id	sid	tid	token	lemma	pos
eurjchem-828	1	1	untitled	untitle	VERB
eurjchem-828	1	2	european	european	PROPN
eurjchem-828	1	3	journal	journal	PROPN
eurjchem-828	1	4	of	of	ADP
eurjchem-828	1	5	chemistry	chemistry	NOUN
eurjchem-828	1	6	4	4	NUM
eurjchem-828	1	7	(	(	PUNCT
eurjchem-828	1	8	4	4	NUM
eurjchem-828	1	9	)	)	PUNCT
eurjchem-828	1	10	(	(	PUNCT
eurjchem-828	1	11	2013	2013	NUM
eurjchem-828	1	12	)	)	PUNCT
eurjchem-828	1	13	336‐342	336‐342	PROPN
eurjchem-828	1	14	european	european	PROPN
eurjchem-828	1	15	journal	journal	PROPN
eurjchem-828	1	16	of	of	ADP
eurjchem-828	1	17	chemistry	chemistry	NOUN
eurjchem-828	1	18	issn	issn	PROPN
eurjchem-828	1	19	2153‐2249	2153‐2249	PROPN
eurjchem-828	1	20	(	(	PUNCT
eurjchem-828	1	21	print	print	NOUN
eurjchem-828	1	22	)	)	PUNCT
eurjchem-828	1	23	/	/	SYM
eurjchem-828	1	24	issn	issn	PROPN
eurjchem-828	1	25	2153‐2257	2153‐2257	NUM
eurjchem-828	1	26	(	(	PUNCT
eurjchem-828	1	27	online	online	ADJ
eurjchem-828	1	28	)	)	PUNCT
eurjchem-828	1	29			NOUN
eurjchem-828	1	30	2013	2013	NUM
eurjchem-828	1	31	eurjchem	eurjchem	PROPN
eurjchem-828	1	32	doi:10.5155	doi:10.5155	NOUN
eurjchem-828	1	33	/	/	SYM
eurjchem-828	1	34	eurjchem.4.4.336‐342.828	eurjchem.4.4.336‐342.828	NOUN
eurjchem-828	1	35	european	european	ADJ
eurjchem-828	1	36	journal	journal	NOUN
eurjchem-828	1	37	of	of	ADP
eurjchem-828	1	38	chemistry	chemistry	PROPN
eurjchem-828	1	39	journal	journal	PROPN
eurjchem-828	1	40	homepage	homepage	NOUN
eurjchem-828	1	41	:	:	PUNCT
eurjchem-828	1	42	www.eurjchem.com	www.eurjchem.com	X
eurjchem-828	1	43	synthesis	synthesis	NOUN
eurjchem-828	1	44	of	of	ADP
eurjchem-828	1	45	intermediate	intermediate	ADJ
eurjchem-828	1	46	compounds	compound	NOUN
eurjchem-828	1	47	with	with	ADP
eurjchem-828	1	48	p‐n	p‐n	NOUN
eurjchem-828	1	49	bond	bond	NOUN
eurjchem-828	1	50	from	from	ADP
eurjchem-828	1	51	(	(	PUNCT
eurjchem-828	1	52	thio)carbamates	thio)carbamate	NOUN
eurjchem-828	1	53	and	and	CCONJ
eurjchem-828	1	54	chlorodioxaphospholanes	chlorodioxaphospholane	NOUN
eurjchem-828	1	55	and	and	CCONJ
eurjchem-828	1	56	‐phosphorinanes	‐phosphorinanes	PROPN
eurjchem-828	1	57	and	and	CCONJ
eurjchem-828	1	58	their	their	PRON
eurjchem-828	1	59	reactivity	reactivity	NOUN
eurjchem-828	1	60	dmitry	dmitry	PROPN
eurjchem-828	1	61	murzin	murzin	PROPN
eurjchem-828	1	62	a	a	DET
eurjchem-828	1	63	,	,	PUNCT
eurjchem-828	1	64	b	b	NOUN
eurjchem-828	1	65	,	,	PUNCT
eurjchem-828	1	66	*	*	PUNCT
eurjchem-828	1	67	and	and	CCONJ
eurjchem-828	1	68	vera	vera	NOUN
eurjchem-828	1	69	kolesova	kolesova	PROPN
eurjchem-828	2	1	b	b	X
eurjchem-828	2	2	a	a	DET
eurjchem-828	2	3	department	department	NOUN
eurjchem-828	2	4	of	of	ADP
eurjchem-828	2	5	chemical	chemical	PROPN
eurjchem-828	2	6	engineering	engineering	PROPN
eurjchem-828	2	7	,	,	PUNCT
eurjchem-828	2	8	åbo	åbo	PROPN
eurjchem-828	2	9	akademi	akademi	PROPN
eurjchem-828	2	10	university	university	PROPN
eurjchem-828	2	11	,	,	PUNCT
eurjchem-828	2	12	turku	turku	PROPN
eurjchem-828	2	13	,	,	PUNCT
eurjchem-828	2	14	20500	20500	NUM
eurjchem-828	2	15	,	,	PUNCT
eurjchem-828	2	16	finland	finland	PROPN
eurjchem-828	2	17	b	b	PROPN
eurjchem-828	2	18	department	department	PROPN
eurjchem-828	2	19	of	of	ADP
eurjchem-828	2	20	chemistry	chemistry	NOUN
eurjchem-828	2	21	and	and	CCONJ
eurjchem-828	2	22	technology	technology	NOUN
eurjchem-828	2	23	of	of	ADP
eurjchem-828	2	24	organic	organic	ADJ
eurjchem-828	2	25	synthesis	synthesis	NOUN
eurjchem-828	2	26	,	,	PUNCT
eurjchem-828	2	27	faculty	faculty	NOUN
eurjchem-828	2	28	of	of	ADP
eurjchem-828	2	29	technology	technology	NOUN
eurjchem-828	2	30	of	of	ADP
eurjchem-828	2	31	organic	organic	ADJ
eurjchem-828	2	32	substances	substance	NOUN
eurjchem-828	2	33	and	and	CCONJ
eurjchem-828	2	34	pharmaceutical	pharmaceutical	NOUN
eurjchem-828	2	35	chemistry	chemistry	NOUN
eurjchem-828	2	36	,	,	PUNCT
eurjchem-828	2	37	mendeleev	mendeleev	PROPN
eurjchem-828	2	38	university	university	PROPN
eurjchem-828	2	39	of	of	ADP
eurjchem-828	2	40	chemical	chemical	PROPN
eurjchem-828	2	41	technology	technology	NOUN
eurjchem-828	2	42	,	,	PUNCT
eurjchem-828	2	43	moscow	moscow	PROPN
eurjchem-828	2	44	,	,	PUNCT
eurjchem-828	2	45	125047	125047	NUM
eurjchem-828	2	46	,	,	PUNCT
eurjchem-828	2	47	russia	russia	NOUN
eurjchem-828	2	48	*	*	PUNCT
eurjchem-828	2	49	corresponding	correspond	VERB
eurjchem-828	2	50	author	author	NOUN
eurjchem-828	2	51	at	at	ADP
eurjchem-828	2	52	:	:	PUNCT
eurjchem-828	2	53	department	department	NOUN
eurjchem-828	2	54	of	of	ADP
eurjchem-828	2	55	chemical	chemical	PROPN
eurjchem-828	2	56	engineering	engineering	PROPN
eurjchem-828	2	57	,	,	PUNCT
eurjchem-828	2	58	åbo	åbo	PROPN
eurjchem-828	2	59	akademi	akademi	PROPN
eurjchem-828	2	60	university	university	PROPN
eurjchem-828	2	61	,	,	PUNCT
eurjchem-828	2	62	turku	turku	PROPN
eurjchem-828	2	63	,	,	PUNCT
eurjchem-828	2	64	20500	20500	NUM
eurjchem-828	2	65	,	,	PUNCT
eurjchem-828	2	66	finland	finland	PROPN
eurjchem-828	2	67	.	.	PUNCT
eurjchem-828	3	1	tel	tel	PROPN
eurjchem-828	3	2	.	.	PUNCT
eurjchem-828	3	3	:	:	PUNCT
eurjchem-828	4	1	+358.2.2154985	+358.2.2154985	NUM
eurjchem-828	4	2	;	;	PUNCT
eurjchem-828	4	3	fax	fax	NOUN
eurjchem-828	4	4	:	:	PUNCT
eurjchem-828	4	5	+358.2.2154479	+358.2.2154479	PROPN
eurjchem-828	4	6	.	.	PUNCT
eurjchem-828	4	7	e‐mail	e‐mail	PUNCT
eurjchem-828	4	8	address	address	NOUN
eurjchem-828	4	9	:	:	PUNCT
eurjchem-828	4	10	dmurzin@abo.fi	dmurzin@abo.fi	PROPN
eurjchem-828	4	11	(	(	PUNCT
eurjchem-828	4	12	d.	d.	PROPN
eurjchem-828	4	13	murzin	murzin	PROPN
eurjchem-828	4	14	)	)	PUNCT
eurjchem-828	4	15	.	.	PUNCT
eurjchem-828	5	1	article	article	NOUN
eurjchem-828	5	2	information	information	PROPN
eurjchem-828	5	3	abstract	abstract	ADV
eurjchem-828	5	4	received	receive	VERB
eurjchem-828	5	5	:	:	PUNCT
eurjchem-828	5	6	13	13	NUM
eurjchem-828	5	7	may	may	AUX
eurjchem-828	5	8	2013	2013	NUM
eurjchem-828	5	9	received	receive	VERB
eurjchem-828	5	10	in	in	ADP
eurjchem-828	5	11	revised	revise	VERB
eurjchem-828	5	12	form	form	NOUN
eurjchem-828	5	13	:	:	PUNCT
eurjchem-828	5	14	11	11	NUM
eurjchem-828	5	15	june	june	PROPN
eurjchem-828	5	16	2013	2013	NUM
eurjchem-828	5	17	accepted	accept	VERB
eurjchem-828	5	18	:	:	PUNCT
eurjchem-828	5	19	14	14	NUM
eurjchem-828	5	20	june	june	PROPN
eurjchem-828	5	21	2013	2013	NUM
eurjchem-828	5	22	online	online	NOUN
eurjchem-828	5	23	:	:	PUNCT
eurjchem-828	5	24	31	31	NUM
eurjchem-828	5	25	december	december	PROPN
eurjchem-828	5	26	2013	2013	NUM
eurjchem-828	5	27	keywords	keyword	VERB
eurjchem-828	5	28	a	a	DET
eurjchem-828	5	29	variety	variety	NOUN
eurjchem-828	5	30	of	of	ADP
eurjchem-828	5	31	2‐(n‐alkoxy(thio)carbonyl	2‐(n‐alkoxy(thio)carbonyl	ADJ
eurjchem-828	5	32	alkyl(aryl)amino)‐1,3,2‐dioxaphospholanes	alkyl(aryl)amino)‐1,3,2‐dioxaphospholane	NOUN
eurjchem-828	5	33	and	and	CCONJ
eurjchem-828	5	34	phosphorinanes	phosphorinane	NOUN
eurjchem-828	5	35	were	be	AUX
eurjchem-828	5	36	prepared	prepare	VERB
eurjchem-828	5	37	from	from	ADP
eurjchem-828	5	38	chlorodioxaphospholanes	chlorodioxaphospholane	NOUN
eurjchem-828	5	39	and	and	CCONJ
eurjchem-828	5	40	phosphorinanes	phosphorinane	NOUN
eurjchem-828	5	41	.	.	PUNCT
eurjchem-828	6	1	their	their	PRON
eurjchem-828	6	2	structures	structure	NOUN
eurjchem-828	6	3	were	be	AUX
eurjchem-828	6	4	determined	determine	VERB
eurjchem-828	6	5	by	by	ADP
eurjchem-828	6	6	ir	ir	PROPN
eurjchem-828	6	7	,	,	PUNCT
eurjchem-828	6	8	mass	mass	ADJ
eurjchem-828	6	9	and	and	CCONJ
eurjchem-828	6	10	nmr	nmr	NOUN
eurjchem-828	6	11	spectroscopy	spectroscopy	NOUN
eurjchem-828	6	12	.	.	PUNCT
eurjchem-828	7	1	these	these	DET
eurjchem-828	7	2	compounds	compound	NOUN
eurjchem-828	7	3	were	be	AUX
eurjchem-828	7	4	employed	employ	VERB
eurjchem-828	7	5	in	in	ADP
eurjchem-828	7	6	direct	direct	ADJ
eurjchem-828	7	7	reactions	reaction	NOUN
eurjchem-828	7	8	with	with	ADP
eurjchem-828	7	9	elemental	elemental	ADJ
eurjchem-828	7	10	sulphur	sulphur	NOUN
eurjchem-828	7	11	and	and	CCONJ
eurjchem-828	7	12	methylester	methylester	NOUN
eurjchem-828	7	13	of	of	ADP
eurjchem-828	7	14	chloroacetic	chloroacetic	ADJ
eurjchem-828	7	15	acid	acid	NOUN
eurjchem-828	7	16	giving	give	VERB
eurjchem-828	7	17	potentially	potentially	ADV
eurjchem-828	7	18	physiologically	physiologically	ADV
eurjchem-828	7	19	active	active	ADJ
eurjchem-828	7	20	n‐phosphorylated	n‐phosphorylate	VERB
eurjchem-828	7	21	carbamates	carbamate	NOUN
eurjchem-828	7	22	with	with	ADP
eurjchem-828	7	23	p(o)‐n	p(o)‐n	PROPN
eurjchem-828	7	24	and	and	CCONJ
eurjchem-828	7	25	p(s)n	p(s)n	NOUN
eurjchem-828	7	26	bonds	bond	NOUN
eurjchem-828	7	27	.	.	PUNCT
eurjchem-828	8	1	mass‐spectra	mass‐spectra	ADJ
eurjchem-828	8	2	sulfur	sulfur	NOUN
eurjchem-828	8	3	addition	addition	NOUN
eurjchem-828	8	4	phosphorinanes	phosphorinane	VERB
eurjchem-828	8	5	arbuzov	arbuzov	VERB
eurjchem-828	8	6	rearrangement	rearrangement	NOUN
eurjchem-828	8	7	chlorodioxaphospholanes	chlorodioxaphospholane	NOUN
eurjchem-828	8	8	n‐phosphorylated	n‐phosphorylate	VERB
eurjchem-828	8	9	carbamates	carbamate	NOUN
eurjchem-828	8	10	1	1	NUM
eurjchem-828	8	11	.	.	PUNCT
eurjchem-828	9	1	introduction	introduction	NOUN
eurjchem-828	9	2	synthesis	synthesis	NOUN
eurjchem-828	9	3	of	of	ADP
eurjchem-828	9	4	compounds	compound	NOUN
eurjchem-828	9	5	with	with	ADP
eurjchem-828	9	6	p‐n	p‐n	NOUN
eurjchem-828	9	7	bonds	bond	NOUN
eurjchem-828	9	8	has	have	AUX
eurjchem-828	9	9	been	be	AUX
eurjchem-828	9	10	extensively	extensively	ADV
eurjchem-828	9	11	discussed	discuss	VERB
eurjchem-828	9	12	in	in	ADP
eurjchem-828	9	13	the	the	DET
eurjchem-828	9	14	literature	literature	NOUN
eurjchem-828	9	15	due	due	ADP
eurjchem-828	9	16	to	to	ADP
eurjchem-828	9	17	their	their	PRON
eurjchem-828	9	18	physiological	physiological	ADJ
eurjchem-828	9	19	and	and	CCONJ
eurjchem-828	9	20	catalytic	catalytic	ADJ
eurjchem-828	9	21	properties	property	NOUN
eurjchem-828	9	22	.	.	PUNCT
eurjchem-828	10	1	for	for	ADP
eurjchem-828	10	2	example	example	NOUN
eurjchem-828	10	3	,	,	PUNCT
eurjchem-828	10	4	synthesis	synthesis	NOUN
eurjchem-828	10	5	of	of	ADP
eurjchem-828	10	6	n‐phosphorylated	n‐phosphorylate	VERB
eurjchem-828	10	7	carbamates	carbamate	NOUN
eurjchem-828	10	8	(	(	PUNCT
eurjchem-828	10	9	figure	figure	NOUN
eurjchem-828	10	10	1	1	NUM
eurjchem-828	10	11	)	)	PUNCT
eurjchem-828	10	12	is	be	AUX
eurjchem-828	10	13	mainly	mainly	ADV
eurjchem-828	10	14	driven	drive	VERB
eurjchem-828	10	15	by	by	ADP
eurjchem-828	10	16	physiological	physiological	ADJ
eurjchem-828	10	17	properties	property	NOUN
eurjchem-828	10	18	of	of	ADP
eurjchem-828	10	19	these	these	DET
eurjchem-828	10	20	compounds	compound	NOUN
eurjchem-828	10	21	;	;	PUNCT
eurjchem-828	10	22	those	those	PRON
eurjchem-828	10	23	could	could	AUX
eurjchem-828	10	24	be	be	AUX
eurjchem-828	10	25	used	use	VERB
eurjchem-828	10	26	as	as	ADP
eurjchem-828	10	27	,	,	PUNCT
eurjchem-828	10	28	for	for	ADP
eurjchem-828	10	29	example	example	NOUN
eurjchem-828	10	30	,	,	PUNCT
eurjchem-828	10	31	pesticides	pesticide	VERB
eurjchem-828	10	32	[	[	X
eurjchem-828	10	33	1	1	NUM
eurjchem-828	10	34	]	]	PUNCT
eurjchem-828	10	35	.	.	PUNCT
eurjchem-828	11	1	figure	figure	NOUN
eurjchem-828	11	2	1	1	NUM
eurjchem-828	12	1	.	.	NUM
eurjchem-828	12	2	n‐phosporylated	n‐phosporylate	VERB
eurjchem-828	12	3	carbamates	carbamate	NOUN
eurjchem-828	12	4	,	,	PUNCT
eurjchem-828	12	5	x	x	PRON
eurjchem-828	12	6	stands	stand	VERB
eurjchem-828	12	7	for	for	ADP
eurjchem-828	12	8	oxygen	oxygen	NOUN
eurjchem-828	12	9	or	or	CCONJ
eurjchem-828	12	10	sulphur	sulphur	NOUN
eurjchem-828	12	11	.	.	PUNCT
eurjchem-828	13	1	an	an	DET
eurjchem-828	13	2	important	important	ADJ
eurjchem-828	13	3	property	property	NOUN
eurjchem-828	13	4	of	of	ADP
eurjchem-828	13	5	such	such	ADJ
eurjchem-828	13	6	compounds	compound	NOUN
eurjchem-828	13	7	is	be	AUX
eurjchem-828	13	8	their	their	PRON
eurjchem-828	13	9	selective	selective	ADJ
eurjchem-828	13	10	toxicity	toxicity	NOUN
eurjchem-828	13	11	.	.	PUNCT
eurjchem-828	14	1	carbamates	carbamate	NOUN
eurjchem-828	14	2	with	with	ADP
eurjchem-828	14	3	p‐n	p‐n	NOUN
eurjchem-828	14	4	bonds	bond	NOUN
eurjchem-828	14	5	,	,	PUNCT
eurjchem-828	14	6	derivatives	derivative	NOUN
eurjchem-828	14	7	of	of	ADP
eurjchem-828	14	8	p(iii	p(iii	NOUN
eurjchem-828	14	9	)	)	PUNCT
eurjchem-828	14	10	,	,	PUNCT
eurjchem-828	14	11	can	can	AUX
eurjchem-828	14	12	have	have	VERB
eurjchem-828	14	13	high	high	ADJ
eurjchem-828	14	14	reactivity	reactivity	NOUN
eurjchem-828	14	15	,	,	PUNCT
eurjchem-828	14	16	which	which	PRON
eurjchem-828	14	17	gives	give	VERB
eurjchem-828	14	18	an	an	DET
eurjchem-828	14	19	opportunity	opportunity	NOUN
eurjchem-828	14	20	to	to	PART
eurjchem-828	14	21	synthesize	synthesize	VERB
eurjchem-828	14	22	corresponding	corresponding	ADJ
eurjchem-828	14	23	derivatives	derivative	NOUN
eurjchem-828	14	24	of	of	ADP
eurjchem-828	14	25	p(v	p(v	NOUN
eurjchem-828	14	26	)	)	PUNCT
eurjchem-828	14	27	containing	contain	VERB
eurjchem-828	14	28	also	also	ADV
eurjchem-828	14	29	sulphur	sulphur	NOUN
eurjchem-828	14	30	.	.	PUNCT
eurjchem-828	15	1	synthesis	synthesis	NOUN
eurjchem-828	15	2	of	of	ADP
eurjchem-828	15	3	compounds	compound	NOUN
eurjchem-828	15	4	1	1	NUM
eurjchem-828	15	5	and	and	CCONJ
eurjchem-828	15	6	2	2	NUM
eurjchem-828	15	7	when	when	SCONJ
eurjchem-828	15	8	r2	r2	PROPN
eurjchem-828	15	9	is	be	AUX
eurjchem-828	15	10	h	h	NOUN
eurjchem-828	15	11	,	,	PUNCT
eurjchem-828	15	12	can	can	AUX
eurjchem-828	15	13	be	be	AUX
eurjchem-828	15	14	carried	carry	VERB
eurjchem-828	15	15	out	out	ADP
eurjchem-828	15	16	through	through	ADP
eurjchem-828	15	17	the	the	DET
eurjchem-828	15	18	route	route	NOUN
eurjchem-828	15	19	displayed	display	VERB
eurjchem-828	15	20	in	in	ADP
eurjchem-828	15	21	scheme	scheme	NOUN
eurjchem-828	15	22	1	1	NUM
eurjchem-828	15	23	[	[	X
eurjchem-828	15	24	2	2	NUM
eurjchem-828	15	25	]	]	PUNCT
eurjchem-828	15	26	.	.	PUNCT
eurjchem-828	16	1	another	another	DET
eurjchem-828	16	2	synthetic	synthetic	ADJ
eurjchem-828	16	3	option	option	NOUN
eurjchem-828	16	4	is	be	AUX
eurjchem-828	16	5	the	the	DET
eurjchem-828	16	6	reaction	reaction	NOUN
eurjchem-828	16	7	of	of	ADP
eurjchem-828	16	8	pcl3	pcl3	NOUN
eurjchem-828	16	9	with	with	ADP
eurjchem-828	16	10	n‐chloroamides	n‐chloroamides	X
eurjchem-828	16	11	of	of	ADP
eurjchem-828	16	12	carbonic	carbonic	ADJ
eurjchem-828	16	13	acid	acid	NOUN
eurjchem-828	16	14	roc(o)nhcl	roc(o)nhcl	PROPN
eurjchem-828	16	15	or	or	CCONJ
eurjchem-828	16	16	n‐chloroaminoethers	n‐chloroaminoether	NOUN
eurjchem-828	16	17	(	(	PUNCT
eurjchem-828	16	18	ro)2c	ro)2c	NOUN
eurjchem-828	16	19	=	=	NOUN
eurjchem-828	16	20	ncl	ncl	NOUN
eurjchem-828	16	21	leading	lead	VERB
eurjchem-828	16	22	to	to	ADP
eurjchem-828	16	23	rocon	rocon	NOUN
eurjchem-828	16	24	=	=	NOUN
eurjchem-828	16	25	pcl3	pcl3	NOUN
eurjchem-828	16	26	which	which	PRON
eurjchem-828	16	27	can	can	AUX
eurjchem-828	16	28	undergo	undergo	VERB
eurjchem-828	16	29	hydrolysis	hydrolysis	NOUN
eurjchem-828	16	30	to	to	PART
eurjchem-828	16	31	yield	yield	VERB
eurjchem-828	16	32	n‐dichlorophosphoryl	n‐dichlorophosphoryl	PUNCT
eurjchem-828	16	33	carbamates	carbamate	VERB
eurjchem-828	16	34	[	[	X
eurjchem-828	16	35	3	3	NUM
eurjchem-828	16	36	]	]	PUNCT
eurjchem-828	16	37	.	.	PUNCT
eurjchem-828	17	1	the	the	DET
eurjchem-828	17	2	range	range	NOUN
eurjchem-828	17	3	of	of	ADP
eurjchem-828	17	4	synthetic	synthetic	ADJ
eurjchem-828	17	5	methods	method	NOUN
eurjchem-828	17	6	was	be	AUX
eurjchem-828	17	7	enlarged	enlarge	VERB
eurjchem-828	17	8	when	when	SCONJ
eurjchem-828	17	9	it	it	PRON
eurjchem-828	17	10	turned	turn	VERB
eurjchem-828	17	11	out	out	ADP
eurjchem-828	17	12	that	that	SCONJ
eurjchem-828	17	13	unsubstituted	unsubstituted	ADJ
eurjchem-828	17	14	phosphorylated	phosphorylate	VERB
eurjchem-828	17	15	carbamates	carbamate	NOUN
eurjchem-828	17	16	can	can	AUX
eurjchem-828	17	17	be	be	AUX
eurjchem-828	17	18	formed	form	VERB
eurjchem-828	17	19	when	when	SCONJ
eurjchem-828	17	20	phosphory‐	phosphory‐	NOUN
eurjchem-828	17	21	lated	late	VERB
eurjchem-828	17	22	isocyanates	isocyanate	NOUN
eurjchem-828	17	23	react	react	VERB
eurjchem-828	17	24	with	with	ADP
eurjchem-828	17	25	alcohols	alcohol	NOUN
eurjchem-828	17	26	or	or	CCONJ
eurjchem-828	17	27	mercaptanes	mercaptane	NOUN
eurjchem-828	17	28	[	[	X
eurjchem-828	17	29	4	4	NUM
eurjchem-828	17	30	]	]	PUNCT
eurjchem-828	17	31	.	.	PUNCT
eurjchem-828	18	1	this	this	DET
eurjchem-828	18	2	method	method	NOUN
eurjchem-828	18	3	can	can	AUX
eurjchem-828	18	4	be	be	AUX
eurjchem-828	18	5	applied	apply	VERB
eurjchem-828	18	6	for	for	ADP
eurjchem-828	18	7	the	the	DET
eurjchem-828	18	8	synthesis	synthesis	NOUN
eurjchem-828	18	9	of	of	ADP
eurjchem-828	18	10	various	various	ADJ
eurjchem-828	18	11	types	type	NOUN
eurjchem-828	18	12	of	of	ADP
eurjchem-828	18	13	phosphorylated	phosphorylate	VERB
eurjchem-828	18	14	carbamates	carbamate	NOUN
eurjchem-828	18	15	.	.	PUNCT
eurjchem-828	19	1	for	for	ADP
eurjchem-828	19	2	example	example	NOUN
eurjchem-828	19	3	,	,	PUNCT
eurjchem-828	19	4	bis(chlromethyl	bis(chlromethyl	NOUN
eurjchem-828	19	5	)	)	PUNCT
eurjchem-828	19	6	phosphinoylisocyanate	phosphinoylisocyanate	NOUN
eurjchem-828	19	7	reacts	react	VERB
eurjchem-828	19	8	easily	easily	ADV
eurjchem-828	19	9	with	with	ADP
eurjchem-828	19	10	alcohols	alcohol	NOUN
eurjchem-828	19	11	to	to	PART
eurjchem-828	19	12	give	give	VERB
eurjchem-828	19	13	the	the	DET
eurjchem-828	19	14	corresponding	corresponding	ADJ
eurjchem-828	19	15	phosphorylated	phosphorylate	VERB
eurjchem-828	19	16	carbamates	carbamate	NOUN
eurjchem-828	19	17	(	(	PUNCT
eurjchem-828	19	18	clch2)2p(o	clch2)2p(o	PROPN
eurjchem-828	19	19	)	)	PUNCT
eurjchem-828	19	20	nhc(o)or	nhc(o)or	PUNCT
eurjchem-828	20	1	[	[	X
eurjchem-828	20	2	5	5	NUM
eurjchem-828	20	3	]	]	PUNCT
eurjchem-828	20	4	.	.	PUNCT
eurjchem-828	21	1	the	the	DET
eurjchem-828	21	2	methods	method	NOUN
eurjchem-828	21	3	discussed	discuss	VERB
eurjchem-828	21	4	above	above	ADP
eurjchem-828	21	5	allow	allow	VERB
eurjchem-828	21	6	,	,	PUNCT
eurjchem-828	21	7	however	however	ADV
eurjchem-828	21	8	,	,	PUNCT
eurjchem-828	21	9	only	only	ADV
eurjchem-828	21	10	the	the	DET
eurjchem-828	21	11	synthesis	synthesis	NOUN
eurjchem-828	21	12	of	of	ADP
eurjchem-828	21	13	unsubstituted	unsubstituted	ADJ
eurjchem-828	21	14	phosphorylated	phosphorylate	VERB
eurjchem-828	21	15	carbamates	carbamate	NOUN
eurjchem-828	21	16	.	.	PUNCT
eurjchem-828	22	1	substituted	substitute	VERB
eurjchem-828	22	2	carbamates	carbamate	NOUN
eurjchem-828	22	3	,	,	PUNCT
eurjchem-828	22	4	in	in	ADP
eurjchem-828	22	5	turn	turn	NOUN
eurjchem-828	22	6	,	,	PUNCT
eurjchem-828	22	7	can	can	AUX
eurjchem-828	22	8	be	be	AUX
eurjchem-828	22	9	obtained	obtain	VERB
eurjchem-828	22	10	by	by	ADP
eurjchem-828	22	11	several	several	ADJ
eurjchem-828	22	12	methods	method	NOUN
eurjchem-828	22	13	,	,	PUNCT
eurjchem-828	22	14	including	include	VERB
eurjchem-828	22	15	for	for	ADP
eurjchem-828	22	16	example	example	NOUN
eurjchem-828	22	17	arbuzov	arbuzov	PROPN
eurjchem-828	22	18	rearrange‐	rearrange‐	NOUN
eurjchem-828	22	19	ment	ment	NOUN
eurjchem-828	22	20	(	(	PUNCT
eurjchem-828	22	21	scheme	scheme	NOUN
eurjchem-828	22	22	2	2	NUM
eurjchem-828	22	23	)	)	PUNCT
eurjchem-828	23	1	[	[	X
eurjchem-828	23	2	6	6	NUM
eurjchem-828	23	3	]	]	PUNCT
eurjchem-828	23	4	.	.	PUNCT
eurjchem-828	24	1	another	another	DET
eurjchem-828	24	2	method	method	NOUN
eurjchem-828	24	3	involves	involve	VERB
eurjchem-828	24	4	the	the	DET
eurjchem-828	24	5	reaction	reaction	NOUN
eurjchem-828	24	6	of	of	ADP
eurjchem-828	24	7	chloroanhydrides	chloroanhydride	NOUN
eurjchem-828	24	8	of	of	ADP
eurjchem-828	24	9	various	various	ADJ
eurjchem-828	24	10	phosphor	phosphor	NOUN
eurjchem-828	24	11	containing	contain	VERB
eurjchem-828	24	12	acids	acid	NOUN
eurjchem-828	24	13	with	with	ADP
eurjchem-828	24	14	sodium	sodium	NOUN
eurjchem-828	24	15	carbamates	carbamate	NOUN
eurjchem-828	24	16	[	[	X
eurjchem-828	24	17	7	7	NUM
eurjchem-828	24	18	]	]	PUNCT
eurjchem-828	24	19	.	.	PUNCT
eurjchem-828	25	1	utilization	utilization	NOUN
eurjchem-828	25	2	of	of	ADP
eurjchem-828	25	3	such	such	ADJ
eurjchem-828	25	4	preparative	preparative	ADJ
eurjchem-828	25	5	methods	method	NOUN
eurjchem-828	25	6	in	in	ADP
eurjchem-828	25	7	industrial	industrial	ADJ
eurjchem-828	25	8	scale	scale	NOUN
eurjchem-828	25	9	is	be	AUX
eurjchem-828	25	10	challenging	challenge	VERB
eurjchem-828	25	11	due	due	ADJ
eurjchem-828	25	12	to	to	ADP
eurjchem-828	25	13	the	the	DET
eurjchem-828	25	14	need	need	NOUN
eurjchem-828	25	15	of	of	ADP
eurjchem-828	25	16	using	use	VERB
eurjchem-828	25	17	metallic	metallic	ADJ
eurjchem-828	25	18	sodium	sodium	NOUN
eurjchem-828	25	19	for	for	ADP
eurjchem-828	25	20	synthesis	synthesis	NOUN
eurjchem-828	25	21	of	of	ADP
eurjchem-828	25	22	sodium	sodium	NOUN
eurjchem-828	25	23	carbamates	carbamate	NOUN
eurjchem-828	25	24	,	,	PUNCT
eurjchem-828	25	25	making	make	VERB
eurjchem-828	25	26	the	the	DET
eurjchem-828	25	27	process	process	NOUN
eurjchem-828	25	28	unnecessarily	unnecessarily	ADV
eurjchem-828	25	29	complicated	complicate	VERB
eurjchem-828	25	30	.	.	PUNCT
eurjchem-828	26	1	an	an	DET
eurjchem-828	26	2	alternative	alternative	ADJ
eurjchem-828	26	3	way	way	NOUN
eurjchem-828	26	4	is	be	AUX
eurjchem-828	26	5	to	to	PART
eurjchem-828	26	6	form	form	VERB
eurjchem-828	26	7	p‐n	p‐n	NOUN
eurjchem-828	26	8	bonds	bond	NOUN
eurjchem-828	26	9	directly	directly	ADV
eurjchem-828	26	10	from	from	ADP
eurjchem-828	26	11	a	a	DET
eurjchem-828	26	12	nitrogen	nitrogen	NOUN
eurjchem-828	26	13	compound	compound	NOUN
eurjchem-828	26	14	containing	contain	VERB
eurjchem-828	26	15	an	an	DET
eurjchem-828	26	16	n‐h	n‐h	NUM
eurjchem-828	26	17	bond	bond	NOUN
eurjchem-828	26	18	.	.	PUNCT
eurjchem-828	27	1	it	it	PRON
eurjchem-828	27	2	is	be	AUX
eurjchem-828	27	3	possible	possible	ADJ
eurjchem-828	27	4	,	,	PUNCT
eurjchem-828	27	5	for	for	ADP
eurjchem-828	27	6	example	example	NOUN
eurjchem-828	27	7	,	,	PUNCT
eurjchem-828	27	8	to	to	PART
eurjchem-828	27	9	react	react	VERB
eurjchem-828	27	10	halogen	halogen	NOUN
eurjchem-828	27	11	containing	contain	VERB
eurjchem-828	27	12	compounds	compound	NOUN
eurjchem-828	27	13	,	,	PUNCT
eurjchem-828	27	14	such	such	ADJ
eurjchem-828	27	15	as	as	ADP
eurjchem-828	27	16	chloroanhydrides	chloroanhydride	NOUN
eurjchem-828	27	17	of	of	ADP
eurjchem-828	27	18	varios	vario	NOUN
eurjchem-828	27	19	p(iii	p(iii	ADV
eurjchem-828	27	20	)	)	PUNCT
eurjchem-828	27	21	acids	acid	NOUN
eurjchem-828	27	22	with	with	ADP
eurjchem-828	27	23	amines	amine	NOUN
eurjchem-828	27	24	giving	give	VERB
eurjchem-828	27	25	a	a	DET
eurjchem-828	27	26	p(iii)‐n	p(iii)‐n	PROPN
eurjchem-828	27	27	bond	bond	NOUN
eurjchem-828	27	28	.	.	PUNCT
eurjchem-828	28	1	in	in	ADP
eurjchem-828	28	2	the	the	DET
eurjchem-828	28	3	work	work	NOUN
eurjchem-828	28	4	of	of	ADP
eurjchem-828	28	5	dutton	dutton	NOUN
eurjchem-828	28	6	and	and	CCONJ
eurjchem-828	28	7	coworkers	coworker	NOUN
eurjchem-828	28	8	[	[	X
eurjchem-828	28	9	8	8	NUM
eurjchem-828	28	10	]	]	PUNCT
eurjchem-828	28	11	,	,	PUNCT
eurjchem-828	28	12	chloro‐	chloro‐	PROPN
eurjchem-828	28	13	2‐dimethyl‐5,5‐dioxaphosporinane‐1,3,2	2‐dimethyl‐5,5‐dioxaphosporinane‐1,3,2	NUM
eurjchem-828	28	14	was	be	AUX
eurjchem-828	28	15	reacted	react	VERB
eurjchem-828	28	16	with	with	ADP
eurjchem-828	28	17	various	various	ADJ
eurjchem-828	28	18	amines	amine	NOUN
eurjchem-828	28	19	,	,	PUNCT
eurjchem-828	28	20	such	such	ADJ
eurjchem-828	28	21	as	as	ADP
eurjchem-828	28	22	tert‐butylamine	tert‐butylamine	NOUN
eurjchem-828	28	23	resulting	result	VERB
eurjchem-828	28	24	in	in	ADP
eurjchem-828	28	25	the	the	DET
eurjchem-828	28	26	formation	formation	NOUN
eurjchem-828	28	27	of	of	ADP
eurjchem-828	28	28	several	several	ADJ
eurjchem-828	28	29	1,3,2	1,3,2	NUM
eurjchem-828	28	30	dioxaphosporinanes	dioxaphosporinane	NOUN
eurjchem-828	28	31	.	.	PUNCT
eurjchem-828	29	1	a	a	DET
eurjchem-828	29	2	similar	similar	ADJ
eurjchem-828	29	3	approach	approach	NOUN
eurjchem-828	29	4	was	be	AUX
eurjchem-828	29	5	adopted	adopt	VERB
eurjchem-828	29	6	by	by	ADP
eurjchem-828	29	7	browne	browne	PROPN
eurjchem-828	29	8	et	et	PROPN
eurjchem-828	29	9	al	al	PROPN
eurjchem-828	29	10	.	.	PUNCT
eurjchem-828	30	1	[	[	X
eurjchem-828	30	2	9	9	NUM
eurjchem-828	30	3	]	]	PUNCT
eurjchem-828	30	4	where	where	SCONJ
eurjchem-828	30	5	phosporochloridite	phosporochloridite	PROPN
eurjchem-828	30	6	was	be	AUX
eurjchem-828	30	7	reacted	react	VERB
eurjchem-828	30	8	with	with	ADP
eurjchem-828	30	9	amines	amine	NOUN
eurjchem-828	30	10	followed	follow	VERB
eurjchem-828	30	11	by	by	ADP
eurjchem-828	30	12	reaction	reaction	NOUN
eurjchem-828	30	13	with	with	ADP
eurjchem-828	30	14	elemental	elemental	ADJ
eurjchem-828	30	15	sulfur	sulfur	NOUN
eurjchem-828	30	16	to	to	PART
eurjchem-828	30	17	obtain	obtain	VERB
eurjchem-828	30	18	potential	potential	ADJ
eurjchem-828	30	19	insecticides	insecticide	NOUN
eurjchem-828	30	20	.	.	PUNCT
eurjchem-828	31	1	another	another	DET
eurjchem-828	31	2	example	example	NOUN
eurjchem-828	31	3	has	have	AUX
eurjchem-828	31	4	been	be	AUX
eurjchem-828	31	5	reported	report	VERB
eurjchem-828	31	6	by	by	ADP
eurjchem-828	31	7	de	de	PROPN
eurjchem-828	31	8	vries	vries	PROPN
eurjchem-828	31	9	[	[	X
eurjchem-828	31	10	10	10	NUM
eurjchem-828	31	11	]	]	PUNCT
eurjchem-828	31	12	,	,	PUNCT
eurjchem-828	31	13	where	where	SCONJ
eurjchem-828	31	14	ethylene	ethylene	NOUN
eurjchem-828	31	15	chlorophosphite	chlorophosphite	NOUN
eurjchem-828	31	16	was	be	AUX
eurjchem-828	31	17	allowed	allow	VERB
eurjchem-828	31	18	to	to	PART
eurjchem-828	31	19	react	react	VERB
eurjchem-828	31	20	with	with	ADP
eurjchem-828	31	21	diisopropylamine	diisopropylamine	NOUN
eurjchem-828	31	22	in	in	ADP
eurjchem-828	31	23	dichloromethane	dichloromethane	NOUN
eurjchem-828	31	24	giving	give	VERB
eurjchem-828	31	25	the	the	DET
eurjchem-828	31	26	cyclic	cyclic	ADJ
eurjchem-828	31	27	ethylene	ethylene	NOUN
eurjchem-828	31	28	phosphite	phosphite	NOUN
eurjchem-828	31	29	ester	ester	NOUN
eurjchem-828	31	30	.	.	PUNCT
eurjchem-828	32	1	this	this	DET
eurjchem-828	32	2	synthetic	synthetic	ADJ
eurjchem-828	32	3	methodology	methodology	NOUN
eurjchem-828	32	4	became	become	VERB
eurjchem-828	32	5	popular	popular	ADJ
eurjchem-828	32	6	recently	recently	ADV
eurjchem-828	32	7	in	in	ADP
eurjchem-828	32	8	connection	connection	NOUN
eurjchem-828	32	9	with	with	ADP
eurjchem-828	32	10	the	the	DET
eurjchem-828	32	11	synthesis	synthesis	NOUN
eurjchem-828	32	12	of	of	ADP
eurjchem-828	32	13	a	a	DET
eurjchem-828	32	14	library	library	NOUN
eurjchem-828	32	15	of	of	ADP
eurjchem-828	32	16	chiral	chiral	ADJ
eurjchem-828	32	17	ligands	ligand	NOUN
eurjchem-828	32	18	based	base	VERB
eurjchem-828	32	19	on	on	ADP
eurjchem-828	32	20	monodentate	monodentate	ADJ
eurjchem-828	32	21	phosphoramidites	phosphoramidite	NOUN
eurjchem-828	32	22	[	[	X
eurjchem-828	32	23	11,12	11,12	NUM
eurjchem-828	32	24	]	]	PUNCT
eurjchem-828	32	25	when	when	SCONJ
eurjchem-828	32	26	stoichiometric	stoichiometric	ADJ
eurjchem-828	32	27	amounts	amount	NOUN
eurjchem-828	32	28	of	of	ADP
eurjchem-828	32	29	reagents	reagent	NOUN
eurjchem-828	32	30	such	such	ADJ
eurjchem-828	32	31	as	as	ADP
eurjchem-828	32	32	chlorodioxa	chlorodioxa	NOUN
eurjchem-828	32	33	phospholane	phospholane	NOUN
eurjchem-828	32	34	(	(	PUNCT
eurjchem-828	32	35	4	4	NUM
eurjchem-828	32	36	)	)	PUNCT
eurjchem-828	32	37	and	and	CCONJ
eurjchem-828	32	38	diacetylamines	diacetylamine	NOUN
eurjchem-828	32	39	are	be	AUX
eurjchem-828	32	40	put	put	VERB
eurjchem-828	32	41	in	in	ADP
eurjchem-828	32	42	contact	contact	NOUN
eurjchem-828	32	43	in	in	ADP
eurjchem-828	32	44	the	the	DET
eurjchem-828	32	45	presence	presence	NOUN
eurjchem-828	32	46	of	of	ADP
eurjchem-828	32	47	a	a	DET
eurjchem-828	32	48	hcl	hcl	PROPN
eurjchem-828	32	49	acceptor	acceptor	NOUN
eurjchem-828	32	50	(	(	PUNCT
eurjchem-828	32	51	triethylamine	triethylamine	NOUN
eurjchem-828	32	52	)	)	PUNCT
eurjchem-828	32	53	giving	give	VERB
eurjchem-828	32	54	finally	finally	ADV
eurjchem-828	32	55	phosphoramidites	phosphoramidite	NOUN
eurjchem-828	32	56	(	(	PUNCT
eurjchem-828	32	57	5	5	NUM
eurjchem-828	32	58	)	)	PUNCT
eurjchem-828	32	59	(	(	PUNCT
eurjchem-828	32	60	scheme	scheme	NOUN
eurjchem-828	32	61	3	3	NUM
eurjchem-828	32	62	)	)	PUNCT
eurjchem-828	32	63	.	.	PUNCT
eurjchem-828	33	1	murzin	murzin	PROPN
eurjchem-828	33	2	and	and	CCONJ
eurjchem-828	33	3	kolesova	kolesova	PROPN
eurjchem-828	33	4	/	/	SYM
eurjchem-828	33	5	european	european	PROPN
eurjchem-828	33	6	journal	journal	PROPN
eurjchem-828	33	7	of	of	ADP
eurjchem-828	33	8	chemistry	chemistry	NOUN
eurjchem-828	33	9	4	4	NUM
eurjchem-828	33	10	(	(	PUNCT
eurjchem-828	33	11	4	4	NUM
eurjchem-828	33	12	)	)	PUNCT
eurjchem-828	33	13	(	(	PUNCT
eurjchem-828	33	14	2013	2013	NUM
eurjchem-828	33	15	)	)	PUNCT
eurjchem-828	33	16	336‐342	336‐342	NUM
eurjchem-828	33	17	337	337	NUM
eurjchem-828	33	18	scheme	scheme	NOUN
eurjchem-828	33	19	1	1	NUM
eurjchem-828	33	20	scheme	scheme	NOUN
eurjchem-828	33	21	2	2	NUM
eurjchem-828	33	22	scheme	scheme	NOUN
eurjchem-828	33	23	3	3	NUM
eurjchem-828	33	24	the	the	DET
eurjchem-828	33	25	protocol	protocol	NOUN
eurjchem-828	33	26	was	be	AUX
eurjchem-828	33	27	even	even	ADV
eurjchem-828	33	28	automated	automate	VERB
eurjchem-828	33	29	by	by	ADP
eurjchem-828	33	30	using	use	VERB
eurjchem-828	33	31	a	a	DET
eurjchem-828	33	32	96	96	NUM
eurjchem-828	33	33	well	well	NOUN
eurjchem-828	33	34	filter	filter	NOUN
eurjchem-828	33	35	plate	plate	NOUN
eurjchem-828	33	36	,	,	PUNCT
eurjchem-828	33	37	as	as	SCONJ
eurjchem-828	33	38	simple	simple	ADJ
eurjchem-828	33	39	filtration	filtration	NOUN
eurjchem-828	33	40	of	of	ADP
eurjchem-828	33	41	the	the	DET
eurjchem-828	33	42	precipitated	precipitate	VERB
eurjchem-828	33	43	hcl	hcl	PROPN
eurjchem-828	33	44	salt	salt	NOUN
eurjchem-828	33	45	can	can	AUX
eurjchem-828	33	46	be	be	AUX
eurjchem-828	33	47	performed	perform	VERB
eurjchem-828	33	48	without	without	ADP
eurjchem-828	33	49	further	further	ADJ
eurjchem-828	33	50	ligand	ligand	ADJ
eurjchem-828	33	51	purification	purification	NOUN
eurjchem-828	33	52	.	.	PUNCT
eurjchem-828	34	1	in	in	ADP
eurjchem-828	34	2	fact	fact	NOUN
eurjchem-828	34	3	,	,	PUNCT
eurjchem-828	34	4	triethylamine	triethylamine	NOUN
eurjchem-828	34	5	started	start	VERB
eurjchem-828	34	6	to	to	PART
eurjchem-828	34	7	be	be	AUX
eurjchem-828	34	8	used	use	VERB
eurjchem-828	34	9	rather	rather	ADV
eurjchem-828	34	10	long	long	ADJ
eurjchem-828	34	11	time	time	NOUN
eurjchem-828	34	12	ago	ago	ADV
eurjchem-828	34	13	as	as	ADP
eurjchem-828	34	14	a	a	DET
eurjchem-828	34	15	hcl	hcl	PROPN
eurjchem-828	34	16	acceptor	acceptor	NOUN
eurjchem-828	34	17	not	not	PART
eurjchem-828	34	18	only	only	ADV
eurjchem-828	34	19	for	for	ADP
eurjchem-828	34	20	reaction	reaction	NOUN
eurjchem-828	34	21	of	of	ADP
eurjchem-828	34	22	phosphorochloridite	phosphorochloridite	NOUN
eurjchem-828	34	23	with	with	ADP
eurjchem-828	34	24	amines	amine	NOUN
eurjchem-828	34	25	per	per	ADP
eurjchem-828	34	26	se	se	ADV
eurjchem-828	34	27	,	,	PUNCT
eurjchem-828	34	28	but	but	CCONJ
eurjchem-828	34	29	also	also	ADV
eurjchem-828	34	30	for	for	ADP
eurjchem-828	34	31	reactants	reactant	NOUN
eurjchem-828	34	32	with	with	ADP
eurjchem-828	34	33	the	the	DET
eurjchem-828	34	34	‐nh‐c(o)‐	‐nh‐c(o)‐	PROPN
eurjchem-828	34	35	group	group	NOUN
eurjchem-828	34	36	,	,	PUNCT
eurjchem-828	34	37	such	such	ADJ
eurjchem-828	34	38	as	as	ADP
eurjchem-828	34	39	n‐methylacetamide	n‐methylacetamide	ADV
eurjchem-828	34	40	[	[	X
eurjchem-828	34	41	13,14	13,14	NUM
eurjchem-828	34	42	]	]	PUNCT
eurjchem-828	34	43	.	.	PUNCT
eurjchem-828	35	1	alternatively	alternatively	ADV
eurjchem-828	35	2	‐caprolactam	‐caprolactam	NOUN
eurjchem-828	35	3	can	can	AUX
eurjchem-828	35	4	be	be	AUX
eurjchem-828	35	5	used	use	VERB
eurjchem-828	35	6	[	[	PUNCT
eurjchem-828	35	7	15	15	NUM
eurjchem-828	35	8	]	]	PUNCT
eurjchem-828	35	9	.	.	PUNCT
eurjchem-828	36	1	in	in	ADP
eurjchem-828	36	2	the	the	DET
eurjchem-828	36	3	latter	latter	ADJ
eurjchem-828	36	4	case	case	NOUN
eurjchem-828	36	5	[	[	X
eurjchem-828	36	6	15	15	NUM
eurjchem-828	36	7	]	]	X
eurjchem-828	36	8	it	it	PRON
eurjchem-828	36	9	is	be	AUX
eurjchem-828	36	10	supposed	suppose	VERB
eurjchem-828	36	11	that	that	SCONJ
eurjchem-828	36	12	the	the	DET
eurjchem-828	36	13	reaction	reaction	NOUN
eurjchem-828	36	14	proceeds	proceed	VERB
eurjchem-828	36	15	via	via	ADP
eurjchem-828	36	16	intermediate	intermediate	ADJ
eurjchem-828	36	17	formation	formation	NOUN
eurjchem-828	36	18	of	of	ADP
eurjchem-828	36	19	a	a	DET
eurjchem-828	36	20	five	five	NUM
eurjchem-828	36	21	membered	membere	VERB
eurjchem-828	36	22	complex	complex	NOUN
eurjchem-828	36	23	.	.	PUNCT
eurjchem-828	37	1	interestingly	interestingly	ADV
eurjchem-828	37	2	,	,	PUNCT
eurjchem-828	37	3	in	in	ADP
eurjchem-828	37	4	earlier	early	ADJ
eurjchem-828	37	5	work	work	NOUN
eurjchem-828	37	6	[	[	X
eurjchem-828	37	7	13	13	NUM
eurjchem-828	37	8	]	]	PUNCT
eurjchem-828	37	9	,	,	PUNCT
eurjchem-828	37	10	also	also	ADV
eurjchem-828	37	11	phosphorylated	phosphorylate	VERB
eurjchem-828	37	12	carbamates	carbamate	NOUN
eurjchem-828	37	13	with	with	ADP
eurjchem-828	37	14	p‐n(r)‐c(o)or	p‐n(r)‐c(o)or	NOUN
eurjchem-828	37	15	motifs	motif	NOUN
eurjchem-828	37	16	were	be	AUX
eurjchem-828	37	17	synthesized	synthesize	VERB
eurjchem-828	37	18	,	,	PUNCT
eurjchem-828	37	19	including	include	VERB
eurjchem-828	37	20	2‐(n‐ethoxycarbonyl	2‐(n‐ethoxycarbonyl	PROPN
eurjchem-828	37	21	methylamino)‐l,3,2‐dioxa‐	methylamino)‐l,3,2‐dioxa‐	PROPN
eurjchem-828	37	22	phospholane	phospholane	NOUN
eurjchem-828	37	23	(	(	PUNCT
eurjchem-828	37	24	6	6	NUM
eurjchem-828	37	25	)	)	PUNCT
eurjchem-828	37	26	,	,	PUNCT
eurjchem-828	37	27	diethyl	diethyl	VERB
eurjchem-828	37	28	n‐ethoxycarbonyl‐n‐methylphosphor‐	n‐ethoxycarbonyl‐n‐methylphosphor‐	NUM
eurjchem-828	37	29	amidite	amidite	ADJ
eurjchem-828	37	30	(	(	PUNCT
eurjchem-828	37	31	7	7	NUM
eurjchem-828	37	32	)	)	PUNCT
eurjchem-828	37	33	and	and	CCONJ
eurjchem-828	37	34	4,5‐benzo‐2‐(n‐ethoxycarbonymethylamino)‐	4,5‐benzo‐2‐(n‐ethoxycarbonymethylamino)‐	NUM
eurjchem-828	37	35	1,3,2‐dioxaphospholane	1,3,2‐dioxaphospholane	NUM
eurjchem-828	37	36	(	(	PUNCT
eurjchem-828	37	37	8)	8)	NUM
eurjchem-828	37	38	(	(	PUNCT
eurjchem-828	37	39	figure	figure	NOUN
eurjchem-828	37	40	2	2	NUM
eurjchem-828	37	41	)	)	PUNCT
eurjchem-828	37	42	.	.	PUNCT
eurjchem-828	38	1	n‐phosphorylated	n‐phosphorylate	VERB
eurjchem-828	38	2	methylcarbamates	methylcarbamate	NOUN
eurjchem-828	38	3	,	,	PUNCT
eurjchem-828	38	4	in	in	ADP
eurjchem-828	38	5	turn	turn	NOUN
eurjchem-828	38	6	,	,	PUNCT
eurjchem-828	38	7	were	be	AUX
eurjchem-828	38	8	shown	show	VERB
eurjchem-828	38	9	to	to	PART
eurjchem-828	38	10	react	react	VERB
eurjchem-828	38	11	with	with	ADP
eurjchem-828	38	12	elemental	elemental	ADJ
eurjchem-828	38	13	sulfur	sulfur	NOUN
eurjchem-828	38	14	[	[	X
eurjchem-828	38	15	9,15	9,15	X
eurjchem-828	38	16	]	]	X
eurjchem-828	38	17	.	.	PUNCT
eurjchem-828	39	1	the	the	DET
eurjchem-828	39	2	products	product	NOUN
eurjchem-828	39	3	possess	possess	VERB
eurjchem-828	39	4	insecticidal	insecticidal	NOUN
eurjchem-828	39	5	activity	activity	NOUN
eurjchem-828	39	6	resulting	result	VERB
eurjchem-828	39	7	,	,	PUNCT
eurjchem-828	39	8	however	however	ADV
eurjchem-828	39	9	,	,	PUNCT
eurjchem-828	39	10	in	in	ADP
eurjchem-828	39	11	burns	burn	NOUN
eurjchem-828	39	12	of	of	ADP
eurjchem-828	39	13	the	the	DET
eurjchem-828	39	14	leaves	leave	NOUN
eurjchem-828	39	15	.	.	PUNCT
eurjchem-828	40	1	chloroanhydrides	chloroanhydride	NOUN
eurjchem-828	40	2	can	can	AUX
eurjchem-828	40	3	also	also	ADV
eurjchem-828	40	4	react	react	VERB
eurjchem-828	40	5	with	with	ADP
eurjchem-828	40	6	compound	compound	NOUN
eurjchem-828	40	7	7	7	NUM
eurjchem-828	40	8	[	[	X
eurjchem-828	40	9	15	15	NUM
eurjchem-828	40	10	]	]	PUNCT
eurjchem-828	40	11	.	.	PUNCT
eurjchem-828	41	1	the	the	DET
eurjchem-828	41	2	aim	aim	NOUN
eurjchem-828	41	3	of	of	ADP
eurjchem-828	41	4	the	the	DET
eurjchem-828	41	5	present	present	ADJ
eurjchem-828	41	6	work	work	NOUN
eurjchem-828	41	7	was	be	AUX
eurjchem-828	41	8	to	to	PART
eurjchem-828	41	9	synthesize	synthesize	VERB
eurjchem-828	41	10	components	component	NOUN
eurjchem-828	41	11	with	with	ADP
eurjchem-828	41	12	p‐n	p‐n	NOUN
eurjchem-828	41	13	bonds	bond	NOUN
eurjchem-828	41	14	from	from	ADP
eurjchem-828	41	15	(	(	PUNCT
eurjchem-828	41	16	thio)carbamates	thio)carbamate	NOUN
eurjchem-828	41	17	and	and	CCONJ
eurjchem-828	41	18	chlorodioxa‐	chlorodioxa‐	PROPN
eurjchem-828	41	19	phospholanes	phospholane	NOUN
eurjchem-828	41	20	and	and	CCONJ
eurjchem-828	41	21	‐phosphorinanes	‐phosphorinanes	PROPN
eurjchem-828	41	22	and	and	CCONJ
eurjchem-828	41	23	to	to	PART
eurjchem-828	41	24	study	study	VERB
eurjchem-828	41	25	their	their	PRON
eurjchem-828	41	26	reactivity	reactivity	NOUN
eurjchem-828	41	27	in	in	ADP
eurjchem-828	41	28	reactions	reaction	NOUN
eurjchem-828	41	29	with	with	ADP
eurjchem-828	41	30	elemental	elemental	ADJ
eurjchem-828	41	31	sulphur	sulphur	NOUN
eurjchem-828	41	32	and	and	CCONJ
eurjchem-828	41	33	chloro	chloro	NOUN
eurjchem-828	41	34	anhydrides	anhydride	NOUN
eurjchem-828	41	35	.	.	PUNCT
eurjchem-828	42	1	the	the	DET
eurjchem-828	42	2	compounds	compound	NOUN
eurjchem-828	42	3	obtained	obtain	VERB
eurjchem-828	42	4	from	from	ADP
eurjchem-828	42	5	these	these	DET
eurjchem-828	42	6	reactions	reaction	NOUN
eurjchem-828	42	7	could	could	AUX
eurjchem-828	42	8	be	be	AUX
eurjchem-828	42	9	potential	potential	ADJ
eurjchem-828	42	10	insecticides	insecticide	NOUN
eurjchem-828	42	11	and	and	CCONJ
eurjchem-828	42	12	regulators	regulator	NOUN
eurjchem-828	42	13	of	of	ADP
eurjchem-828	42	14	plant	plant	NOUN
eurjchem-828	42	15	growth	growth	NOUN
eurjchem-828	42	16	.	.	PUNCT
eurjchem-828	43	1	2	2	X
eurjchem-828	43	2	.	.	X
eurjchem-828	43	3	experimental	experimental	ADJ
eurjchem-828	43	4	2.1	2.1	NUM
eurjchem-828	43	5	.	.	PUNCT
eurjchem-828	43	6	synthesis	synthesis	NOUN
eurjchem-828	43	7	in	in	ADP
eurjchem-828	43	8	the	the	DET
eurjchem-828	43	9	current	current	ADJ
eurjchem-828	43	10	work	work	NOUN
eurjchem-828	43	11	,	,	PUNCT
eurjchem-828	43	12	all	all	PRON
eurjchem-828	43	13	synthesized	synthesize	VERB
eurjchem-828	43	14	phosphorylated	phosphorylate	VERB
eurjchem-828	43	15	carbamates	carbamate	NOUN
eurjchem-828	43	16	were	be	AUX
eurjchem-828	43	17	obtained	obtain	VERB
eurjchem-828	43	18	by	by	ADP
eurjchem-828	43	19	reactions	reaction	NOUN
eurjchem-828	43	20	of	of	ADP
eurjchem-828	43	21	2‐chloro‐1,3,2‐	2‐chloro‐1,3,2‐	PROPN
eurjchem-828	43	22	dioxaphospholane	dioxaphospholane	NOUN
eurjchem-828	43	23	/	/	SYM
eurjchem-828	43	24	phosphorinane	phosphorinane	NOUN
eurjchem-828	43	25	(	(	PUNCT
eurjchem-828	43	26	9	9	NUM
eurjchem-828	43	27	)	)	PUNCT
eurjchem-828	43	28	with	with	ADP
eurjchem-828	43	29	carbamates	carbamate	NOUN
eurjchem-828	43	30	and	and	CCONJ
eurjchem-828	43	31	thiocarbamates	thiocarbamate	NOUN
eurjchem-828	43	32	in	in	ADP
eurjchem-828	43	33	the	the	DET
eurjchem-828	43	34	presence	presence	NOUN
eurjchem-828	43	35	of	of	ADP
eurjchem-828	43	36	hcl	hcl	PROPN
eurjchem-828	43	37	acceptor‐triethylamine	acceptor‐triethylamine	PROPN
eurjchem-828	43	38	(	(	PUNCT
eurjchem-828	43	39	scheme	scheme	NOUN
eurjchem-828	43	40	4	4	NUM
eurjchem-828	43	41	)	)	PUNCT
eurjchem-828	43	42	.	.	PUNCT
eurjchem-828	44	1	the	the	DET
eurjchem-828	44	2	synthesized	synthesize	VERB
eurjchem-828	44	3	compounds	compound	NOUN
eurjchem-828	44	4	are	be	AUX
eurjchem-828	44	5	presented	present	VERB
eurjchem-828	44	6	in	in	ADP
eurjchem-828	44	7	table	table	NOUN
eurjchem-828	44	8	1	1	NUM
eurjchem-828	44	9	.	.	PUNCT
eurjchem-828	45	1	it	it	PRON
eurjchem-828	45	2	should	should	AUX
eurjchem-828	45	3	be	be	AUX
eurjchem-828	45	4	noted	note	VERB
eurjchem-828	45	5	that	that	SCONJ
eurjchem-828	45	6	among	among	ADP
eurjchem-828	45	7	these	these	DET
eurjchem-828	45	8	compounds	compound	NOUN
eurjchem-828	45	9	only	only	ADV
eurjchem-828	45	10	compound	compound	NOUN
eurjchem-828	45	11	10b	10b	NOUN
eurjchem-828	45	12	was	be	AUX
eurjchem-828	45	13	synthesized	synthesize	VERB
eurjchem-828	45	14	previously	previously	ADV
eurjchem-828	45	15	[	[	X
eurjchem-828	45	16	13	13	NUM
eurjchem-828	45	17	]	]	PUNCT
eurjchem-828	45	18	.	.	PUNCT
eurjchem-828	46	1	synthesis	synthesis	NOUN
eurjchem-828	46	2	of	of	ADP
eurjchem-828	46	3	compounds	compound	NOUN
eurjchem-828	46	4	10a‐10	10a‐10	VERB
eurjchem-828	46	5	m	m	VERB
eurjchem-828	46	6	was	be	AUX
eurjchem-828	46	7	performed	perform	VERB
eurjchem-828	46	8	under	under	ADP
eurjchem-828	46	9	nitrogen	nitrogen	NOUN
eurjchem-828	46	10	atmosphere	atmosphere	NOUN
eurjchem-828	46	11	.	.	PUNCT
eurjchem-828	47	1	to	to	ADP
eurjchem-828	47	2	a	a	DET
eurjchem-828	47	3	solution	solution	NOUN
eurjchem-828	47	4	of	of	ADP
eurjchem-828	47	5	(	(	PUNCT
eurjchem-828	47	6	thio)carbamate	thio)carbamate	NUM
eurjchem-828	47	7	and	and	CCONJ
eurjchem-828	47	8	triethylamine	triethylamine	NOUN
eurjchem-828	47	9	(	(	PUNCT
eurjchem-828	47	10	1.5	1.5	NUM
eurjchem-828	47	11	fold	fold	ADJ
eurjchem-828	47	12	mole	mole	NOUN
eurjchem-828	47	13	excess	excess	NOUN
eurjchem-828	47	14	)	)	PUNCT
eurjchem-828	47	15	in	in	ADP
eurjchem-828	47	16	25	25	NUM
eurjchem-828	47	17	or	or	CCONJ
eurjchem-828	47	18	50	50	NUM
eurjchem-828	47	19	ml	ml	NOUN
eurjchem-828	47	20	of	of	ADP
eurjchem-828	47	21	dried	dry	VERB
eurjchem-828	47	22	dioxane	dioxane	NOUN
eurjchem-828	47	23	an	an	DET
eurjchem-828	47	24	equimolar	equimolar	NOUN
eurjchem-828	47	25	amount	amount	NOUN
eurjchem-828	47	26	2‐chloro‐1,3,2‐dioxaphospho‐	2‐chloro‐1,3,2‐dioxaphospho‐	ADJ
eurjchem-828	47	27	lane	lane	NOUN
eurjchem-828	47	28	or	or	CCONJ
eurjchem-828	47	29	chloro‐1,3,2‐dioxaphosphorinane	chloro‐1,3,2‐dioxaphosphorinane	PROPN
eurjchem-828	47	30	was	be	AUX
eurjchem-828	47	31	added	add	VERB
eurjchem-828	47	32	drop‐wise	drop‐wise	NOUN
eurjchem-828	47	33	.	.	PUNCT
eurjchem-828	48	1	the	the	DET
eurjchem-828	48	2	quantities	quantity	NOUN
eurjchem-828	48	3	are	be	AUX
eurjchem-828	48	4	given	give	VERB
eurjchem-828	48	5	in	in	ADP
eurjchem-828	48	6	table	table	NOUN
eurjchem-828	48	7	2	2	NUM
eurjchem-828	48	8	.	.	PUNCT
eurjchem-828	49	1	the	the	DET
eurjchem-828	49	2	mixture	mixture	NOUN
eurjchem-828	49	3	was	be	AUX
eurjchem-828	49	4	stirred	stir	VERB
eurjchem-828	49	5	for	for	ADP
eurjchem-828	49	6	2	2	NUM
eurjchem-828	49	7	h	h	NOUN
eurjchem-828	49	8	at	at	ADP
eurjchem-828	49	9	55‐60	55‐60	NUM
eurjchem-828	49	10	oc	oc	NOUN
eurjchem-828	49	11	.	.	PUNCT
eurjchem-828	50	1	after	after	ADP
eurjchem-828	50	2	filtering	filter	VERB
eurjchem-828	50	3	triethylamine	triethylamine	NOUN
eurjchem-828	50	4	salt	salt	NOUN
eurjchem-828	50	5	and	and	CCONJ
eurjchem-828	50	6	evaporating	evaporate	VERB
eurjchem-828	50	7	the	the	DET
eurjchem-828	50	8	solvent	solvent	NOUN
eurjchem-828	50	9	in	in	ADP
eurjchem-828	50	10	vacuum	vacuum	PROPN
eurjchem-828	50	11	(	(	PUNCT
eurjchem-828	50	12	1‐12	1‐12	NUM
eurjchem-828	50	13	mm	mm	NUM
eurjchem-828	50	14	hg	hg	NOUN
eurjchem-828	50	15	)	)	PUNCT
eurjchem-828	50	16	the	the	DET
eurjchem-828	50	17	residual	residual	ADJ
eurjchem-828	50	18	was	be	AUX
eurjchem-828	50	19	distilled	distil	VERB
eurjchem-828	50	20	at	at	ADP
eurjchem-828	50	21	0.1‐0.2	0.1‐0.2	NUM
eurjchem-828	50	22	mm	mm	PROPN
eurjchem-828	50	23	hg	hg	PROPN
eurjchem-828	50	24	.	.	PUNCT
eurjchem-828	51	1	the	the	DET
eurjchem-828	51	2	yields	yield	NOUN
eurjchem-828	51	3	reported	report	VERB
eurjchem-828	51	4	below	below	ADV
eurjchem-828	51	5	are	be	AUX
eurjchem-828	51	6	isolated	isolate	VERB
eurjchem-828	51	7	yields	yield	NOUN
eurjchem-828	51	8	.	.	PUNCT
eurjchem-828	52	1	ethyl	ethyl	PROPN
eurjchem-828	52	2	1,3,2‐dioxaphospholan‐2‐ylcarbamate	1,3,2‐dioxaphospholan‐2‐ylcarbamate	PROPN
eurjchem-828	52	3	(	(	PUNCT
eurjchem-828	52	4	10a	10a	NUM
eurjchem-828	52	5	):	):	PUNCT
eurjchem-828	52	6	ir	ir	PROPN
eurjchem-828	52	7	(	(	PUNCT
eurjchem-828	52	8	kbr	kbr	PROPN
eurjchem-828	52	9	,	,	PUNCT
eurjchem-828	52	10			PROPN
eurjchem-828	52	11	,	,	PUNCT
eurjchem-828	52	12	cm‐1	cm‐1	PROPN
eurjchem-828	52	13	):	):	PUNCT
eurjchem-828	52	14	2990	2990	NUM
eurjchem-828	52	15	(	(	PUNCT
eurjchem-828	52	16	c‐h	c‐h	NUM
eurjchem-828	52	17	)	)	PUNCT
eurjchem-828	52	18	,	,	PUNCT
eurjchem-828	52	19	1710	1710	NUM
eurjchem-828	52	20	(	(	PUNCT
eurjchem-828	52	21	c	c	NOUN
eurjchem-828	52	22	=	=	NOUN
eurjchem-828	52	23	o	o	NOUN
eurjchem-828	52	24	)	)	PUNCT
eurjchem-828	52	25	,	,	PUNCT
eurjchem-828	52	26	1230	1230	NUM
eurjchem-828	52	27	(	(	PUNCT
eurjchem-828	52	28	c‐o‐c	c‐o‐c	NOUN
eurjchem-828	52	29	)	)	PUNCT
eurjchem-828	52	30	,	,	PUNCT
eurjchem-828	52	31	1010	1010	NUM
eurjchem-828	52	32	(	(	PUNCT
eurjchem-828	52	33	p‐o‐c	p‐o‐c	PROPN
eurjchem-828	52	34	)	)	PUNCT
eurjchem-828	52	35	.	.	PUNCT
eurjchem-828	53	1	31p	31p	NUM
eurjchem-828	53	2	nmr	nmr	NOUN
eurjchem-828	53	3	(	(	PUNCT
eurjchem-828	53	4	36.43	36.43	NUM
eurjchem-828	53	5	mhz	mhz	NOUN
eurjchem-828	53	6	,	,	PUNCT
eurjchem-828	53	7	85%h3po4	85%h3po4	PROPN
eurjchem-828	53	8	,	,	PUNCT
eurjchem-828	53	9	δ	δ	PROPN
eurjchem-828	53	10	,	,	PUNCT
eurjchem-828	53	11	ppm	ppm	NOUN
eurjchem-828	53	12	):	):	PUNCT
eurjchem-828	53	13	133	133	NUM
eurjchem-828	53	14	.	.	PUNCT
eurjchem-828	54	1	nd20	nd20	PROPN
eurjchem-828	54	2	=	=	PROPN
eurjchem-828	54	3	1.4220	1.4220	NUM
eurjchem-828	54	4	(	(	PUNCT
eurjchem-828	54	5	identical	identical	ADJ
eurjchem-828	54	6	to	to	ADP
eurjchem-828	54	7	the	the	DET
eurjchem-828	54	8	substrate	substrate	NOUN
eurjchem-828	54	9	)	)	PUNCT
eurjchem-828	54	10	.	.	PUNCT
eurjchem-828	55	1	338	338	NUM
eurjchem-828	55	2	murzin	murzin	NOUN
eurjchem-828	55	3	and	and	CCONJ
eurjchem-828	55	4	kolesova	kolesova	PROPN
eurjchem-828	55	5	/	/	SYM
eurjchem-828	55	6	european	european	PROPN
eurjchem-828	55	7	journal	journal	PROPN
eurjchem-828	55	8	of	of	ADP
eurjchem-828	55	9	chemistry	chemistry	NOUN
eurjchem-828	55	10	4	4	NUM
eurjchem-828	55	11	(	(	PUNCT
eurjchem-828	55	12	4	4	NUM
eurjchem-828	55	13	)	)	PUNCT
eurjchem-828	55	14	(	(	PUNCT
eurjchem-828	55	15	2013	2013	NUM
eurjchem-828	55	16	)	)	PUNCT
eurjchem-828	55	17	336‐342	336‐342	NUM
eurjchem-828	55	18	figure	figure	NOUN
eurjchem-828	55	19	2	2	NUM
eurjchem-828	55	20	.	.	PUNCT
eurjchem-828	55	21	phosphorylated	phosphorylate	VERB
eurjchem-828	55	22	carbamates	carbamate	NOUN
eurjchem-828	55	23	with	with	ADP
eurjchem-828	55	24	p‐n(r)‐c(o)or	p‐n(r)‐c(o)or	NOUN
eurjchem-828	55	25	motif	motif	NOUN
eurjchem-828	55	26	.	.	PUNCT
eurjchem-828	56	1	scheme	scheme	NOUN
eurjchem-828	56	2	4	4	NUM
eurjchem-828	56	3	table	table	NOUN
eurjchem-828	56	4	1	1	NUM
eurjchem-828	56	5	.	.	PUNCT
eurjchem-828	56	6	structure	structure	NOUN
eurjchem-828	56	7	of	of	ADP
eurjchem-828	56	8	synthesized	synthesize	VERB
eurjchem-828	56	9	compound	compound	NOUN
eurjchem-828	56	10	10	10	NUM
eurjchem-828	56	11	.	.	PUNCT
eurjchem-828	57	1	compound	compound	VERB
eurjchem-828	57	2	n	n	NOUN
eurjchem-828	57	3	x	x	SYM
eurjchem-828	57	4	r	r	NOUN
eurjchem-828	57	5	r1	r1	NOUN
eurjchem-828	57	6	10a	10a	PROPN
eurjchem-828	57	7	2	2	NUM
eurjchem-828	57	8	o	o	NOUN
eurjchem-828	57	9	h	h	NOUN
eurjchem-828	57	10	c2h5	c2h5	PROPN
eurjchem-828	57	11	10b	10b	NOUN
eurjchem-828	57	12	ch3	ch3	PROPN
eurjchem-828	57	13	c2h5	c2h5	ADP
eurjchem-828	57	14	10c	10c	PROPN
eurjchem-828	57	15	c6h5	c6h5	PROPN
eurjchem-828	57	16	ch3	ch3	PROPN
eurjchem-828	57	17	10d	10d	PROPN
eurjchem-828	57	18	c6h5	c6h5	PROPN
eurjchem-828	57	19	i‐c3h7	i‐c3h7	NOUN
eurjchem-828	57	20	10e	10e	NOUN
eurjchem-828	57	21	c6h4cl	c6h4cl	PROPN
eurjchem-828	57	22	i‐c3h7	i‐c3h7	NOUN
eurjchem-828	57	23	10f	10f	PROPN
eurjchem-828	57	24	2	2	NUM
eurjchem-828	57	25	s	s	PART
eurjchem-828	57	26	ch2‐ch	ch2‐ch	NOUN
eurjchem-828	57	27	=	=	NOUN
eurjchem-828	57	28	ch2	ch2	NOUN
eurjchem-828	57	29	c2h5	c2h5	ADP
eurjchem-828	57	30	10	10	NUM
eurjchem-828	57	31	g	g	PROPN
eurjchem-828	57	32	c6h5	c6h5	PROPN
eurjchem-828	57	33	ch3	ch3	PROPN
eurjchem-828	57	34	10h	10h	PROPN
eurjchem-828	57	35	c6h5	c6h5	PROPN
eurjchem-828	57	36	i‐c3h7	i‐c3h7	NOUN
eurjchem-828	57	37	10i	10i	NUM
eurjchem-828	57	38	c6h5	c6h5	PROPN
eurjchem-828	57	39	c4h9	c4h9	PROPN
eurjchem-828	57	40	10j	10j	NUM
eurjchem-828	57	41	3	3	NUM
eurjchem-828	57	42	o	o	NOUN
eurjchem-828	57	43	h	h	NOUN
eurjchem-828	57	44	c2h5	c2h5	ADP
eurjchem-828	57	45	10k	10k	PROPN
eurjchem-828	57	46	c6h5	c6h5	PROPN
eurjchem-828	57	47	ch3	ch3	PROPN
eurjchem-828	57	48	10l	10l	PROPN
eurjchem-828	57	49	c6h5	c6h5	PROPN
eurjchem-828	57	50	i‐c3h7	i‐c3h7	VERB
eurjchem-828	57	51	10	10	NUM
eurjchem-828	57	52	m	m	PROPN
eurjchem-828	57	53	s	s	NOUN
eurjchem-828	57	54	h	h	NOUN
eurjchem-828	57	55	ch3	ch3	PROPN
eurjchem-828	57	56	table	table	NOUN
eurjchem-828	57	57	2	2	NUM
eurjchem-828	57	58	.	.	X
eurjchem-828	58	1	ratio	ratio	NOUN
eurjchem-828	58	2	of	of	ADP
eurjchem-828	58	3	reactants	reactant	NOUN
eurjchem-828	58	4	.	.	PUNCT
eurjchem-828	59	1	product/	product/	NUM
eurjchem-828	59	2	reactants	reactant	NOUN
eurjchem-828	59	3	,	,	PUNCT
eurjchem-828	59	4	mole	mole	NOUN
eurjchem-828	59	5	carbamate	carbamate	NOUN
eurjchem-828	59	6	,	,	PUNCT
eurjchem-828	59	7	mole	mole	NOUN
eurjchem-828	59	8	et3n	et3n	PROPN
eurjchem-828	59	9	,	,	PUNCT
eurjchem-828	59	10	mole	mole	ADJ
eurjchem-828	59	11	volume	volume	NOUN
eurjchem-828	59	12	of	of	ADP
eurjchem-828	59	13	solvent	solvent	NOUN
eurjchem-828	59	14	,	,	PUNCT
eurjchem-828	59	15	ml	ml	ADP
eurjchem-828	59	16	10a	10a	PROPN
eurjchem-828	59	17	0.10	0.10	NUM
eurjchem-828	59	18	0.150	0.150	NUM
eurjchem-828	59	19	0.150	0.150	NUM
eurjchem-828	59	20	50	50	NUM
eurjchem-828	59	21	10b	10b	NOUN
eurjchem-828	59	22	0.10	0.10	NUM
eurjchem-828	59	23	0.150	0.150	NUM
eurjchem-828	59	24	0.150	0.150	NUM
eurjchem-828	59	25	50	50	NUM
eurjchem-828	59	26	10c	10c	NOUN
eurjchem-828	59	27	0.03	0.03	NUM
eurjchem-828	59	28	0.030	0.030	NUM
eurjchem-828	59	29	0.045	0.045	NUM
eurjchem-828	59	30	50	50	NUM
eurjchem-828	59	31	10d	10d	NUM
eurjchem-828	59	32	0.03	0.03	NUM
eurjchem-828	59	33	0.030	0.030	NUM
eurjchem-828	59	34	0.045	0.045	NUM
eurjchem-828	59	35	50	50	NUM
eurjchem-828	59	36	10e	10e	NOUN
eurjchem-828	59	37	0.04	0.04	NUM
eurjchem-828	59	38	0.040	0.040	NUM
eurjchem-828	59	39	0.060	0.060	NUM
eurjchem-828	59	40	50	50	NUM
eurjchem-828	59	41	10f	10f	NOUN
eurjchem-828	59	42	0.03	0.03	NUM
eurjchem-828	59	43	0.030	0.030	NUM
eurjchem-828	59	44	0.045	0.045	NUM
eurjchem-828	59	45	25	25	NUM
eurjchem-828	59	46	10	10	NUM
eurjchem-828	59	47	g	g	NOUN
eurjchem-828	59	48	0.09	0.09	NUM
eurjchem-828	59	49	0.090	0.090	NUM
eurjchem-828	59	50	0.140	0.140	NUM
eurjchem-828	59	51	50	50	NUM
eurjchem-828	59	52	10h	10h	NUM
eurjchem-828	59	53	0.03	0.03	NUM
eurjchem-828	59	54	0.030	0.030	NUM
eurjchem-828	59	55	0.045	0.045	NUM
eurjchem-828	59	56	50	50	NUM
eurjchem-828	59	57	10i	10i	NOUN
eurjchem-828	59	58	0.01	0.01	NUM
eurjchem-828	59	59	0.010	0.010	NUM
eurjchem-828	59	60	0.015	0.015	NUM
eurjchem-828	59	61	25	25	NUM
eurjchem-828	59	62	10j	10j	NUM
eurjchem-828	59	63	0.05	0.05	NUM
eurjchem-828	59	64	0.075	0.075	NUM
eurjchem-828	59	65	0.050	0.050	NUM
eurjchem-828	59	66	50	50	NUM
eurjchem-828	59	67	10k	10k	NOUN
eurjchem-828	59	68	0.10	0.10	NUM
eurjchem-828	59	69	0.100	0.100	NUM
eurjchem-828	59	70	0.150	0.150	NUM
eurjchem-828	59	71	70	70	NUM
eurjchem-828	59	72	10l	10l	NOUN
eurjchem-828	59	73	0.05	0.05	NUM
eurjchem-828	59	74	0.050	0.050	NUM
eurjchem-828	59	75	0.075	0.075	NUM
eurjchem-828	59	76	50	50	NUM
eurjchem-828	59	77	10	10	NUM
eurjchem-828	59	78	m	m	NOUN
eurjchem-828	59	79	0.05	0.05	NUM
eurjchem-828	59	80	0.050	0.050	NUM
eurjchem-828	59	81	0.100	0.100	NUM
eurjchem-828	59	82	50	50	NUM
eurjchem-828	59	83	ethyl	ethyl	PROPN
eurjchem-828	59	84	1,3,2‐dioxaphospholan‐2‐yl(methyl)carbamate	1,3,2‐dioxaphospholan‐2‐yl(methyl)carbamate	NUM
eurjchem-828	59	85	(	(	PUNCT
eurjchem-828	59	86	10b	10b	NOUN
eurjchem-828	59	87	):	):	PUNCT
eurjchem-828	59	88	yield	yield	NOUN
eurjchem-828	59	89	:	:	PUNCT
eurjchem-828	59	90	32	32	NUM
eurjchem-828	59	91	%	%	NOUN
eurjchem-828	59	92	.	.	PUNCT
eurjchem-828	60	1	b.p	b.p	PROPN
eurjchem-828	60	2	.	.	PROPN
eurjchem-828	60	3	:	:	PUNCT
eurjchem-828	60	4	50	50	NUM
eurjchem-828	60	5	oc/0.1	oc/0.1	NOUN
eurjchem-828	60	6	mm	mm	NUM
eurjchem-828	60	7	hg	hg	PROPN
eurjchem-828	60	8	.	.	PUNCT
eurjchem-828	61	1	ir	ir	PROPN
eurjchem-828	61	2	(	(	PUNCT
eurjchem-828	61	3	kbr	kbr	PROPN
eurjchem-828	61	4	,	,	PUNCT
eurjchem-828	61	5			PROPN
eurjchem-828	61	6	,	,	PUNCT
eurjchem-828	61	7	cm‐1	cm‐1	PROPN
eurjchem-828	61	8	):	):	PUNCT
eurjchem-828	61	9	2990	2990	NUM
eurjchem-828	61	10	(	(	PUNCT
eurjchem-828	61	11	c‐h	c‐h	NUM
eurjchem-828	61	12	)	)	PUNCT
eurjchem-828	61	13	,	,	PUNCT
eurjchem-828	61	14	1710	1710	NUM
eurjchem-828	61	15	(	(	PUNCT
eurjchem-828	61	16	c	c	NOUN
eurjchem-828	61	17	=	=	NOUN
eurjchem-828	61	18	o	o	NOUN
eurjchem-828	61	19	)	)	PUNCT
eurjchem-828	61	20	,	,	PUNCT
eurjchem-828	61	21	1220	1220	NUM
eurjchem-828	61	22	(	(	PUNCT
eurjchem-828	61	23	c‐o‐c	c‐o‐c	NOUN
eurjchem-828	61	24	)	)	PUNCT
eurjchem-828	61	25	,	,	PUNCT
eurjchem-828	61	26	1010	1010	NUM
eurjchem-828	61	27	(	(	PUNCT
eurjchem-828	61	28	p‐o‐c	p‐o‐c	PROPN
eurjchem-828	61	29	)	)	PUNCT
eurjchem-828	61	30	.	.	PUNCT
eurjchem-828	62	1	31p	31p	NUM
eurjchem-828	62	2	nmr	nmr	NOUN
eurjchem-828	62	3	(	(	PUNCT
eurjchem-828	62	4	36.43	36.43	NUM
eurjchem-828	62	5	mhz	mhz	NOUN
eurjchem-828	62	6	,	,	PUNCT
eurjchem-828	62	7	85%h3po4	85%h3po4	PROPN
eurjchem-828	62	8	,	,	PUNCT
eurjchem-828	62	9	δ	δ	PROPN
eurjchem-828	62	10	,	,	PUNCT
eurjchem-828	62	11	ppm):128.5	ppm):128.5	PROPN
eurjchem-828	62	12	(	(	PUNCT
eurjchem-828	62	13	128.8	128.8	NUM
eurjchem-828	62	14	in	in	ADP
eurjchem-828	62	15	[	[	X
eurjchem-828	62	16	12	12	NUM
eurjchem-828	62	17	]	]	PUNCT
eurjchem-828	62	18	)	)	PUNCT
eurjchem-828	62	19	.	.	PUNCT
eurjchem-828	63	1	nd20	nd20	PROPN
eurjchem-828	63	2	=	=	PROPN
eurjchem-828	63	3	1.4540	1.4540	NUM
eurjchem-828	63	4	.	.	PUNCT
eurjchem-828	64	1	methyl	methyl	PROPN
eurjchem-828	64	2	1,3,2‐dioxaphospholan‐2‐yl(phenyl)carbamate	1,3,2‐dioxaphospholan‐2‐yl(phenyl)carbamate	NUM
eurjchem-828	64	3	(	(	PUNCT
eurjchem-828	64	4	10c	10c	NOUN
eurjchem-828	64	5	):	):	PUNCT
eurjchem-828	64	6	yield	yield	NOUN
eurjchem-828	64	7	:	:	PUNCT
eurjchem-828	64	8	58	58	NUM
eurjchem-828	64	9	%	%	NOUN
eurjchem-828	64	10	.	.	PUNCT
eurjchem-828	65	1	b.p	b.p	PROPN
eurjchem-828	65	2	.	.	PROPN
eurjchem-828	65	3	:	:	PUNCT
eurjchem-828	65	4	85	85	NUM
eurjchem-828	65	5	oc/0.2	oc/0.2	NOUN
eurjchem-828	65	6	mm	mm	PROPN
eurjchem-828	65	7	hg	hg	PROPN
eurjchem-828	65	8	.	.	PUNCT
eurjchem-828	66	1	ir	ir	PROPN
eurjchem-828	66	2	(	(	PUNCT
eurjchem-828	66	3	kbr	kbr	PROPN
eurjchem-828	66	4	,	,	PUNCT
eurjchem-828	66	5			PROPN
eurjchem-828	66	6	,	,	PUNCT
eurjchem-828	66	7	cm‐1	cm‐1	PROPN
eurjchem-828	66	8	):	):	PUNCT
eurjchem-828	66	9	2990	2990	NUM
eurjchem-828	66	10	(	(	PUNCT
eurjchem-828	66	11	c‐h	c‐h	NUM
eurjchem-828	66	12	)	)	PUNCT
eurjchem-828	66	13	,	,	PUNCT
eurjchem-828	66	14	1700	1700	NUM
eurjchem-828	66	15	(	(	PUNCT
eurjchem-828	66	16	c	c	NOUN
eurjchem-828	66	17	=	=	NOUN
eurjchem-828	66	18	o	o	NOUN
eurjchem-828	66	19	)	)	PUNCT
eurjchem-828	66	20	,	,	PUNCT
eurjchem-828	66	21	1600	1600	NUM
eurjchem-828	66	22	,	,	PUNCT
eurjchem-828	66	23	1500	1500	NUM
eurjchem-828	66	24	,	,	PUNCT
eurjchem-828	66	25	1450	1450	NUM
eurjchem-828	66	26	(	(	PUNCT
eurjchem-828	66	27	c6h5	c6h5	NOUN
eurjchem-828	66	28	)	)	PUNCT
eurjchem-828	66	29	,	,	PUNCT
eurjchem-828	66	30	1000	1000	NUM
eurjchem-828	66	31	(	(	PUNCT
eurjchem-828	66	32	p‐o‐c	p‐o‐c	NOUN
eurjchem-828	66	33	)	)	PUNCT
eurjchem-828	66	34	.	.	PUNCT
eurjchem-828	67	1	31p	31p	NUM
eurjchem-828	67	2	nmr	nmr	NOUN
eurjchem-828	67	3	(	(	PUNCT
eurjchem-828	67	4	36.43	36.43	NUM
eurjchem-828	67	5	mhz	mhz	NOUN
eurjchem-828	67	6	,	,	PUNCT
eurjchem-828	67	7	85%h3po4	85%h3po4	PROPN
eurjchem-828	67	8	,	,	PUNCT
eurjchem-828	67	9	δ	δ	PROPN
eurjchem-828	67	10	,	,	PUNCT
eurjchem-828	67	11	ppm	ppm	NOUN
eurjchem-828	67	12	):	):	PUNCT
eurjchem-828	67	13	130	130	NUM
eurjchem-828	67	14	.	.	PUNCT
eurjchem-828	68	1	ms	ms	NOUN
eurjchem-828	68	2	(	(	PUNCT
eurjchem-828	68	3	ei	ei	PROPN
eurjchem-828	68	4	,	,	PUNCT
eurjchem-828	68	5	m	m	PROPN
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eurjchem-828	68	7	z	z	PROPN
eurjchem-828	68	8	(	(	PUNCT
eurjchem-828	68	9	%	%	NOUN
eurjchem-828	68	10	)	)	PUNCT
eurjchem-828	68	11	):	):	PUNCT
eurjchem-828	68	12	241	241	NUM
eurjchem-828	68	13	(	(	PUNCT
eurjchem-828	68	14	m+	m+	NUM
eurjchem-828	68	15	,	,	PUNCT
eurjchem-828	68	16	0.55	0.55	NUM
eurjchem-828	68	17	)	)	PUNCT
eurjchem-828	68	18	m+	m+	NOUN
eurjchem-828	68	19	.	.	PUNCT
eurjchem-828	69	1	nd20	nd20	PROPN
eurjchem-828	69	2	=	=	PROPN
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eurjchem-828	69	4	.	.	PUNCT
eurjchem-828	70	1	isopropyl	isopropyl	PROPN
eurjchem-828	70	2	1,3,2‐dioxaphospholan‐2‐yl(phenyl)carbamate	1,3,2‐dioxaphospholan‐2‐yl(phenyl)carbamate	NUM
eurjchem-828	70	3	(	(	PUNCT
eurjchem-828	70	4	10d	10d	NUM
eurjchem-828	70	5	):	):	PUNCT
eurjchem-828	70	6	color	color	NOUN
eurjchem-828	70	7	:	:	PUNCT
eurjchem-828	70	8	white	white	ADJ
eurjchem-828	70	9	.	.	PUNCT
eurjchem-828	70	10	yield	yield	NOUN
eurjchem-828	70	11	:	:	PUNCT
eurjchem-828	70	12	82	82	NUM
eurjchem-828	70	13	%	%	NOUN
eurjchem-828	70	14	.	.	PUNCT
eurjchem-828	71	1	m.p	m.p	PROPN
eurjchem-828	71	2	.	.	PROPN
eurjchem-828	71	3	:	:	PUNCT
eurjchem-828	71	4	80‐81	80‐81	PROPN
eurjchem-828	71	5	oc	oc	PROPN
eurjchem-828	71	6	.	.	PROPN
eurjchem-828	72	1	ir	ir	PROPN
eurjchem-828	72	2	(	(	PUNCT
eurjchem-828	72	3	kbr	kbr	PROPN
eurjchem-828	72	4	,	,	PUNCT
eurjchem-828	72	5			PROPN
eurjchem-828	72	6	,	,	PUNCT
eurjchem-828	72	7	cm‐1	cm‐1	PROPN
eurjchem-828	72	8	):	):	PUNCT
eurjchem-828	72	9	1700	1700	NUM
eurjchem-828	72	10	(	(	PUNCT
eurjchem-828	72	11	c	c	NOUN
eurjchem-828	72	12	=	=	NOUN
eurjchem-828	72	13	o	o	NOUN
eurjchem-828	72	14	)	)	PUNCT
eurjchem-828	72	15	,	,	PUNCT
eurjchem-828	72	16	1600	1600	NUM
eurjchem-828	72	17	,	,	PUNCT
eurjchem-828	72	18	1530	1530	NUM
eurjchem-828	72	19	,	,	PUNCT
eurjchem-828	72	20	1440	1440	NUM
eurjchem-828	72	21	(	(	PUNCT
eurjchem-828	72	22	c6h5	c6h5	NOUN
eurjchem-828	72	23	)	)	PUNCT
eurjchem-828	72	24	,	,	PUNCT
eurjchem-828	72	25	1220	1220	NUM
eurjchem-828	72	26	(	(	PUNCT
eurjchem-828	72	27	c‐o‐c	c‐o‐c	NOUN
eurjchem-828	72	28	)	)	PUNCT
eurjchem-828	72	29	,	,	PUNCT
eurjchem-828	72	30	995	995	NUM
eurjchem-828	72	31	(	(	PUNCT
eurjchem-828	72	32	p‐o‐c	p‐o‐c	PROPN
eurjchem-828	72	33	)	)	PUNCT
eurjchem-828	72	34	.	.	PUNCT
eurjchem-828	73	1	isopropyl	isopropyl	NOUN
eurjchem-828	73	2	(	(	PUNCT
eurjchem-828	73	3	2‐chlorophenyl)(1,3,2‐dioxaphospholan‐2‐yl	2‐chlorophenyl)(1,3,2‐dioxaphospholan‐2‐yl	PROPN
eurjchem-828	73	4	)	)	PUNCT
eurjchem-828	73	5	carbamate	carbamate	NOUN
eurjchem-828	73	6	(	(	PUNCT
eurjchem-828	73	7	10e	10e	NUM
eurjchem-828	73	8	):	):	PUNCT
eurjchem-828	73	9	yield	yield	NOUN
eurjchem-828	73	10	:	:	PUNCT
eurjchem-828	73	11	50	50	NUM
eurjchem-828	73	12	%	%	NOUN
eurjchem-828	73	13	.	.	PUNCT
eurjchem-828	74	1	b.p	b.p	PROPN
eurjchem-828	74	2	.	.	PROPN
eurjchem-828	74	3	:	:	PUNCT
eurjchem-828	74	4	95	95	NUM
eurjchem-828	74	5	oc/0.2	oc/0.2	NOUN
eurjchem-828	74	6	mm	mm	NUM
eurjchem-828	74	7	hg	hg	PROPN
eurjchem-828	74	8	.	.	PUNCT
eurjchem-828	75	1	ir	ir	PROPN
eurjchem-828	75	2	(	(	PUNCT
eurjchem-828	75	3	kbr	kbr	PROPN
eurjchem-828	75	4	,	,	PUNCT
eurjchem-828	75	5			PROPN
eurjchem-828	75	6	,	,	PUNCT
eurjchem-828	75	7	cm‐1	cm‐1	PROPN
eurjchem-828	75	8	):	):	PUNCT
eurjchem-828	75	9	2990	2990	NUM
eurjchem-828	75	10	(	(	PUNCT
eurjchem-828	75	11	c‐h	c‐h	NUM
eurjchem-828	75	12	)	)	PUNCT
eurjchem-828	75	13	,	,	PUNCT
eurjchem-828	75	14	1700	1700	NUM
eurjchem-828	75	15	(	(	PUNCT
eurjchem-828	75	16	c	c	NOUN
eurjchem-828	75	17	=	=	NOUN
eurjchem-828	75	18	o	o	NOUN
eurjchem-828	75	19	)	)	PUNCT
eurjchem-828	75	20	,	,	PUNCT
eurjchem-828	75	21	1600	1600	NUM
eurjchem-828	75	22	,	,	PUNCT
eurjchem-828	75	23	1530	1530	NUM
eurjchem-828	75	24	,	,	PUNCT
eurjchem-828	75	25	1440	1440	NUM
eurjchem-828	75	26	(	(	PUNCT
eurjchem-828	75	27	c6h5	c6h5	NOUN
eurjchem-828	75	28	)	)	PUNCT
eurjchem-828	75	29	,	,	PUNCT
eurjchem-828	75	30	1220	1220	NUM
eurjchem-828	75	31	(	(	PUNCT
eurjchem-828	75	32	c‐o‐c	c‐o‐c	NOUN
eurjchem-828	75	33	)	)	PUNCT
eurjchem-828	75	34	,	,	PUNCT
eurjchem-828	75	35	990	990	NUM
eurjchem-828	75	36	(	(	PUNCT
eurjchem-828	75	37	p‐o‐c	p‐o‐c	PROPN
eurjchem-828	75	38	)	)	PUNCT
eurjchem-828	75	39	.	.	PUNCT
eurjchem-828	76	1	nd20	nd20	PROPN
eurjchem-828	76	2	=	=	PROPN
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eurjchem-828	76	4	.	.	PUNCT
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eurjchem-828	76	6	allyl(1,3,2‐dioxaphospholan‐2‐yl)carbamothioate	allyl(1,3,2‐dioxaphospholan‐2‐yl)carbamothioate	PROPN
eurjchem-828	76	7	(	(	PUNCT
eurjchem-828	76	8	10f	10f	NUM
eurjchem-828	76	9	):	):	PUNCT
eurjchem-828	76	10	b.p	b.p	PROPN
eurjchem-828	76	11	.	.	PROPN
eurjchem-828	76	12	:	:	PUNCT
eurjchem-828	76	13	65‐68	65‐68	PROPN
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eurjchem-828	76	15	mm	mm	NUM
eurjchem-828	76	16	hg	hg	PROPN
eurjchem-828	76	17	.	.	PUNCT
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eurjchem-828	77	2	(	(	PUNCT
eurjchem-828	77	3	kbr	kbr	PROPN
eurjchem-828	77	4	,	,	PUNCT
eurjchem-828	77	5			PROPN
eurjchem-828	77	6	,	,	PUNCT
eurjchem-828	77	7	cm‐1	cm‐1	PROPN
eurjchem-828	77	8	):	):	PUNCT
eurjchem-828	77	9	2990	2990	NUM
eurjchem-828	77	10	(	(	PUNCT
eurjchem-828	77	11	c‐h	c‐h	NUM
eurjchem-828	77	12	)	)	PUNCT
eurjchem-828	77	13	,	,	PUNCT
eurjchem-828	77	14	1390	1390	NUM
eurjchem-828	77	15	(	(	PUNCT
eurjchem-828	77	16	c	c	NOUN
eurjchem-828	77	17	=	=	SYM
eurjchem-828	77	18	s	s	NOUN
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eurjchem-828	77	20	,	,	PUNCT
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eurjchem-828	77	23	c	c	NOUN
eurjchem-828	77	24	=	=	SYM
eurjchem-828	77	25	c	c	NOUN
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eurjchem-828	77	27	,	,	PUNCT
eurjchem-828	77	28	1010	1010	NUM
eurjchem-828	77	29	(	(	PUNCT
eurjchem-828	77	30	p‐o‐c	p‐o‐c	PROPN
eurjchem-828	77	31	)	)	PUNCT
eurjchem-828	77	32	.	.	PUNCT
eurjchem-828	78	1	ms	ms	NOUN
eurjchem-828	78	2	(	(	PUNCT
eurjchem-828	78	3	ei	ei	PROPN
eurjchem-828	78	4	,	,	PUNCT
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eurjchem-828	78	7	z	z	PROPN
eurjchem-828	78	8	(	(	PUNCT
eurjchem-828	78	9	%	%	NOUN
eurjchem-828	78	10	)	)	PUNCT
eurjchem-828	78	11	):	):	PUNCT
eurjchem-828	78	12	235	235	NUM
eurjchem-828	78	13	(	(	PUNCT
eurjchem-828	78	14	m+	m+	NUM
eurjchem-828	78	15	,	,	PUNCT
eurjchem-828	78	16	190	190	NUM
eurjchem-828	78	17	[	[	X
eurjchem-828	78	18	(	(	PUNCT
eurjchem-828	78	19	ch2o)2pn(cs)ch2ch	ch2o)2pn(cs)ch2ch	X
eurjchem-828	78	20	=	=	SYM
eurjchem-828	78	21	ch2]+	ch2]+	X
eurjchem-828	78	22	,	,	PUNCT
eurjchem-828	78	23	149	149	NUM
eurjchem-828	78	24	[	[	X
eurjchem-828	78	25	(	(	PUNCT
eurjchem-828	78	26	ch2o)2pn(cs)]+	ch2o)2pn(cs)]+	PROPN
eurjchem-828	78	27	,	,	PUNCT
eurjchem-828	78	28	105	105	NUM
eurjchem-828	78	29	[	[	X
eurjchem-828	78	30	(	(	PUNCT
eurjchem-828	78	31	ch2o)2pn]+	ch2o)2pn]+	NOUN
eurjchem-828	78	32	.	.	PUNCT
eurjchem-828	79	1	nd20	nd20	PROPN
eurjchem-828	79	2	=	=	PROPN
eurjchem-828	79	3	1.5191	1.5191	NUM
eurjchem-828	79	4	.	.	PUNCT
eurjchem-828	79	5	o‐methyl	o‐methyl	PROPN
eurjchem-828	80	1	1,3,2‐dioxaphospholan‐2‐yl(phenyl)carbamo	1,3,2‐dioxaphospholan‐2‐yl(phenyl)carbamo	PROPN
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eurjchem-828	80	3	(	(	PUNCT
eurjchem-828	80	4	10	10	NUM
eurjchem-828	80	5	g	g	NOUN
eurjchem-828	80	6	):	):	PUNCT
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eurjchem-828	80	8	:	:	PUNCT
eurjchem-828	80	9	63	63	NUM
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eurjchem-828	81	1	b.p	b.p	PROPN
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eurjchem-828	81	3	:	:	PUNCT
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eurjchem-828	81	7	hg	hg	PROPN
eurjchem-828	81	8	.	.	PUNCT
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eurjchem-828	82	3	kbr	kbr	PROPN
eurjchem-828	82	4	,	,	PUNCT
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eurjchem-828	82	16	,	,	PUNCT
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eurjchem-828	82	18	,	,	PUNCT
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eurjchem-828	82	21	c6h5	c6h5	NOUN
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eurjchem-828	82	23	,	,	PUNCT
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eurjchem-828	82	30	,	,	PUNCT
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eurjchem-828	82	32	(	(	PUNCT
eurjchem-828	82	33	p‐	p‐	PROPN
eurjchem-828	82	34	o‐c	o‐c	NUM
eurjchem-828	82	35	)	)	PUNCT
eurjchem-828	82	36	.	.	PUNCT
eurjchem-828	83	1	ms	ms	NOUN
eurjchem-828	83	2	(	(	PUNCT
eurjchem-828	83	3	ei	ei	PROPN
eurjchem-828	83	4	,	,	PUNCT
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eurjchem-828	83	7	z	z	PROPN
eurjchem-828	83	8	(	(	PUNCT
eurjchem-828	83	9	%	%	NOUN
eurjchem-828	83	10	)	)	PUNCT
eurjchem-828	83	11	):	):	PUNCT
eurjchem-828	83	12	257(m+	257(m+	NUM
eurjchem-828	83	13	,	,	PUNCT
eurjchem-828	83	14	1.1	1.1	NUM
eurjchem-828	83	15	)	)	PUNCT
eurjchem-828	83	16	,	,	PUNCT
eurjchem-828	83	17	243	243	NUM
eurjchem-828	84	1	[	[	X
eurjchem-828	84	2	(	(	PUNCT
eurjchem-828	84	3	ch2o)2pn(c6h5)csoh]+	ch2o)2pn(c6h5)csoh]+	PROPN
eurjchem-828	84	4	,	,	PUNCT
eurjchem-828	84	5	4.19	4.19	NUM
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eurjchem-828	84	7	.	.	PUNCT
eurjchem-828	85	1	nd20	nd20	PROPN
eurjchem-828	85	2	=	=	PROPN
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eurjchem-828	85	4	.	.	PUNCT
eurjchem-828	85	5	o‐isopropyl	o‐isopropyl	PUNCT
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eurjchem-828	86	3	(	(	PUNCT
eurjchem-828	86	4	10h	10h	NUM
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eurjchem-828	87	2	:	:	PUNCT
eurjchem-828	87	3	67	67	NUM
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eurjchem-828	87	5	.	.	PUNCT
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eurjchem-828	88	2	.	.	PROPN
eurjchem-828	88	3	:	:	PUNCT
eurjchem-828	88	4	84‐85	84‐85	PROPN
eurjchem-828	88	5	oc	oc	PROPN
eurjchem-828	88	6	.	.	PROPN
eurjchem-828	89	1	ir	ir	PROPN
eurjchem-828	89	2	(	(	PUNCT
eurjchem-828	89	3	kbr	kbr	PROPN
eurjchem-828	89	4	,	,	PUNCT
eurjchem-828	89	5			PROPN
eurjchem-828	89	6	,	,	PUNCT
eurjchem-828	89	7	cm‐1	cm‐1	PROPN
eurjchem-828	89	8	):	):	PUNCT
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eurjchem-828	89	10	(	(	PUNCT
eurjchem-828	89	11	c‐h	c‐h	NUM
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eurjchem-828	89	13	,	,	PUNCT
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eurjchem-828	89	15	,	,	PUNCT
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eurjchem-828	89	17	,	,	PUNCT
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eurjchem-828	89	19	(	(	PUNCT
eurjchem-828	89	20	c6h5	c6h5	NOUN
eurjchem-828	89	21	)	)	PUNCT
eurjchem-828	89	22	,	,	PUNCT
eurjchem-828	89	23	1375	1375	NUM
eurjchem-828	89	24	(	(	PUNCT
eurjchem-828	89	25	c	c	NOUN
eurjchem-828	89	26	=	=	SYM
eurjchem-828	89	27	s	s	NOUN
eurjchem-828	89	28	)	)	PUNCT
eurjchem-828	89	29	,	,	PUNCT
eurjchem-828	89	30	1250	1250	NUM
eurjchem-828	89	31	(	(	PUNCT
eurjchem-828	89	32	c‐o‐c	c‐o‐c	NOUN
eurjchem-828	89	33	)	)	PUNCT
eurjchem-828	89	34	,	,	PUNCT
eurjchem-828	89	35	990	990	NUM
eurjchem-828	89	36	(	(	PUNCT
eurjchem-828	89	37	p‐o‐c	p‐o‐c	PROPN
eurjchem-828	89	38	)	)	PUNCT
eurjchem-828	89	39	.	.	PUNCT
eurjchem-828	90	1	o‐butyl	o‐butyl	PROPN
eurjchem-828	91	1	1,3,2‐dioxaphospholan‐2‐yl(phenyl)carbamothioate	1,3,2‐dioxaphospholan‐2‐yl(phenyl)carbamothioate	PROPN
eurjchem-828	91	2	(	(	PUNCT
eurjchem-828	91	3	10i	10i	NUM
eurjchem-828	91	4	):	):	PUNCT
eurjchem-828	91	5	color	color	NOUN
eurjchem-828	91	6	:	:	PUNCT
eurjchem-828	91	7	white	white	ADJ
eurjchem-828	91	8	.	.	PUNCT
eurjchem-828	92	1	yield	yield	NOUN
eurjchem-828	92	2	:	:	PUNCT
eurjchem-828	92	3	70	70	NUM
eurjchem-828	92	4	%	%	NOUN
eurjchem-828	92	5	.	.	PUNCT
eurjchem-828	93	1	m.p	m.p	PROPN
eurjchem-828	93	2	.	.	PROPN
eurjchem-828	93	3	:	:	PUNCT
eurjchem-828	94	1	68‐70	68‐70	NUM
eurjchem-828	94	2	oc	oc	PROPN
eurjchem-828	94	3	.	.	PUNCT
eurjchem-828	94	4	ir	ir	PROPN
eurjchem-828	94	5	(	(	PUNCT
eurjchem-828	94	6	kbr	kbr	PROPN
eurjchem-828	94	7	,	,	PUNCT
eurjchem-828	94	8			PROPN
eurjchem-828	94	9	,	,	PUNCT
eurjchem-828	94	10	cm‐1	cm‐1	PROPN
eurjchem-828	94	11	):	):	PUNCT
eurjchem-828	94	12	2990	2990	NUM
eurjchem-828	94	13	(	(	PUNCT
eurjchem-828	94	14	c‐h	c‐h	NUM
eurjchem-828	94	15	)	)	PUNCT
eurjchem-828	94	16	,	,	PUNCT
eurjchem-828	94	17	1600	1600	NUM
eurjchem-828	94	18	,	,	PUNCT
eurjchem-828	94	19	1520	1520	NUM
eurjchem-828	94	20	,	,	PUNCT
eurjchem-828	94	21	1450	1450	NUM
eurjchem-828	94	22	(	(	PUNCT
eurjchem-828	94	23	c6h5	c6h5	NOUN
eurjchem-828	94	24	)	)	PUNCT
eurjchem-828	94	25	,	,	PUNCT
eurjchem-828	94	26	1360	1360	NUM
eurjchem-828	94	27	(	(	PUNCT
eurjchem-828	94	28	c	c	NOUN
eurjchem-828	94	29	=	=	SYM
eurjchem-828	94	30	s	s	NOUN
eurjchem-828	94	31	)	)	PUNCT
eurjchem-828	94	32	.	.	PUNCT
eurjchem-828	95	1	31p	31p	NUM
eurjchem-828	95	2	nmr	nmr	NOUN
eurjchem-828	95	3	(	(	PUNCT
eurjchem-828	95	4	36.43	36.43	NUM
eurjchem-828	95	5	mhz	mhz	NOUN
eurjchem-828	95	6	,	,	PUNCT
eurjchem-828	95	7	85%h3po4	85%h3po4	PROPN
eurjchem-828	95	8	,	,	PUNCT
eurjchem-828	95	9	δ	δ	PROPN
eurjchem-828	95	10	,	,	PUNCT
eurjchem-828	95	11	ppm	ppm	NUM
eurjchem-828	95	12	):	):	PUNCT
eurjchem-828	95	13	112	112	NUM
eurjchem-828	95	14	.	.	PUNCT
eurjchem-828	96	1	ms	ms	NOUN
eurjchem-828	96	2	(	(	PUNCT
eurjchem-828	96	3	ei	ei	PROPN
eurjchem-828	96	4	,	,	PUNCT
eurjchem-828	96	5	m	m	PROPN
eurjchem-828	96	6	/	/	SYM
eurjchem-828	96	7	z	z	PROPN
eurjchem-828	96	8	(	(	PUNCT
eurjchem-828	96	9	%	%	NOUN
eurjchem-828	96	10	)	)	PUNCT
eurjchem-828	96	11	):	):	PUNCT
eurjchem-828	96	12	299	299	NUM
eurjchem-828	96	13	(	(	PUNCT
eurjchem-828	96	14	m+	m+	NUM
eurjchem-828	96	15	,	,	PUNCT
eurjchem-828	96	16	0.11	0.11	NUM
eurjchem-828	96	17	)	)	PUNCT
eurjchem-828	96	18	.	.	PUNCT
eurjchem-828	97	1	ethyl	ethyl	PROPN
eurjchem-828	97	2	1,3,2‐dioxaphosphinan‐2‐ylcarbamate	1,3,2‐dioxaphosphinan‐2‐ylcarbamate	PROPN
eurjchem-828	97	3	(	(	PUNCT
eurjchem-828	97	4	10j	10j	NUM
eurjchem-828	97	5	):	):	PUNCT
eurjchem-828	97	6	ir	ir	PROPN
eurjchem-828	97	7	(	(	PUNCT
eurjchem-828	97	8	kbr	kbr	PROPN
eurjchem-828	97	9	,	,	PUNCT
eurjchem-828	97	10			PROPN
eurjchem-828	97	11	,	,	PUNCT
eurjchem-828	97	12	cm‐1	cm‐1	PROPN
eurjchem-828	97	13	):	):	PUNCT
eurjchem-828	97	14	1790	1790	NUM
eurjchem-828	97	15	(	(	PUNCT
eurjchem-828	97	16	c	c	NOUN
eurjchem-828	97	17	=	=	NOUN
eurjchem-828	97	18	o	o	NOUN
eurjchem-828	97	19	)	)	PUNCT
eurjchem-828	97	20	,	,	PUNCT
eurjchem-828	97	21	1010	1010	NUM
eurjchem-828	97	22	(	(	PUNCT
eurjchem-828	97	23	p‐o‐c	p‐o‐c	PROPN
eurjchem-828	97	24	)	)	PUNCT
eurjchem-828	97	25	.	.	PUNCT
eurjchem-828	98	1	methyl	methyl	PROPN
eurjchem-828	98	2	1,3,2‐dioxaphosphinan‐2‐yl(phenyl)carbamate	1,3,2‐dioxaphosphinan‐2‐yl(phenyl)carbamate	PROPN
eurjchem-828	98	3	(	(	PUNCT
eurjchem-828	98	4	10k	10k	NUM
eurjchem-828	98	5	):	):	PUNCT
eurjchem-828	98	6	yield	yield	NOUN
eurjchem-828	98	7	:	:	PUNCT
eurjchem-828	98	8	57	57	NUM
eurjchem-828	98	9	%	%	NOUN
eurjchem-828	98	10	.	.	PUNCT
eurjchem-828	99	1	b.p	b.p	PROPN
eurjchem-828	99	2	.	.	PUNCT
eurjchem-828	99	3	:	:	PUNCT
eurjchem-828	100	1	115‐120	115‐120	NUM
eurjchem-828	100	2	oc/0.2	oc/0.2	NOUN
eurjchem-828	100	3	mmhg	mmhg	PROPN
eurjchem-828	100	4	.	.	PUNCT
eurjchem-828	101	1	ir	ir	PROPN
eurjchem-828	101	2	(	(	PUNCT
eurjchem-828	101	3	kbr	kbr	PROPN
eurjchem-828	101	4	,	,	PUNCT
eurjchem-828	101	5			PROPN
eurjchem-828	101	6	,	,	PUNCT
eurjchem-828	101	7	cm‐1	cm‐1	PROPN
eurjchem-828	101	8	):	):	PUNCT
eurjchem-828	101	9	3000	3000	NUM
eurjchem-828	101	10	(	(	PUNCT
eurjchem-828	101	11	c‐h	c‐h	NUM
eurjchem-828	101	12	)	)	PUNCT
eurjchem-828	101	13	,	,	PUNCT
eurjchem-828	101	14	1600	1600	NUM
eurjchem-828	101	15	,	,	PUNCT
eurjchem-828	101	16	1540	1540	NUM
eurjchem-828	101	17	,	,	PUNCT
eurjchem-828	101	18	1460	1460	NUM
eurjchem-828	101	19	(	(	PUNCT
eurjchem-828	101	20	c6h5	c6h5	NOUN
eurjchem-828	101	21	)	)	PUNCT
eurjchem-828	101	22	,	,	PUNCT
eurjchem-828	101	23	1770	1770	NUM
eurjchem-828	101	24	(	(	PUNCT
eurjchem-828	101	25	c	c	NOUN
eurjchem-828	101	26	=	=	NOUN
eurjchem-828	101	27	o	o	NOUN
eurjchem-828	101	28	)	)	PUNCT
eurjchem-828	101	29	,	,	PUNCT
eurjchem-828	101	30	1020	1020	NUM
eurjchem-828	101	31	(	(	PUNCT
eurjchem-828	101	32	p‐o‐c	p‐o‐c	PROPN
eurjchem-828	101	33	)	)	PUNCT
eurjchem-828	101	34	,	,	PUNCT
eurjchem-828	101	35	1210	1210	NUM
eurjchem-828	101	36	(	(	PUNCT
eurjchem-828	101	37	c‐o‐c	c‐o‐c	NOUN
eurjchem-828	101	38	)	)	PUNCT
eurjchem-828	101	39	.	.	PUNCT
eurjchem-828	102	1	ms	ms	NOUN
eurjchem-828	102	2	(	(	PUNCT
eurjchem-828	102	3	ei	ei	PROPN
eurjchem-828	102	4	,	,	PUNCT
eurjchem-828	102	5	m	m	PROPN
eurjchem-828	102	6	/	/	SYM
eurjchem-828	102	7	z	z	PROPN
eurjchem-828	102	8	(	(	PUNCT
eurjchem-828	102	9	%	%	NOUN
eurjchem-828	102	10	)	)	PUNCT
eurjchem-828	102	11	):	):	PUNCT
eurjchem-828	102	12	255	255	NUM
eurjchem-828	102	13	(	(	PUNCT
eurjchem-828	102	14	m+	m+	NUM
eurjchem-828	102	15	)	)	PUNCT
eurjchem-828	102	16	.	.	PUNCT
eurjchem-828	103	1	isopropyl	isopropyl	PROPN
eurjchem-828	103	2	1,3,2‐dioxaphosphinan‐2‐yl(phenyl)carbamate	1,3,2‐dioxaphosphinan‐2‐yl(phenyl)carbamate	PROPN
eurjchem-828	103	3	(	(	PUNCT
eurjchem-828	103	4	10l	10l	NUM
eurjchem-828	103	5	):	):	PUNCT
eurjchem-828	103	6	color	color	NOUN
eurjchem-828	103	7	:	:	PUNCT
eurjchem-828	103	8	white	white	ADJ
eurjchem-828	103	9	.	.	PUNCT
eurjchem-828	103	10	yield	yield	NOUN
eurjchem-828	103	11	:	:	PUNCT
eurjchem-828	103	12	64	64	NUM
eurjchem-828	103	13	%	%	NOUN
eurjchem-828	103	14	.	.	PUNCT
eurjchem-828	104	1	m.p	m.p	PROPN
eurjchem-828	104	2	.	.	PROPN
eurjchem-828	104	3	:	:	PUNCT
eurjchem-828	104	4	73‐75	73‐75	NUM
eurjchem-828	104	5	oc	oc	NOUN
eurjchem-828	104	6	(	(	PUNCT
eurjchem-828	104	7	crystallized	crystallize	VERB
eurjchem-828	104	8	in	in	ADP
eurjchem-828	104	9	petroleum	petroleum	NOUN
eurjchem-828	104	10	ether	ether	NOUN
eurjchem-828	104	11	)	)	PUNCT
eurjchem-828	104	12	.	.	PUNCT
eurjchem-828	105	1	ir	ir	PROPN
eurjchem-828	105	2	(	(	PUNCT
eurjchem-828	105	3	kbr	kbr	PROPN
eurjchem-828	105	4	,	,	PUNCT
eurjchem-828	105	5			PROPN
eurjchem-828	105	6	,	,	PUNCT
eurjchem-828	105	7	cm‐1	cm‐1	PROPN
eurjchem-828	105	8	):	):	PUNCT
eurjchem-828	105	9	3000	3000	NUM
eurjchem-828	105	10	(	(	PUNCT
eurjchem-828	105	11	c‐h	c‐h	NUM
eurjchem-828	105	12	)	)	PUNCT
eurjchem-828	105	13	,	,	PUNCT
eurjchem-828	105	14	1600	1600	NUM
eurjchem-828	105	15	,	,	PUNCT
eurjchem-828	105	16	1540	1540	NUM
eurjchem-828	105	17	,	,	PUNCT
eurjchem-828	105	18	1450	1450	NUM
eurjchem-828	105	19	(	(	PUNCT
eurjchem-828	105	20	c6h5	c6h5	NOUN
eurjchem-828	105	21	)	)	PUNCT
eurjchem-828	105	22	,	,	PUNCT
eurjchem-828	105	23	1750	1750	NUM
eurjchem-828	105	24	(	(	PUNCT
eurjchem-828	105	25	c	c	NOUN
eurjchem-828	105	26	=	=	NOUN
eurjchem-828	105	27	o	o	NOUN
eurjchem-828	105	28	)	)	PUNCT
eurjchem-828	105	29	,	,	PUNCT
eurjchem-828	105	30	1040	1040	NUM
eurjchem-828	105	31	(	(	PUNCT
eurjchem-828	105	32	p‐o‐c	p‐o‐c	NOUN
eurjchem-828	105	33	)	)	PUNCT
eurjchem-828	105	34	.	.	PUNCT
eurjchem-828	106	1	ms	ms	NOUN
eurjchem-828	106	2	(	(	PUNCT
eurjchem-828	106	3	ei	ei	PROPN
eurjchem-828	106	4	,	,	PUNCT
eurjchem-828	106	5	m	m	PROPN
eurjchem-828	106	6	/	/	SYM
eurjchem-828	106	7	z	z	PROPN
eurjchem-828	106	8	(	(	PUNCT
eurjchem-828	106	9	%	%	NOUN
eurjchem-828	106	10	)	)	PUNCT
eurjchem-828	106	11	):	):	PUNCT
eurjchem-828	106	12	299	299	NUM
eurjchem-828	106	13	(	(	PUNCT
eurjchem-828	106	14	(	(	PUNCT
eurjchem-828	106	15	m+o)+	m+o)+	PROPN
eurjchem-828	106	16	)	)	PUNCT
eurjchem-828	106	17	.	.	PUNCT
eurjchem-828	107	1	o‐methyl	o‐methyl	PROPN
eurjchem-828	108	1	1,3,2‐dioxaphosphinan‐2‐ylcarbamothioate	1,3,2‐dioxaphosphinan‐2‐ylcarbamothioate	NOUN
eurjchem-828	108	2	(	(	PUNCT
eurjchem-828	108	3	10	10	NUM
eurjchem-828	108	4	m	m	NOUN
eurjchem-828	108	5	):	):	PUNCT
eurjchem-828	108	6	color	color	NOUN
eurjchem-828	108	7	:	:	PUNCT
eurjchem-828	108	8	white	white	ADJ
eurjchem-828	108	9	.	.	PUNCT
eurjchem-828	109	1	yield	yield	NOUN
eurjchem-828	109	2	:	:	PUNCT
eurjchem-828	109	3	52	52	NUM
eurjchem-828	109	4	%	%	NOUN
eurjchem-828	109	5	.	.	PUNCT
eurjchem-828	110	1	m.p.:90‐91	m.p.:90‐91	PROPN
eurjchem-828	111	1	oc	oc	PROPN
eurjchem-828	111	2	.	.	PROPN
eurjchem-828	112	1	ir	ir	PROPN
eurjchem-828	112	2	(	(	PUNCT
eurjchem-828	112	3	kbr	kbr	PROPN
eurjchem-828	112	4	,	,	PUNCT
eurjchem-828	112	5			PROPN
eurjchem-828	112	6	,	,	PUNCT
eurjchem-828	112	7	cm‐1	cm‐1	PROPN
eurjchem-828	112	8	):	):	PUNCT
eurjchem-828	112	9	3000	3000	NUM
eurjchem-828	112	10	(	(	PUNCT
eurjchem-828	112	11	c‐h	c‐h	NUM
eurjchem-828	112	12	)	)	PUNCT
eurjchem-828	112	13	,	,	PUNCT
eurjchem-828	112	14	1600	1600	NUM
eurjchem-828	112	15	,	,	PUNCT
eurjchem-828	112	16	1500	1500	NUM
eurjchem-828	112	17	,	,	PUNCT
eurjchem-828	112	18	1450	1450	NUM
eurjchem-828	112	19	(	(	PUNCT
eurjchem-828	112	20	c6h5	c6h5	NOUN
eurjchem-828	112	21	)	)	PUNCT
eurjchem-828	112	22	,	,	PUNCT
eurjchem-828	112	23	1370	1370	NUM
eurjchem-828	112	24	(	(	PUNCT
eurjchem-828	112	25	c	c	NOUN
eurjchem-828	112	26	=	=	SYM
eurjchem-828	112	27	s	s	NOUN
eurjchem-828	112	28	)	)	PUNCT
eurjchem-828	112	29	,	,	PUNCT
eurjchem-828	112	30	1020	1020	NUM
eurjchem-828	112	31	(	(	PUNCT
eurjchem-828	112	32	p‐o‐c	p‐o‐c	PROPN
eurjchem-828	112	33	)	)	PUNCT
eurjchem-828	112	34	.	.	PUNCT
eurjchem-828	113	1	2.2	2.2	NUM
eurjchem-828	113	2	.	.	PUNCT
eurjchem-828	113	3	reactions	reaction	NOUN
eurjchem-828	113	4	with	with	ADP
eurjchem-828	113	5	elemental	elemental	ADJ
eurjchem-828	113	6	sulphur	sulphur	NOUN
eurjchem-828	113	7	for	for	ADP
eurjchem-828	113	8	synthesis	synthesis	NOUN
eurjchem-828	113	9	of	of	ADP
eurjchem-828	113	10	phosphorylated	phosphorylate	VERB
eurjchem-828	113	11	carbamates	carbamate	NOUN
eurjchem-828	113	12	with	with	ADP
eurjchem-828	113	13	p	p	NOUN
eurjchem-828	113	14	=	=	NOUN
eurjchem-828	113	15	s	s	PART
eurjchem-828	113	16	bond	bond	NOUN
eurjchem-828	113	17	corresponding	correspond	VERB
eurjchem-828	113	18	reactants	reactant	NOUN
eurjchem-828	113	19	were	be	AUX
eurjchem-828	113	20	put	put	VERB
eurjchem-828	113	21	in	in	ADP
eurjchem-828	113	22	contact	contact	NOUN
eurjchem-828	113	23	with	with	ADP
eurjchem-828	113	24	elemental	elemental	ADJ
eurjchem-828	113	25	sulphur	sulphur	NOUN
eurjchem-828	113	26	in	in	ADP
eurjchem-828	113	27	dioxane	dioxane	NOUN
eurjchem-828	113	28	(	(	PUNCT
eurjchem-828	113	29	scheme	scheme	NOUN
eurjchem-828	113	30	5	5	NUM
eurjchem-828	113	31	)	)	PUNCT
eurjchem-828	113	32	.	.	PUNCT
eurjchem-828	114	1	the	the	DET
eurjchem-828	114	2	list	list	NOUN
eurjchem-828	114	3	of	of	ADP
eurjchem-828	114	4	synthesized	synthesize	VERB
eurjchem-828	114	5	compounds	compound	NOUN
eurjchem-828	114	6	in	in	SCONJ
eurjchem-828	114	7	displayed	display	VERB
eurjchem-828	114	8	in	in	ADP
eurjchem-828	114	9	table	table	NOUN
eurjchem-828	114	10	3	3	NUM
eurjchem-828	114	11	.	.	PUNCT
eurjchem-828	115	1	few	few	ADJ
eurjchem-828	115	2	drops	drop	NOUN
eurjchem-828	115	3	of	of	ADP
eurjchem-828	115	4	the	the	DET
eurjchem-828	115	5	catalyst	catalyst	NOUN
eurjchem-828	115	6	‐triethylamine	‐triethylamine	PROPN
eurjchem-828	115	7	were	be	AUX
eurjchem-828	115	8	added	add	VERB
eurjchem-828	115	9	.	.	PUNCT
eurjchem-828	116	1	the	the	DET
eurjchem-828	116	2	mixture	mixture	NOUN
eurjchem-828	116	3	was	be	AUX
eurjchem-828	116	4	kept	keep	VERB
eurjchem-828	116	5	boiling	boil	VERB
eurjchem-828	116	6	for	for	ADP
eurjchem-828	116	7	ca	ca	NOUN
eurjchem-828	116	8	.	.	PUNCT
eurjchem-828	117	1	6	6	NUM
eurjchem-828	117	2	h.	h.	NOUN
eurjchem-828	117	3	after	after	ADP
eurjchem-828	117	4	evaporating	evaporate	VERB
eurjchem-828	117	5	the	the	DET
eurjchem-828	117	6	solvent	solvent	NOUN
eurjchem-828	117	7	,	,	PUNCT
eurjchem-828	117	8	the	the	DET
eurjchem-828	117	9	products	product	NOUN
eurjchem-828	117	10	underwent	undergo	VERB
eurjchem-828	117	11	crystallization	crystallization	NOUN
eurjchem-828	117	12	by	by	ADP
eurjchem-828	117	13	adding	add	VERB
eurjchem-828	117	14	first	first	ADJ
eurjchem-828	117	15	toluene	toluene	NOUN
eurjchem-828	117	16	and	and	CCONJ
eurjchem-828	117	17	then	then	ADV
eurjchem-828	117	18	petroleum	petroleum	NOUN
eurjchem-828	117	19	ether	ether	NOUN
eurjchem-828	117	20	(	(	PUNCT
eurjchem-828	117	21	11a	11a	NUM
eurjchem-828	117	22	)	)	PUNCT
eurjchem-828	117	23	or	or	CCONJ
eurjchem-828	117	24	hexane	hexane	NOUN
eurjchem-828	117	25	(	(	PUNCT
eurjchem-828	117	26	11c	11c	NOUN
eurjchem-828	117	27	,	,	PUNCT
eurjchem-828	117	28	11d	11d	NUM
eurjchem-828	117	29	)	)	PUNCT
eurjchem-828	117	30	.	.	PUNCT
eurjchem-828	118	1	alternatively	alternatively	ADV
eurjchem-828	118	2	after	after	SCONJ
eurjchem-828	118	3	solvent	solvent	ADJ
eurjchem-828	118	4	evaporation	evaporation	NOUN
eurjchem-828	118	5	further	further	ADJ
eurjchem-828	118	6	distillation	distillation	NOUN
eurjchem-828	118	7	/	/	SYM
eurjchem-828	118	8	treatment	treatment	NOUN
eurjchem-828	118	9	under	under	ADP
eurjchem-828	118	10	vacuum	vacuum	NOUN
eurjchem-828	118	11	(	(	PUNCT
eurjchem-828	118	12	1	1	NUM
eurjchem-828	118	13	mm	mm	NUM
eurjchem-828	118	14	hg	hg	NOUN
eurjchem-828	118	15	)	)	PUNCT
eurjchem-828	118	16	was	be	AUX
eurjchem-828	118	17	performed	perform	VERB
eurjchem-828	118	18	(	(	PUNCT
eurjchem-828	118	19	11e	11e	NOUN
eurjchem-828	118	20	,	,	PUNCT
eurjchem-828	118	21	11f	11f	NUM
eurjchem-828	118	22	)	)	PUNCT
eurjchem-828	118	23	leading	lead	VERB
eurjchem-828	118	24	to	to	ADP
eurjchem-828	118	25	viscosous	viscosous	ADJ
eurjchem-828	118	26	oil	oil	NOUN
eurjchem-828	118	27	.	.	PUNCT
eurjchem-828	119	1	compound	compound	NOUN
eurjchem-828	119	2	11b	11b	NOUN
eurjchem-828	119	3	was	be	AUX
eurjchem-828	119	4	purified	purify	VERB
eurjchem-828	119	5	using	use	VERB
eurjchem-828	119	6	tlc	tlc	NOUN
eurjchem-828	119	7	with	with	ADP
eurjchem-828	119	8	eluent	eluent	NOUN
eurjchem-828	119	9	chcl3	chcl3	PROPN
eurjchem-828	119	10	.	.	PUNCT
eurjchem-828	120	1	conditions	condition	NOUN
eurjchem-828	120	2	of	of	ADP
eurjchem-828	120	3	experiments	experiment	NOUN
eurjchem-828	120	4	are	be	AUX
eurjchem-828	120	5	summarized	summarize	VERB
eurjchem-828	120	6	in	in	ADP
eurjchem-828	120	7	table	table	NOUN
eurjchem-828	120	8	4	4	NUM
eurjchem-828	120	9	.	.	PUNCT
eurjchem-828	120	10	o‐isopropyl	o‐isopropyl	PUNCT
eurjchem-828	121	1	phenyl(2‐sulfido‐1,3,2‐dioxaphospholan‐2‐yl	phenyl(2‐sulfido‐1,3,2‐dioxaphospholan‐2‐yl	ADJ
eurjchem-828	121	2	)	)	PUNCT
eurjchem-828	121	3	carbamate	carbamate	PROPN
eurjchem-828	121	4	(	(	PUNCT
eurjchem-828	121	5	11a	11a	NUM
eurjchem-828	121	6	):	):	PUNCT
eurjchem-828	121	7	color	color	NOUN
eurjchem-828	121	8	:	:	PUNCT
eurjchem-828	121	9	white	white	ADJ
eurjchem-828	121	10	.	.	PUNCT
eurjchem-828	122	1	yield	yield	NOUN
eurjchem-828	122	2	:	:	PUNCT
eurjchem-828	122	3	39	39	NUM
eurjchem-828	122	4	%	%	NOUN
eurjchem-828	122	5	.	.	PUNCT
eurjchem-828	123	1	m.p	m.p	PROPN
eurjchem-828	123	2	.	.	PROPN
eurjchem-828	123	3	:	:	PUNCT
eurjchem-828	123	4	96‐98	96‐98	NUM
eurjchem-828	123	5	oc	oc	NOUN
eurjchem-828	123	6	.	.	PUNCT
eurjchem-828	124	1	ir	ir	PROPN
eurjchem-828	124	2	(	(	PUNCT
eurjchem-828	124	3	kbr	kbr	PROPN
eurjchem-828	124	4	,	,	PUNCT
eurjchem-828	124	5			PROPN
eurjchem-828	124	6	,	,	PUNCT
eurjchem-828	124	7	cm‐1	cm‐1	PROPN
eurjchem-828	124	8	):	):	PUNCT
eurjchem-828	124	9	1600	1600	NUM
eurjchem-828	124	10	,	,	PUNCT
eurjchem-828	124	11	1500	1500	NUM
eurjchem-828	124	12	,	,	PUNCT
eurjchem-828	124	13	1470	1470	NUM
eurjchem-828	124	14	(	(	PUNCT
eurjchem-828	124	15	c6h5	c6h5	NOUN
eurjchem-828	124	16	)	)	PUNCT
eurjchem-828	124	17	,	,	PUNCT
eurjchem-828	124	18	1740	1740	NUM
eurjchem-828	124	19	(	(	PUNCT
eurjchem-828	124	20	c	c	NOUN
eurjchem-828	124	21	=	=	NOUN
eurjchem-828	124	22	o	o	NOUN
eurjchem-828	124	23	)	)	PUNCT
eurjchem-828	124	24	,	,	PUNCT
eurjchem-828	124	25	840	840	NUM
eurjchem-828	124	26	(	(	PUNCT
eurjchem-828	124	27	p	p	NOUN
eurjchem-828	124	28	=	=	SYM
eurjchem-828	124	29	s	s	PART
eurjchem-828	124	30	)	)	PUNCT
eurjchem-828	124	31	.	.	PUNCT
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eurjchem-828	125	2	and	and	CCONJ
eurjchem-828	125	3	kolesova	kolesova	PROPN
eurjchem-828	125	4	/	/	SYM
eurjchem-828	125	5	european	european	PROPN
eurjchem-828	125	6	journal	journal	PROPN
eurjchem-828	125	7	of	of	ADP
eurjchem-828	125	8	chemistry	chemistry	NOUN
eurjchem-828	125	9	4	4	NUM
eurjchem-828	125	10	(	(	PUNCT
eurjchem-828	125	11	4	4	NUM
eurjchem-828	125	12	)	)	PUNCT
eurjchem-828	125	13	(	(	PUNCT
eurjchem-828	125	14	2013	2013	NUM
eurjchem-828	125	15	)	)	PUNCT
eurjchem-828	125	16	336‐342	336‐342	PROPN
eurjchem-828	125	17	339	339	NUM
eurjchem-828	126	1	10	10	NUM
eurjchem-828	126	2	+	+	SYM
eurjchem-828	126	3	s	s	NOUN
eurjchem-828	126	4	11	11	NUM
eurjchem-828	126	5	p	p	NOUN
eurjchem-828	126	6	o	o	X
eurjchem-828	126	7	o	o	X
eurjchem-828	126	8	n(h2c	n(h2c	NOUN
eurjchem-828	126	9	)	)	PUNCT
eurjchem-828	126	10	n	n	NOUN
eurjchem-828	126	11	r	r	NOUN
eurjchem-828	126	12	x	x	PUNCT
eurjchem-828	126	13	o	o	NOUN
eurjchem-828	126	14	r1	r1	NOUN
eurjchem-828	126	15	p	p	X
eurjchem-828	126	16	o	o	X
eurjchem-828	126	17	o	o	X
eurjchem-828	126	18	n(h2c	n(h2c	NOUN
eurjchem-828	126	19	)	)	PUNCT
eurjchem-828	126	20	n	n	NOUN
eurjchem-828	126	21	r	r	NOUN
eurjchem-828	126	22	x	x	PUNCT
eurjchem-828	126	23	o	o	X
eurjchem-828	126	24	r1	r1	PROPN
eurjchem-828	126	25	s	s	PART
eurjchem-828	126	26	scheme	scheme	NOUN
eurjchem-828	126	27	5	5	NUM
eurjchem-828	126	28	scheme	scheme	NOUN
eurjchem-828	126	29	6	6	NUM
eurjchem-828	126	30	31p	31p	NOUN
eurjchem-828	126	31	nmr	nmr	NOUN
eurjchem-828	126	32	(	(	PUNCT
eurjchem-828	126	33	36.43	36.43	NUM
eurjchem-828	126	34	mhz	mhz	NOUN
eurjchem-828	126	35	,	,	PUNCT
eurjchem-828	126	36	85%h3po4	85%h3po4	PROPN
eurjchem-828	126	37	,	,	PUNCT
eurjchem-828	126	38	δ	δ	PROPN
eurjchem-828	126	39	,	,	PUNCT
eurjchem-828	126	40	ppm	ppm	NOUN
eurjchem-828	126	41	):	):	PUNCT
eurjchem-828	126	42	82.3	82.3	NUM
eurjchem-828	126	43	.	.	PUNCT
eurjchem-828	127	1	ms	ms	NOUN
eurjchem-828	127	2	(	(	PUNCT
eurjchem-828	127	3	ei	ei	PROPN
eurjchem-828	127	4	,	,	PUNCT
eurjchem-828	127	5	m	m	PROPN
eurjchem-828	127	6	/	/	SYM
eurjchem-828	127	7	z	z	PROPN
eurjchem-828	127	8	(	(	PUNCT
eurjchem-828	127	9	%	%	NOUN
eurjchem-828	127	10	)	)	PUNCT
eurjchem-828	127	11	):	):	PUNCT
eurjchem-828	127	12	301	301	NUM
eurjchem-828	127	13	(	(	PUNCT
eurjchem-828	127	14	15.47	15.47	NUM
eurjchem-828	127	15	%	%	NOUN
eurjchem-828	127	16	)	)	PUNCT
eurjchem-828	127	17	m+	m+	NOUN
eurjchem-828	127	18	.	.	PUNCT
eurjchem-828	128	1	anal	anal	PROPN
eurjchem-828	128	2	.	.	PUNCT
eurjchem-828	128	3	calcd	calcd	NOUN
eurjchem-828	128	4	.	.	PUNCT
eurjchem-828	129	1	for	for	ADP
eurjchem-828	129	2	c5h10no3ps	c5h10no3ps	NUM
eurjchem-828	129	3	:	:	PUNCT
eurjchem-828	129	4	c	c	X
eurjchem-828	129	5	,	,	PUNCT
eurjchem-828	129	6	47.77	47.77	NUM
eurjchem-828	129	7	;	;	PUNCT
eurjchem-828	129	8	h	h	NOUN
eurjchem-828	129	9	,	,	PUNCT
eurjchem-828	129	10	5.42	5.42	NUM
eurjchem-828	129	11	;	;	PUNCT
eurjchem-828	129	12	n	n	CCONJ
eurjchem-828	129	13	,	,	PUNCT
eurjchem-828	129	14	4.70	4.70	NUM
eurjchem-828	129	15	.	.	PUNCT
eurjchem-828	129	16	found	find	VERB
eurjchem-828	129	17	:	:	PUNCT
eurjchem-828	130	1	c	c	X
eurjchem-828	130	2	,	,	PUNCT
eurjchem-828	130	3	47.80	47.80	NUM
eurjchem-828	130	4	;	;	PUNCT
eurjchem-828	130	5	h	h	NOUN
eurjchem-828	130	6	,	,	PUNCT
eurjchem-828	130	7	5.31	5.31	NUM
eurjchem-828	130	8	;	;	PUNCT
eurjchem-828	130	9	n	n	CCONJ
eurjchem-828	130	10	,	,	PUNCT
eurjchem-828	130	11	5.22	5.22	NUM
eurjchem-828	130	12	%	%	NOUN
eurjchem-828	130	13	.	.	PUNCT
eurjchem-828	130	14	o‐isopropyl	o‐isopropyl	PUNCT
eurjchem-828	131	1	2‐chlorophenyl(2‐sulfido‐1,3,2‐dioxaphospholan‐	2‐chlorophenyl(2‐sulfido‐1,3,2‐dioxaphospholan‐	NUM
eurjchem-828	131	2	2‐yl)carbamate	2‐yl)carbamate	NUM
eurjchem-828	131	3	(	(	PUNCT
eurjchem-828	131	4	11b	11b	NOUN
eurjchem-828	131	5	):	):	PUNCT
eurjchem-828	131	6	color	color	NOUN
eurjchem-828	131	7	:	:	PUNCT
eurjchem-828	131	8	white	white	ADJ
eurjchem-828	131	9	.	.	PUNCT
eurjchem-828	132	1	yield	yield	NOUN
eurjchem-828	132	2	:	:	PUNCT
eurjchem-828	132	3	20	20	NUM
eurjchem-828	132	4	%	%	NOUN
eurjchem-828	132	5	.	.	PUNCT
eurjchem-828	133	1	m.p	m.p	PROPN
eurjchem-828	133	2	.	.	PROPN
eurjchem-828	133	3	:	:	PUNCT
eurjchem-828	134	1	101‐103	101‐103	NUM
eurjchem-828	134	2	oc	oc	PROPN
eurjchem-828	134	3	.	.	PROPN
eurjchem-828	134	4	ir	ir	PROPN
eurjchem-828	134	5	(	(	PUNCT
eurjchem-828	134	6	kbr	kbr	PROPN
eurjchem-828	134	7	,	,	PUNCT
eurjchem-828	134	8			PROPN
eurjchem-828	134	9	,	,	PUNCT
eurjchem-828	134	10	cm‐1	cm‐1	PROPN
eurjchem-828	134	11	):	):	PUNCT
eurjchem-828	134	12	2990	2990	NUM
eurjchem-828	134	13	(	(	PUNCT
eurjchem-828	134	14	ch	ch	NOUN
eurjchem-828	134	15	)	)	PUNCT
eurjchem-828	134	16	,	,	PUNCT
eurjchem-828	134	17	1595	1595	NUM
eurjchem-828	134	18	,	,	PUNCT
eurjchem-828	134	19	1530	1530	NUM
eurjchem-828	134	20	,	,	PUNCT
eurjchem-828	134	21	1440	1440	NUM
eurjchem-828	134	22	(	(	PUNCT
eurjchem-828	134	23	c6h5	c6h5	NOUN
eurjchem-828	134	24	)	)	PUNCT
eurjchem-828	134	25	,	,	PUNCT
eurjchem-828	134	26	1730	1730	NUM
eurjchem-828	134	27	(	(	PUNCT
eurjchem-828	134	28	c	c	NOUN
eurjchem-828	134	29	=	=	NOUN
eurjchem-828	134	30	o	o	NOUN
eurjchem-828	134	31	)	)	PUNCT
eurjchem-828	134	32	,	,	PUNCT
eurjchem-828	134	33	1230	1230	NUM
eurjchem-828	134	34	(	(	PUNCT
eurjchem-828	134	35	c‐o‐c	c‐o‐c	NOUN
eurjchem-828	134	36	)	)	PUNCT
eurjchem-828	134	37	,	,	PUNCT
eurjchem-828	134	38	995	995	NUM
eurjchem-828	134	39	(	(	PUNCT
eurjchem-828	134	40	p‐o‐c	p‐o‐c	PROPN
eurjchem-828	134	41	)	)	PUNCT
eurjchem-828	134	42	,	,	PUNCT
eurjchem-828	134	43	770	770	NUM
eurjchem-828	134	44	,	,	PUNCT
eurjchem-828	134	45	690	690	NUM
eurjchem-828	134	46	(	(	PUNCT
eurjchem-828	134	47	p	p	NOUN
eurjchem-828	134	48	=	=	SYM
eurjchem-828	134	49	s	s	PART
eurjchem-828	134	50	)	)	PUNCT
eurjchem-828	134	51	.	.	PUNCT
eurjchem-828	134	52	o‐methyl	o‐methyl	PUNCT
eurjchem-828	135	1	phenyl	phenyl	NOUN
eurjchem-828	135	2	2‐sulfido‐	2‐sulfido‐	NUM
eurjchem-828	135	3	1,3,2‐dioxaphospholan‐2‐yl‐	1,3,2‐dioxaphospholan‐2‐yl‐	NUM
eurjchem-828	135	4	carbamothioate	carbamothioate	NOUN
eurjchem-828	135	5	(	(	PUNCT
eurjchem-828	135	6	11c	11c	NOUN
eurjchem-828	135	7	):	):	PUNCT
eurjchem-828	135	8	color	color	NOUN
eurjchem-828	135	9	:	:	PUNCT
eurjchem-828	135	10	white	white	ADJ
eurjchem-828	135	11	.	.	PUNCT
eurjchem-828	135	12	yield	yield	NOUN
eurjchem-828	135	13	:	:	PUNCT
eurjchem-828	135	14	27	27	NUM
eurjchem-828	135	15	%	%	NOUN
eurjchem-828	135	16	.	.	PUNCT
eurjchem-828	136	1	m.p	m.p	PROPN
eurjchem-828	136	2	.	.	PROPN
eurjchem-828	136	3	:	:	PUNCT
eurjchem-828	137	1	110‐112	110‐112	NUM
eurjchem-828	137	2	oc	oc	PROPN
eurjchem-828	137	3	.	.	PROPN
eurjchem-828	137	4	ir	ir	PROPN
eurjchem-828	137	5	(	(	PUNCT
eurjchem-828	137	6	kbr	kbr	PROPN
eurjchem-828	137	7	,	,	PUNCT
eurjchem-828	137	8			PROPN
eurjchem-828	137	9	,	,	PUNCT
eurjchem-828	137	10	cm‐1	cm‐1	PROPN
eurjchem-828	137	11	):	):	PUNCT
eurjchem-828	137	12	1590	1590	NUM
eurjchem-828	137	13	,	,	PUNCT
eurjchem-828	137	14	1530	1530	NUM
eurjchem-828	137	15	(	(	PUNCT
eurjchem-828	137	16	c6h5	c6h5	NOUN
eurjchem-828	137	17	)	)	PUNCT
eurjchem-828	137	18	,	,	PUNCT
eurjchem-828	137	19	1730	1730	NUM
eurjchem-828	137	20	(	(	PUNCT
eurjchem-828	137	21	c	c	NOUN
eurjchem-828	137	22	=	=	NOUN
eurjchem-828	137	23	o	o	NOUN
eurjchem-828	137	24	)	)	PUNCT
eurjchem-828	137	25	,	,	PUNCT
eurjchem-828	137	26	1390	1390	NUM
eurjchem-828	137	27	(	(	PUNCT
eurjchem-828	137	28	c	c	NOUN
eurjchem-828	137	29	=	=	SYM
eurjchem-828	137	30	s	s	NOUN
eurjchem-828	137	31	)	)	PUNCT
eurjchem-828	137	32	,	,	PUNCT
eurjchem-828	137	33	780	780	NUM
eurjchem-828	137	34	(	(	PUNCT
eurjchem-828	137	35	p	p	NOUN
eurjchem-828	137	36	=	=	NOUN
eurjchem-828	137	37	s	s	PART
eurjchem-828	137	38	)	)	PUNCT
eurjchem-828	137	39	.	.	PUNCT
eurjchem-828	137	40	o‐isopropyl	o‐isopropyl	PUNCT
eurjchem-828	138	1	phenyl	phenyl	NOUN
eurjchem-828	138	2	2‐sulfido‐	2‐sulfido‐	NUM
eurjchem-828	138	3	1,3,2‐dioxaphospholan‐2‐yl	1,3,2‐dioxaphospholan‐2‐yl	NUM
eurjchem-828	138	4	carbamothioate	carbamothioate	NOUN
eurjchem-828	138	5	(	(	PUNCT
eurjchem-828	138	6	11d	11d	X
eurjchem-828	138	7	):	):	PUNCT
eurjchem-828	138	8	color	color	NOUN
eurjchem-828	138	9	:	:	PUNCT
eurjchem-828	138	10	white	white	ADJ
eurjchem-828	138	11	.	.	PUNCT
eurjchem-828	139	1	yield	yield	NOUN
eurjchem-828	139	2	:	:	PUNCT
eurjchem-828	139	3	34	34	NUM
eurjchem-828	139	4	%	%	NOUN
eurjchem-828	139	5	.	.	PUNCT
eurjchem-828	140	1	m.p	m.p	PROPN
eurjchem-828	140	2	.	.	PROPN
eurjchem-828	140	3	:	:	PUNCT
eurjchem-828	141	1	150‐151	150‐151	NUM
eurjchem-828	141	2	oc	oc	PROPN
eurjchem-828	141	3	.	.	PROPN
eurjchem-828	141	4	ir	ir	PROPN
eurjchem-828	141	5	(	(	PUNCT
eurjchem-828	141	6	kbr	kbr	PROPN
eurjchem-828	141	7	,	,	PUNCT
eurjchem-828	141	8			PROPN
eurjchem-828	141	9	,	,	PUNCT
eurjchem-828	141	10	cm‐1	cm‐1	PROPN
eurjchem-828	141	11	):	):	PUNCT
eurjchem-828	141	12	2980	2980	NUM
eurjchem-828	141	13	(	(	PUNCT
eurjchem-828	141	14	ch	ch	NOUN
eurjchem-828	141	15	)	)	PUNCT
eurjchem-828	141	16	,	,	PUNCT
eurjchem-828	141	17	1595	1595	NUM
eurjchem-828	141	18	,	,	PUNCT
eurjchem-828	141	19	1530	1530	NUM
eurjchem-828	141	20	,	,	PUNCT
eurjchem-828	141	21	1440	1440	NUM
eurjchem-828	141	22	(	(	PUNCT
eurjchem-828	141	23	c6h5	c6h5	NOUN
eurjchem-828	141	24	)	)	PUNCT
eurjchem-828	141	25	,	,	PUNCT
eurjchem-828	141	26	1380	1380	NUM
eurjchem-828	141	27	(	(	PUNCT
eurjchem-828	141	28	c	c	NOUN
eurjchem-828	141	29	=	=	SYM
eurjchem-828	141	30	s	s	NOUN
eurjchem-828	141	31	)	)	PUNCT
eurjchem-828	141	32	,	,	PUNCT
eurjchem-828	141	33	990	990	NUM
eurjchem-828	141	34	(	(	PUNCT
eurjchem-828	141	35	p‐o‐c	p‐o‐c	PROPN
eurjchem-828	141	36	)	)	PUNCT
eurjchem-828	141	37	,	,	PUNCT
eurjchem-828	141	38	690	690	NUM
eurjchem-828	141	39	,	,	PUNCT
eurjchem-828	141	40	770	770	NUM
eurjchem-828	141	41	,	,	PUNCT
eurjchem-828	141	42	(	(	PUNCT
eurjchem-828	141	43	p	p	NOUN
eurjchem-828	141	44	=	=	NOUN
eurjchem-828	141	45	s	s	PART
eurjchem-828	141	46	)	)	PUNCT
eurjchem-828	141	47	.	.	PUNCT
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eurjchem-828	142	2	(	(	PUNCT
eurjchem-828	142	3	ei	ei	PROPN
eurjchem-828	142	4	,	,	PUNCT
eurjchem-828	142	5	m	m	PROPN
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eurjchem-828	142	8	(	(	PUNCT
eurjchem-828	142	9	%	%	NOUN
eurjchem-828	142	10	)	)	PUNCT
eurjchem-828	142	11	):	):	PUNCT
eurjchem-828	142	12	139	139	NUM
eurjchem-828	142	13	(	(	PUNCT
eurjchem-828	142	14	ch2o)2psnh2	ch2o)2psnh2	PROPN
eurjchem-828	142	15	+	+	PROPN
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eurjchem-828	142	17	8.65	8.65	NUM
eurjchem-828	142	18	)	)	PUNCT
eurjchem-828	142	19	,	,	PUNCT
eurjchem-828	142	20	123	123	NUM
eurjchem-828	142	21	(	(	PUNCT
eurjchem-828	142	22	ch2o)2ps+	ch2o)2ps+	PROPN
eurjchem-828	142	23	,	,	PUNCT
eurjchem-828	142	24	(	(	PUNCT
eurjchem-828	142	25	11.52	11.52	NUM
eurjchem-828	142	26	)	)	PUNCT
eurjchem-828	142	27	)	)	PUNCT
eurjchem-828	142	28	.	.	PUNCT
eurjchem-828	142	29	o‐methyl	o‐methyl	PROPN
eurjchem-828	143	1	phenyl(2‐sulfido‐1,3,2‐dioxaphosphinan‐2‐yl	phenyl(2‐sulfido‐1,3,2‐dioxaphosphinan‐2‐yl	PROPN
eurjchem-828	143	2	)	)	PUNCT
eurjchem-828	143	3	carbamate	carbamate	PROPN
eurjchem-828	143	4	(	(	PUNCT
eurjchem-828	143	5	11e	11e	NUM
eurjchem-828	143	6	):	):	PUNCT
eurjchem-828	143	7	yield	yield	NOUN
eurjchem-828	143	8	:	:	PUNCT
eurjchem-828	143	9	59	59	NUM
eurjchem-828	143	10	%	%	NOUN
eurjchem-828	143	11	.	.	PUNCT
eurjchem-828	144	1	ir	ir	PROPN
eurjchem-828	144	2	(	(	PUNCT
eurjchem-828	144	3	kbr	kbr	PROPN
eurjchem-828	144	4	,	,	PUNCT
eurjchem-828	144	5			PROPN
eurjchem-828	144	6	,	,	PUNCT
eurjchem-828	144	7	cm‐1	cm‐1	PROPN
eurjchem-828	144	8	):	):	PUNCT
eurjchem-828	144	9	1600	1600	NUM
eurjchem-828	144	10	,	,	PUNCT
eurjchem-828	144	11	1530	1530	NUM
eurjchem-828	144	12	,	,	PUNCT
eurjchem-828	144	13	1450	1450	NUM
eurjchem-828	144	14	(	(	PUNCT
eurjchem-828	144	15	c6h5	c6h5	NOUN
eurjchem-828	144	16	)	)	PUNCT
eurjchem-828	144	17	,	,	PUNCT
eurjchem-828	144	18	1720	1720	NUM
eurjchem-828	144	19	(	(	PUNCT
eurjchem-828	144	20	c	c	NOUN
eurjchem-828	144	21	=	=	NOUN
eurjchem-828	144	22	o	o	NOUN
eurjchem-828	144	23	)	)	PUNCT
eurjchem-828	144	24	,	,	PUNCT
eurjchem-828	144	25	1220	1220	NUM
eurjchem-828	144	26	cm‐1(c‐o‐c	cm‐1(c‐o‐c	NOUN
eurjchem-828	144	27	)	)	PUNCT
eurjchem-828	144	28	,	,	PUNCT
eurjchem-828	144	29	1020	1020	NUM
eurjchem-828	144	30	(	(	PUNCT
eurjchem-828	144	31	p‐o‐c	p‐o‐c	PROPN
eurjchem-828	144	32	)	)	PUNCT
eurjchem-828	144	33	,	,	PUNCT
eurjchem-828	144	34	690	690	NUM
eurjchem-828	144	35	,	,	PUNCT
eurjchem-828	144	36	760	760	NUM
eurjchem-828	144	37	,	,	PUNCT
eurjchem-828	144	38	(	(	PUNCT
eurjchem-828	144	39	p	p	NOUN
eurjchem-828	144	40	=	=	NOUN
eurjchem-828	144	41	s	s	PART
eurjchem-828	144	42	)	)	PUNCT
eurjchem-828	144	43	.	.	PUNCT
eurjchem-828	144	44	o‐methyl	o‐methyl	PROPN
eurjchem-828	145	1	phenyl	phenyl	NOUN
eurjchem-828	145	2	2‐sulfido‐1,3,2‐dioxaphosphinan‐2‐yl	2‐sulfido‐1,3,2‐dioxaphosphinan‐2‐yl	NUM
eurjchem-828	145	3	carbamothioate	carbamothioate	NOUN
eurjchem-828	145	4	(	(	PUNCT
eurjchem-828	145	5	11f	11f	NUM
eurjchem-828	145	6	):	):	PUNCT
eurjchem-828	145	7	yield	yield	NOUN
eurjchem-828	145	8	:	:	PUNCT
eurjchem-828	145	9	64	64	NUM
eurjchem-828	145	10	%	%	NOUN
eurjchem-828	145	11	.	.	PUNCT
eurjchem-828	146	1	ir	ir	PROPN
eurjchem-828	146	2	(	(	PUNCT
eurjchem-828	146	3	kbr	kbr	PROPN
eurjchem-828	146	4	,	,	PUNCT
eurjchem-828	146	5			PROPN
eurjchem-828	146	6	,	,	PUNCT
eurjchem-828	146	7	cm‐1	cm‐1	PROPN
eurjchem-828	146	8	):	):	PUNCT
eurjchem-828	146	9	1590	1590	NUM
eurjchem-828	146	10	,	,	PUNCT
eurjchem-828	146	11	1490	1490	NUM
eurjchem-828	146	12	(	(	PUNCT
eurjchem-828	146	13	c6h5	c6h5	NOUN
eurjchem-828	146	14	)	)	PUNCT
eurjchem-828	146	15	,	,	PUNCT
eurjchem-828	146	16	1380	1380	NUM
eurjchem-828	146	17	(	(	PUNCT
eurjchem-828	146	18	c	c	NOUN
eurjchem-828	146	19	=	=	SYM
eurjchem-828	146	20	s	s	NOUN
eurjchem-828	146	21	)	)	PUNCT
eurjchem-828	146	22	,	,	PUNCT
eurjchem-828	146	23	1220	1220	NUM
eurjchem-828	146	24	(	(	PUNCT
eurjchem-828	146	25	c‐o‐c	c‐o‐c	NOUN
eurjchem-828	146	26	)	)	PUNCT
eurjchem-828	146	27	,	,	PUNCT
eurjchem-828	146	28	1030	1030	NUM
eurjchem-828	146	29	(	(	PUNCT
eurjchem-828	146	30	p‐o‐c	p‐o‐c	PROPN
eurjchem-828	146	31	)	)	PUNCT
eurjchem-828	146	32	,	,	PUNCT
eurjchem-828	146	33	680	680	NUM
eurjchem-828	146	34	,	,	PUNCT
eurjchem-828	146	35	750	750	NUM
eurjchem-828	146	36	,	,	PUNCT
eurjchem-828	146	37	(	(	PUNCT
eurjchem-828	146	38	p	p	NOUN
eurjchem-828	146	39	=	=	NOUN
eurjchem-828	146	40	s	s	PART
eurjchem-828	146	41	)	)	PUNCT
eurjchem-828	146	42	.	.	PUNCT
eurjchem-828	147	1	table	table	NOUN
eurjchem-828	147	2	3	3	NUM
eurjchem-828	147	3	.	.	PUNCT
eurjchem-828	147	4	structure	structure	NOUN
eurjchem-828	147	5	of	of	ADP
eurjchem-828	147	6	synthesized	synthesize	VERB
eurjchem-828	147	7	compound	compound	NOUN
eurjchem-828	147	8	11	11	NUM
eurjchem-828	147	9	.	.	PUNCT
eurjchem-828	148	1	compound	compound	VERB
eurjchem-828	148	2	n	n	NOUN
eurjchem-828	148	3	x	x	SYM
eurjchem-828	148	4	r	r	NOUN
eurjchem-828	148	5	r1	r1	NOUN
eurjchem-828	148	6	11a	11a	NOUN
eurjchem-828	148	7	2	2	NUM
eurjchem-828	148	8	o	o	NOUN
eurjchem-828	148	9	c6h5	c6h5	PROPN
eurjchem-828	148	10	i‐c3h7	i‐c3h7	NOUN
eurjchem-828	148	11	11b	11b	NOUN
eurjchem-828	148	12	c6h4cl	c6h4cl	PROPN
eurjchem-828	148	13	i‐c3h7	i‐c3h7	NOUN
eurjchem-828	148	14	11c	11c	NUM
eurjchem-828	148	15	2	2	NUM
eurjchem-828	148	16	s	s	PART
eurjchem-828	148	17	c6h5	c6h5	PROPN
eurjchem-828	148	18	ch3	ch3	PROPN
eurjchem-828	148	19	11d	11d	PROPN
eurjchem-828	148	20	c6h5	c6h5	PROPN
eurjchem-828	148	21	i‐c3h7	i‐c3h7	NOUN
eurjchem-828	148	22	11e	11e	NOUN
eurjchem-828	148	23	3	3	NUM
eurjchem-828	148	24	o	o	PROPN
eurjchem-828	148	25	c6h5	c6h5	PROPN
eurjchem-828	148	26	ch3	ch3	PROPN
eurjchem-828	148	27	11f	11f	NOUN
eurjchem-828	148	28	s	s	PROPN
eurjchem-828	148	29	c6h5	c6h5	PROPN
eurjchem-828	148	30	ch3	ch3	PROPN
eurjchem-828	148	31	table	table	NOUN
eurjchem-828	148	32	4	4	NUM
eurjchem-828	148	33	.	.	PUNCT
eurjchem-828	149	1	ratio	ratio	NOUN
eurjchem-828	149	2	of	of	ADP
eurjchem-828	149	3	reactants	reactant	NOUN
eurjchem-828	149	4	in	in	ADP
eurjchem-828	149	5	reactions	reaction	NOUN
eurjchem-828	149	6	of	of	ADP
eurjchem-828	149	7	carbamates	carbamate	NOUN
eurjchem-828	149	8	with	with	ADP
eurjchem-828	149	9	sulphur	sulphur	NOUN
eurjchem-828	149	10	.	.	PUNCT
eurjchem-828	150	1	product/	product/	NUM
eurjchem-828	150	2	reactants	reactant	NOUN
eurjchem-828	150	3	carbamate	carbamate	PROPN
eurjchem-828	150	4	type	type	NOUN
eurjchem-828	150	5	carbamate	carbamate	NOUN
eurjchem-828	150	6	amount	amount	NOUN
eurjchem-828	150	7	,	,	PUNCT
eurjchem-828	150	8	mole	mole	NOUN
eurjchem-828	150	9	s	s	NOUN
eurjchem-828	150	10	,	,	PUNCT
eurjchem-828	150	11	mole	mole	ADJ
eurjchem-828	150	12	volume	volume	NOUN
eurjchem-828	150	13	of	of	ADP
eurjchem-828	150	14	solvent	solvent	ADJ
eurjchem-828	150	15	11a	11a	NOUN
eurjchem-828	150	16	10d	10d	NUM
eurjchem-828	150	17	0.025	0.025	NUM
eurjchem-828	150	18	0.025	0.025	NUM
eurjchem-828	150	19	30	30	NUM
eurjchem-828	150	20	11b	11b	NOUN
eurjchem-828	150	21	10e	10e	NOUN
eurjchem-828	150	22	0.010	0.010	NUM
eurjchem-828	150	23	0.010	0.010	NUM
eurjchem-828	150	24	50	50	NUM
eurjchem-828	150	25	11c	11c	NOUN
eurjchem-828	150	26	10	10	NUM
eurjchem-828	150	27	g	g	NOUN
eurjchem-828	150	28	0.030	0.030	NUM
eurjchem-828	150	29	0.030	0.030	NUM
eurjchem-828	150	30	25	25	NUM
eurjchem-828	150	31	11d	11d	NOUN
eurjchem-828	150	32	10h	10h	NUM
eurjchem-828	150	33	0.020	0.020	NUM
eurjchem-828	150	34	0.020	0.020	NUM
eurjchem-828	150	35	15	15	NUM
eurjchem-828	150	36	11e	11e	NOUN
eurjchem-828	150	37	10k	10k	X
eurjchem-828	150	38	0.025	0.025	NUM
eurjchem-828	150	39	0.025	0.025	NUM
eurjchem-828	150	40	20	20	NUM
eurjchem-828	150	41	11f	11f	NOUN
eurjchem-828	150	42	10	10	NUM
eurjchem-828	150	43	m	m	NUM
eurjchem-828	150	44	0.025	0.025	NUM
eurjchem-828	150	45	0.025	0.025	NUM
eurjchem-828	150	46	20	20	NUM
eurjchem-828	150	47	2.3	2.3	NUM
eurjchem-828	150	48	.	.	PUNCT
eurjchem-828	151	1	reaction	reaction	NOUN
eurjchem-828	151	2	with	with	ADP
eurjchem-828	151	3	methylchlorformate	methylchlorformate	PROPN
eurjchem-828	151	4	corresponding	corresponding	ADJ
eurjchem-828	151	5	phosphorylated	phosphorylate	VERB
eurjchem-828	151	6	carbamates	carbamate	NOUN
eurjchem-828	151	7	were	be	AUX
eurjchem-828	151	8	put	put	VERB
eurjchem-828	151	9	in	in	ADP
eurjchem-828	151	10	contact	contact	NOUN
eurjchem-828	151	11	with	with	ADP
eurjchem-828	151	12	methyl	methyl	NOUN
eurjchem-828	151	13	chlorformate	chlorformate	NOUN
eurjchem-828	151	14	in	in	ADP
eurjchem-828	151	15	dioxane	dioxane	NOUN
eurjchem-828	151	16	(	(	PUNCT
eurjchem-828	151	17	scheme	scheme	NOUN
eurjchem-828	151	18	6	6	NUM
eurjchem-828	151	19	)	)	PUNCT
eurjchem-828	151	20	and	and	CCONJ
eurjchem-828	151	21	the	the	DET
eurjchem-828	151	22	synthesized	synthesize	VERB
eurjchem-828	151	23	compounds	compound	NOUN
eurjchem-828	151	24	are	be	AUX
eurjchem-828	151	25	presented	present	VERB
eurjchem-828	151	26	in	in	ADP
eurjchem-828	151	27	table	table	NOUN
eurjchem-828	151	28	5	5	NUM
eurjchem-828	151	29	.	.	PUNCT
eurjchem-828	152	1	few	few	ADJ
eurjchem-828	152	2	drops	drop	NOUN
eurjchem-828	152	3	of	of	ADP
eurjchem-828	152	4	the	the	DET
eurjchem-828	152	5	catalyst	catalyst	NOUN
eurjchem-828	152	6	‐	‐	NOUN
eurjchem-828	152	7	triethylamine	triethylamine	NOUN
eurjchem-828	152	8	were	be	AUX
eurjchem-828	152	9	added	add	VERB
eurjchem-828	152	10	.	.	PUNCT
eurjchem-828	153	1	the	the	DET
eurjchem-828	153	2	mixture	mixture	NOUN
eurjchem-828	153	3	was	be	AUX
eurjchem-828	153	4	kept	keep	VERB
eurjchem-828	153	5	boiling	boil	VERB
eurjchem-828	153	6	.	.	PUNCT
eurjchem-828	154	1	after	after	ADP
eurjchem-828	154	2	evaporating	evaporate	VERB
eurjchem-828	154	3	the	the	DET
eurjchem-828	154	4	solvent	solvent	NOUN
eurjchem-828	154	5	the	the	DET
eurjchem-828	154	6	products	product	NOUN
eurjchem-828	154	7	12a	12a	NOUN
eurjchem-828	154	8	,	,	PUNCT
eurjchem-828	154	9	12b	12b	NOUN
eurjchem-828	154	10	slowly	slowly	ADV
eurjchem-828	154	11	crystallized	crystallize	VERB
eurjchem-828	154	12	.	.	PUNCT
eurjchem-828	155	1	compound	compound	NOUN
eurjchem-828	155	2	12a	12a	NOUN
eurjchem-828	155	3	was	be	AUX
eurjchem-828	155	4	purified	purify	VERB
eurjchem-828	155	5	using	use	VERB
eurjchem-828	155	6	tlc	tlc	NOUN
eurjchem-828	155	7	with	with	ADP
eurjchem-828	155	8	eluent	eluent	NOUN
eurjchem-828	155	9	chcl3	chcl3	PROPN
eurjchem-828	155	10	.	.	PUNCT
eurjchem-828	156	1	compound	compound	PROPN
eurjchem-828	156	2	12c	12c	NUM
eurjchem-828	156	3	is	be	AUX
eurjchem-828	156	4	an	an	DET
eurjchem-828	156	5	oily	oily	ADJ
eurjchem-828	156	6	compound	compound	NOUN
eurjchem-828	156	7	which	which	PRON
eurjchem-828	156	8	underwent	undergo	VERB
eurjchem-828	156	9	vacuum	vacuum	NOUN
eurjchem-828	156	10	treatment	treatment	NOUN
eurjchem-828	156	11	at	at	ADP
eurjchem-828	156	12	1	1	NUM
eurjchem-828	156	13	mm	mm	NUM
eurjchem-828	156	14	hg	hg	NOUN
eurjchem-828	156	15	.	.	PUNCT
eurjchem-828	157	1	alternatively	alternatively	ADV
eurjchem-828	157	2	after	after	ADP
eurjchem-828	157	3	solvent	solvent	ADJ
eurjchem-828	157	4	evaporation	evaporation	NOUN
eurjchem-828	157	5	subsequent	subsequent	ADJ
eurjchem-828	157	6	distillation	distillation	NOUN
eurjchem-828	157	7	under	under	ADP
eurjchem-828	157	8	vacuum	vacuum	NOUN
eurjchem-828	157	9	(	(	PUNCT
eurjchem-828	157	10	0.2	0.2	NUM
eurjchem-828	157	11	mm	mm	NUM
eurjchem-828	157	12	hg	hg	NOUN
eurjchem-828	157	13	)	)	PUNCT
eurjchem-828	157	14	was	be	AUX
eurjchem-828	157	15	performed	perform	VERB
eurjchem-828	157	16	(	(	PUNCT
eurjchem-828	157	17	12d	12d	NUM
eurjchem-828	157	18	,	,	PUNCT
eurjchem-828	157	19	12e	12e	NUM
eurjchem-828	157	20	,	,	PUNCT
eurjchem-828	157	21	12f	12f	NUM
eurjchem-828	157	22	)	)	PUNCT
eurjchem-828	157	23	leading	lead	VERB
eurjchem-828	157	24	to	to	ADP
eurjchem-828	157	25	viscosous	viscosous	ADJ
eurjchem-828	157	26	oils	oil	NOUN
eurjchem-828	157	27	.	.	PUNCT
eurjchem-828	158	1	conditions	condition	NOUN
eurjchem-828	158	2	of	of	ADP
eurjchem-828	158	3	experiments	experiment	NOUN
eurjchem-828	158	4	are	be	AUX
eurjchem-828	158	5	summarized	summarize	VERB
eurjchem-828	158	6	in	in	ADP
eurjchem-828	158	7	table	table	NOUN
eurjchem-828	158	8	6	6	NUM
eurjchem-828	158	9	.	.	PUNCT
eurjchem-828	158	10	table	table	NOUN
eurjchem-828	158	11	5	5	NUM
eurjchem-828	158	12	.	.	PUNCT
eurjchem-828	159	1	structure	structure	NOUN
eurjchem-828	159	2	of	of	ADP
eurjchem-828	159	3	synthesized	synthesize	VERB
eurjchem-828	159	4	compound	compound	NOUN
eurjchem-828	159	5	12	12	NUM
eurjchem-828	159	6	.	.	PUNCT
eurjchem-828	160	1	compound	compound	NOUN
eurjchem-828	160	2	n	n	NOUN
eurjchem-828	160	3	x	x	SYM
eurjchem-828	160	4	r	r	NOUN
eurjchem-828	160	5	r1	r1	NOUN
eurjchem-828	160	6	12a	12a	NOUN
eurjchem-828	160	7	2	2	NUM
eurjchem-828	160	8	o	o	NOUN
eurjchem-828	160	9	h	h	NOUN
eurjchem-828	160	10	c2h5	c2h5	ADP
eurjchem-828	160	11	12b	12b	X
eurjchem-828	160	12	c6h5	c6h5	PROPN
eurjchem-828	160	13	i‐c3h7	i‐c3h7	NOUN
eurjchem-828	160	14	12c	12c	NOUN
eurjchem-828	160	15	c6h4cl	c6h4cl	PROPN
eurjchem-828	160	16	i‐c3h7	i‐c3h7	NOUN
eurjchem-828	160	17	12d	12d	NOUN
eurjchem-828	160	18	2	2	NUM
eurjchem-828	160	19	s	s	PROPN
eurjchem-828	160	20	c6h5	c6h5	PROPN
eurjchem-828	160	21	ch3	ch3	PROPN
eurjchem-828	160	22	12e	12e	PROPN
eurjchem-828	160	23	c6h5	c6h5	PROPN
eurjchem-828	160	24	i‐c3h7	i‐c3h7	NOUN
eurjchem-828	160	25	12f	12f	NUM
eurjchem-828	160	26	3	3	NUM
eurjchem-828	160	27	o	o	NOUN
eurjchem-828	160	28	c6h5	c6h5	PROPN
eurjchem-828	160	29	ch3	ch3	PROPN
eurjchem-828	160	30	table	table	NOUN
eurjchem-828	160	31	6	6	NUM
eurjchem-828	160	32	.	.	PUNCT
eurjchem-828	161	1	conditions	condition	NOUN
eurjchem-828	161	2	in	in	ADP
eurjchem-828	161	3	reactions	reaction	NOUN
eurjchem-828	161	4	of	of	ADP
eurjchem-828	161	5	carbamates	carbamate	NOUN
eurjchem-828	161	6	with	with	ADP
eurjchem-828	161	7	methylchlorformiate	methylchlorformiate	NOUN
eurjchem-828	161	8	.	.	PUNCT
eurjchem-828	162	1	product/	product/	NUM
eurjchem-828	162	2	reactants	reactant	VERB
eurjchem-828	162	3	carbamate	carbamate	PROPN
eurjchem-828	162	4	type	type	NOUN
eurjchem-828	162	5	carbamate	carbamate	NOUN
eurjchem-828	162	6	amount	amount	NOUN
eurjchem-828	162	7	,	,	PUNCT
eurjchem-828	162	8	mole	mole	NOUN
eurjchem-828	162	9	mcf	mcf	NOUN
eurjchem-828	162	10	,	,	PUNCT
eurjchem-828	162	11	ml	ml	ADP
eurjchem-828	162	12	reaction	reaction	NOUN
eurjchem-828	162	13	time	time	NOUN
eurjchem-828	162	14	,	,	PUNCT
eurjchem-828	162	15	h	h	NOUN
eurjchem-828	162	16	yield	yield	NOUN
eurjchem-828	162	17	,	,	PUNCT
eurjchem-828	162	18	%	%	NOUN
eurjchem-828	162	19	12a	12a	NOUN
eurjchem-828	162	20	10a	10a	NOUN
eurjchem-828	162	21	0.05	0.05	NUM
eurjchem-828	162	22	40	40	NUM
eurjchem-828	162	23	6	6	NUM
eurjchem-828	162	24	79	79	NUM
eurjchem-828	162	25	12b	12b	NOUN
eurjchem-828	162	26	10d	10d	NUM
eurjchem-828	162	27	0.04	0.04	NUM
eurjchem-828	162	28	30	30	NUM
eurjchem-828	162	29	4	4	NUM
eurjchem-828	162	30	83	83	NUM
eurjchem-828	162	31	12c	12c	NOUN
eurjchem-828	162	32	10e	10e	NOUN
eurjchem-828	162	33	0.04	0.04	NUM
eurjchem-828	162	34	30	30	NUM
eurjchem-828	162	35	4	4	NUM
eurjchem-828	162	36	79	79	NUM
eurjchem-828	162	37	12d	12d	NUM
eurjchem-828	162	38	10	10	NUM
eurjchem-828	162	39	g	g	NOUN
eurjchem-828	162	40	0.01	0.01	NUM
eurjchem-828	162	41	30	30	NUM
eurjchem-828	162	42	11	11	NUM
eurjchem-828	162	43	80	80	NUM
eurjchem-828	162	44	12e	12e	NOUN
eurjchem-828	162	45	10h	10h	NUM
eurjchem-828	162	46	0.01	0.01	NUM
eurjchem-828	162	47	30	30	NUM
eurjchem-828	162	48	11	11	NUM
eurjchem-828	162	49	74	74	NUM
eurjchem-828	162	50	12f	12f	NOUN
eurjchem-828	162	51	10k	10k	NOUN
eurjchem-828	162	52	0.03	0.03	NUM
eurjchem-828	162	53	25	25	NUM
eurjchem-828	162	54	8	8	NUM
eurjchem-828	162	55	67	67	NUM
eurjchem-828	162	56	ethyl	ethyl	NOUN
eurjchem-828	162	57	(	(	PUNCT
eurjchem-828	162	58	2‐chloroethoxy)(methoxy)phosphorylcarbamate	2‐chloroethoxy)(methoxy)phosphorylcarbamate	NOUN
eurjchem-828	162	59	(	(	PUNCT
eurjchem-828	162	60	12a	12a	NUM
eurjchem-828	162	61	):	):	PUNCT
eurjchem-828	162	62	color	color	NOUN
eurjchem-828	162	63	:	:	PUNCT
eurjchem-828	162	64	white	white	ADJ
eurjchem-828	162	65	.	.	PUNCT
eurjchem-828	163	1	m.p	m.p	PROPN
eurjchem-828	163	2	.	.	PROPN
eurjchem-828	163	3	:	:	PUNCT
eurjchem-828	164	1	155‐156	155‐156	NUM
eurjchem-828	164	2	oc	oc	PROPN
eurjchem-828	164	3	.	.	PUNCT
eurjchem-828	164	4	ir	ir	PROPN
eurjchem-828	164	5	(	(	PUNCT
eurjchem-828	164	6	kbr	kbr	PROPN
eurjchem-828	164	7	,	,	PUNCT
eurjchem-828	164	8			PROPN
eurjchem-828	164	9	,	,	PUNCT
eurjchem-828	164	10	cm‐1	cm‐1	PROPN
eurjchem-828	164	11	):	):	PUNCT
eurjchem-828	164	12	1730	1730	NUM
eurjchem-828	164	13	,	,	PUNCT
eurjchem-828	164	14	1780	1780	NUM
eurjchem-828	164	15	(	(	PUNCT
eurjchem-828	164	16	c	c	NOUN
eurjchem-828	164	17	=	=	NOUN
eurjchem-828	164	18	o	o	NOUN
eurjchem-828	164	19	)	)	PUNCT
eurjchem-828	164	20	,	,	PUNCT
eurjchem-828	164	21	1010	1010	NUM
eurjchem-828	164	22	(	(	PUNCT
eurjchem-828	164	23	p‐o‐c	p‐o‐c	PROPN
eurjchem-828	164	24	)	)	PUNCT
eurjchem-828	164	25	,	,	PUNCT
eurjchem-828	164	26	1270	1270	NUM
eurjchem-828	164	27	(	(	PUNCT
eurjchem-828	164	28	p	p	NOUN
eurjchem-828	164	29	=	=	NOUN
eurjchem-828	164	30	o	o	NOUN
eurjchem-828	164	31	)	)	PUNCT
eurjchem-828	164	32	.	.	PUNCT
eurjchem-828	165	1	isopropyl	isopropyl	NOUN
eurjchem-828	165	2	(	(	PUNCT
eurjchem-828	165	3	2‐chloroethoxy)(methoxy)phosphoryl(phenyl	2‐chloroethoxy)(methoxy)phosphoryl(phenyl	NUM
eurjchem-828	165	4	)	)	PUNCT
eurjchem-828	165	5	carbamate	carbamate	NOUN
eurjchem-828	165	6	(	(	PUNCT
eurjchem-828	165	7	12b	12b	X
eurjchem-828	165	8	):	):	PUNCT
eurjchem-828	165	9	color	color	NOUN
eurjchem-828	165	10	:	:	PUNCT
eurjchem-828	165	11	white	white	ADJ
eurjchem-828	165	12	.	.	PUNCT
eurjchem-828	166	1	m.p	m.p	PROPN
eurjchem-828	166	2	.	.	PROPN
eurjchem-828	166	3	:	:	PUNCT
eurjchem-828	167	1	109	109	NUM
eurjchem-828	167	2	oc	oc	NOUN
eurjchem-828	167	3	.	.	PUNCT
eurjchem-828	167	4	ir	ir	PROPN
eurjchem-828	167	5	(	(	PUNCT
eurjchem-828	167	6	kbr	kbr	PROPN
eurjchem-828	167	7	,	,	PUNCT
eurjchem-828	167	8			PROPN
eurjchem-828	167	9	,	,	PUNCT
eurjchem-828	167	10	cm‐1	cm‐1	PROPN
eurjchem-828	167	11	):	):	PUNCT
eurjchem-828	167	12	1600	1600	NUM
eurjchem-828	167	13	,	,	PUNCT
eurjchem-828	167	14	1520	1520	NUM
eurjchem-828	167	15	,	,	PUNCT
eurjchem-828	167	16	1440	1440	NUM
eurjchem-828	167	17	(	(	PUNCT
eurjchem-828	167	18	c6h5	c6h5	NOUN
eurjchem-828	167	19	)	)	PUNCT
eurjchem-828	167	20	,	,	PUNCT
eurjchem-828	167	21	1720	1720	NUM
eurjchem-828	167	22	,	,	PUNCT
eurjchem-828	167	23	1732	1732	NUM
eurjchem-828	167	24	(	(	PUNCT
eurjchem-828	167	25	c	c	NOUN
eurjchem-828	167	26	=	=	NOUN
eurjchem-828	167	27	o	o	NOUN
eurjchem-828	167	28	)	)	PUNCT
eurjchem-828	167	29	,	,	PUNCT
eurjchem-828	167	30	1210	1210	NUM
eurjchem-828	167	31	(	(	PUNCT
eurjchem-828	167	32	c‐o‐c	c‐o‐c	NOUN
eurjchem-828	167	33	)	)	PUNCT
eurjchem-828	167	34	,	,	PUNCT
eurjchem-828	167	35	1025	1025	NUM
eurjchem-828	167	36	,	,	PUNCT
eurjchem-828	167	37	1170	1170	NUM
eurjchem-828	167	38	(	(	PUNCT
eurjchem-828	167	39	p‐o‐c	p‐o‐c	PROPN
eurjchem-828	167	40	)	)	PUNCT
eurjchem-828	167	41	,	,	PUNCT
eurjchem-828	167	42	1275	1275	NUM
eurjchem-828	167	43	(	(	PUNCT
eurjchem-828	167	44	p	p	NOUN
eurjchem-828	167	45	=	=	NOUN
eurjchem-828	167	46	o	o	NOUN
eurjchem-828	167	47	)	)	PUNCT
eurjchem-828	167	48	.	.	PUNCT
eurjchem-828	168	1	ms	ms	NOUN
eurjchem-828	168	2	(	(	PUNCT
eurjchem-828	168	3	ei	ei	PROPN
eurjchem-828	168	4	,	,	PUNCT
eurjchem-828	168	5	m	m	PROPN
eurjchem-828	168	6	/	/	SYM
eurjchem-828	168	7	z	z	PROPN
eurjchem-828	168	8	(	(	PUNCT
eurjchem-828	168	9	%	%	NOUN
eurjchem-828	168	10	)	)	PUNCT
eurjchem-828	168	11	):	):	PUNCT
eurjchem-828	168	12	363	363	NUM
eurjchem-828	168	13	(	(	PUNCT
eurjchem-828	168	14	m+	m+	NUM
eurjchem-828	168	15	,	,	PUNCT
eurjchem-828	168	16	5.72	5.72	NUM
eurjchem-828	168	17	)	)	PUNCT
eurjchem-828	168	18	,	,	PUNCT
eurjchem-828	168	19	328	328	NUM
eurjchem-828	168	20	(	(	PUNCT
eurjchem-828	168	21	(	(	PUNCT
eurjchem-828	168	22	m‐cl)+	m‐cl)+	PROPN
eurjchem-828	168	23	,	,	PUNCT
eurjchem-828	168	24	1.34	1.34	NUM
eurjchem-828	168	25	)	)	PUNCT
eurjchem-828	168	26	.	.	PUNCT
eurjchem-828	169	1	isopropyl	isopropyl	NOUN
eurjchem-828	169	2	(	(	PUNCT
eurjchem-828	169	3	2‐chloroethoxy)(methoxy)phosphoryl(2‐chloro	2‐chloroethoxy)(methoxy)phosphoryl(2‐chloro	NUM
eurjchem-828	169	4	phenyl)carbamate	phenyl)carbamate	NOUN
eurjchem-828	169	5	(	(	PUNCT
eurjchem-828	169	6	12c	12c	NUM
eurjchem-828	169	7	):	):	PUNCT
eurjchem-828	169	8	color	color	NOUN
eurjchem-828	169	9	:	:	PUNCT
eurjchem-828	169	10	viscosous	viscosous	ADJ
eurjchem-828	169	11	oil	oil	NOUN
eurjchem-828	169	12	.	.	PUNCT
eurjchem-828	170	1	ir	ir	PROPN
eurjchem-828	170	2	(	(	PUNCT
eurjchem-828	170	3	kbr	kbr	PROPN
eurjchem-828	170	4	,	,	PUNCT
eurjchem-828	170	5			PROPN
eurjchem-828	170	6	,	,	PUNCT
eurjchem-828	170	7	cm‐1	cm‐1	PROPN
eurjchem-828	170	8	):	):	PUNCT
eurjchem-828	170	9	1600	1600	NUM
eurjchem-828	170	10	,	,	PUNCT
eurjchem-828	170	11	1510	1510	NUM
eurjchem-828	170	12	,	,	PUNCT
eurjchem-828	170	13	1440	1440	NUM
eurjchem-828	170	14	(	(	PUNCT
eurjchem-828	170	15	c6h5	c6h5	NOUN
eurjchem-828	170	16	)	)	PUNCT
eurjchem-828	170	17	,	,	PUNCT
eurjchem-828	170	18	1717	1717	NUM
eurjchem-828	170	19	,	,	PUNCT
eurjchem-828	170	20	1740	1740	NUM
eurjchem-828	170	21	(	(	PUNCT
eurjchem-828	170	22	c	c	NOUN
eurjchem-828	170	23	=	=	NOUN
eurjchem-828	170	24	o	o	NOUN
eurjchem-828	170	25	)	)	PUNCT
eurjchem-828	170	26	,	,	PUNCT
eurjchem-828	170	27	1035	1035	NUM
eurjchem-828	170	28	(	(	PUNCT
eurjchem-828	170	29	p‐o‐c	p‐o‐c	NOUN
eurjchem-828	170	30	)	)	PUNCT
eurjchem-828	170	31	,	,	PUNCT
eurjchem-828	170	32	1270	1270	NUM
eurjchem-828	170	33	(	(	PUNCT
eurjchem-828	170	34	p	p	NOUN
eurjchem-828	170	35	=	=	NOUN
eurjchem-828	170	36	o	o	NOUN
eurjchem-828	170	37	)	)	PUNCT
eurjchem-828	170	38	.	.	PUNCT
eurjchem-828	171	1	ms	ms	NOUN
eurjchem-828	171	2	(	(	PUNCT
eurjchem-828	171	3	ei	ei	PROPN
eurjchem-828	171	4	,	,	PUNCT
eurjchem-828	171	5	m	m	PROPN
eurjchem-828	171	6	/	/	SYM
eurjchem-828	171	7	z	z	PROPN
eurjchem-828	171	8	(	(	PUNCT
eurjchem-828	171	9	%	%	NOUN
eurjchem-828	171	10	)	)	PUNCT
eurjchem-828	171	11	):	):	PUNCT
eurjchem-828	171	12	397	397	NUM
eurjchem-828	171	13	(	(	PUNCT
eurjchem-828	171	14	m+	m+	NUM
eurjchem-828	171	15	,	,	PUNCT
eurjchem-828	171	16	1.24	1.24	NUM
eurjchem-828	171	17	%	%	NOUN
eurjchem-828	171	18	)	)	PUNCT
eurjchem-828	171	19	.	.	PUNCT
eurjchem-828	171	20	o‐methyl	o‐methyl	PUNCT
eurjchem-828	172	1	(	(	PUNCT
eurjchem-828	172	2	2‐chloroethoxy)(methoxy)phosphoryl(phenyl	2‐chloroethoxy)(methoxy)phosphoryl(phenyl	NUM
eurjchem-828	172	3	)	)	PUNCT
eurjchem-828	172	4	carbamothioate	carbamothioate	NOUN
eurjchem-828	172	5	(	(	PUNCT
eurjchem-828	172	6	12d	12d	NUM
eurjchem-828	172	7	):	):	PUNCT
eurjchem-828	172	8	b.p	b.p	PROPN
eurjchem-828	172	9	:	:	PUNCT
eurjchem-828	172	10	125	125	NUM
eurjchem-828	172	11	oc/0.2	oc/0.2	NOUN
eurjchem-828	172	12	mm	mm	NUM
eurjchem-828	172	13	hg	hg	NOUN
eurjchem-828	172	14	.	.	PUNCT
eurjchem-828	173	1	nd20	nd20	PROPN
eurjchem-828	173	2	=	=	PROPN
eurjchem-828	173	3	1.5510	1.5510	NUM
eurjchem-828	173	4	.	.	PUNCT
eurjchem-828	174	1	ir	ir	PROPN
eurjchem-828	174	2	(	(	PUNCT
eurjchem-828	174	3	kbr	kbr	PROPN
eurjchem-828	174	4	,	,	PUNCT
eurjchem-828	174	5			PROPN
eurjchem-828	174	6	,	,	PUNCT
eurjchem-828	174	7	cm‐1	cm‐1	PROPN
eurjchem-828	174	8	):	):	PUNCT
eurjchem-828	174	9	1590	1590	NUM
eurjchem-828	174	10	,	,	PUNCT
eurjchem-828	174	11	1530	1530	NUM
eurjchem-828	174	12	,	,	PUNCT
eurjchem-828	174	13	1440	1440	NUM
eurjchem-828	174	14	(	(	PUNCT
eurjchem-828	174	15	c6h5	c6h5	NOUN
eurjchem-828	174	16	)	)	PUNCT
eurjchem-828	174	17	,	,	PUNCT
eurjchem-828	174	18	1750	1750	NUM
eurjchem-828	174	19	(	(	PUNCT
eurjchem-828	174	20	c	c	NOUN
eurjchem-828	174	21	=	=	NOUN
eurjchem-828	174	22	o	o	NOUN
eurjchem-828	174	23	)	)	PUNCT
eurjchem-828	174	24	,	,	PUNCT
eurjchem-828	174	25	1350	1350	NUM
eurjchem-828	174	26	(	(	PUNCT
eurjchem-828	174	27	c	c	NOUN
eurjchem-828	174	28	=	=	SYM
eurjchem-828	174	29	s	s	NOUN
eurjchem-828	174	30	)	)	PUNCT
eurjchem-828	174	31	,	,	PUNCT
eurjchem-828	174	32	1210	1210	NUM
eurjchem-828	174	33	(	(	PUNCT
eurjchem-828	174	34	c‐o‐c	c‐o‐c	NOUN
eurjchem-828	174	35	)	)	PUNCT
eurjchem-828	174	36	,	,	PUNCT
eurjchem-828	174	37	1000	1000	NUM
eurjchem-828	174	38	(	(	PUNCT
eurjchem-828	174	39	p‐o‐c	p‐o‐c	PROPN
eurjchem-828	174	40	)	)	PUNCT
eurjchem-828	174	41	,	,	PUNCT
eurjchem-828	174	42	1300	1300	NUM
eurjchem-828	174	43	(	(	PUNCT
eurjchem-828	174	44	p	p	NOUN
eurjchem-828	174	45	=	=	NOUN
eurjchem-828	174	46	o	o	NOUN
eurjchem-828	174	47	)	)	PUNCT
eurjchem-828	174	48	.	.	PUNCT
eurjchem-828	174	49	o‐isopropyl	o‐isopropyl	PUNCT
eurjchem-828	175	1	(	(	PUNCT
eurjchem-828	175	2	2‐chloroethoxy)(methoxy)phosphoryl(phenyl	2‐chloroethoxy)(methoxy)phosphoryl(phenyl	NOUN
eurjchem-828	175	3	)	)	PUNCT
eurjchem-828	175	4	carbamothioate	carbamothioate	NOUN
eurjchem-828	175	5	(	(	PUNCT
eurjchem-828	175	6	12e	12e	NUM
eurjchem-828	175	7	):	):	PUNCT
eurjchem-828	175	8	b.p	b.p	PROPN
eurjchem-828	175	9	.	.	PROPN
eurjchem-828	175	10	:	:	PUNCT
eurjchem-828	176	1	120‐122	120‐122	NUM
eurjchem-828	176	2	oc/0.2	oc/0.2	NOUN
eurjchem-828	176	3	mm	mm	NUM
eurjchem-828	176	4	hg	hg	NOUN
eurjchem-828	176	5	,	,	PUNCT
eurjchem-828	176	6	after	after	ADP
eurjchem-828	176	7	that	that	DET
eurjchem-828	176	8	340	340	NUM
eurjchem-828	176	9	murzin	murzin	NOUN
eurjchem-828	176	10	and	and	CCONJ
eurjchem-828	176	11	kolesova	kolesova	PROPN
eurjchem-828	176	12	/	/	SYM
eurjchem-828	176	13	european	european	PROPN
eurjchem-828	176	14	journal	journal	PROPN
eurjchem-828	176	15	of	of	ADP
eurjchem-828	176	16	chemistry	chemistry	NOUN
eurjchem-828	176	17	4	4	NUM
eurjchem-828	176	18	(	(	PUNCT
eurjchem-828	176	19	4	4	NUM
eurjchem-828	176	20	)	)	PUNCT
eurjchem-828	176	21	(	(	PUNCT
eurjchem-828	176	22	2013	2013	NUM
eurjchem-828	176	23	)	)	PUNCT
eurjchem-828	176	24	336‐342	336‐342	NUM
eurjchem-828	177	1	the	the	DET
eurjchem-828	177	2	product	product	NOUN
eurjchem-828	177	3	crystallized	crystallize	VERB
eurjchem-828	177	4	.	.	PUNCT
eurjchem-828	178	1	color	color	NOUN
eurjchem-828	178	2	:	:	PUNCT
eurjchem-828	178	3	white	white	ADJ
eurjchem-828	178	4	.	.	PUNCT
eurjchem-828	179	1	m.p	m.p	PROPN
eurjchem-828	179	2	.	.	PROPN
eurjchem-828	179	3	:	:	PUNCT
eurjchem-828	180	1	125	125	NUM
eurjchem-828	180	2	oc	oc	NOUN
eurjchem-828	180	3	.	.	PUNCT
eurjchem-828	180	4	ir	ir	PROPN
eurjchem-828	180	5	(	(	PUNCT
eurjchem-828	180	6	kbr	kbr	PROPN
eurjchem-828	180	7	,	,	PUNCT
eurjchem-828	180	8			PROPN
eurjchem-828	180	9	,	,	PUNCT
eurjchem-828	180	10	cm‐1	cm‐1	PROPN
eurjchem-828	180	11	):	):	PUNCT
eurjchem-828	180	12	1590	1590	NUM
eurjchem-828	180	13	,	,	PUNCT
eurjchem-828	180	14	1530	1530	NUM
eurjchem-828	180	15	,	,	PUNCT
eurjchem-828	180	16	1440	1440	NUM
eurjchem-828	180	17	(	(	PUNCT
eurjchem-828	180	18	c6h5	c6h5	NOUN
eurjchem-828	180	19	)	)	PUNCT
eurjchem-828	180	20	,	,	PUNCT
eurjchem-828	180	21	1730	1730	NUM
eurjchem-828	180	22	(	(	PUNCT
eurjchem-828	180	23	c	c	NOUN
eurjchem-828	180	24	=	=	NOUN
eurjchem-828	180	25	o	o	NOUN
eurjchem-828	180	26	)	)	PUNCT
eurjchem-828	180	27	,	,	PUNCT
eurjchem-828	180	28	1390	1390	NUM
eurjchem-828	180	29	(	(	PUNCT
eurjchem-828	180	30	c	c	NOUN
eurjchem-828	180	31	=	=	SYM
eurjchem-828	180	32	s	s	NOUN
eurjchem-828	180	33	)	)	PUNCT
eurjchem-828	180	34	,	,	PUNCT
eurjchem-828	180	35	1230	1230	NUM
eurjchem-828	180	36	(	(	PUNCT
eurjchem-828	180	37	c‐o‐c	c‐o‐c	NOUN
eurjchem-828	180	38	)	)	PUNCT
eurjchem-828	180	39	,	,	PUNCT
eurjchem-828	180	40	1000	1000	NUM
eurjchem-828	180	41	(	(	PUNCT
eurjchem-828	180	42	p‐o‐c	p‐o‐c	PROPN
eurjchem-828	180	43	)	)	PUNCT
eurjchem-828	180	44	,	,	PUNCT
eurjchem-828	180	45	1300	1300	NUM
eurjchem-828	180	46	(	(	PUNCT
eurjchem-828	180	47	p	p	NOUN
eurjchem-828	180	48	=	=	NOUN
eurjchem-828	180	49	o	o	NOUN
eurjchem-828	180	50	)	)	PUNCT
eurjchem-828	180	51	.	.	PUNCT
eurjchem-828	181	1	ethyl	ethyl	PROPN
eurjchem-828	181	2	(	(	PUNCT
eurjchem-828	181	3	3‐chloropropoxy)(methoxy)phosphoryl(phenyl	3‐chloropropoxy)(methoxy)phosphoryl(phenyl	NUM
eurjchem-828	181	4	)	)	PUNCT
eurjchem-828	181	5	carbamate	carbamate	NOUN
eurjchem-828	181	6	(	(	PUNCT
eurjchem-828	181	7	12f	12f	NUM
eurjchem-828	181	8	):	):	PUNCT
eurjchem-828	181	9	b.p	b.p	PROPN
eurjchem-828	181	10	:	:	PUNCT
eurjchem-828	181	11	96	96	NUM
eurjchem-828	181	12	oc/0.2	oc/0.2	NOUN
eurjchem-828	181	13	mm	mm	NUM
eurjchem-828	181	14	hg	hg	PROPN
eurjchem-828	181	15	.	.	PUNCT
eurjchem-828	182	1	ir	ir	PROPN
eurjchem-828	182	2	(	(	PUNCT
eurjchem-828	182	3	kbr	kbr	PROPN
eurjchem-828	182	4	,	,	PUNCT
eurjchem-828	182	5			PROPN
eurjchem-828	182	6	,	,	PUNCT
eurjchem-828	182	7	cm‐1	cm‐1	PROPN
eurjchem-828	182	8	):	):	PUNCT
eurjchem-828	182	9	1600	1600	NUM
eurjchem-828	182	10	,	,	PUNCT
eurjchem-828	182	11	1520	1520	NUM
eurjchem-828	182	12	,	,	PUNCT
eurjchem-828	182	13	1450	1450	NUM
eurjchem-828	182	14	(	(	PUNCT
eurjchem-828	182	15	c6h5	c6h5	NOUN
eurjchem-828	182	16	)	)	PUNCT
eurjchem-828	182	17	,	,	PUNCT
eurjchem-828	182	18	1750	1750	NUM
eurjchem-828	182	19	,	,	PUNCT
eurjchem-828	182	20	1705	1705	NUM
eurjchem-828	182	21	(	(	PUNCT
eurjchem-828	182	22	c	c	NOUN
eurjchem-828	182	23	=	=	NOUN
eurjchem-828	182	24	o	o	NOUN
eurjchem-828	182	25	)	)	PUNCT
eurjchem-828	182	26	,	,	PUNCT
eurjchem-828	182	27	1200	1200	NUM
eurjchem-828	182	28	(	(	PUNCT
eurjchem-828	182	29	c‐o‐c	c‐o‐c	NOUN
eurjchem-828	182	30	)	)	PUNCT
eurjchem-828	182	31	,	,	PUNCT
eurjchem-828	182	32	1000	1000	NUM
eurjchem-828	182	33	(	(	PUNCT
eurjchem-828	182	34	p‐o‐	p‐o‐	NOUN
eurjchem-828	182	35	c	c	NOUN
eurjchem-828	182	36	)	)	PUNCT
eurjchem-828	182	37	,	,	PUNCT
eurjchem-828	182	38	1300	1300	NUM
eurjchem-828	182	39	(	(	PUNCT
eurjchem-828	182	40	p	p	NOUN
eurjchem-828	182	41	=	=	NOUN
eurjchem-828	182	42	o	o	NOUN
eurjchem-828	182	43	)	)	PUNCT
eurjchem-828	182	44	.	.	PUNCT
eurjchem-828	183	1	31p	31p	NUM
eurjchem-828	183	2	nmr	nmr	NOUN
eurjchem-828	183	3	(	(	PUNCT
eurjchem-828	183	4	36.43	36.43	NUM
eurjchem-828	183	5	mhz	mhz	NOUN
eurjchem-828	183	6	,	,	PUNCT
eurjchem-828	183	7	85%h3po4	85%h3po4	PROPN
eurjchem-828	183	8	,	,	PUNCT
eurjchem-828	183	9	δ	δ	PROPN
eurjchem-828	183	10	,	,	PUNCT
eurjchem-828	183	11	ppm	ppm	NOUN
eurjchem-828	183	12	):	):	PUNCT
eurjchem-828	183	13	‐13.9	‐13.9	NOUN
eurjchem-828	183	14	.	.	PUNCT
eurjchem-828	184	1	ms	ms	NOUN
eurjchem-828	184	2	(	(	PUNCT
eurjchem-828	184	3	ei	ei	PROPN
eurjchem-828	184	4	,	,	PUNCT
eurjchem-828	184	5	m	m	PROPN
eurjchem-828	184	6	/	/	SYM
eurjchem-828	184	7	z	z	PROPN
eurjchem-828	184	8	(	(	PUNCT
eurjchem-828	184	9	%	%	NOUN
eurjchem-828	184	10	)	)	PUNCT
eurjchem-828	184	11	):	):	PUNCT
eurjchem-828	184	12	290	290	NUM
eurjchem-828	184	13	(	(	PUNCT
eurjchem-828	184	14	m‐cooch3)+	m‐cooch3)+	NOUN
eurjchem-828	184	15	,	,	PUNCT
eurjchem-828	184	16	5.72	5.72	NUM
eurjchem-828	184	17	)	)	PUNCT
eurjchem-828	184	18	.	.	PUNCT
eurjchem-828	185	1	nd20	nd20	PROPN
eurjchem-828	185	2	=	=	PROPN
eurjchem-828	185	3	1.5510	1.5510	NUM
eurjchem-828	185	4	.	.	PUNCT
eurjchem-828	185	5	2.4	2.4	NUM
eurjchem-828	185	6	.	.	PUNCT
eurjchem-828	186	1	instrumentation	instrumentation	NOUN
eurjchem-828	186	2	mass	mass	PROPN
eurjchem-828	186	3	spectra	spectra	PROPN
eurjchem-828	186	4	were	be	AUX
eurjchem-828	186	5	measured	measure	VERB
eurjchem-828	186	6	with	with	ADP
eurjchem-828	186	7	varian	varian	PROPN
eurjchem-828	186	8	mat	mat	PROPN
eurjchem-828	186	9	ch‐7a	ch‐7a	PROPN
eurjchem-828	186	10	instrument	instrument	NOUN
eurjchem-828	186	11	,	,	PUNCT
eurjchem-828	186	12	while	while	SCONJ
eurjchem-828	186	13	bruker	bruker	X
eurjchem-828	186	14	hx‐90e	hx‐90e	PUNCT
eurjchem-828	186	15	nmr	nmr	NOUN
eurjchem-828	186	16	spectrometer	spectrometer	NOUN
eurjchem-828	186	17	(	(	PUNCT
eurjchem-828	186	18	36.43	36.43	NUM
eurjchem-828	186	19	mhz	mhz	NOUN
eurjchem-828	186	20	)	)	PUNCT
eurjchem-828	186	21	with	with	ADP
eurjchem-828	186	22	85%h3po4	85%h3po4	PROPN
eurjchem-828	186	23	as	as	ADP
eurjchem-828	186	24	an	an	DET
eurjchem-828	186	25	external	external	ADJ
eurjchem-828	186	26	standard	standard	NOUN
eurjchem-828	186	27	was	be	AUX
eurjchem-828	186	28	used	use	VERB
eurjchem-828	186	29	for	for	ADP
eurjchem-828	186	30	31p	31p	NUM
eurjchem-828	186	31	nmr	nmr	NOUN
eurjchem-828	186	32	measurements	measurement	NOUN
eurjchem-828	186	33	.	.	PUNCT
eurjchem-828	187	1	ir	ir	PROPN
eurjchem-828	187	2	spectra	spectra	PROPN
eurjchem-828	187	3	were	be	AUX
eurjchem-828	187	4	measured	measure	VERB
eurjchem-828	187	5	with	with	ADP
eurjchem-828	187	6	ir	ir	PROPN
eurjchem-828	187	7	spectrophotometer	spectrophotometer	NOUN
eurjchem-828	187	8	ur‐20	ur‐20	VERB
eurjchem-828	187	9	either	either	CCONJ
eurjchem-828	187	10	in	in	ADP
eurjchem-828	187	11	ccl4	ccl4	PROPN
eurjchem-828	187	12	or	or	CCONJ
eurjchem-828	187	13	using	use	VERB
eurjchem-828	187	14	kbr	kbr	PROPN
eurjchem-828	187	15	.	.	PUNCT
eurjchem-828	188	1	the	the	DET
eurjchem-828	188	2	'	'	PUNCT
eurjchem-828	188	3	hot‐	hot‐	NOUN
eurjchem-828	188	4	stage	stage	NOUN
eurjchem-828	188	5	'	'	PUNCT
eurjchem-828	188	6	apparatus	apparatus	NOUN
eurjchem-828	188	7	was	be	AUX
eurjchem-828	188	8	used	use	VERB
eurjchem-828	188	9	to	to	PART
eurjchem-828	188	10	measure	measure	VERB
eurjchem-828	188	11	the	the	DET
eurjchem-828	188	12	melting	melting	NOUN
eurjchem-828	188	13	point	point	NOUN
eurjchem-828	188	14	with	with	ADP
eurjchem-828	188	15	a	a	DET
eurjchem-828	188	16	possibility	possibility	NOUN
eurjchem-828	188	17	to	to	PART
eurjchem-828	188	18	look	look	VERB
eurjchem-828	188	19	at	at	ADP
eurjchem-828	188	20	the	the	DET
eurjchem-828	188	21	sample	sample	NOUN
eurjchem-828	188	22	through	through	ADP
eurjchem-828	188	23	a	a	DET
eurjchem-828	188	24	microscope	microscope	NOUN
eurjchem-828	188	25	while	while	SCONJ
eurjchem-828	188	26	its	its	PRON
eurjchem-828	188	27	temperature	temperature	NOUN
eurjchem-828	188	28	is	be	AUX
eurjchem-828	188	29	increased	increase	VERB
eurjchem-828	188	30	.	.	PUNCT
eurjchem-828	189	1	3	3	X
eurjchem-828	189	2	.	.	X
eurjchem-828	189	3	results	result	NOUN
eurjchem-828	189	4	and	and	CCONJ
eurjchem-828	189	5	discussion	discussion	NOUN
eurjchem-828	189	6	3.1	3.1	NUM
eurjchem-828	189	7	.	.	PUNCT
eurjchem-828	190	1	synthesis	synthesis	NOUN
eurjchem-828	190	2	and	and	CCONJ
eurjchem-828	190	3	characterization	characterization	NOUN
eurjchem-828	190	4	of	of	ADP
eurjchem-828	190	5	phosphorylated	phosphorylate	VERB
eurjchem-828	190	6	carbamates	carbamate	NOUN
eurjchem-828	190	7	in	in	ADP
eurjchem-828	190	8	ir	ir	PROPN
eurjchem-828	190	9	spectra	spectra	NOUN
eurjchem-828	190	10	of	of	ADP
eurjchem-828	190	11	components	component	NOUN
eurjchem-828	190	12	10a‐10e	10a‐10e	NUM
eurjchem-828	190	13	and	and	CCONJ
eurjchem-828	190	14	10j‐10l	10j‐10l	NUM
eurjchem-828	190	15	there	there	PRON
eurjchem-828	190	16	were	be	VERB
eurjchem-828	190	17	characteristic	characteristic	ADJ
eurjchem-828	190	18	peaks	peak	NOUN
eurjchem-828	190	19	of	of	ADP
eurjchem-828	190	20	carbonyl	carbonyl	NOUN
eurjchem-828	190	21	group	group	NOUN
eurjchem-828	190	22	in	in	ADP
eurjchem-828	190	23	the	the	DET
eurjchem-828	190	24	range	range	NOUN
eurjchem-828	190	25	1700‐	1700‐	NUM
eurjchem-828	190	26	1720	1720	NUM
eurjchem-828	190	27	cm‐1	cm‐1	NOUN
eurjchem-828	190	28	for	for	ADP
eurjchem-828	190	29	10a‐10e	10a‐10e	NUM
eurjchem-828	190	30	(	(	PUNCT
eurjchem-828	190	31	1715	1715	NUM
eurjchem-828	190	32	cm‐1	cm‐1	NOUN
eurjchem-828	190	33	as	as	SCONJ
eurjchem-828	190	34	mentioned	mention	VERB
eurjchem-828	190	35	in	in	ADP
eurjchem-828	190	36	[	[	X
eurjchem-828	190	37	13	13	NUM
eurjchem-828	190	38	]	]	PUNCT
eurjchem-828	190	39	)	)	PUNCT
eurjchem-828	190	40	and	and	CCONJ
eurjchem-828	190	41	1750‐1790	1750‐1790	NUM
eurjchem-828	190	42	for	for	ADP
eurjchem-828	190	43	10j‐10l	10j‐10l	NUM
eurjchem-828	190	44	.	.	PUNCT
eurjchem-828	191	1	presence	presence	NOUN
eurjchem-828	191	2	of	of	ADP
eurjchem-828	191	3	the	the	DET
eurjchem-828	191	4	c	c	PROPN
eurjchem-828	191	5	=	=	SYM
eurjchem-828	191	6	s	s	PART
eurjchem-828	191	7	group	group	NOUN
eurjchem-828	191	8	resulted	result	VERB
eurjchem-828	191	9	in	in	ADP
eurjchem-828	191	10	peaks	peak	NOUN
eurjchem-828	191	11	at	at	ADP
eurjchem-828	191	12	1360‐1390	1360‐1390	NUM
eurjchem-828	191	13	cm‐1	cm‐1	NOUN
eurjchem-828	191	14	.	.	PUNCT
eurjchem-828	192	1	for	for	ADP
eurjchem-828	192	2	the	the	DET
eurjchem-828	192	3	phospholane	phospholane	NOUN
eurjchem-828	192	4	ring	ring	NOUN
eurjchem-828	192	5	the	the	DET
eurjchem-828	192	6	characteristic	characteristic	ADJ
eurjchem-828	192	7	peaks	peak	NOUN
eurjchem-828	192	8	are	be	AUX
eurjchem-828	192	9	in	in	ADP
eurjchem-828	192	10	the	the	DET
eurjchem-828	192	11	region	region	NOUN
eurjchem-828	192	12	of	of	ADP
eurjchem-828	192	13	990‐1100	990‐1100	NUM
eurjchem-828	192	14	cm‐1	cm‐1	NOUN
eurjchem-828	192	15	.	.	PUNCT
eurjchem-828	193	1	the	the	DET
eurjchem-828	193	2	spectra	spectra	NOUN
eurjchem-828	193	3	also	also	ADV
eurjchem-828	193	4	contain	contain	VERB
eurjchem-828	193	5	peaks	peak	NOUN
eurjchem-828	193	6	of	of	ADP
eurjchem-828	193	7	the	the	DET
eurjchem-828	193	8	phenyl	phenyl	NOUN
eurjchem-828	193	9	ring	ring	NOUN
eurjchem-828	193	10	(	(	PUNCT
eurjchem-828	193	11	1450‐1600	1450‐1600	NUM
eurjchem-828	193	12	cm‐1	cm‐1	NOUN
eurjchem-828	193	13	)	)	PUNCT
eurjchem-828	193	14	,	,	PUNCT
eurjchem-828	193	15	while	while	SCONJ
eurjchem-828	193	16	components	component	NOUN
eurjchem-828	193	17	10a	10a	NOUN
eurjchem-828	193	18	and	and	CCONJ
eurjchem-828	193	19	10j	10j	NUM
eurjchem-828	193	20	have	have	VERB
eurjchem-828	193	21	peaks	peak	NOUN
eurjchem-828	193	22	corresponding	correspond	VERB
eurjchem-828	193	23	to	to	ADP
eurjchem-828	193	24	nh	nh	PROPN
eurjchem-828	193	25	vibrations	vibration	NOUN
eurjchem-828	193	26	.	.	PUNCT
eurjchem-828	194	1	31p	31p	NOUN
eurjchem-828	194	2	nmp	nmp	NOUN
eurjchem-828	194	3	confirms	confirm	VERB
eurjchem-828	194	4	formation	formation	NOUN
eurjchem-828	194	5	of	of	ADP
eurjchem-828	194	6	trivalent	trivalent	ADJ
eurjchem-828	194	7	phosphor	phosphor	NOUN
eurjchem-828	194	8	carbamates	carbamate	VERB
eurjchem-828	194	9	derivatives	derivative	NOUN
eurjchem-828	194	10	with	with	ADP
eurjchem-828	194	11	signals	signal	NOUN
eurjchem-828	194	12	at	at	ADP
eurjchem-828	194	13	122	122	NUM
eurjchem-828	194	14	ppm	ppm	NOUN
eurjchem-828	194	15	.	.	PUNCT
eurjchem-828	195	1	mass	mass	ADJ
eurjchem-828	195	2	spectra	spectra	NOUN
eurjchem-828	195	3	of	of	ADP
eurjchem-828	195	4	some	some	DET
eurjchem-828	195	5	substances	substance	NOUN
eurjchem-828	195	6	of	of	ADP
eurjchem-828	195	7	type	type	NOUN
eurjchem-828	195	8	10	10	NUM
eurjchem-828	195	9	contain	contain	VERB
eurjchem-828	195	10	molecular	molecular	ADJ
eurjchem-828	195	11	ions	ion	NOUN
eurjchem-828	195	12	,	,	PUNCT
eurjchem-828	195	13	such	such	ADJ
eurjchem-828	195	14	as	as	ADP
eurjchem-828	195	15	for	for	ADP
eurjchem-828	195	16	example	example	NOUN
eurjchem-828	195	17	component	component	NOUN
eurjchem-828	195	18	10c	10c	NOUN
eurjchem-828	195	19	,	,	PUNCT
eurjchem-828	195	20	where	where	SCONJ
eurjchem-828	195	21	the	the	DET
eurjchem-828	195	22	amount	amount	NOUN
eurjchem-828	195	23	of	of	ADP
eurjchem-828	195	24	molecular	molecular	ADJ
eurjchem-828	195	25	ion	ion	NOUN
eurjchem-828	195	26	is	be	AUX
eurjchem-828	195	27	0.55	0.55	NUM
eurjchem-828	195	28	%	%	NOUN
eurjchem-828	195	29	,	,	PUNCT
eurjchem-828	195	30	which	which	PRON
eurjchem-828	195	31	is	be	AUX
eurjchem-828	195	32	high	high	ADJ
eurjchem-828	195	33	for	for	ADP
eurjchem-828	195	34	phosphor	phosphor	NOUN
eurjchem-828	195	35	containing	contain	VERB
eurjchem-828	195	36	compounds	compound	NOUN
eurjchem-828	195	37	at	at	ADP
eurjchem-828	195	38	rather	rather	ADV
eurjchem-828	195	39	severe	severe	ADJ
eurjchem-828	195	40	conditions	condition	NOUN
eurjchem-828	195	41	(	(	PUNCT
eurjchem-828	195	42	70	70	NUM
eurjchem-828	195	43	ev	ev	NOUN
eurjchem-828	195	44	)	)	PUNCT
eurjchem-828	195	45	,	,	PUNCT
eurjchem-828	195	46	being	be	AUX
eurjchem-828	195	47	a	a	DET
eurjchem-828	195	48	sign	sign	NOUN
eurjchem-828	195	49	of	of	ADP
eurjchem-828	195	50	a	a	DET
eurjchem-828	195	51	strong	strong	ADJ
eurjchem-828	195	52	p‐n	p‐n	NOUN
eurjchem-828	195	53	bond	bond	NOUN
eurjchem-828	195	54	in	in	ADP
eurjchem-828	195	55	phosphorylated	phosphorylate	VERB
eurjchem-828	195	56	carbamates	carbamate	NOUN
eurjchem-828	195	57	.	.	PUNCT
eurjchem-828	196	1	calculations	calculation	NOUN
eurjchem-828	196	2	of	of	ADP
eurjchem-828	196	3	the	the	DET
eurjchem-828	196	4	partial	partial	ADJ
eurjchem-828	196	5	charge	charge	NOUN
eurjchem-828	196	6	of	of	ADP
eurjchem-828	196	7	p	p	NOUN
eurjchem-828	196	8	and	and	CCONJ
eurjchem-828	196	9	n	n	ADV
eurjchem-828	196	10	using	use	VERB
eurjchem-828	196	11	extended	extended	ADJ
eurjchem-828	196	12	huckel	huckel	NOUN
eurjchem-828	196	13	method	method	NOUN
eurjchem-828	196	14	after	after	ADP
eurjchem-828	196	15	structure	structure	NOUN
eurjchem-828	196	16	optimization	optimization	NOUN
eurjchem-828	196	17	with	with	ADP
eurjchem-828	196	18	mm2	mm2	PROPN
eurjchem-828	196	19	(	(	PUNCT
eurjchem-828	196	20	chem	chem	NOUN
eurjchem-828	196	21	3d	3d	NOUN
eurjchem-828	196	22	pro	pro	NOUN
eurjchem-828	196	23	)	)	PUNCT
eurjchem-828	196	24	gave	give	VERB
eurjchem-828	196	25	respectively	respectively	ADV
eurjchem-828	196	26	the	the	DET
eurjchem-828	196	27	values	value	NOUN
eurjchem-828	196	28	0.905374	0.905374	NUM
eurjchem-828	196	29	and	and	CCONJ
eurjchem-828	196	30	0.164095	0.164095	NUM
eurjchem-828	196	31	,	,	PUNCT
eurjchem-828	196	32	while	while	SCONJ
eurjchem-828	196	33	p‐n	p‐n	NOUN
eurjchem-828	196	34	bond	bond	NOUN
eurjchem-828	196	35	length	length	NOUN
eurjchem-828	196	36	is	be	AUX
eurjchem-828	196	37	1.773	1.773	NUM
eurjchem-828	196	38	å	å	NOUN
eurjchem-828	196	39	.	.	PUNCT
eurjchem-828	197	1	the	the	DET
eurjchem-828	197	2	values	value	NOUN
eurjchem-828	197	3	of	of	ADP
eurjchem-828	197	4	ion	ion	NOUN
eurjchem-828	197	5	fragments	fragment	NOUN
eurjchem-828	197	6	in	in	ADP
eurjchem-828	197	7	the	the	DET
eurjchem-828	197	8	mass	mass	ADJ
eurjchem-828	197	9	spectra	spectra	NOUN
eurjchem-828	197	10	of	of	ADP
eurjchem-828	197	11	compound	compound	NOUN
eurjchem-828	197	12	10c	10c	NOUN
eurjchem-828	197	13	are	be	AUX
eurjchem-828	197	14	given	give	VERB
eurjchem-828	197	15	in	in	ADP
eurjchem-828	197	16	table	table	NOUN
eurjchem-828	197	17	7	7	NUM
eurjchem-828	197	18	.	.	PUNCT
eurjchem-828	197	19	table	table	NOUN
eurjchem-828	197	20	7	7	NUM
eurjchem-828	197	21	.	.	PUNCT
eurjchem-828	197	22	mass	mass	ADJ
eurjchem-828	197	23	spectra	spectra	ADJ
eurjchem-828	197	24	fragments	fragment	NOUN
eurjchem-828	197	25	for	for	ADP
eurjchem-828	197	26	10c	10c	NOUN
eurjchem-828	197	27	.	.	PUNCT
eurjchem-828	198	1	m	m	VERB
eurjchem-828	198	2	/	/	SYM
eurjchem-828	198	3	e	e	PROPN
eurjchem-828	198	4	i	i	PROPN
eurjchem-828	198	5	/	/	SYM
eurjchem-828	198	6	imax	imax	PROPN
eurjchem-828	198	7	ions	ion	NOUN
eurjchem-828	198	8	241	241	NUM
eurjchem-828	198	9	0.55	0.55	NUM
eurjchem-828	198	10	m+	m+	NUM
eurjchem-828	198	11	151	151	NUM
eurjchem-828	198	12	100	100	NUM
eurjchem-828	198	13	%	%	NOUN
eurjchem-828	199	1	[	[	X
eurjchem-828	199	2	c6h5ncooch3]+	c6h5ncooch3]+	PROPN
eurjchem-828	199	3	119	119	NUM
eurjchem-828	199	4	37.17	37.17	NUM
eurjchem-828	200	1	[	[	X
eurjchem-828	200	2	c6h5nco]+	c6h5nco]+	ADJ
eurjchem-828	200	3	93	93	NUM
eurjchem-828	200	4	7.15	7.15	NUM
eurjchem-828	201	1	[	[	X
eurjchem-828	201	2	c6h5nh2]+	c6h5nh2]+	NOUN
eurjchem-828	201	3	92	92	NUM
eurjchem-828	201	4	28.37	28.37	NUM
eurjchem-828	201	5	[	[	X
eurjchem-828	201	6	c6h5nh]+	c6h5nh]+	X
eurjchem-828	201	7	91	91	NUM
eurjchem-828	201	8	24.57	24.57	NUM
eurjchem-828	201	9	[	[	X
eurjchem-828	201	10	c6h5n]+	c6h5n]+	PROPN
eurjchem-828	201	11	59	59	NUM
eurjchem-828	201	12	17.85	17.85	NUM
eurjchem-828	202	1	[	[	X
eurjchem-828	202	2	cooch3]+	cooch3]+	NOUN
eurjchem-828	202	3	the	the	DET
eurjchem-828	202	4	stability	stability	NOUN
eurjchem-828	202	5	of	of	ADP
eurjchem-828	202	6	the	the	DET
eurjchem-828	202	7	molecular	molecular	ADJ
eurjchem-828	202	8	ion	ion	NOUN
eurjchem-828	202	9	depends	depend	VERB
eurjchem-828	202	10	on	on	ADP
eurjchem-828	202	11	the	the	DET
eurjchem-828	202	12	number	number	NOUN
eurjchem-828	202	13	of	of	ADP
eurjchem-828	202	14	carbon	carbon	NOUN
eurjchem-828	202	15	atoms	atom	NOUN
eurjchem-828	202	16	in	in	ADP
eurjchem-828	202	17	the	the	DET
eurjchem-828	202	18	chain	chain	NOUN
eurjchem-828	202	19	,	,	PUNCT
eurjchem-828	202	20	since	since	SCONJ
eurjchem-828	202	21	for	for	ADP
eurjchem-828	202	22	component	component	NOUN
eurjchem-828	202	23	10k	10k	NOUN
eurjchem-828	202	24	with	with	ADP
eurjchem-828	202	25	three	three	NUM
eurjchem-828	202	26	carbon	carbon	NOUN
eurjchem-828	202	27	atoms	atom	NOUN
eurjchem-828	202	28	in	in	ADP
eurjchem-828	202	29	the	the	DET
eurjchem-828	202	30	cycle	cycle	NOUN
eurjchem-828	202	31	the	the	DET
eurjchem-828	202	32	relative	relative	ADJ
eurjchem-828	202	33	amount	amount	NOUN
eurjchem-828	202	34	of	of	ADP
eurjchem-828	202	35	an	an	DET
eurjchem-828	202	36	ion	ion	NOUN
eurjchem-828	202	37	with	with	ADP
eurjchem-828	202	38	m	m	PROPN
eurjchem-828	202	39	/	/	SYM
eurjchem-828	202	40	e	e	NOUN
eurjchem-828	202	41	255	255	NUM
eurjchem-828	202	42	is	be	AUX
eurjchem-828	202	43	11.71	11.71	NUM
eurjchem-828	202	44	%	%	NOUN
eurjchem-828	202	45	.	.	PUNCT
eurjchem-828	203	1	the	the	DET
eurjchem-828	203	2	main	main	ADJ
eurjchem-828	203	3	fragmentation	fragmentation	NOUN
eurjchem-828	203	4	for	for	ADP
eurjchem-828	203	5	compound	compound	NOUN
eurjchem-828	203	6	10k	10k	NOUN
eurjchem-828	203	7	path	path	NOUN
eurjchem-828	203	8	is	be	AUX
eurjchem-828	203	9	[	[	X
eurjchem-828	203	10	m+	m+	X
eurjchem-828	203	11	]	]	X
eurjchem-828	203	12	‐>[(ch2)3oop]+	‐>[(ch2)3oop]+	PROPN
eurjchem-828	203	13	(	(	PUNCT
eurjchem-828	203	14	m	m	NOUN
eurjchem-828	203	15	/	/	SYM
eurjchem-828	203	16	e	e	PROPN
eurjchem-828	203	17	105	105	NUM
eurjchem-828	203	18	;	;	PUNCT
eurjchem-828	203	19	88.77	88.77	NUM
eurjchem-828	203	20	%	%	NOUN
eurjchem-828	203	21	)	)	PUNCT
eurjchem-828	204	1	+	+	CCONJ
eurjchem-828	205	1	[	[	X
eurjchem-828	205	2	nh(c6h5	nh(c6h5	ADJ
eurjchem-828	205	3	)	)	PUNCT
eurjchem-828	205	4	cooch3]+	cooch3]+	NOUN
eurjchem-828	205	5	(	(	PUNCT
eurjchem-828	205	6	m	m	NOUN
eurjchem-828	205	7	/	/	SYM
eurjchem-828	205	8	e	e	NOUN
eurjchem-828	205	9	151	151	NUM
eurjchem-828	205	10	;	;	PUNCT
eurjchem-828	205	11	48.08	48.08	NUM
eurjchem-828	205	12	%	%	NOUN
eurjchem-828	205	13	)	)	PUNCT
eurjchem-828	205	14	although	although	SCONJ
eurjchem-828	205	15	in	in	ADP
eurjchem-828	205	16	the	the	DET
eurjchem-828	205	17	spectra	spectra	NOUN
eurjchem-828	205	18	also	also	ADV
eurjchem-828	205	19	ions	ion	VERB
eurjchem-828	205	20	with	with	ADP
eurjchem-828	205	21	the	the	DET
eurjchem-828	205	22	p‐n	p‐n	NOUN
eurjchem-828	205	23	bond	bond	NOUN
eurjchem-828	205	24	are	be	AUX
eurjchem-828	205	25	present	present	ADJ
eurjchem-828	205	26	.	.	PUNCT
eurjchem-828	206	1	the	the	DET
eurjchem-828	206	2	main	main	ADJ
eurjchem-828	206	3	ions	ion	NOUN
eurjchem-828	206	4	in	in	ADP
eurjchem-828	206	5	the	the	DET
eurjchem-828	206	6	spectra	spectra	NOUN
eurjchem-828	206	7	of	of	ADP
eurjchem-828	206	8	compound	compound	ADJ
eurjchem-828	206	9	10k	10k	NOUN
eurjchem-828	206	10	are	be	AUX
eurjchem-828	206	11	given	give	VERB
eurjchem-828	206	12	in	in	ADP
eurjchem-828	206	13	table	table	NOUN
eurjchem-828	206	14	8	8	NUM
eurjchem-828	206	15	.	.	PUNCT
eurjchem-828	207	1	in	in	ADP
eurjchem-828	207	2	case	case	NOUN
eurjchem-828	207	3	of	of	ADP
eurjchem-828	207	4	compound	compound	NOUN
eurjchem-828	207	5	10l	10l	NOUN
eurjchem-828	207	6	it	it	PRON
eurjchem-828	207	7	could	could	AUX
eurjchem-828	207	8	be	be	AUX
eurjchem-828	207	9	expected	expect	VERB
eurjchem-828	207	10	that	that	SCONJ
eurjchem-828	207	11	the	the	DET
eurjchem-828	207	12	molecular	molecular	ADJ
eurjchem-828	207	13	ion	ion	NOUN
eurjchem-828	207	14	is	be	AUX
eurjchem-828	207	15	not	not	PART
eurjchem-828	207	16	present	present	ADJ
eurjchem-828	207	17	,	,	PUNCT
eurjchem-828	207	18	since	since	SCONJ
eurjchem-828	207	19	the	the	DET
eurjchem-828	207	20	isopropyl	isopropyl	NOUN
eurjchem-828	207	21	group	group	NOUN
eurjchem-828	207	22	could	could	AUX
eurjchem-828	207	23	be	be	AUX
eurjchem-828	207	24	easily	easily	ADV
eurjchem-828	207	25	cleaved	cleave	VERB
eurjchem-828	207	26	.	.	PUNCT
eurjchem-828	208	1	on	on	ADP
eurjchem-828	208	2	the	the	DET
eurjchem-828	208	3	other	other	ADJ
eurjchem-828	208	4	hand	hand	NOUN
eurjchem-828	208	5	there	there	PRON
eurjchem-828	208	6	is	be	VERB
eurjchem-828	208	7	an	an	DET
eurjchem-828	208	8	ion	ion	NOUN
eurjchem-828	208	9	with	with	ADP
eurjchem-828	208	10	m	m	PROPN
eurjchem-828	208	11	/	/	SYM
eurjchem-828	208	12	e	e	PROPN
eurjchem-828	208	13	299	299	NUM
eurjchem-828	208	14	,	,	PUNCT
eurjchem-828	208	15	corresponding	correspond	VERB
eurjchem-828	208	16	to	to	PART
eurjchem-828	208	17	compound	compound	VERB
eurjchem-828	208	18	10l	10l	NOUN
eurjchem-828	208	19	with	with	ADP
eurjchem-828	208	20	p	p	X
eurjchem-828	208	21	=	=	NOUN
eurjchem-828	208	22	o.	o.	NOUN
eurjchem-828	208	23	moreover	moreover	ADV
eurjchem-828	208	24	in	in	ADP
eurjchem-828	208	25	mass	mass	ADJ
eurjchem-828	208	26	spectra	spectra	ADJ
eurjchem-828	208	27	ions	ion	NOUN
eurjchem-828	208	28	with	with	ADP
eurjchem-828	208	29	m	m	PROPN
eurjchem-828	208	30	/	/	SYM
eurjchem-828	208	31	e	e	PROPN
eurjchem-828	208	32	105	105	NUM
eurjchem-828	208	33	(	(	PUNCT
eurjchem-828	208	34	see	see	VERB
eurjchem-828	208	35	table	table	NOUN
eurjchem-828	208	36	8)	8)	NUM
eurjchem-828	208	37	are	be	AUX
eurjchem-828	208	38	absent	absent	ADJ
eurjchem-828	208	39	,	,	PUNCT
eurjchem-828	208	40	while	while	SCONJ
eurjchem-828	208	41	there	there	PRON
eurjchem-828	208	42	is	be	VERB
eurjchem-828	208	43	an	an	DET
eurjchem-828	208	44	ion	ion	NOUN
eurjchem-828	208	45	with	with	ADP
eurjchem-828	208	46	m	m	PROPN
eurjchem-828	208	47	/	/	SYM
eurjchem-828	208	48	e	e	ADP
eurjchem-828	208	49	121	121	NUM
eurjchem-828	208	50	(	(	PUNCT
eurjchem-828	208	51	ch2(ch2o)2po	ch2(ch2o)2po	NUM
eurjchem-828	208	52	)	)	PUNCT
eurjchem-828	208	53	albeit	albeit	SCONJ
eurjchem-828	208	54	with	with	ADP
eurjchem-828	208	55	low	low	ADJ
eurjchem-828	208	56	intensity	intensity	NOUN
eurjchem-828	208	57	(	(	PUNCT
eurjchem-828	208	58	5.64	5.64	NUM
eurjchem-828	208	59	%	%	NOUN
eurjchem-828	208	60	)	)	PUNCT
eurjchem-828	208	61	.	.	PUNCT
eurjchem-828	209	1	oxidation	oxidation	NOUN
eurjchem-828	209	2	of	of	ADP
eurjchem-828	209	3	p(iii	p(iii	ADV
eurjchem-828	209	4	)	)	PUNCT
eurjchem-828	209	5	to	to	ADP
eurjchem-828	209	6	p(v	p(v	NOUN
eurjchem-828	209	7	)	)	PUNCT
eurjchem-828	209	8	during	during	ADP
eurjchem-828	209	9	synthesis	synthesis	NOUN
eurjchem-828	209	10	and	and	CCONJ
eurjchem-828	209	11	work	work	VERB
eurjchem-828	209	12	up	up	ADP
eurjchem-828	209	13	also	also	ADV
eurjchem-828	209	14	follows	follow	VERB
eurjchem-828	209	15	from	from	ADP
eurjchem-828	209	16	nmr	nmr	NOUN
eurjchem-828	209	17	spectra	spectra	PROPN
eurjchem-828	209	18	.	.	PROPN
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eurjchem-828	209	20	8	8	NUM
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eurjchem-828	209	22	mass	mass	ADJ
eurjchem-828	209	23	spectra	spectra	ADJ
eurjchem-828	209	24	fragments	fragment	NOUN
eurjchem-828	209	25	for	for	ADP
eurjchem-828	209	26	10k	10k	NOUN
eurjchem-828	209	27	.	.	PUNCT
eurjchem-828	210	1	m	m	PROPN
eurjchem-828	210	2	/	/	SYM
eurjchem-828	210	3	e	e	VERB
eurjchem-828	210	4	i	i	PROPN
eurjchem-828	210	5	/	/	SYM
eurjchem-828	210	6	imax	imax	PROPN
eurjchem-828	210	7	ions	ion	VERB
eurjchem-828	210	8	271	271	NUM
eurjchem-828	210	9	2.62	2.62	NUM
eurjchem-828	210	10	mo+	mo+	ADJ
eurjchem-828	210	11	255	255	NUM
eurjchem-828	210	12	11.71	11.71	NUM
eurjchem-828	210	13	m+	m+	NUM
eurjchem-828	210	14	196	196	NUM
eurjchem-828	210	15	1.53	1.53	NUM
eurjchem-828	211	1	[	[	X
eurjchem-828	211	2	m‐	m‐	X
eurjchem-828	211	3	co‐	co‐	NOUN
eurjchem-828	211	4	ch3]+	ch3]+	NOUN
eurjchem-828	211	5	185	185	NUM
eurjchem-828	211	6	30.55	30.55	NUM
eurjchem-828	211	7	[	[	X
eurjchem-828	211	8	hopohnc6h5coh]+	hopohnc6h5coh]+	X
eurjchem-828	211	9	151	151	NUM
eurjchem-828	211	10	48.08	48.08	NUM
eurjchem-828	212	1	[	[	X
eurjchem-828	212	2	c6h5ncooch3]+	c6h5ncooch3]+	X
eurjchem-828	212	3	139	139	NUM
eurjchem-828	212	4	22.12	22.12	NUM
eurjchem-828	212	5	[	[	X
eurjchem-828	212	6	pohnc6h5]+	pohnc6h5]+	X
eurjchem-828	212	7	120	120	NUM
eurjchem-828	212	8	11.52	11.52	NUM
eurjchem-828	213	1	[	[	X
eurjchem-828	213	2	c6h5ncoh]+	c6h5ncoh]+	NOUN
eurjchem-828	213	3	119	119	NUM
eurjchem-828	213	4	37.17	37.17	NUM
eurjchem-828	213	5	[	[	X
eurjchem-828	213	6	c6h5nco]+	c6h5nco]+	NUM
eurjchem-828	213	7	105	105	NUM
eurjchem-828	213	8	88.17	88.17	NUM
eurjchem-828	213	9	93	93	NUM
eurjchem-828	213	10	7.15	7.15	NUM
eurjchem-828	214	1	[	[	X
eurjchem-828	214	2	c6h5nh2]+	c6h5nh2]+	NOUN
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eurjchem-828	215	1	[	[	X
eurjchem-828	215	2	c6h5nh]+	c6h5nh]+	X
eurjchem-828	215	3	91	91	NUM
eurjchem-828	215	4	24.57	24.57	NUM
eurjchem-828	216	1	[	[	X
eurjchem-828	216	2	c6h5n]+	c6h5n]+	PROPN
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eurjchem-828	216	4	25.3	25.3	NUM
eurjchem-828	217	1	[	[	X
eurjchem-828	217	2	c6h5]+	c6h5]+	X
eurjchem-828	217	3	59	59	NUM
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eurjchem-828	217	6	cooch3]+	cooch3]+	ADJ
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eurjchem-828	217	11	ch2ch2ch]+	ch2ch2ch]+	X
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eurjchem-828	217	31	.	.	PUNCT
eurjchem-828	218	1	thus	thus	ADV
eurjchem-828	218	2	the	the	DET
eurjchem-828	218	3	intensity	intensity	NOUN
eurjchem-828	218	4	of	of	ADP
eurjchem-828	218	5	the	the	DET
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eurjchem-828	218	7	ion	ion	NOUN
eurjchem-828	218	8	(	(	PUNCT
eurjchem-828	218	9	m	m	NOUN
eurjchem-828	218	10	/	/	SYM
eurjchem-828	218	11	e	e	NOUN
eurjchem-828	218	12	257	257	NUM
eurjchem-828	218	13	)	)	PUNCT
eurjchem-828	218	14	in	in	ADP
eurjchem-828	218	15	phosphorylated	phosphorylate	VERB
eurjchem-828	218	16	thiocarbamate	thiocarbamate	NOUN
eurjchem-828	218	17	10	10	NUM
eurjchem-828	218	18	g	g	NOUN
eurjchem-828	218	19	is	be	AUX
eurjchem-828	218	20	just	just	ADV
eurjchem-828	218	21	1.1	1.1	NUM
eurjchem-828	218	22	%	%	NOUN
eurjchem-828	218	23	,	,	PUNCT
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eurjchem-828	218	25	for	for	ADP
eurjchem-828	218	26	compound	compound	NOUN
eurjchem-828	218	27	10i	10i	NOUN
eurjchem-828	218	28	it	it	PRON
eurjchem-828	218	29	is	be	AUX
eurjchem-828	218	30	even	even	ADV
eurjchem-828	218	31	lower	low	ADJ
eurjchem-828	218	32	‐0.11	‐0.11	NOUN
eurjchem-828	218	33	%	%	NOUN
eurjchem-828	218	34	.	.	PUNCT
eurjchem-828	219	1	the	the	DET
eurjchem-828	219	2	p‐n	p‐n	NOUN
eurjchem-828	219	3	bond	bond	NOUN
eurjchem-828	219	4	length	length	NOUN
eurjchem-828	219	5	calculated	calculate	VERB
eurjchem-828	219	6	by	by	ADP
eurjchem-828	219	7	extended	extended	ADJ
eurjchem-828	219	8	huckel	huckel	NOUN
eurjchem-828	219	9	method	method	NOUN
eurjchem-828	219	10	(	(	PUNCT
eurjchem-828	219	11	chem	chem	NOUN
eurjchem-828	219	12	3d	3d	NOUN
eurjchem-828	219	13	pro	pro	NOUN
eurjchem-828	219	14	)	)	PUNCT
eurjchem-828	219	15	after	after	ADP
eurjchem-828	219	16	structure	structure	NOUN
eurjchem-828	219	17	optimization	optimization	NOUN
eurjchem-828	219	18	for	for	ADP
eurjchem-828	219	19	compound	compound	NOUN
eurjchem-828	219	20	10	10	NUM
eurjchem-828	219	21	g	g	NOUN
eurjchem-828	219	22	is	be	AUX
eurjchem-828	219	23	marginally	marginally	ADV
eurjchem-828	219	24	larger	large	ADJ
eurjchem-828	219	25	(	(	PUNCT
eurjchem-828	219	26	1.775	1.775	NUM
eurjchem-828	219	27	å	å	NOUN
eurjchem-828	219	28	)	)	PUNCT
eurjchem-828	219	29	than	than	ADP
eurjchem-828	219	30	for	for	ADP
eurjchem-828	219	31	compound	compound	NOUN
eurjchem-828	219	32	10c	10c	NOUN
eurjchem-828	219	33	,	,	PUNCT
eurjchem-828	219	34	while	while	SCONJ
eurjchem-828	219	35	the	the	DET
eurjchem-828	219	36	partial	partial	ADJ
eurjchem-828	219	37	charges	charge	NOUN
eurjchem-828	219	38	for	for	ADP
eurjchem-828	219	39	p	p	NOUN
eurjchem-828	219	40	and	and	CCONJ
eurjchem-828	219	41	n	n	ADV
eurjchem-828	219	42	get	get	VERB
eurjchem-828	219	43	the	the	DET
eurjchem-828	219	44	values	value	NOUN
eurjchem-828	219	45	1.06544	1.06544	NUM
eurjchem-828	219	46	and	and	CCONJ
eurjchem-828	219	47	0.222732	0.222732	NUM
eurjchem-828	219	48	.	.	PUNCT
eurjchem-828	220	1	in	in	ADP
eurjchem-828	220	2	the	the	DET
eurjchem-828	220	3	case	case	NOUN
eurjchem-828	220	4	of	of	ADP
eurjchem-828	220	5	compound	compound	NOUN
eurjchem-828	220	6	10c	10c	NOUN
eurjchem-828	220	7	the	the	DET
eurjchem-828	220	8	ion	ion	NOUN
eurjchem-828	220	9	with	with	ADP
eurjchem-828	220	10	m	m	PROPN
eurjchem-828	220	11	/	/	SYM
eurjchem-828	220	12	e	e	NOUN
eurjchem-828	220	13	120	120	NUM
eurjchem-828	220	14	[	[	X
eurjchem-828	220	15	c6h5nhco]+	c6h5nhco]+	NOUN
eurjchem-828	220	16	is	be	AUX
eurjchem-828	220	17	the	the	DET
eurjchem-828	220	18	main	main	ADJ
eurjchem-828	220	19	one	one	NOUN
eurjchem-828	220	20	,	,	PUNCT
eurjchem-828	220	21	while	while	SCONJ
eurjchem-828	220	22	intensity	intensity	NOUN
eurjchem-828	220	23	of	of	ADP
eurjchem-828	220	24	ion	ion	NOUN
eurjchem-828	220	25	with	with	ADP
eurjchem-828	220	26	m	m	PROPN
eurjchem-828	220	27	/	/	SYM
eurjchem-828	220	28	e	e	NOUN
eurjchem-828	220	29	136	136	NUM
eurjchem-828	220	30	[	[	X
eurjchem-828	220	31	c6h5nhcs	c6h5nhcs	X
eurjchem-828	220	32	]	]	X
eurjchem-828	220	33	+	+	CCONJ
eurjchem-828	220	34	is	be	AUX
eurjchem-828	220	35	14.06	14.06	NUM
eurjchem-828	220	36	%	%	NOUN
eurjchem-828	220	37	which	which	PRON
eurjchem-828	220	38	is	be	AUX
eurjchem-828	220	39	typical	typical	ADJ
eurjchem-828	220	40	for	for	ADP
eurjchem-828	220	41	thiocarbamates	thiocarbamate	NOUN
eurjchem-828	220	42	with	with	ADP
eurjchem-828	220	43	a	a	DET
eurjchem-828	220	44	long	long	ADJ
eurjchem-828	220	45	chain	chain	NOUN
eurjchem-828	220	46	substituent	substituent	NOUN
eurjchem-828	220	47	in	in	ADP
eurjchem-828	220	48	the	the	DET
eurjchem-828	220	49	ester	ester	NOUN
eurjchem-828	220	50	part	part	NOUN
eurjchem-828	220	51	of	of	ADP
eurjchem-828	220	52	the	the	DET
eurjchem-828	220	53	molecule	molecule	NOUN
eurjchem-828	220	54	.	.	PUNCT
eurjchem-828	221	1	mass	mass	PROPN
eurjchem-828	221	2	spectrum	spectrum	NOUN
eurjchem-828	221	3	of	of	ADP
eurjchem-828	221	4	the	the	DET
eurjchem-828	221	5	same	same	ADJ
eurjchem-828	221	6	compound	compound	NOUN
eurjchem-828	221	7	10c	10c	NOUN
eurjchem-828	221	8	contains	contain	VERB
eurjchem-828	221	9	also	also	ADV
eurjchem-828	221	10	ions	ion	NOUN
eurjchem-828	221	11	with	with	ADP
eurjchem-828	221	12	m	m	PROPN
eurjchem-828	221	13	/	/	SYM
eurjchem-828	221	14	e	e	NOUN
eurjchem-828	221	15	154	154	NUM
eurjchem-828	221	16	(	(	PUNCT
eurjchem-828	221	17	16.04	16.04	NUM
eurjchem-828	221	18	%	%	NOUN
eurjchem-828	221	19	)	)	PUNCT
eurjchem-828	221	20	and	and	CCONJ
eurjchem-828	221	21	155	155	NUM
eurjchem-828	221	22	(	(	PUNCT
eurjchem-828	221	23	5.5	5.5	NUM
eurjchem-828	221	24	%	%	NOUN
eurjchem-828	221	25	)	)	PUNCT
eurjchem-828	221	26	corresponding	correspond	VERB
eurjchem-828	221	27	respectively	respectively	ADV
eurjchem-828	221	28	to	to	ADP
eurjchem-828	221	29	[	[	PUNCT
eurjchem-828	221	30	oponc6h5]+	oponc6h5]+	X
eurjchem-828	221	31	and	and	CCONJ
eurjchem-828	221	32	[	[	X
eurjchem-828	221	33	oponhc6h5]+	oponhc6h5]+	X
eurjchem-828	221	34	.	.	PUNCT
eurjchem-828	222	1	if	if	SCONJ
eurjchem-828	222	2	a	a	DET
eurjchem-828	222	3	substituent	substituent	NOUN
eurjchem-828	222	4	at	at	ADP
eurjchem-828	222	5	n	n	PROPN
eurjchem-828	222	6	is	be	AUX
eurjchem-828	222	7	not	not	PART
eurjchem-828	222	8	phenyl	phenyl	NOUN
eurjchem-828	222	9	,	,	PUNCT
eurjchem-828	222	10	but	but	CCONJ
eurjchem-828	222	11	for	for	ADP
eurjchem-828	222	12	example	example	NOUN
eurjchem-828	222	13	allyl	allyl	PROPN
eurjchem-828	222	14	radical	radical	PROPN
eurjchem-828	222	15	mass	mass	PROPN
eurjchem-828	222	16	spectra	spectra	NOUN
eurjchem-828	222	17	are	be	AUX
eurjchem-828	222	18	different	different	ADJ
eurjchem-828	222	19	,	,	PUNCT
eurjchem-828	222	20	since	since	SCONJ
eurjchem-828	222	21	then	then	ADV
eurjchem-828	222	22	n‐c	n‐c	PROPN
eurjchem-828	222	23	bond	bond	NOUN
eurjchem-828	222	24	is	be	AUX
eurjchem-828	222	25	much	much	ADV
eurjchem-828	222	26	less	less	ADV
eurjchem-828	222	27	stable	stable	ADJ
eurjchem-828	222	28	(	(	PUNCT
eurjchem-828	222	29	n‐c	n‐c	NUM
eurjchem-828	222	30	bond	bond	NOUN
eurjchem-828	222	31	distances	distance	NOUN
eurjchem-828	222	32	are	be	AUX
eurjchem-828	222	33	respectively	respectively	ADV
eurjchem-828	222	34	1.316	1.316	NUM
eurjchem-828	222	35	and	and	CCONJ
eurjchem-828	222	36	1.470	1.470	NUM
eurjchem-828	222	37	å	å	NOUN
eurjchem-828	222	38	for	for	ADP
eurjchem-828	222	39	compound	compound	NOUN
eurjchem-828	222	40	10	10	NUM
eurjchem-828	222	41	g	g	NOUN
eurjchem-828	222	42	and	and	CCONJ
eurjchem-828	222	43	10f	10f	NUM
eurjchem-828	222	44	)	)	PUNCT
eurjchem-828	222	45	.	.	PUNCT
eurjchem-828	223	1	thus	thus	ADV
eurjchem-828	223	2	mass	mass	ADJ
eurjchem-828	223	3	spectrum	spectrum	NOUN
eurjchem-828	223	4	of	of	ADP
eurjchem-828	223	5	compound	compound	NOUN
eurjchem-828	223	6	10f	10f	PROPN
eurjchem-828	223	7	(	(	PUNCT
eurjchem-828	223	8	table	table	NOUN
eurjchem-828	223	9	9	9	NUM
eurjchem-828	223	10	)	)	PUNCT
eurjchem-828	223	11	demonstrates	demonstrate	VERB
eurjchem-828	223	12	presence	presence	NOUN
eurjchem-828	223	13	of	of	ADP
eurjchem-828	223	14	an	an	DET
eurjchem-828	223	15	ion	ion	NOUN
eurjchem-828	223	16	of	of	ADP
eurjchem-828	223	17	m	m	PROPN
eurjchem-828	223	18	/	/	SYM
eurjchem-828	223	19	e	e	NOUN
eurjchem-828	223	20	206	206	NUM
eurjchem-828	223	21	with	with	ADP
eurjchem-828	223	22	intensity	intensity	NOUN
eurjchem-828	223	23	1.37	1.37	NUM
eurjchem-828	223	24	%	%	NOUN
eurjchem-828	223	25	as	as	ADV
eurjchem-828	223	26	well	well	ADV
eurjchem-828	223	27	the	the	DET
eurjchem-828	223	28	ion	ion	NOUN
eurjchem-828	223	29	with	with	ADP
eurjchem-828	223	30	m	m	PROPN
eurjchem-828	223	31	/	/	SYM
eurjchem-828	223	32	e	e	NOUN
eurjchem-828	223	33	149	149	NUM
eurjchem-828	223	34	(	(	PUNCT
eurjchem-828	223	35	1.85	1.85	NUM
eurjchem-828	223	36	%	%	NOUN
eurjchem-828	223	37	)	)	PUNCT
eurjchem-828	223	38	.	.	PUNCT
eurjchem-828	224	1	the	the	DET
eurjchem-828	224	2	rupture	rupture	NOUN
eurjchem-828	224	3	of	of	ADP
eurjchem-828	224	4	the	the	DET
eurjchem-828	224	5	dioxaphospholane	dioxaphospholane	NOUN
eurjchem-828	224	6	cycle	cycle	NOUN
eurjchem-828	224	7	is	be	AUX
eurjchem-828	224	8	hindered	hinder	VERB
eurjchem-828	224	9	,	,	PUNCT
eurjchem-828	224	10	which	which	PRON
eurjchem-828	224	11	is	be	AUX
eurjchem-828	224	12	confirmed	confirm	VERB
eurjchem-828	224	13	by	by	ADP
eurjchem-828	224	14	the	the	DET
eurjchem-828	224	15	presence	presence	NOUN
eurjchem-828	224	16	of	of	ADP
eurjchem-828	224	17	such	such	ADJ
eurjchem-828	224	18	ions	ion	NOUN
eurjchem-828	224	19	as	as	ADP
eurjchem-828	224	20	m	m	NOUN
eurjchem-828	224	21	/	/	SYM
eurjchem-828	224	22	e	e	PROPN
eurjchem-828	224	23	105	105	NUM
eurjchem-828	224	24	(	(	PUNCT
eurjchem-828	224	25	2.01	2.01	NUM
eurjchem-828	224	26	%	%	NOUN
eurjchem-828	224	27	)	)	PUNCT
eurjchem-828	224	28	and	and	CCONJ
eurjchem-828	224	29	m	m	PROPN
eurjchem-828	224	30	/	/	SYM
eurjchem-828	224	31	e	e	X
eurjchem-828	224	32	91	91	NUM
eurjchem-828	224	33	(	(	PUNCT
eurjchem-828	224	34	26.69	26.69	NUM
eurjchem-828	224	35	%	%	NOUN
eurjchem-828	224	36	)	)	PUNCT
eurjchem-828	224	37	.	.	PUNCT
eurjchem-828	225	1	table	table	NOUN
eurjchem-828	225	2	9	9	NUM
eurjchem-828	225	3	.	.	PUNCT
eurjchem-828	225	4	mass	mass	ADJ
eurjchem-828	225	5	spectra	spectra	ADJ
eurjchem-828	225	6	fragments	fragment	NOUN
eurjchem-828	225	7	for	for	ADP
eurjchem-828	225	8	10f	10f	NUM
eurjchem-828	225	9	.	.	PUNCT
eurjchem-828	226	1	m	m	PROPN
eurjchem-828	226	2	/	/	SYM
eurjchem-828	226	3	e	e	PROPN
eurjchem-828	226	4	i	i	PROPN
eurjchem-828	226	5	/	/	SYM
eurjchem-828	226	6	imax	imax	PROPN
eurjchem-828	226	7	ions	ion	NOUN
eurjchem-828	226	8	255	255	NUM
eurjchem-828	226	9	1.05	1.05	NUM
eurjchem-828	226	10	m+	m+	NOUN
eurjchem-828	226	11	206	206	NUM
eurjchem-828	226	12	1.3	1.3	NUM
eurjchem-828	227	1	[	[	X
eurjchem-828	227	2	(	(	PUNCT
eurjchem-828	227	3	ch2o)2pn(cso)ch2ch	ch2o)2pn(cso)ch2ch	PROPN
eurjchem-828	227	4	=	=	SYM
eurjchem-828	227	5	ch2]+	ch2]+	NOUN
eurjchem-828	227	6	190	190	NUM
eurjchem-828	227	7	3.28	3.28	NUM
eurjchem-828	227	8	[	[	X
eurjchem-828	227	9	(	(	PUNCT
eurjchem-828	227	10	ch2o)2pn(cs)ch2ch	ch2o)2pn(cs)ch2ch	X
eurjchem-828	227	11	=	=	NOUN
eurjchem-828	227	12	ch2]+	ch2]+	NOUN
eurjchem-828	227	13	149	149	NUM
eurjchem-828	227	14	1.85	1.85	NUM
eurjchem-828	227	15	[	[	X
eurjchem-828	227	16	(	(	PUNCT
eurjchem-828	227	17	ch2o)2pn(cs)]+	ch2o)2pn(cs)]+	PROPN
eurjchem-828	227	18	105	105	NUM
eurjchem-828	227	19	2.09	2.09	NUM
eurjchem-828	227	20	[	[	X
eurjchem-828	227	21	(	(	PUNCT
eurjchem-828	227	22	ch2o)2pn]+	ch2o)2pn]+	X
eurjchem-828	227	23	91	91	NUM
eurjchem-828	227	24	26.69	26.69	NUM
eurjchem-828	227	25	[	[	X
eurjchem-828	227	26	(	(	PUNCT
eurjchem-828	227	27	ch2o)2p]+	ch2o)2p]+	PROPN
eurjchem-828	227	28	58	58	NUM
eurjchem-828	227	29	19.38	19.38	NUM
eurjchem-828	227	30	[	[	PUNCT
eurjchem-828	227	31	ncs]+	ncs]+	NOUN
eurjchem-828	227	32	45	45	NUM
eurjchem-828	227	33	30.29	30.29	NUM
eurjchem-828	227	34	[	[	X
eurjchem-828	227	35	oc2h5]+	oc2h5]+	X
eurjchem-828	227	36	41	41	NUM
eurjchem-828	227	37	36.65	36.65	NUM
eurjchem-828	227	38	[	[	X
eurjchem-828	227	39	ch2ch	ch2ch	X
eurjchem-828	227	40	=	=	ADJ
eurjchem-828	227	41	ch2]+	ch2]+	NOUN
eurjchem-828	227	42	28	28	NUM
eurjchem-828	227	43	100	100	NUM
eurjchem-828	227	44	%	%	NOUN
eurjchem-828	227	45	‐	‐	VERB
eurjchem-828	227	46	3.2	3.2	NUM
eurjchem-828	227	47	.	.	PUNCT
eurjchem-828	228	1	reactivity	reactivity	NOUN
eurjchem-828	228	2	reactions	reaction	NOUN
eurjchem-828	228	3	of	of	ADP
eurjchem-828	228	4	phosphorylated	phosphorylate	VERB
eurjchem-828	228	5	carbamates	carbamate	NOUN
eurjchem-828	228	6	with	with	ADP
eurjchem-828	228	7	an	an	DET
eurjchem-828	228	8	effective	effective	ADJ
eurjchem-828	228	9	electrophile	electrophile	NOUN
eurjchem-828	228	10	,	,	PUNCT
eurjchem-828	228	11	elemental	elemental	ADJ
eurjchem-828	228	12	sulphur	sulphur	NOUN
eurjchem-828	228	13	(	(	PUNCT
eurjchem-828	228	14	s8	s8	PROPN
eurjchem-828	228	15	)	)	PUNCT
eurjchem-828	228	16	were	be	AUX
eurjchem-828	228	17	conducted	conduct	VERB
eurjchem-828	228	18	according	accord	VERB
eurjchem-828	228	19	to	to	ADP
eurjchem-828	228	20	scheme	scheme	NOUN
eurjchem-828	228	21	5	5	NUM
eurjchem-828	228	22	.	.	PUNCT
eurjchem-828	228	23	thin	thin	ADJ
eurjchem-828	228	24	layer	layer	NOUN
eurjchem-828	228	25	chromatography	chromatography	NOUN
eurjchem-828	228	26	,	,	PUNCT
eurjchem-828	228	27	ir	ir	PROPN
eurjchem-828	228	28	,	,	PUNCT
eurjchem-828	228	29	mass	mass	ADJ
eurjchem-828	228	30	and	and	CCONJ
eurjchem-828	228	31	nmr	nmr	NOUN
eurjchem-828	228	32	spectra	spectra	NOUN
eurjchem-828	228	33	were	be	AUX
eurjchem-828	228	34	used	use	VERB
eurjchem-828	228	35	to	to	PART
eurjchem-828	228	36	identify	identify	VERB
eurjchem-828	228	37	the	the	DET
eurjchem-828	228	38	purity	purity	NOUN
eurjchem-828	228	39	and	and	CCONJ
eurjchem-828	228	40	structure	structure	NOUN
eurjchem-828	228	41	of	of	ADP
eurjchem-828	228	42	these	these	PRON
eurjchem-828	228	43	not	not	PART
eurjchem-828	228	44	previously	previously	ADV
eurjchem-828	228	45	reported	report	VERB
eurjchem-828	228	46	compounds	compound	NOUN
eurjchem-828	228	47	.	.	PUNCT
eurjchem-828	229	1	in	in	ADP
eurjchem-828	229	2	the	the	DET
eurjchem-828	229	3	ir	ir	PROPN
eurjchem-828	229	4	spectra	spectra	NOUN
eurjchem-828	229	5	there	there	PRON
eurjchem-828	229	6	are	be	VERB
eurjchem-828	229	7	vibrations	vibration	NOUN
eurjchem-828	229	8	corresponding	correspond	VERB
eurjchem-828	229	9	to	to	ADP
eurjchem-828	229	10	the	the	DET
eurjchem-828	229	11	carbonyl	carbonyl	NOUN
eurjchem-828	229	12	group	group	NOUN
eurjchem-828	229	13	at	at	ADP
eurjchem-828	229	14	1720‐1740	1720‐1740	PROPN
eurjchem-828	229	15	cm‐1	cm‐1	PROPN
eurjchem-828	229	16	(	(	PUNCT
eurjchem-828	229	17	11a	11a	NOUN
eurjchem-828	229	18	,	,	PUNCT
eurjchem-828	229	19	11b	11b	NOUN
eurjchem-828	229	20	,	,	PUNCT
eurjchem-828	229	21	and	and	CCONJ
eurjchem-828	229	22	11e	11e	NUM
eurjchem-828	229	23	)	)	PUNCT
eurjchem-828	229	24	and	and	CCONJ
eurjchem-828	229	25	c	c	X
eurjchem-828	229	26	=	=	NOUN
eurjchem-828	229	27	s	s	NOUN
eurjchem-828	229	28	group	group	NOUN
eurjchem-828	229	29	at	at	ADP
eurjchem-828	229	30	1380‐1390	1380‐1390	NUM
eurjchem-828	229	31	cm‐1	cm‐1	PROPN
eurjchem-828	229	32	(	(	PUNCT
eurjchem-828	229	33	11c	11c	NOUN
eurjchem-828	229	34	,	,	PUNCT
eurjchem-828	229	35	11d	11d	NOUN
eurjchem-828	229	36	,	,	PUNCT
eurjchem-828	229	37	and	and	CCONJ
eurjchem-828	229	38	11f	11f	NUM
eurjchem-828	229	39	)	)	PUNCT
eurjchem-828	229	40	.	.	PUNCT
eurjchem-828	230	1	in	in	ADP
eurjchem-828	230	2	the	the	DET
eurjchem-828	230	3	region	region	NOUN
eurjchem-828	231	1	1600‐1470	1600‐1470	NUM
eurjchem-828	231	2	cm‐1	cm‐1	INTJ
eurjchem-828	231	3	there	there	PRON
eurjchem-828	231	4	are	be	VERB
eurjchem-828	231	5	peaks	peak	NOUN
eurjchem-828	231	6	corresponding	correspond	VERB
eurjchem-828	231	7	to	to	ADP
eurjchem-828	231	8	the	the	DET
eurjchem-828	231	9	phenyl	phenyl	NOUN
eurjchem-828	231	10	ring	ring	NOUN
eurjchem-828	231	11	and	and	CCONJ
eurjchem-828	231	12	dioxaphospholane	dioxaphospholane	NOUN
eurjchem-828	231	13	cycle	cycle	NOUN
eurjchem-828	231	14	.	.	PUNCT
eurjchem-828	232	1	for	for	ADP
eurjchem-828	232	2	p	p	PROPN
eurjchem-828	232	3	=	=	NOUN
eurjchem-828	232	4	s	s	PART
eurjchem-828	232	5	bonds	bond	NOUN
eurjchem-828	232	6	typically	typically	ADV
eurjchem-828	232	7	there	there	PRON
eurjchem-828	232	8	are	be	VERB
eurjchem-828	232	9	two	two	NUM
eurjchem-828	232	10	peaks	peak	NOUN
eurjchem-828	232	11	in	in	ADP
eurjchem-828	232	12	a	a	DET
eurjchem-828	232	13	rather	rather	ADJ
eurjchem-828	232	14	range	range	NOUN
eurjchem-828	232	15	of	of	ADP
eurjchem-828	232	16	770‐840	770‐840	PROPN
eurjchem-828	232	17	cm‐1	cm‐1	NOUN
eurjchem-828	232	18	and	and	CCONJ
eurjchem-828	232	19	600‐700	600‐700	NUM
eurjchem-828	232	20	murzin	murzin	NOUN
eurjchem-828	232	21	and	and	CCONJ
eurjchem-828	232	22	kolesova	kolesova	PROPN
eurjchem-828	232	23	/	/	SYM
eurjchem-828	232	24	european	european	PROPN
eurjchem-828	232	25	journal	journal	PROPN
eurjchem-828	232	26	of	of	ADP
eurjchem-828	232	27	chemistry	chemistry	NOUN
eurjchem-828	232	28	4	4	NUM
eurjchem-828	232	29	(	(	PUNCT
eurjchem-828	232	30	4	4	NUM
eurjchem-828	232	31	)	)	PUNCT
eurjchem-828	232	32	(	(	PUNCT
eurjchem-828	232	33	2013	2013	NUM
eurjchem-828	232	34	)	)	PUNCT
eurjchem-828	232	35	336‐342	336‐342	PROPN
eurjchem-828	232	36	341	341	NUM
eurjchem-828	232	37	cm‐1	cm‐1	NOUN
eurjchem-828	232	38	also	also	ADV
eurjchem-828	232	39	seen	see	VERB
eurjchem-828	232	40	for	for	ADP
eurjchem-828	232	41	the	the	DET
eurjchem-828	232	42	compounds	compound	NOUN
eurjchem-828	232	43	synthesized	synthesize	VERB
eurjchem-828	232	44	in	in	ADP
eurjchem-828	232	45	the	the	DET
eurjchem-828	232	46	present	present	ADJ
eurjchem-828	232	47	work	work	NOUN
eurjchem-828	232	48	,	,	PUNCT
eurjchem-828	232	49	where	where	SCONJ
eurjchem-828	232	50	the	the	DET
eurjchem-828	232	51	peaks	peak	NOUN
eurjchem-828	232	52	of	of	ADP
eurjchem-828	232	53	p	p	X
eurjchem-828	232	54	=	=	X
eurjchem-828	232	55	s	s	NOUN
eurjchem-828	232	56	for	for	ADP
eurjchem-828	232	57	compound	compound	NOUN
eurjchem-828	232	58	11d	11d	NOUN
eurjchem-828	232	59	were	be	AUX
eurjchem-828	232	60	noticeable	noticeable	ADJ
eurjchem-828	232	61	at	at	ADP
eurjchem-828	232	62	660	660	NUM
eurjchem-828	232	63	and	and	CCONJ
eurjchem-828	232	64	770	770	NUM
eurjchem-828	232	65	cm‐1	cm‐1	NOUN
eurjchem-828	232	66	.	.	PUNCT
eurjchem-828	233	1	in	in	ADP
eurjchem-828	233	2	the	the	DET
eurjchem-828	233	3	mass	mass	NOUN
eurjchem-828	233	4	spectrum	spectrum	NOUN
eurjchem-828	233	5	of	of	ADP
eurjchem-828	233	6	compound	compound	NOUN
eurjchem-828	233	7	11a	11a	NOUN
eurjchem-828	233	8	(	(	PUNCT
eurjchem-828	233	9	table	table	NOUN
eurjchem-828	233	10	10	10	NUM
eurjchem-828	233	11	)	)	PUNCT
eurjchem-828	233	12	the	the	DET
eurjchem-828	233	13	intensity	intensity	NOUN
eurjchem-828	233	14	of	of	ADP
eurjchem-828	233	15	the	the	DET
eurjchem-828	233	16	molecular	molecular	ADJ
eurjchem-828	233	17	ion	ion	NOUN
eurjchem-828	233	18	is	be	AUX
eurjchem-828	233	19	rather	rather	ADV
eurjchem-828	233	20	high	high	ADJ
eurjchem-828	233	21	(	(	PUNCT
eurjchem-828	233	22	15.47	15.47	NUM
eurjchem-828	233	23	%	%	NOUN
eurjchem-828	233	24	)	)	PUNCT
eurjchem-828	233	25	confirming	confirm	VERB
eurjchem-828	233	26	the	the	DET
eurjchem-828	233	27	strength	strength	NOUN
eurjchem-828	233	28	of	of	ADP
eurjchem-828	233	29	p‐n	p‐n	NOUN
eurjchem-828	233	30	bonds	bond	NOUN
eurjchem-828	233	31	in	in	ADP
eurjchem-828	233	32	the	the	DET
eurjchem-828	233	33	synthesized	synthesize	VERB
eurjchem-828	233	34	phosphorylated	phosphorylate	VERB
eurjchem-828	233	35	carbamates	carbamate	NOUN
eurjchem-828	233	36	.	.	PUNCT
eurjchem-828	234	1	presence	presence	NOUN
eurjchem-828	234	2	of	of	ADP
eurjchem-828	234	3	[	[	PUNCT
eurjchem-828	234	4	m+2]+	m+2]+	PRON
eurjchem-828	234	5	also	also	ADV
eurjchem-828	234	6	confirms	confirm	VERB
eurjchem-828	234	7	the	the	DET
eurjchem-828	234	8	structure	structure	NOUN
eurjchem-828	234	9	of	of	ADP
eurjchem-828	234	10	compound	compound	NOUN
eurjchem-828	234	11	11a	11a	NOUN
eurjchem-828	234	12	since	since	SCONJ
eurjchem-828	234	13	the	the	DET
eurjchem-828	234	14	signal	signal	NOUN
eurjchem-828	234	15	is	be	AUX
eurjchem-828	234	16	due	due	ADJ
eurjchem-828	234	17	to	to	PART
eurjchem-828	234	18	isotope	isotope	NOUN
eurjchem-828	234	19	s34	s34	NOUN
eurjchem-828	234	20	.	.	PUNCT
eurjchem-828	235	1	in	in	ADP
eurjchem-828	235	2	the	the	DET
eurjchem-828	235	3	mass	mass	NOUN
eurjchem-828	235	4	spectrum	spectrum	NOUN
eurjchem-828	235	5	of	of	ADP
eurjchem-828	235	6	compound	compound	NOUN
eurjchem-828	235	7	11d	11d	NOUN
eurjchem-828	235	8	it	it	PRON
eurjchem-828	235	9	could	could	AUX
eurjchem-828	235	10	be	be	AUX
eurjchem-828	235	11	expected	expect	VERB
eurjchem-828	235	12	that	that	SCONJ
eurjchem-828	235	13	the	the	DET
eurjchem-828	235	14	intensity	intensity	NOUN
eurjchem-828	235	15	of	of	ADP
eurjchem-828	235	16	molecular	molecular	ADJ
eurjchem-828	235	17	ion	ion	NOUN
eurjchem-828	235	18	is	be	AUX
eurjchem-828	235	19	low	low	ADJ
eurjchem-828	235	20	compared	compare	VERB
eurjchem-828	235	21	to	to	ADP
eurjchem-828	235	22	compound	compound	VERB
eurjchem-828	235	23	11a	11a	NOUN
eurjchem-828	235	24	,	,	PUNCT
eurjchem-828	235	25	since	since	SCONJ
eurjchem-828	235	26	thiocarbamates	thiocarbamate	NOUN
eurjchem-828	235	27	are	be	AUX
eurjchem-828	235	28	not	not	PART
eurjchem-828	235	29	stable	stable	ADJ
eurjchem-828	235	30	at	at	ADP
eurjchem-828	235	31	the	the	DET
eurjchem-828	235	32	conditions	condition	NOUN
eurjchem-828	235	33	of	of	ADP
eurjchem-828	235	34	electron	electron	NOUN
eurjchem-828	235	35	beam	beam	NOUN
eurjchem-828	235	36	.	.	PUNCT
eurjchem-828	236	1	indeed	indeed	ADV
eurjchem-828	236	2	the	the	DET
eurjchem-828	236	3	molecular	molecular	ADJ
eurjchem-828	236	4	ion	ion	NOUN
eurjchem-828	236	5	is	be	AUX
eurjchem-828	236	6	absent	absent	ADJ
eurjchem-828	236	7	,	,	PUNCT
eurjchem-828	236	8	while	while	SCONJ
eurjchem-828	236	9	an	an	DET
eurjchem-828	236	10	ion	ion	NOUN
eurjchem-828	236	11	[	[	X
eurjchem-828	236	12	(	(	PUNCT
eurjchem-828	236	13	ch2o)2ps]+	ch2o)2ps]+	NOUN
eurjchem-828	236	14	with	with	ADP
eurjchem-828	236	15	m	m	PROPN
eurjchem-828	236	16	/	/	SYM
eurjchem-828	236	17	e	e	NOUN
eurjchem-828	236	18	123	123	NUM
eurjchem-828	236	19	(	(	PUNCT
eurjchem-828	236	20	11.53	11.53	NUM
eurjchem-828	236	21	%	%	NOUN
eurjchem-828	236	22	)	)	PUNCT
eurjchem-828	236	23	confirms	confirm	VERB
eurjchem-828	236	24	addition	addition	NOUN
eurjchem-828	236	25	of	of	ADP
eurjchem-828	236	26	sulphur	sulphur	NOUN
eurjchem-828	236	27	to	to	ADP
eurjchem-828	236	28	the	the	DET
eurjchem-828	236	29	substrate	substrate	NOUN
eurjchem-828	236	30	10h	10h	NUM
eurjchem-828	236	31	.	.	PUNCT
eurjchem-828	237	1	in	in	ADP
eurjchem-828	237	2	the	the	DET
eurjchem-828	237	3	case	case	NOUN
eurjchem-828	237	4	of	of	ADP
eurjchem-828	237	5	compound	compound	ADJ
eurjchem-828	237	6	11d	11d	ADJ
eurjchem-828	237	7	intensity	intensity	NOUN
eurjchem-828	237	8	of	of	ADP
eurjchem-828	237	9	[	[	X
eurjchem-828	237	10	c6h5ncs]+	c6h5ncs]+	NOUN
eurjchem-828	237	11	ion	ion	NOUN
eurjchem-828	237	12	(	(	PUNCT
eurjchem-828	237	13	m	m	NOUN
eurjchem-828	237	14	/	/	SYM
eurjchem-828	237	15	e	e	NOUN
eurjchem-828	237	16	135	135	NUM
eurjchem-828	237	17	)	)	PUNCT
eurjchem-828	237	18	is	be	AUX
eurjchem-828	237	19	rather	rather	ADV
eurjchem-828	237	20	low	low	ADJ
eurjchem-828	237	21	(	(	PUNCT
eurjchem-828	237	22	2.37	2.37	NUM
eurjchem-828	237	23	%	%	NOUN
eurjchem-828	237	24	)	)	PUNCT
eurjchem-828	237	25	in	in	ADP
eurjchem-828	237	26	comparison	comparison	NOUN
eurjchem-828	237	27	with	with	ADP
eurjchem-828	237	28	[	[	X
eurjchem-828	237	29	c6h5nco]+	c6h5nco]+	NOUN
eurjchem-828	237	30	,	,	PUNCT
eurjchem-828	237	31	which	which	PRON
eurjchem-828	237	32	is	be	AUX
eurjchem-828	237	33	the	the	DET
eurjchem-828	237	34	main	main	ADJ
eurjchem-828	237	35	ion	ion	NOUN
eurjchem-828	237	36	.	.	PUNCT
eurjchem-828	238	1	the	the	DET
eurjchem-828	238	2	partial	partial	ADJ
eurjchem-828	238	3	charges	charge	NOUN
eurjchem-828	238	4	of	of	ADP
eurjchem-828	238	5	p	p	NOUN
eurjchem-828	238	6	and	and	CCONJ
eurjchem-828	238	7	n	n	NOUN
eurjchem-828	238	8	for	for	ADP
eurjchem-828	238	9	compound	compound	NOUN
eurjchem-828	238	10	11a	11a	NOUN
eurjchem-828	238	11	(	(	PUNCT
eurjchem-828	238	12	1.9673	1.9673	NUM
eurjchem-828	238	13	and	and	CCONJ
eurjchem-828	238	14	‐0.0143	‐0.0143	NOUN
eurjchem-828	238	15	)	)	PUNCT
eurjchem-828	238	16	as	as	ADV
eurjchem-828	238	17	well	well	ADV
eurjchem-828	238	18	as	as	ADP
eurjchem-828	238	19	the	the	DET
eurjchem-828	238	20	bond	bond	NOUN
eurjchem-828	238	21	length	length	NOUN
eurjchem-828	238	22	(	(	PUNCT
eurjchem-828	238	23	1.773	1.773	NUM
eurjchem-828	238	24	å	å	NOUN
eurjchem-828	238	25	)	)	PUNCT
eurjchem-828	238	26	differ	differ	VERB
eurjchem-828	238	27	from	from	ADP
eurjchem-828	238	28	the	the	DET
eurjchem-828	238	29	corresponding	corresponding	ADJ
eurjchem-828	238	30	thiocarbamate	thiocarbamate	ADJ
eurjchem-828	238	31	11d	11d	NOUN
eurjchem-828	238	32	(	(	PUNCT
eurjchem-828	238	33	charges	charge	NOUN
eurjchem-828	238	34	of	of	ADP
eurjchem-828	238	35	p	p	NOUN
eurjchem-828	238	36	and	and	CCONJ
eurjchem-828	238	37	n	n	PRON
eurjchem-828	238	38	being	be	AUX
eurjchem-828	238	39	2.00269	2.00269	NUM
eurjchem-828	238	40	and	and	CCONJ
eurjchem-828	238	41	0.17678	0.17678	NUM
eurjchem-828	238	42	,	,	PUNCT
eurjchem-828	238	43	respectively	respectively	ADV
eurjchem-828	238	44	,	,	PUNCT
eurjchem-828	238	45	bond	bond	NOUN
eurjchem-828	238	46	length	length	NOUN
eurjchem-828	238	47	1.778	1.778	NUM
eurjchem-828	238	48	å	å	NOUN
eurjchem-828	238	49	)	)	PUNCT
eurjchem-828	238	50	in	in	ADP
eurjchem-828	238	51	line	line	NOUN
eurjchem-828	238	52	with	with	ADP
eurjchem-828	238	53	mass	mass	PROPN
eurjchem-828	238	54	spectra	spectra	PROPN
eurjchem-828	238	55	.	.	PROPN
eurjchem-828	238	56	table	table	PROPN
eurjchem-828	238	57	10	10	NUM
eurjchem-828	238	58	.	.	PUNCT
eurjchem-828	239	1	mass	mass	ADJ
eurjchem-828	239	2	spectra	spectra	ADJ
eurjchem-828	239	3	fragments	fragment	NOUN
eurjchem-828	239	4	for	for	ADP
eurjchem-828	239	5	11a	11a	NOUN
eurjchem-828	239	6	.	.	PUNCT
eurjchem-828	240	1	m	m	PUNCT
eurjchem-828	240	2	/	/	SYM
eurjchem-828	240	3	e	e	PROPN
eurjchem-828	240	4	i	i	PROPN
eurjchem-828	240	5	/	/	SYM
eurjchem-828	240	6	imax	imax	PROPN
eurjchem-828	240	7	ions	ion	NOUN
eurjchem-828	240	8	303	303	NUM
eurjchem-828	240	9	0.55	0.55	NUM
eurjchem-828	240	10	[	[	X
eurjchem-828	240	11	m+2]+	m+2]+	NUM
eurjchem-828	240	12	302	302	NUM
eurjchem-828	240	13	1.90	1.90	NUM
eurjchem-828	240	14	[	[	PUNCT
eurjchem-828	240	15	m+1]+	m+1]+	NUM
eurjchem-828	240	16	301	301	NUM
eurjchem-828	240	17	15.47	15.47	NUM
eurjchem-828	240	18	m+	m+	NUM
eurjchem-828	240	19	242	242	NUM
eurjchem-828	240	20	2.55	2.55	NUM
eurjchem-828	241	1	[	[	X
eurjchem-828	241	2	(	(	PUNCT
eurjchem-828	241	3	ch2o)2psnc6h5co]+	ch2o)2psnc6h5co]+	NOUN
eurjchem-828	241	4	215	215	NUM
eurjchem-828	241	5	19.25	19.25	NUM
eurjchem-828	241	6	[	[	X
eurjchem-828	241	7	(	(	PUNCT
eurjchem-828	241	8	ch2o)2psnhc6h5]+	ch2o)2psnhc6h5]+	PROPN
eurjchem-828	241	9	214	214	NUM
eurjchem-828	241	10	1.82	1.82	NUM
eurjchem-828	241	11	[	[	X
eurjchem-828	241	12	(	(	PUNCT
eurjchem-828	241	13	ch2o)2psnc6h5]+	ch2o)2psnc6h5]+	PROPN
eurjchem-828	241	14	199	199	NUM
eurjchem-828	241	15	6.58	6.58	NUM
eurjchem-828	242	1	[	[	X
eurjchem-828	242	2	hopsnc6h5co]+	hopsnc6h5co]+	NUM
eurjchem-828	242	3	183	183	NUM
eurjchem-828	242	4	2.38	2.38	NUM
eurjchem-828	242	5	[	[	X
eurjchem-828	242	6	hpsnc6h5co]+	hpsnc6h5co]+	NUM
eurjchem-828	242	7	182	182	NUM
eurjchem-828	242	8	5.25	5.25	NUM
eurjchem-828	242	9	[	[	X
eurjchem-828	242	10	psnc6h5co]+	psnc6h5co]+	NUM
eurjchem-828	242	11	172	172	NUM
eurjchem-828	242	12	6.39	6.39	NUM
eurjchem-828	242	13	[	[	X
eurjchem-828	242	14	hopsnhc6h5]+	hopsnhc6h5]+	X
eurjchem-828	242	15	171	171	NUM
eurjchem-828	242	16	8.02	8.02	NUM
eurjchem-828	242	17	[	[	X
eurjchem-828	242	18	hopsnc6h5]+	hopsnc6h5]+	X
eurjchem-828	242	19	170	170	NUM
eurjchem-828	242	20	3.54	3.54	NUM
eurjchem-828	243	1	[	[	X
eurjchem-828	243	2	opsnc6h5]+	opsnc6h5]+	NUM
eurjchem-828	243	3	155	155	NUM
eurjchem-828	243	4	8.0	8.0	NUM
eurjchem-828	244	1	[	[	X
eurjchem-828	244	2	psnhc6h5]+	psnhc6h5]+	PROPN
eurjchem-828	244	3	154	154	NUM
eurjchem-828	244	4	2.59	2.59	NUM
eurjchem-828	244	5	[	[	X
eurjchem-828	244	6	psnc6h5]+	psnc6h5]+	NUM
eurjchem-828	244	7	141	141	NUM
eurjchem-828	244	8	12.43	12.43	NUM
eurjchem-828	245	1	[	[	X
eurjchem-828	245	2	(	(	PUNCT
eurjchem-828	245	3	ch2o)2pshnh]+	ch2o)2pshnh]+	NOUN
eurjchem-828	245	4	140	140	NUM
eurjchem-828	245	5	16.1	16.1	NUM
eurjchem-828	245	6	[	[	X
eurjchem-828	245	7	(	(	PUNCT
eurjchem-828	245	8	ch2o)2psoh]+	ch2o)2psoh]+	PROPN
eurjchem-828	245	9	138	138	NUM
eurjchem-828	245	10	2.59	2.59	NUM
eurjchem-828	245	11	[	[	X
eurjchem-828	245	12	(	(	PUNCT
eurjchem-828	245	13	ch2o)2psnh]+	ch2o)2psnh]+	NOUN
eurjchem-828	245	14	124	124	NUM
eurjchem-828	245	15	1.88	1.88	NUM
eurjchem-828	245	16	[	[	X
eurjchem-828	245	17	(	(	PUNCT
eurjchem-828	245	18	ch2o)2psh]+	ch2o)2psh]+	NOUN
eurjchem-828	245	19	123	123	NUM
eurjchem-828	245	20	15.24	15.24	NUM
eurjchem-828	245	21	[	[	X
eurjchem-828	245	22	(	(	PUNCT
eurjchem-828	245	23	ch2o)2ps]+	ch2o)2ps]+	NOUN
eurjchem-828	245	24	119	119	NUM
eurjchem-828	245	25	100	100	NUM
eurjchem-828	245	26	[	[	X
eurjchem-828	245	27	c6h5nco]+	c6h5nco]+	NUM
eurjchem-828	245	28	91	91	NUM
eurjchem-828	245	29	19.43	19.43	NUM
eurjchem-828	245	30	[	[	X
eurjchem-828	245	31	c6h5n]+	c6h5n]+	PROPN
eurjchem-828	245	32	77	77	NUM
eurjchem-828	245	33	3.1	3.1	NUM
eurjchem-828	245	34	[	[	X
eurjchem-828	245	35	c6h5]+	c6h5]+	X
eurjchem-828	245	36	43	43	NUM
eurjchem-828	245	37	49.11	49.11	NUM
eurjchem-828	245	38	[	[	X
eurjchem-828	245	39	c3h7]+	c3h7]+	VERB
eurjchem-828	245	40	reactivity	reactivity	NOUN
eurjchem-828	245	41	of	of	ADP
eurjchem-828	245	42	carbamates	carbamate	NOUN
eurjchem-828	245	43	was	be	AUX
eurjchem-828	245	44	also	also	ADV
eurjchem-828	245	45	tested	test	VERB
eurjchem-828	245	46	in	in	ADP
eurjchem-828	245	47	the	the	DET
eurjchem-828	245	48	reaction	reaction	NOUN
eurjchem-828	245	49	with	with	ADP
eurjchem-828	245	50	acetylchloride	acetylchloride	ADV
eurjchem-828	245	51	,	,	PUNCT
eurjchem-828	245	52	which	which	PRON
eurjchem-828	245	53	was	be	AUX
eurjchem-828	245	54	taken	take	VERB
eurjchem-828	245	55	in	in	ADP
eurjchem-828	245	56	access	access	NOUN
eurjchem-828	245	57	(	(	PUNCT
eurjchem-828	245	58	scheme	scheme	NOUN
eurjchem-828	245	59	6	6	NUM
eurjchem-828	245	60	)	)	PUNCT
eurjchem-828	245	61	.	.	PUNCT
eurjchem-828	246	1	thin	thin	ADJ
eurjchem-828	246	2	layer	layer	NOUN
eurjchem-828	246	3	chromatography	chromatography	NOUN
eurjchem-828	246	4	,	,	PUNCT
eurjchem-828	246	5	ir	ir	PROPN
eurjchem-828	246	6	,	,	PUNCT
eurjchem-828	246	7	mass	mass	ADJ
eurjchem-828	246	8	and	and	CCONJ
eurjchem-828	246	9	nmr	nmr	NOUN
eurjchem-828	246	10	spectra	spectra	NOUN
eurjchem-828	246	11	were	be	AUX
eurjchem-828	246	12	used	use	VERB
eurjchem-828	246	13	to	to	PART
eurjchem-828	246	14	identify	identify	VERB
eurjchem-828	246	15	the	the	DET
eurjchem-828	246	16	purity	purity	NOUN
eurjchem-828	246	17	and	and	CCONJ
eurjchem-828	246	18	structure	structure	NOUN
eurjchem-828	246	19	of	of	ADP
eurjchem-828	246	20	these	these	PRON
eurjchem-828	246	21	not	not	PART
eurjchem-828	246	22	previously	previously	ADV
eurjchem-828	246	23	reported	report	VERB
eurjchem-828	246	24	compounds	compound	NOUN
eurjchem-828	246	25	.	.	PUNCT
eurjchem-828	247	1	in	in	ADP
eurjchem-828	247	2	the	the	DET
eurjchem-828	247	3	ir	ir	PROPN
eurjchem-828	247	4	spectra	spectra	NOUN
eurjchem-828	247	5	there	there	PRON
eurjchem-828	247	6	are	be	VERB
eurjchem-828	247	7	peaks	peak	NOUN
eurjchem-828	247	8	corresponding	correspond	VERB
eurjchem-828	247	9	to	to	ADP
eurjchem-828	247	10	c	c	NOUN
eurjchem-828	247	11	=	=	NOUN
eurjchem-828	247	12	o	o	NOUN
eurjchem-828	247	13	group	group	NOUN
eurjchem-828	247	14	for	for	ADP
eurjchem-828	247	15	compound	compound	NOUN
eurjchem-828	247	16	12a	12a	NOUN
eurjchem-828	247	17	and	and	CCONJ
eurjchem-828	247	18	12c	12c	NUM
eurjchem-828	247	19	(	(	PUNCT
eurjchem-828	247	20	1700‐1760	1700‐1760	NUM
eurjchem-828	247	21	cm‐1	cm‐1	NOUN
eurjchem-828	247	22	)	)	PUNCT
eurjchem-828	247	23	,	,	PUNCT
eurjchem-828	247	24	12d	12d	NUM
eurjchem-828	247	25	and	and	CCONJ
eurjchem-828	247	26	12e	12e	NOUN
eurjchem-828	247	27	(	(	PUNCT
eurjchem-828	247	28	1730‐1760	1730‐1760	NUM
eurjchem-828	247	29	cm‐1	cm‐1	NOUN
eurjchem-828	247	30	)	)	PUNCT
eurjchem-828	247	31	as	as	ADV
eurjchem-828	247	32	well	well	ADV
eurjchem-828	247	33	as	as	ADP
eurjchem-828	247	34	p	p	PROPN
eurjchem-828	247	35	=	=	PROPN
eurjchem-828	247	36	o	o	PROPN
eurjchem-828	247	37	group	group	NOUN
eurjchem-828	247	38	(	(	PUNCT
eurjchem-828	247	39	1210‐1300	1210‐1300	NUM
eurjchem-828	247	40	cm‐1	cm‐1	NOUN
eurjchem-828	247	41	)	)	PUNCT
eurjchem-828	247	42	and	and	CCONJ
eurjchem-828	247	43	the	the	DET
eurjchem-828	247	44	phenyl	phenyl	NOUN
eurjchem-828	247	45	ring	ring	NOUN
eurjchem-828	247	46	(	(	PUNCT
eurjchem-828	247	47	1490‐1600	1490‐1600	NUM
eurjchem-828	247	48	cm‐1	cm‐1	NOUN
eurjchem-828	247	49	)	)	PUNCT
eurjchem-828	247	50	for	for	ADP
eurjchem-828	247	51	compounds	compound	NOUN
eurjchem-828	247	52	12b‐12f	12b‐12f	NUM
eurjchem-828	247	53	.	.	PUNCT
eurjchem-828	248	1	intensity	intensity	NOUN
eurjchem-828	248	2	of	of	ADP
eurjchem-828	248	3	molecular	molecular	ADJ
eurjchem-828	248	4	ions	ion	NOUN
eurjchem-828	248	5	m+	m+	NUM
eurjchem-828	248	6	and	and	CCONJ
eurjchem-828	248	7	[	[	PUNCT
eurjchem-828	248	8	m+2]+	m+2]+	PUNCT
eurjchem-828	248	9	was	be	AUX
eurjchem-828	248	10	as	as	ADV
eurjchem-828	248	11	high	high	ADJ
eurjchem-828	248	12	as	as	ADP
eurjchem-828	248	13	61.88	61.88	NUM
eurjchem-828	248	14	%	%	NOUN
eurjchem-828	248	15	for	for	ADP
eurjchem-828	248	16	compound	compound	NOUN
eurjchem-828	248	17	12f	12f	NUM
eurjchem-828	248	18	,	,	PUNCT
eurjchem-828	248	19	while	while	SCONJ
eurjchem-828	248	20	it	it	PRON
eurjchem-828	248	21	was	be	AUX
eurjchem-828	248	22	only	only	ADV
eurjchem-828	248	23	5.72	5.72	NUM
eurjchem-828	248	24	%	%	NOUN
eurjchem-828	248	25	for	for	ADP
eurjchem-828	248	26	compound	compound	NOUN
eurjchem-828	248	27	12b	12b	NOUN
eurjchem-828	248	28	and	and	CCONJ
eurjchem-828	248	29	4.24	4.24	NUM
eurjchem-828	248	30	%	%	NOUN
eurjchem-828	248	31	for	for	ADP
eurjchem-828	248	32	compound	compound	NOUN
eurjchem-828	248	33	12c	12c	NUM
eurjchem-828	248	34	.	.	PUNCT
eurjchem-828	249	1	among	among	ADP
eurjchem-828	249	2	other	other	ADJ
eurjchem-828	249	3	ions	ion	NOUN
eurjchem-828	249	4	in	in	ADP
eurjchem-828	249	5	the	the	DET
eurjchem-828	249	6	mass	mass	NOUN
eurjchem-828	249	7	spectrum	spectrum	NOUN
eurjchem-828	249	8	of	of	ADP
eurjchem-828	249	9	compound	compound	NOUN
eurjchem-828	249	10	12f	12f	NUM
eurjchem-828	249	11	the	the	DET
eurjchem-828	249	12	following	follow	VERB
eurjchem-828	249	13	ones	one	NOUN
eurjchem-828	249	14	should	should	AUX
eurjchem-828	249	15	be	be	AUX
eurjchem-828	249	16	mentioned	mention	VERB
eurjchem-828	249	17	corresponding	correspond	VERB
eurjchem-828	249	18	to	to	ADP
eurjchem-828	249	19	the	the	DET
eurjchem-828	249	20	removal	removal	NOUN
eurjchem-828	249	21	of	of	ADP
eurjchem-828	249	22	cl	cl	NOUN
eurjchem-828	250	1	[	[	X
eurjchem-828	250	2	m‐	m‐	X
eurjchem-828	250	3	cl]+	cl]+	NOUN
eurjchem-828	250	4	,	,	PUNCT
eurjchem-828	250	5	(	(	PUNCT
eurjchem-828	250	6	m	m	NOUN
eurjchem-828	250	7	/	/	SYM
eurjchem-828	250	8	e	e	NOUN
eurjchem-828	250	9	314	314	NUM
eurjchem-828	250	10	,	,	PUNCT
eurjchem-828	250	11	1.38	1.38	NUM
eurjchem-828	250	12	%	%	NOUN
eurjchem-828	250	13	)	)	PUNCT
eurjchem-828	250	14	,	,	PUNCT
eurjchem-828	250	15	methoxycarbonyl	methoxycarbonyl	PROPN
eurjchem-828	250	16	group	group	NOUN
eurjchem-828	250	17	[	[	X
eurjchem-828	250	18	m‐ch3oc(o)]+	m‐ch3oc(o)]+	PROPN
eurjchem-828	250	19	(	(	PUNCT
eurjchem-828	250	20	m	m	NOUN
eurjchem-828	250	21	/	/	SYM
eurjchem-828	250	22	e	e	NOUN
eurjchem-828	250	23	290	290	NUM
eurjchem-828	250	24	,	,	PUNCT
eurjchem-828	250	25	5.32	5.32	NUM
eurjchem-828	250	26	%	%	NOUN
eurjchem-828	250	27	)	)	PUNCT
eurjchem-828	250	28	,	,	PUNCT
eurjchem-828	250	29	as	as	ADV
eurjchem-828	250	30	well	well	ADV
eurjchem-828	250	31	as	as	ADP
eurjchem-828	250	32	both	both	PRON
eurjchem-828	250	33	of	of	ADP
eurjchem-828	250	34	them	they	PRON
eurjchem-828	250	35	[	[	X
eurjchem-828	250	36	m‐cl‐ch3oc(o)]+	m‐cl‐ch3oc(o)]+	PROPN
eurjchem-828	250	37	(	(	PUNCT
eurjchem-828	250	38	m	m	NOUN
eurjchem-828	250	39	/	/	SYM
eurjchem-828	250	40	e	e	NOUN
eurjchem-828	250	41	255	255	NUM
eurjchem-828	250	42	,	,	PUNCT
eurjchem-828	250	43	4.21	4.21	NUM
eurjchem-828	250	44	%	%	NOUN
eurjchem-828	250	45	)	)	PUNCT
eurjchem-828	250	46	.	.	PUNCT
eurjchem-828	251	1	4	4	X
eurjchem-828	251	2	.	.	X
eurjchem-828	251	3	conclusions	conclusion	NOUN
eurjchem-828	251	4	several	several	ADJ
eurjchem-828	251	5	intermediates	intermediate	NOUN
eurjchem-828	251	6	,	,	PUNCT
eurjchem-828	251	7	derivatives	derivative	NOUN
eurjchem-828	251	8	of	of	ADP
eurjchem-828	251	9	carbamates	carbamate	NOUN
eurjchem-828	251	10	and	and	CCONJ
eurjchem-828	251	11	cyclophosphoric	cyclophosphoric	ADJ
eurjchem-828	251	12	acids	acid	NOUN
eurjchem-828	251	13	with	with	ADP
eurjchem-828	251	14	p‐n	p‐n	NOUN
eurjchem-828	251	15	bond	bond	NOUN
eurjchem-828	251	16	and	and	CCONJ
eurjchem-828	251	17	the	the	DET
eurjchem-828	251	18	following	follow	VERB
eurjchem-828	251	19	structure	structure	NOUN
eurjchem-828	251	20	(	(	PUNCT
eurjchem-828	251	21	scheme	scheme	NOUN
eurjchem-828	251	22	7	7	NUM
eurjchem-828	251	23	)	)	PUNCT
eurjchem-828	251	24	were	be	AUX
eurjchem-828	251	25	synthesized	synthesize	VERB
eurjchem-828	251	26	from	from	ADP
eurjchem-828	251	27	(	(	PUNCT
eurjchem-828	251	28	thio)carbamates	thio)carbamate	NOUN
eurjchem-828	251	29	and	and	CCONJ
eurjchem-828	251	30	chlorodioxa‐phospholanes	chlorodioxa‐phospholane	NOUN
eurjchem-828	251	31	and	and	CCONJ
eurjchem-828	251	32	‐phosphorinanes	‐phosphorinane	NOUN
eurjchem-828	251	33	using	use	VERB
eurjchem-828	251	34	triethylamine	triethylamine	NOUN
eurjchem-828	251	35	as	as	ADP
eurjchem-828	251	36	hcl	hcl	PROPN
eurjchem-828	251	37	acceptor	acceptor	NOUN
eurjchem-828	251	38	.	.	PUNCT
eurjchem-828	252	1	these	these	DET
eurjchem-828	252	2	compounds	compound	NOUN
eurjchem-828	252	3	were	be	AUX
eurjchem-828	252	4	identified	identify	VERB
eurjchem-828	252	5	using	use	VERB
eurjchem-828	252	6	ir	ir	PROPN
eurjchem-828	252	7	,	,	PUNCT
eurjchem-828	252	8	mass	mass	ADJ
eurjchem-828	252	9	spectroscopy	spectroscopy	NOUN
eurjchem-828	252	10	and	and	CCONJ
eurjchem-828	252	11	31p	31p	NUM
eurjchem-828	252	12	nmr	nmr	NOUN
eurjchem-828	252	13	.	.	PUNCT
eurjchem-828	253	1	n	n	NOUN
eurjchem-828	253	2	=	=	SYM
eurjchem-828	253	3	2	2	NUM
eurjchem-828	253	4	,	,	PUNCT
eurjchem-828	253	5	3	3	NUM
eurjchem-828	253	6	r	r	NOUN
eurjchem-828	253	7	=	=	SYM
eurjchem-828	253	8	h	h	NOUN
eurjchem-828	253	9	,	,	PUNCT
eurjchem-828	253	10	‐ch3	‐ch3	ADJ
eurjchem-828	253	11	,	,	PUNCT
eurjchem-828	253	12	‐ch2‐ch	‐ch2‐ch	NOUN
eurjchem-828	253	13	=	=	SYM
eurjchem-828	253	14	ch2	ch2	X
eurjchem-828	253	15	,	,	PUNCT
eurjchem-828	253	16	c6h5	c6h5	PROPN
eurjchem-828	253	17	,	,	PUNCT
eurjchem-828	253	18	c6h4cl	c6h4cl	PROPN
eurjchem-828	253	19	r1	r1	PROPN
eurjchem-828	253	20	=	=	SYM
eurjchem-828	253	21	ch3	ch3	PROPN
eurjchem-828	253	22	,	,	PUNCT
eurjchem-828	253	23	c2h5	c2h5	PROPN
eurjchem-828	253	24	,	,	PUNCT
eurjchem-828	253	25	i‐c3h7	i‐c3h7	NOUN
eurjchem-828	253	26	,	,	PUNCT
eurjchem-828	253	27	c4h9	c4h9	NOUN
eurjchem-828	253	28	scheme	scheme	VERB
eurjchem-828	253	29	7	7	NUM
eurjchem-828	253	30	the	the	DET
eurjchem-828	253	31	reactivity	reactivity	NOUN
eurjchem-828	253	32	of	of	ADP
eurjchem-828	253	33	phosphorylated	phosphorylate	VERB
eurjchem-828	253	34	carbamates	carbamate	NOUN
eurjchem-828	253	35	was	be	AUX
eurjchem-828	253	36	investigated	investigate	VERB
eurjchem-828	253	37	in	in	ADP
eurjchem-828	253	38	the	the	DET
eurjchem-828	253	39	sulphur	sulphur	NOUN
eurjchem-828	253	40	addition	addition	NOUN
eurjchem-828	253	41	reaction	reaction	NOUN
eurjchem-828	253	42	giving	give	VERB
eurjchem-828	253	43	the	the	DET
eurjchem-828	253	44	following	follow	VERB
eurjchem-828	253	45	previously	previously	ADV
eurjchem-828	253	46	not	not	PART
eurjchem-828	253	47	reported	report	VERB
eurjchem-828	253	48	o‐alkyl	o‐alkyl	PUNCT
eurjchem-828	253	49	phenyl‐2‐sulfido‐	phenyl‐2‐sulfido‐	ADJ
eurjchem-828	253	50	1,3,2‐dioxaphospholan	1,3,2‐dioxaphospholan	NUM
eurjchem-828	253	51	(	(	PUNCT
eurjchem-828	253	52	or	or	CCONJ
eurjchem-828	253	53	dioxaphospinan)‐2‐yl)‐carbamates	dioxaphospinan)‐2‐yl)‐carbamate	NOUN
eurjchem-828	253	54	and	and	CCONJ
eurjchem-828	253	55	‐carbamothioates	‐carbamothioate	NOUN
eurjchem-828	253	56	(	(	PUNCT
eurjchem-828	253	57	scheme	scheme	NOUN
eurjchem-828	253	58	8)	8)	NUM
eurjchem-828	253	59	.	.	PUNCT
eurjchem-828	254	1	the	the	DET
eurjchem-828	254	2	structure	structure	NOUN
eurjchem-828	254	3	was	be	AUX
eurjchem-828	254	4	determined	determine	VERB
eurjchem-828	254	5	by	by	ADP
eurjchem-828	254	6	ir	ir	PROPN
eurjchem-828	254	7	,	,	PUNCT
eurjchem-828	254	8	mass	mass	ADJ
eurjchem-828	254	9	spectroscopy	spectroscopy	NOUN
eurjchem-828	254	10	and	and	CCONJ
eurjchem-828	254	11	31p	31p	NUM
eurjchem-828	254	12	nmr	nmr	NOUN
eurjchem-828	254	13	.	.	PUNCT
eurjchem-828	255	1	n	n	NOUN
eurjchem-828	255	2	=	=	SYM
eurjchem-828	255	3	2	2	NUM
eurjchem-828	255	4	,	,	PUNCT
eurjchem-828	255	5	3	3	NUM
eurjchem-828	255	6	x	x	SYM
eurjchem-828	255	7	=	=	SYM
eurjchem-828	255	8	o	o	NOUN
eurjchem-828	255	9	,	,	PUNCT
eurjchem-828	255	10	s	s	PART
eurjchem-828	255	11	r	r	NOUN
eurjchem-828	255	12	=	=	PUNCT
eurjchem-828	255	13	c6h5	c6h5	PROPN
eurjchem-828	255	14	,	,	PUNCT
eurjchem-828	255	15	c6h4cl	c6h4cl	PROPN
eurjchem-828	255	16	,	,	PUNCT
eurjchem-828	255	17	r1	r1	PROPN
eurjchem-828	255	18	=	=	SYM
eurjchem-828	255	19	ch3	ch3	PROPN
eurjchem-828	255	20	,	,	PUNCT
eurjchem-828	255	21	i‐c3h7	i‐c3h7	AUX
eurjchem-828	255	22	scheme	scheme	NOUN
eurjchem-828	255	23	8	8	NUM
eurjchem-828	255	24	a	a	DET
eurjchem-828	255	25	possibility	possibility	NOUN
eurjchem-828	255	26	to	to	PART
eurjchem-828	255	27	synthesize	synthesize	VERB
eurjchem-828	255	28	for	for	ADP
eurjchem-828	255	29	the	the	DET
eurjchem-828	255	30	first	first	ADJ
eurjchem-828	255	31	time	time	NOUN
eurjchem-828	255	32	alkyl	alkyl	PROPN
eurjchem-828	255	33	(	(	PUNCT
eurjchem-828	255	34	2‐	2‐	NUM
eurjchem-828	255	35	chloroethoxy	chloroethoxy	ADJ
eurjchem-828	255	36	or	or	CCONJ
eurjchem-828	255	37	propoxy)(methoxy)phosphoryl(2‐aryl	propoxy)(methoxy)phosphoryl(2‐aryl	NOUN
eurjchem-828	255	38	)	)	PUNCT
eurjchem-828	255	39	carba‐	carba‐	NOUN
eurjchem-828	255	40	mates	mate	NOUN
eurjchem-828	255	41	(	(	PUNCT
eurjchem-828	255	42	or	or	CCONJ
eurjchem-828	255	43	carbamothioates	carbamothioate	NOUN
eurjchem-828	255	44	)	)	PUNCT
eurjchem-828	255	45	(	(	PUNCT
eurjchem-828	255	46	scheme	scheme	NOUN
eurjchem-828	255	47	9	9	NUM
eurjchem-828	255	48	)	)	PUNCT
eurjchem-828	255	49	through	through	ADP
eurjchem-828	255	50	an	an	DET
eurjchem-828	255	51	arbuzov	arbuzov	NOUN
eurjchem-828	255	52	type	type	NOUN
eurjchem-828	255	53	rearrangement	rearrangement	NOUN
eurjchem-828	255	54	was	be	AUX
eurjchem-828	255	55	demonstrated	demonstrate	VERB
eurjchem-828	255	56	by	by	ADP
eurjchem-828	255	57	reacting	react	VERB
eurjchem-828	255	58	corresponding	correspond	VERB
eurjchem-828	255	59	intermediates	intermediate	NOUN
eurjchem-828	255	60	containing	contain	VERB
eurjchem-828	255	61	p‐n	p‐n	NOUN
eurjchem-828	255	62	bonds	bond	NOUN
eurjchem-828	255	63	and	and	CCONJ
eurjchem-828	255	64	methyl	methyl	NOUN
eurjchem-828	255	65	formate	formate	NOUN
eurjchem-828	255	66	.	.	PUNCT
eurjchem-828	256	1	n	n	NOUN
eurjchem-828	256	2	=	=	SYM
eurjchem-828	256	3	2	2	NUM
eurjchem-828	256	4	,	,	PUNCT
eurjchem-828	256	5	3	3	NUM
eurjchem-828	256	6	x	x	SYM
eurjchem-828	256	7	=	=	SYM
eurjchem-828	256	8	o	o	NOUN
eurjchem-828	256	9	,	,	PUNCT
eurjchem-828	256	10	s	s	NOUN
eurjchem-828	256	11	r	r	NOUN
eurjchem-828	256	12	=	=	SYM
eurjchem-828	256	13	h	h	NOUN
eurjchem-828	256	14	,	,	PUNCT
eurjchem-828	256	15	c6h5	c6h5	PROPN
eurjchem-828	256	16	,	,	PUNCT
eurjchem-828	256	17	c6h4cl	c6h4cl	PROPN
eurjchem-828	256	18	r1	r1	PROPN
eurjchem-828	256	19	=	=	SYM
eurjchem-828	256	20	ch3	ch3	PROPN
eurjchem-828	256	21	,	,	PUNCT
eurjchem-828	256	22	i‐c3h7	i‐c3h7	NOUN
eurjchem-828	256	23	scheme	scheme	NOUN
eurjchem-828	256	24	9	9	NUM
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eurjchem-828	256	26	analysis	analysis	NOUN
eurjchem-828	256	27	of	of	ADP
eurjchem-828	256	28	mass	mass	ADJ
eurjchem-828	256	29	spectra	spectra	NOUN
eurjchem-828	256	30	of	of	ADP
eurjchem-828	256	31	the	the	DET
eurjchem-828	256	32	intermediates	intermediate	NOUN
eurjchem-828	256	33	and	and	CCONJ
eurjchem-828	256	34	the	the	DET
eurjchem-828	256	35	products	product	NOUN
eurjchem-828	256	36	was	be	AUX
eurjchem-828	256	37	performed	perform	VERB
eurjchem-828	256	38	and	and	CCONJ
eurjchem-828	256	39	the	the	DET
eurjchem-828	256	40	main	main	ADJ
eurjchem-828	256	41	fragmentations	fragmentation	NOUN
eurjchem-828	256	42	pathways	pathway	NOUN
eurjchem-828	256	43	in	in	ADP
eurjchem-828	256	44	mass	mass	ADJ
eurjchem-828	256	45	spectra	spectra	NOUN
eurjchem-828	256	46	were	be	AUX
eurjchem-828	256	47	discussed	discuss	VERB
eurjchem-828	256	48	.	.	PUNCT
eurjchem-828	257	1	acknowledgement	acknowledgement	PROPN
eurjchem-828	257	2	technical	technical	ADJ
eurjchem-828	257	3	help	help	NOUN
eurjchem-828	257	4	and	and	CCONJ
eurjchem-828	257	5	assistance	assistance	NOUN
eurjchem-828	257	6	of	of	ADP
eurjchem-828	257	7	prof	prof	PROPN
eurjchem-828	257	8	.	.	PUNCT
eurjchem-828	258	1	reko	reko	PROPN
eurjchem-828	258	2	leino	leino	PROPN
eurjchem-828	258	3	during	during	ADP
eurjchem-828	258	4	preparation	preparation	NOUN
eurjchem-828	258	5	of	of	ADP
eurjchem-828	258	6	the	the	DET
eurjchem-828	258	7	manuscript	manuscript	NOUN
eurjchem-828	258	8	are	be	AUX
eurjchem-828	258	9	highly	highly	ADV
eurjchem-828	258	10	appreciated	appreciated	ADJ
eurjchem-828	258	11	.	.	PUNCT
eurjchem-828	259	1	references	reference	NOUN
eurjchem-828	259	2	[	[	X
eurjchem-828	259	3	1	1	NUM
eurjchem-828	259	4	]	]	PUNCT
eurjchem-828	259	5	.	.	PUNCT
eurjchem-828	260	1	fahmy	fahmy	PROPN
eurjchem-828	260	2	,	,	PUNCT
eurjchem-828	260	3	m.	m.	NOUN
eurjchem-828	260	4	a.	a.	NOUN
eurjchem-828	260	5	;	;	PUNCT
eurjchem-828	260	6	fukuto	fukuto	ADJ
eurjchem-828	260	7	,	,	PUNCT
eurjchem-828	260	8	t.	t.	PROPN
eurjchem-828	260	9	r.	r.	PROPN
eurjchem-828	260	10	;	;	PUNCT
eurjchem-828	260	11	myers	myers	PROPN
eurjchem-828	260	12	,	,	PUNCT
eurjchem-828	260	13	r.	r.	PROPN
eurjchem-828	260	14	o.	o.	PROPN
eurjchem-828	260	15	;	;	PUNCT
eurjchem-828	260	16	march	march	PROPN
eurjchem-828	260	17	,	,	PUNCT
eurjchem-828	260	18	r.	r.	PROPN
eurjchem-828	260	19	b.	b.	PROPN
eurjchem-828	260	20	j.	j.	PROPN
eurjchem-828	260	21	agr	agr	PROPN
eurjchem-828	260	22	.	.	PUNCT
eurjchem-828	260	23	food	food	NOUN
eurjchem-828	260	24	chem	chem	NOUN
eurjchem-828	260	25	.	.	PUNCT
eurjchem-828	261	1	1970	1970	NUM
eurjchem-828	261	2	,	,	PUNCT
eurjchem-828	261	3	18	18	NUM
eurjchem-828	261	4	,	,	PUNCT
eurjchem-828	261	5	793‐796	793‐796	NUM
eurjchem-828	261	6	.	.	PUNCT
eurjchem-828	262	1	[	[	X
eurjchem-828	262	2	2	2	NUM
eurjchem-828	262	3	]	]	PUNCT
eurjchem-828	262	4	.	.	PUNCT
eurjchem-828	263	1	derkach	derkach	PROPN
eurjchem-828	263	2	,	,	PUNCT
eurjchem-828	263	3	g.	g.	PROPN
eurjchem-828	263	4	i.	i.	PROPN
eurjchem-828	263	5	;	;	PUNCT
eurjchem-828	263	6	samarai	samarai	PROPN
eurjchem-828	263	7	,	,	PUNCT
eurjchem-828	263	8	l.	l.	PROPN
eurjchem-828	263	9	i.	i.	PROPN
eurjchem-828	263	10	;	;	PUNCT
eurjchem-828	263	11	kirsanov	kirsanov	PROPN
eurjchem-828	263	12	,	,	PUNCT
eurjchem-828	263	13	a.	a.	PROPN
eurjchem-828	263	14	v.	v.	PROPN
eurjchem-828	263	15	russ	russ	PROPN
eurjchem-828	263	16	.	.	PUNCT
eurjchem-828	264	1	j.	j.	PROPN
eurjchem-828	264	2	gen	gen	PROPN
eurjchem-828	264	3	.	.	PROPN
eurjchem-828	264	4	chem	chem	PROPN
eurjchem-828	264	5	.	.	PUNCT
eurjchem-828	265	1	1962	1962	NUM
eurjchem-828	265	2	,	,	PUNCT
eurjchem-828	265	3	32	32	NUM
eurjchem-828	265	4	,	,	PUNCT
eurjchem-828	265	5	3761‐3764	3761‐3764	NUM
eurjchem-828	265	6	.	.	PUNCT
eurjchem-828	266	1	[	[	X
eurjchem-828	266	2	3	3	NUM
eurjchem-828	266	3	]	]	PUNCT
eurjchem-828	266	4	.	.	PUNCT
eurjchem-828	267	1	ivanova	ivanova	PROPN
eurjchem-828	267	2	,	,	PUNCT
eurjchem-828	267	3	z.	z.	PROPN
eurjchem-828	267	4	m.	m.	PROPN
eurjchem-828	267	5	;	;	PUNCT
eurjchem-828	267	6	stukalo	stukalo	NOUN
eurjchem-828	267	7	,	,	PUNCT
eurjchem-828	267	8	e.	e.	PROPN
eurjchem-828	267	9	n.	n.	PROPN
eurjchem-828	267	10	;	;	PUNCT
eurjchem-828	267	11	tishchishina	tishchishina	PROPN
eurjchem-828	267	12	,	,	PUNCT
eurjchem-828	267	13	a.	a.	PROPN
eurjchem-828	267	14	s.	s.	PROPN
eurjchem-828	267	15	;	;	PUNCT
eurjchem-828	267	16	derkach	derkach	PROPN
eurjchem-828	267	17	,	,	PUNCT
eurjchem-828	267	18	g.	g.	PROPN
eurjchem-828	267	19	i.	i.	PROPN
eurjchem-828	267	20	russ	russ	PROPN
eurjchem-828	267	21	.	.	PUNCT
eurjchem-828	268	1	j.	j.	PROPN
eurjchem-828	268	2	gen	gen	PROPN
eurjchem-828	268	3	.	.	PROPN
eurjchem-828	268	4	chem	chem	PROPN
eurjchem-828	268	5	.	.	PUNCT
eurjchem-828	269	1	1970	1970	NUM
eurjchem-828	269	2	,	,	PUNCT
eurjchem-828	269	3	40	40	NUM
eurjchem-828	269	4	,	,	PUNCT
eurjchem-828	269	5	1942‐1948	1942‐1948	NUM
eurjchem-828	269	6	.	.	PUNCT
eurjchem-828	270	1	[	[	X
eurjchem-828	270	2	4	4	NUM
eurjchem-828	270	3	]	]	PUNCT
eurjchem-828	270	4	.	.	PUNCT
eurjchem-828	271	1	pudovik	pudovik	PROPN
eurjchem-828	271	2	,	,	PUNCT
eurjchem-828	271	3	m.	m.	NOUN
eurjchem-828	271	4	a.	a.	PROPN
eurjchem-828	271	5	;	;	PUNCT
eurjchem-828	271	6	saakyan	saakyan	PROPN
eurjchem-828	271	7	,	,	PUNCT
eurjchem-828	271	8	g.	g.	PROPN
eurjchem-828	271	9	m.	m.	PROPN
eurjchem-828	271	10	;	;	PUNCT
eurjchem-828	271	11	khairullin	khairullin	PROPN
eurjchem-828	271	12	,	,	PUNCT
eurjchem-828	271	13	v.	v.	PROPN
eurjchem-828	271	14	n.	n.	PROPN
eurjchem-828	271	15	;	;	PUNCT
eurjchem-828	271	16	khailova	khailova	PROPN
eurjchem-828	271	17	,	,	PUNCT
eurjchem-828	271	18	n.	n.	PROPN
eurjchem-828	271	19	a.	a.	PROPN
eurjchem-828	271	20	;	;	PUNCT
eurjchem-828	271	21	pudovik	pudovik	NOUN
eurjchem-828	271	22	,	,	PUNCT
eurjchem-828	271	23	a.	a.	PROPN
eurjchem-828	271	24	n.	n.	PROPN
eurjchem-828	271	25	russ	russ	PROPN
eurjchem-828	271	26	.	.	PROPN
eurjchem-828	272	1	chem	chem	PROPN
eurjchem-828	272	2	.	.	PUNCT
eurjchem-828	273	1	bull	bull	NOUN
eurjchem-828	273	2	.	.	PUNCT
eurjchem-828	274	1	1999	1999	NUM
eurjchem-828	274	2	,	,	PUNCT
eurjchem-828	274	3	48	48	NUM
eurjchem-828	274	4	,	,	PUNCT
eurjchem-828	274	5	806‐807	806‐807	NUM
eurjchem-828	274	6	.	.	PUNCT
eurjchem-828	275	1	[	[	X
eurjchem-828	275	2	5	5	NUM
eurjchem-828	275	3	]	]	PUNCT
eurjchem-828	275	4	.	.	PUNCT
eurjchem-828	276	1	shokol	shokol	PROPN
eurjchem-828	276	2	,	,	PUNCT
eurjchem-828	276	3	v.	v.	PROPN
eurjchem-828	276	4	a.	a.	NOUN
eurjchem-828	276	5	;	;	PUNCT
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eurjchem-828	276	7	,	,	PUNCT
eurjchem-828	276	8	n.	n.	PROPN
eurjchem-828	276	9	k.	k.	PROPN
eurjchem-828	276	10	;	;	PUNCT
eurjchem-828	276	11	derkach	derkach	PROPN
eurjchem-828	276	12	,	,	PUNCT
eurjchem-828	276	13	g.	g.	PROPN
eurjchem-828	276	14	i.	i.	PROPN
eurjchem-828	276	15	russ	russ	PROPN
eurjchem-828	276	16	.	.	PUNCT
eurjchem-828	277	1	j.	j.	PROPN
eurjchem-828	277	2	gen	gen	PROPN
eurjchem-828	277	3	.	.	PROPN
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eurjchem-828	277	5	.	.	PUNCT
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eurjchem-828	278	2	,	,	PUNCT
eurjchem-828	278	3	36	36	NUM
eurjchem-828	278	4	,	,	PUNCT
eurjchem-828	278	5	1442‐1444	1442‐1444	NUM
eurjchem-828	278	6	.	.	PUNCT
eurjchem-828	279	1	[	[	X
eurjchem-828	279	2	6	6	NUM
eurjchem-828	279	3	]	]	PUNCT
eurjchem-828	279	4	.	.	PUNCT
eurjchem-828	280	1	kolesova	kolesova	PROPN
eurjchem-828	280	2	,	,	PUNCT
eurjchem-828	280	3	v.	v.	PROPN
eurjchem-828	280	4	a.	a.	NOUN
eurjchem-828	280	5	;	;	PUNCT
eurjchem-828	280	6	aleshnikova	aleshnikova	NOUN
eurjchem-828	280	7	,	,	PUNCT
eurjchem-828	280	8	t.	t.	PROPN
eurjchem-828	280	9	v.	v.	PROPN
eurjchem-828	280	10	;	;	PUNCT
eurjchem-828	280	11	strepikheev	strepikheev	PROPN
eurjchem-828	280	12	,	,	PUNCT
eurjchem-828	280	13	y.	y.	PROPN
eurjchem-828	280	14	a.	a.	PROPN
eurjchem-828	280	15	;	;	PUNCT
eurjchem-828	280	16	arbuzova	arbuzova	PROPN
eurjchem-828	280	17	,	,	PUNCT
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eurjchem-828	280	19	v.	v.	PROPN
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eurjchem-828	280	21	.	.	PUNCT
eurjchem-828	281	1	j.	j.	PROPN
eurjchem-828	281	2	gen	gen	PROPN
eurjchem-828	281	3	.	.	PROPN
eurjchem-828	281	4	chem	chem	PROPN
eurjchem-828	281	5	.	.	PUNCT
eurjchem-828	282	1	1985	1985	NUM
eurjchem-828	282	2	,	,	PUNCT
eurjchem-828	282	3	55	55	NUM
eurjchem-828	282	4	,	,	PUNCT
eurjchem-828	282	5	2037‐2039	2037‐2039	NUM
eurjchem-828	282	6	.	.	PUNCT
eurjchem-828	283	1	342	342	NUM
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eurjchem-828	283	3	and	and	CCONJ
eurjchem-828	283	4	kolesova	kolesova	PROPN
eurjchem-828	283	5	/	/	SYM
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eurjchem-828	283	7	journal	journal	PROPN
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eurjchem-828	283	11	(	(	PUNCT
eurjchem-828	283	12	4	4	NUM
eurjchem-828	283	13	)	)	PUNCT
eurjchem-828	283	14	(	(	PUNCT
eurjchem-828	283	15	2013	2013	NUM
eurjchem-828	283	16	)	)	PUNCT
eurjchem-828	283	17	336‐342	336‐342	NUM
eurjchem-828	284	1	[	[	X
eurjchem-828	284	2	7	7	NUM
eurjchem-828	284	3	]	]	PUNCT
eurjchem-828	284	4	.	.	PUNCT
eurjchem-828	284	5	conge	conge	PROPN
eurjchem-828	284	6	,	,	PUNCT
eurjchem-828	284	7	a.	a.	PROPN
eurjchem-828	284	8	;	;	PUNCT
eurjchem-828	284	9	guimaraes	guimaraes	PROPN
eurjchem-828	284	10	,	,	PUNCT
eurjchem-828	284	11	a.	a.	NOUN
eurjchem-828	284	12	g.	g.	PROPN
eurjchem-828	284	13	;	;	PUNCT
eurjchem-828	284	14	martin	martin	PROPN
eurjchem-828	284	15	,	,	PUNCT
eurjchem-828	284	16	j.	j.	PROPN
eurjchem-828	284	17	;	;	PUNCT
eurjchem-828	284	18	nardin	nardin	PROPN
eurjchem-828	284	19	,	,	PUNCT
eurjchem-828	284	20	r.	r.	PROPN
eurjchem-828	284	21	;	;	PUNCT
eurjchem-828	284	22	robert	robert	PROPN
eurjchem-828	284	23	,	,	PUNCT
eurjchem-828	284	24	j.	j.	PROPN
eurjchem-828	284	25	b.	b.	PROPN
eurjchem-828	284	26	org	org	PROPN
eurjchem-828	284	27	.	.	PUNCT
eurjchem-828	285	1	magn	magn	PROPN
eurjchem-828	285	2	.	.	PUNCT
eurjchem-828	286	1	reson	reson	PROPN
eurjchem-828	286	2	.	.	PUNCT
eurjchem-828	287	1	1974	1974	NUM
eurjchem-828	287	2	,	,	PUNCT
eurjchem-828	287	3	6	6	NUM
eurjchem-828	287	4	,	,	PUNCT
eurjchem-828	287	5	629‐635	629‐635	NOUN
eurjchem-828	287	6	.	.	PUNCT
eurjchem-828	288	1	[	[	X
eurjchem-828	288	2	8	8	NUM
eurjchem-828	288	3	]	]	PUNCT
eurjchem-828	288	4	.	.	PUNCT
eurjchem-828	289	1	dutton	dutton	PROPN
eurjchem-828	289	2	,	,	PUNCT
eurjchem-828	289	3	f.	f.	PROPN
eurjchem-828	289	4	e.	e.	PROPN
eurjchem-828	289	5	;	;	PUNCT
eurjchem-828	289	6	gemrich	gemrich	PROPN
eurjchem-828	289	7	,	,	PUNCT
eurjchem-828	289	8	e.	e.	PROPN
eurjchem-828	289	9	g.	g.	PROPN
eurjchem-828	289	10	;	;	PUNCT
eurjchem-828	289	11	lee	lee	PROPN
eurjchem-828	289	12	,	,	PUNCT
eurjchem-828	289	13	b.	b.	PROPN
eurjchem-828	289	14	l.	l.	PROPN
eurjchem-828	289	15	;	;	PUNCT
eurjchem-828	289	16	nelson	nelson	PROPN
eurjchem-828	289	17	,	,	PUNCT
eurjchem-828	289	18	s.	s.	PROPN
eurjchem-828	289	19	j.	j.	PROPN
eurjchem-828	289	20	;	;	PUNCT
eurjchem-828	289	21	parham	parham	PROPN
eurjchem-828	289	22	,	,	PUNCT
eurjchem-828	289	23	p.	p.	PROPN
eurjchem-828	289	24	h.	h.	PROPN
eurjchem-828	289	25	;	;	PUNCT
eurjchem-828	289	26	seaman	seaman	PROPN
eurjchem-828	289	27	,	,	PUNCT
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eurjchem-828	289	30	j.	j.	PROPN
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eurjchem-828	289	32	.	.	PUNCT
eurjchem-828	290	1	food	food	NOUN
eurjchem-828	290	2	chem	chem	NOUN
eurjchem-828	290	3	.	.	PUNCT
eurjchem-828	291	1	1981	1981	NUM
eurjchem-828	291	2	,	,	PUNCT
eurjchem-828	291	3	29	29	NUM
eurjchem-828	291	4	,	,	PUNCT
eurjchem-828	291	5	1114‐1118	1114‐1118	NUM
eurjchem-828	291	6	.	.	PUNCT
eurjchem-828	292	1	[	[	X
eurjchem-828	292	2	9	9	NUM
eurjchem-828	292	3	]	]	PUNCT
eurjchem-828	292	4	.	.	PUNCT
eurjchem-828	293	1	browne	browne	PROPN
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eurjchem-828	293	3	j.	j.	PROPN
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eurjchem-828	293	5	;	;	PUNCT
eurjchem-828	293	6	driver	driver	NOUN
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eurjchem-828	293	10	;	;	PUNCT
eurjchem-828	293	11	russel	russel	PROPN
eurjchem-828	293	12	,	,	PUNCT
eurjchem-828	293	13	j.	j.	PROPN
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eurjchem-828	293	17	,	,	PUNCT
eurjchem-828	293	18	p.	p.	NOUN
eurjchem-828	293	19	g.	g.	PROPN
eurjchem-828	293	20	j.	j.	PROPN
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eurjchem-828	293	22	.	.	PUNCT
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eurjchem-828	294	2	.	.	PUNCT
eurjchem-828	295	1	perkin	perkin	PROPN
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eurjchem-828	295	3	.	.	PUNCT
eurjchem-828	296	1	i	i	PRON
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eurjchem-828	296	3	,	,	PUNCT
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eurjchem-828	296	5	.	.	PUNCT
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eurjchem-828	297	2	10	10	NUM
eurjchem-828	297	3	]	]	PUNCT
eurjchem-828	297	4	.	.	PUNCT
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eurjchem-828	298	4	boogers	booger	NOUN
eurjchem-828	298	5	,	,	PUNCT
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eurjchem-828	298	7	a.	a.	PROPN
eurjchem-828	298	8	f.	f.	PROPN
eurjchem-828	298	9	;	;	PUNCT
eurjchem-828	298	10	vries	vries	PROPN
eurjchem-828	298	11	,	,	PUNCT
eurjchem-828	298	12	a.	a.	PROPN
eurjchem-828	298	13	h.	h.	PROPN
eurjchem-828	298	14	m.	m.	PROPN
eurjchem-828	298	15	;	;	PUNCT
eurjchem-828	298	16	vries	vries	PROPN
eurjchem-828	298	17	,	,	PUNCT
eurjchem-828	298	18	j.	j.	PROPN
eurjchem-828	298	19	g.	g.	PROPN
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eurjchem-828	298	21	.	.	PUNCT
eurjchem-828	299	1	lett	lett	PROPN
eurjchem-828	299	2	.	.	PUNCT
eurjchem-828	300	1	2004	2004	NUM
eurjchem-828	300	2	,	,	PUNCT
eurjchem-828	300	3	6	6	NUM
eurjchem-828	300	4	,	,	PUNCT
eurjchem-828	300	5	1733‐1735	1733‐1735	NUM
eurjchem-828	300	6	.	.	PUNCT
eurjchem-828	301	1	[	[	X
eurjchem-828	301	2	11	11	NUM
eurjchem-828	301	3	]	]	PUNCT
eurjchem-828	301	4	.	.	PUNCT
eurjchem-828	302	1	lefort	lefort	PROPN
eurjchem-828	302	2	l.	l.	PROPN
eurjchem-828	302	3	;	;	PUNCT
eurjchem-828	302	4	boogers	booger	NOUN
eurjchem-828	302	5	,	,	PUNCT
eurjchem-828	302	6	j.	j.	PROPN
eurjchem-828	302	7	a.	a.	PROPN
eurjchem-828	302	8	f.	f.	PROPN
eurjchem-828	302	9	;	;	PUNCT
eurjchem-828	302	10	vries	vries	PROPN
eurjchem-828	302	11	,	,	PUNCT
eurjchem-828	302	12	j.	j.	PROPN
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eurjchem-828	302	14	;	;	PUNCT
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eurjchem-828	302	16	,	,	PUNCT
eurjchem-828	302	17	a.	a.	PROPN
eurjchem-828	302	18	h.	h.	PROPN
eurjchem-828	302	19	m.	m.	PROPN
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eurjchem-828	302	21	.	.	PUNCT
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eurjchem-828	303	2	.	.	PUNCT
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eurjchem-828	304	2	,	,	PUNCT
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eurjchem-828	304	4	,	,	PUNCT
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eurjchem-828	304	6	.	.	PUNCT
eurjchem-828	305	1	[	[	X
eurjchem-828	305	2	12	12	NUM
eurjchem-828	305	3	]	]	PUNCT
eurjchem-828	305	4	.	.	PUNCT
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eurjchem-828	306	2	,	,	PUNCT
eurjchem-828	306	3	w.	w.	PROPN
eurjchem-828	306	4	;	;	PUNCT
eurjchem-828	306	5	yamaguchi	yamaguchi	PROPN
eurjchem-828	306	6	,	,	PUNCT
eurjchem-828	306	7	k.	k.	PROPN
eurjchem-828	306	8	;	;	PUNCT
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eurjchem-828	306	10	,	,	PUNCT
eurjchem-828	306	11	g.	g.	PROPN
eurjchem-828	306	12	;	;	PUNCT
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eurjchem-828	306	15	s.	s.	PROPN
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eurjchem-828	306	19	,	,	PUNCT
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eurjchem-828	306	21	;	;	PUNCT
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eurjchem-828	306	23	,	,	PUNCT
eurjchem-828	306	24	s.	s.	PROPN
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eurjchem-828	306	27	.	.	PUNCT
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eurjchem-828	307	2	.	.	PUNCT
eurjchem-828	307	3	pol	pol	PROPN
eurjchem-828	307	4	.	.	PUNCT
eurjchem-828	308	1	chem	chem	PROPN
eurjchem-828	308	2	.	.	PUNCT
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eurjchem-828	309	2	.	.	PROPN
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eurjchem-828	309	4	,	,	PUNCT
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eurjchem-828	309	6	,	,	PUNCT
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eurjchem-828	309	8	.	.	PUNCT
eurjchem-828	310	1	[	[	X
eurjchem-828	310	2	13	13	NUM
eurjchem-828	310	3	]	]	PUNCT
eurjchem-828	310	4	.	.	PUNCT
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eurjchem-828	311	2	,	,	PUNCT
eurjchem-828	311	3	g.	g.	PROPN
eurjchem-828	311	4	makrom	makrom	PROPN
eurjchem-828	311	5	.	.	PUNCT
eurjchem-828	312	1	chem	chem	PROPN
eurjchem-828	312	2	.	.	PUNCT
eurjchem-828	313	1	1988	1988	NUM
eurjchem-828	313	2	,	,	PUNCT
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eurjchem-828	313	4	,	,	PUNCT
eurjchem-828	313	5	2513‐2520	2513‐2520	NUM
eurjchem-828	313	6	.	.	PUNCT
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eurjchem-828	314	2	14	14	NUM
eurjchem-828	314	3	]	]	PUNCT
eurjchem-828	314	4	.	.	PUNCT
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eurjchem-828	315	2	,	,	PUNCT
eurjchem-828	315	3	a.	a.	NOUN
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eurjchem-828	315	5	;	;	PUNCT
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eurjchem-828	315	7	,	,	PUNCT
eurjchem-828	315	8	e.	e.	PROPN
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eurjchem-828	315	11	.	.	PUNCT
eurjchem-828	316	1	j.	j.	PROPN
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eurjchem-828	316	3	.	.	PROPN
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eurjchem-828	316	5	.	.	PUNCT
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eurjchem-828	317	2	,	,	PUNCT
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eurjchem-828	317	4	,	,	PUNCT
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eurjchem-828	317	6	.	.	PUNCT
eurjchem-828	318	1	[	[	X
eurjchem-828	318	2	15	15	NUM
eurjchem-828	318	3	]	]	PUNCT
eurjchem-828	318	4	.	.	PUNCT
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eurjchem-828	319	2	,	,	PUNCT
eurjchem-828	319	3	l.	l.	PROPN
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eurjchem-828	319	5	;	;	PUNCT
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eurjchem-828	319	7	,	,	PUNCT
eurjchem-828	319	8	p.	p.	PROPN
eurjchem-828	319	9	i.	i.	PROPN
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eurjchem-828	320	2	.	.	PUNCT
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eurjchem-828	322	4	.	.	PUNCT
eurjchem-828	323	1	sci	sci	PROPN
eurjchem-828	323	2	.	.	PROPN
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eurjchem-828	323	4	,	,	PUNCT
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