id	sid	tid	token	lemma	pos
eurjchem-870	1	1	untitled	untitle	VERB
eurjchem-870	1	2	european	european	PROPN
eurjchem-870	1	3	journal	journal	PROPN
eurjchem-870	1	4	of	of	ADP
eurjchem-870	1	5	chemistry	chemistry	NOUN
eurjchem-870	1	6	5	5	NUM
eurjchem-870	1	7	(	(	PUNCT
eurjchem-870	1	8	1	1	NUM
eurjchem-870	1	9	)	)	PUNCT
eurjchem-870	1	10	(	(	PUNCT
eurjchem-870	1	11	2014	2014	NUM
eurjchem-870	1	12	)	)	PUNCT
eurjchem-870	1	13	24‐32	24‐32	NUM
eurjchem-870	1	14	european	european	ADJ
eurjchem-870	1	15	journal	journal	PROPN
eurjchem-870	1	16	of	of	ADP
eurjchem-870	1	17	chemistry	chemistry	NOUN
eurjchem-870	1	18	issn	issn	PROPN
eurjchem-870	1	19	2153‐2249	2153‐2249	PROPN
eurjchem-870	1	20	(	(	PUNCT
eurjchem-870	1	21	print	print	NOUN
eurjchem-870	1	22	)	)	PUNCT
eurjchem-870	1	23	/	/	SYM
eurjchem-870	1	24	issn	issn	PROPN
eurjchem-870	1	25	2153‐2257	2153‐2257	NUM
eurjchem-870	1	26	(	(	PUNCT
eurjchem-870	1	27	online	online	ADJ
eurjchem-870	1	28	)	)	PUNCT
eurjchem-870	1	29			NOUN
eurjchem-870	1	30	2014	2014	NUM
eurjchem-870	2	1	eurjchem	eurjchem	PROPN
eurjchem-870	2	2	publishing	publish	VERB
eurjchem-870	2	3	‐	‐	NOUN
eurjchem-870	2	4	printed	print	VERB
eurjchem-870	2	5	in	in	ADP
eurjchem-870	2	6	the	the	DET
eurjchem-870	2	7	usa	usa	PROPN
eurjchem-870	2	8	http://dx.doi.org/10.5155/eurjchem.5.1.24‐32.870	http://dx.doi.org/10.5155/eurjchem.5.1.24‐32.870	PROPN
eurjchem-870	2	9	european	european	PROPN
eurjchem-870	2	10	journal	journal	PROPN
eurjchem-870	2	11	of	of	ADP
eurjchem-870	2	12	chemistry	chemistry	PROPN
eurjchem-870	2	13	journal	journal	PROPN
eurjchem-870	2	14	homepage	homepage	NOUN
eurjchem-870	2	15	:	:	PUNCT
eurjchem-870	2	16	www.eurjchem.com	www.eurjchem.com	X
eurjchem-870	2	17	synthesis	synthesis	NOUN
eurjchem-870	2	18	and	and	CCONJ
eurjchem-870	2	19	characterization	characterization	NOUN
eurjchem-870	2	20	of	of	ADP
eurjchem-870	2	21	novel	novel	ADJ
eurjchem-870	2	22	pyrazolone	pyrazolone	NOUN
eurjchem-870	2	23	derivatives	derivative	NOUN
eurjchem-870	2	24	magda	magda	PROPN
eurjchem-870	2	25	ismail	ismail	PROPN
eurjchem-870	2	26	marzouk	marzouk	X
eurjchem-870	2	27	a	a	PRON
eurjchem-870	2	28	,	,	PUNCT
eurjchem-870	2	29	*	*	PROPN
eurjchem-870	2	30	,	,	PUNCT
eurjchem-870	2	31	galal	galal	PROPN
eurjchem-870	2	32	hosni	hosni	PROPN
eurjchem-870	2	33	sayed	say	VERB
eurjchem-870	2	34	a	a	PRON
eurjchem-870	2	35	,	,	PUNCT
eurjchem-870	2	36	mohamed	mohamed	PROPN
eurjchem-870	2	37	said	say	VERB
eurjchem-870	2	38	abd	abd	PROPN
eurjchem-870	2	39	elhalim	elhalim	PROPN
eurjchem-870	2	40	b	b	PROPN
eurjchem-870	2	41	and	and	CCONJ
eurjchem-870	2	42	salma	salma	PROPN
eurjchem-870	2	43	yehia	yehia	PROPN
eurjchem-870	2	44	mansour	mansour	PROPN
eurjchem-870	3	1	a	a	DET
eurjchem-870	3	2	a	a	DET
eurjchem-870	3	3	heterocyclic	heterocyclic	ADJ
eurjchem-870	3	4	synthetic	synthetic	ADJ
eurjchem-870	3	5	laboratory	laboratory	NOUN
eurjchem-870	3	6	,	,	PUNCT
eurjchem-870	3	7	chemistry	chemistry	NOUN
eurjchem-870	3	8	department	department	NOUN
eurjchem-870	3	9	,	,	PUNCT
eurjchem-870	3	10	faculty	faculty	NOUN
eurjchem-870	3	11	of	of	ADP
eurjchem-870	3	12	science	science	NOUN
eurjchem-870	3	13	,	,	PUNCT
eurjchem-870	3	14	ain	ain	PROPN
eurjchem-870	3	15	shams	shams	PROPN
eurjchem-870	3	16	university	university	PROPN
eurjchem-870	3	17	,	,	PUNCT
eurjchem-870	3	18	abbassia	abbassia	NOUN
eurjchem-870	3	19	11566	11566	NUM
eurjchem-870	3	20	,	,	PUNCT
eurjchem-870	3	21	cairo	cairo	PROPN
eurjchem-870	3	22	,	,	PUNCT
eurjchem-870	3	23	egypt	egypt	PROPN
eurjchem-870	3	24	b	b	PROPN
eurjchem-870	3	25	heterocyclic	heterocyclic	ADJ
eurjchem-870	3	26	synthetic	synthetic	ADJ
eurjchem-870	3	27	laboratory	laboratory	NOUN
eurjchem-870	3	28	,	,	PUNCT
eurjchem-870	3	29	chemistry	chemistry	NOUN
eurjchem-870	3	30	department	department	NOUN
eurjchem-870	3	31	,	,	PUNCT
eurjchem-870	3	32	faculty	faculty	NOUN
eurjchem-870	3	33	of	of	ADP
eurjchem-870	3	34	engineering	engineering	NOUN
eurjchem-870	3	35	,	,	PUNCT
eurjchem-870	3	36	ain	ain	PROPN
eurjchem-870	3	37	shams	shams	PROPN
eurjchem-870	3	38	university	university	PROPN
eurjchem-870	3	39	,	,	PUNCT
eurjchem-870	3	40	abbassia	abbassia	NOUN
eurjchem-870	3	41	11566	11566	NUM
eurjchem-870	3	42	,	,	PUNCT
eurjchem-870	3	43	cairo	cairo	PROPN
eurjchem-870	3	44	,	,	PUNCT
eurjchem-870	3	45	egypt	egypt	PROPN
eurjchem-870	3	46	*	*	PUNCT
eurjchem-870	3	47	corresponding	correspond	VERB
eurjchem-870	3	48	author	author	NOUN
eurjchem-870	3	49	at	at	ADP
eurjchem-870	3	50	:	:	PUNCT
eurjchem-870	3	51	heterocyclic	heterocyclic	ADJ
eurjchem-870	3	52	synthetic	synthetic	ADJ
eurjchem-870	3	53	laboratory	laboratory	NOUN
eurjchem-870	3	54	,	,	PUNCT
eurjchem-870	3	55	chemistry	chemistry	NOUN
eurjchem-870	3	56	department	department	NOUN
eurjchem-870	3	57	,	,	PUNCT
eurjchem-870	3	58	faculty	faculty	NOUN
eurjchem-870	3	59	of	of	ADP
eurjchem-870	3	60	science	science	NOUN
eurjchem-870	3	61	,	,	PUNCT
eurjchem-870	3	62	ain	ain	PROPN
eurjchem-870	3	63	shams	shams	PROPN
eurjchem-870	3	64	university	university	PROPN
eurjchem-870	3	65	,	,	PUNCT
eurjchem-870	3	66	abbassia	abbassia	NOUN
eurjchem-870	3	67	11566	11566	NUM
eurjchem-870	3	68	,	,	PUNCT
eurjchem-870	3	69	cairo	cairo	PROPN
eurjchem-870	3	70	,	,	PUNCT
eurjchem-870	3	71	egypt	egypt	PROPN
eurjchem-870	3	72	.	.	PUNCT
eurjchem-870	4	1	tel	tel	PROPN
eurjchem-870	4	2	.	.	PUNCT
eurjchem-870	4	3	:	:	PUNCT
eurjchem-870	5	1	+2.0122.3309974	+2.0122.3309974	X
eurjchem-870	5	2	.	.	PUNCT
eurjchem-870	6	1	fax	fax	NOUN
eurjchem-870	6	2	:	:	PUNCT
eurjchem-870	6	3	+2.02.24662917	+2.02.24662917	PROPN
eurjchem-870	6	4	.	.	PUNCT
eurjchem-870	6	5	e‐mail	e‐mail	PUNCT
eurjchem-870	7	1	address	address	NOUN
eurjchem-870	7	2	:	:	PUNCT
eurjchem-870	7	3	magda_marzouk@sci.asu.edu.eg	magda_marzouk@sci.asu.edu.eg	X
eurjchem-870	7	4	(	(	PUNCT
eurjchem-870	7	5	m.	m.	NOUN
eurjchem-870	7	6	marzouk	marzouk	ADV
eurjchem-870	7	7	)	)	PUNCT
eurjchem-870	7	8	.	.	PUNCT
eurjchem-870	8	1	article	article	NOUN
eurjchem-870	8	2	information	information	PROPN
eurjchem-870	8	3	abstract	abstract	ADJ
eurjchem-870	8	4	doi	doi	NOUN
eurjchem-870	8	5	:	:	PUNCT
eurjchem-870	8	6	10.5155	10.5155	NUM
eurjchem-870	8	7	/	/	SYM
eurjchem-870	8	8	eurjchem.5.1.24‐32.870	eurjchem.5.1.24‐32.870	NOUN
eurjchem-870	8	9	received	receive	VERB
eurjchem-870	8	10	:	:	PUNCT
eurjchem-870	8	11	08	08	NUM
eurjchem-870	8	12	july	july	PROPN
eurjchem-870	8	13	2013	2013	NUM
eurjchem-870	8	14	received	receive	VERB
eurjchem-870	8	15	in	in	ADP
eurjchem-870	8	16	revised	revise	VERB
eurjchem-870	8	17	form	form	NOUN
eurjchem-870	8	18	:	:	PUNCT
eurjchem-870	8	19	26	26	NUM
eurjchem-870	8	20	august	august	PROPN
eurjchem-870	8	21	2013	2013	NUM
eurjchem-870	8	22	accepted	accept	VERB
eurjchem-870	8	23	:	:	PUNCT
eurjchem-870	8	24	26	26	NUM
eurjchem-870	8	25	august	august	PROPN
eurjchem-870	8	26	2013	2013	NUM
eurjchem-870	8	27	online	online	NOUN
eurjchem-870	8	28	:	:	PUNCT
eurjchem-870	8	29	31	31	NUM
eurjchem-870	8	30	march	march	NOUN
eurjchem-870	8	31	2014	2014	NUM
eurjchem-870	8	32	keywords	keyword	VERB
eurjchem-870	8	33	the	the	DET
eurjchem-870	8	34	reactivity	reactivity	NOUN
eurjchem-870	8	35	of	of	ADP
eurjchem-870	8	36	hydrogen	hydrogen	NOUN
eurjchem-870	8	37	atoms	atom	NOUN
eurjchem-870	8	38	at	at	ADP
eurjchem-870	8	39	c‐4	c‐4	PROPN
eurjchem-870	8	40	of	of	ADP
eurjchem-870	8	41	pyrazolone	pyrazolone	NOUN
eurjchem-870	8	42	3	3	NUM
eurjchem-870	8	43	towards	towards	ADP
eurjchem-870	8	44	condensation	condensation	NOUN
eurjchem-870	8	45	reactions	reaction	NOUN
eurjchem-870	8	46	was	be	AUX
eurjchem-870	8	47	studied	study	VERB
eurjchem-870	8	48	by	by	ADP
eurjchem-870	8	49	its	its	PRON
eurjchem-870	8	50	reaction	reaction	NOUN
eurjchem-870	8	51	with	with	ADP
eurjchem-870	8	52	p‐anisaldehyde	p‐anisaldehyde	NOUN
eurjchem-870	8	53	,	,	PUNCT
eurjchem-870	8	54	malononitrile	malononitrile	NOUN
eurjchem-870	8	55	and/or	and/or	CCONJ
eurjchem-870	8	56	ethyl	ethyl	PROPN
eurjchem-870	8	57	acetoacetate	acetoacetate	NOUN
eurjchem-870	8	58	in	in	ADP
eurjchem-870	8	59	the	the	DET
eurjchem-870	8	60	presence	presence	NOUN
eurjchem-870	8	61	of	of	ADP
eurjchem-870	8	62	ammonium	ammonium	NOUN
eurjchem-870	8	63	acetate	acetate	NOUN
eurjchem-870	8	64	and/or	and/or	CCONJ
eurjchem-870	8	65	piperidine	piperidine	NOUN
eurjchem-870	8	66	,	,	PUNCT
eurjchem-870	8	67	glucose	glucose	NOUN
eurjchem-870	8	68	,	,	PUNCT
eurjchem-870	8	69	phenyl	phenyl	NOUN
eurjchem-870	8	70	isothiocyanate	isothiocyanate	NOUN
eurjchem-870	8	71	,	,	PUNCT
eurjchem-870	8	72	2‐amino	2‐amino	NUM
eurjchem-870	8	73	thiazole	thiazole	NOUN
eurjchem-870	8	74	and	and	CCONJ
eurjchem-870	8	75	aniline	aniline	NOUN
eurjchem-870	8	76	to	to	PART
eurjchem-870	8	77	afford	afford	VERB
eurjchem-870	8	78	compounds	compound	NOUN
eurjchem-870	8	79	4‐6	4‐6	PROPN
eurjchem-870	8	80	,	,	PUNCT
eurjchem-870	8	81	13	13	NUM
eurjchem-870	8	82	,	,	PUNCT
eurjchem-870	8	83	15	15	NUM
eurjchem-870	8	84	,	,	PUNCT
eurjchem-870	8	85	17	17	NUM
eurjchem-870	8	86	and	and	CCONJ
eurjchem-870	8	87	18	18	NUM
eurjchem-870	8	88	,	,	PUNCT
eurjchem-870	8	89	respectively	respectively	ADV
eurjchem-870	8	90	.	.	PUNCT
eurjchem-870	9	1	reaction	reaction	NOUN
eurjchem-870	9	2	of	of	ADP
eurjchem-870	9	3	amino	amino	ADJ
eurjchem-870	9	4	carbonitrile	carbonitrile	NOUN
eurjchem-870	9	5	4	4	NUM
eurjchem-870	9	6	with	with	ADP
eurjchem-870	9	7	ammonium	ammonium	NOUN
eurjchem-870	9	8	thiocyanate	thiocyanate	NOUN
eurjchem-870	9	9	,	,	PUNCT
eurjchem-870	9	10	and	and	CCONJ
eurjchem-870	9	11	formamide	formamide	ADV
eurjchem-870	9	12	afforded	afford	VERB
eurjchem-870	9	13	compound	compound	NOUN
eurjchem-870	9	14	7	7	NUM
eurjchem-870	9	15	and	and	CCONJ
eurjchem-870	9	16	pyrazolo[3,4‐b]pyridinylformamide	pyrazolo[3,4‐b]pyridinylformamide	NOUN
eurjchem-870	9	17	,	,	PUNCT
eurjchem-870	9	18	9	9	NUM
eurjchem-870	9	19	.	.	PUNCT
eurjchem-870	9	20	reaction	reaction	NOUN
eurjchem-870	9	21	of	of	ADP
eurjchem-870	9	22	compound	compound	NOUN
eurjchem-870	9	23	7	7	NUM
eurjchem-870	9	24	with	with	ADP
eurjchem-870	9	25	hydrazine	hydrazine	NOUN
eurjchem-870	9	26	hydrate	hydrate	NOUN
eurjchem-870	9	27	gave	gave	AUX
eurjchem-870	9	28	thiocyanato‐1,3,4‐thiadiazol‐2‐yl)‐1h‐pyrazolo[3,4‐b]pyridin‐6‐amine	thiocyanato‐1,3,4‐thiadiazol‐2‐yl)‐1h‐pyrazolo[3,4‐b]pyridin‐6‐amine	VERB
eurjchem-870	9	29	derivative	derivative	ADJ
eurjchem-870	9	30	,	,	PUNCT
eurjchem-870	9	31	8	8	NUM
eurjchem-870	9	32	.	.	PUNCT
eurjchem-870	10	1	acetyla‐	acetyla‐	VERB
eurjchem-870	10	2	tion	tion	NOUN
eurjchem-870	10	3	of	of	ADP
eurjchem-870	10	4	amino	amino	ADJ
eurjchem-870	10	5	carbonitriles	carbonitrile	NOUN
eurjchem-870	10	6	4	4	NUM
eurjchem-870	10	7	and	and	CCONJ
eurjchem-870	10	8	5	5	NUM
eurjchem-870	10	9	afforded	afford	VERB
eurjchem-870	10	10	compound	compound	NOUN
eurjchem-870	10	11	10	10	NUM
eurjchem-870	10	12	and	and	CCONJ
eurjchem-870	10	13	11	11	NUM
eurjchem-870	10	14	,	,	PUNCT
eurjchem-870	10	15	respectively	respectively	ADV
eurjchem-870	10	16	.	.	PUNCT
eurjchem-870	11	1	reaction	reaction	NOUN
eurjchem-870	11	2	of	of	ADP
eurjchem-870	11	3	compound	compound	NOUN
eurjchem-870	11	4	11	11	NUM
eurjchem-870	11	5	with	with	ADP
eurjchem-870	11	6	hydrazine	hydrazine	NOUN
eurjchem-870	11	7	hydrate	hydrate	NOUN
eurjchem-870	11	8	afforded	afford	VERB
eurjchem-870	11	9	azanediyl	azanediyl	NOUN
eurjchem-870	11	10	compound	compound	VERB
eurjchem-870	11	11	12	12	NUM
eurjchem-870	11	12	.	.	PUNCT
eurjchem-870	12	1	the	the	DET
eurjchem-870	12	2	pyrazolone	pyrazolone	NOUN
eurjchem-870	12	3	19	19	NUM
eurjchem-870	12	4	reacted	react	VERB
eurjchem-870	12	5	with	with	ADP
eurjchem-870	12	6	different	different	ADJ
eurjchem-870	12	7	nitrogen	nitrogen	NOUN
eurjchem-870	12	8	nucleophiles	nucleophile	NOUN
eurjchem-870	12	9	such	such	ADJ
eurjchem-870	12	10	as	as	ADP
eurjchem-870	12	11	hydrazine	hydrazine	NOUN
eurjchem-870	12	12	hydrate	hydrate	NOUN
eurjchem-870	12	13	,	,	PUNCT
eurjchem-870	12	14	urea	urea	NOUN
eurjchem-870	12	15	,	,	PUNCT
eurjchem-870	12	16	thiourea	thiourea	NOUN
eurjchem-870	12	17	and	and	CCONJ
eurjchem-870	12	18	hydroxylamine	hydroxylamine	ADJ
eurjchem-870	12	19	hydrochloride	hydrochloride	NOUN
eurjchem-870	12	20	to	to	PART
eurjchem-870	12	21	afford	afford	VERB
eurjchem-870	12	22	compounds	compound	NOUN
eurjchem-870	12	23	22‐25	22‐25	PROPN
eurjchem-870	12	24	.	.	PUNCT
eurjchem-870	13	1	the	the	DET
eurjchem-870	13	2	reactivity	reactivity	NOUN
eurjchem-870	13	3	of	of	ADP
eurjchem-870	13	4	pyrazolone	pyrazolone	NOUN
eurjchem-870	13	5	19	19	NUM
eurjchem-870	13	6	as	as	ADP
eurjchem-870	13	7	an	an	DET
eurjchem-870	13	8	α	α	NOUN
eurjchem-870	13	9	,	,	PUNCT
eurjchem-870	13	10	β‐unsaturated	β‐unsaturate	VERB
eurjchem-870	13	11	compound	compound	NOUN
eurjchem-870	13	12	towards	towards	ADP
eurjchem-870	13	13	several	several	ADJ
eurjchem-870	13	14	carbon	carbon	NOUN
eurjchem-870	13	15	nucleophiles	nucleophile	NOUN
eurjchem-870	13	16	under	under	ADP
eurjchem-870	13	17	michael	michael	PROPN
eurjchem-870	13	18	reaction	reaction	NOUN
eurjchem-870	13	19	was	be	AUX
eurjchem-870	13	20	studied	study	VERB
eurjchem-870	13	21	by	by	ADP
eurjchem-870	13	22	its	its	PRON
eurjchem-870	13	23	reaction	reaction	NOUN
eurjchem-870	13	24	with	with	ADP
eurjchem-870	13	25	ethyl	ethyl	PROPN
eurjchem-870	13	26	acetoacetate	acetoacetate	NOUN
eurjchem-870	13	27	,	,	PUNCT
eurjchem-870	13	28	ethyl	ethyl	PROPN
eurjchem-870	13	29	cyanoacetate	cyanoacetate	NOUN
eurjchem-870	13	30	,	,	PUNCT
eurjchem-870	13	31	and	and	CCONJ
eurjchem-870	13	32	malononitrile	malononitrile	NOUN
eurjchem-870	13	33	under	under	ADP
eurjchem-870	13	34	different	different	ADJ
eurjchem-870	13	35	reaction	reaction	NOUN
eurjchem-870	13	36	conditions	condition	NOUN
eurjchem-870	13	37	and	and	CCONJ
eurjchem-870	13	38	pyrazolone	pyrazolone	NOUN
eurjchem-870	13	39	3	3	NUM
eurjchem-870	13	40	to	to	PART
eurjchem-870	13	41	afford	afford	VERB
eurjchem-870	13	42	compounds	compound	NOUN
eurjchem-870	13	43	26‐32	26‐32	NUM
eurjchem-870	13	44	,	,	PUNCT
eurjchem-870	13	45	respectively	respectively	ADV
eurjchem-870	13	46	.	.	PUNCT
eurjchem-870	14	1	synthesis	synthesis	NOUN
eurjchem-870	14	2	of	of	ADP
eurjchem-870	14	3	amino	amino	ADJ
eurjchem-870	14	4	carbonitriles	carbonitrile	NOUN
eurjchem-870	14	5	5	5	NUM
eurjchem-870	14	6	,	,	PUNCT
eurjchem-870	14	7	pyrazolone	pyrazolone	NOUN
eurjchem-870	14	8	19	19	NUM
eurjchem-870	14	9	and	and	CCONJ
eurjchem-870	14	10	pyrazolo[3,4‐c]pyrazole	pyrazolo[3,4‐c]pyrazole	PROPN
eurjchem-870	14	11	22	22	NUM
eurjchem-870	14	12	were	be	AUX
eurjchem-870	14	13	carried	carry	VERB
eurjchem-870	14	14	out	out	ADP
eurjchem-870	14	15	under	under	ADP
eurjchem-870	14	16	microwave	microwave	NOUN
eurjchem-870	14	17	irradiation	irradiation	NOUN
eurjchem-870	14	18	.	.	PUNCT
eurjchem-870	15	1	the	the	DET
eurjchem-870	15	2	newly	newly	ADV
eurjchem-870	15	3	synthesized	synthesize	VERB
eurjchem-870	15	4	compounds	compound	NOUN
eurjchem-870	15	5	were	be	AUX
eurjchem-870	15	6	characterized	characterize	VERB
eurjchem-870	15	7	by	by	ADP
eurjchem-870	15	8	ir	ir	PROPN
eurjchem-870	15	9	,	,	PUNCT
eurjchem-870	15	10	1h	1h	NUM
eurjchem-870	15	11	nmr	nmr	NOUN
eurjchem-870	15	12	and	and	CCONJ
eurjchem-870	15	13	mass	mass	ADJ
eurjchem-870	15	14	spectral	spectral	ADJ
eurjchem-870	15	15	data	datum	NOUN
eurjchem-870	15	16	.	.	PUNCT
eurjchem-870	16	1	pyrazolone	pyrazolone	NOUN
eurjchem-870	16	2	malononitrile	malononitrile	NOUN
eurjchem-870	16	3	azo	azo	NOUN
eurjchem-870	16	4	compounds	compound	VERB
eurjchem-870	16	5	pyrazolo	pyrazolo	ADJ
eurjchem-870	16	6	pyrimidine	pyrimidine	NOUN
eurjchem-870	16	7	microwave	microwave	NOUN
eurjchem-870	16	8	irradiation	irradiation	NOUN
eurjchem-870	16	9	α	α	NOUN
eurjchem-870	16	10	,	,	PUNCT
eurjchem-870	16	11	β‐unsaturated	β‐unsaturate	VERB
eurjchem-870	16	12	ketone	ketone	NOUN
eurjchem-870	16	13	1	1	NUM
eurjchem-870	16	14	.	.	PUNCT
eurjchem-870	17	1	introduction	introduction	NOUN
eurjchem-870	17	2	pyrazolone	pyrazolone	NOUN
eurjchem-870	17	3	is	be	AUX
eurjchem-870	17	4	a	a	DET
eurjchem-870	17	5	five	five	NUM
eurjchem-870	17	6	membered	membere	VERB
eurjchem-870	17	7	lactam	lactam	NOUN
eurjchem-870	17	8	ring	ring	NOUN
eurjchem-870	17	9	[	[	X
eurjchem-870	17	10	1	1	NUM
eurjchem-870	17	11	]	]	PUNCT
eurjchem-870	17	12	containing	contain	VERB
eurjchem-870	17	13	two	two	NUM
eurjchem-870	17	14	nitrogen	nitrogen	NOUN
eurjchem-870	17	15	atoms	atom	NOUN
eurjchem-870	17	16	and	and	CCONJ
eurjchem-870	17	17	one	one	NUM
eurjchem-870	17	18	ketonic	ketonic	ADJ
eurjchem-870	17	19	group	group	NOUN
eurjchem-870	17	20	in	in	ADP
eurjchem-870	17	21	its	its	PRON
eurjchem-870	17	22	structure	structure	NOUN
eurjchem-870	17	23	.	.	PUNCT
eurjchem-870	18	1	during	during	ADP
eurjchem-870	18	2	the	the	DET
eurjchem-870	18	3	discovery	discovery	NOUN
eurjchem-870	18	4	of	of	ADP
eurjchem-870	18	5	pyrazolone	pyrazolone	NOUN
eurjchem-870	18	6	,	,	PUNCT
eurjchem-870	18	7	they	they	PRON
eurjchem-870	18	8	were	be	AUX
eurjchem-870	18	9	only	only	ADV
eurjchem-870	18	10	known	know	VERB
eurjchem-870	18	11	as	as	ADP
eurjchem-870	18	12	nsaids	nsaid	NOUN
eurjchem-870	18	13	[	[	X
eurjchem-870	18	14	2	2	NUM
eurjchem-870	18	15	]	]	PUNCT
eurjchem-870	18	16	but	but	CCONJ
eurjchem-870	18	17	,	,	PUNCT
eurjchem-870	18	18	since	since	SCONJ
eurjchem-870	18	19	year	year	NOUN
eurjchem-870	18	20	2000	2000	NUM
eurjchem-870	18	21	,	,	PUNCT
eurjchem-870	18	22	they	they	PRON
eurjchem-870	18	23	play	play	VERB
eurjchem-870	18	24	versatile	versatile	ADJ
eurjchem-870	18	25	role	role	NOUN
eurjchem-870	18	26	in	in	ADP
eurjchem-870	18	27	several	several	ADJ
eurjchem-870	18	28	complications	complication	NOUN
eurjchem-870	18	29	like	like	ADP
eurjchem-870	18	30	cerebral	cerebral	ADJ
eurjchem-870	18	31	ischemia	ischemia	NOUN
eurjchem-870	18	32	and	and	CCONJ
eurjchem-870	18	33	cardiovascular	cardiovascular	ADJ
eurjchem-870	18	34	diseases	disease	NOUN
eurjchem-870	18	35	[	[	X
eurjchem-870	18	36	3	3	NUM
eurjchem-870	18	37	]	]	PUNCT
eurjchem-870	18	38	.	.	PUNCT
eurjchem-870	19	1	the	the	DET
eurjchem-870	19	2	chemistry	chemistry	NOUN
eurjchem-870	19	3	of	of	ADP
eurjchem-870	19	4	pyrazolone	pyrazolone	NOUN
eurjchem-870	19	5	has	have	AUX
eurjchem-870	19	6	gained	gain	VERB
eurjchem-870	19	7	increasing	increase	VERB
eurjchem-870	19	8	attention	attention	NOUN
eurjchem-870	19	9	due	due	ADP
eurjchem-870	19	10	to	to	ADP
eurjchem-870	19	11	its	its	PRON
eurjchem-870	19	12	diverse	diverse	ADJ
eurjchem-870	19	13	pharmacological	pharmacological	ADJ
eurjchem-870	19	14	properties	property	NOUN
eurjchem-870	19	15	[	[	X
eurjchem-870	19	16	4	4	X
eurjchem-870	19	17	]	]	PUNCT
eurjchem-870	19	18	such	such	ADJ
eurjchem-870	19	19	as	as	ADP
eurjchem-870	19	20	cytotoxic	cytotoxic	ADJ
eurjchem-870	19	21	[	[	X
eurjchem-870	19	22	5,6	5,6	NUM
eurjchem-870	19	23	]	]	PUNCT
eurjchem-870	19	24	,	,	PUNCT
eurjchem-870	19	25	anti‐inflammatory	anti‐inflammatory	NOUN
eurjchem-870	20	1	[	[	X
eurjchem-870	20	2	7	7	NUM
eurjchem-870	20	3	]	]	PUNCT
eurjchem-870	20	4	,	,	PUNCT
eurjchem-870	20	5	antimicrobial	antimicrobial	ADJ
eurjchem-870	20	6	[	[	X
eurjchem-870	20	7	8,9	8,9	NUM
eurjchem-870	20	8	]	]	PUNCT
eurjchem-870	20	9	,	,	PUNCT
eurjchem-870	20	10	antioxidant	antioxidant	ADJ
eurjchem-870	20	11	[	[	X
eurjchem-870	20	12	10	10	NUM
eurjchem-870	20	13	]	]	PUNCT
eurjchem-870	20	14	,	,	PUNCT
eurjchem-870	20	15	antiviral	antiviral	NOUN
eurjchem-870	20	16	[	[	X
eurjchem-870	20	17	11	11	NUM
eurjchem-870	20	18	]	]	PUNCT
eurjchem-870	20	19	,	,	PUNCT
eurjchem-870	20	20	oral	oral	ADJ
eurjchem-870	20	21	hypoglycemic	hypoglycemic	ADJ
eurjchem-870	20	22	activity	activity	NOUN
eurjchem-870	21	1	[	[	X
eurjchem-870	21	2	12	12	NUM
eurjchem-870	21	3	]	]	PUNCT
eurjchem-870	21	4	and	and	CCONJ
eurjchem-870	21	5	analgesic	analgesic	ADJ
eurjchem-870	21	6	[	[	X
eurjchem-870	21	7	13,14	13,14	NUM
eurjchem-870	21	8	]	]	PUNCT
eurjchem-870	21	9	.	.	PUNCT
eurjchem-870	22	1	pyrazolones	pyrazolone	NOUN
eurjchem-870	22	2	are	be	AUX
eurjchem-870	22	3	believed	believe	VERB
eurjchem-870	22	4	to	to	PART
eurjchem-870	22	5	be	be	AUX
eurjchem-870	22	6	involved	involve	VERB
eurjchem-870	22	7	in	in	ADP
eurjchem-870	22	8	various	various	ADJ
eurjchem-870	22	9	biochemical	biochemical	ADJ
eurjchem-870	22	10	and	and	CCONJ
eurjchem-870	22	11	physiological	physiological	ADJ
eurjchem-870	22	12	reactions	reaction	NOUN
eurjchem-870	22	13	and	and	CCONJ
eurjchem-870	22	14	thus	thus	ADV
eurjchem-870	22	15	scientific	scientific	ADJ
eurjchem-870	22	16	research	research	NOUN
eurjchem-870	22	17	programs	program	NOUN
eurjchem-870	22	18	are	be	AUX
eurjchem-870	22	19	continually	continually	ADV
eurjchem-870	22	20	improvising	improvise	VERB
eurjchem-870	22	21	synthetic	synthetic	ADJ
eurjchem-870	22	22	techniques	technique	NOUN
eurjchem-870	22	23	to	to	PART
eurjchem-870	22	24	prepare	prepare	VERB
eurjchem-870	22	25	numerous	numerous	ADJ
eurjchem-870	22	26	pyrazolone	pyrazolone	NOUN
eurjchem-870	22	27	derivatives	derivative	NOUN
eurjchem-870	22	28	.	.	PUNCT
eurjchem-870	23	1	for	for	ADP
eurjchem-870	23	2	the	the	DET
eurjchem-870	23	3	last	last	ADJ
eurjchem-870	23	4	decade	decade	NOUN
eurjchem-870	23	5	a	a	DET
eurjchem-870	23	6	lot	lot	NOUN
eurjchem-870	23	7	of	of	ADP
eurjchem-870	23	8	work	work	NOUN
eurjchem-870	23	9	has	have	AUX
eurjchem-870	23	10	been	be	AUX
eurjchem-870	23	11	going	go	VERB
eurjchem-870	23	12	on	on	ADP
eurjchem-870	23	13	the	the	DET
eurjchem-870	23	14	pyrazolone	pyrazolone	NOUN
eurjchem-870	23	15	nucleus	nucleus	NOUN
eurjchem-870	23	16	.	.	PUNCT
eurjchem-870	24	1	scientists	scientist	NOUN
eurjchem-870	24	2	have	have	AUX
eurjchem-870	24	3	developed	develop	VERB
eurjchem-870	24	4	large	large	ADJ
eurjchem-870	24	5	number	number	NOUN
eurjchem-870	24	6	of	of	ADP
eurjchem-870	24	7	new	new	ADJ
eurjchem-870	24	8	compounds	compound	NOUN
eurjchem-870	24	9	related	relate	VERB
eurjchem-870	24	10	to	to	ADP
eurjchem-870	24	11	this	this	DET
eurjchem-870	24	12	moiety	moiety	NOUN
eurjchem-870	24	13	and	and	CCONJ
eurjchem-870	24	14	screened	screen	VERB
eurjchem-870	24	15	them	they	PRON
eurjchem-870	24	16	for	for	ADP
eurjchem-870	24	17	their	their	PRON
eurjchem-870	24	18	different	different	ADJ
eurjchem-870	24	19	pharmacological	pharmacological	NOUN
eurjchem-870	24	20	activities	activity	NOUN
eurjchem-870	24	21	to	to	PART
eurjchem-870	24	22	get	get	VERB
eurjchem-870	24	23	a	a	DET
eurjchem-870	24	24	molecule	molecule	NOUN
eurjchem-870	24	25	of	of	ADP
eurjchem-870	24	26	desired	desire	VERB
eurjchem-870	24	27	pharmacological	pharmacological	ADJ
eurjchem-870	24	28	activity	activity	NOUN
eurjchem-870	24	29	.	.	PUNCT
eurjchem-870	25	1	although	although	SCONJ
eurjchem-870	25	2	earlier	early	ADV
eurjchem-870	25	3	many	many	ADJ
eurjchem-870	25	4	of	of	ADP
eurjchem-870	25	5	pyrazolone	pyrazolone	NOUN
eurjchem-870	25	6	derivatives	derivative	NOUN
eurjchem-870	25	7	were	be	AUX
eurjchem-870	25	8	associated	associate	VERB
eurjchem-870	25	9	with	with	ADP
eurjchem-870	25	10	adverse	adverse	ADJ
eurjchem-870	25	11	effects	effect	NOUN
eurjchem-870	25	12	such	such	ADJ
eurjchem-870	25	13	as	as	ADP
eurjchem-870	25	14	agranulocytosis	agranulocytosis	NOUN
eurjchem-870	25	15	,	,	PUNCT
eurjchem-870	25	16	skin	skin	NOUN
eurjchem-870	25	17	rashes	rash	NOUN
eurjchem-870	25	18	and	and	CCONJ
eurjchem-870	25	19	blood	blood	NOUN
eurjchem-870	25	20	dyscariasis	dyscariasis	NOUN
eurjchem-870	25	21	,	,	PUNCT
eurjchem-870	25	22	etc	etc	X
eurjchem-870	25	23	.	.	X
eurjchem-870	25	24	2	2	X
eurjchem-870	25	25	.	.	X
eurjchem-870	25	26	experimental	experimental	ADJ
eurjchem-870	25	27	2.1	2.1	NUM
eurjchem-870	25	28	.	.	PUNCT
eurjchem-870	26	1	instrumentation	instrumentation	NOUN
eurjchem-870	26	2	all	all	DET
eurjchem-870	26	3	melting	melt	VERB
eurjchem-870	26	4	points	point	NOUN
eurjchem-870	26	5	were	be	AUX
eurjchem-870	26	6	measured	measure	VERB
eurjchem-870	26	7	on	on	ADP
eurjchem-870	26	8	a	a	DET
eurjchem-870	26	9	gallenkamp	gallenkamp	NOUN
eurjchem-870	26	10	melting	melting	NOUN
eurjchem-870	26	11	point	point	NOUN
eurjchem-870	26	12	apparatus	apparatus	NOUN
eurjchem-870	26	13	and	and	CCONJ
eurjchem-870	26	14	are	be	AUX
eurjchem-870	26	15	uncorrected	uncorrecte	VERB
eurjchem-870	26	16	.	.	PUNCT
eurjchem-870	27	1	all	all	DET
eurjchem-870	27	2	microwave	microwave	NOUN
eurjchem-870	27	3	reactions	reaction	NOUN
eurjchem-870	27	4	were	be	AUX
eurjchem-870	27	5	carried	carry	VERB
eurjchem-870	27	6	out	out	ADP
eurjchem-870	27	7	in	in	ADP
eurjchem-870	27	8	a	a	DET
eurjchem-870	27	9	domestic	domestic	ADJ
eurjchem-870	27	10	microwave	microwave	NOUN
eurjchem-870	27	11	oven	oven	NOUN
eurjchem-870	27	12	(	(	PUNCT
eurjchem-870	27	13	galanza	galanza	PROPN
eurjchem-870	27	14	950	950	NUM
eurjchem-870	27	15	)	)	PUNCT
eurjchem-870	27	16	.	.	PUNCT
eurjchem-870	28	1	the	the	DET
eurjchem-870	28	2	infrared	infrared	ADJ
eurjchem-870	28	3	spectra	spectra	NOUN
eurjchem-870	28	4	were	be	AUX
eurjchem-870	28	5	recorded	record	VERB
eurjchem-870	28	6	using	use	VERB
eurjchem-870	28	7	potassium	potassium	NOUN
eurjchem-870	28	8	bromide	bromide	NOUN
eurjchem-870	28	9	disks	disk	NOUN
eurjchem-870	28	10	on	on	ADP
eurjchem-870	28	11	a	a	DET
eurjchem-870	28	12	pye	pye	NOUN
eurjchem-870	28	13	unicam	unicam	VERB
eurjchem-870	29	1	sp‐3‐300	sp‐3‐300	PROPN
eurjchem-870	29	2	infrared	infrared	ADJ
eurjchem-870	29	3	spectrophotometer	spectrophotometer	NOUN
eurjchem-870	29	4	.	.	PUNCT
eurjchem-870	30	1	1h	1h	NUM
eurjchem-870	30	2	nmr	nmr	PROPN
eurjchem-870	30	3	spectra	spectra	NOUN
eurjchem-870	30	4	were	be	AUX
eurjchem-870	30	5	run	run	VERB
eurjchem-870	30	6	at	at	ADP
eurjchem-870	30	7	300	300	NUM
eurjchem-870	30	8	mhz	mhz	NOUN
eurjchem-870	30	9	,	,	PUNCT
eurjchem-870	30	10	on	on	ADP
eurjchem-870	30	11	a	a	DET
eurjchem-870	30	12	varian	varian	PROPN
eurjchem-870	30	13	mercury	mercury	PROPN
eurjchem-870	30	14	vx‐	vx‐	PROPN
eurjchem-870	30	15	300	300	NUM
eurjchem-870	30	16	nmr	nmr	NOUN
eurjchem-870	30	17	spectrometer	spectrometer	NOUN
eurjchem-870	30	18	,	,	PUNCT
eurjchem-870	30	19	using	use	VERB
eurjchem-870	30	20	tms	tms	PROPN
eurjchem-870	30	21	as	as	ADP
eurjchem-870	30	22	internal	internal	ADJ
eurjchem-870	30	23	standard	standard	NOUN
eurjchem-870	30	24	in	in	ADP
eurjchem-870	30	25	deuterated	deuterate	VERB
eurjchem-870	30	26	chloroform	chloroform	NOUN
eurjchem-870	30	27	or	or	CCONJ
eurjchem-870	30	28	deuterated	deuterate	VERB
eurjchem-870	30	29	dimethyl	dimethyl	NOUN
eurjchem-870	30	30	sulphoxide	sulphoxide	NOUN
eurjchem-870	30	31	.	.	PUNCT
eurjchem-870	31	1	chemical	chemical	ADJ
eurjchem-870	31	2	shifts	shift	NOUN
eurjchem-870	31	3	are	be	AUX
eurjchem-870	31	4	quoted	quote	VERB
eurjchem-870	31	5	δ	δ	PROPN
eurjchem-870	31	6	in	in	ADP
eurjchem-870	31	7	ppm	ppm	PROPN
eurjchem-870	31	8	.	.	PUNCT
eurjchem-870	32	1	the	the	DET
eurjchem-870	32	2	mass	mass	ADJ
eurjchem-870	32	3	spectra	spectra	NOUN
eurjchem-870	32	4	were	be	AUX
eurjchem-870	32	5	recorded	record	VERB
eurjchem-870	32	6	on	on	ADP
eurjchem-870	32	7	shimadzu	shimadzu	PROPN
eurjchem-870	32	8	gcms‐qp‐1000ex	gcms‐qp‐1000ex	PROPN
eurjchem-870	32	9	mass	mass	ADJ
eurjchem-870	32	10	spectrometers	spectrometer	NOUN
eurjchem-870	32	11	at	at	ADP
eurjchem-870	32	12	70	70	NUM
eurjchem-870	32	13	 	 	SPACE
eurjchem-870	32	14	ev	ev	NOUN
eurjchem-870	32	15	.	.	PUNCT
eurjchem-870	33	1	all	all	DET
eurjchem-870	33	2	the	the	DET
eurjchem-870	33	3	spectral	spectral	ADJ
eurjchem-870	33	4	measurements	measurement	NOUN
eurjchem-870	33	5	as	as	ADV
eurjchem-870	33	6	well	well	ADV
eurjchem-870	33	7	as	as	ADP
eurjchem-870	33	8	elemental	elemental	ADJ
eurjchem-870	33	9	analyses	analysis	NOUN
eurjchem-870	33	10	were	be	AUX
eurjchem-870	33	11	carried	carry	VERB
eurjchem-870	33	12	out	out	ADP
eurjchem-870	33	13	at	at	ADP
eurjchem-870	33	14	the	the	DET
eurjchem-870	33	15	micro	micro	ADJ
eurjchem-870	33	16	analytical	analytical	ADJ
eurjchem-870	33	17	center	center	NOUN
eurjchem-870	33	18	of	of	ADP
eurjchem-870	33	19	cairo	cairo	PROPN
eurjchem-870	33	20	university	university	PROPN
eurjchem-870	33	21	,	,	PUNCT
eurjchem-870	33	22	egypt	egypt	PROPN
eurjchem-870	33	23	,	,	PUNCT
eurjchem-870	33	24	and	and	CCONJ
eurjchem-870	33	25	the	the	DET
eurjchem-870	33	26	main	main	ADJ
eurjchem-870	33	27	defence	defence	NOUN
eurjchem-870	33	28	chemical	chemical	NOUN
eurjchem-870	33	29	laboratory	laboratory	NOUN
eurjchem-870	33	30	2	2	NUM
eurjchem-870	33	31	.	.	PUNCT
eurjchem-870	34	1	the	the	DET
eurjchem-870	34	2	antimicrobial	antimicrobial	ADJ
eurjchem-870	34	3	activities	activity	NOUN
eurjchem-870	34	4	were	be	AUX
eurjchem-870	34	5	carried	carry	VERB
eurjchem-870	34	6	out	out	ADP
eurjchem-870	34	7	at	at	ADP
eurjchem-870	34	8	egyptian	egyptian	ADJ
eurjchem-870	34	9	petroleum	petroleum	PROPN
eurjchem-870	34	10	research	research	PROPN
eurjchem-870	34	11	institute	institute	PROPN
eurjchem-870	34	12	,	,	PUNCT
eurjchem-870	34	13	fermentation	fermentation	NOUN
eurjchem-870	34	14	biotechnology	biotechnology	NOUN
eurjchem-870	34	15	lab	lab	NOUN
eurjchem-870	34	16	.	.	PUNCT
eurjchem-870	35	1	all	all	DET
eurjchem-870	35	2	the	the	DET
eurjchem-870	35	3	chemical	chemical	ADJ
eurjchem-870	35	4	reactions	reaction	NOUN
eurjchem-870	35	5	are	be	AUX
eurjchem-870	35	6	monitored	monitor	VERB
eurjchem-870	35	7	by	by	ADP
eurjchem-870	35	8	tlc	tlc	PROPN
eurjchem-870	35	9	.	.	PUNCT
eurjchem-870	36	1	marzouk	marzouk	X
eurjchem-870	36	2	et	et	PROPN
eurjchem-870	36	3	al	al	PROPN
eurjchem-870	36	4	.	.	PUNCT
eurjchem-870	36	5	/	/	SYM
eurjchem-870	36	6	european	european	PROPN
eurjchem-870	36	7	journal	journal	PROPN
eurjchem-870	36	8	of	of	ADP
eurjchem-870	36	9	chemistry	chemistry	NOUN
eurjchem-870	36	10	5	5	NUM
eurjchem-870	36	11	(	(	PUNCT
eurjchem-870	36	12	1	1	NUM
eurjchem-870	36	13	)	)	PUNCT
eurjchem-870	36	14	(	(	PUNCT
eurjchem-870	36	15	2014	2014	NUM
eurjchem-870	36	16	)	)	PUNCT
eurjchem-870	36	17	24‐32	24‐32	NUM
eurjchem-870	36	18	25	25	NUM
eurjchem-870	36	19	scheme	scheme	NOUN
eurjchem-870	36	20	1	1	NUM
eurjchem-870	36	21	2.2	2.2	NUM
eurjchem-870	36	22	.	.	PUNCT
eurjchem-870	37	1	synthesis	synthesis	NOUN
eurjchem-870	37	2	2.2.1	2.2.1	NUM
eurjchem-870	37	3	.	.	PUNCT
eurjchem-870	38	1	1,3‐diphenyl‐1h‐pyrazol‐5(4h)‐one	1,3‐diphenyl‐1h‐pyrazol‐5(4h)‐one	NUM
eurjchem-870	38	2	(	(	PUNCT
eurjchem-870	38	3	3	3	NUM
eurjchem-870	38	4	)	)	PUNCT
eurjchem-870	38	5	a	a	DET
eurjchem-870	38	6	mixture	mixture	NOUN
eurjchem-870	38	7	of	of	ADP
eurjchem-870	38	8	phenyl	phenyl	NOUN
eurjchem-870	38	9	hydrazine	hydrazine	NOUN
eurjchem-870	38	10	(	(	PUNCT
eurjchem-870	38	11	1	1	NUM
eurjchem-870	38	12	)	)	PUNCT
eurjchem-870	38	13	(	(	PUNCT
eurjchem-870	38	14	10.8	10.8	NUM
eurjchem-870	38	15	 	 	SPACE
eurjchem-870	38	16	ml	ml	NOUN
eurjchem-870	38	17	,	,	PUNCT
eurjchem-870	38	18	0.1	0.1	NUM
eurjchem-870	38	19	mol	mol	NOUN
eurjchem-870	38	20	)	)	PUNCT
eurjchem-870	38	21	,	,	PUNCT
eurjchem-870	38	22	ethyl	ethyl	PROPN
eurjchem-870	38	23	benzoylacetate	benzoylacetate	NOUN
eurjchem-870	38	24	(	(	PUNCT
eurjchem-870	38	25	2	2	NUM
eurjchem-870	38	26	)	)	PUNCT
eurjchem-870	38	27	(	(	PUNCT
eurjchem-870	38	28	19.2	19.2	NUM
eurjchem-870	38	29	 	 	SPACE
eurjchem-870	38	30	ml	ml	NOUN
eurjchem-870	38	31	,	,	PUNCT
eurjchem-870	38	32	0.1	0.1	NUM
eurjchem-870	38	33	 	 	SPACE
eurjchem-870	38	34	mol	mol	NOUN
eurjchem-870	38	35	)	)	PUNCT
eurjchem-870	38	36	in	in	ADP
eurjchem-870	38	37	acetic	acetic	ADJ
eurjchem-870	38	38	acid	acid	NOUN
eurjchem-870	38	39	(	(	PUNCT
eurjchem-870	38	40	50	50	NUM
eurjchem-870	38	41	 	 	SPACE
eurjchem-870	38	42	ml	ml	NOUN
eurjchem-870	38	43	)	)	PUNCT
eurjchem-870	38	44	was	be	AUX
eurjchem-870	38	45	refluxed	refluxe	VERB
eurjchem-870	38	46	for	for	ADP
eurjchem-870	38	47	4	4	NUM
eurjchem-870	38	48	 	 	SPACE
eurjchem-870	38	49	h	h	NOUN
eurjchem-870	38	50	,	,	PUNCT
eurjchem-870	38	51	and	and	CCONJ
eurjchem-870	38	52	left	leave	VERB
eurjchem-870	38	53	to	to	PART
eurjchem-870	38	54	cool	cool	ADJ
eurjchem-870	38	55	.	.	PUNCT
eurjchem-870	39	1	the	the	DET
eurjchem-870	39	2	separated	separate	VERB
eurjchem-870	39	3	solid	solid	ADJ
eurjchem-870	39	4	was	be	AUX
eurjchem-870	39	5	filtered	filter	VERB
eurjchem-870	39	6	off	off	ADP
eurjchem-870	39	7	,	,	PUNCT
eurjchem-870	39	8	washed	wash	VERB
eurjchem-870	39	9	with	with	ADP
eurjchem-870	39	10	ethanol	ethanol	NOUN
eurjchem-870	39	11	,	,	PUNCT
eurjchem-870	39	12	dried	dry	VERB
eurjchem-870	39	13	and	and	CCONJ
eurjchem-870	39	14	recrystallized	recrystallize	VERB
eurjchem-870	39	15	from	from	ADP
eurjchem-870	39	16	acetic	acetic	ADJ
eurjchem-870	39	17	acid	acid	NOUN
eurjchem-870	39	18	.	.	PUNCT
eurjchem-870	40	1	color	color	NOUN
eurjchem-870	40	2	:	:	PUNCT
eurjchem-870	40	3	yellow	yellow	ADJ
eurjchem-870	40	4	.	.	PUNCT
eurjchem-870	41	1	yield	yield	NOUN
eurjchem-870	41	2	:	:	PUNCT
eurjchem-870	41	3	90	90	NUM
eurjchem-870	41	4	%	%	NOUN
eurjchem-870	41	5	.	.	PUNCT
eurjchem-870	42	1	m.p	m.p	PROPN
eurjchem-870	42	2	.	.	PROPN
eurjchem-870	42	3	:	:	PUNCT
eurjchem-870	43	1	138‐140	138‐140	NUM
eurjchem-870	43	2	°	°	PROPN
eurjchem-870	43	3	c	c	X
eurjchem-870	43	4	(	(	PUNCT
eurjchem-870	43	5	lit	lit	ADJ
eurjchem-870	43	6	.	.	PUNCT
eurjchem-870	44	1	[	[	X
eurjchem-870	44	2	15	15	NUM
eurjchem-870	44	3	]	]	PUNCT
eurjchem-870	44	4	,	,	PUNCT
eurjchem-870	44	5	135	135	NUM
eurjchem-870	44	6	°	°	NOUN
eurjchem-870	44	7	c	c	NOUN
eurjchem-870	44	8	)	)	PUNCT
eurjchem-870	44	9	.	.	PUNCT
eurjchem-870	45	1	ft‐ir	ft‐ir	NOUN
eurjchem-870	45	2	(	(	PUNCT
eurjchem-870	45	3	kbr	kbr	PROPN
eurjchem-870	45	4	,	,	PUNCT
eurjchem-870	45	5			PROPN
eurjchem-870	45	6	,	,	PUNCT
eurjchem-870	45	7	cm‐1	cm‐1	PROPN
eurjchem-870	45	8	):	):	PUNCT
eurjchem-870	45	9	3055	3055	NUM
eurjchem-870	45	10	(	(	PUNCT
eurjchem-870	45	11	ch	ch	NOUN
eurjchem-870	45	12	aromatic	aromatic	NOUN
eurjchem-870	45	13	)	)	PUNCT
eurjchem-870	45	14	,	,	PUNCT
eurjchem-870	45	15	2954	2954	NUM
eurjchem-870	45	16	,	,	PUNCT
eurjchem-870	45	17	2911	2911	NUM
eurjchem-870	45	18	(	(	PUNCT
eurjchem-870	45	19	ch	ch	NOUN
eurjchem-870	45	20	aliphatic	aliphatic	PROPN
eurjchem-870	45	21	)	)	PUNCT
eurjchem-870	45	22	,	,	PUNCT
eurjchem-870	45	23	1706	1706	NUM
eurjchem-870	45	24	(	(	PUNCT
eurjchem-870	45	25	c	c	NOUN
eurjchem-870	45	26	=	=	NOUN
eurjchem-870	45	27	o	o	NOUN
eurjchem-870	45	28	)	)	PUNCT
eurjchem-870	45	29	.	.	PUNCT
eurjchem-870	46	1	1h	1h	NUM
eurjchem-870	46	2	nmr	nmr	NOUN
eurjchem-870	46	3	(	(	PUNCT
eurjchem-870	46	4	300	300	NUM
eurjchem-870	46	5	mhz	mhz	NOUN
eurjchem-870	46	6	,	,	PUNCT
eurjchem-870	46	7	cdcl3	cdcl3	PROPN
eurjchem-870	46	8	,	,	PUNCT
eurjchem-870	46	9	δ	δ	PROPN
eurjchem-870	46	10	,	,	PUNCT
eurjchem-870	46	11	ppm	ppm	NOUN
eurjchem-870	46	12	):	):	PUNCT
eurjchem-870	46	13	7.94	7.94	NUM
eurjchem-870	46	14	(	(	PUNCT
eurjchem-870	46	15	d	d	PROPN
eurjchem-870	46	16	,	,	PUNCT
eurjchem-870	46	17	2h	2h	NUM
eurjchem-870	46	18	,	,	PUNCT
eurjchem-870	46	19	arh	arh	ADJ
eurjchem-870	46	20	)	)	PUNCT
eurjchem-870	46	21	,	,	PUNCT
eurjchem-870	46	22	7.80	7.80	NUM
eurjchem-870	46	23	(	(	PUNCT
eurjchem-870	46	24	d	d	PROPN
eurjchem-870	46	25	,	,	PUNCT
eurjchem-870	46	26	2h	2h	NUM
eurjchem-870	46	27	,	,	PUNCT
eurjchem-870	46	28	arh	arh	ADJ
eurjchem-870	46	29	)	)	PUNCT
eurjchem-870	46	30	,	,	PUNCT
eurjchem-870	46	31	7.34‐7.53	7.34‐7.53	NUM
eurjchem-870	46	32	(	(	PUNCT
eurjchem-870	46	33	m	m	PROPN
eurjchem-870	46	34	,	,	PUNCT
eurjchem-870	46	35	4h	4h	NUM
eurjchem-870	46	36	,	,	PUNCT
eurjchem-870	46	37	arh	arh	PROPN
eurjchem-870	46	38	)	)	PUNCT
eurjchem-870	46	39	,	,	PUNCT
eurjchem-870	46	40	7.42	7.42	NUM
eurjchem-870	46	41	(	(	PUNCT
eurjchem-870	46	42	t	t	PROPN
eurjchem-870	46	43	,	,	PUNCT
eurjchem-870	46	44	2h	2h	NUM
eurjchem-870	46	45	,	,	PUNCT
eurjchem-870	46	46	arh	arh	ADJ
eurjchem-870	46	47	)	)	PUNCT
eurjchem-870	46	48	,	,	PUNCT
eurjchem-870	46	49	3.87	3.87	NUM
eurjchem-870	46	50	(	(	PUNCT
eurjchem-870	46	51	s	s	PROPN
eurjchem-870	46	52	,	,	PUNCT
eurjchem-870	46	53	2h	2h	NUM
eurjchem-870	46	54	,	,	PUNCT
eurjchem-870	46	55	ch2	ch2	PROPN
eurjchem-870	46	56	)	)	PUNCT
eurjchem-870	46	57	.	.	PUNCT
eurjchem-870	47	1	ms	ms	NOUN
eurjchem-870	47	2	(	(	PUNCT
eurjchem-870	47	3	ei	ei	PROPN
eurjchem-870	47	4	,	,	PUNCT
eurjchem-870	47	5	m	m	PROPN
eurjchem-870	47	6	/	/	SYM
eurjchem-870	47	7	z	z	PROPN
eurjchem-870	47	8	(	(	PUNCT
eurjchem-870	47	9	%	%	NOUN
eurjchem-870	47	10	)	)	PUNCT
eurjchem-870	47	11	):	):	PUNCT
eurjchem-870	47	12	236	236	NUM
eurjchem-870	47	13	(	(	PUNCT
eurjchem-870	47	14	m+	m+	NOUN
eurjchem-870	47	15	·	·	SYM
eurjchem-870	47	16	,	,	PUNCT
eurjchem-870	47	17	100	100	NUM
eurjchem-870	47	18	)	)	PUNCT
eurjchem-870	47	19	,	,	PUNCT
eurjchem-870	47	20	194	194	NUM
eurjchem-870	47	21	(	(	PUNCT
eurjchem-870	47	22	10.51	10.51	NUM
eurjchem-870	47	23	)	)	PUNCT
eurjchem-870	47	24	,	,	PUNCT
eurjchem-870	47	25	105	105	NUM
eurjchem-870	47	26	(	(	PUNCT
eurjchem-870	47	27	29.76	29.76	NUM
eurjchem-870	47	28	)	)	PUNCT
eurjchem-870	47	29	,	,	PUNCT
eurjchem-870	47	30	103	103	NUM
eurjchem-870	47	31	(	(	PUNCT
eurjchem-870	47	32	63.39	63.39	NUM
eurjchem-870	47	33	)	)	PUNCT
eurjchem-870	47	34	,	,	PUNCT
eurjchem-870	47	35	91	91	NUM
eurjchem-870	47	36	(	(	PUNCT
eurjchem-870	47	37	53.48	53.48	NUM
eurjchem-870	47	38	)	)	PUNCT
eurjchem-870	47	39	,	,	PUNCT
eurjchem-870	47	40	78	78	NUM
eurjchem-870	47	41	(	(	PUNCT
eurjchem-870	47	42	7.19	7.19	NUM
eurjchem-870	47	43	)	)	PUNCT
eurjchem-870	47	44	,	,	PUNCT
eurjchem-870	47	45	77	77	NUM
eurjchem-870	47	46	(	(	PUNCT
eurjchem-870	47	47	84.85	84.85	NUM
eurjchem-870	47	48	)	)	PUNCT
eurjchem-870	47	49	.	.	PUNCT
eurjchem-870	48	1	anal	anal	PROPN
eurjchem-870	48	2	.	.	PUNCT
eurjchem-870	48	3	calcd	calcd	NOUN
eurjchem-870	48	4	.	.	PUNCT
eurjchem-870	49	1	for	for	SCONJ
eurjchem-870	49	2	c15h12n2o	c15h12n2o	NOUN
eurjchem-870	49	3	:	:	PUNCT
eurjchem-870	49	4	c	c	X
eurjchem-870	49	5	,	,	PUNCT
eurjchem-870	49	6	76.25	76.25	NUM
eurjchem-870	49	7	;	;	PUNCT
eurjchem-870	49	8	h	h	NOUN
eurjchem-870	49	9	,	,	PUNCT
eurjchem-870	49	10	5.12	5.12	NUM
eurjchem-870	49	11	;	;	PUNCT
eurjchem-870	49	12	n	n	CCONJ
eurjchem-870	49	13	,	,	PUNCT
eurjchem-870	49	14	11.86	11.86	NUM
eurjchem-870	49	15	.	.	PUNCT
eurjchem-870	49	16	found	find	VERB
eurjchem-870	49	17	:	:	PUNCT
eurjchem-870	50	1	c	c	X
eurjchem-870	50	2	,	,	PUNCT
eurjchem-870	50	3	76.36	76.36	NUM
eurjchem-870	50	4	;	;	PUNCT
eurjchem-870	50	5	h	h	NOUN
eurjchem-870	50	6	,	,	PUNCT
eurjchem-870	50	7	5.14	5.14	NUM
eurjchem-870	50	8	;	;	PUNCT
eurjchem-870	50	9	n	n	CCONJ
eurjchem-870	50	10	,	,	PUNCT
eurjchem-870	50	11	12.01	12.01	NUM
eurjchem-870	50	12	%	%	NOUN
eurjchem-870	50	13	.	.	PUNCT
eurjchem-870	51	1	2.2.2	2.2.2	X
eurjchem-870	51	2	.	.	PUNCT
eurjchem-870	52	1	6‐amino‐4‐(4‐methoxyphenyl)‐1,3‐diphenyl‐1h‐	6‐amino‐4‐(4‐methoxyphenyl)‐1,3‐diphenyl‐1h‐	NUM
eurjchem-870	52	2	pyrazolo[3,4‐b]pyridine‐5‐carbonitrile	pyrazolo[3,4‐b]pyridine‐5‐carbonitrile	ADJ
eurjchem-870	52	3	(	(	PUNCT
eurjchem-870	52	4	4	4	NUM
eurjchem-870	52	5	)	)	PUNCT
eurjchem-870	52	6	a	a	DET
eurjchem-870	52	7	mixture	mixture	NOUN
eurjchem-870	52	8	of	of	ADP
eurjchem-870	52	9	pyrazolone	pyrazolone	NOUN
eurjchem-870	52	10	3	3	NUM
eurjchem-870	52	11	(	(	PUNCT
eurjchem-870	52	12	2.36	2.36	NUM
eurjchem-870	52	13	 	 	SPACE
eurjchem-870	52	14	g	g	NOUN
eurjchem-870	52	15	,	,	PUNCT
eurjchem-870	52	16	0.01	0.01	NUM
eurjchem-870	52	17	 	 	SPACE
eurjchem-870	52	18	mol	mol	NUM
eurjchem-870	52	19	)	)	PUNCT
eurjchem-870	52	20	,	,	PUNCT
eurjchem-870	52	21	malononitrile	malononitrile	NOUN
eurjchem-870	52	22	(	(	PUNCT
eurjchem-870	52	23	0.66	0.66	NUM
eurjchem-870	52	24	 	 	SPACE
eurjchem-870	52	25	g	g	NOUN
eurjchem-870	52	26	,	,	PUNCT
eurjchem-870	52	27	0.01	0.01	NUM
eurjchem-870	52	28	 	 	SPACE
eurjchem-870	52	29	mol	mol	NUM
eurjchem-870	52	30	)	)	PUNCT
eurjchem-870	52	31	,	,	PUNCT
eurjchem-870	52	32	ammonium	ammonium	NOUN
eurjchem-870	52	33	acetate	acetate	NOUN
eurjchem-870	52	34	(	(	PUNCT
eurjchem-870	52	35	2.31	2.31	NUM
eurjchem-870	52	36	 	 	SPACE
eurjchem-870	52	37	g	g	NOUN
eurjchem-870	52	38	,	,	PUNCT
eurjchem-870	52	39	0.03	0.03	NUM
eurjchem-870	52	40	 	 	SPACE
eurjchem-870	52	41	mol	mol	NOUN
eurjchem-870	52	42	,	,	PUNCT
eurjchem-870	52	43	)	)	PUNCT
eurjchem-870	52	44	,	,	PUNCT
eurjchem-870	52	45	and	and	CCONJ
eurjchem-870	52	46	p‐	p‐	PROPN
eurjchem-870	52	47	anisaldehyde	anisaldehyde	NOUN
eurjchem-870	52	48	(	(	PUNCT
eurjchem-870	52	49	1.36	1.36	NUM
eurjchem-870	52	50	 	 	SPACE
eurjchem-870	52	51	ml	ml	NOUN
eurjchem-870	52	52	,	,	PUNCT
eurjchem-870	52	53	0.01	0.01	NUM
eurjchem-870	52	54	 	 	SPACE
eurjchem-870	52	55	mol	mol	NOUN
eurjchem-870	52	56	)	)	PUNCT
eurjchem-870	52	57	was	be	AUX
eurjchem-870	52	58	fused	fuse	VERB
eurjchem-870	52	59	for	for	ADP
eurjchem-870	52	60	15	15	NUM
eurjchem-870	52	61	 	 	SPACE
eurjchem-870	52	62	h	h	NOUN
eurjchem-870	52	63	at	at	ADP
eurjchem-870	52	64	140‐170	140‐170	NUM
eurjchem-870	52	65	°	°	ADP
eurjchem-870	52	66	c	c	NOUN
eurjchem-870	52	67	,	,	PUNCT
eurjchem-870	52	68	the	the	DET
eurjchem-870	52	69	reaction	reaction	NOUN
eurjchem-870	52	70	mixture	mixture	NOUN
eurjchem-870	52	71	was	be	AUX
eurjchem-870	52	72	poured	pour	VERB
eurjchem-870	52	73	onto	onto	ADP
eurjchem-870	52	74	water	water	NOUN
eurjchem-870	52	75	,	,	PUNCT
eurjchem-870	52	76	to	to	PART
eurjchem-870	52	77	give	give	VERB
eurjchem-870	52	78	the	the	DET
eurjchem-870	52	79	solid	solid	ADJ
eurjchem-870	52	80	product	product	NOUN
eurjchem-870	52	81	4	4	NUM
eurjchem-870	52	82	which	which	PRON
eurjchem-870	52	83	was	be	AUX
eurjchem-870	52	84	washed	wash	VERB
eurjchem-870	52	85	with	with	ADP
eurjchem-870	52	86	water	water	NOUN
eurjchem-870	52	87	(	(	PUNCT
eurjchem-870	52	88	3×30	3×30	NUM
eurjchem-870	52	89	 	 	SPACE
eurjchem-870	52	90	ml	ml	NOUN
eurjchem-870	52	91	)	)	PUNCT
eurjchem-870	52	92	,	,	PUNCT
eurjchem-870	52	93	dried	dry	VERB
eurjchem-870	52	94	,	,	PUNCT
eurjchem-870	52	95	and	and	CCONJ
eurjchem-870	52	96	recrystallized	recrystallize	VERB
eurjchem-870	52	97	from	from	ADP
eurjchem-870	52	98	benzene	benzene	NOUN
eurjchem-870	52	99	:	:	PUNCT
eurjchem-870	52	100	ethanol	ethanol	NOUN
eurjchem-870	52	101	(	(	PUNCT
eurjchem-870	52	102	2:1	2:1	NUM
eurjchem-870	52	103	)	)	PUNCT
eurjchem-870	52	104	(	(	PUNCT
eurjchem-870	52	105	scheme	scheme	NOUN
eurjchem-870	52	106	1	1	NUM
eurjchem-870	52	107	)	)	PUNCT
eurjchem-870	52	108	.	.	PUNCT
eurjchem-870	53	1	color	color	NOUN
eurjchem-870	53	2	:	:	PUNCT
eurjchem-870	53	3	brown	brown	ADJ
eurjchem-870	53	4	.	.	PUNCT
eurjchem-870	54	1	yield	yield	NOUN
eurjchem-870	54	2	:	:	PUNCT
eurjchem-870	54	3	86.3	86.3	NUM
eurjchem-870	54	4	%	%	NOUN
eurjchem-870	54	5	.	.	PUNCT
eurjchem-870	55	1	m.p	m.p	PROPN
eurjchem-870	55	2	.	.	PROPN
eurjchem-870	55	3	:	:	PUNCT
eurjchem-870	56	1	248‐250	248‐250	NUM
eurjchem-870	56	2	°	°	PROPN
eurjchem-870	56	3	c	c	X
eurjchem-870	56	4	.	.	PUNCT
eurjchem-870	56	5	ft‐ir	ft‐ir	NOUN
eurjchem-870	56	6	(	(	PUNCT
eurjchem-870	56	7	kbr	kbr	PROPN
eurjchem-870	56	8	,	,	PUNCT
eurjchem-870	56	9			PROPN
eurjchem-870	56	10	,	,	PUNCT
eurjchem-870	56	11	cm‐1	cm‐1	PROPN
eurjchem-870	56	12	):	):	PUNCT
eurjchem-870	56	13	3451	3451	NUM
eurjchem-870	56	14	,	,	PUNCT
eurjchem-870	56	15	3338	3338	NUM
eurjchem-870	56	16	(	(	PUNCT
eurjchem-870	56	17	nh2	nh2	PROPN
eurjchem-870	56	18	)	)	PUNCT
eurjchem-870	56	19	,	,	PUNCT
eurjchem-870	56	20	2202	2202	NUM
eurjchem-870	56	21	(	(	PUNCT
eurjchem-870	56	22	c≡n	c≡n	PROPN
eurjchem-870	56	23	)	)	PUNCT
eurjchem-870	56	24	,	,	PUNCT
eurjchem-870	56	25	1604	1604	NUM
eurjchem-870	56	26	(	(	PUNCT
eurjchem-870	56	27	c	c	NOUN
eurjchem-870	56	28	=	=	SYM
eurjchem-870	56	29	n	n	NUM
eurjchem-870	56	30	)	)	PUNCT
eurjchem-870	56	31	.	.	PUNCT
eurjchem-870	57	1	1h	1h	NUM
eurjchem-870	57	2	nmr	nmr	NOUN
eurjchem-870	57	3	(	(	PUNCT
eurjchem-870	57	4	300	300	NUM
eurjchem-870	57	5	mhz	mhz	NOUN
eurjchem-870	57	6	,	,	PUNCT
eurjchem-870	57	7	dmso	dmso	NOUN
eurjchem-870	57	8	,	,	PUNCT
eurjchem-870	57	9	δ	δ	PROPN
eurjchem-870	57	10	,	,	PUNCT
eurjchem-870	57	11	ppm	ppm	NOUN
eurjchem-870	57	12	)	)	PUNCT
eurjchem-870	57	13	,	,	PUNCT
eurjchem-870	57	14	δ	δ	PROPN
eurjchem-870	57	15	:	:	PUNCT
eurjchem-870	57	16	7.06‐7.14	7.06‐7.14	NUM
eurjchem-870	57	17	(	(	PUNCT
eurjchem-870	57	18	m	m	PROPN
eurjchem-870	57	19	,	,	PUNCT
eurjchem-870	57	20	14h	14h	NUM
eurjchem-870	57	21	,	,	PUNCT
eurjchem-870	57	22	arh	arh	PROPN
eurjchem-870	57	23	)	)	PUNCT
eurjchem-870	57	24	,	,	PUNCT
eurjchem-870	57	25	5.02	5.02	NUM
eurjchem-870	57	26	(	(	PUNCT
eurjchem-870	57	27	s	s	PROPN
eurjchem-870	57	28	,	,	PUNCT
eurjchem-870	57	29	2h	2h	NUM
eurjchem-870	57	30	,	,	PUNCT
eurjchem-870	57	31	nh2	nh2	PROPN
eurjchem-870	57	32	d2o	d2o	PROPN
eurjchem-870	57	33	exchangeable	exchangeable	ADJ
eurjchem-870	57	34	)	)	PUNCT
eurjchem-870	57	35	,	,	PUNCT
eurjchem-870	57	36	3.82	3.82	NUM
eurjchem-870	57	37	(	(	PUNCT
eurjchem-870	57	38	s	s	PROPN
eurjchem-870	57	39	,	,	PUNCT
eurjchem-870	57	40	3h	3h	NUM
eurjchem-870	57	41	,	,	PUNCT
eurjchem-870	57	42	och3	och3	ADJ
eurjchem-870	57	43	)	)	PUNCT
eurjchem-870	57	44	.	.	PUNCT
eurjchem-870	58	1	ms	ms	NOUN
eurjchem-870	58	2	(	(	PUNCT
eurjchem-870	58	3	ei	ei	PROPN
eurjchem-870	58	4	,	,	PUNCT
eurjchem-870	58	5	m	m	PROPN
eurjchem-870	58	6	/	/	SYM
eurjchem-870	58	7	z	z	PROPN
eurjchem-870	58	8	(	(	PUNCT
eurjchem-870	58	9	%	%	NOUN
eurjchem-870	58	10	)	)	PUNCT
eurjchem-870	58	11	):	):	PUNCT
eurjchem-870	58	12	417	417	NUM
eurjchem-870	58	13	(	(	PUNCT
eurjchem-870	58	14	m+	m+	NUM
eurjchem-870	58	15	·	·	SYM
eurjchem-870	58	16	,	,	PUNCT
eurjchem-870	58	17	0.80	0.80	NUM
eurjchem-870	58	18	)	)	PUNCT
eurjchem-870	58	19	,	,	PUNCT
eurjchem-870	58	20	330	330	NUM
eurjchem-870	58	21	(	(	PUNCT
eurjchem-870	58	22	74.22	74.22	NUM
eurjchem-870	58	23	)	)	PUNCT
eurjchem-870	58	24	,	,	PUNCT
eurjchem-870	58	25	287	287	NUM
eurjchem-870	58	26	(	(	PUNCT
eurjchem-870	58	27	24.48	24.48	NUM
eurjchem-870	58	28	)	)	PUNCT
eurjchem-870	58	29	,	,	PUNCT
eurjchem-870	58	30	121	121	NUM
eurjchem-870	58	31	(	(	PUNCT
eurjchem-870	58	32	100	100	NUM
eurjchem-870	58	33	)	)	PUNCT
eurjchem-870	58	34	,	,	PUNCT
eurjchem-870	58	35	77	77	NUM
eurjchem-870	58	36	(	(	PUNCT
eurjchem-870	58	37	32.72	32.72	NUM
eurjchem-870	58	38	)	)	PUNCT
eurjchem-870	58	39	.	.	PUNCT
eurjchem-870	59	1	anal	anal	PROPN
eurjchem-870	59	2	.	.	PUNCT
eurjchem-870	59	3	calcd	calcd	NOUN
eurjchem-870	59	4	.	.	PUNCT
eurjchem-870	60	1	for	for	ADP
eurjchem-870	60	2	c26h19n5o	c26h19n5o	NOUN
eurjchem-870	60	3	:	:	PUNCT
eurjchem-870	60	4	c	c	X
eurjchem-870	60	5	,	,	PUNCT
eurjchem-870	60	6	74.80	74.80	NUM
eurjchem-870	60	7	;	;	PUNCT
eurjchem-870	60	8	h	h	NOUN
eurjchem-870	60	9	,	,	PUNCT
eurjchem-870	60	10	4.59	4.59	NUM
eurjchem-870	60	11	;	;	PUNCT
eurjchem-870	60	12	n	n	CCONJ
eurjchem-870	60	13	,	,	PUNCT
eurjchem-870	60	14	16.78	16.78	NUM
eurjchem-870	60	15	.	.	PUNCT
eurjchem-870	60	16	found	find	VERB
eurjchem-870	60	17	:	:	PUNCT
eurjchem-870	61	1	c	c	X
eurjchem-870	61	2	,	,	PUNCT
eurjchem-870	61	3	74.95	74.95	NUM
eurjchem-870	61	4	;	;	PUNCT
eurjchem-870	61	5	h	h	NOUN
eurjchem-870	61	6	,	,	PUNCT
eurjchem-870	61	7	4.72	4.72	NUM
eurjchem-870	61	8	;	;	PUNCT
eurjchem-870	61	9	n	n	CCONJ
eurjchem-870	61	10	,	,	PUNCT
eurjchem-870	61	11	16.68	16.68	NUM
eurjchem-870	61	12	%	%	NOUN
eurjchem-870	61	13	.	.	PUNCT
eurjchem-870	62	1	2.2.3	2.2.3	NUM
eurjchem-870	62	2	.	.	NOUN
eurjchem-870	62	3	6‐amino‐4‐(4‐methoxyphenyl)‐1,3‐diphenyl‐1,4‐	6‐amino‐4‐(4‐methoxyphenyl)‐1,3‐diphenyl‐1,4‐	NUM
eurjchem-870	62	4	dihydropyrano[2,3‐c]pyrazole‐5‐carbonitrile	dihydropyrano[2,3‐c]pyrazole‐5‐carbonitrile	NOUN
eurjchem-870	62	5	(	(	PUNCT
eurjchem-870	62	6	5	5	NUM
eurjchem-870	62	7	)	)	PUNCT
eurjchem-870	62	8	method	method	NOUN
eurjchem-870	62	9	a	a	PRON
eurjchem-870	62	10	:	:	PUNCT
eurjchem-870	62	11	a	a	DET
eurjchem-870	62	12	mixture	mixture	NOUN
eurjchem-870	62	13	of	of	ADP
eurjchem-870	62	14	pyrazolone	pyrazolone	NOUN
eurjchem-870	62	15	3	3	NUM
eurjchem-870	62	16	(	(	PUNCT
eurjchem-870	62	17	2.36	2.36	NUM
eurjchem-870	62	18	 	 	SPACE
eurjchem-870	62	19	g	g	NOUN
eurjchem-870	62	20	,	,	PUNCT
eurjchem-870	62	21	0.01	0.01	NUM
eurjchem-870	62	22	 	 	SPACE
eurjchem-870	62	23	mol	mol	NUM
eurjchem-870	62	24	)	)	PUNCT
eurjchem-870	62	25	,	,	PUNCT
eurjchem-870	62	26	malononitrile	malononitrile	NOUN
eurjchem-870	62	27	(	(	PUNCT
eurjchem-870	62	28	0.66	0.66	NUM
eurjchem-870	62	29	 	 	SPACE
eurjchem-870	62	30	g	g	NOUN
eurjchem-870	62	31	,	,	PUNCT
eurjchem-870	62	32	0.01	0.01	NUM
eurjchem-870	62	33	 	 	SPACE
eurjchem-870	62	34	mol	mol	NOUN
eurjchem-870	62	35	)	)	PUNCT
eurjchem-870	62	36	,	,	PUNCT
eurjchem-870	62	37	and	and	CCONJ
eurjchem-870	62	38	p‐anisaldehyde	p‐anisaldehyde	X
eurjchem-870	62	39	(	(	PUNCT
eurjchem-870	62	40	1.36	1.36	NUM
eurjchem-870	62	41	 	 	SPACE
eurjchem-870	62	42	ml	ml	NOUN
eurjchem-870	62	43	,	,	PUNCT
eurjchem-870	62	44	0.01	0.01	NUM
eurjchem-870	62	45	 	 	SPACE
eurjchem-870	62	46	mol	mol	NUM
eurjchem-870	62	47	)	)	PUNCT
eurjchem-870	62	48	in	in	ADP
eurjchem-870	62	49	presence	presence	NOUN
eurjchem-870	62	50	of	of	ADP
eurjchem-870	62	51	1	1	NUM
eurjchem-870	62	52	 	 	SPACE
eurjchem-870	62	53	ml	ml	NOUN
eurjchem-870	62	54	piperidine	piperidine	NOUN
eurjchem-870	62	55	was	be	AUX
eurjchem-870	62	56	fused	fuse	VERB
eurjchem-870	62	57	for	for	ADP
eurjchem-870	62	58	15	15	NUM
eurjchem-870	62	59	 	 	SPACE
eurjchem-870	62	60	h	h	NOUN
eurjchem-870	62	61	at	at	ADP
eurjchem-870	62	62	140	140	NUM
eurjchem-870	62	63	°	°	NOUN
eurjchem-870	62	64	c	c	NOUN
eurjchem-870	62	65	.	.	PUNCT
eurjchem-870	63	1	after	after	ADP
eurjchem-870	63	2	cooling	cool	VERB
eurjchem-870	63	3	,	,	PUNCT
eurjchem-870	63	4	the	the	DET
eurjchem-870	63	5	solid	solid	ADJ
eurjchem-870	63	6	product	product	NOUN
eurjchem-870	63	7	was	be	AUX
eurjchem-870	63	8	washed	wash	VERB
eurjchem-870	63	9	with	with	ADP
eurjchem-870	63	10	ethanol	ethanol	NOUN
eurjchem-870	63	11	,	,	PUNCT
eurjchem-870	63	12	filtered	filter	VERB
eurjchem-870	63	13	off	off	ADP
eurjchem-870	63	14	,	,	PUNCT
eurjchem-870	63	15	dried	dry	VERB
eurjchem-870	63	16	,	,	PUNCT
eurjchem-870	63	17	and	and	CCONJ
eurjchem-870	63	18	crystallized	crystallize	VERB
eurjchem-870	63	19	from	from	ADP
eurjchem-870	63	20	benzene	benzene	NOUN
eurjchem-870	63	21	:	:	PUNCT
eurjchem-870	63	22	ethanol	ethanol	NOUN
eurjchem-870	63	23	(	(	PUNCT
eurjchem-870	63	24	2:1	2:1	NUM
eurjchem-870	63	25	)	)	PUNCT
eurjchem-870	63	26	(	(	PUNCT
eurjchem-870	63	27	scheme	scheme	NOUN
eurjchem-870	63	28	1	1	NUM
eurjchem-870	63	29	)	)	PUNCT
eurjchem-870	63	30	.	.	PUNCT
eurjchem-870	64	1	color	color	NOUN
eurjchem-870	64	2	:	:	PUNCT
eurjchem-870	64	3	brown	brown	ADJ
eurjchem-870	64	4	.	.	PUNCT
eurjchem-870	65	1	yield	yield	NOUN
eurjchem-870	65	2	:	:	PUNCT
eurjchem-870	65	3	14	14	NUM
eurjchem-870	65	4	%	%	NOUN
eurjchem-870	65	5	.	.	PUNCT
eurjchem-870	66	1	m.p	m.p	PROPN
eurjchem-870	66	2	.	.	PROPN
eurjchem-870	66	3	:	:	PUNCT
eurjchem-870	67	1	288‐	288‐	NUM
eurjchem-870	67	2	290	290	NUM
eurjchem-870	67	3	°	°	SYM
eurjchem-870	67	4	c	c	NOUN
eurjchem-870	67	5	.	.	PUNCT
eurjchem-870	68	1	ft‐ir	ft‐ir	NOUN
eurjchem-870	68	2	(	(	PUNCT
eurjchem-870	68	3	kbr	kbr	PROPN
eurjchem-870	68	4	,	,	PUNCT
eurjchem-870	68	5			PROPN
eurjchem-870	68	6	,	,	PUNCT
eurjchem-870	68	7	cm‐1	cm‐1	PROPN
eurjchem-870	68	8	):	):	PUNCT
eurjchem-870	68	9	3400	3400	NUM
eurjchem-870	68	10	,	,	PUNCT
eurjchem-870	68	11	3376	3376	NUM
eurjchem-870	68	12	(	(	PUNCT
eurjchem-870	68	13	nh2	nh2	PROPN
eurjchem-870	68	14	)	)	PUNCT
eurjchem-870	68	15	,	,	PUNCT
eurjchem-870	68	16	2206	2206	NUM
eurjchem-870	68	17	(	(	PUNCT
eurjchem-870	68	18	c≡n	c≡n	PROPN
eurjchem-870	68	19	)	)	PUNCT
eurjchem-870	68	20	,	,	PUNCT
eurjchem-870	68	21	1600	1600	NUM
eurjchem-870	68	22	(	(	PUNCT
eurjchem-870	68	23	c	c	NOUN
eurjchem-870	68	24	=	=	SYM
eurjchem-870	68	25	n	n	NUM
eurjchem-870	68	26	)	)	PUNCT
eurjchem-870	68	27	.	.	PUNCT
eurjchem-870	69	1	1h	1h	NUM
eurjchem-870	69	2	nmr	nmr	NOUN
eurjchem-870	69	3	(	(	PUNCT
eurjchem-870	69	4	300	300	NUM
eurjchem-870	69	5	mhz	mhz	NOUN
eurjchem-870	69	6	,	,	PUNCT
eurjchem-870	69	7	dmso	dmso	NOUN
eurjchem-870	69	8	,	,	PUNCT
eurjchem-870	69	9	δ	δ	PROPN
eurjchem-870	69	10	,	,	PUNCT
eurjchem-870	69	11	ppm	ppm	NUM
eurjchem-870	69	12	):	):	PUNCT
eurjchem-870	69	13	6.97‐7.44	6.97‐7.44	NUM
eurjchem-870	69	14	(	(	PUNCT
eurjchem-870	69	15	m	m	PROPN
eurjchem-870	69	16	,	,	PUNCT
eurjchem-870	69	17	16h	16h	NUM
eurjchem-870	69	18	,	,	PUNCT
eurjchem-870	69	19	14arh	14arh	INTJ
eurjchem-870	69	20	,	,	PUNCT
eurjchem-870	69	21	nh2	nh2	PROPN
eurjchem-870	69	22	)	)	PUNCT
eurjchem-870	69	23	,	,	PUNCT
eurjchem-870	69	24	3.83	3.83	NUM
eurjchem-870	69	25	(	(	PUNCT
eurjchem-870	69	26	s	s	PROPN
eurjchem-870	69	27	,	,	PUNCT
eurjchem-870	69	28	1h	1h	NUM
eurjchem-870	69	29	,	,	PUNCT
eurjchem-870	69	30	benzilic	benzilic	NOUN
eurjchem-870	69	31	)	)	PUNCT
eurjchem-870	69	32	,	,	PUNCT
eurjchem-870	69	33	3.70	3.70	NUM
eurjchem-870	69	34	(	(	PUNCT
eurjchem-870	69	35	s	s	PROPN
eurjchem-870	69	36	,	,	PUNCT
eurjchem-870	69	37	3h	3h	NUM
eurjchem-870	69	38	,	,	PUNCT
eurjchem-870	69	39	och3	och3	ADJ
eurjchem-870	69	40	)	)	PUNCT
eurjchem-870	69	41	.	.	PUNCT
eurjchem-870	70	1	ms	ms	NOUN
eurjchem-870	70	2	(	(	PUNCT
eurjchem-870	70	3	ei	ei	PROPN
eurjchem-870	70	4	,	,	PUNCT
eurjchem-870	70	5	m	m	PROPN
eurjchem-870	70	6	/	/	SYM
eurjchem-870	70	7	z	z	PROPN
eurjchem-870	70	8	(	(	PUNCT
eurjchem-870	70	9	%	%	NOUN
eurjchem-870	70	10	)	)	PUNCT
eurjchem-870	70	11	):	):	PUNCT
eurjchem-870	70	12	420	420	NUM
eurjchem-870	70	13	(	(	PUNCT
eurjchem-870	70	14	6.83	6.83	NUM
eurjchem-870	70	15	,	,	PUNCT
eurjchem-870	70	16	m+	m+	NOUN
eurjchem-870	70	17	·	·	PUNCT
eurjchem-870	70	18	)	)	PUNCT
eurjchem-870	70	19	,	,	PUNCT
eurjchem-870	70	20	408	408	NUM
eurjchem-870	70	21	(	(	PUNCT
eurjchem-870	70	22	27.95	27.95	NUM
eurjchem-870	70	23	)	)	PUNCT
eurjchem-870	70	24	,	,	PUNCT
eurjchem-870	70	25	360	360	NUM
eurjchem-870	70	26	(	(	PUNCT
eurjchem-870	70	27	22.67	22.67	NUM
eurjchem-870	70	28	)	)	PUNCT
eurjchem-870	70	29	,	,	PUNCT
eurjchem-870	70	30	247	247	NUM
eurjchem-870	70	31	(	(	PUNCT
eurjchem-870	70	32	10.25	10.25	NUM
eurjchem-870	70	33	)	)	PUNCT
eurjchem-870	70	34	,	,	PUNCT
eurjchem-870	70	35	95	95	NUM
eurjchem-870	70	36	(	(	PUNCT
eurjchem-870	70	37	23.91	23.91	NUM
eurjchem-870	70	38	)	)	PUNCT
eurjchem-870	70	39	,	,	PUNCT
eurjchem-870	70	40	55	55	NUM
eurjchem-870	70	41	(	(	PUNCT
eurjchem-870	70	42	100	100	NUM
eurjchem-870	70	43	)	)	PUNCT
eurjchem-870	70	44	.	.	PUNCT
eurjchem-870	71	1	anal	anal	PROPN
eurjchem-870	71	2	.	.	PUNCT
eurjchem-870	71	3	calcd	calcd	NOUN
eurjchem-870	71	4	.	.	PUNCT
eurjchem-870	72	1	for	for	ADP
eurjchem-870	72	2	c26h20n4o2	c26h20n4o2	PROPN
eurjchem-870	72	3	:	:	PUNCT
eurjchem-870	72	4	c	c	X
eurjchem-870	72	5	,	,	PUNCT
eurjchem-870	72	6	74.27	74.27	NUM
eurjchem-870	72	7	;	;	PUNCT
eurjchem-870	72	8	h	h	NOUN
eurjchem-870	72	9	,	,	PUNCT
eurjchem-870	72	10	4.79	4.79	NUM
eurjchem-870	72	11	;	;	PUNCT
eurjchem-870	72	12	n	n	CCONJ
eurjchem-870	72	13	,	,	PUNCT
eurjchem-870	72	14	13.33	13.33	NUM
eurjchem-870	72	15	.	.	PUNCT
eurjchem-870	72	16	found	find	VERB
eurjchem-870	72	17	:	:	PUNCT
eurjchem-870	73	1	c	c	X
eurjchem-870	73	2	,	,	PUNCT
eurjchem-870	73	3	74.41	74.41	NUM
eurjchem-870	73	4	;	;	PUNCT
eurjchem-870	73	5	h	h	NOUN
eurjchem-870	73	6	,	,	PUNCT
eurjchem-870	73	7	4.98	4.98	NUM
eurjchem-870	73	8	;	;	PUNCT
eurjchem-870	73	9	n	n	CCONJ
eurjchem-870	73	10	,	,	PUNCT
eurjchem-870	73	11	13.54	13.54	NUM
eurjchem-870	73	12	%	%	NOUN
eurjchem-870	73	13	.	.	PUNCT
eurjchem-870	74	1	method	method	PROPN
eurjchem-870	74	2	b	b	NOUN
eurjchem-870	74	3	:	:	PUNCT
eurjchem-870	74	4	a	a	DET
eurjchem-870	74	5	mixture	mixture	NOUN
eurjchem-870	74	6	of	of	ADP
eurjchem-870	74	7	pyrazolone	pyrazolone	NOUN
eurjchem-870	74	8	3	3	NUM
eurjchem-870	74	9	(	(	PUNCT
eurjchem-870	74	10	2.36	2.36	NUM
eurjchem-870	74	11	 	 	SPACE
eurjchem-870	74	12	g	g	NOUN
eurjchem-870	74	13	,	,	PUNCT
eurjchem-870	74	14	0.01	0.01	NUM
eurjchem-870	74	15	 	 	SPACE
eurjchem-870	74	16	mol	mol	NUM
eurjchem-870	74	17	)	)	PUNCT
eurjchem-870	74	18	,	,	PUNCT
eurjchem-870	74	19	malononitrile	malononitrile	NOUN
eurjchem-870	74	20	(	(	PUNCT
eurjchem-870	74	21	0.66	0.66	NUM
eurjchem-870	74	22	 	 	SPACE
eurjchem-870	74	23	g	g	NOUN
eurjchem-870	74	24	,	,	PUNCT
eurjchem-870	74	25	0.01	0.01	NUM
eurjchem-870	74	26	 	 	SPACE
eurjchem-870	74	27	mol	mol	NOUN
eurjchem-870	74	28	)	)	PUNCT
eurjchem-870	74	29	,	,	PUNCT
eurjchem-870	74	30	and	and	CCONJ
eurjchem-870	74	31	p‐anisaldehyde	p‐anisaldehyde	X
eurjchem-870	74	32	(	(	PUNCT
eurjchem-870	74	33	1.36	1.36	NUM
eurjchem-870	74	34	 	 	SPACE
eurjchem-870	74	35	ml	ml	NOUN
eurjchem-870	74	36	,	,	PUNCT
eurjchem-870	74	37	0.01	0.01	NUM
eurjchem-870	74	38	 	 	SPACE
eurjchem-870	74	39	mol	mol	NUM
eurjchem-870	74	40	)	)	PUNCT
eurjchem-870	74	41	in	in	ADP
eurjchem-870	74	42	presence	presence	NOUN
eurjchem-870	74	43	of	of	ADP
eurjchem-870	74	44	1	1	NUM
eurjchem-870	74	45	 	 	SPACE
eurjchem-870	74	46	ml	ml	NOUN
eurjchem-870	74	47	piperidine	piperidine	NOUN
eurjchem-870	74	48	was	be	AUX
eurjchem-870	74	49	heated	heat	VERB
eurjchem-870	74	50	under	under	ADP
eurjchem-870	74	51	microwave	microwave	NOUN
eurjchem-870	74	52	irradiation	irradiation	NOUN
eurjchem-870	74	53	for	for	ADP
eurjchem-870	74	54	2	2	NUM
eurjchem-870	74	55	min	min	NOUN
eurjchem-870	74	56	,	,	PUNCT
eurjchem-870	74	57	at	at	ADP
eurjchem-870	74	58	power	power	NOUN
eurjchem-870	74	59	180	180	NUM
eurjchem-870	74	60	watt	watt	NOUN
eurjchem-870	74	61	.	.	PUNCT
eurjchem-870	75	1	after	after	ADP
eurjchem-870	75	2	cooling	cool	VERB
eurjchem-870	75	3	,	,	PUNCT
eurjchem-870	75	4	the	the	DET
eurjchem-870	75	5	solid	solid	ADJ
eurjchem-870	75	6	product	product	NOUN
eurjchem-870	75	7	was	be	AUX
eurjchem-870	75	8	washed	wash	VERB
eurjchem-870	75	9	with	with	ADP
eurjchem-870	75	10	ethanol	ethanol	NOUN
eurjchem-870	75	11	,	,	PUNCT
eurjchem-870	75	12	filtered	filter	VERB
eurjchem-870	75	13	off	off	ADP
eurjchem-870	75	14	,	,	PUNCT
eurjchem-870	75	15	dried	dry	VERB
eurjchem-870	75	16	,	,	PUNCT
eurjchem-870	75	17	and	and	CCONJ
eurjchem-870	75	18	crystallized	crystallize	VERB
eurjchem-870	75	19	from	from	ADP
eurjchem-870	75	20	benzene	benzene	NOUN
eurjchem-870	75	21	:	:	PUNCT
eurjchem-870	75	22	ethanol	ethanol	NOUN
eurjchem-870	75	23	(	(	PUNCT
eurjchem-870	75	24	2:1	2:1	NUM
eurjchem-870	75	25	)	)	PUNCT
eurjchem-870	75	26	.	.	PUNCT
eurjchem-870	76	1	2.2.4	2.2.4	NUM
eurjchem-870	76	2	.	.	X
eurjchem-870	76	3	4‐(4‐methoxyphenyl)‐6‐methyl‐1,3‐diphenyl‐1h‐	4‐(4‐methoxyphenyl)‐6‐methyl‐1,3‐diphenyl‐1h‐	NUM
eurjchem-870	76	4	pyrazolo[3,4‐b]pyridine	pyrazolo[3,4‐b]pyridine	NOUN
eurjchem-870	76	5	(	(	PUNCT
eurjchem-870	76	6	6	6	NUM
eurjchem-870	76	7	)	)	PUNCT
eurjchem-870	76	8	a	a	DET
eurjchem-870	76	9	mixture	mixture	NOUN
eurjchem-870	76	10	of	of	ADP
eurjchem-870	76	11	pyrazolone	pyrazolone	NOUN
eurjchem-870	76	12	3	3	NUM
eurjchem-870	76	13	(	(	PUNCT
eurjchem-870	76	14	2.36	2.36	NUM
eurjchem-870	76	15	 	 	SPACE
eurjchem-870	76	16	g	g	NOUN
eurjchem-870	76	17	,	,	PUNCT
eurjchem-870	76	18	0.01	0.01	NUM
eurjchem-870	76	19	 	 	SPACE
eurjchem-870	76	20	mol	mol	NUM
eurjchem-870	76	21	)	)	PUNCT
eurjchem-870	76	22	,	,	PUNCT
eurjchem-870	76	23	ethyl	ethyl	PROPN
eurjchem-870	76	24	acetoacetate	acetoacetate	NOUN
eurjchem-870	76	25	(	(	PUNCT
eurjchem-870	76	26	2.94	2.94	NUM
eurjchem-870	76	27	 	 	SPACE
eurjchem-870	76	28	ml	ml	NOUN
eurjchem-870	76	29	,	,	PUNCT
eurjchem-870	76	30	0.01	0.01	NUM
eurjchem-870	76	31	 	 	SPACE
eurjchem-870	76	32	mol	mol	NOUN
eurjchem-870	76	33	,	,	PUNCT
eurjchem-870	76	34	)	)	PUNCT
eurjchem-870	76	35	,	,	PUNCT
eurjchem-870	76	36	ammonium	ammonium	NOUN
eurjchem-870	76	37	acetate	acetate	NOUN
eurjchem-870	76	38	(	(	PUNCT
eurjchem-870	76	39	2.31	2.31	NUM
eurjchem-870	76	40	 	 	SPACE
eurjchem-870	76	41	g	g	NOUN
eurjchem-870	76	42	,	,	PUNCT
eurjchem-870	76	43	0.03	0.03	NUM
eurjchem-870	76	44	 	 	SPACE
eurjchem-870	76	45	mol	mol	NOUN
eurjchem-870	76	46	)	)	PUNCT
eurjchem-870	76	47	,	,	PUNCT
eurjchem-870	76	48	and	and	CCONJ
eurjchem-870	76	49	p‐anisaldehyde	p‐anisaldehyde	X
eurjchem-870	76	50	(	(	PUNCT
eurjchem-870	76	51	1.36	1.36	NUM
eurjchem-870	76	52	 	 	SPACE
eurjchem-870	76	53	ml	ml	NOUN
eurjchem-870	76	54	,	,	PUNCT
eurjchem-870	76	55	0.01	0.01	NUM
eurjchem-870	76	56	 	 	SPACE
eurjchem-870	76	57	mol	mol	NOUN
eurjchem-870	76	58	)	)	PUNCT
eurjchem-870	76	59	was	be	AUX
eurjchem-870	76	60	fused	fuse	VERB
eurjchem-870	76	61	for	for	ADP
eurjchem-870	76	62	15	15	NUM
eurjchem-870	76	63	 	 	SPACE
eurjchem-870	76	64	h	h	NOUN
eurjchem-870	76	65	at	at	ADP
eurjchem-870	76	66	140	140	NUM
eurjchem-870	76	67	°	°	NOUN
eurjchem-870	76	68	c	c	NOUN
eurjchem-870	76	69	.	.	PUNCT
eurjchem-870	77	1	after	after	ADP
eurjchem-870	77	2	cooling	cool	VERB
eurjchem-870	77	3	,	,	PUNCT
eurjchem-870	77	4	the	the	DET
eurjchem-870	77	5	solid	solid	ADJ
eurjchem-870	77	6	product	product	NOUN
eurjchem-870	77	7	was	be	AUX
eurjchem-870	77	8	washed	wash	VERB
eurjchem-870	77	9	with	with	ADP
eurjchem-870	77	10	water	water	NOUN
eurjchem-870	77	11	,	,	PUNCT
eurjchem-870	77	12	filtered	filter	VERB
eurjchem-870	77	13	off	off	ADP
eurjchem-870	77	14	,	,	PUNCT
eurjchem-870	77	15	dried	dry	VERB
eurjchem-870	77	16	,	,	PUNCT
eurjchem-870	77	17	and	and	CCONJ
eurjchem-870	77	18	crystallized	crystallize	VERB
eurjchem-870	77	19	from	from	ADP
eurjchem-870	77	20	benzene	benzene	NOUN
eurjchem-870	77	21	:	:	PUNCT
eurjchem-870	77	22	petroleum	petroleum	NOUN
eurjchem-870	77	23	ether	ether	NOUN
eurjchem-870	77	24	(	(	PUNCT
eurjchem-870	77	25	60‐80	60‐80	NOUN
eurjchem-870	77	26	°	°	SYM
eurjchem-870	77	27	c	c	NOUN
eurjchem-870	77	28	)	)	PUNCT
eurjchem-870	77	29	(	(	PUNCT
eurjchem-870	77	30	2:1	2:1	NUM
eurjchem-870	77	31	)	)	PUNCT
eurjchem-870	77	32	(	(	PUNCT
eurjchem-870	77	33	scheme	scheme	NOUN
eurjchem-870	77	34	1	1	NUM
eurjchem-870	77	35	)	)	PUNCT
eurjchem-870	77	36	.	.	PUNCT
eurjchem-870	78	1	color	color	NOUN
eurjchem-870	78	2	:	:	PUNCT
eurjchem-870	78	3	brown	brown	ADJ
eurjchem-870	78	4	.	.	PUNCT
eurjchem-870	79	1	yield	yield	NOUN
eurjchem-870	79	2	:	:	PUNCT
eurjchem-870	79	3	50	50	NUM
eurjchem-870	79	4	%	%	NOUN
eurjchem-870	79	5	.	.	PUNCT
eurjchem-870	80	1	m.p	m.p	PROPN
eurjchem-870	80	2	.	.	PROPN
eurjchem-870	80	3	:	:	PUNCT
eurjchem-870	81	1	246‐248	246‐248	NUM
eurjchem-870	81	2	°	°	ADP
eurjchem-870	81	3	c	c	X
eurjchem-870	81	4	.	.	PUNCT
eurjchem-870	82	1	ft‐ir	ft‐ir	NOUN
eurjchem-870	82	2	(	(	PUNCT
eurjchem-870	82	3	kbr	kbr	PROPN
eurjchem-870	82	4	,	,	PUNCT
eurjchem-870	82	5			PROPN
eurjchem-870	82	6	,	,	PUNCT
eurjchem-870	82	7	cm‐1	cm‐1	PROPN
eurjchem-870	82	8	):	):	PUNCT
eurjchem-870	82	9	3058	3058	NUM
eurjchem-870	82	10	(	(	PUNCT
eurjchem-870	82	11	ch	ch	NOUN
eurjchem-870	82	12	aromatic	aromatic	NOUN
eurjchem-870	82	13	)	)	PUNCT
eurjchem-870	82	14	,	,	PUNCT
eurjchem-870	82	15	2958	2958	NUM
eurjchem-870	82	16	(	(	PUNCT
eurjchem-870	82	17	ch	ch	NOUN
eurjchem-870	82	18	aliphatic	aliphatic	PROPN
eurjchem-870	82	19	)	)	PUNCT
eurjchem-870	82	20	,	,	PUNCT
eurjchem-870	82	21	1635	1635	NUM
eurjchem-870	82	22	(	(	PUNCT
eurjchem-870	82	23	c	c	NOUN
eurjchem-870	82	24	=	=	SYM
eurjchem-870	82	25	n	n	NUM
eurjchem-870	82	26	)	)	PUNCT
eurjchem-870	82	27	,	,	PUNCT
eurjchem-870	82	28	1601	1601	NUM
eurjchem-870	82	29	(	(	PUNCT
eurjchem-870	82	30	c	c	NOUN
eurjchem-870	82	31	=	=	SYM
eurjchem-870	82	32	c	c	NOUN
eurjchem-870	82	33	)	)	PUNCT
eurjchem-870	82	34	.	.	PUNCT
eurjchem-870	83	1	26	26	NUM
eurjchem-870	83	2	marzouk	marzouk	ADJ
eurjchem-870	83	3	et	et	PROPN
eurjchem-870	83	4	al	al	PROPN
eurjchem-870	83	5	.	.	PUNCT
eurjchem-870	83	6	/	/	SYM
eurjchem-870	83	7	european	european	PROPN
eurjchem-870	83	8	journal	journal	PROPN
eurjchem-870	83	9	of	of	ADP
eurjchem-870	83	10	chemistry	chemistry	NOUN
eurjchem-870	83	11	5	5	NUM
eurjchem-870	83	12	(	(	PUNCT
eurjchem-870	83	13	1	1	NUM
eurjchem-870	83	14	)	)	PUNCT
eurjchem-870	83	15	(	(	PUNCT
eurjchem-870	83	16	2014	2014	NUM
eurjchem-870	83	17	)	)	PUNCT
eurjchem-870	83	18	24‐32	24‐32	NUM
eurjchem-870	83	19	1h	1h	NUM
eurjchem-870	83	20	nmr	nmr	NOUN
eurjchem-870	83	21	(	(	PUNCT
eurjchem-870	83	22	300	300	NUM
eurjchem-870	83	23	mhz	mhz	NOUN
eurjchem-870	83	24	,	,	PUNCT
eurjchem-870	83	25	dmso	dmso	NOUN
eurjchem-870	83	26	,	,	PUNCT
eurjchem-870	83	27	δ	δ	PROPN
eurjchem-870	83	28	,	,	PUNCT
eurjchem-870	83	29	ppm	ppm	NUM
eurjchem-870	83	30	):	):	PUNCT
eurjchem-870	83	31	6.88‐8.11	6.88‐8.11	NUM
eurjchem-870	83	32	(	(	PUNCT
eurjchem-870	83	33	m	m	PROPN
eurjchem-870	83	34	,	,	PUNCT
eurjchem-870	83	35	15h	15h	NUM
eurjchem-870	83	36	,	,	PUNCT
eurjchem-870	83	37	arh	arh	PROPN
eurjchem-870	83	38	)	)	PUNCT
eurjchem-870	83	39	,	,	PUNCT
eurjchem-870	83	40	3.81	3.81	NUM
eurjchem-870	83	41	(	(	PUNCT
eurjchem-870	83	42	s	s	PROPN
eurjchem-870	83	43	,	,	PUNCT
eurjchem-870	83	44	3h	3h	NUM
eurjchem-870	83	45	,	,	PUNCT
eurjchem-870	83	46	och3	och3	ADJ
eurjchem-870	83	47	)	)	PUNCT
eurjchem-870	83	48	,	,	PUNCT
eurjchem-870	83	49	3.30	3.30	NUM
eurjchem-870	83	50	(	(	PUNCT
eurjchem-870	83	51	s	s	PROPN
eurjchem-870	83	52	,	,	PUNCT
eurjchem-870	83	53	3h	3h	NUM
eurjchem-870	83	54	,	,	PUNCT
eurjchem-870	83	55	ch3	ch3	PROPN
eurjchem-870	83	56	)	)	PUNCT
eurjchem-870	83	57	.	.	PUNCT
eurjchem-870	84	1	ms	ms	PROPN
eurjchem-870	84	2	(	(	PUNCT
eurjchem-870	84	3	ei	ei	PROPN
eurjchem-870	84	4	,	,	PUNCT
eurjchem-870	84	5	m	m	PROPN
eurjchem-870	84	6	/	/	SYM
eurjchem-870	84	7	z	z	PROPN
eurjchem-870	84	8	(	(	PUNCT
eurjchem-870	84	9	%	%	NOUN
eurjchem-870	84	10	)	)	PUNCT
eurjchem-870	84	11	):	):	PUNCT
eurjchem-870	84	12	391	391	NUM
eurjchem-870	84	13	(	(	PUNCT
eurjchem-870	84	14	21.7	21.7	NUM
eurjchem-870	84	15	,	,	PUNCT
eurjchem-870	84	16	m+	m+	NOUN
eurjchem-870	84	17	·	·	PUNCT
eurjchem-870	84	18	)	)	PUNCT
eurjchem-870	84	19	,	,	PUNCT
eurjchem-870	84	20	354	354	NUM
eurjchem-870	84	21	(	(	PUNCT
eurjchem-870	84	22	100	100	NUM
eurjchem-870	84	23	)	)	PUNCT
eurjchem-870	84	24	,	,	PUNCT
eurjchem-870	84	25	353	353	NUM
eurjchem-870	84	26	(	(	PUNCT
eurjchem-870	84	27	82.6	82.6	NUM
eurjchem-870	84	28	)	)	PUNCT
eurjchem-870	84	29	,	,	PUNCT
eurjchem-870	84	30	188	188	NUM
eurjchem-870	84	31	(	(	PUNCT
eurjchem-870	84	32	26.1	26.1	NUM
eurjchem-870	84	33	)	)	PUNCT
eurjchem-870	84	34	,	,	PUNCT
eurjchem-870	84	35	77	77	NUM
eurjchem-870	84	36	(	(	PUNCT
eurjchem-870	84	37	95.7	95.7	NUM
eurjchem-870	84	38	)	)	PUNCT
eurjchem-870	84	39	,	,	PUNCT
eurjchem-870	84	40	68	68	NUM
eurjchem-870	84	41	(	(	PUNCT
eurjchem-870	84	42	13.0	13.0	NUM
eurjchem-870	84	43	)	)	PUNCT
eurjchem-870	84	44	.	.	PUNCT
eurjchem-870	85	1	anal	anal	PROPN
eurjchem-870	85	2	.	.	PUNCT
eurjchem-870	85	3	calcd	calcd	NOUN
eurjchem-870	85	4	.	.	PUNCT
eurjchem-870	86	1	for	for	ADP
eurjchem-870	86	2	c26h21n3o	c26h21n3o	NOUN
eurjchem-870	86	3	:	:	PUNCT
eurjchem-870	86	4	c	c	X
eurjchem-870	86	5	,	,	PUNCT
eurjchem-870	86	6	79.77	79.77	NUM
eurjchem-870	86	7	;	;	PUNCT
eurjchem-870	86	8	h	h	NOUN
eurjchem-870	86	9	,	,	PUNCT
eurjchem-870	86	10	5.41	5.41	NUM
eurjchem-870	86	11	;	;	PUNCT
eurjchem-870	86	12	n	n	CCONJ
eurjchem-870	86	13	,	,	PUNCT
eurjchem-870	86	14	10.73	10.73	NUM
eurjchem-870	86	15	.	.	PUNCT
eurjchem-870	87	1	found	find	VERB
eurjchem-870	87	2	:	:	PUNCT
eurjchem-870	88	1	c	c	X
eurjchem-870	88	2	,	,	PUNCT
eurjchem-870	88	3	79.91	79.91	NUM
eurjchem-870	88	4	;	;	PUNCT
eurjchem-870	88	5	h	h	NOUN
eurjchem-870	88	6	,	,	PUNCT
eurjchem-870	88	7	5.60	5.60	NUM
eurjchem-870	88	8	;	;	PUNCT
eurjchem-870	88	9	n	n	CCONJ
eurjchem-870	88	10	,	,	PUNCT
eurjchem-870	88	11	10.96	10.96	NUM
eurjchem-870	88	12	%	%	NOUN
eurjchem-870	88	13	.	.	PUNCT
eurjchem-870	89	1	2.2.5	2.2.5	X
eurjchem-870	89	2	.	.	PUNCT
eurjchem-870	90	1	(	(	PUNCT
eurjchem-870	90	2	6‐amino‐4‐(4‐methoxyphenyl)‐1,3‐diphenyl‐1h‐	6‐amino‐4‐(4‐methoxyphenyl)‐1,3‐diphenyl‐1h‐	NUM
eurjchem-870	90	3	pyrazolo[3,4‐b]pyridin‐5‐yl)(iminomethyl	pyrazolo[3,4‐b]pyridin‐5‐yl)(iminomethyl	NOUN
eurjchem-870	90	4	)	)	PUNCT
eurjchem-870	90	5	thiocyanatomethanethioimidate	thiocyanatomethanethioimidate	NOUN
eurjchem-870	90	6	(	(	PUNCT
eurjchem-870	90	7	7	7	NUM
eurjchem-870	90	8	)	)	PUNCT
eurjchem-870	90	9	a	a	DET
eurjchem-870	90	10	mixture	mixture	NOUN
eurjchem-870	90	11	of	of	ADP
eurjchem-870	90	12	pyrazolopyridine‐5‐carbonitrile	pyrazolopyridine‐5‐carbonitrile	ADV
eurjchem-870	90	13	4	4	NUM
eurjchem-870	90	14	(	(	PUNCT
eurjchem-870	90	15	4.17	4.17	NUM
eurjchem-870	90	16	 	 	SPACE
eurjchem-870	90	17	g	g	NOUN
eurjchem-870	90	18	,	,	PUNCT
eurjchem-870	90	19	0.01	0.01	NUM
eurjchem-870	90	20	 	 	SPACE
eurjchem-870	90	21	mol	mol	NUM
eurjchem-870	90	22	)	)	PUNCT
eurjchem-870	90	23	,	,	PUNCT
eurjchem-870	90	24	ammonium	ammonium	NOUN
eurjchem-870	90	25	thiocyanate	thiocyanate	NOUN
eurjchem-870	90	26	(	(	PUNCT
eurjchem-870	90	27	2.28	2.28	NUM
eurjchem-870	90	28	 	 	SPACE
eurjchem-870	90	29	g	g	NOUN
eurjchem-870	90	30	,	,	PUNCT
eurjchem-870	90	31	0.03	0.03	NUM
eurjchem-870	90	32	 	 	SPACE
eurjchem-870	90	33	mol	mol	NOUN
eurjchem-870	90	34	)	)	PUNCT
eurjchem-870	90	35	,	,	PUNCT
eurjchem-870	90	36	in	in	ADP
eurjchem-870	90	37	acetic	acetic	ADJ
eurjchem-870	90	38	acid	acid	NOUN
eurjchem-870	90	39	(	(	PUNCT
eurjchem-870	90	40	10	10	NUM
eurjchem-870	90	41	 	 	SPACE
eurjchem-870	90	42	ml	ml	NOUN
eurjchem-870	90	43	)	)	PUNCT
eurjchem-870	90	44	was	be	AUX
eurjchem-870	90	45	refluxed	refluxe	VERB
eurjchem-870	90	46	for	for	ADP
eurjchem-870	90	47	10	10	NUM
eurjchem-870	90	48	 	 	SPACE
eurjchem-870	90	49	h	h	NOUN
eurjchem-870	90	50	,	,	PUNCT
eurjchem-870	90	51	the	the	DET
eurjchem-870	90	52	reaction	reaction	NOUN
eurjchem-870	90	53	mixture	mixture	NOUN
eurjchem-870	90	54	was	be	AUX
eurjchem-870	90	55	poured	pour	VERB
eurjchem-870	90	56	onto	onto	ADP
eurjchem-870	90	57	water	water	NOUN
eurjchem-870	90	58	,	,	PUNCT
eurjchem-870	90	59	filtered	filter	VERB
eurjchem-870	90	60	off	off	ADP
eurjchem-870	90	61	,	,	PUNCT
eurjchem-870	90	62	washed	wash	VERB
eurjchem-870	90	63	with	with	ADP
eurjchem-870	90	64	water	water	NOUN
eurjchem-870	90	65	,	,	PUNCT
eurjchem-870	90	66	dried	dry	VERB
eurjchem-870	90	67	and	and	CCONJ
eurjchem-870	90	68	recrystallized	recrystallize	VERB
eurjchem-870	90	69	from	from	ADP
eurjchem-870	90	70	ethanol	ethanol	NOUN
eurjchem-870	90	71	(	(	PUNCT
eurjchem-870	90	72	scheme	scheme	NOUN
eurjchem-870	90	73	1	1	NUM
eurjchem-870	90	74	)	)	PUNCT
eurjchem-870	90	75	.	.	PUNCT
eurjchem-870	91	1	color	color	NOUN
eurjchem-870	91	2	:	:	PUNCT
eurjchem-870	91	3	brown	brown	ADJ
eurjchem-870	91	4	.	.	PUNCT
eurjchem-870	92	1	yield	yield	NOUN
eurjchem-870	92	2	:	:	PUNCT
eurjchem-870	92	3	92	92	NUM
eurjchem-870	92	4	%	%	NOUN
eurjchem-870	92	5	.	.	PUNCT
eurjchem-870	93	1	m.p	m.p	PROPN
eurjchem-870	93	2	.	.	PROPN
eurjchem-870	93	3	:	:	PUNCT
eurjchem-870	94	1	222‐224	222‐224	NUM
eurjchem-870	94	2	°	°	SYM
eurjchem-870	94	3	c	c	X
eurjchem-870	94	4	.	.	PUNCT
eurjchem-870	95	1	ft‐ir	ft‐ir	NOUN
eurjchem-870	95	2	(	(	PUNCT
eurjchem-870	95	3	kbr	kbr	PROPN
eurjchem-870	95	4	,	,	PUNCT
eurjchem-870	95	5			PROPN
eurjchem-870	95	6	,	,	PUNCT
eurjchem-870	95	7	cm‐1	cm‐1	PROPN
eurjchem-870	95	8	):	):	PUNCT
eurjchem-870	95	9	3457	3457	NUM
eurjchem-870	95	10	,	,	PUNCT
eurjchem-870	95	11	3338	3338	NUM
eurjchem-870	95	12	(	(	PUNCT
eurjchem-870	95	13	nh	nh	NOUN
eurjchem-870	95	14	,	,	PUNCT
eurjchem-870	95	15	nh2	nh2	PROPN
eurjchem-870	95	16	)	)	PUNCT
eurjchem-870	95	17	,	,	PUNCT
eurjchem-870	95	18	2207	2207	NUM
eurjchem-870	95	19	(	(	PUNCT
eurjchem-870	95	20	c≡n	c≡n	PROPN
eurjchem-870	95	21	)	)	PUNCT
eurjchem-870	95	22	,	,	PUNCT
eurjchem-870	95	23	1602	1602	NUM
eurjchem-870	95	24	(	(	PUNCT
eurjchem-870	95	25	c	c	NOUN
eurjchem-870	95	26	=	=	SYM
eurjchem-870	95	27	n	n	NUM
eurjchem-870	95	28	)	)	PUNCT
eurjchem-870	95	29	.	.	PUNCT
eurjchem-870	96	1	1h	1h	NUM
eurjchem-870	96	2	nmr	nmr	NOUN
eurjchem-870	96	3	(	(	PUNCT
eurjchem-870	96	4	300	300	NUM
eurjchem-870	96	5	mhz	mhz	NOUN
eurjchem-870	96	6	,	,	PUNCT
eurjchem-870	96	7	cdcl3	cdcl3	PROPN
eurjchem-870	96	8	,	,	PUNCT
eurjchem-870	96	9	δ	δ	PROPN
eurjchem-870	96	10	,	,	PUNCT
eurjchem-870	96	11	ppm	ppm	NUM
eurjchem-870	96	12	):	):	PUNCT
eurjchem-870	96	13	6.94‐7.95(m	6.94‐7.95(m	NUM
eurjchem-870	96	14	,	,	PUNCT
eurjchem-870	96	15	14h	14h	NUM
eurjchem-870	96	16	,	,	PUNCT
eurjchem-870	96	17	arh	arh	PROPN
eurjchem-870	96	18	)	)	PUNCT
eurjchem-870	96	19	,	,	PUNCT
eurjchem-870	96	20	5.69	5.69	NUM
eurjchem-870	96	21	(	(	PUNCT
eurjchem-870	96	22	s	s	PROPN
eurjchem-870	96	23	,	,	PUNCT
eurjchem-870	96	24	4h	4h	NOUN
eurjchem-870	96	25	,	,	PUNCT
eurjchem-870	96	26	2nh	2nh	NOUN
eurjchem-870	96	27	,	,	PUNCT
eurjchem-870	96	28	nh2	nh2	PROPN
eurjchem-870	96	29	d2o	d2o	PROPN
eurjchem-870	96	30	exchangeable	exchangeable	ADJ
eurjchem-870	96	31	)	)	PUNCT
eurjchem-870	96	32	,	,	PUNCT
eurjchem-870	96	33	3.78	3.78	NUM
eurjchem-870	96	34	(	(	PUNCT
eurjchem-870	96	35	s	s	PROPN
eurjchem-870	96	36	,	,	PUNCT
eurjchem-870	96	37	3h	3h	NUM
eurjchem-870	96	38	,	,	PUNCT
eurjchem-870	96	39	och3	och3	ADJ
eurjchem-870	96	40	)	)	PUNCT
eurjchem-870	96	41	.	.	PUNCT
eurjchem-870	97	1	ms	ms	NOUN
eurjchem-870	97	2	(	(	PUNCT
eurjchem-870	97	3	ei	ei	PROPN
eurjchem-870	97	4	,	,	PUNCT
eurjchem-870	97	5	m	m	PROPN
eurjchem-870	97	6	/	/	SYM
eurjchem-870	97	7	z	z	PROPN
eurjchem-870	97	8	(	(	PUNCT
eurjchem-870	97	9	%	%	NOUN
eurjchem-870	97	10	)	)	PUNCT
eurjchem-870	97	11	):	):	PUNCT
eurjchem-870	97	12	535	535	NUM
eurjchem-870	97	13	(	(	PUNCT
eurjchem-870	97	14	20.0	20.0	NUM
eurjchem-870	97	15	,	,	PUNCT
eurjchem-870	97	16	m+	m+	NOUN
eurjchem-870	97	17	·	·	PUNCT
eurjchem-870	97	18	)	)	PUNCT
eurjchem-870	97	19	376	376	NUM
eurjchem-870	97	20	(	(	PUNCT
eurjchem-870	97	21	16.7	16.7	NUM
eurjchem-870	97	22	)	)	PUNCT
eurjchem-870	97	23	,	,	PUNCT
eurjchem-870	97	24	195	195	NUM
eurjchem-870	97	25	(	(	PUNCT
eurjchem-870	97	26	16.7	16.7	NUM
eurjchem-870	97	27	)	)	PUNCT
eurjchem-870	97	28	,	,	PUNCT
eurjchem-870	97	29	103	103	NUM
eurjchem-870	97	30	(	(	PUNCT
eurjchem-870	97	31	100	100	NUM
eurjchem-870	97	32	)	)	PUNCT
eurjchem-870	97	33	,	,	PUNCT
eurjchem-870	97	34	104	104	NUM
eurjchem-870	97	35	(	(	PUNCT
eurjchem-870	97	36	46.7	46.7	NUM
eurjchem-870	97	37	)	)	PUNCT
eurjchem-870	97	38	,	,	PUNCT
eurjchem-870	97	39	79	79	NUM
eurjchem-870	97	40	(	(	PUNCT
eurjchem-870	97	41	26.7	26.7	NUM
eurjchem-870	97	42	)	)	PUNCT
eurjchem-870	97	43	,	,	PUNCT
eurjchem-870	97	44	78	78	NUM
eurjchem-870	97	45	(	(	PUNCT
eurjchem-870	97	46	36.7	36.7	NUM
eurjchem-870	97	47	)	)	PUNCT
eurjchem-870	97	48	,	,	PUNCT
eurjchem-870	97	49	77(96.7	77(96.7	NUM
eurjchem-870	97	50	)	)	PUNCT
eurjchem-870	97	51	.	.	PUNCT
eurjchem-870	98	1	anal	anal	PROPN
eurjchem-870	98	2	.	.	PUNCT
eurjchem-870	98	3	calcd	calcd	NOUN
eurjchem-870	98	4	.	.	PUNCT
eurjchem-870	99	1	for	for	ADP
eurjchem-870	99	2	c28h21n7os2	c28h21n7os2	NOUN
eurjchem-870	99	3	:	:	PUNCT
eurjchem-870	99	4	c	c	X
eurjchem-870	99	5	,	,	PUNCT
eurjchem-870	99	6	62.78	62.78	NUM
eurjchem-870	99	7	;	;	PUNCT
eurjchem-870	99	8	h	h	NOUN
eurjchem-870	99	9	,	,	PUNCT
eurjchem-870	99	10	3.95	3.95	NUM
eurjchem-870	99	11	;	;	PUNCT
eurjchem-870	99	12	n	n	CCONJ
eurjchem-870	99	13	,	,	PUNCT
eurjchem-870	99	14	18.30	18.30	NUM
eurjchem-870	99	15	;	;	PUNCT
eurjchem-870	99	16	s	s	NUM
eurjchem-870	99	17	,	,	PUNCT
eurjchem-870	99	18	11.97	11.97	NUM
eurjchem-870	99	19	.	.	PUNCT
eurjchem-870	99	20	found	find	VERB
eurjchem-870	99	21	:	:	PUNCT
eurjchem-870	100	1	c	c	X
eurjchem-870	100	2	,	,	PUNCT
eurjchem-870	100	3	62.92	62.92	NUM
eurjchem-870	100	4	;	;	PUNCT
eurjchem-870	100	5	h	h	X
eurjchem-870	100	6	,	,	PUNCT
eurjchem-870	100	7	4.15	4.15	NUM
eurjchem-870	100	8	;	;	PUNCT
eurjchem-870	100	9	n	n	CCONJ
eurjchem-870	100	10	,	,	PUNCT
eurjchem-870	100	11	12.13	12.13	NUM
eurjchem-870	100	12	;	;	PUNCT
eurjchem-870	100	13	s	s	X
eurjchem-870	100	14	,	,	PUNCT
eurjchem-870	100	15	11.94	11.94	NUM
eurjchem-870	100	16	%	%	NOUN
eurjchem-870	100	17	.	.	PUNCT
eurjchem-870	101	1	2.2.6	2.2.6	X
eurjchem-870	101	2	.	.	PUNCT
eurjchem-870	101	3	4‐(4‐methoxyphenyl)‐1,3‐diphenyl‐5‐(5‐thiocyanato‐	4‐(4‐methoxyphenyl)‐1,3‐diphenyl‐5‐(5‐thiocyanato‐	NUM
eurjchem-870	101	4	1,3,4‐thiadiazol‐2‐yl)‐1h‐pyrazolo[3,4‐b]pyridin‐6‐amine	1,3,4‐thiadiazol‐2‐yl)‐1h‐pyrazolo[3,4‐b]pyridin‐6‐amine	NUM
eurjchem-870	101	5	(	(	PUNCT
eurjchem-870	101	6	8)	8)	NUM
eurjchem-870	101	7	a	a	DET
eurjchem-870	101	8	mixture	mixture	NOUN
eurjchem-870	101	9	of	of	ADP
eurjchem-870	101	10	(	(	PUNCT
eurjchem-870	101	11	iminomethyl	iminomethyl	PROPN
eurjchem-870	101	12	)	)	PUNCT
eurjchem-870	101	13	thiocyanatomethanethio‐	thiocyanatomethanethio‐	NOUN
eurjchem-870	101	14	imidate	imidate	VERB
eurjchem-870	101	15	7	7	NUM
eurjchem-870	101	16	(	(	PUNCT
eurjchem-870	101	17	5.35	5.35	NUM
eurjchem-870	101	18	 	 	SPACE
eurjchem-870	101	19	g	g	NOUN
eurjchem-870	101	20	,	,	PUNCT
eurjchem-870	101	21	0.01	0.01	NUM
eurjchem-870	101	22	 	 	SPACE
eurjchem-870	101	23	mol	mol	NOUN
eurjchem-870	101	24	)	)	PUNCT
eurjchem-870	101	25	,	,	PUNCT
eurjchem-870	101	26	hydrazine	hydrazine	NOUN
eurjchem-870	101	27	hydrate	hydrate	NOUN
eurjchem-870	101	28	(	(	PUNCT
eurjchem-870	101	29	0.5	0.5	NUM
eurjchem-870	101	30	 	 	SPACE
eurjchem-870	101	31	ml	ml	NOUN
eurjchem-870	101	32	,	,	PUNCT
eurjchem-870	101	33	0.01	0.01	NUM
eurjchem-870	101	34	 	 	SPACE
eurjchem-870	101	35	mol	mol	NOUN
eurjchem-870	101	36	)	)	PUNCT
eurjchem-870	101	37	,	,	PUNCT
eurjchem-870	101	38	in	in	ADP
eurjchem-870	101	39	absolute	absolute	ADJ
eurjchem-870	101	40	ethanol	ethanol	NOUN
eurjchem-870	101	41	(	(	PUNCT
eurjchem-870	101	42	20	20	NUM
eurjchem-870	101	43	 	 	SPACE
eurjchem-870	101	44	ml	ml	NOUN
eurjchem-870	101	45	)	)	PUNCT
eurjchem-870	101	46	was	be	AUX
eurjchem-870	101	47	refluxed	refluxe	VERB
eurjchem-870	101	48	for	for	ADP
eurjchem-870	101	49	2	2	NUM
eurjchem-870	101	50	 	 	SPACE
eurjchem-870	101	51	h	h	NOUN
eurjchem-870	101	52	,	,	PUNCT
eurjchem-870	101	53	the	the	DET
eurjchem-870	101	54	reaction	reaction	NOUN
eurjchem-870	101	55	mixture	mixture	NOUN
eurjchem-870	101	56	was	be	AUX
eurjchem-870	101	57	concentrated	concentrate	VERB
eurjchem-870	101	58	,	,	PUNCT
eurjchem-870	101	59	and	and	CCONJ
eurjchem-870	101	60	the	the	DET
eurjchem-870	101	61	separated	separate	VERB
eurjchem-870	101	62	solid	solid	ADJ
eurjchem-870	101	63	was	be	AUX
eurjchem-870	101	64	filtered	filter	VERB
eurjchem-870	101	65	off	off	ADP
eurjchem-870	101	66	,	,	PUNCT
eurjchem-870	101	67	dried	dry	VERB
eurjchem-870	101	68	and	and	CCONJ
eurjchem-870	101	69	crystallized	crystallize	VERB
eurjchem-870	101	70	from	from	ADP
eurjchem-870	101	71	ethanol	ethanol	NOUN
eurjchem-870	101	72	:	:	PUNCT
eurjchem-870	101	73	benzene	benzene	NOUN
eurjchem-870	101	74	(	(	PUNCT
eurjchem-870	101	75	1:1	1:1	NUM
eurjchem-870	101	76	)	)	PUNCT
eurjchem-870	101	77	(	(	PUNCT
eurjchem-870	101	78	scheme	scheme	NOUN
eurjchem-870	101	79	1	1	NUM
eurjchem-870	101	80	)	)	PUNCT
eurjchem-870	101	81	.	.	PUNCT
eurjchem-870	102	1	color	color	NOUN
eurjchem-870	102	2	:	:	PUNCT
eurjchem-870	102	3	dark	dark	PROPN
eurjchem-870	102	4	brown	brown	PROPN
eurjchem-870	102	5	.	.	PUNCT
eurjchem-870	103	1	yield	yield	NOUN
eurjchem-870	103	2	:	:	PUNCT
eurjchem-870	103	3	35	35	NUM
eurjchem-870	103	4	%	%	NOUN
eurjchem-870	103	5	.	.	PUNCT
eurjchem-870	104	1	m.p	m.p	PROPN
eurjchem-870	104	2	.	.	PROPN
eurjchem-870	104	3	:	:	PUNCT
eurjchem-870	105	1	225‐227	225‐227	NUM
eurjchem-870	105	2	°	°	ADP
eurjchem-870	105	3	c	c	X
eurjchem-870	105	4	.	.	PUNCT
eurjchem-870	105	5	ft‐ir	ft‐ir	NOUN
eurjchem-870	105	6	(	(	PUNCT
eurjchem-870	105	7	kbr	kbr	PROPN
eurjchem-870	105	8	,	,	PUNCT
eurjchem-870	105	9			PROPN
eurjchem-870	105	10	,	,	PUNCT
eurjchem-870	105	11	cm‐1	cm‐1	PROPN
eurjchem-870	105	12	):	):	PUNCT
eurjchem-870	105	13	3324	3324	NUM
eurjchem-870	105	14	(	(	PUNCT
eurjchem-870	105	15	nh2	nh2	PROPN
eurjchem-870	105	16	)	)	PUNCT
eurjchem-870	105	17	,	,	PUNCT
eurjchem-870	105	18	1602	1602	NUM
eurjchem-870	105	19	(	(	PUNCT
eurjchem-870	105	20	c	c	NOUN
eurjchem-870	105	21	=	=	SYM
eurjchem-870	105	22	n	n	NUM
eurjchem-870	105	23	)	)	PUNCT
eurjchem-870	105	24	,	,	PUNCT
eurjchem-870	105	25	1252	1252	NUM
eurjchem-870	105	26	(	(	PUNCT
eurjchem-870	105	27	c	c	NOUN
eurjchem-870	105	28	=	=	SYM
eurjchem-870	105	29	c	c	NOUN
eurjchem-870	105	30	)	)	PUNCT
eurjchem-870	105	31	.	.	PUNCT
eurjchem-870	106	1	1h	1h	NUM
eurjchem-870	106	2	nmr	nmr	NOUN
eurjchem-870	106	3	(	(	PUNCT
eurjchem-870	106	4	300	300	NUM
eurjchem-870	106	5	mhz	mhz	NOUN
eurjchem-870	106	6	,	,	PUNCT
eurjchem-870	106	7	cdcl3	cdcl3	PROPN
eurjchem-870	106	8	,	,	PUNCT
eurjchem-870	106	9	δ	δ	PROPN
eurjchem-870	106	10	,	,	PUNCT
eurjchem-870	106	11	ppm	ppm	NOUN
eurjchem-870	106	12	):	):	PUNCT
eurjchem-870	106	13	7.02‐8.05	7.02‐8.05	NOUN
eurjchem-870	106	14	(	(	PUNCT
eurjchem-870	106	15	m	m	PROPN
eurjchem-870	106	16	,	,	PUNCT
eurjchem-870	106	17	14h	14h	NUM
eurjchem-870	106	18	,	,	PUNCT
eurjchem-870	106	19	arh	arh	PROPN
eurjchem-870	106	20	)	)	PUNCT
eurjchem-870	106	21	,	,	PUNCT
eurjchem-870	106	22	5.63	5.63	NUM
eurjchem-870	106	23	(	(	PUNCT
eurjchem-870	106	24	s	s	PROPN
eurjchem-870	106	25	,	,	PUNCT
eurjchem-870	106	26	2h	2h	NUM
eurjchem-870	106	27	,	,	PUNCT
eurjchem-870	106	28	nh2	nh2	PROPN
eurjchem-870	106	29	d2o	d2o	PROPN
eurjchem-870	106	30	exchangeable	exchangeable	ADJ
eurjchem-870	106	31	)	)	PUNCT
eurjchem-870	106	32	,	,	PUNCT
eurjchem-870	106	33	3.87	3.87	NUM
eurjchem-870	106	34	(	(	PUNCT
eurjchem-870	106	35	s	s	PROPN
eurjchem-870	106	36	,	,	PUNCT
eurjchem-870	106	37	3h	3h	NUM
eurjchem-870	106	38	,	,	PUNCT
eurjchem-870	106	39	och3	och3	ADJ
eurjchem-870	106	40	)	)	PUNCT
eurjchem-870	106	41	.	.	PUNCT
eurjchem-870	107	1	ms	ms	NOUN
eurjchem-870	107	2	(	(	PUNCT
eurjchem-870	107	3	ei	ei	PROPN
eurjchem-870	107	4	,	,	PUNCT
eurjchem-870	107	5	m	m	PROPN
eurjchem-870	107	6	/	/	SYM
eurjchem-870	107	7	z	z	PROPN
eurjchem-870	107	8	(	(	PUNCT
eurjchem-870	107	9	%	%	NOUN
eurjchem-870	107	10	)	)	PUNCT
eurjchem-870	107	11	):	):	PUNCT
eurjchem-870	107	12	533	533	NUM
eurjchem-870	107	13	(	(	PUNCT
eurjchem-870	107	14	0.01	0.01	NUM
eurjchem-870	107	15	,	,	PUNCT
eurjchem-870	107	16	m+	m+	NOUN
eurjchem-870	107	17	·	·	PUNCT
eurjchem-870	107	18	)	)	PUNCT
eurjchem-870	107	19	,	,	PUNCT
eurjchem-870	107	20	516	516	NUM
eurjchem-870	107	21	(	(	PUNCT
eurjchem-870	107	22	14.3	14.3	NUM
eurjchem-870	107	23	)	)	PUNCT
eurjchem-870	107	24	,	,	PUNCT
eurjchem-870	107	25	210	210	NUM
eurjchem-870	107	26	(	(	PUNCT
eurjchem-870	107	27	17.1	17.1	NUM
eurjchem-870	107	28	)	)	PUNCT
eurjchem-870	107	29	,	,	PUNCT
eurjchem-870	107	30	119	119	NUM
eurjchem-870	107	31	(	(	PUNCT
eurjchem-870	107	32	45.7	45.7	NUM
eurjchem-870	107	33	)	)	PUNCT
eurjchem-870	107	34	,	,	PUNCT
eurjchem-870	107	35	93	93	NUM
eurjchem-870	107	36	(	(	PUNCT
eurjchem-870	107	37	25.7	25.7	NUM
eurjchem-870	107	38	)	)	PUNCT
eurjchem-870	107	39	,	,	PUNCT
eurjchem-870	107	40	60	60	NUM
eurjchem-870	107	41	(	(	PUNCT
eurjchem-870	107	42	25.7	25.7	NUM
eurjchem-870	107	43	)	)	PUNCT
eurjchem-870	107	44	,	,	PUNCT
eurjchem-870	107	45	58	58	NUM
eurjchem-870	107	46	(	(	PUNCT
eurjchem-870	107	47	17.1	17.1	NUM
eurjchem-870	107	48	)	)	PUNCT
eurjchem-870	107	49	,	,	PUNCT
eurjchem-870	107	50	57	57	NUM
eurjchem-870	107	51	(	(	PUNCT
eurjchem-870	107	52	100	100	NUM
eurjchem-870	107	53	)	)	PUNCT
eurjchem-870	107	54	.	.	PUNCT
eurjchem-870	108	1	anal	anal	PROPN
eurjchem-870	108	2	.	.	PUNCT
eurjchem-870	108	3	calcd	calcd	NOUN
eurjchem-870	108	4	.	.	PUNCT
eurjchem-870	109	1	for	for	SCONJ
eurjchem-870	109	2	c28h19n7os2	c28h19n7os2	PROPN
eurjchem-870	109	3	:	:	PUNCT
eurjchem-870	109	4	c	c	X
eurjchem-870	109	5	,	,	PUNCT
eurjchem-870	109	6	63.02	63.02	NUM
eurjchem-870	109	7	;	;	PUNCT
eurjchem-870	109	8	h	h	NOUN
eurjchem-870	109	9	,	,	PUNCT
eurjchem-870	109	10	3.59	3.59	NUM
eurjchem-870	109	11	;	;	PUNCT
eurjchem-870	109	12	n	n	CCONJ
eurjchem-870	109	13	,	,	PUNCT
eurjchem-870	109	14	18.37	18.37	NUM
eurjchem-870	109	15	;	;	PUNCT
eurjchem-870	109	16	s	s	NUM
eurjchem-870	109	17	,	,	PUNCT
eurjchem-870	109	18	12.02	12.02	NUM
eurjchem-870	109	19	.	.	PUNCT
eurjchem-870	109	20	found	find	VERB
eurjchem-870	109	21	:	:	PUNCT
eurjchem-870	110	1	c	c	X
eurjchem-870	110	2	,	,	PUNCT
eurjchem-870	110	3	63.28	63.28	NUM
eurjchem-870	110	4	;	;	PUNCT
eurjchem-870	110	5	h	h	X
eurjchem-870	110	6	,	,	PUNCT
eurjchem-870	110	7	4.13	4.13	NUM
eurjchem-870	110	8	;	;	PUNCT
eurjchem-870	110	9	n	n	CCONJ
eurjchem-870	110	10	,	,	PUNCT
eurjchem-870	110	11	19.02	19.02	NUM
eurjchem-870	110	12	;	;	PUNCT
eurjchem-870	110	13	s	s	X
eurjchem-870	110	14	,	,	PUNCT
eurjchem-870	110	15	12.25	12.25	NUM
eurjchem-870	110	16	%	%	NOUN
eurjchem-870	110	17	.	.	PUNCT
eurjchem-870	111	1	2.2.7	2.2.7	X
eurjchem-870	111	2	.	.	PUNCT
eurjchem-870	112	1	n‐(5‐cyano‐4‐(4‐methoxyphenyl)‐1,3‐diphenyl‐1h‐	n‐(5‐cyano‐4‐(4‐methoxyphenyl)‐1,3‐diphenyl‐1h‐	ADP
eurjchem-870	112	2	pyrazolo[3,4‐b]pyridin‐6‐yl)formamide	pyrazolo[3,4‐b]pyridin‐6‐yl)formamide	NOUN
eurjchem-870	113	1	(	(	PUNCT
eurjchem-870	113	2	9	9	X
eurjchem-870	113	3	)	)	PUNCT
eurjchem-870	113	4	a	a	DET
eurjchem-870	113	5	mixture	mixture	NOUN
eurjchem-870	113	6	of	of	ADP
eurjchem-870	113	7	pyrazolopyridine‐5‐carbonitrile	pyrazolopyridine‐5‐carbonitrile	ADV
eurjchem-870	113	8	4	4	NUM
eurjchem-870	113	9	(	(	PUNCT
eurjchem-870	113	10	4.17	4.17	NUM
eurjchem-870	113	11	 	 	SPACE
eurjchem-870	113	12	g	g	NOUN
eurjchem-870	113	13	,	,	PUNCT
eurjchem-870	113	14	0.01	0.01	NUM
eurjchem-870	113	15	 	 	SPACE
eurjchem-870	113	16	mol	mol	NUM
eurjchem-870	113	17	)	)	PUNCT
eurjchem-870	113	18	,	,	PUNCT
eurjchem-870	113	19	formic	formic	NOUN
eurjchem-870	113	20	acid	acid	NOUN
eurjchem-870	113	21	(	(	PUNCT
eurjchem-870	113	22	5	5	NUM
eurjchem-870	113	23	 	 	SPACE
eurjchem-870	113	24	ml	ml	NOUN
eurjchem-870	113	25	)	)	PUNCT
eurjchem-870	113	26	,	,	PUNCT
eurjchem-870	113	27	formamide	formamide	ADV
eurjchem-870	113	28	(	(	PUNCT
eurjchem-870	113	29	10	10	NUM
eurjchem-870	113	30	 	 	SPACE
eurjchem-870	113	31	ml	ml	NOUN
eurjchem-870	113	32	)	)	PUNCT
eurjchem-870	113	33	,	,	PUNCT
eurjchem-870	113	34	and	and	CCONJ
eurjchem-870	113	35	dimethyl	dimethyl	NOUN
eurjchem-870	113	36	formamide	formamide	ADV
eurjchem-870	113	37	(	(	PUNCT
eurjchem-870	113	38	5	5	NUM
eurjchem-870	113	39	 	 	SPACE
eurjchem-870	113	40	ml	ml	NOUN
eurjchem-870	113	41	)	)	PUNCT
eurjchem-870	113	42	was	be	AUX
eurjchem-870	113	43	refluxed	refluxe	VERB
eurjchem-870	113	44	for	for	ADP
eurjchem-870	113	45	12	12	NUM
eurjchem-870	113	46	 	 	SPACE
eurjchem-870	113	47	h	h	NOUN
eurjchem-870	113	48	,	,	PUNCT
eurjchem-870	113	49	the	the	DET
eurjchem-870	113	50	reaction	reaction	NOUN
eurjchem-870	113	51	mixture	mixture	NOUN
eurjchem-870	113	52	was	be	AUX
eurjchem-870	113	53	poured	pour	VERB
eurjchem-870	113	54	onto	onto	ADP
eurjchem-870	113	55	water	water	NOUN
eurjchem-870	113	56	to	to	PART
eurjchem-870	113	57	give	give	VERB
eurjchem-870	113	58	solid	solid	ADJ
eurjchem-870	113	59	which	which	PRON
eurjchem-870	113	60	was	be	AUX
eurjchem-870	113	61	filtered	filter	VERB
eurjchem-870	113	62	off	off	ADP
eurjchem-870	113	63	,	,	PUNCT
eurjchem-870	113	64	washed	wash	VERB
eurjchem-870	113	65	with	with	ADP
eurjchem-870	113	66	water	water	NOUN
eurjchem-870	113	67	,	,	PUNCT
eurjchem-870	113	68	dried	dry	VERB
eurjchem-870	113	69	and	and	CCONJ
eurjchem-870	113	70	recrystallized	recrystallize	VERB
eurjchem-870	113	71	from	from	ADP
eurjchem-870	113	72	benzene	benzene	NOUN
eurjchem-870	113	73	(	(	PUNCT
eurjchem-870	113	74	scheme	scheme	NOUN
eurjchem-870	113	75	1	1	NUM
eurjchem-870	113	76	)	)	PUNCT
eurjchem-870	113	77	.	.	PUNCT
eurjchem-870	114	1	color	color	NOUN
eurjchem-870	114	2	:	:	PUNCT
eurjchem-870	114	3	green	green	ADJ
eurjchem-870	114	4	.	.	PUNCT
eurjchem-870	115	1	yield	yield	NOUN
eurjchem-870	115	2	:	:	PUNCT
eurjchem-870	115	3	76.4	76.4	NUM
eurjchem-870	115	4	%	%	NOUN
eurjchem-870	115	5	.	.	PUNCT
eurjchem-870	116	1	m.p	m.p	PROPN
eurjchem-870	116	2	.	.	PROPN
eurjchem-870	116	3	:	:	PUNCT
eurjchem-870	117	1	230‐232	230‐232	NUM
eurjchem-870	117	2	°	°	ADP
eurjchem-870	117	3	c	c	X
eurjchem-870	117	4	.	.	PUNCT
eurjchem-870	118	1	ft‐ir	ft‐ir	NOUN
eurjchem-870	118	2	(	(	PUNCT
eurjchem-870	118	3	kbr	kbr	PROPN
eurjchem-870	118	4	,	,	PUNCT
eurjchem-870	118	5			PROPN
eurjchem-870	118	6	,	,	PUNCT
eurjchem-870	118	7	cm‐1	cm‐1	PROPN
eurjchem-870	118	8	):	):	PUNCT
eurjchem-870	118	9	3428	3428	NUM
eurjchem-870	118	10	(	(	PUNCT
eurjchem-870	118	11	nh	nh	NOUN
eurjchem-870	118	12	)	)	PUNCT
eurjchem-870	118	13	,	,	PUNCT
eurjchem-870	118	14	2208	2208	NUM
eurjchem-870	118	15	(	(	PUNCT
eurjchem-870	118	16	c≡n	c≡n	NOUN
eurjchem-870	118	17	)	)	PUNCT
eurjchem-870	118	18	,	,	PUNCT
eurjchem-870	118	19	1670	1670	NUM
eurjchem-870	118	20	(	(	PUNCT
eurjchem-870	118	21	c	c	NOUN
eurjchem-870	118	22	=	=	NOUN
eurjchem-870	118	23	o	o	NOUN
eurjchem-870	118	24	)	)	PUNCT
eurjchem-870	118	25	,	,	PUNCT
eurjchem-870	118	26	1604	1604	NUM
eurjchem-870	118	27	(	(	PUNCT
eurjchem-870	118	28	c	c	NOUN
eurjchem-870	118	29	=	=	SYM
eurjchem-870	118	30	n	n	NUM
eurjchem-870	118	31	)	)	PUNCT
eurjchem-870	118	32	.	.	PUNCT
eurjchem-870	119	1	1h	1h	NUM
eurjchem-870	119	2	nmr	nmr	NOUN
eurjchem-870	119	3	(	(	PUNCT
eurjchem-870	119	4	300	300	NUM
eurjchem-870	119	5	mhz	mhz	NOUN
eurjchem-870	119	6	,	,	PUNCT
eurjchem-870	119	7	cdcl3	cdcl3	PROPN
eurjchem-870	119	8	,	,	PUNCT
eurjchem-870	119	9	δ	δ	PROPN
eurjchem-870	119	10	,	,	PUNCT
eurjchem-870	119	11	ppm	ppm	NUM
eurjchem-870	119	12	):	):	PUNCT
eurjchem-870	119	13	7.02‐8.20	7.02‐8.20	NUM
eurjchem-870	119	14	(	(	PUNCT
eurjchem-870	119	15	m	m	PROPN
eurjchem-870	119	16	,	,	PUNCT
eurjchem-870	119	17	15h	15h	NUM
eurjchem-870	119	18	,	,	PUNCT
eurjchem-870	119	19	14arh	14arh	INTJ
eurjchem-870	119	20	,	,	PUNCT
eurjchem-870	119	21	‐ch	‐ch	NOUN
eurjchem-870	119	22	)	)	PUNCT
eurjchem-870	119	23	,	,	PUNCT
eurjchem-870	119	24	5.73	5.73	NUM
eurjchem-870	119	25	(	(	PUNCT
eurjchem-870	119	26	s	s	PROPN
eurjchem-870	119	27	,	,	PUNCT
eurjchem-870	119	28	1h	1h	NUM
eurjchem-870	119	29	,	,	PUNCT
eurjchem-870	119	30	nh	nh	PROPN
eurjchem-870	119	31	d2o	d2o	PROPN
eurjchem-870	119	32	exchangeable	exchangeable	ADJ
eurjchem-870	119	33	)	)	PUNCT
eurjchem-870	119	34	,	,	PUNCT
eurjchem-870	119	35	3.87	3.87	NUM
eurjchem-870	119	36	(	(	PUNCT
eurjchem-870	119	37	s	s	PROPN
eurjchem-870	119	38	,	,	PUNCT
eurjchem-870	119	39	3h	3h	NUM
eurjchem-870	119	40	,	,	PUNCT
eurjchem-870	119	41	och3	och3	ADJ
eurjchem-870	119	42	)	)	PUNCT
eurjchem-870	119	43	.	.	PUNCT
eurjchem-870	120	1	ms	ms	NOUN
eurjchem-870	120	2	(	(	PUNCT
eurjchem-870	120	3	ei	ei	PROPN
eurjchem-870	120	4	,	,	PUNCT
eurjchem-870	120	5	m	m	PROPN
eurjchem-870	120	6	/	/	SYM
eurjchem-870	120	7	z	z	PROPN
eurjchem-870	120	8	(	(	PUNCT
eurjchem-870	120	9	%	%	NOUN
eurjchem-870	120	10	)	)	PUNCT
eurjchem-870	120	11	):	):	PUNCT
eurjchem-870	120	12	445	445	NUM
eurjchem-870	120	13	(	(	PUNCT
eurjchem-870	120	14	0.01	0.01	NUM
eurjchem-870	120	15	,	,	PUNCT
eurjchem-870	120	16	m+	m+	NOUN
eurjchem-870	120	17	·	·	PUNCT
eurjchem-870	120	18	)	)	PUNCT
eurjchem-870	120	19	,	,	PUNCT
eurjchem-870	120	20	386	386	NUM
eurjchem-870	120	21	(	(	PUNCT
eurjchem-870	120	22	21.4	21.4	NUM
eurjchem-870	120	23	)	)	PUNCT
eurjchem-870	120	24	,	,	PUNCT
eurjchem-870	120	25	354	354	NUM
eurjchem-870	120	26	(	(	PUNCT
eurjchem-870	120	27	21.4	21.4	NUM
eurjchem-870	120	28	)	)	PUNCT
eurjchem-870	120	29	,	,	PUNCT
eurjchem-870	120	30	238	238	NUM
eurjchem-870	120	31	(	(	PUNCT
eurjchem-870	120	32	16.7	16.7	NUM
eurjchem-870	120	33	)	)	PUNCT
eurjchem-870	120	34	,	,	PUNCT
eurjchem-870	120	35	194	194	NUM
eurjchem-870	120	36	(	(	PUNCT
eurjchem-870	120	37	26.2	26.2	NUM
eurjchem-870	120	38	)	)	PUNCT
eurjchem-870	120	39	,	,	PUNCT
eurjchem-870	120	40	119	119	NUM
eurjchem-870	120	41	(	(	PUNCT
eurjchem-870	120	42	23.8	23.8	NUM
eurjchem-870	120	43	)	)	PUNCT
eurjchem-870	120	44	,	,	PUNCT
eurjchem-870	120	45	106	106	NUM
eurjchem-870	120	46	(	(	PUNCT
eurjchem-870	120	47	23.8	23.8	NUM
eurjchem-870	120	48	)	)	PUNCT
eurjchem-870	120	49	,	,	PUNCT
eurjchem-870	120	50	93	93	NUM
eurjchem-870	120	51	(	(	PUNCT
eurjchem-870	120	52	31.0	31.0	NUM
eurjchem-870	120	53	)	)	PUNCT
eurjchem-870	120	54	,	,	PUNCT
eurjchem-870	120	55	77	77	NUM
eurjchem-870	120	56	(	(	PUNCT
eurjchem-870	120	57	100	100	NUM
eurjchem-870	120	58	)	)	PUNCT
eurjchem-870	120	59	.	.	PUNCT
eurjchem-870	121	1	anal	anal	PROPN
eurjchem-870	121	2	.	.	PUNCT
eurjchem-870	121	3	calcd	calcd	NOUN
eurjchem-870	121	4	.	.	PUNCT
eurjchem-870	122	1	for	for	ADP
eurjchem-870	122	2	c27h19n5o2	c27h19n5o2	PROPN
eurjchem-870	122	3	:	:	PUNCT
eurjchem-870	122	4	c	c	X
eurjchem-870	122	5	,	,	PUNCT
eurjchem-870	122	6	72.80	72.80	NUM
eurjchem-870	122	7	;	;	PUNCT
eurjchem-870	122	8	h	h	NOUN
eurjchem-870	122	9	,	,	PUNCT
eurjchem-870	122	10	4.30	4.30	NUM
eurjchem-870	122	11	;	;	PUNCT
eurjchem-870	122	12	n	n	CCONJ
eurjchem-870	122	13	,	,	PUNCT
eurjchem-870	122	14	15.72	15.72	NUM
eurjchem-870	122	15	.	.	PUNCT
eurjchem-870	122	16	found	find	VERB
eurjchem-870	122	17	:	:	PUNCT
eurjchem-870	123	1	c	c	X
eurjchem-870	123	2	,	,	PUNCT
eurjchem-870	123	3	73.13	73.13	NUM
eurjchem-870	123	4	;	;	PUNCT
eurjchem-870	123	5	h	h	NOUN
eurjchem-870	123	6	,	,	PUNCT
eurjchem-870	123	7	4.70	4.70	NUM
eurjchem-870	123	8	;	;	PUNCT
eurjchem-870	123	9	n	n	CCONJ
eurjchem-870	123	10	,	,	PUNCT
eurjchem-870	123	11	15.90	15.90	NUM
eurjchem-870	123	12	%	%	NOUN
eurjchem-870	123	13	.	.	PUNCT
eurjchem-870	124	1	2.2.8	2.2.8	X
eurjchem-870	124	2	.	.	PUNCT
eurjchem-870	124	3	general	general	ADJ
eurjchem-870	124	4	procedure	procedure	NOUN
eurjchem-870	124	5	for	for	ADP
eurjchem-870	124	6	compounds	compound	NOUN
eurjchem-870	124	7	10	10	NUM
eurjchem-870	124	8	and	and	CCONJ
eurjchem-870	124	9	11	11	NUM
eurjchem-870	124	10	a	a	DET
eurjchem-870	124	11	mixture	mixture	NOUN
eurjchem-870	124	12	of	of	ADP
eurjchem-870	124	13	amino	amino	ADJ
eurjchem-870	124	14	carbonitrile	carbonitrile	NOUN
eurjchem-870	124	15	4	4	NUM
eurjchem-870	124	16	and/or	and/or	CCONJ
eurjchem-870	124	17	5	5	NUM
eurjchem-870	124	18	(	(	PUNCT
eurjchem-870	124	19	0.01	0.01	NUM
eurjchem-870	124	20	 	 	SPACE
eurjchem-870	124	21	mol	mol	NOUN
eurjchem-870	124	22	)	)	PUNCT
eurjchem-870	124	23	and	and	CCONJ
eurjchem-870	124	24	acetic	acetic	ADJ
eurjchem-870	124	25	anhydride	anhydride	NOUN
eurjchem-870	124	26	(	(	PUNCT
eurjchem-870	124	27	20	20	NUM
eurjchem-870	124	28	 	 	SPACE
eurjchem-870	124	29	ml	ml	NOUN
eurjchem-870	124	30	)	)	PUNCT
eurjchem-870	124	31	was	be	AUX
eurjchem-870	124	32	refluxed	refluxe	VERB
eurjchem-870	124	33	for	for	ADP
eurjchem-870	124	34	5	5	NUM
eurjchem-870	124	35	 	 	SPACE
eurjchem-870	124	36	h	h	NOUN
eurjchem-870	124	37	,	,	PUNCT
eurjchem-870	124	38	the	the	DET
eurjchem-870	124	39	reaction	reaction	NOUN
eurjchem-870	124	40	mixture	mixture	NOUN
eurjchem-870	124	41	was	be	AUX
eurjchem-870	124	42	poured	pour	VERB
eurjchem-870	124	43	onto	onto	ADP
eurjchem-870	124	44	water	water	NOUN
eurjchem-870	124	45	,	,	PUNCT
eurjchem-870	124	46	the	the	DET
eurjchem-870	124	47	separated	separate	VERB
eurjchem-870	124	48	solid	solid	ADJ
eurjchem-870	124	49	was	be	AUX
eurjchem-870	124	50	filtered	filter	VERB
eurjchem-870	124	51	off	off	ADP
eurjchem-870	124	52	,	,	PUNCT
eurjchem-870	124	53	washed	wash	VERB
eurjchem-870	124	54	with	with	ADP
eurjchem-870	124	55	water	water	NOUN
eurjchem-870	124	56	,	,	PUNCT
eurjchem-870	124	57	dried	dry	VERB
eurjchem-870	124	58	and	and	CCONJ
eurjchem-870	124	59	recrystallized	recrystallize	VERB
eurjchem-870	124	60	from	from	ADP
eurjchem-870	124	61	benzene	benzene	NOUN
eurjchem-870	124	62	:	:	PUNCT
eurjchem-870	125	1	ethanol	ethanol	NOUN
eurjchem-870	125	2	(	(	PUNCT
eurjchem-870	125	3	2:1	2:1	NUM
eurjchem-870	125	4	)	)	PUNCT
eurjchem-870	125	5	(	(	PUNCT
eurjchem-870	125	6	scheme	scheme	NOUN
eurjchem-870	125	7	2	2	NUM
eurjchem-870	125	8	)	)	PUNCT
eurjchem-870	125	9	.	.	PUNCT
eurjchem-870	126	1	n‐(5‐cyano‐4‐(4‐methoxyphenyl)‐1,3‐diphenyl‐1h‐pyrazolo	n‐(5‐cyano‐4‐(4‐methoxyphenyl)‐1,3‐diphenyl‐1h‐pyrazolo	PROPN
eurjchem-870	126	2	[	[	X
eurjchem-870	126	3	3,4‐b]pyridin‐6‐yl)acetamide	3,4‐b]pyridin‐6‐yl)acetamide	NUM
eurjchem-870	126	4	(	(	PUNCT
eurjchem-870	126	5	10	10	NUM
eurjchem-870	126	6	):	):	PUNCT
eurjchem-870	127	1	color	color	NOUN
eurjchem-870	127	2	:	:	PUNCT
eurjchem-870	127	3	brown	brown	ADJ
eurjchem-870	127	4	.	.	PUNCT
eurjchem-870	127	5	yield	yield	NOUN
eurjchem-870	127	6	:	:	PUNCT
eurjchem-870	127	7	85.45	85.45	NUM
eurjchem-870	127	8	%	%	NOUN
eurjchem-870	127	9	.	.	PUNCT
eurjchem-870	128	1	m.p.:234‐236	m.p.:234‐236	PROPN
eurjchem-870	129	1	°	°	PROPN
eurjchem-870	129	2	c	c	X
eurjchem-870	129	3	.	.	PUNCT
eurjchem-870	130	1	ft‐ir	ft‐ir	NOUN
eurjchem-870	130	2	(	(	PUNCT
eurjchem-870	130	3	kbr,	kbr,	PROPN
eurjchem-870	130	4	,	,	PUNCT
eurjchem-870	130	5	cm‐1	cm‐1	PROPN
eurjchem-870	130	6	):	):	PUNCT
eurjchem-870	130	7	3436	3436	NUM
eurjchem-870	130	8	(	(	PUNCT
eurjchem-870	130	9	nh	nh	NOUN
eurjchem-870	130	10	)	)	PUNCT
eurjchem-870	130	11	,	,	PUNCT
eurjchem-870	130	12	2216	2216	NUM
eurjchem-870	130	13	(	(	PUNCT
eurjchem-870	130	14	c≡n	c≡n	PROPN
eurjchem-870	130	15	)	)	PUNCT
eurjchem-870	130	16	,	,	PUNCT
eurjchem-870	130	17	1712	1712	NUM
eurjchem-870	130	18	(	(	PUNCT
eurjchem-870	130	19	c	c	NOUN
eurjchem-870	130	20	=	=	NOUN
eurjchem-870	130	21	o	o	NOUN
eurjchem-870	130	22	)	)	PUNCT
eurjchem-870	130	23	.	.	PUNCT
eurjchem-870	131	1	1h	1h	NUM
eurjchem-870	131	2	nmr	nmr	NOUN
eurjchem-870	131	3	(	(	PUNCT
eurjchem-870	131	4	300	300	NUM
eurjchem-870	131	5	mhz	mhz	NOUN
eurjchem-870	131	6	,	,	PUNCT
eurjchem-870	131	7	cdcl3	cdcl3	PROPN
eurjchem-870	131	8	,	,	PUNCT
eurjchem-870	131	9	δ	δ	PROPN
eurjchem-870	131	10	,	,	PUNCT
eurjchem-870	131	11	ppm	ppm	NOUN
eurjchem-870	131	12	):	):	PUNCT
eurjchem-870	131	13	7.01‐	7.01‐	NUM
eurjchem-870	131	14	8.10	8.10	NUM
eurjchem-870	131	15	(	(	PUNCT
eurjchem-870	131	16	m	m	PROPN
eurjchem-870	131	17	,	,	PUNCT
eurjchem-870	131	18	15h	15h	NUM
eurjchem-870	131	19	,	,	PUNCT
eurjchem-870	131	20	14arh	14arh	INTJ
eurjchem-870	131	21	,	,	PUNCT
eurjchem-870	131	22	nh	nh	PROPN
eurjchem-870	131	23	)	)	PUNCT
eurjchem-870	131	24	,	,	PUNCT
eurjchem-870	131	25	3.92	3.92	NUM
eurjchem-870	131	26	(	(	PUNCT
eurjchem-870	131	27	s	s	PROPN
eurjchem-870	131	28	,	,	PUNCT
eurjchem-870	131	29	3h	3h	NUM
eurjchem-870	131	30	,	,	PUNCT
eurjchem-870	131	31	och3	och3	ADJ
eurjchem-870	131	32	)	)	PUNCT
eurjchem-870	131	33	,	,	PUNCT
eurjchem-870	131	34	1.26	1.26	NUM
eurjchem-870	131	35	(	(	PUNCT
eurjchem-870	131	36	s	s	PROPN
eurjchem-870	131	37	,	,	PUNCT
eurjchem-870	131	38	3h	3h	NUM
eurjchem-870	131	39	,	,	PUNCT
eurjchem-870	131	40	coch3	coch3	NOUN
eurjchem-870	131	41	)	)	PUNCT
eurjchem-870	131	42	.	.	PUNCT
eurjchem-870	132	1	ms	ms	NOUN
eurjchem-870	132	2	(	(	PUNCT
eurjchem-870	132	3	ei	ei	PROPN
eurjchem-870	132	4	,	,	PUNCT
eurjchem-870	132	5	m	m	PROPN
eurjchem-870	132	6	/	/	SYM
eurjchem-870	132	7	z	z	PROPN
eurjchem-870	132	8	(	(	PUNCT
eurjchem-870	132	9	%	%	NOUN
eurjchem-870	132	10	)	)	PUNCT
eurjchem-870	132	11	):	):	PUNCT
eurjchem-870	132	12	459	459	NUM
eurjchem-870	132	13	(	(	PUNCT
eurjchem-870	132	14	16.7	16.7	NUM
eurjchem-870	132	15	%	%	NOUN
eurjchem-870	132	16	,	,	PUNCT
eurjchem-870	132	17	m+	m+	NOUN
eurjchem-870	132	18	·	·	PUNCT
eurjchem-870	132	19	)	)	PUNCT
eurjchem-870	132	20	,	,	PUNCT
eurjchem-870	132	21	355	355	NUM
eurjchem-870	132	22	(	(	PUNCT
eurjchem-870	132	23	19.4	19.4	NUM
eurjchem-870	132	24	)	)	PUNCT
eurjchem-870	132	25	,	,	PUNCT
eurjchem-870	132	26	279	279	NUM
eurjchem-870	132	27	(	(	PUNCT
eurjchem-870	132	28	16.7	16.7	NUM
eurjchem-870	132	29	)	)	PUNCT
eurjchem-870	132	30	,	,	PUNCT
eurjchem-870	132	31	135	135	NUM
eurjchem-870	132	32	(	(	PUNCT
eurjchem-870	132	33	27.8	27.8	NUM
eurjchem-870	132	34	)	)	PUNCT
eurjchem-870	132	35	,	,	PUNCT
eurjchem-870	132	36	121	121	NUM
eurjchem-870	132	37	(	(	PUNCT
eurjchem-870	132	38	50.0	50.0	NUM
eurjchem-870	132	39	)	)	PUNCT
eurjchem-870	132	40	,	,	PUNCT
eurjchem-870	132	41	119	119	NUM
eurjchem-870	132	42	(	(	PUNCT
eurjchem-870	132	43	22.2	22.2	NUM
eurjchem-870	132	44	)	)	PUNCT
eurjchem-870	132	45	,	,	PUNCT
eurjchem-870	132	46	93	93	NUM
eurjchem-870	132	47	(	(	PUNCT
eurjchem-870	132	48	22.2	22.2	NUM
eurjchem-870	132	49	)	)	PUNCT
eurjchem-870	132	50	,	,	PUNCT
eurjchem-870	132	51	78	78	NUM
eurjchem-870	132	52	(	(	PUNCT
eurjchem-870	132	53	16.7	16.7	NUM
eurjchem-870	132	54	)	)	PUNCT
eurjchem-870	132	55	,	,	PUNCT
eurjchem-870	132	56	77	77	NUM
eurjchem-870	132	57	(	(	PUNCT
eurjchem-870	132	58	100	100	NUM
eurjchem-870	132	59	)	)	PUNCT
eurjchem-870	132	60	.	.	PUNCT
eurjchem-870	133	1	anal	anal	PROPN
eurjchem-870	133	2	.	.	PUNCT
eurjchem-870	133	3	calcd	calcd	NOUN
eurjchem-870	133	4	.	.	PUNCT
eurjchem-870	134	1	for	for	SCONJ
eurjchem-870	134	2	c28h21n5o2	c28h21n5o2	PROPN
eurjchem-870	134	3	:	:	PUNCT
eurjchem-870	134	4	c	c	X
eurjchem-870	134	5	,	,	PUNCT
eurjchem-870	134	6	73.19	73.19	NUM
eurjchem-870	134	7	;	;	PUNCT
eurjchem-870	134	8	h	h	NOUN
eurjchem-870	134	9	,	,	PUNCT
eurjchem-870	134	10	4.61	4.61	NUM
eurjchem-870	134	11	;	;	PUNCT
eurjchem-870	134	12	n	n	CCONJ
eurjchem-870	134	13	,	,	PUNCT
eurjchem-870	134	14	15.24	15.24	NUM
eurjchem-870	134	15	.	.	PUNCT
eurjchem-870	134	16	found	find	VERB
eurjchem-870	134	17	:	:	PUNCT
eurjchem-870	135	1	c	c	X
eurjchem-870	135	2	,	,	PUNCT
eurjchem-870	135	3	73.17	73.17	NUM
eurjchem-870	135	4	;	;	PUNCT
eurjchem-870	135	5	h	h	X
eurjchem-870	135	6	,	,	PUNCT
eurjchem-870	135	7	4.50	4.50	NUM
eurjchem-870	135	8	;	;	PUNCT
eurjchem-870	135	9	n	n	CCONJ
eurjchem-870	135	10	,	,	PUNCT
eurjchem-870	135	11	15.36	15.36	NUM
eurjchem-870	135	12	%	%	NOUN
eurjchem-870	135	13	.	.	PUNCT
eurjchem-870	136	1	n‐(5‐cyano‐4‐(4‐methoxyphenyl)‐1,3‐diphenyl‐1,4‐dihydro	n‐(5‐cyano‐4‐(4‐methoxyphenyl)‐1,3‐diphenyl‐1,4‐dihydro	PROPN
eurjchem-870	136	2	pyrano[2,3‐c]pyrazol‐6‐yl)acetamide	pyrano[2,3‐c]pyrazol‐6‐yl)acetamide	X
eurjchem-870	136	3	(	(	PUNCT
eurjchem-870	136	4	11	11	NUM
eurjchem-870	136	5	):	):	PUNCT
eurjchem-870	136	6	color	color	NOUN
eurjchem-870	136	7	:	:	PUNCT
eurjchem-870	136	8	dark	dark	PROPN
eurjchem-870	136	9	brown	brown	PROPN
eurjchem-870	136	10	.	.	PUNCT
eurjchem-870	137	1	yield	yield	NOUN
eurjchem-870	137	2	:	:	PUNCT
eurjchem-870	137	3	55.88	55.88	NUM
eurjchem-870	137	4	%	%	NOUN
eurjchem-870	137	5	.	.	PUNCT
eurjchem-870	138	1	m.p	m.p	PROPN
eurjchem-870	138	2	.	.	PROPN
eurjchem-870	138	3	:	:	PUNCT
eurjchem-870	139	1	>	>	PUNCT
eurjchem-870	139	2	300	300	NUM
eurjchem-870	139	3	°	°	SYM
eurjchem-870	139	4	c	c	NOUN
eurjchem-870	139	5	.	.	PUNCT
eurjchem-870	140	1	ft‐ir	ft‐ir	NOUN
eurjchem-870	140	2	(	(	PUNCT
eurjchem-870	140	3	kbr	kbr	PROPN
eurjchem-870	140	4	,	,	PUNCT
eurjchem-870	140	5			PROPN
eurjchem-870	140	6	,	,	PUNCT
eurjchem-870	140	7	cm‐1	cm‐1	PROPN
eurjchem-870	140	8	):	):	PUNCT
eurjchem-870	140	9	3421	3421	NUM
eurjchem-870	140	10	(	(	PUNCT
eurjchem-870	140	11	nh	nh	NOUN
eurjchem-870	140	12	)	)	PUNCT
eurjchem-870	140	13	,	,	PUNCT
eurjchem-870	140	14	2211	2211	NUM
eurjchem-870	140	15	(	(	PUNCT
eurjchem-870	140	16	c≡n	c≡n	PROPN
eurjchem-870	140	17	)	)	PUNCT
eurjchem-870	140	18	,	,	PUNCT
eurjchem-870	140	19	1714	1714	NUM
eurjchem-870	140	20	(	(	PUNCT
eurjchem-870	140	21	c	c	NOUN
eurjchem-870	140	22	=	=	NOUN
eurjchem-870	140	23	o	o	NOUN
eurjchem-870	140	24	)	)	PUNCT
eurjchem-870	140	25	,	,	PUNCT
eurjchem-870	140	26	1598	1598	NUM
eurjchem-870	140	27	(	(	PUNCT
eurjchem-870	140	28	c	c	NOUN
eurjchem-870	140	29	=	=	SYM
eurjchem-870	140	30	n	n	NUM
eurjchem-870	140	31	)	)	PUNCT
eurjchem-870	140	32	.	.	PUNCT
eurjchem-870	141	1	1h	1h	NUM
eurjchem-870	141	2	nmr	nmr	NOUN
eurjchem-870	141	3	(	(	PUNCT
eurjchem-870	141	4	300	300	NUM
eurjchem-870	141	5	mhz	mhz	NOUN
eurjchem-870	141	6	,	,	PUNCT
eurjchem-870	141	7	cdcl3	cdcl3	PROPN
eurjchem-870	141	8	,	,	PUNCT
eurjchem-870	141	9	δ	δ	PROPN
eurjchem-870	141	10	,	,	PUNCT
eurjchem-870	141	11	ppm	ppm	NUM
eurjchem-870	141	12	):	):	PUNCT
eurjchem-870	141	13	6.47‐7.90	6.47‐7.90	NUM
eurjchem-870	141	14	(	(	PUNCT
eurjchem-870	141	15	m	m	PROPN
eurjchem-870	141	16	,	,	PUNCT
eurjchem-870	141	17	15h	15h	NUM
eurjchem-870	141	18	,	,	PUNCT
eurjchem-870	141	19	14	14	NUM
eurjchem-870	141	20	arh	arh	PROPN
eurjchem-870	141	21	,	,	PUNCT
eurjchem-870	141	22	nh	nh	PROPN
eurjchem-870	141	23	)	)	PUNCT
eurjchem-870	141	24	,	,	PUNCT
eurjchem-870	141	25	3.94	3.94	NUM
eurjchem-870	141	26	(	(	PUNCT
eurjchem-870	141	27	s	s	PROPN
eurjchem-870	141	28	,	,	PUNCT
eurjchem-870	141	29	1h	1h	NUM
eurjchem-870	141	30	,	,	PUNCT
eurjchem-870	141	31	benzilic	benzilic	NOUN
eurjchem-870	141	32	)	)	PUNCT
eurjchem-870	141	33	,	,	PUNCT
eurjchem-870	141	34	3.78	3.78	NUM
eurjchem-870	141	35	(	(	PUNCT
eurjchem-870	141	36	s	s	PROPN
eurjchem-870	141	37	,	,	PUNCT
eurjchem-870	141	38	3h	3h	NUM
eurjchem-870	141	39	,	,	PUNCT
eurjchem-870	141	40	och3	och3	ADJ
eurjchem-870	141	41	)	)	PUNCT
eurjchem-870	141	42	,	,	PUNCT
eurjchem-870	141	43	2.07	2.07	NUM
eurjchem-870	141	44	(	(	PUNCT
eurjchem-870	141	45	s	s	PROPN
eurjchem-870	141	46	,	,	PUNCT
eurjchem-870	141	47	3h	3h	NUM
eurjchem-870	141	48	,	,	PUNCT
eurjchem-870	141	49	coch3	coch3	NOUN
eurjchem-870	141	50	)	)	PUNCT
eurjchem-870	141	51	.	.	PUNCT
eurjchem-870	142	1	ms	ms	NOUN
eurjchem-870	142	2	(	(	PUNCT
eurjchem-870	142	3	ei	ei	PROPN
eurjchem-870	142	4	,	,	PUNCT
eurjchem-870	142	5	m	m	PROPN
eurjchem-870	142	6	/	/	SYM
eurjchem-870	142	7	z	z	PROPN
eurjchem-870	142	8	(	(	PUNCT
eurjchem-870	142	9	%	%	NOUN
eurjchem-870	142	10	)	)	PUNCT
eurjchem-870	142	11	):	):	PUNCT
eurjchem-870	142	12	431	431	NUM
eurjchem-870	142	13	(	(	PUNCT
eurjchem-870	142	14	7.8	7.8	NUM
eurjchem-870	142	15	,	,	PUNCT
eurjchem-870	142	16	[	[	X
eurjchem-870	142	17	m	m	VERB
eurjchem-870	142	18	‐	‐	ADJ
eurjchem-870	142	19	ch3o·]+	ch3o·]+	PROPN
eurjchem-870	142	20	)	)	PUNCT
eurjchem-870	142	21	,	,	PUNCT
eurjchem-870	142	22	236	236	NUM
eurjchem-870	142	23	(	(	PUNCT
eurjchem-870	142	24	19.6	19.6	NUM
eurjchem-870	142	25	)	)	PUNCT
eurjchem-870	142	26	,	,	PUNCT
eurjchem-870	142	27	126	126	NUM
eurjchem-870	142	28	(	(	PUNCT
eurjchem-870	142	29	13.7	13.7	NUM
eurjchem-870	142	30	)	)	PUNCT
eurjchem-870	142	31	,	,	PUNCT
eurjchem-870	142	32	84	84	NUM
eurjchem-870	142	33	(	(	PUNCT
eurjchem-870	142	34	25.5	25.5	NUM
eurjchem-870	142	35	)	)	PUNCT
eurjchem-870	142	36	,	,	PUNCT
eurjchem-870	142	37	70	70	NUM
eurjchem-870	142	38	(	(	PUNCT
eurjchem-870	142	39	27.5	27.5	NUM
eurjchem-870	142	40	)	)	PUNCT
eurjchem-870	142	41	,	,	PUNCT
eurjchem-870	142	42	64	64	NUM
eurjchem-870	142	43	(	(	PUNCT
eurjchem-870	142	44	100	100	NUM
eurjchem-870	142	45	)	)	PUNCT
eurjchem-870	142	46	,	,	PUNCT
eurjchem-870	142	47	55	55	NUM
eurjchem-870	142	48	(	(	PUNCT
eurjchem-870	142	49	23.5	23.5	NUM
eurjchem-870	142	50	)	)	PUNCT
eurjchem-870	142	51	,	,	PUNCT
eurjchem-870	142	52	53	53	NUM
eurjchem-870	142	53	(	(	PUNCT
eurjchem-870	142	54	37.3	37.3	NUM
eurjchem-870	142	55	)	)	PUNCT
eurjchem-870	142	56	.	.	PUNCT
eurjchem-870	143	1	anal	anal	PROPN
eurjchem-870	143	2	.	.	PUNCT
eurjchem-870	143	3	calcd	calcd	NOUN
eurjchem-870	143	4	.	.	PUNCT
eurjchem-870	144	1	for	for	SCONJ
eurjchem-870	144	2	c28h22n4o3	c28h22n4o3	NOUN
eurjchem-870	144	3	:	:	PUNCT
eurjchem-870	144	4	c	c	X
eurjchem-870	144	5	,	,	PUNCT
eurjchem-870	144	6	72.71	72.71	NUM
eurjchem-870	144	7	;	;	PUNCT
eurjchem-870	144	8	h	h	X
eurjchem-870	144	9	,	,	PUNCT
eurjchem-870	144	10	4.79	4.79	NUM
eurjchem-870	144	11	;	;	PUNCT
eurjchem-870	144	12	n	n	CCONJ
eurjchem-870	144	13	,	,	PUNCT
eurjchem-870	144	14	12.11	12.11	NUM
eurjchem-870	144	15	.	.	PUNCT
eurjchem-870	144	16	found	find	VERB
eurjchem-870	144	17	:	:	PUNCT
eurjchem-870	145	1	c	c	X
eurjchem-870	145	2	,	,	PUNCT
eurjchem-870	145	3	72.65	72.65	NUM
eurjchem-870	145	4	;	;	PUNCT
eurjchem-870	145	5	h	h	NOUN
eurjchem-870	145	6	,	,	PUNCT
eurjchem-870	145	7	4.58	4.58	NUM
eurjchem-870	145	8	;	;	PUNCT
eurjchem-870	145	9	n	n	CCONJ
eurjchem-870	145	10	,	,	PUNCT
eurjchem-870	145	11	12.90	12.90	NUM
eurjchem-870	145	12	%	%	NOUN
eurjchem-870	145	13	.	.	PUNCT
eurjchem-870	146	1	2.2.9	2.2.9	X
eurjchem-870	146	2	.	.	PUNCT
eurjchem-870	147	1	6,6'‐(1,1’(hydrazine‐1,2‐diylbis(ethane‐1,1‐diyl	6,6'‐(1,1’(hydrazine‐1,2‐diylbis(ethane‐1,1‐diyl	NUM
eurjchem-870	147	2	)	)	PUNCT
eurjchem-870	147	3	)	)	PUNCT
eurjchem-870	148	1	bis(azanediyl))bis(4‐(4‐methoxyphenyl)‐1,3‐diphenyl‐1,4‐	bis(azanediyl))bis(4‐(4‐methoxyphenyl)‐1,3‐diphenyl‐1,4‐	DET
eurjchem-870	148	2	dihydropyrano[2,3‐c]pyrazole‐5‐carbonitrile	dihydropyrano[2,3‐c]pyrazole‐5‐carbonitrile	NOUN
eurjchem-870	148	3	)	)	PUNCT
eurjchem-870	148	4	(	(	PUNCT
eurjchem-870	148	5	12	12	NUM
eurjchem-870	148	6	)	)	PUNCT
eurjchem-870	148	7	a	a	DET
eurjchem-870	148	8	 	 	SPACE
eurjchem-870	148	9	mixture	mixture	NOUN
eurjchem-870	148	10	of	of	ADP
eurjchem-870	148	11	pyrazoloacetamide	pyrazoloacetamide	ADJ
eurjchem-870	148	12	11	11	NUM
eurjchem-870	148	13	(	(	PUNCT
eurjchem-870	148	14	4.62	4.62	NUM
eurjchem-870	148	15	 	 	SPACE
eurjchem-870	148	16	g	g	NOUN
eurjchem-870	148	17	,	,	PUNCT
eurjchem-870	148	18	0.01	0.01	NUM
eurjchem-870	148	19	 	 	SPACE
eurjchem-870	148	20	mol	mol	NOUN
eurjchem-870	148	21	)	)	PUNCT
eurjchem-870	148	22	hydrazine	hydrazine	NOUN
eurjchem-870	148	23	hydrate	hydrate	NOUN
eurjchem-870	148	24	(	(	PUNCT
eurjchem-870	148	25	0.5	0.5	NUM
eurjchem-870	148	26	 	 	SPACE
eurjchem-870	148	27	ml	ml	NOUN
eurjchem-870	148	28	,	,	PUNCT
eurjchem-870	148	29	0.01	0.01	NUM
eurjchem-870	148	30	 	 	SPACE
eurjchem-870	148	31	mol	mol	NOUN
eurjchem-870	148	32	)	)	PUNCT
eurjchem-870	148	33	in	in	ADP
eurjchem-870	148	34	absolute	absolute	ADJ
eurjchem-870	148	35	ethanol	ethanol	NOUN
eurjchem-870	148	36	(	(	PUNCT
eurjchem-870	148	37	50	50	NUM
eurjchem-870	148	38	 	 	SPACE
eurjchem-870	148	39	ml	ml	NOUN
eurjchem-870	148	40	)	)	PUNCT
eurjchem-870	148	41	was	be	AUX
eurjchem-870	148	42	refluxed	refluxe	VERB
eurjchem-870	148	43	for	for	ADP
eurjchem-870	148	44	2	2	NUM
eurjchem-870	148	45	 	 	SPACE
eurjchem-870	148	46	h	h	NOUN
eurjchem-870	148	47	,	,	PUNCT
eurjchem-870	148	48	the	the	DET
eurjchem-870	148	49	reaction	reaction	NOUN
eurjchem-870	148	50	mixture	mixture	NOUN
eurjchem-870	148	51	was	be	AUX
eurjchem-870	148	52	poured	pour	VERB
eurjchem-870	148	53	onto	onto	ADP
eurjchem-870	148	54	ice	ice	NOUN
eurjchem-870	148	55	:	:	PUNCT
eurjchem-870	148	56	hcl	hcl	PROPN
eurjchem-870	148	57	(	(	PUNCT
eurjchem-870	148	58	1:3	1:3	NUM
eurjchem-870	148	59	)	)	PUNCT
eurjchem-870	148	60	.	.	PUNCT
eurjchem-870	149	1	the	the	DET
eurjchem-870	149	2	solid	solid	ADJ
eurjchem-870	149	3	that	that	PRON
eurjchem-870	149	4	separated	separate	VERB
eurjchem-870	149	5	was	be	AUX
eurjchem-870	149	6	filtered	filter	VERB
eurjchem-870	149	7	off	off	ADP
eurjchem-870	149	8	,	,	PUNCT
eurjchem-870	149	9	washed	wash	VERB
eurjchem-870	149	10	with	with	ADP
eurjchem-870	149	11	water	water	NOUN
eurjchem-870	149	12	,	,	PUNCT
eurjchem-870	149	13	dried	dry	VERB
eurjchem-870	149	14	and	and	CCONJ
eurjchem-870	149	15	recrystallized	recrystallize	VERB
eurjchem-870	149	16	from	from	ADP
eurjchem-870	149	17	benzene	benzene	NOUN
eurjchem-870	149	18	:	:	PUNCT
eurjchem-870	149	19	ethanol	ethanol	NOUN
eurjchem-870	149	20	(	(	PUNCT
eurjchem-870	149	21	2:1	2:1	NUM
eurjchem-870	149	22	)	)	PUNCT
eurjchem-870	149	23	(	(	PUNCT
eurjchem-870	149	24	scheme	scheme	NOUN
eurjchem-870	149	25	1	1	NUM
eurjchem-870	149	26	)	)	PUNCT
eurjchem-870	149	27	.	.	PUNCT
eurjchem-870	150	1	color	color	NOUN
eurjchem-870	150	2	:	:	PUNCT
eurjchem-870	150	3	pale	pale	ADJ
eurjchem-870	150	4	brown	brown	NOUN
eurjchem-870	150	5	.	.	PUNCT
eurjchem-870	151	1	yield	yield	NOUN
eurjchem-870	151	2	:	:	PUNCT
eurjchem-870	151	3	22	22	NUM
eurjchem-870	151	4	%	%	NOUN
eurjchem-870	151	5	.	.	PUNCT
eurjchem-870	152	1	m.p	m.p	PROPN
eurjchem-870	152	2	.	.	PROPN
eurjchem-870	152	3	:	:	PUNCT
eurjchem-870	153	1	280‐282	280‐282	PROPN
eurjchem-870	153	2	°	°	NUM
eurjchem-870	153	3	c	c	NOUN
eurjchem-870	153	4	.	.	PUNCT
eurjchem-870	154	1	ft‐ir	ft‐ir	NOUN
eurjchem-870	154	2	(	(	PUNCT
eurjchem-870	154	3	kbr	kbr	PROPN
eurjchem-870	154	4	,	,	PUNCT
eurjchem-870	154	5			PROPN
eurjchem-870	154	6	,	,	PUNCT
eurjchem-870	154	7	cm‐1	cm‐1	PROPN
eurjchem-870	154	8	):	):	PUNCT
eurjchem-870	154	9	3336	3336	NUM
eurjchem-870	154	10	(	(	PUNCT
eurjchem-870	154	11	nh	nh	NOUN
eurjchem-870	154	12	)	)	PUNCT
eurjchem-870	154	13	,	,	PUNCT
eurjchem-870	154	14	2207	2207	NUM
eurjchem-870	154	15	(	(	PUNCT
eurjchem-870	154	16	c≡n	c≡n	PROPN
eurjchem-870	154	17	)	)	PUNCT
eurjchem-870	154	18	,	,	PUNCT
eurjchem-870	154	19	1600	1600	NUM
eurjchem-870	154	20	(	(	PUNCT
eurjchem-870	154	21	c	c	NOUN
eurjchem-870	154	22	=	=	SYM
eurjchem-870	154	23	n	n	NUM
eurjchem-870	154	24	)	)	PUNCT
eurjchem-870	154	25	.	.	PUNCT
eurjchem-870	155	1	1h	1h	NUM
eurjchem-870	155	2	nmr	nmr	NOUN
eurjchem-870	155	3	(	(	PUNCT
eurjchem-870	155	4	300	300	NUM
eurjchem-870	155	5	mhz	mhz	NOUN
eurjchem-870	155	6	,	,	PUNCT
eurjchem-870	155	7	cdcl3	cdcl3	PROPN
eurjchem-870	155	8	,	,	PUNCT
eurjchem-870	155	9	δ	δ	PROPN
eurjchem-870	155	10	,	,	PUNCT
eurjchem-870	155	11	ppm	ppm	NUM
eurjchem-870	155	12	):	):	PUNCT
eurjchem-870	155	13	6.83‐	6.83‐	NUM
eurjchem-870	155	14	7.79	7.79	NUM
eurjchem-870	155	15	(	(	PUNCT
eurjchem-870	155	16	m	m	PROPN
eurjchem-870	155	17	,	,	PUNCT
eurjchem-870	155	18	28h	28h	NUM
eurjchem-870	155	19	,	,	PUNCT
eurjchem-870	155	20	arh	arh	PROPN
eurjchem-870	155	21	)	)	PUNCT
eurjchem-870	155	22	,	,	PUNCT
eurjchem-870	155	23	3.83	3.83	NUM
eurjchem-870	155	24	(	(	PUNCT
eurjchem-870	155	25	s	s	PROPN
eurjchem-870	155	26	,	,	PUNCT
eurjchem-870	155	27	2h	2h	NUM
eurjchem-870	155	28	,	,	PUNCT
eurjchem-870	155	29	benzilic	benzilic	NOUN
eurjchem-870	155	30	)	)	PUNCT
eurjchem-870	155	31	,	,	PUNCT
eurjchem-870	155	32	3.69	3.69	NUM
eurjchem-870	155	33	(	(	PUNCT
eurjchem-870	155	34	m	m	PROPN
eurjchem-870	155	35	,	,	PUNCT
eurjchem-870	155	36	2h	2h	NUM
eurjchem-870	155	37	,	,	PUNCT
eurjchem-870	155	38	2chnh	2chnh	NUM
eurjchem-870	155	39	)	)	PUNCT
eurjchem-870	155	40	,	,	PUNCT
eurjchem-870	155	41	3.49	3.49	NUM
eurjchem-870	155	42	(	(	PUNCT
eurjchem-870	155	43	s	s	PROPN
eurjchem-870	155	44	,	,	PUNCT
eurjchem-870	155	45	6h	6h	NUM
eurjchem-870	155	46	,	,	PUNCT
eurjchem-870	155	47	2och3	2och3	NUM
eurjchem-870	155	48	)	)	PUNCT
eurjchem-870	155	49	,	,	PUNCT
eurjchem-870	155	50	2.73	2.73	NUM
eurjchem-870	155	51	(	(	PUNCT
eurjchem-870	155	52	s	s	PROPN
eurjchem-870	155	53	,	,	PUNCT
eurjchem-870	155	54	4h	4h	NUM
eurjchem-870	155	55	,	,	PUNCT
eurjchem-870	155	56	4nh	4nh	NOUN
eurjchem-870	155	57	d2o	d2o	NOUN
eurjchem-870	155	58	exchangeable	exchangeable	ADJ
eurjchem-870	155	59	)	)	PUNCT
eurjchem-870	155	60	,	,	PUNCT
eurjchem-870	155	61	1.04(d	1.04(d	PROPN
eurjchem-870	155	62	,	,	PUNCT
eurjchem-870	155	63	6h	6h	NUM
eurjchem-870	155	64	,	,	PUNCT
eurjchem-870	155	65	2ch3	2ch3	NUM
eurjchem-870	155	66	)	)	PUNCT
eurjchem-870	155	67	.	.	PUNCT
eurjchem-870	156	1	ms	ms	NOUN
eurjchem-870	156	2	(	(	PUNCT
eurjchem-870	156	3	ei	ei	PROPN
eurjchem-870	156	4	,	,	PUNCT
eurjchem-870	156	5	m	m	PROPN
eurjchem-870	156	6	/	/	SYM
eurjchem-870	156	7	z	z	PROPN
eurjchem-870	156	8	(	(	PUNCT
eurjchem-870	156	9	%	%	NOUN
eurjchem-870	156	10	)	)	PUNCT
eurjchem-870	156	11	):	):	PUNCT
eurjchem-870	156	12	926	926	NUM
eurjchem-870	156	13	(	(	PUNCT
eurjchem-870	156	14	18.8	18.8	NUM
eurjchem-870	156	15	,	,	PUNCT
eurjchem-870	156	16	m+2	m+2	NOUN
eurjchem-870	156	17	)	)	PUNCT
eurjchem-870	156	18	,	,	PUNCT
eurjchem-870	156	19	319	319	NUM
eurjchem-870	156	20	(	(	PUNCT
eurjchem-870	156	21	15.6	15.6	NUM
eurjchem-870	156	22	)	)	PUNCT
eurjchem-870	156	23	,	,	PUNCT
eurjchem-870	156	24	234	234	NUM
eurjchem-870	156	25	(	(	PUNCT
eurjchem-870	156	26	15.6	15.6	NUM
eurjchem-870	156	27	)	)	PUNCT
eurjchem-870	156	28	,	,	PUNCT
eurjchem-870	156	29	128	128	NUM
eurjchem-870	156	30	(	(	PUNCT
eurjchem-870	156	31	12.5	12.5	NUM
eurjchem-870	156	32	)	)	PUNCT
eurjchem-870	156	33	,	,	PUNCT
eurjchem-870	156	34	112	112	NUM
eurjchem-870	156	35	(	(	PUNCT
eurjchem-870	156	36	18.8	18.8	NUM
eurjchem-870	156	37	)	)	PUNCT
eurjchem-870	156	38	,	,	PUNCT
eurjchem-870	156	39	84	84	NUM
eurjchem-870	156	40	(	(	PUNCT
eurjchem-870	156	41	40.6	40.6	NUM
eurjchem-870	156	42	)	)	PUNCT
eurjchem-870	156	43	,	,	PUNCT
eurjchem-870	156	44	78	78	NUM
eurjchem-870	156	45	(	(	PUNCT
eurjchem-870	156	46	40.6	40.6	NUM
eurjchem-870	156	47	)	)	PUNCT
eurjchem-870	156	48	,	,	PUNCT
eurjchem-870	156	49	77	77	NUM
eurjchem-870	156	50	(	(	PUNCT
eurjchem-870	156	51	62.5	62.5	NUM
eurjchem-870	156	52	)	)	PUNCT
eurjchem-870	156	53	,	,	PUNCT
eurjchem-870	156	54	60	60	NUM
eurjchem-870	156	55	(	(	PUNCT
eurjchem-870	156	56	46.9	46.9	NUM
eurjchem-870	156	57	)	)	PUNCT
eurjchem-870	156	58	,	,	PUNCT
eurjchem-870	156	59	58	58	NUM
eurjchem-870	156	60	(	(	PUNCT
eurjchem-870	156	61	56.3	56.3	NUM
eurjchem-870	156	62	)	)	PUNCT
eurjchem-870	156	63	,	,	PUNCT
eurjchem-870	156	64	56	56	NUM
eurjchem-870	156	65	(	(	PUNCT
eurjchem-870	156	66	75.0	75.0	NUM
eurjchem-870	156	67	)	)	PUNCT
eurjchem-870	156	68	,	,	PUNCT
eurjchem-870	156	69	55	55	NUM
eurjchem-870	156	70	(	(	PUNCT
eurjchem-870	156	71	100	100	NUM
eurjchem-870	156	72	)	)	PUNCT
eurjchem-870	156	73	.	.	PUNCT
eurjchem-870	157	1	anal	anal	PROPN
eurjchem-870	157	2	.	.	PUNCT
eurjchem-870	157	3	calcd	calcd	NOUN
eurjchem-870	157	4	.	.	PUNCT
eurjchem-870	158	1	for	for	ADP
eurjchem-870	158	2	c56h48n10o4	c56h48n10o4	PROPN
eurjchem-870	158	3	:	:	PUNCT
eurjchem-870	158	4	c	c	X
eurjchem-870	158	5	,	,	PUNCT
eurjchem-870	158	6	72.71	72.71	NUM
eurjchem-870	158	7	;	;	PUNCT
eurjchem-870	158	8	h	h	NOUN
eurjchem-870	158	9	,	,	PUNCT
eurjchem-870	158	10	5.23	5.23	NUM
eurjchem-870	158	11	;	;	PUNCT
eurjchem-870	158	12	n	n	CCONJ
eurjchem-870	158	13	,	,	PUNCT
eurjchem-870	158	14	15.14	15.14	NUM
eurjchem-870	158	15	.	.	PUNCT
eurjchem-870	158	16	found	find	VERB
eurjchem-870	158	17	:	:	PUNCT
eurjchem-870	159	1	c	c	X
eurjchem-870	159	2	,	,	PUNCT
eurjchem-870	159	3	72.53	72.53	NUM
eurjchem-870	159	4	;	;	PUNCT
eurjchem-870	159	5	h	h	NOUN
eurjchem-870	159	6	,	,	PUNCT
eurjchem-870	159	7	5.34	5.34	NUM
eurjchem-870	159	8	;	;	PUNCT
eurjchem-870	159	9	n	n	CCONJ
eurjchem-870	159	10	,	,	PUNCT
eurjchem-870	159	11	15.20	15.20	NUM
eurjchem-870	159	12	%	%	NOUN
eurjchem-870	159	13	.	.	PUNCT
eurjchem-870	160	1	2.2.10	2.2.10	NUM
eurjchem-870	160	2	.	.	PUNCT
eurjchem-870	161	1	4‐(2,3,4,5,6‐pentahydroxyhexylidene)‐1,3‐diphenyl‐	4‐(2,3,4,5,6‐pentahydroxyhexylidene)‐1,3‐diphenyl‐	PROPN
eurjchem-870	161	2	1h‐pyrazol‐5(4h)‐one	1h‐pyrazol‐5(4h)‐one	NUM
eurjchem-870	161	3	(	(	PUNCT
eurjchem-870	161	4	13	13	NUM
eurjchem-870	161	5	)	)	PUNCT
eurjchem-870	161	6	a	a	DET
eurjchem-870	161	7	mixture	mixture	NOUN
eurjchem-870	161	8	of	of	ADP
eurjchem-870	161	9	pyrazolone	pyrazolone	NOUN
eurjchem-870	161	10	3	3	NUM
eurjchem-870	161	11	(	(	PUNCT
eurjchem-870	161	12	2.36	2.36	NUM
eurjchem-870	161	13	 	 	SPACE
eurjchem-870	161	14	g	g	NOUN
eurjchem-870	161	15	,	,	PUNCT
eurjchem-870	161	16	0.01	0.01	NUM
eurjchem-870	161	17	 	 	SPACE
eurjchem-870	161	18	mol	mol	NUM
eurjchem-870	161	19	)	)	PUNCT
eurjchem-870	161	20	,	,	PUNCT
eurjchem-870	161	21	glucose	glucose	NOUN
eurjchem-870	161	22	(	(	PUNCT
eurjchem-870	161	23	2.3	2.3	NUM
eurjchem-870	161	24	 	 	SPACE
eurjchem-870	161	25	g	g	NOUN
eurjchem-870	161	26	,	,	PUNCT
eurjchem-870	161	27	0.01	0.01	NUM
eurjchem-870	161	28	 	 	SPACE
eurjchem-870	161	29	mol	mol	NOUN
eurjchem-870	161	30	)	)	PUNCT
eurjchem-870	161	31	in	in	ADP
eurjchem-870	161	32	h2o	h2o	PROPN
eurjchem-870	161	33	(	(	PUNCT
eurjchem-870	161	34	1	1	NUM
eurjchem-870	161	35	 	 	SPACE
eurjchem-870	161	36	ml	ml	NOUN
eurjchem-870	161	37	)	)	PUNCT
eurjchem-870	161	38	,	,	PUNCT
eurjchem-870	161	39	ethanol	ethanol	NOUN
eurjchem-870	161	40	(	(	PUNCT
eurjchem-870	161	41	5	5	NUM
eurjchem-870	161	42	 	 	SPACE
eurjchem-870	161	43	ml	ml	NOUN
eurjchem-870	161	44	)	)	PUNCT
eurjchem-870	161	45	,	,	PUNCT
eurjchem-870	161	46	and	and	CCONJ
eurjchem-870	161	47	dmf	dmf	PROPN
eurjchem-870	161	48	(	(	PUNCT
eurjchem-870	161	49	5	5	NUM
eurjchem-870	161	50	 	 	SPACE
eurjchem-870	161	51	ml	ml	NOUN
eurjchem-870	161	52	)	)	PUNCT
eurjchem-870	161	53	was	be	AUX
eurjchem-870	161	54	heated	heat	VERB
eurjchem-870	161	55	on	on	ADP
eurjchem-870	161	56	water	water	NOUN
eurjchem-870	161	57	bath	bath	NOUN
eurjchem-870	161	58	for	for	ADP
eurjchem-870	161	59	4	4	NUM
eurjchem-870	161	60	 	 	SPACE
eurjchem-870	161	61	h	h	NOUN
eurjchem-870	161	62	,	,	PUNCT
eurjchem-870	161	63	the	the	DET
eurjchem-870	161	64	solid	solid	ADJ
eurjchem-870	161	65	that	that	PRON
eurjchem-870	161	66	separated	separate	VERB
eurjchem-870	161	67	after	after	ADP
eurjchem-870	161	68	cooling	cool	VERB
eurjchem-870	161	69	and	and	CCONJ
eurjchem-870	161	70	evaporating	evaporate	VERB
eurjchem-870	161	71	the	the	DET
eurjchem-870	161	72	solvent	solvent	NOUN
eurjchem-870	161	73	was	be	AUX
eurjchem-870	161	74	filtered	filter	VERB
eurjchem-870	161	75	off	off	ADP
eurjchem-870	161	76	,	,	PUNCT
eurjchem-870	161	77	washed	wash	VERB
eurjchem-870	161	78	with	with	ADP
eurjchem-870	161	79	water	water	NOUN
eurjchem-870	161	80	(	(	PUNCT
eurjchem-870	161	81	30	30	NUM
eurjchem-870	161	82	 	 	SPACE
eurjchem-870	161	83	ml	ml	NOUN
eurjchem-870	161	84	)	)	PUNCT
eurjchem-870	161	85	,	,	PUNCT
eurjchem-870	161	86	dried	dry	VERB
eurjchem-870	161	87	and	and	CCONJ
eurjchem-870	161	88	crystallized	crystallize	VERB
eurjchem-870	161	89	from	from	ADP
eurjchem-870	161	90	benzene	benzene	NOUN
eurjchem-870	161	91	:	:	PUNCT
eurjchem-870	162	1	ethanol	ethanol	NOUN
eurjchem-870	162	2	(	(	PUNCT
eurjchem-870	162	3	3:1	3:1	NUM
eurjchem-870	162	4	)	)	PUNCT
eurjchem-870	162	5	(	(	PUNCT
eurjchem-870	162	6	scheme	scheme	NOUN
eurjchem-870	162	7	2	2	NUM
eurjchem-870	162	8	)	)	PUNCT
eurjchem-870	162	9	.	.	PUNCT
eurjchem-870	163	1	color	color	NOUN
eurjchem-870	163	2	:	:	PUNCT
eurjchem-870	163	3	green	green	ADJ
eurjchem-870	163	4	.	.	PUNCT
eurjchem-870	164	1	yield	yield	NOUN
eurjchem-870	164	2	:	:	PUNCT
eurjchem-870	164	3	95	95	NUM
eurjchem-870	164	4	%	%	NOUN
eurjchem-870	164	5	.	.	PUNCT
eurjchem-870	165	1	m.p	m.p	PROPN
eurjchem-870	165	2	.	.	PROPN
eurjchem-870	165	3	:	:	PUNCT
eurjchem-870	166	1	190‐192	190‐192	NUM
eurjchem-870	166	2	°	°	ADP
eurjchem-870	166	3	c	c	X
eurjchem-870	166	4	.	.	PUNCT
eurjchem-870	167	1	ft‐ir	ft‐ir	NOUN
eurjchem-870	167	2	(	(	PUNCT
eurjchem-870	167	3	kbr	kbr	PROPN
eurjchem-870	167	4	,	,	PUNCT
eurjchem-870	167	5			PROPN
eurjchem-870	167	6	,	,	PUNCT
eurjchem-870	167	7	cm‐1	cm‐1	PROPN
eurjchem-870	167	8	):	):	PUNCT
eurjchem-870	167	9	3380	3380	NUM
eurjchem-870	167	10	(	(	PUNCT
eurjchem-870	167	11	oh	oh	INTJ
eurjchem-870	167	12	)	)	PUNCT
eurjchem-870	167	13	,	,	PUNCT
eurjchem-870	167	14	3066	3066	NUM
eurjchem-870	167	15	(	(	PUNCT
eurjchem-870	167	16	ch	ch	NOUN
eurjchem-870	167	17	aromatic	aromatic	NOUN
eurjchem-870	167	18	)	)	PUNCT
eurjchem-870	167	19	,	,	PUNCT
eurjchem-870	167	20	2930	2930	NUM
eurjchem-870	167	21	(	(	PUNCT
eurjchem-870	167	22	ch	ch	NOUN
eurjchem-870	167	23	aliphatic	aliphatic	PROPN
eurjchem-870	167	24	)	)	PUNCT
eurjchem-870	167	25	,	,	PUNCT
eurjchem-870	167	26	1696	1696	NUM
eurjchem-870	167	27	(	(	PUNCT
eurjchem-870	167	28	c	c	NOUN
eurjchem-870	167	29	=	=	NOUN
eurjchem-870	167	30	o	o	NOUN
eurjchem-870	167	31	)	)	PUNCT
eurjchem-870	167	32	.	.	PUNCT
eurjchem-870	168	1	1h	1h	NUM
eurjchem-870	168	2	nmr	nmr	NOUN
eurjchem-870	168	3	(	(	PUNCT
eurjchem-870	168	4	300	300	NUM
eurjchem-870	168	5	mhz	mhz	NOUN
eurjchem-870	168	6	,	,	PUNCT
eurjchem-870	168	7	dmso	dmso	NOUN
eurjchem-870	168	8	,	,	PUNCT
eurjchem-870	168	9	δ	δ	PROPN
eurjchem-870	168	10	,	,	PUNCT
eurjchem-870	168	11	ppm	ppm	NOUN
eurjchem-870	168	12	):	):	PUNCT
eurjchem-870	168	13	7.77‐7.93	7.77‐7.93	NUM
eurjchem-870	168	14	(	(	PUNCT
eurjchem-870	168	15	m	m	PROPN
eurjchem-870	168	16	,	,	PUNCT
eurjchem-870	168	17	4h	4h	NUM
eurjchem-870	168	18	,	,	PUNCT
eurjchem-870	168	19	arh	arh	PROPN
eurjchem-870	168	20	)	)	PUNCT
eurjchem-870	168	21	,	,	PUNCT
eurjchem-870	168	22	7.49‐7.62	7.49‐7.62	NUM
eurjchem-870	168	23	(	(	PUNCT
eurjchem-870	168	24	m	m	PROPN
eurjchem-870	168	25	,	,	PUNCT
eurjchem-870	168	26	5h	5h	NUM
eurjchem-870	168	27	,	,	PUNCT
eurjchem-870	168	28	5arh	5arh	NUM
eurjchem-870	168	29	)	)	PUNCT
eurjchem-870	168	30	,	,	PUNCT
eurjchem-870	168	31	7.30‐7.37	7.30‐7.37	NUM
eurjchem-870	168	32	(	(	PUNCT
eurjchem-870	168	33	m	m	PROPN
eurjchem-870	168	34	,	,	PUNCT
eurjchem-870	168	35	2h	2h	NUM
eurjchem-870	168	36	,	,	PUNCT
eurjchem-870	168	37	1arh,=ch	1arh,=ch	PROPN
eurjchem-870	168	38	)	)	PUNCT
eurjchem-870	168	39	,	,	PUNCT
eurjchem-870	168	40	4.60	4.60	NUM
eurjchem-870	168	41	,	,	PUNCT
eurjchem-870	168	42	4.92	4.92	NUM
eurjchem-870	168	43	,	,	PUNCT
eurjchem-870	168	44	5.96	5.96	NUM
eurjchem-870	168	45	,	,	PUNCT
eurjchem-870	168	46	6.07	6.07	NUM
eurjchem-870	168	47	(	(	PUNCT
eurjchem-870	168	48	s	s	PROPN
eurjchem-870	168	49	,	,	PUNCT
eurjchem-870	168	50	5h	5h	NUM
eurjchem-870	168	51	,	,	PUNCT
eurjchem-870	168	52	5oh	5oh	ADJ
eurjchem-870	168	53	,	,	PUNCT
eurjchem-870	168	54	d2o	d2o	NOUN
eurjchem-870	168	55	exchangeable	exchangeable	ADJ
eurjchem-870	168	56	)	)	PUNCT
eurjchem-870	168	57	,	,	PUNCT
eurjchem-870	168	58	4.03‐4.16	4.03‐4.16	PROPN
eurjchem-870	168	59	(	(	PUNCT
eurjchem-870	168	60	m	m	PROPN
eurjchem-870	168	61	,	,	PUNCT
eurjchem-870	168	62	1h	1h	NUM
eurjchem-870	168	63	,	,	PUNCT
eurjchem-870	168	64	=	=	NOUN
eurjchem-870	168	65	chchoh	chchoh	NOUN
eurjchem-870	168	66	)	)	PUNCT
eurjchem-870	168	67	,	,	PUNCT
eurjchem-870	168	68	3.77‐3.86	3.77‐3.86	NUM
eurjchem-870	168	69	(	(	PUNCT
eurjchem-870	168	70	m	m	PROPN
eurjchem-870	168	71	,	,	PUNCT
eurjchem-870	168	72	2h	2h	NUM
eurjchem-870	168	73	,	,	PUNCT
eurjchem-870	168	74	ch2oh	ch2oh	NOUN
eurjchem-870	168	75	)	)	PUNCT
eurjchem-870	168	76	,	,	PUNCT
eurjchem-870	168	77	3.61‐3.67	3.61‐3.67	NUM
eurjchem-870	168	78	(	(	PUNCT
eurjchem-870	168	79	m	m	PROPN
eurjchem-870	168	80	,	,	PUNCT
eurjchem-870	168	81	3h	3h	NUM
eurjchem-870	168	82	,	,	PUNCT
eurjchem-870	168	83	glucose	glucose	NOUN
eurjchem-870	168	84	moiety	moiety	NOUN
eurjchem-870	168	85	)	)	PUNCT
eurjchem-870	168	86	.	.	PUNCT
eurjchem-870	169	1	ms	ms	NOUN
eurjchem-870	169	2	(	(	PUNCT
eurjchem-870	169	3	ei	ei	PROPN
eurjchem-870	169	4	,	,	PUNCT
eurjchem-870	169	5	m	m	PROPN
eurjchem-870	169	6	/	/	SYM
eurjchem-870	169	7	z	z	PROPN
eurjchem-870	169	8	(	(	PUNCT
eurjchem-870	169	9	%	%	NOUN
eurjchem-870	169	10	)	)	PUNCT
eurjchem-870	169	11	):	):	PUNCT
eurjchem-870	169	12	398	398	NUM
eurjchem-870	169	13	(	(	PUNCT
eurjchem-870	169	14	0.06	0.06	NUM
eurjchem-870	169	15	,	,	PUNCT
eurjchem-870	169	16	m+	m+	NOUN
eurjchem-870	169	17	·	·	PUNCT
eurjchem-870	169	18	)	)	PUNCT
eurjchem-870	169	19	,	,	PUNCT
eurjchem-870	169	20	24.7	24.7	NUM
eurjchem-870	169	21	(	(	PUNCT
eurjchem-870	169	22	20.12	20.12	NUM
eurjchem-870	169	23	)	)	PUNCT
eurjchem-870	169	24	,	,	PUNCT
eurjchem-870	169	25	236	236	NUM
eurjchem-870	169	26	(	(	PUNCT
eurjchem-870	169	27	13.36	13.36	NUM
eurjchem-870	169	28	)	)	PUNCT
eurjchem-870	169	29	,	,	PUNCT
eurjchem-870	169	30	91	91	NUM
eurjchem-870	169	31	(	(	PUNCT
eurjchem-870	169	32	100	100	NUM
eurjchem-870	169	33	)	)	PUNCT
eurjchem-870	169	34	,	,	PUNCT
eurjchem-870	169	35	92	92	NUM
eurjchem-870	169	36	(	(	PUNCT
eurjchem-870	169	37	16.16	16.16	NUM
eurjchem-870	169	38	)	)	PUNCT
eurjchem-870	169	39	,	,	PUNCT
eurjchem-870	169	40	76	76	NUM
eurjchem-870	169	41	(	(	PUNCT
eurjchem-870	169	42	14.01	14.01	NUM
eurjchem-870	169	43	)	)	PUNCT
eurjchem-870	169	44	.	.	PUNCT
eurjchem-870	170	1	anal	anal	PROPN
eurjchem-870	170	2	.	.	PUNCT
eurjchem-870	170	3	calcd	calcd	NOUN
eurjchem-870	170	4	.	.	PUNCT
eurjchem-870	171	1	for	for	ADP
eurjchem-870	171	2	c21h22n2o6	c21h22n2o6	PROPN
eurjchem-870	171	3	:	:	PUNCT
eurjchem-870	171	4	c	c	X
eurjchem-870	171	5	,	,	PUNCT
eurjchem-870	171	6	63.31	63.31	NUM
eurjchem-870	171	7	;	;	PUNCT
eurjchem-870	171	8	h	h	NOUN
eurjchem-870	171	9	,	,	PUNCT
eurjchem-870	171	10	5.57	5.57	NUM
eurjchem-870	171	11	;	;	PUNCT
eurjchem-870	171	12	n	n	CCONJ
eurjchem-870	171	13	,	,	PUNCT
eurjchem-870	171	14	7.03	7.03	NUM
eurjchem-870	171	15	.	.	PUNCT
eurjchem-870	171	16	found	find	VERB
eurjchem-870	171	17	:	:	PUNCT
eurjchem-870	172	1	c	c	X
eurjchem-870	172	2	,	,	PUNCT
eurjchem-870	172	3	63.50	63.50	NUM
eurjchem-870	172	4	;	;	PUNCT
eurjchem-870	172	5	h	h	NOUN
eurjchem-870	172	6	,	,	PUNCT
eurjchem-870	172	7	5.77	5.77	NUM
eurjchem-870	172	8	;	;	PUNCT
eurjchem-870	172	9	n	n	CCONJ
eurjchem-870	172	10	,	,	PUNCT
eurjchem-870	172	11	7.15	7.15	NUM
eurjchem-870	172	12	%	%	NOUN
eurjchem-870	172	13	.	.	PUNCT
eurjchem-870	173	1	2.2.11	2.2.11	NUM
eurjchem-870	173	2	.	.	PUNCT
eurjchem-870	174	1	5‐oxo‐n,1,3‐triphenyl‐4,5‐dihydro‐1h‐	5‐oxo‐n,1,3‐triphenyl‐4,5‐dihydro‐1h‐	NUM
eurjchem-870	174	2	pyrazole‐4‐carbothioamide	pyrazole‐4‐carbothioamide	NOUN
eurjchem-870	174	3	(	(	PUNCT
eurjchem-870	174	4	15	15	NUM
eurjchem-870	174	5	)	)	PUNCT
eurjchem-870	174	6	a	a	DET
eurjchem-870	174	7	mixture	mixture	NOUN
eurjchem-870	174	8	of	of	ADP
eurjchem-870	174	9	pyrazolone	pyrazolone	NOUN
eurjchem-870	174	10	3	3	NUM
eurjchem-870	174	11	(	(	PUNCT
eurjchem-870	174	12	2.36	2.36	NUM
eurjchem-870	174	13	 	 	SPACE
eurjchem-870	174	14	g	g	NOUN
eurjchem-870	174	15	,	,	PUNCT
eurjchem-870	174	16	0.01	0.01	NUM
eurjchem-870	174	17	 	 	SPACE
eurjchem-870	174	18	mol	mol	NOUN
eurjchem-870	174	19	)	)	PUNCT
eurjchem-870	174	20	and	and	CCONJ
eurjchem-870	174	21	phenyl	phenyl	NOUN
eurjchem-870	174	22	isothiocyanate	isothiocyanate	NOUN
eurjchem-870	174	23	(	(	PUNCT
eurjchem-870	174	24	0.6	0.6	NUM
eurjchem-870	174	25	 	 	SPACE
eurjchem-870	174	26	ml	ml	NOUN
eurjchem-870	174	27	,	,	PUNCT
eurjchem-870	174	28	0.01	0.01	NUM
eurjchem-870	174	29	 	 	SPACE
eurjchem-870	174	30	mol	mol	NOUN
eurjchem-870	174	31	)	)	PUNCT
eurjchem-870	174	32	in	in	ADP
eurjchem-870	174	33	dry	dry	ADJ
eurjchem-870	174	34	acetone	acetone	NOUN
eurjchem-870	174	35	(	(	PUNCT
eurjchem-870	174	36	50	50	NUM
eurjchem-870	174	37	 	 	SPACE
eurjchem-870	174	38	ml	ml	NOUN
eurjchem-870	174	39	)	)	PUNCT
eurjchem-870	174	40	in	in	ADP
eurjchem-870	174	41	the	the	DET
eurjchem-870	174	42	presence	presence	NOUN
eurjchem-870	174	43	of	of	ADP
eurjchem-870	174	44	piperidine	piperidine	NOUN
eurjchem-870	174	45	(	(	PUNCT
eurjchem-870	174	46	0.5	0.5	NUM
eurjchem-870	174	47	 	 	SPACE
eurjchem-870	174	48	ml	ml	NOUN
eurjchem-870	174	49	)	)	PUNCT
eurjchem-870	174	50	was	be	AUX
eurjchem-870	174	51	heated	heat	VERB
eurjchem-870	174	52	on	on	ADP
eurjchem-870	174	53	water	water	NOUN
eurjchem-870	174	54	bath	bath	NOUN
eurjchem-870	174	55	for	for	ADP
eurjchem-870	174	56	4	4	NUM
eurjchem-870	174	57	 	 	SPACE
eurjchem-870	174	58	h.	h.	NOUN
eurjchem-870	174	59	the	the	PRON
eurjchem-870	174	60	separated	separate	VERB
eurjchem-870	174	61	solid	solid	ADJ
eurjchem-870	174	62	after	after	ADP
eurjchem-870	174	63	pouring	pour	VERB
eurjchem-870	174	64	onto	onto	ADP
eurjchem-870	174	65	ic	ic	PRON
eurjchem-870	174	66	:	:	PUNCT
eurjchem-870	174	67	ehcl	ehcl	PROPN
eurjchem-870	174	68	(	(	PUNCT
eurjchem-870	174	69	1:2	1:2	NUM
eurjchem-870	174	70	)	)	PUNCT
eurjchem-870	174	71	was	be	AUX
eurjchem-870	174	72	filtered	filter	VERB
eurjchem-870	174	73	off	off	ADP
eurjchem-870	174	74	,	,	PUNCT
eurjchem-870	174	75	washed	wash	VERB
eurjchem-870	174	76	with	with	ADP
eurjchem-870	174	77	water	water	NOUN
eurjchem-870	174	78	,	,	PUNCT
eurjchem-870	174	79	dried	dry	VERB
eurjchem-870	174	80	and	and	CCONJ
eurjchem-870	174	81	crystallized	crystallize	VERB
eurjchem-870	174	82	from	from	ADP
eurjchem-870	174	83	ethanol	ethanol	NOUN
eurjchem-870	174	84	(	(	PUNCT
eurjchem-870	174	85	scheme	scheme	NOUN
eurjchem-870	174	86	2	2	NUM
eurjchem-870	174	87	)	)	PUNCT
eurjchem-870	174	88	.	.	PUNCT
eurjchem-870	175	1	color	color	NOUN
eurjchem-870	175	2	:	:	PUNCT
eurjchem-870	175	3	yellow	yellow	ADJ
eurjchem-870	175	4	.	.	PUNCT
eurjchem-870	176	1	yield	yield	NOUN
eurjchem-870	176	2	:	:	PUNCT
eurjchem-870	176	3	25.3	25.3	NUM
eurjchem-870	176	4	%	%	NOUN
eurjchem-870	176	5	.	.	PUNCT
eurjchem-870	177	1	m.p	m.p	PROPN
eurjchem-870	177	2	.	.	PROPN
eurjchem-870	177	3	:	:	PUNCT
eurjchem-870	178	1	180‐182	180‐182	NUM
eurjchem-870	178	2	°	°	PROPN
eurjchem-870	178	3	c	c	X
eurjchem-870	178	4	.	.	PUNCT
eurjchem-870	179	1	ft‐ir	ft‐ir	NOUN
eurjchem-870	179	2	(	(	PUNCT
eurjchem-870	179	3	kbr	kbr	PROPN
eurjchem-870	179	4	,	,	PUNCT
eurjchem-870	179	5			PROPN
eurjchem-870	179	6	,	,	PUNCT
eurjchem-870	179	7	cm‐1	cm‐1	PROPN
eurjchem-870	179	8	):	):	PUNCT
eurjchem-870	179	9	3063	3063	NUM
eurjchem-870	179	10	(	(	PUNCT
eurjchem-870	179	11	nh	nh	NOUN
eurjchem-870	179	12	)	)	PUNCT
eurjchem-870	179	13	,	,	PUNCT
eurjchem-870	179	14	3034	3034	NUM
eurjchem-870	179	15	(	(	PUNCT
eurjchem-870	179	16	ch	ch	NOUN
eurjchem-870	179	17	aromatic	aromatic	NOUN
eurjchem-870	179	18	)	)	PUNCT
eurjchem-870	179	19	,	,	PUNCT
eurjchem-870	179	20	2912	2912	NUM
eurjchem-870	179	21	(	(	PUNCT
eurjchem-870	179	22	ch	ch	NOUN
eurjchem-870	179	23	aliphatic	aliphatic	PROPN
eurjchem-870	179	24	)	)	PUNCT
eurjchem-870	179	25	,	,	PUNCT
eurjchem-870	179	26	1711	1711	NUM
eurjchem-870	179	27	(	(	PUNCT
eurjchem-870	179	28	c	c	NOUN
eurjchem-870	179	29	=	=	NOUN
eurjchem-870	179	30	o	o	NOUN
eurjchem-870	179	31	)	)	PUNCT
eurjchem-870	179	32	.	.	PUNCT
eurjchem-870	180	1	1h	1h	NUM
eurjchem-870	180	2	nmr	nmr	NOUN
eurjchem-870	180	3	(	(	PUNCT
eurjchem-870	180	4	300	300	NUM
eurjchem-870	180	5	mhz	mhz	NOUN
eurjchem-870	180	6	,	,	PUNCT
eurjchem-870	180	7	cdcl3	cdcl3	PROPN
eurjchem-870	180	8	,	,	PUNCT
eurjchem-870	180	9	δ	δ	PROPN
eurjchem-870	180	10	,	,	PUNCT
eurjchem-870	180	11	ppm	ppm	NUM
eurjchem-870	180	12	):	):	PUNCT
eurjchem-870	180	13	8.64	8.64	NUM
eurjchem-870	180	14	(	(	PUNCT
eurjchem-870	180	15	s	s	PROPN
eurjchem-870	180	16	,	,	PUNCT
eurjchem-870	180	17	1h	1h	NUM
eurjchem-870	180	18	,	,	PUNCT
eurjchem-870	180	19	oh	oh	INTJ
eurjchem-870	180	20	,	,	PUNCT
eurjchem-870	180	21	d2o	d2o	NOUN
eurjchem-870	180	22	exchangeable	exchangeable	ADJ
eurjchem-870	180	23	)	)	PUNCT
eurjchem-870	180	24	,	,	PUNCT
eurjchem-870	180	25	6.91‐8.08	6.91‐8.08	NUM
eurjchem-870	180	26	(	(	PUNCT
eurjchem-870	180	27	m	m	PROPN
eurjchem-870	180	28	,	,	PUNCT
eurjchem-870	180	29	15h	15h	NUM
eurjchem-870	180	30	,	,	PUNCT
eurjchem-870	180	31	arh	arh	PROPN
eurjchem-870	180	32	)	)	PUNCT
eurjchem-870	180	33	,	,	PUNCT
eurjchem-870	180	34	1.60	1.60	NUM
eurjchem-870	180	35	(	(	PUNCT
eurjchem-870	180	36	s	s	PROPN
eurjchem-870	180	37	,	,	PUNCT
eurjchem-870	180	38	1h	1h	NUM
eurjchem-870	180	39	,	,	PUNCT
eurjchem-870	180	40	nh	nh	PROPN
eurjchem-870	180	41	,	,	PUNCT
eurjchem-870	180	42	d2o	d2o	PROPN
eurjchem-870	180	43	exchangeable	exchangeable	ADJ
eurjchem-870	180	44	)	)	PUNCT
eurjchem-870	180	45	.	.	PUNCT
eurjchem-870	181	1	ms	ms	NOUN
eurjchem-870	181	2	(	(	PUNCT
eurjchem-870	181	3	ei	ei	PROPN
eurjchem-870	181	4	,	,	PUNCT
eurjchem-870	181	5	m	m	PROPN
eurjchem-870	181	6	/	/	SYM
eurjchem-870	181	7	z	z	PROPN
eurjchem-870	181	8	(	(	PUNCT
eurjchem-870	181	9	%	%	NOUN
eurjchem-870	181	10	)	)	PUNCT
eurjchem-870	181	11	):	):	PUNCT
eurjchem-870	181	12	373	373	NUM
eurjchem-870	181	13	(	(	PUNCT
eurjchem-870	181	14	3.33	3.33	NUM
eurjchem-870	181	15	,	,	PUNCT
eurjchem-870	181	16	m+2	m+2	NOUN
eurjchem-870	181	17	)	)	PUNCT
eurjchem-870	181	18	,	,	PUNCT
eurjchem-870	181	19	371	371	NUM
eurjchem-870	181	20	(	(	PUNCT
eurjchem-870	181	21	40.86	40.86	NUM
eurjchem-870	181	22	,	,	PUNCT
eurjchem-870	181	23	m+	m+	NUM
eurjchem-870	181	24	.	.	PUNCT
eurjchem-870	181	25	)	)	PUNCT
eurjchem-870	181	26	,	,	PUNCT
eurjchem-870	181	27	279	279	NUM
eurjchem-870	181	28	(	(	PUNCT
eurjchem-870	181	29	22.20	22.20	NUM
eurjchem-870	181	30	)	)	PUNCT
eurjchem-870	181	31	,	,	PUNCT
eurjchem-870	181	32	278	278	NUM
eurjchem-870	181	33	(	(	PUNCT
eurjchem-870	181	34	100	100	NUM
eurjchem-870	181	35	)	)	PUNCT
eurjchem-870	181	36	,	,	PUNCT
eurjchem-870	181	37	93	93	NUM
eurjchem-870	181	38	(	(	PUNCT
eurjchem-870	181	39	21.48	21.48	NUM
eurjchem-870	181	40	)	)	PUNCT
eurjchem-870	181	41	,	,	PUNCT
eurjchem-870	181	42	77	77	NUM
eurjchem-870	181	43	(	(	PUNCT
eurjchem-870	181	44	56.96	56.96	NUM
eurjchem-870	181	45	)	)	PUNCT
eurjchem-870	181	46	.	.	PUNCT
eurjchem-870	182	1	anal	anal	PROPN
eurjchem-870	182	2	.	.	PUNCT
eurjchem-870	182	3	calcd	calcd	NOUN
eurjchem-870	182	4	.	.	PUNCT
eurjchem-870	183	1	for	for	ADP
eurjchem-870	183	2	c22h17n3os	c22h17n3os	PROPN
eurjchem-870	183	3	:	:	PUNCT
eurjchem-870	183	4	c	c	X
eurjchem-870	183	5	,	,	PUNCT
eurjchem-870	183	6	71.14	71.14	NUM
eurjchem-870	183	7	;	;	PUNCT
eurjchem-870	183	8	h	h	NOUN
eurjchem-870	183	9	,	,	PUNCT
eurjchem-870	183	10	4.61	4.61	NUM
eurjchem-870	183	11	;	;	PUNCT
eurjchem-870	183	12	n	n	CCONJ
eurjchem-870	183	13	,	,	PUNCT
eurjchem-870	183	14	11.31	11.31	NUM
eurjchem-870	183	15	;	;	PUNCT
eurjchem-870	183	16	s	s	X
eurjchem-870	183	17	,	,	PUNCT
eurjchem-870	183	18	8.63	8.63	NUM
eurjchem-870	183	19	.	.	PUNCT
eurjchem-870	183	20	found	find	VERB
eurjchem-870	183	21	:	:	PUNCT
eurjchem-870	184	1	c	c	X
eurjchem-870	184	2	,	,	PUNCT
eurjchem-870	184	3	70.83	70.83	NUM
eurjchem-870	184	4	;	;	PUNCT
eurjchem-870	184	5	h	h	NOUN
eurjchem-870	184	6	,	,	PUNCT
eurjchem-870	184	7	5.32	5.32	NUM
eurjchem-870	184	8	;	;	PUNCT
eurjchem-870	184	9	n	n	CCONJ
eurjchem-870	184	10	,	,	PUNCT
eurjchem-870	184	11	11.32	11.32	NUM
eurjchem-870	184	12	;	;	PUNCT
eurjchem-870	184	13	s	s	VERB
eurjchem-870	184	14	8.71	8.71	NUM
eurjchem-870	184	15	%	%	NOUN
eurjchem-870	184	16	.	.	PUNCT
eurjchem-870	185	1	marzouk	marzouk	INTJ
eurjchem-870	185	2	et	et	PROPN
eurjchem-870	185	3	al	al	PROPN
eurjchem-870	185	4	.	.	PUNCT
eurjchem-870	185	5	/	/	SYM
eurjchem-870	185	6	european	european	PROPN
eurjchem-870	185	7	journal	journal	PROPN
eurjchem-870	185	8	of	of	ADP
eurjchem-870	185	9	chemistry	chemistry	NOUN
eurjchem-870	185	10	5	5	NUM
eurjchem-870	185	11	(	(	PUNCT
eurjchem-870	185	12	1	1	NUM
eurjchem-870	185	13	)	)	PUNCT
eurjchem-870	185	14	(	(	PUNCT
eurjchem-870	185	15	2014	2014	NUM
eurjchem-870	185	16	)	)	PUNCT
eurjchem-870	185	17	24‐32	24‐32	NUM
eurjchem-870	186	1	27	27	NUM
eurjchem-870	186	2	n	n	CCONJ
eurjchem-870	186	3	n	n	PRON
eurjchem-870	186	4	ph	ph	ADJ
eurjchem-870	186	5	ph	ph	NOUN
eurjchem-870	186	6	o	o	NOUN
eurjchem-870	186	7	(	(	PUNCT
eurjchem-870	186	8	choh)4ch2oh	choh)4ch2oh	NOUN
eurjchem-870	186	9	13	13	NUM
eurjchem-870	186	10	n	n	CCONJ
eurjchem-870	186	11	n	n	ADV
eurjchem-870	186	12	ph	ph	ADJ
eurjchem-870	186	13	ph	ph	NOUN
eurjchem-870	186	14	o	o	NOUN
eurjchem-870	186	15	3	3	NUM
eurjchem-870	186	16	n	n	ADP
eurjchem-870	186	17	n	n	PRON
eurjchem-870	186	18	ph	ph	NOUN
eurjchem-870	186	19	s	s	PART
eurjchem-870	186	20	ph	ph	NOUN
eurjchem-870	186	21	o	o	NOUN
eurjchem-870	186	22	nhph	nhph	NOUN
eurjchem-870	186	23	n	n	CCONJ
eurjchem-870	186	24	n	n	PRON
eurjchem-870	186	25	ph	ph	NOUN
eurjchem-870	186	26	s	s	PART
eurjchem-870	186	27	ph	ph	NOUN
eurjchem-870	186	28	o	o	PROPN
eurjchem-870	186	29	nhph	nhph	PROPN
eurjchem-870	186	30	b	b	PROPN
eurjchem-870	186	31	hcl	hcl	PROPN
eurjchem-870	186	32	15	15	NUM
eurjchem-870	186	33	14	14	NUM
eurjchem-870	186	34	phncs	phnc	NOUN
eurjchem-870	186	35	n2h4	n2h4	ADP
eurjchem-870	186	36	n	n	CCONJ
eurjchem-870	186	37	n	n	CCONJ
eurjchem-870	186	38	n	n	NOUN
eurjchem-870	186	39	h	h	NOUN
eurjchem-870	186	40	n	n	CCONJ
eurjchem-870	186	41	ph	ph	ADJ
eurjchem-870	186	42	ph	ph	NOUN
eurjchem-870	186	43	ph	ph	NOUN
eurjchem-870	186	44	s	s	PART
eurjchem-870	186	45	16	16	NUM
eurjchem-870	186	46	n	n	CCONJ
eurjchem-870	186	47	n	n	ADV
eurjchem-870	186	48	ph	ph	ADJ
eurjchem-870	186	49	ph	ph	NOUN
eurjchem-870	186	50	o	o	NOUN
eurjchem-870	186	51	n	n	ADP
eurjchem-870	186	52	s	s	PROPN
eurjchem-870	186	53	n	n	CCONJ
eurjchem-870	186	54	n	n	NUM
eurjchem-870	186	55	17	17	NUM
eurjchem-870	186	56	n	n	CCONJ
eurjchem-870	186	57	n	n	CCONJ
eurjchem-870	186	58	ph	ph	ADJ
eurjchem-870	186	59	ph	ph	NOUN
eurjchem-870	186	60	o	o	NOUN
eurjchem-870	186	61	phn	phn	NOUN
eurjchem-870	186	62	n	n	NOUN
eurjchem-870	186	63	glucose	glucose	NOUN
eurjchem-870	186	64	/	/	SYM
eurjchem-870	186	65	dmf	dmf	PROPN
eurjchem-870	186	66	etoh	etoh	X
eurjchem-870	186	67	/	/	SYM
eurjchem-870	186	68	acoh	acoh	ADJ
eurjchem-870	186	69	acetone	acetone	NOUN
eurjchem-870	186	70	/	/	SYM
eurjchem-870	186	71	piperidine	piperidine	NOUN
eurjchem-870	186	72	nano2	nano2	NOUN
eurjchem-870	186	73	/	/	SYM
eurjchem-870	186	74	hcl	hcl	PROPN
eurjchem-870	186	75	2	2	NUM
eurjchem-870	186	76	-	-	PUNCT
eurjchem-870	186	77	amino	amino	NOUN
eurjchem-870	186	78	thiazole	thiazole	NOUN
eurjchem-870	186	79	nano2	nano2	PROPN
eurjchem-870	186	80	/	/	SYM
eurjchem-870	186	81	hcl	hcl	PROPN
eurjchem-870	186	82	aniline	aniline	PROPN
eurjchem-870	186	83	n	n	CCONJ
eurjchem-870	186	84	n	n	CCONJ
eurjchem-870	186	85	ph	ph	ADJ
eurjchem-870	186	86	ph	ph	NOUN
eurjchem-870	186	87	o	o	PROPN
eurjchem-870	186	88	ar	ar	NOUN
eurjchem-870	186	89	p	p	NOUN
eurjchem-870	186	90	-	-	PUNCT
eurjchem-870	186	91	anisaldehyde	anisaldehyde	NOUN
eurjchem-870	186	92	etoh	etoh	NOUN
eurjchem-870	186	93	/	/	SYM
eurjchem-870	186	94	piperidine	piperidine	NOUN
eurjchem-870	186	95	ar	ar	NOUN
eurjchem-870	186	96	=	=	NOUN
eurjchem-870	186	97	c6h4(4	c6h4(4	PROPN
eurjchem-870	186	98	-	-	PUNCT
eurjchem-870	186	99	och3	och3	ADJ
eurjchem-870	186	100	)	)	PUNCT
eurjchem-870	186	101	19	19	NUM
eurjchem-870	186	102	n	n	NOUN
eurjchem-870	186	103	n	n	CCONJ
eurjchem-870	186	104	ph	ph	NOUN
eurjchem-870	186	105	ph	ph	NOUN
eurjchem-870	187	1	oh	oh	INTJ
eurjchem-870	187	2	phn	phn	INTJ
eurjchem-870	187	3	n	n	NUM
eurjchem-870	187	4	18	18	NUM
eurjchem-870	187	5	n	n	CCONJ
eurjchem-870	187	6	n	n	PRON
eurjchem-870	187	7	ph	ph	NOUN
eurjchem-870	187	8	s	s	PART
eurjchem-870	188	1	ph	ph	ADJ
eurjchem-870	188	2	oh	oh	INTJ
eurjchem-870	188	3	nhph	nhph	ADJ
eurjchem-870	188	4	scheme	scheme	NOUN
eurjchem-870	188	5	2	2	NUM
eurjchem-870	188	6	2.2.12	2.2.12	NUM
eurjchem-870	188	7	.	.	PUNCT
eurjchem-870	189	1	2,4,6‐triphenyl‐1,2‐dihydropyrazolo[3,4‐c]pyrazole‐	2,4,6‐triphenyl‐1,2‐dihydropyrazolo[3,4‐c]pyrazole‐	NUM
eurjchem-870	189	2	3‐(6h)‐thione	3‐(6h)‐thione	NUM
eurjchem-870	189	3	(	(	PUNCT
eurjchem-870	189	4	16	16	NUM
eurjchem-870	189	5	)	)	PUNCT
eurjchem-870	189	6	a	a	DET
eurjchem-870	189	7	mixture	mixture	NOUN
eurjchem-870	189	8	of	of	ADP
eurjchem-870	189	9	pyrazolidine‐4‐carbothioamide	pyrazolidine‐4‐carbothioamide	PROPN
eurjchem-870	189	10	15	15	NUM
eurjchem-870	189	11	(	(	PUNCT
eurjchem-870	189	12	3.71	3.71	NUM
eurjchem-870	189	13	 	 	SPACE
eurjchem-870	189	14	g	g	NOUN
eurjchem-870	189	15	,	,	PUNCT
eurjchem-870	189	16	0.01	0.01	NUM
eurjchem-870	189	17	 	 	SPACE
eurjchem-870	189	18	mol	mol	NOUN
eurjchem-870	189	19	)	)	PUNCT
eurjchem-870	189	20	hydrazine	hydrazine	NOUN
eurjchem-870	189	21	hydrate	hydrate	NOUN
eurjchem-870	189	22	(	(	PUNCT
eurjchem-870	189	23	0.5	0.5	NUM
eurjchem-870	189	24	 	 	SPACE
eurjchem-870	189	25	ml	ml	NOUN
eurjchem-870	189	26	,	,	PUNCT
eurjchem-870	189	27	0.01	0.01	NUM
eurjchem-870	189	28	 	 	SPACE
eurjchem-870	189	29	mol	mol	NOUN
eurjchem-870	189	30	)	)	PUNCT
eurjchem-870	189	31	in	in	ADP
eurjchem-870	189	32	absolute	absolute	ADJ
eurjchem-870	189	33	ethanol	ethanol	NOUN
eurjchem-870	189	34	(	(	PUNCT
eurjchem-870	189	35	50	50	NUM
eurjchem-870	189	36	 	 	SPACE
eurjchem-870	189	37	ml	ml	NOUN
eurjchem-870	189	38	)	)	PUNCT
eurjchem-870	189	39	was	be	AUX
eurjchem-870	189	40	refluxed	refluxe	VERB
eurjchem-870	189	41	for	for	ADP
eurjchem-870	189	42	10	10	NUM
eurjchem-870	189	43	 	 	SPACE
eurjchem-870	189	44	h.	h.	NOUN
eurjchem-870	189	45	after	after	ADP
eurjchem-870	189	46	cooling	cool	VERB
eurjchem-870	189	47	the	the	DET
eurjchem-870	189	48	reaction	reaction	NOUN
eurjchem-870	189	49	mixture	mixture	NOUN
eurjchem-870	189	50	was	be	AUX
eurjchem-870	189	51	poured	pour	VERB
eurjchem-870	189	52	onto	onto	ADP
eurjchem-870	189	53	ice	ice	NOUN
eurjchem-870	189	54	:	:	PUNCT
eurjchem-870	189	55	hcl	hcl	PROPN
eurjchem-870	189	56	(	(	PUNCT
eurjchem-870	189	57	1:3	1:3	NUM
eurjchem-870	189	58	)	)	PUNCT
eurjchem-870	189	59	,	,	PUNCT
eurjchem-870	189	60	the	the	DET
eurjchem-870	189	61	separated	separate	VERB
eurjchem-870	189	62	solid	solid	ADJ
eurjchem-870	189	63	was	be	AUX
eurjchem-870	189	64	filtered	filter	VERB
eurjchem-870	189	65	off	off	ADP
eurjchem-870	189	66	,	,	PUNCT
eurjchem-870	189	67	washed	wash	VERB
eurjchem-870	189	68	with	with	ADP
eurjchem-870	189	69	water	water	NOUN
eurjchem-870	189	70	,	,	PUNCT
eurjchem-870	189	71	dried	dry	VERB
eurjchem-870	189	72	and	and	CCONJ
eurjchem-870	189	73	recrystallized	recrystallize	VERB
eurjchem-870	189	74	from	from	ADP
eurjchem-870	189	75	benzene	benzene	NOUN
eurjchem-870	189	76	(	(	PUNCT
eurjchem-870	189	77	scheme	scheme	NOUN
eurjchem-870	189	78	2	2	NUM
eurjchem-870	189	79	)	)	PUNCT
eurjchem-870	189	80	.	.	PUNCT
eurjchem-870	190	1	color	color	NOUN
eurjchem-870	190	2	:	:	PUNCT
eurjchem-870	190	3	white	white	ADJ
eurjchem-870	190	4	.	.	PUNCT
eurjchem-870	191	1	yield	yield	NOUN
eurjchem-870	191	2	:	:	PUNCT
eurjchem-870	191	3	65	65	NUM
eurjchem-870	191	4	%	%	NOUN
eurjchem-870	191	5	.	.	PUNCT
eurjchem-870	192	1	m.p	m.p	PROPN
eurjchem-870	192	2	.	.	PROPN
eurjchem-870	192	3	:	:	PUNCT
eurjchem-870	193	1	235‐237	235‐237	NUM
eurjchem-870	193	2	°	°	SYM
eurjchem-870	193	3	c	c	X
eurjchem-870	193	4	.	.	PUNCT
eurjchem-870	194	1	ft‐ir	ft‐ir	NOUN
eurjchem-870	194	2	(	(	PUNCT
eurjchem-870	194	3	kbr	kbr	PROPN
eurjchem-870	194	4	,	,	PUNCT
eurjchem-870	194	5			PROPN
eurjchem-870	194	6	,	,	PUNCT
eurjchem-870	194	7	cm‐1	cm‐1	PROPN
eurjchem-870	194	8	):	):	PUNCT
eurjchem-870	194	9	3011	3011	NUM
eurjchem-870	194	10	(	(	PUNCT
eurjchem-870	194	11	nh	nh	NOUN
eurjchem-870	194	12	)	)	PUNCT
eurjchem-870	194	13	,	,	PUNCT
eurjchem-870	194	14	1597	1597	NUM
eurjchem-870	194	15	(	(	PUNCT
eurjchem-870	194	16	c	c	NOUN
eurjchem-870	194	17	=	=	SYM
eurjchem-870	194	18	n	n	NUM
eurjchem-870	194	19	)	)	PUNCT
eurjchem-870	194	20	,	,	PUNCT
eurjchem-870	194	21	1454	1454	NUM
eurjchem-870	194	22	(	(	PUNCT
eurjchem-870	194	23	ncs	ncs	NOUN
eurjchem-870	194	24	)	)	PUNCT
eurjchem-870	194	25	.	.	PUNCT
eurjchem-870	195	1	1h	1h	NUM
eurjchem-870	195	2	nmr	nmr	NOUN
eurjchem-870	195	3	(	(	PUNCT
eurjchem-870	195	4	300	300	NUM
eurjchem-870	195	5	mhz	mhz	NOUN
eurjchem-870	195	6	,	,	PUNCT
eurjchem-870	195	7	dmso	dmso	NOUN
eurjchem-870	195	8	,	,	PUNCT
eurjchem-870	195	9	δ	δ	PROPN
eurjchem-870	195	10	,	,	PUNCT
eurjchem-870	195	11	ppm	ppm	NOUN
eurjchem-870	195	12	):	):	PUNCT
eurjchem-870	195	13	7.23‐	7.23‐	NUM
eurjchem-870	195	14	7.91	7.91	NUM
eurjchem-870	195	15	(	(	PUNCT
eurjchem-870	195	16	m	m	PROPN
eurjchem-870	195	17	,	,	PUNCT
eurjchem-870	195	18	16h	16h	NUM
eurjchem-870	195	19	,	,	PUNCT
eurjchem-870	195	20	15arh	15arh	NUM
eurjchem-870	195	21	,	,	PUNCT
eurjchem-870	195	22	nh	nh	PROPN
eurjchem-870	195	23	)	)	PUNCT
eurjchem-870	195	24	.	.	PUNCT
eurjchem-870	196	1	ms	ms	NOUN
eurjchem-870	196	2	(	(	PUNCT
eurjchem-870	196	3	ei	ei	PROPN
eurjchem-870	196	4	,	,	PUNCT
eurjchem-870	196	5	m	m	PROPN
eurjchem-870	196	6	/	/	SYM
eurjchem-870	196	7	z	z	PROPN
eurjchem-870	196	8	(	(	PUNCT
eurjchem-870	196	9	%	%	NOUN
eurjchem-870	196	10	)	)	PUNCT
eurjchem-870	196	11	):	):	PUNCT
eurjchem-870	196	12	368	368	NUM
eurjchem-870	196	13	(	(	PUNCT
eurjchem-870	196	14	8.00	8.00	NUM
eurjchem-870	196	15	,	,	PUNCT
eurjchem-870	196	16	m+	m+	NOUN
eurjchem-870	196	17	·	·	PUNCT
eurjchem-870	196	18	)	)	PUNCT
eurjchem-870	196	19	,	,	PUNCT
eurjchem-870	196	20	260	260	NUM
eurjchem-870	196	21	(	(	PUNCT
eurjchem-870	196	22	100	100	NUM
eurjchem-870	196	23	)	)	PUNCT
eurjchem-870	196	24	,	,	PUNCT
eurjchem-870	196	25	108	108	NUM
eurjchem-870	196	26	(	(	PUNCT
eurjchem-870	196	27	12.0	12.0	NUM
eurjchem-870	196	28	)	)	PUNCT
eurjchem-870	196	29	,	,	PUNCT
eurjchem-870	196	30	97	97	NUM
eurjchem-870	196	31	(	(	PUNCT
eurjchem-870	196	32	26.0	26.0	NUM
eurjchem-870	196	33	)	)	PUNCT
eurjchem-870	196	34	,	,	PUNCT
eurjchem-870	196	35	85	85	NUM
eurjchem-870	196	36	(	(	PUNCT
eurjchem-870	196	37	32.0	32.0	NUM
eurjchem-870	196	38	)	)	PUNCT
eurjchem-870	196	39	,	,	PUNCT
eurjchem-870	196	40	83	83	NUM
eurjchem-870	196	41	(	(	PUNCT
eurjchem-870	196	42	30.0	30.0	NUM
eurjchem-870	196	43	)	)	PUNCT
eurjchem-870	196	44	,	,	PUNCT
eurjchem-870	196	45	68	68	NUM
eurjchem-870	196	46	(	(	PUNCT
eurjchem-870	196	47	24.0	24.0	NUM
eurjchem-870	196	48	)	)	PUNCT
eurjchem-870	196	49	,	,	PUNCT
eurjchem-870	196	50	55	55	NUM
eurjchem-870	196	51	(	(	PUNCT
eurjchem-870	196	52	46.0	46.0	NUM
eurjchem-870	196	53	)	)	PUNCT
eurjchem-870	196	54	.	.	PUNCT
eurjchem-870	197	1	anal	anal	PROPN
eurjchem-870	197	2	.	.	PUNCT
eurjchem-870	197	3	calcd	calcd	NOUN
eurjchem-870	197	4	.	.	PUNCT
eurjchem-870	198	1	for	for	SCONJ
eurjchem-870	198	2	c22h16n4s	c22h16n4s	PROPN
eurjchem-870	198	3	:	:	PUNCT
eurjchem-870	198	4	c	c	X
eurjchem-870	198	5	,	,	PUNCT
eurjchem-870	198	6	71.71	71.71	NUM
eurjchem-870	198	7	;	;	PUNCT
eurjchem-870	198	8	h	h	NOUN
eurjchem-870	198	9	,	,	PUNCT
eurjchem-870	198	10	4.38	4.38	NUM
eurjchem-870	198	11	;	;	PUNCT
eurjchem-870	198	12	n	n	CCONJ
eurjchem-870	198	13	,	,	PUNCT
eurjchem-870	198	14	15.21	15.21	NUM
eurjchem-870	198	15	;	;	PUNCT
eurjchem-870	198	16	s	s	PROPN
eurjchem-870	198	17	,	,	PUNCT
eurjchem-870	198	18	8.70	8.70	NUM
eurjchem-870	198	19	.	.	PUNCT
eurjchem-870	198	20	found	find	VERB
eurjchem-870	198	21	:	:	PUNCT
eurjchem-870	199	1	c	c	X
eurjchem-870	199	2	,	,	PUNCT
eurjchem-870	199	3	71.92	71.92	NUM
eurjchem-870	199	4	;	;	PUNCT
eurjchem-870	199	5	h	h	NOUN
eurjchem-870	199	6	,	,	PUNCT
eurjchem-870	199	7	4.51	4.51	NUM
eurjchem-870	199	8	;	;	PUNCT
eurjchem-870	199	9	n	n	CCONJ
eurjchem-870	199	10	,	,	PUNCT
eurjchem-870	199	11	15.34	15.34	NUM
eurjchem-870	199	12	;	;	PUNCT
eurjchem-870	199	13	s	s	X
eurjchem-870	199	14	,	,	PUNCT
eurjchem-870	199	15	8.90	8.90	NUM
eurjchem-870	199	16	%	%	NOUN
eurjchem-870	199	17	.	.	PUNCT
eurjchem-870	200	1	2.2.13	2.2.13	NUM
eurjchem-870	200	2	.	.	PUNCT
eurjchem-870	201	1	1,3‐diphenyl‐4‐(thiazol‐2‐yldiazenyl)‐1h‐pyrazol‐	1,3‐diphenyl‐4‐(thiazol‐2‐yldiazenyl)‐1h‐pyrazol‐	NUM
eurjchem-870	201	2	5(4h)‐one	5(4h)‐one	NUM
eurjchem-870	201	3	(	(	PUNCT
eurjchem-870	201	4	17	17	NUM
eurjchem-870	201	5	)	)	PUNCT
eurjchem-870	201	6	2‐aminothiazole	2‐aminothiazole	NOUN
eurjchem-870	201	7	(	(	PUNCT
eurjchem-870	201	8	0.1	0.1	NUM
eurjchem-870	201	9	g	g	NOUN
eurjchem-870	201	10	,	,	PUNCT
eurjchem-870	201	11	0.001mol	0.001mol	PROPN
eurjchem-870	201	12	)	)	PUNCT
eurjchem-870	201	13	was	be	AUX
eurjchem-870	201	14	dissolved	dissolve	VERB
eurjchem-870	201	15	in	in	ADP
eurjchem-870	201	16	conc	conc	NOUN
eurjchem-870	201	17	.	.	PUNCT
eurjchem-870	202	1	hcl	hcl	PROPN
eurjchem-870	202	2	(	(	PUNCT
eurjchem-870	202	3	5	5	NUM
eurjchem-870	202	4	ml	ml	NOUN
eurjchem-870	202	5	)	)	PUNCT
eurjchem-870	202	6	and	and	CCONJ
eurjchem-870	202	7	the	the	DET
eurjchem-870	202	8	solution	solution	NOUN
eurjchem-870	202	9	was	be	AUX
eurjchem-870	202	10	then	then	ADV
eurjchem-870	202	11	cooled	cool	VERB
eurjchem-870	202	12	to	to	ADP
eurjchem-870	202	13	0‐5	0‐5	NUM
eurjchem-870	202	14	°	°	SCONJ
eurjchem-870	202	15	c	c	NOUN
eurjchem-870	202	16	.	.	PUNCT
eurjchem-870	202	17	sodium	sodium	NOUN
eurjchem-870	202	18	nitrite	nitrite	NOUN
eurjchem-870	202	19	(	(	PUNCT
eurjchem-870	202	20	0.069	0.069	NUM
eurjchem-870	202	21	 	 	SPACE
eurjchem-870	202	22	g	g	PROPN
eurjchem-870	202	23	,	,	PUNCT
eurjchem-870	202	24	0.001mol	0.001mol	PROPN
eurjchem-870	202	25	)	)	PUNCT
eurjchem-870	202	26	in	in	ADP
eurjchem-870	202	27	water	water	NOUN
eurjchem-870	202	28	(	(	PUNCT
eurjchem-870	202	29	3	3	NUM
eurjchem-870	202	30	ml	ml	NOUN
eurjchem-870	202	31	)	)	PUNCT
eurjchem-870	202	32	was	be	AUX
eurjchem-870	202	33	then	then	ADV
eurjchem-870	202	34	added	add	VERB
eurjchem-870	202	35	to	to	ADP
eurjchem-870	202	36	this	this	DET
eurjchem-870	202	37	solution	solution	NOUN
eurjchem-870	202	38	dropwise	dropwise	NOUN
eurjchem-870	202	39	with	with	ADP
eurjchem-870	202	40	vigorous	vigorous	ADJ
eurjchem-870	202	41	stirring	stirring	NOUN
eurjchem-870	202	42	during	during	ADP
eurjchem-870	202	43	about	about	ADV
eurjchem-870	202	44	1	1	NUM
eurjchem-870	202	45	 	 	SPACE
eurjchem-870	202	46	h	h	NOUN
eurjchem-870	202	47	,	,	PUNCT
eurjchem-870	202	48	while	while	SCONJ
eurjchem-870	202	49	cooling	cool	VERB
eurjchem-870	202	50	at	at	ADP
eurjchem-870	202	51	0‐5	0‐5	NOUN
eurjchem-870	202	52	°	°	ADP
eurjchem-870	202	53	c	c	X
eurjchem-870	202	54	.	.	PUNCT
eurjchem-870	203	1	the	the	DET
eurjchem-870	203	2	clear	clear	ADJ
eurjchem-870	203	3	diazonium	diazonium	NOUN
eurjchem-870	203	4	salt	salt	NOUN
eurjchem-870	203	5	solution	solution	NOUN
eurjchem-870	203	6	was	be	AUX
eurjchem-870	203	7	then	then	ADV
eurjchem-870	203	8	added	add	VERB
eurjchem-870	203	9	dropwise	dropwise	NOUN
eurjchem-870	203	10	to	to	ADP
eurjchem-870	203	11	a	a	DET
eurjchem-870	203	12	well	well	ADV
eurjchem-870	203	13	cooled	cool	VERB
eurjchem-870	203	14	(	(	PUNCT
eurjchem-870	203	15	0‐5	0‐5	PROPN
eurjchem-870	203	16	°	°	ADP
eurjchem-870	203	17	c	c	NOUN
eurjchem-870	203	18	)	)	PUNCT
eurjchem-870	203	19	and	and	CCONJ
eurjchem-870	203	20	stirred	stir	VERB
eurjchem-870	203	21	solution	solution	NOUN
eurjchem-870	203	22	of	of	ADP
eurjchem-870	203	23	pyrazolone	pyrazolone	NOUN
eurjchem-870	203	24	3	3	NUM
eurjchem-870	203	25	(	(	PUNCT
eurjchem-870	203	26	0.236	0.236	NUM
eurjchem-870	203	27	 	 	SPACE
eurjchem-870	203	28	g	g	PROPN
eurjchem-870	203	29	,	,	PUNCT
eurjchem-870	203	30	0.001mol	0.001mol	PROPN
eurjchem-870	203	31	)	)	PUNCT
eurjchem-870	203	32	in	in	ADP
eurjchem-870	203	33	sodium	sodium	NOUN
eurjchem-870	203	34	acetate	acetate	NOUN
eurjchem-870	203	35	(	(	PUNCT
eurjchem-870	203	36	1	1	NUM
eurjchem-870	203	37	 	 	SPACE
eurjchem-870	203	38	g	g	NOUN
eurjchem-870	203	39	,	,	PUNCT
eurjchem-870	203	40	dissolved	dissolve	VERB
eurjchem-870	203	41	in	in	ADP
eurjchem-870	203	42	5	5	NUM
eurjchem-870	203	43	 	 	SPACE
eurjchem-870	203	44	ml	ml	NOUN
eurjchem-870	203	45	of	of	ADP
eurjchem-870	203	46	25	25	NUM
eurjchem-870	203	47	%	%	NOUN
eurjchem-870	203	48	aqueous	aqueous	ADJ
eurjchem-870	203	49	ethanol	ethanol	NOUN
eurjchem-870	203	50	)	)	PUNCT
eurjchem-870	203	51	.	.	PUNCT
eurjchem-870	204	1	stirring	stirring	NOUN
eurjchem-870	204	2	was	be	AUX
eurjchem-870	204	3	continued	continue	VERB
eurjchem-870	204	4	for	for	ADP
eurjchem-870	204	5	4h	4h	NUM
eurjchem-870	204	6	at	at	ADP
eurjchem-870	204	7	0‐5	0‐5	NOUN
eurjchem-870	204	8	°	°	SCONJ
eurjchem-870	204	9	c	c	NOUN
eurjchem-870	204	10	and	and	CCONJ
eurjchem-870	204	11	the	the	DET
eurjchem-870	204	12	precipitated	precipitate	VERB
eurjchem-870	204	13	product	product	NOUN
eurjchem-870	204	14	separated	separate	VERB
eurjchem-870	204	15	upon	upon	SCONJ
eurjchem-870	204	16	dilution	dilution	NOUN
eurjchem-870	204	17	with	with	ADP
eurjchem-870	204	18	cold	cold	ADJ
eurjchem-870	204	19	water	water	NOUN
eurjchem-870	204	20	(	(	PUNCT
eurjchem-870	204	21	25	25	NUM
eurjchem-870	204	22	ml	ml	NOUN
eurjchem-870	204	23	)	)	PUNCT
eurjchem-870	204	24	was	be	AUX
eurjchem-870	204	25	filtered	filter	VERB
eurjchem-870	204	26	off	off	ADP
eurjchem-870	204	27	,	,	PUNCT
eurjchem-870	204	28	washed	wash	VERB
eurjchem-870	204	29	with	with	ADP
eurjchem-870	204	30	water	water	NOUN
eurjchem-870	204	31	several	several	ADJ
eurjchem-870	204	32	times	time	NOUN
eurjchem-870	204	33	,	,	PUNCT
eurjchem-870	204	34	dried	dry	VERB
eurjchem-870	204	35	and	and	CCONJ
eurjchem-870	204	36	recrystallized	recrystallize	VERB
eurjchem-870	204	37	from	from	ADP
eurjchem-870	204	38	ethanol	ethanol	NOUN
eurjchem-870	204	39	:	:	PUNCT
eurjchem-870	204	40	benzene	benzene	NOUN
eurjchem-870	204	41	(	(	PUNCT
eurjchem-870	204	42	1:1	1:1	NUM
eurjchem-870	204	43	)	)	PUNCT
eurjchem-870	204	44	(	(	PUNCT
eurjchem-870	204	45	scheme	scheme	NOUN
eurjchem-870	204	46	2	2	NUM
eurjchem-870	204	47	)	)	PUNCT
eurjchem-870	204	48	.	.	PUNCT
eurjchem-870	205	1	color	color	NOUN
eurjchem-870	205	2	:	:	PUNCT
eurjchem-870	205	3	white	white	ADJ
eurjchem-870	205	4	.	.	PUNCT
eurjchem-870	206	1	yield	yield	NOUN
eurjchem-870	206	2	:	:	PUNCT
eurjchem-870	206	3	80.2	80.2	NUM
eurjchem-870	206	4	%	%	NOUN
eurjchem-870	206	5	.	.	PUNCT
eurjchem-870	207	1	m.p	m.p	PROPN
eurjchem-870	207	2	.	.	PROPN
eurjchem-870	207	3	:	:	PUNCT
eurjchem-870	208	1	182‐184	182‐184	PROPN
eurjchem-870	208	2	°	°	ADP
eurjchem-870	208	3	c	c	X
eurjchem-870	208	4	.	.	PUNCT
eurjchem-870	209	1	ft‐ir	ft‐ir	NOUN
eurjchem-870	209	2	(	(	PUNCT
eurjchem-870	209	3	kbr	kbr	PROPN
eurjchem-870	209	4	,	,	PUNCT
eurjchem-870	209	5			PROPN
eurjchem-870	209	6	,	,	PUNCT
eurjchem-870	209	7	cm‐1	cm‐1	PROPN
eurjchem-870	209	8	):	):	PUNCT
eurjchem-870	209	9	1712	1712	NUM
eurjchem-870	209	10	(	(	PUNCT
eurjchem-870	209	11	c	c	NOUN
eurjchem-870	209	12	=	=	NOUN
eurjchem-870	209	13	o	o	NOUN
eurjchem-870	209	14	)	)	PUNCT
eurjchem-870	209	15	,	,	PUNCT
eurjchem-870	209	16	1663	1663	NUM
eurjchem-870	209	17	(	(	PUNCT
eurjchem-870	209	18	c	c	NOUN
eurjchem-870	209	19	=	=	SYM
eurjchem-870	209	20	n	n	NUM
eurjchem-870	209	21	)	)	PUNCT
eurjchem-870	209	22	.	.	PUNCT
eurjchem-870	210	1	1h	1h	NUM
eurjchem-870	210	2	nmr	nmr	NOUN
eurjchem-870	210	3	(	(	PUNCT
eurjchem-870	210	4	300	300	NUM
eurjchem-870	210	5	mhz	mhz	NOUN
eurjchem-870	210	6	,	,	PUNCT
eurjchem-870	210	7	cdcl3	cdcl3	PROPN
eurjchem-870	210	8	,	,	PUNCT
eurjchem-870	210	9	δ	δ	PROPN
eurjchem-870	210	10	,	,	PUNCT
eurjchem-870	210	11	ppm	ppm	NUM
eurjchem-870	210	12	):	):	PUNCT
eurjchem-870	210	13	8.23‐8.24	8.23‐8.24	NUM
eurjchem-870	210	14	(	(	PUNCT
eurjchem-870	210	15	d	d	PROPN
eurjchem-870	210	16	,	,	PUNCT
eurjchem-870	210	17	1h	1h	NUM
eurjchem-870	210	18	,	,	PUNCT
eurjchem-870	210	19	nch	nch	NOUN
eurjchem-870	210	20	)	)	PUNCT
eurjchem-870	210	21	,	,	PUNCT
eurjchem-870	210	22	7.52‐8.07	7.52‐8.07	NUM
eurjchem-870	210	23	(	(	PUNCT
eurjchem-870	210	24	m	m	PROPN
eurjchem-870	210	25	,	,	PUNCT
eurjchem-870	210	26	4h	4h	NUM
eurjchem-870	210	27	,	,	PUNCT
eurjchem-870	210	28	arh	arh	PROPN
eurjchem-870	210	29	)	)	PUNCT
eurjchem-870	210	30	,	,	PUNCT
eurjchem-870	210	31	7.50‐7.51	7.50‐7.51	NUM
eurjchem-870	210	32	(	(	PUNCT
eurjchem-870	210	33	d	d	PROPN
eurjchem-870	210	34	,	,	PUNCT
eurjchem-870	210	35	1h	1h	NUM
eurjchem-870	210	36	,	,	PUNCT
eurjchem-870	210	37	=	=	NOUN
eurjchem-870	210	38	ch‐s	ch‐s	X
eurjchem-870	210	39	)	)	PUNCT
eurjchem-870	210	40	,	,	PUNCT
eurjchem-870	210	41	7.04‐7.25	7.04‐7.25	NUM
eurjchem-870	210	42	(	(	PUNCT
eurjchem-870	210	43	m	m	PROPN
eurjchem-870	210	44	,	,	PUNCT
eurjchem-870	210	45	6h	6h	NUM
eurjchem-870	210	46	,	,	PUNCT
eurjchem-870	210	47	arh	arh	PROPN
eurjchem-870	210	48	)	)	PUNCT
eurjchem-870	210	49	,	,	PUNCT
eurjchem-870	210	50	3.87	3.87	NUM
eurjchem-870	210	51	(	(	PUNCT
eurjchem-870	210	52	s	s	PROPN
eurjchem-870	210	53	,	,	PUNCT
eurjchem-870	210	54	1h	1h	NUM
eurjchem-870	210	55	,	,	PUNCT
eurjchem-870	210	56	ch	ch	NOUN
eurjchem-870	210	57	)	)	PUNCT
eurjchem-870	210	58	.	.	PUNCT
eurjchem-870	211	1	ms	ms	NOUN
eurjchem-870	211	2	(	(	PUNCT
eurjchem-870	211	3	ei	ei	PROPN
eurjchem-870	211	4	,	,	PUNCT
eurjchem-870	211	5	m	m	PROPN
eurjchem-870	211	6	/	/	SYM
eurjchem-870	211	7	z	z	PROPN
eurjchem-870	211	8	(	(	PUNCT
eurjchem-870	211	9	%	%	NOUN
eurjchem-870	211	10	)	)	PUNCT
eurjchem-870	211	11	):	):	PUNCT
eurjchem-870	211	12	347	347	NUM
eurjchem-870	211	13	(	(	PUNCT
eurjchem-870	211	14	62.7	62.7	NUM
eurjchem-870	211	15	,	,	PUNCT
eurjchem-870	211	16	m+	m+	NOUN
eurjchem-870	211	17	·	·	PUNCT
eurjchem-870	211	18	)	)	PUNCT
eurjchem-870	211	19	,	,	PUNCT
eurjchem-870	211	20	236	236	NUM
eurjchem-870	211	21	(	(	PUNCT
eurjchem-870	211	22	16.4	16.4	NUM
eurjchem-870	211	23	)	)	PUNCT
eurjchem-870	211	24	,	,	PUNCT
eurjchem-870	211	25	129	129	NUM
eurjchem-870	211	26	(	(	PUNCT
eurjchem-870	211	27	100	100	NUM
eurjchem-870	211	28	)	)	PUNCT
eurjchem-870	211	29	,	,	PUNCT
eurjchem-870	211	30	84	84	NUM
eurjchem-870	211	31	(	(	PUNCT
eurjchem-870	211	32	19.4	19.4	NUM
eurjchem-870	211	33	)	)	PUNCT
eurjchem-870	211	34	,	,	PUNCT
eurjchem-870	211	35	78	78	NUM
eurjchem-870	211	36	(	(	PUNCT
eurjchem-870	211	37	19.4	19.4	NUM
eurjchem-870	211	38	)	)	PUNCT
eurjchem-870	211	39	,	,	PUNCT
eurjchem-870	211	40	77	77	NUM
eurjchem-870	211	41	(	(	PUNCT
eurjchem-870	211	42	74.6	74.6	NUM
eurjchem-870	211	43	)	)	PUNCT
eurjchem-870	211	44	,	,	PUNCT
eurjchem-870	211	45	55	55	NUM
eurjchem-870	211	46	(	(	PUNCT
eurjchem-870	211	47	4.5	4.5	NUM
eurjchem-870	211	48	)	)	PUNCT
eurjchem-870	211	49	.	.	PUNCT
eurjchem-870	212	1	anal	anal	PROPN
eurjchem-870	212	2	.	.	PUNCT
eurjchem-870	212	3	calcd	calcd	NOUN
eurjchem-870	212	4	.	.	PUNCT
eurjchem-870	213	1	for	for	ADP
eurjchem-870	213	2	c18h13n5os	c18h13n5o	NOUN
eurjchem-870	213	3	:	:	PUNCT
eurjchem-870	213	4	c	c	X
eurjchem-870	213	5	,	,	PUNCT
eurjchem-870	213	6	62.23	62.23	NUM
eurjchem-870	213	7	;	;	PUNCT
eurjchem-870	213	8	h	h	X
eurjchem-870	213	9	,	,	PUNCT
eurjchem-870	213	10	3.77	3.77	NUM
eurjchem-870	213	11	;	;	PUNCT
eurjchem-870	213	12	n	n	CCONJ
eurjchem-870	213	13	,	,	PUNCT
eurjchem-870	213	14	20.16	20.16	NUM
eurjchem-870	213	15	;	;	PUNCT
eurjchem-870	213	16	s	s	X
eurjchem-870	213	17	,	,	PUNCT
eurjchem-870	213	18	9.23	9.23	NUM
eurjchem-870	213	19	.	.	PUNCT
eurjchem-870	213	20	found	find	VERB
eurjchem-870	213	21	:	:	PUNCT
eurjchem-870	214	1	c	c	X
eurjchem-870	214	2	,	,	PUNCT
eurjchem-870	214	3	62.41	62.41	NUM
eurjchem-870	214	4	;	;	PUNCT
eurjchem-870	214	5	h	h	NOUN
eurjchem-870	214	6	,	,	PUNCT
eurjchem-870	214	7	3.92	3.92	NUM
eurjchem-870	214	8	,	,	PUNCT
eurjchem-870	214	9	n	n	CCONJ
eurjchem-870	214	10	,	,	PUNCT
eurjchem-870	214	11	20.19	20.19	NUM
eurjchem-870	214	12	;	;	PUNCT
eurjchem-870	214	13	s	s	X
eurjchem-870	214	14	,	,	PUNCT
eurjchem-870	214	15	9.41	9.41	NUM
eurjchem-870	214	16	%	%	NOUN
eurjchem-870	214	17	.	.	PUNCT
eurjchem-870	215	1	2.2.14	2.2.14	X
eurjchem-870	215	2	.	.	PUNCT
eurjchem-870	216	1	1,3‐diphenyl‐4‐(phenyldiazenyl)‐1h‐pyrazol‐5‐ol	1,3‐diphenyl‐4‐(phenyldiazenyl)‐1h‐pyrazol‐5‐ol	NUM
eurjchem-870	216	2	(	(	PUNCT
eurjchem-870	216	3	18	18	NUM
eurjchem-870	216	4	)	)	PUNCT
eurjchem-870	216	5	aniline	aniline	NOUN
eurjchem-870	216	6	(	(	PUNCT
eurjchem-870	216	7	0.093	0.093	NUM
eurjchem-870	216	8	 	 	SPACE
eurjchem-870	216	9	ml	ml	NOUN
eurjchem-870	216	10	,	,	PUNCT
eurjchem-870	216	11	0.001mol	0.001mol	PROPN
eurjchem-870	216	12	)	)	PUNCT
eurjchem-870	216	13	in	in	ADP
eurjchem-870	216	14	conc	conc	NOUN
eurjchem-870	216	15	.	.	PUNCT
eurjchem-870	217	1	hcl	hcl	PROPN
eurjchem-870	217	2	(	(	PUNCT
eurjchem-870	217	3	3.6	3.6	NUM
eurjchem-870	217	4	 	 	SPACE
eurjchem-870	217	5	ml	ml	NOUN
eurjchem-870	217	6	)	)	PUNCT
eurjchem-870	217	7	and	and	CCONJ
eurjchem-870	217	8	water	water	NOUN
eurjchem-870	217	9	(	(	PUNCT
eurjchem-870	217	10	1	1	NUM
eurjchem-870	217	11	ml	ml	NOUN
eurjchem-870	217	12	)	)	PUNCT
eurjchem-870	217	13	was	be	AUX
eurjchem-870	217	14	cooled	cool	VERB
eurjchem-870	217	15	in	in	ADP
eurjchem-870	217	16	ice	ice	NOUN
eurjchem-870	217	17	bath	bath	NOUN
eurjchem-870	217	18	at	at	ADP
eurjchem-870	217	19	0‐5	0‐5	NOUN
eurjchem-870	217	20	°	°	ADP
eurjchem-870	217	21	c	c	NOUN
eurjchem-870	217	22	and	and	CCONJ
eurjchem-870	217	23	diazotized	diazotize	VERB
eurjchem-870	217	24	with	with	ADP
eurjchem-870	217	25	the	the	DET
eurjchem-870	217	26	solution	solution	NOUN
eurjchem-870	217	27	of	of	ADP
eurjchem-870	217	28	sodium	sodium	NOUN
eurjchem-870	217	29	nitrite	nitrite	NOUN
eurjchem-870	217	30	(	(	PUNCT
eurjchem-870	217	31	0.345	0.345	NUM
eurjchem-870	217	32	 	 	SPACE
eurjchem-870	217	33	g	g	NOUN
eurjchem-870	217	34	)	)	PUNCT
eurjchem-870	217	35	in	in	ADP
eurjchem-870	217	36	water	water	NOUN
eurjchem-870	217	37	(	(	PUNCT
eurjchem-870	217	38	2	2	NUM
eurjchem-870	217	39	 	 	SPACE
eurjchem-870	217	40	ml	ml	NOUN
eurjchem-870	217	41	)	)	PUNCT
eurjchem-870	217	42	.	.	PUNCT
eurjchem-870	218	1	the	the	DET
eurjchem-870	218	2	cold	cold	ADJ
eurjchem-870	218	3	diazonium	diazonium	NOUN
eurjchem-870	218	4	solution	solution	NOUN
eurjchem-870	218	5	was	be	AUX
eurjchem-870	218	6	added	add	VERB
eurjchem-870	218	7	slowly	slowly	ADV
eurjchem-870	218	8	to	to	ADP
eurjchem-870	218	9	a	a	DET
eurjchem-870	218	10	well	well	ADV
eurjchem-870	218	11	stirred	stir	VERB
eurjchem-870	218	12	solution	solution	NOUN
eurjchem-870	218	13	pyrazolone	pyrazolone	NOUN
eurjchem-870	218	14	3	3	NUM
eurjchem-870	218	15	(	(	PUNCT
eurjchem-870	218	16	0.236	0.236	NUM
eurjchem-870	218	17	 	 	SPACE
eurjchem-870	218	18	g	g	NOUN
eurjchem-870	218	19	,	,	PUNCT
eurjchem-870	218	20	0.001	0.001	NUM
eurjchem-870	218	21	 	 	SPACE
eurjchem-870	218	22	mol	mol	NOUN
eurjchem-870	218	23	)	)	PUNCT
eurjchem-870	218	24	in	in	ADP
eurjchem-870	218	25	pyridine	pyridine	NOUN
eurjchem-870	218	26	(	(	PUNCT
eurjchem-870	218	27	20	20	NUM
eurjchem-870	218	28	 	 	SPACE
eurjchem-870	218	29	ml	ml	NOUN
eurjchem-870	218	30	)	)	PUNCT
eurjchem-870	218	31	.	.	PUNCT
eurjchem-870	219	1	the	the	DET
eurjchem-870	219	2	reaction	reaction	NOUN
eurjchem-870	219	3	mixture	mixture	NOUN
eurjchem-870	219	4	was	be	AUX
eurjchem-870	219	5	stirred	stir	VERB
eurjchem-870	219	6	for	for	ADP
eurjchem-870	219	7	another	another	DET
eurjchem-870	219	8	2	2	NUM
eurjchem-870	219	9	 	 	SPACE
eurjchem-870	219	10	h.	h.	NOUN
eurjchem-870	219	11	the	the	DET
eurjchem-870	219	12	crude	crude	ADJ
eurjchem-870	219	13	product	product	NOUN
eurjchem-870	219	14	was	be	AUX
eurjchem-870	219	15	filtered	filter	VERB
eurjchem-870	219	16	off	off	ADP
eurjchem-870	219	17	,	,	PUNCT
eurjchem-870	219	18	dried	dry	VERB
eurjchem-870	219	19	and	and	CCONJ
eurjchem-870	219	20	recrystallized	recrystallize	VERB
eurjchem-870	219	21	from	from	ADP
eurjchem-870	219	22	ethanol	ethanol	NOUN
eurjchem-870	219	23	(	(	PUNCT
eurjchem-870	219	24	scheme	scheme	NOUN
eurjchem-870	219	25	2	2	NUM
eurjchem-870	219	26	)	)	PUNCT
eurjchem-870	219	27	.	.	PUNCT
eurjchem-870	220	1	color	color	NOUN
eurjchem-870	220	2	:	:	PUNCT
eurjchem-870	220	3	orange	orange	ADJ
eurjchem-870	220	4	.	.	PUNCT
eurjchem-870	221	1	yield	yield	NOUN
eurjchem-870	221	2	:	:	PUNCT
eurjchem-870	221	3	55	55	NUM
eurjchem-870	221	4	%	%	NOUN
eurjchem-870	221	5	.	.	PUNCT
eurjchem-870	222	1	m.p	m.p	PROPN
eurjchem-870	222	2	.	.	PROPN
eurjchem-870	222	3	:	:	PUNCT
eurjchem-870	223	1	160‐162	160‐162	NUM
eurjchem-870	223	2	°	°	NUM
eurjchem-870	223	3	c	c	X
eurjchem-870	223	4	.	.	PUNCT
eurjchem-870	224	1	ft‐ir	ft‐ir	NOUN
eurjchem-870	224	2	(	(	PUNCT
eurjchem-870	224	3	kbr	kbr	PROPN
eurjchem-870	224	4	,	,	PUNCT
eurjchem-870	224	5			PROPN
eurjchem-870	224	6	,	,	PUNCT
eurjchem-870	224	7	cm‐1	cm‐1	PROPN
eurjchem-870	224	8	):	):	PUNCT
eurjchem-870	224	9	3435	3435	NUM
eurjchem-870	224	10	(	(	PUNCT
eurjchem-870	224	11	oh	oh	INTJ
eurjchem-870	224	12	)	)	PUNCT
eurjchem-870	224	13	,	,	PUNCT
eurjchem-870	224	14	1650	1650	NUM
eurjchem-870	224	15	(	(	PUNCT
eurjchem-870	224	16	c	c	NOUN
eurjchem-870	224	17	=	=	NOUN
eurjchem-870	224	18	o	o	NOUN
eurjchem-870	224	19	)	)	PUNCT
eurjchem-870	224	20	.	.	PUNCT
eurjchem-870	225	1	1h	1h	NUM
eurjchem-870	225	2	nmr	nmr	NOUN
eurjchem-870	225	3	(	(	PUNCT
eurjchem-870	225	4	300	300	NUM
eurjchem-870	225	5	mhz	mhz	NOUN
eurjchem-870	225	6	,	,	PUNCT
eurjchem-870	225	7	cdcl3	cdcl3	PROPN
eurjchem-870	225	8	,	,	PUNCT
eurjchem-870	225	9	δ	δ	PROPN
eurjchem-870	225	10	,	,	PUNCT
eurjchem-870	225	11	ppm	ppm	NUM
eurjchem-870	225	12	):	):	PUNCT
eurjchem-870	225	13	14.07	14.07	NUM
eurjchem-870	225	14	(	(	PUNCT
eurjchem-870	225	15	s	s	PROPN
eurjchem-870	225	16	,	,	PUNCT
eurjchem-870	225	17	1h	1h	NUM
eurjchem-870	225	18	,	,	PUNCT
eurjchem-870	225	19	oh	oh	INTJ
eurjchem-870	225	20	d2o	d2o	NOUN
eurjchem-870	225	21	exchangeable	exchangeable	ADJ
eurjchem-870	225	22	)	)	PUNCT
eurjchem-870	225	23	,	,	PUNCT
eurjchem-870	225	24	7.22‐8.28	7.22‐8.28	NUM
eurjchem-870	225	25	(	(	PUNCT
eurjchem-870	225	26	m	m	PROPN
eurjchem-870	225	27	,	,	PUNCT
eurjchem-870	225	28	15h	15h	NUM
eurjchem-870	225	29	,	,	PUNCT
eurjchem-870	225	30	arh	arh	PROPN
eurjchem-870	225	31	)	)	PUNCT
eurjchem-870	225	32	.	.	PUNCT
eurjchem-870	226	1	ms	ms	NOUN
eurjchem-870	226	2	(	(	PUNCT
eurjchem-870	226	3	ei	ei	PROPN
eurjchem-870	226	4	,	,	PUNCT
eurjchem-870	226	5	m	m	PROPN
eurjchem-870	226	6	/	/	SYM
eurjchem-870	226	7	z	z	PROPN
eurjchem-870	226	8	(	(	PUNCT
eurjchem-870	226	9	%	%	NOUN
eurjchem-870	226	10	)	)	PUNCT
eurjchem-870	226	11	):	):	PUNCT
eurjchem-870	226	12	340	340	NUM
eurjchem-870	226	13	(	(	PUNCT
eurjchem-870	226	14	72.6	72.6	NUM
eurjchem-870	226	15	,	,	PUNCT
eurjchem-870	226	16	m+	m+	NOUN
eurjchem-870	226	17	·	·	PUNCT
eurjchem-870	226	18	)	)	PUNCT
eurjchem-870	226	19	,	,	PUNCT
eurjchem-870	226	20	263	263	NUM
eurjchem-870	226	21	(	(	PUNCT
eurjchem-870	226	22	26.0	26.0	NUM
eurjchem-870	226	23	)	)	PUNCT
eurjchem-870	226	24	,	,	PUNCT
eurjchem-870	226	25	235	235	NUM
eurjchem-870	226	26	(	(	PUNCT
eurjchem-870	226	27	28.3	28.3	NUM
eurjchem-870	226	28	)	)	PUNCT
eurjchem-870	226	29	,	,	PUNCT
eurjchem-870	226	30	220	220	NUM
eurjchem-870	226	31	(	(	PUNCT
eurjchem-870	226	32	6.0	6.0	NUM
eurjchem-870	226	33	)	)	PUNCT
eurjchem-870	226	34	,	,	PUNCT
eurjchem-870	226	35	77	77	NUM
eurjchem-870	226	36	(	(	PUNCT
eurjchem-870	226	37	100	100	NUM
eurjchem-870	226	38	)	)	PUNCT
eurjchem-870	226	39	,	,	PUNCT
eurjchem-870	226	40	78	78	NUM
eurjchem-870	226	41	(	(	PUNCT
eurjchem-870	226	42	7.5	7.5	NUM
eurjchem-870	226	43	)	)	PUNCT
eurjchem-870	226	44	.	.	PUNCT
eurjchem-870	227	1	anal	anal	PROPN
eurjchem-870	227	2	.	.	PUNCT
eurjchem-870	227	3	calcd	calcd	NOUN
eurjchem-870	227	4	.	.	PUNCT
eurjchem-870	228	1	for	for	SCONJ
eurjchem-870	228	2	c21h16n4o	c21h16n4o	PROPN
eurjchem-870	228	3	:	:	PUNCT
eurjchem-870	228	4	c	c	X
eurjchem-870	228	5	,	,	PUNCT
eurjchem-870	228	6	74.10	74.10	NUM
eurjchem-870	228	7	;	;	PUNCT
eurjchem-870	228	8	h	h	NOUN
eurjchem-870	228	9	,	,	PUNCT
eurjchem-870	228	10	4.74	4.74	NUM
eurjchem-870	228	11	;	;	PUNCT
eurjchem-870	228	12	n	n	CCONJ
eurjchem-870	228	13	,	,	PUNCT
eurjchem-870	228	14	16.46	16.46	NUM
eurjchem-870	228	15	.	.	PUNCT
eurjchem-870	228	16	found	find	VERB
eurjchem-870	228	17	:	:	PUNCT
eurjchem-870	229	1	c	c	X
eurjchem-870	229	2	,	,	PUNCT
eurjchem-870	229	3	74.23	74.23	NUM
eurjchem-870	229	4	;	;	PUNCT
eurjchem-870	229	5	h	h	NOUN
eurjchem-870	229	6	,	,	PUNCT
eurjchem-870	229	7	4.91	4.91	NUM
eurjchem-870	229	8	;	;	PUNCT
eurjchem-870	229	9	n	n	CCONJ
eurjchem-870	229	10	,	,	PUNCT
eurjchem-870	229	11	16.53	16.53	NUM
eurjchem-870	229	12	%	%	NOUN
eurjchem-870	229	13	.	.	PUNCT
eurjchem-870	230	1	2.2.15	2.2.15	X
eurjchem-870	230	2	.	.	PROPN
eurjchem-870	230	3	4‐(4‐methoxybenzylidene)‐1,3‐diphenyl‐1h‐pyrazol‐	4‐(4‐methoxybenzylidene)‐1,3‐diphenyl‐1h‐pyrazol‐	NUM
eurjchem-870	231	1	5(4h)‐one	5(4h)‐one	NUM
eurjchem-870	231	2	(	(	PUNCT
eurjchem-870	231	3	19	19	NUM
eurjchem-870	231	4	)	)	PUNCT
eurjchem-870	231	5	method	method	NOUN
eurjchem-870	231	6	a	a	DET
eurjchem-870	231	7	:	:	PUNCT
eurjchem-870	231	8	a	a	DET
eurjchem-870	231	9	mixture	mixture	NOUN
eurjchem-870	231	10	of	of	ADP
eurjchem-870	231	11	pyrazolone	pyrazolone	NOUN
eurjchem-870	231	12	3	3	NUM
eurjchem-870	231	13	(	(	PUNCT
eurjchem-870	231	14	2.36	2.36	NUM
eurjchem-870	231	15	 	 	SPACE
eurjchem-870	231	16	g	g	NOUN
eurjchem-870	231	17	,	,	PUNCT
eurjchem-870	231	18	0.01	0.01	NUM
eurjchem-870	231	19	 	 	SPACE
eurjchem-870	231	20	mol	mol	NUM
eurjchem-870	231	21	)	)	PUNCT
eurjchem-870	231	22	,	,	PUNCT
eurjchem-870	231	23	p‐	p‐	NOUN
eurjchem-870	231	24	anisaldehyde	anisaldehyde	NOUN
eurjchem-870	231	25	(	(	PUNCT
eurjchem-870	231	26	1.36	1.36	NUM
eurjchem-870	231	27	 	 	SPACE
eurjchem-870	231	28	ml	ml	NOUN
eurjchem-870	231	29	,	,	PUNCT
eurjchem-870	231	30	0.01	0.01	NUM
eurjchem-870	231	31	 	 	SPACE
eurjchem-870	231	32	mol	mol	NOUN
eurjchem-870	231	33	)	)	PUNCT
eurjchem-870	231	34	in	in	ADP
eurjchem-870	231	35	ethanol	ethanol	NOUN
eurjchem-870	231	36	(	(	PUNCT
eurjchem-870	231	37	70	70	NUM
eurjchem-870	231	38	 	 	SPACE
eurjchem-870	231	39	ml	ml	NOUN
eurjchem-870	231	40	)	)	PUNCT
eurjchem-870	231	41	in	in	ADP
eurjchem-870	231	42	presence	presence	NOUN
eurjchem-870	231	43	of	of	ADP
eurjchem-870	231	44	piperidine	piperidine	NOUN
eurjchem-870	231	45	(	(	PUNCT
eurjchem-870	231	46	1	1	NUM
eurjchem-870	231	47	 	 	SPACE
eurjchem-870	231	48	ml	ml	NOUN
eurjchem-870	231	49	)	)	PUNCT
eurjchem-870	231	50	was	be	AUX
eurjchem-870	231	51	refluxed	refluxe	VERB
eurjchem-870	231	52	for	for	ADP
eurjchem-870	231	53	2	2	NUM
eurjchem-870	231	54	 	 	SPACE
eurjchem-870	231	55	h.	h.	NOUN
eurjchem-870	231	56	a	a	DET
eurjchem-870	231	57	white	white	ADJ
eurjchem-870	231	58	powder	powder	NOUN
eurjchem-870	231	59	was	be	AUX
eurjchem-870	231	60	formed	form	VERB
eurjchem-870	231	61	during	during	ADP
eurjchem-870	231	62	reflux	reflux	NOUN
eurjchem-870	231	63	.	.	PUNCT
eurjchem-870	232	1	after	after	ADP
eurjchem-870	232	2	cooling	cool	VERB
eurjchem-870	232	3	,	,	PUNCT
eurjchem-870	232	4	the	the	DET
eurjchem-870	232	5	white	white	ADJ
eurjchem-870	232	6	powder	powder	NOUN
eurjchem-870	232	7	was	be	AUX
eurjchem-870	232	8	filtered	filter	VERB
eurjchem-870	232	9	off	off	ADP
eurjchem-870	232	10	,	,	PUNCT
eurjchem-870	232	11	washed	wash	VERB
eurjchem-870	232	12	with	with	ADP
eurjchem-870	232	13	ethanol	ethanol	NOUN
eurjchem-870	232	14	,	,	PUNCT
eurjchem-870	232	15	dried	dry	VERB
eurjchem-870	232	16	and	and	CCONJ
eurjchem-870	232	17	crystallized	crystallize	VERB
eurjchem-870	232	18	from	from	ADP
eurjchem-870	232	19	ethanol	ethanol	NOUN
eurjchem-870	232	20	(	(	PUNCT
eurjchem-870	232	21	scheme	scheme	NOUN
eurjchem-870	232	22	2	2	NUM
eurjchem-870	232	23	)	)	PUNCT
eurjchem-870	232	24	.	.	PUNCT
eurjchem-870	233	1	color	color	NOUN
eurjchem-870	233	2	:	:	PUNCT
eurjchem-870	233	3	white	white	ADJ
eurjchem-870	233	4	.	.	PUNCT
eurjchem-870	234	1	yield	yield	NOUN
eurjchem-870	234	2	:	:	PUNCT
eurjchem-870	234	3	81.6	81.6	NUM
eurjchem-870	234	4	%	%	NOUN
eurjchem-870	234	5	.	.	PUNCT
eurjchem-870	235	1	m.p	m.p	PROPN
eurjchem-870	235	2	.	.	PROPN
eurjchem-870	235	3	:	:	PUNCT
eurjchem-870	236	1	218‐220	218‐220	NUM
eurjchem-870	236	2	°	°	ADP
eurjchem-870	236	3	c	c	NOUN
eurjchem-870	236	4	.	.	PUNCT
eurjchem-870	236	5	ft‐ir	ft‐ir	NOUN
eurjchem-870	236	6	(	(	PUNCT
eurjchem-870	236	7	kbr	kbr	PROPN
eurjchem-870	236	8	,	,	PUNCT
eurjchem-870	236	9			PROPN
eurjchem-870	236	10	,	,	PUNCT
eurjchem-870	236	11	cm‐1	cm‐1	PROPN
eurjchem-870	236	12	):	):	PUNCT
eurjchem-870	236	13	3054	3054	NUM
eurjchem-870	236	14	(	(	PUNCT
eurjchem-870	236	15	ch	ch	NOUN
eurjchem-870	236	16	aromatic	aromatic	NOUN
eurjchem-870	236	17	)	)	PUNCT
eurjchem-870	236	18	,	,	PUNCT
eurjchem-870	236	19	2950	2950	NUM
eurjchem-870	236	20	(	(	PUNCT
eurjchem-870	236	21	ch	ch	NOUN
eurjchem-870	236	22	aliphatic	aliphatic	PROPN
eurjchem-870	236	23	)	)	PUNCT
eurjchem-870	236	24	,	,	PUNCT
eurjchem-870	236	25	1714	1714	NUM
eurjchem-870	236	26	(	(	PUNCT
eurjchem-870	236	27	c	c	NOUN
eurjchem-870	236	28	=	=	NOUN
eurjchem-870	236	29	o	o	NOUN
eurjchem-870	236	30	)	)	PUNCT
eurjchem-870	236	31	.	.	PUNCT
eurjchem-870	237	1	1h	1h	NUM
eurjchem-870	237	2	nmr	nmr	NOUN
eurjchem-870	237	3	(	(	PUNCT
eurjchem-870	237	4	300	300	NUM
eurjchem-870	237	5	mhz	mhz	NOUN
eurjchem-870	237	6	,	,	PUNCT
eurjchem-870	237	7	dmso	dmso	NOUN
eurjchem-870	237	8	,	,	PUNCT
eurjchem-870	237	9	δ	δ	PROPN
eurjchem-870	237	10	,	,	PUNCT
eurjchem-870	237	11	ppm	ppm	NOUN
eurjchem-870	237	12	):	):	PUNCT
eurjchem-870	237	13	6.76‐8.04	6.76‐8.04	NUM
eurjchem-870	237	14	(	(	PUNCT
eurjchem-870	237	15	m	m	PROPN
eurjchem-870	237	16	,	,	PUNCT
eurjchem-870	237	17	14h	14h	NUM
eurjchem-870	237	18	,	,	PUNCT
eurjchem-870	237	19	arh	arh	PROPN
eurjchem-870	237	20	)	)	PUNCT
eurjchem-870	237	21	,	,	PUNCT
eurjchem-870	237	22	5.13	5.13	NUM
eurjchem-870	237	23	(	(	PUNCT
eurjchem-870	237	24	s	s	PROPN
eurjchem-870	237	25	,	,	PUNCT
eurjchem-870	237	26	1h	1h	NUM
eurjchem-870	237	27	,	,	PUNCT
eurjchem-870	237	28	ch	ch	NOUN
eurjchem-870	237	29	)	)	PUNCT
eurjchem-870	237	30	,	,	PUNCT
eurjchem-870	237	31	3.86	3.86	NUM
eurjchem-870	237	32	(	(	PUNCT
eurjchem-870	237	33	s	s	PROPN
eurjchem-870	237	34	,	,	PUNCT
eurjchem-870	237	35	3h	3h	NUM
eurjchem-870	237	36	,	,	PUNCT
eurjchem-870	237	37	och3	och3	ADJ
eurjchem-870	237	38	)	)	PUNCT
eurjchem-870	237	39	.	.	PUNCT
eurjchem-870	238	1	28	28	NUM
eurjchem-870	238	2	marzouk	marzouk	ADV
eurjchem-870	238	3	et	et	PROPN
eurjchem-870	238	4	al	al	PROPN
eurjchem-870	238	5	.	.	PUNCT
eurjchem-870	238	6	/	/	SYM
eurjchem-870	238	7	european	european	PROPN
eurjchem-870	238	8	journal	journal	PROPN
eurjchem-870	238	9	of	of	ADP
eurjchem-870	238	10	chemistry	chemistry	NOUN
eurjchem-870	238	11	5	5	NUM
eurjchem-870	238	12	(	(	PUNCT
eurjchem-870	238	13	1	1	NUM
eurjchem-870	238	14	)	)	PUNCT
eurjchem-870	238	15	(	(	PUNCT
eurjchem-870	238	16	2014	2014	NUM
eurjchem-870	238	17	)	)	PUNCT
eurjchem-870	238	18	24‐32	24‐32	NUM
eurjchem-870	238	19	scheme	scheme	NOUN
eurjchem-870	238	20	3	3	NUM
eurjchem-870	238	21	ms	ms	NOUN
eurjchem-870	238	22	(	(	PUNCT
eurjchem-870	238	23	ei	ei	PROPN
eurjchem-870	238	24	,	,	PUNCT
eurjchem-870	238	25	m	m	PROPN
eurjchem-870	238	26	/	/	SYM
eurjchem-870	238	27	z	z	PROPN
eurjchem-870	238	28	(	(	PUNCT
eurjchem-870	238	29	%	%	NOUN
eurjchem-870	238	30	)	)	PUNCT
eurjchem-870	238	31	):	):	PUNCT
eurjchem-870	238	32	354	354	NUM
eurjchem-870	238	33	(	(	PUNCT
eurjchem-870	238	34	71.7	71.7	NUM
eurjchem-870	238	35	,	,	PUNCT
eurjchem-870	238	36	m+	m+	NOUN
eurjchem-870	238	37	·	·	PUNCT
eurjchem-870	238	38	)	)	PUNCT
eurjchem-870	238	39	,	,	PUNCT
eurjchem-870	238	40	247	247	NUM
eurjchem-870	238	41	(	(	PUNCT
eurjchem-870	238	42	36.1	36.1	NUM
eurjchem-870	238	43	)	)	PUNCT
eurjchem-870	238	44	,	,	PUNCT
eurjchem-870	238	45	236	236	NUM
eurjchem-870	238	46	(	(	PUNCT
eurjchem-870	238	47	42.8	42.8	NUM
eurjchem-870	238	48	)	)	PUNCT
eurjchem-870	238	49	,	,	PUNCT
eurjchem-870	238	50	78	78	NUM
eurjchem-870	238	51	(	(	PUNCT
eurjchem-870	238	52	8.6	8.6	NUM
eurjchem-870	238	53	)	)	PUNCT
eurjchem-870	238	54	,	,	PUNCT
eurjchem-870	238	55	57	57	NUM
eurjchem-870	238	56	(	(	PUNCT
eurjchem-870	238	57	13.9	13.9	NUM
eurjchem-870	238	58	)	)	PUNCT
eurjchem-870	238	59	,	,	PUNCT
eurjchem-870	238	60	56(100	56(100	NOUN
eurjchem-870	238	61	)	)	PUNCT
eurjchem-870	238	62	.	.	PUNCT
eurjchem-870	239	1	anal	anal	PROPN
eurjchem-870	239	2	.	.	PUNCT
eurjchem-870	239	3	calcd	calcd	NOUN
eurjchem-870	239	4	.	.	PUNCT
eurjchem-870	240	1	for	for	ADP
eurjchem-870	240	2	c23h18n2o2	c23h18n2o2	NOUN
eurjchem-870	240	3	:	:	PUNCT
eurjchem-870	240	4	c	c	X
eurjchem-870	240	5	,	,	PUNCT
eurjchem-870	240	6	77.95	77.95	NUM
eurjchem-870	240	7	;	;	PUNCT
eurjchem-870	240	8	h	h	NOUN
eurjchem-870	240	9	,	,	PUNCT
eurjchem-870	240	10	5.12	5.12	NUM
eurjchem-870	240	11	;	;	PUNCT
eurjchem-870	240	12	n	n	CCONJ
eurjchem-870	240	13	,	,	PUNCT
eurjchem-870	240	14	7.90	7.90	NUM
eurjchem-870	240	15	.	.	PUNCT
eurjchem-870	240	16	found	find	VERB
eurjchem-870	240	17	:	:	PUNCT
eurjchem-870	241	1	c	c	X
eurjchem-870	241	2	,	,	PUNCT
eurjchem-870	241	3	78.19	78.19	NUM
eurjchem-870	241	4	;	;	PUNCT
eurjchem-870	241	5	h	h	NOUN
eurjchem-870	241	6	,	,	PUNCT
eurjchem-870	241	7	5.30	5.30	NUM
eurjchem-870	241	8	;	;	PUNCT
eurjchem-870	241	9	n	n	CCONJ
eurjchem-870	241	10	,	,	PUNCT
eurjchem-870	241	11	8.13	8.13	NUM
eurjchem-870	241	12	%	%	NOUN
eurjchem-870	241	13	.	.	PUNCT
eurjchem-870	242	1	method	method	PROPN
eurjchem-870	242	2	b	b	NOUN
eurjchem-870	242	3	:	:	PUNCT
eurjchem-870	242	4	a	a	DET
eurjchem-870	242	5	mixture	mixture	NOUN
eurjchem-870	242	6	of	of	ADP
eurjchem-870	242	7	pyrazolone	pyrazolone	NOUN
eurjchem-870	242	8	3	3	NUM
eurjchem-870	242	9	(	(	PUNCT
eurjchem-870	242	10	2.36	2.36	NUM
eurjchem-870	242	11	 	 	SPACE
eurjchem-870	242	12	g	g	NOUN
eurjchem-870	242	13	,	,	PUNCT
eurjchem-870	242	14	0.01	0.01	NUM
eurjchem-870	242	15	 	 	SPACE
eurjchem-870	242	16	mol	mol	NUM
eurjchem-870	242	17	)	)	PUNCT
eurjchem-870	242	18	,	,	PUNCT
eurjchem-870	242	19	p‐	p‐	NOUN
eurjchem-870	242	20	anisaldehyde	anisaldehyde	NOUN
eurjchem-870	242	21	(	(	PUNCT
eurjchem-870	242	22	1.36	1.36	NUM
eurjchem-870	242	23	 	 	SPACE
eurjchem-870	242	24	ml	ml	NOUN
eurjchem-870	242	25	,	,	PUNCT
eurjchem-870	242	26	0.01	0.01	NUM
eurjchem-870	242	27	 	 	SPACE
eurjchem-870	242	28	mol	mol	NUM
eurjchem-870	242	29	)	)	PUNCT
eurjchem-870	242	30	in	in	ADP
eurjchem-870	242	31	presence	presence	NOUN
eurjchem-870	242	32	of	of	ADP
eurjchem-870	242	33	piperidine	piperidine	NOUN
eurjchem-870	242	34	(	(	PUNCT
eurjchem-870	242	35	1	1	NUM
eurjchem-870	242	36	 	 	SPACE
eurjchem-870	242	37	ml	ml	NOUN
eurjchem-870	242	38	)	)	PUNCT
eurjchem-870	242	39	was	be	AUX
eurjchem-870	242	40	heated	heat	VERB
eurjchem-870	242	41	under	under	ADP
eurjchem-870	242	42	microwave	microwave	NOUN
eurjchem-870	242	43	irradiation	irradiation	NOUN
eurjchem-870	242	44	for	for	ADP
eurjchem-870	242	45	2	2	NUM
eurjchem-870	242	46	min	min	NOUN
eurjchem-870	242	47	at	at	ADP
eurjchem-870	242	48	power	power	NOUN
eurjchem-870	242	49	180	180	NUM
eurjchem-870	242	50	.	.	PUNCT
eurjchem-870	243	1	after	after	ADP
eurjchem-870	243	2	cooling	cool	VERB
eurjchem-870	243	3	,	,	PUNCT
eurjchem-870	243	4	the	the	DET
eurjchem-870	243	5	separated	separate	VERB
eurjchem-870	243	6	solid	solid	ADJ
eurjchem-870	243	7	was	be	AUX
eurjchem-870	243	8	filtered	filter	VERB
eurjchem-870	243	9	off	off	ADP
eurjchem-870	243	10	,	,	PUNCT
eurjchem-870	243	11	washed	wash	VERB
eurjchem-870	243	12	with	with	ADP
eurjchem-870	243	13	ethanol	ethanol	NOUN
eurjchem-870	243	14	,	,	PUNCT
eurjchem-870	243	15	dried	dry	VERB
eurjchem-870	243	16	and	and	CCONJ
eurjchem-870	243	17	recrystallized	recrystallize	VERB
eurjchem-870	243	18	from	from	ADP
eurjchem-870	243	19	ethanol	ethanol	NOUN
eurjchem-870	243	20	.	.	PUNCT
eurjchem-870	244	1	2.2.16	2.2.16	NUM
eurjchem-870	244	2	.	.	PUNCT
eurjchem-870	245	1	4‐(4‐methoxyphenyl)‐1,3‐diphenyl‐1,3a,4,5‐	4‐(4‐methoxyphenyl)‐1,3‐diphenyl‐1,3a,4,5‐	NUM
eurjchem-870	245	2	tetrahydropyrazolo[3,4‐c]pyrazole	tetrahydropyrazolo[3,4‐c]pyrazole	PROPN
eurjchem-870	245	3	(	(	PUNCT
eurjchem-870	245	4	22	22	NUM
eurjchem-870	245	5	)	)	PUNCT
eurjchem-870	245	6	method	method	NOUN
eurjchem-870	245	7	a	a	DET
eurjchem-870	245	8	:	:	PUNCT
eurjchem-870	245	9	a	a	DET
eurjchem-870	245	10	mixture	mixture	NOUN
eurjchem-870	245	11	of	of	ADP
eurjchem-870	245	12	pyrazolone	pyrazolone	NOUN
eurjchem-870	245	13	19	19	NUM
eurjchem-870	245	14	(	(	PUNCT
eurjchem-870	245	15	3.54	3.54	NUM
eurjchem-870	245	16	 	 	SPACE
eurjchem-870	245	17	g	g	NOUN
eurjchem-870	245	18	,	,	PUNCT
eurjchem-870	245	19	0.01	0.01	NUM
eurjchem-870	245	20	 	 	SPACE
eurjchem-870	245	21	mol	mol	NOUN
eurjchem-870	245	22	)	)	PUNCT
eurjchem-870	245	23	,	,	PUNCT
eurjchem-870	245	24	hydrazine	hydrazine	NOUN
eurjchem-870	245	25	hydrate	hydrate	NOUN
eurjchem-870	245	26	(	(	PUNCT
eurjchem-870	245	27	0.5	0.5	NUM
eurjchem-870	245	28	 	 	SPACE
eurjchem-870	245	29	ml	ml	NOUN
eurjchem-870	245	30	,	,	PUNCT
eurjchem-870	245	31	0.01	0.01	NUM
eurjchem-870	245	32	 	 	SPACE
eurjchem-870	245	33	mol	mol	NOUN
eurjchem-870	245	34	)	)	PUNCT
eurjchem-870	245	35	in	in	ADP
eurjchem-870	245	36	ethanol	ethanol	NOUN
eurjchem-870	245	37	(	(	PUNCT
eurjchem-870	245	38	30	30	NUM
eurjchem-870	245	39	 	 	SPACE
eurjchem-870	245	40	ml	ml	NOUN
eurjchem-870	245	41	)	)	PUNCT
eurjchem-870	245	42	was	be	AUX
eurjchem-870	245	43	refluxed	refluxe	VERB
eurjchem-870	245	44	for	for	ADP
eurjchem-870	245	45	2	2	NUM
eurjchem-870	245	46	 	 	SPACE
eurjchem-870	245	47	h.	h.	NOUN
eurjchem-870	246	1	the	the	DET
eurjchem-870	246	2	reaction	reaction	NOUN
eurjchem-870	246	3	mixture	mixture	NOUN
eurjchem-870	246	4	was	be	AUX
eurjchem-870	246	5	then	then	ADV
eurjchem-870	246	6	poured	pour	VERB
eurjchem-870	246	7	onto	onto	ADP
eurjchem-870	246	8	ice	ice	NOUN
eurjchem-870	246	9	:	:	PUNCT
eurjchem-870	246	10	hcl	hcl	PROPN
eurjchem-870	246	11	(	(	PUNCT
eurjchem-870	246	12	1:3	1:3	NUM
eurjchem-870	246	13	)	)	PUNCT
eurjchem-870	246	14	,	,	PUNCT
eurjchem-870	246	15	the	the	DET
eurjchem-870	246	16	solid	solid	ADJ
eurjchem-870	246	17	product	product	NOUN
eurjchem-870	246	18	that	that	PRON
eurjchem-870	246	19	formed	form	VERB
eurjchem-870	246	20	was	be	AUX
eurjchem-870	246	21	filtered	filter	VERB
eurjchem-870	246	22	off	off	ADP
eurjchem-870	246	23	and	and	CCONJ
eurjchem-870	246	24	washed	wash	VERB
eurjchem-870	246	25	with	with	ADP
eurjchem-870	246	26	water	water	NOUN
eurjchem-870	246	27	(	(	PUNCT
eurjchem-870	246	28	4	4	NUM
eurjchem-870	246	29	×	×	NOUN
eurjchem-870	246	30	30	30	NUM
eurjchem-870	246	31	 	 	SPACE
eurjchem-870	246	32	ml	ml	NOUN
eurjchem-870	246	33	)	)	PUNCT
eurjchem-870	246	34	,	,	PUNCT
eurjchem-870	246	35	dried	dry	VERB
eurjchem-870	246	36	and	and	CCONJ
eurjchem-870	246	37	recrystallized	recrystallize	VERB
eurjchem-870	246	38	from	from	ADP
eurjchem-870	246	39	benzene	benzene	NOUN
eurjchem-870	246	40	(	(	PUNCT
eurjchem-870	246	41	scheme	scheme	NOUN
eurjchem-870	246	42	3	3	NUM
eurjchem-870	246	43	)	)	PUNCT
eurjchem-870	246	44	.	.	PUNCT
eurjchem-870	247	1	color	color	NOUN
eurjchem-870	247	2	:	:	PUNCT
eurjchem-870	247	3	purple	purple	ADJ
eurjchem-870	247	4	.	.	PUNCT
eurjchem-870	248	1	yield	yield	NOUN
eurjchem-870	248	2	:	:	PUNCT
eurjchem-870	248	3	98	98	NUM
eurjchem-870	248	4	%	%	NOUN
eurjchem-870	248	5	.	.	PUNCT
eurjchem-870	249	1	m.p	m.p	PROPN
eurjchem-870	249	2	.	.	PROPN
eurjchem-870	249	3	:	:	PUNCT
eurjchem-870	250	1	185‐187	185‐187	NUM
eurjchem-870	250	2	°	°	NUM
eurjchem-870	250	3	c	c	X
eurjchem-870	250	4	.	.	PUNCT
eurjchem-870	251	1	ft‐ir	ft‐ir	NOUN
eurjchem-870	251	2	(	(	PUNCT
eurjchem-870	251	3	kbr	kbr	PROPN
eurjchem-870	251	4	,	,	PUNCT
eurjchem-870	251	5			PROPN
eurjchem-870	251	6	,	,	PUNCT
eurjchem-870	251	7	cm‐1	cm‐1	PROPN
eurjchem-870	251	8	):	):	PUNCT
eurjchem-870	251	9	3623	3623	NUM
eurjchem-870	251	10	(	(	PUNCT
eurjchem-870	251	11	nh	nh	NOUN
eurjchem-870	251	12	)	)	PUNCT
eurjchem-870	251	13	,	,	PUNCT
eurjchem-870	251	14	3056	3056	NUM
eurjchem-870	251	15	,	,	PUNCT
eurjchem-870	251	16	3030	3030	NUM
eurjchem-870	251	17	(	(	PUNCT
eurjchem-870	251	18	ch	ch	NOUN
eurjchem-870	251	19	aromatic	aromatic	NOUN
eurjchem-870	251	20	)	)	PUNCT
eurjchem-870	251	21	,	,	PUNCT
eurjchem-870	251	22	1569	1569	NUM
eurjchem-870	251	23	(	(	PUNCT
eurjchem-870	251	24	c	c	NOUN
eurjchem-870	251	25	=	=	SYM
eurjchem-870	251	26	n	n	NUM
eurjchem-870	251	27	)	)	PUNCT
eurjchem-870	251	28	.	.	PUNCT
eurjchem-870	252	1	1h	1h	NUM
eurjchem-870	252	2	nmr	nmr	NOUN
eurjchem-870	252	3	(	(	PUNCT
eurjchem-870	252	4	300	300	NUM
eurjchem-870	252	5	mhz	mhz	NOUN
eurjchem-870	252	6	,	,	PUNCT
eurjchem-870	252	7	dmso	dmso	NOUN
eurjchem-870	252	8	,	,	PUNCT
eurjchem-870	252	9	δ	δ	PROPN
eurjchem-870	252	10	,	,	PUNCT
eurjchem-870	252	11	ppm	ppm	NUM
eurjchem-870	252	12	):	):	PUNCT
eurjchem-870	252	13	8.12	8.12	NUM
eurjchem-870	252	14	(	(	PUNCT
eurjchem-870	252	15	s	s	PROPN
eurjchem-870	252	16	,	,	PUNCT
eurjchem-870	252	17	1h	1h	NUM
eurjchem-870	252	18	,	,	PUNCT
eurjchem-870	252	19	nh	nh	PROPN
eurjchem-870	252	20	,	,	PUNCT
eurjchem-870	252	21	d2o	d2o	PROPN
eurjchem-870	252	22	exchangeable	exchangeable	ADJ
eurjchem-870	252	23	)	)	PUNCT
eurjchem-870	252	24	,	,	PUNCT
eurjchem-870	252	25	6.76‐8.04	6.76‐8.04	NUM
eurjchem-870	252	26	(	(	PUNCT
eurjchem-870	252	27	m	m	PROPN
eurjchem-870	252	28	,	,	PUNCT
eurjchem-870	252	29	14h	14h	NUM
eurjchem-870	252	30	,	,	PUNCT
eurjchem-870	252	31	arh	arh	PROPN
eurjchem-870	252	32	)	)	PUNCT
eurjchem-870	252	33	,	,	PUNCT
eurjchem-870	252	34	5.13	5.13	NUM
eurjchem-870	252	35	(	(	PUNCT
eurjchem-870	252	36	s	s	PROPN
eurjchem-870	252	37	,	,	PUNCT
eurjchem-870	252	38	1h	1h	NUM
eurjchem-870	252	39	,	,	PUNCT
eurjchem-870	252	40	chc	chc	PROPN
eurjchem-870	252	41	=	=	SYM
eurjchem-870	252	42	n	n	NUM
eurjchem-870	252	43	)	)	PUNCT
eurjchem-870	252	44	,	,	PUNCT
eurjchem-870	252	45	3.82(s	3.82(s	NOUN
eurjchem-870	252	46	,	,	PUNCT
eurjchem-870	252	47	1h	1h	NUM
eurjchem-870	252	48	,	,	PUNCT
eurjchem-870	252	49	ch‐nh	ch‐nh	NOUN
eurjchem-870	252	50	)	)	PUNCT
eurjchem-870	252	51	,	,	PUNCT
eurjchem-870	252	52	3.68	3.68	NUM
eurjchem-870	252	53	(	(	PUNCT
eurjchem-870	252	54	s	s	PROPN
eurjchem-870	252	55	,	,	PUNCT
eurjchem-870	252	56	3h	3h	NUM
eurjchem-870	252	57	,	,	PUNCT
eurjchem-870	252	58	och3	och3	ADJ
eurjchem-870	252	59	)	)	PUNCT
eurjchem-870	252	60	.	.	PUNCT
eurjchem-870	253	1	ms	ms	NOUN
eurjchem-870	253	2	(	(	PUNCT
eurjchem-870	253	3	ei	ei	PROPN
eurjchem-870	253	4	,	,	PUNCT
eurjchem-870	253	5	m	m	PROPN
eurjchem-870	253	6	/	/	SYM
eurjchem-870	253	7	z	z	PROPN
eurjchem-870	253	8	(	(	PUNCT
eurjchem-870	253	9	%	%	NOUN
eurjchem-870	253	10	)	)	PUNCT
eurjchem-870	253	11	):	):	PUNCT
eurjchem-870	253	12	370	370	NUM
eurjchem-870	253	13	(	(	PUNCT
eurjchem-870	253	14	0.5	0.5	NUM
eurjchem-870	253	15	,	,	PUNCT
eurjchem-870	253	16	m+2	m+2	NOUN
eurjchem-870	253	17	)	)	PUNCT
eurjchem-870	253	18	,	,	PUNCT
eurjchem-870	253	19	355	355	NUM
eurjchem-870	253	20	(	(	PUNCT
eurjchem-870	253	21	24.1	24.1	NUM
eurjchem-870	253	22	)	)	PUNCT
eurjchem-870	253	23	,	,	PUNCT
eurjchem-870	253	24	354	354	NUM
eurjchem-870	253	25	(	(	PUNCT
eurjchem-870	253	26	100	100	NUM
eurjchem-870	253	27	)	)	PUNCT
eurjchem-870	253	28	,	,	PUNCT
eurjchem-870	253	29	353	353	NUM
eurjchem-870	253	30	(	(	PUNCT
eurjchem-870	253	31	30.2	30.2	NUM
eurjchem-870	253	32	)	)	PUNCT
eurjchem-870	253	33	,	,	PUNCT
eurjchem-870	253	34	247	247	NUM
eurjchem-870	253	35	(	(	PUNCT
eurjchem-870	253	36	47.5	47.5	NUM
eurjchem-870	253	37	)	)	PUNCT
eurjchem-870	253	38	,	,	PUNCT
eurjchem-870	253	39	221	221	NUM
eurjchem-870	253	40	(	(	PUNCT
eurjchem-870	253	41	33.2	33.2	NUM
eurjchem-870	253	42	)	)	PUNCT
eurjchem-870	253	43	,	,	PUNCT
eurjchem-870	253	44	77	77	NUM
eurjchem-870	253	45	(	(	PUNCT
eurjchem-870	253	46	44.8	44.8	NUM
eurjchem-870	253	47	)	)	PUNCT
eurjchem-870	253	48	.	.	PUNCT
eurjchem-870	254	1	anal	anal	PROPN
eurjchem-870	254	2	.	.	PUNCT
eurjchem-870	254	3	calcd	calcd	NOUN
eurjchem-870	254	4	.	.	PUNCT
eurjchem-870	255	1	for	for	SCONJ
eurjchem-870	255	2	c23h20n4o	c23h20n4o	NOUN
eurjchem-870	255	3	:	:	PUNCT
eurjchem-870	255	4	c	c	X
eurjchem-870	255	5	,	,	PUNCT
eurjchem-870	255	6	74.98	74.98	NUM
eurjchem-870	255	7	;	;	PUNCT
eurjchem-870	255	8	h	h	NOUN
eurjchem-870	255	9	,	,	PUNCT
eurjchem-870	255	10	5.47	5.47	NUM
eurjchem-870	255	11	;	;	PUNCT
eurjchem-870	255	12	n	n	CCONJ
eurjchem-870	255	13	,	,	PUNCT
eurjchem-870	255	14	15.21	15.21	NUM
eurjchem-870	255	15	.	.	PUNCT
eurjchem-870	255	16	found	find	VERB
eurjchem-870	255	17	:	:	PUNCT
eurjchem-870	256	1	c	c	X
eurjchem-870	256	2	,	,	PUNCT
eurjchem-870	256	3	75.14	75.14	NUM
eurjchem-870	256	4	;	;	PUNCT
eurjchem-870	256	5	h	h	NOUN
eurjchem-870	256	6	,	,	PUNCT
eurjchem-870	256	7	5.62	5.62	NUM
eurjchem-870	256	8	;	;	PUNCT
eurjchem-870	256	9	n	n	CCONJ
eurjchem-870	256	10	,	,	PUNCT
eurjchem-870	256	11	15.35	15.35	NUM
eurjchem-870	256	12	%	%	NOUN
eurjchem-870	256	13	.	.	PUNCT
eurjchem-870	257	1	method	method	PROPN
eurjchem-870	257	2	b	b	NOUN
eurjchem-870	257	3	:	:	PUNCT
eurjchem-870	257	4	a	a	DET
eurjchem-870	257	5	mixture	mixture	NOUN
eurjchem-870	257	6	of	of	ADP
eurjchem-870	257	7	pyrazolone	pyrazolone	NOUN
eurjchem-870	257	8	19	19	NUM
eurjchem-870	257	9	(	(	PUNCT
eurjchem-870	257	10	3.54	3.54	NUM
eurjchem-870	257	11	 	 	SPACE
eurjchem-870	257	12	g	g	NOUN
eurjchem-870	257	13	,	,	PUNCT
eurjchem-870	257	14	0.01	0.01	NUM
eurjchem-870	257	15	 	 	SPACE
eurjchem-870	257	16	mol	mol	NOUN
eurjchem-870	257	17	)	)	PUNCT
eurjchem-870	257	18	,	,	PUNCT
eurjchem-870	257	19	hydrazine	hydrazine	NOUN
eurjchem-870	257	20	hydrate	hydrate	NOUN
eurjchem-870	257	21	(	(	PUNCT
eurjchem-870	257	22	0.5	0.5	NUM
eurjchem-870	257	23	 	 	SPACE
eurjchem-870	257	24	ml	ml	NOUN
eurjchem-870	257	25	,	,	PUNCT
eurjchem-870	257	26	0.01	0.01	NUM
eurjchem-870	257	27	 	 	SPACE
eurjchem-870	257	28	mol	mol	NOUN
eurjchem-870	257	29	)	)	PUNCT
eurjchem-870	257	30	was	be	AUX
eurjchem-870	257	31	heated	heat	VERB
eurjchem-870	257	32	under	under	ADP
eurjchem-870	257	33	microwave	microwave	NOUN
eurjchem-870	257	34	irradiation	irradiation	NOUN
eurjchem-870	257	35	for	for	ADP
eurjchem-870	257	36	4	4	NUM
eurjchem-870	257	37	min	min	NOUN
eurjchem-870	257	38	at	at	ADP
eurjchem-870	257	39	power	power	NOUN
eurjchem-870	257	40	360	360	NUM
eurjchem-870	257	41	watt	watt	NOUN
eurjchem-870	257	42	.	.	PUNCT
eurjchem-870	258	1	the	the	DET
eurjchem-870	258	2	separated	separate	VERB
eurjchem-870	258	3	solid	solid	ADJ
eurjchem-870	258	4	was	be	AUX
eurjchem-870	258	5	filtered	filter	VERB
eurjchem-870	258	6	off	off	ADP
eurjchem-870	258	7	and	and	CCONJ
eurjchem-870	258	8	washed	wash	VERB
eurjchem-870	258	9	with	with	ADP
eurjchem-870	258	10	water	water	NOUN
eurjchem-870	258	11	(	(	PUNCT
eurjchem-870	258	12	4	4	NUM
eurjchem-870	258	13	×	×	NOUN
eurjchem-870	258	14	30	30	NUM
eurjchem-870	258	15	 	 	SPACE
eurjchem-870	258	16	ml	ml	NOUN
eurjchem-870	258	17	)	)	PUNCT
eurjchem-870	258	18	,	,	PUNCT
eurjchem-870	258	19	dried	dry	VERB
eurjchem-870	258	20	and	and	CCONJ
eurjchem-870	258	21	recrystallized	recrystallize	VERB
eurjchem-870	258	22	from	from	ADP
eurjchem-870	258	23	benzene	benzene	NOUN
eurjchem-870	258	24	.	.	PUNCT
eurjchem-870	259	1	2.2.17	2.2.17	NUM
eurjchem-870	259	2	.	.	PUNCT
eurjchem-870	260	1	4‐(4‐methoxyphenyl)‐1,3‐diphenyl‐4,5‐dihydro‐1h‐	4‐(4‐methoxyphenyl)‐1,3‐diphenyl‐4,5‐dihydro‐1h‐	NUM
eurjchem-870	260	2	pyrazolo[3,4‐d]pyrimidin‐6(3ah)‐one	pyrazolo[3,4‐d]pyrimidin‐6(3ah)‐one	NOUN
eurjchem-870	260	3	(	(	PUNCT
eurjchem-870	260	4	23	23	NUM
eurjchem-870	260	5	)	)	PUNCT
eurjchem-870	260	6	a	a	DET
eurjchem-870	260	7	mixture	mixture	NOUN
eurjchem-870	260	8	of	of	ADP
eurjchem-870	260	9	pyrazolone	pyrazolone	NOUN
eurjchem-870	260	10	19	19	NUM
eurjchem-870	260	11	(	(	PUNCT
eurjchem-870	260	12	3.54	3.54	NUM
eurjchem-870	260	13	 	 	SPACE
eurjchem-870	260	14	g	g	NOUN
eurjchem-870	260	15	,	,	PUNCT
eurjchem-870	260	16	0.01	0.01	NUM
eurjchem-870	260	17	 	 	SPACE
eurjchem-870	260	18	mol	mol	NOUN
eurjchem-870	260	19	)	)	PUNCT
eurjchem-870	260	20	,	,	PUNCT
eurjchem-870	260	21	and	and	CCONJ
eurjchem-870	260	22	urea	urea	NOUN
eurjchem-870	260	23	(	(	PUNCT
eurjchem-870	260	24	0.6	0.6	NUM
eurjchem-870	260	25	 	 	SPACE
eurjchem-870	260	26	g	g	NOUN
eurjchem-870	260	27	,	,	PUNCT
eurjchem-870	260	28	0.01	0.01	NUM
eurjchem-870	260	29	 	 	SPACE
eurjchem-870	260	30	mol	mol	NOUN
eurjchem-870	260	31	)	)	PUNCT
eurjchem-870	260	32	in	in	ADP
eurjchem-870	260	33	glacial	glacial	ADJ
eurjchem-870	260	34	acetic	acetic	ADJ
eurjchem-870	260	35	acid	acid	NOUN
eurjchem-870	260	36	(	(	PUNCT
eurjchem-870	260	37	20	20	NUM
eurjchem-870	260	38	 	 	SPACE
eurjchem-870	260	39	ml	ml	NOUN
eurjchem-870	260	40	)	)	PUNCT
eurjchem-870	260	41	was	be	AUX
eurjchem-870	260	42	refluxed	refluxe	VERB
eurjchem-870	260	43	for	for	ADP
eurjchem-870	260	44	5	5	NUM
eurjchem-870	260	45	 	 	SPACE
eurjchem-870	260	46	h.	h.	NOUN
eurjchem-870	260	47	the	the	PRON
eurjchem-870	260	48	separated	separate	VERB
eurjchem-870	260	49	solid	solid	ADJ
eurjchem-870	260	50	after	after	ADP
eurjchem-870	260	51	pouring	pour	VERB
eurjchem-870	260	52	on	on	ADP
eurjchem-870	260	53	crushed	crushed	ADJ
eurjchem-870	260	54	ice	ice	NOUN
eurjchem-870	260	55	was	be	AUX
eurjchem-870	260	56	filtered	filter	VERB
eurjchem-870	260	57	off	off	ADP
eurjchem-870	260	58	,	,	PUNCT
eurjchem-870	260	59	washed	wash	VERB
eurjchem-870	260	60	with	with	ADP
eurjchem-870	260	61	water	water	NOUN
eurjchem-870	260	62	,	,	PUNCT
eurjchem-870	260	63	dried	dry	VERB
eurjchem-870	260	64	and	and	CCONJ
eurjchem-870	260	65	crystallized	crystallize	VERB
eurjchem-870	260	66	from	from	ADP
eurjchem-870	260	67	benzene	benzene	NOUN
eurjchem-870	260	68	(	(	PUNCT
eurjchem-870	260	69	scheme	scheme	NOUN
eurjchem-870	260	70	3	3	NUM
eurjchem-870	260	71	)	)	PUNCT
eurjchem-870	260	72	.	.	PUNCT
eurjchem-870	261	1	color	color	NOUN
eurjchem-870	261	2	:	:	PUNCT
eurjchem-870	261	3	yellow	yellow	ADJ
eurjchem-870	261	4	.	.	PUNCT
eurjchem-870	262	1	yield	yield	NOUN
eurjchem-870	262	2	:	:	PUNCT
eurjchem-870	262	3	45	45	NUM
eurjchem-870	262	4	%	%	NOUN
eurjchem-870	262	5	.	.	PUNCT
eurjchem-870	263	1	m.p	m.p	PROPN
eurjchem-870	263	2	.	.	PROPN
eurjchem-870	263	3	:	:	PUNCT
eurjchem-870	264	1	143‐145	143‐145	PROPN
eurjchem-870	264	2	°	°	ADP
eurjchem-870	264	3	c	c	X
eurjchem-870	264	4	.	.	PUNCT
eurjchem-870	265	1	ft‐ir	ft‐ir	NOUN
eurjchem-870	265	2	(	(	PUNCT
eurjchem-870	265	3	kbr	kbr	PROPN
eurjchem-870	265	4	,	,	PUNCT
eurjchem-870	265	5			PROPN
eurjchem-870	265	6	,	,	PUNCT
eurjchem-870	265	7	cm‐1	cm‐1	PROPN
eurjchem-870	265	8	):	):	PUNCT
eurjchem-870	265	9	3625	3625	NUM
eurjchem-870	265	10	(	(	PUNCT
eurjchem-870	265	11	nh	nh	NOUN
eurjchem-870	265	12	)	)	PUNCT
eurjchem-870	265	13	,	,	PUNCT
eurjchem-870	265	14	1723	1723	NUM
eurjchem-870	265	15	(	(	PUNCT
eurjchem-870	265	16	c	c	NOUN
eurjchem-870	265	17	=	=	NOUN
eurjchem-870	265	18	o	o	NOUN
eurjchem-870	265	19	)	)	PUNCT
eurjchem-870	265	20	,	,	PUNCT
eurjchem-870	265	21	1602	1602	NUM
eurjchem-870	265	22	(	(	PUNCT
eurjchem-870	265	23	c	c	NOUN
eurjchem-870	265	24	=	=	SYM
eurjchem-870	265	25	n	n	NUM
eurjchem-870	265	26	)	)	PUNCT
eurjchem-870	265	27	.	.	PUNCT
eurjchem-870	266	1	1h	1h	NUM
eurjchem-870	266	2	nmr	nmr	NOUN
eurjchem-870	266	3	(	(	PUNCT
eurjchem-870	266	4	300	300	NUM
eurjchem-870	266	5	mhz	mhz	NOUN
eurjchem-870	266	6	,	,	PUNCT
eurjchem-870	266	7	cdcl3	cdcl3	PROPN
eurjchem-870	266	8	,	,	PUNCT
eurjchem-870	266	9	δ	δ	PROPN
eurjchem-870	266	10	,	,	PUNCT
eurjchem-870	266	11	ppm	ppm	NOUN
eurjchem-870	266	12	):	):	PUNCT
eurjchem-870	266	13	6.76‐8.07	6.76‐8.07	NUM
eurjchem-870	266	14	(	(	PUNCT
eurjchem-870	266	15	m	m	PROPN
eurjchem-870	266	16	,	,	PUNCT
eurjchem-870	266	17	14h	14h	NUM
eurjchem-870	266	18	,	,	PUNCT
eurjchem-870	266	19	arh	arh	PROPN
eurjchem-870	266	20	)	)	PUNCT
eurjchem-870	266	21	,	,	PUNCT
eurjchem-870	266	22	5.17	5.17	NUM
eurjchem-870	266	23	(	(	PUNCT
eurjchem-870	266	24	s	s	PROPN
eurjchem-870	266	25	,	,	PUNCT
eurjchem-870	266	26	1h	1h	NUM
eurjchem-870	266	27	,	,	PUNCT
eurjchem-870	266	28	chnh	chnh	NOUN
eurjchem-870	266	29	)	)	PUNCT
eurjchem-870	266	30	,	,	PUNCT
eurjchem-870	266	31	3.91	3.91	NUM
eurjchem-870	266	32	(	(	PUNCT
eurjchem-870	266	33	s	s	PROPN
eurjchem-870	266	34	,	,	PUNCT
eurjchem-870	266	35	3h	3h	NUM
eurjchem-870	266	36	,	,	PUNCT
eurjchem-870	266	37	och3	och3	ADJ
eurjchem-870	266	38	)	)	PUNCT
eurjchem-870	266	39	,	,	PUNCT
eurjchem-870	266	40	3.78	3.78	NUM
eurjchem-870	266	41	(	(	PUNCT
eurjchem-870	266	42	s	s	PROPN
eurjchem-870	266	43	,	,	PUNCT
eurjchem-870	266	44	1h	1h	NUM
eurjchem-870	266	45	,	,	PUNCT
eurjchem-870	266	46	nh	nh	PROPN
eurjchem-870	266	47	d2o	d2o	PROPN
eurjchem-870	266	48	exchangeable	exchangeable	ADJ
eurjchem-870	266	49	)	)	PUNCT
eurjchem-870	266	50	,	,	PUNCT
eurjchem-870	266	51	3.72	3.72	NUM
eurjchem-870	266	52	(	(	PUNCT
eurjchem-870	266	53	s	s	PROPN
eurjchem-870	266	54	,	,	PUNCT
eurjchem-870	266	55	1h	1h	NUM
eurjchem-870	266	56	,	,	PUNCT
eurjchem-870	266	57	ch	ch	NOUN
eurjchem-870	266	58	)	)	PUNCT
eurjchem-870	266	59	.	.	PUNCT
eurjchem-870	267	1	ms	ms	NOUN
eurjchem-870	267	2	(	(	PUNCT
eurjchem-870	267	3	ei	ei	PROPN
eurjchem-870	267	4	,	,	PUNCT
eurjchem-870	267	5	m	m	PROPN
eurjchem-870	267	6	/	/	SYM
eurjchem-870	267	7	z	z	PROPN
eurjchem-870	267	8	(	(	PUNCT
eurjchem-870	267	9	%	%	NOUN
eurjchem-870	267	10	)	)	PUNCT
eurjchem-870	267	11	):	):	PUNCT
eurjchem-870	267	12	355	355	NUM
eurjchem-870	267	13	(	(	PUNCT
eurjchem-870	267	14	12.4	12.4	NUM
eurjchem-870	267	15	,	,	PUNCT
eurjchem-870	267	16	[	[	X
eurjchem-870	267	17	m‐chno·]+	m‐chno·]+	ADJ
eurjchem-870	267	18	)	)	PUNCT
eurjchem-870	267	19	,	,	PUNCT
eurjchem-870	267	20	247	247	NUM
eurjchem-870	267	21	(	(	PUNCT
eurjchem-870	267	22	20.7	20.7	NUM
eurjchem-870	267	23	)	)	PUNCT
eurjchem-870	267	24	,	,	PUNCT
eurjchem-870	267	25	236	236	NUM
eurjchem-870	267	26	(	(	PUNCT
eurjchem-870	267	27	59.9	59.9	NUM
eurjchem-870	267	28	)	)	PUNCT
eurjchem-870	267	29	,	,	PUNCT
eurjchem-870	267	30	77	77	NUM
eurjchem-870	267	31	(	(	PUNCT
eurjchem-870	267	32	100	100	NUM
eurjchem-870	267	33	)	)	PUNCT
eurjchem-870	267	34	,	,	PUNCT
eurjchem-870	267	35	78	78	NUM
eurjchem-870	267	36	(	(	PUNCT
eurjchem-870	267	37	9.1	9.1	NUM
eurjchem-870	267	38	)	)	PUNCT
eurjchem-870	267	39	.	.	PUNCT
eurjchem-870	268	1	anal	anal	PROPN
eurjchem-870	268	2	.	.	PUNCT
eurjchem-870	268	3	calcd	calcd	NOUN
eurjchem-870	268	4	.	.	PUNCT
eurjchem-870	269	1	for	for	ADP
eurjchem-870	269	2	c24h20n4o2	c24h20n4o2	ADJ
eurjchem-870	269	3	:	:	PUNCT
eurjchem-870	269	4	c	c	X
eurjchem-870	269	5	,	,	PUNCT
eurjchem-870	269	6	72.71	72.71	NUM
eurjchem-870	269	7	,	,	PUNCT
eurjchem-870	269	8	h	h	NOUN
eurjchem-870	269	9	;	;	PUNCT
eurjchem-870	269	10	5.08	5.08	NUM
eurjchem-870	269	11	,	,	PUNCT
eurjchem-870	269	12	n	n	CCONJ
eurjchem-870	269	13	;	;	PUNCT
eurjchem-870	269	14	14.13	14.13	NUM
eurjchem-870	269	15	.	.	PUNCT
eurjchem-870	269	16	found	find	VERB
eurjchem-870	269	17	:	:	PUNCT
eurjchem-870	270	1	c	c	X
eurjchem-870	270	2	,	,	PUNCT
eurjchem-870	270	3	72.90	72.90	NUM
eurjchem-870	270	4	;	;	PUNCT
eurjchem-870	270	5	h	h	NOUN
eurjchem-870	270	6	,	,	PUNCT
eurjchem-870	270	7	5.21	5.21	NUM
eurjchem-870	270	8	;	;	PUNCT
eurjchem-870	270	9	n	n	CCONJ
eurjchem-870	270	10	,	,	PUNCT
eurjchem-870	270	11	14.31	14.31	NUM
eurjchem-870	270	12	%	%	NOUN
eurjchem-870	270	13	.	.	PUNCT
eurjchem-870	271	1	2.2.18	2.2.18	NUM
eurjchem-870	271	2	.	.	NOUN
eurjchem-870	271	3	1‐(4‐(4‐methoxyphenyl)‐1,3‐diphenyl‐1,4‐	1‐(4‐(4‐methoxyphenyl)‐1,3‐diphenyl‐1,4‐	NUM
eurjchem-870	271	4	dihydropyrazolo[4,3‐e][1,3]thiazin‐6‐yl)thiourea	dihydropyrazolo[4,3‐e][1,3]thiazin‐6‐yl)thiourea	PROPN
eurjchem-870	271	5	(	(	PUNCT
eurjchem-870	271	6	24	24	NUM
eurjchem-870	271	7	)	)	PUNCT
eurjchem-870	271	8	a	a	DET
eurjchem-870	271	9	mixture	mixture	NOUN
eurjchem-870	271	10	of	of	ADP
eurjchem-870	271	11	pyrazolone	pyrazolone	NOUN
eurjchem-870	271	12	19	19	NUM
eurjchem-870	271	13	(	(	PUNCT
eurjchem-870	271	14	3.54	3.54	NUM
eurjchem-870	271	15	 	 	SPACE
eurjchem-870	271	16	g	g	NOUN
eurjchem-870	271	17	,	,	PUNCT
eurjchem-870	271	18	0.01	0.01	NUM
eurjchem-870	271	19	 	 	SPACE
eurjchem-870	271	20	mol	mol	NOUN
eurjchem-870	271	21	)	)	PUNCT
eurjchem-870	271	22	and	and	CCONJ
eurjchem-870	271	23	thiourea	thiourea	NOUN
eurjchem-870	271	24	(	(	PUNCT
eurjchem-870	271	25	0.76	0.76	NUM
eurjchem-870	271	26	 	 	SPACE
eurjchem-870	271	27	g	g	NOUN
eurjchem-870	271	28	,	,	PUNCT
eurjchem-870	271	29	0.01	0.01	NUM
eurjchem-870	271	30	 	 	SPACE
eurjchem-870	271	31	mol	mol	NOUN
eurjchem-870	271	32	)	)	PUNCT
eurjchem-870	271	33	in	in	ADP
eurjchem-870	271	34	glacial	glacial	ADJ
eurjchem-870	271	35	acetic	acetic	ADJ
eurjchem-870	271	36	acid	acid	NOUN
eurjchem-870	271	37	(	(	PUNCT
eurjchem-870	271	38	20	20	NUM
eurjchem-870	271	39	 	 	SPACE
eurjchem-870	271	40	ml	ml	NOUN
eurjchem-870	271	41	)	)	PUNCT
eurjchem-870	271	42	was	be	AUX
eurjchem-870	271	43	refluxed	refluxe	VERB
eurjchem-870	271	44	for	for	ADP
eurjchem-870	271	45	5	5	NUM
eurjchem-870	271	46	 	 	SPACE
eurjchem-870	271	47	h.	h.	NOUN
eurjchem-870	272	1	the	the	DET
eurjchem-870	272	2	reaction	reaction	NOUN
eurjchem-870	272	3	mixture	mixture	NOUN
eurjchem-870	272	4	was	be	AUX
eurjchem-870	272	5	poured	pour	VERB
eurjchem-870	272	6	on	on	ADP
eurjchem-870	272	7	crushed	crush	VERB
eurjchem-870	272	8	ice	ice	NOUN
eurjchem-870	272	9	to	to	PART
eurjchem-870	272	10	give	give	VERB
eurjchem-870	272	11	a	a	DET
eurjchem-870	272	12	yellow	yellow	ADJ
eurjchem-870	272	13	solid	solid	NOUN
eurjchem-870	272	14	which	which	PRON
eurjchem-870	272	15	was	be	AUX
eurjchem-870	272	16	filtered	filter	VERB
eurjchem-870	272	17	off	off	ADP
eurjchem-870	272	18	,	,	PUNCT
eurjchem-870	272	19	washed	wash	VERB
eurjchem-870	272	20	with	with	ADP
eurjchem-870	272	21	water	water	NOUN
eurjchem-870	272	22	,	,	PUNCT
eurjchem-870	272	23	dried	dry	VERB
eurjchem-870	272	24	and	and	CCONJ
eurjchem-870	272	25	crystallized	crystallize	VERB
eurjchem-870	272	26	from	from	ADP
eurjchem-870	272	27	benzene	benzene	NOUN
eurjchem-870	272	28	:	:	PUNCT
eurjchem-870	272	29	ethanol	ethanol	NOUN
eurjchem-870	272	30	(	(	PUNCT
eurjchem-870	272	31	1:1	1:1	NUM
eurjchem-870	272	32	)	)	PUNCT
eurjchem-870	272	33	(	(	PUNCT
eurjchem-870	272	34	scheme	scheme	NOUN
eurjchem-870	272	35	3	3	NUM
eurjchem-870	272	36	)	)	PUNCT
eurjchem-870	272	37	.	.	PUNCT
eurjchem-870	273	1	color	color	NOUN
eurjchem-870	273	2	:	:	PUNCT
eurjchem-870	273	3	yellow	yellow	ADJ
eurjchem-870	273	4	.	.	PUNCT
eurjchem-870	274	1	yield	yield	NOUN
eurjchem-870	274	2	:	:	PUNCT
eurjchem-870	274	3	60.15	60.15	NUM
eurjchem-870	274	4	%	%	NOUN
eurjchem-870	274	5	.	.	PUNCT
eurjchem-870	275	1	m.p	m.p	PROPN
eurjchem-870	275	2	.	.	PROPN
eurjchem-870	275	3	:	:	PUNCT
eurjchem-870	276	1	205‐207	205‐207	PROPN
eurjchem-870	276	2	°	°	SYM
eurjchem-870	276	3	c	c	NOUN
eurjchem-870	276	4	.	.	PUNCT
eurjchem-870	277	1	ft‐ir	ft‐ir	NOUN
eurjchem-870	277	2	(	(	PUNCT
eurjchem-870	277	3	kbr	kbr	PROPN
eurjchem-870	277	4	,	,	PUNCT
eurjchem-870	277	5			PROPN
eurjchem-870	277	6	,	,	PUNCT
eurjchem-870	277	7	cm‐1	cm‐1	PROPN
eurjchem-870	277	8	):	):	PUNCT
eurjchem-870	277	9	3380	3380	NUM
eurjchem-870	277	10	,	,	PUNCT
eurjchem-870	277	11	3276	3276	NUM
eurjchem-870	277	12	(	(	PUNCT
eurjchem-870	277	13	nh	nh	PROPN
eurjchem-870	277	14	,	,	PUNCT
eurjchem-870	277	15	nh2	nh2	PROPN
eurjchem-870	277	16	)	)	PUNCT
eurjchem-870	277	17	,	,	PUNCT
eurjchem-870	277	18	1614	1614	NUM
eurjchem-870	277	19	(	(	PUNCT
eurjchem-870	277	20	c	c	NOUN
eurjchem-870	277	21	=	=	SYM
eurjchem-870	277	22	n	n	NUM
eurjchem-870	277	23	)	)	PUNCT
eurjchem-870	277	24	.	.	PUNCT
eurjchem-870	278	1	1h	1h	NUM
eurjchem-870	278	2	nmr	nmr	NOUN
eurjchem-870	278	3	(	(	PUNCT
eurjchem-870	278	4	300	300	NUM
eurjchem-870	278	5	mhz	mhz	NOUN
eurjchem-870	278	6	,	,	PUNCT
eurjchem-870	278	7	cdcl3	cdcl3	PROPN
eurjchem-870	278	8	,	,	PUNCT
eurjchem-870	278	9	δ	δ	PROPN
eurjchem-870	278	10	,	,	PUNCT
eurjchem-870	278	11	ppm	ppm	NUM
eurjchem-870	278	12	):	):	PUNCT
eurjchem-870	278	13	6.79‐7.96	6.79‐7.96	NUM
eurjchem-870	278	14	(	(	PUNCT
eurjchem-870	278	15	m	m	PROPN
eurjchem-870	278	16	,	,	PUNCT
eurjchem-870	278	17	14h	14h	NUM
eurjchem-870	278	18	,	,	PUNCT
eurjchem-870	278	19	arh	arh	PROPN
eurjchem-870	278	20	)	)	PUNCT
eurjchem-870	278	21	,	,	PUNCT
eurjchem-870	278	22	5.16	5.16	NUM
eurjchem-870	278	23	(	(	PUNCT
eurjchem-870	278	24	s	s	PROPN
eurjchem-870	278	25	,	,	PUNCT
eurjchem-870	278	26	1h	1h	NUM
eurjchem-870	278	27	,	,	PUNCT
eurjchem-870	278	28	benzilic	benzilic	NOUN
eurjchem-870	278	29	)	)	PUNCT
eurjchem-870	278	30	,	,	PUNCT
eurjchem-870	278	31	3.69	3.69	NUM
eurjchem-870	278	32	(	(	PUNCT
eurjchem-870	278	33	s	s	PROPN
eurjchem-870	278	34	,	,	PUNCT
eurjchem-870	278	35	3h	3h	NUM
eurjchem-870	278	36	,	,	PUNCT
eurjchem-870	278	37	och3	och3	ADJ
eurjchem-870	278	38	)	)	PUNCT
eurjchem-870	278	39	,	,	PUNCT
eurjchem-870	278	40	3.08	3.08	NUM
eurjchem-870	278	41	(	(	PUNCT
eurjchem-870	278	42	s	s	PROPN
eurjchem-870	278	43	,	,	PUNCT
eurjchem-870	278	44	3h	3h	NUM
eurjchem-870	278	45	,	,	PUNCT
eurjchem-870	278	46	nh	nh	PROPN
eurjchem-870	278	47	,	,	PUNCT
eurjchem-870	278	48	nh2	nh2	PROPN
eurjchem-870	278	49	d2o	d2o	PROPN
eurjchem-870	278	50	exchangeable	exchangeable	ADJ
eurjchem-870	278	51	)	)	PUNCT
eurjchem-870	278	52	.	.	PUNCT
eurjchem-870	279	1	ms	ms	NOUN
eurjchem-870	279	2	(	(	PUNCT
eurjchem-870	279	3	ei	ei	PROPN
eurjchem-870	279	4	,	,	PUNCT
eurjchem-870	279	5	m	m	PROPN
eurjchem-870	279	6	/	/	SYM
eurjchem-870	279	7	z	z	PROPN
eurjchem-870	279	8	(	(	PUNCT
eurjchem-870	279	9	%	%	NOUN
eurjchem-870	279	10	)	)	PUNCT
eurjchem-870	279	11	):	):	PUNCT
eurjchem-870	279	12	471	471	NUM
eurjchem-870	279	13	(	(	PUNCT
eurjchem-870	279	14	23.3	23.3	NUM
eurjchem-870	279	15	,	,	PUNCT
eurjchem-870	279	16	m+	m+	NOUN
eurjchem-870	279	17	·	·	PUNCT
eurjchem-870	279	18	)	)	PUNCT
eurjchem-870	279	19	,	,	PUNCT
eurjchem-870	279	20	236	236	NUM
eurjchem-870	279	21	(	(	PUNCT
eurjchem-870	279	22	26.7	26.7	NUM
eurjchem-870	279	23	)	)	PUNCT
eurjchem-870	279	24	,	,	PUNCT
eurjchem-870	279	25	235	235	NUM
eurjchem-870	279	26	(	(	PUNCT
eurjchem-870	279	27	30.0	30.0	NUM
eurjchem-870	279	28	)	)	PUNCT
eurjchem-870	279	29	,	,	PUNCT
eurjchem-870	279	30	91	91	NUM
eurjchem-870	279	31	(	(	PUNCT
eurjchem-870	279	32	30.0	30.0	NUM
eurjchem-870	279	33	)	)	PUNCT
eurjchem-870	279	34	,	,	PUNCT
eurjchem-870	279	35	77	77	NUM
eurjchem-870	279	36	(	(	PUNCT
eurjchem-870	279	37	100	100	NUM
eurjchem-870	279	38	)	)	PUNCT
eurjchem-870	279	39	.	.	PUNCT
eurjchem-870	280	1	anal	anal	PROPN
eurjchem-870	280	2	.	.	PUNCT
eurjchem-870	280	3	calcd	calcd	NOUN
eurjchem-870	280	4	.	.	PUNCT
eurjchem-870	281	1	for	for	ADP
eurjchem-870	281	2	c25h21n5os2	c25h21n5os2	NOUN
eurjchem-870	281	3	:	:	PUNCT
eurjchem-870	281	4	c	c	X
eurjchem-870	281	5	,	,	PUNCT
eurjchem-870	281	6	63.67	63.67	NUM
eurjchem-870	281	7	;	;	PUNCT
eurjchem-870	281	8	h	h	NOUN
eurjchem-870	281	9	,	,	PUNCT
eurjchem-870	281	10	4.49	4.49	NUM
eurjchem-870	281	11	;	;	PUNCT
eurjchem-870	281	12	n	n	CCONJ
eurjchem-870	281	13	,	,	PUNCT
eurjchem-870	281	14	14.85	14.85	NUM
eurjchem-870	281	15	;	;	PUNCT
eurjchem-870	281	16	s	s	NOUN
eurjchem-870	281	17	,	,	PUNCT
eurjchem-870	281	18	13.60	13.60	NUM
eurjchem-870	281	19	.	.	PUNCT
eurjchem-870	281	20	found	find	VERB
eurjchem-870	281	21	:	:	PUNCT
eurjchem-870	282	1	c	c	X
eurjchem-870	282	2	,	,	PUNCT
eurjchem-870	282	3	63.82	63.82	NUM
eurjchem-870	282	4	;	;	PUNCT
eurjchem-870	282	5	h	h	X
eurjchem-870	282	6	,	,	PUNCT
eurjchem-870	282	7	4.60	4.60	NUM
eurjchem-870	282	8	;	;	PUNCT
eurjchem-870	282	9	n	n	CCONJ
eurjchem-870	282	10	,	,	PUNCT
eurjchem-870	282	11	14.93	14.93	NUM
eurjchem-870	282	12	;	;	PUNCT
eurjchem-870	282	13	s	s	X
eurjchem-870	282	14	,	,	PUNCT
eurjchem-870	282	15	13.81	13.81	NUM
eurjchem-870	282	16	%	%	NOUN
eurjchem-870	282	17	.	.	PUNCT
eurjchem-870	283	1	2.2.19	2.2.19	NUM
eurjchem-870	283	2	.	.	PUNCT
eurjchem-870	284	1	3‐(4‐methoxyphenyl)‐4,6‐diphenyl‐3a,6‐dihydro‐3h‐	3‐(4‐methoxyphenyl)‐4,6‐diphenyl‐3a,6‐dihydro‐3h‐	ADJ
eurjchem-870	284	2	pyrazolo[3,4‐c]isoxazole	pyrazolo[3,4‐c]isoxazole	NOUN
eurjchem-870	284	3	(	(	PUNCT
eurjchem-870	284	4	25	25	NUM
eurjchem-870	284	5	)	)	PUNCT
eurjchem-870	284	6	a	a	DET
eurjchem-870	284	7	mixture	mixture	NOUN
eurjchem-870	284	8	of	of	ADP
eurjchem-870	284	9	pyrazolone	pyrazolone	NOUN
eurjchem-870	284	10	19	19	NUM
eurjchem-870	284	11	(	(	PUNCT
eurjchem-870	284	12	3.54	3.54	NUM
eurjchem-870	284	13	 	 	SPACE
eurjchem-870	284	14	g	g	NOUN
eurjchem-870	284	15	,	,	PUNCT
eurjchem-870	284	16	0.01	0.01	NUM
eurjchem-870	284	17	 	 	SPACE
eurjchem-870	284	18	mol	mol	NOUN
eurjchem-870	284	19	)	)	PUNCT
eurjchem-870	284	20	and	and	CCONJ
eurjchem-870	284	21	hydroxylamine	hydroxylamine	ADJ
eurjchem-870	284	22	hydrochloride	hydrochloride	NOUN
eurjchem-870	284	23	(	(	PUNCT
eurjchem-870	284	24	0.69	0.69	NUM
eurjchem-870	284	25	 	 	SPACE
eurjchem-870	284	26	g	g	NOUN
eurjchem-870	284	27	,	,	PUNCT
eurjchem-870	284	28	0.01	0.01	NUM
eurjchem-870	284	29	 	 	SPACE
eurjchem-870	284	30	mol	mol	NOUN
eurjchem-870	284	31	)	)	PUNCT
eurjchem-870	284	32	in	in	ADP
eurjchem-870	284	33	presence	presence	NOUN
eurjchem-870	284	34	of	of	ADP
eurjchem-870	284	35	pyridine	pyridine	NOUN
eurjchem-870	284	36	(	(	PUNCT
eurjchem-870	284	37	10	10	NUM
eurjchem-870	284	38	 	 	SPACE
eurjchem-870	284	39	ml	ml	NOUN
eurjchem-870	284	40	)	)	PUNCT
eurjchem-870	284	41	was	be	AUX
eurjchem-870	284	42	refluxed	refluxe	VERB
eurjchem-870	284	43	for	for	ADP
eurjchem-870	284	44	6	6	NUM
eurjchem-870	284	45	 	 	SPACE
eurjchem-870	284	46	h	h	NOUN
eurjchem-870	284	47	,	,	PUNCT
eurjchem-870	284	48	the	the	PRON
eurjchem-870	284	49	separated	separate	VERB
eurjchem-870	284	50	solid	solid	ADJ
eurjchem-870	284	51	after	after	SCONJ
eurjchem-870	284	52	cooling	cool	VERB
eurjchem-870	284	53	was	be	AUX
eurjchem-870	284	54	filtered	filter	VERB
eurjchem-870	284	55	off	off	ADP
eurjchem-870	284	56	,	,	PUNCT
eurjchem-870	284	57	dried	dry	VERB
eurjchem-870	284	58	and	and	CCONJ
eurjchem-870	284	59	crystallized	crystallize	VERB
eurjchem-870	284	60	from	from	ADP
eurjchem-870	284	61	petroleum	petroleum	NOUN
eurjchem-870	284	62	ether	ether	NOUN
eurjchem-870	284	63	80‐100	80‐100	NOUN
eurjchem-870	285	1	°	°	PROPN
eurjchem-870	285	2	c	c	NOUN
eurjchem-870	285	3	(	(	PUNCT
eurjchem-870	285	4	scheme	scheme	NOUN
eurjchem-870	285	5	4	4	NUM
eurjchem-870	285	6	)	)	PUNCT
eurjchem-870	285	7	.	.	PUNCT
eurjchem-870	286	1	color	color	NOUN
eurjchem-870	286	2	:	:	PUNCT
eurjchem-870	286	3	pale	pale	ADJ
eurjchem-870	286	4	yellow	yellow	ADJ
eurjchem-870	286	5	.	.	PUNCT
eurjchem-870	287	1	yield	yield	NOUN
eurjchem-870	287	2	:	:	PUNCT
eurjchem-870	287	3	70.1	70.1	NUM
eurjchem-870	287	4	%	%	NOUN
eurjchem-870	287	5	.	.	PUNCT
eurjchem-870	288	1	m.p	m.p	PROPN
eurjchem-870	288	2	.	.	PROPN
eurjchem-870	288	3	:	:	PUNCT
eurjchem-870	289	1	112‐115	112‐115	PROPN
eurjchem-870	289	2	°	°	SYM
eurjchem-870	289	3	c	c	PROPN
eurjchem-870	289	4	.	.	PUNCT
eurjchem-870	290	1	ft‐ir	ft‐ir	NOUN
eurjchem-870	290	2	(	(	PUNCT
eurjchem-870	290	3	kbr	kbr	PROPN
eurjchem-870	290	4	,	,	PUNCT
eurjchem-870	290	5			PROPN
eurjchem-870	290	6	,	,	PUNCT
eurjchem-870	290	7	cm‐1	cm‐1	PROPN
eurjchem-870	290	8	):	):	PUNCT
eurjchem-870	290	9	3058	3058	NUM
eurjchem-870	290	10	(	(	PUNCT
eurjchem-870	290	11	ch	ch	NOUN
eurjchem-870	290	12	aromatic	aromatic	NOUN
eurjchem-870	290	13	)	)	PUNCT
eurjchem-870	290	14	,	,	PUNCT
eurjchem-870	290	15	2952	2952	NUM
eurjchem-870	290	16	(	(	PUNCT
eurjchem-870	290	17	ch	ch	NOUN
eurjchem-870	290	18	aliphatic	aliphatic	PROPN
eurjchem-870	290	19	)	)	PUNCT
eurjchem-870	290	20	,	,	PUNCT
eurjchem-870	290	21	1600	1600	NUM
eurjchem-870	290	22	(	(	PUNCT
eurjchem-870	290	23	c	c	NOUN
eurjchem-870	290	24	=	=	SYM
eurjchem-870	290	25	n	n	NUM
eurjchem-870	290	26	)	)	PUNCT
eurjchem-870	290	27	.	.	PUNCT
eurjchem-870	291	1	1h	1h	NUM
eurjchem-870	291	2	nmr	nmr	NOUN
eurjchem-870	291	3	(	(	PUNCT
eurjchem-870	291	4	300	300	NUM
eurjchem-870	291	5	mhz	mhz	NOUN
eurjchem-870	291	6	,	,	PUNCT
eurjchem-870	291	7	cdcl3	cdcl3	PROPN
eurjchem-870	291	8	,	,	PUNCT
eurjchem-870	291	9	δ	δ	PROPN
eurjchem-870	291	10	,	,	PUNCT
eurjchem-870	291	11	ppm	ppm	NOUN
eurjchem-870	291	12	):	):	PUNCT
eurjchem-870	291	13	6.74‐8.55	6.74‐8.55	NUM
eurjchem-870	291	14	(	(	PUNCT
eurjchem-870	291	15	m	m	PROPN
eurjchem-870	291	16	,	,	PUNCT
eurjchem-870	291	17	14h	14h	NUM
eurjchem-870	291	18	,	,	PUNCT
eurjchem-870	291	19	arh	arh	PROPN
eurjchem-870	291	20	)	)	PUNCT
eurjchem-870	291	21	,	,	PUNCT
eurjchem-870	291	22	3.91	3.91	NUM
eurjchem-870	291	23	(	(	PUNCT
eurjchem-870	291	24	d	d	PROPN
eurjchem-870	291	25	,	,	PUNCT
eurjchem-870	291	26	1h	1h	NUM
eurjchem-870	291	27	,	,	PUNCT
eurjchem-870	291	28	ch‐o	ch‐o	NOUN
eurjchem-870	291	29	)	)	PUNCT
eurjchem-870	291	30	,	,	PUNCT
eurjchem-870	291	31	3.83	3.83	NUM
eurjchem-870	291	32	(	(	PUNCT
eurjchem-870	291	33	s	s	PROPN
eurjchem-870	291	34	,	,	PUNCT
eurjchem-870	291	35	3h	3h	NUM
eurjchem-870	291	36	,	,	PUNCT
eurjchem-870	291	37	och3	och3	ADJ
eurjchem-870	291	38	)	)	PUNCT
eurjchem-870	291	39	,	,	PUNCT
eurjchem-870	291	40	2.85	2.85	NUM
eurjchem-870	291	41	(	(	PUNCT
eurjchem-870	291	42	d	d	PROPN
eurjchem-870	291	43	,	,	PUNCT
eurjchem-870	291	44	1h	1h	NUM
eurjchem-870	291	45	,	,	PUNCT
eurjchem-870	291	46	ch‐c	ch‐c	NOUN
eurjchem-870	291	47	=	=	NOUN
eurjchem-870	291	48	n	n	NUM
eurjchem-870	291	49	)	)	PUNCT
eurjchem-870	291	50	.	.	PUNCT
eurjchem-870	292	1	ms	ms	NOUN
eurjchem-870	292	2	(	(	PUNCT
eurjchem-870	292	3	ei	ei	PROPN
eurjchem-870	292	4	,	,	PUNCT
eurjchem-870	292	5	m	m	PROPN
eurjchem-870	292	6	/	/	SYM
eurjchem-870	292	7	z	z	PROPN
eurjchem-870	292	8	(	(	PUNCT
eurjchem-870	292	9	%	%	NOUN
eurjchem-870	292	10	)	)	PUNCT
eurjchem-870	292	11	):	):	PUNCT
eurjchem-870	292	12	354	354	NUM
eurjchem-870	292	13	(	(	PUNCT
eurjchem-870	292	14	42	42	NUM
eurjchem-870	292	15	,	,	PUNCT
eurjchem-870	292	16	[	[	X
eurjchem-870	292	17	m‐	m‐	VERB
eurjchem-870	292	18	ch3o·]+	ch3o·]+	PROPN
eurjchem-870	292	19	)	)	PUNCT
eurjchem-870	292	20	,	,	PUNCT
eurjchem-870	292	21	247	247	NUM
eurjchem-870	292	22	(	(	PUNCT
eurjchem-870	292	23	17.4	17.4	NUM
eurjchem-870	292	24	)	)	PUNCT
eurjchem-870	292	25	,	,	PUNCT
eurjchem-870	292	26	235	235	NUM
eurjchem-870	292	27	(	(	PUNCT
eurjchem-870	292	28	49.9	49.9	NUM
eurjchem-870	292	29	)	)	PUNCT
eurjchem-870	292	30	,	,	PUNCT
eurjchem-870	292	31	77	77	NUM
eurjchem-870	292	32	(	(	PUNCT
eurjchem-870	292	33	100	100	NUM
eurjchem-870	292	34	)	)	PUNCT
eurjchem-870	292	35	,	,	PUNCT
eurjchem-870	292	36	57	57	NUM
eurjchem-870	292	37	(	(	PUNCT
eurjchem-870	292	38	3.5	3.5	NUM
eurjchem-870	292	39	)	)	PUNCT
eurjchem-870	292	40	.	.	PUNCT
eurjchem-870	293	1	anal	anal	PROPN
eurjchem-870	293	2	.	.	PUNCT
eurjchem-870	293	3	calcd	calcd	NOUN
eurjchem-870	293	4	.	.	PUNCT
eurjchem-870	294	1	for	for	ADP
eurjchem-870	294	2	c23h19n3o2	c23h19n3o2	PROPN
eurjchem-870	294	3	:	:	PUNCT
eurjchem-870	294	4	c	c	X
eurjchem-870	294	5	,	,	PUNCT
eurjchem-870	294	6	74.78	74.78	NUM
eurjchem-870	294	7	;	;	PUNCT
eurjchem-870	294	8	h	h	NOUN
eurjchem-870	294	9	,	,	PUNCT
eurjchem-870	294	10	5.18	5.18	NUM
eurjchem-870	294	11	;	;	PUNCT
eurjchem-870	294	12	n	n	CCONJ
eurjchem-870	294	13	,	,	PUNCT
eurjchem-870	294	14	11.37	11.37	NUM
eurjchem-870	294	15	.	.	PUNCT
eurjchem-870	294	16	found	find	VERB
eurjchem-870	294	17	:	:	PUNCT
eurjchem-870	295	1	c	c	X
eurjchem-870	295	2	,	,	PUNCT
eurjchem-870	295	3	75.10	75.10	NUM
eurjchem-870	295	4	;	;	PUNCT
eurjchem-870	295	5	h	h	NOUN
eurjchem-870	295	6	,	,	PUNCT
eurjchem-870	295	7	5.25	5.25	NUM
eurjchem-870	295	8	;	;	PUNCT
eurjchem-870	295	9	n	n	CCONJ
eurjchem-870	295	10	,	,	PUNCT
eurjchem-870	295	11	11.56	11.56	NUM
eurjchem-870	295	12	%	%	NOUN
eurjchem-870	295	13	.	.	PUNCT
eurjchem-870	296	1	marzouk	marzouk	INTJ
eurjchem-870	296	2	et	et	PROPN
eurjchem-870	296	3	al	al	PROPN
eurjchem-870	296	4	.	.	PUNCT
eurjchem-870	296	5	/	/	SYM
eurjchem-870	296	6	european	european	PROPN
eurjchem-870	296	7	journal	journal	PROPN
eurjchem-870	296	8	of	of	ADP
eurjchem-870	296	9	chemistry	chemistry	NOUN
eurjchem-870	296	10	5	5	NUM
eurjchem-870	296	11	(	(	PUNCT
eurjchem-870	296	12	1	1	NUM
eurjchem-870	296	13	)	)	PUNCT
eurjchem-870	296	14	(	(	PUNCT
eurjchem-870	296	15	2014	2014	NUM
eurjchem-870	296	16	)	)	PUNCT
eurjchem-870	296	17	24‐32	24‐32	NUM
eurjchem-870	296	18	29	29	NUM
eurjchem-870	296	19	scheme	scheme	NOUN
eurjchem-870	296	20	4	4	NUM
eurjchem-870	296	21	2.2.20	2.2.20	NUM
eurjchem-870	296	22	.	.	PUNCT
eurjchem-870	297	1	1‐(6‐hydroxy‐4‐(4‐methoxyphenyl)‐1,3‐diphenyl‐1,4‐	1‐(6‐hydroxy‐4‐(4‐methoxyphenyl)‐1,3‐diphenyl‐1,4‐	PROPN
eurjchem-870	297	2	dihydropyrano[2,3‐c]pyrazol‐5‐yl)ethanone	dihydropyrano[2,3‐c]pyrazol‐5‐yl)ethanone	NUM
eurjchem-870	297	3	(	(	PUNCT
eurjchem-870	297	4	26	26	NUM
eurjchem-870	297	5	)	)	PUNCT
eurjchem-870	297	6	a	a	DET
eurjchem-870	297	7	mixture	mixture	NOUN
eurjchem-870	297	8	of	of	ADP
eurjchem-870	297	9	pyrazolone	pyrazolone	NOUN
eurjchem-870	297	10	19	19	NUM
eurjchem-870	297	11	(	(	PUNCT
eurjchem-870	297	12	0.708	0.708	NUM
eurjchem-870	297	13	 	 	SPACE
eurjchem-870	297	14	g	g	NOUN
eurjchem-870	297	15	,	,	PUNCT
eurjchem-870	297	16	0.002	0.002	NUM
eurjchem-870	297	17	 	 	SPACE
eurjchem-870	297	18	mol	mol	NOUN
eurjchem-870	297	19	)	)	PUNCT
eurjchem-870	297	20	,	,	PUNCT
eurjchem-870	297	21	ethyl	ethyl	PROPN
eurjchem-870	297	22	acetoacetate	acetoacetate	NOUN
eurjchem-870	297	23	(	(	PUNCT
eurjchem-870	297	24	0.26	0.26	NUM
eurjchem-870	297	25	 	 	SPACE
eurjchem-870	297	26	ml	ml	NOUN
eurjchem-870	297	27	,	,	PUNCT
eurjchem-870	297	28	0.002	0.002	NUM
eurjchem-870	297	29	 	 	SPACE
eurjchem-870	297	30	mol	mol	NOUN
eurjchem-870	297	31	,	,	PUNCT
eurjchem-870	297	32	)	)	PUNCT
eurjchem-870	297	33	in	in	ADP
eurjchem-870	297	34	sodium	sodium	NOUN
eurjchem-870	297	35	ethoxide	ethoxide	NOUN
eurjchem-870	297	36	(	(	PUNCT
eurjchem-870	297	37	1	1	NUM
eurjchem-870	297	38	%	%	NOUN
eurjchem-870	297	39	)	)	PUNCT
eurjchem-870	297	40	solution	solution	NOUN
eurjchem-870	297	41	was	be	AUX
eurjchem-870	297	42	refluxed	refluxe	VERB
eurjchem-870	297	43	for	for	ADP
eurjchem-870	297	44	6	6	NUM
eurjchem-870	297	45	 	 	SPACE
eurjchem-870	297	46	h.	h.	NOUN
eurjchem-870	297	47	the	the	DET
eurjchem-870	297	48	mixture	mixture	NOUN
eurjchem-870	297	49	was	be	AUX
eurjchem-870	297	50	poured	pour	VERB
eurjchem-870	297	51	onto	onto	ADP
eurjchem-870	297	52	ice	ice	NOUN
eurjchem-870	297	53	:	:	PUNCT
eurjchem-870	298	1	hcl	hcl	PROPN
eurjchem-870	298	2	(	(	PUNCT
eurjchem-870	298	3	1:3	1:3	NUM
eurjchem-870	298	4	)	)	PUNCT
eurjchem-870	298	5	,	,	PUNCT
eurjchem-870	298	6	the	the	DET
eurjchem-870	298	7	separated	separate	VERB
eurjchem-870	298	8	solid	solid	ADJ
eurjchem-870	298	9	was	be	AUX
eurjchem-870	298	10	filtered	filter	VERB
eurjchem-870	298	11	off	off	ADP
eurjchem-870	298	12	,	,	PUNCT
eurjchem-870	298	13	washed	wash	VERB
eurjchem-870	298	14	with	with	ADP
eurjchem-870	298	15	water	water	NOUN
eurjchem-870	298	16	,	,	PUNCT
eurjchem-870	298	17	dried	dry	VERB
eurjchem-870	298	18	and	and	CCONJ
eurjchem-870	298	19	recrystallized	recrystallize	VERB
eurjchem-870	298	20	from	from	ADP
eurjchem-870	298	21	ethanol	ethanol	NOUN
eurjchem-870	298	22	(	(	PUNCT
eurjchem-870	298	23	scheme	scheme	NOUN
eurjchem-870	298	24	4	4	NUM
eurjchem-870	298	25	)	)	PUNCT
eurjchem-870	298	26	.	.	PUNCT
eurjchem-870	299	1	color	color	NOUN
eurjchem-870	299	2	:	:	PUNCT
eurjchem-870	299	3	pale	pale	ADJ
eurjchem-870	299	4	yellow	yellow	ADJ
eurjchem-870	299	5	.	.	PUNCT
eurjchem-870	300	1	yield	yield	NOUN
eurjchem-870	300	2	:	:	PUNCT
eurjchem-870	300	3	73.17	73.17	NUM
eurjchem-870	300	4	%	%	NOUN
eurjchem-870	300	5	.	.	PUNCT
eurjchem-870	301	1	m.p	m.p	PROPN
eurjchem-870	301	2	.	.	PROPN
eurjchem-870	301	3	:	:	PUNCT
eurjchem-870	302	1	140‐142	140‐142	NUM
eurjchem-870	302	2	°	°	NUM
eurjchem-870	302	3	c	c	X
eurjchem-870	302	4	.	.	PUNCT
eurjchem-870	302	5	ft‐ir	ft‐ir	NOUN
eurjchem-870	302	6	(	(	PUNCT
eurjchem-870	302	7	kbr	kbr	PROPN
eurjchem-870	302	8	,	,	PUNCT
eurjchem-870	302	9			PROPN
eurjchem-870	302	10	,	,	PUNCT
eurjchem-870	302	11	cm‐1	cm‐1	PROPN
eurjchem-870	302	12	):	):	PUNCT
eurjchem-870	302	13	3629	3629	NUM
eurjchem-870	302	14	(	(	PUNCT
eurjchem-870	302	15	oh	oh	INTJ
eurjchem-870	302	16	)	)	PUNCT
eurjchem-870	302	17	,	,	PUNCT
eurjchem-870	302	18	1713	1713	NUM
eurjchem-870	302	19	(	(	PUNCT
eurjchem-870	302	20	c	c	NOUN
eurjchem-870	302	21	=	=	NOUN
eurjchem-870	302	22	o	o	NOUN
eurjchem-870	302	23	)	)	PUNCT
eurjchem-870	302	24	,	,	PUNCT
eurjchem-870	302	25	1601	1601	NUM
eurjchem-870	302	26	(	(	PUNCT
eurjchem-870	302	27	c	c	NOUN
eurjchem-870	302	28	=	=	SYM
eurjchem-870	302	29	n	n	NUM
eurjchem-870	302	30	)	)	PUNCT
eurjchem-870	302	31	.	.	PUNCT
eurjchem-870	303	1	1h	1h	NUM
eurjchem-870	303	2	nmr	nmr	NOUN
eurjchem-870	303	3	(	(	PUNCT
eurjchem-870	303	4	300	300	NUM
eurjchem-870	303	5	mhz	mhz	NOUN
eurjchem-870	303	6	,	,	PUNCT
eurjchem-870	303	7	dmso	dmso	NOUN
eurjchem-870	303	8	,	,	PUNCT
eurjchem-870	303	9	δ	δ	PROPN
eurjchem-870	303	10	,	,	PUNCT
eurjchem-870	303	11	ppm	ppm	NUM
eurjchem-870	303	12	):	):	PUNCT
eurjchem-870	303	13	6.84‐8.68	6.84‐8.68	NUM
eurjchem-870	303	14	(	(	PUNCT
eurjchem-870	303	15	m	m	PROPN
eurjchem-870	303	16	,	,	PUNCT
eurjchem-870	303	17	14h	14h	NUM
eurjchem-870	303	18	,	,	PUNCT
eurjchem-870	303	19	arh	arh	PROPN
eurjchem-870	303	20	)	)	PUNCT
eurjchem-870	303	21	,	,	PUNCT
eurjchem-870	303	22	6.00	6.00	NUM
eurjchem-870	303	23	(	(	PUNCT
eurjchem-870	303	24	s	s	PROPN
eurjchem-870	303	25	,	,	PUNCT
eurjchem-870	303	26	1h	1h	NUM
eurjchem-870	303	27	,	,	PUNCT
eurjchem-870	303	28	oh	oh	INTJ
eurjchem-870	303	29	,	,	PUNCT
eurjchem-870	303	30	d2o	d2o	NOUN
eurjchem-870	303	31	exchangeable	exchangeable	ADJ
eurjchem-870	303	32	)	)	PUNCT
eurjchem-870	303	33	,	,	PUNCT
eurjchem-870	303	34	5.21	5.21	NUM
eurjchem-870	303	35	(	(	PUNCT
eurjchem-870	303	36	s	s	PROPN
eurjchem-870	303	37	,	,	PUNCT
eurjchem-870	303	38	1h	1h	NUM
eurjchem-870	303	39	,	,	PUNCT
eurjchem-870	303	40	benzilic	benzilic	NOUN
eurjchem-870	303	41	)	)	PUNCT
eurjchem-870	303	42	,	,	PUNCT
eurjchem-870	303	43	3.91	3.91	NUM
eurjchem-870	303	44	(	(	PUNCT
eurjchem-870	303	45	s	s	PROPN
eurjchem-870	303	46	,	,	PUNCT
eurjchem-870	303	47	3h	3h	NUM
eurjchem-870	303	48	,	,	PUNCT
eurjchem-870	303	49	och3	och3	ADJ
eurjchem-870	303	50	)	)	PUNCT
eurjchem-870	303	51	,	,	PUNCT
eurjchem-870	303	52	3.71(s	3.71(s	PROPN
eurjchem-870	303	53	,	,	PUNCT
eurjchem-870	303	54	3h	3h	NUM
eurjchem-870	303	55	,	,	PUNCT
eurjchem-870	303	56	coch3	coch3	NOUN
eurjchem-870	303	57	)	)	PUNCT
eurjchem-870	303	58	.	.	PUNCT
eurjchem-870	304	1	ms	ms	NOUN
eurjchem-870	304	2	(	(	PUNCT
eurjchem-870	304	3	ei	ei	PROPN
eurjchem-870	304	4	,	,	PUNCT
eurjchem-870	304	5	m	m	PROPN
eurjchem-870	304	6	/	/	SYM
eurjchem-870	304	7	z	z	PROPN
eurjchem-870	304	8	(	(	PUNCT
eurjchem-870	304	9	%	%	NOUN
eurjchem-870	304	10	)	)	PUNCT
eurjchem-870	304	11	):	):	PUNCT
eurjchem-870	304	12	440	440	NUM
eurjchem-870	304	13	(	(	PUNCT
eurjchem-870	304	14	9.4	9.4	NUM
eurjchem-870	304	15	,	,	PUNCT
eurjchem-870	304	16	[	[	X
eurjchem-870	304	17	m	m	NOUN
eurjchem-870	304	18	+2·]+	+2·]+	ADJ
eurjchem-870	304	19	)	)	PUNCT
eurjchem-870	304	20	,	,	PUNCT
eurjchem-870	304	21	354	354	NUM
eurjchem-870	304	22	(	(	PUNCT
eurjchem-870	304	23	71.8	71.8	NUM
eurjchem-870	304	24	)	)	PUNCT
eurjchem-870	304	25	,	,	PUNCT
eurjchem-870	304	26	353	353	NUM
eurjchem-870	304	27	(	(	PUNCT
eurjchem-870	304	28	34.1	34.1	NUM
eurjchem-870	304	29	)	)	PUNCT
eurjchem-870	304	30	,	,	PUNCT
eurjchem-870	304	31	352	352	NUM
eurjchem-870	304	32	(	(	PUNCT
eurjchem-870	304	33	21.2	21.2	NUM
eurjchem-870	304	34	)	)	PUNCT
eurjchem-870	304	35	,	,	PUNCT
eurjchem-870	304	36	268	268	NUM
eurjchem-870	304	37	(	(	PUNCT
eurjchem-870	304	38	100	100	NUM
eurjchem-870	304	39	)	)	PUNCT
eurjchem-870	304	40	,	,	PUNCT
eurjchem-870	304	41	267	267	NUM
eurjchem-870	304	42	(	(	PUNCT
eurjchem-870	304	43	45.9	45.9	NUM
eurjchem-870	304	44	)	)	PUNCT
eurjchem-870	304	45	,	,	PUNCT
eurjchem-870	304	46	251	251	NUM
eurjchem-870	304	47	(	(	PUNCT
eurjchem-870	304	48	28.2	28.2	NUM
eurjchem-870	304	49	)	)	PUNCT
eurjchem-870	304	50	,	,	PUNCT
eurjchem-870	304	51	249	249	NUM
eurjchem-870	304	52	(	(	PUNCT
eurjchem-870	304	53	58.8	58.8	NUM
eurjchem-870	304	54	)	)	PUNCT
eurjchem-870	304	55	,	,	PUNCT
eurjchem-870	304	56	172	172	NUM
eurjchem-870	304	57	(	(	PUNCT
eurjchem-870	304	58	15.3),77	15.3),77	NOUN
eurjchem-870	304	59	(	(	PUNCT
eurjchem-870	304	60	40.0	40.0	NUM
eurjchem-870	304	61	)	)	PUNCT
eurjchem-870	304	62	,	,	PUNCT
eurjchem-870	304	63	78	78	NUM
eurjchem-870	304	64	(	(	PUNCT
eurjchem-870	304	65	11.8	11.8	NUM
eurjchem-870	304	66	)	)	PUNCT
eurjchem-870	304	67	.	.	PUNCT
eurjchem-870	305	1	anal	anal	PROPN
eurjchem-870	305	2	.	.	PUNCT
eurjchem-870	305	3	calcd	calcd	NOUN
eurjchem-870	305	4	.	.	PUNCT
eurjchem-870	306	1	for	for	ADP
eurjchem-870	306	2	c27h22n2o4	c27h22n2o4	PROPN
eurjchem-870	306	3	:	:	PUNCT
eurjchem-870	306	4	c	c	X
eurjchem-870	306	5	,	,	PUNCT
eurjchem-870	306	6	73.96	73.96	NUM
eurjchem-870	306	7	;	;	PUNCT
eurjchem-870	306	8	h	h	NOUN
eurjchem-870	306	9	,	,	PUNCT
eurjchem-870	306	10	5.06	5.06	NUM
eurjchem-870	306	11	;	;	PUNCT
eurjchem-870	306	12	n	n	CCONJ
eurjchem-870	306	13	,	,	PUNCT
eurjchem-870	306	14	6.39	6.39	NUM
eurjchem-870	306	15	.	.	PUNCT
eurjchem-870	306	16	found	find	VERB
eurjchem-870	306	17	:	:	PUNCT
eurjchem-870	307	1	c	c	X
eurjchem-870	307	2	,	,	PUNCT
eurjchem-870	307	3	74.14	74.14	NUM
eurjchem-870	307	4	;	;	PUNCT
eurjchem-870	307	5	h	h	NOUN
eurjchem-870	307	6	,	,	PUNCT
eurjchem-870	307	7	5.20	5.20	NUM
eurjchem-870	307	8	;	;	PUNCT
eurjchem-870	307	9	n	n	CCONJ
eurjchem-870	307	10	,	,	PUNCT
eurjchem-870	307	11	6.51	6.51	NUM
eurjchem-870	307	12	%	%	NOUN
eurjchem-870	307	13	.	.	PUNCT
eurjchem-870	308	1	2.2.21	2.2.21	NUM
eurjchem-870	308	2	.	.	PUNCT
eurjchem-870	309	1	1‐(6‐hydroxy‐4‐(4‐methoxyphenyl)‐1,3‐diphenyl‐1h‐	1‐(6‐hydroxy‐4‐(4‐methoxyphenyl)‐1,3‐diphenyl‐1h‐	NUM
eurjchem-870	309	2	pyrazolo[3,4‐b]pyridin‐5yl)ethanone	pyrazolo[3,4‐b]pyridin‐5yl)ethanone	PROPN
eurjchem-870	309	3	(	(	PUNCT
eurjchem-870	309	4	27	27	NUM
eurjchem-870	309	5	)	)	PUNCT
eurjchem-870	309	6	a	a	DET
eurjchem-870	309	7	mixture	mixture	NOUN
eurjchem-870	309	8	of	of	ADP
eurjchem-870	309	9	pyrazolone	pyrazolone	NOUN
eurjchem-870	309	10	19	19	NUM
eurjchem-870	309	11	(	(	PUNCT
eurjchem-870	309	12	0.708	0.708	NUM
eurjchem-870	309	13	 	 	SPACE
eurjchem-870	309	14	g	g	NOUN
eurjchem-870	309	15	,	,	PUNCT
eurjchem-870	309	16	0.002	0.002	NUM
eurjchem-870	309	17	 	 	SPACE
eurjchem-870	309	18	mol	mol	NOUN
eurjchem-870	309	19	)	)	PUNCT
eurjchem-870	309	20	,	,	PUNCT
eurjchem-870	309	21	ammonium	ammonium	NOUN
eurjchem-870	309	22	acetate	acetate	NOUN
eurjchem-870	309	23	(	(	PUNCT
eurjchem-870	309	24	2	2	NUM
eurjchem-870	309	25	 	 	SPACE
eurjchem-870	309	26	g	g	NOUN
eurjchem-870	309	27	)	)	PUNCT
eurjchem-870	309	28	,	,	PUNCT
eurjchem-870	309	29	and	and	CCONJ
eurjchem-870	309	30	ethyl	ethyl	PROPN
eurjchem-870	309	31	acetoacetate	acetoacetate	NOUN
eurjchem-870	309	32	(	(	PUNCT
eurjchem-870	309	33	0.26	0.26	NUM
eurjchem-870	309	34	 	 	SPACE
eurjchem-870	309	35	ml	ml	NOUN
eurjchem-870	309	36	,	,	PUNCT
eurjchem-870	309	37	0.002	0.002	NUM
eurjchem-870	309	38	 	 	SPACE
eurjchem-870	309	39	mol	mol	NOUN
eurjchem-870	309	40	,	,	PUNCT
eurjchem-870	309	41	)	)	PUNCT
eurjchem-870	309	42	was	be	AUX
eurjchem-870	309	43	fused	fuse	VERB
eurjchem-870	309	44	for	for	ADP
eurjchem-870	309	45	7	7	NUM
eurjchem-870	309	46	 	 	SPACE
eurjchem-870	309	47	h	h	NOUN
eurjchem-870	309	48	at	at	ADP
eurjchem-870	309	49	170	170	NUM
eurjchem-870	309	50	°	°	NOUN
eurjchem-870	309	51	c	c	NOUN
eurjchem-870	309	52	.	.	PUNCT
eurjchem-870	310	1	after	after	ADP
eurjchem-870	310	2	cooling	cool	VERB
eurjchem-870	310	3	,	,	PUNCT
eurjchem-870	310	4	the	the	DET
eurjchem-870	310	5	reaction	reaction	NOUN
eurjchem-870	310	6	mixture	mixture	NOUN
eurjchem-870	310	7	was	be	AUX
eurjchem-870	310	8	triturated	triturate	VERB
eurjchem-870	310	9	with	with	ADP
eurjchem-870	310	10	petroleum	petroleum	NOUN
eurjchem-870	310	11	ether	ether	NOUN
eurjchem-870	310	12	(	(	PUNCT
eurjchem-870	310	13	60‐80	60‐80	NOUN
eurjchem-870	310	14	°	°	SYM
eurjchem-870	310	15	c	c	NOUN
eurjchem-870	310	16	)	)	PUNCT
eurjchem-870	310	17	to	to	PART
eurjchem-870	310	18	give	give	VERB
eurjchem-870	310	19	an	an	DET
eurjchem-870	310	20	orange	orange	NOUN
eurjchem-870	310	21	solid	solid	NOUN
eurjchem-870	310	22	which	which	PRON
eurjchem-870	310	23	was	be	AUX
eurjchem-870	310	24	recrystallized	recrystallize	VERB
eurjchem-870	310	25	from	from	ADP
eurjchem-870	310	26	petroleum	petroleum	NOUN
eurjchem-870	310	27	ether	ether	NOUN
eurjchem-870	310	28	60‐80	60‐80	NOUN
eurjchem-870	311	1	°	°	ADP
eurjchem-870	311	2	c	c	X
eurjchem-870	311	3	(	(	PUNCT
eurjchem-870	311	4	scheme	scheme	NOUN
eurjchem-870	311	5	4	4	NUM
eurjchem-870	311	6	)	)	PUNCT
eurjchem-870	311	7	.	.	PUNCT
eurjchem-870	312	1	color	color	NOUN
eurjchem-870	312	2	:	:	PUNCT
eurjchem-870	312	3	orange	orange	ADJ
eurjchem-870	312	4	.	.	PUNCT
eurjchem-870	313	1	yield	yield	NOUN
eurjchem-870	313	2	:	:	PUNCT
eurjchem-870	313	3	66.66	66.66	NUM
eurjchem-870	313	4	%	%	NOUN
eurjchem-870	313	5	.	.	PUNCT
eurjchem-870	314	1	m.p.:136‐138	m.p.:136‐138	PROPN
eurjchem-870	314	2	°	°	PROPN
eurjchem-870	314	3	c	c	PROPN
eurjchem-870	314	4	.	.	PUNCT
eurjchem-870	315	1	ft‐ir	ft‐ir	NOUN
eurjchem-870	315	2	(	(	PUNCT
eurjchem-870	315	3	kbr	kbr	PROPN
eurjchem-870	315	4	,	,	PUNCT
eurjchem-870	315	5			PROPN
eurjchem-870	315	6	,	,	PUNCT
eurjchem-870	315	7	cm‐1	cm‐1	PROPN
eurjchem-870	315	8	):	):	PUNCT
eurjchem-870	315	9	3055	3055	NUM
eurjchem-870	315	10	(	(	PUNCT
eurjchem-870	315	11	oh	oh	INTJ
eurjchem-870	315	12	)	)	PUNCT
eurjchem-870	315	13	1706	1706	NUM
eurjchem-870	315	14	(	(	PUNCT
eurjchem-870	315	15	c	c	NOUN
eurjchem-870	315	16	=	=	NOUN
eurjchem-870	315	17	o	o	NOUN
eurjchem-870	315	18	)	)	PUNCT
eurjchem-870	315	19	.	.	PUNCT
eurjchem-870	316	1	1h	1h	NUM
eurjchem-870	316	2	nmr	nmr	NOUN
eurjchem-870	316	3	(	(	PUNCT
eurjchem-870	316	4	300	300	NUM
eurjchem-870	316	5	mhz	mhz	NOUN
eurjchem-870	316	6	,	,	PUNCT
eurjchem-870	316	7	cdcl3	cdcl3	PROPN
eurjchem-870	316	8	,	,	PUNCT
eurjchem-870	316	9	δ	δ	PROPN
eurjchem-870	316	10	,	,	PUNCT
eurjchem-870	316	11	ppm	ppm	NUM
eurjchem-870	316	12	):	):	PUNCT
eurjchem-870	316	13	14.89	14.89	NUM
eurjchem-870	316	14	(	(	PUNCT
eurjchem-870	316	15	s	s	PROPN
eurjchem-870	316	16	,	,	PUNCT
eurjchem-870	316	17	1h	1h	NUM
eurjchem-870	316	18	,	,	PUNCT
eurjchem-870	316	19	oh	oh	INTJ
eurjchem-870	316	20	,	,	PUNCT
eurjchem-870	316	21	d2o	d2o	NOUN
eurjchem-870	316	22	exchangeable	exchangeable	ADJ
eurjchem-870	316	23	)	)	PUNCT
eurjchem-870	316	24	,	,	PUNCT
eurjchem-870	316	25	7.12‐7.91	7.12‐7.91	NUM
eurjchem-870	316	26	(	(	PUNCT
eurjchem-870	316	27	m	m	PROPN
eurjchem-870	316	28	,	,	PUNCT
eurjchem-870	316	29	14h	14h	NUM
eurjchem-870	316	30	,	,	PUNCT
eurjchem-870	316	31	arh	arh	PROPN
eurjchem-870	316	32	)	)	PUNCT
eurjchem-870	316	33	,	,	PUNCT
eurjchem-870	316	34	3.76	3.76	NUM
eurjchem-870	316	35	(	(	PUNCT
eurjchem-870	316	36	s	s	PROPN
eurjchem-870	316	37	,	,	PUNCT
eurjchem-870	316	38	3h	3h	NUM
eurjchem-870	316	39	,	,	PUNCT
eurjchem-870	316	40	och3	och3	ADJ
eurjchem-870	316	41	)	)	PUNCT
eurjchem-870	316	42	,	,	PUNCT
eurjchem-870	316	43	3.60	3.60	NUM
eurjchem-870	316	44	(	(	PUNCT
eurjchem-870	316	45	s	s	PROPN
eurjchem-870	316	46	,	,	PUNCT
eurjchem-870	316	47	3h	3h	NUM
eurjchem-870	316	48	,	,	PUNCT
eurjchem-870	316	49	coch3	coch3	NOUN
eurjchem-870	316	50	)	)	PUNCT
eurjchem-870	316	51	.	.	PUNCT
eurjchem-870	317	1	ms	ms	NOUN
eurjchem-870	317	2	(	(	PUNCT
eurjchem-870	317	3	ei	ei	PROPN
eurjchem-870	317	4	,	,	PUNCT
eurjchem-870	317	5	m	m	PROPN
eurjchem-870	317	6	/	/	SYM
eurjchem-870	317	7	z	z	PROPN
eurjchem-870	317	8	(	(	PUNCT
eurjchem-870	317	9	%	%	NOUN
eurjchem-870	317	10	)	)	PUNCT
eurjchem-870	317	11	):	):	PUNCT
eurjchem-870	317	12	435	435	NUM
eurjchem-870	317	13	(	(	PUNCT
eurjchem-870	317	14	3.4	3.4	NUM
eurjchem-870	317	15	,	,	PUNCT
eurjchem-870	317	16	m+	m+	NOUN
eurjchem-870	317	17	·	·	PUNCT
eurjchem-870	317	18	)	)	PUNCT
eurjchem-870	317	19	,	,	PUNCT
eurjchem-870	317	20	289	289	NUM
eurjchem-870	317	21	(	(	PUNCT
eurjchem-870	317	22	2.9	2.9	NUM
eurjchem-870	317	23	)	)	PUNCT
eurjchem-870	317	24	,	,	PUNCT
eurjchem-870	317	25	276	276	NUM
eurjchem-870	317	26	(	(	PUNCT
eurjchem-870	317	27	9.1	9.1	NUM
eurjchem-870	317	28	)	)	PUNCT
eurjchem-870	317	29	,	,	PUNCT
eurjchem-870	317	30	171	171	NUM
eurjchem-870	317	31	(	(	PUNCT
eurjchem-870	317	32	7.4	7.4	NUM
eurjchem-870	317	33	)	)	PUNCT
eurjchem-870	317	34	,	,	PUNCT
eurjchem-870	317	35	121	121	NUM
eurjchem-870	317	36	(	(	PUNCT
eurjchem-870	317	37	100	100	NUM
eurjchem-870	317	38	)	)	PUNCT
eurjchem-870	317	39	.	.	PUNCT
eurjchem-870	318	1	anal	anal	PROPN
eurjchem-870	318	2	.	.	PUNCT
eurjchem-870	318	3	calcd	calcd	NOUN
eurjchem-870	318	4	.	.	PUNCT
eurjchem-870	319	1	for	for	ADP
eurjchem-870	319	2	c27h21n3o3	c27h21n3o3	PROPN
eurjchem-870	319	3	:	:	PUNCT
eurjchem-870	319	4	c	c	NOUN
eurjchem-870	319	5	,	,	PUNCT
eurjchem-870	319	6	74.47	74.47	NUM
eurjchem-870	319	7	;	;	PUNCT
eurjchem-870	319	8	h	h	NOUN
eurjchem-870	319	9	,	,	PUNCT
eurjchem-870	319	10	4.86	4.86	NUM
eurjchem-870	319	11	;	;	PUNCT
eurjchem-870	319	12	n	n	CCONJ
eurjchem-870	319	13	,	,	PUNCT
eurjchem-870	319	14	9.65	9.65	NUM
eurjchem-870	319	15	.	.	PUNCT
eurjchem-870	319	16	found	find	VERB
eurjchem-870	319	17	:	:	PUNCT
eurjchem-870	320	1	c	c	X
eurjchem-870	320	2	,	,	PUNCT
eurjchem-870	320	3	74.51	74.51	NUM
eurjchem-870	320	4	;	;	PUNCT
eurjchem-870	320	5	h	h	X
eurjchem-870	320	6	,	,	PUNCT
eurjchem-870	320	7	4.93	4.93	NUM
eurjchem-870	320	8	;	;	PUNCT
eurjchem-870	320	9	n	n	CCONJ
eurjchem-870	320	10	,	,	PUNCT
eurjchem-870	320	11	9.72	9.72	NUM
eurjchem-870	320	12	%	%	NOUN
eurjchem-870	320	13	.	.	PUNCT
eurjchem-870	321	1	2.2.22	2.2.22	NUM
eurjchem-870	321	2	.	.	PUNCT
eurjchem-870	321	3	4‐(4‐methoxyphenyl)‐6‐oxo‐1,3‐diphenyl‐1,6‐dihydro	4‐(4‐methoxyphenyl)‐6‐oxo‐1,3‐diphenyl‐1,6‐dihydro	PROPN
eurjchem-870	321	4	pyrano[2,3‐c]pyrazole‐5‐carbonitrile	pyrano[2,3‐c]pyrazole‐5‐carbonitrile	NOUN
eurjchem-870	321	5	(	(	PUNCT
eurjchem-870	321	6	28	28	NUM
eurjchem-870	321	7	)	)	PUNCT
eurjchem-870	321	8	a	a	DET
eurjchem-870	321	9	mixture	mixture	NOUN
eurjchem-870	321	10	of	of	ADP
eurjchem-870	321	11	pyrazolone	pyrazolone	NOUN
eurjchem-870	321	12	19	19	NUM
eurjchem-870	321	13	(	(	PUNCT
eurjchem-870	321	14	0.708	0.708	NUM
eurjchem-870	321	15	 	 	SPACE
eurjchem-870	321	16	g	g	NOUN
eurjchem-870	321	17	,	,	PUNCT
eurjchem-870	321	18	0.002	0.002	NUM
eurjchem-870	321	19	 	 	SPACE
eurjchem-870	321	20	mol	mol	NOUN
eurjchem-870	321	21	)	)	PUNCT
eurjchem-870	321	22	,	,	PUNCT
eurjchem-870	321	23	ethyl	ethyl	PROPN
eurjchem-870	321	24	cyanoacetate	cyanoacetate	NOUN
eurjchem-870	321	25	(	(	PUNCT
eurjchem-870	321	26	0.226	0.226	NUM
eurjchem-870	321	27	 	 	SPACE
eurjchem-870	321	28	ml	ml	NOUN
eurjchem-870	321	29	,	,	PUNCT
eurjchem-870	321	30	0.002	0.002	NUM
eurjchem-870	321	31	 	 	SPACE
eurjchem-870	321	32	mol	mol	NOUN
eurjchem-870	321	33	)	)	PUNCT
eurjchem-870	321	34	in	in	ADP
eurjchem-870	321	35	sodium	sodium	NOUN
eurjchem-870	321	36	ethoxide	ethoxide	NOUN
eurjchem-870	321	37	(	(	PUNCT
eurjchem-870	321	38	1	1	NUM
eurjchem-870	321	39	%	%	NOUN
eurjchem-870	321	40	)	)	PUNCT
eurjchem-870	321	41	solution	solution	NOUN
eurjchem-870	321	42	was	be	AUX
eurjchem-870	321	43	refluxed	refluxe	VERB
eurjchem-870	321	44	for	for	ADP
eurjchem-870	321	45	6	6	NUM
eurjchem-870	321	46	 	 	SPACE
eurjchem-870	321	47	h.	h.	NOUN
eurjchem-870	321	48	the	the	DET
eurjchem-870	321	49	mixture	mixture	NOUN
eurjchem-870	321	50	was	be	AUX
eurjchem-870	321	51	poured	pour	VERB
eurjchem-870	321	52	onto	onto	ADP
eurjchem-870	321	53	ice	ice	NOUN
eurjchem-870	321	54	:	:	PUNCT
eurjchem-870	322	1	hcl	hcl	PROPN
eurjchem-870	322	2	(	(	PUNCT
eurjchem-870	322	3	1:3	1:3	NUM
eurjchem-870	322	4	)	)	PUNCT
eurjchem-870	322	5	,	,	PUNCT
eurjchem-870	322	6	the	the	DET
eurjchem-870	322	7	separated	separate	VERB
eurjchem-870	322	8	solid	solid	ADJ
eurjchem-870	322	9	was	be	AUX
eurjchem-870	322	10	filtered	filter	VERB
eurjchem-870	322	11	off	off	ADP
eurjchem-870	322	12	,	,	PUNCT
eurjchem-870	322	13	washed	wash	VERB
eurjchem-870	322	14	with	with	ADP
eurjchem-870	322	15	water	water	NOUN
eurjchem-870	322	16	,	,	PUNCT
eurjchem-870	322	17	dried	dry	VERB
eurjchem-870	322	18	and	and	CCONJ
eurjchem-870	322	19	recrystallized	recrystallize	VERB
eurjchem-870	322	20	from	from	ADP
eurjchem-870	322	21	ethanol	ethanol	NOUN
eurjchem-870	322	22	(	(	PUNCT
eurjchem-870	322	23	scheme	scheme	NOUN
eurjchem-870	322	24	4	4	NUM
eurjchem-870	322	25	)	)	PUNCT
eurjchem-870	322	26	.	.	PUNCT
eurjchem-870	323	1	color	color	NOUN
eurjchem-870	323	2	:	:	PUNCT
eurjchem-870	323	3	pale	pale	ADJ
eurjchem-870	323	4	green	green	NOUN
eurjchem-870	323	5	.	.	PUNCT
eurjchem-870	324	1	yield	yield	NOUN
eurjchem-870	324	2	:	:	PUNCT
eurjchem-870	324	3	35.16	35.16	NUM
eurjchem-870	324	4	%	%	NOUN
eurjchem-870	324	5	.	.	PUNCT
eurjchem-870	325	1	m.p	m.p	PROPN
eurjchem-870	325	2	.	.	PROPN
eurjchem-870	325	3	:	:	PUNCT
eurjchem-870	326	1	136‐138	136‐138	PROPN
eurjchem-870	326	2	°	°	SYM
eurjchem-870	326	3	c	c	PROPN
eurjchem-870	326	4	.	.	PUNCT
eurjchem-870	327	1	ft‐ir	ft‐ir	NOUN
eurjchem-870	327	2	(	(	PUNCT
eurjchem-870	327	3	kbr	kbr	PROPN
eurjchem-870	327	4	,	,	PUNCT
eurjchem-870	327	5			PROPN
eurjchem-870	327	6	,	,	PUNCT
eurjchem-870	327	7	cm‐1	cm‐1	PROPN
eurjchem-870	327	8	):	):	PUNCT
eurjchem-870	327	9	2208	2208	NUM
eurjchem-870	327	10	(	(	PUNCT
eurjchem-870	327	11	c≡n	c≡n	PROPN
eurjchem-870	327	12	)	)	PUNCT
eurjchem-870	327	13	,	,	PUNCT
eurjchem-870	327	14	1706	1706	NUM
eurjchem-870	327	15	(	(	PUNCT
eurjchem-870	327	16	c	c	NOUN
eurjchem-870	327	17	=	=	NOUN
eurjchem-870	327	18	o	o	NOUN
eurjchem-870	327	19	)	)	PUNCT
eurjchem-870	327	20	,	,	PUNCT
eurjchem-870	327	21	1665	1665	NUM
eurjchem-870	327	22	(	(	PUNCT
eurjchem-870	327	23	c	c	NOUN
eurjchem-870	327	24	=	=	SYM
eurjchem-870	327	25	n	n	NUM
eurjchem-870	327	26	)	)	PUNCT
eurjchem-870	327	27	,	,	PUNCT
eurjchem-870	327	28	1621	1621	NUM
eurjchem-870	327	29	(	(	PUNCT
eurjchem-870	327	30	c	c	NOUN
eurjchem-870	327	31	=	=	SYM
eurjchem-870	327	32	c	c	NOUN
eurjchem-870	327	33	)	)	PUNCT
eurjchem-870	327	34	.	.	PUNCT
eurjchem-870	328	1	1h	1h	NUM
eurjchem-870	328	2	nmr	nmr	NOUN
eurjchem-870	328	3	(	(	PUNCT
eurjchem-870	328	4	300	300	NUM
eurjchem-870	328	5	mhz	mhz	NOUN
eurjchem-870	328	6	,	,	PUNCT
eurjchem-870	328	7	dmso	dmso	NOUN
eurjchem-870	328	8	,	,	PUNCT
eurjchem-870	328	9	δ	δ	PROPN
eurjchem-870	328	10	,	,	PUNCT
eurjchem-870	328	11	ppm	ppm	NOUN
eurjchem-870	328	12	):	):	PUNCT
eurjchem-870	328	13	7.25‐7.82	7.25‐7.82	NUM
eurjchem-870	328	14	(	(	PUNCT
eurjchem-870	328	15	m	m	PROPN
eurjchem-870	328	16	,	,	PUNCT
eurjchem-870	328	17	14h	14h	NUM
eurjchem-870	328	18	,	,	PUNCT
eurjchem-870	328	19	arh	arh	PROPN
eurjchem-870	328	20	)	)	PUNCT
eurjchem-870	328	21	,	,	PUNCT
eurjchem-870	328	22	3.79	3.79	NUM
eurjchem-870	328	23	(	(	PUNCT
eurjchem-870	328	24	s	s	PROPN
eurjchem-870	328	25	,	,	PUNCT
eurjchem-870	328	26	3h	3h	NUM
eurjchem-870	328	27	,	,	PUNCT
eurjchem-870	328	28	och3	och3	ADJ
eurjchem-870	328	29	)	)	PUNCT
eurjchem-870	328	30	.	.	PUNCT
eurjchem-870	329	1	ms	ms	NOUN
eurjchem-870	329	2	(	(	PUNCT
eurjchem-870	329	3	ei	ei	PROPN
eurjchem-870	329	4	,	,	PUNCT
eurjchem-870	329	5	m	m	PROPN
eurjchem-870	329	6	/	/	SYM
eurjchem-870	329	7	z	z	PROPN
eurjchem-870	329	8	(	(	PUNCT
eurjchem-870	329	9	%	%	NOUN
eurjchem-870	329	10	)	)	PUNCT
eurjchem-870	329	11	):	):	PUNCT
eurjchem-870	329	12	354	354	NUM
eurjchem-870	329	13	(	(	PUNCT
eurjchem-870	329	14	9.4	9.4	NUM
eurjchem-870	329	15	,	,	PUNCT
eurjchem-870	329	16	[	[	X
eurjchem-870	329	17	m‐c3h3no·]+	m‐c3h3no·]+	NOUN
eurjchem-870	329	18	)	)	PUNCT
eurjchem-870	329	19	,	,	PUNCT
eurjchem-870	329	20	236	236	NUM
eurjchem-870	329	21	30	30	NUM
eurjchem-870	329	22	marzouk	marzouk	ADV
eurjchem-870	329	23	et	et	PROPN
eurjchem-870	329	24	al	al	PROPN
eurjchem-870	329	25	.	.	PUNCT
eurjchem-870	329	26	/	/	SYM
eurjchem-870	329	27	european	european	PROPN
eurjchem-870	329	28	journal	journal	PROPN
eurjchem-870	329	29	of	of	ADP
eurjchem-870	329	30	chemistry	chemistry	NOUN
eurjchem-870	329	31	5	5	NUM
eurjchem-870	329	32	(	(	PUNCT
eurjchem-870	329	33	1	1	NUM
eurjchem-870	329	34	)	)	PUNCT
eurjchem-870	329	35	(	(	PUNCT
eurjchem-870	329	36	2014	2014	NUM
eurjchem-870	329	37	)	)	PUNCT
eurjchem-870	329	38	24‐32	24‐32	NUM
eurjchem-870	329	39	(	(	PUNCT
eurjchem-870	329	40	44.2	44.2	NUM
eurjchem-870	329	41	)	)	PUNCT
eurjchem-870	329	42	,	,	PUNCT
eurjchem-870	329	43	105	105	NUM
eurjchem-870	329	44	(	(	PUNCT
eurjchem-870	329	45	23.2	23.2	NUM
eurjchem-870	329	46	)	)	PUNCT
eurjchem-870	329	47	,	,	PUNCT
eurjchem-870	329	48	91	91	NUM
eurjchem-870	329	49	(	(	PUNCT
eurjchem-870	329	50	42.0	42.0	NUM
eurjchem-870	329	51	)	)	PUNCT
eurjchem-870	329	52	,	,	PUNCT
eurjchem-870	329	53	85	85	NUM
eurjchem-870	329	54	(	(	PUNCT
eurjchem-870	329	55	32.6	32.6	NUM
eurjchem-870	329	56	)	)	PUNCT
eurjchem-870	329	57	,	,	PUNCT
eurjchem-870	329	58	69	69	NUM
eurjchem-870	329	59	(	(	PUNCT
eurjchem-870	329	60	42.0	42.0	NUM
eurjchem-870	329	61	)	)	PUNCT
eurjchem-870	329	62	,	,	PUNCT
eurjchem-870	329	63	57	57	NUM
eurjchem-870	329	64	(	(	PUNCT
eurjchem-870	329	65	100	100	NUM
eurjchem-870	329	66	)	)	PUNCT
eurjchem-870	329	67	,	,	PUNCT
eurjchem-870	329	68	51	51	NUM
eurjchem-870	329	69	(	(	PUNCT
eurjchem-870	329	70	282	282	NUM
eurjchem-870	329	71	)	)	PUNCT
eurjchem-870	329	72	.	.	PUNCT
eurjchem-870	330	1	anal	anal	PROPN
eurjchem-870	330	2	.	.	PUNCT
eurjchem-870	330	3	calcd	calcd	NOUN
eurjchem-870	330	4	.	.	PUNCT
eurjchem-870	331	1	for	for	ADP
eurjchem-870	331	2	c26h17n3o3	c26h17n3o3	NOUN
eurjchem-870	331	3	:	:	PUNCT
eurjchem-870	331	4	c	c	X
eurjchem-870	331	5	,	,	PUNCT
eurjchem-870	331	6	74.45	74.45	NUM
eurjchem-870	331	7	;	;	PUNCT
eurjchem-870	331	8	h	h	NOUN
eurjchem-870	331	9	,	,	PUNCT
eurjchem-870	331	10	4.09	4.09	NUM
eurjchem-870	331	11	;	;	PUNCT
eurjchem-870	331	12	n	n	CCONJ
eurjchem-870	331	13	,	,	PUNCT
eurjchem-870	331	14	10.02	10.02	NUM
eurjchem-870	331	15	.	.	PUNCT
eurjchem-870	331	16	found	find	VERB
eurjchem-870	331	17	:	:	PUNCT
eurjchem-870	332	1	c	c	X
eurjchem-870	332	2	,	,	PUNCT
eurjchem-870	332	3	74.62	74.62	NUM
eurjchem-870	332	4	;	;	PUNCT
eurjchem-870	332	5	h	h	NOUN
eurjchem-870	332	6	,	,	PUNCT
eurjchem-870	332	7	4.13	4.13	NUM
eurjchem-870	332	8	;	;	PUNCT
eurjchem-870	332	9	n	n	CCONJ
eurjchem-870	332	10	,	,	PUNCT
eurjchem-870	332	11	10.21	10.21	NUM
eurjchem-870	332	12	%	%	NOUN
eurjchem-870	332	13	.	.	PUNCT
eurjchem-870	333	1	2.2.23	2.2.23	X
eurjchem-870	333	2	.	.	PUNCT
eurjchem-870	334	1	2‐((3‐methoxyphenyl)(5‐oxo‐1,3‐diphenyl‐4,5‐	2‐((3‐methoxyphenyl)(5‐oxo‐1,3‐diphenyl‐4,5‐	PROPN
eurjchem-870	334	2	dihydro‐1h‐pyrazol‐4‐yl)methyl)malononitrile	dihydro‐1h‐pyrazol‐4‐yl)methyl)malononitrile	NOUN
eurjchem-870	334	3	(	(	PUNCT
eurjchem-870	334	4	29	29	NUM
eurjchem-870	334	5	)	)	PUNCT
eurjchem-870	334	6	a	a	DET
eurjchem-870	334	7	mixture	mixture	NOUN
eurjchem-870	334	8	of	of	ADP
eurjchem-870	334	9	pyrazolone	pyrazolone	NOUN
eurjchem-870	334	10	19	19	NUM
eurjchem-870	334	11	(	(	PUNCT
eurjchem-870	334	12	3.54	3.54	NUM
eurjchem-870	334	13	 	 	SPACE
eurjchem-870	334	14	g	g	NOUN
eurjchem-870	334	15	,	,	PUNCT
eurjchem-870	334	16	0.01	0.01	NUM
eurjchem-870	334	17	 	 	SPACE
eurjchem-870	334	18	mol	mol	NOUN
eurjchem-870	334	19	)	)	PUNCT
eurjchem-870	334	20	and	and	CCONJ
eurjchem-870	334	21	malononitrile	malononitrile	NOUN
eurjchem-870	334	22	(	(	PUNCT
eurjchem-870	334	23	0.66	0.66	NUM
eurjchem-870	334	24	 	 	SPACE
eurjchem-870	334	25	g	g	NOUN
eurjchem-870	334	26	,	,	PUNCT
eurjchem-870	334	27	0.01	0.01	NUM
eurjchem-870	334	28	 	 	SPACE
eurjchem-870	334	29	mol	mol	NOUN
eurjchem-870	334	30	)	)	PUNCT
eurjchem-870	334	31	in	in	ADP
eurjchem-870	334	32	ethanol	ethanol	NOUN
eurjchem-870	334	33	(	(	PUNCT
eurjchem-870	334	34	30	30	NUM
eurjchem-870	334	35	 	 	SPACE
eurjchem-870	334	36	ml	ml	NOUN
eurjchem-870	334	37	)	)	PUNCT
eurjchem-870	334	38	in	in	ADP
eurjchem-870	334	39	the	the	DET
eurjchem-870	334	40	presence	presence	NOUN
eurjchem-870	334	41	of	of	ADP
eurjchem-870	334	42	piperidine	piperidine	NOUN
eurjchem-870	334	43	(	(	PUNCT
eurjchem-870	334	44	1	1	NUM
eurjchem-870	334	45	 	 	SPACE
eurjchem-870	334	46	ml	ml	NOUN
eurjchem-870	334	47	)	)	PUNCT
eurjchem-870	334	48	was	be	AUX
eurjchem-870	334	49	refluxed	refluxe	VERB
eurjchem-870	334	50	for	for	ADP
eurjchem-870	334	51	10	10	NUM
eurjchem-870	334	52	 	 	SPACE
eurjchem-870	334	53	h.	h.	NOUN
eurjchem-870	334	54	after	after	ADP
eurjchem-870	334	55	cooling	cool	VERB
eurjchem-870	334	56	,	,	PUNCT
eurjchem-870	334	57	solid	solid	ADJ
eurjchem-870	334	58	crystals	crystal	NOUN
eurjchem-870	334	59	were	be	AUX
eurjchem-870	334	60	produced	produce	VERB
eurjchem-870	334	61	which	which	PRON
eurjchem-870	334	62	were	be	AUX
eurjchem-870	334	63	filtered	filter	VERB
eurjchem-870	334	64	off	off	ADP
eurjchem-870	334	65	,	,	PUNCT
eurjchem-870	334	66	dried	dry	VERB
eurjchem-870	334	67	and	and	CCONJ
eurjchem-870	334	68	recrystallized	recrystallize	VERB
eurjchem-870	334	69	from	from	ADP
eurjchem-870	334	70	ethanol	ethanol	NOUN
eurjchem-870	334	71	:	:	PUNCT
eurjchem-870	334	72	benzene	benzene	NOUN
eurjchem-870	334	73	(	(	PUNCT
eurjchem-870	334	74	2:1	2:1	NUM
eurjchem-870	334	75	)	)	PUNCT
eurjchem-870	334	76	(	(	PUNCT
eurjchem-870	334	77	scheme	scheme	NOUN
eurjchem-870	334	78	4	4	NUM
eurjchem-870	334	79	)	)	PUNCT
eurjchem-870	334	80	.	.	PUNCT
eurjchem-870	335	1	color	color	NOUN
eurjchem-870	335	2	:	:	PUNCT
eurjchem-870	335	3	brown	brown	ADJ
eurjchem-870	335	4	crystals	crystal	NOUN
eurjchem-870	335	5	.	.	PUNCT
eurjchem-870	336	1	yield	yield	NOUN
eurjchem-870	336	2	:	:	PUNCT
eurjchem-870	336	3	69	69	NUM
eurjchem-870	336	4	%	%	NOUN
eurjchem-870	336	5	.	.	PUNCT
eurjchem-870	337	1	m.p	m.p	PROPN
eurjchem-870	337	2	.	.	PROPN
eurjchem-870	337	3	:	:	PUNCT
eurjchem-870	337	4	211‐213	211‐213	NUM
eurjchem-870	337	5	°	°	SYM
eurjchem-870	337	6	c	c	NOUN
eurjchem-870	337	7	.	.	PUNCT
eurjchem-870	338	1	ft‐ir	ft‐ir	NOUN
eurjchem-870	338	2	(	(	PUNCT
eurjchem-870	338	3	kbr	kbr	PROPN
eurjchem-870	338	4	,	,	PUNCT
eurjchem-870	338	5			PROPN
eurjchem-870	338	6	,	,	PUNCT
eurjchem-870	338	7	cm‐1	cm‐1	PROPN
eurjchem-870	338	8	):	):	PUNCT
eurjchem-870	338	9	3328	3328	NUM
eurjchem-870	338	10	(	(	PUNCT
eurjchem-870	338	11	oh	oh	INTJ
eurjchem-870	338	12	)	)	PUNCT
eurjchem-870	338	13	,	,	PUNCT
eurjchem-870	338	14	2189	2189	NUM
eurjchem-870	338	15	,	,	PUNCT
eurjchem-870	338	16	2153	2153	NUM
eurjchem-870	338	17	(	(	PUNCT
eurjchem-870	338	18	c≡n	c≡n	PROPN
eurjchem-870	338	19	)	)	PUNCT
eurjchem-870	338	20	,	,	PUNCT
eurjchem-870	338	21	1639	1639	NUM
eurjchem-870	338	22	(	(	PUNCT
eurjchem-870	338	23	c	c	NOUN
eurjchem-870	338	24	=	=	NOUN
eurjchem-870	338	25	o	o	NOUN
eurjchem-870	338	26	)	)	PUNCT
eurjchem-870	338	27	,	,	PUNCT
eurjchem-870	338	28	1601	1601	NUM
eurjchem-870	338	29	(	(	PUNCT
eurjchem-870	338	30	c	c	NOUN
eurjchem-870	338	31	=	=	SYM
eurjchem-870	338	32	n	n	NUM
eurjchem-870	338	33	)	)	PUNCT
eurjchem-870	338	34	.	.	PUNCT
eurjchem-870	339	1	1h	1h	NUM
eurjchem-870	339	2	nmr	nmr	NOUN
eurjchem-870	339	3	(	(	PUNCT
eurjchem-870	339	4	300	300	NUM
eurjchem-870	339	5	mhz	mhz	NOUN
eurjchem-870	339	6	,	,	PUNCT
eurjchem-870	339	7	dmso	dmso	NOUN
eurjchem-870	339	8	,	,	PUNCT
eurjchem-870	339	9	δ	δ	PROPN
eurjchem-870	339	10	,	,	PUNCT
eurjchem-870	339	11	ppm	ppm	NUM
eurjchem-870	339	12	):	):	PUNCT
eurjchem-870	339	13	18.11	18.11	NUM
eurjchem-870	339	14	(	(	PUNCT
eurjchem-870	339	15	s	s	PROPN
eurjchem-870	339	16	,	,	PUNCT
eurjchem-870	339	17	1h	1h	NUM
eurjchem-870	339	18	,	,	PUNCT
eurjchem-870	339	19	oh	oh	INTJ
eurjchem-870	339	20	d2o	d2o	NOUN
eurjchem-870	339	21	exchangeable	exchangeable	ADJ
eurjchem-870	339	22	)	)	PUNCT
eurjchem-870	339	23	,	,	PUNCT
eurjchem-870	339	24	6.76‐8.03	6.76‐8.03	NUM
eurjchem-870	339	25	(	(	PUNCT
eurjchem-870	339	26	m	m	PROPN
eurjchem-870	339	27	,	,	PUNCT
eurjchem-870	339	28	14h	14h	NUM
eurjchem-870	339	29	,	,	PUNCT
eurjchem-870	339	30	arh	arh	PROPN
eurjchem-870	339	31	)	)	PUNCT
eurjchem-870	339	32	,	,	PUNCT
eurjchem-870	339	33	5.12	5.12	NUM
eurjchem-870	339	34	(	(	PUNCT
eurjchem-870	339	35	d	d	PROPN
eurjchem-870	339	36	,	,	PUNCT
eurjchem-870	339	37	1h	1h	NUM
eurjchem-870	339	38	,	,	PUNCT
eurjchem-870	339	39	chchcn	chchcn	PROPN
eurjchem-870	339	40	)	)	PUNCT
eurjchem-870	339	41	,	,	PUNCT
eurjchem-870	339	42	3.68	3.68	NUM
eurjchem-870	339	43	(	(	PUNCT
eurjchem-870	339	44	s	s	PROPN
eurjchem-870	339	45	,	,	PUNCT
eurjchem-870	339	46	3h	3h	NUM
eurjchem-870	339	47	,	,	PUNCT
eurjchem-870	339	48	och3	och3	ADJ
eurjchem-870	339	49	)	)	PUNCT
eurjchem-870	339	50	,	,	PUNCT
eurjchem-870	339	51	3.15	3.15	NUM
eurjchem-870	339	52	(	(	PUNCT
eurjchem-870	339	53	d	d	PROPN
eurjchem-870	339	54	,	,	PUNCT
eurjchem-870	339	55	1h	1h	NUM
eurjchem-870	339	56	,	,	PUNCT
eurjchem-870	339	57	chchcn	chchcn	PROPN
eurjchem-870	339	58	)	)	PUNCT
eurjchem-870	339	59	.	.	PUNCT
eurjchem-870	340	1	ms	ms	NOUN
eurjchem-870	340	2	(	(	PUNCT
eurjchem-870	340	3	ei	ei	PROPN
eurjchem-870	340	4	,	,	PUNCT
eurjchem-870	340	5	m	m	PROPN
eurjchem-870	340	6	/	/	SYM
eurjchem-870	340	7	z	z	PROPN
eurjchem-870	340	8	(	(	PUNCT
eurjchem-870	340	9	%	%	NOUN
eurjchem-870	340	10	)	)	PUNCT
eurjchem-870	340	11	):	):	PUNCT
eurjchem-870	340	12	420	420	NUM
eurjchem-870	340	13	(	(	PUNCT
eurjchem-870	340	14	3.1	3.1	NUM
eurjchem-870	340	15	,	,	PUNCT
eurjchem-870	340	16	m+	m+	NOUN
eurjchem-870	340	17	·	·	PUNCT
eurjchem-870	340	18	)	)	PUNCT
eurjchem-870	340	19	,	,	PUNCT
eurjchem-870	340	20	236	236	NUM
eurjchem-870	340	21	(	(	PUNCT
eurjchem-870	340	22	3.1	3.1	NUM
eurjchem-870	340	23	)	)	PUNCT
eurjchem-870	340	24	,	,	PUNCT
eurjchem-870	340	25	84	84	NUM
eurjchem-870	340	26	(	(	PUNCT
eurjchem-870	340	27	100	100	NUM
eurjchem-870	340	28	)	)	PUNCT
eurjchem-870	340	29	,	,	PUNCT
eurjchem-870	340	30	70	70	NUM
eurjchem-870	340	31	(	(	PUNCT
eurjchem-870	340	32	15.5	15.5	NUM
eurjchem-870	340	33	)	)	PUNCT
eurjchem-870	340	34	,	,	PUNCT
eurjchem-870	340	35	57	57	NUM
eurjchem-870	340	36	(	(	PUNCT
eurjchem-870	340	37	37.6	37.6	NUM
eurjchem-870	340	38	)	)	PUNCT
eurjchem-870	340	39	.	.	PUNCT
eurjchem-870	341	1	anal	anal	PROPN
eurjchem-870	341	2	.	.	PUNCT
eurjchem-870	341	3	calcd	calcd	NOUN
eurjchem-870	341	4	.	.	PUNCT
eurjchem-870	342	1	for	for	ADP
eurjchem-870	342	2	c26h20n4o2	c26h20n4o2	PROPN
eurjchem-870	342	3	:	:	PUNCT
eurjchem-870	342	4	c	c	X
eurjchem-870	342	5	,	,	PUNCT
eurjchem-870	342	6	74.27	74.27	NUM
eurjchem-870	342	7	;	;	PUNCT
eurjchem-870	342	8	h	h	NOUN
eurjchem-870	342	9	,	,	PUNCT
eurjchem-870	342	10	4.79	4.79	NUM
eurjchem-870	342	11	;	;	PUNCT
eurjchem-870	342	12	n	n	CCONJ
eurjchem-870	342	13	,	,	PUNCT
eurjchem-870	342	14	13.33	13.33	NUM
eurjchem-870	342	15	.	.	PUNCT
eurjchem-870	342	16	found	find	VERB
eurjchem-870	342	17	:	:	PUNCT
eurjchem-870	343	1	c	c	X
eurjchem-870	343	2	,	,	PUNCT
eurjchem-870	343	3	73.95	73.95	NUM
eurjchem-870	343	4	;	;	PUNCT
eurjchem-870	343	5	h	h	NOUN
eurjchem-870	343	6	,	,	PUNCT
eurjchem-870	343	7	4.64	4.64	NUM
eurjchem-870	343	8	;	;	PUNCT
eurjchem-870	343	9	n	n	CCONJ
eurjchem-870	343	10	,	,	PUNCT
eurjchem-870	343	11	13.24	13.24	NUM
eurjchem-870	343	12	%	%	NOUN
eurjchem-870	343	13	.	.	PUNCT
eurjchem-870	344	1	2.2.24	2.2.24	X
eurjchem-870	344	2	.	.	PUNCT
eurjchem-870	345	1	[	[	X
eurjchem-870	345	2	5‐amino‐4‐(4‐methoxyphenyl)‐1,3‐diphenyl‐1,4‐	5‐amino‐4‐(4‐methoxyphenyl)‐1,3‐diphenyl‐1,4‐	NUM
eurjchem-870	345	3	dihydro‐9‐oxa‐1,2,6,8‐tetraaza‐cyclopenta[b]naphthalen‐7‐	dihydro‐9‐oxa‐1,2,6,8‐tetraaza‐cyclopenta[b]naphthalen‐7‐	PROPN
eurjchem-870	345	4	yl	yl	NOUN
eurjchem-870	345	5	]	]	X
eurjchem-870	345	6	acetonitrile	acetonitrile	NOUN
eurjchem-870	345	7	(	(	PUNCT
eurjchem-870	345	8	30	30	NUM
eurjchem-870	345	9	)	)	PUNCT
eurjchem-870	345	10	a	a	DET
eurjchem-870	345	11	mixture	mixture	NOUN
eurjchem-870	345	12	of	of	ADP
eurjchem-870	345	13	pyrazolone	pyrazolone	NOUN
eurjchem-870	345	14	19	19	NUM
eurjchem-870	345	15	(	(	PUNCT
eurjchem-870	345	16	0.708	0.708	NUM
eurjchem-870	345	17	 	 	SPACE
eurjchem-870	345	18	g	g	NOUN
eurjchem-870	345	19	,	,	PUNCT
eurjchem-870	345	20	0.002	0.002	NUM
eurjchem-870	345	21	 	 	SPACE
eurjchem-870	345	22	mol	mol	NOUN
eurjchem-870	345	23	)	)	PUNCT
eurjchem-870	345	24	,	,	PUNCT
eurjchem-870	345	25	malononitrile	malononitrile	NOUN
eurjchem-870	345	26	(	(	PUNCT
eurjchem-870	345	27	0.132	0.132	NUM
eurjchem-870	345	28	 	 	SPACE
eurjchem-870	345	29	g	g	NOUN
eurjchem-870	345	30	,	,	PUNCT
eurjchem-870	345	31	0.002	0.002	NUM
eurjchem-870	345	32	 	 	SPACE
eurjchem-870	345	33	mol	mol	NOUN
eurjchem-870	345	34	)	)	PUNCT
eurjchem-870	345	35	in	in	ADP
eurjchem-870	345	36	sodium	sodium	NOUN
eurjchem-870	345	37	ethoxide	ethoxide	NOUN
eurjchem-870	345	38	(	(	PUNCT
eurjchem-870	345	39	1	1	NUM
eurjchem-870	345	40	%	%	NOUN
eurjchem-870	345	41	)	)	PUNCT
eurjchem-870	345	42	solution	solution	NOUN
eurjchem-870	345	43	was	be	AUX
eurjchem-870	345	44	refluxed	refluxe	VERB
eurjchem-870	345	45	for	for	ADP
eurjchem-870	345	46	6	6	NUM
eurjchem-870	345	47	 	 	SPACE
eurjchem-870	345	48	h.	h.	NOUN
eurjchem-870	345	49	the	the	DET
eurjchem-870	345	50	mixture	mixture	NOUN
eurjchem-870	345	51	was	be	AUX
eurjchem-870	345	52	poured	pour	VERB
eurjchem-870	345	53	onto	onto	ADP
eurjchem-870	345	54	ice	ice	NOUN
eurjchem-870	345	55	:	:	PUNCT
eurjchem-870	345	56	hydrochloric	hydrochloric	ADJ
eurjchem-870	345	57	acid	acid	NOUN
eurjchem-870	345	58	,	,	PUNCT
eurjchem-870	345	59	the	the	DET
eurjchem-870	345	60	solid	solid	ADJ
eurjchem-870	345	61	that	that	PRON
eurjchem-870	345	62	separated	separate	VERB
eurjchem-870	345	63	was	be	AUX
eurjchem-870	345	64	filtered	filter	VERB
eurjchem-870	345	65	off	off	ADP
eurjchem-870	345	66	,	,	PUNCT
eurjchem-870	345	67	washed	wash	VERB
eurjchem-870	345	68	with	with	ADP
eurjchem-870	345	69	water	water	NOUN
eurjchem-870	345	70	,	,	PUNCT
eurjchem-870	345	71	dried	dry	VERB
eurjchem-870	345	72	and	and	CCONJ
eurjchem-870	345	73	recrystallized	recrystallize	VERB
eurjchem-870	345	74	from	from	ADP
eurjchem-870	345	75	benzene	benzene	NOUN
eurjchem-870	345	76	(	(	PUNCT
eurjchem-870	345	77	scheme	scheme	NOUN
eurjchem-870	345	78	4	4	NUM
eurjchem-870	345	79	)	)	PUNCT
eurjchem-870	345	80	.	.	PUNCT
eurjchem-870	346	1	color	color	NOUN
eurjchem-870	346	2	:	:	PUNCT
eurjchem-870	346	3	pale	pale	ADJ
eurjchem-870	346	4	yellow	yellow	ADJ
eurjchem-870	346	5	.	.	PUNCT
eurjchem-870	347	1	yield	yield	NOUN
eurjchem-870	347	2	:	:	PUNCT
eurjchem-870	347	3	40	40	NUM
eurjchem-870	347	4	%	%	NOUN
eurjchem-870	347	5	.	.	PUNCT
eurjchem-870	348	1	m.p	m.p	PROPN
eurjchem-870	348	2	.	.	PROPN
eurjchem-870	348	3	:	:	PUNCT
eurjchem-870	348	4	117‐119	117‐119	NUM
eurjchem-870	348	5	°	°	NUM
eurjchem-870	348	6	c	c	NOUN
eurjchem-870	348	7	.	.	PUNCT
eurjchem-870	349	1	ft‐ir	ft‐ir	NOUN
eurjchem-870	349	2	(	(	PUNCT
eurjchem-870	349	3	kbr	kbr	PROPN
eurjchem-870	349	4	,	,	PUNCT
eurjchem-870	349	5			PROPN
eurjchem-870	349	6	,	,	PUNCT
eurjchem-870	349	7	cm‐1	cm‐1	PROPN
eurjchem-870	349	8	):	):	PUNCT
eurjchem-870	349	9	3424	3424	NUM
eurjchem-870	349	10	,	,	PUNCT
eurjchem-870	349	11	3322	3322	NUM
eurjchem-870	349	12	(	(	PUNCT
eurjchem-870	349	13	nh2	nh2	PROPN
eurjchem-870	349	14	)	)	PUNCT
eurjchem-870	349	15	,	,	PUNCT
eurjchem-870	349	16	2213	2213	NUM
eurjchem-870	349	17	(	(	PUNCT
eurjchem-870	349	18	c≡n	c≡n	PROPN
eurjchem-870	349	19	)	)	PUNCT
eurjchem-870	349	20	,	,	PUNCT
eurjchem-870	349	21	1642	1642	NUM
eurjchem-870	349	22	(	(	PUNCT
eurjchem-870	349	23	c	c	NOUN
eurjchem-870	349	24	=	=	SYM
eurjchem-870	349	25	n	n	NUM
eurjchem-870	349	26	)	)	PUNCT
eurjchem-870	349	27	,	,	PUNCT
eurjchem-870	349	28	1602	1602	NUM
eurjchem-870	349	29	(	(	PUNCT
eurjchem-870	349	30	c	c	NOUN
eurjchem-870	349	31	=	=	SYM
eurjchem-870	349	32	c	c	NOUN
eurjchem-870	349	33	)	)	PUNCT
eurjchem-870	349	34	.	.	PUNCT
eurjchem-870	350	1	1h	1h	NUM
eurjchem-870	350	2	nmr	nmr	NOUN
eurjchem-870	350	3	(	(	PUNCT
eurjchem-870	350	4	300	300	NUM
eurjchem-870	350	5	mhz	mhz	NOUN
eurjchem-870	350	6	,	,	PUNCT
eurjchem-870	350	7	dmso	dmso	NOUN
eurjchem-870	350	8	,	,	PUNCT
eurjchem-870	350	9	δ	δ	PROPN
eurjchem-870	350	10	,	,	PUNCT
eurjchem-870	350	11	ppm	ppm	NOUN
eurjchem-870	350	12	):	):	PUNCT
eurjchem-870	350	13	7.07‐	7.07‐	NUM
eurjchem-870	350	14	7.83	7.83	NUM
eurjchem-870	350	15	(	(	PUNCT
eurjchem-870	350	16	m	m	PROPN
eurjchem-870	350	17	,	,	PUNCT
eurjchem-870	350	18	15h	15h	NUM
eurjchem-870	350	19	,	,	PUNCT
eurjchem-870	350	20	14arh	14arh	INTJ
eurjchem-870	350	21	,	,	PUNCT
eurjchem-870	350	22	1h	1h	NUM
eurjchem-870	350	23	benzilic	benzilic	NOUN
eurjchem-870	350	24	)	)	PUNCT
eurjchem-870	350	25	,	,	PUNCT
eurjchem-870	350	26	6.00	6.00	NUM
eurjchem-870	350	27	(	(	PUNCT
eurjchem-870	350	28	s	s	PROPN
eurjchem-870	350	29	,	,	PUNCT
eurjchem-870	350	30	2h	2h	NUM
eurjchem-870	350	31	,	,	PUNCT
eurjchem-870	350	32	nh2	nh2	PROPN
eurjchem-870	350	33	d2o	d2o	PROPN
eurjchem-870	350	34	exchangeable	exchangeable	ADJ
eurjchem-870	350	35	)	)	PUNCT
eurjchem-870	350	36	,	,	PUNCT
eurjchem-870	350	37	3.82	3.82	NUM
eurjchem-870	350	38	(	(	PUNCT
eurjchem-870	350	39	s	s	PROPN
eurjchem-870	350	40	,	,	PUNCT
eurjchem-870	350	41	2h	2h	NUM
eurjchem-870	350	42	,	,	PUNCT
eurjchem-870	350	43	ch2cn	ch2cn	NUM
eurjchem-870	350	44	)	)	PUNCT
eurjchem-870	350	45	,	,	PUNCT
eurjchem-870	350	46	3.35	3.35	NUM
eurjchem-870	350	47	(	(	PUNCT
eurjchem-870	350	48	s	s	PROPN
eurjchem-870	350	49	,	,	PUNCT
eurjchem-870	350	50	3h	3h	NUM
eurjchem-870	350	51	,	,	PUNCT
eurjchem-870	350	52	och3	och3	ADJ
eurjchem-870	350	53	)	)	PUNCT
eurjchem-870	350	54	.	.	PUNCT
eurjchem-870	351	1	ms	ms	NOUN
eurjchem-870	351	2	(	(	PUNCT
eurjchem-870	351	3	ei	ei	PROPN
eurjchem-870	351	4	,	,	PUNCT
eurjchem-870	351	5	m	m	PROPN
eurjchem-870	351	6	/	/	SYM
eurjchem-870	351	7	z	z	PROPN
eurjchem-870	351	8	(	(	PUNCT
eurjchem-870	351	9	%	%	NOUN
eurjchem-870	351	10	)	)	PUNCT
eurjchem-870	351	11	):	):	PUNCT
eurjchem-870	351	12	443	443	NUM
eurjchem-870	351	13	(	(	PUNCT
eurjchem-870	351	14	54.5	54.5	NUM
eurjchem-870	351	15	,	,	PUNCT
eurjchem-870	351	16	[	[	X
eurjchem-870	351	17	m‐chno·]+	m‐chno·]+	ADJ
eurjchem-870	351	18	)	)	PUNCT
eurjchem-870	351	19	,	,	PUNCT
eurjchem-870	351	20	295	295	NUM
eurjchem-870	351	21	(	(	PUNCT
eurjchem-870	351	22	45.5	45.5	NUM
eurjchem-870	351	23	)	)	PUNCT
eurjchem-870	351	24	,	,	PUNCT
eurjchem-870	351	25	138	138	NUM
eurjchem-870	351	26	(	(	PUNCT
eurjchem-870	351	27	45.5	45.5	NUM
eurjchem-870	351	28	)	)	PUNCT
eurjchem-870	351	29	,	,	PUNCT
eurjchem-870	351	30	122	122	NUM
eurjchem-870	351	31	(	(	PUNCT
eurjchem-870	351	32	54.5	54.5	NUM
eurjchem-870	351	33	)	)	PUNCT
eurjchem-870	351	34	,	,	PUNCT
eurjchem-870	351	35	109	109	NUM
eurjchem-870	351	36	(	(	PUNCT
eurjchem-870	351	37	72.7	72.7	NUM
eurjchem-870	351	38	)	)	PUNCT
eurjchem-870	351	39	,	,	PUNCT
eurjchem-870	351	40	108	108	NUM
eurjchem-870	351	41	(	(	PUNCT
eurjchem-870	351	42	63.6	63.6	NUM
eurjchem-870	351	43	)	)	PUNCT
eurjchem-870	351	44	,	,	PUNCT
eurjchem-870	351	45	93	93	NUM
eurjchem-870	351	46	(	(	PUNCT
eurjchem-870	351	47	27.2	27.2	NUM
eurjchem-870	351	48	)	)	PUNCT
eurjchem-870	351	49	,	,	PUNCT
eurjchem-870	351	50	67	67	NUM
eurjchem-870	351	51	(	(	PUNCT
eurjchem-870	351	52	72.7)52	72.7)52	NUM
eurjchem-870	351	53	(	(	PUNCT
eurjchem-870	351	54	100	100	NUM
eurjchem-870	351	55	)	)	PUNCT
eurjchem-870	351	56	.	.	PUNCT
eurjchem-870	352	1	anal	anal	PROPN
eurjchem-870	352	2	.	.	PUNCT
eurjchem-870	352	3	calcd	calcd	NOUN
eurjchem-870	352	4	.	.	PUNCT
eurjchem-870	353	1	for	for	ADP
eurjchem-870	353	2	c29h22n6o2	c29h22n6o2	NOUN
eurjchem-870	353	3	:	:	PUNCT
eurjchem-870	353	4	c	c	X
eurjchem-870	353	5	,	,	PUNCT
eurjchem-870	353	6	71.59	71.59	NUM
eurjchem-870	353	7	;	;	PUNCT
eurjchem-870	353	8	h	h	NOUN
eurjchem-870	353	9	,	,	PUNCT
eurjchem-870	353	10	4.56	4.56	NUM
eurjchem-870	353	11	;	;	PUNCT
eurjchem-870	353	12	n	n	CCONJ
eurjchem-870	353	13	,	,	PUNCT
eurjchem-870	353	14	17.27	17.27	NUM
eurjchem-870	353	15	.	.	PUNCT
eurjchem-870	353	16	found	find	VERB
eurjchem-870	353	17	:	:	PUNCT
eurjchem-870	354	1	c	c	X
eurjchem-870	354	2	,	,	PUNCT
eurjchem-870	354	3	71.61	71.61	NUM
eurjchem-870	354	4	;	;	PUNCT
eurjchem-870	355	1	h	h	NOUN
eurjchem-870	355	2	,	,	PUNCT
eurjchem-870	355	3	4.71	4.71	NUM
eurjchem-870	355	4	;	;	PUNCT
eurjchem-870	355	5	n	n	CCONJ
eurjchem-870	355	6	,	,	PUNCT
eurjchem-870	355	7	17.41	17.41	NUM
eurjchem-870	355	8	%	%	NOUN
eurjchem-870	355	9	.	.	PUNCT
eurjchem-870	356	1	2.2.25	2.2.25	NUM
eurjchem-870	356	2	.	.	PUNCT
eurjchem-870	357	1	[	[	X
eurjchem-870	357	2	5‐amino‐4‐(4‐methoxyphenyl)‐1,3‐diphenyl‐4,9‐	5‐amino‐4‐(4‐methoxyphenyl)‐1,3‐diphenyl‐4,9‐	NUM
eurjchem-870	357	3	dihydro‐1h‐pyrazolo[4’,3’:5,6]pyrido[2,3‐d]pyrimidin‐7‐	dihydro‐1h‐pyrazolo[4’,3’:5,6]pyrido[2,3‐d]pyrimidin‐7‐	NUM
eurjchem-870	357	4	yl]acetonitrile	yl]acetonitrile	NOUN
eurjchem-870	357	5	(	(	PUNCT
eurjchem-870	357	6	31	31	NUM
eurjchem-870	357	7	)	)	PUNCT
eurjchem-870	357	8	a	a	DET
eurjchem-870	357	9	mixture	mixture	NOUN
eurjchem-870	357	10	of	of	ADP
eurjchem-870	357	11	pyrazolone	pyrazolone	NOUN
eurjchem-870	357	12	19	19	NUM
eurjchem-870	357	13	(	(	PUNCT
eurjchem-870	357	14	0.708	0.708	NUM
eurjchem-870	357	15	 	 	SPACE
eurjchem-870	357	16	g	g	NOUN
eurjchem-870	357	17	,	,	PUNCT
eurjchem-870	357	18	0.002	0.002	NUM
eurjchem-870	357	19	 	 	SPACE
eurjchem-870	357	20	mol	mol	NOUN
eurjchem-870	357	21	)	)	PUNCT
eurjchem-870	357	22	,	,	PUNCT
eurjchem-870	357	23	malononitrile	malononitrile	NOUN
eurjchem-870	357	24	(	(	PUNCT
eurjchem-870	357	25	0.132	0.132	NUM
eurjchem-870	357	26	 	 	SPACE
eurjchem-870	357	27	g	g	NOUN
eurjchem-870	357	28	,	,	PUNCT
eurjchem-870	357	29	0.002	0.002	NUM
eurjchem-870	357	30	 	 	SPACE
eurjchem-870	357	31	mol	mol	NOUN
eurjchem-870	357	32	)	)	PUNCT
eurjchem-870	357	33	and	and	CCONJ
eurjchem-870	357	34	ammonium	ammonium	NOUN
eurjchem-870	357	35	acetate	acetate	NOUN
eurjchem-870	357	36	(	(	PUNCT
eurjchem-870	357	37	2	2	NUM
eurjchem-870	357	38	 	 	SPACE
eurjchem-870	357	39	g	g	NOUN
eurjchem-870	357	40	)	)	PUNCT
eurjchem-870	357	41	was	be	AUX
eurjchem-870	357	42	fused	fuse	VERB
eurjchem-870	357	43	for	for	ADP
eurjchem-870	357	44	7	7	NUM
eurjchem-870	357	45	 	 	SPACE
eurjchem-870	357	46	h	h	NOUN
eurjchem-870	357	47	at	at	ADP
eurjchem-870	357	48	170	170	NUM
eurjchem-870	357	49	°	°	NOUN
eurjchem-870	357	50	c	c	NOUN
eurjchem-870	357	51	.	.	PUNCT
eurjchem-870	358	1	after	after	ADP
eurjchem-870	358	2	cooling	cool	VERB
eurjchem-870	358	3	,	,	PUNCT
eurjchem-870	358	4	the	the	DET
eurjchem-870	358	5	solid	solid	ADJ
eurjchem-870	358	6	was	be	AUX
eurjchem-870	358	7	washed	wash	VERB
eurjchem-870	358	8	with	with	ADP
eurjchem-870	358	9	water	water	NOUN
eurjchem-870	358	10	,	,	PUNCT
eurjchem-870	358	11	filtered	filter	VERB
eurjchem-870	358	12	off	off	ADP
eurjchem-870	358	13	,	,	PUNCT
eurjchem-870	358	14	dried	dry	VERB
eurjchem-870	358	15	,	,	PUNCT
eurjchem-870	358	16	and	and	CCONJ
eurjchem-870	358	17	recrystallized	recrystallize	VERB
eurjchem-870	358	18	from	from	ADP
eurjchem-870	358	19	benzene	benzene	NOUN
eurjchem-870	358	20	:	:	PUNCT
eurjchem-870	358	21	ethanol	ethanol	NOUN
eurjchem-870	358	22	(	(	PUNCT
eurjchem-870	358	23	1:2	1:2	NUM
eurjchem-870	358	24	)	)	PUNCT
eurjchem-870	358	25	(	(	PUNCT
eurjchem-870	358	26	scheme	scheme	NOUN
eurjchem-870	358	27	4	4	NUM
eurjchem-870	358	28	)	)	PUNCT
eurjchem-870	358	29	.	.	PUNCT
eurjchem-870	359	1	color	color	NOUN
eurjchem-870	359	2	:	:	PUNCT
eurjchem-870	359	3	pale	pale	ADJ
eurjchem-870	359	4	yellow	yellow	ADJ
eurjchem-870	359	5	.	.	PUNCT
eurjchem-870	360	1	yield	yield	NOUN
eurjchem-870	360	2	:	:	PUNCT
eurjchem-870	360	3	40	40	NUM
eurjchem-870	360	4	%	%	NOUN
eurjchem-870	360	5	.	.	PUNCT
eurjchem-870	361	1	m.p	m.p	PROPN
eurjchem-870	361	2	.	.	PROPN
eurjchem-870	361	3	:	:	PUNCT
eurjchem-870	362	1	190‐192	190‐192	NUM
eurjchem-870	362	2	°	°	ADP
eurjchem-870	362	3	c	c	X
eurjchem-870	362	4	.	.	PUNCT
eurjchem-870	363	1	ft‐ir	ft‐ir	NOUN
eurjchem-870	363	2	(	(	PUNCT
eurjchem-870	363	3	kbr	kbr	PROPN
eurjchem-870	363	4	,	,	PUNCT
eurjchem-870	363	5			PROPN
eurjchem-870	363	6	,	,	PUNCT
eurjchem-870	363	7	cm‐1	cm‐1	PROPN
eurjchem-870	363	8	):	):	PUNCT
eurjchem-870	363	9	3428	3428	NUM
eurjchem-870	363	10	,	,	PUNCT
eurjchem-870	363	11	3321	3321	NUM
eurjchem-870	363	12	(	(	PUNCT
eurjchem-870	363	13	nh	nh	PROPN
eurjchem-870	363	14	,	,	PUNCT
eurjchem-870	363	15	nh2	nh2	PROPN
eurjchem-870	363	16	)	)	PUNCT
eurjchem-870	363	17	,	,	PUNCT
eurjchem-870	363	18	2203	2203	NUM
eurjchem-870	363	19	(	(	PUNCT
eurjchem-870	363	20	c≡n	c≡n	PROPN
eurjchem-870	363	21	)	)	PUNCT
eurjchem-870	363	22	,	,	PUNCT
eurjchem-870	363	23	1599	1599	NUM
eurjchem-870	363	24	(	(	PUNCT
eurjchem-870	363	25	c	c	X
eurjchem-870	363	26	=	=	SYM
eurjchem-870	363	27	c	c	NOUN
eurjchem-870	363	28	)	)	PUNCT
eurjchem-870	363	29	.	.	PUNCT
eurjchem-870	364	1	1h	1h	NUM
eurjchem-870	364	2	nmr	nmr	NOUN
eurjchem-870	364	3	(	(	PUNCT
eurjchem-870	364	4	300	300	NUM
eurjchem-870	364	5	mhz	mhz	NOUN
eurjchem-870	364	6	,	,	PUNCT
eurjchem-870	364	7	dmso	dmso	NOUN
eurjchem-870	364	8	,	,	PUNCT
eurjchem-870	364	9	δ	δ	PROPN
eurjchem-870	364	10	,	,	PUNCT
eurjchem-870	364	11	ppm	ppm	NUM
eurjchem-870	364	12	):	):	PUNCT
eurjchem-870	364	13	7.05‐8.32	7.05‐8.32	NUM
eurjchem-870	364	14	(	(	PUNCT
eurjchem-870	364	15	m	m	PROPN
eurjchem-870	364	16	,	,	PUNCT
eurjchem-870	364	17	14h	14h	NUM
eurjchem-870	364	18	,	,	PUNCT
eurjchem-870	364	19	arh	arh	PROPN
eurjchem-870	364	20	)	)	PUNCT
eurjchem-870	364	21	,	,	PUNCT
eurjchem-870	364	22	5.95	5.95	NUM
eurjchem-870	364	23	(	(	PUNCT
eurjchem-870	364	24	s	s	PROPN
eurjchem-870	364	25	,	,	PUNCT
eurjchem-870	364	26	1h	1h	NUM
eurjchem-870	364	27	,	,	PUNCT
eurjchem-870	364	28	benzilic	benzilic	NOUN
eurjchem-870	364	29	)	)	PUNCT
eurjchem-870	364	30	,	,	PUNCT
eurjchem-870	364	31	5.70	5.70	NUM
eurjchem-870	364	32	(	(	PUNCT
eurjchem-870	364	33	s	s	PROPN
eurjchem-870	364	34	,	,	PUNCT
eurjchem-870	364	35	2h	2h	NUM
eurjchem-870	364	36	,	,	PUNCT
eurjchem-870	364	37	nh2	nh2	PROPN
eurjchem-870	364	38	d2o	d2o	PROPN
eurjchem-870	364	39	exchangeable	exchangeable	ADJ
eurjchem-870	364	40	)	)	PUNCT
eurjchem-870	364	41	,	,	PUNCT
eurjchem-870	364	42	5.66	5.66	NUM
eurjchem-870	364	43	(	(	PUNCT
eurjchem-870	364	44	s	s	PROPN
eurjchem-870	364	45	,	,	PUNCT
eurjchem-870	364	46	1h	1h	NUM
eurjchem-870	364	47	,	,	PUNCT
eurjchem-870	364	48	nh	nh	PROPN
eurjchem-870	364	49	d2o	d2o	PROPN
eurjchem-870	364	50	exchangeable	exchangeable	ADJ
eurjchem-870	364	51	)	)	PUNCT
eurjchem-870	364	52	,	,	PUNCT
eurjchem-870	364	53	3.84	3.84	NUM
eurjchem-870	364	54	(	(	PUNCT
eurjchem-870	364	55	s	s	PROPN
eurjchem-870	364	56	,	,	PUNCT
eurjchem-870	364	57	3h	3h	NUM
eurjchem-870	364	58	,	,	PUNCT
eurjchem-870	364	59	och3	och3	ADJ
eurjchem-870	364	60	)	)	PUNCT
eurjchem-870	364	61	,	,	PUNCT
eurjchem-870	364	62	3.67	3.67	NUM
eurjchem-870	364	63	(	(	PUNCT
eurjchem-870	364	64	s	s	PROPN
eurjchem-870	364	65	,	,	PUNCT
eurjchem-870	364	66	2h	2h	NUM
eurjchem-870	364	67	,	,	PUNCT
eurjchem-870	364	68	ch2cn	ch2cn	NUM
eurjchem-870	364	69	)	)	PUNCT
eurjchem-870	364	70	.	.	PUNCT
eurjchem-870	365	1	ms	ms	NOUN
eurjchem-870	365	2	(	(	PUNCT
eurjchem-870	365	3	ei	ei	PROPN
eurjchem-870	365	4	,	,	PUNCT
eurjchem-870	365	5	m	m	PROPN
eurjchem-870	365	6	/	/	SYM
eurjchem-870	365	7	z	z	PROPN
eurjchem-870	365	8	(	(	PUNCT
eurjchem-870	365	9	%	%	NOUN
eurjchem-870	365	10	)	)	PUNCT
eurjchem-870	365	11	):	):	PUNCT
eurjchem-870	365	12	435	435	NUM
eurjchem-870	365	13	(	(	PUNCT
eurjchem-870	365	14	10.6	10.6	NUM
eurjchem-870	365	15	,	,	PUNCT
eurjchem-870	365	16	[	[	X
eurjchem-870	365	17	m‐	m‐	X
eurjchem-870	365	18	c2h4n2·]+	c2h4n2·]+	PROPN
eurjchem-870	365	19	)	)	PUNCT
eurjchem-870	365	20	,	,	PUNCT
eurjchem-870	365	21	435	435	NUM
eurjchem-870	365	22	(	(	PUNCT
eurjchem-870	365	23	10.6	10.6	NUM
eurjchem-870	365	24	)	)	PUNCT
eurjchem-870	365	25	,	,	PUNCT
eurjchem-870	365	26	236	236	NUM
eurjchem-870	365	27	(	(	PUNCT
eurjchem-870	365	28	36.2	36.2	NUM
eurjchem-870	365	29	)	)	PUNCT
eurjchem-870	365	30	,	,	PUNCT
eurjchem-870	365	31	160	160	NUM
eurjchem-870	365	32	(	(	PUNCT
eurjchem-870	365	33	12.8	12.8	NUM
eurjchem-870	365	34	)	)	PUNCT
eurjchem-870	365	35	,	,	PUNCT
eurjchem-870	365	36	93	93	NUM
eurjchem-870	365	37	(	(	PUNCT
eurjchem-870	365	38	51.1	51.1	NUM
eurjchem-870	365	39	)	)	PUNCT
eurjchem-870	365	40	,	,	PUNCT
eurjchem-870	365	41	84	84	NUM
eurjchem-870	365	42	(	(	PUNCT
eurjchem-870	365	43	36.2	36.2	NUM
eurjchem-870	365	44	)	)	PUNCT
eurjchem-870	365	45	,	,	PUNCT
eurjchem-870	365	46	78	78	NUM
eurjchem-870	365	47	(	(	PUNCT
eurjchem-870	365	48	29.8	29.8	NUM
eurjchem-870	365	49	)	)	PUNCT
eurjchem-870	365	50	,	,	PUNCT
eurjchem-870	365	51	77	77	NUM
eurjchem-870	365	52	(	(	PUNCT
eurjchem-870	365	53	100	100	NUM
eurjchem-870	365	54	)	)	PUNCT
eurjchem-870	365	55	,	,	PUNCT
eurjchem-870	365	56	56	56	NUM
eurjchem-870	365	57	(	(	PUNCT
eurjchem-870	365	58	55.3	55.3	NUM
eurjchem-870	365	59	)	)	PUNCT
eurjchem-870	365	60	.	.	PUNCT
eurjchem-870	366	1	anal	anal	PROPN
eurjchem-870	366	2	.	.	PUNCT
eurjchem-870	366	3	calcd	calcd	NOUN
eurjchem-870	366	4	.	.	PUNCT
eurjchem-870	367	1	for	for	SCONJ
eurjchem-870	367	2	c29h23n7o	c29h23n7o	PROPN
eurjchem-870	367	3	:	:	PUNCT
eurjchem-870	367	4	c	c	X
eurjchem-870	367	5	,	,	PUNCT
eurjchem-870	367	6	71.74	71.74	NUM
eurjchem-870	367	7	;	;	PUNCT
eurjchem-870	367	8	h	h	NOUN
eurjchem-870	367	9	,	,	PUNCT
eurjchem-870	367	10	4.77	4.77	NUM
eurjchem-870	367	11	;	;	PUNCT
eurjchem-870	367	12	n	n	CCONJ
eurjchem-870	367	13	,	,	PUNCT
eurjchem-870	367	14	20.19	20.19	NUM
eurjchem-870	367	15	.	.	PUNCT
eurjchem-870	367	16	found	find	VERB
eurjchem-870	367	17	:	:	PUNCT
eurjchem-870	368	1	c	c	X
eurjchem-870	368	2	,	,	PUNCT
eurjchem-870	368	3	71.82	71.82	NUM
eurjchem-870	368	4	;	;	PUNCT
eurjchem-870	368	5	h	h	NOUN
eurjchem-870	368	6	,	,	PUNCT
eurjchem-870	368	7	4.93	4.93	NUM
eurjchem-870	368	8	;	;	PUNCT
eurjchem-870	368	9	n	n	CCONJ
eurjchem-870	368	10	,	,	PUNCT
eurjchem-870	368	11	20.23	20.23	NUM
eurjchem-870	368	12	%	%	NOUN
eurjchem-870	368	13	.	.	PUNCT
eurjchem-870	369	1	2.2.26	2.2.26	X
eurjchem-870	369	2	.	.	PUNCT
eurjchem-870	369	3	4‐((5‐hydroxy‐1,3diphenyl‐1h‐pyrazol‐4‐yl)(4‐	4‐((5‐hydroxy‐1,3diphenyl‐1h‐pyrazol‐4‐yl)(4‐	NOUN
eurjchem-870	369	4	methoxyphenyl)methyl)‐1,3‐diphenyl‐1h‐pyrazol‐5‐ol	methoxyphenyl)methyl)‐1,3‐diphenyl‐1h‐pyrazol‐5‐ol	NOUN
eurjchem-870	369	5	(	(	PUNCT
eurjchem-870	369	6	32	32	NUM
eurjchem-870	369	7	)	)	PUNCT
eurjchem-870	369	8	pyrazolone	pyrazolone	NOUN
eurjchem-870	369	9	19	19	NUM
eurjchem-870	369	10	(	(	PUNCT
eurjchem-870	369	11	3.54	3.54	NUM
eurjchem-870	369	12	 	 	SPACE
eurjchem-870	369	13	g	g	NOUN
eurjchem-870	369	14	,	,	PUNCT
eurjchem-870	369	15	0.01	0.01	NUM
eurjchem-870	369	16	 	 	SPACE
eurjchem-870	369	17	mol	mol	NOUN
eurjchem-870	369	18	)	)	PUNCT
eurjchem-870	369	19	was	be	AUX
eurjchem-870	369	20	added	add	VERB
eurjchem-870	369	21	at	at	ADP
eurjchem-870	369	22	room	room	NOUN
eurjchem-870	369	23	temperature	temperature	NOUN
eurjchem-870	369	24	with	with	ADP
eurjchem-870	369	25	stirring	stir	VERB
eurjchem-870	369	26	to	to	ADP
eurjchem-870	369	27	a	a	DET
eurjchem-870	369	28	mixture	mixture	NOUN
eurjchem-870	369	29	of	of	ADP
eurjchem-870	369	30	pyrazolone	pyrazolone	NOUN
eurjchem-870	369	31	3	3	NUM
eurjchem-870	369	32	(	(	PUNCT
eurjchem-870	369	33	2.36	2.36	NUM
eurjchem-870	369	34	 	 	SPACE
eurjchem-870	369	35	g	g	NOUN
eurjchem-870	369	36	,	,	PUNCT
eurjchem-870	369	37	0.01	0.01	NUM
eurjchem-870	369	38	 	 	SPACE
eurjchem-870	369	39	mol	mol	NOUN
eurjchem-870	369	40	)	)	PUNCT
eurjchem-870	369	41	,	,	PUNCT
eurjchem-870	369	42	and	and	CCONJ
eurjchem-870	369	43	sodium	sodium	NOUN
eurjchem-870	369	44	ethoxide	ethoxide	NOUN
eurjchem-870	369	45	(	(	PUNCT
eurjchem-870	369	46	0.5	0.5	NUM
eurjchem-870	369	47	 	 	SPACE
eurjchem-870	369	48	g	g	NOUN
eurjchem-870	369	49	sodium	sodium	NOUN
eurjchem-870	369	50	in	in	ADP
eurjchem-870	369	51	10	10	NUM
eurjchem-870	369	52	 	 	SPACE
eurjchem-870	369	53	ml	ml	NOUN
eurjchem-870	369	54	)	)	PUNCT
eurjchem-870	369	55	,	,	PUNCT
eurjchem-870	369	56	then	then	ADV
eurjchem-870	369	57	the	the	DET
eurjchem-870	369	58	mixture	mixture	NOUN
eurjchem-870	369	59	was	be	AUX
eurjchem-870	369	60	stirred	stir	VERB
eurjchem-870	369	61	for	for	ADP
eurjchem-870	369	62	another	another	DET
eurjchem-870	369	63	1	1	NUM
eurjchem-870	369	64	 	 	SPACE
eurjchem-870	369	65	h	h	NOUN
eurjchem-870	369	66	at	at	ADP
eurjchem-870	369	67	100	100	NUM
eurjchem-870	369	68	°	°	NOUN
eurjchem-870	369	69	c	c	NOUN
eurjchem-870	369	70	.	.	PUNCT
eurjchem-870	370	1	the	the	DET
eurjchem-870	370	2	mixture	mixture	NOUN
eurjchem-870	370	3	was	be	AUX
eurjchem-870	370	4	poured	pour	VERB
eurjchem-870	370	5	onto	onto	ADP
eurjchem-870	370	6	ice	ice	NOUN
eurjchem-870	370	7	:	:	PUNCT
eurjchem-870	370	8	hydrochloric	hydrochloric	ADJ
eurjchem-870	370	9	acid	acid	NOUN
eurjchem-870	370	10	(	(	PUNCT
eurjchem-870	370	11	1:3	1:3	NUM
eurjchem-870	370	12	)	)	PUNCT
eurjchem-870	370	13	,	,	PUNCT
eurjchem-870	370	14	the	the	DET
eurjchem-870	370	15	separated	separate	VERB
eurjchem-870	370	16	solid	solid	ADJ
eurjchem-870	370	17	was	be	AUX
eurjchem-870	370	18	filtered	filter	VERB
eurjchem-870	370	19	off	off	ADP
eurjchem-870	370	20	,	,	PUNCT
eurjchem-870	370	21	washed	wash	VERB
eurjchem-870	370	22	with	with	ADP
eurjchem-870	370	23	water	water	NOUN
eurjchem-870	370	24	,	,	PUNCT
eurjchem-870	370	25	dried	dry	VERB
eurjchem-870	370	26	and	and	CCONJ
eurjchem-870	370	27	recrystallized	recrystallize	VERB
eurjchem-870	370	28	from	from	ADP
eurjchem-870	370	29	ethanol	ethanol	NOUN
eurjchem-870	370	30	(	(	PUNCT
eurjchem-870	370	31	scheme	scheme	NOUN
eurjchem-870	370	32	4	4	NUM
eurjchem-870	370	33	)	)	PUNCT
eurjchem-870	370	34	.	.	PUNCT
eurjchem-870	371	1	color	color	NOUN
eurjchem-870	371	2	:	:	PUNCT
eurjchem-870	371	3	red	red	ADJ
eurjchem-870	371	4	.	.	PUNCT
eurjchem-870	371	5	yield	yield	NOUN
eurjchem-870	371	6	:	:	PUNCT
eurjchem-870	371	7	90.4	90.4	NUM
eurjchem-870	371	8	%	%	NOUN
eurjchem-870	371	9	.	.	PUNCT
eurjchem-870	372	1	m.p.:178‐180	m.p.:178‐180	NOUN
eurjchem-870	372	2	°	°	ADP
eurjchem-870	372	3	c	c	NOUN
eurjchem-870	372	4	.	.	PUNCT
eurjchem-870	373	1	ft‐ir	ft‐ir	NOUN
eurjchem-870	373	2	(	(	PUNCT
eurjchem-870	373	3	kbr	kbr	PROPN
eurjchem-870	373	4	,	,	PUNCT
eurjchem-870	373	5			PROPN
eurjchem-870	373	6	,	,	PUNCT
eurjchem-870	373	7	cm‐1	cm‐1	PROPN
eurjchem-870	373	8	):	):	PUNCT
eurjchem-870	373	9	3448	3448	NUM
eurjchem-870	373	10	(	(	PUNCT
eurjchem-870	373	11	oh	oh	INTJ
eurjchem-870	373	12	)	)	PUNCT
eurjchem-870	373	13	,	,	PUNCT
eurjchem-870	373	14	3058	3058	NUM
eurjchem-870	373	15	(	(	PUNCT
eurjchem-870	373	16	ch	ch	NOUN
eurjchem-870	373	17	aromatic	aromatic	NOUN
eurjchem-870	373	18	)	)	PUNCT
eurjchem-870	373	19	,	,	PUNCT
eurjchem-870	373	20	2928	2928	NUM
eurjchem-870	373	21	(	(	PUNCT
eurjchem-870	373	22	ch	ch	NOUN
eurjchem-870	373	23	aliphatic	aliphatic	PROPN
eurjchem-870	373	24	)	)	PUNCT
eurjchem-870	373	25	,	,	PUNCT
eurjchem-870	373	26	1603	1603	NUM
eurjchem-870	373	27	(	(	PUNCT
eurjchem-870	373	28	c	c	NOUN
eurjchem-870	373	29	=	=	SYM
eurjchem-870	373	30	n	n	NUM
eurjchem-870	373	31	)	)	PUNCT
eurjchem-870	373	32	.	.	PUNCT
eurjchem-870	374	1	1h	1h	NUM
eurjchem-870	374	2	nmr	nmr	NOUN
eurjchem-870	374	3	(	(	PUNCT
eurjchem-870	374	4	300	300	NUM
eurjchem-870	374	5	mhz	mhz	NOUN
eurjchem-870	374	6	,	,	PUNCT
eurjchem-870	374	7	dmso	dmso	NOUN
eurjchem-870	374	8	,	,	PUNCT
eurjchem-870	374	9	δ	δ	PROPN
eurjchem-870	374	10	,	,	PUNCT
eurjchem-870	374	11	ppm	ppm	NUM
eurjchem-870	374	12	):	):	PUNCT
eurjchem-870	374	13	8.62	8.62	NUM
eurjchem-870	374	14	(	(	PUNCT
eurjchem-870	374	15	s	s	PROPN
eurjchem-870	374	16	,	,	PUNCT
eurjchem-870	374	17	2h	2h	NUM
eurjchem-870	374	18	,	,	PUNCT
eurjchem-870	374	19	oh	oh	INTJ
eurjchem-870	374	20	d2o	d2o	NOUN
eurjchem-870	374	21	exchangeable	exchangeable	ADJ
eurjchem-870	374	22	)	)	PUNCT
eurjchem-870	374	23	,	,	PUNCT
eurjchem-870	374	24	6.85‐7.89	6.85‐7.89	NUM
eurjchem-870	374	25	(	(	PUNCT
eurjchem-870	374	26	m	m	PROPN
eurjchem-870	374	27	,	,	PUNCT
eurjchem-870	374	28	24h	24h	NOUN
eurjchem-870	374	29	,	,	PUNCT
eurjchem-870	374	30	arh	arh	PROPN
eurjchem-870	374	31	)	)	PUNCT
eurjchem-870	374	32	,	,	PUNCT
eurjchem-870	374	33	5.23	5.23	NUM
eurjchem-870	374	34	(	(	PUNCT
eurjchem-870	374	35	s	s	PROPN
eurjchem-870	374	36	,	,	PUNCT
eurjchem-870	374	37	1h	1h	NUM
eurjchem-870	374	38	,	,	PUNCT
eurjchem-870	374	39	benzilic	benzilic	NOUN
eurjchem-870	374	40	)	)	PUNCT
eurjchem-870	374	41	,	,	PUNCT
eurjchem-870	374	42	3.89	3.89	NUM
eurjchem-870	374	43	(	(	PUNCT
eurjchem-870	374	44	s	s	PROPN
eurjchem-870	374	45	,	,	PUNCT
eurjchem-870	374	46	3h	3h	NUM
eurjchem-870	374	47	,	,	PUNCT
eurjchem-870	374	48	och3	och3	ADJ
eurjchem-870	374	49	)	)	PUNCT
eurjchem-870	374	50	.	.	PUNCT
eurjchem-870	375	1	ms	ms	NOUN
eurjchem-870	375	2	(	(	PUNCT
eurjchem-870	375	3	ei	ei	PROPN
eurjchem-870	375	4	,	,	PUNCT
eurjchem-870	375	5	m	m	PROPN
eurjchem-870	375	6	/	/	SYM
eurjchem-870	375	7	z	z	PROPN
eurjchem-870	375	8	(	(	PUNCT
eurjchem-870	375	9	%	%	NOUN
eurjchem-870	375	10	)	)	PUNCT
eurjchem-870	375	11	):	):	PUNCT
eurjchem-870	375	12	590	590	NUM
eurjchem-870	375	13	(	(	PUNCT
eurjchem-870	375	14	0.01	0.01	NUM
eurjchem-870	375	15	,	,	PUNCT
eurjchem-870	375	16	m+	m+	NOUN
eurjchem-870	375	17	·	·	PUNCT
eurjchem-870	375	18	)	)	PUNCT
eurjchem-870	375	19	,	,	PUNCT
eurjchem-870	375	20	236	236	NUM
eurjchem-870	375	21	(	(	PUNCT
eurjchem-870	375	22	60.6	60.6	NUM
eurjchem-870	375	23	)	)	PUNCT
eurjchem-870	375	24	,	,	PUNCT
eurjchem-870	375	25	149	149	NUM
eurjchem-870	375	26	(	(	PUNCT
eurjchem-870	375	27	100	100	NUM
eurjchem-870	375	28	)	)	PUNCT
eurjchem-870	375	29	,	,	PUNCT
eurjchem-870	375	30	148	148	NUM
eurjchem-870	375	31	(	(	PUNCT
eurjchem-870	375	32	33.3	33.3	NUM
eurjchem-870	375	33	)	)	PUNCT
eurjchem-870	375	34	,	,	PUNCT
eurjchem-870	375	35	135	135	NUM
eurjchem-870	375	36	(	(	PUNCT
eurjchem-870	375	37	12.1	12.1	NUM
eurjchem-870	375	38	)	)	PUNCT
eurjchem-870	375	39	,	,	PUNCT
eurjchem-870	375	40	121	121	NUM
eurjchem-870	375	41	(	(	PUNCT
eurjchem-870	375	42	21.2	21.2	NUM
eurjchem-870	375	43	)	)	PUNCT
eurjchem-870	375	44	,	,	PUNCT
eurjchem-870	375	45	92	92	NUM
eurjchem-870	375	46	(	(	PUNCT
eurjchem-870	375	47	16.7	16.7	NUM
eurjchem-870	375	48	)	)	PUNCT
eurjchem-870	375	49	,	,	PUNCT
eurjchem-870	375	50	77	77	NUM
eurjchem-870	375	51	(	(	PUNCT
eurjchem-870	375	52	45.5	45.5	NUM
eurjchem-870	375	53	)	)	PUNCT
eurjchem-870	375	54	.	.	PUNCT
eurjchem-870	376	1	anal	anal	PROPN
eurjchem-870	376	2	.	.	PUNCT
eurjchem-870	376	3	calcd	calcd	NOUN
eurjchem-870	376	4	.	.	PUNCT
eurjchem-870	377	1	for	for	SCONJ
eurjchem-870	377	2	c38h30n4o3	c38h30n4o3	PROPN
eurjchem-870	377	3	:	:	PUNCT
eurjchem-870	377	4	c	c	X
eurjchem-870	377	5	,	,	PUNCT
eurjchem-870	377	6	77.27	77.27	NUM
eurjchem-870	377	7	;	;	PUNCT
eurjchem-870	377	8	h	h	NOUN
eurjchem-870	377	9	,	,	PUNCT
eurjchem-870	377	10	5.12	5.12	NUM
eurjchem-870	377	11	;	;	PUNCT
eurjchem-870	377	12	n	n	CCONJ
eurjchem-870	377	13	,	,	PUNCT
eurjchem-870	377	14	9.49	9.49	NUM
eurjchem-870	377	15	.	.	PUNCT
eurjchem-870	377	16	found	find	VERB
eurjchem-870	377	17	:	:	PUNCT
eurjchem-870	378	1	c	c	X
eurjchem-870	378	2	,	,	PUNCT
eurjchem-870	378	3	77.32	77.32	NUM
eurjchem-870	378	4	;	;	PUNCT
eurjchem-870	378	5	h	h	NOUN
eurjchem-870	378	6	,	,	PUNCT
eurjchem-870	378	7	5.27	5.27	NUM
eurjchem-870	378	8	;	;	PUNCT
eurjchem-870	378	9	n	n	CCONJ
eurjchem-870	378	10	,	,	PUNCT
eurjchem-870	378	11	9.62	9.62	NUM
eurjchem-870	378	12	%	%	NOUN
eurjchem-870	378	13	.	.	PUNCT
eurjchem-870	379	1	2.3	2.3	NUM
eurjchem-870	379	2	.	.	PUNCT
eurjchem-870	380	1	antimicrobial	antimicrobial	ADJ
eurjchem-870	380	2	activities	activity	NOUN
eurjchem-870	380	3	the	the	DET
eurjchem-870	380	4	synthesized	synthesize	VERB
eurjchem-870	380	5	compounds	compound	NOUN
eurjchem-870	380	6	were	be	AUX
eurjchem-870	380	7	evaluated	evaluate	VERB
eurjchem-870	380	8	for	for	ADP
eurjchem-870	380	9	their	their	PRON
eurjchem-870	380	10	antimicrobial	antimicrobial	ADJ
eurjchem-870	380	11	activities	activity	NOUN
eurjchem-870	380	12	using	use	VERB
eurjchem-870	380	13	the	the	DET
eurjchem-870	380	14	agar	agar	NOUN
eurjchem-870	380	15	diffusion	diffusion	NOUN
eurjchem-870	380	16	technique	technique	NOUN
eurjchem-870	380	17	[	[	X
eurjchem-870	380	18	16	16	NUM
eurjchem-870	380	19	]	]	PUNCT
eurjchem-870	380	20	.	.	PUNCT
eurjchem-870	381	1	all	all	DET
eurjchem-870	381	2	chemical	chemical	NOUN
eurjchem-870	381	3	compounds	compound	NOUN
eurjchem-870	381	4	were	be	AUX
eurjchem-870	381	5	dissolved	dissolve	VERB
eurjchem-870	381	6	in	in	ADP
eurjchem-870	381	7	dmf	dmf	PROPN
eurjchem-870	381	8	(	(	PUNCT
eurjchem-870	381	9	5000	5000	NUM
eurjchem-870	381	10	ppm	ppm	NOUN
eurjchem-870	381	11	)	)	PUNCT
eurjchem-870	381	12	.	.	PUNCT
eurjchem-870	382	1	the	the	DET
eurjchem-870	382	2	tested	test	VERB
eurjchem-870	382	3	compounds	compound	NOUN
eurjchem-870	382	4	were	be	AUX
eurjchem-870	382	5	evaluated	evaluate	VERB
eurjchem-870	382	6	against	against	ADP
eurjchem-870	382	7	gram	gram	PROPN
eurjchem-870	382	8	‐ve	‐ve	NOUN
eurjchem-870	382	9	bacteria	bacteria	NOUN
eurjchem-870	382	10	(	(	PUNCT
eurjchem-870	382	11	pseudomonas	pseudomona	NOUN
eurjchem-870	382	12	aeruginosa	aeruginosa	PROPN
eurjchem-870	382	13	atcc	atcc	PROPN
eurjchem-870	382	14	10145	10145	NUM
eurjchem-870	382	15	and	and	CCONJ
eurjchem-870	382	16	escherichia	escherichia	NOUN
eurjchem-870	382	17	coli	coli	NOUN
eurjchem-870	382	18	atcc	atcc	NOUN
eurjchem-870	382	19	23282	23282	NUM
eurjchem-870	382	20	)	)	PUNCT
eurjchem-870	382	21	,	,	PUNCT
eurjchem-870	382	22	gram	gram	PROPN
eurjchem-870	382	23	+	+	PROPN
eurjchem-870	382	24	ve	ve	PROPN
eurjchem-870	382	25	bacteria	bacteria	NOUN
eurjchem-870	382	26	(	(	PUNCT
eurjchem-870	382	27	bacillus	bacillus	NOUN
eurjchem-870	382	28	subtilis	subtili	NOUN
eurjchem-870	382	29	atcc	atcc	PROPN
eurjchem-870	382	30	6633	6633	NUM
eurjchem-870	382	31	,	,	PUNCT
eurjchem-870	382	32	micrococcus	micrococcus	NOUN
eurjchem-870	382	33	luteus	luteus	PROPN
eurjchem-870	382	34	atcc	atcc	NOUN
eurjchem-870	382	35	25922	25922	NUM
eurjchem-870	382	36	)	)	PUNCT
eurjchem-870	382	37	and	and	CCONJ
eurjchem-870	382	38	yeast	yeast	NOUN
eurjchem-870	382	39	(	(	PUNCT
eurjchem-870	382	40	candida	candida	NOUN
eurjchem-870	382	41	albicans	albican	NOUN
eurjchem-870	382	42	imru	imru	VERB
eurjchem-870	382	43	3669	3669	NUM
eurjchem-870	382	44	and	and	CCONJ
eurjchem-870	382	45	filamentous	filamentous	ADJ
eurjchem-870	382	46	niger	niger	NOUN
eurjchem-870	382	47	atcc	atcc	NOUN
eurjchem-870	382	48	16404	16404	NUM
eurjchem-870	382	49	)	)	PUNCT
eurjchem-870	382	50	.	.	PUNCT
eurjchem-870	383	1	the	the	DET
eurjchem-870	383	2	bacteria	bacteria	NOUN
eurjchem-870	383	3	and	and	CCONJ
eurjchem-870	383	4	yeast	yeast	NOUN
eurjchem-870	383	5	were	be	AUX
eurjchem-870	383	6	grown	grow	VERB
eurjchem-870	383	7	on	on	ADP
eurjchem-870	383	8	nutrient	nutrient	NOUN
eurjchem-870	383	9	agar	agar	NOUN
eurjchem-870	383	10	while	while	SCONJ
eurjchem-870	383	11	the	the	DET
eurjchem-870	383	12	fungus	fungus	NOUN
eurjchem-870	383	13	was	be	AUX
eurjchem-870	383	14	grown	grow	VERB
eurjchem-870	383	15	on	on	ADP
eurjchem-870	383	16	czapek	czapek	NOUN
eurjchem-870	383	17	’s	’s	PART
eurjchem-870	383	18	dox	dox	NOUN
eurjchem-870	383	19	agar	agar	NOUN
eurjchem-870	383	20	medium	medium	NOUN
eurjchem-870	383	21	.	.	PUNCT
eurjchem-870	384	1	the	the	DET
eurjchem-870	384	2	negative	negative	PROPN
eurjchem-870	384	3	control	control	PROPN
eurjchem-870	384	4	dmf	dmf	PROPN
eurjchem-870	384	5	was	be	AUX
eurjchem-870	384	6	showed	show	VERB
eurjchem-870	384	7	no	no	DET
eurjchem-870	384	8	antimicrobial	antimicrobial	ADJ
eurjchem-870	384	9	activity	activity	NOUN
eurjchem-870	384	10	against	against	ADP
eurjchem-870	384	11	the	the	DET
eurjchem-870	384	12	tested	test	VERB
eurjchem-870	384	13	microorganism	microorganism	NOUN
eurjchem-870	384	14	,	,	PUNCT
eurjchem-870	384	15	and	and	CCONJ
eurjchem-870	384	16	the	the	DET
eurjchem-870	384	17	positive	positive	ADJ
eurjchem-870	384	18	control	control	NOUN
eurjchem-870	384	19	was	be	AUX
eurjchem-870	384	20	erythromycin	erythromycin	NOUN
eurjchem-870	384	21	for	for	ADP
eurjchem-870	384	22	bacteria	bacteria	NOUN
eurjchem-870	384	23	and	and	CCONJ
eurjchem-870	384	24	metronidazole	metronidazole	NOUN
eurjchem-870	384	25	for	for	ADP
eurjchem-870	384	26	yeast	yeast	NOUN
eurjchem-870	384	27	and	and	CCONJ
eurjchem-870	384	28	fungus	fungus	NOUN
eurjchem-870	384	29	.	.	PUNCT
eurjchem-870	385	1	all	all	DET
eurjchem-870	385	2	examination	examination	NOUN
eurjchem-870	385	3	were	be	AUX
eurjchem-870	385	4	done	do	VERB
eurjchem-870	385	5	in	in	ADP
eurjchem-870	385	6	duplicates	duplicate	NOUN
eurjchem-870	385	7	and	and	CCONJ
eurjchem-870	385	8	the	the	DET
eurjchem-870	385	9	listed	list	VERB
eurjchem-870	385	10	are	be	AUX
eurjchem-870	385	11	the	the	DET
eurjchem-870	385	12	average	average	NOUN
eurjchem-870	385	13	of	of	ADP
eurjchem-870	385	14	the	the	DET
eurjchem-870	385	15	obtained	obtain	VERB
eurjchem-870	385	16	results	result	NOUN
eurjchem-870	385	17	.	.	PUNCT
eurjchem-870	386	1	3	3	X
eurjchem-870	386	2	.	.	NOUN
eurjchem-870	386	3	results	result	NOUN
eurjchem-870	386	4	and	and	CCONJ
eurjchem-870	386	5	discussion	discussion	NOUN
eurjchem-870	386	6	3.1	3.1	NUM
eurjchem-870	386	7	.	.	PUNCT
eurjchem-870	387	1	synthesis	synthesis	VERB
eurjchem-870	387	2	the	the	DET
eurjchem-870	387	3	starting	starting	NOUN
eurjchem-870	387	4	material	material	NOUN
eurjchem-870	387	5	pyrazolone	pyrazolone	NOUN
eurjchem-870	387	6	3	3	NUM
eurjchem-870	387	7	was	be	AUX
eurjchem-870	387	8	prepared	prepare	VERB
eurjchem-870	387	9	by	by	ADP
eurjchem-870	387	10	literature	literature	NOUN
eurjchem-870	387	11	known	know	VERB
eurjchem-870	387	12	procedure	procedure	NOUN
eurjchem-870	387	13	[	[	X
eurjchem-870	387	14	17	17	NUM
eurjchem-870	387	15	]	]	PUNCT
eurjchem-870	387	16	using	use	VERB
eurjchem-870	387	17	ethyl	ethyl	PROPN
eurjchem-870	387	18	benzoyl	benzoyl	PROPN
eurjchem-870	387	19	acetate	acetate	NOUN
eurjchem-870	387	20	1	1	NUM
eurjchem-870	387	21	as	as	ADP
eurjchem-870	387	22	β‐keto	β‐keto	PUNCT
eurjchem-870	387	23	ester	ester	NOUN
eurjchem-870	387	24	and	and	CCONJ
eurjchem-870	387	25	phenyl	phenyl	NOUN
eurjchem-870	387	26	hydrazine	hydrazine	NOUN
eurjchem-870	387	27	,	,	PUNCT
eurjchem-870	387	28	2	2	X
eurjchem-870	387	29	.	.	PUNCT
eurjchem-870	388	1	in	in	ADP
eurjchem-870	388	2	principle	principle	NOUN
eurjchem-870	388	3	,	,	PUNCT
eurjchem-870	388	4	for	for	ADP
eurjchem-870	388	5	compounds	compound	NOUN
eurjchem-870	388	6	unsubstituted	unsubstitute	VERB
eurjchem-870	388	7	at	at	ADP
eurjchem-870	388	8	pyrazole	pyrazole	NOUN
eurjchem-870	388	9	c‐4	c‐4	PROPN
eurjchem-870	388	10	,	,	PUNCT
eurjchem-870	388	11	three	three	NUM
eurjchem-870	388	12	isomers	isomer	NOUN
eurjchem-870	388	13	are	be	AUX
eurjchem-870	388	14	possible	possible	ADJ
eurjchem-870	388	15	,	,	PUNCT
eurjchem-870	388	16	assigned	assign	VERB
eurjchem-870	388	17	as	as	ADP
eurjchem-870	388	18	1h‐pyrazol‐5‐ol	1h‐pyrazol‐5‐ol	NUM
eurjchem-870	388	19	(	(	PUNCT
eurjchem-870	388	20	a	a	NOUN
eurjchem-870	388	21	)	)	PUNCT
eurjchem-870	388	22	,	,	PUNCT
eurjchem-870	388	23	2,4‐dihydro‐3h‐	2,4‐dihydro‐3h‐	PROPN
eurjchem-870	388	24	pyrazol‐3‐one	pyrazol‐3‐one	NOUN
eurjchem-870	388	25	(	(	PUNCT
eurjchem-870	388	26	b	b	NOUN
eurjchem-870	388	27	)	)	PUNCT
eurjchem-870	388	28	and	and	CCONJ
eurjchem-870	388	29	1,2‐dihydro‐3h‐pyrazol‐3‐one	1,2‐dihydro‐3h‐pyrazol‐3‐one	NUM
eurjchem-870	388	30	(	(	PUNCT
eurjchem-870	388	31	c	c	NOUN
eurjchem-870	388	32	)	)	PUNCT
eurjchem-870	388	33	(	(	PUNCT
eurjchem-870	388	34	scheme	scheme	NOUN
eurjchem-870	388	35	5	5	NUM
eurjchem-870	388	36	)	)	PUNCT
eurjchem-870	388	37	.	.	PUNCT
eurjchem-870	389	1	scheme	scheme	NOUN
eurjchem-870	389	2	5	5	NUM
eurjchem-870	389	3	the	the	DET
eurjchem-870	389	4	ir	ir	PROPN
eurjchem-870	389	5	spectra	spectra	NOUN
eurjchem-870	389	6	of	of	ADP
eurjchem-870	389	7	3	3	NUM
eurjchem-870	389	8	displayed	display	VERB
eurjchem-870	389	9	band	band	NOUN
eurjchem-870	389	10	at	at	ADP
eurjchem-870	389	11	1706	1706	NUM
eurjchem-870	389	12	cm−1	cm−1	NOUN
eurjchem-870	389	13	due	due	ADP
eurjchem-870	389	14	to	to	ADP
eurjchem-870	389	15	c	c	NOUN
eurjchem-870	389	16	=	=	NOUN
eurjchem-870	389	17	o	o	NOUN
eurjchem-870	389	18	absorption	absorption	NOUN
eurjchem-870	389	19	at	at	ADP
eurjchem-870	389	20	position	position	NOUN
eurjchem-870	389	21	5	5	NUM
eurjchem-870	389	22	and	and	CCONJ
eurjchem-870	389	23	the	the	DET
eurjchem-870	389	24	1h	1h	NUM
eurjchem-870	389	25	nmr	nmr	NOUN
eurjchem-870	389	26	spectrum	spectrum	VERB
eurjchem-870	389	27	devoid	devoid	ADJ
eurjchem-870	389	28	of	of	ADP
eurjchem-870	389	29	exchangeable	exchangeable	ADJ
eurjchem-870	389	30	nh	nh	NOUN
eurjchem-870	389	31	or	or	CCONJ
eurjchem-870	389	32	oh	oh	INTJ
eurjchem-870	389	33	which	which	PRON
eurjchem-870	389	34	indicated	indicate	VERB
eurjchem-870	389	35	that	that	SCONJ
eurjchem-870	389	36	pyrazolone	pyrazolone	NOUN
eurjchem-870	389	37	3	3	NUM
eurjchem-870	389	38	exists	exist	VERB
eurjchem-870	389	39	in	in	ADP
eurjchem-870	389	40	the	the	DET
eurjchem-870	389	41	keto	keto	NOUN
eurjchem-870	389	42	form	form	NOUN
eurjchem-870	389	43	in	in	ADP
eurjchem-870	389	44	either	either	CCONJ
eurjchem-870	389	45	the	the	DET
eurjchem-870	389	46	solid	solid	ADJ
eurjchem-870	389	47	state	state	NOUN
eurjchem-870	389	48	or	or	CCONJ
eurjchem-870	389	49	the	the	DET
eurjchem-870	389	50	liquid	liquid	ADJ
eurjchem-870	389	51	state	state	NOUN
eurjchem-870	389	52	.	.	PUNCT
eurjchem-870	390	1	the	the	DET
eurjchem-870	390	2	reactivity	reactivity	NOUN
eurjchem-870	390	3	of	of	ADP
eurjchem-870	390	4	hydrogen	hydrogen	NOUN
eurjchem-870	390	5	atoms	atom	NOUN
eurjchem-870	390	6	at	at	ADP
eurjchem-870	390	7	c‐4	c‐4	PROPN
eurjchem-870	390	8	is	be	AUX
eurjchem-870	390	9	the	the	DET
eurjchem-870	390	10	most	most	ADV
eurjchem-870	390	11	outstanding	outstanding	ADJ
eurjchem-870	390	12	chemical	chemical	NOUN
eurjchem-870	390	13	property	property	NOUN
eurjchem-870	390	14	of	of	ADP
eurjchem-870	390	15	pyrazolone	pyrazolone	NOUN
eurjchem-870	390	16	3	3	NUM
eurjchem-870	390	17	towards	towards	ADP
eurjchem-870	390	18	condensation	condensation	NOUN
eurjchem-870	390	19	reactions	reaction	NOUN
eurjchem-870	390	20	(	(	PUNCT
eurjchem-870	390	21	scheme	scheme	NOUN
eurjchem-870	390	22	1	1	NUM
eurjchem-870	390	23	)	)	PUNCT
eurjchem-870	390	24	.	.	PUNCT
eurjchem-870	391	1	amino	amino	ADJ
eurjchem-870	391	2	carbonitriles	carbonitrile	NOUN
eurjchem-870	391	3	4	4	NUM
eurjchem-870	391	4	and	and	CCONJ
eurjchem-870	391	5	5	5	NUM
eurjchem-870	391	6	and	and	CCONJ
eurjchem-870	391	7	pyrazolopyridine	pyrazolopyridine	PRON
eurjchem-870	391	8	6	6	NUM
eurjchem-870	391	9	were	be	AUX
eurjchem-870	391	10	synthesized	synthesize	VERB
eurjchem-870	391	11	via	via	ADP
eurjchem-870	391	12	a	a	DET
eurjchem-870	391	13	multicomponent	multicomponent	ADJ
eurjchem-870	391	14	reaction	reaction	NOUN
eurjchem-870	391	15	of	of	ADP
eurjchem-870	391	16	pyrazolone	pyrazolone	NOUN
eurjchem-870	391	17	3	3	NUM
eurjchem-870	391	18	with	with	ADP
eurjchem-870	391	19	p‐anisaldehyde	p‐anisaldehyde	PUNCT
eurjchem-870	391	20	and	and	CCONJ
eurjchem-870	391	21	active	active	ADJ
eurjchem-870	391	22	methylene	methylene	NOUN
eurjchem-870	391	23	compounds	compound	NOUN
eurjchem-870	391	24	such	such	ADJ
eurjchem-870	391	25	as	as	ADP
eurjchem-870	391	26	malononitrile	malononitrile	NOUN
eurjchem-870	391	27	and/or	and/or	CCONJ
eurjchem-870	391	28	ethyl	ethyl	PROPN
eurjchem-870	391	29	acetoacetate	acetoacetate	NOUN
eurjchem-870	391	30	in	in	ADP
eurjchem-870	391	31	the	the	DET
eurjchem-870	391	32	presence	presence	NOUN
eurjchem-870	391	33	of	of	ADP
eurjchem-870	391	34	ammonium	ammonium	NOUN
eurjchem-870	391	35	acetate	acetate	NOUN
eurjchem-870	391	36	and/or	and/or	CCONJ
eurjchem-870	391	37	piperidine	piperidine	NOUN
eurjchem-870	391	38	at	at	ADP
eurjchem-870	391	39	140‐170	140‐170	NUM
eurjchem-870	391	40	°	°	ADP
eurjchem-870	391	41	c	c	NOUN
eurjchem-870	391	42	.	.	PUNCT
eurjchem-870	392	1	the	the	DET
eurjchem-870	392	2	appearance	appearance	NOUN
eurjchem-870	392	3	of	of	ADP
eurjchem-870	392	4	the	the	DET
eurjchem-870	392	5	cyano	cyano	NOUN
eurjchem-870	392	6	and	and	CCONJ
eurjchem-870	392	7	the	the	DET
eurjchem-870	392	8	amino	amino	NOUN
eurjchem-870	392	9	functions	function	NOUN
eurjchem-870	392	10	in	in	ADP
eurjchem-870	392	11	the	the	DET
eurjchem-870	392	12	ir	ir	NOUN
eurjchem-870	392	13	of	of	ADP
eurjchem-870	392	14	the	the	DET
eurjchem-870	392	15	reaction	reaction	NOUN
eurjchem-870	392	16	products	product	NOUN
eurjchem-870	392	17	support	support	VERB
eurjchem-870	392	18	the	the	DET
eurjchem-870	392	19	structures	structure	NOUN
eurjchem-870	392	20	of	of	ADP
eurjchem-870	392	21	compounds	compound	NOUN
eurjchem-870	392	22	4	4	NUM
eurjchem-870	392	23	,	,	PUNCT
eurjchem-870	392	24	and	and	CCONJ
eurjchem-870	392	25	5	5	NUM
eurjchem-870	392	26	.	.	X
eurjchem-870	393	1	it	it	PRON
eurjchem-870	393	2	has	have	AUX
eurjchem-870	393	3	been	be	AUX
eurjchem-870	393	4	reported	report	VERB
eurjchem-870	393	5	that	that	SCONJ
eurjchem-870	393	6	amino	amino	NOUN
eurjchem-870	393	7	carbonitriles	carbonitrile	NOUN
eurjchem-870	393	8	reacted	react	VERB
eurjchem-870	393	9	with	with	ADP
eurjchem-870	393	10	ammonium	ammonium	NOUN
eurjchem-870	393	11	thiocyanate	thiocyanate	NOUN
eurjchem-870	393	12	[	[	X
eurjchem-870	393	13	18	18	NUM
eurjchem-870	393	14	]	]	PUNCT
eurjchem-870	393	15	in	in	ADP
eurjchem-870	393	16	boiling	boil	VERB
eurjchem-870	393	17	acetic	acetic	ADJ
eurjchem-870	393	18	acid	acid	NOUN
eurjchem-870	393	19	to	to	PART
eurjchem-870	393	20	give	give	VERB
eurjchem-870	393	21	(	(	PUNCT
eurjchem-870	393	22	thioxo	thioxo	ADJ
eurjchem-870	393	23	pyrimidinyl	pyrimidinyl	NOUN
eurjchem-870	393	24	)	)	PUNCT
eurjchem-870	393	25	thiourea	thiourea	NOUN
eurjchem-870	393	26	derivatives	derivative	NOUN
eurjchem-870	393	27	,	,	PUNCT
eurjchem-870	393	28	while	while	SCONJ
eurjchem-870	393	29	in	in	ADP
eurjchem-870	393	30	our	our	PRON
eurjchem-870	393	31	investigation	investigation	NOUN
eurjchem-870	393	32	we	we	PRON
eurjchem-870	393	33	isolated	isolate	VERB
eurjchem-870	393	34	the	the	DET
eurjchem-870	393	35	amino(iminomethyl)thiocyanato	amino(iminomethyl)thiocyanato	PROPN
eurjchem-870	393	36	methanethioimidate	methanethioimidate	NOUN
eurjchem-870	393	37	7	7	NUM
eurjchem-870	393	38	through	through	ADP
eurjchem-870	393	39	two	two	NUM
eurjchem-870	393	40	consecutive	consecutive	ADJ
eurjchem-870	393	41	additions	addition	NOUN
eurjchem-870	393	42	of	of	ADP
eurjchem-870	393	43	two	two	NUM
eurjchem-870	393	44	molecules	molecule	NOUN
eurjchem-870	393	45	of	of	ADP
eurjchem-870	393	46	ammonium	ammonium	NOUN
eurjchem-870	393	47	thiocyanate	thiocyanate	NOUN
eurjchem-870	393	48	to	to	ADP
eurjchem-870	393	49	compound	compound	VERB
eurjchem-870	393	50	4	4	NUM
eurjchem-870	393	51	.	.	PUNCT
eurjchem-870	394	1	the	the	DET
eurjchem-870	394	2	structure	structure	NOUN
eurjchem-870	394	3	of	of	ADP
eurjchem-870	394	4	compound	compound	NOUN
eurjchem-870	394	5	7	7	NUM
eurjchem-870	394	6	was	be	AUX
eurjchem-870	394	7	confirmed	confirm	VERB
eurjchem-870	394	8	by	by	ADP
eurjchem-870	394	9	ir	ir	PROPN
eurjchem-870	394	10	which	which	PRON
eurjchem-870	394	11	showed	show	VERB
eurjchem-870	394	12	band	band	NOUN
eurjchem-870	394	13	at	at	ADP
eurjchem-870	394	14	2207	2207	NUM
eurjchem-870	394	15	(	(	PUNCT
eurjchem-870	394	16	c≡n	c≡n	NOUN
eurjchem-870	394	17	)	)	PUNCT
eurjchem-870	394	18	,	,	PUNCT
eurjchem-870	394	19	and	and	CCONJ
eurjchem-870	394	20	also	also	ADV
eurjchem-870	394	21	its	its	PRON
eurjchem-870	394	22	reaction	reaction	NOUN
eurjchem-870	394	23	with	with	ADP
eurjchem-870	394	24	hydrazine	hydrazine	NOUN
eurjchem-870	394	25	hydrate	hydrate	NOUN
eurjchem-870	394	26	to	to	PART
eurjchem-870	394	27	afford	afford	VERB
eurjchem-870	394	28	pyrazolo[3,4‐b]pyridin‐6‐amine	pyrazolo[3,4‐b]pyridin‐6‐amine	PRON
eurjchem-870	394	29	derivative	derivative	ADJ
eurjchem-870	394	30	8	8	NUM
eurjchem-870	394	31	.	.	PUNCT
eurjchem-870	395	1	marzouk	marzouk	X
eurjchem-870	395	2	et	et	PROPN
eurjchem-870	395	3	al	al	PROPN
eurjchem-870	395	4	.	.	PUNCT
eurjchem-870	395	5	/	/	SYM
eurjchem-870	395	6	european	european	PROPN
eurjchem-870	395	7	journal	journal	PROPN
eurjchem-870	395	8	of	of	ADP
eurjchem-870	395	9	chemistry	chemistry	NOUN
eurjchem-870	395	10	5	5	NUM
eurjchem-870	395	11	(	(	PUNCT
eurjchem-870	395	12	1	1	NUM
eurjchem-870	395	13	)	)	PUNCT
eurjchem-870	395	14	(	(	PUNCT
eurjchem-870	395	15	2014	2014	NUM
eurjchem-870	395	16	)	)	PUNCT
eurjchem-870	395	17	24‐32	24‐32	NUM
eurjchem-870	395	18	31	31	NUM
eurjchem-870	395	19	table	table	NOUN
eurjchem-870	395	20	1	1	NUM
eurjchem-870	395	21	.	.	PUNCT
eurjchem-870	395	22	microwave	microwave	NOUN
eurjchem-870	395	23	synthesis	synthesis	NOUN
eurjchem-870	395	24	of	of	ADP
eurjchem-870	395	25	compounds	compound	NOUN
eurjchem-870	395	26	5	5	NUM
eurjchem-870	395	27	,	,	PUNCT
eurjchem-870	395	28	19	19	NUM
eurjchem-870	395	29	and	and	CCONJ
eurjchem-870	395	30	22	22	NUM
eurjchem-870	395	31	.	.	PUNCT
eurjchem-870	396	1	compound	compound	VERB
eurjchem-870	396	2	no	no	DET
eurjchem-870	396	3	power	power	NOUN
eurjchem-870	396	4	(	(	PUNCT
eurjchem-870	396	5	watt	watt	NOUN
eurjchem-870	396	6	)	)	PUNCT
eurjchem-870	396	7	time	time	NOUN
eurjchem-870	396	8	(	(	PUNCT
eurjchem-870	396	9	min	min	NOUN
eurjchem-870	396	10	)	)	PUNCT
eurjchem-870	396	11	yield	yield	NOUN
eurjchem-870	396	12	(	(	PUNCT
eurjchem-870	396	13	%	%	INTJ
eurjchem-870	396	14	)	)	PUNCT
eurjchem-870	396	15	mw	mw	PROPN
eurjchem-870	396	16	/	/	SYM
eurjchem-870	396	17	conventional	conventional	ADJ
eurjchem-870	396	18	5	5	NUM
eurjchem-870	396	19	180	180	NUM
eurjchem-870	396	20	4	4	NUM
eurjchem-870	396	21	50/14	50/14	NUM
eurjchem-870	396	22	19	19	NUM
eurjchem-870	396	23	180	180	NUM
eurjchem-870	396	24	2	2	NUM
eurjchem-870	396	25	90/82	90/82	NUM
eurjchem-870	396	26	22	22	NUM
eurjchem-870	396	27	360	360	NUM
eurjchem-870	396	28	4	4	NUM
eurjchem-870	396	29	99/98	99/98	NUM
eurjchem-870	396	30	table	table	NOUN
eurjchem-870	396	31	2	2	NUM
eurjchem-870	396	32	.	.	PUNCT
eurjchem-870	397	1	the	the	DET
eurjchem-870	397	2	antimicrobial	antimicrobial	ADJ
eurjchem-870	397	3	activities	activity	NOUN
eurjchem-870	397	4	of	of	ADP
eurjchem-870	397	5	compounds	compound	NOUN
eurjchem-870	397	6	8	8	NUM
eurjchem-870	397	7	,	,	PUNCT
eurjchem-870	397	8	23	23	NUM
eurjchem-870	397	9	,	,	PUNCT
eurjchem-870	397	10	27	27	NUM
eurjchem-870	397	11	and	and	CCONJ
eurjchem-870	397	12	31	31	NUM
eurjchem-870	397	13	*	*	PUNCT
eurjchem-870	397	14	.	.	PUNCT
eurjchem-870	398	1	compound	compound	VERB
eurjchem-870	398	2	no	no	DET
eurjchem-870	398	3	bacillus	bacillus	NOUN
eurjchem-870	398	4	subtilis	subtili	NOUN
eurjchem-870	398	5	micrococcus	micrococcus	NOUN
eurjchem-870	398	6	lutes	lute	NOUN
eurjchem-870	398	7	pseudonomus	pseudonomus	VERB
eurjchem-870	398	8	aerugino	aerugino	PROPN
eurjchem-870	398	9	escherichia	escherichia	NOUN
eurjchem-870	398	10	coli	coli	NOUN
eurjchem-870	398	11	candida	candida	NOUN
eurjchem-870	398	12	albicans	albican	VERB
eurjchem-870	398	13	filamentous	filamentous	ADJ
eurjchem-870	398	14	niger	niger	NOUN
eurjchem-870	398	15	8	8	NUM
eurjchem-870	398	16	‐	‐	NOUN
eurjchem-870	398	17	‐	‐	ADV
eurjchem-870	398	18	‐	‐	ADV
eurjchem-870	398	19	‐	‐	ADV
eurjchem-870	398	20	‐	‐	ADV
eurjchem-870	398	21	‐	‐	ADV
eurjchem-870	398	22	23	23	NUM
eurjchem-870	398	23	‐	‐	NOUN
eurjchem-870	398	24	‐	‐	ADV
eurjchem-870	398	25	17.0	17.0	NUM
eurjchem-870	398	26	20.0	20.0	NUM
eurjchem-870	398	27	‐	‐	NOUN
eurjchem-870	398	28	‐	‐	ADV
eurjchem-870	398	29	27	27	NUM
eurjchem-870	398	30	36.0	36.0	NUM
eurjchem-870	398	31	27.0	27.0	NUM
eurjchem-870	398	32	27.0	27.0	NUM
eurjchem-870	398	33	32.0	32.0	NUM
eurjchem-870	398	34	21.0	21.0	NUM
eurjchem-870	398	35	17.0	17.0	NUM
eurjchem-870	398	36	31	31	NUM
eurjchem-870	398	37	23.0	23.0	NUM
eurjchem-870	398	38	21.0	21.0	NUM
eurjchem-870	398	39	18.0	18.0	NUM
eurjchem-870	398	40	22.0	22.0	NUM
eurjchem-870	398	41	20.0	20.0	NUM
eurjchem-870	398	42	15.0	15.0	NUM
eurjchem-870	398	43	erythromycin	erythromycin	NOUN
eurjchem-870	398	44	32.0	32.0	NUM
eurjchem-870	398	45	32.0	32.0	NUM
eurjchem-870	398	46	30.0	30.0	NUM
eurjchem-870	398	47	44.0	44.0	NUM
eurjchem-870	398	48	‐	‐	NOUN
eurjchem-870	398	49	‐	‐	ADJ
eurjchem-870	398	50	metronidazole	metronidazole	NOUN
eurjchem-870	398	51	‐	‐	VERB
eurjchem-870	398	52	‐	‐	ADV
eurjchem-870	398	53	‐	‐	ADV
eurjchem-870	398	54	‐	‐	ADV
eurjchem-870	398	55	27.0	27.0	NUM
eurjchem-870	398	56	25.0	25.0	NUM
eurjchem-870	398	57	dmf	dmf	PROPN
eurjchem-870	398	58	‐	‐	VERB
eurjchem-870	398	59	‐	‐	ADV
eurjchem-870	398	60	‐	‐	ADV
eurjchem-870	398	61	‐	‐	ADV
eurjchem-870	398	62	‐	‐	ADV
eurjchem-870	398	63	‐	‐	NOUN
eurjchem-870	398	64	*	*	VERB
eurjchem-870	398	65	erythromycin	erythromycin	NOUN
eurjchem-870	398	66	was	be	AUX
eurjchem-870	398	67	used	use	VERB
eurjchem-870	398	68	as	as	ADP
eurjchem-870	398	69	a	a	DET
eurjchem-870	398	70	standard	standard	NOUN
eurjchem-870	398	71	against	against	ADP
eurjchem-870	398	72	gram	gram	NOUN
eurjchem-870	398	73	positive	positive	ADJ
eurjchem-870	398	74	and	and	CCONJ
eurjchem-870	398	75	gram	gram	ADJ
eurjchem-870	398	76	negative	negative	ADJ
eurjchem-870	398	77	bacteria	bacteria	NOUN
eurjchem-870	398	78	,	,	PUNCT
eurjchem-870	398	79	while	while	SCONJ
eurjchem-870	398	80	metronidazole	metronidazole	NOUN
eurjchem-870	398	81	was	be	AUX
eurjchem-870	398	82	used	use	VERB
eurjchem-870	398	83	as	as	ADP
eurjchem-870	398	84	a	a	DET
eurjchem-870	398	85	standard	standard	NOUN
eurjchem-870	398	86	against	against	ADP
eurjchem-870	398	87	fungi	fungi	PROPN
eurjchem-870	398	88	,	,	PUNCT
eurjchem-870	398	89	and	and	CCONJ
eurjchem-870	398	90	the	the	DET
eurjchem-870	398	91	negative	negative	ADJ
eurjchem-870	398	92	controle	controle	PROPN
eurjchem-870	398	93	was	be	AUX
eurjchem-870	398	94	dmf	dmf	PROPN
eurjchem-870	398	95	.	.	PUNCT
eurjchem-870	398	96	treatment	treatment	NOUN
eurjchem-870	398	97	of	of	ADP
eurjchem-870	398	98	compound	compound	NOUN
eurjchem-870	398	99	4	4	NUM
eurjchem-870	398	100	with	with	ADP
eurjchem-870	398	101	formamide	formamide	ADV
eurjchem-870	398	102	in	in	ADP
eurjchem-870	398	103	the	the	DET
eurjchem-870	398	104	presence	presence	NOUN
eurjchem-870	398	105	of	of	ADP
eurjchem-870	398	106	formic	formic	PROPN
eurjchem-870	398	107	acid	acid	PROPN
eurjchem-870	398	108	and	and	CCONJ
eurjchem-870	398	109	dmf	dmf	PROPN
eurjchem-870	398	110	afforded	afford	VERB
eurjchem-870	398	111	the	the	DET
eurjchem-870	398	112	open	open	ADJ
eurjchem-870	398	113	structure	structure	NOUN
eurjchem-870	398	114	pyrazolo[3,4‐b]pyridinylformamide	pyrazolo[3,4‐b]pyridinylformamide	ADV
eurjchem-870	398	115	9	9	NUM
eurjchem-870	398	116	.	.	X
eurjchem-870	398	117	acetylation	acetylation	NOUN
eurjchem-870	398	118	of	of	ADP
eurjchem-870	398	119	compounds	compound	NOUN
eurjchem-870	398	120	4	4	NUM
eurjchem-870	398	121	and	and	CCONJ
eurjchem-870	398	122	5	5	NUM
eurjchem-870	398	123	with	with	ADP
eurjchem-870	398	124	acetic	acetic	ADJ
eurjchem-870	398	125	anhydride	anhydride	NOUN
eurjchem-870	398	126	afforded	afford	VERB
eurjchem-870	398	127	the	the	DET
eurjchem-870	398	128	acetylated	acetylate	VERB
eurjchem-870	398	129	compounds	compound	NOUN
eurjchem-870	398	130	pyrazolo[3,4‐b]pyridin‐6‐	pyrazolo[3,4‐b]pyridin‐6‐	VERB
eurjchem-870	398	131	yl)acetamide	yl)acetamide	NOUN
eurjchem-870	398	132	(	(	PUNCT
eurjchem-870	398	133	10	10	NUM
eurjchem-870	398	134	)	)	PUNCT
eurjchem-870	398	135	and	and	CCONJ
eurjchem-870	398	136	dihydropyrano[2,3‐c]‐pyrazol‐6‐	dihydropyrano[2,3‐c]‐pyrazol‐6‐	ADJ
eurjchem-870	398	137	yl)acetamide	yl)acetamide	NOUN
eurjchem-870	398	138	11	11	NUM
eurjchem-870	398	139	,	,	PUNCT
eurjchem-870	398	140	respectively	respectively	ADV
eurjchem-870	398	141	.	.	PUNCT
eurjchem-870	399	1	the	the	DET
eurjchem-870	399	2	structures	structure	NOUN
eurjchem-870	399	3	of	of	ADP
eurjchem-870	399	4	these	these	DET
eurjchem-870	399	5	compounds	compound	NOUN
eurjchem-870	399	6	were	be	AUX
eurjchem-870	399	7	confirmed	confirm	VERB
eurjchem-870	399	8	by	by	ADP
eurjchem-870	399	9	spectroscopic	spectroscopic	ADJ
eurjchem-870	399	10	data	datum	NOUN
eurjchem-870	399	11	and	and	CCONJ
eurjchem-870	399	12	also	also	ADV
eurjchem-870	399	13	the	the	DET
eurjchem-870	399	14	reaction	reaction	NOUN
eurjchem-870	399	15	of	of	ADP
eurjchem-870	399	16	compound	compound	NOUN
eurjchem-870	399	17	11	11	NUM
eurjchem-870	399	18	with	with	ADP
eurjchem-870	399	19	hydrazine	hydrazine	NOUN
eurjchem-870	399	20	hydrate	hydrate	NOUN
eurjchem-870	399	21	to	to	PART
eurjchem-870	399	22	give	give	VERB
eurjchem-870	399	23	the	the	DET
eurjchem-870	399	24	bis	bis	ADJ
eurjchem-870	399	25	compound	compound	NOUN
eurjchem-870	399	26	12	12	NUM
eurjchem-870	399	27	.	.	PUNCT
eurjchem-870	400	1	the	the	DET
eurjchem-870	400	2	hydrazine	hydrazine	NOUN
eurjchem-870	400	3	hydrate	hydrate	NOUN
eurjchem-870	400	4	is	be	AUX
eurjchem-870	400	5	an	an	DET
eurjchem-870	400	6	ambident	ambident	ADJ
eurjchem-870	400	7	nucleophile	nucleophile	NOUN
eurjchem-870	400	8	therefore	therefore	ADV
eurjchem-870	400	9	one	one	NUM
eurjchem-870	400	10	molecule	molecule	NOUN
eurjchem-870	400	11	of	of	ADP
eurjchem-870	400	12	it	it	PRON
eurjchem-870	400	13	attacks	attack	VERB
eurjchem-870	400	14	two	two	NUM
eurjchem-870	400	15	molecules	molecule	NOUN
eurjchem-870	400	16	of	of	ADP
eurjchem-870	400	17	compound	compound	NOUN
eurjchem-870	400	18	11	11	NUM
eurjchem-870	400	19	followed	follow	VERB
eurjchem-870	400	20	by	by	ADP
eurjchem-870	400	21	hydrogenation	hydrogenation	NOUN
eurjchem-870	400	22	to	to	PART
eurjchem-870	400	23	afford	afford	VERB
eurjchem-870	400	24	the	the	DET
eurjchem-870	400	25	bis	bis	ADJ
eurjchem-870	400	26	compound	compound	NOUN
eurjchem-870	401	1	12	12	NUM
eurjchem-870	401	2	(	(	PUNCT
eurjchem-870	401	3	scheme	scheme	NOUN
eurjchem-870	401	4	1	1	NUM
eurjchem-870	401	5	)	)	PUNCT
eurjchem-870	401	6	.	.	PUNCT
eurjchem-870	402	1	condensation	condensation	NOUN
eurjchem-870	402	2	of	of	ADP
eurjchem-870	402	3	pyrazolone	pyrazolone	NOUN
eurjchem-870	402	4	3	3	NUM
eurjchem-870	402	5	with	with	ADP
eurjchem-870	402	6	glucose	glucose	NOUN
eurjchem-870	402	7	in	in	ADP
eurjchem-870	402	8	ethanol	ethanol	NOUN
eurjchem-870	402	9	/	/	SYM
eurjchem-870	402	10	dmf	dmf	PROPN
eurjchem-870	402	11	/	/	SYM
eurjchem-870	402	12	drops	drop	NOUN
eurjchem-870	402	13	of	of	ADP
eurjchem-870	402	14	acoh	acoh	ADJ
eurjchem-870	402	15	mixture	mixture	NOUN
eurjchem-870	402	16	furnished	furnish	VERB
eurjchem-870	402	17	the	the	DET
eurjchem-870	402	18	penta	penta	ADJ
eurjchem-870	402	19	hydroxy	hydroxy	PROPN
eurjchem-870	402	20	hexylidene	hexylidene	NOUN
eurjchem-870	402	21	pyrazolone	pyrazolone	NOUN
eurjchem-870	402	22	derivative	derivative	ADJ
eurjchem-870	402	23	13	13	NUM
eurjchem-870	402	24	.	.	PUNCT
eurjchem-870	403	1	the	the	DET
eurjchem-870	403	2	active	active	ADJ
eurjchem-870	403	3	methylene	methylene	NOUN
eurjchem-870	403	4	group	group	NOUN
eurjchem-870	403	5	of	of	ADP
eurjchem-870	403	6	pyrazolone	pyrazolone	NOUN
eurjchem-870	403	7	3	3	NUM
eurjchem-870	403	8	reacted	react	VERB
eurjchem-870	403	9	with	with	ADP
eurjchem-870	403	10	phenyl	phenyl	NOUN
eurjchem-870	403	11	isothiocyanate	isothiocyanate	NOUN
eurjchem-870	403	12	[	[	X
eurjchem-870	403	13	19	19	NUM
eurjchem-870	403	14	]	]	PUNCT
eurjchem-870	403	15	in	in	ADP
eurjchem-870	403	16	the	the	DET
eurjchem-870	403	17	presence	presence	NOUN
eurjchem-870	403	18	of	of	ADP
eurjchem-870	403	19	piperidine	piperidine	NOUN
eurjchem-870	403	20	to	to	PART
eurjchem-870	403	21	give	give	VERB
eurjchem-870	403	22	an	an	DET
eurjchem-870	403	23	intermediate	intermediate	ADJ
eurjchem-870	403	24	thiolate	thiolate	ADJ
eurjchem-870	403	25	anion	anion	NOUN
eurjchem-870	403	26	14	14	NUM
eurjchem-870	403	27	which	which	PRON
eurjchem-870	403	28	upon	upon	SCONJ
eurjchem-870	403	29	treatment	treatment	NOUN
eurjchem-870	403	30	with	with	ADP
eurjchem-870	403	31	dilute	dilute	ADJ
eurjchem-870	403	32	hydrochloric	hydrochloric	ADJ
eurjchem-870	403	33	acid	acid	NOUN
eurjchem-870	403	34	furnished	furnish	VERB
eurjchem-870	403	35	functionalized	functionalize	VERB
eurjchem-870	403	36	thioamide	thioamide	ADP
eurjchem-870	403	37	15	15	NUM
eurjchem-870	403	38	(	(	PUNCT
eurjchem-870	403	39	scheme	scheme	NOUN
eurjchem-870	403	40	2	2	NUM
eurjchem-870	403	41	)	)	PUNCT
eurjchem-870	403	42	.	.	PUNCT
eurjchem-870	404	1	compound	compound	NOUN
eurjchem-870	404	2	15	15	NUM
eurjchem-870	404	3	is	be	AUX
eurjchem-870	404	4	a	a	DET
eurjchem-870	404	5	versatile	versatile	ADJ
eurjchem-870	404	6	multifunctional	multifunctional	ADJ
eurjchem-870	404	7	reagent	reagent	NOUN
eurjchem-870	404	8	which	which	PRON
eurjchem-870	404	9	reacted	react	VERB
eurjchem-870	404	10	with	with	ADP
eurjchem-870	404	11	hydrazine	hydrazine	NOUN
eurjchem-870	404	12	hydrate	hydrate	NOUN
eurjchem-870	404	13	to	to	PART
eurjchem-870	404	14	afford	afford	VERB
eurjchem-870	404	15	pyrazolo[3,4‐	pyrazolo[3,4‐	NOUN
eurjchem-870	404	16	c]pyrazolethione	c]pyrazolethione	X
eurjchem-870	404	17	16	16	NUM
eurjchem-870	404	18	.	.	PUNCT
eurjchem-870	405	1	novel	novel	NOUN
eurjchem-870	405	2	4‐thiazolyl	4‐thiazolyl	ADJ
eurjchem-870	405	3	diazenyl‐1h‐pyrazol‐5‐one	diazenyl‐1h‐pyrazol‐5‐one	NOUN
eurjchem-870	405	4	(	(	PUNCT
eurjchem-870	405	5	17	17	NUM
eurjchem-870	405	6	)	)	PUNCT
eurjchem-870	405	7	and	and	CCONJ
eurjchem-870	405	8	4‐(phenyldiazenyl)‐1h‐pyrazol‐5‐ol	4‐(phenyldiazenyl)‐1h‐pyrazol‐5‐ol	NUM
eurjchem-870	405	9	(	(	PUNCT
eurjchem-870	405	10	18	18	NUM
eurjchem-870	405	11	)	)	PUNCT
eurjchem-870	405	12	have	have	AUX
eurjchem-870	405	13	been	be	AUX
eurjchem-870	405	14	obtained	obtain	VERB
eurjchem-870	405	15	as	as	ADP
eurjchem-870	405	16	red	red	ADJ
eurjchem-870	405	17	and	and	CCONJ
eurjchem-870	405	18	orange	orange	ADJ
eurjchem-870	405	19	dyes	dye	NOUN
eurjchem-870	405	20	respectively	respectively	ADV
eurjchem-870	405	21	via	via	ADP
eurjchem-870	405	22	the	the	DET
eurjchem-870	405	23	diazonium	diazonium	NOUN
eurjchem-870	405	24	cation	cation	NOUN
eurjchem-870	405	25	resulting	result	VERB
eurjchem-870	405	26	from	from	ADP
eurjchem-870	405	27	the	the	DET
eurjchem-870	405	28	interaction	interaction	NOUN
eurjchem-870	405	29	of	of	ADP
eurjchem-870	405	30	nitrite	nitrite	NOUN
eurjchem-870	405	31	with	with	ADP
eurjchem-870	405	32	pyrazolone	pyrazolone	NOUN
eurjchem-870	405	33	3	3	NUM
eurjchem-870	405	34	followed	follow	VERB
eurjchem-870	405	35	by	by	ADP
eurjchem-870	405	36	coupling	couple	VERB
eurjchem-870	405	37	with	with	ADP
eurjchem-870	405	38	2‐aminothiazole	2‐aminothiazole	PROPN
eurjchem-870	405	39	and	and	CCONJ
eurjchem-870	405	40	aniline	aniline	NOUN
eurjchem-870	405	41	(	(	PUNCT
eurjchem-870	405	42	scheme	scheme	NOUN
eurjchem-870	405	43	2	2	NUM
eurjchem-870	405	44	)	)	PUNCT
eurjchem-870	405	45	.	.	PUNCT
eurjchem-870	406	1	the	the	DET
eurjchem-870	406	2	pyrazolone	pyrazolone	NOUN
eurjchem-870	406	3	3	3	NUM
eurjchem-870	406	4	was	be	AUX
eurjchem-870	406	5	reacted	react	VERB
eurjchem-870	406	6	with	with	ADP
eurjchem-870	406	7	p‐anisaldehyde	p‐anisaldehyde	PUNCT
eurjchem-870	407	1	[	[	X
eurjchem-870	407	2	17	17	NUM
eurjchem-870	407	3	]	]	PUNCT
eurjchem-870	407	4	in	in	ADP
eurjchem-870	407	5	the	the	DET
eurjchem-870	407	6	presence	presence	NOUN
eurjchem-870	407	7	of	of	ADP
eurjchem-870	407	8	piperidine	piperidine	NOUN
eurjchem-870	407	9	to	to	PART
eurjchem-870	407	10	give	give	VERB
eurjchem-870	407	11	the	the	DET
eurjchem-870	407	12	pyrazolone	pyrazolone	NOUN
eurjchem-870	407	13	19	19	NUM
eurjchem-870	407	14	according	accord	VERB
eurjchem-870	407	15	to	to	ADP
eurjchem-870	407	16	knoevenagel	knoevenagel	NOUN
eurjchem-870	407	17	condensation	condensation	NOUN
eurjchem-870	407	18	reaction	reaction	NOUN
eurjchem-870	407	19	which	which	PRON
eurjchem-870	407	20	is	be	AUX
eurjchem-870	407	21	an	an	DET
eurjchem-870	407	22	important	important	ADJ
eurjchem-870	407	23	tool	tool	NOUN
eurjchem-870	407	24	for	for	ADP
eurjchem-870	407	25	the	the	DET
eurjchem-870	407	26	formation	formation	NOUN
eurjchem-870	407	27	of	of	ADP
eurjchem-870	407	28	new	new	ADJ
eurjchem-870	407	29	carbon‐carbon	carbon‐carbon	NOUN
eurjchem-870	407	30	bonds	bond	NOUN
eurjchem-870	407	31	.	.	PUNCT
eurjchem-870	408	1	to	to	PART
eurjchem-870	408	2	show	show	VERB
eurjchem-870	408	3	the	the	DET
eurjchem-870	408	4	synthetic	synthetic	ADJ
eurjchem-870	408	5	potentiality	potentiality	NOUN
eurjchem-870	408	6	of	of	ADP
eurjchem-870	408	7	compound	compound	NOUN
eurjchem-870	408	8	19	19	NUM
eurjchem-870	408	9	,	,	PUNCT
eurjchem-870	408	10	the	the	DET
eurjchem-870	408	11	reactivity	reactivity	NOUN
eurjchem-870	408	12	of	of	ADP
eurjchem-870	408	13	compound	compound	NOUN
eurjchem-870	408	14	19	19	NUM
eurjchem-870	408	15	with	with	ADP
eurjchem-870	408	16	different	different	ADJ
eurjchem-870	408	17	nitrogen	nitrogen	NOUN
eurjchem-870	408	18	nucleophiles	nucleophile	NOUN
eurjchem-870	408	19	such	such	ADJ
eurjchem-870	408	20	as	as	ADP
eurjchem-870	408	21	hydrazine	hydrazine	NOUN
eurjchem-870	408	22	hydrate	hydrate	NOUN
eurjchem-870	408	23	,	,	PUNCT
eurjchem-870	408	24	urea	urea	NOUN
eurjchem-870	408	25	,	,	PUNCT
eurjchem-870	408	26	thiourea	thiourea	NOUN
eurjchem-870	408	27	and	and	CCONJ
eurjchem-870	408	28	hydroxylamine	hydroxylamine	ADJ
eurjchem-870	408	29	hydrochloride	hydrochloride	NOUN
eurjchem-870	408	30	was	be	AUX
eurjchem-870	408	31	examined	examine	VERB
eurjchem-870	408	32	(	(	PUNCT
eurjchem-870	408	33	scheme	scheme	NOUN
eurjchem-870	408	34	3,4	3,4	NUM
eurjchem-870	408	35	)	)	PUNCT
eurjchem-870	408	36	.	.	PUNCT
eurjchem-870	409	1	reactions	reaction	NOUN
eurjchem-870	409	2	of	of	ADP
eurjchem-870	409	3	compound	compound	NOUN
eurjchem-870	409	4	19	19	NUM
eurjchem-870	409	5	with	with	ADP
eurjchem-870	409	6	hydrazine	hydrazine	NOUN
eurjchem-870	409	7	hydrate	hydrate	NOUN
eurjchem-870	409	8	and	and	CCONJ
eurjchem-870	409	9	urea	urea	NOUN
eurjchem-870	409	10	afforded	afford	VERB
eurjchem-870	409	11	pyrazolo[3,4‐c]pyrazole	pyrazolo[3,4‐c]pyrazole	PROPN
eurjchem-870	409	12	(	(	PUNCT
eurjchem-870	409	13	22	22	NUM
eurjchem-870	409	14	)	)	PUNCT
eurjchem-870	409	15	and	and	CCONJ
eurjchem-870	409	16	pyrazolo[3,4‐	pyrazolo[3,4‐	PROPN
eurjchem-870	409	17	d]pyrimidinone	d]pyrimidinone	PROPN
eurjchem-870	409	18	(	(	PUNCT
eurjchem-870	409	19	23	23	NUM
eurjchem-870	409	20	)	)	PUNCT
eurjchem-870	409	21	via	via	ADP
eurjchem-870	409	22	β‐attack	β‐attack	PUNCT
eurjchem-870	409	23	on	on	ADP
eurjchem-870	409	24	the	the	DET
eurjchem-870	409	25	c	c	PROPN
eurjchem-870	409	26	=	=	NOUN
eurjchem-870	409	27	c	c	NOUN
eurjchem-870	409	28	moiety	moiety	NOUN
eurjchem-870	409	29	in	in	ADP
eurjchem-870	409	30	compound	compound	NOUN
eurjchem-870	409	31	19	19	NUM
eurjchem-870	409	32	to	to	PART
eurjchem-870	409	33	give	give	VERB
eurjchem-870	409	34	the	the	DET
eurjchem-870	409	35	non‐isolable	non‐isolable	ADJ
eurjchem-870	409	36	intermediates	intermediate	NOUN
eurjchem-870	409	37	20	20	NUM
eurjchem-870	409	38	,	,	PUNCT
eurjchem-870	409	39	21a	21a	NUM
eurjchem-870	409	40	,	,	PUNCT
eurjchem-870	409	41	which	which	PRON
eurjchem-870	409	42	underwent	undergo	VERB
eurjchem-870	409	43	1,5	1,5	NUM
eurjchem-870	409	44	and	and	CCONJ
eurjchem-870	409	45	1,6	1,6	NUM
eurjchem-870	409	46	intramolecular	intramolecular	ADJ
eurjchem-870	409	47	dipolar	dipolar	ADJ
eurjchem-870	409	48	cyclization	cyclization	NOUN
eurjchem-870	409	49	.	.	PUNCT
eurjchem-870	410	1	reaction	reaction	NOUN
eurjchem-870	410	2	of	of	ADP
eurjchem-870	410	3	thiourea	thiourea	NOUN
eurjchem-870	410	4	with	with	ADP
eurjchem-870	410	5	compound	compound	PROPN
eurjchem-870	410	6	19	19	NUM
eurjchem-870	410	7	via	via	ADP
eurjchem-870	410	8	β‐attack	β‐attack	PUNCT
eurjchem-870	410	9	on	on	ADP
eurjchem-870	410	10	the	the	DET
eurjchem-870	410	11	c	c	PROPN
eurjchem-870	410	12	=	=	NOUN
eurjchem-870	410	13	c	c	NOUN
eurjchem-870	410	14	moiety	moiety	NOUN
eurjchem-870	410	15	in	in	ADP
eurjchem-870	410	16	compound	compound	NOUN
eurjchem-870	410	17	19	19	NUM
eurjchem-870	410	18	gave	give	VERB
eurjchem-870	410	19	the	the	DET
eurjchem-870	410	20	non‐isolable	non‐isolable	ADJ
eurjchem-870	410	21	intermediate	intermediate	ADJ
eurjchem-870	410	22	21b	21b	NOUN
eurjchem-870	410	23	which	which	PRON
eurjchem-870	410	24	underwent	undergo	VERB
eurjchem-870	410	25	1,6	1,6	NUM
eurjchem-870	410	26	intramolecular	intramolecular	ADJ
eurjchem-870	410	27	dipolar	dipolar	ADJ
eurjchem-870	410	28	cyclization	cyclization	NOUN
eurjchem-870	410	29	through	through	ADP
eurjchem-870	410	30	the	the	DET
eurjchem-870	410	31	sulfur	sulfur	NOUN
eurjchem-870	410	32	atom	atom	NOUN
eurjchem-870	410	33	,	,	PUNCT
eurjchem-870	410	34	followed	follow	VERB
eurjchem-870	410	35	by	by	ADP
eurjchem-870	410	36	the	the	DET
eurjchem-870	410	37	loss	loss	NOUN
eurjchem-870	410	38	of	of	ADP
eurjchem-870	410	39	ammonia	ammonia	NOUN
eurjchem-870	410	40	through	through	ADP
eurjchem-870	410	41	the	the	DET
eurjchem-870	410	42	reaction	reaction	NOUN
eurjchem-870	410	43	with	with	ADP
eurjchem-870	410	44	another	another	DET
eurjchem-870	410	45	molecule	molecule	NOUN
eurjchem-870	410	46	of	of	ADP
eurjchem-870	410	47	thiourea	thiourea	NOUN
eurjchem-870	410	48	to	to	PART
eurjchem-870	410	49	give	give	VERB
eurjchem-870	410	50	pyrazolo[4,3‐e][1,3]thiazinyl	pyrazolo[4,3‐e][1,3]thiazinyl	ADJ
eurjchem-870	410	51	thiourea	thiourea	NOUN
eurjchem-870	410	52	(	(	PUNCT
eurjchem-870	410	53	24	24	NUM
eurjchem-870	410	54	)	)	PUNCT
eurjchem-870	410	55	.	.	PUNCT
eurjchem-870	411	1	hydroxylamine	hydroxylamine	PROPN
eurjchem-870	411	2	hydrochloride	hydrochloride	NOUN
eurjchem-870	411	3	was	be	AUX
eurjchem-870	411	4	reacted	react	VERB
eurjchem-870	411	5	with	with	ADP
eurjchem-870	411	6	compound	compound	NOUN
eurjchem-870	411	7	19	19	NUM
eurjchem-870	411	8	in	in	ADP
eurjchem-870	411	9	the	the	DET
eurjchem-870	411	10	presence	presence	NOUN
eurjchem-870	411	11	of	of	ADP
eurjchem-870	411	12	pyridine	pyridine	NOUN
eurjchem-870	411	13	to	to	PART
eurjchem-870	411	14	give	give	VERB
eurjchem-870	411	15	pyrazolo[3,4‐c]isoxazole	pyrazolo[3,4‐c]isoxazole	NOUN
eurjchem-870	411	16	(	(	PUNCT
eurjchem-870	411	17	25	25	NUM
eurjchem-870	411	18	)	)	PUNCT
eurjchem-870	411	19	.	.	PUNCT
eurjchem-870	412	1	in	in	ADP
eurjchem-870	412	2	this	this	DET
eurjchem-870	412	3	work	work	NOUN
eurjchem-870	412	4	,	,	PUNCT
eurjchem-870	412	5	we	we	PRON
eurjchem-870	412	6	aim	aim	VERB
eurjchem-870	412	7	to	to	PART
eurjchem-870	412	8	study	study	VERB
eurjchem-870	412	9	the	the	DET
eurjchem-870	412	10	reactivity	reactivity	NOUN
eurjchem-870	412	11	of	of	ADP
eurjchem-870	412	12	compound	compound	NOUN
eurjchem-870	412	13	19	19	NUM
eurjchem-870	412	14	as	as	ADP
eurjchem-870	412	15	α	α	PROPN
eurjchem-870	412	16	,	,	PUNCT
eurjchem-870	412	17	β‐unsaturated	β‐unsaturate	VERB
eurjchem-870	412	18	compound	compound	NOUN
eurjchem-870	412	19	towards	towards	ADP
eurjchem-870	412	20	several	several	ADJ
eurjchem-870	412	21	carbon	carbon	NOUN
eurjchem-870	412	22	nucleophiles	nucleophile	NOUN
eurjchem-870	412	23	under	under	ADP
eurjchem-870	412	24	michael	michael	PROPN
eurjchem-870	412	25	reaction	reaction	NOUN
eurjchem-870	412	26	(	(	PUNCT
eurjchem-870	412	27	scheme	scheme	NOUN
eurjchem-870	412	28	4	4	NUM
eurjchem-870	412	29	)	)	PUNCT
eurjchem-870	412	30	.	.	PUNCT
eurjchem-870	413	1	the	the	DET
eurjchem-870	413	2	formation	formation	NOUN
eurjchem-870	413	3	of	of	ADP
eurjchem-870	413	4	pyrano[2,3‐c	pyrano[2,3‐c	NOUN
eurjchem-870	413	5	]	]	X
eurjchem-870	413	6	pyrazolyl	pyrazolyl	ADJ
eurjchem-870	413	7	ethanone	ethanone	NOUN
eurjchem-870	413	8	(	(	PUNCT
eurjchem-870	413	9	26	26	NUM
eurjchem-870	413	10	)	)	PUNCT
eurjchem-870	413	11	and	and	CCONJ
eurjchem-870	413	12	pyrazolo[3,4‐b]pyridinyl	pyrazolo[3,4‐b]pyridinyl	ADJ
eurjchem-870	413	13	ethanone	ethanone	NOUN
eurjchem-870	413	14	(	(	PUNCT
eurjchem-870	413	15	27	27	NUM
eurjchem-870	413	16	)	)	PUNCT
eurjchem-870	413	17	seems	seem	VERB
eurjchem-870	413	18	to	to	PART
eurjchem-870	413	19	proceed	proceed	VERB
eurjchem-870	413	20	by	by	ADP
eurjchem-870	413	21	the	the	DET
eurjchem-870	413	22	addition	addition	NOUN
eurjchem-870	413	23	of	of	ADP
eurjchem-870	413	24	the	the	DET
eurjchem-870	413	25	nucleophile	nucleophile	ADJ
eurjchem-870	413	26	ethyl	ethyl	NOUN
eurjchem-870	413	27	acetoacetate	acetoacetate	NOUN
eurjchem-870	413	28	on	on	ADP
eurjchem-870	413	29	the	the	DET
eurjchem-870	413	30	β‐	β‐	ADJ
eurjchem-870	413	31	carbon	carbon	NOUN
eurjchem-870	413	32	of	of	ADP
eurjchem-870	413	33	the	the	DET
eurjchem-870	413	34	electrophile	electrophile	NOUN
eurjchem-870	413	35	(	(	PUNCT
eurjchem-870	413	36	19	19	NUM
eurjchem-870	413	37	)	)	PUNCT
eurjchem-870	413	38	in	in	ADP
eurjchem-870	413	39	a	a	DET
eurjchem-870	413	40	conjugate	conjugate	ADJ
eurjchem-870	413	41	addition	addition	NOUN
eurjchem-870	413	42	reaction	reaction	NOUN
eurjchem-870	413	43	in	in	ADP
eurjchem-870	413	44	the	the	DET
eurjchem-870	413	45	presence	presence	NOUN
eurjchem-870	413	46	of	of	ADP
eurjchem-870	413	47	sodium	sodium	NOUN
eurjchem-870	413	48	ethoxide	ethoxide	NOUN
eurjchem-870	413	49	and/or	and/or	CCONJ
eurjchem-870	413	50	ammonium	ammonium	NOUN
eurjchem-870	413	51	acetate	acetate	NOUN
eurjchem-870	413	52	followed	follow	VERB
eurjchem-870	413	53	by	by	ADP
eurjchem-870	413	54	6‐exo‐dig	6‐exo‐dig	NUM
eurjchem-870	413	55	cyclization	cyclization	NOUN
eurjchem-870	413	56	and	and	CCONJ
eurjchem-870	413	57	dehydrogenation	dehydrogenation	NOUN
eurjchem-870	413	58	.	.	PUNCT
eurjchem-870	414	1	similarly	similarly	ADV
eurjchem-870	414	2	compound	compound	VERB
eurjchem-870	414	3	28	28	NUM
eurjchem-870	414	4	is	be	AUX
eurjchem-870	414	5	formed	form	VERB
eurjchem-870	414	6	by	by	ADP
eurjchem-870	414	7	the	the	DET
eurjchem-870	414	8	addition	addition	NOUN
eurjchem-870	414	9	of	of	ADP
eurjchem-870	414	10	ethyl	ethyl	PROPN
eurjchem-870	414	11	cyanoacetate	cyanoacetate	NOUN
eurjchem-870	414	12	to	to	ADP
eurjchem-870	414	13	pyrazolone	pyrazolone	NOUN
eurjchem-870	414	14	3	3	NUM
eurjchem-870	414	15	in	in	ADP
eurjchem-870	414	16	the	the	DET
eurjchem-870	414	17	presence	presence	NOUN
eurjchem-870	414	18	of	of	ADP
eurjchem-870	414	19	sodium	sodium	NOUN
eurjchem-870	414	20	ethoxide	ethoxide	NOUN
eurjchem-870	414	21	.	.	PUNCT
eurjchem-870	415	1	the	the	DET
eurjchem-870	415	2	addition	addition	NOUN
eurjchem-870	415	3	of	of	ADP
eurjchem-870	415	4	malononitrile	malononitrile	NOUN
eurjchem-870	415	5	to	to	PART
eurjchem-870	415	6	compound	compound	VERB
eurjchem-870	415	7	19	19	NUM
eurjchem-870	415	8	in	in	ADP
eurjchem-870	415	9	the	the	DET
eurjchem-870	415	10	presence	presence	NOUN
eurjchem-870	415	11	of	of	ADP
eurjchem-870	415	12	piperidine	piperidine	NOUN
eurjchem-870	415	13	afforded	afford	VERB
eurjchem-870	415	14	the	the	DET
eurjchem-870	415	15	adduct	adduct	NOUN
eurjchem-870	415	16	compound	compound	NOUN
eurjchem-870	415	17	29	29	NUM
eurjchem-870	415	18	which	which	PRON
eurjchem-870	415	19	exists	exist	VERB
eurjchem-870	415	20	in	in	ADP
eurjchem-870	415	21	the	the	DET
eurjchem-870	415	22	keto	keto	NOUN
eurjchem-870	415	23	/	/	SYM
eurjchem-870	415	24	enol	enol	NOUN
eurjchem-870	415	25	forms	form	NOUN
eurjchem-870	415	26	which	which	PRON
eurjchem-870	415	27	was	be	AUX
eurjchem-870	415	28	inferred	infer	VERB
eurjchem-870	415	29	from	from	ADP
eurjchem-870	415	30	its	its	PRON
eurjchem-870	415	31	spectroscopic	spectroscopic	ADJ
eurjchem-870	415	32	data	datum	NOUN
eurjchem-870	415	33	.	.	PUNCT
eurjchem-870	416	1	ir	ir	PROPN
eurjchem-870	416	2	spectrum	spectrum	PROPN
eurjchem-870	416	3	showed	show	VERB
eurjchem-870	416	4	bands	band	NOUN
eurjchem-870	416	5	at	at	ADP
eurjchem-870	416	6	1639	1639	NUM
eurjchem-870	416	7	cm‐1	cm‐1	PROPN
eurjchem-870	416	8	for	for	ADP
eurjchem-870	416	9	c	c	NOUN
eurjchem-870	416	10	=	=	NOUN
eurjchem-870	416	11	o	o	NOUN
eurjchem-870	416	12	,	,	PUNCT
eurjchem-870	416	13	and	and	CCONJ
eurjchem-870	416	14	3328	3328	NUM
eurjchem-870	416	15	cm‐1	cm‐1	NOUN
eurjchem-870	416	16	due	due	ADP
eurjchem-870	416	17	to	to	ADP
eurjchem-870	416	18	oh	oh	PROPN
eurjchem-870	416	19	,	,	PUNCT
eurjchem-870	416	20	1h	1h	NUM
eurjchem-870	416	21	nmr	nmr	NOUN
eurjchem-870	416	22	spectrum	spectrum	NOUN
eurjchem-870	416	23	showed	show	VERB
eurjchem-870	416	24	δ	δ	PROPN
eurjchem-870	416	25	18.11	18.11	NUM
eurjchem-870	416	26	ppm	ppm	NOUN
eurjchem-870	416	27	for	for	ADP
eurjchem-870	416	28	oh	oh	INTJ
eurjchem-870	416	29	.	.	PUNCT
eurjchem-870	417	1	on	on	ADP
eurjchem-870	417	2	the	the	DET
eurjchem-870	417	3	other	other	ADJ
eurjchem-870	417	4	hand	hand	NOUN
eurjchem-870	417	5	,	,	PUNCT
eurjchem-870	417	6	the	the	DET
eurjchem-870	417	7	addition	addition	NOUN
eurjchem-870	417	8	of	of	ADP
eurjchem-870	417	9	malononitrile	malononitrile	NOUN
eurjchem-870	417	10	to	to	PART
eurjchem-870	417	11	compound	compound	VERB
eurjchem-870	417	12	19	19	NUM
eurjchem-870	417	13	in	in	ADP
eurjchem-870	417	14	the	the	DET
eurjchem-870	417	15	presence	presence	NOUN
eurjchem-870	417	16	of	of	ADP
eurjchem-870	417	17	sodium	sodium	NOUN
eurjchem-870	417	18	ethoxide	ethoxide	NOUN
eurjchem-870	417	19	and/or	and/or	CCONJ
eurjchem-870	417	20	ammonium	ammonium	NOUN
eurjchem-870	417	21	acetate	acetate	NOUN
eurjchem-870	417	22	afforded	afford	VERB
eurjchem-870	417	23	compounds	compound	NOUN
eurjchem-870	417	24	30	30	NUM
eurjchem-870	417	25	and	and	CCONJ
eurjchem-870	417	26	31	31	NUM
eurjchem-870	417	27	.	.	PUNCT
eurjchem-870	418	1	malononitirile	malononitirile	NOUN
eurjchem-870	418	2	was	be	AUX
eurjchem-870	418	3	added	add	VERB
eurjchem-870	418	4	to	to	ADP
eurjchem-870	418	5	the	the	PRON
eurjchem-870	418	6	β‐carbon	β‐carbon	PUNCT
eurjchem-870	418	7	of	of	ADP
eurjchem-870	418	8	compound	compound	NOUN
eurjchem-870	418	9	19	19	NUM
eurjchem-870	418	10	followed	follow	VERB
eurjchem-870	418	11	by	by	ADP
eurjchem-870	418	12	nucleophilic	nucleophilic	ADJ
eurjchem-870	418	13	addition	addition	NOUN
eurjchem-870	418	14	of	of	ADP
eurjchem-870	418	15	the	the	DET
eurjchem-870	418	16	hydroxyl	hydroxyl	NOUN
eurjchem-870	418	17	and/or	and/or	CCONJ
eurjchem-870	418	18	the	the	DET
eurjchem-870	418	19	amino	amino	NOUN
eurjchem-870	418	20	groups	group	NOUN
eurjchem-870	418	21	to	to	ADP
eurjchem-870	418	22	the	the	DET
eurjchem-870	418	23	cyano	cyano	NOUN
eurjchem-870	418	24	group	group	NOUN
eurjchem-870	418	25	through	through	ADP
eurjchem-870	418	26	6‐exo‐dig	6‐exo‐dig	NUM
eurjchem-870	418	27	cyclization	cyclization	NOUN
eurjchem-870	418	28	,	,	PUNCT
eurjchem-870	418	29	then	then	ADV
eurjchem-870	418	30	another	another	DET
eurjchem-870	418	31	molecule	molecule	NOUN
eurjchem-870	418	32	of	of	ADP
eurjchem-870	418	33	malononitrile	malononitrile	NOUN
eurjchem-870	418	34	was	be	AUX
eurjchem-870	418	35	attacked	attack	VERB
eurjchem-870	418	36	by	by	ADP
eurjchem-870	418	37	the	the	DET
eurjchem-870	418	38	formed	form	VERB
eurjchem-870	418	39	amino	amino	NOUN
eurjchem-870	418	40	group	group	NOUN
eurjchem-870	418	41	followed	follow	VERB
eurjchem-870	418	42	by	by	ADP
eurjchem-870	418	43	cyclization	cyclization	NOUN
eurjchem-870	418	44	and	and	CCONJ
eurjchem-870	418	45	hydrogen	hydrogen	NOUN
eurjchem-870	418	46	transfer	transfer	NOUN
eurjchem-870	418	47	to	to	PART
eurjchem-870	418	48	give	give	VERB
eurjchem-870	418	49	compounds	compound	NOUN
eurjchem-870	418	50	30	30	NUM
eurjchem-870	418	51	and	and	CCONJ
eurjchem-870	418	52	31	31	NUM
eurjchem-870	418	53	,	,	PUNCT
eurjchem-870	418	54	respectively	respectively	ADV
eurjchem-870	418	55	.	.	PUNCT
eurjchem-870	419	1	stirring	stirring	NOUN
eurjchem-870	419	2	of	of	ADP
eurjchem-870	419	3	compound	compound	NOUN
eurjchem-870	419	4	19	19	NUM
eurjchem-870	419	5	with	with	ADP
eurjchem-870	419	6	pyrazolone	pyrazolone	NOUN
eurjchem-870	419	7	(	(	PUNCT
eurjchem-870	419	8	3	3	NUM
eurjchem-870	419	9	)	)	PUNCT
eurjchem-870	419	10	in	in	ADP
eurjchem-870	419	11	the	the	DET
eurjchem-870	419	12	presence	presence	NOUN
eurjchem-870	419	13	of	of	ADP
eurjchem-870	419	14	sodium	sodium	NOUN
eurjchem-870	419	15	ethoxide	ethoxide	NOUN
eurjchem-870	419	16	afforded	afford	VERB
eurjchem-870	419	17	hydroxy	hydroxy	PROPN
eurjchem-870	419	18	pyrazolyl	pyrazolyl	ADJ
eurjchem-870	419	19	pyrazolol	pyrazolol	NOUN
eurjchem-870	419	20	(	(	PUNCT
eurjchem-870	419	21	32	32	NUM
eurjchem-870	419	22	)	)	PUNCT
eurjchem-870	419	23	.	.	PUNCT
eurjchem-870	420	1	it	it	PRON
eurjchem-870	420	2	was	be	AUX
eurjchem-870	420	3	observed	observe	VERB
eurjchem-870	420	4	that	that	SCONJ
eurjchem-870	420	5	microwave	microwave	NOUN
eurjchem-870	420	6	irradiation	irradiation	NOUN
eurjchem-870	420	7	method	method	NOUN
eurjchem-870	420	8	was	be	AUX
eurjchem-870	420	9	practically	practically	ADV
eurjchem-870	420	10	superior	superior	ADJ
eurjchem-870	420	11	to	to	ADP
eurjchem-870	420	12	conventional	conventional	ADJ
eurjchem-870	420	13	heating	heating	NOUN
eurjchem-870	420	14	method	method	NOUN
eurjchem-870	420	15	in	in	ADP
eurjchem-870	420	16	terms	term	NOUN
eurjchem-870	420	17	of	of	ADP
eurjchem-870	420	18	higher	high	ADJ
eurjchem-870	420	19	yields	yield	NOUN
eurjchem-870	420	20	,	,	PUNCT
eurjchem-870	420	21	rapid	rapid	ADJ
eurjchem-870	420	22	,	,	PUNCT
eurjchem-870	420	23	and	and	CCONJ
eurjchem-870	420	24	environmentally	environmentally	ADV
eurjchem-870	420	25	benign	benign	ADJ
eurjchem-870	420	26	process	process	NOUN
eurjchem-870	420	27	.	.	PUNCT
eurjchem-870	421	1	we	we	PRON
eurjchem-870	421	2	carried	carry	VERB
eurjchem-870	421	3	out	out	ADP
eurjchem-870	421	4	some	some	PRON
eurjchem-870	421	5	of	of	ADP
eurjchem-870	421	6	the	the	DET
eurjchem-870	421	7	reactions	reaction	NOUN
eurjchem-870	421	8	using	use	VERB
eurjchem-870	421	9	microwave	microwave	NOUN
eurjchem-870	421	10	irradiation	irradiation	NOUN
eurjchem-870	421	11	to	to	PART
eurjchem-870	421	12	improve	improve	VERB
eurjchem-870	421	13	the	the	DET
eurjchem-870	421	14	yield	yield	NOUN
eurjchem-870	421	15	and	and	CCONJ
eurjchem-870	421	16	the	the	DET
eurjchem-870	421	17	time	time	NOUN
eurjchem-870	421	18	of	of	ADP
eurjchem-870	421	19	the	the	DET
eurjchem-870	421	20	reactions	reaction	NOUN
eurjchem-870	421	21	.	.	PUNCT
eurjchem-870	422	1	synthesis	synthesis	NOUN
eurjchem-870	422	2	of	of	ADP
eurjchem-870	422	3	amino	amino	ADJ
eurjchem-870	422	4	carbonitriles	carbonitrile	NOUN
eurjchem-870	422	5	(	(	PUNCT
eurjchem-870	422	6	5	5	NUM
eurjchem-870	422	7	)	)	PUNCT
eurjchem-870	422	8	,	,	PUNCT
eurjchem-870	422	9	pyrazolone	pyrazolone	NOUN
eurjchem-870	422	10	(	(	PUNCT
eurjchem-870	422	11	19	19	NUM
eurjchem-870	422	12	)	)	PUNCT
eurjchem-870	422	13	and	and	CCONJ
eurjchem-870	422	14	pyrazolo[3,4‐	pyrazolo[3,4‐	PROPN
eurjchem-870	422	15	c]pyrazole	c]pyrazole	PROPN
eurjchem-870	422	16	(	(	PUNCT
eurjchem-870	422	17	22	22	NUM
eurjchem-870	422	18	)	)	PUNCT
eurjchem-870	422	19	under	under	ADP
eurjchem-870	422	20	microwave	microwave	NOUN
eurjchem-870	422	21	irradiation	irradiation	NOUN
eurjchem-870	422	22	showed	show	VERB
eurjchem-870	422	23	improvement	improvement	NOUN
eurjchem-870	422	24	in	in	ADP
eurjchem-870	422	25	the	the	DET
eurjchem-870	422	26	yield	yield	NOUN
eurjchem-870	422	27	and	and	CCONJ
eurjchem-870	422	28	the	the	DET
eurjchem-870	422	29	time	time	NOUN
eurjchem-870	422	30	of	of	ADP
eurjchem-870	422	31	the	the	DET
eurjchem-870	422	32	reactions	reaction	NOUN
eurjchem-870	422	33	(	(	PUNCT
eurjchem-870	422	34	table	table	NOUN
eurjchem-870	422	35	1	1	NUM
eurjchem-870	422	36	)	)	PUNCT
eurjchem-870	422	37	.	.	PUNCT
eurjchem-870	423	1	formation	formation	NOUN
eurjchem-870	423	2	of	of	ADP
eurjchem-870	423	3	compounds	compound	NOUN
eurjchem-870	423	4	5	5	NUM
eurjchem-870	423	5	,	,	PUNCT
eurjchem-870	423	6	19	19	NUM
eurjchem-870	423	7	and	and	CCONJ
eurjchem-870	423	8	22	22	NUM
eurjchem-870	423	9	under	under	ADP
eurjchem-870	423	10	microwave	microwave	NOUN
eurjchem-870	423	11	irradiation	irradiation	NOUN
eurjchem-870	423	12	produced	produce	VERB
eurjchem-870	423	13	the	the	DET
eurjchem-870	423	14	products	product	NOUN
eurjchem-870	423	15	in	in	ADP
eurjchem-870	423	16	good	good	ADJ
eurjchem-870	423	17	yield	yield	NOUN
eurjchem-870	423	18	within	within	ADP
eurjchem-870	423	19	2‐4	2‐4	NUM
eurjchem-870	423	20	minutes	minute	NOUN
eurjchem-870	423	21	.	.	PUNCT
eurjchem-870	424	1	the	the	DET
eurjchem-870	424	2	reactions	reaction	NOUN
eurjchem-870	424	3	were	be	AUX
eurjchem-870	424	4	carried	carry	VERB
eurjchem-870	424	5	out	out	ADP
eurjchem-870	424	6	under	under	ADP
eurjchem-870	424	7	solvent	solvent	ADJ
eurjchem-870	424	8	free	free	ADJ
eurjchem-870	424	9	conditions	condition	NOUN
eurjchem-870	424	10	to	to	PART
eurjchem-870	424	11	avoid	avoid	VERB
eurjchem-870	424	12	problems	problem	NOUN
eurjchem-870	424	13	associated	associate	VERB
eurjchem-870	424	14	with	with	ADP
eurjchem-870	424	15	solvent	solvent	ADJ
eurjchem-870	424	16	use	use	NOUN
eurjchem-870	424	17	such	such	ADJ
eurjchem-870	424	18	as	as	ADP
eurjchem-870	424	19	cost	cost	NOUN
eurjchem-870	424	20	,	,	PUNCT
eurjchem-870	424	21	handling	handling	NOUN
eurjchem-870	424	22	and	and	CCONJ
eurjchem-870	424	23	specifically	specifically	ADV
eurjchem-870	424	24	safety	safety	NOUN
eurjchem-870	424	25	,	,	PUNCT
eurjchem-870	424	26	because	because	SCONJ
eurjchem-870	424	27	of	of	ADP
eurjchem-870	424	28	fire	fire	NOUN
eurjchem-870	424	29	hazard	hazard	NOUN
eurjchem-870	424	30	due	due	ADP
eurjchem-870	424	31	to	to	ADP
eurjchem-870	424	32	occurrence	occurrence	NOUN
eurjchem-870	424	33	of	of	ADP
eurjchem-870	424	34	sparks	spark	NOUN
eurjchem-870	424	35	in	in	ADP
eurjchem-870	424	36	microwave	microwave	NOUN
eurjchem-870	424	37	ovens	oven	NOUN
eurjchem-870	424	38	.	.	PUNCT
eurjchem-870	425	1	the	the	DET
eurjchem-870	425	2	reactions	reaction	NOUN
eurjchem-870	425	3	were	be	AUX
eurjchem-870	425	4	less	less	ADV
eurjchem-870	425	5	effective	effective	ADJ
eurjchem-870	425	6	and	and	CCONJ
eurjchem-870	425	7	took	take	VERB
eurjchem-870	425	8	two	two	NUM
eurjchem-870	425	9	hours	hour	NOUN
eurjchem-870	425	10	to	to	PART
eurjchem-870	425	11	be	be	AUX
eurjchem-870	425	12	completed	complete	VERB
eurjchem-870	425	13	when	when	SCONJ
eurjchem-870	425	14	carried	carry	VERB
eurjchem-870	425	15	out	out	ADP
eurjchem-870	425	16	in	in	ADP
eurjchem-870	425	17	ethanol	ethanol	NOUN
eurjchem-870	425	18	under	under	ADP
eurjchem-870	425	19	reflux	reflux	NOUN
eurjchem-870	425	20	.	.	PROPN
eurjchem-870	426	1	3.2	3.2	NUM
eurjchem-870	426	2	.	.	PUNCT
eurjchem-870	427	1	antimicrobial	antimicrobial	ADJ
eurjchem-870	427	2	activities	activity	NOUN
eurjchem-870	427	3	32	32	NUM
eurjchem-870	427	4	marzouk	marzouk	ADV
eurjchem-870	427	5	et	et	PROPN
eurjchem-870	427	6	al	al	PROPN
eurjchem-870	427	7	.	.	PUNCT
eurjchem-870	427	8	/	/	SYM
eurjchem-870	427	9	european	european	PROPN
eurjchem-870	427	10	journal	journal	PROPN
eurjchem-870	427	11	of	of	ADP
eurjchem-870	427	12	chemistry	chemistry	NOUN
eurjchem-870	427	13	5	5	NUM
eurjchem-870	427	14	(	(	PUNCT
eurjchem-870	427	15	1	1	NUM
eurjchem-870	427	16	)	)	PUNCT
eurjchem-870	427	17	(	(	PUNCT
eurjchem-870	427	18	2014	2014	NUM
eurjchem-870	427	19	)	)	PUNCT
eurjchem-870	427	20	24‐32	24‐32	NUM
eurjchem-870	427	21	compound	compound	NOUN
eurjchem-870	427	22	27	27	NUM
eurjchem-870	427	23	showed	show	VERB
eurjchem-870	427	24	higher	high	ADJ
eurjchem-870	427	25	reactivity	reactivity	NOUN
eurjchem-870	427	26	towards	towards	ADP
eurjchem-870	427	27	bacillus	bacillus	NOUN
eurjchem-870	427	28	subtilis	subtili	NOUN
eurjchem-870	427	29	than	than	ADP
eurjchem-870	427	30	the	the	DET
eurjchem-870	427	31	reference	reference	NOUN
eurjchem-870	427	32	and	and	CCONJ
eurjchem-870	427	33	high	high	ADJ
eurjchem-870	427	34	reactivity	reactivity	NOUN
eurjchem-870	427	35	towards	towards	ADP
eurjchem-870	427	36	gram	gram	PROPN
eurjchem-870	427	37	‐ve	‐ve	NOUN
eurjchem-870	427	38	bacteria	bacteria	NOUN
eurjchem-870	427	39	,	,	PUNCT
eurjchem-870	427	40	gram	gram	PROPN
eurjchem-870	427	41	+	+	PROPN
eurjchem-870	427	42	ve	ve	NOUN
eurjchem-870	427	43	bacteria	bacteria	NOUN
eurjchem-870	427	44	and	and	CCONJ
eurjchem-870	427	45	fungi	fungus	NOUN
eurjchem-870	427	46	.	.	PUNCT
eurjchem-870	428	1	compound	compound	NOUN
eurjchem-870	428	2	31	31	NUM
eurjchem-870	428	3	showed	show	VERB
eurjchem-870	428	4	moderate	moderate	ADJ
eurjchem-870	428	5	reactivity	reactivity	NOUN
eurjchem-870	428	6	towards	towards	ADP
eurjchem-870	428	7	gram	gram	PROPN
eurjchem-870	428	8	‐ve	‐ve	NOUN
eurjchem-870	428	9	bacteria	bacteria	NOUN
eurjchem-870	428	10	,	,	PUNCT
eurjchem-870	428	11	gram	gram	PROPN
eurjchem-870	428	12	+	+	PROPN
eurjchem-870	428	13	ve	ve	NOUN
eurjchem-870	428	14	bacteria	bacteria	NOUN
eurjchem-870	428	15	and	and	CCONJ
eurjchem-870	428	16	fungi	fungus	NOUN
eurjchem-870	428	17	.	.	PUNCT
eurjchem-870	429	1	compound	compound	NOUN
eurjchem-870	429	2	8	8	NUM
eurjchem-870	429	3	showed	show	VERB
eurjchem-870	429	4	no	no	DET
eurjchem-870	429	5	reactivity	reactivity	NOUN
eurjchem-870	429	6	towards	towards	ADP
eurjchem-870	429	7	gram	gram	PROPN
eurjchem-870	429	8	‐ve	‐ve	NOUN
eurjchem-870	429	9	bacteria	bacteria	NOUN
eurjchem-870	429	10	,	,	PUNCT
eurjchem-870	429	11	gram	gram	PROPN
eurjchem-870	429	12	+	+	PROPN
eurjchem-870	429	13	ve	ve	NOUN
eurjchem-870	429	14	bacteria	bacteria	NOUN
eurjchem-870	429	15	and	and	CCONJ
eurjchem-870	429	16	fungi	fungus	NOUN
eurjchem-870	429	17	(	(	PUNCT
eurjchem-870	429	18	table	table	NOUN
eurjchem-870	429	19	2	2	NUM
eurjchem-870	429	20	)	)	PUNCT
eurjchem-870	429	21	.	.	PUNCT
eurjchem-870	430	1	4	4	X
eurjchem-870	430	2	.	.	X
eurjchem-870	430	3	conclusion	conclusion	NOUN
eurjchem-870	430	4	pyrazolone	pyrazolone	NOUN
eurjchem-870	430	5	3	3	NUM
eurjchem-870	430	6	is	be	AUX
eurjchem-870	430	7	an	an	DET
eurjchem-870	430	8	active	active	ADJ
eurjchem-870	430	9	compound	compound	NOUN
eurjchem-870	430	10	towards	towards	ADP
eurjchem-870	430	11	condensation	condensation	NOUN
eurjchem-870	430	12	reactions	reaction	NOUN
eurjchem-870	430	13	.	.	PUNCT
eurjchem-870	431	1	pyrazolone	pyrazolone	NOUN
eurjchem-870	431	2	19	19	NUM
eurjchem-870	431	3	acts	act	NOUN
eurjchem-870	431	4	as	as	ADP
eurjchem-870	431	5	an	an	DET
eurjchem-870	431	6	α	α	NOUN
eurjchem-870	431	7	,	,	PUNCT
eurjchem-870	431	8	β‐unsaturated	β‐unsaturate	VERB
eurjchem-870	431	9	compound	compound	NOUN
eurjchem-870	431	10	towards	towards	ADP
eurjchem-870	431	11	different	different	ADJ
eurjchem-870	431	12	carbon	carbon	NOUN
eurjchem-870	431	13	and	and	CCONJ
eurjchem-870	431	14	nitrogen	nitrogen	NOUN
eurjchem-870	431	15	nucleophiles	nucleophile	NOUN
eurjchem-870	431	16	.	.	PUNCT
eurjchem-870	432	1	microwave	microwave	NOUN
eurjchem-870	432	2	irradiation	irradiation	NOUN
eurjchem-870	432	3	method	method	NOUN
eurjchem-870	432	4	was	be	AUX
eurjchem-870	432	5	practically	practically	ADV
eurjchem-870	432	6	superior	superior	ADJ
eurjchem-870	432	7	to	to	ADP
eurjchem-870	432	8	conventional	conventional	ADJ
eurjchem-870	432	9	heating	heating	NOUN
eurjchem-870	432	10	method	method	NOUN
eurjchem-870	432	11	in	in	ADP
eurjchem-870	432	12	terms	term	NOUN
eurjchem-870	432	13	of	of	ADP
eurjchem-870	432	14	higher	high	ADJ
eurjchem-870	432	15	yields	yield	NOUN
eurjchem-870	432	16	,	,	PUNCT
eurjchem-870	432	17	rapid	rapid	ADJ
eurjchem-870	432	18	,	,	PUNCT
eurjchem-870	432	19	and	and	CCONJ
eurjchem-870	432	20	environmentally	environmentally	ADV
eurjchem-870	432	21	benign	benign	ADJ
eurjchem-870	432	22	process	process	NOUN
eurjchem-870	432	23	.	.	PUNCT
eurjchem-870	433	1	acknowledgements	acknowledgement	NOUN
eurjchem-870	433	2	technical	technical	ADJ
eurjchem-870	433	3	support	support	NOUN
eurjchem-870	433	4	from	from	ADP
eurjchem-870	433	5	department	department	NOUN
eurjchem-870	433	6	of	of	ADP
eurjchem-870	433	7	chemistry	chemistry	NOUN
eurjchem-870	433	8	,	,	PUNCT
eurjchem-870	433	9	faculty	faculty	NOUN
eurjchem-870	433	10	of	of	ADP
eurjchem-870	433	11	science	science	NOUN
eurjchem-870	433	12	,	,	PUNCT
eurjchem-870	433	13	ain	ain	PROPN
eurjchem-870	433	14	shams	sham	NOUN
eurjchem-870	433	15	university	university	PROPN
eurjchem-870	433	16	is	be	AUX
eurjchem-870	433	17	gratefully	gratefully	ADV
eurjchem-870	433	18	acknowledged	acknowledge	VERB
eurjchem-870	433	19	.	.	PUNCT
eurjchem-870	434	1	references	reference	NOUN
eurjchem-870	434	2	[	[	X
eurjchem-870	434	3	1	1	NUM
eurjchem-870	434	4	]	]	PUNCT
eurjchem-870	434	5	.	.	PUNCT
eurjchem-870	435	1	kumar	kumar	PROPN
eurjchem-870	435	2	,	,	PUNCT
eurjchem-870	435	3	l.	l.	PROPN
eurjchem-870	435	4	;	;	PUNCT
eurjchem-870	435	5	thakur	thakur	PROPN
eurjchem-870	435	6	,	,	PUNCT
eurjchem-870	435	7	c.	c.	PROPN
eurjchem-870	435	8	;	;	PUNCT
eurjchem-870	435	9	sharma	sharma	PROPN
eurjchem-870	435	10	,	,	PUNCT
eurjchem-870	435	11	v.	v.	PROPN
eurjchem-870	435	12	int	int	NOUN
eurjchem-870	435	13	.	.	PUNCT
eurjchem-870	436	1	j.	j.	PROPN
eurjchem-870	436	2	res	res	PROPN
eurjchem-870	436	3	.	.	PUNCT
eurjchem-870	437	1	pharm	pharm	PROPN
eurjchem-870	437	2	.	.	PUNCT
eurjchem-870	438	1	sci	sci	PROPN
eurjchem-870	438	2	.	.	PROPN
eurjchem-870	438	3	2012	2012	NUM
eurjchem-870	438	4	,	,	PUNCT
eurjchem-870	438	5	2	2	NUM
eurjchem-870	438	6	,	,	PUNCT
eurjchem-870	438	7	13‐22	13‐22	NUM
eurjchem-870	439	1	[	[	X
eurjchem-870	439	2	2	2	NUM
eurjchem-870	439	3	]	]	PUNCT
eurjchem-870	439	4	.	.	PUNCT
eurjchem-870	440	1	halen	halen	NOUN
eurjchem-870	440	2	,	,	PUNCT
eurjchem-870	440	3	p.	p.	PROPN
eurjchem-870	440	4	k.	k.	PROPN
eurjchem-870	440	5	;	;	PUNCT
eurjchem-870	440	6	murumkar	murumkar	PROPN
eurjchem-870	440	7	,	,	PUNCT
eurjchem-870	440	8	p.	p.	PROPN
eurjchem-870	440	9	;	;	PUNCT
eurjchem-870	441	1	giridhar	giridhar	PROPN
eurjchem-870	441	2	,	,	PUNCT
eurjchem-870	441	3	r.	r.	PROPN
eurjchem-870	441	4	;	;	PUNCT
eurjchem-870	441	5	yadav	yadav	PROPN
eurjchem-870	441	6	,	,	PUNCT
eurjchem-870	441	7	m.	m.	PROPN
eurjchem-870	441	8	r.	r.	PROPN
eurjchem-870	441	9	mini‐rev	mini‐rev	PROPN
eurjchem-870	441	10	.	.	PUNCT
eurjchem-870	442	1	med	med	PROPN
eurjchem-870	442	2	.	.	PROPN
eurjchem-870	442	3	chem	chem	PROPN
eurjchem-870	442	4	.	.	PUNCT
eurjchem-870	443	1	2009	2009	NUM
eurjchem-870	443	2	,	,	PUNCT
eurjchem-870	443	3	9	9	NUM
eurjchem-870	443	4	,	,	PUNCT
eurjchem-870	443	5	124‐139	124‐139	NUM
eurjchem-870	443	6	.	.	PUNCT
eurjchem-870	444	1	[	[	X
eurjchem-870	444	2	3	3	NUM
eurjchem-870	444	3	]	]	PUNCT
eurjchem-870	444	4	.	.	PUNCT
eurjchem-870	445	1	kucukguzel	kucukguzel	ADJ
eurjchem-870	445	2	,	,	PUNCT
eurjchem-870	445	3	g.	g.	PROPN
eurjchem-870	445	4	;	;	PUNCT
eurjchem-870	445	5	rollas	rollas	PROPN
eurjchem-870	445	6	,	,	PUNCT
eurjchem-870	445	7	s.	s.	PROPN
eurjchem-870	445	8	;	;	PUNCT
eurjchem-870	445	9	erdeniz	erdeniz	PROPN
eurjchem-870	445	10	,	,	PUNCT
eurjchem-870	445	11	h.	h.	PROPN
eurjchem-870	445	12	;	;	PUNCT
eurjchem-870	445	13	kiraz	kiraz	PROPN
eurjchem-870	445	14	,	,	PUNCT
eurjchem-870	445	15	m.	m.	NOUN
eurjchem-870	445	16	;	;	PUNCT
eurjchem-870	445	17	ekinci	ekinci	PROPN
eurjchem-870	445	18	,	,	PUNCT
eurjchem-870	445	19	a.	a.	NOUN
eurjchem-870	445	20	;	;	PUNCT
eurjchem-870	445	21	cevdet	cevdet	NOUN
eurjchem-870	445	22	,	,	PUNCT
eurjchem-870	445	23	v.	v.	ADP
eurjchem-870	445	24	a.	a.	PROPN
eurjchem-870	445	25	eur	eur	PROPN
eurjchem-870	445	26	.	.	PUNCT
eurjchem-870	446	1	j.	j.	PROPN
eurjchem-870	446	2	med	med	PROPN
eurjchem-870	446	3	.	.	PROPN
eurjchem-870	446	4	chem	chem	PROPN
eurjchem-870	446	5	.	.	PUNCT
eurjchem-870	447	1	2000	2000	NUM
eurjchem-870	447	2	,	,	PUNCT
eurjchem-870	447	3	35	35	NUM
eurjchem-870	447	4	,	,	PUNCT
eurjchem-870	447	5	761‐771	761‐771	NUM
eurjchem-870	447	6	.	.	PUNCT
eurjchem-870	448	1	[	[	X
eurjchem-870	448	2	4	4	NUM
eurjchem-870	448	3	]	]	PUNCT
eurjchem-870	448	4	.	.	PUNCT
eurjchem-870	448	5	mariappan	mariappan	PROPN
eurjchem-870	448	6	,	,	PUNCT
eurjchem-870	448	7	g.	g.	PROPN
eurjchem-870	448	8	;	;	PUNCT
eurjchem-870	448	9	saha	saha	PROPN
eurjchem-870	448	10	,	,	PUNCT
eurjchem-870	448	11	b.	b.	PROPN
eurjchem-870	448	12	p.	p.	PROPN
eurjchem-870	448	13	;	;	PUNCT
eurjchem-870	448	14	sutharson	sutharson	PROPN
eurjchem-870	448	15	,	,	PUNCT
eurjchem-870	448	16	l.	l.	PROPN
eurjchem-870	448	17	;	;	PUNCT
eurjchem-870	448	18	ankit	ankit	PROPN
eurjchem-870	448	19	,	,	PUNCT
eurjchem-870	448	20	garg	garg	PROPN
eurjchem-870	448	21	,	,	PUNCT
eurjchem-870	448	22	s.	s.	PROPN
eurjchem-870	448	23	pandey	pandey	PROPN
eurjchem-870	448	24	,	,	PUNCT
eurjchem-870	448	25	l.	l.	PROPN
eurjchem-870	448	26	kumar	kumar	PROPN
eurjchem-870	448	27	,	,	PUNCT
eurjchem-870	448	28	d.	d.	PROPN
eurjchem-870	448	29	j.	j.	PROPN
eurjchem-870	448	30	pharm	pharm	PROPN
eurjchem-870	448	31	.	.	PUNCT
eurjchem-870	449	1	res	re	NOUN
eurjchem-870	449	2	.	.	PUNCT
eurjchem-870	450	1	2010	2010	NUM
eurjchem-870	450	2	,	,	PUNCT
eurjchem-870	450	3	3	3	NUM
eurjchem-870	450	4	,	,	PUNCT
eurjchem-870	450	5	2856‐2859	2856‐2859	NUM
eurjchem-870	450	6	.	.	PUNCT
eurjchem-870	451	1	[	[	X
eurjchem-870	451	2	5	5	NUM
eurjchem-870	451	3	]	]	PUNCT
eurjchem-870	451	4	.	.	PUNCT
eurjchem-870	452	1	devnath	devnath	NOUN
eurjchem-870	452	2	,	,	PUNCT
eurjchem-870	452	3	h.	h.	PROPN
eurjchem-870	452	4	p.	p.	PROPN
eurjchem-870	452	5	;	;	PUNCT
eurjchem-870	453	1	islam	islam	PROPN
eurjchem-870	453	2	,	,	PUNCT
eurjchem-870	453	3	m.	m.	PROPN
eurjchem-870	453	4	r.	r.	PROPN
eurjchem-870	453	5	bangladesh	bangladesh	PROPN
eurjchem-870	453	6	j.	j.	PROPN
eurjchem-870	453	7	pharmacol	pharmacol	PROPN
eurjchem-870	453	8	.	.	PUNCT
eurjchem-870	454	1	2010	2010	NUM
eurjchem-870	454	2	,	,	PUNCT
eurjchem-870	454	3	5	5	NUM
eurjchem-870	454	4	,	,	PUNCT
eurjchem-870	454	5	30‐33	30‐33	NUM
eurjchem-870	454	6	.	.	PUNCT
eurjchem-870	455	1	[	[	X
eurjchem-870	455	2	6	6	NUM
eurjchem-870	455	3	]	]	PUNCT
eurjchem-870	455	4	.	.	PUNCT
eurjchem-870	456	1	rahat	rahat	PROPN
eurjchem-870	456	2	,	,	PUNCT
eurjchem-870	456	3	k.	k.	PROPN
eurjchem-870	456	4	;	;	PUNCT
eurjchem-870	456	5	imam	imam	PROPN
eurjchem-870	456	6	,	,	PUNCT
eurjchem-870	456	7	u.	u.	PROPN
eurjchem-870	456	8	;	;	PUNCT
eurjchem-870	456	9	alam	alam	PROPN
eurjchem-870	456	10	,	,	PUNCT
eurjchem-870	456	11	m.	m.	NOUN
eurjchem-870	456	12	;	;	PUNCT
eurjchem-870	456	13	sultan	sultan	PROPN
eurjchem-870	456	14	,	,	PUNCT
eurjchem-870	456	15	d.	d.	PROPN
eurjchem-870	456	16	bangladesh	bangladesh	PROPN
eurjchem-870	456	17	j.	j.	PROPN
eurjchem-870	456	18	pharmacol	pharmacol	PROPN
eurjchem-870	456	19	.	.	PUNCT
eurjchem-870	456	20	2008	2008	NUM
eurjchem-870	456	21	,	,	PUNCT
eurjchem-870	456	22	3	3	NUM
eurjchem-870	456	23	,	,	PUNCT
eurjchem-870	456	24	27‐35	27‐35	NUM
eurjchem-870	456	25	.	.	PUNCT
eurjchem-870	457	1	[	[	X
eurjchem-870	457	2	7	7	NUM
eurjchem-870	457	3	]	]	PUNCT
eurjchem-870	457	4	.	.	PUNCT
eurjchem-870	457	5	soni	soni	PROPN
eurjchem-870	457	6	,	,	PUNCT
eurjchem-870	457	7	j.	j.	PROPN
eurjchem-870	457	8	p.	p.	PROPN
eurjchem-870	457	9	;	;	PUNCT
eurjchem-870	457	10	sen	sen	PROPN
eurjchem-870	457	11	,	,	PUNCT
eurjchem-870	457	12	d.	d.	PROPN
eurjchem-870	457	13	j.	j.	PROPN
eurjchem-870	457	14	;	;	PUNCT
eurjchem-870	457	15	modh	modh	PROPN
eurjchem-870	457	16	,	,	PUNCT
eurjchem-870	457	17	k.	k.	PROPN
eurjchem-870	457	18	m.	m.	PROPN
eurjchem-870	457	19	j.	j.	PROPN
eurjchem-870	457	20	appl	appl	PROPN
eurjchem-870	457	21	.	.	PUNCT
eurjchem-870	458	1	pharm	pharm	PROPN
eurjchem-870	458	2	.	.	PUNCT
eurjchem-870	459	1	sci	sci	PROPN
eurjchem-870	459	2	.	.	PROPN
eurjchem-870	459	3	2011	2011	NUM
eurjchem-870	459	4	,	,	PUNCT
eurjchem-870	459	5	1	1	NUM
eurjchem-870	459	6	,	,	PUNCT
eurjchem-870	459	7	115‐120	115‐120	NUM
eurjchem-870	459	8	.	.	PUNCT
eurjchem-870	460	1	[	[	X
eurjchem-870	460	2	8	8	NUM
eurjchem-870	460	3	]	]	PUNCT
eurjchem-870	460	4	.	.	PUNCT
eurjchem-870	461	1	sunitha	sunitha	PROPN
eurjchem-870	461	2	,	,	PUNCT
eurjchem-870	461	3	s.	s.	PROPN
eurjchem-870	461	4	;	;	PUNCT
eurjchem-870	461	5	aravindakshan	aravindakshan	PROPN
eurjchem-870	461	6	,	,	PUNCT
eurjchem-870	461	7	k.	k.	PROPN
eurjchem-870	461	8	k.	k.	PROPN
eurjchem-870	461	9	int	int	PROPN
eurjchem-870	461	10	.	.	PUNCT
eurjchem-870	462	1	j.	j.	PROPN
eurjchem-870	462	2	pharm	pharm	PROPN
eurjchem-870	462	3	.	.	PUNCT
eurjchem-870	463	1	bio	bio	PROPN
eurjchem-870	463	2	.	.	PUNCT
eurjchem-870	464	1	sci	sci	PROPN
eurjchem-870	464	2	.	.	PROPN
eurjchem-870	464	3	2011	2011	NUM
eurjchem-870	464	4	,	,	PUNCT
eurjchem-870	464	5	2	2	NUM
eurjchem-870	464	6	,	,	PUNCT
eurjchem-870	464	7	108‐	108‐	NUM
eurjchem-870	464	8	113	113	NUM
eurjchem-870	464	9	.	.	PUNCT
eurjchem-870	465	1	[	[	X
eurjchem-870	465	2	9	9	NUM
eurjchem-870	465	3	]	]	PUNCT
eurjchem-870	465	4	.	.	PUNCT
eurjchem-870	466	1	vijesh	vijesh	PROPN
eurjchem-870	466	2	,	,	PUNCT
eurjchem-870	466	3	a.	a.	NOUN
eurjchem-870	466	4	m.	m.	NOUN
eurjchem-870	466	5	;	;	PUNCT
eurjchem-870	466	6	arun	arun	PROPN
eurjchem-870	466	7	,	,	PUNCT
eurjchem-870	466	8	m.	m.	NOUN
eurjchem-870	466	9	i.	i.	NOUN
eurjchem-870	466	10	;	;	PUNCT
eurjchem-870	466	11	shrikrishna	shrikrishna	NOUN
eurjchem-870	466	12	,	,	PUNCT
eurjchem-870	466	13	i.	i.	NOUN
eurjchem-870	466	14	;	;	PUNCT
eurjchem-870	466	15	shivananda	shivananda	PROPN
eurjchem-870	466	16	,	,	PUNCT
eurjchem-870	466	17	k.	k.	PROPN
eurjchem-870	466	18	n.	n.	PROPN
eurjchem-870	466	19	;	;	PUNCT
eurjchem-870	466	20	shyma	shyma	NOUN
eurjchem-870	466	21	,	,	PUNCT
eurjchem-870	466	22	p.	p.	PROPN
eurjchem-870	466	23	c.	c.	PROPN
eurjchem-870	466	24	;	;	PUNCT
eurjchem-870	466	25	arulmoli	arulmoli	NOUN
eurjchem-870	466	26	,	,	PUNCT
eurjchem-870	466	27	t.	t.	PROPN
eurjchem-870	466	28	der	der	PROPN
eurjchem-870	466	29	pharma	pharma	PROPN
eurjchem-870	466	30	chem	chem	NOUN
eurjchem-870	466	31	.	.	PUNCT
eurjchem-870	467	1	2011	2011	NUM
eurjchem-870	467	2	,	,	PUNCT
eurjchem-870	467	3	3	3	NUM
eurjchem-870	467	4	,	,	PUNCT
eurjchem-870	467	5	454‐463	454‐463	PROPN
eurjchem-870	467	6	.	.	PUNCT
eurjchem-870	468	1	[	[	X
eurjchem-870	468	2	10	10	NUM
eurjchem-870	468	3	]	]	PUNCT
eurjchem-870	468	4	.	.	PUNCT
eurjchem-870	469	1	kumar	kumar	PROPN
eurjchem-870	469	2	,	,	PUNCT
eurjchem-870	469	3	k.	k.	PROPN
eurjchem-870	469	4	s.	s.	PROPN
eurjchem-870	469	5	;	;	PUNCT
eurjchem-870	469	6	rajasekharan	rajasekharan	VERB
eurjchem-870	469	7	,	,	PUNCT
eurjchem-870	469	8	a.	a.	NOUN
eurjchem-870	469	9	int	int	NOUN
eurjchem-870	469	10	.	.	PUNCT
eurjchem-870	470	1	j.	j.	PROPN
eurjchem-870	470	2	res	res	PROPN
eurjchem-870	470	3	.	.	PUNCT
eurjchem-870	471	1	pharm	pharm	PROPN
eurjchem-870	471	2	.	.	PUNCT
eurjchem-870	472	1	chem	chem	PROPN
eurjchem-870	472	2	.	.	PUNCT
eurjchem-870	473	1	2012	2012	NUM
eurjchem-870	473	2	,	,	PUNCT
eurjchem-870	473	3	2	2	NUM
eurjchem-870	473	4	,	,	PUNCT
eurjchem-870	473	5	327‐	327‐	NUM
eurjchem-870	473	6	337	337	NUM
eurjchem-870	473	7	.	.	PUNCT
eurjchem-870	474	1	[	[	X
eurjchem-870	474	2	11	11	NUM
eurjchem-870	474	3	]	]	PUNCT
eurjchem-870	474	4	.	.	PUNCT
eurjchem-870	475	1	evstropov	evstropov	NOUN
eurjchem-870	475	2	,	,	PUNCT
eurjchem-870	475	3	a.	a.	NOUN
eurjchem-870	475	4	n.	n.	NOUN
eurjchem-870	475	5	;	;	PUNCT
eurjchem-870	475	6	yavorovskaya	yavorovskaya	PROPN
eurjchem-870	475	7	,	,	PUNCT
eurjchem-870	475	8	v.	v.	PROPN
eurjchem-870	475	9	e.	e.	PROPN
eurjchem-870	475	10	;	;	PUNCT
eurjchem-870	475	11	vorobev	vorobev	ADJ
eurjchem-870	475	12	,	,	PUNCT
eurjchem-870	475	13	e.	e.	PROPN
eurjchem-870	475	14	s.	s.	PROPN
eurjchem-870	475	15	;	;	PUNCT
eurjchem-870	475	16	khudonogova	khudonogova	PROPN
eurjchem-870	475	17	,	,	PUNCT
eurjchem-870	475	18	z.	z.	PROPN
eurjchem-870	475	19	p.	p.	PROPN
eurjchem-870	475	20	;	;	PUNCT
eurjchem-870	475	21	medvedeva	medvedeva	PROPN
eurjchem-870	475	22	,	,	PUNCT
eurjchem-870	475	23	s.	s.	PROPN
eurjchem-870	475	24	g.	g.	PROPN
eurjchem-870	475	25	;	;	PUNCT
eurjchem-870	475	26	filimonov	filimonov	PROPN
eurjchem-870	475	27	,	,	PUNCT
eurjchem-870	475	28	v.	v.	PROPN
eurjchem-870	475	29	d.	d.	PROPN
eurjchem-870	475	30	;	;	PUNCT
eurjchem-870	475	31	prishchep	prishchep	NOUN
eurjchem-870	475	32	,	,	PUNCT
eurjchem-870	475	33	t.	t.	PROPN
eurjchem-870	475	34	p.	p.	PROPN
eurjchem-870	475	35	;	;	PUNCT
eurjchem-870	475	36	saratikov	saratikov	PROPN
eurjchem-870	475	37	,	,	PUNCT
eurjchem-870	475	38	a.	a.	PROPN
eurjchem-870	475	39	s.	s.	PROPN
eurjchem-870	475	40	pharm	pharm	PROPN
eurjchem-870	475	41	.	.	PUNCT
eurjchem-870	476	1	chem	chem	PROPN
eurjchem-870	476	2	.	.	PUNCT
eurjchem-870	477	1	j.	j.	PROPN
eurjchem-870	477	2	1992	1992	NUM
eurjchem-870	477	3	,	,	PUNCT
eurjchem-870	477	4	26	26	NUM
eurjchem-870	477	5	,	,	PUNCT
eurjchem-870	477	6	426‐430	426‐430	PROPN
eurjchem-870	477	7	.	.	PUNCT
eurjchem-870	478	1	[	[	X
eurjchem-870	478	2	12	12	NUM
eurjchem-870	478	3	]	]	PUNCT
eurjchem-870	478	4	.	.	PUNCT
eurjchem-870	479	1	nirupam	nirupam	PROPN
eurjchem-870	479	2	,	,	PUNCT
eurjchem-870	479	3	d.	d.	PROPN
eurjchem-870	479	4	;	;	PUNCT
eurjchem-870	479	5	abilasha	abilasha	PROPN
eurjchem-870	479	6	,	,	PUNCT
eurjchem-870	479	7	v.	v.	PROPN
eurjchem-870	479	8	;	;	PUNCT
eurjchem-870	479	9	shrivastava	shrivastava	PROPN
eurjchem-870	479	10	,	,	PUNCT
eurjchem-870	479	11	k.	k.	PROPN
eurjchem-870	479	12	;	;	PUNCT
eurjchem-870	479	13	shrivastva	shrivastva	PROPN
eurjchem-870	479	14	,	,	PUNCT
eurjchem-870	479	15	p.	p.	NOUN
eurjchem-870	479	16	;	;	PUNCT
eurjchem-870	479	17	sushant	sushant	PROPN
eurjchem-870	479	18	,	,	PUNCT
eurjchem-870	479	19	k.	k.	PROPN
eurjchem-870	479	20	indian	indian	PROPN
eurjchem-870	479	21	j.	j.	PROPN
eurjchem-870	479	22	chem	chem	PROPN
eurjchem-870	479	23	.	.	PUNCT
eurjchem-870	480	1	b	b	PROPN
eurjchem-870	480	2	2008	2008	NUM
eurjchem-870	480	3	,	,	PUNCT
eurjchem-870	480	4	47	47	NUM
eurjchem-870	480	5	,	,	PUNCT
eurjchem-870	480	6	1555‐1558	1555‐1558	NUM
eurjchem-870	480	7	.	.	PUNCT
eurjchem-870	481	1	[	[	X
eurjchem-870	481	2	13	13	NUM
eurjchem-870	481	3	]	]	PUNCT
eurjchem-870	481	4	.	.	PUNCT
eurjchem-870	482	1	amir	amir	PROPN
eurjchem-870	482	2	,	,	PUNCT
eurjchem-870	482	3	m.	m.	NOUN
eurjchem-870	482	4	;	;	PUNCT
eurjchem-870	482	5	shikha	shikha	PROPN
eurjchem-870	482	6	,	,	PUNCT
eurjchem-870	482	7	k.	k.	PROPN
eurjchem-870	482	8	indian	indian	PROPN
eurjchem-870	482	9	j.	j.	PROPN
eurjchem-870	482	10	chem	chem	PROPN
eurjchem-870	482	11	.	.	PUNCT
eurjchem-870	483	1	b	b	NOUN
eurjchem-870	483	2	2005	2005	NUM
eurjchem-870	483	3	,	,	PUNCT
eurjchem-870	483	4	44	44	NUM
eurjchem-870	483	5	,	,	PUNCT
eurjchem-870	483	6	2532‐2537	2532‐2537	NUM
eurjchem-870	483	7	.	.	PUNCT
eurjchem-870	484	1	[	[	X
eurjchem-870	484	2	14	14	NUM
eurjchem-870	484	3	]	]	PUNCT
eurjchem-870	484	4	.	.	PUNCT
eurjchem-870	485	1	ragab	ragab	PROPN
eurjchem-870	485	2	,	,	PUNCT
eurjchem-870	485	3	f.	f.	PROPN
eurjchem-870	485	4	a.	a.	PROPN
eurjchem-870	485	5	;	;	PUNCT
eurjchem-870	486	1	abdel‐gawad	abdel‐gawad	PROPN
eurjchem-870	486	2	,	,	PUNCT
eurjchem-870	486	3	n.	n.	NOUN
eurjchem-870	486	4	m.	m.	NOUN
eurjchem-870	486	5	;	;	PUNCT
eurjchem-870	486	6	georgey	georgey	PROPN
eurjchem-870	486	7	,	,	PUNCT
eurjchem-870	486	8	h.	h.	PROPN
eurjchem-870	486	9	h.	h.	PROPN
eurjchem-870	486	10	;	;	PUNCT
eurjchem-870	486	11	said	say	VERB
eurjchem-870	486	12	,	,	PUNCT
eurjchem-870	486	13	m.	m.	PROPN
eurjchem-870	486	14	f.	f.	PROPN
eurjchem-870	486	15	chem	chem	PROPN
eurjchem-870	486	16	.	.	PUNCT
eurjchem-870	487	1	pharm	pharm	NOUN
eurjchem-870	487	2	.	.	PUNCT
eurjchem-870	488	1	bull	bull	PROPN
eurjchem-870	488	2	.	.	PUNCT
eurjchem-870	489	1	2013	2013	NUM
eurjchem-870	489	2	,	,	PUNCT
eurjchem-870	489	3	61(8	61(8	NUM
eurjchem-870	489	4	)	)	PUNCT
eurjchem-870	489	5	,	,	PUNCT
eurjchem-870	489	6	834‐845	834‐845	PROPN
eurjchem-870	489	7	.	.	PUNCT
eurjchem-870	490	1	[	[	X
eurjchem-870	490	2	15	15	NUM
eurjchem-870	490	3	]	]	PUNCT
eurjchem-870	490	4	.	.	PUNCT
eurjchem-870	490	5	al‐mutairi	al‐mutairi	PROPN
eurjchem-870	490	6	,	,	PUNCT
eurjchem-870	490	7	a.	a.	NOUN
eurjchem-870	490	8	a.	a.	NOUN
eurjchem-870	490	9	;	;	PUNCT
eurjchem-870	490	10	el‐baih	el‐baih	PROPN
eurjchem-870	490	11	,	,	PUNCT
eurjchem-870	490	12	f.	f.	PROPN
eurjchem-870	490	13	e.	e.	PROPN
eurjchem-870	490	14	m.	m.	PROPN
eurjchem-870	490	15	;	;	PUNCT
eurjchem-870	490	16	al‐hazimi	al‐hazimi	PROPN
eurjchem-870	490	17	,	,	PUNCT
eurjchem-870	490	18	h.	h.	PROPN
eurjchem-870	490	19	m.	m.	PROPN
eurjchem-870	490	20	j.	j.	PROPN
eurjchem-870	490	21	saudi	saudi	PROPN
eurjchem-870	490	22	chem	chem	PROPN
eurjchem-870	490	23	.	.	PUNCT
eurjchem-870	491	1	soc	soc	PROPN
eurjchem-870	491	2	.	.	PUNCT
eurjchem-870	492	1	2010	2010	NUM
eurjchem-870	492	2	,	,	PUNCT
eurjchem-870	492	3	14	14	NUM
eurjchem-870	492	4	,	,	PUNCT
eurjchem-870	492	5	287‐299	287‐299	NUM
eurjchem-870	492	6	.	.	PUNCT
eurjchem-870	493	1	[	[	X
eurjchem-870	493	2	16	16	NUM
eurjchem-870	493	3	]	]	PUNCT
eurjchem-870	493	4	.	.	PUNCT
eurjchem-870	494	1	cooper	cooper	PROPN
eurjchem-870	494	2	,	,	PUNCT
eurjchem-870	494	3	r.	r.	PROPN
eurjchem-870	494	4	e.	e.	PROPN
eurjchem-870	494	5	;	;	PUNCT
eurjchem-870	494	6	kavanageh	kavanageh	PROPN
eurjchem-870	494	7	,	,	PUNCT
eurjchem-870	494	8	f.	f.	PROPN
eurjchem-870	494	9	w.	w.	PROPN
eurjchem-870	494	10	analytical	analytical	PROPN
eurjchem-870	494	11	microbiology	microbiology	NOUN
eurjchem-870	494	12	,	,	PUNCT
eurjchem-870	494	13	vol	vol	NOUN
eurjchem-870	494	14	.	.	PUNCT
eurjchem-870	495	1	i	i	PRON
eurjchem-870	495	2	and	and	CCONJ
eurjchem-870	495	3	ii	ii	PROPN
eurjchem-870	495	4	,	,	PUNCT
eurjchem-870	495	5	academic	academic	ADJ
eurjchem-870	495	6	press	press	NOUN
eurjchem-870	495	7	:	:	PUNCT
eurjchem-870	495	8	new	new	PROPN
eurjchem-870	495	9	york	york	PROPN
eurjchem-870	495	10	and	and	CCONJ
eurjchem-870	495	11	london	london	PROPN
eurjchem-870	495	12	,	,	PUNCT
eurjchem-870	495	13	1972	1972	NUM
eurjchem-870	495	14	.	.	PUNCT
eurjchem-870	496	1	[	[	X
eurjchem-870	496	2	17	17	NUM
eurjchem-870	496	3	]	]	PUNCT
eurjchem-870	496	4	.	.	PUNCT
eurjchem-870	497	1	vogel	vogel	PROPN
eurjchem-870	497	2	,	,	PUNCT
eurjchem-870	497	3	a.	a.	PROPN
eurjchem-870	497	4	i.	i.	PROPN
eurjchem-870	497	5	elementary	elementary	PROPN
eurjchem-870	497	6	practical	practical	ADJ
eurjchem-870	497	7	organic	organic	ADJ
eurjchem-870	497	8	chemistry	chemistry	NOUN
eurjchem-870	497	9	part	part	NOUN
eurjchem-870	497	10	ii	ii	PROPN
eurjchem-870	497	11	,	,	PUNCT
eurjchem-870	497	12	qualitative	qualitative	VERB
eurjchem-870	497	13	organic	organic	ADJ
eurjchem-870	497	14	analysis	analysis	NOUN
eurjchem-870	497	15	,	,	PUNCT
eurjchem-870	497	16	2nd	2nd	ADJ
eurjchem-870	497	17	edition	edition	NOUN
eurjchem-870	497	18	,	,	PUNCT
eurjchem-870	497	19	longman	longman	PROPN
eurjchem-870	497	20	,	,	PUNCT
eurjchem-870	497	21	london	london	PROPN
eurjchem-870	497	22	1966	1966	NUM
eurjchem-870	497	23	.	.	PUNCT
eurjchem-870	498	1	[	[	X
eurjchem-870	498	2	18	18	NUM
eurjchem-870	498	3	]	]	PUNCT
eurjchem-870	498	4	.	.	PUNCT
eurjchem-870	499	1	abdel‐fattah	abdel‐fattah	PROPN
eurjchem-870	499	2	,	,	PUNCT
eurjchem-870	499	3	a.	a.	NOUN
eurjchem-870	499	4	m.	m.	NOUN
eurjchem-870	499	5	;	;	PUNCT
eurjchem-870	499	6	sherif	sherif	PROPN
eurjchem-870	499	7	,	,	PUNCT
eurjchem-870	499	8	s.	s.	PROPN
eurjchem-870	499	9	m.	m.	PROPN
eurjchem-870	499	10	;	;	PUNCT
eurjchem-870	499	11	el‐reedy	el‐reedy	NOUN
eurjchem-870	499	12	,	,	PUNCT
eurjchem-870	499	13	a.	a.	NOUN
eurjchem-870	499	14	m.	m.	NOUN
eurjchem-870	499	15	;	;	PUNCT
eurjchem-870	499	16	gad‐alla	gad‐alla	NUM
eurjchem-870	499	17	,	,	PUNCT
eurjchem-870	499	18	s.	s.	PROPN
eurjchem-870	499	19	a.	a.	NOUN
eurjchem-870	499	20	phosphorus	phosphorus	PROPN
eurjchem-870	499	21	sulfur	sulfur	NOUN
eurjchem-870	499	22	1992	1992	NUM
eurjchem-870	499	23	,	,	PUNCT
eurjchem-870	499	24	70	70	NUM
eurjchem-870	499	25	,	,	PUNCT
eurjchem-870	499	26	67‐73	67‐73	NOUN
eurjchem-870	499	27	.	.	PUNCT
eurjchem-870	500	1	[	[	X
eurjchem-870	500	2	19	19	NUM
eurjchem-870	500	3	]	]	PUNCT
eurjchem-870	500	4	.	.	PUNCT
eurjchem-870	501	1	khalil	khalil	PROPN
eurjchem-870	501	2	,	,	PUNCT
eurjchem-870	501	3	m.	m.	NOUN
eurjchem-870	501	4	a.	a.	PROPN
eurjchem-870	501	5	;	;	PUNCT
eurjchem-870	501	6	sayed	say	VERB
eurjchem-870	501	7	,	,	PUNCT
eurjchem-870	501	8	s.	s.	PROPN
eurjchem-870	501	9	m.	m.	PROPN
eurjchem-870	501	10	;	;	PUNCT
eurjchem-870	501	11	raslan	raslan	NOUN
eurjchem-870	501	12	,	,	PUNCT
eurjchem-870	501	13	m.	m.	NOUN
eurjchem-870	501	14	a.	a.	PROPN
eurjchem-870	501	15	am	am	PROPN
eurjchem-870	501	16	.	.	PUNCT
eurjchem-870	502	1	j.	j.	PROPN
eurjchem-870	502	2	org	org	PROPN
eurjchem-870	502	3	.	.	PUNCT
eurjchem-870	502	4	chem	chem	PROPN
eurjchem-870	502	5	.	.	PUNCT
eurjchem-870	503	1	2012	2012	NUM
eurjchem-870	503	2	,	,	PUNCT
eurjchem-870	503	3	2	2	NUM
eurjchem-870	503	4	,	,	PUNCT
eurjchem-870	503	5	161‐	161‐	NUM
eurjchem-870	503	6	170	170	NUM
eurjchem-870	503	7	.	.	PUNCT