id	sid	tid	token	lemma	pos
eurjchem-769	1	1	untitled	untitle	VERB
eurjchem-769	1	2	european	european	PROPN
eurjchem-769	1	3	journal	journal	PROPN
eurjchem-769	1	4	of	of	ADP
eurjchem-769	1	5	chemistry	chemistry	NOUN
eurjchem-769	1	6	4	4	NUM
eurjchem-769	1	7	(	(	PUNCT
eurjchem-769	1	8	4	4	NUM
eurjchem-769	1	9	)	)	PUNCT
eurjchem-769	1	10	(	(	PUNCT
eurjchem-769	1	11	2013	2013	NUM
eurjchem-769	1	12	)	)	PUNCT
eurjchem-769	1	13	450‐453	450‐453	NUM
eurjchem-769	1	14	european	european	PROPN
eurjchem-769	1	15	journal	journal	PROPN
eurjchem-769	1	16	of	of	ADP
eurjchem-769	1	17	chemistry	chemistry	NOUN
eurjchem-769	1	18	issn	issn	PROPN
eurjchem-769	1	19	2153‐2249	2153‐2249	PROPN
eurjchem-769	1	20	(	(	PUNCT
eurjchem-769	1	21	print	print	NOUN
eurjchem-769	1	22	)	)	PUNCT
eurjchem-769	1	23	/	/	SYM
eurjchem-769	1	24	issn	issn	PROPN
eurjchem-769	1	25	2153‐2257	2153‐2257	NUM
eurjchem-769	1	26	(	(	PUNCT
eurjchem-769	1	27	online	online	ADJ
eurjchem-769	1	28	)	)	PUNCT
eurjchem-769	1	29			NOUN
eurjchem-769	1	30	2013	2013	NUM
eurjchem-769	1	31	eurjchem	eurjchem	PROPN
eurjchem-769	1	32	doi:10.5155	doi:10.5155	NOUN
eurjchem-769	1	33	/	/	SYM
eurjchem-769	1	34	eurjchem.4.4.450‐453.769	eurjchem.4.4.450‐453.769	NOUN
eurjchem-769	1	35	european	european	ADJ
eurjchem-769	1	36	journal	journal	PROPN
eurjchem-769	1	37	of	of	ADP
eurjchem-769	1	38	chemistry	chemistry	PROPN
eurjchem-769	1	39	journal	journal	PROPN
eurjchem-769	1	40	homepage	homepage	NOUN
eurjchem-769	1	41	:	:	PUNCT
eurjchem-769	1	42	www.eurjchem.com	www.eurjchem.com	X
eurjchem-769	1	43	glycerol	glycerol	NOUN
eurjchem-769	1	44	mediated	mediate	VERB
eurjchem-769	1	45	,	,	PUNCT
eurjchem-769	1	46	one	one	NUM
eurjchem-769	1	47	pot	pot	NOUN
eurjchem-769	1	48	,	,	PUNCT
eurjchem-769	1	49	multicomponent	multicomponent	NOUN
eurjchem-769	1	50	synthesis	synthesis	NOUN
eurjchem-769	1	51	of	of	ADP
eurjchem-769	1	52	dihydropyrano[2,3‐c]pyrazoles	dihydropyrano[2,3‐c]pyrazole	NOUN
eurjchem-769	1	53	harvinder	harvinder	NOUN
eurjchem-769	1	54	singh	singh	PROPN
eurjchem-769	1	55	sohal	sohal	VERB
eurjchem-769	1	56	a	a	PRON
eurjchem-769	1	57	,	,	PUNCT
eurjchem-769	1	58	arun	arun	PROPN
eurjchem-769	1	59	goyal	goyal	PROPN
eurjchem-769	1	60	a	a	PROPN
eurjchem-769	1	61	,	,	PUNCT
eurjchem-769	1	62	rajeev	rajeev	PROPN
eurjchem-769	1	63	sharma	sharma	PROPN
eurjchem-769	1	64	a	a	PROPN
eurjchem-769	1	65	,	,	PUNCT
eurjchem-769	1	66	rajshree	rajshree	PROPN
eurjchem-769	1	67	khare	khare	PROPN
eurjchem-769	1	68	b	b	PROPN
eurjchem-769	1	69	and	and	CCONJ
eurjchem-769	1	70	sanjay	sanjay	PROPN
eurjchem-769	1	71	kumar	kumar	PROPN
eurjchem-769	1	72	a	a	PROPN
eurjchem-769	1	73	,	,	PUNCT
eurjchem-769	1	74	*	*	PUNCT
eurjchem-769	1	75	a	a	DET
eurjchem-769	1	76	department	department	NOUN
eurjchem-769	1	77	of	of	ADP
eurjchem-769	1	78	chemistry	chemistry	NOUN
eurjchem-769	1	79	,	,	PUNCT
eurjchem-769	1	80	multani	multani	PROPN
eurjchem-769	1	81	mal	mal	PROPN
eurjchem-769	1	82	modi	modi	PROPN
eurjchem-769	1	83	college	college	PROPN
eurjchem-769	1	84	,	,	PUNCT
eurjchem-769	1	85	patiala	patiala	NOUN
eurjchem-769	1	86	,	,	PUNCT
eurjchem-769	1	87	147001	147001	NUM
eurjchem-769	1	88	,	,	PUNCT
eurjchem-769	1	89	punjab	punjab	PROPN
eurjchem-769	1	90	,	,	PUNCT
eurjchem-769	1	91	india	india	PROPN
eurjchem-769	1	92	b	b	PROPN
eurjchem-769	1	93	department	department	PROPN
eurjchem-769	1	94	of	of	ADP
eurjchem-769	1	95	chemistry	chemistry	NOUN
eurjchem-769	1	96	,	,	PUNCT
eurjchem-769	1	97	maharishi	maharishi	PROPN
eurjchem-769	1	98	markandeshwar	markandeshwar	PROPN
eurjchem-769	1	99	university	university	PROPN
eurjchem-769	1	100	,	,	PUNCT
eurjchem-769	1	101	mullana	mullana	PROPN
eurjchem-769	1	102	,	,	PUNCT
eurjchem-769	1	103	133207	133207	NUM
eurjchem-769	1	104	,	,	PUNCT
eurjchem-769	1	105	haryana	haryana	PROPN
eurjchem-769	1	106	,	,	PUNCT
eurjchem-769	1	107	india	india	PROPN
eurjchem-769	1	108	*	*	PUNCT
eurjchem-769	1	109	corresponding	correspond	VERB
eurjchem-769	1	110	author	author	NOUN
eurjchem-769	1	111	at	at	ADP
eurjchem-769	1	112	:	:	PUNCT
eurjchem-769	1	113	department	department	NOUN
eurjchem-769	1	114	of	of	ADP
eurjchem-769	1	115	chemistry	chemistry	NOUN
eurjchem-769	1	116	,	,	PUNCT
eurjchem-769	1	117	multani	multani	PROPN
eurjchem-769	1	118	mal	mal	PROPN
eurjchem-769	1	119	modi	modi	PROPN
eurjchem-769	1	120	college	college	PROPN
eurjchem-769	1	121	,	,	PUNCT
eurjchem-769	1	122	patiala	patiala	NOUN
eurjchem-769	1	123	,	,	PUNCT
eurjchem-769	1	124	147001	147001	NUM
eurjchem-769	1	125	,	,	PUNCT
eurjchem-769	1	126	punjab	punjab	PROPN
eurjchem-769	1	127	,	,	PUNCT
eurjchem-769	1	128	india	india	PROPN
eurjchem-769	1	129	.	.	PUNCT
eurjchem-769	2	1	tel	tel	PROPN
eurjchem-769	2	2	.	.	PUNCT
eurjchem-769	2	3	:	:	PUNCT
eurjchem-769	3	1	+91.988.8339791	+91.988.8339791	NUM
eurjchem-769	3	2	;	;	PUNCT
eurjchem-769	3	3	fax	fax	NOUN
eurjchem-769	3	4	:	:	PUNCT
eurjchem-769	3	5	+91.175.2212049	+91.175.2212049	NUM
eurjchem-769	3	6	.	.	PUNCT
eurjchem-769	3	7	e‐mail	e‐mail	PUNCT
eurjchem-769	4	1	address	address	NOUN
eurjchem-769	4	2	:	:	PUNCT
eurjchem-769	4	3	sanjay2002@gmail.com	sanjay2002@gmail.com	PROPN
eurjchem-769	4	4	(	(	PUNCT
eurjchem-769	4	5	s.	s.	PROPN
eurjchem-769	4	6	kumar	kumar	PROPN
eurjchem-769	4	7	)	)	PUNCT
eurjchem-769	4	8	.	.	PUNCT
eurjchem-769	5	1	article	article	NOUN
eurjchem-769	5	2	information	information	PROPN
eurjchem-769	5	3	abstract	abstract	ADV
eurjchem-769	5	4	received	receive	VERB
eurjchem-769	5	5	:	:	PUNCT
eurjchem-769	5	6	12	12	NUM
eurjchem-769	5	7	march	march	NOUN
eurjchem-769	5	8	2013	2013	NUM
eurjchem-769	5	9	received	receive	VERB
eurjchem-769	5	10	in	in	ADP
eurjchem-769	5	11	revised	revise	VERB
eurjchem-769	5	12	form	form	NOUN
eurjchem-769	5	13	:	:	PUNCT
eurjchem-769	5	14	13	13	NUM
eurjchem-769	5	15	june	june	PROPN
eurjchem-769	5	16	2013	2013	NUM
eurjchem-769	5	17	accepted	accept	VERB
eurjchem-769	5	18	:	:	PUNCT
eurjchem-769	6	1	14	14	NUM
eurjchem-769	6	2	june	june	PROPN
eurjchem-769	6	3	2013	2013	NUM
eurjchem-769	6	4	online	online	NOUN
eurjchem-769	6	5	:	:	PUNCT
eurjchem-769	6	6	31	31	NUM
eurjchem-769	6	7	december	december	PROPN
eurjchem-769	6	8	2013	2013	NUM
eurjchem-769	6	9	keywords	keyword	VERB
eurjchem-769	6	10	multi	multi	ADJ
eurjchem-769	6	11	component	component	NOUN
eurjchem-769	6	12	,	,	PUNCT
eurjchem-769	6	13	one	one	NUM
eurjchem-769	6	14	pot	pot	NOUN
eurjchem-769	6	15	synthesis	synthesis	NOUN
eurjchem-769	6	16	of	of	ADP
eurjchem-769	6	17	various	various	ADJ
eurjchem-769	6	18	dihydropyrano[2,3‐c]pyrazole	dihydropyrano[2,3‐c]pyrazole	ADJ
eurjchem-769	6	19	derivatives	derivative	NOUN
eurjchem-769	6	20	from	from	ADP
eurjchem-769	6	21	the	the	DET
eurjchem-769	6	22	condensation	condensation	NOUN
eurjchem-769	6	23	of	of	ADP
eurjchem-769	6	24	ethyl	ethyl	PROPN
eurjchem-769	6	25	acetoacetate	acetoacetate	NOUN
eurjchem-769	6	26	,	,	PUNCT
eurjchem-769	6	27	hydrazine	hydrazine	NOUN
eurjchem-769	6	28	,	,	PUNCT
eurjchem-769	6	29	aromatic	aromatic	ADJ
eurjchem-769	6	30	aldehyde	aldehyde	NOUN
eurjchem-769	6	31	and	and	CCONJ
eurjchem-769	6	32	malononitrile	malononitrile	NOUN
eurjchem-769	6	33	has	have	AUX
eurjchem-769	6	34	been	be	AUX
eurjchem-769	6	35	described	describe	VERB
eurjchem-769	6	36	using	use	VERB
eurjchem-769	6	37	glycerol	glycerol	NOUN
eurjchem-769	6	38	,	,	PUNCT
eurjchem-769	6	39	as	as	ADP
eurjchem-769	6	40	environmentally	environmentally	ADV
eurjchem-769	6	41	benign	benign	ADJ
eurjchem-769	6	42	,	,	PUNCT
eurjchem-769	6	43	economical	economical	ADJ
eurjchem-769	6	44	,	,	PUNCT
eurjchem-769	6	45	and	and	CCONJ
eurjchem-769	6	46	easily	easily	ADV
eurjchem-769	6	47	available	available	ADJ
eurjchem-769	6	48	solvent	solvent	NOUN
eurjchem-769	6	49	.	.	PUNCT
eurjchem-769	7	1	the	the	DET
eurjchem-769	7	2	targeted	target	VERB
eurjchem-769	7	3	molecules	molecule	NOUN
eurjchem-769	7	4	are	be	AUX
eurjchem-769	7	5	obtained	obtain	VERB
eurjchem-769	7	6	in	in	ADP
eurjchem-769	7	7	excellent	excellent	ADJ
eurjchem-769	7	8	yield	yield	NOUN
eurjchem-769	7	9	without	without	ADP
eurjchem-769	7	10	use	use	NOUN
eurjchem-769	7	11	of	of	ADP
eurjchem-769	7	12	any	any	DET
eurjchem-769	7	13	additional	additional	ADJ
eurjchem-769	7	14	catalyst	catalyst	NOUN
eurjchem-769	7	15	.	.	PUNCT
eurjchem-769	8	1	glycerol	glycerol	NOUN
eurjchem-769	8	2	aldehydes	aldehyde	NOUN
eurjchem-769	8	3	catalyst	catalyst	NOUN
eurjchem-769	8	4	free	free	ADJ
eurjchem-769	8	5	malononitrile	malononitrile	NOUN
eurjchem-769	8	6	pyrazol‐5‐one	pyrazol‐5‐one	NUM
eurjchem-769	8	7	dihydropyrano[2,3‐c]pyrazole	dihydropyrano[2,3‐c]pyrazole	NOUN
eurjchem-769	8	8	1	1	NUM
eurjchem-769	8	9	.	.	X
eurjchem-769	9	1	introduction	introduction	NOUN
eurjchem-769	9	2	the	the	DET
eurjchem-769	9	3	development	development	NOUN
eurjchem-769	9	4	of	of	ADP
eurjchem-769	9	5	green	green	ADJ
eurjchem-769	9	6	methodologies	methodology	NOUN
eurjchem-769	9	7	with	with	ADP
eurjchem-769	9	8	the	the	DET
eurjchem-769	9	9	choice	choice	NOUN
eurjchem-769	9	10	of	of	ADP
eurjchem-769	9	11	green	green	ADJ
eurjchem-769	9	12	solvents	solvent	NOUN
eurjchem-769	9	13	and	and	CCONJ
eurjchem-769	9	14	solvents	solvent	NOUN
eurjchem-769	9	15	from	from	ADP
eurjchem-769	9	16	renewable	renewable	ADJ
eurjchem-769	9	17	resources	resource	NOUN
eurjchem-769	9	18	has	have	AUX
eurjchem-769	9	19	gained	gain	VERB
eurjchem-769	9	20	much	much	ADJ
eurjchem-769	9	21	interest	interest	NOUN
eurjchem-769	9	22	in	in	ADP
eurjchem-769	9	23	recent	recent	ADJ
eurjchem-769	9	24	years	year	NOUN
eurjchem-769	10	1	[	[	X
eurjchem-769	10	2	1‐5	1‐5	X
eurjchem-769	10	3	]	]	PUNCT
eurjchem-769	10	4	.	.	PUNCT
eurjchem-769	11	1	with	with	ADP
eurjchem-769	11	2	this	this	DET
eurjchem-769	11	3	concern	concern	NOUN
eurjchem-769	11	4	,	,	PUNCT
eurjchem-769	11	5	use	use	NOUN
eurjchem-769	11	6	of	of	ADP
eurjchem-769	11	7	water	water	NOUN
eurjchem-769	11	8	has	have	AUX
eurjchem-769	11	9	attracted	attract	VERB
eurjchem-769	11	10	much	much	ADJ
eurjchem-769	11	11	attention	attention	NOUN
eurjchem-769	11	12	[	[	X
eurjchem-769	11	13	6‐11	6‐11	NUM
eurjchem-769	11	14	]	]	X
eurjchem-769	11	15	,	,	PUNCT
eurjchem-769	11	16	however	however	ADV
eurjchem-769	11	17	water	water	NOUN
eurjchem-769	11	18	based	base	VERB
eurjchem-769	11	19	processes	process	NOUN
eurjchem-769	11	20	are	be	AUX
eurjchem-769	11	21	still	still	ADV
eurjchem-769	11	22	subject	subject	ADJ
eurjchem-769	11	23	to	to	ADP
eurjchem-769	11	24	limitations	limitation	NOUN
eurjchem-769	11	25	due	due	ADP
eurjchem-769	11	26	to	to	ADP
eurjchem-769	11	27	solubility	solubility	NOUN
eurjchem-769	11	28	problems	problem	NOUN
eurjchem-769	11	29	of	of	ADP
eurjchem-769	11	30	highly	highly	ADV
eurjchem-769	11	31	hydrophobic	hydrophobic	NOUN
eurjchem-769	11	32	substrates	substrate	NOUN
eurjchem-769	11	33	.	.	PUNCT
eurjchem-769	12	1	on	on	ADP
eurjchem-769	12	2	the	the	DET
eurjchem-769	12	3	other	other	ADJ
eurjchem-769	12	4	hand	hand	NOUN
eurjchem-769	12	5	,	,	PUNCT
eurjchem-769	12	6	excellent	excellent	ADJ
eurjchem-769	12	7	solvent	solvent	NOUN
eurjchem-769	12	8	properties	property	NOUN
eurjchem-769	12	9	like	like	ADP
eurjchem-769	12	10	low	low	ADJ
eurjchem-769	12	11	toxicity	toxicity	NOUN
eurjchem-769	12	12	(	(	PUNCT
eurjchem-769	12	13	ld50	ld50	PROPN
eurjchem-769	12	14	(	(	PUNCT
eurjchem-769	12	15	oral	oral	ADJ
eurjchem-769	12	16	rat	rat	NOUN
eurjchem-769	12	17	)	)	PUNCT
eurjchem-769	12	18	12600	12600	NUM
eurjchem-769	12	19	mg	mg	PROPN
eurjchem-769	12	20	/	/	SYM
eurjchem-769	12	21	kg	kg	PROPN
eurjchem-769	12	22	)	)	PUNCT
eurjchem-769	12	23	,	,	PUNCT
eurjchem-769	12	24	biodegradability	biodegradability	NOUN
eurjchem-769	12	25	,	,	PUNCT
eurjchem-769	12	26	low‐flammability	low‐flammability	NOUN
eurjchem-769	12	27	,	,	PUNCT
eurjchem-769	12	28	long	long	ADJ
eurjchem-769	12	29	liquid	liquid	ADJ
eurjchem-769	12	30	range	range	NOUN
eurjchem-769	12	31	(	(	PUNCT
eurjchem-769	12	32	boiling	boiling	NOUN
eurjchem-769	12	33	point	point	NOUN
eurjchem-769	12	34	290	290	NUM
eurjchem-769	12	35	°	°	NOUN
eurjchem-769	12	36	c	c	NOUN
eurjchem-769	12	37	)	)	PUNCT
eurjchem-769	12	38	,	,	PUNCT
eurjchem-769	12	39	low	low	ADJ
eurjchem-769	12	40	vapor	vapor	NOUN
eurjchem-769	12	41	pressure	pressure	NOUN
eurjchem-769	12	42	and	and	CCONJ
eurjchem-769	12	43	solubility	solubility	NOUN
eurjchem-769	12	44	of	of	ADP
eurjchem-769	12	45	polar	polar	ADJ
eurjchem-769	12	46	organic	organic	ADJ
eurjchem-769	12	47	compounds	compound	NOUN
eurjchem-769	12	48	made	make	VERB
eurjchem-769	12	49	the	the	DET
eurjchem-769	12	50	glycerol	glycerol	NOUN
eurjchem-769	12	51	an	an	DET
eurjchem-769	12	52	excellent	excellent	ADJ
eurjchem-769	12	53	option	option	NOUN
eurjchem-769	12	54	to	to	PART
eurjchem-769	12	55	use	use	VERB
eurjchem-769	12	56	as	as	ADV
eurjchem-769	12	57	solvent	solvent	NOUN
eurjchem-769	12	58	for	for	ADP
eurjchem-769	12	59	organic	organic	ADJ
eurjchem-769	12	60	synthesis	synthesis	NOUN
eurjchem-769	12	61	[	[	X
eurjchem-769	12	62	12	12	NUM
eurjchem-769	12	63	]	]	PUNCT
eurjchem-769	12	64	.	.	PUNCT
eurjchem-769	13	1	further	far	ADV
eurjchem-769	13	2	with	with	ADP
eurjchem-769	13	3	the	the	DET
eurjchem-769	13	4	present	present	ADJ
eurjchem-769	13	5	emphasis	emphasis	NOUN
eurjchem-769	13	6	and	and	CCONJ
eurjchem-769	13	7	increasing	increase	VERB
eurjchem-769	13	8	demand	demand	NOUN
eurjchem-769	13	9	of	of	ADP
eurjchem-769	13	10	biodiesel	biodiesel	NOUN
eurjchem-769	13	11	,	,	PUNCT
eurjchem-769	13	12	which	which	PRON
eurjchem-769	13	13	is	be	AUX
eurjchem-769	13	14	responsible	responsible	ADJ
eurjchem-769	13	15	for	for	ADP
eurjchem-769	13	16	the	the	DET
eurjchem-769	13	17	excess	excess	ADJ
eurjchem-769	13	18	production	production	NOUN
eurjchem-769	13	19	of	of	ADP
eurjchem-769	13	20	glycerol	glycerol	NOUN
eurjchem-769	13	21	as	as	ADP
eurjchem-769	13	22	by‐product	by‐product	NOUN
eurjchem-769	13	23	,	,	PUNCT
eurjchem-769	13	24	triggered	trigger	VERB
eurjchem-769	13	25	the	the	DET
eurjchem-769	13	26	discovery	discovery	NOUN
eurjchem-769	13	27	of	of	ADP
eurjchem-769	13	28	processes	process	NOUN
eurjchem-769	13	29	that	that	PRON
eurjchem-769	13	30	use	use	VERB
eurjchem-769	13	31	glycerol	glycerol	NOUN
eurjchem-769	13	32	for	for	ADP
eurjchem-769	13	33	the	the	DET
eurjchem-769	13	34	synthesis	synthesis	NOUN
eurjchem-769	13	35	of	of	ADP
eurjchem-769	13	36	value	value	NOUN
eurjchem-769	13	37	added	add	VERB
eurjchem-769	13	38	chemicals	chemical	NOUN
eurjchem-769	13	39	,	,	PUNCT
eurjchem-769	13	40	as	as	ADP
eurjchem-769	13	41	reaction	reaction	NOUN
eurjchem-769	13	42	medium	medium	NOUN
eurjchem-769	13	43	and	and	CCONJ
eurjchem-769	13	44	for	for	ADP
eurjchem-769	13	45	other	other	ADJ
eurjchem-769	13	46	applications	application	NOUN
eurjchem-769	13	47	[	[	X
eurjchem-769	13	48	13‐19	13‐19	NUM
eurjchem-769	13	49	]	]	PUNCT
eurjchem-769	13	50	.	.	PUNCT
eurjchem-769	14	1	recently	recently	ADV
eurjchem-769	14	2	glycerol	glycerol	NOUN
eurjchem-769	14	3	has	have	AUX
eurjchem-769	14	4	been	be	AUX
eurjchem-769	14	5	used	use	VERB
eurjchem-769	14	6	for	for	ADP
eurjchem-769	14	7	heck	heck	NOUN
eurjchem-769	14	8	and	and	CCONJ
eurjchem-769	14	9	suzuki	suzuki	PROPN
eurjchem-769	14	10	coupling	coupling	NOUN
eurjchem-769	15	1	[	[	X
eurjchem-769	15	2	20‐22	20‐22	NUM
eurjchem-769	15	3	]	]	PUNCT
eurjchem-769	15	4	,	,	PUNCT
eurjchem-769	15	5	michael	michael	PROPN
eurjchem-769	15	6	addition	addition	NOUN
eurjchem-769	15	7	[	[	X
eurjchem-769	15	8	23	23	NUM
eurjchem-769	15	9	]	]	PUNCT
eurjchem-769	15	10	,	,	PUNCT
eurjchem-769	15	11	fridel‐crafts	fridel‐craft	NOUN
eurjchem-769	15	12	type	type	NOUN
eurjchem-769	15	13	addition	addition	NOUN
eurjchem-769	15	14	,	,	PUNCT
eurjchem-769	15	15	epoxide	epoxide	NOUN
eurjchem-769	15	16	ring	ring	NOUN
eurjchem-769	15	17	opening	opening	NOUN
eurjchem-769	15	18	[	[	X
eurjchem-769	15	19	24	24	NUM
eurjchem-769	15	20	]	]	PUNCT
eurjchem-769	15	21	,	,	PUNCT
eurjchem-769	15	22	synthesis	synthesis	NOUN
eurjchem-769	15	23	of	of	ADP
eurjchem-769	15	24	xanthenes	xanthene	NOUN
eurjchem-769	15	25	[	[	X
eurjchem-769	15	26	25	25	NUM
eurjchem-769	15	27	]	]	PUNCT
eurjchem-769	15	28	and	and	CCONJ
eurjchem-769	15	29	very	very	ADV
eurjchem-769	15	30	recently	recently	ADV
eurjchem-769	15	31	for	for	ADP
eurjchem-769	15	32	the	the	DET
eurjchem-769	15	33	production	production	NOUN
eurjchem-769	15	34	of	of	ADP
eurjchem-769	15	35	benzodiazepines	benzodiazepine	NOUN
eurjchem-769	15	36	and	and	CCONJ
eurjchem-769	15	37	octahydroacridines	octahydroacridine	NOUN
eurjchem-769	15	38	[	[	X
eurjchem-769	15	39	26,27	26,27	NUM
eurjchem-769	15	40	]	]	PUNCT
eurjchem-769	15	41	.	.	PUNCT
eurjchem-769	16	1	in	in	ADP
eurjchem-769	16	2	addition	addition	NOUN
eurjchem-769	16	3	,	,	PUNCT
eurjchem-769	16	4	pyranopyrazoles	pyranopyrazole	NOUN
eurjchem-769	16	5	are	be	AUX
eurjchem-769	16	6	important	important	ADJ
eurjchem-769	16	7	class	class	NOUN
eurjchem-769	16	8	of	of	ADP
eurjchem-769	16	9	heterocyclic	heterocyclic	ADJ
eurjchem-769	16	10	chemistry	chemistry	NOUN
eurjchem-769	16	11	.	.	PUNCT
eurjchem-769	17	1	compounds	compound	NOUN
eurjchem-769	17	2	containing	contain	VERB
eurjchem-769	17	3	pyranopyrazole	pyranopyrazole	ADJ
eurjchem-769	17	4	scaffold	scaffold	NOUN
eurjchem-769	17	5	are	be	AUX
eurjchem-769	17	6	biological	biological	ADJ
eurjchem-769	17	7	active	active	ADJ
eurjchem-769	17	8	and	and	CCONJ
eurjchem-769	17	9	have	have	VERB
eurjchem-769	17	10	applications	application	NOUN
eurjchem-769	17	11	as	as	ADP
eurjchem-769	17	12	pharmaceutical	pharmaceutical	ADJ
eurjchem-769	17	13	ingredients	ingredient	NOUN
eurjchem-769	17	14	and	and	CCONJ
eurjchem-769	17	15	biodegradable	biodegradable	ADJ
eurjchem-769	17	16	agrochemicals	agrochemical	NOUN
eurjchem-769	17	17	[	[	X
eurjchem-769	17	18	28‐31	28‐31	X
eurjchem-769	17	19	]	]	X
eurjchem-769	17	20	.	.	PUNCT
eurjchem-769	18	1	pyrano[2,3‐c]pyrazole	pyrano[2,3‐c]pyrazole	NOUN
eurjchem-769	18	2	derivatives	derivative	NOUN
eurjchem-769	18	3	show	show	VERB
eurjchem-769	18	4	many	many	ADJ
eurjchem-769	18	5	bioacti‐	bioacti‐	NOUN
eurjchem-769	18	6	vities	vitie	NOUN
eurjchem-769	18	7	such	such	ADJ
eurjchem-769	18	8	as	as	ADP
eurjchem-769	18	9	antimicrobial	antimicrobial	ADJ
eurjchem-769	18	10	[	[	X
eurjchem-769	18	11	32	32	NUM
eurjchem-769	18	12	]	]	PUNCT
eurjchem-769	18	13	,	,	PUNCT
eurjchem-769	18	14	insecticidal	insecticidal	NOUN
eurjchem-769	18	15	[	[	X
eurjchem-769	18	16	33	33	NUM
eurjchem-769	18	17	]	]	PUNCT
eurjchem-769	18	18	,	,	PUNCT
eurjchem-769	18	19	anti‐inflam‐	anti‐inflam‐	X
eurjchem-769	18	20	matory	matory	ADJ
eurjchem-769	18	21	activities	activity	NOUN
eurjchem-769	18	22	[	[	X
eurjchem-769	18	23	34	34	NUM
eurjchem-769	18	24	]	]	PUNCT
eurjchem-769	18	25	and	and	CCONJ
eurjchem-769	18	26	molluscicidal	molluscicidal	ADJ
eurjchem-769	18	27	activity	activity	NOUN
eurjchem-769	18	28	[	[	X
eurjchem-769	18	29	35,36	35,36	NUM
eurjchem-769	18	30	]	]	PUNCT
eurjchem-769	18	31	.	.	PUNCT
eurjchem-769	19	1	pyrano[2,3‐c]pyrazoles	pyrano[2,3‐c]pyrazole	NOUN
eurjchem-769	19	2	are	be	AUX
eurjchem-769	19	3	known	know	VERB
eurjchem-769	19	4	have	have	VERB
eurjchem-769	19	5	application	application	NOUN
eurjchem-769	19	6	in	in	ADP
eurjchem-769	19	7	screening	screen	VERB
eurjchem-769	19	8	kit	kit	NOUN
eurjchem-769	19	9	for	for	ADP
eurjchem-769	19	10	chk1	chk1	PROPN
eurjchem-769	19	11	kinase	kinase	PROPN
eurjchem-769	19	12	inhibitor	inhibitor	NOUN
eurjchem-769	20	1	[	[	X
eurjchem-769	20	2	37,38	37,38	X
eurjchem-769	20	3	]	]	PUNCT
eurjchem-769	20	4	and	and	CCONJ
eurjchem-769	20	5	also	also	ADV
eurjchem-769	20	6	used	use	VERB
eurjchem-769	20	7	as	as	ADP
eurjchem-769	20	8	photoactive	photoactive	ADJ
eurjchem-769	20	9	material	material	NOUN
eurjchem-769	20	10	[	[	X
eurjchem-769	20	11	39	39	NUM
eurjchem-769	20	12	]	]	PUNCT
eurjchem-769	20	13	.	.	PUNCT
eurjchem-769	21	1	these	these	DET
eurjchem-769	21	2	molecules	molecule	NOUN
eurjchem-769	21	3	can	can	AUX
eurjchem-769	21	4	be	be	AUX
eurjchem-769	21	5	synthesized	synthesize	VERB
eurjchem-769	21	6	by	by	ADP
eurjchem-769	21	7	the	the	DET
eurjchem-769	21	8	reaction	reaction	NOUN
eurjchem-769	21	9	of	of	ADP
eurjchem-769	21	10	pyrazol‐5‐one	pyrazol‐5‐one	NUM
eurjchem-769	21	11	with	with	ADP
eurjchem-769	21	12	tetracyanoethylene	tetracyanoethylene	NOUN
eurjchem-769	21	13	[	[	X
eurjchem-769	21	14	28	28	NUM
eurjchem-769	21	15	]	]	PUNCT
eurjchem-769	21	16	,	,	PUNCT
eurjchem-769	21	17	arylidene	arylidene	NOUN
eurjchem-769	21	18	malononitrile	malononitrile	NOUN
eurjchem-769	21	19	using	use	VERB
eurjchem-769	21	20	catalysts	catalyst	NOUN
eurjchem-769	21	21	like	like	ADP
eurjchem-769	21	22	tea	tea	NOUN
eurjchem-769	21	23	[	[	X
eurjchem-769	21	24	29‐31	29‐31	X
eurjchem-769	21	25	]	]	PUNCT
eurjchem-769	21	26	.	.	PUNCT
eurjchem-769	22	1	in	in	ADP
eurjchem-769	22	2	addition	addition	NOUN
eurjchem-769	22	3	multi‐component	multi‐component	NOUN
eurjchem-769	22	4	procedures	procedure	NOUN
eurjchem-769	22	5	have	have	AUX
eurjchem-769	22	6	been	be	AUX
eurjchem-769	22	7	developed	develop	VERB
eurjchem-769	22	8	using	use	VERB
eurjchem-769	22	9	catalysts	catalyst	NOUN
eurjchem-769	22	10	like	like	ADP
eurjchem-769	22	11	dbsa	dbsa	NOUN
eurjchem-769	22	12	[	[	X
eurjchem-769	22	13	40	40	NUM
eurjchem-769	22	14	]	]	PUNCT
eurjchem-769	22	15	,	,	PUNCT
eurjchem-769	22	16	mgo	mgo	PROPN
eurjchem-769	23	1	[	[	X
eurjchem-769	23	2	41	41	NUM
eurjchem-769	23	3	]	]	PUNCT
eurjchem-769	23	4	,	,	PUNCT
eurjchem-769	23	5	imidazole	imidazole	NOUN
eurjchem-769	24	1	[	[	X
eurjchem-769	24	2	42	42	NUM
eurjchem-769	24	3	]	]	PUNCT
eurjchem-769	24	4	,	,	PUNCT
eurjchem-769	24	5	β‐	β‐	ADJ
eurjchem-769	24	6	cyclodextrin	cyclodextrin	NOUN
eurjchem-769	25	1	[	[	X
eurjchem-769	25	2	43	43	NUM
eurjchem-769	25	3	]	]	PUNCT
eurjchem-769	25	4	,	,	PUNCT
eurjchem-769	25	5	ba(oh)2	ba(oh)2	NOUN
eurjchem-769	25	6	[	[	X
eurjchem-769	25	7	44	44	NUM
eurjchem-769	25	8	]	]	PUNCT
eurjchem-769	25	9	.	.	PUNCT
eurjchem-769	26	1	the	the	DET
eurjchem-769	26	2	already	already	ADV
eurjchem-769	26	3	reported	report	VERB
eurjchem-769	26	4	procedures	procedure	NOUN
eurjchem-769	26	5	have	have	VERB
eurjchem-769	26	6	many	many	ADJ
eurjchem-769	26	7	advantages	advantage	NOUN
eurjchem-769	26	8	over	over	ADP
eurjchem-769	26	9	one	one	NUM
eurjchem-769	26	10	another	another	DET
eurjchem-769	26	11	,	,	PUNCT
eurjchem-769	26	12	but	but	CCONJ
eurjchem-769	26	13	few	few	ADJ
eurjchem-769	26	14	methods	method	NOUN
eurjchem-769	26	15	have	have	VERB
eurjchem-769	26	16	one	one	NUM
eurjchem-769	26	17	or	or	CCONJ
eurjchem-769	26	18	another	another	DET
eurjchem-769	26	19	drawback	drawback	NOUN
eurjchem-769	26	20	like	like	ADP
eurjchem-769	26	21	solubility	solubility	NOUN
eurjchem-769	26	22	of	of	ADP
eurjchem-769	26	23	reactants	reactant	NOUN
eurjchem-769	26	24	,	,	PUNCT
eurjchem-769	26	25	tedious	tedious	ADJ
eurjchem-769	26	26	work‐up	work‐up	ADJ
eurjchem-769	26	27	procedures	procedure	NOUN
eurjchem-769	26	28	and	and	CCONJ
eurjchem-769	26	29	hazardous	hazardous	ADJ
eurjchem-769	26	30	regents	regent	NOUN
eurjchem-769	26	31	or	or	CCONJ
eurjchem-769	26	32	solvents	solvent	NOUN
eurjchem-769	26	33	.	.	PUNCT
eurjchem-769	27	1	therefore	therefore	ADV
eurjchem-769	27	2	,	,	PUNCT
eurjchem-769	27	3	development	development	NOUN
eurjchem-769	27	4	of	of	ADP
eurjchem-769	27	5	clean	clean	ADJ
eurjchem-769	27	6	and	and	CCONJ
eurjchem-769	27	7	efficient	efficient	ADJ
eurjchem-769	27	8	procedure	procedure	NOUN
eurjchem-769	27	9	for	for	ADP
eurjchem-769	27	10	the	the	DET
eurjchem-769	27	11	synthesis	synthesis	NOUN
eurjchem-769	27	12	of	of	ADP
eurjchem-769	27	13	dihydropyrano[2,3‐c]pyrazoles	dihydropyrano[2,3‐c]pyrazole	NOUN
eurjchem-769	27	14	is	be	AUX
eurjchem-769	27	15	still	still	ADV
eurjchem-769	27	16	timely	timely	ADJ
eurjchem-769	27	17	.	.	PUNCT
eurjchem-769	28	1	in	in	ADP
eurjchem-769	28	2	the	the	DET
eurjchem-769	28	3	present	present	ADJ
eurjchem-769	28	4	paper	paper	NOUN
eurjchem-769	28	5	,	,	PUNCT
eurjchem-769	28	6	we	we	PRON
eurjchem-769	28	7	have	have	AUX
eurjchem-769	28	8	described	describe	VERB
eurjchem-769	28	9	a	a	DET
eurjchem-769	28	10	catalyst	catalyst	NOUN
eurjchem-769	28	11	free	free	ADJ
eurjchem-769	28	12	,	,	PUNCT
eurjchem-769	28	13	one	one	NUM
eurjchem-769	28	14	pot	pot	NOUN
eurjchem-769	28	15	,	,	PUNCT
eurjchem-769	28	16	multicomponent	multicomponent	NOUN
eurjchem-769	28	17	protocol	protocol	NOUN
eurjchem-769	28	18	for	for	ADP
eurjchem-769	28	19	the	the	DET
eurjchem-769	28	20	synthesis	synthesis	NOUN
eurjchem-769	28	21	of	of	ADP
eurjchem-769	28	22	dihydropyrano[2,3‐c]pyrazoles	dihydropyrano[2,3‐c]pyrazole	NOUN
eurjchem-769	28	23	using	use	VERB
eurjchem-769	28	24	glycerol	glycerol	NOUN
eurjchem-769	28	25	as	as	ADP
eurjchem-769	28	26	an	an	DET
eurjchem-769	28	27	economical	economical	ADJ
eurjchem-769	28	28	,	,	PUNCT
eurjchem-769	28	29	easily	easily	ADV
eurjchem-769	28	30	available	available	ADJ
eurjchem-769	28	31	and	and	CCONJ
eurjchem-769	28	32	environment	environment	VERB
eurjchem-769	28	33	friendly	friendly	ADJ
eurjchem-769	28	34	solvent	solvent	NOUN
eurjchem-769	28	35	(	(	PUNCT
eurjchem-769	28	36	scheme	scheme	NOUN
eurjchem-769	28	37	1	1	NUM
eurjchem-769	28	38	)	)	PUNCT
eurjchem-769	28	39	.	.	PUNCT
eurjchem-769	29	1	2	2	X
eurjchem-769	29	2	.	.	X
eurjchem-769	29	3	experimental	experimental	ADJ
eurjchem-769	29	4	2.1	2.1	NUM
eurjchem-769	29	5	.	.	PUNCT
eurjchem-769	30	1	instrumentation	instrumentation	NOUN
eurjchem-769	30	2	materials	material	NOUN
eurjchem-769	30	3	were	be	AUX
eurjchem-769	30	4	obtained	obtain	VERB
eurjchem-769	30	5	from	from	ADP
eurjchem-769	30	6	commercial	commercial	ADJ
eurjchem-769	30	7	suppliers	supplier	NOUN
eurjchem-769	30	8	and	and	CCONJ
eurjchem-769	30	9	were	be	AUX
eurjchem-769	30	10	used	use	VERB
eurjchem-769	30	11	without	without	ADP
eurjchem-769	30	12	further	further	ADJ
eurjchem-769	30	13	purifications	purification	NOUN
eurjchem-769	30	14	.	.	PUNCT
eurjchem-769	31	1	melting	melt	VERB
eurjchem-769	31	2	points	point	NOUN
eurjchem-769	31	3	were	be	AUX
eurjchem-769	31	4	recorded	record	VERB
eurjchem-769	31	5	in	in	ADP
eurjchem-769	31	6	open	open	ADJ
eurjchem-769	31	7	end	end	NOUN
eurjchem-769	31	8	capillaries	capillary	NOUN
eurjchem-769	31	9	and	and	CCONJ
eurjchem-769	31	10	are	be	AUX
eurjchem-769	31	11	uncorrected	uncorrecte	VERB
eurjchem-769	31	12	.	.	PUNCT
eurjchem-769	32	1	1h	1h	NUM
eurjchem-769	32	2	nmr	nmr	PROPN
eurjchem-769	32	3	spectra	spectra	NOUN
eurjchem-769	32	4	were	be	AUX
eurjchem-769	32	5	recorded	record	VERB
eurjchem-769	32	6	in	in	ADP
eurjchem-769	32	7	cdcl3	cdcl3	NOUN
eurjchem-769	32	8	solution	solution	NOUN
eurjchem-769	32	9	on	on	ADP
eurjchem-769	32	10	a	a	DET
eurjchem-769	32	11	bruker	bruker	PROPN
eurjchem-769	32	12	avance	avance	PROPN
eurjchem-769	32	13	ii	ii	PROPN
eurjchem-769	32	14	400	400	NUM
eurjchem-769	32	15	mhz	mhz	NOUN
eurjchem-769	32	16	spectrometer	spectrometer	NOUN
eurjchem-769	32	17	;	;	PUNCT
eurjchem-769	32	18	chemical	chemical	NOUN
eurjchem-769	32	19	shifts	shift	NOUN
eurjchem-769	32	20	(	(	PUNCT
eurjchem-769	32	21	δ	δ	NOUN
eurjchem-769	32	22	)	)	PUNCT
eurjchem-769	32	23	are	be	AUX
eurjchem-769	32	24	reported	report	VERB
eurjchem-769	32	25	in	in	ADP
eurjchem-769	32	26	ppm	ppm	ADJ
eurjchem-769	32	27	relative	relative	ADJ
eurjchem-769	32	28	to	to	ADP
eurjchem-769	32	29	tms	tms	PROPN
eurjchem-769	32	30	as	as	ADP
eurjchem-769	32	31	internal	internal	ADJ
eurjchem-769	32	32	standard	standard	NOUN
eurjchem-769	32	33	.	.	PUNCT
eurjchem-769	33	1	the	the	DET
eurjchem-769	33	2	ir	ir	PROPN
eurjchem-769	33	3	spectra	spectra	PROPN
eurjchem-769	33	4	were	be	AUX
eurjchem-769	33	5	recorded	record	VERB
eurjchem-769	33	6	at	at	ADP
eurjchem-769	33	7	perkin‐elmer	perkin‐elmer	PROPN
eurjchem-769	33	8	spectrum	spectrum	PROPN
eurjchem-769	33	9	ii	ii	PROPN
eurjchem-769	33	10	infra‐red	infra‐re	VERB
eurjchem-769	33	11	spectrophoto‐	spectrophoto‐	PROPN
eurjchem-769	33	12	meter	meter	NOUN
eurjchem-769	33	13	.	.	PUNCT
eurjchem-769	34	1	2.2	2.2	NUM
eurjchem-769	34	2	.	.	PUNCT
eurjchem-769	34	3	synthesis	synthesis	NOUN
eurjchem-769	34	4	2.2.1	2.2.1	NUM
eurjchem-769	34	5	.	.	PUNCT
eurjchem-769	34	6	general	general	ADJ
eurjchem-769	34	7	procedure	procedure	NOUN
eurjchem-769	34	8	for	for	ADP
eurjchem-769	34	9	synthesis	synthesis	NOUN
eurjchem-769	34	10	of	of	ADP
eurjchem-769	34	11	6‐amino‐4‐(aryl)‐3‐	6‐amino‐4‐(aryl)‐3‐	NOUN
eurjchem-769	34	12	methyl‐1,4‐dihydropyrano[2,3‐c]pyrazole‐5‐carbonitrile	methyl‐1,4‐dihydropyrano[2,3‐c]pyrazole‐5‐carbonitrile	ADP
eurjchem-769	34	13	sohal	sohal	VERB
eurjchem-769	34	14	et	et	PROPN
eurjchem-769	34	15	al	al	PROPN
eurjchem-769	34	16	.	.	PUNCT
eurjchem-769	34	17	/	/	SYM
eurjchem-769	34	18	european	european	PROPN
eurjchem-769	34	19	journal	journal	PROPN
eurjchem-769	34	20	of	of	ADP
eurjchem-769	34	21	chemistry	chemistry	NOUN
eurjchem-769	34	22	4	4	NUM
eurjchem-769	34	23	(	(	PUNCT
eurjchem-769	34	24	4	4	NUM
eurjchem-769	34	25	)	)	PUNCT
eurjchem-769	34	26	(	(	PUNCT
eurjchem-769	34	27	2013	2013	NUM
eurjchem-769	34	28	)	)	PUNCT
eurjchem-769	35	1	450‐453	450‐453	NUM
eurjchem-769	35	2	451	451	NUM
eurjchem-769	35	3	scheme	scheme	NOUN
eurjchem-769	35	4	1	1	NUM
eurjchem-769	35	5	in	in	ADP
eurjchem-769	35	6	a	a	DET
eurjchem-769	35	7	conical	conical	ADJ
eurjchem-769	35	8	flask	flask	NOUN
eurjchem-769	35	9	,	,	PUNCT
eurjchem-769	35	10	hydrazine	hydrazine	NOUN
eurjchem-769	35	11	hydrate	hydrate	NOUN
eurjchem-769	35	12	(	(	PUNCT
eurjchem-769	35	13	1	1	NUM
eurjchem-769	35	14	mmol	mmol	NOUN
eurjchem-769	35	15	)	)	PUNCT
eurjchem-769	35	16	,	,	PUNCT
eurjchem-769	35	17	ethylacetoacetate	ethylacetoacetate	VERB
eurjchem-769	35	18	(	(	PUNCT
eurjchem-769	35	19	1	1	NUM
eurjchem-769	35	20	mmol	mmol	NOUN
eurjchem-769	35	21	)	)	PUNCT
eurjchem-769	35	22	,	,	PUNCT
eurjchem-769	35	23	aldehyde	aldehyde	NOUN
eurjchem-769	35	24	(	(	PUNCT
eurjchem-769	35	25	1	1	NUM
eurjchem-769	35	26	mmol	mmol	NOUN
eurjchem-769	35	27	)	)	PUNCT
eurjchem-769	35	28	and	and	CCONJ
eurjchem-769	35	29	malononitrile	malononitrile	NOUN
eurjchem-769	35	30	were	be	AUX
eurjchem-769	35	31	added	add	VERB
eurjchem-769	35	32	successively	successively	ADV
eurjchem-769	35	33	in	in	ADP
eurjchem-769	35	34	glycerol	glycerol	NOUN
eurjchem-769	35	35	(	(	PUNCT
eurjchem-769	35	36	2	2	NUM
eurjchem-769	35	37	ml	ml	NOUN
eurjchem-769	35	38	)	)	PUNCT
eurjchem-769	35	39	.	.	PUNCT
eurjchem-769	36	1	reaction	reaction	NOUN
eurjchem-769	36	2	mixture	mixture	NOUN
eurjchem-769	36	3	was	be	AUX
eurjchem-769	36	4	stirred	stir	VERB
eurjchem-769	36	5	at	at	ADP
eurjchem-769	36	6	80	80	NUM
eurjchem-769	36	7	°	°	NOUN
eurjchem-769	36	8	c	c	NOUN
eurjchem-769	36	9	.	.	PUNCT
eurjchem-769	37	1	after	after	ADP
eurjchem-769	37	2	the	the	DET
eurjchem-769	37	3	completion	completion	NOUN
eurjchem-769	37	4	of	of	ADP
eurjchem-769	37	5	reaction	reaction	NOUN
eurjchem-769	37	6	(	(	PUNCT
eurjchem-769	37	7	monitored	monitor	VERB
eurjchem-769	37	8	by	by	ADP
eurjchem-769	37	9	tlc	tlc	PROPN
eurjchem-769	37	10	)	)	PUNCT
eurjchem-769	37	11	,	,	PUNCT
eurjchem-769	37	12	diluted	dilute	VERB
eurjchem-769	37	13	the	the	DET
eurjchem-769	37	14	reaction	reaction	NOUN
eurjchem-769	37	15	mixture	mixture	NOUN
eurjchem-769	37	16	with	with	ADP
eurjchem-769	37	17	ice	ice	NOUN
eurjchem-769	37	18	cold	cold	ADJ
eurjchem-769	37	19	water	water	NOUN
eurjchem-769	37	20	.	.	PUNCT
eurjchem-769	38	1	filtered	filter	VERB
eurjchem-769	38	2	the	the	DET
eurjchem-769	38	3	solid	solid	ADJ
eurjchem-769	38	4	thus	thus	ADV
eurjchem-769	38	5	obtained	obtain	VERB
eurjchem-769	38	6	and	and	CCONJ
eurjchem-769	38	7	recrystallized	recrystallize	VERB
eurjchem-769	38	8	with	with	ADP
eurjchem-769	38	9	ethanol	ethanol	NOUN
eurjchem-769	38	10	(	(	PUNCT
eurjchem-769	38	11	scheme	scheme	NOUN
eurjchem-769	38	12	1	1	NUM
eurjchem-769	38	13	)	)	PUNCT
eurjchem-769	38	14	.	.	PUNCT
eurjchem-769	39	1	6‐amino‐5‐cyano‐3‐methyl‐4‐phenyl‐1,4‐dihydropyrano[2,3‐	6‐amino‐5‐cyano‐3‐methyl‐4‐phenyl‐1,4‐dihydropyrano[2,3‐	NUM
eurjchem-769	39	2	c]pyrazole	c]pyrazole	PROPN
eurjchem-769	39	3	(	(	PUNCT
eurjchem-769	39	4	5a	5a	NUM
eurjchem-769	39	5	):	):	PUNCT
eurjchem-769	39	6	color	color	NOUN
eurjchem-769	39	7	:	:	PUNCT
eurjchem-769	39	8	white	white	ADJ
eurjchem-769	39	9	crystals	crystal	NOUN
eurjchem-769	39	10	.	.	PUNCT
eurjchem-769	40	1	m.p	m.p	PROPN
eurjchem-769	40	2	.	.	PROPN
eurjchem-769	40	3	:	:	PUNCT
eurjchem-769	41	1	243‐245	243‐245	NUM
eurjchem-769	41	2	°	°	PROPN
eurjchem-769	41	3	c	c	X
eurjchem-769	41	4	.	.	PUNCT
eurjchem-769	42	1	ft‐ir	ft‐ir	NOUN
eurjchem-769	42	2	(	(	PUNCT
eurjchem-769	42	3	kbr	kbr	PROPN
eurjchem-769	42	4	,	,	PUNCT
eurjchem-769	42	5	ν	ν	PROPN
eurjchem-769	42	6	,	,	PUNCT
eurjchem-769	42	7	cm‐1	cm‐1	PROPN
eurjchem-769	42	8	):	):	PUNCT
eurjchem-769	42	9	3450	3450	NUM
eurjchem-769	42	10	,	,	PUNCT
eurjchem-769	42	11	3370	3370	NUM
eurjchem-769	42	12	,	,	PUNCT
eurjchem-769	42	13	3116	3116	NUM
eurjchem-769	42	14	,	,	PUNCT
eurjchem-769	42	15	2195	2195	NUM
eurjchem-769	42	16	,	,	PUNCT
eurjchem-769	42	17	1645	1645	NUM
eurjchem-769	42	18	,	,	PUNCT
eurjchem-769	42	19	1610	1610	NUM
eurjchem-769	42	20	,	,	PUNCT
eurjchem-769	42	21	1605	1605	NUM
eurjchem-769	42	22	,	,	PUNCT
eurjchem-769	42	23	1483	1483	NUM
eurjchem-769	42	24	,	,	PUNCT
eurjchem-769	42	25	1390	1390	NUM
eurjchem-769	42	26	,	,	PUNCT
eurjchem-769	42	27	1240	1240	NUM
eurjchem-769	42	28	,	,	PUNCT
eurjchem-769	42	29	1022	1022	NUM
eurjchem-769	42	30	,	,	PUNCT
eurjchem-769	42	31	860	860	NUM
eurjchem-769	42	32	.	.	PUNCT
eurjchem-769	43	1	1h	1h	NUM
eurjchem-769	43	2	nmr	nmr	NOUN
eurjchem-769	43	3	(	(	PUNCT
eurjchem-769	43	4	400	400	NUM
eurjchem-769	43	5	mhz	mhz	NOUN
eurjchem-769	43	6	,	,	PUNCT
eurjchem-769	43	7	cdcl3	cdcl3	PROPN
eurjchem-769	43	8	,	,	PUNCT
eurjchem-769	43	9	δ	δ	PROPN
eurjchem-769	43	10	,	,	PUNCT
eurjchem-769	43	11	ppm	ppm	NUM
eurjchem-769	43	12	):	):	PUNCT
eurjchem-769	43	13	1.80	1.80	NUM
eurjchem-769	43	14	(	(	PUNCT
eurjchem-769	43	15	s	s	PROPN
eurjchem-769	43	16	,	,	PUNCT
eurjchem-769	43	17	3h	3h	NUM
eurjchem-769	43	18	,	,	PUNCT
eurjchem-769	43	19	ch3	ch3	PROPN
eurjchem-769	43	20	)	)	PUNCT
eurjchem-769	43	21	,	,	PUNCT
eurjchem-769	43	22	4.62	4.62	NUM
eurjchem-769	43	23	(	(	PUNCT
eurjchem-769	43	24	s	s	PROPN
eurjchem-769	43	25	,	,	PUNCT
eurjchem-769	43	26	1h	1h	NUM
eurjchem-769	43	27	,	,	PUNCT
eurjchem-769	43	28	ch	ch	NOUN
eurjchem-769	43	29	)	)	PUNCT
eurjchem-769	43	30	,	,	PUNCT
eurjchem-769	43	31	6.95	6.95	NUM
eurjchem-769	43	32	(	(	PUNCT
eurjchem-769	43	33	s	s	NOUN
eurjchem-769	43	34	,	,	PUNCT
eurjchem-769	43	35	2h	2h	NUM
eurjchem-769	43	36	,	,	PUNCT
eurjchem-769	43	37	nh2	nh2	PROPN
eurjchem-769	43	38	)	)	PUNCT
eurjchem-769	43	39	,	,	PUNCT
eurjchem-769	43	40	7.16‐7.45	7.16‐7.45	NUM
eurjchem-769	43	41	(	(	PUNCT
eurjchem-769	43	42	m	m	PROPN
eurjchem-769	43	43	,	,	PUNCT
eurjchem-769	43	44	5h	5h	NUM
eurjchem-769	43	45	,	,	PUNCT
eurjchem-769	43	46	ar‐h	ar‐h	NOUN
eurjchem-769	43	47	)	)	PUNCT
eurjchem-769	43	48	,	,	PUNCT
eurjchem-769	43	49	12.16	12.16	NUM
eurjchem-769	43	50	(	(	PUNCT
eurjchem-769	43	51	br	br	PROPN
eurjchem-769	43	52	s	s	PROPN
eurjchem-769	43	53	,	,	PUNCT
eurjchem-769	43	54	1h	1h	NUM
eurjchem-769	43	55	,	,	PUNCT
eurjchem-769	43	56	nh	nh	PROPN
eurjchem-769	43	57	)	)	PUNCT
eurjchem-769	43	58	.	.	PUNCT
eurjchem-769	44	1	anal	anal	PROPN
eurjchem-769	44	2	.	.	PUNCT
eurjchem-769	44	3	calcd	calcd	NOUN
eurjchem-769	44	4	.	.	PUNCT
eurjchem-769	45	1	for	for	ADP
eurjchem-769	45	2	c14h12n4o	c14h12n4o	NOUN
eurjchem-769	45	3	:	:	PUNCT
eurjchem-769	45	4	c	c	X
eurjchem-769	45	5	,	,	PUNCT
eurjchem-769	45	6	66.65	66.65	NUM
eurjchem-769	45	7	;	;	PUNCT
eurjchem-769	45	8	h	h	NOUN
eurjchem-769	45	9	,	,	PUNCT
eurjchem-769	45	10	4.79	4.79	NUM
eurjchem-769	45	11	;	;	PUNCT
eurjchem-769	45	12	n	n	CCONJ
eurjchem-769	45	13	,	,	PUNCT
eurjchem-769	45	14	22.21	22.21	NUM
eurjchem-769	45	15	.	.	PUNCT
eurjchem-769	45	16	found	find	VERB
eurjchem-769	45	17	:	:	PUNCT
eurjchem-769	46	1	c	c	X
eurjchem-769	46	2	,	,	PUNCT
eurjchem-769	46	3	66.51	66.51	NUM
eurjchem-769	46	4	;	;	PUNCT
eurjchem-769	46	5	h	h	X
eurjchem-769	46	6	,	,	PUNCT
eurjchem-769	46	7	4.70	4.70	NUM
eurjchem-769	46	8	;	;	PUNCT
eurjchem-769	46	9	n	n	CCONJ
eurjchem-769	46	10	,	,	PUNCT
eurjchem-769	46	11	22.07	22.07	NUM
eurjchem-769	46	12	%	%	NOUN
eurjchem-769	46	13	.	.	PUNCT
eurjchem-769	47	1	6‐amino‐4‐(4‐chlorophenyl)‐3‐methyl‐1,4‐dihydropyrano[2	6‐amino‐4‐(4‐chlorophenyl)‐3‐methyl‐1,4‐dihydropyrano[2	NOUN
eurjchem-769	47	2	,	,	PUNCT
eurjchem-769	47	3	3‐c]pyrazole‐5‐carbonitrile	3‐c]pyrazole‐5‐carbonitrile	NUM
eurjchem-769	47	4	(	(	PUNCT
eurjchem-769	47	5	5b	5b	NUM
eurjchem-769	47	6	):	):	PUNCT
eurjchem-769	47	7	color	color	NOUN
eurjchem-769	47	8	:	:	PUNCT
eurjchem-769	47	9	white	white	ADJ
eurjchem-769	47	10	crystals	crystal	NOUN
eurjchem-769	47	11	.	.	PUNCT
eurjchem-769	48	1	m.p	m.p	PROPN
eurjchem-769	48	2	.	.	PROPN
eurjchem-769	48	3	:	:	PUNCT
eurjchem-769	49	1	233‐235	233‐235	NUM
eurjchem-769	49	2	°	°	SYM
eurjchem-769	49	3	c	c	NOUN
eurjchem-769	49	4	.	.	PUNCT
eurjchem-769	50	1	ft‐ir	ft‐ir	NOUN
eurjchem-769	50	2	(	(	PUNCT
eurjchem-769	50	3	kbr	kbr	PROPN
eurjchem-769	50	4	,	,	PUNCT
eurjchem-769	50	5	ν	ν	PROPN
eurjchem-769	50	6	,	,	PUNCT
eurjchem-769	50	7	cm‐1	cm‐1	PROPN
eurjchem-769	50	8	):	):	PUNCT
eurjchem-769	50	9	3490	3490	NUM
eurjchem-769	50	10	,	,	PUNCT
eurjchem-769	50	11	3253	3253	NUM
eurjchem-769	50	12	,	,	PUNCT
eurjchem-769	50	13	2930	2930	NUM
eurjchem-769	50	14	,	,	PUNCT
eurjchem-769	50	15	2260	2260	NUM
eurjchem-769	50	16	,	,	PUNCT
eurjchem-769	50	17	1650	1650	NUM
eurjchem-769	50	18	,	,	PUNCT
eurjchem-769	50	19	1610	1610	NUM
eurjchem-769	50	20	,	,	PUNCT
eurjchem-769	50	21	1508	1508	NUM
eurjchem-769	50	22	,	,	PUNCT
eurjchem-769	50	23	1399	1399	NUM
eurjchem-769	50	24	,	,	PUNCT
eurjchem-769	50	25	1270	1270	NUM
eurjchem-769	50	26	,	,	PUNCT
eurjchem-769	50	27	1200	1200	NUM
eurjchem-769	50	28	,	,	PUNCT
eurjchem-769	50	29	1050	1050	NUM
eurjchem-769	50	30	,	,	PUNCT
eurjchem-769	50	31	750	750	NUM
eurjchem-769	50	32	.	.	PUNCT
eurjchem-769	51	1	1h	1h	NUM
eurjchem-769	51	2	nmr	nmr	NOUN
eurjchem-769	51	3	(	(	PUNCT
eurjchem-769	51	4	400	400	NUM
eurjchem-769	51	5	mhz	mhz	NOUN
eurjchem-769	51	6	,	,	PUNCT
eurjchem-769	51	7	cdcl3	cdcl3	PROPN
eurjchem-769	51	8	,	,	PUNCT
eurjchem-769	51	9	δ	δ	PROPN
eurjchem-769	51	10	,	,	PUNCT
eurjchem-769	51	11	ppm	ppm	NUM
eurjchem-769	51	12	):	):	PUNCT
eurjchem-769	51	13	1.78	1.78	NUM
eurjchem-769	51	14	(	(	PUNCT
eurjchem-769	51	15	s	s	PROPN
eurjchem-769	51	16	,	,	PUNCT
eurjchem-769	51	17	3h	3h	NUM
eurjchem-769	51	18	,	,	PUNCT
eurjchem-769	51	19	ch3	ch3	PROPN
eurjchem-769	51	20	)	)	PUNCT
eurjchem-769	51	21	,	,	PUNCT
eurjchem-769	51	22	4.54	4.54	NUM
eurjchem-769	51	23	(	(	PUNCT
eurjchem-769	51	24	s	s	PROPN
eurjchem-769	51	25	,	,	PUNCT
eurjchem-769	51	26	1h	1h	NUM
eurjchem-769	51	27	,	,	PUNCT
eurjchem-769	51	28	ch	ch	NOUN
eurjchem-769	51	29	)	)	PUNCT
eurjchem-769	51	30	,	,	PUNCT
eurjchem-769	51	31	6.59	6.59	NUM
eurjchem-769	51	32	(	(	PUNCT
eurjchem-769	51	33	s	s	PROPN
eurjchem-769	51	34	,	,	PUNCT
eurjchem-769	51	35	2h	2h	NUM
eurjchem-769	51	36	,	,	PUNCT
eurjchem-769	51	37	nh2	nh2	PROPN
eurjchem-769	51	38	)	)	PUNCT
eurjchem-769	51	39	,	,	PUNCT
eurjchem-769	51	40	7.1‐7.2	7.1‐7.2	NUM
eurjchem-769	51	41	(	(	PUNCT
eurjchem-769	51	42	m	m	PROPN
eurjchem-769	51	43	,	,	PUNCT
eurjchem-769	51	44	4h	4h	NUM
eurjchem-769	51	45	,	,	PUNCT
eurjchem-769	51	46	ar‐h	ar‐h	PROPN
eurjchem-769	51	47	)	)	PUNCT
eurjchem-769	51	48	,	,	PUNCT
eurjchem-769	51	49	11.94	11.94	NUM
eurjchem-769	51	50	(	(	PUNCT
eurjchem-769	51	51	br	br	PROPN
eurjchem-769	51	52	s	s	PROPN
eurjchem-769	51	53	,	,	PUNCT
eurjchem-769	51	54	1h	1h	NUM
eurjchem-769	51	55	,	,	PUNCT
eurjchem-769	51	56	nh	nh	PROPN
eurjchem-769	51	57	)	)	PUNCT
eurjchem-769	51	58	.	.	PUNCT
eurjchem-769	52	1	anal	anal	PROPN
eurjchem-769	52	2	.	.	PUNCT
eurjchem-769	52	3	calcd	calcd	NOUN
eurjchem-769	52	4	.	.	PUNCT
eurjchem-769	53	1	for	for	SCONJ
eurjchem-769	53	2	c14h11n4clo	c14h11n4clo	ADP
eurjchem-769	53	3	:	:	PUNCT
eurjchem-769	53	4	c	c	X
eurjchem-769	53	5	,	,	PUNCT
eurjchem-769	53	6	58.65	58.65	NUM
eurjchem-769	53	7	;	;	PUNCT
eurjchem-769	53	8	h	h	NOUN
eurjchem-769	53	9	,	,	PUNCT
eurjchem-769	53	10	3.87	3.87	NUM
eurjchem-769	53	11	;	;	PUNCT
eurjchem-769	53	12	n	n	CCONJ
eurjchem-769	53	13	,	,	PUNCT
eurjchem-769	53	14	19.54	19.54	NUM
eurjchem-769	53	15	.	.	PUNCT
eurjchem-769	53	16	found	find	VERB
eurjchem-769	53	17	:	:	PUNCT
eurjchem-769	54	1	c	c	X
eurjchem-769	54	2	,	,	PUNCT
eurjchem-769	54	3	58.61	58.61	NUM
eurjchem-769	54	4	;	;	PUNCT
eurjchem-769	54	5	h	h	NOUN
eurjchem-769	54	6	,	,	PUNCT
eurjchem-769	54	7	3.80	3.80	NUM
eurjchem-769	54	8	;	;	PUNCT
eurjchem-769	54	9	n	n	CCONJ
eurjchem-769	54	10	,	,	PUNCT
eurjchem-769	54	11	19.51	19.51	NUM
eurjchem-769	54	12	%	%	NOUN
eurjchem-769	54	13	.	.	PUNCT
eurjchem-769	55	1	6‐amino‐3‐methyl‐4‐(3‐nitrophenyl)‐1,4‐dihydropyrano[2,3‐	6‐amino‐3‐methyl‐4‐(3‐nitrophenyl)‐1,4‐dihydropyrano[2,3‐	PROPN
eurjchem-769	56	1	c]pyrazole‐5‐carbonitrile	c]pyrazole‐5‐carbonitrile	NOUN
eurjchem-769	56	2	(	(	PUNCT
eurjchem-769	56	3	5f	5f	NOUN
eurjchem-769	56	4	):	):	PUNCT
eurjchem-769	56	5	color	color	NOUN
eurjchem-769	56	6	:	:	PUNCT
eurjchem-769	56	7	white	white	ADJ
eurjchem-769	56	8	crystals	crystal	NOUN
eurjchem-769	56	9	.	.	PUNCT
eurjchem-769	57	1	m.p	m.p	PROPN
eurjchem-769	57	2	.	.	PROPN
eurjchem-769	57	3	:	:	PUNCT
eurjchem-769	58	1	218‐	218‐	NUM
eurjchem-769	58	2	220	220	NUM
eurjchem-769	58	3	°	°	NOUN
eurjchem-769	58	4	c	c	NOUN
eurjchem-769	58	5	.	.	PUNCT
eurjchem-769	59	1	ft‐ir	ft‐ir	NOUN
eurjchem-769	59	2	(	(	PUNCT
eurjchem-769	59	3	kbr	kbr	PROPN
eurjchem-769	59	4	,	,	PUNCT
eurjchem-769	59	5	ν	ν	PROPN
eurjchem-769	59	6	,	,	PUNCT
eurjchem-769	59	7	cm‐1	cm‐1	PROPN
eurjchem-769	59	8	):	):	PUNCT
eurjchem-769	59	9	3510	3510	NUM
eurjchem-769	59	10	,	,	PUNCT
eurjchem-769	59	11	3260	3260	NUM
eurjchem-769	59	12	,	,	PUNCT
eurjchem-769	59	13	2945	2945	NUM
eurjchem-769	59	14	,	,	PUNCT
eurjchem-769	59	15	2332	2332	NUM
eurjchem-769	59	16	,	,	PUNCT
eurjchem-769	59	17	1670	1670	NUM
eurjchem-769	59	18	,	,	PUNCT
eurjchem-769	59	19	1620	1620	NUM
eurjchem-769	59	20	,	,	PUNCT
eurjchem-769	59	21	1525	1525	NUM
eurjchem-769	59	22	,	,	PUNCT
eurjchem-769	59	23	1410	1410	NUM
eurjchem-769	59	24	,	,	PUNCT
eurjchem-769	59	25	1283	1283	NUM
eurjchem-769	59	26	,	,	PUNCT
eurjchem-769	59	27	1225	1225	NUM
eurjchem-769	59	28	,	,	PUNCT
eurjchem-769	59	29	1100	1100	NUM
eurjchem-769	59	30	,	,	PUNCT
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eurjchem-769	59	35	1h	1h	NUM
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eurjchem-769	59	38	400	400	NUM
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eurjchem-769	59	40	,	,	PUNCT
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eurjchem-769	59	42	,	,	PUNCT
eurjchem-769	59	43	δ	δ	PROPN
eurjchem-769	59	44	,	,	PUNCT
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eurjchem-769	59	50	,	,	PUNCT
eurjchem-769	59	51	3h	3h	NUM
eurjchem-769	59	52	,	,	PUNCT
eurjchem-769	59	53	ch3	ch3	PROPN
eurjchem-769	59	54	)	)	PUNCT
eurjchem-769	59	55	,	,	PUNCT
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eurjchem-769	59	58	s	s	PROPN
eurjchem-769	59	59	,	,	PUNCT
eurjchem-769	59	60	1h	1h	NUM
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eurjchem-769	59	62	ch	ch	NOUN
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eurjchem-769	59	64	,	,	PUNCT
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eurjchem-769	59	67	s	s	PROPN
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eurjchem-769	59	73	,	,	PUNCT
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eurjchem-769	59	76	m	m	PROPN
eurjchem-769	59	77	,	,	PUNCT
eurjchem-769	59	78	4h	4h	NUM
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eurjchem-769	59	82	,	,	PUNCT
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eurjchem-769	59	85	br	br	PROPN
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eurjchem-769	59	88	1h	1h	NUM
eurjchem-769	59	89	,	,	PUNCT
eurjchem-769	59	90	nh	nh	PROPN
eurjchem-769	59	91	)	)	PUNCT
eurjchem-769	59	92	.	.	PUNCT
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eurjchem-769	60	2	.	.	PUNCT
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eurjchem-769	60	4	.	.	PUNCT
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eurjchem-769	61	2	c14h11n5o3	c14h11n5o3	PROPN
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eurjchem-769	61	4	c	c	X
eurjchem-769	61	5	,	,	PUNCT
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eurjchem-769	61	9	,	,	PUNCT
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eurjchem-769	61	11	;	;	PUNCT
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eurjchem-769	61	13	,	,	PUNCT
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eurjchem-769	62	2	,	,	PUNCT
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eurjchem-769	62	5	h	h	NOUN
eurjchem-769	62	6	,	,	PUNCT
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eurjchem-769	62	8	;	;	PUNCT
eurjchem-769	62	9	n	n	CCONJ
eurjchem-769	62	10	,	,	PUNCT
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eurjchem-769	62	13	.	.	PUNCT
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eurjchem-769	63	3	(	(	PUNCT
eurjchem-769	63	4	5h	5h	NOUN
eurjchem-769	63	5	):	):	PUNCT
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eurjchem-769	63	7	:	:	PUNCT
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eurjchem-769	64	2	.	.	PROPN
eurjchem-769	64	3	:	:	PUNCT
eurjchem-769	65	1	208‐210	208‐210	NUM
eurjchem-769	65	2	°	°	ADP
eurjchem-769	65	3	c	c	X
eurjchem-769	65	4	.	.	PUNCT
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eurjchem-769	66	4	,	,	PUNCT
eurjchem-769	66	5	ν	ν	PROPN
eurjchem-769	66	6	,	,	PUNCT
eurjchem-769	66	7	cm‐1	cm‐1	PROPN
eurjchem-769	66	8	):	):	PUNCT
eurjchem-769	66	9	3481	3481	NUM
eurjchem-769	66	10	,	,	PUNCT
eurjchem-769	66	11	3253	3253	NUM
eurjchem-769	66	12	,	,	PUNCT
eurjchem-769	66	13	2925	2925	NUM
eurjchem-769	66	14	,	,	PUNCT
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eurjchem-769	66	18	,	,	PUNCT
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eurjchem-769	66	20	,	,	PUNCT
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eurjchem-769	66	22	,	,	PUNCT
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eurjchem-769	66	24	,	,	PUNCT
eurjchem-769	66	25	1258	1258	NUM
eurjchem-769	66	26	,	,	PUNCT
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eurjchem-769	66	28	,	,	PUNCT
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eurjchem-769	66	30	,	,	PUNCT
eurjchem-769	66	31	870	870	NUM
eurjchem-769	66	32	,	,	PUNCT
eurjchem-769	66	33	804	804	NUM
eurjchem-769	66	34	,	,	PUNCT
eurjchem-769	66	35	565	565	NUM
eurjchem-769	66	36	.	.	PUNCT
eurjchem-769	66	37	1h	1h	NUM
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eurjchem-769	66	39	(	(	PUNCT
eurjchem-769	66	40	400	400	NUM
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eurjchem-769	66	42	,	,	PUNCT
eurjchem-769	66	43	cdcl3	cdcl3	PROPN
eurjchem-769	66	44	,	,	PUNCT
eurjchem-769	66	45	δ	δ	PROPN
eurjchem-769	66	46	,	,	PUNCT
eurjchem-769	66	47	ppm	ppm	NUM
eurjchem-769	66	48	):	):	PUNCT
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eurjchem-769	66	50	(	(	PUNCT
eurjchem-769	66	51	s	s	PROPN
eurjchem-769	66	52	,	,	PUNCT
eurjchem-769	66	53	3h	3h	NUM
eurjchem-769	66	54	,	,	PUNCT
eurjchem-769	66	55	ch3	ch3	PROPN
eurjchem-769	66	56	)	)	PUNCT
eurjchem-769	66	57	,	,	PUNCT
eurjchem-769	66	58	3.69	3.69	NUM
eurjchem-769	66	59	(	(	PUNCT
eurjchem-769	66	60	s	s	PROPN
eurjchem-769	66	61	,	,	PUNCT
eurjchem-769	66	62	3h	3h	NUM
eurjchem-769	66	63	,	,	PUNCT
eurjchem-769	66	64	och3	och3	ADJ
eurjchem-769	66	65	)	)	PUNCT
eurjchem-769	66	66	,	,	PUNCT
eurjchem-769	66	67	4.50	4.50	NUM
eurjchem-769	66	68	(	(	PUNCT
eurjchem-769	66	69	s	s	PROPN
eurjchem-769	66	70	,	,	PUNCT
eurjchem-769	66	71	1h	1h	NUM
eurjchem-769	66	72	,	,	PUNCT
eurjchem-769	66	73	ch	ch	NOUN
eurjchem-769	66	74	)	)	PUNCT
eurjchem-769	66	75	,	,	PUNCT
eurjchem-769	66	76	6.83	6.83	NUM
eurjchem-769	66	77	(	(	PUNCT
eurjchem-769	66	78	s	s	PROPN
eurjchem-769	66	79	,	,	PUNCT
eurjchem-769	66	80	2h	2h	NUM
eurjchem-769	66	81	,	,	PUNCT
eurjchem-769	66	82	nh2	nh2	PROPN
eurjchem-769	66	83	)	)	PUNCT
eurjchem-769	66	84	,	,	PUNCT
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eurjchem-769	66	86	(	(	PUNCT
eurjchem-769	66	87	m	m	PROPN
eurjchem-769	66	88	,	,	PUNCT
eurjchem-769	66	89	4h	4h	NUM
eurjchem-769	66	90	,	,	PUNCT
eurjchem-769	66	91	ar‐h	ar‐h	PROPN
eurjchem-769	66	92	)	)	PUNCT
eurjchem-769	66	93	,	,	PUNCT
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eurjchem-769	66	96	br	br	PROPN
eurjchem-769	66	97	s	s	PROPN
eurjchem-769	66	98	,	,	PUNCT
eurjchem-769	66	99	1h	1h	NUM
eurjchem-769	66	100	,	,	PUNCT
eurjchem-769	66	101	nh	nh	PROPN
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eurjchem-769	66	103	.	.	PUNCT
eurjchem-769	67	1	anal	anal	PROPN
eurjchem-769	67	2	.	.	PUNCT
eurjchem-769	67	3	calcd	calcd	NOUN
eurjchem-769	67	4	.	.	PUNCT
eurjchem-769	68	1	for	for	ADP
eurjchem-769	68	2	c15h14n4o2	c15h14n4o2	PROPN
eurjchem-769	68	3	:	:	PUNCT
eurjchem-769	68	4	c	c	X
eurjchem-769	68	5	,	,	PUNCT
eurjchem-769	68	6	63.82	63.82	NUM
eurjchem-769	68	7	;	;	PUNCT
eurjchem-769	68	8	h	h	NOUN
eurjchem-769	68	9	,	,	PUNCT
eurjchem-769	68	10	5.00	5.00	NUM
eurjchem-769	68	11	;	;	PUNCT
eurjchem-769	68	12	n	n	CCONJ
eurjchem-769	68	13	,	,	PUNCT
eurjchem-769	68	14	19.85	19.85	NUM
eurjchem-769	68	15	.	.	PUNCT
eurjchem-769	68	16	found	find	VERB
eurjchem-769	68	17	:	:	PUNCT
eurjchem-769	69	1	c	c	X
eurjchem-769	69	2	,	,	PUNCT
eurjchem-769	69	3	63.71	63.71	NUM
eurjchem-769	69	4	;	;	PUNCT
eurjchem-769	69	5	h	h	NOUN
eurjchem-769	69	6	,	,	PUNCT
eurjchem-769	69	7	5.15	5.15	NUM
eurjchem-769	69	8	;	;	PUNCT
eurjchem-769	69	9	n	n	CCONJ
eurjchem-769	69	10	,	,	PUNCT
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eurjchem-769	69	13	.	.	PUNCT
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eurjchem-769	70	2	,	,	PUNCT
eurjchem-769	70	3	3‐c]pyrazole‐5‐carbonitrile	3‐c]pyrazole‐5‐carbonitrile	NUM
eurjchem-769	70	4	(	(	PUNCT
eurjchem-769	70	5	5j	5j	NUM
eurjchem-769	70	6	):	):	PUNCT
eurjchem-769	70	7	color	color	NOUN
eurjchem-769	70	8	:	:	PUNCT
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eurjchem-769	70	10	crystals	crystal	NOUN
eurjchem-769	70	11	.	.	PUNCT
eurjchem-769	71	1	m.p	m.p	PROPN
eurjchem-769	71	2	.	.	PROPN
eurjchem-769	71	3	:	:	PUNCT
eurjchem-769	72	1	240–242	240–242	NUM
eurjchem-769	72	2	°	°	PRON
eurjchem-769	72	3	c	c	NOUN
eurjchem-769	72	4	.	.	PUNCT
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eurjchem-769	73	2	(	(	PUNCT
eurjchem-769	73	3	kbr	kbr	PROPN
eurjchem-769	73	4	,	,	PUNCT
eurjchem-769	73	5	ν	ν	PROPN
eurjchem-769	73	6	,	,	PUNCT
eurjchem-769	73	7	cm‐1	cm‐1	PROPN
eurjchem-769	73	8	):	):	PUNCT
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eurjchem-769	73	10	,	,	PUNCT
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eurjchem-769	73	12	,	,	PUNCT
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eurjchem-769	73	16	,	,	PUNCT
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eurjchem-769	73	18	,	,	PUNCT
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eurjchem-769	73	20	,	,	PUNCT
eurjchem-769	73	21	1595	1595	NUM
eurjchem-769	73	22	,	,	PUNCT
eurjchem-769	73	23	1508	1508	NUM
eurjchem-769	73	24	,	,	PUNCT
eurjchem-769	73	25	1410	1410	NUM
eurjchem-769	73	26	,	,	PUNCT
eurjchem-769	73	27	1260	1260	NUM
eurjchem-769	73	28	,	,	PUNCT
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eurjchem-769	73	30	,	,	PUNCT
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eurjchem-769	73	32	,	,	PUNCT
eurjchem-769	73	33	835	835	NUM
eurjchem-769	73	34	.	.	PUNCT
eurjchem-769	74	1	1h	1h	NUM
eurjchem-769	74	2	nmr	nmr	NOUN
eurjchem-769	74	3	(	(	PUNCT
eurjchem-769	74	4	400	400	NUM
eurjchem-769	74	5	mhz	mhz	NOUN
eurjchem-769	74	6	,	,	PUNCT
eurjchem-769	74	7	cdcl3	cdcl3	PROPN
eurjchem-769	74	8	,	,	PUNCT
eurjchem-769	74	9	δ	δ	PROPN
eurjchem-769	74	10	,	,	PUNCT
eurjchem-769	74	11	ppm	ppm	NUM
eurjchem-769	74	12	):	):	PUNCT
eurjchem-769	74	13	1.80	1.80	NUM
eurjchem-769	74	14	(	(	PUNCT
eurjchem-769	74	15	s	s	PROPN
eurjchem-769	74	16	,	,	PUNCT
eurjchem-769	74	17	3h	3h	NUM
eurjchem-769	74	18	,	,	PUNCT
eurjchem-769	74	19	ch3	ch3	PROPN
eurjchem-769	74	20	)	)	PUNCT
eurjchem-769	74	21	,	,	PUNCT
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eurjchem-769	74	23	(	(	PUNCT
eurjchem-769	74	24	s	s	PROPN
eurjchem-769	74	25	,	,	PUNCT
eurjchem-769	74	26	3h	3h	NUM
eurjchem-769	74	27	,	,	PUNCT
eurjchem-769	74	28	ch3	ch3	PROPN
eurjchem-769	74	29	)	)	PUNCT
eurjchem-769	74	30	,	,	PUNCT
eurjchem-769	74	31	4.50	4.50	NUM
eurjchem-769	74	32	(	(	PUNCT
eurjchem-769	74	33	s	s	PROPN
eurjchem-769	74	34	,	,	PUNCT
eurjchem-769	74	35	1h	1h	NUM
eurjchem-769	74	36	,	,	PUNCT
eurjchem-769	74	37	ch	ch	NOUN
eurjchem-769	74	38	)	)	PUNCT
eurjchem-769	74	39	,	,	PUNCT
eurjchem-769	74	40	6.57	6.57	NUM
eurjchem-769	74	41	(	(	PUNCT
eurjchem-769	74	42	s	s	PROPN
eurjchem-769	74	43	,	,	PUNCT
eurjchem-769	74	44	2h	2h	NUM
eurjchem-769	74	45	,	,	PUNCT
eurjchem-769	74	46	nh2	nh2	PROPN
eurjchem-769	74	47	)	)	PUNCT
eurjchem-769	74	48	,	,	PUNCT
eurjchem-769	74	49	6.81‐7.10	6.81‐7.10	PROPN
eurjchem-769	74	50	(	(	PUNCT
eurjchem-769	74	51	m	m	PROPN
eurjchem-769	74	52	,	,	PUNCT
eurjchem-769	74	53	4h	4h	NUM
eurjchem-769	74	54	,	,	PUNCT
eurjchem-769	74	55	ar‐h	ar‐h	PROPN
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eurjchem-769	74	57	,	,	PUNCT
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eurjchem-769	74	62	,	,	PUNCT
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eurjchem-769	74	64	,	,	PUNCT
eurjchem-769	74	65	nh	nh	PROPN
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eurjchem-769	74	67	.	.	PUNCT
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eurjchem-769	75	2	.	.	PUNCT
eurjchem-769	75	3	calcd	calcd	NOUN
eurjchem-769	75	4	.	.	PUNCT
eurjchem-769	76	1	for	for	ADP
eurjchem-769	76	2	c15h14n4o	c15h14n4o	NOUN
eurjchem-769	76	3	:	:	PUNCT
eurjchem-769	76	4	c	c	X
eurjchem-769	76	5	,	,	PUNCT
eurjchem-769	76	6	67.65	67.65	NUM
eurjchem-769	76	7	;	;	PUNCT
eurjchem-769	76	8	h	h	NOUN
eurjchem-769	76	9	,	,	PUNCT
eurjchem-769	76	10	5.30	5.30	NUM
eurjchem-769	76	11	;	;	PUNCT
eurjchem-769	76	12	n	n	CCONJ
eurjchem-769	76	13	,	,	PUNCT
eurjchem-769	76	14	21.04	21.04	NUM
eurjchem-769	76	15	.	.	PUNCT
eurjchem-769	76	16	found	find	VERB
eurjchem-769	76	17	:	:	PUNCT
eurjchem-769	77	1	c	c	X
eurjchem-769	77	2	,	,	PUNCT
eurjchem-769	77	3	68.10	68.10	NUM
eurjchem-769	77	4	;	;	PUNCT
eurjchem-769	77	5	h	h	X
eurjchem-769	77	6	,	,	PUNCT
eurjchem-769	77	7	5.20	5.20	NUM
eurjchem-769	77	8	;	;	PUNCT
eurjchem-769	77	9	n	n	CCONJ
eurjchem-769	77	10	,	,	PUNCT
eurjchem-769	77	11	20.01	20.01	NUM
eurjchem-769	77	12	%	%	NOUN
eurjchem-769	77	13	.	.	PUNCT
eurjchem-769	78	1	2.2.2	2.2.2	X
eurjchem-769	78	2	.	.	PUNCT
eurjchem-769	78	3	general	general	ADJ
eurjchem-769	78	4	procedure	procedure	NOUN
eurjchem-769	78	5	for	for	ADP
eurjchem-769	78	6	synthesis	synthesis	NOUN
eurjchem-769	78	7	of	of	ADP
eurjchem-769	78	8	6‐amino‐4‐(aryl)‐3‐	6‐amino‐4‐(aryl)‐3‐	NUM
eurjchem-769	78	9	methyl‐1‐phenyl‐1,4‐dihydropyrano[2,3‐c]pyrazole‐5‐	methyl‐1‐phenyl‐1,4‐dihydropyrano[2,3‐c]pyrazole‐5‐	NUM
eurjchem-769	78	10	carbonitrile	carbonitrile	VERB
eurjchem-769	78	11	in	in	ADP
eurjchem-769	78	12	a	a	DET
eurjchem-769	78	13	conical	conical	ADJ
eurjchem-769	78	14	flask	flask	NOUN
eurjchem-769	78	15	,	,	PUNCT
eurjchem-769	78	16	pheynyl	pheynyl	NOUN
eurjchem-769	78	17	hydrazine	hydrazine	NOUN
eurjchem-769	78	18	(	(	PUNCT
eurjchem-769	78	19	1	1	NUM
eurjchem-769	78	20	mmol	mmol	NOUN
eurjchem-769	78	21	)	)	PUNCT
eurjchem-769	78	22	,	,	PUNCT
eurjchem-769	78	23	ethylacetoacetate	ethylacetoacetate	VERB
eurjchem-769	78	24	(	(	PUNCT
eurjchem-769	78	25	1	1	NUM
eurjchem-769	78	26	mmol	mmol	NOUN
eurjchem-769	78	27	)	)	PUNCT
eurjchem-769	78	28	,	,	PUNCT
eurjchem-769	78	29	were	be	AUX
eurjchem-769	78	30	added	add	VERB
eurjchem-769	78	31	in	in	ADP
eurjchem-769	78	32	glycerol	glycerol	NOUN
eurjchem-769	78	33	(	(	PUNCT
eurjchem-769	78	34	2	2	NUM
eurjchem-769	78	35	ml	ml	NOUN
eurjchem-769	78	36	)	)	PUNCT
eurjchem-769	78	37	and	and	CCONJ
eurjchem-769	78	38	stirred	stir	VERB
eurjchem-769	78	39	for	for	ADP
eurjchem-769	78	40	10	10	NUM
eurjchem-769	78	41	min	min	NOUN
eurjchem-769	78	42	at	at	ADP
eurjchem-769	78	43	80	80	NUM
eurjchem-769	78	44	°	°	NOUN
eurjchem-769	78	45	c	c	NOUN
eurjchem-769	78	46	.	.	PUNCT
eurjchem-769	79	1	then	then	ADV
eurjchem-769	79	2	,	,	PUNCT
eurjchem-769	79	3	aldehyde	aldehyde	NOUN
eurjchem-769	79	4	(	(	PUNCT
eurjchem-769	79	5	1	1	NUM
eurjchem-769	79	6	mmol	mmol	NOUN
eurjchem-769	79	7	)	)	PUNCT
eurjchem-769	79	8	and	and	CCONJ
eurjchem-769	79	9	malononitrile	malononitrile	NOUN
eurjchem-769	79	10	were	be	AUX
eurjchem-769	79	11	added	add	VERB
eurjchem-769	79	12	successively	successively	ADV
eurjchem-769	79	13	and	and	CCONJ
eurjchem-769	79	14	stirred	stir	VERB
eurjchem-769	79	15	the	the	DET
eurjchem-769	79	16	reaction	reaction	NOUN
eurjchem-769	79	17	mixture	mixture	NOUN
eurjchem-769	79	18	at	at	ADP
eurjchem-769	79	19	the	the	DET
eurjchem-769	79	20	same	same	ADJ
eurjchem-769	79	21	temperature	temperature	NOUN
eurjchem-769	79	22	.	.	PUNCT
eurjchem-769	80	1	after	after	ADP
eurjchem-769	80	2	the	the	DET
eurjchem-769	80	3	completion	completion	NOUN
eurjchem-769	80	4	of	of	ADP
eurjchem-769	80	5	reaction	reaction	NOUN
eurjchem-769	80	6	(	(	PUNCT
eurjchem-769	80	7	monitored	monitor	VERB
eurjchem-769	80	8	by	by	ADP
eurjchem-769	80	9	tlc	tlc	PROPN
eurjchem-769	80	10	)	)	PUNCT
eurjchem-769	80	11	,	,	PUNCT
eurjchem-769	80	12	diluted	dilute	VERB
eurjchem-769	80	13	the	the	DET
eurjchem-769	80	14	reaction	reaction	NOUN
eurjchem-769	80	15	mixture	mixture	NOUN
eurjchem-769	80	16	with	with	ADP
eurjchem-769	80	17	ice	ice	NOUN
eurjchem-769	80	18	cold	cold	ADJ
eurjchem-769	80	19	water	water	NOUN
eurjchem-769	80	20	.	.	PUNCT
eurjchem-769	81	1	filtered	filter	VERB
eurjchem-769	81	2	the	the	DET
eurjchem-769	81	3	solid	solid	ADJ
eurjchem-769	81	4	thus	thus	ADV
eurjchem-769	81	5	obtained	obtain	VERB
eurjchem-769	81	6	and	and	CCONJ
eurjchem-769	81	7	recrystallized	recrystallize	VERB
eurjchem-769	81	8	with	with	ADP
eurjchem-769	81	9	ethanol	ethanol	NOUN
eurjchem-769	81	10	(	(	PUNCT
eurjchem-769	81	11	scheme	scheme	NOUN
eurjchem-769	81	12	1	1	NUM
eurjchem-769	81	13	)	)	PUNCT
eurjchem-769	81	14	.	.	PUNCT
eurjchem-769	82	1	6‐amino‐5‐cyano‐3‐methyl‐1,4‐diphenyl‐1,4‐dihydropyrano	6‐amino‐5‐cyano‐3‐methyl‐1,4‐diphenyl‐1,4‐dihydropyrano	NUM
eurjchem-769	83	1	[	[	X
eurjchem-769	83	2	2,3‐c	2,3‐c	X
eurjchem-769	83	3	]	]	X
eurjchem-769	83	4	pyrazole	pyrazole	NOUN
eurjchem-769	83	5	(	(	PUNCT
eurjchem-769	83	6	6a	6a	NOUN
eurjchem-769	83	7	):	):	PUNCT
eurjchem-769	83	8	color	color	NOUN
eurjchem-769	83	9	:	:	PUNCT
eurjchem-769	83	10	white	white	ADJ
eurjchem-769	83	11	crystals	crystal	NOUN
eurjchem-769	83	12	.	.	PUNCT
eurjchem-769	84	1	m.p	m.p	PROPN
eurjchem-769	84	2	.	.	PROPN
eurjchem-769	84	3	:	:	PUNCT
eurjchem-769	85	1	169‐170	169‐170	NUM
eurjchem-769	85	2	°	°	PRON
eurjchem-769	85	3	c	c	X
eurjchem-769	85	4	.	.	PUNCT
eurjchem-769	86	1	ft‐ir	ft‐ir	NOUN
eurjchem-769	86	2	(	(	PUNCT
eurjchem-769	86	3	kbr	kbr	PROPN
eurjchem-769	86	4	,	,	PUNCT
eurjchem-769	86	5	ν	ν	PROPN
eurjchem-769	86	6	,	,	PUNCT
eurjchem-769	86	7	cm‐1	cm‐1	PROPN
eurjchem-769	86	8	):	):	PUNCT
eurjchem-769	86	9	3472	3472	NUM
eurjchem-769	86	10	,	,	PUNCT
eurjchem-769	86	11	3320	3320	NUM
eurjchem-769	86	12	,	,	PUNCT
eurjchem-769	86	13	2195	2195	NUM
eurjchem-769	86	14	,	,	PUNCT
eurjchem-769	86	15	1660	1660	NUM
eurjchem-769	86	16	,	,	PUNCT
eurjchem-769	86	17	1590	1590	NUM
eurjchem-769	86	18	,	,	PUNCT
eurjchem-769	86	19	1264	1264	NUM
eurjchem-769	86	20	,	,	PUNCT
eurjchem-769	86	21	1125	1125	NUM
eurjchem-769	86	22	,	,	PUNCT
eurjchem-769	86	23	1027	1027	NUM
eurjchem-769	86	24	,	,	PUNCT
eurjchem-769	86	25	753	753	NUM
eurjchem-769	86	26	.	.	NUM
eurjchem-769	86	27	1h	1h	NUM
eurjchem-769	86	28	nmr	nmr	NOUN
eurjchem-769	86	29	(	(	PUNCT
eurjchem-769	86	30	400	400	NUM
eurjchem-769	86	31	mhz	mhz	NOUN
eurjchem-769	86	32	,	,	PUNCT
eurjchem-769	86	33	cdcl3	cdcl3	PROPN
eurjchem-769	86	34	,	,	PUNCT
eurjchem-769	86	35	δ	δ	PROPN
eurjchem-769	86	36	,	,	PUNCT
eurjchem-769	86	37	ppm	ppm	NOUN
eurjchem-769	86	38	):	):	PUNCT
eurjchem-769	86	39	1.93	1.93	NUM
eurjchem-769	86	40	(	(	PUNCT
eurjchem-769	86	41	s	s	PROPN
eurjchem-769	86	42	,	,	PUNCT
eurjchem-769	86	43	3h	3h	NUM
eurjchem-769	86	44	,	,	PUNCT
eurjchem-769	86	45	ch3	ch3	PROPN
eurjchem-769	86	46	)	)	PUNCT
eurjchem-769	86	47	,	,	PUNCT
eurjchem-769	86	48	4.62	4.62	NUM
eurjchem-769	86	49	(	(	PUNCT
eurjchem-769	86	50	s	s	PROPN
eurjchem-769	86	51	,	,	PUNCT
eurjchem-769	86	52	1h	1h	NUM
eurjchem-769	86	53	,	,	PUNCT
eurjchem-769	86	54	ch	ch	NOUN
eurjchem-769	86	55	)	)	PUNCT
eurjchem-769	86	56	,	,	PUNCT
eurjchem-769	86	57	6.99	6.99	NUM
eurjchem-769	86	58	(	(	PUNCT
eurjchem-769	86	59	s	s	PROPN
eurjchem-769	86	60	,	,	PUNCT
eurjchem-769	86	61	2h	2h	NUM
eurjchem-769	86	62	,	,	PUNCT
eurjchem-769	86	63	nh2	nh2	PROPN
eurjchem-769	86	64	)	)	PUNCT
eurjchem-769	86	65	,	,	PUNCT
eurjchem-769	86	66	7.16‐7.32	7.16‐7.32	NUM
eurjchem-769	86	67	(	(	PUNCT
eurjchem-769	86	68	m	m	PROPN
eurjchem-769	86	69	,	,	PUNCT
eurjchem-769	86	70	10h	10h	NUM
eurjchem-769	86	71	,	,	PUNCT
eurjchem-769	86	72	ar‐h	ar‐h	NOUN
eurjchem-769	86	73	)	)	PUNCT
eurjchem-769	86	74	.	.	PUNCT
eurjchem-769	87	1	anal	anal	PROPN
eurjchem-769	87	2	.	.	PUNCT
eurjchem-769	87	3	calcd	calcd	NOUN
eurjchem-769	87	4	.	.	PUNCT
eurjchem-769	88	1	for	for	ADP
eurjchem-769	88	2	c20h16n4o	c20h16n4o	NOUN
eurjchem-769	88	3	:	:	PUNCT
eurjchem-769	88	4	c	c	PROPN
eurjchem-769	88	5	73.15	73.15	NUM
eurjchem-769	88	6	,	,	PUNCT
eurjchem-769	88	7	h	h	NOUN
eurjchem-769	88	8	4.91	4.91	NUM
eurjchem-769	88	9	,	,	PUNCT
eurjchem-769	88	10	n	n	PRON
eurjchem-769	88	11	17.06	17.06	NUM
eurjchem-769	88	12	;	;	PUNCT
eurjchem-769	88	13	found	find	VERB
eurjchem-769	88	14	c	c	PROPN
eurjchem-769	88	15	73.19	73.19	NUM
eurjchem-769	88	16	,	,	PUNCT
eurjchem-769	88	17	h	h	NOUN
eurjchem-769	88	18	5.01	5.01	NUM
eurjchem-769	88	19	,	,	PUNCT
eurjchem-769	88	20	n	n	PRON
eurjchem-769	88	21	17.10	17.10	NUM
eurjchem-769	88	22	%	%	NOUN
eurjchem-769	88	23	.	.	PUNCT
eurjchem-769	89	1	6‐amino‐4‐(4‐chlorophenyl)‐5‐cyano‐3‐methyl‐1‐phenyl‐1,4‐	6‐amino‐4‐(4‐chlorophenyl)‐5‐cyano‐3‐methyl‐1‐phenyl‐1,4‐	NUM
eurjchem-769	89	2	dihydropyrano[2,3‐c]pyrazole	dihydropyrano[2,3‐c]pyrazole	PROPN
eurjchem-769	89	3	(	(	PUNCT
eurjchem-769	89	4	6b	6b	NOUN
eurjchem-769	89	5	):	):	PUNCT
eurjchem-769	89	6	color	color	NOUN
eurjchem-769	89	7	:	:	PUNCT
eurjchem-769	89	8	white	white	ADJ
eurjchem-769	89	9	crystals	crystal	NOUN
eurjchem-769	89	10	.	.	PUNCT
eurjchem-769	90	1	m.p	m.p	PROPN
eurjchem-769	90	2	.	.	PROPN
eurjchem-769	90	3	:	:	PUNCT
eurjchem-769	91	1	175‐176	175‐176	PROPN
eurjchem-769	91	2	°	°	PROPN
eurjchem-769	91	3	c	c	X
eurjchem-769	91	4	.	.	PUNCT
eurjchem-769	92	1	ft‐ir	ft‐ir	NOUN
eurjchem-769	92	2	(	(	PUNCT
eurjchem-769	92	3	kbr	kbr	PROPN
eurjchem-769	92	4	,	,	PUNCT
eurjchem-769	92	5	ν	ν	PROPN
eurjchem-769	92	6	,	,	PUNCT
eurjchem-769	92	7	cm‐1	cm‐1	PROPN
eurjchem-769	92	8	):	):	PUNCT
eurjchem-769	92	9	3468	3468	NUM
eurjchem-769	92	10	,	,	PUNCT
eurjchem-769	92	11	3325	3325	NUM
eurjchem-769	92	12	,	,	PUNCT
eurjchem-769	92	13	2200	2200	NUM
eurjchem-769	92	14	,	,	PUNCT
eurjchem-769	92	15	1662	1662	NUM
eurjchem-769	92	16	,	,	PUNCT
eurjchem-769	92	17	1596	1596	NUM
eurjchem-769	92	18	,	,	PUNCT
eurjchem-769	92	19	1390	1390	NUM
eurjchem-769	92	20	,	,	PUNCT
eurjchem-769	92	21	1262	1262	NUM
eurjchem-769	92	22	,	,	PUNCT
eurjchem-769	92	23	1122	1122	NUM
eurjchem-769	92	24	,	,	PUNCT
eurjchem-769	92	25	1016	1016	NUM
eurjchem-769	92	26	,	,	PUNCT
eurjchem-769	92	27	752	752	NUM
eurjchem-769	92	28	.	.	PUNCT
eurjchem-769	93	1	1h	1h	NUM
eurjchem-769	93	2	nmr	nmr	NOUN
eurjchem-769	93	3	(	(	PUNCT
eurjchem-769	93	4	400	400	NUM
eurjchem-769	93	5	mhz	mhz	NOUN
eurjchem-769	93	6	,	,	PUNCT
eurjchem-769	93	7	cdcl3	cdcl3	PROPN
eurjchem-769	93	8	,	,	PUNCT
eurjchem-769	93	9	δ	δ	PROPN
eurjchem-769	93	10	,	,	PUNCT
eurjchem-769	93	11	ppm	ppm	NUM
eurjchem-769	93	12	):	):	PUNCT
eurjchem-769	93	13	1.83	1.83	NUM
eurjchem-769	93	14	(	(	PUNCT
eurjchem-769	93	15	s	s	PROPN
eurjchem-769	93	16	,	,	PUNCT
eurjchem-769	93	17	3h	3h	NUM
eurjchem-769	93	18	,	,	PUNCT
eurjchem-769	93	19	ch3	ch3	PROPN
eurjchem-769	93	20	)	)	PUNCT
eurjchem-769	93	21	,	,	PUNCT
eurjchem-769	93	22	4.51	4.51	NUM
eurjchem-769	93	23	(	(	PUNCT
eurjchem-769	93	24	s	s	PROPN
eurjchem-769	93	25	,	,	PUNCT
eurjchem-769	93	26	1h	1h	NUM
eurjchem-769	93	27	,	,	PUNCT
eurjchem-769	93	28	ch	ch	NOUN
eurjchem-769	93	29	)	)	PUNCT
eurjchem-769	93	30	,	,	PUNCT
eurjchem-769	93	31	6.73	6.73	NUM
eurjchem-769	93	32	(	(	PUNCT
eurjchem-769	93	33	s	s	PROPN
eurjchem-769	93	34	,	,	PUNCT
eurjchem-769	93	35	2h	2h	NUM
eurjchem-769	93	36	,	,	PUNCT
eurjchem-769	93	37	nh2	nh2	PROPN
eurjchem-769	93	38	)	)	PUNCT
eurjchem-769	93	39	,	,	PUNCT
eurjchem-769	93	40	6.75‐	6.75‐	NUM
eurjchem-769	93	41	7.90	7.90	NUM
eurjchem-769	93	42	(	(	PUNCT
eurjchem-769	93	43	m	m	PROPN
eurjchem-769	93	44	,	,	PUNCT
eurjchem-769	93	45	9h	9h	NUM
eurjchem-769	93	46	,	,	PUNCT
eurjchem-769	93	47	ar‐h	ar‐h	NOUN
eurjchem-769	93	48	)	)	PUNCT
eurjchem-769	93	49	.	.	PUNCT
eurjchem-769	94	1	anal	anal	PROPN
eurjchem-769	94	2	.	.	PUNCT
eurjchem-769	94	3	calcd	calcd	NOUN
eurjchem-769	94	4	.	.	PUNCT
eurjchem-769	95	1	for	for	ADP
eurjchem-769	95	2	c20h15cln4o	c20h15cln4o	NOUN
eurjchem-769	95	3	:	:	PUNCT
eurjchem-769	95	4	c	c	PROPN
eurjchem-769	95	5	66.21	66.21	NUM
eurjchem-769	95	6	,	,	PUNCT
eurjchem-769	95	7	h	h	NOUN
eurjchem-769	95	8	4.17	4.17	NUM
eurjchem-769	95	9	,	,	PUNCT
eurjchem-769	95	10	n	n	PRON
eurjchem-769	95	11	15.44	15.44	NUM
eurjchem-769	95	12	;	;	PUNCT
eurjchem-769	95	13	found	find	VERB
eurjchem-769	95	14	c	c	PROPN
eurjchem-769	95	15	66.26	66.26	NUM
eurjchem-769	95	16	,	,	PUNCT
eurjchem-769	95	17	h	h	NOUN
eurjchem-769	95	18	4.19	4.19	NUM
eurjchem-769	95	19	,	,	PUNCT
eurjchem-769	95	20	n	n	PRON
eurjchem-769	95	21	15.52	15.52	NUM
eurjchem-769	95	22	%	%	NOUN
eurjchem-769	95	23	.	.	PUNCT
eurjchem-769	96	1	6‐amino‐4‐(2‐chlorophenyl)‐5‐cyano‐3‐methyl‐1‐phenyl‐1,4‐	6‐amino‐4‐(2‐chlorophenyl)‐5‐cyano‐3‐methyl‐1‐phenyl‐1,4‐	NUM
eurjchem-769	96	2	dihydropyrano[2,3‐c]pyrazole	dihydropyrano[2,3‐c]pyrazole	NOUN
eurjchem-769	96	3	(	(	PUNCT
eurjchem-769	96	4	6c	6c	NOUN
eurjchem-769	96	5	):	):	PUNCT
eurjchem-769	96	6	color	color	NOUN
eurjchem-769	96	7	:	:	PUNCT
eurjchem-769	96	8	white	white	ADJ
eurjchem-769	96	9	crystals	crystal	NOUN
eurjchem-769	96	10	.	.	PUNCT
eurjchem-769	97	1	m.p	m.p	PROPN
eurjchem-769	97	2	.	.	PROPN
eurjchem-769	97	3	:	:	PUNCT
eurjchem-769	98	1	143‐145	143‐145	PROPN
eurjchem-769	98	2	°	°	ADP
eurjchem-769	98	3	c	c	X
eurjchem-769	98	4	.	.	PUNCT
eurjchem-769	99	1	ft‐ir	ft‐ir	NOUN
eurjchem-769	99	2	(	(	PUNCT
eurjchem-769	99	3	kbr	kbr	PROPN
eurjchem-769	99	4	,	,	PUNCT
eurjchem-769	99	5	ν	ν	PROPN
eurjchem-769	99	6	,	,	PUNCT
eurjchem-769	99	7	cm‐1	cm‐1	PROPN
eurjchem-769	99	8	):	):	PUNCT
eurjchem-769	99	9	3472	3472	NUM
eurjchem-769	99	10	,	,	PUNCT
eurjchem-769	99	11	3324	3324	NUM
eurjchem-769	99	12	,	,	PUNCT
eurjchem-769	99	13	2194	2194	NUM
eurjchem-769	99	14	,	,	PUNCT
eurjchem-769	99	15	1656	1656	NUM
eurjchem-769	99	16	,	,	PUNCT
eurjchem-769	99	17	1592	1592	NUM
eurjchem-769	99	18	,	,	PUNCT
eurjchem-769	99	19	1389	1389	NUM
eurjchem-769	99	20	,	,	PUNCT
eurjchem-769	99	21	1264	1264	NUM
eurjchem-769	99	22	,	,	PUNCT
eurjchem-769	99	23	1125	1125	NUM
eurjchem-769	99	24	,	,	PUNCT
eurjchem-769	99	25	1028	1028	NUM
eurjchem-769	99	26	,	,	PUNCT
eurjchem-769	99	27	752	752	NUM
eurjchem-769	99	28	.	.	PUNCT
eurjchem-769	100	1	1h	1h	NUM
eurjchem-769	100	2	nmr	nmr	NOUN
eurjchem-769	100	3	(	(	PUNCT
eurjchem-769	100	4	400	400	NUM
eurjchem-769	100	5	mhz	mhz	NOUN
eurjchem-769	100	6	,	,	PUNCT
eurjchem-769	100	7	cdcl3	cdcl3	PROPN
eurjchem-769	100	8	,	,	PUNCT
eurjchem-769	100	9	δ	δ	PROPN
eurjchem-769	100	10	,	,	PUNCT
eurjchem-769	100	11	ppm	ppm	NUM
eurjchem-769	100	12	):	):	PUNCT
eurjchem-769	100	13	1.90	1.90	NUM
eurjchem-769	100	14	(	(	PUNCT
eurjchem-769	100	15	s	s	PROPN
eurjchem-769	100	16	,	,	PUNCT
eurjchem-769	100	17	3h	3h	NUM
eurjchem-769	100	18	,	,	PUNCT
eurjchem-769	100	19	ch3	ch3	PROPN
eurjchem-769	100	20	)	)	PUNCT
eurjchem-769	100	21	,	,	PUNCT
eurjchem-769	100	22	4.52	4.52	NUM
eurjchem-769	100	23	(	(	PUNCT
eurjchem-769	100	24	s	s	PROPN
eurjchem-769	100	25	,	,	PUNCT
eurjchem-769	100	26	1h	1h	NUM
eurjchem-769	100	27	,	,	PUNCT
eurjchem-769	100	28	ch	ch	NOUN
eurjchem-769	100	29	)	)	PUNCT
eurjchem-769	100	30	,	,	PUNCT
eurjchem-769	100	31	6.62	6.62	NUM
eurjchem-769	100	32	(	(	PUNCT
eurjchem-769	100	33	s	s	PROPN
eurjchem-769	100	34	,	,	PUNCT
eurjchem-769	100	35	2h	2h	NUM
eurjchem-769	100	36	,	,	PUNCT
eurjchem-769	100	37	nh2	nh2	PROPN
eurjchem-769	100	38	)	)	PUNCT
eurjchem-769	100	39	,	,	PUNCT
eurjchem-769	100	40	6.9‐	6.9‐	NUM
eurjchem-769	100	41	7.6	7.6	NUM
eurjchem-769	100	42	(	(	PUNCT
eurjchem-769	100	43	m	m	PROPN
eurjchem-769	100	44	,	,	PUNCT
eurjchem-769	100	45	9h	9h	NUM
eurjchem-769	100	46	,	,	PUNCT
eurjchem-769	100	47	ar‐h	ar‐h	NOUN
eurjchem-769	100	48	)	)	PUNCT
eurjchem-769	100	49	.	.	PUNCT
eurjchem-769	101	1	anal	anal	PROPN
eurjchem-769	101	2	.	.	PUNCT
eurjchem-769	101	3	calcd	calcd	NOUN
eurjchem-769	101	4	.	.	PUNCT
eurjchem-769	102	1	for	for	ADP
eurjchem-769	102	2	c20h15cln4o	c20h15cln4o	NOUN
eurjchem-769	102	3	:	:	PUNCT
eurjchem-769	102	4	c	c	PROPN
eurjchem-769	102	5	66.21	66.21	NUM
eurjchem-769	102	6	,	,	PUNCT
eurjchem-769	102	7	h	h	NOUN
eurjchem-769	102	8	4.17	4.17	NUM
eurjchem-769	102	9	,	,	PUNCT
eurjchem-769	102	10	n	n	PRON
eurjchem-769	102	11	15.44	15.44	NUM
eurjchem-769	102	12	;	;	PUNCT
eurjchem-769	102	13	found	find	VERB
eurjchem-769	102	14	c	c	PROPN
eurjchem-769	102	15	66.26	66.26	NUM
eurjchem-769	102	16	,	,	PUNCT
eurjchem-769	102	17	h	h	NOUN
eurjchem-769	102	18	4.22	4.22	NUM
eurjchem-769	102	19	,	,	PUNCT
eurjchem-769	102	20	n	n	PRON
eurjchem-769	102	21	15.48	15.48	NUM
eurjchem-769	102	22	%	%	NOUN
eurjchem-769	102	23	.	.	PUNCT
eurjchem-769	103	1	6‐amino‐4‐(4‐nitrophenyl)‐5‐cyano‐3‐methyl‐1‐phenyl‐1,4‐	6‐amino‐4‐(4‐nitrophenyl)‐5‐cyano‐3‐methyl‐1‐phenyl‐1,4‐	NUM
eurjchem-769	103	2	dihydropyrano[2,3‐c]pyrazole	dihydropyrano[2,3‐c]pyrazole	NOUN
eurjchem-769	103	3	(	(	PUNCT
eurjchem-769	103	4	6d	6d	NUM
eurjchem-769	103	5	):	):	PUNCT
eurjchem-769	103	6	color	color	NOUN
eurjchem-769	103	7	:	:	PUNCT
eurjchem-769	103	8	white	white	ADJ
eurjchem-769	103	9	crystals	crystal	NOUN
eurjchem-769	103	10	.	.	PUNCT
eurjchem-769	104	1	m.p	m.p	PROPN
eurjchem-769	104	2	.	.	PROPN
eurjchem-769	104	3	:	:	PUNCT
eurjchem-769	105	1	195‐197	195‐197	NUM
eurjchem-769	105	2	°	°	NUM
eurjchem-769	105	3	c	c	X
eurjchem-769	105	4	.	.	PUNCT
eurjchem-769	106	1	ft‐ir	ft‐ir	NOUN
eurjchem-769	106	2	(	(	PUNCT
eurjchem-769	106	3	kbr	kbr	PROPN
eurjchem-769	106	4	,	,	PUNCT
eurjchem-769	106	5	ν	ν	PROPN
eurjchem-769	106	6	,	,	PUNCT
eurjchem-769	106	7	cm‐1	cm‐1	PROPN
eurjchem-769	106	8	):	):	PUNCT
eurjchem-769	106	9	3430	3430	NUM
eurjchem-769	106	10	,	,	PUNCT
eurjchem-769	106	11	3340	3340	NUM
eurjchem-769	106	12	,	,	PUNCT
eurjchem-769	106	13	2192	2192	NUM
eurjchem-769	106	14	,	,	PUNCT
eurjchem-769	106	15	1665	1665	NUM
eurjchem-769	106	16	,	,	PUNCT
eurjchem-769	106	17	1596	1596	NUM
eurjchem-769	106	18	,	,	PUNCT
eurjchem-769	106	19	1354	1354	NUM
eurjchem-769	106	20	,	,	PUNCT
eurjchem-769	106	21	1124	1124	NUM
eurjchem-769	106	22	,	,	PUNCT
eurjchem-769	106	23	832	832	NUM
eurjchem-769	106	24	,	,	PUNCT
eurjchem-769	106	25	754	754	NUM
eurjchem-769	106	26	.	.	PUNCT
eurjchem-769	107	1	1h	1h	NUM
eurjchem-769	107	2	nmr	nmr	NOUN
eurjchem-769	107	3	(	(	PUNCT
eurjchem-769	107	4	400	400	NUM
eurjchem-769	107	5	mhz	mhz	NOUN
eurjchem-769	107	6	,	,	PUNCT
eurjchem-769	107	7	cdcl3	cdcl3	PROPN
eurjchem-769	107	8	,	,	PUNCT
eurjchem-769	107	9	δ	δ	PROPN
eurjchem-769	107	10	,	,	PUNCT
eurjchem-769	107	11	ppm	ppm	NUM
eurjchem-769	107	12	):	):	PUNCT
eurjchem-769	107	13	1.80	1.80	NUM
eurjchem-769	107	14	(	(	PUNCT
eurjchem-769	107	15	s	s	PROPN
eurjchem-769	107	16	,	,	PUNCT
eurjchem-769	107	17	3h	3h	NUM
eurjchem-769	107	18	,	,	PUNCT
eurjchem-769	107	19	ch3	ch3	PROPN
eurjchem-769	107	20	)	)	PUNCT
eurjchem-769	107	21	,	,	PUNCT
eurjchem-769	107	22	4.96	4.96	NUM
eurjchem-769	107	23	(	(	PUNCT
eurjchem-769	107	24	s	s	PROPN
eurjchem-769	107	25	,	,	PUNCT
eurjchem-769	107	26	1h	1h	NUM
eurjchem-769	107	27	,	,	PUNCT
eurjchem-769	107	28	ch	ch	NOUN
eurjchem-769	107	29	)	)	PUNCT
eurjchem-769	107	30	,	,	PUNCT
eurjchem-769	107	31	6.98	6.98	NUM
eurjchem-769	107	32	(	(	PUNCT
eurjchem-769	107	33	s	s	PROPN
eurjchem-769	107	34	,	,	PUNCT
eurjchem-769	107	35	2h	2h	NUM
eurjchem-769	107	36	,	,	PUNCT
eurjchem-769	107	37	nh2	nh2	PROPN
eurjchem-769	107	38	)	)	PUNCT
eurjchem-769	107	39	,	,	PUNCT
eurjchem-769	107	40	7.32‐8.20	7.32‐8.20	NUM
eurjchem-769	107	41	(	(	PUNCT
eurjchem-769	107	42	m	m	PROPN
eurjchem-769	107	43	,	,	PUNCT
eurjchem-769	107	44	9h	9h	NUM
eurjchem-769	107	45	,	,	PUNCT
eurjchem-769	107	46	ar‐h	ar‐h	NOUN
eurjchem-769	107	47	)	)	PUNCT
eurjchem-769	107	48	.	.	PUNCT
eurjchem-769	108	1	anal	anal	PROPN
eurjchem-769	108	2	.	.	PUNCT
eurjchem-769	108	3	calcd	calcd	NOUN
eurjchem-769	108	4	.	.	PUNCT
eurjchem-769	109	1	for	for	ADP
eurjchem-769	109	2	c20h15n5o3	c20h15n5o3	PROPN
eurjchem-769	109	3	:	:	PUNCT
eurjchem-769	109	4	c	c	PROPN
eurjchem-769	109	5	64.34	64.34	NUM
eurjchem-769	109	6	,	,	PUNCT
eurjchem-769	109	7	h	h	NOUN
eurjchem-769	109	8	4.05	4.05	NUM
eurjchem-769	109	9	,	,	PUNCT
eurjchem-769	109	10	n	n	PRON
eurjchem-769	109	11	18.76	18.76	NUM
eurjchem-769	109	12	;	;	PUNCT
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eurjchem-769	109	14	c	c	PROPN
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eurjchem-769	109	16	h	h	NOUN
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eurjchem-769	109	18	,	,	PUNCT
eurjchem-769	109	19	n	n	PRON
eurjchem-769	109	20	18.80	18.80	NUM
eurjchem-769	109	21	%	%	NOUN
eurjchem-769	109	22	.	.	PUNCT
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eurjchem-769	110	2	dihydropyrano[2,3‐c]pyrazole	dihydropyrano[2,3‐c]pyrazole	NOUN
eurjchem-769	110	3	(	(	PUNCT
eurjchem-769	110	4	6f	6f	NUM
eurjchem-769	110	5	):	):	PUNCT
eurjchem-769	110	6	color	color	NOUN
eurjchem-769	110	7	:	:	PUNCT
eurjchem-769	110	8	white	white	ADJ
eurjchem-769	110	9	crystals	crystal	NOUN
eurjchem-769	110	10	.	.	PUNCT
eurjchem-769	111	1	m.p	m.p	PROPN
eurjchem-769	111	2	.	.	PROPN
eurjchem-769	111	3	:	:	PUNCT
eurjchem-769	112	1	191‐193	191‐193	NUM
eurjchem-769	112	2	°	°	PROPN
eurjchem-769	112	3	c	c	X
eurjchem-769	112	4	.	.	PUNCT
eurjchem-769	113	1	ft‐ir	ft‐ir	NOUN
eurjchem-769	113	2	(	(	PUNCT
eurjchem-769	113	3	kbr	kbr	PROPN
eurjchem-769	113	4	,	,	PUNCT
eurjchem-769	113	5	ν	ν	PROPN
eurjchem-769	113	6	,	,	PUNCT
eurjchem-769	113	7	cm‐1	cm‐1	PROPN
eurjchem-769	113	8	):	):	PUNCT
eurjchem-769	113	9	3420	3420	NUM
eurjchem-769	113	10	,	,	PUNCT
eurjchem-769	113	11	3330	3330	NUM
eurjchem-769	113	12	,	,	PUNCT
eurjchem-769	113	13	2194	2194	NUM
eurjchem-769	113	14	,	,	PUNCT
eurjchem-769	113	15	1675	1675	NUM
eurjchem-769	113	16	,	,	PUNCT
eurjchem-769	113	17	1598	1598	NUM
eurjchem-769	113	18	,	,	PUNCT
eurjchem-769	113	19	1390	1390	NUM
eurjchem-769	113	20	,	,	PUNCT
eurjchem-769	113	21	1264	1264	NUM
eurjchem-769	113	22	,	,	PUNCT
eurjchem-769	113	23	1126	1126	NUM
eurjchem-769	113	24	,	,	PUNCT
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eurjchem-769	113	26	,	,	PUNCT
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eurjchem-769	113	28	.	.	PUNCT
eurjchem-769	114	1	1h	1h	NUM
eurjchem-769	114	2	nmr	nmr	NOUN
eurjchem-769	114	3	(	(	PUNCT
eurjchem-769	114	4	400	400	NUM
eurjchem-769	114	5	mhz	mhz	NOUN
eurjchem-769	114	6	,	,	PUNCT
eurjchem-769	114	7	cdcl3	cdcl3	PROPN
eurjchem-769	114	8	,	,	PUNCT
eurjchem-769	114	9	δ	δ	PROPN
eurjchem-769	114	10	,	,	PUNCT
eurjchem-769	114	11	ppm	ppm	NUM
eurjchem-769	114	12	):	):	PUNCT
eurjchem-769	114	13	1.82	1.82	NUM
eurjchem-769	114	14	(	(	PUNCT
eurjchem-769	114	15	s	s	PROPN
eurjchem-769	114	16	,	,	PUNCT
eurjchem-769	114	17	3h	3h	NUM
eurjchem-769	114	18	,	,	PUNCT
eurjchem-769	114	19	ch3	ch3	PROPN
eurjchem-769	114	20	)	)	PUNCT
eurjchem-769	114	21	,	,	PUNCT
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eurjchem-769	114	23	(	(	PUNCT
eurjchem-769	114	24	s	s	PROPN
eurjchem-769	114	25	,	,	PUNCT
eurjchem-769	114	26	1h	1h	NUM
eurjchem-769	114	27	,	,	PUNCT
eurjchem-769	114	28	ch	ch	NOUN
eurjchem-769	114	29	)	)	PUNCT
eurjchem-769	114	30	,	,	PUNCT
eurjchem-769	114	31	7.40	7.40	NUM
eurjchem-769	114	32	(	(	PUNCT
eurjchem-769	114	33	s	s	PROPN
eurjchem-769	114	34	,	,	PUNCT
eurjchem-769	114	35	2h	2h	NUM
eurjchem-769	114	36	,	,	PUNCT
eurjchem-769	114	37	nh2	nh2	PROPN
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eurjchem-769	114	39	,	,	PUNCT
eurjchem-769	114	40	7.20‐	7.20‐	NUM
eurjchem-769	114	41	8.12	8.12	NUM
eurjchem-769	114	42	(	(	PUNCT
eurjchem-769	114	43	m	m	PROPN
eurjchem-769	114	44	,	,	PUNCT
eurjchem-769	114	45	9h	9h	NUM
eurjchem-769	114	46	,	,	PUNCT
eurjchem-769	114	47	ar‐h	ar‐h	NOUN
eurjchem-769	114	48	)	)	PUNCT
eurjchem-769	114	49	.	.	PUNCT
eurjchem-769	115	1	anal	anal	PROPN
eurjchem-769	115	2	.	.	PUNCT
eurjchem-769	115	3	calcd	calcd	NOUN
eurjchem-769	115	4	.	.	PUNCT
eurjchem-769	116	1	for	for	ADP
eurjchem-769	116	2	c20h15n5o3	c20h15n5o3	PROPN
eurjchem-769	116	3	:	:	PUNCT
eurjchem-769	116	4	c	c	PROPN
eurjchem-769	116	5	64.34	64.34	NUM
eurjchem-769	116	6	,	,	PUNCT
eurjchem-769	116	7	h	h	NOUN
eurjchem-769	116	8	4.05	4.05	NUM
eurjchem-769	116	9	,	,	PUNCT
eurjchem-769	116	10	n	n	PRON
eurjchem-769	116	11	18.76	18.76	NUM
eurjchem-769	116	12	;	;	PUNCT
eurjchem-769	116	13	found	find	VERB
eurjchem-769	116	14	c	c	PROPN
eurjchem-769	116	15	64.38	64.38	NUM
eurjchem-769	116	16	h	h	NOUN
eurjchem-769	116	17	4.10	4.10	NUM
eurjchem-769	116	18	,	,	PUNCT
eurjchem-769	116	19	n	n	PROPN
eurjchem-769	116	20	18.81	18.81	NUM
eurjchem-769	116	21	%	%	NOUN
eurjchem-769	116	22	.	.	PUNCT
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eurjchem-769	117	2	1,4‐dihydropyrano[2,3‐c]pyrazole	1,4‐dihydropyrano[2,3‐c]pyrazole	NUM
eurjchem-769	117	3	(	(	PUNCT
eurjchem-769	117	4	6	6	NUM
eurjchem-769	117	5	g	g	NOUN
eurjchem-769	117	6	):	):	PUNCT
eurjchem-769	117	7	color	color	NOUN
eurjchem-769	117	8	:	:	PUNCT
eurjchem-769	117	9	white	white	ADJ
eurjchem-769	117	10	crystals	crystal	NOUN
eurjchem-769	117	11	.	.	PUNCT
eurjchem-769	118	1	m.p	m.p	PROPN
eurjchem-769	118	2	.	.	PROPN
eurjchem-769	118	3	:	:	PUNCT
eurjchem-769	119	1	209‐211	209‐211	NUM
eurjchem-769	119	2	°	°	ADP
eurjchem-769	119	3	c	c	X
eurjchem-769	119	4	.	.	PUNCT
eurjchem-769	120	1	ft‐ir	ft‐ir	NOUN
eurjchem-769	120	2	(	(	PUNCT
eurjchem-769	120	3	kbr	kbr	PROPN
eurjchem-769	120	4	,	,	PUNCT
eurjchem-769	120	5	ν	ν	PROPN
eurjchem-769	120	6	,	,	PUNCT
eurjchem-769	120	7	cm‐1	cm‐1	PROPN
eurjchem-769	120	8	):	):	PUNCT
eurjchem-769	120	9	3414	3414	NUM
eurjchem-769	120	10	,	,	PUNCT
eurjchem-769	120	11	3314	3314	NUM
eurjchem-769	120	12	,	,	PUNCT
eurjchem-769	120	13	2178	2178	NUM
eurjchem-769	120	14	,	,	PUNCT
eurjchem-769	120	15	1658	1658	NUM
eurjchem-769	120	16	,	,	PUNCT
eurjchem-769	120	17	1594	1594	NUM
eurjchem-769	120	18	,	,	PUNCT
eurjchem-769	120	19	1398	1398	NUM
eurjchem-769	120	20	,	,	PUNCT
eurjchem-769	120	21	1258	1258	NUM
eurjchem-769	120	22	,	,	PUNCT
eurjchem-769	120	23	1128	1128	NUM
eurjchem-769	120	24	,	,	PUNCT
eurjchem-769	120	25	1026	1026	NUM
eurjchem-769	120	26	,	,	PUNCT
eurjchem-769	120	27	754	754	NUM
eurjchem-769	120	28	.	.	PUNCT
eurjchem-769	121	1	1h	1h	NUM
eurjchem-769	121	2	nmr	nmr	NOUN
eurjchem-769	121	3	(	(	PUNCT
eurjchem-769	121	4	400	400	NUM
eurjchem-769	121	5	mhz	mhz	NOUN
eurjchem-769	121	6	,	,	PUNCT
eurjchem-769	121	7	cdcl3	cdcl3	PROPN
eurjchem-769	121	8	,	,	PUNCT
eurjchem-769	121	9	δ	δ	PROPN
eurjchem-769	121	10	,	,	PUNCT
eurjchem-769	121	11	ppm	ppm	NUM
eurjchem-769	121	12	):	):	PUNCT
eurjchem-769	121	13	1.78	1.78	NUM
eurjchem-769	121	14	(	(	PUNCT
eurjchem-769	121	15	s	s	PROPN
eurjchem-769	121	16	,	,	PUNCT
eurjchem-769	121	17	3h	3h	NUM
eurjchem-769	121	18	,	,	PUNCT
eurjchem-769	121	19	ch3	ch3	PROPN
eurjchem-769	121	20	)	)	PUNCT
eurjchem-769	121	21	,	,	PUNCT
eurjchem-769	121	22	4.56	4.56	NUM
eurjchem-769	121	23	(	(	PUNCT
eurjchem-769	121	24	s	s	PROPN
eurjchem-769	121	25	,	,	PUNCT
eurjchem-769	121	26	1h	1h	NUM
eurjchem-769	121	27	,	,	PUNCT
eurjchem-769	121	28	ch	ch	NOUN
eurjchem-769	121	29	)	)	PUNCT
eurjchem-769	121	30	,	,	PUNCT
eurjchem-769	121	31	7.12	7.12	NUM
eurjchem-769	121	32	(	(	PUNCT
eurjchem-769	121	33	s	s	PROPN
eurjchem-769	121	34	,	,	PUNCT
eurjchem-769	121	35	2h	2h	NUM
eurjchem-769	121	36	,	,	PUNCT
eurjchem-769	121	37	nh2	nh2	PROPN
eurjchem-769	121	38	)	)	PUNCT
eurjchem-769	121	39	,	,	PUNCT
eurjchem-769	121	40	6.72‐	6.72‐	NUM
eurjchem-769	121	41	7.78	7.78	NUM
eurjchem-769	121	42	(	(	PUNCT
eurjchem-769	121	43	m	m	PROPN
eurjchem-769	121	44	,	,	PUNCT
eurjchem-769	121	45	9h	9h	NUM
eurjchem-769	121	46	,	,	PUNCT
eurjchem-769	121	47	ar‐h	ar‐h	NOUN
eurjchem-769	121	48	)	)	PUNCT
eurjchem-769	121	49	,	,	PUNCT
eurjchem-769	121	50	9.38	9.38	NUM
eurjchem-769	121	51	(	(	PUNCT
eurjchem-769	121	52	s	s	PROPN
eurjchem-769	121	53	,	,	PUNCT
eurjchem-769	121	54	1h	1h	NUM
eurjchem-769	121	55	,	,	PUNCT
eurjchem-769	121	56	oh	oh	INTJ
eurjchem-769	121	57	)	)	PUNCT
eurjchem-769	121	58	.	.	PUNCT
eurjchem-769	122	1	anal	anal	PROPN
eurjchem-769	122	2	.	.	PUNCT
eurjchem-769	122	3	calcd	calcd	NOUN
eurjchem-769	122	4	.	.	PUNCT
eurjchem-769	123	1	for	for	ADP
eurjchem-769	123	2	c20h16n4o2	c20h16n4o2	PROPN
eurjchem-769	123	3	:	:	PUNCT
eurjchem-769	123	4	c	c	PROPN
eurjchem-769	123	5	69.76	69.76	NUM
eurjchem-769	123	6	,	,	PUNCT
eurjchem-769	123	7	h	h	NOUN
eurjchem-769	123	8	4.68	4.68	NUM
eurjchem-769	123	9	,	,	PUNCT
eurjchem-769	123	10	n	n	PRON
eurjchem-769	123	11	16.27	16.27	NUM
eurjchem-769	123	12	;	;	PUNCT
eurjchem-769	123	13	found	find	VERB
eurjchem-769	123	14	c	c	PROPN
eurjchem-769	123	15	69.82	69.82	NUM
eurjchem-769	123	16	,	,	PUNCT
eurjchem-769	123	17	h	h	NOUN
eurjchem-769	123	18	4.72	4.72	NUM
eurjchem-769	123	19	,	,	PUNCT
eurjchem-769	123	20	n	n	PRON
eurjchem-769	123	21	16.31	16.31	NUM
eurjchem-769	123	22	%	%	NOUN
eurjchem-769	123	23	.	.	PUNCT
eurjchem-769	124	1	6‐amino‐4‐(4‐methoxyphenyl)‐5‐cyano‐3‐methyl‐1‐phenyl‐	6‐amino‐4‐(4‐methoxyphenyl)‐5‐cyano‐3‐methyl‐1‐phenyl‐	NUM
eurjchem-769	124	2	1,4‐dihydropyrano[2,3‐c	1,4‐dihydropyrano[2,3‐c	NUM
eurjchem-769	124	3	]	]	X
eurjchem-769	124	4	pyrazole	pyrazole	NOUN
eurjchem-769	124	5	(	(	PUNCT
eurjchem-769	124	6	6h	6h	NOUN
eurjchem-769	124	7	):	):	PUNCT
eurjchem-769	124	8	color	color	NOUN
eurjchem-769	124	9	:	:	PUNCT
eurjchem-769	124	10	white	white	ADJ
eurjchem-769	124	11	crystals	crystal	NOUN
eurjchem-769	124	12	.	.	PUNCT
eurjchem-769	125	1	m.p	m.p	PROPN
eurjchem-769	125	2	.	.	PROPN
eurjchem-769	125	3	:	:	PUNCT
eurjchem-769	126	1	175‐177	175‐177	NUM
eurjchem-769	126	2	°	°	ADP
eurjchem-769	126	3	c	c	X
eurjchem-769	126	4	.	.	PUNCT
eurjchem-769	127	1	ft‐ir	ft‐ir	NOUN
eurjchem-769	127	2	(	(	PUNCT
eurjchem-769	127	3	kbr	kbr	PROPN
eurjchem-769	127	4	,	,	PUNCT
eurjchem-769	127	5	ν	ν	PROPN
eurjchem-769	127	6	,	,	PUNCT
eurjchem-769	127	7	cm‐1	cm‐1	PROPN
eurjchem-769	127	8	):	):	PUNCT
eurjchem-769	127	9	3395	3395	NUM
eurjchem-769	127	10	,	,	PUNCT
eurjchem-769	127	11	3322	3322	NUM
eurjchem-769	127	12	,	,	PUNCT
eurjchem-769	127	13	2192	2192	NUM
eurjchem-769	127	14	,	,	PUNCT
eurjchem-769	127	15	1660	1660	NUM
eurjchem-769	127	16	,	,	PUNCT
eurjchem-769	127	17	1595	1595	NUM
eurjchem-769	127	18	,	,	PUNCT
eurjchem-769	127	19	1394	1394	NUM
eurjchem-769	127	20	,	,	PUNCT
eurjchem-769	127	21	1250	1250	NUM
eurjchem-769	127	22	,	,	PUNCT
eurjchem-769	127	23	1128	1128	NUM
eurjchem-769	127	24	,	,	PUNCT
eurjchem-769	127	25	813	813	NUM
eurjchem-769	127	26	.	.	PUNCT
eurjchem-769	128	1	1h	1h	NUM
eurjchem-769	128	2	nmr	nmr	NOUN
eurjchem-769	128	3	(	(	PUNCT
eurjchem-769	128	4	400	400	NUM
eurjchem-769	128	5	mhz	mhz	NOUN
eurjchem-769	128	6	,	,	PUNCT
eurjchem-769	128	7	cdcl3	cdcl3	PROPN
eurjchem-769	128	8	,	,	PUNCT
eurjchem-769	128	9	δ	δ	PROPN
eurjchem-769	128	10	,	,	PUNCT
eurjchem-769	128	11	ppm	ppm	NUM
eurjchem-769	128	12	):	):	PUNCT
eurjchem-769	128	13	1.81	1.81	NUM
eurjchem-769	128	14	(	(	PUNCT
eurjchem-769	128	15	s	s	PROPN
eurjchem-769	128	16	,	,	PUNCT
eurjchem-769	128	17	3h	3h	NUM
eurjchem-769	128	18	,	,	PUNCT
eurjchem-769	128	19	ch3	ch3	PROPN
eurjchem-769	128	20	)	)	PUNCT
eurjchem-769	128	21	,	,	PUNCT
eurjchem-769	128	22	3.76	3.76	NUM
eurjchem-769	128	23	(	(	PUNCT
eurjchem-769	128	24	s	s	PROPN
eurjchem-769	128	25	,	,	PUNCT
eurjchem-769	128	26	3h	3h	NUM
eurjchem-769	128	27	,	,	PUNCT
eurjchem-769	128	28	och3	och3	ADJ
eurjchem-769	128	29	)	)	PUNCT
eurjchem-769	128	30	,	,	PUNCT
eurjchem-769	128	31	4.57	4.57	NUM
eurjchem-769	128	32	(	(	PUNCT
eurjchem-769	128	33	s	s	PROPN
eurjchem-769	128	34	,	,	PUNCT
eurjchem-769	128	35	1h	1h	NUM
eurjchem-769	128	36	,	,	PUNCT
eurjchem-769	128	37	ch	ch	NOUN
eurjchem-769	128	38	)	)	PUNCT
eurjchem-769	128	39	,	,	PUNCT
eurjchem-769	128	40	7.2	7.2	NUM
eurjchem-769	128	41	(	(	PUNCT
eurjchem-769	128	42	s	s	PROPN
eurjchem-769	128	43	,	,	PUNCT
eurjchem-769	128	44	2h	2h	NUM
eurjchem-769	128	45	,	,	PUNCT
eurjchem-769	128	46	nh2	nh2	PROPN
eurjchem-769	128	47	)	)	PUNCT
eurjchem-769	128	48	,	,	PUNCT
eurjchem-769	128	49	6.8‐8.1	6.8‐8.1	NUM
eurjchem-769	128	50	(	(	PUNCT
eurjchem-769	128	51	s	s	PROPN
eurjchem-769	128	52	,	,	PUNCT
eurjchem-769	128	53	9h	9h	NUM
eurjchem-769	128	54	,	,	PUNCT
eurjchem-769	128	55	ar‐h	ar‐h	NOUN
eurjchem-769	128	56	)	)	PUNCT
eurjchem-769	128	57	.	.	PUNCT
eurjchem-769	129	1	anal	anal	PROPN
eurjchem-769	129	2	.	.	PUNCT
eurjchem-769	129	3	calcd	calcd	NOUN
eurjchem-769	129	4	.	.	PUNCT
eurjchem-769	130	1	for	for	ADP
eurjchem-769	130	2	c21h18n4o2	c21h18n4o2	PROPN
eurjchem-769	130	3	:	:	PUNCT
eurjchem-769	130	4	c	c	PROPN
eurjchem-769	130	5	70.38	70.38	NUM
eurjchem-769	130	6	,	,	PUNCT
eurjchem-769	130	7	h	h	NOUN
eurjchem-769	130	8	5.06	5.06	NUM
eurjchem-769	130	9	,	,	PUNCT
eurjchem-769	130	10	n	n	PRON
eurjchem-769	130	11	15.63	15.63	NUM
eurjchem-769	130	12	;	;	PUNCT
eurjchem-769	130	13	found	find	VERB
eurjchem-769	130	14	c	c	PROPN
eurjchem-769	130	15	70.42	70.42	NUM
eurjchem-769	130	16	,	,	PUNCT
eurjchem-769	130	17	h	h	NOUN
eurjchem-769	130	18	5.11	5.11	NUM
eurjchem-769	130	19	,	,	PUNCT
eurjchem-769	130	20	n	n	PRON
eurjchem-769	130	21	15.68	15.68	NUM
eurjchem-769	130	22	%	%	NOUN
eurjchem-769	130	23	.	.	PUNCT
eurjchem-769	131	1	6‐amino‐4‐(4‐methylphenyl)‐5‐cyano‐3‐methyl‐1‐phenyl‐1,4‐	6‐amino‐4‐(4‐methylphenyl)‐5‐cyano‐3‐methyl‐1‐phenyl‐1,4‐	NUM
eurjchem-769	131	2	dihydropyrano[2,3‐c]pyrazole	dihydropyrano[2,3‐c]pyrazole	NOUN
eurjchem-769	131	3	(	(	PUNCT
eurjchem-769	131	4	6j	6j	NUM
eurjchem-769	131	5	):	):	PUNCT
eurjchem-769	131	6	color	color	NOUN
eurjchem-769	131	7	:	:	PUNCT
eurjchem-769	131	8	white	white	ADJ
eurjchem-769	131	9	crystals	crystal	NOUN
eurjchem-769	131	10	.	.	PUNCT
eurjchem-769	132	1	m.p	m.p	PROPN
eurjchem-769	132	2	.	.	PROPN
eurjchem-769	132	3	:	:	PUNCT
eurjchem-769	133	1	140‐142	140‐142	NUM
eurjchem-769	133	2	°	°	NUM
eurjchem-769	133	3	c	c	X
eurjchem-769	133	4	.	.	PUNCT
eurjchem-769	133	5	ft‐ir	ft‐ir	NOUN
eurjchem-769	133	6	(	(	PUNCT
eurjchem-769	133	7	kbr	kbr	PROPN
eurjchem-769	133	8	,	,	PUNCT
eurjchem-769	133	9	ν	ν	PROPN
eurjchem-769	133	10	,	,	PUNCT
eurjchem-769	133	11	cm‐1	cm‐1	PROPN
eurjchem-769	133	12	):	):	PUNCT
eurjchem-769	133	13	3414	3414	NUM
eurjchem-769	133	14	,	,	PUNCT
eurjchem-769	133	15	3314	3314	NUM
eurjchem-769	133	16	,	,	PUNCT
eurjchem-769	133	17	2178	2178	NUM
eurjchem-769	133	18	,	,	PUNCT
eurjchem-769	133	19	1658	1658	NUM
eurjchem-769	133	20	,	,	PUNCT
eurjchem-769	133	21	1594	1594	NUM
eurjchem-769	133	22	,	,	PUNCT
eurjchem-769	133	23	1398	1398	NUM
eurjchem-769	133	24	,	,	PUNCT
eurjchem-769	133	25	1258	1258	NUM
eurjchem-769	133	26	,	,	PUNCT
eurjchem-769	133	27	1128	1128	NUM
eurjchem-769	133	28	,	,	PUNCT
eurjchem-769	133	29	1026	1026	NUM
eurjchem-769	133	30	,	,	PUNCT
eurjchem-769	133	31	754	754	NUM
eurjchem-769	133	32	.	.	PUNCT
eurjchem-769	133	33	1h	1h	NUM
eurjchem-769	133	34	nmr	nmr	NOUN
eurjchem-769	133	35	(	(	PUNCT
eurjchem-769	133	36	400	400	NUM
eurjchem-769	133	37	mhz	mhz	NOUN
eurjchem-769	133	38	,	,	PUNCT
eurjchem-769	133	39	cdcl3	cdcl3	PROPN
eurjchem-769	133	40	,	,	PUNCT
eurjchem-769	133	41	δ	δ	PROPN
eurjchem-769	133	42	,	,	PUNCT
eurjchem-769	133	43	ppm	ppm	NUM
eurjchem-769	133	44	):	):	PUNCT
eurjchem-769	133	45	1.81	1.81	NUM
eurjchem-769	133	46	(	(	PUNCT
eurjchem-769	133	47	s	s	PROPN
eurjchem-769	133	48	,	,	PUNCT
eurjchem-769	133	49	3h	3h	NUM
eurjchem-769	133	50	,	,	PUNCT
eurjchem-769	133	51	ch3	ch3	PROPN
eurjchem-769	133	52	)	)	PUNCT
eurjchem-769	133	53	,	,	PUNCT
eurjchem-769	133	54	2.1	2.1	NUM
eurjchem-769	133	55	(	(	PUNCT
eurjchem-769	133	56	s	s	PROPN
eurjchem-769	133	57	,	,	PUNCT
eurjchem-769	133	58	3h	3h	NUM
eurjchem-769	133	59	,	,	PUNCT
eurjchem-769	133	60	ch3	ch3	PROPN
eurjchem-769	133	61	)	)	PUNCT
eurjchem-769	133	62	,	,	PUNCT
eurjchem-769	133	63	4.5	4.5	NUM
eurjchem-769	133	64	(	(	PUNCT
eurjchem-769	133	65	s	s	PROPN
eurjchem-769	133	66	,	,	PUNCT
eurjchem-769	133	67	1h	1h	NUM
eurjchem-769	133	68	,	,	PUNCT
eurjchem-769	133	69	ch	ch	NOUN
eurjchem-769	133	70	)	)	PUNCT
eurjchem-769	133	71	,	,	PUNCT
eurjchem-769	133	72	6.85	6.85	NUM
eurjchem-769	133	73	(	(	PUNCT
eurjchem-769	133	74	s	s	PROPN
eurjchem-769	133	75	,	,	PUNCT
eurjchem-769	133	76	2h	2h	NUM
eurjchem-769	133	77	,	,	PUNCT
eurjchem-769	133	78	nh2	nh2	PROPN
eurjchem-769	133	79	)	)	PUNCT
eurjchem-769	133	80	,	,	PUNCT
eurjchem-769	133	81	7.1‐8.01	7.1‐8.01	NUM
eurjchem-769	133	82	(	(	PUNCT
eurjchem-769	133	83	m	m	PROPN
eurjchem-769	133	84	,	,	PUNCT
eurjchem-769	133	85	9h	9h	NUM
eurjchem-769	133	86	,	,	PUNCT
eurjchem-769	133	87	ar‐h	ar‐h	NOUN
eurjchem-769	133	88	)	)	PUNCT
eurjchem-769	133	89	.	.	PUNCT
eurjchem-769	134	1	anal	anal	PROPN
eurjchem-769	134	2	.	.	PUNCT
eurjchem-769	134	3	calcd	calcd	NOUN
eurjchem-769	134	4	.	.	PUNCT
eurjchem-769	135	1	for	for	ADP
eurjchem-769	135	2	c21h18n4o	c21h18n4o	NOUN
eurjchem-769	135	3	:	:	PUNCT
eurjchem-769	135	4	c	c	PROPN
eurjchem-769	135	5	73.67	73.67	NUM
eurjchem-769	135	6	,	,	PUNCT
eurjchem-769	135	7	h	h	NOUN
eurjchem-769	135	8	5.30	5.30	NUM
eurjchem-769	135	9	,	,	PUNCT
eurjchem-769	135	10	n	n	PRON
eurjchem-769	135	11	16.36	16.36	NUM
eurjchem-769	135	12	;	;	PUNCT
eurjchem-769	135	13	found	find	VERB
eurjchem-769	135	14	c	c	PROPN
eurjchem-769	135	15	73.71	73.71	NUM
eurjchem-769	135	16	,	,	PUNCT
eurjchem-769	135	17	h	h	NOUN
eurjchem-769	135	18	5.34	5.34	NUM
eurjchem-769	135	19	,	,	PUNCT
eurjchem-769	135	20	n	n	PRON
eurjchem-769	135	21	16.42	16.42	NUM
eurjchem-769	135	22	%	%	NOUN
eurjchem-769	135	23	.	.	PUNCT
eurjchem-769	136	1	452	452	NUM
eurjchem-769	136	2	sohal	sohal	NOUN
eurjchem-769	136	3	et	et	PROPN
eurjchem-769	136	4	al	al	PROPN
eurjchem-769	136	5	.	.	PUNCT
eurjchem-769	136	6	/	/	SYM
eurjchem-769	136	7	european	european	PROPN
eurjchem-769	136	8	journal	journal	PROPN
eurjchem-769	136	9	of	of	ADP
eurjchem-769	136	10	chemistry	chemistry	NOUN
eurjchem-769	136	11	4	4	NUM
eurjchem-769	136	12	(	(	PUNCT
eurjchem-769	136	13	4	4	NUM
eurjchem-769	136	14	)	)	PUNCT
eurjchem-769	136	15	(	(	PUNCT
eurjchem-769	136	16	2013	2013	NUM
eurjchem-769	136	17	)	)	PUNCT
eurjchem-769	137	1	450‐453	450‐453	NUM
eurjchem-769	137	2	table	table	NOUN
eurjchem-769	137	3	1	1	NUM
eurjchem-769	137	4	.	.	PUNCT
eurjchem-769	137	5	effect	effect	NOUN
eurjchem-769	137	6	of	of	ADP
eurjchem-769	137	7	solvent	solvent	NOUN
eurjchem-769	137	8	on	on	ADP
eurjchem-769	137	9	the	the	DET
eurjchem-769	137	10	synthesis	synthesis	NOUN
eurjchem-769	137	11	of	of	ADP
eurjchem-769	137	12	compounds	compound	NOUN
eurjchem-769	137	13	5a	5a	NUM
eurjchem-769	137	14	and	and	CCONJ
eurjchem-769	137	15	6a	6a	NOUN
eurjchem-769	137	16	.	.	PUNCT
eurjchem-769	138	1	product	product	NOUN
eurjchem-769	138	2	yield	yield	NOUN
eurjchem-769	138	3	,	,	PUNCT
eurjchem-769	138	4	%	%	NOUN
eurjchem-769	138	5	a	a	DET
eurjchem-769	138	6	etoh	etoh	NOUN
eurjchem-769	138	7	meoh	meoh	NOUN
eurjchem-769	138	8	glycerol	glycerol	NOUN
eurjchem-769	139	1	ch3cn	ch3cn	PROPN
eurjchem-769	139	2	5a	5a	NUM
eurjchem-769	139	3	87	87	NUM
eurjchem-769	139	4	88	88	NUM
eurjchem-769	139	5	93	93	NUM
eurjchem-769	139	6	80	80	NUM
eurjchem-769	139	7	6a	6a	NOUN
eurjchem-769	139	8	86	86	NUM
eurjchem-769	139	9	87	87	NUM
eurjchem-769	139	10	92	92	NUM
eurjchem-769	139	11	82	82	NUM
eurjchem-769	139	12	a	a	DET
eurjchem-769	139	13	yield	yield	NOUN
eurjchem-769	139	14	refers	refer	VERB
eurjchem-769	139	15	to	to	ADP
eurjchem-769	139	16	pure	pure	ADJ
eurjchem-769	139	17	isolated	isolated	ADJ
eurjchem-769	139	18	product	product	NOUN
eurjchem-769	139	19	.	.	PUNCT
eurjchem-769	140	1	scheme	scheme	NOUN
eurjchem-769	140	2	2	2	NUM
eurjchem-769	140	3	3	3	NUM
eurjchem-769	140	4	.	.	NOUN
eurjchem-769	140	5	results	result	NOUN
eurjchem-769	140	6	and	and	CCONJ
eurjchem-769	140	7	discussion	discussion	NOUN
eurjchem-769	140	8	at	at	ADP
eurjchem-769	140	9	first	first	ADV
eurjchem-769	140	10	,	,	PUNCT
eurjchem-769	140	11	reaction	reaction	NOUN
eurjchem-769	140	12	between	between	ADP
eurjchem-769	140	13	hydrazine	hydrazine	NOUN
eurjchem-769	140	14	1	1	NUM
eurjchem-769	140	15	,	,	PUNCT
eurjchem-769	140	16	ethyl	ethyl	PROPN
eurjchem-769	140	17	acetoacetate	acetoacetate	NOUN
eurjchem-769	140	18	2	2	NUM
eurjchem-769	140	19	,	,	PUNCT
eurjchem-769	140	20	benzaldehyde	benzaldehyde	NOUN
eurjchem-769	140	21	3	3	NUM
eurjchem-769	140	22	,	,	PUNCT
eurjchem-769	140	23	and	and	CCONJ
eurjchem-769	140	24	malononitrile	malononitrile	NOUN
eurjchem-769	140	25	4	4	NUM
eurjchem-769	140	26	,	,	PUNCT
eurjchem-769	140	27	was	be	AUX
eurjchem-769	140	28	carried	carry	VERB
eurjchem-769	140	29	out	out	ADP
eurjchem-769	140	30	as	as	ADP
eurjchem-769	140	31	a	a	DET
eurjchem-769	140	32	test	test	NOUN
eurjchem-769	140	33	reaction	reaction	NOUN
eurjchem-769	140	34	in	in	ADP
eurjchem-769	140	35	different	different	ADJ
eurjchem-769	140	36	solvents	solvent	NOUN
eurjchem-769	140	37	like	like	ADP
eurjchem-769	140	38	methanol	methanol	NOUN
eurjchem-769	140	39	,	,	PUNCT
eurjchem-769	140	40	ethanol	ethanol	NOUN
eurjchem-769	140	41	,	,	PUNCT
eurjchem-769	140	42	acetonitrile	acetonitrile	NOUN
eurjchem-769	140	43	and	and	CCONJ
eurjchem-769	140	44	glycerol	glycerol	NOUN
eurjchem-769	140	45	.	.	PUNCT
eurjchem-769	141	1	glycerol	glycerol	NOUN
eurjchem-769	141	2	as	as	ADP
eurjchem-769	141	3	solvent	solvent	NOUN
eurjchem-769	141	4	provides	provide	VERB
eurjchem-769	141	5	the	the	DET
eurjchem-769	141	6	good	good	ADJ
eurjchem-769	141	7	results	result	NOUN
eurjchem-769	141	8	as	as	SCONJ
eurjchem-769	141	9	compared	compare	VERB
eurjchem-769	141	10	to	to	ADP
eurjchem-769	141	11	other	other	ADJ
eurjchem-769	141	12	organic	organic	ADJ
eurjchem-769	141	13	solvents	solvent	NOUN
eurjchem-769	141	14	(	(	PUNCT
eurjchem-769	141	15	table	table	NOUN
eurjchem-769	141	16	1	1	NUM
eurjchem-769	141	17	)	)	PUNCT
eurjchem-769	141	18	.	.	PUNCT
eurjchem-769	142	1	in	in	ADP
eurjchem-769	142	2	a	a	DET
eurjchem-769	142	3	typical	typical	ADJ
eurjchem-769	142	4	experimental	experimental	ADJ
eurjchem-769	142	5	procedure	procedure	NOUN
eurjchem-769	142	6	,	,	PUNCT
eurjchem-769	142	7	a	a	DET
eurjchem-769	142	8	mixture	mixture	NOUN
eurjchem-769	142	9	of	of	ADP
eurjchem-769	142	10	hydrazine	hydrazine	NOUN
eurjchem-769	142	11	hydrate	hydrate	NOUN
eurjchem-769	142	12	(	(	PUNCT
eurjchem-769	142	13	10	10	NUM
eurjchem-769	142	14	mmol	mmol	NOUN
eurjchem-769	142	15	,	,	PUNCT
eurjchem-769	142	16	0.5	0.5	NUM
eurjchem-769	142	17	g	g	NOUN
eurjchem-769	142	18	)	)	PUNCT
eurjchem-769	142	19	1	1	NUM
eurjchem-769	142	20	,	,	PUNCT
eurjchem-769	142	21	ethyl	ethyl	PROPN
eurjchem-769	142	22	acetoacetate	acetoacetate	NOUN
eurjchem-769	142	23	(	(	PUNCT
eurjchem-769	142	24	10	10	NUM
eurjchem-769	142	25	mmol	mmol	NOUN
eurjchem-769	142	26	,	,	PUNCT
eurjchem-769	142	27	1.30	1.30	NUM
eurjchem-769	142	28	g	g	NOUN
eurjchem-769	142	29	)	)	PUNCT
eurjchem-769	142	30	2	2	NUM
eurjchem-769	142	31	,	,	PUNCT
eurjchem-769	142	32	benzaldehyde	benzaldehyde	NOUN
eurjchem-769	142	33	(	(	PUNCT
eurjchem-769	142	34	10	10	NUM
eurjchem-769	142	35	mmol	mmol	NOUN
eurjchem-769	142	36	,	,	PUNCT
eurjchem-769	142	37	1.06	1.06	NUM
eurjchem-769	142	38	g	g	NOUN
eurjchem-769	142	39	)	)	PUNCT
eurjchem-769	142	40	3	3	NUM
eurjchem-769	142	41	and	and	CCONJ
eurjchem-769	142	42	malononitrile	malononitrile	NOUN
eurjchem-769	142	43	(	(	PUNCT
eurjchem-769	142	44	10	10	NUM
eurjchem-769	142	45	mmol	mmol	NOUN
eurjchem-769	142	46	,	,	PUNCT
eurjchem-769	142	47	0.66	0.66	NUM
eurjchem-769	142	48	g	g	NOUN
eurjchem-769	142	49	)	)	PUNCT
eurjchem-769	142	50	4	4	NUM
eurjchem-769	142	51	were	be	AUX
eurjchem-769	142	52	added	add	VERB
eurjchem-769	142	53	in	in	ADP
eurjchem-769	142	54	glycerol	glycerol	NOUN
eurjchem-769	142	55	(	(	PUNCT
eurjchem-769	142	56	10	10	NUM
eurjchem-769	142	57	ml	ml	NOUN
eurjchem-769	142	58	)	)	PUNCT
eurjchem-769	142	59	and	and	CCONJ
eurjchem-769	142	60	stirred	stir	VERB
eurjchem-769	142	61	in	in	ADP
eurjchem-769	142	62	a	a	DET
eurjchem-769	142	63	pre‐heated	pre‐heated	ADJ
eurjchem-769	142	64	bath	bath	NOUN
eurjchem-769	142	65	at	at	ADP
eurjchem-769	142	66	80	80	NUM
eurjchem-769	142	67	°	°	NOUN
eurjchem-769	142	68	c	c	NOUN
eurjchem-769	142	69	.	.	PUNCT
eurjchem-769	143	1	after	after	ADP
eurjchem-769	143	2	the	the	DET
eurjchem-769	143	3	completion	completion	NOUN
eurjchem-769	143	4	of	of	ADP
eurjchem-769	143	5	reaction	reaction	NOUN
eurjchem-769	143	6	(	(	PUNCT
eurjchem-769	143	7	vide	vide	NOUN
eurjchem-769	143	8	tlc	tlc	PROPN
eurjchem-769	143	9	)	)	PUNCT
eurjchem-769	143	10	,	,	PUNCT
eurjchem-769	143	11	reaction	reaction	NOUN
eurjchem-769	143	12	mixture	mixture	NOUN
eurjchem-769	143	13	was	be	AUX
eurjchem-769	143	14	cooled	cool	VERB
eurjchem-769	143	15	to	to	ADP
eurjchem-769	143	16	room	room	NOUN
eurjchem-769	143	17	temperature	temperature	NOUN
eurjchem-769	143	18	and	and	CCONJ
eurjchem-769	143	19	water	water	NOUN
eurjchem-769	143	20	(	(	PUNCT
eurjchem-769	143	21	50	50	NUM
eurjchem-769	143	22	ml	ml	NOUN
eurjchem-769	143	23	)	)	PUNCT
eurjchem-769	143	24	was	be	AUX
eurjchem-769	143	25	added	add	VERB
eurjchem-769	143	26	.	.	PUNCT
eurjchem-769	144	1	solid	solid	ADJ
eurjchem-769	144	2	thus	thus	ADV
eurjchem-769	144	3	separated	separate	VERB
eurjchem-769	144	4	was	be	AUX
eurjchem-769	144	5	filtered	filter	VERB
eurjchem-769	144	6	and	and	CCONJ
eurjchem-769	144	7	dried	dry	VERB
eurjchem-769	144	8	,	,	PUNCT
eurjchem-769	144	9	recrystallized	recrystallize	VERB
eurjchem-769	144	10	from	from	ADP
eurjchem-769	144	11	ethanol	ethanol	NOUN
eurjchem-769	144	12	to	to	PART
eurjchem-769	144	13	afford	afford	VERB
eurjchem-769	144	14	5a	5a	NUM
eurjchem-769	144	15	,	,	PUNCT
eurjchem-769	144	16	6‐amino‐5‐	6‐amino‐5‐	NUM
eurjchem-769	144	17	cyano‐3‐methyl‐4‐phenyl‐1,4‐dihydropyrano[2,3‐c]pyrazole	cyano‐3‐methyl‐4‐phenyl‐1,4‐dihydropyrano[2,3‐c]pyrazole	NOUN
eurjchem-769	144	18	,	,	PUNCT
eurjchem-769	144	19	in	in	ADP
eurjchem-769	144	20	93	93	NUM
eurjchem-769	144	21	%	%	NOUN
eurjchem-769	144	22	yield	yield	NOUN
eurjchem-769	144	23	,	,	PUNCT
eurjchem-769	144	24	colorless	colorless	ADJ
eurjchem-769	144	25	crystals	crystal	NOUN
eurjchem-769	144	26	,	,	PUNCT
eurjchem-769	144	27	melting	melt	VERB
eurjchem-769	144	28	point	point	NOUN
eurjchem-769	145	1	243‐245	243‐245	NUM
eurjchem-769	145	2	°	°	SYM
eurjchem-769	145	3	c	c	NOUN
eurjchem-769	145	4	.	.	PUNCT
eurjchem-769	146	1	structure	structure	NOUN
eurjchem-769	146	2	of	of	ADP
eurjchem-769	146	3	compound	compound	NOUN
eurjchem-769	146	4	5a	5a	NUM
eurjchem-769	146	5	is	be	AUX
eurjchem-769	146	6	confirmed	confirm	VERB
eurjchem-769	146	7	by	by	ADP
eurjchem-769	146	8	advanced	advanced	ADJ
eurjchem-769	146	9	spectroscopic	spectroscopic	ADJ
eurjchem-769	146	10	techniques	technique	NOUN
eurjchem-769	146	11	.	.	PUNCT
eurjchem-769	147	1	in	in	ADP
eurjchem-769	147	2	1h	1h	NUM
eurjchem-769	147	3	nmr	nmr	NOUN
eurjchem-769	147	4	spectrum	spectrum	NOUN
eurjchem-769	147	5	,	,	PUNCT
eurjchem-769	147	6	singlet	singlet	NOUN
eurjchem-769	147	7	is	be	AUX
eurjchem-769	147	8	observed	observe	VERB
eurjchem-769	147	9	at	at	ADP
eurjchem-769	147	10	δ	δ	PROPN
eurjchem-769	147	11	12.16	12.16	NUM
eurjchem-769	147	12	ppm	ppm	NOUN
eurjchem-769	147	13	for	for	ADP
eurjchem-769	147	14	n‐h	n‐h	DET
eurjchem-769	147	15	proton	proton	NOUN
eurjchem-769	147	16	and	and	CCONJ
eurjchem-769	147	17	multiplet	multiplet	NOUN
eurjchem-769	147	18	for	for	ADP
eurjchem-769	147	19	five	five	NUM
eurjchem-769	147	20	aromatic	aromatic	ADJ
eurjchem-769	147	21	proton	proton	NOUN
eurjchem-769	147	22	of	of	ADP
eurjchem-769	147	23	phenyl	phenyl	NOUN
eurjchem-769	147	24	ring	ring	NOUN
eurjchem-769	147	25	is	be	AUX
eurjchem-769	147	26	observed	observe	VERB
eurjchem-769	147	27	between	between	ADP
eurjchem-769	147	28	δ	δ	PROPN
eurjchem-769	147	29	7.16‐7.45	7.16‐7.45	NUM
eurjchem-769	147	30	ppm	ppm	NOUN
eurjchem-769	147	31	and	and	CCONJ
eurjchem-769	147	32	for	for	ADP
eurjchem-769	147	33	nh2	nh2	PROPN
eurjchem-769	147	34	group	group	NOUN
eurjchem-769	147	35	,	,	PUNCT
eurjchem-769	147	36	a	a	DET
eurjchem-769	147	37	signal	signal	NOUN
eurjchem-769	147	38	is	be	AUX
eurjchem-769	147	39	observed	observe	VERB
eurjchem-769	147	40	at	at	ADP
eurjchem-769	147	41	δ	δ	PROPN
eurjchem-769	147	42	6.95	6.95	NUM
eurjchem-769	147	43	ppm	ppm	NOUN
eurjchem-769	147	44	and	and	CCONJ
eurjchem-769	147	45	a	a	DET
eurjchem-769	147	46	singlet	singlet	NOUN
eurjchem-769	147	47	observed	observe	VERB
eurjchem-769	147	48	at	at	ADP
eurjchem-769	147	49	δ	δ	PROPN
eurjchem-769	147	50	1.80	1.80	NUM
eurjchem-769	147	51	ppm	ppm	NOUN
eurjchem-769	147	52	represented	represent	VERB
eurjchem-769	147	53	‐ch3	‐ch3	PROPN
eurjchem-769	147	54	group	group	NOUN
eurjchem-769	147	55	.	.	PUNCT
eurjchem-769	148	1	in	in	ADP
eurjchem-769	148	2	ir	ir	PROPN
eurjchem-769	148	3	spectrum	spectrum	NOUN
eurjchem-769	148	4	,	,	PUNCT
eurjchem-769	148	5	n‐h	n‐h	DET
eurjchem-769	148	6	stretching	stretch	VERB
eurjchem-769	148	7	is	be	AUX
eurjchem-769	148	8	observed	observe	VERB
eurjchem-769	148	9	at	at	ADP
eurjchem-769	148	10	3370	3370	NUM
eurjchem-769	148	11	cm‐1	cm‐1	NOUN
eurjchem-769	148	12	and	and	CCONJ
eurjchem-769	148	13	cn	cn	PROPN
eurjchem-769	148	14	stretching	stretching	NOUN
eurjchem-769	148	15	is	be	AUX
eurjchem-769	148	16	observed	observe	VERB
eurjchem-769	148	17	at	at	ADP
eurjchem-769	148	18	2195	2195	NUM
eurjchem-769	148	19	cm‐1	cm‐1	NOUN
eurjchem-769	148	20	.	.	PUNCT
eurjchem-769	149	1	to	to	PART
eurjchem-769	149	2	check	check	VERB
eurjchem-769	149	3	the	the	DET
eurjchem-769	149	4	versatility	versatility	NOUN
eurjchem-769	149	5	of	of	ADP
eurjchem-769	149	6	this	this	DET
eurjchem-769	149	7	process	process	NOUN
eurjchem-769	149	8	,	,	PUNCT
eurjchem-769	149	9	we	we	PRON
eurjchem-769	149	10	have	have	AUX
eurjchem-769	149	11	reacted	react	VERB
eurjchem-769	149	12	hydrazine	hydrazine	NOUN
eurjchem-769	149	13	hydrate	hydrate	NOUN
eurjchem-769	149	14	/	/	SYM
eurjchem-769	149	15	phenyl	phenyl	NOUN
eurjchem-769	149	16	hydrazine	hydrazine	NOUN
eurjchem-769	149	17	,	,	PUNCT
eurjchem-769	149	18	ethylacetoacetate	ethylacetoacetate	NOUN
eurjchem-769	149	19	,	,	PUNCT
eurjchem-769	149	20	and	and	CCONJ
eurjchem-769	149	21	malononitrile	malononitrile	NOUN
eurjchem-769	149	22	with	with	ADP
eurjchem-769	149	23	different	different	ADJ
eurjchem-769	149	24	aldehydes	aldehyde	NOUN
eurjchem-769	149	25	and	and	CCONJ
eurjchem-769	149	26	results	result	NOUN
eurjchem-769	149	27	are	be	AUX
eurjchem-769	149	28	summarized	summarize	VERB
eurjchem-769	149	29	in	in	ADP
eurjchem-769	149	30	table	table	NOUN
eurjchem-769	149	31	2	2	NUM
eurjchem-769	149	32	.	.	PUNCT
eurjchem-769	150	1	reactions	reaction	NOUN
eurjchem-769	150	2	proceed	proceed	VERB
eurjchem-769	150	3	smoothly	smoothly	ADV
eurjchem-769	150	4	with	with	ADP
eurjchem-769	150	5	aldehydes	aldehyde	NOUN
eurjchem-769	150	6	bearing	bear	VERB
eurjchem-769	150	7	electron	electron	NOUN
eurjchem-769	150	8	withdrawing	withdraw	VERB
eurjchem-769	150	9	as	as	ADV
eurjchem-769	150	10	well	well	ADV
eurjchem-769	150	11	as	as	ADP
eurjchem-769	150	12	electron	electron	NOUN
eurjchem-769	150	13	donating	donate	VERB
eurjchem-769	150	14	substituents	substituent	NOUN
eurjchem-769	150	15	(	(	PUNCT
eurjchem-769	150	16	table	table	NOUN
eurjchem-769	150	17	2	2	NUM
eurjchem-769	150	18	)	)	PUNCT
eurjchem-769	150	19	.	.	PUNCT
eurjchem-769	151	1	this	this	DET
eurjchem-769	151	2	method	method	NOUN
eurjchem-769	151	3	tolerates	tolerate	VERB
eurjchem-769	151	4	various	various	ADJ
eurjchem-769	151	5	functionalities	functionality	NOUN
eurjchem-769	151	6	like	like	ADP
eurjchem-769	151	7	nitro	nitro	NOUN
eurjchem-769	151	8	,	,	PUNCT
eurjchem-769	151	9	ether	ether	NOUN
eurjchem-769	151	10	,	,	PUNCT
eurjchem-769	151	11	halogen	halogen	PROPN
eurjchem-769	151	12	etc	etc	X
eurjchem-769	151	13	.	.	X
eurjchem-769	151	14	on	on	ADP
eurjchem-769	151	15	the	the	DET
eurjchem-769	151	16	aldehydes	aldehyde	NOUN
eurjchem-769	151	17	.	.	PUNCT
eurjchem-769	152	1	efficacy	efficacy	NOUN
eurjchem-769	152	2	of	of	ADP
eurjchem-769	152	3	this	this	DET
eurjchem-769	152	4	method	method	NOUN
eurjchem-769	152	5	is	be	AUX
eurjchem-769	152	6	fairly	fairly	ADV
eurjchem-769	152	7	general	general	ADJ
eurjchem-769	152	8	and	and	CCONJ
eurjchem-769	152	9	afforded	afford	VERB
eurjchem-769	152	10	the	the	DET
eurjchem-769	152	11	resultant	resultant	NOUN
eurjchem-769	152	12	products	product	NOUN
eurjchem-769	152	13	in	in	ADP
eurjchem-769	152	14	excellent	excellent	ADJ
eurjchem-769	152	15	yield	yield	NOUN
eurjchem-769	152	16	and	and	CCONJ
eurjchem-769	152	17	products	product	NOUN
eurjchem-769	152	18	are	be	AUX
eurjchem-769	152	19	obtained	obtain	VERB
eurjchem-769	152	20	by	by	ADP
eurjchem-769	152	21	simple	simple	ADJ
eurjchem-769	152	22	work	work	NOUN
eurjchem-769	152	23	up	up	ADP
eurjchem-769	152	24	.	.	PUNCT
eurjchem-769	153	1	taking	take	VERB
eurjchem-769	153	2	into	into	ADP
eurjchem-769	153	3	account	account	NOUN
eurjchem-769	153	4	the	the	DET
eurjchem-769	153	5	reports	report	NOUN
eurjchem-769	153	6	of	of	ADP
eurjchem-769	153	7	the	the	DET
eurjchem-769	153	8	literature	literature	NOUN
eurjchem-769	153	9	[	[	X
eurjchem-769	153	10	32	32	NUM
eurjchem-769	153	11	]	]	PUNCT
eurjchem-769	153	12	,	,	PUNCT
eurjchem-769	153	13	we	we	PRON
eurjchem-769	153	14	have	have	AUX
eurjchem-769	153	15	proposed	propose	VERB
eurjchem-769	153	16	a	a	DET
eurjchem-769	153	17	route	route	NOUN
eurjchem-769	153	18	(	(	PUNCT
eurjchem-769	153	19	scheme	scheme	NOUN
eurjchem-769	153	20	2	2	NUM
eurjchem-769	153	21	)	)	PUNCT
eurjchem-769	153	22	for	for	ADP
eurjchem-769	153	23	the	the	DET
eurjchem-769	153	24	formation	formation	NOUN
eurjchem-769	153	25	of	of	ADP
eurjchem-769	153	26	compound	compound	NOUN
eurjchem-769	153	27	5	5	NUM
eurjchem-769	153	28	and	and	CCONJ
eurjchem-769	153	29	6	6	NUM
eurjchem-769	153	30	.	.	PUNCT
eurjchem-769	154	1	in	in	ADP
eurjchem-769	154	2	the	the	DET
eurjchem-769	154	3	first	first	ADJ
eurjchem-769	154	4	step	step	NOUN
eurjchem-769	154	5	,	,	PUNCT
eurjchem-769	154	6	condensation	condensation	NOUN
eurjchem-769	154	7	of	of	ADP
eurjchem-769	154	8	hydrazine	hydrazine	NOUN
eurjchem-769	154	9	and	and	CCONJ
eurjchem-769	154	10	ethylacetoacetate	ethylacetoacetate	VERB
eurjchem-769	154	11	take	take	VERB
eurjchem-769	154	12	place	place	NOUN
eurjchem-769	154	13	to	to	PART
eurjchem-769	154	14	form	form	VERB
eurjchem-769	154	15	7	7	NUM
eurjchem-769	154	16	and	and	CCONJ
eurjchem-769	154	17	knoevenagal	knoevenagal	ADJ
eurjchem-769	154	18	condensation	condensation	NOUN
eurjchem-769	154	19	take	take	VERB
eurjchem-769	154	20	place	place	NOUN
eurjchem-769	154	21	between	between	ADP
eurjchem-769	154	22	malononitrile	malononitrile	NOUN
eurjchem-769	154	23	and	and	CCONJ
eurjchem-769	154	24	aldehyde	aldehyde	NOUN
eurjchem-769	154	25	to	to	PART
eurjchem-769	154	26	form	form	VERB
eurjchem-769	154	27	arylidenepropanedinitrile	arylidenepropanedinitrile	NOUN
eurjchem-769	154	28	8	8	NUM
eurjchem-769	154	29	,	,	PUNCT
eurjchem-769	154	30	then	then	ADV
eurjchem-769	154	31	the	the	DET
eurjchem-769	154	32	michael	michael	PROPN
eurjchem-769	154	33	addition	addition	NOUN
eurjchem-769	154	34	of	of	ADP
eurjchem-769	154	35	compound	compound	NOUN
eurjchem-769	154	36	7	7	NUM
eurjchem-769	154	37	to	to	PART
eurjchem-769	154	38	8	8	NUM
eurjchem-769	154	39	occur	occur	VERB
eurjchem-769	154	40	to	to	PART
eurjchem-769	154	41	form	form	VERB
eurjchem-769	154	42	9	9	NUM
eurjchem-769	154	43	.	.	PUNCT
eurjchem-769	155	1	then	then	ADV
eurjchem-769	155	2	attack	attack	NOUN
eurjchem-769	155	3	of	of	ADP
eurjchem-769	155	4	nucleophilic	nucleophilic	ADJ
eurjchem-769	155	5	oxygen	oxygen	NOUN
eurjchem-769	155	6	of	of	ADP
eurjchem-769	155	7	9	9	NUM
eurjchem-769	155	8	on	on	ADP
eurjchem-769	155	9	cn	cn	PROPN
eurjchem-769	155	10	take	take	VERB
eurjchem-769	155	11	place	place	NOUN
eurjchem-769	155	12	to	to	PART
eurjchem-769	155	13	form	form	VERB
eurjchem-769	155	14	desired	desire	VERB
eurjchem-769	155	15	product	product	NOUN
eurjchem-769	155	16	5	5	NUM
eurjchem-769	155	17	or	or	CCONJ
eurjchem-769	155	18	6	6	NUM
eurjchem-769	155	19	.	.	NOUN
eurjchem-769	155	20	4	4	NUM
eurjchem-769	155	21	.	.	X
eurjchem-769	155	22	conclusion	conclusion	NOUN
eurjchem-769	155	23	in	in	ADP
eurjchem-769	155	24	conclusion	conclusion	NOUN
eurjchem-769	155	25	,	,	PUNCT
eurjchem-769	155	26	the	the	DET
eurjchem-769	155	27	present	present	ADJ
eurjchem-769	155	28	work	work	NOUN
eurjchem-769	155	29	provides	provide	VERB
eurjchem-769	155	30	an	an	DET
eurjchem-769	155	31	excellent	excellent	ADJ
eurjchem-769	155	32	route	route	NOUN
eurjchem-769	155	33	for	for	ADP
eurjchem-769	155	34	the	the	DET
eurjchem-769	155	35	production	production	NOUN
eurjchem-769	155	36	of	of	ADP
eurjchem-769	155	37	6‐amino‐4‐(aryl)‐3‐methyl‐1,4‐	6‐amino‐4‐(aryl)‐3‐methyl‐1,4‐	NUM
eurjchem-769	155	38	dihydropyrano[2,3‐c]pyrazole‐5‐carbonitrile	dihydropyrano[2,3‐c]pyrazole‐5‐carbonitrile	NOUN
eurjchem-769	155	39	and	and	CCONJ
eurjchem-769	155	40	6‐amino‐4‐	6‐amino‐4‐	NOUN
eurjchem-769	155	41	(	(	PUNCT
eurjchem-769	155	42	aryl)‐3‐methyl‐1‐phenyl‐1,4‐dihydropyrano[2,3‐c]pyrazole‐5‐	aryl)‐3‐methyl‐1‐phenyl‐1,4‐dihydropyrano[2,3‐c]pyrazole‐5‐	PROPN
eurjchem-769	155	43	carbonitrile	carbonitrile	VERB
eurjchem-769	155	44	without	without	ADP
eurjchem-769	155	45	use	use	NOUN
eurjchem-769	155	46	of	of	ADP
eurjchem-769	155	47	any	any	DET
eurjchem-769	155	48	hazardous	hazardous	ADJ
eurjchem-769	155	49	reagent	reagent	NOUN
eurjchem-769	155	50	.	.	PUNCT
eurjchem-769	156	1	in	in	ADP
eurjchem-769	156	2	addition	addition	NOUN
eurjchem-769	156	3	,	,	PUNCT
eurjchem-769	156	4	use	use	NOUN
eurjchem-769	156	5	of	of	ADP
eurjchem-769	156	6	environmentally	environmentally	ADV
eurjchem-769	156	7	benign	benign	ADJ
eurjchem-769	156	8	,	,	PUNCT
eurjchem-769	156	9	economical	economical	ADJ
eurjchem-769	156	10	and	and	CCONJ
eurjchem-769	156	11	easily	easily	ADV
eurjchem-769	156	12	available	available	ADJ
eurjchem-769	156	13	glycerol	glycerol	NOUN
eurjchem-769	156	14	as	as	SCONJ
eurjchem-769	156	15	solvent	solvent	NOUN
eurjchem-769	156	16	proves	prove	VERB
eurjchem-769	156	17	the	the	DET
eurjchem-769	156	18	merit	merit	NOUN
eurjchem-769	156	19	of	of	ADP
eurjchem-769	156	20	this	this	DET
eurjchem-769	156	21	protocol	protocol	NOUN
eurjchem-769	156	22	.	.	PUNCT
eurjchem-769	157	1	the	the	DET
eurjchem-769	157	2	targeted	target	VERB
eurjchem-769	157	3	molecules	molecule	NOUN
eurjchem-769	157	4	are	be	AUX
eurjchem-769	157	5	obtained	obtain	VERB
eurjchem-769	157	6	in	in	ADP
eurjchem-769	157	7	excellent	excellent	ADJ
eurjchem-769	157	8	yield	yield	NOUN
eurjchem-769	157	9	(	(	PUNCT
eurjchem-769	157	10	86‐93	86‐93	NUM
eurjchem-769	157	11	%	%	NOUN
eurjchem-769	157	12	)	)	PUNCT
eurjchem-769	157	13	without	without	ADP
eurjchem-769	157	14	any	any	DET
eurjchem-769	157	15	side	side	NOUN
eurjchem-769	157	16	product	product	NOUN
eurjchem-769	157	17	.	.	PUNCT
eurjchem-769	158	1	acknowledgements	acknowledgement	NOUN
eurjchem-769	158	2	the	the	DET
eurjchem-769	158	3	authors	author	NOUN
eurjchem-769	158	4	thank	thank	VERB
eurjchem-769	158	5	university	university	PROPN
eurjchem-769	158	6	grants	grant	NOUN
eurjchem-769	158	7	commission	commission	PROPN
eurjchem-769	158	8	,	,	PUNCT
eurjchem-769	158	9	new	new	PROPN
eurjchem-769	158	10	delhi	delhi	PROPN
eurjchem-769	158	11	,	,	PUNCT
eurjchem-769	158	12	india	india	PROPN
eurjchem-769	158	13	for	for	ADP
eurjchem-769	158	14	the	the	DET
eurjchem-769	158	15	financial	financial	ADJ
eurjchem-769	158	16	support	support	NOUN
eurjchem-769	158	17	(	(	PUNCT
eurjchem-769	158	18	sanction	sanction	NOUN
eurjchem-769	158	19	no	no	NOUN
eurjchem-769	158	20	.	.	PUNCT
eurjchem-769	158	21	f.no.8‐2	f.no.8‐2	PUNCT
eurjchem-769	158	22	(	(	PUNCT
eurjchem-769	158	23	52)/2011	52)/2011	NUM
eurjchem-769	158	24	(	(	PUNCT
eurjchem-769	158	25	mrp	mrp	NOUN
eurjchem-769	158	26	/	/	SYM
eurjchem-769	158	27	ncrb	ncrb	NOUN
eurjchem-769	158	28	)	)	PUNCT
eurjchem-769	158	29	)	)	PUNCT
eurjchem-769	158	30	.	.	PUNCT
eurjchem-769	159	1	sohal	sohal	VERB
eurjchem-769	159	2	et	et	PROPN
eurjchem-769	159	3	al	al	PROPN
eurjchem-769	159	4	.	.	PUNCT
eurjchem-769	159	5	/	/	SYM
eurjchem-769	159	6	european	european	PROPN
eurjchem-769	159	7	journal	journal	PROPN
eurjchem-769	159	8	of	of	ADP
eurjchem-769	159	9	chemistry	chemistry	NOUN
eurjchem-769	159	10	4	4	NUM
eurjchem-769	159	11	(	(	PUNCT
eurjchem-769	159	12	4	4	NUM
eurjchem-769	159	13	)	)	PUNCT
eurjchem-769	159	14	(	(	PUNCT
eurjchem-769	159	15	2013	2013	NUM
eurjchem-769	159	16	)	)	PUNCT
eurjchem-769	159	17	450‐453	450‐453	NOUN
eurjchem-769	159	18	453	453	NUM
eurjchem-769	159	19	table	table	NOUN
eurjchem-769	159	20	2	2	NUM
eurjchem-769	159	21	.	.	PUNCT
eurjchem-769	159	22	synthesis	synthesis	NOUN
eurjchem-769	159	23	of	of	ADP
eurjchem-769	159	24	1,4‐dihydropyrano[2,3‐c]pyrazole	1,4‐dihydropyrano[2,3‐c]pyrazole	ADJ
eurjchem-769	159	25	derivative	derivative	NOUN
eurjchem-769	159	26	.	.	PUNCT
eurjchem-769	160	1	sample	sample	NOUN
eurjchem-769	160	2	no	no	DET
eurjchem-769	160	3	product	product	NOUN
eurjchem-769	160	4	a	a	DET
eurjchem-769	160	5	r1	r1	NOUN
eurjchem-769	160	6	r	r	NOUN
eurjchem-769	160	7	yield	yield	NOUN
eurjchem-769	160	8	(	(	PUNCT
eurjchem-769	160	9	%	%	INTJ
eurjchem-769	160	10	)	)	PUNCT
eurjchem-769	160	11	b	b	NOUN
eurjchem-769	160	12	melting	melting	NOUN
eurjchem-769	160	13	point	point	NOUN
eurjchem-769	160	14	(	(	PUNCT
eurjchem-769	160	15	°	°	ADP
eurjchem-769	160	16	c	c	NOUN
eurjchem-769	160	17	)	)	PUNCT
eurjchem-769	160	18	1	1	NUM
eurjchem-769	160	19	5a	5a	NUM
eurjchem-769	160	20	c6h5	c6h5	NOUN
eurjchem-769	160	21	h	h	NOUN
eurjchem-769	160	22	93	93	NUM
eurjchem-769	160	23	243‐245	243‐245	NUM
eurjchem-769	160	24	2	2	NUM
eurjchem-769	160	25	5b	5b	NUM
eurjchem-769	160	26	4‐cl	4‐cl	NUM
eurjchem-769	160	27	c6h5	c6h5	NOUN
eurjchem-769	160	28	h	h	NOUN
eurjchem-769	160	29	92	92	NUM
eurjchem-769	160	30	233‐235	233‐235	NUM
eurjchem-769	160	31	3	3	NUM
eurjchem-769	160	32	5c	5c	NUM
eurjchem-769	160	33	2‐cl	2‐cl	NUM
eurjchem-769	160	34	c6h5	c6h5	NOUN
eurjchem-769	160	35	h	h	NOUN
eurjchem-769	160	36	90	90	NUM
eurjchem-769	160	37	246‐248	246‐248	NUM
eurjchem-769	160	38	4	4	NUM
eurjchem-769	160	39	5d	5d	NUM
eurjchem-769	161	1	4‐no2c6h5	4‐no2c6h5	PROPN
eurjchem-769	161	2	h	h	NOUN
eurjchem-769	161	3	92	92	NUM
eurjchem-769	161	4	249‐252	249‐252	NUM
eurjchem-769	161	5	5	5	NUM
eurjchem-769	161	6	5e	5e	NOUN
eurjchem-769	161	7	2‐no2c6h5	2‐no2c6h5	NUM
eurjchem-769	161	8	h	h	NOUN
eurjchem-769	161	9	86	86	NUM
eurjchem-769	161	10	210‐212	210‐212	NUM
eurjchem-769	161	11	6	6	NUM
eurjchem-769	161	12	5f	5f	NOUN
eurjchem-769	161	13	3‐no2c6h5	3‐no2c6h5	PROPN
eurjchem-769	161	14	h	h	NOUN
eurjchem-769	162	1	90	90	NUM
eurjchem-769	162	2	218‐220	218‐220	NUM
eurjchem-769	162	3	7	7	NUM
eurjchem-769	162	4	5	5	NUM
eurjchem-769	162	5	g	g	NOUN
eurjchem-769	162	6	4‐ohc6h5	4‐ohc6h5	NUM
eurjchem-769	162	7	h	h	NOUN
eurjchem-769	162	8	90	90	NUM
eurjchem-769	162	9	202‐204	202‐204	NUM
eurjchem-769	162	10	8	8	NUM
eurjchem-769	162	11	5h	5h	NUM
eurjchem-769	162	12	4‐omec6h5	4‐omec6h5	PROPN
eurjchem-769	162	13	h	h	NOUN
eurjchem-769	162	14	92	92	NUM
eurjchem-769	162	15	208‐210	208‐210	NUM
eurjchem-769	162	16	9	9	NUM
eurjchem-769	162	17	5i	5i	NUM
eurjchem-769	162	18	c6h5ch	c6h5ch	NOUN
eurjchem-769	162	19	=	=	NOUN
eurjchem-769	162	20	ch	ch	NOUN
eurjchem-769	162	21	h	h	NOUN
eurjchem-769	162	22	88	88	NUM
eurjchem-769	162	23	200‐202	200‐202	NUM
eurjchem-769	162	24	10	10	NUM
eurjchem-769	162	25	5j	5j	NUM
eurjchem-769	162	26	4‐mec6h5	4‐mec6h5	NUM
eurjchem-769	162	27	h	h	NOUN
eurjchem-769	162	28	89	89	NUM
eurjchem-769	162	29	240‐242	240‐242	NUM
eurjchem-769	162	30	11	11	NUM
eurjchem-769	162	31	6a	6a	NOUN
eurjchem-769	162	32	c6h5	c6h5	NOUN
eurjchem-769	162	33	ph	ph	VERB
eurjchem-769	162	34	92	92	NUM
eurjchem-769	162	35	169‐170	169‐170	NUM
eurjchem-769	162	36	12	12	NUM
eurjchem-769	162	37	6b	6b	NOUN
eurjchem-769	162	38	4‐cl	4‐cl	NUM
eurjchem-769	162	39	c6h5	c6h5	NOUN
eurjchem-769	162	40	ph	ph	PROPN
eurjchem-769	162	41	91	91	NUM
eurjchem-769	162	42	175‐176	175‐176	NUM
eurjchem-769	162	43	13	13	NUM
eurjchem-769	162	44	6c	6c	NOUN
eurjchem-769	162	45	2‐cl	2‐cl	NUM
eurjchem-769	162	46	c6h5	c6h5	NOUN
eurjchem-769	162	47	ph	ph	PROPN
eurjchem-769	162	48	88	88	NUM
eurjchem-769	162	49	143‐145	143‐145	NUM
eurjchem-769	162	50	14	14	NUM
eurjchem-769	162	51	6d	6d	NUM
eurjchem-769	162	52	4‐no2c6h5	4‐no2c6h5	NUM
eurjchem-769	162	53	ph	ph	PROPN
eurjchem-769	162	54	87	87	NUM
eurjchem-769	162	55	195‐197	195‐197	NUM
eurjchem-769	162	56	15	15	NUM
eurjchem-769	162	57	6e	6e	NUM
eurjchem-769	162	58	2‐no2c6h5	2‐no2c6h5	NUM
eurjchem-769	162	59	ph	ph	NOUN
eurjchem-769	162	60	89	89	NUM
eurjchem-769	162	61	199‐200	199‐200	NUM
eurjchem-769	162	62	16	16	NUM
eurjchem-769	162	63	6f	6f	NUM
eurjchem-769	162	64	3‐no2c6h5	3‐no2c6h5	PROPN
eurjchem-769	162	65	ph	ph	NOUN
eurjchem-769	162	66	91	91	NUM
eurjchem-769	162	67	191‐193	191‐193	NUM
eurjchem-769	162	68	17	17	NUM
eurjchem-769	162	69	6	6	NUM
eurjchem-769	162	70	g	g	NOUN
eurjchem-769	162	71	4‐ohc6h5	4‐ohc6h5	NUM
eurjchem-769	162	72	ph	ph	NOUN
eurjchem-769	162	73	90	90	NUM
eurjchem-769	162	74	209‐211	209‐211	NUM
eurjchem-769	162	75	18	18	NUM
eurjchem-769	162	76	6h	6h	NUM
eurjchem-769	162	77	4‐omec6h5	4‐omec6h5	NOUN
eurjchem-769	162	78	ph	ph	PROPN
eurjchem-769	162	79	92	92	NUM
eurjchem-769	162	80	175‐177	175‐177	NUM
eurjchem-769	162	81	19	19	NUM
eurjchem-769	162	82	6i	6i	NUM
eurjchem-769	162	83	c6h5ch	c6h5ch	NOUN
eurjchem-769	162	84	=	=	NOUN
eurjchem-769	162	85	ch	ch	NOUN
eurjchem-769	162	86	ph	ph	NOUN
eurjchem-769	162	87	87	87	NUM
eurjchem-769	162	88	140‐142	140‐142	NUM
eurjchem-769	162	89	20	20	NUM
eurjchem-769	162	90	6j	6j	NOUN
eurjchem-769	163	1	4‐ch3c6h4	4‐ch3c6h4	PRON
eurjchem-769	163	2	ph	ph	VERB
eurjchem-769	163	3	89	89	NUM
eurjchem-769	163	4	176‐177	176‐177	NUM
eurjchem-769	163	5	a	a	DET
eurjchem-769	163	6	products	product	NOUN
eurjchem-769	163	7	were	be	AUX
eurjchem-769	163	8	characterized	characterize	VERB
eurjchem-769	163	9	with	with	ADP
eurjchem-769	163	10	spectral	spectral	ADJ
eurjchem-769	163	11	techniques	technique	NOUN
eurjchem-769	163	12	and	and	CCONJ
eurjchem-769	163	13	compared	compare	VERB
eurjchem-769	163	14	with	with	ADP
eurjchem-769	163	15	authentic	authentic	ADJ
eurjchem-769	163	16	samples	sample	NOUN
eurjchem-769	163	17	.	.	PUNCT
eurjchem-769	164	1	b	b	X
eurjchem-769	164	2	yield	yield	NOUN
eurjchem-769	164	3	refers	refer	VERB
eurjchem-769	164	4	to	to	ADP
eurjchem-769	164	5	pure	pure	ADJ
eurjchem-769	164	6	isolated	isolated	ADJ
eurjchem-769	164	7	product	product	NOUN
eurjchem-769	164	8	.	.	PUNCT
eurjchem-769	165	1	references	reference	NOUN
eurjchem-769	165	2	[	[	X
eurjchem-769	165	3	1	1	NUM
eurjchem-769	165	4	]	]	PUNCT
eurjchem-769	165	5	.	.	PUNCT
eurjchem-769	166	1	handy	handy	ADJ
eurjchem-769	166	2	,	,	PUNCT
eurjchem-769	166	3	s.	s.	PROPN
eurjchem-769	166	4	t.	t.	PROPN
eurjchem-769	166	5	chem	chem	PROPN
eurjchem-769	166	6	.	.	PUNCT
eurjchem-769	167	1	eur	eur	PROPN
eurjchem-769	167	2	.	.	PUNCT
eurjchem-769	168	1	j.	j.	PROPN
eurjchem-769	168	2	2003	2003	NUM
eurjchem-769	168	3	,	,	PUNCT
eurjchem-769	168	4	9	9	NUM
eurjchem-769	168	5	,	,	PUNCT
eurjchem-769	168	6	2938‐2944	2938‐2944	NUM
eurjchem-769	168	7	.	.	PUNCT
eurjchem-769	169	1	[	[	X
eurjchem-769	169	2	2	2	NUM
eurjchem-769	169	3	]	]	PUNCT
eurjchem-769	169	4	.	.	PUNCT
eurjchem-769	169	5	leitner	leitner	NOUN
eurjchem-769	169	6	,	,	PUNCT
eurjchem-769	169	7	w.	w.	PROPN
eurjchem-769	169	8	green	green	PROPN
eurjchem-769	169	9	chem	chem	PROPN
eurjchem-769	169	10	.	.	PUNCT
eurjchem-769	170	1	2007	2007	NUM
eurjchem-769	170	2	,	,	PUNCT
eurjchem-769	170	3	9	9	NUM
eurjchem-769	170	4	,	,	PUNCT
eurjchem-769	170	5	923‐923	923‐923	NUM
eurjchem-769	170	6	.	.	PUNCT
eurjchem-769	171	1	[	[	X
eurjchem-769	171	2	3	3	NUM
eurjchem-769	171	3	]	]	PUNCT
eurjchem-769	171	4	.	.	PUNCT
eurjchem-769	172	1	horváth	horváth	PROPN
eurjchem-769	172	2	,	,	PUNCT
eurjchem-769	172	3	i.	i.	PROPN
eurjchem-769	172	4	t.	t.	PROPN
eurjchem-769	172	5	green	green	PROPN
eurjchem-769	172	6	chem	chem	PROPN
eurjchem-769	172	7	.	.	PUNCT
eurjchem-769	173	1	2008	2008	NUM
eurjchem-769	173	2	,	,	PUNCT
eurjchem-769	173	3	10	10	NUM
eurjchem-769	173	4	,	,	PUNCT
eurjchem-769	173	5	1024‐1028	1024‐1028	NUM
eurjchem-769	173	6	.	.	PUNCT
eurjchem-769	174	1	[	[	X
eurjchem-769	174	2	4	4	NUM
eurjchem-769	174	3	]	]	PUNCT
eurjchem-769	174	4	.	.	PUNCT
eurjchem-769	175	1	giovanni	giovanni	PROPN
eurjchem-769	175	2	,	,	PUNCT
eurjchem-769	175	3	i.	i.	NOUN
eurjchem-769	175	4	;	;	PUNCT
eurjchem-769	175	5	silke	silke	NOUN
eurjchem-769	175	6	,	,	PUNCT
eurjchem-769	175	7	h.	h.	NOUN
eurjchem-769	175	8	;	;	PUNCT
eurjchem-769	175	9	dieter	dieter	NOUN
eurjchem-769	175	10	,	,	PUNCT
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eurjchem-769	175	12	;	;	PUNCT
eurjchem-769	175	13	burkhard	burkhard	PROPN
eurjchem-769	175	14	,	,	PUNCT
eurjchem-769	175	15	k.	k.	PROPN
eurjchem-769	175	16	green	green	PROPN
eurjchem-769	175	17	chem	chem	PROPN
eurjchem-769	175	18	.	.	PUNCT
eurjchem-769	176	1	2006	2006	NUM
eurjchem-769	176	2	,	,	PUNCT
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eurjchem-769	176	4	,	,	PUNCT
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eurjchem-769	176	6	.	.	PUNCT
eurjchem-769	177	1	[	[	X
eurjchem-769	177	2	5	5	NUM
eurjchem-769	177	3	]	]	PUNCT
eurjchem-769	177	4	.	.	PUNCT
eurjchem-769	178	1	clark	clark	PROPN
eurjchem-769	178	2	,	,	PUNCT
eurjchem-769	178	3	j.	j.	PROPN
eurjchem-769	178	4	h.	h.	PROPN
eurjchem-769	178	5	green	green	PROPN
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eurjchem-769	178	7	.	.	PUNCT
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eurjchem-769	179	2	,	,	PUNCT
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eurjchem-769	179	4	,	,	PUNCT
eurjchem-769	179	5	1‐8	1‐8	NOUN
eurjchem-769	179	6	.	.	PUNCT
eurjchem-769	180	1	[	[	X
eurjchem-769	180	2	6	6	NUM
eurjchem-769	180	3	]	]	PUNCT
eurjchem-769	180	4	.	.	PUNCT
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eurjchem-769	181	2	,	,	PUNCT
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eurjchem-769	181	5	;	;	PUNCT
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eurjchem-769	181	7	,	,	PUNCT
eurjchem-769	181	8	c.	c.	PROPN
eurjchem-769	181	9	j.	j.	PROPN
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eurjchem-769	181	11	.	.	PUNCT
eurjchem-769	182	1	soc	soc	PROPN
eurjchem-769	182	2	.	.	PUNCT
eurjchem-769	183	1	rev	rev	PROPN
eurjchem-769	183	2	.	.	PROPN
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eurjchem-769	183	4	,	,	PUNCT
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eurjchem-769	183	6	,	,	PUNCT
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eurjchem-769	183	8	.	.	PUNCT
eurjchem-769	184	1	[	[	X
eurjchem-769	184	2	7	7	NUM
eurjchem-769	184	3	]	]	PUNCT
eurjchem-769	184	4	.	.	PUNCT
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eurjchem-769	184	6	,	,	PUNCT
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eurjchem-769	184	9	;	;	PUNCT
eurjchem-769	184	10	coyne	coyne	PROPN
eurjchem-769	184	11	,	,	PUNCT
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eurjchem-769	184	13	g.	g.	PROPN
eurjchem-769	184	14	chem	chem	PROPN
eurjchem-769	184	15	.	.	PUNCT
eurjchem-769	185	1	rev	rev	PROPN
eurjchem-769	185	2	.	.	PROPN
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eurjchem-769	185	4	,	,	PUNCT
eurjchem-769	185	5	110	110	NUM
eurjchem-769	185	6	,	,	PUNCT
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eurjchem-769	185	8	.	.	PUNCT
eurjchem-769	186	1	[	[	X
eurjchem-769	186	2	8	8	NUM
eurjchem-769	186	3	]	]	PUNCT
eurjchem-769	186	4	.	.	PUNCT
eurjchem-769	187	1	chanda	chanda	PROPN
eurjchem-769	187	2	,	,	PUNCT
eurjchem-769	187	3	a.	a.	PROPN
eurjchem-769	187	4	;	;	PUNCT
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eurjchem-769	187	6	,	,	PUNCT
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eurjchem-769	187	8	v.	v.	ADP
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eurjchem-769	187	10	.	.	PUNCT
eurjchem-769	188	1	rev	rev	PROPN
eurjchem-769	188	2	.	.	PROPN
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eurjchem-769	188	4	,	,	PUNCT
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eurjchem-769	188	6	,	,	PUNCT
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eurjchem-769	188	8	.	.	PUNCT
eurjchem-769	189	1	[	[	X
eurjchem-769	189	2	9	9	NUM
eurjchem-769	189	3	]	]	PUNCT
eurjchem-769	189	4	.	.	PUNCT
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eurjchem-769	190	2	,	,	PUNCT
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eurjchem-769	190	4	j.	j.	PROPN
eurjchem-769	190	5	chem	chem	PROPN
eurjchem-769	190	6	.	.	PUNCT
eurjchem-769	191	1	rev	rev	PROPN
eurjchem-769	191	2	.	.	PROPN
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eurjchem-769	191	4	,	,	PUNCT
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eurjchem-769	191	6	,	,	PUNCT
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eurjchem-769	191	8	.	.	PUNCT
eurjchem-769	192	1	[	[	X
eurjchem-769	192	2	10	10	NUM
eurjchem-769	192	3	]	]	PUNCT
eurjchem-769	192	4	.	.	PUNCT
eurjchem-769	193	1	li	li	PROPN
eurjchem-769	193	2	,	,	PUNCT
eurjchem-769	193	3	c.	c.	PROPN
eurjchem-769	193	4	j.	j.	PROPN
eurjchem-769	193	5	chem	chem	PROPN
eurjchem-769	193	6	.	.	PUNCT
eurjchem-769	194	1	rev	rev	PROPN
eurjchem-769	194	2	.	.	PROPN
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eurjchem-769	194	4	,	,	PUNCT
eurjchem-769	194	5	105	105	NUM
eurjchem-769	194	6	,	,	PUNCT
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eurjchem-769	194	8	.	.	PUNCT
eurjchem-769	195	1	[	[	X
eurjchem-769	195	2	11	11	NUM
eurjchem-769	195	3	]	]	PUNCT
eurjchem-769	195	4	.	.	PUNCT
eurjchem-769	196	1	li	li	PROPN
eurjchem-769	196	2	,	,	PUNCT
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eurjchem-769	196	4	j.	j.	PROPN
eurjchem-769	196	5	chem	chem	PROPN
eurjchem-769	196	6	.	.	PUNCT
eurjchem-769	197	1	rev	rev	PROPN
eurjchem-769	197	2	.	.	PROPN
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eurjchem-769	197	4	,	,	PUNCT
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eurjchem-769	197	6	,	,	PUNCT
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eurjchem-769	197	8	.	.	PUNCT
eurjchem-769	198	1	[	[	X
eurjchem-769	198	2	12	12	NUM
eurjchem-769	198	3	]	]	PUNCT
eurjchem-769	198	4	.	.	PUNCT
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eurjchem-769	199	2	,	,	PUNCT
eurjchem-769	199	3	m.	m.	NOUN
eurjchem-769	199	4	;	;	PUNCT
eurjchem-769	199	5	rossi	rossi	ADJ
eurjchem-769	199	6	,	,	PUNCT
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eurjchem-769	199	20	;	;	PUNCT
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eurjchem-769	199	25	;	;	PUNCT
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eurjchem-769	200	1	[	[	X
eurjchem-769	200	2	13	13	NUM
eurjchem-769	200	3	]	]	PUNCT
eurjchem-769	200	4	.	.	PUNCT
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eurjchem-769	201	2	,	,	PUNCT
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eurjchem-769	201	4	;	;	PUNCT
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eurjchem-769	201	8	;	;	PUNCT
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eurjchem-769	201	10	,	,	PUNCT
eurjchem-769	201	11	h.	h.	PROPN
eurjchem-769	201	12	;	;	PUNCT
eurjchem-769	201	13	rossi	rossi	ADJ
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eurjchem-769	201	15	;	;	PUNCT
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eurjchem-769	201	17	,	,	PUNCT
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eurjchem-769	201	21	.	.	PUNCT
eurjchem-769	202	1	chem	chem	PROPN
eurjchem-769	202	2	.	.	PUNCT
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eurjchem-769	203	2	.	.	PUNCT
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eurjchem-769	204	2	.	.	PROPN
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eurjchem-769	205	2	,	,	PUNCT
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eurjchem-769	205	4	,	,	PUNCT
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eurjchem-769	205	6	.	.	PUNCT
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eurjchem-769	206	2	14	14	NUM
eurjchem-769	206	3	]	]	PUNCT
eurjchem-769	206	4	.	.	PUNCT
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eurjchem-769	208	2	.	.	PROPN
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eurjchem-769	208	4	,	,	PUNCT
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eurjchem-769	208	8	.	.	PUNCT
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eurjchem-769	209	4	.	.	PUNCT
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eurjchem-769	210	9	.	.	PUNCT
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eurjchem-769	211	2	.	.	PUNCT
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eurjchem-769	212	2	.	.	PUNCT
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eurjchem-769	213	2	.	.	PROPN
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eurjchem-769	214	2	,	,	PUNCT
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eurjchem-769	215	4	.	.	PUNCT
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eurjchem-769	217	2	,	,	PUNCT
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eurjchem-769	218	4	.	.	PUNCT
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eurjchem-769	219	10	;	;	PUNCT
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eurjchem-769	220	2	.	.	PUNCT
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eurjchem-769	221	2	.	.	PROPN
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eurjchem-769	221	4	,	,	PUNCT
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eurjchem-769	222	4	.	.	PUNCT
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eurjchem-769	224	2	,	,	PUNCT
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eurjchem-769	224	6	.	.	PUNCT
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eurjchem-769	225	4	.	.	PUNCT
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eurjchem-769	226	6	bhagat	bhagat	PROPN
eurjchem-769	226	7	,	,	PUNCT
eurjchem-769	226	8	s.	s.	PROPN
eurjchem-769	226	9	b.	b.	PROPN
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eurjchem-769	226	12	,	,	PUNCT
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eurjchem-769	227	2	,	,	PUNCT
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eurjchem-769	227	4	,	,	PUNCT
eurjchem-769	227	5	5697‐5701	5697‐5701	NUM
eurjchem-769	227	6	.	.	PUNCT
eurjchem-769	228	1	[	[	X
eurjchem-769	228	2	20	20	NUM
eurjchem-769	228	3	]	]	PUNCT
eurjchem-769	228	4	.	.	PUNCT
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eurjchem-769	229	4	;	;	PUNCT
eurjchem-769	229	5	litvak	litvak	PROPN
eurjchem-769	229	6	,	,	PUNCT
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eurjchem-769	229	8	;	;	PUNCT
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eurjchem-769	229	10	,	,	PUNCT
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eurjchem-769	229	12	;	;	PUNCT
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eurjchem-769	229	14	,	,	PUNCT
eurjchem-769	229	15	y.	y.	PROPN
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eurjchem-769	230	3	.	.	PUNCT
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eurjchem-769	231	2	,	,	PUNCT
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eurjchem-769	231	4	,	,	PUNCT
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eurjchem-769	231	6	.	.	PUNCT
eurjchem-769	232	1	[	[	X
eurjchem-769	232	2	21	21	NUM
eurjchem-769	232	3	]	]	PUNCT
eurjchem-769	232	4	.	.	PUNCT
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eurjchem-769	233	2	,	,	PUNCT
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eurjchem-769	233	4	;	;	PUNCT
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eurjchem-769	233	6	,	,	PUNCT
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eurjchem-769	234	2	.	.	PUNCT
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eurjchem-769	235	2	,	,	PUNCT
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eurjchem-769	235	4	,	,	PUNCT
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eurjchem-769	235	6	.	.	PUNCT
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eurjchem-769	236	3	]	]	PUNCT
eurjchem-769	236	4	.	.	PUNCT
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eurjchem-769	237	2	,	,	PUNCT
eurjchem-769	237	3	a.	a.	PROPN
eurjchem-769	237	4	;	;	PUNCT
eurjchem-769	237	5	dlugy	dlugy	PROPN
eurjchem-769	237	6	,	,	PUNCT
eurjchem-769	237	7	c.	c.	PROPN
eurjchem-769	237	8	;	;	PUNCT
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eurjchem-769	237	10	,	,	PUNCT
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eurjchem-769	237	13	.	.	PUNCT
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eurjchem-769	238	2	.	.	PUNCT
eurjchem-769	239	1	2007	2007	NUM
eurjchem-769	239	2	,	,	PUNCT
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eurjchem-769	239	4	,	,	PUNCT
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eurjchem-769	240	3	]	]	PUNCT
eurjchem-769	240	4	.	.	PUNCT
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eurjchem-769	241	2	,	,	PUNCT
eurjchem-769	241	3	y.	y.	PROPN
eurjchem-769	241	4	;	;	PUNCT
eurjchem-769	241	5	barrault	barrault	NOUN
eurjchem-769	241	6	,	,	PUNCT
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eurjchem-769	241	8	;	;	PUNCT
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eurjchem-769	242	2	.	.	PUNCT
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eurjchem-769	242	4	,	,	PUNCT
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eurjchem-769	242	8	.	.	PUNCT
eurjchem-769	243	1	[	[	X
eurjchem-769	243	2	24	24	NUM
eurjchem-769	243	3	]	]	PUNCT
eurjchem-769	243	4	.	.	PUNCT
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eurjchem-769	244	2	,	,	PUNCT
eurjchem-769	244	3	a.	a.	NOUN
eurjchem-769	244	4	;	;	PUNCT
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eurjchem-769	244	8	;	;	PUNCT
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eurjchem-769	244	13	koerkamp	koerkamp	PROPN
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eurjchem-769	244	15	c.	c.	PROPN
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eurjchem-769	245	2	.	.	PUNCT
eurjchem-769	246	1	j.	j.	PROPN
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eurjchem-769	246	3	,	,	PUNCT
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eurjchem-769	247	3	]	]	PUNCT
eurjchem-769	247	4	.	.	PUNCT
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eurjchem-769	248	4	;	;	PUNCT
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eurjchem-769	248	6	,	,	PUNCT
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eurjchem-769	248	8	;	;	PUNCT
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eurjchem-769	248	17	.	.	PUNCT
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eurjchem-769	249	2	.	.	PUNCT
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eurjchem-769	250	2	,	,	PUNCT
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eurjchem-769	250	6	.	.	PUNCT
eurjchem-769	251	1	[	[	X
eurjchem-769	251	2	26	26	NUM
eurjchem-769	251	3	]	]	PUNCT
eurjchem-769	251	4	.	.	PUNCT
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eurjchem-769	252	2	,	,	PUNCT
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eurjchem-769	252	5	;	;	PUNCT
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eurjchem-769	252	10	;	;	PUNCT
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eurjchem-769	252	12	,	,	PUNCT
eurjchem-769	252	13	g.	g.	PROPN
eurjchem-769	252	14	;	;	PUNCT
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eurjchem-769	252	17	e.	e.	PROPN
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eurjchem-769	252	24	;	;	PUNCT
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eurjchem-769	252	30	.	.	PUNCT
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eurjchem-769	253	2	,	,	PUNCT
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eurjchem-769	253	4	,	,	PUNCT
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eurjchem-769	253	6	.	.	PUNCT
eurjchem-769	254	1	[	[	X
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eurjchem-769	254	3	]	]	PUNCT
eurjchem-769	254	4	.	.	PUNCT
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eurjchem-769	255	17	,	,	PUNCT
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eurjchem-769	255	19	;	;	PUNCT
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eurjchem-769	255	21	,	,	PUNCT
eurjchem-769	255	22	e.	e.	PROPN
eurjchem-769	255	23	j.	j.	PROPN
eurjchem-769	255	24	;	;	PUNCT
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eurjchem-769	255	26	,	,	PUNCT
eurjchem-769	255	27	d.	d.	PROPN
eurjchem-769	255	28	;	;	PUNCT
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eurjchem-769	257	4	.	.	PUNCT
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eurjchem-769	260	4	.	.	PUNCT
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eurjchem-769	260	6	,	,	PUNCT
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eurjchem-769	260	10	,	,	PUNCT
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eurjchem-769	261	3	]	]	PUNCT
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eurjchem-769	262	14	.	.	PUNCT
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eurjchem-769	263	2	.	.	PUNCT
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eurjchem-769	264	2	,	,	PUNCT
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eurjchem-769	265	3	]	]	PUNCT
eurjchem-769	265	4	.	.	PUNCT
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eurjchem-769	266	5	;	;	PUNCT
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eurjchem-769	266	10	;	;	PUNCT
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eurjchem-769	268	2	,	,	PUNCT
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eurjchem-769	270	4	s.	s.	PROPN
eurjchem-769	270	5	;	;	PUNCT
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eurjchem-769	270	17	.	.	PUNCT
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eurjchem-769	272	2	.	.	PUNCT
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eurjchem-769	273	2	,	,	PUNCT
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eurjchem-769	273	4	,	,	PUNCT
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eurjchem-769	273	6	.	.	PUNCT
eurjchem-769	274	1	[	[	X
eurjchem-769	274	2	33	33	NUM
eurjchem-769	274	3	]	]	PUNCT
eurjchem-769	274	4	.	.	PUNCT
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eurjchem-769	275	2	,	,	PUNCT
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eurjchem-769	275	5	;	;	PUNCT
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eurjchem-769	275	15	;	;	PUNCT
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eurjchem-769	275	17	,	,	PUNCT
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eurjchem-769	276	2	,	,	PUNCT
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eurjchem-769	276	4	,	,	PUNCT
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eurjchem-769	277	4	.	.	PUNCT
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eurjchem-769	278	14	o.	o.	PROPN
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eurjchem-769	278	16	;	;	PUNCT
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eurjchem-769	278	20	e.	e.	PROPN
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eurjchem-769	278	23	.	.	PUNCT
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eurjchem-769	279	2	,	,	PUNCT
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eurjchem-769	279	4	,	,	PUNCT
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eurjchem-769	279	6	.	.	PUNCT
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eurjchem-769	280	3	]	]	SYM
eurjchem-769	280	4	.	.	PUNCT
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eurjchem-769	280	9	;	;	PUNCT
eurjchem-769	280	10	metz	metz	PROPN
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eurjchem-769	280	13	;	;	PUNCT
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eurjchem-769	280	18	;	;	PUNCT
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eurjchem-769	281	2	.	.	PUNCT
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eurjchem-769	282	2	,	,	PUNCT
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eurjchem-769	282	4	,	,	PUNCT
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eurjchem-769	283	3	]	]	PUNCT
eurjchem-769	283	4	.	.	PUNCT
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eurjchem-769	284	3	f.	f.	PROPN
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eurjchem-769	284	7	,	,	PUNCT
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eurjchem-769	284	15	,	,	PUNCT
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eurjchem-769	285	2	.	.	PUNCT
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eurjchem-769	286	2	,	,	PUNCT
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eurjchem-769	286	4	,	,	PUNCT
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eurjchem-769	287	4	.	.	PUNCT
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eurjchem-769	288	4	;	;	PUNCT
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eurjchem-769	288	29	.	.	PUNCT
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eurjchem-769	290	2	,	,	PUNCT
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eurjchem-769	290	4	,	,	PUNCT
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eurjchem-769	290	6	.	.	PUNCT
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eurjchem-769	291	4	.	.	PUNCT
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eurjchem-769	292	4	;	;	PUNCT
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eurjchem-769	292	6	,	,	PUNCT
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eurjchem-769	292	16	;	;	PUNCT
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eurjchem-769	292	20	;	;	PUNCT
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eurjchem-769	293	4	,	,	PUNCT
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eurjchem-769	293	6	.	.	PUNCT
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eurjchem-769	294	4	.	.	PUNCT
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eurjchem-769	295	4	;	;	PUNCT
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eurjchem-769	300	4	.	.	PUNCT
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eurjchem-769	303	4	,	,	PUNCT
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eurjchem-769	305	7	a.	a.	NOUN
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eurjchem-769	307	4	.	.	PUNCT
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eurjchem-769	311	17	,	,	PUNCT
eurjchem-769	311	18	50	50	NUM
eurjchem-769	311	19	,	,	PUNCT
eurjchem-769	311	20	6834‐	6834‐	NUM
eurjchem-769	311	21	6837	6837	NUM
eurjchem-769	311	22	.	.	PUNCT