	fullerene	NOUN
eurjchem-604	288	17	(	(	PUNCT
eurjchem-604	288	18	c60	c60	NOUN
eurjchem-604	288	19	)	)	PUNCT
eurjchem-604	288	20	also	also	ADV
eurjchem-604	288	21	shows	show	VERB
eurjchem-604	288	22	some	some	DET
eurjchem-604	288	23	pathways	pathway	NOUN
eurjchem-604	288	24	in	in	ADP
eurjchem-604	288	25	preparations	preparation	NOUN
eurjchem-604	288	26	of	of	ADP
eurjchem-604	288	27	organometallic	organometallic	ADJ
eurjchem-604	288	28	compounds	compound	NOUN
eurjchem-604	288	29	.	.	PUNCT
eurjchem-604	289	1	the	the	DET
eurjchem-604	289	2	fullerene	fullerene	NOUN
eurjchem-604	289	3	shows	show	VERB
eurjchem-604	289	4	substitution	substitution	NOUN
eurjchem-604	289	5	of	of	ADP
eurjchem-604	289	6	some	some	DET
eurjchem-604	289	7	ligands	ligand	NOUN
eurjchem-604	289	8	like	like	ADP
eurjchem-604	289	9	acetonitril	acetonitril	NOUN
eurjchem-604	289	10	and	and	CCONJ
eurjchem-604	289	11	co	co	NOUN
eurjchem-604	289	12	or	or	CCONJ
eurjchem-604	289	13	vice	vice	ADV
eurjchem-604	289	14	versa	versa	ADV
eurjchem-604	289	15	with	with	ADP
eurjchem-604	289	16	some	some	DET
eurjchem-604	289	17	ligands	ligand	NOUN
eurjchem-604	289	18	like	like	ADP
eurjchem-604	289	19	pph3	pph3	NOUN
eurjchem-604	289	20	and	and	CCONJ
eurjchem-604	289	21	pcy3	pcy3	PROPN
eurjchem-604	289	22	.	.	PUNCT
eurjchem-604	290	1	the	the	DET
eurjchem-604	290	2	studies	study	NOUN
eurjchem-604	290	3	on	on	ADP
eurjchem-604	290	4	chemical	chemical	ADJ
eurjchem-604	290	5	reactivity	reactivity	NOUN
eurjchem-604	290	6	of	of	ADP
eurjchem-604	290	7	fullerene	fullerene	NOUN
eurjchem-604	290	8	c60	c60	NOUN
eurjchem-604	290	9	towards	towards	ADP
eurjchem-604	290	10	fac‐mo(co)3(mecn)(dppe	fac‐mo(co)3(mecn)(dppe	NOUN
eurjchem-604	290	11	)	)	PUNCT
eurjchem-604	290	12	and	and	CCONJ
eurjchem-604	290	13	me(co)4(dppe	me(co)4(dppe	PROPN
eurjchem-604	290	14	)	)	PUNCT
eurjchem-604	290	15	shows	show	VERB
eurjchem-604	290	16	that	that	SCONJ
eurjchem-604	290	17	the	the	DET
eurjchem-604	290	18	c60	c60	NOUN
eurjchem-604	290	19	easily	easily	ADV
eurjchem-604	290	20	replace	replace	VERB
eurjchem-604	290	21	acetonitril	acetonitril	NOUN
eurjchem-604	290	22	ligands	ligand	NOUN
eurjchem-604	290	23	in	in	ADP
eurjchem-604	290	24	chlorobenzene	chlorobenzene	NOUN
eurjchem-604	290	25	at	at	ADP
eurjchem-604	290	26	about	about	ADP
eurjchem-604	290	27	80oc	80oc	PROPN
eurjchem-604	290	28	to	to	PART
eurjchem-604	290	29	give	give	VERB
eurjchem-604	290	30	fac‐mo(co)3(dppe	fac‐mo(co)3(dppe	PROPN
eurjchem-604	290	31	)	)	PUNCT
eurjchem-604	290	32	(	(	PUNCT
eurjchem-604	290	33	ƞ2‐c60	ƞ2‐c60	NOUN
eurjchem-604	290	34	)	)	PUNCT
eurjchem-604	290	35	,	,	PUNCT
eurjchem-604	290	36	whereas	whereas	SCONJ
eurjchem-604	290	37	fullerene	fullerene	NOUN
eurjchem-604	290	38	c60	c60	NOUN
eurjchem-604	290	39	reacted	react	VERB
eurjchem-604	290	40	with	with	ADP
eurjchem-604	290	41	me(co)4(dppe	me(co)4(dppe	PROPN
eurjchem-604	290	42	)	)	PUNCT
eurjchem-604	290	43	in	in	ADP
eurjchem-604	290	44	refluxing	refluxing	NOUN
eurjchem-604	290	45	chlorobenzene	chlorobenzene	NOUN
eurjchem-604	290	46	to	to	PART
eurjchem-604	290	47	afford	afford	VERB
eurjchem-604	290	48	an	an	DET
eurjchem-604	290	49	isomeric	isomeric	ADJ
eurjchem-604	290	50	mixture	mixture	NOUN
eurjchem-604	290	51	of	of	ADP
eurjchem-604	290	52	fac‐	fac‐	PROPN
eurjchem-604	290	53	and	and	CCONJ
eurjchem-604	290	54	mer‐mo(co)3(dppe)(ƞ2‐	mer‐mo(co)3(dppe)(ƞ2‐	ADJ
eurjchem-604	290	55	c60	c60	NOUN
eurjchem-604	290	56	)	)	PUNCT
eurjchem-604	291	1	[	[	X
eurjchem-604	291	2	55	55	NUM
eurjchem-604	291	3	]	]	PUNCT
eurjchem-604	291	4	.	.	PUNCT
eurjchem-604	292	1	the	the	DET
eurjchem-604	292	2	lewis	lewis	PROPN
eurjchem-604	292	3	bases	basis	NOUN
eurjchem-604	292	4	(	(	PUNCT
eurjchem-604	292	5	l	l	NOUN
eurjchem-604	292	6	)	)	PUNCT
eurjchem-604	292	7	triphenylphosphine	triphenylphosphine	NOUN
eurjchem-604	292	8	(	(	PUNCT
eurjchem-604	292	9	pph3	pph3	PROPN
eurjchem-604	292	10	)	)	PUNCT
eurjchem-604	292	11	and	and	CCONJ
eurjchem-604	292	12	tricyclohexyl	tricyclohexyl	PROPN
eurjchem-604	292	13	phosphine	phosphine	NOUN
eurjchem-604	292	14	(	(	PUNCT
eurjchem-604	292	15	p(cy)3	p(cy)3	NOUN
eurjchem-604	292	16	)	)	PUNCT
eurjchem-604	292	17	displace	displace	VERB
eurjchem-604	292	18	60‐fullerene	60‐fullerene	NUM
eurjchem-604	292	19	(	(	PUNCT
eurjchem-604	292	20	c60	c60	NOUN
eurjchem-604	292	21	)	)	PUNCT
eurjchem-604	292	22	retracted	retract	VERB
eurjchem-604	292	23	374	374	NUM
eurjchem-604	292	24	kaushik	kaushik	NOUN
eurjchem-604	292	25	et	et	PROPN
eurjchem-604	292	26	al	al	PROPN
eurjchem-604	292	27	.	.	PUNCT
eurjchem-604	292	28	/	/	SYM
eurjchem-604	292	29	european	european	PROPN
eurjchem-604	292	30	journal	journal	PROPN
eurjchem-604	292	31	of	of	ADP
eurjchem-604	292	32	chemistry	chemistry	NOUN
eurjchem-604	292	33	3	3	NUM
eurjchem-604	292	34	(	(	PUNCT
eurjchem-604	292	35	3	3	NUM
eurjchem-604	292	36	)	)	PUNCT
eurjchem-604	292	37	(	(	PUNCT
eurjchem-604	292	38	2012	2012	NUM
eurjchem-604	292	39	)	)	PUNCT
eurjchem-604	292	40	367‐394	367‐394	NOUN
eurjchem-604	292	41	from	from	ADP
eurjchem-604	292	42	the	the	DET
eurjchem-604	292	43	complex	complex	ADJ
eurjchem-604	292	44	fac‐(η2‐c60)(η2‐phen)m(co)3	fac‐(η2‐c60)(η2‐phen)m(co)3	NOUN
eurjchem-604	292	45	(	(	PUNCT
eurjchem-604	292	46	m	m	PROPN
eurjchem-604	292	47	=	=	SYM
eurjchem-604	292	48	mo	mo	PROPN
eurjchem-604	292	49	,	,	PUNCT
eurjchem-604	292	50	w	w	PROPN
eurjchem-604	292	51	)	)	PUNCT
eurjchem-604	292	52	(	(	PUNCT
eurjchem-604	292	53	phen	phen	NOUN
eurjchem-604	292	54	=	=	SYM
eurjchem-604	292	55	1,10‐phenanthroline	1,10‐phenanthroline	PROPN
eurjchem-604	292	56	)	)	PUNCT
eurjchem-604	292	57	(	(	PUNCT
eurjchem-604	292	58	scheme	scheme	NOUN
eurjchem-604	292	59	14	14	NUM
eurjchem-604	292	60	)	)	PUNCT
eurjchem-604	293	1	[	[	X
eurjchem-604	293	2	56,57	56,57	NOUN
eurjchem-604	293	3	]	]	X
eurjchem-604	293	4	.	.	PUNCT
eurjchem-604	294	1	scheme	scheme	VERB
eurjchem-604	294	2	14	14	NUM
eurjchem-604	294	3	2.3.2	2.3.2	NUM
eurjchem-604	294	4	.	.	PUNCT
eurjchem-604	295	1	m(co)4	m(co)4	NOUN
eurjchem-604	295	2	transfer	transfer	NOUN
eurjchem-604	295	3	reagents	reagent	NOUN
eurjchem-604	295	4	these	these	DET
eurjchem-604	295	5	reagents	reagent	NOUN
eurjchem-604	295	6	have	have	VERB
eurjchem-604	295	7	their	their	PRON
eurjchem-604	295	8	remarkable	remarkable	ADJ
eurjchem-604	295	9	importance	importance	NOUN
eurjchem-604	295	10	in	in	ADP
eurjchem-604	295	11	synthesis	synthesis	NOUN
eurjchem-604	295	12	of	of	ADP
eurjchem-604	295	13	metal	metal	NOUN
eurjchem-604	295	14	carbonyl	carbonyl	NOUN
eurjchem-604	295	15	complexes	complex	NOUN
eurjchem-604	295	16	with	with	ADP
eurjchem-604	295	17	ligands	ligand	NOUN
eurjchem-604	295	18	.	.	PUNCT
eurjchem-604	296	1	these	these	DET
eurjchem-604	296	2	m(co)4	m(co)4	NOUN
eurjchem-604	296	3	transfer	transfer	NOUN
eurjchem-604	296	4	reagents	reagent	NOUN
eurjchem-604	296	5	form	form	VERB
eurjchem-604	296	6	some	some	DET
eurjchem-604	296	7	complexes	complex	NOUN
eurjchem-604	296	8	which	which	PRON
eurjchem-604	296	9	were	be	AUX
eurjchem-604	296	10	not	not	PART
eurjchem-604	296	11	easily	easily	ADV
eurjchem-604	296	12	formed	form	VERB
eurjchem-604	296	13	by	by	ADP
eurjchem-604	296	14	direct	direct	ADJ
eurjchem-604	296	15	reaction	reaction	NOUN
eurjchem-604	296	16	of	of	ADP
eurjchem-604	296	17	m(co)6	m(co)6	PROPN
eurjchem-604	296	18	with	with	ADP
eurjchem-604	296	19	ligands	ligand	NOUN
eurjchem-604	296	20	.	.	PUNCT
eurjchem-604	297	1	in	in	ADP
eurjchem-604	297	2	this	this	DET
eurjchem-604	297	3	project	project	NOUN
eurjchem-604	297	4	we	we	PRON
eurjchem-604	297	5	use	use	VERB
eurjchem-604	297	6	m(co)4nbd	m(co)4nbd	NOUN
eurjchem-604	297	7	as	as	ADP
eurjchem-604	297	8	m(co)4	m(co)4	NOUN
eurjchem-604	297	9	transfer	transfer	NOUN
eurjchem-604	297	10	reagent	reagent	NOUN
eurjchem-604	297	11	and	and	CCONJ
eurjchem-604	297	12	prepared	prepared	ADJ
eurjchem-604	297	13	m(co)4l	m(co)4l	ADJ
eurjchem-604	297	14	type	type	NOUN
eurjchem-604	297	15	complexes	complex	NOUN
eurjchem-604	297	16	with	with	ADP
eurjchem-604	297	17	tdd	tdd	NOUN
eurjchem-604	297	18	.	.	PUNCT
eurjchem-604	298	1	if	if	SCONJ
eurjchem-604	298	2	such	such	ADJ
eurjchem-604	298	3	reaction	reaction	NOUN
eurjchem-604	298	4	carried	carry	VERB
eurjchem-604	298	5	out	out	ADP
eurjchem-604	298	6	with	with	ADP
eurjchem-604	298	7	m(co)6	m(co)6	NOUN
eurjchem-604	298	8	and	and	CCONJ
eurjchem-604	298	9	tdd	tdd	NOUN
eurjchem-604	298	10	in	in	ADP
eurjchem-604	298	11	equimolar	equimolar	ADJ
eurjchem-604	298	12	quantities	quantity	NOUN
eurjchem-604	298	13	mono‐substituted	mono‐substitute	VERB
eurjchem-604	298	14	complexes	complex	NOUN
eurjchem-604	298	15	were	be	AUX
eurjchem-604	298	16	formed	form	VERB
eurjchem-604	298	17	.	.	PUNCT
eurjchem-604	299	1	if	if	SCONJ
eurjchem-604	299	2	we	we	PRON
eurjchem-604	299	3	use	use	VERB
eurjchem-604	299	4	metalcarbonyls	metalcarbonyls	NOUN
eurjchem-604	299	5	in	in	ADP
eurjchem-604	299	6	bimolar	bimolar	ADJ
eurjchem-604	299	7	quantity	quantity	NOUN
eurjchem-604	299	8	,	,	PUNCT
eurjchem-604	299	9	binuclear	binuclear	NOUN
eurjchem-604	299	10	complexes	complex	NOUN
eurjchem-604	299	11	were	be	AUX
eurjchem-604	299	12	formed	form	VERB
eurjchem-604	299	13	.	.	PUNCT
eurjchem-604	300	1	in	in	ADP
eurjchem-604	300	2	other	other	ADJ
eurjchem-604	300	3	preparation	preparation	NOUN
eurjchem-604	300	4	we	we	PRON
eurjchem-604	300	5	use	use	VERB
eurjchem-604	300	6	m(co)4cod	m(co)4cod	NOUN
eurjchem-604	300	7	as	as	ADP
eurjchem-604	300	8	m(co)4	m(co)4	NOUN
eurjchem-604	300	9	transfer	transfer	NOUN
eurjchem-604	300	10	reagent	reagent	NOUN
eurjchem-604	300	11	with	with	ADP
eurjchem-604	300	12	dttt	dttt	NOUN
eurjchem-604	300	13	.	.	PUNCT
eurjchem-604	301	1	dttt	dttt	PROPN
eurjchem-604	301	2	is	be	AUX
eurjchem-604	301	3	a	a	DET
eurjchem-604	301	4	monodentate	monodentate	ADJ
eurjchem-604	301	5	ligand	ligand	NOUN
eurjchem-604	301	6	and	and	CCONJ
eurjchem-604	301	7	form	form	VERB
eurjchem-604	301	8	m(co)5dttt	m(co)5dttt	PROPN
eurjchem-604	302	1	but	but	CCONJ
eurjchem-604	302	2	we	we	PRON
eurjchem-604	302	3	were	be	AUX
eurjchem-604	302	4	keen	keen	ADJ
eurjchem-604	302	5	to	to	PART
eurjchem-604	302	6	form	form	VERB
eurjchem-604	302	7	bisubstituted	bisubstitute	VERB
eurjchem-604	302	8	complexes	complex	NOUN
eurjchem-604	302	9	with	with	ADP
eurjchem-604	302	10	dttt	dttt	PROPN
eurjchem-604	302	11	,	,	PUNCT
eurjchem-604	302	12	when	when	SCONJ
eurjchem-604	302	13	we	we	PRON
eurjchem-604	302	14	use	use	VERB
eurjchem-604	302	15	m(co)4cod	m(co)4cod	NOUN
eurjchem-604	302	16	as	as	ADP
eurjchem-604	302	17	m(co)4	m(co)4	NOUN
eurjchem-604	302	18	transfer	transfer	NOUN
eurjchem-604	302	19	reagent	reagent	NOUN
eurjchem-604	302	20	,	,	PUNCT
eurjchem-604	302	21	bisubstituted	bisubstitute	VERB
eurjchem-604	302	22	complexes	complex	NOUN
eurjchem-604	302	23	m(co)4(dttt)2	m(co)4(dttt)2	NOUN
eurjchem-604	302	24	were	be	AUX
eurjchem-604	302	25	formed	form	VERB
eurjchem-604	302	26	.	.	PUNCT
eurjchem-604	303	1	the	the	DET
eurjchem-604	303	2	thermal	thermal	ADJ
eurjchem-604	303	3	substitution	substitution	NOUN
eurjchem-604	303	4	of	of	ADP
eurjchem-604	303	5	mo(co)4(η2:2‐cod	mo(co)4(η2:2‐cod	NOUN
eurjchem-604	303	6	)	)	PUNCT
eurjchem-604	303	7	and	and	CCONJ
eurjchem-604	303	8	mo(co)4(η2:2‐nbd	mo(co)4(η2:2‐nbd	NOUN
eurjchem-604	303	9	)	)	PUNCT
eurjchem-604	303	10	with	with	ADP
eurjchem-604	303	11	,	,	PUNCT
eurjchem-604	303	12	bfeda	bfeda	PROPN
eurjchem-604	303	13	gave	give	VERB
eurjchem-604	303	14	the	the	DET
eurjchem-604	303	15	same	same	ADJ
eurjchem-604	303	16	product	product	NOUN
eurjchem-604	303	17	which	which	PRON
eurjchem-604	303	18	was	be	AUX
eurjchem-604	303	19	isolated	isolate	VERB
eurjchem-604	303	20	by	by	ADP
eurjchem-604	303	21	using	use	VERB
eurjchem-604	303	22	the	the	DET
eurjchem-604	303	23	same	same	ADJ
eurjchem-604	303	24	procedure	procedure	NOUN
eurjchem-604	303	25	.	.	PUNCT
eurjchem-604	304	1	thus	thus	ADV
eurjchem-604	304	2	,	,	PUNCT
eurjchem-604	304	3	both	both	PRON
eurjchem-604	304	4	of	of	ADP
eurjchem-604	304	5	mo(co)4(η2:2‐nbd	mo(co)4(η2:2‐nbd	PROPN
eurjchem-604	304	6	)	)	PUNCT
eurjchem-604	304	7	and	and	CCONJ
eurjchem-604	304	8	of	of	ADP
eurjchem-604	304	9	mo(co)4(η2:2‐cod	mo(co)4(η2:2‐cod	NUM
eurjchem-604	304	10	)	)	PUNCT
eurjchem-604	304	11	can	can	AUX
eurjchem-604	304	12	be	be	AUX
eurjchem-604	304	13	used	use	VERB
eurjchem-604	304	14	as	as	ADP
eurjchem-604	304	15	mo(co)4	mo(co)4	NOUN
eurjchem-604	304	16	transfer	transfer	NOUN
eurjchem-604	304	17	reagent	reagent	NOUN
eurjchem-604	304	18	for	for	ADP
eurjchem-604	304	19	the	the	DET
eurjchem-604	304	20	synthesis	synthesis	NOUN
eurjchem-604	304	21	of	of	ADP
eurjchem-604	304	22	mo(co)4(bfeda	mo(co)4(bfeda	PROPN
eurjchem-604	304	23	)	)	PUNCT
eurjchem-604	305	1	[	[	X
eurjchem-604	305	2	58	58	NUM
eurjchem-604	305	3	]	]	PUNCT
eurjchem-604	305	4	.	.	PUNCT
eurjchem-604	306	1	2.3.2.1	2.3.2.1	X
eurjchem-604	306	2	.	.	PUNCT
eurjchem-604	306	3	m(co)4	m(co)4	PROPN
eurjchem-604	306	4	nbd	nbd	PROPN
eurjchem-604	306	5	2.3.2.1.1	2.3.2.1.1	PROPN
eurjchem-604	306	6	.	.	PUNCT
eurjchem-604	306	7	preparation	preparation	NOUN
eurjchem-604	306	8	of	of	ADP
eurjchem-604	306	9	[	[	X
eurjchem-604	306	10	m(co)4(nbd	m(co)4(nbd	NOUN
eurjchem-604	306	11	)	)	PUNCT
eurjchem-604	306	12	]	]	PUNCT
eurjchem-604	307	1	r.	r.	PROPN
eurjchem-604	307	2	b.	b.	PROPN
eurjchem-604	307	3	king	king	PROPN
eurjchem-604	307	4	prepared	prepare	VERB
eurjchem-604	307	5	[	[	X
eurjchem-604	307	6	m(co)4(nbd	m(co)4(nbd	NOUN
eurjchem-604	307	7	)	)	PUNCT
eurjchem-604	307	8	]	]	PUNCT
eurjchem-604	307	9	by	by	ADP
eurjchem-604	307	10	refluxing	refluxing	NOUN
eurjchem-604	307	11	m(co)6	m(co)6	PROPN
eurjchem-604	307	12	and	and	CCONJ
eurjchem-604	307	13	2,5‐norbornadiene	2,5‐norbornadiene	NUM
eurjchem-604	307	14	(	(	PUNCT
eurjchem-604	307	15	η2:2‐nbd	η2:2‐nbd	PROPN
eurjchem-604	307	16	)	)	PUNCT
eurjchem-604	307	17	in	in	ADP
eurjchem-604	307	18	25	25	NUM
eurjchem-604	307	19	ml	ml	NOUN
eurjchem-604	307	20	iso‐octane	iso‐octane	NOUN
eurjchem-604	307	21	.	.	PUNCT
eurjchem-604	308	1	and	and	CCONJ
eurjchem-604	308	2	yield	yield	VERB
eurjchem-604	308	3	yellow	yellow	ADJ
eurjchem-604	308	4	crystals	crystal	NOUN
eurjchem-604	308	5	of	of	ADP
eurjchem-604	308	6	the	the	DET
eurjchem-604	308	7	complex	complex	NOUN
eurjchem-604	308	8	on	on	ADP
eurjchem-604	308	9	crystallization	crystallization	NOUN
eurjchem-604	308	10	from	from	ADP
eurjchem-604	308	11	n‐hexane	n‐hexane	NOUN
eurjchem-604	308	12	solution	solution	NOUN
eurjchem-604	308	13	[	[	X
eurjchem-604	308	14	59‐61	59‐61	NUM
eurjchem-604	308	15	]	]	PUNCT
eurjchem-604	308	16	.	.	PUNCT
eurjchem-604	309	1	bennett	bennett	PROPN
eurjchem-604	309	2	et	et	PROPN
eurjchem-604	309	3	al	al	PROPN
eurjchem-604	309	4	.	.	PROPN
eurjchem-604	310	1	later	later	ADV
eurjchem-604	310	2	also	also	ADV
eurjchem-604	310	3	prepared	prepare	VERB
eurjchem-604	310	4	[	[	X
eurjchem-604	310	5	m(co)4(nbd	m(co)4(nbd	NOUN
eurjchem-604	310	6	)	)	PUNCT
eurjchem-604	310	7	]	]	PUNCT
eurjchem-604	310	8	with	with	ADP
eurjchem-604	310	9	some	some	DET
eurjchem-604	310	10	other	other	ADJ
eurjchem-604	310	11	parallel	parallel	ADJ
eurjchem-604	310	12	method	method	NOUN
eurjchem-604	310	13	[	[	X
eurjchem-604	310	14	62	62	NUM
eurjchem-604	310	15	]	]	PUNCT
eurjchem-604	310	16	.	.	PUNCT
eurjchem-604	311	1	2.3.2.1.2	2.3.2.1.2	X
eurjchem-604	311	2	.	.	PUNCT
eurjchem-604	312	1	uses	use	NOUN
eurjchem-604	312	2	of	of	ADP
eurjchem-604	312	3	[	[	PUNCT
eurjchem-604	312	4	m(co)4(nbd)]as	m(co)4(nbd)]as	ADJ
eurjchem-604	312	5	m(co)4	m(co)4	NOUN
eurjchem-604	312	6	transfer	transfer	NOUN
eurjchem-604	312	7	agent	agent	NOUN
eurjchem-604	312	8	reaction	reaction	NOUN
eurjchem-604	312	9	of	of	ADP
eurjchem-604	312	10	norbornadiene	norbornadiene	ADJ
eurjchem-604	312	11	complex	complex	NOUN
eurjchem-604	312	12	c7h8cr(co)4	c7h8cr(co)4	X
eurjchem-604	312	13	with	with	ADP
eurjchem-604	312	14	tris(dimethylamino)arsine	tris(dimethylamino)arsine	NOUN
eurjchem-604	312	15	(	(	PUNCT
eurjchem-604	312	16	tdas	tda	NOUN
eurjchem-604	312	17	)	)	PUNCT
eurjchem-604	312	18	at	at	ADP
eurjchem-604	312	19	room	room	NOUN
eurjchem-604	312	20	temperature	temperature	NOUN
eurjchem-604	312	21	gives	give	VERB
eurjchem-604	312	22	trans‐(tdas)2cr(co)4	trans‐(tdas)2cr(co)4	PRON
eurjchem-604	312	23	which	which	PRON
eurjchem-604	312	24	was	be	AUX
eurjchem-604	312	25	isolated	isolate	VERB
eurjchem-604	312	26	as	as	ADP
eurjchem-604	312	27	yellow	yellow	ADJ
eurjchem-604	312	28	complex	complex	NOUN
eurjchem-604	312	29	.	.	PUNCT
eurjchem-604	313	1	while	while	SCONJ
eurjchem-604	313	2	the	the	DET
eurjchem-604	313	3	reaction	reaction	NOUN
eurjchem-604	313	4	of	of	ADP
eurjchem-604	313	5	m(co)6	m(co)6	PROPN
eurjchem-604	313	6	with	with	ADP
eurjchem-604	313	7	tdas	tda	NOUN
eurjchem-604	313	8	gives	give	VERB
eurjchem-604	313	9	monosubstituted	monosubstitute	VERB
eurjchem-604	313	10	complex	complex	ADJ
eurjchem-604	313	11	(	(	PUNCT
eurjchem-604	313	12	tdas)cr(co)5	tdas)cr(co)5	PROPN
eurjchem-604	314	1	[	[	X
eurjchem-604	314	2	63	63	NUM
eurjchem-604	314	3	]	]	PUNCT
eurjchem-604	314	4	.	.	PUNCT
eurjchem-604	315	1	[	[	X
eurjchem-604	315	2	m(co)4(nbd	m(co)4(nbd	NOUN
eurjchem-604	315	3	)	)	PUNCT
eurjchem-604	315	4	]	]	PUNCT
eurjchem-604	316	1	(	(	PUNCT
eurjchem-604	316	2	m	m	NOUN
eurjchem-604	316	3	=	=	NOUN
eurjchem-604	316	4	cr	cr	NOUN
eurjchem-604	316	5	or	or	CCONJ
eurjchem-604	316	6	mo	mo	PROPN
eurjchem-604	316	7	)	)	PUNCT
eurjchem-604	316	8	react	react	VERB
eurjchem-604	316	9	with	with	ADP
eurjchem-604	316	10	l1	l1	PROPN
eurjchem-604	316	11	(	(	PUNCT
eurjchem-604	316	12	ph2p(ch2)2o(ch2)2o(ch2)2pph2	ph2p(ch2)2o(ch2)2o(ch2)2pph2	PROPN
eurjchem-604	316	13	)	)	PUNCT
eurjchem-604	316	14	(	(	PUNCT
eurjchem-604	316	15	scheme	scheme	NOUN
eurjchem-604	316	16	15	15	NUM
eurjchem-604	316	17	)	)	PUNCT
eurjchem-604	316	18	to	to	PART
eurjchem-604	316	19	give	give	VERB
eurjchem-604	316	20	the	the	DET
eurjchem-604	316	21	trans‐	trans‐	PROPN
eurjchem-604	316	22	[	[	X
eurjchem-604	316	23	cr(co)4(l1	cr(co)4(l1	PROPN
eurjchem-604	316	24	)	)	PUNCT
eurjchem-604	316	25	]	]	PUNCT
eurjchem-604	316	26	and	and	CCONJ
eurjchem-604	316	27	cis‐	cis‐	NOUN
eurjchem-604	317	1	[	[	X
eurjchem-604	317	2	mo(co)4(l1	mo(co)4(l1	NOUN
eurjchem-604	317	3	)	)	PUNCT
eurjchem-604	317	4	]	]	PUNCT
eurjchem-604	317	5	respectively	respectively	ADV
eurjchem-604	317	6	,	,	PUNCT
eurjchem-604	317	7	both	both	PRON
eurjchem-604	317	8	of	of	ADP
eurjchem-604	317	9	which	which	PRON
eurjchem-604	317	10	show	show	VERB
eurjchem-604	317	11	coordination	coordination	NOUN
eurjchem-604	317	12	of	of	ADP
eurjchem-604	317	13	l1	l1	PROPN
eurjchem-604	317	14	through	through	ADP
eurjchem-604	317	15	the	the	DET
eurjchem-604	317	16	p	p	NOUN
eurjchem-604	317	17	atoms	atom	NOUN
eurjchem-604	317	18	only	only	ADV
eurjchem-604	317	19	,	,	PUNCT
eurjchem-604	317	20	giving	give	VERB
eurjchem-604	317	21	11‐membered	11‐membered	NUM
eurjchem-604	317	22	ring	ring	NOUN
eurjchem-604	317	23	metallocyclic	metallocyclic	NOUN
eurjchem-604	317	24	complexes	complex	NOUN
eurjchem-604	317	25	.	.	PUNCT
eurjchem-604	318	1	the	the	DET
eurjchem-604	318	2	crystal	crystal	NOUN
eurjchem-604	318	3	structure	structure	NOUN
eurjchem-604	318	4	of	of	ADP
eurjchem-604	318	5	[	[	X
eurjchem-604	318	6	mo(co)4(l1	mo(co)4(l1	NOUN
eurjchem-604	318	7	)	)	PUNCT
eurjchem-604	318	8	]	]	PUNCT
eurjchem-604	318	9	confirms	confirm	VERB
eurjchem-604	318	10	the	the	DET
eurjchem-604	318	11	cis‐geometry	cis‐geometry	NOUN
eurjchem-604	318	12	of	of	ADP
eurjchem-604	318	13	the	the	DET
eurjchem-604	318	14	product	product	NOUN
eurjchem-604	318	15	[	[	X
eurjchem-604	318	16	64	64	NUM
eurjchem-604	318	17	]	]	PUNCT
eurjchem-604	318	18	.	.	PUNCT
eurjchem-604	319	1	scheme	scheme	VERB
eurjchem-604	319	2	15	15	NUM
eurjchem-604	319	3	2.3.2.2	2.3.2.2	NUM
eurjchem-604	319	4	.	.	PUNCT
eurjchem-604	320	1	m(co)4	m(co)4	PROPN
eurjchem-604	320	2	cod	cod	NOUN
eurjchem-604	320	3	fisher	fisher	NOUN
eurjchem-604	320	4	and	and	CCONJ
eurjchem-604	320	5	frohlich	frohlich	NOUN
eurjchem-604	320	6	prepared	prepare	VERB
eurjchem-604	320	7	[	[	X
eurjchem-604	320	8	m(co)4(cod	m(co)4(cod	NOUN
eurjchem-604	320	9	)	)	PUNCT
eurjchem-604	320	10	]	]	PUNCT
eurjchem-604	320	11	by	by	ADP
eurjchem-604	320	12	refluxing	refluxing	NOUN
eurjchem-604	320	13	m(co)6	m(co)6	PROPN
eurjchem-604	320	14	and	and	CCONJ
eurjchem-604	320	15	1,5‐cyclooctadiene	1,5‐cyclooctadiene	NUM
eurjchem-604	320	16	(	(	PUNCT
eurjchem-604	320	17	cod	cod	NOUN
eurjchem-604	320	18	)	)	PUNCT
eurjchem-604	320	19	in	in	ADP
eurjchem-604	320	20	n‐heptane	n‐heptane	NUM
eurjchem-604	320	21	.	.	PUNCT
eurjchem-604	321	1	cooling	cool	VERB
eurjchem-604	321	2	the	the	DET
eurjchem-604	321	3	solution	solution	NOUN
eurjchem-604	321	4	to	to	ADP
eurjchem-604	321	5	‐35oc	‐35oc	VERB
eurjchem-604	321	6	yielded	yield	VERB
eurjchem-604	321	7	yellow	yellow	ADJ
eurjchem-604	321	8	crystals	crystal	NOUN
eurjchem-604	321	9	of	of	ADP
eurjchem-604	321	10	m(co)4(η2:2‐cod	m(co)4(η2:2‐cod	NOUN
eurjchem-604	321	11	)	)	PUNCT
eurjchem-604	322	1	[	[	X
eurjchem-604	322	2	65	65	NUM
eurjchem-604	322	3	]	]	PUNCT
eurjchem-604	322	4	.	.	PUNCT
eurjchem-604	323	1	r.	r.	PROPN
eurjchem-604	323	2	b.	b.	PROPN
eurjchem-604	323	3	king	king	PROPN
eurjchem-604	323	4	also	also	ADV
eurjchem-604	323	5	prepared	prepare	VERB
eurjchem-604	323	6	[	[	PUNCT
eurjchem-604	323	7	m(co)4(cod	m(co)4(cod	NOUN
eurjchem-604	323	8	)	)	PUNCT
eurjchem-604	323	9	]	]	PUNCT
eurjchem-604	324	1	later	later	ADV
eurjchem-604	324	2	[	[	X
eurjchem-604	324	3	66	66	NUM
eurjchem-604	324	4	]	]	PUNCT
eurjchem-604	324	5	.	.	PUNCT
eurjchem-604	325	1	the	the	DET
eurjchem-604	325	2	thermal	thermal	ADJ
eurjchem-604	325	3	substitution	substitution	NOUN
eurjchem-604	325	4	of	of	ADP
eurjchem-604	325	5	1,5‐cyclooctadiene	1,5‐cyclooctadiene	NUM
eurjchem-604	325	6	(	(	PUNCT
eurjchem-604	325	7	cod	cod	NOUN
eurjchem-604	325	8	)	)	PUNCT
eurjchem-604	325	9	by	by	ADP
eurjchem-604	325	10	bis(diphenylphosphino)alkanes	bis(diphenylphosphino)alkane	NOUN
eurjchem-604	325	11	,	,	PUNCT
eurjchem-604	325	12	(	(	PUNCT
eurjchem-604	325	13	c6h5)2p(ch2)np(c6h5)2	c6h5)2p(ch2)np(c6h5)2	PROPN
eurjchem-604	325	14	(	(	PUNCT
eurjchem-604	325	15	n	n	NOUN
eurjchem-604	325	16	=	=	SYM
eurjchem-604	325	17	1	1	NUM
eurjchem-604	325	18	,	,	PUNCT
eurjchem-604	325	19	2	2	NUM
eurjchem-604	325	20	,	,	PUNCT
eurjchem-604	325	21	3	3	NUM
eurjchem-604	325	22	)	)	PUNCT
eurjchem-604	325	23	in	in	ADP
eurjchem-604	325	24	m(co)4(η2:2‐cod	m(co)4(η2:2‐cod	NOUN
eurjchem-604	325	25	)	)	PUNCT
eurjchem-604	325	26	complexes	complex	NOUN
eurjchem-604	325	27	(	(	PUNCT
eurjchem-604	325	28	m	m	PROPN
eurjchem-604	325	29	=	=	SYM
eurjchem-604	325	30	cr	cr	PROPN
eurjchem-604	325	31	,	,	PUNCT
eurjchem-604	325	32	mo	mo	PROPN
eurjchem-604	325	33	,	,	PUNCT
eurjchem-604	325	34	w	w	PROPN
eurjchem-604	325	35	)	)	PUNCT
eurjchem-604	325	36	,	,	PUNCT
eurjchem-604	325	37	were	be	AUX
eurjchem-604	325	38	studied	study	VERB
eurjchem-604	325	39	by	by	ADP
eurjchem-604	325	40	kayran	kayran	PROPN
eurjchem-604	325	41	et	et	PROPN
eurjchem-604	325	42	al	al	PROPN
eurjchem-604	325	43	.	.	PUNCT
eurjchem-604	326	1	[	[	X
eurjchem-604	326	2	67	67	NUM
eurjchem-604	326	3	]	]	PUNCT
eurjchem-604	326	4	.	.	PUNCT
eurjchem-604	327	1	the	the	DET
eurjchem-604	327	2	reactions	reaction	NOUN
eurjchem-604	327	3	of	of	ADP
eurjchem-604	327	4	cr(co)4(cod	cr(co)4(cod	NOUN
eurjchem-604	327	5	)	)	PUNCT
eurjchem-604	327	6	and	and	CCONJ
eurjchem-604	327	7	mo(co)4(nbd	mo(co)4(nbd	PROPN
eurjchem-604	327	8	)	)	PUNCT
eurjchem-604	327	9	with	with	ADP
eurjchem-604	327	10	h5‐cp*ir(2,5‐dimethylthiophene	h5‐cp*ir(2,5‐dimethylthiophene	NOUN
eurjchem-604	327	11	)	)	PUNCT
eurjchem-604	327	12	give	give	VERB
eurjchem-604	327	13	modest	modest	ADJ
eurjchem-604	327	14	amounts	amount	NOUN
eurjchem-604	327	15	of	of	ADP
eurjchem-604	327	16	the	the	DET
eurjchem-604	327	17	[	[	X
eurjchem-604	327	18	h6‐cp*ir(c	h6‐cp*ir(c	PROPN
eurjchem-604	327	19	,	,	PUNCT
eurjchem-604	327	20	s‐2,5‐me2t)]m(co)3	s‐2,5‐me2t)]m(co)3	ADJ
eurjchem-604	327	21	products	product	NOUN
eurjchem-604	327	22	[	[	X
eurjchem-604	327	23	68	68	NUM
eurjchem-604	327	24	]	]	PUNCT
eurjchem-604	327	25	.	.	PUNCT
eurjchem-604	328	1	2.3.2.3	2.3.2.3	NUM
eurjchem-604	328	2	.	.	PUNCT
eurjchem-604	328	3	m(co)4	m(co)4	PROPN
eurjchem-604	328	4	(	(	PUNCT
eurjchem-604	328	5	piperidine)2	piperidine)2	NOUN
eurjchem-604	328	6	mariusz	mariusz	PROPN
eurjchem-604	328	7	et	et	PROPN
eurjchem-604	328	8	al	al	PROPN
eurjchem-604	328	9	.	.	PROPN
eurjchem-604	328	10	prepared	prepare	VERB
eurjchem-604	328	11	m(co)4(piperidine)2	m(co)4(piperidine)2	PROPN
eurjchem-604	328	12	where	where	SCONJ
eurjchem-604	328	13	(	(	PUNCT
eurjchem-604	328	14	m	m	PROPN
eurjchem-604	328	15	=	=	SYM
eurjchem-604	328	16	mo	mo	PROPN
eurjchem-604	328	17	,	,	PUNCT
eurjchem-604	328	18	w	w	PROPN
eurjchem-604	328	19	)	)	PUNCT
eurjchem-604	328	20	by	by	ADP
eurjchem-604	328	21	thermal	thermal	ADJ
eurjchem-604	328	22	reaction	reaction	NOUN
eurjchem-604	328	23	of	of	ADP
eurjchem-604	328	24	mo(co)6	mo(co)6	NOUN
eurjchem-604	328	25	with	with	ADP
eurjchem-604	328	26	piperidine	piperidine	NOUN
eurjchem-604	328	27	and	and	CCONJ
eurjchem-604	328	28	found	find	VERB
eurjchem-604	328	29	cis‐	cis‐	NOUN
eurjchem-604	328	30	bonding	bonding	NOUN
eurjchem-604	328	31	in	in	ADP
eurjchem-604	328	32	m(co)4(piperidine)2	m(co)4(piperidine)2	PROPN
eurjchem-604	328	33	.	.	PUNCT
eurjchem-604	329	1	the	the	DET
eurjchem-604	329	2	two	two	NUM
eurjchem-604	329	3	piperidine	piperidine	NOUN
eurjchem-604	329	4	ligands	ligand	NOUN
eurjchem-604	329	5	in	in	ADP
eurjchem-604	329	6	this	this	DET
eurjchem-604	329	7	yellow‐colored	yellow‐colore	VERB
eurjchem-604	329	8	compound	compound	NOUN
eurjchem-604	329	9	are	be	AUX
eurjchem-604	329	10	labile	labile	ADJ
eurjchem-604	329	11	,	,	PUNCT
eurjchem-604	329	12	which	which	PRON
eurjchem-604	329	13	allows	allow	VERB
eurjchem-604	329	14	other	other	ADJ
eurjchem-604	329	15	ligands	ligand	NOUN
eurjchem-604	329	16	to	to	PART
eurjchem-604	329	17	be	be	AUX
eurjchem-604	329	18	introduced	introduce	VERB
eurjchem-604	329	19	under	under	ADP
eurjchem-604	329	20	mild	mild	ADJ
eurjchem-604	329	21	conditions	condition	NOUN
eurjchem-604	329	22	and	and	CCONJ
eurjchem-604	329	23	its	its	PRON
eurjchem-604	329	24	dimmers	dimmer	NOUN
eurjchem-604	329	25	[	[	X
eurjchem-604	329	26	69	69	NUM
eurjchem-604	329	27	]	]	PUNCT
eurjchem-604	329	28	.	.	PUNCT
eurjchem-604	330	1	the	the	DET
eurjchem-604	330	2	reaction	reaction	NOUN
eurjchem-604	330	3	of	of	ADP
eurjchem-604	330	4	[	[	X
eurjchem-604	330	5	mo(co)4(piperidine)2	mo(co)4(piperidine)2	PROPN
eurjchem-604	330	6	]	]	PUNCT
eurjchem-604	330	7	with	with	ADP
eurjchem-604	330	8	triphenyl	triphenyl	NOUN
eurjchem-604	330	9	phosphine	phosphine	NOUN
eurjchem-604	330	10	in	in	ADP
eurjchem-604	330	11	boiling	boil	VERB
eurjchem-604	330	12	dichloromethane	dichloromethane	NOUN
eurjchem-604	330	13	(	(	PUNCT
eurjchem-604	330	14	b.p	b.p	PROPN
eurjchem-604	330	15	.	.	PUNCT
eurjchem-604	330	16	=	=	PUNCT
eurjchem-604	331	1	~40	~40	PUNCT
eurjchem-604	331	2	°	°	NOUN
eurjchem-604	331	3	c	c	X
eurjchem-604	331	4	)	)	PUNCT
eurjchem-604	331	5	gives	give	VERB
eurjchem-604	331	6	cis‐	cis‐	NOUN
eurjchem-604	331	7	[	[	X
eurjchem-604	331	8	mo(co)4(pph3)2	mo(co)4(pph3)2	X
eurjchem-604	331	9	]	]	X
eurjchem-604	331	10	.	.	PUNCT
eurjchem-604	332	1	this	this	DET
eurjchem-604	332	2	cis‐complex	cis‐complex	NOUN
eurjchem-604	332	3	isomerizes	isomerize	NOUN
eurjchem-604	332	4	in	in	ADP
eurjchem-604	332	5	toluene	toluene	NOUN
eurjchem-604	332	6	to	to	PART
eurjchem-604	332	7	trans‐[mo(co)4(pph3)2	trans‐[mo(co)4(pph3)2	VERB
eurjchem-604	332	8	]	]	X
eurjchem-604	333	1	[	[	X
eurjchem-604	333	2	70	70	NUM
eurjchem-604	333	3	]	]	PUNCT
eurjchem-604	333	4	.	.	PUNCT
eurjchem-604	334	1	the	the	DET
eurjchem-604	334	2	study	study	NOUN
eurjchem-604	334	3	on	on	ADP
eurjchem-604	334	4	carbonyl	carbonyl	NOUN
eurjchem-604	334	5	complexes	complex	NOUN
eurjchem-604	334	6	of	of	ADP
eurjchem-604	334	7	manganese	manganese	NOUN
eurjchem-604	334	8	,	,	PUNCT
eurjchem-604	334	9	rhenium	rhenium	NOUN
eurjchem-604	334	10	and	and	CCONJ
eurjchem-604	334	11	molybdenum	molybdenum	NOUN
eurjchem-604	334	12	with	with	ADP
eurjchem-604	334	13	ethynyliminopyridine	ethynyliminopyridine	NOUN
eurjchem-604	334	14	ligands	ligand	NOUN
eurjchem-604	334	15	found	find	VERB
eurjchem-604	334	16	that	that	SCONJ
eurjchem-604	334	17	[	[	X
eurjchem-604	334	18	mbr(co)5	mbr(co)5	NOUN
eurjchem-604	334	19	]	]	X
eurjchem-604	334	20	reacts	react	VERB
eurjchem-604	334	21	with	with	ADP
eurjchem-604	334	22	m‐ethynylphenylamine	m‐ethynylphenylamine	PUNCT
eurjchem-604	334	23	and	and	CCONJ
eurjchem-604	334	24	pyridine‐2‐carboxaldehyde	pyridine‐2‐carboxaldehyde	NUM
eurjchem-604	334	25	in	in	ADP
eurjchem-604	334	26	refluxing	refluxing	NOUN
eurjchem-604	334	27	tetrahydrofuran	tetrahydrofuran	NOUN
eurjchem-604	334	28	to	to	PART
eurjchem-604	334	29	give	give	VERB
eurjchem-604	334	30	,	,	PUNCT
eurjchem-604	334	31	fac‐	fac‐	PROPN
eurjchem-604	335	1	[	[	X
eurjchem-604	335	2	mbr(co)3(py‐2‐ch	mbr(co)3(py‐2‐ch	X
eurjchem-604	335	3	=	=	NOUN
eurjchem-604	335	4	n‐	n‐	NOUN
eurjchem-604	335	5	c6h4‐m‐(c≡ch	c6h4‐m‐(c≡ch	NOUN
eurjchem-604	335	6	)	)	PUNCT
eurjchem-604	335	7	)	)	PUNCT
eurjchem-604	335	8	]	]	PUNCT
eurjchem-604	336	1	(	(	PUNCT
eurjchem-604	336	2	m	m	PROPN
eurjchem-604	336	3	=	=	SYM
eurjchem-604	336	4	mn	mn	PROPN
eurjchem-604	336	5	,	,	PUNCT
eurjchem-604	336	6	1a	1a	NUM
eurjchem-604	336	7	;	;	PUNCT
eurjchem-604	336	8	re	re	NOUN
eurjchem-604	336	9	,	,	PUNCT
eurjchem-604	336	10	2a	2a	NUM
eurjchem-604	336	11	)	)	PUNCT
eurjchem-604	336	12	.	.	PUNCT
eurjchem-604	337	1	the	the	DET
eurjchem-604	337	2	same	same	ADJ
eurjchem-604	337	3	method	method	NOUN
eurjchem-604	337	4	affords	afford	VERB
eurjchem-604	337	5	the	the	DET
eurjchem-604	337	6	tetracarbonyl	tetracarbonyl	NOUN
eurjchem-604	337	7	[	[	X
eurjchem-604	337	8	mo(co)4{py‐2‐ch	mo(co)4{py‐2‐ch	X
eurjchem-604	337	9	=	=	NOUN
eurjchem-604	337	10	n‐c6h4‐m‐	n‐c6h4‐m‐	NOUN
eurjchem-604	337	11	(	(	PUNCT
eurjchem-604	337	12	c≡ch	c≡ch	X
eurjchem-604	337	13	)	)	PUNCT
eurjchem-604	337	14	}	}	PUNCT
eurjchem-604	337	15	]	]	PUNCT
eurjchem-604	337	16	(	(	PUNCT
eurjchem-604	337	17	3a	3a	NUM
eurjchem-604	337	18	)	)	PUNCT
eurjchem-604	337	19	starting	start	VERB
eurjchem-604	337	20	from	from	ADP
eurjchem-604	337	21	[	[	X
eurjchem-604	337	22	mo(co)4(piperidine)2	mo(co)4(piperidine)2	PROPN
eurjchem-604	337	23	]	]	X
eurjchem-604	338	1	[	[	X
eurjchem-604	338	2	71	71	NUM
eurjchem-604	338	3	]	]	PUNCT
eurjchem-604	338	4	.	.	PUNCT
eurjchem-604	339	1	robert	robert	PROPN
eurjchem-604	339	2	h.	h.	PROPN
eurjchem-604	339	3	guinn	guinn	PROPN
eurjchem-604	339	4	and	and	CCONJ
eurjchem-604	339	5	regina	regina	PROPN
eurjchem-604	339	6	gilliland	gilliland	PROPN
eurjchem-604	340	1	[	[	X
eurjchem-604	340	2	72	72	NUM
eurjchem-604	340	3	]	]	X
eurjchem-604	340	4	prepared	prepare	VERB
eurjchem-604	340	5	cis‐	cis‐	NOUN
eurjchem-604	341	1	[	[	X
eurjchem-604	341	2	mo(co)4(pph3)2	mo(co)4(pph3)2	X
eurjchem-604	341	3	]	]	PUNCT
eurjchem-604	341	4	by	by	ADP
eurjchem-604	341	5	reaction	reaction	NOUN
eurjchem-604	341	6	of	of	ADP
eurjchem-604	341	7	cis‐[mo(co)4(pip)2	cis‐[mo(co)4(pip)2	NOUN
eurjchem-604	341	8	]	]	PUNCT
eurjchem-604	341	9	with	with	ADP
eurjchem-604	341	10	triphenylphosphine	triphenylphosphine	NOUN
eurjchem-604	341	11	(	(	PUNCT
eurjchem-604	341	12	pph3	pph3	PROPN
eurjchem-604	341	13	)	)	PUNCT
eurjchem-604	341	14	(	(	PUNCT
eurjchem-604	341	15	scheme	scheme	NOUN
eurjchem-604	341	16	16	16	NUM
eurjchem-604	341	17	)	)	PUNCT
eurjchem-604	341	18	in	in	ADP
eurjchem-604	341	19	dry	dry	ADJ
eurjchem-604	341	20	ch2cl2	ch2cl2	NOUN
eurjchem-604	341	21	on	on	ADP
eurjchem-604	341	22	refluxing	refluxing	NOUN
eurjchem-604	341	23	at	at	ADP
eurjchem-604	341	24	50	50	NUM
eurjchem-604	341	25	oc	oc	NOUN
eurjchem-604	341	26	for	for	ADP
eurjchem-604	341	27	15	15	NUM
eurjchem-604	341	28	min	min	NOUN
eurjchem-604	341	29	using	use	VERB
eurjchem-604	341	30	previous	previous	ADJ
eurjchem-604	341	31	reference	reference	NOUN
eurjchem-604	341	32	of	of	ADP
eurjchem-604	341	33	allen	allen	PROPN
eurjchem-604	341	34	et	et	PROPN
eurjchem-604	341	35	al	al	PROPN
eurjchem-604	341	36	.	.	PUNCT
eurjchem-604	342	1	[	[	X
eurjchem-604	342	2	73	73	NUM
eurjchem-604	342	3	]	]	PUNCT
eurjchem-604	342	4	.	.	PUNCT
eurjchem-604	343	1	2.3.2.4	2.3.2.4	NUM
eurjchem-604	343	2	.	.	X
eurjchem-604	343	3	m(co)4	m(co)4	PROPN
eurjchem-604	343	4	(	(	PUNCT
eurjchem-604	343	5	ch3cn)2	ch3cn)2	NOUN
eurjchem-604	343	6	it	it	PRON
eurjchem-604	343	7	has	have	AUX
eurjchem-604	343	8	been	be	AUX
eurjchem-604	343	9	reported	report	VERB
eurjchem-604	343	10	that	that	SCONJ
eurjchem-604	343	11	nitrile	nitrile	ADJ
eurjchem-604	343	12	complexes	complex	NOUN
eurjchem-604	343	13	of	of	ADP
eurjchem-604	343	14	the	the	DET
eurjchem-604	343	15	group	group	NOUN
eurjchem-604	343	16	vib	vib	PROPN
eurjchem-604	343	17	metal	metal	NOUN
eurjchem-604	343	18	carbonyls	carbonyl	NOUN
eurjchem-604	343	19	are	be	AUX
eurjchem-604	343	20	prepared	prepare	VERB
eurjchem-604	343	21	by	by	ADP
eurjchem-604	343	22	photolytic	photolytic	ADJ
eurjchem-604	343	23	displacement	displacement	NOUN
eurjchem-604	343	24	of	of	ADP
eurjchem-604	343	25	carbonyl	carbonyl	NOUN
eurjchem-604	343	26	group	group	NOUN
eurjchem-604	343	27	to	to	PART
eurjchem-604	343	28	give	give	VERB
eurjchem-604	343	29	mono‐	mono‐	NOUN
eurjchem-604	343	30	and	and	CCONJ
eurjchem-604	343	31	disubstituted	disubstitute	VERB
eurjchem-604	343	32	derivatives	derivative	NOUN
eurjchem-604	344	1	[	[	X
eurjchem-604	344	2	74,75	74,75	NOUN
eurjchem-604	344	3	]	]	PUNCT
eurjchem-604	344	4	or	or	CCONJ
eurjchem-604	344	5	by	by	ADP
eurjchem-604	344	6	displacement	displacement	NOUN
eurjchem-604	344	7	of	of	ADP
eurjchem-604	344	8	diglyme	diglyme	NOUN
eurjchem-604	344	9	in	in	ADP
eurjchem-604	344	10	(	(	PUNCT
eurjchem-604	344	11	diglyme)mo(co)3	diglyme)mo(co)3	NOUN
eurjchem-604	344	12	to	to	PART
eurjchem-604	344	13	give	give	VERB
eurjchem-604	344	14	disubstituted	disubstituted	ADJ
eurjchem-604	344	15	derivatives	derivative	NOUN
eurjchem-604	344	16	[	[	X
eurjchem-604	344	17	76	76	NUM
eurjchem-604	344	18	]	]	PUNCT
eurjchem-604	344	19	.	.	PUNCT
eurjchem-604	345	1	the	the	DET
eurjchem-604	345	2	photoproduction	photoproduction	NOUN
eurjchem-604	345	3	of	of	ADP
eurjchem-604	345	4	metal	metal	NOUN
eurjchem-604	345	5	hexacarbonyl	hexacarbonyl	NOUN
eurjchem-604	345	6	derivatives	derivative	NOUN
eurjchem-604	345	7	(	(	PUNCT
eurjchem-604	345	8	m	m	PROPN
eurjchem-604	345	9	=	=	SYM
eurjchem-604	345	10	cr	cr	PROPN
eurjchem-604	345	11	,	,	PUNCT
eurjchem-604	345	12	mo	mo	PROPN
eurjchem-604	345	13	,	,	PUNCT
eurjchem-604	345	14	w	w	NOUN
eurjchem-604	345	15	)	)	PUNCT
eurjchem-604	345	16	in	in	ADP
eurjchem-604	345	17	acetonitrile	acetonitrile	NOUN
eurjchem-604	345	18	results	result	VERB
eurjchem-604	345	19	the	the	DET
eurjchem-604	345	20	formation	formation	NOUN
eurjchem-604	345	21	of	of	ADP
eurjchem-604	345	22	species	specie	NOUN
eurjchem-604	345	23	m(co)4(ch3cn)2	m(co)4(ch3cn)2	NOUN
eurjchem-604	345	24	,	,	PUNCT
eurjchem-604	345	25	m(co)5(ch3cn	m(co)5(ch3cn	PROPN
eurjchem-604	345	26	)	)	PUNCT
eurjchem-604	345	27	and	and	CCONJ
eurjchem-604	345	28	in	in	ADP
eurjchem-604	345	29	the	the	DET
eurjchem-604	345	30	cases	case	NOUN
eurjchem-604	345	31	of	of	ADP
eurjchem-604	345	32	mo	mo	PROPN
eurjchem-604	345	33	and	and	CCONJ
eurjchem-604	345	34	w	w	PROPN
eurjchem-604	345	35	m(co)3(ch3cn)3	m(co)3(ch3cn)3	PROPN
eurjchem-604	345	36	also	also	ADV
eurjchem-604	345	37	formed	form	VERB
eurjchem-604	345	38	.	.	PUNCT
eurjchem-604	346	1	the	the	DET
eurjchem-604	346	2	metal	metal	NOUN
eurjchem-604	346	3	hexacarbonyls	hexacarbonyls	PROPN
eurjchem-604	346	4	m(co)6	m(co)6	PROPN
eurjchem-604	346	5	(	(	PUNCT
eurjchem-604	346	6	m	m	PROPN
eurjchem-604	346	7	=	=	SYM
eurjchem-604	346	8	cr	cr	PROPN
eurjchem-604	346	9	,	,	PUNCT
eurjchem-604	346	10	mo	mo	PROPN
eurjchem-604	346	11	,	,	PUNCT
eurjchem-604	346	12	w	w	NOUN
eurjchem-604	346	13	)	)	PUNCT
eurjchem-604	346	14	are	be	AUX
eurjchem-604	346	15	dissolved	dissolve	VERB
eurjchem-604	346	16	in	in	ADP
eurjchem-604	346	17	acetonitrile	acetonitrile	NOUN
eurjchem-604	346	18	resulting	result	VERB
eurjchem-604	346	19	colorless	colorless	ADJ
eurjchem-604	346	20	solutions	solution	NOUN
eurjchem-604	346	21	when	when	SCONJ
eurjchem-604	346	22	exposed	expose	VERB
eurjchem-604	346	23	to	to	ADP
eurjchem-604	346	24	ultraviolet	ultraviolet	ADJ
eurjchem-604	346	25	radiations	radiation	NOUN
eurjchem-604	346	26	,	,	PUNCT
eurjchem-604	346	27	they	they	PRON
eurjchem-604	346	28	turn	turn	VERB
eurjchem-604	346	29	bright	bright	ADJ
eurjchem-604	346	30	yellow	yellow	ADJ
eurjchem-604	346	31	almost	almost	ADV
eurjchem-604	346	32	immediately	immediately	ADV
eurjchem-604	346	33	to	to	PART
eurjchem-604	346	34	form	form	VERB
eurjchem-604	346	35	the	the	DET
eurjchem-604	346	36	above	above	ADJ
eurjchem-604	346	37	complexes	complex	NOUN
eurjchem-604	346	38	[	[	X
eurjchem-604	346	39	77	77	NUM
eurjchem-604	346	40	]	]	PUNCT
eurjchem-604	346	41	.	.	PUNCT
eurjchem-604	347	1	reaction	reaction	NOUN
eurjchem-604	347	2	of	of	ADP
eurjchem-604	347	3	[	[	X
eurjchem-604	347	4	(	(	PUNCT
eurjchem-604	347	5	pph2c5h4)cp3fe4(co)4	pph2c5h4)cp3fe4(co)4	NOUN
eurjchem-604	347	6	]	]	PUNCT
eurjchem-604	347	7	with	with	ADP
eurjchem-604	347	8	(	(	PUNCT
eurjchem-604	347	9	co)4w(ch3cn)2	co)4w(ch3cn)2	NOUN
eurjchem-604	347	10	at	at	ADP
eurjchem-604	347	11	ambient	ambient	ADJ
eurjchem-604	347	12	temperature	temperature	NOUN
eurjchem-604	347	13	affords	afford	NOUN
eurjchem-604	347	14	[	[	X
eurjchem-604	347	15	(	(	PUNCT
eurjchem-604	347	16	co)4w(pph2c5h4	co)4w(pph2c5h4	NOUN
eurjchem-604	347	17	)	)	PUNCT
eurjchem-604	347	18	cp3fe4(co)4	cp3fe4(co)4	PROPN
eurjchem-604	347	19	]	]	PUNCT
eurjchem-604	347	20	as	as	ADP
eurjchem-604	347	21	the	the	DET
eurjchem-604	347	22	major	major	ADJ
eurjchem-604	347	23	product	product	NOUN
eurjchem-604	347	24	,	,	PUNCT
eurjchem-604	347	25	together	together	ADV
eurjchem-604	347	26	with	with	ADP
eurjchem-604	347	27	a	a	DET
eurjchem-604	347	28	small	small	ADJ
eurjchem-604	347	29	amount	amount	NOUN
eurjchem-604	347	30	of	of	ADP
eurjchem-604	347	31	[	[	X
eurjchem-604	347	32	(	(	PUNCT
eurjchem-604	347	33	co)5w(pph2c5h4)cp3fe4(co)4	co)5w(pph2c5h4)cp3fe4(co)4	ADP
eurjchem-604	347	34	]	]	X
eurjchem-604	348	1	[	[	X
eurjchem-604	348	2	78	78	NUM
eurjchem-604	348	3	]	]	PUNCT
eurjchem-604	348	4	.	.	PUNCT
eurjchem-604	349	1	isocyanides	isocyanide	NOUN
eurjchem-604	349	2	also	also	ADV
eurjchem-604	349	3	forms	form	VERB
eurjchem-604	349	4	extensive	extensive	ADJ
eurjchem-604	349	5	families	family	NOUN
eurjchem-604	349	6	of	of	ADP
eurjchem-604	349	7	complexes	complex	NOUN
eurjchem-604	349	8	that	that	PRON
eurjchem-604	349	9	are	be	AUX
eurjchem-604	349	10	related	relate	VERB
eurjchem-604	349	11	to	to	ADP
eurjchem-604	349	12	the	the	DET
eurjchem-604	349	13	metal	metal	NOUN
eurjchem-604	349	14	carbonyls	carbonyl	VERB
eurjchem-604	349	15	.	.	PUNCT
eurjchem-604	350	1	typical	typical	ADJ
eurjchem-604	350	2	isocynide	isocynide	ADJ
eurjchem-604	350	3	ligands	ligand	NOUN
eurjchem-604	350	4	are	be	AUX
eurjchem-604	350	5	menc	menc	ADJ
eurjchem-604	350	6	and	and	CCONJ
eurjchem-604	350	7	t‐butylisocyanide	t‐butylisocyanide	X
eurjchem-604	350	8	(	(	PUNCT
eurjchem-604	350	9	me3c‐nc	me3c‐nc	NOUN
eurjchem-604	350	10	)	)	PUNCT
eurjchem-604	350	11	.	.	PUNCT
eurjchem-604	351	1	a	a	DET
eurjchem-604	351	2	special	special	ADJ
eurjchem-604	351	3	case	case	NOUN
eurjchem-604	351	4	is	be	AUX
eurjchem-604	351	5	cf3nc	cf3nc	NOUN
eurjchem-604	351	6	,	,	PUNCT
eurjchem-604	351	7	an	an	DET
eurjchem-604	351	8	unstable	unstable	ADJ
eurjchem-604	351	9	molecule	molecule	NOUN
eurjchem-604	351	10	that	that	PRON
eurjchem-604	351	11	forms	form	VERB
eurjchem-604	351	12	stable	stable	ADJ
eurjchem-604	351	13	complexes	complex	NOUN
eurjchem-604	351	14	whose	whose	DET
eurjchem-604	351	15	behavior	behavior	NOUN
eurjchem-604	351	16	closely	closely	ADV
eurjchem-604	351	17	parallels	parallel	VERB
eurjchem-604	351	18	that	that	SCONJ
eurjchem-604	351	19	of	of	ADP
eurjchem-604	351	20	the	the	DET
eurjchem-604	351	21	metal	metal	NOUN
eurjchem-604	351	22	carbonyls	carbonyls	NOUN
eurjchem-604	351	23	[	[	X
eurjchem-604	351	24	79	79	NUM
eurjchem-604	351	25	]	]	PUNCT
eurjchem-604	351	26	.	.	PUNCT
eurjchem-604	352	1	scheme	scheme	NOUN
eurjchem-604	352	2	16	16	NUM
eurjchem-604	352	3	retracted	retract	VERB
eurjchem-604	352	4	kaushik	kaushik	PROPN
eurjchem-604	352	5	et	et	PROPN
eurjchem-604	352	6	al	al	PROPN
eurjchem-604	352	7	.	.	PUNCT
eurjchem-604	352	8	/	/	SYM
eurjchem-604	352	9	european	european	PROPN
eurjchem-604	352	10	journal	journal	PROPN
eurjchem-604	352	11	of	of	ADP
eurjchem-604	352	12	chemistry	chemistry	NOUN
eurjchem-604	352	13	3	3	NUM
eurjchem-604	352	14	(	(	PUNCT
eurjchem-604	352	15	3	3	NUM
eurjchem-604	352	16	)	)	PUNCT
eurjchem-604	352	17	(	(	PUNCT
eurjchem-604	352	18	2012	2012	NUM
eurjchem-604	352	19	)	)	PUNCT
eurjchem-604	352	20	367‐394	367‐394	NOUN
eurjchem-604	353	1	375	375	NUM
eurjchem-604	353	2	2.3.2.5	2.3.2.5	NUM
eurjchem-604	353	3	.	.	PUNCT
eurjchem-604	353	4	m(co)4(bipy	m(co)4(bipy	NOUN
eurjchem-604	353	5	)	)	PUNCT
eurjchem-604	353	6	2,2’‐bipyridine	2,2’‐bipyridine	NUM
eurjchem-604	353	7	have	have	AUX
eurjchem-604	353	8	been	be	AUX
eurjchem-604	353	9	prepared	prepare	VERB
eurjchem-604	353	10	by	by	ADP
eurjchem-604	353	11	smith	smith	PROPN
eurjchem-604	353	12	et	et	PROPN
eurjchem-604	353	13	al	al	PROPN
eurjchem-604	353	14	.	.	PUNCT
eurjchem-604	354	1	[	[	X
eurjchem-604	354	2	80	80	NUM
eurjchem-604	354	3	]	]	PUNCT
eurjchem-604	354	4	.	.	PUNCT
eurjchem-604	355	1	darensbourg	darensbourg	PROPN
eurjchem-604	355	2	et	et	PROPN
eurjchem-604	355	3	al	al	PROPN
eurjchem-604	355	4	.	.	PROPN
eurjchem-604	355	5	found	find	VERB
eurjchem-604	355	6	that	that	SCONJ
eurjchem-604	355	7	these	these	DET
eurjchem-604	355	8	complexes	complex	NOUN
eurjchem-604	355	9	were	be	AUX
eurjchem-604	355	10	synthesized	synthesize	VERB
eurjchem-604	355	11	by	by	ADP
eurjchem-604	355	12	reacting	react	VERB
eurjchem-604	355	13	[	[	X
eurjchem-604	355	14	mo(co)6	mo(co)6	X
eurjchem-604	355	15	]	]	PUNCT
eurjchem-604	355	16	with	with	ADP
eurjchem-604	355	17	excess	excess	ADJ
eurjchem-604	355	18	2,2’‐bipyridine	2,2’‐bipyridine	NUM
eurjchem-604	355	19	(	(	PUNCT
eurjchem-604	355	20	n‐n	n‐n	NOUN
eurjchem-604	355	21	)	)	PUNCT
eurjchem-604	355	22	ligand	ligand	NOUN
eurjchem-604	355	23	in	in	ADP
eurjchem-604	355	24	deoxygenated	deoxygenate	VERB
eurjchem-604	355	25	toluene	toluene	NOUN
eurjchem-604	355	26	at	at	ADP
eurjchem-604	355	27	reflux	reflux	NOUN
eurjchem-604	355	28	(	(	PUNCT
eurjchem-604	355	29	scheme	scheme	NOUN
eurjchem-604	355	30	17	17	NUM
eurjchem-604	355	31	)	)	PUNCT
eurjchem-604	355	32	.	.	PUNCT
eurjchem-604	356	1	reaction	reaction	NOUN
eurjchem-604	356	2	times	time	NOUN
eurjchem-604	356	3	for	for	ADP
eurjchem-604	356	4	the	the	DET
eurjchem-604	356	5	thermal	thermal	ADJ
eurjchem-604	356	6	synthesis	synthesis	NOUN
eurjchem-604	356	7	of	of	ADP
eurjchem-604	356	8	[	[	X
eurjchem-604	356	9	mo(co)4(bipy	mo(co)4(bipy	PROPN
eurjchem-604	356	10	)	)	PUNCT
eurjchem-604	356	11	]	]	PUNCT
eurjchem-604	356	12	complexes	complex	NOUN
eurjchem-604	356	13	vary	vary	VERB
eurjchem-604	356	14	between	between	ADP
eurjchem-604	356	15	1.5	1.5	NUM
eurjchem-604	356	16	to	to	ADP
eurjchem-604	356	17	2.0	2.0	NUM
eurjchem-604	356	18	hours	hour	NOUN
eurjchem-604	357	1	[	[	X
eurjchem-604	357	2	81	81	NUM
eurjchem-604	357	3	]	]	PUNCT
eurjchem-604	357	4	.	.	PUNCT
eurjchem-604	358	1	scheme	scheme	NOUN
eurjchem-604	358	2	17	17	NUM
eurjchem-604	358	3	later	later	ADV
eurjchem-604	358	4	david	david	PROPN
eurjchem-604	358	5	manuta	manuta	PROPN
eurjchem-604	358	6	et	et	PROPN
eurjchem-604	358	7	.	.	PUNCT
eurjchem-604	359	1	al	al	PROPN
eurjchem-604	359	2	.	.	PROPN
eurjchem-604	359	3	synthesize	synthesize	PROPN
eurjchem-604	359	4	mo(co)4(2,2'‐bipy	mo(co)4(2,2'‐bipy	PROPN
eurjchem-604	359	5	)	)	PUNCT
eurjchem-604	359	6	by	by	ADP
eurjchem-604	359	7	photolysis	photolysis	NOUN
eurjchem-604	359	8	of	of	ADP
eurjchem-604	359	9	a	a	DET
eurjchem-604	359	10	solution	solution	NOUN
eurjchem-604	359	11	containing	contain	VERB
eurjchem-604	359	12	the	the	DET
eurjchem-604	359	13	parent	parent	NOUN
eurjchem-604	359	14	hexacarbonyl	hexacarbonyl	NOUN
eurjchem-604	359	15	and	and	CCONJ
eurjchem-604	359	16	2,2'‐bipyridine(n‐n	2,2'‐bipyridine(n‐n	NUM
eurjchem-604	359	17	)	)	PUNCT
eurjchem-604	359	18	(	(	PUNCT
eurjchem-604	359	19	scheme	scheme	NOUN
eurjchem-604	359	20	18	18	NUM
eurjchem-604	359	21	)	)	PUNCT
eurjchem-604	360	1	[	[	X
eurjchem-604	360	2	82	82	NUM
eurjchem-604	360	3	]	]	PUNCT
eurjchem-604	360	4	.	.	PUNCT
eurjchem-604	361	1	scheme	scheme	PROPN
eurjchem-604	361	2	18	18	NUM
eurjchem-604	361	3	fred	fred	PROPN
eurjchem-604	361	4	basolo	basolo	PROPN
eurjchem-604	362	1	and	and	CCONJ
eurjchem-604	362	2	john	john	PROPN
eurjchem-604	362	3	mcdonald	mcdonald	PROPN
eurjchem-604	362	4	found	find	VERB
eurjchem-604	362	5	that	that	SCONJ
eurjchem-604	362	6	the	the	DET
eurjchem-604	362	7	oxidative	oxidative	ADJ
eurjchem-604	362	8	elimination	elimination	NOUN
eurjchem-604	362	9	reactions	reaction	NOUN
eurjchem-604	362	10	of	of	ADP
eurjchem-604	362	11	m(co)4l	m(co)4l	PROPN
eurjchem-604	362	12	(	(	PUNCT
eurjchem-604	362	13	m	m	PROPN
eurjchem-604	362	14	=	=	SYM
eurjchem-604	362	15	mo	mo	PROPN
eurjchem-604	362	16	,	,	PUNCT
eurjchem-604	362	17	w	w	PROPN
eurjchem-604	362	18	;	;	PUNCT
eurjchem-604	362	19	l=	l=	ADJ
eurjchem-604	362	20	2,2’‐	2,2’‐	NUM
eurjchem-604	362	21	bipyridine	bipyridine	NOUN
eurjchem-604	362	22	)	)	PUNCT
eurjchem-604	362	23	with	with	ADP
eurjchem-604	362	24	mercuric	mercuric	ADJ
eurjchem-604	362	25	halides	halide	NOUN
eurjchem-604	362	26	yields	yield	NOUN
eurjchem-604	362	27	m(co)3l(hgx	m(co)3l(hgx	NOUN
eurjchem-604	362	28	)	)	PUNCT
eurjchem-604	362	29	and	and	CCONJ
eurjchem-604	362	30	co	co	AUX
eurjchem-604	362	31	using	use	VERB
eurjchem-604	362	32	acetone	acetone	NOUN
eurjchem-604	362	33	as	as	ADP
eurjchem-604	362	34	solvent	solvent	NOUN
eurjchem-604	362	35	[	[	X
eurjchem-604	362	36	83	83	NUM
eurjchem-604	362	37	]	]	PUNCT
eurjchem-604	362	38	.	.	PUNCT
eurjchem-604	363	1	6‐ferrocenyl‐2,2′‐bipyridine	6‐ferrocenyl‐2,2′‐bipyridine	NUM
eurjchem-604	363	2	,	,	PUNCT
eurjchem-604	363	3	prepared	prepare	VERB
eurjchem-604	363	4	by	by	ADP
eurjchem-604	363	5	the	the	DET
eurjchem-604	363	6	reaction	reaction	NOUN
eurjchem-604	363	7	of	of	ADP
eurjchem-604	363	8	lithiated	lithiated	ADJ
eurjchem-604	363	9	ferrocene	ferrocene	NOUN
eurjchem-604	363	10	and	and	CCONJ
eurjchem-604	363	11	bipyridine	bipyridine	NOUN
eurjchem-604	363	12	,	,	PUNCT
eurjchem-604	363	13	reacts	react	VERB
eurjchem-604	363	14	with	with	ADP
eurjchem-604	363	15	pentacarbonyl	pentacarbonyl	NOUN
eurjchem-604	363	16	[	[	X
eurjchem-604	363	17	η2‐bis(trimethylsilyl)ethyne	η2‐bis(trimethylsilyl)ethyne	X
eurjchem-604	363	18	]	]	X
eurjchem-604	363	19	tungsten(0	tungsten(0	NOUN
eurjchem-604	363	20	)	)	PUNCT
eurjchem-604	363	21	to	to	PART
eurjchem-604	363	22	form	form	VERB
eurjchem-604	363	23	tetracarbonyl(6‐ferrocenyl‐2,2′‐	tetracarbonyl(6‐ferrocenyl‐2,2′‐	PRON
eurjchem-604	363	24	bipyridine)tungsten(0	bipyridine)tungsten(0	ADP
eurjchem-604	363	25	)	)	PUNCT
eurjchem-604	363	26	which	which	PRON
eurjchem-604	363	27	was	be	AUX
eurjchem-604	363	28	isolated	isolate	VERB
eurjchem-604	363	29	as	as	ADP
eurjchem-604	363	30	analytically	analytically	ADV
eurjchem-604	363	31	pure	pure	ADJ
eurjchem-604	363	32	substance	substance	NOUN
eurjchem-604	363	33	(	(	PUNCT
eurjchem-604	363	34	scheme	scheme	NOUN
eurjchem-604	363	35	19	19	NUM
eurjchem-604	363	36	)	)	PUNCT
eurjchem-604	364	1	[	[	X
eurjchem-604	364	2	84	84	NUM
eurjchem-604	364	3	]	]	PUNCT
eurjchem-604	364	4	.	.	PUNCT
eurjchem-604	365	1	fe	fe	PROPN
eurjchem-604	365	2	n	n	CCONJ
eurjchem-604	365	3	n	n	PROPN
eurjchem-604	365	4	w	w	NOUN
eurjchem-604	365	5	oc	oc	NOUN
eurjchem-604	365	6	oc	oc	PART
eurjchem-604	365	7	co	co	AUX
eurjchem-604	365	8	co	co	AUX
eurjchem-604	365	9	scheme	scheme	VERB
eurjchem-604	365	10	19	19	NUM
eurjchem-604	365	11	2.3.2.6	2.3.2.6	NUM
eurjchem-604	365	12	.	.	PUNCT
eurjchem-604	366	1	m(co)4(pme3)2	m(co)4(pme3)2	NOUN
eurjchem-604	366	2	all	all	DET
eurjchem-604	366	3	metal	metal	NOUN
eurjchem-604	366	4	carbonyls	carbonyls	NOUN
eurjchem-604	366	5	undergo	undergo	VERB
eurjchem-604	366	6	substitution	substitution	NOUN
eurjchem-604	366	7	by	by	ADP
eurjchem-604	366	8	organophosphorus	organophosphorus	NOUN
eurjchem-604	366	9	ligands	ligand	NOUN
eurjchem-604	366	10	.	.	PUNCT
eurjchem-604	367	1	for	for	ADP
eurjchem-604	367	2	example	example	NOUN
eurjchem-604	367	3	,	,	PUNCT
eurjchem-604	367	4	the	the	DET
eurjchem-604	367	5	series	series	NOUN
eurjchem-604	367	6	mo(co)6‐	mo(co)6‐	PROPN
eurjchem-604	367	7	x(pr3)x	x(pr3)x	PROPN
eurjchem-604	367	8	is	be	AUX
eurjchem-604	367	9	well	well	ADV
eurjchem-604	367	10	known	know	VERB
eurjchem-604	367	11	for	for	ADP
eurjchem-604	367	12	various	various	ADJ
eurjchem-604	367	13	phosphine	phosphine	NOUN
eurjchem-604	367	14	ligands	ligand	NOUN
eurjchem-604	367	15	for	for	ADP
eurjchem-604	367	16	x	x	SYM
eurjchem-604	367	17	=	=	SYM
eurjchem-604	367	18	1,2	1,2	NUM
eurjchem-604	367	19	and	and	CCONJ
eurjchem-604	367	20	3	3	NUM
eurjchem-604	367	21	.	.	PUNCT
eurjchem-604	368	1	pf3	pf3	NOUN
eurjchem-604	368	2	behaves	behave	VERB
eurjchem-604	368	3	similarly	similarly	ADV
eurjchem-604	368	4	but	but	CCONJ
eurjchem-604	368	5	is	be	AUX
eurjchem-604	368	6	remarkable	remarkable	ADJ
eurjchem-604	368	7	because	because	SCONJ
eurjchem-604	368	8	it	it	PRON
eurjchem-604	368	9	readily	readily	ADV
eurjchem-604	368	10	forms	form	VERB
eurjchem-604	368	11	homoleptic	homoleptic	ADJ
eurjchem-604	368	12	analogous	analogous	ADJ
eurjchem-604	368	13	of	of	ADP
eurjchem-604	368	14	the	the	DET
eurjchem-604	368	15	binary	binary	ADJ
eurjchem-604	368	16	metal	metal	NOUN
eurjchem-604	368	17	carbonyls	carbonyls	PROPN
eurjchem-604	368	18	i.	i.	PROPN
eurjchem-604	368	19	e.	e.	PROPN
eurjchem-604	368	20	mo(pf3)6	mo(pf3)6	PROPN
eurjchem-604	368	21	.	.	PUNCT
eurjchem-604	369	1	air	air	PROPN
eurjchem-604	369	2	stable	stable	ADJ
eurjchem-604	369	3	and	and	CCONJ
eurjchem-604	369	4	sublimable	sublimable	ADJ
eurjchem-604	369	5	bis(phosphine)metal	bis(phosphine)metal	NUM
eurjchem-604	369	6	tetracarbonyls	tetracarbonyls	NOUN
eurjchem-604	369	7	of	of	ADP
eurjchem-604	369	8	chromium	chromium	NOUN
eurjchem-604	369	9	,	,	PUNCT
eurjchem-604	369	10	molybdenum	molybdenum	NOUN
eurjchem-604	369	11	and	and	CCONJ
eurjchem-604	369	12	tungsten	tungsten	NOUN
eurjchem-604	369	13	have	have	AUX
eurjchem-604	369	14	been	be	AUX
eurjchem-604	369	15	prepared	prepare	VERB
eurjchem-604	369	16	by	by	ADP
eurjchem-604	369	17	a	a	DET
eurjchem-604	369	18	ligand	ligand	ADJ
eurjchem-604	369	19	displacement	displacement	ADJ
eurjchem-604	369	20	reaction	reaction	NOUN
eurjchem-604	369	21	with	with	ADP
eurjchem-604	369	22	the	the	DET
eurjchem-604	369	23	octahydrotriborotetracarbonyl	octahydrotriborotetracarbonyl	ADJ
eurjchem-604	369	24	metalate	metalate	ADJ
eurjchem-604	369	25	anions	anion	NOUN
eurjchem-604	369	26	(	(	PUNCT
eurjchem-604	369	27	scheme	scheme	NOUN
eurjchem-604	369	28	20	20	NUM
eurjchem-604	369	29	)	)	PUNCT
eurjchem-604	370	1	[	[	X
eurjchem-604	370	2	85	85	NUM
eurjchem-604	370	3	]	]	PUNCT
eurjchem-604	370	4	.	.	PUNCT
eurjchem-604	371	1	scheme	scheme	NOUN
eurjchem-604	371	2	20	20	NUM
eurjchem-604	371	3	klanberg	klanberg	NOUN
eurjchem-604	371	4	and	and	CCONJ
eurjchem-604	371	5	mutterties	muttertie	NOUN
eurjchem-604	371	6	later	later	ADV
eurjchem-604	371	7	prepared	prepare	VERB
eurjchem-604	371	8	colorless	colorless	ADJ
eurjchem-604	371	9	to	to	PART
eurjchem-604	371	10	faintly	faintly	ADV
eurjchem-604	371	11	yellowish	yellowish	VERB
eurjchem-604	371	12	crystalline	crystalline	NOUN
eurjchem-604	371	13	complexes	complex	NOUN
eurjchem-604	371	14	of	of	ADP
eurjchem-604	371	15	type	type	NOUN
eurjchem-604	371	16	m(co)4(ph3)2	m(co)4(ph3)2	NOUN
eurjchem-604	371	17	have	have	AUX
eurjchem-604	371	18	been	be	AUX
eurjchem-604	371	19	synthesized	synthesize	VERB
eurjchem-604	371	20	[	[	PUNCT
eurjchem-604	371	21	86	86	NUM
eurjchem-604	371	22	]	]	PUNCT
eurjchem-604	371	23	.	.	PUNCT
eurjchem-604	372	1	uses	use	VERB
eurjchem-604	372	2	:	:	PUNCT
eurjchem-604	372	3	a	a	DET
eurjchem-604	372	4	study	study	NOUN
eurjchem-604	372	5	on	on	ADP
eurjchem-604	372	6	photodissociation	photodissociation	NOUN
eurjchem-604	372	7	of	of	ADP
eurjchem-604	372	8	the	the	DET
eurjchem-604	372	9	phosphine‐	phosphine‐	NOUN
eurjchem-604	372	10	substituted	substitute	VERB
eurjchem-604	372	11	transition	transition	NOUN
eurjchem-604	372	12	metal	metal	NOUN
eurjchem-604	372	13	carbonylcomplexes	carbonylcomplexe	NOUN
eurjchem-604	372	14	cr(co)5l	cr(co)5l	PROPN
eurjchem-604	372	15	was	be	AUX
eurjchem-604	372	16	performed	perform	VERB
eurjchem-604	372	17	with	with	ADP
eurjchem-604	372	18	time‐dependent	time‐dependent	NOUN
eurjchem-604	372	19	dft	dft	PROPN
eurjchem-604	372	20	theory	theory	NOUN
eurjchem-604	372	21	to	to	PART
eurjchem-604	372	22	explore	explore	VERB
eurjchem-604	372	23	the	the	DET
eurjchem-604	372	24	propensity	propensity	NOUN
eurjchem-604	372	25	of	of	ADP
eurjchem-604	372	26	the	the	DET
eurjchem-604	372	27	excited	excited	ADJ
eurjchem-604	372	28	molecules	molecule	NOUN
eurjchem-604	372	29	to	to	PART
eurjchem-604	372	30	expel	expel	VERB
eurjchem-604	372	31	their	their	PRON
eurjchem-604	372	32	ligands	ligand	NOUN
eurjchem-604	372	33	.	.	PUNCT
eurjchem-604	373	1	the	the	DET
eurjchem-604	373	2	influence	influence	NOUN
eurjchem-604	373	3	of	of	ADP
eurjchem-604	373	4	the	the	DET
eurjchem-604	373	5	ph3	ph3	PROPN
eurjchem-604	373	6	ligand	ligand	NOUN
eurjchem-604	373	7	on	on	ADP
eurjchem-604	373	8	the	the	DET
eurjchem-604	373	9	properties	property	NOUN
eurjchem-604	373	10	of	of	ADP
eurjchem-604	373	11	these	these	DET
eurjchem-604	373	12	complexes	complex	NOUN
eurjchem-604	373	13	is	be	AUX
eurjchem-604	373	14	compared	compare	VERB
eurjchem-604	373	15	with	with	ADP
eurjchem-604	373	16	the	the	DET
eurjchem-604	373	17	photodissociation	photodissociation	NOUN
eurjchem-604	373	18	behavior	behavior	NOUN
eurjchem-604	373	19	of	of	ADP
eurjchem-604	373	20	the	the	DET
eurjchem-604	373	21	carbonyl	carbonyl	NOUN
eurjchem-604	373	22	complex	complex	ADJ
eurjchem-604	373	23	cr(co)6	cr(co)6	NOUN
eurjchem-604	373	24	.	.	PUNCT
eurjchem-604	374	1	all	all	DET
eurjchem-604	374	2	calculations	calculation	NOUN
eurjchem-604	374	3	indicate	indicate	VERB
eurjchem-604	374	4	that	that	SCONJ
eurjchem-604	374	5	the	the	DET
eurjchem-604	374	6	excited	excited	ADJ
eurjchem-604	374	7	cr(co)5l	cr(co)5l	NOUN
eurjchem-604	374	8	molecules	molecule	NOUN
eurjchem-604	374	9	(	(	PUNCT
eurjchem-604	374	10	l	l	NOUN
eurjchem-604	374	11	=	=	SYM
eurjchem-604	374	12	ph3	ph3	PROPN
eurjchem-604	374	13	,	,	PUNCT
eurjchem-604	374	14	pc2h5	pc2h5	PROPN
eurjchem-604	374	15	,	,	PUNCT
eurjchem-604	374	16	and	and	CCONJ
eurjchem-604	374	17	pch3	pch3	ADJ
eurjchem-604	374	18	)	)	PUNCT
eurjchem-604	374	19	prefer	prefer	VERB
eurjchem-604	374	20	dissociation	dissociation	NOUN
eurjchem-604	374	21	of	of	ADP
eurjchem-604	374	22	their	their	PRON
eurjchem-604	374	23	phosphorus	phosphorus	NOUN
eurjchem-604	374	24	substituent	substituent	NOUN
eurjchem-604	374	25	over	over	ADP
eurjchem-604	374	26	that	that	PRON
eurjchem-604	374	27	of	of	ADP
eurjchem-604	374	28	an	an	DET
eurjchem-604	374	29	co	co	X
eurjchem-604	374	30	ligand	ligand	NOUN
eurjchem-604	374	31	(	(	PUNCT
eurjchem-604	374	32	figure	figure	NOUN
eurjchem-604	374	33	7	7	NUM
eurjchem-604	374	34	)	)	PUNCT
eurjchem-604	374	35	.	.	PUNCT
eurjchem-604	375	1	this	this	PRON
eurjchem-604	375	2	suggests	suggest	VERB
eurjchem-604	375	3	that	that	SCONJ
eurjchem-604	375	4	the	the	DET
eurjchem-604	375	5	photochemical	photochemical	ADJ
eurjchem-604	375	6	approach	approach	NOUN
eurjchem-604	375	7	may	may	AUX
eurjchem-604	375	8	be	be	AUX
eurjchem-604	375	9	a	a	DET
eurjchem-604	375	10	viable	viable	ADJ
eurjchem-604	375	11	complement	complement	NOUN
eurjchem-604	375	12	to	to	ADP
eurjchem-604	375	13	the	the	DET
eurjchem-604	375	14	ligand	ligand	NOUN
eurjchem-604	375	15	exchange	exchange	NOUN
eurjchem-604	375	16	and	and	CCONJ
eurjchem-604	375	17	redox	redox	ADJ
eurjchem-604	375	18	methods	method	NOUN
eurjchem-604	375	19	that	that	PRON
eurjchem-604	375	20	are	be	AUX
eurjchem-604	375	21	currently	currently	ADV
eurjchem-604	375	22	employed	employ	VERB
eurjchem-604	375	23	to	to	PART
eurjchem-604	375	24	demetalate	demetalate	NOUN
eurjchem-604	375	25	transition	transition	NOUN
eurjchem-604	375	26	metal	metal	NOUN
eurjchem-604	375	27	complexed	complexe	VERB
eurjchem-604	375	28	organophosphorus	organophosphorus	NOUN
eurjchem-604	375	29	compounds	compound	NOUN
eurjchem-604	375	30	[	[	X
eurjchem-604	375	31	87	87	NUM
eurjchem-604	375	32	]	]	PUNCT
eurjchem-604	375	33	.	.	PUNCT
eurjchem-604	376	1	figure	figure	NOUN
eurjchem-604	376	2	7	7	NUM
eurjchem-604	376	3	.	.	PUNCT
eurjchem-604	376	4	photodissociation	photodissociation	NOUN
eurjchem-604	376	5	of	of	ADP
eurjchem-604	376	6	phosphine‐substituted	phosphine‐substitute	VERB
eurjchem-604	376	7	transition	transition	NOUN
eurjchem-604	376	8	metal	metal	NOUN
eurjchem-604	376	9	carbonyl	carbonyl	NOUN
eurjchem-604	376	10	complexes	complex	NOUN
eurjchem-604	376	11	[	[	PUNCT
eurjchem-604	376	12	87	87	NUM
eurjchem-604	376	13	]	]	PUNCT
eurjchem-604	376	14	.	.	PUNCT
eurjchem-604	377	1	2.3.3	2.3.3	NUM
eurjchem-604	377	2	.	.	PUNCT
eurjchem-604	377	3	m(co)3	m(co)3	NOUN
eurjchem-604	377	4	transfer	transfer	NOUN
eurjchem-604	377	5	reagents	reagent	NOUN
eurjchem-604	377	6	many	many	ADJ
eurjchem-604	377	7	ligands	ligand	NOUN
eurjchem-604	377	8	are	be	AUX
eurjchem-604	377	9	known	know	VERB
eurjchem-604	377	10	which	which	PRON
eurjchem-604	377	11	act	act	NOUN
eurjchem-604	377	12	as	as	ADP
eurjchem-604	377	13	m(co)3	m(co)3	PROPN
eurjchem-604	377	14	transfer	transfer	NOUN
eurjchem-604	377	15	reagent	reagent	NOUN
eurjchem-604	377	16	.	.	PUNCT
eurjchem-604	378	1	some	some	PRON
eurjchem-604	378	2	of	of	ADP
eurjchem-604	378	3	them	they	PRON
eurjchem-604	378	4	are	be	AUX
eurjchem-604	378	5	discussed	discuss	VERB
eurjchem-604	378	6	here	here	ADV
eurjchem-604	378	7	.	.	PUNCT
eurjchem-604	379	1	2.3.3.1	2.3.3.1	NUM
eurjchem-604	379	2	.	.	PUNCT
eurjchem-604	379	3	m(co)3(acetonitril	m(co)3(acetonitril	PROPN
eurjchem-604	379	4	)	)	PUNCT
eurjchem-604	379	5	methyl	methyl	NOUN
eurjchem-604	379	6	cyanide	cyanide	NOUN
eurjchem-604	379	7	(	(	PUNCT
eurjchem-604	379	8	acetonitril	acetonitril	NOUN
eurjchem-604	379	9	)	)	PUNCT
eurjchem-604	379	10	ligands	ligand	NOUN
eurjchem-604	379	11	are	be	AUX
eurjchem-604	379	12	capable	capable	ADJ
eurjchem-604	379	13	to	to	PART
eurjchem-604	379	14	displace	displace	VERB
eurjchem-604	379	15	two	two	NUM
eurjchem-604	379	16	or	or	CCONJ
eurjchem-604	379	17	three	three	NUM
eurjchem-604	379	18	co	co	NOUN
eurjchem-604	379	19	molecules	molecule	NOUN
eurjchem-604	379	20	from	from	ADP
eurjchem-604	379	21	m(co)6	m(co)6	NOUN
eurjchem-604	379	22	hence	hence	ADV
eurjchem-604	379	23	represent	represent	VERB
eurjchem-604	379	24	properties	property	NOUN
eurjchem-604	379	25	as	as	ADP
eurjchem-604	379	26	m(co)4	m(co)4	PROPN
eurjchem-604	379	27	as	as	ADV
eurjchem-604	379	28	well	well	ADV
eurjchem-604	379	29	as	as	ADP
eurjchem-604	379	30	m(co)3	m(co)3	PROPN
eurjchem-604	379	31	transfer	transfer	NOUN
eurjchem-604	379	32	reagent	reagent	NOUN
eurjchem-604	379	33	.	.	PUNCT
eurjchem-604	380	1	but	but	CCONJ
eurjchem-604	380	2	the	the	DET
eurjchem-604	380	3	studies	study	NOUN
eurjchem-604	380	4	shows	show	VERB
eurjchem-604	380	5	that	that	SCONJ
eurjchem-604	380	6	m(co)3	m(co)3	PROPN
eurjchem-604	380	7	tranfer	tranfer	NOUN
eurjchem-604	380	8	properties	property	NOUN
eurjchem-604	380	9	are	be	AUX
eurjchem-604	380	10	more	more	ADV
eurjchem-604	380	11	common	common	ADJ
eurjchem-604	380	12	for	for	ADP
eurjchem-604	380	13	acetonitril	acetonitril	NOUN
eurjchem-604	380	14	.	.	PUNCT
eurjchem-604	381	1	tate	tate	PROPN
eurjchem-604	381	2	et	et	PROPN
eurjchem-604	381	3	al	al	PROPN
eurjchem-604	381	4	.	.	PROPN
eurjchem-604	381	5	find	find	VERB
eurjchem-604	381	6	that	that	SCONJ
eurjchem-604	381	7	tri‐nitrile	tri‐nitrile	DET
eurjchem-604	381	8	derivatives	derivative	NOUN
eurjchem-604	381	9	are	be	AUX
eurjchem-604	381	10	prepared	prepare	VERB
eurjchem-604	381	11	very	very	ADV
eurjchem-604	381	12	conveniently	conveniently	ADV
eurjchem-604	381	13	by	by	ADP
eurjchem-604	381	14	direct	direct	ADJ
eurjchem-604	381	15	reaction	reaction	NOUN
eurjchem-604	381	16	.	.	PUNCT
eurjchem-604	382	1	for	for	ADP
eurjchem-604	382	2	instance	instance	NOUN
eurjchem-604	382	3	on	on	ADP
eurjchem-604	382	4	refluxing	refluxing	NOUN
eurjchem-604	382	5	mo(co)6	mo(co)6	PROPN
eurjchem-604	382	6	in	in	ADP
eurjchem-604	382	7	excess	excess	ADJ
eurjchem-604	382	8	acetonitrile	acetonitrile	NOUN
eurjchem-604	382	9	under	under	ADP
eurjchem-604	382	10	nitrogen	nitrogen	NOUN
eurjchem-604	382	11	,	,	PUNCT
eurjchem-604	382	12	a	a	DET
eurjchem-604	382	13	near	near	ADJ
eurjchem-604	382	14	quantitative	quantitative	ADJ
eurjchem-604	382	15	yield	yield	NOUN
eurjchem-604	382	16	of	of	ADP
eurjchem-604	382	17	(	(	PUNCT
eurjchem-604	382	18	ch3cn)3mo(co)3	ch3cn)3mo(co)3	PROPN
eurjchem-604	382	19	is	be	AUX
eurjchem-604	382	20	obtained	obtain	VERB
eurjchem-604	382	21	with	with	ADP
eurjchem-604	382	22	evolution	evolution	NOUN
eurjchem-604	382	23	of	of	ADP
eurjchem-604	382	24	3	3	NUM
eurjchem-604	382	25	moles	mole	NOUN
eurjchem-604	382	26	of	of	ADP
eurjchem-604	382	27	gas	gas	NOUN
eurjchem-604	382	28	in	in	ADP
eurjchem-604	382	29	less	less	ADJ
eurjchem-604	382	30	than	than	ADP
eurjchem-604	382	31	4	4	NUM
eurjchem-604	382	32	hr	hr	NOUN
eurjchem-604	382	33	.	.	PUNCT
eurjchem-604	383	1	it	it	PRON
eurjchem-604	383	2	is	be	AUX
eurjchem-604	383	3	identical	identical	ADJ
eurjchem-604	383	4	with	with	ADP
eurjchem-604	383	5	the	the	DET
eurjchem-604	383	6	compound	compound	NOUN
eurjchem-604	383	7	prepared	prepare	VERB
eurjchem-604	383	8	by	by	ADP
eurjchem-604	383	9	werner	werner	PROPN
eurjchem-604	383	10	and	and	CCONJ
eurjchem-604	383	11	coffield	coffield	VERB
eurjchem-604	383	12	[	[	X
eurjchem-604	383	13	76	76	NUM
eurjchem-604	383	14	]	]	PUNCT
eurjchem-604	383	15	via	via	ADP
eurjchem-604	383	16	a	a	DET
eurjchem-604	383	17	different	different	ADJ
eurjchem-604	383	18	route	route	NOUN
eurjchem-604	383	19	.	.	PUNCT
eurjchem-604	384	1	similarly	similarly	ADV
eurjchem-604	384	2	w(co)6	w(co)6	PROPN
eurjchem-604	384	3	give	give	VERB
eurjchem-604	384	4	(	(	PUNCT
eurjchem-604	384	5	ch3cn)3w(co)3	ch3cn)3w(co)3	PROPN
eurjchem-604	384	6	after	after	ADP
eurjchem-604	384	7	40‐hr	40‐hr	NUM
eurjchem-604	384	8	reflux	reflux	NOUN
eurjchem-604	384	9	which	which	PRON
eurjchem-604	384	10	shows	show	VERB
eurjchem-604	384	11	greater	great	ADJ
eurjchem-604	384	12	air	air	NOUN
eurjchem-604	384	13	stability	stability	NOUN
eurjchem-604	384	14	.	.	PUNCT
eurjchem-604	385	1	(	(	PUNCT
eurjchem-604	385	2	ch3cn)3cr(co)3	ch3cn)3cr(co)3	PROPN
eurjchem-604	385	3	also	also	ADV
eurjchem-604	385	4	been	be	AUX
eurjchem-604	385	5	prepared	prepare	VERB
eurjchem-604	385	6	but	but	CCONJ
eurjchem-604	385	7	it	it	PRON
eurjchem-604	385	8	shows	show	VERB
eurjchem-604	385	9	extremely	extremely	ADV
eurjchem-604	385	10	sensitivity	sensitivity	NOUN
eurjchem-604	385	11	and	and	CCONJ
eurjchem-604	385	12	less	less	ADJ
eurjchem-604	385	13	stability	stability	NOUN
eurjchem-604	385	14	.	.	PUNCT
eurjchem-604	386	1	these	these	DET
eurjchem-604	386	2	compounds	compound	NOUN
eurjchem-604	386	3	serves	serve	VERB
eurjchem-604	386	4	as	as	ADP
eurjchem-604	386	5	excellent	excellent	ADJ
eurjchem-604	386	6	intermediates	intermediate	NOUN
eurjchem-604	386	7	in	in	ADP
eurjchem-604	386	8	the	the	DET
eurjchem-604	386	9	formation	formation	NOUN
eurjchem-604	386	10	of	of	ADP
eurjchem-604	386	11	new	new	ADJ
eurjchem-604	386	12	compounds	compound	NOUN
eurjchem-604	386	13	not	not	PART
eurjchem-604	386	14	available	available	ADJ
eurjchem-604	386	15	by	by	ADP
eurjchem-604	386	16	other	other	ADJ
eurjchem-604	386	17	routes	route	NOUN
eurjchem-604	386	18	[	[	X
eurjchem-604	386	19	88	88	NUM
eurjchem-604	386	20	]	]	PUNCT
eurjchem-604	386	21	.	.	PUNCT
eurjchem-604	387	1	elschenbroich	elschenbroich	NOUN
eurjchem-604	387	2	and	and	CCONJ
eurjchem-604	387	3	salzer	salzer	NOUN
eurjchem-604	387	4	shows	show	VERB
eurjchem-604	387	5	that	that	SCONJ
eurjchem-604	387	6	upon	upon	SCONJ
eurjchem-604	387	7	refluxing	refluxe	VERB
eurjchem-604	387	8	in	in	ADP
eurjchem-604	387	9	a	a	DET
eurjchem-604	387	10	solution	solution	NOUN
eurjchem-604	387	11	of	of	ADP
eurjchem-604	387	12	acetonitrile	acetonitrile	NOUN
eurjchem-604	387	13	,	,	PUNCT
eurjchem-604	387	14	mo(co)6	mo(co)6	X
eurjchem-604	387	15	converts	convert	NOUN
eurjchem-604	387	16	to	to	ADP
eurjchem-604	387	17	its	its	PRON
eurjchem-604	387	18	tris(acetonitrile	tris(acetonitrile	NOUN
eurjchem-604	387	19	)	)	PUNCT
eurjchem-604	387	20	derivative[mo(co)3(mecn)3	derivative[mo(co)3(mecn)3	PUNCT
eurjchem-604	387	21	]	]	PUNCT
eurjchem-604	387	22	.	.	PUNCT
eurjchem-604	388	1	the	the	DET
eurjchem-604	388	2	resulting	result	VERB
eurjchem-604	388	3	air‐sensitive	air‐sensitive	ADJ
eurjchem-604	388	4	compound	compound	NOUN
eurjchem-604	388	5	serves	serve	VERB
eurjchem-604	388	6	as	as	ADP
eurjchem-604	388	7	a	a	DET
eurjchem-604	388	8	source	source	NOUN
eurjchem-604	388	9	of	of	ADP
eurjchem-604	388	10	"	"	PUNCT
eurjchem-604	388	11	mo(co)3	mo(co)3	NOUN
eurjchem-604	388	12	"	"	PUNCT
eurjchem-604	389	1	[	[	X
eurjchem-604	389	2	89	89	NUM
eurjchem-604	389	3	]	]	PUNCT
eurjchem-604	389	4	.	.	PUNCT
eurjchem-604	390	1	acrylonitrile	acrylonitrile	NOUN
eurjchem-604	390	2	complexes	complex	NOUN
eurjchem-604	390	3	(	(	PUNCT
eurjchem-604	390	4	ch2	ch2	PROPN
eurjchem-604	390	5	=	=	ADJ
eurjchem-604	390	6	chcn)w(co)5of	chcn)w(co)5of	NOUN
eurjchem-604	390	7	tungsten	tungsten	NOUN
eurjchem-604	390	8	carbonyl	carbonyl	NOUN
eurjchem-604	390	9	have	have	AUX
eurjchem-604	390	10	been	be	AUX
eurjchem-604	390	11	also	also	ADV
eurjchem-604	390	12	prepared	prepare	VERB
eurjchem-604	390	13	in	in	ADP
eurjchem-604	390	14	which	which	PRON
eurjchem-604	390	15	acrilonotril	acrilonotril	NOUN
eurjchem-604	390	16	is	be	AUX
eurjchem-604	390	17	bonded	bond	VERB
eurjchem-604	390	18	to	to	PART
eurjchem-604	390	19	tungsten	tungsten	VERB
eurjchem-604	390	20	by	by	ADP
eurjchem-604	390	21	mean	mean	NOUN
eurjchem-604	390	22	of	of	ADP
eurjchem-604	390	23	lone	lone	ADJ
eurjchem-604	390	24	pair	pair	NOUN
eurjchem-604	390	25	of	of	ADP
eurjchem-604	390	26	electrons	electron	NOUN
eurjchem-604	390	27	on	on	ADP
eurjchem-604	390	28	the	the	DET
eurjchem-604	390	29	nitrogen	nitrogen	NOUN
eurjchem-604	390	30	.	.	PUNCT
eurjchem-604	391	1	the	the	DET
eurjchem-604	391	2	complex	complex	NOUN
eurjchem-604	391	3	is	be	AUX
eurjchem-604	391	4	prepared	prepare	VERB
eurjchem-604	391	5	by	by	ADP
eurjchem-604	391	6	stirring	stir	VERB
eurjchem-604	391	7	(	(	PUNCT
eurjchem-604	391	8	ch3cn)w(co)5	ch3cn)w(co)5	PROPN
eurjchem-604	391	9	overnight	overnight	ADV
eurjchem-604	391	10	in	in	ADP
eurjchem-604	391	11	excess	excess	ADJ
eurjchem-604	391	12	acrylonitrile	acrylonitrile	NOUN
eurjchem-604	391	13	followed	follow	VERB
eurjchem-604	391	14	by	by	ADP
eurjchem-604	391	15	vacuum	vacuum	NOUN
eurjchem-604	391	16	evaporation	evaporation	NOUN
eurjchem-604	391	17	of	of	ADP
eurjchem-604	391	18	the	the	DET
eurjchem-604	391	19	displaced	displaced	ADJ
eurjchem-604	391	20	acetonitrile	acetonitrile	NOUN
eurjchem-604	391	21	and	and	CCONJ
eurjchem-604	391	22	excess	excess	ADJ
eurjchem-604	391	23	acrylonitrile	acrylonitrile	NOUN
eurjchem-604	391	24	[	[	X
eurjchem-604	391	25	90	90	NUM
eurjchem-604	391	26	]	]	PUNCT
eurjchem-604	391	27	.	.	PUNCT
eurjchem-604	392	1	the	the	DET
eurjchem-604	392	2	reaction	reaction	NOUN
eurjchem-604	392	3	of	of	ADP
eurjchem-604	392	4	mo(co)3(ch3cn)3	mo(co)3(ch3cn)3	PROPN
eurjchem-604	392	5	and	and	CCONJ
eurjchem-604	392	6	e2ph2	e2ph2	ADJ
eurjchem-604	392	7	(	(	PUNCT
eurjchem-604	392	8	e	e	NOUN
eurjchem-604	392	9	=	=	NOUN
eurjchem-604	392	10	se	se	X
eurjchem-604	392	11	or	or	CCONJ
eurjchem-604	392	12	te	te	PROPN
eurjchem-604	392	13	)	)	PUNCT
eurjchem-604	392	14	yields	yield	VERB
eurjchem-604	392	15	the	the	DET
eurjchem-604	392	16	edge‐sharing	edge‐share	VERB
eurjchem-604	392	17	bioctahedral	bioctahedral	ADJ
eurjchem-604	392	18	,	,	PUNCT
eurjchem-604	392	19	metal‐metal	metal‐metal	PROPN
eurjchem-604	392	20	bonded	bond	VERB
eurjchem-604	392	21	mo(i	mo(i	ADJ
eurjchem-604	392	22	)	)	PUNCT
eurjchem-604	392	23	products	product	NOUN
eurjchem-604	393	1	[	[	X
eurjchem-604	393	2	mo(co)3(ch3cn)(μ‐eph)]2	mo(co)3(ch3cn)(μ‐eph)]2	PROPN
eurjchem-604	393	3	[	[	X
eurjchem-604	393	4	91	91	NUM
eurjchem-604	393	5	]	]	PUNCT
eurjchem-604	393	6	.	.	PUNCT
eurjchem-604	394	1	duterium	duterium	PROPN
eurjchem-604	394	2	labeled	label	VERB
eurjchem-604	394	3	(	(	PUNCT
eurjchem-604	394	4	fulvene)m(co)3(m	fulvene)m(co)3(m	PROPN
eurjchem-604	394	5	=	=	SYM
eurjchem-604	394	6	cr	cr	PROPN
eurjchem-604	394	7	,	,	PUNCT
eurjchem-604	394	8	mo	mo	NOUN
eurjchem-604	394	9	)	)	PUNCT
eurjchem-604	394	10	complexes	complex	NOUN
eurjchem-604	394	11	were	be	AUX
eurjchem-604	394	12	prepared	prepare	VERB
eurjchem-604	394	13	in	in	ADP
eurjchem-604	394	14	high	high	ADJ
eurjchem-604	394	15	yields	yield	NOUN
eurjchem-604	394	16	by	by	ADP
eurjchem-604	394	17	reacting	react	VERB
eurjchem-604	394	18	the	the	DET
eurjchem-604	394	19	duterated	duterate	VERB
eurjchem-604	394	20	fulvene	fulvene	NOUN
eurjchem-604	394	21	ligand	ligand	NOUN
eurjchem-604	394	22	with	with	ADP
eurjchem-604	394	23	(	(	PUNCT
eurjchem-604	394	24	mecn)3m(co)3	mecn)3m(co)3	NOUN
eurjchem-604	395	1	[	[	X
eurjchem-604	395	2	92	92	NUM
eurjchem-604	395	3	]	]	PUNCT
eurjchem-604	395	4	.	.	PUNCT
eurjchem-604	396	1	retracted	retract	VERB
eurjchem-604	396	2	376	376	NUM
eurjchem-604	396	3	kaushik	kaushik	NOUN
eurjchem-604	396	4	et	et	PROPN
eurjchem-604	396	5	al	al	PROPN
eurjchem-604	396	6	.	.	PUNCT
eurjchem-604	396	7	/	/	SYM
eurjchem-604	396	8	european	european	PROPN
eurjchem-604	396	9	journal	journal	PROPN
eurjchem-604	396	10	of	of	ADP
eurjchem-604	396	11	chemistry	chemistry	NOUN
eurjchem-604	396	12	3	3	NUM
eurjchem-604	396	13	(	(	PUNCT
eurjchem-604	396	14	3	3	NUM
eurjchem-604	396	15	)	)	PUNCT
eurjchem-604	396	16	(	(	PUNCT
eurjchem-604	396	17	2012	2012	NUM
eurjchem-604	396	18	)	)	PUNCT
eurjchem-604	396	19	367‐394	367‐394	NOUN
eurjchem-604	396	20	on	on	ADP
eurjchem-604	396	21	refluxing	refluxing	NOUN
eurjchem-604	396	22	(	(	PUNCT
eurjchem-604	396	23	ch3cn)3w(co)3	ch3cn)3w(co)3	PROPN
eurjchem-604	396	24	in	in	ADP
eurjchem-604	396	25	3‐hexyne	3‐hexyne	NUM
eurjchem-604	396	26	,	,	PUNCT
eurjchem-604	396	27	2	2	NUM
eurjchem-604	396	28	equivalent	equivalent	NOUN
eurjchem-604	396	29	co	co	NOUN
eurjchem-604	396	30	was	be	AUX
eurjchem-604	396	31	evolved	evolve	VERB
eurjchem-604	396	32	and	and	CCONJ
eurjchem-604	396	33	results	result	VERB
eurjchem-604	396	34	yellow	yellow	ADJ
eurjchem-604	396	35	colored	colored	ADJ
eurjchem-604	396	36	(	(	PUNCT
eurjchem-604	396	37	ch3ch2c	ch3ch2c	X
eurjchem-604	396	38	=	=	SYM
eurjchem-604	396	39	cch2ch3)3w(co	cch2ch3)3w(co	NOUN
eurjchem-604	396	40	)	)	PUNCT
eurjchem-604	397	1	[	[	X
eurjchem-604	397	2	93	93	NUM
eurjchem-604	397	3	]	]	PUNCT
eurjchem-604	397	4	.	.	PUNCT
eurjchem-604	398	1	thermolysis	thermolysis	NOUN
eurjchem-604	398	2	of	of	ADP
eurjchem-604	398	3	[	[	X
eurjchem-604	398	4	(	(	PUNCT
eurjchem-604	398	5	mo(co)4(μ‐	mo(co)4(μ‐	PROPN
eurjchem-604	398	6	dpfb)2	dpfb)2	PROPN
eurjchem-604	398	7	]	]	X
eurjchem-604	398	8	(	(	PUNCT
eurjchem-604	398	9	dpfb	dpfb	NOUN
eurjchem-604	398	10	=	=	SYM
eurjchem-604	398	11	1,4‐bis	1,4‐bis	NUM
eurjchem-604	398	12	(	(	PUNCT
eurjchem-604	398	13	diphyenylphosphino)‐2,5‐	diphyenylphosphino)‐2,5‐	NOUN
eurjchem-604	398	14	difluorobenzene	difluorobenzene	NOUN
eurjchem-604	398	15	)	)	PUNCT
eurjchem-604	398	16	in	in	ADP
eurjchem-604	398	17	acetonitrile	acetonitrile	NOUN
eurjchem-604	398	18	followed	follow	VERB
eurjchem-604	398	19	by	by	ADP
eurjchem-604	398	20	addition	addition	NOUN
eurjchem-604	398	21	of	of	ADP
eurjchem-604	398	22	triphenylphosphine	triphenylphosphine	NOUN
eurjchem-604	398	23	yields	yield	NOUN
eurjchem-604	398	24	trans‐	trans‐	VERB
eurjchem-604	399	1	[	[	X
eurjchem-604	399	2	mo(co)4(pph3)2	mo(co)4(pph3)2	X
eurjchem-604	399	3	]	]	PUNCT
eurjchem-604	399	4	and	and	CCONJ
eurjchem-604	399	5	free	free	ADJ
eurjchem-604	399	6	dpfb	dpfb	NOUN
eurjchem-604	399	7	which	which	PRON
eurjchem-604	399	8	co‐crystallise	co‐crystallise	NOUN
eurjchem-604	399	9	[	[	X
eurjchem-604	399	10	94	94	NUM
eurjchem-604	399	11	]	]	PUNCT
eurjchem-604	399	12	.	.	PUNCT
eurjchem-604	400	1	2.4	2.4	NUM
eurjchem-604	400	2	.	.	PUNCT
eurjchem-604	400	3	substitution	substitution	NOUN
eurjchem-604	400	4	reactions	reaction	NOUN
eurjchem-604	400	5	of	of	ADP
eurjchem-604	400	6	cyclopentadienyl	cyclopentadienyl	NOUN
eurjchem-604	400	7	and	and	CCONJ
eurjchem-604	400	8	cyclohepatrienyl	cyclohepatrienyl	NOUN
eurjchem-604	400	9	complexes	complex	NOUN
eurjchem-604	400	10	of	of	ADP
eurjchem-604	400	11	m(co)6	m(co)6	NOUN
eurjchem-604	400	12	the	the	DET
eurjchem-604	400	13	n‐cyclopentadienyl	n‐cyclopentadienyl	PUNCT
eurjchem-604	400	14	and	and	CCONJ
eurjchem-604	400	15	n‐arenes	n‐arene	NOUN
eurjchem-604	400	16	groups	group	NOUN
eurjchem-604	400	17	are	be	AUX
eurjchem-604	400	18	among	among	ADP
eurjchem-604	400	19	the	the	DET
eurjchem-604	400	20	most	most	ADV
eurjchem-604	400	21	common	common	ADJ
eurjchem-604	400	22	class	class	NOUN
eurjchem-604	400	23	of	of	ADP
eurjchem-604	400	24	ligand	ligand	NOUN
eurjchem-604	400	25	encountered	encounter	VERB
eurjchem-604	400	26	in	in	ADP
eurjchem-604	400	27	organotransition	organotransition	NOUN
eurjchem-604	400	28	metal	metal	NOUN
eurjchem-604	400	29	chemistry	chemistry	NOUN
eurjchem-604	400	30	.	.	PUNCT
eurjchem-604	401	1	transition	transition	NOUN
eurjchem-604	401	2	metal	metal	NOUN
eurjchem-604	401	3	complexes	complex	NOUN
eurjchem-604	401	4	with	with	ADP
eurjchem-604	401	5	these	these	DET
eurjchem-604	401	6	ligands	ligand	NOUN
eurjchem-604	401	7	have	have	AUX
eurjchem-604	401	8	been	be	AUX
eurjchem-604	401	9	studied	study	VERB
eurjchem-604	401	10	extensively	extensively	ADV
eurjchem-604	401	11	and	and	CCONJ
eurjchem-604	401	12	many	many	ADJ
eurjchem-604	401	13	of	of	ADP
eurjchem-604	401	14	which	which	PRON
eurjchem-604	401	15	have	have	AUX
eurjchem-604	401	16	contributed	contribute	VERB
eurjchem-604	401	17	to	to	ADP
eurjchem-604	401	18	the	the	DET
eurjchem-604	401	19	development	development	NOUN
eurjchem-604	401	20	of	of	ADP
eurjchem-604	401	21	areas	area	NOUN
eurjchem-604	401	22	such	such	ADJ
eurjchem-604	401	23	as	as	ADP
eurjchem-604	401	24	homogenous	homogenous	ADJ
eurjchem-604	401	25	catalyst	catalyst	NOUN
eurjchem-604	401	26	,	,	PUNCT
eurjchem-604	401	27	organic	organic	ADJ
eurjchem-604	401	28	synthesis	synthesis	NOUN
eurjchem-604	401	29	,	,	PUNCT
eurjchem-604	401	30	new	new	ADJ
eurjchem-604	401	31	materials	material	NOUN
eurjchem-604	401	32	and	and	CCONJ
eurjchem-604	401	33	biological	biological	ADJ
eurjchem-604	401	34	and	and	CCONJ
eurjchem-604	401	35	medical	medical	ADJ
eurjchem-604	401	36	sciences	science	NOUN
eurjchem-604	402	1	[	[	X
eurjchem-604	402	2	95	95	NUM
eurjchem-604	402	3	]	]	PUNCT
eurjchem-604	402	4	.	.	PUNCT
eurjchem-604	403	1	a	a	DET
eurjchem-604	403	2	variety	variety	NOUN
eurjchem-604	403	3	of	of	ADP
eurjchem-604	403	4	polyolephenic	polyolephenic	ADJ
eurjchem-604	403	5	and	and	CCONJ
eurjchem-604	403	6	aromatic	aromatic	ADJ
eurjchem-604	403	7	hydrocarbons	hydrocarbon	NOUN
eurjchem-604	403	8	have	have	AUX
eurjchem-604	403	9	been	be	AUX
eurjchem-604	403	10	shown	show	VERB
eurjchem-604	403	11	to	to	PART
eurjchem-604	403	12	react	react	VERB
eurjchem-604	403	13	with	with	ADP
eurjchem-604	403	14	carbonyls	carbonyls	NOUN
eurjchem-604	403	15	of	of	ADP
eurjchem-604	403	16	group	group	NOUN
eurjchem-604	403	17	vi	vi	PROPN
eurjchem-604	403	18	metals	metal	NOUN
eurjchem-604	403	19	to	to	PART
eurjchem-604	403	20	afford	afford	VERB
eurjchem-604	403	21	π‐complexes	π‐complexes	PUNCT
eurjchem-604	403	22	.	.	PUNCT
eurjchem-604	404	1	compounds	compound	NOUN
eurjchem-604	404	2	of	of	ADP
eurjchem-604	404	3	the	the	DET
eurjchem-604	404	4	type	type	NOUN
eurjchem-604	404	5	l‐m(co)3	l‐m(co)3	NOUN
eurjchem-604	405	1	[	[	X
eurjchem-604	405	2	m	m	X
eurjchem-604	405	3	=	=	SYM
eurjchem-604	405	4	cr	cr	PROPN
eurjchem-604	405	5	,	,	PUNCT
eurjchem-604	405	6	mo	mo	PROPN
eurjchem-604	405	7	or	or	CCONJ
eurjchem-604	405	8	w	w	PROPN
eurjchem-604	405	9	]	]	PUNCT
eurjchem-604	405	10	have	have	AUX
eurjchem-604	405	11	been	be	AUX
eurjchem-604	405	12	obtained	obtain	VERB
eurjchem-604	405	13	from	from	ADP
eurjchem-604	405	14	aromatic	aromatic	ADJ
eurjchem-604	405	15	hydrocarbons	hydrocarbon	NOUN
eurjchem-604	405	16	[	[	X
eurjchem-604	405	17	96‐100	96‐100	X
eurjchem-604	405	18	]	]	PUNCT
eurjchem-604	405	19	and	and	CCONJ
eurjchem-604	405	20	from	from	ADP
eurjchem-604	405	21	cycloheptatriene	cycloheptatriene	NOUN
eurjchem-604	405	22	[	[	X
eurjchem-604	405	23	101,102	101,102	NUM
eurjchem-604	405	24	]	]	PUNCT
eurjchem-604	405	25	,	,	PUNCT
eurjchem-604	405	26	1,3,5‐cyclooctatriene	1,3,5‐cyclooctatriene	NUM
eurjchem-604	406	1	[	[	X
eurjchem-604	406	2	103,104	103,104	NUM
eurjchem-604	406	3	]	]	PUNCT
eurjchem-604	406	4	and	and	CCONJ
eurjchem-604	406	5	even	even	ADV
eurjchem-604	406	6	cyclononatetracene	cyclononatetracene	NOUN
eurjchem-604	407	1	[	[	X
eurjchem-604	407	2	100	100	NUM
eurjchem-604	407	3	]	]	PUNCT
eurjchem-604	407	4	in	in	ADP
eurjchem-604	407	5	addition	addition	NOUN
eurjchem-604	407	6	to	to	ADP
eurjchem-604	407	7	complexes	complex	NOUN
eurjchem-604	407	8	derived	derive	VERB
eurjchem-604	407	9	from	from	ADP
eurjchem-604	407	10	conjugated	conjugated	ADJ
eurjchem-604	407	11	trienes	triene	NOUN
eurjchem-604	407	12	,	,	PUNCT
eurjchem-604	407	13	metal	metal	NOUN
eurjchem-604	407	14	complexes	complex	NOUN
eurjchem-604	407	15	l‐m(co)4	l‐m(co)4	NOUN
eurjchem-604	407	16	involving	involve	VERB
eurjchem-604	407	17	non	non	ADJ
eurjchem-604	407	18	conjugating	conjugating	PROPN
eurjchem-604	407	19	dienes	diene	VERB
eurjchem-604	407	20	1,5	1,5	NUM
eurjchem-604	407	21	cyclooctadiene	cyclooctadiene	NOUN
eurjchem-604	408	1	[	[	X
eurjchem-604	408	2	105‐107	105‐107	NUM
eurjchem-604	408	3	]	]	PUNCT
eurjchem-604	408	4	and	and	CCONJ
eurjchem-604	408	5	bicycle‐	bicycle‐	X
eurjchem-604	409	1	[	[	X
eurjchem-604	409	2	2.2.1]heptadiene	2.2.1]heptadiene	NUM
eurjchem-604	409	3	[	[	X
eurjchem-604	409	4	108,109	108,109	NUM
eurjchem-604	409	5	]	]	PUNCT
eurjchem-604	409	6	have	have	AUX
eurjchem-604	409	7	been	be	AUX
eurjchem-604	409	8	reported	report	VERB
eurjchem-604	409	9	[	[	X
eurjchem-604	409	10	110	110	NUM
eurjchem-604	409	11	]	]	PUNCT
eurjchem-604	409	12	.	.	PUNCT
eurjchem-604	410	1	2.4.1	2.4.1	X
eurjchem-604	410	2	.	.	PUNCT
eurjchem-604	411	1	m(co)4cp	m(co)4cp	PROPN
eurjchem-604	411	2	preparation	preparation	NOUN
eurjchem-604	411	3	:	:	PUNCT
eurjchem-604	411	4	m(co)4cp	m(co)4cp	PROPN
eurjchem-604	411	5	was	be	AUX
eurjchem-604	411	6	prepared	prepare	VERB
eurjchem-604	411	7	by	by	ADP
eurjchem-604	411	8	thermal	thermal	ADJ
eurjchem-604	411	9	substitution	substitution	NOUN
eurjchem-604	411	10	reaction	reaction	NOUN
eurjchem-604	411	11	of	of	ADP
eurjchem-604	411	12	m(co)6	m(co)6	PROPN
eurjchem-604	411	13	with	with	ADP
eurjchem-604	411	14	cyclopentadiene	cyclopentadiene	NOUN
eurjchem-604	411	15	[	[	X
eurjchem-604	411	16	111	111	NUM
eurjchem-604	411	17	]	]	PUNCT
eurjchem-604	411	18	.	.	PUNCT
eurjchem-604	412	1	the	the	DET
eurjchem-604	412	2	ligand	ligand	ADJ
eurjchem-604	412	3	substitution	substitution	NOUN
eurjchem-604	412	4	reaction	reaction	NOUN
eurjchem-604	412	5	of	of	ADP
eurjchem-604	412	6	m(co)4cp	m(co)4cp	PROPN
eurjchem-604	412	7	proceed	proceed	VERB
eurjchem-604	412	8	via	via	ADP
eurjchem-604	412	9	co	co	NOUN
eurjchem-604	412	10	substitution	substitution	NOUN
eurjchem-604	412	11	method	method	NOUN
eurjchem-604	412	12	(	(	PUNCT
eurjchem-604	412	13	scheme	scheme	NOUN
eurjchem-604	412	14	21	21	NUM
eurjchem-604	412	15	)	)	PUNCT
eurjchem-604	413	1	[	[	X
eurjchem-604	413	2	112	112	NUM
eurjchem-604	413	3	]	]	PUNCT
eurjchem-604	413	4	.	.	PUNCT
eurjchem-604	414	1	scheme	scheme	NOUN
eurjchem-604	414	2	21	21	NUM
eurjchem-604	414	3	dicarbonyl(ƞ5‐cyclopentadienyl)iodoiron(ii	dicarbonyl(ƞ5‐cyclopentadienyl)iodoiron(ii	PROPN
eurjchem-604	414	4	)	)	PUNCT
eurjchem-604	414	5	is	be	AUX
eurjchem-604	414	6	widely	widely	ADV
eurjchem-604	414	7	used	use	VERB
eurjchem-604	414	8	and	and	CCONJ
eurjchem-604	414	9	easily	easily	ADV
eurjchem-604	414	10	prepared	prepared	ADJ
eurjchem-604	414	11	precursor	precursor	NOUN
eurjchem-604	414	12	for	for	ADP
eurjchem-604	414	13	a	a	DET
eurjchem-604	414	14	variety	variety	NOUN
eurjchem-604	414	15	of	of	ADP
eurjchem-604	414	16	organometallic	organometallic	ADJ
eurjchem-604	414	17	iron	iron	NOUN
eurjchem-604	414	18	complexes	complex	NOUN
eurjchem-604	414	19	[	[	X
eurjchem-604	414	20	113	113	NUM
eurjchem-604	414	21	]	]	PUNCT
eurjchem-604	414	22	.	.	PUNCT
eurjchem-604	415	1	mcardle	mcardle	PROPN
eurjchem-604	415	2	et	et	PROPN
eurjchem-604	415	3	al	al	PROPN
eurjchem-604	415	4	.	.	PROPN
eurjchem-604	415	5	and	and	CCONJ
eurjchem-604	415	6	akita	akita	PROPN
eurjchem-604	415	7	et	et	PROPN
eurjchem-604	415	8	al	al	PROPN
eurjchem-604	415	9	.	.	PROPN
eurjchem-604	415	10	have	have	AUX
eurjchem-604	415	11	been	be	AUX
eurjchem-604	415	12	prepared	prepare	VERB
eurjchem-604	415	13	similar	similar	ADJ
eurjchem-604	415	14	complexes	complex	NOUN
eurjchem-604	415	15	with	with	ADP
eurjchem-604	415	16	substituted	substitute	VERB
eurjchem-604	415	17	cp	cp	PROPN
eurjchem-604	415	18	rings	ring	NOUN
eurjchem-604	415	19	[	[	X
eurjchem-604	415	20	114,115	114,115	NUM
eurjchem-604	415	21	]	]	PUNCT
eurjchem-604	415	22	.	.	PUNCT
eurjchem-604	416	1	linkage	linkage	NOUN
eurjchem-604	416	2	isomerism	isomerism	NOUN
eurjchem-604	416	3	in	in	ADP
eurjchem-604	416	4	carbonyl‐π‐cyclopentadienyl	carbonyl‐π‐cyclopentadienyl	ADJ
eurjchem-604	416	5	(	(	PUNCT
eurjchem-604	416	6	thiocynato)metal	thiocynato)metal	ADJ
eurjchem-604	416	7	complexes	complex	NOUN
eurjchem-604	416	8	of	of	ADP
eurjchem-604	416	9	manganese	manganese	NOUN
eurjchem-604	416	10	,	,	PUNCT
eurjchem-604	416	11	chromium	chromium	NOUN
eurjchem-604	416	12	,	,	PUNCT
eurjchem-604	416	13	molybdenum	molybdenum	NOUN
eurjchem-604	416	14	,	,	PUNCT
eurjchem-604	416	15	tungsten	tungsten	NOUN
eurjchem-604	416	16	and	and	CCONJ
eurjchem-604	416	17	rhodium	rhodium	NOUN
eurjchem-604	416	18	has	have	AUX
eurjchem-604	416	19	also	also	ADV
eurjchem-604	416	20	been	be	AUX
eurjchem-604	416	21	studied	study	VERB
eurjchem-604	416	22	by	by	ADP
eurjchem-604	416	23	thomas	thomas	PROPN
eurjchem-604	416	24	and	and	CCONJ
eurjchem-604	416	25	andrew	andrew	PROPN
eurjchem-604	417	1	[	[	X
eurjchem-604	417	2	116	116	X
eurjchem-604	417	3	]	]	PUNCT
eurjchem-604	417	4	.	.	PUNCT
eurjchem-604	418	1	n‐heterocyclic	n‐heterocyclic	PROPN
eurjchem-604	418	2	carbenes	carbene	NOUN
eurjchem-604	418	3	(	(	PUNCT
eurjchem-604	418	4	nhc	nhc	PROPN
eurjchem-604	418	5	)	)	PUNCT
eurjchem-604	418	6	(	(	PUNCT
eurjchem-604	418	7	scheme	scheme	NOUN
eurjchem-604	418	8	22	22	NUM
eurjchem-604	418	9	)	)	PUNCT
eurjchem-604	418	10	have	have	AUX
eurjchem-604	418	11	proved	prove	VERB
eurjchem-604	418	12	to	to	PART
eurjchem-604	418	13	be	be	AUX
eurjchem-604	418	14	excellent	excellent	ADJ
eurjchem-604	418	15	ligand	ligand	NOUN
eurjchem-604	418	16	in	in	ADP
eurjchem-604	418	17	transition	transition	NOUN
eurjchem-604	418	18	metal	metal	NOUN
eurjchem-604	418	19	complexes	complex	NOUN
eurjchem-604	418	20	.	.	PUNCT
eurjchem-604	419	1	photolysis	photolysis	NOUN
eurjchem-604	419	2	of	of	ADP
eurjchem-604	419	3	[	[	X
eurjchem-604	419	4	cpmn(co)3	cpmn(co)3	NOUN
eurjchem-604	419	5	]	]	PUNCT
eurjchem-604	419	6	in	in	ADP
eurjchem-604	419	7	presence	presence	NOUN
eurjchem-604	419	8	of	of	ADP
eurjchem-604	419	9	1,3,4,5‐tetramethylimidazoline‐	1,3,4,5‐tetramethylimidazoline‐	NUM
eurjchem-604	419	10	2‐thione	2‐thione	NOUN
eurjchem-604	419	11	sc3n2me4	sc3n2me4	NOUN
eurjchem-604	419	12	produce	produce	VERB
eurjchem-604	419	13	thione‐bridged	thione‐bridge	VERB
eurjchem-604	419	14	dinuclear	dinuclear	ADJ
eurjchem-604	419	15	complex	complex	ADJ
eurjchem-604	419	16	[	[	X
eurjchem-604	419	17	(	(	PUNCT
eurjchem-604	419	18	cpmn(co)2)2(sc3n2me4	cpmn(co)2)2(sc3n2me4	NOUN
eurjchem-604	419	19	)	)	PUNCT
eurjchem-604	419	20	]	]	PUNCT
eurjchem-604	419	21	.	.	PUNCT
eurjchem-604	420	1	mn‐s‐mn	mn‐s‐mn	PROPN
eurjchem-604	420	2	framework	framework	NOUN
eurjchem-604	420	3	found	find	VERB
eurjchem-604	420	4	responsible	responsible	ADJ
eurjchem-604	420	5	for	for	ADP
eurjchem-604	420	6	dinuclear	dinuclear	ADJ
eurjchem-604	420	7	complexes	complex	NOUN
eurjchem-604	420	8	.	.	PUNCT
eurjchem-604	421	1	photoreaction	photoreaction	NOUN
eurjchem-604	421	2	of	of	ADP
eurjchem-604	421	3	m(co)6	m(co)6	PROPN
eurjchem-604	421	4	(	(	PUNCT
eurjchem-604	421	5	m	m	PROPN
eurjchem-604	421	6	=	=	SYM
eurjchem-604	421	7	mo	mo	PROPN
eurjchem-604	421	8	,	,	PUNCT
eurjchem-604	421	9	w	w	PROPN
eurjchem-604	421	10	)	)	PUNCT
eurjchem-604	421	11	with	with	ADP
eurjchem-604	421	12	sc3n2me4	sc3n2me4	PROPN
eurjchem-604	421	13	afforded	afford	VERB
eurjchem-604	421	14	mononuclear	mononuclear	ADJ
eurjchem-604	421	15	complexes	complex	NOUN
eurjchem-604	421	16	[	[	X
eurjchem-604	421	17	m(co)5(sc3n2me4	m(co)5(sc3n2me4	ADJ
eurjchem-604	421	18	)	)	PUNCT
eurjchem-604	421	19	]	]	PUNCT
eurjchem-604	421	20	.	.	PUNCT
eurjchem-604	422	1	it	it	PRON
eurjchem-604	422	2	was	be	AUX
eurjchem-604	422	3	predict	predict	VERB
eurjchem-604	422	4	that	that	SCONJ
eurjchem-604	422	5	formation	formation	NOUN
eurjchem-604	422	6	of	of	ADP
eurjchem-604	422	7	dinuclear	dinuclear	ADJ
eurjchem-604	422	8	complex	complex	NOUN
eurjchem-604	422	9	was	be	AUX
eurjchem-604	422	10	somewhat	somewhat	ADV
eurjchem-604	422	11	predicted	predict	VERB
eurjchem-604	422	12	due	due	ADP
eurjchem-604	422	13	to	to	ADP
eurjchem-604	422	14	presence	presence	NOUN
eurjchem-604	422	15	of	of	ADP
eurjchem-604	422	16	cp	cp	NUM
eurjchem-604	422	17	ligand	ligand	NOUN
eurjchem-604	423	1	[	[	X
eurjchem-604	423	2	117	117	NUM
eurjchem-604	423	3	]	]	PUNCT
eurjchem-604	423	4	.	.	PUNCT
eurjchem-604	424	1	scheme	scheme	VERB
eurjchem-604	424	2	22	22	NUM
eurjchem-604	424	3	2.4.2	2.4.2	NUM
eurjchem-604	424	4	.	.	PUNCT
eurjchem-604	425	1	m(co)3(ƞ6‐c7h8	m(co)3(ƞ6‐c7h8	PROPN
eurjchem-604	425	2	)	)	PUNCT
eurjchem-604	426	1	although	although	SCONJ
eurjchem-604	426	2	cycloheptatriene	cycloheptatriene	NOUN
eurjchem-604	426	3	(	(	PUNCT
eurjchem-604	426	4	c7h8	c7h8	NOUN
eurjchem-604	426	5	)	)	PUNCT
eurjchem-604	426	6	and	and	CCONJ
eurjchem-604	426	7	cycloheptatrienyl	cycloheptatrienyl	NOUN
eurjchem-604	426	8	(	(	PUNCT
eurjchem-604	426	9	c7h7	c7h7	NOUN
eurjchem-604	426	10	)	)	PUNCT
eurjchem-604	426	11	transition	transition	NOUN
eurjchem-604	426	12	metal	metal	NOUN
eurjchem-604	426	13	carbonyl	carbonyl	NOUN
eurjchem-604	426	14	complexes	complex	NOUN
eurjchem-604	426	15	have	have	AUX
eurjchem-604	426	16	been	be	AUX
eurjchem-604	426	17	known	know	VERB
eurjchem-604	426	18	over	over	ADP
eurjchem-604	426	19	six	six	NUM
eurjchem-604	426	20	decades	decade	NOUN
eurjchem-604	426	21	.	.	PUNCT
eurjchem-604	427	1	the	the	DET
eurjchem-604	427	2	first	first	ADJ
eurjchem-604	427	3	cycloheptatriene	cycloheptatriene	NOUN
eurjchem-604	427	4	complex	complex	PROPN
eurjchem-604	427	5	mo(co)3(c7h8	mo(co)3(c7h8	PROPN
eurjchem-604	427	6	)	)	PUNCT
eurjchem-604	427	7	was	be	AUX
eurjchem-604	427	8	prepared	prepare	VERB
eurjchem-604	427	9	by	by	ADP
eurjchem-604	427	10	wilkinson	wilkinson	PROPN
eurjchem-604	427	11	et	et	PROPN
eurjchem-604	427	12	al	al	PROPN
eurjchem-604	427	13	.	.	PROPN
eurjchem-604	428	1	in	in	ADP
eurjchem-604	428	2	1958	1958	NUM
eurjchem-604	428	3	and	and	CCONJ
eurjchem-604	428	4	cycloheptatrienyl	cycloheptatrienyl	NOUN
eurjchem-604	428	5	complexes	complex	NOUN
eurjchem-604	428	6	shortly	shortly	ADV
eurjchem-604	428	7	after	after	ADP
eurjchem-604	428	8	[	[	X
eurjchem-604	428	9	94	94	NUM
eurjchem-604	428	10	]	]	PUNCT
eurjchem-604	428	11	.	.	PUNCT
eurjchem-604	429	1	2.4.2.1	2.4.2.1	NUM
eurjchem-604	429	2	.	.	PUNCT
eurjchem-604	429	3	synthesis	synthesis	NOUN
eurjchem-604	429	4	of	of	ADP
eurjchem-604	429	5	η6‐cycloheptatriene	η6‐cycloheptatriene	ADJ
eurjchem-604	429	6	molybdenum	molybdenum	NOUN
eurjchem-604	429	7	tricarbonyl	tricarbonyl	NOUN
eurjchem-604	429	8	[	[	X
eurjchem-604	429	9	(	(	PUNCT
eurjchem-604	429	10	η6‐c7h8)mo(co)3	η6‐c7h8)mo(co)3	PROPN
eurjchem-604	429	11	]	]	PUNCT
eurjchem-604	429	12	moderately	moderately	ADV
eurjchem-604	429	13	air‐sensitive	air‐sensitive	NUM
eurjchem-604	429	14	organometallic	organometallic	ADJ
eurjchem-604	429	15	arene	arene	NOUN
eurjchem-604	429	16	complex	complex	NOUN
eurjchem-604	429	17	have	have	AUX
eurjchem-604	429	18	been	be	AUX
eurjchem-604	429	19	prepared	prepare	VERB
eurjchem-604	429	20	from	from	ADP
eurjchem-604	429	21	mo(co)6the	mo(co)6the	PRON
eurjchem-604	429	22	molecular	molecular	ADJ
eurjchem-604	429	23	structure	structure	NOUN
eurjchem-604	429	24	of	of	ADP
eurjchem-604	429	25	(	(	PUNCT
eurjchem-604	429	26	η6‐c7h8)mo(co)3	η6‐c7h8)mo(co)3	PROPN
eurjchem-604	429	27	has	have	AUX
eurjchem-604	429	28	been	be	AUX
eurjchem-604	429	29	determined	determine	VERB
eurjchem-604	429	30	by	by	ADP
eurjchem-604	429	31	x‐ray	x‐ray	PROPN
eurjchem-604	429	32	diffraction	diffraction	NOUN
eurjchem-604	430	1	[	[	X
eurjchem-604	430	2	118	118	NUM
eurjchem-604	430	3	]	]	PUNCT
eurjchem-604	430	4	and	and	CCONJ
eurjchem-604	430	5	the	the	DET
eurjchem-604	430	6	compound	compound	NOUN
eurjchem-604	430	7	has	have	VERB
eurjchem-604	430	8	the	the	DET
eurjchem-604	430	9	structure	structure	NOUN
eurjchem-604	430	10	indicated	indicate	VERB
eurjchem-604	430	11	in	in	ADP
eurjchem-604	430	12	scheme	scheme	NOUN
eurjchem-604	430	13	23	23	NUM
eurjchem-604	430	14	.	.	PUNCT
eurjchem-604	431	1	those	those	PRON
eurjchem-604	431	2	of	of	ADP
eurjchem-604	431	3	the	the	DET
eurjchem-604	431	4	closely	closely	ADV
eurjchem-604	431	5	related	relate	VERB
eurjchem-604	431	6	compounds	compound	NOUN
eurjchem-604	431	7	(	(	PUNCT
eurjchem-604	431	8	c6h6)cr(co)3	c6h6)cr(co)3	PROPN
eurjchem-604	431	9	[	[	X
eurjchem-604	431	10	(	(	PUNCT
eurjchem-604	431	11	benzene	benzene	NOUN
eurjchem-604	431	12	)	)	PUNCT
eurjchem-604	431	13	chromium	chromium	NOUN
eurjchem-604	431	14	tricarbonyl	tricarbonyl	NOUN
eurjchem-604	431	15	]	]	X
eurjchem-604	432	1	[	[	X
eurjchem-604	432	2	119	119	NUM
eurjchem-604	432	3	]	]	PUNCT
eurjchem-604	432	4	and	and	CCONJ
eurjchem-604	432	5	(	(	PUNCT
eurjchem-604	432	6	me6c6)cr(co)3	me6c6)cr(co)3	PROPN
eurjchem-604	432	7	[	[	X
eurjchem-604	432	8	(	(	PUNCT
eurjchem-604	432	9	hexamethylbenzene	hexamethylbenzene	NOUN
eurjchem-604	432	10	)	)	PUNCT
eurjchem-604	432	11	chromium	chromium	NOUN
eurjchem-604	432	12	tricarbonyl	tricarbonyl	NOUN
eurjchem-604	432	13	]	]	X
eurjchem-604	433	1	[	[	X
eurjchem-604	433	2	120‐122	120‐122	NUM
eurjchem-604	433	3	]	]	PUNCT
eurjchem-604	433	4	have	have	AUX
eurjchem-604	433	5	also	also	ADV
eurjchem-604	433	6	been	be	AUX
eurjchem-604	433	7	established	establish	VERB
eurjchem-604	433	8	in	in	ADP
eurjchem-604	433	9	detail	detail	NOUN
eurjchem-604	433	10	and	and	CCONJ
eurjchem-604	433	11	reveal	reveal	VERB
eurjchem-604	433	12	a	a	DET
eurjchem-604	433	13	"	"	PUNCT
eurjchem-604	433	14	piano	piano	NOUN
eurjchem-604	433	15	stool	stool	NOUN
eurjchem-604	433	16	"	"	PUNCT
eurjchem-604	433	17	structure	structure	NOUN
eurjchem-604	433	18	with	with	ADP
eurjchem-604	433	19	the	the	DET
eurjchem-604	433	20	arene	arene	ADJ
eurjchem-604	433	21	moiety	moiety	NOUN
eurjchem-604	433	22	π‐bonded	π‐bonde	VERB
eurjchem-604	433	23	to	to	ADP
eurjchem-604	433	24	the	the	DET
eurjchem-604	433	25	metal	metal	NOUN
eurjchem-604	433	26	(	(	PUNCT
eurjchem-604	433	27	scheme	scheme	NOUN
eurjchem-604	433	28	23	23	NUM
eurjchem-604	433	29	)	)	PUNCT
eurjchem-604	433	30	.	.	PUNCT
eurjchem-604	434	1	scheme	scheme	NOUN
eurjchem-604	434	2	23	23	NUM
eurjchem-604	434	3	cycloheptatriene	cycloheptatriene	NOUN
eurjchem-604	434	4	in	in	ADP
eurjchem-604	434	5	cyclopentadiene	cyclopentadiene	NOUN
eurjchem-604	434	6	/	/	SYM
eurjchem-604	434	7	nonane	nonane	NOUN
eurjchem-604	434	8	were	be	AUX
eurjchem-604	434	9	taken	take	VERB
eurjchem-604	434	10	in	in	ADP
eurjchem-604	434	11	schlenk	schlenk	PROPN
eurjchem-604	434	12	flask	flask	NOUN
eurjchem-604	434	13	or	or	CCONJ
eurjchem-604	434	14	round‐bottom	round‐bottom	NOUN
eurjchem-604	434	15	flask	flask	NOUN
eurjchem-604	434	16	and	and	CCONJ
eurjchem-604	434	17	add	add	VERB
eurjchem-604	434	18	mo(co)6	mo(co)6	NOUN
eurjchem-604	434	19	(	(	PUNCT
eurjchem-604	434	20	2	2	NUM
eurjchem-604	434	21	.	.	NOUN
eurjchem-604	434	22	0	0	NUM
eurjchem-604	435	1	g.	g.	NOUN
eurjchem-604	435	2	7	7	NUM
eurjchem-604	435	3	.	.	PROPN
eurjchem-604	435	4	6	6	NUM
eurjchem-604	435	5	mmol	mmol	NOUN
eurjchem-604	435	6	)	)	PUNCT
eurjchem-604	435	7	to	to	ADP
eurjchem-604	435	8	this	this	DET
eurjchem-604	435	9	flask	flask	NOUN
eurjchem-604	435	10	and	and	CCONJ
eurjchem-604	435	11	heat	heat	VERB
eurjchem-604	435	12	the	the	DET
eurjchem-604	435	13	contents	content	NOUN
eurjchem-604	435	14	of	of	ADP
eurjchem-604	435	15	the	the	DET
eurjchem-604	435	16	flask	flask	NOUN
eurjchem-604	435	17	carefully	carefully	ADV
eurjchem-604	435	18	to	to	PART
eurjchem-604	435	19	reflux	reflux	VERB
eurjchem-604	435	20	for	for	ADP
eurjchem-604	435	21	2	2	NUM
eurjchem-604	435	22	hours	hour	NOUN
eurjchem-604	435	23	.	.	PUNCT
eurjchem-604	436	1	at	at	ADP
eurjchem-604	436	2	the	the	DET
eurjchem-604	436	3	end	end	NOUN
eurjchem-604	436	4	of	of	ADP
eurjchem-604	436	5	the	the	DET
eurjchem-604	436	6	reflux	reflux	NOUN
eurjchem-604	436	7	period	period	NOUN
eurjchem-604	436	8	,	,	PUNCT
eurjchem-604	436	9	cool	cool	VERB
eurjchem-604	436	10	the	the	DET
eurjchem-604	436	11	reaction	reaction	NOUN
eurjchem-604	436	12	mixture	mixture	NOUN
eurjchem-604	436	13	to	to	PART
eurjchem-604	436	14	room	room	VERB
eurjchem-604	436	15	temperature	temperature	NOUN
eurjchem-604	436	16	under	under	ADP
eurjchem-604	436	17	a	a	DET
eurjchem-604	436	18	nitrogen	nitrogen	NOUN
eurjchem-604	436	19	gas	gas	NOUN
eurjchem-604	436	20	flow	flow	NOUN
eurjchem-604	436	21	.	.	PUNCT
eurjchem-604	437	1	red	red	ADJ
eurjchem-604	437	2	/	/	SYM
eurjchem-604	437	3	orange	orange	ADJ
eurjchem-604	437	4	/	/	SYM
eurjchem-604	437	5	black	black	ADJ
eurjchem-604	437	6	(	(	PUNCT
eurjchem-604	437	7	η6‐c7h8)mo(co)3	η6‐c7h8)mo(co)3	ADJ
eurjchem-604	437	8	solution	solution	NOUN
eurjchem-604	437	9	formed	form	VERB
eurjchem-604	437	10	which	which	PRON
eurjchem-604	437	11	was	be	AUX
eurjchem-604	437	12	crystallized	crystallize	VERB
eurjchem-604	437	13	on	on	ADP
eurjchem-604	437	14	the	the	DET
eurjchem-604	437	15	alumina	alumina	NOUN
eurjchem-604	437	16	cake	cake	NOUN
eurjchem-604	437	17	.	.	PUNCT
eurjchem-604	438	1	upon	upon	SCONJ
eurjchem-604	438	2	washing	wash	VERB
eurjchem-604	438	3	several	several	ADJ
eurjchem-604	438	4	times	time	NOUN
eurjchem-604	438	5	with	with	ADP
eurjchem-604	438	6	ch2cl2	ch2cl2	NOUN
eurjchem-604	438	7	solvent	solvent	NOUN
eurjchem-604	438	8	(	(	PUNCT
eurjchem-604	438	9	η6‐c7h8)mo(co)3	η6‐c7h8)mo(co)3	NOUN
eurjchem-604	438	10	crystallize	crystallize	VERB
eurjchem-604	438	11	as	as	ADP
eurjchem-604	438	12	red	red	ADJ
eurjchem-604	438	13	solid	solid	PROPN
eurjchem-604	438	14	.	.	PUNCT
eurjchem-604	439	1	the	the	DET
eurjchem-604	439	2	red	red	PROPN
eurjchem-604	439	3	solid	solid	NOUN
eurjchem-604	439	4	will	will	AUX
eurjchem-604	439	5	turn	turn	VERB
eurjchem-604	439	6	black	black	ADJ
eurjchem-604	439	7	and	and	CCONJ
eurjchem-604	439	8	decompose	decompose	VERB
eurjchem-604	439	9	if	if	SCONJ
eurjchem-604	439	10	it	it	PRON
eurjchem-604	439	11	is	be	AUX
eurjchem-604	439	12	exposed	expose	VERB
eurjchem-604	439	13	to	to	ADP
eurjchem-604	439	14	air	air	NOUN
eurjchem-604	439	15	for	for	ADP
eurjchem-604	439	16	only	only	ADV
eurjchem-604	439	17	one	one	NUM
eurjchem-604	439	18	day	day	NOUN
eurjchem-604	440	1	[	[	X
eurjchem-604	440	2	123,124	123,124	NUM
eurjchem-604	440	3	]	]	PUNCT
eurjchem-604	440	4	.	.	PUNCT
eurjchem-604	441	1	the	the	DET
eurjchem-604	441	2	reaction	reaction	NOUN
eurjchem-604	441	3	of	of	ADP
eurjchem-604	441	4	tris(dimethylamino)phosphine(tdp	tris(dimethylamino)phosphine(tdp	NOUN
eurjchem-604	441	5	)	)	PUNCT
eurjchem-604	441	6	and	and	CCONJ
eurjchem-604	441	7	tris(dimethylamino)arsine(tdas	tris(dimethylamino)arsine(tdas	PROPN
eurjchem-604	441	8	)	)	PUNCT
eurjchem-604	441	9	with	with	ADP
eurjchem-604	441	10	the	the	DET
eurjchem-604	441	11	c7h8m(co)3	c7h8m(co)3	NOUN
eurjchem-604	441	12	(	(	PUNCT
eurjchem-604	441	13	m	m	PROPN
eurjchem-604	441	14	=	=	SYM
eurjchem-604	441	15	cr	cr	PROPN
eurjchem-604	441	16	,	,	PUNCT
eurjchem-604	441	17	mo	mo	PROPN
eurjchem-604	441	18	,	,	PUNCT
eurjchem-604	441	19	w	w	NOUN
eurjchem-604	441	20	)	)	PUNCT
eurjchem-604	441	21	in	in	ADP
eurjchem-604	441	22	hydrocarbon	hydrocarbon	NOUN
eurjchem-604	441	23	solvents	solvent	NOUN
eurjchem-604	441	24	has	have	AUX
eurjchem-604	441	25	been	be	AUX
eurjchem-604	441	26	investigated	investigate	VERB
eurjchem-604	441	27	.	.	PUNCT
eurjchem-604	442	1	the	the	DET
eurjchem-604	442	2	first	first	ADJ
eurjchem-604	442	3	step	step	NOUN
eurjchem-604	442	4	of	of	ADP
eurjchem-604	442	5	this	this	DET
eurjchem-604	442	6	reaction	reaction	NOUN
eurjchem-604	442	7	appear	appear	VERB
eurjchem-604	442	8	to	to	PART
eurjchem-604	442	9	be	be	AUX
eurjchem-604	442	10	the	the	DET
eurjchem-604	442	11	complete	complete	ADJ
eurjchem-604	442	12	displacement	displacement	NOUN
eurjchem-604	442	13	of	of	ADP
eurjchem-604	442	14	the	the	DET
eurjchem-604	442	15	coordinated	coordinated	ADJ
eurjchem-604	442	16	olifin	olifin	NOUN
eurjchem-604	442	17	with	with	ADP
eurjchem-604	442	18	the	the	DET
eurjchem-604	442	19	legands	legand	NOUN
eurjchem-604	442	20	products	product	NOUN
eurjchem-604	442	21	with	with	ADP
eurjchem-604	442	22	two	two	NUM
eurjchem-604	442	23	legands	legand	NOUN
eurjchem-604	442	24	in	in	ADP
eurjchem-604	442	25	cis	cis	NOUN
eurjchem-604	442	26	position	position	NOUN
eurjchem-604	442	27	are	be	AUX
eurjchem-604	442	28	found	find	VERB
eurjchem-604	442	29	to	to	PART
eurjchem-604	442	30	be	be	AUX
eurjchem-604	442	31	unstable	unstable	ADJ
eurjchem-604	442	32	&	&	CCONJ
eurjchem-604	442	33	undergo	undergo	VERB
eurjchem-604	442	34	further	further	ADJ
eurjchem-604	442	35	change	change	NOUN
eurjchem-604	442	36	by	by	ADP
eurjchem-604	442	37	following	follow	VERB
eurjchem-604	442	38	two	two	NUM
eurjchem-604	442	39	processes	process	NOUN
eurjchem-604	442	40	.	.	PUNCT
eurjchem-604	443	1	1	1	X
eurjchem-604	443	2	.	.	X
eurjchem-604	443	3	rearrangement	rearrangement	NOUN
eurjchem-604	443	4	of	of	ADP
eurjchem-604	443	5	cis	cis	NOUN
eurjchem-604	443	6	derivative	derivative	NOUN
eurjchem-604	443	7	to	to	ADP
eurjchem-604	443	8	trans	trans	VERB
eurjchem-604	443	9	derivative	derivative	ADJ
eurjchem-604	443	10	2	2	NUM
eurjchem-604	443	11	.	.	PUNCT
eurjchem-604	444	1	removal	removal	NOUN
eurjchem-604	444	2	of	of	ADP
eurjchem-604	444	3	a	a	DET
eurjchem-604	444	4	ligand	ligand	NOUN
eurjchem-604	444	5	by	by	ADP
eurjchem-604	444	6	decomposition	decomposition	NOUN
eurjchem-604	444	7	generated	generate	VERB
eurjchem-604	444	8	carbon	carbon	NOUN
eurjchem-604	444	9	monoxide	monoxide	NOUN
eurjchem-604	444	10	[	[	X
eurjchem-604	444	11	125	125	NUM
eurjchem-604	444	12	]	]	PUNCT
eurjchem-604	444	13	.	.	PUNCT
eurjchem-604	445	1	the	the	DET
eurjchem-604	445	2	trisubstituted	trisubstitute	VERB
eurjchem-604	445	3	metalcarbonyl	metalcarbonyl	NOUN
eurjchem-604	445	4	complexes	complex	NOUN
eurjchem-604	445	5	containing	contain	VERB
eurjchem-604	445	6	ligands	ligand	NOUN
eurjchem-604	445	7	which	which	PRON
eurjchem-604	445	8	coordinate	coordinate	VERB
eurjchem-604	445	9	through	through	ADP
eurjchem-604	445	10	bicovalent	bicovalent	NOUN
eurjchem-604	445	11	sulfur	sulfur	NOUN
eurjchem-604	445	12	are	be	AUX
eurjchem-604	445	13	reported	report	VERB
eurjchem-604	445	14	.	.	PUNCT
eurjchem-604	446	1	direct	direct	ADJ
eurjchem-604	446	2	reaction	reaction	NOUN
eurjchem-604	446	3	of	of	ADP
eurjchem-604	446	4	the	the	DET
eurjchem-604	446	5	ligands	ligand	NOUN
eurjchem-604	446	6	with	with	ADP
eurjchem-604	446	7	cycloheptatrienemolybdenumtricarbonyl	cycloheptatrienemolybdenumtricarbonyl	NOUN
eurjchem-604	446	8	[	[	X
eurjchem-604	446	9	m(co)3(ƞ6‐c7h8	m(co)3(ƞ6‐c7h8	NOUN
eurjchem-604	446	10	)	)	PUNCT
eurjchem-604	446	11	]	]	PUNCT
eurjchem-604	446	12	,	,	PUNCT
eurjchem-604	446	13	complexes	complex	NOUN
eurjchem-604	446	14	of	of	ADP
eurjchem-604	446	15	type	type	NOUN
eurjchem-604	446	16	mo(co)3l3	mo(co)3l3	NOUN
eurjchem-604	446	17	were	be	AUX
eurjchem-604	446	18	prepared	prepare	VERB
eurjchem-604	446	19	where	where	SCONJ
eurjchem-604	446	20	l	l	NOUN
eurjchem-604	446	21	representing	represent	VERB
eurjchem-604	446	22	dimethyl	dimethyl	NOUN
eurjchem-604	446	23	sulfide	sulfide	NOUN
eurjchem-604	447	1	[	[	X
eurjchem-604	447	2	(	(	PUNCT
eurjchem-604	447	3	ch3)2s	ch3)2s	PROPN
eurjchem-604	447	4	]	]	PUNCT
eurjchem-604	447	5	,	,	PUNCT
eurjchem-604	447	6	diethyl	diethyl	NOUN
eurjchem-604	447	7	sulfide	sulfide	NOUN
eurjchem-604	448	1	[	[	X
eurjchem-604	448	2	(	(	PUNCT
eurjchem-604	448	3	c2h5)2s	c2h5)2s	X
eurjchem-604	448	4	]	]	X
eurjchem-604	448	5	,	,	PUNCT
eurjchem-604	448	6	thiourea	thiourea	NOUN
eurjchem-604	449	1	[	[	X
eurjchem-604	449	2	(	(	PUNCT
eurjchem-604	449	3	ch2)2cs	ch2)2cs	NOUN
eurjchem-604	449	4	]	]	X
eurjchem-604	449	5	,	,	PUNCT
eurjchem-604	449	6	thioacetamide	thioacetamide	ADJ
eurjchem-604	449	7	[	[	X
eurjchem-604	449	8	ch2csnh2	ch2csnh2	X
eurjchem-604	449	9	]	]	X
eurjchem-604	450	1	[	[	X
eurjchem-604	450	2	126	126	NUM
eurjchem-604	450	3	]	]	PUNCT
eurjchem-604	450	4	.	.	PUNCT
eurjchem-604	451	1	2.4.3	2.4.3	X
eurjchem-604	451	2	.	.	PUNCT
eurjchem-604	451	3	m(co)3(ƞ6‐c8h8	m(co)3(ƞ6‐c8h8	NOUN
eurjchem-604	451	4	)	)	PUNCT
eurjchem-604	451	5	preparation	preparation	NOUN
eurjchem-604	451	6	:	:	PUNCT
eurjchem-604	451	7	winstein	winstein	PROPN
eurjchem-604	451	8	et	et	PROPN
eurjchem-604	451	9	al	al	PROPN
eurjchem-604	451	10	.	.	PROPN
eurjchem-604	452	1	prepared	prepare	VERB
eurjchem-604	452	2	cyclooctatetraene	cyclooctatetraene	NOUN
eurjchem-604	452	3	complexes	complex	NOUN
eurjchem-604	452	4	(	(	PUNCT
eurjchem-604	452	5	ƞ6‐c8h8)mo(co)3	ƞ6‐c8h8)mo(co)3	PROPN
eurjchem-604	452	6	,	,	PUNCT
eurjchem-604	452	7	in	in	ADP
eurjchem-604	452	8	which	which	PRON
eurjchem-604	452	9	this	this	DET
eurjchem-604	452	10	olefin	olefin	NOUN
eurjchem-604	452	11	is	be	AUX
eurjchem-604	452	12	bound	bind	VERB
eurjchem-604	452	13	to	to	ADP
eurjchem-604	452	14	a	a	DET
eurjchem-604	452	15	metal	metal	NOUN
eurjchem-604	452	16	by	by	ADP
eurjchem-604	452	17	six	six	NUM
eurjchem-604	452	18	π‐electrons	π‐electron	NOUN
eurjchem-604	452	19	on	on	ADP
eurjchem-604	452	20	six	six	NUM
eurjchem-604	452	21	carbon	carbon	NOUN
eurjchem-604	452	22	atoms	atom	NOUN
eurjchem-604	452	23	[	[	X
eurjchem-604	452	24	127	127	NUM
eurjchem-604	452	25	]	]	PUNCT
eurjchem-604	452	26	.	.	PUNCT
eurjchem-604	453	1	cyclooctatetraene	cyclooctatetraene	PROPN
eurjchem-604	453	2	is	be	AUX
eurjchem-604	453	3	displaced	displace	VERB
eurjchem-604	453	4	from	from	ADP
eurjchem-604	453	5	c8h8ru(co)3	c8h8ru(co)3	NUM
eurjchem-604	453	6	by	by	ADP
eurjchem-604	453	7	i2	i2	PROPN
eurjchem-604	453	8	or	or	CCONJ
eurjchem-604	453	9	p(och2)3cet	p(och2)3cet	NOUN
eurjchem-604	453	10	giving	give	VERB
eurjchem-604	453	11	[	[	PUNCT
eurjchem-604	453	12	ru(co)3i2]2	ru(co)3i2]2	NOUN
eurjchem-604	453	13	and	and	CCONJ
eurjchem-604	453	14	trans‐	trans‐	X
eurjchem-604	454	1	[	[	X
eurjchem-604	454	2	p(och2)3cet]2ru(co)3	p(och2)3cet]2ru(co)3	NOUN
eurjchem-604	454	3	,	,	PUNCT
eurjchem-604	454	4	respectively	respectively	ADV
eurjchem-604	454	5	.	.	PUNCT
eurjchem-604	455	1	mercury(ii	mercury(ii	NOUN
eurjchem-604	455	2	)	)	PUNCT
eurjchem-604	455	3	chloride	chloride	NOUN
eurjchem-604	455	4	,	,	PUNCT
eurjchem-604	455	5	bromide	bromide	NOUN
eurjchem-604	455	6	,	,	PUNCT
eurjchem-604	455	7	or	or	CCONJ
eurjchem-604	455	8	thiocyanate	thiocyanate	NOUN
eurjchem-604	455	9	also	also	ADV
eurjchem-604	455	10	react	react	VERB
eurjchem-604	455	11	with	with	ADP
eurjchem-604	455	12	c8h8ru(co)3	c8h8ru(co)3	NUM
eurjchem-604	455	13	to	to	PART
eurjchem-604	455	14	afford	afford	VERB
eurjchem-604	455	15	the	the	DET
eurjchem-604	455	16	binuclear	binuclear	NOUN
eurjchem-604	455	17	complexes[ru(co)3(hgx)x]2	complexes[ru(co)3(hgx)x]2	PROPN
eurjchem-604	455	18	(	(	PUNCT
eurjchem-604	455	19	xcl	xcl	PROPN
eurjchem-604	455	20	,	,	PUNCT
eurjchem-604	455	21	br	br	PROPN
eurjchem-604	455	22	,	,	PUNCT
eurjchem-604	455	23	or	or	CCONJ
eurjchem-604	455	24	scn	scn	NOUN
eurjchem-604	455	25	)	)	PUNCT
eurjchem-604	455	26	,	,	PUNCT
eurjchem-604	455	27	which	which	PRON
eurjchem-604	455	28	undergo	undergo	VERB
eurjchem-604	455	29	bridge‐splitting	bridge‐splitting	NOUN
eurjchem-604	455	30	reactions	reaction	NOUN
eurjchem-604	455	31	with	with	ADP
eurjchem-604	455	32	pyridine	pyridine	NOUN
eurjchem-604	455	33	without	without	ADP
eurjchem-604	455	34	retracted	retracted	ADJ
eurjchem-604	455	35	kaushik	kaushik	PROPN
eurjchem-604	455	36	et	et	PROPN
eurjchem-604	455	37	al	al	PROPN
eurjchem-604	455	38	.	.	PUNCT
eurjchem-604	455	39	/	/	SYM
eurjchem-604	455	40	european	european	PROPN
eurjchem-604	455	41	journal	journal	PROPN
eurjchem-604	455	42	of	of	ADP
eurjchem-604	455	43	chemistry	chemistry	NOUN
eurjchem-604	455	44	3	3	NUM
eurjchem-604	455	45	(	(	PUNCT
eurjchem-604	455	46	3	3	NUM
eurjchem-604	455	47	)	)	PUNCT
eurjchem-604	455	48	(	(	PUNCT
eurjchem-604	455	49	2012	2012	NUM
eurjchem-604	455	50	)	)	PUNCT
eurjchem-604	455	51	367‐394	367‐394	NOUN
eurjchem-604	455	52	377	377	NUM
eurjchem-604	455	53	breaking	break	VERB
eurjchem-604	455	54	the	the	DET
eurjchem-604	455	55	ru‐hg	ru‐hg	NUM
eurjchem-604	455	56	bond	bond	NOUN
eurjchem-604	455	57	,	,	PUNCT
eurjchem-604	455	58	to	to	PART
eurjchem-604	455	59	give	give	VERB
eurjchem-604	455	60	the	the	DET
eurjchem-604	455	61	complexes	complex	NOUN
eurjchem-604	455	62	ru(co)3py(hgx)x	ru(co)3py(hgx)x	PROPN
eurjchem-604	455	63	[	[	X
eurjchem-604	455	64	128	128	NUM
eurjchem-604	455	65	]	]	PUNCT
eurjchem-604	455	66	.	.	PUNCT
eurjchem-604	456	1	3	3	X
eurjchem-604	456	2	.	.	PUNCT
eurjchem-604	456	3	kinetics	kinetic	NOUN
eurjchem-604	456	4	and	and	CCONJ
eurjchem-604	456	5	mechanism	mechanism	NOUN
eurjchem-604	456	6	of	of	ADP
eurjchem-604	456	7	substitution	substitution	NOUN
eurjchem-604	456	8	reactions	reaction	NOUN
eurjchem-604	456	9	in	in	ADP
eurjchem-604	456	10	metal	metal	NOUN
eurjchem-604	456	11	carbonyls	carbonyls	NOUN
eurjchem-604	456	12	ligand	ligand	NOUN
eurjchem-604	456	13	substitution	substitution	NOUN
eurjchem-604	456	14	reactions	reaction	NOUN
eurjchem-604	456	15	are	be	AUX
eurjchem-604	456	16	essential	essential	ADJ
eurjchem-604	456	17	for	for	ADP
eurjchem-604	456	18	the	the	DET
eurjchem-604	456	19	use	use	NOUN
eurjchem-604	456	20	of	of	ADP
eurjchem-604	456	21	transition	transition	NOUN
eurjchem-604	456	22	metal	metal	NOUN
eurjchem-604	456	23	organometallic	organometallic	NOUN
eurjchem-604	456	24	compounds	compound	NOUN
eurjchem-604	456	25	as	as	ADP
eurjchem-604	456	26	catalysts	catalyst	NOUN
eurjchem-604	456	27	.	.	PUNCT
eurjchem-604	457	1	therefore	therefore	ADV
eurjchem-604	457	2	,	,	PUNCT
eurjchem-604	457	3	it	it	PRON
eurjchem-604	457	4	is	be	AUX
eurjchem-604	457	5	important	important	ADJ
eurjchem-604	457	6	that	that	SCONJ
eurjchem-604	457	7	we	we	PRON
eurjchem-604	457	8	know	know	VERB
eurjchem-604	457	9	what	what	PRON
eurjchem-604	457	10	factors	factor	NOUN
eurjchem-604	457	11	affect	affect	VERB
eurjchem-604	457	12	the	the	DET
eurjchem-604	457	13	rates	rate	NOUN
eurjchem-604	457	14	of	of	ADP
eurjchem-604	457	15	reactions	reaction	NOUN
eurjchem-604	457	16	and	and	CCONJ
eurjchem-604	457	17	why	why	SCONJ
eurjchem-604	457	18	.	.	PUNCT
eurjchem-604	458	1	much	much	ADJ
eurjchem-604	458	2	information	information	NOUN
eurjchem-604	458	3	,	,	PUNCT
eurjchem-604	458	4	both	both	PRON
eurjchem-604	458	5	qualitative	qualitative	ADJ
eurjchem-604	458	6	and	and	CCONJ
eurjchem-604	458	7	quantitative	quantitative	ADJ
eurjchem-604	458	8	,	,	PUNCT
eurjchem-604	458	9	is	be	AUX
eurjchem-604	458	10	available	available	ADJ
eurjchem-604	458	11	[	[	X
eurjchem-604	458	12	129	129	NUM
eurjchem-604	458	13	]	]	PUNCT
eurjchem-604	458	14	on	on	ADP
eurjchem-604	458	15	the	the	DET
eurjchem-604	458	16	reactivity	reactivity	NOUN
eurjchem-604	458	17	of	of	ADP
eurjchem-604	458	18	organometallic	organometallic	ADJ
eurjchem-604	458	19	compounds	compound	NOUN
eurjchem-604	458	20	.	.	PUNCT
eurjchem-604	459	1	more	more	ADV
eurjchem-604	459	2	detailed	detailed	ADJ
eurjchem-604	459	3	kinetic	kinetic	ADJ
eurjchem-604	459	4	study	study	NOUN
eurjchem-604	459	5	that	that	PRON
eurjchem-604	459	6	give	give	VERB
eurjchem-604	459	7	information	information	NOUN
eurjchem-604	459	8	on	on	ADP
eurjchem-604	459	9	the	the	DET
eurjchem-604	459	10	mechanism	mechanism	NOUN
eurjchem-604	459	11	of	of	ADP
eurjchem-604	459	12	ligand	ligand	ADJ
eurjchem-604	459	13	substitution	substitution	NOUN
eurjchem-604	459	14	and	and	CCONJ
eurjchem-604	459	15	the	the	DET
eurjchem-604	459	16	factors	factor	NOUN
eurjchem-604	459	17	contributes	contribute	VERB
eurjchem-604	459	18	to	to	ADP
eurjchem-604	459	19	rates	rate	NOUN
eurjchem-604	459	20	of	of	ADP
eurjchem-604	459	21	reaction	reaction	NOUN
eurjchem-604	459	22	aredescribed	aredescribe	VERB
eurjchem-604	459	23	here	here	ADV
eurjchem-604	459	24	.	.	PUNCT
eurjchem-604	460	1	fred	fred	PROPN
eurjchem-604	460	2	basolo	basolo	PROPN
eurjchem-604	460	3	found	find	VERB
eurjchem-604	460	4	that	that	SCONJ
eurjchem-604	460	5	co	co	NOUN
eurjchem-604	460	6	substitution	substitution	NOUN
eurjchem-604	460	7	reactions	reaction	NOUN
eurjchem-604	460	8	of	of	ADP
eurjchem-604	460	9	metal	metal	NOUN
eurjchem-604	460	10	carbonyls	carbonyls	NOUN
eurjchem-604	460	11	proceed	proceed	VERB
eurjchem-604	460	12	via	via	ADP
eurjchem-604	460	13	three	three	NUM
eurjchem-604	460	14	different	different	ADJ
eurjchem-604	460	15	systems	system	NOUN
eurjchem-604	460	16	:	:	PUNCT
eurjchem-604	460	17	(	(	PUNCT
eurjchem-604	460	18	a	a	X
eurjchem-604	460	19	)	)	PUNCT
eurjchem-604	460	20	compounds	compound	NOUN
eurjchem-604	460	21	where	where	SCONJ
eurjchem-604	460	22	ring	ring	NOUN
eurjchem-604	460	23	slippage	slippage	NOUN
eurjchem-604	460	24	seems	seem	VERB
eurjchem-604	460	25	to	to	PART
eurjchem-604	460	26	be	be	AUX
eurjchem-604	460	27	involved	involve	VERB
eurjchem-604	460	28	in	in	ADP
eurjchem-604	460	29	reaction	reaction	NOUN
eurjchem-604	460	30	;	;	PUNCT
eurjchem-604	460	31	(	(	PUNCT
eurjchem-604	460	32	b	b	X
eurjchem-604	460	33	)	)	PUNCT
eurjchem-604	460	34	heterocyclic	heterocyclic	ADJ
eurjchem-604	460	35	metal	metal	NOUN
eurjchem-604	460	36	carbonyls	carbonyls	NOUN
eurjchem-604	460	37	,	,	PUNCT
eurjchem-604	460	38	and	and	CCONJ
eurjchem-604	460	39	(	(	PUNCT
eurjchem-604	460	40	c	c	X
eurjchem-604	460	41	)	)	PUNCT
eurjchem-604	460	42	17‐electron	17‐electron	NUM
eurjchem-604	460	43	metal	metal	NOUN
eurjchem-604	460	44	complexes	complex	NOUN
eurjchem-604	460	45	[	[	X
eurjchem-604	460	46	130	130	NUM
eurjchem-604	460	47	]	]	PUNCT
eurjchem-604	460	48	.	.	PUNCT
eurjchem-604	461	1	3.1	3.1	NUM
eurjchem-604	461	2	.	.	PUNCT
eurjchem-604	461	3	ring	ring	NOUN
eurjchem-604	461	4	slipping	slip	VERB
eurjchem-604	461	5	mechanism	mechanism	NOUN
eurjchem-604	461	6	about	about	ADV
eurjchem-604	461	7	six	six	NUM
eurjchem-604	461	8	decades	decade	NOUN
eurjchem-604	461	9	ago	ago	ADV
eurjchem-604	461	10	study	study	NOUN
eurjchem-604	461	11	of	of	ADP
eurjchem-604	461	12	co	co	NOUN
eurjchem-604	461	13	exchange	exchange	NOUN
eurjchem-604	461	14	using	use	VERB
eurjchem-604	461	15	14co	14co	NOUN
eurjchem-604	461	16	,	,	PUNCT
eurjchem-604	461	17	and	and	CCONJ
eurjchem-604	461	18	of	of	ADP
eurjchem-604	461	19	co	co	NOUN
eurjchem-604	461	20	substitution	substitution	NOUN
eurjchem-604	461	21	with	with	ADP
eurjchem-604	461	22	p‐ligands	p‐ligand	NOUN
eurjchem-604	461	23	on	on	ADP
eurjchem-604	461	24	binary	binary	ADJ
eurjchem-604	461	25	metal	metal	NOUN
eurjchem-604	461	26	carbonyls	carbonyl	VERB
eurjchem-604	461	27	.	.	PUNCT
eurjchem-604	462	1	since	since	SCONJ
eurjchem-604	462	2	very	very	ADV
eurjchem-604	462	3	little	little	ADJ
eurjchem-604	462	4	work	work	NOUN
eurjchem-604	462	5	[	[	X
eurjchem-604	462	6	131	131	NUM
eurjchem-604	462	7	]	]	PUNCT
eurjchem-604	462	8	of	of	ADP
eurjchem-604	462	9	this	this	DET
eurjchem-604	462	10	type	type	NOUN
eurjchem-604	462	11	had	have	AUX
eurjchem-604	462	12	been	be	AUX
eurjchem-604	462	13	done	do	VERB
eurjchem-604	462	14	at	at	ADP
eurjchem-604	462	15	that	that	DET
eurjchem-604	462	16	time	time	NOUN
eurjchem-604	462	17	,	,	PUNCT
eurjchem-604	462	18	the	the	DET
eurjchem-604	462	19	observations	observation	NOUN
eurjchem-604	462	20	were	be	AUX
eurjchem-604	462	21	often	often	ADV
eurjchem-604	462	22	a	a	DET
eurjchem-604	462	23	source	source	NOUN
eurjchem-604	462	24	of	of	ADP
eurjchem-604	462	25	some	some	DET
eurjchem-604	462	26	surprise	surprise	NOUN
eurjchem-604	462	27	.	.	PUNCT
eurjchem-604	463	1	for	for	ADP
eurjchem-604	463	2	example	example	NOUN
eurjchem-604	463	3	,	,	PUNCT
eurjchem-604	463	4	ni(co)4	ni(co)4	PROPN
eurjchem-604	463	5	was	be	AUX
eurjchem-604	463	6	found	find	VERB
eurjchem-604	463	7	[	[	X
eurjchem-604	463	8	132	132	NUM
eurjchem-604	463	9	]	]	PUNCT
eurjchem-604	463	10	to	to	PART
eurjchem-604	463	11	exchange	exchange	VERB
eurjchem-604	463	12	co	co	VERB
eurjchem-604	463	13	by	by	ADP
eurjchem-604	463	14	a	a	DET
eurjchem-604	463	15	dissociative	dissociative	ADJ
eurjchem-604	463	16	process	process	NOUN
eurjchem-604	463	17	,	,	PUNCT
eurjchem-604	463	18	although	although	SCONJ
eurjchem-604	463	19	one	one	PRON
eurjchem-604	463	20	might	might	AUX
eurjchem-604	463	21	have	have	AUX
eurjchem-604	463	22	expected	expect	VERB
eurjchem-604	463	23	the	the	DET
eurjchem-604	463	24	4‐	4‐	NUM
eurjchem-604	463	25	coordinate	coordinate	NOUN
eurjchem-604	463	26	complex	complex	NOUN
eurjchem-604	463	27	to	to	PART
eurjchem-604	463	28	readily	readily	ADV
eurjchem-604	463	29	expend	expend	VERB
eurjchem-604	463	30	its	its	PRON
eurjchem-604	463	31	coordination	coordination	NOUN
eurjchem-604	463	32	number	number	NOUN
eurjchem-604	463	33	to	to	PART
eurjchem-604	463	34	permit	permit	VERB
eurjchem-604	463	35	a	a	DET
eurjchem-604	463	36	low	low	ADJ
eurjchem-604	463	37	energy	energy	NOUN
eurjchem-604	463	38	associative	associative	ADJ
eurjchem-604	463	39	pathway	pathway	NOUN
eurjchem-604	463	40	for	for	ADP
eurjchem-604	463	41	reaction	reaction	NOUN
eurjchem-604	463	42	.	.	PUNCT
eurjchem-604	464	1	we	we	PRON
eurjchem-604	464	2	discuss	discuss	VERB
eurjchem-604	464	3	and	and	CCONJ
eurjchem-604	464	4	understand	understand	VERB
eurjchem-604	464	5	this	this	DET
eurjchem-604	464	6	behavior	behavior	NOUN
eurjchem-604	464	7	in	in	ADP
eurjchem-604	464	8	terms	term	NOUN
eurjchem-604	464	9	of	of	ADP
eurjchem-604	464	10	tolman	tolman	PROPN
eurjchem-604	464	11	’s	’s	PART
eurjchem-604	464	12	[	[	X
eurjchem-604	464	13	133	133	NUM
eurjchem-604	464	14	]	]	PUNCT
eurjchem-604	464	15	16‐	16‐	NUM
eurjchem-604	464	16	and	and	CCONJ
eurjchem-604	464	17	18‐electron	18‐electron	NUM
eurjchem-604	464	18	rule	rule	NOUN
eurjchem-604	464	19	.	.	PUNCT
eurjchem-604	465	1	an	an	DET
eurjchem-604	465	2	associative	associative	ADJ
eurjchem-604	465	3	substitution	substitution	NOUN
eurjchem-604	465	4	for	for	ADP
eurjchem-604	465	5	ni(co)4	ni(co)4	NOUN
eurjchem-604	465	6	would	would	AUX
eurjchem-604	465	7	require	require	VERB
eurjchem-604	465	8	the	the	DET
eurjchem-604	465	9	formation	formation	NOUN
eurjchem-604	465	10	of	of	ADP
eurjchem-604	465	11	an	an	DET
eurjchem-604	465	12	unstable	unstable	ADJ
eurjchem-604	465	13	20‐electron	20‐electron	NUM
eurjchem-604	465	14	transition	transition	NOUN
eurjchem-604	465	15	state	state	NOUN
eurjchem-604	465	16	or	or	CCONJ
eurjchem-604	465	17	active	active	ADJ
eurjchem-604	465	18	intermediate	intermediate	ADJ
eurjchem-604	465	19	.	.	PUNCT
eurjchem-604	466	1	we	we	PRON
eurjchem-604	466	2	find	find	VERB
eurjchem-604	466	3	[	[	X
eurjchem-604	466	4	134	134	NUM
eurjchem-604	466	5	]	]	PUNCT
eurjchem-604	466	6	that	that	SCONJ
eurjchem-604	466	7	cono(co)3	cono(co)3	PROPN
eurjchem-604	466	8	(	(	PUNCT
eurjchem-604	466	9	scheme	scheme	NOUN
eurjchem-604	466	10	24	24	NUM
eurjchem-604	466	11	)	)	PUNCT
eurjchem-604	466	12	and	and	CCONJ
eurjchem-604	466	13	fe(no)2(co)2	fe(no)2(co)2	PROPN
eurjchem-604	466	14	,	,	PUNCT
eurjchem-604	466	15	isoelectronic	isoelectronic	ADJ
eurjchem-604	466	16	and	and	CCONJ
eurjchem-604	466	17	isostructural	isostructural	ADJ
eurjchem-604	466	18	with	with	ADP
eurjchem-604	466	19	ni(co)4	ni(co)4	NUM
eurjchem-604	466	20	,	,	PUNCT
eurjchem-604	466	21	both	both	PRON
eurjchem-604	466	22	undergo	undergo	VERB
eurjchem-604	466	23	co	co	NOUN
eurjchem-604	466	24	substitution	substitution	NOUN
eurjchem-604	466	25	by	by	ADP
eurjchem-604	466	26	an	an	DET
eurjchem-604	466	27	associative	associative	ADJ
eurjchem-604	466	28	process	process	NOUN
eurjchem-604	466	29	.	.	PUNCT
eurjchem-604	467	1	the	the	DET
eurjchem-604	467	2	interpretation	interpretation	NOUN
eurjchem-604	467	3	given	give	VERB
eurjchem-604	467	4	the	the	DET
eurjchem-604	467	5	observation	observation	NOUN
eurjchem-604	467	6	,	,	PUNCT
eurjchem-604	467	7	before	before	ADP
eurjchem-604	467	8	the	the	DET
eurjchem-604	467	9	16‐	16‐	NUM
eurjchem-604	467	10	,	,	PUNCT
eurjchem-604	467	11	18‐	18‐	NUM
eurjchem-604	467	12	electron	electron	NOUN
eurjchem-604	467	13	rule	rule	NOUN
eurjchem-604	467	14	and	and	CCONJ
eurjchem-604	467	15	before	before	ADP
eurjchem-604	467	16	the	the	DET
eurjchem-604	467	17	bent	bent	ADJ
eurjchem-604	467	18	metal	metal	NOUN
eurjchem-604	467	19	nitrosyl	nitrosyl	NOUN
eurjchem-604	467	20	,	,	PUNCT
eurjchem-604	467	21	was	be	AUX
eurjchem-604	467	22	that	that	SCONJ
eurjchem-604	467	23	a	a	DET
eurjchem-604	467	24	pair	pair	NOUN
eurjchem-604	467	25	of	of	ADP
eurjchem-604	467	26	electrons	electron	NOUN
eurjchem-604	467	27	is	be	AUX
eurjchem-604	467	28	localized	localize	VERB
eurjchem-604	467	29	on	on	ADP
eurjchem-604	467	30	the	the	DET
eurjchem-604	467	31	nitrosyl	nitrosyl	ADJ
eurjchem-604	467	32	group	group	NOUN
eurjchem-604	467	33	freeing	free	VERB
eurjchem-604	467	34	a	a	DET
eurjchem-604	467	35	low	low	ADJ
eurjchem-604	467	36	energy	energy	NOUN
eurjchem-604	467	37	metal	metal	NOUN
eurjchem-604	467	38	orbital	orbital	NOUN
eurjchem-604	467	39	for	for	ADP
eurjchem-604	467	40	nucleophilic	nucleophilic	ADJ
eurjchem-604	467	41	attack	attack	NOUN
eurjchem-604	467	42	.	.	PUNCT
eurjchem-604	468	1	scheme	scheme	NOUN
eurjchem-604	468	2	24	24	NUM
eurjchem-604	468	3	such	such	DET
eurjchem-604	468	4	a	a	DET
eurjchem-604	468	5	process	process	NOUN
eurjchem-604	468	6	that	that	PRON
eurjchem-604	468	7	maintains	maintain	VERB
eurjchem-604	468	8	an	an	DET
eurjchem-604	468	9	18‐electron	18‐electron	NUM
eurjchem-604	468	10	count	count	NOUN
eurjchem-604	468	11	throughout	throughout	ADP
eurjchem-604	468	12	is	be	AUX
eurjchem-604	468	13	much	much	ADV
eurjchem-604	468	14	less	less	ADV
eurjchem-604	468	15	available	available	ADJ
eurjchem-604	468	16	for	for	ADP
eurjchem-604	468	17	a	a	DET
eurjchem-604	468	18	compound	compound	NOUN
eurjchem-604	468	19	with	with	ADP
eurjchem-604	468	20	only	only	ADV
eurjchem-604	468	21	co	co	NOUN
eurjchem-604	468	22	ligands	ligand	NOUN
eurjchem-604	468	23	because	because	SCONJ
eurjchem-604	468	24	n	n	NUM
eurjchem-604	468	25	is	be	AUX
eurjchem-604	468	26	more	more	ADV
eurjchem-604	468	27	electronegative	electronegative	ADJ
eurjchem-604	468	28	than	than	ADP
eurjchem-604	468	29	c	c	PROPN
eurjchem-604	468	30	and	and	CCONJ
eurjchem-604	468	31	because	because	SCONJ
eurjchem-604	468	32	the	the	DET
eurjchem-604	468	33	nitrosyl	nitrosyl	ADJ
eurjchem-604	468	34	ligand	ligand	NOUN
eurjchem-604	468	35	is	be	AUX
eurjchem-604	468	36	formally	formally	ADV
eurjchem-604	468	37	present	present	ADJ
eurjchem-604	468	38	as	as	ADP
eurjchem-604	468	39	no+	no+	NOUN
eurjchem-604	468	40	.	.	PUNCT
eurjchem-604	469	1	more	more	ADV
eurjchem-604	469	2	readily	readily	ADV
eurjchem-604	469	3	explained	explain	VERB
eurjchem-604	469	4	after	after	ADP
eurjchem-604	469	5	the	the	DET
eurjchem-604	469	6	nitrosyl	nitrosyl	ADJ
eurjchem-604	469	7	ligand	ligand	NOUN
eurjchem-604	469	8	experience	experience	NOUN
eurjchem-604	469	9	,	,	PUNCT
eurjchem-604	469	10	the	the	DET
eurjchem-604	469	11	observations	observation	NOUN
eurjchem-604	469	12	[	[	X
eurjchem-604	469	13	135	135	NUM
eurjchem-604	469	14	]	]	PUNCT
eurjchem-604	469	15	that	that	SCONJ
eurjchem-604	469	16	the	the	DET
eurjchem-604	469	17	compounds	compound	NOUN
eurjchem-604	469	18	(	(	PUNCT
eurjchem-604	469	19	ƞ5‐c5h5)m(co)2	ƞ5‐c5h5)m(co)2	NUM
eurjchem-604	469	20	(	(	PUNCT
eurjchem-604	469	21	where	where	SCONJ
eurjchem-604	469	22	m	m	VERB
eurjchem-604	469	23	=	=	SYM
eurjchem-604	469	24	co	co	X
eurjchem-604	469	25	,	,	PUNCT
eurjchem-604	469	26	rh	rh	PROPN
eurjchem-604	469	27	,	,	PUNCT
eurjchem-604	469	28	or	or	CCONJ
eurjchem-604	469	29	ir	ir	NOUN
eurjchem-604	469	30	)	)	PUNCT
eurjchem-604	469	31	undergo	undergo	VERB
eurjchem-604	469	32	co	co	NOUN
eurjchem-604	469	33	substitution	substitution	NOUN
eurjchem-604	469	34	by	by	ADP
eurjchem-604	469	35	an	an	DET
eurjchem-604	469	36	associative	associative	ADJ
eurjchem-604	469	37	pathway	pathway	NOUN
eurjchem-604	469	38	(	(	PUNCT
eurjchem-604	469	39	scheme	scheme	NOUN
eurjchem-604	469	40	25	25	NUM
eurjchem-604	469	41	)	)	PUNCT
eurjchem-604	469	42	.	.	PUNCT
eurjchem-604	470	1	surprisingly	surprisingly	ADV
eurjchem-604	470	2	,	,	PUNCT
eurjchem-604	470	3	because	because	SCONJ
eurjchem-604	470	4	these	these	DET
eurjchem-604	470	5	compounds	compound	NOUN
eurjchem-604	470	6	are	be	AUX
eurjchem-604	470	7	pseudo‐isoelectronic	pseudo‐isoelectronic	ADJ
eurjchem-604	470	8	with	with	ADP
eurjchem-604	470	9	fe(co)5	fe(co)5	ADJ
eurjchem-604	470	10	which	which	PRON
eurjchem-604	470	11	only	only	ADV
eurjchem-604	470	12	very	very	ADV
eurjchem-604	470	13	slowly	slowly	ADV
eurjchem-604	470	14	reacts	react	VERB
eurjchem-604	470	15	thermally	thermally	ADV
eurjchem-604	470	16	by	by	ADP
eurjchem-604	470	17	a	a	DET
eurjchem-604	470	18	dissociative	dissociative	ADJ
eurjchem-604	470	19	process	process	NOUN
eurjchem-604	470	20	[	[	X
eurjchem-604	470	21	131	131	NUM
eurjchem-604	470	22	]	]	PUNCT
eurjchem-604	470	23	.	.	PUNCT
eurjchem-604	471	1	more	more	ADV
eurjchem-604	471	2	readily	readily	ADV
eurjchem-604	471	3	interpreted	interpret	VERB
eurjchem-604	471	4	,	,	PUNCT
eurjchem-604	471	5	because	because	SCONJ
eurjchem-604	471	6	after	after	ADP
eurjchem-604	471	7	the	the	DET
eurjchem-604	471	8	nitrosyl	nitrosyl	ADJ
eurjchem-604	471	9	experience	experience	NOUN
eurjchem-604	471	10	we	we	PRON
eurjchem-604	471	11	were	be	AUX
eurjchem-604	471	12	prepared	prepared	ADJ
eurjchem-604	471	13	to	to	PART
eurjchem-604	471	14	localize	localize	VERB
eurjchem-604	471	15	a	a	DET
eurjchem-604	471	16	pair	pair	NOUN
eurjchem-604	471	17	of	of	ADP
eurjchem-604	471	18	electrons	electron	NOUN
eurjchem-604	471	19	on	on	ADP
eurjchem-604	471	20	the	the	DET
eurjchem-604	471	21	cyclopentadienyl	cyclopentadienyl	NOUN
eurjchem-604	471	22	ring	ring	NOUN
eurjchem-604	471	23	in	in	ADP
eurjchem-604	471	24	order	order	NOUN
eurjchem-604	471	25	to	to	PART
eurjchem-604	471	26	permit	permit	VERB
eurjchem-604	471	27	nucleophilic	nucleophilic	ADJ
eurjchem-604	471	28	attack	attack	NOUN
eurjchem-604	471	29	of	of	ADP
eurjchem-604	471	30	a	a	DET
eurjchem-604	471	31	low	low	ADJ
eurjchem-604	471	32	energy	energy	NOUN
eurjchem-604	471	33	metal	metal	NOUN
eurjchem-604	471	34	orbital	orbital	NOUN
eurjchem-604	471	35	.	.	PUNCT
eurjchem-604	472	1	some	some	DET
eurjchem-604	472	2	years	year	NOUN
eurjchem-604	472	3	later	later	ADV
eurjchem-604	472	4	it	it	PRON
eurjchem-604	472	5	was	be	AUX
eurjchem-604	472	6	suggested	suggest	VERB
eurjchem-604	472	7	[	[	X
eurjchem-604	472	8	136	136	NUM
eurjchem-604	472	9	]	]	PUNCT
eurjchem-604	472	10	that	that	SCONJ
eurjchem-604	472	11	the	the	DET
eurjchem-604	472	12	pair	pair	NOUN
eurjchem-604	472	13	of	of	ADP
eurjchem-604	472	14	electrons	electron	NOUN
eurjchem-604	472	15	localized	localize	VERB
eurjchem-604	472	16	on	on	ADP
eurjchem-604	472	17	the	the	DET
eurjchem-604	472	18	cyclopentadienyl	cyclopentadienyl	NOUN
eurjchem-604	472	19	ring	ring	NOUN
eurjchem-604	472	20	could	could	AUX
eurjchem-604	472	21	be	be	AUX
eurjchem-604	472	22	formulated	formulate	VERB
eurjchem-604	472	23	as	as	ADP
eurjchem-604	472	24	an	an	DET
eurjchem-604	472	25	ƞ3	ƞ3	NOUN
eurjchem-604	472	26	allyl‐ene	allyl‐ene	NOUN
eurjchem-604	472	27	system	system	NOUN
eurjchem-604	472	28	.	.	PUNCT
eurjchem-604	473	1	there	there	ADV
eurjchem-604	473	2	isnow	isnow	VERB
eurjchem-604	473	3	x‐ray	x‐ray	ADJ
eurjchem-604	473	4	evidence	evidence	NOUN
eurjchem-604	473	5	[	[	X
eurjchem-604	473	6	137	137	NUM
eurjchem-604	473	7	]	]	PUNCT
eurjchem-604	473	8	for	for	ADP
eurjchem-604	473	9	such	such	DET
eurjchem-604	473	10	a	a	DET
eurjchem-604	473	11	cyclic	cyclic	ADJ
eurjchem-604	473	12	ligand	ligand	NOUN
eurjchem-604	473	13	in	in	ADP
eurjchem-604	473	14	the	the	DET
eurjchem-604	473	15	compound	compound	NOUN
eurjchem-604	473	16	(	(	PUNCT
eurjchem-604	473	17	ƞ5‐c5h5)(ƞ3‐c5h5)w(co)2	ƞ5‐c5h5)(ƞ3‐c5h5)w(co)2	NOUN
eurjchem-604	473	18	.	.	PUNCT
eurjchem-604	474	1	this	this	PRON
eurjchem-604	474	2	suggests	suggest	VERB
eurjchem-604	474	3	that	that	SCONJ
eurjchem-604	474	4	an	an	DET
eurjchem-604	474	5	ƞ5→	ƞ5→	NUM
eurjchem-604	474	6	ƞ3	ƞ3	NOUN
eurjchem-604	474	7	→	→	SYM
eurjchem-604	474	8	ƞ5associative	ƞ5associative	ADJ
eurjchem-604	474	9	pathway	pathway	NOUN
eurjchem-604	474	10	is	be	AUX
eurjchem-604	474	11	involved	involve	VERB
eurjchem-604	474	12	.	.	PUNCT
eurjchem-604	475	1	scheme	scheme	NOUN
eurjchem-604	475	2	25	25	NUM
eurjchem-604	475	3	as	as	SCONJ
eurjchem-604	475	4	expected	expect	VERB
eurjchem-604	475	5	for	for	ADP
eurjchem-604	475	6	a	a	DET
eurjchem-604	475	7	mechanism	mechanism	NOUN
eurjchem-604	475	8	that	that	PRON
eurjchem-604	475	9	requires	require	VERB
eurjchem-604	475	10	the	the	DET
eurjchem-604	475	11	flow	flow	NOUN
eurjchem-604	475	12	of	of	ADP
eurjchem-604	475	13	electron	electron	NOUN
eurjchem-604	475	14	density	density	NOUN
eurjchem-604	475	15	from	from	ADP
eurjchem-604	475	16	the	the	DET
eurjchem-604	475	17	metal	metal	NOUN
eurjchem-604	475	18	into	into	ADP
eurjchem-604	475	19	the	the	DET
eurjchem-604	475	20	cyclic	cyclic	ADJ
eurjchem-604	475	21	ligand	ligand	NOUN
eurjchem-604	475	22	,	,	PUNCT
eurjchem-604	475	23	electron	electron	NOUN
eurjchem-604	475	24	withdrawing	withdraw	VERB
eurjchem-604	475	25	substituents	substituent	NOUN
eurjchem-604	475	26	(	(	PUNCT
eurjchem-604	475	27	no2	no2	NOUN
eurjchem-604	475	28	)	)	PUNCT
eurjchem-604	475	29	on	on	ADP
eurjchem-604	475	30	the	the	DET
eurjchem-604	475	31	ring	ring	NOUN
eurjchem-604	475	32	enhance	enhance	NOUN
eurjchem-604	475	33	rates	rate	NOUN
eurjchem-604	475	34	of	of	ADP
eurjchem-604	475	35	co	co	NOUN
eurjchem-604	475	36	substitution	substitution	NOUN
eurjchem-604	475	37	and	and	CCONJ
eurjchem-604	475	38	electron	electron	NOUN
eurjchem-604	475	39	donating	donate	VERB
eurjchem-604	475	40	groups	group	NOUN
eurjchem-604	475	41	(	(	PUNCT
eurjchem-604	475	42	ch3	ch3	PROPN
eurjchem-604	475	43	)	)	PUNCT
eurjchem-604	475	44	on	on	ADP
eurjchem-604	475	45	the	the	DET
eurjchem-604	475	46	ring	ring	NOUN
eurjchem-604	475	47	retard	retard	NOUN
eurjchem-604	475	48	rates	rate	NOUN
eurjchem-604	475	49	of	of	ADP
eurjchem-604	475	50	substitution	substitution	NOUN
eurjchem-604	475	51	(	(	PUNCT
eurjchem-604	475	52	scheme	scheme	NOUN
eurjchem-604	475	53	26	26	NUM
eurjchem-604	475	54	)	)	PUNCT
eurjchem-604	475	55	.	.	PUNCT
eurjchem-604	476	1	scheme	scheme	NOUN
eurjchem-604	476	2	26	26	NUM
eurjchem-604	476	3	furthermore	furthermore	ADV
eurjchem-604	476	4	a	a	DET
eurjchem-604	476	5	relative	relative	ADJ
eurjchem-604	476	6	rate	rate	NOUN
eurjchem-604	476	7	increase	increase	NOUN
eurjchem-604	476	8	of	of	ADP
eurjchem-604	476	9	108	108	NUM
eurjchem-604	476	10	was	be	AUX
eurjchem-604	476	11	observed	observe	VERB
eurjchem-604	476	12	for	for	ADP
eurjchem-604	476	13	(	(	PUNCT
eurjchem-604	476	14	ƞ5‐indenyl)rh(co)2	ƞ5‐indenyl)rh(co)2	NOUN
eurjchem-604	476	15	over	over	ADP
eurjchem-604	476	16	(	(	PUNCT
eurjchem-604	476	17	ƞ5‐cyclopentadienyl)rh(co)2	ƞ5‐cyclopentadienyl)rh(co)2	PROPN
eurjchem-604	476	18	,	,	PUNCT
eurjchem-604	476	19	and	and	CCONJ
eurjchem-604	476	20	this	this	PRON
eurjchem-604	476	21	has	have	AUX
eurjchem-604	476	22	been	be	AUX
eurjchem-604	476	23	termed	term	VERB
eurjchem-604	476	24	the	the	DET
eurjchem-604	476	25	indenyl	indenyl	ADJ
eurjchem-604	476	26	ligand	ligand	ADJ
eurjchem-604	476	27	effect	effect	NOUN
eurjchem-604	477	1	[	[	X
eurjchem-604	477	2	138	138	NUM
eurjchem-604	477	3	]	]	PUNCT
eurjchem-604	477	4	.	.	PUNCT
eurjchem-604	478	1	this	this	PRON
eurjchem-604	478	2	had	have	AUX
eurjchem-604	478	3	been	be	AUX
eurjchem-604	478	4	previously	previously	ADV
eurjchem-604	478	5	observed	observe	VERB
eurjchem-604	478	6	(	(	PUNCT
eurjchem-604	478	7	scheme	scheme	NOUN
eurjchem-604	478	8	27	27	NUM
eurjchem-604	478	9	)	)	PUNCT
eurjchem-604	479	1	[	[	X
eurjchem-604	479	2	139	139	NUM
eurjchem-604	479	3	]	]	PUNCT
eurjchem-604	479	4	and	and	CCONJ
eurjchem-604	479	5	explained	explain	VERB
eurjchem-604	479	6	on	on	ADP
eurjchem-604	479	7	the	the	DET
eurjchem-604	479	8	basis	basis	NOUN
eurjchem-604	479	9	of	of	ADP
eurjchem-604	479	10	the	the	DET
eurjchem-604	479	11	fused	fuse	VERB
eurjchem-604	479	12	six‐ring	six‐ring	ADJ
eurjchem-604	479	13	aromaticity	aromaticity	NOUN
eurjchem-604	479	14	in	in	ADP
eurjchem-604	479	15	the	the	DET
eurjchem-604	479	16	transition	transition	NOUN
eurjchem-604	479	17	state	state	NOUN
eurjchem-604	479	18	tending	tend	VERB
eurjchem-604	479	19	to	to	PART
eurjchem-604	479	20	drive	drive	VERB
eurjchem-604	479	21	the	the	DET
eurjchem-604	479	22	associative	associative	ADJ
eurjchem-604	479	23	reaction	reaction	NOUN
eurjchem-604	479	24	.	.	PUNCT
eurjchem-604	480	1	scheme	scheme	NOUN
eurjchem-604	480	2	27	27	NUM
eurjchem-604	480	3	these	these	DET
eurjchem-604	480	4	studies	study	NOUN
eurjchem-604	480	5	show	show	VERB
eurjchem-604	480	6	it	it	PRON
eurjchem-604	480	7	is	be	AUX
eurjchem-604	480	8	possible	possible	ADJ
eurjchem-604	480	9	to	to	PART
eurjchem-604	480	10	markedly	markedly	ADV
eurjchem-604	480	11	vary	vary	VERB
eurjchem-604	480	12	(	(	PUNCT
eurjchem-604	480	13	over	over	ADP
eurjchem-604	480	14	1010	1010	NUM
eurjchem-604	480	15	times	time	NOUN
eurjchem-604	480	16	)	)	PUNCT
eurjchem-604	481	1	the	the	DET
eurjchem-604	481	2	rates	rate	NOUN
eurjchem-604	481	3	of	of	ADP
eurjchem-604	481	4	ligand	ligand	ADJ
eurjchem-604	481	5	substitution	substitution	NOUN
eurjchem-604	481	6	of	of	ADP
eurjchem-604	481	7	organometallic	organometallic	ADJ
eurjchem-604	481	8	compounds	compound	NOUN
eurjchem-604	481	9	,	,	PUNCT
eurjchem-604	481	10	and	and	CCONJ
eurjchem-604	481	11	if	if	SCONJ
eurjchem-604	481	12	necessary	necessary	ADJ
eurjchem-604	481	13	to	to	ADP
eurjchem-604	481	14	fine	fine	ADJ
eurjchem-604	481	15	tune	tune	NOUN
eurjchem-604	481	16	these	these	DET
eurjchem-604	481	17	rates	rate	NOUN
eurjchem-604	481	18	for	for	ADP
eurjchem-604	481	19	optimum	optimum	ADJ
eurjchem-604	481	20	homogenous	homogenous	ADJ
eurjchem-604	481	21	catalysis	catalysis	NOUN
eurjchem-604	481	22	conditions	condition	NOUN
eurjchem-604	481	23	.	.	PUNCT
eurjchem-604	482	1	3.2	3.2	NUM
eurjchem-604	482	2	.	.	PUNCT
eurjchem-604	482	3	heterocyclic	heterocyclic	ADJ
eurjchem-604	482	4	metal	metal	NOUN
eurjchem-604	482	5	carbonyl	carbonyl	NOUN
eurjchem-604	482	6	mechanism	mechanism	NOUN
eurjchem-604	482	7	although	although	SCONJ
eurjchem-604	482	8	thousands	thousand	NOUN
eurjchem-604	482	9	of	of	ADP
eurjchem-604	482	10	papers	paper	NOUN
eurjchem-604	482	11	have	have	AUX
eurjchem-604	482	12	been	be	AUX
eurjchem-604	482	13	published	publish	VERB
eurjchem-604	482	14	on	on	ADP
eurjchem-604	482	15	the	the	DET
eurjchem-604	482	16	synthesis	synthesis	NOUN
eurjchem-604	482	17	and	and	CCONJ
eurjchem-604	482	18	reactions	reaction	NOUN
eurjchem-604	482	19	if	if	SCONJ
eurjchem-604	482	20	ƞ5‐carbocyclic	ƞ5‐carbocyclic	NUM
eurjchem-604	482	21	metal	metal	NOUN
eurjchem-604	482	22	carbonyls	carbonyls	NOUN
eurjchem-604	482	23	,	,	PUNCT
eurjchem-604	482	24	much	much	ADV
eurjchem-604	482	25	less	less	ADJ
eurjchem-604	482	26	work	work	NOUN
eurjchem-604	482	27	has	have	AUX
eurjchem-604	482	28	been	be	AUX
eurjchem-604	482	29	done	do	VERB
eurjchem-604	482	30	with	with	ADP
eurjchem-604	482	31	the	the	DET
eurjchem-604	482	32	corresponding	correspond	VERB
eurjchem-604	482	33	ƞ5‐	ƞ5‐	NOUN
eurjchem-604	482	34	heterocyclic	heterocyclic	ADJ
eurjchem-604	482	35	compounds	compound	NOUN
eurjchem-604	482	36	[	[	X
eurjchem-604	482	37	140	140	NUM
eurjchem-604	482	38	]	]	PUNCT
eurjchem-604	482	39	.	.	PUNCT
eurjchem-604	483	1	no	no	DET
eurjchem-604	483	2	work	work	NOUN
eurjchem-604	483	3	had	have	AUX
eurjchem-604	483	4	been	be	AUX
eurjchem-604	483	5	reported	report	VERB
eurjchem-604	483	6	on	on	ADP
eurjchem-604	483	7	the	the	DET
eurjchem-604	483	8	kinetics	kinetic	NOUN
eurjchem-604	483	9	and	and	CCONJ
eurjchem-604	483	10	mechanisms	mechanism	NOUN
eurjchem-604	483	11	of	of	ADP
eurjchem-604	483	12	co	co	NOUN
eurjchem-604	483	13	substitutions	substitution	NOUN
eurjchem-604	483	14	of	of	ADP
eurjchem-604	483	15	these	these	DET
eurjchem-604	483	16	compounds	compound	NOUN
eurjchem-604	483	17	,	,	PUNCT
eurjchem-604	483	18	so	so	SCONJ
eurjchem-604	483	19	it	it	PRON
eurjchem-604	483	20	was	be	AUX
eurjchem-604	483	21	decided	decide	VERB
eurjchem-604	483	22	to	to	PART
eurjchem-604	483	23	mount	mount	VERB
eurjchem-604	483	24	such	such	DET
eurjchem-604	483	25	an	an	DET
eurjchem-604	483	26	investigation	investigation	NOUN
eurjchem-604	483	27	.	.	PUNCT
eurjchem-604	484	1	compounds	compound	NOUN
eurjchem-604	484	2	,	,	PUNCT
eurjchem-604	484	3	corresponding	correspond	VERB
eurjchem-604	484	4	to	to	ADP
eurjchem-604	484	5	known	known	ADJ
eurjchem-604	484	6	ƞ5‐cyclopentadienyl	ƞ5‐cyclopentadienyl	NOUN
eurjchem-604	484	7	metal	metal	NOUN
eurjchem-604	484	8	carbonyls	carbonyls	NOUN
eurjchem-604	484	9	,	,	PUNCT
eurjchem-604	484	10	were	be	AUX
eurjchem-604	484	11	prepared	prepare	VERB
eurjchem-604	484	12	and	and	CCONJ
eurjchem-604	484	13	studied	study	VERB
eurjchem-604	484	14	that	that	PRON
eurjchem-604	484	15	have	have	VERB
eurjchem-604	484	16	one	one	NUM
eurjchem-604	484	17	heteroatom	heteroatom	NOUN
eurjchem-604	484	18	(	(	PUNCT
eurjchem-604	484	19	n	n	CCONJ
eurjchem-604	484	20	,	,	PUNCT
eurjchem-604	484	21	p	p	X
eurjchem-604	484	22	,	,	PUNCT
eurjchem-604	484	23	or	or	CCONJ
eurjchem-604	484	24	as	as	ADP
eurjchem-604	484	25	)	)	PUNCT
eurjchem-604	484	26	in	in	ADP
eurjchem-604	484	27	the	the	DET
eurjchem-604	484	28	5‐membered	5‐membered	NUM
eurjchem-604	484	29	ring	ring	NOUN
eurjchem-604	484	30	.	.	PUNCT
eurjchem-604	485	1	the	the	DET
eurjchem-604	485	2	reactions	reaction	NOUN
eurjchem-604	485	3	investigated	investigate	VERB
eurjchem-604	485	4	[	[	X
eurjchem-604	485	5	141	141	NUM
eurjchem-604	485	6	]	]	PUNCT
eurjchem-604	485	7	are	be	AUX
eurjchem-604	485	8	presented	present	VERB
eurjchem-604	485	9	in	in	ADP
eurjchem-604	485	10	scheme	scheme	NOUN
eurjchem-604	485	11	28	28	NUM
eurjchem-604	485	12	,	,	PUNCT
eurjchem-604	485	13	where	where	SCONJ
eurjchem-604	485	14	e	e	NOUN
eurjchem-604	485	15	=	=	SYM
eurjchem-604	485	16	c	c	X
eurjchem-604	485	17	,	,	PUNCT
eurjchem-604	485	18	n	n	CCONJ
eurjchem-604	485	19	,	,	PUNCT
eurjchem-604	485	20	p	p	NOUN
eurjchem-604	485	21	or	or	CCONJ
eurjchem-604	485	22	as	as	ADP
eurjchem-604	485	23	,	,	PUNCT
eurjchem-604	485	24	and	and	CCONJ
eurjchem-604	485	25	l	l	NOUN
eurjchem-604	485	26	=	=	SYM
eurjchem-604	485	27	pr3	pr3	NOUN
eurjchem-604	485	28	or	or	CCONJ
eurjchem-604	485	29	p(or)3	p(or)3	PROPN
eurjchem-604	485	30	.	.	PUNCT
eurjchem-604	486	1	scheme	scheme	NOUN
eurjchem-604	486	2	28	28	NUM
eurjchem-604	486	3	the	the	DET
eurjchem-604	486	4	compounds	compound	NOUN
eurjchem-604	486	5	where	where	SCONJ
eurjchem-604	486	6	e	e	PROPN
eurjchem-604	486	7	=	=	SYM
eurjchem-604	486	8	c13	c13	PROPN
eurjchem-604	486	9	,	,	PUNCT
eurjchem-604	486	10	p	p	NOUN
eurjchem-604	486	11	or	or	CCONJ
eurjchem-604	486	12	as	as	SCONJ
eurjchem-604	486	13	do	do	AUX
eurjchem-604	486	14	not	not	PART
eurjchem-604	486	15	react	react	VERB
eurjchem-604	486	16	even	even	ADV
eurjchem-604	486	17	after	after	ADP
eurjchem-604	486	18	3	3	NUM
eurjchem-604	486	19	days	day	NOUN
eurjchem-604	486	20	at	at	ADP
eurjchem-604	486	21	130	130	NUM
eurjchem-604	486	22	oc	oc	NOUN
eurjchem-604	486	23	.	.	PUNCT
eurjchem-604	487	1	the	the	DET
eurjchem-604	487	2	(	(	PUNCT
eurjchem-604	487	3	ƞ5‐n‐heterocycle)mn(co)3	ƞ5‐n‐heterocycle)mn(co)3	PRON
eurjchem-604	487	4	does	do	AUX
eurjchem-604	487	5	reaction	reaction	NOUN
eurjchem-604	487	6	at	at	ADP
eurjchem-604	487	7	these	these	DET
eurjchem-604	487	8	conditions	condition	NOUN
eurjchem-604	487	9	with	with	ADP
eurjchem-604	487	10	a	a	DET
eurjchem-604	487	11	second	second	ADJ
eurjchem-604	487	12	order	order	NOUN
eurjchem-604	487	13	rate	rate	NOUN
eurjchem-604	487	14	law	law	NOUN
eurjchem-604	487	15	,	,	PUNCT
eurjchem-604	487	16	first	first	ADJ
eurjchem-604	487	17	order	order	NOUN
eurjchem-604	487	18	in	in	ADP
eurjchem-604	487	19	concentrations	concentration	NOUN
eurjchem-604	487	20	of	of	ADP
eurjchem-604	487	21	the	the	DET
eurjchem-604	487	22	complex	complex	NOUN
eurjchem-604	487	23	and	and	CCONJ
eurjchem-604	487	24	of	of	ADP
eurjchem-604	487	25	the	the	DET
eurjchem-604	487	26	nucleophile	nucleophile	NOUN
eurjchem-604	487	27	.	.	PUNCT
eurjchem-604	488	1	values	value	NOUN
eurjchem-604	488	2	of	of	ADP
eurjchem-604	488	3	second	second	ADJ
eurjchem-604	488	4	order	order	NOUN
eurjchem-604	488	5	rate	rate	NOUN
eurjchem-604	488	6	constant	constant	ADJ
eurjchem-604	488	7	at	at	ADP
eurjchem-604	488	8	130oc	130oc	PROPN
eurjchem-604	488	9	in	in	ADP
eurjchem-604	488	10	decalin	decalin	PROPN
eurjchem-604	488	11	are	be	AUX
eurjchem-604	488	12	1.2	1.2	NUM
eurjchem-604	488	13	x	x	SYM
eurjchem-604	488	14	10‐6	10‐6	NUM
eurjchem-604	488	15	mol‐1lit	mol‐1lit	VERB
eurjchem-604	488	16	sec‐1	sec‐1	PROPN
eurjchem-604	488	17	for	for	ADP
eurjchem-604	488	18	the	the	DET
eurjchem-604	488	19	nucleophile	nucleophile	ADJ
eurjchem-604	488	20	p(n‐bu)3	p(n‐bu)3	NOUN
eurjchem-604	488	21	and	and	CCONJ
eurjchem-604	488	22	2.0	2.0	NUM
eurjchem-604	488	23	x	x	SYM
eurjchem-604	488	24	10‐6	10‐6	NUM
eurjchem-604	488	25	mol‐1.l	mol‐1.l	NOUN
eurjchem-604	488	26	.	.	PUNCT
eurjchem-604	488	27	sec‐1	sec‐1	NUM
eurjchem-604	488	28	for	for	ADP
eurjchem-604	488	29	p(oet)3	p(oet)3	PROPN
eurjchem-604	488	30	.	.	PUNCT
eurjchem-604	489	1	the	the	DET
eurjchem-604	489	2	tentative	tentative	ADJ
eurjchem-604	489	3	interpretation	interpretation	NOUN
eurjchem-604	489	4	given	give	VERB
eurjchem-604	489	5	these	these	DET
eurjchem-604	489	6	observations	observation	NOUN
eurjchem-604	489	7	that	that	SCONJ
eurjchem-604	489	8	only	only	ADV
eurjchem-604	489	9	the	the	DET
eurjchem-604	489	10	n‐heterocyclic	n‐heterocyclic	PUNCT
eurjchem-604	489	11	compound	compound	NOUN
eurjchem-604	489	12	reacts	react	NOUN
eurjchem-604	489	13	is	be	AUX
eurjchem-604	489	14	that	that	SCONJ
eurjchem-604	489	15	n	n	X
eurjchem-604	489	16	is	be	AUX
eurjchem-604	489	17	the	the	DET
eurjchem-604	489	18	most	most	ADV
eurjchem-604	489	19	electronegative	electronegative	ADJ
eurjchem-604	489	20	atoms	atom	NOUN
eurjchem-604	489	21	used	use	VERB
eurjchem-604	489	22	,	,	PUNCT
eurjchem-604	489	23	e.	e.	PROPN
eurjchem-604	489	24	g.	g.	PROPN
eurjchem-604	489	25	n	n	PROPN
eurjchem-604	489	26	,	,	PUNCT
eurjchem-604	489	27	3.0	3.0	NUM
eurjchem-604	489	28	;	;	PUNCT
eurjchem-604	489	29	c	c	X
eurjchem-604	489	30	,	,	PUNCT
eurjchem-604	489	31	2.5	2.5	NUM
eurjchem-604	489	32	;	;	PUNCT
eurjchem-604	489	33	p	p	X
eurjchem-604	489	34	,	,	PUNCT
eurjchem-604	489	35	2.1	2.1	NUM
eurjchem-604	489	36	;	;	PUNCT
eurjchem-604	489	37	as	as	ADP
eurjchem-604	489	38	,	,	PUNCT
eurjchem-604	489	39	2.0	2.0	NUM
eurjchem-604	489	40	.	.	PUNCT
eurjchem-604	490	1	again	again	ADV
eurjchem-604	490	2	the	the	DET
eurjchem-604	490	3	greater	great	ADJ
eurjchem-604	490	4	electron	electron	NOUN
eurjchem-604	490	5	withdrawing	withdraw	VERB
eurjchem-604	490	6	property	property	NOUN
eurjchem-604	490	7	of	of	ADP
eurjchem-604	490	8	the	the	DET
eurjchem-604	490	9	cyclic	cyclic	ADJ
eurjchem-604	490	10	ligand	ligand	NOUN
eurjchem-604	490	11	with	with	ADP
eurjchem-604	490	12	the	the	DET
eurjchem-604	490	13	more	more	ADV
eurjchem-604	490	14	electronegative	electronegative	ADJ
eurjchem-604	490	15	n	n	NOUN
eurjchem-604	490	16	atoms	atom	NOUN
eurjchem-604	490	17	seems	seem	VERB
eurjchem-604	490	18	to	to	PART
eurjchem-604	490	19	enhance	enhance	VERB
eurjchem-604	490	20	the	the	DET
eurjchem-604	490	21	rate	rate	NOUN
eurjchem-604	490	22	of	of	ADP
eurjchem-604	490	23	an	an	DET
eurjchem-604	490	24	ƞ5→	ƞ5→	NOUN
eurjchem-604	490	25	ƞ3→	ƞ3→	NOUN
eurjchem-604	490	26	ƞ5	ƞ5	NOUN
eurjchem-604	490	27	mechanism	mechanism	NOUN
eurjchem-604	490	28	.	.	PUNCT
eurjchem-604	491	1	retracted	retract	VERB
eurjchem-604	491	2	378	378	NUM
eurjchem-604	491	3	kaushik	kaushik	NOUN
eurjchem-604	491	4	et	et	PROPN
eurjchem-604	491	5	al	al	PROPN
eurjchem-604	491	6	.	.	PUNCT
eurjchem-604	491	7	/	/	SYM
eurjchem-604	491	8	european	european	PROPN
eurjchem-604	491	9	journal	journal	PROPN
eurjchem-604	491	10	of	of	ADP
eurjchem-604	491	11	chemistry	chemistry	NOUN
eurjchem-604	491	12	3	3	NUM
eurjchem-604	491	13	(	(	PUNCT
eurjchem-604	491	14	3	3	NUM
eurjchem-604	491	15	)	)	PUNCT
eurjchem-604	491	16	(	(	PUNCT
eurjchem-604	491	17	2012	2012	NUM
eurjchem-604	491	18	)	)	PUNCT
eurjchem-604	491	19	367‐394	367‐394	NOUN
eurjchem-604	491	20	another	another	DET
eurjchem-604	491	21	interesting	interesting	ADJ
eurjchem-604	491	22	observation	observation	NOUN
eurjchem-604	491	23	[	[	X
eurjchem-604	491	24	142	142	NUM
eurjchem-604	491	25	]	]	PUNCT
eurjchem-604	491	26	was	be	AUX
eurjchem-604	491	27	made	make	VERB
eurjchem-604	491	28	when	when	SCONJ
eurjchem-604	491	29	the	the	DET
eurjchem-604	491	30	rates	rate	NOUN
eurjchem-604	491	31	of	of	ADP
eurjchem-604	491	32	reaction	reaction	NOUN
eurjchem-604	491	33	of	of	ADP
eurjchem-604	491	34	three	three	NUM
eurjchem-604	491	35	(	(	PUNCT
eurjchem-604	491	36	ƞ5‐n‐heterocyclic)mn(co)3	ƞ5‐n‐heterocyclic)mn(co)3	NUM
eurjchem-604	491	37	were	be	AUX
eurjchem-604	491	38	compared	compare	VERB
eurjchem-604	491	39	(	(	PUNCT
eurjchem-604	491	40	scheme	scheme	NOUN
eurjchem-604	491	41	29	29	NUM
eurjchem-604	491	42	)	)	PUNCT
eurjchem-604	491	43	.	.	PUNCT
eurjchem-604	492	1	scheme	scheme	VERB
eurjchem-604	492	2	29	29	NUM
eurjchem-604	492	3	addition	addition	NOUN
eurjchem-604	492	4	of	of	ADP
eurjchem-604	492	5	two	two	NUM
eurjchem-604	492	6	methyl	methyl	NOUN
eurjchem-604	492	7	substituent	substituent	NOUN
eurjchem-604	492	8	which	which	PRON
eurjchem-604	492	9	are	be	AUX
eurjchem-604	492	10	electron	electron	NOUN
eurjchem-604	492	11	donating	donate	VERB
eurjchem-604	492	12	to	to	ADP
eurjchem-604	492	13	the	the	DET
eurjchem-604	492	14	pyrrolyl	pyrrolyl	ADJ
eurjchem-604	492	15	ligand	ligand	NOUN
eurjchem-604	492	16	are	be	AUX
eurjchem-604	492	17	expected	expect	VERB
eurjchem-604	492	18	to	to	PART
eurjchem-604	492	19	decrease	decrease	VERB
eurjchem-604	492	20	the	the	DET
eurjchem-604	492	21	rate	rate	NOUN
eurjchem-604	492	22	of	of	ADP
eurjchem-604	492	23	co	co	NOUN
eurjchem-604	492	24	substitution	substitution	NOUN
eurjchem-604	492	25	by	by	ADP
eurjchem-604	492	26	an	an	DET
eurjchem-604	492	27	associative	associative	ADJ
eurjchem-604	492	28	ƞ5→	ƞ5→	NUM
eurjchem-604	492	29	ƞ3→	ƞ3→	ADP
eurjchem-604	492	30	ƞ5mechanism	ƞ5mechanism	PROPN
eurjchem-604	492	31	.	.	PUNCT
eurjchem-604	493	1	what	what	PRON
eurjchem-604	493	2	was	be	AUX
eurjchem-604	493	3	not	not	PART
eurjchem-604	493	4	anticipated	anticipate	VERB
eurjchem-604	493	5	is	be	AUX
eurjchem-604	493	6	that	that	SCONJ
eurjchem-604	493	7	the	the	DET
eurjchem-604	493	8	positions	position	NOUN
eurjchem-604	493	9	of	of	ADP
eurjchem-604	493	10	the	the	DET
eurjchem-604	493	11	methyl	methyl	NOUN
eurjchem-604	493	12	groups	group	NOUN
eurjchem-604	493	13	on	on	ADP
eurjchem-604	493	14	the	the	DET
eurjchem-604	493	15	ring	ring	NOUN
eurjchem-604	493	16	would	would	AUX
eurjchem-604	493	17	have	have	VERB
eurjchem-604	493	18	such	such	DET
eurjchem-604	493	19	a	a	DET
eurjchem-604	493	20	large	large	ADJ
eurjchem-604	493	21	effect	effect	NOUN
eurjchem-604	493	22	,	,	PUNCT
eurjchem-604	493	23	the	the	DET
eurjchem-604	493	24	2,5‐dimethyl	2,5‐dimethyl	NUM
eurjchem-604	493	25	pyrrolyl	pyrrolyl	PROPN
eurjchem-604	493	26	decreases	decrease	VERB
eurjchem-604	493	27	the	the	DET
eurjchem-604	493	28	rate	rate	NOUN
eurjchem-604	493	29	of	of	ADP
eurjchem-604	493	30	substitution	substitution	NOUN
eurjchem-604	493	31	100	100	NUM
eurjchem-604	493	32	times	time	NOUN
eurjchem-604	493	33	more	more	ADJ
eurjchem-604	493	34	than	than	SCONJ
eurjchem-604	493	35	does	do	VERB
eurjchem-604	493	36	the	the	DET
eurjchem-604	493	37	3,4‐dimethyl	3,4‐dimethyl	NUM
eurjchem-604	493	38	pyrrolyl	pyrrolyl	NOUN
eurjchem-604	493	39	.	.	PUNCT
eurjchem-604	494	1	we	we	PRON
eurjchem-604	494	2	suggest	suggest	VERB
eurjchem-604	494	3	this	this	DET
eurjchem-604	494	4	results	result	NOUN
eurjchem-604	494	5	form	form	VERB
eurjchem-604	494	6	a	a	DET
eurjchem-604	494	7	preferred	preferred	ADJ
eurjchem-604	494	8	ring	ring	NOUN
eurjchem-604	494	9	slippage	slippage	NOUN
eurjchem-604	494	10	towards	towards	ADP
eurjchem-604	494	11	the	the	DET
eurjchem-604	494	12	formation	formation	NOUN
eurjchem-604	494	13	of	of	ADP
eurjchem-604	494	14	an	an	DET
eurjchem-604	494	15	ƞ3‐2‐azaallyl	ƞ3‐2‐azaallyl	NUM
eurjchem-604	494	16	bonding	bonding	NOUN
eurjchem-604	494	17	mode	mode	NOUN
eurjchem-604	494	18	of	of	ADP
eurjchem-604	494	19	the	the	DET
eurjchem-604	494	20	metal	metal	NOUN
eurjchem-604	494	21	moiety	moiety	NOUN
eurjchem-604	494	22	to	to	ADP
eurjchem-604	494	23	the	the	DET
eurjchem-604	494	24	pyrrolyl	pyrrolyl	ADJ
eurjchem-604	494	25	ligand	ligand	NOUN
eurjchem-604	494	26	(	(	PUNCT
eurjchem-604	494	27	scheme	scheme	NOUN
eurjchem-604	494	28	30	30	NUM
eurjchem-604	494	29	)	)	PUNCT
eurjchem-604	494	30	in	in	ADP
eurjchem-604	494	31	the	the	DET
eurjchem-604	494	32	transition	transition	NOUN
eurjchem-604	494	33	state	state	NOUN
eurjchem-604	494	34	or	or	CCONJ
eurjchem-604	494	35	active	active	ADJ
eurjchem-604	494	36	intermediate	intermediate	ADJ
eurjchem-604	494	37	for	for	ADP
eurjchem-604	494	38	reaction	reaction	NOUN
eurjchem-604	494	39	.	.	PUNCT
eurjchem-604	495	1	scheme	scheme	NOUN
eurjchem-604	495	2	30	30	NUM
eurjchem-604	495	3	this	this	DET
eurjchem-604	495	4	slippage	slippage	NOUN
eurjchem-604	495	5	towards	towards	ADP
eurjchem-604	495	6	nitrogen	nitrogen	NOUN
eurjchem-604	495	7	results	result	NOUN
eurjchem-604	495	8	in	in	ADP
eurjchem-604	495	9	a	a	DET
eurjchem-604	495	10	much	much	ADV
eurjchem-604	495	11	more	more	ADV
eurjchem-604	495	12	crowded	crowded	ADJ
eurjchem-604	495	13	transition	transition	NOUN
eurjchem-604	495	14	state	state	NOUN
eurjchem-604	495	15	for	for	ADP
eurjchem-604	495	16	(	(	PUNCT
eurjchem-604	495	17	i	i	NOUN
eurjchem-604	495	18	)	)	PUNCT
eurjchem-604	495	19	than	than	ADP
eurjchem-604	495	20	for	for	ADP
eurjchem-604	495	21	the	the	DET
eurjchem-604	495	22	corresponding	correspond	VERB
eurjchem-604	495	23	3,4‐	3,4‐	NUM
eurjchem-604	495	24	dimethylpyrrolyl	dimethylpyrrolyl	ADJ
eurjchem-604	495	25	system	system	NOUN
eurjchem-604	495	26	,	,	PUNCT
eurjchem-604	495	27	and	and	CCONJ
eurjchem-604	495	28	thus	thus	ADV
eurjchem-604	495	29	a	a	DET
eurjchem-604	495	30	much	much	ADV
eurjchem-604	495	31	greater	great	ADJ
eurjchem-604	495	32	retardation	retardation	NOUN
eurjchem-604	495	33	in	in	ADP
eurjchem-604	495	34	the	the	DET
eurjchem-604	495	35	rate	rate	NOUN
eurjchem-604	495	36	of	of	ADP
eurjchem-604	495	37	co	co	NOUN
eurjchem-604	495	38	substitution	substitution	NOUN
eurjchem-604	495	39	,	,	PUNCT
eurjchem-604	495	40	support	support	NOUN
eurjchem-604	495	41	for	for	ADP
eurjchem-604	495	42	ring	ring	NOUN
eurjchem-604	495	43	slippage	slippage	NOUN
eurjchem-604	495	44	towards	towards	ADP
eurjchem-604	495	45	n	n	NUM
eurjchem-604	495	46	is	be	AUX
eurjchem-604	495	47	provided	provide	VERB
eurjchem-604	495	48	[	[	X
eurjchem-604	495	49	143	143	NUM
eurjchem-604	495	50	]	]	PUNCT
eurjchem-604	495	51	by	by	ADP
eurjchem-604	495	52	the	the	DET
eurjchem-604	495	53	x‐ray	x‐ray	PROPN
eurjchem-604	495	54	structure	structure	NOUN
eurjchem-604	495	55	of	of	ADP
eurjchem-604	495	56	(	(	PUNCT
eurjchem-604	495	57	ƞ5‐3,4‐	ƞ5‐3,4‐	PROPN
eurjchem-604	495	58	dimethylpyrrolyl)mn(co)3which	dimethylpyrrolyl)mn(co)3which	PROPN
eurjchem-604	495	59	shows	show	VERB
eurjchem-604	495	60	such	such	ADJ
eurjchem-604	495	61	slippage	slippage	NOUN
eurjchem-604	495	62	even	even	ADV
eurjchem-604	495	63	in	in	ADP
eurjchem-604	495	64	the	the	DET
eurjchem-604	495	65	ground	ground	NOUN
eurjchem-604	495	66	state	state	NOUN
eurjchem-604	495	67	.	.	PUNCT
eurjchem-604	496	1	since	since	SCONJ
eurjchem-604	496	2	only	only	ADV
eurjchem-604	496	3	the	the	DET
eurjchem-604	496	4	n‐heterocycle	n‐heterocycle	X
eurjchem-604	496	5	compounds	compound	NOUN
eurjchem-604	496	6	(	(	PUNCT
eurjchem-604	496	7	ƞ5‐n‐	ƞ5‐n‐	PROPN
eurjchem-604	496	8	heterocycle)mn(co)3react	heterocycle)mn(co)3react	VERB
eurjchem-604	496	9	rapidly	rapidly	ADV
eurjchem-604	496	10	enough	enough	ADV
eurjchem-604	496	11	even	even	ADV
eurjchem-604	496	12	at	at	ADP
eurjchem-604	496	13	130oc	130oc	PROPN
eurjchem-604	496	14	to	to	PART
eurjchem-604	496	15	conduct	conduct	VERB
eurjchem-604	496	16	a	a	DET
eurjchem-604	496	17	kinetic	kinetic	ADJ
eurjchem-604	496	18	study	study	NOUN
eurjchem-604	496	19	,	,	PUNCT
eurjchem-604	496	20	it	it	PRON
eurjchem-604	496	21	has	have	AUX
eurjchem-604	496	22	not	not	PART
eurjchem-604	496	23	been	be	AUX
eurjchem-604	496	24	possible	possible	ADJ
eurjchem-604	496	25	to	to	PART
eurjchem-604	496	26	determine	determine	VERB
eurjchem-604	496	27	if	if	SCONJ
eurjchem-604	496	28	indeed	indeed	ADV
eurjchem-604	496	29	there	there	PRON
eurjchem-604	496	30	is	be	VERB
eurjchem-604	496	31	a	a	DET
eurjchem-604	496	32	quantitative	quantitative	ADJ
eurjchem-604	496	33	correlation	correlation	NOUN
eurjchem-604	496	34	between	between	ADP
eurjchem-604	496	35	the	the	DET
eurjchem-604	496	36	rates	rate	NOUN
eurjchem-604	496	37	of	of	ADP
eurjchem-604	496	38	co	co	NOUN
eurjchem-604	496	39	substitution	substitution	NOUN
eurjchem-604	496	40	and	and	CCONJ
eurjchem-604	496	41	the	the	DET
eurjchem-604	496	42	electronegativity	electronegativity	NOUN
eurjchem-604	496	43	of	of	ADP
eurjchem-604	496	44	the	the	DET
eurjchem-604	496	45	hetero	hetero	NOUN
eurjchem-604	496	46	atom	atom	NOUN
eurjchem-604	496	47	.	.	PUNCT
eurjchem-604	497	1	this	this	PRON
eurjchem-604	497	2	should	should	AUX
eurjchem-604	497	3	be	be	AUX
eurjchem-604	497	4	possible	possible	ADJ
eurjchem-604	497	5	providing	provide	VERB
eurjchem-604	497	6	we	we	PRON
eurjchem-604	497	7	could	could	AUX
eurjchem-604	497	8	prepare	prepare	VERB
eurjchem-604	497	9	the	the	DET
eurjchem-604	497	10	more	more	ADV
eurjchem-604	497	11	reactive	reactive	ADJ
eurjchem-604	497	12	compounds	compound	NOUN
eurjchem-604	497	13	of	of	ADP
eurjchem-604	497	14	the	the	DET
eurjchem-604	497	15	type	type	NOUN
eurjchem-604	497	16	(	(	PUNCT
eurjchem-604	497	17	ƞ5‐heterocycle)m(co)2	ƞ5‐heterocycle)m(co)2	NOUN
eurjchem-604	497	18	,	,	PUNCT
eurjchem-604	497	19	where	where	SCONJ
eurjchem-604	497	20	m	m	VERB
eurjchem-604	497	21	=	=	SYM
eurjchem-604	497	22	co	co	X
eurjchem-604	497	23	,	,	PUNCT
eurjchem-604	497	24	rh	rh	PROPN
eurjchem-604	497	25	,	,	PUNCT
eurjchem-604	497	26	or	or	CCONJ
eurjchem-604	497	27	ir	ir	PROPN
eurjchem-604	497	28	.	.	PUNCT
eurjchem-604	498	1	an	an	DET
eurjchem-604	498	2	attempt	attempt	NOUN
eurjchem-604	498	3	(	(	PUNCT
eurjchem-604	498	4	scheme	scheme	NOUN
eurjchem-604	498	5	31	31	NUM
eurjchem-604	498	6	)	)	PUNCT
eurjchem-604	499	1	[	[	X
eurjchem-604	499	2	144	144	NUM
eurjchem-604	499	3	]	]	PUNCT
eurjchem-604	499	4	was	be	AUX
eurjchem-604	499	5	made	make	VERB
eurjchem-604	499	6	to	to	PART
eurjchem-604	499	7	prepare	prepare	VERB
eurjchem-604	499	8	(	(	PUNCT
eurjchem-604	499	9	ƞ5‐2,5‐dimethylpyrrolyl)rh(co)2by	ƞ5‐2,5‐dimethylpyrrolyl)rh(co)2by	PROPN
eurjchem-604	499	10	a	a	DET
eurjchem-604	499	11	reaction	reaction	NOUN
eurjchem-604	499	12	analogous	analogous	ADJ
eurjchem-604	499	13	to	to	ADP
eurjchem-604	499	14	that	that	PRON
eurjchem-604	499	15	used	use	VERB
eurjchem-604	499	16	for	for	ADP
eurjchem-604	499	17	the	the	DET
eurjchem-604	499	18	synthesis	synthesis	NOUN
eurjchem-604	499	19	of	of	ADP
eurjchem-604	499	20	(	(	PUNCT
eurjchem-604	499	21	ƞ5‐c5h5)rh(co)2	ƞ5‐c5h5)rh(co)2	PROPN
eurjchem-604	499	22	.	.	PUNCT
eurjchem-604	499	23	scheme	scheme	NOUN
eurjchem-604	499	24	31	31	NUM
eurjchem-604	499	25	the	the	DET
eurjchem-604	499	26	desired	desire	VERB
eurjchem-604	499	27	and	and	CCONJ
eurjchem-604	499	28	expected	expect	VERB
eurjchem-604	499	29	monomeric	monomeric	ADJ
eurjchem-604	499	30	(	(	PUNCT
eurjchem-604	499	31	ƞ5‐2,5‐	ƞ5‐2,5‐	NOUN
eurjchem-604	499	32	(	(	PUNCT
eurjchem-604	499	33	ch3)2c4h2n)rh(co)2was	ch3)2c4h2n)rh(co)2wa	VERB
eurjchem-604	499	34	not	not	PART
eurjchem-604	499	35	obtained	obtain	VERB
eurjchem-604	499	36	,	,	PUNCT
eurjchem-604	499	37	so	so	SCONJ
eurjchem-604	499	38	we	we	PRON
eurjchem-604	499	39	have	have	AUX
eurjchem-604	499	40	as	as	ADV
eurjchem-604	499	41	yet	yet	ADV
eurjchem-604	499	42	been	be	AUX
eurjchem-604	499	43	unable	unable	ADJ
eurjchem-604	499	44	to	to	PART
eurjchem-604	499	45	test	test	VERB
eurjchem-604	499	46	the	the	DET
eurjchem-604	499	47	concept	concept	NOUN
eurjchem-604	499	48	of	of	ADP
eurjchem-604	499	49	reactivity	reactivity	NOUN
eurjchem-604	499	50	versus	versus	ADP
eurjchem-604	499	51	the	the	DET
eurjchem-604	499	52	electronegativity	electronegativity	NOUN
eurjchem-604	499	53	of	of	ADP
eurjchem-604	499	54	the	the	DET
eurjchem-604	499	55	heteroatom	heteroatom	NOUN
eurjchem-604	499	56	.	.	PUNCT
eurjchem-604	500	1	however	however	ADV
eurjchem-604	500	2	,	,	PUNCT
eurjchem-604	500	3	the	the	DET
eurjchem-604	500	4	dimer	dimer	NOUN
eurjchem-604	500	5	obtained	obtain	VERB
eurjchem-604	500	6	is	be	AUX
eurjchem-604	500	7	the	the	DET
eurjchem-604	500	8	first	first	ADJ
eurjchem-604	500	9	example	example	NOUN
eurjchem-604	500	10	of	of	ADP
eurjchem-604	500	11	a	a	DET
eurjchem-604	500	12	heterocyclic	heterocyclic	ADJ
eurjchem-604	500	13	bridging	bridging	NOUN
eurjchem-604	500	14	ligand	ligand	NOUN
eurjchem-604	500	15	between	between	ADP
eurjchem-604	500	16	two	two	NUM
eurjchem-604	500	17	metals	metal	NOUN
eurjchem-604	500	18	utilizing	utilize	VERB
eurjchem-604	500	19	both	both	CCONJ
eurjchem-604	500	20	the	the	DET
eurjchem-604	500	21	σ	σ	NOUN
eurjchem-604	500	22	and	and	CCONJ
eurjchem-604	500	23	the	the	DET
eurjchem-604	500	24	ƞ2‐π	ƞ2‐π	ADJ
eurjchem-604	500	25	bonding	bonding	NOUN
eurjchem-604	500	26	modes	mode	NOUN
eurjchem-604	500	27	of	of	ADP
eurjchem-604	500	28	the	the	DET
eurjchem-604	500	29	ligand	ligand	NOUN
eurjchem-604	500	30	to	to	PART
eurjchem-604	500	31	form	form	VERB
eurjchem-604	500	32	a	a	DET
eurjchem-604	500	33	highly	highly	ADV
eurjchem-604	500	34	distorted	distorted	ADJ
eurjchem-604	500	35	metal‐olefin	metal‐olefin	NOUN
eurjchem-604	500	36	moiety	moiety	NOUN
eurjchem-604	500	37	.	.	PUNCT
eurjchem-604	501	1	3.3	3.3	NUM
eurjchem-604	501	2	.	.	X
eurjchem-604	502	1	17‐electron	17‐electron	NUM
eurjchem-604	502	2	metal	metal	NOUN
eurjchem-604	502	3	complexesmechanism	complexesmechanism	NOUN
eurjchem-604	502	4	it	it	PRON
eurjchem-604	502	5	is	be	AUX
eurjchem-604	502	6	well	well	ADV
eurjchem-604	502	7	known	know	VERB
eurjchem-604	502	8	that	that	SCONJ
eurjchem-604	502	9	for	for	ADP
eurjchem-604	502	10	molecular	molecular	ADJ
eurjchem-604	502	11	transition	transition	NOUN
eurjchem-604	502	12	metal	metal	NOUN
eurjchem-604	502	13	organometallic	organometallic	NOUN
eurjchem-604	502	14	compounds	compound	VERB
eurjchem-604	502	15	18‐electrons	18‐electrons	NUM
eurjchem-604	502	16	is	be	AUX
eurjchem-604	502	17	the	the	DET
eurjchem-604	502	18	magic	magic	ADJ
eurjchem-604	502	19	number	number	NOUN
eurjchem-604	502	20	for	for	ADP
eurjchem-604	502	21	maximum	maximum	ADJ
eurjchem-604	502	22	stability	stability	NOUN
eurjchem-604	502	23	.	.	PUNCT
eurjchem-604	503	1	three	three	NUM
eurjchem-604	503	2	decade	decade	NOUN
eurjchem-604	503	3	ago	ago	ADV
eurjchem-604	503	4	brown	brown	ADJ
eurjchem-604	503	5	[	[	X
eurjchem-604	503	6	145	145	NUM
eurjchem-604	503	7	]	]	PUNCT
eurjchem-604	503	8	reported	report	VERB
eurjchem-604	503	9	that	that	SCONJ
eurjchem-604	503	10	17‐electron	17‐electron	NUM
eurjchem-604	503	11	metal	metal	NOUN
eurjchem-604	503	12	carbonyl	carbonyl	NOUN
eurjchem-604	503	13	radicals	radical	NOUN
eurjchem-604	503	14	,	,	PUNCT
eurjchem-604	503	15	such	such	ADJ
eurjchem-604	503	16	as	as	ADP
eurjchem-604	503	17	mn(co)5	mn(co)5	ADJ
eurjchem-604	503	18	and	and	CCONJ
eurjchem-604	503	19	re(c0)5	re(c0)5	PROPN
eurjchem-604	503	20	,	,	PUNCT
eurjchem-604	503	21	are	be	AUX
eurjchem-604	503	22	substitution	substitution	NOUN
eurjchem-604	503	23	labile	labile	NOUN
eurjchem-604	503	24	.	.	PUNCT
eurjchem-604	504	1	these	these	DET
eurjchem-604	504	2	radicals	radical	NOUN
eurjchem-604	504	3	were	be	AUX
eurjchem-604	504	4	generated	generate	VERB
eurjchem-604	504	5	photochemically	photochemically	ADV
eurjchem-604	504	6	in	in	ADP
eurjchem-604	504	7	solution	solution	NOUN
eurjchem-604	504	8	and	and	CCONJ
eurjchem-604	504	9	studied	study	VERB
eurjchem-604	504	10	in	in	ADP
eurjchem-604	504	11	situ	situ	NOUN
eurjchem-604	504	12	,	,	PUNCT
eurjchem-604	504	13	so	so	SCONJ
eurjchem-604	504	14	shi	shi	PROPN
eurjchem-604	504	15	&	&	CCONJ
eurjchem-604	504	16	richmond	richmond	PROPN
eurjchem-604	505	1	[	[	X
eurjchem-604	505	2	146	146	NUM
eurjchem-604	505	3	]	]	PUNCT
eurjchem-604	505	4	decided	decide	VERB
eurjchem-604	505	5	to	to	PART
eurjchem-604	505	6	investigate	investigate	VERB
eurjchem-604	505	7	v(co)6	v(co)6	NUM
eurjchem-604	505	8	which	which	PRON
eurjchem-604	505	9	is	be	AUX
eurjchem-604	505	10	a	a	DET
eurjchem-604	505	11	stable	stable	ADJ
eurjchem-604	505	12	solid	solid	ADJ
eurjchem-604	505	13	17‐electron	17‐electron	NUM
eurjchem-604	505	14	binary	binary	ADJ
eurjchem-604	505	15	metal	metal	NOUN
eurjchem-604	505	16	carbonyl	carbonyl	NOUN
eurjchem-604	505	17	(	(	PUNCT
eurjchem-604	505	18	scheme	scheme	NOUN
eurjchem-604	505	19	32	32	NUM
eurjchem-604	505	20	)	)	PUNCT
eurjchem-604	505	21	.	.	PUNCT
eurjchem-604	506	1	scheme	scheme	NOUN
eurjchem-604	506	2	32	32	NUM
eurjchem-604	506	3	the	the	DET
eurjchem-604	506	4	reaction	reaction	NOUN
eurjchem-604	506	5	proceeds	proceed	NOUN
eurjchem-604	506	6	by	by	ADP
eurjchem-604	506	7	an	an	DET
eurjchem-604	506	8	associative	associative	ADJ
eurjchem-604	506	9	mechanism	mechanism	NOUN
eurjchem-604	506	10	.	.	PUNCT
eurjchem-604	507	1	the	the	DET
eurjchem-604	507	2	point	point	NOUN
eurjchem-604	507	3	of	of	ADP
eurjchem-604	507	4	interest	interest	NOUN
eurjchem-604	507	5	here	here	ADV
eurjchem-604	507	6	is	be	AUX
eurjchem-604	507	7	that	that	SCONJ
eurjchem-604	507	8	it	it	PRON
eurjchem-604	507	9	was	be	AUX
eurjchem-604	507	10	possible	possible	ADJ
eurjchem-604	507	11	for	for	ADP
eurjchem-604	507	12	the	the	DET
eurjchem-604	507	13	first	first	ADJ
eurjchem-604	507	14	time	time	NOUN
eurjchem-604	507	15	to	to	PART
eurjchem-604	507	16	quantitatively	quantitatively	ADV
eurjchem-604	507	17	compare	compare	VERB
eurjchem-604	507	18	the	the	DET
eurjchem-604	507	19	rates	rate	NOUN
eurjchem-604	507	20	of	of	ADP
eurjchem-604	507	21	co	co	NOUN
eurjchem-604	507	22	substitution	substitution	NOUN
eurjchem-604	507	23	of	of	ADP
eurjchem-604	507	24	analogous	analogous	ADJ
eurjchem-604	507	25	17‐	17‐	NUM
eurjchem-604	507	26	and	and	CCONJ
eurjchem-604	507	27	18‐electron	18‐electron	NUM
eurjchem-604	507	28	metal	metal	NOUN
eurjchem-604	507	29	carbonyls	carbonyls	NOUN
eurjchem-604	507	30	(	(	PUNCT
eurjchem-604	507	31	scheme	scheme	NOUN
eurjchem-604	507	32	33	33	NUM
eurjchem-604	507	33	)	)	PUNCT
eurjchem-604	507	34	.	.	PUNCT
eurjchem-604	508	1	scheme	scheme	VERB
eurjchem-604	508	2	33	33	NUM
eurjchem-604	508	3	this	this	DET
eurjchem-604	508	4	rapid	rapid	ADJ
eurjchem-604	508	5	rate	rate	NOUN
eurjchem-604	508	6	of	of	ADP
eurjchem-604	508	7	associative	associative	ADJ
eurjchem-604	508	8	ligand	ligand	NOUN
eurjchem-604	508	9	substitution	substitution	NOUN
eurjchem-604	508	10	of	of	ADP
eurjchem-604	508	11	a	a	DET
eurjchem-604	508	12	17‐	17‐	NUM
eurjchem-604	508	13	electron	electron	NOUN
eurjchem-604	508	14	over	over	ADP
eurjchem-604	508	15	a	a	DET
eurjchem-604	508	16	corresponding	correspond	VERB
eurjchem-604	508	17	18‐electron	18‐electron	NUM
eurjchem-604	508	18	metal	metal	NOUN
eurjchem-604	508	19	complex	complex	NOUN
eurjchem-604	508	20	is	be	AUX
eurjchem-604	508	21	in	in	ADP
eurjchem-604	508	22	accord	accord	NOUN
eurjchem-604	508	23	with	with	ADP
eurjchem-604	508	24	the	the	DET
eurjchem-604	508	25	lower	low	ADJ
eurjchem-604	508	26	energy	energy	NOUN
eurjchem-604	508	27	barrier	barrier	NOUN
eurjchem-604	508	28	for	for	ADP
eurjchem-604	508	29	the	the	DET
eurjchem-604	508	30	reaction	reaction	NOUN
eurjchem-604	508	31	process	process	NOUN
eurjchem-604	508	32	of	of	ADP
eurjchem-604	508	33	17‐electron	17‐electron	NUM
eurjchem-604	508	34	→19‐electron	→19‐electron	PUNCT
eurjchem-604	508	35	compared	compare	VERB
eurjchem-604	508	36	to	to	ADP
eurjchem-604	508	37	that	that	PRON
eurjchem-604	508	38	of	of	ADP
eurjchem-604	508	39	18‐electron	18‐electron	NUM
eurjchem-604	508	40	→20‐electron	→20‐electron	X
eurjchem-604	508	41	.	.	PUNCT
eurjchem-604	509	1	this	this	DET
eurjchem-604	509	2	investigation	investigation	NOUN
eurjchem-604	509	3	was	be	AUX
eurjchem-604	509	4	extended	extend	VERB
eurjchem-604	509	5	to	to	ADP
eurjchem-604	509	6	the	the	DET
eurjchem-604	509	7	reaction	reaction	NOUN
eurjchem-604	509	8	of	of	ADP
eurjchem-604	509	9	vanadocene	vanadocene	NOUN
eurjchem-604	509	10	,	,	PUNCT
eurjchem-604	509	11	(	(	PUNCT
eurjchem-604	509	12	ƞ5‐c5h5)v	ƞ5‐c5h5)v	PROPN
eurjchem-604	509	13	,	,	PUNCT
eurjchem-604	509	14	with	with	ADP
eurjchem-604	509	15	co	co	NOUN
eurjchem-604	509	16	to	to	PART
eurjchem-604	509	17	give	give	VERB
eurjchem-604	509	18	the	the	DET
eurjchem-604	509	19	17‐electron	17‐electron	NUM
eurjchem-604	509	20	adduct	adduct	NOUN
eurjchem-604	509	21	(	(	PUNCT
eurjchem-604	509	22	ƞ5‐c5h5)2vc0	ƞ5‐c5h5)2vc0	NUM
eurjchem-604	509	23	and	and	CCONJ
eurjchem-604	509	24	to	to	ADP
eurjchem-604	509	25	its	its	PRON
eurjchem-604	509	26	co	co	ADJ
eurjchem-604	509	27	exchange	exchange	PROPN
eurjchem-604	509	28	kinetics	kinetic	NOUN
eurjchem-604	510	1	[	[	X
eurjchem-604	510	2	147	147	NUM
eurjchem-604	510	3	]	]	PUNCT
eurjchem-604	510	4	.	.	PUNCT
eurjchem-604	511	1	the	the	DET
eurjchem-604	511	2	rate	rate	NOUN
eurjchem-604	511	3	of	of	ADP
eurjchem-604	511	4	co	co	NOUN
eurjchem-604	511	5	exchange	exchange	NOUN
eurjchem-604	511	6	is	be	AUX
eurjchem-604	511	7	fast	fast	ADJ
eurjchem-604	511	8	and	and	CCONJ
eurjchem-604	511	9	it	it	PRON
eurjchem-604	511	10	goes	go	VERB
eurjchem-604	511	11	by	by	ADP
eurjchem-604	511	12	an	an	DET
eurjchem-604	511	13	associative	associative	ADJ
eurjchem-604	511	14	mechanism	mechanism	NOUN
eurjchem-604	511	15	as	as	SCONJ
eurjchem-604	511	16	proposed	propose	VERB
eurjchem-604	511	17	by	by	ADP
eurjchem-604	511	18	the	the	DET
eurjchem-604	511	19	reaction	reaction	NOUN
eurjchem-604	511	20	profile	profile	NOUN
eurjchem-604	511	21	.	.	PUNCT
eurjchem-604	512	1	experiments	experiment	NOUN
eurjchem-604	512	2	showed	show	VERB
eurjchem-604	512	3	that	that	SCONJ
eurjchem-604	512	4	the	the	DET
eurjchem-604	512	5	rate	rate	NOUN
eurjchem-604	512	6	of	of	ADP
eurjchem-604	512	7	co	co	ADJ
eurjchem-604	512	8	exchange	exchange	NOUN
eurjchem-604	512	9	with	with	ADP
eurjchem-604	512	10	(	(	PUNCT
eurjchem-604	512	11	ƞ5‐	ƞ5‐	NOUN
eurjchem-604	512	12	c5h5)vco	c5h5)vco	NOUN
eurjchem-604	512	13	is	be	AUX
eurjchem-604	512	14	greater	great	ADJ
eurjchem-604	512	15	than	than	ADP
eurjchem-604	512	16	the	the	DET
eurjchem-604	512	17	rate	rate	NOUN
eurjchem-604	512	18	of	of	ADP
eurjchem-604	512	19	addition	addition	NOUN
eurjchem-604	512	20	of	of	ADP
eurjchem-604	512	21	co	co	NOUN
eurjchem-604	512	22	to	to	PART
eurjchem-604	512	23	vanadocene	vanadocene	VERB
eurjchem-604	512	24	,	,	PUNCT
eurjchem-604	512	25	which	which	PRON
eurjchem-604	512	26	accounts	account	VERB
eurjchem-604	512	27	for	for	ADP
eurjchem-604	512	28	the	the	DET
eurjchem-604	512	29	higher	high	ADJ
eurjchem-604	512	30	energy	energy	NOUN
eurjchem-604	512	31	barrier	barrier	NOUN
eurjchem-604	512	32	.	.	PUNCT
eurjchem-604	513	1	it	it	PRON
eurjchem-604	513	2	is	be	AUX
eurjchem-604	513	3	believed	believe	VERB
eurjchem-604	513	4	this	this	PRON
eurjchem-604	513	5	is	be	AUX
eurjchem-604	513	6	caused	cause	VERB
eurjchem-604	513	7	by	by	ADP
eurjchem-604	513	8	the	the	DET
eurjchem-604	513	9	conformational	conformational	ADJ
eurjchem-604	513	10	change	change	NOUN
eurjchem-604	513	11	required	require	VERB
eurjchem-604	513	12	when	when	SCONJ
eurjchem-604	513	13	co	co	NOUN
eurjchem-604	513	14	is	be	AUX
eurjchem-604	513	15	added	add	VERB
eurjchem-604	513	16	to	to	PART
eurjchem-604	513	17	vanadocene	vanadocene	VERB
eurjchem-604	513	18	,	,	PUNCT
eurjchem-604	513	19	whereas	whereas	SCONJ
eurjchem-604	513	20	the	the	DET
eurjchem-604	513	21	associative	associative	NOUN
eurjchem-604	513	22	co	co	NOUN
eurjchem-604	513	23	exchange	exchange	NOUN
eurjchem-604	513	24	takes	take	VERB
eurjchem-604	513	25	place	place	NOUN
eurjchem-604	513	26	without	without	ADP
eurjchem-604	513	27	the	the	DET
eurjchem-604	513	28	expenditure	expenditure	NOUN
eurjchem-604	513	29	of	of	ADP
eurjchem-604	513	30	energy	energy	NOUN
eurjchem-604	513	31	required	require	VERB
eurjchem-604	513	32	to	to	PART
eurjchem-604	513	33	bend	bend	VERB
eurjchem-604	513	34	back	back	ADP
eurjchem-604	513	35	the	the	DET
eurjchem-604	513	36	cyclopentadienyl	cyclopentadienyl	NOUN
eurjchem-604	513	37	rings	ring	NOUN
eurjchem-604	513	38	.	.	PUNCT
eurjchem-604	514	1	a	a	DET
eurjchem-604	514	2	dramatic	dramatic	ADJ
eurjchem-604	514	3	change	change	NOUN
eurjchem-604	514	4	in	in	ADP
eurjchem-604	514	5	rate	rate	NOUN
eurjchem-604	514	6	and	and	CCONJ
eurjchem-604	514	7	in	in	ADP
eurjchem-604	514	8	mechanism	mechanism	NOUN
eurjchem-604	514	9	was	be	AUX
eurjchem-604	514	10	observed	observe	VERB
eurjchem-604	514	11	[	[	PUNCT
eurjchem-604	514	12	148	148	NUM
eurjchem-604	514	13	]	]	PUNCT
eurjchem-604	514	14	when	when	SCONJ
eurjchem-604	514	15	cyclopentadienyl	cyclopentadienyl	NOUN
eurjchem-604	514	16	was	be	AUX
eurjchem-604	514	17	replaced	replace	VERB
eurjchem-604	514	18	by	by	ADP
eurjchem-604	514	19	pentadienyl	pentadienyl	NOUN
eurjchem-604	514	20	in	in	ADP
eurjchem-604	514	21	these	these	DET
eurjchem-604	514	22	systems	system	NOUN
eurjchem-604	514	23	.	.	PUNCT
eurjchem-604	515	1	the	the	DET
eurjchem-604	515	2	compound	compound	NOUN
eurjchem-604	515	3	(	(	PUNCT
eurjchem-604	515	4	ƞ5‐c5h7)vco	ƞ5‐c5h7)vco	NOUN
eurjchem-604	515	5	is	be	AUX
eurjchem-604	515	6	substituted	substitute	VERB
eurjchem-604	515	7	inert	inert	NOUN
eurjchem-604	515	8	and	and	CCONJ
eurjchem-604	515	9	substitution	substitution	NOUN
eurjchem-604	515	10	takes	take	VERB
eurjchem-604	515	11	place	place	NOUN
eurjchem-604	515	12	by	by	ADP
eurjchem-604	515	13	a	a	DET
eurjchem-604	515	14	dissociative	dissociative	ADJ
eurjchem-604	515	15	pathway	pathway	NOUN
eurjchem-604	515	16	.	.	PUNCT
eurjchem-604	516	1	this	this	PRON
eurjchem-604	516	2	is	be	AUX
eurjchem-604	516	3	the	the	DET
eurjchem-604	516	4	first	first	ADJ
eurjchem-604	516	5	report	report	NOUN
eurjchem-604	516	6	of	of	ADP
eurjchem-604	516	7	a	a	DET
eurjchem-604	516	8	kinetic	kinetic	ADJ
eurjchem-604	516	9	study	study	NOUN
eurjchem-604	516	10	of	of	ADP
eurjchem-604	516	11	a	a	DET
eurjchem-604	516	12	17‐electron	17‐electron	NUM
eurjchem-604	516	13	organometallic	organometallic	ADJ
eurjchem-604	516	14	compound	compound	NOUN
eurjchem-604	516	15	that	that	PRON
eurjchem-604	516	16	is	be	AUX
eurjchem-604	516	17	slow	slow	ADJ
eurjchem-604	516	18	to	to	PART
eurjchem-604	516	19	react	react	VERB
eurjchem-604	516	20	and	and	CCONJ
eurjchem-604	516	21	that	that	SCONJ
eurjchem-604	516	22	reacts	react	VERB
eurjchem-604	516	23	by	by	ADP
eurjchem-604	516	24	a	a	DET
eurjchem-604	516	25	dissociative	dissociative	ADJ
eurjchem-604	516	26	process	process	NOUN
eurjchem-604	516	27	.	.	PUNCT
eurjchem-604	517	1	the	the	DET
eurjchem-604	517	2	absence	absence	NOUN
eurjchem-604	517	3	of	of	ADP
eurjchem-604	517	4	a	a	DET
eurjchem-604	517	5	facile	facile	ADJ
eurjchem-604	517	6	associative	associative	ADJ
eurjchem-604	517	7	substitution	substitution	NOUN
eurjchem-604	517	8	pathway	pathway	NOUN
eurjchem-604	517	9	in	in	ADP
eurjchem-604	517	10	the	the	DET
eurjchem-604	517	11	pentadienyl	pentadienyl	NOUN
eurjchem-604	517	12	compounds	compound	NOUN
eurjchem-604	517	13	may	may	AUX
eurjchem-604	517	14	be	be	AUX
eurjchem-604	517	15	attributed	attribute	VERB
eurjchem-604	517	16	to	to	ADP
eurjchem-604	517	17	the	the	DET
eurjchem-604	517	18	more	more	ADV
eurjchem-604	517	19	rigid	rigid	ADJ
eurjchem-604	517	20	(	(	PUNCT
eurjchem-604	517	21	ƞ5‐c5h7)2v	ƞ5‐c5h7)2v	NOUN
eurjchem-604	517	22	moiety	moiety	NOUN
eurjchem-604	517	23	,	,	PUNCT
eurjchem-604	517	24	decreased	decrease	VERB
eurjchem-604	517	25	v‐	v‐	NOUN
eurjchem-604	517	26	co	co	ADJ
eurjchem-604	517	27	π‐backbonding	π‐backbonding	PROPN
eurjchem-604	517	28	,	,	PUNCT
eurjchem-604	517	29	or	or	CCONJ
eurjchem-604	517	30	reduced	reduce	VERB
eurjchem-604	517	31	electron	electron	NOUN
eurjchem-604	517	32	spin	spin	NOUN
eurjchem-604	517	33	delocalization	delocalization	NOUN
eurjchem-604	517	34	,	,	PUNCT
eurjchem-604	517	35	all	all	PRON
eurjchem-604	517	36	of	of	ADP
eurjchem-604	517	37	which	which	PRON
eurjchem-604	517	38	make	make	VERB
eurjchem-604	517	39	the	the	DET
eurjchem-604	517	40	meral	meral	ADJ
eurjchem-604	517	41	center	center	NOUN
eurjchem-604	517	42	less	less	ADV
eurjchem-604	517	43	susceptible	susceptible	ADJ
eurjchem-604	517	44	to	to	ADP
eurjchem-604	517	45	nucleophilic	nucleophilic	ADJ
eurjchem-604	517	46	attack	attack	NOUN
eurjchem-604	517	47	.	.	PUNCT
eurjchem-604	518	1	4	4	X
eurjchem-604	518	2	.	.	X
eurjchem-604	518	3	previously	previously	ADV
eurjchem-604	518	4	reported	report	VERB
eurjchem-604	518	5	substituted	substitute	VERB
eurjchem-604	518	6	complexes	complex	NOUN
eurjchem-604	518	7	of	of	ADP
eurjchem-604	518	8	g‐6	g‐6	VERB
eurjchem-604	518	9	metal	metal	NOUN
eurjchem-604	518	10	carbonyls	carbonyls	NOUN
eurjchem-604	518	11	4.1	4.1	NUM
eurjchem-604	518	12	.	.	PUNCT
eurjchem-604	519	1	metal	metal	NOUN
eurjchem-604	519	2	carbonyl	carbonyl	NOUN
eurjchem-604	519	3	complexes	complex	NOUN
eurjchem-604	519	4	with	with	ADP
eurjchem-604	519	5	monodentate	monodentate	ADJ
eurjchem-604	519	6	ligands	ligand	NOUN
eurjchem-604	519	7	the	the	DET
eurjchem-604	519	8	photochemical	photochemical	ADJ
eurjchem-604	519	9	reactions	reaction	NOUN
eurjchem-604	519	10	of	of	ADP
eurjchem-604	519	11	w(co)6	w(co)6	PROPN
eurjchem-604	519	12	with	with	ADP
eurjchem-604	519	13	alkynes	alkynes	PROPN
eurjchem-604	519	14	hc≡ch	hc≡ch	PROPN
eurjchem-604	519	15	,	,	PUNCT
eurjchem-604	519	16	hc≡cme	hc≡cme	PROPN
eurjchem-604	519	17	and	and	CCONJ
eurjchem-604	519	18	hc≡ccme3	hc≡ccme3	PROPN
eurjchem-604	519	19	give	give	VERB
eurjchem-604	519	20	the	the	DET
eurjchem-604	519	21	unstable	unstable	ADJ
eurjchem-604	519	22	terminal	terminal	ADJ
eurjchem-604	519	23	alkyne	alkyne	NOUN
eurjchem-604	519	24	complexes	complex	NOUN
eurjchem-604	519	25	[	[	X
eurjchem-604	519	26	w(co)5(η2‐hc≡cr	w(co)5(η2‐hc≡cr	X
eurjchem-604	519	27	)	)	PUNCT
eurjchem-604	519	28	]	]	PUNCT
eurjchem-604	519	29	,	,	PUNCT
eurjchem-604	520	1	[	[	X
eurjchem-604	520	2	w(co)4(η2‐hc≡cr)2	w(co)4(η2‐hc≡cr)2	ADP
eurjchem-604	520	3	]	]	PUNCT
eurjchem-604	520	4	,	,	PUNCT
eurjchem-604	520	5	[	[	X
eurjchem-604	520	6	w(co)(η2‐hc≡cr)3	w(co)(η2‐hc≡cr)3	X
eurjchem-604	520	7	]	]	X
eurjchem-604	520	8	,	,	PUNCT
eurjchem-604	520	9	and	and	CCONJ
eurjchem-604	520	10	vinylidene	vinylidene	NOUN
eurjchem-604	520	11	derivatives	derivative	NOUN
eurjchem-604	520	12	[	[	X
eurjchem-604	520	13	w(co)5(c	w(co)5(c	NOUN
eurjchem-604	520	14	=	=	SYM
eurjchem-604	520	15	chr	chr	NOUN
eurjchem-604	520	16	)	)	PUNCT
eurjchem-604	520	17	]	]	PUNCT
eurjchem-604	520	18	.	.	PUNCT
eurjchem-604	521	1	retracted	retract	VERB
eurjchem-604	521	2	kaushik	kaushik	PROPN
eurjchem-604	521	3	et	et	PROPN
eurjchem-604	521	4	al	al	PROPN
eurjchem-604	521	5	.	.	PUNCT
eurjchem-604	521	6	/	/	SYM
eurjchem-604	521	7	european	european	PROPN
eurjchem-604	521	8	journal	journal	PROPN
eurjchem-604	521	9	of	of	ADP
eurjchem-604	521	10	chemistry	chemistry	NOUN
eurjchem-604	521	11	3	3	NUM
eurjchem-604	521	12	(	(	PUNCT
eurjchem-604	521	13	3	3	NUM
eurjchem-604	521	14	)	)	PUNCT
eurjchem-604	521	15	(	(	PUNCT
eurjchem-604	521	16	2012	2012	NUM
eurjchem-604	521	17	)	)	PUNCT
eurjchem-604	521	18	367‐394	367‐394	NOUN
eurjchem-604	521	19	379	379	NUM
eurjchem-604	521	20	the	the	DET
eurjchem-604	521	21	studies	study	NOUN
eurjchem-604	521	22	show	show	VERB
eurjchem-604	521	23	that	that	SCONJ
eurjchem-604	521	24	alkynes	alkyne	NOUN
eurjchem-604	521	25	behave	behave	VERB
eurjchem-604	521	26	as	as	ADP
eurjchem-604	521	27	monodentate	monodentate	ADJ
eurjchem-604	521	28	ligand	ligand	NOUN
eurjchem-604	522	1	[	[	X
eurjchem-604	522	2	149	149	NUM
eurjchem-604	522	3	]	]	PUNCT
eurjchem-604	522	4	.	.	PUNCT
eurjchem-604	523	1	the	the	DET
eurjchem-604	523	2	metal	metal	NOUN
eurjchem-604	523	3	carbonyl	carbonyl	NOUN
eurjchem-604	523	4	complexes	complex	NOUN
eurjchem-604	523	5	with	with	ADP
eurjchem-604	523	6	various	various	ADJ
eurjchem-604	523	7	monodentate	monodentate	NOUN
eurjchem-604	523	8	ligands	ligand	NOUN
eurjchem-604	523	9	are	be	AUX
eurjchem-604	523	10	shown	show	VERB
eurjchem-604	523	11	below	below	ADP
eurjchem-604	523	12	.	.	PUNCT
eurjchem-604	524	1	4.1.1	4.1.1	X
eurjchem-604	524	2	.	.	PUNCT
eurjchem-604	524	3	monosubstituted	monosubstitute	VERB
eurjchem-604	524	4	complexes	complex	NOUN
eurjchem-604	524	5	[	[	X
eurjchem-604	524	6	m(co)5l	m(co)5l	X
eurjchem-604	524	7	]	]	X
eurjchem-604	524	8	a	a	DET
eurjchem-604	524	9	series	series	NOUN
eurjchem-604	524	10	of	of	ADP
eurjchem-604	524	11	carbonylchromium	carbonylchromium	NOUN
eurjchem-604	524	12	,	,	PUNCT
eurjchem-604	524	13	molybdenum	molybdenum	NOUN
eurjchem-604	524	14	and	and	CCONJ
eurjchem-604	524	15	tungsten	tungsten	NOUN
eurjchem-604	524	16	complexes	complex	NOUN
eurjchem-604	524	17	containing	contain	VERB
eurjchem-604	524	18	ferrocenylpyrazole	ferrocenylpyrazole	NOUN
eurjchem-604	524	19	ligands	ligand	NOUN
eurjchem-604	524	20	,	,	PUNCT
eurjchem-604	524	21	(	(	PUNCT
eurjchem-604	524	22	m(co)5l	m(co)5l	X
eurjchem-604	524	23	)	)	PUNCT
eurjchem-604	524	24	(	(	PUNCT
eurjchem-604	524	25	m	m	NOUN
eurjchem-604	524	26	=	=	SYM
eurjchem-604	524	27	cr	cr	PROPN
eurjchem-604	524	28	,	,	PUNCT
eurjchem-604	524	29	mo	mo	NOUN
eurjchem-604	524	30	or	or	CCONJ
eurjchem-604	524	31	w	w	PROPN
eurjchem-604	524	32	;	;	PUNCT
eurjchem-604	524	33	l	l	NOUN
eurjchem-604	524	34	represents	represent	VERB
eurjchem-604	524	35	ferrocenyl	ferrocenyl	ADJ
eurjchem-604	524	36	pyrazole	pyrazole	NOUN
eurjchem-604	524	37	)	)	PUNCT
eurjchem-604	524	38	,	,	PUNCT
eurjchem-604	524	39	have	have	AUX
eurjchem-604	524	40	been	be	AUX
eurjchem-604	524	41	prepared	prepare	VERB
eurjchem-604	524	42	by	by	ADP
eurjchem-604	524	43	the	the	DET
eurjchem-604	524	44	photochemical	photochemical	ADJ
eurjchem-604	524	45	reactions	reaction	NOUN
eurjchem-604	524	46	of	of	ADP
eurjchem-604	524	47	ferrocenylpyrazole	ferrocenylpyrazole	NOUN
eurjchem-604	524	48	ligands	ligand	NOUN
eurjchem-604	524	49	with	with	ADP
eurjchem-604	524	50	m(co)6	m(co)6	NOUN
eurjchem-604	524	51	[	[	X
eurjchem-604	524	52	150	150	NUM
eurjchem-604	524	53	]	]	PUNCT
eurjchem-604	524	54	.	.	PUNCT
eurjchem-604	525	1	tetraazaadamantane	tetraazaadamantane	PROPN
eurjchem-604	525	2	(	(	PUNCT
eurjchem-604	525	3	taad	taad	ADJ
eurjchem-604	525	4	)	)	PUNCT
eurjchem-604	525	5	reacts	react	VERB
eurjchem-604	525	6	with	with	ADP
eurjchem-604	525	7	group‐vi	group‐vi	VERB
eurjchem-604	525	8	metal	metal	NOUN
eurjchem-604	525	9	hexacarbonyls	hexacarbonyls	NOUN
eurjchem-604	525	10	to	to	PART
eurjchem-604	525	11	give	give	VERB
eurjchem-604	525	12	homonuclear	homonuclear	NOUN
eurjchem-604	525	13	(	(	PUNCT
eurjchem-604	525	14	taad)m(co)5	taad)m(co)5	PROPN
eurjchem-604	525	15	(	(	PUNCT
eurjchem-604	525	16	m=	m=	X
eurjchem-604	525	17	cr	cr	PROPN
eurjchem-604	525	18	,	,	PUNCT
eurjchem-604	525	19	mo	mo	PROPN
eurjchem-604	525	20	and	and	CCONJ
eurjchem-604	525	21	w	w	NOUN
eurjchem-604	525	22	)	)	PUNCT
eurjchem-604	525	23	derivatives	derivative	NOUN
eurjchem-604	525	24	[	[	X
eurjchem-604	525	25	151	151	NUM
eurjchem-604	525	26	]	]	PUNCT
eurjchem-604	525	27	.	.	PUNCT
eurjchem-604	526	1	[	[	X
eurjchem-604	526	2	m(co)4l	m(co)4l	X
eurjchem-604	526	3	]	]	X
eurjchem-604	526	4	(	(	PUNCT
eurjchem-604	526	5	m	m	PROPN
eurjchem-604	526	6	=	=	SYM
eurjchem-604	526	7	cr	cr	PROPN
eurjchem-604	526	8	,	,	PUNCT
eurjchem-604	526	9	mo	mo	PROPN
eurjchem-604	526	10	or	or	CCONJ
eurjchem-604	526	11	w	w	NOUN
eurjchem-604	526	12	;	;	PUNCT
eurjchem-604	526	13	l	l	NOUN
eurjchem-604	526	14	=	=	SYM
eurjchem-604	526	15	1,5‐diselena‐5‐ferrocenophane	1,5‐diselena‐5‐ferrocenophane	NOUN
eurjchem-604	526	16	)	)	PUNCT
eurjchem-604	526	17	have	have	AUX
eurjchem-604	526	18	been	be	AUX
eurjchem-604	526	19	prepared	prepare	VERB
eurjchem-604	526	20	.	.	PUNCT
eurjchem-604	527	1	the	the	DET
eurjchem-604	527	2	structures	structure	NOUN
eurjchem-604	527	3	of	of	ADP
eurjchem-604	527	4	[	[	X
eurjchem-604	527	5	m(co)4l	m(co)4l	X
eurjchem-604	527	6	]	]	X
eurjchem-604	527	7	(	(	PUNCT
eurjchem-604	527	8	m	m	PROPN
eurjchem-604	527	9	=	=	SYM
eurjchem-604	527	10	cr	cr	PROPN
eurjchem-604	527	11	,	,	PUNCT
eurjchem-604	527	12	mo	mo	PROPN
eurjchem-604	527	13	)	)	PUNCT
eurjchem-604	527	14	show	show	VERB
eurjchem-604	527	15	that	that	SCONJ
eurjchem-604	527	16	l	l	NOUN
eurjchem-604	527	17	adopts	adopt	VERB
eurjchem-604	527	18	the	the	DET
eurjchem-604	527	19	unusual	unusual	ADJ
eurjchem-604	527	20	meso‐2	meso‐2	NOUN
eurjchem-604	527	21	conformation	conformation	NOUN
eurjchem-604	528	1	[	[	X
eurjchem-604	528	2	152	152	NUM
eurjchem-604	528	3	]	]	PUNCT
eurjchem-604	528	4	.	.	PUNCT
eurjchem-604	529	1	thermal	thermal	ADJ
eurjchem-604	529	2	reactions	reaction	NOUN
eurjchem-604	529	3	of	of	ADP
eurjchem-604	529	4	the	the	DET
eurjchem-604	529	5	metal	metal	NOUN
eurjchem-604	529	6	hexacarbonyls	hexacarbonyls	PROPN
eurjchem-604	529	7	m(co)6	m(co)6	PROPN
eurjchem-604	529	8	(	(	PUNCT
eurjchem-604	529	9	m	m	PROPN
eurjchem-604	529	10	=	=	SYM
eurjchem-604	529	11	cr	cr	PROPN
eurjchem-604	529	12	,	,	PUNCT
eurjchem-604	529	13	mo	mo	PROPN
eurjchem-604	529	14	but	but	CCONJ
eurjchem-604	529	15	not	not	PART
eurjchem-604	529	16	w	w	NOUN
eurjchem-604	529	17	)	)	PUNCT
eurjchem-604	529	18	with	with	ADP
eurjchem-604	529	19	tris(dimethylamino)arsine	tris(dimethylamino)arsine	NOUN
eurjchem-604	529	20	(	(	PUNCT
eurjchem-604	529	21	tdas	tda	NOUN
eurjchem-604	529	22	)	)	PUNCT
eurjchem-604	529	23	give	give	VERB
eurjchem-604	529	24	monosubstituted	monosubstitute	VERB
eurjchem-604	529	25	derivatives	derivative	NOUN
eurjchem-604	529	26	tdasm(co)5	tdasm(co)5	NOUN
eurjchem-604	529	27	(	(	PUNCT
eurjchem-604	529	28	m	m	PROPN
eurjchem-604	529	29	=	=	SYM
eurjchem-604	529	30	cr	cr	PROPN
eurjchem-604	529	31	,	,	PUNCT
eurjchem-604	529	32	mo	mo	PROPN
eurjchem-604	529	33	)	)	PUNCT
eurjchem-604	530	1	[	[	X
eurjchem-604	530	2	153	153	NUM
eurjchem-604	530	3	]	]	PUNCT
eurjchem-604	530	4	.	.	PUNCT
eurjchem-604	531	1	[	[	X
eurjchem-604	531	2	m(co)5(dttt	m(co)5(dttt	NUM
eurjchem-604	531	3	)	)	PUNCT
eurjchem-604	531	4	]	]	PUNCT
eurjchem-604	532	1	[	[	X
eurjchem-604	532	2	m	m	NOUN
eurjchem-604	532	3	=	=	ADJ
eurjchem-604	532	4	cr	cr	PROPN
eurjchem-604	532	5	;	;	PUNCT
eurjchem-604	532	6	mo	mo	PROPN
eurjchem-604	532	7	;	;	PUNCT
eurjchem-604	532	8	w	w	NOUN
eurjchem-604	532	9	]	]	PUNCT
eurjchem-604	532	10	,	,	PUNCT
eurjchem-604	532	11	have	have	AUX
eurjchem-604	532	12	been	be	AUX
eurjchem-604	532	13	synthesized	synthesize	VERB
eurjchem-604	532	14	by	by	ADP
eurjchem-604	532	15	the	the	DET
eurjchem-604	532	16	photochemical	photochemical	ADJ
eurjchem-604	532	17	reaction	reaction	NOUN
eurjchem-604	532	18	of	of	ADP
eurjchem-604	532	19	metal	metal	NOUN
eurjchem-604	532	20	carbonyls	carbonyls	NOUN
eurjchem-604	532	21	[	[	X
eurjchem-604	532	22	m(co)6	m(co)6	X
eurjchem-604	532	23	]	]	X
eurjchem-604	532	24	(	(	PUNCT
eurjchem-604	532	25	m	m	NOUN
eurjchem-604	532	26	=	=	SYM
eurjchem-604	532	27	cr	cr	PROPN
eurjchem-604	532	28	,	,	PUNCT
eurjchem-604	532	29	mo	mo	PROPN
eurjchem-604	532	30	and	and	CCONJ
eurjchem-604	532	31	w	w	PROPN
eurjchem-604	532	32	)	)	PUNCT
eurjchem-604	532	33	,	,	PUNCT
eurjchem-604	532	34	with	with	ADP
eurjchem-604	532	35	3,5‐dimethyl‐tetrahydro‐2h‐1,3,5‐thiadiazine‐2‐	3,5‐dimethyl‐tetrahydro‐2h‐1,3,5‐thiadiazine‐2‐	NUM
eurjchem-604	532	36	thione	thione	NOUN
eurjchem-604	532	37	(	(	PUNCT
eurjchem-604	532	38	dttt	dttt	PROPN
eurjchem-604	532	39	)	)	PUNCT
eurjchem-604	532	40	.	.	PUNCT
eurjchem-604	533	1	the	the	DET
eurjchem-604	533	2	spectroscopic	spectroscopic	ADJ
eurjchem-604	533	3	studies	study	NOUN
eurjchem-604	533	4	show	show	VERB
eurjchem-604	533	5	that	that	SCONJ
eurjchem-604	533	6	dttt	dttt	PROPN
eurjchem-604	533	7	behaves	behave	VERB
eurjchem-604	533	8	as	as	ADP
eurjchem-604	533	9	a	a	DET
eurjchem-604	533	10	monodentate	monodentate	ADJ
eurjchem-604	533	11	ligand	ligand	NOUN
eurjchem-604	533	12	coordinating	coordinating	NOUN
eurjchem-604	533	13	via	via	ADP
eurjchem-604	533	14	the	the	DET
eurjchem-604	533	15	sulfur	sulfur	NOUN
eurjchem-604	533	16	(	(	PUNCT
eurjchem-604	533	17	c	c	NOUN
eurjchem-604	533	18	=	=	SYM
eurjchem-604	533	19	s	s	NOUN
eurjchem-604	533	20	)	)	PUNCT
eurjchem-604	533	21	donor	donor	NOUN
eurjchem-604	533	22	atom	atom	NOUN
eurjchem-604	533	23	[	[	X
eurjchem-604	533	24	154	154	NUM
eurjchem-604	533	25	]	]	PUNCT
eurjchem-604	533	26	.	.	PUNCT
eurjchem-604	534	1	m(co)5(2‐aminoazole	m(co)5(2‐aminoazole	NOUN
eurjchem-604	534	2	)	)	PUNCT
eurjchem-604	534	3	,	,	PUNCT
eurjchem-604	534	4	where	where	SCONJ
eurjchem-604	534	5	m	m	VERB
eurjchem-604	534	6	=	=	VERB
eurjchem-604	534	7	cr	cr	PROPN
eurjchem-604	534	8	or	or	CCONJ
eurjchem-604	534	9	w	w	PROPN
eurjchem-604	534	10	,	,	PUNCT
eurjchem-604	534	11	showed	show	VERB
eurjchem-604	534	12	preferred	preferred	ADJ
eurjchem-604	534	13	endocyclic	endocyclic	ADJ
eurjchem-604	534	14	imine	imine	NOUN
eurjchem-604	534	15	coordination	coordination	NOUN
eurjchem-604	534	16	when	when	SCONJ
eurjchem-604	534	17	provided	provide	VERB
eurjchem-604	534	18	with	with	ADP
eurjchem-604	534	19	endocyclic	endocyclic	ADJ
eurjchem-604	534	20	soft	soft	ADJ
eurjchem-604	534	21	thioether	thioether	NOUN
eurjchem-604	534	22	or	or	CCONJ
eurjchem-604	534	23	endocyclic	endocyclic	ADJ
eurjchem-604	534	24	hard	hard	ADJ
eurjchem-604	534	25	amine	amine	NOUN
eurjchem-604	534	26	,	,	PUNCT
eurjchem-604	534	27	endocyclic	endocyclic	ADJ
eurjchem-604	534	28	borderline	borderline	NOUN
eurjchem-604	534	29	imine	imine	NOUN
eurjchem-604	534	30	and	and	CCONJ
eurjchem-604	534	31	exocyclic	exocyclic	ADJ
eurjchem-604	534	32	hard	hard	ADJ
eurjchem-604	534	33	amine	amine	ADJ
eurjchem-604	534	34	coordination	coordination	NOUN
eurjchem-604	534	35	sites	site	NOUN
eurjchem-604	534	36	[	[	X
eurjchem-604	534	37	155	155	NUM
eurjchem-604	534	38	]	]	PUNCT
eurjchem-604	534	39	.	.	PUNCT
eurjchem-604	535	1	the	the	DET
eurjchem-604	535	2	synthesis	synthesis	NOUN
eurjchem-604	535	3	and	and	CCONJ
eurjchem-604	535	4	spectroscopic	spectroscopic	ADJ
eurjchem-604	535	5	data	datum	NOUN
eurjchem-604	535	6	of	of	ADP
eurjchem-604	535	7	six	six	NUM
eurjchem-604	535	8	group	group	NOUN
eurjchem-604	535	9	6	6	NUM
eurjchem-604	535	10	metal	metal	NOUN
eurjchem-604	535	11	complexes	complex	NOUN
eurjchem-604	535	12	of	of	ADP
eurjchem-604	535	13	type	type	NOUN
eurjchem-604	535	14	of	of	ADP
eurjchem-604	535	15	m(p{r}{tms}2)(co)5	m(p{r}{tms}2)(co)5	PROPN
eurjchem-604	535	16	,	,	PUNCT
eurjchem-604	535	17	m	m	PROPN
eurjchem-604	535	18	=	=	SYM
eurjchem-604	535	19	cr	cr	PROPN
eurjchem-604	535	20	,	,	PUNCT
eurjchem-604	535	21	mo	mo	PROPN
eurjchem-604	535	22	,	,	PUNCT
eurjchem-604	535	23	w	w	PROPN
eurjchem-604	535	24	;	;	PUNCT
eurjchem-604	535	25	r	r	NOUN
eurjchem-604	535	26	=	=	PUNCT
eurjchem-604	535	27	c6h5	c6h5	PROPN
eurjchem-604	535	28	and	and	CCONJ
eurjchem-604	535	29	m	m	PROPN
eurjchem-604	535	30	=	=	ADJ
eurjchem-604	535	31	cr	cr	PROPN
eurjchem-604	535	32	;	;	PUNCT
eurjchem-604	535	33	r	r	NOUN
eurjchem-604	535	34	=	=	SYM
eurjchem-604	535	35	h	h	NOUN
eurjchem-604	535	36	with	with	ADP
eurjchem-604	535	37	the	the	DET
eurjchem-604	535	38	silylphosphine	silylphosphine	PROPN
eurjchem-604	535	39	ligands	ligand	NOUN
eurjchem-604	535	40	,	,	PUNCT
eurjchem-604	535	41	p(c6h5){si(ch3)3}2	p(c6h5){si(ch3)3}2	NOUN
eurjchem-604	535	42	and	and	CCONJ
eurjchem-604	535	43	p(h){si(ch3)3}2	p(h){si(ch3)3}2	NOUN
eurjchem-604	535	44	are	be	AUX
eurjchem-604	535	45	reported	report	VERB
eurjchem-604	535	46	[	[	X
eurjchem-604	535	47	156	156	NUM
eurjchem-604	535	48	]	]	PUNCT
eurjchem-604	535	49	.	.	PUNCT
eurjchem-604	536	1	photolysis	photolysis	NOUN
eurjchem-604	536	2	of	of	ADP
eurjchem-604	536	3	hexacarbonylchromium(0	hexacarbonylchromium(0	NOUN
eurjchem-604	536	4	)	)	PUNCT
eurjchem-604	536	5	in	in	ADP
eurjchem-604	536	6	the	the	DET
eurjchem-604	536	7	presence	presence	NOUN
eurjchem-604	536	8	of	of	ADP
eurjchem-604	536	9	2,6‐	2,6‐	NUM
eurjchem-604	536	10	diaminopyridine	diaminopyridine	NOUN
eurjchem-604	536	11	in	in	ADP
eurjchem-604	536	12	toluene	toluene	NOUN
eurjchem-604	536	13	solution	solution	NOUN
eurjchem-604	536	14	at	at	ADP
eurjchem-604	536	15	10	10	NUM
eurjchem-604	536	16	°	°	NOUN
eurjchem-604	536	17	c	c	NOUN
eurjchem-604	536	18	yields	yield	NOUN
eurjchem-604	536	19	pentacarbonyl(2,6‐diaminopyridine)chromium(0	pentacarbonyl(2,6‐diaminopyridine)chromium(0	NOUN
eurjchem-604	536	20	)	)	PUNCT
eurjchem-604	536	21	,	,	PUNCT
eurjchem-604	536	22	which	which	PRON
eurjchem-604	536	23	could	could	AUX
eurjchem-604	536	24	be	be	AUX
eurjchem-604	536	25	isolated	isolate	VERB
eurjchem-604	536	26	from	from	ADP
eurjchem-604	536	27	solution	solution	NOUN
eurjchem-604	536	28	as	as	ADP
eurjchem-604	536	29	plate‐like	plate‐like	ADP
eurjchem-604	536	30	crystals	crystal	NOUN
eurjchem-604	536	31	(	(	PUNCT
eurjchem-604	536	32	scheme	scheme	NOUN
eurjchem-604	536	33	34	34	NUM
eurjchem-604	536	34	)	)	PUNCT
eurjchem-604	536	35	.	.	PUNCT
eurjchem-604	537	1	the	the	DET
eurjchem-604	537	2	2,6‐diaminopyridine	2,6‐diaminopyridine	PROPN
eurjchem-604	537	3	ligand	ligand	NOUN
eurjchem-604	537	4	is	be	AUX
eurjchem-604	537	5	bonded	bond	VERB
eurjchem-604	537	6	to	to	ADP
eurjchem-604	537	7	the	the	DET
eurjchem-604	537	8	chromium	chromium	NOUN
eurjchem-604	537	9	atom	atom	NOUN
eurjchem-604	537	10	through	through	ADP
eurjchem-604	537	11	one	one	NUM
eurjchem-604	537	12	of	of	ADP
eurjchem-604	537	13	the	the	DET
eurjchem-604	537	14	nh2	nh2	NOUN
eurjchem-604	537	15	groups	group	NOUN
eurjchem-604	537	16	[	[	X
eurjchem-604	537	17	157	157	NUM
eurjchem-604	537	18	]	]	PUNCT
eurjchem-604	537	19	.	.	PUNCT
eurjchem-604	538	1	scheme	scheme	NOUN
eurjchem-604	538	2	34	34	NUM
eurjchem-604	538	3	fully	fully	ADV
eurjchem-604	538	4	alkyl	alkyl	ADJ
eurjchem-604	538	5	substituted	substitute	VERB
eurjchem-604	538	6	pyranylidene	pyranylidene	ADJ
eurjchem-604	538	7	carbene	carbene	NOUN
eurjchem-604	538	8	complexes	complex	NOUN
eurjchem-604	538	9	from	from	ADP
eurjchem-604	538	10	m(co)6	m(co)6	NUM
eurjchem-604	538	11	(	(	PUNCT
eurjchem-604	538	12	m	m	PROPN
eurjchem-604	538	13	=	=	SYM
eurjchem-604	538	14	cr	cr	PROPN
eurjchem-604	538	15	,	,	PUNCT
eurjchem-604	538	16	mo	mo	PROPN
eurjchem-604	538	17	,	,	PUNCT
eurjchem-604	538	18	w	w	PROPN
eurjchem-604	538	19	)	)	PUNCT
eurjchem-604	538	20	and	and	CCONJ
eurjchem-604	538	21	the	the	DET
eurjchem-604	538	22	readily	readily	ADV
eurjchem-604	538	23	available	available	ADJ
eurjchem-604	538	24	1‐lithio‐	1‐lithio‐	NUM
eurjchem-604	538	25	1,3‐butadiene	1,3‐butadiene	NUM
eurjchem-604	538	26	,	,	PUNCT
eurjchem-604	538	27	bearing	bear	VERB
eurjchem-604	538	28	a	a	DET
eurjchem-604	538	29	leaving	leaving	NOUN
eurjchem-604	538	30	group	group	NOUN
eurjchem-604	538	31	,	,	PUNCT
eurjchem-604	538	32	via	via	ADP
eurjchem-604	538	33	an	an	DET
eurjchem-604	538	34	intramolecular	intramolecular	ADJ
eurjchem-604	538	35	trapping	trapping	NOUN
eurjchem-604	538	36	of	of	ADP
eurjchem-604	538	37	metallaacylate	metallaacylate	ADJ
eurjchem-604	538	38	intermediates	intermediate	NOUN
eurjchem-604	538	39	.	.	PUNCT
eurjchem-604	539	1	these	these	DET
eurjchem-604	539	2	carbenes	carbene	NOUN
eurjchem-604	539	3	have	have	AUX
eurjchem-604	539	4	been	be	AUX
eurjchem-604	539	5	demonstrated	demonstrate	VERB
eurjchem-604	539	6	to	to	PART
eurjchem-604	539	7	have	have	VERB
eurjchem-604	539	8	interesting	interesting	ADJ
eurjchem-604	539	9	and	and	CCONJ
eurjchem-604	539	10	unique	unique	ADJ
eurjchem-604	539	11	reactivity	reactivity	NOUN
eurjchem-604	539	12	(	(	PUNCT
eurjchem-604	539	13	scheme	scheme	NOUN
eurjchem-604	539	14	35	35	NUM
eurjchem-604	539	15	)	)	PUNCT
eurjchem-604	540	1	[	[	X
eurjchem-604	540	2	158	158	NUM
eurjchem-604	540	3	]	]	PUNCT
eurjchem-604	540	4	.	.	PUNCT
eurjchem-604	541	1	scheme	scheme	VERB
eurjchem-604	541	2	35	35	NUM
eurjchem-604	541	3	4.1.2	4.1.2	NUM
eurjchem-604	541	4	.	.	PUNCT
eurjchem-604	541	5	bisubstituted	bisubstitute	VERB
eurjchem-604	541	6	complexes	complex	NOUN
eurjchem-604	541	7	[	[	X
eurjchem-604	541	8	m(co)4l2	m(co)4l2	PROPN
eurjchem-604	541	9	]	]	PUNCT
eurjchem-604	541	10	tungsten(0	tungsten(0	PROPN
eurjchem-604	541	11	)	)	PUNCT
eurjchem-604	541	12	carbonyl	carbonyl	NOUN
eurjchem-604	541	13	complexes	complex	NOUN
eurjchem-604	541	14	with	with	ADP
eurjchem-604	541	15	1‐(diphenyl‐	1‐(diphenyl‐	PROPN
eurjchem-604	541	16	phosphanyl)‐1′‐vinylferrocene	phosphanyl)‐1′‐vinylferrocene	PROPN
eurjchem-604	541	17	(	(	PUNCT
eurjchem-604	541	18	scheme	scheme	NOUN
eurjchem-604	541	19	36	36	NUM
eurjchem-604	541	20	(	(	PUNCT
eurjchem-604	541	21	a	a	NOUN
eurjchem-604	541	22	)	)	PUNCT
eurjchem-604	541	23	)	)	PUNCT
eurjchem-604	541	24	and	and	CCONJ
eurjchem-604	541	25	1‐	1‐	NUM
eurjchem-604	541	26	(	(	PUNCT
eurjchem-604	541	27	diphenylphosphanyl)‐1′‐(dimethylvinylsilyl)ferrocene	diphenylphosphanyl)‐1′‐(dimethylvinylsilyl)ferrocene	NOUN
eurjchem-604	541	28	(	(	PUNCT
eurjchem-604	541	29	scheme	scheme	NOUN
eurjchem-604	541	30	36	36	NUM
eurjchem-604	541	31	(	(	PUNCT
eurjchem-604	541	32	b	b	NOUN
eurjchem-604	541	33	)	)	PUNCT
eurjchem-604	541	34	)	)	PUNCT
eurjchem-604	541	35	as	as	ADP
eurjchem-604	541	36	p‐monodentate	p‐monodentate	PUNCT
eurjchem-604	541	37	donors	donor	NOUN
eurjchem-604	541	38	,	,	PUNCT
eurjchem-604	541	39	[	[	X
eurjchem-604	541	40	w(co)4(l‐κp)2	w(co)4(l‐κp)2	NOUN
eurjchem-604	541	41	]	]	X
eurjchem-604	541	42	,	,	PUNCT
eurjchem-604	541	43	have	have	AUX
eurjchem-604	541	44	been	be	AUX
eurjchem-604	541	45	prepared	prepare	VERB
eurjchem-604	541	46	[	[	PUNCT
eurjchem-604	541	47	159	159	NUM
eurjchem-604	541	48	]	]	PUNCT
eurjchem-604	541	49	.	.	PUNCT
eurjchem-604	542	1	scheme	scheme	VERB
eurjchem-604	542	2	36	36	NUM
eurjchem-604	542	3	a	a	DET
eurjchem-604	542	4	series	series	NOUN
eurjchem-604	542	5	of	of	ADP
eurjchem-604	542	6	germylene	germylene	NOUN
eurjchem-604	542	7	and	and	CCONJ
eurjchem-604	542	8	stannylene	stannylene	NOUN
eurjchem-604	542	9	(	(	PUNCT
eurjchem-604	542	10	me2nch2ch2o)2e	me2nch2ch2o)2e	NOUN
eurjchem-604	542	11	(	(	PUNCT
eurjchem-604	542	12	e	e	NOUN
eurjchem-604	542	13	=	=	PROPN
eurjchem-604	542	14	ge	ge	PROPN
eurjchem-604	542	15	,	,	PUNCT
eurjchem-604	542	16	e	e	PROPN
eurjchem-604	542	17	=	=	SYM
eurjchem-604	542	18	sn	sn	PROPN
eurjchem-604	542	19	)	)	PUNCT
eurjchem-604	542	20	complexes	complex	NOUN
eurjchem-604	542	21	of	of	ADP
eurjchem-604	542	22	group	group	NOUN
eurjchem-604	542	23	6	6	NUM
eurjchem-604	542	24	metals	metal	NOUN
eurjchem-604	542	25	carbonyls	carbonyls	X
eurjchem-604	542	26	l·m(co)n	l·m(co)n	X
eurjchem-604	542	27	(	(	PUNCT
eurjchem-604	542	28	m	m	PROPN
eurjchem-604	542	29	=	=	SYM
eurjchem-604	542	30	cr	cr	PROPN
eurjchem-604	542	31	,	,	PUNCT
eurjchem-604	542	32	mo	mo	PROPN
eurjchem-604	542	33	,	,	PUNCT
eurjchem-604	542	34	w	w	PROPN
eurjchem-604	542	35	,	,	PUNCT
eurjchem-604	542	36	n	n	NOUN
eurjchem-604	542	37	=	=	SYM
eurjchem-604	542	38	5	5	NUM
eurjchem-604	542	39	or	or	CCONJ
eurjchem-604	542	40	4	4	NUM
eurjchem-604	542	41	)	)	PUNCT
eurjchem-604	542	42	were	be	AUX
eurjchem-604	542	43	prepared	prepare	VERB
eurjchem-604	542	44	[	[	X
eurjchem-604	542	45	160	160	NUM
eurjchem-604	542	46	]	]	PUNCT
eurjchem-604	542	47	.	.	PUNCT
eurjchem-604	543	1	the	the	DET
eurjchem-604	543	2	pentacarbonyl(η2‐bis(trimethylsilyl)ethyne)tungsten(0	pentacarbonyl(η2‐bis(trimethylsilyl)ethyne)tungsten(0	NOUN
eurjchem-604	543	3	)	)	PUNCT
eurjchem-604	543	4	,	,	PUNCT
eurjchem-604	543	5	w(co)5(η2‐btmse	w(co)5(η2‐btmse	PROPN
eurjchem-604	543	6	)	)	PUNCT
eurjchem-604	543	7	,	,	PUNCT
eurjchem-604	543	8	reacts	react	VERB
eurjchem-604	543	9	with	with	ADP
eurjchem-604	543	10	tricyclohexylphosphine	tricyclohexylphosphine	NOUN
eurjchem-604	543	11	,	,	PUNCT
eurjchem-604	543	12	pcy3	pcy3	PROPN
eurjchem-604	543	13	,	,	PUNCT
eurjchem-604	543	14	to	to	PART
eurjchem-604	543	15	yield	yield	VERB
eurjchem-604	543	16	w(co)5(pcy3	w(co)5(pcy3	PROPN
eurjchem-604	543	17	)	)	PUNCT
eurjchem-604	543	18	and	and	CCONJ
eurjchem-604	543	19	w(co)4(pcy3)2	w(co)4(pcy3)2	PROPN
eurjchem-604	543	20	.	.	PUNCT
eurjchem-604	544	1	the	the	DET
eurjchem-604	544	2	former	former	ADJ
eurjchem-604	544	3	complex	complex	NOUN
eurjchem-604	544	4	is	be	AUX
eurjchem-604	544	5	the	the	DET
eurjchem-604	544	6	alkyne	alkyne	ADJ
eurjchem-604	544	7	substitution	substitution	NOUN
eurjchem-604	544	8	product	product	NOUN
eurjchem-604	544	9	,	,	PUNCT
eurjchem-604	544	10	while	while	SCONJ
eurjchem-604	544	11	the	the	DET
eurjchem-604	544	12	latter	latter	ADJ
eurjchem-604	544	13	one	one	NOUN
eurjchem-604	544	14	is	be	AUX
eurjchem-604	544	15	formed	form	VERB
eurjchem-604	544	16	from	from	ADP
eurjchem-604	544	17	the	the	DET
eurjchem-604	544	18	conversion	conversion	NOUN
eurjchem-604	544	19	of	of	ADP
eurjchem-604	544	20	its	its	PRON
eurjchem-604	544	21	labile	labile	ADJ
eurjchem-604	544	22	cis‐isomer	cis‐isomer	PROPN
eurjchem-604	544	23	,	,	PUNCT
eurjchem-604	544	24	which	which	PRON
eurjchem-604	544	25	is	be	AUX
eurjchem-604	544	26	generated	generate	VERB
eurjchem-604	544	27	by	by	ADP
eurjchem-604	544	28	further	further	ADJ
eurjchem-604	544	29	reaction	reaction	NOUN
eurjchem-604	544	30	of	of	ADP
eurjchem-604	544	31	the	the	DET
eurjchem-604	544	32	co	co	NOUN
eurjchem-604	544	33	substitution	substitution	NOUN
eurjchem-604	544	34	product	product	NOUN
eurjchem-604	544	35	,	,	PUNCT
eurjchem-604	544	36	cis‐	cis‐	PROPN
eurjchem-604	544	37	w(co)4(η2‐btmse)(pcy3	w(co)4(η2‐btmse)(pcy3	PROPN
eurjchem-604	544	38	)	)	PUNCT
eurjchem-604	544	39	,	,	PUNCT
eurjchem-604	544	40	with	with	ADP
eurjchem-604	544	41	a	a	DET
eurjchem-604	544	42	second	second	ADJ
eurjchem-604	544	43	pcy3	pcy3	NOUN
eurjchem-604	544	44	molecule	molecule	NOUN
eurjchem-604	544	45	(	(	PUNCT
eurjchem-604	544	46	scheme	scheme	NOUN
eurjchem-604	544	47	37	37	NUM
eurjchem-604	544	48	)	)	PUNCT
eurjchem-604	545	1	[	[	X
eurjchem-604	545	2	161	161	NUM
eurjchem-604	545	3	]	]	PUNCT
eurjchem-604	545	4	.	.	PUNCT
eurjchem-604	546	1	scheme	scheme	NOUN
eurjchem-604	546	2	37	37	NUM
eurjchem-604	546	3	in	in	ADP
eurjchem-604	546	4	trans‐	trans‐	PROPN
eurjchem-604	547	1	[	[	X
eurjchem-604	547	2	mo(co)4(pph3)2	mo(co)4(pph3)2	X
eurjchem-604	547	3	]	]	X
eurjchem-604	547	4	,	,	PUNCT
eurjchem-604	547	5	little	little	ADJ
eurjchem-604	547	6	deviation	deviation	NOUN
eurjchem-604	547	7	from	from	ADP
eurjchem-604	547	8	ideal	ideal	ADJ
eurjchem-604	547	9	octahedral	octahedral	ADJ
eurjchem-604	547	10	geometry	geometry	NOUN
eurjchem-604	547	11	is	be	AUX
eurjchem-604	547	12	seen	see	VERB
eurjchem-604	547	13	and	and	CCONJ
eurjchem-604	547	14	the	the	DET
eurjchem-604	547	15	mo‐‐‐p	mo‐‐‐p	ADJ
eurjchem-604	547	16	bond	bond	NOUN
eurjchem-604	547	17	length	length	NOUN
eurjchem-604	547	18	of	of	ADP
eurjchem-604	547	19	2	2	NUM
eurjchem-604	547	20	.	.	PUNCT
eurjchem-604	548	1	500(1	500(1	NUM
eurjchem-604	548	2	)	)	PUNCT
eurjchem-604	548	3	å	å	PROPN
eurjchem-604	548	4	is	be	AUX
eurjchem-604	548	5	significantly	significantly	ADV
eurjchem-604	548	6	shorter	short	ADJ
eurjchem-604	548	7	than	than	ADP
eurjchem-604	548	8	those	those	PRON
eurjchem-604	548	9	found	find	VERB
eurjchem-604	548	10	in	in	ADP
eurjchem-604	548	11	the	the	DET
eurjchem-604	548	12	cis	cis	NOUN
eurjchem-604	548	13	isomer	isomer	NOUN
eurjchem-604	549	1	[	[	X
eurjchem-604	549	2	162	162	NUM
eurjchem-604	549	3	]	]	PUNCT
eurjchem-604	549	4	.	.	PUNCT
eurjchem-604	550	1	reaction	reaction	NOUN
eurjchem-604	550	2	of	of	ADP
eurjchem-604	550	3	norbornadiene	norbornadiene	ADJ
eurjchem-604	550	4	complex	complex	NOUN
eurjchem-604	550	5	c7h8cr(co)4	c7h8cr(co)4	X
eurjchem-604	550	6	with	with	ADP
eurjchem-604	550	7	tris(dimethylamino)arsine	tris(dimethylamino)arsine	NOUN
eurjchem-604	550	8	(	(	PUNCT
eurjchem-604	550	9	tdas	tda	NOUN
eurjchem-604	550	10	)	)	PUNCT
eurjchem-604	550	11	at	at	ADP
eurjchem-604	550	12	room	room	NOUN
eurjchem-604	550	13	temperature	temperature	NOUN
eurjchem-604	550	14	gives	give	VERB
eurjchem-604	550	15	trans‐(tdas)2cr(co)4	trans‐(tdas)2cr(co)4	PRON
eurjchem-604	550	16	which	which	PRON
eurjchem-604	550	17	was	be	AUX
eurjchem-604	550	18	isolated	isolate	VERB
eurjchem-604	550	19	as	as	ADP
eurjchem-604	550	20	yellow	yellow	ADJ
eurjchem-604	550	21	complex	complex	NOUN
eurjchem-604	550	22	.	.	PUNCT
eurjchem-604	551	1	reactions	reaction	NOUN
eurjchem-604	551	2	of	of	ADP
eurjchem-604	551	3	disubstituted	disubstitute	VERB
eurjchem-604	551	4	derivatives	derivative	NOUN
eurjchem-604	551	5	trans‐	trans‐	VERB
eurjchem-604	551	6	(	(	PUNCT
eurjchem-604	551	7	tdas)2cr(co)4	tdas)2cr(co)4	X
eurjchem-604	551	8	with	with	ADP
eurjchem-604	551	9	carbonmonoxide	carbonmonoxide	NOUN
eurjchem-604	551	10	at	at	ADP
eurjchem-604	551	11	room	room	NOUN
eurjchem-604	551	12	temperature	temperature	NOUN
eurjchem-604	551	13	and	and	CCONJ
eurjchem-604	551	14	pressure	pressure	NOUN
eurjchem-604	551	15	gives	give	VERB
eurjchem-604	551	16	monosubstituted	monosubstitute	VERB
eurjchem-604	551	17	derivatives	derivative	NOUN
eurjchem-604	551	18	(	(	PUNCT
eurjchem-604	551	19	tdas)cr(co)5	tdas)cr(co)5	X
eurjchem-604	552	1	[	[	X
eurjchem-604	552	2	63	63	NUM
eurjchem-604	552	3	]	]	PUNCT
eurjchem-604	552	4	.	.	PUNCT
eurjchem-604	553	1	4.1.3	4.1.3	X
eurjchem-604	553	2	.	.	PUNCT
eurjchem-604	553	3	trisubstituted	trisubstitute	VERB
eurjchem-604	553	4	complexes	complex	NOUN
eurjchem-604	554	1	[	[	X
eurjchem-604	554	2	m(co)3l3	m(co)3l3	X
eurjchem-604	554	3	]	]	X
eurjchem-604	554	4	the	the	DET
eurjchem-604	554	5	trisubstituted	trisubstituted	ADJ
eurjchem-604	554	6	metalcarbonyl	metalcarbonyl	NOUN
eurjchem-604	554	7	complexes	complex	NOUN
eurjchem-604	554	8	containing	contain	VERB
eurjchem-604	554	9	ligands	ligand	NOUN
eurjchem-604	554	10	which	which	PRON
eurjchem-604	554	11	coordinate	coordinate	VERB
eurjchem-604	554	12	through	through	ADP
eurjchem-604	554	13	bicovalent	bicovalent	NOUN
eurjchem-604	554	14	sulfur	sulfur	NOUN
eurjchem-604	554	15	are	be	AUX
eurjchem-604	554	16	reported	report	VERB
eurjchem-604	554	17	.	.	PUNCT
eurjchem-604	555	1	direct	direct	ADJ
eurjchem-604	555	2	reaction	reaction	NOUN
eurjchem-604	555	3	of	of	ADP
eurjchem-604	555	4	the	the	DET
eurjchem-604	555	5	ligands	ligand	NOUN
eurjchem-604	555	6	with	with	ADP
eurjchem-604	555	7	cycloheptatrienemolybdenumtricarbonyl	cycloheptatrienemolybdenumtricarbonyl	NOUN
eurjchem-604	555	8	,	,	PUNCT
eurjchem-604	555	9	mo(co)3l3	mo(co)3l3	PROPN
eurjchem-604	555	10	were	be	AUX
eurjchem-604	555	11	prepared	prepare	VERB
eurjchem-604	555	12	where	where	SCONJ
eurjchem-604	555	13	l	l	NOUN
eurjchem-604	555	14	representing	represent	VERB
eurjchem-604	555	15	dimethyl	dimethyl	NOUN
eurjchem-604	555	16	sulfide	sulfide	NOUN
eurjchem-604	555	17	[	[	X
eurjchem-604	555	18	(	(	PUNCT
eurjchem-604	555	19	ch3)2s	ch3)2s	PROPN
eurjchem-604	555	20	]	]	PUNCT
eurjchem-604	555	21	,	,	PUNCT
eurjchem-604	555	22	diethyl	diethyl	NOUN
eurjchem-604	555	23	sulfide	sulfide	NOUN
eurjchem-604	555	24	[	[	X
eurjchem-604	555	25	(	(	PUNCT
eurjchem-604	555	26	c2h5)2s	c2h5)2s	X
eurjchem-604	555	27	]	]	X
eurjchem-604	555	28	,	,	PUNCT
eurjchem-604	555	29	thiourea	thiourea	NOUN
eurjchem-604	556	1	[	[	X
eurjchem-604	556	2	(	(	PUNCT
eurjchem-604	556	3	ch2)2cs	ch2)2cs	NOUN
eurjchem-604	556	4	]	]	X
eurjchem-604	556	5	,	,	PUNCT
eurjchem-604	556	6	thioacetamide	thioacetamide	ADJ
eurjchem-604	556	7	[	[	X
eurjchem-604	556	8	ch2csnh2	ch2csnh2	X
eurjchem-604	556	9	]	]	X
eurjchem-604	556	10	.	.	PUNCT
eurjchem-604	557	1	the	the	DET
eurjchem-604	557	2	thiourea	thiourea	NOUN
eurjchem-604	557	3	and	and	CCONJ
eurjchem-604	557	4	thioacetamide	thioacetamide	ADJ
eurjchem-604	557	5	compounds	compound	NOUN
eurjchem-604	557	6	are	be	AUX
eurjchem-604	557	7	stable	stable	ADJ
eurjchem-604	557	8	for	for	ADP
eurjchem-604	557	9	periods	period	NOUN
eurjchem-604	557	10	of	of	ADP
eurjchem-604	557	11	atleast	atleast	NOUN
eurjchem-604	557	12	a	a	DET
eurjchem-604	557	13	year	year	NOUN
eurjchem-604	557	14	in	in	ADP
eurjchem-604	557	15	vacuum	vacuum	NOUN
eurjchem-604	557	16	and	and	CCONJ
eurjchem-604	557	17	for	for	ADP
eurjchem-604	557	18	a	a	DET
eurjchem-604	557	19	week	week	NOUN
eurjchem-604	557	20	or	or	CCONJ
eurjchem-604	557	21	move	move	VERB
eurjchem-604	557	22	in	in	ADP
eurjchem-604	557	23	the	the	DET
eurjchem-604	557	24	air	air	NOUN
eurjchem-604	557	25	under	under	ADP
eurjchem-604	557	26	normal	normal	ADJ
eurjchem-604	557	27	laboratory	laboratory	NOUN
eurjchem-604	557	28	condictions	condiction	NOUN
eurjchem-604	557	29	.	.	PUNCT
eurjchem-604	558	1	the	the	DET
eurjchem-604	558	2	diethylcomplexes	diethylcomplexe	NOUN
eurjchem-604	558	3	are	be	AUX
eurjchem-604	558	4	stable	stable	ADJ
eurjchem-604	558	5	for	for	ADP
eurjchem-604	558	6	at	at	ADV
eurjchem-604	558	7	least	least	ADJ
eurjchem-604	558	8	a	a	DET
eurjchem-604	558	9	few	few	ADJ
eurjchem-604	558	10	weeks	week	NOUN
eurjchem-604	558	11	in	in	ADP
eurjchem-604	558	12	vacuum	vacuum	NOUN
eurjchem-604	558	13	but	but	CCONJ
eurjchem-604	558	14	decompose	decompose	NOUN
eurjchem-604	558	15	within	within	ADP
eurjchem-604	558	16	a	a	DET
eurjchem-604	558	17	few	few	ADJ
eurjchem-604	558	18	hours	hour	NOUN
eurjchem-604	558	19	in	in	ADP
eurjchem-604	558	20	air	air	NOUN
eurjchem-604	558	21	.	.	PUNCT
eurjchem-604	559	1	the	the	DET
eurjchem-604	559	2	dimethyl	dimethyl	NOUN
eurjchem-604	559	3	sulfide	sulfide	NOUN
eurjchem-604	559	4	compounds	compound	NOUN
eurjchem-604	559	5	is	be	AUX
eurjchem-604	559	6	immediately	immediately	ADV
eurjchem-604	559	7	decomposed	decompose	VERB
eurjchem-604	559	8	by	by	ADP
eurjchem-604	559	9	air	air	NOUN
eurjchem-604	559	10	and	and	CCONJ
eurjchem-604	559	11	is	be	AUX
eurjchem-604	559	12	stable	stable	ADJ
eurjchem-604	559	13	for	for	ADP
eurjchem-604	559	14	few	few	ADJ
eurjchem-604	559	15	hours	hour	NOUN
eurjchem-604	559	16	under	under	ADP
eurjchem-604	559	17	vacuum	vacuum	NOUN
eurjchem-604	559	18	[	[	X
eurjchem-604	559	19	126	126	NUM
eurjchem-604	559	20	]	]	PUNCT
eurjchem-604	559	21	.	.	PUNCT
eurjchem-604	560	1	4.2	4.2	NUM
eurjchem-604	560	2	.	.	PUNCT
eurjchem-604	560	3	metal	metal	NOUN
eurjchem-604	560	4	carbonyl	carbonyl	NOUN
eurjchem-604	560	5	complexes	complex	NOUN
eurjchem-604	560	6	with	with	ADP
eurjchem-604	560	7	bidentate	bidentate	NOUN
eurjchem-604	560	8	ligands	ligand	NOUN
eurjchem-604	560	9	the	the	DET
eurjchem-604	560	10	metal	metal	NOUN
eurjchem-604	560	11	carbonyl	carbonyl	NOUN
eurjchem-604	560	12	complexes	complex	NOUN
eurjchem-604	560	13	with	with	ADP
eurjchem-604	560	14	bidentate	bidentate	ADJ
eurjchem-604	560	15	ligands	ligand	NOUN
eurjchem-604	560	16	are	be	AUX
eurjchem-604	560	17	variety	variety	NOUN
eurjchem-604	560	18	of	of	ADP
eurjchem-604	560	19	homo‐	homo‐	PROPN
eurjchem-604	560	20	and	and	CCONJ
eurjchem-604	560	21	bimetallic	bimetallic	ADJ
eurjchem-604	560	22	metal	metal	NOUN
eurjchem-604	560	23	carbonyl	carbonyl	NOUN
eurjchem-604	560	24	compounds	compound	NOUN
eurjchem-604	560	25	(	(	PUNCT
eurjchem-604	560	26	scheme38	scheme38	ADJ
eurjchem-604	560	27	)	)	PUNCT
eurjchem-604	560	28	.	.	PUNCT
eurjchem-604	561	1	amandaet	amandaet	PROPN
eurjchem-604	561	2	al	al	PROPN
eurjchem-604	561	3	.	.	PROPN
eurjchem-604	561	4	investigated	investigate	VERB
eurjchem-604	561	5	metal	metal	NOUN
eurjchem-604	561	6	carbonyl	carbonyl	NOUN
eurjchem-604	561	7	retracted	retract	VERB
eurjchem-604	561	8	380	380	NUM
eurjchem-604	561	9	kaushik	kaushik	NOUN
eurjchem-604	561	10	et	et	PROPN
eurjchem-604	561	11	al	al	PROPN
eurjchem-604	561	12	.	.	PUNCT
eurjchem-604	561	13	/	/	SYM
eurjchem-604	561	14	european	european	PROPN
eurjchem-604	561	15	journal	journal	PROPN
eurjchem-604	561	16	of	of	ADP
eurjchem-604	561	17	chemistry	chemistry	NOUN
eurjchem-604	561	18	3	3	NUM
eurjchem-604	561	19	(	(	PUNCT
eurjchem-604	561	20	3	3	NUM
eurjchem-604	561	21	)	)	PUNCT
eurjchem-604	561	22	(	(	PUNCT
eurjchem-604	561	23	2012	2012	NUM
eurjchem-604	561	24	)	)	PUNCT
eurjchem-604	561	25	367‐394	367‐394	NOUN
eurjchem-604	561	26	complexes	complex	NOUN
eurjchem-604	561	27	containing	contain	VERB
eurjchem-604	561	28	1,1‘‐bis(diphenylphosphino)ferrocene	1,1‘‐bis(diphenylphosphino)ferrocene	NUM
eurjchem-604	561	29	(	(	PUNCT
eurjchem-604	561	30	dppf	dppf	NOUN
eurjchem-604	561	31	)	)	PUNCT
eurjchem-604	561	32	with	with	ADP
eurjchem-604	561	33	the	the	DET
eurjchem-604	561	34	general	general	ADJ
eurjchem-604	561	35	formulas	formula	NOUN
eurjchem-604	561	36	m(co)5(dppf	m(co)5(dppf	NOUN
eurjchem-604	561	37	)	)	PUNCT
eurjchem-604	561	38	(	(	PUNCT
eurjchem-604	561	39	1a−c	1a−c	NUM
eurjchem-604	561	40	)	)	PUNCT
eurjchem-604	561	41	,	,	PUNCT
eurjchem-604	561	42	m(co)4(dppf	m(co)4(dppf	NOUN
eurjchem-604	561	43	)	)	PUNCT
eurjchem-604	561	44	(	(	PUNCT
eurjchem-604	561	45	2a−c	2a−c	NUM
eurjchem-604	561	46	)	)	PUNCT
eurjchem-604	561	47	,	,	PUNCT
eurjchem-604	561	48	and	and	CCONJ
eurjchem-604	561	49	(	(	PUNCT
eurjchem-604	561	50	co)5m(dppf)m‘(co)5	co)5m(dppf)m‘(co)5	PROPN
eurjchem-604	561	51	(	(	PUNCT
eurjchem-604	561	52	3a−f	3a−f	PROPN
eurjchem-604	561	53	)	)	PUNCT
eurjchem-604	561	54	(	(	PUNCT
eurjchem-604	561	55	m	m	PROPN
eurjchem-604	561	56	,	,	PUNCT
eurjchem-604	561	57	m	m	PRON
eurjchem-604	561	58	‘	'	PUNCT
eurjchem-604	561	59	=	=	SYM
eurjchem-604	561	60	cr	cr	PROPN
eurjchem-604	561	61	,	,	PUNCT
eurjchem-604	561	62	mo	mo	PROPN
eurjchem-604	561	63	,	,	PUNCT
eurjchem-604	561	64	w	w	PROPN
eurjchem-604	561	65	)	)	PUNCT
eurjchem-604	562	1	[	[	X
eurjchem-604	562	2	163	163	NUM
eurjchem-604	562	3	]	]	PUNCT
eurjchem-604	562	4	.	.	PUNCT
eurjchem-604	563	1	scheme	scheme	VERB
eurjchem-604	563	2	38	38	NUM
eurjchem-604	563	3	4.2.1	4.2.1	NUM
eurjchem-604	563	4	.	.	PUNCT
eurjchem-604	564	1	mononuclear	mononuclear	ADJ
eurjchem-604	564	2	complexes	complex	NOUN
eurjchem-604	564	3	[	[	X
eurjchem-604	564	4	m(co)4l	m(co)4l	X
eurjchem-604	564	5	]	]	X
eurjchem-604	564	6	interaction	interaction	NOUN
eurjchem-604	564	7	of	of	ADP
eurjchem-604	564	8	1‐(2‐pyridylazo)‐2‐naphthol	1‐(2‐pyridylazo)‐2‐naphthol	NUM
eurjchem-604	564	9	(	(	PUNCT
eurjchem-604	564	10	pan	pan	NOUN
eurjchem-604	564	11	)	)	PUNCT
eurjchem-604	564	12	with	with	ADP
eurjchem-604	564	13	[	[	X
eurjchem-604	564	14	mo(co)6	mo(co)6	X
eurjchem-604	564	15	]	]	PUNCT
eurjchem-604	564	16	in	in	ADP
eurjchem-604	564	17	air	air	NOUN
eurjchem-604	564	18	resulted	result	VERB
eurjchem-604	564	19	in	in	ADP
eurjchem-604	564	20	formation	formation	NOUN
eurjchem-604	564	21	of	of	ADP
eurjchem-604	564	22	the	the	DET
eurjchem-604	564	23	tricarbonyl	tricarbonyl	NOUN
eurjchem-604	564	24	oxo‐	oxo‐	NOUN
eurjchem-604	564	25	complex	complex	ADJ
eurjchem-604	564	26	[	[	X
eurjchem-604	564	27	mo(o)(co)3(pan	mo(o)(co)3(pan	NOUN
eurjchem-604	564	28	)	)	PUNCT
eurjchem-604	564	29	]	]	PUNCT
eurjchem-604	565	1	(	(	PUNCT
eurjchem-604	565	2	scheme	scheme	NOUN
eurjchem-604	565	3	39(a	39(a	PROPN
eurjchem-604	565	4	)	)	PUNCT
eurjchem-604	565	5	)	)	PUNCT
eurjchem-604	565	6	.	.	PUNCT
eurjchem-604	566	1	in	in	ADP
eurjchem-604	566	2	presence	presence	NOUN
eurjchem-604	566	3	of	of	ADP
eurjchem-604	566	4	triphenyl	triphenyl	ADJ
eurjchem-604	566	5	phosphine	phosphine	NOUN
eurjchem-604	566	6	(	(	PUNCT
eurjchem-604	566	7	pph3	pph3	PROPN
eurjchem-604	566	8	)	)	PUNCT
eurjchem-604	566	9	,	,	PUNCT
eurjchem-604	566	10	the	the	DET
eurjchem-604	566	11	reaction	reaction	NOUN
eurjchem-604	566	12	of	of	ADP
eurjchem-604	566	13	pan	pan	NOUN
eurjchem-604	566	14	with	with	ADP
eurjchem-604	566	15	either	either	CCONJ
eurjchem-604	566	16	mo(co)6	mo(co)6	PROPN
eurjchem-604	566	17	or	or	CCONJ
eurjchem-604	566	18	ru3(co)12	ru3(co)12	AUX
eurjchem-604	566	19	gave	give	VERB
eurjchem-604	566	20	[	[	PRON
eurjchem-604	566	21	mo(co)3(pan)(pph3	mo(co)3(pan)(pph3	NOUN
eurjchem-604	566	22	)	)	PUNCT
eurjchem-604	566	23	]	]	PUNCT
eurjchem-604	567	1	(	(	PUNCT
eurjchem-604	567	2	scheme	scheme	NOUN
eurjchem-604	567	3	39(b	39(b	NUM
eurjchem-604	567	4	)	)	PUNCT
eurjchem-604	567	5	)	)	PUNCT
eurjchem-604	567	6	,	,	PUNCT
eurjchem-604	567	7	and	and	CCONJ
eurjchem-604	567	8	[	[	X
eurjchem-604	567	9	ru(co)2(pan)(pph3	ru(co)2(pan)(pph3	X
eurjchem-604	567	10	)	)	PUNCT
eurjchem-604	567	11	]	]	PUNCT
eurjchem-604	567	12	.	.	PUNCT
eurjchem-604	568	1	taher	taher	PROPN
eurjchem-604	568	2	et	et	PROPN
eurjchem-604	568	3	al	al	PROPN
eurjchem-604	568	4	.	.	PROPN
eurjchem-604	568	5	reported	report	VERB
eurjchem-604	568	6	that	that	SCONJ
eurjchem-604	568	7	pan	pan	NOUN
eurjchem-604	568	8	behaves	behave	VERB
eurjchem-604	568	9	as	as	ADP
eurjchem-604	568	10	a	a	DET
eurjchem-604	568	11	bidentate	bidentate	ADJ
eurjchem-604	568	12	ligand	ligand	NOUN
eurjchem-604	568	13	coordinating	coordinating	NOUN
eurjchem-604	568	14	via	via	ADP
eurjchem-604	568	15	the	the	DET
eurjchem-604	568	16	two	two	NUM
eurjchem-604	568	17	n	n	CCONJ
eurjchem-604	568	18	donor	donor	NOUN
eurjchem-604	568	19	atom	atom	NOUN
eurjchem-604	569	1	[	[	X
eurjchem-604	569	2	164	164	NUM
eurjchem-604	569	3	]	]	PUNCT
eurjchem-604	569	4	.	.	PUNCT
eurjchem-604	570	1	scheme	scheme	VERB
eurjchem-604	570	2	39	39	NUM
eurjchem-604	570	3	the	the	DET
eurjchem-604	570	4	ability	ability	NOUN
eurjchem-604	570	5	of	of	ADP
eurjchem-604	570	6	the	the	DET
eurjchem-604	570	7	dithiafulvenylphosphine	dithiafulvenylphosphine	ADJ
eurjchem-604	570	8	(	(	PUNCT
eurjchem-604	570	9	p‐dtf	p‐dtf	NOUN
eurjchem-604	570	10	)	)	PUNCT
eurjchem-604	570	11	to	to	PART
eurjchem-604	570	12	react	react	VERB
eurjchem-604	570	13	as	as	ADP
eurjchem-604	570	14	a	a	PRON
eurjchem-604	570	15	monodentate	monodentate	NOUN
eurjchem-604	570	16	(	(	PUNCT
eurjchem-604	570	17	p	p	NOUN
eurjchem-604	570	18	)	)	PUNCT
eurjchem-604	570	19	or	or	CCONJ
eurjchem-604	570	20	a	a	DET
eurjchem-604	570	21	bidentate	bidentate	NOUN
eurjchem-604	570	22	(	(	PUNCT
eurjchem-604	570	23	p	p	X
eurjchem-604	570	24	,	,	PUNCT
eurjchem-604	570	25	s	s	NOUN
eurjchem-604	570	26	)	)	PUNCT
eurjchem-604	570	27	ligand	ligand	NOUN
eurjchem-604	570	28	with	with	ADP
eurjchem-604	570	29	metal	metal	NOUN
eurjchem-604	570	30	carbonylcomplexes	carbonylcomplexe	NOUN
eurjchem-604	570	31	such	such	ADJ
eurjchem-604	570	32	as	as	ADP
eurjchem-604	570	33	mo(co)6	mo(co)6	NOUN
eurjchem-604	570	34	and	and	CCONJ
eurjchem-604	570	35	mnbr(co)5	mnbr(co)5	PROPN
eurjchem-604	570	36	was	be	AUX
eurjchem-604	570	37	investigated	investigate	VERB
eurjchem-604	570	38	(	(	PUNCT
eurjchem-604	570	39	scheme	scheme	NOUN
eurjchem-604	570	40	40	40	NUM
eurjchem-604	570	41	)	)	PUNCT
eurjchem-604	571	1	[	[	X
eurjchem-604	571	2	165	165	NUM
eurjchem-604	571	3	]	]	PUNCT
eurjchem-604	571	4	.	.	PUNCT
eurjchem-604	572	1	the	the	DET
eurjchem-604	572	2	reaction	reaction	NOUN
eurjchem-604	572	3	of	of	ADP
eurjchem-604	572	4	bis(3,5‐dimethyl‐1,2,4‐triazol‐1‐	bis(3,5‐dimethyl‐1,2,4‐triazol‐1‐	PROPN
eurjchem-604	572	5	yl)methane	yl)methane	PROPN
eurjchem-604	572	6	,	,	PUNCT
eurjchem-604	572	7	ch2(3,5‐me2tz)2	ch2(3,5‐me2tz)2	PROPN
eurjchem-604	572	8	,	,	PUNCT
eurjchem-604	572	9	with	with	ADP
eurjchem-604	572	10	m(co)6	m(co)6	NUM
eurjchem-604	572	11	(	(	PUNCT
eurjchem-604	572	12	m	m	NOUN
eurjchem-604	572	13	=	=	NOUN
eurjchem-604	572	14	cr	cr	PROPN
eurjchem-604	572	15	,	,	PUNCT
eurjchem-604	572	16	mo	mo	NOUN
eurjchem-604	572	17	or	or	CCONJ
eurjchem-604	572	18	w	w	NOUN
eurjchem-604	572	19	)	)	PUNCT
eurjchem-604	572	20	in	in	ADP
eurjchem-604	572	21	refluxing	refluxing	NOUN
eurjchem-604	572	22	dme	dme	PROPN
eurjchem-604	572	23	produces	produce	VERB
eurjchem-604	572	24	ch2(3,5‐me2tz)2m(co)4	ch2(3,5‐me2tz)2m(co)4	PRON
eurjchem-604	572	25	in	in	ADP
eurjchem-604	572	26	moderate	moderate	ADJ
eurjchem-604	572	27	yield	yield	NOUN
eurjchem-604	572	28	[	[	X
eurjchem-604	572	29	166	166	NUM
eurjchem-604	572	30	]	]	PUNCT
eurjchem-604	572	31	.	.	PUNCT
eurjchem-604	573	1	metal	metal	NOUN
eurjchem-604	573	2	carbonyl	carbonyl	NOUN
eurjchem-604	573	3	complexes	complex	NOUN
eurjchem-604	573	4	mnbr(co)3(3,3′‐r‐2,2′‐	mnbr(co)3(3,3′‐r‐2,2′‐	PRON
eurjchem-604	573	5	biquinoline	biquinoline	ADJ
eurjchem-604	573	6	)	)	PUNCT
eurjchem-604	573	7	containing	contain	VERB
eurjchem-604	573	8	heterocyclic	heterocyclic	ADJ
eurjchem-604	573	9	nitrogen	nitrogen	NOUN
eurjchem-604	573	10	ligands	ligand	NOUN
eurjchem-604	573	11	(	(	PUNCT
eurjchem-604	573	12	3,3′‐r‐	3,3′‐r‐	NUM
eurjchem-604	573	13	2,2′‐biquinoline	2,2′‐biquinoline	NUM
eurjchem-604	573	14	)	)	PUNCT
eurjchem-604	573	15	(	(	PUNCT
eurjchem-604	573	16	r	r	NOUN
eurjchem-604	573	17	=	=	PROPN
eurjchem-604	573	18	ch3	ch3	PROPN
eurjchem-604	573	19	and	and	CCONJ
eurjchem-604	573	20	ch3	ch3	PROPN
eurjchem-604	573	21	;	;	PUNCT
eurjchem-604	573	22	h	h	NOUN
eurjchem-604	573	23	and	and	CCONJ
eurjchem-604	573	24	h	h	NOUN
eurjchem-604	573	25	;	;	PUNCT
eurjchem-604	573	26	‐‐‐ch2‐‐‐ch2‐‐‐	‐‐‐ch2‐‐‐ch2‐‐‐	NOUN
eurjchem-604	573	27	or	or	CCONJ
eurjchem-604	573	28	‐‐‐	‐‐‐	NUM
eurjchem-604	573	29	ch2‐‐‐ch2‐‐‐ch2‐‐‐	ch2‐‐‐ch2‐‐‐ch2‐‐‐	NOUN
eurjchem-604	573	30	)	)	PUNCT
eurjchem-604	573	31	were	be	AUX
eurjchem-604	573	32	synthesized	synthesize	VERB
eurjchem-604	573	33	.	.	PUNCT
eurjchem-604	574	1	the	the	DET
eurjchem-604	574	2	ligand	ligand	NOUN
eurjchem-604	574	3	(	(	PUNCT
eurjchem-604	574	4	3,3′‐r‐2,2′‐	3,3′‐r‐2,2′‐	PRON
eurjchem-604	574	5	biquinoline	biquinoline	VERB
eurjchem-604	574	6	)	)	PUNCT
eurjchem-604	574	7	behave	behave	VERB
eurjchem-604	574	8	as	as	ADP
eurjchem-604	574	9	bidentate	bidentate	ADJ
eurjchem-604	574	10	ligand	ligand	NOUN
eurjchem-604	574	11	coordinating	coordinating	NOUN
eurjchem-604	574	12	via	via	ADP
eurjchem-604	574	13	two	two	NUM
eurjchem-604	574	14	n	n	DET
eurjchem-604	574	15	donor	donor	NOUN
eurjchem-604	574	16	atoms	atom	NOUN
eurjchem-604	574	17	(	(	PUNCT
eurjchem-604	574	18	scheme	scheme	NOUN
eurjchem-604	574	19	41	41	NUM
eurjchem-604	574	20	)	)	PUNCT
eurjchem-604	575	1	[	[	X
eurjchem-604	575	2	167	167	NUM
eurjchem-604	575	3	]	]	PUNCT
eurjchem-604	575	4	.	.	PUNCT
eurjchem-604	576	1	scheme	scheme	NOUN
eurjchem-604	576	2	40	40	NUM
eurjchem-604	576	3	scheme	scheme	NOUN
eurjchem-604	576	4	41	41	NUM
eurjchem-604	576	5	the	the	DET
eurjchem-604	576	6	synthesis	synthesis	NOUN
eurjchem-604	576	7	of	of	ADP
eurjchem-604	576	8	metal	metal	NOUN
eurjchem-604	576	9	carbonyl	carbonyl	NOUN
eurjchem-604	576	10	complexes	complex	NOUN
eurjchem-604	576	11	containing	contain	VERB
eurjchem-604	576	12	the	the	DET
eurjchem-604	576	13	heterocyclic	heterocyclic	ADJ
eurjchem-604	576	14	nitrogen	nitrogen	NOUN
eurjchem-604	576	15	ligand	ligand	NOUN
eurjchem-604	576	16	4′‐phenyl‐2,2′:6′,2″‐terpyridine	4′‐phenyl‐2,2′:6′,2″‐terpyridine	NOUN
eurjchem-604	576	17	are	be	AUX
eurjchem-604	576	18	reported	report	VERB
eurjchem-604	576	19	.	.	PUNCT
eurjchem-604	577	1	complexes	complex	NOUN
eurjchem-604	577	2	of	of	ADP
eurjchem-604	577	3	the	the	DET
eurjchem-604	577	4	[	[	X
eurjchem-604	577	5	m(co)4(l	m(co)4(l	NOUN
eurjchem-604	577	6	)	)	PUNCT
eurjchem-604	577	7	]	]	PUNCT
eurjchem-604	577	8	type	type	NOUN
eurjchem-604	577	9	(	(	PUNCT
eurjchem-604	577	10	m=	m=	X
eurjchem-604	577	11	mo(0	mo(0	NOUN
eurjchem-604	577	12	)	)	PUNCT
eurjchem-604	577	13	,	,	PUNCT
eurjchem-604	577	14	or	or	CCONJ
eurjchem-604	577	15	w(0	w(0	PROPN
eurjchem-604	577	16	)	)	PUNCT
eurjchem-604	577	17	;	;	PUNCT
eurjchem-604	577	18	and	and	CCONJ
eurjchem-604	577	19	l=4′‐phenyl‐2,2′:6′,2″‐terpyridine	l=4′‐phenyl‐2,2′:6′,2″‐terpyridine	NOUN
eurjchem-604	577	20	)	)	PUNCT
eurjchem-604	577	21	were	be	AUX
eurjchem-604	577	22	prepared	prepare	VERB
eurjchem-604	577	23	by	by	ADP
eurjchem-604	577	24	photosubstitution	photosubstitution	NOUN
eurjchem-604	577	25	or	or	CCONJ
eurjchem-604	577	26	by	by	ADP
eurjchem-604	577	27	thermolytic	thermolytic	ADJ
eurjchem-604	577	28	reactions	reaction	NOUN
eurjchem-604	577	29	[	[	X
eurjchem-604	577	30	168	168	NUM
eurjchem-604	577	31	]	]	PUNCT
eurjchem-604	577	32	.	.	PUNCT
eurjchem-604	578	1	re(i	re(i	NOUN
eurjchem-604	578	2	)	)	PUNCT
eurjchem-604	578	3	carbonyl	carbonyl	NOUN
eurjchem-604	578	4	complex	complex	NOUN
eurjchem-604	578	5	fac‐	fac‐	PROPN
eurjchem-604	579	1	[	[	X
eurjchem-604	579	2	re(co)3(dpop′)cl	re(co)3(dpop′)cl	NOUN
eurjchem-604	579	3	]	]	PUNCT
eurjchem-604	579	4	with	with	ADP
eurjchem-604	579	5	the	the	DET
eurjchem-604	579	6	nominally	nominally	ADV
eurjchem-604	579	7	bi‐dentate	bi‐dentate	ADJ
eurjchem-604	579	8	ligand	ligand	NOUN
eurjchem-604	579	9	dipyrido(2,3‐a:3′,2′‐j)phenazine	dipyrido(2,3‐a:3′,2′‐j)phenazine	PROPN
eurjchem-604	579	10	(	(	PUNCT
eurjchem-604	579	11	dpop′	dpop′	X
eurjchem-604	579	12	)	)	PUNCT
eurjchem-604	579	13	were	be	AUX
eurjchem-604	579	14	prepared	prepare	VERB
eurjchem-604	579	15	(	(	PUNCT
eurjchem-604	579	16	scheme42	scheme42	X
eurjchem-604	579	17	)	)	PUNCT
eurjchem-604	580	1	[	[	X
eurjchem-604	580	2	169	169	NUM
eurjchem-604	580	3	]	]	PUNCT
eurjchem-604	580	4	.	.	PUNCT
eurjchem-604	581	1	scheme	scheme	VERB
eurjchem-604	581	2	42	42	NUM
eurjchem-604	581	3	tungsten(0)‐carbonyl	tungsten(0)‐carbonyl	NOUN
eurjchem-604	581	4	complexes	complex	NOUN
eurjchem-604	581	5	of	of	ADP
eurjchem-604	581	6	naphthylazoimidazoles	naphthylazoimidazole	NOUN
eurjchem-604	581	7	[	[	X
eurjchem-604	581	8	w(co)5(α‐nair‐n	w(co)5(α‐nair‐n	X
eurjchem-604	581	9	)	)	PUNCT
eurjchem-604	581	10	]	]	PUNCT
eurjchem-604	581	11	are	be	AUX
eurjchem-604	581	12	reported	report	VERB
eurjchem-604	581	13	.	.	PUNCT
eurjchem-604	582	1	the	the	DET
eurjchem-604	582	2	complexes	complex	NOUN
eurjchem-604	582	3	have	have	AUX
eurjchem-604	582	4	been	be	AUX
eurjchem-604	582	5	transformed	transform	VERB
eurjchem-604	582	6	to	to	ADP
eurjchem-604	582	7	[	[	X
eurjchem-604	582	8	w(co)4(α‐nair‐n	w(co)4(α‐nair‐n	X
eurjchem-604	582	9	,	,	PUNCT
eurjchem-604	582	10	n′	n′	PROPN
eurjchem-604	582	11	)	)	PUNCT
eurjchem-604	582	12	]	]	PUNCT
eurjchem-604	582	13	at	at	ADP
eurjchem-604	582	14	higher	high	ADJ
eurjchem-604	582	15	temperatures	temperature	NOUN
eurjchem-604	582	16	where	where	SCONJ
eurjchem-604	582	17	α‐nair‐n	α‐nair‐n	ADJ
eurjchem-604	582	18	dentes	dent	VERB
eurjchem-604	582	19	a	a	DET
eurjchem-604	582	20	monodentate	monodentate	ADJ
eurjchem-604	582	21	imidazole‐n	imidazole‐n	PROPN
eurjchem-604	582	22	donor	donor	NOUN
eurjchem-604	582	23	ligand	ligand	NOUN
eurjchem-604	582	24	and	and	CCONJ
eurjchem-604	582	25	α‐nair‐n	α‐nair‐n	NOUN
eurjchem-604	582	26	,	,	PUNCT
eurjchem-604	582	27	n′	n′	PROPN
eurjchem-604	582	28	denotes	denote	VERB
eurjchem-604	582	29	a	a	DET
eurjchem-604	582	30	bidentate	bidentate	NOUN
eurjchem-604	582	31	imidazole‐n	imidazole‐n	NOUN
eurjchem-604	582	32	,	,	PUNCT
eurjchem-604	582	33	azo‐n	azo‐n	NUM
eurjchem-604	582	34	donor	donor	NOUN
eurjchem-604	582	35	ligand	ligand	NOUN
eurjchem-604	583	1	[	[	X
eurjchem-604	583	2	170	170	NUM
eurjchem-604	583	3	]	]	PUNCT
eurjchem-604	583	4	.	.	PUNCT
eurjchem-604	584	1	the	the	DET
eurjchem-604	584	2	chiral	chiral	ADJ
eurjchem-604	584	3	diimine	diimine	PROPN
eurjchem-604	584	4	ligand	ligand	PROPN
eurjchem-604	584	5	c5h4n‐2‐	c5h4n‐2‐	PROPN
eurjchem-604	584	6	c(c6h5)=n{(1s,2s)‐c5h8‐2‐och2c6h5	c(c6h5)=n{(1s,2s)‐c5h8‐2‐och2c6h5	PROPN
eurjchem-604	584	7	)	)	PUNCT
eurjchem-604	584	8	}	}	PUNCT
eurjchem-604	584	9	was	be	AUX
eurjchem-604	584	10	prepared	prepare	VERB
eurjchem-604	584	11	via	via	ADP
eurjchem-604	584	12	the	the	DET
eurjchem-604	584	13	reaction	reaction	NOUN
eurjchem-604	584	14	of	of	ADP
eurjchem-604	584	15	2‐benzoyl	2‐benzoyl	PROPN
eurjchem-604	584	16	pyridine	pyridine	NOUN
eurjchem-604	584	17	and	and	CCONJ
eurjchem-604	584	18	(	(	PUNCT
eurjchem-604	584	19	1s,2s)‐(+)‐2‐	1s,2s)‐(+)‐2‐	NUM
eurjchem-604	584	20	benzyloxycyclopentylamine	benzyloxycyclopentylamine	NOUN
eurjchem-604	584	21	.	.	PUNCT
eurjchem-604	585	1	the	the	DET
eurjchem-604	585	2	ligand	ligand	NOUN
eurjchem-604	585	3	reacts	react	VERB
eurjchem-604	585	4	with	with	ADP
eurjchem-604	585	5	m(co)6	m(co)6	NOUN
eurjchem-604	585	6	in	in	ADP
eurjchem-604	585	7	toluene	toluene	NOUN
eurjchem-604	585	8	to	to	PART
eurjchem-604	585	9	give	give	VERB
eurjchem-604	585	10	the	the	DET
eurjchem-604	585	11	respective	respective	ADJ
eurjchem-604	585	12	chiral	chiral	ADJ
eurjchem-604	585	13	metal(0	metal(0	PROPN
eurjchem-604	585	14	)	)	PUNCT
eurjchem-604	585	15	complexes	complexe	VERB
eurjchem-604	586	1	[	[	X
eurjchem-604	586	2	m(co)4(l‐κn	m(co)4(l‐κn	PROPN
eurjchem-604	586	3	,	,	PUNCT
eurjchem-604	586	4	n′	n′	PROPN
eurjchem-604	586	5	)	)	PUNCT
eurjchem-604	586	6	]	]	PUNCT
eurjchem-604	587	1	(	(	PUNCT
eurjchem-604	587	2	m	m	VERB
eurjchem-604	587	3	=	=	SYM
eurjchem-604	587	4	mo	mo	PROPN
eurjchem-604	587	5	and	and	CCONJ
eurjchem-604	587	6	w	w	NOUN
eurjchem-604	587	7	)	)	PUNCT
eurjchem-604	588	1	[	[	X
eurjchem-604	588	2	171	171	NUM
eurjchem-604	588	3	]	]	PUNCT
eurjchem-604	588	4	.	.	PUNCT
eurjchem-604	589	1	n	n	CCONJ
eurjchem-604	589	2	,	,	PUNCT
eurjchem-604	589	3	n′‐bis(ferrocenylmethylene)ethylenediamine	n′‐bis(ferrocenylmethylene)ethylenediamine	X
eurjchem-604	589	4	(	(	PUNCT
eurjchem-604	589	5	bfeda	bfeda	NOUN
eurjchem-604	589	6	)	)	PUNCT
eurjchem-604	589	7	yields	yield	VERB
eurjchem-604	589	8	m(co)4(bfeda	m(co)4(bfeda	NOUN
eurjchem-604	589	9	)	)	PUNCT
eurjchem-604	589	10	complexes	complex	NOUN
eurjchem-604	589	11	(	(	PUNCT
eurjchem-604	589	12	m	m	PROPN
eurjchem-604	589	13	=	=	SYM
eurjchem-604	589	14	cr	cr	PROPN
eurjchem-604	589	15	,	,	PUNCT
eurjchem-604	589	16	mo	mo	PROPN
eurjchem-604	589	17	,	,	PUNCT
eurjchem-604	589	18	w	w	PROPN
eurjchem-604	589	19	)	)	PUNCT
eurjchem-604	589	20	which	which	PRON
eurjchem-604	589	21	could	could	AUX
eurjchem-604	589	22	be	be	AUX
eurjchem-604	589	23	isolated	isolate	VERB
eurjchem-604	589	24	.	.	PUNCT
eurjchem-604	590	1	in	in	ADP
eurjchem-604	590	2	the	the	DET
eurjchem-604	590	3	case	case	NOUN
eurjchem-604	590	4	of	of	ADP
eurjchem-604	590	5	tungsten	tungsten	NOUN
eurjchem-604	590	6	,	,	PUNCT
eurjchem-604	590	7	w(co)5(bfeda	w(co)5(bfeda	X
eurjchem-604	590	8	)	)	PUNCT
eurjchem-604	590	9	is	be	AUX
eurjchem-604	590	10	formed	form	VERB
eurjchem-604	590	11	as	as	ADP
eurjchem-604	590	12	intermediate	intermediate	ADJ
eurjchem-604	590	13	and	and	CCONJ
eurjchem-604	590	14	then	then	ADV
eurjchem-604	590	15	undergoes	undergo	VERB
eurjchem-604	590	16	the	the	DET
eurjchem-604	590	17	ring	ring	NOUN
eurjchem-604	590	18	closure	closure	NOUN
eurjchem-604	590	19	reaction	reaction	NOUN
eurjchem-604	590	20	yielding	yield	VERB
eurjchem-604	590	21	the	the	DET
eurjchem-604	590	22	ultimate	ultimate	ADJ
eurjchem-604	590	23	product	product	NOUN
eurjchem-604	590	24	w(co)4(bfeda	w(co)4(bfeda	NOUN
eurjchem-604	590	25	)	)	PUNCT
eurjchem-604	591	1	[	[	X
eurjchem-604	591	2	172	172	NUM
eurjchem-604	591	3	]	]	PUNCT
eurjchem-604	591	4	.	.	PUNCT
eurjchem-604	592	1	upon	upon	SCONJ
eurjchem-604	592	2	treatment	treatment	NOUN
eurjchem-604	592	3	of	of	ADP
eurjchem-604	592	4	functionalized	functionalized	ADJ
eurjchem-604	592	5	ligands	ligand	NOUN
eurjchem-604	592	6	ph3snch(sph)(3,5‐me2pz	ph3snch(sph)(3,5‐me2pz	NOUN
eurjchem-604	592	7	)	)	PUNCT
eurjchem-604	592	8	and	and	CCONJ
eurjchem-604	592	9	ph3snch(spy)(3,5‐me2pz	ph3snch(spy)(3,5‐me2pz	PROPN
eurjchem-604	592	10	)	)	PUNCT
eurjchem-604	592	11	(	(	PUNCT
eurjchem-604	592	12	pz	pz	NOUN
eurjchem-604	592	13	=	=	X
eurjchem-604	592	14	pyrazol‐1‐yl	pyrazol‐1‐yl	PROPN
eurjchem-604	592	15	and	and	CCONJ
eurjchem-604	592	16	py	py	NOUN
eurjchem-604	592	17	=	=	NOUN
eurjchem-604	592	18	2‐	2‐	NUM
eurjchem-604	592	19	pyridyl	pyridyl	NOUN
eurjchem-604	592	20	)	)	PUNCT
eurjchem-604	592	21	with	with	ADP
eurjchem-604	592	22	group	group	NOUN
eurjchem-604	592	23	6	6	NUM
eurjchem-604	592	24	metal	metal	NOUN
eurjchem-604	592	25	carbonyl	carbonyl	NOUN
eurjchem-604	592	26	complexes	complex	NOUN
eurjchem-604	592	27	,	,	PUNCT
eurjchem-604	592	28	markedly	markedly	ADV
eurjchem-604	592	29	different	different	ADJ
eurjchem-604	592	30	reactions	reaction	NOUN
eurjchem-604	592	31	are	be	AUX
eurjchem-604	592	32	observed	observe	VERB
eurjchem-604	592	33	.	.	PUNCT
eurjchem-604	593	1	reaction	reaction	NOUN
eurjchem-604	593	2	of	of	ADP
eurjchem-604	593	3	1‐arylthiomethyl‐	1‐arylthiomethyl‐	NUM
eurjchem-604	593	4	3,5‐dimethylpyrazole	3,5‐dimethylpyrazole	NUM
eurjchem-604	593	5	[	[	X
eurjchem-604	593	6	arsch2(3,5‐me2pz	arsch2(3,5‐me2pz	NOUN
eurjchem-604	593	7	)	)	PUNCT
eurjchem-604	593	8	,	,	PUNCT
eurjchem-604	593	9	ar	ar	NOUN
eurjchem-604	593	10	=	=	NOUN
eurjchem-604	593	11	phenyl	phenyl	NOUN
eurjchem-604	593	12	or	or	CCONJ
eurjchem-604	593	13	2‐	2‐	NUM
eurjchem-604	593	14	pyridyl	pyridyl	NOUN
eurjchem-604	593	15	,	,	PUNCT
eurjchem-604	593	16	pz	pz	NOUN
eurjchem-604	593	17	=	=	SYM
eurjchem-604	593	18	pyrazol‐1‐yl	pyrazol‐1‐yl	PROPN
eurjchem-604	593	19	]	]	PUNCT
eurjchem-604	593	20	with	with	ADP
eurjchem-604	593	21	mo(co)6	mo(co)6	PROPN
eurjchem-604	593	22	produces	produce	VERB
eurjchem-604	593	23	complexes	complex	NOUN
eurjchem-604	593	24	arsch2(3,5‐me2pz)mo(co)4	arsch2(3,5‐me2pz)mo(co)4	ADV
eurjchem-604	593	25	,	,	PUNCT
eurjchem-604	593	26	while	while	SCONJ
eurjchem-604	593	27	similar	similar	ADJ
eurjchem-604	593	28	reaction	reaction	NOUN
eurjchem-604	593	29	with	with	ADP
eurjchem-604	593	30	w(co)6	w(co)6	PROPN
eurjchem-604	593	31	yields	yield	VERB
eurjchem-604	593	32	analogous	analogous	ADJ
eurjchem-604	593	33	complexes	complex	NOUN
eurjchem-604	593	34	arsch2(3,5‐me2pz)w(co)4	arsch2(3,5‐me2pz)w(co)4	NOUN
eurjchem-604	593	35	(	(	PUNCT
eurjchem-604	593	36	scheme	scheme	NOUN
eurjchem-604	593	37	43	43	NUM
eurjchem-604	593	38	)	)	PUNCT
eurjchem-604	594	1	[	[	X
eurjchem-604	594	2	173	173	NUM
eurjchem-604	594	3	]	]	PUNCT
eurjchem-604	594	4	.	.	PUNCT
eurjchem-604	595	1	scheme	scheme	NOUN
eurjchem-604	595	2	43	43	NUM
eurjchem-604	595	3	retracted	retracted	ADJ
eurjchem-604	595	4	kaushik	kaushik	PROPN
eurjchem-604	595	5	et	et	PROPN
eurjchem-604	595	6	al	al	PROPN
eurjchem-604	595	7	.	.	PUNCT
eurjchem-604	595	8	/	/	SYM
eurjchem-604	595	9	european	european	PROPN
eurjchem-604	595	10	journal	journal	PROPN
eurjchem-604	595	11	of	of	ADP
eurjchem-604	595	12	chemistry	chemistry	NOUN
eurjchem-604	595	13	3	3	NUM
eurjchem-604	595	14	(	(	PUNCT
eurjchem-604	595	15	3	3	NUM
eurjchem-604	595	16	)	)	PUNCT
eurjchem-604	595	17	(	(	PUNCT
eurjchem-604	595	18	2012	2012	NUM
eurjchem-604	595	19	)	)	PUNCT
eurjchem-604	595	20	367‐394	367‐394	NOUN
eurjchem-604	595	21	381	381	NUM
eurjchem-604	595	22	the	the	DET
eurjchem-604	595	23	mo(co)4dab	mo(co)4dab	NOUN
eurjchem-604	595	24	where	where	SCONJ
eurjchem-604	595	25	dab=	dab=	NOUN
eurjchem-604	595	26	diacetyldihydrazone	diacetyldihydrazone	NOUN
eurjchem-604	595	27	,	,	PUNCT
eurjchem-604	595	28	glyoxalcyclohexylamine	glyoxalcyclohexylamine	NOUN
eurjchem-604	595	29	,	,	PUNCT
eurjchem-604	595	30	diazabutadiene	diazabutadiene	NOUN
eurjchem-604	595	31	were	be	AUX
eurjchem-604	595	32	prepared	prepare	VERB
eurjchem-604	595	33	where	where	SCONJ
eurjchem-604	595	34	dab	dab	NOUN
eurjchem-604	595	35	behave	behave	VERB
eurjchem-604	595	36	as	as	ADP
eurjchem-604	595	37	bidentate	bidentate	ADJ
eurjchem-604	595	38	ligand	ligand	NOUN
eurjchem-604	596	1	[	[	X
eurjchem-604	596	2	174	174	NUM
eurjchem-604	596	3	]	]	PUNCT
eurjchem-604	596	4	.	.	PUNCT
eurjchem-604	597	1	reaction	reaction	NOUN
eurjchem-604	597	2	of	of	ADP
eurjchem-604	597	3	bis(diisopropylamino)carbene	bis(diisopropylamino)carbene	NUM
eurjchem-604	597	4	with	with	ADP
eurjchem-604	597	5	ether	ether	NOUN
eurjchem-604	597	6	substituted	substitute	VERB
eurjchem-604	597	7	mo‐	mo‐	PROPN
eurjchem-604	597	8	,	,	PUNCT
eurjchem-604	597	9	and	and	CCONJ
eurjchem-604	597	10	w‐carbonyls	w‐carbonyls	PUNCT
eurjchem-604	597	11	leads	lead	VERB
eurjchem-604	597	12	to	to	ADP
eurjchem-604	597	13	η2‐bonded	η2‐bonded	ADJ
eurjchem-604	597	14	carbene	carbene	ADJ
eurjchem-604	597	15	complexes	complex	NOUN
eurjchem-604	597	16	which	which	PRON
eurjchem-604	597	17	can	can	AUX
eurjchem-604	597	18	be	be	AUX
eurjchem-604	597	19	converted	convert	VERB
eurjchem-604	597	20	in	in	ADP
eurjchem-604	597	21	contrast	contrast	NOUN
eurjchem-604	597	22	to	to	ADP
eurjchem-604	597	23	the	the	DET
eurjchem-604	597	24	analogous	analogous	ADJ
eurjchem-604	597	25	chromium	chromium	NOUN
eurjchem-604	597	26	complex	complex	NOUN
eurjchem-604	597	27	in	in	ADP
eurjchem-604	597	28	a	a	DET
eurjchem-604	597	29	co‐atmosphere	co‐atmosphere	NOUN
eurjchem-604	597	30	to	to	ADP
eurjchem-604	597	31	imine	imine	ADJ
eurjchem-604	597	32	complexes	complex	NOUN
eurjchem-604	597	33	(	(	PUNCT
eurjchem-604	597	34	scheme	scheme	NOUN
eurjchem-604	597	35	44	44	NUM
eurjchem-604	597	36	)	)	PUNCT
eurjchem-604	598	1	[	[	X
eurjchem-604	598	2	175	175	NUM
eurjchem-604	598	3	]	]	PUNCT
eurjchem-604	598	4	.	.	PUNCT
eurjchem-604	599	1	scheme	scheme	NOUN
eurjchem-604	599	2	44	44	NUM
eurjchem-604	599	3	the	the	DET
eurjchem-604	599	4	complexes	complex	NOUN
eurjchem-604	599	5	[	[	X
eurjchem-604	599	6	m(co)4(ƞ2‐h2l	m(co)4(ƞ2‐h2l	ADJ
eurjchem-604	599	7	)	)	PUNCT
eurjchem-604	599	8	]	]	PUNCT
eurjchem-604	600	1	[	[	X
eurjchem-604	600	2	m	m	X
eurjchem-604	600	3	=	=	ADJ
eurjchem-604	600	4	cr	cr	PROPN
eurjchem-604	600	5	;	;	PUNCT
eurjchem-604	600	6	mo	mo	PROPN
eurjchem-604	600	7	;	;	PUNCT
eurjchem-604	600	8	w	w	X
eurjchem-604	600	9	]	]	PUNCT
eurjchem-604	600	10	have	have	AUX
eurjchem-604	600	11	been	be	AUX
eurjchem-604	600	12	synthesized	synthesize	VERB
eurjchem-604	600	13	by	by	ADP
eurjchem-604	600	14	photochemical	photochemical	ADJ
eurjchem-604	600	15	reactions	reaction	NOUN
eurjchem-604	600	16	of	of	ADP
eurjchem-604	600	17	vib	vib	NOUN
eurjchem-604	600	18	metal	metal	NOUN
eurjchem-604	600	19	carbonyls	carbonyls	NOUN
eurjchem-604	600	20	[	[	X
eurjchem-604	600	21	m(co)6	m(co)6	X
eurjchem-604	600	22	]	]	X
eurjchem-604	601	1	[	[	X
eurjchem-604	601	2	m	m	X
eurjchem-604	601	3	=	=	ADJ
eurjchem-604	601	4	cr	cr	PROPN
eurjchem-604	601	5	;	;	PUNCT
eurjchem-604	601	6	mo	mo	PROPN
eurjchem-604	601	7	;	;	PUNCT
eurjchem-604	601	8	w	w	NOUN
eurjchem-604	601	9	]	]	X
eurjchem-604	601	10	with	with	ADP
eurjchem-604	601	11	n	n	CCONJ
eurjchem-604	601	12	,	,	PUNCT
eurjchem-604	601	13	n’‐bis(salicylidene)‐	n’‐bis(salicylidene)‐	PROPN
eurjchem-604	601	14	1,2‐bis‐(o‐aminophenoxy)ethane	1,2‐bis‐(o‐aminophenoxy)ethane	NOUN
eurjchem-604	601	15	(	(	PUNCT
eurjchem-604	601	16	h2l	h2l	PROPN
eurjchem-604	601	17	)	)	PUNCT
eurjchem-604	601	18	in	in	ADP
eurjchem-604	601	19	thf	thf	NOUN
eurjchem-604	601	20	.	.	PUNCT
eurjchem-604	602	1	the	the	DET
eurjchem-604	602	2	h2l	h2l	PROPN
eurjchem-604	602	3	ligand	ligand	NOUN
eurjchem-604	602	4	was	be	AUX
eurjchem-604	602	5	found	find	VERB
eurjchem-604	602	6	coordinated	coordinate	VERB
eurjchem-604	602	7	to	to	ADP
eurjchem-604	602	8	the	the	DET
eurjchem-604	602	9	central	central	ADJ
eurjchem-604	602	10	metal	metal	NOUN
eurjchem-604	602	11	as	as	ADP
eurjchem-604	602	12	bidentate	bidentate	ADJ
eurjchem-604	602	13	ligand	ligand	NOUN
eurjchem-604	602	14	via	via	ADP
eurjchem-604	602	15	the	the	DET
eurjchem-604	602	16	central	central	ADJ
eurjchem-604	602	17	azomethine	azomethine	NOUN
eurjchem-604	602	18	nitrogen	nitrogen	NOUN
eurjchem-604	602	19	atoms	atom	NOUN
eurjchem-604	603	1	[	[	X
eurjchem-604	603	2	176	176	NUM
eurjchem-604	603	3	]	]	PUNCT
eurjchem-604	603	4	.	.	PUNCT
eurjchem-604	604	1	the	the	DET
eurjchem-604	604	2	interaction	interaction	NOUN
eurjchem-604	604	3	of	of	ADP
eurjchem-604	604	4	the	the	DET
eurjchem-604	604	5	group	group	NOUN
eurjchem-604	604	6	vi	vi	PROPN
eurjchem-604	604	7	metal	metal	NOUN
eurjchem-604	604	8	hexacarbonyls	hexacarbonyls	NOUN
eurjchem-604	604	9	with	with	ADP
eurjchem-604	604	10	electron	electron	NOUN
eurjchem-604	604	11	donors	donor	NOUN
eurjchem-604	604	12	has	have	AUX
eurjchem-604	604	13	been	be	AUX
eurjchem-604	604	14	widely	widely	ADV
eurjchem-604	604	15	explored	explore	VERB
eurjchem-604	604	16	.	.	PUNCT
eurjchem-604	605	1	these	these	DET
eurjchem-604	605	2	reaction	reaction	NOUN
eurjchem-604	605	3	generally	generally	ADV
eurjchem-604	605	4	require	require	VERB
eurjchem-604	605	5	thermal	thermal	ADJ
eurjchem-604	605	6	activation	activation	NOUN
eurjchem-604	605	7	,	,	PUNCT
eurjchem-604	605	8	although	although	SCONJ
eurjchem-604	605	9	in	in	ADP
eurjchem-604	605	10	some	some	DET
eurjchem-604	605	11	cases	case	NOUN
eurjchem-604	605	12	photolytic	photolytic	ADJ
eurjchem-604	605	13	activation	activation	NOUN
eurjchem-604	605	14	was	be	AUX
eurjchem-604	605	15	observed	observe	VERB
eurjchem-604	605	16	.	.	PUNCT
eurjchem-604	606	1	photolytic	photolytic	ADJ
eurjchem-604	606	2	preparation	preparation	NOUN
eurjchem-604	606	3	of	of	ADP
eurjchem-604	606	4	some	some	DET
eurjchem-604	606	5	new	new	ADJ
eurjchem-604	606	6	anionic	anionic	ADJ
eurjchem-604	606	7	derivatives	derivative	NOUN
eurjchem-604	606	8	of	of	ADP
eurjchem-604	606	9	chromium	chromium	NOUN
eurjchem-604	606	10	,	,	PUNCT
eurjchem-604	606	11	molybdenum	molybdenum	NOUN
eurjchem-604	606	12	and	and	CCONJ
eurjchem-604	606	13	tungsten	tungsten	ADJ
eurjchem-604	606	14	hexacarbonyls	hexacarbonyls	PROPN
eurjchem-604	606	15	involving	involve	VERB
eurjchem-604	606	16	both	both	CCONJ
eurjchem-604	606	17	the	the	DET
eurjchem-604	606	18	difluorodithiophosphate	difluorodithiophosphate	ADJ
eurjchem-604	606	19	anion	anion	NOUN
eurjchem-604	606	20	and	and	CCONJ
eurjchem-604	606	21	difluorothiosulphate	difluorothiosulphate	ADJ
eurjchem-604	606	22	anion	anion	NOUN
eurjchem-604	606	23	as	as	ADP
eurjchem-604	606	24	ligands	ligand	NOUN
eurjchem-604	606	25	.	.	PUNCT
eurjchem-604	607	1	the	the	DET
eurjchem-604	607	2	reaction	reaction	NOUN
eurjchem-604	607	3	between	between	ADP
eurjchem-604	607	4	metal	metal	NOUN
eurjchem-604	607	5	hexacarbonyl	hexacarbonyl	NOUN
eurjchem-604	607	6	and	and	CCONJ
eurjchem-604	607	7	complexing	complexe	VERB
eurjchem-604	607	8	anion	anion	NOUN
eurjchem-604	607	9	in	in	ADP
eurjchem-604	607	10	methylene	methylene	ADJ
eurjchem-604	607	11	chloride	chloride	NOUN
eurjchem-604	607	12	solution	solution	NOUN
eurjchem-604	607	13	results	result	VERB
eurjchem-604	607	14	the	the	DET
eurjchem-604	607	15	formation	formation	NOUN
eurjchem-604	607	16	of	of	ADP
eurjchem-604	607	17	m(co)4pf2s2‐	m(co)4pf2s2‐	NOUN
eurjchem-604	607	18	complexes	complex	NOUN
eurjchem-604	607	19	.	.	PUNCT
eurjchem-604	608	1	these	these	DET
eurjchem-604	608	2	complexes	complex	NOUN
eurjchem-604	608	3	were	be	AUX
eurjchem-604	608	4	found	find	VERB
eurjchem-604	608	5	to	to	PART
eurjchem-604	608	6	be	be	AUX
eurjchem-604	608	7	air	air	NOUN
eurjchem-604	608	8	stable	stable	ADJ
eurjchem-604	608	9	in	in	ADP
eurjchem-604	608	10	solid	solid	ADJ
eurjchem-604	608	11	state	state	NOUN
eurjchem-604	608	12	,	,	PUNCT
eurjchem-604	608	13	although	although	SCONJ
eurjchem-604	608	14	solutions	solution	NOUN
eurjchem-604	608	15	are	be	AUX
eurjchem-604	608	16	oxidized	oxidize	VERB
eurjchem-604	608	17	by	by	ADP
eurjchem-604	608	18	atmospheric	atmospheric	ADJ
eurjchem-604	608	19	oxygen	oxygen	NOUN
eurjchem-604	608	20	.	.	PUNCT
eurjchem-604	609	1	the	the	DET
eurjchem-604	609	2	stability	stability	NOUN
eurjchem-604	609	3	increases	increase	VERB
eurjchem-604	609	4	from	from	ADP
eurjchem-604	609	5	chromium	chromium	NOUN
eurjchem-604	609	6	to	to	PART
eurjchem-604	609	7	tungsten	tungsten	VERB
eurjchem-604	609	8	derivatives	derivative	NOUN
eurjchem-604	609	9	[	[	X
eurjchem-604	609	10	177	177	NUM
eurjchem-604	609	11	]	]	PUNCT
eurjchem-604	609	12	.	.	PUNCT
eurjchem-604	610	1	4.2.2	4.2.2	X
eurjchem-604	610	2	.	.	PUNCT
eurjchem-604	610	3	binuclear	binuclear	NOUN
eurjchem-604	610	4	complexes	complexe	VERB
eurjchem-604	610	5	[	[	X
eurjchem-604	610	6	m2(co)10l	m2(co)10l	X
eurjchem-604	610	7	]	]	X
eurjchem-604	610	8	pentacarbonylpyrazinetungsten(0	pentacarbonylpyrazinetungsten(0	NOUN
eurjchem-604	610	9	)	)	PUNCT
eurjchem-604	610	10	,	,	PUNCT
eurjchem-604	610	11	(	(	PUNCT
eurjchem-604	610	12	co)5w(pyz	co)5w(pyz	X
eurjchem-604	610	13	)	)	PUNCT
eurjchem-604	610	14	,	,	PUNCT
eurjchem-604	610	15	is	be	AUX
eurjchem-604	610	16	not	not	PART
eurjchem-604	610	17	stable	stable	ADJ
eurjchem-604	610	18	in	in	ADP
eurjchem-604	610	19	solution	solution	NOUN
eurjchem-604	610	20	in	in	ADP
eurjchem-604	610	21	polar	polar	ADJ
eurjchem-604	610	22	solvents	solvent	NOUN
eurjchem-604	610	23	such	such	ADJ
eurjchem-604	610	24	as	as	ADP
eurjchem-604	610	25	acetone	acetone	NOUN
eurjchem-604	610	26	or	or	CCONJ
eurjchem-604	610	27	dichloromethane	dichloromethane	NOUN
eurjchem-604	610	28	and	and	CCONJ
eurjchem-604	610	29	undergoes	undergo	VERB
eurjchem-604	610	30	conversion	conversion	NOUN
eurjchem-604	610	31	to	to	ADP
eurjchem-604	610	32	a	a	DET
eurjchem-604	610	33	bimetallic	bimetallic	ADJ
eurjchem-604	610	34	complex	complex	NOUN
eurjchem-604	610	35	,	,	PUNCT
eurjchem-604	610	36	(	(	PUNCT
eurjchem-604	610	37	co)5w(pyz)w(co)5[178	co)5w(pyz)w(co)5[178	NOUN
eurjchem-604	610	38	]	]	PUNCT
eurjchem-604	610	39	.	.	PUNCT
eurjchem-604	611	1	density	density	NOUN
eurjchem-604	611	2	functional	functional	ADJ
eurjchem-604	611	3	theory	theory	NOUN
eurjchem-604	611	4	has	have	AUX
eurjchem-604	611	5	been	be	AUX
eurjchem-604	611	6	used	use	VERB
eurjchem-604	611	7	to	to	PART
eurjchem-604	611	8	explore	explore	VERB
eurjchem-604	611	9	possible	possible	ADJ
eurjchem-604	611	10	homoleptic	homoleptic	ADJ
eurjchem-604	611	11	binuclear	binuclear	NOUN
eurjchem-604	611	12	cr	cr	ADP
eurjchem-604	611	13	carbonyls	carbonyl	VERB
eurjchem-604	611	14	cr2(co)n	cr2(co)n	VERB
eurjchem-604	611	15	(	(	PUNCT
eurjchem-604	611	16	n	n	NOUN
eurjchem-604	611	17	=	=	SYM
eurjchem-604	611	18	11	11	NUM
eurjchem-604	611	19	,	,	PUNCT
eurjchem-604	611	20	10	10	NUM
eurjchem-604	611	21	,	,	PUNCT
eurjchem-604	611	22	9	9	NUM
eurjchem-604	611	23	,	,	PUNCT
eurjchem-604	611	24	and	and	CCONJ
eurjchem-604	611	25	8)	8)	NUM
eurjchem-604	611	26	using	use	VERB
eurjchem-604	611	27	the	the	DET
eurjchem-604	611	28	pure	pure	ADJ
eurjchem-604	611	29	dft	dft	NOUN
eurjchem-604	611	30	method	method	NOUN
eurjchem-604	611	31	bp86	bp86	PROPN
eurjchem-604	611	32	and	and	CCONJ
eurjchem-604	611	33	the	the	DET
eurjchem-604	611	34	hybrid	hybrid	ADJ
eurjchem-604	611	35	hartree‐fock	hartree‐fock	NOUN
eurjchem-604	611	36	dft	dft	PROPN
eurjchem-604	611	37	method	method	PROPN
eurjchem-604	611	38	b3lyp	b3lyp	PROPN
eurjchem-604	611	39	.	.	PUNCT
eurjchem-604	612	1	the	the	DET
eurjchem-604	612	2	binuclear	binuclear	NOUN
eurjchem-604	612	3	cr2(co)11	cr2(co)11	VERB
eurjchem-604	612	4	is	be	AUX
eurjchem-604	612	5	computed	compute	VERB
eurjchem-604	612	6	to	to	PART
eurjchem-604	612	7	be	be	AUX
eurjchem-604	612	8	thermodynamically	thermodynamically	ADV
eurjchem-604	612	9	unstable	unstable	ADJ
eurjchem-604	612	10	with	with	ADP
eurjchem-604	612	11	respect	respect	NOUN
eurjchem-604	612	12	to	to	ADP
eurjchem-604	612	13	dissociation	dissociation	NOUN
eurjchem-604	612	14	into	into	ADP
eurjchem-604	612	15	mononuclear	mononuclear	ADJ
eurjchem-604	612	16	fragments	fragment	NOUN
eurjchem-604	612	17	.	.	PUNCT
eurjchem-604	613	1	the	the	DET
eurjchem-604	613	2	following	follow	VERB
eurjchem-604	613	3	binuclear	binuclear	NOUN
eurjchem-604	613	4	cr	cr	NOUN
eurjchem-604	613	5	carbonyls	carbonyls	PROPN
eurjchem-604	613	6	were	be	AUX
eurjchem-604	613	7	found	find	VERB
eurjchem-604	613	8	with	with	ADP
eurjchem-604	613	9	metal‐metal	metal‐metal	ADJ
eurjchem-604	613	10	multiple	multiple	ADJ
eurjchem-604	613	11	bonding	bonding	NOUN
eurjchem-604	613	12	‐	‐	ADJ
eurjchem-604	613	13	cr2(co)10	cr2(co)10	ADJ
eurjchem-604	613	14	,	,	PUNCT
eurjchem-604	613	15	cr2(co)9	cr2(co)9	ADJ
eurjchem-604	613	16	,	,	PUNCT
eurjchem-604	613	17	and	and	CCONJ
eurjchem-604	613	18	cr2(co)8	cr2(co)8	NOUN
eurjchem-604	614	1	[	[	X
eurjchem-604	614	2	179	179	NUM
eurjchem-604	614	3	]	]	PUNCT
eurjchem-604	614	4	.	.	PUNCT
eurjchem-604	615	1	ir	ir	PROPN
eurjchem-604	615	2	spectroelectrochemical	spectroelectrochemical	ADJ
eurjchem-604	615	3	studies	study	NOUN
eurjchem-604	615	4	of	of	ADP
eurjchem-604	615	5	the	the	DET
eurjchem-604	615	6	metal	metal	NOUN
eurjchem-604	615	7	carbonyl	carbonyl	NOUN
eurjchem-604	615	8	dimers	dimer	NOUN
eurjchem-604	615	9	mn2(co)10	mn2(co)10	X
eurjchem-604	615	10	and	and	CCONJ
eurjchem-604	615	11	[	[	X
eurjchem-604	615	12	cpm(co)3]2	cpm(co)3]2	X
eurjchem-604	615	13	(	(	PUNCT
eurjchem-604	615	14	m	m	PROPN
eurjchem-604	615	15	=	=	SYM
eurjchem-604	615	16	w	w	PROPN
eurjchem-604	615	17	,	,	PUNCT
eurjchem-604	615	18	mo	mo	PROPN
eurjchem-604	615	19	)	)	PUNCT
eurjchem-604	615	20	.	.	PUNCT
eurjchem-604	616	1	cross‐	cross‐	PROPN
eurjchem-604	616	2	coupling	couple	VERB
eurjchem-604	616	3	and	and	CCONJ
eurjchem-604	616	4	ligand	ligand	ADJ
eurjchem-604	616	5	substitution	substitution	NOUN
eurjchem-604	616	6	reactions	reaction	NOUN
eurjchem-604	616	7	of	of	ADP
eurjchem-604	616	8	electrochemically	electrochemically	ADV
eurjchem-604	616	9	generated	generate	VERB
eurjchem-604	616	10	organometallic	organometallic	ADJ
eurjchem-604	616	11	radicals	radical	NOUN
eurjchem-604	616	12	were	be	AUX
eurjchem-604	616	13	reported	report	VERB
eurjchem-604	616	14	[	[	X
eurjchem-604	616	15	180	180	NUM
eurjchem-604	616	16	]	]	PUNCT
eurjchem-604	616	17	.	.	PUNCT
eurjchem-604	617	1	the	the	DET
eurjchem-604	617	2	transition	transition	NOUN
eurjchem-604	617	3	metal	metal	NOUN
eurjchem-604	617	4	carbonyl	carbonyl	NOUN
eurjchem-604	617	5	complexes	complex	NOUN
eurjchem-604	617	6	of	of	ADP
eurjchem-604	617	7	1,3‐bis(di‐r‐	1,3‐bis(di‐r‐	NUM
eurjchem-604	617	8	stibino)propanes	stibino)propane	NOUN
eurjchem-604	617	9	(	(	PUNCT
eurjchem-604	617	10	r	r	X
eurjchem-604	617	11	=	=	VERB
eurjchem-604	617	12	me	i	PRON
eurjchem-604	617	13	or	or	CCONJ
eurjchem-604	617	14	ph	ph	VERB
eurjchem-604	617	15	)	)	PUNCT
eurjchem-604	617	16	(	(	PUNCT
eurjchem-604	617	17	distibinopropanes	distibinopropane	NOUN
eurjchem-604	617	18	)	)	PUNCT
eurjchem-604	617	19	with	with	ADP
eurjchem-604	617	20	the	the	DET
eurjchem-604	617	21	carbonyls	carbonyls	NOUN
eurjchem-604	617	22	of	of	ADP
eurjchem-604	617	23	cr	cr	PROPN
eurjchem-604	617	24	,	,	PUNCT
eurjchem-604	617	25	mo	mo	PROPN
eurjchem-604	617	26	,	,	PUNCT
eurjchem-604	617	27	w	w	PROPN
eurjchem-604	617	28	,	,	PUNCT
eurjchem-604	617	29	fe	fe	X
eurjchem-604	617	30	,	,	PUNCT
eurjchem-604	617	31	mn	mn	PROPN
eurjchem-604	617	32	and	and	CCONJ
eurjchem-604	617	33	ni	ni	PROPN
eurjchem-604	617	34	were	be	AUX
eurjchem-604	617	35	prepared	prepare	VERB
eurjchem-604	617	36	.	.	PUNCT
eurjchem-604	618	1	these	these	PRON
eurjchem-604	618	2	include	include	VERB
eurjchem-604	618	3	cis‐[m(co)4{r2sb(ch2)3sbr2	cis‐[m(co)4{r2sb(ch2)3sbr2	NOUN
eurjchem-604	618	4	}	}	PUNCT
eurjchem-604	618	5	]	]	PUNCT
eurjchem-604	618	6	(	(	PUNCT
eurjchem-604	618	7	m	m	PROPN
eurjchem-604	618	8	=	=	SYM
eurjchem-604	618	9	cr	cr	PROPN
eurjchem-604	618	10	,	,	PUNCT
eurjchem-604	618	11	mo	mo	NOUN
eurjchem-604	618	12	or	or	CCONJ
eurjchem-604	618	13	w	w	NOUN
eurjchem-604	618	14	)	)	PUNCT
eurjchem-604	618	15	,	,	PUNCT
eurjchem-604	618	16	[	[	X
eurjchem-604	618	17	{	{	PUNCT
eurjchem-604	618	18	fe(co)4}2{μ‐r2sb(ch2)3sbr2	fe(co)4}2{μ‐r2sb(ch2)3sbr2	NOUN
eurjchem-604	618	19	}	}	PUNCT
eurjchem-604	618	20	]	]	PUNCT
eurjchem-604	618	21	,	,	PUNCT
eurjchem-604	618	22	[	[	X
eurjchem-604	618	23	{	{	PUNCT
eurjchem-604	618	24	ni(co)3}2{μ‐r2sb(ch2)3	ni(co)3}2{μ‐r2sb(ch2)3	NUM
eurjchem-604	618	25	sbr2	sbr2	NOUN
eurjchem-604	618	26	}	}	PUNCT
eurjchem-604	618	27	]	]	PUNCT
eurjchem-604	618	28	(	(	PUNCT
eurjchem-604	618	29	scheme	scheme	NOUN
eurjchem-604	618	30	45	45	NUM
eurjchem-604	618	31	)	)	PUNCT
eurjchem-604	618	32	,	,	PUNCT
eurjchem-604	619	1	[	[	X
eurjchem-604	619	2	co2(co)6{ph2sb(ch2)3sbph2	co2(co)6{ph2sb(ch2)3sbph2	ADJ
eurjchem-604	619	3	}	}	PUNCT
eurjchem-604	619	4	]	]	PUNCT
eurjchem-604	619	5	,	,	PUNCT
eurjchem-604	620	1	[	[	X
eurjchem-604	620	2	co2(co)4	co2(co)4	PROPN
eurjchem-604	620	3	{	{	PUNCT
eurjchem-604	620	4	me2sb(ch2)3sbme2}3	me2sb(ch2)3sbme2}3	NOUN
eurjchem-604	620	5	]	]	PUNCT
eurjchem-604	621	1	[	[	X
eurjchem-604	621	2	co(co)4]2	co(co)4]2	NOUN
eurjchem-604	621	3	and	and	CCONJ
eurjchem-604	621	4	[	[	X
eurjchem-604	621	5	mn2(co)8{ph2sb(ch2)3	mn2(co)8{ph2sb(ch2)3	NOUN
eurjchem-604	621	6	sbph2	sbph2	ADJ
eurjchem-604	621	7	}	}	PUNCT
eurjchem-604	621	8	]	]	PUNCT
eurjchem-604	621	9	.	.	PUNCT
eurjchem-604	622	1	the	the	DET
eurjchem-604	622	2	studies	study	NOUN
eurjchem-604	622	3	show	show	VERB
eurjchem-604	622	4	that	that	SCONJ
eurjchem-604	622	5	distibinopropanes	distibinopropane	NOUN
eurjchem-604	622	6	are	be	AUX
eurjchem-604	622	7	bidentate	bidentate	ADJ
eurjchem-604	622	8	ligands	ligand	NOUN
eurjchem-604	622	9	[	[	X
eurjchem-604	622	10	181	181	NUM
eurjchem-604	622	11	]	]	PUNCT
eurjchem-604	622	12	.	.	PUNCT
eurjchem-604	623	1	sunlight	sunlight	NOUN
eurjchem-604	623	2	irradiation	irradiation	NOUN
eurjchem-604	623	3	of	of	ADP
eurjchem-604	623	4	the	the	DET
eurjchem-604	623	5	reactions	reaction	NOUN
eurjchem-604	623	6	of	of	ADP
eurjchem-604	623	7	[	[	X
eurjchem-604	623	8	m(co)6	m(co)6	X
eurjchem-604	623	9	]	]	NOUN
eurjchem-604	623	10	,	,	PUNCT
eurjchem-604	623	11	m	m	PROPN
eurjchem-604	623	12	=	=	NOUN
eurjchem-604	623	13	cr	cr	PROPN
eurjchem-604	623	14	,	,	PUNCT
eurjchem-604	623	15	mo	mo	PROPN
eurjchem-604	623	16	and	and	CCONJ
eurjchem-604	623	17	w	w	NOUN
eurjchem-604	623	18	with	with	ADP
eurjchem-604	623	19	dimethylglyoxime	dimethylglyoxime	PROPN
eurjchem-604	623	20	(	(	PUNCT
eurjchem-604	623	21	h2dmg	h2dmg	PROPN
eurjchem-604	623	22	)	)	PUNCT
eurjchem-604	623	23	in	in	ADP
eurjchem-604	623	24	thf	thf	NOUN
eurjchem-604	623	25	were	be	AUX
eurjchem-604	623	26	investigated	investigate	VERB
eurjchem-604	623	27	.	.	PUNCT
eurjchem-604	624	1	the	the	DET
eurjchem-604	624	2	reaction	reaction	NOUN
eurjchem-604	624	3	of	of	ADP
eurjchem-604	624	4	[	[	X
eurjchem-604	624	5	cr(co)6	cr(co)6	X
eurjchem-604	624	6	]	]	PUNCT
eurjchem-604	624	7	with	with	ADP
eurjchem-604	624	8	h2dmg	h2dmg	PROPN
eurjchem-604	624	9	resulted	result	VERB
eurjchem-604	624	10	in	in	ADP
eurjchem-604	624	11	the	the	DET
eurjchem-604	624	12	formation	formation	NOUN
eurjchem-604	624	13	of	of	ADP
eurjchem-604	624	14	the	the	DET
eurjchem-604	624	15	square	square	ADJ
eurjchem-604	624	16	pyramidal	pyramidal	ADJ
eurjchem-604	624	17	complex	complex	NOUN
eurjchem-604	624	18	[	[	X
eurjchem-604	624	19	cro(h2dmg)2	cro(h2dmg)2	PROPN
eurjchem-604	624	20	]	]	PUNCT
eurjchem-604	624	21	.	.	PUNCT
eurjchem-604	625	1	the	the	DET
eurjchem-604	625	2	h2dmg	h2dmg	PROPN
eurjchem-604	625	3	coordinated	coordinate	VERB
eurjchem-604	625	4	the	the	DET
eurjchem-604	625	5	metal	metal	NOUN
eurjchem-604	625	6	from	from	ADP
eurjchem-604	625	7	the	the	DET
eurjchem-604	625	8	two	two	NUM
eurjchem-604	625	9	nitrogen	nitrogen	NOUN
eurjchem-604	625	10	atoms	atom	NOUN
eurjchem-604	625	11	.	.	PUNCT
eurjchem-604	626	1	the	the	DET
eurjchem-604	626	2	corresponding	corresponding	ADJ
eurjchem-604	626	3	reactions	reaction	NOUN
eurjchem-604	626	4	of	of	ADP
eurjchem-604	626	5	molybdenum	molybdenum	NOUN
eurjchem-604	626	6	and	and	CCONJ
eurjchem-604	626	7	tungsten	tungsten	VERB
eurjchem-604	626	8	carbonyls	carbonyls	NOUN
eurjchem-604	626	9	yielded	yield	VERB
eurjchem-604	626	10	the	the	DET
eurjchem-604	626	11	binuclear	binuclear	NOUN
eurjchem-604	626	12	oxo	oxo	NOUN
eurjchem-604	626	13	complex	complex	NOUN
eurjchem-604	626	14	[	[	X
eurjchem-604	626	15	(	(	PUNCT
eurjchem-604	626	16	h2dmg)o2m(μ‐	h2dmg)o2m(μ‐	NOUN
eurjchem-604	626	17	o)2mo2(h2dmg	o)2mo2(h2dmg	PROPN
eurjchem-604	626	18	)	)	PUNCT
eurjchem-604	626	19	]	]	PUNCT
eurjchem-604	627	1	[	[	X
eurjchem-604	627	2	182	182	NUM
eurjchem-604	627	3	]	]	PUNCT
eurjchem-604	627	4	.	.	PUNCT
eurjchem-604	628	1	the	the	DET
eurjchem-604	628	2	structure	structure	NOUN
eurjchem-604	628	3	,	,	PUNCT
eurjchem-604	628	4	bonding	bonding	NOUN
eurjchem-604	628	5	,	,	PUNCT
eurjchem-604	628	6	and	and	CCONJ
eurjchem-604	628	7	photochemistry	photochemistry	NOUN
eurjchem-604	628	8	of	of	ADP
eurjchem-604	628	9	the	the	DET
eurjchem-604	628	10	group	group	NOUN
eurjchem-604	628	11	vi	vi	PROPN
eurjchem-604	628	12	cyclopentadienyl	cyclopentadienyl	NOUN
eurjchem-604	628	13	metal	metal	NOUN
eurjchem-604	628	14	carbonyl	carbonyl	NOUN
eurjchem-604	628	15	compounds	compound	NOUN
eurjchem-604	628	16	of	of	ADP
eurjchem-604	628	17	the	the	DET
eurjchem-604	628	18	general	general	ADJ
eurjchem-604	628	19	form	form	NOUN
eurjchem-604	628	20	(	(	PUNCT
eurjchem-604	628	21	η5‐c5h5)2m2(co)6	η5‐c5h5)2m2(co)6	X
eurjchem-604	628	22	,	,	PUNCT
eurjchem-604	628	23	where	where	SCONJ
eurjchem-604	628	24	m	m	PROPN
eurjchem-604	628	25	=	=	SYM
eurjchem-604	628	26	cr	cr	PROPN
eurjchem-604	628	27	,	,	PUNCT
eurjchem-604	628	28	mo	mo	PROPN
eurjchem-604	628	29	,	,	PUNCT
eurjchem-604	628	30	and	and	CCONJ
eurjchem-604	628	31	w	w	NOUN
eurjchem-604	628	32	,	,	PUNCT
eurjchem-604	628	33	and	and	CCONJ
eurjchem-604	628	34	their	their	PRON
eurjchem-604	628	35	ring‐substituted	ring‐substituted	ADJ
eurjchem-604	628	36	and	and	CCONJ
eurjchem-604	628	37	ring‐	ring‐	NOUN
eurjchem-604	628	38	coupled	couple	VERB
eurjchem-604	628	39	derivatives	derivative	NOUN
eurjchem-604	628	40	is	be	AUX
eurjchem-604	628	41	critically	critically	ADV
eurjchem-604	628	42	reviewed	review	VERB
eurjchem-604	628	43	[	[	PUNCT
eurjchem-604	628	44	183	183	NUM
eurjchem-604	628	45	]	]	PUNCT
eurjchem-604	628	46	.	.	PUNCT
eurjchem-604	629	1	scheme	scheme	NOUN
eurjchem-604	629	2	45	45	NUM
eurjchem-604	629	3	binuclear	binuclear	NOUN
eurjchem-604	629	4	metal	metal	NOUN
eurjchem-604	629	5	carbonyl	carbonyl	NOUN
eurjchem-604	629	6	complexes	complex	NOUN
eurjchem-604	629	7	have	have	AUX
eurjchem-604	629	8	been	be	AUX
eurjchem-604	629	9	reported	report	VERB
eurjchem-604	629	10	via	via	ADP
eurjchem-604	629	11	cis‐bridging	cis‐bridge	VERB
eurjchem-604	629	12	bidentate	bidentate	ADJ
eurjchem-604	629	13	coordination	coordination	NOUN
eurjchem-604	629	14	of	of	ADP
eurjchem-604	629	15	the	the	DET
eurjchem-604	629	16	ligand	ligand	NOUN
eurjchem-604	629	17	between	between	ADP
eurjchem-604	629	18	two	two	NUM
eurjchem-604	629	19	metals	metal	NOUN
eurjchem-604	629	20	in	in	ADP
eurjchem-604	629	21	{	{	PUNCT
eurjchem-604	629	22	m2(co)4	m2(co)4	X
eurjchem-604	629	23	[	[	X
eurjchem-604	629	24	μ‐ph2p(s)p(s)ph2]}(m	μ‐ph2p(s)p(s)ph2]}(m	NOUN
eurjchem-604	629	25	=	=	SYM
eurjchem-604	629	26	cr	cr	PROPN
eurjchem-604	629	27	,	,	PUNCT
eurjchem-604	629	28	mo	mo	PROPN
eurjchem-604	629	29	and	and	CCONJ
eurjchem-604	629	30	w	w	NOUN
eurjchem-604	629	31	)	)	PUNCT
eurjchem-604	630	1	[	[	X
eurjchem-604	630	2	184,185	184,185	NUM
eurjchem-604	630	3	]	]	PUNCT
eurjchem-604	630	4	.	.	PUNCT
eurjchem-604	631	1	lithiation	lithiation	NOUN
eurjchem-604	631	2	of	of	ADP
eurjchem-604	631	3	ligand	ligand	PROPN
eurjchem-604	631	4	cpphchchphcp	cpphchchphcp	PROPN
eurjchem-604	631	5	and	and	CCONJ
eurjchem-604	631	6	addition	addition	NOUN
eurjchem-604	631	7	of	of	ADP
eurjchem-604	631	8	(	(	PUNCT
eurjchem-604	631	9	mecn)3m(co)3	mecn)3m(co)3	PROPN
eurjchem-604	631	10	(	(	PUNCT
eurjchem-604	631	11	m	m	PROPN
eurjchem-604	631	12	=	=	SYM
eurjchem-604	631	13	mo	mo	PROPN
eurjchem-604	631	14	,	,	PUNCT
eurjchem-604	631	15	w	w	NOUN
eurjchem-604	631	16	)	)	PUNCT
eurjchem-604	631	17	followed	follow	VERB
eurjchem-604	631	18	by	by	ADP
eurjchem-604	631	19	oxidation	oxidation	NOUN
eurjchem-604	631	20	with	with	ADP
eurjchem-604	631	21	2	2	NUM
eurjchem-604	631	22	equiv	equiv	NOUN
eurjchem-604	631	23	.	.	PUNCT
eurjchem-604	632	1	of	of	ADP
eurjchem-604	632	2	ferrocenium	ferrocenium	PROPN
eurjchem-604	632	3	tetrafluoroborate	tetrafluoroborate	PROPN
eurjchem-604	632	4	,	,	PUNCT
eurjchem-604	632	5	afford	afford	PROPN
eurjchem-604	632	6	(	(	PUNCT
eurjchem-604	632	7	phchchph)‐	phchchph)‐	NOUN
eurjchem-604	632	8	coupled	couple	VERB
eurjchem-604	632	9	bis(cyclopentadienyl	bis(cyclopentadienyl	NOUN
eurjchem-604	632	10	)	)	PUNCT
eurjchem-604	632	11	dinuclear	dinuclear	NOUN
eurjchem-604	632	12	molybdenum	molybdenum	NOUN
eurjchem-604	632	13	and	and	CCONJ
eurjchem-604	632	14	tungsten	tungsten	ADJ
eurjchem-604	632	15	complexes	complex	NOUN
eurjchem-604	632	16	[	[	X
eurjchem-604	632	17	186	186	NUM
eurjchem-604	632	18	]	]	PUNCT
eurjchem-604	632	19	.	.	PUNCT
eurjchem-604	633	1	4.3	4.3	NUM
eurjchem-604	633	2	.	.	PUNCT
eurjchem-604	633	3	metal	metal	NOUN
eurjchem-604	633	4	carbonyl	carbonyl	NOUN
eurjchem-604	633	5	complexes	complex	NOUN
eurjchem-604	633	6	with	with	ADP
eurjchem-604	633	7	tridentate	tridentate	ADJ
eurjchem-604	633	8	ligands	ligand	NOUN
eurjchem-604	633	9	the	the	DET
eurjchem-604	633	10	bicyclic	bicyclic	ADJ
eurjchem-604	633	11	triene	triene	NOUN
eurjchem-604	633	12	5,6‐dimethylenebicyclo	5,6‐dimethylenebicyclo	NUM
eurjchem-604	633	13	[	[	X
eurjchem-604	633	14	2.2.1]heptene‐2	2.2.1]heptene‐2	PROPN
eurjchem-604	633	15	has	have	AUX
eurjchem-604	633	16	been	be	AUX
eurjchem-604	633	17	found	find	VERB
eurjchem-604	633	18	to	to	PART
eurjchem-604	633	19	react	react	VERB
eurjchem-604	633	20	with	with	ADP
eurjchem-604	633	21	chromium	chromium	NOUN
eurjchem-604	633	22	,	,	PUNCT
eurjchem-604	633	23	molybdenum	molybdenum	NOUN
eurjchem-604	633	24	and	and	CCONJ
eurjchem-604	633	25	tungsten	tungsten	ADJ
eurjchem-604	633	26	hexacarbonyls	hexacarbonyls	PROPN
eurjchem-604	633	27	to	to	PART
eurjchem-604	633	28	produce	produce	VERB
eurjchem-604	633	29	volatile	volatile	ADJ
eurjchem-604	633	30	red‐to‐orange	red‐to‐orange	NOUN
eurjchem-604	633	31	crystalline	crystalline	ADJ
eurjchem-604	633	32	solids	solid	NOUN
eurjchem-604	633	33	of	of	ADP
eurjchem-604	633	34	composition	composition	NOUN
eurjchem-604	633	35	of	of	ADP
eurjchem-604	633	36	c9h10m(co)3	c9h10m(co)3	NOUN
eurjchem-604	633	37	[	[	X
eurjchem-604	633	38	187	187	NUM
eurjchem-604	633	39	]	]	PUNCT
eurjchem-604	633	40	.	.	PUNCT
eurjchem-604	634	1	reactions	reaction	NOUN
eurjchem-604	634	2	of	of	ADP
eurjchem-604	634	3	m(co)6	m(co)6	PROPN
eurjchem-604	634	4	,	,	PUNCT
eurjchem-604	634	5	where	where	SCONJ
eurjchem-604	634	6	m	m	VERB
eurjchem-604	634	7	=	=	SYM
eurjchem-604	634	8	cr	cr	PROPN
eurjchem-604	634	9	and	and	CCONJ
eurjchem-604	634	10	mo	mo	PROPN
eurjchem-604	634	11	with	with	ADP
eurjchem-604	634	12	schiff	schiff	NOUN
eurjchem-604	634	13	bases	basis	NOUN
eurjchem-604	634	14	prepared	prepare	VERB
eurjchem-604	634	15	by	by	ADP
eurjchem-604	634	16	the	the	DET
eurjchem-604	634	17	condensation	condensation	NOUN
eurjchem-604	634	18	of	of	ADP
eurjchem-604	634	19	ethanolamine	ethanolamine	NOUN
eurjchem-604	634	20	with	with	ADP
eurjchem-604	634	21	either	either	CCONJ
eurjchem-604	634	22	acetylacetone	acetylacetone	NOUN
eurjchem-604	634	23	or	or	CCONJ
eurjchem-604	634	24	benzoylacetone	benzoylacetone	NOUN
eurjchem-604	634	25	were	be	AUX
eurjchem-604	634	26	investigated	investigate	VERB
eurjchem-604	634	27	.	.	PUNCT
eurjchem-604	635	1	the	the	DET
eurjchem-604	635	2	reactions	reaction	NOUN
eurjchem-604	635	3	of	of	ADP
eurjchem-604	635	4	cr(co)6	cr(co)6	PROPN
eurjchem-604	635	5	in	in	ADP
eurjchem-604	635	6	benzene	benzene	NOUN
eurjchem-604	635	7	resulted	result	VERB
eurjchem-604	635	8	in	in	ADP
eurjchem-604	635	9	the	the	DET
eurjchem-604	635	10	formation	formation	NOUN
eurjchem-604	635	11	of	of	ADP
eurjchem-604	635	12	the	the	DET
eurjchem-604	635	13	tricarbonyl	tricarbonyl	NOUN
eurjchem-604	635	14	drivatives	drivative	VERB
eurjchem-604	635	15	[	[	X
eurjchem-604	635	16	cr(co)3(hl	cr(co)3(hl	NOUN
eurjchem-604	635	17	)	)	PUNCT
eurjchem-604	635	18	]	]	PUNCT
eurjchem-604	635	19	,	,	PUNCT
eurjchem-604	635	20	hl	hl	NOUN
eurjchem-604	635	21	=	=	PUNCT
eurjchem-604	635	22	acaceah	acaceah	PROPN
eurjchem-604	635	23	or	or	CCONJ
eurjchem-604	635	24	baceah	baceah	NOUN
eurjchem-604	635	25	.	.	PUNCT
eurjchem-604	636	1	the	the	DET
eurjchem-604	636	2	hl	hl	NOUN
eurjchem-604	636	3	proved	prove	VERB
eurjchem-604	636	4	to	to	PART
eurjchem-604	636	5	act	act	VERB
eurjchem-604	636	6	as	as	ADP
eurjchem-604	636	7	a	a	DET
eurjchem-604	636	8	tridentate	tridentate	ADJ
eurjchem-604	636	9	ligand	ligand	NOUN
eurjchem-604	636	10	[	[	X
eurjchem-604	636	11	188	188	NUM
eurjchem-604	636	12	]	]	PUNCT
eurjchem-604	636	13	.	.	PUNCT
eurjchem-604	637	1	salts	salt	NOUN
eurjchem-604	637	2	of	of	ADP
eurjchem-604	637	3	(	(	PUNCT
eurjchem-604	637	4	2‐	2‐	NUM
eurjchem-604	637	5	(	(	PUNCT
eurjchem-604	637	6	dimethylamino)ethyl)cyclopentadienyl	dimethylamino)ethyl)cyclopentadienyl	PROPN
eurjchem-604	637	7	(	(	PUNCT
eurjchem-604	637	8	cpn	cpn	NOUN
eurjchem-604	637	9	)	)	PUNCT
eurjchem-604	637	10	group	group	NOUN
eurjchem-604	637	11	vi	vi	NOUN
eurjchem-604	637	12	metal	metal	NOUN
eurjchem-604	637	13	carbonyl	carbonyl	NOUN
eurjchem-604	637	14	anions	anion	NOUN
eurjchem-604	637	15	(	(	PUNCT
eurjchem-604	637	16	[	[	X
eurjchem-604	637	17	m(co)3(η5‐cpn)]‐	m(co)3(η5‐cpn)]‐	X
eurjchem-604	637	18	(	(	PUNCT
eurjchem-604	637	19	m	m	PROPN
eurjchem-604	637	20	=	=	SYM
eurjchem-604	637	21	cr	cr	PROPN
eurjchem-604	637	22	,	,	PUNCT
eurjchem-604	637	23	mo	mo	PROPN
eurjchem-604	637	24	,	,	PUNCT
eurjchem-604	637	25	w	w	NOUN
eurjchem-604	637	26	)	)	PUNCT
eurjchem-604	637	27	)	)	PUNCT
eurjchem-604	637	28	were	be	AUX
eurjchem-604	637	29	reported	report	VERB
eurjchem-604	637	30	(	(	PUNCT
eurjchem-604	637	31	scheme	scheme	NOUN
eurjchem-604	637	32	46	46	NUM
eurjchem-604	637	33	)	)	PUNCT
eurjchem-604	638	1	[	[	X
eurjchem-604	638	2	189	189	NUM
eurjchem-604	638	3	]	]	PUNCT
eurjchem-604	638	4	.	.	PUNCT
eurjchem-604	639	1	the	the	DET
eurjchem-604	639	2	modification	modification	NOUN
eurjchem-604	639	3	of	of	ADP
eurjchem-604	639	4	bis(pyrazol‐1‐yl)methane	bis(pyrazol‐1‐yl)methane	NOUN
eurjchem-604	639	5	by	by	ADP
eurjchem-604	639	6	sulfur	sulfur	NOUN
eurjchem-604	639	7	or	or	CCONJ
eurjchem-604	639	8	selenium	selenium	NOUN
eurjchem-604	639	9	on	on	ADP
eurjchem-604	639	10	the	the	DET
eurjchem-604	639	11	methine	methine	ADJ
eurjchem-604	639	12	carbon	carbon	NOUN
eurjchem-604	639	13	has	have	AUX
eurjchem-604	639	14	been	be	AUX
eurjchem-604	639	15	successfully	successfully	ADV
eurjchem-604	639	16	carried	carry	VERB
eurjchem-604	639	17	out	out	ADP
eurjchem-604	639	18	by	by	ADP
eurjchem-604	639	19	the	the	DET
eurjchem-604	639	20	reaction	reaction	NOUN
eurjchem-604	639	21	of	of	ADP
eurjchem-604	639	22	the	the	DET
eurjchem-604	639	23	bis(pyrazol‐1‐yl)methide	bis(pyrazol‐1‐yl)methide	PROPN
eurjchem-604	639	24	anion	anion	NOUN
eurjchem-604	639	25	,	,	PUNCT
eurjchem-604	639	26	prepared	prepare	VERB
eurjchem-604	639	27	in	in	ADP
eurjchem-604	639	28	situ	situ	NOUN
eurjchem-604	639	29	by	by	ADP
eurjchem-604	639	30	the	the	DET
eurjchem-604	639	31	reaction	reaction	NOUN
eurjchem-604	639	32	of	of	ADP
eurjchem-604	639	33	bis(pyrazol‐1‐yl)methane	bis(pyrazol‐1‐yl)methane	NOUN
eurjchem-604	639	34	with	with	ADP
eurjchem-604	639	35	n‐buli	n‐buli	PUNCT
eurjchem-604	639	36	,	,	PUNCT
eurjchem-604	639	37	with	with	ADP
eurjchem-604	639	38	elemental	elemental	ADJ
eurjchem-604	639	39	sulfur	sulfur	NOUN
eurjchem-604	639	40	or	or	CCONJ
eurjchem-604	639	41	selenium	selenium	NOUN
eurjchem-604	639	42	.	.	PUNCT
eurjchem-604	640	1	these	these	DET
eurjchem-604	640	2	bis(pyrazol‐1‐yl)methylthiolate(scheme	bis(pyrazol‐1‐yl)methylthiolate(scheme	NOUN
eurjchem-604	640	3	47	47	NUM
eurjchem-604	640	4	)	)	PUNCT
eurjchem-604	640	5	or	or	CCONJ
eurjchem-604	640	6	selenolate	selenolate	ADJ
eurjchem-604	640	7	anions	anion	NOUN
eurjchem-604	640	8	reacted	react	VERB
eurjchem-604	640	9	with	with	ADP
eurjchem-604	640	10	m(co)6	m(co)6	NOUN
eurjchem-604	640	11	(	(	PUNCT
eurjchem-604	640	12	m	m	PROPN
eurjchem-604	640	13	=	=	VERB
eurjchem-604	640	14	mo	mo	PROPN
eurjchem-604	640	15	or	or	CCONJ
eurjchem-604	640	16	w	w	NOUN
eurjchem-604	640	17	)	)	PUNCT
eurjchem-604	640	18	in	in	ADP
eurjchem-604	640	19	thf	thf	NOUN
eurjchem-604	640	20	and	and	CCONJ
eurjchem-604	640	21	formed	form	VERB
eurjchem-604	640	22	their	their	PRON
eurjchem-604	640	23	tricarbonyl	tricarbonyl	ADJ
eurjchem-604	640	24	metal	metal	NOUN
eurjchem-604	640	25	anionsch(pz)2em(co)3‐	anionsch(pz)2em(co)3‐	NOUN
eurjchem-604	641	1	[	[	X
eurjchem-604	641	2	190	190	NUM
eurjchem-604	641	3	]	]	PUNCT
eurjchem-604	641	4	.	.	PUNCT
eurjchem-604	642	1	scheme	scheme	NOUN
eurjchem-604	642	2	46	46	NUM
eurjchem-604	642	3	scheme	scheme	NOUN
eurjchem-604	642	4	47	47	NUM
eurjchem-604	642	5	retracted	retract	VERB
eurjchem-604	642	6	382	382	NUM
eurjchem-604	642	7	kaushik	kaushik	NOUN
eurjchem-604	642	8	et	et	PROPN
eurjchem-604	642	9	al	al	PROPN
eurjchem-604	642	10	.	.	PUNCT
eurjchem-604	642	11	/	/	SYM
eurjchem-604	642	12	european	european	PROPN
eurjchem-604	642	13	journal	journal	PROPN
eurjchem-604	642	14	of	of	ADP
eurjchem-604	642	15	chemistry	chemistry	NOUN
eurjchem-604	642	16	3	3	NUM
eurjchem-604	642	17	(	(	PUNCT
eurjchem-604	642	18	3	3	NUM
eurjchem-604	642	19	)	)	PUNCT
eurjchem-604	642	20	(	(	PUNCT
eurjchem-604	642	21	2012	2012	NUM
eurjchem-604	642	22	)	)	PUNCT
eurjchem-604	642	23	367‐394	367‐394	NOUN
eurjchem-604	643	1	the	the	DET
eurjchem-604	643	2	potential	potential	ADJ
eurjchem-604	643	3	use	use	NOUN
eurjchem-604	643	4	of	of	ADP
eurjchem-604	643	5	haptotropic	haptotropic	ADJ
eurjchem-604	643	6	shifts	shift	NOUN
eurjchem-604	643	7	to	to	PART
eurjchem-604	643	8	control	control	VERB
eurjchem-604	643	9	rotational	rotational	ADJ
eurjchem-604	643	10	barriers	barrier	NOUN
eurjchem-604	643	11	has	have	AUX
eurjchem-604	643	12	been	be	AUX
eurjchem-604	643	13	initiated	initiate	VERB
eurjchem-604	643	14	by	by	ADP
eurjchem-604	643	15	the	the	DET
eurjchem-604	643	16	synthesis	synthesis	NOUN
eurjchem-604	643	17	of	of	ADP
eurjchem-604	643	18	(	(	PUNCT
eurjchem-604	643	19	9‐indenyl	9‐indenyl	NUM
eurjchem-604	643	20	)	)	PUNCT
eurjchem-604	643	21	triptycene	triptycene	NOUN
eurjchem-604	643	22	and	and	CCONJ
eurjchem-604	643	23	its	its	PRON
eurjchem-604	643	24	chromium	chromium	NOUN
eurjchem-604	643	25	tricarbonyl	tricarbonyl	NOUN
eurjchem-604	643	26	derivative	derivative	NOUN
eurjchem-604	643	27	.	.	PUNCT
eurjchem-604	644	1	in	in	ADP
eurjchem-604	644	2	the	the	DET
eurjchem-604	644	3	metal	metal	NOUN
eurjchem-604	644	4	complex	complex	NOUN
eurjchem-604	644	5	,	,	PUNCT
eurjchem-604	644	6	the	the	DET
eurjchem-604	644	7	chromium	chromium	NOUN
eurjchem-604	644	8	carbonyl	carbonyl	NOUN
eurjchem-604	644	9	moiety	moiety	NOUN
eurjchem-604	644	10	coordinates	coordinate	NOUN
eurjchem-604	644	11	to	to	ADP
eurjchem-604	644	12	one	one	NUM
eurjchem-604	644	13	of	of	ADP
eurjchem-604	644	14	the	the	DET
eurjchem-604	644	15	blades	blade	NOUN
eurjchem-604	644	16	of	of	ADP
eurjchem-604	644	17	the	the	DET
eurjchem-604	644	18	triptycene	triptycene	NOUN
eurjchem-604	644	19	unit	unit	NOUN
eurjchem-604	644	20	rather	rather	ADV
eurjchem-604	644	21	than	than	ADP
eurjchem-604	644	22	to	to	ADP
eurjchem-604	644	23	the	the	DET
eurjchem-604	644	24	more	more	ADV
eurjchem-604	644	25	crowded	crowded	ADJ
eurjchem-604	644	26	indenyl	indenyl	NOUN
eurjchem-604	644	27	group	group	NOUN
eurjchem-604	644	28	(	(	PUNCT
eurjchem-604	644	29	scheme48	scheme48	NOUN
eurjchem-604	644	30	)	)	PUNCT
eurjchem-604	645	1	[	[	X
eurjchem-604	645	2	191	191	NUM
eurjchem-604	645	3	]	]	PUNCT
eurjchem-604	645	4	.	.	PUNCT
eurjchem-604	646	1	scheme	scheme	NOUN
eurjchem-604	646	2	48	48	NUM
eurjchem-604	646	3	organotransition‐metal	organotransition‐metal	ADJ
eurjchem-604	646	4	complexes	complex	NOUN
eurjchem-604	646	5	of	of	ADP
eurjchem-604	646	6	tridentate	tridentate	ADJ
eurjchem-604	646	7	ligands	ligand	NOUN
eurjchem-604	646	8	were	be	AUX
eurjchem-604	646	9	synthesized	synthesize	VERB
eurjchem-604	646	10	by	by	ADP
eurjchem-604	646	11	shiu	shiu	PROPN
eurjchem-604	646	12	and	and	CCONJ
eurjchem-604	646	13	chou	chou	PROPN
eurjchem-604	646	14	and	and	CCONJ
eurjchem-604	646	15	their	their	PRON
eurjchem-604	646	16	structure	structure	NOUN
eurjchem-604	646	17	and	and	CCONJ
eurjchem-604	646	18	reactivity	reactivity	NOUN
eurjchem-604	646	19	of	of	ADP
eurjchem-604	646	20	first	first	ADJ
eurjchem-604	646	21	intramolecular	intramolecular	ADJ
eurjchem-604	646	22	coordination	coordination	NOUN
eurjchem-604	646	23	compound	compound	NOUN
eurjchem-604	646	24	with	with	ADP
eurjchem-604	646	25	weakely	weakely	ADV
eurjchem-604	646	26	bound	bind	VERB
eurjchem-604	646	27	ƞ2‐arene	ƞ2‐arene	NUM
eurjchem-604	646	28	have	have	AUX
eurjchem-604	646	29	been	be	AUX
eurjchem-604	646	30	done	do	VERB
eurjchem-604	646	31	.	.	PUNCT
eurjchem-604	647	1	they	they	PRON
eurjchem-604	647	2	found	find	VERB
eurjchem-604	647	3	that	that	DET
eurjchem-604	647	4	thermolysis	thermolysis	NOUN
eurjchem-604	647	5	of	of	ADP
eurjchem-604	647	6	(	(	PUNCT
eurjchem-604	647	7	phhcpz’2)mo(co)4	phhcpz’2)mo(co)4	PROPN
eurjchem-604	647	8	in	in	ADP
eurjchem-604	647	9	dme	dme	PROPN
eurjchem-604	647	10	gives	give	VERB
eurjchem-604	647	11	(	(	PUNCT
eurjchem-604	647	12	phhcpz’2)mo(co)3	phhcpz’2)mo(co)3	ADJ
eurjchem-604	647	13	(	(	PUNCT
eurjchem-604	647	14	pz	pz	NOUN
eurjchem-604	647	15	’	'	PUNCT
eurjchem-604	647	16	=	=	SYM
eurjchem-604	647	17	3,5‐dimethylpyrazol‐1‐yl	3,5‐dimethylpyrazol‐1‐yl	NUM
eurjchem-604	647	18	)	)	PUNCT
eurjchem-604	648	1	[	[	X
eurjchem-604	648	2	192	192	NUM
eurjchem-604	648	3	]	]	SYM
eurjchem-604	648	4	.	.	PUNCT
eurjchem-604	649	1	5	5	X
eurjchem-604	649	2	.	.	X
eurjchem-604	649	3	some	some	DET
eurjchem-604	649	4	cluster	cluster	NOUN
eurjchem-604	649	5	complexes	complex	NOUN
eurjchem-604	649	6	of	of	ADP
eurjchem-604	649	7	g‐6	g‐6	VERB
eurjchem-604	649	8	metal	metal	NOUN
eurjchem-604	649	9	carbonyl	carbonyl	NOUN
eurjchem-604	649	10	complexes	complexe	VERB
eurjchem-604	649	11	the	the	DET
eurjchem-604	649	12	phrase	phrase	NOUN
eurjchem-604	649	13	cluster	cluster	NOUN
eurjchem-604	649	14	was	be	AUX
eurjchem-604	649	15	coined	coin	VERB
eurjchem-604	649	16	by	by	ADP
eurjchem-604	649	17	f.	f.	PROPN
eurjchem-604	649	18	a.	a.	NOUN
eurjchem-604	649	19	cotton	cotton	NOUN
eurjchem-604	649	20	in	in	ADP
eurjchem-604	649	21	the	the	DET
eurjchem-604	649	22	early	early	ADJ
eurjchem-604	649	23	1960s	1960	NOUN
eurjchem-604	649	24	to	to	PART
eurjchem-604	649	25	refer	refer	VERB
eurjchem-604	649	26	to	to	ADP
eurjchem-604	649	27	compounds	compound	NOUN
eurjchem-604	649	28	containing	contain	VERB
eurjchem-604	649	29	metal‐metal	metal‐metal	ADJ
eurjchem-604	649	30	bonds	bond	NOUN
eurjchem-604	649	31	.	.	PUNCT
eurjchem-604	650	1	in	in	ADP
eurjchem-604	650	2	1990	1990	NUM
eurjchem-604	650	3	mingos	mingo	NOUN
eurjchem-604	650	4	and	and	CCONJ
eurjchem-604	650	5	wales	wale	NOUN
eurjchem-604	650	6	explain	explain	VERB
eurjchem-604	650	7	cluster	cluster	NOUN
eurjchem-604	650	8	as	as	ADP
eurjchem-604	650	9	a	a	DET
eurjchem-604	650	10	compound	compound	NOUN
eurjchem-604	650	11	contains	contain	VERB
eurjchem-604	650	12	a	a	DET
eurjchem-604	650	13	group	group	NOUN
eurjchem-604	650	14	of	of	ADP
eurjchem-604	650	15	two	two	NUM
eurjchem-604	650	16	or	or	CCONJ
eurjchem-604	650	17	more	more	ADJ
eurjchem-604	650	18	metal	metal	NOUN
eurjchem-604	650	19	atoms	atom	NOUN
eurjchem-604	650	20	where	where	SCONJ
eurjchem-604	650	21	direct	direct	ADJ
eurjchem-604	650	22	and	and	CCONJ
eurjchem-604	650	23	substantial	substantial	ADJ
eurjchem-604	650	24	metal	metal	NOUN
eurjchem-604	650	25	metal	metal	NOUN
eurjchem-604	650	26	bonding	bonding	NOUN
eurjchem-604	650	27	is	be	AUX
eurjchem-604	650	28	present	present	ADJ
eurjchem-604	651	1	[	[	X
eurjchem-604	651	2	193	193	NUM
eurjchem-604	651	3	]	]	PUNCT
eurjchem-604	651	4	.	.	PUNCT
eurjchem-604	652	1	a	a	DET
eurjchem-604	652	2	cluster	cluster	NOUN
eurjchem-604	652	3	is	be	AUX
eurjchem-604	652	4	an	an	DET
eurjchem-604	652	5	ensemble	ensemble	NOUN
eurjchem-604	652	6	of	of	ADP
eurjchem-604	652	7	bound	bind	VERB
eurjchem-604	652	8	atoms	atom	NOUN
eurjchem-604	652	9	intermediate	intermediate	ADJ
eurjchem-604	652	10	in	in	ADP
eurjchem-604	652	11	size	size	NOUN
eurjchem-604	652	12	between	between	ADP
eurjchem-604	652	13	a	a	DET
eurjchem-604	652	14	molecule	molecule	NOUN
eurjchem-604	652	15	and	and	CCONJ
eurjchem-604	652	16	a	a	DET
eurjchem-604	652	17	bulk	bulk	ADJ
eurjchem-604	652	18	solid	solid	NOUN
eurjchem-604	652	19	.	.	PUNCT
eurjchem-604	653	1	transition	transition	NOUN
eurjchem-604	653	2	metals	metal	NOUN
eurjchem-604	653	3	and	and	CCONJ
eurjchem-604	653	4	main	main	ADJ
eurjchem-604	653	5	group	group	NOUN
eurjchem-604	653	6	elements	element	NOUN
eurjchem-604	653	7	form	form	VERB
eurjchem-604	653	8	strong	strong	ADJ
eurjchem-604	653	9	clusters	cluster	NOUN
eurjchem-604	653	10	[	[	X
eurjchem-604	653	11	194	194	NUM
eurjchem-604	653	12	]	]	PUNCT
eurjchem-604	653	13	.	.	PUNCT
eurjchem-604	654	1	the	the	DET
eurjchem-604	654	2	main	main	ADJ
eurjchem-604	654	3	cluster	cluster	NOUN
eurjchem-604	654	4	types	type	NOUN
eurjchem-604	654	5	are	be	AUX
eurjchem-604	654	6	"	"	PUNCT
eurjchem-604	654	7	naked	naked	ADJ
eurjchem-604	654	8	"	"	PUNCT
eurjchem-604	654	9	clusters	cluster	NOUN
eurjchem-604	654	10	(	(	PUNCT
eurjchem-604	654	11	without	without	ADP
eurjchem-604	654	12	stabilizing	stabilize	VERB
eurjchem-604	654	13	ligands	ligand	NOUN
eurjchem-604	654	14	)	)	PUNCT
eurjchem-604	654	15	and	and	CCONJ
eurjchem-604	654	16	those	those	PRON
eurjchem-604	654	17	with	with	ADP
eurjchem-604	654	18	ligands	ligand	NOUN
eurjchem-604	654	19	.	.	PUNCT
eurjchem-604	655	1	for	for	ADP
eurjchem-604	655	2	transition	transition	NOUN
eurjchem-604	655	3	metal	metal	NOUN
eurjchem-604	655	4	clusters	cluster	NOUN
eurjchem-604	655	5	,	,	PUNCT
eurjchem-604	655	6	typical	typical	ADJ
eurjchem-604	655	7	stabilizing	stabilize	VERB
eurjchem-604	655	8	ligands	ligand	NOUN
eurjchem-604	655	9	include	include	VERB
eurjchem-604	655	10	carbon	carbon	NOUN
eurjchem-604	655	11	monoxide	monoxide	NOUN
eurjchem-604	655	12	,	,	PUNCT
eurjchem-604	655	13	halides	halide	NOUN
eurjchem-604	655	14	,	,	PUNCT
eurjchem-604	655	15	isocyanides	isocyanide	NOUN
eurjchem-604	655	16	,	,	PUNCT
eurjchem-604	655	17	alkenes	alkene	NOUN
eurjchem-604	655	18	,	,	PUNCT
eurjchem-604	655	19	and	and	CCONJ
eurjchem-604	655	20	hydrides	hydride	NOUN
eurjchem-604	655	21	.	.	PUNCT
eurjchem-604	656	1	for	for	ADP
eurjchem-604	656	2	main	main	ADJ
eurjchem-604	656	3	group	group	NOUN
eurjchem-604	656	4	elements	element	NOUN
eurjchem-604	656	5	,	,	PUNCT
eurjchem-604	656	6	typical	typical	ADJ
eurjchem-604	656	7	clusters	cluster	NOUN
eurjchem-604	656	8	are	be	AUX
eurjchem-604	656	9	stabilized	stabilize	VERB
eurjchem-604	656	10	by	by	ADP
eurjchem-604	656	11	hydride	hydride	NOUN
eurjchem-604	656	12	ligands	ligand	NOUN
eurjchem-604	656	13	.	.	PUNCT
eurjchem-604	657	1	transition	transition	NOUN
eurjchem-604	657	2	metal	metal	NOUN
eurjchem-604	657	3	clusters	cluster	NOUN
eurjchem-604	657	4	are	be	AUX
eurjchem-604	657	5	frequently	frequently	ADV
eurjchem-604	657	6	composed	compose	VERB
eurjchem-604	657	7	of	of	ADP
eurjchem-604	657	8	refractory	refractory	NOUN
eurjchem-604	657	9	metal	metal	NOUN
eurjchem-604	657	10	atoms	atom	NOUN
eurjchem-604	657	11	.	.	PUNCT
eurjchem-604	658	1	in	in	ADP
eurjchem-604	658	2	general	general	ADJ
eurjchem-604	658	3	metal	metal	NOUN
eurjchem-604	658	4	centers	center	NOUN
eurjchem-604	658	5	with	with	ADP
eurjchem-604	658	6	extended	extended	ADJ
eurjchem-604	658	7	d‐orbitals	d‐orbital	NOUN
eurjchem-604	658	8	form	form	NOUN
eurjchem-604	658	9	stable	stable	ADJ
eurjchem-604	658	10	clusters	cluster	NOUN
eurjchem-604	658	11	because	because	SCONJ
eurjchem-604	658	12	of	of	ADP
eurjchem-604	658	13	favorable	favorable	ADJ
eurjchem-604	658	14	overlap	overlap	NOUN
eurjchem-604	658	15	of	of	ADP
eurjchem-604	658	16	valence	valence	NOUN
eurjchem-604	658	17	orbitals	orbital	NOUN
eurjchem-604	658	18	.	.	PUNCT
eurjchem-604	659	1	thus	thus	ADV
eurjchem-604	659	2	,	,	PUNCT
eurjchem-604	659	3	metals	metal	NOUN
eurjchem-604	659	4	with	with	ADP
eurjchem-604	659	5	a	a	DET
eurjchem-604	659	6	low	low	ADJ
eurjchem-604	659	7	oxidation	oxidation	NOUN
eurjchem-604	659	8	state	state	NOUN
eurjchem-604	659	9	for	for	ADP
eurjchem-604	659	10	the	the	DET
eurjchem-604	659	11	later	later	ADJ
eurjchem-604	659	12	metals	metal	NOUN
eurjchem-604	659	13	and	and	CCONJ
eurjchem-604	659	14	mid‐	mid‐	NOUN
eurjchem-604	659	15	oxidation	oxidation	NOUN
eurjchem-604	659	16	states	state	NOUN
eurjchem-604	659	17	for	for	ADP
eurjchem-604	659	18	the	the	DET
eurjchem-604	659	19	early	early	ADJ
eurjchem-604	659	20	metals	metal	NOUN
eurjchem-604	659	21	tend	tend	VERB
eurjchem-604	659	22	to	to	PART
eurjchem-604	659	23	form	form	VERB
eurjchem-604	659	24	stable	stable	ADJ
eurjchem-604	659	25	clusters	cluster	NOUN
eurjchem-604	659	26	.	.	PUNCT
eurjchem-604	660	1	polynuclear	polynuclear	PROPN
eurjchem-604	660	2	metal	metal	NOUN
eurjchem-604	660	3	carbonyls	carbonyl	NOUN
eurjchem-604	660	4	are	be	AUX
eurjchem-604	660	5	generally	generally	ADV
eurjchem-604	660	6	found	find	VERB
eurjchem-604	660	7	in	in	ADP
eurjchem-604	660	8	late	late	ADJ
eurjchem-604	660	9	transition	transition	NOUN
eurjchem-604	660	10	metals	metal	NOUN
eurjchem-604	660	11	with	with	ADP
eurjchem-604	660	12	low	low	ADJ
eurjchem-604	660	13	formal	formal	ADJ
eurjchem-604	660	14	oxidation	oxidation	NOUN
eurjchem-604	660	15	states	state	NOUN
eurjchem-604	660	16	.	.	PUNCT
eurjchem-604	661	1	braunstein	braunstein	ADV
eurjchem-604	661	2	et	et	PROPN
eurjchem-604	661	3	al	al	PROPN
eurjchem-604	661	4	.	.	PROPN
eurjchem-604	661	5	gives	give	VERB
eurjchem-604	661	6	a	a	DET
eurjchem-604	661	7	review	review	NOUN
eurjchem-604	661	8	of	of	ADP
eurjchem-604	661	9	metal	metal	NOUN
eurjchem-604	661	10	clusters	cluster	NOUN
eurjchem-604	661	11	in	in	ADP
eurjchem-604	661	12	chemistry	chemistry	NOUN
eurjchem-604	661	13	[	[	X
eurjchem-604	661	14	195	195	NUM
eurjchem-604	661	15	]	]	PUNCT
eurjchem-604	661	16	.	.	PUNCT
eurjchem-604	662	1	types	type	NOUN
eurjchem-604	662	2	of	of	ADP
eurjchem-604	662	3	clusters	cluster	NOUN
eurjchem-604	662	4	formed	form	VERB
eurjchem-604	662	5	by	by	ADP
eurjchem-604	662	6	metal	metal	NOUN
eurjchem-604	662	7	carbonyls	carbonyls	NOUN
eurjchem-604	662	8	:	:	PUNCT
eurjchem-604	662	9	generally	generally	ADV
eurjchem-604	662	10	the	the	DET
eurjchem-604	662	11	clusters	cluster	NOUN
eurjchem-604	662	12	referred	refer	VERB
eurjchem-604	662	13	to	to	PART
eurjchem-604	662	14	have	have	VERB
eurjchem-604	662	15	more	more	ADJ
eurjchem-604	662	16	than	than	ADP
eurjchem-604	662	17	one	one	NUM
eurjchem-604	662	18	metal	metal	NOUN
eurjchem-604	662	19	atom	atom	NOUN
eurjchem-604	662	20	.	.	PUNCT
eurjchem-604	663	1	these	these	DET
eurjchem-604	663	2	metal	metal	NOUN
eurjchem-604	663	3	clusters	cluster	NOUN
eurjchem-604	663	4	may	may	AUX
eurjchem-604	663	5	be	be	AUX
eurjchem-604	663	6	homonuclear	homonuclear	NOUN
eurjchem-604	663	7	or	or	CCONJ
eurjchem-604	663	8	heteronuclear	heteronuclear	ADJ
eurjchem-604	663	9	.	.	PUNCT
eurjchem-604	664	1	5.1	5.1	NUM
eurjchem-604	664	2	.	.	PUNCT
eurjchem-604	665	1	homonuclear	homonuclear	PROPN
eurjchem-604	665	2	clusters	cluster	NOUN
eurjchem-604	665	3	homonuclear	homonuclear	PROPN
eurjchem-604	665	4	refers	refer	VERB
eurjchem-604	665	5	to	to	ADP
eurjchem-604	665	6	a	a	DET
eurjchem-604	665	7	cluster	cluster	NOUN
eurjchem-604	665	8	with	with	ADP
eurjchem-604	665	9	only	only	ADV
eurjchem-604	665	10	one	one	NUM
eurjchem-604	665	11	metal	metal	NOUN
eurjchem-604	665	12	element	element	NOUN
eurjchem-604	665	13	.	.	PUNCT
eurjchem-604	666	1	dinuclear	dinuclear	ADJ
eurjchem-604	666	2	metal	metal	NOUN
eurjchem-604	666	3	(	(	PUNCT
eurjchem-604	666	4	i	i	NOUN
eurjchem-604	666	5	)	)	PUNCT
eurjchem-604	666	6	carbonyl	carbonyl	NOUN
eurjchem-604	666	7	thiolates	thiolate	NOUN
eurjchem-604	667	1	[	[	X
eurjchem-604	667	2	w2(sph)2(co)8	w2(sph)2(co)8	X
eurjchem-604	667	3	]	]	X
eurjchem-604	667	4	,	,	PUNCT
eurjchem-604	667	5	[	[	X
eurjchem-604	667	6	mo2(sph)3(co)6]−	mo2(sph)3(co)6]−	X
eurjchem-604	667	7	,	,	PUNCT
eurjchem-604	667	8	[	[	X
eurjchem-604	667	9	mo2(sph)2(co)6	mo2(sph)2(co)6	X
eurjchem-604	667	10	(	(	PUNCT
eurjchem-604	667	11	s2cnet2)]−	s2cnet2)]−	PROPN
eurjchem-604	667	12	,	,	PUNCT
eurjchem-604	667	13	[	[	X
eurjchem-604	667	14	w2(sph)2(co)6dppm	w2(sph)2(co)6dppm	X
eurjchem-604	667	15	]	]	X
eurjchem-604	667	16	and	and	CCONJ
eurjchem-604	667	17	a	a	DET
eurjchem-604	667	18	polymer	polymer	NOUN
eurjchem-604	667	19	[	[	X
eurjchem-604	667	20	w2(sph)2	w2(sph)2	PROPN
eurjchem-604	667	21	(	(	PUNCT
eurjchem-604	667	22	co)6dppm]n	co)6dppm]n	PROPN
eurjchem-604	667	23	were	be	AUX
eurjchem-604	667	24	synthesized	synthesize	VERB
eurjchem-604	667	25	by	by	ADP
eurjchem-604	667	26	the	the	DET
eurjchem-604	667	27	reaction	reaction	NOUN
eurjchem-604	667	28	of	of	ADP
eurjchem-604	667	29	m2(sph)2(co)8	m2(sph)2(co)8	NOUN
eurjchem-604	667	30	]	]	X
eurjchem-604	667	31	(	(	PUNCT
eurjchem-604	667	32	m	m	PROPN
eurjchem-604	667	33	=	=	NOUN
eurjchem-604	667	34	mo	mo	PROPN
eurjchem-604	667	35	,	,	PUNCT
eurjchem-604	667	36	w	w	PROPN
eurjchem-604	667	37	)	)	PUNCT
eurjchem-604	667	38	with	with	ADP
eurjchem-604	667	39	appropriate	appropriate	ADJ
eurjchem-604	667	40	nasr	nasr	PROPN
eurjchem-604	667	41	(	(	PUNCT
eurjchem-604	667	42	sr	sr	PROPN
eurjchem-604	667	43	=	=	PROPN
eurjchem-604	667	44	sc6h5	sc6h5	PROPN
eurjchem-604	667	45	,	,	PUNCT
eurjchem-604	667	46	s2cnet2	s2cnet2	NOUN
eurjchem-604	667	47	)	)	PUNCT
eurjchem-604	667	48	ligands	ligand	NOUN
eurjchem-604	667	49	in	in	ADP
eurjchem-604	667	50	the	the	DET
eurjchem-604	667	51	presence	presence	NOUN
eurjchem-604	667	52	of	of	ADP
eurjchem-604	667	53	tetra‐alkylammonium	tetra‐alkylammonium	NOUN
eurjchem-604	667	54	halide	halide	NOUN
eurjchem-604	667	55	,	,	PUNCT
eurjchem-604	667	56	or	or	CCONJ
eurjchem-604	667	57	with	with	ADP
eurjchem-604	667	58	diphenylphosphinemethane	diphenylphosphinemethane	NOUN
eurjchem-604	667	59	(	(	PUNCT
eurjchem-604	667	60	dppm=(c6h5)2p	dppm=(c6h5)2p	ADJ
eurjchem-604	667	61	ch2p	ch2p	PROPN
eurjchem-604	667	62	(	(	PUNCT
eurjchem-604	667	63	c6h5)2	c6h5)2	NOUN
eurjchem-604	667	64	)	)	PUNCT
eurjchem-604	667	65	in	in	ADP
eurjchem-604	667	66	certain	certain	ADJ
eurjchem-604	667	67	solvents	solvent	NOUN
eurjchem-604	667	68	[	[	X
eurjchem-604	667	69	196	196	NUM
eurjchem-604	667	70	]	]	PUNCT
eurjchem-604	667	71	.	.	PUNCT
eurjchem-604	668	1	the	the	DET
eurjchem-604	668	2	32‐electron	32‐electron	NUM
eurjchem-604	668	3	complex	complex	NOUN
eurjchem-604	668	4	[	[	X
eurjchem-604	668	5	mo2cp2(μ‐come)(μ‐pcy2)(co)2	mo2cp2(μ‐come)(μ‐pcy2)(co)2	X
eurjchem-604	668	6	]	]	X
eurjchem-604	668	7	(	(	PUNCT
eurjchem-604	668	8	cp	cp	INTJ
eurjchem-604	668	9	=	=	SYM
eurjchem-604	668	10	η5‐c5h5	η5‐c5h5	PROPN
eurjchem-604	668	11	)	)	PUNCT
eurjchem-604	668	12	reacts	react	VERB
eurjchem-604	668	13	at	at	ADP
eurjchem-604	668	14	333	333	NUM
eurjchem-604	668	15	k	k	NOUN
eurjchem-604	668	16	with	with	ADP
eurjchem-604	668	17	terminal	terminal	ADJ
eurjchem-604	668	18	alkynes	alkyne	NOUN
eurjchem-604	668	19	rc≡cr	rc≡cr	PROPN
eurjchem-604	668	20	to	to	PART
eurjchem-604	668	21	give	give	VERB
eurjchem-604	668	22	the	the	DET
eurjchem-604	668	23	corresponding	correspond	VERB
eurjchem-604	668	24	derivatives	derivative	NOUN
eurjchem-604	669	1	[	[	X
eurjchem-604	669	2	mo2cp2{μ‐κ2	mo2cp2{μ‐κ2	NUM
eurjchem-604	669	3	:	:	PUNCT
eurjchem-604	669	4	η3‐crchc(ome)}(μ‐	η3‐crchc(ome)}(μ‐	NOUN
eurjchem-604	669	5	pcy2)(co)2	pcy2)(co)2	NOUN
eurjchem-604	669	6	]	]	PUNCT
eurjchem-604	669	7	,	,	PUNCT
eurjchem-604	669	8	(	(	PUNCT
eurjchem-604	669	9	r	r	NOUN
eurjchem-604	669	10	=	=	SYM
eurjchem-604	669	11	p‐tol	p‐tol	PROPN
eurjchem-604	669	12	,	,	PUNCT
eurjchem-604	669	13	co2me	co2me	PROPN
eurjchem-604	669	14	)	)	PUNCT
eurjchem-604	669	15	,	,	PUNCT
eurjchem-604	669	16	with	with	ADP
eurjchem-604	669	17	good	good	ADJ
eurjchem-604	669	18	yields	yield	NOUN
eurjchem-604	669	19	(	(	PUNCT
eurjchem-604	669	20	scheme	scheme	NOUN
eurjchem-604	669	21	49	49	NUM
eurjchem-604	669	22	)	)	PUNCT
eurjchem-604	670	1	[	[	X
eurjchem-604	670	2	197	197	NUM
eurjchem-604	670	3	]	]	PUNCT
eurjchem-604	670	4	.	.	PUNCT
eurjchem-604	671	1	scheme	scheme	NOUN
eurjchem-604	671	2	49	49	NUM
eurjchem-604	671	3	di‐nuclear	di‐nuclear	ADJ
eurjchem-604	671	4	molybdenum	molybdenum	NOUN
eurjchem-604	671	5	and	and	CCONJ
eurjchem-604	671	6	tungsten	tungsten	ADJ
eurjchem-604	671	7	metal	metal	NOUN
eurjchem-604	671	8	cluster	cluster	NOUN
eurjchem-604	671	9	complexes	complex	NOUN
eurjchem-604	672	1	[	[	X
eurjchem-604	672	2	et4n]2	et4n]2	X
eurjchem-604	672	3	[	[	X
eurjchem-604	672	4	mo2(sc6h11)2(co)8	mo2(sc6h11)2(co)8	NOUN
eurjchem-604	672	5	]	]	X
eurjchem-604	672	6	,	,	PUNCT
eurjchem-604	673	1	[	[	X
eurjchem-604	673	2	et4n	et4n	X
eurjchem-604	673	3	]	]	X
eurjchem-604	673	4	[	[	X
eurjchem-604	673	5	mo2(sc6h11)3(co)6	mo2(sc6h11)3(co)6	X
eurjchem-604	673	6	]	]	X
eurjchem-604	673	7	,	,	PUNCT
eurjchem-604	673	8	[	[	X
eurjchem-604	673	9	ph4p	ph4p	X
eurjchem-604	673	10	]	]	X
eurjchem-604	673	11	[	[	X
eurjchem-604	673	12	mo2(sc6h11)3(co)6	mo2(sc6h11)3(co)6	X
eurjchem-604	673	13	]	]	X
eurjchem-604	673	14	,	,	PUNCT
eurjchem-604	673	15	[	[	X
eurjchem-604	673	16	(	(	PUNCT
eurjchem-604	673	17	ch3)3phch2n	ch3)3phch2n	NOUN
eurjchem-604	673	18	]	]	X
eurjchem-604	674	1	[	[	X
eurjchem-604	674	2	mo2(sc6h11)3(co)6	mo2(sc6h11)3(co)6	X
eurjchem-604	674	3	]	]	X
eurjchem-604	674	4	,	,	PUNCT
eurjchem-604	674	5	[	[	X
eurjchem-604	674	6	et4n]2	et4n]2	X
eurjchem-604	674	7	[	[	X
eurjchem-604	674	8	w2(sc6h11)2(co)8	w2(sc6h11)2(co)8	X
eurjchem-604	674	9	]	]	X
eurjchem-604	674	10	,	,	PUNCT
eurjchem-604	674	11	[	[	X
eurjchem-604	674	12	w2(sc6h11)2(co)8	w2(sc6h11)2(co)8	X
eurjchem-604	674	13	]	]	PUNCT
eurjchem-604	674	14	and	and	CCONJ
eurjchem-604	674	15	[	[	X
eurjchem-604	674	16	et4n	et4n	X
eurjchem-604	674	17	]	]	X
eurjchem-604	674	18	[	[	X
eurjchem-604	674	19	w2(sc6h11)3(co)6	w2(sc6h11)3(co)6	X
eurjchem-604	674	20	]	]	PUNCT
eurjchem-604	674	21	had	have	AUX
eurjchem-604	674	22	been	be	AUX
eurjchem-604	674	23	synthesized	synthesize	VERB
eurjchem-604	674	24	with	with	ADP
eurjchem-604	674	25	cyclohexanthiolate	cyclohexanthiolate	NOUN
eurjchem-604	674	26	ligand	ligand	NOUN
eurjchem-604	675	1	[	[	X
eurjchem-604	675	2	198	198	NUM
eurjchem-604	675	3	]	]	PUNCT
eurjchem-604	675	4	.	.	PUNCT
eurjchem-604	676	1	treatment	treatment	NOUN
eurjchem-604	676	2	of	of	ADP
eurjchem-604	676	3	m(allyl)(cl)(co)2(py)2	m(allyl)(cl)(co)2(py)2	PROPN
eurjchem-604	676	4	(	(	PUNCT
eurjchem-604	676	5	m	m	PROPN
eurjchem-604	676	6	=	=	SYM
eurjchem-604	676	7	mo	mo	PROPN
eurjchem-604	676	8	,	,	PUNCT
eurjchem-604	676	9	w	w	PROPN
eurjchem-604	676	10	)	)	PUNCT
eurjchem-604	676	11	with	with	ADP
eurjchem-604	676	12	1	1	NUM
eurjchem-604	676	13	equiv	equiv	NOUN
eurjchem-604	676	14	.	.	PUNCT
eurjchem-604	677	1	of	of	ADP
eurjchem-604	677	2	potassium	potassium	NOUN
eurjchem-604	677	3	pyrazolates	pyrazolate	NOUN
eurjchem-604	677	4	in	in	ADP
eurjchem-604	677	5	tetrahydrofuran	tetrahydrofuran	NOUN
eurjchem-604	677	6	at	at	ADP
eurjchem-604	677	7	−78	−78	PROPN
eurjchem-604	677	8	°	°	PROPN
eurjchem-604	677	9	c	c	NOUN
eurjchem-604	677	10	afforded	afford	VERB
eurjchem-604	677	11	m(allyl)(r2pz)(co)2(py)n	m(allyl)(r2pz)(co)2(py)n	PROPN
eurjchem-604	677	12	(	(	PUNCT
eurjchem-604	677	13	r2pz	r2pz	X
eurjchem-604	677	14	=	=	SYM
eurjchem-604	677	15	3,5‐disubstituted	3,5‐disubstituted	NUM
eurjchem-604	677	16	pyrazolate	pyrazolate	NOUN
eurjchem-604	677	17	;	;	PUNCT
eurjchem-604	677	18	n	n	NOUN
eurjchem-604	677	19	=	=	SYM
eurjchem-604	677	20	1	1	NUM
eurjchem-604	677	21	,	,	PUNCT
eurjchem-604	677	22	2	2	NUM
eurjchem-604	677	23	;	;	PUNCT
eurjchem-604	677	24	r=	r=	ADJ
eurjchem-604	677	25	t‐bu	t‐bu	NOUN
eurjchem-604	677	26	)	)	PUNCT
eurjchem-604	677	27	in	in	ADP
eurjchem-604	677	28	68‐81	68‐81	ADJ
eurjchem-604	677	29	%	%	NOUN
eurjchem-604	677	30	yields	yield	NOUN
eurjchem-604	677	31	.	.	PUNCT
eurjchem-604	678	1	analogous	analogous	ADJ
eurjchem-604	678	2	treatment	treatment	NOUN
eurjchem-604	678	3	of	of	ADP
eurjchem-604	678	4	mo(allyl)(cl)(co)2(ncch3)2	mo(allyl)(cl)(co)2(ncch3)2	NOUN
eurjchem-604	678	5	with	with	ADP
eurjchem-604	678	6	1	1	NUM
eurjchem-604	678	7	equiv	equiv	NOUN
eurjchem-604	678	8	.	.	PUNCT
eurjchem-604	679	1	of	of	ADP
eurjchem-604	679	2	potassium	potassium	NOUN
eurjchem-604	679	3	pyrazolates	pyrazolate	NOUN
eurjchem-604	679	4	(	(	PUNCT
eurjchem-604	679	5	r2pz	r2pz	X
eurjchem-604	679	6	where	where	SCONJ
eurjchem-604	679	7	r=	r=	ADJ
eurjchem-604	679	8	t‐bu	t‐bu	NOUN
eurjchem-604	679	9	)	)	PUNCT
eurjchem-604	679	10	in	in	ADP
eurjchem-604	679	11	tetrahydrofuran	tetrahydrofuran	NOUN
eurjchem-604	679	12	at	at	ADP
eurjchem-604	679	13	−78	−78	PROPN
eurjchem-604	679	14	°	°	PROPN
eurjchem-604	679	15	c	c	NOUN
eurjchem-604	679	16	afforded	afford	VERB
eurjchem-604	679	17	[	[	PUNCT
eurjchem-604	679	18	mo(allyl)(r2pz)(co)2]2	mo(allyl)(r2pz)(co)2]2	PROPN
eurjchem-604	679	19	in	in	ADP
eurjchem-604	679	20	79	79	NUM
eurjchem-604	679	21	%	%	NOUN
eurjchem-604	679	22	yield	yield	NOUN
eurjchem-604	679	23	(	(	PUNCT
eurjchem-604	679	24	scheme	scheme	NOUN
eurjchem-604	679	25	50	50	NUM
eurjchem-604	679	26	)	)	PUNCT
eurjchem-604	679	27	.	.	PUNCT
eurjchem-604	680	1	an	an	DET
eurjchem-604	680	2	x‐ray	x‐ray	PROPN
eurjchem-604	680	3	crystal	crystal	NOUN
eurjchem-604	680	4	structure	structure	NOUN
eurjchem-604	680	5	analysis	analysis	NOUN
eurjchem-604	680	6	of	of	ADP
eurjchem-604	680	7	[	[	X
eurjchem-604	680	8	mo(allyl)(r2pz)(co)2]2	mo(allyl)(r2pz)(co)2]2	PROPN
eurjchem-604	680	9	showed	show	VERB
eurjchem-604	680	10	a	a	DET
eurjchem-604	680	11	dimeric	dimeric	ADJ
eurjchem-604	680	12	structure	structure	NOUN
eurjchem-604	680	13	bridged	bridge	VERB
eurjchem-604	680	14	by	by	ADP
eurjchem-604	680	15	two	two	NUM
eurjchem-604	680	16	μ‐η2	μ‐η2	NUM
eurjchem-604	680	17	:	:	PUNCT
eurjchem-604	680	18	η1‐tbu2pz	η1‐tbu2pz	PROPN
eurjchem-604	680	19	ligands	ligand	NOUN
eurjchem-604	680	20	[	[	X
eurjchem-604	680	21	199	199	NUM
eurjchem-604	680	22	]	]	PUNCT
eurjchem-604	680	23	.	.	PUNCT
eurjchem-604	681	1	scheme	scheme	VERB
eurjchem-604	681	2	50	50	NUM
eurjchem-604	681	3	formation	formation	NOUN
eurjchem-604	681	4	of	of	ADP
eurjchem-604	681	5	carbonylrhenium	carbonylrhenium	NOUN
eurjchem-604	681	6	cryptates	cryptate	NOUN
eurjchem-604	681	7	with	with	ADP
eurjchem-604	681	8	alkali	alkali	ADJ
eurjchem-604	681	9	metal	metal	NOUN
eurjchem-604	681	10	cations	cation	NOUN
eurjchem-604	681	11	was	be	AUX
eurjchem-604	681	12	studied	study	VERB
eurjchem-604	681	13	.	.	PUNCT
eurjchem-604	682	1	coordination	coordination	NOUN
eurjchem-604	682	2	chemistry	chemistry	NOUN
eurjchem-604	682	3	studies	study	NOUN
eurjchem-604	682	4	of	of	ADP
eurjchem-604	682	5	[	[	X
eurjchem-604	682	6	ph2p(e)np(e)ph2]−	ph2p(e)np(e)ph2]−	NOUN
eurjchem-604	682	7	,	,	PUNCT
eurjchem-604	682	8	e	e	X
eurjchem-604	682	9	=	=	SYM
eurjchem-604	682	10	o	o	X
eurjchem-604	682	11	,	,	PUNCT
eurjchem-604	682	12	s	s	X
eurjchem-604	682	13	,	,	PUNCT
eurjchem-604	682	14	se	se	X
eurjchem-604	682	15	towards	towards	ADP
eurjchem-604	682	16	rebr(co)5	rebr(co)5	PROPN
eurjchem-604	682	17	were	be	AUX
eurjchem-604	682	18	key	key	ADJ
eurjchem-604	682	19	target	target	NOUN
eurjchem-604	682	20	of	of	ADP
eurjchem-604	682	21	the	the	DET
eurjchem-604	682	22	study	study	NOUN
eurjchem-604	682	23	in	in	ADP
eurjchem-604	682	24	last	last	ADJ
eurjchem-604	682	25	decade	decade	NOUN
eurjchem-604	682	26	.	.	PUNCT
eurjchem-604	683	1	the	the	DET
eurjchem-604	683	2	reaction	reaction	NOUN
eurjchem-604	683	3	of	of	ADP
eurjchem-604	683	4	rebr(co)5	rebr(co)5	PROPN
eurjchem-604	683	5	with	with	ADP
eurjchem-604	683	6	li[ph2p(o)np(o)ph2	li[ph2p(o)np(o)ph2	NOUN
eurjchem-604	683	7	]	]	PUNCT
eurjchem-604	683	8	afforded	afford	VERB
eurjchem-604	683	9	the	the	DET
eurjchem-604	683	10	cryptate	cryptate	NOUN
eurjchem-604	683	11	li	li	PROPN
eurjchem-604	684	1	[	[	X
eurjchem-604	684	2	re2(co)6{μ‐ph2p(o)np(o)ph2‐κ2o	re2(co)6{μ‐ph2p(o)np(o)ph2‐κ2o	NOUN
eurjchem-604	684	3	,	,	PUNCT
eurjchem-604	684	4	o′}3	o′}3	PROPN
eurjchem-604	684	5	]	]	PUNCT
eurjchem-604	684	6	;	;	PUNCT
eurjchem-604	684	7	whereas	whereas	SCONJ
eurjchem-604	684	8	k	k	PROPN
eurjchem-604	684	9	[	[	X
eurjchem-604	684	10	ph2p(o)np(o)ph2	ph2p(o)np(o)ph2	NOUN
eurjchem-604	684	11	]	]	PUNCT
eurjchem-604	684	12	reacted	react	VERB
eurjchem-604	684	13	with	with	ADP
eurjchem-604	684	14	rebr(co)5	rebr(co)5	PROPN
eurjchem-604	684	15	to	to	PART
eurjchem-604	684	16	give	give	VERB
eurjchem-604	684	17	k	k	PROPN
eurjchem-604	684	18	[	[	X
eurjchem-604	684	19	re2(co)6{μ‐ph2p(o)np(o)ph2‐κ2o	re2(co)6{μ‐ph2p(o)np(o)ph2‐κ2o	NOUN
eurjchem-604	684	20	,	,	PUNCT
eurjchem-604	684	21	o′}{ph2p(o)np(o)ph2‐	o′}{ph2p(o)np(o)ph2‐	PROPN
eurjchem-604	684	22	κ2o	κ2o	PROPN
eurjchem-604	684	23	,	,	PUNCT
eurjchem-604	684	24	o′}2	o′}2	NOUN
eurjchem-604	684	25	]	]	PUNCT
eurjchem-604	684	26	.	.	PUNCT
eurjchem-604	685	1	other	other	ADJ
eurjchem-604	685	2	chalcogen	chalcogen	PROPN
eurjchem-604	685	3	ligands	ligand	NOUN
eurjchem-604	685	4	’	'	PUNCT
eurjchem-604	685	5	salts	salt	NOUN
eurjchem-604	685	6	m	m	VERB
eurjchem-604	686	1	[	[	X
eurjchem-604	686	2	ph2p(e)np(e)ph2	ph2p(e)np(e)ph2	ADJ
eurjchem-604	686	3	]	]	X
eurjchem-604	686	4	,	,	PUNCT
eurjchem-604	686	5	e	e	X
eurjchem-604	686	6	=	=	SYM
eurjchem-604	686	7	se	se	X
eurjchem-604	686	8	and	and	CCONJ
eurjchem-604	686	9	s	s	PROPN
eurjchem-604	686	10	,	,	PUNCT
eurjchem-604	686	11	m	m	VERB
eurjchem-604	686	12	=	=	SYM
eurjchem-604	686	13	k	k	PROPN
eurjchem-604	686	14	and	and	CCONJ
eurjchem-604	686	15	li	li	PROPN
eurjchem-604	686	16	gave	give	VERB
eurjchem-604	686	17	dirhenium	dirhenium	NOUN
eurjchem-604	686	18	carbonyls	carbonyls	NOUN
eurjchem-604	686	19	with	with	ADP
eurjchem-604	686	20	bromido	bromido	NOUN
eurjchem-604	686	21	and	and	CCONJ
eurjchem-604	686	22	ph2p(e)np(e)ph2	ph2p(e)np(e)ph2	NOUN
eurjchem-604	686	23	,	,	PUNCT
eurjchem-604	686	24	e	e	X
eurjchem-604	686	25	=	=	PUNCT
eurjchem-604	686	26	se	se	X
eurjchem-604	686	27	or	or	CCONJ
eurjchem-604	686	28	s	s	X
eurjchem-604	686	29	bridges	bridge	NOUN
eurjchem-604	686	30	upon	upon	SCONJ
eurjchem-604	686	31	reaction	reaction	NOUN
eurjchem-604	686	32	with	with	ADP
eurjchem-604	686	33	rebr(co)5	rebr(co)5	PROPN
eurjchem-604	686	34	[	[	X
eurjchem-604	686	35	200	200	NUM
eurjchem-604	686	36	]	]	PUNCT
eurjchem-604	686	37	.	.	PUNCT
eurjchem-604	687	1	5.2	5.2	NUM
eurjchem-604	687	2	.	.	PUNCT
eurjchem-604	688	1	heteronuclear	heteronuclear	PROPN
eurjchem-604	688	2	clusters	cluster	NOUN
eurjchem-604	688	3	heteronuclear	heteronuclear	PROPN
eurjchem-604	688	4	refers	refer	VERB
eurjchem-604	688	5	to	to	ADP
eurjchem-604	688	6	a	a	DET
eurjchem-604	688	7	cluster	cluster	NOUN
eurjchem-604	688	8	with	with	ADP
eurjchem-604	688	9	at	at	ADV
eurjchem-604	688	10	least	least	ADV
eurjchem-604	688	11	two	two	NUM
eurjchem-604	688	12	different	different	ADJ
eurjchem-604	688	13	metal	metal	NOUN
eurjchem-604	688	14	elements	element	NOUN
eurjchem-604	688	15	.	.	PUNCT
eurjchem-604	689	1	these	these	DET
eurjchem-604	689	2	complexes	complex	NOUN
eurjchem-604	689	3	are	be	AUX
eurjchem-604	689	4	also	also	ADV
eurjchem-604	689	5	known	know	VERB
eurjchem-604	689	6	as	as	ADP
eurjchem-604	689	7	mixed	mixed	ADJ
eurjchem-604	689	8	metal	metal	NOUN
eurjchem-604	689	9	complexes	complex	NOUN
eurjchem-604	689	10	.	.	PUNCT
eurjchem-604	690	1	the	the	DET
eurjchem-604	690	2	oxygen	oxygen	NOUN
eurjchem-604	690	3	transfer	transfer	NOUN
eurjchem-604	690	4	reaction	reaction	NOUN
eurjchem-604	690	5	of	of	ADP
eurjchem-604	690	6	the	the	DET
eurjchem-604	690	7	heterometallic	heterometallic	ADJ
eurjchem-604	690	8	carbonyl	carbonyl	NOUN
eurjchem-604	690	9	cluster	cluster	NOUN
eurjchem-604	690	10	(	(	PUNCT
eurjchem-604	690	11	μ3‐s)feco2(co)9	μ3‐s)feco2(co)9	X
eurjchem-604	690	12	with	with	ADP
eurjchem-604	690	13	bis(p‐	bis(p‐	PROPN
eurjchem-604	690	14	methoxyphenyl)telluroxide	methoxyphenyl)telluroxide	PROPN
eurjchem-604	690	15	(	(	PUNCT
eurjchem-604	690	16	bmpto	bmpto	PROPN
eurjchem-604	690	17	)	)	PUNCT
eurjchem-604	690	18	gives	give	VERB
eurjchem-604	690	19	bis(p‐	bis(p‐	PROPN
eurjchem-604	690	20	methoxyphenyl)telluride	methoxyphenyl)telluride	PROPN
eurjchem-604	690	21	(	(	PUNCT
eurjchem-604	690	22	bmpt	bmpt	ADJ
eurjchem-604	690	23	)	)	PUNCT
eurjchem-604	690	24	coordinated	coordinate	VERB
eurjchem-604	690	25	metal	metal	NOUN
eurjchem-604	690	26	cluster	cluster	NOUN
eurjchem-604	690	27	products	product	NOUN
eurjchem-604	690	28	(	(	PUNCT
eurjchem-604	690	29	μ3‐s)feco2(co)8(bmpt	μ3‐s)feco2(co)8(bmpt	NUM
eurjchem-604	690	30	)	)	PUNCT
eurjchem-604	690	31	and	and	CCONJ
eurjchem-604	690	32	(	(	PUNCT
eurjchem-604	690	33	μ3‐s	μ3‐s	NOUN
eurjchem-604	690	34	)	)	PUNCT
eurjchem-604	690	35	feco2(co)7(bmpt)2	feco2(co)7(bmpt)2	PROPN
eurjchem-604	690	36	,	,	PUNCT
eurjchem-604	690	37	which	which	PRON
eurjchem-604	690	38	react	react	VERB
eurjchem-604	690	39	further	far	ADV
eurjchem-604	690	40	with	with	ADP
eurjchem-604	690	41	pph3	pph3	NOUN
eurjchem-604	690	42	to	to	PART
eurjchem-604	690	43	afford	afford	VERB
eurjchem-604	690	44	ph3p‐substituted	ph3p‐substituted	ADJ
eurjchem-604	690	45	derivatives	derivative	NOUN
eurjchem-604	690	46	(	(	PUNCT
eurjchem-604	690	47	μ3‐s)feco2(co)8(pph3	μ3‐s)feco2(co)8(pph3	NOUN
eurjchem-604	690	48	)	)	PUNCT
eurjchem-604	690	49	and	and	CCONJ
eurjchem-604	690	50	(	(	PUNCT
eurjchem-604	690	51	μ3‐	μ3‐	NOUN
eurjchem-604	690	52	s)feco2(co)7(pph3)2	s)feco2(co)7(pph3)2	NOUN
eurjchem-604	690	53	,	,	PUNCT
eurjchem-604	690	54	respectively	respectively	ADV
eurjchem-604	690	55	[	[	X
eurjchem-604	690	56	201	201	NUM
eurjchem-604	690	57	]	]	PUNCT
eurjchem-604	690	58	.	.	PUNCT
eurjchem-604	691	1	mixed‐metal	mixed‐metal	ADJ
eurjchem-604	691	2	tetrahedral	tetrahedral	ADJ
eurjchem-604	691	3	clusters	cluster	NOUN
eurjchem-604	691	4	[	[	X
eurjchem-604	691	5	(	(	PUNCT
eurjchem-604	691	6	μ3‐e)rucomo(co)7(cpc(o)ch3)]((‐)‐	μ3‐e)rucomo(co)7(cpc(o)ch3)]((‐)‐	PROPN
eurjchem-604	691	7	diop	diop	PROPN
eurjchem-604	691	8	)	)	PUNCT
eurjchem-604	691	9	(	(	PUNCT
eurjchem-604	691	10	e	e	X
eurjchem-604	691	11	=	=	NOUN
eurjchem-604	691	12	se	se	X
eurjchem-604	691	13	,	,	PUNCT
eurjchem-604	691	14	s	s	PART
eurjchem-604	691	15	)	)	PUNCT
eurjchem-604	691	16	were	be	AUX
eurjchem-604	691	17	obtained	obtain	VERB
eurjchem-604	691	18	by	by	ADP
eurjchem-604	691	19	the	the	DET
eurjchem-604	691	20	reactions	reaction	NOUN
eurjchem-604	691	21	of	of	ADP
eurjchem-604	691	22	[	[	X
eurjchem-604	691	23	(	(	PUNCT
eurjchem-604	691	24	μ3‐	μ3‐	NOUN
eurjchem-604	691	25	retracted	retract	VERB
eurjchem-604	691	26	kaushik	kaushik	PROPN
eurjchem-604	691	27	et	et	PROPN
eurjchem-604	691	28	al	al	PROPN
eurjchem-604	691	29	.	.	PUNCT
eurjchem-604	691	30	/	/	SYM
eurjchem-604	691	31	european	european	PROPN
eurjchem-604	691	32	journal	journal	PROPN
eurjchem-604	691	33	of	of	ADP
eurjchem-604	691	34	chemistry	chemistry	NOUN
eurjchem-604	691	35	3	3	NUM
eurjchem-604	691	36	(	(	PUNCT
eurjchem-604	691	37	3	3	NUM
eurjchem-604	691	38	)	)	PUNCT
eurjchem-604	691	39	(	(	PUNCT
eurjchem-604	691	40	2012	2012	NUM
eurjchem-604	691	41	)	)	PUNCT
eurjchem-604	691	42	367‐394	367‐394	NOUN
eurjchem-604	691	43	383	383	NUM
eurjchem-604	691	44	e)ruco2(co)9	e)ruco2(co)9	NOUN
eurjchem-604	691	45	]	]	PUNCT
eurjchem-604	691	46	(	(	PUNCT
eurjchem-604	691	47	e	e	X
eurjchem-604	691	48	=	=	NOUN
eurjchem-604	691	49	se	se	X
eurjchem-604	691	50	,	,	PUNCT
eurjchem-604	691	51	s	s	PART
eurjchem-604	691	52	)	)	PUNCT
eurjchem-604	691	53	and	and	CCONJ
eurjchem-604	691	54	[	[	X
eurjchem-604	691	55	(	(	PUNCT
eurjchem-604	691	56	μ3‐e)rucomo(co)8(cpc(o)ch3	μ3‐e)rucomo(co)8(cpc(o)ch3	NOUN
eurjchem-604	691	57	)	)	PUNCT
eurjchem-604	691	58	]	]	PUNCT
eurjchem-604	692	1	(	(	PUNCT
eurjchem-604	692	2	e	e	X
eurjchem-604	692	3	=	=	NOUN
eurjchem-604	692	4	se	se	X
eurjchem-604	692	5	,	,	PUNCT
eurjchem-604	692	6	s	s	PART
eurjchem-604	692	7	)	)	PUNCT
eurjchem-604	692	8	with	with	ADP
eurjchem-604	692	9	the	the	DET
eurjchem-604	692	10	diphosphine	diphosphine	ADJ
eurjchem-604	692	11	compound	compound	NOUN
eurjchem-604	692	12	(	(	PUNCT
eurjchem-604	692	13	‐)‐diop	‐)‐diop	X
eurjchem-604	692	14	[	[	X
eurjchem-604	692	15	(	(	PUNCT
eurjchem-604	692	16	2,2‐	2,2‐	NUM
eurjchem-604	692	17	dimethyl‐1,3‐dioxolane‐4,5‐diyl	dimethyl‐1,3‐dioxolane‐4,5‐diyl	NOUN
eurjchem-604	692	18	bis‐methylene)bisdiphenyl‐	bis‐methylene)bisdiphenyl‐	NOUN
eurjchem-604	692	19	phosphine	phosphine	NOUN
eurjchem-604	692	20	]	]	PUNCT
eurjchem-604	692	21	in	in	ADP
eurjchem-604	692	22	n‐hexane	n‐hexane	NUM
eurjchem-604	692	23	or	or	CCONJ
eurjchem-604	692	24	thf	thf	NOUN
eurjchem-604	692	25	at	at	ADP
eurjchem-604	692	26	room	room	NOUN
eurjchem-604	692	27	temperature	temperature	NOUN
eurjchem-604	692	28	,	,	PUNCT
eurjchem-604	692	29	respectively	respectively	ADV
eurjchem-604	692	30	(	(	PUNCT
eurjchem-604	692	31	scheme	scheme	NOUN
eurjchem-604	692	32	51	51	NUM
eurjchem-604	692	33	)	)	PUNCT
eurjchem-604	693	1	[	[	X
eurjchem-604	693	2	202	202	NUM
eurjchem-604	693	3	]	]	PUNCT
eurjchem-604	693	4	.	.	PUNCT
eurjchem-604	694	1	scheme	scheme	NOUN
eurjchem-604	694	2	51	51	NUM
eurjchem-604	694	3	the	the	DET
eurjchem-604	694	4	tellurium‐containing	tellurium‐containe	VERB
eurjchem-604	694	5	trigonal	trigonal	ADJ
eurjchem-604	694	6	bipyramidal	bipyramidal	ADJ
eurjchem-604	694	7	clusters	cluster	NOUN
eurjchem-604	694	8	[	[	X
eurjchem-604	694	9	te2crm2(co)10]2‐	te2crm2(co)10]2‐	X
eurjchem-604	694	10	(	(	PUNCT
eurjchem-604	694	11	m	m	PROPN
eurjchem-604	694	12	=	=	SYM
eurjchem-604	694	13	cr	cr	PROPN
eurjchem-604	694	14	;	;	PUNCT
eurjchem-604	694	15	mo	mo	PROPN
eurjchem-604	694	16	;	;	PUNCT
eurjchem-604	694	17	w	w	X
eurjchem-604	694	18	)	)	PUNCT
eurjchem-604	694	19	has	have	AUX
eurjchem-604	694	20	been	be	AUX
eurjchem-604	694	21	synthesized	synthesize	VERB
eurjchem-604	694	22	from	from	ADP
eurjchem-604	694	23	the	the	DET
eurjchem-604	694	24	ring	ring	NOUN
eurjchem-604	694	25	closure	closure	NOUN
eurjchem-604	694	26	reactions	reaction	NOUN
eurjchem-604	694	27	of	of	ADP
eurjchem-604	694	28	the	the	DET
eurjchem-604	694	29	ring	ring	NOUN
eurjchem-604	694	30	complexes	complex	NOUN
eurjchem-604	695	1	[	[	X
eurjchem-604	695	2	te2cr2m2(co)18]2‐	te2cr2m2(co)18]2‐	PROPN
eurjchem-604	695	3	(	(	PUNCT
eurjchem-604	695	4	m	m	PROPN
eurjchem-604	695	5	=	=	SYM
eurjchem-604	695	6	cr	cr	PROPN
eurjchem-604	695	7	;	;	PUNCT
eurjchem-604	695	8	mo	mo	PROPN
eurjchem-604	695	9	;	;	PUNCT
eurjchem-604	695	10	w	w	X
eurjchem-604	695	11	)	)	PUNCT
eurjchem-604	695	12	(	(	PUNCT
eurjchem-604	695	13	scheme	scheme	NOUN
eurjchem-604	695	14	52	52	NUM
eurjchem-604	695	15	)	)	PUNCT
eurjchem-604	695	16	[	[	X
eurjchem-604	695	17	203	203	NUM
eurjchem-604	695	18	]	]	PUNCT
eurjchem-604	695	19	.	.	PUNCT
eurjchem-604	696	1	scheme	scheme	VERB
eurjchem-604	696	2	52	52	NUM
eurjchem-604	696	3	selenium‐capped	selenium‐capped	ADJ
eurjchem-604	696	4	trimolybdenum	trimolybdenum	NOUN
eurjchem-604	696	5	and	and	CCONJ
eurjchem-604	696	6	tritungsten	tritungsten	VERB
eurjchem-604	696	7	ring	ring	NOUN
eurjchem-604	696	8	carbonyl	carbonyl	NOUN
eurjchem-604	696	9	clusters	cluster	NOUN
eurjchem-604	697	1	[	[	X
eurjchem-604	697	2	se2m3(co)10]2−	se2m3(co)10]2−	X
eurjchem-604	697	3	(	(	PUNCT
eurjchem-604	697	4	m	m	PROPN
eurjchem-604	697	5	=	=	SYM
eurjchem-604	697	6	mo	mo	PROPN
eurjchem-604	697	7	,	,	PUNCT
eurjchem-604	697	8	w)have	w)have	AUX
eurjchem-604	697	9	been	be	AUX
eurjchem-604	697	10	synthesized	synthesize	VERB
eurjchem-604	697	11	(	(	PUNCT
eurjchem-604	697	12	figure	figure	NOUN
eurjchem-604	697	13	8)	8)	NUM
eurjchem-604	697	14	.	.	PUNCT
eurjchem-604	698	1	these	these	DET
eurjchem-604	698	2	selenium‐capped	selenium‐cappe	VERB
eurjchem-604	698	3	trimolybdenum	trimolybdenum	NOUN
eurjchem-604	698	4	cluster	cluster	NOUN
eurjchem-604	698	5	compound	compound	NOUN
eurjchem-604	699	1	[	[	X
eurjchem-604	699	2	et4n]2	et4n]2	PROPN
eurjchem-604	699	3	[	[	X
eurjchem-604	699	4	se2mo3(co)10	se2mo3(co)10	X
eurjchem-604	699	5	]	]	X
eurjchem-604	699	6	(	(	PUNCT
eurjchem-604	699	7	[	[	X
eurjchem-604	699	8	et4n]2	et4n]2	PROPN
eurjchem-604	699	9	)	)	PUNCT
eurjchem-604	699	10	can	can	AUX
eurjchem-604	699	11	be	be	AUX
eurjchem-604	699	12	obtained	obtain	VERB
eurjchem-604	699	13	from	from	ADP
eurjchem-604	699	14	the	the	DET
eurjchem-604	699	15	reaction	reaction	NOUN
eurjchem-604	699	16	of	of	ADP
eurjchem-604	699	17	the	the	DET
eurjchem-604	699	18	trichromium	trichromium	NOUN
eurjchem-604	699	19	cluster	cluster	NOUN
eurjchem-604	699	20	compound	compound	NOUN
eurjchem-604	700	1	[	[	X
eurjchem-604	700	2	et4n]2	et4n]2	PROPN
eurjchem-604	700	3	[	[	X
eurjchem-604	700	4	se2cr3(co)10	se2cr3(co)10	X
eurjchem-604	700	5	]	]	X
eurjchem-604	700	6	with	with	ADP
eurjchem-604	700	7	4	4	NUM
eurjchem-604	700	8	equiv	equiv	NOUN
eurjchem-604	700	9	.	.	PUNCT
eurjchem-604	701	1	of	of	ADP
eurjchem-604	701	2	mo(co)6	mo(co)6	PROPN
eurjchem-604	701	3	in	in	ADP
eurjchem-604	701	4	refluxing	refluxing	NOUN
eurjchem-604	701	5	acetone	acetone	NOUN
eurjchem-604	701	6	.	.	PUNCT
eurjchem-604	702	1	on	on	ADP
eurjchem-604	702	2	the	the	DET
eurjchem-604	702	3	other	other	ADJ
eurjchem-604	702	4	hand	hand	NOUN
eurjchem-604	702	5	,	,	PUNCT
eurjchem-604	702	6	when	when	SCONJ
eurjchem-604	702	7	[	[	X
eurjchem-604	702	8	et4n]2	et4n]2	PROPN
eurjchem-604	702	9	[	[	AUX
eurjchem-604	702	10	se2cr3(co)10	se2cr3(co)10	X
eurjchem-604	702	11	]	]	X
eurjchem-604	702	12	reacted	react	VERB
eurjchem-604	702	13	with	with	ADP
eurjchem-604	702	14	4	4	NUM
eurjchem-604	702	15	equiv	equiv	NOUN
eurjchem-604	702	16	.	.	PUNCT
eurjchem-604	703	1	of	of	ADP
eurjchem-604	703	2	w(co)6	w(co)6	PROPN
eurjchem-604	703	3	in	in	ADP
eurjchem-604	703	4	refluxing	refluxing	NOUN
eurjchem-604	703	5	acetone	acetone	NOUN
eurjchem-604	703	6	,	,	PUNCT
eurjchem-604	703	7	the	the	DET
eurjchem-604	703	8	planar	planar	ADJ
eurjchem-604	703	9	cluster	cluster	NOUN
eurjchem-604	703	10	compound	compound	NOUN
eurjchem-604	704	1	[	[	X
eurjchem-604	704	2	et4n]2	et4n]2	X
eurjchem-604	704	3	[	[	X
eurjchem-604	704	4	se2w4(co)18	se2w4(co)18	X
eurjchem-604	704	5	]	]	X
eurjchem-604	704	6	(	(	PUNCT
eurjchem-604	704	7	[	[	X
eurjchem-604	704	8	et4n]2	et4n]2	PROPN
eurjchem-604	704	9	)	)	PUNCT
eurjchem-604	704	10	was	be	AUX
eurjchem-604	704	11	isolated	isolate	VERB
eurjchem-604	704	12	,	,	PUNCT
eurjchem-604	704	13	which	which	PRON
eurjchem-604	704	14	could	could	AUX
eurjchem-604	704	15	further	far	ADV
eurjchem-604	704	16	transform	transform	VERB
eurjchem-604	704	17	to	to	ADP
eurjchem-604	704	18	the	the	DET
eurjchem-604	704	19	tritungsten	tritungsten	ADJ
eurjchem-604	704	20	cluster	cluster	NOUN
eurjchem-604	704	21	compound	compound	NOUN
eurjchem-604	705	1	[	[	X
eurjchem-604	705	2	et4n]2	et4n]2	PROPN
eurjchem-604	706	1	[	[	X
eurjchem-604	706	2	se2w3(co)10	se2w3(co)10	X
eurjchem-604	706	3	]	]	X
eurjchem-604	706	4	(	(	PUNCT
eurjchem-604	706	5	[	[	X
eurjchem-604	706	6	et4n]2	et4n]2	PROPN
eurjchem-604	706	7	)	)	PUNCT
eurjchem-604	706	8	in	in	ADP
eurjchem-604	706	9	good	good	ADJ
eurjchem-604	706	10	yield	yield	NOUN
eurjchem-604	706	11	.	.	PUNCT
eurjchem-604	707	1	alternatively	alternatively	ADV
eurjchem-604	707	2	,	,	PUNCT
eurjchem-604	707	3	these	these	PRON
eurjchem-604	707	4	clusterscould	clusterscould	AUX
eurjchem-604	707	5	be	be	AUX
eurjchem-604	707	6	formed	form	VERB
eurjchem-604	707	7	from	from	ADP
eurjchem-604	707	8	the	the	DET
eurjchem-604	707	9	reactions	reaction	NOUN
eurjchem-604	707	10	of	of	ADP
eurjchem-604	707	11	the	the	DET
eurjchem-604	707	12	monosubstituted	monosubstitute	VERB
eurjchem-604	707	13	products	product	NOUN
eurjchem-604	707	14	[	[	X
eurjchem-604	707	15	et4n]2	et4n]2	X
eurjchem-604	707	16	[	[	X
eurjchem-604	707	17	se2cr2m(co)10	se2cr2m(co)10	VERB
eurjchem-604	707	18	]	]	X
eurjchem-604	707	19	(	(	PUNCT
eurjchem-604	707	20	m	m	PROPN
eurjchem-604	707	21	=	=	SYM
eurjchem-604	707	22	mo	mo	X
eurjchem-604	707	23	;	;	PUNCT
eurjchem-604	707	24	w	w	PROPN
eurjchem-604	707	25	,	,	PUNCT
eurjchem-604	707	26	[	[	X
eurjchem-604	707	27	et4n]2	et4n]2	PROPN
eurjchem-604	707	28	)	)	PUNCT
eurjchem-604	707	29	with	with	ADP
eurjchem-604	707	30	3	3	NUM
eurjchem-604	707	31	equiv	equiv	NOUN
eurjchem-604	707	32	.	.	PUNCT
eurjchem-604	708	1	of	of	ADP
eurjchem-604	708	2	m(co)6	m(co)6	PROPN
eurjchem-604	708	3	in	in	ADP
eurjchem-604	708	4	acetone	acetone	NOUN
eurjchem-604	708	5	,	,	PUNCT
eurjchem-604	708	6	respectively	respectively	ADV
eurjchem-604	708	7	[	[	X
eurjchem-604	708	8	204	204	NUM
eurjchem-604	708	9	]	]	PUNCT
eurjchem-604	708	10	.	.	PUNCT
eurjchem-604	709	1	2,2′‐bipyrimidine	2,2′‐bipyrimidine	NUM
eurjchem-604	709	2	metal	metal	NOUN
eurjchem-604	709	3	multinuclear	multinuclear	NOUN
eurjchem-604	709	4	complexes	complexe	VERB
eurjchem-604	709	5	[	[	X
eurjchem-604	709	6	(	(	PUNCT
eurjchem-604	709	7	(	(	PUNCT
eurjchem-604	709	8	co)4mo)(μ‐1,2,3,4‐bipym)pt(c≡cfc)2	co)4mo)(μ‐1,2,3,4‐bipym)pt(c≡cfc)2	NOUN
eurjchem-604	709	9	]	]	PUNCT
eurjchem-604	709	10	with	with	ADP
eurjchem-604	709	11	mo(co)6	mo(co)6	NOUN
eurjchem-604	709	12	have	have	AUX
eurjchem-604	709	13	been	be	AUX
eurjchem-604	709	14	synthesized	synthesize	VERB
eurjchem-604	709	15	originating	originate	VERB
eurjchem-604	709	16	from	from	ADP
eurjchem-604	709	17	cis‐	cis‐	NOUN
eurjchem-604	710	1	[	[	X
eurjchem-604	710	2	(	(	PUNCT
eurjchem-604	710	3	bipym)pt(c≡cr)2	bipym)pt(c≡cr)2	X
eurjchem-604	710	4	]	]	PUNCT
eurjchem-604	710	5	(	(	PUNCT
eurjchem-604	710	6	r	r	NOUN
eurjchem-604	710	7	=	=	SYM
eurjchem-604	710	8	sime3	sime3	NOUN
eurjchem-604	710	9	)	)	PUNCT
eurjchem-604	710	10	in	in	ADP
eurjchem-604	710	11	presence	presence	NOUN
eurjchem-604	710	12	of	of	ADP
eurjchem-604	710	13	tetrahydrofuran	tetrahydrofuran	NOUN
eurjchem-604	710	14	after	after	ADP
eurjchem-604	710	15	irradiation	irradiation	NOUN
eurjchem-604	710	16	for	for	ADP
eurjchem-604	710	17	16	16	NUM
eurjchem-604	710	18	h	h	NOUN
eurjchem-604	710	19	at	at	ADP
eurjchem-604	710	20	25	25	NUM
eurjchem-604	710	21	°	°	NOUN
eurjchem-604	710	22	c	c	NOUN
eurjchem-604	710	23	[	[	X
eurjchem-604	710	24	186	186	NUM
eurjchem-604	710	25	]	]	PUNCT
eurjchem-604	710	26	.	.	PUNCT
eurjchem-604	711	1	thermolysis	thermolysis	NOUN
eurjchem-604	711	2	of	of	ADP
eurjchem-604	711	3	a	a	DET
eurjchem-604	711	4	toluene	toluene	NOUN
eurjchem-604	711	5	solution	solution	NOUN
eurjchem-604	711	6	containing	contain	VERB
eurjchem-604	711	7	[	[	X
eurjchem-604	711	8	fe2w(co)10(μ3‐s)2	fe2w(co)10(μ3‐s)2	NOUN
eurjchem-604	711	9	]	]	X
eurjchem-604	711	10	(	(	PUNCT
eurjchem-604	711	11	1	1	NUM
eurjchem-604	711	12	)	)	PUNCT
eurjchem-604	711	13	and	and	CCONJ
eurjchem-604	711	14	[	[	X
eurjchem-604	711	15	(	(	PUNCT
eurjchem-604	711	16	η5‐	η5‐	NOUN
eurjchem-604	711	17	c5h5)w(co)3(ccph	c5h5)w(co)3(ccph	NOUN
eurjchem-604	711	18	)	)	PUNCT
eurjchem-604	711	19	]	]	PUNCT
eurjchem-604	711	20	(	(	PUNCT
eurjchem-604	711	21	2	2	NUM
eurjchem-604	711	22	)	)	PUNCT
eurjchem-604	711	23	,	,	PUNCT
eurjchem-604	711	24	at	at	ADP
eurjchem-604	711	25	80	80	NUM
eurjchem-604	711	26	°	°	NOUN
eurjchem-604	711	27	c	c	NOUN
eurjchem-604	711	28	yields	yield	NOUN
eurjchem-604	711	29	the	the	DET
eurjchem-604	711	30	mixed	mixed	ADJ
eurjchem-604	711	31	metal	metal	NOUN
eurjchem-604	711	32	cluster	cluster	NOUN
eurjchem-604	711	33	[	[	X
eurjchem-604	711	34	fe2(co)6(μ3‐s)2w{(η5‐c5h5)w(co)3(ccph)}2	fe2(co)6(μ3‐s)2w{(η5‐c5h5)w(co)3(ccph)}2	X
eurjchem-604	711	35	]	]	X
eurjchem-604	711	36	(	(	PUNCT
eurjchem-604	711	37	scheme	scheme	NOUN
eurjchem-604	711	38	53	53	NUM
eurjchem-604	711	39	)	)	PUNCT
eurjchem-604	712	1	[	[	X
eurjchem-604	712	2	205	205	NUM
eurjchem-604	712	3	]	]	PUNCT
eurjchem-604	712	4	.	.	PUNCT
eurjchem-604	713	1	figure	figure	NOUN
eurjchem-604	713	2	8	8	NUM
eurjchem-604	713	3	.	.	PUNCT
eurjchem-604	714	1	selenium‐capped	selenium‐cappe	VERB
eurjchem-604	714	2	trimolybdenum	trimolybdenum	NOUN
eurjchem-604	714	3	ring	ring	NOUN
eurjchem-604	714	4	carbonyl	carbonyl	NOUN
eurjchem-604	714	5	clusters	cluster	NOUN
eurjchem-604	714	6	[	[	X
eurjchem-604	714	7	204	204	NUM
eurjchem-604	714	8	]	]	PUNCT
eurjchem-604	714	9	.	.	PUNCT
eurjchem-604	715	1	scheme	scheme	NOUN
eurjchem-604	715	2	53	53	NUM
eurjchem-604	715	3	reaction	reaction	NOUN
eurjchem-604	715	4	between	between	ADP
eurjchem-604	715	5	ho2cfcpph2m(co)5	ho2cfcpph2m(co)5	PROPN
eurjchem-604	715	6	(	(	PUNCT
eurjchem-604	715	7	m	m	PROPN
eurjchem-604	715	8	=	=	SYM
eurjchem-604	715	9	cr	cr	PROPN
eurjchem-604	715	10	,	,	PUNCT
eurjchem-604	715	11	mo	mo	PROPN
eurjchem-604	715	12	,	,	PUNCT
eurjchem-604	715	13	w	w	PROPN
eurjchem-604	715	14	;	;	PUNCT
eurjchem-604	715	15	fc	fc	PROPN
eurjchem-604	715	16	=	=	SYM
eurjchem-604	715	17	ferrocene‐1,1′‐diyl	ferrocene‐1,1′‐diyl	X
eurjchem-604	715	18	)	)	PUNCT
eurjchem-604	715	19	and	and	CCONJ
eurjchem-604	715	20	{	{	PUNCT
eurjchem-604	716	1	[	[	X
eurjchem-604	716	2	ti](μ‐σ	ti](μ‐σ	NOUN
eurjchem-604	716	3	,	,	PUNCT
eurjchem-604	716	4	π‐c≡csime3)2}cume	π‐c≡csime3)2}cume	NOUN
eurjchem-604	716	5	at	at	ADP
eurjchem-604	716	6	−30	−30	PROPN
eurjchem-604	716	7	°	°	ADP
eurjchem-604	716	8	c	c	PROPN
eurjchem-604	716	9	gave	give	VERB
eurjchem-604	716	10	the	the	DET
eurjchem-604	716	11	alkyne	alkyne	NOUN
eurjchem-604	716	12	/	/	SYM
eurjchem-604	716	13	ferrocene‐bridged	ferrocene‐bridge	VERB
eurjchem-604	716	14	heterotetrametallic	heterotetrametallic	ADJ
eurjchem-604	716	15	compounds	compound	NOUN
eurjchem-604	716	16	{	{	PUNCT
eurjchem-604	716	17	[	[	X
eurjchem-604	716	18	ti](μ‐σ	ti](μ‐σ	NOUN
eurjchem-604	716	19	,	,	PUNCT
eurjchem-604	716	20	π‐c≡csime3)2}cuo2cfcpph2m(co)5	π‐c≡csime3)2}cuo2cfcpph2m(co)5	PROPN
eurjchem-604	716	21	(	(	PUNCT
eurjchem-604	716	22	m	m	PROPN
eurjchem-604	716	23	=	=	SYM
eurjchem-604	716	24	cr	cr	PROPN
eurjchem-604	716	25	,	,	PUNCT
eurjchem-604	716	26	mo	mo	PROPN
eurjchem-604	716	27	,	,	PUNCT
eurjchem-604	716	28	w	w	PROPN
eurjchem-604	716	29	)	)	PUNCT
eurjchem-604	716	30	(	(	PUNCT
eurjchem-604	716	31	scheme	scheme	NOUN
eurjchem-604	716	32	54	54	NUM
eurjchem-604	716	33	)	)	PUNCT
eurjchem-604	717	1	[	[	X
eurjchem-604	717	2	206	206	NUM
eurjchem-604	717	3	]	]	PUNCT
eurjchem-604	717	4	.	.	PUNCT
eurjchem-604	718	1	scheme	scheme	NOUN
eurjchem-604	718	2	54	54	NUM
eurjchem-604	718	3	the	the	DET
eurjchem-604	718	4	60‐electron	60‐electron	NUM
eurjchem-604	718	5	tetrahedral	tetrahedral	ADJ
eurjchem-604	718	6	clusters	cluster	NOUN
eurjchem-604	718	7	w2ir2(μ‐l)(co)8(η5‐	w2ir2(μ‐l)(co)8(η5‐	NOUN
eurjchem-604	718	8	c5h4me)2	c5h4me)2	PROPN
eurjchem-604	719	1	[	[	X
eurjchem-604	719	2	l	l	NOUN
eurjchem-604	719	3	=	=	NOUN
eurjchem-604	719	4	dppe	dppe	NOUN
eurjchem-604	719	5	,	,	PUNCT
eurjchem-604	719	6	dppf	dppf	VERB
eurjchem-604	719	7	]	]	PUNCT
eurjchem-604	719	8	(	(	PUNCT
eurjchem-604	719	9	scheme	scheme	NOUN
eurjchem-604	719	10	55	55	NUM
eurjchem-604	719	11	)	)	PUNCT
eurjchem-604	719	12	have	have	AUX
eurjchem-604	719	13	been	be	AUX
eurjchem-604	719	14	prepared	prepare	VERB
eurjchem-604	719	15	from	from	ADP
eurjchem-604	719	16	reaction	reaction	NOUN
eurjchem-604	719	17	between	between	ADP
eurjchem-604	719	18	w2ir2(co)10(η5‐c5h4me)2	w2ir2(co)10(η5‐c5h4me)2	PROPN
eurjchem-604	719	19	and	and	CCONJ
eurjchem-604	719	20	the	the	DET
eurjchem-604	719	21	corresponding	corresponding	ADJ
eurjchem-604	719	22	diphosphine	diphosphine	NOUN
eurjchem-604	719	23	in	in	ADP
eurjchem-604	719	24	52	52	NUM
eurjchem-604	719	25	and	and	CCONJ
eurjchem-604	719	26	66	66	NUM
eurjchem-604	719	27	%	%	NOUN
eurjchem-604	719	28	yields	yield	NOUN
eurjchem-604	719	29	,	,	PUNCT
eurjchem-604	719	30	respectively	respectively	ADV
eurjchem-604	719	31	[	[	X
eurjchem-604	719	32	207	207	NUM
eurjchem-604	719	33	]	]	PUNCT
eurjchem-604	719	34	.	.	PUNCT
eurjchem-604	720	1	mixed	mixed	ADJ
eurjchem-604	720	2	ligand	ligand	ADJ
eurjchem-604	720	3	derivatives	derivative	NOUN
eurjchem-604	720	4	of	of	ADP
eurjchem-604	720	5	moir3(μ‐co)3(co)8(η‐c5r5	moir3(μ‐co)3(co)8(η‐c5r5	PROPN
eurjchem-604	720	6	)	)	PUNCT
eurjchem-604	720	7	(	(	PUNCT
eurjchem-604	720	8	r	r	NOUN
eurjchem-604	720	9	=	=	NOUN
eurjchem-604	720	10	h	h	NOUN
eurjchem-604	720	11	,	,	PUNCT
eurjchem-604	720	12	me	i	PRON
eurjchem-604	720	13	)	)	PUNCT
eurjchem-604	720	14	and	and	CCONJ
eurjchem-604	720	15	mo2ir2(μ‐co)3(co)7(η‐c5h5)2	mo2ir2(μ‐co)3(co)7(η‐c5h5)2	VERB
eurjchem-604	720	16	with	with	ADP
eurjchem-604	720	17	stoichiometric	stoichiometric	ADJ
eurjchem-604	720	18	amounts	amount	NOUN
eurjchem-604	720	19	of	of	ADP
eurjchem-604	720	20	the	the	DET
eurjchem-604	720	21	isocyanide	isocyanide	NOUN
eurjchem-604	720	22	butnc	butnc	PROPN
eurjchem-604	720	23	afford	afford	VERB
eurjchem-604	720	24	the	the	DET
eurjchem-604	720	25	ligand	ligand	ADJ
eurjchem-604	720	26	substituted	substitute	VERB
eurjchem-604	720	27	cluster	cluster	NOUN
eurjchem-604	720	28	in	in	ADP
eurjchem-604	720	29	fair	fair	ADJ
eurjchem-604	720	30	to	to	ADP
eurjchem-604	720	31	good	good	ADJ
eurjchem-604	720	32	yields	yield	NOUN
eurjchem-604	720	33	(	(	PUNCT
eurjchem-604	720	34	13‐58	13‐58	NUM
eurjchem-604	720	35	%	%	NOUN
eurjchem-604	720	36	)	)	PUNCT
eurjchem-604	721	1	[	[	X
eurjchem-604	721	2	208	208	NUM
eurjchem-604	721	3	]	]	PUNCT
eurjchem-604	721	4	.	.	PUNCT
eurjchem-604	722	1	tetrahedral	tetrahedral	ADJ
eurjchem-604	722	2	mixed‐metal	mixed‐metal	ADJ
eurjchem-604	722	3	cluster	cluster	NOUN
eurjchem-604	722	4	wir3(co)11(η‐c5h4me	wir3(co)11(η‐c5h4me	NOUN
eurjchem-604	722	5	)	)	PUNCT
eurjchem-604	723	1	is	be	AUX
eurjchem-604	723	2	prepared	prepare	VERB
eurjchem-604	723	3	in	in	ADP
eurjchem-604	723	4	8	8	NUM
eurjchem-604	723	5	%	%	NOUN
eurjchem-604	723	6	yield	yield	NOUN
eurjchem-604	723	7	from	from	ADP
eurjchem-604	723	8	reactions	reaction	NOUN
eurjchem-604	723	9	between	between	ADP
eurjchem-604	723	10	[	[	PUNCT
eurjchem-604	723	11	w(co)3(η‐	w(co)3(η‐	PROPN
eurjchem-604	723	12	c5h4me)]−	c5h4me)]−	PROPN
eurjchem-604	723	13	and	and	CCONJ
eurjchem-604	723	14	ircl(co)2(p‐toluidine	ircl(co)2(p‐toluidine	NOUN
eurjchem-604	723	15	)	)	PUNCT
eurjchem-604	723	16	under	under	ADP
eurjchem-604	723	17	an	an	DET
eurjchem-604	723	18	ar	ar	NOUN
eurjchem-604	723	19	atmosphere	atmosphere	NOUN
eurjchem-604	723	20	,	,	PUNCT
eurjchem-604	723	21	and	and	CCONJ
eurjchem-604	723	22	in	in	ADP
eurjchem-604	723	23	46	46	NUM
eurjchem-604	723	24	%	%	NOUN
eurjchem-604	723	25	yield	yield	NOUN
eurjchem-604	723	26	from	from	ADP
eurjchem-604	723	27	reaction	reaction	NOUN
eurjchem-604	723	28	between	between	ADP
eurjchem-604	723	29	wh(co)3(η‐c5h4me	wh(co)3(η‐c5h4me	NOUN
eurjchem-604	723	30	)	)	PUNCT
eurjchem-604	723	31	and	and	CCONJ
eurjchem-604	723	32	ircl(co)2(p‐toluidine	ircl(co)2(p‐toluidine	NOUN
eurjchem-604	723	33	)	)	PUNCT
eurjchem-604	723	34	under	under	ADP
eurjchem-604	723	35	a	a	DET
eurjchem-604	723	36	co	co	X
eurjchem-604	723	37	atmosphere	atmosphere	NOUN
eurjchem-604	723	38	.	.	PUNCT
eurjchem-604	724	1	wir3(co)11(η‐c5h4me	wir3(co)11(η‐c5h4me	NOUN
eurjchem-604	724	2	)	)	PUNCT
eurjchem-604	724	3	reacts	react	VERB
eurjchem-604	724	4	with	with	ADP
eurjchem-604	724	5	diphenylacetylene	diphenylacetylene	NOUN
eurjchem-604	724	6	to	to	PART
eurjchem-604	724	7	afford	afford	VERB
eurjchem-604	724	8	three	three	NUM
eurjchem-604	724	9	products	product	NOUN
eurjchem-604	724	10	,	,	PUNCT
eurjchem-604	724	11	namely	namely	ADV
eurjchem-604	724	12	tetrahedral	tetrahedral	ADJ
eurjchem-604	724	13	wir3(μ3‐η2‐	wir3(μ3‐η2‐	NOUN
eurjchem-604	724	14	phc2ph)2(co)7(η‐c5h4me	phc2ph)2(co)7(η‐c5h4me	PROPN
eurjchem-604	724	15	)	)	PUNCT
eurjchem-604	724	16	,	,	PUNCT
eurjchem-604	724	17	butterfly	butterfly	VERB
eurjchem-604	724	18	wir3{μ‐η4‐	wir3{μ‐η4‐	PROPN
eurjchem-604	724	19	c(ph)c(ph)c(ph)c(ph)}(co)5(η‐c5h4me	c(ph)c(ph)c(ph)c(ph)}(co)5(η‐c5h4me	PROPN
eurjchem-604	724	20	)	)	PUNCT
eurjchem-604	724	21	and	and	CCONJ
eurjchem-604	724	22	the	the	DET
eurjchem-604	724	23	binuclear	binuclear	NOUN
eurjchem-604	724	24	product	product	NOUN
eurjchem-604	724	25	ir2{μ‐η4‐c(ph)c(ph)c(ph)c(ph)}(co)5	ir2{μ‐η4‐c(ph)c(ph)c(ph)c(ph)}(co)5	VERB
eurjchem-604	725	1	[	[	X
eurjchem-604	725	2	209	209	NUM
eurjchem-604	725	3	]	]	PUNCT
eurjchem-604	725	4	.	.	PUNCT
eurjchem-604	726	1	the	the	DET
eurjchem-604	726	2	nickel‐molybdenum	nickel‐molybdenum	PROPN
eurjchem-604	726	3	complex	complex	NOUN
eurjchem-604	726	4	[	[	X
eurjchem-604	726	5	(	(	PUNCT
eurjchem-604	726	6	η5‐c5me5)ni	η5‐c5me5)ni	PROPN
eurjchem-604	726	7	=	=	PROPN
eurjchem-604	726	8	mo(co)3(η5‐	mo(co)3(η5‐	PROPN
eurjchem-604	726	9	c5h4me	c5h4me	NOUN
eurjchem-604	726	10	)	)	PUNCT
eurjchem-604	726	11	]	]	PUNCT
eurjchem-604	726	12	can	can	AUX
eurjchem-604	726	13	be	be	AUX
eurjchem-604	726	14	considered	consider	VERB
eurjchem-604	726	15	to	to	PART
eurjchem-604	726	16	contain	contain	VERB
eurjchem-604	726	17	a	a	DET
eurjchem-604	726	18	partially	partially	ADV
eurjchem-604	726	19	dative	dative	ADJ
eurjchem-604	726	20	nickel‐	nickel‐	ADJ
eurjchem-604	726	21	molybdenum	molybdenum	NOUN
eurjchem-604	726	22	double	double	ADJ
eurjchem-604	726	23	bond	bond	NOUN
eurjchem-604	726	24	.	.	PUNCT
eurjchem-604	727	1	this	this	DET
eurjchem-604	727	2	complex	complex	ADJ
eurjchem-604	727	3	reacts	react	VERB
eurjchem-604	727	4	with	with	ADP
eurjchem-604	727	5	the	the	DET
eurjchem-604	727	6	bulky	bulky	ADJ
eurjchem-604	727	7	terminal	terminal	ADJ
eurjchem-604	727	8	alkyne	alkyne	NOUN
eurjchem-604	727	9	hc≡ccph2(ome	hc≡ccph2(ome	NOUN
eurjchem-604	727	10	)	)	PUNCT
eurjchem-604	727	11	(	(	PUNCT
eurjchem-604	727	12	dpmp	dpmp	NOUN
eurjchem-604	727	13	)	)	PUNCT
eurjchem-604	727	14	to	to	PART
eurjchem-604	727	15	afford	afford	VERB
eurjchem-604	727	16	the	the	DET
eurjchem-604	727	17	alkyne‐	alkyne‐	ADV
eurjchem-604	727	18	carbonyl	carbonyl	NOUN
eurjchem-604	727	19	coupled	couple	VERB
eurjchem-604	727	20	metallacyclic	metallacyclic	ADJ
eurjchem-604	727	21	product	product	NOUN
eurjchem-604	727	22	(	(	PUNCT
eurjchem-604	727	23	sche	sche	NOUN
eurjchem-604	727	24	me	i	PRON
eurjchem-604	727	25	56	56	NUM
eurjchem-604	727	26	)	)	PUNCT
eurjchem-604	727	27	(	(	PUNCT
eurjchem-604	727	28	r	r	NOUN
eurjchem-604	727	29	=	=	NOUN
eurjchem-604	727	30	cph2(ome	cph2(ome	NOUN
eurjchem-604	727	31	)	)	PUNCT
eurjchem-604	727	32	,	,	PUNCT
eurjchem-604	727	33	ni‐mo	ni‐mo	NUM
eurjchem-604	727	34	)	)	PUNCT
eurjchem-604	727	35	regioselectively	regioselectively	ADV
eurjchem-604	727	36	and	and	CCONJ
eurjchem-604	727	37	exclusively	exclusively	ADV
eurjchem-604	727	38	[	[	X
eurjchem-604	727	39	210	210	NUM
eurjchem-604	727	40	]	]	PUNCT
eurjchem-604	727	41	.	.	PUNCT
eurjchem-604	728	1	scheme	scheme	NOUN
eurjchem-604	728	2	55	55	NUM
eurjchem-604	728	3	retracted	retract	VERB
eurjchem-604	728	4	384	384	NUM
eurjchem-604	728	5	kaushik	kaushik	NOUN
eurjchem-604	728	6	et	et	PROPN
eurjchem-604	728	7	al	al	PROPN
eurjchem-604	728	8	.	.	PUNCT
eurjchem-604	728	9	/	/	SYM
eurjchem-604	728	10	european	european	PROPN
eurjchem-604	728	11	journal	journal	PROPN
eurjchem-604	728	12	of	of	ADP
eurjchem-604	728	13	chemistry	chemistry	NOUN
eurjchem-604	728	14	3	3	NUM
eurjchem-604	728	15	(	(	PUNCT
eurjchem-604	728	16	3	3	NUM
eurjchem-604	728	17	)	)	PUNCT
eurjchem-604	728	18	(	(	PUNCT
eurjchem-604	728	19	2012	2012	NUM
eurjchem-604	728	20	)	)	PUNCT
eurjchem-604	728	21	367‐394	367‐394	NUM
eurjchem-604	728	22	scheme	scheme	NOUN
eurjchem-604	728	23	56	56	NUM
eurjchem-604	728	24	branched	branched	ADJ
eurjchem-604	728	25	dendritic	dendritic	ADJ
eurjchem-604	728	26	metallo	metallo	ADJ
eurjchem-604	728	27	carbosiloxanes	carbosiloxane	NOUN
eurjchem-604	728	28	of	of	ADP
eurjchem-604	728	29	type	type	NOUN
eurjchem-604	728	30	si(och2ch2ch2sime2	si(och2ch2ch2sime2	ADJ
eurjchem-604	729	1	[	[	X
eurjchem-604	729	2	och2pph2m(co)n])4	och2pph2m(co)n])4	PROPN
eurjchem-604	729	3	(	(	PUNCT
eurjchem-604	729	4	n	n	NOUN
eurjchem-604	729	5	=	=	SYM
eurjchem-604	729	6	3	3	NUM
eurjchem-604	729	7	:	:	PUNCT
eurjchem-604	729	8	m	m	PROPN
eurjchem-604	729	9	=	=	SYM
eurjchem-604	729	10	ni	ni	PROPN
eurjchem-604	729	11	;	;	PUNCT
eurjchem-604	729	12	n	n	NOUN
eurjchem-604	729	13	=	=	SYM
eurjchem-604	729	14	4	4	NUM
eurjchem-604	729	15	:	:	PUNCT
eurjchem-604	729	16	m	m	VERB
eurjchem-604	729	17	=	=	SYM
eurjchem-604	729	18	fe	fe	X
eurjchem-604	729	19	;	;	PUNCT
eurjchem-604	729	20	n	n	NOUN
eurjchem-604	729	21	=	=	SYM
eurjchem-604	729	22	5	5	NUM
eurjchem-604	729	23	:	:	PUNCT
eurjchem-604	729	24	m	m	PROPN
eurjchem-604	729	25	=	=	SYM
eurjchem-604	729	26	mo	mo	PROPN
eurjchem-604	729	27	,	,	PUNCT
eurjchem-604	729	28	w	w	NOUN
eurjchem-604	729	29	)	)	PUNCT
eurjchem-604	729	30	have	have	AUX
eurjchem-604	729	31	also	also	ADV
eurjchem-604	729	32	been	be	AUX
eurjchem-604	729	33	prepared	prepare	VERB
eurjchem-604	729	34	(	(	PUNCT
eurjchem-604	729	35	scheme	scheme	NOUN
eurjchem-604	729	36	57	57	NUM
eurjchem-604	729	37	)	)	PUNCT
eurjchem-604	729	38	.	.	PUNCT
eurjchem-604	730	1	these	these	DET
eurjchem-604	730	2	molecules	molecule	NOUN
eurjchem-604	730	3	possess	possess	VERB
eurjchem-604	730	4	phosphorus‐metal	phosphorus‐metal	ADJ
eurjchem-604	730	5	carbonyl	carbonyl	NOUN
eurjchem-604	730	6	groups	group	NOUN
eurjchem-604	730	7	as	as	ADP
eurjchem-604	730	8	end‐grafted	end‐grafted	ADJ
eurjchem-604	730	9	units	unit	NOUN
eurjchem-604	730	10	[	[	X
eurjchem-604	730	11	211	211	NUM
eurjchem-604	730	12	]	]	PUNCT
eurjchem-604	730	13	.	.	PUNCT
eurjchem-604	731	1	scheme	scheme	VERB
eurjchem-604	731	2	57	57	NUM
eurjchem-604	731	3	5.3	5.3	NUM
eurjchem-604	731	4	.	.	PUNCT
eurjchem-604	731	5	predicting	predict	VERB
eurjchem-604	731	6	structures	structure	NOUN
eurjchem-604	731	7	of	of	ADP
eurjchem-604	731	8	cluster	cluster	NOUN
eurjchem-604	731	9	compounds	compound	VERB
eurjchem-604	731	10	the	the	DET
eurjchem-604	731	11	polyhedral	polyhedral	ADJ
eurjchem-604	731	12	skeletal	skeletal	ADJ
eurjchem-604	731	13	electron	electron	NOUN
eurjchem-604	731	14	pair	pair	NOUN
eurjchem-604	731	15	theory	theory	NOUN
eurjchem-604	731	16	or	or	CCONJ
eurjchem-604	731	17	wade	wade	PROPN
eurjchem-604	731	18	's	's	PART
eurjchem-604	731	19	electron	electron	NOUN
eurjchem-604	731	20	counting	counting	NOUN
eurjchem-604	731	21	rules	rule	NOUN
eurjchem-604	731	22	predict	predict	VERB
eurjchem-604	731	23	trends	trend	NOUN
eurjchem-604	731	24	in	in	ADP
eurjchem-604	731	25	the	the	DET
eurjchem-604	731	26	stability	stability	NOUN
eurjchem-604	731	27	and	and	CCONJ
eurjchem-604	731	28	structures	structure	NOUN
eurjchem-604	731	29	of	of	ADP
eurjchem-604	731	30	many	many	ADJ
eurjchem-604	731	31	metal	metal	NOUN
eurjchem-604	731	32	clusters	cluster	NOUN
eurjchem-604	731	33	.	.	PUNCT
eurjchem-604	732	1	the	the	DET
eurjchem-604	732	2	electron	electron	NOUN
eurjchem-604	732	3	counting	counting	NOUN
eurjchem-604	732	4	rules	rule	NOUN
eurjchem-604	732	5	were	be	AUX
eurjchem-604	732	6	originally	originally	ADV
eurjchem-604	732	7	formulated	formulate	VERB
eurjchem-604	732	8	by	by	ADP
eurjchem-604	732	9	kenneth	kenneth	PROPN
eurjchem-604	732	10	wade	wade	PROPN
eurjchem-604	732	11	and	and	CCONJ
eurjchem-604	732	12	were	be	AUX
eurjchem-604	732	13	further	far	ADV
eurjchem-604	732	14	developed	develop	VERB
eurjchem-604	732	15	by	by	ADP
eurjchem-604	732	16	d.	d.	PROPN
eurjchem-604	732	17	m.	m.	PROPN
eurjchem-604	732	18	p.	p.	PROPN
eurjchem-604	732	19	mingos	mingo	NOUN
eurjchem-604	732	20	and	and	CCONJ
eurjchem-604	732	21	others	other	NOUN
eurjchem-604	732	22	;	;	PUNCT
eurjchem-604	732	23	they	they	PRON
eurjchem-604	732	24	are	be	AUX
eurjchem-604	732	25	sometimes	sometimes	ADV
eurjchem-604	732	26	known	know	VERB
eurjchem-604	732	27	as	as	ADP
eurjchem-604	732	28	wade	wade	PROPN
eurjchem-604	732	29	's	's	PART
eurjchem-604	732	30	rules	rule	NOUN
eurjchem-604	732	31	or	or	CCONJ
eurjchem-604	732	32	the	the	DET
eurjchem-604	732	33	wade	wade	PROPN
eurjchem-604	732	34	/	/	SYM
eurjchem-604	732	35	mingos	mingo	NOUN
eurjchem-604	732	36	rules	rule	NOUN
eurjchem-604	732	37	.	.	PUNCT
eurjchem-604	733	1	the	the	DET
eurjchem-604	733	2	rules	rule	NOUN
eurjchem-604	733	3	are	be	AUX
eurjchem-604	733	4	based	base	VERB
eurjchem-604	733	5	on	on	ADP
eurjchem-604	733	6	a	a	DET
eurjchem-604	733	7	molecular	molecular	ADJ
eurjchem-604	733	8	orbital	orbital	ADJ
eurjchem-604	733	9	treatment	treatment	NOUN
eurjchem-604	733	10	of	of	ADP
eurjchem-604	733	11	the	the	DET
eurjchem-604	733	12	bonding	bonding	NOUN
eurjchem-604	733	13	[	[	X
eurjchem-604	733	14	212‐215	212‐215	NUM
eurjchem-604	733	15	]	]	PUNCT
eurjchem-604	733	16	.	.	PUNCT
eurjchem-604	734	1	recently	recently	ADV
eurjchem-604	734	2	these	these	DET
eurjchem-604	734	3	rules	rule	NOUN
eurjchem-604	734	4	are	be	AUX
eurjchem-604	734	5	extended	extend	VERB
eurjchem-604	734	6	and	and	CCONJ
eurjchem-604	734	7	unified	unify	VERB
eurjchem-604	734	8	for	for	ADP
eurjchem-604	734	9	macropolyhedral	macropolyhedral	ADJ
eurjchem-604	734	10	boranes	borane	NOUN
eurjchem-604	734	11	,	,	PUNCT
eurjchem-604	734	12	metallocenes	metallocene	NOUN
eurjchem-604	734	13	and	and	CCONJ
eurjchem-604	734	14	borides	boride	NOUN
eurjchem-604	734	15	.	.	PUNCT
eurjchem-604	735	1	the	the	DET
eurjchem-604	735	2	unified	unified	ADJ
eurjchem-604	735	3	electron	electron	NOUN
eurjchem-604	735	4	counting	counting	NOUN
eurjchem-604	735	5	rules	rule	NOUN
eurjchem-604	735	6	are	be	AUX
eurjchem-604	735	7	called	call	VERB
eurjchem-604	735	8	jemmis	jemmis	PROPN
eurjchem-604	735	9	mno	mno	PROPN
eurjchem-604	735	10	rules	rules	PROPN
eurjchem-604	735	11	[	[	X
eurjchem-604	735	12	216‐217	216‐217	NUM
eurjchem-604	735	13	]	]	PUNCT
eurjchem-604	735	14	.	.	PUNCT
eurjchem-604	736	1	different	different	ADJ
eurjchem-604	736	2	rules	rule	NOUN
eurjchem-604	736	3	(	(	PUNCT
eurjchem-604	736	4	4n	4n	NOUN
eurjchem-604	736	5	,	,	PUNCT
eurjchem-604	736	6	5n	5n	NOUN
eurjchem-604	736	7	or	or	CCONJ
eurjchem-604	736	8	6n	6n	NUM
eurjchem-604	736	9	)	)	PUNCT
eurjchem-604	736	10	are	be	AUX
eurjchem-604	736	11	invoked	invoke	VERB
eurjchem-604	736	12	depending	depend	VERB
eurjchem-604	736	13	on	on	ADP
eurjchem-604	736	14	the	the	DET
eurjchem-604	736	15	number	number	NOUN
eurjchem-604	736	16	of	of	ADP
eurjchem-604	736	17	electrons	electron	NOUN
eurjchem-604	736	18	per	per	ADP
eurjchem-604	736	19	vertex	vertex	NOUN
eurjchem-604	736	20	.	.	PUNCT
eurjchem-604	737	1	the	the	DET
eurjchem-604	737	2	4n	4n	PROPN
eurjchem-604	737	3	rules	rule	NOUN
eurjchem-604	737	4	are	be	AUX
eurjchem-604	737	5	reasonably	reasonably	ADV
eurjchem-604	737	6	accurate	accurate	ADJ
eurjchem-604	737	7	in	in	ADP
eurjchem-604	737	8	predicting	predict	VERB
eurjchem-604	737	9	the	the	DET
eurjchem-604	737	10	structures	structure	NOUN
eurjchem-604	737	11	of	of	ADP
eurjchem-604	737	12	clusters	cluster	NOUN
eurjchem-604	737	13	having	have	VERB
eurjchem-604	737	14	about	about	ADV
eurjchem-604	737	15	4	4	NUM
eurjchem-604	737	16	electrons	electron	NOUN
eurjchem-604	737	17	per	per	ADP
eurjchem-604	737	18	vertex	vertex	NOUN
eurjchem-604	737	19	,	,	PUNCT
eurjchem-604	737	20	as	as	SCONJ
eurjchem-604	737	21	is	be	AUX
eurjchem-604	737	22	the	the	DET
eurjchem-604	737	23	case	case	NOUN
eurjchem-604	737	24	for	for	ADP
eurjchem-604	737	25	many	many	ADJ
eurjchem-604	737	26	boranes	borane	NOUN
eurjchem-604	737	27	and	and	CCONJ
eurjchem-604	737	28	carboranes	carborane	NOUN
eurjchem-604	737	29	.	.	PUNCT
eurjchem-604	738	1	for	for	ADP
eurjchem-604	738	2	such	such	ADJ
eurjchem-604	738	3	clusters	cluster	NOUN
eurjchem-604	738	4	,	,	PUNCT
eurjchem-604	738	5	the	the	DET
eurjchem-604	738	6	structures	structure	NOUN
eurjchem-604	738	7	are	be	AUX
eurjchem-604	738	8	based	base	VERB
eurjchem-604	738	9	ondeltahedra	ondeltahedra	PROPN
eurjchem-604	738	10	,	,	PUNCT
eurjchem-604	738	11	which	which	PRON
eurjchem-604	738	12	are	be	AUX
eurjchem-604	738	13	polyhedrain	polyhedrain	ADJ
eurjchem-604	738	14	which	which	PRON
eurjchem-604	738	15	every	every	DET
eurjchem-604	738	16	face	face	NOUN
eurjchem-604	738	17	is	be	AUX
eurjchem-604	738	18	triangular	triangular	NOUN
eurjchem-604	738	19	.	.	PUNCT
eurjchem-604	739	1	the	the	DET
eurjchem-604	739	2	4n	4n	PROPN
eurjchem-604	739	3	clusters	cluster	NOUN
eurjchem-604	739	4	are	be	AUX
eurjchem-604	739	5	classified	classify	VERB
eurjchem-604	739	6	as	as	ADP
eurjchem-604	739	7	closo‐	closo‐	PROPN
eurjchem-604	739	8	,	,	PUNCT
eurjchem-604	739	9	nido‐	nido‐	PROPN
eurjchem-604	739	10	,	,	PUNCT
eurjchem-604	739	11	arachno‐	arachno‐	PROPN
eurjchem-604	739	12	or	or	CCONJ
eurjchem-604	739	13	hypho‐	hypho‐	VERB
eurjchem-604	739	14	,	,	PUNCT
eurjchem-604	739	15	based	base	VERB
eurjchem-604	739	16	on	on	ADP
eurjchem-604	739	17	whether	whether	SCONJ
eurjchem-604	739	18	they	they	PRON
eurjchem-604	739	19	represent	represent	VERB
eurjchem-604	739	20	a	a	DET
eurjchem-604	739	21	complete	complete	ADJ
eurjchem-604	739	22	(	(	PUNCT
eurjchem-604	739	23	closo‐)deltahedron	closo‐)deltahedron	NUM
eurjchem-604	739	24	,	,	PUNCT
eurjchem-604	739	25	or	or	CCONJ
eurjchem-604	739	26	a	a	DET
eurjchem-604	739	27	deltahedron	deltahedron	NOUN
eurjchem-604	739	28	that	that	PRON
eurjchem-604	739	29	is	be	AUX
eurjchem-604	739	30	missing	miss	VERB
eurjchem-604	739	31	one	one	NUM
eurjchem-604	739	32	(	(	PUNCT
eurjchem-604	739	33	nido‐	nido‐	NOUN
eurjchem-604	739	34	)	)	PUNCT
eurjchem-604	739	35	,	,	PUNCT
eurjchem-604	739	36	two	two	NUM
eurjchem-604	739	37	(	(	PUNCT
eurjchem-604	739	38	arachno‐	arachno‐	PROPN
eurjchem-604	739	39	)	)	PUNCT
eurjchem-604	739	40	or	or	CCONJ
eurjchem-604	739	41	three	three	NUM
eurjchem-604	739	42	(	(	PUNCT
eurjchem-604	739	43	hypho	hypho	NOUN
eurjchem-604	739	44	)	)	PUNCT
eurjchem-604	739	45	vertices	vertex	NOUN
eurjchem-604	739	46	.	.	PUNCT
eurjchem-604	740	1	however	however	ADV
eurjchem-604	740	2	,	,	PUNCT
eurjchem-604	740	3	hypho	hypho	NOUN
eurjchem-604	740	4	clusters	cluster	NOUN
eurjchem-604	740	5	are	be	AUX
eurjchem-604	740	6	relatively	relatively	ADV
eurjchem-604	740	7	uncommon	uncommon	ADJ
eurjchem-604	740	8	due	due	ADP
eurjchem-604	740	9	to	to	ADP
eurjchem-604	740	10	the	the	DET
eurjchem-604	740	11	fact	fact	NOUN
eurjchem-604	740	12	that	that	SCONJ
eurjchem-604	740	13	the	the	DET
eurjchem-604	740	14	electron	electron	NOUN
eurjchem-604	740	15	count	count	NOUN
eurjchem-604	740	16	is	be	AUX
eurjchem-604	740	17	high	high	ADJ
eurjchem-604	740	18	enough	enough	ADV
eurjchem-604	740	19	to	to	PART
eurjchem-604	740	20	start	start	VERB
eurjchem-604	740	21	to	to	PART
eurjchem-604	740	22	fill	fill	VERB
eurjchem-604	740	23	antibonding	antibonding	ADJ
eurjchem-604	740	24	orbitals	orbital	NOUN
eurjchem-604	740	25	and	and	CCONJ
eurjchem-604	740	26	destabilize	destabilize	VERB
eurjchem-604	740	27	the	the	DET
eurjchem-604	740	28	4n	4n	ADJ
eurjchem-604	740	29	structure	structure	NOUN
eurjchem-604	740	30	.	.	PUNCT
eurjchem-604	741	1	if	if	SCONJ
eurjchem-604	741	2	the	the	DET
eurjchem-604	741	3	electron	electron	NOUN
eurjchem-604	741	4	count	count	NOUN
eurjchem-604	741	5	is	be	AUX
eurjchem-604	741	6	close	close	ADJ
eurjchem-604	741	7	to	to	ADP
eurjchem-604	741	8	5	5	NUM
eurjchem-604	741	9	electrons	electron	NOUN
eurjchem-604	741	10	per	per	ADP
eurjchem-604	741	11	vertex	vertex	NOUN
eurjchem-604	741	12	,	,	PUNCT
eurjchem-604	741	13	the	the	DET
eurjchem-604	741	14	structure	structure	NOUN
eurjchem-604	741	15	often	often	ADV
eurjchem-604	741	16	changes	change	VERB
eurjchem-604	741	17	to	to	ADP
eurjchem-604	741	18	one	one	NUM
eurjchem-604	741	19	governed	govern	VERB
eurjchem-604	741	20	by	by	ADP
eurjchem-604	741	21	the	the	DET
eurjchem-604	741	22	5n	5n	NUM
eurjchem-604	741	23	rules	rule	NOUN
eurjchem-604	741	24	,	,	PUNCT
eurjchem-604	741	25	which	which	PRON
eurjchem-604	741	26	are	be	AUX
eurjchem-604	741	27	based	base	VERB
eurjchem-604	741	28	on	on	ADP
eurjchem-604	741	29	3‐connected	3‐connecte	VERB
eurjchem-604	741	30	polyhedra	polyhedra	NOUN
eurjchem-604	741	31	.	.	PUNCT
eurjchem-604	742	1	as	as	SCONJ
eurjchem-604	742	2	the	the	DET
eurjchem-604	742	3	electron	electron	NOUN
eurjchem-604	742	4	count	count	NOUN
eurjchem-604	742	5	increases	increase	VERB
eurjchem-604	742	6	further	far	ADV
eurjchem-604	742	7	,	,	PUNCT
eurjchem-604	742	8	the	the	DET
eurjchem-604	742	9	structures	structure	NOUN
eurjchem-604	742	10	of	of	ADP
eurjchem-604	742	11	clusters	cluster	NOUN
eurjchem-604	742	12	with	with	ADP
eurjchem-604	742	13	5n	5n	NUM
eurjchem-604	742	14	electron	electron	NOUN
eurjchem-604	742	15	counts	count	NOUN
eurjchem-604	742	16	become	become	VERB
eurjchem-604	742	17	unstable	unstable	ADJ
eurjchem-604	742	18	,	,	PUNCT
eurjchem-604	742	19	so	so	SCONJ
eurjchem-604	742	20	the	the	DET
eurjchem-604	742	21	6n	6n	NOUN
eurjchem-604	742	22	rules	rule	NOUN
eurjchem-604	742	23	can	can	AUX
eurjchem-604	742	24	be	be	AUX
eurjchem-604	742	25	implemented	implement	VERB
eurjchem-604	742	26	.	.	PUNCT
eurjchem-604	743	1	the	the	DET
eurjchem-604	743	2	6n	6n	PROPN
eurjchem-604	743	3	clusters	cluster	NOUN
eurjchem-604	743	4	have	have	VERB
eurjchem-604	743	5	structures	structure	NOUN
eurjchem-604	743	6	that	that	PRON
eurjchem-604	743	7	are	be	AUX
eurjchem-604	743	8	based	base	VERB
eurjchem-604	743	9	on	on	ADP
eurjchem-604	743	10	rings	ring	NOUN
eurjchem-604	743	11	.	.	PUNCT
eurjchem-604	744	1	a	a	DET
eurjchem-604	744	2	molecular	molecular	ADJ
eurjchem-604	744	3	orbital	orbital	ADJ
eurjchem-604	744	4	treatment	treatment	NOUN
eurjchem-604	744	5	can	can	AUX
eurjchem-604	744	6	be	be	AUX
eurjchem-604	744	7	used	use	VERB
eurjchem-604	744	8	to	to	PART
eurjchem-604	744	9	rationalize	rationalize	VERB
eurjchem-604	744	10	the	the	DET
eurjchem-604	744	11	bonding	bonding	NOUN
eurjchem-604	744	12	of	of	ADP
eurjchem-604	744	13	cluster	cluster	NOUN
eurjchem-604	744	14	compounds	compound	NOUN
eurjchem-604	744	15	of	of	ADP
eurjchem-604	744	16	the	the	DET
eurjchem-604	744	17	4n	4n	NOUN
eurjchem-604	744	18	,	,	PUNCT
eurjchem-604	744	19	5n	5n	NUM
eurjchem-604	744	20	,	,	PUNCT
eurjchem-604	744	21	and	and	CCONJ
eurjchem-604	744	22	6n	6n	NOUN
eurjchem-604	744	23	types	type	NOUN
eurjchem-604	744	24	.	.	PUNCT
eurjchem-604	745	1	5.3.1	5.3.1	X
eurjchem-604	745	2	.	.	NOUN
eurjchem-604	745	3	4n	4n	NOUN
eurjchem-604	745	4	rules	rule	VERB
eurjchem-604	745	5	the	the	DET
eurjchem-604	745	6	following	follow	VERB
eurjchem-604	745	7	polyhedraare	polyhedraare	NOUN
eurjchem-604	745	8	the	the	DET
eurjchem-604	745	9	basis	basis	NOUN
eurjchem-604	745	10	for	for	ADP
eurjchem-604	745	11	the	the	DET
eurjchem-604	745	12	4n	4n	ADJ
eurjchem-604	745	13	rules	rule	NOUN
eurjchem-604	745	14	;	;	PUNCT
eurjchem-604	745	15	each	each	PRON
eurjchem-604	745	16	of	of	ADP
eurjchem-604	745	17	these	these	PRON
eurjchem-604	745	18	have	have	VERB
eurjchem-604	745	19	triangular	triangular	NOUN
eurjchem-604	745	20	faces	face	NOUN
eurjchem-604	745	21	[	[	X
eurjchem-604	745	22	218	218	NUM
eurjchem-604	745	23	]	]	PUNCT
eurjchem-604	745	24	.	.	PUNCT
eurjchem-604	746	1	the	the	DET
eurjchem-604	746	2	number	number	NOUN
eurjchem-604	746	3	of	of	ADP
eurjchem-604	746	4	vertices	vertex	NOUN
eurjchem-604	746	5	in	in	ADP
eurjchem-604	746	6	the	the	DET
eurjchem-604	746	7	cluster	cluster	NOUN
eurjchem-604	746	8	determines	determine	VERB
eurjchem-604	746	9	what	what	DET
eurjchem-604	746	10	polyhedron	polyhedron	NOUN
eurjchem-604	746	11	the	the	DET
eurjchem-604	746	12	structure	structure	NOUN
eurjchem-604	746	13	is	be	AUX
eurjchem-604	746	14	based	base	VERB
eurjchem-604	746	15	on	on	ADP
eurjchem-604	746	16	.	.	PUNCT
eurjchem-604	746	17	prediction	prediction	NOUN
eurjchem-604	746	18	of	of	ADP
eurjchem-604	746	19	polyhedron	polyhedron	NOUN
eurjchem-604	746	20	structure	structure	NOUN
eurjchem-604	746	21	based	base	VERB
eurjchem-604	746	22	on	on	ADP
eurjchem-604	746	23	number	number	NOUN
eurjchem-604	746	24	of	of	ADP
eurjchem-604	746	25	vertices	vertex	NOUN
eurjchem-604	746	26	in	in	ADP
eurjchem-604	746	27	cluster	cluster	NOUN
eurjchem-604	746	28	i	i	PROPN
eurjchem-604	746	29	d	d	PROPN
eurjchem-604	746	30	given	give	VERB
eurjchem-604	746	31	in	in	ADP
eurjchem-604	746	32	table	table	NOUN
eurjchem-604	746	33	7	7	NUM
eurjchem-604	746	34	.	.	PUNCT
eurjchem-604	746	35	table	table	NOUN
eurjchem-604	746	36	7	7	NUM
eurjchem-604	746	37	.	.	PUNCT
eurjchem-604	746	38	prediction	prediction	NOUN
eurjchem-604	746	39	of	of	ADP
eurjchem-604	746	40	polyhedron	polyhedron	NOUN
eurjchem-604	746	41	structure	structure	NOUN
eurjchem-604	746	42	based	base	VERB
eurjchem-604	746	43	on	on	ADP
eurjchem-604	746	44	number	number	NOUN
eurjchem-604	746	45	of	of	ADP
eurjchem-604	746	46	vertices	vertex	NOUN
eurjchem-604	746	47	in	in	ADP
eurjchem-604	746	48	cluster	cluster	NOUN
eurjchem-604	746	49	.	.	PUNCT
eurjchem-604	747	1	number	number	NOUN
eurjchem-604	747	2	of	of	ADP
eurjchem-604	747	3	vertices	vertex	NOUN
eurjchem-604	747	4	polyhedron	polyhedron	NOUN
eurjchem-604	747	5	4	4	NUM
eurjchem-604	747	6	tetrahedron	tetrahedron	NOUN
eurjchem-604	747	7	5	5	NUM
eurjchem-604	747	8	trigonal	trigonal	ADJ
eurjchem-604	747	9	bipyramid	bipyramid	NOUN
eurjchem-604	747	10	6	6	NUM
eurjchem-604	747	11	octahedron	octahedron	NOUN
eurjchem-604	747	12	7	7	NUM
eurjchem-604	747	13	pentagonal	pentagonal	ADJ
eurjchem-604	747	14	bipyramid	bipyramid	NOUN
eurjchem-604	747	15	8	8	NUM
eurjchem-604	747	16	d2d	d2d	NOUN
eurjchem-604	747	17	(	(	PUNCT
eurjchem-604	747	18	trigonal	trigonal	ADJ
eurjchem-604	747	19	)	)	PUNCT
eurjchem-604	747	20	dodecahedron	dodecahedron	NOUN
eurjchem-604	747	21	9	9	NUM
eurjchem-604	747	22	tricapped	tricappe	VERB
eurjchem-604	747	23	trigonal	trigonal	ADJ
eurjchem-604	747	24	prism	prism	NOUN
eurjchem-604	747	25	10	10	NUM
eurjchem-604	747	26	bicapped	bicappe	VERB
eurjchem-604	747	27	square	square	ADJ
eurjchem-604	747	28	antiprism	antiprism	NOUN
eurjchem-604	747	29	11	11	NUM
eurjchem-604	747	30	octadecahedron	octadecahedron	NOUN
eurjchem-604	747	31	12	12	NUM
eurjchem-604	747	32	icosahedron	icosahedron	X
eurjchem-604	747	33	(	(	PUNCT
eurjchem-604	747	34	bicapped	bicappe	VERB
eurjchem-604	747	35	pentagonal	pentagonal	ADJ
eurjchem-604	747	36	antiprism	antiprism	NOUN
eurjchem-604	747	37	)	)	PUNCT
eurjchem-604	747	38	using	use	VERB
eurjchem-604	747	39	the	the	DET
eurjchem-604	747	40	electron	electron	NOUN
eurjchem-604	747	41	count	count	NOUN
eurjchem-604	747	42	,	,	PUNCT
eurjchem-604	747	43	the	the	DET
eurjchem-604	747	44	predicted	predict	VERB
eurjchem-604	747	45	structure	structure	NOUN
eurjchem-604	747	46	can	can	AUX
eurjchem-604	747	47	be	be	AUX
eurjchem-604	747	48	found	find	VERB
eurjchem-604	747	49	.	.	PUNCT
eurjchem-604	748	1	n	n	PRON
eurjchem-604	748	2	is	be	AUX
eurjchem-604	748	3	the	the	DET
eurjchem-604	748	4	number	number	NOUN
eurjchem-604	748	5	of	of	ADP
eurjchem-604	748	6	vertices	vertex	NOUN
eurjchem-604	748	7	in	in	ADP
eurjchem-604	748	8	the	the	DET
eurjchem-604	748	9	cluster	cluster	NOUN
eurjchem-604	748	10	.	.	PUNCT
eurjchem-604	749	1	the	the	DET
eurjchem-604	749	2	4n	4n	PROPN
eurjchem-604	749	3	rules	rule	NOUN
eurjchem-604	749	4	are	be	AUX
eurjchem-604	749	5	enumerated	enumerate	VERB
eurjchem-604	749	6	in	in	ADP
eurjchem-604	749	7	table	table	NOUN
eurjchem-604	749	8	8	8	NUM
eurjchem-604	749	9	.	.	PUNCT
eurjchem-604	749	10	table	table	NOUN
eurjchem-604	749	11	8	8	NUM
eurjchem-604	749	12	.	.	PUNCT
eurjchem-604	750	1	structure	structure	NOUN
eurjchem-604	750	2	prediction	prediction	NOUN
eurjchem-604	750	3	using	use	VERB
eurjchem-604	750	4	electron	electron	NOUN
eurjchem-604	750	5	count	count	NOUN
eurjchem-604	750	6	.	.	PUNCT
eurjchem-604	751	1	electron	electron	NOUN
eurjchem-604	751	2	count	count	NOUN
eurjchem-604	751	3	name	name	NOUN
eurjchem-604	751	4	predicted	predict	VERB
eurjchem-604	751	5	structure	structure	NOUN
eurjchem-604	751	6	4n‐2	4n‐2	NUM
eurjchem-604	751	7	bicapped	bicappe	VERB
eurjchem-604	751	8	closo	closo	NOUN
eurjchem-604	751	9	n‐2	n‐2	PROPN
eurjchem-604	751	10	vertex	vertex	NOUN
eurjchem-604	751	11	closo	closo	NOUN
eurjchem-604	751	12	polyhedron	polyhedron	NOUN
eurjchem-604	751	13	with	with	ADP
eurjchem-604	751	14	2	2	NUM
eurjchem-604	751	15	capped	cap	VERB
eurjchem-604	751	16	faces	face	NOUN
eurjchem-604	751	17	4n	4n	NOUN
eurjchem-604	751	18	capped	cap	VERB
eurjchem-604	751	19	closo	closo	NOUN
eurjchem-604	751	20	n‐1	n‐1	PRON
eurjchem-604	751	21	vertex	vertex	NOUN
eurjchem-604	751	22	closo	closo	NOUN
eurjchem-604	751	23	polyhedron	polyhedron	NOUN
eurjchem-604	751	24	with	with	ADP
eurjchem-604	751	25	1	1	NUM
eurjchem-604	751	26	face	face	NOUN
eurjchem-604	751	27	capped	cap	VERB
eurjchem-604	751	28	4n+2	4n+2	PROPN
eurjchem-604	751	29	closo	closo	NOUN
eurjchem-604	751	30	closo	closo	NOUN
eurjchem-604	751	31	polyhedron	polyhedron	NOUN
eurjchem-604	751	32	with	with	ADP
eurjchem-604	751	33	n	n	ADP
eurjchem-604	751	34	vertices	vertice	VERB
eurjchem-604	751	35	4n+4	4n+4	PROPN
eurjchem-604	751	36	nido	nido	PROPN
eurjchem-604	751	37	n+1	n+1	PROPN
eurjchem-604	751	38	vertex	vertex	NOUN
eurjchem-604	751	39	closo	closo	NOUN
eurjchem-604	751	40	polyhedron	polyhedron	NOUN
eurjchem-604	751	41	with	with	ADP
eurjchem-604	751	42	1	1	NUM
eurjchem-604	751	43	missing	miss	VERB
eurjchem-604	751	44	vertex	vertex	NOUN
eurjchem-604	751	45	4n+6	4n+6	PROPN
eurjchem-604	751	46	arachno	arachno	VERB
eurjchem-604	751	47	n+2	n+2	PRON
eurjchem-604	751	48	vertex	vertex	NOUN
eurjchem-604	751	49	closo	closo	NOUN
eurjchem-604	751	50	polyhedron	polyhedron	NOUN
eurjchem-604	751	51	with	with	ADP
eurjchem-604	751	52	2	2	NUM
eurjchem-604	751	53	missing	miss	VERB
eurjchem-604	751	54	vertices	vertex	NOUN
eurjchem-604	751	55	4n+8	4n+8	PROPN
eurjchem-604	751	56	hypho	hypho	NOUN
eurjchem-604	751	57	n+3	n+3	PROPN
eurjchem-604	751	58	vertex	vertex	NOUN
eurjchem-604	751	59	closo	closo	NOUN
eurjchem-604	751	60	polyhderon	polyhderon	NOUN
eurjchem-604	751	61	with	with	ADP
eurjchem-604	751	62	3	3	NUM
eurjchem-604	751	63	missing	miss	VERB
eurjchem-604	751	64	vertices	vertex	NOUN
eurjchem-604	751	65	when	when	SCONJ
eurjchem-604	751	66	counting	count	VERB
eurjchem-604	751	67	electrons	electron	NOUN
eurjchem-604	751	68	for	for	ADP
eurjchem-604	751	69	each	each	DET
eurjchem-604	751	70	cluster	cluster	NOUN
eurjchem-604	751	71	,	,	PUNCT
eurjchem-604	751	72	the	the	DET
eurjchem-604	751	73	number	number	NOUN
eurjchem-604	751	74	of	of	ADP
eurjchem-604	751	75	valence	valence	NOUN
eurjchem-604	751	76	electrons	electron	NOUN
eurjchem-604	751	77	is	be	AUX
eurjchem-604	751	78	enumerated	enumerate	VERB
eurjchem-604	751	79	.	.	PUNCT
eurjchem-604	752	1	for	for	ADP
eurjchem-604	752	2	each	each	DET
eurjchem-604	752	3	transition	transition	NOUN
eurjchem-604	752	4	metal	metal	NOUN
eurjchem-604	752	5	present	present	NOUN
eurjchem-604	752	6	,	,	PUNCT
eurjchem-604	752	7	10	10	NUM
eurjchem-604	752	8	electrons	electron	NOUN
eurjchem-604	752	9	are	be	AUX
eurjchem-604	752	10	subtracted	subtract	VERB
eurjchem-604	752	11	from	from	ADP
eurjchem-604	752	12	the	the	DET
eurjchem-604	752	13	total	total	ADJ
eurjchem-604	752	14	electron	electron	NOUN
eurjchem-604	752	15	count	count	NOUN
eurjchem-604	752	16	.	.	PUNCT
eurjchem-604	753	1	for	for	ADP
eurjchem-604	753	2	example	example	NOUN
eurjchem-604	753	3	,	,	PUNCT
eurjchem-604	753	4	in	in	ADP
eurjchem-604	753	5	rh6(co)16	rh6(co)16	NOUN
eurjchem-604	753	6	the	the	DET
eurjchem-604	753	7	total	total	ADJ
eurjchem-604	753	8	number	number	NOUN
eurjchem-604	753	9	of	of	ADP
eurjchem-604	753	10	electrons	electron	NOUN
eurjchem-604	753	11	would	would	AUX
eurjchem-604	753	12	be	be	AUX
eurjchem-604	753	13	6(9	6(9	NUM
eurjchem-604	753	14	)	)	PUNCT
eurjchem-604	754	1	+	+	NUM
eurjchem-604	755	1	16(2	16(2	X
eurjchem-604	755	2	)	)	PUNCT
eurjchem-604	755	3	‐	‐	NOUN
eurjchem-604	755	4	6(10	6(10	NUM
eurjchem-604	755	5	)	)	PUNCT
eurjchem-604	755	6	=	=	PUNCT
eurjchem-604	756	1	86	86	NUM
eurjchem-604	756	2	‐	‐	NOUN
eurjchem-604	756	3	6(10	6(10	NUM
eurjchem-604	756	4	)	)	PUNCT
eurjchem-604	756	5	=	=	SYM
eurjchem-604	757	1	26	26	NUM
eurjchem-604	757	2	.	.	PUNCT
eurjchem-604	758	1	therefore	therefore	ADV
eurjchem-604	758	2	,	,	PUNCT
eurjchem-604	758	3	the	the	DET
eurjchem-604	758	4	cluster	cluster	NOUN
eurjchem-604	758	5	is	be	AUX
eurjchem-604	758	6	a	a	DET
eurjchem-604	758	7	closo	closo	NOUN
eurjchem-604	758	8	polyhedron	polyhedron	NOUN
eurjchem-604	758	9	because	because	SCONJ
eurjchem-604	758	10	n	n	PROPN
eurjchem-604	758	11	=	=	SYM
eurjchem-604	758	12	6	6	NUM
eurjchem-604	758	13	,	,	PUNCT
eurjchem-604	758	14	with	with	ADP
eurjchem-604	758	15	4n	4n	NUM
eurjchem-604	758	16	+	+	CCONJ
eurjchem-604	758	17	2	2	NUM
eurjchem-604	758	18	=	=	SYM
eurjchem-604	758	19	26	26	NUM
eurjchem-604	758	20	.	.	PUNCT
eurjchem-604	759	1	other	other	ADJ
eurjchem-604	759	2	rules	rule	NOUN
eurjchem-604	759	3	may	may	AUX
eurjchem-604	759	4	be	be	AUX
eurjchem-604	759	5	considered	consider	VERB
eurjchem-604	759	6	when	when	SCONJ
eurjchem-604	759	7	predicting	predict	VERB
eurjchem-604	759	8	the	the	DET
eurjchem-604	759	9	structure	structure	NOUN
eurjchem-604	759	10	of	of	ADP
eurjchem-604	759	11	clusters	cluster	NOUN
eurjchem-604	759	12	:	:	PUNCT
eurjchem-604	759	13	1	1	X
eurjchem-604	759	14	.	.	X
eurjchem-604	759	15	for	for	ADP
eurjchem-604	759	16	clusters	cluster	NOUN
eurjchem-604	759	17	consisting	consist	VERB
eurjchem-604	759	18	mostly	mostly	ADV
eurjchem-604	759	19	of	of	ADP
eurjchem-604	759	20	transition	transition	NOUN
eurjchem-604	759	21	metals	metal	NOUN
eurjchem-604	759	22	,	,	PUNCT
eurjchem-604	759	23	any	any	DET
eurjchem-604	759	24	main	main	ADJ
eurjchem-604	759	25	group	group	NOUN
eurjchem-604	759	26	elements	element	NOUN
eurjchem-604	759	27	present	present	ADJ
eurjchem-604	759	28	are	be	AUX
eurjchem-604	759	29	often	often	ADV
eurjchem-604	759	30	best	well	ADV
eurjchem-604	759	31	counted	count	VERB
eurjchem-604	759	32	as	as	ADP
eurjchem-604	759	33	ligands	ligand	NOUN
eurjchem-604	759	34	or	or	CCONJ
eurjchem-604	759	35	interstitial	interstitial	ADJ
eurjchem-604	759	36	atoms	atom	NOUN
eurjchem-604	759	37	,	,	PUNCT
eurjchem-604	759	38	rather	rather	ADV
eurjchem-604	759	39	than	than	ADP
eurjchem-604	759	40	vertices	vertex	NOUN
eurjchem-604	759	41	.	.	PUNCT
eurjchem-604	760	1	2	2	X
eurjchem-604	760	2	.	.	X
eurjchem-604	760	3	larger	large	ADJ
eurjchem-604	760	4	and	and	CCONJ
eurjchem-604	760	5	more	more	ADV
eurjchem-604	760	6	electropositive	electropositive	ADJ
eurjchem-604	760	7	atoms	atom	NOUN
eurjchem-604	760	8	tend	tend	VERB
eurjchem-604	760	9	to	to	PART
eurjchem-604	760	10	occupy	occupy	VERB
eurjchem-604	760	11	vertices	vertex	NOUN
eurjchem-604	760	12	of	of	ADP
eurjchem-604	760	13	high	high	ADJ
eurjchem-604	760	14	connectivity	connectivity	NOUN
eurjchem-604	760	15	and	and	CCONJ
eurjchem-604	760	16	smaller	small	ADJ
eurjchem-604	760	17	more	more	ADV
eurjchem-604	760	18	electronegative	electronegative	ADJ
eurjchem-604	760	19	atoms	atom	NOUN
eurjchem-604	760	20	tend	tend	VERB
eurjchem-604	760	21	to	to	PART
eurjchem-604	760	22	occupy	occupy	VERB
eurjchem-604	760	23	vertices	vertex	NOUN
eurjchem-604	760	24	of	of	ADP
eurjchem-604	760	25	low	low	ADJ
eurjchem-604	760	26	connectivity	connectivity	NOUN
eurjchem-604	760	27	.	.	PUNCT
eurjchem-604	761	1	3	3	X
eurjchem-604	761	2	.	.	X
eurjchem-604	761	3	in	in	ADP
eurjchem-604	761	4	the	the	DET
eurjchem-604	761	5	special	special	ADJ
eurjchem-604	761	6	case	case	NOUN
eurjchem-604	761	7	of	of	ADP
eurjchem-604	761	8	boron	boron	NOUN
eurjchem-604	761	9	hydride	hydride	NOUN
eurjchem-604	761	10	clusters	cluster	NOUN
eurjchem-604	761	11	,	,	PUNCT
eurjchem-604	761	12	each	each	DET
eurjchem-604	761	13	boron	boron	NOUN
eurjchem-604	761	14	connected	connect	VERB
eurjchem-604	761	15	to	to	ADP
eurjchem-604	761	16	3	3	NUM
eurjchem-604	761	17	or	or	CCONJ
eurjchem-604	761	18	more	more	ADJ
eurjchem-604	761	19	vertices	vertex	NOUN
eurjchem-604	761	20	has	have	VERB
eurjchem-604	761	21	one	one	NUM
eurjchem-604	761	22	terminal	terminal	ADJ
eurjchem-604	761	23	hydride	hydride	NOUN
eurjchem-604	761	24	,	,	PUNCT
eurjchem-604	761	25	while	while	SCONJ
eurjchem-604	761	26	a	a	DET
eurjchem-604	761	27	boron	boron	NOUN
eurjchem-604	761	28	connected	connect	VERB
eurjchem-604	761	29	to	to	ADP
eurjchem-604	761	30	2	2	NUM
eurjchem-604	761	31	other	other	ADJ
eurjchem-604	761	32	vertices	vertex	NOUN
eurjchem-604	761	33	has	have	VERB
eurjchem-604	761	34	2	2	NUM
eurjchem-604	761	35	terminal	terminal	ADJ
eurjchem-604	761	36	hydrogens	hydrogen	NOUN
eurjchem-604	761	37	.	.	PUNCT
eurjchem-604	762	1	if	if	SCONJ
eurjchem-604	762	2	more	more	ADJ
eurjchem-604	762	3	hydrogens	hydrogen	NOUN
eurjchem-604	762	4	are	be	AUX
eurjchem-604	762	5	present	present	ADJ
eurjchem-604	762	6	,	,	PUNCT
eurjchem-604	762	7	they	they	PRON
eurjchem-604	762	8	are	be	AUX
eurjchem-604	762	9	placed	place	VERB
eurjchem-604	762	10	in	in	ADP
eurjchem-604	762	11	open	open	ADJ
eurjchem-604	762	12	face	face	NOUN
eurjchem-604	762	13	positions	position	NOUN
eurjchem-604	762	14	to	to	PART
eurjchem-604	762	15	even	even	ADV
eurjchem-604	762	16	out	out	ADP
eurjchem-604	762	17	the	the	DET
eurjchem-604	762	18	coordination	coordination	NOUN
eurjchem-604	762	19	number	number	NOUN
eurjchem-604	762	20	of	of	ADP
eurjchem-604	762	21	the	the	DET
eurjchem-604	762	22	vertices	vertex	NOUN
eurjchem-604	762	23	.	.	PUNCT
eurjchem-604	763	1	4	4	X
eurjchem-604	763	2	.	.	X
eurjchem-604	763	3	for	for	ADP
eurjchem-604	763	4	the	the	DET
eurjchem-604	763	5	special	special	ADJ
eurjchem-604	763	6	case	case	NOUN
eurjchem-604	763	7	of	of	ADP
eurjchem-604	763	8	transition	transition	NOUN
eurjchem-604	763	9	metal	metal	NOUN
eurjchem-604	763	10	clusters	cluster	NOUN
eurjchem-604	763	11	,	,	PUNCT
eurjchem-604	763	12	ligands	ligand	NOUN
eurjchem-604	763	13	are	be	AUX
eurjchem-604	763	14	added	add	VERB
eurjchem-604	763	15	to	to	ADP
eurjchem-604	763	16	the	the	DET
eurjchem-604	763	17	metal	metal	NOUN
eurjchem-604	763	18	centers	center	NOUN
eurjchem-604	763	19	to	to	PART
eurjchem-604	763	20	give	give	VERB
eurjchem-604	763	21	the	the	DET
eurjchem-604	763	22	metals	metal	NOUN
eurjchem-604	763	23	reasonable	reasonable	ADJ
eurjchem-604	763	24	coordination	coordination	NOUN
eurjchem-604	763	25	numbers	number	NOUN
eurjchem-604	763	26	,	,	PUNCT
eurjchem-604	763	27	and	and	CCONJ
eurjchem-604	763	28	if	if	SCONJ
eurjchem-604	763	29	any	any	DET
eurjchem-604	763	30	hydrogen	hydrogen	NOUN
eurjchem-604	763	31	atoms	atom	NOUN
eurjchem-604	763	32	are	be	AUX
eurjchem-604	763	33	present	present	ADJ
eurjchem-604	763	34	they	they	PRON
eurjchem-604	763	35	are	be	AUX
eurjchem-604	763	36	placed	place	VERB
eurjchem-604	763	37	in	in	ADP
eurjchem-604	763	38	bridging	bridging	NOUN
eurjchem-604	763	39	positions	position	NOUN
eurjchem-604	763	40	to	to	PART
eurjchem-604	763	41	even	even	ADV
eurjchem-604	763	42	out	out	ADP
eurjchem-604	763	43	the	the	DET
eurjchem-604	763	44	coordination	coordination	NOUN
eurjchem-604	763	45	numbers	number	NOUN
eurjchem-604	763	46	of	of	ADP
eurjchem-604	763	47	the	the	DET
eurjchem-604	763	48	vertices	vertex	NOUN
eurjchem-604	763	49	.	.	PUNCT
eurjchem-604	764	1	in	in	ADP
eurjchem-604	764	2	general	general	ADJ
eurjchem-604	764	3	,	,	PUNCT
eurjchem-604	764	4	closo	closo	NOUN
eurjchem-604	764	5	structures	structure	NOUN
eurjchem-604	764	6	with	with	ADP
eurjchem-604	764	7	n	n	DET
eurjchem-604	764	8	vertices	vertex	NOUN
eurjchem-604	764	9	are	be	AUX
eurjchem-604	764	10	n‐vertex	n‐vertex	X
eurjchem-604	764	11	polyhedra	polyhedra	NOUN
eurjchem-604	764	12	.	.	PUNCT
eurjchem-604	765	1	to	to	PART
eurjchem-604	765	2	predict	predict	VERB
eurjchem-604	765	3	the	the	DET
eurjchem-604	765	4	structure	structure	NOUN
eurjchem-604	765	5	of	of	ADP
eurjchem-604	765	6	a	a	DET
eurjchem-604	765	7	nido	nido	NOUN
eurjchem-604	765	8	cluster	cluster	NOUN
eurjchem-604	765	9	,	,	PUNCT
eurjchem-604	765	10	the	the	DET
eurjchem-604	765	11	closo	closo	NOUN
eurjchem-604	765	12	cluster	cluster	NOUN
eurjchem-604	765	13	with	with	ADP
eurjchem-604	765	14	n	n	PROPN
eurjchem-604	765	15	+	+	CCONJ
eurjchem-604	765	16	1	1	NUM
eurjchem-604	765	17	vertices	vertex	NOUN
eurjchem-604	765	18	is	be	AUX
eurjchem-604	765	19	used	use	VERB
eurjchem-604	765	20	as	as	ADP
eurjchem-604	765	21	a	a	DET
eurjchem-604	765	22	starting	starting	NOUN
eurjchem-604	765	23	point	point	NOUN
eurjchem-604	765	24	;	;	PUNCT
eurjchem-604	765	25	if	if	SCONJ
eurjchem-604	765	26	the	the	DET
eurjchem-604	765	27	cluster	cluster	NOUN
eurjchem-604	765	28	is	be	AUX
eurjchem-604	765	29	composed	compose	VERB
eurjchem-604	765	30	of	of	ADP
eurjchem-604	765	31	small	small	ADJ
eurjchem-604	765	32	atoms	atom	NOUN
eurjchem-604	765	33	a	a	DET
eurjchem-604	765	34	high	high	ADJ
eurjchem-604	765	35	connectivity	connectivity	NOUN
eurjchem-604	765	36	vertex	vertex	NOUN
eurjchem-604	765	37	is	be	AUX
eurjchem-604	765	38	removed	remove	VERB
eurjchem-604	765	39	,	,	PUNCT
eurjchem-604	765	40	while	while	SCONJ
eurjchem-604	765	41	if	if	SCONJ
eurjchem-604	765	42	the	the	DET
eurjchem-604	765	43	cluster	cluster	NOUN
eurjchem-604	765	44	is	be	AUX
eurjchem-604	765	45	composed	compose	VERB
eurjchem-604	765	46	of	of	ADP
eurjchem-604	765	47	large	large	ADJ
eurjchem-604	765	48	atoms	atom	NOUN
eurjchem-604	765	49	a	a	DET
eurjchem-604	765	50	low	low	ADJ
eurjchem-604	765	51	retracted	retracted	ADJ
eurjchem-604	765	52	kaushik	kaushik	PROPN
eurjchem-604	765	53	et	et	PROPN
eurjchem-604	765	54	al	al	PROPN
eurjchem-604	765	55	.	.	PUNCT
eurjchem-604	765	56	/	/	SYM
eurjchem-604	765	57	european	european	PROPN
eurjchem-604	765	58	journal	journal	PROPN
eurjchem-604	765	59	of	of	ADP
eurjchem-604	765	60	chemistry	chemistry	NOUN
eurjchem-604	765	61	3	3	NUM
eurjchem-604	765	62	(	(	PUNCT
eurjchem-604	765	63	3	3	NUM
eurjchem-604	765	64	)	)	PUNCT
eurjchem-604	765	65	(	(	PUNCT
eurjchem-604	765	66	2012	2012	NUM
eurjchem-604	765	67	)	)	PUNCT
eurjchem-604	765	68	367‐394	367‐394	NOUN
eurjchem-604	765	69	385	385	NUM
eurjchem-604	765	70	connectivity	connectivity	NOUN
eurjchem-604	765	71	vertex	vertex	NOUN
eurjchem-604	765	72	is	be	AUX
eurjchem-604	765	73	removed	remove	VERB
eurjchem-604	765	74	.	.	PUNCT
eurjchem-604	766	1	to	to	PART
eurjchem-604	766	2	predict	predict	VERB
eurjchem-604	766	3	the	the	DET
eurjchem-604	766	4	structure	structure	NOUN
eurjchem-604	766	5	of	of	ADP
eurjchem-604	766	6	an	an	DET
eurjchem-604	766	7	arachno	arachno	NOUN
eurjchem-604	766	8	cluster	cluster	NOUN
eurjchem-604	766	9	,	,	PUNCT
eurjchem-604	766	10	the	the	DET
eurjchem-604	766	11	closo	closo	NOUN
eurjchem-604	766	12	polyhedron	polyhedron	NOUN
eurjchem-604	766	13	with	with	ADP
eurjchem-604	766	14	n	n	NOUN
eurjchem-604	766	15	+	+	CCONJ
eurjchem-604	766	16	2	2	NUM
eurjchem-604	766	17	vertices	vertex	NOUN
eurjchem-604	766	18	is	be	AUX
eurjchem-604	766	19	used	use	VERB
eurjchem-604	766	20	as	as	ADP
eurjchem-604	766	21	the	the	DET
eurjchem-604	766	22	starting	starting	NOUN
eurjchem-604	766	23	point	point	NOUN
eurjchem-604	766	24	,	,	PUNCT
eurjchem-604	766	25	and	and	CCONJ
eurjchem-604	766	26	the	the	DET
eurjchem-604	766	27	n+1	n+1	PROPN
eurjchem-604	766	28	vertex	vertex	NOUN
eurjchem-604	766	29	nido	nido	NOUN
eurjchem-604	766	30	complex	complex	NOUN
eurjchem-604	766	31	is	be	AUX
eurjchem-604	766	32	generated	generate	VERB
eurjchem-604	766	33	by	by	ADP
eurjchem-604	766	34	following	follow	VERB
eurjchem-604	766	35	the	the	DET
eurjchem-604	766	36	rule	rule	NOUN
eurjchem-604	766	37	above	above	ADV
eurjchem-604	766	38	;	;	PUNCT
eurjchem-604	766	39	a	a	DET
eurjchem-604	766	40	second	second	ADJ
eurjchem-604	766	41	vertex	vertex	NOUN
eurjchem-604	766	42	adjacent	adjacent	ADJ
eurjchem-604	766	43	to	to	ADP
eurjchem-604	766	44	the	the	DET
eurjchem-604	766	45	first	first	ADJ
eurjchem-604	766	46	is	be	AUX
eurjchem-604	766	47	removed	remove	VERB
eurjchem-604	766	48	if	if	SCONJ
eurjchem-604	766	49	the	the	DET
eurjchem-604	766	50	cluster	cluster	NOUN
eurjchem-604	766	51	is	be	AUX
eurjchem-604	766	52	composed	compose	VERB
eurjchem-604	766	53	of	of	ADP
eurjchem-604	766	54	mostly	mostly	ADV
eurjchem-604	766	55	small	small	ADJ
eurjchem-604	766	56	atoms	atom	NOUN
eurjchem-604	766	57	,	,	PUNCT
eurjchem-604	766	58	a	a	DET
eurjchem-604	766	59	second	second	ADJ
eurjchem-604	766	60	vertex	vertex	NOUN
eurjchem-604	766	61	not	not	PART
eurjchem-604	766	62	adjacent	adjacent	ADJ
eurjchem-604	766	63	to	to	ADP
eurjchem-604	766	64	the	the	DET
eurjchem-604	766	65	first	first	ADJ
eurjchem-604	766	66	is	be	AUX
eurjchem-604	766	67	removed	remove	VERB
eurjchem-604	766	68	if	if	SCONJ
eurjchem-604	766	69	the	the	DET
eurjchem-604	766	70	cluster	cluster	NOUN
eurjchem-604	766	71	is	be	AUX
eurjchem-604	766	72	composed	compose	VERB
eurjchem-604	766	73	mostly	mostly	ADV
eurjchem-604	766	74	of	of	ADP
eurjchem-604	766	75	large	large	ADJ
eurjchem-604	766	76	atoms	atom	NOUN
eurjchem-604	766	77	.	.	PUNCT
eurjchem-604	767	1	the	the	DET
eurjchem-604	767	2	bookkeeping	bookkeeping	NOUN
eurjchem-604	767	3	for	for	ADP
eurjchem-604	767	4	deltahedral	deltahedral	ADJ
eurjchem-604	767	5	clusters	cluster	NOUN
eurjchem-604	767	6	is	be	AUX
eurjchem-604	767	7	sometimes	sometimes	ADV
eurjchem-604	767	8	carried	carry	VERB
eurjchem-604	767	9	out	out	ADP
eurjchem-604	767	10	by	by	ADP
eurjchem-604	767	11	counting	count	VERB
eurjchem-604	767	12	skeletal	skeletal	ADJ
eurjchem-604	767	13	electrons	electron	NOUN
eurjchem-604	767	14	instead	instead	ADV
eurjchem-604	767	15	of	of	ADP
eurjchem-604	767	16	the	the	DET
eurjchem-604	767	17	total	total	ADJ
eurjchem-604	767	18	number	number	NOUN
eurjchem-604	767	19	of	of	ADP
eurjchem-604	767	20	electrons	electron	NOUN
eurjchem-604	767	21	.	.	PUNCT
eurjchem-604	768	1	the	the	DET
eurjchem-604	768	2	skeletal	skeletal	ADJ
eurjchem-604	768	3	orbital	orbital	NOUN
eurjchem-604	768	4	(	(	PUNCT
eurjchem-604	768	5	electron	electron	NOUN
eurjchem-604	768	6	pair	pair	NOUN
eurjchem-604	768	7	)	)	PUNCT
eurjchem-604	768	8	and	and	CCONJ
eurjchem-604	768	9	skeletal	skeletal	ADJ
eurjchem-604	768	10	electron	electron	NOUN
eurjchem-604	768	11	counts	count	NOUN
eurjchem-604	768	12	for	for	ADP
eurjchem-604	768	13	the	the	DET
eurjchem-604	768	14	four	four	NUM
eurjchem-604	768	15	types	type	NOUN
eurjchem-604	768	16	of	of	ADP
eurjchem-604	768	17	deltahedral	deltahedral	ADJ
eurjchem-604	768	18	clusters	cluster	NOUN
eurjchem-604	768	19	are	be	AUX
eurjchem-604	768	20	:	:	PUNCT
eurjchem-604	768	21			DET
eurjchem-604	768	22	n‐vertex	n‐vertex	PROPN
eurjchem-604	768	23	closo	closo	NOUN
eurjchem-604	768	24	:	:	PUNCT
eurjchem-604	768	25	(	(	PUNCT
eurjchem-604	768	26	n+1	n+1	NOUN
eurjchem-604	768	27	)	)	PUNCT
eurjchem-604	768	28	skeletal	skeletal	ADJ
eurjchem-604	768	29	orbitals	orbital	NOUN
eurjchem-604	768	30	,	,	PUNCT
eurjchem-604	768	31	(	(	PUNCT
eurjchem-604	768	32	2n+2	2n+2	ADV
eurjchem-604	768	33	)	)	PUNCT
eurjchem-604	768	34	skeletal	skeletal	ADJ
eurjchem-604	768	35	electrons	electron	NOUN
eurjchem-604	768	36			NOUN
eurjchem-604	768	37	n‐vertex	n‐vertex	X
eurjchem-604	768	38	nido	nido	NOUN
eurjchem-604	768	39	:	:	PUNCT
eurjchem-604	768	40	(	(	PUNCT
eurjchem-604	768	41	n+2	n+2	NOUN
eurjchem-604	768	42	)	)	PUNCT
eurjchem-604	768	43	skeletal	skeletal	ADJ
eurjchem-604	768	44	orbitals	orbital	NOUN
eurjchem-604	768	45	,	,	PUNCT
eurjchem-604	768	46	(	(	PUNCT
eurjchem-604	768	47	2n+4	2n+4	NOUN
eurjchem-604	768	48	)	)	PUNCT
eurjchem-604	768	49	skeletal	skeletal	ADJ
eurjchem-604	768	50	electrons	electron	NOUN
eurjchem-604	768	51			NOUN
eurjchem-604	768	52	n‐vertex	n‐vertex	NOUN
eurjchem-604	768	53	arachno	arachno	NOUN
eurjchem-604	768	54	:	:	PUNCT
eurjchem-604	768	55	(	(	PUNCT
eurjchem-604	768	56	n+3	n+3	NOUN
eurjchem-604	768	57	)	)	PUNCT
eurjchem-604	768	58	skeletal	skeletal	ADJ
eurjchem-604	768	59	orbitals	orbital	NOUN
eurjchem-604	768	60	,	,	PUNCT
eurjchem-604	768	61	(	(	PUNCT
eurjchem-604	768	62	2n+6	2n+6	NOUN
eurjchem-604	768	63	)	)	PUNCT
eurjchem-604	768	64	skeletal	skeletal	ADJ
eurjchem-604	768	65	electrons	electron	NOUN
eurjchem-604	768	66			NOUN
eurjchem-604	768	67	n‐vertex	n‐vertex	NOUN
eurjchem-604	768	68	hypho	hypho	NOUN
eurjchem-604	768	69	:	:	PUNCT
eurjchem-604	768	70	(	(	PUNCT
eurjchem-604	768	71	n+4	n+4	X
eurjchem-604	768	72	)	)	PUNCT
eurjchem-604	768	73	skeletal	skeletal	ADJ
eurjchem-604	768	74	orbitals	orbital	NOUN
eurjchem-604	768	75	,	,	PUNCT
eurjchem-604	768	76	(	(	PUNCT
eurjchem-604	768	77	2n+8	2n+8	NOUN
eurjchem-604	768	78	)	)	PUNCT
eurjchem-604	768	79	skeletal	skeletal	ADJ
eurjchem-604	768	80	electrons	electron	NOUN
eurjchem-604	768	81	the	the	DET
eurjchem-604	768	82	skeletal	skeletal	ADJ
eurjchem-604	768	83	electron	electron	NOUN
eurjchem-604	768	84	counts	count	NOUN
eurjchem-604	768	85	are	be	AUX
eurjchem-604	768	86	determined	determine	VERB
eurjchem-604	768	87	by	by	ADP
eurjchem-604	768	88	summing	sum	VERB
eurjchem-604	768	89	the	the	DET
eurjchem-604	768	90	total	total	NOUN
eurjchem-604	768	91	of	of	ADP
eurjchem-604	768	92	the	the	DET
eurjchem-604	768	93	following	follow	VERB
eurjchem-604	768	94	number	number	NOUN
eurjchem-604	768	95	of	of	ADP
eurjchem-604	768	96	electrons	electron	NOUN
eurjchem-604	768	97	:	:	PUNCT
eurjchem-604	768	98			X
eurjchem-604	768	99	2	2	NUM
eurjchem-604	768	100	from	from	ADP
eurjchem-604	768	101	each	each	DET
eurjchem-604	768	102	bh	bh	NOUN
eurjchem-604	768	103	unit	unit	NOUN
eurjchem-604	768	104			X
eurjchem-604	768	105	3	3	NUM
eurjchem-604	768	106	from	from	ADP
eurjchem-604	768	107	each	each	DET
eurjchem-604	768	108	ch	ch	NOUN
eurjchem-604	768	109	unit	unit	NOUN
eurjchem-604	768	110			NOUN
eurjchem-604	768	111	1	1	NUM
eurjchem-604	768	112	from	from	ADP
eurjchem-604	768	113	each	each	DET
eurjchem-604	768	114	additional	additional	ADJ
eurjchem-604	768	115	hydrogen	hydrogen	NOUN
eurjchem-604	768	116	atom	atom	NOUN
eurjchem-604	768	117	(	(	PUNCT
eurjchem-604	768	118	over	over	ADP
eurjchem-604	768	119	and	and	CCONJ
eurjchem-604	768	120	above	above	ADP
eurjchem-604	768	121	the	the	DET
eurjchem-604	768	122	ones	one	NOUN
eurjchem-604	768	123	on	on	ADP
eurjchem-604	768	124	the	the	DET
eurjchem-604	768	125	bh	bh	NOUN
eurjchem-604	768	126	and	and	CCONJ
eurjchem-604	768	127	ch	ch	PROPN
eurjchem-604	768	128	units	unit	NOUN
eurjchem-604	768	129	)	)	PUNCT
eurjchem-604	768	130			NOUN
eurjchem-604	769	1	the	the	DET
eurjchem-604	769	2	anionic	anionic	ADJ
eurjchem-604	769	3	charge	charge	NOUN
eurjchem-604	769	4	electrons	electron	NOUN
eurjchem-604	769	5	5.3.2	5.3.2	NUM
eurjchem-604	769	6	.	.	PUNCT
eurjchem-604	769	7	5n	5n	NUM
eurjchem-604	769	8	rules	rule	NOUN
eurjchem-604	769	9	as	as	SCONJ
eurjchem-604	769	10	discussed	discuss	VERB
eurjchem-604	769	11	previously	previously	ADV
eurjchem-604	769	12	,	,	PUNCT
eurjchem-604	769	13	the	the	DET
eurjchem-604	769	14	4n	4n	ADJ
eurjchem-604	769	15	rule	rule	NOUN
eurjchem-604	769	16	mainly	mainly	ADV
eurjchem-604	769	17	deals	deal	VERB
eurjchem-604	769	18	with	with	ADP
eurjchem-604	769	19	clusters	cluster	NOUN
eurjchem-604	769	20	with	with	ADP
eurjchem-604	769	21	electron	electron	NOUN
eurjchem-604	769	22	counts	count	NOUN
eurjchem-604	769	23	of	of	ADP
eurjchem-604	769	24	4n+k	4n+k	NUM
eurjchem-604	769	25	,	,	PUNCT
eurjchem-604	769	26	in	in	ADP
eurjchem-604	769	27	which	which	PRON
eurjchem-604	769	28	approximately	approximately	ADV
eurjchem-604	769	29	4	4	NUM
eurjchem-604	769	30	electrons	electron	NOUN
eurjchem-604	769	31	are	be	AUX
eurjchem-604	769	32	on	on	ADP
eurjchem-604	769	33	each	each	DET
eurjchem-604	769	34	vertex	vertex	NOUN
eurjchem-604	769	35	.	.	PUNCT
eurjchem-604	770	1	as	as	SCONJ
eurjchem-604	770	2	more	more	ADJ
eurjchem-604	770	3	electrons	electron	NOUN
eurjchem-604	770	4	are	be	AUX
eurjchem-604	770	5	added	add	VERB
eurjchem-604	770	6	per	per	ADP
eurjchem-604	770	7	vertex	vertex	NOUN
eurjchem-604	770	8	,	,	PUNCT
eurjchem-604	770	9	the	the	DET
eurjchem-604	770	10	number	number	NOUN
eurjchem-604	770	11	of	of	ADP
eurjchem-604	770	12	the	the	DET
eurjchem-604	770	13	electrons	electron	NOUN
eurjchem-604	770	14	per	per	ADP
eurjchem-604	770	15	vertex	vertex	NOUN
eurjchem-604	770	16	approaches	approach	NOUN
eurjchem-604	770	17	5	5	NUM
eurjchem-604	770	18	.	.	PUNCT
eurjchem-604	770	19	rather	rather	ADV
eurjchem-604	770	20	than	than	ADP
eurjchem-604	770	21	adopting	adopt	VERB
eurjchem-604	770	22	structures	structure	NOUN
eurjchem-604	770	23	based	base	VERB
eurjchem-604	770	24	on	on	ADP
eurjchem-604	770	25	deltahedra	deltahedra	NOUN
eurjchem-604	770	26	,	,	PUNCT
eurjchem-604	770	27	the	the	DET
eurjchem-604	770	28	5n‐	5n‐	NUM
eurjchem-604	770	29	type	type	NOUN
eurjchem-604	770	30	clusters	cluster	NOUN
eurjchem-604	770	31	have	have	VERB
eurjchem-604	770	32	structures	structure	NOUN
eurjchem-604	770	33	based	base	VERB
eurjchem-604	770	34	on	on	ADP
eurjchem-604	770	35	a	a	DET
eurjchem-604	770	36	different	different	ADJ
eurjchem-604	770	37	series	series	NOUN
eurjchem-604	770	38	of	of	ADP
eurjchem-604	770	39	polyhedra	polyhedra	NOUN
eurjchem-604	770	40	known	know	VERB
eurjchem-604	770	41	as	as	ADP
eurjchem-604	770	42	the	the	DET
eurjchem-604	770	43	3‐connectedpolyhedra	3‐connectedpolyhedra	NOUN
eurjchem-604	770	44	,	,	PUNCT
eurjchem-604	770	45	in	in	ADP
eurjchem-604	770	46	which	which	PRON
eurjchem-604	770	47	each	each	DET
eurjchem-604	770	48	vertex	vertex	NOUN
eurjchem-604	770	49	is	be	AUX
eurjchem-604	770	50	connected	connect	VERB
eurjchem-604	770	51	to	to	ADP
eurjchem-604	770	52	3	3	NUM
eurjchem-604	770	53	other	other	ADJ
eurjchem-604	770	54	vertices	vertex	NOUN
eurjchem-604	770	55	.	.	PUNCT
eurjchem-604	771	1	the	the	DET
eurjchem-604	771	2	common	common	ADJ
eurjchem-604	771	3	types	type	NOUN
eurjchem-604	771	4	of	of	ADP
eurjchem-604	771	5	3‐	3‐	NUM
eurjchem-604	771	6	connected	connected	ADJ
eurjchem-604	771	7	polyhedra	polyhedra	NOUN
eurjchem-604	771	8	are	be	AUX
eurjchem-604	771	9	listed	list	VERB
eurjchem-604	771	10	in	in	ADP
eurjchem-604	771	11	table	table	NOUN
eurjchem-604	771	12	9	9	NUM
eurjchem-604	771	13	.	.	PUNCT
eurjchem-604	771	14	table	table	NOUN
eurjchem-604	771	15	9	9	NUM
eurjchem-604	771	16	.	.	PUNCT
eurjchem-604	771	17	prediction	prediction	NOUN
eurjchem-604	771	18	of	of	ADP
eurjchem-604	771	19	polyhedron	polyhedron	NOUN
eurjchem-604	771	20	structure	structure	NOUN
eurjchem-604	771	21	based	base	VERB
eurjchem-604	771	22	on	on	ADP
eurjchem-604	771	23	number	number	NOUN
eurjchem-604	771	24	of	of	ADP
eurjchem-604	771	25	vertices	vertex	NOUN
eurjchem-604	771	26	in	in	ADP
eurjchem-604	771	27	cluster	cluster	NOUN
eurjchem-604	771	28	.	.	PUNCT
eurjchem-604	772	1	number	number	NOUN
eurjchem-604	772	2	of	of	ADP
eurjchem-604	772	3	vertices	vertex	NOUN
eurjchem-604	772	4	type	type	NOUN
eurjchem-604	772	5	of	of	ADP
eurjchem-604	772	6	3‐connected	3‐connecte	VERB
eurjchem-604	772	7	polyhedron	polyhedron	NOUN
eurjchem-604	772	8	4	4	NUM
eurjchem-604	772	9	tetrahedron	tetrahedron	NOUN
eurjchem-604	772	10	6	6	NUM
eurjchem-604	772	11	trigonal	trigonal	ADJ
eurjchem-604	772	12	prism	prism	NOUN
eurjchem-604	772	13	8	8	NUM
eurjchem-604	772	14	cube	cube	NOUN
eurjchem-604	772	15	10	10	NUM
eurjchem-604	772	16	pentagonal	pentagonal	ADJ
eurjchem-604	772	17	prism	prism	NOUN
eurjchem-604	772	18	12	12	NUM
eurjchem-604	772	19	d2d	d2d	NOUN
eurjchem-604	772	20	pseudo‐octahedron	pseudo‐octahedron	NOUN
eurjchem-604	772	21	using	use	VERB
eurjchem-604	772	22	the	the	DET
eurjchem-604	772	23	electron	electron	NOUN
eurjchem-604	772	24	count	count	NOUN
eurjchem-604	772	25	,	,	PUNCT
eurjchem-604	772	26	the	the	DET
eurjchem-604	772	27	predicted	predict	VERB
eurjchem-604	772	28	structure	structure	NOUN
eurjchem-604	772	29	can	can	AUX
eurjchem-604	772	30	be	be	AUX
eurjchem-604	772	31	found	find	VERB
eurjchem-604	772	32	.	.	PUNCT
eurjchem-604	773	1	n	n	PRON
eurjchem-604	773	2	is	be	AUX
eurjchem-604	773	3	the	the	DET
eurjchem-604	773	4	number	number	NOUN
eurjchem-604	773	5	of	of	ADP
eurjchem-604	773	6	vertices	vertex	NOUN
eurjchem-604	773	7	in	in	ADP
eurjchem-604	773	8	the	the	DET
eurjchem-604	773	9	cluster	cluster	NOUN
eurjchem-604	773	10	.	.	PUNCT
eurjchem-604	774	1	the	the	DET
eurjchem-604	774	2	5n	5n	NOUN
eurjchem-604	774	3	rules	rule	NOUN
eurjchem-604	774	4	are	be	AUX
eurjchem-604	774	5	given	give	VERB
eurjchem-604	774	6	in	in	ADP
eurjchem-604	774	7	table	table	NOUN
eurjchem-604	774	8	10	10	NUM
eurjchem-604	774	9	.	.	PUNCT
eurjchem-604	774	10	table	table	NOUN
eurjchem-604	774	11	10	10	NUM
eurjchem-604	774	12	.	.	PUNCT
eurjchem-604	775	1	structure	structure	NOUN
eurjchem-604	775	2	prediction	prediction	NOUN
eurjchem-604	775	3	using	use	VERB
eurjchem-604	775	4	electron	electron	NOUN
eurjchem-604	775	5	count	count	NOUN
eurjchem-604	775	6	.	.	PUNCT
eurjchem-604	776	1	total	total	ADJ
eurjchem-604	776	2	electron	electron	NOUN
eurjchem-604	776	3	count	count	NOUN
eurjchem-604	776	4	predicted	predict	VERB
eurjchem-604	776	5	structure	structure	NOUN
eurjchem-604	776	6	5n	5n	NOUN
eurjchem-604	776	7	n‐vertex	n‐vertex	NOUN
eurjchem-604	776	8	3‐connected	3‐connecte	VERB
eurjchem-604	776	9	polyhedron	polyhedron	NOUN
eurjchem-604	776	10	5n+1	5n+1	PROPN
eurjchem-604	776	11	n‐1	n‐1	PRON
eurjchem-604	776	12	vertex	vertex	NOUN
eurjchem-604	776	13	3‐connected	3‐connecte	VERB
eurjchem-604	776	14	polyhedron	polyhedron	NOUN
eurjchem-604	776	15	with	with	ADP
eurjchem-604	776	16	one	one	NUM
eurjchem-604	776	17	vertex	vertex	NOUN
eurjchem-604	776	18	inserted	insert	VERB
eurjchem-604	776	19	into	into	ADP
eurjchem-604	776	20	an	an	DET
eurjchem-604	776	21	edge	edge	NOUN
eurjchem-604	776	22	5n+2	5n+2	NOUN
eurjchem-604	776	23	n‐2	n‐2	ADJ
eurjchem-604	776	24	vertex	vertex	NOUN
eurjchem-604	776	25	3‐connected	3‐connecte	VERB
eurjchem-604	776	26	polyhedron	polyhedron	NOUN
eurjchem-604	776	27	with	with	ADP
eurjchem-604	776	28	two	two	NUM
eurjchem-604	776	29	vertexes	vertex	NOUN
eurjchem-604	776	30	inserted	insert	VERB
eurjchem-604	776	31	into	into	ADP
eurjchem-604	776	32	edges	edge	NOUN
eurjchem-604	776	33	5n+k	5n+k	NUM
eurjchem-604	776	34	n‐k	n‐k	ADP
eurjchem-604	776	35	vertex	vertex	NOUN
eurjchem-604	776	36	3‐connected	3‐connecte	VERB
eurjchem-604	776	37	polyhedron	polyhedron	NOUN
eurjchem-604	776	38	with	with	ADP
eurjchem-604	776	39	k	k	PROPN
eurjchem-604	776	40	vertexes	vertex	NOUN
eurjchem-604	776	41	inserted	insert	VERB
eurjchem-604	776	42	into	into	ADP
eurjchem-604	776	43	edges	edge	NOUN
eurjchem-604	776	44	5.3.3	5.3.3	NUM
eurjchem-604	776	45	.	.	PUNCT
eurjchem-604	777	1	6n	6n	NOUN
eurjchem-604	777	2	rules	rule	NOUN
eurjchem-604	777	3	as	as	ADP
eurjchem-604	777	4	more	more	ADJ
eurjchem-604	777	5	electrons	electron	NOUN
eurjchem-604	777	6	are	be	AUX
eurjchem-604	777	7	added	add	VERB
eurjchem-604	777	8	to	to	ADP
eurjchem-604	777	9	a	a	DET
eurjchem-604	777	10	5n	5n	NUM
eurjchem-604	777	11	cluster	cluster	NOUN
eurjchem-604	777	12	,	,	PUNCT
eurjchem-604	777	13	the	the	DET
eurjchem-604	777	14	number	number	NOUN
eurjchem-604	777	15	of	of	ADP
eurjchem-604	777	16	electrons	electron	NOUN
eurjchem-604	777	17	per	per	ADP
eurjchem-604	777	18	vertex	vertex	NOUN
eurjchem-604	777	19	approaches	approach	NOUN
eurjchem-604	777	20	6	6	NUM
eurjchem-604	777	21	.	.	PUNCT
eurjchem-604	778	1	instead	instead	ADV
eurjchem-604	778	2	of	of	ADP
eurjchem-604	778	3	adopting	adopt	VERB
eurjchem-604	778	4	structures	structure	NOUN
eurjchem-604	778	5	based	base	VERB
eurjchem-604	778	6	on	on	ADP
eurjchem-604	778	7	4n	4n	NUM
eurjchem-604	778	8	or	or	CCONJ
eurjchem-604	778	9	5n	5n	NUM
eurjchem-604	778	10	rules	rule	NOUN
eurjchem-604	778	11	,	,	PUNCT
eurjchem-604	778	12	the	the	DET
eurjchem-604	778	13	clusters	cluster	NOUN
eurjchem-604	778	14	tend	tend	VERB
eurjchem-604	778	15	to	to	PART
eurjchem-604	778	16	have	have	VERB
eurjchem-604	778	17	structures	structure	NOUN
eurjchem-604	778	18	goverened	goverene	VERB
eurjchem-604	778	19	by	by	ADP
eurjchem-604	778	20	the	the	DET
eurjchem-604	778	21	6n	6n	NOUN
eurjchem-604	778	22	rules	rule	NOUN
eurjchem-604	778	23	,	,	PUNCT
eurjchem-604	778	24	which	which	PRON
eurjchem-604	778	25	are	be	AUX
eurjchem-604	778	26	based	base	VERB
eurjchem-604	778	27	on	on	ADP
eurjchem-604	778	28	rings	ring	NOUN
eurjchem-604	778	29	.	.	PUNCT
eurjchem-604	779	1	the	the	DET
eurjchem-604	779	2	rules	rule	NOUN
eurjchem-604	779	3	for	for	ADP
eurjchem-604	779	4	the	the	DET
eurjchem-604	779	5	6n	6n	NOUN
eurjchem-604	779	6	structures	structure	NOUN
eurjchem-604	779	7	are	be	AUX
eurjchem-604	779	8	given	give	VERB
eurjchem-604	779	9	in	in	ADP
eurjchem-604	779	10	table	table	NOUN
eurjchem-604	779	11	11	11	NUM
eurjchem-604	779	12	.	.	PUNCT
eurjchem-604	779	13	table	table	NOUN
eurjchem-604	779	14	11	11	NUM
eurjchem-604	779	15	.	.	PUNCT
eurjchem-604	780	1	structure	structure	NOUN
eurjchem-604	780	2	prediction	prediction	NOUN
eurjchem-604	780	3	using	use	VERB
eurjchem-604	780	4	electron	electron	NOUN
eurjchem-604	780	5	count	count	NOUN
eurjchem-604	780	6	.	.	PUNCT
eurjchem-604	781	1	total	total	ADJ
eurjchem-604	781	2	electron	electron	NOUN
eurjchem-604	781	3	count	count	NOUN
eurjchem-604	781	4	predicted	predict	VERB
eurjchem-604	781	5	structure	structure	NOUN
eurjchem-604	781	6	6n‐k	6n‐k	ADV
eurjchem-604	781	7	n‐membered	n‐membere	VERB
eurjchem-604	781	8	ring	ring	NOUN
eurjchem-604	781	9	with	with	ADP
eurjchem-604	781	10	k/2	k/2	PROPN
eurjchem-604	781	11	trans‐annular	trans‐annular	ADJ
eurjchem-604	781	12	bonds	bond	NOUN
eurjchem-604	781	13	6n‐4	6n‐4	NUM
eurjchem-604	781	14	n‐membered	n‐membere	VERB
eurjchem-604	781	15	ring	ring	NOUN
eurjchem-604	781	16	with	with	ADP
eurjchem-604	781	17	2	2	NUM
eurjchem-604	781	18	trans‐annular	trans‐annular	ADJ
eurjchem-604	781	19	bonds	bond	NOUN
eurjchem-604	781	20	6n‐2	6n‐2	NUM
eurjchem-604	781	21	n‐membered	n‐membere	VERB
eurjchem-604	781	22	ring	ring	NOUN
eurjchem-604	781	23	with	with	ADP
eurjchem-604	781	24	1	1	NUM
eurjchem-604	781	25	trans‐annular	trans‐annular	ADJ
eurjchem-604	781	26	bond	bond	NOUN
eurjchem-604	781	27	6n	6n	NOUN
eurjchem-604	781	28	n‐membered	n‐membere	VERB
eurjchem-604	781	29	ring	ring	NOUN
eurjchem-604	781	30	6n+2	6n+2	PROPN
eurjchem-604	781	31	n‐membered	n‐membere	VERB
eurjchem-604	781	32	chain	chain	NOUN
eurjchem-604	781	33	(	(	PUNCT
eurjchem-604	781	34	n‐membered	n‐membere	VERB
eurjchem-604	781	35	ring	ring	NOUN
eurjchem-604	781	36	with	with	ADP
eurjchem-604	781	37	1	1	NUM
eurjchem-604	781	38	broken	broken	ADJ
eurjchem-604	781	39	bond	bond	NOUN
eurjchem-604	781	40	)	)	PUNCT
eurjchem-604	781	41	6	6	NUM
eurjchem-604	781	42	.	.	PUNCT
eurjchem-604	782	1	uses	use	NOUN
eurjchem-604	782	2	of	of	ADP
eurjchem-604	782	3	g‐6	g‐6	VERB
eurjchem-604	782	4	metal	metal	NOUN
eurjchem-604	782	5	carbonyl	carbonyl	NOUN
eurjchem-604	782	6	substituted	substitute	VERB
eurjchem-604	782	7	complexes	complex	NOUN
eurjchem-604	782	8	g‐6	g‐6	VERB
eurjchem-604	782	9	metal	metal	NOUN
eurjchem-604	782	10	hexacarbonyls	hexacarbonyls	NOUN
eurjchem-604	782	11	are	be	AUX
eurjchem-604	782	12	widely	widely	ADV
eurjchem-604	782	13	used	use	VERB
eurjchem-604	782	14	in	in	ADP
eurjchem-604	782	15	electron	electron	NOUN
eurjchem-604	782	16	beam‐	beam‐	PROPN
eurjchem-604	782	17	induced	induce	VERB
eurjchem-604	782	18	deposition	deposition	NOUN
eurjchem-604	782	19	technique	technique	NOUN
eurjchem-604	782	20	‐	‐	PUNCT
eurjchem-604	782	21	these	these	PRON
eurjchem-604	782	22	are	be	AUX
eurjchem-604	782	23	easily	easily	ADV
eurjchem-604	782	24	vaporized	vaporize	VERB
eurjchem-604	782	25	and	and	CCONJ
eurjchem-604	782	26	decomposed	decompose	VERB
eurjchem-604	782	27	by	by	ADP
eurjchem-604	782	28	the	the	DET
eurjchem-604	782	29	electron	electron	NOUN
eurjchem-604	782	30	beam	beam	NOUN
eurjchem-604	782	31	providing	provide	VERB
eurjchem-604	782	32	a	a	DET
eurjchem-604	782	33	convenient	convenient	ADJ
eurjchem-604	782	34	source	source	NOUN
eurjchem-604	782	35	of	of	ADP
eurjchem-604	782	36	metal	metal	NOUN
eurjchem-604	782	37	atoms	atom	NOUN
eurjchem-604	782	38	[	[	X
eurjchem-604	782	39	219	219	NUM
eurjchem-604	782	40	]	]	PUNCT
eurjchem-604	782	41	.	.	PUNCT
eurjchem-604	783	1	6.1	6.1	NUM
eurjchem-604	783	2	.	.	PUNCT
eurjchem-604	784	1	as	as	ADP
eurjchem-604	784	2	catalyst	catalyst	NOUN
eurjchem-604	784	3	mo(co)6	mo(co)6	NOUN
eurjchem-604	784	4	,	,	PUNCT
eurjchem-604	785	1	[	[	X
eurjchem-604	785	2	mo(co)3(mecn)3	mo(co)3(mecn)3	NOUN
eurjchem-604	785	3	]	]	X
eurjchem-604	785	4	,	,	PUNCT
eurjchem-604	785	5	and	and	CCONJ
eurjchem-604	785	6	related	related	ADJ
eurjchem-604	785	7	derivatives	derivative	NOUN
eurjchem-604	785	8	are	be	AUX
eurjchem-604	785	9	employed	employ	VERB
eurjchem-604	785	10	as	as	ADP
eurjchem-604	785	11	catalysts	catalyst	NOUN
eurjchem-604	785	12	in	in	ADP
eurjchem-604	785	13	organic	organic	ADJ
eurjchem-604	785	14	synthesis	synthesis	NOUN
eurjchem-604	785	15	.	.	PUNCT
eurjchem-604	786	1	for	for	ADP
eurjchem-604	786	2	example	example	NOUN
eurjchem-604	786	3	,	,	PUNCT
eurjchem-604	786	4	these	these	DET
eurjchem-604	786	5	catalysts	catalyst	NOUN
eurjchem-604	786	6	can	can	AUX
eurjchem-604	786	7	be	be	AUX
eurjchem-604	786	8	used	use	VERB
eurjchem-604	786	9	for	for	ADP
eurjchem-604	786	10	alkyne	alkyne	ADJ
eurjchem-604	786	11	metathesis	metathesis	NOUN
eurjchem-604	786	12	and	and	CCONJ
eurjchem-604	786	13	the	the	DET
eurjchem-604	786	14	pauson‐	pauson‐	ADJ
eurjchem-604	786	15	khand	khand	PROPN
eurjchem-604	786	16	reaction	reaction	NOUN
eurjchem-604	786	17	.	.	PUNCT
eurjchem-604	787	1	6.1.1	6.1.1	X
eurjchem-604	787	2	.	.	PUNCT
eurjchem-604	787	3	metal	metal	NOUN
eurjchem-604	787	4	carbonyl	carbonyl	NOUN
eurjchem-604	787	5	complexes	complex	NOUN
eurjchem-604	787	6	as	as	ADP
eurjchem-604	787	7	catalyst	catalyst	NOUN
eurjchem-604	787	8	most	most	ADJ
eurjchem-604	787	9	of	of	ADP
eurjchem-604	787	10	the	the	DET
eurjchem-604	787	11	existing	exist	VERB
eurjchem-604	787	12	metal	metal	NOUN
eurjchem-604	787	13	carbonyl	carbonyl	NOUN
eurjchem-604	787	14	catalysts	catalyst	NOUN
eurjchem-604	787	15	for	for	ADP
eurjchem-604	787	16	acetylene	acetylene	NOUN
eurjchem-604	787	17	polymerizations	polymerization	NOUN
eurjchem-604	787	18	need	need	VERB
eurjchem-604	787	19	to	to	PART
eurjchem-604	787	20	be	be	AUX
eurjchem-604	787	21	preactivated	preactivate	VERB
eurjchem-604	787	22	by	by	ADP
eurjchem-604	787	23	chlorine‐containing	chlorine‐containe	VERB
eurjchem-604	787	24	additives	additive	NOUN
eurjchem-604	787	25	or	or	CCONJ
eurjchem-604	787	26	by	by	ADP
eurjchem-604	787	27	uv	uv	NOUN
eurjchem-604	787	28	irradiation	irradiation	NOUN
eurjchem-604	787	29	in	in	ADP
eurjchem-604	787	30	halogenated	halogenated	ADJ
eurjchem-604	787	31	solvents	solvent	NOUN
eurjchem-604	787	32	.	.	PUNCT
eurjchem-604	788	1	a	a	DET
eurjchem-604	788	2	series	series	NOUN
eurjchem-604	788	3	of	of	ADP
eurjchem-604	788	4	“	"	PUNCT
eurjchem-604	788	5	simple	simple	ADJ
eurjchem-604	788	6	”	"	PUNCT
eurjchem-604	788	7	metal	metal	NOUN
eurjchem-604	788	8	carbonyl	carbonyl	NOUN
eurjchem-604	788	9	catalysts	catalyst	NOUN
eurjchem-604	788	10	of	of	ADP
eurjchem-604	788	11	general	general	ADJ
eurjchem-604	788	12	structure	structure	NOUN
eurjchem-604	788	13	m(co)xly	m(co)xly	PROPN
eurjchem-604	788	14	(	(	PUNCT
eurjchem-604	788	15	m	m	PROPN
eurjchem-604	788	16	=	=	SYM
eurjchem-604	788	17	mo	mo	PROPN
eurjchem-604	788	18	,	,	PUNCT
eurjchem-604	788	19	w	w	PROPN
eurjchem-604	788	20	;	;	PUNCT
eurjchem-604	788	21	l=	l=	ADJ
eurjchem-604	788	22	bis(trimethylsilyl)ethyne	bis(trimethylsilyl)ethyne	NUM
eurjchem-604	788	23	)	)	PUNCT
eurjchem-604	788	24	were	be	AUX
eurjchem-604	788	25	developed	develop	VERB
eurjchem-604	788	26	,	,	PUNCT
eurjchem-604	788	27	none	none	NOUN
eurjchem-604	788	28	of	of	ADP
eurjchem-604	788	29	which	which	PRON
eurjchem-604	788	30	require	require	VERB
eurjchem-604	788	31	additives	additive	NOUN
eurjchem-604	788	32	or	or	CCONJ
eurjchem-604	788	33	pre‐	pre‐	NOUN
eurjchem-604	788	34	photoirradiation	photoirradiation	NOUN
eurjchem-604	788	35	,	,	PUNCT
eurjchem-604	788	36	most	most	ADJ
eurjchem-604	788	37	of	of	ADP
eurjchem-604	788	38	which	which	PRON
eurjchem-604	788	39	are	be	AUX
eurjchem-604	788	40	air‐	air‐	PUNCT
eurjchem-604	788	41	and	and	CCONJ
eurjchem-604	788	42	moisture‐stable	moisture‐stable	ADJ
eurjchem-604	788	43	,	,	PUNCT
eurjchem-604	788	44	and	and	CCONJ
eurjchem-604	788	45	some	some	PRON
eurjchem-604	788	46	of	of	ADP
eurjchem-604	788	47	which	which	PRON
eurjchem-604	788	48	work	work	VERB
eurjchem-604	788	49	well	well	ADV
eurjchem-604	788	50	in	in	ADP
eurjchem-604	788	51	nonhalogenated	nonhalogenated	ADJ
eurjchem-604	788	52	solvents	solvent	NOUN
eurjchem-604	788	53	[	[	X
eurjchem-604	788	54	220	220	NUM
eurjchem-604	788	55	]	]	PUNCT
eurjchem-604	788	56	.	.	PUNCT
eurjchem-604	789	1	different	different	ADJ
eurjchem-604	789	2	catalyst	catalyst	NOUN
eurjchem-604	789	3	derived	derive	VERB
eurjchem-604	789	4	from	from	ADP
eurjchem-604	789	5	the	the	DET
eurjchem-604	789	6	reaction	reaction	NOUN
eurjchem-604	789	7	of	of	ADP
eurjchem-604	789	8	mo	mo	PROPN
eurjchem-604	789	9	and	and	CCONJ
eurjchem-604	789	10	dimethyl	dimethyl	NOUN
eurjchem-604	789	11	malonate	malonate	NOUN
eurjchem-604	789	12	such	such	ADJ
eurjchem-604	789	13	as	as	ADP
eurjchem-604	789	14	(	(	PUNCT
eurjchem-604	789	15	co)6‐nmo(che2)n	co)6‐nmo(che2)n	PROPN
eurjchem-604	789	16	[	[	X
eurjchem-604	789	17	221	221	NUM
eurjchem-604	789	18	]	]	PUNCT
eurjchem-604	789	19	or	or	CCONJ
eurjchem-604	789	20	(	(	PUNCT
eurjchem-604	789	21	co)5mo(che2	co)5mo(che2	PROPN
eurjchem-604	789	22	)	)	PUNCT
eurjchem-604	790	1	[	[	X
eurjchem-604	790	2	222‐225	222‐225	NUM
eurjchem-604	790	3	]	]	PUNCT
eurjchem-604	790	4	.	.	PUNCT
eurjchem-604	791	1	such	such	ADJ
eurjchem-604	791	2	catalysts	catalyst	NOUN
eurjchem-604	791	3	appear	appear	VERB
eurjchem-604	791	4	to	to	PART
eurjchem-604	791	5	be	be	AUX
eurjchem-604	791	6	of	of	ADP
eurjchem-604	791	7	insufficient	insufficient	ADJ
eurjchem-604	791	8	reactivity	reactivity	NOUN
eurjchem-604	791	9	to	to	PART
eurjchem-604	791	10	initiate	initiate	VERB
eurjchem-604	791	11	ionization	ionization	NOUN
eurjchem-604	791	12	.	.	PUNCT
eurjchem-604	792	1	however	however	ADV
eurjchem-604	792	2	,	,	PUNCT
eurjchem-604	792	3	with	with	ADP
eurjchem-604	792	4	the	the	DET
eurjchem-604	792	5	more	more	ADV
eurjchem-604	792	6	reactive	reactive	ADJ
eurjchem-604	792	7	substrates	substrate	NOUN
eurjchem-604	792	8	,	,	PUNCT
eurjchem-604	792	9	reaction	reaction	NOUN
eurjchem-604	792	10	proceeds	proceed	VERB
eurjchem-604	792	11	normally	normally	ADV
eurjchem-604	792	12	[	[	X
eurjchem-604	792	13	226	226	NUM
eurjchem-604	792	14	]	]	PUNCT
eurjchem-604	792	15	.	.	PUNCT
eurjchem-604	793	1	allylic	allylic	ADJ
eurjchem-604	793	2	alkylation	alkylation	NOUN
eurjchem-604	793	3	catalyzed	catalyze	VERB
eurjchem-604	793	4	by	by	ADP
eurjchem-604	793	5	molybdenum	molybdenum	NOUN
eurjchem-604	793	6	complexes	complex	NOUN
eurjchem-604	793	7	like	like	ADP
eurjchem-604	793	8	mo(bpy)(co)4	mo(bpy)(co)4	PROPN
eurjchem-604	794	1	[	[	X
eurjchem-604	794	2	227,228	227,228	NUM
eurjchem-604	794	3	]	]	PUNCT
eurjchem-604	794	4	,	,	PUNCT
eurjchem-604	794	5	forms	form	VERB
eurjchem-604	794	6	a	a	DET
eurjchem-604	794	7	useful	useful	ADJ
eurjchem-604	794	8	and	and	CCONJ
eurjchem-604	794	9	frequently	frequently	ADV
eurjchem-604	794	10	complementary	complementary	ADJ
eurjchem-604	794	11	alternative	alternative	NOUN
eurjchem-604	794	12	to	to	ADP
eurjchem-604	794	13	the	the	DET
eurjchem-604	794	14	palladium‐catalyzed	palladium‐catalyze	VERB
eurjchem-604	794	15	reactions	reaction	NOUN
eurjchem-604	794	16	.	.	PUNCT
eurjchem-604	795	1	higher	high	ADJ
eurjchem-604	795	2	selectivity	selectivity	NOUN
eurjchem-604	795	3	for	for	ADP
eurjchem-604	795	4	attack	attack	NOUN
eurjchem-604	795	5	at	at	ADP
eurjchem-604	795	6	primary	primary	ADJ
eurjchem-604	795	7	vs.	vs.	X
eurjchem-604	795	8	secondary	secondary	ADJ
eurjchem-604	795	9	carbon	carbon	NOUN
eurjchem-604	795	10	of	of	ADP
eurjchem-604	795	11	a	a	DET
eurjchem-604	795	12	π‐allyl	π‐allyl	PUNCT
eurjchem-604	795	13	fragment	fragment	NOUN
eurjchem-604	795	14	occurs	occur	VERB
eurjchem-604	795	15	with	with	ADP
eurjchem-604	795	16	molybdenum	molybdenum	NOUN
eurjchem-604	795	17	catalyst	catalyst	NOUN
eurjchem-604	795	18	.	.	PUNCT
eurjchem-604	796	1	the	the	DET
eurjchem-604	796	2	synthesis	synthesis	NOUN
eurjchem-604	796	3	of	of	ADP
eurjchem-604	796	4	the	the	DET
eurjchem-604	796	5	dioxo‐molybdenum(vi	dioxo‐molybdenum(vi	NOUN
eurjchem-604	796	6	)	)	PUNCT
eurjchem-604	796	7	and	and	CCONJ
eurjchem-604	796	8	‐tungsten(vi	‐tungsten(vi	NUM
eurjchem-604	796	9	)	)	PUNCT
eurjchem-604	796	10	derivatives	derivative	NOUN
eurjchem-604	796	11	mo2(s‐binol)(thf)n	mo2(s‐binol)(thf)n	PROPN
eurjchem-604	796	12	and	and	CCONJ
eurjchem-604	796	13	mo2	mo2	NOUN
eurjchem-604	797	1	[	[	X
eurjchem-604	797	2	ocme(cf3)2]2(thf	ocme(cf3)2]2(thf	X
eurjchem-604	797	3	)	)	PUNCT
eurjchem-604	797	4	(	(	PUNCT
eurjchem-604	797	5	m	m	PROPN
eurjchem-604	797	6	=	=	SYM
eurjchem-604	797	7	mo	mo	PROPN
eurjchem-604	797	8	,	,	PUNCT
eurjchem-604	797	9	n	n	NOUN
eurjchem-604	797	10	=	=	SYM
eurjchem-604	797	11	2	2	NUM
eurjchem-604	797	12	;	;	PUNCT
eurjchem-604	797	13	w	w	NOUN
eurjchem-604	797	14	,	,	PUNCT
eurjchem-604	797	15	n	n	NOUN
eurjchem-604	797	16	=	=	SYM
eurjchem-604	797	17	1	1	X
eurjchem-604	797	18	)	)	PUNCT
eurjchem-604	797	19	is	be	AUX
eurjchem-604	797	20	reported	report	VERB
eurjchem-604	797	21	(	(	PUNCT
eurjchem-604	797	22	scheme	scheme	NOUN
eurjchem-604	797	23	58	58	NUM
eurjchem-604	797	24	)	)	PUNCT
eurjchem-604	797	25	.	.	PUNCT
eurjchem-604	798	1	andré	andré	PROPN
eurjchem-604	798	2	pontes	pontes	PROPN
eurjchem-604	798	3	et	et	PROPN
eurjchem-604	798	4	al	al	PROPN
eurjchem-604	798	5	.	.	PROPN
eurjchem-604	798	6	have	have	AUX
eurjchem-604	798	7	examined	examine	VERB
eurjchem-604	798	8	the	the	DET
eurjchem-604	798	9	potential	potential	NOUN
eurjchem-604	798	10	of	of	ADP
eurjchem-604	798	11	these	these	DET
eurjchem-604	798	12	complexes	complex	NOUN
eurjchem-604	798	13	as	as	ADP
eurjchem-604	798	14	catalysts	catalyst	NOUN
eurjchem-604	798	15	for	for	ADP
eurjchem-604	798	16	the	the	DET
eurjchem-604	798	17	sulfoxidation	sulfoxidation	NOUN
eurjchem-604	798	18	of	of	ADP
eurjchem-604	798	19	methyl	methyl	NOUN
eurjchem-604	798	20	phenyl	phenyl	NOUN
eurjchem-604	798	21	sulfide	sulfide	NOUN
eurjchem-604	798	22	,	,	PUNCT
eurjchem-604	798	23	olefin	olefin	NOUN
eurjchem-604	798	24	epoxidation	epoxidation	NOUN
eurjchem-604	798	25	and	and	CCONJ
eurjchem-604	798	26	hydrosilylation	hydrosilylation	NOUN
eurjchem-604	798	27	of	of	ADP
eurjchem-604	798	28	carbonyl	carbonyl	NOUN
eurjchem-604	798	29	groups	group	NOUN
eurjchem-604	798	30	[	[	X
eurjchem-604	798	31	229	229	NUM
eurjchem-604	798	32	]	]	PUNCT
eurjchem-604	798	33	.	.	PUNCT
eurjchem-604	799	1	scheme	scheme	VERB
eurjchem-604	799	2	58	58	NUM
eurjchem-604	799	3	alkene	alkene	NOUN
eurjchem-604	799	4	carbonyl	carbonyl	NOUN
eurjchem-604	799	5	complexes	complex	NOUN
eurjchem-604	799	6	of	of	ADP
eurjchem-604	799	7	the	the	DET
eurjchem-604	799	8	type	type	NOUN
eurjchem-604	799	9	:	:	PUNCT
eurjchem-604	799	10	[	[	X
eurjchem-604	799	11	m(co)5(η2‐	m(co)5(η2‐	ADJ
eurjchem-604	799	12	alkene	alkene	NOUN
eurjchem-604	799	13	)	)	PUNCT
eurjchem-604	799	14	]	]	PUNCT
eurjchem-604	799	15	,	,	PUNCT
eurjchem-604	799	16	[	[	X
eurjchem-604	799	17	m(co)4(η2‐alkene)2	m(co)4(η2‐alkene)2	X
eurjchem-604	799	18	]	]	X
eurjchem-604	799	19	,	,	PUNCT
eurjchem-604	799	20	and	and	CCONJ
eurjchem-604	799	21	[	[	X
eurjchem-604	799	22	m(co)3(η2‐alkene)3	m(co)3(η2‐alkene)3	X
eurjchem-604	799	23	]	]	X
eurjchem-604	799	24	have	have	AUX
eurjchem-604	799	25	been	be	AUX
eurjchem-604	799	26	prepared	prepare	VERB
eurjchem-604	799	27	by	by	ADP
eurjchem-604	799	28	photochemical	photochemical	ADJ
eurjchem-604	799	29	reactions	reaction	NOUN
eurjchem-604	799	30	of	of	ADP
eurjchem-604	799	31	group	group	NOUN
eurjchem-604	799	32	6	6	NUM
eurjchem-604	799	33	transition	transition	NOUN
eurjchem-604	799	34	metal	metal	NOUN
eurjchem-604	799	35	carbonyls	carbonyls	NOUN
eurjchem-604	799	36	with	with	ADP
eurjchem-604	799	37	alkenes	alkene	NOUN
eurjchem-604	799	38	.	.	PUNCT
eurjchem-604	800	1	these	these	DET
eurjchem-604	800	2	complexes	complex	NOUN
eurjchem-604	800	3	were	be	AUX
eurjchem-604	800	4	found	find	VERB
eurjchem-604	800	5	to	to	PART
eurjchem-604	800	6	exhibit	exhibit	VERB
eurjchem-604	800	7	some	some	DET
eurjchem-604	800	8	catalytic	catalytic	ADJ
eurjchem-604	800	9	activity	activity	NOUN
eurjchem-604	800	10	.	.	PUNCT
eurjchem-604	801	1	these	these	DET
eurjchem-604	801	2	complexes	complex	NOUN
eurjchem-604	801	3	catalyze	catalyze	NOUN
eurjchem-604	801	4	to	to	ADP
eurjchem-604	801	5	reactions	reaction	NOUN
eurjchem-604	801	6	that	that	PRON
eurjchem-604	801	7	lead	lead	VERB
eurjchem-604	801	8	to	to	ADP
eurjchem-604	801	9	the	the	DET
eurjchem-604	801	10	formation	formation	NOUN
eurjchem-604	801	11	of	of	ADP
eurjchem-604	801	12	new	new	ADJ
eurjchem-604	801	13	carbon‐	carbon‐	NOUN
eurjchem-604	801	14	carbon	carbon	NOUN
eurjchem-604	801	15	bonds	bond	NOUN
eurjchem-604	801	16	,	,	PUNCT
eurjchem-604	801	17	such	such	ADJ
eurjchem-604	801	18	as	as	ADP
eurjchem-604	801	19	metathesis	metathesis	NOUN
eurjchem-604	801	20	,	,	PUNCT
eurjchem-604	801	21	ring‐opening	ring‐opene	VERB
eurjchem-604	801	22	metathesis	metathesis	NOUN
eurjchem-604	801	23	polymerization	polymerization	NOUN
eurjchem-604	801	24	of	of	ADP
eurjchem-604	801	25	cyclic	cyclic	ADJ
eurjchem-604	801	26	olefins	olefin	NOUN
eurjchem-604	801	27	(	(	PUNCT
eurjchem-604	801	28	romp	romp	PROPN
eurjchem-604	801	29	)	)	PUNCT
eurjchem-604	801	30	,	,	PUNCT
eurjchem-604	801	31	and	and	CCONJ
eurjchem-604	801	32	the	the	DET
eurjchem-604	801	33	addition	addition	NOUN
eurjchem-604	801	34	of	of	ADP
eurjchem-604	801	35	haloalkanes	haloalkane	NOUN
eurjchem-604	801	36	to	to	ADP
eurjchem-604	801	37	the	the	DET
eurjchem-604	801	38	double	double	ADJ
eurjchem-604	801	39	bond	bond	NOUN
eurjchem-604	801	40	of	of	ADP
eurjchem-604	801	41	olefin	olefin	NOUN
eurjchem-604	801	42	[	[	X
eurjchem-604	801	43	230	230	NUM
eurjchem-604	801	44	]	]	PUNCT
eurjchem-604	801	45	.	.	PUNCT
eurjchem-604	802	1	the	the	DET
eurjchem-604	802	2	thiacrowns	thiacrown	NOUN
eurjchem-604	802	3	retracted	retract	VERB
eurjchem-604	802	4	386	386	NUM
eurjchem-604	802	5	kaushik	kaushik	PROPN
eurjchem-604	802	6	et	et	PROPN
eurjchem-604	802	7	al	al	PROPN
eurjchem-604	802	8	.	.	PUNCT
eurjchem-604	802	9	/	/	SYM
eurjchem-604	802	10	european	european	PROPN
eurjchem-604	802	11	journal	journal	PROPN
eurjchem-604	802	12	of	of	ADP
eurjchem-604	802	13	chemistry	chemistry	NOUN
eurjchem-604	802	14	3	3	NUM
eurjchem-604	802	15	(	(	PUNCT
eurjchem-604	802	16	3	3	NUM
eurjchem-604	802	17	)	)	PUNCT
eurjchem-604	802	18	(	(	PUNCT
eurjchem-604	802	19	2012	2012	NUM
eurjchem-604	802	20	)	)	PUNCT
eurjchem-604	802	21	367‐394	367‐394	NOUN
eurjchem-604	802	22	were	be	AUX
eurjchem-604	802	23	synthesized	synthesize	VERB
eurjchem-604	802	24	by	by	ADP
eurjchem-604	802	25	the	the	DET
eurjchem-604	802	26	catalytic	catalytic	ADJ
eurjchem-604	802	27	ring	ring	NOUN
eurjchem-604	802	28	opening	opening	NOUN
eurjchem-604	802	29	cyclooligomerization	cyclooligomerization	NOUN
eurjchem-604	802	30	of	of	ADP
eurjchem-604	802	31	thiirane	thiirane	NOUN
eurjchem-604	802	32	using	use	VERB
eurjchem-604	802	33	some	some	DET
eurjchem-604	802	34	group	group	NOUN
eurjchem-604	802	35	vi	vi	NOUN
eurjchem-604	802	36	metal	metal	NOUN
eurjchem-604	802	37	carbonyl	carbonyl	NOUN
eurjchem-604	802	38	complexes	complex	NOUN
eurjchem-604	802	39	as	as	ADP
eurjchem-604	802	40	catalyst	catalyst	NOUN
eurjchem-604	802	41	.	.	PUNCT
eurjchem-604	803	1	the	the	DET
eurjchem-604	803	2	group	group	NOUN
eurjchem-604	803	3	vi	vi	PROPN
eurjchem-604	803	4	catalyst	catalyst	NOUN
eurjchem-604	803	5	precursors	precursor	NOUN
eurjchem-604	803	6	were	be	AUX
eurjchem-604	803	7	transition	transition	NOUN
eurjchem-604	803	8	metal	metal	NOUN
eurjchem-604	803	9	complexes	complex	NOUN
eurjchem-604	803	10	of	of	ADP
eurjchem-604	803	11	the	the	DET
eurjchem-604	803	12	form	form	NOUN
eurjchem-604	803	13	m(ncch3)(pr3)x(co)5−x	m(ncch3)(pr3)x(co)5−x	PROPN
eurjchem-604	803	14	(	(	PUNCT
eurjchem-604	803	15	x=0	x=0	PROPN
eurjchem-604	803	16	,	,	PUNCT
eurjchem-604	803	17	m	m	NOUN
eurjchem-604	803	18	=	=	NOUN
eurjchem-604	803	19	cr	cr	PROPN
eurjchem-604	803	20	,	,	PUNCT
eurjchem-604	803	21	mo	mo	PROPN
eurjchem-604	803	22	and	and	CCONJ
eurjchem-604	803	23	w	w	PROPN
eurjchem-604	803	24	;	;	PUNCT
eurjchem-604	803	25	x=1	x=1	PROPN
eurjchem-604	803	26	,	,	PUNCT
eurjchem-604	803	27	m	m	PROPN
eurjchem-604	803	28	=	=	NOUN
eurjchem-604	803	29	cr	cr	PROPN
eurjchem-604	803	30	,	,	PUNCT
eurjchem-604	803	31	r	r	NOUN
eurjchem-604	803	32	=	=	SYM
eurjchem-604	803	33	ph	ph	ADJ
eurjchem-604	803	34	;	;	PUNCT
eurjchem-604	803	35	m	m	VERB
eurjchem-604	803	36	=	=	NOUN
eurjchem-604	803	37	w	w	PROPN
eurjchem-604	803	38	,	,	PUNCT
eurjchem-604	803	39	r	r	NOUN
eurjchem-604	803	40	=	=	SYM
eurjchem-604	803	41	ph	ph	ADJ
eurjchem-604	803	42	,	,	PUNCT
eurjchem-604	803	43	or	or	CCONJ
eurjchem-604	803	44	oc6h4‐p‐me	oc6h4‐p‐me	ADJ
eurjchem-604	803	45	)	)	PUNCT
eurjchem-604	803	46	.	.	PUNCT
eurjchem-604	804	1	the	the	DET
eurjchem-604	804	2	yields	yield	NOUN
eurjchem-604	804	3	of	of	ADP
eurjchem-604	804	4	the	the	DET
eurjchem-604	804	5	thiacrowns	thiacrown	NOUN
eurjchem-604	804	6	were	be	AUX
eurjchem-604	804	7	significantly	significantly	ADV
eurjchem-604	804	8	improved	improve	VERB
eurjchem-604	804	9	by	by	ADP
eurjchem-604	804	10	the	the	DET
eurjchem-604	804	11	addition	addition	NOUN
eurjchem-604	804	12	of	of	ADP
eurjchem-604	804	13	dialkyl	dialkyl	PROPN
eurjchem-604	804	14	acetylenedicarboxylates	acetylenedicarboxylate	NOUN
eurjchem-604	804	15	to	to	ADP
eurjchem-604	804	16	the	the	DET
eurjchem-604	804	17	reactions	reaction	NOUN
eurjchem-604	804	18	catalyzed	catalyze	VERB
eurjchem-604	804	19	by	by	ADP
eurjchem-604	804	20	the	the	DET
eurjchem-604	804	21	group	group	NOUN
eurjchem-604	804	22	vi	vi	NOUN
eurjchem-604	804	23	complexes	complex	NOUN
eurjchem-604	804	24	(	(	PUNCT
eurjchem-604	804	25	scheme	scheme	NOUN
eurjchem-604	804	26	59	59	NUM
eurjchem-604	804	27	)	)	PUNCT
eurjchem-604	805	1	[	[	X
eurjchem-604	805	2	231	231	NUM
eurjchem-604	805	3	]	]	PUNCT
eurjchem-604	805	4	.	.	PUNCT
eurjchem-604	806	1	scheme	scheme	NOUN
eurjchem-604	806	2	59	59	NUM
eurjchem-604	806	3	the	the	DET
eurjchem-604	806	4	catalytic	catalytic	ADJ
eurjchem-604	806	5	activities	activity	NOUN
eurjchem-604	806	6	of	of	ADP
eurjchem-604	806	7	the	the	DET
eurjchem-604	806	8	complexes	complex	NOUN
eurjchem-604	806	9	,	,	PUNCT
eurjchem-604	806	10	cp′m(co)3x	cp′m(co)3x	VERB
eurjchem-604	806	11	(	(	PUNCT
eurjchem-604	806	12	cp′	cp′	VERB
eurjchem-604	806	13	=	=	SYM
eurjchem-604	806	14	cp	cp	INTJ
eurjchem-604	806	15	(	(	PUNCT
eurjchem-604	806	16	η5‐c5h5	η5‐c5h5	PROPN
eurjchem-604	806	17	)	)	PUNCT
eurjchem-604	806	18	,	,	PUNCT
eurjchem-604	806	19	cp	cp	X
eurjchem-604	806	20	*	*	PUNCT
eurjchem-604	806	21	(	(	PUNCT
eurjchem-604	806	22	η5‐c5me5	η5‐c5me5	NOUN
eurjchem-604	806	23	)	)	PUNCT
eurjchem-604	806	24	;	;	PUNCT
eurjchem-604	806	25	m	m	PROPN
eurjchem-604	806	26	=	=	SYM
eurjchem-604	806	27	mo	mo	PROPN
eurjchem-604	806	28	,	,	PUNCT
eurjchem-604	806	29	w	w	PROPN
eurjchem-604	806	30	;	;	PUNCT
eurjchem-604	806	31	x	x	SYM
eurjchem-604	806	32	=	=	PUNCT
eurjchem-604	806	33	cl	cl	NOUN
eurjchem-604	806	34	,	,	PUNCT
eurjchem-604	806	35	ch3	ch3	PROPN
eurjchem-604	806	36	)	)	PUNCT
eurjchem-604	806	37	and	and	CCONJ
eurjchem-604	806	38	mo(co)6	mo(co)6	NOUN
eurjchem-604	806	39	have	have	AUX
eurjchem-604	806	40	been	be	AUX
eurjchem-604	806	41	examined	examine	VERB
eurjchem-604	806	42	for	for	ADP
eurjchem-604	806	43	the	the	DET
eurjchem-604	806	44	oxidation	oxidation	NOUN
eurjchem-604	806	45	of	of	ADP
eurjchem-604	806	46	phenol	phenol	NOUN
eurjchem-604	806	47	(	(	PUNCT
eurjchem-604	806	48	37	37	NUM
eurjchem-604	806	49	.	.	NOUN
eurjchem-604	806	50	6	6	NUM
eurjchem-604	806	51	g	g	NOUN
eurjchem-604	806	52	/	/	SYM
eurjchem-604	806	53	l	l	NOUN
eurjchem-604	806	54	)	)	PUNCT
eurjchem-604	806	55	using	use	VERB
eurjchem-604	806	56	h2o2	h2o2	NOUN
eurjchem-604	806	57	as	as	ADP
eurjchem-604	806	58	oxidant	oxidant	NOUN
eurjchem-604	806	59	in	in	ADP
eurjchem-604	806	60	aqueous	aqueous	ADJ
eurjchem-604	806	61	solution	solution	NOUN
eurjchem-604	806	62	(	(	PUNCT
eurjchem-604	806	63	scheme	scheme	NOUN
eurjchem-604	806	64	60	60	NUM
eurjchem-604	806	65	)	)	PUNCT
eurjchem-604	806	66	.	.	PUNCT
eurjchem-604	807	1	among	among	ADP
eurjchem-604	807	2	them	they	PRON
eurjchem-604	807	3	,	,	PUNCT
eurjchem-604	807	4	cpmo(co)3cl	cpmo(co)3cl	PROPN
eurjchem-604	807	5	and	and	CCONJ
eurjchem-604	807	6	cpmo(co)3(ch3	cpmo(co)3(ch3	PROPN
eurjchem-604	807	7	)	)	PUNCT
eurjchem-604	807	8	showed	show	VERB
eurjchem-604	807	9	the	the	DET
eurjchem-604	807	10	highest	high	ADJ
eurjchem-604	807	11	catalytic	catalytic	ADJ
eurjchem-604	807	12	activity	activity	NOUN
eurjchem-604	807	13	[	[	X
eurjchem-604	807	14	232	232	NUM
eurjchem-604	807	15	]	]	PUNCT
eurjchem-604	807	16	.	.	PUNCT
eurjchem-604	808	1	scheme	scheme	NOUN
eurjchem-604	808	2	60	60	NUM
eurjchem-604	808	3	6.1.2	6.1.2	NUM
eurjchem-604	808	4	.	.	PUNCT
eurjchem-604	809	1	metal	metal	NOUN
eurjchem-604	809	2	carbonyl	carbonyl	NOUN
eurjchem-604	809	3	cations	cation	NOUN
eurjchem-604	809	4	as	as	ADP
eurjchem-604	809	5	catalyst	catalyst	NOUN
eurjchem-604	809	6	cationic	cationic	ADJ
eurjchem-604	809	7	metal	metal	NOUN
eurjchem-604	809	8	carbonyls	carbonyls	NOUN
eurjchem-604	809	9	[	[	X
eurjchem-604	809	10	m(co)m]n+	m(co)m]n+	PROPN
eurjchem-604	809	11	,	,	PUNCT
eurjchem-604	809	12	which	which	PRON
eurjchem-604	809	13	have	have	VERB
eurjchem-604	809	14	a	a	DET
eurjchem-604	809	15	positive	positive	ADJ
eurjchem-604	809	16	metal	metal	NOUN
eurjchem-604	809	17	charge	charge	NOUN
eurjchem-604	809	18	,	,	PUNCT
eurjchem-604	809	19	were	be	AUX
eurjchem-604	809	20	prepared	prepare	VERB
eurjchem-604	809	21	from	from	ADP
eurjchem-604	809	22	cr	cr	PROPN
eurjchem-604	809	23	,	,	PUNCT
eurjchem-604	809	24	ag	ag	PROPN
eurjchem-604	809	25	,	,	PUNCT
eurjchem-604	809	26	au	au	PROPN
eurjchem-604	809	27	,	,	PUNCT
eurjchem-604	809	28	pd	pd	PROPN
eurjchem-604	809	29	,	,	PUNCT
eurjchem-604	809	30	pt	pt	PROPN
eurjchem-604	809	31	,	,	PUNCT
eurjchem-604	809	32	rh	rh	PROPN
eurjchem-604	809	33	and	and	CCONJ
eurjchem-604	809	34	ir	ir	PROPN
eurjchem-604	809	35	.	.	PUNCT
eurjchem-604	810	1	the	the	DET
eurjchem-604	810	2	m‐c	m‐c	PROPN
eurjchem-604	810	3	bonds	bond	NOUN
eurjchem-604	810	4	of	of	ADP
eurjchem-604	810	5	these	these	DET
eurjchem-604	810	6	compounds	compound	NOUN
eurjchem-604	810	7	were	be	AUX
eurjchem-604	810	8	mainly	mainly	ADV
eurjchem-604	810	9	formed	form	VERB
eurjchem-604	810	10	by	by	ADP
eurjchem-604	810	11	the	the	DET
eurjchem-604	810	12	σ‐dative	σ‐dative	PROPN
eurjchem-604	810	13	bond	bond	NOUN
eurjchem-604	810	14	of	of	ADP
eurjchem-604	810	15	co	co	NOUN
eurjchem-604	810	16	,	,	PUNCT
eurjchem-604	810	17	and	and	CCONJ
eurjchem-604	810	18	then	then	ADV
eurjchem-604	810	19	the	the	DET
eurjchem-604	810	20	ν	ν	PROPN
eurjchem-604	810	21	co	co	NOUN
eurjchem-604	810	22	values	value	NOUN
eurjchem-604	810	23	were	be	AUX
eurjchem-604	810	24	observed	observe	VERB
eurjchem-604	810	25	at	at	ADP
eurjchem-604	810	26	a	a	DET
eurjchem-604	810	27	higher	high	ADJ
eurjchem-604	810	28	wavenumber	wavenumber	NOUN
eurjchem-604	810	29	than	than	ADP
eurjchem-604	810	30	the	the	DET
eurjchem-604	810	31	free	free	PROPN
eurjchem-604	810	32	co.	co.	PROPN
eurjchem-604	810	33	these	these	DET
eurjchem-604	810	34	unstable	unstable	ADJ
eurjchem-604	810	35	cationic	cationic	ADJ
eurjchem-604	810	36	metal	metal	NOUN
eurjchem-604	810	37	carbonyls	carbonyls	NOUN
eurjchem-604	810	38	were	be	AUX
eurjchem-604	810	39	used	use	VERB
eurjchem-604	810	40	as	as	ADP
eurjchem-604	810	41	catalysts	catalyst	NOUN
eurjchem-604	810	42	for	for	ADP
eurjchem-604	810	43	the	the	DET
eurjchem-604	810	44	carbonylation	carbonylation	NOUN
eurjchem-604	810	45	of	of	ADP
eurjchem-604	810	46	olefins	olefin	NOUN
eurjchem-604	810	47	,	,	PUNCT
eurjchem-604	810	48	alcohols	alcohol	NOUN
eurjchem-604	810	49	,	,	PUNCT
eurjchem-604	810	50	dienes	diene	NOUN
eurjchem-604	810	51	,	,	PUNCT
eurjchem-604	810	52	aldehydes	aldehyde	NOUN
eurjchem-604	810	53	and	and	CCONJ
eurjchem-604	810	54	saturated	saturate	VERB
eurjchem-604	810	55	hydrocarbons	hydrocarbon	NOUN
eurjchem-604	810	56	to	to	PART
eurjchem-604	810	57	give	give	VERB
eurjchem-604	810	58	tert‐carboxylic	tert‐carboxylic	ADJ
eurjchem-604	810	59	acids	acid	NOUN
eurjchem-604	810	60	in	in	ADP
eurjchem-604	810	61	high	high	ADJ
eurjchem-604	810	62	yields	yield	NOUN
eurjchem-604	810	63	at	at	ADP
eurjchem-604	810	64	room	room	NOUN
eurjchem-604	810	65	temperature	temperature	NOUN
eurjchem-604	810	66	and	and	CCONJ
eurjchem-604	810	67	atmospheric	atmospheric	ADJ
eurjchem-604	810	68	co	co	NOUN
eurjchem-604	810	69	pressure	pressure	NOUN
eurjchem-604	810	70	[	[	X
eurjchem-604	810	71	233	233	NUM
eurjchem-604	810	72	]	]	PUNCT
eurjchem-604	810	73	.	.	PUNCT
eurjchem-604	811	1	there	there	PRON
eurjchem-604	811	2	has	have	AUX
eurjchem-604	811	3	been	be	AUX
eurjchem-604	811	4	a	a	DET
eurjchem-604	811	5	rapid	rapid	ADJ
eurjchem-604	811	6	development	development	NOUN
eurjchem-604	811	7	in	in	ADP
eurjchem-604	811	8	the	the	DET
eurjchem-604	811	9	study	study	NOUN
eurjchem-604	811	10	of	of	ADP
eurjchem-604	811	11	metal	metal	NOUN
eurjchem-604	811	12	carbonyl	carbonyl	NOUN
eurjchem-604	811	13	cations	cation	NOUN
eurjchem-604	811	14	,	,	PUNCT
eurjchem-604	811	15	which	which	PRON
eurjchem-604	811	16	exhibit	exhibit	VERB
eurjchem-604	811	17	distinguishing	distinguish	VERB
eurjchem-604	811	18	characteristics	characteristic	NOUN
eurjchem-604	811	19	in	in	ADP
eurjchem-604	811	20	comparison	comparison	NOUN
eurjchem-604	811	21	with	with	ADP
eurjchem-604	811	22	typical	typical	ADJ
eurjchem-604	811	23	metal	metal	NOUN
eurjchem-604	811	24	carbonyl	carbonyl	NOUN
eurjchem-604	811	25	complexes	complex	NOUN
eurjchem-604	811	26	.	.	PUNCT
eurjchem-604	812	1	qiang	qiang	PROPN
eurjchem-604	812	2	xu	xu	PROPN
eurjchem-604	812	3	gives	give	VERB
eurjchem-604	812	4	an	an	DET
eurjchem-604	812	5	overview	overview	NOUN
eurjchem-604	812	6	of	of	ADP
eurjchem-604	812	7	the	the	DET
eurjchem-604	812	8	catalytic	catalytic	ADJ
eurjchem-604	812	9	application	application	NOUN
eurjchem-604	812	10	of	of	ADP
eurjchem-604	812	11	metal	metal	NOUN
eurjchem-604	812	12	carbonyl	carbonyl	NOUN
eurjchem-604	812	13	cations	cation	NOUN
eurjchem-604	812	14	,	,	PUNCT
eurjchem-604	812	15	including	include	VERB
eurjchem-604	812	16	the	the	DET
eurjchem-604	812	17	metal	metal	NOUN
eurjchem-604	812	18	carbonyl	carbonyl	NOUN
eurjchem-604	812	19	cluster	cluster	NOUN
eurjchem-604	812	20	cations	cation	NOUN
eurjchem-604	812	21	[	[	X
eurjchem-604	812	22	234	234	NUM
eurjchem-604	812	23	]	]	PUNCT
eurjchem-604	812	24	.	.	PUNCT
eurjchem-604	813	1	6.1.3	6.1.3	NUM
eurjchem-604	813	2	.	.	PUNCT
eurjchem-604	813	3	metal	metal	NOUN
eurjchem-604	813	4	carbonyl	carbonyl	NOUN
eurjchem-604	813	5	clusters	cluster	NOUN
eurjchem-604	813	6	as	as	ADP
eurjchem-604	813	7	catalyst	catalyst	NOUN
eurjchem-604	813	8	catalytic	catalytic	ADJ
eurjchem-604	813	9	activity	activity	NOUN
eurjchem-604	813	10	of	of	ADP
eurjchem-604	813	11	transition	transition	NOUN
eurjchem-604	813	12	metalcarbonyl	metalcarbonyl	NOUN
eurjchem-604	813	13	clusters	cluster	NOUN
eurjchem-604	813	14	substituted	substitute	VERB
eurjchem-604	813	15	with	with	ADP
eurjchem-604	813	16	benzyne	benzyne	PROPN
eurjchem-604	813	17	(	(	PUNCT
eurjchem-604	813	18	and	and	CCONJ
eurjchem-604	813	19	,	,	PUNCT
eurjchem-604	813	20	for	for	ADP
eurjchem-604	813	21	comparison	comparison	NOUN
eurjchem-604	813	22	,	,	PUNCT
eurjchem-604	813	23	benzene	benzene	NOUN
eurjchem-604	813	24	and	and	CCONJ
eurjchem-604	813	25	diene	diene	ADJ
eurjchem-604	813	26	)	)	PUNCT
eurjchem-604	813	27	ligands	ligand	NOUN
eurjchem-604	813	28	was	be	AUX
eurjchem-604	813	29	given	give	VERB
eurjchem-604	813	30	by	by	ADP
eurjchem-604	813	31	sabrina	sabrina	PROPN
eurjchem-604	813	32	brait	brait	PROPN
eurjchem-604	813	33	et	et	PROPN
eurjchem-604	813	34	al	al	PROPN
eurjchem-604	813	35	.	.	PROPN
eurjchem-604	813	36	cluster‐surface	cluster‐surface	NOUN
eurjchem-604	813	37	analogies	analogy	NOUN
eurjchem-604	813	38	are	be	AUX
eurjchem-604	813	39	helpful	helpful	ADJ
eurjchem-604	813	40	in	in	ADP
eurjchem-604	813	41	gaining	gain	VERB
eurjchem-604	813	42	an	an	DET
eurjchem-604	813	43	understanding	understanding	NOUN
eurjchem-604	813	44	of	of	ADP
eurjchem-604	813	45	the	the	DET
eurjchem-604	813	46	homogeneous	homogeneous	ADJ
eurjchem-604	813	47	and	and	CCONJ
eurjchem-604	813	48	heterogeneous	heterogeneous	ADJ
eurjchem-604	813	49	catalytic	catalytic	ADJ
eurjchem-604	813	50	behaviour	behaviour	NOUN
eurjchem-604	813	51	of	of	ADP
eurjchem-604	813	52	the	the	DET
eurjchem-604	813	53	clusters	cluster	NOUN
eurjchem-604	813	54	[	[	X
eurjchem-604	813	55	235	235	NUM
eurjchem-604	813	56	]	]	PUNCT
eurjchem-604	813	57	.	.	PUNCT
eurjchem-604	814	1	molybdenum	molybdenum	PROPN
eurjchem-604	814	2	hexacarbonyl	hexacarbonyl	PROPN
eurjchem-604	814	3	was	be	AUX
eurjchem-604	814	4	immobilized	immobilize	VERB
eurjchem-604	814	5	on	on	ADP
eurjchem-604	814	6	polystyrene	polystyrene	NOUN
eurjchem-604	814	7	(	(	PUNCT
eurjchem-604	814	8	2	2	NUM
eurjchem-604	814	9	%	%	NOUN
eurjchem-604	814	10	cross‐linked	cross‐linke	VERB
eurjchem-604	814	11	with	with	ADP
eurjchem-604	814	12	divinylbenzene	divinylbenzene	NOUN
eurjchem-604	814	13	)	)	PUNCT
eurjchem-604	814	14	via	via	ADP
eurjchem-604	814	15	imidazole	imidazole	NOUN
eurjchem-604	814	16	linkage	linkage	NOUN
eurjchem-604	814	17	to	to	PART
eurjchem-604	814	18	obtain	obtain	VERB
eurjchem-604	814	19	a	a	DET
eurjchem-604	814	20	polymer‐supported	polymer‐supporte	VERB
eurjchem-604	814	21	molybdenum	molybdenum	NOUN
eurjchem-604	814	22	carbonyl	carbonyl	NOUN
eurjchem-604	814	23	catalyst	catalyst	NOUN
eurjchem-604	814	24	(	(	PUNCT
eurjchem-604	814	25	2	2	NUM
eurjchem-604	814	26	)	)	PUNCT
eurjchem-604	814	27	.	.	PUNCT
eurjchem-604	815	1	high	high	ADJ
eurjchem-604	815	2	conversion	conversion	NOUN
eurjchem-604	815	3	of	of	ADP
eurjchem-604	815	4	a	a	DET
eurjchem-604	815	5	range	range	NOUN
eurjchem-604	815	6	of	of	ADP
eurjchem-604	815	7	alkenes	alkene	NOUN
eurjchem-604	815	8	to	to	ADP
eurjchem-604	815	9	epoxides	epoxide	NOUN
eurjchem-604	815	10	was	be	AUX
eurjchem-604	815	11	achieved	achieve	VERB
eurjchem-604	815	12	with	with	ADP
eurjchem-604	815	13	tert‐butyl	tert‐butyl	X
eurjchem-604	815	14	hydroperoxide	hydroperoxide	NOUN
eurjchem-604	815	15	and	and	CCONJ
eurjchem-604	815	16	this	this	DET
eurjchem-604	815	17	catalyst	catalyst	NOUN
eurjchem-604	815	18	.	.	PUNCT
eurjchem-604	816	1	the	the	DET
eurjchem-604	816	2	catalyst	catalyst	NOUN
eurjchem-604	816	3	is	be	AUX
eurjchem-604	816	4	highly	highly	ADV
eurjchem-604	816	5	reusable	reusable	ADJ
eurjchem-604	816	6	and	and	CCONJ
eurjchem-604	816	7	it	it	PRON
eurjchem-604	816	8	was	be	AUX
eurjchem-604	816	9	reused	reuse	VERB
eurjchem-604	816	10	10	10	NUM
eurjchem-604	816	11	times	time	NOUN
eurjchem-604	816	12	without	without	ADP
eurjchem-604	816	13	a	a	DET
eurjchem-604	816	14	considerable	considerable	ADJ
eurjchem-604	816	15	change	change	NOUN
eurjchem-604	816	16	in	in	ADP
eurjchem-604	816	17	its	its	PRON
eurjchem-604	816	18	activity	activity	NOUN
eurjchem-604	816	19	[	[	X
eurjchem-604	816	20	236	236	NUM
eurjchem-604	816	21	]	]	PUNCT
eurjchem-604	816	22	.	.	PUNCT
eurjchem-604	817	1	6.2	6.2	NUM
eurjchem-604	817	2	.	.	PUNCT
eurjchem-604	818	1	in	in	ADP
eurjchem-604	818	2	nano	nano	NOUN
eurjchem-604	818	3	science	science	NOUN
eurjchem-604	818	4	and	and	CCONJ
eurjchem-604	818	5	nanotechnologies	nanotechnology	NOUN
eurjchem-604	818	6	the	the	DET
eurjchem-604	818	7	possible	possible	ADJ
eurjchem-604	818	8	role	role	NOUN
eurjchem-604	818	9	of	of	ADP
eurjchem-604	818	10	metal	metal	NOUN
eurjchem-604	818	11	carbonyl	carbonyl	NOUN
eurjchem-604	818	12	clusters	cluster	NOUN
eurjchem-604	818	13	in	in	ADP
eurjchem-604	818	14	nanoscience	nanoscience	PROPN
eurjchem-604	818	15	and	and	CCONJ
eurjchem-604	818	16	nanotechnologies	nanotechnology	NOUN
eurjchem-604	818	17	was	be	AUX
eurjchem-604	818	18	investigated	investigate	VERB
eurjchem-604	818	19	.	.	PUNCT
eurjchem-604	819	1	although	although	SCONJ
eurjchem-604	819	2	a	a	DET
eurjchem-604	819	3	few	few	ADJ
eurjchem-604	819	4	nanosized	nanosized	ADJ
eurjchem-604	819	5	metal	metal	NOUN
eurjchem-604	819	6	carbonyl	carbonyl	NOUN
eurjchem-604	819	7	clusters	cluster	NOUN
eurjchem-604	819	8	(	(	PUNCT
eurjchem-604	819	9	mcc	mcc	NOUN
eurjchem-604	819	10	)	)	PUNCT
eurjchem-604	819	11	were	be	AUX
eurjchem-604	819	12	already	already	ADV
eurjchem-604	819	13	obtained	obtain	VERB
eurjchem-604	819	14	in	in	ADP
eurjchem-604	819	15	the	the	DET
eurjchem-604	819	16	seventies	seventy	NOUN
eurjchem-604	819	17	,	,	PUNCT
eurjchem-604	819	18	these	these	DET
eurjchem-604	819	19	structurally	structurally	ADV
eurjchem-604	819	20	and	and	CCONJ
eurjchem-604	819	21	compositionally	compositionally	ADV
eurjchem-604	819	22	well‐defined	well‐defined	ADJ
eurjchem-604	819	23	molecules	molecule	NOUN
eurjchem-604	819	24	attracted	attract	VERB
eurjchem-604	819	25	the	the	DET
eurjchem-604	819	26	interest	interest	NOUN
eurjchem-604	819	27	of	of	ADP
eurjchem-604	819	28	nanoscientists	nanoscientist	NOUN
eurjchem-604	819	29	only	only	ADV
eurjchem-604	819	30	as	as	ADP
eurjchem-604	819	31	possible	possible	ADJ
eurjchem-604	819	32	precursors	precursor	NOUN
eurjchem-604	819	33	of	of	ADP
eurjchem-604	819	34	finely	finely	ADV
eurjchem-604	819	35	dispersed	disperse	VERB
eurjchem-604	819	36	metal	metal	NOUN
eurjchem-604	819	37	particles	particle	NOUN
eurjchem-604	819	38	for	for	ADP
eurjchem-604	819	39	heterogeneous	heterogeneous	ADJ
eurjchem-604	819	40	catalysis	catalysis	NOUN
eurjchem-604	819	41	.	.	PUNCT
eurjchem-604	820	1	cristina	cristina	PROPN
eurjchem-604	820	2	et	et	PROPN
eurjchem-604	820	3	al	al	PROPN
eurjchem-604	820	4	give	give	VERB
eurjchem-604	820	5	a	a	DET
eurjchem-604	820	6	brief	brief	ADJ
eurjchem-604	820	7	account	account	NOUN
eurjchem-604	820	8	of	of	ADP
eurjchem-604	820	9	most	most	ADJ
eurjchem-604	820	10	recent	recent	ADJ
eurjchem-604	820	11	results	result	NOUN
eurjchem-604	820	12	in	in	ADP
eurjchem-604	820	13	the	the	DET
eurjchem-604	820	14	field	field	NOUN
eurjchem-604	820	15	of	of	ADP
eurjchem-604	820	16	high‐	high‐	NOUN
eurjchem-604	820	17	nuclearity	nuclearity	NOUN
eurjchem-604	820	18	metal	metal	NOUN
eurjchem-604	820	19	carbonyl	carbonyl	NOUN
eurjchem-604	820	20	clusters	cluster	NOUN
eurjchem-604	820	21	and	and	CCONJ
eurjchem-604	820	22	their	their	PRON
eurjchem-604	820	23	emerging	emerge	VERB
eurjchem-604	820	24	properties	property	NOUN
eurjchem-604	820	25	.	.	PUNCT
eurjchem-604	821	1	in	in	ADP
eurjchem-604	821	2	doing	do	VERB
eurjchem-604	821	3	that	that	PRON
eurjchem-604	821	4	,	,	PUNCT
eurjchem-604	821	5	a	a	DET
eurjchem-604	821	6	look	look	NOUN
eurjchem-604	821	7	to	to	ADP
eurjchem-604	821	8	related	related	ADJ
eurjchem-604	821	9	behaviour	behaviour	NOUN
eurjchem-604	821	10	of	of	ADP
eurjchem-604	821	11	ligand‐	ligand‐	NOUN
eurjchem-604	821	12	stabilised	stabilise	VERB
eurjchem-604	821	13	and	and	CCONJ
eurjchem-604	821	14	ligand‐free	ligand‐free	ADJ
eurjchem-604	821	15	clusters	cluster	NOUN
eurjchem-604	821	16	(	(	PUNCT
eurjchem-604	821	17	figure	figure	NOUN
eurjchem-604	821	18	9	9	NUM
eurjchem-604	821	19	)	)	PUNCT
eurjchem-604	821	20	,	,	PUNCT
eurjchem-604	821	21	including	include	VERB
eurjchem-604	821	22	almost	almost	ADV
eurjchem-604	821	23	mono‐dispersed	mono‐disperse	VERB
eurjchem-604	821	24	ligand‐stabilised	ligand‐stabilise	VERB
eurjchem-604	821	25	metal	metal	NOUN
eurjchem-604	821	26	nanoparticles	nanoparticle	NOUN
eurjchem-604	821	27	,	,	PUNCT
eurjchem-604	821	28	should	should	AUX
eurjchem-604	821	29	be	be	AUX
eurjchem-604	821	30	done	do	VERB
eurjchem-604	821	31	.	.	PUNCT
eurjchem-604	822	1	they	they	PRON
eurjchem-604	822	2	found	find	VERB
eurjchem-604	822	3	contribution	contribution	NOUN
eurjchem-604	822	4	of	of	ADP
eurjchem-604	822	5	metal	metal	NOUN
eurjchem-604	822	6	carbonyl	carbonyl	NOUN
eurjchem-604	822	7	clusters	cluster	NOUN
eurjchem-604	822	8	to	to	ADP
eurjchem-604	822	9	some	some	DET
eurjchem-604	822	10	aspects	aspect	NOUN
eurjchem-604	822	11	of	of	ADP
eurjchem-604	822	12	nanoscience	nanoscience	NOUN
eurjchem-604	822	13	and	and	CCONJ
eurjchem-604	822	14	nanotechnologies	nanotechnology	NOUN
eurjchem-604	822	15	also	also	ADV
eurjchem-604	822	16	[	[	X
eurjchem-604	822	17	237	237	NUM
eurjchem-604	822	18	]	]	PUNCT
eurjchem-604	822	19	.	.	PUNCT
eurjchem-604	823	1	figure	figure	NOUN
eurjchem-604	823	2	9	9	NUM
eurjchem-604	823	3	.	.	PUNCT
eurjchem-604	824	1	an	an	DET
eurjchem-604	824	2	ordered	order	VERB
eurjchem-604	824	3	monolayer	monolayer	NOUN
eurjchem-604	824	4	of	of	ADP
eurjchem-604	824	5	differently	differently	ADV
eurjchem-604	824	6	charged	charge	VERB
eurjchem-604	824	7	individual	individual	ADJ
eurjchem-604	824	8	mcc	mcc	PROPN
eurjchem-604	824	9	capacitors	capacitor	NOUN
eurjchem-604	824	10	in	in	ADP
eurjchem-604	824	11	consequence	consequence	NOUN
eurjchem-604	824	12	of	of	ADP
eurjchem-604	824	13	their	their	PRON
eurjchem-604	824	14	electron‐sink	electron‐sink	NOUN
eurjchem-604	824	15	properties	property	NOUN
eurjchem-604	824	16	and	and	CCONJ
eurjchem-604	824	17	the	the	DET
eurjchem-604	824	18	insulating	insulate	VERB
eurjchem-604	824	19	behavior	behavior	NOUN
eurjchem-604	824	20	of	of	ADP
eurjchem-604	824	21	their	their	PRON
eurjchem-604	824	22	co	co	ADJ
eurjchem-604	824	23	shell	shell	NOUN
eurjchem-604	824	24	[	[	X
eurjchem-604	824	25	237	237	NUM
eurjchem-604	824	26	]	]	PUNCT
eurjchem-604	824	27	.	.	PUNCT
eurjchem-604	825	1	an	an	DET
eurjchem-604	825	2	approach	approach	NOUN
eurjchem-604	825	3	to	to	ADP
eurjchem-604	825	4	noble	noble	ADJ
eurjchem-604	825	5	metal‐metal	metal‐metal	ADJ
eurjchem-604	825	6	oxide	oxide	NOUN
eurjchem-604	825	7	dumbbell	dumbbell	NOUN
eurjchem-604	825	8	nanoparticles	nanoparticle	NOUN
eurjchem-604	825	9	based	base	VERB
eurjchem-604	825	10	on	on	ADP
eurjchem-604	825	11	seed‐mediated	seed‐mediated	ADJ
eurjchem-604	825	12	growth	growth	NOUN
eurjchem-604	825	13	(	(	PUNCT
eurjchem-604	825	14	figure	figure	NOUN
eurjchem-604	825	15	10	10	NUM
eurjchem-604	825	16	)	)	PUNCT
eurjchem-604	825	17	.	.	PUNCT
eurjchem-604	826	1	metal	metal	NOUN
eurjchem-604	826	2	oxides	oxide	NOUN
eurjchem-604	826	3	are	be	AUX
eurjchem-604	826	4	grown	grow	VERB
eurjchem-604	826	5	over	over	ADP
eurjchem-604	826	6	the	the	DET
eurjchem-604	826	7	presynthesized	presynthesize	VERB
eurjchem-604	826	8	noble	noble	ADJ
eurjchem-604	826	9	metal	metal	NOUN
eurjchem-604	826	10	seeds	seed	NOUN
eurjchem-604	826	11	by	by	ADP
eurjchem-604	826	12	thermal	thermal	ADJ
eurjchem-604	826	13	decomposition	decomposition	NOUN
eurjchem-604	826	14	of	of	ADP
eurjchem-604	826	15	metal	metal	NOUN
eurjchem-604	826	16	carbonyl	carbonyl	NOUN
eurjchem-604	826	17	followed	follow	VERB
eurjchem-604	826	18	by	by	ADP
eurjchem-604	826	19	oxidation	oxidation	NOUN
eurjchem-604	826	20	in	in	ADP
eurjchem-604	826	21	air	air	NOUN
eurjchem-604	826	22	.	.	PUNCT
eurjchem-604	827	1	the	the	DET
eurjchem-604	827	2	as‐synthesized	as‐synthesized	ADJ
eurjchem-604	827	3	dumbbell	dumbbell	NOUN
eurjchem-604	827	4	nanoparticles	nanoparticle	NOUN
eurjchem-604	827	5	have	have	VERB
eurjchem-604	827	6	intrinsic	intrinsic	ADJ
eurjchem-604	827	7	epitaxial	epitaxial	ADJ
eurjchem-604	827	8	linkage	linkage	NOUN
eurjchem-604	827	9	between	between	ADP
eurjchem-604	827	10	the	the	DET
eurjchem-604	827	11	metal	metal	NOUN
eurjchem-604	827	12	and	and	CCONJ
eurjchem-604	827	13	the	the	DET
eurjchem-604	827	14	oxide	oxide	NOUN
eurjchem-604	827	15	,	,	PUNCT
eurjchem-604	827	16	providing	provide	VERB
eurjchem-604	827	17	enhanced	enhanced	ADJ
eurjchem-604	827	18	heterojunction	heterojunction	NOUN
eurjchem-604	827	19	interactions	interaction	NOUN
eurjchem-604	827	20	[	[	X
eurjchem-604	827	21	238	238	NUM
eurjchem-604	827	22	]	]	PUNCT
eurjchem-604	827	23	.	.	PUNCT
eurjchem-604	828	1	figure	figure	NOUN
eurjchem-604	828	2	10	10	NUM
eurjchem-604	828	3	.	.	PUNCT
eurjchem-604	829	1	metal	metal	NOUN
eurjchem-604	829	2	carbonyl	carbonyl	NOUN
eurjchem-604	829	3	catalyzed	catalyze	VERB
eurjchem-604	829	4	reaction	reaction	NOUN
eurjchem-604	829	5	:	:	PUNCT
eurjchem-604	829	6	preparation	preparation	NOUN
eurjchem-604	829	7	of	of	ADP
eurjchem-604	829	8	metal‐metal	metal‐metal	ADJ
eurjchem-604	829	9	oxide	oxide	NOUN
eurjchem-604	829	10	dumbbell	dumbbell	NOUN
eurjchem-604	829	11	nanoparticles	nanoparticle	NOUN
eurjchem-604	829	12	[	[	X
eurjchem-604	829	13	238	238	NUM
eurjchem-604	829	14	]	]	PUNCT
eurjchem-604	829	15	.	.	PUNCT
eurjchem-604	830	1	6.3	6.3	NUM
eurjchem-604	830	2	.	.	PUNCT
eurjchem-604	831	1	in	in	ADP
eurjchem-604	831	2	pharmaceuticals	pharmaceutical	NOUN
eurjchem-604	831	3	metal	metal	NOUN
eurjchem-604	831	4	carbonyls	carbonyls	NOUN
eurjchem-604	831	5	and	and	CCONJ
eurjchem-604	831	6	their	their	PRON
eurjchem-604	831	7	use	use	NOUN
eurjchem-604	831	8	as	as	ADP
eurjchem-604	831	9	a	a	DET
eurjchem-604	831	10	new	new	ADJ
eurjchem-604	831	11	class	class	NOUN
eurjchem-604	831	12	of	of	ADP
eurjchem-604	831	13	pharmaceuticals	pharmaceutical	NOUN
eurjchem-604	831	14	were	be	AUX
eurjchem-604	831	15	studied	study	VERB
eurjchem-604	831	16	[	[	PUNCT
eurjchem-604	831	17	239	239	NUM
eurjchem-604	831	18	]	]	PUNCT
eurjchem-604	831	19	.	.	PUNCT
eurjchem-604	832	1	the	the	DET
eurjchem-604	832	2	hydrogenase	hydrogenase	ADJ
eurjchem-604	832	3	enzymes	enzyme	NOUN
eurjchem-604	832	4	contain	contain	VERB
eurjchem-604	832	5	co	co	INTJ
eurjchem-604	832	6	bound	bind	VERB
eurjchem-604	832	7	to	to	PART
eurjchem-604	832	8	iron	iron	VERB
eurjchem-604	832	9	,	,	PUNCT
eurjchem-604	832	10	apparently	apparently	ADV
eurjchem-604	832	11	the	the	DET
eurjchem-604	832	12	co	co	NOUN
eurjchem-604	832	13	stabilizes	stabilize	VERB
eurjchem-604	832	14	low	low	ADJ
eurjchem-604	832	15	oxidation	oxidation	NOUN
eurjchem-604	832	16	states	state	NOUN
eurjchem-604	832	17	which	which	PRON
eurjchem-604	832	18	facilitates	facilitate	VERB
eurjchem-604	832	19	the	the	DET
eurjchem-604	832	20	binding	binding	NOUN
eurjchem-604	832	21	of	of	ADP
eurjchem-604	832	22	hydrogen	hydrogen	NOUN
eurjchem-604	832	23	[	[	X
eurjchem-604	832	24	240,241	240,241	NUM
eurjchem-604	832	25	]	]	PUNCT
eurjchem-604	832	26	.	.	PUNCT
eurjchem-604	833	1	certain	certain	ADJ
eurjchem-604	833	2	metal	metal	NOUN
eurjchem-604	833	3	carbonyls	carbonyls	NOUN
eurjchem-604	833	4	have	have	AUX
eurjchem-604	833	5	been	be	AUX
eurjchem-604	833	6	observed	observe	VERB
eurjchem-604	833	7	in	in	ADP
eurjchem-604	833	8	trace	trace	NOUN
eurjchem-604	833	9	amounts	amount	NOUN
eurjchem-604	833	10	in	in	ADP
eurjchem-604	833	11	landfills	landfill	NOUN
eurjchem-604	833	12	,	,	PUNCT
eurjchem-604	833	13	where	where	SCONJ
eurjchem-604	833	14	the	the	DET
eurjchem-604	833	15	reducing	reduce	VERB
eurjchem-604	833	16	environment	environment	NOUN
eurjchem-604	833	17	is	be	AUX
eurjchem-604	833	18	compatible	compatible	ADJ
eurjchem-604	833	19	with	with	ADP
eurjchem-604	833	20	their	their	PRON
eurjchem-604	833	21	formation	formation	NOUN
eurjchem-604	833	22	[	[	X
eurjchem-604	833	23	242	242	NUM
eurjchem-604	833	24	]	]	SYM
eurjchem-604	833	25	.	.	PUNCT
eurjchem-604	834	1	metal	metal	NOUN
eurjchem-604	834	2	carbonyls	carbonyls	NOUN
eurjchem-604	834	3	have	have	AUX
eurjchem-604	834	4	extensively	extensively	ADV
eurjchem-604	834	5	shown	show	VERB
eurjchem-604	834	6	various	various	ADJ
eurjchem-604	834	7	antimicrobial	antimicrobial	ADJ
eurjchem-604	834	8	activity	activity	NOUN
eurjchem-604	834	9	against	against	ADP
eurjchem-604	834	10	e.	e.	PROPN
eurjchem-604	834	11	coli	coli	PROPN
eurjchem-604	834	12	,	,	PUNCT
eurjchem-604	834	13	s.	s.	PROPN
eurjchem-604	834	14	aureus	aureus	PROPN
eurjchem-604	834	15	,	,	PUNCT
eurjchem-604	834	16	b.	b.	PROPN
eurjchem-604	834	17	subtilis	subtilis	PROPN
eurjchem-604	834	18	,	,	PUNCT
eurjchem-604	834	19	p.	p.	NOUN
eurjchem-604	834	20	vulgaris	vulgaris	PROPN
eurjchem-604	834	21	etc	etc	X
eurjchem-604	834	22	.	.	X
eurjchem-604	834	23	bacteria	bacteria	NOUN
eurjchem-604	834	24	,	,	PUNCT
eurjchem-604	834	25	c.	c.	NOUN
eurjchem-604	834	26	albicans	albican	NOUN
eurjchem-604	834	27	,	,	PUNCT
eurjchem-604	834	28	t.	t.	NOUN
eurjchem-604	834	29	rubrum	rubrum	NOUN
eurjchem-604	834	30	,	,	PUNCT
eurjchem-604	834	31	t.	t.	PROPN
eurjchem-604	834	32	mentagrophytes	mentagrophyte	NOUN
eurjchem-604	834	33	,	,	PUNCT
eurjchem-604	834	34	a.	a.	NOUN
eurjchem-604	834	35	nigeretc	nigeretc	NOUN
eurjchem-604	834	36	.	.	PUNCT
eurjchem-604	835	1	fungi	fungi	PROPN
eurjchem-604	835	2	,	,	PUNCT
eurjchem-604	835	3	cucumber	cucumber	NOUN
eurjchem-604	835	4	mosaic	mosaic	PROPN
eurjchem-604	835	5	virus	virus	NOUN
eurjchem-604	835	6	,	,	PUNCT
eurjchem-604	835	7	insecticidal	insecticidal	NOUN
eurjchem-604	835	8	activity	activity	NOUN
eurjchem-604	835	9	and	and	CCONJ
eurjchem-604	835	10	plant	plant	NOUN
eurjchem-604	835	11	growth	growth	NOUN
eurjchem-604	835	12	inhibitory	inhibitory	ADJ
eurjchem-604	835	13	activity	activity	NOUN
eurjchem-604	835	14	on	on	ADP
eurjchem-604	835	15	rice	rice	NOUN
eurjchem-604	835	16	,	,	PUNCT
eurjchem-604	835	17	wheat	wheat	NOUN
eurjchem-604	835	18	and	and	CCONJ
eurjchem-604	835	19	barley	barley	NOUN
eurjchem-604	835	20	plants	plant	NOUN
eurjchem-604	835	21	.	.	PUNCT
eurjchem-604	836	1	metal	metal	NOUN
eurjchem-604	836	2	carbonyl	carbonyl	NOUN
eurjchem-604	836	3	complexes	complex	NOUN
eurjchem-604	836	4	also	also	ADV
eurjchem-604	836	5	shown	show	VERB
eurjchem-604	836	6	antitherapeutic	antitherapeutic	ADJ
eurjchem-604	836	7	activities	activity	NOUN
eurjchem-604	836	8	like	like	ADP
eurjchem-604	836	9	antitumor	antitumor	PROPN
eurjchem-604	836	10	and	and	CCONJ
eurjchem-604	836	11	cytotoxic	cytotoxic	ADJ
eurjchem-604	836	12	activities	activity	NOUN
eurjchem-604	836	13	[	[	X
eurjchem-604	836	14	242	242	NUM
eurjchem-604	836	15	]	]	SYM
eurjchem-604	836	16	.	.	PUNCT
eurjchem-604	837	1	6.4	6.4	NUM
eurjchem-604	837	2	.	.	PUNCT
eurjchem-604	838	1	in	in	ADP
eurjchem-604	838	2	synthesis	synthesis	NOUN
eurjchem-604	838	3	of	of	ADP
eurjchem-604	838	4	other	other	ADJ
eurjchem-604	838	5	complexes	complex	NOUN
eurjchem-604	838	6	metal	metal	NOUN
eurjchem-604	838	7	carbonyls	carbonyl	NOUN
eurjchem-604	838	8	are	be	AUX
eurjchem-604	838	9	found	find	VERB
eurjchem-604	838	10	their	their	PRON
eurjchem-604	838	11	important	important	ADJ
eurjchem-604	838	12	role	role	NOUN
eurjchem-604	838	13	in	in	ADP
eurjchem-604	838	14	finding	find	VERB
eurjchem-604	838	15	some	some	DET
eurjchem-604	838	16	specific	specific	ADJ
eurjchem-604	838	17	products	product	NOUN
eurjchem-604	838	18	.	.	PUNCT
eurjchem-604	839	1	photochemical	photochemical	ADJ
eurjchem-604	839	2	reactions	reaction	NOUN
eurjchem-604	839	3	of	of	ADP
eurjchem-604	839	4	ferrocenylacetylene	ferrocenylacetylene	NOUN
eurjchem-604	839	5	with	with	ADP
eurjchem-604	839	6	sulfur	sulfur	NOUN
eurjchem-604	839	7	in	in	ADP
eurjchem-604	839	8	presence	presence	NOUN
eurjchem-604	839	9	of	of	ADP
eurjchem-604	839	10	mo(co)6	mo(co)6	PROPN
eurjchem-604	839	11	gives	give	VERB
eurjchem-604	839	12	2,5‐diferrocenylthiophene	2,5‐diferrocenylthiophene	NUM
eurjchem-604	839	13	and	and	CCONJ
eurjchem-604	839	14	,	,	PUNCT
eurjchem-604	839	15	with	with	ADP
eurjchem-604	839	16	cr(co)6	cr(co)6	NOUN
eurjchem-604	839	17	,	,	PUNCT
eurjchem-604	839	18	2,6‐	2,6‐	NUM
eurjchem-604	839	19	diferrocenyldithiine	diferrocenyldithiine	NOUN
eurjchem-604	839	20	formed	form	VERB
eurjchem-604	839	21	.	.	PUNCT
eurjchem-604	840	1	formation	formation	NOUN
eurjchem-604	840	2	of	of	ADP
eurjchem-604	840	3	ferrocenyl‐	ferrocenyl‐	PROPN
eurjchem-604	840	4	substituted	substitute	VERB
eurjchem-604	840	5	thioketone	thioketone	NOUN
eurjchem-604	840	6	complexes	complex	NOUN
eurjchem-604	840	7	was	be	AUX
eurjchem-604	840	8	observed	observe	VERB
eurjchem-604	840	9	in	in	ADP
eurjchem-604	840	10	the	the	DET
eurjchem-604	840	11	reaction	reaction	NOUN
eurjchem-604	840	12	of	of	ADP
eurjchem-604	840	13	ferrocenylacetylene	ferrocenylacetylene	NOUN
eurjchem-604	840	14	with	with	ADP
eurjchem-604	840	15	water	water	NOUN
eurjchem-604	840	16	and	and	CCONJ
eurjchem-604	840	17	sulfur	sulfur	NOUN
eurjchem-604	840	18	,	,	PUNCT
eurjchem-604	840	19	in	in	ADP
eurjchem-604	840	20	presence	presence	NOUN
eurjchem-604	840	21	of	of	ADP
eurjchem-604	840	22	w(co)6	w(co)6	PROPN
eurjchem-604	841	1	[	[	X
eurjchem-604	841	2	243	243	NUM
eurjchem-604	841	3	]	]	PUNCT
eurjchem-604	841	4	.	.	PUNCT
eurjchem-604	842	1	darensbourg	darensbourg	PROPN
eurjchem-604	842	2	reported	report	VERB
eurjchem-604	842	3	the	the	DET
eurjchem-604	842	4	group	group	NOUN
eurjchem-604	842	5	6	6	NUM
eurjchem-604	842	6	pentacarbonyl	pentacarbonyl	NOUN
eurjchem-604	842	7	hydrides	hydride	NOUN
eurjchem-604	842	8	and	and	CCONJ
eurjchem-604	842	9	various	various	ADJ
eurjchem-604	842	10	methods	method	NOUN
eurjchem-604	842	11	for	for	ADP
eurjchem-604	842	12	their	their	PRON
eurjchem-604	842	13	synthesis	synthesis	NOUN
eurjchem-604	842	14	[	[	X
eurjchem-604	842	15	244‐246	244‐246	NUM
eurjchem-604	842	16	]	]	PUNCT
eurjchem-604	842	17	.	.	PUNCT
eurjchem-604	843	1	retracted	retract	VERB
eurjchem-604	843	2	kaushik	kaushik	PROPN
eurjchem-604	843	3	et	et	PROPN
eurjchem-604	843	4	al	al	PROPN
eurjchem-604	843	5	.	.	PUNCT
eurjchem-604	843	6	/	/	SYM
eurjchem-604	843	7	european	european	PROPN
eurjchem-604	843	8	journal	journal	PROPN
eurjchem-604	843	9	of	of	ADP
eurjchem-604	843	10	chemistry	chemistry	NOUN
eurjchem-604	843	11	3	3	NUM
eurjchem-604	843	12	(	(	PUNCT
eurjchem-604	843	13	3	3	NUM
eurjchem-604	843	14	)	)	PUNCT
eurjchem-604	843	15	(	(	PUNCT
eurjchem-604	843	16	2012	2012	NUM
eurjchem-604	843	17	)	)	PUNCT
eurjchem-604	843	18	367‐394	367‐394	NOUN
eurjchem-604	843	19	387	387	NUM
eurjchem-604	843	20	scheme	scheme	NOUN
eurjchem-604	843	21	64	64	NUM
eurjchem-604	843	22	a	a	DET
eurjchem-604	843	23	major	major	ADJ
eurjchem-604	843	24	challenge	challenge	NOUN
eurjchem-604	843	25	that	that	PRON
eurjchem-604	843	26	must	must	AUX
eurjchem-604	843	27	be	be	AUX
eurjchem-604	843	28	met	meet	VERB
eurjchem-604	843	29	for	for	ADP
eurjchem-604	843	30	an	an	DET
eurjchem-604	843	31	asymmetric	asymmetric	ADJ
eurjchem-604	843	32	intermolecular	intermolecular	ADJ
eurjchem-604	843	33	pauson‐khand	pauson‐khand	CCONJ
eurjchem-604	843	34	reaction	reaction	NOUN
eurjchem-604	843	35	is	be	AUX
eurjchem-604	843	36	to	to	PART
eurjchem-604	843	37	be	be	AUX
eurjchem-604	843	38	able	able	ADJ
eurjchem-604	843	39	to	to	PART
eurjchem-604	843	40	limit	limit	VERB
eurjchem-604	843	41	the	the	DET
eurjchem-604	843	42	possible	possible	ADJ
eurjchem-604	843	43	positions	position	NOUN
eurjchem-604	843	44	on	on	ADP
eurjchem-604	843	45	the	the	DET
eurjchem-604	843	46	metal	metal	NOUN
eurjchem-604	843	47	complex	complex	NOUN
eurjchem-604	843	48	for	for	ADP
eurjchem-604	843	49	the	the	DET
eurjchem-604	843	50	organic	organic	ADJ
eurjchem-604	843	51	partners	partner	NOUN
eurjchem-604	843	52	.	.	PUNCT
eurjchem-604	844	1	toward	toward	ADP
eurjchem-604	844	2	this	this	DET
eurjchem-604	844	3	end	end	NOUN
eurjchem-604	844	4	,	,	PUNCT
eurjchem-604	844	5	the	the	DET
eurjchem-604	844	6	synthesis	synthesis	NOUN
eurjchem-604	844	7	of	of	ADP
eurjchem-604	844	8	monometallic	monometallic	NOUN
eurjchem-604	844	9	systems	system	NOUN
eurjchem-604	844	10	derived	derive	VERB
eurjchem-604	844	11	from	from	ADP
eurjchem-604	844	12	m(co)6	m(co)6	NOUN
eurjchem-604	844	13	and	and	CCONJ
eurjchem-604	844	14	two	two	NUM
eurjchem-604	844	15	bidentate	bidentate	ADJ
eurjchem-604	844	16	ligands	ligand	NOUN
eurjchem-604	844	17	,	,	PUNCT
eurjchem-604	844	18	in	in	ADP
eurjchem-604	844	19	which	which	PRON
eurjchem-604	844	20	the	the	DET
eurjchem-604	844	21	number	number	NOUN
eurjchem-604	844	22	of	of	ADP
eurjchem-604	844	23	possible	possible	ADJ
eurjchem-604	844	24	coordination	coordination	NOUN
eurjchem-604	844	25	sites	site	NOUN
eurjchem-604	844	26	is	be	AUX
eurjchem-604	844	27	reduced	reduce	VERB
eurjchem-604	844	28	to	to	ADP
eurjchem-604	844	29	two	two	NUM
eurjchem-604	844	30	this	this	DET
eurjchem-604	844	31	lead	lead	NOUN
eurjchem-604	844	32	to	to	ADP
eurjchem-604	844	33	enantioselective	enantioselective	ADJ
eurjchem-604	844	34	pauson‐khand	pauson‐khand	NOUN
eurjchem-604	844	35	reactions	reaction	NOUN
eurjchem-604	844	36	resulting	result	VERB
eurjchem-604	844	37	the	the	DET
eurjchem-604	844	38	formation	formation	NOUN
eurjchem-604	844	39	of	of	ADP
eurjchem-604	844	40	chiral	chiral	ADJ
eurjchem-604	844	41	cyclopentanones	cyclopentanone	NOUN
eurjchem-604	844	42	(	(	PUNCT
eurjchem-604	844	43	scheme	scheme	NOUN
eurjchem-604	844	44	61	61	NUM
eurjchem-604	844	45	)	)	PUNCT
eurjchem-604	845	1	[	[	X
eurjchem-604	845	2	247	247	NUM
eurjchem-604	845	3	]	]	PUNCT
eurjchem-604	845	4	.	.	PUNCT
eurjchem-604	846	1	scheme	scheme	NOUN
eurjchem-604	846	2	61	61	NUM
eurjchem-604	846	3	new	new	ADJ
eurjchem-604	846	4	polynuclear	polynuclear	NOUN
eurjchem-604	846	5	lanthanide(iii	lanthanide(iii	PROPN
eurjchem-604	846	6	)	)	PUNCT
eurjchem-604	846	7	ionic	ionic	ADJ
eurjchem-604	846	8	clusters	cluster	NOUN
eurjchem-604	846	9	of	of	ADP
eurjchem-604	846	10	general	general	ADJ
eurjchem-604	846	11	formula	formula	NOUN
eurjchem-604	847	1	[	[	X
eurjchem-604	847	2	ln9(acac)16(oh)10]+	ln9(acac)16(oh)10]+	X
eurjchem-604	847	3	[	[	X
eurjchem-604	847	4	mo2(co)10(μ‐h)]−	mo2(co)10(μ‐h)]−	PROPN
eurjchem-604	847	5	(	(	PUNCT
eurjchem-604	847	6	ln	ln	NOUN
eurjchem-604	847	7	=	=	PUNCT
eurjchem-604	847	8	sm	sm	PROPN
eurjchem-604	847	9	,	,	PUNCT
eurjchem-604	847	10	eu	eu	PROPN
eurjchem-604	847	11	,	,	PUNCT
eurjchem-604	847	12	gd	gd	NOUN
eurjchem-604	847	13	,	,	PUNCT
eurjchem-604	847	14	dy	dy	X
eurjchem-604	847	15	,	,	PUNCT
eurjchem-604	847	16	yb	yb	PROPN
eurjchem-604	847	17	)	)	PUNCT
eurjchem-604	847	18	and	and	CCONJ
eurjchem-604	847	19	[	[	X
eurjchem-604	847	20	sm9(acac)16(oh)10]+	sm9(acac)16(oh)10]+	X
eurjchem-604	847	21	[	[	X
eurjchem-604	847	22	crw(co)10(μ‐h)]−	crw(co)10(μ‐h)]−	PROPN
eurjchem-604	847	23	is	be	AUX
eurjchem-604	847	24	reported	report	VERB
eurjchem-604	847	25	.	.	PUNCT
eurjchem-604	848	1	the	the	DET
eurjchem-604	848	2	polynuclear	polynuclear	NOUN
eurjchem-604	848	3	complexes	complex	NOUN
eurjchem-604	848	4	,	,	PUNCT
eurjchem-604	848	5	prepared	prepare	VERB
eurjchem-604	848	6	under	under	ADP
eurjchem-604	848	7	pure	pure	ADJ
eurjchem-604	848	8	nitrogen	nitrogen	NOUN
eurjchem-604	848	9	atmosphere	atmosphere	NOUN
eurjchem-604	848	10	by	by	ADP
eurjchem-604	848	11	interaction	interaction	NOUN
eurjchem-604	848	12	of	of	ADP
eurjchem-604	848	13	the	the	DET
eurjchem-604	848	14	hydridic	hydridic	ADJ
eurjchem-604	848	15	metal	metal	NOUN
eurjchem-604	848	16	carbonyls	carbonyls	NOUN
eurjchem-604	848	17	with	with	ADP
eurjchem-604	848	18	the	the	DET
eurjchem-604	848	19	β‐dichetonate	β‐dichetonate	PUNCT
eurjchem-604	848	20	ln(acac)3·3h2o	ln(acac)3·3h2o	PROPN
eurjchem-604	848	21	(	(	PUNCT
eurjchem-604	848	22	ln	ln	NOUN
eurjchem-604	848	23	=	=	PUNCT
eurjchem-604	848	24	sm	sm	PROPN
eurjchem-604	848	25	,	,	PUNCT
eurjchem-604	848	26	eu	eu	PROPN
eurjchem-604	848	27	,	,	PUNCT
eurjchem-604	848	28	gd	gd	NOUN
eurjchem-604	848	29	,	,	PUNCT
eurjchem-604	848	30	dy	dy	X
eurjchem-604	848	31	,	,	PUNCT
eurjchem-604	848	32	yb	yb	PROPN
eurjchem-604	848	33	)	)	PUNCT
eurjchem-604	849	1	[	[	X
eurjchem-604	849	2	248	248	NUM
eurjchem-604	849	3	]	]	PUNCT
eurjchem-604	849	4	.	.	PUNCT
eurjchem-604	850	1	novel	novel	ADJ
eurjchem-604	850	2	c3v	c3v	PROPN
eurjchem-604	850	3	‐symmetric	‐symmetric	PROPN
eurjchem-604	850	4	scaffold	scaffold	NOUN
eurjchem-604	850	5	,	,	PUNCT
eurjchem-604	850	6	trindane	trindane	NOUN
eurjchem-604	850	7	has	have	AUX
eurjchem-604	850	8	been	be	AUX
eurjchem-604	850	9	efficiently	efficiently	ADV
eurjchem-604	850	10	synthesized	synthesize	VERB
eurjchem-604	850	11	from	from	ADP
eurjchem-604	850	12	1,3,5‐tris(bromomethyl)‐2,4,6‐	1,3,5‐tris(bromomethyl)‐2,4,6‐	NUM
eurjchem-604	850	13	tris(chloromethyl)benzene	tris(chloromethyl)benzene	NOUN
eurjchem-604	850	14	in	in	ADP
eurjchem-604	850	15	six	six	NUM
eurjchem-604	850	16	steps	step	NOUN
eurjchem-604	850	17	with	with	ADP
eurjchem-604	850	18	47	47	NUM
eurjchem-604	850	19	%	%	NOUN
eurjchem-604	850	20	overall	overall	ADJ
eurjchem-604	850	21	yield	yield	NOUN
eurjchem-604	850	22	.	.	PUNCT
eurjchem-604	851	1	the	the	DET
eurjchem-604	851	2	control	control	NOUN
eurjchem-604	851	3	of	of	ADP
eurjchem-604	851	4	all‐synstereochemistry	all‐synstereochemistry	NOUN
eurjchem-604	851	5	in	in	ADP
eurjchem-604	851	6	the	the	DET
eurjchem-604	851	7	tribenzylation	tribenzylation	NOUN
eurjchem-604	851	8	step	step	NOUN
eurjchem-604	851	9	has	have	AUX
eurjchem-604	851	10	been	be	AUX
eurjchem-604	851	11	achieved	achieve	VERB
eurjchem-604	851	12	by	by	ADP
eurjchem-604	851	13	blocking	block	VERB
eurjchem-604	851	14	one	one	NUM
eurjchem-604	851	15	side	side	NOUN
eurjchem-604	851	16	of	of	ADP
eurjchem-604	851	17	the	the	DET
eurjchem-604	851	18	trindane	trindane	NOUN
eurjchem-604	851	19	ring	ring	NOUN
eurjchem-604	851	20	by	by	ADP
eurjchem-604	851	21	metal	metal	NOUN
eurjchem-604	851	22	carbonyl	carbonyl	NOUN
eurjchem-604	851	23	complexes	complex	NOUN
eurjchem-604	851	24	(	(	PUNCT
eurjchem-604	851	25	scheme	scheme	NOUN
eurjchem-604	851	26	62	62	NUM
eurjchem-604	851	27	)	)	PUNCT
eurjchem-604	852	1	[	[	X
eurjchem-604	852	2	249	249	NUM
eurjchem-604	852	3	]	]	PUNCT
eurjchem-604	852	4	.	.	PUNCT
eurjchem-604	853	1	scheme	scheme	VERB
eurjchem-604	853	2	62	62	NUM
eurjchem-604	853	3	chromium	chromium	NOUN
eurjchem-604	853	4	fischer	fischer	NOUN
eurjchem-604	853	5	carbene	carbene	NOUN
eurjchem-604	853	6	complexes	complex	NOUN
eurjchem-604	853	7	,	,	PUNCT
eurjchem-604	853	8	[	[	X
eurjchem-604	853	9	cr{=ome(r)}(co)5	cr{=ome(r)}(co)5	X
eurjchem-604	853	10	]	]	X
eurjchem-604	853	11	have	have	AUX
eurjchem-604	853	12	been	be	AUX
eurjchem-604	853	13	utilized	utilize	VERB
eurjchem-604	853	14	as	as	ADP
eurjchem-604	853	15	a	a	DET
eurjchem-604	853	16	source	source	NOUN
eurjchem-604	853	17	of	of	ADP
eurjchem-604	853	18	chromium	chromium	NOUN
eurjchem-604	853	19	carbonyls	carbonyls	NOUN
eurjchem-604	853	20	in	in	ADP
eurjchem-604	853	21	the	the	DET
eurjchem-604	853	22	synthesis	synthesis	NOUN
eurjchem-604	853	23	of	of	ADP
eurjchem-604	853	24	chromium	chromium	NOUN
eurjchem-604	853	25	nhc	nhc	NOUN
eurjchem-604	853	26	(	(	PUNCT
eurjchem-604	853	27	n‐heterocyclic	n‐heterocyclic	ADV
eurjchem-604	853	28	carbene	carbene	NOUN
eurjchem-604	853	29	)	)	PUNCT
eurjchem-604	853	30	complexes	complex	NOUN
eurjchem-604	853	31	(	(	PUNCT
eurjchem-604	853	32	scheme	scheme	NOUN
eurjchem-604	853	33	63	63	NUM
eurjchem-604	853	34	)	)	PUNCT
eurjchem-604	853	35	.	.	PUNCT
eurjchem-604	854	1	the	the	DET
eurjchem-604	854	2	method	method	NOUN
eurjchem-604	854	3	can	can	AUX
eurjchem-604	854	4	be	be	AUX
eurjchem-604	854	5	employed	employ	VERB
eurjchem-604	854	6	for	for	ADP
eurjchem-604	854	7	the	the	DET
eurjchem-604	854	8	synthesis	synthesis	NOUN
eurjchem-604	854	9	of	of	ADP
eurjchem-604	854	10	molybdenum	molybdenum	NOUN
eurjchem-604	854	11	and	and	CCONJ
eurjchem-604	854	12	tungsten	tungsten	NOUN
eurjchem-604	854	13	nhc	nhc	PROPN
eurjchem-604	854	14	compounds	compound	VERB
eurjchem-604	855	1	[	[	X
eurjchem-604	855	2	250	250	NUM
eurjchem-604	855	3	]	]	PUNCT
eurjchem-604	855	4	.	.	PUNCT
eurjchem-604	856	1	the	the	DET
eurjchem-604	856	2	reaction	reaction	NOUN
eurjchem-604	856	3	of	of	ADP
eurjchem-604	856	4	fischer	fischer	PROPN
eurjchem-604	856	5	carbene	carbene	NOUN
eurjchem-604	856	6	complex	complex	NOUN
eurjchem-604	856	7	with	with	ADP
eurjchem-604	856	8	o‐	o‐	PROPN
eurjchem-604	856	9	alkynylpyridine	alkynylpyridine	NOUN
eurjchem-604	856	10	carbonyl	carbonyl	NOUN
eurjchem-604	856	11	derivatives	derivative	NOUN
eurjchem-604	856	12	involves	involve	VERB
eurjchem-604	856	13	the	the	DET
eurjchem-604	856	14	generation	generation	NOUN
eurjchem-604	856	15	of	of	ADP
eurjchem-604	856	16	furo	furo	NOUN
eurjchem-604	857	1	[	[	X
eurjchem-604	857	2	3,4‐c]pyridine	3,4‐c]pyridine	NOUN
eurjchem-604	857	3	as	as	ADP
eurjchem-604	857	4	transient	transient	ADJ
eurjchem-604	857	5	intermediates	intermediate	NOUN
eurjchem-604	857	6	through	through	ADP
eurjchem-604	857	7	the	the	DET
eurjchem-604	857	8	coupling	coupling	NOUN
eurjchem-604	857	9	of	of	ADP
eurjchem-604	857	10	o‐alkynylpyridine	o‐alkynylpyridine	PUNCT
eurjchem-604	857	11	carbonyl	carbonyl	NOUN
eurjchem-604	857	12	derivatives	derivative	NOUN
eurjchem-604	857	13	with	with	ADP
eurjchem-604	857	14	carbene	carbene	NOUN
eurjchem-604	857	15	complex	complex	ADJ
eurjchem-604	857	16	and	and	CCONJ
eurjchem-604	857	17	subsequent	subsequent	ADJ
eurjchem-604	857	18	diels‐alder	diels‐alder	NOUN
eurjchem-604	857	19	trapping	trap	VERB
eurjchem-604	857	20	with	with	ADP
eurjchem-604	857	21	suitable	suitable	ADJ
eurjchem-604	857	22	dienophiles	dienophile	NOUN
eurjchem-604	857	23	resulted	result	VERB
eurjchem-604	857	24	in	in	ADP
eurjchem-604	857	25	the	the	DET
eurjchem-604	857	26	formation	formation	NOUN
eurjchem-604	857	27	of	of	ADP
eurjchem-604	857	28	isoquinoline	isoquinoline	ADJ
eurjchem-604	857	29	derivatives	derivative	NOUN
eurjchem-604	857	30	and	and	CCONJ
eurjchem-604	857	31	the	the	DET
eurjchem-604	857	32	entire	entire	ADJ
eurjchem-604	857	33	sequence	sequence	NOUN
eurjchem-604	857	34	can	can	AUX
eurjchem-604	857	35	be	be	AUX
eurjchem-604	857	36	run	run	VERB
eurjchem-604	857	37	in	in	ADP
eurjchem-604	857	38	one	one	NUM
eurjchem-604	857	39	pot	pot	NOUN
eurjchem-604	857	40	(	(	PUNCT
eurjchem-604	857	41	scheme	scheme	NOUN
eurjchem-604	857	42	64	64	NUM
eurjchem-604	857	43	)	)	PUNCT
eurjchem-604	857	44	.	.	PUNCT
eurjchem-604	858	1	when	when	SCONJ
eurjchem-604	858	2	an	an	DET
eurjchem-604	858	3	olefinic	olefinic	ADJ
eurjchem-604	858	4	tether	tether	NOUN
eurjchem-604	858	5	was	be	AUX
eurjchem-604	858	6	present	present	ADJ
eurjchem-604	858	7	,	,	PUNCT
eurjchem-604	858	8	intramolecular	intramolecular	ADJ
eurjchem-604	858	9	diels‐alder	diels‐alder	NOUN
eurjchem-604	858	10	cycloaddition	cycloaddition	NOUN
eurjchem-604	858	11	occurred	occurred	AUX
eurjchem-604	858	12	followed	follow	VERB
eurjchem-604	858	13	by	by	ADP
eurjchem-604	858	14	ring	ring	NOUN
eurjchem-604	858	15	opening	opening	NOUN
eurjchem-604	858	16	to	to	PART
eurjchem-604	858	17	yield	yield	VERB
eurjchem-604	858	18	tricyclic	tricyclic	ADJ
eurjchem-604	858	19	alcohols	alcohol	NOUN
eurjchem-604	858	20	[	[	X
eurjchem-604	858	21	251	251	NUM
eurjchem-604	858	22	]	]	PUNCT
eurjchem-604	858	23	.	.	PUNCT
eurjchem-604	859	1	scheme	scheme	VERB
eurjchem-604	859	2	63	63	NUM
eurjchem-604	859	3	phosphazene	phosphazene	NOUN
eurjchem-604	859	4	copolymers	copolymer	NOUN
eurjchem-604	859	5	(	(	PUNCT
eurjchem-604	859	6	scheme	scheme	NOUN
eurjchem-604	859	7	65	65	NUM
eurjchem-604	859	8	)	)	PUNCT
eurjchem-604	859	9	carrying	carry	VERB
eurjchem-604	859	10	nitrile	nitrile	NOUN
eurjchem-604	859	11	,	,	PUNCT
eurjchem-604	859	12	pyridine	pyridine	NOUN
eurjchem-604	859	13	and	and	CCONJ
eurjchem-604	859	14	phosphine	phosphine	NOUN
eurjchem-604	859	15	ligands	ligand	NOUN
eurjchem-604	859	16	have	have	AUX
eurjchem-604	859	17	been	be	AUX
eurjchem-604	859	18	synthesized	synthesize	VERB
eurjchem-604	859	19	by	by	ADP
eurjchem-604	859	20	sequential	sequential	ADJ
eurjchem-604	859	21	substitution	substitution	NOUN
eurjchem-604	859	22	from	from	ADP
eurjchem-604	859	23	[	[	X
eurjchem-604	859	24	npcl2]n	npcl2]n	ADJ
eurjchem-604	859	25	.	.	PUNCT
eurjchem-604	860	1	their	their	PRON
eurjchem-604	860	2	reactions	reaction	NOUN
eurjchem-604	860	3	with	with	ADP
eurjchem-604	860	4	[	[	X
eurjchem-604	860	5	w(meoh)(co)5	w(meoh)(co)5	NUM
eurjchem-604	860	6	]	]	PUNCT
eurjchem-604	860	7	gives	give	VERB
eurjchem-604	860	8	the	the	DET
eurjchem-604	860	9	corresponding	corresponding	ADJ
eurjchem-604	860	10	tungstencarbonyl	tungstencarbonyl	NOUN
eurjchem-604	860	11	complexes	complex	NOUN
eurjchem-604	860	12	,	,	PUNCT
eurjchem-604	860	13	that	that	PRON
eurjchem-604	860	14	undergo	undergo	VERB
eurjchem-604	860	15	a	a	DET
eurjchem-604	860	16	complete	complete	ADJ
eurjchem-604	860	17	decarbonylation	decarbonylation	NOUN
eurjchem-604	860	18	below	below	ADP
eurjchem-604	860	19	300	300	NUM
eurjchem-604	860	20	°	°	NOUN
eurjchem-604	860	21	c	c	NOUN
eurjchem-604	860	22	forming	form	VERB
eurjchem-604	860	23	metal	metal	NOUN
eurjchem-604	860	24	containing	contain	VERB
eurjchem-604	860	25	species	specie	NOUN
eurjchem-604	860	26	that	that	PRON
eurjchem-604	860	27	have	have	VERB
eurjchem-604	860	28	a	a	DET
eurjchem-604	860	29	stabilizing	stabilize	VERB
eurjchem-604	860	30	effect	effect	NOUN
eurjchem-604	860	31	on	on	ADP
eurjchem-604	860	32	the	the	DET
eurjchem-604	860	33	polymeric	polymeric	ADJ
eurjchem-604	860	34	matrices	matrix	NOUN
eurjchem-604	860	35	[	[	X
eurjchem-604	860	36	252	252	NUM
eurjchem-604	860	37	]	]	PUNCT
eurjchem-604	860	38	.	.	PUNCT
eurjchem-604	861	1	scheme	scheme	NOUN
eurjchem-604	861	2	65	65	NUM
eurjchem-604	861	3	polymer‐bound	polymer‐bound	NOUN
eurjchem-604	861	4	ruthenium	ruthenium	NOUN
eurjchem-604	861	5	and	and	CCONJ
eurjchem-604	861	6	molybdenum	molybdenum	NOUN
eurjchem-604	861	7	carbonyl	carbonyl	NOUN
eurjchem-604	861	8	fragments	fragment	NOUN
eurjchem-604	861	9	were	be	AUX
eurjchem-604	861	10	prepared	prepare	VERB
eurjchem-604	861	11	and	and	CCONJ
eurjchem-604	861	12	their	their	PRON
eurjchem-604	861	13	use	use	NOUN
eurjchem-604	861	14	in	in	ADP
eurjchem-604	861	15	a	a	DET
eurjchem-604	861	16	ligand	ligand	ADJ
eurjchem-604	861	17	exchange	exchange	NOUN
eurjchem-604	861	18	reaction	reaction	NOUN
eurjchem-604	861	19	was	be	AUX
eurjchem-604	861	20	demonstrated	demonstrate	VERB
eurjchem-604	861	21	(	(	PUNCT
eurjchem-604	861	22	scheme	scheme	NOUN
eurjchem-604	861	23	66	66	NUM
eurjchem-604	861	24	)	)	PUNCT
eurjchem-604	862	1	[	[	X
eurjchem-604	862	2	253	253	NUM
eurjchem-604	862	3	]	]	PUNCT
eurjchem-604	862	4	.	.	PUNCT
eurjchem-604	863	1	scheme	scheme	NOUN
eurjchem-604	863	2	66	66	NUM
eurjchem-604	863	3	in	in	ADP
eurjchem-604	863	4	preparation	preparation	NOUN
eurjchem-604	863	5	of	of	ADP
eurjchem-604	863	6	metal	metal	NOUN
eurjchem-604	863	7	carbonyl	carbonyl	NOUN
eurjchem-604	863	8	anions	anion	NOUN
eurjchem-604	863	9	:	:	PUNCT
eurjchem-604	863	10	gibson	gibson	PROPN
eurjchem-604	863	11	et	et	PROPN
eurjchem-604	863	12	al	al	PROPN
eurjchem-604	863	13	.	.	PROPN
eurjchem-604	863	14	generated	generate	VERB
eurjchem-604	863	15	group	group	NOUN
eurjchem-604	863	16	6	6	NUM
eurjchem-604	863	17	metal	metal	NOUN
eurjchem-604	863	18	carbonyl	carbonyl	NOUN
eurjchem-604	863	19	anionshm(co)5‐by	anionshm(co)5‐by	NOUN
eurjchem-604	863	20	ion‐pair	ion‐pair	PRON
eurjchem-604	863	21	extraction	extraction	NOUN
eurjchem-604	863	22	.	.	PUNCT
eurjchem-604	864	1	synthesis	synthesis	NOUN
eurjchem-604	864	2	ofhm(co)5‐(m	ofhm(co)5‐(m	NUM
eurjchem-604	864	3	=	=	SYM
eurjchem-604	864	4	cr	cr	PROPN
eurjchem-604	864	5	or	or	CCONJ
eurjchem-604	864	6	w	w	PROPN
eurjchem-604	864	7	)	)	PUNCT
eurjchem-604	864	8	from	from	ADP
eurjchem-604	864	9	m(co)6	m(co)6	NUM
eurjchem-604	864	10	utilizes	utilize	VERB
eurjchem-604	864	11	tetraethylammonium	tetraethylammonium	NOUN
eurjchem-604	864	12	hydrogen	hydrogen	NOUN
eurjchem-604	864	13	sulfate	sulfate	NOUN
eurjchem-604	864	14	as	as	SCONJ
eurjchem-604	864	15	the	the	DET
eurjchem-604	864	16	phase	phase	NOUN
eurjchem-604	864	17	transfer	transfer	VERB
eurjchem-604	864	18	aganet	aganet	NOUN
eurjchem-604	864	19	together	together	ADV
eurjchem-604	864	20	with	with	ADP
eurjchem-604	864	21	powdered	powdered	ADJ
eurjchem-604	864	22	koh	koh	PROPN
eurjchem-604	865	1	[	[	X
eurjchem-604	865	2	254	254	NUM
eurjchem-604	865	3	]	]	PUNCT
eurjchem-604	865	4	.	.	PUNCT
eurjchem-604	866	1	the	the	DET
eurjchem-604	866	2	reaction	reaction	NOUN
eurjchem-604	866	3	times	time	NOUN
eurjchem-604	866	4	were	be	AUX
eurjchem-604	866	5	short	short	ADJ
eurjchem-604	866	6	and	and	CCONJ
eurjchem-604	866	7	the	the	DET
eurjchem-604	866	8	product	product	NOUN
eurjchem-604	866	9	yields	yield	NOUN
eurjchem-604	866	10	were	be	AUX
eurjchem-604	866	11	good	good	ADJ
eurjchem-604	866	12	[	[	X
eurjchem-604	866	13	255	255	NUM
eurjchem-604	866	14	]	]	PUNCT
eurjchem-604	866	15	.	.	PUNCT
eurjchem-604	867	1	cherng	cherng	NOUN
eurjchem-604	867	2	et	et	PROPN
eurjchem-604	867	3	al	al	PROPN
eurjchem-604	867	4	.	.	PROPN
eurjchem-604	867	5	have	have	AUX
eurjchem-604	867	6	synthesized	synthesize	VERB
eurjchem-604	867	7	chromium	chromium	NOUN
eurjchem-604	867	8	pentacarbonyl	pentacarbonyl	NOUN
eurjchem-604	867	9	derivatives	derivative	NOUN
eurjchem-604	867	10	of	of	ADP
eurjchem-604	867	11	arsenic	arsenic	ADJ
eurjchem-604	867	12	(	(	PUNCT
eurjchem-604	867	13	v	v	NOUN
eurjchem-604	867	14	)	)	PUNCT
eurjchem-604	867	15	and	and	CCONJ
eurjchem-604	867	16	antimony	antimony	NOUN
eurjchem-604	867	17	(	(	PUNCT
eurjchem-604	867	18	v	v	NOUN
eurjchem-604	867	19	)	)	PUNCT
eurjchem-604	867	20	(	(	PUNCT
eurjchem-604	867	21	scheme	scheme	NOUN
eurjchem-604	867	22	67	67	NUM
eurjchem-604	867	23	)	)	PUNCT
eurjchem-604	868	1	[	[	X
eurjchem-604	868	2	256	256	NUM
eurjchem-604	868	3	]	]	PUNCT
eurjchem-604	868	4	.	.	PUNCT
eurjchem-604	869	1	the	the	DET
eurjchem-604	869	2	tungsten	tungsten	NOUN
eurjchem-604	869	3	and	and	CCONJ
eurjchem-604	869	4	molybdenum	molybdenum	NOUN
eurjchem-604	869	5	hexacarbonyls	hexacarbonyls	PROPN
eurjchem-604	869	6	,	,	PUNCT
eurjchem-604	869	7	m(co)6	m(co)6	NUM
eurjchem-604	869	8	(	(	PUNCT
eurjchem-604	869	9	m	m	PROPN
eurjchem-604	869	10	=	=	SYM
eurjchem-604	869	11	w	w	PROPN
eurjchem-604	869	12	,	,	PUNCT
eurjchem-604	869	13	mo	mo	NOUN
eurjchem-604	869	14	)	)	PUNCT
eurjchem-604	869	15	,	,	PUNCT
eurjchem-604	869	16	dissolve	dissolve	VERB
eurjchem-604	869	17	in	in	ADP
eurjchem-604	869	18	fluorosulfonic	fluorosulfonic	ADJ
eurjchem-604	869	19	acid	acid	NOUN
eurjchem-604	869	20	,	,	PUNCT
eurjchem-604	869	21	hso3f	hso3f	NOUN
eurjchem-604	869	22	,	,	PUNCT
eurjchem-604	869	23	to	to	PART
eurjchem-604	869	24	generate	generate	VERB
eurjchem-604	869	25	the	the	DET
eurjchem-604	869	26	tungsten	tungsten	NOUN
eurjchem-604	869	27	and	and	CCONJ
eurjchem-604	869	28	molybdenum	molybdenum	NOUN
eurjchem-604	869	29	carbonyl	carbonyl	NOUN
eurjchem-604	869	30	cations	cation	NOUN
eurjchem-604	869	31	,	,	PUNCT
eurjchem-604	869	32	[	[	X
eurjchem-604	869	33	m(co)4]2+(solv	m(co)4]2+(solv	NOUN
eurjchem-604	869	34	)	)	PUNCT
eurjchem-604	869	35	,	,	PUNCT
eurjchem-604	869	36	which	which	PRON
eurjchem-604	869	37	are	be	AUX
eurjchem-604	869	38	transformed	transform	VERB
eurjchem-604	869	39	,	,	PUNCT
eurjchem-604	869	40	by	by	ADP
eurjchem-604	869	41	exposure	exposure	NOUN
eurjchem-604	869	42	to	to	ADP
eurjchem-604	869	43	an	an	DET
eurjchem-604	869	44	no	no	DET
eurjchem-604	869	45	atmosphere	atmosphere	NOUN
eurjchem-604	869	46	,	,	PUNCT
eurjchem-604	869	47	into	into	ADP
eurjchem-604	869	48	the	the	DET
eurjchem-604	869	49	tungsten	tungsten	NOUN
eurjchem-604	869	50	and	and	CCONJ
eurjchem-604	869	51	molybdenum	molybdenum	NOUN
eurjchem-604	869	52	carbonyldinitrosyl	carbonyldinitrosyl	NOUN
eurjchem-604	869	53	cations	cation	NOUN
eurjchem-604	869	54	,	,	PUNCT
eurjchem-604	869	55	[	[	X
eurjchem-604	869	56	m(co)(no)2]2+(solv	m(co)(no)2]2+(solv	X
eurjchem-604	869	57	)	)	PUNCT
eurjchem-604	869	58	,	,	PUNCT
eurjchem-604	869	59	respectively	respectively	ADV
eurjchem-604	869	60	(	(	PUNCT
eurjchem-604	869	61	scheme	scheme	NOUN
eurjchem-604	869	62	68	68	NUM
eurjchem-604	869	63	)	)	PUNCT
eurjchem-604	870	1	[	[	X
eurjchem-604	870	2	257	257	NUM
eurjchem-604	870	3	]	]	PUNCT
eurjchem-604	870	4	.	.	PUNCT
eurjchem-604	871	1	retracted	retract	VERB
eurjchem-604	871	2	388	388	NUM
eurjchem-604	871	3	kaushik	kaushik	PROPN
eurjchem-604	871	4	et	et	PROPN
eurjchem-604	871	5	al	al	PROPN
eurjchem-604	871	6	.	.	PUNCT
eurjchem-604	871	7	/	/	SYM
eurjchem-604	871	8	european	european	PROPN
eurjchem-604	871	9	journal	journal	PROPN
eurjchem-604	871	10	of	of	ADP
eurjchem-604	871	11	chemistry	chemistry	NOUN
eurjchem-604	871	12	3	3	NUM
eurjchem-604	871	13	(	(	PUNCT
eurjchem-604	871	14	3	3	NUM
eurjchem-604	871	15	)	)	PUNCT
eurjchem-604	871	16	(	(	PUNCT
eurjchem-604	871	17	2012	2012	NUM
eurjchem-604	871	18	)	)	PUNCT
eurjchem-604	871	19	367‐394	367‐394	NUM
eurjchem-604	871	20	scheme	scheme	NOUN
eurjchem-604	871	21	67	67	NUM
eurjchem-604	871	22	scheme	scheme	NOUN
eurjchem-604	871	23	68	68	NUM
eurjchem-604	871	24	mo(co)4(ll	mo(co)4(ll	NOUN
eurjchem-604	871	25	)	)	PUNCT
eurjchem-604	871	26	complexes	complex	NOUN
eurjchem-604	871	27	,	,	PUNCT
eurjchem-604	871	28	where	where	SCONJ
eurjchem-604	871	29	ll	ll	AUX
eurjchem-604	871	30	=	=	PRON
eurjchem-604	871	31	polypyridyl	polypyridyl	ADJ
eurjchem-604	871	32	ligands	ligand	NOUN
eurjchem-604	871	33	such	such	ADJ
eurjchem-604	871	34	as	as	ADP
eurjchem-604	871	35	2,2′‐bipyridine	2,2′‐bipyridine	NUM
eurjchem-604	871	36	and	and	CCONJ
eurjchem-604	871	37	1,10‐phenanthroline	1,10‐phenanthroline	NUM
eurjchem-604	871	38	,	,	PUNCT
eurjchem-604	871	39	undergo	undergo	VERB
eurjchem-604	871	40	quasi‐reversible	quasi‐reversible	ADJ
eurjchem-604	871	41	,	,	PUNCT
eurjchem-604	871	42	one‐electron	one‐electron	ADJ
eurjchem-604	871	43	oxidations	oxidation	NOUN
eurjchem-604	871	44	in	in	ADP
eurjchem-604	871	45	methylene	methylene	NOUN
eurjchem-604	871	46	chloride	chloride	NOUN
eurjchem-604	871	47	yielding	yield	VERB
eurjchem-604	871	48	the	the	DET
eurjchem-604	871	49	corresponding	corresponding	ADJ
eurjchem-604	871	50	radical	radical	ADJ
eurjchem-604	871	51	cations	cation	NOUN
eurjchem-604	871	52	,	,	PUNCT
eurjchem-604	871	53	[	[	X
eurjchem-604	871	54	mo(co)4(ll)]+	mo(co)4(ll)]+	X
eurjchem-604	871	55	(	(	PUNCT
eurjchem-604	871	56	figure	figure	NOUN
eurjchem-604	871	57	11	11	NUM
eurjchem-604	871	58	)	)	PUNCT
eurjchem-604	871	59	.	.	PUNCT
eurjchem-604	872	1	these	these	DET
eurjchem-604	872	2	electrogenerated	electrogenerate	VERB
eurjchem-604	872	3	species	specie	NOUN
eurjchem-604	872	4	undergo	undergo	VERB
eurjchem-604	872	5	rapid	rapid	ADJ
eurjchem-604	872	6	ligand	ligand	NOUN
eurjchem-604	872	7	substitution	substitution	NOUN
eurjchem-604	872	8	in	in	ADP
eurjchem-604	872	9	the	the	DET
eurjchem-604	872	10	presence	presence	NOUN
eurjchem-604	872	11	of	of	ADP
eurjchem-604	872	12	acetonitrile	acetonitrile	NOUN
eurjchem-604	872	13	,	,	PUNCT
eurjchem-604	872	14	yielding	yield	VERB
eurjchem-604	872	15	[	[	PUNCT
eurjchem-604	872	16	mo(co)3(ll)(ch3cn)]+	mo(co)3(ll)(ch3cn)]+	PROPN
eurjchem-604	873	1	[	[	X
eurjchem-604	873	2	258	258	NUM
eurjchem-604	873	3	]	]	PUNCT
eurjchem-604	873	4	.	.	PUNCT
eurjchem-604	874	1	figure	figure	NOUN
eurjchem-604	874	2	11	11	NUM
eurjchem-604	874	3	.	.	PUNCT
eurjchem-604	875	1	generation	generation	NOUN
eurjchem-604	875	2	of	of	ADP
eurjchem-604	875	3	metal	metal	NOUN
eurjchem-604	875	4	carbonyl	carbonyl	NOUN
eurjchem-604	875	5	cations	cation	NOUN
eurjchem-604	875	6	from	from	ADP
eurjchem-604	875	7	mo(co)4(ll	mo(co)4(ll	NOUN
eurjchem-604	875	8	)	)	PUNCT
eurjchem-604	875	9	complexes	complex	NOUN
eurjchem-604	875	10	,	,	PUNCT
eurjchem-604	875	11	where	where	SCONJ
eurjchem-604	875	12	ll	ll	AUX
eurjchem-604	875	13	=	=	NOUN
eurjchem-604	875	14	2,2′‐bipyridine	2,2′‐bipyridine	NUM
eurjchem-604	875	15	or1,10‐phenanthroline	or1,10‐phenanthroline	VERB
eurjchem-604	875	16	[	[	X
eurjchem-604	875	17	258	258	NUM
eurjchem-604	875	18	]	]	PUNCT
eurjchem-604	875	19	.	.	PUNCT
eurjchem-604	876	1	the	the	DET
eurjchem-604	876	2	cationic	cationic	ADJ
eurjchem-604	876	3	alkoxy	alkoxy	ADJ
eurjchem-604	876	4	and	and	CCONJ
eurjchem-604	876	5	hydroxycarbyne	hydroxycarbyne	NOUN
eurjchem-604	876	6	complexes	complex	NOUN
eurjchem-604	876	7	[	[	X
eurjchem-604	876	8	m2cp2(μ‐cor)(μ‐pr‘2)2]bf4	m2cp2(μ‐cor)(μ‐pr‘2)2]bf4	PROPN
eurjchem-604	876	9	(	(	PUNCT
eurjchem-604	876	10	cp	cp	INTJ
eurjchem-604	876	11	=	=	SYM
eurjchem-604	876	12	η5‐c5h5	η5‐c5h5	PROPN
eurjchem-604	876	13	;	;	PUNCT
eurjchem-604	876	14	m	m	VERB
eurjchem-604	876	15	=	=	SYM
eurjchem-604	876	16	w	w	PROPN
eurjchem-604	876	17	,	,	PUNCT
eurjchem-604	876	18	r	r	NOUN
eurjchem-604	876	19	=	=	PUNCT
eurjchem-604	876	20	me	me	PROPN
eurjchem-604	876	21	,	,	PUNCT
eurjchem-604	876	22	r	r	NOUN
eurjchem-604	876	23	‘	'	PUNCT
eurjchem-604	876	24	=	=	SYM
eurjchem-604	876	25	ph	ph	ADJ
eurjchem-604	876	26	;	;	PUNCT
eurjchem-604	876	27	m	m	PROPN
eurjchem-604	876	28	=	=	SYM
eurjchem-604	876	29	mo	mo	PROPN
eurjchem-604	876	30	,	,	PUNCT
eurjchem-604	876	31	r	r	NOUN
eurjchem-604	876	32	=	=	PUNCT
eurjchem-604	876	33	me	i	PRON
eurjchem-604	876	34	and	and	CCONJ
eurjchem-604	876	35	h	h	NOUN
eurjchem-604	876	36	,	,	PUNCT
eurjchem-604	876	37	r	r	NOUN
eurjchem-604	876	38	‘	'	PUNCT
eurjchem-604	876	39	=	=	NOUN
eurjchem-604	876	40	et	et	NOUN
eurjchem-604	876	41	)	)	PUNCT
eurjchem-604	876	42	and	and	CCONJ
eurjchem-604	876	43	[	[	X
eurjchem-604	876	44	mo2cp2(μ‐cor)(μ‐	mo2cp2(μ‐cor)(μ‐	NOUN
eurjchem-604	876	45	cor‘)(μ‐pcy2)]bf4	cor‘)(μ‐pcy2)]bf4	X
eurjchem-604	876	46	(	(	PUNCT
eurjchem-604	876	47	r	r	X
eurjchem-604	876	48	=	=	PUNCT
eurjchem-604	876	49	me	i	PRON
eurjchem-604	876	50	;	;	PUNCT
eurjchem-604	876	51	r	r	NOUN
eurjchem-604	876	52	‘	'	PUNCT
eurjchem-604	876	53	=	=	ADJ
eurjchem-604	876	54	h	h	NOUN
eurjchem-604	876	55	,	,	PUNCT
eurjchem-604	876	56	me	i	PRON
eurjchem-604	876	57	,	,	PUNCT
eurjchem-604	876	58	et	et	NOUN
eurjchem-604	876	59	)	)	PUNCT
eurjchem-604	876	60	are	be	AUX
eurjchem-604	876	61	obtained	obtain	VERB
eurjchem-604	876	62	in	in	ADP
eurjchem-604	876	63	high	high	ADJ
eurjchem-604	876	64	yield	yield	NOUN
eurjchem-604	876	65	by	by	ADP
eurjchem-604	876	66	the	the	DET
eurjchem-604	876	67	reaction	reaction	NOUN
eurjchem-604	876	68	of	of	ADP
eurjchem-604	876	69	the	the	DET
eurjchem-604	876	70	corresponding	corresponding	ADJ
eurjchem-604	876	71	neutral	neutral	ADJ
eurjchem-604	876	72	monocarbonyl	monocarbonyl	NOUN
eurjchem-604	876	73	precursors	precursor	NOUN
eurjchem-604	876	74	with	with	ADP
eurjchem-604	876	75	either	either	CCONJ
eurjchem-604	876	76	[	[	X
eurjchem-604	876	77	me3o]bf4	me3o]bf4	NOUN
eurjchem-604	876	78	or	or	CCONJ
eurjchem-604	876	79	hbf4·oet2	hbf4·oet2	NOUN
eurjchem-604	876	80	in	in	ADP
eurjchem-604	876	81	dichloromethane	dichloromethane	NOUN
eurjchem-604	876	82	[	[	X
eurjchem-604	876	83	253‐264	253‐264	NOUN
eurjchem-604	876	84	]	]	PUNCT
eurjchem-604	876	85	.	.	PUNCT
eurjchem-604	877	1	6.5	6.5	NUM
eurjchem-604	877	2	.	.	PUNCT
eurjchem-604	878	1	use	use	NOUN
eurjchem-604	878	2	of	of	ADP
eurjchem-604	878	3	metal	metal	NOUN
eurjchem-604	878	4	carbonyl	carbonyl	NOUN
eurjchem-604	878	5	complexes	complex	NOUN
eurjchem-604	878	6	to	to	PART
eurjchem-604	878	7	achieve	achieve	VERB
eurjchem-604	878	8	high	high	ADJ
eurjchem-604	878	9	enantioselectivity	enantioselectivity	NOUN
eurjchem-604	878	10	in	in	ADP
eurjchem-604	878	11	the	the	DET
eurjchem-604	878	12	asymmetric	asymmetric	ADJ
eurjchem-604	878	13	allylboration	allylboration	NOUN
eurjchem-604	878	14	of	of	ADP
eurjchem-604	878	15	unsaturated	unsaturated	ADJ
eurjchem-604	878	16	aldehydes	aldehyde	NOUN
eurjchem-604	878	17	the	the	DET
eurjchem-604	878	18	metal	metal	NOUN
eurjchem-604	878	19	carbonyl	carbonyl	NOUN
eurjchem-604	878	20	units	unit	NOUN
eurjchem-604	878	21	have	have	AUX
eurjchem-604	878	22	been	be	AUX
eurjchem-604	878	23	used	use	VERB
eurjchem-604	878	24	as	as	ADP
eurjchem-604	878	25	bulky	bulky	ADJ
eurjchem-604	878	26	substituents	substituent	NOUN
eurjchem-604	878	27	on	on	ADP
eurjchem-604	878	28	chiral	chiral	ADJ
eurjchem-604	878	29	substrates	substrate	NOUN
eurjchem-604	878	30	enabling	enable	VERB
eurjchem-604	878	31	the	the	DET
eurjchem-604	878	32	diastereoselectivity	diastereoselectivity	NOUN
eurjchem-604	878	33	of	of	ADP
eurjchem-604	878	34	c‐c	c‐c	NUM
eurjchem-604	878	35	bond	bond	NOUN
eurjchem-604	878	36	forming	form	VERB
eurjchem-604	878	37	reaction	reaction	NOUN
eurjchem-604	878	38	at	at	ADP
eurjchem-604	878	39	adjacent	adjacent	ADJ
eurjchem-604	878	40	positions	position	NOUN
eurjchem-604	878	41	to	to	PART
eurjchem-604	878	42	be	be	AUX
eurjchem-604	878	43	enhanced	enhance	VERB
eurjchem-604	878	44	[	[	PUNCT
eurjchem-604	878	45	265	265	NUM
eurjchem-604	878	46	]	]	PUNCT
eurjchem-604	878	47	.	.	PUNCT
eurjchem-604	879	1	the	the	DET
eurjchem-604	879	2	electronic	electronic	ADJ
eurjchem-604	879	3	and/or	and/or	CCONJ
eurjchem-604	879	4	steric	steric	ADJ
eurjchem-604	879	5	influence	influence	NOUN
eurjchem-604	879	6	of	of	ADP
eurjchem-604	879	7	the	the	DET
eurjchem-604	879	8	metal	metal	NOUN
eurjchem-604	879	9	on	on	ADP
eurjchem-604	879	10	the	the	DET
eurjchem-604	879	11	unsaturated	unsaturated	ADJ
eurjchem-604	879	12	organic	organic	ADJ
eurjchem-604	879	13	ligand	ligand	NOUN
eurjchem-604	879	14	is	be	AUX
eurjchem-604	879	15	of	of	ADP
eurjchem-604	879	16	course	course	NOUN
eurjchem-604	879	17	central	central	ADJ
eurjchem-604	879	18	to	to	ADP
eurjchem-604	879	19	the	the	DET
eurjchem-604	879	20	success	success	NOUN
eurjchem-604	879	21	of	of	ADP
eurjchem-604	879	22	these	these	PRON
eurjchem-604	879	23	and	and	CCONJ
eurjchem-604	879	24	many	many	ADJ
eurjchem-604	879	25	other	other	ADJ
eurjchem-604	879	26	applications	application	NOUN
eurjchem-604	879	27	.	.	PUNCT
eurjchem-604	880	1	william	william	PROPN
eurjchem-604	880	2	r	r	PROPN
eurjchem-604	880	3	roush	roush	PROPN
eurjchem-604	880	4	et	et	PROPN
eurjchem-604	880	5	al	al	PROPN
eurjchem-604	880	6	.	.	PROPN
eurjchem-604	881	1	report	report	NOUN
eurjchem-604	881	2	effect	effect	NOUN
eurjchem-604	881	3	of	of	ADP
eurjchem-604	881	4	metal	metal	NOUN
eurjchem-604	881	5	carbonyl	carbonyl	NOUN
eurjchem-604	881	6	complexes	complex	NOUN
eurjchem-604	881	7	,	,	PUNCT
eurjchem-604	881	8	specifically	specifically	ADV
eurjchem-604	881	9	the	the	DET
eurjchem-604	881	10	ability	ability	NOUN
eurjchem-604	881	11	of	of	ADP
eurjchem-604	881	12	such	such	ADJ
eurjchem-604	881	13	complexes	complex	NOUN
eurjchem-604	881	14	to	to	PART
eurjchem-604	881	15	enhance	enhance	VERB
eurjchem-604	881	16	the	the	DET
eurjchem-604	881	17	enantioselectivity	enantioselectivity	NOUN
eurjchem-604	881	18	of	of	ADP
eurjchem-604	881	19	the	the	DET
eurjchem-604	881	20	asymmetric	asymmetric	ADJ
eurjchem-604	881	21	allylborations	allylboration	NOUN
eurjchem-604	881	22	of	of	ADP
eurjchem-604	881	23	unsaturated	unsaturated	ADJ
eurjchem-604	881	24	(	(	PUNCT
eurjchem-604	881	25	aryl	aryl	NOUN
eurjchem-604	881	26	and	and	CCONJ
eurjchem-604	881	27	propargylic	propargylic	ADJ
eurjchem-604	881	28	)	)	PUNCT
eurjchem-604	881	29	aldehydes	aldehyde	NOUN
eurjchem-604	881	30	.	.	PUNCT
eurjchem-604	882	1	these	these	DET
eurjchem-604	882	2	reactions	reaction	NOUN
eurjchem-604	882	3	were	be	AUX
eurjchem-604	882	4	in	in	ADP
eurjchem-604	882	5	contrast	contrast	NOUN
eurjchem-604	882	6	to	to	ADP
eurjchem-604	882	7	the	the	DET
eurjchem-604	882	8	previously	previously	ADV
eurjchem-604	882	9	reported	report	VERB
eurjchem-604	882	10	examples	example	NOUN
eurjchem-604	882	11	in	in	ADP
eurjchem-604	882	12	which	which	PRON
eurjchem-604	882	13	the	the	DET
eurjchem-604	882	14	diastereoface	diastereoface	NOUN
eurjchem-604	882	15	selectivity	selectivity	NOUN
eurjchem-604	882	16	of	of	ADP
eurjchem-604	882	17	the	the	DET
eurjchem-604	882	18	metal	metal	NOUN
eurjchem-604	882	19	carbonyl	carbonyl	NOUN
eurjchem-604	882	20	containing	contain	VERB
eurjchem-604	882	21	chiral	chiral	ADJ
eurjchem-604	882	22	substrates	substrate	NOUN
eurjchem-604	882	23	that	that	PRON
eurjchem-604	882	24	is	be	AUX
eurjchem-604	882	25	enhanced	enhance	VERB
eurjchem-604	882	26	[	[	PUNCT
eurjchem-604	882	27	265‐	265‐	NUM
eurjchem-604	882	28	275	275	NUM
eurjchem-604	882	29	]	]	PUNCT
eurjchem-604	882	30	.	.	PUNCT
eurjchem-604	883	1	the	the	DET
eurjchem-604	883	2	reactions	reaction	NOUN
eurjchem-604	883	3	in	in	ADP
eurjchem-604	883	4	which	which	PRON
eurjchem-604	883	5	metal	metal	NOUN
eurjchem-604	883	6	carbonyl	carbonyl	NOUN
eurjchem-604	883	7	ligand	ligand	NOUN
eurjchem-604	883	8	of	of	ADP
eurjchem-604	883	9	achiral	achiral	ADJ
eurjchem-604	883	10	substrates	substrate	NOUN
eurjchem-604	883	11	lead	lead	VERB
eurjchem-604	883	12	to	to	ADP
eurjchem-604	883	13	enhancement	enhancement	NOUN
eurjchem-604	883	14	of	of	ADP
eurjchem-604	883	15	the	the	DET
eurjchem-604	883	16	enantiofacial	enantiofacial	ADJ
eurjchem-604	883	17	selectivity	selectivity	NOUN
eurjchem-604	883	18	of	of	ADP
eurjchem-604	883	19	a	a	DET
eurjchem-604	883	20	chiral	chiral	ADJ
eurjchem-604	883	21	reagent	reagent	NOUN
eurjchem-604	883	22	[	[	X
eurjchem-604	883	23	276‐278	276‐278	NUM
eurjchem-604	883	24	]	]	PUNCT
eurjchem-604	883	25	.	.	PUNCT
eurjchem-604	884	1	previous	previous	ADJ
eurjchem-604	884	2	studies	study	NOUN
eurjchem-604	884	3	have	have	AUX
eurjchem-604	884	4	established	establish	VERB
eurjchem-604	884	5	that	that	SCONJ
eurjchem-604	884	6	the	the	DET
eurjchem-604	884	7	asymmetric	asymmetric	ADJ
eurjchem-604	884	8	allylboration	allylboration	NOUN
eurjchem-604	884	9	of	of	ADP
eurjchem-604	884	10	aromatic	aromatic	ADJ
eurjchem-604	884	11	aldehydes	aldehyde	NOUN
eurjchem-604	884	12	like	like	ADP
eurjchem-604	884	13	benzaldehyde	benzaldehyde	NOUN
eurjchem-604	884	14	proceed	proceed	VERB
eurjchem-604	884	15	with	with	ADP
eurjchem-604	884	16	only	only	ADJ
eurjchem-604	884	17	moderate	moderate	ADJ
eurjchem-604	884	18	stereoselectivity	stereoselectivity	NOUN
eurjchem-604	884	19	of	of	ADP
eurjchem-604	884	20	55‐72	55‐72	NUM
eurjchem-604	884	21	%	%	NOUN
eurjchem-604	884	22	in	in	ADP
eurjchem-604	884	23	thf	thf	NOUN
eurjchem-604	884	24	.	.	PUNCT
eurjchem-604	885	1	the	the	DET
eurjchem-604	885	2	use	use	NOUN
eurjchem-604	885	3	of	of	ADP
eurjchem-604	885	4	benzaldehyde	benzaldehyde	NOUN
eurjchem-604	885	5	chromium	chromium	NOUN
eurjchem-604	885	6	tricarbonyl	tricarbonyl	NOUN
eurjchem-604	885	7	complex	complex	NOUN
eurjchem-604	885	8	as	as	ADP
eurjchem-604	885	9	a	a	DET
eurjchem-604	885	10	surrogate	surrogate	NOUN
eurjchem-604	885	11	for	for	ADP
eurjchem-604	885	12	c6h5cho	c6h5cho	NOUN
eurjchem-604	885	13	[	[	X
eurjchem-604	885	14	279	279	NUM
eurjchem-604	885	15	]	]	X
eurjchem-604	885	16	,	,	PUNCT
eurjchem-604	885	17	in	in	ADP
eurjchem-604	885	18	the	the	DET
eurjchem-604	885	19	asymmetric	asymmetric	ADJ
eurjchem-604	885	20	allylboration	allylboration	NOUN
eurjchem-604	885	21	with	with	ADP
eurjchem-604	885	22	(	(	PUNCT
eurjchem-604	885	23	r	r	NOUN
eurjchem-604	885	24	,	,	PUNCT
eurjchem-604	885	25	r)‐1	r)‐1	NOUN
eurjchem-604	885	26	in	in	ADP
eurjchem-604	885	27	toluene	toluene	NOUN
eurjchem-604	885	28	at	at	ADP
eurjchem-604	885	29	‐78	‐78	ADJ
eurjchem-604	885	30	oc	oc	NOUN
eurjchem-604	885	31	followed	follow	VERB
eurjchem-604	885	32	by	by	ADP
eurjchem-604	885	33	oxidative	oxidative	ADJ
eurjchem-604	885	34	decomposition	decomposition	NOUN
eurjchem-604	885	35	provide	provide	NOUN
eurjchem-604	885	36	(	(	PUNCT
eurjchem-604	885	37	s	s	X
eurjchem-604	885	38	)	)	PUNCT
eurjchem-604	885	39	in	in	ADP
eurjchem-604	885	40	greater	great	ADJ
eurjchem-604	885	41	than	than	ADP
eurjchem-604	885	42	90	90	NUM
eurjchem-604	885	43	%	%	NOUN
eurjchem-604	885	44	yield	yield	NOUN
eurjchem-604	885	45	.	.	PUNCT
eurjchem-604	886	1	the	the	DET
eurjchem-604	886	2	(	(	PUNCT
eurjchem-604	886	3	e)‐crotylboration	e)‐crotylboration	NOUN
eurjchem-604	886	4	of	of	ADP
eurjchem-604	886	5	chromium	chromium	NOUN
eurjchem-604	886	6	tricarbonyl	tricarbonyl	NOUN
eurjchem-604	886	7	complex	complex	NOUN
eurjchem-604	886	8	with	with	ADP
eurjchem-604	886	9	(	(	PUNCT
eurjchem-604	886	10	r	r	NOUN
eurjchem-604	886	11	,	,	PUNCT
eurjchem-604	886	12	r	r	NOUN
eurjchem-604	886	13	)	)	PUNCT
eurjchem-604	886	14	was	be	AUX
eurjchem-604	886	15	also	also	ADV
eurjchem-604	886	16	provide	provide	VERB
eurjchem-604	886	17	92	92	NUM
eurjchem-604	886	18	%	%	NOUN
eurjchem-604	886	19	yield	yield	NOUN
eurjchem-604	886	20	[	[	X
eurjchem-604	886	21	280	280	NUM
eurjchem-604	886	22	]	]	PUNCT
eurjchem-604	886	23	.	.	PUNCT
eurjchem-604	887	1	6.6	6.6	NUM
eurjchem-604	887	2	.	.	PUNCT
eurjchem-604	888	1	in	in	ADP
eurjchem-604	888	2	preparation	preparation	NOUN
eurjchem-604	888	3	of	of	ADP
eurjchem-604	888	4	catalysts	catalyst	NOUN
eurjchem-604	888	5	cp*mo(pme3)3h	cp*mo(pme3)3h	NOUN
eurjchem-604	888	6	undergoes	undergoe	NOUN
eurjchem-604	888	7	carbonyl	carbonyl	NOUN
eurjchem-604	888	8	abstraction	abstraction	NOUN
eurjchem-604	888	9	reactions	reaction	NOUN
eurjchem-604	888	10	with	with	ADP
eurjchem-604	888	11	a	a	DET
eurjchem-604	888	12	variety	variety	NOUN
eurjchem-604	888	13	of	of	ADP
eurjchem-604	888	14	reagents	reagent	NOUN
eurjchem-604	888	15	,	,	PUNCT
eurjchem-604	888	16	including	include	VERB
eurjchem-604	888	17	co2	co2	NOUN
eurjchem-604	888	18	,	,	PUNCT
eurjchem-604	888	19	(	(	PUNCT
eurjchem-604	888	20	ch2o)n	ch2o)n	NOUN
eurjchem-604	888	21	,	,	PUNCT
eurjchem-604	888	22	hco2h	hco2h	PROPN
eurjchem-604	888	23	,	,	PUNCT
eurjchem-604	888	24	and	and	CCONJ
eurjchem-604	888	25	meoh	meoh	NOUN
eurjchem-604	888	26	to	to	PART
eurjchem-604	888	27	yield	yield	VERB
eurjchem-604	888	28	cp*mo(pme3)2(co)h	cp*mo(pme3)2(co)h	PROPN
eurjchem-604	888	29	.	.	PUNCT
eurjchem-604	889	1	the	the	DET
eurjchem-604	889	2	cp*mo(pme3)2(co)h	cp*mo(pme3)2(co)h	PROPN
eurjchem-604	889	3	serves	serve	VERB
eurjchem-604	889	4	as	as	ADP
eurjchem-604	889	5	a	a	DET
eurjchem-604	889	6	catalyst	catalyst	NOUN
eurjchem-604	889	7	for	for	ADP
eurjchem-604	889	8	the	the	DET
eurjchem-604	889	9	decomposition	decomposition	NOUN
eurjchem-604	889	10	of	of	ADP
eurjchem-604	889	11	hco2h	hco2h	PROPN
eurjchem-604	889	12	to	to	PART
eurjchem-604	889	13	co2	co2	NOUN
eurjchem-604	889	14	and	and	CCONJ
eurjchem-604	889	15	h2	h2	NOUN
eurjchem-604	889	16	.	.	PUNCT
eurjchem-604	890	1	[	[	X
eurjchem-604	890	2	260	260	NUM
eurjchem-604	890	3	]	]	X
eurjchem-604	890	4	preparation	preparation	NOUN
eurjchem-604	890	5	of	of	ADP
eurjchem-604	890	6	alumina	alumina	NOUN
eurjchem-604	890	7	supported	support	VERB
eurjchem-604	890	8	pd‐w	pd‐w	PROPN
eurjchem-604	890	9	and	and	CCONJ
eurjchem-604	890	10	pd‐mo	pd‐mo	DET
eurjchem-604	890	11	catalysts	catalyst	NOUN
eurjchem-604	890	12	was	be	AUX
eurjchem-604	890	13	done	do	VERB
eurjchem-604	890	14	photolytically	photolytically	ADV
eurjchem-604	890	15	from	from	ADP
eurjchem-604	890	16	group	group	NOUN
eurjchem-604	890	17	vi	vi	PROPN
eurjchem-604	890	18	metal	metal	NOUN
eurjchem-604	890	19	carbonyls	carbonyls	NOUN
eurjchem-604	890	20	.	.	PUNCT
eurjchem-604	891	1	tungsten	tungsten	NOUN
eurjchem-604	891	2	and	and	CCONJ
eurjchem-604	891	3	molybdenum	molybdenum	NOUN
eurjchem-604	891	4	were	be	AUX
eurjchem-604	891	5	introduced	introduce	VERB
eurjchem-604	891	6	in	in	ADP
eurjchem-604	891	7	γ‐	γ‐	ADJ
eurjchem-604	891	8	al2o3	al2o3	PROPN
eurjchem-604	891	9	and	and	CCONJ
eurjchem-604	891	10	pd	pd	PROPN
eurjchem-604	891	11	/	/	SYM
eurjchem-604	891	12	γ‐al2o3	γ‐al2o3	ADV
eurjchem-604	891	13	using	use	VERB
eurjchem-604	891	14	metalcarbonyls	metalcarbonyls	NOUN
eurjchem-604	891	15	[	[	X
eurjchem-604	891	16	w(co)6	w(co)6	PROPN
eurjchem-604	891	17	and	and	CCONJ
eurjchem-604	891	18	mo(co)6	mo(co)6	X
eurjchem-604	891	19	]	]	PUNCT
eurjchem-604	891	20	photoactivation	photoactivation	NOUN
eurjchem-604	891	21	.	.	PUNCT
eurjchem-604	892	1	the	the	DET
eurjchem-604	892	2	results	result	NOUN
eurjchem-604	892	3	showed	show	VERB
eurjchem-604	892	4	that	that	SCONJ
eurjchem-604	892	5	a	a	DET
eurjchem-604	892	6	reaction	reaction	NOUN
eurjchem-604	892	7	between	between	ADP
eurjchem-604	892	8	the	the	DET
eurjchem-604	892	9	hexacarbonyls	hexacarbonyls	PROPN
eurjchem-604	892	10	and	and	CCONJ
eurjchem-604	892	11	the	the	DET
eurjchem-604	892	12	supported	support	VERB
eurjchem-604	892	13	palladium	palladium	NOUN
eurjchem-604	892	14	particles	particle	NOUN
eurjchem-604	892	15	takes	take	VERB
eurjchem-604	892	16	place	place	NOUN
eurjchem-604	892	17	leading	lead	VERB
eurjchem-604	892	18	to	to	ADP
eurjchem-604	892	19	bimetallic	bimetallic	ADJ
eurjchem-604	892	20	catalysts	catalyst	NOUN
eurjchem-604	892	21	,	,	PUNCT
eurjchem-604	892	22	with	with	ADP
eurjchem-604	892	23	clear	clear	ADJ
eurjchem-604	892	24	palladium‐tungsten	palladium‐tungsten	ADJ
eurjchem-604	892	25	and	and	CCONJ
eurjchem-604	892	26	palladium‐molybdenum	palladium‐molybdenum	ADJ
eurjchem-604	892	27	interactions	interaction	NOUN
eurjchem-604	892	28	(	(	PUNCT
eurjchem-604	892	29	scheme	scheme	NOUN
eurjchem-604	892	30	69	69	NUM
eurjchem-604	892	31	)	)	PUNCT
eurjchem-604	892	32	.	.	PUNCT
eurjchem-604	893	1	scheme	scheme	NOUN
eurjchem-604	893	2	69	69	NUM
eurjchem-604	893	3	both	both	DET
eurjchem-604	893	4	group	group	NOUN
eurjchem-604	893	5	vi	vi	NOUN
eurjchem-604	893	6	metals	metal	NOUN
eurjchem-604	893	7	strongly	strongly	ADV
eurjchem-604	893	8	modify	modify	VERB
eurjchem-604	893	9	the	the	DET
eurjchem-604	893	10	chemisorption	chemisorption	NOUN
eurjchem-604	893	11	properties	property	NOUN
eurjchem-604	893	12	of	of	ADP
eurjchem-604	893	13	palladium	palladium	NOUN
eurjchem-604	893	14	,	,	PUNCT
eurjchem-604	893	15	while	while	SCONJ
eurjchem-604	893	16	molybdenum	molybdenum	NOUN
eurjchem-604	893	17	seems	seem	VERB
eurjchem-604	893	18	to	to	PART
eurjchem-604	893	19	be	be	AUX
eurjchem-604	893	20	present	present	ADJ
eurjchem-604	893	21	in	in	ADP
eurjchem-604	893	22	a	a	DET
eurjchem-604	893	23	reduced	reduced	ADJ
eurjchem-604	893	24	state	state	NOUN
eurjchem-604	893	25	in	in	ADP
eurjchem-604	893	26	close	close	ADJ
eurjchem-604	893	27	association	association	NOUN
eurjchem-604	893	28	with	with	ADP
eurjchem-604	893	29	palladium	palladium	NOUN
eurjchem-604	894	1	[	[	X
eurjchem-604	894	2	281	281	NUM
eurjchem-604	894	3	]	]	PUNCT
eurjchem-604	894	4	.	.	PUNCT
eurjchem-604	895	1	molybdenum	molybdenum	NOUN
eurjchem-604	895	2	carbonyl	carbonyl	NOUN
eurjchem-604	895	3	complexes	complex	NOUN
eurjchem-604	895	4	immobilized	immobilize	VERB
eurjchem-604	895	5	onto	onto	ADP
eurjchem-604	895	6	polymer‐bound	polymer‐bound	NOUN
eurjchem-604	895	7	phosphines	phosphine	NOUN
eurjchem-604	895	8	were	be	AUX
eurjchem-604	895	9	easily	easily	ADV
eurjchem-604	895	10	prepared	prepare	VERB
eurjchem-604	895	11	in	in	ADP
eurjchem-604	895	12	two	two	NUM
eurjchem-604	895	13	steps	step	NOUN
eurjchem-604	895	14	from	from	ADP
eurjchem-604	895	15	commercially	commercially	ADV
eurjchem-604	895	16	available	available	ADJ
eurjchem-604	895	17	chloromethylated	chloromethylate	VERB
eurjchem-604	895	18	polystyrene	polystyrene	NOUN
eurjchem-604	895	19	resin	resin	NOUN
eurjchem-604	895	20	.	.	PUNCT
eurjchem-604	896	1	these	these	DET
eurjchem-604	896	2	catalysts	catalyst	NOUN
eurjchem-604	896	3	were	be	AUX
eurjchem-604	896	4	found	find	VERB
eurjchem-604	896	5	to	to	PART
eurjchem-604	896	6	efficiently	efficiently	ADV
eurjchem-604	896	7	catalyze	catalyze	VERB
eurjchem-604	896	8	epoxidation	epoxidation	NOUN
eurjchem-604	896	9	of	of	ADP
eurjchem-604	896	10	a	a	DET
eurjchem-604	896	11	wide	wide	ADJ
eurjchem-604	896	12	variety	variety	NOUN
eurjchem-604	896	13	of	of	ADP
eurjchem-604	896	14	alkenes	alkene	NOUN
eurjchem-604	896	15	,	,	PUNCT
eurjchem-604	896	16	including	include	VERB
eurjchem-604	896	17	aromatic	aromatic	ADJ
eurjchem-604	896	18	and	and	CCONJ
eurjchem-604	896	19	aliphatic	aliphatic	ADJ
eurjchem-604	896	20	terminal	terminal	ADJ
eurjchem-604	896	21	alkenes	alkene	NOUN
eurjchem-604	896	22	using	use	VERB
eurjchem-604	896	23	tert‐butylhydroperoxide	tert‐butylhydroperoxide	ADV
eurjchem-604	896	24	(	(	PUNCT
eurjchem-604	896	25	scheme	scheme	NOUN
eurjchem-604	896	26	70	70	NUM
eurjchem-604	896	27	)	)	PUNCT
eurjchem-604	896	28	.	.	PUNCT
eurjchem-604	897	1	the	the	DET
eurjchem-604	897	2	new	new	ADJ
eurjchem-604	897	3	heterogenized	heterogenize	VERB
eurjchem-604	897	4	molybdenum	molybdenum	NOUN
eurjchem-604	897	5	carbonyl	carbonyl	NOUN
eurjchem-604	897	6	epoxidation	epoxidation	NOUN
eurjchem-604	897	7	catalysts	catalyst	NOUN
eurjchem-604	897	8	can	can	AUX
eurjchem-604	897	9	be	be	AUX
eurjchem-604	897	10	easily	easily	ADV
eurjchem-604	897	11	recovered	recover	VERB
eurjchem-604	897	12	by	by	ADP
eurjchem-604	897	13	simple	simple	ADJ
eurjchem-604	897	14	filtration	filtration	NOUN
eurjchem-604	897	15	and	and	CCONJ
eurjchem-604	897	16	show	show	VERB
eurjchem-604	897	17	no	no	DET
eurjchem-604	897	18	appreciable	appreciable	ADJ
eurjchem-604	897	19	loss	loss	NOUN
eurjchem-604	897	20	of	of	ADP
eurjchem-604	897	21	activity	activity	NOUN
eurjchem-604	897	22	even	even	ADV
eurjchem-604	897	23	after	after	ADP
eurjchem-604	897	24	10	10	NUM
eurjchem-604	897	25	times	time	NOUN
eurjchem-604	897	26	of	of	ADP
eurjchem-604	897	27	recycling	recycling	NOUN
eurjchem-604	897	28	.	.	PUNCT
eurjchem-604	898	1	hence	hence	ADV
eurjchem-604	898	2	they	they	PRON
eurjchem-604	898	3	show	show	VERB
eurjchem-604	898	4	a	a	DET
eurjchem-604	898	5	new	new	ADJ
eurjchem-604	898	6	class	class	NOUN
eurjchem-604	898	7	of	of	ADP
eurjchem-604	898	8	novel	novel	NOUN
eurjchem-604	898	9	reusable	reusable	ADJ
eurjchem-604	898	10	and	and	CCONJ
eurjchem-604	898	11	highly	highly	ADV
eurjchem-604	898	12	active	active	ADJ
eurjchem-604	898	13	epoxidation	epoxidation	NOUN
eurjchem-604	898	14	catalysts	catalyst	NOUN
eurjchem-604	898	15	[	[	X
eurjchem-604	898	16	282	282	NUM
eurjchem-604	898	17	]	]	PUNCT
eurjchem-604	898	18	.	.	PUNCT
eurjchem-604	899	1	scheme	scheme	PROPN
eurjchem-604	899	2	70	70	NUM
eurjchem-604	899	3	retracted	retract	VERB
eurjchem-604	899	4	kaushik	kaushik	PROPN
eurjchem-604	899	5	et	et	PROPN
eurjchem-604	899	6	al	al	PROPN
eurjchem-604	899	7	.	.	PUNCT
eurjchem-604	899	8	/	/	SYM
eurjchem-604	899	9	european	european	PROPN
eurjchem-604	899	10	journal	journal	PROPN
eurjchem-604	899	11	of	of	ADP
eurjchem-604	899	12	chemistry	chemistry	NOUN
eurjchem-604	899	13	3	3	NUM
eurjchem-604	899	14	(	(	PUNCT
eurjchem-604	899	15	3	3	NUM
eurjchem-604	899	16	)	)	PUNCT
eurjchem-604	899	17	(	(	PUNCT
eurjchem-604	899	18	2012	2012	NUM
eurjchem-604	899	19	)	)	PUNCT
eurjchem-604	899	20	367‐394	367‐394	NOUN
eurjchem-604	899	21	389	389	NUM
eurjchem-604	899	22	polymer‐bound	polymer‐bound	NOUN
eurjchem-604	899	23	schiff	schiff	NOUN
eurjchem-604	899	24	base	base	NOUN
eurjchem-604	899	25	ligandwas	ligandwa	VERB
eurjchem-604	899	26	prepared	prepare	VERB
eurjchem-604	899	27	by	by	ADP
eurjchem-604	899	28	oxidation	oxidation	NOUN
eurjchem-604	899	29	of	of	ADP
eurjchem-604	899	30	chloromethylated	chloromethylate	VERB
eurjchem-604	899	31	polystyrene	polystyrene	NOUN
eurjchem-604	899	32	to	to	ADP
eurjchem-604	899	33	aldehydic	aldehydic	ADJ
eurjchem-604	899	34	polystyreneand	polystyreneand	NOUN
eurjchem-604	899	35	then	then	ADV
eurjchem-604	899	36	reaction	reaction	NOUN
eurjchem-604	899	37	with	with	ADP
eurjchem-604	899	38	ethylene	ethylene	NOUN
eurjchem-604	899	39	diamine	diamine	NOUN
eurjchem-604	899	40	.	.	PUNCT
eurjchem-604	900	1	the	the	DET
eurjchem-604	900	2	functionalized	functionalized	ADJ
eurjchem-604	900	3	polystyrene	polystyrene	NOUN
eurjchem-604	900	4	was	be	AUX
eurjchem-604	900	5	used	use	VERB
eurjchem-604	900	6	to	to	PART
eurjchem-604	900	7	immobilize	immobilize	VERB
eurjchem-604	900	8	mo(co)6	mo(co)6	PROPN
eurjchem-604	900	9	and	and	CCONJ
eurjchem-604	900	10	polymer‐bound	polymer‐bound	NOUN
eurjchem-604	900	11	molybdenum	molybdenum	NOUN
eurjchem-604	900	12	carbonyl	carbonyl	NOUN
eurjchem-604	900	13	schiff	schiff	NOUN
eurjchem-604	900	14	base	base	NOUN
eurjchem-604	900	15	catalystwas	catalystwas	PROPN
eurjchem-604	900	16	produced	produce	VERB
eurjchem-604	900	17	.	.	PUNCT
eurjchem-604	901	1	this	this	DET
eurjchem-604	901	2	supported	support	VERB
eurjchem-604	901	3	catalyst	catalyst	NOUN
eurjchem-604	901	4	shows	show	VERB
eurjchem-604	901	5	high	high	ADJ
eurjchem-604	901	6	activity	activity	NOUN
eurjchem-604	901	7	in	in	ADP
eurjchem-604	901	8	epoxidation	epoxidation	NOUN
eurjchem-604	901	9	of	of	ADP
eurjchem-604	901	10	various	various	ADJ
eurjchem-604	901	11	alkenes	alkene	NOUN
eurjchem-604	901	12	in	in	ADP
eurjchem-604	901	13	the	the	DET
eurjchem-604	901	14	presence	presence	NOUN
eurjchem-604	901	15	of	of	ADP
eurjchem-604	901	16	tert‐butylhydroperoxide	tert‐butylhydroperoxide	ADV
eurjchem-604	901	17	(	(	PUNCT
eurjchem-604	901	18	scheme	scheme	NOUN
eurjchem-604	901	19	71	71	NUM
eurjchem-604	901	20	)	)	PUNCT
eurjchem-604	901	21	.	.	PUNCT
eurjchem-604	902	1	the	the	DET
eurjchem-604	902	2	supported	support	VERB
eurjchem-604	902	3	molybdenum	molybdenum	NOUN
eurjchem-604	902	4	catalyst	catalyst	NOUN
eurjchem-604	902	5	can	can	AUX
eurjchem-604	902	6	be	be	AUX
eurjchem-604	902	7	recovered	recover	VERB
eurjchem-604	902	8	and	and	CCONJ
eurjchem-604	902	9	reused	reuse	VERB
eurjchem-604	902	10	for	for	ADP
eurjchem-604	902	11	eight	eight	NUM
eurjchem-604	902	12	times	time	NOUN
eurjchem-604	902	13	without	without	ADP
eurjchem-604	902	14	loss	loss	NOUN
eurjchem-604	902	15	in	in	ADP
eurjchem-604	902	16	its	its	PRON
eurjchem-604	902	17	activity	activity	NOUN
eurjchem-604	902	18	[	[	X
eurjchem-604	902	19	283	283	NUM
eurjchem-604	902	20	]	]	PUNCT
eurjchem-604	902	21	.	.	PUNCT
eurjchem-604	903	1	scheme	scheme	NOUN
eurjchem-604	903	2	71	71	NUM
eurjchem-604	903	3	7	7	NUM
eurjchem-604	903	4	.	.	PUNCT
eurjchem-604	904	1	studies	study	NOUN
eurjchem-604	904	2	done	do	VERB
eurjchem-604	904	3	on	on	ADP
eurjchem-604	904	4	metal	metal	NOUN
eurjchem-604	904	5	carbonyl	carbonyl	NOUN
eurjchem-604	904	6	complexes	complex	NOUN
eurjchem-604	904	7	kinetics	kinetic	NOUN
eurjchem-604	904	8	and	and	CCONJ
eurjchem-604	904	9	mechanism	mechanism	NOUN
eurjchem-604	904	10	of	of	ADP
eurjchem-604	904	11	co	co	NOUN
eurjchem-604	904	12	substitution	substitution	NOUN
eurjchem-604	904	13	reaction	reaction	NOUN
eurjchem-604	904	14	of	of	ADP
eurjchem-604	904	15	m(co)6	m(co)6	PROPN
eurjchem-604	904	16	(	(	PUNCT
eurjchem-604	904	17	m=	m=	X
eurjchem-604	904	18	cr	cr	PROPN
eurjchem-604	904	19	,	,	PUNCT
eurjchem-604	904	20	mo	mo	PROPN
eurjchem-604	904	21	,	,	PUNCT
eurjchem-604	904	22	w	w	PROPN
eurjchem-604	904	23	)	)	PUNCT
eurjchem-604	904	24	with	with	ADP
eurjchem-604	904	25	(	(	PUNCT
eurjchem-604	904	26	ch3)3no	ch3)3no	PROPN
eurjchem-604	904	27	in	in	ADP
eurjchem-604	904	28	the	the	DET
eurjchem-604	904	29	absence	absence	NOUN
eurjchem-604	904	30	and	and	CCONJ
eurjchem-604	904	31	presence	presence	NOUN
eurjchem-604	904	32	of	of	ADP
eurjchem-604	904	33	triphenyl	triphenyl	ADJ
eurjchem-604	904	34	phosphine	phosphine	NOUN
eurjchem-604	904	35	pph3	pph3	NOUN
eurjchem-604	904	36	were	be	AUX
eurjchem-604	904	37	incestigated	incestigate	VERB
eurjchem-604	904	38	.	.	PUNCT
eurjchem-604	905	1	the	the	DET
eurjchem-604	905	2	rates	rate	NOUN
eurjchem-604	905	3	of	of	ADP
eurjchem-604	905	4	reaction	reaction	NOUN
eurjchem-604	905	5	are	be	AUX
eurjchem-604	905	6	first‐order	first‐order	NOUN
eurjchem-604	905	7	in	in	ADP
eurjchem-604	905	8	concentrations	concentration	NOUN
eurjchem-604	905	9	of	of	ADP
eurjchem-604	905	10	m(co)6	m(co)6	NOUN
eurjchem-604	905	11	and	and	CCONJ
eurjchem-604	905	12	of	of	ADP
eurjchem-604	905	13	(	(	PUNCT
eurjchem-604	905	14	ch3)3no	ch3)3no	PROPN
eurjchem-604	905	15	but	but	CCONJ
eurjchem-604	905	16	zero‐order	zero‐order	VERB
eurjchem-604	905	17	in	in	ADP
eurjchem-604	905	18	pph3	pph3	NOUN
eurjchem-604	905	19	concentration	concentration	NOUN
eurjchem-604	905	20	.	.	PUNCT
eurjchem-604	906	1	the	the	DET
eurjchem-604	906	2	rate	rate	NOUN
eurjchem-604	906	3	of	of	ADP
eurjchem-604	906	4	reaction	reaction	NOUN
eurjchem-604	906	5	decrease	decrease	NOUN
eurjchem-604	906	6	in	in	ADP
eurjchem-604	906	7	the	the	DET
eurjchem-604	906	8	order	order	NOUN
eurjchem-604	906	9	w	w	X
eurjchem-604	906	10	>	>	X
eurjchem-604	906	11	mo≈cr	mo≈cr	NOUN
eurjchem-604	906	12	.	.	PUNCT
eurjchem-604	907	1	the	the	DET
eurjchem-604	907	2	mechanism	mechanism	NOUN
eurjchem-604	907	3	was	be	AUX
eurjchem-604	907	4	suggested	suggest	VERB
eurjchem-604	907	5	with	with	ADP
eurjchem-604	907	6	the	the	DET
eurjchem-604	907	7	formation	formation	NOUN
eurjchem-604	907	8	of	of	ADP
eurjchem-604	907	9	coordinatively	coordinatively	ADV
eurjchem-604	907	10	unsaturated	unsaturated	ADJ
eurjchem-604	907	11	intermediates	intermediate	NOUN
eurjchem-604	907	12	of	of	ADP
eurjchem-604	907	13	the	the	DET
eurjchem-604	907	14	type	type	NOUN
eurjchem-604	907	15	m(co)5	m(co)5	PROPN
eurjchem-604	907	16	,	,	PUNCT
eurjchem-604	907	17	which	which	PRON
eurjchem-604	907	18	then	then	ADV
eurjchem-604	907	19	rapidly	rapidly	ADV
eurjchem-604	907	20	react	react	VERB
eurjchem-604	907	21	with	with	ADP
eurjchem-604	907	22	an	an	DET
eurjchem-604	907	23	entering	enter	VERB
eurjchem-604	907	24	ligand	ligand	NOUN
eurjchem-604	907	25	[	[	X
eurjchem-604	907	26	284	284	NUM
eurjchem-604	907	27	]	]	PUNCT
eurjchem-604	907	28	.	.	PUNCT
eurjchem-604	908	1	thermally	thermally	ADV
eurjchem-604	908	2	activated	activate	VERB
eurjchem-604	908	3	ligand‐dissociation	ligand‐dissociation	NOUN
eurjchem-604	908	4	processes	process	NOUN
eurjchem-604	908	5	in	in	ADP
eurjchem-604	908	6	substituted	substitute	VERB
eurjchem-604	908	7	group	group	NOUN
eurjchem-604	908	8	6b	6b	NOUN
eurjchem-604	908	9	metal	metal	NOUN
eurjchem-604	908	10	carbonyl	carbonyl	NOUN
eurjchem-604	908	11	derivatives	derivative	NOUN
eurjchem-604	908	12	involving	involve	VERB
eurjchem-604	908	13	the	the	DET
eurjchem-604	908	14	tightly	tightly	ADV
eurjchem-604	908	15	bound	bind	VERB
eurjchem-604	908	16	,	,	PUNCT
eurjchem-604	908	17	ubiquitous	ubiquitous	ADJ
eurjchem-604	908	18	phosphine	phosphine	NOUN
eurjchem-604	908	19	or	or	CCONJ
eurjchem-604	908	20	phosphate	phosphate	ADJ
eurjchem-604	908	21	ligands	ligand	NOUN
eurjchem-604	908	22	have	have	AUX
eurjchem-604	908	23	rarely	rarely	ADV
eurjchem-604	908	24	been	be	AUX
eurjchem-604	908	25	studied	study	VERB
eurjchem-604	908	26	quantitatively	quantitatively	ADV
eurjchem-604	908	27	.	.	PUNCT
eurjchem-604	909	1	kinetic	kinetic	ADJ
eurjchem-604	909	2	and	and	CCONJ
eurjchem-604	909	3	mechanistic	mechanistic	ADJ
eurjchem-604	909	4	studies	study	NOUN
eurjchem-604	909	5	of	of	ADP
eurjchem-604	909	6	cis‐mo(co)2l2	cis‐mo(co)2l2	PROPN
eurjchem-604	909	7	derivatieves	derivatieve	VERB
eurjchem-604	909	8	(	(	PUNCT
eurjchem-604	909	9	l	l	NOUN
eurjchem-604	909	10	=	=	SYM
eurjchem-604	909	11	phosphine	phosphine	NOUN
eurjchem-604	909	12	or	or	CCONJ
eurjchem-604	909	13	phosphate	phosphate	NOUN
eurjchem-604	909	14	)	)	PUNCT
eurjchem-604	909	15	are	be	AUX
eurjchem-604	909	16	presented	present	VERB
eurjchem-604	909	17	for	for	ADP
eurjchem-604	909	18	the	the	DET
eurjchem-604	909	19	substitution	substitution	NOUN
eurjchem-604	909	20	reaction	reaction	NOUN
eurjchem-604	909	21	of	of	ADP
eurjchem-604	909	22	one	one	NUM
eurjchem-604	909	23	of	of	ADP
eurjchem-604	909	24	the	the	DET
eurjchem-604	909	25	ligands	ligand	NOUN
eurjchem-604	909	26	(	(	PUNCT
eurjchem-604	909	27	l	l	NOUN
eurjchem-604	909	28	)	)	PUNCT
eurjchem-604	909	29	by	by	ADP
eurjchem-604	909	30	carbon	carbon	NOUN
eurjchem-604	909	31	monoxide	monoxide	NOUN
eurjchem-604	909	32	.	.	PUNCT
eurjchem-604	910	1	these	these	DET
eurjchem-604	910	2	processes	process	NOUN
eurjchem-604	910	3	were	be	AUX
eurjchem-604	910	4	observed	observe	VERB
eurjchem-604	910	5	to	to	PART
eurjchem-604	910	6	proceed	proceed	VERB
eurjchem-604	910	7	by	by	ADP
eurjchem-604	910	8	a	a	DET
eurjchem-604	910	9	dissociative	dissociative	ADJ
eurjchem-604	910	10	mechanism	mechanism	NOUN
eurjchem-604	910	11	with	with	ADP
eurjchem-604	910	12	the	the	DET
eurjchem-604	910	13	rate	rate	NOUN
eurjchem-604	910	14	of	of	ADP
eurjchem-604	910	15	substitution	substitution	NOUN
eurjchem-604	910	16	being	be	AUX
eurjchem-604	910	17	greatly	greatly	ADV
eurjchem-604	910	18	enhanced	enhance	VERB
eurjchem-604	910	19	as	as	ADP
eurjchem-604	910	20	the	the	DET
eurjchem-604	910	21	size	size	NOUN
eurjchem-604	910	22	of	of	ADP
eurjchem-604	910	23	the	the	DET
eurjchem-604	910	24	phosphorus	phosphorus	NOUN
eurjchem-604	910	25	ligand	ligand	NOUN
eurjchem-604	910	26	increases	increase	NOUN
eurjchem-604	910	27	within	within	ADP
eurjchem-604	910	28	a	a	DET
eurjchem-604	910	29	series	series	NOUN
eurjchem-604	910	30	of	of	ADP
eurjchem-604	910	31	phosphine	phosphine	NOUN
eurjchem-604	910	32	or	or	CCONJ
eurjchem-604	910	33	phosphate	phosphate	ADJ
eurjchem-604	910	34	derivates	derivate	NOUN
eurjchem-604	910	35	.	.	PUNCT
eurjchem-604	911	1	the	the	DET
eurjchem-604	911	2	cis‐mo(co)4l2	cis‐mo(co)4l2	PROPN
eurjchem-604	911	3	species	specie	NOUN
eurjchem-604	911	4	were	be	AUX
eurjchem-604	911	5	found	find	VERB
eurjchem-604	911	6	to	to	PART
eurjchem-604	911	7	react	react	VERB
eurjchem-604	911	8	stereo	stereo	NOUN
eurjchem-604	911	9	specifically	specifically	ADV
eurjchem-604	911	10	with	with	ADP
eurjchem-604	911	11	co	co	NOUN
eurjchem-604	911	12	to	to	PART
eurjchem-604	911	13	afford	afford	VERB
eurjchem-604	911	14	cis‐mo(co)4l2	cis‐mo(co)4l2	PROPN
eurjchem-604	911	15	derivative	derivative	NOUN
eurjchem-604	911	16	was	be	AUX
eurjchem-604	911	17	observed	observe	VERB
eurjchem-604	911	18	to	to	PART
eurjchem-604	911	19	be	be	AUX
eurjchem-604	911	20	nonfluxional	nonfluxional	ADJ
eurjchem-604	911	21	during	during	ADP
eurjchem-604	911	22	its	its	PRON
eurjchem-604	911	23	solution	solution	NOUN
eurjchem-604	911	24	lifetime	lifetime	NOUN
eurjchem-604	911	25	.	.	PUNCT
eurjchem-604	912	1	rate	rate	NOUN
eurjchem-604	912	2	studies	study	NOUN
eurjchem-604	912	3	of	of	ADP
eurjchem-604	912	4	phosphine	phosphine	NOUN
eurjchem-604	912	5	dissociation	dissociation	NOUN
eurjchem-604	912	6	in	in	ADP
eurjchem-604	912	7	trans‐	trans‐	PROPN
eurjchem-604	912	8	mo(co)4(pph3)2	mo(co)4(pph3)2	PROPN
eurjchem-604	912	9	are	be	AUX
eurjchem-604	912	10	reported	report	VERB
eurjchem-604	912	11	which	which	PRON
eurjchem-604	912	12	dekmonstrate	dekmonstrate	VERB
eurjchem-604	912	13	this	this	DET
eurjchem-604	912	14	process	process	NOUN
eurjchem-604	912	15	to	to	PART
eurjchem-604	912	16	be	be	AUX
eurjchem-604	912	17	less	less	ADV
eurjchem-604	912	18	facile	facile	ADJ
eurjchem-604	912	19	when	when	SCONJ
eurjchem-604	912	20	compared	compare	VERB
eurjchem-604	912	21	with	with	ADP
eurjchem-604	912	22	the	the	DET
eurjchem-604	912	23	analogous	analogous	ADJ
eurjchem-604	912	24	process	process	NOUN
eurjchem-604	912	25	in	in	ADP
eurjchem-604	912	26	cls‐mo(co)4(pph3)2	cls‐mo(co)4(pph3)2	PROPN
eurjchem-604	912	27	[	[	X
eurjchem-604	912	28	285	285	NUM
eurjchem-604	912	29	]	]	PUNCT
eurjchem-604	912	30	.	.	PUNCT
eurjchem-604	913	1	the	the	DET
eurjchem-604	913	2	enthalpies	enthalpy	NOUN
eurjchem-604	913	3	of	of	ADP
eurjchem-604	913	4	(	(	PUNCT
eurjchem-604	913	5	i	i	NOUN
eurjchem-604	913	6	)	)	PUNCT
eurjchem-604	913	7	the	the	DET
eurjchem-604	913	8	dissociation	dissociation	NOUN
eurjchem-604	913	9	reactions	reaction	NOUN
eurjchem-604	913	10	of	of	ADP
eurjchem-604	913	11	the	the	DET
eurjchem-604	913	12	carbonyl	carbonyl	NOUN
eurjchem-604	913	13	ligand	ligand	NOUN
eurjchem-604	913	14	in	in	ADP
eurjchem-604	913	15	cr(co)n	cr(co)n	NOUN
eurjchem-604	913	16	[	[	X
eurjchem-604	913	17	n	n	X
eurjchem-604	913	18	=	=	SYM
eurjchem-604	913	19	6	6	NUM
eurjchem-604	913	20	,	,	PUNCT
eurjchem-604	913	21	5	5	NUM
eurjchem-604	913	22	,	,	PUNCT
eurjchem-604	913	23	4	4	NUM
eurjchem-604	913	24	]	]	PUNCT
eurjchem-604	913	25	,	,	PUNCT
eurjchem-604	913	26	fe(co)5	fe(co)5	ADJ
eurjchem-604	913	27	,	,	PUNCT
eurjchem-604	913	28	and	and	CCONJ
eurjchem-604	913	29	ni(co)n	ni(co)n	X
eurjchem-604	914	1	[	[	X
eurjchem-604	914	2	n	n	X
eurjchem-604	914	3	=	=	SYM
eurjchem-604	914	4	4	4	NUM
eurjchem-604	914	5	,	,	PUNCT
eurjchem-604	914	6	3	3	NUM
eurjchem-604	914	7	,	,	PUNCT
eurjchem-604	914	8	2	2	NUM
eurjchem-604	914	9	]	]	PUNCT
eurjchem-604	914	10	,	,	PUNCT
eurjchem-604	914	11	(	(	PUNCT
eurjchem-604	914	12	ii	ii	NOUN
eurjchem-604	914	13	)	)	PUNCT
eurjchem-604	914	14	the	the	DET
eurjchem-604	914	15	dissociation	dissociation	NOUN
eurjchem-604	914	16	reactions	reaction	NOUN
eurjchem-604	914	17	of	of	ADP
eurjchem-604	914	18	the	the	DET
eurjchem-604	914	19	heteroligand	heteroligand	NOUN
eurjchem-604	914	20	l	l	NOUN
eurjchem-604	914	21	in	in	ADP
eurjchem-604	914	22	cr(co)5l	cr(co)5l	PROPN
eurjchem-604	914	23	[	[	X
eurjchem-604	914	24	l	l	X
eurjchem-604	914	25	=	=	SYM
eurjchem-604	914	26	cs	cs	PROPN
eurjchem-604	914	27	,	,	PUNCT
eurjchem-604	914	28	xe	xe	PROPN
eurjchem-604	914	29	,	,	PUNCT
eurjchem-604	914	30	h2	h2	PROPN
eurjchem-604	914	31	,	,	PUNCT
eurjchem-604	914	32	c2h4	c2h4	X
eurjchem-604	914	33	,	,	PUNCT
eurjchem-604	914	34	c2f4	c2f4	PROPN
eurjchem-604	914	35	]	]	X
eurjchem-604	914	36	,	,	PUNCT
eurjchem-604	914	37	cr(co)3l	cr(co)3l	NOUN
eurjchem-604	914	38	[	[	X
eurjchem-604	914	39	l	l	X
eurjchem-604	914	40	=	=	SYM
eurjchem-604	914	41	c6h6	c6h6	PROPN
eurjchem-604	914	42	,	,	PUNCT
eurjchem-604	914	43	c6me6	c6me6	NOUN
eurjchem-604	914	44	]	]	X
eurjchem-604	914	45	,	,	PUNCT
eurjchem-604	914	46	and	and	CCONJ
eurjchem-604	914	47	fe(co)4l	fe(co)4l	NOUN
eurjchem-604	915	1	[	[	X
eurjchem-604	915	2	l	l	NOUN
eurjchem-604	915	3	=	=	SYM
eurjchem-604	915	4	h2	h2	PROPN
eurjchem-604	915	5	,	,	PUNCT
eurjchem-604	915	6	c2h4	c2h4	X
eurjchem-604	915	7	]	]	X
eurjchem-604	915	8	,	,	PUNCT
eurjchem-604	915	9	(	(	PUNCT
eurjchem-604	915	10	iii	iii	X
eurjchem-604	915	11	)	)	PUNCT
eurjchem-604	915	12	the	the	DET
eurjchem-604	915	13	deprotonation	deprotonation	NOUN
eurjchem-604	915	14	reactions	reaction	NOUN
eurjchem-604	915	15	of	of	ADP
eurjchem-604	915	16	cr(co)3c6h6	cr(co)3c6h6	NOUN
eurjchem-604	915	17	and	and	CCONJ
eurjchem-604	915	18	fe(co)3c4h6	fe(co)3c4h6	PROPN
eurjchem-604	915	19	,	,	PUNCT
eurjchem-604	915	20	(	(	PUNCT
eurjchem-604	915	21	iv	iv	X
eurjchem-604	915	22	)	)	PUNCT
eurjchem-604	915	23	the	the	DET
eurjchem-604	915	24	protonation	protonation	NOUN
eurjchem-604	915	25	reaction	reaction	NOUN
eurjchem-604	915	26	of	of	ADP
eurjchem-604	915	27	ferrocene	ferrocene	NOUN
eurjchem-604	915	28	,	,	PUNCT
eurjchem-604	915	29	and	and	CCONJ
eurjchem-604	915	30	(	(	PUNCT
eurjchem-604	915	31	v	v	NOUN
eurjchem-604	915	32	)	)	PUNCT
eurjchem-604	915	33	the	the	DET
eurjchem-604	915	34	hydrogenation	hydrogenation	NOUN
eurjchem-604	915	35	reactions	reaction	NOUN
eurjchem-604	915	36	of	of	ADP
eurjchem-604	915	37	mn2(co)10	mn2(co)10	PROPN
eurjchem-604	915	38	and	and	CCONJ
eurjchem-604	915	39	co2(co)8	co2(co)8	NOUN
eurjchem-604	915	40	were	be	AUX
eurjchem-604	915	41	calculated	calculate	VERB
eurjchem-604	915	42	at	at	ADP
eurjchem-604	915	43	the	the	DET
eurjchem-604	915	44	dft	dft	PROPN
eurjchem-604	915	45	/	/	SYM
eurjchem-604	915	46	bp86	bp86	PROPN
eurjchem-604	915	47	,	,	PUNCT
eurjchem-604	915	48	mp2	mp2	PROPN
eurjchem-604	915	49	,	,	PUNCT
eurjchem-604	915	50	mp3	mp3	PROPN
eurjchem-604	915	51	,	,	PUNCT
eurjchem-604	915	52	scs‐mp2	scs‐mp2	PROPN
eurjchem-604	915	53	,	,	PUNCT
eurjchem-604	915	54	and	and	CCONJ
eurjchem-604	915	55	scs‐mp3	scs‐mp3	PROPN
eurjchem-604	915	56	levels	level	NOUN
eurjchem-604	915	57	and	and	CCONJ
eurjchem-604	915	58	compared	compare	VERB
eurjchem-604	915	59	with	with	ADP
eurjchem-604	915	60	the	the	DET
eurjchem-604	915	61	corresponding	corresponding	ADJ
eurjchem-604	915	62	experimental	experimental	ADJ
eurjchem-604	915	63	data	datum	NOUN
eurjchem-604	915	64	.	.	PUNCT
eurjchem-604	916	1	it	it	PRON
eurjchem-604	916	2	was	be	AUX
eurjchem-604	916	3	found	find	VERB
eurjchem-604	916	4	that	that	SCONJ
eurjchem-604	916	5	the	the	DET
eurjchem-604	916	6	erratic	erratic	ADJ
eurjchem-604	916	7	behavior	behavior	NOUN
eurjchem-604	916	8	of	of	ADP
eurjchem-604	916	9	the	the	DET
eurjchem-604	916	10	low‐order	low‐order	NOUN
eurjchem-604	916	11	mp	mp	NOUN
eurjchem-604	916	12	approaches	approach	NOUN
eurjchem-604	916	13	can	can	AUX
eurjchem-604	916	14	be	be	AUX
eurjchem-604	916	15	corrected	correct	VERB
eurjchem-604	916	16	by	by	ADP
eurjchem-604	916	17	the	the	DET
eurjchem-604	916	18	newly	newly	ADV
eurjchem-604	916	19	developed	develop	VERB
eurjchem-604	916	20	spin	spin	NOUN
eurjchem-604	916	21	component	component	NOUN
eurjchem-604	916	22	scaled	scale	VERB
eurjchem-604	916	23	(	(	PUNCT
eurjchem-604	916	24	scs	scs	NOUN
eurjchem-604	916	25	)	)	PUNCT
eurjchem-604	916	26	perturbation	perturbation	NOUN
eurjchem-604	916	27	theory	theory	NOUN
eurjchem-604	916	28	.	.	PUNCT
eurjchem-604	917	1	the	the	DET
eurjchem-604	917	2	scs‐mp3	scs‐mp3	PROPN
eurjchem-604	917	3	enthalpy	enthalpy	NOUN
eurjchem-604	917	4	of	of	ADP
eurjchem-604	917	5	the	the	DET
eurjchem-604	917	6	hydrogenation	hydrogenation	NOUN
eurjchem-604	917	7	reaction	reaction	NOUN
eurjchem-604	917	8	of	of	ADP
eurjchem-604	917	9	mn2(co)10	mn2(co)10	PROPN
eurjchem-604	917	10	(	(	PUNCT
eurjchem-604	917	11	5.8	5.8	NUM
eurjchem-604	917	12	kcal	kcal	NOUN
eurjchem-604	917	13	/	/	SYM
eurjchem-604	917	14	mol	mol	NOUN
eurjchem-604	917	15	)	)	PUNCT
eurjchem-604	917	16	agrees	agree	VERB
eurjchem-604	917	17	better	well	ADV
eurjchem-604	917	18	with	with	ADP
eurjchem-604	917	19	the	the	DET
eurjchem-604	917	20	experiment	experiment	NOUN
eurjchem-604	917	21	(	(	PUNCT
eurjchem-604	917	22	8.7	8.7	NUM
eurjchem-604	917	23	±	±	NUM
eurjchem-604	917	24	0	0	NUM
eurjchem-604	917	25	.	.	PROPN
eurjchem-604	917	26	3	3	NUM
eurjchem-604	917	27	kcal	kcal	NOUN
eurjchem-604	917	28	/	/	SYM
eurjchem-604	917	29	mol	mol	NOUN
eurjchem-604	917	30	)	)	PUNCT
eurjchem-604	917	31	than	than	ADP
eurjchem-604	917	32	the	the	DET
eurjchem-604	917	33	bp86	bp86	PROPN
eurjchem-604	917	34	value	value	NOUN
eurjchem-604	917	35	(	(	PUNCT
eurjchem-604	917	36	1.7	1.7	NUM
eurjchem-604	917	37	kcal	kcal	NOUN
eurjchem-604	917	38	/	/	SYM
eurjchem-604	917	39	mol	mol	NOUN
eurjchem-604	917	40	)	)	PUNCT
eurjchem-604	917	41	.	.	PUNCT
eurjchem-604	918	1	the	the	DET
eurjchem-604	918	2	scs‐mp3	scs‐mp3	PROPN
eurjchem-604	918	3	proton	proton	NOUN
eurjchem-604	918	4	affinity	affinity	NOUN
eurjchem-604	918	5	of	of	ADP
eurjchem-604	918	6	metal‐protonated	metal‐protonate	VERB
eurjchem-604	918	7	ferrocene	ferrocene	NOUN
eurjchem-604	918	8	(	(	PUNCT
eurjchem-604	918	9	214.8	214.8	NUM
eurjchem-604	918	10	kcal	kcal	NOUN
eurjchem-604	918	11	/	/	SYM
eurjchem-604	918	12	mol	mol	NOUN
eurjchem-604	918	13	)	)	PUNCT
eurjchem-604	918	14	and	and	CCONJ
eurjchem-604	918	15	of	of	ADP
eurjchem-604	918	16	the	the	DET
eurjchem-604	918	17	agostic	agostic	ADJ
eurjchem-604	918	18	form	form	NOUN
eurjchem-604	918	19	(	(	PUNCT
eurjchem-604	918	20	203.9	203.9	NUM
eurjchem-604	918	21	kcal	kcal	NOUN
eurjchem-604	918	22	/	/	SYM
eurjchem-604	918	23	mol	mol	NOUN
eurjchem-604	918	24	)	)	PUNCT
eurjchem-604	918	25	compare	compare	VERB
eurjchem-604	918	26	well	well	ADV
eurjchem-604	918	27	with	with	ADP
eurjchem-604	918	28	the	the	DET
eurjchem-604	918	29	experimental	experimental	ADJ
eurjchem-604	918	30	values	value	NOUN
eurjchem-604	918	31	(	(	PUNCT
eurjchem-604	918	32	206−213	206−213	NUM
eurjchem-604	918	33	kcal	kcal	NOUN
eurjchem-604	918	34	/	/	SYM
eurjchem-604	918	35	mol	mol	NOUN
eurjchem-604	918	36	)	)	PUNCT
eurjchem-604	918	37	and	and	CCONJ
eurjchem-604	918	38	contrary	contrary	ADJ
eurjchem-604	918	39	to	to	ADP
eurjchem-604	918	40	mp2	mp2	PROPN
eurjchem-604	918	41	do	do	AUX
eurjchem-604	918	42	not	not	PART
eurjchem-604	918	43	exclude	exclude	VERB
eurjchem-604	918	44	the	the	DET
eurjchem-604	918	45	dynamic	dynamic	ADJ
eurjchem-604	918	46	behavior	behavior	NOUN
eurjchem-604	918	47	of	of	ADP
eurjchem-604	918	48	protonated	protonated	ADJ
eurjchem-604	918	49	ferrocene	ferrocene	NOUN
eurjchem-604	918	50	.	.	PUNCT
eurjchem-604	919	1	it	it	PRON
eurjchem-604	919	2	is	be	AUX
eurjchem-604	919	3	suggested	suggest	VERB
eurjchem-604	919	4	that	that	SCONJ
eurjchem-604	919	5	for	for	ADP
eurjchem-604	919	6	complex	complex	ADJ
eurjchem-604	919	7	chemical	chemical	NOUN
eurjchem-604	919	8	systems	system	NOUN
eurjchem-604	919	9	including	include	VERB
eurjchem-604	919	10	transition	transition	NOUN
eurjchem-604	919	11	metals	metal	NOUN
eurjchem-604	919	12	simultanous	simultanous	ADJ
eurjchem-604	919	13	application	application	NOUN
eurjchem-604	919	14	of	of	ADP
eurjchem-604	919	15	dft	dft	PROPN
eurjchem-604	919	16	and	and	CCONJ
eurjchem-604	919	17	scs‐mp3	scs‐mp3	PROPN
eurjchem-604	919	18	methods	method	NOUN
eurjchem-604	919	19	may	may	AUX
eurjchem-604	919	20	be	be	AUX
eurjchem-604	919	21	helpful	helpful	ADJ
eurjchem-604	919	22	to	to	PART
eurjchem-604	919	23	increase	increase	VERB
eurjchem-604	919	24	the	the	DET
eurjchem-604	919	25	reliability	reliability	NOUN
eurjchem-604	919	26	of	of	ADP
eurjchem-604	919	27	the	the	DET
eurjchem-604	919	28	predictions	prediction	NOUN
eurjchem-604	919	29	[	[	X
eurjchem-604	919	30	286	286	NUM
eurjchem-604	919	31	]	]	PUNCT
eurjchem-604	919	32	.	.	PUNCT
eurjchem-604	920	1	vaporization	vaporization	NOUN
eurjchem-604	920	2	thermodynamics	thermodynamic	NOUN
eurjchem-604	920	3	of	of	ADP
eurjchem-604	920	4	low	low	ADJ
eurjchem-604	920	5	and	and	CCONJ
eurjchem-604	920	6	high	high	ADJ
eurjchem-604	920	7	(	(	PUNCT
eurjchem-604	920	8	>	>	SYM
eurjchem-604	920	9	400	400	NUM
eurjchem-604	920	10	g	g	NOUN
eurjchem-604	920	11	/	/	SYM
eurjchem-604	920	12	mol	mol	NOUN
eurjchem-604	920	13	)	)	PUNCT
eurjchem-604	920	14	molecular	molecular	ADJ
eurjchem-604	920	15	weight	weight	NOUN
eurjchem-604	920	16	(	(	PUNCT
eurjchem-604	920	17	mw	mw	NOUN
eurjchem-604	920	18	)	)	PUNCT
eurjchem-604	920	19	carbonyls	carbonyl	NOUN
eurjchem-604	920	20	were	be	AUX
eurjchem-604	920	21	compared	compare	VERB
eurjchem-604	920	22	.	.	PUNCT
eurjchem-604	921	1	a	a	DET
eurjchem-604	921	2	gravimetric‐torsion	gravimetric‐torsion	NOUN
eurjchem-604	921	3	effusion	effusion	NOUN
eurjchem-604	921	4	method	method	NOUN
eurjchem-604	921	5	was	be	AUX
eurjchem-604	921	6	used	use	VERB
eurjchem-604	921	7	to	to	PART
eurjchem-604	921	8	measure	measure	VERB
eurjchem-604	921	9	vapor	vapor	NOUN
eurjchem-604	921	10	pressures	pressure	NOUN
eurjchem-604	921	11	of	of	ADP
eurjchem-604	921	12	carbonyls	carbonyls	NOUN
eurjchem-604	921	13	such	such	ADJ
eurjchem-604	921	14	os3(co)12	os3(co)12	PROPN
eurjchem-604	921	15	,	,	PUNCT
eurjchem-604	921	16	rh6(co)16	rh6(co)16	PROPN
eurjchem-604	921	17	,	,	PUNCT
eurjchem-604	921	18	ru3(co)12	ru3(co)12	PROPN
eurjchem-604	921	19	,	,	PUNCT
eurjchem-604	921	20	co2(co)8	co2(co)8	PROPN
eurjchem-604	921	21	,	,	PUNCT
eurjchem-604	921	22	cr(co)6	cr(co)6	NOUN
eurjchem-604	921	23	,	,	PUNCT
eurjchem-604	921	24	and	and	CCONJ
eurjchem-604	921	25	w(co)6carbonyls	w(co)6carbonyls	PROPN
eurjchem-604	921	26	.	.	PUNCT
eurjchem-604	922	1	the	the	DET
eurjchem-604	922	2	studies	study	NOUN
eurjchem-604	922	3	found	find	VERB
eurjchem-604	922	4	that	that	SCONJ
eurjchem-604	922	5	os3(co)12	os3(co)12	PROPN
eurjchem-604	922	6	,	,	PUNCT
eurjchem-604	922	7	cr(co)6	cr(co)6	NOUN
eurjchem-604	922	8	,	,	PUNCT
eurjchem-604	922	9	and	and	CCONJ
eurjchem-604	922	10	w(co)6	w(co)6	PROPN
eurjchem-604	922	11	have	have	AUX
eurjchem-604	922	12	shown	show	VERB
eurjchem-604	922	13	virtually	virtually	ADV
eurjchem-604	922	14	no	no	DET
eurjchem-604	922	15	disproportionation	disproportionation	NOUN
eurjchem-604	922	16	in	in	ADP
eurjchem-604	922	17	structure	structure	NOUN
eurjchem-604	922	18	[	[	X
eurjchem-604	922	19	287	287	NUM
eurjchem-604	922	20	]	]	PUNCT
eurjchem-604	922	21	.	.	PUNCT
eurjchem-604	923	1	dombek	dombek	PROPN
eurjchem-604	923	2	and	and	CCONJ
eurjchem-604	923	3	angelici	angelici	ADV
eurjchem-604	923	4	done	do	VERB
eurjchem-604	923	5	study	study	NOUN
eurjchem-604	923	6	of	of	ADP
eurjchem-604	923	7	the	the	DET
eurjchem-604	923	8	reaction	reaction	NOUN
eurjchem-604	923	9	of	of	ADP
eurjchem-604	923	10	group	group	NOUN
eurjchem-604	923	11	6	6	NUM
eurjchem-604	923	12	metal	metal	NOUN
eurjchem-604	923	13	thiocarbonyl	thiocarbonyl	NOUN
eurjchem-604	923	14	complexes	complex	NOUN
eurjchem-604	923	15	with	with	ADP
eurjchem-604	923	16	nucleophiles	nucleophile	NOUN
eurjchem-604	923	17	.	.	PUNCT
eurjchem-604	924	1	they	they	PRON
eurjchem-604	924	2	found	find	VERB
eurjchem-604	924	3	that	that	SCONJ
eurjchem-604	924	4	primary	primary	ADJ
eurjchem-604	924	5	amines	amine	NOUN
eurjchem-604	924	6	readily	readily	ADV
eurjchem-604	924	7	react	react	VERB
eurjchem-604	924	8	with	with	ADP
eurjchem-604	924	9	m(co)5(cs	m(co)5(cs	NOUN
eurjchem-604	924	10	)	)	PUNCT
eurjchem-604	924	11	complexes	complex	NOUN
eurjchem-604	924	12	where	where	SCONJ
eurjchem-604	924	13	(	(	PUNCT
eurjchem-604	924	14	m	m	PROPN
eurjchem-604	924	15	=	=	SYM
eurjchem-604	924	16	cr	cr	PROPN
eurjchem-604	924	17	,	,	PUNCT
eurjchem-604	924	18	mo	mo	PROPN
eurjchem-604	924	19	,	,	PUNCT
eurjchem-604	924	20	w	w	NOUN
eurjchem-604	924	21	)	)	PUNCT
eurjchem-604	924	22	to	to	PART
eurjchem-604	924	23	give	give	VERB
eurjchem-604	924	24	isocyanide	isocyanide	NOUN
eurjchem-604	924	25	complexes	complex	NOUN
eurjchem-604	924	26	,	,	PUNCT
eurjchem-604	924	27	m(co)5(cnr	m(co)5(cnr	NUM
eurjchem-604	924	28	)	)	PUNCT
eurjchem-604	924	29	.	.	PUNCT
eurjchem-604	925	1	secondary	secondary	ADJ
eurjchem-604	925	2	amines	amine	NOUN
eurjchem-604	925	3	are	be	AUX
eurjchem-604	925	4	found	find	VERB
eurjchem-604	925	5	to	to	PART
eurjchem-604	925	6	give	give	VERB
eurjchem-604	925	7	lower	low	ADJ
eurjchem-604	925	8	yields	yield	NOUN
eurjchem-604	925	9	of	of	ADP
eurjchem-604	925	10	thioformamide	thioformamide	ADJ
eurjchem-604	925	11	complexes	complex	NOUN
eurjchem-604	925	12	w(co)5(s	w(co)5(	NOUN
eurjchem-604	925	13	=	=	SYM
eurjchem-604	925	14	c(h)nr2	c(h)nr2	NOUN
eurjchem-604	925	15	)	)	PUNCT
eurjchem-604	925	16	.	.	PUNCT
eurjchem-604	926	1	kinetic	kinetic	ADJ
eurjchem-604	926	2	studies	study	NOUN
eurjchem-604	926	3	show	show	VERB
eurjchem-604	926	4	a	a	DET
eurjchem-604	926	5	second	second	ADJ
eurjchem-604	926	6	order	order	NOUN
eurjchem-604	926	7	dependence	dependence	NOUN
eurjchem-604	926	8	in	in	ADP
eurjchem-604	926	9	amine	amine	ADJ
eurjchem-604	926	10	concentration	concentration	NOUN
eurjchem-604	926	11	.	.	PUNCT
eurjchem-604	927	1	it	it	PRON
eurjchem-604	927	2	was	be	AUX
eurjchem-604	927	3	suggested	suggest	VERB
eurjchem-604	927	4	that	that	SCONJ
eurjchem-604	927	5	the	the	DET
eurjchem-604	927	6	rate‐determining	rate‐determining	NOUN
eurjchem-604	927	7	step	step	NOUN
eurjchem-604	927	8	is	be	AUX
eurjchem-604	927	9	the	the	DET
eurjchem-604	927	10	addition	addition	NOUN
eurjchem-604	927	11	of	of	ADP
eurjchem-604	927	12	a	a	DET
eurjchem-604	927	13	hydrogen‐bonded	hydrogen‐bonde	VERB
eurjchem-604	927	14	amine	amine	NOUN
eurjchem-604	927	15	to	to	ADP
eurjchem-604	927	16	the	the	DET
eurjchem-604	927	17	thiocarbonyl	thiocarbonyl	ADJ
eurjchem-604	927	18	atom	atom	NOUN
eurjchem-604	927	19	.	.	PUNCT
eurjchem-604	928	1	the	the	DET
eurjchem-604	928	2	phosphine	phosphine	NOUN
eurjchem-604	928	3	substituted	substitute	VERB
eurjchem-604	928	4	analogues	analogue	NOUN
eurjchem-604	928	5	,	,	PUNCT
eurjchem-604	928	6	cis‐	cis‐	NOUN
eurjchem-604	928	7	and	and	CCONJ
eurjchem-604	928	8	trans‐	trans‐	PROPN
eurjchem-604	928	9	w(co)4(cs)(pph3	w(co)4(cs)(pph3	NOUN
eurjchem-604	928	10	)	)	PUNCT
eurjchem-604	928	11	reacts	react	VERB
eurjchem-604	928	12	much	much	ADV
eurjchem-604	928	13	slower	slow	ADJ
eurjchem-604	928	14	,	,	PUNCT
eurjchem-604	928	15	presumably	presumably	ADV
eurjchem-604	928	16	due	due	ADP
eurjchem-604	928	17	to	to	ADP
eurjchem-604	928	18	increased	increase	VERB
eurjchem-604	928	19	electron	electron	NOUN
eurjchem-604	928	20	density	density	NOUN
eurjchem-604	928	21	at	at	ADP
eurjchem-604	928	22	the	the	DET
eurjchem-604	928	23	thiocarbonyl	thiocarbonyl	PROPN
eurjchem-604	928	24	ligand	ligand	NOUN
eurjchem-604	928	25	.	.	PUNCT
eurjchem-604	929	1	azide	azide	NOUN
eurjchem-604	929	2	ion	ion	NOUN
eurjchem-604	929	3	reacts	react	VERB
eurjchem-604	929	4	rapidly	rapidly	ADV
eurjchem-604	929	5	with	with	ADP
eurjchem-604	929	6	m(co)5(cs	m(co)5(cs	NOUN
eurjchem-604	929	7	)	)	PUNCT
eurjchem-604	929	8	,	,	PUNCT
eurjchem-604	929	9	forming	form	VERB
eurjchem-604	929	10	cleanely	cleanely	ADV
eurjchem-604	929	11	the	the	DET
eurjchem-604	929	12	known	know	VERB
eurjchem-604	929	13	w(co)5(cs	w(co)5(cs	NOUN
eurjchem-604	929	14	)	)	PUNCT
eurjchem-604	929	15	.	.	PUNCT
eurjchem-604	930	1	a	a	DET
eurjchem-604	930	2	number	number	NOUN
eurjchem-604	930	3	of	of	ADP
eurjchem-604	930	4	weaker	weak	ADJ
eurjchem-604	930	5	nucleophiles	nucleophile	NOUN
eurjchem-604	930	6	including	include	VERB
eurjchem-604	930	7	water	water	NOUN
eurjchem-604	930	8	,	,	PUNCT
eurjchem-604	930	9	alcohols	alcohol	NOUN
eurjchem-604	930	10	,	,	PUNCT
eurjchem-604	930	11	hydrazine	hydrazine	NOUN
eurjchem-604	930	12	,	,	PUNCT
eurjchem-604	930	13	aniline	aniline	NOUN
eurjchem-604	930	14	,	,	PUNCT
eurjchem-604	930	15	ammonia	ammonia	NOUN
eurjchem-604	930	16	,	,	PUNCT
eurjchem-604	930	17	ch3sh	ch3sh	NUM
eurjchem-604	930	18	and	and	CCONJ
eurjchem-604	930	19	ph3po	ph3po	NUM
eurjchem-604	930	20	do	do	AUX
eurjchem-604	930	21	not	not	PART
eurjchem-604	930	22	react	react	VERB
eurjchem-604	930	23	with	with	ADP
eurjchem-604	930	24	w(co)5(cs	w(co)5(c	NOUN
eurjchem-604	930	25	)	)	PUNCT
eurjchem-604	930	26	.	.	PUNCT
eurjchem-604	931	1	stronger	strong	ADJ
eurjchem-604	931	2	nucleophiles	nucleophile	NOUN
eurjchem-604	931	3	such	such	ADJ
eurjchem-604	931	4	as	as	ADP
eurjchem-604	931	5	ch3li	ch3li	NOUN
eurjchem-604	931	6	,	,	PUNCT
eurjchem-604	931	7	r2nli	r2nli	PROPN
eurjchem-604	931	8	and	and	CCONJ
eurjchem-604	931	9	ro‐	ro‐	NOUN
eurjchem-604	931	10	appear	appear	VERB
eurjchem-604	931	11	to	to	PART
eurjchem-604	931	12	add	add	VERB
eurjchem-604	931	13	to	to	ADP
eurjchem-604	931	14	the	the	DET
eurjchem-604	931	15	cs	cs	PROPN
eurjchem-604	931	16	ligand	ligand	NOUN
eurjchem-604	931	17	,	,	PUNCT
eurjchem-604	931	18	although	although	SCONJ
eurjchem-604	931	19	the	the	DET
eurjchem-604	931	20	reactions	reaction	NOUN
eurjchem-604	931	21	are	be	AUX
eurjchem-604	931	22	not	not	PART
eurjchem-604	931	23	straightforward	straightforward	ADJ
eurjchem-604	931	24	[	[	X
eurjchem-604	931	25	288	288	NUM
eurjchem-604	931	26	]	]	PUNCT
eurjchem-604	931	27	.	.	PUNCT
eurjchem-604	932	1	a	a	DET
eurjchem-604	932	2	range	range	NOUN
eurjchem-604	932	3	of	of	ADP
eurjchem-604	932	4	microwave‐enhanced	microwave‐enhance	VERB
eurjchem-604	932	5	reactions	reaction	NOUN
eurjchem-604	932	6	of	of	ADP
eurjchem-604	932	7	group	group	NOUN
eurjchem-604	932	8	vib	vib	PROPN
eurjchem-604	932	9	metal	metal	NOUN
eurjchem-604	932	10	carbonyls	carbonyls	NOUN
eurjchem-604	932	11	were	be	AUX
eurjchem-604	932	12	presented	present	VERB
eurjchem-604	932	13	by	by	ADP
eurjchem-604	932	14	ardon	ardon	PROPN
eurjchem-604	932	15	et	et	PROPN
eurjchem-604	932	16	al	al	PROPN
eurjchem-604	932	17	.	.	PUNCT
eurjchem-604	933	1	(	(	PUNCT
eurjchem-604	933	2	scheme	scheme	NOUN
eurjchem-604	933	3	72	72	NUM
eurjchem-604	933	4	)	)	PUNCT
eurjchem-604	933	5	.	.	PUNCT
eurjchem-604	934	1	molybdenum	molybdenum	NOUN
eurjchem-604	934	2	hexacarbonyl	hexacarbonyl	PROPN
eurjchem-604	934	3	is	be	AUX
eurjchem-604	934	4	particularly	particularly	ADV
eurjchem-604	934	5	well	well	ADV
eurjchem-604	934	6	suited	suited	ADJ
eurjchem-604	934	7	to	to	ADP
eurjchem-604	934	8	this	this	DET
eurjchem-604	934	9	procedure	procedure	NOUN
eurjchem-604	934	10	,	,	PUNCT
eurjchem-604	934	11	with	with	ADP
eurjchem-604	934	12	reactions	reaction	NOUN
eurjchem-604	934	13	generally	generally	ADV
eurjchem-604	934	14	proceeding	proceed	VERB
eurjchem-604	934	15	cleanly	cleanly	ADV
eurjchem-604	934	16	and	and	CCONJ
eurjchem-604	934	17	without	without	ADP
eurjchem-604	934	18	need	need	NOUN
eurjchem-604	934	19	for	for	ADP
eurjchem-604	934	20	an	an	DET
eurjchem-604	934	21	inert	inert	ADJ
eurjchem-604	934	22	atmosphere	atmosphere	NOUN
eurjchem-604	934	23	.	.	PUNCT
eurjchem-604	935	1	reactions	reaction	NOUN
eurjchem-604	935	2	of	of	ADP
eurjchem-604	935	3	chromium	chromium	NOUN
eurjchem-604	935	4	and	and	CCONJ
eurjchem-604	935	5	tungsten	tungsten	ADJ
eurjchem-604	935	6	hexacarbonyls	hexacarbonyls	NOUN
eurjchem-604	935	7	are	be	AUX
eurjchem-604	935	8	less	less	ADV
eurjchem-604	935	9	impressive	impressive	ADJ
eurjchem-604	935	10	[	[	X
eurjchem-604	935	11	289	289	NUM
eurjchem-604	935	12	]	]	PUNCT
eurjchem-604	935	13	.	.	PUNCT
eurjchem-604	936	1	scheme	scheme	VERB
eurjchem-604	936	2	72	72	NUM
eurjchem-604	936	3	many	many	ADJ
eurjchem-604	936	4	carbonyl	carbonyl	NOUN
eurjchem-604	936	5	diimine	diimine	NOUN
eurjchem-604	936	6	complexes	complex	NOUN
eurjchem-604	936	7	of	of	ADP
eurjchem-604	936	8	first‐row	first‐row	NOUN
eurjchem-604	936	9	transition	transition	NOUN
eurjchem-604	936	10	metals	metal	NOUN
eurjchem-604	936	11	have	have	AUX
eurjchem-604	936	12	been	be	AUX
eurjchem-604	936	13	found	find	VERB
eurjchem-604	936	14	to	to	PART
eurjchem-604	936	15	be	be	AUX
eurjchem-604	936	16	photoreactive	photoreactive	ADJ
eurjchem-604	936	17	under	under	ADP
eurjchem-604	936	18	irradiation	irradiation	NOUN
eurjchem-604	936	19	into	into	ADP
eurjchem-604	936	20	their	their	PRON
eurjchem-604	936	21	lowest	low	ADJ
eurjchem-604	936	22	metal‐to‐ligand	metal‐to‐ligand	NOUN
eurjchem-604	936	23	charge‐transfer	charge‐transfer	NOUN
eurjchem-604	936	24	(	(	PUNCT
eurjchem-604	936	25	mlct	mlct	NOUN
eurjchem-604	936	26	)	)	PUNCT
eurjchem-604	936	27	absorption	absorption	NOUN
eurjchem-604	936	28	band	band	NOUN
eurjchem-604	936	29	(	(	PUNCT
eurjchem-604	936	30	metal	metal	NOUN
eurjchem-604	936	31	→	→	SYM
eurjchem-604	936	32	α‐diimine	α‐diimine	NUM
eurjchem-604	936	33	)	)	PUNCT
eurjchem-604	936	34	,	,	PUNCT
eurjchem-604	936	35	the	the	DET
eurjchem-604	936	36	observed	observe	VERB
eurjchem-604	936	37	primary	primary	ADJ
eurjchem-604	936	38	reaction	reaction	NOUN
eurjchem-604	936	39	corresponding	correspond	VERB
eurjchem-604	936	40	to	to	ADP
eurjchem-604	936	41	a	a	DET
eurjchem-604	936	42	carbonyl	carbonyl	NOUN
eurjchem-604	936	43	loss	loss	NOUN
eurjchem-604	936	44	.	.	PUNCT
eurjchem-604	937	1	metal‐to‐ligand	metal‐to‐ligand	NOUN
eurjchem-604	937	2	charge‐transfer	charge‐transfer	NOUN
eurjchem-604	937	3	(	(	PUNCT
eurjchem-604	937	4	mlct	mlct	ADJ
eurjchem-604	937	5	)	)	PUNCT
eurjchem-604	937	6	excited‐state	excited‐state	ADJ
eurjchem-604	937	7	dynamics	dynamic	NOUN
eurjchem-604	937	8	of	of	ADP
eurjchem-604	937	9	cr(co)4(bpy	cr(co)4(bpy	NOUN
eurjchem-604	937	10	)	)	PUNCT
eurjchem-604	937	11	(	(	PUNCT
eurjchem-604	937	12	bpy	bpy	VERB
eurjchem-604	937	13	=	=	SYM
eurjchem-604	937	14	2,2‘‐bipyridine	2,2‘‐bipyridine	NOUN
eurjchem-604	937	15	)	)	PUNCT
eurjchem-604	937	16	have	have	AUX
eurjchem-604	937	17	been	be	AUX
eurjchem-604	937	18	investigated	investigate	VERB
eurjchem-604	937	19	through	through	ADP
eurjchem-604	937	20	wave	wave	NOUN
eurjchem-604	937	21	packet	packet	NOUN
eurjchem-604	937	22	propagations	propagation	NOUN
eurjchem-604	937	23	on	on	ADP
eurjchem-604	937	24	casscf	casscf	PROPN
eurjchem-604	937	25	/	/	SYM
eurjchem-604	937	26	mr‐cci	mr‐cci	PROPN
eurjchem-604	937	27	potentials	potential	NOUN
eurjchem-604	937	28	and	and	CCONJ
eurjchem-604	937	29	compared	compare	VERB
eurjchem-604	937	30	with	with	ADP
eurjchem-604	937	31	the	the	DET
eurjchem-604	937	32	results	result	NOUN
eurjchem-604	937	33	of	of	ADP
eurjchem-604	937	34	recent	recent	ADJ
eurjchem-604	937	35	femtosecond	femtosecond	NOUN
eurjchem-604	937	36	time‐resolved	time‐resolve	VERB
eurjchem-604	937	37	spectroscopic	spectroscopic	ADJ
eurjchem-604	937	38	study	study	NOUN
eurjchem-604	937	39	[	[	X
eurjchem-604	937	40	290	290	NUM
eurjchem-604	937	41	]	]	PUNCT
eurjchem-604	937	42	.	.	PUNCT
eurjchem-604	938	1	photoinduced	photoinduce	VERB
eurjchem-604	938	2	co‐loss	co‐loss	NOUN
eurjchem-604	938	3	and	and	CCONJ
eurjchem-604	938	4	arene‐loss	arene‐loss	NOUN
eurjchem-604	938	5	from	from	ADP
eurjchem-604	938	6	(	(	PUNCT
eurjchem-604	938	7	η6‐	η6‐	NOUN
eurjchem-604	938	8	c6h5y)cr(co)3	c6h5y)cr(co)3	NOUN
eurjchem-604	938	9	(	(	PUNCT
eurjchem-604	938	10	y	y	NOUN
eurjchem-604	938	11	=	=	PUNCT
eurjchem-604	938	12	nh2	nh2	PROPN
eurjchem-604	938	13	,	,	PUNCT
eurjchem-604	938	14	och3	och3	ADJ
eurjchem-604	938	15	,	,	PUNCT
eurjchem-604	938	16	h	h	NOUN
eurjchem-604	938	17	,	,	PUNCT
eurjchem-604	938	18	cho	cho	NOUN
eurjchem-604	938	19	or	or	CCONJ
eurjchem-604	938	20	co2ch3	co2ch3	ADJ
eurjchem-604	938	21	)	)	PUNCT
eurjchem-604	938	22	result	result	VERB
eurjchem-604	938	23	from	from	ADP
eurjchem-604	938	24	discrete	discrete	ADJ
eurjchem-604	938	25	photophysical	photophysical	ADJ
eurjchem-604	938	26	processes	process	NOUN
eurjchem-604	938	27	whose	whose	DET
eurjchem-604	938	28	efficiency	efficiency	NOUN
eurjchem-604	938	29	depends	depend	VERB
eurjchem-604	938	30	on	on	ADP
eurjchem-604	938	31	the	the	DET
eurjchem-604	938	32	solvent	solvent	NOUN
eurjchem-604	938	33	(	(	PUNCT
eurjchem-604	938	34	scheme	scheme	NOUN
eurjchem-604	938	35	73	73	NUM
eurjchem-604	938	36	)	)	PUNCT
eurjchem-604	938	37	.	.	PUNCT
eurjchem-604	939	1	the	the	DET
eurjchem-604	939	2	quantum	quantum	NOUN
eurjchem-604	939	3	yield	yield	NOUN
eurjchem-604	939	4	(	(	PUNCT
eurjchem-604	939	5	φ	φ	NOUN
eurjchem-604	939	6	)	)	PUNCT
eurjchem-604	939	7	for	for	ADP
eurjchem-604	939	8	arene	arene	NOUN
eurjchem-604	939	9	loss	loss	NOUN
eurjchem-604	939	10	is	be	AUX
eurjchem-604	939	11	greater	great	ADJ
eurjchem-604	939	12	in	in	ADP
eurjchem-604	939	13	halocarbon	halocarbon	NOUN
eurjchem-604	939	14	than	than	ADP
eurjchem-604	939	15	in	in	ADP
eurjchem-604	939	16	hydrocarbon	hydrocarbon	NOUN
eurjchem-604	939	17	solvents	solvent	NOUN
eurjchem-604	939	18	[	[	X
eurjchem-604	939	19	291	291	NUM
eurjchem-604	939	20	]	]	PUNCT
eurjchem-604	939	21	.	.	PUNCT
eurjchem-604	940	1	retracted	retract	VERB
eurjchem-604	940	2	390	390	NUM
eurjchem-604	940	3	kaushik	kaushik	PROPN
eurjchem-604	940	4	et	et	PROPN
eurjchem-604	940	5	al	al	PROPN
eurjchem-604	940	6	.	.	PUNCT
eurjchem-604	940	7	/	/	SYM
eurjchem-604	940	8	european	european	PROPN
eurjchem-604	940	9	journal	journal	PROPN
eurjchem-604	940	10	of	of	ADP
eurjchem-604	940	11	chemistry	chemistry	NOUN
eurjchem-604	940	12	3	3	NUM
eurjchem-604	940	13	(	(	PUNCT
eurjchem-604	940	14	3	3	NUM
eurjchem-604	940	15	)	)	PUNCT
eurjchem-604	940	16	(	(	PUNCT
eurjchem-604	940	17	2012	2012	NUM
eurjchem-604	940	18	)	)	PUNCT
eurjchem-604	940	19	367‐394	367‐394	NUM
eurjchem-604	940	20	scheme	scheme	NOUN
eurjchem-604	940	21	73	73	NUM
eurjchem-604	940	22	zhang	zhang	PROPN
eurjchem-604	940	23	et	et	PROPN
eurjchem-604	940	24	al	al	PROPN
eurjchem-604	940	25	.	.	PROPN
eurjchem-604	940	26	studied	study	VERB
eurjchem-604	940	27	cyclopentadienylmolybdenum	cyclopentadienylmolybdenum	ADJ
eurjchem-604	940	28	carbonyls	carbonyls	NOUN
eurjchem-604	940	29	cp2mo2(co)n	cp2mo2(co)n	NOUN
eurjchem-604	940	30	(	(	PUNCT
eurjchem-604	940	31	cp	cp	INTJ
eurjchem-604	940	32	=	=	SYM
eurjchem-604	940	33	η5‐c5h5	η5‐c5h5	PROPN
eurjchem-604	940	34	;	;	PUNCT
eurjchem-604	940	35	n	n	PROPN
eurjchem-604	940	36	=	=	SYM
eurjchem-604	940	37	6−1	6−1	NUM
eurjchem-604	940	38	)	)	PUNCT
eurjchem-604	940	39	(	(	PUNCT
eurjchem-604	940	40	figure	figure	NOUN
eurjchem-604	940	41	12	12	NUM
eurjchem-604	940	42	)	)	PUNCT
eurjchem-604	940	43	by	by	ADP
eurjchem-604	940	44	density	density	NOUN
eurjchem-604	940	45	functional	functional	ADJ
eurjchem-604	940	46	theory	theory	NOUN
eurjchem-604	940	47	and	and	CCONJ
eurjchem-604	940	48	predicted	predict	VERB
eurjchem-604	940	49	stability	stability	NOUN
eurjchem-604	940	50	of	of	ADP
eurjchem-604	940	51	metal	metal	NOUN
eurjchem-604	940	52	carbonyl	carbonyl	NOUN
eurjchem-604	940	53	complexes	complex	NOUN
eurjchem-604	940	54	[	[	X
eurjchem-604	940	55	292	292	NUM
eurjchem-604	940	56	]	]	PUNCT
eurjchem-604	940	57	.	.	PUNCT
eurjchem-604	941	1	the	the	DET
eurjchem-604	941	2	two	two	NUM
eurjchem-604	941	3	lowest	low	ADJ
eurjchem-604	941	4	energy	energy	NOUN
eurjchem-604	941	5	structures	structure	NOUN
eurjchem-604	941	6	predicted	predict	VERB
eurjchem-604	941	7	for	for	ADP
eurjchem-604	941	8	cp2mo2(co)6	cp2mo2(co)6	PROPN
eurjchem-604	941	9	lie	lie	VERB
eurjchem-604	941	10	within	within	ADP
eurjchem-604	941	11	4	4	NUM
eurjchem-604	941	12	kcal	kcal	NOUN
eurjchem-604	941	13	/	/	SYM
eurjchem-604	941	14	mol	mol	ADP
eurjchem-604	941	15	of	of	ADP
eurjchem-604	941	16	each	each	DET
eurjchem-604	941	17	other	other	ADJ
eurjchem-604	941	18	.	.	PUNCT
eurjchem-604	942	1	both	both	PRON
eurjchem-604	942	2	have	have	VERB
eurjchem-604	942	3	mo−mo	mo−mo	ADJ
eurjchem-604	942	4	single	single	ADJ
eurjchem-604	942	5	bonds	bond	NOUN
eurjchem-604	942	6	of	of	ADP
eurjchem-604	942	7	lengths	length	NOUN
eurjchem-604	942	8	3	3	NUM
eurjchem-604	942	9	.	.	PUNCT
eurjchem-604	943	1	2−3	2−3	NUM
eurjchem-604	943	2	.	.	PUNCT
eurjchem-604	944	1	3	3	NUM
eurjchem-604	944	2	å	å	NOUN
eurjchem-604	944	3	with	with	ADP
eurjchem-604	944	4	all	all	DET
eurjchem-604	944	5	terminal	terminal	ADJ
eurjchem-604	944	6	carbonyl	carbonyl	NOUN
eurjchem-604	944	7	groups	group	NOUN
eurjchem-604	944	8	and	and	CCONJ
eurjchem-604	944	9	correspond	correspond	VERB
eurjchem-604	944	10	to	to	ADP
eurjchem-604	944	11	stable	stable	ADJ
eurjchem-604	944	12	compounds	compound	NOUN
eurjchem-604	944	13	.	.	PUNCT
eurjchem-604	945	1	similarly	similarly	ADV
eurjchem-604	945	2	,	,	PUNCT
eurjchem-604	945	3	the	the	DET
eurjchem-604	945	4	lowest	low	ADJ
eurjchem-604	945	5	energy	energy	NOUN
eurjchem-604	945	6	structure	structure	NOUN
eurjchem-604	945	7	predicted	predict	VERB
eurjchem-604	945	8	for	for	ADP
eurjchem-604	945	9	cp2mo2(co)4	cp2mo2(co)4	PROPN
eurjchem-604	945	10	has	have	VERB
eurjchem-604	945	11	a	a	DET
eurjchem-604	945	12	formal	formal	ADJ
eurjchem-604	945	13	mo≡mo	mo≡mo	NOUN
eurjchem-604	945	14	triple	triple	ADJ
eurjchem-604	945	15	bond	bond	NOUN
eurjchem-604	945	16	of	of	ADP
eurjchem-604	945	17	length	length	NOUN
eurjchem-604	945	18	~2	~2	NOUN
eurjchem-604	945	19	.	.	PUNCT
eurjchem-604	946	1	5	5	NUM
eurjchem-604	946	2	å	å	NOUN
eurjchem-604	946	3	with	with	ADP
eurjchem-604	946	4	four	four	NUM
eurjchem-604	946	5	weakly	weakly	ADJ
eurjchem-604	946	6	semibridging	semibridging	NOUN
eurjchem-604	946	7	carbonyl	carbonyl	NOUN
eurjchem-604	946	8	groups	group	NOUN
eurjchem-604	946	9	also	also	ADV
eurjchem-604	946	10	corresponding	correspond	VERB
eurjchem-604	946	11	to	to	ADP
eurjchem-604	946	12	a	a	DET
eurjchem-604	946	13	stable	stable	ADJ
eurjchem-604	946	14	compound	compound	NOUN
eurjchem-604	946	15	structurally	structurally	ADV
eurjchem-604	946	16	characterized	characterize	VERB
eurjchem-604	946	17	by	by	ADP
eurjchem-604	946	18	x‐ray	x‐ray	PROPN
eurjchem-604	946	19	diffraction	diffraction	PROPN
eurjchem-604	946	20	.	.	PUNCT
eurjchem-604	947	1	the	the	DET
eurjchem-604	947	2	pentacarbonyl	pentacarbonyl	PROPN
eurjchem-604	947	3	cp2mo2(co)5	cp2mo2(co)5	PROPN
eurjchem-604	947	4	,	,	PUNCT
eurjchem-604	947	5	which	which	PRON
eurjchem-604	947	6	is	be	AUX
eurjchem-604	947	7	not	not	PART
eurjchem-604	947	8	known	know	VERB
eurjchem-604	947	9	experimentally	experimentally	ADV
eurjchem-604	947	10	as	as	ADP
eurjchem-604	947	11	a	a	DET
eurjchem-604	947	12	stable	stable	ADJ
eurjchem-604	947	13	compound	compound	NOUN
eurjchem-604	947	14	but	but	CCONJ
eurjchem-604	947	15	only	only	ADV
eurjchem-604	947	16	as	as	ADP
eurjchem-604	947	17	a	a	DET
eurjchem-604	947	18	transient	transient	ADJ
eurjchem-604	947	19	intermediate	intermediate	NOUN
eurjchem-604	947	20	,	,	PUNCT
eurjchem-604	947	21	is	be	AUX
eurjchem-604	947	22	shown	show	VERB
eurjchem-604	947	23	to	to	PART
eurjchem-604	947	24	have	have	VERB
eurjchem-604	947	25	a	a	DET
eurjchem-604	947	26	structure	structure	NOUN
eurjchem-604	947	27	with	with	ADP
eurjchem-604	947	28	one	one	NUM
eurjchem-604	947	29	symmetrical	symmetrical	ADJ
eurjchem-604	947	30	bridging	bridging	NOUN
eurjchem-604	947	31	two‐electron	two‐electron	NUM
eurjchem-604	947	32	donor	donor	NOUN
eurjchem-604	947	33	and	and	CCONJ
eurjchem-604	947	34	four	four	NUM
eurjchem-604	947	35	terminal	terminal	ADJ
eurjchem-604	947	36	carbonyl	carbonyl	NOUN
eurjchem-604	947	37	groups	group	NOUN
eurjchem-604	947	38	as	as	ADV
eurjchem-604	947	39	well	well	ADV
eurjchem-604	947	40	as	as	ADP
eurjchem-604	947	41	a	a	DET
eurjchem-604	947	42	formal	formal	ADJ
eurjchem-604	947	43	mo	mo	PROPN
eurjchem-604	947	44	=	=	ADJ
eurjchem-604	947	45	mo	mo	PROPN
eurjchem-604	947	46	double	double	ADJ
eurjchem-604	947	47	bond	bond	NOUN
eurjchem-604	947	48	.	.	PUNCT
eurjchem-604	948	1	furthermore	furthermore	ADV
eurjchem-604	948	2	,	,	PUNCT
eurjchem-604	948	3	cp2mo2(co)5	cp2mo2(co)5	PROPN
eurjchem-604	948	4	is	be	AUX
eurjchem-604	948	5	predicted	predict	VERB
eurjchem-604	948	6	to	to	PART
eurjchem-604	948	7	be	be	AUX
eurjchem-604	948	8	thermodynamically	thermodynamically	ADV
eurjchem-604	948	9	unstable	unstable	ADJ
eurjchem-604	948	10	with	with	ADP
eurjchem-604	948	11	respect	respect	NOUN
eurjchem-604	948	12	to	to	ADP
eurjchem-604	948	13	dispropor‐	dispropor‐	VERB
eurjchem-604	948	14	tionation	tionation	NOUN
eurjchem-604	948	15	into	into	ADP
eurjchem-604	948	16	cp2mo2(co)6	cp2mo2(co)6	PROPN
eurjchem-604	948	17	+	+	CCONJ
eurjchem-604	948	18	cp2mo2(co)4	cp2mo2(co)4	PROPN
eurjchem-604	948	19	.	.	PUNCT
eurjchem-604	949	1	the	the	DET
eurjchem-604	949	2	lowest	low	ADJ
eurjchem-604	949	3	energy	energy	NOUN
eurjchem-604	949	4	structure	structure	NOUN
eurjchem-604	949	5	for	for	ADP
eurjchem-604	949	6	cp2mo2(co)3	cp2mo2(co)3	PROPN
eurjchem-604	949	7	is	be	AUX
eurjchem-604	949	8	a	a	DET
eurjchem-604	949	9	triplet	triplet	NOUN
eurjchem-604	949	10	with	with	ADP
eurjchem-604	949	11	a	a	DET
eurjchem-604	949	12	formal	formal	ADJ
eurjchem-604	949	13	mo≡mo	mo≡mo	NOUN
eurjchem-604	949	14	triple	triple	ADJ
eurjchem-604	949	15	bond	bond	NOUN
eurjchem-604	949	16	.	.	PUNCT
eurjchem-604	950	1	a	a	DET
eurjchem-604	950	2	higher	high	ADJ
eurjchem-604	950	3	energy	energy	NOUN
eurjchem-604	950	4	singlet	singlet	NOUN
eurjchem-604	950	5	structure	structure	NOUN
eurjchem-604	950	6	with	with	ADP
eurjchem-604	950	7	one	one	NUM
eurjchem-604	950	8	four‐	four‐	NOUN
eurjchem-604	950	9	electron‐donor	electron‐donor	NOUN
eurjchem-604	950	10	bridging	bridging	NOUN
eurjchem-604	950	11	carbonyl	carbonyl	NOUN
eurjchem-604	950	12	group	group	NOUN
eurjchem-604	950	13	is	be	AUX
eurjchem-604	950	14	also	also	ADV
eurjchem-604	950	15	found	find	VERB
eurjchem-604	950	16	for	for	ADP
eurjchem-604	950	17	cp2mo2(co)3	cp2mo2(co)3	PROPN
eurjchem-604	950	18	.	.	PUNCT
eurjchem-604	951	1	figure	figure	NOUN
eurjchem-604	951	2	12	12	NUM
eurjchem-604	951	3	.	.	PUNCT
eurjchem-604	952	1	x‐ray	x‐ray	ADJ
eurjchem-604	952	2	crystallogh	crystallogh	NOUN
eurjchem-604	952	3	of	of	ADP
eurjchem-604	952	4	cyclopentadienylmolybdenum	cyclopentadienylmolybdenum	ADJ
eurjchem-604	952	5	carbonyls	carbonyls	NOUN
eurjchem-604	952	6	cp2mo2(co)n	cp2mo2(co)n	NOUN
eurjchem-604	952	7	(	(	PUNCT
eurjchem-604	952	8	cp	cp	INTJ
eurjchem-604	952	9	=	=	SYM
eurjchem-604	952	10	η5‐c5h5	η5‐c5h5	PROPN
eurjchem-604	952	11	;	;	PUNCT
eurjchem-604	952	12	n	n	NOUN
eurjchem-604	952	13	=	=	SYM
eurjchem-604	952	14	6‐1	6‐1	NOUN
eurjchem-604	952	15	)	)	PUNCT
eurjchem-604	953	1	[	[	X
eurjchem-604	953	2	292	292	NUM
eurjchem-604	953	3	]	]	PUNCT
eurjchem-604	953	4	.	.	PUNCT
eurjchem-604	954	1	intramolecular	intramolecular	ADJ
eurjchem-604	954	2	carbonylcarbonyl	carbonylcarbonyl	ADJ
eurjchem-604	954	3	interactions	interaction	NOUN
eurjchem-604	954	4	in	in	ADP
eurjchem-604	954	5	w	w	PROPN
eurjchem-604	954	6	,	,	PUNCT
eurjchem-604	954	7	mo	mo	NOUN
eurjchem-604	954	8	and	and	CCONJ
eurjchem-604	954	9	fe	fe	NOUN
eurjchem-604	954	10	complexes	complex	NOUN
eurjchem-604	954	11	containing	contain	VERB
eurjchem-604	954	12	the	the	DET
eurjchem-604	954	13	η1‐n‐maleimidato	η1‐n‐maleimidato	PROPN
eurjchem-604	954	14	ligand	ligand	NOUN
eurjchem-604	954	15	was	be	AUX
eurjchem-604	954	16	found	find	VERB
eurjchem-604	954	17	both	both	PRON
eurjchem-604	954	18	for	for	ADP
eurjchem-604	954	19	experimental	experimental	ADJ
eurjchem-604	954	20	and	and	CCONJ
eurjchem-604	954	21	calculated	calculated	ADJ
eurjchem-604	954	22	structures	structure	NOUN
eurjchem-604	954	23	.	.	PUNCT
eurjchem-604	955	1	it	it	PRON
eurjchem-604	955	2	is	be	AUX
eurjchem-604	955	3	probably	probably	ADV
eurjchem-604	955	4	the	the	DET
eurjchem-604	955	5	first	first	ADJ
eurjchem-604	955	6	approach	approach	NOUN
eurjchem-604	955	7	to	to	PART
eurjchem-604	955	8	explain	explain	VERB
eurjchem-604	955	9	this	this	DET
eurjchem-604	955	10	type	type	NOUN
eurjchem-604	955	11	of	of	ADP
eurjchem-604	955	12	intramolecular	intramolecular	ADJ
eurjchem-604	955	13	interactions	interaction	NOUN
eurjchem-604	955	14	acting	act	VERB
eurjchem-604	955	15	in	in	ADP
eurjchem-604	955	16	organometallic	organometallic	ADJ
eurjchem-604	955	17	compounds	compound	NOUN
eurjchem-604	955	18	.	.	PUNCT
eurjchem-604	956	1	the	the	DET
eurjchem-604	956	2	investigations	investigation	NOUN
eurjchem-604	956	3	indicate	indicate	VERB
eurjchem-604	956	4	also	also	ADV
eurjchem-604	956	5	the	the	DET
eurjchem-604	956	6	differences	difference	NOUN
eurjchem-604	956	7	in	in	ADP
eurjchem-604	956	8	the	the	DET
eurjchem-604	956	9	character	character	NOUN
eurjchem-604	956	10	of	of	ADP
eurjchem-604	956	11	bonding	bonding	NOUN
eurjchem-604	956	12	between	between	ADP
eurjchem-604	956	13	the	the	DET
eurjchem-604	956	14	η‐n‐maleimidato	η‐n‐maleimidato	PROPN
eurjchem-604	956	15	ligand	ligand	NOUN
eurjchem-604	956	16	and	and	CCONJ
eurjchem-604	956	17	the	the	DET
eurjchem-604	956	18	central	central	ADJ
eurjchem-604	956	19	metal	metal	NOUN
eurjchem-604	956	20	atom	atom	NOUN
eurjchem-604	956	21	[	[	X
eurjchem-604	956	22	293	293	NUM
eurjchem-604	956	23	]	]	PUNCT
eurjchem-604	956	24	.	.	PUNCT
eurjchem-604	957	1	the	the	DET
eurjchem-604	957	2	adsorption	adsorption	NOUN
eurjchem-604	957	3	and	and	CCONJ
eurjchem-604	957	4	thermal	thermal	ADJ
eurjchem-604	957	5	behavior	behavior	NOUN
eurjchem-604	957	6	of	of	ADP
eurjchem-604	957	7	(	(	PUNCT
eurjchem-604	957	8	η6‐	η6‐	NOUN
eurjchem-604	957	9	benzene)tricarbonyl	benzene)tricarbonyl	NOUN
eurjchem-604	957	10	chromium	chromium	NOUN
eurjchem-604	957	11	(	(	PUNCT
eurjchem-604	957	12	0	0	NUM
eurjchem-604	957	13	)	)	PUNCT
eurjchem-604	957	14	,	,	PUNCT
eurjchem-604	957	15	(	(	PUNCT
eurjchem-604	957	16	η6‐c6h6)cr(co)3	η6‐c6h6)cr(co)3	PROPN
eurjchem-604	957	17	,	,	PUNCT
eurjchem-604	957	18	inside	inside	ADP
eurjchem-604	957	19	zeolite	zeolite	NOUN
eurjchem-604	957	20	y	y	PROPN
eurjchem-604	957	21	have	have	AUX
eurjchem-604	957	22	been	be	AUX
eurjchem-604	957	23	investigated	investigate	VERB
eurjchem-604	957	24	.	.	PUNCT
eurjchem-604	958	1	the	the	DET
eurjchem-604	958	2	thermal	thermal	ADJ
eurjchem-604	958	3	decomposition	decomposition	NOUN
eurjchem-604	958	4	of	of	ADP
eurjchem-604	958	5	(	(	PUNCT
eurjchem-604	958	6	η6‐c6h6)cr(co)3	η6‐c6h6)cr(co)3	PROPN
eurjchem-604	958	7	in	in	ADP
eurjchem-604	958	8	zeolite	zeolite	NOUN
eurjchem-604	958	9	y	y	PROPN
eurjchem-604	958	10	seems	seem	VERB
eurjchem-604	958	11	strongly	strongly	ADV
eurjchem-604	958	12	dependent	dependent	ADJ
eurjchem-604	958	13	on	on	ADP
eurjchem-604	958	14	the	the	DET
eurjchem-604	958	15	experimental	experimental	ADJ
eurjchem-604	958	16	conditions	condition	NOUN
eurjchem-604	958	17	employed	employ	VERB
eurjchem-604	958	18	:	:	PUNCT
eurjchem-604	958	19	heating	heating	NOUN
eurjchem-604	958	20	(	(	PUNCT
eurjchem-604	958	21	η6‐c6h6)cr(co)3	η6‐c6h6)cr(co)3	PROPN
eurjchem-604	958	22	adsorbed	adsorb	VERB
eurjchem-604	958	23	inside	inside	ADP
eurjchem-604	958	24	zeolite	zeolite	NOUN
eurjchem-604	958	25	y	y	PROPN
eurjchem-604	958	26	in	in	ADP
eurjchem-604	958	27	a	a	DET
eurjchem-604	958	28	schlenk	schlenk	NOUN
eurjchem-604	958	29	tube	tube	NOUN
eurjchem-604	958	30	under	under	ADP
eurjchem-604	958	31	nitrogen	nitrogen	NOUN
eurjchem-604	958	32	flow	flow	NOUN
eurjchem-604	958	33	results	result	NOUN
eurjchem-604	958	34	in	in	ADP
eurjchem-604	958	35	the	the	DET
eurjchem-604	958	36	formation	formation	NOUN
eurjchem-604	958	37	of	of	ADP
eurjchem-604	958	38	benzene	benzene	NOUN
eurjchem-604	958	39	and	and	CCONJ
eurjchem-604	958	40	cr	cr	NOUN
eurjchem-604	958	41	metal	metal	PROPN
eurjchem-604	958	42	,	,	PUNCT
eurjchem-604	958	43	whereas	whereas	SCONJ
eurjchem-604	958	44	heating	heat	VERB
eurjchem-604	958	45	the	the	DET
eurjchem-604	958	46	same	same	ADJ
eurjchem-604	958	47	complex	complex	NOUN
eurjchem-604	958	48	in	in	ADP
eurjchem-604	958	49	a	a	DET
eurjchem-604	958	50	closed	closed	ADJ
eurjchem-604	958	51	vessel	vessel	NOUN
eurjchem-604	958	52	yields	yield	NOUN
eurjchem-604	958	53	a	a	DET
eurjchem-604	958	54	different	different	ADJ
eurjchem-604	958	55	metal	metal	NOUN
eurjchem-604	958	56	carbonyl	carbonyl	NOUN
eurjchem-604	958	57	species	specie	NOUN
eurjchem-604	958	58	,	,	PUNCT
eurjchem-604	958	59	cr(co)6	cr(co)6	X
eurjchem-604	959	1	[	[	X
eurjchem-604	959	2	294	294	NUM
eurjchem-604	959	3	]	]	PUNCT
eurjchem-604	959	4	.	.	PUNCT
eurjchem-604	960	1	the	the	DET
eurjchem-604	960	2	electronic	electronic	ADJ
eurjchem-604	960	3	description	description	NOUN
eurjchem-604	960	4	of	of	ADP
eurjchem-604	960	5	octahedral	octahedral	ADJ
eurjchem-604	960	6	(	(	PUNCT
eurjchem-604	960	7	fac‐	fac‐	NOUN
eurjchem-604	961	1	[	[	X
eurjchem-604	961	2	m(co)3l3]n	m(co)3l3]n	X
eurjchem-604	961	3	,	,	PUNCT
eurjchem-604	961	4	with	with	ADP
eurjchem-604	961	5	m	m	PROPN
eurjchem-604	961	6	=	=	SYM
eurjchem-604	961	7	re	re	PROPN
eurjchem-604	961	8	,	,	PUNCT
eurjchem-604	961	9	ru	ru	PROPN
eurjchem-604	961	10	,	,	PUNCT
eurjchem-604	961	11	and	and	CCONJ
eurjchem-604	961	12	mn	mn	PROPN
eurjchem-604	961	13	,	,	PUNCT
eurjchem-604	961	14	and	and	CCONJ
eurjchem-604	961	15	[	[	X
eurjchem-604	961	16	cr(co)5l]n	cr(co)5l]n	NOUN
eurjchem-604	961	17	)	)	PUNCT
eurjchem-604	961	18	,	,	PUNCT
eurjchem-604	961	19	square‐planar	square‐planar	NOUN
eurjchem-604	961	20	(	(	PUNCT
eurjchem-604	961	21	cis‐	cis‐	NOUN
eurjchem-604	961	22	[	[	X
eurjchem-604	961	23	pt(co)2l2]n	pt(co)2l2]n	NOUN
eurjchem-604	961	24	)	)	PUNCT
eurjchem-604	961	25	,	,	PUNCT
eurjchem-604	961	26	and	and	CCONJ
eurjchem-604	961	27	tetrahedral	tetrahedral	ADJ
eurjchem-604	961	28	(	(	PUNCT
eurjchem-604	961	29	[	[	NOUN
eurjchem-604	961	30	ni(co)3l]n	ni(co)3l]n	NOUN
eurjchem-604	961	31	)	)	PUNCT
eurjchem-604	961	32	carbonyl	carbonyl	NOUN
eurjchem-604	961	33	complexes	complex	NOUN
eurjchem-604	961	34	(	(	PUNCT
eurjchem-604	961	35	where	where	SCONJ
eurjchem-604	961	36	l	l	NOUN
eurjchem-604	961	37	=	=	NOUN
eurjchem-604	961	38	monodentate	monodentate	PROPN
eurjchem-604	961	39	ligand	ligand	NOUN
eurjchem-604	961	40	)	)	PUNCT
eurjchem-604	961	41	was	be	AUX
eurjchem-604	961	42	obtained	obtain	VERB
eurjchem-604	961	43	.	.	PUNCT
eurjchem-604	962	1	the	the	DET
eurjchem-604	962	2	analysis	analysis	NOUN
eurjchem-604	962	3	indicates	indicate	VERB
eurjchem-604	962	4	that	that	SCONJ
eurjchem-604	962	5	while	while	SCONJ
eurjchem-604	962	6	ligand	ligand	ADJ
eurjchem-604	962	7	electronic	electronic	ADJ
eurjchem-604	962	8	parameters	parameter	NOUN
eurjchem-604	962	9	may	may	AUX
eurjchem-604	962	10	be	be	AUX
eurjchem-604	962	11	considered	consider	VERB
eurjchem-604	962	12	as	as	ADP
eurjchem-604	962	13	a	a	DET
eurjchem-604	962	14	measure	measure	NOUN
eurjchem-604	962	15	of	of	ADP
eurjchem-604	962	16	the	the	DET
eurjchem-604	962	17	net	net	ADJ
eurjchem-604	962	18	donor	donor	NOUN
eurjchem-604	962	19	power	power	NOUN
eurjchem-604	962	20	of	of	ADP
eurjchem-604	962	21	the	the	DET
eurjchem-604	962	22	ligand	ligand	NOUN
eurjchem-604	962	23	,	,	PUNCT
eurjchem-604	962	24	the	the	DET
eurjchem-604	962	25	net	net	ADJ
eurjchem-604	962	26	transfer	transfer	NOUN
eurjchem-604	962	27	of	of	ADP
eurjchem-604	962	28	the	the	DET
eurjchem-604	962	29	electron	electron	NOUN
eurjchem-604	962	30	density	density	NOUN
eurjchem-604	962	31	(	(	PUNCT
eurjchem-604	962	32	or	or	CCONJ
eurjchem-604	962	33	charge	charge	NOUN
eurjchem-604	962	34	)	)	PUNCT
eurjchem-604	962	35	does	do	AUX
eurjchem-604	962	36	not	not	PART
eurjchem-604	962	37	occur	occur	VERB
eurjchem-604	962	38	from	from	ADP
eurjchem-604	962	39	the	the	DET
eurjchem-604	962	40	ligand	ligand	NOUN
eurjchem-604	962	41	to	to	ADP
eurjchem-604	962	42	the	the	DET
eurjchem-604	962	43	metal	metal	NOUN
eurjchem-604	962	44	ion	ion	NOUN
eurjchem-604	962	45	.	.	PUNCT
eurjchem-604	963	1	in	in	ADP
eurjchem-604	963	2	[	[	PUNCT
eurjchem-604	963	3	m(co)xly]n	m(co)xly]n	ADJ
eurjchem-604	963	4	carbonyl	carbonyl	NOUN
eurjchem-604	963	5	species	specie	NOUN
eurjchem-604	963	6	,	,	PUNCT
eurjchem-604	963	7	the	the	DET
eurjchem-604	963	8	charge	charge	NOUN
eurjchem-604	963	9	transfer	transfer	NOUN
eurjchem-604	963	10	occurs	occur	VERB
eurjchem-604	963	11	from	from	ADP
eurjchem-604	963	12	the	the	DET
eurjchem-604	963	13	ligand	ligand	ADJ
eurjchem-604	963	14	l	l	NOUN
eurjchem-604	963	15	to	to	ADP
eurjchem-604	963	16	the	the	DET
eurjchem-604	963	17	oxygen	oxygen	NOUN
eurjchem-604	963	18	atom	atom	NOUN
eurjchem-604	963	19	of	of	ADP
eurjchem-604	963	20	the	the	DET
eurjchem-604	963	21	bound	bind	VERB
eurjchem-604	963	22	carbon	carbon	NOUN
eurjchem-604	963	23	monoxides	monoxide	NOUN
eurjchem-604	963	24	.	.	PUNCT
eurjchem-604	964	1	this	this	DET
eurjchem-604	964	2	charge	charge	NOUN
eurjchem-604	964	3	transfer	transfer	NOUN
eurjchem-604	964	4	translates	translate	VERB
eurjchem-604	964	5	into	into	ADP
eurjchem-604	964	6	changes	change	NOUN
eurjchem-604	964	7	of	of	ADP
eurjchem-604	964	8	the	the	DET
eurjchem-604	964	9	polarization	polarization	NOUN
eurjchem-604	964	10	(	(	PUNCT
eurjchem-604	964	11	or	or	CCONJ
eurjchem-604	964	12	permanent	permanent	ADJ
eurjchem-604	964	13	dipole	dipole	NOUN
eurjchem-604	964	14	)	)	PUNCT
eurjchem-604	964	15	and	and	CCONJ
eurjchem-604	964	16	the	the	DET
eurjchem-604	964	17	covalency	covalency	NOUN
eurjchem-604	964	18	of	of	ADP
eurjchem-604	964	19	the	the	DET
eurjchem-604	964	20	c≡o	c≡o	PROPN
eurjchem-604	964	21	bonds	bond	NOUN
eurjchem-604	964	22	,	,	PUNCT
eurjchem-604	964	23	and	and	CCONJ
eurjchem-604	964	24	it	it	PRON
eurjchem-604	964	25	is	be	AUX
eurjchem-604	964	26	this	this	DET
eurjchem-604	964	27	effect	effect	NOUN
eurjchem-604	964	28	that	that	PRON
eurjchem-604	964	29	is	be	AUX
eurjchem-604	964	30	probed	probe	VERB
eurjchem-604	964	31	in	in	ADP
eurjchem-604	964	32	ir	ir	PROPN
eurjchem-604	964	33	spectroscopy	spectroscopy	NOUN
eurjchem-604	964	34	.	.	PUNCT
eurjchem-604	965	1	as	as	ADP
eurjchem-604	965	2	the	the	DET
eurjchem-604	965	3	analysis	analysis	NOUN
eurjchem-604	965	4	shifts	shift	NOUN
eurjchem-604	965	5	from	from	ADP
eurjchem-604	965	6	ir	ir	PROPN
eurjchem-604	965	7	radiations	radiation	NOUN
eurjchem-604	965	8	to	to	ADP
eurjchem-604	965	9	electrochemical	electrochemical	ADJ
eurjchem-604	965	10	potentials	potential	NOUN
eurjchem-604	965	11	,	,	PUNCT
eurjchem-604	965	12	the	the	DET
eurjchem-604	965	13	parameters	parameter	NOUN
eurjchem-604	965	14	best	well	ADV
eurjchem-604	965	15	describe	describe	VERB
eurjchem-604	965	16	the	the	DET
eurjchem-604	965	17	relative	relative	ADJ
eurjchem-604	965	18	thermodynamic	thermodynamic	ADJ
eurjchem-604	965	19	stability	stability	NOUN
eurjchem-604	965	20	of	of	ADP
eurjchem-604	965	21	the	the	DET
eurjchem-604	965	22	oxidized	oxidize	VERB
eurjchem-604	965	23	and	and	CCONJ
eurjchem-604	965	24	reduced	reduce	VERB
eurjchem-604	965	25	[	[	X
eurjchem-604	965	26	m(co)xly]n	m(co)xly]n	NUM
eurjchem-604	965	27	/	/	SYM
eurjchem-604	965	28	n+1	n+1	PROPN
eurjchem-604	965	29	species	specie	NOUN
eurjchem-604	965	30	.	.	PUNCT
eurjchem-604	966	1	no	no	DET
eurjchem-604	966	2	relationship	relationship	NOUN
eurjchem-604	966	3	is	be	AUX
eurjchem-604	966	4	found	find	VERB
eurjchem-604	966	5	between	between	ADP
eurjchem-604	966	6	the	the	DET
eurjchem-604	966	7	metal	metal	NOUN
eurjchem-604	966	8	natural	natural	ADJ
eurjchem-604	966	9	charge	charge	NOUN
eurjchem-604	966	10	of	of	ADP
eurjchem-604	966	11	the	the	PRON
eurjchem-604	966	12	[	[	X
eurjchem-604	966	13	m(co)xly]n	m(co)xly]n	ADJ
eurjchem-604	966	14	fragments	fragment	NOUN
eurjchem-604	966	15	analyzed	analyze	VERB
eurjchem-604	966	16	and	and	CCONJ
eurjchem-604	966	17	the	the	DET
eurjchem-604	966	18	parameters	parameter	NOUN
eurjchem-604	966	19	[	[	X
eurjchem-604	966	20	295	295	NUM
eurjchem-604	966	21	]	]	PUNCT
eurjchem-604	966	22	.	.	PUNCT
eurjchem-604	967	1	the	the	DET
eurjchem-604	967	2	reactivity	reactivity	NOUN
eurjchem-604	967	3	of	of	ADP
eurjchem-604	967	4	a	a	DET
eurjchem-604	967	5	nucleophilic	nucleophilic	ADJ
eurjchem-604	967	6	nickel	nickel	NOUN
eurjchem-604	967	7	acylate	acylate	NOUN
eurjchem-604	967	8	complex	complex	NOUN
eurjchem-604	967	9	with	with	ADP
eurjchem-604	967	10	a	a	DET
eurjchem-604	967	11	tungsten	tungsten	ADJ
eurjchem-604	967	12	carbene	carbene	NOUN
eurjchem-604	967	13	complex	complex	NOUN
eurjchem-604	967	14	,	,	PUNCT
eurjchem-604	967	15	fe(co)5	fe(co)5	ADJ
eurjchem-604	967	16	,	,	PUNCT
eurjchem-604	967	17	cr(co)6	cr(co)6	NOUN
eurjchem-604	967	18	,	,	PUNCT
eurjchem-604	967	19	pph3	pph3	NOUN
eurjchem-604	967	20	,	,	PUNCT
eurjchem-604	967	21	and	and	CCONJ
eurjchem-604	967	22	co	co	NOUN
eurjchem-604	967	23	was	be	AUX
eurjchem-604	967	24	investigated	investigate	VERB
eurjchem-604	967	25	.	.	PUNCT
eurjchem-604	968	1	with	with	ADP
eurjchem-604	968	2	the	the	DET
eurjchem-604	968	3	tungsten	tungsten	ADJ
eurjchem-604	968	4	carbene	carbene	NOUN
eurjchem-604	968	5	complex	complex	NOUN
eurjchem-604	968	6	,	,	PUNCT
eurjchem-604	968	7	a	a	DET
eurjchem-604	968	8	methyl	methyl	NOUN
eurjchem-604	968	9	transfer	transfer	NOUN
eurjchem-604	968	10	occurred	occur	VERB
eurjchem-604	968	11	.	.	PUNCT
eurjchem-604	969	1	with	with	ADP
eurjchem-604	969	2	the	the	DET
eurjchem-604	969	3	metal	metal	NOUN
eurjchem-604	969	4	carbonyl	carbonyl	NOUN
eurjchem-604	969	5	complexes	complex	NOUN
eurjchem-604	969	6	,	,	PUNCT
eurjchem-604	969	7	the	the	DET
eurjchem-604	969	8	acylate	acylate	ADJ
eurjchem-604	969	9	group	group	NOUN
eurjchem-604	969	10	on	on	ADP
eurjchem-604	969	11	the	the	DET
eurjchem-604	969	12	nickel	nickel	NOUN
eurjchem-604	969	13	and	and	CCONJ
eurjchem-604	969	14	a	a	DET
eurjchem-604	969	15	carbonyl	carbonyl	NOUN
eurjchem-604	969	16	on	on	ADP
eurjchem-604	969	17	the	the	DET
eurjchem-604	969	18	iron	iron	NOUN
eurjchem-604	969	19	or	or	CCONJ
eurjchem-604	969	20	chromium	chromium	NOUN
eurjchem-604	969	21	traded	trade	VERB
eurjchem-604	969	22	places	place	NOUN
eurjchem-604	969	23	.	.	PUNCT
eurjchem-604	970	1	with	with	ADP
eurjchem-604	970	2	the	the	DET
eurjchem-604	970	3	pph3	pph3	NOUN
eurjchem-604	970	4	and	and	CCONJ
eurjchem-604	970	5	co	co	NOUN
eurjchem-604	970	6	,	,	PUNCT
eurjchem-604	970	7	the	the	DET
eurjchem-604	970	8	acylate	acylate	ADJ
eurjchem-604	970	9	anion	anion	NOUN
eurjchem-604	970	10	was	be	AUX
eurjchem-604	970	11	replaced	replace	VERB
eurjchem-604	970	12	by	by	ADP
eurjchem-604	970	13	the	the	DET
eurjchem-604	970	14	phosphine	phosphine	NOUN
eurjchem-604	970	15	or	or	CCONJ
eurjchem-604	970	16	co	co	ADJ
eurjchem-604	970	17	ligand	ligand	PROPN
eurjchem-604	970	18	(	(	PUNCT
eurjchem-604	970	19	scheme	scheme	NOUN
eurjchem-604	970	20	74	74	NUM
eurjchem-604	970	21	)	)	PUNCT
eurjchem-604	971	1	[	[	X
eurjchem-604	971	2	296	296	NUM
eurjchem-604	971	3	]	]	PUNCT
eurjchem-604	971	4	.	.	PUNCT
eurjchem-604	972	1	scheme	scheme	NOUN
eurjchem-604	972	2	74	74	NUM
eurjchem-604	972	3	8	8	NUM
eurjchem-604	972	4	.	.	PUNCT
eurjchem-604	973	1	conclusion	conclusion	NOUN
eurjchem-604	973	2	the	the	DET
eurjchem-604	973	3	g‐vib	g‐vib	ADJ
eurjchem-604	973	4	metal	metal	NOUN
eurjchem-604	973	5	carbonyl	carbonyl	NOUN
eurjchem-604	973	6	complexes	complex	NOUN
eurjchem-604	973	7	are	be	AUX
eurjchem-604	973	8	of	of	ADP
eurjchem-604	973	9	great	great	ADJ
eurjchem-604	973	10	interest	interest	NOUN
eurjchem-604	973	11	toscientists	toscientist	NOUN
eurjchem-604	973	12	since	since	SCONJ
eurjchem-604	973	13	last	last	ADJ
eurjchem-604	973	14	5	5	NUM
eurjchem-604	973	15	decades	decade	NOUN
eurjchem-604	973	16	,	,	PUNCT
eurjchem-604	973	17	and	and	CCONJ
eurjchem-604	973	18	various	various	ADJ
eurjchem-604	973	19	studies	study	NOUN
eurjchem-604	973	20	have	have	AUX
eurjchem-604	973	21	been	be	AUX
eurjchem-604	973	22	done	do	VERB
eurjchem-604	973	23	on	on	ADP
eurjchem-604	973	24	these	these	DET
eurjchem-604	973	25	molecules	molecule	NOUN
eurjchem-604	973	26	.	.	PUNCT
eurjchem-604	974	1	the	the	DET
eurjchem-604	974	2	successful	successful	ADJ
eurjchem-604	974	3	development	development	NOUN
eurjchem-604	974	4	of	of	ADP
eurjchem-604	974	5	metal	metal	NOUN
eurjchem-604	974	6	carbonyl	carbonyl	NOUN
eurjchem-604	974	7	complexes	complex	NOUN
eurjchem-604	974	8	and	and	CCONJ
eurjchem-604	974	9	their	their	PRON
eurjchem-604	974	10	products	product	NOUN
eurjchem-604	974	11	has	have	AUX
eurjchem-604	974	12	been	be	AUX
eurjchem-604	974	13	demonstrated	demonstrate	VERB
eurjchem-604	974	14	by	by	ADP
eurjchem-604	974	15	various	various	ADJ
eurjchem-604	974	16	examples	example	NOUN
eurjchem-604	974	17	of	of	ADP
eurjchem-604	974	18	recent	recent	ADJ
eurjchem-604	974	19	literature	literature	NOUN
eurjchem-604	974	20	.	.	PUNCT
eurjchem-604	975	1	the	the	DET
eurjchem-604	975	2	review	review	NOUN
eurjchem-604	975	3	article	article	NOUN
eurjchem-604	975	4	highlights	highlight	VERB
eurjchem-604	975	5	various	various	ADJ
eurjchem-604	975	6	types	type	NOUN
eurjchem-604	975	7	of	of	ADP
eurjchem-604	975	8	metal	metal	NOUN
eurjchem-604	975	9	carbonyl	carbonyl	NOUN
eurjchem-604	975	10	complexes	complex	NOUN
eurjchem-604	975	11	,	,	PUNCT
eurjchem-604	975	12	complexation	complexation	NOUN
eurjchem-604	975	13	agents	agent	NOUN
eurjchem-604	975	14	and	and	CCONJ
eurjchem-604	975	15	substitution	substitution	NOUN
eurjchem-604	975	16	reactions	reaction	NOUN
eurjchem-604	975	17	of	of	ADP
eurjchem-604	975	18	g‐vib	g‐vib	ADJ
eurjchem-604	975	19	metal	metal	NOUN
eurjchem-604	975	20	carbonyls	carbonyls	NOUN
eurjchem-604	975	21	with	with	ADP
eurjchem-604	975	22	various	various	ADJ
eurjchem-604	975	23	ligands	ligand	NOUN
eurjchem-604	975	24	.	.	PUNCT
eurjchem-604	976	1	this	this	DET
eurjchem-604	976	2	review	review	NOUN
eurjchem-604	976	3	has	have	AUX
eurjchem-604	976	4	given	give	VERB
eurjchem-604	976	5	just	just	ADV
eurjchem-604	976	6	a	a	DET
eurjchem-604	976	7	few	few	ADJ
eurjchem-604	976	8	examples	example	NOUN
eurjchem-604	976	9	of	of	ADP
eurjchem-604	976	10	what	what	PRON
eurjchem-604	976	11	is	be	AUX
eurjchem-604	976	12	being	be	AUX
eurjchem-604	976	13	done	do	VERB
eurjchem-604	976	14	in	in	ADP
eurjchem-604	976	15	the	the	DET
eurjchem-604	976	16	area	area	NOUN
eurjchem-604	976	17	as	as	SCONJ
eurjchem-604	976	18	we	we	PRON
eurjchem-604	976	19	change	change	VERB
eurjchem-604	976	20	to	to	ADP
eurjchem-604	976	21	our	our	PRON
eurjchem-604	976	22	work	work	NOUN
eurjchem-604	976	23	of	of	ADP
eurjchem-604	976	24	the	the	DET
eurjchem-604	976	25	future	future	NOUN
eurjchem-604	976	26	.	.	PUNCT
eurjchem-604	977	1	acknowledgements	acknowledgement	NOUN
eurjchem-604	977	2	sincere	sincere	ADJ
eurjchem-604	977	3	thanks	thank	NOUN
eurjchem-604	977	4	are	be	AUX
eurjchem-604	977	5	due	due	ADJ
eurjchem-604	977	6	to	to	ADP
eurjchem-604	977	7	dr	dr	PROPN
eurjchem-604	977	8	.	.	PROPN
eurjchem-604	977	9	chandrawati	chandrawati	PROPN
eurjchem-604	977	10	,	,	PUNCT
eurjchem-604	977	11	head	head	NOUN
eurjchem-604	977	12	,	,	PUNCT
eurjchem-604	977	13	department	department	NOUN
eurjchem-604	977	14	of	of	ADP
eurjchem-604	977	15	chemistry	chemistry	NOUN
eurjchem-604	977	16	,	,	PUNCT
eurjchem-604	977	17	durga	durga	PROPN
eurjchem-604	977	18	prasad	prasad	PROPN
eurjchem-604	977	19	baljeet	baljeet	PROPN
eurjchem-604	977	20	singh	singh	PROPN
eurjchem-604	977	21	post	post	PROPN
eurjchem-604	977	22	graduate	graduate	PROPN
eurjchem-604	977	23	college	college	NOUN
eurjchem-604	977	24	,	,	PUNCT
eurjchem-604	977	25	anoopshahar	anoopshahar	PROPN
eurjchem-604	977	26	,	,	PUNCT
eurjchem-604	977	27	bulandshahar	bulandshahar	NOUN
eurjchem-604	977	28	,	,	PUNCT
eurjchem-604	977	29	uttarpradesh	uttarpradesh	PRON
eurjchem-604	977	30	,	,	PUNCT
eurjchem-604	977	31	india	india	PROPN
eurjchem-604	977	32	and	and	CCONJ
eurjchem-604	977	33	mr	mr	PROPN
eurjchem-604	977	34	.	.	PROPN
eurjchem-604	977	35	pradeep	pradeep	PROPN
eurjchem-604	977	36	kumar	kumar	PROPN
eurjchem-604	977	37	mathur	mathur	PROPN
eurjchem-604	977	38	,	,	PUNCT
eurjchem-604	977	39	head	head	NOUN
eurjchem-604	977	40	,	,	PUNCT
eurjchem-604	977	41	department	department	NOUN
eurjchem-604	977	42	of	of	ADP
eurjchem-604	977	43	chemistry	chemistry	NOUN
eurjchem-604	977	44	,	,	PUNCT
eurjchem-604	977	45	mahanand	mahanand	NOUN
eurjchem-604	977	46	mission	mission	PROPN
eurjchem-604	977	47	harijan	harijan	PROPN
eurjchem-604	977	48	college	college	PROPN
eurjchem-604	977	49	,	,	PUNCT
eurjchem-604	977	50	ghaziabad	ghaziabad	PROPN
eurjchem-604	977	51	,	,	PUNCT
eurjchem-604	977	52	uttarpradesh	uttarpradesh	PROPN
eurjchem-604	977	53	,	,	PUNCT
eurjchem-604	977	54	india	india	PROPN
eurjchem-604	977	55	,	,	PUNCT
eurjchem-604	977	56	for	for	ADP
eurjchem-604	977	57	providing	provide	VERB
eurjchem-604	977	58	research	research	NOUN
eurjchem-604	977	59	facilities	facility	NOUN
eurjchem-604	977	60	.	.	PUNCT
eurjchem-604	978	1	authors	author	NOUN
eurjchem-604	978	2	are	be	AUX
eurjchem-604	978	3	also	also	ADV
eurjchem-604	978	4	thankful	thankful	ADJ
eurjchem-604	978	5	to	to	ADP
eurjchem-604	978	6	dr	dr	PROPN
eurjchem-604	978	7	.	.	PROPN
eurjchem-604	978	8	kushal	kushal	PROPN
eurjchem-604	978	9	pal	pal	PROPN
eurjchem-604	978	10	singh	singh	PROPN
eurjchem-604	978	11	,	,	PUNCT
eurjchem-604	978	12	principal	principal	NOUN
eurjchem-604	978	13	,	,	PUNCT
eurjchem-604	978	14	durga	durga	PROPN
eurjchem-604	978	15	prasad	prasad	PROPN
eurjchem-604	978	16	baljeet	baljeet	PROPN
eurjchem-604	978	17	singh	singh	PROPN
eurjchem-604	978	18	post	post	PROPN
eurjchem-604	978	19	graduate	graduate	PROPN
eurjchem-604	978	20	college	college	NOUN
eurjchem-604	978	21	,	,	PUNCT
eurjchem-604	978	22	anoopshahar	anoopshahar	PROPN
eurjchem-604	978	23	,	,	PUNCT
eurjchem-604	978	24	bulandshahar	bulandshahar	NOUN
eurjchem-604	978	25	,	,	PUNCT
eurjchem-604	978	26	uttarpradesh	uttarpradesh	PRON
eurjchem-604	978	27	,	,	PUNCT
eurjchem-604	978	28	india	india	PROPN
eurjchem-604	978	29	,	,	PUNCT
eurjchem-604	978	30	for	for	ADP
eurjchem-604	978	31	his	his	PRON
eurjchem-604	978	32	constant	constant	ADJ
eurjchem-604	978	33	encouragement	encouragement	NOUN
eurjchem-604	978	34	to	to	PART
eurjchem-604	978	35	carry	carry	VERB
eurjchem-604	978	36	out	out	ADP
eurjchem-604	978	37	such	such	ADJ
eurjchem-604	978	38	research	research	NOUN
eurjchem-604	978	39	work	work	NOUN
eurjchem-604	978	40	.	.	PUNCT
eurjchem-604	979	1	special	special	ADJ
eurjchem-604	979	2	thanks	thank	NOUN
eurjchem-604	979	3	retracted	retract	VERB
eurjchem-604	979	4	kaushik	kaushik	PROPN
eurjchem-604	979	5	et	et	PROPN
eurjchem-604	979	6	al	al	PROPN
eurjchem-604	979	7	.	.	PUNCT
eurjchem-604	979	8	/	/	SYM
eurjchem-604	979	9	european	european	PROPN
eurjchem-604	979	10	journal	journal	PROPN
eurjchem-604	979	11	of	of	ADP
eurjchem-604	979	12	chemistry	chemistry	NOUN
eurjchem-604	979	13	3	3	NUM
eurjchem-604	979	14	(	(	PUNCT
eurjchem-604	979	15	3	3	NUM
eurjchem-604	979	16	)	)	PUNCT
eurjchem-604	979	17	(	(	PUNCT
eurjchem-604	979	18	2012	2012	NUM
eurjchem-604	979	19	)	)	PUNCT
eurjchem-604	979	20	367‐394	367‐394	NOUN
eurjchem-604	979	21	391	391	NUM
eurjchem-604	979	22	are	be	AUX
eurjchem-604	979	23	also	also	ADV
eurjchem-604	979	24	due	due	ADJ
eurjchem-604	979	25	to	to	ADP
eurjchem-604	979	26	central	central	ADJ
eurjchem-604	979	27	drug	drug	NOUN
eurjchem-604	979	28	and	and	CCONJ
eurjchem-604	979	29	research	research	NOUN
eurjchem-604	979	30	institute	institute	PROPN
eurjchem-604	979	31	,	,	PUNCT
eurjchem-604	979	32	lucknow	lucknow	PROPN
eurjchem-604	979	33	,	,	PUNCT
eurjchem-604	979	34	india	india	PROPN
eurjchem-604	979	35	;	;	PUNCT
eurjchem-604	979	36	intertek	intertek	PROPN
eurjchem-604	979	37	,	,	PUNCT
eurjchem-604	979	38	mumbai	mumbai	PROPN
eurjchem-604	979	39	,	,	PUNCT
eurjchem-604	979	40	india	india	PROPN
eurjchem-604	979	41	and	and	CCONJ
eurjchem-604	979	42	tata	tata	PROPN
eurjchem-604	979	43	institute	institute	PROPN
eurjchem-604	979	44	of	of	ADP
eurjchem-604	979	45	fundamental	fundamental	ADJ
eurjchem-604	979	46	research	research	NOUN
eurjchem-604	979	47	,	,	PUNCT
eurjchem-604	979	48	mumbai	mumbai	PROPN
eurjchem-604	979	49	,	,	PUNCT
eurjchem-604	979	50	india	india	PROPN
eurjchem-604	979	51	for	for	ADP
eurjchem-604	979	52	allocation	allocation	NOUN
eurjchem-604	979	53	of	of	ADP
eurjchem-604	979	54	time	time	NOUN
eurjchem-604	979	55	for	for	ADP
eurjchem-604	979	56	various	various	ADJ
eurjchem-604	979	57	analyses	analysis	NOUN
eurjchem-604	979	58	.	.	PUNCT
eurjchem-604	980	1	references	reference	NOUN
eurjchem-604	980	2	[	[	X
eurjchem-604	980	3	1	1	NUM
eurjchem-604	980	4	]	]	PUNCT
eurjchem-604	980	5	.	.	PUNCT
eurjchem-604	981	1	elschenbroich	elschenbroich	PROPN
eurjchem-604	981	2	,	,	PUNCT
eurjchem-604	981	3	c.	c.	PROPN
eurjchem-604	981	4	,	,	PUNCT
eurjchem-604	981	5	organometallics	organometallic	NOUN
eurjchem-604	981	6	,	,	PUNCT
eurjchem-604	981	7	wiley‐vch	wiley‐vch	PROPN
eurjchem-604	981	8	,	,	PUNCT
eurjchem-604	981	9	weinheim	weinheim	NOUN
eurjchem-604	981	10	,	,	PUNCT
eurjchem-604	981	11	2006	2006	NUM
eurjchem-604	981	12	.	.	PUNCT
eurjchem-604	982	1	[	[	X
eurjchem-604	982	2	2	2	NUM
eurjchem-604	982	3	]	]	PUNCT
eurjchem-604	982	4	.	.	PUNCT
eurjchem-604	982	5	trout	trout	PROPN
eurjchem-604	982	6	,	,	PUNCT
eurjchem-604	982	7	w.	w.	PROPN
eurjchem-604	982	8	e.	e.	PROPN
eurjchem-604	982	9	j.	j.	PROPN
eurjchem-604	982	10	chem	chem	PROPN
eurjchem-604	982	11	.	.	PUNCT
eurjchem-604	983	1	educ	educ	PROPN
eurjchem-604	983	2	.	.	PUNCT
eurjchem-604	984	1	1937	1937	NUM
eurjchem-604	984	2	,	,	PUNCT
eurjchem-604	984	3	14(10	14(10	NUM
eurjchem-604	984	4	)	)	PUNCT
eurjchem-604	984	5	,	,	PUNCT
eurjchem-604	984	6	453‐458	453‐458	NOUN
eurjchem-604	984	7	.	.	PUNCT
eurjchem-604	985	1	[	[	X
eurjchem-604	985	2	3	3	NUM
eurjchem-604	985	3	]	]	PUNCT
eurjchem-604	985	4	.	.	PUNCT
eurjchem-604	986	1	whitaker	whitaker	PROPN
eurjchem-604	986	2	,	,	PUNCT
eurjchem-604	986	3	a.	a.	NOUN
eurjchem-604	986	4	;	;	PUNCT
eurjchem-604	986	5	jeffery	jeffery	PROPN
eurjchem-604	986	6	,	,	PUNCT
eurjchem-604	986	7	j.	j.	PROPN
eurjchem-604	986	8	w.	w.	PROPN
eurjchem-604	986	9	acta	acta	PROPN
eurjchem-604	986	10	crystallogr	crystallogr	PROPN
eurjchem-604	986	11	.	.	PUNCT
eurjchem-604	987	1	1967	1967	NUM
eurjchem-604	987	2	,	,	PUNCT
eurjchem-604	987	3	23	23	NUM
eurjchem-604	987	4	,	,	PUNCT
eurjchem-604	987	5	977‐984	977‐984	NUM
eurjchem-604	987	6	.	.	PUNCT
eurjchem-604	988	1	[	[	X
eurjchem-604	988	2	4	4	NUM
eurjchem-604	988	3	]	]	PUNCT
eurjchem-604	988	4	.	.	PUNCT
eurjchem-604	989	1	patnaik	patnaik	PROPN
eurjchem-604	989	2	,	,	PUNCT
eurjchem-604	989	3	p.	p.	PROPN
eurjchem-604	989	4	a	a	DET
eurjchem-604	989	5	comprehensive	comprehensive	ADJ
eurjchem-604	989	6	guide	guide	NOUN
eurjchem-604	989	7	to	to	ADP
eurjchem-604	989	8	the	the	DET
eurjchem-604	989	9	hazardous	hazardous	ADJ
eurjchem-604	989	10	properties	property	NOUN
eurjchem-604	989	11	of	of	ADP
eurjchem-604	989	12	chemical	chemical	ADJ
eurjchem-604	989	13	substances	substance	NOUN
eurjchem-604	989	14	,	,	PUNCT
eurjchem-604	989	15	3rd	3rd	ADJ
eurjchem-604	989	16	edn	edn	NOUN
eurjchem-604	989	17	.	.	PUNCT
eurjchem-604	989	18	,	,	PUNCT
eurjchem-604	989	19	wiley	wiley	PROPN
eurjchem-604	989	20	,	,	PUNCT
eurjchem-604	989	21	pp	pp	ADJ
eurjchem-604	989	22	.	.	PUNCT
eurjchem-604	989	23	626	626	NUM
eurjchem-604	989	24	,	,	PUNCT
eurjchem-604	989	25	2007	2007	NUM
eurjchem-604	989	26	.	.	PUNCT
eurjchem-604	990	1	[	[	X
eurjchem-604	990	2	5	5	NUM
eurjchem-604	990	3	]	]	PUNCT
eurjchem-604	990	4	.	.	PUNCT
eurjchem-604	990	5	brimm	brimm	PROPN
eurjchem-604	990	6	,	,	PUNCT
eurjchem-604	990	7	e.	e.	PROPN
eurjchem-604	990	8	o.	o.	PROPN
eurjchem-604	990	9	;	;	PUNCT
eurjchem-604	990	10	lynch	lynch	PROPN
eurjchem-604	990	11	,	,	PUNCT
eurjchem-604	990	12	m.	m.	NOUN
eurjchem-604	990	13	a.	a.	NOUN
eurjchem-604	990	14	;	;	PUNCT
eurjchem-604	990	15	sesny	sesny	NOUN
eurjchem-604	990	16	,	,	PUNCT
eurjchem-604	990	17	w.	w.	PROPN
eurjchem-604	990	18	j.	j.	PROPN
eurjchem-604	990	19	,	,	PUNCT
eurjchem-604	990	20	process	process	NOUN
eurjchem-604	990	21	for	for	ADP
eurjchem-604	990	22	preparing	prepare	VERB
eurjchem-604	990	23	chromium	chromium	NOUN
eurjchem-604	990	24	carbonyl	carbonyl	NOUN
eurjchem-604	990	25	,	,	PUNCT
eurjchem-604	990	26	united	united	PROPN
eurjchem-604	990	27	states	states	PROPN
eurjchem-604	990	28	patent	patent	NOUN
eurjchem-604	990	29	2803525	2803525	NUM
eurjchem-604	990	30	,	,	PUNCT
eurjchem-604	990	31	aug	aug	PROPN
eurjchem-604	990	32	.	.	PROPN
eurjchem-604	990	33	29	29	NUM
eurjchem-604	990	34	,	,	PUNCT
eurjchem-604	990	35	1961	1961	NUM
eurjchem-604	990	36	.	.	PUNCT
eurjchem-604	991	1	[	[	X
eurjchem-604	991	2	6	6	NUM
eurjchem-604	991	3	]	]	PUNCT
eurjchem-604	991	4	.	.	PUNCT
eurjchem-604	992	1	patnaik	patnaik	PROPN
eurjchem-604	992	2	,	,	PUNCT
eurjchem-604	992	3	p.	p.	NOUN
eurjchem-604	992	4	chromium	chromium	NOUN
eurjchem-604	992	5	hexacarbonyl	hexacarbonyl	NOUN
eurjchem-604	992	6	.	.	PUNCT
eurjchem-604	993	1	handbook	handbook	NOUN
eurjchem-604	993	2	of	of	ADP
eurjchem-604	993	3	inorganic	inorganic	ADJ
eurjchem-604	993	4	chemicals	chemical	NOUN
eurjchem-604	993	5	.	.	PUNCT
eurjchem-604	994	1	mcgraw‐hill	mcgraw‐hill	PROPN
eurjchem-604	994	2	professional	professional	PROPN
eurjchem-604	994	3	.	.	PUNCT
eurjchem-604	995	1	pp	pp	X
eurjchem-604	995	2	.	.	PUNCT
eurjchem-604	996	1	222–223	222–223	NUM
eurjchem-604	996	2	,	,	PUNCT
eurjchem-604	996	3	2003	2003	NUM
eurjchem-604	996	4	.	.	PUNCT
eurjchem-604	997	1	[	[	X
eurjchem-604	997	2	7	7	NUM
eurjchem-604	997	3	]	]	PUNCT
eurjchem-604	997	4	.	.	PUNCT
eurjchem-604	998	1	chromium	chromium	NOUN
eurjchem-604	998	2	(	(	PUNCT
eurjchem-604	998	3	iii	iii	NOUN
eurjchem-604	998	4	)	)	PUNCT
eurjchem-604	998	5	and	and	CCONJ
eurjchem-604	998	6	compounds	compound	VERB
eurjchem-604	998	7	fact	fact	NOUN
eurjchem-604	998	8	sheet	sheet	NOUN
eurjchem-604	998	9	,	,	PUNCT
eurjchem-604	998	10	national	national	ADJ
eurjchem-604	998	11	pollutant	pollutant	ADJ
eurjchem-604	998	12	inventory	inventory	NOUN
eurjchem-604	998	13	(	(	PUNCT
eurjchem-604	998	14	http://www	http://www	PROPN
eurjchem-604	998	15	.	.	PUNCT
eurjchem-604	999	1	npi	npi	PROPN
eurjchem-604	999	2	.	.	PROPN
eurjchem-604	999	3	gov	gov	PROPN
eurjchem-604	999	4	.	.	PROPN
eurjchem-604	999	5	au	au	PROPN
eurjchem-604	999	6	/	/	SYM
eurjchem-604	999	7	database	database	NOUN
eurjchem-604	999	8	/	/	SYM
eurjchem-604	999	9	substance‐	substance‐	NOUN
eurjchem-604	999	10	info	info	NOUN
eurjchem-604	999	11	/	/	SYM
eurjchem-604	999	12	profiles/24	profiles/24	PROPN
eurjchem-604	999	13	.	.	PUNCT
eurjchem-604	1000	1	html	html	NOUN
eurjchem-604	1000	2	)	)	PUNCT
eurjchem-604	1000	3	.	.	PUNCT
eurjchem-604	1001	1	[	[	X
eurjchem-604	1001	2	8	8	NUM
eurjchem-604	1001	3	]	]	PUNCT
eurjchem-604	1001	4	.	.	PUNCT
eurjchem-604	1002	1	hurd	hurd	PROPN
eurjchem-604	1002	2	,	,	PUNCT
eurjchem-604	1002	3	d.	d.	PROPN
eurjchem-604	1002	4	t.	t.	PROPN
eurjchem-604	1002	5	,	,	PUNCT
eurjchem-604	1002	6	synthesis	synthesis	NOUN
eurjchem-604	1002	7	of	of	ADP
eurjchem-604	1002	8	molybdenum	molybdenum	NOUN
eurjchem-604	1002	9	and	and	CCONJ
eurjchem-604	1002	10	tungsten	tungsten	NOUN
eurjchem-604	1002	11	carbonyls	carbonyls	NOUN
eurjchem-604	1002	12	,	,	PUNCT
eurjchem-604	1002	13	united	united	PROPN
eurjchem-604	1002	14	states	states	PROPN
eurjchem-604	1002	15	patent	patent	PROPN
eurjchem-604	1002	16	2554194	2554194	NUM
eurjchem-604	1002	17	,	,	PUNCT
eurjchem-604	1002	18	may	may	AUX
eurjchem-604	1002	19	.	.	PUNCT
eurjchem-604	1002	20	22	22	NUM
eurjchem-604	1002	21	,	,	PUNCT
eurjchem-604	1002	22	1951	1951	NUM
eurjchem-604	1002	23	.	.	PUNCT
eurjchem-604	1003	1	[	[	X
eurjchem-604	1003	2	9	9	NUM
eurjchem-604	1003	3	]	]	PUNCT
eurjchem-604	1003	4	.	.	PUNCT
eurjchem-604	1004	1	randolph	randolph	PROPN
eurjchem-604	1004	2	,	,	PUNCT
eurjchem-604	1004	3	s.	s.	PROPN
eurjchem-604	1004	4	;	;	PUNCT
eurjchem-604	1004	5	fowlkes	fowlke	NOUN
eurjchem-604	1004	6	,	,	PUNCT
eurjchem-604	1004	7	j.	j.	PROPN
eurjchem-604	1004	8	;	;	PUNCT
eurjchem-604	1004	9	rack	rack	NOUN
eurjchem-604	1004	10	,	,	PUNCT
eurjchem-604	1004	11	p.	p.	NOUN
eurjchem-604	1004	12	crit	crit	PROPN
eurjchem-604	1004	13	.	.	PUNCT
eurjchem-604	1005	1	rev	rev	PROPN
eurjchem-604	1005	2	.	.	PROPN
eurjchem-604	1005	3	solid	solid	PROPN
eurjchem-604	1005	4	.	.	PUNCT
eurjchem-604	1006	1	state2006	state2006	PROPN
eurjchem-604	1006	2	,	,	PUNCT
eurjchem-604	1006	3	31	31	NUM
eurjchem-604	1006	4	,	,	PUNCT
eurjchem-604	1006	5	55‐	55‐	NUM
eurjchem-604	1006	6	89	89	NUM
eurjchem-604	1006	7	.	.	PUNCT
eurjchem-604	1007	1	[	[	X
eurjchem-604	1007	2	10	10	NUM
eurjchem-604	1007	3	]	]	PUNCT
eurjchem-604	1007	4	.	.	PUNCT
eurjchem-604	1007	5	faller	faller	PROPN
eurjchem-604	1007	6	,	,	PUNCT
eurjchem-604	1007	7	j.	j.	PROPN
eurjchem-604	1007	8	w.	w.	PROPN
eurjchem-604	1007	9	,	,	PUNCT
eurjchem-604	1007	10	hexacarbonylmolybdenum	hexacarbonylmolybdenum	ADJ
eurjchem-604	1007	11	,	,	PUNCT
eurjchem-604	1007	12	encyclopedia	encyclopedia	NOUN
eurjchem-604	1007	13	of	of	ADP
eurjchem-604	1007	14	reagents	reagent	NOUN
eurjchem-604	1007	15	for	for	ADP
eurjchem-604	1007	16	organic	organic	ADJ
eurjchem-604	1007	17	synthesis	synthesis	NOUN
eurjchem-604	1007	18	,	,	PUNCT
eurjchem-604	1007	19	ed	ed	NOUN
eurjchem-604	1007	20	:	:	PUNCT
eurjchem-604	1007	21	l.	l.	PROPN
eurjchem-604	1007	22	paquette	paquette	PROPN
eurjchem-604	1007	23	,	,	PUNCT
eurjchem-604	1007	24	j.	j.	PROPN
eurjchem-604	1007	25	wiley	wiley	PROPN
eurjchem-604	1007	26	&	&	CCONJ
eurjchem-604	1007	27	sons	son	NOUN
eurjchem-604	1007	28	,	,	PUNCT
eurjchem-604	1007	29	new	new	PROPN
eurjchem-604	1007	30	york	york	PROPN
eurjchem-604	1007	31	,	,	PUNCT
eurjchem-604	1007	32	2004	2004	NUM
eurjchem-604	1007	33	.	.	PUNCT
eurjchem-604	1008	1	[	[	X
eurjchem-604	1008	2	11	11	NUM
eurjchem-604	1008	3	]	]	PUNCT
eurjchem-604	1008	4	.	.	PUNCT
eurjchem-604	1009	1	http://www	http://www	PROPN
eurjchem-604	1009	2	.	.	PUNCT
eurjchem-604	1009	3	chm	chm	PROPN
eurjchem-604	1009	4	.	.	PUNCT
eurjchem-604	1010	1	bris	bris	PROPN
eurjchem-604	1010	2	.	.	PUNCT
eurjchem-604	1011	1	ac	ac	PROPN
eurjchem-604	1011	2	.	.	PUNCT
eurjchem-604	1012	1	uk	uk	PROPN
eurjchem-604	1012	2	/	/	SYM
eurjchem-604	1012	3	teaching‐	teaching‐	NOUN
eurjchem-604	1012	4	labs	labs	PROPN
eurjchem-604	1012	5	/	/	SYM
eurjchem-604	1012	6	inorganic2ndyear/2004‐2005labmanual	inorganic2ndyear/2004‐2005labmanual	PROPN
eurjchem-604	1012	7	/	/	SYM
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eurjchem-604	1012	9	.	.	PUNCT
eurjchem-604	1013	1	pdf	pdf	NOUN
eurjchem-604	1014	1	[	[	X
eurjchem-604	1014	2	12	12	NUM
eurjchem-604	1014	3	]	]	PUNCT
eurjchem-604	1014	4	.	.	PUNCT
eurjchem-604	1015	1	marradi	marradi	PROPN
eurjchem-604	1015	2	,	,	PUNCT
eurjchem-604	1015	3	m.	m.	NOUN
eurjchem-604	1015	4	synlett	synlett	PROPN
eurjchem-604	1015	5	.	.	PUNCT
eurjchem-604	1016	1	2005	2005	NUM
eurjchem-604	1016	2	,	,	PUNCT
eurjchem-604	1016	3	7	7	NUM
eurjchem-604	1016	4	,	,	PUNCT
eurjchem-604	1016	5	1195‐1196	1195‐1196	NUM
eurjchem-604	1016	6	.	.	PUNCT
eurjchem-604	1017	1	[	[	X
eurjchem-604	1017	2	13	13	NUM
eurjchem-604	1017	3	]	]	SYM
eurjchem-604	1017	4	.	.	PUNCT
eurjchem-604	1017	5	feldmann	feldmann	PROPN
eurjchem-604	1017	6	,	,	PUNCT
eurjchem-604	1017	7	j.	j.	PROPN
eurjchem-604	1017	8	;	;	PUNCT
eurjchem-604	1017	9	cullen	cullen	PROPN
eurjchem-604	1017	10	,	,	PUNCT
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eurjchem-604	1017	12	r.	r.	PROPN
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eurjchem-604	1017	14	.	.	PUNCT
eurjchem-604	1018	1	sci	sci	PROPN
eurjchem-604	1018	2	.	.	PROPN
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eurjchem-604	1018	4	.	.	PROPN
eurjchem-604	1018	5	1997	1997	NUM
eurjchem-604	1018	6	,	,	PUNCT
eurjchem-604	1018	7	31	31	NUM
eurjchem-604	1018	8	,	,	PUNCT
eurjchem-604	1018	9	2125‐	2125‐	NUM
eurjchem-604	1018	10	2129	2129	NUM
eurjchem-604	1018	11	.	.	PUNCT
eurjchem-604	1019	1	[	[	X
eurjchem-604	1019	2	14	14	NUM
eurjchem-604	1019	3	]	]	SYM
eurjchem-604	1019	4	.	.	PUNCT
eurjchem-604	1020	1	feldmann	feldmann	PROPN
eurjchem-604	1020	2	,	,	PUNCT
eurjchem-604	1020	3	j.	j.	PROPN
eurjchem-604	1020	4	;	;	PUNCT
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eurjchem-604	1020	6	,	,	PUNCT
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eurjchem-604	1020	8	;	;	PUNCT
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eurjchem-604	1020	10	,	,	PUNCT
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eurjchem-604	1020	12	v.	v.	ADP
eurjchem-604	1020	13	fresen	fresen	PROPN
eurjchem-604	1020	14	.	.	PUNCT
eurjchem-604	1021	1	j.	j.	PROPN
eurjchem-604	1021	2	anal	anal	PROPN
eurjchem-604	1021	3	.	.	PUNCT
eurjchem-604	1022	1	chem	chem	PROPN
eurjchem-604	1022	2	.	.	PUNCT
eurjchem-604	1023	1	1994	1994	NUM
eurjchem-604	1023	2	,	,	PUNCT
eurjchem-604	1023	3	350	350	NUM
eurjchem-604	1023	4	,	,	PUNCT
eurjchem-604	1023	5	228‐235	228‐235	NUM
eurjchem-604	1023	6	.	.	PUNCT
eurjchem-604	1024	1	[	[	X
eurjchem-604	1024	2	15	15	NUM
eurjchem-604	1024	3	]	]	PUNCT
eurjchem-604	1024	4	.	.	PUNCT
eurjchem-604	1025	1	kubas	kubas	PROPN
eurjchem-604	1025	2	,	,	PUNCT
eurjchem-604	1025	3	g.	g.	PROPN
eurjchem-604	1025	4	j.	j.	PROPN
eurjchem-604	1025	5	,	,	PUNCT
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eurjchem-604	1025	7	dihydrogen	dihydrogen	NOUN
eurjchem-604	1025	8	and	and	CCONJ
eurjchem-604	1025	9	σ‐bond	σ‐bond	NOUN
eurjchem-604	1025	10	complexes	complex	NOUN
eurjchem-604	1025	11	,	,	PUNCT
eurjchem-604	1025	12	kluwer	kluwer	NOUN
eurjchem-604	1025	13	academic	academic	NOUN
eurjchem-604	1025	14	/	/	SYM
eurjchem-604	1025	15	plenum	plenum	NOUN
eurjchem-604	1025	16	publishers	publisher	NOUN
eurjchem-604	1025	17	,	,	PUNCT
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eurjchem-604	1025	19	york	york	PROPN
eurjchem-604	1025	20	,	,	PUNCT
eurjchem-604	1025	21	2001	2001	NUM
eurjchem-604	1025	22	.	.	PUNCT
eurjchem-604	1026	1	[	[	X
eurjchem-604	1026	2	16	16	NUM
eurjchem-604	1026	3	]	]	PUNCT
eurjchem-604	1026	4	.	.	PUNCT
eurjchem-604	1027	1	kubas	kubas	PROPN
eurjchem-604	1027	2	,	,	PUNCT
eurjchem-604	1027	3	g.	g.	PROPN
eurjchem-604	1027	4	j.	j.	PROPN
eurjchem-604	1027	5	;	;	PUNCT
eurjchem-604	1027	6	vandersluys	vandersluys	PROPN
eurjchem-604	1027	7	,	,	PUNCT
eurjchem-604	1027	8	l.	l.	PROPN
eurjchem-604	1027	9	s.	s.	PROPN
eurjchem-604	1027	10	inorg	inorg	PROPN
eurjchem-604	1027	11	.	.	PUNCT
eurjchem-604	1028	1	syn	syn	PROPN
eurjchem-604	1028	2	.	.	PROPN
eurjchem-604	1028	3	1990	1990	NUM
eurjchem-604	1028	4	,	,	PUNCT
eurjchem-604	1028	5	28	28	NUM
eurjchem-604	1028	6	,	,	PUNCT
eurjchem-604	1028	7	29‐33	29‐33	NUM
eurjchem-604	1028	8	.	.	PUNCT
eurjchem-604	1029	1	[	[	X
eurjchem-604	1029	2	17	17	NUM
eurjchem-604	1029	3	]	]	PUNCT
eurjchem-604	1029	4	.	.	PUNCT
eurjchem-604	1030	1	blanchard	blanchard	PROPN
eurjchem-604	1030	2	,	,	PUNCT
eurjchem-604	1030	3	a.	a.	NOUN
eurjchem-604	1030	4	a.	a.	NOUN
eurjchem-604	1030	5	chem	chem	PROPN
eurjchem-604	1030	6	.	.	PUNCT
eurjchem-604	1031	1	rev	rev	PROPN
eurjchem-604	1031	2	.	.	PROPN
eurjchem-604	1031	3	1937	1937	NUM
eurjchem-604	1031	4	,	,	PUNCT
eurjchem-604	1031	5	21	21	NUM
eurjchem-604	1031	6	,	,	PUNCT
eurjchem-604	1031	7	3‐38	3‐38	NUM
eurjchem-604	1031	8	.	.	PUNCT
eurjchem-604	1032	1	[	[	X
eurjchem-604	1032	2	18	18	NUM
eurjchem-604	1032	3	]	]	PUNCT
eurjchem-604	1032	4	.	.	PUNCT
eurjchem-604	1033	1	allian	allian	PROPN
eurjchem-604	1033	2	,	,	PUNCT
eurjchem-604	1033	3	a.	a.	PROPN
eurjchem-604	1033	4	d.	d.	PROPN
eurjchem-604	1033	5	;	;	PUNCT
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eurjchem-604	1033	7	,	,	PUNCT
eurjchem-604	1033	8	y.	y.	PROPN
eurjchem-604	1033	9	;	;	PUNCT
eurjchem-604	1033	10	saeys	saey	NOUN
eurjchem-604	1033	11	,	,	PUNCT
eurjchem-604	1033	12	m.	m.	NOUN
eurjchem-604	1033	13	;	;	PUNCT
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eurjchem-604	1033	15	,	,	PUNCT
eurjchem-604	1033	16	g.	g.	PROPN
eurjchem-604	1033	17	m.	m.	PROPN
eurjchem-604	1033	18	;	;	PUNCT
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eurjchem-604	1033	20	,	,	PUNCT
eurjchem-604	1033	21	m.	m.	NOUN
eurjchem-604	1033	22	vib	vib	PROPN
eurjchem-604	1033	23	.	.	PROPN
eurjchem-604	1033	24	spectrosc	spectrosc	PROPN
eurjchem-604	1033	25	.	.	PUNCT
eurjchem-604	1034	1	2006	2006	NUM
eurjchem-604	1034	2	,	,	PUNCT
eurjchem-604	1034	3	41	41	NUM
eurjchem-604	1034	4	,	,	PUNCT
eurjchem-604	1034	5	101‐111	101‐111	NUM
eurjchem-604	1034	6	.	.	PUNCT
eurjchem-604	1035	1	[	[	X
eurjchem-604	1035	2	19	19	NUM
eurjchem-604	1035	3	]	]	PUNCT
eurjchem-604	1035	4	.	.	PUNCT
eurjchem-604	1035	5	feldmann	feldmann	PROPN
eurjchem-604	1035	6	,	,	PUNCT
eurjchem-604	1035	7	j.	j.	PROPN
eurjchem-604	1035	8	j.	j.	PROPN
eurjchem-604	1035	9	env	env	PROPN
eurjchem-604	1035	10	.	.	PROPN
eurjchem-604	1035	11	monitor	monitor	PROPN
eurjchem-604	1035	12	.	.	PUNCT
eurjchem-604	1036	1	1999	1999	NUM
eurjchem-604	1036	2	,	,	PUNCT
eurjchem-604	1036	3	1(1	1(1	NUM
eurjchem-604	1036	4	)	)	PUNCT
eurjchem-604	1036	5	,	,	PUNCT
eurjchem-604	1036	6	33‐37	33‐37	NUM
eurjchem-604	1036	7	.	.	PUNCT
eurjchem-604	1037	1	[	[	X
eurjchem-604	1037	2	20	20	NUM
eurjchem-604	1037	3	]	]	PUNCT
eurjchem-604	1037	4	.	.	PUNCT
eurjchem-604	1038	1	roode	roode	PROPN
eurjchem-604	1038	2	,	,	PUNCT
eurjchem-604	1038	3	w.	w.	PROPN
eurjchem-604	1038	4	h.	h.	PROPN
eurjchem-604	1038	5	;	;	PUNCT
eurjchem-604	1038	6	vrieze	vrieze	PROPN
eurjchem-604	1038	7	,	,	PUNCT
eurjchem-604	1038	8	k.	k.	PROPN
eurjchem-604	1038	9	j.	j.	PROPN
eurjchem-604	1038	10	organomet	organomet	PROPN
eurjchem-604	1038	11	.	.	PUNCT
eurjchem-604	1039	1	chem	chem	NOUN
eurjchem-604	1039	2	.	.	PUNCT
eurjchem-604	1040	1	1977	1977	NUM
eurjchem-604	1040	2	,	,	PUNCT
eurjchem-604	1040	3	135(2	135(2	NUM
eurjchem-604	1040	4	)	)	PUNCT
eurjchem-604	1040	5	,	,	PUNCT
eurjchem-604	1040	6	183‐193	183‐193	NUM
eurjchem-604	1040	7	.	.	PUNCT
eurjchem-604	1041	1	[	[	X
eurjchem-604	1041	2	21	21	NUM
eurjchem-604	1041	3	]	]	PUNCT
eurjchem-604	1041	4	.	.	PUNCT
eurjchem-604	1042	1	graham	graham	PROPN
eurjchem-604	1042	2	,	,	PUNCT
eurjchem-604	1042	3	j.	j.	PROPN
eurjchem-604	1042	4	r	r	PROPN
eurjchem-604	1042	5	;	;	PUNCT
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eurjchem-604	1042	7	,	,	PUNCT
eurjchem-604	1042	8	r.	r.	PROPN
eurjchem-604	1042	9	j.	j.	PROPN
eurjchem-604	1042	10	inorg	inorg	PROPN
eurjchem-604	1042	11	.	.	PUNCT
eurjchem-604	1043	1	chem	chem	PROPN
eurjchem-604	1043	2	.	.	PUNCT
eurjchem-604	1044	1	1967	1967	NUM
eurjchem-604	1044	2	,	,	PUNCT
eurjchem-604	1044	3	6(11	6(11	NUM
eurjchem-604	1044	4	)	)	PUNCT
eurjchem-604	1044	5	,	,	PUNCT
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eurjchem-604	1044	7	.	.	PUNCT
eurjchem-604	1045	1	[	[	X
eurjchem-604	1045	2	22	22	NUM
eurjchem-604	1045	3	]	]	PUNCT
eurjchem-604	1045	4	.	.	PUNCT
eurjchem-604	1046	1	subasi	subasi	PROPN
eurjchem-604	1046	2	,	,	PUNCT
eurjchem-604	1046	3	e.	e.	PROPN
eurjchem-604	1046	4	;	;	PUNCT
eurjchem-604	1046	5	ugur	ugur	PROPN
eurjchem-604	1046	6	,	,	PUNCT
eurjchem-604	1046	7	f.	f.	PROPN
eurjchem-604	1046	8	;	;	PUNCT
eurjchem-604	1046	9	senturk	senturk	PROPN
eurjchem-604	1046	10	,	,	PUNCT
eurjchem-604	1046	11	o.	o.	PROPN
eurjchem-604	1046	12	s.	s.	PROPN
eurjchem-604	1046	13	trans	trans	PROPN
eurjchem-604	1046	14	.	.	PROPN
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eurjchem-604	1046	16	.	.	PUNCT
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eurjchem-604	1047	2	.	.	PUNCT
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eurjchem-604	1048	2	,	,	PUNCT
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eurjchem-604	1048	4	,	,	PUNCT
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eurjchem-604	1048	6	.	.	PUNCT
eurjchem-604	1049	1	[	[	X
eurjchem-604	1049	2	23	23	NUM
eurjchem-604	1049	3	]	]	PUNCT
eurjchem-604	1049	4	.	.	PUNCT
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eurjchem-604	1050	2	,	,	PUNCT
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eurjchem-604	1050	4	;	;	PUNCT
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eurjchem-604	1050	6	,	,	PUNCT
eurjchem-604	1050	7	b.	b.	PROPN
eurjchem-604	1050	8	;	;	PUNCT
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eurjchem-604	1050	10	,	,	PUNCT
eurjchem-604	1050	11	h.	h.	PROPN
eurjchem-604	1050	12	inorg	inorg	PROPN
eurjchem-604	1050	13	.	.	PUNCT
eurjchem-604	1051	1	chim	chim	PROPN
eurjchem-604	1051	2	.	.	PUNCT
eurjchem-604	1052	1	acta	acta	PROPN
eurjchem-604	1052	2	2004	2004	NUM
eurjchem-604	1052	3	,	,	PUNCT
eurjchem-604	1052	4	357(6	357(6	NUM
eurjchem-604	1052	5	)	)	PUNCT
eurjchem-604	1052	6	,	,	PUNCT
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eurjchem-604	1052	8	.	.	PUNCT
eurjchem-604	1053	1	[	[	X
eurjchem-604	1053	2	24	24	NUM
eurjchem-604	1053	3	]	]	PUNCT
eurjchem-604	1053	4	.	.	PUNCT
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eurjchem-604	1054	2	,	,	PUNCT
eurjchem-604	1054	3	e.	e.	PROPN
eurjchem-604	1054	4	e.	e.	PROPN
eurjchem-604	1054	5	;	;	PUNCT
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eurjchem-604	1054	7	,	,	PUNCT
eurjchem-604	1054	8	v.	v.	PROPN
eurjchem-604	1054	9	i.	i.	PROPN
eurjchem-604	1054	10	;	;	PUNCT
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eurjchem-604	1054	12	,	,	PUNCT
eurjchem-604	1054	13	s.	s.	PROPN
eurjchem-604	1054	14	e.	e.	PROPN
eurjchem-604	1054	15	;	;	PUNCT
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eurjchem-604	1054	17	,	,	PUNCT
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eurjchem-604	1054	19	y.	y.	PROPN
eurjchem-604	1054	20	;	;	PUNCT
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eurjchem-604	1054	22	,	,	PUNCT
eurjchem-604	1054	23	k.	k.	PROPN
eurjchem-604	1054	24	a.	a.	PROPN
eurjchem-604	1054	25	;	;	PUNCT
eurjchem-604	1054	26	vasyanina	vasyanina	PROPN
eurjchem-604	1054	27	,	,	PUNCT
eurjchem-604	1054	28	l.	l.	PROPN
eurjchem-604	1054	29	k.	k.	PROPN
eurjchem-604	1054	30	j.	j.	PROPN
eurjchem-604	1054	31	organomet	organomet	PROPN
eurjchem-604	1054	32	.	.	PUNCT
eurjchem-604	1055	1	chem	chem	NOUN
eurjchem-604	1055	2	.	.	PUNCT
eurjchem-604	1056	1	2001	2001	NUM
eurjchem-604	1056	2	,	,	PUNCT
eurjchem-604	1056	3	631(1‐2	631(1‐2	NUM
eurjchem-604	1056	4	)	)	PUNCT
eurjchem-604	1056	5	,	,	PUNCT
eurjchem-604	1056	6	1‐8	1‐8	NOUN
eurjchem-604	1056	7	.	.	PUNCT
eurjchem-604	1057	1	[	[	X
eurjchem-604	1057	2	25	25	NUM
eurjchem-604	1057	3	]	]	PUNCT
eurjchem-604	1057	4	.	.	PUNCT
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eurjchem-604	1058	2	,	,	PUNCT
eurjchem-604	1058	3	q.	q.	PROPN
eurjchem-604	1058	4	;	;	PUNCT
eurjchem-604	1058	5	mcdonald	mcdonald	PROPN
eurjchem-604	1058	6	,	,	PUNCT
eurjchem-604	1058	7	r.	r.	PROPN
eurjchem-604	1058	8	;	;	PUNCT
eurjchem-604	1058	9	takats	takat	NOUN
eurjchem-604	1058	10	,	,	PUNCT
eurjchem-604	1058	11	j.	j.	PROPN
eurjchem-604	1058	12	j.	j.	PROPN
eurjchem-604	1058	13	organomet	organomet	PROPN
eurjchem-604	1058	14	.	.	PUNCT
eurjchem-604	1059	1	chem	chem	NOUN
eurjchem-604	1059	2	.	.	PUNCT
eurjchem-604	1060	1	2003	2003	NUM
eurjchem-604	1060	2	,	,	PUNCT
eurjchem-604	1060	3	681(1‐	681(1‐	PROPN
eurjchem-604	1060	4	2	2	NUM
eurjchem-604	1060	5	)	)	PUNCT
eurjchem-604	1060	6	,	,	PUNCT
eurjchem-604	1060	7	250‐257	250‐257	NOUN
eurjchem-604	1060	8	.	.	PUNCT
eurjchem-604	1061	1	[	[	X
eurjchem-604	1061	2	26	26	NUM
eurjchem-604	1061	3	]	]	PUNCT
eurjchem-604	1061	4	.	.	PUNCT
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eurjchem-604	1062	2	,	,	PUNCT
eurjchem-604	1062	3	e.	e.	PROPN
eurjchem-604	1062	4	;	;	PUNCT
eurjchem-604	1062	5	özkar	özkar	PROPN
eurjchem-604	1062	6	,	,	PUNCT
eurjchem-604	1062	7	s.	s.	PROPN
eurjchem-604	1062	8	j.	j.	PROPN
eurjchem-604	1062	9	organomet	organomet	PROPN
eurjchem-604	1062	10	.	.	PUNCT
eurjchem-604	1063	1	chem	chem	NOUN
eurjchem-604	1063	2	.	.	PUNCT
eurjchem-604	1064	1	2006	2006	NUM
eurjchem-604	1064	2	,	,	PUNCT
eurjchem-604	1064	3	691(15	691(15	NUM
eurjchem-604	1064	4	)	)	PUNCT
eurjchem-604	1064	5	,	,	PUNCT
eurjchem-604	1064	6	3267‐	3267‐	NUM
eurjchem-604	1064	7	3273	3273	NUM
eurjchem-604	1064	8	.	.	PUNCT
eurjchem-604	1065	1	[	[	X
eurjchem-604	1065	2	27	27	NUM
eurjchem-604	1065	3	]	]	PUNCT
eurjchem-604	1065	4	.	.	PUNCT
eurjchem-604	1066	1	pearson	pearson	PROPN
eurjchem-604	1066	2	,	,	PUNCT
eurjchem-604	1066	3	a.	a.	PROPN
eurjchem-604	1066	4	j.	j.	PROPN
eurjchem-604	1066	5	,	,	PUNCT
eurjchem-604	1066	6	trimethylamine	trimethylamine	NOUN
eurjchem-604	1066	7	n‐oxide	n‐oxide	NUM
eurjchem-604	1066	8	,	,	PUNCT
eurjchem-604	1066	9	encyclopedia	encyclopedia	NOUN
eurjchem-604	1066	10	of	of	ADP
eurjchem-604	1066	11	reagents	reagent	NOUN
eurjchem-604	1066	12	for	for	ADP
eurjchem-604	1066	13	organic	organic	ADJ
eurjchem-604	1066	14	synthesis	synthesis	NOUN
eurjchem-604	1066	15	,	,	PUNCT
eurjchem-604	1066	16	john	john	PROPN
eurjchem-604	1066	17	wiley	wiley	PROPN
eurjchem-604	1066	18	&	&	CCONJ
eurjchem-604	1066	19	sons	son	NOUN
eurjchem-604	1066	20	,	,	PUNCT
eurjchem-604	1066	21	new	new	PROPN
eurjchem-604	1066	22	york	york	PROPN
eurjchem-604	1066	23	,	,	PUNCT
eurjchem-604	1066	24	2001	2001	NUM
eurjchem-604	1066	25	.	.	PUNCT
eurjchem-604	1067	1	[	[	X
eurjchem-604	1067	2	28	28	NUM
eurjchem-604	1067	3	]	]	PUNCT
eurjchem-604	1067	4	.	.	PUNCT
eurjchem-604	1068	1	franzen	franzen	PROPN
eurjchem-604	1068	2	,	,	PUNCT
eurjchem-604	1068	3	v.	v.	X
eurjchem-604	1068	4	org	org	NOUN
eurjchem-604	1068	5	.	.	PUNCT
eurjchem-604	1068	6	synth	synth	PROPN
eurjchem-604	1068	7	.	.	PUNCT
eurjchem-604	1069	1	1967	1967	NUM
eurjchem-604	1069	2	,	,	PUNCT
eurjchem-604	1069	3	47	47	NUM
eurjchem-604	1069	4	,	,	PUNCT
eurjchem-604	1069	5	96‐96	96‐96	NUM
eurjchem-604	1069	6	.	.	PUNCT
eurjchem-604	1070	1	[	[	X
eurjchem-604	1070	2	29	29	NUM
eurjchem-604	1070	3	]	]	PUNCT
eurjchem-604	1070	4	.	.	PUNCT
eurjchem-604	1071	1	ingham	ingham	PROPN
eurjchem-604	1071	2	,	,	PUNCT
eurjchem-604	1071	3	w.	w.	PROPN
eurjchem-604	1071	4	l.	l.	PROPN
eurjchem-604	1071	5	;	;	PUNCT
eurjchem-604	1071	6	billing	billing	NOUN
eurjchem-604	1071	7	,	,	PUNCT
eurjchem-604	1071	8	d.	d.	PROPN
eurjchem-604	1071	9	g.	g.	PROPN
eurjchem-604	1071	10	;	;	PUNCT
eurjchem-604	1071	11	levendis	levendis	PROPN
eurjchem-604	1071	12	,	,	PUNCT
eurjchem-604	1071	13	d.	d.	PROPN
eurjchem-604	1071	14	c.	c.	PROPN
eurjchem-604	1071	15	;	;	PUNCT
eurjchem-604	1071	16	coville	coville	PROPN
eurjchem-604	1071	17	,	,	PUNCT
eurjchem-604	1071	18	n.	n.	PROPN
eurjchem-604	1071	19	j.	j.	PROPN
eurjchem-604	1071	20	inorg	inorg	PROPN
eurjchem-604	1071	21	.	.	PUNCT
eurjchem-604	1072	1	chim	chim	PROPN
eurjchem-604	1072	2	.	.	PUNCT
eurjchem-604	1073	1	acta	acta	PROPN
eurjchem-604	1073	2	1991	1991	NUM
eurjchem-604	1073	3	,	,	PUNCT
eurjchem-604	1073	4	187(1	187(1	NUM
eurjchem-604	1073	5	)	)	PUNCT
eurjchem-604	1073	6	,	,	PUNCT
eurjchem-604	1073	7	17‐21	17‐21	NUM
eurjchem-604	1073	8	.	.	PUNCT
eurjchem-604	1074	1	[	[	X
eurjchem-604	1074	2	30	30	NUM
eurjchem-604	1074	3	]	]	PUNCT
eurjchem-604	1074	4	.	.	PUNCT
eurjchem-604	1074	5	strohmeier	strohmeier	PROPN
eurjchem-604	1074	6	,	,	PUNCT
eurjchem-604	1074	7	w.	w.	PROPN
eurjchem-604	1074	8	angew	angew	PROPN
eurjchem-604	1074	9	.	.	PUNCT
eurjchem-604	1075	1	chem	chem	PROPN
eurjchem-604	1075	2	.	.	PUNCT
eurjchem-604	1076	1	int	int	NOUN
eurjchem-604	1076	2	.	.	PUNCT
eurjchem-604	1077	1	ed	ed	NOUN
eurjchem-604	1077	2	.	.	PUNCT
eurjchem-604	1078	1	eng	eng	PROPN
eurjchem-604	1078	2	.	.	PROPN
eurjchem-604	1078	3	1964	1964	NUM
eurjchem-604	1078	4	,	,	PUNCT
eurjchem-604	1078	5	3	3	NUM
eurjchem-604	1078	6	,	,	PUNCT
eurjchem-604	1078	7	730‐737	730‐737	NUM
eurjchem-604	1078	8	.	.	PUNCT
eurjchem-604	1079	1	[	[	X
eurjchem-604	1079	2	31	31	NUM
eurjchem-604	1079	3	]	]	PUNCT
eurjchem-604	1079	4	.	.	PUNCT
eurjchem-604	1079	5	stolz	stolz	PROPN
eurjchem-604	1079	6	,	,	PUNCT
eurjchem-604	1079	7	i.	i.	PROPN
eurjchem-604	1079	8	w.	w.	PROPN
eurjchem-604	1079	9	;	;	PUNCT
eurjchem-604	1079	10	dobson	dobson	PROPN
eurjchem-604	1079	11	,	,	PUNCT
eurjchem-604	1079	12	g.	g.	PROPN
eurjchem-604	1079	13	r.	r.	PROPN
eurjchem-604	1079	14	;	;	PUNCT
eurjchem-604	1079	15	sheline	sheline	PROPN
eurjchem-604	1079	16	,	,	PUNCT
eurjchem-604	1079	17	r.	r.	PROPN
eurjchem-604	1079	18	k.	k.	PROPN
eurjchem-604	1079	19	j.	j.	PROPN
eurjchem-604	1079	20	am	am	PROPN
eurjchem-604	1079	21	.	.	PUNCT
eurjchem-604	1080	1	chem	chem	PROPN
eurjchem-604	1080	2	.	.	PUNCT
eurjchem-604	1081	1	soc	soc	PROPN
eurjchem-604	1081	2	.	.	PUNCT
eurjchem-604	1082	1	1962	1962	NUM
eurjchem-604	1082	2	,	,	PUNCT
eurjchem-604	1082	3	84(18	84(18	NUM
eurjchem-604	1082	4	)	)	PUNCT
eurjchem-604	1082	5	,	,	PUNCT
eurjchem-604	1082	6	3589‐3590	3589‐3590	NUM
eurjchem-604	1082	7	.	.	PUNCT
eurjchem-604	1083	1	[	[	X
eurjchem-604	1083	2	32	32	NUM
eurjchem-604	1083	3	]	]	PUNCT
eurjchem-604	1083	4	.	.	PUNCT
eurjchem-604	1084	1	vongustorf	vongustorf	PROPN
eurjchem-604	1084	2	,	,	PUNCT
eurjchem-604	1084	3	e.	e.	PROPN
eurjchem-604	1084	4	k.	k.	PROPN
eurjchem-604	1084	5	;	;	PUNCT
eurjchem-604	1084	6	greveis	greveis	PROPN
eurjchem-604	1084	7	,	,	PUNCT
eurjchem-604	1084	8	f.	f.	PROPN
eurjchem-604	1084	9	w.	w.	PROPN
eurjchem-604	1084	10	fortschr	fortschr	PROPN
eurjchem-604	1084	11	.	.	PUNCT
eurjchem-604	1085	1	chem	chem	PROPN
eurjchem-604	1085	2	.	.	PUNCT
eurjchem-604	1086	1	forsch	forsch	PROPN
eurjchem-604	1086	2	.	.	PROPN
eurjchem-604	1087	1	1969	1969	NUM
eurjchem-604	1087	2	,	,	PUNCT
eurjchem-604	1087	3	13	13	NUM
eurjchem-604	1087	4	,	,	PUNCT
eurjchem-604	1087	5	366‐369	366‐369	NUM
eurjchem-604	1087	6	.	.	PUNCT
eurjchem-604	1088	1	[	[	X
eurjchem-604	1088	2	33	33	NUM
eurjchem-604	1088	3	]	]	PUNCT
eurjchem-604	1088	4	.	.	PUNCT
eurjchem-604	1089	1	graham	graham	PROPN
eurjchem-604	1089	2	,	,	PUNCT
eurjchem-604	1089	3	m.	m.	NOUN
eurjchem-604	1089	4	a.	a.	PROPN
eurjchem-604	1089	5	;	;	PUNCT
eurjchem-604	1089	6	rest	rest	NOUN
eurjchem-604	1089	7	,	,	PUNCT
eurjchem-604	1089	8	a.	a.	PROPN
eurjchem-604	1089	9	j.	j.	PROPN
eurjchem-604	1089	10	;	;	PUNCT
eurjchem-604	1089	11	turner	turner	PROPN
eurjchem-604	1089	12	,	,	PUNCT
eurjchem-604	1089	13	j.	j.	PROPN
eurjchem-604	1089	14	j.	j.	PROPN
eurjchem-604	1089	15	j.	j.	PROPN
eurjchem-604	1089	16	organomet	organomet	PROPN
eurjchem-604	1089	17	.	.	PUNCT
eurjchem-604	1090	1	chem	chem	NOUN
eurjchem-604	1090	2	.	.	PUNCT
eurjchem-604	1091	1	1972	1972	NUM
eurjchem-604	1091	2	,	,	PUNCT
eurjchem-604	1091	3	34(2	34(2	NUM
eurjchem-604	1091	4	)	)	PUNCT
eurjchem-604	1091	5	,	,	PUNCT
eurjchem-604	1091	6	c34‐c36	c34‐c36	PROPN
eurjchem-604	1091	7	.	.	PUNCT
eurjchem-604	1092	1	[	[	X
eurjchem-604	1092	2	34	34	NUM
eurjchem-604	1092	3	]	]	PUNCT
eurjchem-604	1092	4	.	.	PUNCT
eurjchem-604	1093	1	ogden	ogden	PROPN
eurjchem-604	1093	2	,	,	PUNCT
eurjchem-604	1093	3	j.	j.	PROPN
eurjchem-604	1093	4	s.	s.	PROPN
eurjchem-604	1093	5	;	;	PUNCT
eurjchem-604	1093	6	turner	turner	PROPN
eurjchem-604	1093	7	,	,	PUNCT
eurjchem-604	1093	8	j.	j.	PROPN
eurjchem-604	1093	9	j.	j.	PROPN
eurjchem-604	1093	10	chem	chem	PROPN
eurjchem-604	1093	11	.	.	PUNCT
eurjchem-604	1094	1	brit	brit	PROPN
eurjchem-604	1094	2	.	.	PUNCT
eurjchem-604	1095	1	1971	1971	NUM
eurjchem-604	1095	2	,	,	PUNCT
eurjchem-604	1095	3	7	7	NUM
eurjchem-604	1095	4	,	,	PUNCT
eurjchem-604	1095	5	186‐188	186‐188	NUM
eurjchem-604	1095	6	.	.	PUNCT
eurjchem-604	1096	1	[	[	X
eurjchem-604	1096	2	35	35	NUM
eurjchem-604	1096	3	]	]	PUNCT
eurjchem-604	1096	4	.	.	PUNCT
eurjchem-604	1097	1	melntyre	melntyre	PROPN
eurjchem-604	1097	2	,	,	PUNCT
eurjchem-604	1097	3	j.	j.	PROPN
eurjchem-604	1097	4	a.	a.	PROPN
eurjchem-604	1097	5	j.	j.	PROPN
eurjchem-604	1097	6	physic	physic	PROPN
eurjchem-604	1097	7	.	.	PUNCT
eurjchem-604	1098	1	chem	chem	PROPN
eurjchem-604	1098	2	.	.	PUNCT
eurjchem-604	1099	1	1970	1970	NUM
eurjchem-604	1099	2	,	,	PUNCT
eurjchem-604	1099	3	74	74	NUM
eurjchem-604	1099	4	,	,	PUNCT
eurjchem-604	1099	5	2408‐2411	2408‐2411	NUM
eurjchem-604	1099	6	.	.	PUNCT
eurjchem-604	1100	1	[	[	X
eurjchem-604	1100	2	36	36	NUM
eurjchem-604	1100	3	]	]	PUNCT
eurjchem-604	1100	4	.	.	PUNCT
eurjchem-604	1101	1	rest	rest	NOUN
eurjchem-604	1101	2	,	,	PUNCT
eurjchem-604	1101	3	a.	a.	PROPN
eurjchem-604	1101	4	j.	j.	PROPN
eurjchem-604	1101	5	;	;	PUNCT
eurjchem-604	1101	6	turner	turner	PROPN
eurjchem-604	1101	7	,	,	PUNCT
eurjchem-604	1101	8	j.	j.	PROPN
eurjchem-604	1101	9	j.	j.	PROPN
eurjchem-604	1101	10	chem	chem	PROPN
eurjchem-604	1101	11	.	.	PUNCT
eurjchem-604	1102	1	commun	commun	PROPN
eurjchem-604	1102	2	.	.	PROPN
eurjchem-604	1103	1	1969	1969	NUM
eurjchem-604	1103	2	,	,	PUNCT
eurjchem-604	1103	3	8	8	NUM
eurjchem-604	1103	4	,	,	PUNCT
eurjchem-604	1103	5	375‐376	375‐376	NUM
eurjchem-604	1103	6	.	.	PUNCT
eurjchem-604	1104	1	[	[	X
eurjchem-604	1104	2	37	37	NUM
eurjchem-604	1104	3	]	]	PUNCT
eurjchem-604	1104	4	.	.	PUNCT
eurjchem-604	1105	1	boylan	boylan	PROPN
eurjchem-604	1105	2	,	,	PUNCT
eurjchem-604	1105	3	m.	m.	PROPN
eurjchem-604	1105	4	j.	j.	PROPN
eurjchem-604	1105	5	;	;	PUNCT
eurjchem-604	1105	6	braterman	braterman	NOUN
eurjchem-604	1105	7	,	,	PUNCT
eurjchem-604	1105	8	p.	p.	PROPN
eurjchem-604	1105	9	s.	s.	PROPN
eurjchem-604	1105	10	;	;	PUNCT
eurjchem-604	1105	11	fullarton	fullarton	PROPN
eurjchem-604	1105	12	,	,	PUNCT
eurjchem-604	1105	13	a.	a.	NOUN
eurjchem-604	1105	14	j.	j.	PROPN
eurjchem-604	1105	15	organomet	organomet	PROPN
eurjchem-604	1105	16	.	.	PUNCT
eurjchem-604	1106	1	chem	chem	NOUN
eurjchem-604	1106	2	.	.	PUNCT
eurjchem-604	1107	1	1971	1971	NUM
eurjchem-604	1107	2	,	,	PUNCT
eurjchem-604	1107	3	31	31	NUM
eurjchem-604	1107	4	,	,	PUNCT
eurjchem-604	1107	5	c29‐c30	c29‐c30	NOUN
eurjchem-604	1107	6	.	.	PUNCT
eurjchem-604	1108	1	[	[	X
eurjchem-604	1108	2	38	38	NUM
eurjchem-604	1108	3	]	]	PUNCT
eurjchem-604	1108	4	.	.	PUNCT
eurjchem-604	1108	5	schwenzer	schwenzer	PROPN
eurjchem-604	1108	6	,	,	PUNCT
eurjchem-604	1108	7	g.	g.	PROPN
eurjchem-604	1108	8	;	;	PUNCT
eurjchem-604	1108	9	darensbourg	darensbourg	PROPN
eurjchem-604	1108	10	,	,	PUNCT
eurjchem-604	1108	11	m.	m.	NOUN
eurjchem-604	1108	12	y.	y.	PROPN
eurjchem-604	1108	13	inorg	inorg	PROPN
eurjchem-604	1108	14	.	.	PUNCT
eurjchem-604	1109	1	chem	chem	PROPN
eurjchem-604	1109	2	.	.	PUNCT
eurjchem-604	1110	1	1972	1972	NUM
eurjchem-604	1110	2	,	,	PUNCT
eurjchem-604	1110	3	11(8	11(8	NUM
eurjchem-604	1110	4	)	)	PUNCT
eurjchem-604	1110	5	,	,	PUNCT
eurjchem-604	1110	6	1967‐	1967‐	NUM
eurjchem-604	1110	7	1970	1970	NUM
eurjchem-604	1110	8	.	.	PUNCT
eurjchem-604	1111	1	[	[	X
eurjchem-604	1111	2	39	39	NUM
eurjchem-604	1111	3	]	]	PUNCT
eurjchem-604	1111	4	.	.	PUNCT
eurjchem-604	1112	1	fub	fub	PROPN
eurjchem-604	1112	2	.	.	PUNCT
eurjchem-604	1113	1	w	w	PROPN
eurjchem-604	1113	2	;	;	PUNCT
eurjchem-604	1113	3	trushin	trushin	PROPN
eurjchem-604	1113	4	,	,	PUNCT
eurjchem-604	1113	5	s.	s.	PROPN
eurjchem-604	1113	6	a.	a.	PROPN
eurjchem-604	1113	7	;	;	PUNCT
eurjchem-604	1113	8	schmid	schmid	PROPN
eurjchem-604	1113	9	,	,	PUNCT
eurjchem-604	1113	10	w.	w.	PROPN
eurjchem-604	1113	11	e.	e.	PROPN
eurjchem-604	1113	12	res	res	PROPN
eurjchem-604	1113	13	.	.	PROPN
eurjchem-604	1113	14	chem	chem	PROPN
eurjchem-604	1113	15	.	.	PUNCT
eurjchem-604	1114	1	intermed	interme	VERB
eurjchem-604	1114	2	.	.	PROPN
eurjchem-604	1115	1	2001	2001	NUM
eurjchem-604	1115	2	,	,	PUNCT
eurjchem-604	1115	3	27(4‐5	27(4‐5	NUM
eurjchem-604	1115	4	)	)	PUNCT
eurjchem-604	1115	5	,	,	PUNCT
eurjchem-604	1115	6	447‐457	447‐457	NUM
eurjchem-604	1115	7	.	.	PUNCT
eurjchem-604	1116	1	[	[	X
eurjchem-604	1116	2	40	40	NUM
eurjchem-604	1116	3	]	]	PUNCT
eurjchem-604	1116	4	.	.	PUNCT
eurjchem-604	1117	1	subasi	subasi	PROPN
eurjchem-604	1117	2	,	,	PUNCT
eurjchem-604	1117	3	e.	e.	PROPN
eurjchem-604	1117	4	;	;	PUNCT
eurjchem-604	1117	5	temel	temel	PROPN
eurjchem-604	1117	6	,	,	PUNCT
eurjchem-604	1117	7	h.	h.	PROPN
eurjchem-604	1117	8	synth	synth	PROPN
eurjchem-604	1117	9	.	.	PUNCT
eurjchem-604	1118	1	react	react	VERB
eurjchem-604	1118	2	.	.	PUNCT
eurjchem-604	1119	1	inorg	inorg	PROPN
eurjchem-604	1119	2	.	.	PUNCT
eurjchem-604	1120	1	me	i	PRON
eurjchem-604	1120	2	.	.	PUNCT
eurjchem-604	1121	1	2007	2007	NUM
eurjchem-604	1121	2	,	,	PUNCT
eurjchem-604	1121	3	37(2	37(2	PRON
eurjchem-604	1121	4	)	)	PUNCT
eurjchem-604	1121	5	,	,	PUNCT
eurjchem-604	1121	6	85‐89	85‐89	ADJ
eurjchem-604	1121	7	.	.	PUNCT
eurjchem-604	1122	1	[	[	X
eurjchem-604	1122	2	41	41	NUM
eurjchem-604	1122	3	]	]	PUNCT
eurjchem-604	1122	4	.	.	PUNCT
eurjchem-604	1123	1	şenturk	şenturk	ADJ
eurjchem-604	1123	2	,	,	PUNCT
eurjchem-604	1123	3	o.	o.	PROPN
eurjchem-604	1123	4	s.	s.	PROPN
eurjchem-604	1123	5	;	;	PUNCT
eurjchem-604	1123	6	ugur	ugur	PROPN
eurjchem-604	1123	7	,	,	PUNCT
eurjchem-604	1123	8	f.	f.	PROPN
eurjchem-604	1123	9	synth	synth	PROPN
eurjchem-604	1123	10	.	.	PUNCT
eurjchem-604	1124	1	react	react	VERB
eurjchem-604	1124	2	.	.	PUNCT
eurjchem-604	1125	1	inorg	inorg	PROPN
eurjchem-604	1125	2	.	.	PUNCT
eurjchem-604	1126	1	me	i	PRON
eurjchem-604	1126	2	.	.	PUNCT
eurjchem-604	1127	1	2001	2001	NUM
eurjchem-604	1127	2	,	,	PUNCT
eurjchem-604	1127	3	31(10	31(10	NUM
eurjchem-604	1127	4	)	)	PUNCT
eurjchem-604	1127	5	,	,	PUNCT
eurjchem-604	1127	6	1843‐	1843‐	NUM
eurjchem-604	1127	7	1851	1851	NUM
eurjchem-604	1127	8	.	.	PUNCT
eurjchem-604	1128	1	[	[	X
eurjchem-604	1128	2	42	42	NUM
eurjchem-604	1128	3	]	]	PUNCT
eurjchem-604	1128	4	.	.	PUNCT
eurjchem-604	1129	1	ozdemir	ozdemir	PROPN
eurjchem-604	1129	2	,	,	PUNCT
eurjchem-604	1129	3	u.	u.	PROPN
eurjchem-604	1129	4	;	;	PUNCT
eurjchem-604	1129	5	karacan	karacan	ADJ
eurjchem-604	1129	6	,	,	PUNCT
eurjchem-604	1129	7	n.	n.	PROPN
eurjchem-604	1129	8	;	;	PUNCT
eurjchem-604	1129	9	senturk	senturk	PROPN
eurjchem-604	1129	10	,	,	PUNCT
eurjchem-604	1129	11	o.	o.	PROPN
eurjchem-604	1129	12	s.	s.	PROPN
eurjchem-604	1129	13	;	;	PUNCT
eurjchem-604	1129	14	sert	sert	PROPN
eurjchem-604	1129	15	,	,	PUNCT
eurjchem-604	1129	16	s.	s.	PROPN
eurjchem-604	1129	17	;	;	PUNCT
eurjchem-604	1129	18	ugur	ugur	PROPN
eurjchem-604	1129	19	,	,	PUNCT
eurjchem-604	1129	20	f.	f.	PROPN
eurjchem-604	1129	21	synth	synth	PROPN
eurjchem-604	1129	22	.	.	PUNCT
eurjchem-604	1130	1	react	react	VERB
eurjchem-604	1130	2	.	.	PUNCT
eurjchem-604	1131	1	inorg	inorg	PROPN
eurjchem-604	1131	2	.	.	PUNCT
eurjchem-604	1132	1	me	i	PRON
eurjchem-604	1132	2	.	.	PUNCT
eurjchem-604	1133	1	2004	2004	NUM
eurjchem-604	1133	2	,	,	PUNCT
eurjchem-604	1133	3	34(6	34(6	NOUN
eurjchem-604	1133	4	)	)	PUNCT
eurjchem-604	1133	5	,	,	PUNCT
eurjchem-604	1133	6	1057‐1067	1057‐1067	NUM
eurjchem-604	1133	7	.	.	PUNCT
eurjchem-604	1134	1	[	[	X
eurjchem-604	1134	2	43	43	NUM
eurjchem-604	1134	3	]	]	PUNCT
eurjchem-604	1134	4	.	.	PUNCT
eurjchem-604	1135	1	frey	frey	PROPN
eurjchem-604	1135	2	,	,	PUNCT
eurjchem-604	1135	3	g.	g.	PROPN
eurjchem-604	1135	4	d.	d.	PROPN
eurjchem-604	1135	5	;	;	PUNCT
eurjchem-604	1135	6	ofele	ofele	PROPN
eurjchem-604	1135	7	,	,	PUNCT
eurjchem-604	1135	8	k.	k.	PROPN
eurjchem-604	1135	9	;	;	PUNCT
eurjchem-604	1135	10	krist	krist	PROPN
eurjchem-604	1135	11	,	,	PUNCT
eurjchem-604	1135	12	h.	h.	PROPN
eurjchem-604	1135	13	g.	g.	PROPN
eurjchem-604	1135	14	;	;	PUNCT
eurjchem-604	1135	15	herdtweck	herdtweck	NOUN
eurjchem-604	1135	16	,	,	PUNCT
eurjchem-604	1135	17	e.	e.	PROPN
eurjchem-604	1135	18	;	;	PUNCT
eurjchem-604	1135	19	herrmann	herrmann	PROPN
eurjchem-604	1135	20	,	,	PUNCT
eurjchem-604	1135	21	w.	w.	PROPN
eurjchem-604	1135	22	a.	a.	NOUN
eurjchem-604	1135	23	inorg	inorg	PROPN
eurjchem-604	1135	24	.	.	PUNCT
eurjchem-604	1136	1	chim	chim	PROPN
eurjchem-604	1136	2	.	.	PUNCT
eurjchem-604	1137	1	acta	acta	PROPN
eurjchem-604	1137	2	2006	2006	NUM
eurjchem-604	1137	3	,	,	PUNCT
eurjchem-604	1137	4	359(9	359(9	NUM
eurjchem-604	1137	5	)	)	PUNCT
eurjchem-604	1137	6	,	,	PUNCT
eurjchem-604	1137	7	2622‐2634	2622‐2634	NUM
eurjchem-604	1137	8	.	.	PUNCT
eurjchem-604	1138	1	[	[	X
eurjchem-604	1138	2	44	44	NUM
eurjchem-604	1138	3	]	]	PUNCT
eurjchem-604	1138	4	.	.	PUNCT
eurjchem-604	1139	1	ozkar	ozkar	PROPN
eurjchem-604	1139	2	,	,	PUNCT
eurjchem-604	1139	3	s.	s.	PROPN
eurjchem-604	1139	4	;	;	PUNCT
eurjchem-604	1139	5	kayran	kayran	PROPN
eurjchem-604	1139	6	,	,	PUNCT
eurjchem-604	1139	7	c.	c.	PROPN
eurjchem-604	1139	8	;	;	PUNCT
eurjchem-604	1139	9	demir	demir	PROPN
eurjchem-604	1139	10	,	,	PUNCT
eurjchem-604	1139	11	n.	n.	PROPN
eurjchem-604	1139	12	j.	j.	PROPN
eurjchem-604	1139	13	organomet	organomet	PROPN
eurjchem-604	1139	14	.	.	PUNCT
eurjchem-604	1140	1	chem	chem	NOUN
eurjchem-604	1140	2	.	.	PUNCT
eurjchem-604	1141	1	2003	2003	NUM
eurjchem-604	1141	2	,	,	PUNCT
eurjchem-604	1141	3	688(1‐2	688(1‐2	NUM
eurjchem-604	1141	4	)	)	PUNCT
eurjchem-604	1141	5	,	,	PUNCT
eurjchem-604	1141	6	62‐67	62‐67	NUM
eurjchem-604	1141	7	.	.	PUNCT
eurjchem-604	1142	1	[	[	X
eurjchem-604	1142	2	45	45	NUM
eurjchem-604	1142	3	]	]	PUNCT
eurjchem-604	1142	4	.	.	PUNCT
eurjchem-604	1143	1	ruff	ruff	PROPN
eurjchem-604	1143	2	,	,	PUNCT
eurjchem-604	1143	3	j.	j.	PROPN
eurjchem-604	1143	4	k.	k.	PROPN
eurjchem-604	1143	5	;	;	PUNCT
eurjchem-604	1143	6	lustig	lustig	PROPN
eurjchem-604	1143	7	,	,	PUNCT
eurjchem-604	1143	8	m.	m.	NOUN
eurjchem-604	1143	9	inorg	inorg	PROPN
eurjchem-604	1143	10	.	.	PUNCT
eurjchem-604	1144	1	chem	chem	PROPN
eurjchem-604	1144	2	.	.	PUNCT
eurjchem-604	1145	1	1968	1968	NUM
eurjchem-604	1145	2	,	,	PUNCT
eurjchem-604	1145	3	7(10	7(10	NUM
eurjchem-604	1145	4	)	)	PUNCT
eurjchem-604	1145	5	,	,	PUNCT
eurjchem-604	1145	6	2171‐2173	2171‐2173	NUM
eurjchem-604	1145	7	.	.	PUNCT
eurjchem-604	1146	1	[	[	X
eurjchem-604	1146	2	46	46	NUM
eurjchem-604	1146	3	]	]	PUNCT
eurjchem-604	1146	4	.	.	PUNCT
eurjchem-604	1147	1	iupac	iupac	PROPN
eurjchem-604	1147	2	,	,	PUNCT
eurjchem-604	1147	3	compendium	compendium	NOUN
eurjchem-604	1147	4	of	of	ADP
eurjchem-604	1147	5	chemical	chemical	NOUN
eurjchem-604	1147	6	terminology	terminology	NOUN
eurjchem-604	1147	7	,	,	PUNCT
eurjchem-604	1147	8	2nded	2nded	NUM
eurjchem-604	1147	9	.	.	PUNCT
eurjchem-604	1148	1	the	the	DET
eurjchem-604	1148	2	gold	gold	NOUN
eurjchem-604	1148	3	book	book	NOUN
eurjchem-604	1148	4	,	,	PUNCT
eurjchem-604	1148	5	1997	1997	NUM
eurjchem-604	1148	6	,	,	PUNCT
eurjchem-604	1148	7	online	online	ADJ
eurjchem-604	1148	8	corrected	correct	VERB
eurjchem-604	1148	9	version	version	NOUN
eurjchem-604	1148	10	:	:	PUNCT
eurjchem-604	1148	11	"	"	PUNCT
eurjchem-604	1148	12	complex	complex	ADJ
eurjchem-604	1148	13	"	"	PUNCT
eurjchem-604	1148	14	,	,	PUNCT
eurjchem-604	1148	15	2006	2006	NUM
eurjchem-604	1148	16	.	.	PUNCT
eurjchem-604	1149	1	[	[	X
eurjchem-604	1149	2	47	47	NUM
eurjchem-604	1149	3	]	]	PUNCT
eurjchem-604	1149	4	.	.	PUNCT
eurjchem-604	1150	1	iupac	iupac	PROPN
eurjchem-604	1150	2	,	,	PUNCT
eurjchem-604	1150	3	compendium	compendium	NOUN
eurjchem-604	1150	4	of	of	ADP
eurjchem-604	1150	5	chemical	chemical	NOUN
eurjchem-604	1150	6	terminology	terminology	NOUN
eurjchem-604	1150	7	,	,	PUNCT
eurjchem-604	1150	8	2nded	2nded	NUM
eurjchem-604	1150	9	.	.	PUNCT
eurjchem-604	1151	1	the	the	DET
eurjchem-604	1151	2	gold	gold	NOUN
eurjchem-604	1151	3	book	book	NOUN
eurjchem-604	1151	4	,	,	PUNCT
eurjchem-604	1151	5	1997	1997	NUM
eurjchem-604	1151	6	,	,	PUNCT
eurjchem-604	1151	7	online	online	ADJ
eurjchem-604	1151	8	corrected	correct	VERB
eurjchem-604	1151	9	version	version	NOUN
eurjchem-604	1151	10	:	:	PUNCT
eurjchem-604	1151	11	"	"	PUNCT
eurjchem-604	1151	12	coordination	coordination	NOUN
eurjchem-604	1151	13	entity	entity	NOUN
eurjchem-604	1151	14	"	"	PUNCT
eurjchem-604	1151	15	,	,	PUNCT
eurjchem-604	1151	16	2006	2006	NUM
eurjchem-604	1151	17	.	.	PUNCT
eurjchem-604	1152	1	[	[	X
eurjchem-604	1152	2	48	48	NUM
eurjchem-604	1152	3	]	]	PUNCT
eurjchem-604	1152	4	.	.	PUNCT
eurjchem-604	1152	5	asali	asali	PROPN
eurjchem-604	1152	6	,	,	PUNCT
eurjchem-604	1152	7	k.	k.	PROPN
eurjchem-604	1152	8	j.	j.	PROPN
eurjchem-604	1152	9	;	;	PUNCT
eurjchem-604	1152	10	janaydeh	janaydeh	PROPN
eurjchem-604	1152	11	,	,	PUNCT
eurjchem-604	1152	12	h.	h.	PROPN
eurjchem-604	1152	13	a.	a.	PROPN
eurjchem-604	1152	14	acta	acta	PROPN
eurjchem-604	1152	15	chim	chim	PROPN
eurjchem-604	1152	16	.	.	PUNCT
eurjchem-604	1153	1	slov	slov	PROPN
eurjchem-604	1153	2	.	.	PROPN
eurjchem-604	1154	1	2003	2003	NUM
eurjchem-604	1154	2	,	,	PUNCT
eurjchem-604	1154	3	50	50	NUM
eurjchem-604	1154	4	,	,	PUNCT
eurjchem-604	1154	5	677‐686	677‐686	NUM
eurjchem-604	1154	6	.	.	PUNCT
eurjchem-604	1155	1	[	[	X
eurjchem-604	1155	2	49	49	NUM
eurjchem-604	1155	3	]	]	PUNCT
eurjchem-604	1155	4	.	.	PUNCT
eurjchem-604	1156	1	banide	banide	PROPN
eurjchem-604	1156	2	,	,	PUNCT
eurjchem-604	1156	3	e.	e.	PROPN
eurjchem-604	1156	4	v.	v.	PROPN
eurjchem-604	1156	5	;	;	PUNCT
eurjchem-604	1156	6	grealis	grealis	PROPN
eurjchem-604	1156	7	,	,	PUNCT
eurjchem-604	1156	8	j.	j.	PROPN
eurjchem-604	1156	9	p.	p.	PROPN
eurjchem-604	1156	10	;	;	PUNCT
eurjchem-604	1156	11	muller‐bunz	muller‐bunz	PROPN
eurjchem-604	1156	12	,	,	PUNCT
eurjchem-604	1156	13	h.	h.	PROPN
eurjchem-604	1156	14	;	;	PUNCT
eurjchem-604	1156	15	ortin	ortin	PROPN
eurjchem-604	1156	16	,	,	PUNCT
eurjchem-604	1156	17	y.	y.	PROPN
eurjchem-604	1156	18	;	;	PUNCT
eurjchem-604	1156	19	casey	casey	NOUN
eurjchem-604	1156	20	,	,	PUNCT
eurjchem-604	1156	21	m.	m.	NOUN
eurjchem-604	1156	22	;	;	PUNCT
eurjchem-604	1156	23	mendicute‐fierro	mendicute‐fierro	PROPN
eurjchem-604	1156	24	,	,	PUNCT
eurjchem-604	1156	25	c.	c.	NOUN
eurjchem-604	1156	26	;	;	PUNCT
eurjchem-604	1156	27	lagunas	laguna	NOUN
eurjchem-604	1156	28	,	,	PUNCT
eurjchem-604	1156	29	m.	m.	NOUN
eurjchem-604	1156	30	c.	c.	PROPN
eurjchem-604	1156	31	;	;	PUNCT
eurjchem-604	1156	32	mcglinchey	mcglinchey	PROPN
eurjchem-604	1156	33	,	,	PUNCT
eurjchem-604	1156	34	m.	m.	PROPN
eurjchem-604	1156	35	j.	j.	PROPN
eurjchem-604	1156	36	j.	j.	PROPN
eurjchem-604	1156	37	organomet	organomet	PROPN
eurjchem-604	1156	38	.	.	PUNCT
eurjchem-604	1157	1	chem	chem	NOUN
eurjchem-604	1157	2	.	.	PUNCT
eurjchem-604	1158	1	2008	2008	NUM
eurjchem-604	1158	2	,	,	PUNCT
eurjchem-604	1158	3	693(10	693(10	NUM
eurjchem-604	1158	4	)	)	PUNCT
eurjchem-604	1158	5	,	,	PUNCT
eurjchem-604	1158	6	1759‐1770	1759‐1770	NUM
eurjchem-604	1158	7	.	.	PUNCT
eurjchem-604	1159	1	[	[	X
eurjchem-604	1159	2	50	50	NUM
eurjchem-604	1159	3	]	]	PUNCT
eurjchem-604	1159	4	.	.	PUNCT
eurjchem-604	1160	1	heinicke	heinicke	PROPN
eurjchem-604	1160	2	,	,	PUNCT
eurjchem-604	1160	3	j.	j.	PROPN
eurjchem-604	1160	4	;	;	PUNCT
eurjchem-604	1160	5	surana	surana	PROPN
eurjchem-604	1160	6	,	,	PUNCT
eurjchem-604	1160	7	a.	a.	NOUN
eurjchem-604	1160	8	;	;	PUNCT
eurjchem-604	1160	9	singh	singh	PROPN
eurjchem-604	1160	10	,	,	PUNCT
eurjchem-604	1160	11	s.	s.	PROPN
eurjchem-604	1160	12	;	;	PUNCT
eurjchem-604	1160	13	gupta	gupta	PROPN
eurjchem-604	1160	14	,	,	PUNCT
eurjchem-604	1160	15	n.	n.	NOUN
eurjchem-604	1160	16	;	;	PUNCT
eurjchem-604	1160	17	bansal	bansal	NOUN
eurjchem-604	1160	18	,	,	PUNCT
eurjchem-604	1160	19	r.	r.	PROPN
eurjchem-604	1160	20	k.	k.	PROPN
eurjchem-604	1160	21	phos	phos	PROPN
eurjchem-604	1160	22	.	.	PUNCT
eurjchem-604	1161	1	sul	sul	PROPN
eurjchem-604	1161	2	.	.	PROPN
eurjchem-604	1161	3	silicon	silicon	PROPN
eurjchem-604	1161	4	relat	relat	PROPN
eurjchem-604	1161	5	.	.	PUNCT
eurjchem-604	1162	1	elem	elem	NOUN
eurjchem-604	1162	2	.	.	PUNCT
eurjchem-604	1163	1	2002	2002	NUM
eurjchem-604	1163	2	,	,	PUNCT
eurjchem-604	1163	3	177(8‐9	177(8‐9	NUM
eurjchem-604	1163	4	)	)	PUNCT
eurjchem-604	1163	5	,	,	PUNCT
eurjchem-604	1163	6	2117‐2118	2117‐2118	NUM
eurjchem-604	1163	7	.	.	PUNCT
eurjchem-604	1164	1	[	[	X
eurjchem-604	1164	2	51	51	NUM
eurjchem-604	1164	3	]	]	PUNCT
eurjchem-604	1164	4	.	.	PUNCT
eurjchem-604	1165	1	miki	miki	PROPN
eurjchem-604	1165	2	,	,	PUNCT
eurjchem-604	1165	3	k.	k.	PROPN
eurjchem-604	1165	4	;	;	PUNCT
eurjchem-604	1165	5	yokoi	yokoi	PROPN
eurjchem-604	1165	6	,	,	PUNCT
eurjchem-604	1165	7	t.	t.	PROPN
eurjchem-604	1165	8	;	;	PUNCT
eurjchem-604	1165	9	nishino	nishino	PROPN
eurjchem-604	1165	10	,	,	PUNCT
eurjchem-604	1165	11	f.	f.	PROPN
eurjchem-604	1165	12	;	;	PUNCT
eurjchem-604	1165	13	ohe	ohe	PROPN
eurjchem-604	1165	14	,	,	PUNCT
eurjchem-604	1165	15	k.	k.	PROPN
eurjchem-604	1165	16	;	;	PUNCT
eurjchem-604	1165	17	uemura	uemura	PROPN
eurjchem-604	1165	18	,	,	PUNCT
eurjchem-604	1165	19	s.	s.	PROPN
eurjchem-604	1165	20	j.	j.	PROPN
eurjchem-604	1165	21	organomet	organomet	PROPN
eurjchem-604	1165	22	.	.	PUNCT
eurjchem-604	1166	1	chem	chem	NOUN
eurjchem-604	1166	2	.	.	PUNCT
eurjchem-604	1167	1	2002	2002	NUM
eurjchem-604	1167	2	,	,	PUNCT
eurjchem-604	1167	3	645(1‐2	645(1‐2	NOUN
eurjchem-604	1167	4	)	)	PUNCT
eurjchem-604	1167	5	,	,	PUNCT
eurjchem-604	1167	6	228‐234	228‐234	NUM
eurjchem-604	1167	7	.	.	PUNCT
eurjchem-604	1168	1	[	[	X
eurjchem-604	1168	2	52	52	NUM
eurjchem-604	1168	3	]	]	SYM
eurjchem-604	1168	4	.	.	PUNCT
eurjchem-604	1168	5	karahan	karahan	PROPN
eurjchem-604	1168	6	,	,	PUNCT
eurjchem-604	1168	7	s.	s.	PROPN
eurjchem-604	1168	8	;	;	PUNCT
eurjchem-604	1168	9	köse	köse	PROPN
eurjchem-604	1168	10	,	,	PUNCT
eurjchem-604	1168	11	p.	p.	NOUN
eurjchem-604	1168	12	;	;	PUNCT
eurjchem-604	1168	13	subasi	subasi	PROPN
eurjchem-604	1168	14	,	,	PUNCT
eurjchem-604	1168	15	e.	e.	PROPN
eurjchem-604	1168	16	;	;	PUNCT
eurjchem-604	1168	17	temel	temel	PROPN
eurjchem-604	1168	18	,	,	PUNCT
eurjchem-604	1168	19	h.	h.	PROPN
eurjchem-604	1168	20	synth	synth	PROPN
eurjchem-604	1168	21	.	.	PUNCT
eurjchem-604	1169	1	react	react	VERB
eurjchem-604	1169	2	.	.	PUNCT
eurjchem-604	1170	1	inorg	inorg	PROPN
eurjchem-604	1170	2	.	.	PUNCT
eurjchem-604	1171	1	me	i	PRON
eurjchem-604	1171	2	.	.	PUNCT
eurjchem-604	1172	1	2008	2008	NUM
eurjchem-604	1172	2	,	,	PUNCT
eurjchem-604	1172	3	38(7	38(7	NUM
eurjchem-604	1172	4	)	)	PUNCT
eurjchem-604	1172	5	,	,	PUNCT
eurjchem-604	1172	6	615‐619	615‐619	NUM
eurjchem-604	1172	7	.	.	PUNCT
eurjchem-604	1173	1	[	[	X
eurjchem-604	1173	2	53	53	NUM
eurjchem-604	1173	3	]	]	PUNCT
eurjchem-604	1173	4	.	.	PUNCT
eurjchem-604	1174	1	subasi	subasi	PROPN
eurjchem-604	1174	2	,	,	PUNCT
eurjchem-604	1174	3	e.	e.	PROPN
eurjchem-604	1174	4	;	;	PUNCT
eurjchem-604	1174	5	kose	kose	PROPN
eurjchem-604	1174	6	,	,	PUNCT
eurjchem-604	1174	7	p.	p.	PROPN
eurjchem-604	1174	8	;	;	PUNCT
eurjchem-604	1174	9	karahan	karahan	PROPN
eurjchem-604	1174	10	,	,	PUNCT
eurjchem-604	1174	11	s.	s.	PROPN
eurjchem-604	1174	12	;	;	PUNCT
eurjchem-604	1174	13	ergun	ergun	NOUN
eurjchem-604	1174	14	,	,	PUNCT
eurjchem-604	1174	15	y.	y.	NOUN
eurjchem-604	1174	16	synth	synth	PROPN
eurjchem-604	1174	17	.	.	PUNCT
eurjchem-604	1175	1	react	react	VERB
eurjchem-604	1175	2	.	.	PUNCT
eurjchem-604	1176	1	inorg	inorg	PROPN
eurjchem-604	1176	2	.	.	PUNCT
eurjchem-604	1177	1	me	i	PRON
eurjchem-604	1177	2	.	.	PUNCT
eurjchem-604	1178	1	2009	2009	NUM
eurjchem-604	1178	2	,	,	PUNCT
eurjchem-604	1178	3	39(3	39(3	NUM
eurjchem-604	1178	4	)	)	PUNCT
eurjchem-604	1178	5	,	,	PUNCT
eurjchem-604	1178	6	139‐143	139‐143	NOUN
eurjchem-604	1178	7	.	.	PUNCT
eurjchem-604	1179	1	[	[	X
eurjchem-604	1179	2	54	54	NUM
eurjchem-604	1179	3	]	]	PUNCT
eurjchem-604	1179	4	.	.	PUNCT
eurjchem-604	1180	1	gan	gan	PROPN
eurjchem-604	1180	2	,	,	PUNCT
eurjchem-604	1180	3	x.	x.	NOUN
eurjchem-604	1180	4	x.	x.	PROPN
eurjchem-604	1180	5	;	;	PUNCT
eurjchem-604	1180	6	tan	tan	PROPN
eurjchem-604	1180	7	,	,	PUNCT
eurjchem-604	1180	8	r.	r.	PROPN
eurjchem-604	1180	9	y.	y.	PROPN
eurjchem-604	1180	10	;	;	PUNCT
eurjchem-604	1180	11	song	song	PROPN
eurjchem-604	1180	12	,	,	PUNCT
eurjchem-604	1180	13	h.	h.	PROPN
eurjchem-604	1180	14	b.	b.	PROPN
eurjchem-604	1180	15	;	;	PUNCT
eurjchem-604	1180	16	zhao	zhao	PROPN
eurjchem-604	1180	17	,	,	PUNCT
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eurjchem-604	1180	19	m.	m.	NOUN
eurjchem-604	1180	20	;	;	PUNCT
eurjchem-604	1180	21	tang	tang	PROPN
eurjchem-604	1180	22	,	,	PUNCT
eurjchem-604	1180	23	l.	l.	PROPN
eurjchem-604	1180	24	f.	f.	PROPN
eurjchem-604	1180	25	j.	j.	PROPN
eurjchem-604	1180	26	coord	coord	PROPN
eurjchem-604	1180	27	.	.	PUNCT
eurjchem-604	1181	1	chem	chem	PROPN
eurjchem-604	1181	2	.	.	PUNCT
eurjchem-604	1182	1	2006	2006	NUM
eurjchem-604	1182	2	,	,	PUNCT
eurjchem-604	1182	3	59(7	59(7	NUM
eurjchem-604	1182	4	)	)	PUNCT
eurjchem-604	1182	5	,	,	PUNCT
eurjchem-604	1182	6	783‐789	783‐789	NUM
eurjchem-604	1182	7	.	.	PUNCT
eurjchem-604	1183	1	[	[	X
eurjchem-604	1183	2	55	55	NUM
eurjchem-604	1183	3	]	]	PUNCT
eurjchem-604	1183	4	.	.	PUNCT
eurjchem-604	1184	1	song	song	PROPN
eurjchem-604	1184	2	,	,	PUNCT
eurjchem-604	1184	3	l.	l.	PROPN
eurjchem-604	1184	4	c.	c.	PROPN
eurjchem-604	1184	5	;	;	PUNCT
eurjchem-604	1184	6	zhu	zhu	PROPN
eurjchem-604	1184	7	,	,	PUNCT
eurjchem-604	1184	8	y.	y.	PROPN
eurjchem-604	1184	9	h.	h.	PROPN
eurjchem-604	1184	10	;	;	PUNCT
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eurjchem-604	1184	12	,	,	PUNCT
eurjchem-604	1184	13	q.	q.	PROPN
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eurjchem-604	1184	15	polyhedron	polyhedron	PROPN
eurjchem-604	1184	16	1998	1998	NUM
eurjchem-604	1184	17	,	,	PUNCT
eurjchem-604	1184	18	17(4	17(4	NUM
eurjchem-604	1184	19	)	)	PUNCT
eurjchem-604	1184	20	,	,	PUNCT
eurjchem-604	1184	21	469‐473	469‐473	NUM
eurjchem-604	1184	22	.	.	PUNCT
eurjchem-604	1185	1	[	[	X
eurjchem-604	1185	2	56	56	NUM
eurjchem-604	1185	3	]	]	PUNCT
eurjchem-604	1185	4	.	.	PUNCT
eurjchem-604	1186	1	delgado	delgado	PROPN
eurjchem-604	1186	2	,	,	PUNCT
eurjchem-604	1186	3	y.	y.	PROPN
eurjchem-604	1186	4	o.	o.	PROPN
eurjchem-604	1186	5	;	;	PUNCT
eurjchem-604	1186	6	de	de	PROPN
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eurjchem-604	1186	8	,	,	PUNCT
eurjchem-604	1186	9	j.	j.	PROPN
eurjchem-604	1186	10	;	;	PUNCT
eurjchem-604	1186	11	cortes‐figueroa	cortes‐figueroa	PROPN
eurjchem-604	1186	12	,	,	PUNCT
eurjchem-604	1186	13	j.	j.	PROPN
eurjchem-604	1186	14	e.	e.	PROPN
eurjchem-604	1186	15	j.	j.	PROPN
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eurjchem-604	1186	17	.	.	PUNCT
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eurjchem-604	1187	2	.	.	PUNCT
eurjchem-604	1188	1	2005	2005	NUM
eurjchem-604	1188	2	,	,	PUNCT
eurjchem-604	1188	3	690(14	690(14	NUM
eurjchem-604	1188	4	)	)	PUNCT
eurjchem-604	1188	5	,	,	PUNCT
eurjchem-604	1188	6	3366‐3372	3366‐3372	NUM
eurjchem-604	1188	7	.	.	PUNCT
eurjchem-604	1189	1	[	[	X
eurjchem-604	1189	2	57	57	NUM
eurjchem-604	1189	3	]	]	PUNCT
eurjchem-604	1189	4	.	.	PUNCT
eurjchem-604	1190	1	rivera‐rivera	rivera‐rivera	PROPN
eurjchem-604	1190	2	,	,	PUNCT
eurjchem-604	1190	3	l.	l.	PROPN
eurjchem-604	1190	4	a.	a.	PROPN
eurjchem-604	1190	5	;	;	PUNCT
eurjchem-604	1190	6	roman	roman	NOUN
eurjchem-604	1190	7	,	,	PUNCT
eurjchem-604	1190	8	g.	g.	PROPN
eurjchem-604	1190	9	c.	c.	PROPN
eurjchem-604	1190	10	;	;	PUNCT
eurjchem-604	1190	11	acevedo	acevedo	PROPN
eurjchem-604	1190	12	,	,	PUNCT
eurjchem-604	1190	13	d.	d.	PROPN
eurjchem-604	1190	14	a.	a.	PROPN
eurjchem-604	1190	15	;	;	PUNCT
eurjchem-604	1190	16	delgado	delgado	PROPN
eurjchem-604	1190	17	,	,	PUNCT
eurjchem-604	1190	18	y.	y.	PROPN
eurjchem-604	1190	19	o.	o.	PROPN
eurjchem-604	1190	20	;	;	PUNCT
eurjchem-604	1190	21	figueroa	figueroa	PROPN
eurjchem-604	1190	22	,	,	PUNCT
eurjchem-604	1190	23	j.	j.	PROPN
eurjchem-604	1190	24	e.	e.	PROPN
eurjchem-604	1190	25	c.	c.	PROPN
eurjchem-604	1190	26	inorg	inorg	PROPN
eurjchem-604	1190	27	.	.	PUNCT
eurjchem-604	1191	1	chim	chim	PROPN
eurjchem-604	1191	2	.	.	PUNCT
eurjchem-604	1192	1	acta	acta	PROPN
eurjchem-604	1192	2	2004	2004	NUM
eurjchem-604	1192	3	,	,	PUNCT
eurjchem-604	1192	4	357(3	357(3	NUM
eurjchem-604	1192	5	)	)	PUNCT
eurjchem-604	1192	6	,	,	PUNCT
eurjchem-604	1192	7	881‐887	881‐887	NUM
eurjchem-604	1192	8	.	.	PUNCT
eurjchem-604	1193	1	[	[	X
eurjchem-604	1193	2	58	58	NUM
eurjchem-604	1193	3	]	]	PUNCT
eurjchem-604	1193	4	.	.	PUNCT
eurjchem-604	1194	1	kocak	kocak	PROPN
eurjchem-604	1194	2	,	,	PUNCT
eurjchem-604	1194	3	f.	f.	PROPN
eurjchem-604	1194	4	s.	s.	PROPN
eurjchem-604	1194	5	,	,	PUNCT
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eurjchem-604	1194	7	entitled	entitle	VERB
eurjchem-604	1194	8	“	"	PUNCT
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eurjchem-604	1194	12	of	of	ADP
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eurjchem-604	1194	14	[	[	X
eurjchem-604	1194	15	n	n	CCONJ
eurjchem-604	1194	16	,	,	PUNCT
eurjchem-604	1194	17	n’‐bis(ferrocenylmethylene	n’‐bis(ferrocenylmethylene	ADJ
eurjchem-604	1194	18	)	)	PUNCT
eurjchem-604	1194	19	ethylenediamine	ethylenediamine	NOUN
eurjchem-604	1194	20	]	]	X
eurjchem-604	1194	21	molybdenum	molybdenum	NOUN
eurjchem-604	1194	22	(	(	PUNCT
eurjchem-604	1194	23	0	0	NUM
eurjchem-604	1194	24	)	)	PUNCT
eurjchem-604	1194	25	complexe	complexe	PROPN
eurjchem-604	1194	26	”	"	PUNCT
eurjchem-604	1194	27	,	,	PUNCT
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eurjchem-604	1194	29	east	east	PROPN
eurjchem-604	1194	30	technical	technical	PROPN
eurjchem-604	1194	31	university	university	PROPN
eurjchem-604	1194	32	,	,	PUNCT
eurjchem-604	1194	33	p.	p.	PROPN
eurjchem-604	1194	34	p.	p.	PROPN
eurjchem-604	1194	35	34‐35	34‐35	NUM
eurjchem-604	1194	36	,	,	PUNCT
eurjchem-604	1194	37	may	may	AUX
eurjchem-604	1194	38	2005	2005	NUM
eurjchem-604	1194	39	.	.	PUNCT
eurjchem-604	1195	1	[	[	X
eurjchem-604	1195	2	59	59	NUM
eurjchem-604	1195	3	]	]	PUNCT
eurjchem-604	1195	4	.	.	PUNCT
eurjchem-604	1196	1	king	king	PROPN
eurjchem-604	1196	2	,	,	PUNCT
eurjchem-604	1196	3	r.	r.	PROPN
eurjchem-604	1196	4	b.	b.	PROPN
eurjchem-604	1196	5	inorg	inorg	PROPN
eurjchem-604	1196	6	.	.	PUNCT
eurjchem-604	1197	1	chem	chem	PROPN
eurjchem-604	1197	2	.	.	PUNCT
eurjchem-604	1198	1	1963	1963	NUM
eurjchem-604	1198	2	,	,	PUNCT
eurjchem-604	1198	3	2	2	NUM
eurjchem-604	1198	4	,	,	PUNCT
eurjchem-604	1198	5	936‐944	936‐944	NUM
eurjchem-604	1198	6	.	.	PUNCT
eurjchem-604	1199	1	[	[	X
eurjchem-604	1199	2	60	60	NUM
eurjchem-604	1199	3	]	]	PUNCT
eurjchem-604	1199	4	.	.	PUNCT
eurjchem-604	1199	5	werner	werner	PROPN
eurjchem-604	1199	6	,	,	PUNCT
eurjchem-604	1199	7	h.	h.	PROPN
eurjchem-604	1199	8	;	;	PUNCT
eurjchem-604	1199	9	prinz	prinz	PROPN
eurjchem-604	1199	10	,	,	PUNCT
eurjchem-604	1199	11	r.	r.	PROPN
eurjchem-604	1199	12	chem	chem	PROPN
eurjchem-604	1199	13	.	.	PUNCT
eurjchem-604	1200	1	ber	ber	PROPN
eurjchem-604	1200	2	.	.	PUNCT
eurjchem-604	1200	3	1967	1967	NUM
eurjchem-604	1200	4	,	,	PUNCT
eurjchem-604	1200	5	100	100	NUM
eurjchem-604	1200	6	,	,	PUNCT
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eurjchem-604	1200	8	.	.	PUNCT
eurjchem-604	1201	1	[	[	X
eurjchem-604	1201	2	61	61	NUM
eurjchem-604	1201	3	]	]	PUNCT
eurjchem-604	1201	4	.	.	PUNCT
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eurjchem-604	1202	2	,	,	PUNCT
eurjchem-604	1202	3	r.	r.	PROPN
eurjchem-604	1202	4	b.	b.	PROPN
eurjchem-604	1202	5	,	,	PUNCT
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eurjchem-604	1202	8	,	,	PUNCT
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eurjchem-604	1202	10	.	.	NOUN
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eurjchem-604	1202	12	,	,	PUNCT
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eurjchem-604	1202	15	,	,	PUNCT
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eurjchem-604	1202	18	,	,	PUNCT
eurjchem-604	1202	19	n.	n.	PROPN
eurjchem-604	1202	20	y.	y.	PROPN
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eurjchem-604	1202	23	.	.	PUNCT
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eurjchem-604	1203	2	,	,	PUNCT
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eurjchem-604	1203	4	.	.	PUNCT
eurjchem-604	1204	1	[	[	X
eurjchem-604	1204	2	62	62	NUM
eurjchem-604	1204	3	]	]	PUNCT
eurjchem-604	1204	4	.	.	PUNCT
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eurjchem-604	1204	6	,	,	PUNCT
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eurjchem-604	1204	8	a.	a.	PROPN
eurjchem-604	1204	9	;	;	PUNCT
eurjchem-604	1204	10	pratt	pratt	PROPN
eurjchem-604	1204	11	,	,	PUNCT
eurjchem-604	1204	12	l.	l.	PROPN
eurjchem-604	1204	13	;	;	PUNCT
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eurjchem-604	1204	15	,	,	PUNCT
eurjchem-604	1204	16	g.	g.	PROPN
eurjchem-604	1204	17	j.	j.	PROPN
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eurjchem-604	1204	19	.	.	PUNCT
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eurjchem-604	1205	2	.	.	PUNCT
eurjchem-604	1206	1	1961	1961	NUM
eurjchem-604	1206	2	,	,	PUNCT
eurjchem-604	1206	3	2037‐	2037‐	NUM
eurjchem-604	1206	4	2044	2044	NUM
eurjchem-604	1206	5	.	.	PUNCT
eurjchem-604	1207	1	[	[	X
eurjchem-604	1207	2	63	63	NUM
eurjchem-604	1207	3	]	]	PUNCT
eurjchem-604	1207	4	.	.	PUNCT
eurjchem-604	1208	1	king	king	PROPN
eurjchem-604	1208	2	r.	r.	PROPN
eurjchem-604	1208	3	b.	b.	PROPN
eurjchem-604	1208	4	;	;	PUNCT
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eurjchem-604	1208	6	,	,	PUNCT
eurjchem-604	1208	7	t.	t.	PROPN
eurjchem-604	1208	8	f.	f.	PROPN
eurjchem-604	1208	9	inorg	inorg	PROPN
eurjchem-604	1208	10	.	.	PUNCT
eurjchem-604	1209	1	chem	chem	PROPN
eurjchem-604	1209	2	.	.	PUNCT
eurjchem-604	1210	1	1971	1971	NUM
eurjchem-604	1210	2	,	,	PUNCT
eurjchem-604	1210	3	10(6	10(6	NOUN
eurjchem-604	1210	4	)	)	PUNCT
eurjchem-604	1210	5	,	,	PUNCT
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eurjchem-604	1210	7	.	.	PUNCT
eurjchem-604	1211	1	[	[	X
eurjchem-604	1211	2	64	64	NUM
eurjchem-604	1211	3	]	]	PUNCT
eurjchem-604	1211	4	.	.	PUNCT
eurjchem-604	1212	1	heuer	heuer	PROPN
eurjchem-604	1212	2	,	,	PUNCT
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eurjchem-604	1212	4	;	;	PUNCT
eurjchem-604	1212	5	matthews	matthews	PROPN
eurjchem-604	1212	6	,	,	PUNCT
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eurjchem-604	1212	8	l.	l.	PROPN
eurjchem-604	1212	9	;	;	PUNCT
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eurjchem-604	1212	11	,	,	PUNCT
eurjchem-604	1212	12	g.	g.	PROPN
eurjchem-604	1212	13	;	;	PUNCT
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eurjchem-604	1212	15	,	,	PUNCT
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eurjchem-604	1212	17	j.	j.	PROPN
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eurjchem-604	1212	19	.	.	PUNCT
eurjchem-604	1213	1	chem	chem	NOUN
eurjchem-604	1213	2	.	.	PUNCT
eurjchem-604	1214	1	2002	2002	NUM
eurjchem-604	1214	2	,	,	PUNCT
eurjchem-604	1214	3	655(1‐2	655(1‐2	NUM
eurjchem-604	1214	4	)	)	PUNCT
eurjchem-604	1214	5	,	,	PUNCT
eurjchem-604	1214	6	55‐62	55‐62	NUM
eurjchem-604	1214	7	.	.	PUNCT
eurjchem-604	1215	1	[	[	X
eurjchem-604	1215	2	65	65	NUM
eurjchem-604	1215	3	]	]	PUNCT
eurjchem-604	1215	4	.	.	PUNCT
eurjchem-604	1216	1	fisher	fisher	PROPN
eurjchem-604	1216	2	,	,	PUNCT
eurjchem-604	1216	3	e.	e.	PROPN
eurjchem-604	1216	4	o.	o.	PROPN
eurjchem-604	1216	5	;	;	PUNCT
eurjchem-604	1216	6	frohlich	frohlich	PROPN
eurjchem-604	1216	7	,	,	PUNCT
eurjchem-604	1216	8	w.	w.	PROPN
eurjchem-604	1216	9	chem	chem	PROPN
eurjchem-604	1216	10	.	.	PUNCT
eurjchem-604	1217	1	ber	ber	PROPN
eurjchem-604	1217	2	.	.	PUNCT
eurjchem-604	1217	3	1959	1959	NUM
eurjchem-604	1217	4	,	,	PUNCT
eurjchem-604	1217	5	92	92	NUM
eurjchem-604	1217	6	,	,	PUNCT
eurjchem-604	1217	7	2995‐2998	2995‐2998	NUM
eurjchem-604	1217	8	.	.	PUNCT
eurjchem-604	1218	1	[	[	X
eurjchem-604	1218	2	66	66	NUM
eurjchem-604	1218	3	]	]	PUNCT
eurjchem-604	1218	4	.	.	PUNCT
eurjchem-604	1218	5	king	king	PROPN
eurjchem-604	1218	6	,	,	PUNCT
eurjchem-604	1218	7	r.	r.	PROPN
eurjchem-604	1218	8	b.	b.	PROPN
eurjchem-604	1218	9	j.	j.	PROPN
eurjchem-604	1218	10	organomet	organomet	PROPN
eurjchem-604	1218	11	.	.	PUNCT
eurjchem-604	1219	1	chem	chem	PROPN
eurjchem-604	1219	2	.	.	PUNCT
eurjchem-604	1220	1	1967	1967	NUM
eurjchem-604	1220	2	,	,	PUNCT
eurjchem-604	1220	3	8(1	8(1	NOUN
eurjchem-604	1220	4	)	)	PUNCT
eurjchem-604	1220	5	,	,	PUNCT
eurjchem-604	1220	6	139‐148	139‐148	NUM
eurjchem-604	1220	7	.	.	PUNCT
eurjchem-604	1221	1	[	[	X
eurjchem-604	1221	2	67	67	NUM
eurjchem-604	1221	3	]	]	PUNCT
eurjchem-604	1221	4	.	.	PUNCT
eurjchem-604	1222	1	kayran	kayran	PROPN
eurjchem-604	1222	2	,	,	PUNCT
eurjchem-604	1222	3	c.	c.	NOUN
eurjchem-604	1222	4	;	;	PUNCT
eurjchem-604	1222	5	kozanoglu	kozanoglu	NOUN
eurjchem-604	1222	6	,	,	PUNCT
eurjchem-604	1222	7	f.	f.	PROPN
eurjchem-604	1222	8	;	;	PUNCT
eurjchem-604	1222	9	ozkar	ozkar	PROPN
eurjchem-604	1222	10	,	,	PUNCT
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eurjchem-604	1222	12	;	;	PUNCT
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eurjchem-604	1222	14	,	,	PUNCT
eurjchem-604	1222	15	s.	s.	PROPN
eurjchem-604	1222	16	;	;	PUNCT
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eurjchem-604	1222	18	,	,	PUNCT
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eurjchem-604	1222	20	;	;	PUNCT
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eurjchem-604	1222	22	,	,	PUNCT
eurjchem-604	1222	23	c.	c.	PROPN
eurjchem-604	1222	24	g.	g.	PROPN
eurjchem-604	1222	25	inorg	inorg	PROPN
eurjchem-604	1222	26	.	.	PUNCT
eurjchem-604	1223	1	chim	chim	PROPN
eurjchem-604	1223	2	.	.	PUNCT
eurjchem-604	1224	1	acta	acta	PROPN
eurjchem-604	1224	2	1999	1999	NUM
eurjchem-604	1224	3	,	,	PUNCT
eurjchem-604	1224	4	284(2	284(2	NUM
eurjchem-604	1224	5	)	)	PUNCT
eurjchem-604	1224	6	,	,	PUNCT
eurjchem-604	1224	7	229‐236	229‐236	NUM
eurjchem-604	1224	8	.	.	PUNCT
eurjchem-604	1225	1	[	[	X
eurjchem-604	1225	2	68	68	NUM
eurjchem-604	1225	3	]	]	PUNCT
eurjchem-604	1225	4	.	.	PUNCT
eurjchem-604	1226	1	chen	chen	PROPN
eurjchem-604	1226	2	,	,	PUNCT
eurjchem-604	1226	3	j.	j.	PROPN
eurjchem-604	1226	4	;	;	PUNCT
eurjchem-604	1226	5	angelici	angelici	PROPN
eurjchem-604	1226	6	,	,	PUNCT
eurjchem-604	1226	7	r.	r.	PROPN
eurjchem-604	1226	8	j.	j.	PROPN
eurjchem-604	1226	9	inorg	inorg	PROPN
eurjchem-604	1226	10	.	.	PUNCT
eurjchem-604	1227	1	chim	chim	PROPN
eurjchem-604	1227	2	.	.	PUNCT
eurjchem-604	1228	1	acta	acta	PROPN
eurjchem-604	1228	2	2002	2002	NUM
eurjchem-604	1228	3	,	,	PUNCT
eurjchem-604	1228	4	334	334	NUM
eurjchem-604	1228	5	,	,	PUNCT
eurjchem-604	1228	6	204‐212	204‐212	NUM
eurjchem-604	1228	7	.	.	PUNCT
eurjchem-604	1229	1	[	[	X
eurjchem-604	1229	2	69	69	NUM
eurjchem-604	1229	3	]	]	SYM
eurjchem-604	1229	4	.	.	PUNCT
eurjchem-604	1230	1	mitoraj	mitoraj	ADJ
eurjchem-604	1230	2	,	,	PUNCT
eurjchem-604	1230	3	m.	m.	NOUN
eurjchem-604	1230	4	p.	p.	NOUN
eurjchem-604	1230	5	;	;	PUNCT
eurjchem-604	1230	6	michalak	michalak	NOUN
eurjchem-604	1230	7	,	,	PUNCT
eurjchem-604	1230	8	a.	a.	PROPN
eurjchem-604	1230	9	j.	j.	PROPN
eurjchem-604	1230	10	mol	mol	PROPN
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eurjchem-604	1230	13	.	.	PUNCT
eurjchem-604	1231	1	2010	2010	NUM
eurjchem-604	1231	2	,	,	PUNCT
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eurjchem-604	1231	4	,	,	PUNCT
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eurjchem-604	1231	6	.	.	PUNCT
eurjchem-604	1232	1	[	[	X
eurjchem-604	1232	2	70	70	NUM
eurjchem-604	1232	3	]	]	PUNCT
eurjchem-604	1232	4	.	.	PUNCT
eurjchem-604	1232	5	darensbourg	darensbourg	PROPN
eurjchem-604	1232	6	,	,	PUNCT
eurjchem-604	1232	7	d.	d.	PROPN
eurjchem-604	1232	8	j.	j.	PROPN
eurjchem-604	1232	9	;	;	PUNCT
eurjchem-604	1232	10	kump	kump	PROPN
eurjchem-604	1232	11	,	,	PUNCT
eurjchem-604	1232	12	r.	r.	PROPN
eurjchem-604	1232	13	l.	l.	PROPN
eurjchem-604	1232	14	inorg	inorg	PROPN
eurjchem-604	1232	15	.	.	PUNCT
eurjchem-604	1233	1	chem	chem	PROPN
eurjchem-604	1233	2	.	.	PUNCT
eurjchem-604	1234	1	1978	1978	NUM
eurjchem-604	1234	2	,	,	PUNCT
eurjchem-604	1234	3	17(9	17(9	NOUN
eurjchem-604	1234	4	)	)	PUNCT
eurjchem-604	1234	5	,	,	PUNCT
eurjchem-604	1234	6	2680‐	2680‐	NUM
eurjchem-604	1234	7	2682	2682	NUM
eurjchem-604	1234	8	.	.	PUNCT
eurjchem-604	1235	1	[	[	X
eurjchem-604	1235	2	71	71	NUM
eurjchem-604	1235	3	]	]	PUNCT
eurjchem-604	1235	4	.	.	PUNCT
eurjchem-604	1236	1	garcia‐escudero	garcia‐escudero	NOUN
eurjchem-604	1236	2	,	,	PUNCT
eurjchem-604	1236	3	l.	l.	PROPN
eurjchem-604	1236	4	a.	a.	PROPN
eurjchem-604	1236	5	;	;	PUNCT
eurjchem-604	1236	6	miguel	miguel	PROPN
eurjchem-604	1236	7	,	,	PUNCT
eurjchem-604	1236	8	d.	d.	PROPN
eurjchem-604	1236	9	;	;	PUNCT
eurjchem-604	1236	10	turiel	turiel	PROPN
eurjchem-604	1236	11	,	,	PUNCT
eurjchem-604	1236	12	j.	j.	PROPN
eurjchem-604	1236	13	a.	a.	PROPN
eurjchem-604	1236	14	j.	j.	PROPN
eurjchem-604	1236	15	organomet	organomet	PROPN
eurjchem-604	1236	16	.	.	PUNCT
eurjchem-604	1237	1	chem	chem	NOUN
eurjchem-604	1237	2	.	.	PUNCT
eurjchem-604	1238	1	2006	2006	NUM
eurjchem-604	1238	2	,	,	PUNCT
eurjchem-604	1238	3	691(16	691(16	NUM
eurjchem-604	1238	4	)	)	PUNCT
eurjchem-604	1238	5	,	,	PUNCT
eurjchem-604	1238	6	3434‐3444	3434‐3444	NUM
eurjchem-604	1238	7	.	.	PUNCT
eurjchem-604	1239	1	[	[	X
eurjchem-604	1239	2	72	72	NUM
eurjchem-604	1239	3	]	]	PUNCT
eurjchem-604	1239	4	.	.	PUNCT
eurjchem-604	1240	1	guinn	guinn	PROPN
eurjchem-604	1240	2	r.	r.	PROPN
eurjchem-604	1240	3	h.	h.	PROPN
eurjchem-604	1240	4	;	;	PUNCT
eurjchem-604	1240	5	gilliland	gilliland	PROPN
eurjchem-604	1240	6	,	,	PUNCT
eurjchem-604	1240	7	r.	r.	PROPN
eurjchem-604	1240	8	,	,	PUNCT
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eurjchem-604	1240	10	3	3	NUM
eurjchem-604	1240	11	.	.	PUNCT
eurjchem-604	1240	12	14‐identification	14‐identification	NUM
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eurjchem-604	1240	15	(	(	PUNCT
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eurjchem-604	1240	17	)	)	PUNCT
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eurjchem-604	1240	20	[	[	X
eurjchem-604	1240	21	mo(co)4(l)2	mo(co)4(l)2	X
eurjchem-604	1240	22	]	]	PUNCT
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eurjchem-604	1240	24	infra‐	infra‐	PROPN
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eurjchem-604	1240	27	,	,	PUNCT
eurjchem-604	1240	28	1‐6	1‐6	NUM
eurjchem-604	1240	29	,	,	PUNCT
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eurjchem-604	1240	31	15	15	NUM
eurjchem-604	1240	32	,	,	PUNCT
eurjchem-604	1240	33	2008	2008	NUM
eurjchem-604	1241	1	[	[	X
eurjchem-604	1241	2	http://science	http://science	NOUN
eurjchem-604	1241	3	.	.	PUNCT
eurjchem-604	1241	4	herograw	herograw	PROPN
eurjchem-604	1241	5	.	.	PUNCT
eurjchem-604	1242	1	net	net	ADJ
eurjchem-604	1242	2	/	/	SYM
eurjchem-604	1242	3	lbox	lbox	NOUN
eurjchem-604	1242	4	/	/	SYM
eurjchem-604	1242	5	c423l‐e314	c423l‐e314	NOUN
eurjchem-604	1242	6	.	.	PUNCT
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eurjchem-604	1242	8	]	]	PUNCT
eurjchem-604	1243	1	[	[	X
eurjchem-604	1243	2	73	73	NUM
eurjchem-604	1243	3	]	]	PUNCT
eurjchem-604	1243	4	.	.	PUNCT
eurjchem-604	1244	1	allen	allen	PROPN
eurjchem-604	1244	2	,	,	PUNCT
eurjchem-604	1244	3	a.	a.	PROPN
eurjchem-604	1244	4	;	;	PUNCT
eurjchem-604	1244	5	barrett	barrett	PROPN
eurjchem-604	1244	6	,	,	PUNCT
eurjchem-604	1244	7	p.	p.	PROPN
eurjchem-604	1244	8	can	can	AUX
eurjchem-604	1244	9	.	.	PUNCT
eurjchem-604	1245	1	j.	j.	PROPN
eurjchem-604	1245	2	chem	chem	PROPN
eurjchem-604	1245	3	.	.	PUNCT
eurjchem-604	1246	1	1968	1968	NUM
eurjchem-604	1246	2	,	,	PUNCT
eurjchem-604	1246	3	46	46	NUM
eurjchem-604	1246	4	,	,	PUNCT
eurjchem-604	1246	5	1649‐1653	1649‐1653	NUM
eurjchem-604	1246	6	.	.	PUNCT
eurjchem-604	1247	1	[	[	X
eurjchem-604	1247	2	74	74	NUM
eurjchem-604	1247	3	]	]	PUNCT
eurjchem-604	1247	4	.	.	PUNCT
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eurjchem-604	1247	6	,	,	PUNCT
eurjchem-604	1247	7	w.	w.	PROPN
eurjchem-604	1247	8	;	;	PUNCT
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eurjchem-604	1247	10	,	,	PUNCT
eurjchem-604	1247	11	g.	g.	PROPN
eurjchem-604	1247	12	chem	chem	PROPN
eurjchem-604	1247	13	.	.	PUNCT
eurjchem-604	1248	1	ber	ber	NOUN
eurjchem-604	1248	2	.	.	PUNCT
eurjchem-604	1249	1	1961	1961	NUM
eurjchem-604	1249	2	,	,	PUNCT
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eurjchem-604	1249	4	,	,	PUNCT
eurjchem-604	1249	5	1346‐1349	1346‐1349	NUM
eurjchem-604	1249	6	.	.	PUNCT
eurjchem-604	1250	1	[	[	X
eurjchem-604	1250	2	75	75	NUM
eurjchem-604	1250	3	]	]	PUNCT
eurjchem-604	1250	4	.	.	PUNCT
eurjchem-604	1251	1	strohmeier	strohmeier	PROPN
eurjchem-604	1251	2	,	,	PUNCT
eurjchem-604	1251	3	w.	w.	PROPN
eurjchem-604	1251	4	;	;	PUNCT
eurjchem-604	1251	5	gerlach	gerlach	PROPN
eurjchem-604	1251	6	,	,	PUNCT
eurjchem-604	1251	7	k.	k.	PROPN
eurjchem-604	1251	8	z.	z.	PROPN
eurjchem-604	1251	9	naturforsch	naturforsch	PROPN
eurjchem-604	1251	10	.	.	PUNCT
eurjchem-604	1252	1	1960	1960	NUM
eurjchem-604	1252	2	,	,	PUNCT
eurjchem-604	1252	3	15b	15b	NUM
eurjchem-604	1252	4	,	,	PUNCT
eurjchem-604	1252	5	622‐622	622‐622	NUM
eurjchem-604	1252	6	.	.	PUNCT
eurjchem-604	1253	1	[	[	X
eurjchem-604	1253	2	76	76	NUM
eurjchem-604	1253	3	]	]	PUNCT
eurjchem-604	1253	4	.	.	PUNCT
eurjchem-604	1254	1	werner	werner	PROPN
eurjchem-604	1254	2	,	,	PUNCT
eurjchem-604	1254	3	r.	r.	PROPN
eurjchem-604	1254	4	p.	p.	PROPN
eurjchem-604	1254	5	m.	m.	NOUN
eurjchem-604	1254	6	;	;	PUNCT
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eurjchem-604	1254	8	,	,	PUNCT
eurjchem-604	1254	9	t.	t.	PROPN
eurjchem-604	1254	10	h.	h.	PROPN
eurjchem-604	1254	11	,	,	PUNCT
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eurjchem-604	1254	17	,	,	PUNCT
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eurjchem-604	1254	19	,	,	PUNCT
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eurjchem-604	1254	21	p.	p.	NOUN
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eurjchem-604	1254	23	,	,	PUNCT
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eurjchem-604	1254	29	,	,	PUNCT
eurjchem-604	1254	30	1961	1961	NUM
eurjchem-604	1254	31	.	.	PUNCT
eurjchem-604	1255	1	[	[	X
eurjchem-604	1255	2	77	77	NUM
eurjchem-604	1255	3	]	]	SYM
eurjchem-604	1255	4	.	.	PUNCT
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eurjchem-604	1256	2	,	,	PUNCT
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eurjchem-604	1256	4	r.	r.	PROPN
eurjchem-604	1256	5	;	;	PUNCT
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eurjchem-604	1256	7	,	,	PUNCT
eurjchem-604	1256	8	m.	m.	PROPN
eurjchem-604	1256	9	f.	f.	PROPN
eurjchem-604	1256	10	a.	a.	PROPN
eurjchem-604	1256	11	;	;	PUNCT
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eurjchem-604	1256	13	,	,	PUNCT
eurjchem-604	1256	14	i.	i.	PROPN
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eurjchem-604	1256	16	;	;	PUNCT
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eurjchem-604	1256	18	,	,	PUNCT
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eurjchem-604	1256	20	k.	k.	PROPN
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eurjchem-604	1256	22	.	.	PUNCT
eurjchem-604	1257	1	chem	chem	PROPN
eurjchem-604	1257	2	.	.	PUNCT
eurjchem-604	1258	1	1962	1962	NUM
eurjchem-604	1258	2	,	,	PUNCT
eurjchem-604	1258	3	1(3	1(3	NUM
eurjchem-604	1258	4	)	)	PUNCT
eurjchem-604	1258	5	,	,	PUNCT
eurjchem-604	1258	6	526‐530	526‐530	NUM
eurjchem-604	1258	7	.	.	PUNCT
eurjchem-604	1259	1	[	[	X
eurjchem-604	1259	2	78	78	NUM
eurjchem-604	1259	3	]	]	PUNCT
eurjchem-604	1259	4	.	.	PUNCT
eurjchem-604	1260	1	dai	dai	PROPN
eurjchem-604	1260	2	,	,	PUNCT
eurjchem-604	1260	3	h.	h.	PROPN
eurjchem-604	1260	4	f.	f.	PROPN
eurjchem-604	1260	5	;	;	PUNCT
eurjchem-604	1260	6	yeh	yeh	PROPN
eurjchem-604	1260	7	,	,	PUNCT
eurjchem-604	1260	8	w.	w.	PROPN
eurjchem-604	1260	9	y.	y.	PROPN
eurjchem-604	1260	10	inorg	inorg	PROPN
eurjchem-604	1260	11	.	.	PUNCT
eurjchem-604	1261	1	chim	chim	PROPN
eurjchem-604	1261	2	.	.	PUNCT
eurjchem-604	1262	1	acta	acta	PROPN
eurjchem-604	1262	2	2010	2010	NUM
eurjchem-604	1262	3	,	,	PUNCT
eurjchem-604	1262	4	363(5	363(5	NUM
eurjchem-604	1262	5	)	)	PUNCT
eurjchem-604	1262	6	,	,	PUNCT
eurjchem-604	1262	7	925‐929	925‐929	NOUN
eurjchem-604	1262	8	.	.	PUNCT
eurjchem-604	1263	1	[	[	X
eurjchem-604	1263	2	79	79	NUM
eurjchem-604	1263	3	]	]	PUNCT
eurjchem-604	1263	4	.	.	PUNCT
eurjchem-604	1264	1	carnahan	carnahan	PROPN
eurjchem-604	1264	2	,	,	PUNCT
eurjchem-604	1264	3	e.	e.	PROPN
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eurjchem-604	1264	5	;	;	PUNCT
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eurjchem-604	1264	7	,	,	PUNCT
eurjchem-604	1264	8	j.	j.	PROPN
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eurjchem-604	1264	10	;	;	PUNCT
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eurjchem-604	1264	12	,	,	PUNCT
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eurjchem-604	1264	17	.	.	PUNCT
eurjchem-604	1265	1	res	re	NOUN
eurjchem-604	1265	2	.	.	PUNCT
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eurjchem-604	1265	4	,	,	PUNCT
eurjchem-604	1265	5	26	26	NUM
eurjchem-604	1265	6	,	,	PUNCT
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eurjchem-604	1265	8	.	.	PUNCT
eurjchem-604	1266	1	[	[	X
eurjchem-604	1266	2	80	80	NUM
eurjchem-604	1266	3	]	]	PUNCT
eurjchem-604	1266	4	.	.	PUNCT
eurjchem-604	1267	1	smith	smith	PROPN
eurjchem-604	1267	2	,	,	PUNCT
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eurjchem-604	1267	4	p.	p.	NOUN
eurjchem-604	1267	5	;	;	PUNCT
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eurjchem-604	1267	7	,	,	PUNCT
eurjchem-604	1267	8	j.	j.	PROPN
eurjchem-604	1267	9	j.	j.	PROPN
eurjchem-604	1267	10	s.	s.	PROPN
eurjchem-604	1267	11	;	;	PUNCT
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eurjchem-604	1267	13	,	,	PUNCT
eurjchem-604	1267	14	c.	c.	PROPN
eurjchem-604	1267	15	l.	l.	PROPN
eurjchem-604	1267	16	;	;	PUNCT
eurjchem-604	1267	17	org	org	PROPN
eurjchem-604	1267	18	.	.	PUNCT
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eurjchem-604	1267	20	.	.	PUNCT
eurjchem-604	1268	1	2004	2004	NUM
eurjchem-604	1268	2	,	,	PUNCT
eurjchem-604	1268	3	10	10	NUM
eurjchem-604	1268	4	,	,	PUNCT
eurjchem-604	1268	5	107‐	107‐	NUM
eurjchem-604	1268	6	107	107	NUM
eurjchem-604	1268	7	.	.	PUNCT
eurjchem-604	1269	1	[	[	X
eurjchem-604	1269	2	81	81	NUM
eurjchem-604	1269	3	]	]	PUNCT
eurjchem-604	1269	4	.	.	PUNCT
eurjchem-604	1270	1	darensbourg	darensbourg	PROPN
eurjchem-604	1270	2	,	,	PUNCT
eurjchem-604	1270	3	d.	d.	PROPN
eurjchem-604	1270	4	j.	j.	PROPN
eurjchem-604	1270	5	;	;	PUNCT
eurjchem-604	1270	6	kump	kump	PROPN
eurjchem-604	1270	7	,	,	PUNCT
eurjchem-604	1270	8	r.	r.	PROPN
eurjchem-604	1270	9	l.	l.	PROPN
eurjchem-604	1270	10	inorg	inorg	PROPN
eurjchem-604	1270	11	.	.	PUNCT
eurjchem-604	1271	1	chem	chem	PROPN
eurjchem-604	1271	2	.	.	PUNCT
eurjchem-604	1272	1	1978	1978	NUM
eurjchem-604	1272	2	,	,	PUNCT
eurjchem-604	1272	3	17(9	17(9	NOUN
eurjchem-604	1272	4	)	)	PUNCT
eurjchem-604	1272	5	,	,	PUNCT
eurjchem-604	1272	6	2680‐	2680‐	NUM
eurjchem-604	1272	7	2682	2682	NUM
eurjchem-604	1272	8	.	.	PUNCT
eurjchem-604	1273	1	[	[	X
eurjchem-604	1273	2	82	82	NUM
eurjchem-604	1273	3	]	]	PUNCT
eurjchem-604	1273	4	.	.	PUNCT
eurjchem-604	1274	1	manuta	manuta	ADV
eurjchem-604	1274	2	,	,	PUNCT
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eurjchem-604	1274	5	;	;	PUNCT
eurjchem-604	1274	6	lees	lee	NOUN
eurjchem-604	1274	7	,	,	PUNCT
eurjchem-604	1274	8	a.	a.	PROPN
eurjchem-604	1274	9	j.	j.	PROPN
eurjchem-604	1274	10	j.	j.	PROPN
eurjchem-604	1274	11	chem	chem	PROPN
eurjchem-604	1274	12	.	.	PUNCT
eurjchem-604	1275	1	educ	educ	PROPN
eurjchem-604	1275	2	.	.	PUNCT
eurjchem-604	1276	1	1987	1987	NUM
eurjchem-604	1276	2	,	,	PUNCT
eurjchem-604	1276	3	64(7	64(7	NOUN
eurjchem-604	1276	4	)	)	PUNCT
eurjchem-604	1276	5	,	,	PUNCT
eurjchem-604	1276	6	637‐638	637‐638	PROPN
eurjchem-604	1276	7	.	.	PUNCT
eurjchem-604	1277	1	[	[	X
eurjchem-604	1277	2	83	83	NUM
eurjchem-604	1277	3	]	]	PUNCT
eurjchem-604	1277	4	.	.	PUNCT
eurjchem-604	1278	1	basolo	basolo	PROPN
eurjchem-604	1278	2	,	,	PUNCT
eurjchem-604	1278	3	f.	f.	PROPN
eurjchem-604	1278	4	;	;	PUNCT
eurjchem-604	1278	5	mcdonald	mcdonald	PROPN
eurjchem-604	1278	6	,	,	PUNCT
eurjchem-604	1278	7	j.	j.	PROPN
eurjchem-604	1278	8	w.	w.	PROPN
eurjchem-604	1278	9	inorg	inorg	PROPN
eurjchem-604	1278	10	.	.	PUNCT
eurjchem-604	1279	1	chem	chem	PROPN
eurjchem-604	1279	2	.	.	PUNCT
eurjchem-604	1280	1	1971	1971	NUM
eurjchem-604	1280	2	,	,	PUNCT
eurjchem-604	1280	3	10(3	10(3	NUM
eurjchem-604	1280	4	)	)	PUNCT
eurjchem-604	1280	5	,	,	PUNCT
eurjchem-604	1280	6	492‐497	492‐497	NOUN
eurjchem-604	1280	7	.	.	PUNCT
eurjchem-604	1281	1	[	[	X
eurjchem-604	1281	2	84	84	NUM
eurjchem-604	1281	3	]	]	PUNCT
eurjchem-604	1281	4	.	.	PUNCT
eurjchem-604	1281	5	edinc	edinc	PROPN
eurjchem-604	1281	6	,	,	PUNCT
eurjchem-604	1281	7	p.	p.	NOUN
eurjchem-604	1281	8	;	;	PUNCT
eurjchem-604	1281	9	onal	onal	ADJ
eurjchem-604	1281	10	,	,	PUNCT
eurjchem-604	1281	11	a.	a.	NOUN
eurjchem-604	1281	12	m.	m.	NOUN
eurjchem-604	1281	13	;	;	PUNCT
eurjchem-604	1281	14	ozkar	ozkar	PROPN
eurjchem-604	1281	15	,	,	PUNCT
eurjchem-604	1281	16	s.	s.	PROPN
eurjchem-604	1281	17	j.	j.	PROPN
eurjchem-604	1281	18	organomet	organomet	PROPN
eurjchem-604	1281	19	.	.	PUNCT
eurjchem-604	1282	1	chem	chem	NOUN
eurjchem-604	1282	2	.	.	PUNCT
eurjchem-604	1283	1	2007	2007	NUM
eurjchem-604	1283	2	,	,	PUNCT
eurjchem-604	1283	3	692(10	692(10	NUM
eurjchem-604	1283	4	)	)	PUNCT
eurjchem-604	1283	5	,	,	PUNCT
eurjchem-604	1283	6	1983‐1989	1983‐1989	NUM
eurjchem-604	1283	7	.	.	PUNCT
eurjchem-604	1284	1	[	[	X
eurjchem-604	1284	2	85	85	NUM
eurjchem-604	1284	3	]	]	PUNCT
eurjchem-604	1284	4	.	.	PUNCT
eurjchem-604	1284	5	klanberg	klanberg	PROPN
eurjchem-604	1284	6	,	,	PUNCT
eurjchem-604	1284	7	f.	f.	PROPN
eurjchem-604	1284	8	;	;	PUNCT
eurjchem-604	1284	9	guggenberger	guggenberger	NOUN
eurjchem-604	1284	10	,	,	PUNCT
eurjchem-604	1284	11	l.	l.	PROPN
eurjchem-604	1284	12	j.	j.	PROPN
eurjchem-604	1284	13	chem	chem	PROPN
eurjchem-604	1284	14	.	.	PUNCT
eurjchem-604	1285	1	commun	commun	PROPN
eurjchem-604	1285	2	.	.	PROPN
eurjchem-604	1286	1	1967	1967	NUM
eurjchem-604	1286	2	,	,	PUNCT
eurjchem-604	1286	3	8(24	8(24	NUM
eurjchem-604	1286	4	)	)	PUNCT
eurjchem-604	1286	5	,	,	PUNCT
eurjchem-604	1286	6	1293‐	1293‐	NUM
eurjchem-604	1286	7	1294	1294	NUM
eurjchem-604	1286	8	.	.	PUNCT
eurjchem-604	1287	1	[	[	X
eurjchem-604	1287	2	86	86	NUM
eurjchem-604	1287	3	]	]	PUNCT
eurjchem-604	1287	4	.	.	PUNCT
eurjchem-604	1288	1	klanberg	klanberg	PROPN
eurjchem-604	1288	2	,	,	PUNCT
eurjchem-604	1288	3	f.	f.	PROPN
eurjchem-604	1288	4	;	;	PUNCT
eurjchem-604	1288	5	mutterties	muttertie	NOUN
eurjchem-604	1288	6	,	,	PUNCT
eurjchem-604	1288	7	e.	e.	PROPN
eurjchem-604	1288	8	l.	l.	PROPN
eurjchem-604	1288	9	j.	j.	PROPN
eurjchem-604	1288	10	am	am	PROPN
eurjchem-604	1288	11	.	.	PUNCT
eurjchem-604	1289	1	chem	chem	PROPN
eurjchem-604	1289	2	.	.	PUNCT
eurjchem-604	1290	1	soc	soc	PROPN
eurjchem-604	1290	2	.	.	PUNCT
eurjchem-604	1291	1	1968	1968	NUM
eurjchem-604	1291	2	,	,	PUNCT
eurjchem-604	1291	3	90(12	90(12	NUM
eurjchem-604	1291	4	)	)	PUNCT
eurjchem-604	1291	5	,	,	PUNCT
eurjchem-604	1291	6	3296‐	3296‐	NUM
eurjchem-604	1291	7	3297	3297	NUM
eurjchem-604	1291	8	.	.	PUNCT
eurjchem-604	1292	1	[	[	X
eurjchem-604	1292	2	87	87	NUM
eurjchem-604	1292	3	]	]	PUNCT
eurjchem-604	1292	4	.	.	PUNCT
eurjchem-604	1292	5	goumans	gouman	NOUN
eurjchem-604	1292	6	,	,	PUNCT
eurjchem-604	1292	7	t.	t.	PROPN
eurjchem-604	1292	8	p.	p.	PROPN
eurjchem-604	1292	9	m.	m.	NOUN
eurjchem-604	1292	10	;	;	PUNCT
eurjchem-604	1292	11	ehlers	ehler	NOUN
eurjchem-604	1292	12	,	,	PUNCT
eurjchem-604	1292	13	a.	a.	PROPN
eurjchem-604	1292	14	w.	w.	PROPN
eurjchem-604	1292	15	;	;	PUNCT
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eurjchem-604	1292	17	,	,	PUNCT
eurjchem-604	1292	18	m.	m.	PROPN
eurjchem-604	1292	19	c.	c.	PROPN
eurjchem-604	1292	20	;	;	PUNCT
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eurjchem-604	1292	22	,	,	PUNCT
eurjchem-604	1292	23	a.	a.	PROPN
eurjchem-604	1292	24	;	;	PUNCT
eurjchem-604	1292	25	baerends	baerend	NOUN
eurjchem-604	1292	26	,	,	PUNCT
eurjchem-604	1292	27	e.	e.	PROPN
eurjchem-604	1292	28	j.	j.	PROPN
eurjchem-604	1292	29	;	;	PUNCT
eurjchem-604	1292	30	lammertsma	lammertsma	PROPN
eurjchem-604	1292	31	,	,	PUNCT
eurjchem-604	1292	32	k.	k.	PROPN
eurjchem-604	1292	33	j.	j.	PROPN
eurjchem-604	1292	34	am	am	PROPN
eurjchem-604	1292	35	.	.	PUNCT
eurjchem-604	1293	1	chem	chem	PROPN
eurjchem-604	1293	2	.	.	PUNCT
eurjchem-604	1294	1	soc	soc	PROPN
eurjchem-604	1294	2	.	.	PUNCT
eurjchem-604	1295	1	2003	2003	NUM
eurjchem-604	1295	2	,	,	PUNCT
eurjchem-604	1295	3	125(12	125(12	NUM
eurjchem-604	1295	4	)	)	PUNCT
eurjchem-604	1295	5	,	,	PUNCT
eurjchem-604	1295	6	3558‐3567	3558‐3567	NUM
eurjchem-604	1295	7	.	.	PUNCT
eurjchem-604	1296	1	[	[	X
eurjchem-604	1296	2	88	88	NUM
eurjchem-604	1296	3	]	]	PUNCT
eurjchem-604	1296	4	.	.	PUNCT
eurjchem-604	1297	1	tate	tate	PROPN
eurjchem-604	1297	2	,	,	PUNCT
eurjchem-604	1297	3	d.	d.	PROPN
eurjchem-604	1297	4	p.	p.	PROPN
eurjchem-604	1297	5	;	;	PUNCT
eurjchem-604	1297	6	knipple	knipple	PROPN
eurjchem-604	1297	7	,	,	PUNCT
eurjchem-604	1297	8	k.	k.	PROPN
eurjchem-604	1297	9	r.	r.	PROPN
eurjchem-604	1297	10	;	;	PUNCT
eurjchem-604	1297	11	augl	augl	NOUN
eurjchem-604	1297	12	,	,	PUNCT
eurjchem-604	1297	13	j.	j.	PROPN
eurjchem-604	1297	14	m.	m.	PROPN
eurjchem-604	1297	15	inorg	inorg	PROPN
eurjchem-604	1297	16	.	.	PUNCT
eurjchem-604	1298	1	chem	chem	PROPN
eurjchem-604	1298	2	.	.	PUNCT
eurjchem-604	1299	1	1962	1962	NUM
eurjchem-604	1299	2	,	,	PUNCT
eurjchem-604	1299	3	1(2	1(2	NUM
eurjchem-604	1299	4	)	)	PUNCT
eurjchem-604	1299	5	,	,	PUNCT
eurjchem-604	1299	6	433‐	433‐	NUM
eurjchem-604	1299	7	444	444	NUM
eurjchem-604	1299	8	.	.	PUNCT
eurjchem-604	1300	1	[	[	X
eurjchem-604	1300	2	89	89	NUM
eurjchem-604	1300	3	]	]	PUNCT
eurjchem-604	1300	4	.	.	PUNCT
eurjchem-604	1300	5	elschenbroich	elschenbroich	PROPN
eurjchem-604	1300	6	,	,	PUNCT
eurjchem-604	1300	7	c.	c.	NOUN
eurjchem-604	1300	8	;	;	PUNCT
eurjchem-604	1300	9	salzer	salzer	NOUN
eurjchem-604	1300	10	,	,	PUNCT
eurjchem-604	1300	11	a.	a.	NOUN
eurjchem-604	1300	12	,	,	PUNCT
eurjchem-604	1300	13	organometallics	organometallic	NOUN
eurjchem-604	1300	14	:	:	PUNCT
eurjchem-604	1300	15	a	a	DET
eurjchem-604	1300	16	concise	concise	ADJ
eurjchem-604	1300	17	introduction	introduction	NOUN
eurjchem-604	1300	18	,	,	PUNCT
eurjchem-604	1300	19	2nd	2nd	ADJ
eurjchem-604	1300	20	ed	ed	NOUN
eurjchem-604	1300	21	.	.	PROPN
eurjchem-604	1300	22	,	,	PUNCT
eurjchem-604	1300	23	wiley‐vch	wiley‐vch	PROPN
eurjchem-604	1300	24	:	:	PUNCT
eurjchem-604	1300	25	weinheim	weinheim	PROPN
eurjchem-604	1300	26	,	,	PUNCT
eurjchem-604	1300	27	1992	1992	NUM
eurjchem-604	1300	28	.	.	PUNCT
eurjchem-604	1301	1	[	[	X
eurjchem-604	1301	2	90	90	NUM
eurjchem-604	1301	3	]	]	PUNCT
eurjchem-604	1301	4	.	.	PUNCT
eurjchem-604	1302	1	tate	tate	PROPN
eurjchem-604	1302	2	,	,	PUNCT
eurjchem-604	1302	3	d.	d.	PROPN
eurjchem-604	1302	4	p.	p.	PROPN
eurjchem-604	1302	5	;	;	PUNCT
eurjchem-604	1302	6	augl	augl	NOUN
eurjchem-604	1302	7	,	,	PUNCT
eurjchem-604	1302	8	j.	j.	PROPN
eurjchem-604	1302	9	m.	m.	PROPN
eurjchem-604	1302	10	;	;	PUNCT
eurjchem-604	1302	11	buss	buss	PROPN
eurjchem-604	1302	12	,	,	PUNCT
eurjchem-604	1302	13	a.	a.	NOUN
eurjchem-604	1302	14	inorg	inorg	PROPN
eurjchem-604	1302	15	.	.	PUNCT
eurjchem-604	1303	1	chem	chem	PROPN
eurjchem-604	1303	2	.	.	PUNCT
eurjchem-604	1304	1	1963	1963	NUM
eurjchem-604	1304	2	,	,	PUNCT
eurjchem-604	1304	3	2(2	2(2	NUM
eurjchem-604	1304	4	)	)	PUNCT
eurjchem-604	1304	5	,	,	PUNCT
eurjchem-604	1304	6	427‐428	427‐428	NUM
eurjchem-604	1304	7	.	.	PUNCT
eurjchem-604	1305	1	[	[	X
eurjchem-604	1305	2	91	91	NUM
eurjchem-604	1305	3	]	]	PUNCT
eurjchem-604	1305	4	.	.	PUNCT
eurjchem-604	1305	5	carey	carey	PROPN
eurjchem-604	1305	6	,	,	PUNCT
eurjchem-604	1305	7	j.	j.	PROPN
eurjchem-604	1305	8	;	;	PUNCT
eurjchem-604	1305	9	fettinger	fettinger	PROPN
eurjchem-604	1305	10	,	,	PUNCT
eurjchem-604	1305	11	j.	j.	PROPN
eurjchem-604	1305	12	c.	c.	PROPN
eurjchem-604	1305	13	;	;	PUNCT
eurjchem-604	1305	14	poli	poli	PROPN
eurjchem-604	1305	15	,	,	PUNCT
eurjchem-604	1305	16	r.	r.	PROPN
eurjchem-604	1305	17	;	;	PUNCT
eurjchem-604	1305	18	smith	smith	PROPN
eurjchem-604	1305	19	,	,	PUNCT
eurjchem-604	1305	20	k.	k.	PROPN
eurjchem-604	1305	21	m.	m.	PROPN
eurjchem-604	1305	22	inorg	inorg	PROPN
eurjchem-604	1305	23	.	.	PUNCT
eurjchem-604	1306	1	chim	chim	PROPN
eurjchem-604	1306	2	.	.	PUNCT
eurjchem-604	1307	1	acta2000	acta2000	PROPN
eurjchem-604	1307	2	,	,	PUNCT
eurjchem-604	1307	3	299(1	299(1	NUM
eurjchem-604	1307	4	)	)	PUNCT
eurjchem-604	1307	5	,	,	PUNCT
eurjchem-604	1307	6	118‐122	118‐122	NUM
eurjchem-604	1307	7	.	.	PUNCT
eurjchem-604	1308	1	[	[	X
eurjchem-604	1308	2	92	92	NUM
eurjchem-604	1308	3	]	]	PUNCT
eurjchem-604	1308	4	.	.	PUNCT
eurjchem-604	1309	1	edelmann	edelmann	PROPN
eurjchem-604	1309	2	,	,	PUNCT
eurjchem-604	1309	3	f.	f.	PROPN
eurjchem-604	1309	4	t.	t.	PROPN
eurjchem-604	1309	5	inorg	inorg	PROPN
eurjchem-604	1309	6	.	.	PUNCT
eurjchem-604	1310	1	chim	chim	PROPN
eurjchem-604	1310	2	.	.	PUNCT
eurjchem-604	1311	1	acta	acta	PROPN
eurjchem-604	1311	2	2004	2004	NUM
eurjchem-604	1311	3	,	,	PUNCT
eurjchem-604	1311	4	357(15	357(15	NUM
eurjchem-604	1311	5	)	)	PUNCT
eurjchem-604	1311	6	,	,	PUNCT
eurjchem-604	1311	7	4592‐4595	4592‐4595	NUM
eurjchem-604	1311	8	.	.	PUNCT
eurjchem-604	1312	1	[	[	X
eurjchem-604	1312	2	93	93	NUM
eurjchem-604	1312	3	]	]	PUNCT
eurjchem-604	1312	4	.	.	PUNCT
eurjchem-604	1313	1	tate	tate	PROPN
eurjchem-604	1313	2	,	,	PUNCT
eurjchem-604	1313	3	d.	d.	PROPN
eurjchem-604	1313	4	p.	p.	PROPN
eurjchem-604	1313	5	;	;	PUNCT
eurjchem-604	1313	6	augl	augl	NOUN
eurjchem-604	1313	7	,	,	PUNCT
eurjchem-604	1313	8	j.	j.	PROPN
eurjchem-604	1313	9	m.	m.	PROPN
eurjchem-604	1313	10	j.	j.	PROPN
eurjchem-604	1313	11	am	am	PROPN
eurjchem-604	1313	12	.	.	PUNCT
eurjchem-604	1314	1	chem	chem	PROPN
eurjchem-604	1314	2	.	.	PUNCT
eurjchem-604	1315	1	soc	soc	PROPN
eurjchem-604	1315	2	.	.	PUNCT
eurjchem-604	1316	1	1963	1963	NUM
eurjchem-604	1316	2	,	,	PUNCT
eurjchem-604	1316	3	85	85	NUM
eurjchem-604	1316	4	,	,	PUNCT
eurjchem-604	1316	5	2174‐2175	2174‐2175	NUM
eurjchem-604	1316	6	.	.	PUNCT
eurjchem-604	1317	1	[	[	X
eurjchem-604	1317	2	94	94	NUM
eurjchem-604	1317	3	]	]	PUNCT
eurjchem-604	1317	4	.	.	PUNCT
eurjchem-604	1317	5	hogarth	hogarth	PROPN
eurjchem-604	1317	6	,	,	PUNCT
eurjchem-604	1317	7	g.	g.	PROPN
eurjchem-604	1317	8	;	;	PUNCT
eurjchem-604	1317	9	norman	norman	PROPN
eurjchem-604	1317	10	,	,	PUNCT
eurjchem-604	1317	11	t.	t.	NOUN
eurjchem-604	1317	12	inorg	inorg	PROPN
eurjchem-604	1317	13	.	.	PUNCT
eurjchem-604	1318	1	chim	chim	PROPN
eurjchem-604	1318	2	.	.	PUNCT
eurjchem-604	1319	1	acta	acta	PROPN
eurjchem-604	1319	2	1997	1997	NUM
eurjchem-604	1319	3	,	,	PUNCT
eurjchem-604	1319	4	254(1	254(1	NUM
eurjchem-604	1319	5	)	)	PUNCT
eurjchem-604	1319	6	,	,	PUNCT
eurjchem-604	1319	7	167‐171	167‐171	NUM
eurjchem-604	1319	8	.	.	PUNCT
eurjchem-604	1320	1	[	[	X
eurjchem-604	1320	2	95	95	NUM
eurjchem-604	1320	3	]	]	PUNCT
eurjchem-604	1320	4	.	.	PUNCT
eurjchem-604	1321	1	green	green	ADJ
eurjchem-604	1321	2	,	,	PUNCT
eurjchem-604	1321	3	m.	m.	PROPN
eurjchem-604	1321	4	l.	l.	PROPN
eurjchem-604	1321	5	h.	h.	PROPN
eurjchem-604	1321	6	;	;	PUNCT
eurjchem-604	1321	7	dennis	dennis	PROPN
eurjchem-604	1321	8	,	,	PUNCT
eurjchem-604	1321	9	k.	k.	PROPN
eurjchem-604	1322	1	p.	p.	PROPN
eurjchem-604	1322	2	chem	chem	PROPN
eurjchem-604	1322	3	.	.	PUNCT
eurjchem-604	1323	1	rev	rev	PROPN
eurjchem-604	1323	2	.	.	PROPN
eurjchem-604	1323	3	1995	1995	NUM
eurjchem-604	1323	4	,	,	PUNCT
eurjchem-604	1323	5	95	95	NUM
eurjchem-604	1323	6	,	,	PUNCT
eurjchem-604	1323	7	439‐473	439‐473	NUM
eurjchem-604	1324	1	[	[	X
eurjchem-604	1324	2	96	96	NUM
eurjchem-604	1324	3	]	]	PUNCT
eurjchem-604	1324	4	.	.	PUNCT
eurjchem-604	1325	1	fischer	fischer	PROPN
eurjchem-604	1325	2	,	,	PUNCT
eurjchem-604	1325	3	e.	e.	PROPN
eurjchem-604	1325	4	o.	o.	PROPN
eurjchem-604	1325	5	;	;	PUNCT
eurjchem-604	1325	6	ofele	ofele	PROPN
eurjchem-604	1325	7	,	,	PUNCT
eurjchem-604	1325	8	k.	k.	PROPN
eurjchem-604	1325	9	;	;	PUNCT
eurjchem-604	1325	10	essler	essler	PROPN
eurjchem-604	1325	11	,	,	PUNCT
eurjchem-604	1325	12	h.	h.	PROPN
eurjchem-604	1325	13	;	;	PUNCT
eurjchem-604	1325	14	frohlich	frohlich	PROPN
eurjchem-604	1325	15	,	,	PUNCT
eurjchem-604	1325	16	w.	w.	PROPN
eurjchem-604	1325	17	;	;	PUNCT
eurjchem-604	1325	18	mortensen	mortensen	PROPN
eurjchem-604	1325	19	j.	j.	PROPN
eurjchem-604	1325	20	p.	p.	PROPN
eurjchem-604	1325	21	;	;	PUNCT
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eurjchem-604	1325	23	,	,	PUNCT
eurjchem-604	1325	24	w.	w.	PROPN
eurjchem-604	1325	25	chem	chem	PROPN
eurjchem-604	1325	26	.	.	PUNCT
eurjchem-604	1326	1	ber	ber	PROPN
eurjchem-604	1326	2	.	.	PUNCT
eurjchem-604	1327	1	1958	1958	NUM
eurjchem-604	1327	2	,	,	PUNCT
eurjchem-604	1327	3	91	91	NUM
eurjchem-604	1327	4	,	,	PUNCT
eurjchem-604	1327	5	2763‐2772	2763‐2772	NUM
eurjchem-604	1327	6	.	.	PUNCT
eurjchem-604	1327	7	retracted	retract	VERB
eurjchem-604	1327	8	392	392	NUM
eurjchem-604	1327	9	kaushik	kaushik	PROPN
eurjchem-604	1327	10	et	et	PROPN
eurjchem-604	1327	11	al	al	PROPN
eurjchem-604	1327	12	.	.	PUNCT
eurjchem-604	1327	13	/	/	SYM
eurjchem-604	1327	14	european	european	PROPN
eurjchem-604	1327	15	journal	journal	PROPN
eurjchem-604	1327	16	of	of	ADP
eurjchem-604	1327	17	chemistry	chemistry	NOUN
eurjchem-604	1327	18	3	3	NUM
eurjchem-604	1327	19	(	(	PUNCT
eurjchem-604	1327	20	3	3	NUM
eurjchem-604	1327	21	)	)	PUNCT
eurjchem-604	1327	22	(	(	PUNCT
eurjchem-604	1327	23	2012	2012	NUM
eurjchem-604	1327	24	)	)	PUNCT
eurjchem-604	1327	25	367‐394	367‐394	NOUN
eurjchem-604	1328	1	[	[	X
eurjchem-604	1328	2	97	97	NUM
eurjchem-604	1328	3	]	]	PUNCT
eurjchem-604	1328	4	.	.	PUNCT
eurjchem-604	1329	1	natta	natta	PROPN
eurjchem-604	1329	2	,	,	PUNCT
eurjchem-604	1329	3	g.	g.	PROPN
eurjchem-604	1329	4	;	;	PUNCT
eurjchem-604	1329	5	ercoli	ercoli	PROPN
eurjchem-604	1329	6	,	,	PUNCT
eurjchem-604	1329	7	e.	e.	PROPN
eurjchem-604	1329	8	;	;	PUNCT
eurjchem-604	1329	9	calderazzo	calderazzo	PROPN
eurjchem-604	1329	10	,	,	PUNCT
eurjchem-604	1329	11	f.	f.	PROPN
eurjchem-604	1329	12	chim	chim	PROPN
eurjchem-604	1329	13	.	.	PUNCT
eurjchem-604	1330	1	ind	ind	PROPN
eurjchem-604	1330	2	.	.	PUNCT
eurjchem-604	1331	1	milano	milano	PROPN
eurjchem-604	1331	2	1958	1958	NUM
eurjchem-604	1331	3	,	,	PUNCT
eurjchem-604	1331	4	40	40	NUM
eurjchem-604	1331	5	,	,	PUNCT
eurjchem-604	1331	6	287‐	287‐	NUM
eurjchem-604	1331	7	288	288	NUM
eurjchem-604	1331	8	.	.	PUNCT
eurjchem-604	1332	1	[	[	X
eurjchem-604	1332	2	98	98	NUM
eurjchem-604	1332	3	]	]	PUNCT
eurjchem-604	1332	4	.	.	PUNCT
eurjchem-604	1333	1	fischer	fischer	PROPN
eurjchem-604	1333	2	,	,	PUNCT
eurjchem-604	1333	3	e.	e.	PROPN
eurjchem-604	1333	4	o.	o.	PROPN
eurjchem-604	1333	5	;	;	PUNCT
eurjchem-604	1333	6	kriebitzsch	kriebitzsch	PROPN
eurjchem-604	1333	7	n.	n.	PROPN
eurjchem-604	1333	8	;	;	PUNCT
eurjchem-604	1333	9	fischer	fischer	PROPN
eurjchem-604	1333	10	,	,	PUNCT
eurjchem-604	1333	11	r.	r.	PROPN
eurjchem-604	1333	12	d.	d.	PROPN
eurjchem-604	1333	13	chem	chem	PROPN
eurjchem-604	1333	14	.	.	PUNCT
eurjchem-604	1334	1	ber	ber	PROPN
eurjchem-604	1334	2	.	.	PUNCT
eurjchem-604	1334	3	1959	1959	NUM
eurjchem-604	1334	4	,	,	PUNCT
eurjchem-604	1334	5	92	92	NUM
eurjchem-604	1334	6	,	,	PUNCT
eurjchem-604	1334	7	3214‐3222	3214‐3222	NUM
eurjchem-604	1334	8	.	.	PUNCT
eurjchem-604	1335	1	[	[	X
eurjchem-604	1335	2	99	99	NUM
eurjchem-604	1335	3	]	]	PUNCT
eurjchem-604	1335	4	.	.	PUNCT
eurjchem-604	1336	1	king	king	PROPN
eurjchem-604	1336	2	,	,	PUNCT
eurjchem-604	1336	3	r.	r.	PROPN
eurjchem-604	1336	4	b.	b.	PROPN
eurjchem-604	1336	5	;	;	PUNCT
eurjchem-604	1336	6	stone	stone	PROPN
eurjchem-604	1336	7	,	,	PUNCT
eurjchem-604	1336	8	f.	f.	PROPN
eurjchem-604	1336	9	g.	g.	PROPN
eurjchem-604	1336	10	a.	a.	PROPN
eurjchem-604	1336	11	j.	j.	PROPN
eurjchem-604	1336	12	am	am	PROPN
eurjchem-604	1336	13	.	.	PUNCT
eurjchem-604	1337	1	chem	chem	NOUN
eurjchem-604	1337	2	.	.	PUNCT
eurjchem-604	1338	1	soc	soc	PROPN
eurjchem-604	1338	2	.	.	PUNCT
eurjchem-604	1339	1	1960	1960	NUM
eurjchem-604	1339	2	,	,	PUNCT
eurjchem-604	1339	3	82	82	NUM
eurjchem-604	1339	4	,	,	PUNCT
eurjchem-604	1339	5	4557‐4562	4557‐4562	NUM
eurjchem-604	1339	6	.	.	PUNCT
eurjchem-604	1340	1	[	[	X
eurjchem-604	1340	2	100	100	NUM
eurjchem-604	1340	3	]	]	PUNCT
eurjchem-604	1340	4	.	.	PUNCT
eurjchem-604	1341	1	abel	abel	PROPN
eurjchem-604	1341	2	,	,	PUNCT
eurjchem-604	1341	3	e.	e.	PROPN
eurjchem-604	1341	4	w.	w.	PROPN
eurjchem-604	1341	5	;	;	PUNCT
eurjchem-604	1341	6	bennett	bennett	PROPN
eurjchem-604	1341	7	,	,	PUNCT
eurjchem-604	1341	8	m.	m.	NOUN
eurjchem-604	1341	9	a.	a.	PROPN
eurjchem-604	1341	10	;	;	PUNCT
eurjchem-604	1341	11	burton	burton	PROPN
eurjchem-604	1341	12	,	,	PUNCT
eurjchem-604	1341	13	r.	r.	PROPN
eurjchem-604	1341	14	;	;	PUNCT
eurjchem-604	1341	15	wilkinson	wilkinson	PROPN
eurjchem-604	1341	16	,	,	PUNCT
eurjchem-604	1341	17	g.	g.	PROPN
eurjchem-604	1341	18	j.	j.	PROPN
eurjchem-604	1341	19	chem	chem	PROPN
eurjchem-604	1341	20	.	.	PUNCT
eurjchem-604	1342	1	soc	soc	PROPN
eurjchem-604	1342	2	.	.	PUNCT
eurjchem-604	1343	1	1958	1958	NUM
eurjchem-604	1343	2	,	,	PUNCT
eurjchem-604	1343	3	4559‐4563	4559‐4563	NUM
eurjchem-604	1343	4	.	.	PUNCT
eurjchem-604	1344	1	[	[	X
eurjchem-604	1344	2	101	101	NUM
eurjchem-604	1344	3	]	]	PUNCT
eurjchem-604	1344	4	.	.	PUNCT
eurjchem-604	1345	1	manuel	manuel	PROPN
eurjchem-604	1345	2	,	,	PUNCT
eurjchem-604	1345	3	t.	t.	PROPN
eurjchem-604	1345	4	a.	a.	NOUN
eurjchem-604	1345	5	;	;	PUNCT
eurjchem-604	1345	6	stone	stone	NOUN
eurjchem-604	1345	7	,	,	PUNCT
eurjchem-604	1345	8	f.	f.	PROPN
eurjchem-604	1345	9	g.	g.	PROPN
eurjchem-604	1345	10	a.	a.	PROPN
eurjchem-604	1345	11	chem	chem	PROPN
eurjchem-604	1345	12	.	.	PUNCT
eurjchem-604	1346	1	ind	ind	PROPN
eurjchem-604	1346	2	.	.	PUNCT
eurjchem-604	1347	1	1960	1960	NUM
eurjchem-604	1347	2	,	,	PUNCT
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eurjchem-604	1347	4	.	.	PUNCT
eurjchem-604	1348	1	[	[	X
eurjchem-604	1348	2	102	102	NUM
eurjchem-604	1348	3	]	]	SYM
eurjchem-604	1348	4	.	.	PUNCT
eurjchem-604	1349	1	fisher	fisher	PROPN
eurjchem-604	1349	2	,	,	PUNCT
eurjchem-604	1349	3	e.	e.	PROPN
eurjchem-604	1349	4	o.	o.	PROPN
eurjchem-604	1349	5	;	;	PUNCT
eurjchem-604	1349	6	palm	palm	PROPN
eurjchem-604	1349	7	,	,	PUNCT
eurjchem-604	1349	8	c.	c.	PROPN
eurjchem-604	1349	9	;	;	PUNCT
eurjchem-604	1349	10	fritz	fritz	PROPN
eurjchem-604	1349	11	,	,	PUNCT
eurjchem-604	1349	12	h.	h.	PROPN
eurjchem-604	1349	13	p.	p.	PROPN
eurjchem-604	1349	14	chem	chem	PROPN
eurjchem-604	1349	15	.	.	PUNCT
eurjchem-604	1350	1	ber	ber	PROPN
eurjchem-604	1350	2	.	.	PUNCT
eurjchem-604	1350	3	1959	1959	NUM
eurjchem-604	1350	4	,	,	PUNCT
eurjchem-604	1350	5	92	92	NUM
eurjchem-604	1350	6	,	,	PUNCT
eurjchem-604	1350	7	2645‐2657	2645‐2657	NUM
eurjchem-604	1350	8	.	.	PUNCT
eurjchem-604	1351	1	[	[	X
eurjchem-604	1351	2	103	103	NUM
eurjchem-604	1351	3	]	]	SYM
eurjchem-604	1351	4	.	.	PUNCT
eurjchem-604	1352	1	fisher	fisher	PROPN
eurjchem-604	1352	2	,	,	PUNCT
eurjchem-604	1352	3	e.	e.	PROPN
eurjchem-604	1352	4	o.	o.	PROPN
eurjchem-604	1352	5	;	;	PUNCT
eurjchem-604	1352	6	palm	palm	NOUN
eurjchem-604	1352	7	,	,	PUNCT
eurjchem-604	1352	8	c.	c.	PROPN
eurjchem-604	1352	9	z.	z.	PROPN
eurjchem-604	1352	10	naturfosch	naturfosch	PROPN
eurjchem-604	1352	11	.	.	PUNCT
eurjchem-604	1353	1	1959	1959	NUM
eurjchem-604	1353	2	,	,	PUNCT
eurjchem-604	1353	3	14b	14b	NUM
eurjchem-604	1353	4	,	,	PUNCT
eurjchem-604	1353	5	598‐299	598‐299	NOUN
eurjchem-604	1353	6	.	.	PUNCT
eurjchem-604	1354	1	[	[	X
eurjchem-604	1354	2	104	104	NUM
eurjchem-604	1354	3	]	]	PUNCT
eurjchem-604	1354	4	.	.	PUNCT
eurjchem-604	1355	1	manuel	manuel	PROPN
eurjchem-604	1355	2	,	,	PUNCT
eurjchem-604	1355	3	t.	t.	PROPN
eurjchem-604	1355	4	a.	a.	NOUN
eurjchem-604	1355	5	;	;	PUNCT
eurjchem-604	1355	6	stone	stone	NOUN
eurjchem-604	1355	7	,	,	PUNCT
eurjchem-604	1355	8	f.	f.	PROPN
eurjchem-604	1355	9	g.	g.	PROPN
eurjchem-604	1355	10	a.	a.	PROPN
eurjchem-604	1355	11	chem	chem	PROPN
eurjchem-604	1355	12	.	.	PUNCT
eurjchem-604	1356	1	ind	ind	PROPN
eurjchem-604	1356	2	.	.	PUNCT
eurjchem-604	1356	3	1959	1959	NUM
eurjchem-604	1356	4	,	,	PUNCT
eurjchem-604	1356	5	1349‐1350	1349‐1350	NUM
eurjchem-604	1356	6	.	.	PUNCT
eurjchem-604	1357	1	[	[	X
eurjchem-604	1357	2	105	105	NUM
eurjchem-604	1357	3	]	]	PUNCT
eurjchem-604	1357	4	.	.	PUNCT
eurjchem-604	1358	1	fischer	fischer	PROPN
eurjchem-604	1358	2	,	,	PUNCT
eurjchem-604	1358	3	e.	e.	PROPN
eurjchem-604	1358	4	o.	o.	PROPN
eurjchem-604	1358	5	;	;	PUNCT
eurjchem-604	1358	6	frohlich	frohlich	PROPN
eurjchem-604	1358	7	,	,	PUNCT
eurjchem-604	1358	8	w.	w.	PROPN
eurjchem-604	1358	9	chem	chem	PROPN
eurjchem-604	1358	10	.	.	PUNCT
eurjchem-604	1359	1	ber	ber	PROPN
eurjchem-604	1359	2	.	.	PUNCT
eurjchem-604	1359	3	1959	1959	NUM
eurjchem-604	1359	4	,	,	PUNCT
eurjchem-604	1359	5	92	92	NUM
eurjchem-604	1359	6	,	,	PUNCT
eurjchem-604	1359	7	2995‐2998	2995‐2998	NUM
eurjchem-604	1359	8	.	.	PUNCT
eurjchem-604	1360	1	[	[	X
eurjchem-604	1360	2	106	106	NUM
eurjchem-604	1360	3	]	]	PUNCT
eurjchem-604	1360	4	.	.	PUNCT
eurjchem-604	1360	5	bannett	bannett	PROPN
eurjchem-604	1360	6	,	,	PUNCT
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eurjchem-604	1360	8	a.	a.	PROPN
eurjchem-604	1360	9	;	;	PUNCT
eurjchem-604	1360	10	wilkinson	wilkinson	PROPN
eurjchem-604	1360	11	,	,	PUNCT
eurjchem-604	1360	12	g.	g.	PROPN
eurjchem-604	1360	13	chem	chem	PROPN
eurjchem-604	1360	14	.	.	PUNCT
eurjchem-604	1361	1	ind	ind	PROPN
eurjchem-604	1361	2	.	.	PUNCT
eurjchem-604	1361	3	1959	1959	NUM
eurjchem-604	1361	4	,	,	PUNCT
eurjchem-604	1361	5	1516‐1517	1516‐1517	NUM
eurjchem-604	1361	6	.	.	PUNCT
eurjchem-604	1362	1	[	[	X
eurjchem-604	1362	2	107	107	NUM
eurjchem-604	1362	3	]	]	PUNCT
eurjchem-604	1362	4	.	.	PUNCT
eurjchem-604	1363	1	pettit	pettit	PROPN
eurjchem-604	1363	2	,	,	PUNCT
eurjchem-604	1363	3	r.	r.	PROPN
eurjchem-604	1363	4	j.	j.	PROPN
eurjchem-604	1363	5	am	am	PROPN
eurjchem-604	1363	6	.	.	PUNCT
eurjchem-604	1364	1	chem	chem	PROPN
eurjchem-604	1364	2	.	.	PUNCT
eurjchem-604	1365	1	soc	soc	PROPN
eurjchem-604	1365	2	.	.	PUNCT
eurjchem-604	1366	1	1959	1959	NUM
eurjchem-604	1366	2	,	,	PUNCT
eurjchem-604	1366	3	81	81	NUM
eurjchem-604	1366	4	,	,	PUNCT
eurjchem-604	1366	5	1266‐1266	1266‐1266	NUM
eurjchem-604	1366	6	.	.	PUNCT
eurjchem-604	1367	1	[	[	X
eurjchem-604	1367	2	108	108	NUM
eurjchem-604	1367	3	]	]	PUNCT
eurjchem-604	1367	4	.	.	PUNCT
eurjchem-604	1368	1	burton	burton	PROPN
eurjchem-604	1368	2	,	,	PUNCT
eurjchem-604	1368	3	r.	r.	PROPN
eurjchem-604	1368	4	;	;	PUNCT
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eurjchem-604	1368	6	,	,	PUNCT
eurjchem-604	1368	7	m.	m.	PROPN
eurjchem-604	1368	8	l.	l.	PROPN
eurjchem-604	1368	9	h.	h.	PROPN
eurjchem-604	1368	10	;	;	PUNCT
eurjchem-604	1368	11	abel	abel	PROPN
eurjchem-604	1368	12	,	,	PUNCT
eurjchem-604	1368	13	e.	e.	PROPN
eurjchem-604	1368	14	w.	w.	PROPN
eurjchem-604	1368	15	;	;	PUNCT
eurjchem-604	1368	16	wilkinson	wilkinson	PROPN
eurjchem-604	1368	17	,	,	PUNCT
eurjchem-604	1368	18	g.	g.	PROPN
eurjchem-604	1368	19	chem	chem	PROPN
eurjchem-604	1368	20	.	.	PUNCT
eurjchem-604	1369	1	ind	ind	PROPN
eurjchem-604	1369	2	.	.	PUNCT
eurjchem-604	1370	1	1958	1958	NUM
eurjchem-604	1370	2	,	,	PUNCT
eurjchem-604	1370	3	1592‐1593	1592‐1593	NUM
eurjchem-604	1370	4	.	.	PUNCT
eurjchem-604	1371	1	[	[	X
eurjchem-604	1371	2	109	109	NUM
eurjchem-604	1371	3	]	]	PUNCT
eurjchem-604	1371	4	.	.	PUNCT
eurjchem-604	1372	1	king	king	PROPN
eurjchem-604	1372	2	,	,	PUNCT
eurjchem-604	1372	3	r.	r.	PROPN
eurjchem-604	1372	4	b.	b.	PROPN
eurjchem-604	1372	5	;	;	PUNCT
eurjchem-604	1372	6	stone	stone	PROPN
eurjchem-604	1372	7	,	,	PUNCT
eurjchem-604	1372	8	f.	f.	PROPN
eurjchem-604	1372	9	g.	g.	PROPN
eurjchem-604	1372	10	a.	a.	PROPN
eurjchem-604	1372	11	j.	j.	PROPN
eurjchem-604	1372	12	am	am	PROPN
eurjchem-604	1372	13	.	.	PUNCT
eurjchem-604	1373	1	chem	chem	NOUN
eurjchem-604	1373	2	.	.	PUNCT
eurjchem-604	1374	1	soc	soc	PROPN
eurjchem-604	1374	2	.	.	PUNCT
eurjchem-604	1375	1	1961	1961	NUM
eurjchem-604	1375	2	,	,	PUNCT
eurjchem-604	1375	3	83(17	83(17	NUM
eurjchem-604	1375	4	)	)	PUNCT
eurjchem-604	1375	5	,	,	PUNCT
eurjchem-604	1375	6	3590‐3593	3590‐3593	NUM
eurjchem-604	1375	7	.	.	PUNCT
eurjchem-604	1376	1	[	[	X
eurjchem-604	1376	2	110	110	NUM
eurjchem-604	1376	3	]	]	PUNCT
eurjchem-604	1376	4	.	.	PUNCT
eurjchem-604	1377	1	green	green	ADJ
eurjchem-604	1377	2	,	,	PUNCT
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eurjchem-604	1377	4	l.	l.	PROPN
eurjchem-604	1377	5	h.	h.	PROPN
eurjchem-604	1377	6	,	,	PUNCT
eurjchem-604	1377	7	some	some	DET
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eurjchem-604	1377	10	of	of	ADP
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eurjchem-604	1377	12	and	and	CCONJ
eurjchem-604	1377	13	related	related	ADJ
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eurjchem-604	1377	15	,	,	PUNCT
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eurjchem-604	1377	19	,	,	PUNCT
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eurjchem-604	1377	23	,	,	PUNCT
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eurjchem-604	1377	27	,	,	PUNCT
eurjchem-604	1377	28	373‐388	373‐388	NUM
eurjchem-604	1377	29	,	,	PUNCT
eurjchem-604	1377	30	1972	1972	NUM
eurjchem-604	1377	31	.	.	PUNCT
eurjchem-604	1378	1	(	(	PUNCT
eurjchem-604	1378	2	http://www.iupac.org/publications/pac/pdf/1972/pdf/3003x03	http://www.iupac.org/publications/pac/pdf/1972/pdf/3003x03	X
eurjchem-604	1378	3	73.pdf	73.pdf	PROPN
eurjchem-604	1378	4	)	)	PUNCT
eurjchem-604	1379	1	[	[	X
eurjchem-604	1379	2	111	111	NUM
eurjchem-604	1379	3	]	]	PUNCT
eurjchem-604	1379	4	.	.	PUNCT
eurjchem-604	1380	1	froberg	froberg	PROPN
eurjchem-604	1380	2	,	,	PUNCT
eurjchem-604	1380	3	s.	s.	PROPN
eurjchem-604	1380	4	;	;	PUNCT
eurjchem-604	1380	5	felton	felton	PROPN
eurjchem-604	1380	6	,	,	PUNCT
eurjchem-604	1380	7	g.	g.	PROPN
eurjchem-604	1380	8	a.	a.	PROPN
eurjchem-604	1380	9	n.	n.	PROPN
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eurjchem-604	1380	20	complexes	complex	NOUN
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eurjchem-604	1380	31	,	,	PUNCT
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eurjchem-604	1380	33	48309	48309	NUM
eurjchem-604	1380	34	(	(	PUNCT
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eurjchem-604	1381	1	[	[	X
eurjchem-604	1381	2	112	112	NUM
eurjchem-604	1381	3	]	]	PUNCT
eurjchem-604	1381	4	.	.	PUNCT
eurjchem-604	1382	1	zeller	zeller	PROPN
eurjchem-604	1382	2	,	,	PUNCT
eurjchem-604	1382	3	m.	m.	NOUN
eurjchem-604	1382	4	;	;	PUNCT
eurjchem-604	1382	5	lazich	lazich	ADV
eurjchem-604	1382	6	,	,	PUNCT
eurjchem-604	1382	7	e.	e.	PROPN
eurjchem-604	1382	8	;	;	PUNCT
eurjchem-604	1382	9	hunter	hunter	NOUN
eurjchem-604	1382	10	,	,	PUNCT
eurjchem-604	1382	11	a.	a.	PROPN
eurjchem-604	1382	12	d.	d.	PROPN
eurjchem-604	1382	13	acta	acta	PROPN
eurjchem-604	1382	14	cryst	cryst	PROPN
eurjchem-604	1382	15	.	.	PUNCT
eurjchem-604	1383	1	2003	2003	NUM
eurjchem-604	1383	2	,	,	PUNCT
eurjchem-604	1383	3	e59	e59	NOUN
eurjchem-604	1383	4	,	,	PUNCT
eurjchem-604	1383	5	m914‐	m914‐	NOUN
eurjchem-604	1383	6	m915	m915	PROPN
eurjchem-604	1383	7	.	.	PUNCT
eurjchem-604	1384	1	[	[	X
eurjchem-604	1384	2	113	113	NUM
eurjchem-604	1384	3	]	]	PUNCT
eurjchem-604	1384	4	.	.	PUNCT
eurjchem-604	1385	1	mcardle	mcardle	PROPN
eurjchem-604	1385	2	,	,	PUNCT
eurjchem-604	1385	3	p.	p.	NOUN
eurjchem-604	1385	4	;	;	PUNCT
eurjchem-604	1385	5	o’neill	o’neill	PROPN
eurjchem-604	1385	6	,	,	PUNCT
eurjchem-604	1385	7	l.	l.	PROPN
eurjchem-604	1385	8	;	;	PUNCT
eurjchem-604	1385	9	cunningham	cunningham	PROPN
eurjchem-604	1385	10	,	,	PUNCT
eurjchem-604	1385	11	d.	d.	PROPN
eurjchem-604	1385	12	inorg	inorg	PROPN
eurjchem-604	1385	13	.	.	PUNCT
eurjchem-604	1386	1	chim	chim	PROPN
eurjchem-604	1386	2	.	.	PUNCT
eurjchem-604	1387	1	acta	acta	PROPN
eurjchem-604	1387	2	1999	1999	NUM
eurjchem-604	1387	3	,	,	PUNCT
eurjchem-604	1387	4	291	291	NUM
eurjchem-604	1387	5	,	,	PUNCT
eurjchem-604	1387	6	252‐257	252‐257	PROPN
eurjchem-604	1387	7	.	.	PUNCT
eurjchem-604	1388	1	[	[	X
eurjchem-604	1388	2	114	114	NUM
eurjchem-604	1388	3	]	]	PUNCT
eurjchem-604	1388	4	.	.	PUNCT
eurjchem-604	1388	5	akita	akita	PROPN
eurjchem-604	1388	6	,	,	PUNCT
eurjchem-604	1388	7	m.	m.	NOUN
eurjchem-604	1388	8	;	;	PUNCT
eurjchem-604	1388	9	terada	terada	PROPN
eurjchem-604	1388	10	,	,	PUNCT
eurjchem-604	1388	11	m.	m.	NOUN
eurjchem-604	1388	12	;	;	PUNCT
eurjchem-604	1388	13	tanaka	tanaka	PROPN
eurjchem-604	1388	14	,	,	PUNCT
eurjchem-604	1388	15	m.	m.	NOUN
eurjchem-604	1388	16	;	;	PUNCT
eurjchem-604	1388	17	morooka	morooka	PROPN
eurjchem-604	1388	18	,	,	PUNCT
eurjchem-604	1388	19	y.	y.	PROPN
eurjchem-604	1388	20	j.	j.	PROPN
eurjchem-604	1388	21	organomet	organomet	PROPN
eurjchem-604	1388	22	.	.	PUNCT
eurjchem-604	1389	1	chem	chem	NOUN
eurjchem-604	1389	2	.	.	PUNCT
eurjchem-604	1390	1	1996	1996	NUM
eurjchem-604	1390	2	,	,	PUNCT
eurjchem-604	1390	3	510	510	NUM
eurjchem-604	1390	4	,	,	PUNCT
eurjchem-604	1390	5	255‐261	255‐261	NUM
eurjchem-604	1390	6	.	.	PUNCT
eurjchem-604	1391	1	[	[	X
eurjchem-604	1391	2	115	115	NUM
eurjchem-604	1391	3	]	]	PUNCT
eurjchem-604	1391	4	.	.	PUNCT
eurjchem-604	1392	1	sloan	sloan	PROPN
eurjchem-604	1392	2	,	,	PUNCT
eurjchem-604	1392	3	t.	t.	PROPN
eurjchem-604	1392	4	e.	e.	PROPN
eurjchem-604	1392	5	,	,	PUNCT
eurjchem-604	1392	6	wojcicki	wojcicki	PROPN
eurjchem-604	1392	7	,	,	PUNCT
eurjchem-604	1392	8	a.	a.	NOUN
eurjchem-604	1392	9	inorg	inorg	PROPN
eurjchem-604	1392	10	.	.	PUNCT
eurjchem-604	1393	1	chem	chem	PROPN
eurjchem-604	1393	2	.	.	PUNCT
eurjchem-604	1394	1	1968	1968	NUM
eurjchem-604	1394	2	,	,	PUNCT
eurjchem-604	1394	3	7(7	7(7	NUM
eurjchem-604	1394	4	)	)	PUNCT
eurjchem-604	1394	5	,	,	PUNCT
eurjchem-604	1394	6	1268‐1269	1268‐1269	NUM
eurjchem-604	1394	7	.	.	PUNCT
eurjchem-604	1395	1	[	[	X
eurjchem-604	1395	2	116	116	NUM
eurjchem-604	1395	3	]	]	PUNCT
eurjchem-604	1395	4	.	.	PUNCT
eurjchem-604	1396	1	saito	saito	PROPN
eurjchem-604	1396	2	,	,	PUNCT
eurjchem-604	1396	3	k.	k.	PROPN
eurjchem-604	1396	4	;	;	PUNCT
eurjchem-604	1396	5	kawano	kawano	PROPN
eurjchem-604	1396	6	,	,	PUNCT
eurjchem-604	1396	7	y.	y.	PROPN
eurjchem-604	1396	8	;	;	PUNCT
eurjchem-604	1396	9	shimoi	shimoi	NOUN
eurjchem-604	1396	10	,	,	PUNCT
eurjchem-604	1396	11	m.	m.	NOUN
eurjchem-604	1396	12	eur	eur	PROPN
eurjchem-604	1396	13	.	.	PUNCT
eurjchem-604	1397	1	j.	j.	PROPN
eurjchem-604	1397	2	inorg	inorg	PROPN
eurjchem-604	1397	3	.	.	PUNCT
eurjchem-604	1398	1	chem	chem	PROPN
eurjchem-604	1398	2	.	.	PUNCT
eurjchem-604	1399	1	2007	2007	NUM
eurjchem-604	1399	2	,	,	PUNCT
eurjchem-604	1399	3	17	17	NUM
eurjchem-604	1399	4	,	,	PUNCT
eurjchem-604	1399	5	3195‐	3195‐	NUM
eurjchem-604	1399	6	3200	3200	NUM
eurjchem-604	1399	7	.	.	PUNCT
eurjchem-604	1400	1	[	[	X
eurjchem-604	1400	2	117	117	NUM
eurjchem-604	1400	3	]	]	PUNCT
eurjchem-604	1400	4	.	.	PUNCT
eurjchem-604	1401	1	dunitz	dunitz	PROPN
eurjchem-604	1401	2	,	,	PUNCT
eurjchem-604	1401	3	j.	j.	PROPN
eurjchem-604	1401	4	d.	d.	PROPN
eurjchem-604	1401	5	;	;	PUNCT
eurjchem-604	1401	6	pauling	paule	VERB
eurjchem-604	1401	7	,	,	PUNCT
eurjchem-604	1401	8	p.	p.	NOUN
eurjchem-604	1401	9	helv	helv	PROPN
eurjchem-604	1401	10	.	.	PUNCT
eurjchem-604	1402	1	chim	chim	PROPN
eurjchem-604	1402	2	.	.	PUNCT
eurjchem-604	1403	1	acta1960	acta1960	PROPN
eurjchem-604	1403	2	,	,	PUNCT
eurjchem-604	1403	3	43	43	NUM
eurjchem-604	1403	4	,	,	PUNCT
eurjchem-604	1403	5	2188‐2197	2188‐2197	NUM
eurjchem-604	1403	6	.	.	PUNCT
eurjchem-604	1404	1	[	[	X
eurjchem-604	1404	2	118	118	NUM
eurjchem-604	1404	3	]	]	PUNCT
eurjchem-604	1404	4	.	.	PUNCT
eurjchem-604	1405	1	bailey	bailey	PROPN
eurjchem-604	1405	2	,	,	PUNCT
eurjchem-604	1405	3	m.	m.	PROPN
eurjchem-604	1405	4	f.	f.	PROPN
eurjchem-604	1405	5	;	;	PUNCT
eurjchem-604	1405	6	dahl	dahl	PROPN
eurjchem-604	1405	7	,	,	PUNCT
eurjchem-604	1405	8	l.	l.	PROPN
eurjchem-604	1405	9	f.	f.	PROPN
eurjchem-604	1405	10	inorg	inorg	PROPN
eurjchem-604	1405	11	.	.	PUNCT
eurjchem-604	1406	1	chem	chem	PROPN
eurjchem-604	1406	2	.	.	PUNCT
eurjchem-604	1407	1	1965	1965	NUM
eurjchem-604	1407	2	,	,	PUNCT
eurjchem-604	1407	3	4(9	4(9	NUM
eurjchem-604	1407	4	)	)	PUNCT
eurjchem-604	1407	5	,	,	PUNCT
eurjchem-604	1407	6	1314‐1319	1314‐1319	NUM
eurjchem-604	1407	7	.	.	PUNCT
eurjchem-604	1408	1	[	[	X
eurjchem-604	1408	2	119	119	NUM
eurjchem-604	1408	3	]	]	PUNCT
eurjchem-604	1408	4	.	.	PUNCT
eurjchem-604	1409	1	bailey	bailey	PROPN
eurjchem-604	1409	2	,	,	PUNCT
eurjchem-604	1409	3	m.	m.	PROPN
eurjchem-604	1409	4	f.	f.	PROPN
eurjchem-604	1409	5	;	;	PUNCT
eurjchem-604	1409	6	dahl	dahl	PROPN
eurjchem-604	1409	7	,	,	PUNCT
eurjchem-604	1409	8	l.	l.	PROPN
eurjchem-604	1409	9	f.	f.	PROPN
eurjchem-604	1409	10	inorg	inorg	PROPN
eurjchem-604	1409	11	.	.	PUNCT
eurjchem-604	1410	1	chem	chem	PROPN
eurjchem-604	1410	2	.	.	PUNCT
eurjchem-604	1411	1	1965	1965	NUM
eurjchem-604	1411	2	,	,	PUNCT
eurjchem-604	1411	3	4(9	4(9	NUM
eurjchem-604	1411	4	)	)	PUNCT
eurjchem-604	1411	5	,	,	PUNCT
eurjchem-604	1411	6	1298‐1306	1298‐1306	NUM
eurjchem-604	1411	7	.	.	PUNCT
eurjchem-604	1412	1	[	[	X
eurjchem-604	1412	2	120	120	NUM
eurjchem-604	1412	3	]	]	PUNCT
eurjchem-604	1412	4	.	.	PUNCT
eurjchem-604	1413	1	timmers	timmers	PROPN
eurjchem-604	1413	2	,	,	PUNCT
eurjchem-604	1413	3	f.	f.	PROPN
eurjchem-604	1413	4	j.	j.	PROPN
eurjchem-604	1413	5	;	;	PUNCT
eurjchem-604	1413	6	wacholtz	wacholtz	PROPN
eurjchem-604	1413	7	,	,	PUNCT
eurjchem-604	1413	8	w.	w.	PROPN
eurjchem-604	1413	9	f.	f.	PROPN
eurjchem-604	1413	10	j.	j.	PROPN
eurjchem-604	1413	11	chem	chem	PROPN
eurjchem-604	1413	12	.	.	PUNCT
eurjchem-604	1414	1	edu	edu	PROPN
eurjchem-604	1414	2	.	.	PROPN
eurjchem-604	1414	3	1994	1994	NUM
eurjchem-604	1414	4	,	,	PUNCT
eurjchem-604	1414	5	71	71	NUM
eurjchem-604	1414	6	,	,	PUNCT
eurjchem-604	1414	7	987‐990	987‐990	NUM
eurjchem-604	1414	8	.	.	PUNCT
eurjchem-604	1415	1	[	[	X
eurjchem-604	1415	2	121	121	NUM
eurjchem-604	1415	3	]	]	PUNCT
eurjchem-604	1415	4	.	.	PUNCT
eurjchem-604	1416	1	king	king	PROPN
eurjchem-604	1416	2	,	,	PUNCT
eurjchem-604	1416	3	r.	r.	PROPN
eurjchem-604	1416	4	b.	b.	PROPN
eurjchem-604	1416	5	,	,	PUNCT
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eurjchem-604	1416	7	syntheses	synthesis	NOUN
eurjchem-604	1416	8	,	,	PUNCT
eurjchem-604	1416	9	vol	vol	NOUN
eurjchem-604	1416	10	.	.	NOUN
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eurjchem-604	1416	12	,	,	PUNCT
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eurjchem-604	1416	15	,	,	PUNCT
eurjchem-604	1416	16	new	new	PROPN
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eurjchem-604	1416	18	,	,	PUNCT
eurjchem-604	1416	19	p.	p.	NOUN
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eurjchem-604	1416	21	,	,	PUNCT
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eurjchem-604	1416	23	.	.	PUNCT
eurjchem-604	1417	1	[	[	X
eurjchem-604	1417	2	122	122	NUM
eurjchem-604	1417	3	]	]	PUNCT
eurjchem-604	1417	4	.	.	PUNCT
eurjchem-604	1417	5	abel	abel	PROPN
eurjchem-604	1417	6	,	,	PUNCT
eurjchem-604	1417	7	e.	e.	PROPN
eurjchem-604	1417	8	;	;	PUNCT
eurjchem-604	1417	9	bennett	bennett	PROPN
eurjchem-604	1417	10	,	,	PUNCT
eurjchem-604	1417	11	w.	w.	PROPN
eurjchem-604	1417	12	m.	m.	PROPN
eurjchem-604	1417	13	a.	a.	PROPN
eurjchem-604	1417	14	;	;	PUNCT
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eurjchem-604	1417	16	,	,	PUNCT
eurjchem-604	1417	17	r.	r.	PROPN
eurjchem-604	1417	18	;	;	PUNCT
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eurjchem-604	1417	20	,	,	PUNCT
eurjchem-604	1417	21	g.	g.	PROPN
eurjchem-604	1417	22	j.	j.	PROPN
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eurjchem-604	1417	24	.	.	PUNCT
eurjchem-604	1418	1	soc	soc	PROPN
eurjchem-604	1418	2	.	.	PUNCT
eurjchem-604	1419	1	1958	1958	NUM
eurjchem-604	1419	2	,	,	PUNCT
eurjchem-604	1419	3	4559‐4563	4559‐4563	NUM
eurjchem-604	1419	4	.	.	PUNCT
eurjchem-604	1420	1	[	[	X
eurjchem-604	1420	2	123	123	NUM
eurjchem-604	1420	3	]	]	PUNCT
eurjchem-604	1420	4	.	.	PUNCT
eurjchem-604	1421	1	experiment	experiment	NOUN
eurjchem-604	1421	2	4	4	NUM
eurjchem-604	1421	3	,	,	PUNCT
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eurjchem-604	1421	5	organometallic	organometallic	ADJ
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eurjchem-604	1421	9	,	,	PUNCT
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eurjchem-604	1421	12	laboratory	laboratory	NOUN
eurjchem-604	1421	13	,	,	PUNCT
eurjchem-604	1421	14	4:153	4:153	NUM
eurjchem-604	1421	15	,	,	PUNCT
eurjchem-604	1421	16	pp	pp	ADJ
eurjchem-604	1421	17	.	.	PUNCT
eurjchem-604	1422	1	1‐8	1‐8	NUM
eurjchem-604	1422	2	,	,	PUNCT
eurjchem-604	1422	3	2004	2004	NUM
eurjchem-604	1422	4	(	(	PUNCT
eurjchem-604	1422	5	http://www.uiowa.edu/~c004153a/mocox‐f04rev.pdf	http://www.uiowa.edu/~c004153a/mocox‐f04rev.pdf	X
eurjchem-604	1422	6	)	)	PUNCT
eurjchem-604	1423	1	[	[	X
eurjchem-604	1423	2	124	124	NUM
eurjchem-604	1423	3	]	]	PUNCT
eurjchem-604	1423	4	.	.	PUNCT
eurjchem-604	1424	1	king	king	PROPN
eurjchem-604	1424	2	,	,	PUNCT
eurjchem-604	1424	3	r.	r.	PROPN
eurjchem-604	1424	4	b.	b.	PROPN
eurjchem-604	1424	5	;	;	PUNCT
eurjchem-604	1424	6	korenowski	korenowski	PROPN
eurjchem-604	1424	7	,	,	PUNCT
eurjchem-604	1424	8	t.	t.	PROPN
eurjchem-604	1424	9	f.	f.	PROPN
eurjchem-604	1424	10	inorg	inorg	PROPN
eurjchem-604	1424	11	.	.	PUNCT
eurjchem-604	1425	1	chem	chem	PROPN
eurjchem-604	1425	2	.	.	PUNCT
eurjchem-604	1426	1	1971	1971	NUM
eurjchem-604	1426	2	,	,	PUNCT
eurjchem-604	1426	3	10(6	10(6	NOUN
eurjchem-604	1426	4	)	)	PUNCT
eurjchem-604	1426	5	,	,	PUNCT
eurjchem-604	1426	6	1188‐1195	1188‐1195	NUM
eurjchem-604	1426	7	.	.	PUNCT
eurjchem-604	1427	1	[	[	X
eurjchem-604	1427	2	125	125	NUM
eurjchem-604	1427	3	]	]	PUNCT
eurjchem-604	1427	4	.	.	PUNCT
eurjchem-604	1428	1	cotton	cotton	NOUN
eurjchem-604	1428	2	,	,	PUNCT
eurjchem-604	1428	3	f.	f.	PROPN
eurjchem-604	1428	4	a.	a.	PROPN
eurjchem-604	1428	5	;	;	PUNCT
eurjchem-604	1428	6	zingales	zingale	NOUN
eurjchem-604	1428	7	,	,	PUNCT
eurjchem-604	1428	8	f.	f.	PROPN
eurjchem-604	1428	9	inorg	inorg	PROPN
eurjchem-604	1428	10	.	.	PUNCT
eurjchem-604	1429	1	chem	chem	PROPN
eurjchem-604	1429	2	.	.	PUNCT
eurjchem-604	1430	1	1962	1962	NUM
eurjchem-604	1430	2	,	,	PUNCT
eurjchem-604	1430	3	1(1	1(1	NUM
eurjchem-604	1430	4	)	)	PUNCT
eurjchem-604	1430	5	,	,	PUNCT
eurjchem-604	1430	6	145‐147	145‐147	NOUN
eurjchem-604	1430	7	.	.	PUNCT
eurjchem-604	1431	1	[	[	X
eurjchem-604	1431	2	126	126	NUM
eurjchem-604	1431	3	]	]	PUNCT
eurjchem-604	1431	4	.	.	PUNCT
eurjchem-604	1432	1	winstein	winstein	PROPN
eurjchem-604	1432	2	,	,	PUNCT
eurjchem-604	1432	3	s.	s.	PROPN
eurjchem-604	1432	4	;	;	PUNCT
eurjchem-604	1432	5	kaesz	kaesz	PRON
eurjchem-604	1432	6	,	,	PUNCT
eurjchem-604	1432	7	h.	h.	PROPN
eurjchem-604	1432	8	d.	d.	PROPN
eurjchem-604	1432	9	;	;	PUNCT
eurjchem-604	1432	10	kreiter	kreiter	PROPN
eurjchem-604	1432	11	,	,	PUNCT
eurjchem-604	1432	12	c.	c.	PROPN
eurjchem-604	1432	13	g.	g.	PROPN
eurjchem-604	1432	14	;	;	PUNCT
eurjchem-604	1432	15	friedrich	friedrich	PROPN
eurjchem-604	1432	16	,	,	PUNCT
eurjchem-604	1432	17	e.	e.	PROPN
eurjchem-604	1432	18	c.	c.	PROPN
eurjchem-604	1432	19	j.	j.	PROPN
eurjchem-604	1432	20	am	am	PROPN
eurjchem-604	1432	21	.	.	PUNCT
eurjchem-604	1433	1	chem	chem	NOUN
eurjchem-604	1433	2	.	.	PUNCT
eurjchem-604	1434	1	soc	soc	PROPN
eurjchem-604	1434	2	.	.	PUNCT
eurjchem-604	1435	1	1965	1965	NUM
eurjchem-604	1435	2	,	,	PUNCT
eurjchem-604	1435	3	87(14	87(14	NOUN
eurjchem-604	1435	4	)	)	PUNCT
eurjchem-604	1435	5	,	,	PUNCT
eurjchem-604	1435	6	3267‐3269	3267‐3269	NUM
eurjchem-604	1435	7	.	.	PUNCT
eurjchem-604	1436	1	[	[	X
eurjchem-604	1436	2	127	127	NUM
eurjchem-604	1436	3	]	]	PUNCT
eurjchem-604	1436	4	.	.	PUNCT
eurjchem-604	1436	5	bruce	bruce	PROPN
eurjchem-604	1436	6	,	,	PUNCT
eurjchem-604	1436	7	m.	m.	NOUN
eurjchem-604	1436	8	i.	i.	PROPN
eurjchem-604	1436	9	;	;	PUNCT
eurjchem-604	1436	10	cooke	cooke	PROPN
eurjchem-604	1436	11	,	,	PUNCT
eurjchem-604	1436	12	m.	m.	NOUN
eurjchem-604	1436	13	;	;	PUNCT
eurjchem-604	1436	14	green	green	ADJ
eurjchem-604	1436	15	,	,	PUNCT
eurjchem-604	1436	16	m.	m.	NOUN
eurjchem-604	1436	17	j.	j.	PROPN
eurjchem-604	1436	18	organomet	organomet	PROPN
eurjchem-604	1436	19	.	.	PUNCT
eurjchem-604	1437	1	chem	chem	NOUN
eurjchem-604	1437	2	.	.	PUNCT
eurjchem-604	1438	1	1968	1968	NUM
eurjchem-604	1438	2	,	,	PUNCT
eurjchem-604	1438	3	13(1	13(1	NUM
eurjchem-604	1438	4	)	)	PUNCT
eurjchem-604	1438	5	,	,	PUNCT
eurjchem-604	1438	6	227‐234	227‐234	NUM
eurjchem-604	1438	7	.	.	PUNCT
eurjchem-604	1439	1	[	[	X
eurjchem-604	1439	2	128	128	NUM
eurjchem-604	1439	3	]	]	PUNCT
eurjchem-604	1439	4	.	.	PUNCT
eurjchem-604	1440	1	atwood	atwood	PROPN
eurjchem-604	1440	2	,	,	PUNCT
eurjchem-604	1440	3	j.	j.	PROPN
eurjchem-604	1440	4	d.	d.	PROPN
eurjchem-604	1440	5	,	,	PUNCT
eurjchem-604	1440	6	inorganic	inorganic	ADJ
eurjchem-604	1440	7	and	and	CCONJ
eurjchem-604	1440	8	organometallic	organometallic	ADJ
eurjchem-604	1440	9	reaction	reaction	NOUN
eurjchem-604	1440	10	mechanism	mechanism	NOUN
eurjchem-604	1440	11	,	,	PUNCT
eurjchem-604	1440	12	bool	bool	PROPN
eurjchem-604	1440	13	publishing	publishing	PROPN
eurjchem-604	1440	14	co.	co.	PROPN
eurjchem-604	1440	15	,	,	PUNCT
eurjchem-604	1440	16	monterey	monterey	NOUN
eurjchem-604	1440	17	,	,	PUNCT
eurjchem-604	1440	18	ca	ca	NOUN
eurjchem-604	1440	19	,	,	PUNCT
eurjchem-604	1440	20	1985	1985	NUM
eurjchem-604	1440	21	.	.	PUNCT
eurjchem-604	1441	1	[	[	X
eurjchem-604	1441	2	129	129	NUM
eurjchem-604	1441	3	]	]	PUNCT
eurjchem-604	1441	4	.	.	PUNCT
eurjchem-604	1442	1	basolo	basolo	PROPN
eurjchem-604	1442	2	,	,	PUNCT
eurjchem-604	1442	3	f.	f.	PROPN
eurjchem-604	1442	4	pure	pure	PROPN
eurjchem-604	1442	5	appl	appl	PROPN
eurjchem-604	1442	6	.	.	PUNCT
eurjchem-604	1443	1	chem	chem	PROPN
eurjchem-604	1443	2	.	.	PUNCT
eurjchem-604	1444	1	1988	1988	NUM
eurjchem-604	1444	2	,	,	PUNCT
eurjchem-604	1444	3	60(8	60(8	NUM
eurjchem-604	1444	4	)	)	PUNCT
eurjchem-604	1444	5	,	,	PUNCT
eurjchem-604	1444	6	1193‐1196	1193‐1196	NUM
eurjchem-604	1444	7	.	.	PUNCT
eurjchem-604	1445	1	[	[	X
eurjchem-604	1445	2	130	130	NUM
eurjchem-604	1445	3	]	]	PUNCT
eurjchem-604	1445	4	.	.	PUNCT
eurjchem-604	1445	5	keeley	keeley	PROPN
eurjchem-604	1445	6	,	,	PUNCT
eurjchem-604	1445	7	d.	d.	PROPN
eurjchem-604	1445	8	f.	f.	PROPN
eurjchem-604	1445	9	;	;	PUNCT
eurjchem-604	1445	10	johnson	johnson	PROPN
eurjchem-604	1445	11	,	,	PUNCT
eurjchem-604	1445	12	r.	r.	PROPN
eurjchem-604	1445	13	e.	e.	PROPN
eurjchem-604	1445	14	inorg	inorg	PROPN
eurjchem-604	1445	15	.	.	PUNCT
eurjchem-604	1446	1	nucl	nucl	PROPN
eurjchem-604	1446	2	.	.	PUNCT
eurjchem-604	1447	1	chem	chem	PROPN
eurjchem-604	1447	2	.	.	PUNCT
eurjchem-604	1448	1	1959	1959	NUM
eurjchem-604	1448	2	,	,	PUNCT
eurjchem-604	1448	3	11	11	NUM
eurjchem-604	1448	4	,	,	PUNCT
eurjchem-604	1448	5	33‐41	33‐41	NUM
eurjchem-604	1448	6	.	.	PUNCT
eurjchem-604	1449	1	[	[	X
eurjchem-604	1449	2	131	131	NUM
eurjchem-604	1449	3	]	]	SYM
eurjchem-604	1449	4	.	.	PUNCT
eurjchem-604	1450	1	wojcicki	wojcicki	PROPN
eurjchem-604	1450	2	,	,	PUNCT
eurjchem-604	1450	3	a.	a.	NOUN
eurjchem-604	1450	4	;	;	PUNCT
eurjchem-604	1450	5	basolo	basolo	PROPN
eurjchem-604	1450	6	,	,	PUNCT
eurjchem-604	1450	7	f.	f.	PROPN
eurjchem-604	1450	8	j.	j.	PROPN
eurjchem-604	1450	9	am	am	PROPN
eurjchem-604	1450	10	.	.	PUNCT
eurjchem-604	1451	1	chem	chem	PROPN
eurjchem-604	1451	2	.	.	PUNCT
eurjchem-604	1452	1	soc	soc	PROPN
eurjchem-604	1452	2	.	.	PUNCT
eurjchem-604	1453	1	1961	1961	NUM
eurjchem-604	1453	2	,	,	PUNCT
eurjchem-604	1453	3	83(3	83(3	NUM
eurjchem-604	1453	4	)	)	PUNCT
eurjchem-604	1453	5	,	,	PUNCT
eurjchem-604	1453	6	520‐525	520‐525	PROPN
eurjchem-604	1453	7	.	.	PUNCT
eurjchem-604	1454	1	[	[	X
eurjchem-604	1454	2	132	132	NUM
eurjchem-604	1454	3	]	]	PUNCT
eurjchem-604	1454	4	.	.	PUNCT
eurjchem-604	1455	1	day	day	NOUN
eurjchem-604	1455	2	,	,	PUNCT
eurjchem-604	1455	3	j.	j.	PROPN
eurjchem-604	1455	4	p.	p.	PROPN
eurjchem-604	1455	5	;	;	PUNCT
eurjchem-604	1455	6	pearson	pearson	PROPN
eurjchem-604	1455	7	,	,	PUNCT
eurjchem-604	1455	8	r.	r.	PROPN
eurjchem-604	1455	9	g.	g.	PROPN
eurjchem-604	1455	10	;	;	PUNCT
eurjchem-604	1455	11	basolo	basolo	PROPN
eurjchem-604	1455	12	,	,	PUNCT
eurjchem-604	1455	13	f.	f.	PROPN
eurjchem-604	1455	14	j.	j.	PROPN
eurjchem-604	1455	15	am	am	PROPN
eurjchem-604	1455	16	.	.	PUNCT
eurjchem-604	1456	1	chem	chem	PROPN
eurjchem-604	1456	2	.	.	PUNCT
eurjchem-604	1457	1	soc	soc	PROPN
eurjchem-604	1457	2	.	.	PUNCT
eurjchem-604	1458	1	1968	1968	NUM
eurjchem-604	1458	2	,	,	PUNCT
eurjchem-604	1458	3	90(25	90(25	NUM
eurjchem-604	1458	4	)	)	PUNCT
eurjchem-604	1458	5	,	,	PUNCT
eurjchem-604	1458	6	6927‐6933	6927‐6933	NUM
eurjchem-604	1458	7	.	.	PUNCT
eurjchem-604	1459	1	[	[	X
eurjchem-604	1459	2	133	133	NUM
eurjchem-604	1459	3	]	]	PUNCT
eurjchem-604	1459	4	.	.	PUNCT
eurjchem-604	1460	1	tolman	tolman	PROPN
eurjchem-604	1460	2	,	,	PUNCT
eurjchem-604	1460	3	c.	c.	PROPN
eurjchem-604	1460	4	a.	a.	PROPN
eurjchem-604	1460	5	chem	chem	PROPN
eurjchem-604	1460	6	.	.	PUNCT
eurjchem-604	1461	1	rev	rev	PROPN
eurjchem-604	1461	2	.	.	PROPN
eurjchem-604	1461	3	1977	1977	NUM
eurjchem-604	1461	4	,	,	PUNCT
eurjchem-604	1461	5	77	77	NUM
eurjchem-604	1461	6	,	,	PUNCT
eurjchem-604	1461	7	313‐348	313‐348	NUM
eurjchem-604	1461	8	.	.	PUNCT
eurjchem-604	1462	1	[	[	X
eurjchem-604	1462	2	134	134	NUM
eurjchem-604	1462	3	]	]	PUNCT
eurjchem-604	1462	4	.	.	PUNCT
eurjchem-604	1463	1	thorsteinson	thorsteinson	PROPN
eurjchem-604	1463	2	,	,	PUNCT
eurjchem-604	1463	3	e.	e.	PROPN
eurjchem-604	1463	4	m.	m.	PROPN
eurjchem-604	1463	5	;	;	PUNCT
eurjchem-604	1463	6	basolo	basolo	PROPN
eurjchem-604	1463	7	,	,	PUNCT
eurjchem-604	1463	8	f.	f.	PROPN
eurjchem-604	1463	9	j.	j.	PROPN
eurjchem-604	1463	10	am	am	PROPN
eurjchem-604	1463	11	.	.	PUNCT
eurjchem-604	1464	1	chem	chem	NOUN
eurjchem-604	1464	2	.	.	PUNCT
eurjchem-604	1465	1	soc	soc	PROPN
eurjchem-604	1465	2	.	.	PUNCT
eurjchem-604	1466	1	1966	1966	NUM
eurjchem-604	1466	2	,	,	PUNCT
eurjchem-604	1466	3	88(17	88(17	NUM
eurjchem-604	1466	4	)	)	PUNCT
eurjchem-604	1466	5	,	,	PUNCT
eurjchem-604	1466	6	3929‐	3929‐	NUM
eurjchem-604	1466	7	3936	3936	NUM
eurjchem-604	1466	8	.	.	PUNCT
eurjchem-604	1467	1	[	[	X
eurjchem-604	1467	2	135	135	NUM
eurjchem-604	1467	3	]	]	PUNCT
eurjchem-604	1467	4	.	.	PUNCT
eurjchem-604	1467	5	schuster‐woldan	schuster‐woldan	PROPN
eurjchem-604	1467	6	,	,	PUNCT
eurjchem-604	1467	7	h.	h.	PROPN
eurjchem-604	1467	8	g.	g.	PROPN
eurjchem-604	1467	9	;	;	PUNCT
eurjchem-604	1467	10	basolo	basolo	PROPN
eurjchem-604	1467	11	,	,	PUNCT
eurjchem-604	1467	12	f.	f.	PROPN
eurjchem-604	1467	13	j.	j.	PROPN
eurjchem-604	1467	14	am	am	PROPN
eurjchem-604	1467	15	.	.	PUNCT
eurjchem-604	1468	1	chem	chem	NOUN
eurjchem-604	1468	2	.	.	PUNCT
eurjchem-604	1469	1	soc	soc	PROPN
eurjchem-604	1469	2	.	.	PUNCT
eurjchem-604	1470	1	1966	1966	NUM
eurjchem-604	1470	2	,	,	PUNCT
eurjchem-604	1470	3	88(8	88(8	NUM
eurjchem-604	1470	4	)	)	PUNCT
eurjchem-604	1470	5	,	,	PUNCT
eurjchem-604	1470	6	1657‐1663	1657‐1663	NUM
eurjchem-604	1470	7	.	.	PUNCT
eurjchem-604	1471	1	[	[	X
eurjchem-604	1471	2	136	136	NUM
eurjchem-604	1471	3	]	]	PUNCT
eurjchem-604	1471	4	.	.	PUNCT
eurjchem-604	1472	1	cramer	cramer	PROPN
eurjchem-604	1472	2	,	,	PUNCT
eurjchem-604	1472	3	r.	r.	PROPN
eurjchem-604	1472	4	;	;	PUNCT
eurjchem-604	1472	5	seiwell	seiwell	NOUN
eurjchem-604	1472	6	,	,	PUNCT
eurjchem-604	1472	7	l.	l.	PROPN
eurjchem-604	1472	8	p.	p.	PROPN
eurjchem-604	1472	9	j.	j.	PROPN
eurjchem-604	1472	10	organomet	organomet	PROPN
eurjchem-604	1472	11	.	.	PUNCT
eurjchem-604	1473	1	chem	chem	NOUN
eurjchem-604	1473	2	.	.	PUNCT
eurjchem-604	1474	1	1975	1975	NUM
eurjchem-604	1474	2	,	,	PUNCT
eurjchem-604	1474	3	92(2	92(2	NUM
eurjchem-604	1474	4	)	)	PUNCT
eurjchem-604	1474	5	,	,	PUNCT
eurjchem-604	1474	6	245‐252	245‐252	NUM
eurjchem-604	1474	7	.	.	PUNCT
eurjchem-604	1475	1	[	[	X
eurjchem-604	1475	2	137	137	NUM
eurjchem-604	1475	3	]	]	PUNCT
eurjchem-604	1475	4	.	.	PUNCT
eurjchem-604	1475	5	huttner	huttner	PROPN
eurjchem-604	1475	6	,	,	PUNCT
eurjchem-604	1475	7	g.	g.	PROPN
eurjchem-604	1475	8	;	;	PUNCT
eurjchem-604	1475	9	brintzinger	brintzinger	NOUN
eurjchem-604	1475	10	,	,	PUNCT
eurjchem-604	1475	11	h.	h.	PROPN
eurjchem-604	1475	12	h.	h.	PROPN
eurjchem-604	1475	13	;	;	PUNCT
eurjchem-604	1475	14	bell	bell	PROPN
eurjchem-604	1475	15	,	,	PUNCT
eurjchem-604	1475	16	l.	l.	PROPN
eurjchem-604	1475	17	g.	g.	PROPN
eurjchem-604	1475	18	;	;	PUNCT
eurjchem-604	1475	19	friedlich	friedlich	PROPN
eurjchem-604	1475	20	,	,	PUNCT
eurjchem-604	1475	21	p.	p.	PROPN
eurjchem-604	1475	22	;	;	PUNCT
eurjchem-604	1475	23	bejenki	bejenki	PROPN
eurjchem-604	1475	24	,	,	PUNCT
eurjchem-604	1475	25	v.	v.	PROPN
eurjchem-604	1475	26	;	;	PUNCT
eurjchem-604	1475	27	neugebauer	neugebauer	PROPN
eurjchem-604	1475	28	,	,	PUNCT
eurjchem-604	1475	29	d.	d.	PROPN
eurjchem-604	1475	30	j.	j.	PROPN
eurjchem-604	1475	31	organomet	organomet	PROPN
eurjchem-604	1475	32	.	.	PUNCT
eurjchem-604	1476	1	chem	chem	NOUN
eurjchem-604	1476	2	.	.	PUNCT
eurjchem-604	1477	1	1978	1978	NUM
eurjchem-604	1477	2	,	,	PUNCT
eurjchem-604	1477	3	145(3	145(3	NUM
eurjchem-604	1477	4	)	)	PUNCT
eurjchem-604	1477	5	,	,	PUNCT
eurjchem-604	1477	6	329‐333	329‐333	NUM
eurjchem-604	1477	7	.	.	PUNCT
eurjchem-604	1478	1	[	[	X
eurjchem-604	1478	2	138	138	NUM
eurjchem-604	1478	3	]	]	PUNCT
eurjchem-604	1478	4	.	.	PUNCT
eurjchem-604	1479	1	ji	ji	PROPN
eurjchem-604	1479	2	,	,	PUNCT
eurjchem-604	1479	3	l.	l.	PROPN
eurjchem-604	1479	4	n.	n.	PROPN
eurjchem-604	1479	5	;	;	PUNCT
eurjchem-604	1479	6	rerek	rerek	NOUN
eurjchem-604	1479	7	,	,	PUNCT
eurjchem-604	1479	8	m.	m.	PROPN
eurjchem-604	1479	9	e.	e.	PROPN
eurjchem-604	1479	10	;	;	PUNCT
eurjchem-604	1479	11	basolo	basolo	PROPN
eurjchem-604	1479	12	,	,	PUNCT
eurjchem-604	1479	13	f.	f.	PROPN
eurjchem-604	1479	14	organometallics	organometallic	NOUN
eurjchem-604	1479	15	1984	1984	NUM
eurjchem-604	1479	16	,	,	PUNCT
eurjchem-604	1479	17	3(5	3(5	NUM
eurjchem-604	1479	18	)	)	PUNCT
eurjchem-604	1479	19	,	,	PUNCT
eurjchem-604	1480	1	740‐	740‐	NUM
eurjchem-604	1480	2	745	745	NUM
eurjchem-604	1480	3	.	.	PUNCT
eurjchem-604	1481	1	[	[	X
eurjchem-604	1481	2	139	139	NUM
eurjchem-604	1481	3	]	]	PUNCT
eurjchem-604	1481	4	.	.	PUNCT
eurjchem-604	1482	1	hart‐davis	hart‐davis	PROPN
eurjchem-604	1482	2	,	,	PUNCT
eurjchem-604	1482	3	a.	a.	PROPN
eurjchem-604	1482	4	j.	j.	PROPN
eurjchem-604	1482	5	;	;	PUNCT
eurjchem-604	1482	6	mawby	mawby	PROPN
eurjchem-604	1482	7	,	,	PUNCT
eurjchem-604	1482	8	r.	r.	PROPN
eurjchem-604	1482	9	j.	j.	PROPN
eurjchem-604	1482	10	j.	j.	PROPN
eurjchem-604	1482	11	chem	chem	PROPN
eurjchem-604	1482	12	.	.	PUNCT
eurjchem-604	1483	1	soc	soc	PROPN
eurjchem-604	1483	2	.	.	PUNCT
eurjchem-604	1484	1	a	a	DET
eurjchem-604	1484	2	1969	1969	NUM
eurjchem-604	1484	3	,	,	PUNCT
eurjchem-604	1484	4	2403‐2407	2403‐2407	NUM
eurjchem-604	1484	5	.	.	PUNCT
eurjchem-604	1485	1	[	[	X
eurjchem-604	1485	2	140	140	NUM
eurjchem-604	1485	3	]	]	PUNCT
eurjchem-604	1485	4	.	.	PUNCT
eurjchem-604	1486	1	novi	novi	PROPN
eurjchem-604	1486	2	,	,	PUNCT
eurjchem-604	1486	3	m.	m.	NOUN
eurjchem-604	1486	4	;	;	PUNCT
eurjchem-604	1486	5	guiseppe	guiseppe	PROPN
eurjchem-604	1486	6	,	,	PUNCT
eurjchem-604	1486	7	g.	g.	PROPN
eurjchem-604	1486	8	;	;	PUNCT
eurjchem-604	1486	9	dell’erba	dell’erba	ADV
eurjchem-604	1486	10	,	,	PUNCT
eurjchem-604	1486	11	c.	c.	PROPN
eurjchem-604	1486	12	j.	j.	PROPN
eurjchem-604	1486	13	heterocyclic	heterocyclic	PROPN
eurjchem-604	1486	14	.	.	PUNCT
eurjchem-604	1487	1	chem	chem	PROPN
eurjchem-604	1487	2	.	.	PUNCT
eurjchem-604	1488	1	1975	1975	NUM
eurjchem-604	1488	2	,	,	PUNCT
eurjchem-604	1488	3	12(5	12(5	NUM
eurjchem-604	1488	4	)	)	PUNCT
eurjchem-604	1488	5	,	,	PUNCT
eurjchem-604	1488	6	1055‐1059	1055‐1059	NUM
eurjchem-604	1488	7	.	.	PUNCT
eurjchem-604	1489	1	[	[	X
eurjchem-604	1489	2	141	141	NUM
eurjchem-604	1489	3	]	]	PUNCT
eurjchem-604	1489	4	.	.	PUNCT
eurjchem-604	1490	1	mossis	mossis	PROPN
eurjchem-604	1490	2	,	,	PUNCT
eurjchem-604	1490	3	d.	d.	PROPN
eurjchem-604	1490	4	e.	e.	PROPN
eurjchem-604	1490	5	;	;	PUNCT
eurjchem-604	1490	6	basolo	basolo	PROPN
eurjchem-604	1490	7	,	,	PUNCT
eurjchem-604	1490	8	f.	f.	PROPN
eurjchem-604	1490	9	j.	j.	PROPN
eurjchem-604	1490	10	am	am	PROPN
eurjchem-604	1490	11	.	.	PUNCT
eurjchem-604	1491	1	chem	chem	PROPN
eurjchem-604	1491	2	.	.	PUNCT
eurjchem-604	1492	1	soc	soc	PROPN
eurjchem-604	1492	2	.	.	PUNCT
eurjchem-604	1493	1	1968	1968	NUM
eurjchem-604	1493	2	,	,	PUNCT
eurjchem-604	1493	3	90(10	90(10	NUM
eurjchem-604	1493	4	)	)	PUNCT
eurjchem-604	1493	5	,	,	PUNCT
eurjchem-604	1493	6	2531‐2535	2531‐2535	NUM
eurjchem-604	1493	7	.	.	PUNCT
eurjchem-604	1494	1	[	[	X
eurjchem-604	1494	2	142	142	NUM
eurjchem-604	1494	3	]	]	PUNCT
eurjchem-604	1494	4	.	.	PUNCT
eurjchem-604	1495	1	angelici	angelici	PROPN
eurjchem-604	1495	2	,	,	PUNCT
eurjchem-604	1495	3	r.	r.	PROPN
eurjchem-604	1495	4	s.	s.	PROPN
eurjchem-604	1495	5	;	;	PUNCT
eurjchem-604	1495	6	lowen	lowen	PROPN
eurjchem-604	1495	7	,	,	PUNCT
eurjchem-604	1495	8	w.	w.	PROPN
eurjchem-604	1495	9	inorg	inorg	PROPN
eurjchem-604	1495	10	.	.	PUNCT
eurjchem-604	1496	1	chem	chem	PROPN
eurjchem-604	1496	2	.	.	PUNCT
eurjchem-604	1497	1	1967	1967	NUM
eurjchem-604	1497	2	,	,	PUNCT
eurjchem-604	1497	3	6(4	6(4	NUM
eurjchem-604	1497	4	)	)	PUNCT
eurjchem-604	1497	5	,	,	PUNCT
eurjchem-604	1497	6	682‐686	682‐686	NUM
eurjchem-604	1497	7	.	.	PUNCT
eurjchem-604	1498	1	[	[	X
eurjchem-604	1498	2	143	143	NUM
eurjchem-604	1498	3	]	]	PUNCT
eurjchem-604	1498	4	.	.	PUNCT
eurjchem-604	1499	1	kershner	kershner	PROPN
eurjchem-604	1499	2	,	,	PUNCT
eurjchem-604	1499	3	d.	d.	PROPN
eurjchem-604	1499	4	l.	l.	PROPN
eurjchem-604	1499	5	;	;	PUNCT
eurjchem-604	1499	6	rheingold	rheingold	PROPN
eurjchem-604	1499	7	,	,	PUNCT
eurjchem-604	1499	8	a.	a.	PROPN
eurjchem-604	1499	9	l.	l.	PROPN
eurjchem-604	1499	10	;	;	PUNCT
eurjchem-604	1499	11	basolo	basolo	PROPN
eurjchem-604	1499	12	,	,	PUNCT
eurjchem-604	1499	13	f.	f.	PROPN
eurjchem-604	1499	14	organometallics	organometallic	NOUN
eurjchem-604	1499	15	1987	1987	NUM
eurjchem-604	1499	16	,	,	PUNCT
eurjchem-604	1499	17	6	6	NUM
eurjchem-604	1499	18	,	,	PUNCT
eurjchem-604	1499	19	196‐198	196‐198	NUM
eurjchem-604	1499	20	.	.	PUNCT
eurjchem-604	1500	1	[	[	X
eurjchem-604	1500	2	144	144	NUM
eurjchem-604	1500	3	]	]	PUNCT
eurjchem-604	1500	4	.	.	PUNCT
eurjchem-604	1501	1	jones	jones	PROPN
eurjchem-604	1501	2	,	,	PUNCT
eurjchem-604	1501	3	d.	d.	PROPN
eurjchem-604	1501	4	j.	j.	PROPN
eurjchem-604	1501	5	;	;	PUNCT
eurjchem-604	1501	6	mawby	mawby	PROPN
eurjchem-604	1501	7	,	,	PUNCT
eurjchem-604	1501	8	r.	r.	PROPN
eurjchem-604	1501	9	j.	j.	PROPN
eurjchem-604	1501	10	inorg	inorg	PROPN
eurjchem-604	1501	11	.	.	PUNCT
eurjchem-604	1502	1	chim	chim	PROPN
eurjchem-604	1502	2	.	.	PUNCT
eurjchem-604	1503	1	acta	acta	PROPN
eurjchem-604	1503	2	1972	1972	NUM
eurjchem-604	1503	3	,	,	PUNCT
eurjchem-604	1503	4	6	6	NUM
eurjchem-604	1503	5	,	,	PUNCT
eurjchem-604	1503	6	157‐160	157‐160	NUM
eurjchem-604	1503	7	.	.	PUNCT
eurjchem-604	1504	1	[	[	X
eurjchem-604	1504	2	145	145	NUM
eurjchem-604	1504	3	]	]	PUNCT
eurjchem-604	1504	4	.	.	PUNCT
eurjchem-604	1505	1	kidd	kidd	PROPN
eurjchem-604	1505	2	,	,	PUNCT
eurjchem-604	1505	3	d.	d.	PROPN
eurjchem-604	1505	4	r.	r.	PROPN
eurjchem-604	1505	5	;	;	PUNCT
eurjchem-604	1505	6	brown	brown	ADJ
eurjchem-604	1505	7	,	,	PUNCT
eurjchem-604	1505	8	t.	t.	PROPN
eurjchem-604	1505	9	l.	l.	PROPN
eurjchem-604	1505	10	j.	j.	PROPN
eurjchem-604	1505	11	am	am	PROPN
eurjchem-604	1505	12	.	.	PUNCT
eurjchem-604	1506	1	chem	chem	PROPN
eurjchem-604	1506	2	.	.	PUNCT
eurjchem-604	1507	1	soc	soc	PROPN
eurjchem-604	1507	2	.	.	PUNCT
eurjchem-604	1508	1	1978	1978	NUM
eurjchem-604	1508	2	,	,	PUNCT
eurjchem-604	1508	3	100(13	100(13	NUM
eurjchem-604	1508	4	)	)	PUNCT
eurjchem-604	1508	5	,	,	PUNCT
eurjchem-604	1508	6	4095‐4103	4095‐4103	NUM
eurjchem-604	1508	7	.	.	PUNCT
eurjchem-604	1509	1	[	[	X
eurjchem-604	1509	2	146	146	NUM
eurjchem-604	1509	3	]	]	PUNCT
eurjchem-604	1509	4	.	.	PUNCT
eurjchem-604	1510	1	shi	shi	PROPN
eurjchem-604	1510	2	,	,	PUNCT
eurjchem-604	1510	3	q.	q.	PROPN
eurjchem-604	1510	4	z.	z.	PROPN
eurjchem-604	1510	5	;	;	PUNCT
eurjchem-604	1510	6	richmond	richmond	PROPN
eurjchem-604	1510	7	,	,	PUNCT
eurjchem-604	1510	8	t.	t.	PROPN
eurjchem-604	1510	9	g.	g.	PROPN
eurjchem-604	1510	10	;	;	PUNCT
eurjchem-604	1510	11	trogler	trogler	NOUN
eurjchem-604	1510	12	,	,	PUNCT
eurjchem-604	1510	13	w.	w.	PROPN
eurjchem-604	1510	14	c.	c.	PROPN
eurjchem-604	1510	15	;	;	PUNCT
eurjchem-604	1510	16	basolo	basolo	PROPN
eurjchem-604	1510	17	,	,	PUNCT
eurjchem-604	1510	18	f.	f.	PROPN
eurjchem-604	1510	19	j.	j.	PROPN
eurjchem-604	1510	20	am	am	PROPN
eurjchem-604	1510	21	.	.	PUNCT
eurjchem-604	1511	1	chem	chem	PROPN
eurjchem-604	1511	2	.	.	PUNCT
eurjchem-604	1512	1	soc	soc	PROPN
eurjchem-604	1512	2	.	.	PUNCT
eurjchem-604	1513	1	1984	1984	NUM
eurjchem-604	1513	2	,	,	PUNCT
eurjchem-604	1513	3	106(1	106(1	NUM
eurjchem-604	1513	4	)	)	PUNCT
eurjchem-604	1513	5	,	,	PUNCT
eurjchem-604	1513	6	71‐76	71‐76	NOUN
eurjchem-604	1513	7	.	.	PUNCT
eurjchem-604	1514	1	[	[	X
eurjchem-604	1514	2	147	147	NUM
eurjchem-604	1514	3	]	]	PUNCT
eurjchem-604	1514	4	.	.	PUNCT
eurjchem-604	1515	1	brown	brown	PROPN
eurjchem-604	1515	2	,	,	PUNCT
eurjchem-604	1515	3	t.	t.	PROPN
eurjchem-604	1515	4	l.	l.	PROPN
eurjchem-604	1515	5	ann	ann	PROPN
eurjchem-604	1515	6	.	.	PUNCT
eurjchem-604	1516	1	ny	ny	PROPN
eurjchem-604	1516	2	.	.	PROPN
eurjchem-604	1516	3	acad	acad	PROPN
eurjchem-604	1516	4	.	.	PUNCT
eurjchem-604	1517	1	sci	sci	PROPN
eurjchem-604	1517	2	.	.	PROPN
eurjchem-604	1517	3	1980	1980	NUM
eurjchem-604	1517	4	,	,	PUNCT
eurjchem-604	1517	5	333	333	NUM
eurjchem-604	1517	6	,	,	PUNCT
eurjchem-604	1517	7	80‐89	80‐89	X
eurjchem-604	1517	8	.	.	PUNCT
eurjchem-604	1518	1	[	[	X
eurjchem-604	1518	2	148	148	NUM
eurjchem-604	1518	3	]	]	PUNCT
eurjchem-604	1518	4	.	.	PUNCT
eurjchem-604	1519	1	kowaleski	kowaleski	PROPN
eurjchem-604	1519	2	,	,	PUNCT
eurjchem-604	1519	3	r.	r.	PROPN
eurjchem-604	1519	4	m.	m.	PROPN
eurjchem-604	1519	5	;	;	PUNCT
eurjchem-604	1519	6	basolo	basolo	PROPN
eurjchem-604	1519	7	,	,	PUNCT
eurjchem-604	1519	8	f.	f.	PROPN
eurjchem-604	1519	9	;	;	PUNCT
eurjchem-604	1519	10	trogler	trogler	NOUN
eurjchem-604	1519	11	,	,	PUNCT
eurjchem-604	1519	12	w.	w.	PROPN
eurjchem-604	1519	13	c.	c.	PROPN
eurjchem-604	1519	14	;	;	PUNCT
eurjchem-604	1519	15	ernst	ernst	PROPN
eurjchem-604	1519	16	,	,	PUNCT
eurjchem-604	1519	17	r.	r.	PROPN
eurjchem-604	1519	18	d.	d.	PROPN
eurjchem-604	1519	19	j.	j.	PROPN
eurjchem-604	1519	20	am	am	PROPN
eurjchem-604	1519	21	.	.	PUNCT
eurjchem-604	1520	1	chem	chem	PROPN
eurjchem-604	1520	2	.	.	PUNCT
eurjchem-604	1521	1	soc	soc	PROPN
eurjchem-604	1521	2	.	.	PUNCT
eurjchem-604	1522	1	1986	1986	NUM
eurjchem-604	1522	2	,	,	PUNCT
eurjchem-604	1522	3	108(19	108(19	NUM
eurjchem-604	1522	4	)	)	PUNCT
eurjchem-604	1522	5	,	,	PUNCT
eurjchem-604	1522	6	6046‐6048	6046‐6048	NUM
eurjchem-604	1522	7	.	.	PUNCT
eurjchem-604	1523	1	[	[	X
eurjchem-604	1523	2	149	149	NUM
eurjchem-604	1523	3	]	]	PUNCT
eurjchem-604	1523	4	.	.	PUNCT
eurjchem-604	1523	5	szymanska‐buzar	szymanska‐buzar	NOUN
eurjchem-604	1523	6	,	,	PUNCT
eurjchem-604	1523	7	t.	t.	PROPN
eurjchem-604	1523	8	;	;	PUNCT
eurjchem-604	1523	9	kern	kern	PROPN
eurjchem-604	1523	10	,	,	PUNCT
eurjchem-604	1523	11	k.	k.	PROPN
eurjchem-604	1523	12	j.	j.	PROPN
eurjchem-604	1523	13	organomet	organomet	PROPN
eurjchem-604	1523	14	.	.	PUNCT
eurjchem-604	1524	1	chem	chem	NOUN
eurjchem-604	1524	2	.	.	PUNCT
eurjchem-604	1525	1	2001	2001	NUM
eurjchem-604	1525	2	,	,	PUNCT
eurjchem-604	1525	3	622(1‐2	622(1‐2	NUM
eurjchem-604	1525	4	)	)	PUNCT
eurjchem-604	1525	5	,	,	PUNCT
eurjchem-604	1525	6	74‐83	74‐83	NOUN
eurjchem-604	1525	7	.	.	PUNCT
eurjchem-604	1526	1	[	[	X
eurjchem-604	1526	2	150	150	NUM
eurjchem-604	1526	3	]	]	PUNCT
eurjchem-604	1526	4	.	.	PUNCT
eurjchem-604	1526	5	tang	tang	PROPN
eurjchem-604	1526	6	,	,	PUNCT
eurjchem-604	1526	7	l.	l.	PROPN
eurjchem-604	1526	8	f.	f.	PROPN
eurjchem-604	1526	9	;	;	PUNCT
eurjchem-604	1526	10	jia	jia	PROPN
eurjchem-604	1526	11	,	,	PUNCT
eurjchem-604	1526	12	w.	w.	PROPN
eurjchem-604	1526	13	l.	l.	PROPN
eurjchem-604	1526	14	wang	wang	PROPN
eurjchem-604	1526	15	,	,	PUNCT
eurjchem-604	1526	16	z.	z.	PROPN
eurjchem-604	1526	17	h.	h.	PROPN
eurjchem-604	1526	18	,	,	PUNCT
eurjchem-604	1526	19	chai	chai	NOUN
eurjchem-604	1526	20	,	,	PUNCT
eurjchem-604	1526	21	j.	j.	PROPN
eurjchem-604	1526	22	f.	f.	PROPN
eurjchem-604	1526	23	;	;	PUNCT
eurjchem-604	1526	24	wang	wang	PROPN
eurjchem-604	1526	25	,	,	PUNCT
eurjchem-604	1526	26	j.	j.	PROPN
eurjchem-604	1526	27	t.	t.	PROPN
eurjchem-604	1526	28	j.	j.	PROPN
eurjchem-604	1526	29	organomet	organomet	PROPN
eurjchem-604	1526	30	.	.	PUNCT
eurjchem-604	1527	1	chem	chem	NOUN
eurjchem-604	1527	2	.	.	PUNCT
eurjchem-604	1528	1	2001	2001	NUM
eurjchem-604	1528	2	,	,	PUNCT
eurjchem-604	1528	3	637	637	NUM
eurjchem-604	1528	4	,	,	PUNCT
eurjchem-604	1528	5	209‐215	209‐215	NUM
eurjchem-604	1528	6	.	.	PUNCT
eurjchem-604	1529	1	[	[	X
eurjchem-604	1529	2	151	151	NUM
eurjchem-604	1529	3	]	]	SYM
eurjchem-604	1529	4	.	.	PUNCT
eurjchem-604	1530	1	tripathi	tripathi	PROPN
eurjchem-604	1530	2	,	,	PUNCT
eurjchem-604	1530	3	s.	s.	PROPN
eurjchem-604	1530	4	c.	c.	PROPN
eurjchem-604	1530	5	;	;	PUNCT
eurjchem-604	1530	6	srivastava	srivastava	PROPN
eurjchem-604	1530	7	,	,	PUNCT
eurjchem-604	1530	8	s.	s.	PROPN
eurjchem-604	1530	9	c.	c.	PROPN
eurjchem-604	1530	10	;	;	PUNCT
eurjchem-604	1530	11	srivastava	srivastava	PROPN
eurjchem-604	1530	12	,	,	PUNCT
eurjchem-604	1531	1	p.	p.	PROPN
eurjchem-604	1531	2	k.	k.	PROPN
eurjchem-604	1532	1	trans	trans	PROPN
eurjchem-604	1532	2	.	.	PUNCT
eurjchem-604	1533	1	metal	metal	PROPN
eurjchem-604	1533	2	.	.	PUNCT
eurjchem-604	1533	3	chem	chem	PROPN
eurjchem-604	1533	4	.	.	PUNCT
eurjchem-604	1534	1	1982	1982	NUM
eurjchem-604	1534	2	,	,	PUNCT
eurjchem-604	1534	3	7(3	7(3	NUM
eurjchem-604	1534	4	)	)	PUNCT
eurjchem-604	1534	5	,	,	PUNCT
eurjchem-604	1534	6	170‐174	170‐174	NUM
eurjchem-604	1534	7	.	.	PUNCT
eurjchem-604	1535	1	[	[	X
eurjchem-604	1535	2	152	152	NUM
eurjchem-604	1535	3	]	]	PUNCT
eurjchem-604	1535	4	.	.	PUNCT
eurjchem-604	1536	1	gu	gu	PROPN
eurjchem-604	1536	2	,	,	PUNCT
eurjchem-604	1536	3	c.	c.	PROPN
eurjchem-604	1536	4	y.	y.	PROPN
eurjchem-604	1536	5	;	;	PUNCT
eurjchem-604	1536	6	jing	jing	PROPN
eurjchem-604	1536	7	,	,	PUNCT
eurjchem-604	1536	8	s.	s.	PROPN
eurjchem-604	1536	9	;	;	PUNCT
eurjchem-604	1536	10	ji	ji	PROPN
eurjchem-604	1536	11	,	,	PUNCT
eurjchem-604	1536	12	w.	w.	PROPN
eurjchem-604	1536	13	;	;	PUNCT
eurjchem-604	1536	14	li	li	PROPN
eurjchem-604	1536	15	,	,	PUNCT
eurjchem-604	1536	16	z.	z.	PROPN
eurjchem-604	1536	17	w.	w.	PROPN
eurjchem-604	1536	18	inorg	inorg	PROPN
eurjchem-604	1536	19	.	.	PUNCT
eurjchem-604	1537	1	chim	chim	PROPN
eurjchem-604	1537	2	.	.	PUNCT
eurjchem-604	1538	1	acta	acta	PROPN
eurjchem-604	1538	2	2010	2010	NUM
eurjchem-604	1538	3	,	,	PUNCT
eurjchem-604	1538	4	363(7	363(7	NUM
eurjchem-604	1538	5	)	)	PUNCT
eurjchem-604	1538	6	,	,	PUNCT
eurjchem-604	1538	7	1604‐1606	1604‐1606	NUM
eurjchem-604	1538	8	.	.	PUNCT
eurjchem-604	1539	1	[	[	X
eurjchem-604	1539	2	153	153	NUM
eurjchem-604	1539	3	]	]	PUNCT
eurjchem-604	1539	4	.	.	PUNCT
eurjchem-604	1540	1	king	king	PROPN
eurjchem-604	1540	2	,	,	PUNCT
eurjchem-604	1540	3	r.	r.	PROPN
eurjchem-604	1540	4	b.	b.	PROPN
eurjchem-604	1540	5	;	;	PUNCT
eurjchem-604	1540	6	korenowski	korenowski	PROPN
eurjchem-604	1540	7	,	,	PUNCT
eurjchem-604	1540	8	t.	t.	PROPN
eurjchem-604	1540	9	f.	f.	PROPN
eurjchem-604	1540	10	inorg	inorg	PROPN
eurjchem-604	1540	11	.	.	PUNCT
eurjchem-604	1541	1	chem	chem	PROPN
eurjchem-604	1541	2	.	.	PUNCT
eurjchem-604	1542	1	1971	1971	NUM
eurjchem-604	1542	2	,	,	PUNCT
eurjchem-604	1542	3	10(6	10(6	NOUN
eurjchem-604	1542	4	)	)	PUNCT
eurjchem-604	1542	5	,	,	PUNCT
eurjchem-604	1542	6	1188‐1195	1188‐1195	NUM
eurjchem-604	1542	7	.	.	PUNCT
eurjchem-604	1543	1	[	[	X
eurjchem-604	1543	2	154	154	NUM
eurjchem-604	1543	3	]	]	PUNCT
eurjchem-604	1543	4	.	.	PUNCT
eurjchem-604	1544	1	sert	sert	PROPN
eurjchem-604	1544	2	,	,	PUNCT
eurjchem-604	1544	3	s.	s.	PROPN
eurjchem-604	1544	4	;	;	PUNCT
eurjchem-604	1544	5	ercag	ercag	PROPN
eurjchem-604	1544	6	,	,	PUNCT
eurjchem-604	1544	7	a.	a.	NOUN
eurjchem-604	1544	8	;	;	PUNCT
eurjchem-604	1544	9	senturk	senturk	PROPN
eurjchem-604	1544	10	,	,	PUNCT
eurjchem-604	1544	11	o.	o.	PROPN
eurjchem-604	1544	12	s.	s.	PROPN
eurjchem-604	1544	13	;	;	PUNCT
eurjchem-604	1544	14	sterenberg	sterenberg	PROPN
eurjchem-604	1544	15	,	,	PUNCT
eurjchem-604	1544	16	b.	b.	PROPN
eurjchem-604	1544	17	t.	t.	PROPN
eurjchem-604	1544	18	;	;	PUNCT
eurjchem-604	1544	19	udachin	udachin	PROPN
eurjchem-604	1544	20	,	,	PUNCT
eurjchem-604	1544	21	k.	k.	PROPN
eurjchem-604	1544	22	a.	a.	PROPN
eurjchem-604	1544	23	;	;	PUNCT
eurjchem-604	1544	24	ozdemir	ozdemir	PROPN
eurjchem-604	1544	25	,	,	PUNCT
eurjchem-604	1544	26	u.	u.	PROPN
eurjchem-604	1544	27	;	;	PUNCT
eurjchem-604	1544	28	sarikahya	sarikahya	PROPN
eurjchem-604	1544	29	,	,	PUNCT
eurjchem-604	1544	30	f.	f.	PROPN
eurjchem-604	1544	31	polyhedron	polyhedron	PROPN
eurjchem-604	1544	32	2003	2003	NUM
eurjchem-604	1544	33	,	,	PUNCT
eurjchem-604	1544	34	22(13	22(13	NUM
eurjchem-604	1544	35	)	)	PUNCT
eurjchem-604	1544	36	,	,	PUNCT
eurjchem-604	1544	37	1689‐1693	1689‐1693	NOUN
eurjchem-604	1544	38	.	.	PUNCT
eurjchem-604	1545	1	[	[	X
eurjchem-604	1545	2	155	155	NUM
eurjchem-604	1545	3	]	]	SYM
eurjchem-604	1545	4	.	.	PUNCT
eurjchem-604	1546	1	jongh	jongh	PROPN
eurjchem-604	1546	2	,	,	PUNCT
eurjchem-604	1546	3	l.	l.	PROPN
eurjchem-604	1546	4	a.	a.	PROPN
eurjchem-604	1546	5	;	;	PUNCT
eurjchem-604	1546	6	strasser	strasser	NOUN
eurjchem-604	1546	7	,	,	PUNCT
eurjchem-604	1546	8	c.	c.	PROPN
eurjchem-604	1546	9	e.	e.	PROPN
eurjchem-604	1546	10	;	;	PUNCT
eurjchem-604	1546	11	raubenheimer	raubenheimer	PROPN
eurjchem-604	1546	12	,	,	PUNCT
eurjchem-604	1546	13	h.	h.	PROPN
eurjchem-604	1546	14	g.	g.	PROPN
eurjchem-604	1546	15	;	;	PUNCT
eurjchem-604	1546	16	cronje	cronje	PROPN
eurjchem-604	1546	17	,	,	PUNCT
eurjchem-604	1546	18	s.	s.	PROPN
eurjchem-604	1546	19	polyhedron	polyhedron	PROPN
eurjchem-604	1546	20	2009	2009	NUM
eurjchem-604	1546	21	,	,	PUNCT
eurjchem-604	1546	22	28(16	28(16	NUM
eurjchem-604	1546	23	)	)	PUNCT
eurjchem-604	1546	24	,	,	PUNCT
eurjchem-604	1546	25	3635‐3641	3635‐3641	NUM
eurjchem-604	1546	26	.	.	PUNCT
eurjchem-604	1547	1	[	[	X
eurjchem-604	1547	2	156	156	NUM
eurjchem-604	1547	3	]	]	PUNCT
eurjchem-604	1547	4	.	.	PUNCT
eurjchem-604	1548	1	rooney	rooney	PROPN
eurjchem-604	1548	2	,	,	PUNCT
eurjchem-604	1548	3	c.	c.	PROPN
eurjchem-604	1548	4	p.	p.	PROPN
eurjchem-604	1548	5	;	;	PUNCT
eurjchem-604	1548	6	wade	wade	PROPN
eurjchem-604	1548	7	,	,	PUNCT
eurjchem-604	1548	8	j.	j.	PROPN
eurjchem-604	1548	9	l.	l.	PROPN
eurjchem-604	1548	10	;	;	PUNCT
eurjchem-604	1548	11	hinkle	hinkle	PROPN
eurjchem-604	1548	12	,	,	PUNCT
eurjchem-604	1548	13	a.	a.	PROPN
eurjchem-604	1548	14	c.	c.	PROPN
eurjchem-604	1548	15	;	;	PUNCT
eurjchem-604	1548	16	stolley	stolley	PROPN
eurjchem-604	1548	17	,	,	PUNCT
eurjchem-604	1548	18	r.	r.	PROPN
eurjchem-604	1548	19	m.	m.	PROPN
eurjchem-604	1548	20	;	;	PUNCT
eurjchem-604	1548	21	miller	miller	PROPN
eurjchem-604	1548	22	,	,	PUNCT
eurjchem-604	1548	23	s.	s.	PROPN
eurjchem-604	1548	24	m.	m.	PROPN
eurjchem-604	1548	25	;	;	PUNCT
eurjchem-604	1548	26	helm	helm	NOUN
eurjchem-604	1548	27	,	,	PUNCT
eurjchem-604	1548	28	m.	m.	NOUN
eurjchem-604	1548	29	l.	l.	PROPN
eurjchem-604	1548	30	main	main	ADJ
eurjchem-604	1548	31	group	group	NOUN
eurjchem-604	1548	32	chem	chem	NOUN
eurjchem-604	1548	33	.	.	PUNCT
eurjchem-604	1549	1	2008	2008	NUM
eurjchem-604	1549	2	,	,	PUNCT
eurjchem-604	1549	3	7(2	7(2	NUM
eurjchem-604	1549	4	)	)	PUNCT
eurjchem-604	1549	5	,	,	PUNCT
eurjchem-604	1549	6	155‐165	155‐165	NUM
eurjchem-604	1549	7	.	.	PUNCT
eurjchem-604	1550	1	[	[	X
eurjchem-604	1550	2	157	157	NUM
eurjchem-604	1550	3	]	]	PUNCT
eurjchem-604	1550	4	.	.	PUNCT
eurjchem-604	1550	5	morkan	morkan	PROPN
eurjchem-604	1550	6	,	,	PUNCT
eurjchem-604	1550	7	i.	i.	PROPN
eurjchem-604	1550	8	a	a	NOUN
eurjchem-604	1550	9	;	;	PUNCT
eurjchem-604	1550	10	guven	guven	ADJ
eurjchem-604	1550	11	,	,	PUNCT
eurjchem-604	1550	12	k.	k.	PROPN
eurjchem-604	1550	13	;	;	PUNCT
eurjchem-604	1550	14	ozkar	ozkar	PROPN
eurjchem-604	1550	15	,	,	PUNCT
eurjchem-604	1550	16	s.	s.	PROPN
eurjchem-604	1550	17	j.	j.	PROPN
eurjchem-604	1550	18	organomet	organomet	PROPN
eurjchem-604	1550	19	.	.	PUNCT
eurjchem-604	1551	1	chem	chem	NOUN
eurjchem-604	1551	2	.	.	PUNCT
eurjchem-604	1552	1	2004	2004	NUM
eurjchem-604	1552	2	,	,	PUNCT
eurjchem-604	1552	3	689(14	689(14	NUM
eurjchem-604	1552	4	)	)	PUNCT
eurjchem-604	1552	5	,	,	PUNCT
eurjchem-604	1552	6	2319‐2323	2319‐2323	NUM
eurjchem-604	1552	7	.	.	PUNCT
eurjchem-604	1553	1	[	[	X
eurjchem-604	1553	2	158	158	NUM
eurjchem-604	1553	3	]	]	PUNCT
eurjchem-604	1553	4	.	.	PUNCT
eurjchem-604	1554	1	wang	wang	PROPN
eurjchem-604	1554	2	,	,	PUNCT
eurjchem-604	1554	3	q.	q.	PROPN
eurjchem-604	1554	4	;	;	PUNCT
eurjchem-604	1554	5	zhang	zhang	PROPN
eurjchem-604	1554	6	,	,	PUNCT
eurjchem-604	1554	7	w.	w.	PROPN
eurjchem-604	1554	8	x.	x.	PROPN
eurjchem-604	1554	9	;	;	PUNCT
eurjchem-604	1554	10	zhenfeng	zhenfeng	PROPN
eurjchem-604	1554	11	,	,	PUNCT
eurjchem-604	1554	12	x.	x.	NOUN
eurjchem-604	1554	13	,	,	PUNCT
eurjchem-604	1554	14	organometallics	organometallic	NOUN
eurjchem-604	1554	15	2008	2008	NUM
eurjchem-604	1554	16	,	,	PUNCT
eurjchem-604	1554	17	27(15	27(15	NUM
eurjchem-604	1554	18	)	)	PUNCT
eurjchem-604	1554	19	,	,	PUNCT
eurjchem-604	1554	20	3627‐3629	3627‐3629	NUM
eurjchem-604	1554	21	.	.	PUNCT
eurjchem-604	1555	1	[	[	X
eurjchem-604	1555	2	159	159	NUM
eurjchem-604	1555	3	]	]	PUNCT
eurjchem-604	1555	4	.	.	PUNCT
eurjchem-604	1556	1	stepnicka	stepnicka	PROPN
eurjchem-604	1556	2	,	,	PUNCT
eurjchem-604	1556	3	p.	p.	PROPN
eurjchem-604	1556	4	j.	j.	PROPN
eurjchem-604	1557	1	organomet	organomet	PROPN
eurjchem-604	1557	2	.	.	PUNCT
eurjchem-604	1558	1	chem	chem	NOUN
eurjchem-604	1558	2	.	.	PUNCT
eurjchem-604	1559	1	2008	2008	NUM
eurjchem-604	1559	2	,	,	PUNCT
eurjchem-604	1559	3	693(2	693(2	NUM
eurjchem-604	1559	4	)	)	PUNCT
eurjchem-604	1559	5	,	,	PUNCT
eurjchem-604	1559	6	297‐306	297‐306	NUM
eurjchem-604	1559	7	.	.	PUNCT
eurjchem-604	1560	1	[	[	X
eurjchem-604	1560	2	160	160	NUM
eurjchem-604	1560	3	]	]	PUNCT
eurjchem-604	1560	4	.	.	PUNCT
eurjchem-604	1561	1	portnyagin	portnyagin	PROPN
eurjchem-604	1561	2	,	,	PUNCT
eurjchem-604	1561	3	i.	i.	PROPN
eurjchem-604	1561	4	a.	a.	PROPN
eurjchem-604	1561	5	;	;	PUNCT
eurjchem-604	1561	6	nechaev	nechaev	NOUN
eurjchem-604	1561	7	,	,	PUNCT
eurjchem-604	1561	8	m.	m.	PROPN
eurjchem-604	1561	9	s.	s.	PROPN
eurjchem-604	1561	10	j.	j.	PROPN
eurjchem-604	1561	11	organomet	organomet	PROPN
eurjchem-604	1561	12	.	.	PUNCT
eurjchem-604	1562	1	chem	chem	NOUN
eurjchem-604	1562	2	.	.	PUNCT
eurjchem-604	1563	1	2009	2009	NUM
eurjchem-604	1563	2	,	,	PUNCT
eurjchem-604	1563	3	694(19	694(19	NUM
eurjchem-604	1563	4	)	)	PUNCT
eurjchem-604	1563	5	,	,	PUNCT
eurjchem-604	1563	6	3149‐3153	3149‐3153	NUM
eurjchem-604	1563	7	.	.	PUNCT
eurjchem-604	1564	1	[	[	X
eurjchem-604	1564	2	161	161	NUM
eurjchem-604	1564	3	]	]	PUNCT
eurjchem-604	1564	4	.	.	PUNCT
eurjchem-604	1565	1	demircan	demircan	PROPN
eurjchem-604	1565	2	,	,	PUNCT
eurjchem-604	1565	3	o.	o.	INTJ
eurjchem-604	1565	4	;	;	PUNCT
eurjchem-604	1565	5	ozkar	ozkar	PROPN
eurjchem-604	1565	6	,	,	PUNCT
eurjchem-604	1565	7	s.	s.	PROPN
eurjchem-604	1565	8	;	;	PUNCT
eurjchem-604	1565	9	ulku	ulku	NOUN
eurjchem-604	1565	10	,	,	PUNCT
eurjchem-604	1565	11	d.	d.	PROPN
eurjchem-604	1565	12	;	;	PUNCT
eurjchem-604	1565	13	yildirim	yildirim	PROPN
eurjchem-604	1565	14	,	,	PUNCT
eurjchem-604	1565	15	l.	l.	PROPN
eurjchem-604	1565	16	t.	t.	PROPN
eurjchem-604	1565	17	j.	j.	PROPN
eurjchem-604	1565	18	organomet	organomet	PROPN
eurjchem-604	1565	19	.	.	PUNCT
eurjchem-604	1566	1	chem	chem	NOUN
eurjchem-604	1566	2	.	.	PUNCT
eurjchem-604	1567	1	2003	2003	NUM
eurjchem-604	1567	2	,	,	PUNCT
eurjchem-604	1567	3	688(1‐2	688(1‐2	NUM
eurjchem-604	1567	4	)	)	PUNCT
eurjchem-604	1567	5	,	,	PUNCT
eurjchem-604	1567	6	68‐74	68‐74	NOUN
eurjchem-604	1567	7	.	.	PUNCT
eurjchem-604	1568	1	[	[	X
eurjchem-604	1568	2	162	162	NUM
eurjchem-604	1568	3	]	]	PUNCT
eurjchem-604	1568	4	.	.	PUNCT
eurjchem-604	1569	1	hogarth	hogarth	PROPN
eurjchem-604	1569	2	,	,	PUNCT
eurjchem-604	1569	3	g.	g.	PROPN
eurjchem-604	1569	4	;	;	PUNCT
eurjchem-604	1569	5	norman	norman	PROPN
eurjchem-604	1569	6	,	,	PUNCT
eurjchem-604	1569	7	t.	t.	NOUN
eurjchem-604	1569	8	inorg	inorg	PROPN
eurjchem-604	1569	9	.	.	PUNCT
eurjchem-604	1570	1	chim	chim	PROPN
eurjchem-604	1570	2	.	.	PUNCT
eurjchem-604	1571	1	acta	acta	PROPN
eurjchem-604	1571	2	1997	1997	NUM
eurjchem-604	1571	3	,	,	PUNCT
eurjchem-604	1571	4	254(1	254(1	NUM
eurjchem-604	1571	5	)	)	PUNCT
eurjchem-604	1571	6	,	,	PUNCT
eurjchem-604	1571	7	167‐171	167‐171	NUM
eurjchem-604	1571	8	.	.	PUNCT
eurjchem-604	1572	1	[	[	X
eurjchem-604	1572	2	163	163	NUM
eurjchem-604	1572	3	]	]	PUNCT
eurjchem-604	1572	4	.	.	PUNCT
eurjchem-604	1573	1	ohs	ohs	PROPN
eurjchem-604	1573	2	,	,	PUNCT
eurjchem-604	1573	3	a.	a.	PROPN
eurjchem-604	1573	4	c.	c.	PROPN
eurjchem-604	1573	5	;	;	PUNCT
eurjchem-604	1573	6	rheingold	rheingold	PROPN
eurjchem-604	1573	7	,	,	PUNCT
eurjchem-604	1573	8	a.	a.	PROPN
eurjchem-604	1573	9	l.	l.	PROPN
eurjchem-604	1573	10	;	;	PUNCT
eurjchem-604	1573	11	shaw	shaw	PROPN
eurjchem-604	1573	12	,	,	PUNCT
eurjchem-604	1573	13	m.	m.	PROPN
eurjchem-604	1573	14	j.	j.	PROPN
eurjchem-604	1573	15	;	;	PUNCT
eurjchem-604	1573	16	nataro	nataro	PROPN
eurjchem-604	1573	17	,	,	PUNCT
eurjchem-604	1573	18	c.	c.	NOUN
eurjchem-604	1573	19	organometallics	organometallic	NOUN
eurjchem-604	1573	20	2004	2004	NUM
eurjchem-604	1573	21	,	,	PUNCT
eurjchem-604	1573	22	23(20	23(20	NUM
eurjchem-604	1573	23	)	)	PUNCT
eurjchem-604	1573	24	,	,	PUNCT
eurjchem-604	1573	25	4655‐4660	4655‐4660	NOUN
eurjchem-604	1573	26	.	.	PUNCT
eurjchem-604	1574	1	[	[	X
eurjchem-604	1574	2	164	164	NUM
eurjchem-604	1574	3	]	]	PUNCT
eurjchem-604	1574	4	.	.	PUNCT
eurjchem-604	1575	1	taher	taher	PROPN
eurjchem-604	1575	2	,	,	PUNCT
eurjchem-604	1575	3	m.	m.	NOUN
eurjchem-604	1575	4	a.	a.	PROPN
eurjchem-604	1575	5	;	;	PUNCT
eurjchem-604	1575	6	jarelnabbi	jarelnabbi	VERB
eurjchem-604	1575	7	,	,	PUNCT
eurjchem-604	1575	8	s.	s.	PROPN
eurjchem-604	1575	9	e.	e.	PROPN
eurjchem-604	1575	10	;	;	PUNCT
eurjchem-604	1575	11	al‐sehemi	al‐sehemi	PROPN
eurjchem-604	1575	12	,	,	PUNCT
eurjchem-604	1575	13	a.	a.	NOUN
eurjchem-604	1575	14	g.	g.	PROPN
eurjchem-604	1575	15	m.	m.	PROPN
eurjchem-604	1575	16	;	;	PUNCT
eurjchem-604	1575	17	el‐medani	el‐medani	PROPN
eurjchem-604	1575	18	,	,	PUNCT
eurjchem-604	1575	19	s.	s.	PROPN
eurjchem-604	1575	20	m.	m.	PROPN
eurjchem-604	1575	21	;	;	PUNCT
eurjchem-604	1575	22	ramadan	ramadan	PROPN
eurjchem-604	1575	23	,	,	PUNCT
eurjchem-604	1575	24	r.	r.	PROPN
eurjchem-604	1575	25	m.	m.	PROPN
eurjchem-604	1575	26	j.	j.	PROPN
eurjchem-604	1575	27	coord	coord	PROPN
eurjchem-604	1575	28	.	.	PUNCT
eurjchem-604	1576	1	chem	chem	PROPN
eurjchem-604	1576	2	.	.	PUNCT
eurjchem-604	1577	1	2009	2009	NUM
eurjchem-604	1577	2	,	,	PUNCT
eurjchem-604	1577	3	62(8	62(8	NUM
eurjchem-604	1577	4	)	)	PUNCT
eurjchem-604	1577	5	,	,	PUNCT
eurjchem-604	1577	6	1293‐1301	1293‐1301	NUM
eurjchem-604	1577	7	.	.	PUNCT
eurjchem-604	1578	1	[	[	X
eurjchem-604	1578	2	165	165	NUM
eurjchem-604	1578	3	]	]	PUNCT
eurjchem-604	1578	4	.	.	PUNCT
eurjchem-604	1579	1	guerro	guerro	PROPN
eurjchem-604	1579	2	,	,	PUNCT
eurjchem-604	1579	3	m.	m.	NOUN
eurjchem-604	1579	4	;	;	PUNCT
eurjchem-604	1579	5	piazza	piazza	NOUN
eurjchem-604	1579	6	,	,	PUNCT
eurjchem-604	1579	7	e.	e.	PROPN
eurjchem-604	1579	8	d.	d.	PROPN
eurjchem-604	1579	9	;	;	PUNCT
eurjchem-604	1579	10	jiang	jiang	PROPN
eurjchem-604	1579	11	,	,	PUNCT
eurjchem-604	1579	12	x.	x.	PROPN
eurjchem-604	1579	13	roisnel	roisnel	PROPN
eurjchem-604	1579	14	,	,	PUNCT
eurjchem-604	1579	15	t.	t.	PROPN
eurjchem-604	1579	16	;	;	PUNCT
eurjchem-604	1579	17	lorcy	lorcy	PROPN
eurjchem-604	1579	18	,	,	PUNCT
eurjchem-604	1579	19	d.	d.	PROPN
eurjchem-604	1579	20	j.	j.	PROPN
eurjchem-604	1579	21	organomet	organomet	PROPN
eurjchem-604	1579	22	.	.	PUNCT
eurjchem-604	1580	1	chem	chem	NOUN
eurjchem-604	1580	2	.	.	PUNCT
eurjchem-604	1581	1	2008	2008	NUM
eurjchem-604	1581	2	,	,	PUNCT
eurjchem-604	1581	3	693(13	693(13	NUM
eurjchem-604	1581	4	)	)	PUNCT
eurjchem-604	1581	5	,	,	PUNCT
eurjchem-604	1581	6	2345‐2350	2345‐2350	NUM
eurjchem-604	1581	7	.	.	PUNCT
eurjchem-604	1582	1	[	[	X
eurjchem-604	1582	2	166	166	NUM
eurjchem-604	1582	3	]	]	PUNCT
eurjchem-604	1582	4	.	.	PUNCT
eurjchem-604	1582	5	tang	tang	PROPN
eurjchem-604	1582	6	,	,	PUNCT
eurjchem-604	1582	7	f.	f.	PROPN
eurjchem-604	1582	8	l.	l.	PROPN
eurjchem-604	1582	9	;	;	PUNCT
eurjchem-604	1582	10	wang	wang	PROPN
eurjchem-604	1582	11	,	,	PUNCT
eurjchem-604	1582	12	z.	z.	PROPN
eurjchem-604	1582	13	h.	h.	PROPN
eurjchem-604	1582	14	;	;	PUNCT
eurjchem-604	1582	15	chai	chai	NOUN
eurjchem-604	1582	16	,	,	PUNCT
eurjchem-604	1582	17	j.	j.	PROPN
eurjchem-604	1582	18	f.	f.	PROPN
eurjchem-604	1582	19	;	;	PUNCT
eurjchem-604	1583	1	leng	leng	PROPN
eurjchem-604	1583	2	,	,	PUNCT
eurjchem-604	1583	3	x.	x.	PROPN
eurjchem-604	1583	4	b.	b.	PROPN
eurjchem-604	1583	5	;	;	PUNCT
eurjchem-604	1583	6	wang	wang	PROPN
eurjchem-604	1583	7	,	,	PUNCT
eurjchem-604	1583	8	j.	j.	PROPN
eurjchem-604	1583	9	t.	t.	PROPN
eurjchem-604	1583	10	;	;	PUNCT
eurjchem-604	1583	11	wang	wang	PROPN
eurjchem-604	1583	12	,	,	PUNCT
eurjchem-604	1583	13	h.	h.	PROPN
eurjchem-604	1583	14	g.	g.	PROPN
eurjchem-604	1583	15	j.	j.	PROPN
eurjchem-604	1583	16	organomet	organomet	PROPN
eurjchem-604	1583	17	.	.	PUNCT
eurjchem-604	1584	1	chem	chem	NOUN
eurjchem-604	1584	2	.	.	PUNCT
eurjchem-604	1585	1	2002	2002	NUM
eurjchem-604	1585	2	,	,	PUNCT
eurjchem-604	1585	3	642(1‐2	642(1‐2	NUM
eurjchem-604	1585	4	)	)	PUNCT
eurjchem-604	1585	5	,	,	PUNCT
eurjchem-604	1586	1	179‐185	179‐185	NUM
eurjchem-604	1586	2	.	.	PUNCT
eurjchem-604	1587	1	[	[	X
eurjchem-604	1587	2	167	167	NUM
eurjchem-604	1587	3	]	]	PUNCT
eurjchem-604	1587	4	.	.	PUNCT
eurjchem-604	1588	1	moya	moya	PROPN
eurjchem-604	1588	2	,	,	PUNCT
eurjchem-604	1588	3	s.	s.	PROPN
eurjchem-604	1588	4	a.	a.	PROPN
eurjchem-604	1588	5	;	;	PUNCT
eurjchem-604	1588	6	guerrero	guerrero	PROPN
eurjchem-604	1588	7	,	,	PUNCT
eurjchem-604	1588	8	j.	j.	PROPN
eurjchem-604	1588	9	;	;	PUNCT
eurjchem-604	1588	10	pastene	pastene	PROPN
eurjchem-604	1588	11	,	,	PUNCT
eurjchem-604	1588	12	r.	r.	PROPN
eurjchem-604	1588	13	;	;	PUNCT
eurjchem-604	1588	14	guzman	guzman	PROPN
eurjchem-604	1588	15	,	,	PUNCT
eurjchem-604	1588	16	i.	i.	PROPN
eurjchem-604	1588	17	a.	a.	PROPN
eurjchem-604	1588	18	;	;	PUNCT
eurjchem-604	1588	19	pardey	pardey	PROPN
eurjchem-604	1588	20	,	,	PUNCT
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eurjchem-604	1588	22	j.	j.	PROPN
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eurjchem-604	1588	25	,	,	PUNCT
eurjchem-604	1588	26	21(4	21(4	NUM
eurjchem-604	1588	27	)	)	PUNCT
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eurjchem-604	1589	3	]	]	PUNCT
eurjchem-604	1589	4	.	.	PUNCT
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eurjchem-604	1590	2	,	,	PUNCT
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eurjchem-604	1590	22	a.	a.	PROPN
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eurjchem-604	1590	26	,	,	PUNCT
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eurjchem-604	1591	1	chim	chim	PROPN
eurjchem-604	1591	2	.	.	PUNCT
eurjchem-604	1592	1	acta	acta	PROPN
eurjchem-604	1592	2	2001	2001	NUM
eurjchem-604	1592	3	,	,	PUNCT
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eurjchem-604	1592	5	)	)	PUNCT
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eurjchem-604	1592	7	7‐14	7‐14	NUM
eurjchem-604	1592	8	.	.	PUNCT
eurjchem-604	1593	1	[	[	X
eurjchem-604	1593	2	169	169	NUM
eurjchem-604	1593	3	]	]	PUNCT
eurjchem-604	1593	4	.	.	PUNCT
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eurjchem-604	1594	2	,	,	PUNCT
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eurjchem-604	1594	7	,	,	PUNCT
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eurjchem-604	1594	9	;	;	PUNCT
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eurjchem-604	1594	11	,	,	PUNCT
eurjchem-604	1594	12	r.	r.	PROPN
eurjchem-604	1594	13	r.	r.	PROPN
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eurjchem-604	1595	1	chim	chim	PROPN
eurjchem-604	1595	2	.	.	PUNCT
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eurjchem-604	1596	2	2006	2006	NUM
eurjchem-604	1596	3	,	,	PUNCT
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eurjchem-604	1596	5	)	)	PUNCT
eurjchem-604	1596	6	,	,	PUNCT
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eurjchem-604	1596	8	.	.	PUNCT
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eurjchem-604	1597	2	170	170	NUM
eurjchem-604	1597	3	]	]	PUNCT
eurjchem-604	1597	4	.	.	PUNCT
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eurjchem-604	1598	2	,	,	PUNCT
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eurjchem-604	1598	4	;	;	PUNCT
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eurjchem-604	1598	6	,	,	PUNCT
eurjchem-604	1598	7	a.	a.	PROPN
eurjchem-604	1598	8	k.	k.	PROPN
eurjchem-604	1598	9	;	;	PUNCT
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eurjchem-604	1598	11	,	,	PUNCT
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eurjchem-604	1598	13	polyhedron	polyhedron	NOUN
eurjchem-604	1598	14	2009	2009	NUM
eurjchem-604	1598	15	,	,	PUNCT
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eurjchem-604	1598	17	)	)	PUNCT
eurjchem-604	1598	18	,	,	PUNCT
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eurjchem-604	1598	20	.	.	PUNCT
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eurjchem-604	1599	2	171	171	NUM
eurjchem-604	1599	3	]	]	PUNCT
eurjchem-604	1599	4	.	.	PUNCT
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eurjchem-604	1600	2	,	,	PUNCT
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eurjchem-604	1600	8	;	;	PUNCT
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eurjchem-604	1600	10	,	,	PUNCT
eurjchem-604	1600	11	s.	s.	PROPN
eurjchem-604	1600	12	g.	g.	PROPN
eurjchem-604	1600	13	;	;	PUNCT
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eurjchem-604	1600	15	,	,	PUNCT
eurjchem-604	1600	16	s.	s.	PROPN
eurjchem-604	1600	17	;	;	PUNCT
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eurjchem-604	1600	19	,	,	PUNCT
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eurjchem-604	1600	21	h.	h.	PROPN
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eurjchem-604	1600	23	2009	2009	NUM
eurjchem-604	1600	24	,	,	PUNCT
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eurjchem-604	1600	26	)	)	PUNCT
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eurjchem-604	1600	29	.	.	PUNCT
eurjchem-604	1601	1	[	[	X
eurjchem-604	1601	2	172	172	NUM
eurjchem-604	1601	3	]	]	PUNCT
eurjchem-604	1601	4	.	.	PUNCT
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eurjchem-604	1602	2	,	,	PUNCT
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eurjchem-604	1602	5	;	;	PUNCT
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eurjchem-604	1602	7	,	,	PUNCT
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eurjchem-604	1602	9	;	;	PUNCT
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eurjchem-604	1602	22	j.	j.	PROPN
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eurjchem-604	1602	24	.	.	PUNCT
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eurjchem-604	1603	2	.	.	PUNCT
eurjchem-604	1604	1	2006	2006	NUM
eurjchem-604	1604	2	,	,	PUNCT
eurjchem-604	1604	3	691(23	691(23	NOUN
eurjchem-604	1604	4	)	)	PUNCT
eurjchem-604	1604	5	,	,	PUNCT
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eurjchem-604	1604	7	.	.	PUNCT
eurjchem-604	1604	8	.	.	PUNCT
eurjchem-604	1605	1	[	[	X
eurjchem-604	1605	2	173	173	NUM
eurjchem-604	1605	3	]	]	PUNCT
eurjchem-604	1605	4	.	.	PUNCT
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eurjchem-604	1606	2	,	,	PUNCT
eurjchem-604	1606	3	y.	y.	PROPN
eurjchem-604	1606	4	f.	f.	PROPN
eurjchem-604	1606	5	;	;	PUNCT
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eurjchem-604	1606	7	,	,	PUNCT
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eurjchem-604	1606	9	t.	t.	PROPN
eurjchem-604	1606	10	;	;	PUNCT
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eurjchem-604	1606	12	,	,	PUNCT
eurjchem-604	1606	13	h.	h.	PROPN
eurjchem-604	1606	14	b.	b.	PROPN
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eurjchem-604	1606	17	,	,	PUNCT
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eurjchem-604	1606	19	f.	f.	PROPN
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eurjchem-604	1606	22	.	.	PUNCT
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eurjchem-604	1607	2	.	.	PUNCT
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eurjchem-604	1608	2	,	,	PUNCT
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eurjchem-604	1608	4	)	)	PUNCT
eurjchem-604	1608	5	,	,	PUNCT
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eurjchem-604	1608	7	.	.	PUNCT
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eurjchem-604	1609	2	174	174	NUM
eurjchem-604	1609	3	]	]	PUNCT
eurjchem-604	1609	4	.	.	PUNCT
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eurjchem-604	1610	2	,	,	PUNCT
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eurjchem-604	1610	4	;	;	PUNCT
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eurjchem-604	1610	6	,	,	PUNCT
eurjchem-604	1610	7	a.	a.	NOUN
eurjchem-604	1610	8	;	;	PUNCT
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eurjchem-604	1610	10	,	,	PUNCT
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eurjchem-604	1610	15	,	,	PUNCT
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eurjchem-604	1610	17	j.	j.	PROPN
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eurjchem-604	1610	19	.	.	PUNCT
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eurjchem-604	1611	2	.	.	PUNCT
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eurjchem-604	1612	2	,	,	PUNCT
eurjchem-604	1612	3	263(2	263(2	NUM
eurjchem-604	1612	4	)	)	PUNCT
eurjchem-604	1612	5	,	,	PUNCT
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eurjchem-604	1612	7	.	.	PUNCT
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eurjchem-604	1613	2	175	175	NUM
eurjchem-604	1613	3	]	]	PUNCT
eurjchem-604	1613	4	.	.	PUNCT
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eurjchem-604	1613	6	,	,	PUNCT
eurjchem-604	1613	7	g.	g.	PROPN
eurjchem-604	1613	8	d.	d.	PROPN
eurjchem-604	1613	9	;	;	PUNCT
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eurjchem-604	1613	11	,	,	PUNCT
eurjchem-604	1613	12	e.	e.	PROPN
eurjchem-604	1613	13	;	;	PUNCT
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eurjchem-604	1613	15	,	,	PUNCT
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eurjchem-604	1613	17	a.	a.	PROPN
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eurjchem-604	1613	20	.	.	PUNCT
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eurjchem-604	1614	2	.	.	PUNCT
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eurjchem-604	1615	2	,	,	PUNCT
eurjchem-604	1615	3	691(11	691(11	NUM
eurjchem-604	1615	4	)	)	PUNCT
eurjchem-604	1615	5	,	,	PUNCT
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eurjchem-604	1615	7	.	.	PUNCT
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eurjchem-604	1616	2	176	176	NUM
eurjchem-604	1616	3	]	]	PUNCT
eurjchem-604	1616	4	.	.	PUNCT
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eurjchem-604	1616	6	,	,	PUNCT
eurjchem-604	1616	7	e.	e.	PROPN
eurjchem-604	1616	8	;	;	PUNCT
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eurjchem-604	1616	10	,	,	PUNCT
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eurjchem-604	1616	12	;	;	PUNCT
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eurjchem-604	1616	14	,	,	PUNCT
eurjchem-604	1616	15	o.	o.	PROPN
eurjchem-604	1616	16	s.	s.	PROPN
eurjchem-604	1616	17	;	;	PUNCT
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eurjchem-604	1616	19	,	,	PUNCT
eurjchem-604	1616	20	f.	f.	PROPN
eurjchem-604	1616	21	j.	j.	PROPN
eurjchem-604	1616	22	coord	coord	PROPN
eurjchem-604	1616	23	.	.	PUNCT
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eurjchem-604	1617	2	.	.	PUNCT
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eurjchem-604	1618	2	,	,	PUNCT
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eurjchem-604	1618	4	)	)	PUNCT
eurjchem-604	1618	5	,	,	PUNCT
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eurjchem-604	1618	7	.	.	PUNCT
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eurjchem-604	1619	3	]	]	PUNCT
eurjchem-604	1619	4	.	.	PUNCT
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eurjchem-604	1619	6	,	,	PUNCT
eurjchem-604	1619	7	j.	j.	PROPN
eurjchem-604	1619	8	k.	k.	PROPN
eurjchem-604	1619	9	;	;	PUNCT
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eurjchem-604	1619	11	,	,	PUNCT
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eurjchem-604	1619	13	inorg	inorg	PROPN
eurjchem-604	1619	14	.	.	PUNCT
eurjchem-604	1620	1	chem	chem	PROPN
eurjchem-604	1620	2	.	.	PUNCT
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eurjchem-604	1621	2	,	,	PUNCT
eurjchem-604	1621	3	7(10	7(10	NUM
eurjchem-604	1621	4	)	)	PUNCT
eurjchem-604	1621	5	,	,	PUNCT
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eurjchem-604	1621	7	.	.	PUNCT
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eurjchem-604	1622	2	178	178	NUM
eurjchem-604	1622	3	]	]	SYM
eurjchem-604	1622	4	.	.	PUNCT
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eurjchem-604	1623	2	,	,	PUNCT
eurjchem-604	1623	3	f.	f.	PROPN
eurjchem-604	1623	4	;	;	PUNCT
eurjchem-604	1623	5	kayran	kayran	PROPN
eurjchem-604	1623	6	,	,	PUNCT
eurjchem-604	1623	7	c.	c.	NOUN
eurjchem-604	1623	8	;	;	PUNCT
eurjchem-604	1623	9	ozkar	ozkar	PROPN
eurjchem-604	1623	10	,	,	PUNCT
eurjchem-604	1623	11	s.	s.	PROPN
eurjchem-604	1623	12	j.	j.	PROPN
eurjchem-604	1623	13	organomet	organomet	PROPN
eurjchem-604	1623	14	.	.	PUNCT
eurjchem-604	1624	1	chem	chem	NOUN
eurjchem-604	1624	2	.	.	PUNCT
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eurjchem-604	1625	2	,	,	PUNCT
eurjchem-604	1625	3	691(12	691(12	NUM
eurjchem-604	1625	4	)	)	PUNCT
eurjchem-604	1625	5	,	,	PUNCT
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eurjchem-604	1625	7	.	.	PUNCT
eurjchem-604	1626	1	[	[	X
eurjchem-604	1626	2	179	179	NUM
eurjchem-604	1626	3	]	]	PUNCT
eurjchem-604	1626	4	.	.	PUNCT
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eurjchem-604	1627	2	,	,	PUNCT
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eurjchem-604	1627	4	b.	b.	PROPN
eurjchem-604	1627	5	;	;	PUNCT
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eurjchem-604	1627	7	,	,	PUNCT
eurjchem-604	1627	8	y.	y.	PROPN
eurjchem-604	1627	9	;	;	PUNCT
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eurjchem-604	1627	11	,	,	PUNCT
eurjchem-604	1627	12	h.	h.	PROPN
eurjchem-604	1627	13	f.	f.	PROPN
eurjchem-604	1627	14	;	;	PUNCT
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eurjchem-604	1627	16	,	,	PUNCT
eurjchem-604	1627	17	n.	n.	PROPN
eurjchem-604	1627	18	;	;	PUNCT
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eurjchem-604	1627	20	,	,	PUNCT
eurjchem-604	1627	21	s.	s.	PROPN
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eurjchem-604	1627	23	.	.	PUNCT
eurjchem-604	1628	1	chim	chim	PROPN
eurjchem-604	1628	2	.	.	PUNCT
eurjchem-604	1629	1	acta	acta	PROPN
eurjchem-604	1629	2	2005	2005	NUM
eurjchem-604	1629	3	,	,	PUNCT
eurjchem-604	1629	4	358(5	358(5	NUM
eurjchem-604	1629	5	)	)	PUNCT
eurjchem-604	1629	6	,	,	PUNCT
eurjchem-604	1629	7	1442‐1452	1442‐1452	NUM
eurjchem-604	1629	8	.	.	PUNCT
eurjchem-604	1630	1	[	[	X
eurjchem-604	1630	2	180	180	NUM
eurjchem-604	1630	3	]	]	PUNCT
eurjchem-604	1630	4	.	.	PUNCT
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eurjchem-604	1631	2	,	,	PUNCT
eurjchem-604	1631	3	r.	r.	PROPN
eurjchem-604	1631	4	e.	e.	PROPN
eurjchem-604	1631	5	;	;	PUNCT
eurjchem-604	1631	6	kubiak	kubiak	PROPN
eurjchem-604	1631	7	,	,	PUNCT
eurjchem-604	1631	8	c.	c.	PROPN
eurjchem-604	1631	9	p.	p.	PROPN
eurjchem-604	1631	10	j.	j.	PROPN
eurjchem-604	1631	11	electroanalytical	electroanalytical	PROPN
eurjchem-604	1631	12	chem	chem	PROPN
eurjchem-604	1631	13	.	.	PUNCT
eurjchem-604	1631	14	1995	1995	NUM
eurjchem-604	1631	15	,	,	PUNCT
eurjchem-604	1631	16	393(1	393(1	NUM
eurjchem-604	1631	17	)	)	PUNCT
eurjchem-604	1631	18	,	,	PUNCT
eurjchem-604	1631	19	75‐86	75‐86	NOUN
eurjchem-604	1631	20	.	.	PUNCT
eurjchem-604	1632	1	[	[	X
eurjchem-604	1632	2	181	181	NUM
eurjchem-604	1632	3	]	]	SYM
eurjchem-604	1632	4	.	.	PUNCT
eurjchem-604	1632	5	brown	brown	PROPN
eurjchem-604	1632	6	,	,	PUNCT
eurjchem-604	1632	7	m.	m.	NOUN
eurjchem-604	1632	8	d.	d.	PROPN
eurjchem-604	1632	9	;	;	PUNCT
eurjchem-604	1632	10	levason	levason	PROPN
eurjchem-604	1632	11	,	,	PUNCT
eurjchem-604	1632	12	w.	w.	PROPN
eurjchem-604	1632	13	;	;	PUNCT
eurjchem-604	1632	14	manning	man	VERB
eurjchem-604	1632	15	,	,	PUNCT
eurjchem-604	1632	16	j.	j.	PROPN
eurjchem-604	1632	17	m.	m.	PROPN
eurjchem-604	1632	18	;	;	PUNCT
eurjchem-604	1632	19	reid	reid	PROPN
eurjchem-604	1632	20	,	,	PUNCT
eurjchem-604	1632	21	g.	g.	PROPN
eurjchem-604	1632	22	j.	j.	PROPN
eurjchem-604	1632	23	organomet	organomet	PROPN
eurjchem-604	1632	24	.	.	PUNCT
eurjchem-604	1633	1	chem	chem	NOUN
eurjchem-604	1633	2	.	.	PUNCT
eurjchem-604	1634	1	2005	2005	NUM
eurjchem-604	1634	2	,	,	PUNCT
eurjchem-604	1634	3	690(6	690(6	NUM
eurjchem-604	1634	4	)	)	PUNCT
eurjchem-604	1634	5	,	,	PUNCT
eurjchem-604	1634	6	1540‐1548	1540‐1548	NUM
eurjchem-604	1634	7	.	.	PUNCT
eurjchem-604	1635	1	[	[	X
eurjchem-604	1635	2	182	182	NUM
eurjchem-604	1635	3	]	]	PUNCT
eurjchem-604	1635	4	.	.	PUNCT
eurjchem-604	1636	1	mohamed	mohamed	PROPN
eurjchem-604	1636	2	,	,	PUNCT
eurjchem-604	1636	3	h.	h.	PROPN
eurjchem-604	1636	4	a.	a.	PROPN
eurjchem-604	1636	5	j.	j.	PROPN
eurjchem-604	1636	6	mol	mol	PROPN
eurjchem-604	1636	7	.	.	PROPN
eurjchem-604	1636	8	struct	struct	NOUN
eurjchem-604	1636	9	.	.	PUNCT
eurjchem-604	1637	1	2006	2006	NUM
eurjchem-604	1637	2	,	,	PUNCT
eurjchem-604	1637	3	784(1‐3	784(1‐3	NUM
eurjchem-604	1637	4	)	)	PUNCT
eurjchem-604	1637	5	,	,	PUNCT
eurjchem-604	1637	6	254‐258	254‐258	NUM
eurjchem-604	1637	7	.	.	PUNCT
eurjchem-604	1638	1	[	[	X
eurjchem-604	1638	2	183	183	NUM
eurjchem-604	1638	3	]	]	PUNCT
eurjchem-604	1638	4	.	.	PUNCT
eurjchem-604	1639	1	bitterwolf	bitterwolf	ADJ
eurjchem-604	1639	2	,	,	PUNCT
eurjchem-604	1639	3	t.	t.	PROPN
eurjchem-604	1639	4	e.	e.	PROPN
eurjchem-604	1639	5	coord	coord	PROPN
eurjchem-604	1639	6	.	.	PUNCT
eurjchem-604	1640	1	chem	chem	PROPN
eurjchem-604	1640	2	.	.	PUNCT
eurjchem-604	1641	1	rev	rev	PROPN
eurjchem-604	1641	2	.	.	PROPN
eurjchem-604	1641	3	2001	2001	NUM
eurjchem-604	1641	4	,	,	PUNCT
eurjchem-604	1641	5	211(1	211(1	NUM
eurjchem-604	1641	6	)	)	PUNCT
eurjchem-604	1641	7	,	,	PUNCT
eurjchem-604	1641	8	235‐254	235‐254	NUM
eurjchem-604	1641	9	.	.	PUNCT
eurjchem-604	1642	1	[	[	X
eurjchem-604	1642	2	184	184	NUM
eurjchem-604	1642	3	]	]	PUNCT
eurjchem-604	1642	4	.	.	PUNCT
eurjchem-604	1643	1	sert	sert	PROPN
eurjchem-604	1643	2	,	,	PUNCT
eurjchem-604	1643	3	s.	s.	PROPN
eurjchem-604	1643	4	;	;	PUNCT
eurjchem-604	1643	5	senturk	senturk	PROPN
eurjchem-604	1643	6	,	,	PUNCT
eurjchem-604	1643	7	o.	o.	PROPN
eurjchem-604	1643	8	s.	s.	PROPN
eurjchem-604	1643	9	;	;	PUNCT
eurjchem-604	1643	10	ugur	ugur	PROPN
eurjchem-604	1643	11	,	,	PUNCT
eurjchem-604	1643	12	f.	f.	PROPN
eurjchem-604	1643	13	s.	s.	PROPN
eurjchem-604	1643	14	trans	trans	PROPN
eurjchem-604	1643	15	.	.	PROPN
eurjchem-604	1643	16	met	meet	VERB
eurjchem-604	1643	17	.	.	PUNCT
eurjchem-604	1644	1	chem	chem	NOUN
eurjchem-604	1644	2	.	.	PUNCT
eurjchem-604	1645	1	2003	2003	NUM
eurjchem-604	1645	2	,	,	PUNCT
eurjchem-604	1645	3	28	28	NUM
eurjchem-604	1645	4	,	,	PUNCT
eurjchem-604	1645	5	133‐	133‐	NUM
eurjchem-604	1645	6	136	136	NUM
eurjchem-604	1645	7	.	.	PUNCT
eurjchem-604	1646	1	[	[	X
eurjchem-604	1646	2	185	185	NUM
eurjchem-604	1646	3	]	]	PUNCT
eurjchem-604	1646	4	.	.	PUNCT
eurjchem-604	1647	1	senturk	senturk	PROPN
eurjchem-604	1647	2	,	,	PUNCT
eurjchem-604	1647	3	o.	o.	PROPN
eurjchem-604	1647	4	s.	s.	PROPN
eurjchem-604	1647	5	;	;	PUNCT
eurjchem-604	1647	6	ugur	ugur	PROPN
eurjchem-604	1647	7	,	,	PUNCT
eurjchem-604	1647	8	f.	f.	PROPN
eurjchem-604	1647	9	synth	synth	PROPN
eurjchem-604	1647	10	.	.	PUNCT
eurjchem-604	1648	1	react	react	VERB
eurjchem-604	1648	2	.	.	PUNCT
eurjchem-604	1649	1	inorg	inorg	PROPN
eurjchem-604	1649	2	.	.	PUNCT
eurjchem-604	1650	1	me	i	PRON
eurjchem-604	1650	2	.	.	PUNCT
eurjchem-604	1651	1	2001	2001	NUM
eurjchem-604	1651	2	,	,	PUNCT
eurjchem-604	1651	3	31(10	31(10	NUM
eurjchem-604	1651	4	)	)	PUNCT
eurjchem-604	1651	5	,	,	PUNCT
eurjchem-604	1651	6	1843‐	1843‐	NUM
eurjchem-604	1651	7	1851	1851	NUM
eurjchem-604	1651	8	.	.	PUNCT
eurjchem-604	1652	1	[	[	X
eurjchem-604	1652	2	186	186	NUM
eurjchem-604	1652	3	]	]	PUNCT
eurjchem-604	1652	4	.	.	PUNCT
eurjchem-604	1653	1	bin	bin	PROPN
eurjchem-604	1653	2	li	li	PROPN
eurjchem-604	1653	3	,	,	PUNCT
eurjchem-604	1653	4	wang	wang	PROPN
eurjchem-604	1653	5	,	,	PUNCT
eurjchem-604	1653	6	b.	b.	PROPN
eurjchem-604	1653	7	;	;	PUNCT
eurjchem-604	1653	8	xu	xu	PROPN
eurjchem-604	1653	9	,	,	PUNCT
eurjchem-604	1653	10	s.	s.	PROPN
eurjchem-604	1653	11	and	and	CCONJ
eurjchem-604	1653	12	zhou	zhou	PROPN
eurjchem-604	1653	13	,	,	PUNCT
eurjchem-604	1653	14	x.	x.	PROPN
eurjchem-604	1653	15	j.	j.	PROPN
eurjchem-604	1653	16	organomet	organomet	PROPN
eurjchem-604	1653	17	.	.	PUNCT
eurjchem-604	1654	1	chem	chem	NOUN
eurjchem-604	1654	2	.	.	PUNCT
eurjchem-604	1655	1	2005	2005	NUM
eurjchem-604	1655	2	,	,	PUNCT
eurjchem-604	1655	3	690(23	690(23	NOUN
eurjchem-604	1655	4	)	)	PUNCT
eurjchem-604	1655	5	,	,	PUNCT
eurjchem-604	1655	6	5309‐5317	5309‐5317	NUM
eurjchem-604	1655	7	.	.	PUNCT
eurjchem-604	1656	1	[	[	X
eurjchem-604	1656	2	187	187	NUM
eurjchem-604	1656	3	]	]	PUNCT
eurjchem-604	1656	4	.	.	PUNCT
eurjchem-604	1657	1	king	king	PROPN
eurjchem-604	1657	2	,	,	PUNCT
eurjchem-604	1657	3	r.	r.	PROPN
eurjchem-604	1657	4	b.	b.	PROPN
eurjchem-604	1657	5	;	;	PUNCT
eurjchem-604	1657	6	stone	stone	PROPN
eurjchem-604	1657	7	,	,	PUNCT
eurjchem-604	1657	8	f.	f.	PROPN
eurjchem-604	1657	9	g.	g.	PROPN
eurjchem-604	1657	10	a.	a.	PROPN
eurjchem-604	1657	11	j.	j.	PROPN
eurjchem-604	1657	12	am	am	PROPN
eurjchem-604	1657	13	.	.	PUNCT
eurjchem-604	1658	1	chem	chem	NOUN
eurjchem-604	1658	2	.	.	PUNCT
eurjchem-604	1659	1	soc	soc	PROPN
eurjchem-604	1659	2	.	.	PUNCT
eurjchem-604	1660	1	1961	1961	NUM
eurjchem-604	1660	2	,	,	PUNCT
eurjchem-604	1660	3	83(17	83(17	NUM
eurjchem-604	1660	4	)	)	PUNCT
eurjchem-604	1660	5	,	,	PUNCT
eurjchem-604	1660	6	3590‐3593	3590‐3593	NUM
eurjchem-604	1660	7	.	.	PUNCT
eurjchem-604	1661	1	[	[	X
eurjchem-604	1661	2	188	188	NUM
eurjchem-604	1661	3	]	]	PUNCT
eurjchem-604	1661	4	.	.	PUNCT
eurjchem-604	1661	5	soliman	soliman	PROPN
eurjchem-604	1661	6	,	,	PUNCT
eurjchem-604	1661	7	a.	a.	NOUN
eurjchem-604	1661	8	a.	a.	PROPN
eurjchem-604	1661	9	;	;	PUNCT
eurjchem-604	1661	10	ali	ali	PROPN
eurjchem-604	1661	11	,	,	PUNCT
eurjchem-604	1661	12	s.	s.	PROPN
eurjchem-604	1661	13	a.	a.	PROPN
eurjchem-604	1661	14	;	;	PUNCT
eurjchem-604	1661	15	orabi	orabi	NOUN
eurjchem-604	1661	16	,	,	PUNCT
eurjchem-604	1661	17	a.	a.	NOUN
eurjchem-604	1661	18	spectrochim	spectrochim	PROPN
eurjchem-604	1661	19	.	.	PUNCT
eurjchem-604	1662	1	acta	acta	PROPN
eurjchem-604	1662	2	a	a	DET
eurjchem-604	1662	3	2006	2006	NUM
eurjchem-604	1662	4	,	,	PUNCT
eurjchem-604	1662	5	65(3‐4	65(3‐4	NUM
eurjchem-604	1662	6	)	)	PUNCT
eurjchem-604	1662	7	,	,	PUNCT
eurjchem-604	1662	8	841‐845	841‐845	NUM
eurjchem-604	1662	9	.	.	PUNCT
eurjchem-604	1663	1	[	[	X
eurjchem-604	1663	2	189	189	NUM
eurjchem-604	1663	3	]	]	PUNCT
eurjchem-604	1663	4	.	.	PUNCT
eurjchem-604	1664	1	fischer	fischer	PROPN
eurjchem-604	1664	2	,	,	PUNCT
eurjchem-604	1664	3	p.	p.	PROPN
eurjchem-604	1664	4	j.	j.	PROPN
eurjchem-604	1664	5	;	;	PUNCT
eurjchem-604	1664	6	krohn	krohn	PROPN
eurjchem-604	1664	7	,	,	PUNCT
eurjchem-604	1664	8	k.	k.	PROPN
eurjchem-604	1664	9	m.	m.	PROPN
eurjchem-604	1664	10	;	;	PUNCT
eurjchem-604	1664	11	mwenda	mwenda	ADV
eurjchem-604	1664	12	,	,	PUNCT
eurjchem-604	1664	13	e.	e.	PROPN
eurjchem-604	1664	14	t.	t.	PROPN
eurjchem-604	1664	15	;	;	PUNCT
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eurjchem-604	1664	17	jr	jr	PROPN
eurjchem-604	1664	18	.	.	PROPN
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eurjchem-604	1665	2	g.	g.	PROPN
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eurjchem-604	1665	4	2005	2005	NUM
eurjchem-604	1665	5	,	,	PUNCT
eurjchem-604	1665	6	24(7	24(7	NUM
eurjchem-604	1665	7	)	)	PUNCT
eurjchem-604	1665	8	,	,	PUNCT
eurjchem-604	1666	1	1776‐1779	1776‐1779	NUM
eurjchem-604	1666	2	.	.	PUNCT
eurjchem-604	1667	1	[	[	X
eurjchem-604	1667	2	190	190	NUM
eurjchem-604	1667	3	]	]	PUNCT
eurjchem-604	1667	4	.	.	PUNCT
eurjchem-604	1668	1	tan	tan	PROPN
eurjchem-604	1668	2	,	,	PUNCT
eurjchem-604	1668	3	r.	r.	PROPN
eurjchem-604	1668	4	y.	y.	PROPN
eurjchem-604	1668	5	;	;	PUNCT
eurjchem-604	1668	6	song	song	PROPN
eurjchem-604	1668	7	,	,	PUNCT
eurjchem-604	1668	8	h.	h.	PROPN
eurjchem-604	1668	9	b.	b.	PROPN
eurjchem-604	1668	10	;	;	PUNCT
eurjchem-604	1668	11	tang	tang	PROPN
eurjchem-604	1668	12	,	,	PUNCT
eurjchem-604	1668	13	l.	l.	PROPN
eurjchem-604	1668	14	f.	f.	PROPN
eurjchem-604	1668	15	j.	j.	PROPN
eurjchem-604	1668	16	organomet	organomet	PROPN
eurjchem-604	1668	17	.	.	PUNCT
eurjchem-604	1669	1	chem	chem	NOUN
eurjchem-604	1669	2	.	.	PUNCT
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eurjchem-604	1670	2	,	,	PUNCT
eurjchem-604	1670	3	691(26	691(26	NOUN
eurjchem-604	1670	4	)	)	PUNCT
eurjchem-604	1670	5	,	,	PUNCT
eurjchem-604	1670	6	5964‐5969	5964‐5969	NUM
eurjchem-604	1670	7	.	.	PUNCT
eurjchem-604	1671	1	[	[	X
eurjchem-604	1671	2	191	191	NUM
eurjchem-604	1671	3	]	]	PUNCT
eurjchem-604	1671	4	.	.	PUNCT
eurjchem-604	1671	5	harrington	harrington	PROPN
eurjchem-604	1671	6	,	,	PUNCT
eurjchem-604	1671	7	l.	l.	PROPN
eurjchem-604	1671	8	e.	e.	PROPN
eurjchem-604	1671	9	;	;	PUNCT
eurjchem-604	1671	10	cahill	cahill	PROPN
eurjchem-604	1671	11	,	,	PUNCT
eurjchem-604	1671	12	l.	l.	PROPN
eurjchem-604	1671	13	s.	s.	PROPN
eurjchem-604	1671	14	;	;	PUNCT
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eurjchem-604	1671	16	,	,	PUNCT
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eurjchem-604	1671	18	j.	j.	PROPN
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eurjchem-604	1671	21	,	,	PUNCT
eurjchem-604	1671	22	23(12	23(12	NUM
eurjchem-604	1671	23	)	)	PUNCT
eurjchem-604	1671	24	,	,	PUNCT
eurjchem-604	1671	25	2884‐2891	2884‐2891	NUM
eurjchem-604	1671	26	.	.	PUNCT
eurjchem-604	1672	1	[	[	X
eurjchem-604	1672	2	192	192	NUM
eurjchem-604	1672	3	]	]	PUNCT
eurjchem-604	1672	4	.	.	PUNCT
eurjchem-604	1672	5	shlu	shlu	PROPN
eurjchem-604	1672	6	,	,	PUNCT
eurjchem-604	1672	7	k.	k.	PROPN
eurjchem-604	1672	8	b.	b.	PROPN
eurjchem-604	1672	9	;	;	PUNCT
eurjchem-604	1672	10	chou	chou	PROPN
eurjchem-604	1672	11	,	,	PUNCT
eurjchem-604	1672	12	c.	c.	PROPN
eurjchem-604	1672	13	c.	c.	PROPN
eurjchem-604	1672	14	;	;	PUNCT
eurjchem-604	1672	15	wang	wang	PROPN
eurjchem-604	1672	16	,	,	PUNCT
eurjchem-604	1672	17	s.	s.	PROPN
eurjchem-604	1672	18	l.	l.	PROPN
eurjchem-604	1672	19	;	;	PUNCT
eurjchem-604	1672	20	wei	wei	PROPN
eurjchem-604	1672	21	,	,	PUNCT
eurjchem-604	1672	22	s.	s.	PROPN
eurjchem-604	1672	23	c.	c.	PROPN
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eurjchem-604	1672	26	,	,	PUNCT
eurjchem-604	1672	27	9	9	NUM
eurjchem-604	1672	28	,	,	PUNCT
eurjchem-604	1672	29	286‐288	286‐288	NUM
eurjchem-604	1672	30	.	.	PUNCT
eurjchem-604	1673	1	[	[	X
eurjchem-604	1673	2	193	193	NUM
eurjchem-604	1673	3	]	]	SYM
eurjchem-604	1673	4	.	.	PUNCT
eurjchem-604	1673	5	mingos	mingos	PROPN
eurjchem-604	1673	6	,	,	PUNCT
eurjchem-604	1673	7	d.	d.	PROPN
eurjchem-604	1673	8	m.	m.	PROPN
eurjchem-604	1673	9	p.	p.	PROPN
eurjchem-604	1673	10	;	;	PUNCT
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eurjchem-604	1673	12	,	,	PUNCT
eurjchem-604	1673	13	d.	d.	PROPN
eurjchem-604	1673	14	j.	j.	PROPN
eurjchem-604	1673	15	introduction	introduction	PROPN
eurjchem-604	1673	16	to	to	PART
eurjchem-604	1673	17	cluster	cluster	NOUN
eurjchem-604	1673	18	chemistry	chemistry	NOUN
eurjchem-604	1673	19	,	,	PUNCT
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eurjchem-604	1673	22	press	press	PROPN
eurjchem-604	1673	23	,	,	PUNCT
eurjchem-604	1673	24	1990	1990	NUM
eurjchem-604	1673	25	.	.	PUNCT
eurjchem-604	1674	1	[	[	X
eurjchem-604	1674	2	194	194	NUM
eurjchem-604	1674	3	]	]	PUNCT
eurjchem-604	1674	4	.	.	PUNCT
eurjchem-604	1675	1	huheey	huheey	PROPN
eurjchem-604	1675	2	,	,	PUNCT
eurjchem-604	1675	3	j.	j.	PROPN
eurjchem-604	1675	4	e.	e.	PROPN
eurjchem-604	1675	5	inorganic	inorganic	PROPN
eurjchem-604	1675	6	chemistry	chemistry	PROPN
eurjchem-604	1675	7	,	,	PUNCT
eurjchem-604	1675	8	3rded	3rded	NUM
eurjchem-604	1675	9	.	.	PUNCT
eurjchem-604	1676	1	harper	harper	NOUN
eurjchem-604	1676	2	and	and	CCONJ
eurjchem-604	1676	3	row	row	NOUN
eurjchem-604	1676	4	,	,	PUNCT
eurjchem-604	1676	5	new	new	PROPN
eurjchem-604	1676	6	york	york	PROPN
eurjchem-604	1676	7	,	,	PUNCT
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eurjchem-604	1676	9	.	.	PUNCT
eurjchem-604	1677	1	[	[	X
eurjchem-604	1677	2	195	195	NUM
eurjchem-604	1677	3	]	]	PUNCT
eurjchem-604	1677	4	.	.	PUNCT
eurjchem-604	1677	5	braunstein	braunstein	ADJ
eurjchem-604	1677	6	,	,	PUNCT
eurjchem-604	1677	7	p.	p.	PROPN
eurjchem-604	1677	8	;	;	PUNCT
eurjchem-604	1677	9	oro	oro	PROPN
eurjchem-604	1677	10	,	,	PUNCT
eurjchem-604	1677	11	l.	l.	PROPN
eurjchem-604	1677	12	a.	a.	PROPN
eurjchem-604	1677	13	;	;	PUNCT
eurjchem-604	1677	14	raithby	raithby	NOUN
eurjchem-604	1677	15	,	,	PUNCT
eurjchem-604	1677	16	p.	p.	PROPN
eurjchem-604	1677	17	r.	r.	PROPN
eurjchem-604	1677	18	metal	metal	PROPN
eurjchem-604	1677	19	clusters	cluster	NOUN
eurjchem-604	1677	20	in	in	ADP
eurjchem-604	1677	21	chemistry	chemistry	NOUN
eurjchem-604	1677	22	,	,	PUNCT
eurjchem-604	1677	23	wiley‐vch	wiley‐vch	PROPN
eurjchem-604	1677	24	,	,	PUNCT
eurjchem-604	1677	25	weinheim	weinheim	PROPN
eurjchem-604	1677	26	,	,	PUNCT
eurjchem-604	1677	27	1999	1999	NUM
eurjchem-604	1677	28	.	.	PUNCT
eurjchem-604	1678	1	[	[	X
eurjchem-604	1678	2	196	196	NUM
eurjchem-604	1678	3	]	]	PUNCT
eurjchem-604	1678	4	.	.	PUNCT
eurjchem-604	1679	1	zhuang	zhuang	PROPN
eurjchem-604	1679	2	,	,	PUNCT
eurjchem-604	1679	3	b.	b.	PROPN
eurjchem-604	1679	4	;	;	PUNCT
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eurjchem-604	1679	6	,	,	PUNCT
eurjchem-604	1679	7	h.	h.	PROPN
eurjchem-604	1679	8	;	;	PUNCT
eurjchem-604	1679	9	pan	pan	PROPN
eurjchem-604	1679	10	,	,	PUNCT
eurjchem-604	1679	11	g.	g.	PROPN
eurjchem-604	1679	12	;	;	PUNCT
eurjchem-604	1679	13	he	he	PRON
eurjchem-604	1679	14	,	,	PUNCT
eurjchem-604	1679	15	l.	l.	PROPN
eurjchem-604	1679	16	;	;	PUNCT
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eurjchem-604	1679	18	,	,	PUNCT
eurjchem-604	1679	19	q.	q.	PROPN
eurjchem-604	1679	20	;	;	PUNCT
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eurjchem-604	1679	22	,	,	PUNCT
eurjchem-604	1679	23	z.	z.	PROPN
eurjchem-604	1679	24	;	;	PUNCT
eurjchem-604	1679	25	peng	peng	PROPN
eurjchem-604	1679	26	,	,	PUNCT
eurjchem-604	1679	27	s.	s.	PROPN
eurjchem-604	1679	28	;	;	PUNCT
eurjchem-604	1679	29	wu	wu	PROPN
eurjchem-604	1679	30	,	,	PUNCT
eurjchem-604	1679	31	k.	k.	PROPN
eurjchem-604	1679	32	j.	j.	PROPN
eurjchem-604	1679	33	organomet	organomet	PROPN
eurjchem-604	1679	34	.	.	PUNCT
eurjchem-604	1680	1	chem	chem	NOUN
eurjchem-604	1680	2	.	.	PUNCT
eurjchem-604	1681	1	2001	2001	NUM
eurjchem-604	1681	2	,	,	PUNCT
eurjchem-604	1681	3	640(1‐2	640(1‐2	NUM
eurjchem-604	1681	4	)	)	PUNCT
eurjchem-604	1681	5	,	,	PUNCT
eurjchem-604	1681	6	127‐139	127‐139	NUM
eurjchem-604	1681	7	.	.	PUNCT
eurjchem-604	1682	1	retracted	retract	VERB
eurjchem-604	1682	2	kaushik	kaushik	PROPN
eurjchem-604	1682	3	et	et	PROPN
eurjchem-604	1682	4	al	al	PROPN
eurjchem-604	1682	5	.	.	PUNCT
eurjchem-604	1682	6	/	/	SYM
eurjchem-604	1682	7	european	european	PROPN
eurjchem-604	1682	8	journal	journal	PROPN
eurjchem-604	1682	9	of	of	ADP
eurjchem-604	1682	10	chemistry	chemistry	NOUN
eurjchem-604	1682	11	3	3	NUM
eurjchem-604	1682	12	(	(	PUNCT
eurjchem-604	1682	13	3	3	NUM
eurjchem-604	1682	14	)	)	PUNCT
eurjchem-604	1682	15	(	(	PUNCT
eurjchem-604	1682	16	2012	2012	NUM
eurjchem-604	1682	17	)	)	PUNCT
eurjchem-604	1682	18	367‐394	367‐394	NOUN
eurjchem-604	1682	19	393	393	NUM
eurjchem-604	1683	1	[	[	X
eurjchem-604	1683	2	197	197	NUM
eurjchem-604	1683	3	]	]	PUNCT
eurjchem-604	1683	4	.	.	PUNCT
eurjchem-604	1684	1	garcia	garcia	PROPN
eurjchem-604	1684	2	,	,	PUNCT
eurjchem-604	1684	3	m.	m.	PROPN
eurjchem-604	1684	4	e.	e.	PROPN
eurjchem-604	1684	5	;	;	PUNCT
eurjchem-604	1684	6	garcia‐vivo	garcia‐vivo	VERB
eurjchem-604	1684	7	,	,	PUNCT
eurjchem-604	1684	8	d.	d.	PROPN
eurjchem-604	1684	9	;	;	PUNCT
eurjchem-604	1684	10	ruiz	ruiz	NOUN
eurjchem-604	1684	11	,	,	PUNCT
eurjchem-604	1684	12	m.	m.	NOUN
eurjchem-604	1684	13	a.	a.	NOUN
eurjchem-604	1684	14	j.	j.	PROPN
eurjchem-604	1684	15	organomet	organomet	PROPN
eurjchem-604	1684	16	.	.	PUNCT
eurjchem-604	1685	1	chem	chem	NOUN
eurjchem-604	1685	2	.	.	PUNCT
eurjchem-604	1686	1	2010	2010	NUM
eurjchem-604	1686	2	,	,	PUNCT
eurjchem-604	1686	3	695(10‐11	695(10‐11	NUM
eurjchem-604	1686	4	)	)	PUNCT
eurjchem-604	1686	5	,	,	PUNCT
eurjchem-604	1686	6	1592‐1597	1592‐1597	NUM
eurjchem-604	1686	7	.	.	PUNCT
eurjchem-604	1687	1	[	[	X
eurjchem-604	1687	2	198	198	NUM
eurjchem-604	1687	3	]	]	PUNCT
eurjchem-604	1687	4	.	.	PUNCT
eurjchem-604	1688	1	zhou	zhou	PROPN
eurjchem-604	1688	2	,	,	PUNCT
eurjchem-604	1688	3	z.	z.	PROPN
eurjchem-604	1688	4	;	;	PUNCT
eurjchem-604	1688	5	zhuang	zhuang	PROPN
eurjchem-604	1688	6	,	,	PUNCT
eurjchem-604	1688	7	b.	b.	PROPN
eurjchem-604	1688	8	;	;	PUNCT
eurjchem-604	1688	9	wu	wu	PROPN
eurjchem-604	1688	10	,	,	PUNCT
eurjchem-604	1688	11	k.	k.	PROPN
eurjchem-604	1688	12	;	;	PUNCT
eurjchem-604	1688	13	liu	liu	PROPN
eurjchem-604	1688	14	,	,	PUNCT
eurjchem-604	1688	15	p.	p.	PROPN
eurjchem-604	1688	16	;	;	PUNCT
eurjchem-604	1688	17	wei	wei	PROPN
eurjchem-604	1688	18	,	,	PUNCT
eurjchem-604	1688	19	y.	y.	PROPN
eurjchem-604	1688	20	;	;	PUNCT
eurjchem-604	1688	21	yao	yao	PROPN
eurjchem-604	1688	22	,	,	PUNCT
eurjchem-604	1688	23	y.	y.	PROPN
eurjchem-604	1688	24	j.	j.	PROPN
eurjchem-604	1688	25	organomet	organomet	PROPN
eurjchem-604	1688	26	.	.	PUNCT
eurjchem-604	1689	1	chem	chem	NOUN
eurjchem-604	1689	2	.	.	PUNCT
eurjchem-604	1690	1	2007	2007	NUM
eurjchem-604	1690	2	,	,	PUNCT
eurjchem-604	1690	3	692(7	692(7	NUM
eurjchem-604	1690	4	)	)	PUNCT
eurjchem-604	1690	5	,	,	PUNCT
eurjchem-604	1690	6	1411‐1420	1411‐1420	X
eurjchem-604	1690	7	.	.	PUNCT
eurjchem-604	1691	1	[	[	X
eurjchem-604	1691	2	199	199	NUM
eurjchem-604	1691	3	]	]	SYM
eurjchem-604	1691	4	.	.	PUNCT
eurjchem-604	1692	1	el‐kadri	el‐kadri	ADJ
eurjchem-604	1692	2	,	,	PUNCT
eurjchem-604	1692	3	o.	o.	NOUN
eurjchem-604	1692	4	m.	m.	NOUN
eurjchem-604	1692	5	;	;	PUNCT
eurjchem-604	1692	6	heeg	heeg	ADV
eurjchem-604	1692	7	,	,	PUNCT
eurjchem-604	1692	8	m.	m.	NOUN
eurjchem-604	1692	9	j.	j.	PROPN
eurjchem-604	1692	10	;	;	PUNCT
eurjchem-604	1692	11	winter	winter	NOUN
eurjchem-604	1692	12	,	,	PUNCT
eurjchem-604	1692	13	c.	c.	PROPN
eurjchem-604	1692	14	h.	h.	PROPN
eurjchem-604	1692	15	j.	j.	PROPN
eurjchem-604	1692	16	organomet	organomet	PROPN
eurjchem-604	1692	17	.	.	PUNCT
eurjchem-604	1693	1	chem	chem	NOUN
eurjchem-604	1693	2	.	.	PUNCT
eurjchem-604	1694	1	2009	2009	NUM
eurjchem-604	1694	2	,	,	PUNCT
eurjchem-604	1694	3	694(24	694(24	NUM
eurjchem-604	1694	4	)	)	PUNCT
eurjchem-604	1694	5	,	,	PUNCT
eurjchem-604	1694	6	3902‐3911	3902‐3911	NUM
eurjchem-604	1694	7	.	.	PUNCT
eurjchem-604	1695	1	[	[	X
eurjchem-604	1695	2	200	200	NUM
eurjchem-604	1695	3	]	]	PUNCT
eurjchem-604	1695	4	.	.	PUNCT
eurjchem-604	1696	1	rodriguez‐palacios	rodriguez‐palacios	PROPN
eurjchem-604	1696	2	,	,	PUNCT
eurjchem-604	1696	3	r.	r.	PROPN
eurjchem-604	1696	4	;	;	PUNCT
eurjchem-604	1696	5	reyes‐lezama	reyes‐lezama	NOUN
eurjchem-604	1696	6	,	,	PUNCT
eurjchem-604	1696	7	m.	m.	NOUN
eurjchem-604	1696	8	;	;	PUNCT
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eurjchem-604	1696	10	,	,	PUNCT
eurjchem-604	1696	11	l.	l.	PROPN
eurjchem-604	1696	12	;	;	PUNCT
eurjchem-604	1696	13	lemus‐santana	lemus‐santana	PROPN
eurjchem-604	1696	14	,	,	PUNCT
eurjchem-604	1696	15	a.	a.	NOUN
eurjchem-604	1696	16	a.	a.	NOUN
eurjchem-604	1696	17	;	;	PUNCT
eurjchem-604	1696	18	sanchez‐guadarrama	sanchez‐guadarrama	PROPN
eurjchem-604	1696	19	,	,	PUNCT
eurjchem-604	1696	20	o.	o.	NOUN
eurjchem-604	1696	21	;	;	PUNCT
eurjchem-604	1696	22	hopfl	hopfl	NOUN
eurjchem-604	1696	23	,	,	PUNCT
eurjchem-604	1696	24	h.	h.	PROPN
eurjchem-604	1696	25	;	;	PUNCT
eurjchem-604	1696	26	zuniga‐	zuniga‐	PROPN
eurjchem-604	1696	27	villarreal	villarreal	NOUN
eurjchem-604	1696	28	,	,	PUNCT
eurjchem-604	1696	29	n.	n.	NOUN
eurjchem-604	1696	30	polyhedron	polyhedron	NOUN
eurjchem-604	1696	31	2010	2010	NUM
eurjchem-604	1696	32	,	,	PUNCT
eurjchem-604	1696	33	29(16	29(16	NUM
eurjchem-604	1696	34	)	)	PUNCT
eurjchem-604	1696	35	,	,	PUNCT
eurjchem-604	1696	36	3103‐3110	3103‐3110	NUM
eurjchem-604	1696	37	.	.	PUNCT
eurjchem-604	1697	1	[	[	X
eurjchem-604	1697	2	201	201	NUM
eurjchem-604	1697	3	]	]	PUNCT
eurjchem-604	1697	4	.	.	PUNCT
eurjchem-604	1698	1	song	song	PROPN
eurjchem-604	1698	2	,	,	PUNCT
eurjchem-604	1698	3	l.	l.	PROPN
eurjchem-604	1698	4	c.	c.	PROPN
eurjchem-604	1698	5	;	;	PUNCT
eurjchem-604	1698	6	li	li	PROPN
eurjchem-604	1698	7	,	,	PUNCT
eurjchem-604	1698	8	q.	q.	PROPN
eurjchem-604	1698	9	s.	s.	PROPN
eurjchem-604	1698	10	;	;	PUNCT
eurjchem-604	1698	11	hu	hu	PROPN
eurjchem-604	1698	12	,	,	PUNCT
eurjchem-604	1698	13	q.	q.	PROPN
eurjchem-604	1698	14	m.	m.	PROPN
eurjchem-604	1698	15	;	;	PUNCT
eurjchem-604	1698	16	dong	dong	PROPN
eurjchem-604	1698	17	,	,	PUNCT
eurjchem-604	1698	18	y.	y.	PROPN
eurjchem-604	1698	19	b.	b.	PROPN
eurjchem-604	1699	1	j.	j.	PROPN
eurjchem-604	1699	2	organomet	organomet	PROPN
eurjchem-604	1699	3	.	.	PUNCT
eurjchem-604	1700	1	chem	chem	NOUN
eurjchem-604	1700	2	.	.	PUNCT
eurjchem-604	1701	1	2001	2001	NUM
eurjchem-604	1701	2	,	,	PUNCT
eurjchem-604	1701	3	619(1‐2	619(1‐2	NUM
eurjchem-604	1701	4	)	)	PUNCT
eurjchem-604	1701	5	,	,	PUNCT
eurjchem-604	1701	6	194‐203	194‐203	NUM
eurjchem-604	1701	7	.	.	PUNCT
eurjchem-604	1702	1	[	[	X
eurjchem-604	1702	2	202	202	NUM
eurjchem-604	1702	3	]	]	PUNCT
eurjchem-604	1702	4	.	.	PUNCT
eurjchem-604	1703	1	zhu	zhu	PROPN
eurjchem-604	1703	2	,	,	PUNCT
eurjchem-604	1703	3	b.	b.	PROPN
eurjchem-604	1703	4	h.	h.	PROPN
eurjchem-604	1703	5	;	;	PUNCT
eurjchem-604	1703	6	yin	yin	PROPN
eurjchem-604	1703	7	,	,	PUNCT
eurjchem-604	1703	8	y.	y.	PROPN
eurjchem-604	1703	9	q.	q.	PROPN
eurjchem-604	1703	10	synth	synth	PROPN
eurjchem-604	1703	11	.	.	PUNCT
eurjchem-604	1704	1	react	react	VERB
eurjchem-604	1704	2	.	.	PUNCT
eurjchem-604	1705	1	inorg	inorg	PROPN
eurjchem-604	1705	2	.	.	PUNCT
eurjchem-604	1706	1	me	i	PRON
eurjchem-604	1706	2	.	.	PUNCT
eurjchem-604	1707	1	2006	2006	NUM
eurjchem-604	1707	2	,	,	PUNCT
eurjchem-604	1707	3	36(4	36(4	NUM
eurjchem-604	1707	4	)	)	PUNCT
eurjchem-604	1707	5	,	,	PUNCT
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eurjchem-604	1707	7	.	.	PUNCT
eurjchem-604	1708	1	[	[	X
eurjchem-604	1708	2	203	203	NUM
eurjchem-604	1708	3	]	]	PUNCT
eurjchem-604	1708	4	.	.	PUNCT
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eurjchem-604	1708	6	,	,	PUNCT
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eurjchem-604	1708	8	;	;	PUNCT
eurjchem-604	1708	9	lin	lin	PROPN
eurjchem-604	1708	10	,	,	PUNCT
eurjchem-604	1708	11	s.	s.	PROPN
eurjchem-604	1708	12	f.	f.	PROPN
eurjchem-604	1708	13	;	;	PUNCT
eurjchem-604	1708	14	guo	guo	PROPN
eurjchem-604	1708	15	,	,	PUNCT
eurjchem-604	1708	16	y.	y.	PROPN
eurjchem-604	1708	17	w.	w.	PROPN
eurjchem-604	1708	18	;	;	PUNCT
eurjchem-604	1708	19	hsu	hsu	PROPN
eurjchem-604	1708	20	,	,	PUNCT
eurjchem-604	1708	21	m.	m.	PROPN
eurjchem-604	1708	22	h.	h.	PROPN
eurjchem-604	1708	23	;	;	PUNCT
eurjchem-604	1708	24	lai	lai	PROPN
eurjchem-604	1708	25	,	,	PUNCT
eurjchem-604	1708	26	y.	y.	PROPN
eurjchem-604	1708	27	w.	w.	PROPN
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eurjchem-604	1708	29	2004	2004	NUM
eurjchem-604	1708	30	,	,	PUNCT
eurjchem-604	1708	31	23(22	23(22	PROPN
eurjchem-604	1708	32	)	)	PUNCT
eurjchem-604	1708	33	,	,	PUNCT
eurjchem-604	1708	34	5182‐5187	5182‐5187	NUM
eurjchem-604	1708	35	.	.	PUNCT
eurjchem-604	1709	1	[	[	X
eurjchem-604	1709	2	204	204	NUM
eurjchem-604	1709	3	]	]	PUNCT
eurjchem-604	1709	4	.	.	PUNCT
eurjchem-604	1710	1	hsu	hsu	PROPN
eurjchem-604	1710	2	,	,	PUNCT
eurjchem-604	1710	3	m.	m.	PROPN
eurjchem-604	1710	4	h.	h.	PROPN
eurjchem-604	1710	5	;	;	PUNCT
eurjchem-604	1710	6	miu	miu	PROPN
eurjchem-604	1710	7	,	,	PUNCT
eurjchem-604	1710	8	c.	c.	PROPN
eurjchem-604	1710	9	y.	y.	PROPN
eurjchem-604	1710	10	;	;	PUNCT
eurjchem-604	1710	11	lin	lin	PROPN
eurjchem-604	1710	12	,	,	PUNCT
eurjchem-604	1710	13	y.	y.	PROPN
eurjchem-604	1710	14	c.	c.	PROPN
eurjchem-604	1710	15	;	;	PUNCT
eurjchem-604	1710	16	shieh	shieh	PROPN
eurjchem-604	1710	17	,	,	PUNCT
eurjchem-604	1710	18	m.	m.	NOUN
eurjchem-604	1710	19	j.	j.	PROPN
eurjchem-604	1710	20	organomet	organomet	PROPN
eurjchem-604	1710	21	.	.	PUNCT
eurjchem-604	1711	1	chem	chem	NOUN
eurjchem-604	1711	2	.	.	PUNCT
eurjchem-604	1712	1	2006	2006	NUM
eurjchem-604	1712	2	,	,	PUNCT
eurjchem-604	1712	3	691(5	691(5	NUM
eurjchem-604	1712	4	)	)	PUNCT
eurjchem-604	1712	5	,	,	PUNCT
eurjchem-604	1712	6	966‐974	966‐974	NUM
eurjchem-604	1712	7	.	.	PUNCT
eurjchem-604	1713	1	[	[	X
eurjchem-604	1713	2	205	205	NUM
eurjchem-604	1713	3	]	]	PUNCT
eurjchem-604	1713	4	.	.	PUNCT
eurjchem-604	1714	1	mathur	mathur	PROPN
eurjchem-604	1714	2	,	,	PUNCT
eurjchem-604	1714	3	p.	p.	PROPN
eurjchem-604	1714	4	;	;	PUNCT
eurjchem-604	1714	5	mukhopadhyay	mukhopadhyay	NOUN
eurjchem-604	1714	6	,	,	PUNCT
eurjchem-604	1714	7	s.	s.	PROPN
eurjchem-604	1714	8	;	;	PUNCT
eurjchem-604	1714	9	ahmed	ahmed	PROPN
eurjchem-604	1714	10	,	,	PUNCT
eurjchem-604	1714	11	m.	m.	NOUN
eurjchem-604	1714	12	o.	o.	PROPN
eurjchem-604	1714	13	;	;	PUNCT
eurjchem-604	1714	14	lahiri	lahiri	PROPN
eurjchem-604	1714	15	,	,	PUNCT
eurjchem-604	1714	16	g.	g.	PROPN
eurjchem-604	1714	17	k.	k.	PROPN
eurjchem-604	1714	18	;	;	PUNCT
eurjchem-604	1714	19	chakraborty	chakraborty	PROPN
eurjchem-604	1714	20	,	,	PUNCT
eurjchem-604	1714	21	s.	s.	PROPN
eurjchem-604	1714	22	;	;	PUNCT
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eurjchem-604	1714	24	,	,	PUNCT
eurjchem-604	1714	25	v.	v.	PROPN
eurjchem-604	1714	26	g.	g.	PROPN
eurjchem-604	1714	27	;	;	PUNCT
eurjchem-604	1714	28	bhadbhade	bhadbhade	NOUN
eurjchem-604	1714	29	,	,	PUNCT
eurjchem-604	1714	30	m.	m.	NOUN
eurjchem-604	1714	31	m.	m.	NOUN
eurjchem-604	1714	32	;	;	PUNCT
eurjchem-604	1714	33	umbarkar	umbarkar	PROPN
eurjchem-604	1714	34	,	,	PUNCT
eurjchem-604	1714	35	s.	s.	PROPN
eurjchem-604	1714	36	b.	b.	PROPN
eurjchem-604	1714	37	j.	j.	PROPN
eurjchem-604	1714	38	organomet	organomet	PROPN
eurjchem-604	1714	39	.	.	PUNCT
eurjchem-604	1715	1	chem	chem	NOUN
eurjchem-604	1715	2	.	.	PUNCT
eurjchem-604	1716	1	2001	2001	NUM
eurjchem-604	1716	2	,	,	PUNCT
eurjchem-604	1716	3	629(1‐2	629(1‐2	NUM
eurjchem-604	1716	4	)	)	PUNCT
eurjchem-604	1716	5	,	,	PUNCT
eurjchem-604	1716	6	160‐164	160‐164	NUM
eurjchem-604	1716	7	.	.	PUNCT
eurjchem-604	1717	1	[	[	X
eurjchem-604	1717	2	206	206	NUM
eurjchem-604	1717	3	]	]	PUNCT
eurjchem-604	1717	4	.	.	PUNCT
eurjchem-604	1717	5	kuhnert	kuhnert	PROPN
eurjchem-604	1717	6	,	,	PUNCT
eurjchem-604	1717	7	j.	j.	PROPN
eurjchem-604	1717	8	;	;	PUNCT
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eurjchem-604	1717	10	,	,	PUNCT
eurjchem-604	1717	11	m.	m.	NOUN
eurjchem-604	1717	12	;	;	PUNCT
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eurjchem-604	1717	14	,	,	PUNCT
eurjchem-604	1717	15	t.	t.	PROPN
eurjchem-604	1717	16	;	;	PUNCT
eurjchem-604	1717	17	walfort	walfort	PROPN
eurjchem-604	1717	18	,	,	PUNCT
eurjchem-604	1717	19	b.	b.	PROPN
eurjchem-604	1717	20	;	;	PUNCT
eurjchem-604	1717	21	stepnicka	stepnicka	PROPN
eurjchem-604	1717	22	,	,	PUNCT
eurjchem-604	1717	23	p.	p.	PROPN
eurjchem-604	1717	24	;	;	PUNCT
eurjchem-604	1717	25	lang	lang	PROPN
eurjchem-604	1717	26	,	,	PUNCT
eurjchem-604	1717	27	h.	h.	PROPN
eurjchem-604	1717	28	j.	j.	PROPN
eurjchem-604	1717	29	organomet	organomet	PROPN
eurjchem-604	1717	30	.	.	PUNCT
eurjchem-604	1718	1	chem	chem	NOUN
eurjchem-604	1718	2	.	.	PUNCT
eurjchem-604	1719	1	2007	2007	NUM
eurjchem-604	1719	2	,	,	PUNCT
eurjchem-604	1719	3	692(20	692(20	NUM
eurjchem-604	1719	4	)	)	PUNCT
eurjchem-604	1719	5	,	,	PUNCT
eurjchem-604	1719	6	4303‐4314	4303‐4314	NOUN
eurjchem-604	1719	7	.	.	PUNCT
eurjchem-604	1720	1	[	[	X
eurjchem-604	1720	2	207	207	NUM
eurjchem-604	1720	3	]	]	PUNCT
eurjchem-604	1720	4	.	.	PUNCT
eurjchem-604	1721	1	blitz	blitz	PROPN
eurjchem-604	1721	2	,	,	PUNCT
eurjchem-604	1721	3	j.	j.	PROPN
eurjchem-604	1721	4	p.	p.	PROPN
eurjchem-604	1721	5	;	;	PUNCT
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eurjchem-604	1721	7	,	,	PUNCT
eurjchem-604	1721	8	n.	n.	PROPN
eurjchem-604	1721	9	t.	t.	PROPN
eurjchem-604	1721	10	;	;	PUNCT
eurjchem-604	1721	11	humphrey	humphrey	PROPN
eurjchem-604	1721	12	,	,	PUNCT
eurjchem-604	1721	13	m.	m.	PROPN
eurjchem-604	1721	14	g.	g.	PROPN
eurjchem-604	1721	15	j.	j.	PROPN
eurjchem-604	1721	16	organomet	organomet	PROPN
eurjchem-604	1721	17	.	.	PUNCT
eurjchem-604	1722	1	chem	chem	NOUN
eurjchem-604	1722	2	.	.	PUNCT
eurjchem-604	1723	1	2002	2002	NUM
eurjchem-604	1723	2	,	,	PUNCT
eurjchem-604	1723	3	650(1‐2	650(1‐2	NOUN
eurjchem-604	1723	4	)	)	PUNCT
eurjchem-604	1723	5	,	,	PUNCT
eurjchem-604	1723	6	133‐140	133‐140	NUM
eurjchem-604	1723	7	.	.	PUNCT
eurjchem-604	1724	1	[	[	X
eurjchem-604	1724	2	208	208	NUM
eurjchem-604	1724	3	]	]	PUNCT
eurjchem-604	1724	4	.	.	PUNCT
eurjchem-604	1725	1	usher	usher	PROPN
eurjchem-604	1725	2	,	,	PUNCT
eurjchem-604	1725	3	a.	a.	PROPN
eurjchem-604	1725	4	j.	j.	PROPN
eurjchem-604	1725	5	;	;	PUNCT
eurjchem-604	1725	6	humphrey	humphrey	PROPN
eurjchem-604	1725	7	,	,	PUNCT
eurjchem-604	1725	8	m.	m.	NOUN
eurjchem-604	1725	9	g.	g.	PROPN
eurjchem-604	1725	10	;	;	PUNCT
eurjchem-604	1725	11	willis	willis	PROPN
eurjchem-604	1725	12	,	,	PUNCT
eurjchem-604	1725	13	a.	a.	PROPN
eurjchem-604	1725	14	c.	c.	PROPN
eurjchem-604	1725	15	j.	j.	PROPN
eurjchem-604	1725	16	organomet	organomet	PROPN
eurjchem-604	1725	17	.	.	PUNCT
eurjchem-604	1726	1	chem	chem	NOUN
eurjchem-604	1726	2	.	.	PUNCT
eurjchem-604	1727	1	2003	2003	NUM
eurjchem-604	1727	2	,	,	PUNCT
eurjchem-604	1727	3	682(1‐2	682(1‐2	NUM
eurjchem-604	1727	4	)	)	PUNCT
eurjchem-604	1727	5	,	,	PUNCT
eurjchem-604	1727	6	41‐48	41‐48	NUM
eurjchem-604	1727	7	.	.	PUNCT
eurjchem-604	1728	1	[	[	X
eurjchem-604	1728	2	209	209	NUM
eurjchem-604	1728	3	]	]	PUNCT
eurjchem-604	1728	4	.	.	PUNCT
eurjchem-604	1729	1	notaras	notaras	PROPN
eurjchem-604	1729	2	,	,	PUNCT
eurjchem-604	1729	3	e.	e.	PROPN
eurjchem-604	1729	4	g.	g.	PROPN
eurjchem-604	1729	5	a.	a.	PROPN
eurjchem-604	1729	6	;	;	PUNCT
eurjchem-604	1729	7	lucas	lucas	PROPN
eurjchem-604	1729	8	,	,	PUNCT
eurjchem-604	1729	9	n.	n.	PROPN
eurjchem-604	1729	10	t.	t.	PROPN
eurjchem-604	1729	11	;	;	PUNCT
eurjchem-604	1729	12	blitz	blitz	PROPN
eurjchem-604	1729	13	,	,	PUNCT
eurjchem-604	1729	14	j.	j.	PROPN
eurjchem-604	1729	15	p.	p.	PROPN
eurjchem-604	1729	16	;	;	PUNCT
eurjchem-604	1729	17	humphrey	humphrey	PROPN
eurjchem-604	1729	18	,	,	PUNCT
eurjchem-604	1729	19	m.	m.	PROPN
eurjchem-604	1729	20	g.	g.	PROPN
eurjchem-604	1729	21	j.	j.	PROPN
eurjchem-604	1729	22	organomet	organomet	PROPN
eurjchem-604	1729	23	.	.	PUNCT
eurjchem-604	1730	1	chem	chem	NOUN
eurjchem-604	1730	2	.	.	PUNCT
eurjchem-604	1731	1	2001	2001	NUM
eurjchem-604	1731	2	,	,	PUNCT
eurjchem-604	1731	3	631(1‐2	631(1‐2	NUM
eurjchem-604	1731	4	)	)	PUNCT
eurjchem-604	1731	5	,	,	PUNCT
eurjchem-604	1731	6	143‐150	143‐150	PROPN
eurjchem-604	1731	7	.	.	PUNCT
eurjchem-604	1732	1	[	[	X
eurjchem-604	1732	2	210	210	NUM
eurjchem-604	1732	3	]	]	PUNCT
eurjchem-604	1732	4	.	.	PUNCT
eurjchem-604	1733	1	brenner	brenner	PROPN
eurjchem-604	1733	2	,	,	PUNCT
eurjchem-604	1733	3	e.	e.	PROPN
eurjchem-604	1733	4	;	;	PUNCT
eurjchem-604	1733	5	chetcuti	chetcuti	PROPN
eurjchem-604	1733	6	,	,	PUNCT
eurjchem-604	1733	7	m.	m.	PROPN
eurjchem-604	1733	8	j.	j.	PROPN
eurjchem-604	1733	9	;	;	PUNCT
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eurjchem-604	1733	11	,	,	PUNCT
eurjchem-604	1733	12	i.	i.	NOUN
eurjchem-604	1733	13	;	;	PUNCT
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eurjchem-604	1733	15	,	,	PUNCT
eurjchem-604	1733	16	r.	r.	PROPN
eurjchem-604	1733	17	j.	j.	PROPN
eurjchem-604	1733	18	organomet	organomet	PROPN
eurjchem-604	1733	19	.	.	PUNCT
eurjchem-604	1734	1	chem	chem	NOUN
eurjchem-604	1734	2	.	.	PUNCT
eurjchem-604	1735	1	2007	2007	NUM
eurjchem-604	1735	2	,	,	PUNCT
eurjchem-604	1735	3	692(22	692(22	NUM
eurjchem-604	1735	4	)	)	PUNCT
eurjchem-604	1735	5	,	,	PUNCT
eurjchem-604	1735	6	5097‐5102	5097‐5102	NUM
eurjchem-604	1735	7	.	.	PUNCT
eurjchem-604	1736	1	[	[	X
eurjchem-604	1736	2	211	211	NUM
eurjchem-604	1736	3	]	]	PUNCT
eurjchem-604	1736	4	.	.	PUNCT
eurjchem-604	1737	1	lang	lang	PROPN
eurjchem-604	1737	2	,	,	PUNCT
eurjchem-604	1737	3	h.	h.	PROPN
eurjchem-604	1737	4	;	;	PUNCT
eurjchem-604	1737	5	luhmann	luhmann	PROPN
eurjchem-604	1737	6	,	,	PUNCT
eurjchem-604	1737	7	b.	b.	PROPN
eurjchem-604	1737	8	;	;	PUNCT
eurjchem-604	1737	9	buschbeck	buschbeck	PROPN
eurjchem-604	1737	10	,	,	PUNCT
eurjchem-604	1737	11	r.	r.	PROPN
eurjchem-604	1737	12	j.	j.	PROPN
eurjchem-604	1737	13	organomet	organomet	PROPN
eurjchem-604	1737	14	.	.	PUNCT
eurjchem-604	1738	1	chem	chem	NOUN
eurjchem-604	1738	2	.	.	PUNCT
eurjchem-604	1739	1	2004	2004	NUM
eurjchem-604	1739	2	,	,	PUNCT
eurjchem-604	1739	3	689(22	689(22	NUM
eurjchem-604	1739	4	)	)	PUNCT
eurjchem-604	1739	5	,	,	PUNCT
eurjchem-604	1739	6	3598‐3603	3598‐3603	NUM
eurjchem-604	1739	7	.	.	PUNCT
eurjchem-604	1740	1	[	[	X
eurjchem-604	1740	2	212	212	NUM
eurjchem-604	1740	3	]	]	PUNCT
eurjchem-604	1740	4	.	.	PUNCT
eurjchem-604	1741	1	wade	wade	PROPN
eurjchem-604	1741	2	,	,	PUNCT
eurjchem-604	1741	3	k.	k.	PROPN
eurjchem-604	1741	4	adv	adv	PROPN
eurjchem-604	1741	5	.	.	PUNCT
eurjchem-604	1741	6	inorg	inorg	PROPN
eurjchem-604	1741	7	.	.	PUNCT
eurjchem-604	1742	1	chem	chem	PROPN
eurjchem-604	1742	2	.	.	PUNCT
eurjchem-604	1743	1	radiochem	radiochem	PROPN
eurjchem-604	1743	2	.	.	PUNCT
eurjchem-604	1744	1	1976	1976	NUM
eurjchem-604	1744	2	,	,	PUNCT
eurjchem-604	1744	3	18	18	NUM
eurjchem-604	1744	4	,	,	PUNCT
eurjchem-604	1744	5	1‐66	1‐66	NUM
eurjchem-604	1744	6	.	.	PUNCT
eurjchem-604	1745	1	[	[	X
eurjchem-604	1745	2	213	213	NUM
eurjchem-604	1745	3	]	]	PUNCT
eurjchem-604	1745	4	.	.	PUNCT
eurjchem-604	1746	1	girolami	girolami	PROPN
eurjchem-604	1746	2	,	,	PUNCT
eurjchem-604	1746	3	g.	g.	PROPN
eurjchem-604	1746	4	;	;	PUNCT
eurjchem-604	1746	5	lecture	lecture	NOUN
eurjchem-604	1746	6	notes	note	NOUN
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eurjchem-604	1746	10	university	university	PROPN
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eurjchem-604	1746	12	illinois	illinois	PROPN
eurjchem-604	1746	13	,	,	PUNCT
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eurjchem-604	1746	15	.	.	PUNCT
eurjchem-604	1747	1	these	these	DET
eurjchem-604	1747	2	notes	note	NOUN
eurjchem-604	1747	3	contained	contain	VERB
eurjchem-604	1747	4	original	original	ADJ
eurjchem-604	1747	5	material	material	NOUN
eurjchem-604	1747	6	that	that	PRON
eurjchem-604	1747	7	served	serve	VERB
eurjchem-604	1747	8	as	as	ADP
eurjchem-604	1747	9	the	the	DET
eurjchem-604	1747	10	basis	basis	NOUN
eurjchem-604	1747	11	of	of	ADP
eurjchem-604	1747	12	the	the	DET
eurjchem-604	1747	13	sections	section	NOUN
eurjchem-604	1747	14	on	on	ADP
eurjchem-604	1747	15	the	the	DET
eurjchem-604	1747	16	4n	4n	NOUN
eurjchem-604	1747	17	,	,	PUNCT
eurjchem-604	1747	18	5n	5n	NUM
eurjchem-604	1747	19	,	,	PUNCT
eurjchem-604	1747	20	and	and	CCONJ
eurjchem-604	1747	21	6n	6n	NUM
eurjchem-604	1747	22	rules	rule	NOUN
eurjchem-604	1747	23	,	,	PUNCT
eurjchem-604	1747	24	2008	2008	NUM
eurjchem-604	1747	25	.	.	PUNCT
eurjchem-604	1748	1	[	[	X
eurjchem-604	1748	2	214	214	NUM
eurjchem-604	1748	3	]	]	PUNCT
eurjchem-604	1748	4	.	.	PUNCT
eurjchem-604	1749	1	gilespie	gilespie	PROPN
eurjchem-604	1749	2	,	,	PUNCT
eurjchem-604	1749	3	r.	r.	PROPN
eurjchem-604	1749	4	j.	j.	PROPN
eurjchem-604	1749	5	chem	chem	PROPN
eurjchem-604	1749	6	.	.	PUNCT
eurjchem-604	1750	1	soc	soc	PROPN
eurjchem-604	1750	2	.	.	PUNCT
eurjchem-604	1751	1	rev	rev	PROPN
eurjchem-604	1751	2	.	.	PROPN
eurjchem-604	1751	3	1979	1979	NUM
eurjchem-604	1751	4	,	,	PUNCT
eurjchem-604	1751	5	8(3	8(3	NUM
eurjchem-604	1751	6	)	)	PUNCT
eurjchem-604	1751	7	,	,	PUNCT
eurjchem-604	1751	8	315‐352	315‐352	NUM
eurjchem-604	1751	9	.	.	PUNCT
eurjchem-604	1752	1	[	[	X
eurjchem-604	1752	2	215	215	NUM
eurjchem-604	1752	3	]	]	PUNCT
eurjchem-604	1752	4	.	.	PUNCT
eurjchem-604	1752	5	mingos	mingos	PROPN
eurjchem-604	1752	6	,	,	PUNCT
eurjchem-604	1752	7	d.	d.	PROPN
eurjchem-604	1752	8	m.	m.	PROPN
eurjchem-604	1752	9	p.	p.	PROPN
eurjchem-604	1752	10	accounts	account	VERB
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eurjchem-604	1752	12	.	.	PUNCT
eurjchem-604	1753	1	res	re	NOUN
eurjchem-604	1753	2	.	.	PROPN
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eurjchem-604	1753	4	,	,	PUNCT
eurjchem-604	1753	5	17(9	17(9	NOUN
eurjchem-604	1753	6	)	)	PUNCT
eurjchem-604	1753	7	,	,	PUNCT
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eurjchem-604	1753	9	.	.	PUNCT
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eurjchem-604	1754	2	216	216	NUM
eurjchem-604	1754	3	]	]	PUNCT
eurjchem-604	1754	4	.	.	PUNCT
eurjchem-604	1754	5	jemmis	jemmis	PROPN
eurjchem-604	1754	6	,	,	PUNCT
eurjchem-604	1754	7	e.	e.	PROPN
eurjchem-604	1754	8	d.	d.	PROPN
eurjchem-604	1754	9	;	;	PUNCT
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eurjchem-604	1754	11	,	,	PUNCT
eurjchem-604	1754	12	m.	m.	NOUN
eurjchem-604	1754	13	m.	m.	NOUN
eurjchem-604	1754	14	;	;	PUNCT
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eurjchem-604	1754	16	,	,	PUNCT
eurjchem-604	1754	17	p.	p.	PROPN
eurjchem-604	1754	18	d.	d.	PROPN
eurjchem-604	1755	1	j.	j.	PROPN
eurjchem-604	1755	2	am	am	PROPN
eurjchem-604	1755	3	.	.	PUNCT
eurjchem-604	1756	1	chem	chem	PROPN
eurjchem-604	1756	2	.	.	PUNCT
eurjchem-604	1757	1	soc	soc	PROPN
eurjchem-604	1757	2	.	.	PUNCT
eurjchem-604	1758	1	2001	2001	NUM
eurjchem-604	1758	2	,	,	PUNCT
eurjchem-604	1758	3	123(18	123(18	NUM
eurjchem-604	1758	4	)	)	PUNCT
eurjchem-604	1758	5	,	,	PUNCT
eurjchem-604	1758	6	4313‐4323	4313‐4323	NOUN
eurjchem-604	1758	7	.	.	PUNCT
eurjchem-604	1759	1	[	[	X
eurjchem-604	1759	2	217	217	NUM
eurjchem-604	1759	3	]	]	PUNCT
eurjchem-604	1759	4	.	.	PUNCT
eurjchem-604	1759	5	jemmis	jemmis	PROPN
eurjchem-604	1759	6	,	,	PUNCT
eurjchem-604	1759	7	e.	e.	PROPN
eurjchem-604	1759	8	d.	d.	PROPN
eurjchem-604	1759	9	;	;	PUNCT
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eurjchem-604	1759	11	,	,	PUNCT
eurjchem-604	1759	12	m.	m.	NOUN
eurjchem-604	1759	13	m.	m.	NOUN
eurjchem-604	1759	14	;	;	PUNCT
eurjchem-604	1759	15	pancharatna	pancharatna	PROPN
eurjchem-604	1759	16	,	,	PUNCT
eurjchem-604	1759	17	p.	p.	PROPN
eurjchem-604	1759	18	d.	d.	PROPN
eurjchem-604	1759	19	chem	chem	PROPN
eurjchem-604	1759	20	.	.	PUNCT
eurjchem-604	1760	1	rev	rev	PROPN
eurjchem-604	1760	2	.	.	PROPN
eurjchem-604	1760	3	2002	2002	NUM
eurjchem-604	1760	4	,	,	PUNCT
eurjchem-604	1760	5	102(1	102(1	NUM
eurjchem-604	1760	6	)	)	PUNCT
eurjchem-604	1760	7	,	,	PUNCT
eurjchem-604	1760	8	93‐144	93‐144	NUM
eurjchem-604	1760	9	.	.	PUNCT
eurjchem-604	1761	1	[	[	X
eurjchem-604	1761	2	218	218	NUM
eurjchem-604	1761	3	]	]	PUNCT
eurjchem-604	1761	4	.	.	PUNCT
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eurjchem-604	1762	2	,	,	PUNCT
eurjchem-604	1762	3	f.	f.	PROPN
eurjchem-604	1762	4	a.	a.	PROPN
eurjchem-604	1762	5	;	;	PUNCT
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eurjchem-604	1762	7	,	,	PUNCT
eurjchem-604	1762	8	g.	g.	PROPN
eurjchem-604	1762	9	;	;	PUNCT
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eurjchem-604	1762	11	,	,	PUNCT
eurjchem-604	1762	12	c.	c.	PROPN
eurjchem-604	1762	13	a.	a.	PROPN
eurjchem-604	1762	14	;	;	PUNCT
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eurjchem-604	1762	16	,	,	PUNCT
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eurjchem-604	1762	19	inorganic	inorganic	ADJ
eurjchem-604	1762	20	chemistry	chemistry	NOUN
eurjchem-604	1762	21	,	,	PUNCT
eurjchem-604	1762	22	6thed	6thed	NUM
eurjchem-604	1762	23	.	.	PUNCT
eurjchem-604	1762	24	,	,	PUNCT
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eurjchem-604	1762	31	.	.	PUNCT
eurjchem-604	1763	1	[	[	X
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eurjchem-604	1763	3	]	]	PUNCT
eurjchem-604	1763	4	.	.	PUNCT
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eurjchem-604	1764	2	,	,	PUNCT
eurjchem-604	1764	3	s.	s.	PROPN
eurjchem-604	1764	4	;	;	PUNCT
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eurjchem-604	1764	6	,	,	PUNCT
eurjchem-604	1764	7	j.	j.	PROPN
eurjchem-604	1764	8	;	;	PUNCT
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eurjchem-604	1764	10	,	,	PUNCT
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eurjchem-604	1764	13	.	.	PUNCT
eurjchem-604	1765	1	rev	rev	PROPN
eurjchem-604	1765	2	.	.	PROPN
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eurjchem-604	1765	4	state2006	state2006	PROPN
eurjchem-604	1765	5	,	,	PUNCT
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eurjchem-604	1765	7	)	)	PUNCT
eurjchem-604	1765	8	,	,	PUNCT
eurjchem-604	1765	9	55‐57	55‐57	NUM
eurjchem-604	1765	10	.	.	PUNCT
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eurjchem-604	1766	2	220	220	NUM
eurjchem-604	1766	3	]	]	PUNCT
eurjchem-604	1766	4	.	.	PUNCT
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eurjchem-604	1767	2	,	,	PUNCT
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eurjchem-604	1767	4	;	;	PUNCT
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eurjchem-604	1767	6	,	,	PUNCT
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eurjchem-604	1767	8	;	;	PUNCT
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eurjchem-604	1767	10	,	,	PUNCT
eurjchem-604	1767	11	j.	j.	PROPN
eurjchem-604	1767	12	w.	w.	PROPN
eurjchem-604	1767	13	y.	y.	PROPN
eurjchem-604	1767	14	;	;	PUNCT
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eurjchem-604	1767	36	k.	k.	PROPN
eurjchem-604	1767	37	l.	l.	PROPN
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eurjchem-604	1768	1	s.	s.	PROPN
eurjchem-604	1768	2	;	;	PUNCT
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eurjchem-604	1768	4	,	,	PUNCT
eurjchem-604	1768	5	b.	b.	PROPN
eurjchem-604	1768	6	z.	z.	PROPN
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eurjchem-604	1768	8	,	,	PUNCT
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eurjchem-604	1768	10	)	)	PUNCT
eurjchem-604	1768	11	,	,	PUNCT
eurjchem-604	1768	12	6918‐6924	6918‐6924	NUM
eurjchem-604	1768	13	.	.	PUNCT
eurjchem-604	1769	1	[	[	X
eurjchem-604	1769	2	221	221	NUM
eurjchem-604	1769	3	]	]	PUNCT
eurjchem-604	1769	4	.	.	PUNCT
eurjchem-604	1770	1	dunne	dunne	PROPN
eurjchem-604	1770	2	,	,	PUNCT
eurjchem-604	1770	3	t.	t.	PROPN
eurjchem-604	1770	4	g.	g.	PROPN
eurjchem-604	1770	5	;	;	PUNCT
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eurjchem-604	1770	7	,	,	PUNCT
eurjchem-604	1770	8	f.	f.	PROPN
eurjchem-604	1770	9	a.	a.	NOUN
eurjchem-604	1770	10	inorg	inorg	PROPN
eurjchem-604	1770	11	.	.	PUNCT
eurjchem-604	1771	1	chem	chem	PROPN
eurjchem-604	1771	2	.	.	PUNCT
eurjchem-604	1772	1	1963	1963	NUM
eurjchem-604	1772	2	,	,	PUNCT
eurjchem-604	1772	3	2(2	2(2	NUM
eurjchem-604	1772	4	)	)	PUNCT
eurjchem-604	1772	5	,	,	PUNCT
eurjchem-604	1772	6	263‐266	263‐266	NUM
eurjchem-604	1772	7	.	.	PUNCT
eurjchem-604	1773	1	[	[	X
eurjchem-604	1773	2	222	222	NUM
eurjchem-604	1773	3	]	]	PUNCT
eurjchem-604	1773	4	.	.	PUNCT
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eurjchem-604	1774	2	,	,	PUNCT
eurjchem-604	1774	3	m.	m.	NOUN
eurjchem-604	1774	4	y.	y.	PROPN
eurjchem-604	1774	5	;	;	PUNCT
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eurjchem-604	1774	7	,	,	PUNCT
eurjchem-604	1774	8	h.	h.	PROPN
eurjchem-604	1774	9	l.	l.	PROPN
eurjchem-604	1774	10	;	;	PUNCT
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eurjchem-604	1774	12	,	,	PUNCT
eurjchem-604	1774	13	d.	d.	PROPN
eurjchem-604	1774	14	j.	j.	PROPN
eurjchem-604	1774	15	;	;	PUNCT
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eurjchem-604	1774	17	,	,	PUNCT
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eurjchem-604	1774	19	j.	j.	PROPN
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eurjchem-604	1774	21	.	.	PUNCT
eurjchem-604	1775	1	chem	chem	PROPN
eurjchem-604	1775	2	.	.	PUNCT
eurjchem-604	1776	1	soc	soc	PROPN
eurjchem-604	1776	2	.	.	PUNCT
eurjchem-604	1777	1	1973	1973	NUM
eurjchem-604	1777	2	,	,	PUNCT
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eurjchem-604	1777	4	,	,	PUNCT
eurjchem-604	1777	5	5919‐5924	5919‐5924	NUM
eurjchem-604	1777	6	.	.	PUNCT
eurjchem-604	1778	1	[	[	X
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eurjchem-604	1778	3	]	]	PUNCT
eurjchem-604	1778	4	.	.	PUNCT
eurjchem-604	1779	1	darensbourg	darensbourg	PROPN
eurjchem-604	1779	2	,	,	PUNCT
eurjchem-604	1779	3	d.	d.	PROPN
eurjchem-604	1779	4	j.	j.	PROPN
eurjchem-604	1779	5	;	;	PUNCT
eurjchem-604	1779	6	darensbourg	darensbourg	PROPN
eurjchem-604	1779	7	,	,	PUNCT
eurjchem-604	1779	8	m.	m.	NOUN
eurjchem-604	1779	9	y.	y.	PROPN
eurjchem-604	1779	10	inorg	inorg	PROPN
eurjchem-604	1779	11	.	.	PUNCT
eurjchem-604	1780	1	chem	chem	PROPN
eurjchem-604	1780	2	.	.	PUNCT
eurjchem-604	1781	1	1970	1970	NUM
eurjchem-604	1781	2	,	,	PUNCT
eurjchem-604	1781	3	9(7	9(7	NUM
eurjchem-604	1781	4	)	)	PUNCT
eurjchem-604	1781	5	,	,	PUNCT
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eurjchem-604	1781	7	.	.	PUNCT
eurjchem-604	1782	1	[	[	X
eurjchem-604	1782	2	224	224	NUM
eurjchem-604	1782	3	]	]	PUNCT
eurjchem-604	1782	4	.	.	PUNCT
eurjchem-604	1783	1	fischer	fischer	PROPN
eurjchem-604	1783	2	,	,	PUNCT
eurjchem-604	1783	3	e.	e.	PROPN
eurjchem-604	1783	4	o.	o.	PROPN
eurjchem-604	1783	5	;	;	PUNCT
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eurjchem-604	1783	7	,	,	PUNCT
eurjchem-604	1783	8	a.	a.	PROPN
eurjchem-604	1783	9	angew	angew	PROPN
eurjchem-604	1783	10	.	.	PUNCT
eurjchem-604	1784	1	chem	chem	PROPN
eurjchem-604	1784	2	.	.	PUNCT
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eurjchem-604	1785	2	.	.	PUNCT
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eurjchem-604	1786	2	.	.	PROPN
eurjchem-604	1786	3	,	,	PUNCT
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eurjchem-604	1786	5	.	.	PROPN
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eurjchem-604	1786	7	,	,	PUNCT
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eurjchem-604	1786	9	,	,	PUNCT
eurjchem-604	1786	10	580‐	580‐	NUM
eurjchem-604	1786	11	581	581	NUM
eurjchem-604	1786	12	.	.	PUNCT
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eurjchem-604	1787	3	]	]	SYM
eurjchem-604	1787	4	.	.	PUNCT
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eurjchem-604	1788	2	,	,	PUNCT
eurjchem-604	1788	3	e.	e.	PROPN
eurjchem-604	1788	4	o.	o.	PROPN
eurjchem-604	1788	5	;	;	PUNCT
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eurjchem-604	1788	7	,	,	PUNCT
eurjchem-604	1788	8	v.	v.	CCONJ
eurjchem-604	1788	9	j.	j.	PROPN
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eurjchem-604	1788	11	.	.	PUNCT
eurjchem-604	1789	1	chem	chem	NOUN
eurjchem-604	1789	2	.	.	PUNCT
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eurjchem-604	1790	2	,	,	PUNCT
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eurjchem-604	1790	5	,	,	PUNCT
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eurjchem-604	1790	7	.	.	PUNCT
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eurjchem-604	1791	3	]	]	PUNCT
eurjchem-604	1791	4	.	.	PUNCT
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eurjchem-604	1792	2	,	,	PUNCT
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eurjchem-604	1792	4	m.	m.	PROPN
eurjchem-604	1792	5	;	;	PUNCT
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eurjchem-604	1792	7	,	,	PUNCT
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eurjchem-604	1792	9	j.	j.	PROPN
eurjchem-604	1792	10	am	am	PROPN
eurjchem-604	1792	11	.	.	PUNCT
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eurjchem-604	1793	2	.	.	PUNCT
eurjchem-604	1794	1	soc	soc	PROPN
eurjchem-604	1794	2	.	.	PUNCT
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eurjchem-604	1795	2	,	,	PUNCT
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eurjchem-604	1795	4	,	,	PUNCT
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eurjchem-604	1795	6	.	.	PUNCT
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eurjchem-604	1796	3	]	]	PUNCT
eurjchem-604	1796	4	.	.	PUNCT
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eurjchem-604	1797	2	,	,	PUNCT
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eurjchem-604	1797	4	;	;	PUNCT
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eurjchem-604	1797	6	,	,	PUNCT
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eurjchem-604	1797	8	a.	a.	PROPN
eurjchem-604	1797	9	;	;	PUNCT
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eurjchem-604	1797	11	,	,	PUNCT
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eurjchem-604	1797	13	j.	j.	PROPN
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eurjchem-604	1797	15	.	.	PUNCT
eurjchem-604	1798	1	soc	soc	PROPN
eurjchem-604	1798	2	.	.	PUNCT
eurjchem-604	1799	1	1959	1959	NUM
eurjchem-604	1799	2	,	,	PUNCT
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eurjchem-604	1799	4	.	.	PUNCT
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eurjchem-604	1800	3	]	]	PUNCT
eurjchem-604	1800	4	.	.	PUNCT
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eurjchem-604	1800	6	,	,	PUNCT
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eurjchem-604	1800	10	j.	j.	PROPN
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eurjchem-604	1800	12	.	.	PUNCT
eurjchem-604	1801	1	soc	soc	PROPN
eurjchem-604	1801	2	.	.	PUNCT
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eurjchem-604	1802	2	,	,	PUNCT
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eurjchem-604	1802	4	.	.	PUNCT
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eurjchem-604	1803	3	]	]	PUNCT
eurjchem-604	1803	4	.	.	PUNCT
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eurjchem-604	1804	2	,	,	PUNCT
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eurjchem-604	1804	5	;	;	PUNCT
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eurjchem-604	1804	7	,	,	PUNCT
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eurjchem-604	1804	9	m.	m.	NOUN
eurjchem-604	1804	10	;	;	PUNCT
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eurjchem-604	1804	12	,	,	PUNCT
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eurjchem-604	1804	14	;	;	PUNCT
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eurjchem-604	1804	16	,	,	PUNCT
eurjchem-604	1804	17	c.	c.	PROPN
eurjchem-604	1804	18	c.	c.	PROPN
eurjchem-604	1804	19	;	;	PUNCT
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eurjchem-604	1804	21	,	,	PUNCT
eurjchem-604	1804	22	b.	b.	PROPN
eurjchem-604	1804	23	inorg	inorg	PROPN
eurjchem-604	1804	24	.	.	PUNCT
eurjchem-604	1805	1	chim	chim	PROPN
eurjchem-604	1805	2	.	.	PUNCT
eurjchem-604	1806	1	acta	acta	PROPN
eurjchem-604	1806	2	2008	2008	NUM
eurjchem-604	1806	3	,	,	PUNCT
eurjchem-604	1806	4	361(7	361(7	NUM
eurjchem-604	1806	5	)	)	PUNCT
eurjchem-604	1806	6	,	,	PUNCT
eurjchem-604	1806	7	1915‐1921	1915‐1921	NUM
eurjchem-604	1806	8	.	.	PUNCT
eurjchem-604	1807	1	[	[	X
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eurjchem-604	1807	3	]	]	PUNCT
eurjchem-604	1807	4	.	.	PUNCT
eurjchem-604	1808	1	buzar	buzar	PROPN
eurjchem-604	1808	2	,	,	PUNCT
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eurjchem-604	1808	4	s.	s.	PROPN
eurjchem-604	1808	5	coord	coord	PROPN
eurjchem-604	1808	6	.	.	PUNCT
eurjchem-604	1809	1	chem	chem	PROPN
eurjchem-604	1809	2	.	.	PUNCT
eurjchem-604	1810	1	rev	rev	PROPN
eurjchem-604	1810	2	.	.	PROPN
eurjchem-604	1810	3	2006	2006	NUM
eurjchem-604	1810	4	,	,	PUNCT
eurjchem-604	1810	5	250(9‐10	250(9‐10	NOUN
eurjchem-604	1810	6	)	)	PUNCT
eurjchem-604	1810	7	,	,	PUNCT
eurjchem-604	1810	8	976‐990	976‐990	NUM
eurjchem-604	1810	9	.	.	PUNCT
eurjchem-604	1811	1	[	[	X
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eurjchem-604	1811	3	]	]	PUNCT
eurjchem-604	1811	4	.	.	PUNCT
eurjchem-604	1812	1	adams	adams	PROPN
eurjchem-604	1812	2	,	,	PUNCT
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eurjchem-604	1812	4	d.	d.	PROPN
eurjchem-604	1812	5	;	;	PUNCT
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eurjchem-604	1812	7	,	,	PUNCT
eurjchem-604	1812	8	k.	k.	PROPN
eurjchem-604	1812	9	m.	m.	PROPN
eurjchem-604	1812	10	;	;	PUNCT
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eurjchem-604	1812	12	,	,	PUNCT
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eurjchem-604	1812	14	s.	s.	PROPN
eurjchem-604	1812	15	j.	j.	PROPN
eurjchem-604	1812	16	organomet	organomet	PROPN
eurjchem-604	1812	17	.	.	PUNCT
eurjchem-604	1813	1	chem	chem	NOUN
eurjchem-604	1813	2	.	.	PUNCT
eurjchem-604	1814	1	2002	2002	NUM
eurjchem-604	1814	2	,	,	PUNCT
eurjchem-604	1814	3	652(1‐2	652(1‐2	NUM
eurjchem-604	1814	4	)	)	PUNCT
eurjchem-604	1814	5	,	,	PUNCT
eurjchem-604	1814	6	51‐59	51‐59	NUM
eurjchem-604	1814	7	.	.	PUNCT
eurjchem-604	1815	1	[	[	X
eurjchem-604	1815	2	232	232	NUM
eurjchem-604	1815	3	]	]	PUNCT
eurjchem-604	1815	4	.	.	PUNCT
eurjchem-604	1816	1	wang	wang	PROPN
eurjchem-604	1816	2	,	,	PUNCT
eurjchem-604	1816	3	z.	z.	PROPN
eurjchem-604	1816	4	;	;	PUNCT
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eurjchem-604	1816	6	,	,	PUNCT
eurjchem-604	1816	7	c.	c.	PROPN
eurjchem-604	1816	8	w.	w.	PROPN
eurjchem-604	1816	9	;	;	PUNCT
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eurjchem-604	1816	11	,	,	PUNCT
eurjchem-604	1816	12	s.	s.	PROPN
eurjchem-604	1816	13	;	;	PUNCT
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eurjchem-604	1816	15	,	,	PUNCT
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eurjchem-604	1816	17	s.	s.	PROPN
eurjchem-604	1816	18	a.	a.	PROPN
eurjchem-604	1816	19	;	;	PUNCT
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eurjchem-604	1816	21	,	,	PUNCT
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eurjchem-604	1816	23	appl	appl	PROPN
eurjchem-604	1816	24	.	.	PUNCT
eurjchem-604	1817	1	catal	catal	PROPN
eurjchem-604	1817	2	.	.	PUNCT
eurjchem-604	1818	1	a	a	DET
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eurjchem-604	1818	3	.	.	PROPN
eurjchem-604	1818	4	2011	2011	NUM
eurjchem-604	1818	5	,	,	PUNCT
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eurjchem-604	1818	7	)	)	PUNCT
eurjchem-604	1818	8	,	,	PUNCT
eurjchem-604	1818	9	269‐274	269‐274	NUM
eurjchem-604	1818	10	.	.	PUNCT
eurjchem-604	1819	1	[	[	X
eurjchem-604	1819	2	233	233	NUM
eurjchem-604	1819	3	]	]	PUNCT
eurjchem-604	1819	4	.	.	PUNCT
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eurjchem-604	1820	2	,	,	PUNCT
eurjchem-604	1820	3	q.	q.	PROPN
eurjchem-604	1820	4	;	;	PUNCT
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eurjchem-604	1820	6	,	,	PUNCT
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eurjchem-604	1820	9	.	.	PUNCT
eurjchem-604	1821	1	surf	surf	PROPN
eurjchem-604	1821	2	.	.	PUNCT
eurjchem-604	1822	1	sci	sci	PROPN
eurjchem-604	1822	2	.	.	PUNCT
eurjchem-604	1822	3	catal	catal	PROPN
eurjchem-604	1822	4	.	.	PUNCT
eurjchem-604	1823	1	2003	2003	NUM
eurjchem-604	1823	2	,	,	PUNCT
eurjchem-604	1823	3	145	145	NUM
eurjchem-604	1823	4	,	,	PUNCT
eurjchem-604	1823	5	215‐218	215‐218	NUM
eurjchem-604	1823	6	.	.	PUNCT
eurjchem-604	1824	1	[	[	X
eurjchem-604	1824	2	234	234	NUM
eurjchem-604	1824	3	]	]	PUNCT
eurjchem-604	1824	4	.	.	PUNCT
eurjchem-604	1825	1	xu	xu	PROPN
eurjchem-604	1825	2	,	,	PUNCT
eurjchem-604	1825	3	q.	q.	PROPN
eurjchem-604	1825	4	coord	coord	PROPN
eurjchem-604	1825	5	.	.	PUNCT
eurjchem-604	1826	1	chem	chem	PROPN
eurjchem-604	1826	2	.	.	PUNCT
eurjchem-604	1827	1	rev	rev	PROPN
eurjchem-604	1827	2	.	.	PROPN
eurjchem-604	1827	3	2002	2002	NUM
eurjchem-604	1827	4	,	,	PUNCT
eurjchem-604	1827	5	231(1‐2	231(1‐2	NUM
eurjchem-604	1827	6	)	)	PUNCT
eurjchem-604	1827	7	,	,	PUNCT
eurjchem-604	1827	8	83‐108	83‐108	NUM
eurjchem-604	1827	9	.	.	PUNCT
eurjchem-604	1828	1	[	[	X
eurjchem-604	1828	2	235	235	NUM
eurjchem-604	1828	3	]	]	PUNCT
eurjchem-604	1828	4	.	.	PUNCT
eurjchem-604	1829	1	brait	brait	PROPN
eurjchem-604	1829	2	,	,	PUNCT
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eurjchem-604	1829	4	;	;	PUNCT
eurjchem-604	1829	5	deabate	deabate	NOUN
eurjchem-604	1829	6	,	,	PUNCT
eurjchem-604	1829	7	s.	s.	PROPN
eurjchem-604	1829	8	;	;	PUNCT
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eurjchem-604	1829	10	,	,	PUNCT
eurjchem-604	1829	11	s.	s.	PROPN
eurjchem-604	1829	12	a.	a.	PROPN
eurjchem-604	1829	13	r.	r.	PROPN
eurjchem-604	1829	14	;	;	PUNCT
eurjchem-604	1829	15	sappa	sappa	PROPN
eurjchem-604	1829	16	,	,	PUNCT
eurjchem-604	1829	17	e.	e.	PROPN
eurjchem-604	1829	18	j.	j.	PROPN
eurjchem-604	1829	19	cluster	cluster	PROPN
eurjchem-604	1829	20	sci	sci	PROPN
eurjchem-604	1829	21	.	.	PROPN
eurjchem-604	1829	22	2001	2001	NUM
eurjchem-604	1829	23	,	,	PUNCT
eurjchem-604	1829	24	12(1	12(1	NUM
eurjchem-604	1829	25	)	)	PUNCT
eurjchem-604	1829	26	,	,	PUNCT
eurjchem-604	1829	27	139‐173	139‐173	NUM
eurjchem-604	1829	28	.	.	PUNCT
eurjchem-604	1830	1	[	[	X
eurjchem-604	1830	2	236	236	NUM
eurjchem-604	1830	3	]	]	PUNCT
eurjchem-604	1830	4	.	.	PUNCT
eurjchem-604	1830	5	grivani	grivani	PROPN
eurjchem-604	1830	6	,	,	PUNCT
eurjchem-604	1830	7	g.	g.	PROPN
eurjchem-604	1830	8	;	;	PUNCT
eurjchem-604	1830	9	tangestaninejad	tangestaninejad	NOUN
eurjchem-604	1830	10	,	,	PUNCT
eurjchem-604	1830	11	s.	s.	PROPN
eurjchem-604	1830	12	;	;	PUNCT
eurjchem-604	1830	13	habibi	habibi	PROPN
eurjchem-604	1830	14	,	,	PUNCT
eurjchem-604	1830	15	m.	m.	PROPN
eurjchem-604	1830	16	h.	h.	PROPN
eurjchem-604	1830	17	;	;	PUNCT
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eurjchem-604	1830	19	,	,	PUNCT
eurjchem-604	1830	20	v.	v.	ADP
eurjchem-604	1830	21	cat	cat	NOUN
eurjchem-604	1830	22	.	.	PUNCT
eurjchem-604	1831	1	commun	commun	PROPN
eurjchem-604	1831	2	.	.	PUNCT
eurjchem-604	1832	1	2005	2005	NUM
eurjchem-604	1832	2	,	,	PUNCT
eurjchem-604	1832	3	6(6	6(6	NOUN
eurjchem-604	1832	4	)	)	PUNCT
eurjchem-604	1832	5	,	,	PUNCT
eurjchem-604	1832	6	375‐378	375‐378	NUM
eurjchem-604	1832	7	.	.	PUNCT
eurjchem-604	1833	1	[	[	X
eurjchem-604	1833	2	237	237	NUM
eurjchem-604	1833	3	]	]	PUNCT
eurjchem-604	1833	4	.	.	PUNCT
eurjchem-604	1834	1	femoni	femoni	PROPN
eurjchem-604	1834	2	,	,	PUNCT
eurjchem-604	1834	3	c.	c.	PROPN
eurjchem-604	1834	4	;	;	PUNCT
eurjchem-604	1834	5	iapalucci	iapalucci	PROPN
eurjchem-604	1834	6	,	,	PUNCT
eurjchem-604	1834	7	m.	m.	PROPN
eurjchem-604	1834	8	c.	c.	PROPN
eurjchem-604	1834	9	;	;	PUNCT
eurjchem-604	1834	10	kaswalder	kaswalder	PROPN
eurjchem-604	1834	11	,	,	PUNCT
eurjchem-604	1834	12	f.	f.	PROPN
eurjchem-604	1834	13	;	;	PUNCT
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eurjchem-604	1834	15	,	,	PUNCT
eurjchem-604	1834	16	g	g	PROPN
eurjchem-604	1834	17	;	;	PUNCT
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eurjchem-604	1834	19	,	,	PUNCT
eurjchem-604	1834	20	s.	s.	PROPN
eurjchem-604	1834	21	coord	coord	PROPN
eurjchem-604	1834	22	.	.	PUNCT
eurjchem-604	1835	1	chem	chem	PROPN
eurjchem-604	1835	2	.	.	PUNCT
eurjchem-604	1836	1	rev	rev	PROPN
eurjchem-604	1836	2	.	.	PROPN
eurjchem-604	1836	3	2006	2006	NUM
eurjchem-604	1836	4	,	,	PUNCT
eurjchem-604	1836	5	250(11‐12	250(11‐12	NUM
eurjchem-604	1836	6	)	)	PUNCT
eurjchem-604	1836	7	,	,	PUNCT
eurjchem-604	1836	8	1580‐1604	1580‐1604	NUM
eurjchem-604	1836	9	.	.	PUNCT
eurjchem-604	1837	1	[	[	X
eurjchem-604	1837	2	238	238	NUM
eurjchem-604	1837	3	]	]	PUNCT
eurjchem-604	1837	4	.	.	PUNCT
eurjchem-604	1838	1	wang	wang	PROPN
eurjchem-604	1838	2	,	,	PUNCT
eurjchem-604	1838	3	c.	c.	PROPN
eurjchem-604	1838	4	;	;	PUNCT
eurjchem-604	1838	5	yin	yin	PROPN
eurjchem-604	1838	6	,	,	PUNCT
eurjchem-604	1838	7	h.	h.	PROPN
eurjchem-604	1838	8	;	;	PUNCT
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eurjchem-604	1838	10	,	,	PUNCT
eurjchem-604	1838	11	s.	s.	PROPN
eurjchem-604	1838	12	;	;	PUNCT
eurjchem-604	1838	13	sun	sun	PROPN
eurjchem-604	1838	14	,	,	PUNCT
eurjchem-604	1838	15	s.	s.	PROPN
eurjchem-604	1838	16	chem	chem	PROPN
eurjchem-604	1838	17	.	.	PUNCT
eurjchem-604	1839	1	mater	mater	PROPN
eurjchem-604	1839	2	.	.	PUNCT
eurjchem-604	1840	1	2010	2010	NUM
eurjchem-604	1840	2	,	,	PUNCT
eurjchem-604	1840	3	22(10	22(10	NUM
eurjchem-604	1840	4	)	)	PUNCT
eurjchem-604	1840	5	,	,	PUNCT
eurjchem-604	1840	6	3277‐	3277‐	NUM
eurjchem-604	1840	7	3282	3282	NUM
eurjchem-604	1840	8	.	.	PUNCT
eurjchem-604	1841	1	[	[	X
eurjchem-604	1841	2	239	239	NUM
eurjchem-604	1841	3	]	]	PUNCT
eurjchem-604	1841	4	.	.	PUNCT
eurjchem-604	1842	1	mann	mann	PROPN
eurjchem-604	1842	2	,	,	PUNCT
eurjchem-604	1842	3	b.	b.	PROPN
eurjchem-604	1842	4	e.	e.	PROPN
eurjchem-604	1842	5	;	;	PUNCT
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eurjchem-604	1842	7	,	,	PUNCT
eurjchem-604	1842	8	t.	t.	PROPN
eurjchem-604	1842	9	r.	r.	PROPN
eurjchem-604	1842	10	;	;	PUNCT
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eurjchem-604	1842	12	,	,	PUNCT
eurjchem-604	1842	13	j.	j.	PROPN
eurjchem-604	1842	14	e.	e.	PROPN
eurjchem-604	1842	15	;	;	PUNCT
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eurjchem-604	1842	17	,	,	PUNCT
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eurjchem-604	1842	19	;	;	PUNCT
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eurjchem-604	1842	21	,	,	PUNCT
eurjchem-604	1842	22	c.	c.	PROPN
eurjchem-604	1842	23	;	;	PUNCT
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eurjchem-604	1842	25	,	,	PUNCT
eurjchem-604	1842	26	r.	r.	PROPN
eurjchem-604	1842	27	j.	j.	PROPN
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eurjchem-604	1842	29	.	.	PUNCT
eurjchem-604	1843	1	biochem	biochem	PROPN
eurjchem-604	1843	2	.	.	PUNCT
eurjchem-604	1844	1	2003	2003	NUM
eurjchem-604	1844	2	,	,	PUNCT
eurjchem-604	1844	3	96(1	96(1	NUM
eurjchem-604	1844	4	)	)	PUNCT
eurjchem-604	1844	5	,	,	PUNCT
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eurjchem-604	1844	7	.	.	PUNCT
eurjchem-604	1845	1	[	[	X
eurjchem-604	1845	2	240	240	NUM
eurjchem-604	1845	3	]	]	PUNCT
eurjchem-604	1845	4	.	.	PUNCT
eurjchem-604	1846	1	jaouen	jaouen	PROPN
eurjchem-604	1846	2	,	,	PUNCT
eurjchem-604	1846	3	g.	g.	PROPN
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eurjchem-604	1846	5	:	:	PUNCT
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eurjchem-604	1847	2	,	,	PUNCT
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eurjchem-604	1847	4	,	,	PUNCT
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eurjchem-604	1847	6	,	,	PUNCT
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eurjchem-604	1847	8	:	:	PUNCT
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eurjchem-604	1847	10	,	,	PUNCT
eurjchem-604	1847	11	2006	2006	NUM
eurjchem-604	1847	12	.	.	PUNCT
eurjchem-604	1848	1	[	[	X
eurjchem-604	1848	2	241	241	NUM
eurjchem-604	1848	3	]	]	PUNCT
eurjchem-604	1848	4	.	.	PUNCT
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eurjchem-604	1848	6	,	,	PUNCT
eurjchem-604	1848	7	j.	j.	PROPN
eurjchem-604	1848	8	j.	j.	PROPN
eurjchem-604	1848	9	env	env	PROPN
eurjchem-604	1848	10	.	.	PROPN
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eurjchem-604	1848	12	.	.	PUNCT
eurjchem-604	1849	1	1999	1999	NUM
eurjchem-604	1849	2	,	,	PUNCT
eurjchem-604	1849	3	1	1	NUM
eurjchem-604	1849	4	,	,	PUNCT
eurjchem-604	1849	5	33‐37	33‐37	NUM
eurjchem-604	1849	6	.	.	PUNCT
eurjchem-604	1850	1	[	[	X
eurjchem-604	1850	2	242	242	NUM
eurjchem-604	1850	3	]	]	PUNCT
eurjchem-604	1850	4	.	.	PUNCT
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eurjchem-604	1851	2	,	,	PUNCT
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eurjchem-604	1851	4	;	;	PUNCT
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eurjchem-604	1851	6	,	,	PUNCT
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eurjchem-604	1851	8	n.	n.	PROPN
eurjchem-604	1851	9	;	;	PUNCT
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eurjchem-604	1851	11	,	,	PUNCT
eurjchem-604	1851	12	p.	p.	PROPN
eurjchem-604	1851	13	n.	n.	PROPN
eurjchem-604	1851	14	j.	j.	PROPN
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eurjchem-604	1851	16	.	.	PUNCT
eurjchem-604	1852	1	ind	ind	PROPN
eurjchem-604	1852	2	.	.	PUNCT
eurjchem-604	1853	1	res	re	NOUN
eurjchem-604	1853	2	.	.	PUNCT
eurjchem-604	1854	1	india	india	PROPN
eurjchem-604	1854	2	2009	2009	NUM
eurjchem-604	1854	3	,	,	PUNCT
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eurjchem-604	1854	5	,	,	PUNCT
eurjchem-604	1854	6	181‐187	181‐187	NUM
eurjchem-604	1854	7	.	.	PUNCT
eurjchem-604	1855	1	[	[	X
eurjchem-604	1855	2	243	243	NUM
eurjchem-604	1855	3	]	]	PUNCT
eurjchem-604	1855	4	.	.	PUNCT
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eurjchem-604	1856	2	,	,	PUNCT
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eurjchem-604	1856	4	;	;	PUNCT
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eurjchem-604	1856	6	,	,	PUNCT
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eurjchem-604	1856	8	k.	k.	PROPN
eurjchem-604	1856	9	;	;	PUNCT
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eurjchem-604	1856	11	,	,	PUNCT
eurjchem-604	1856	12	s.	s.	PROPN
eurjchem-604	1856	13	;	;	PUNCT
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eurjchem-604	1856	15	,	,	PUNCT
eurjchem-604	1856	16	v.	v.	PROPN
eurjchem-604	1856	17	k.	k.	PROPN
eurjchem-604	1856	18	;	;	PUNCT
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eurjchem-604	1856	20	,	,	PUNCT
eurjchem-604	1856	21	s.	s.	PROPN
eurjchem-604	1856	22	m.	m.	PROPN
eurjchem-604	1856	23	j.	j.	PROPN
eurjchem-604	1856	24	organomet	organomet	PROPN
eurjchem-604	1856	25	.	.	PUNCT
eurjchem-604	1857	1	chem	chem	NOUN
eurjchem-604	1857	2	.	.	PUNCT
eurjchem-604	1858	1	2010	2010	NUM
eurjchem-604	1858	2	,	,	PUNCT
eurjchem-604	1858	3	695(7	695(7	NUM
eurjchem-604	1858	4	)	)	PUNCT
eurjchem-604	1858	5	,	,	PUNCT
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eurjchem-604	1858	7	.	.	PUNCT
eurjchem-604	1859	1	[	[	X
eurjchem-604	1859	2	244	244	NUM
eurjchem-604	1859	3	]	]	PUNCT
eurjchem-604	1859	4	.	.	PUNCT
eurjchem-604	1860	1	darensbourg	darensbourg	PROPN
eurjchem-604	1860	2	,	,	PUNCT
eurjchem-604	1860	3	d.	d.	PROPN
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eurjchem-604	1860	5	;	;	PUNCT
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eurjchem-604	1860	7	,	,	PUNCT
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eurjchem-604	1860	9	;	;	PUNCT
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eurjchem-604	1860	16	.	.	PUNCT
eurjchem-604	1861	1	chem	chem	NOUN
eurjchem-604	1861	2	.	.	PUNCT
eurjchem-604	1862	1	soc	soc	PROPN
eurjchem-604	1862	2	.	.	PUNCT
eurjchem-604	1863	1	1981	1981	NUM
eurjchem-604	1863	2	,	,	PUNCT
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eurjchem-604	1863	4	,	,	PUNCT
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eurjchem-604	1863	6	.	.	PUNCT
eurjchem-604	1864	1	[	[	X
eurjchem-604	1864	2	245	245	NUM
eurjchem-604	1864	3	]	]	PUNCT
eurjchem-604	1864	4	.	.	PUNCT
eurjchem-604	1864	5	darensbourg	darensbourg	PROPN
eurjchem-604	1864	6	,	,	PUNCT
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eurjchem-604	1864	8	y.	y.	PROPN
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eurjchem-604	1864	11	,	,	PUNCT
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eurjchem-604	1864	13	c.	c.	PROPN
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eurjchem-604	1864	15	.	.	PUNCT
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eurjchem-604	1865	2	.	.	PUNCT
eurjchem-604	1866	1	1981	1981	NUM
eurjchem-604	1866	2	,	,	PUNCT
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eurjchem-604	1866	4	,	,	PUNCT
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eurjchem-604	1866	6	.	.	PUNCT
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eurjchem-604	1867	2	246	246	NUM
eurjchem-604	1867	3	]	]	PUNCT
eurjchem-604	1867	4	.	.	PUNCT
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eurjchem-604	1868	2	,	,	PUNCT
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eurjchem-604	1868	4	y.	y.	PROPN
eurjchem-604	1868	5	;	;	PUNCT
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eurjchem-604	1868	7	,	,	PUNCT
eurjchem-604	1868	8	s.	s.	PROPN
eurjchem-604	1868	9	j.	j.	PROPN
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eurjchem-604	1868	11	.	.	PUNCT
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eurjchem-604	1869	2	.	.	PUNCT
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eurjchem-604	1870	2	.	.	PUNCT
eurjchem-604	1871	1	1981	1981	NUM
eurjchem-604	1871	2	,	,	PUNCT
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eurjchem-604	1871	4	,	,	PUNCT
eurjchem-604	1871	5	5914‐	5914‐	NUM
eurjchem-604	1871	6	5915	5915	NUM
eurjchem-604	1871	7	.	.	PUNCT
eurjchem-604	1872	1	[	[	X
eurjchem-604	1872	2	247	247	NUM
eurjchem-604	1872	3	]	]	PUNCT
eurjchem-604	1872	4	.	.	PUNCT
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eurjchem-604	1873	2	,	,	PUNCT
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eurjchem-604	1873	6	,	,	PUNCT
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eurjchem-604	1873	15	,	,	PUNCT
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eurjchem-604	1873	19	.	.	PUNCT
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eurjchem-604	1874	2	.	.	PUNCT
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eurjchem-604	1875	2	,	,	PUNCT
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eurjchem-604	1875	4	)	)	PUNCT
eurjchem-604	1875	5	,	,	PUNCT
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eurjchem-604	1875	7	.	.	PUNCT
eurjchem-604	1876	1	[	[	X
eurjchem-604	1876	2	248	248	NUM
eurjchem-604	1876	3	]	]	PUNCT
eurjchem-604	1876	4	.	.	PUNCT
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eurjchem-604	1877	2	,	,	PUNCT
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eurjchem-604	1877	7	;	;	PUNCT
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eurjchem-604	1877	9	,	,	PUNCT
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eurjchem-604	1877	14	.	.	PUNCT
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eurjchem-604	1878	2	,	,	PUNCT
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eurjchem-604	1878	4	,	,	PUNCT
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eurjchem-604	1878	6	.	.	PUNCT
eurjchem-604	1879	1	[	[	X
eurjchem-604	1879	2	249	249	NUM
eurjchem-604	1879	3	]	]	PUNCT
eurjchem-604	1879	4	.	.	PUNCT
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eurjchem-604	1880	2	,	,	PUNCT
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eurjchem-604	1880	4	j.	j.	PROPN
eurjchem-604	1880	5	;	;	PUNCT
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eurjchem-604	1880	7	,	,	PUNCT
eurjchem-604	1880	8	y.	y.	PROPN
eurjchem-604	1880	9	s.	s.	PROPN
eurjchem-604	1880	10	;	;	PUNCT
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eurjchem-604	1880	12	,	,	PUNCT
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eurjchem-604	1880	14	;	;	PUNCT
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eurjchem-604	1880	16	,	,	PUNCT
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eurjchem-604	1880	26	,	,	PUNCT
eurjchem-604	1880	27	k.	k.	PROPN
eurjchem-604	1880	28	;	;	PUNCT
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eurjchem-604	1880	32	k.	k.	PROPN
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eurjchem-604	1881	2	.	.	PUNCT
eurjchem-604	1882	1	2002	2002	NUM
eurjchem-604	1882	2	,	,	PUNCT
eurjchem-604	1882	3	4(5	4(5	NUM
eurjchem-604	1882	4	)	)	PUNCT
eurjchem-604	1882	5	,	,	PUNCT
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eurjchem-604	1883	2	.	.	PUNCT
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eurjchem-604	1884	2	250	250	NUM
eurjchem-604	1884	3	]	]	PUNCT
eurjchem-604	1884	4	.	.	PUNCT
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eurjchem-604	1885	2	,	,	PUNCT
eurjchem-604	1885	3	s.	s.	PROPN
eurjchem-604	1885	4	;	;	PUNCT
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eurjchem-604	1885	6	,	,	PUNCT
eurjchem-604	1885	7	s.	s.	PROPN
eurjchem-604	1885	8	y.	y.	PROPN
eurjchem-604	1885	9	;	;	PUNCT
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eurjchem-604	1885	12	y.	y.	PROPN
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eurjchem-604	1885	14	;	;	PUNCT
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eurjchem-604	1885	16	,	,	PUNCT
eurjchem-604	1885	17	k.	k.	PROPN
eurjchem-604	1885	18	h.	h.	PROPN
eurjchem-604	1885	19	;	;	PUNCT
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eurjchem-604	1885	21	,	,	PUNCT
eurjchem-604	1885	22	h.	h.	PROPN
eurjchem-604	1885	23	;	;	PUNCT
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eurjchem-604	1885	25	,	,	PUNCT
eurjchem-604	1885	26	y.	y.	PROPN
eurjchem-604	1885	27	k.	k.	PROPN
eurjchem-604	1886	1	j.	j.	PROPN
eurjchem-604	1886	2	organomet	organomet	PROPN
eurjchem-604	1886	3	.	.	PUNCT
eurjchem-604	1887	1	chem	chem	NOUN
eurjchem-604	1887	2	.	.	PUNCT
eurjchem-604	1888	1	2007	2007	NUM
eurjchem-604	1888	2	,	,	PUNCT
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eurjchem-604	1888	4	)	)	PUNCT
eurjchem-604	1888	5	,	,	PUNCT
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eurjchem-604	1888	7	.	.	PUNCT
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eurjchem-604	1889	2	251	251	NUM
eurjchem-604	1889	3	]	]	PUNCT
eurjchem-604	1889	4	.	.	PUNCT
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eurjchem-604	1889	6	,	,	PUNCT
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eurjchem-604	1889	8	;	;	PUNCT
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eurjchem-604	1889	10	,	,	PUNCT
eurjchem-604	1889	11	g.	g.	PROPN
eurjchem-604	1889	12	p.	p.	PROPN
eurjchem-604	1889	13	;	;	PUNCT
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eurjchem-604	1889	15	,	,	PUNCT
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eurjchem-604	1889	17	k.	k.	PROPN
eurjchem-604	1889	18	j.	j.	PROPN
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eurjchem-604	1889	20	.	.	PUNCT
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eurjchem-604	1890	2	.	.	PUNCT
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eurjchem-604	1891	2	,	,	PUNCT
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eurjchem-604	1891	4	)	)	PUNCT
eurjchem-604	1891	5	,	,	PUNCT
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eurjchem-604	1891	7	.	.	PUNCT
eurjchem-604	1892	1	[	[	X
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eurjchem-604	1892	3	]	]	PUNCT
eurjchem-604	1892	4	.	.	PUNCT
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eurjchem-604	1893	2	,	,	PUNCT
eurjchem-604	1893	3	g.	g.	PROPN
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eurjchem-604	1893	5	;	;	PUNCT
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eurjchem-604	1893	7	,	,	PUNCT
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eurjchem-604	1893	9	j.	j.	PROPN
eurjchem-604	1893	10	g.	g.	PROPN
eurjchem-604	1893	11	;	;	PUNCT
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eurjchem-604	1893	13	,	,	PUNCT
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eurjchem-604	1893	23	,	,	PUNCT
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eurjchem-604	1893	25	)	)	PUNCT
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eurjchem-604	1893	28	.	.	PUNCT
eurjchem-604	1894	1	[	[	X
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eurjchem-604	1894	3	]	]	PUNCT
eurjchem-604	1894	4	.	.	PUNCT
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eurjchem-604	1895	2	,	,	PUNCT
eurjchem-604	1895	3	n.	n.	PROPN
eurjchem-604	1895	4	e.	e.	PROPN
eurjchem-604	1895	5	;	;	PUNCT
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eurjchem-604	1895	7	,	,	PUNCT
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eurjchem-604	1895	9	l.	l.	PROPN
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eurjchem-604	1895	12	,	,	PUNCT
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eurjchem-604	1895	14	)	)	PUNCT
eurjchem-604	1895	15	,	,	PUNCT
eurjchem-604	1895	16	4167‐	4167‐	NUM
eurjchem-604	1895	17	4169	4169	NUM
eurjchem-604	1895	18	.	.	PUNCT
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eurjchem-604	1896	2	254	254	NUM
eurjchem-604	1896	3	]	]	PUNCT
eurjchem-604	1896	4	.	.	PUNCT
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eurjchem-604	1897	2	,	,	PUNCT
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eurjchem-604	1897	7	,	,	PUNCT
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eurjchem-604	1897	9	/	/	SYM
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eurjchem-604	1897	14	,	,	PUNCT
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eurjchem-604	1898	2	255	255	NUM
eurjchem-604	1898	3	]	]	PUNCT
eurjchem-604	1898	4	.	.	PUNCT
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eurjchem-604	1899	2	,	,	PUNCT
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eurjchem-604	1899	5	;	;	PUNCT
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eurjchem-604	1899	7	,	,	PUNCT
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eurjchem-604	1899	10	;	;	PUNCT
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eurjchem-604	1899	12	,	,	PUNCT
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eurjchem-604	1899	17	,	,	PUNCT
eurjchem-604	1899	18	1(5	1(5	NUM
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eurjchem-604	1899	20	,	,	PUNCT
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eurjchem-604	1900	2	256	256	NUM
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eurjchem-604	1900	4	.	.	PUNCT
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eurjchem-604	1901	2	,	,	PUNCT
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eurjchem-604	1901	5	;	;	PUNCT
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eurjchem-604	1901	7	,	,	PUNCT
eurjchem-604	1901	8	y.	y.	PROPN
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eurjchem-604	1901	10	;	;	PUNCT
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eurjchem-604	1901	22	,	,	PUNCT
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eurjchem-604	1901	27	,	,	PUNCT
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eurjchem-604	1901	30	.	.	PUNCT
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eurjchem-604	1902	2	.	.	PUNCT
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eurjchem-604	1903	2	,	,	PUNCT
eurjchem-604	1903	3	40(6	40(6	PROPN
eurjchem-604	1903	4	)	)	PUNCT
eurjchem-604	1903	5	,	,	PUNCT
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eurjchem-604	1903	7	.	.	PUNCT
eurjchem-604	1904	1	[	[	X
eurjchem-604	1904	2	257	257	NUM
eurjchem-604	1904	3	]	]	PUNCT
eurjchem-604	1904	4	.	.	PUNCT
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eurjchem-604	1905	2	,	,	PUNCT
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eurjchem-604	1905	4	;	;	PUNCT
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eurjchem-604	1905	6	,	,	PUNCT
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eurjchem-604	1905	9	.	.	PUNCT
eurjchem-604	1906	1	chem	chem	PROPN
eurjchem-604	1906	2	.	.	PUNCT
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eurjchem-604	1907	2	,	,	PUNCT
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eurjchem-604	1907	4	)	)	PUNCT
eurjchem-604	1907	5	,	,	PUNCT
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eurjchem-604	1907	7	.	.	PUNCT
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eurjchem-604	1908	2	258	258	NUM
eurjchem-604	1908	3	]	]	PUNCT
eurjchem-604	1908	4	.	.	PUNCT
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eurjchem-604	1909	2	,	,	PUNCT
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eurjchem-604	1909	4	;	;	PUNCT
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eurjchem-604	1909	6	,	,	PUNCT
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eurjchem-604	1909	14	.	.	PUNCT
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eurjchem-604	1910	2	.	.	PUNCT
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eurjchem-604	1911	3	,	,	PUNCT
eurjchem-604	1911	4	360(10	360(10	NUM
eurjchem-604	1911	5	)	)	PUNCT
eurjchem-604	1911	6	,	,	PUNCT
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eurjchem-604	1911	8	.	.	PUNCT
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eurjchem-604	1912	2	259	259	NUM
eurjchem-604	1912	3	]	]	PUNCT
eurjchem-604	1912	4	.	.	PUNCT
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eurjchem-604	1913	2	,	,	PUNCT
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eurjchem-604	1913	24	,	,	PUNCT
eurjchem-604	1913	25	26(20	26(20	NUM
eurjchem-604	1913	26	)	)	PUNCT
eurjchem-604	1913	27	,	,	PUNCT
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eurjchem-604	1913	29	.	.	PUNCT
eurjchem-604	1914	1	[	[	X
eurjchem-604	1914	2	260	260	NUM
eurjchem-604	1914	3	]	]	PUNCT
eurjchem-604	1914	4	.	.	PUNCT
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eurjchem-604	1915	2	,	,	PUNCT
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eurjchem-604	1915	38	.	.	PUNCT
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eurjchem-604	1916	2	261	261	NUM
eurjchem-604	1916	3	]	]	PUNCT
eurjchem-604	1916	4	.	.	PUNCT
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eurjchem-604	1917	30	,	,	PUNCT
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eurjchem-604	1917	34	.	.	PUNCT
eurjchem-604	1918	1	[	[	X
eurjchem-604	1918	2	262	262	NUM
eurjchem-604	1918	3	]	]	PUNCT
eurjchem-604	1918	4	.	.	PUNCT
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eurjchem-604	1919	2	,	,	PUNCT
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eurjchem-604	1920	2	263	263	NUM
eurjchem-604	1920	3	]	]	PUNCT
eurjchem-604	1920	4	.	.	PUNCT
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eurjchem-604	1921	2	,	,	PUNCT
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eurjchem-604	1921	7	chemistry	chemistry	NOUN
eurjchem-604	1921	8	:	:	PUNCT
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eurjchem-604	1921	16	:	:	PUNCT
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eurjchem-604	1922	2	264	264	NUM
eurjchem-604	1922	3	]	]	PUNCT
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eurjchem-604	1923	2	,	,	PUNCT
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eurjchem-604	1923	36	,	,	PUNCT
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eurjchem-604	1923	38	.	.	PUNCT
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eurjchem-604	1924	3	]	]	PUNCT
eurjchem-604	1924	4	.	.	PUNCT
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eurjchem-604	1925	2	,	,	PUNCT
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eurjchem-604	1925	10	;	;	PUNCT
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eurjchem-604	1926	2	.	.	PUNCT
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eurjchem-604	1927	2	.	.	PUNCT
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eurjchem-604	1928	2	,	,	PUNCT
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eurjchem-604	1928	4	)	)	PUNCT
eurjchem-604	1928	5	,	,	PUNCT
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eurjchem-604	1928	7	.	.	PUNCT
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eurjchem-604	1929	3	]	]	PUNCT
eurjchem-604	1929	4	.	.	PUNCT
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eurjchem-604	1930	2	,	,	PUNCT
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eurjchem-604	1931	2	.	.	PUNCT
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eurjchem-604	1932	4	.	.	PUNCT
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eurjchem-604	1933	12	,	,	PUNCT
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eurjchem-604	1933	18	.	.	PUNCT
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eurjchem-604	1934	3	]	]	PUNCT
eurjchem-604	1934	4	.	.	PUNCT
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eurjchem-604	1935	24	.	.	PUNCT
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eurjchem-604	1936	2	,	,	PUNCT
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eurjchem-604	1936	4	,	,	PUNCT
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eurjchem-604	1936	6	.	.	PUNCT
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eurjchem-604	1937	2	269	269	NUM
eurjchem-604	1937	3	]	]	PUNCT
eurjchem-604	1937	4	.	.	PUNCT
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eurjchem-604	1938	2	,	,	PUNCT
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eurjchem-604	1938	4	;	;	PUNCT
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eurjchem-604	1938	8	;	;	PUNCT
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eurjchem-604	1938	10	,	,	PUNCT
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eurjchem-604	1938	12	;	;	PUNCT
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eurjchem-604	1938	22	.	.	PUNCT
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eurjchem-604	1938	24	,	,	PUNCT
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eurjchem-604	1938	26	)	)	PUNCT
eurjchem-604	1938	27	,	,	PUNCT
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eurjchem-604	1938	29	.	.	PUNCT
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eurjchem-604	1939	2	270	270	NUM
eurjchem-604	1939	3	]	]	PUNCT
eurjchem-604	1939	4	.	.	PUNCT
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eurjchem-604	1940	4	;	;	PUNCT
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eurjchem-604	1940	8	;	;	PUNCT
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eurjchem-604	1940	20	,	,	PUNCT
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eurjchem-604	1940	23	,	,	PUNCT
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eurjchem-604	1940	25	.	.	PUNCT
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eurjchem-604	1941	4	.	.	PUNCT
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eurjchem-604	1942	8	;	;	PUNCT
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eurjchem-604	1942	18	.	.	PUNCT
eurjchem-604	1942	19	1985	1985	NUM
eurjchem-604	1942	20	,	,	PUNCT
eurjchem-604	1942	21	26(19	26(19	NUM
eurjchem-604	1942	22	)	)	PUNCT
eurjchem-604	1942	23	,	,	PUNCT
eurjchem-604	1942	24	2317‐2318	2317‐2318	NUM
eurjchem-604	1942	25	.	.	PUNCT
eurjchem-604	1943	1	[	[	X
eurjchem-604	1943	2	272	272	NUM
eurjchem-604	1943	3	]	]	PUNCT
eurjchem-604	1943	4	.	.	PUNCT
eurjchem-604	1944	1	top	top	ADJ
eurjchem-604	1944	2	,	,	PUNCT
eurjchem-604	1944	3	s.	s.	PROPN
eurjchem-604	1944	4	;	;	PUNCT
eurjchem-604	1944	5	jaouen	jaouen	PROPN
eurjchem-604	1944	6	,	,	PUNCT
eurjchem-604	1944	7	g.	g.	PROPN
eurjchem-604	1944	8	tetrahedron	tetrahedron	PROPN
eurjchem-604	1944	9	lett	lett	PROPN
eurjchem-604	1944	10	.	.	PUNCT
eurjchem-604	1945	1	1978	1978	NUM
eurjchem-604	1945	2	,	,	PUNCT
eurjchem-604	1945	3	19(9	19(9	NUM
eurjchem-604	1945	4	)	)	PUNCT
eurjchem-604	1945	5	,	,	PUNCT
eurjchem-604	1945	6	787‐790	787‐790	NOUN
eurjchem-604	1945	7	.	.	PUNCT
eurjchem-604	1946	1	[	[	X
eurjchem-604	1946	2	273	273	NUM
eurjchem-604	1946	3	]	]	PUNCT
eurjchem-604	1946	4	.	.	PUNCT
eurjchem-604	1947	1	uemura	uemura	PROPN
eurjchem-604	1947	2	,	,	PUNCT
eurjchem-604	1947	3	m.	m.	NOUN
eurjchem-604	1947	4	;	;	PUNCT
eurjchem-604	1947	5	minami	minami	PROPN
eurjchem-604	1947	6	,	,	PUNCT
eurjchem-604	1947	7	t.	t.	PROPN
eurjchem-604	1947	8	;	;	PUNCT
eurjchem-604	1947	9	hirotau	hirotau	PROPN
eurjchem-604	1947	10	,	,	PUNCT
eurjchem-604	1947	11	k.	k.	PROPN
eurjchem-604	1947	12	;	;	PUNCT
eurjchem-604	1947	13	hayashi	hayashi	PROPN
eurjchem-604	1947	14	,	,	PUNCT
eurjchem-604	1947	15	y.	y.	PROPN
eurjchem-604	1947	16	j.	j.	PROPN
eurjchem-604	1947	17	org	org	PROPN
eurjchem-604	1947	18	.	.	PUNCT
eurjchem-604	1947	19	chem	chem	PROPN
eurjchem-604	1947	20	.	.	PUNCT
eurjchem-604	1948	1	1989	1989	NUM
eurjchem-604	1948	2	,	,	PUNCT
eurjchem-604	1948	3	54	54	NUM
eurjchem-604	1948	4	,	,	PUNCT
eurjchem-604	1948	5	469‐477	469‐477	NOUN
eurjchem-604	1948	6	.	.	PUNCT
eurjchem-604	1949	1	[	[	X
eurjchem-604	1949	2	274	274	NUM
eurjchem-604	1949	3	]	]	PUNCT
eurjchem-604	1949	4	.	.	PUNCT
eurjchem-604	1950	1	albert	albert	PROPN
eurjchem-604	1950	2	,	,	PUNCT
eurjchem-604	1950	3	j.	j.	PROPN
eurjchem-604	1950	4	;	;	PUNCT
eurjchem-604	1950	5	davies	davy	NOUN
eurjchem-604	1950	6	,	,	PUNCT
eurjchem-604	1950	7	s.	s.	PROPN
eurjchem-604	1950	8	g.	g.	PROPN
eurjchem-604	1950	9	tetrahedron	tetrahedron	PROPN
eurjchem-604	1950	10	lett	lett	PROPN
eurjchem-604	1950	11	.	.	PUNCT
eurjchem-604	1950	12	1984	1984	NUM
eurjchem-604	1950	13	,	,	PUNCT
eurjchem-604	1950	14	25	25	NUM
eurjchem-604	1950	15	,	,	PUNCT
eurjchem-604	1950	16	1897‐1900	1897‐1900	NUM
eurjchem-604	1950	17	.	.	PUNCT
eurjchem-604	1951	1	[	[	X
eurjchem-604	1951	2	275	275	NUM
eurjchem-604	1951	3	]	]	PUNCT
eurjchem-604	1951	4	.	.	PUNCT
eurjchem-604	1951	5	doyle	doyle	PROPN
eurjchem-604	1951	6	,	,	PUNCT
eurjchem-604	1951	7	m.	m.	NOUN
eurjchem-604	1951	8	m.	m.	NOUN
eurjchem-604	1951	9	;	;	PUNCT
eurjchem-604	1951	10	jackson	jackson	PROPN
eurjchem-604	1951	11	,	,	PUNCT
eurjchem-604	1951	12	w.	w.	PROPN
eurjchem-604	1951	13	r.	r.	PROPN
eurjchem-604	1951	14	;	;	PUNCT
eurjchem-604	1951	15	perlmutter	perlmutter	NOUN
eurjchem-604	1951	16	,	,	PUNCT
eurjchem-604	1951	17	p.	p.	NOUN
eurjchem-604	1951	18	tetrahedron	tetrahedron	PROPN
eurjchem-604	1951	19	lett	lett	PROPN
eurjchem-604	1951	20	.	.	PUNCT
eurjchem-604	1951	21	1989	1989	NUM
eurjchem-604	1951	22	,	,	PUNCT
eurjchem-604	1951	23	30(39	30(39	NUM
eurjchem-604	1951	24	)	)	PUNCT
eurjchem-604	1951	25	,	,	PUNCT
eurjchem-604	1951	26	5357‐5360	5357‐5360	NUM
eurjchem-604	1951	27	.	.	PUNCT
eurjchem-604	1952	1	[	[	X
eurjchem-604	1952	2	276	276	NUM
eurjchem-604	1952	3	]	]	PUNCT
eurjchem-604	1952	4	.	.	PUNCT
eurjchem-604	1953	1	uemura	uemura	PROPN
eurjchem-604	1953	2	,	,	PUNCT
eurjchem-604	1953	3	m.	m.	NOUN
eurjchem-604	1953	4	;	;	PUNCT
eurjchem-604	1953	5	minami	minami	PROPN
eurjchem-604	1953	6	,	,	PUNCT
eurjchem-604	1953	7	t.	t.	PROPN
eurjchem-604	1953	8	;	;	PUNCT
eurjchem-604	1953	9	isobe	isobe	NOUN
eurjchem-604	1953	10	,	,	PUNCT
eurjchem-604	1953	11	k.	k.	PROPN
eurjchem-604	1953	12	;	;	PUNCT
eurjchem-604	1953	13	kobayashi	kobayashi	PROPN
eurjchem-604	1953	14	,	,	PUNCT
eurjchem-604	1953	15	t.	t.	PROPN
eurjchem-604	1953	16	;	;	PUNCT
eurjchem-604	1953	17	hayashi	hayashi	PROPN
eurjchem-604	1953	18	,	,	PUNCT
eurjchem-604	1953	19	y.	y.	PROPN
eurjchem-604	1953	20	tetrahedron	tetrahedron	PROPN
eurjchem-604	1953	21	lett	lett	PROPN
eurjchem-604	1953	22	.	.	PUNCT
eurjchem-604	1954	1	1986	1986	NUM
eurjchem-604	1954	2	,	,	PUNCT
eurjchem-604	1954	3	27(8	27(8	NUM
eurjchem-604	1954	4	)	)	PUNCT
eurjchem-604	1954	5	,	,	PUNCT
eurjchem-604	1954	6	967‐970	967‐970	NUM
eurjchem-604	1954	7	.	.	PUNCT
eurjchem-604	1955	1	[	[	X
eurjchem-604	1955	2	277	277	NUM
eurjchem-604	1955	3	]	]	PUNCT
eurjchem-604	1955	4	.	.	PUNCT
eurjchem-604	1956	1	marshall	marshall	PROPN
eurjchem-604	1956	2	,	,	PUNCT
eurjchem-604	1956	3	j.	j.	PROPN
eurjchem-604	1956	4	a.	a.	PROPN
eurjchem-604	1956	5	;	;	PUNCT
eurjchem-604	1956	6	gung	gung	PROPN
eurjchem-604	1956	7	,	,	PUNCT
eurjchem-604	1956	8	w.	w.	PROPN
eurjchem-604	1956	9	y.	y.	PROPN
eurjchem-604	1956	10	tetrahedron	tetrahedron	PROPN
eurjchem-604	1956	11	lett	lett	PROPN
eurjchem-604	1956	12	.	.	PUNCT
eurjchem-604	1956	13	1989	1989	NUM
eurjchem-604	1956	14	,	,	PUNCT
eurjchem-604	1956	15	30(3	30(3	NUM
eurjchem-604	1956	16	)	)	PUNCT
eurjchem-604	1956	17	,	,	PUNCT
eurjchem-604	1956	18	309‐312	309‐312	NUM
eurjchem-604	1956	19	.	.	PUNCT
eurjchem-604	1957	1	[	[	X
eurjchem-604	1957	2	278	278	NUM
eurjchem-604	1957	3	]	]	PUNCT
eurjchem-604	1957	4	.	.	PUNCT
eurjchem-604	1958	1	nunn	nunn	PROPN
eurjchem-604	1958	2	,	,	PUNCT
eurjchem-604	1958	3	k.	k.	PROPN
eurjchem-604	1958	4	;	;	PUNCT
eurjchem-604	1958	5	mosset	mosset	VERB
eurjchem-604	1958	6	,	,	PUNCT
eurjchem-604	1958	7	p.	p.	PROPN
eurjchem-604	1958	8	;	;	PUNCT
eurjchem-604	1959	1	gree	gree	PROPN
eurjchem-604	1959	2	,	,	PUNCT
eurjchem-604	1959	3	r.	r.	PROPN
eurjchem-604	1959	4	;	;	PUNCT
eurjchem-604	1959	5	saalfrank	saalfrank	PROPN
eurjchem-604	1959	6	,	,	PUNCT
eurjchem-604	1959	7	r.	r.	PROPN
eurjchem-604	1959	8	w.	w.	PROPN
eurjchem-604	1959	9	angew	angew	PROPN
eurjchem-604	1959	10	.	.	PUNCT
eurjchem-604	1960	1	chem	chem	PROPN
eurjchem-604	1960	2	.	.	PUNCT
eurjchem-604	1961	1	int	int	NOUN
eurjchem-604	1961	2	.	.	PUNCT
eurjchem-604	1962	1	ed	ed	NOUN
eurjchem-604	1962	2	.	.	PROPN
eurjchem-604	1962	3	,	,	PUNCT
eurjchem-604	1962	4	eng	eng	PROPN
eurjchem-604	1962	5	.	.	PROPN
eurjchem-604	1962	6	1988	1988	NUM
eurjchem-604	1962	7	,	,	PUNCT
eurjchem-604	1962	8	27(9	27(9	NOUN
eurjchem-604	1962	9	)	)	PUNCT
eurjchem-604	1962	10	,	,	PUNCT
eurjchem-604	1962	11	1188‐1189	1188‐1189	NUM
eurjchem-604	1962	12	.	.	PUNCT
eurjchem-604	1963	1	[	[	X
eurjchem-604	1963	2	279	279	NUM
eurjchem-604	1963	3	]	]	PUNCT
eurjchem-604	1963	4	.	.	PUNCT
eurjchem-604	1964	1	roush	roush	PROPN
eurjchem-604	1964	2	,	,	PUNCT
eurjchem-604	1964	3	w.	w.	PROPN
eurjchem-604	1964	4	r.	r.	PROPN
eurjchem-604	1964	5	;	;	PUNCT
eurjchem-604	1964	6	park	park	PROPN
eurjchem-604	1964	7	,	,	PUNCT
eurjchem-604	1964	8	j.	j.	PROPN
eurjchem-604	1964	9	c.	c.	PROPN
eurjchem-604	1964	10	j.	j.	PROPN
eurjchem-604	1964	11	org	org	PROPN
eurjchem-604	1964	12	.	.	PUNCT
eurjchem-604	1964	13	chem	chem	PROPN
eurjchem-604	1964	14	.	.	PUNCT
eurjchem-604	1965	1	1990	1990	NUM
eurjchem-604	1965	2	,	,	PUNCT
eurjchem-604	1965	3	55(4	55(4	NUM
eurjchem-604	1965	4	)	)	PUNCT
eurjchem-604	1965	5	,	,	PUNCT
eurjchem-604	1965	6	1143‐1144	1143‐1144	NUM
eurjchem-604	1965	7	.	.	PUNCT
eurjchem-604	1966	1	[	[	X
eurjchem-604	1966	2	280	280	NUM
eurjchem-604	1966	3	]	]	PUNCT
eurjchem-604	1966	4	.	.	PUNCT
eurjchem-604	1966	5	shin	shin	PROPN
eurjchem-604	1966	6	,	,	PUNCT
eurjchem-604	1966	7	j.	j.	PROPN
eurjchem-604	1966	8	h.	h.	PROPN
eurjchem-604	1966	9	;	;	PUNCT
eurjchem-604	1966	10	churchill	churchill	PROPN
eurjchem-604	1966	11	,	,	PUNCT
eurjchem-604	1966	12	d.	d.	PROPN
eurjchem-604	1966	13	g.	g.	PROPN
eurjchem-604	1966	14	;	;	PUNCT
eurjchem-604	1966	15	parkin	parkin	NOUN
eurjchem-604	1966	16	,	,	PUNCT
eurjchem-604	1966	17	g.	g.	PROPN
eurjchem-604	1966	18	j.	j.	PROPN
eurjchem-604	1966	19	organomet	organomet	PROPN
eurjchem-604	1966	20	.	.	PUNCT
eurjchem-604	1967	1	chem	chem	NOUN
eurjchem-604	1967	2	.	.	PUNCT
eurjchem-604	1968	1	2002	2002	NUM
eurjchem-604	1968	2	,	,	PUNCT
eurjchem-604	1968	3	642(1‐2	642(1‐2	NUM
eurjchem-604	1968	4	)	)	PUNCT
eurjchem-604	1968	5	,	,	PUNCT
eurjchem-604	1968	6	9‐15	9‐15	NUM
eurjchem-604	1968	7	.	.	PUNCT
eurjchem-604	1969	1	[	[	X
eurjchem-604	1969	2	281	281	NUM
eurjchem-604	1969	3	]	]	PUNCT
eurjchem-604	1969	4	.	.	PUNCT
eurjchem-604	1970	1	sica	sica	PROPN
eurjchem-604	1970	2	,	,	PUNCT
eurjchem-604	1970	3	a.	a.	NOUN
eurjchem-604	1970	4	m.	m.	NOUN
eurjchem-604	1970	5	;	;	PUNCT
eurjchem-604	1970	6	baibich	baibich	PROPN
eurjchem-604	1970	7	,	,	PUNCT
eurjchem-604	1970	8	i.	i.	PROPN
eurjchem-604	1970	9	m.	m.	PROPN
eurjchem-604	1970	10	;	;	PUNCT
eurjchem-604	1970	11	gigola	gigola	PROPN
eurjchem-604	1970	12	,	,	PUNCT
eurjchem-604	1971	1	c.	c.	PROPN
eurjchem-604	1971	2	e.	e.	PROPN
eurjchem-604	1971	3	j.	j.	PROPN
eurjchem-604	1972	1	molecular	molecular	PROPN
eurjchem-604	1972	2	cat	cat	NOUN
eurjchem-604	1972	3	.	.	PUNCT
eurjchem-604	1973	1	a	a	DET
eurjchem-604	1973	2	:	:	PUNCT
eurjchem-604	1973	3	chem	chem	NOUN
eurjchem-604	1973	4	.	.	PUNCT
eurjchem-604	1973	5	2003	2003	NUM
eurjchem-604	1973	6	,	,	PUNCT
eurjchem-604	1973	7	195(1‐2	195(1‐2	NUM
eurjchem-604	1973	8	)	)	PUNCT
eurjchem-604	1973	9	,	,	PUNCT
eurjchem-604	1973	10	225‐233	225‐233	NUM
eurjchem-604	1973	11	.	.	PUNCT
eurjchem-604	1974	1	[	[	X
eurjchem-604	1974	2	282	282	NUM
eurjchem-604	1974	3	]	]	PUNCT
eurjchem-604	1974	4	.	.	PUNCT
eurjchem-604	1975	1	tangestaninejad	tangestaninejad	NOUN
eurjchem-604	1975	2	,	,	PUNCT
eurjchem-604	1975	3	s.	s.	PROPN
eurjchem-604	1975	4	;	;	PUNCT
eurjchem-604	1975	5	habibi	habibi	PROPN
eurjchem-604	1975	6	,	,	PUNCT
eurjchem-604	1975	7	m.	m.	PROPN
eurjchem-604	1975	8	h.	h.	PROPN
eurjchem-604	1975	9	;	;	PUNCT
eurjchem-604	1975	10	mirkhani	mirkhani	NOUN
eurjchem-604	1975	11	,	,	PUNCT
eurjchem-604	1975	12	v.	v.	ADV
eurjchem-604	1975	13	;	;	PUNCT
eurjchem-604	1975	14	moghadam	moghadam	PROPN
eurjchem-604	1975	15	,	,	PUNCT
eurjchem-604	1975	16	m.	m.	NOUN
eurjchem-604	1975	17	;	;	PUNCT
eurjchem-604	1975	18	grivani	grivani	NOUN
eurjchem-604	1975	19	,	,	PUNCT
eurjchem-604	1975	20	g.	g.	PROPN
eurjchem-604	1975	21	inorg	inorg	PROPN
eurjchem-604	1975	22	.	.	PUNCT
eurjchem-604	1976	1	chem	chem	PROPN
eurjchem-604	1976	2	.	.	PUNCT
eurjchem-604	1977	1	commun	commun	PROPN
eurjchem-604	1977	2	.	.	PUNCT
eurjchem-604	1978	1	2006	2006	NUM
eurjchem-604	1978	2	,	,	PUNCT
eurjchem-604	1978	3	9(6	9(6	NUM
eurjchem-604	1978	4	)	)	PUNCT
eurjchem-604	1978	5	,	,	PUNCT
eurjchem-604	1978	6	575‐578	575‐578	NUM
eurjchem-604	1978	7	.	.	PUNCT
eurjchem-604	1979	1	[	[	X
eurjchem-604	1979	2	283	283	NUM
eurjchem-604	1979	3	]	]	PUNCT
eurjchem-604	1979	4	.	.	PUNCT
eurjchem-604	1980	1	grivani	grivani	PROPN
eurjchem-604	1980	2	,	,	PUNCT
eurjchem-604	1980	3	g.	g.	PROPN
eurjchem-604	1980	4	;	;	PUNCT
eurjchem-604	1980	5	tangestaninejad	tangestaninejad	NOUN
eurjchem-604	1980	6	,	,	PUNCT
eurjchem-604	1980	7	s.	s.	PROPN
eurjchem-604	1980	8	;	;	PUNCT
eurjchem-604	1980	9	halili	halili	PROPN
eurjchem-604	1980	10	,	,	PUNCT
eurjchem-604	1980	11	a.	a.	NOUN
eurjchem-604	1980	12	inorg	inorg	PROPN
eurjchem-604	1980	13	.	.	PUNCT
eurjchem-604	1981	1	chem	chem	PROPN
eurjchem-604	1981	2	.	.	PUNCT
eurjchem-604	1982	1	commun	commun	PROPN
eurjchem-604	1982	2	.	.	PUNCT
eurjchem-604	1983	1	2007	2007	NUM
eurjchem-604	1983	2	,	,	PUNCT
eurjchem-604	1983	3	10(8	10(8	NUM
eurjchem-604	1983	4	)	)	PUNCT
eurjchem-604	1983	5	,	,	PUNCT
eurjchem-604	1983	6	914‐917	914‐917	NOUN
eurjchem-604	1983	7	.	.	PUNCT
eurjchem-604	1984	1	[	[	X
eurjchem-604	1984	2	284	284	NUM
eurjchem-604	1984	3	]	]	PUNCT
eurjchem-604	1984	4	.	.	PUNCT
eurjchem-604	1985	1	shi	shi	PROPN
eurjchem-604	1985	2	,	,	PUNCT
eurjchem-604	1985	3	y.	y.	PROPN
eurjchem-604	1985	4	l.	l.	PROPN
eurjchem-604	1985	5	;	;	PUNCT
eurjchem-604	1985	6	gao	gao	PROPN
eurjchem-604	1985	7	,	,	PUNCT
eurjchem-604	1985	8	y.	y.	PROPN
eurjchem-604	1985	9	c.	c.	PROPN
eurjchem-604	1985	10	;	;	PUNCT
eurjchem-604	1985	11	shi	shi	PROPN
eurjchem-604	1985	12	,	,	PUNCT
eurjchem-604	1985	13	q.	q.	PROPN
eurjchem-604	1985	14	z.	z.	PROPN
eurjchem-604	1985	15	organometallics	organometallics	PROPN
eurjchem-604	1985	16	1978	1978	NUM
eurjchem-604	1985	17	,	,	PUNCT
eurjchem-604	1985	18	6	6	NUM
eurjchem-604	1985	19	,	,	PUNCT
eurjchem-604	1985	20	1528‐1531	1528‐1531	NUM
eurjchem-604	1985	21	.	.	PUNCT
eurjchem-604	1986	1	[	[	X
eurjchem-604	1986	2	285	285	NUM
eurjchem-604	1986	3	]	]	PUNCT
eurjchem-604	1986	4	.	.	PUNCT
eurjchem-604	1987	1	darensbourg	darensbourg	PROPN
eurjchem-604	1987	2	,	,	PUNCT
eurjchem-604	1987	3	d.	d.	PROPN
eurjchem-604	1987	4	j.	j.	PROPN
eurjchem-604	1987	5	;	;	PUNCT
eurjchem-604	1987	6	graves	grave	NOUN
eurjchem-604	1987	7	,	,	PUNCT
eurjchem-604	1987	8	a.	a.	NOUN
eurjchem-604	1987	9	h.	h.	PROPN
eurjchem-604	1987	10	inorg	inorg	PROPN
eurjchem-604	1987	11	.	.	PUNCT
eurjchem-604	1988	1	chem	chem	PROPN
eurjchem-604	1988	2	.	.	PUNCT
eurjchem-604	1989	1	1979	1979	NUM
eurjchem-604	1989	2	,	,	PUNCT
eurjchem-604	1989	3	18(5	18(5	NUM
eurjchem-604	1989	4	)	)	PUNCT
eurjchem-604	1989	5	,	,	PUNCT
eurjchem-604	1989	6	1257‐	1257‐	NUM
eurjchem-604	1989	7	1261	1261	NUM
eurjchem-604	1989	8	.	.	PUNCT
eurjchem-604	1990	1	[	[	X
eurjchem-604	1990	2	286	286	NUM
eurjchem-604	1990	3	]	]	PUNCT
eurjchem-604	1990	4	.	.	PUNCT
eurjchem-604	1991	1	hyla‐kryspin	hyla‐kryspin	PROPN
eurjchem-604	1991	2	,	,	PUNCT
eurjchem-604	1991	3	i.	i.	NOUN
eurjchem-604	1991	4	;	;	PUNCT
eurjchem-604	1991	5	grimme	grimme	PROPN
eurjchem-604	1991	6	,	,	PUNCT
eurjchem-604	1991	7	s.	s.	PROPN
eurjchem-604	1991	8	organometallics	organometallics	PROPN
eurjchem-604	1991	9	2004	2004	NUM
eurjchem-604	1991	10	,	,	PUNCT
eurjchem-604	1991	11	23(23	23(23	NOUN
eurjchem-604	1991	12	)	)	PUNCT
eurjchem-604	1991	13	,	,	PUNCT
eurjchem-604	1991	14	5581‐	5581‐	NUM
eurjchem-604	1991	15	5592	5592	NUM
eurjchem-604	1991	16	.	.	PUNCT
eurjchem-604	1992	1	[	[	X
eurjchem-604	1992	2	287	287	NUM
eurjchem-604	1992	3	]	]	PUNCT
eurjchem-604	1992	4	.	.	PUNCT
eurjchem-604	1993	1	chandra	chandra	PROPN
eurjchem-604	1993	2	,	,	PUNCT
eurjchem-604	1993	3	d.	d.	PROPN
eurjchem-604	1993	4	;	;	PUNCT
eurjchem-604	1993	5	lau	lau	PROPN
eurjchem-604	1993	6	,	,	PUNCT
eurjchem-604	1993	7	k.	k.	PROPN
eurjchem-604	1993	8	h.	h.	PROPN
eurjchem-604	1993	9	;	;	PUNCT
eurjchem-604	1993	10	chien	chien	PROPN
eurjchem-604	1993	11	,	,	PUNCT
eurjchem-604	1993	12	w.	w.	PROPN
eurjchem-604	1993	13	m.	m.	PROPN
eurjchem-604	1993	14	;	;	PUNCT
eurjchem-604	1993	15	garner	garner	NOUN
eurjchem-604	1993	16	,	,	PUNCT
eurjchem-604	1993	17	m.	m.	NOUN
eurjchem-604	1993	18	j.	j.	PROPN
eurjchem-604	1993	19	phys	phys	PROPN
eurjchem-604	1993	20	.	.	PUNCT
eurjchem-604	1994	1	chem	chem	PROPN
eurjchem-604	1994	2	.	.	PUNCT
eurjchem-604	1995	1	solids	solid	NOUN
eurjchem-604	1995	2	2005	2005	NUM
eurjchem-604	1995	3	,	,	PUNCT
eurjchem-604	1995	4	66(2‐4	66(2‐4	NUM
eurjchem-604	1995	5	)	)	PUNCT
eurjchem-604	1995	6	,	,	PUNCT
eurjchem-604	1995	7	241‐245	241‐245	NUM
eurjchem-604	1995	8	.	.	PUNCT
eurjchem-604	1996	1	[	[	X
eurjchem-604	1996	2	288	288	NUM
eurjchem-604	1996	3	]	]	PUNCT
eurjchem-604	1996	4	.	.	PUNCT
eurjchem-604	1997	1	dombek	dombek	PROPN
eurjchem-604	1997	2	,	,	PUNCT
eurjchem-604	1997	3	b.	b.	PROPN
eurjchem-604	1997	4	d.	d.	PROPN
eurjchem-604	1997	5	;	;	PUNCT
eurjchem-604	1997	6	angelci	angelci	PROPN
eurjchem-604	1997	7	,	,	PUNCT
eurjchem-604	1997	8	r.	r.	PROPN
eurjchem-604	1997	9	j.	j.	PROPN
eurjchem-604	1997	10	inorg	inorg	PROPN
eurjchem-604	1997	11	.	.	PUNCT
eurjchem-604	1998	1	chem	chem	PROPN
eurjchem-604	1998	2	.	.	PUNCT
eurjchem-604	1999	1	1976	1976	NUM
eurjchem-604	1999	2	,	,	PUNCT
eurjchem-604	1999	3	15(10	15(10	NUM
eurjchem-604	1999	4	)	)	PUNCT
eurjchem-604	1999	5	,	,	PUNCT
eurjchem-604	1999	6	2403‐2408	2403‐2408	X
eurjchem-604	1999	7	.	.	PUNCT
eurjchem-604	2000	1	[	[	X
eurjchem-604	2000	2	289	289	NUM
eurjchem-604	2000	3	]	]	PUNCT
eurjchem-604	2000	4	.	.	PUNCT
eurjchem-604	2001	1	ardon	ardon	NOUN
eurjchem-604	2001	2	,	,	PUNCT
eurjchem-604	2001	3	m.	m.	NOUN
eurjchem-604	2001	4	;	;	PUNCT
eurjchem-604	2001	5	hogarth	hogarth	NOUN
eurjchem-604	2001	6	,	,	PUNCT
eurjchem-604	2001	7	g.	g.	PROPN
eurjchem-604	2001	8	;	;	PUNCT
eurjchem-604	2001	9	oscroft	oscroft	ADV
eurjchem-604	2001	10	,	,	PUNCT
eurjchem-604	2001	11	d.	d.	PROPN
eurjchem-604	2001	12	t.	t.	PROPN
eurjchem-604	2001	13	w.	w.	PROPN
eurjchem-604	2001	14	j.	j.	PROPN
eurjchem-604	2001	15	organomet	organomet	PROPN
eurjchem-604	2001	16	.	.	PUNCT
eurjchem-604	2002	1	chem	chem	NOUN
eurjchem-604	2002	2	.	.	PUNCT
eurjchem-604	2003	1	2004	2004	NUM
eurjchem-604	2003	2	,	,	PUNCT
eurjchem-604	2003	3	689(15	689(15	NUM
eurjchem-604	2003	4	)	)	PUNCT
eurjchem-604	2003	5	,	,	PUNCT
eurjchem-604	2003	6	2429‐2435	2429‐2435	NUM
eurjchem-604	2003	7	.	.	PUNCT
eurjchem-604	2004	1	[	[	X
eurjchem-604	2004	2	290	290	NUM
eurjchem-604	2004	3	]	]	PUNCT
eurjchem-604	2004	4	.	.	PUNCT
eurjchem-604	2004	5	guillaumont	guillaumont	VERB
eurjchem-604	2004	6	,	,	PUNCT
eurjchem-604	2004	7	d.	d.	PROPN
eurjchem-604	2004	8	;	;	PUNCT
eurjchem-604	2004	9	vlek	vlek	PROPN
eurjchem-604	2004	10	jr	jr	PROPN
eurjchem-604	2004	11	.	.	PUNCT
eurjchem-604	2004	12	a.	a.	PROPN
eurjchem-604	2004	13	;	;	PUNCT
eurjchem-604	2004	14	daniel	daniel	PROPN
eurjchem-604	2004	15	,	,	PUNCT
eurjchem-604	2004	16	c.	c.	PROPN
eurjchem-604	2004	17	j.	j.	PROPN
eurjchem-604	2004	18	phy	phy	PROPN
eurjchem-604	2004	19	.	.	PROPN
eurjchem-604	2004	20	chem	chem	PROPN
eurjchem-604	2004	21	.	.	PUNCT
eurjchem-604	2005	1	a	a	DET
eurjchem-604	2005	2	2001	2001	NUM
eurjchem-604	2005	3	,	,	PUNCT
eurjchem-604	2005	4	105(7	105(7	NUM
eurjchem-604	2005	5	)	)	PUNCT
eurjchem-604	2005	6	,	,	PUNCT
eurjchem-604	2005	7	1107‐1114	1107‐1114	NUM
eurjchem-604	2005	8	.	.	PUNCT
eurjchem-604	2005	9	retracted	retract	VERB
eurjchem-604	2005	10	394	394	NUM
eurjchem-604	2005	11	kaushik	kaushik	NOUN
eurjchem-604	2005	12	et	et	PROPN
eurjchem-604	2005	13	al	al	PROPN
eurjchem-604	2005	14	.	.	PUNCT
eurjchem-604	2005	15	/	/	SYM
eurjchem-604	2005	16	european	european	PROPN
eurjchem-604	2005	17	journal	journal	PROPN
eurjchem-604	2005	18	of	of	ADP
eurjchem-604	2005	19	chemistry	chemistry	NOUN
eurjchem-604	2005	20	3	3	NUM
eurjchem-604	2005	21	(	(	PUNCT
eurjchem-604	2005	22	3	3	NUM
eurjchem-604	2005	23	)	)	PUNCT
eurjchem-604	2005	24	(	(	PUNCT
eurjchem-604	2005	25	2012	2012	NUM
eurjchem-604	2005	26	)	)	PUNCT
eurjchem-604	2005	27	367‐394	367‐394	NOUN
eurjchem-604	2006	1	[	[	X
eurjchem-604	2006	2	291	291	NUM
eurjchem-604	2006	3	]	]	PUNCT
eurjchem-604	2006	4	.	.	PUNCT
eurjchem-604	2006	5	alamiry	alamiry	PROPN
eurjchem-604	2006	6	,	,	PUNCT
eurjchem-604	2006	7	m.	m.	NOUN
eurjchem-604	2006	8	a.	a.	PROPN
eurjchem-604	2006	9	h.	h.	PROPN
eurjchem-604	2006	10	;	;	PUNCT
eurjchem-604	2006	11	brennan	brennan	PROPN
eurjchem-604	2006	12	,	,	PUNCT
eurjchem-604	2006	13	p.	p.	PROPN
eurjchem-604	2006	14	;	;	PUNCT
eurjchem-604	2006	15	long	long	ADV
eurjchem-604	2006	16	,	,	PUNCT
eurjchem-604	2006	17	c.	c.	PROPN
eurjchem-604	2006	18	;	;	PUNCT
eurjchem-604	2006	19	pryce	pryce	PROPN
eurjchem-604	2006	20	,	,	PUNCT
eurjchem-604	2006	21	m.	m.	NOUN
eurjchem-604	2006	22	t.	t.	PROPN
eurjchem-604	2006	23	j.	j.	PROPN
eurjchem-604	2006	24	organomet	organomet	PROPN
eurjchem-604	2006	25	.	.	PUNCT
eurjchem-604	2007	1	chem	chem	NOUN
eurjchem-604	2007	2	.	.	PUNCT
eurjchem-604	2008	1	2008	2008	NUM
eurjchem-604	2008	2	,	,	PUNCT
eurjchem-604	2008	3	693(17	693(17	NUM
eurjchem-604	2008	4	)	)	PUNCT
eurjchem-604	2008	5	,	,	PUNCT
eurjchem-604	2008	6	2907‐2914	2907‐2914	NUM
eurjchem-604	2008	7	.	.	PUNCT
eurjchem-604	2009	1	[	[	X
eurjchem-604	2009	2	292	292	NUM
eurjchem-604	2009	3	]	]	PUNCT
eurjchem-604	2009	4	.	.	PUNCT
eurjchem-604	2010	1	zhang	zhang	PROPN
eurjchem-604	2010	2	,	,	PUNCT
eurjchem-604	2010	3	x.	x.	PROPN
eurjchem-604	2010	4	;	;	PUNCT
eurjchem-604	2010	5	li	li	PROPN
eurjchem-604	2010	6	,	,	PUNCT
eurjchem-604	2010	7	q.	q.	PROPN
eurjchem-604	2010	8	s.	s.	PROPN
eurjchem-604	2010	9	;	;	PUNCT
eurjchem-604	2010	10	ge	ge	PROPN
eurjchem-604	2010	11	,	,	PUNCT
eurjchem-604	2010	12	m.	m.	NOUN
eurjchem-604	2010	13	;	;	PUNCT
eurjchem-604	2010	14	xie	xie	PROPN
eurjchem-604	2010	15	,	,	PUNCT
eurjchem-604	2010	16	y.	y.	PROPN
eurjchem-604	2010	17	;	;	PUNCT
eurjchem-604	2010	18	king	king	PROPN
eurjchem-604	2010	19	,	,	PUNCT
eurjchem-604	2010	20	r.	r.	PROPN
eurjchem-604	2010	21	b.	b.	PROPN
eurjchem-604	2010	22	;	;	PUNCT
eurjchem-604	2010	23	schaefer	schaefer	PROPN
eurjchem-604	2010	24	,	,	PUNCT
eurjchem-604	2010	25	h.	h.	PROPN
eurjchem-604	2010	26	f.	f.	PROPN
eurjchem-604	2010	27	organometallics	organometallics	PROPN
eurjchem-604	2010	28	2	2	NUM
eurjchem-604	2010	29	009	009	NUM
eurjchem-604	2010	30	,	,	PUNCT
eurjchem-604	2010	31	28(9	28(9	NOUN
eurjchem-604	2010	32	)	)	PUNCT
eurjchem-604	2010	33	,	,	PUNCT
eurjchem-604	2010	34	2818‐2829	2818‐2829	NUM
eurjchem-604	2010	35	.	.	PUNCT
eurjchem-604	2011	1	[	[	X
eurjchem-604	2011	2	293	293	NUM
eurjchem-604	2011	3	]	]	PUNCT
eurjchem-604	2011	4	.	.	PUNCT
eurjchem-604	2011	5	palusiak	palusiak	PROPN
eurjchem-604	2011	6	,	,	PUNCT
eurjchem-604	2011	7	m.	m.	NOUN
eurjchem-604	2011	8	;	;	PUNCT
eurjchem-604	2011	9	rudolf	rudolf	PROPN
eurjchem-604	2011	10	,	,	PUNCT
eurjchem-604	2011	11	b.	b.	PROPN
eurjchem-604	2011	12	;	;	PUNCT
eurjchem-604	2011	13	zakrzewski	zakrzewski	PROPN
eurjchem-604	2011	14	,	,	PUNCT
eurjchem-604	2011	15	j.	j.	PROPN
eurjchem-604	2011	16	;	;	PUNCT
eurjchem-604	2011	17	pfitzner	pfitzner	NOUN
eurjchem-604	2011	18	,	,	PUNCT
eurjchem-604	2011	19	a.	a.	NOUN
eurjchem-604	2011	20	;	;	PUNCT
eurjchem-604	2011	21	zabel	zabel	PROPN
eurjchem-604	2011	22	,	,	PUNCT
eurjchem-604	2011	23	m.	m.	NOUN
eurjchem-604	2011	24	;	;	PUNCT
eurjchem-604	2011	25	grabowski	grabowski	PROPN
eurjchem-604	2011	26	,	,	PUNCT
eurjchem-604	2011	27	s.	s.	PROPN
eurjchem-604	2011	28	j.	j.	PROPN
eurjchem-604	2011	29	j.	j.	PROPN
eurjchem-604	2011	30	organomet	organomet	PROPN
eurjchem-604	2011	31	.	.	PUNCT
eurjchem-604	2012	1	chem	chem	NOUN
eurjchem-604	2012	2	.	.	PUNCT
eurjchem-604	2013	1	2006	2006	NUM
eurjchem-604	2013	2	,	,	PUNCT
eurjchem-604	2013	3	691(15	691(15	NUM
eurjchem-604	2013	4	)	)	PUNCT
eurjchem-604	2013	5	,	,	PUNCT
eurjchem-604	2013	6	3232‐3238	3232‐3238	NUM
eurjchem-604	2013	7	.	.	PUNCT
eurjchem-604	2014	1	[	[	X
eurjchem-604	2014	2	294	294	NUM
eurjchem-604	2014	3	]	]	PUNCT
eurjchem-604	2014	4	.	.	PUNCT
eurjchem-604	2015	1	huang	huang	PROPN
eurjchem-604	2015	2	,	,	PUNCT
eurjchem-604	2015	3	y.	y.	PROPN
eurjchem-604	2015	4	;	;	PUNCT
eurjchem-604	2015	5	poissant	poissant	PROPN
eurjchem-604	2015	6	,	,	PUNCT
eurjchem-604	2015	7	r.	r.	PROPN
eurjchem-604	2015	8	r.	r.	PROPN
eurjchem-604	2015	9	langmuir	langmuir	PROPN
eurjchem-604	2015	10	2002	2002	NUM
eurjchem-604	2015	11	,	,	PUNCT
eurjchem-604	2015	12	18(14	18(14	NUM
eurjchem-604	2015	13	)	)	PUNCT
eurjchem-604	2015	14	,	,	PUNCT
eurjchem-604	2015	15	5487‐5496	5487‐5496	NUM
eurjchem-604	2015	16	.	.	PUNCT
eurjchem-604	2016	1	[	[	X
eurjchem-604	2016	2	295	295	NUM
eurjchem-604	2016	3	]	]	SYM
eurjchem-604	2016	4	.	.	PUNCT
eurjchem-604	2017	1	zobi	zobi	PROPN
eurjchem-604	2017	2	,	,	PUNCT
eurjchem-604	2017	3	f.	f.	PROPN
eurjchem-604	2017	4	inorg	inorg	PROPN
eurjchem-604	2017	5	.	.	PUNCT
eurjchem-604	2018	1	chem	chem	PROPN
eurjchem-604	2018	2	.	.	PUNCT
eurjchem-604	2019	1	2010	2010	NUM
eurjchem-604	2019	2	,	,	PUNCT
eurjchem-604	2019	3	49(22	49(22	NOUN
eurjchem-604	2019	4	)	)	PUNCT
eurjchem-604	2019	5	,	,	PUNCT
eurjchem-604	2019	6	10370‐10377	10370‐10377	NUM
eurjchem-604	2019	7	.	.	PUNCT
eurjchem-604	2020	1	[	[	X
eurjchem-604	2020	2	296	296	NUM
eurjchem-604	2020	3	]	]	PUNCT
eurjchem-604	2020	4	.	.	PUNCT
eurjchem-604	2020	5	hermanson	hermanson	PROPN
eurjchem-604	2020	6	,	,	PUNCT
eurjchem-604	2020	7	j.	j.	PROPN
eurjchem-604	2020	8	r.	r.	PROPN
eurjchem-604	2020	9	;	;	PUNCT
eurjchem-604	2020	10	figley	figley	NOUN
eurjchem-604	2020	11	,	,	PUNCT
eurjchem-604	2020	12	t.	t.	NOUN
eurjchem-604	2020	13	m.	m.	NOUN
eurjchem-604	2020	14	;	;	PUNCT
eurjchem-604	2020	15	seibert	seibert	PROPN
eurjchem-604	2020	16	,	,	PUNCT
eurjchem-604	2020	17	a.	a.	PROPN
eurjchem-604	2020	18	l.	l.	PROPN
eurjchem-604	2020	19	;	;	PUNCT
eurjchem-604	2020	20	pinhas	pinha	NOUN
eurjchem-604	2020	21	,	,	PUNCT
eurjchem-604	2020	22	a.	a.	PROPN
eurjchem-604	2020	23	r.	r.	PROPN
eurjchem-604	2020	24	j.	j.	PROPN
eurjchem-604	2020	25	organomet	organomet	PROPN
eurjchem-604	2020	26	.	.	PUNCT
eurjchem-604	2021	1	chem	chem	NOUN
eurjchem-604	2021	2	.	.	PUNCT
eurjchem-604	2022	1	2008	2008	NUM
eurjchem-604	2022	2	,	,	PUNCT
eurjchem-604	2022	3	693(11	693(11	NUM
eurjchem-604	2022	4	)	)	PUNCT
eurjchem-604	2022	5	,	,	PUNCT
eurjchem-604	2022	6	2061‐2064	2061‐2064	X
eurjchem-604	2022	7	.	.	PUNCT
eurjchem-604	2022	8	retracted	retract	VERB