id	sid	tid	token	lemma	pos
eurjchem-624	1	1	untitled	untitle	VERB
eurjchem-624	1	2	european	european	PROPN
eurjchem-624	1	3	journal	journal	PROPN
eurjchem-624	1	4	of	of	ADP
eurjchem-624	1	5	chemistry	chemistry	NOUN
eurjchem-624	1	6	3	3	NUM
eurjchem-624	1	7	(	(	PUNCT
eurjchem-624	1	8	3	3	NUM
eurjchem-624	1	9	)	)	PUNCT
eurjchem-624	1	10	(	(	PUNCT
eurjchem-624	1	11	2012	2012	NUM
eurjchem-624	1	12	)	)	PUNCT
eurjchem-624	1	13	267‐272	267‐272	NUM
eurjchem-624	1	14	european	european	PROPN
eurjchem-624	1	15	journal	journal	PROPN
eurjchem-624	1	16	of	of	ADP
eurjchem-624	1	17	chemistry	chemistry	NOUN
eurjchem-624	1	18	issn	issn	PROPN
eurjchem-624	1	19	2153‐2249	2153‐2249	PROPN
eurjchem-624	1	20	(	(	PUNCT
eurjchem-624	1	21	print	print	NOUN
eurjchem-624	1	22	)	)	PUNCT
eurjchem-624	1	23	/	/	SYM
eurjchem-624	1	24	issn	issn	PROPN
eurjchem-624	1	25	2153‐2257	2153‐2257	NUM
eurjchem-624	1	26	(	(	PUNCT
eurjchem-624	1	27	online	online	ADJ
eurjchem-624	1	28	)	)	PUNCT
eurjchem-624	1	29			NOUN
eurjchem-624	1	30	2012	2012	NUM
eurjchem-624	1	31	eurjchem	eurjchem	PROPN
eurjchem-624	1	32	doi:10.5155	doi:10.5155	ADJ
eurjchem-624	1	33	/	/	SYM
eurjchem-624	1	34	eurjchem.3.3.267‐272.624	eurjchem.3.3.267‐272.624	ADJ
eurjchem-624	1	35	european	european	ADJ
eurjchem-624	1	36	journal	journal	NOUN
eurjchem-624	1	37	of	of	ADP
eurjchem-624	1	38	chemistry	chemistry	PROPN
eurjchem-624	1	39	journal	journal	PROPN
eurjchem-624	1	40	homepage	homepage	NOUN
eurjchem-624	1	41	:	:	PUNCT
eurjchem-624	1	42	www.eurjchem.com	www.eurjchem.com	X
eurjchem-624	1	43	correlation	correlation	NOUN
eurjchem-624	1	44	of	of	ADP
eurjchem-624	1	45	the	the	DET
eurjchem-624	1	46	rates	rate	NOUN
eurjchem-624	1	47	of	of	ADP
eurjchem-624	1	48	solvolysis	solvolysis	NOUN
eurjchem-624	1	49	of	of	ADP
eurjchem-624	1	50	tert‐butyl	tert‐butyl	X
eurjchem-624	1	51	chlorothioformate	chlorothioformate	NOUN
eurjchem-624	1	52	and	and	CCONJ
eurjchem-624	1	53	observations	observation	NOUN
eurjchem-624	1	54	concerning	concern	VERB
eurjchem-624	1	55	the	the	DET
eurjchem-624	1	56	reaction	reaction	NOUN
eurjchem-624	1	57	mechanism	mechanism	NOUN
eurjchem-624	1	58	jin	jin	PROPN
eurjchem-624	1	59	burm	burm	PROPN
eurjchem-624	1	60	kyonga	kyonga	PROPN
eurjchem-624	1	61	,	,	PUNCT
eurjchem-624	1	62	yelin	yelin	PROPN
eurjchem-624	1	63	leea	leea	VERB
eurjchem-624	1	64	,	,	PUNCT
eurjchem-624	1	65	malcolm	malcolm	PROPN
eurjchem-624	1	66	john	john	PROPN
eurjchem-624	1	67	d’souzab	d’souzab	PROPN
eurjchem-624	1	68	,	,	PUNCT
eurjchem-624	1	69	*	*	PROPN
eurjchem-624	1	70	,	,	PUNCT
eurjchem-624	1	71	brian	brian	PROPN
eurjchem-624	1	72	patrick	patrick	PROPN
eurjchem-624	1	73	mahonb	mahonb	PROPN
eurjchem-624	1	74	,	,	PUNCT
eurjchem-624	1	75	and	and	CCONJ
eurjchem-624	1	76	dennis	dennis	PROPN
eurjchem-624	1	77	neil	neil	PROPN
eurjchem-624	1	78	kevillc	kevillc	PROPN
eurjchem-624	1	79	a	a	DET
eurjchem-624	1	80	department	department	NOUN
eurjchem-624	1	81	of	of	ADP
eurjchem-624	1	82	chemistry	chemistry	NOUN
eurjchem-624	1	83	and	and	CCONJ
eurjchem-624	1	84	applied	apply	VERB
eurjchem-624	1	85	chemistry	chemistry	NOUN
eurjchem-624	1	86	,	,	PUNCT
eurjchem-624	1	87	hanyang	hanyang	NOUN
eurjchem-624	1	88	university	university	PROPN
eurjchem-624	1	89	,	,	PUNCT
eurjchem-624	1	90	ansan‐si	ansan‐si	NOUN
eurjchem-624	1	91	,	,	PUNCT
eurjchem-624	1	92	gyeonggi‐do	gyeonggi‐do	PROPN
eurjchem-624	1	93	,	,	PUNCT
eurjchem-624	1	94	426‐791	426‐791	PROPN
eurjchem-624	1	95	,	,	PUNCT
eurjchem-624	1	96	korea	korea	PROPN
eurjchem-624	1	97	b	b	PROPN
eurjchem-624	1	98	department	department	PROPN
eurjchem-624	1	99	of	of	ADP
eurjchem-624	1	100	chemistry	chemistry	NOUN
eurjchem-624	1	101	,	,	PUNCT
eurjchem-624	1	102	wesley	wesley	PROPN
eurjchem-624	1	103	college	college	PROPN
eurjchem-624	1	104	,	,	PUNCT
eurjchem-624	1	105	dover	dover	PROPN
eurjchem-624	1	106	,	,	PUNCT
eurjchem-624	1	107	de	de	PROPN
eurjchem-624	1	108	,	,	PUNCT
eurjchem-624	1	109	19901	19901	NUM
eurjchem-624	1	110	,	,	PUNCT
eurjchem-624	1	111	usa	usa	PROPN
eurjchem-624	1	112	c	c	PROPN
eurjchem-624	1	113	department	department	PROPN
eurjchem-624	1	114	of	of	ADP
eurjchem-624	1	115	chemistry	chemistry	NOUN
eurjchem-624	1	116	and	and	CCONJ
eurjchem-624	1	117	biochemistry	biochemistry	NOUN
eurjchem-624	1	118	,	,	PUNCT
eurjchem-624	1	119	northern	northern	ADJ
eurjchem-624	1	120	illinois	illinois	PROPN
eurjchem-624	1	121	university	university	PROPN
eurjchem-624	1	122	,	,	PUNCT
eurjchem-624	1	123	dekalb	dekalb	PROPN
eurjchem-624	1	124	,	,	PUNCT
eurjchem-624	1	125	il	il	PROPN
eurjchem-624	1	126	,	,	PUNCT
eurjchem-624	1	127	60115	60115	NUM
eurjchem-624	1	128	,	,	PUNCT
eurjchem-624	1	129	usa	usa	PROPN
eurjchem-624	1	130	*	*	PUNCT
eurjchem-624	1	131	corresponding	correspond	VERB
eurjchem-624	1	132	author	author	NOUN
eurjchem-624	1	133	at	at	ADP
eurjchem-624	1	134	:	:	PUNCT
eurjchem-624	1	135	department	department	NOUN
eurjchem-624	1	136	of	of	ADP
eurjchem-624	1	137	chemistry	chemistry	NOUN
eurjchem-624	1	138	,	,	PUNCT
eurjchem-624	1	139	wesley	wesley	PROPN
eurjchem-624	1	140	college	college	PROPN
eurjchem-624	1	141	,	,	PUNCT
eurjchem-624	1	142	dover	dover	PROPN
eurjchem-624	1	143	,	,	PUNCT
eurjchem-624	1	144	de	de	PROPN
eurjchem-624	1	145	,	,	PUNCT
eurjchem-624	1	146	19901	19901	NUM
eurjchem-624	1	147	,	,	PUNCT
eurjchem-624	1	148	usa	usa	PROPN
eurjchem-624	1	149	.	.	PROPN
eurjchem-624	1	150	tel	tel	PROPN
eurjchem-624	1	151	.	.	PUNCT
eurjchem-624	1	152	:	:	PUNCT
eurjchem-624	2	1	+1.302.7362528	+1.302.7362528	X
eurjchem-624	2	2	;	;	PUNCT
eurjchem-624	2	3	fax	fax	NOUN
eurjchem-624	2	4	:	:	PUNCT
eurjchem-624	2	5	+1.302.7362301	+1.302.7362301	PROPN
eurjchem-624	2	6	.	.	PUNCT
eurjchem-624	2	7	e‐mail	e‐mail	PUNCT
eurjchem-624	3	1	address	address	NOUN
eurjchem-624	3	2	:	:	PUNCT
eurjchem-624	3	3	dsouzama@wesley.edu	dsouzama@wesley.edu	PROPN
eurjchem-624	3	4	(	(	PUNCT
eurjchem-624	3	5	m.j	m.j	PROPN
eurjchem-624	3	6	.	.	PROPN
eurjchem-624	3	7	d’souza	d’souza	PROPN
eurjchem-624	3	8	)	)	PUNCT
eurjchem-624	3	9	.	.	PUNCT
eurjchem-624	4	1	article	article	NOUN
eurjchem-624	4	2	information	information	PROPN
eurjchem-624	4	3	abstract	abstract	ADV
eurjchem-624	4	4	received	receive	VERB
eurjchem-624	4	5	:	:	PUNCT
eurjchem-624	4	6	24	24	NUM
eurjchem-624	4	7	april	april	PROPN
eurjchem-624	4	8	2012	2012	NUM
eurjchem-624	4	9	received	receive	VERB
eurjchem-624	4	10	in	in	ADP
eurjchem-624	4	11	revised	revise	VERB
eurjchem-624	4	12	form	form	NOUN
eurjchem-624	4	13	:	:	PUNCT
eurjchem-624	4	14	19	19	NUM
eurjchem-624	4	15	may	may	AUX
eurjchem-624	4	16	2012	2012	NUM
eurjchem-624	4	17	accepted	accept	VERB
eurjchem-624	4	18	:	:	PUNCT
eurjchem-624	4	19	19	19	NUM
eurjchem-624	4	20	may	may	PROPN
eurjchem-624	4	21	2012	2012	NUM
eurjchem-624	4	22	online	online	NOUN
eurjchem-624	4	23	:	:	PUNCT
eurjchem-624	4	24	30	30	NUM
eurjchem-624	4	25	september	september	PROPN
eurjchem-624	4	26	2012	2012	NUM
eurjchem-624	4	27	keywords	keyword	VERB
eurjchem-624	4	28	the	the	DET
eurjchem-624	4	29	“	"	PUNCT
eurjchem-624	4	30	parent	parent	NOUN
eurjchem-624	4	31	”	"	PUNCT
eurjchem-624	4	32	tertiary	tertiary	ADJ
eurjchem-624	4	33	alkyl	alkyl	NOUN
eurjchem-624	4	34	chloroformate	chloroformate	NOUN
eurjchem-624	4	35	,	,	PUNCT
eurjchem-624	4	36	tert‐butyl	tert‐butyl	ADP
eurjchem-624	4	37	chloroformate	chloroformate	NOUN
eurjchem-624	4	38	,	,	PUNCT
eurjchem-624	4	39	is	be	AUX
eurjchem-624	4	40	unstable	unstable	ADJ
eurjchem-624	4	41	,	,	PUNCT
eurjchem-624	4	42	but	but	CCONJ
eurjchem-624	4	43	the	the	DET
eurjchem-624	4	44	tert‐	tert‐	ADJ
eurjchem-624	4	45	butyl	butyl	NOUN
eurjchem-624	4	46	chlorothioformate	chlorothioformate	NOUN
eurjchem-624	4	47	(	(	PUNCT
eurjchem-624	4	48	1	1	X
eurjchem-624	4	49	)	)	PUNCT
eurjchem-624	4	50	is	be	AUX
eurjchem-624	4	51	of	of	ADP
eurjchem-624	4	52	increased	increase	VERB
eurjchem-624	4	53	stability	stability	NOUN
eurjchem-624	4	54	and	and	CCONJ
eurjchem-624	4	55	a	a	DET
eurjchem-624	4	56	kinetic	kinetic	ADJ
eurjchem-624	4	57	investigation	investigation	NOUN
eurjchem-624	4	58	of	of	ADP
eurjchem-624	4	59	the	the	DET
eurjchem-624	4	60	solvolyses	solvolyse	NOUN
eurjchem-624	4	61	is	be	AUX
eurjchem-624	4	62	presented	present	VERB
eurjchem-624	4	63	.	.	PUNCT
eurjchem-624	5	1	analyses	analysis	NOUN
eurjchem-624	5	2	in	in	ADP
eurjchem-624	5	3	terms	term	NOUN
eurjchem-624	5	4	of	of	ADP
eurjchem-624	5	5	simple	simple	ADJ
eurjchem-624	5	6	and	and	CCONJ
eurjchem-624	5	7	extended	extended	ADJ
eurjchem-624	5	8	grunwald‐winstein	grunwald‐winstein	ADJ
eurjchem-624	5	9	equations	equation	NOUN
eurjchem-624	5	10	are	be	AUX
eurjchem-624	5	11	carried	carry	VERB
eurjchem-624	5	12	out	out	ADP
eurjchem-624	5	13	.	.	PUNCT
eurjchem-624	6	1	the	the	DET
eurjchem-624	6	2	original	original	ADJ
eurjchem-624	6	3	one‐term	one‐term	NOUN
eurjchem-624	6	4	equation	equation	NOUN
eurjchem-624	6	5	satisfactorily	satisfactorily	ADV
eurjchem-624	6	6	correlates	correlate	VERB
eurjchem-624	6	7	the	the	DET
eurjchem-624	6	8	data	datum	NOUN
eurjchem-624	6	9	with	with	ADP
eurjchem-624	6	10	sensitivity	sensitivity	NOUN
eurjchem-624	6	11	towards	towards	ADP
eurjchem-624	6	12	changes	change	NOUN
eurjchem-624	6	13	in	in	ADP
eurjchem-624	6	14	solvent	solvent	ADJ
eurjchem-624	6	15	ionizing	ionizing	NOUN
eurjchem-624	6	16	power	power	NOUN
eurjchem-624	6	17	of	of	ADP
eurjchem-624	6	18	0.73±0.03	0.73±0.03	NUM
eurjchem-624	6	19	.	.	PUNCT
eurjchem-624	7	1	when	when	SCONJ
eurjchem-624	7	2	the	the	DET
eurjchem-624	7	3	two‐term	two‐term	NOUN
eurjchem-624	7	4	equation	equation	NOUN
eurjchem-624	7	5	is	be	AUX
eurjchem-624	7	6	applied	apply	VERB
eurjchem-624	7	7	,	,	PUNCT
eurjchem-624	7	8	the	the	DET
eurjchem-624	7	9	sensitivity	sensitivity	NOUN
eurjchem-624	7	10	towards	towards	ADP
eurjchem-624	7	11	changes	change	NOUN
eurjchem-624	7	12	in	in	ADP
eurjchem-624	7	13	solvent	solvent	ADJ
eurjchem-624	7	14	nucleophilicity	nucleophilicity	NOUN
eurjchem-624	7	15	of	of	ADP
eurjchem-624	7	16	0.13±0.09	0.13±0.09	PROPN
eurjchem-624	7	17	is	be	AUX
eurjchem-624	7	18	associated	associate	VERB
eurjchem-624	7	19	with	with	ADP
eurjchem-624	7	20	a	a	DET
eurjchem-624	7	21	high	high	ADJ
eurjchem-624	7	22	(	(	PUNCT
eurjchem-624	7	23	0.17	0.17	NUM
eurjchem-624	7	24	)	)	PUNCT
eurjchem-624	7	25	probability	probability	NOUN
eurjchem-624	7	26	that	that	SCONJ
eurjchem-624	7	27	the	the	DET
eurjchem-624	7	28	term	term	NOUN
eurjchem-624	7	29	that	that	PRON
eurjchem-624	7	30	it	it	PRON
eurjchem-624	7	31	governs	govern	VERB
eurjchem-624	7	32	is	be	AUX
eurjchem-624	7	33	not	not	PART
eurjchem-624	7	34	statistically	statistically	ADV
eurjchem-624	7	35	significant	significant	ADJ
eurjchem-624	7	36	.	.	PUNCT
eurjchem-624	8	1	solvolysis	solvolysis	NOUN
eurjchem-624	8	2	ionization	ionization	NOUN
eurjchem-624	8	3	addition‐elimination	addition‐elimination	NOUN
eurjchem-624	8	4	activation	activation	NOUN
eurjchem-624	8	5	parameters	parameter	NOUN
eurjchem-624	8	6	tert‐butyl	tert‐butyl	ADP
eurjchem-624	8	7	chlorothioformate	chlorothioformate	VERB
eurjchem-624	8	8	grunwald‐winstein	grunwald‐winstein	ADJ
eurjchem-624	8	9	equations	equation	NOUN
eurjchem-624	8	10	1	1	NUM
eurjchem-624	8	11	.	.	PUNCT
eurjchem-624	9	1	introduction	introduction	NOUN
eurjchem-624	9	2	there	there	PRON
eurjchem-624	9	3	have	have	AUX
eurjchem-624	9	4	been	be	AUX
eurjchem-624	9	5	extensive	extensive	ADJ
eurjchem-624	9	6	studies	study	NOUN
eurjchem-624	9	7	of	of	ADP
eurjchem-624	9	8	the	the	DET
eurjchem-624	9	9	solvolyses	solvolyse	NOUN
eurjchem-624	9	10	of	of	ADP
eurjchem-624	9	11	chloroformate	chloroformate	ADJ
eurjchem-624	9	12	esters	ester	NOUN
eurjchem-624	9	13	[	[	X
eurjchem-624	9	14	1	1	NUM
eurjchem-624	9	15	]	]	PUNCT
eurjchem-624	9	16	.	.	PUNCT
eurjchem-624	10	1	recent	recent	ADJ
eurjchem-624	10	2	studies	study	NOUN
eurjchem-624	10	3	have	have	AUX
eurjchem-624	10	4	included	include	VERB
eurjchem-624	10	5	the	the	DET
eurjchem-624	10	6	application	application	NOUN
eurjchem-624	10	7	of	of	ADP
eurjchem-624	10	8	linear	linear	PROPN
eurjchem-624	10	9	free	free	ADJ
eurjchem-624	10	10	energy	energy	NOUN
eurjchem-624	10	11	relationships	relationship	NOUN
eurjchem-624	10	12	(	(	PUNCT
eurjchem-624	10	13	lfers	lfer	NOUN
eurjchem-624	10	14	)	)	PUNCT
eurjchem-624	10	15	,	,	PUNCT
eurjchem-624	10	16	such	such	ADJ
eurjchem-624	10	17	as	as	ADP
eurjchem-624	10	18	the	the	DET
eurjchem-624	10	19	grunwald‐winstein	grunwald‐winstein	ADJ
eurjchem-624	10	20	(	(	PUNCT
eurjchem-624	10	21	g‐w	g‐w	NOUN
eurjchem-624	10	22	)	)	PUNCT
eurjchem-624	10	23	equation	equation	NOUN
eurjchem-624	10	24	[	[	X
eurjchem-624	10	25	2‐4	2‐4	NUM
eurjchem-624	10	26	]	]	PUNCT
eurjchem-624	10	27	,	,	PUNCT
eurjchem-624	10	28	which	which	PRON
eurjchem-624	10	29	consider	consider	VERB
eurjchem-624	10	30	the	the	DET
eurjchem-624	10	31	influence	influence	NOUN
eurjchem-624	10	32	of	of	ADP
eurjchem-624	10	33	changes	change	NOUN
eurjchem-624	10	34	in	in	ADP
eurjchem-624	10	35	solvent	solvent	ADJ
eurjchem-624	10	36	composition	composition	NOUN
eurjchem-624	10	37	on	on	ADP
eurjchem-624	10	38	the	the	DET
eurjchem-624	10	39	rates	rate	NOUN
eurjchem-624	10	40	of	of	ADP
eurjchem-624	10	41	solvolysis	solvolysis	NOUN
eurjchem-624	10	42	reactions	reaction	NOUN
eurjchem-624	10	43	.	.	PUNCT
eurjchem-624	11	1	in	in	ADP
eurjchem-624	11	2	the	the	DET
eurjchem-624	11	3	present	present	ADJ
eurjchem-624	11	4	study	study	NOUN
eurjchem-624	11	5	,	,	PUNCT
eurjchem-624	11	6	we	we	PRON
eurjchem-624	11	7	consider	consider	VERB
eurjchem-624	11	8	the	the	DET
eurjchem-624	11	9	solvolyses	solvolyse	NOUN
eurjchem-624	11	10	of	of	ADP
eurjchem-624	11	11	a	a	DET
eurjchem-624	11	12	tertiary	tertiary	ADJ
eurjchem-624	11	13	alkyl	alkyl	NOUN
eurjchem-624	11	14	chlorothioformate	chlorothioformate	NOUN
eurjchem-624	11	15	(	(	PUNCT
eurjchem-624	11	16	t‐buscocl	t‐buscocl	NUM
eurjchem-624	11	17	,	,	PUNCT
eurjchem-624	11	18	1	1	NUM
eurjchem-624	11	19	)	)	PUNCT
eurjchem-624	11	20	.	.	PUNCT
eurjchem-624	12	1	it	it	PRON
eurjchem-624	12	2	has	have	AUX
eurjchem-624	12	3	previously	previously	ADV
eurjchem-624	12	4	been	be	AUX
eurjchem-624	12	5	shown	show	VERB
eurjchem-624	12	6	[	[	PUNCT
eurjchem-624	12	7	5‐9	5‐9	NOUN
eurjchem-624	12	8	]	]	PUNCT
eurjchem-624	12	9	for	for	ADP
eurjchem-624	12	10	chloroformates	chloroformate	NOUN
eurjchem-624	12	11	that	that	SCONJ
eurjchem-624	12	12	the	the	DET
eurjchem-624	12	13	replacement	replacement	NOUN
eurjchem-624	12	14	of	of	ADP
eurjchem-624	12	15	the	the	DET
eurjchem-624	12	16	alkoxy	alkoxy	ADJ
eurjchem-624	12	17	oxygen	oxygen	NOUN
eurjchem-624	12	18	by	by	ADP
eurjchem-624	12	19	sulfur	sulfur	NOUN
eurjchem-624	12	20	leads	lead	VERB
eurjchem-624	12	21	to	to	ADP
eurjchem-624	12	22	a	a	DET
eurjchem-624	12	23	move	move	NOUN
eurjchem-624	12	24	,	,	PUNCT
eurjchem-624	12	25	away	away	ADV
eurjchem-624	12	26	from	from	ADP
eurjchem-624	12	27	an	an	DET
eurjchem-624	12	28	addition‐elimination	addition‐elimination	NOUN
eurjchem-624	12	29	mechanism	mechanism	NOUN
eurjchem-624	12	30	(	(	PUNCT
eurjchem-624	12	31	scheme	scheme	NOUN
eurjchem-624	12	32	1	1	NUM
eurjchem-624	12	33	)	)	PUNCT
eurjchem-624	12	34	towards	towards	ADP
eurjchem-624	12	35	one	one	NUM
eurjchem-624	12	36	of	of	ADP
eurjchem-624	12	37	several	several	ADJ
eurjchem-624	12	38	possible	possible	ADJ
eurjchem-624	12	39	ionization	ionization	NOUN
eurjchem-624	12	40	mechanisms	mechanism	NOUN
eurjchem-624	12	41	(	(	PUNCT
eurjchem-624	12	42	scheme	scheme	NOUN
eurjchem-624	12	43	2	2	NUM
eurjchem-624	12	44	)	)	PUNCT
eurjchem-624	12	45	.	.	PUNCT
eurjchem-624	13	1	scheme	scheme	NOUN
eurjchem-624	13	2	1	1	NUM
eurjchem-624	13	3	the	the	DET
eurjchem-624	13	4	original	original	ADJ
eurjchem-624	13	5	grunwald‐winstein	grunwald‐winstein	ADJ
eurjchem-624	13	6	(	(	PUNCT
eurjchem-624	13	7	g‐w	g‐w	NOUN
eurjchem-624	13	8	)	)	PUNCT
eurjchem-624	13	9	equation	equation	NOUN
eurjchem-624	13	10	employed	employ	VERB
eurjchem-624	13	11	tert‐butyl	tert‐butyl	ADP
eurjchem-624	13	12	chloride	chloride	NOUN
eurjchem-624	13	13	as	as	ADP
eurjchem-624	13	14	the	the	DET
eurjchem-624	13	15	standard	standard	ADJ
eurjchem-624	13	16	substrate	substrate	NOUN
eurjchem-624	13	17	and	and	CCONJ
eurjchem-624	13	18	80	80	NUM
eurjchem-624	13	19	%	%	NOUN
eurjchem-624	13	20	ethanol	ethanol	NOUN
eurjchem-624	13	21	as	as	ADP
eurjchem-624	13	22	the	the	DET
eurjchem-624	13	23	standard	standard	ADJ
eurjchem-624	13	24	solvent	solvent	NOUN
eurjchem-624	13	25	(	(	PUNCT
eurjchem-624	13	26	equation	equation	NOUN
eurjchem-624	13	27	1	1	NUM
eurjchem-624	13	28	)	)	PUNCT
eurjchem-624	13	29	.	.	PUNCT
eurjchem-624	14	1	log	log	NOUN
eurjchem-624	14	2	(	(	PUNCT
eurjchem-624	14	3	k	k	NOUN
eurjchem-624	14	4	/	/	SYM
eurjchem-624	14	5	ko	ko	PROPN
eurjchem-624	14	6	)	)	PUNCT
eurjchem-624	15	1	=	=	PUNCT
eurjchem-624	16	1	my	my	PRON
eurjchem-624	16	2	+	+	X
eurjchem-624	16	3	c	c	X
eurjchem-624	16	4	(	(	PUNCT
eurjchem-624	16	5	1	1	NUM
eurjchem-624	16	6	)	)	PUNCT
eurjchem-624	16	7	in	in	ADP
eurjchem-624	16	8	equation	equation	NOUN
eurjchem-624	16	9	1	1	NUM
eurjchem-624	16	10	,	,	PUNCT
eurjchem-624	16	11	k	k	NOUN
eurjchem-624	16	12	,	,	PUNCT
eurjchem-624	16	13	and	and	CCONJ
eurjchem-624	16	14	ko	ko	PROPN
eurjchem-624	16	15	are	be	AUX
eurjchem-624	16	16	the	the	DET
eurjchem-624	16	17	specific	specific	ADJ
eurjchem-624	16	18	rates	rate	NOUN
eurjchem-624	16	19	of	of	ADP
eurjchem-624	16	20	solvolysis	solvolysis	NOUN
eurjchem-624	16	21	(	(	PUNCT
eurjchem-624	16	22	first‐order	first‐order	NOUN
eurjchem-624	16	23	rate	rate	NOUN
eurjchem-624	16	24	coefficients	coefficient	NOUN
eurjchem-624	16	25	)	)	PUNCT
eurjchem-624	16	26	in	in	ADP
eurjchem-624	16	27	the	the	DET
eurjchem-624	16	28	solvent	solvent	NOUN
eurjchem-624	16	29	under	under	ADP
eurjchem-624	16	30	consideration	consideration	NOUN
eurjchem-624	16	31	and	and	CCONJ
eurjchem-624	16	32	in	in	ADP
eurjchem-624	16	33	the	the	DET
eurjchem-624	16	34	standard	standard	ADJ
eurjchem-624	16	35	solvent	solvent	NOUN
eurjchem-624	16	36	respectively	respectively	ADV
eurjchem-624	16	37	,	,	PUNCT
eurjchem-624	16	38	m	m	VERB
eurjchem-624	16	39	is	be	AUX
eurjchem-624	16	40	a	a	DET
eurjchem-624	16	41	measure	measure	NOUN
eurjchem-624	16	42	of	of	ADP
eurjchem-624	16	43	the	the	DET
eurjchem-624	16	44	sensitivity	sensitivity	NOUN
eurjchem-624	16	45	of	of	ADP
eurjchem-624	16	46	the	the	DET
eurjchem-624	16	47	specific	specific	ADJ
eurjchem-624	16	48	rate	rate	NOUN
eurjchem-624	16	49	of	of	ADP
eurjchem-624	16	50	solvolysis	solvolysis	NOUN
eurjchem-624	16	51	towards	towards	ADP
eurjchem-624	16	52	changes	change	NOUN
eurjchem-624	16	53	in	in	ADP
eurjchem-624	16	54	solvent	solvent	ADJ
eurjchem-624	16	55	ionizing	ionizing	NOUN
eurjchem-624	16	56	power	power	NOUN
eurjchem-624	16	57	(	(	PUNCT
eurjchem-624	16	58	y	y	NOUN
eurjchem-624	16	59	)	)	PUNCT
eurjchem-624	16	60	.	.	PUNCT
eurjchem-624	17	1	the	the	DET
eurjchem-624	17	2	y	y	PROPN
eurjchem-624	17	3	values	value	NOUN
eurjchem-624	17	4	are	be	AUX
eurjchem-624	17	5	based	base	VERB
eurjchem-624	17	6	on	on	ADP
eurjchem-624	17	7	the	the	DET
eurjchem-624	17	8	specific	specific	ADJ
eurjchem-624	17	9	rates	rate	NOUN
eurjchem-624	17	10	of	of	ADP
eurjchem-624	17	11	solvolysis	solvolysis	NOUN
eurjchem-624	17	12	of	of	ADP
eurjchem-624	17	13	the	the	DET
eurjchem-624	17	14	standard	standard	ADJ
eurjchem-624	17	15	substrate	substrate	NOUN
eurjchem-624	17	16	with	with	ADP
eurjchem-624	17	17	m	m	PROPN
eurjchem-624	17	18	set	set	VERB
eurjchem-624	17	19	at	at	ADP
eurjchem-624	17	20	unity	unity	NOUN
eurjchem-624	17	21	and	and	CCONJ
eurjchem-624	17	22	c	c	NOUN
eurjchem-624	17	23	at	at	ADP
eurjchem-624	17	24	zero	zero	NUM
eurjchem-624	17	25	[	[	X
eurjchem-624	17	26	2	2	NUM
eurjchem-624	17	27	]	]	PUNCT
eurjchem-624	17	28	.	.	PUNCT
eurjchem-624	18	1	subsequently	subsequently	ADV
eurjchem-624	18	2	,	,	PUNCT
eurjchem-624	18	3	it	it	PRON
eurjchem-624	18	4	was	be	AUX
eurjchem-624	18	5	realized	realize	VERB
eurjchem-624	18	6	that	that	SCONJ
eurjchem-624	18	7	the	the	DET
eurjchem-624	18	8	solvolyses	solvolyse	NOUN
eurjchem-624	18	9	of	of	ADP
eurjchem-624	18	10	1‐adamantyl	1‐adamantyl	NUM
eurjchem-624	18	11	or	or	CCONJ
eurjchem-624	18	12	2‐adamantyl	2‐adamantyl	NUM
eurjchem-624	18	13	derivatives	derivative	NOUN
eurjchem-624	18	14	(	(	PUNCT
eurjchem-624	18	15	1‐adx	1‐adx	NUM
eurjchem-624	18	16	or	or	CCONJ
eurjchem-624	18	17	2‐adx	2‐adx	NUM
eurjchem-624	18	18	)	)	PUNCT
eurjchem-624	18	19	,	,	PUNCT
eurjchem-624	18	20	incorporating	incorporate	VERB
eurjchem-624	18	21	the	the	DET
eurjchem-624	18	22	adamantane	adamantane	NOUN
eurjchem-624	18	23	cage	cage	NOUN
eurjchem-624	18	24	attached	attach	VERB
eurjchem-624	18	25	to	to	ADP
eurjchem-624	18	26	a	a	DET
eurjchem-624	18	27	leaving	leave	VERB
eurjchem-624	18	28	group	group	NOUN
eurjchem-624	18	29	x	x	NOUN
eurjchem-624	18	30	,	,	PUNCT
eurjchem-624	18	31	minimized	minimize	VERB
eurjchem-624	18	32	the	the	DET
eurjchem-624	18	33	extent	extent	NOUN
eurjchem-624	18	34	of	of	ADP
eurjchem-624	18	35	nucleophilic	nucleophilic	ADJ
eurjchem-624	18	36	assistance	assistance	NOUN
eurjchem-624	18	37	to	to	ADP
eurjchem-624	18	38	the	the	DET
eurjchem-624	18	39	ionization	ionization	NOUN
eurjchem-624	18	40	process	process	NOUN
eurjchem-624	18	41	[	[	X
eurjchem-624	18	42	10‐12	10‐12	NUM
eurjchem-624	18	43	]	]	PUNCT
eurjchem-624	18	44	.	.	PUNCT
eurjchem-624	19	1	discussions	discussion	NOUN
eurjchem-624	19	2	of	of	ADP
eurjchem-624	19	3	the	the	DET
eurjchem-624	19	4	development	development	NOUN
eurjchem-624	19	5	of	of	ADP
eurjchem-624	19	6	y	y	PROPN
eurjchem-624	19	7	scales	scale	NOUN
eurjchem-624	19	8	and	and	CCONJ
eurjchem-624	19	9	values	value	NOUN
eurjchem-624	19	10	for	for	ADP
eurjchem-624	19	11	a	a	DET
eurjchem-624	19	12	wide	wide	ADJ
eurjchem-624	19	13	variety	variety	NOUN
eurjchem-624	19	14	of	of	ADP
eurjchem-624	19	15	yx	yx	NOUN
eurjchem-624	19	16	scales	scale	NOUN
eurjchem-624	19	17	have	have	AUX
eurjchem-624	19	18	previously	previously	ADV
eurjchem-624	19	19	been	be	AUX
eurjchem-624	19	20	presented	present	VERB
eurjchem-624	19	21	[	[	X
eurjchem-624	19	22	4,13	4,13	X
eurjchem-624	19	23	]	]	PUNCT
eurjchem-624	19	24	.	.	PUNCT
eurjchem-624	20	1	(	(	PUNCT
eurjchem-624	20	2	a	a	X
eurjchem-624	20	3	)	)	PUNCT
eurjchem-624	20	4	unimolecular	unimolecular	ADJ
eurjchem-624	20	5	solvolyses	solvolyse	VERB
eurjchem-624	20	6	(	(	PUNCT
eurjchem-624	20	7	b	b	NOUN
eurjchem-624	20	8	)	)	PUNCT
eurjchem-624	20	9	unimolecular	unimolecular	ADJ
eurjchem-624	20	10	solvolysis‐decomposition	solvolysis‐decomposition	NOUN
eurjchem-624	20	11	scheme	scheme	NOUN
eurjchem-624	20	12	2	2	NUM
eurjchem-624	20	13	268	268	NUM
eurjchem-624	20	14	d'souza	d'souza	PROPN
eurjchem-624	20	15	et	et	PROPN
eurjchem-624	20	16	al	al	PROPN
eurjchem-624	20	17	.	.	PUNCT
eurjchem-624	20	18	/	/	SYM
eurjchem-624	20	19	european	european	PROPN
eurjchem-624	20	20	journal	journal	PROPN
eurjchem-624	20	21	of	of	ADP
eurjchem-624	20	22	chemistry	chemistry	NOUN
eurjchem-624	20	23	3	3	NUM
eurjchem-624	20	24	(	(	PUNCT
eurjchem-624	20	25	3	3	NUM
eurjchem-624	20	26	)	)	PUNCT
eurjchem-624	20	27	(	(	PUNCT
eurjchem-624	20	28	2012	2012	NUM
eurjchem-624	20	29	)	)	PUNCT
eurjchem-624	20	30	267‐272	267‐272	NUM
eurjchem-624	20	31	while	while	SCONJ
eurjchem-624	20	32	there	there	PRON
eurjchem-624	20	33	was	be	VERB
eurjchem-624	20	34	some	some	DET
eurjchem-624	20	35	success	success	NOUN
eurjchem-624	20	36	in	in	ADP
eurjchem-624	20	37	applying	apply	VERB
eurjchem-624	20	38	the	the	DET
eurjchem-624	20	39	original	original	ADJ
eurjchem-624	20	40	form	form	NOUN
eurjchem-624	20	41	of	of	ADP
eurjchem-624	20	42	the	the	DET
eurjchem-624	20	43	equation	equation	NOUN
eurjchem-624	20	44	to	to	ADP
eurjchem-624	20	45	bimolecular	bimolecular	ADJ
eurjchem-624	20	46	solvolyses	solvolyse	NOUN
eurjchem-624	20	47	for	for	ADP
eurjchem-624	20	48	a	a	DET
eurjchem-624	20	49	series	series	NOUN
eurjchem-624	20	50	of	of	ADP
eurjchem-624	20	51	aqueous‐organic	aqueous‐organic	ADJ
eurjchem-624	20	52	solvent	solvent	ADJ
eurjchem-624	20	53	compositions	composition	NOUN
eurjchem-624	20	54	for	for	ADP
eurjchem-624	20	55	a	a	DET
eurjchem-624	20	56	given	give	VERB
eurjchem-624	20	57	organic	organic	ADJ
eurjchem-624	20	58	component	component	NOUN
eurjchem-624	21	1	[	[	X
eurjchem-624	21	2	3	3	NUM
eurjchem-624	21	3	]	]	PUNCT
eurjchem-624	21	4	,	,	PUNCT
eurjchem-624	21	5	it	it	PRON
eurjchem-624	21	6	was	be	AUX
eurjchem-624	21	7	realized	realize	VERB
eurjchem-624	21	8	that	that	SCONJ
eurjchem-624	21	9	for	for	ADP
eurjchem-624	21	10	an	an	DET
eurjchem-624	21	11	application	application	NOUN
eurjchem-624	21	12	involving	involve	VERB
eurjchem-624	21	13	a	a	DET
eurjchem-624	21	14	single	single	ADJ
eurjchem-624	21	15	lfer	lfer	NOUN
eurjchem-624	21	16	for	for	ADP
eurjchem-624	21	17	solvolyses	solvolyse	NOUN
eurjchem-624	21	18	in	in	ADP
eurjchem-624	21	19	a	a	DET
eurjchem-624	21	20	series	series	NOUN
eurjchem-624	21	21	of	of	ADP
eurjchem-624	21	22	aqueous‐organic	aqueous‐organic	ADJ
eurjchem-624	21	23	mixtures	mixture	NOUN
eurjchem-624	21	24	an	an	DET
eurjchem-624	21	25	extended	extended	ADJ
eurjchem-624	21	26	approach	approach	NOUN
eurjchem-624	21	27	would	would	AUX
eurjchem-624	21	28	be	be	AUX
eurjchem-624	21	29	required	require	VERB
eurjchem-624	21	30	,	,	PUNCT
eurjchem-624	21	31	and	and	CCONJ
eurjchem-624	21	32	this	this	PRON
eurjchem-624	21	33	led	lead	VERB
eurjchem-624	21	34	to	to	ADP
eurjchem-624	21	35	the	the	DET
eurjchem-624	21	36	addition	addition	NOUN
eurjchem-624	21	37	of	of	ADP
eurjchem-624	21	38	a	a	DET
eurjchem-624	21	39	second	second	ADJ
eurjchem-624	21	40	term	term	NOUN
eurjchem-624	21	41	to	to	PART
eurjchem-624	21	42	give	give	VERB
eurjchem-624	21	43	the	the	DET
eurjchem-624	21	44	original	original	ADJ
eurjchem-624	21	45	(	(	PUNCT
eurjchem-624	21	46	extended	extended	ADJ
eurjchem-624	21	47	)	)	PUNCT
eurjchem-624	21	48	two‐term	two‐term	ADP
eurjchem-624	21	49	g‐w	g‐w	PROPN
eurjchem-624	21	50	equation	equation	NOUN
eurjchem-624	21	51	[	[	X
eurjchem-624	21	52	equation	equation	NOUN
eurjchem-624	21	53	2	2	NUM
eurjchem-624	21	54	]	]	PUNCT
eurjchem-624	21	55	.	.	PUNCT
eurjchem-624	22	1	log	log	NOUN
eurjchem-624	22	2	(	(	PUNCT
eurjchem-624	22	3	k	k	NOUN
eurjchem-624	22	4	/	/	SYM
eurjchem-624	22	5	ko	ko	PROPN
eurjchem-624	22	6	)	)	PUNCT
eurjchem-624	22	7	=	=	PUNCT
eurjchem-624	23	1	ln	ln	NOUN
eurjchem-624	24	1	+	+	CCONJ
eurjchem-624	24	2	my	my	PRON
eurjchem-624	24	3	+	+	X
eurjchem-624	24	4	c	c	X
eurjchem-624	24	5	(	(	PUNCT
eurjchem-624	24	6	2	2	NUM
eurjchem-624	24	7	)	)	PUNCT
eurjchem-624	24	8	the	the	DET
eurjchem-624	24	9	additional	additional	ADJ
eurjchem-624	24	10	term	term	NOUN
eurjchem-624	24	11	involves	involve	VERB
eurjchem-624	24	12	the	the	DET
eurjchem-624	24	13	sensitivity	sensitivity	NOUN
eurjchem-624	24	14	l	l	NOUN
eurjchem-624	24	15	to	to	ADP
eurjchem-624	24	16	changes	change	NOUN
eurjchem-624	24	17	in	in	ADP
eurjchem-624	24	18	solvent	solvent	ADJ
eurjchem-624	24	19	nucleophilicity	nucleophilicity	NOUN
eurjchem-624	24	20	n.	n.	PROPN
eurjchem-624	24	21	initially	initially	ADV
eurjchem-624	24	22	this	this	DET
eurjchem-624	24	23	scale	scale	NOUN
eurjchem-624	24	24	was	be	AUX
eurjchem-624	24	25	set	set	VERB
eurjchem-624	24	26	up	up	ADP
eurjchem-624	24	27	using	use	VERB
eurjchem-624	24	28	methyl	methyl	NOUN
eurjchem-624	24	29	p‐toluenesulfonate	p‐toluenesulfonate	PUNCT
eurjchem-624	24	30	(	(	PUNCT
eurjchem-624	24	31	tosylate	tosylate	VERB
eurjchem-624	24	32	)	)	PUNCT
eurjchem-624	24	33	as	as	ADP
eurjchem-624	24	34	the	the	DET
eurjchem-624	24	35	standard	standard	ADJ
eurjchem-624	24	36	substrate	substrate	NOUN
eurjchem-624	24	37	(	(	PUNCT
eurjchem-624	24	38	l	l	NOUN
eurjchem-624	24	39	=	=	SYM
eurjchem-624	24	40	1	1	NUM
eurjchem-624	24	41	;	;	PUNCT
eurjchem-624	24	42	c	c	X
eurjchem-624	24	43	=	=	SYM
eurjchem-624	24	44	0	0	NUM
eurjchem-624	24	45	)	)	PUNCT
eurjchem-624	25	1	[	[	X
eurjchem-624	25	2	14	14	NUM
eurjchem-624	25	3	]	]	PUNCT
eurjchem-624	25	4	,	,	PUNCT
eurjchem-624	25	5	but	but	CCONJ
eurjchem-624	25	6	there	there	PRON
eurjchem-624	25	7	was	be	VERB
eurjchem-624	25	8	no	no	DET
eurjchem-624	25	9	rigid	rigid	ADJ
eurjchem-624	25	10	way	way	NOUN
eurjchem-624	25	11	to	to	PART
eurjchem-624	25	12	arrive	arrive	VERB
eurjchem-624	25	13	at	at	ADP
eurjchem-624	25	14	the	the	DET
eurjchem-624	25	15	required	require	VERB
eurjchem-624	25	16	m	m	NOUN
eurjchem-624	25	17	value	value	NOUN
eurjchem-624	25	18	for	for	ADP
eurjchem-624	25	19	the	the	DET
eurjchem-624	25	20	process	process	NOUN
eurjchem-624	25	21	[	[	X
eurjchem-624	25	22	15	15	NUM
eurjchem-624	25	23	]	]	PUNCT
eurjchem-624	25	24	.	.	PUNCT
eurjchem-624	26	1	use	use	NOUN
eurjchem-624	26	2	of	of	ADP
eurjchem-624	26	3	an	an	DET
eurjchem-624	26	4	initially	initially	ADV
eurjchem-624	26	5	positively	positively	ADV
eurjchem-624	26	6	charged	charge	VERB
eurjchem-624	26	7	leaving	leaving	NOUN
eurjchem-624	26	8	group	group	NOUN
eurjchem-624	26	9	,	,	PUNCT
eurjchem-624	26	10	leaving	leave	VERB
eurjchem-624	26	11	as	as	ADP
eurjchem-624	26	12	a	a	DET
eurjchem-624	26	13	neutral	neutral	ADJ
eurjchem-624	26	14	molecule	molecule	NOUN
eurjchem-624	26	15	,	,	PUNCT
eurjchem-624	26	16	minimizes	minimize	VERB
eurjchem-624	26	17	the	the	DET
eurjchem-624	26	18	need	need	NOUN
eurjchem-624	26	19	to	to	PART
eurjchem-624	26	20	consider	consider	VERB
eurjchem-624	26	21	leaving‐group	leaving‐group	NOUN
eurjchem-624	26	22	influences	influence	NOUN
eurjchem-624	26	23	[	[	X
eurjchem-624	26	24	15,16	15,16	NUM
eurjchem-624	26	25	]	]	PUNCT
eurjchem-624	26	26	and	and	CCONJ
eurjchem-624	26	27	the	the	DET
eurjchem-624	26	28	s‐methyldibenzothiophenium	s‐methyldibenzothiophenium	NOUN
eurjchem-624	26	29	ion	ion	NOUN
eurjchem-624	26	30	is	be	AUX
eurjchem-624	26	31	usually	usually	ADV
eurjchem-624	26	32	chosen	choose	VERB
eurjchem-624	26	33	as	as	ADP
eurjchem-624	26	34	the	the	DET
eurjchem-624	26	35	standard	standard	ADJ
eurjchem-624	26	36	substrate	substrate	NOUN
eurjchem-624	26	37	,	,	PUNCT
eurjchem-624	26	38	to	to	PART
eurjchem-624	26	39	yield	yield	VERB
eurjchem-624	26	40	the	the	DET
eurjchem-624	26	41	nt	nt	ADJ
eurjchem-624	26	42	scale	scale	NOUN
eurjchem-624	26	43	[	[	X
eurjchem-624	26	44	16	16	NUM
eurjchem-624	26	45	]	]	PUNCT
eurjchem-624	26	46	.	.	PUNCT
eurjchem-624	27	1	the	the	DET
eurjchem-624	27	2	development	development	NOUN
eurjchem-624	27	3	and	and	CCONJ
eurjchem-624	27	4	uses	use	NOUN
eurjchem-624	27	5	of	of	ADP
eurjchem-624	27	6	this	this	DET
eurjchem-624	27	7	scale	scale	NOUN
eurjchem-624	27	8	has	have	AUX
eurjchem-624	27	9	been	be	AUX
eurjchem-624	27	10	reviewed	review	VERB
eurjchem-624	27	11	[	[	X
eurjchem-624	27	12	4,17	4,17	NOUN
eurjchem-624	27	13	]	]	PUNCT
eurjchem-624	27	14	.	.	PUNCT
eurjchem-624	28	1	studies	study	NOUN
eurjchem-624	28	2	involving	involve	VERB
eurjchem-624	28	3	the	the	DET
eurjchem-624	28	4	application	application	NOUN
eurjchem-624	28	5	of	of	ADP
eurjchem-624	28	6	the	the	DET
eurjchem-624	28	7	g‐w	g‐w	PROPN
eurjchem-624	28	8	equation	equation	NOUN
eurjchem-624	28	9	to	to	PART
eurjchem-624	28	10	chloroformate	chloroformate	VERB
eurjchem-624	28	11	esters	ester	NOUN
eurjchem-624	28	12	have	have	AUX
eurjchem-624	28	13	included	include	VERB
eurjchem-624	28	14	the	the	DET
eurjchem-624	28	15	methyl	methyl	NOUN
eurjchem-624	28	16	ester	ester	NOUN
eurjchem-624	28	17	[	[	X
eurjchem-624	28	18	18	18	NUM
eurjchem-624	28	19	]	]	PUNCT
eurjchem-624	28	20	,	,	PUNCT
eurjchem-624	28	21	examples	example	NOUN
eurjchem-624	28	22	of	of	ADP
eurjchem-624	28	23	primary	primary	ADJ
eurjchem-624	28	24	alkyl	alkyl	NOUN
eurjchem-624	28	25	esters	ester	NOUN
eurjchem-624	28	26	such	such	ADJ
eurjchem-624	28	27	as	as	ADP
eurjchem-624	28	28	ethyl	ethyl	PROPN
eurjchem-624	28	29	[	[	X
eurjchem-624	28	30	6	6	NUM
eurjchem-624	28	31	]	]	PUNCT
eurjchem-624	28	32	,	,	PUNCT
eurjchem-624	28	33	propyl	propyl	NOUN
eurjchem-624	28	34	[	[	X
eurjchem-624	28	35	19	19	NUM
eurjchem-624	28	36	]	]	PUNCT
eurjchem-624	28	37	,	,	PUNCT
eurjchem-624	28	38	isobutyl	isobutyl	NOUN
eurjchem-624	29	1	[	[	X
eurjchem-624	29	2	9	9	NUM
eurjchem-624	29	3	]	]	PUNCT
eurjchem-624	29	4	,	,	PUNCT
eurjchem-624	29	5	neopentyl	neopentyl	NOUN
eurjchem-624	30	1	[	[	X
eurjchem-624	30	2	20	20	NUM
eurjchem-624	30	3	]	]	PUNCT
eurjchem-624	30	4	,	,	PUNCT
eurjchem-624	30	5	and	and	CCONJ
eurjchem-624	30	6	n‐octyl	n‐octyl	PUNCT
eurjchem-624	31	1	[	[	X
eurjchem-624	31	2	21	21	NUM
eurjchem-624	31	3	]	]	PUNCT
eurjchem-624	31	4	,	,	PUNCT
eurjchem-624	31	5	examples	example	NOUN
eurjchem-624	31	6	of	of	ADP
eurjchem-624	31	7	secondary	secondary	ADJ
eurjchem-624	31	8	alkyl	alkyl	ADJ
eurjchem-624	31	9	esters	ester	NOUN
eurjchem-624	31	10	such	such	ADJ
eurjchem-624	31	11	as	as	ADP
eurjchem-624	31	12	isopropyl	isopropyl	NOUN
eurjchem-624	31	13	[	[	X
eurjchem-624	31	14	22,23	22,23	NOUN
eurjchem-624	31	15	]	]	PUNCT
eurjchem-624	31	16	and	and	CCONJ
eurjchem-624	31	17	2‐	2‐	NUM
eurjchem-624	31	18	adamantyl	adamantyl	PROPN
eurjchem-624	31	19	[	[	X
eurjchem-624	31	20	24	24	NUM
eurjchem-624	31	21	]	]	PUNCT
eurjchem-624	31	22	,	,	PUNCT
eurjchem-624	31	23	phenyl	phenyl	NOUN
eurjchem-624	31	24	[	[	X
eurjchem-624	31	25	25	25	NUM
eurjchem-624	31	26	]	]	PUNCT
eurjchem-624	31	27	,	,	PUNCT
eurjchem-624	31	28	and	and	CCONJ
eurjchem-624	31	29	substituted	substitute	VERB
eurjchem-624	31	30	phenyl	phenyl	NOUN
eurjchem-624	31	31	esters	ester	NOUN
eurjchem-624	31	32	[	[	X
eurjchem-624	31	33	26,27	26,27	NUM
eurjchem-624	31	34	]	]	PUNCT
eurjchem-624	31	35	.	.	PUNCT
eurjchem-624	32	1	there	there	PRON
eurjchem-624	32	2	has	have	AUX
eurjchem-624	32	3	been	be	AUX
eurjchem-624	32	4	only	only	ADV
eurjchem-624	32	5	one	one	NUM
eurjchem-624	32	6	study	study	NOUN
eurjchem-624	32	7	in	in	ADP
eurjchem-624	32	8	terms	term	NOUN
eurjchem-624	32	9	of	of	ADP
eurjchem-624	32	10	the	the	DET
eurjchem-624	32	11	g‐w	g‐w	PROPN
eurjchem-624	32	12	equation	equation	NOUN
eurjchem-624	32	13	of	of	ADP
eurjchem-624	32	14	a	a	DET
eurjchem-624	32	15	tertiary	tertiary	ADJ
eurjchem-624	32	16	alkyl	alkyl	NOUN
eurjchem-624	32	17	chloroformate	chloroformate	NOUN
eurjchem-624	32	18	.	.	PUNCT
eurjchem-624	33	1	the	the	DET
eurjchem-624	33	2	simplest	simple	ADJ
eurjchem-624	33	3	,	,	PUNCT
eurjchem-624	33	4	tert‐	tert‐	ADJ
eurjchem-624	33	5	butyl	butyl	NOUN
eurjchem-624	33	6	chloroformate	chloroformate	NOUN
eurjchem-624	33	7	,	,	PUNCT
eurjchem-624	33	8	decomposes	decompose	VERB
eurjchem-624	33	9	rapidly	rapidly	ADV
eurjchem-624	33	10	above	above	ADP
eurjchem-624	33	11	10	10	NUM
eurjchem-624	33	12	oc	oc	NOUN
eurjchem-624	33	13	and	and	CCONJ
eurjchem-624	33	14	the	the	DET
eurjchem-624	33	15	major	major	ADJ
eurjchem-624	33	16	products	product	NOUN
eurjchem-624	33	17	are	be	AUX
eurjchem-624	33	18	isobutylene	isobutylene	ADJ
eurjchem-624	33	19	,	,	PUNCT
eurjchem-624	33	20	hydrogen	hydrogen	NOUN
eurjchem-624	33	21	chloride	chloride	NOUN
eurjchem-624	33	22	,	,	PUNCT
eurjchem-624	33	23	and	and	CCONJ
eurjchem-624	33	24	carbon	carbon	NOUN
eurjchem-624	33	25	dioxide	dioxide	NOUN
eurjchem-624	34	1	[	[	X
eurjchem-624	34	2	28	28	NUM
eurjchem-624	34	3	]	]	PUNCT
eurjchem-624	34	4	.	.	PUNCT
eurjchem-624	35	1	the	the	DET
eurjchem-624	35	2	tert‐pentyl	tert‐pentyl	NOUN
eurjchem-624	35	3	chloroformate	chloroformate	NOUN
eurjchem-624	35	4	has	have	AUX
eurjchem-624	35	5	been	be	AUX
eurjchem-624	35	6	reported	report	VERB
eurjchem-624	35	7	to	to	PART
eurjchem-624	35	8	be	be	AUX
eurjchem-624	35	9	only	only	ADV
eurjchem-624	35	10	slightly	slightly	ADV
eurjchem-624	35	11	more	more	ADV
eurjchem-624	35	12	stable	stable	ADJ
eurjchem-624	36	1	[	[	X
eurjchem-624	36	2	29	29	NUM
eurjchem-624	36	3	]	]	PUNCT
eurjchem-624	36	4	.	.	PUNCT
eurjchem-624	37	1	the	the	DET
eurjchem-624	37	2	1‐adamantyl	1‐adamantyl	NUM
eurjchem-624	37	3	chloroformate	chloroformate	NOUN
eurjchem-624	37	4	has	have	AUX
eurjchem-624	37	5	been	be	AUX
eurjchem-624	37	6	extensively	extensively	ADV
eurjchem-624	37	7	studied	study	VERB
eurjchem-624	37	8	in	in	ADP
eurjchem-624	37	9	terms	term	NOUN
eurjchem-624	37	10	not	not	PART
eurjchem-624	37	11	only	only	ADV
eurjchem-624	37	12	of	of	ADP
eurjchem-624	37	13	solvolysis	solvolysis	NOUN
eurjchem-624	37	14	(	(	PUNCT
eurjchem-624	37	15	accompanied	accompany	VERB
eurjchem-624	37	16	by	by	ADP
eurjchem-624	37	17	decomposition	decomposition	NOUN
eurjchem-624	37	18	)	)	PUNCT
eurjchem-624	38	1	[	[	X
eurjchem-624	38	2	30‐33	30‐33	X
eurjchem-624	38	3	]	]	PUNCT
eurjchem-624	38	4	but	but	CCONJ
eurjchem-624	38	5	also	also	ADV
eurjchem-624	38	6	in	in	ADP
eurjchem-624	38	7	terms	term	NOUN
eurjchem-624	38	8	of	of	ADP
eurjchem-624	38	9	decomposition	decomposition	NOUN
eurjchem-624	38	10	in	in	ADP
eurjchem-624	38	11	relatively	relatively	ADV
eurjchem-624	38	12	inert	inert	ADJ
eurjchem-624	38	13	solvents	solvent	NOUN
eurjchem-624	38	14	[	[	X
eurjchem-624	38	15	32‐34	32‐34	NUM
eurjchem-624	38	16	]	]	PUNCT
eurjchem-624	38	17	.	.	PUNCT
eurjchem-624	39	1	in	in	ADP
eurjchem-624	39	2	aqueous‐organic	aqueous‐organic	ADJ
eurjchem-624	39	3	solvents	solvent	NOUN
eurjchem-624	39	4	,	,	PUNCT
eurjchem-624	39	5	the	the	DET
eurjchem-624	39	6	reaction	reaction	NOUN
eurjchem-624	39	7	proceeds	proceed	VERB
eurjchem-624	39	8	by	by	ADP
eurjchem-624	39	9	an	an	DET
eurjchem-624	39	10	ionization	ionization	NOUN
eurjchem-624	39	11	mechanism	mechanism	NOUN
eurjchem-624	39	12	[	[	X
eurjchem-624	39	13	30,31	30,31	NOUN
eurjchem-624	39	14	]	]	PUNCT
eurjchem-624	39	15	and	and	CCONJ
eurjchem-624	39	16	,	,	PUNCT
eurjchem-624	39	17	in	in	ADP
eurjchem-624	39	18	the	the	DET
eurjchem-624	39	19	solvents	solvent	NOUN
eurjchem-624	39	20	commonly	commonly	ADV
eurjchem-624	39	21	used	use	VERB
eurjchem-624	39	22	for	for	ADP
eurjchem-624	39	23	solvolysis	solvolysis	NOUN
eurjchem-624	39	24	studies	study	NOUN
eurjchem-624	39	25	,	,	PUNCT
eurjchem-624	39	26	only	only	ADV
eurjchem-624	39	27	in	in	ADP
eurjchem-624	39	28	100	100	NUM
eurjchem-624	39	29	%	%	NOUN
eurjchem-624	39	30	ethanol	ethanol	NOUN
eurjchem-624	39	31	was	be	AUX
eurjchem-624	39	32	a	a	DET
eurjchem-624	39	33	very	very	ADV
eurjchem-624	39	34	small	small	ADJ
eurjchem-624	39	35	amount	amount	NOUN
eurjchem-624	39	36	(	(	PUNCT
eurjchem-624	39	37	less	less	ADJ
eurjchem-624	39	38	than	than	ADP
eurjchem-624	39	39	1	1	NUM
eurjchem-624	39	40	%	%	NOUN
eurjchem-624	39	41	)	)	PUNCT
eurjchem-624	39	42	of	of	ADP
eurjchem-624	39	43	the	the	DET
eurjchem-624	39	44	mixed	mixed	ADJ
eurjchem-624	39	45	carbonate	carbonate	NOUN
eurjchem-624	39	46	detected	detect	VERB
eurjchem-624	39	47	,	,	PUNCT
eurjchem-624	39	48	which	which	PRON
eurjchem-624	39	49	could	could	AUX
eurjchem-624	39	50	result	result	VERB
eurjchem-624	39	51	either	either	CCONJ
eurjchem-624	39	52	from	from	ADP
eurjchem-624	39	53	addition‐elimination	addition‐elimination	NOUN
eurjchem-624	39	54	(	(	PUNCT
eurjchem-624	39	55	association‐dissociation	association‐dissociation	NOUN
eurjchem-624	39	56	)	)	PUNCT
eurjchem-624	39	57	,	,	PUNCT
eurjchem-624	39	58	as	as	SCONJ
eurjchem-624	39	59	shown	show	VERB
eurjchem-624	39	60	in	in	ADP
eurjchem-624	39	61	scheme	scheme	NOUN
eurjchem-624	39	62	1	1	NUM
eurjchem-624	39	63	,	,	PUNCT
eurjchem-624	39	64	or	or	CCONJ
eurjchem-624	39	65	by	by	ADP
eurjchem-624	39	66	ionization	ionization	NOUN
eurjchem-624	39	67	to	to	ADP
eurjchem-624	39	68	chloride	chloride	NOUN
eurjchem-624	39	69	and	and	CCONJ
eurjchem-624	39	70	carboxylium	carboxylium	NOUN
eurjchem-624	39	71	ions	ion	NOUN
eurjchem-624	39	72	,	,	PUNCT
eurjchem-624	39	73	followed	follow	VERB
eurjchem-624	39	74	by	by	ADP
eurjchem-624	39	75	solvent	solvent	ADJ
eurjchem-624	39	76	capture	capture	NOUN
eurjchem-624	39	77	(	(	PUNCT
eurjchem-624	39	78	scheme	scheme	NOUN
eurjchem-624	39	79	2a	2a	NUM
eurjchem-624	39	80	)	)	PUNCT
eurjchem-624	39	81	.	.	PUNCT
eurjchem-624	40	1	in	in	ADP
eurjchem-624	40	2	the	the	DET
eurjchem-624	40	3	other	other	ADJ
eurjchem-624	40	4	solvents	solvent	NOUN
eurjchem-624	40	5	,	,	PUNCT
eurjchem-624	40	6	all	all	PRON
eurjchem-624	40	7	of	of	ADP
eurjchem-624	40	8	the	the	DET
eurjchem-624	40	9	products	product	NOUN
eurjchem-624	40	10	were	be	AUX
eurjchem-624	40	11	consistent	consistent	ADJ
eurjchem-624	40	12	with	with	ADP
eurjchem-624	40	13	a	a	DET
eurjchem-624	40	14	solvolysis‐decomposition	solvolysis‐decomposition	NOUN
eurjchem-624	40	15	mechanism	mechanism	NOUN
eurjchem-624	40	16	.	.	PUNCT
eurjchem-624	41	1	for	for	ADP
eurjchem-624	41	2	chloride	chloride	NOUN
eurjchem-624	41	3	and	and	CCONJ
eurjchem-624	41	4	ether	ether	NOUN
eurjchem-624	41	5	formation	formation	NOUN
eurjchem-624	41	6	,	,	PUNCT
eurjchem-624	41	7	this	this	PRON
eurjchem-624	41	8	would	would	AUX
eurjchem-624	41	9	be	be	AUX
eurjchem-624	41	10	as	as	ADP
eurjchem-624	41	11	in	in	ADP
eurjchem-624	41	12	scheme	scheme	NOUN
eurjchem-624	41	13	2b	2b	NOUN
eurjchem-624	41	14	.	.	PUNCT
eurjchem-624	42	1	alcohol	alcohol	NOUN
eurjchem-624	42	2	formation	formation	NOUN
eurjchem-624	42	3	could	could	AUX
eurjchem-624	42	4	result	result	VERB
eurjchem-624	42	5	for	for	ADP
eurjchem-624	42	6	either	either	CCONJ
eurjchem-624	42	7	the	the	DET
eurjchem-624	42	8	scheme	scheme	NOUN
eurjchem-624	42	9	2b	2b	NUM
eurjchem-624	42	10	pathway	pathway	NOUN
eurjchem-624	42	11	or	or	CCONJ
eurjchem-624	42	12	via	via	ADP
eurjchem-624	42	13	loss	loss	NOUN
eurjchem-624	42	14	of	of	ADP
eurjchem-624	42	15	carbon	carbon	NOUN
eurjchem-624	42	16	dioxide	dioxide	NOUN
eurjchem-624	42	17	from	from	ADP
eurjchem-624	42	18	an	an	DET
eurjchem-624	42	19	initially	initially	ADV
eurjchem-624	42	20	formed	form	VERB
eurjchem-624	42	21	half	half	ADJ
eurjchem-624	42	22	carbonate	carbonate	NOUN
eurjchem-624	42	23	(	(	PUNCT
eurjchem-624	42	24	rocooh	rocooh	NOUN
eurjchem-624	42	25	)	)	PUNCT
eurjchem-624	42	26	.	.	PUNCT
eurjchem-624	43	1	the	the	DET
eurjchem-624	43	2	increased	increase	VERB
eurjchem-624	43	3	stability	stability	NOUN
eurjchem-624	43	4	of	of	ADP
eurjchem-624	43	5	the	the	DET
eurjchem-624	43	6	neat	neat	ADJ
eurjchem-624	43	7	substance	substance	NOUN
eurjchem-624	43	8	[	[	X
eurjchem-624	43	9	35	35	NUM
eurjchem-624	43	10	]	]	PUNCT
eurjchem-624	43	11	could	could	AUX
eurjchem-624	43	12	be	be	AUX
eurjchem-624	43	13	due	due	ADJ
eurjchem-624	43	14	in	in	ADP
eurjchem-624	43	15	part	part	NOUN
eurjchem-624	43	16	to	to	ADP
eurjchem-624	43	17	it	it	PRON
eurjchem-624	43	18	being	be	AUX
eurjchem-624	43	19	a	a	DET
eurjchem-624	43	20	solid	solid	ADJ
eurjchem-624	43	21	and	and	CCONJ
eurjchem-624	43	22	in	in	ADP
eurjchem-624	43	23	part	part	NOUN
eurjchem-624	43	24	due	due	ADP
eurjchem-624	43	25	to	to	ADP
eurjchem-624	43	26	alkene	alkene	ADJ
eurjchem-624	43	27	formation	formation	NOUN
eurjchem-624	43	28	,	,	PUNCT
eurjchem-624	43	29	which	which	PRON
eurjchem-624	43	30	would	would	AUX
eurjchem-624	43	31	put	put	VERB
eurjchem-624	43	32	a	a	DET
eurjchem-624	43	33	double	double	ADJ
eurjchem-624	43	34	bond	bond	NOUN
eurjchem-624	43	35	at	at	ADP
eurjchem-624	43	36	a	a	DET
eurjchem-624	43	37	bridgehead	bridgehead	NOUN
eurjchem-624	43	38	,	,	PUNCT
eurjchem-624	43	39	being	be	AUX
eurjchem-624	43	40	highly	highly	ADV
eurjchem-624	43	41	unfavorable	unfavorable	ADJ
eurjchem-624	43	42	(	(	PUNCT
eurjchem-624	43	43	bredt	bredt	PROPN
eurjchem-624	43	44	’s	’s	PART
eurjchem-624	43	45	rule	rule	NOUN
eurjchem-624	43	46	)	)	PUNCT
eurjchem-624	43	47	relative	relative	ADJ
eurjchem-624	43	48	to	to	ADP
eurjchem-624	43	49	the	the	DET
eurjchem-624	43	50	dominant	dominant	ADJ
eurjchem-624	43	51	alkene‐formation	alkene‐formation	NOUN
eurjchem-624	43	52	pathway	pathway	NOUN
eurjchem-624	43	53	involved	involve	VERB
eurjchem-624	43	54	in	in	ADP
eurjchem-624	43	55	the	the	DET
eurjchem-624	43	56	tert‐butyl	tert‐butyl	ADP
eurjchem-624	43	57	chloroformate	chloroformate	ADJ
eurjchem-624	43	58	decomposition	decomposition	NOUN
eurjchem-624	43	59	.	.	PUNCT
eurjchem-624	44	1	the	the	DET
eurjchem-624	44	2	much	much	ADV
eurjchem-624	44	3	slower	slow	ADJ
eurjchem-624	44	4	reaction	reaction	NOUN
eurjchem-624	44	5	of	of	ADP
eurjchem-624	44	6	1‐adamantyl	1‐adamantyl	NUM
eurjchem-624	44	7	fluoroformate	fluoroformate	NOUN
eurjchem-624	44	8	[	[	X
eurjchem-624	44	9	36	36	NUM
eurjchem-624	44	10	]	]	PUNCT
eurjchem-624	44	11	suggests	suggest	VERB
eurjchem-624	44	12	that	that	SCONJ
eurjchem-624	44	13	ionization	ionization	NOUN
eurjchem-624	44	14	is	be	AUX
eurjchem-624	44	15	not	not	PART
eurjchem-624	44	16	to	to	PART
eurjchem-624	44	17	1‐ad+(ocox)‐	1‐ad+(ocox)‐	NUM
eurjchem-624	44	18	,	,	PUNCT
eurjchem-624	44	19	where	where	SCONJ
eurjchem-624	44	20	the	the	DET
eurjchem-624	44	21	substrate	substrate	NOUN
eurjchem-624	44	22	with	with	ADP
eurjchem-624	44	23	the	the	DET
eurjchem-624	44	24	more	more	ADV
eurjchem-624	44	25	electronegative	electronegative	ADJ
eurjchem-624	44	26	fluorine	fluorine	NOUN
eurjchem-624	44	27	for	for	ADP
eurjchem-624	44	28	x	x	PRON
eurjchem-624	44	29	would	would	AUX
eurjchem-624	44	30	be	be	AUX
eurjchem-624	44	31	expected	expect	VERB
eurjchem-624	44	32	to	to	PART
eurjchem-624	44	33	contain	contain	VERB
eurjchem-624	44	34	the	the	DET
eurjchem-624	44	35	superior	superior	ADJ
eurjchem-624	44	36	leaving	leaving	NOUN
eurjchem-624	44	37	group	group	NOUN
eurjchem-624	44	38	.	.	PUNCT
eurjchem-624	45	1	the	the	DET
eurjchem-624	45	2	substrate	substrate	NOUN
eurjchem-624	45	3	of	of	ADP
eurjchem-624	45	4	the	the	DET
eurjchem-624	45	5	present	present	ADJ
eurjchem-624	45	6	investigation	investigation	NOUN
eurjchem-624	45	7	tert‐butyl	tert‐butyl	PRON
eurjchem-624	45	8	chlorothioformate	chlorothioformate	NOUN
eurjchem-624	45	9	(	(	PUNCT
eurjchem-624	45	10	1	1	NUM
eurjchem-624	45	11	)	)	PUNCT
eurjchem-624	45	12	is	be	AUX
eurjchem-624	45	13	commercially	commercially	ADV
eurjchem-624	45	14	available	available	ADJ
eurjchem-624	45	15	but	but	CCONJ
eurjchem-624	45	16	it	it	PRON
eurjchem-624	45	17	was	be	AUX
eurjchem-624	45	18	found	find	VERB
eurjchem-624	45	19	to	to	PART
eurjchem-624	45	20	be	be	AUX
eurjchem-624	45	21	rather	rather	ADV
eurjchem-624	45	22	unstable	unstable	ADJ
eurjchem-624	45	23	,	,	PUNCT
eurjchem-624	45	24	even	even	ADV
eurjchem-624	45	25	when	when	SCONJ
eurjchem-624	45	26	stored	store	VERB
eurjchem-624	45	27	in	in	ADP
eurjchem-624	45	28	a	a	DET
eurjchem-624	45	29	cold	cold	ADJ
eurjchem-624	45	30	room	room	NOUN
eurjchem-624	45	31	.	.	PUNCT
eurjchem-624	46	1	such	such	ADJ
eurjchem-624	46	2	storage	storage	NOUN
eurjchem-624	46	3	allowed	allow	VERB
eurjchem-624	46	4	use	use	NOUN
eurjchem-624	46	5	for	for	ADP
eurjchem-624	46	6	several	several	ADJ
eurjchem-624	46	7	weeks	week	NOUN
eurjchem-624	46	8	but	but	CCONJ
eurjchem-624	46	9	eventually	eventually	ADV
eurjchem-624	46	10	a	a	DET
eurjchem-624	46	11	new	new	ADJ
eurjchem-624	46	12	sample	sample	NOUN
eurjchem-624	46	13	was	be	AUX
eurjchem-624	46	14	required	require	VERB
eurjchem-624	46	15	.	.	PUNCT
eurjchem-624	47	1	compound	compound	NOUN
eurjchem-624	47	2	1	1	NUM
eurjchem-624	47	3	has	have	AUX
eurjchem-624	47	4	been	be	AUX
eurjchem-624	47	5	used	use	VERB
eurjchem-624	47	6	in	in	ADP
eurjchem-624	47	7	the	the	DET
eurjchem-624	47	8	preparation	preparation	NOUN
eurjchem-624	47	9	of	of	ADP
eurjchem-624	47	10	herbicides	herbicide	NOUN
eurjchem-624	47	11	,	,	PUNCT
eurjchem-624	47	12	pesticides	pesticide	NOUN
eurjchem-624	47	13	and	and	CCONJ
eurjchem-624	47	14	antifungal	antifungal	ADJ
eurjchem-624	47	15	agents	agent	NOUN
eurjchem-624	47	16	and	and	CCONJ
eurjchem-624	47	17	,	,	PUNCT
eurjchem-624	47	18	in	in	ADP
eurjchem-624	47	19	particular	particular	ADJ
eurjchem-624	47	20	,	,	PUNCT
eurjchem-624	47	21	in	in	ADP
eurjchem-624	47	22	the	the	DET
eurjchem-624	47	23	derivatization	derivatization	NOUN
eurjchem-624	47	24	of	of	ADP
eurjchem-624	47	25	5‐fluorouracil	5‐fluorouracil	PROPN
eurjchem-624	47	26	(	(	PUNCT
eurjchem-624	47	27	2,4‐	2,4‐	NUM
eurjchem-624	47	28	dihydroxy‐5‐fluoropyrimidine)to	dihydroxy‐5‐fluoropyrimidine)to	NOUN
eurjchem-624	47	29	give	give	VERB
eurjchem-624	47	30	promising	promise	VERB
eurjchem-624	47	31	antitumor	antitumor	PROPN
eurjchem-624	47	32	agents	agent	NOUN
eurjchem-624	48	1	[	[	X
eurjchem-624	48	2	37	37	NUM
eurjchem-624	48	3	]	]	SYM
eurjchem-624	48	4	.	.	PUNCT
eurjchem-624	49	1	2	2	X
eurjchem-624	49	2	.	.	X
eurjchem-624	49	3	experimental	experimental	NOUN
eurjchem-624	49	4	the	the	DET
eurjchem-624	49	5	tert‐butyl	tert‐butyl	PRON
eurjchem-624	49	6	chlorothioformate	chlorothioformate	NOUN
eurjchem-624	49	7	(	(	PUNCT
eurjchem-624	49	8	96	96	NUM
eurjchem-624	49	9	%	%	NOUN
eurjchem-624	49	10	,	,	PUNCT
eurjchem-624	49	11	sigma‐aldrich	sigma‐aldrich	PRON
eurjchem-624	49	12	)	)	PUNCT
eurjchem-624	49	13	was	be	AUX
eurjchem-624	49	14	used	use	VERB
eurjchem-624	49	15	as	as	SCONJ
eurjchem-624	49	16	received	receive	VERB
eurjchem-624	49	17	.	.	PUNCT
eurjchem-624	50	1	solvents	solvent	NOUN
eurjchem-624	50	2	were	be	AUX
eurjchem-624	50	3	purified	purify	VERB
eurjchem-624	50	4	as	as	SCONJ
eurjchem-624	50	5	described	describe	VERB
eurjchem-624	50	6	previously	previously	ADV
eurjchem-624	50	7	[	[	X
eurjchem-624	50	8	26	26	NUM
eurjchem-624	50	9	]	]	PUNCT
eurjchem-624	50	10	.	.	PUNCT
eurjchem-624	51	1	kinetic	kinetic	ADJ
eurjchem-624	51	2	measurements	measurement	NOUN
eurjchem-624	51	3	were	be	AUX
eurjchem-624	51	4	made	make	VERB
eurjchem-624	51	5	conductometrically	conductometrically	ADV
eurjchem-624	51	6	using	use	VERB
eurjchem-624	51	7	a	a	DET
eurjchem-624	51	8	rapid	rapid	ADJ
eurjchem-624	51	9	response	response	NOUN
eurjchem-624	51	10	technique	technique	NOUN
eurjchem-624	51	11	[	[	X
eurjchem-624	51	12	38	38	NUM
eurjchem-624	51	13	]	]	PUNCT
eurjchem-624	51	14	.	.	PUNCT
eurjchem-624	52	1	runs	run	NOUN
eurjchem-624	52	2	were	be	AUX
eurjchem-624	52	3	carried	carry	VERB
eurjchem-624	52	4	out	out	ADP
eurjchem-624	52	5	in	in	ADP
eurjchem-624	52	6	duplicate	duplicate	NOUN
eurjchem-624	52	7	with	with	ADP
eurjchem-624	52	8	at	at	ADV
eurjchem-624	52	9	least	least	ADV
eurjchem-624	52	10	70	70	NUM
eurjchem-624	52	11	readings	reading	NOUN
eurjchem-624	52	12	taken	take	VERB
eurjchem-624	52	13	at	at	ADP
eurjchem-624	52	14	suitable	suitable	ADJ
eurjchem-624	52	15	intervals	interval	NOUN
eurjchem-624	52	16	over	over	ADP
eurjchem-624	52	17	approximately	approximately	ADV
eurjchem-624	52	18	three	three	NUM
eurjchem-624	52	19	half‐lives	half‐live	NOUN
eurjchem-624	52	20	and	and	CCONJ
eurjchem-624	52	21	infinity	infinity	NOUN
eurjchem-624	52	22	readings	reading	NOUN
eurjchem-624	52	23	were	be	AUX
eurjchem-624	52	24	taken	take	VERB
eurjchem-624	52	25	after	after	ADP
eurjchem-624	52	26	ten	ten	NUM
eurjchem-624	52	27	half‐lives	half‐live	NOUN
eurjchem-624	52	28	.	.	PUNCT
eurjchem-624	53	1	the	the	DET
eurjchem-624	53	2	values	value	NOUN
eurjchem-624	53	3	were	be	AUX
eurjchem-624	53	4	used	use	VERB
eurjchem-624	53	5	to	to	PART
eurjchem-624	53	6	calculate	calculate	VERB
eurjchem-624	53	7	an	an	DET
eurjchem-624	53	8	average	average	ADJ
eurjchem-624	53	9	value	value	NOUN
eurjchem-624	53	10	,	,	PUNCT
eurjchem-624	53	11	accompanied	accompany	VERB
eurjchem-624	53	12	by	by	ADP
eurjchem-624	53	13	the	the	DET
eurjchem-624	53	14	associated	associated	ADJ
eurjchem-624	53	15	standard	standard	ADJ
eurjchem-624	53	16	deviation	deviation	NOUN
eurjchem-624	53	17	.	.	PUNCT
eurjchem-624	54	1	simple	simple	ADJ
eurjchem-624	54	2	and	and	CCONJ
eurjchem-624	54	3	multiple	multiple	ADJ
eurjchem-624	54	4	regression	regression	NOUN
eurjchem-624	54	5	analyses	analysis	NOUN
eurjchem-624	54	6	were	be	AUX
eurjchem-624	54	7	carried	carry	VERB
eurjchem-624	54	8	out	out	ADP
eurjchem-624	54	9	using	use	VERB
eurjchem-624	54	10	the	the	DET
eurjchem-624	54	11	excel	excel	ADJ
eurjchem-624	54	12	2010	2010	NUM
eurjchem-624	54	13	package	package	NOUN
eurjchem-624	54	14	from	from	ADP
eurjchem-624	54	15	the	the	DET
eurjchem-624	54	16	microsoft	microsoft	PROPN
eurjchem-624	54	17	corporation	corporation	NOUN
eurjchem-624	54	18	.	.	PUNCT
eurjchem-624	55	1	3	3	X
eurjchem-624	55	2	.	.	NOUN
eurjchem-624	55	3	results	result	NOUN
eurjchem-624	55	4	and	and	CCONJ
eurjchem-624	55	5	discussion	discussion	VERB
eurjchem-624	55	6	the	the	DET
eurjchem-624	55	7	specific	specific	ADJ
eurjchem-624	55	8	rates	rate	NOUN
eurjchem-624	55	9	of	of	ADP
eurjchem-624	55	10	solvolysis	solvolysis	NOUN
eurjchem-624	55	11	of	of	ADP
eurjchem-624	55	12	1	1	NUM
eurjchem-624	55	13	in	in	ADP
eurjchem-624	55	14	nineteen	nineteen	NUM
eurjchem-624	55	15	solvents	solvent	NOUN
eurjchem-624	55	16	,	,	PUNCT
eurjchem-624	55	17	at	at	ADP
eurjchem-624	55	18	25.0	25.0	NUM
eurjchem-624	55	19	oc	oc	NOUN
eurjchem-624	55	20	are	be	AUX
eurjchem-624	55	21	reported	report	VERB
eurjchem-624	55	22	in	in	ADP
eurjchem-624	55	23	table	table	NOUN
eurjchem-624	55	24	1	1	NUM
eurjchem-624	55	25	,	,	PUNCT
eurjchem-624	55	26	together	together	ADV
eurjchem-624	55	27	with	with	ADP
eurjchem-624	55	28	the	the	DET
eurjchem-624	55	29	applicable	applicable	ADJ
eurjchem-624	55	30	nt	nt	NOUN
eurjchem-624	55	31	[	[	X
eurjchem-624	55	32	16,17	16,17	NUM
eurjchem-624	55	33	]	]	PUNCT
eurjchem-624	55	34	and	and	CCONJ
eurjchem-624	55	35	ycl	ycl	X
eurjchem-624	56	1	[	[	X
eurjchem-624	56	2	13,39‐42	13,39‐42	X
eurjchem-624	56	3	]	]	PUNCT
eurjchem-624	56	4	values	value	NOUN
eurjchem-624	56	5	.	.	PUNCT
eurjchem-624	57	1	values	value	NOUN
eurjchem-624	57	2	at	at	ADP
eurjchem-624	57	3	three	three	NUM
eurjchem-624	57	4	elevated	elevated	ADJ
eurjchem-624	57	5	temperatures	temperature	NOUN
eurjchem-624	57	6	in	in	ADP
eurjchem-624	57	7	100	100	NUM
eurjchem-624	57	8	%	%	NOUN
eurjchem-624	57	9	and	and	CCONJ
eurjchem-624	57	10	80	80	NUM
eurjchem-624	57	11	%	%	NOUN
eurjchem-624	57	12	ethanol	ethanol	NOUN
eurjchem-624	57	13	and	and	CCONJ
eurjchem-624	57	14	at	at	ADP
eurjchem-624	57	15	three	three	NUM
eurjchem-624	57	16	reduced	reduce	VERB
eurjchem-624	57	17	temperatures	temperature	NOUN
eurjchem-624	57	18	in	in	ADP
eurjchem-624	57	19	97	97	NUM
eurjchem-624	57	20	%	%	NOUN
eurjchem-624	57	21	and	and	CCONJ
eurjchem-624	57	22	90	90	NUM
eurjchem-624	57	23	%	%	NOUN
eurjchem-624	57	24	2,2,2‐trifluoroethanol	2,2,2‐trifluoroethanol	NUM
eurjchem-624	57	25	(	(	PUNCT
eurjchem-624	57	26	tfe	tfe	NOUN
eurjchem-624	57	27	)	)	PUNCT
eurjchem-624	57	28	were	be	AUX
eurjchem-624	57	29	also	also	ADV
eurjchem-624	57	30	obtained	obtain	VERB
eurjchem-624	57	31	.	.	PUNCT
eurjchem-624	58	1	for	for	ADP
eurjchem-624	58	2	each	each	DET
eurjchem-624	58	3	solvent	solvent	NOUN
eurjchem-624	58	4	,	,	PUNCT
eurjchem-624	58	5	these	these	DET
eurjchem-624	58	6	three	three	NUM
eurjchem-624	58	7	values	value	NOUN
eurjchem-624	58	8	were	be	AUX
eurjchem-624	58	9	combined	combine	VERB
eurjchem-624	58	10	with	with	ADP
eurjchem-624	58	11	the	the	DET
eurjchem-624	58	12	value	value	NOUN
eurjchem-624	58	13	at	at	ADP
eurjchem-624	58	14	25.0	25.0	NUM
eurjchem-624	58	15	oc	oc	NOUN
eurjchem-624	58	16	from	from	ADP
eurjchem-624	58	17	table	table	NOUN
eurjchem-624	58	18	1	1	NUM
eurjchem-624	58	19	for	for	ADP
eurjchem-624	58	20	a	a	DET
eurjchem-624	58	21	treatment	treatment	NOUN
eurjchem-624	58	22	in	in	ADP
eurjchem-624	58	23	terms	term	NOUN
eurjchem-624	58	24	of	of	ADP
eurjchem-624	58	25	the	the	DET
eurjchem-624	58	26	eyring	eyring	NOUN
eurjchem-624	58	27	equation	equation	NOUN
eurjchem-624	58	28	to	to	PART
eurjchem-624	58	29	arrive	arrive	VERB
eurjchem-624	58	30	at	at	ADP
eurjchem-624	58	31	values	value	NOUN
eurjchem-624	58	32	for	for	ADP
eurjchem-624	58	33	the	the	DET
eurjchem-624	58	34	enthalpy	enthalpy	NOUN
eurjchem-624	58	35	and	and	CCONJ
eurjchem-624	58	36	entropy	entropy	NOUN
eurjchem-624	58	37	of	of	ADP
eurjchem-624	58	38	activation	activation	NOUN
eurjchem-624	58	39	,	,	PUNCT
eurjchem-624	58	40	accompanied	accompany	VERB
eurjchem-624	58	41	by	by	ADP
eurjchem-624	58	42	the	the	DET
eurjchem-624	58	43	standard	standard	ADJ
eurjchem-624	58	44	errors	error	NOUN
eurjchem-624	58	45	(	(	PUNCT
eurjchem-624	58	46	table	table	NOUN
eurjchem-624	58	47	2	2	NUM
eurjchem-624	58	48	)	)	PUNCT
eurjchem-624	58	49	.	.	PUNCT
eurjchem-624	59	1	the	the	DET
eurjchem-624	59	2	major	major	ADJ
eurjchem-624	59	3	change	change	NOUN
eurjchem-624	59	4	in	in	ADP
eurjchem-624	59	5	going	go	VERB
eurjchem-624	59	6	from	from	ADP
eurjchem-624	59	7	ethanol	ethanol	NOUN
eurjchem-624	59	8	or	or	CCONJ
eurjchem-624	59	9	80	80	NUM
eurjchem-624	59	10	%	%	NOUN
eurjchem-624	59	11	ethanol	ethanol	NOUN
eurjchem-624	59	12	to	to	ADP
eurjchem-624	59	13	the	the	DET
eurjchem-624	59	14	two	two	NUM
eurjchem-624	59	15	aqueous‐tfe	aqueous‐tfe	ADJ
eurjchem-624	59	16	solvents	solvent	NOUN
eurjchem-624	59	17	is	be	AUX
eurjchem-624	59	18	a	a	DET
eurjchem-624	59	19	reduction	reduction	NOUN
eurjchem-624	59	20	of	of	ADP
eurjchem-624	59	21	4‐6	4‐6	PROPN
eurjchem-624	59	22	k	k	PROPN
eurjchem-624	59	23	cal	cal	PROPN
eurjchem-624	59	24	/	/	SYM
eurjchem-624	59	25	mole	mole	NOUN
eurjchem-624	59	26	in	in	ADP
eurjchem-624	59	27	the	the	DET
eurjchem-624	59	28	enthalpies	enthalpy	NOUN
eurjchem-624	59	29	of	of	ADP
eurjchem-624	59	30	activation	activation	NOUN
eurjchem-624	59	31	.	.	PUNCT
eurjchem-624	60	1	the	the	DET
eurjchem-624	60	2	entropy	entropy	NOUN
eurjchem-624	60	3	values	value	NOUN
eurjchem-624	60	4	of	of	ADP
eurjchem-624	60	5	‐17	‐17	ADJ
eurjchem-624	60	6	and	and	CCONJ
eurjchem-624	60	7	‐12	‐12	NOUN
eurjchem-624	60	8	cal	cal	ADJ
eurjchem-624	60	9	mol‐1	mol‐1	NOUN
eurjchem-624	60	10	k‐1	k‐1	NOUN
eurjchem-624	60	11	for	for	ADP
eurjchem-624	60	12	the	the	DET
eurjchem-624	60	13	ethanol	ethanol	NOUN
eurjchem-624	60	14	and	and	CCONJ
eurjchem-624	60	15	80	80	NUM
eurjchem-624	60	16	%	%	NOUN
eurjchem-624	60	17	ethanol	ethanol	NOUN
eurjchem-624	60	18	bracket	bracket	VERB
eurjchem-624	60	19	the	the	DET
eurjchem-624	60	20	values	value	NOUN
eurjchem-624	60	21	of	of	ADP
eurjchem-624	60	22	‐14	‐14	NOUN
eurjchem-624	60	23	and	and	CCONJ
eurjchem-624	60	24	‐15	‐15	PROPN
eurjchem-624	60	25	cal	cal	ADJ
eurjchem-624	60	26	mol‐1	mol‐1	NOUN
eurjchem-624	60	27	k‐1	k‐1	NOUN
eurjchem-624	60	28	for	for	ADP
eurjchem-624	60	29	the	the	DET
eurjchem-624	60	30	aqueous‐tfe	aqueous‐tfe	ADJ
eurjchem-624	60	31	solvents	solvent	NOUN
eurjchem-624	60	32	.	.	PUNCT
eurjchem-624	61	1	entropies	entropy	NOUN
eurjchem-624	61	2	of	of	ADP
eurjchem-624	61	3	this	this	DET
eurjchem-624	61	4	magnitude	magnitude	NOUN
eurjchem-624	61	5	are	be	AUX
eurjchem-624	61	6	on	on	ADP
eurjchem-624	61	7	the	the	DET
eurjchem-624	61	8	border	border	NOUN
eurjchem-624	61	9	between	between	ADP
eurjchem-624	61	10	values	value	NOUN
eurjchem-624	61	11	of	of	ADP
eurjchem-624	61	12	‐14	‐14	X
eurjchem-624	61	13	to	to	ADP
eurjchem-624	61	14	‐9	‐9	NUM
eurjchem-624	61	15	cal	cal	NUM
eurjchem-624	61	16	mol‐1	mol‐1	NOUN
eurjchem-624	61	17	k‐1	k‐1	NOUN
eurjchem-624	61	18	proposed	propose	VERB
eurjchem-624	61	19	for	for	ADP
eurjchem-624	61	20	sn1	sn1	PROPN
eurjchem-624	61	21	reactions	reaction	NOUN
eurjchem-624	61	22	of	of	ADP
eurjchem-624	61	23	alkyl	alkyl	ADJ
eurjchem-624	61	24	chlorides	chloride	NOUN
eurjchem-624	61	25	and	and	CCONJ
eurjchem-624	61	26	values	value	NOUN
eurjchem-624	61	27	of	of	ADP
eurjchem-624	61	28	‐23	‐23	NOUN
eurjchem-624	61	29	to	to	ADP
eurjchem-624	61	30	‐19	‐19	PROPN
eurjchem-624	61	31	cal	cal	PROPN
eurjchem-624	61	32	mol‐1	mol‐1	NOUN
eurjchem-624	61	33	k‐1	k‐1	NOUN
eurjchem-624	61	34	for	for	ADP
eurjchem-624	61	35	the	the	DET
eurjchem-624	61	36	corresponding	corresponding	ADJ
eurjchem-624	61	37	sn2	sn2	PROPN
eurjchem-624	61	38	reactions	reaction	NOUN
eurjchem-624	61	39	[	[	X
eurjchem-624	61	40	43	43	NUM
eurjchem-624	61	41	]	]	PUNCT
eurjchem-624	61	42	.	.	PUNCT
eurjchem-624	62	1	table	table	NOUN
eurjchem-624	62	2	1	1	NUM
eurjchem-624	62	3	.	.	PUNCT
eurjchem-624	62	4	specific	specific	ADJ
eurjchem-624	62	5	rates	rate	NOUN
eurjchem-624	62	6	of	of	ADP
eurjchem-624	62	7	solvolysis	solvolysis	NOUN
eurjchem-624	62	8	(	(	PUNCT
eurjchem-624	62	9	k	k	NOUN
eurjchem-624	62	10	)	)	PUNCT
eurjchem-624	62	11	of	of	ADP
eurjchem-624	62	12	tert‐butyl	tert‐butyl	PRON
eurjchem-624	62	13	chlorothioformate	chlorothioformate	NOUN
eurjchem-624	62	14	(	(	PUNCT
eurjchem-624	62	15	1	1	NUM
eurjchem-624	62	16	)	)	PUNCT
eurjchem-624	62	17	,	,	PUNCT
eurjchem-624	62	18	in	in	ADP
eurjchem-624	62	19	several	several	ADJ
eurjchem-624	62	20	pure	pure	ADJ
eurjchem-624	62	21	and	and	CCONJ
eurjchem-624	62	22	binary	binary	ADJ
eurjchem-624	62	23	solvents	solvent	NOUN
eurjchem-624	62	24	at	at	ADP
eurjchem-624	62	25	25.0	25.0	NUM
eurjchem-624	62	26	oc	oc	NOUN
eurjchem-624	62	27	,	,	PUNCT
eurjchem-624	62	28	and	and	CCONJ
eurjchem-624	62	29	literature	literature	NOUN
eurjchem-624	62	30	values	value	NOUN
eurjchem-624	62	31	of	of	ADP
eurjchem-624	62	32	nt	not	PART
eurjchem-624	62	33	and	and	CCONJ
eurjchem-624	62	34	ycl	ycl	PROPN
eurjchem-624	62	35	for	for	ADP
eurjchem-624	62	36	the	the	DET
eurjchem-624	62	37	solvents	solvent	NOUN
eurjchem-624	62	38	.	.	PUNCT
eurjchem-624	63	1	solvent	solvent	VERB
eurjchem-624	63	2	a	a	DET
eurjchem-624	63	3	104	104	NUM
eurjchem-624	63	4	k1	k1	NOUN
eurjchem-624	63	5	,	,	PUNCT
eurjchem-624	63	6	s‐1	s‐1	VERB
eurjchem-624	63	7	,	,	PUNCT
eurjchem-624	63	8	b	b	PROPN
eurjchem-624	63	9	ntc	ntc	NOUN
eurjchem-624	63	10	ycld	ycld	NOUN
eurjchem-624	63	11	100	100	NUM
eurjchem-624	63	12	%	%	NOUN
eurjchem-624	63	13	etoh	etoh	NOUN
eurjchem-624	63	14	0.0777	0.0777	NUM
eurjchem-624	63	15	±	±	PROPN
eurjchem-624	63	16	0.0003	0.0003	NUM
eurjchem-624	63	17	0.37	0.37	NUM
eurjchem-624	63	18	‐2.50	‐2.50	NUM
eurjchem-624	63	19	90	90	NUM
eurjchem-624	63	20	%	%	NOUN
eurjchem-624	63	21	etoh	etoh	NOUN
eurjchem-624	63	22	0.612	0.612	NUM
eurjchem-624	63	23	±	±	NUM
eurjchem-624	63	24	0.002	0.002	NUM
eurjchem-624	63	25	0.16	0.16	NUM
eurjchem-624	63	26	‐0.90	‐0.90	ADV
eurjchem-624	63	27	80	80	NUM
eurjchem-624	63	28	%	%	NOUN
eurjchem-624	63	29	etoh	etoh	NOUN
eurjchem-624	63	30	4.04	4.04	NUM
eurjchem-624	63	31	±	±	NUM
eurjchem-624	63	32	0.02	0.02	NUM
eurjchem-624	63	33	0.00	0.00	NUM
eurjchem-624	63	34	0.00	0.00	NUM
eurjchem-624	63	35	70	70	NUM
eurjchem-624	63	36	%	%	NOUN
eurjchem-624	63	37	etoh	etoh	NOUN
eurjchem-624	63	38	17.5	17.5	NUM
eurjchem-624	63	39	±	±	NUM
eurjchem-624	63	40	0.2	0.2	NUM
eurjchem-624	63	41	‐0.20	‐0.20	NUM
eurjchem-624	63	42	0.78	0.78	NUM
eurjchem-624	63	43	100	100	NUM
eurjchem-624	63	44	%	%	NOUN
eurjchem-624	63	45	meoh	meoh	NOUN
eurjchem-624	63	46	0.743	0.743	NUM
eurjchem-624	63	47	±	±	NUM
eurjchem-624	63	48	0.003e	0.003e	PROPN
eurjchem-624	63	49	0.17	0.17	NUM
eurjchem-624	63	50	‐1.20	‐1.20	NOUN
eurjchem-624	63	51	90	90	NUM
eurjchem-624	63	52	%	%	NOUN
eurjchem-624	63	53	meoh	meoh	NOUN
eurjchem-624	63	54	3.75	3.75	NUM
eurjchem-624	63	55	±	±	NUM
eurjchem-624	63	56	0.02	0.02	NUM
eurjchem-624	63	57	‐0.01	‐0.01	NOUN
eurjchem-624	63	58	‐0.20	‐0.20	NUM
eurjchem-624	63	59	80	80	NUM
eurjchem-624	63	60	%	%	NOUN
eurjchem-624	63	61	meoh	meoh	NOUN
eurjchem-624	63	62	15.9	15.9	NUM
eurjchem-624	63	63	±	±	NUM
eurjchem-624	63	64	0.02	0.02	NUM
eurjchem-624	63	65	‐0.06	‐0.06	NOUN
eurjchem-624	63	66	0.67	0.67	NUM
eurjchem-624	63	67	90	90	NUM
eurjchem-624	63	68	%	%	NOUN
eurjchem-624	63	69	acetone	acetone	NOUN
eurjchem-624	63	70	0.0341	0.0341	NUM
eurjchem-624	63	71	±	±	NOUN
eurjchem-624	63	72	0.0003	0.0003	NUM
eurjchem-624	63	73	‐0.35	‐0.35	NOUN
eurjchem-624	63	74	‐2.39	‐2.39	NOUN
eurjchem-624	63	75	80	80	NUM
eurjchem-624	63	76	%	%	NOUN
eurjchem-624	63	77	acetone	acetone	NOUN
eurjchem-624	63	78	0.605	0.605	NUM
eurjchem-624	63	79	±	±	NUM
eurjchem-624	63	80	0.004	0.004	NUM
eurjchem-624	63	81	‐0.37	‐0.37	NUM
eurjchem-624	63	82	‐0.80	‐0.80	NUM
eurjchem-624	63	83	70	70	NUM
eurjchem-624	63	84	%	%	NOUN
eurjchem-624	63	85	acetone	acetone	NOUN
eurjchem-624	63	86	4.94	4.94	NUM
eurjchem-624	63	87	±	±	NUM
eurjchem-624	63	88	0.03	0.03	NUM
eurjchem-624	63	89	‐0.42	‐0.42	ADV
eurjchem-624	63	90	0.17	0.17	NUM
eurjchem-624	63	91	60	60	NUM
eurjchem-624	63	92	%	%	NOUN
eurjchem-624	63	93	acetone	acetone	NOUN
eurjchem-624	63	94	27.5	27.5	NUM
eurjchem-624	63	95	±	±	NUM
eurjchem-624	63	96	0.2	0.2	NUM
eurjchem-624	63	97	‐0.52	‐0.52	NUM
eurjchem-624	63	98	1.00	1.00	NUM
eurjchem-624	63	99	97	97	NUM
eurjchem-624	63	100	%	%	NOUN
eurjchem-624	63	101	tfe	tfe	NOUN
eurjchem-624	63	102	(	(	PUNCT
eurjchem-624	63	103	w	w	PROPN
eurjchem-624	63	104	/	/	SYM
eurjchem-624	63	105	w	w	NOUN
eurjchem-624	63	106	)	)	PUNCT
eurjchem-624	63	107	373	373	NUM
eurjchem-624	63	108	±	±	NUM
eurjchem-624	63	109	3	3	NUM
eurjchem-624	63	110	‐3.30	‐3.30	PROPN
eurjchem-624	63	111	2.83	2.83	NUM
eurjchem-624	63	112	90	90	NUM
eurjchem-624	63	113	%	%	NOUN
eurjchem-624	63	114	tfe	tfe	NOUN
eurjchem-624	63	115	(	(	PUNCT
eurjchem-624	63	116	w	w	PROPN
eurjchem-624	63	117	/	/	SYM
eurjchem-624	63	118	w	w	NOUN
eurjchem-624	63	119	)	)	PUNCT
eurjchem-624	63	120	320	320	NUM
eurjchem-624	63	121	±	±	NUM
eurjchem-624	63	122	1	1	NUM
eurjchem-624	63	123	‐2.55	‐2.55	NUM
eurjchem-624	63	124	2.85	2.85	NUM
eurjchem-624	63	125	80t‐20ef	80t‐20ef	NUM
eurjchem-624	63	126	48.7	48.7	NUM
eurjchem-624	63	127	±	±	NUM
eurjchem-624	63	128	0.7	0.7	NUM
eurjchem-624	63	129	‐1.76	‐1.76	NOUN
eurjchem-624	63	130	1.89	1.89	NUM
eurjchem-624	63	131	60t‐40ef	60t‐40ef	NUM
eurjchem-624	63	132	5.54	5.54	NUM
eurjchem-624	63	133	±	±	NUM
eurjchem-624	63	134	0.05	0.05	NUM
eurjchem-624	63	135	‐0.94	‐0.94	NOUN
eurjchem-624	63	136	0.63	0.63	NUM
eurjchem-624	63	137	40t‐60ef	40t‐60ef	NUM
eurjchem-624	63	138	0.853	0.853	NUM
eurjchem-624	63	139	±	±	NUM
eurjchem-624	63	140	0.002	0.002	NUM
eurjchem-624	63	141	‐0.34	‐0.34	NOUN
eurjchem-624	63	142	‐0.48	‐0.48	NOUN
eurjchem-624	63	143	20t‐80ef	20t‐80ef	NUM
eurjchem-624	63	144	0.171	0.171	NUM
eurjchem-624	63	145	±	±	NUM
eurjchem-624	63	146	0.001	0.001	NUM
eurjchem-624	63	147	0.08	0.08	NUM
eurjchem-624	63	148	‐1.42	‐1.42	NUM
eurjchem-624	63	149	70%hfip	70%hfip	PROPN
eurjchem-624	63	150	(	(	PUNCT
eurjchem-624	63	151	w	w	PROPN
eurjchem-624	63	152	/	/	SYM
eurjchem-624	63	153	w	w	NOUN
eurjchem-624	63	154	)	)	PUNCT
eurjchem-624	63	155	4387	4387	NUM
eurjchem-624	63	156	±	±	NUM
eurjchem-624	63	157	61	61	NUM
eurjchem-624	63	158	‐2.94	‐2.94	NUM
eurjchem-624	63	159	3.83	3.83	NUM
eurjchem-624	63	160	50%hfip	50%hfip	NUM
eurjchem-624	63	161	(	(	PUNCT
eurjchem-624	63	162	w	w	PROPN
eurjchem-624	63	163	/	/	SYM
eurjchem-624	63	164	w	w	NOUN
eurjchem-624	63	165	)	)	PUNCT
eurjchem-624	63	166	702	702	NUM
eurjchem-624	63	167	±	±	NUM
eurjchem-624	63	168	12	12	NUM
eurjchem-624	63	169	‐2.49	‐2.49	ADP
eurjchem-624	63	170	3.80	3.80	NUM
eurjchem-624	63	171	a	a	PRON
eurjchem-624	63	172	on	on	ADP
eurjchem-624	63	173	a	a	DET
eurjchem-624	63	174	volume‐volume	volume‐volume	NOUN
eurjchem-624	63	175	basis	basis	NOUN
eurjchem-624	63	176	at	at	ADP
eurjchem-624	63	177	25.0	25.0	NUM
eurjchem-624	63	178	°	°	NOUN
eurjchem-624	63	179	c	c	NOUN
eurjchem-624	63	180	unless	unless	SCONJ
eurjchem-624	63	181	otherwise	otherwise	ADV
eurjchem-624	63	182	indicated	indicate	VERB
eurjchem-624	63	183	.	.	PUNCT
eurjchem-624	64	1	b	b	X
eurjchem-624	64	2	with	with	ADP
eurjchem-624	64	3	associated	associated	ADJ
eurjchem-624	64	4	standard	standard	ADJ
eurjchem-624	64	5	deviations	deviation	NOUN
eurjchem-624	64	6	.	.	PUNCT
eurjchem-624	65	1	c	c	NOUN
eurjchem-624	65	2	from	from	ADP
eurjchem-624	65	3	ref	ref	NOUN
eurjchem-624	65	4	.	.	PUNCT
eurjchem-624	66	1	[	[	X
eurjchem-624	66	2	17	17	NUM
eurjchem-624	66	3	]	]	PUNCT
eurjchem-624	66	4	.	.	PUNCT
eurjchem-624	67	1	d	d	NOUN
eurjchem-624	67	2	from	from	ADP
eurjchem-624	67	3	refs	ref	NOUN
eurjchem-624	67	4	.	.	PUNCT
eurjchem-624	68	1	[	[	X
eurjchem-624	68	2	13,40‐42	13,40‐42	X
eurjchem-624	68	3	]	]	PUNCT
eurjchem-624	68	4	.	.	PUNCT
eurjchem-624	69	1	e	e	X
eurjchem-624	69	2	also	also	ADV
eurjchem-624	69	3	a	a	DET
eurjchem-624	69	4	value	value	NOUN
eurjchem-624	69	5	of	of	ADP
eurjchem-624	69	6	0.533	0.533	NUM
eurjchem-624	69	7	±	±	NUM
eurjchem-624	69	8	0.002	0.002	NUM
eurjchem-624	69	9	in	in	ADP
eurjchem-624	69	10	100	100	NUM
eurjchem-624	69	11	%	%	NOUN
eurjchem-624	69	12	meod	meod	NOUN
eurjchem-624	69	13	corresponding	correspond	VERB
eurjchem-624	69	14	to	to	ADP
eurjchem-624	69	15	a	a	DET
eurjchem-624	69	16	kmeoh	kmeoh	NOUN
eurjchem-624	69	17	/	/	SYM
eurjchem-624	69	18	kmeod	kmeod	NOUN
eurjchem-624	69	19	value	value	NOUN
eurjchem-624	69	20	of	of	ADP
eurjchem-624	69	21	1.39	1.39	NUM
eurjchem-624	69	22	±	±	NUM
eurjchem-624	69	23	0.01	0.01	NUM
eurjchem-624	69	24	.	.	PUNCT
eurjchem-624	70	1	f	f	PROPN
eurjchem-624	70	2	t‐e	t‐e	PROPN
eurjchem-624	70	3	are	be	AUX
eurjchem-624	70	4	tfe‐etoh	tfe‐etoh	NUM
eurjchem-624	70	5	mixtures	mixture	NOUN
eurjchem-624	70	6	.	.	PUNCT
eurjchem-624	71	1	for	for	ADP
eurjchem-624	71	2	methanolysis	methanolysis	NOUN
eurjchem-624	71	3	,	,	PUNCT
eurjchem-624	71	4	the	the	DET
eurjchem-624	71	5	specific	specific	ADJ
eurjchem-624	71	6	rate	rate	NOUN
eurjchem-624	71	7	was	be	AUX
eurjchem-624	71	8	determined	determine	VERB
eurjchem-624	71	9	in	in	ADP
eurjchem-624	71	10	both	both	DET
eurjchem-624	71	11	meoh	meoh	NOUN
eurjchem-624	71	12	and	and	CCONJ
eurjchem-624	71	13	meod	meod	NOUN
eurjchem-624	71	14	,	,	PUNCT
eurjchem-624	71	15	allowing	allow	VERB
eurjchem-624	71	16	a	a	DET
eurjchem-624	71	17	solvent	solvent	ADJ
eurjchem-624	71	18	deuterium	deuterium	NOUN
eurjchem-624	71	19	isotope	isotope	NOUN
eurjchem-624	71	20	effect	effect	NOUN
eurjchem-624	71	21	(	(	PUNCT
eurjchem-624	71	22	kh	kh	PROPN
eurjchem-624	71	23	/	/	SYM
eurjchem-624	71	24	kd	kd	PROPN
eurjchem-624	71	25	)	)	PUNCT
eurjchem-624	71	26	of	of	ADP
eurjchem-624	71	27	1.39	1.39	NUM
eurjchem-624	71	28	to	to	PART
eurjchem-624	71	29	be	be	AUX
eurjchem-624	71	30	determined	determine	VERB
eurjchem-624	71	31	(	(	PUNCT
eurjchem-624	71	32	table	table	NOUN
eurjchem-624	71	33	1	1	NUM
eurjchem-624	71	34	)	)	PUNCT
eurjchem-624	71	35	,	,	PUNCT
eurjchem-624	71	36	this	this	DET
eurjchem-624	71	37	value	value	NOUN
eurjchem-624	71	38	is	be	AUX
eurjchem-624	71	39	similar	similar	ADJ
eurjchem-624	71	40	to	to	ADP
eurjchem-624	71	41	the	the	DET
eurjchem-624	71	42	value	value	NOUN
eurjchem-624	71	43	of	of	ADP
eurjchem-624	71	44	1.26	1.26	NUM
eurjchem-624	71	45	for	for	ADP
eurjchem-624	71	46	the	the	DET
eurjchem-624	71	47	methanoysis	methanoysis	NOUN
eurjchem-624	71	48	of	of	ADP
eurjchem-624	71	49	tert‐butyl	tert‐butyl	DET
eurjchem-624	71	50	fluoroformate	fluoroformate	NOUN
eurjchem-624	71	51	,	,	PUNCT
eurjchem-624	71	52	which	which	PRON
eurjchem-624	71	53	is	be	AUX
eurjchem-624	71	54	believed	believe	VERB
eurjchem-624	71	55	to	to	PART
eurjchem-624	71	56	follow	follow	VERB
eurjchem-624	71	57	a	a	DET
eurjchem-624	71	58	unimolecular	unimolecular	ADJ
eurjchem-624	71	59	pathway	pathway	NOUN
eurjchem-624	71	60	.	.	PUNCT
eurjchem-624	72	1	values	value	NOUN
eurjchem-624	72	2	for	for	ADP
eurjchem-624	72	3	chloroformate	chloroformate	ADJ
eurjchem-624	72	4	esters	ester	NOUN
eurjchem-624	72	5	have	have	AUX
eurjchem-624	72	6	usually	usually	ADV
eurjchem-624	72	7	been	be	AUX
eurjchem-624	72	8	close	close	ADJ
eurjchem-624	72	9	to	to	ADP
eurjchem-624	72	10	two	two	NUM
eurjchem-624	72	11	for	for	ADP
eurjchem-624	72	12	reactions	reaction	NOUN
eurjchem-624	72	13	believed	believe	VERB
eurjchem-624	72	14	to	to	PART
eurjchem-624	72	15	go	go	VERB
eurjchem-624	72	16	by	by	ADP
eurjchem-624	72	17	the	the	DET
eurjchem-624	72	18	addition‐	addition‐	ADJ
eurjchem-624	72	19	elimination	elimination	NOUN
eurjchem-624	72	20	pathway	pathway	NOUN
eurjchem-624	72	21	with	with	ADP
eurjchem-624	72	22	,	,	PUNCT
eurjchem-624	72	23	for	for	ADP
eurjchem-624	72	24	example	example	NOUN
eurjchem-624	72	25	,	,	PUNCT
eurjchem-624	72	26	values	value	NOUN
eurjchem-624	72	27	of	of	ADP
eurjchem-624	72	28	2.17	2.17	NUM
eurjchem-624	72	29	for	for	ADP
eurjchem-624	72	30	n‐	n‐	NOUN
eurjchem-624	72	31	propyl	propyl	NOUN
eurjchem-624	72	32	chloroformate	chloroformate	NOUN
eurjchem-624	72	33	[	[	X
eurjchem-624	72	34	19	19	NUM
eurjchem-624	72	35	]	]	PUNCT
eurjchem-624	72	36	and	and	CCONJ
eurjchem-624	72	37	1.87	1.87	NUM
eurjchem-624	72	38	for	for	ADP
eurjchem-624	72	39	2‐adamantyl	2‐adamantyl	NUM
eurjchem-624	72	40	chloroformate	chloroformate	NOUN
eurjchem-624	72	41	[	[	X
eurjchem-624	72	42	24	24	NUM
eurjchem-624	72	43	]	]	PUNCT
eurjchem-624	72	44	.	.	PUNCT
eurjchem-624	73	1	when	when	SCONJ
eurjchem-624	73	2	all	all	PRON
eurjchem-624	73	3	of	of	ADP
eurjchem-624	73	4	the	the	DET
eurjchem-624	73	5	hydrogens	hydrogen	NOUN
eurjchem-624	73	6	of	of	ADP
eurjchem-624	73	7	one	one	NUM
eurjchem-624	73	8	of	of	ADP
eurjchem-624	73	9	three	three	NUM
eurjchem-624	73	10	d'souza	d'souza	PROPN
eurjchem-624	73	11	et	et	PROPN
eurjchem-624	73	12	al	al	PROPN
eurjchem-624	73	13	.	.	PUNCT
eurjchem-624	73	14	/	/	SYM
eurjchem-624	73	15	european	european	PROPN
eurjchem-624	73	16	journal	journal	PROPN
eurjchem-624	73	17	of	of	ADP
eurjchem-624	73	18	chemistry	chemistry	NOUN
eurjchem-624	73	19	3	3	NUM
eurjchem-624	73	20	(	(	PUNCT
eurjchem-624	73	21	3	3	NUM
eurjchem-624	73	22	)	)	PUNCT
eurjchem-624	73	23	(	(	PUNCT
eurjchem-624	73	24	2012	2012	NUM
eurjchem-624	73	25	)	)	PUNCT
eurjchem-624	73	26	267‐272	267‐272	PROPN
eurjchem-624	73	27	269	269	NUM
eurjchem-624	73	28	methyl	methyl	NOUN
eurjchem-624	73	29	groups	group	NOUN
eurjchem-624	73	30	of	of	ADP
eurjchem-624	73	31	tert‐butyl	tert‐butyl	ADP
eurjchem-624	73	32	chloroformate	chloroformate	NOUN
eurjchem-624	73	33	are	be	AUX
eurjchem-624	73	34	replaced	replace	VERB
eurjchem-624	73	35	by	by	ADP
eurjchem-624	73	36	chlorine	chlorine	NOUN
eurjchem-624	73	37	(	(	PUNCT
eurjchem-624	73	38	2,2,2‐trichloro‐1,1‐dimethylethyl	2,2,2‐trichloro‐1,1‐dimethylethyl	NUM
eurjchem-624	73	39	chloroformate	chloroformate	NOUN
eurjchem-624	73	40	)	)	PUNCT
eurjchem-624	73	41	,	,	PUNCT
eurjchem-624	73	42	the	the	DET
eurjchem-624	73	43	substrate	substrate	NOUN
eurjchem-624	73	44	is	be	AUX
eurjchem-624	73	45	quite	quite	ADV
eurjchem-624	73	46	stable	stable	ADJ
eurjchem-624	73	47	and	and	CCONJ
eurjchem-624	73	48	the	the	DET
eurjchem-624	73	49	kmeoh	kmeoh	PROPN
eurjchem-624	73	50	/	/	SYM
eurjchem-624	73	51	kmeod	kmeod	PROPN
eurjchem-624	73	52	ratio	ratio	NOUN
eurjchem-624	73	53	of	of	ADP
eurjchem-624	73	54	2.14	2.14	NUM
eurjchem-624	73	55	indicates	indicate	VERB
eurjchem-624	73	56	an	an	DET
eurjchem-624	73	57	addition‐elimination	addition‐elimination	NOUN
eurjchem-624	73	58	pathway	pathway	NOUN
eurjchem-624	73	59	for	for	ADP
eurjchem-624	73	60	the	the	DET
eurjchem-624	73	61	methanolysis	methanolysis	NOUN
eurjchem-624	73	62	of	of	ADP
eurjchem-624	73	63	this	this	DET
eurjchem-624	73	64	trisubstituted‐tert‐alkyl	trisubstituted‐tert‐alkyl	NOUN
eurjchem-624	73	65	chloroformate	chloroformate	NOUN
eurjchem-624	73	66	[	[	X
eurjchem-624	73	67	44	44	NUM
eurjchem-624	73	68	]	]	PUNCT
eurjchem-624	73	69	.	.	PUNCT
eurjchem-624	74	1	table	table	NOUN
eurjchem-624	74	2	2	2	NUM
eurjchem-624	74	3	.	.	PUNCT
eurjchem-624	74	4	specific	specific	ADJ
eurjchem-624	74	5	rates	rate	NOUN
eurjchem-624	74	6	of	of	ADP
eurjchem-624	74	7	solvolysis	solvolysis	NOUN
eurjchem-624	74	8	(	(	PUNCT
eurjchem-624	74	9	k	k	NOUN
eurjchem-624	74	10	)	)	PUNCT
eurjchem-624	74	11	of	of	ADP
eurjchem-624	74	12	1	1	NUM
eurjchem-624	74	13	in	in	ADP
eurjchem-624	74	14	100	100	NUM
eurjchem-624	74	15	%	%	NOUN
eurjchem-624	74	16	and	and	CCONJ
eurjchem-624	74	17	80	80	NUM
eurjchem-624	74	18	%	%	NOUN
eurjchem-624	74	19	ethanol	ethanol	NOUN
eurjchem-624	74	20	and	and	CCONJ
eurjchem-624	74	21	in	in	ADP
eurjchem-624	74	22	97	97	NUM
eurjchem-624	74	23	%	%	NOUN
eurjchem-624	74	24	and	and	CCONJ
eurjchem-624	74	25	90	90	NUM
eurjchem-624	74	26	%	%	NOUN
eurjchem-624	74	27	tfe	tfe	NOUN
eurjchem-624	74	28	(	(	PUNCT
eurjchem-624	74	29	w	w	PROPN
eurjchem-624	74	30	/	/	SYM
eurjchem-624	74	31	w	w	NOUN
eurjchem-624	74	32	)	)	PUNCT
eurjchem-624	74	33	at	at	ADP
eurjchem-624	74	34	temperatures	temperature	NOUN
eurjchem-624	74	35	other	other	ADJ
eurjchem-624	74	36	than	than	ADP
eurjchem-624	74	37	25.0	25.0	NUM
eurjchem-624	74	38	oc	oc	NOUN
eurjchem-624	74	39	and	and	CCONJ
eurjchem-624	74	40	the	the	DET
eurjchem-624	74	41	enthalpies	enthalpy	NOUN
eurjchem-624	74	42	(	(	PUNCT
eurjchem-624	74	43	δh≠	δh≠	NOUN
eurjchem-624	74	44	)	)	PUNCT
eurjchem-624	74	45	and	and	CCONJ
eurjchem-624	74	46	entropies	entropy	NOUN
eurjchem-624	74	47	(	(	PUNCT
eurjchem-624	74	48	δs≠	δs≠	NOUN
eurjchem-624	74	49	)	)	PUNCT
eurjchem-624	74	50	of	of	ADP
eurjchem-624	74	51	activation	activation	NOUN
eurjchem-624	74	52	.	.	PUNCT
eurjchem-624	75	1	solvent	solvent	ADJ
eurjchem-624	75	2	temp	temp	NOUN
eurjchem-624	75	3	,	,	PUNCT
eurjchem-624	75	4	oc	oc	ADP
eurjchem-624	75	5	104	104	NUM
eurjchem-624	75	6	k1	k1	NOUN
eurjchem-624	75	7	,	,	PUNCT
eurjchem-624	75	8	s‐1	s‐1	VERB
eurjchem-624	75	9	a	a	DET
eurjchem-624	75	10	δh≠298	δh≠298	NOUN
eurjchem-624	75	11	(	(	PUNCT
eurjchem-624	75	12	kcal	kcal	ADJ
eurjchem-624	75	13	/	/	SYM
eurjchem-624	75	14	mole	mole	NOUN
eurjchem-624	75	15	)	)	PUNCT
eurjchem-624	75	16	b	b	NOUN
eurjchem-624	75	17	,	,	PUNCT
eurjchem-624	75	18	c	c	NOUN
eurjchem-624	75	19	δs≠298	δs≠298	NOUN
eurjchem-624	75	20	(	(	PUNCT
eurjchem-624	75	21	eu	eu	PROPN
eurjchem-624	75	22	)	)	PUNCT
eurjchem-624	75	23	b	b	NOUN
eurjchem-624	75	24	,	,	PUNCT
eurjchem-624	75	25	c	c	PROPN
eurjchem-624	75	26	100	100	NUM
eurjchem-624	75	27	%	%	NOUN
eurjchem-624	75	28	etoh	etoh	PROPN
eurjchem-624	75	29	42.0	42.0	NUM
eurjchem-624	75	30	0.444	0.444	NUM
eurjchem-624	75	31	±	±	NUM
eurjchem-624	75	32	0.002	0.002	NUM
eurjchem-624	75	33	19.2	19.2	NUM
eurjchem-624	75	34	±	±	NUM
eurjchem-624	75	35	0.5	0.5	NUM
eurjchem-624	75	36	‐17.4	‐17.4	NUM
eurjchem-624	75	37	±	±	NUM
eurjchem-624	75	38	1.6	1.6	NUM
eurjchem-624	75	39	50.0	50.0	NUM
eurjchem-624	75	40	0.975	0.975	NUM
eurjchem-624	75	41	±	±	NUM
eurjchem-624	75	42	0.001	0.001	NUM
eurjchem-624	75	43	55.0	55.0	NUM
eurjchem-624	75	44	1.71	1.71	NUM
eurjchem-624	75	45	±	±	NUM
eurjchem-624	75	46	0.01	0.01	NUM
eurjchem-624	75	47	80	80	NUM
eurjchem-624	75	48	%	%	NOUN
eurjchem-624	75	49	etoh	etoh	NOUN
eurjchem-624	75	50	30.0	30.0	NUM
eurjchem-624	75	51	6.56	6.56	NUM
eurjchem-624	75	52	±	±	NUM
eurjchem-624	75	53	0.03	0.03	NUM
eurjchem-624	75	54	18.5	18.5	NUM
eurjchem-624	75	55	±	±	NUM
eurjchem-624	75	56	0.4	0.4	NUM
eurjchem-624	75	57	‐12.2	‐12.2	NUM
eurjchem-624	75	58	±	±	NUM
eurjchem-624	75	59	1.4	1.4	NUM
eurjchem-624	75	60	35.0	35.0	NUM
eurjchem-624	75	61	11.4	11.4	NUM
eurjchem-624	75	62	±	±	NUM
eurjchem-624	75	63	0.3	0.3	NUM
eurjchem-624	75	64	40.0	40.0	NUM
eurjchem-624	75	65	18.6	18.6	NUM
eurjchem-624	75	66	±	±	NUM
eurjchem-624	75	67	0.2	0.2	NUM
eurjchem-624	75	68	97	97	NUM
eurjchem-624	75	69	%	%	NOUN
eurjchem-624	75	70	tfe	tfe	NOUN
eurjchem-624	75	71	2.0	2.0	NUM
eurjchem-624	75	72	44.7	44.7	NUM
eurjchem-624	75	73	±	±	NUM
eurjchem-624	75	74	0.7	0.7	NUM
eurjchem-624	75	75	15.4	15.4	NUM
eurjchem-624	75	76	±	±	NUM
eurjchem-624	75	77	0.7	0.7	NUM
eurjchem-624	75	78	‐13.7	‐13.7	NOUN
eurjchem-624	75	79	±	±	NUM
eurjchem-624	75	80	2.6	2.6	NUM
eurjchem-624	75	81	(	(	PUNCT
eurjchem-624	75	82	w	w	PROPN
eurjchem-624	75	83	/	/	SYM
eurjchem-624	75	84	w	w	NOUN
eurjchem-624	75	85	)	)	PUNCT
eurjchem-624	75	86	0.0	0.0	NUM
eurjchem-624	75	87	34.5	34.5	NUM
eurjchem-624	75	88	±	±	NUM
eurjchem-624	75	89	0.4	0.4	NUM
eurjchem-624	75	90	‐5.0	‐5.0	NUM
eurjchem-624	75	91	17.1	17.1	NUM
eurjchem-624	75	92	±	±	NUM
eurjchem-624	75	93	0.2	0.2	NUM
eurjchem-624	75	94	90	90	NUM
eurjchem-624	75	95	%	%	NOUN
eurjchem-624	75	96	tfe	tfe	NOUN
eurjchem-624	75	97	2.0	2.0	NUM
eurjchem-624	75	98	53.9	53.9	NUM
eurjchem-624	75	99	±	±	NUM
eurjchem-624	75	100	0.6	0.6	NUM
eurjchem-624	75	101	13.3	13.3	NUM
eurjchem-624	75	102	±	±	NUM
eurjchem-624	75	103	1.0	1.0	NUM
eurjchem-624	75	104	‐14.5	‐14.5	PROPN
eurjchem-624	75	105	±	±	NUM
eurjchem-624	75	106	3.6	3.6	NUM
eurjchem-624	75	107	(	(	PUNCT
eurjchem-624	75	108	w	w	PROPN
eurjchem-624	75	109	/	/	SYM
eurjchem-624	75	110	w	w	NOUN
eurjchem-624	75	111	)	)	PUNCT
eurjchem-624	75	112	0.0	0.0	NUM
eurjchem-624	75	113	42.3	42.3	NUM
eurjchem-624	75	114	±	±	NUM
eurjchem-624	75	115	0.8	0.8	NUM
eurjchem-624	75	116	‐5.0	‐5.0	NUM
eurjchem-624	75	117	20.9	20.9	NUM
eurjchem-624	75	118	±	±	NUM
eurjchem-624	75	119	0.5	0.5	NUM
eurjchem-624	75	120	a	a	PRON
eurjchem-624	75	121	with	with	ADP
eurjchem-624	75	122	associated	associated	ADJ
eurjchem-624	75	123	standard	standard	ADJ
eurjchem-624	75	124	deviations	deviation	NOUN
eurjchem-624	75	125	.	.	PUNCT
eurjchem-624	76	1	b	b	NOUN
eurjchem-624	76	2	based	base	VERB
eurjchem-624	76	3	on	on	ADP
eurjchem-624	76	4	four	four	NUM
eurjchem-624	76	5	temperatures	temperature	NOUN
eurjchem-624	76	6	(	(	PUNCT
eurjchem-624	76	7	also	also	ADV
eurjchem-624	76	8	including	include	VERB
eurjchem-624	76	9	the	the	DET
eurjchem-624	76	10	25.0	25.0	NUM
eurjchem-624	76	11	oc	oc	NOUN
eurjchem-624	76	12	value	value	NOUN
eurjchem-624	76	13	from	from	ADP
eurjchem-624	76	14	table	table	NOUN
eurjchem-624	76	15	1	1	NUM
eurjchem-624	76	16	)	)	PUNCT
eurjchem-624	76	17	.	.	PUNCT
eurjchem-624	77	1	c	c	NOUN
eurjchem-624	77	2	with	with	ADP
eurjchem-624	77	3	associated	associated	ADJ
eurjchem-624	77	4	standard	standard	ADJ
eurjchem-624	77	5	error	error	NOUN
eurjchem-624	77	6	.	.	PUNCT
eurjchem-624	78	1	the	the	DET
eurjchem-624	78	2	rate	rate	NOUN
eurjchem-624	78	3	data	datum	NOUN
eurjchem-624	78	4	of	of	ADP
eurjchem-624	78	5	table	table	NOUN
eurjchem-624	78	6	1	1	NUM
eurjchem-624	78	7	have	have	AUX
eurjchem-624	78	8	been	be	AUX
eurjchem-624	78	9	analyzed	analyze	VERB
eurjchem-624	78	10	in	in	ADP
eurjchem-624	78	11	terms	term	NOUN
eurjchem-624	78	12	of	of	ADP
eurjchem-624	78	13	both	both	CCONJ
eurjchem-624	78	14	the	the	DET
eurjchem-624	78	15	simple	simple	ADJ
eurjchem-624	78	16	(	(	PUNCT
eurjchem-624	78	17	equation	equation	NOUN
eurjchem-624	78	18	1	1	NUM
eurjchem-624	78	19	)	)	PUNCT
eurjchem-624	78	20	and	and	CCONJ
eurjchem-624	78	21	extended	extend	VERB
eurjchem-624	78	22	(	(	PUNCT
eurjchem-624	78	23	equation	equation	NOUN
eurjchem-624	78	24	2	2	NUM
eurjchem-624	78	25	)	)	PUNCT
eurjchem-624	78	26	forms	form	NOUN
eurjchem-624	78	27	of	of	ADP
eurjchem-624	78	28	the	the	DET
eurjchem-624	78	29	g‐w	g‐w	PROPN
eurjchem-624	78	30	equation	equation	NOUN
eurjchem-624	78	31	.	.	PUNCT
eurjchem-624	79	1	the	the	DET
eurjchem-624	79	2	correlation	correlation	NOUN
eurjchem-624	79	3	values	value	NOUN
eurjchem-624	79	4	;	;	PUNCT
eurjchem-624	79	5	sensitivities	sensitivity	NOUN
eurjchem-624	79	6	towards	towards	ADP
eurjchem-624	79	7	solvent	solvent	ADJ
eurjchem-624	79	8	nucleophilicity	nucleophilicity	NOUN
eurjchem-624	79	9	and	and	CCONJ
eurjchem-624	79	10	solvent	solvent	ADJ
eurjchem-624	79	11	ionizing	ionizing	NOUN
eurjchem-624	79	12	power	power	NOUN
eurjchem-624	79	13	,	,	PUNCT
eurjchem-624	79	14	intercept	intercept	NOUN
eurjchem-624	79	15	(	(	PUNCT
eurjchem-624	79	16	residual	residual	ADJ
eurjchem-624	79	17	)	)	PUNCT
eurjchem-624	79	18	values	value	NOUN
eurjchem-624	79	19	,	,	PUNCT
eurjchem-624	79	20	simple	simple	ADJ
eurjchem-624	79	21	and	and	CCONJ
eurjchem-624	79	22	multiple	multiple	ADJ
eurjchem-624	79	23	correlation	correlation	NOUN
eurjchem-624	79	24	coefficients	coefficient	NOUN
eurjchem-624	79	25	,	,	PUNCT
eurjchem-624	79	26	and	and	CCONJ
eurjchem-624	79	27	f‐test	f‐t	ADJ
eurjchem-624	79	28	values	value	NOUN
eurjchem-624	79	29	are	be	AUX
eurjchem-624	79	30	presented	present	VERB
eurjchem-624	79	31	in	in	ADP
eurjchem-624	79	32	table	table	NOUN
eurjchem-624	79	33	3	3	NUM
eurjchem-624	79	34	,	,	PUNCT
eurjchem-624	79	35	where	where	SCONJ
eurjchem-624	79	36	the	the	DET
eurjchem-624	79	37	values	value	NOUN
eurjchem-624	79	38	for	for	ADP
eurjchem-624	79	39	1	1	NUM
eurjchem-624	79	40	are	be	AUX
eurjchem-624	79	41	compared	compare	VERB
eurjchem-624	79	42	with	with	ADP
eurjchem-624	79	43	values	value	NOUN
eurjchem-624	79	44	for	for	ADP
eurjchem-624	79	45	a	a	DET
eurjchem-624	79	46	selection	selection	NOUN
eurjchem-624	79	47	of	of	ADP
eurjchem-624	79	48	solvolyses	solvolyse	NOUN
eurjchem-624	79	49	of	of	ADP
eurjchem-624	79	50	other	other	ADJ
eurjchem-624	79	51	haloformates	haloformate	NOUN
eurjchem-624	79	52	from	from	ADP
eurjchem-624	79	53	the	the	DET
eurjchem-624	79	54	literature	literature	NOUN
eurjchem-624	79	55	.	.	PUNCT
eurjchem-624	80	1	the	the	DET
eurjchem-624	80	2	analyses	analysis	NOUN
eurjchem-624	80	3	of	of	ADP
eurjchem-624	80	4	1	1	NUM
eurjchem-624	80	5	are	be	AUX
eurjchem-624	80	6	carried	carry	VERB
eurjchem-624	80	7	out	out	ADP
eurjchem-624	80	8	both	both	CCONJ
eurjchem-624	80	9	with	with	ADP
eurjchem-624	80	10	and	and	CCONJ
eurjchem-624	80	11	without	without	ADP
eurjchem-624	80	12	the	the	DET
eurjchem-624	80	13	tfe‐	tfe‐	NOUN
eurjchem-624	80	14	ethanol	ethanol	NOUN
eurjchem-624	80	15	data	datum	NOUN
eurjchem-624	80	16	points	point	NOUN
eurjchem-624	80	17	.	.	PUNCT
eurjchem-624	81	1	frequently	frequently	ADV
eurjchem-624	81	2	the	the	DET
eurjchem-624	81	3	tfe‐ethanol	tfe‐ethanol	ADJ
eurjchem-624	81	4	values	value	NOUN
eurjchem-624	81	5	deviate	deviate	VERB
eurjchem-624	81	6	from	from	ADP
eurjchem-624	81	7	the	the	DET
eurjchem-624	81	8	correlations	correlation	NOUN
eurjchem-624	81	9	in	in	ADP
eurjchem-624	81	10	pure	pure	ADJ
eurjchem-624	81	11	solvents	solvent	NOUN
eurjchem-624	81	12	and	and	CCONJ
eurjchem-624	81	13	aqueous	aqueous	ADJ
eurjchem-624	81	14	binary	binary	ADJ
eurjchem-624	81	15	solvents	solvent	NOUN
eurjchem-624	81	16	[	[	X
eurjchem-624	81	17	45	45	NUM
eurjchem-624	81	18	]	]	PUNCT
eurjchem-624	81	19	but	but	CCONJ
eurjchem-624	81	20	in	in	ADP
eurjchem-624	81	21	the	the	DET
eurjchem-624	81	22	present	present	ADJ
eurjchem-624	81	23	instance	instance	NOUN
eurjchem-624	81	24	,	,	PUNCT
eurjchem-624	81	25	as	as	SCONJ
eurjchem-624	81	26	can	can	AUX
eurjchem-624	81	27	be	be	AUX
eurjchem-624	81	28	seen	see	VERB
eurjchem-624	81	29	from	from	ADP
eurjchem-624	81	30	the	the	DET
eurjchem-624	81	31	values	value	NOUN
eurjchem-624	81	32	in	in	ADP
eurjchem-624	81	33	table	table	NOUN
eurjchem-624	81	34	3	3	NUM
eurjchem-624	81	35	and	and	CCONJ
eurjchem-624	81	36	from	from	ADP
eurjchem-624	81	37	figures	figure	NOUN
eurjchem-624	81	38	1	1	NUM
eurjchem-624	81	39	and	and	CCONJ
eurjchem-624	81	40	2	2	NUM
eurjchem-624	81	41	,	,	PUNCT
eurjchem-624	81	42	the	the	DET
eurjchem-624	81	43	four	four	NUM
eurjchem-624	81	44	tfe‐	tfe‐	NOUN
eurjchem-624	81	45	ethanol	ethanol	NOUN
eurjchem-624	81	46	solvolyses	solvolyse	VERB
eurjchem-624	81	47	conform	conform	VERB
eurjchem-624	81	48	to	to	ADP
eurjchem-624	81	49	the	the	DET
eurjchem-624	81	50	values	value	NOUN
eurjchem-624	81	51	for	for	ADP
eurjchem-624	81	52	the	the	DET
eurjchem-624	81	53	other	other	ADJ
eurjchem-624	81	54	15	15	NUM
eurjchem-624	81	55	solvolyses	solvolyse	NOUN
eurjchem-624	81	56	studied	study	VERB
eurjchem-624	81	57	.	.	PUNCT
eurjchem-624	82	1	figure	figure	NOUN
eurjchem-624	82	2	1	1	NUM
eurjchem-624	82	3	.	.	PUNCT
eurjchem-624	83	1	the	the	DET
eurjchem-624	83	2	plot	plot	NOUN
eurjchem-624	83	3	of	of	ADP
eurjchem-624	83	4	log	log	NOUN
eurjchem-624	83	5	(	(	PUNCT
eurjchem-624	83	6	k	k	NOUN
eurjchem-624	83	7	/	/	SYM
eurjchem-624	83	8	ko	ko	PROPN
eurjchem-624	83	9	)	)	PUNCT
eurjchem-624	83	10	for	for	ADP
eurjchem-624	83	11	tert‐butyl	tert‐butyl	X
eurjchem-624	83	12	chlorothioformate	chlorothioformate	NOUN
eurjchem-624	83	13	(	(	PUNCT
eurjchem-624	83	14	1	1	NUM
eurjchem-624	83	15	)	)	PUNCT
eurjchem-624	83	16	against	against	ADP
eurjchem-624	83	17	ycl	ycl	PROPN
eurjchem-624	83	18	in	in	ADP
eurjchem-624	83	19	the	the	DET
eurjchem-624	83	20	nineteen	nineteen	NUM
eurjchem-624	83	21	solvents	solvent	NOUN
eurjchem-624	83	22	of	of	ADP
eurjchem-624	83	23	this	this	DET
eurjchem-624	83	24	study	study	NOUN
eurjchem-624	83	25	;	;	PUNCT
eurjchem-624	83	26	slope	slope	NOUN
eurjchem-624	83	27	of	of	ADP
eurjchem-624	83	28	0.73	0.73	NUM
eurjchem-624	83	29	+	+	NOUN
eurjchem-624	83	30	0.03	0.03	NUM
eurjchem-624	83	31	.	.	PUNCT
eurjchem-624	84	1	a	a	DET
eurjchem-624	84	2	further	further	ADJ
eurjchem-624	84	3	observation	observation	NOUN
eurjchem-624	84	4	is	be	AUX
eurjchem-624	84	5	that	that	SCONJ
eurjchem-624	84	6	there	there	PRON
eurjchem-624	84	7	is	be	VERB
eurjchem-624	84	8	,	,	PUNCT
eurjchem-624	84	9	at	at	ADP
eurjchem-624	84	10	best	good	ADJ
eurjchem-624	84	11	,	,	PUNCT
eurjchem-624	84	12	only	only	ADV
eurjchem-624	84	13	a	a	DET
eurjchem-624	84	14	marginal	marginal	ADJ
eurjchem-624	84	15	improvement	improvement	NOUN
eurjchem-624	84	16	observed	observe	VERB
eurjchem-624	84	17	when	when	SCONJ
eurjchem-624	84	18	the	the	DET
eurjchem-624	84	19	values	value	NOUN
eurjchem-624	84	20	obtained	obtain	VERB
eurjchem-624	84	21	using	use	VERB
eurjchem-624	84	22	equation	equation	NOUN
eurjchem-624	84	23	2	2	NUM
eurjchem-624	84	24	are	be	AUX
eurjchem-624	84	25	compared	compare	VERB
eurjchem-624	84	26	to	to	ADP
eurjchem-624	84	27	those	those	PRON
eurjchem-624	84	28	obtained	obtain	VERB
eurjchem-624	84	29	using	use	VERB
eurjchem-624	84	30	equation	equation	NOUN
eurjchem-624	84	31	1	1	NUM
eurjchem-624	84	32	.	.	PUNCT
eurjchem-624	85	1	indeed	indeed	ADV
eurjchem-624	85	2	the	the	DET
eurjchem-624	85	3	four	four	NUM
eurjchem-624	85	4	correlation	correlation	NOUN
eurjchem-624	85	5	coefficients	coefficient	NOUN
eurjchem-624	85	6	,	,	PUNCT
eurjchem-624	85	7	equation	equation	NOUN
eurjchem-624	85	8	1	1	NUM
eurjchem-624	85	9	or	or	CCONJ
eurjchem-624	85	10	equation	equation	NOUN
eurjchem-624	85	11	2	2	NUM
eurjchem-624	85	12	coupled	couple	VERB
eurjchem-624	85	13	with	with	ADP
eurjchem-624	85	14	19	19	NUM
eurjchem-624	85	15	or	or	CCONJ
eurjchem-624	85	16	15	15	NUM
eurjchem-624	85	17	solvents	solvent	NOUN
eurjchem-624	85	18	,	,	PUNCT
eurjchem-624	85	19	vary	vary	VERB
eurjchem-624	85	20	only	only	ADV
eurjchem-624	85	21	from	from	ADP
eurjchem-624	85	22	0.998	0.998	NUM
eurjchem-624	85	23	to	to	ADP
eurjchem-624	85	24	0.991	0.991	NUM
eurjchem-624	85	25	.	.	PUNCT
eurjchem-624	86	1	figure	figure	NOUN
eurjchem-624	86	2	2	2	NUM
eurjchem-624	86	3	.	.	PUNCT
eurjchem-624	87	1	the	the	DET
eurjchem-624	87	2	plot	plot	NOUN
eurjchem-624	87	3	of	of	ADP
eurjchem-624	87	4	log	log	NOUN
eurjchem-624	87	5	(	(	PUNCT
eurjchem-624	87	6	k	k	NOUN
eurjchem-624	87	7	/	/	SYM
eurjchem-624	87	8	ko	ko	PROPN
eurjchem-624	87	9	)	)	PUNCT
eurjchem-624	87	10	for	for	ADP
eurjchem-624	87	11	tert‐butyl	tert‐butyl	X
eurjchem-624	87	12	chlorothioformate	chlorothioformate	NOUN
eurjchem-624	87	13	(	(	PUNCT
eurjchem-624	87	14	1	1	NUM
eurjchem-624	87	15	)	)	PUNCT
eurjchem-624	87	16	against	against	ADP
eurjchem-624	87	17	0.13	0.13	NUM
eurjchem-624	87	18	nt	not	PART
eurjchem-624	87	19	+	+	NUM
eurjchem-624	87	20	0.80	0.80	NUM
eurjchem-624	87	21	ycl	ycl	NOUN
eurjchem-624	87	22	in	in	ADP
eurjchem-624	87	23	the	the	DET
eurjchem-624	87	24	nineteen	nineteen	NUM
eurjchem-624	87	25	pure	pure	ADJ
eurjchem-624	87	26	and	and	CCONJ
eurjchem-624	87	27	binary	binary	ADJ
eurjchem-624	87	28	solvents	solvent	NOUN
eurjchem-624	87	29	studied	study	VERB
eurjchem-624	87	30	.	.	PUNCT
eurjchem-624	88	1	accordingly	accordingly	ADV
eurjchem-624	88	2	,	,	PUNCT
eurjchem-624	88	3	the	the	DET
eurjchem-624	88	4	f‐test	f‐t	ADJ
eurjchem-624	88	5	values	value	NOUN
eurjchem-624	88	6	on	on	ADP
eurjchem-624	88	7	moving	move	VERB
eurjchem-624	88	8	to	to	ADP
eurjchem-624	88	9	equation	equation	NOUN
eurjchem-624	88	10	2	2	NUM
eurjchem-624	88	11	are	be	AUX
eurjchem-624	88	12	about	about	ADV
eurjchem-624	88	13	halved	halve	VERB
eurjchem-624	88	14	and	and	CCONJ
eurjchem-624	88	15	the	the	DET
eurjchem-624	88	16	probabilities	probability	NOUN
eurjchem-624	88	17	that	that	PRON
eurjchem-624	88	18	the	the	DET
eurjchem-624	88	19	ln	ln	ADJ
eurjchem-624	88	20	term	term	NOUN
eurjchem-624	88	21	is	be	AUX
eurjchem-624	88	22	not	not	PART
eurjchem-624	88	23	statistically	statistically	ADV
eurjchem-624	88	24	significant	significant	ADJ
eurjchem-624	88	25	are	be	AUX
eurjchem-624	88	26	very	very	ADV
eurjchem-624	88	27	high	high	ADJ
eurjchem-624	88	28	at	at	ADP
eurjchem-624	88	29	0.17	0.17	NUM
eurjchem-624	88	30	for	for	ADP
eurjchem-624	88	31	19	19	NUM
eurjchem-624	88	32	solvents	solvent	NOUN
eurjchem-624	88	33	and	and	CCONJ
eurjchem-624	88	34	0.22	0.22	NUM
eurjchem-624	88	35	for	for	ADP
eurjchem-624	88	36	15	15	NUM
eurjchem-624	88	37	solvents	solvent	NOUN
eurjchem-624	88	38	.	.	PUNCT
eurjchem-624	89	1	one	one	PRON
eurjchem-624	89	2	can	can	AUX
eurjchem-624	89	3	draw	draw	VERB
eurjchem-624	89	4	the	the	DET
eurjchem-624	89	5	conclusions	conclusion	NOUN
eurjchem-624	89	6	that	that	PRON
eurjchem-624	89	7	the	the	DET
eurjchem-624	89	8	specific	specific	ADJ
eurjchem-624	89	9	rates	rate	NOUN
eurjchem-624	89	10	of	of	ADP
eurjchem-624	89	11	solvolysis	solvolysis	NOUN
eurjchem-624	89	12	of	of	ADP
eurjchem-624	89	13	1	1	NUM
eurjchem-624	89	14	are	be	AUX
eurjchem-624	89	15	satisfactorily	satisfactorily	ADV
eurjchem-624	89	16	correlated	correlate	VERB
eurjchem-624	89	17	using	use	VERB
eurjchem-624	89	18	equation	equation	NOUN
eurjchem-624	89	19	1	1	NUM
eurjchem-624	89	20	and	and	CCONJ
eurjchem-624	89	21	that	that	SCONJ
eurjchem-624	89	22	there	there	PRON
eurjchem-624	89	23	is	be	VERB
eurjchem-624	89	24	no	no	DET
eurjchem-624	89	25	justification	justification	NOUN
eurjchem-624	89	26	from	from	ADP
eurjchem-624	89	27	the	the	DET
eurjchem-624	89	28	analyses	analysis	NOUN
eurjchem-624	89	29	for	for	ADP
eurjchem-624	89	30	applying	apply	VERB
eurjchem-624	89	31	equation	equation	NOUN
eurjchem-624	89	32	2	2	NUM
eurjchem-624	89	33	.	.	PUNCT
eurjchem-624	90	1	however	however	ADV
eurjchem-624	90	2	,	,	PUNCT
eurjchem-624	90	3	one	one	PRON
eurjchem-624	90	4	can	can	AUX
eurjchem-624	90	5	not	not	PART
eurjchem-624	90	6	rule	rule	VERB
eurjchem-624	90	7	out	out	ADP
eurjchem-624	90	8	a	a	DET
eurjchem-624	90	9	small	small	ADJ
eurjchem-624	90	10	sensitivity	sensitivity	NOUN
eurjchem-624	90	11	towards	towards	ADP
eurjchem-624	90	12	changes	change	NOUN
eurjchem-624	90	13	in	in	ADP
eurjchem-624	90	14	solvent	solvent	ADJ
eurjchem-624	90	15	nucleophilicity	nucleophilicity	NOUN
eurjchem-624	90	16	.	.	PUNCT
eurjchem-624	91	1	other	other	ADJ
eurjchem-624	91	2	data	datum	NOUN
eurjchem-624	91	3	in	in	ADP
eurjchem-624	91	4	table	table	NOUN
eurjchem-624	91	5	3	3	NUM
eurjchem-624	91	6	are	be	AUX
eurjchem-624	91	7	for	for	ADP
eurjchem-624	91	8	1‐adamantyl	1‐adamantyl	NUM
eurjchem-624	91	9	chloroformate	chloroformate	NOUN
eurjchem-624	91	10	(	(	PUNCT
eurjchem-624	91	11	1‐adococl	1‐adococl	NUM
eurjchem-624	91	12	)	)	PUNCT
eurjchem-624	92	1	[	[	X
eurjchem-624	92	2	30,31	30,31	NUM
eurjchem-624	92	3	]	]	PUNCT
eurjchem-624	92	4	,	,	PUNCT
eurjchem-624	92	5	2‐adamantyl	2‐adamantyl	NUM
eurjchem-624	92	6	chloroformate	chloroformate	NOUN
eurjchem-624	92	7	(	(	PUNCT
eurjchem-624	92	8	2‐adococl	2‐adococl	NUM
eurjchem-624	92	9	)	)	PUNCT
eurjchem-624	93	1	[	[	X
eurjchem-624	93	2	24	24	NUM
eurjchem-624	93	3	]	]	PUNCT
eurjchem-624	93	4	,	,	PUNCT
eurjchem-624	93	5	isopropyl	isopropyl	NOUN
eurjchem-624	93	6	chloroformate	chloroformate	NOUN
eurjchem-624	93	7	(	(	PUNCT
eurjchem-624	93	8	i‐prococl	i‐prococl	VERB
eurjchem-624	93	9	)	)	PUNCT
eurjchem-624	94	1	[	[	X
eurjchem-624	94	2	22,23	22,23	NOUN
eurjchem-624	94	3	]	]	X
eurjchem-624	94	4	,	,	PUNCT
eurjchem-624	94	5	methyl	methyl	NOUN
eurjchem-624	94	6	chloroformate	chloroformate	NOUN
eurjchem-624	94	7	(	(	PUNCT
eurjchem-624	94	8	meococl	meococl	ADJ
eurjchem-624	94	9	)	)	PUNCT
eurjchem-624	95	1	[	[	X
eurjchem-624	95	2	18	18	NUM
eurjchem-624	95	3	]	]	PUNCT
eurjchem-624	95	4	,	,	PUNCT
eurjchem-624	95	5	and	and	CCONJ
eurjchem-624	95	6	phenyl	phenyl	NOUN
eurjchem-624	95	7	chloroformate	chloroformate	NOUN
eurjchem-624	95	8	(	(	PUNCT
eurjchem-624	95	9	phococl	phococl	NOUN
eurjchem-624	95	10	)	)	PUNCT
eurjchem-624	96	1	[	[	X
eurjchem-624	96	2	25	25	NUM
eurjchem-624	96	3	]	]	PUNCT
eurjchem-624	96	4	.	.	PUNCT
eurjchem-624	97	1	methyl	methyl	NOUN
eurjchem-624	97	2	chlorothioformate	chlorothioformate	NOUN
eurjchem-624	97	3	(	(	PUNCT
eurjchem-624	97	4	mescocl	mescocl	NOUN
eurjchem-624	97	5	)	)	PUNCT
eurjchem-624	98	1	[	[	X
eurjchem-624	98	2	7	7	NUM
eurjchem-624	98	3	]	]	PUNCT
eurjchem-624	98	4	,	,	PUNCT
eurjchem-624	98	5	ethyl	ethyl	PROPN
eurjchem-624	98	6	chlorothioformate	chlorothioformate	NOUN
eurjchem-624	98	7	(	(	PUNCT
eurjchem-624	98	8	etscocl)[6	etscocl)[6	NOUN
eurjchem-624	98	9	]	]	PUNCT
eurjchem-624	98	10	,	,	PUNCT
eurjchem-624	98	11	iso‐butyl	iso‐butyl	ADV
eurjchem-624	98	12	chlorothioformate	chlorothioformate	NOUN
eurjchem-624	98	13	(	(	PUNCT
eurjchem-624	98	14	i‐	i‐	ADJ
eurjchem-624	98	15	buscocl	buscocl	ADJ
eurjchem-624	98	16	)	)	PUNCT
eurjchem-624	99	1	[	[	X
eurjchem-624	99	2	9	9	NUM
eurjchem-624	99	3	]	]	PUNCT
eurjchem-624	99	4	,	,	PUNCT
eurjchem-624	99	5	the	the	DET
eurjchem-624	99	6	secondary	secondary	ADJ
eurjchem-624	99	7	iso‐propyl	iso‐propyl	ADJ
eurjchem-624	99	8	chlorothioformate	chlorothioformate	NOUN
eurjchem-624	99	9	(	(	PUNCT
eurjchem-624	99	10	i‐	i‐	NOUN
eurjchem-624	99	11	prscocl	prscocl	NOUN
eurjchem-624	99	12	)	)	PUNCT
eurjchem-624	100	1	[	[	X
eurjchem-624	100	2	8	8	NUM
eurjchem-624	100	3	]	]	PUNCT
eurjchem-624	100	4	,	,	PUNCT
eurjchem-624	100	5	and	and	CCONJ
eurjchem-624	100	6	two	two	NUM
eurjchem-624	100	7	tertiary	tertiary	ADJ
eurjchem-624	100	8	fluoroformates	fluoroformate	NOUN
eurjchem-624	100	9	,	,	PUNCT
eurjchem-624	100	10	tert‐butyl	tert‐butyl	ADP
eurjchem-624	100	11	fluoroformate	fluoroformate	NOUN
eurjchem-624	100	12	(	(	PUNCT
eurjchem-624	100	13	t‐buocof	t‐buocof	PUNCT
eurjchem-624	100	14	)	)	PUNCT
eurjchem-624	101	1	[	[	X
eurjchem-624	101	2	46	46	NUM
eurjchem-624	101	3	]	]	PUNCT
eurjchem-624	101	4	and	and	CCONJ
eurjchem-624	101	5	1‐adamantyl	1‐adamantyl	NUM
eurjchem-624	101	6	fluoroformate	fluoroformate	NOUN
eurjchem-624	101	7	(	(	PUNCT
eurjchem-624	101	8	1‐adocof)[36	1‐adocof)[36	NUM
eurjchem-624	101	9	]	]	PUNCT
eurjchem-624	101	10	are	be	AUX
eurjchem-624	101	11	additional	additional	ADJ
eurjchem-624	101	12	substrates	substrate	NOUN
eurjchem-624	101	13	for	for	ADP
eurjchem-624	101	14	which	which	PRON
eurjchem-624	101	15	the	the	DET
eurjchem-624	101	16	analyses	analysis	NOUN
eurjchem-624	101	17	of	of	ADP
eurjchem-624	101	18	their	their	PRON
eurjchem-624	101	19	rates	rate	NOUN
eurjchem-624	101	20	of	of	ADP
eurjchem-624	101	21	solvolysis	solvolysis	NOUN
eurjchem-624	101	22	are	be	AUX
eurjchem-624	101	23	presented	present	VERB
eurjchem-624	101	24	within	within	ADP
eurjchem-624	101	25	the	the	DET
eurjchem-624	101	26	table	table	NOUN
eurjchem-624	101	27	.	.	PUNCT
eurjchem-624	102	1	it	it	PRON
eurjchem-624	102	2	is	be	AUX
eurjchem-624	102	3	of	of	ADP
eurjchem-624	102	4	interest	interest	NOUN
eurjchem-624	102	5	that	that	PRON
eurjchem-624	102	6	in	in	ADP
eurjchem-624	102	7	the	the	DET
eurjchem-624	102	8	presence	presence	NOUN
eurjchem-624	102	9	of	of	ADP
eurjchem-624	102	10	antimony	antimony	NOUN
eurjchem-624	102	11	pentafluoride	pentafluoride	NOUN
eurjchem-624	102	12	as	as	ADP
eurjchem-624	102	13	a	a	DET
eurjchem-624	102	14	solution	solution	NOUN
eurjchem-624	102	15	in	in	ADP
eurjchem-624	102	16	so2	so2	PROPN
eurjchem-624	102	17	or	or	CCONJ
eurjchem-624	102	18	so2clf	so2clf	PROPN
eurjchem-624	102	19	,	,	PUNCT
eurjchem-624	102	20	methyl	methyl	NOUN
eurjchem-624	102	21	and	and	CCONJ
eurjchem-624	102	22	ethyl	ethyl	PROPN
eurjchem-624	102	23	chlorothioformates	chlorothioformate	NOUN
eurjchem-624	102	24	give	give	VERB
eurjchem-624	102	25	alkylthiocarbonyl	alkylthiocarbonyl	ADJ
eurjchem-624	102	26	cations	cation	NOUN
eurjchem-624	102	27	but	but	CCONJ
eurjchem-624	102	28	the	the	DET
eurjchem-624	102	29	corresponding	corresponding	ADJ
eurjchem-624	102	30	chloroformate	chloroformate	NOUN
eurjchem-624	102	31	(	(	PUNCT
eurjchem-624	102	32	or	or	CCONJ
eurjchem-624	102	33	halosulfite	halosulfite	ADJ
eurjchem-624	102	34	)	)	PUNCT
eurjchem-624	102	35	esters	ester	NOUN
eurjchem-624	102	36	react	react	VERB
eurjchem-624	102	37	with	with	ADP
eurjchem-624	102	38	loss	loss	NOUN
eurjchem-624	102	39	of	of	ADP
eurjchem-624	102	40	carbon	carbon	NOUN
eurjchem-624	102	41	dioxide	dioxide	NOUN
eurjchem-624	102	42	(	(	PUNCT
eurjchem-624	102	43	or	or	CCONJ
eurjchem-624	102	44	sulfur	sulfur	NOUN
eurjchem-624	102	45	dioxide	dioxide	NOUN
eurjchem-624	102	46	)	)	PUNCT
eurjchem-624	102	47	,	,	PUNCT
eurjchem-624	102	48	to	to	PART
eurjchem-624	102	49	give	give	VERB
eurjchem-624	102	50	alkyl	alkyl	ADJ
eurjchem-624	102	51	fluoroantimonates	fluoroantimonate	NOUN
eurjchem-624	102	52	(	(	PUNCT
eurjchem-624	102	53	for	for	ADP
eurjchem-624	102	54	chlorides	chloride	NOUN
eurjchem-624	102	55	a	a	DET
eurjchem-624	102	56	rapid	rapid	ADJ
eurjchem-624	102	57	exchange	exchange	NOUN
eurjchem-624	102	58	with	with	ADP
eurjchem-624	102	59	excess	excess	ADJ
eurjchem-624	102	60	antimony	antimony	NOUN
eurjchem-624	102	61	pentafluoride	pentafluoride	NOUN
eurjchem-624	102	62	occurs	occur	VERB
eurjchem-624	102	63	)	)	PUNCT
eurjchem-624	102	64	.	.	PUNCT
eurjchem-624	103	1	although	although	SCONJ
eurjchem-624	103	2	the	the	DET
eurjchem-624	103	3	conditions	condition	NOUN
eurjchem-624	103	4	are	be	AUX
eurjchem-624	103	5	very	very	ADV
eurjchem-624	103	6	different	different	ADJ
eurjchem-624	103	7	to	to	ADP
eurjchem-624	103	8	solvolysis	solvolysis	NOUN
eurjchem-624	103	9	conditions	condition	NOUN
eurjchem-624	103	10	,	,	PUNCT
eurjchem-624	103	11	these	these	DET
eurjchem-624	103	12	findings	finding	NOUN
eurjchem-624	104	1	[	[	X
eurjchem-624	104	2	47	47	NUM
eurjchem-624	104	3	]	]	PUNCT
eurjchem-624	104	4	do	do	AUX
eurjchem-624	104	5	indicate	indicate	VERB
eurjchem-624	104	6	that	that	SCONJ
eurjchem-624	104	7	halothioformates	halothioformate	NOUN
eurjchem-624	104	8	will	will	AUX
eurjchem-624	104	9	have	have	VERB
eurjchem-624	104	10	an	an	DET
eurjchem-624	104	11	increased	increase	VERB
eurjchem-624	104	12	tendency	tendency	NOUN
eurjchem-624	104	13	,	,	PUNCT
eurjchem-624	104	14	relative	relative	ADJ
eurjchem-624	104	15	to	to	ADP
eurjchem-624	104	16	haloformates	haloformate	NOUN
eurjchem-624	104	17	,	,	PUNCT
eurjchem-624	104	18	to	to	PART
eurjchem-624	104	19	follow	follow	VERB
eurjchem-624	104	20	scheme	scheme	NOUN
eurjchem-624	104	21	2a	2a	NUM
eurjchem-624	104	22	rather	rather	ADV
eurjchem-624	104	23	than	than	ADP
eurjchem-624	104	24	scheme	scheme	NOUN
eurjchem-624	104	25	2b	2b	NOUN
eurjchem-624	104	26	.	.	PUNCT
eurjchem-624	105	1	support	support	NOUN
eurjchem-624	105	2	for	for	ADP
eurjchem-624	105	3	this	this	DET
eurjchem-624	105	4	view	view	NOUN
eurjchem-624	105	5	comes	come	VERB
eurjchem-624	105	6	from	from	ADP
eurjchem-624	105	7	the	the	DET
eurjchem-624	105	8	observation	observation	NOUN
eurjchem-624	105	9	[	[	X
eurjchem-624	105	10	48	48	NUM
eurjchem-624	105	11	]	]	PUNCT
eurjchem-624	105	12	that	that	PRON
eurjchem-624	105	13	calculated	calculate	VERB
eurjchem-624	105	14	bond	bond	NOUN
eurjchem-624	105	15	dissociation	dissociation	NOUN
eurjchem-624	105	16	energies	energy	NOUN
eurjchem-624	105	17	suggest	suggest	VERB
eurjchem-624	105	18	that	that	SCONJ
eurjchem-624	105	19	a	a	DET
eurjchem-624	105	20	direct	direct	ADJ
eurjchem-624	105	21	cleavage	cleavage	NOUN
eurjchem-624	105	22	of	of	ADP
eurjchem-624	105	23	the	the	DET
eurjchem-624	105	24	co‐cl	co‐cl	X
eurjchem-624	105	25	bond	bond	NOUN
eurjchem-624	105	26	in	in	ADP
eurjchem-624	105	27	a	a	DET
eurjchem-624	105	28	chlorothioformate	chlorothioformate	NOUN
eurjchem-624	105	29	would	would	AUX
eurjchem-624	105	30	be	be	AUX
eurjchem-624	105	31	a	a	DET
eurjchem-624	105	32	relatively	relatively	ADV
eurjchem-624	105	33	favorable	favorable	ADJ
eurjchem-624	105	34	process	process	NOUN
eurjchem-624	105	35	.	.	PUNCT
eurjchem-624	106	1	a	a	DET
eurjchem-624	106	2	comparison	comparison	NOUN
eurjchem-624	106	3	of	of	ADP
eurjchem-624	106	4	the	the	DET
eurjchem-624	106	5	rates	rate	NOUN
eurjchem-624	106	6	of	of	ADP
eurjchem-624	106	7	solvolysis	solvolysis	NOUN
eurjchem-624	106	8	of	of	ADP
eurjchem-624	106	9	mescocl	mescocl	NOUN
eurjchem-624	106	10	,	,	PUNCT
eurjchem-624	106	11	etscocl	etscocl	NOUN
eurjchem-624	106	12	,	,	PUNCT
eurjchem-624	106	13	i‐buscocl	i‐buscocl	X
eurjchem-624	106	14	,	,	PUNCT
eurjchem-624	106	15	i‐prscocl	i‐prscocl	VERB
eurjchem-624	106	16	,	,	PUNCT
eurjchem-624	106	17	and	and	CCONJ
eurjchem-624	106	18	t‐buscocl	t‐buscocl	PUNCT
eurjchem-624	106	19	in	in	ADP
eurjchem-624	106	20	table	table	NOUN
eurjchem-624	106	21	4	4	NUM
eurjchem-624	106	22	shows	show	VERB
eurjchem-624	106	23	a	a	DET
eurjchem-624	106	24	very	very	ADV
eurjchem-624	106	25	similar	similar	ADJ
eurjchem-624	106	26	ethanolysis	ethanolysis	NOUN
eurjchem-624	106	27	rate	rate	NOUN
eurjchem-624	106	28	order	order	NOUN
eurjchem-624	106	29	of	of	ADP
eurjchem-624	106	30	kmescocl	kmescocl	PROPN
eurjchem-624	107	1	≈	≈	PROPN
eurjchem-624	107	2	ketscocl	ketscocl	PROPN
eurjchem-624	108	1	≈	≈	PROPN
eurjchem-624	108	2	ki‐	ki‐	PROPN
eurjchem-624	108	3	buscocl	buscocl	ADJ
eurjchem-624	109	1	≈	≈	PROPN
eurjchem-624	109	2	ki‐prscocl	ki‐prscocl	NOUN
eurjchem-624	110	1	≈	≈	PROPN
eurjchem-624	110	2	kt‐buscocl	kt‐buscocl	ADJ
eurjchem-624	110	3	.	.	PUNCT
eurjchem-624	111	1	on	on	ADP
eurjchem-624	111	2	the	the	DET
eurjchem-624	111	3	other	other	ADJ
eurjchem-624	111	4	hand	hand	NOUN
eurjchem-624	111	5	,	,	PUNCT
eurjchem-624	111	6	the	the	DET
eurjchem-624	111	7	methanolysis	methanolysis	NOUN
eurjchem-624	111	8	rate	rate	NOUN
eurjchem-624	111	9	of	of	ADP
eurjchem-624	111	10	the	the	DET
eurjchem-624	111	11	tertiary	tertiary	ADJ
eurjchem-624	111	12	alkyl	alkyl	NOUN
eurjchem-624	111	13	thioester	thioester	NOUN
eurjchem-624	111	14	is	be	AUX
eurjchem-624	111	15	three	three	NUM
eurjchem-624	111	16	times	time	NOUN
eurjchem-624	111	17	faster	fast	ADV
eurjchem-624	111	18	that	that	SCONJ
eurjchem-624	111	19	it	it	PRON
eurjchem-624	111	20	’s	’	VERB
eurjchem-624	111	21	secondary	secondary	ADJ
eurjchem-624	111	22	or	or	CCONJ
eurjchem-624	111	23	primary	primary	ADJ
eurjchem-624	111	24	counterparts	counterpart	NOUN
eurjchem-624	111	25	.	.	PUNCT
eurjchem-624	112	1	in	in	ADP
eurjchem-624	112	2	the	the	DET
eurjchem-624	112	3	highly	highly	ADV
eurjchem-624	112	4	ionizing	ionize	VERB
eurjchem-624	112	5	fluoroalcohols	fluoroalcohol	NOUN
eurjchem-624	112	6	[	[	PUNCT
eurjchem-624	112	7	tfe	tfe	NOUN
eurjchem-624	112	8	or	or	CCONJ
eurjchem-624	112	9	1,1,1,3,3,3‐hexafluoro‐2‐propanol	1,1,1,3,3,3‐hexafluoro‐2‐propanol	NUM
eurjchem-624	112	10	(	(	PUNCT
eurjchem-624	112	11	hfip	hfip	PROPN
eurjchem-624	112	12	)	)	PUNCT
eurjchem-624	112	13	]	]	PUNCT
eurjchem-624	112	14	,	,	PUNCT
eurjchem-624	112	15	the	the	DET
eurjchem-624	112	16	reactivity	reactivity	NOUN
eurjchem-624	112	17	order	order	NOUN
eurjchem-624	112	18	kmescocl	kmescocl	NOUN
eurjchem-624	112	19	<	<	X
eurjchem-624	112	20	ketscocl	ketscocl	PROPN
eurjchem-624	113	1	≈	≈	PROPN
eurjchem-624	113	2	ki‐buscocl	ki‐buscocl	PROPN
eurjchem-624	113	3	<	<	AUX
eurjchem-624	113	4	ki‐	ki‐	PROPN
eurjchem-624	113	5	prscocl	prscocl	NOUN
eurjchem-624	113	6	<	<	X
eurjchem-624	113	7	<	<	X
eurjchem-624	113	8	kt‐buscocl	kt‐buscocl	NOUN
eurjchem-624	113	9	observed	observe	VERB
eurjchem-624	113	10	,	,	PUNCT
eurjchem-624	113	11	is	be	AUX
eurjchem-624	113	12	now	now	ADV
eurjchem-624	113	13	greatly	greatly	ADV
eurjchem-624	113	14	influenced	influence	VERB
eurjchem-624	113	15	by	by	ADP
eurjchem-624	113	16	the	the	DET
eurjchem-624	113	17	alkyl	alkyl	PROPN
eurjchem-624	113	18	group	group	NOUN
eurjchem-624	113	19	structure	structure	NOUN
eurjchem-624	113	20	.	.	PUNCT
eurjchem-624	114	1	270	270	NUM
eurjchem-624	114	2	d'souza	d'souza	PROPN
eurjchem-624	114	3	et	et	PROPN
eurjchem-624	114	4	al	al	PROPN
eurjchem-624	114	5	.	.	PUNCT
eurjchem-624	114	6	/	/	SYM
eurjchem-624	114	7	european	european	PROPN
eurjchem-624	114	8	journal	journal	PROPN
eurjchem-624	114	9	of	of	ADP
eurjchem-624	114	10	chemistry	chemistry	NOUN
eurjchem-624	114	11	3	3	NUM
eurjchem-624	114	12	(	(	PUNCT
eurjchem-624	114	13	3	3	NUM
eurjchem-624	114	14	)	)	PUNCT
eurjchem-624	114	15	(	(	PUNCT
eurjchem-624	114	16	2012	2012	NUM
eurjchem-624	114	17	)	)	PUNCT
eurjchem-624	114	18	267‐272	267‐272	NUM
eurjchem-624	114	19	table	table	NOUN
eurjchem-624	114	20	3	3	NUM
eurjchem-624	114	21	.	.	PUNCT
eurjchem-624	114	22	correlation	correlation	NOUN
eurjchem-624	114	23	of	of	ADP
eurjchem-624	114	24	the	the	DET
eurjchem-624	114	25	specific	specific	ADJ
eurjchem-624	114	26	rates	rate	NOUN
eurjchem-624	114	27	of	of	ADP
eurjchem-624	114	28	reaction	reaction	NOUN
eurjchem-624	114	29	of	of	ADP
eurjchem-624	114	30	several	several	ADJ
eurjchem-624	114	31	chloro‐	chloro‐	NOUN
eurjchem-624	114	32	and	and	CCONJ
eurjchem-624	114	33	chlorothioformate	chlorothioformate	VERB
eurjchem-624	114	34	esters	ester	NOUN
eurjchem-624	114	35	and	and	CCONJ
eurjchem-624	114	36	tert‐butyl‐	tert‐butyl‐	PROPN
eurjchem-624	114	37	and	and	CCONJ
eurjchem-624	114	38	1‐adamantyl	1‐adamantyl	NUM
eurjchem-624	114	39	fluoroformate	fluoroformate	NOUN
eurjchem-624	114	40	using	use	VERB
eurjchem-624	114	41	the	the	DET
eurjchem-624	114	42	simple	simple	ADJ
eurjchem-624	114	43	and	and	CCONJ
eurjchem-624	114	44	extended	extended	ADJ
eurjchem-624	114	45	formsa	formsa	NOUN
eurjchem-624	114	46	of	of	ADP
eurjchem-624	114	47	the	the	DET
eurjchem-624	114	48	grunwald‐winstein	grunwald‐winstein	ADJ
eurjchem-624	114	49	equation	equation	NOUN
eurjchem-624	114	50	(	(	PUNCT
eurjchem-624	114	51	equation	equation	NOUN
eurjchem-624	114	52	1	1	NUM
eurjchem-624	114	53	and	and	CCONJ
eurjchem-624	114	54	equation	equation	NOUN
eurjchem-624	114	55	2	2	NUM
eurjchem-624	114	56	)	)	PUNCT
eurjchem-624	114	57	.	.	PUNCT
eurjchem-624	115	1	substrate	substrate	NOUN
eurjchem-624	115	2	nb	nb	PROPN
eurjchem-624	115	3	lc	lc	PROPN
eurjchem-624	115	4	,	,	PUNCT
eurjchem-624	116	1	d	d	X
eurjchem-624	116	2	mc	mc	PROPN
eurjchem-624	116	3	cc	cc	PROPN
eurjchem-624	116	4	l	l	PROPN
eurjchem-624	116	5	/	/	SYM
eurjchem-624	116	6	m	m	VERB
eurjchem-624	116	7	re	re	NOUN
eurjchem-624	116	8	ff	ff	X
eurjchem-624	116	9	mechanismg	mechanismg	ADV
eurjchem-624	116	10	t‐buscocl	t‐buscocl	PUNCT
eurjchem-624	116	11	(	(	PUNCT
eurjchem-624	116	12	1	1	X
eurjchem-624	116	13	)	)	PUNCT
eurjchem-624	116	14	19	19	NUM
eurjchem-624	116	15	‐	‐	NOUN
eurjchem-624	116	16	0.73	0.73	NUM
eurjchem-624	116	17	±	±	NUM
eurjchem-624	116	18	0.03	0.03	NUM
eurjchem-624	116	19	‐0.10	‐0.10	NUM
eurjchem-624	116	20	±	±	NUM
eurjchem-624	116	21	0.05	0.05	NUM
eurjchem-624	116	22	‐	‐	NOUN
eurjchem-624	116	23	0.988	0.988	NUM
eurjchem-624	116	24	686	686	NUM
eurjchem-624	116	25	i	i	PRON
eurjchem-624	116	26	19	19	NUM
eurjchem-624	116	27	0.13	0.13	NUM
eurjchem-624	116	28	±	±	NUM
eurjchem-624	116	29	0.09	0.09	NUM
eurjchem-624	116	30	(	(	PUNCT
eurjchem-624	116	31	0.17	0.17	NUM
eurjchem-624	116	32	)	)	PUNCT
eurjchem-624	116	33	0.80	0.80	NUM
eurjchem-624	116	34	±	±	NUM
eurjchem-624	116	35	0.06	0.06	NUM
eurjchem-624	116	36	‐0.03	‐0.03	NUM
eurjchem-624	116	37	±	±	NUM
eurjchem-624	116	38	0.07	0.07	NUM
eurjchem-624	116	39	0.16	0.16	NUM
eurjchem-624	116	40	0.989	0.989	NUM
eurjchem-624	116	41	365	365	NUM
eurjchem-624	116	42	i	i	PRON
eurjchem-624	116	43	15	15	NUM
eurjchem-624	116	44	‐	‐	VERB
eurjchem-624	116	45	0.72	0.72	NUM
eurjchem-624	116	46	±	±	NUM
eurjchem-624	116	47	0.03	0.03	NUM
eurjchem-624	116	48	‐0.04	‐0.04	NUM
eurjchem-624	116	49	±	±	NUM
eurjchem-624	116	50	0.06	0.06	NUM
eurjchem-624	116	51	‐	‐	NOUN
eurjchem-624	116	52	0.990	0.990	NUM
eurjchem-624	116	53	647	647	NUM
eurjchem-624	116	54	i	i	PRON
eurjchem-624	116	55	15	15	NUM
eurjchem-624	116	56	0.12	0.12	NUM
eurjchem-624	116	57	±	±	NUM
eurjchem-624	116	58	0.09	0.09	NUM
eurjchem-624	116	59	(	(	PUNCT
eurjchem-624	116	60	0.22	0.22	NUM
eurjchem-624	116	61	)	)	PUNCT
eurjchem-624	116	62	0.78	0.78	NUM
eurjchem-624	116	63	±	±	NOUN
eurjchem-624	116	64	0.06	0.06	NUM
eurjchem-624	116	65	0.02	0.02	NUM
eurjchem-624	116	66	±	±	NUM
eurjchem-624	116	67	0.07	0.07	NUM
eurjchem-624	116	68	0.15	0.15	NUM
eurjchem-624	116	69	0.991	0.991	NUM
eurjchem-624	116	70	341	341	NUM
eurjchem-624	116	71	i	i	NOUN
eurjchem-624	116	72	1‐adococlh	1‐adococlh	NUM
eurjchem-624	116	73	15	15	NUM
eurjchem-624	116	74	‐	‐	NOUN
eurjchem-624	116	75	0.47	0.47	NUM
eurjchem-624	116	76	±	±	NUM
eurjchem-624	116	77	0.03	0.03	NUM
eurjchem-624	116	78	0.03	0.03	NUM
eurjchem-624	116	79	±	±	NUM
eurjchem-624	116	80	0.05	0.05	NUM
eurjchem-624	116	81	‐	‐	NOUN
eurjchem-624	116	82	0.985	0.985	NUM
eurjchem-624	116	83	‐	‐	NOUN
eurjchem-624	116	84	i	i	PRON
eurjchem-624	116	85	11i	11i	NOUN
eurjchem-624	116	86	0.08	0.08	NUM
eurjchem-624	116	87	±	±	NUM
eurjchem-624	116	88	0.20	0.20	NUM
eurjchem-624	116	89	(	(	PUNCT
eurjchem-624	116	90	0.71	0.71	NUM
eurjchem-624	116	91	)	)	PUNCT
eurjchem-624	116	92	0.59	0.59	NUM
eurjchem-624	116	93	±	±	NUM
eurjchem-624	116	94	0.05	0.05	NUM
eurjchem-624	116	95	0.06	0.06	NUM
eurjchem-624	116	96	±	±	NUM
eurjchem-624	116	97	0.08	0.08	NUM
eurjchem-624	116	98	0.14	0.14	NUM
eurjchem-624	116	99	0.985	0.985	NUM
eurjchem-624	116	100	179	179	NUM
eurjchem-624	116	101	i	i	PRON
eurjchem-624	116	102	2‐adococlj	2‐adococlj	NUM
eurjchem-624	116	103	19	19	NUM
eurjchem-624	116	104	‐	‐	NOUN
eurjchem-624	116	105	0.47	0.47	NUM
eurjchem-624	116	106	±	±	NUM
eurjchem-624	116	107	0.03	0.03	NUM
eurjchem-624	116	108	‐0.11	‐0.11	NUM
eurjchem-624	116	109	±	±	NOUN
eurjchem-624	116	110	0.19	0.19	NUM
eurjchem-624	116	111	‐	‐	NOUN
eurjchem-624	116	112	0.970	0.970	NUM
eurjchem-624	116	113	‐	‐	NOUN
eurjchem-624	116	114	i	i	PRON
eurjchem-624	116	115	19	19	NUM
eurjchem-624	116	116	0.03	0.03	NUM
eurjchem-624	116	117	±	±	NUM
eurjchem-624	116	118	0.07	0.07	NUM
eurjchem-624	116	119	(	(	PUNCT
eurjchem-624	116	120	0.70	0.70	NUM
eurjchem-624	116	121	)	)	PUNCT
eurjchem-624	116	122	0.48	0.48	NUM
eurjchem-624	116	123	±	±	NUM
eurjchem-624	116	124	0.04	0.04	NUM
eurjchem-624	116	125	‐0.10	‐0.10	NUM
eurjchem-624	116	126	±	±	NUM
eurjchem-624	116	127	0.19	0.19	NUM
eurjchem-624	116	128	0.06	0.06	NUM
eurjchem-624	116	129	0.971	0.971	NUM
eurjchem-624	116	130	130	130	NUM
eurjchem-624	117	1	i	i	NOUN
eurjchem-624	117	2	i‐prococlk	i‐prococlk	VERB
eurjchem-624	117	3	9	9	NUM
eurjchem-624	117	4	1.35	1.35	NUM
eurjchem-624	117	5	±	±	NUM
eurjchem-624	117	6	0.22	0.22	NUM
eurjchem-624	117	7	0.40	0.40	NUM
eurjchem-624	117	8	±	±	NUM
eurjchem-624	117	9	0.05	0.05	NUM
eurjchem-624	117	10	0.18	0.18	NUM
eurjchem-624	117	11	±	±	NUM
eurjchem-624	117	12	0.07	0.07	NUM
eurjchem-624	117	13	3.38	3.38	NUM
eurjchem-624	117	14	0.960	0.960	NUM
eurjchem-624	117	15	35	35	NUM
eurjchem-624	117	16	a‐e	a‐e	PROPN
eurjchem-624	117	17	16	16	NUM
eurjchem-624	117	18	0.28	0.28	NUM
eurjchem-624	117	19	±	±	NUM
eurjchem-624	117	20	0.04	0.04	NUM
eurjchem-624	117	21	0.59	0.59	NUM
eurjchem-624	117	22	±	±	NUM
eurjchem-624	117	23	0.04	0.04	NUM
eurjchem-624	117	24	‐0.32	‐0.32	NUM
eurjchem-624	117	25	±	±	NUM
eurjchem-624	117	26	0.06	0.06	NUM
eurjchem-624	117	27	0.47	0.47	NUM
eurjchem-624	117	28	0.982	0.982	NUM
eurjchem-624	117	29	176	176	NUM
eurjchem-624	118	1	i	i	PRON
eurjchem-624	118	2	meococll	meococll	VERB
eurjchem-624	118	3	19	19	NUM
eurjchem-624	118	4	1.59	1.59	NUM
eurjchem-624	118	5	±	±	NUM
eurjchem-624	118	6	0.09	0.09	NUM
eurjchem-624	118	7	0.58	0.58	NUM
eurjchem-624	118	8	±	±	NUM
eurjchem-624	118	9	0.05	0.05	NUM
eurjchem-624	118	10	0.16	0.16	NUM
eurjchem-624	118	11	±	±	NUM
eurjchem-624	118	12	0.07	0.07	NUM
eurjchem-624	118	13	2.74	2.74	NUM
eurjchem-624	118	14	0.977	0.977	NUM
eurjchem-624	118	15	171	171	NUM
eurjchem-624	118	16	a‐e	a‐e	PROPN
eurjchem-624	118	17	phococlm	phococlm	NOUN
eurjchem-624	118	18	49	49	NUM
eurjchem-624	118	19	1.66	1.66	NUM
eurjchem-624	118	20	±	±	NUM
eurjchem-624	118	21	0.05	0.05	NUM
eurjchem-624	118	22	0.56	0.56	NUM
eurjchem-624	118	23	±	±	NUM
eurjchem-624	118	24	0.03	0.03	NUM
eurjchem-624	118	25	0.15	0.15	NUM
eurjchem-624	118	26	±	±	NUM
eurjchem-624	118	27	0.07	0.07	NUM
eurjchem-624	118	28	2.96	2.96	NUM
eurjchem-624	118	29	0.980	0.980	NUM
eurjchem-624	118	30	568	568	NUM
eurjchem-624	118	31	a‐e	a‐e	NOUN
eurjchem-624	118	32	mescocln	mescocln	PROPN
eurjchem-624	118	33	12	12	NUM
eurjchem-624	118	34	1.48	1.48	NUM
eurjchem-624	118	35	±	±	NUM
eurjchem-624	118	36	0.18	0.18	NUM
eurjchem-624	118	37	0.44	0.44	NUM
eurjchem-624	118	38	±0.06	±0.06	PROPN
eurjchem-624	118	39	0.08	0.08	NUM
eurjchem-624	118	40	±	±	NUM
eurjchem-624	118	41	0.08	0.08	NUM
eurjchem-624	118	42	3.36	3.36	NUM
eurjchem-624	118	43	0.949	0.949	NUM
eurjchem-624	118	44	40	40	NUM
eurjchem-624	118	45	a‐e	a‐e	PROPN
eurjchem-624	118	46	8	8	NUM
eurjchem-624	118	47	0.79	0.79	NUM
eurjchem-624	118	48	±	±	NUM
eurjchem-624	118	49	0.06	0.06	NUM
eurjchem-624	118	50	0.85	0.85	NUM
eurjchem-624	118	51	±	±	NUM
eurjchem-624	118	52	0.07	0.07	NUM
eurjchem-624	118	53	‐0.27	‐0.27	X
eurjchem-624	118	54	±	±	NUM
eurjchem-624	118	55	0.08	0.08	NUM
eurjchem-624	118	56	0.92	0.92	NUM
eurjchem-624	118	57	0.987	0.987	NUM
eurjchem-624	118	58	95	95	NUM
eurjchem-624	118	59	i	i	PRON
eurjchem-624	118	60	etscoclo	etscoclo	VERB
eurjchem-624	118	61	19	19	NUM
eurjchem-624	118	62	0.66	0.66	NUM
eurjchem-624	118	63	±	±	NUM
eurjchem-624	118	64	0.08	0.08	NUM
eurjchem-624	118	65	0.93	0.93	NUM
eurjchem-624	118	66	±	±	NUM
eurjchem-624	118	67	0.07	0.07	NUM
eurjchem-624	118	68	‐0.16	‐0.16	NUM
eurjchem-624	118	69	±	±	PROPN
eurjchem-624	119	1	0.11	0.11	NUM
eurjchem-624	119	2	0.71	0.71	NUM
eurjchem-624	119	3	0.961	0.961	NUM
eurjchem-624	119	4	96	96	NUM
eurjchem-624	119	5	i	i	NOUN
eurjchem-624	119	6	i‐prscoclp	i‐prscoclp	PUNCT
eurjchem-624	119	7	19	19	NUM
eurjchem-624	119	8	0.38	0.38	NUM
eurjchem-624	119	9	±	±	NUM
eurjchem-624	119	10	0.11	0.11	NUM
eurjchem-624	119	11	0.72	0.72	NUM
eurjchem-624	119	12	±	±	NUM
eurjchem-624	119	13	0.09	0.09	NUM
eurjchem-624	119	14	‐0.28	‐0.28	PROPN
eurjchem-624	119	15	±	±	NUM
eurjchem-624	119	16	0.10	0.10	NUM
eurjchem-624	119	17	0.53	0.53	NUM
eurjchem-624	119	18	0.961	0.961	NUM
eurjchem-624	119	19	97	97	NUM
eurjchem-624	120	1	i	i	PRON
eurjchem-624	120	2	i‐buscoclq	i‐buscoclq	VERB
eurjchem-624	120	3	15	15	NUM
eurjchem-624	120	4	0.42	0.42	NUM
eurjchem-624	120	5	±	±	NUM
eurjchem-624	120	6	0.13	0.13	NUM
eurjchem-624	120	7	0.73	0.73	NUM
eurjchem-624	120	8	±	±	NUM
eurjchem-624	120	9	0.09	0.09	NUM
eurjchem-624	120	10	‐0.37	‐0.37	NUM
eurjchem-624	120	11	±	±	NOUN
eurjchem-624	120	12	0.13	0.13	NUM
eurjchem-624	120	13	0.58	0.58	NUM
eurjchem-624	120	14	0.961	0.961	NUM
eurjchem-624	120	15	73	73	NUM
eurjchem-624	121	1	i	i	NOUN
eurjchem-624	121	2	t‐buocofr	t‐buocofr	NUM
eurjchem-624	121	3	17	17	NUM
eurjchem-624	121	4	0.41	0.41	NUM
eurjchem-624	121	5	±	±	NUM
eurjchem-624	121	6	0.05	0.05	NUM
eurjchem-624	121	7	0.65	0.65	NUM
eurjchem-624	121	8	±	±	NUM
eurjchem-624	121	9	0.03	0.03	NUM
eurjchem-624	121	10	0.02	0.02	NUM
eurjchem-624	121	11	±	±	NUM
eurjchem-624	121	12	0.04	0.04	NUM
eurjchem-624	121	13	0.63	0.63	NUM
eurjchem-624	121	14	0.989	0.989	NUM
eurjchem-624	121	15	301	301	NUM
eurjchem-624	121	16	i	i	NOUN
eurjchem-624	121	17	1‐adocofs	1‐adocofs	NUM
eurjchem-624	121	18	16	16	NUM
eurjchem-624	121	19	‐	‐	NOUN
eurjchem-624	121	20	0.70	0.70	NUM
eurjchem-624	121	21	+	+	CCONJ
eurjchem-624	121	22	0.01	0.01	NUM
eurjchem-624	121	23	‐0.02	‐0.02	NOUN
eurjchem-624	122	1	+	+	CCONJ
eurjchem-624	122	2	0.05	0.05	NUM
eurjchem-624	122	3	‐	‐	NOUN
eurjchem-624	122	4	0.999	0.999	NUM
eurjchem-624	122	5	‐	‐	NOUN
eurjchem-624	122	6	i	i	PRON
eurjchem-624	122	7	cl3cc(ch3)2ococlt	cl3cc(ch3)2ococlt	VERB
eurjchem-624	122	8	33	33	NUM
eurjchem-624	122	9	1.42	1.42	NUM
eurjchem-624	123	1	+	+	CCONJ
eurjchem-624	123	2	0.09	0.09	NUM
eurjchem-624	123	3	0.39	0.39	NUM
eurjchem-624	124	1	+	+	NUM
eurjchem-624	124	2	0.05	0.05	NUM
eurjchem-624	124	3	0.16	0.16	NUM
eurjchem-624	125	1	+	+	CCONJ
eurjchem-624	125	2	0.08	0.08	NUM
eurjchem-624	125	3	3.64	3.64	NUM
eurjchem-624	125	4	0.945	0.945	NUM
eurjchem-624	125	5	‐	‐	NOUN
eurjchem-624	125	6	a‐e	a‐e	PROPN
eurjchem-624	125	7	a	a	DET
eurjchem-624	125	8	which	which	DET
eurjchem-624	125	9	form	form	NOUN
eurjchem-624	125	10	used	use	VERB
eurjchem-624	125	11	is	be	AUX
eurjchem-624	125	12	clear	clear	ADJ
eurjchem-624	125	13	from	from	ADP
eurjchem-624	125	14	the	the	DET
eurjchem-624	125	15	presence	presence	NOUN
eurjchem-624	125	16	or	or	CCONJ
eurjchem-624	125	17	absence	absence	NOUN
eurjchem-624	125	18	of	of	ADP
eurjchem-624	125	19	an	an	DET
eurjchem-624	125	20	l	l	NOUN
eurjchem-624	125	21	value	value	NOUN
eurjchem-624	125	22	.	.	PUNCT
eurjchem-624	126	1	b	b	X
eurjchem-624	127	1	n	n	PRON
eurjchem-624	127	2	is	be	AUX
eurjchem-624	127	3	the	the	DET
eurjchem-624	127	4	number	number	NOUN
eurjchem-624	127	5	of	of	ADP
eurjchem-624	127	6	solvents	solvent	NOUN
eurjchem-624	127	7	.	.	PUNCT
eurjchem-624	128	1	c	c	NOUN
eurjchem-624	128	2	with	with	ADP
eurjchem-624	128	3	associated	associated	ADJ
eurjchem-624	128	4	standard	standard	ADJ
eurjchem-624	128	5	error	error	NOUN
eurjchem-624	128	6	.	.	PUNCT
eurjchem-624	129	1	d	d	X
eurjchem-624	129	2	accompanied	accompany	VERB
eurjchem-624	129	3	by	by	ADP
eurjchem-624	129	4	the	the	DET
eurjchem-624	129	5	probabilities	probability	NOUN
eurjchem-624	129	6	that	that	PRON
eurjchem-624	129	7	the	the	DET
eurjchem-624	129	8	lnt	lnt	NOUN
eurjchem-624	129	9	term	term	NOUN
eurjchem-624	129	10	is	be	AUX
eurjchem-624	129	11	not	not	PART
eurjchem-624	129	12	statistically	statistically	ADV
eurjchem-624	129	13	significant	significant	ADJ
eurjchem-624	129	14	when	when	SCONJ
eurjchem-624	129	15	value	value	NOUN
eurjchem-624	129	16	is	be	AUX
eurjchem-624	129	17	greater	great	ADJ
eurjchem-624	129	18	than	than	ADP
eurjchem-624	129	19	0.001	0.001	NUM
eurjchem-624	129	20	.	.	PUNCT
eurjchem-624	130	1	e	e	ADP
eurjchem-624	130	2	simple	simple	ADJ
eurjchem-624	130	3	or	or	CCONJ
eurjchem-624	130	4	multiple	multiple	ADJ
eurjchem-624	130	5	correlation	correlation	NOUN
eurjchem-624	130	6	coefficient	coefficient	NOUN
eurjchem-624	130	7	.	.	PUNCT
eurjchem-624	131	1	f	f	PROPN
eurjchem-624	131	2	f‐test	f‐test	PUNCT
eurjchem-624	131	3	value	value	NOUN
eurjchem-624	131	4	.	.	PUNCT
eurjchem-624	132	1	g	g	NOUN
eurjchem-624	132	2	ionization	ionization	NOUN
eurjchem-624	132	3	(	(	PUNCT
eurjchem-624	132	4	i	i	NOUN
eurjchem-624	132	5	)	)	PUNCT
eurjchem-624	132	6	or	or	CCONJ
eurjchem-624	132	7	addition‐elimination	addition‐elimination	NOUN
eurjchem-624	132	8	(	(	PUNCT
eurjchem-624	132	9	a‐e	a‐e	PROPN
eurjchem-624	132	10	)	)	PUNCT
eurjchem-624	132	11	.	.	PUNCT
eurjchem-624	133	1	h	h	NOUN
eurjchem-624	133	2	values	value	NOUN
eurjchem-624	133	3	taken	take	VERB
eurjchem-624	133	4	from	from	ADP
eurjchem-624	133	5	ref	ref	NOUN
eurjchem-624	133	6	.	.	PUNCT
eurjchem-624	134	1	[	[	X
eurjchem-624	134	2	22,23,30,31	22,23,30,31	NUM
eurjchem-624	134	3	]	]	PUNCT
eurjchem-624	134	4	.	.	PUNCT
eurjchem-624	135	1	i	i	PRON
eurjchem-624	135	2	see	see	VERB
eurjchem-624	135	3	ref	ref	NOUN
eurjchem-624	135	4	.	.	PUNCT
eurjchem-624	136	1	[	[	X
eurjchem-624	136	2	23	23	NUM
eurjchem-624	136	3	]	]	PUNCT
eurjchem-624	136	4	for	for	ADP
eurjchem-624	136	5	the	the	DET
eurjchem-624	136	6	11	11	NUM
eurjchem-624	136	7	solvents	solvent	NOUN
eurjchem-624	136	8	involved	involve	VERB
eurjchem-624	136	9	.	.	PUNCT
eurjchem-624	137	1	j	j	NOUN
eurjchem-624	137	2	with	with	ADP
eurjchem-624	137	3	omission	omission	NOUN
eurjchem-624	137	4	of	of	ADP
eurjchem-624	137	5	the	the	DET
eurjchem-624	137	6	four	four	NUM
eurjchem-624	137	7	data	datum	NOUN
eurjchem-624	137	8	points	point	NOUN
eurjchem-624	137	9	for	for	ADP
eurjchem-624	137	10	100	100	NUM
eurjchem-624	137	11	and	and	CCONJ
eurjchem-624	137	12	90	90	NUM
eurjchem-624	137	13	%	%	NOUN
eurjchem-624	137	14	etoh	etoh	NOUN
eurjchem-624	137	15	and	and	CCONJ
eurjchem-624	137	16	meoh	meoh	PROPN
eurjchem-624	137	17	.	.	PUNCT
eurjchem-624	138	1	k	k	PROPN
eurjchem-624	138	2	from	from	ADP
eurjchem-624	138	3	ref	ref	NOUN
eurjchem-624	138	4	.	.	PUNCT
eurjchem-624	139	1	[	[	X
eurjchem-624	139	2	23	23	NUM
eurjchem-624	139	3	]	]	PUNCT
eurjchem-624	139	4	.	.	PUNCT
eurjchem-624	140	1	l	l	NOUN
eurjchem-624	140	2	from	from	ADP
eurjchem-624	140	3	ref	ref	NOUN
eurjchem-624	140	4	.	.	PUNCT
eurjchem-624	141	1	[	[	X
eurjchem-624	141	2	18	18	NUM
eurjchem-624	141	3	]	]	PUNCT
eurjchem-624	141	4	.	.	PUNCT
eurjchem-624	142	1	m	m	VERB
eurjchem-624	142	2	from	from	ADP
eurjchem-624	142	3	ref	ref	NOUN
eurjchem-624	142	4	.	.	PUNCT
eurjchem-624	143	1	[	[	X
eurjchem-624	143	2	49	49	NUM
eurjchem-624	143	3	]	]	PUNCT
eurjchem-624	143	4	.	.	PUNCT
eurjchem-624	144	1	n	n	PROPN
eurjchem-624	144	2	from	from	ADP
eurjchem-624	144	3	ref	ref	NOUN
eurjchem-624	144	4	.	.	PUNCT
eurjchem-624	145	1	[	[	X
eurjchem-624	145	2	7	7	NUM
eurjchem-624	145	3	]	]	PUNCT
eurjchem-624	145	4	.	.	PUNCT
eurjchem-624	146	1	o	o	NOUN
eurjchem-624	146	2	from	from	ADP
eurjchem-624	146	3	ref	ref	NOUN
eurjchem-624	146	4	.	.	PUNCT
eurjchem-624	147	1	[	[	X
eurjchem-624	147	2	6	6	NUM
eurjchem-624	147	3	]	]	PUNCT
eurjchem-624	147	4	.	.	PUNCT
eurjchem-624	148	1	p	p	NOUN
eurjchem-624	148	2	from	from	ADP
eurjchem-624	148	3	ref	ref	NOUN
eurjchem-624	148	4	.	.	PUNCT
eurjchem-624	149	1	[	[	X
eurjchem-624	149	2	8	8	NUM
eurjchem-624	149	3	]	]	PUNCT
eurjchem-624	149	4	.	.	PUNCT
eurjchem-624	150	1	q	q	PUNCT
eurjchem-624	151	1	from	from	ADP
eurjchem-624	151	2	ref	ref	NOUN
eurjchem-624	151	3	.	.	PUNCT
eurjchem-624	152	1	[	[	X
eurjchem-624	152	2	9	9	NUM
eurjchem-624	152	3	]	]	PUNCT
eurjchem-624	152	4	.	.	PUNCT
eurjchem-624	153	1	r	r	NOUN
eurjchem-624	153	2	from	from	ADP
eurjchem-624	153	3	ref	ref	NOUN
eurjchem-624	153	4	.	.	PUNCT
eurjchem-624	154	1	[	[	X
eurjchem-624	154	2	46	46	NUM
eurjchem-624	154	3	]	]	PUNCT
eurjchem-624	154	4	.	.	PUNCT
eurjchem-624	155	1	s	s	VERB
eurjchem-624	155	2	from	from	ADP
eurjchem-624	155	3	ref	ref	NOUN
eurjchem-624	155	4	.	.	PUNCT
eurjchem-624	156	1	[	[	X
eurjchem-624	156	2	36	36	NUM
eurjchem-624	156	3	]	]	PUNCT
eurjchem-624	156	4	.	.	PUNCT
eurjchem-624	157	1	t	t	PROPN
eurjchem-624	157	2	from	from	ADP
eurjchem-624	157	3	ref	ref	NOUN
eurjchem-624	157	4	.	.	PUNCT
eurjchem-624	158	1	[	[	X
eurjchem-624	158	2	44	44	NUM
eurjchem-624	158	3	]	]	PUNCT
eurjchem-624	158	4	.	.	PUNCT
eurjchem-624	159	1	table	table	NOUN
eurjchem-624	159	2	4	4	NUM
eurjchem-624	159	3	.	.	PUNCT
eurjchem-624	160	1	a	a	DET
eurjchem-624	160	2	comparison	comparison	NOUN
eurjchem-624	160	3	of	of	ADP
eurjchem-624	160	4	the	the	DET
eurjchem-624	160	5	rates	rate	NOUN
eurjchem-624	160	6	of	of	ADP
eurjchem-624	160	7	solvolysis	solvolysis	NOUN
eurjchem-624	160	8	of	of	ADP
eurjchem-624	160	9	mescocl	mescocl	NOUN
eurjchem-624	160	10	,	,	PUNCT
eurjchem-624	160	11	etscocl	etscocl	NOUN
eurjchem-624	160	12	,	,	PUNCT
eurjchem-624	160	13	i‐buscocl	i‐buscocl	X
eurjchem-624	160	14	,	,	PUNCT
eurjchem-624	160	15	i‐prscocl	i‐prscocl	VERB
eurjchem-624	160	16	,	,	PUNCT
eurjchem-624	160	17	and	and	CCONJ
eurjchem-624	160	18	t‐buscocl	t‐buscocl	PUNCT
eurjchem-624	160	19	in	in	ADP
eurjchem-624	160	20	selected	select	VERB
eurjchem-624	160	21	common	common	ADJ
eurjchem-624	160	22	solvents	solvent	NOUN
eurjchem-624	160	23	at	at	ADP
eurjchem-624	160	24	25.0	25.0	NUM
eurjchem-624	160	25	oc	oc	NOUN
eurjchem-624	160	26	.	.	PUNCT
eurjchem-624	161	1	solvent	solvent	NOUN
eurjchem-624	161	2	(	(	PUNCT
eurjchem-624	161	3	%	%	INTJ
eurjchem-624	161	4	)	)	PUNCT
eurjchem-624	161	5	mescocl	mescocl	NOUN
eurjchem-624	161	6	105k	105k	NOUN
eurjchem-624	161	7	,	,	PUNCT
eurjchem-624	161	8	s‐1	s‐1	VERB
eurjchem-624	161	9	a	a	DET
eurjchem-624	161	10	etscocl	etscocl	NOUN
eurjchem-624	161	11	105k	105k	NOUN
eurjchem-624	161	12	,	,	PUNCT
eurjchem-624	161	13	s‐1	s‐1	VERB
eurjchem-624	161	14	b	b	PROPN
eurjchem-624	161	15	i‐buscocl	i‐buscocl	ADP
eurjchem-624	161	16	105k	105k	PROPN
eurjchem-624	161	17	,	,	PUNCT
eurjchem-624	161	18	s‐1	s‐1	VERB
eurjchem-624	161	19	c	c	NOUN
eurjchem-624	161	20	i‐prscocl	i‐prscocl	X
eurjchem-624	161	21	105k	105k	PROPN
eurjchem-624	161	22	,	,	PUNCT
eurjchem-624	161	23	s‐1	s‐1	VERB
eurjchem-624	161	24	d	d	NOUN
eurjchem-624	161	25	t‐buscocl	t‐buscocl	ADP
eurjchem-624	161	26	105k	105k	PROPN
eurjchem-624	161	27	,	,	PUNCT
eurjchem-624	161	28	s‐1	s‐1	VERB
eurjchem-624	161	29	e	e	NOUN
eurjchem-624	161	30	100	100	NUM
eurjchem-624	161	31	%	%	NOUN
eurjchem-624	161	32	meoh	meoh	NOUN
eurjchem-624	161	33	2.00	2.00	NUM
eurjchem-624	161	34	2.15	2.15	NUM
eurjchem-624	161	35	2.27	2.27	NUM
eurjchem-624	161	36	1.99	1.99	NUM
eurjchem-624	161	37	7.43	7.43	NUM
eurjchem-624	161	38	100	100	NUM
eurjchem-624	161	39	%	%	NOUN
eurjchem-624	161	40	etoh	etoh	NOUN
eurjchem-624	161	41	0.884	0.884	NUM
eurjchem-624	162	1	0.430	0.430	NUM
eurjchem-624	162	2	1.01	1.01	NUM
eurjchem-624	162	3	1.21	1.21	NUM
eurjchem-624	162	4	0.777	0.777	NUM
eurjchem-624	162	5	80	80	NUM
eurjchem-624	162	6	%	%	NOUN
eurjchem-624	162	7	etoh	etoh	NOUN
eurjchem-624	162	8	2.44	2.44	NUM
eurjchem-624	162	9	2.68	2.68	NUM
eurjchem-624	162	10	2.99	2.99	NUM
eurjchem-624	162	11	13.7	13.7	NUM
eurjchem-624	162	12	40.4	40.4	NUM
eurjchem-624	162	13	97	97	NUM
eurjchem-624	162	14	%	%	NOUN
eurjchem-624	162	15	tfe	tfe	NOUN
eurjchem-624	162	16	0.986	0.986	NUM
eurjchem-624	162	17	5.98	5.98	NUM
eurjchem-624	162	18	6.01	6.01	NUM
eurjchem-624	162	19	49.8	49.8	NUM
eurjchem-624	162	20	3730	3730	NUM
eurjchem-624	162	21	90	90	NUM
eurjchem-624	162	22	%	%	NOUN
eurjchem-624	162	23	tfe	tfe	NOUN
eurjchem-624	162	24	1.92	1.92	NUM
eurjchem-624	162	25	10.2	10.2	NUM
eurjchem-624	162	26	11.7	11.7	NUM
eurjchem-624	162	27	69.5	69.5	NUM
eurjchem-624	162	28	3200	3200	NUM
eurjchem-624	162	29	70	70	NUM
eurjchem-624	162	30	%	%	NOUN
eurjchem-624	162	31	hfip	hfip	PROPN
eurjchem-624	162	32	13.9	13.9	NUM
eurjchem-624	162	33	81.3	81.3	NUM
eurjchem-624	162	34	78.4	78.4	NUM
eurjchem-624	162	35	659	659	NUM
eurjchem-624	162	36	43870	43870	NUM
eurjchem-624	162	37	a	a	DET
eurjchem-624	162	38	ref	ref	NOUN
eurjchem-624	163	1	[	[	X
eurjchem-624	163	2	7	7	NUM
eurjchem-624	163	3	]	]	PUNCT
eurjchem-624	163	4	.	.	PUNCT
eurjchem-624	164	1	b	b	X
eurjchem-624	164	2	rates	rate	NOUN
eurjchem-624	164	3	are	be	AUX
eurjchem-624	164	4	reported	report	VERB
eurjchem-624	164	5	at	at	ADP
eurjchem-624	164	6	24.2	24.2	NUM
eurjchem-624	164	7	oc	oc	NOUN
eurjchem-624	164	8	in	in	ADP
eurjchem-624	164	9	ref	ref	NOUN
eurjchem-624	164	10	.	.	PUNCT
eurjchem-624	165	1	[	[	X
eurjchem-624	165	2	6	6	NUM
eurjchem-624	165	3	]	]	PUNCT
eurjchem-624	165	4	.	.	PUNCT
eurjchem-624	166	1	c	c	PROPN
eurjchem-624	166	2	ref	ref	NOUN
eurjchem-624	166	3	.	.	PUNCT
eurjchem-624	167	1	[	[	X
eurjchem-624	167	2	9	9	NUM
eurjchem-624	167	3	]	]	PUNCT
eurjchem-624	167	4	.	.	PUNCT
eurjchem-624	168	1	d	d	PRON
eurjchem-624	168	2	ref	ref	NOUN
eurjchem-624	168	3	.	.	PUNCT
eurjchem-624	169	1	[	[	X
eurjchem-624	169	2	8	8	NUM
eurjchem-624	169	3	]	]	PUNCT
eurjchem-624	169	4	.	.	PUNCT
eurjchem-624	170	1	e	e	NOUN
eurjchem-624	170	2	table	table	NOUN
eurjchem-624	170	3	1	1	NUM
eurjchem-624	170	4	.	.	PUNCT
eurjchem-624	171	1	the	the	DET
eurjchem-624	171	2	analysis	analysis	NOUN
eurjchem-624	171	3	for	for	ADP
eurjchem-624	171	4	1	1	NUM
eurjchem-624	171	5	in	in	ADP
eurjchem-624	171	6	all	all	PRON
eurjchem-624	171	7	of	of	ADP
eurjchem-624	171	8	the	the	DET
eurjchem-624	171	9	19	19	NUM
eurjchem-624	171	10	solvents	solvent	NOUN
eurjchem-624	171	11	of	of	ADP
eurjchem-624	171	12	the	the	DET
eurjchem-624	171	13	study	study	NOUN
eurjchem-624	171	14	using	use	VERB
eurjchem-624	171	15	equation	equation	NOUN
eurjchem-624	171	16	1	1	NUM
eurjchem-624	171	17	leads	lead	VERB
eurjchem-624	171	18	to	to	ADP
eurjchem-624	171	19	an	an	DET
eurjchem-624	171	20	m	m	NOUN
eurjchem-624	171	21	value	value	NOUN
eurjchem-624	171	22	of	of	ADP
eurjchem-624	171	23	0.73±0.03	0.73±0.03	NUM
eurjchem-624	171	24	.	.	PUNCT
eurjchem-624	172	1	using	use	VERB
eurjchem-624	172	2	equation	equation	NOUN
eurjchem-624	172	3	2	2	NUM
eurjchem-624	172	4	values	value	NOUN
eurjchem-624	172	5	are	be	AUX
eurjchem-624	172	6	obtained	obtain	VERB
eurjchem-624	172	7	of	of	ADP
eurjchem-624	172	8	0.13±0.09	0.13±0.09	PROPN
eurjchem-624	172	9	for	for	ADP
eurjchem-624	172	10	l	l	NOUN
eurjchem-624	172	11	and	and	CCONJ
eurjchem-624	172	12	0.80±0.06	0.80±0.06	NOUN
eurjchem-624	172	13	for	for	ADP
eurjchem-624	172	14	m.	m.	NOUN
eurjchem-624	172	15	these	these	DET
eurjchem-624	172	16	values	value	NOUN
eurjchem-624	172	17	are	be	AUX
eurjchem-624	172	18	very	very	ADV
eurjchem-624	172	19	little	little	ADV
eurjchem-624	172	20	changed	change	VERB
eurjchem-624	172	21	for	for	ADP
eurjchem-624	172	22	analyses	analysis	NOUN
eurjchem-624	172	23	carried	carry	VERB
eurjchem-624	172	24	out	out	ADP
eurjchem-624	172	25	with	with	ADP
eurjchem-624	172	26	the	the	DET
eurjchem-624	172	27	omission	omission	NOUN
eurjchem-624	172	28	of	of	ADP
eurjchem-624	172	29	the	the	DET
eurjchem-624	172	30	four	four	NUM
eurjchem-624	172	31	data	datum	NOUN
eurjchem-624	172	32	points	point	NOUN
eurjchem-624	172	33	for	for	ADP
eurjchem-624	172	34	tfe‐ethanol	tfe‐ethanol	ADJ
eurjchem-624	172	35	(	(	PUNCT
eurjchem-624	172	36	t‐e	t‐e	NOUN
eurjchem-624	172	37	)	)	PUNCT
eurjchem-624	172	38	solvents	solvent	NOUN
eurjchem-624	172	39	.	.	PUNCT
eurjchem-624	173	1	the	the	DET
eurjchem-624	173	2	l	l	NOUN
eurjchem-624	173	3	/	/	SYM
eurjchem-624	173	4	m	m	PROPN
eurjchem-624	173	5	ratio	ratio	NOUN
eurjchem-624	173	6	of	of	ADP
eurjchem-624	173	7	0.16	0.16	NUM
eurjchem-624	173	8	observed	observed	ADJ
eurjchem-624	173	9	using	use	VERB
eurjchem-624	173	10	equation	equation	NOUN
eurjchem-624	173	11	2	2	NUM
eurjchem-624	173	12	is	be	AUX
eurjchem-624	173	13	low	low	ADJ
eurjchem-624	173	14	in	in	ADP
eurjchem-624	173	15	comparison	comparison	NOUN
eurjchem-624	173	16	to	to	ADP
eurjchem-624	173	17	those	those	PRON
eurjchem-624	173	18	obtained	obtain	VERB
eurjchem-624	173	19	for	for	ADP
eurjchem-624	173	20	the	the	DET
eurjchem-624	173	21	corresponding	corresponding	ADJ
eurjchem-624	173	22	primary	primary	ADJ
eurjchem-624	173	23	and	and	CCONJ
eurjchem-624	173	24	secondary	secondary	ADJ
eurjchem-624	173	25	alkyl	alkyl	NOUN
eurjchem-624	173	26	thioesters	thioester	NOUN
eurjchem-624	173	27	.	.	PUNCT
eurjchem-624	174	1	a	a	DET
eurjchem-624	174	2	dual	dual	ADJ
eurjchem-624	174	3	mechanism	mechanism	NOUN
eurjchem-624	174	4	was	be	AUX
eurjchem-624	174	5	proposed	propose	VERB
eurjchem-624	174	6	for	for	ADP
eurjchem-624	174	7	the	the	DET
eurjchem-624	174	8	solvolysis	solvolysis	NOUN
eurjchem-624	174	9	of	of	ADP
eurjchem-624	174	10	mescocl	mescocl	NOUN
eurjchem-624	174	11	[	[	X
eurjchem-624	174	12	7	7	NUM
eurjchem-624	174	13	]	]	PUNCT
eurjchem-624	174	14	.	.	PUNCT
eurjchem-624	175	1	in	in	ADP
eurjchem-624	175	2	12	12	NUM
eurjchem-624	175	3	of	of	ADP
eurjchem-624	175	4	the	the	DET
eurjchem-624	175	5	more	more	ADV
eurjchem-624	175	6	nucleophilic	nucleophilic	ADJ
eurjchem-624	175	7	solvents	solvent	NOUN
eurjchem-624	175	8	,	,	PUNCT
eurjchem-624	175	9	an	an	DET
eurjchem-624	175	10	l	l	NOUN
eurjchem-624	175	11	value	value	NOUN
eurjchem-624	175	12	of	of	ADP
eurjchem-624	175	13	1.48±0.18	1.48±0.18	NUM
eurjchem-624	175	14	and	and	CCONJ
eurjchem-624	175	15	an	an	DET
eurjchem-624	175	16	m	m	NOUN
eurjchem-624	175	17	value	value	NOUN
eurjchem-624	175	18	of	of	ADP
eurjchem-624	175	19	0.44±0.06	0.44±0.06	NOUN
eurjchem-624	175	20	were	be	AUX
eurjchem-624	175	21	obtained	obtain	VERB
eurjchem-624	175	22	.	.	PUNCT
eurjchem-624	176	1	the	the	DET
eurjchem-624	176	2	l	l	PROPN
eurjchem-624	176	3	/	/	SYM
eurjchem-624	176	4	m	m	PROPN
eurjchem-624	176	5	ratio	ratio	NOUN
eurjchem-624	176	6	of	of	ADP
eurjchem-624	176	7	3.36	3.36	NUM
eurjchem-624	176	8	is	be	AUX
eurjchem-624	176	9	consistent	consistent	ADJ
eurjchem-624	176	10	with	with	ADP
eurjchem-624	176	11	the	the	DET
eurjchem-624	176	12	proposal	proposal	NOUN
eurjchem-624	176	13	of	of	ADP
eurjchem-624	176	14	a	a	DET
eurjchem-624	176	15	dominant	dominant	ADJ
eurjchem-624	176	16	addition‐elimination	addition‐elimination	NOUN
eurjchem-624	176	17	mechanism	mechanism	NOUN
eurjchem-624	176	18	for	for	ADP
eurjchem-624	176	19	mescocl	mescocl	NOUN
eurjchem-624	176	20	in	in	ADP
eurjchem-624	176	21	these	these	DET
eurjchem-624	176	22	solvents	solvent	NOUN
eurjchem-624	176	23	.	.	PUNCT
eurjchem-624	177	1	in	in	ADP
eurjchem-624	177	2	the	the	DET
eurjchem-624	177	3	remaining	remain	VERB
eurjchem-624	177	4	eight	eight	NUM
eurjchem-624	177	5	highly	highly	ADV
eurjchem-624	177	6	ionizing	ionize	VERB
eurjchem-624	177	7	solvents	solvent	NOUN
eurjchem-624	177	8	studied	study	VERB
eurjchem-624	177	9	an	an	DET
eurjchem-624	177	10	l	l	NOUN
eurjchem-624	177	11	/	/	SYM
eurjchem-624	177	12	m	m	NOUN
eurjchem-624	177	13	ratio	ratio	NOUN
eurjchem-624	177	14	of	of	ADP
eurjchem-624	177	15	0.92	0.92	NUM
eurjchem-624	177	16	was	be	AUX
eurjchem-624	177	17	obtained	obtain	VERB
eurjchem-624	177	18	.	.	PUNCT
eurjchem-624	178	1	this	this	DET
eurjchem-624	178	2	value	value	NOUN
eurjchem-624	178	3	is	be	AUX
eurjchem-624	178	4	similar	similar	ADJ
eurjchem-624	178	5	to	to	ADP
eurjchem-624	178	6	the	the	DET
eurjchem-624	178	7	l	l	NOUN
eurjchem-624	178	8	/	/	SYM
eurjchem-624	178	9	m	m	NOUN
eurjchem-624	178	10	ratios	ratio	NOUN
eurjchem-624	178	11	(	(	PUNCT
eurjchem-624	178	12	0.53‐0.71	0.53‐0.71	NOUN
eurjchem-624	178	13	)	)	PUNCT
eurjchem-624	178	14	obtained	obtain	VERB
eurjchem-624	178	15	for	for	ADP
eurjchem-624	178	16	etscocl	etscocl	NOUN
eurjchem-624	178	17	,	,	PUNCT
eurjchem-624	178	18	i‐prscocl	i‐prscocl	VERB
eurjchem-624	178	19	,	,	PUNCT
eurjchem-624	178	20	and	and	CCONJ
eurjchem-624	178	21	i‐buscocl	i‐buscocl	PUNCT
eurjchem-624	178	22	.	.	PUNCT
eurjchem-624	179	1	these	these	DET
eurjchem-624	179	2	values	value	NOUN
eurjchem-624	179	3	were	be	AUX
eurjchem-624	179	4	considered	consider	VERB
eurjchem-624	179	5	[	[	PUNCT
eurjchem-624	179	6	6‐9	6‐9	NOUN
eurjchem-624	179	7	]	]	PUNCT
eurjchem-624	179	8	to	to	PART
eurjchem-624	179	9	reflect	reflect	VERB
eurjchem-624	179	10	an	an	DET
eurjchem-624	179	11	ionization	ionization	NOUN
eurjchem-624	179	12	mechanism	mechanism	NOUN
eurjchem-624	179	13	(	(	PUNCT
eurjchem-624	179	14	scheme	scheme	NOUN
eurjchem-624	179	15	2a	2a	NUM
eurjchem-624	179	16	)	)	PUNCT
eurjchem-624	179	17	involving	involve	VERB
eurjchem-624	179	18	loss	loss	NOUN
eurjchem-624	179	19	of	of	ADP
eurjchem-624	179	20	chloride	chloride	NOUN
eurjchem-624	179	21	ion	ion	NOUN
eurjchem-624	179	22	to	to	PART
eurjchem-624	179	23	give	give	VERB
eurjchem-624	179	24	a	a	DET
eurjchem-624	179	25	carboxylium	carboxylium	NOUN
eurjchem-624	179	26	ion	ion	NOUN
eurjchem-624	179	27	with	with	ADP
eurjchem-624	179	28	appreciable	appreciable	ADJ
eurjchem-624	179	29	stabilization	stabilization	NOUN
eurjchem-624	179	30	by	by	ADP
eurjchem-624	179	31	nucleophilic	nucleophilic	ADJ
eurjchem-624	179	32	solvation	solvation	NOUN
eurjchem-624	179	33	.	.	PUNCT
eurjchem-624	180	1	phenyl	phenyl	NOUN
eurjchem-624	180	2	chlorothioformate	chlorothioformate	NOUN
eurjchem-624	180	3	,	,	PUNCT
eurjchem-624	180	4	which	which	PRON
eurjchem-624	180	5	would	would	AUX
eurjchem-624	180	6	solvolyze	solvolyze	VERB
eurjchem-624	180	7	in	in	ADP
eurjchem-624	180	8	the	the	DET
eurjchem-624	180	9	usual	usual	ADJ
eurjchem-624	180	10	solvents	solvent	NOUN
eurjchem-624	180	11	employed	employ	VERB
eurjchem-624	180	12	in	in	ADP
eurjchem-624	180	13	g‐w	g‐w	PROPN
eurjchem-624	180	14	equation	equation	NOUN
eurjchem-624	180	15	studies	study	NOUN
eurjchem-624	180	16	without	without	ADP
eurjchem-624	180	17	involvement	involvement	NOUN
eurjchem-624	180	18	of	of	ADP
eurjchem-624	180	19	the	the	DET
eurjchem-624	180	20	phenyl	phenyl	NOUN
eurjchem-624	180	21	cation	cation	NOUN
eurjchem-624	180	22	shows	show	VERB
eurjchem-624	180	23	very	very	ADV
eurjchem-624	180	24	similar	similar	ADJ
eurjchem-624	180	25	behavior	behavior	NOUN
eurjchem-624	180	26	to	to	ADP
eurjchem-624	180	27	the	the	DET
eurjchem-624	180	28	solvolyses	solvolyse	NOUN
eurjchem-624	180	29	of	of	ADP
eurjchem-624	180	30	the	the	DET
eurjchem-624	180	31	methyl	methyl	NOUN
eurjchem-624	180	32	,	,	PUNCT
eurjchem-624	180	33	primary	primary	ADJ
eurjchem-624	180	34	and	and	CCONJ
eurjchem-624	180	35	secondary	secondary	ADJ
eurjchem-624	180	36	alkyl	alkyl	NOUN
eurjchem-624	180	37	thioesters	thioester	NOUN
eurjchem-624	180	38	,	,	PUNCT
eurjchem-624	180	39	with	with	SCONJ
eurjchem-624	180	40	the	the	DET
eurjchem-624	180	41	l	l	NOUN
eurjchem-624	180	42	and	and	CCONJ
eurjchem-624	180	43	m	m	PROPN
eurjchem-624	180	44	values	value	NOUN
eurjchem-624	180	45	observed	observe	VERB
eurjchem-624	180	46	being	be	AUX
eurjchem-624	180	47	0.62±0.08	0.62±0.08	ADJ
eurjchem-624	180	48	and	and	CCONJ
eurjchem-624	180	49	0.92±0.11	0.92±0.11	PROPN
eurjchem-624	180	50	,	,	PUNCT
eurjchem-624	180	51	respectively	respectively	ADV
eurjchem-624	180	52	[	[	X
eurjchem-624	180	53	5	5	NUM
eurjchem-624	180	54	]	]	PUNCT
eurjchem-624	180	55	.	.	PUNCT
eurjchem-624	181	1	in	in	ADP
eurjchem-624	181	2	this	this	DET
eurjchem-624	181	3	correlation	correlation	NOUN
eurjchem-624	181	4	,	,	PUNCT
eurjchem-624	181	5	the	the	DET
eurjchem-624	181	6	data	data	NOUN
eurjchem-624	181	7	points	point	VERB
eurjchem-624	181	8	in	in	ADP
eurjchem-624	181	9	100	100	NUM
eurjchem-624	181	10	%	%	NOUN
eurjchem-624	181	11	methanol	methanol	NOUN
eurjchem-624	181	12	and	and	CCONJ
eurjchem-624	181	13	100	100	NUM
eurjchem-624	181	14	%	%	NOUN
eurjchem-624	181	15	and	and	CCONJ
eurjchem-624	181	16	90	90	NUM
eurjchem-624	181	17	%	%	NOUN
eurjchem-624	181	18	ethanol	ethanol	NOUN
eurjchem-624	181	19	were	be	AUX
eurjchem-624	181	20	not	not	PART
eurjchem-624	181	21	included	include	VERB
eurjchem-624	181	22	in	in	ADP
eurjchem-624	181	23	the	the	DET
eurjchem-624	181	24	analyses	analysis	NOUN
eurjchem-624	181	25	because	because	SCONJ
eurjchem-624	181	26	of	of	ADP
eurjchem-624	181	27	the	the	DET
eurjchem-624	181	28	presence	presence	NOUN
eurjchem-624	181	29	of	of	ADP
eurjchem-624	181	30	an	an	DET
eurjchem-624	181	31	addition‐	addition‐	ADJ
eurjchem-624	181	32	elimination	elimination	NOUN
eurjchem-624	181	33	component	component	NOUN
eurjchem-624	181	34	.	.	PUNCT
eurjchem-624	182	1	the	the	DET
eurjchem-624	182	2	corresponding	corresponding	ADJ
eurjchem-624	182	3	values	value	NOUN
eurjchem-624	182	4	obtained	obtain	VERB
eurjchem-624	182	5	for	for	ADP
eurjchem-624	182	6	phenyl	phenyl	NOUN
eurjchem-624	182	7	chloroformate	chloroformate	NOUN
eurjchem-624	182	8	,	,	PUNCT
eurjchem-624	182	9	l	l	NOUN
eurjchem-624	182	10	value	value	NOUN
eurjchem-624	182	11	of	of	ADP
eurjchem-624	182	12	1.66±0.05	1.66±0.05	NUM
eurjchem-624	182	13	and	and	CCONJ
eurjchem-624	182	14	m	m	NOUN
eurjchem-624	182	15	value	value	NOUN
eurjchem-624	182	16	of	of	ADP
eurjchem-624	182	17	0.56±0.03	0.56±0.03	NOUN
eurjchem-624	182	18	including	include	VERB
eurjchem-624	182	19	all	all	PRON
eurjchem-624	182	20	of	of	ADP
eurjchem-624	182	21	the	the	DET
eurjchem-624	182	22	49	49	NUM
eurjchem-624	182	23	available	available	ADJ
eurjchem-624	182	24	solvolyses	solvolyse	VERB
eurjchem-624	182	25	[	[	X
eurjchem-624	182	26	49	49	NUM
eurjchem-624	182	27	]	]	PUNCT
eurjchem-624	182	28	,	,	PUNCT
eurjchem-624	182	29	can	can	AUX
eurjchem-624	182	30	be	be	AUX
eurjchem-624	182	31	taken	take	VERB
eurjchem-624	182	32	as	as	ADP
eurjchem-624	182	33	being	be	AUX
eurjchem-624	182	34	typical	typical	ADJ
eurjchem-624	182	35	for	for	ADP
eurjchem-624	182	36	the	the	DET
eurjchem-624	182	37	addition‐	addition‐	ADJ
eurjchem-624	182	38	elimination	elimination	NOUN
eurjchem-624	182	39	pathway	pathway	NOUN
eurjchem-624	182	40	,	,	PUNCT
eurjchem-624	182	41	with	with	ADP
eurjchem-624	182	42	the	the	DET
eurjchem-624	182	43	addition	addition	NOUN
eurjchem-624	182	44	step	step	NOUN
eurjchem-624	182	45	rate‐determining	rate‐determine	VERB
eurjchem-624	182	46	.	.	PUNCT
eurjchem-624	183	1	for	for	ADP
eurjchem-624	183	2	example	example	NOUN
eurjchem-624	183	3	,	,	PUNCT
eurjchem-624	183	4	for	for	ADP
eurjchem-624	183	5	50	50	NUM
eurjchem-624	183	6	of	of	ADP
eurjchem-624	183	7	51	51	NUM
eurjchem-624	183	8	solvolyses	solvolyse	NOUN
eurjchem-624	183	9	of	of	ADP
eurjchem-624	183	10	isopropenyl	isopropenyl	ADJ
eurjchem-624	183	11	chloroformate	chloroformate	NOUN
eurjchem-624	183	12	[	[	X
eurjchem-624	183	13	ch2	ch2	NOUN
eurjchem-624	183	14	=	=	NOUN
eurjchem-624	183	15	c(ch3)ococl	c(ch3)ococl	NOUN
eurjchem-624	183	16	]	]	X
eurjchem-624	183	17	(	(	PUNCT
eurjchem-624	183	18	97	97	NUM
eurjchem-624	183	19	%	%	NOUN
eurjchem-624	183	20	hfip	hfip	NOUN
eurjchem-624	183	21	specific	specific	ADJ
eurjchem-624	183	22	rate	rate	NOUN
eurjchem-624	183	23	value	value	NOUN
eurjchem-624	183	24	omitted	omit	VERB
eurjchem-624	183	25	)	)	PUNCT
eurjchem-624	183	26	,	,	PUNCT
eurjchem-624	183	27	very	very	ADV
eurjchem-624	183	28	similar	similar	ADJ
eurjchem-624	183	29	values	value	NOUN
eurjchem-624	183	30	of	of	ADP
eurjchem-624	183	31	1.54±0.03	1.54±0.03	NUM
eurjchem-624	183	32	and	and	CCONJ
eurjchem-624	183	33	0.54±0.03	0.54±0.03	NOUN
eurjchem-624	183	34	,	,	PUNCT
eurjchem-624	183	35	respectively	respectively	ADV
eurjchem-624	183	36	,	,	PUNCT
eurjchem-624	183	37	were	be	AUX
eurjchem-624	183	38	obtained	obtain	VERB
eurjchem-624	183	39	[	[	X
eurjchem-624	183	40	50	50	NUM
eurjchem-624	183	41	]	]	PUNCT
eurjchem-624	183	42	and	and	CCONJ
eurjchem-624	183	43	it	it	PRON
eurjchem-624	183	44	was	be	AUX
eurjchem-624	183	45	shown	show	VERB
eurjchem-624	183	46	that	that	SCONJ
eurjchem-624	183	47	the	the	DET
eurjchem-624	183	48	solvolyses	solvolyse	NOUN
eurjchem-624	183	49	of	of	ADP
eurjchem-624	183	50	phenyl	phenyl	NOUN
eurjchem-624	183	51	chloroformate	chloroformate	NOUN
eurjchem-624	183	52	was	be	AUX
eurjchem-624	183	53	a	a	DET
eurjchem-624	183	54	very	very	ADV
eurjchem-624	183	55	good	good	ADJ
eurjchem-624	183	56	similarity	similarity	NOUN
eurjchem-624	183	57	model	model	NOUN
eurjchem-624	183	58	to	to	PART
eurjchem-624	183	59	use	use	VERB
eurjchem-624	183	60	in	in	ADP
eurjchem-624	183	61	a	a	DET
eurjchem-624	183	62	linear	linear	ADJ
eurjchem-624	183	63	free	free	ADJ
eurjchem-624	183	64	energy	energy	NOUN
eurjchem-624	183	65	comparison	comparison	NOUN
eurjchem-624	183	66	with	with	ADP
eurjchem-624	183	67	the	the	DET
eurjchem-624	183	68	specific	specific	ADJ
eurjchem-624	183	69	rates	rate	NOUN
eurjchem-624	183	70	of	of	ADP
eurjchem-624	183	71	solvolysis	solvolysis	NOUN
eurjchem-624	183	72	of	of	ADP
eurjchem-624	183	73	isopropenyl	isopropenyl	NOUN
eurjchem-624	183	74	chloroformate	chloroformate	NOUN
eurjchem-624	183	75	,	,	PUNCT
eurjchem-624	183	76	with	with	ADP
eurjchem-624	183	77	a	a	DET
eurjchem-624	183	78	value	value	NOUN
eurjchem-624	183	79	of	of	ADP
eurjchem-624	183	80	0.95±0.02	0.95±0.02	NOUN
eurjchem-624	183	81	for	for	ADP
eurjchem-624	183	82	the	the	DET
eurjchem-624	183	83	slope	slope	NOUN
eurjchem-624	183	84	and	and	CCONJ
eurjchem-624	183	85	a	a	DET
eurjchem-624	183	86	correlation	correlation	NOUN
eurjchem-624	183	87	coefficient	coefficient	NOUN
eurjchem-624	183	88	of	of	ADP
eurjchem-624	183	89	0.991	0.991	NUM
eurjchem-624	183	90	.	.	PUNCT
eurjchem-624	184	1	as	as	ADP
eurjchem-624	184	2	examples	example	NOUN
eurjchem-624	184	3	of	of	ADP
eurjchem-624	184	4	compounds	compound	NOUN
eurjchem-624	184	5	involving	involve	VERB
eurjchem-624	184	6	a	a	DET
eurjchem-624	184	7	proposed	propose	VERB
eurjchem-624	184	8	concerted	concert	VERB
eurjchem-624	184	9	decomposition‐ionization	decomposition‐ionization	NOUN
eurjchem-624	184	10	process	process	NOUN
eurjchem-624	184	11	in	in	ADP
eurjchem-624	184	12	the	the	DET
eurjchem-624	184	13	rate‐determining	rate‐determining	NOUN
eurjchem-624	184	14	step	step	NOUN
eurjchem-624	184	15	,	,	PUNCT
eurjchem-624	184	16	d'souza	d'souza	PROPN
eurjchem-624	184	17	et	et	PROPN
eurjchem-624	184	18	al	al	PROPN
eurjchem-624	184	19	.	.	PUNCT
eurjchem-624	184	20	/	/	SYM
eurjchem-624	184	21	european	european	PROPN
eurjchem-624	184	22	journal	journal	PROPN
eurjchem-624	184	23	of	of	ADP
eurjchem-624	184	24	chemistry	chemistry	NOUN
eurjchem-624	184	25	3	3	NUM
eurjchem-624	184	26	(	(	PUNCT
eurjchem-624	184	27	3	3	NUM
eurjchem-624	184	28	)	)	PUNCT
eurjchem-624	184	29	(	(	PUNCT
eurjchem-624	184	30	2012	2012	NUM
eurjchem-624	184	31	)	)	PUNCT
eurjchem-624	184	32	267‐272	267‐272	PROPN
eurjchem-624	184	33	271	271	NUM
eurjchem-624	184	34	we	we	PRON
eurjchem-624	184	35	can	can	AUX
eurjchem-624	184	36	look	look	VERB
eurjchem-624	184	37	to	to	ADP
eurjchem-624	184	38	adamantyl	adamantyl	VERB
eurjchem-624	184	39	derivatives	derivative	NOUN
eurjchem-624	184	40	.	.	PUNCT
eurjchem-624	185	1	these	these	PRON
eurjchem-624	185	2	are	be	AUX
eurjchem-624	185	3	used	use	VERB
eurjchem-624	185	4	as	as	ADP
eurjchem-624	185	5	either	either	DET
eurjchem-624	185	6	1‐adamantyl	1‐adamantyl	NUM
eurjchem-624	185	7	or	or	CCONJ
eurjchem-624	185	8	2‐adamantyl	2‐adamantyl	NUM
eurjchem-624	185	9	derivatives	derivative	NOUN
eurjchem-624	185	10	to	to	PART
eurjchem-624	185	11	set	set	VERB
eurjchem-624	185	12	up	up	ADP
eurjchem-624	185	13	scales	scale	NOUN
eurjchem-624	185	14	of	of	ADP
eurjchem-624	185	15	solvent	solvent	ADJ
eurjchem-624	185	16	ionizing	ionizing	NOUN
eurjchem-624	185	17	power	power	NOUN
eurjchem-624	185	18	and	and	CCONJ
eurjchem-624	185	19	,	,	PUNCT
eurjchem-624	185	20	hence	hence	ADV
eurjchem-624	185	21	,	,	PUNCT
eurjchem-624	185	22	when	when	SCONJ
eurjchem-624	185	23	yx	yx	NOUN
eurjchem-624	185	24	values	value	NOUN
eurjchem-624	185	25	are	be	AUX
eurjchem-624	185	26	used	use	VERB
eurjchem-624	185	27	,	,	PUNCT
eurjchem-624	185	28	by	by	ADP
eurjchem-624	185	29	definition	definition	NOUN
eurjchem-624	185	30	the	the	DET
eurjchem-624	185	31	l	l	NOUN
eurjchem-624	185	32	values	value	NOUN
eurjchem-624	185	33	for	for	ADP
eurjchem-624	185	34	solvolyses	solvolyse	NOUN
eurjchem-624	185	35	involving	involve	VERB
eurjchem-624	185	36	adamantyl	adamantyl	ADJ
eurjchem-624	185	37	cation	cation	NOUN
eurjchem-624	185	38	formation	formation	NOUN
eurjchem-624	185	39	will	will	AUX
eurjchem-624	185	40	be	be	AUX
eurjchem-624	185	41	zero	zero	NUM
eurjchem-624	185	42	.	.	PUNCT
eurjchem-624	186	1	it	it	PRON
eurjchem-624	186	2	can	can	AUX
eurjchem-624	186	3	be	be	AUX
eurjchem-624	186	4	seen	see	VERB
eurjchem-624	186	5	within	within	ADP
eurjchem-624	186	6	table	table	NOUN
eurjchem-624	186	7	3	3	NUM
eurjchem-624	186	8	that	that	PRON
eurjchem-624	186	9	the	the	DET
eurjchem-624	186	10	l	l	NOUN
eurjchem-624	186	11	values	value	NOUN
eurjchem-624	186	12	for	for	ADP
eurjchem-624	186	13	adamantyl	adamantyl	ADJ
eurjchem-624	186	14	chloroformate	chloroformate	NOUN
eurjchem-624	186	15	solvolysis	solvolysis	NOUN
eurjchem-624	186	16	are	be	AUX
eurjchem-624	186	17	negligible	negligible	ADJ
eurjchem-624	186	18	.	.	PUNCT
eurjchem-624	187	1	the	the	DET
eurjchem-624	187	2	low	low	ADJ
eurjchem-624	187	3	m	m	PROPN
eurjchem-624	187	4	values	value	NOUN
eurjchem-624	187	5	of	of	ADP
eurjchem-624	187	6	0.47	0.47	NUM
eurjchem-624	187	7	to	to	PART
eurjchem-624	187	8	0.59	0.59	NUM
eurjchem-624	187	9	observed	observe	VERB
eurjchem-624	187	10	for	for	ADP
eurjchem-624	187	11	the	the	DET
eurjchem-624	187	12	pathway	pathway	NOUN
eurjchem-624	187	13	involving	involve	VERB
eurjchem-624	187	14	ionization	ionization	NOUN
eurjchem-624	187	15	requires	require	VERB
eurjchem-624	187	16	that	that	SCONJ
eurjchem-624	187	17	the	the	DET
eurjchem-624	187	18	concurrent	concurrent	ADJ
eurjchem-624	187	19	decomposition	decomposition	NOUN
eurjchem-624	187	20	reduces	reduce	VERB
eurjchem-624	187	21	the	the	DET
eurjchem-624	187	22	need	need	NOUN
eurjchem-624	187	23	for	for	ADP
eurjchem-624	187	24	electrophilic	electrophilic	ADJ
eurjchem-624	187	25	assistance	assistance	NOUN
eurjchem-624	187	26	at	at	ADP
eurjchem-624	187	27	the	the	DET
eurjchem-624	187	28	chloride‐ion	chloride‐ion	NOUN
eurjchem-624	187	29	leaving	leave	VERB
eurjchem-624	187	30	group	group	NOUN
eurjchem-624	187	31	and	and	CCONJ
eurjchem-624	187	32	,	,	PUNCT
eurjchem-624	187	33	thinking	think	VERB
eurjchem-624	187	34	in	in	ADP
eurjchem-624	187	35	terms	term	NOUN
eurjchem-624	187	36	of	of	ADP
eurjchem-624	187	37	the	the	DET
eurjchem-624	187	38	influence	influence	NOUN
eurjchem-624	187	39	upon	upon	SCONJ
eurjchem-624	187	40	the	the	DET
eurjchem-624	187	41	reaction	reaction	NOUN
eurjchem-624	187	42	coordinate	coordinate	NOUN
eurjchem-624	187	43	,	,	PUNCT
eurjchem-624	187	44	an	an	DET
eurjchem-624	187	45	earlier	early	ADJ
eurjchem-624	187	46	transition	transition	NOUN
eurjchem-624	187	47	state	state	NOUN
eurjchem-624	187	48	is	be	AUX
eurjchem-624	187	49	involved	involve	VERB
eurjchem-624	187	50	.	.	PUNCT
eurjchem-624	188	1	a	a	DET
eurjchem-624	188	2	similar	similar	ADJ
eurjchem-624	188	3	process	process	NOUN
eurjchem-624	188	4	is	be	AUX
eurjchem-624	188	5	believed	believe	VERB
eurjchem-624	188	6	to	to	PART
eurjchem-624	188	7	operate	operate	VERB
eurjchem-624	188	8	for	for	ADP
eurjchem-624	188	9	1‐	1‐	NUM
eurjchem-624	188	10	adamantyl	adamantyl	ADJ
eurjchem-624	188	11	fluoroformate	fluoroformate	NOUN
eurjchem-624	188	12	(	(	PUNCT
eurjchem-624	188	13	table	table	NOUN
eurjchem-624	188	14	3	3	NUM
eurjchem-624	188	15	)	)	PUNCT
eurjchem-624	188	16	but	but	CCONJ
eurjchem-624	188	17	,	,	PUNCT
eurjchem-624	188	18	due	due	ADP
eurjchem-624	188	19	to	to	ADP
eurjchem-624	188	20	the	the	DET
eurjchem-624	188	21	stronger	strong	ADJ
eurjchem-624	188	22	c‐f	c‐f	NOUN
eurjchem-624	188	23	bond	bond	NOUN
eurjchem-624	188	24	being	be	AUX
eurjchem-624	188	25	heterolyzed	heterolyze	VERB
eurjchem-624	188	26	,	,	PUNCT
eurjchem-624	188	27	there	there	PRON
eurjchem-624	188	28	is	be	VERB
eurjchem-624	188	29	an	an	DET
eurjchem-624	188	30	increased	increase	VERB
eurjchem-624	188	31	need	need	NOUN
eurjchem-624	188	32	for	for	ADP
eurjchem-624	188	33	electrophilic	electrophilic	ADJ
eurjchem-624	188	34	assistance	assistance	NOUN
eurjchem-624	188	35	from	from	ADP
eurjchem-624	188	36	the	the	DET
eurjchem-624	188	37	solvent	solvent	NOUN
eurjchem-624	188	38	and	and	CCONJ
eurjchem-624	188	39	a	a	DET
eurjchem-624	188	40	larger	large	ADJ
eurjchem-624	188	41	m	m	NOUN
eurjchem-624	188	42	value	value	NOUN
eurjchem-624	188	43	of	of	ADP
eurjchem-624	188	44	0.70±0.01	0.70±0.01	NOUN
eurjchem-624	188	45	is	be	AUX
eurjchem-624	188	46	observed	observe	VERB
eurjchem-624	188	47	for	for	ADP
eurjchem-624	188	48	reactions	reaction	NOUN
eurjchem-624	188	49	in	in	ADP
eurjchem-624	188	50	fluoroalcohol	fluoroalcohol	NOUN
eurjchem-624	188	51	(	(	PUNCT
eurjchem-624	188	52	hfip	hfip	PROPN
eurjchem-624	188	53	,	,	PUNCT
eurjchem-624	188	54	tfe	tfe	NOUN
eurjchem-624	188	55	)	)	PUNCT
eurjchem-624	188	56	containing	contain	VERB
eurjchem-624	188	57	solvents	solvent	NOUN
eurjchem-624	188	58	.	.	PUNCT
eurjchem-624	189	1	the	the	DET
eurjchem-624	189	2	l	l	NOUN
eurjchem-624	189	3	and	and	CCONJ
eurjchem-624	189	4	m	m	PROPN
eurjchem-624	189	5	values	value	NOUN
eurjchem-624	189	6	associated	associate	VERB
eurjchem-624	189	7	with	with	ADP
eurjchem-624	189	8	tert‐butyl	tert‐butyl	PRON
eurjchem-624	189	9	fluoroformate	fluoroformate	PROPN
eurjchem-624	189	10	solvolyses	solvolyse	NOUN
eurjchem-624	189	11	in	in	ADP
eurjchem-624	189	12	17	17	NUM
eurjchem-624	189	13	solvents	solvent	NOUN
eurjchem-624	189	14	of	of	ADP
eurjchem-624	189	15	0.41	0.41	NUM
eurjchem-624	189	16	and	and	CCONJ
eurjchem-624	189	17	0.65	0.65	NUM
eurjchem-624	189	18	,	,	PUNCT
eurjchem-624	189	19	respectively	respectively	ADV
eurjchem-624	189	20	,	,	PUNCT
eurjchem-624	189	21	(	(	PUNCT
eurjchem-624	189	22	table	table	NOUN
eurjchem-624	189	23	3	3	NUM
eurjchem-624	189	24	)	)	PUNCT
eurjchem-624	189	25	are	be	AUX
eurjchem-624	189	26	similar	similar	ADJ
eurjchem-624	189	27	to	to	ADP
eurjchem-624	189	28	the	the	DET
eurjchem-624	189	29	values	value	NOUN
eurjchem-624	189	30	of	of	ADP
eurjchem-624	189	31	0.30	0.30	NUM
eurjchem-624	189	32	and	and	CCONJ
eurjchem-624	189	33	0.76	0.76	NUM
eurjchem-624	189	34	for	for	ADP
eurjchem-624	189	35	tert‐butyl	tert‐butyl	X
eurjchem-624	189	36	chloride	chloride	NOUN
eurjchem-624	189	37	solvolyses	solvolyse	NOUN
eurjchem-624	189	38	[	[	X
eurjchem-624	189	39	17,40	17,40	NUM
eurjchem-624	189	40	]	]	PUNCT
eurjchem-624	189	41	and	and	CCONJ
eurjchem-624	189	42	a	a	DET
eurjchem-624	189	43	pathway	pathway	NOUN
eurjchem-624	189	44	with	with	ADP
eurjchem-624	189	45	nucleophilic	nucleophilic	ADJ
eurjchem-624	189	46	solvation	solvation	NOUN
eurjchem-624	189	47	of	of	ADP
eurjchem-624	189	48	an	an	DET
eurjchem-624	189	49	incipient	incipient	NOUN
eurjchem-624	189	50	tert‐butyl	tert‐butyl	ADP
eurjchem-624	189	51	cation	cation	NOUN
eurjchem-624	189	52	could	could	AUX
eurjchem-624	189	53	be	be	AUX
eurjchem-624	189	54	quite	quite	ADV
eurjchem-624	189	55	similar	similar	ADJ
eurjchem-624	189	56	to	to	ADP
eurjchem-624	189	57	the	the	DET
eurjchem-624	189	58	ionization	ionization	NOUN
eurjchem-624	189	59	process	process	NOUN
eurjchem-624	189	60	involved	involve	VERB
eurjchem-624	189	61	in	in	ADP
eurjchem-624	189	62	the	the	DET
eurjchem-624	189	63	solvolyses	solvolyse	NOUN
eurjchem-624	189	64	of	of	ADP
eurjchem-624	189	65	the	the	DET
eurjchem-624	189	66	chloride	chloride	NOUN
eurjchem-624	189	67	but	but	CCONJ
eurjchem-624	189	68	with	with	ADP
eurjchem-624	189	69	a	a	DET
eurjchem-624	189	70	fluoroformate	fluoroformate	ADJ
eurjchem-624	189	71	anion	anion	NOUN
eurjchem-624	189	72	as	as	ADP
eurjchem-624	189	73	the	the	DET
eurjchem-624	189	74	leaving	leaving	NOUN
eurjchem-624	189	75	group	group	NOUN
eurjchem-624	189	76	.	.	PUNCT
eurjchem-624	190	1	however	however	ADV
eurjchem-624	190	2	,	,	PUNCT
eurjchem-624	190	3	the	the	DET
eurjchem-624	190	4	ionization	ionization	NOUN
eurjchem-624	190	5	process	process	NOUN
eurjchem-624	190	6	for	for	ADP
eurjchem-624	190	7	solvolyses	solvolyse	NOUN
eurjchem-624	190	8	of	of	ADP
eurjchem-624	190	9	1	1	NUM
eurjchem-624	190	10	is	be	AUX
eurjchem-624	190	11	unlikely	unlikely	ADJ
eurjchem-624	190	12	to	to	PART
eurjchem-624	190	13	involve	involve	VERB
eurjchem-624	190	14	a	a	DET
eurjchem-624	190	15	simple	simple	ADJ
eurjchem-624	190	16	ionization	ionization	NOUN
eurjchem-624	190	17	to	to	ADP
eurjchem-624	190	18	a	a	DET
eurjchem-624	190	19	carbocation	carbocation	NOUN
eurjchem-624	190	20	and	and	CCONJ
eurjchem-624	190	21	chloroformate	chloroformate	ADJ
eurjchem-624	190	22	anion	anion	NOUN
eurjchem-624	190	23	in	in	ADP
eurjchem-624	190	24	the	the	DET
eurjchem-624	190	25	rate	rate	NOUN
eurjchem-624	190	26	determining	determine	VERB
eurjchem-624	190	27	step	step	NOUN
eurjchem-624	190	28	(	(	PUNCT
eurjchem-624	190	29	rds	rds	NOUN
eurjchem-624	190	30	)	)	PUNCT
eurjchem-624	190	31	,	,	PUNCT
eurjchem-624	190	32	because	because	SCONJ
eurjchem-624	190	33	,	,	PUNCT
eurjchem-624	190	34	as	as	SCONJ
eurjchem-624	190	35	discussed	discuss	VERB
eurjchem-624	190	36	in	in	ADP
eurjchem-624	190	37	the	the	DET
eurjchem-624	190	38	introduction	introduction	NOUN
eurjchem-624	190	39	,	,	PUNCT
eurjchem-624	190	40	the	the	DET
eurjchem-624	190	41	considerably	considerably	ADV
eurjchem-624	190	42	slower	slow	ADJ
eurjchem-624	190	43	reaction	reaction	NOUN
eurjchem-624	190	44	of	of	ADP
eurjchem-624	190	45	a	a	DET
eurjchem-624	190	46	fluoroformate	fluoroformate	ADJ
eurjchem-624	190	47	relative	relative	ADJ
eurjchem-624	190	48	to	to	ADP
eurjchem-624	190	49	the	the	DET
eurjchem-624	190	50	corresponding	corresponding	ADJ
eurjchem-624	190	51	chloroformate	chloroformate	NOUN
eurjchem-624	190	52	argues	argue	VERB
eurjchem-624	190	53	in	in	ADP
eurjchem-624	190	54	favor	favor	NOUN
eurjchem-624	190	55	of	of	ADP
eurjchem-624	190	56	a	a	DET
eurjchem-624	190	57	mechanism	mechanism	NOUN
eurjchem-624	190	58	with	with	ADP
eurjchem-624	190	59	some	some	DET
eurjchem-624	190	60	degree	degree	NOUN
eurjchem-624	190	61	of	of	ADP
eurjchem-624	190	62	fission	fission	NOUN
eurjchem-624	190	63	of	of	ADP
eurjchem-624	190	64	the	the	DET
eurjchem-624	190	65	carbon‐chlorine	carbon‐chlorine	NOUN
eurjchem-624	190	66	bond	bond	NOUN
eurjchem-624	190	67	in	in	ADP
eurjchem-624	190	68	the	the	DET
eurjchem-624	190	69	rds	rd	NOUN
eurjchem-624	190	70	.	.	PUNCT
eurjchem-624	191	1	further	far	ADV
eurjchem-624	191	2	,	,	PUNCT
eurjchem-624	191	3	estimates	estimate	VERB
eurjchem-624	191	4	[	[	X
eurjchem-624	191	5	51	51	NUM
eurjchem-624	191	6	]	]	PUNCT
eurjchem-624	191	7	have	have	AUX
eurjchem-624	191	8	indicated	indicate	VERB
eurjchem-624	191	9	very	very	ADV
eurjchem-624	191	10	large	large	ADJ
eurjchem-624	191	11	rate	rate	NOUN
eurjchem-624	191	12	ratios	ratio	NOUN
eurjchem-624	191	13	for	for	ADP
eurjchem-624	191	14	solvolyses	solvolyse	NOUN
eurjchem-624	191	15	of	of	ADP
eurjchem-624	191	16	tert‐butyl	tert‐butyl	NUM
eurjchem-624	191	17	and	and	CCONJ
eurjchem-624	191	18	isopropyl	isopropyl	NOUN
eurjchem-624	191	19	chlorides	chloride	NOUN
eurjchem-624	191	20	(	(	PUNCT
eurjchem-624	191	21	or	or	CCONJ
eurjchem-624	191	22	bromides	bromide	NOUN
eurjchem-624	191	23	)	)	PUNCT
eurjchem-624	191	24	with	with	ADP
eurjchem-624	191	25	values	value	NOUN
eurjchem-624	191	26	of	of	ADP
eurjchem-624	191	27	about	about	ADV
eurjchem-624	191	28	106	106	NUM
eurjchem-624	191	29	in	in	ADP
eurjchem-624	191	30	97	97	NUM
eurjchem-624	191	31	%	%	NOUN
eurjchem-624	191	32	hfip	hfip	NOUN
eurjchem-624	191	33	and	and	CCONJ
eurjchem-624	191	34	104	104	NUM
eurjchem-624	191	35	in	in	ADP
eurjchem-624	191	36	80	80	NUM
eurjchem-624	191	37	%	%	NOUN
eurjchem-624	191	38	ethanol	ethanol	NOUN
eurjchem-624	191	39	.	.	PUNCT
eurjchem-624	192	1	the	the	DET
eurjchem-624	192	2	present	present	ADJ
eurjchem-624	192	3	ratio	ratio	NOUN
eurjchem-624	192	4	for	for	ADP
eurjchem-624	192	5	solvolyses	solvolyse	NOUN
eurjchem-624	192	6	of	of	ADP
eurjchem-624	192	7	1	1	NUM
eurjchem-624	192	8	and	and	CCONJ
eurjchem-624	192	9	the	the	DET
eurjchem-624	192	10	isopropyl	isopropyl	NOUN
eurjchem-624	192	11	equivalent	equivalent	NOUN
eurjchem-624	192	12	of	of	ADP
eurjchem-624	192	13	67	67	NUM
eurjchem-624	192	14	in	in	ADP
eurjchem-624	192	15	70	70	NUM
eurjchem-624	192	16	%	%	NOUN
eurjchem-624	192	17	hfip	hfip	NOUN
eurjchem-624	192	18	(	(	PUNCT
eurjchem-624	192	19	table	table	NOUN
eurjchem-624	192	20	4	4	NUM
eurjchem-624	192	21	)	)	PUNCT
eurjchem-624	192	22	is	be	AUX
eurjchem-624	192	23	much	much	ADV
eurjchem-624	192	24	lower	low	ADJ
eurjchem-624	192	25	and	and	CCONJ
eurjchem-624	192	26	suggest	suggest	VERB
eurjchem-624	192	27	a	a	DET
eurjchem-624	192	28	reduced	reduce	VERB
eurjchem-624	192	29	alkyl	alkyl	NOUN
eurjchem-624	192	30	group‐sulfur	group‐sulfur	NOUN
eurjchem-624	192	31	bond	bond	NOUN
eurjchem-624	192	32	fission	fission	NOUN
eurjchem-624	192	33	at	at	ADP
eurjchem-624	192	34	the	the	DET
eurjchem-624	192	35	transition	transition	NOUN
eurjchem-624	192	36	state	state	NOUN
eurjchem-624	192	37	of	of	ADP
eurjchem-624	192	38	the	the	DET
eurjchem-624	192	39	rds	rd	NOUN
eurjchem-624	192	40	.	.	PUNCT
eurjchem-624	193	1	unfortunately	unfortunately	ADV
eurjchem-624	193	2	,	,	PUNCT
eurjchem-624	193	3	there	there	PRON
eurjchem-624	193	4	does	do	AUX
eurjchem-624	193	5	not	not	PART
eurjchem-624	193	6	appear	appear	VERB
eurjchem-624	193	7	to	to	PART
eurjchem-624	193	8	be	be	AUX
eurjchem-624	193	9	any	any	DET
eurjchem-624	193	10	estimates	estimate	NOUN
eurjchem-624	193	11	available	available	ADJ
eurjchem-624	193	12	for	for	SCONJ
eurjchem-624	193	13	tert‐butyl	tert‐butyl	NOUN
eurjchem-624	193	14	to	to	PART
eurjchem-624	193	15	isopropyl	isopropyl	VERB
eurjchem-624	193	16	solvolytic	solvolytic	ADJ
eurjchem-624	193	17	rate	rate	NOUN
eurjchem-624	193	18	ratios	ratio	NOUN
eurjchem-624	193	19	involved	involve	VERB
eurjchem-624	193	20	in	in	ADP
eurjchem-624	193	21	the	the	DET
eurjchem-624	193	22	rds	rds	NOUN
eurjchem-624	193	23	ionization	ionization	NOUN
eurjchem-624	193	24	to	to	ADP
eurjchem-624	193	25	a	a	DET
eurjchem-624	193	26	carboxylium	carboxylium	NOUN
eurjchem-624	193	27	ion	ion	NOUN
eurjchem-624	193	28	and	and	CCONJ
eurjchem-624	193	29	a	a	DET
eurjchem-624	193	30	chloride	chloride	NOUN
eurjchem-624	193	31	ion	ion	NOUN
eurjchem-624	193	32	.	.	PUNCT
eurjchem-624	194	1	a	a	DET
eurjchem-624	194	2	likely	likely	ADV
eurjchem-624	194	3	mechanistic	mechanistic	ADJ
eurjchem-624	194	4	candidate	candidate	NOUN
eurjchem-624	194	5	leading	lead	VERB
eurjchem-624	194	6	to	to	ADP
eurjchem-624	194	7	the	the	DET
eurjchem-624	194	8	modest	modest	ADJ
eurjchem-624	194	9	value	value	NOUN
eurjchem-624	194	10	for	for	ADP
eurjchem-624	194	11	the	the	DET
eurjchem-624	194	12	ratio	ratio	NOUN
eurjchem-624	194	13	obtained	obtain	VERB
eurjchem-624	194	14	in	in	ADP
eurjchem-624	194	15	70	70	NUM
eurjchem-624	194	16	%	%	NOUN
eurjchem-624	194	17	hfip	hfip	NOUN
eurjchem-624	194	18	involves	involve	VERB
eurjchem-624	194	19	a	a	DET
eurjchem-624	194	20	rate‐determining	rate‐determining	NOUN
eurjchem-624	194	21	solvolysis‐decomposition	solvolysis‐decomposition	NOUN
eurjchem-624	194	22	involving	involve	VERB
eurjchem-624	194	23	expulsion	expulsion	NOUN
eurjchem-624	194	24	of	of	ADP
eurjchem-624	194	25	cos	cos	PROPN
eurjchem-624	194	26	and	and	CCONJ
eurjchem-624	194	27	formation	formation	NOUN
eurjchem-624	194	28	of	of	ADP
eurjchem-624	194	29	r+	r+	NOUN
eurjchem-624	194	30	and	and	CCONJ
eurjchem-624	194	31	cl‐	cl‐	VERB
eurjchem-624	194	32	counterions	counterion	NOUN
eurjchem-624	194	33	(	(	PUNCT
eurjchem-624	194	34	scheme	scheme	NOUN
eurjchem-624	194	35	2b	2b	NOUN
eurjchem-624	194	36	)	)	PUNCT
eurjchem-624	194	37	.	.	PUNCT
eurjchem-624	195	1	such	such	DET
eurjchem-624	195	2	a	a	DET
eurjchem-624	195	3	mechanism	mechanism	NOUN
eurjchem-624	195	4	can	can	AUX
eurjchem-624	195	5	be	be	AUX
eurjchem-624	195	6	considered	consider	VERB
eurjchem-624	195	7	as	as	ADP
eurjchem-624	195	8	a	a	DET
eurjchem-624	195	9	hybrid	hybrid	NOUN
eurjchem-624	195	10	of	of	ADP
eurjchem-624	195	11	the	the	DET
eurjchem-624	195	12	two	two	NUM
eurjchem-624	195	13	schemes	scheme	NOUN
eurjchem-624	195	14	considered	consider	VERB
eurjchem-624	195	15	immediately	immediately	ADV
eurjchem-624	195	16	above	above	ADP
eurjchem-624	195	17	with	with	ADP
eurjchem-624	195	18	a	a	DET
eurjchem-624	195	19	relatively	relatively	ADV
eurjchem-624	195	20	large	large	ADJ
eurjchem-624	195	21	contribution	contribution	NOUN
eurjchem-624	195	22	from	from	ADP
eurjchem-624	195	23	the	the	DET
eurjchem-624	195	24	ionization	ionization	NOUN
eurjchem-624	195	25	to	to	AUX
eurjchem-624	195	26	r+	r+	NOUN
eurjchem-624	195	27	component	component	NOUN
eurjchem-624	195	28	for	for	ADP
eurjchem-624	195	29	tert‐butyl	tert‐butyl	ADP
eurjchem-624	195	30	fluoroformate	fluoroformate	ADJ
eurjchem-624	195	31	and	and	CCONJ
eurjchem-624	195	32	appreciable	appreciable	ADJ
eurjchem-624	195	33	contributions	contribution	NOUN
eurjchem-624	195	34	from	from	ADP
eurjchem-624	195	35	both	both	DET
eurjchem-624	195	36	this	this	DET
eurjchem-624	195	37	component	component	NOUN
eurjchem-624	195	38	and	and	CCONJ
eurjchem-624	195	39	the	the	DET
eurjchem-624	195	40	component	component	NOUN
eurjchem-624	195	41	involving	involve	VERB
eurjchem-624	195	42	ionization	ionization	NOUN
eurjchem-624	195	43	to	to	ADP
eurjchem-624	195	44	rsco+	rsco+	PROPN
eurjchem-624	195	45	for	for	ADP
eurjchem-624	195	46	tert‐butyl	tert‐butyl	X
eurjchem-624	195	47	chlorothioformate	chlorothioformate	NOUN
eurjchem-624	195	48	solvolyses	solvolyse	NOUN
eurjchem-624	195	49	.	.	PUNCT
eurjchem-624	196	1	it	it	PRON
eurjchem-624	196	2	was	be	AUX
eurjchem-624	196	3	mentioned	mention	VERB
eurjchem-624	196	4	earlier	early	ADV
eurjchem-624	196	5	that	that	SCONJ
eurjchem-624	196	6	the	the	DET
eurjchem-624	196	7	magnitude	magnitude	NOUN
eurjchem-624	196	8	of	of	ADP
eurjchem-624	196	9	the	the	DET
eurjchem-624	196	10	deuterium	deuterium	NOUN
eurjchem-624	196	11	isotope	isotope	NOUN
eurjchem-624	196	12	effect	effect	NOUN
eurjchem-624	196	13	for	for	ADP
eurjchem-624	196	14	2,2,2‐trichloro‐1,1‐dimethylethyl	2,2,2‐trichloro‐1,1‐dimethylethyl	NUM
eurjchem-624	196	15	chloroformate	chloroformate	NOUN
eurjchem-624	196	16	(	(	PUNCT
eurjchem-624	196	17	β	β	X
eurjchem-624	196	18	,	,	PUNCT
eurjchem-624	196	19	β	β	X
eurjchem-624	196	20	,	,	PUNCT
eurjchem-624	196	21	β‐trichloro‐tert‐butyl	β‐trichloro‐tert‐butyl	PROPN
eurjchem-624	196	22	chloroformate	chloroformate	NOUN
eurjchem-624	196	23	)	)	PUNCT
eurjchem-624	196	24	suggested	suggest	VERB
eurjchem-624	196	25	a	a	DET
eurjchem-624	196	26	changeover	changeover	NOUN
eurjchem-624	196	27	from	from	ADP
eurjchem-624	196	28	ionization	ionization	NOUN
eurjchem-624	196	29	to	to	ADP
eurjchem-624	196	30	addition‐elimination	addition‐elimination	NOUN
eurjchem-624	196	31	on	on	ADP
eurjchem-624	196	32	introduction	introduction	NOUN
eurjchem-624	196	33	of	of	ADP
eurjchem-624	196	34	the	the	DET
eurjchem-624	196	35	three	three	NUM
eurjchem-624	196	36	electron‐withdrawing	electron‐withdrawe	VERB
eurjchem-624	196	37	chlorine	chlorine	NOUN
eurjchem-624	196	38	atoms	atom	NOUN
eurjchem-624	196	39	.	.	PUNCT
eurjchem-624	197	1	this	this	PRON
eurjchem-624	197	2	was	be	AUX
eurjchem-624	197	3	given	give	VERB
eurjchem-624	197	4	strong	strong	ADJ
eurjchem-624	197	5	support	support	NOUN
eurjchem-624	197	6	by	by	ADP
eurjchem-624	197	7	a	a	DET
eurjchem-624	197	8	g‐w	g‐w	PROPN
eurjchem-624	197	9	equation	equation	NOUN
eurjchem-624	197	10	treatment	treatment	NOUN
eurjchem-624	197	11	[	[	X
eurjchem-624	197	12	44	44	NUM
eurjchem-624	197	13	]	]	PUNCT
eurjchem-624	197	14	leading	lead	VERB
eurjchem-624	197	15	(	(	PUNCT
eurjchem-624	197	16	table	table	NOUN
eurjchem-624	197	17	3	3	NUM
eurjchem-624	197	18	)	)	PUNCT
eurjchem-624	197	19	to	to	ADP
eurjchem-624	197	20	an	an	DET
eurjchem-624	197	21	l	l	NOUN
eurjchem-624	197	22	value	value	NOUN
eurjchem-624	197	23	of	of	ADP
eurjchem-624	197	24	1.42±0.09	1.42±0.09	NUM
eurjchem-624	197	25	and	and	CCONJ
eurjchem-624	197	26	an	an	DET
eurjchem-624	197	27	m	m	NOUN
eurjchem-624	197	28	value	value	NOUN
eurjchem-624	197	29	of	of	ADP
eurjchem-624	197	30	0.39±0.05	0.39±0.05	NOUN
eurjchem-624	197	31	.	.	PUNCT
eurjchem-624	198	1	4	4	X
eurjchem-624	198	2	.	.	X
eurjchem-624	198	3	conclusions	conclusion	NOUN
eurjchem-624	198	4	the	the	DET
eurjchem-624	198	5	increased	increase	VERB
eurjchem-624	198	6	stability	stability	NOUN
eurjchem-624	198	7	of	of	ADP
eurjchem-624	198	8	tert‐butyl	tert‐butyl	PRON
eurjchem-624	198	9	chlorothioformate	chlorothioformate	NOUN
eurjchem-624	198	10	(	(	PUNCT
eurjchem-624	198	11	1	1	NUM
eurjchem-624	198	12	)	)	PUNCT
eurjchem-624	198	13	relative	relative	ADJ
eurjchem-624	198	14	to	to	ADP
eurjchem-624	198	15	the	the	DET
eurjchem-624	198	16	corresponding	corresponding	ADJ
eurjchem-624	198	17	chloroformate	chloroformate	NOUN
eurjchem-624	198	18	may	may	AUX
eurjchem-624	198	19	well	well	ADV
eurjchem-624	198	20	be	be	AUX
eurjchem-624	198	21	related	relate	VERB
eurjchem-624	198	22	to	to	ADP
eurjchem-624	198	23	the	the	DET
eurjchem-624	198	24	observation	observation	NOUN
eurjchem-624	198	25	[	[	X
eurjchem-624	198	26	47	47	NUM
eurjchem-624	198	27	]	]	PUNCT
eurjchem-624	198	28	for	for	ADP
eurjchem-624	198	29	alkyl	alkyl	ADJ
eurjchem-624	198	30	thioesters	thioester	NOUN
eurjchem-624	198	31	and	and	CCONJ
eurjchem-624	198	32	esters	ester	NOUN
eurjchem-624	198	33	that	that	PRON
eurjchem-624	198	34	treatment	treatment	NOUN
eurjchem-624	198	35	with	with	ADP
eurjchem-624	198	36	antimony	antimony	NOUN
eurjchem-624	198	37	pentafluoride	pentafluoride	NOUN
eurjchem-624	198	38	in	in	ADP
eurjchem-624	198	39	so2	so2	PROPN
eurjchem-624	198	40	or	or	CCONJ
eurjchem-624	198	41	so2clf	so2clf	PROPN
eurjchem-624	198	42	result	result	NOUN
eurjchem-624	198	43	in	in	ADP
eurjchem-624	198	44	the	the	DET
eurjchem-624	198	45	formation	formation	NOUN
eurjchem-624	198	46	of	of	ADP
eurjchem-624	198	47	carboxylium	carboxylium	NOUN
eurjchem-624	198	48	ions	ion	NOUN
eurjchem-624	198	49	for	for	ADP
eurjchem-624	198	50	methyl	methyl	NOUN
eurjchem-624	198	51	or	or	CCONJ
eurjchem-624	198	52	ethyl	ethyl	PROPN
eurjchem-624	198	53	chlorothioformate	chlorothioformate	NOUN
eurjchem-624	198	54	but	but	CCONJ
eurjchem-624	198	55	a	a	DET
eurjchem-624	198	56	loss	loss	NOUN
eurjchem-624	198	57	of	of	ADP
eurjchem-624	198	58	carbon	carbon	NOUN
eurjchem-624	198	59	dioxide	dioxide	NOUN
eurjchem-624	198	60	(	(	PUNCT
eurjchem-624	198	61	and	and	CCONJ
eurjchem-624	198	62	chloride	chloride	NOUN
eurjchem-624	198	63	/	/	SYM
eurjchem-624	198	64	fluoride	fluoride	NOUN
eurjchem-624	198	65	exchange	exchange	NOUN
eurjchem-624	198	66	)	)	PUNCT
eurjchem-624	198	67	leads	lead	VERB
eurjchem-624	198	68	to	to	ADP
eurjchem-624	198	69	methyl	methyl	NOUN
eurjchem-624	198	70	or	or	CCONJ
eurjchem-624	198	71	ethyl	ethyl	PROPN
eurjchem-624	198	72	hexafluoroantimonate	hexafluoroantimonate	PROPN
eurjchem-624	198	73	for	for	ADP
eurjchem-624	198	74	the	the	DET
eurjchem-624	198	75	chloroformate	chloroformate	NOUN
eurjchem-624	198	76	.	.	PUNCT
eurjchem-624	199	1	for	for	ADP
eurjchem-624	199	2	the	the	DET
eurjchem-624	199	3	solvolyses	solvolyse	NOUN
eurjchem-624	199	4	of	of	ADP
eurjchem-624	199	5	the	the	DET
eurjchem-624	199	6	19	19	NUM
eurjchem-624	199	7	solvents	solvent	NOUN
eurjchem-624	199	8	of	of	ADP
eurjchem-624	199	9	this	this	DET
eurjchem-624	199	10	study	study	NOUN
eurjchem-624	199	11	,	,	PUNCT
eurjchem-624	199	12	including	include	VERB
eurjchem-624	199	13	eight	eight	NUM
eurjchem-624	199	14	with	with	ADP
eurjchem-624	199	15	fluoroalcohol	fluoroalcohol	NOUN
eurjchem-624	199	16	content	content	NOUN
eurjchem-624	199	17	,	,	PUNCT
eurjchem-624	199	18	a	a	DET
eurjchem-624	199	19	treatment	treatment	NOUN
eurjchem-624	199	20	in	in	ADP
eurjchem-624	199	21	terms	term	NOUN
eurjchem-624	199	22	of	of	ADP
eurjchem-624	199	23	the	the	DET
eurjchem-624	199	24	one‐term	one‐term	NOUN
eurjchem-624	199	25	grunwald‐winstein	grunwald‐winstein	ADJ
eurjchem-624	199	26	equation	equation	NOUN
eurjchem-624	199	27	using	use	VERB
eurjchem-624	199	28	ycl	ycl	PROPN
eurjchem-624	199	29	values	value	NOUN
eurjchem-624	199	30	leads	lead	VERB
eurjchem-624	199	31	to	to	ADP
eurjchem-624	199	32	a	a	DET
eurjchem-624	199	33	good	good	ADJ
eurjchem-624	199	34	correlation	correlation	NOUN
eurjchem-624	199	35	(	(	PUNCT
eurjchem-624	199	36	r	r	NOUN
eurjchem-624	199	37	=	=	NOUN
eurjchem-624	199	38	0.988	0.988	NUM
eurjchem-624	199	39	)	)	PUNCT
eurjchem-624	199	40	with	with	ADP
eurjchem-624	199	41	an	an	DET
eurjchem-624	199	42	m	m	NOUN
eurjchem-624	199	43	value	value	NOUN
eurjchem-624	199	44	(	(	PUNCT
eurjchem-624	199	45	sensitivity	sensitivity	NOUN
eurjchem-624	199	46	towards	towards	ADP
eurjchem-624	199	47	changes	change	NOUN
eurjchem-624	199	48	in	in	ADP
eurjchem-624	199	49	solvent	solvent	ADJ
eurjchem-624	199	50	ionizing	ionizing	NOUN
eurjchem-624	199	51	power	power	NOUN
eurjchem-624	199	52	)	)	PUNCT
eurjchem-624	199	53	of	of	ADP
eurjchem-624	199	54	0.73±0.03	0.73±0.03	NUM
eurjchem-624	199	55	.	.	PUNCT
eurjchem-624	200	1	there	there	PRON
eurjchem-624	200	2	is	be	VERB
eurjchem-624	200	3	only	only	ADV
eurjchem-624	200	4	negligible	negligible	ADJ
eurjchem-624	200	5	improvement	improvement	NOUN
eurjchem-624	200	6	when	when	SCONJ
eurjchem-624	200	7	the	the	DET
eurjchem-624	200	8	two‐term	two‐term	NOUN
eurjchem-624	200	9	[	[	X
eurjchem-624	200	10	equation	equation	NOUN
eurjchem-624	200	11	2	2	NUM
eurjchem-624	200	12	]	]	PUNCT
eurjchem-624	200	13	g‐w	g‐w	NOUN
eurjchem-624	200	14	equation	equation	NOUN
eurjchem-624	200	15	is	be	AUX
eurjchem-624	200	16	applied	apply	VERB
eurjchem-624	200	17	(	(	PUNCT
eurjchem-624	200	18	r	r	NOUN
eurjchem-624	200	19	=	=	SYM
eurjchem-624	200	20	0.989	0.989	NUM
eurjchem-624	200	21	)	)	PUNCT
eurjchem-624	200	22	and	and	CCONJ
eurjchem-624	200	23	the	the	DET
eurjchem-624	200	24	l	l	NOUN
eurjchem-624	200	25	value	value	NOUN
eurjchem-624	200	26	(	(	PUNCT
eurjchem-624	200	27	sensitivity	sensitivity	NOUN
eurjchem-624	200	28	to	to	PART
eurjchem-624	200	29	changes	change	NOUN
eurjchem-624	200	30	in	in	ADP
eurjchem-624	200	31	solvent	solvent	ADJ
eurjchem-624	200	32	nucleophilicity	nucleophilicity	NOUN
eurjchem-624	200	33	)	)	PUNCT
eurjchem-624	200	34	is	be	AUX
eurjchem-624	200	35	0.13±0.09	0.13±0.09	VERB
eurjchem-624	200	36	,	,	PUNCT
eurjchem-624	200	37	associated	associate	VERB
eurjchem-624	200	38	with	with	ADP
eurjchem-624	200	39	a	a	DET
eurjchem-624	200	40	high	high	ADJ
eurjchem-624	200	41	(	(	PUNCT
eurjchem-624	200	42	0.17	0.17	NUM
eurjchem-624	200	43	)	)	PUNCT
eurjchem-624	200	44	probability	probability	NOUN
eurjchem-624	200	45	that	that	SCONJ
eurjchem-624	200	46	the	the	DET
eurjchem-624	200	47	lnt	lnt	NOUN
eurjchem-624	200	48	term	term	NOUN
eurjchem-624	200	49	is	be	AUX
eurjchem-624	200	50	not	not	PART
eurjchem-624	200	51	statistically	statistically	ADV
eurjchem-624	200	52	significant	significant	ADJ
eurjchem-624	200	53	.	.	PUNCT
eurjchem-624	201	1	there	there	PRON
eurjchem-624	201	2	is	be	VERB
eurjchem-624	201	3	no	no	DET
eurjchem-624	201	4	evidence	evidence	NOUN
eurjchem-624	201	5	,	,	PUNCT
eurjchem-624	201	6	even	even	ADV
eurjchem-624	201	7	in	in	ADP
eurjchem-624	201	8	pure	pure	ADJ
eurjchem-624	201	9	ethanol	ethanol	NOUN
eurjchem-624	201	10	and	and	CCONJ
eurjchem-624	201	11	methanol	methanol	NOUN
eurjchem-624	201	12	,	,	PUNCT
eurjchem-624	201	13	for	for	ADP
eurjchem-624	201	14	the	the	DET
eurjchem-624	201	15	incursion	incursion	NOUN
eurjchem-624	201	16	of	of	ADP
eurjchem-624	201	17	the	the	DET
eurjchem-624	201	18	addition‐	addition‐	ADJ
eurjchem-624	201	19	elimination	elimination	NOUN
eurjchem-624	201	20	pathway	pathway	NOUN
eurjchem-624	201	21	.	.	PUNCT
eurjchem-624	202	1	for	for	ADP
eurjchem-624	202	2	such	such	DET
eurjchem-624	202	3	a	a	DET
eurjchem-624	202	4	pathway	pathway	NOUN
eurjchem-624	202	5	(	(	PUNCT
eurjchem-624	202	6	scheme	scheme	NOUN
eurjchem-624	202	7	1	1	NUM
eurjchem-624	202	8	)	)	PUNCT
eurjchem-624	202	9	,	,	PUNCT
eurjchem-624	202	10	the	the	DET
eurjchem-624	202	11	l	l	NOUN
eurjchem-624	202	12	value	value	NOUN
eurjchem-624	202	13	is	be	AUX
eurjchem-624	202	14	considerably	considerably	ADV
eurjchem-624	202	15	larger	large	ADJ
eurjchem-624	202	16	and	and	CCONJ
eurjchem-624	202	17	it	it	PRON
eurjchem-624	202	18	is	be	AUX
eurjchem-624	202	19	at	at	ADP
eurjchem-624	202	20	a	a	DET
eurjchem-624	202	21	magnitude	magnitude	NOUN
eurjchem-624	202	22	of	of	ADP
eurjchem-624	202	23	1.66	1.66	NUM
eurjchem-624	202	24	(	(	PUNCT
eurjchem-624	202	25	±0.05	±0.05	NOUN
eurjchem-624	202	26	)	)	PUNCT
eurjchem-624	202	27	for	for	ADP
eurjchem-624	202	28	phenyl	phenyl	NOUN
eurjchem-624	202	29	chloroformate	chloroformate	NOUN
eurjchem-624	202	30	solvolysis	solvolysis	NOUN
eurjchem-624	202	31	:	:	PUNCT
eurjchem-624	202	32	a	a	DET
eurjchem-624	202	33	value	value	NOUN
eurjchem-624	202	34	generally	generally	ADV
eurjchem-624	202	35	taken	take	VERB
eurjchem-624	202	36	as	as	ADP
eurjchem-624	202	37	typical	typical	ADJ
eurjchem-624	202	38	for	for	ADP
eurjchem-624	202	39	an	an	DET
eurjchem-624	202	40	addition‐elimination	addition‐elimination	NOUN
eurjchem-624	202	41	pathway	pathway	NOUN
eurjchem-624	202	42	.	.	PUNCT
eurjchem-624	203	1	typical	typical	ADJ
eurjchem-624	203	2	values	value	NOUN
eurjchem-624	203	3	for	for	ADP
eurjchem-624	203	4	the	the	DET
eurjchem-624	203	5	pathway	pathway	NOUN
eurjchem-624	203	6	shown	show	VERB
eurjchem-624	203	7	in	in	ADP
eurjchem-624	203	8	scheme	scheme	NOUN
eurjchem-624	203	9	2b	2b	NUM
eurjchem-624	203	10	are	be	AUX
eurjchem-624	203	11	the	the	DET
eurjchem-624	203	12	essentially	essentially	ADV
eurjchem-624	203	13	zero	zero	NUM
eurjchem-624	203	14	l	l	NOUN
eurjchem-624	203	15	values	value	NOUN
eurjchem-624	203	16	observed	observe	VERB
eurjchem-624	203	17	for	for	ADP
eurjchem-624	203	18	1‐adamantyl	1‐adamantyl	NUM
eurjchem-624	203	19	and	and	CCONJ
eurjchem-624	203	20	2‐	2‐	NUM
eurjchem-624	203	21	adamantyl	adamantyl	PROPN
eurjchem-624	203	22	chloroformate	chloroformate	NOUN
eurjchem-624	203	23	solvolyses	solvolyse	NOUN
eurjchem-624	203	24	.	.	PUNCT
eurjchem-624	204	1	the	the	DET
eurjchem-624	204	2	ionization	ionization	NOUN
eurjchem-624	204	3	solvolyses	solvolyse	NOUN
eurjchem-624	204	4	of	of	ADP
eurjchem-624	204	5	mescocl	mescocl	NOUN
eurjchem-624	204	6	,	,	PUNCT
eurjchem-624	204	7	etscocl	etscocl	NOUN
eurjchem-624	204	8	,	,	PUNCT
eurjchem-624	204	9	i‐buscocl	i‐buscocl	ADP
eurjchem-624	204	10	,	,	PUNCT
eurjchem-624	204	11	and	and	CCONJ
eurjchem-624	204	12	i‐prscocl	i‐prscocl	X
eurjchem-624	204	13	involve	involve	VERB
eurjchem-624	204	14	an	an	DET
eurjchem-624	204	15	l	l	NOUN
eurjchem-624	204	16	/	/	SYM
eurjchem-624	204	17	m	m	NOUN
eurjchem-624	204	18	range	range	NOUN
eurjchem-624	204	19	of	of	ADP
eurjchem-624	204	20	0.53‐0.92	0.53‐0.92	NUM
eurjchem-624	204	21	.	.	PUNCT
eurjchem-624	205	1	it	it	PRON
eurjchem-624	205	2	is	be	AUX
eurjchem-624	205	3	believed	believe	VERB
eurjchem-624	205	4	that	that	SCONJ
eurjchem-624	205	5	this	this	DET
eurjchem-624	205	6	magnitude	magnitude	NOUN
eurjchem-624	205	7	of	of	ADP
eurjchem-624	205	8	l	l	PROPN
eurjchem-624	205	9	/	/	SYM
eurjchem-624	205	10	m	m	PROPN
eurjchem-624	205	11	ratios	ratio	NOUN
eurjchem-624	205	12	reflects	reflect	VERB
eurjchem-624	205	13	a	a	DET
eurjchem-624	205	14	pathway	pathway	NOUN
eurjchem-624	205	15	of	of	ADP
eurjchem-624	205	16	the	the	DET
eurjchem-624	205	17	scheme	scheme	NOUN
eurjchem-624	205	18	2a	2a	NUM
eurjchem-624	205	19	type	type	NOUN
eurjchem-624	205	20	,	,	PUNCT
eurjchem-624	205	21	with	with	ADP
eurjchem-624	205	22	the	the	DET
eurjchem-624	205	23	formation	formation	NOUN
eurjchem-624	205	24	of	of	ADP
eurjchem-624	205	25	the	the	DET
eurjchem-624	205	26	carboxylium	carboxylium	NOUN
eurjchem-624	205	27	ion	ion	NOUN
eurjchem-624	205	28	assisted	assist	VERB
eurjchem-624	205	29	by	by	ADP
eurjchem-624	205	30	an	an	DET
eurjchem-624	205	31	appreciable	appreciable	ADJ
eurjchem-624	205	32	nucleophilic	nucleophilic	ADJ
eurjchem-624	205	33	solvation	solvation	NOUN
eurjchem-624	205	34	.	.	PUNCT
eurjchem-624	206	1	in	in	ADP
eurjchem-624	206	2	contrast	contrast	NOUN
eurjchem-624	206	3	,	,	PUNCT
eurjchem-624	206	4	the	the	DET
eurjchem-624	206	5	corresponding	corresponding	NOUN
eurjchem-624	206	6	tert‐butyl	tert‐butyl	ADP
eurjchem-624	206	7	ester	ester	NOUN
eurjchem-624	206	8	(	(	PUNCT
eurjchem-624	206	9	1	1	X
eurjchem-624	206	10	)	)	PUNCT
eurjchem-624	206	11	follows	follow	VERB
eurjchem-624	206	12	the	the	DET
eurjchem-624	206	13	scheme	scheme	NOUN
eurjchem-624	206	14	2b	2b	NOUN
eurjchem-624	206	15	variant	variant	NOUN
eurjchem-624	206	16	of	of	ADP
eurjchem-624	206	17	the	the	DET
eurjchem-624	206	18	ionization	ionization	NOUN
eurjchem-624	206	19	process	process	NOUN
eurjchem-624	206	20	.	.	PUNCT
eurjchem-624	207	1	the	the	DET
eurjchem-624	207	2	vanishingly	vanishingly	ADV
eurjchem-624	207	3	low	low	ADJ
eurjchem-624	207	4	l	l	NOUN
eurjchem-624	207	5	value	value	NOUN
eurjchem-624	207	6	is	be	AUX
eurjchem-624	207	7	probably	probably	ADV
eurjchem-624	207	8	a	a	DET
eurjchem-624	207	9	consequence	consequence	NOUN
eurjchem-624	207	10	of	of	ADP
eurjchem-624	207	11	a	a	DET
eurjchem-624	207	12	concerted	concerted	ADJ
eurjchem-624	207	13	ionization‐fragmentation	ionization‐fragmentation	NOUN
eurjchem-624	207	14	having	have	VERB
eurjchem-624	207	15	an	an	DET
eurjchem-624	207	16	appreciable	appreciable	ADJ
eurjchem-624	207	17	internal	internal	ADJ
eurjchem-624	207	18	driving	driving	NOUN
eurjchem-624	207	19	force	force	NOUN
eurjchem-624	207	20	and	and	CCONJ
eurjchem-624	207	21	a	a	DET
eurjchem-624	207	22	lower	low	ADJ
eurjchem-624	207	23	demand	demand	NOUN
eurjchem-624	207	24	for	for	ADP
eurjchem-624	207	25	assistance	assistance	NOUN
eurjchem-624	207	26	from	from	ADP
eurjchem-624	207	27	nucleophilic	nucleophilic	ADJ
eurjchem-624	207	28	solvation	solvation	NOUN
eurjchem-624	207	29	.	.	PUNCT
eurjchem-624	208	1	acknowledgements	acknowledgement	VERB
eurjchem-624	208	2	the	the	DET
eurjchem-624	208	3	research	research	NOUN
eurjchem-624	208	4	in	in	ADP
eurjchem-624	208	5	the	the	DET
eurjchem-624	208	6	us	us	PROPN
eurjchem-624	208	7	is	be	AUX
eurjchem-624	208	8	supported	support	VERB
eurjchem-624	208	9	,	,	PUNCT
eurjchem-624	208	10	in	in	ADP
eurjchem-624	208	11	part	part	NOUN
eurjchem-624	208	12	,	,	PUNCT
eurjchem-624	208	13	by	by	ADP
eurjchem-624	208	14	the	the	DET
eurjchem-624	208	15	delaware	delaware	PROPN
eurjchem-624	208	16	inbre	inbre	PROPN
eurjchem-624	208	17	and	and	CCONJ
eurjchem-624	208	18	epscor	epscor	ADJ
eurjchem-624	208	19	programs	program	NOUN
eurjchem-624	208	20	‐	‐	NOUN
eurjchem-624	208	21	supported	support	VERB
eurjchem-624	208	22	by	by	ADP
eurjchem-624	208	23	grants	grant	NOUN
eurjchem-624	208	24	from	from	ADP
eurjchem-624	208	25	the	the	DET
eurjchem-624	208	26	national	national	ADJ
eurjchem-624	208	27	center	center	NOUN
eurjchem-624	208	28	for	for	ADP
eurjchem-624	208	29	research	research	NOUN
eurjchem-624	208	30	resources‐ncrr	resources‐ncrr	X
eurjchem-624	208	31	(	(	PUNCT
eurjchem-624	208	32	5p20rr016472‐12	5p20rr016472‐12	NUM
eurjchem-624	208	33	)	)	PUNCT
eurjchem-624	208	34	and	and	CCONJ
eurjchem-624	208	35	the	the	DET
eurjchem-624	208	36	national	national	PROPN
eurjchem-624	208	37	institute	institute	PROPN
eurjchem-624	208	38	of	of	ADP
eurjchem-624	208	39	general	general	PROPN
eurjchem-624	208	40	medical	medical	PROPN
eurjchem-624	208	41	sciences	science	NOUN
eurjchem-624	208	42	‐	‐	ADJ
eurjchem-624	208	43	nigms	nigms	NOUN
eurjchem-624	208	44	(	(	PUNCT
eurjchem-624	208	45	8	8	NUM
eurjchem-624	208	46	p20	p20	NOUN
eurjchem-624	208	47	gm103446‐12	gm103446‐12	PROPN
eurjchem-624	208	48	)	)	PUNCT
eurjchem-624	208	49	from	from	ADP
eurjchem-624	208	50	the	the	DET
eurjchem-624	208	51	national	national	PROPN
eurjchem-624	208	52	institutes	institutes	PROPN
eurjchem-624	208	53	of	of	ADP
eurjchem-624	208	54	health	health	PROPN
eurjchem-624	208	55	(	(	PUNCT
eurjchem-624	208	56	nih	nih	PROPN
eurjchem-624	208	57	)	)	PUNCT
eurjchem-624	208	58	;	;	PUNCT
eurjchem-624	208	59	a	a	DET
eurjchem-624	208	60	national	national	PROPN
eurjchem-624	208	61	science	science	PROPN
eurjchem-624	208	62	foundation	foundation	PROPN
eurjchem-624	208	63	(	(	PUNCT
eurjchem-624	208	64	nsf	nsf	PROPN
eurjchem-624	208	65	)	)	PUNCT
eurjchem-624	208	66	delaware	delaware	PROPN
eurjchem-624	208	67	epscor	epscor	PROPN
eurjchem-624	208	68	grant	grant	PROPN
eurjchem-624	208	69	eps‐0814251	eps‐0814251	PROPN
eurjchem-624	208	70	;	;	PUNCT
eurjchem-624	208	71	and	and	CCONJ
eurjchem-624	208	72	a	a	DET
eurjchem-624	208	73	nsf	nsf	PROPN
eurjchem-624	208	74	ari‐r2	ari‐r2	PROPN
eurjchem-624	208	75	grant	grant	NOUN
eurjchem-624	208	76	0960503	0960503	NUM
eurjchem-624	208	77	.	.	PUNCT
eurjchem-624	209	1	references	reference	NOUN
eurjchem-624	209	2	[	[	X
eurjchem-624	209	3	1	1	NUM
eurjchem-624	209	4	]	]	PUNCT
eurjchem-624	209	5	.	.	PUNCT
eurjchem-624	210	1	kevill	kevill	PROPN
eurjchem-624	210	2	d.	d.	PROPN
eurjchem-624	210	3	n.	n.	PROPN
eurjchem-624	210	4	chloroformate	chloroformate	PROPN
eurjchem-624	210	5	esters	ester	NOUN
eurjchem-624	210	6	and	and	CCONJ
eurjchem-624	210	7	related	related	ADJ
eurjchem-624	210	8	compounds	compound	NOUN
eurjchem-624	210	9	.	.	PUNCT
eurjchem-624	211	1	in	in	ADP
eurjchem-624	211	2	:	:	PUNCT
eurjchem-624	211	3	patai	patai	PROPN
eurjchem-624	211	4	s.	s.	PROPN
eurjchem-624	211	5	editor	editor	PROPN
eurjchem-624	211	6	.	.	PUNCT
eurjchem-624	212	1	the	the	DET
eurjchem-624	212	2	chemistry	chemistry	NOUN
eurjchem-624	212	3	of	of	ADP
eurjchem-624	212	4	the	the	DET
eurjchem-624	212	5	functional	functional	ADJ
eurjchem-624	212	6	groups	group	NOUN
eurjchem-624	212	7	:	:	PUNCT
eurjchem-624	212	8	the	the	DET
eurjchem-624	212	9	chemistry	chemistry	NOUN
eurjchem-624	212	10	of	of	ADP
eurjchem-624	212	11	acyl	acyl	ADJ
eurjchem-624	212	12	halides	halide	NOUN
eurjchem-624	212	13	.	.	PUNCT
eurjchem-624	213	1	wiley	wiley	PROPN
eurjchem-624	213	2	;	;	PUNCT
eurjchem-624	213	3	new	new	PROPN
eurjchem-624	213	4	york	york	PROPN
eurjchem-624	213	5	:	:	PUNCT
eurjchem-624	213	6	1972	1972	NUM
eurjchem-624	213	7	,	,	PUNCT
eurjchem-624	213	8	pp	pp	ADJ
eurjchem-624	213	9	.	.	PUNCT
eurjchem-624	214	1	381‐453	381‐453	NUM
eurjchem-624	214	2	,	,	PUNCT
eurjchem-624	214	3	chapter	chapter	NOUN
eurjchem-624	214	4	12	12	NUM
eurjchem-624	214	5	.	.	PUNCT
eurjchem-624	215	1	[	[	X
eurjchem-624	215	2	2	2	NUM
eurjchem-624	215	3	]	]	PUNCT
eurjchem-624	215	4	.	.	PUNCT
eurjchem-624	216	1	grunwald	grunwald	PROPN
eurjchem-624	216	2	,	,	PUNCT
eurjchem-624	216	3	e.	e.	PROPN
eurjchem-624	216	4	;	;	PUNCT
eurjchem-624	216	5	winstein	winstein	PROPN
eurjchem-624	216	6	,	,	PUNCT
eurjchem-624	216	7	s.	s.	PROPN
eurjchem-624	216	8	j.	j.	PROPN
eurjchem-624	216	9	am	am	PROPN
eurjchem-624	216	10	.	.	PUNCT
eurjchem-624	217	1	chem	chem	PROPN
eurjchem-624	217	2	.	.	PUNCT
eurjchem-624	218	1	soc	soc	PROPN
eurjchem-624	218	2	.	.	PUNCT
eurjchem-624	219	1	1948	1948	NUM
eurjchem-624	219	2	,	,	PUNCT
eurjchem-624	219	3	70	70	NUM
eurjchem-624	219	4	,	,	PUNCT
eurjchem-624	219	5	846‐854	846‐854	NUM
eurjchem-624	219	6	.	.	PUNCT
eurjchem-624	220	1	[	[	X
eurjchem-624	220	2	3	3	NUM
eurjchem-624	220	3	]	]	PUNCT
eurjchem-624	220	4	.	.	PUNCT
eurjchem-624	220	5	winstein	winstein	PROPN
eurjchem-624	220	6	,	,	PUNCT
eurjchem-624	220	7	s.	s.	PROPN
eurjchem-624	220	8	;	;	PUNCT
eurjchem-624	220	9	grunwald	grunwald	PROPN
eurjchem-624	220	10	,	,	PUNCT
eurjchem-624	220	11	e.	e.	PROPN
eurjchem-624	220	12	;	;	PUNCT
eurjchem-624	220	13	jones	jones	PROPN
eurjchem-624	220	14	,	,	PUNCT
eurjchem-624	220	15	h.	h.	PROPN
eurjchem-624	220	16	w.	w.	PROPN
eurjchem-624	220	17	j.	j.	PROPN
eurjchem-624	220	18	am	am	PROPN
eurjchem-624	220	19	.	.	PUNCT
eurjchem-624	221	1	chem	chem	PROPN
eurjchem-624	221	2	.	.	PUNCT
eurjchem-624	222	1	soc	soc	PROPN
eurjchem-624	222	2	.	.	PUNCT
eurjchem-624	223	1	1951	1951	NUM
eurjchem-624	223	2	,	,	PUNCT
eurjchem-624	223	3	73	73	NUM
eurjchem-624	223	4	,	,	PUNCT
eurjchem-624	223	5	2700‐2707	2700‐2707	NOUN
eurjchem-624	223	6	.	.	PUNCT
eurjchem-624	224	1	[	[	X
eurjchem-624	224	2	4	4	NUM
eurjchem-624	224	3	]	]	PUNCT
eurjchem-624	224	4	.	.	PUNCT
eurjchem-624	224	5	kevill	kevill	PROPN
eurjchem-624	224	6	,	,	PUNCT
eurjchem-624	224	7	d.	d.	PROPN
eurjchem-624	224	8	n.	n.	PROPN
eurjchem-624	224	9	;	;	PUNCT
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eurjchem-624	224	11	,	,	PUNCT
eurjchem-624	224	12	m.	m.	NOUN
eurjchem-624	224	13	j.	j.	PROPN
eurjchem-624	224	14	j.	j.	PROPN
eurjchem-624	224	15	chem	chem	PROPN
eurjchem-624	224	16	.	.	PUNCT
eurjchem-624	225	1	res	re	NOUN
eurjchem-624	225	2	.	.	PROPN
eurjchem-624	225	3	2008	2008	NUM
eurjchem-624	225	4	,	,	PUNCT
eurjchem-624	225	5	61‐66	61‐66	NOUN
eurjchem-624	225	6	.	.	PUNCT
eurjchem-624	226	1	[	[	X
eurjchem-624	226	2	5	5	NUM
eurjchem-624	226	3	]	]	PUNCT
eurjchem-624	226	4	.	.	PUNCT
eurjchem-624	227	1	kevill	kevill	PROPN
eurjchem-624	227	2	,	,	PUNCT
eurjchem-624	227	3	d.	d.	PROPN
eurjchem-624	227	4	n.	n.	PROPN
eurjchem-624	227	5	;	;	PUNCT
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eurjchem-624	227	7	,	,	PUNCT
eurjchem-624	227	8	m.	m.	PROPN
eurjchem-624	227	9	w.	w.	PROPN
eurjchem-624	227	10	;	;	PUNCT
eurjchem-624	227	11	d’souza	d’souza	PROPN
eurjchem-624	227	12	,	,	PUNCT
eurjchem-624	227	13	m.	m.	NOUN
eurjchem-624	227	14	j.	j.	PROPN
eurjchem-624	227	15	j.	j.	PROPN
eurjchem-624	227	16	org	org	PROPN
eurjchem-624	227	17	.	.	PUNCT
eurjchem-624	227	18	chem	chem	PROPN
eurjchem-624	227	19	.	.	PUNCT
eurjchem-624	228	1	1997	1997	NUM
eurjchem-624	228	2	,	,	PUNCT
eurjchem-624	228	3	62	62	NUM
eurjchem-624	228	4	,	,	PUNCT
eurjchem-624	228	5	7869‐	7869‐	NUM
eurjchem-624	228	6	7871	7871	NUM
eurjchem-624	228	7	.	.	PUNCT
eurjchem-624	229	1	[	[	X
eurjchem-624	229	2	6	6	NUM
eurjchem-624	229	3	]	]	PUNCT
eurjchem-624	229	4	.	.	PUNCT
eurjchem-624	230	1	kevill	kevill	PROPN
eurjchem-624	230	2	,	,	PUNCT
eurjchem-624	230	3	d.	d.	PROPN
eurjchem-624	230	4	n.	n.	PROPN
eurjchem-624	230	5	;	;	PUNCT
eurjchem-624	230	6	d’souza	d’souza	PROPN
eurjchem-624	230	7	,	,	PUNCT
eurjchem-624	230	8	m.	m.	NOUN
eurjchem-624	230	9	j.	j.	PROPN
eurjchem-624	230	10	j.	j.	PROPN
eurjchem-624	230	11	org	org	PROPN
eurjchem-624	230	12	.	.	PUNCT
eurjchem-624	230	13	chem	chem	PROPN
eurjchem-624	230	14	.	.	PUNCT
eurjchem-624	231	1	1998	1998	NUM
eurjchem-624	231	2	,	,	PUNCT
eurjchem-624	231	3	63	63	NUM
eurjchem-624	231	4	,	,	PUNCT
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eurjchem-624	231	6	.	.	PUNCT
eurjchem-624	232	1	[	[	X
eurjchem-624	232	2	7	7	NUM
eurjchem-624	232	3	]	]	PUNCT
eurjchem-624	232	4	.	.	PUNCT
eurjchem-624	233	1	d’souza	d’souza	PROPN
eurjchem-624	233	2	,	,	PUNCT
eurjchem-624	233	3	m.	m.	NOUN
eurjchem-624	233	4	j.	j.	PROPN
eurjchem-624	233	5	;	;	PUNCT
eurjchem-624	233	6	hailey	hailey	PROPN
eurjchem-624	233	7	,	,	PUNCT
eurjchem-624	233	8	s.	s.	PROPN
eurjchem-624	233	9	m.	m.	PROPN
eurjchem-624	233	10	;	;	PUNCT
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eurjchem-624	233	12	,	,	PUNCT
eurjchem-624	233	13	d.	d.	PROPN
eurjchem-624	233	14	n.	n.	PROPN
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eurjchem-624	233	16	.	.	PUNCT
eurjchem-624	234	1	j.	j.	PROPN
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eurjchem-624	234	3	.	.	PUNCT
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eurjchem-624	235	2	.	.	PROPN
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eurjchem-624	235	4	,	,	PUNCT
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eurjchem-624	235	6	,	,	PUNCT
eurjchem-624	235	7	2253‐	2253‐	NUM
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eurjchem-624	235	9	.	.	PUNCT
eurjchem-624	236	1	[	[	X
eurjchem-624	236	2	8	8	NUM
eurjchem-624	236	3	]	]	PUNCT
eurjchem-624	236	4	.	.	PUNCT
eurjchem-624	236	5	d’souza	d’souza	PROPN
eurjchem-624	236	6	m.	m.	NOUN
eurjchem-624	236	7	j.	j.	PROPN
eurjchem-624	236	8	;	;	PUNCT
eurjchem-624	236	9	mahon	mahon	PROPN
eurjchem-624	236	10	,	,	PUNCT
eurjchem-624	236	11	b.	b.	PROPN
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eurjchem-624	236	15	,	,	PUNCT
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eurjchem-624	237	1	j.	j.	PROPN
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eurjchem-624	238	2	.	.	PROPN
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eurjchem-624	238	4	,	,	PUNCT
eurjchem-624	238	5	11	11	NUM
eurjchem-624	238	6	,	,	PUNCT
eurjchem-624	238	7	2597‐	2597‐	NUM
eurjchem-624	238	8	2611	2611	NUM
eurjchem-624	238	9	.	.	PUNCT
eurjchem-624	239	1	[	[	X
eurjchem-624	239	2	9	9	NUM
eurjchem-624	239	3	]	]	PUNCT
eurjchem-624	239	4	.	.	PUNCT
eurjchem-624	240	1	d’souza	d’souza	PROPN
eurjchem-624	240	2	,	,	PUNCT
eurjchem-624	240	3	m.	m.	NOUN
eurjchem-624	240	4	j.	j.	PROPN
eurjchem-624	240	5	;	;	PUNCT
eurjchem-624	240	6	mcaneny	mcaneny	PROPN
eurjchem-624	240	7	,	,	PUNCT
eurjchem-624	240	8	m.	m.	NOUN
eurjchem-624	240	9	j.	j.	PROPN
eurjchem-624	240	10	;	;	PUNCT
eurjchem-624	240	11	kevill	kevill	PROPN
eurjchem-624	240	12	,	,	PUNCT
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eurjchem-624	240	19	b.	b.	PROPN
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eurjchem-624	241	2	,	,	PUNCT
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eurjchem-624	241	4	,	,	PUNCT
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eurjchem-624	241	6	.	.	PUNCT
eurjchem-624	242	1	[	[	X
eurjchem-624	242	2	10	10	NUM
eurjchem-624	242	3	]	]	PUNCT
eurjchem-624	242	4	.	.	PUNCT
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eurjchem-624	243	2	,	,	PUNCT
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eurjchem-624	243	5	;	;	PUNCT
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eurjchem-624	243	7	,	,	PUNCT
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eurjchem-624	243	10	;	;	PUNCT
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eurjchem-624	243	16	.	.	PUNCT
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eurjchem-624	243	18	.	.	PUNCT
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eurjchem-624	243	20	,	,	PUNCT
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eurjchem-624	243	22	,	,	PUNCT
eurjchem-624	243	23	5183‐	5183‐	NUM
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eurjchem-624	243	25	.	.	PUNCT
eurjchem-624	244	1	[	[	X
eurjchem-624	244	2	11	11	NUM
eurjchem-624	244	3	]	]	PUNCT
eurjchem-624	244	4	.	.	PUNCT
eurjchem-624	245	1	bentley	bentley	PROPN
eurjchem-624	245	2	,	,	PUNCT
eurjchem-624	245	3	t.	t.	PROPN
eurjchem-624	245	4	w.	w.	PROPN
eurjchem-624	245	5	;	;	PUNCT
eurjchem-624	245	6	schleyer	schleyer	PROPN
eurjchem-624	245	7	,	,	PUNCT
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eurjchem-624	246	2	.	.	PUNCT
eurjchem-624	247	1	org	org	PROPN
eurjchem-624	247	2	.	.	PUNCT
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eurjchem-624	247	4	.	.	PUNCT
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eurjchem-624	248	2	,	,	PUNCT
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eurjchem-624	248	4	,	,	PUNCT
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eurjchem-624	248	6	.	.	PUNCT
eurjchem-624	249	1	[	[	X
eurjchem-624	249	2	12	12	NUM
eurjchem-624	249	3	]	]	PUNCT
eurjchem-624	249	4	.	.	PUNCT
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eurjchem-624	249	9	;	;	PUNCT
eurjchem-624	249	10	bentley	bentley	PROPN
eurjchem-624	249	11	,	,	PUNCT
eurjchem-624	249	12	t.	t.	PROPN
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eurjchem-624	249	14	;	;	PUNCT
eurjchem-624	249	15	schleyer	schleyer	PROPN
eurjchem-624	249	16	,	,	PUNCT
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eurjchem-624	249	22	.	.	PUNCT
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eurjchem-624	250	2	.	.	PUNCT
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eurjchem-624	251	2	.	.	PUNCT
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eurjchem-624	252	2	,	,	PUNCT
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eurjchem-624	252	4	,	,	PUNCT
eurjchem-624	252	5	7667‐7674	7667‐7674	NUM
eurjchem-624	252	6	.	.	PUNCT
eurjchem-624	253	1	[	[	X
eurjchem-624	253	2	13	13	NUM
eurjchem-624	253	3	]	]	PUNCT
eurjchem-624	253	4	.	.	PUNCT
eurjchem-624	254	1	bentley	bentley	PROPN
eurjchem-624	254	2	,	,	PUNCT
eurjchem-624	254	3	t.	t.	PROPN
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eurjchem-624	254	5	;	;	PUNCT
eurjchem-624	254	6	llewellyn	llewellyn	PROPN
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eurjchem-624	255	2	.	.	PUNCT
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eurjchem-624	256	2	.	.	PUNCT
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eurjchem-624	257	2	,	,	PUNCT
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eurjchem-624	257	4	,	,	PUNCT
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eurjchem-624	257	6	.	.	PUNCT
eurjchem-624	258	1	[	[	X
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eurjchem-624	258	4	.	.	PUNCT
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eurjchem-624	259	5	;	;	PUNCT
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eurjchem-624	259	7	,	,	PUNCT
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eurjchem-624	259	18	.	.	PUNCT
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eurjchem-624	260	2	.	.	PUNCT
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eurjchem-624	261	2	.	.	PUNCT
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eurjchem-624	262	2	,	,	PUNCT
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eurjchem-624	262	4	,	,	PUNCT
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eurjchem-624	262	6	.	.	PUNCT
eurjchem-624	263	1	[	[	X
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eurjchem-624	263	3	]	]	PUNCT
eurjchem-624	263	4	.	.	PUNCT
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eurjchem-624	264	2	,	,	PUNCT
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eurjchem-624	264	13	.	.	PUNCT
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eurjchem-624	265	2	.	.	PUNCT
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eurjchem-624	266	2	.	.	PUNCT
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eurjchem-624	267	2	,	,	PUNCT
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eurjchem-624	267	4	,	,	PUNCT
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eurjchem-624	267	6	.	.	PUNCT
eurjchem-624	268	1	[	[	X
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eurjchem-624	268	3	]	]	PUNCT
eurjchem-624	268	4	.	.	PUNCT
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eurjchem-624	269	2	,	,	PUNCT
eurjchem-624	269	3	d.	d.	PROPN
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eurjchem-624	269	5	;	;	PUNCT
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eurjchem-624	269	12	.	.	PUNCT
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eurjchem-624	270	2	,	,	PUNCT
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eurjchem-624	270	4	,	,	PUNCT
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eurjchem-624	270	6	.	.	PUNCT
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eurjchem-624	271	4	.	.	PUNCT
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eurjchem-624	272	2	,	,	PUNCT
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eurjchem-624	274	4	.	.	PUNCT
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eurjchem-624	277	2	.	.	PUNCT
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eurjchem-624	278	2	,	,	PUNCT
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eurjchem-624	278	4	.	.	PUNCT
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eurjchem-624	279	4	.	.	PUNCT
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eurjchem-624	280	2	,	,	PUNCT
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eurjchem-624	286	2	.	.	PROPN
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eurjchem-624	291	13	,	,	PUNCT
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eurjchem-624	291	22	.	.	PUNCT
eurjchem-624	292	1	korean	korean	ADJ
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eurjchem-624	292	3	.	.	PUNCT
eurjchem-624	293	1	soc	soc	PROPN
eurjchem-624	293	2	.	.	PUNCT
eurjchem-624	294	1	2000	2000	NUM
eurjchem-624	294	2	,	,	PUNCT
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eurjchem-624	294	4	,	,	PUNCT
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eurjchem-624	294	6	.	.	PUNCT
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eurjchem-624	295	2	23	23	NUM
eurjchem-624	295	3	]	]	PUNCT
eurjchem-624	295	4	.	.	PUNCT
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eurjchem-624	296	2	,	,	PUNCT
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eurjchem-624	296	7	,	,	PUNCT
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eurjchem-624	296	10	;	;	PUNCT
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eurjchem-624	296	12	,	,	PUNCT
eurjchem-624	296	13	k.	k.	PROPN
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eurjchem-624	296	16	kyong	kyong	PROPN
eurjchem-624	296	17	,	,	PUNCT
eurjchem-624	296	18	j.	j.	PROPN
eurjchem-624	296	19	b.	b.	PROPN
eurjchem-624	296	20	;	;	PUNCT
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eurjchem-624	296	22	,	,	PUNCT
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eurjchem-624	296	24	n.	n.	PROPN
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eurjchem-624	296	26	.	.	PUNCT
eurjchem-624	297	1	j.	j.	PROPN
eurjchem-624	297	2	mol	mol	PROPN
eurjchem-624	297	3	.	.	PUNCT
eurjchem-624	298	1	sci	sci	PROPN
eurjchem-624	298	2	.	.	PROPN
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eurjchem-624	298	4	,	,	PUNCT
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eurjchem-624	298	6	,	,	PUNCT
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eurjchem-624	298	8	.	.	PUNCT
eurjchem-624	299	1	[	[	X
eurjchem-624	299	2	24	24	NUM
eurjchem-624	299	3	]	]	PUNCT
eurjchem-624	299	4	.	.	PUNCT
eurjchem-624	300	1	kyong	kyong	PROPN
eurjchem-624	300	2	,	,	PUNCT
eurjchem-624	300	3	j.	j.	PROPN
eurjchem-624	300	4	b.	b.	PROPN
eurjchem-624	300	5	;	;	PUNCT
eurjchem-624	300	6	yoo	yoo	PROPN
eurjchem-624	300	7	,	,	PUNCT
eurjchem-624	300	8	j.	j.	PROPN
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eurjchem-624	300	10	.	.	PROPN
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eurjchem-624	300	12	kevill	kevill	PROPN
eurjchem-624	300	13	,	,	PUNCT
eurjchem-624	300	14	d.	d.	PROPN
eurjchem-624	300	15	n.	n.	PROPN
eurjchem-624	300	16	j.	j.	PROPN
eurjchem-624	300	17	org	org	PROPN
eurjchem-624	300	18	.	.	PUNCT
eurjchem-624	300	19	chem	chem	PROPN
eurjchem-624	300	20	.	.	PUNCT
eurjchem-624	301	1	2003	2003	NUM
eurjchem-624	301	2	,	,	PUNCT
eurjchem-624	301	3	68	68	NUM
eurjchem-624	301	4	,	,	PUNCT
eurjchem-624	301	5	3425‐3432	3425‐3432	NUM
eurjchem-624	301	6	.	.	PUNCT
eurjchem-624	302	1	[	[	X
eurjchem-624	302	2	25	25	NUM
eurjchem-624	302	3	]	]	PUNCT
eurjchem-624	302	4	.	.	PUNCT
eurjchem-624	303	1	kevill	kevill	PROPN
eurjchem-624	303	2	,	,	PUNCT
eurjchem-624	303	3	d.	d.	PROPN
eurjchem-624	303	4	n.	n.	PROPN
eurjchem-624	303	5	;	;	PUNCT
eurjchem-624	303	6	d’souza	d’souza	PROPN
eurjchem-624	303	7	,	,	PUNCT
eurjchem-624	303	8	m.	m.	NOUN
eurjchem-624	303	9	j.	j.	PROPN
eurjchem-624	303	10	j.	j.	PROPN
eurjchem-624	303	11	chem	chem	PROPN
eurjchem-624	303	12	.	.	PUNCT
eurjchem-624	304	1	soc	soc	PROPN
eurjchem-624	304	2	.	.	PUNCT
eurjchem-624	305	1	perkin	perkin	PROPN
eurjchem-624	305	2	trans	trans	PROPN
eurjchem-624	305	3	.	.	PROPN
eurjchem-624	305	4	2	2	NUM
eurjchem-624	305	5	1997	1997	NUM
eurjchem-624	305	6	,	,	PUNCT
eurjchem-624	305	7	1721‐	1721‐	NUM
eurjchem-624	305	8	1724	1724	NUM
eurjchem-624	305	9	.	.	PUNCT
eurjchem-624	306	1	[	[	X
eurjchem-624	306	2	26	26	NUM
eurjchem-624	306	3	]	]	PUNCT
eurjchem-624	306	4	.	.	PUNCT
eurjchem-624	307	1	d’souza	d’souza	PROPN
eurjchem-624	307	2	,	,	PUNCT
eurjchem-624	307	3	m.	m.	NOUN
eurjchem-624	307	4	j.	j.	PROPN
eurjchem-624	307	5	;	;	PUNCT
eurjchem-624	307	6	shuman	shuman	PROPN
eurjchem-624	307	7	,	,	PUNCT
eurjchem-624	307	8	k.	k.	PROPN
eurjchem-624	307	9	e.	e.	PROPN
eurjchem-624	307	10	;	;	PUNCT
eurjchem-624	307	11	carter	carter	PROPN
eurjchem-624	307	12	,	,	PUNCT
eurjchem-624	307	13	s.	s.	PROPN
eurjchem-624	307	14	e.	e.	PROPN
eurjchem-624	307	15	;	;	PUNCT
eurjchem-624	307	16	kevill	kevill	PROPN
eurjchem-624	307	17	,	,	PUNCT
eurjchem-624	307	18	d.	d.	PROPN
eurjchem-624	307	19	n.	n.	PROPN
eurjchem-624	307	20	int	int	PROPN
eurjchem-624	307	21	.	.	PUNCT
eurjchem-624	308	1	j.	j.	PROPN
eurjchem-624	308	2	mol	mol	PROPN
eurjchem-624	308	3	.	.	PUNCT
eurjchem-624	309	1	sci	sci	PROPN
eurjchem-624	309	2	.	.	PROPN
eurjchem-624	309	3	2008	2008	NUM
eurjchem-624	309	4	,	,	PUNCT
eurjchem-624	309	5	9	9	NUM
eurjchem-624	309	6	,	,	PUNCT
eurjchem-624	309	7	2231‐2242	2231‐2242	NUM
eurjchem-624	309	8	.	.	PUNCT
eurjchem-624	310	1	[	[	X
eurjchem-624	310	2	27	27	NUM
eurjchem-624	310	3	]	]	PUNCT
eurjchem-624	310	4	.	.	PUNCT
eurjchem-624	311	1	d’souza	d’souza	PROPN
eurjchem-624	311	2	,	,	PUNCT
eurjchem-624	311	3	m.	m.	NOUN
eurjchem-624	311	4	j.	j.	PROPN
eurjchem-624	311	5	;	;	PUNCT
eurjchem-624	311	6	knapp	knapp	PROPN
eurjchem-624	311	7	,	,	PUNCT
eurjchem-624	311	8	j.	j.	PROPN
eurjchem-624	311	9	a.	a.	PROPN
eurjchem-624	311	10	;	;	PUNCT
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eurjchem-624	311	12	,	,	PUNCT
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eurjchem-624	311	15	;	;	PUNCT
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eurjchem-624	311	17	,	,	PUNCT
eurjchem-624	311	18	d.	d.	PROPN
eurjchem-624	311	19	n.	n.	PROPN
eurjchem-624	311	20	int	int	PROPN
eurjchem-624	311	21	.	.	PUNCT
eurjchem-624	312	1	j.	j.	PROPN
eurjchem-624	312	2	mol	mol	PROPN
eurjchem-624	312	3	.	.	PUNCT
eurjchem-624	313	1	sci	sci	PROPN
eurjchem-624	313	2	.	.	PROPN
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eurjchem-624	313	4	,	,	PUNCT
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eurjchem-624	313	6	,	,	PUNCT
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eurjchem-624	313	8	.	.	PUNCT
eurjchem-624	314	1	[	[	X
eurjchem-624	314	2	28	28	NUM
eurjchem-624	314	3	]	]	PUNCT
eurjchem-624	314	4	.	.	PUNCT
eurjchem-624	315	1	choppin	choppin	NOUN
eurjchem-624	315	2	,	,	PUNCT
eurjchem-624	315	3	a.	a.	PROPN
eurjchem-624	315	4	r.	r.	PROPN
eurjchem-624	315	5	;	;	PUNCT
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eurjchem-624	315	7	,	,	PUNCT
eurjchem-624	315	8	j.	j.	PROPN
eurjchem-624	315	9	w.	w.	PROPN
eurjchem-624	315	10	;	;	PUNCT
eurjchem-624	315	11	j.	j.	PROPN
eurjchem-624	315	12	am	am	PROPN
eurjchem-624	315	13	.	.	PUNCT
eurjchem-624	316	1	chem	chem	PROPN
eurjchem-624	316	2	.	.	PUNCT
eurjchem-624	317	1	soc	soc	PROPN
eurjchem-624	317	2	.	.	PUNCT
eurjchem-624	318	1	1948	1948	NUM
eurjchem-624	318	2	,	,	PUNCT
eurjchem-624	318	3	70	70	NUM
eurjchem-624	318	4	,	,	PUNCT
eurjchem-624	318	5	2967‐2967	2967‐2967	NUM
eurjchem-624	318	6	.	.	PUNCT
eurjchem-624	319	1	[	[	X
eurjchem-624	319	2	29	29	NUM
eurjchem-624	319	3	]	]	PUNCT
eurjchem-624	319	4	.	.	PUNCT
eurjchem-624	319	5	sakakibara	sakakibara	PROPN
eurjchem-624	319	6	,	,	PUNCT
eurjchem-624	319	7	s.	s.	PROPN
eurjchem-624	319	8	;	;	PUNCT
eurjchem-624	319	9	shin	shin	PROPN
eurjchem-624	319	10	.	.	PUNCT
eurjchem-624	319	11	m.	m.	NOUN
eurjchem-624	319	12	;	;	PUNCT
eurjchem-624	320	1	fujino	fujino	PROPN
eurjchem-624	320	2	,	,	PUNCT
eurjchem-624	320	3	m.	m.	NOUN
eurjchem-624	320	4	;	;	PUNCT
eurjchem-624	320	5	shimonishi	shimonishi	PROPN
eurjchem-624	320	6	,	,	PUNCT
eurjchem-624	320	7	y.	y.	PROPN
eurjchem-624	320	8	;	;	PUNCT
eurjchem-624	320	9	inove	inove	PROPN
eurjchem-624	320	10	,	,	PUNCT
eurjchem-624	320	11	s.	s.	PROPN
eurjchem-624	320	12	;	;	PUNCT
eurjchem-624	320	13	inukai	inukai	PROPN
eurjchem-624	320	14	,	,	PUNCT
eurjchem-624	320	15	n.	n.	PROPN
eurjchem-624	320	16	bull	bull	PROPN
eurjchem-624	320	17	.	.	PUNCT
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eurjchem-624	321	2	.	.	PUNCT
eurjchem-624	322	1	soc	soc	PROPN
eurjchem-624	322	2	.	.	PUNCT
eurjchem-624	323	1	jpn	jpn	PROPN
eurjchem-624	323	2	.	.	PROPN
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eurjchem-624	324	2	,	,	PUNCT
eurjchem-624	324	3	38	38	NUM
eurjchem-624	324	4	,	,	PUNCT
eurjchem-624	324	5	1522‐1525	1522‐1525	NUM
eurjchem-624	324	6	.	.	PUNCT
eurjchem-624	325	1	[	[	X
eurjchem-624	325	2	30	30	NUM
eurjchem-624	325	3	]	]	PUNCT
eurjchem-624	325	4	.	.	PUNCT
eurjchem-624	326	1	kevill	kevill	PROPN
eurjchem-624	326	2	,	,	PUNCT
eurjchem-624	326	3	d.	d.	PROPN
eurjchem-624	326	4	n.	n.	PROPN
eurjchem-624	326	5	;	;	PUNCT
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eurjchem-624	326	7	,	,	PUNCT
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eurjchem-624	326	9	l.	l.	PROPN
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eurjchem-624	326	12	.	.	PUNCT
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eurjchem-624	327	2	,	,	PUNCT
eurjchem-624	327	3	707‐710	707‐710	NUM
eurjchem-624	327	4	.	.	PUNCT
eurjchem-624	328	1	[	[	X
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eurjchem-624	328	3	]	]	PUNCT
eurjchem-624	328	4	.	.	PUNCT
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eurjchem-624	329	2	,	,	PUNCT
eurjchem-624	329	3	d.	d.	PROPN
eurjchem-624	329	4	n.	n.	PROPN
eurjchem-624	329	5	;	;	PUNCT
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eurjchem-624	329	7	,	,	PUNCT
eurjchem-624	329	8	j.	j.	PROPN
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eurjchem-624	329	10	;	;	PUNCT
eurjchem-624	329	11	weitl	weitl	PROPN
eurjchem-624	329	12	,	,	PUNCT
eurjchem-624	329	13	f.	f.	PROPN
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eurjchem-624	329	17	.	.	PUNCT
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eurjchem-624	329	19	.	.	PUNCT
eurjchem-624	330	1	1990	1990	NUM
eurjchem-624	330	2	,	,	PUNCT
eurjchem-624	330	3	55	55	NUM
eurjchem-624	330	4	,	,	PUNCT
eurjchem-624	330	5	4304‐4311	4304‐4311	NUM
eurjchem-624	330	6	.	.	PUNCT
eurjchem-624	331	1	[	[	X
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eurjchem-624	331	3	]	]	PUNCT
eurjchem-624	331	4	.	.	PUNCT
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eurjchem-624	332	2	,	,	PUNCT
eurjchem-624	332	3	d.	d.	PROPN
eurjchem-624	332	4	n.	n.	PROPN
eurjchem-624	332	5	;	;	PUNCT
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eurjchem-624	332	7	,	,	PUNCT
eurjchem-624	332	8	f.	f.	PROPN
eurjchem-624	332	9	l.	l.	PROPN
eurjchem-624	332	10	j.	j.	PROPN
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eurjchem-624	332	12	.	.	PUNCT
eurjchem-624	333	1	soc	soc	PROPN
eurjchem-624	333	2	.	.	PUNCT
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eurjchem-624	334	3	.	.	PROPN
eurjchem-624	334	4	1	1	NUM
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eurjchem-624	334	6	,	,	PUNCT
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eurjchem-624	334	8	.	.	PUNCT
eurjchem-624	335	1	[	[	X
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eurjchem-624	335	3	]	]	PUNCT
eurjchem-624	335	4	.	.	PUNCT
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eurjchem-624	336	2	,	,	PUNCT
eurjchem-624	336	3	d.	d.	PROPN
eurjchem-624	336	4	n.	n.	PROPN
eurjchem-624	336	5	;	;	PUNCT
eurjchem-624	336	6	weitl	weitl	PROPN
eurjchem-624	336	7	,	,	PUNCT
eurjchem-624	336	8	f.	f.	PROPN
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eurjchem-624	336	12	.	.	PUNCT
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eurjchem-624	337	2	.	.	PROPN
eurjchem-624	338	1	synop	synop	PROPN
eurjchem-624	338	2	.	.	PUNCT
eurjchem-624	339	1	1989	1989	NUM
eurjchem-624	339	2	,	,	PUNCT
eurjchem-624	339	3	318‐319	318‐319	NUM
eurjchem-624	339	4	.	.	PUNCT
eurjchem-624	340	1	[	[	X
eurjchem-624	340	2	34	34	NUM
eurjchem-624	340	3	]	]	PUNCT
eurjchem-624	340	4	.	.	PUNCT
eurjchem-624	341	1	kevill	kevill	PROPN
eurjchem-624	341	2	,	,	PUNCT
eurjchem-624	341	3	d.	d.	PROPN
eurjchem-624	341	4	n.	n.	PROPN
eurjchem-624	341	5	;	;	PUNCT
eurjchem-624	341	6	weitl	weitl	PROPN
eurjchem-624	341	7	,	,	PUNCT
eurjchem-624	341	8	f.	f.	PROPN
eurjchem-624	341	9	l.	l.	PROPN
eurjchem-624	341	10	j.	j.	PROPN
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eurjchem-624	341	12	.	.	PUNCT
eurjchem-624	342	1	chem	chem	PROPN
eurjchem-624	342	2	.	.	PUNCT
eurjchem-624	343	1	soc	soc	PROPN
eurjchem-624	343	2	.	.	PUNCT
eurjchem-624	344	1	1968	1968	NUM
eurjchem-624	344	2	,	,	PUNCT
eurjchem-624	344	3	90	90	NUM
eurjchem-624	344	4	,	,	PUNCT
eurjchem-624	344	5	6416‐6420	6416‐6420	NUM
eurjchem-624	344	6	.	.	PUNCT
eurjchem-624	345	1	[	[	X
eurjchem-624	345	2	35	35	NUM
eurjchem-624	345	3	]	]	PUNCT
eurjchem-624	345	4	.	.	PUNCT
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eurjchem-624	346	2	,	,	PUNCT
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eurjchem-624	346	5	;	;	PUNCT
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eurjchem-624	346	7	,	,	PUNCT
eurjchem-624	346	8	e.	e.	PROPN
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eurjchem-624	346	10	;	;	PUNCT
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eurjchem-624	346	12	,	,	PUNCT
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eurjchem-624	346	16	.	.	PUNCT
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eurjchem-624	347	2	.	.	PUNCT
eurjchem-624	348	1	soc	soc	PROPN
eurjchem-624	348	2	.	.	PUNCT
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eurjchem-624	349	2	,	,	PUNCT
eurjchem-624	349	3	88	88	NUM
eurjchem-624	349	4	,	,	PUNCT
eurjchem-624	349	5	1988‐1992	1988‐1992	NUM
eurjchem-624	349	6	.	.	PUNCT
eurjchem-624	350	1	[	[	X
eurjchem-624	350	2	36	36	NUM
eurjchem-624	350	3	]	]	PUNCT
eurjchem-624	350	4	.	.	PUNCT
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eurjchem-624	351	2	,	,	PUNCT
eurjchem-624	351	3	d.	d.	PROPN
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eurjchem-624	351	5	;	;	PUNCT
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eurjchem-624	351	7	,	,	PUNCT
eurjchem-624	351	8	j.	j.	PROPN
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eurjchem-624	351	10	j.	j.	PROPN
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eurjchem-624	351	12	.	.	PUNCT
eurjchem-624	351	13	chem	chem	PROPN
eurjchem-624	351	14	.	.	PUNCT
eurjchem-624	352	1	1992	1992	NUM
eurjchem-624	352	2	,	,	PUNCT
eurjchem-624	352	3	57	57	NUM
eurjchem-624	352	4	,	,	PUNCT
eurjchem-624	352	5	258‐265	258‐265	NUM
eurjchem-624	352	6	.	.	PUNCT
eurjchem-624	353	1	[	[	X
eurjchem-624	353	2	37	37	NUM
eurjchem-624	353	3	]	]	PUNCT
eurjchem-624	353	4	.	.	PUNCT
eurjchem-624	353	5	hoshiko	hoshiko	NOUN
eurjchem-624	353	6	,	,	PUNCT
eurjchem-624	353	7	t.	t.	PROPN
eurjchem-624	353	8	;	;	PUNCT
eurjchem-624	353	9	ozaki	ozaki	PROPN
eurjchem-624	353	10	,	,	PUNCT
eurjchem-624	353	11	s.	s.	PROPN
eurjchem-624	353	12	;	;	PUNCT
eurjchem-624	353	13	watanabe	watanabe	PROPN
eurjchem-624	353	14	,	,	PUNCT
eurjchem-624	353	15	y.	y.	PROPN
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eurjchem-624	353	22	,	,	PUNCT
eurjchem-624	353	23	s.	s.	PROPN
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eurjchem-624	353	26	,	,	PUNCT
eurjchem-624	353	27	k.	k.	PROPN
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eurjchem-624	353	30	,	,	PUNCT
eurjchem-624	353	31	a.	a.	PROPN
eurjchem-624	353	32	;	;	PUNCT
eurjchem-624	353	33	iigo	iigo	ADJ
eurjchem-624	353	34	,	,	PUNCT
eurjchem-624	353	35	m.	m.	NOUN
eurjchem-624	353	36	chem	chem	NOUN
eurjchem-624	353	37	.	.	PUNCT
eurjchem-624	354	1	pharm	pharm	NOUN
eurjchem-624	354	2	.	.	PUNCT
eurjchem-624	355	1	bull	bull	PROPN
eurjchem-624	355	2	.	.	PUNCT
eurjchem-624	356	1	1985	1985	NUM
eurjchem-624	356	2	,	,	PUNCT
eurjchem-624	356	3	33	33	NUM
eurjchem-624	356	4	,	,	PUNCT
eurjchem-624	356	5	2832‐	2832‐	NUM
eurjchem-624	356	6	2837	2837	NUM
eurjchem-624	356	7	.	.	PUNCT
eurjchem-624	357	1	[	[	X
eurjchem-624	357	2	38	38	NUM
eurjchem-624	357	3	]	]	PUNCT
eurjchem-624	357	4	.	.	PUNCT
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eurjchem-624	358	2	,	,	PUNCT
eurjchem-624	358	3	y.	y.	PROPN
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eurjchem-624	358	5	;	;	PUNCT
eurjchem-624	358	6	seong	seong	PROPN
eurjchem-624	358	7	,	,	PUNCT
eurjchem-624	358	8	m.	m.	PROPN
eurjchem-624	358	9	h.	h.	PROPN
eurjchem-624	358	10	;	;	PUNCT
eurjchem-624	358	11	lee	lee	PROPN
eurjchem-624	358	12	,	,	PUNCT
eurjchem-624	358	13	e.	e.	PROPN
eurjchem-624	358	14	s.	s.	PROPN
eurjchem-624	358	15	;	;	PUNCT
eurjchem-624	358	16	lee	lee	PROPN
eurjchem-624	358	17	,	,	PUNCT
eurjchem-624	358	18	y.	y.	NOUN
eurjchem-624	358	19	‐w	‐w	NOUN
eurjchem-624	358	20	.	.	PUNCT
eurjchem-624	358	21	;	;	PUNCT
eurjchem-624	358	22	won	win	VERB
eurjchem-624	358	23	,	,	PUNCT
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eurjchem-624	358	25	;	;	PUNCT
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eurjchem-624	358	27	,	,	PUNCT
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eurjchem-624	358	29	b.	b.	PROPN
eurjchem-624	358	30	;	;	PUNCT
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eurjchem-624	358	32	,	,	PUNCT
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eurjchem-624	358	34	n.	n.	PROPN
eurjchem-624	358	35	bull	bull	PROPN
eurjchem-624	358	36	.	.	PUNCT
eurjchem-624	359	1	korean	korean	ADJ
eurjchem-624	359	2	chem	chem	PROPN
eurjchem-624	359	3	.	.	PUNCT
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eurjchem-624	360	2	.	.	PUNCT
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eurjchem-624	361	2	,	,	PUNCT
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eurjchem-624	361	4	,	,	PUNCT
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eurjchem-624	361	6	.	.	PUNCT
eurjchem-624	362	1	[	[	X
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eurjchem-624	362	3	]	]	PUNCT
eurjchem-624	362	4	.	.	PUNCT
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eurjchem-624	362	6	,	,	PUNCT
eurjchem-624	362	7	t.	t.	PROPN
eurjchem-624	362	8	w.	w.	PROPN
eurjchem-624	362	9	;	;	PUNCT
eurjchem-624	362	10	carter	carter	PROPN
eurjchem-624	362	11	,	,	PUNCT
eurjchem-624	362	12	g.	g.	PROPN
eurjchem-624	362	13	e.	e.	PROPN
eurjchem-624	362	14	j.	j.	PROPN
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eurjchem-624	362	16	.	.	PUNCT
eurjchem-624	363	1	chem	chem	PROPN
eurjchem-624	363	2	.	.	PUNCT
eurjchem-624	364	1	soc	soc	PROPN
eurjchem-624	364	2	.	.	PUNCT
eurjchem-624	365	1	1982	1982	NUM
eurjchem-624	365	2	,	,	PUNCT
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eurjchem-624	365	4	,	,	PUNCT
eurjchem-624	365	5	5741‐5747	5741‐5747	PROPN
eurjchem-624	365	6	.	.	PUNCT
eurjchem-624	366	1	[	[	X
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eurjchem-624	366	3	]	]	PUNCT
eurjchem-624	366	4	.	.	PUNCT
eurjchem-624	367	1	kevill	kevill	PROPN
eurjchem-624	367	2	,	,	PUNCT
eurjchem-624	367	3	d.	d.	PROPN
eurjchem-624	367	4	n.	n.	PROPN
eurjchem-624	367	5	;	;	PUNCT
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eurjchem-624	367	7	,	,	PUNCT
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eurjchem-624	367	9	j.	j.	PROPN
eurjchem-624	367	10	j.	j.	PROPN
eurjchem-624	367	11	chem	chem	PROPN
eurjchem-624	367	12	.	.	PUNCT
eurjchem-624	368	1	res	re	NOUN
eurjchem-624	368	2	.	.	PUNCT
eurjchem-624	369	1	synop	synop	ADJ
eurjchem-624	369	2	.	.	PUNCT
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eurjchem-624	370	2	,	,	PUNCT
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eurjchem-624	370	4	.	.	PUNCT
eurjchem-624	371	1	[	[	X
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eurjchem-624	371	3	]	]	PUNCT
eurjchem-624	371	4	.	.	PUNCT
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eurjchem-624	372	2	,	,	PUNCT
eurjchem-624	372	3	j.	j.	PROPN
eurjchem-624	372	4	s.	s.	PROPN
eurjchem-624	372	5	;	;	PUNCT
eurjchem-624	372	6	d’souza	d’souza	PROPN
eurjchem-624	372	7	,	,	PUNCT
eurjchem-624	372	8	m.	m.	NOUN
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eurjchem-624	372	10	;	;	PUNCT
eurjchem-624	372	11	kevill	kevill	PROPN
eurjchem-624	372	12	,	,	PUNCT
eurjchem-624	372	13	d.	d.	PROPN
eurjchem-624	372	14	n.	n.	PROPN
eurjchem-624	372	15	j.	j.	PROPN
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eurjchem-624	372	17	.	.	PUNCT
eurjchem-624	373	1	chem	chem	NOUN
eurjchem-624	373	2	.	.	PUNCT
eurjchem-624	374	1	soc	soc	PROPN
eurjchem-624	374	2	.	.	PUNCT
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eurjchem-624	375	2	,	,	PUNCT
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eurjchem-624	375	4	,	,	PUNCT
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eurjchem-624	375	6	.	.	PUNCT
eurjchem-624	376	1	[	[	X
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eurjchem-624	376	3	]	]	PUNCT
eurjchem-624	376	4	.	.	PUNCT
eurjchem-624	377	1	kevill	kevill	PROPN
eurjchem-624	377	2	,	,	PUNCT
eurjchem-624	377	3	d.	d.	PROPN
eurjchem-624	377	4	n.	n.	PROPN
eurjchem-624	377	5	;	;	PUNCT
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eurjchem-624	377	7	,	,	PUNCT
eurjchem-624	377	8	z.	z.	PROPN
eurjchem-624	377	9	h.	h.	PROPN
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eurjchem-624	377	11	.	.	PUNCT
eurjchem-624	378	1	j.	j.	PROPN
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eurjchem-624	378	3	.	.	PUNCT
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eurjchem-624	379	2	.	.	PUNCT
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eurjchem-624	379	4	,	,	PUNCT
eurjchem-624	379	5	7	7	NUM
eurjchem-624	379	6	,	,	PUNCT
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eurjchem-624	379	8	.	.	PUNCT
eurjchem-624	380	1	[	[	X
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eurjchem-624	380	3	]	]	PUNCT
eurjchem-624	380	4	.	.	PUNCT
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eurjchem-624	381	2	,	,	PUNCT
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eurjchem-624	382	4	,	,	PUNCT
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eurjchem-624	382	15	.	.	PUNCT
eurjchem-624	383	1	[	[	X
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eurjchem-624	383	4	.	.	PUNCT
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eurjchem-624	384	2	,	,	PUNCT
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eurjchem-624	384	5	;	;	PUNCT
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eurjchem-624	384	7	,	,	PUNCT
eurjchem-624	384	8	s.	s.	PROPN
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eurjchem-624	384	10	;	;	PUNCT
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eurjchem-624	386	2	.	.	PUNCT
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eurjchem-624	387	2	,	,	PUNCT
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eurjchem-624	387	4	,	,	PUNCT
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eurjchem-624	387	6	.	.	PUNCT
eurjchem-624	388	1	[	[	X
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eurjchem-624	388	3	]	]	PUNCT
eurjchem-624	388	4	.	.	PUNCT
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eurjchem-624	389	2	,	,	PUNCT
eurjchem-624	389	3	d.	d.	PROPN
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eurjchem-624	389	5	;	;	PUNCT
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eurjchem-624	389	7	,	,	PUNCT
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eurjchem-624	389	11	.	.	PUNCT
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eurjchem-624	389	13	.	.	PUNCT
eurjchem-624	390	1	2002	2002	NUM
eurjchem-624	390	2	,	,	PUNCT
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eurjchem-624	390	4	,	,	PUNCT
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eurjchem-624	390	6	.	.	PUNCT
eurjchem-624	391	1	[	[	X
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eurjchem-624	391	3	]	]	PUNCT
eurjchem-624	391	4	.	.	PUNCT
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eurjchem-624	392	2	,	,	PUNCT
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eurjchem-624	392	5	.	.	PUNCT
eurjchem-624	392	6	;	;	PUNCT
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eurjchem-624	392	8	,	,	PUNCT
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eurjchem-624	392	11	;	;	PUNCT
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eurjchem-624	392	13	,	,	PUNCT
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eurjchem-624	394	2	.	.	PUNCT
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eurjchem-624	395	2	,	,	PUNCT
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eurjchem-624	395	4	,	,	PUNCT
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eurjchem-624	395	6	.	.	PUNCT
eurjchem-624	396	1	[	[	X
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eurjchem-624	396	4	.	.	PUNCT
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eurjchem-624	397	5	;	;	PUNCT
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eurjchem-624	397	13	;	;	PUNCT
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eurjchem-624	397	15	,	,	PUNCT
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eurjchem-624	397	17	j.	j.	PROPN
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eurjchem-624	397	19	.	.	PUNCT
eurjchem-624	398	1	chem	chem	PROPN
eurjchem-624	398	2	.	.	PUNCT
eurjchem-624	399	1	soc	soc	PROPN
eurjchem-624	399	2	.	.	PUNCT
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eurjchem-624	400	2	,	,	PUNCT
eurjchem-624	400	3	96	96	NUM
eurjchem-624	400	4	,	,	PUNCT
eurjchem-624	400	5	2221‐2228	2221‐2228	NUM
eurjchem-624	400	6	.	.	PUNCT
eurjchem-624	401	1	[	[	X
eurjchem-624	401	2	48	48	NUM
eurjchem-624	401	3	]	]	PUNCT
eurjchem-624	401	4	.	.	PUNCT
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eurjchem-624	402	2	,	,	PUNCT
eurjchem-624	402	3	t.	t.	PROPN
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eurjchem-624	402	5	j.	j.	PROPN
eurjchem-624	402	6	org	org	PROPN
eurjchem-624	402	7	.	.	PUNCT
eurjchem-624	402	8	chem	chem	PROPN
eurjchem-624	402	9	.	.	PUNCT
eurjchem-624	403	1	2008	2008	NUM
eurjchem-624	403	2	,	,	PUNCT
eurjchem-624	403	3	73	73	NUM
eurjchem-624	403	4	,	,	PUNCT
eurjchem-624	403	5	6251‐6257	6251‐6257	NUM
eurjchem-624	403	6	.	.	PUNCT
eurjchem-624	404	1	[	[	X
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eurjchem-624	404	3	]	]	PUNCT
eurjchem-624	404	4	.	.	PUNCT
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eurjchem-624	404	6	,	,	PUNCT
eurjchem-624	404	7	d.	d.	PROPN
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eurjchem-624	404	9	;	;	PUNCT
eurjchem-624	404	10	koyoshi	koyoshi	PROPN
eurjchem-624	404	11	,	,	PUNCT
eurjchem-624	404	12	f.	f.	PROPN
eurjchem-624	404	13	;	;	PUNCT
eurjchem-624	404	14	d’souza	d’souza	PROPN
eurjchem-624	404	15	,	,	PUNCT
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eurjchem-624	404	17	j.	j.	PROPN
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eurjchem-624	404	19	.	.	PUNCT
eurjchem-624	405	1	j.	j.	PROPN
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eurjchem-624	405	3	.	.	PUNCT
eurjchem-624	406	1	sci	sci	PROPN
eurjchem-624	406	2	.	.	PROPN
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eurjchem-624	406	4	,	,	PUNCT
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eurjchem-624	406	6	,	,	PUNCT
eurjchem-624	406	7	346‐362	346‐362	NUM
eurjchem-624	406	8	.	.	PUNCT
eurjchem-624	407	1	[	[	X
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eurjchem-624	407	3	]	]	PUNCT
eurjchem-624	407	4	.	.	PUNCT
eurjchem-624	408	1	d’souza	d’souza	PROPN
eurjchem-624	408	2	,	,	PUNCT
eurjchem-624	408	3	m.	m.	NOUN
eurjchem-624	408	4	j.	j.	PROPN
eurjchem-624	408	5	;	;	PUNCT
eurjchem-624	408	6	shuman	shuman	PROPN
eurjchem-624	408	7	,	,	PUNCT
eurjchem-624	408	8	k.	k.	PROPN
eurjchem-624	408	9	e.	e.	PROPN
eurjchem-624	408	10	;	;	PUNCT
eurjchem-624	408	11	omondi	omondi	PROPN
eurjchem-624	408	12	,	,	PUNCT
eurjchem-624	408	13	a.	a.	PROPN
eurjchem-624	408	14	o.	o.	PROPN
eurjchem-624	408	15	;	;	PUNCT
eurjchem-624	408	16	kevill	kevill	PROPN
eurjchem-624	408	17	,	,	PUNCT
eurjchem-624	408	18	d.	d.	PROPN
eurjchem-624	408	19	n.	n.	PROPN
eurjchem-624	408	20	eur	eur	PROPN
eurjchem-624	408	21	.	.	PUNCT
eurjchem-624	409	1	j.	j.	PROPN
eurjchem-624	409	2	chem	chem	PROPN
eurjchem-624	409	3	.	.	PUNCT
eurjchem-624	410	1	2011	2011	NUM
eurjchem-624	410	2	,	,	PUNCT
eurjchem-624	410	3	2	2	NUM
eurjchem-624	410	4	,	,	PUNCT
eurjchem-624	410	5	130‐135	130‐135	NOUN
eurjchem-624	410	6	.	.	PUNCT
eurjchem-624	411	1	[	[	X
eurjchem-624	411	2	51	51	NUM
eurjchem-624	411	3	]	]	PUNCT
eurjchem-624	411	4	.	.	PUNCT
eurjchem-624	412	1	bentley	bentley	PROPN
eurjchem-624	412	2	,	,	PUNCT
eurjchem-624	412	3	t.	t.	PROPN
eurjchem-624	412	4	w.	w.	PROPN
eurjchem-624	412	5	;	;	PUNCT
eurjchem-624	412	6	bowen	bowen	PROPN
eurjchem-624	412	7	,	,	PUNCT
eurjchem-624	412	8	c.	c.	PROPN
eurjchem-624	412	9	t.	t.	PROPN
eurjchem-624	412	10	;	;	PUNCT
eurjchem-624	412	11	parker	parker	PROPN
eurjchem-624	412	12	,	,	PUNCT
eurjchem-624	412	13	w.	w.	PROPN
eurjchem-624	412	14	;	;	PUNCT
eurjchem-624	412	15	watt	watt	NOUN
eurjchem-624	412	16	,	,	PUNCT
eurjchem-624	412	17	c.	c.	PROPN
eurjchem-624	412	18	i.	i.	PROPN
eurjchem-624	412	19	f.	f.	PROPN
eurjchem-624	412	20	j.	j.	PROPN
eurjchem-624	412	21	chem	chem	PROPN
eurjchem-624	412	22	.	.	PUNCT
eurjchem-624	413	1	soc	soc	PROPN
eurjchem-624	413	2	.	.	PUNCT
eurjchem-624	413	3	,	,	PUNCT
eurjchem-624	413	4	perkin	perkin	PROPN
eurjchem-624	413	5	trans	trans	PROPN
eurjchem-624	413	6	.	.	PROPN
eurjchem-624	414	1	2	2	NUM
eurjchem-624	414	2	1980	1980	NUM
eurjchem-624	414	3	,	,	PUNCT
eurjchem-624	414	4	1244‐1252	1244‐1252	NUM
eurjchem-624	414	5	.	.	PUNCT