id	sid	tid	token	lemma	pos
eurjchem-940	1	1	untitled	untitle	VERB
eurjchem-940	1	2	european	european	PROPN
eurjchem-940	1	3	journal	journal	PROPN
eurjchem-940	1	4	of	of	ADP
eurjchem-940	1	5	chemistry	chemistry	NOUN
eurjchem-940	1	6	5	5	NUM
eurjchem-940	1	7	(	(	PUNCT
eurjchem-940	1	8	1	1	NUM
eurjchem-940	1	9	)	)	PUNCT
eurjchem-940	1	10	(	(	PUNCT
eurjchem-940	1	11	2014	2014	NUM
eurjchem-940	1	12	)	)	PUNCT
eurjchem-940	1	13	162‐166	162‐166	PROPN
eurjchem-940	1	14	european	european	PROPN
eurjchem-940	1	15	journal	journal	PROPN
eurjchem-940	1	16	of	of	ADP
eurjchem-940	1	17	chemistry	chemistry	NOUN
eurjchem-940	1	18	issn	issn	PROPN
eurjchem-940	1	19	2153‐2249	2153‐2249	PROPN
eurjchem-940	1	20	(	(	PUNCT
eurjchem-940	1	21	print	print	NOUN
eurjchem-940	1	22	)	)	PUNCT
eurjchem-940	1	23	/	/	SYM
eurjchem-940	1	24	issn	issn	PROPN
eurjchem-940	1	25	2153‐2257	2153‐2257	NUM
eurjchem-940	1	26	(	(	PUNCT
eurjchem-940	1	27	online	online	ADJ
eurjchem-940	1	28	)	)	PUNCT
eurjchem-940	1	29			NOUN
eurjchem-940	1	30	2014	2014	NUM
eurjchem-940	2	1	eurjchem	eurjchem	PROPN
eurjchem-940	2	2	publishing	publish	VERB
eurjchem-940	2	3	‐	‐	NOUN
eurjchem-940	2	4	printed	print	VERB
eurjchem-940	2	5	in	in	ADP
eurjchem-940	2	6	the	the	DET
eurjchem-940	2	7	usa	usa	PROPN
eurjchem-940	2	8	http://dx.doi.org/10.5155/eurjchem.5.1.162‐166.940	http://dx.doi.org/10.5155/eurjchem.5.1.162‐166.940	ADJ
eurjchem-940	2	9	european	european	PROPN
eurjchem-940	2	10	journal	journal	PROPN
eurjchem-940	2	11	of	of	ADP
eurjchem-940	2	12	chemistry	chemistry	PROPN
eurjchem-940	2	13	journal	journal	PROPN
eurjchem-940	2	14	homepage	homepage	NOUN
eurjchem-940	2	15	:	:	PUNCT
eurjchem-940	2	16	www.eurjchem.com	www.eurjchem.com	X
eurjchem-940	3	1	an	an	DET
eurjchem-940	3	2	n‐heterocyclic	n‐heterocyclic	ADV
eurjchem-940	3	3	carbene‐palladium‐η3‐allyl	carbene‐palladium‐η3‐allyl	ADJ
eurjchem-940	3	4	chloride	chloride	NOUN
eurjchem-940	3	5	complex	complex	NOUN
eurjchem-940	3	6	for	for	ADP
eurjchem-940	3	7	the	the	DET
eurjchem-940	3	8	suzuki‐miyaura	suzuki‐miyaura	PROPN
eurjchem-940	3	9	coupling	coupling	NOUN
eurjchem-940	3	10	of	of	ADP
eurjchem-940	3	11	aryl	aryl	PROPN
eurjchem-940	3	12	halides	halide	NOUN
eurjchem-940	3	13	noland	noland	PROPN
eurjchem-940	3	14	william	william	PROPN
eurjchem-940	3	15	broekemier	broekemier	PROPN
eurjchem-940	3	16	a	a	PROPN
eurjchem-940	3	17	,	,	PUNCT
eurjchem-940	3	18	noah	noah	PROPN
eurjchem-940	3	19	curtis	curtis	PROPN
eurjchem-940	3	20	broekemier	broekemier	PROPN
eurjchem-940	3	21	a	a	PROPN
eurjchem-940	3	22	,	,	PUNCT
eurjchem-940	3	23	randall	randall	PROPN
eurjchem-940	3	24	thomas	thomas	PROPN
eurjchem-940	3	25	short	short	PROPN
eurjchem-940	3	26	b	b	PROPN
eurjchem-940	3	27	and	and	CCONJ
eurjchem-940	3	28	hector	hector	PROPN
eurjchem-940	3	29	palencia	palencia	PROPN
eurjchem-940	3	30	a	a	DET
eurjchem-940	3	31	,	,	PUNCT
eurjchem-940	3	32	c	c	NOUN
eurjchem-940	3	33	,	,	PUNCT
eurjchem-940	3	34	*	*	PUNCT
eurjchem-940	3	35	a	a	DET
eurjchem-940	3	36	department	department	NOUN
eurjchem-940	3	37	of	of	ADP
eurjchem-940	3	38	chemistry	chemistry	NOUN
eurjchem-940	3	39	,	,	PUNCT
eurjchem-940	3	40	university	university	PROPN
eurjchem-940	3	41	of	of	ADP
eurjchem-940	3	42	nebraska	nebraska	PROPN
eurjchem-940	3	43	at	at	ADP
eurjchem-940	3	44	kearney	kearney	PROPN
eurjchem-940	3	45	,	,	PUNCT
eurjchem-940	3	46	kearney	kearney	PROPN
eurjchem-940	3	47	,	,	PUNCT
eurjchem-940	3	48	ne	ne	PROPN
eurjchem-940	3	49	68849	68849	NUM
eurjchem-940	3	50	,	,	PUNCT
eurjchem-940	3	51	usa	usa	PROPN
eurjchem-940	3	52	b	b	PROPN
eurjchem-940	3	53	department	department	PROPN
eurjchem-940	3	54	of	of	ADP
eurjchem-940	3	55	chemistry	chemistry	NOUN
eurjchem-940	3	56	,	,	PUNCT
eurjchem-940	3	57	ball	ball	NOUN
eurjchem-940	3	58	state	state	PROPN
eurjchem-940	3	59	university	university	PROPN
eurjchem-940	3	60	,	,	PUNCT
eurjchem-940	3	61	muncie	muncie	PROPN
eurjchem-940	3	62	,	,	PUNCT
eurjchem-940	3	63	in	in	ADP
eurjchem-940	3	64	47306	47306	NUM
eurjchem-940	3	65	,	,	PUNCT
eurjchem-940	3	66	usa	usa	PROPN
eurjchem-940	3	67	c	c	PROPN
eurjchem-940	3	68	nebraska	nebraska	PROPN
eurjchem-940	3	69	center	center	PROPN
eurjchem-940	3	70	for	for	ADP
eurjchem-940	3	71	materials	material	NOUN
eurjchem-940	3	72	and	and	CCONJ
eurjchem-940	3	73	nanoscience	nanoscience	NOUN
eurjchem-940	3	74	,	,	PUNCT
eurjchem-940	3	75	university	university	PROPN
eurjchem-940	3	76	of	of	ADP
eurjchem-940	3	77	nebraska	nebraska	PROPN
eurjchem-940	3	78	,	,	PUNCT
eurjchem-940	3	79	lincoln	lincoln	PROPN
eurjchem-940	3	80	,	,	PUNCT
eurjchem-940	3	81	ne	ne	PROPN
eurjchem-940	3	82	68588‐0298	68588‐0298	PROPN
eurjchem-940	3	83	,	,	PUNCT
eurjchem-940	3	84	usa	usa	PROPN
eurjchem-940	3	85	*	*	PUNCT
eurjchem-940	3	86	corresponding	correspond	VERB
eurjchem-940	3	87	author	author	NOUN
eurjchem-940	3	88	at	at	ADP
eurjchem-940	3	89	:	:	PUNCT
eurjchem-940	3	90	department	department	NOUN
eurjchem-940	3	91	of	of	ADP
eurjchem-940	3	92	chemistry	chemistry	NOUN
eurjchem-940	3	93	,	,	PUNCT
eurjchem-940	3	94	university	university	PROPN
eurjchem-940	3	95	of	of	ADP
eurjchem-940	3	96	nebraska	nebraska	PROPN
eurjchem-940	3	97	at	at	ADP
eurjchem-940	3	98	kearney	kearney	PROPN
eurjchem-940	3	99	,	,	PUNCT
eurjchem-940	3	100	kearney	kearney	PROPN
eurjchem-940	3	101	,	,	PUNCT
eurjchem-940	3	102	ne	ne	PROPN
eurjchem-940	3	103	68849	68849	NUM
eurjchem-940	3	104	,	,	PUNCT
eurjchem-940	3	105	usa	usa	PROPN
eurjchem-940	3	106	.	.	PROPN
eurjchem-940	3	107	tel	tel	PROPN
eurjchem-940	3	108	.	.	PUNCT
eurjchem-940	3	109	:	:	PUNCT
eurjchem-940	4	1	+1.308.8658479	+1.308.8658479	ADJ
eurjchem-940	4	2	.	.	PUNCT
eurjchem-940	5	1	fax	fax	NOUN
eurjchem-940	5	2	:	:	PUNCT
eurjchem-940	5	3	+1.308.8658479	+1.308.8658479	ADJ
eurjchem-940	5	4	.	.	PUNCT
eurjchem-940	5	5	e‐mail	e‐mail	PUNCT
eurjchem-940	6	1	address	address	NOUN
eurjchem-940	6	2	:	:	PUNCT
eurjchem-940	6	3	palenciah2@unk.edu	palenciah2@unk.edu	PROPN
eurjchem-940	6	4	(	(	PUNCT
eurjchem-940	6	5	h.	h.	PROPN
eurjchem-940	6	6	palencia	palencia	PROPN
eurjchem-940	6	7	)	)	PUNCT
eurjchem-940	6	8	.	.	PUNCT
eurjchem-940	7	1	article	article	NOUN
eurjchem-940	7	2	information	information	PROPN
eurjchem-940	7	3	abstract	abstract	ADJ
eurjchem-940	7	4	doi	doi	NOUN
eurjchem-940	7	5	:	:	PUNCT
eurjchem-940	7	6	10.5155	10.5155	NUM
eurjchem-940	7	7	/	/	SYM
eurjchem-940	7	8	eurjchem.5.1.162‐166.940	eurjchem.5.1.162‐166.940	PROPN
eurjchem-940	7	9	received	receive	VERB
eurjchem-940	7	10	:	:	PUNCT
eurjchem-940	7	11	29	29	NUM
eurjchem-940	7	12	september	september	PROPN
eurjchem-940	7	13	2013	2013	NUM
eurjchem-940	7	14	received	receive	VERB
eurjchem-940	7	15	in	in	ADP
eurjchem-940	7	16	revised	revise	VERB
eurjchem-940	7	17	form	form	NOUN
eurjchem-940	7	18	:	:	PUNCT
eurjchem-940	7	19	28	28	NUM
eurjchem-940	7	20	october	october	PROPN
eurjchem-940	7	21	2013	2013	NUM
eurjchem-940	7	22	accepted	accept	VERB
eurjchem-940	7	23	:	:	PUNCT
eurjchem-940	7	24	29	29	NUM
eurjchem-940	7	25	october	october	PROPN
eurjchem-940	7	26	2013	2013	NUM
eurjchem-940	7	27	online	online	NOUN
eurjchem-940	7	28	:	:	PUNCT
eurjchem-940	7	29	31	31	NUM
eurjchem-940	7	30	march	march	NOUN
eurjchem-940	7	31	2014	2014	NUM
eurjchem-940	7	32	keywords	keyword	VERB
eurjchem-940	7	33	an	an	DET
eurjchem-940	7	34	unsymmetrical	unsymmetrical	ADJ
eurjchem-940	7	35	,	,	PUNCT
eurjchem-940	7	36	well‐defined	well‐defined	ADJ
eurjchem-940	7	37	n‐heterocyclic	n‐heterocyclic	PUNCT
eurjchem-940	7	38	carbene‐palladium‐η3‐allyl	carbene‐palladium‐η3‐allyl	ADJ
eurjchem-940	7	39	chloride	chloride	NOUN
eurjchem-940	7	40	complex	complex	NOUN
eurjchem-940	7	41	has	have	AUX
eurjchem-940	7	42	been	be	AUX
eurjchem-940	7	43	synthesized	synthesize	VERB
eurjchem-940	7	44	and	and	CCONJ
eurjchem-940	7	45	used	use	VERB
eurjchem-940	7	46	as	as	ADP
eurjchem-940	7	47	an	an	DET
eurjchem-940	7	48	efficient	efficient	ADJ
eurjchem-940	7	49	catalyst	catalyst	NOUN
eurjchem-940	7	50	for	for	ADP
eurjchem-940	7	51	the	the	DET
eurjchem-940	7	52	suzuki‐miyaura	suzuki‐miyaura	NOUN
eurjchem-940	7	53	cross‐coupling	cross‐coupling	NOUN
eurjchem-940	7	54	of	of	ADP
eurjchem-940	7	55	aryl	aryl	NOUN
eurjchem-940	7	56	bromides	bromide	NOUN
eurjchem-940	7	57	and	and	CCONJ
eurjchem-940	7	58	activated	activate	VERB
eurjchem-940	7	59	aryl	aryl	NOUN
eurjchem-940	7	60	chlorides	chloride	NOUN
eurjchem-940	7	61	.	.	PUNCT
eurjchem-940	8	1	the	the	DET
eurjchem-940	8	2	catalyst	catalyst	NOUN
eurjchem-940	8	3	provides	provide	VERB
eurjchem-940	8	4	moderate	moderate	ADJ
eurjchem-940	8	5	to	to	ADP
eurjchem-940	8	6	high	high	ADJ
eurjchem-940	8	7	yields	yield	NOUN
eurjchem-940	8	8	of	of	ADP
eurjchem-940	8	9	cross‐coupling	cross‐couple	VERB
eurjchem-940	8	10	products	product	NOUN
eurjchem-940	8	11	at	at	ADP
eurjchem-940	8	12	50	50	NUM
eurjchem-940	8	13	°	°	NOUN
eurjchem-940	8	14	c	c	NOUN
eurjchem-940	8	15	in	in	ADP
eurjchem-940	8	16	2	2	NUM
eurjchem-940	8	17	hours	hour	NOUN
eurjchem-940	8	18	,	,	PUNCT
eurjchem-940	8	19	using	use	VERB
eurjchem-940	8	20	1	1	NUM
eurjchem-940	8	21	mol	mol	ADP
eurjchem-940	8	22	%	%	NOUN
eurjchem-940	8	23	of	of	ADP
eurjchem-940	8	24	the	the	DET
eurjchem-940	8	25	catalyst	catalyst	NOUN
eurjchem-940	8	26	and	and	CCONJ
eurjchem-940	8	27	isopropyl	isopropyl	NOUN
eurjchem-940	8	28	alcohol	alcohol	NOUN
eurjchem-940	8	29	as	as	ADP
eurjchem-940	8	30	solvent	solvent	NOUN
eurjchem-940	8	31	.	.	PUNCT
eurjchem-940	9	1	carbenes	carbene	NOUN
eurjchem-940	9	2	palladium	palladium	NOUN
eurjchem-940	9	3	aryl	aryl	NOUN
eurjchem-940	9	4	chlorides	chloride	NOUN
eurjchem-940	9	5	aryl	aryl	NOUN
eurjchem-940	9	6	bromides	bromide	NOUN
eurjchem-940	9	7	cross‐coupling	cross‐couple	VERB
eurjchem-940	9	8	homogeneous	homogeneous	ADJ
eurjchem-940	9	9	catalysis	catalysis	NOUN
eurjchem-940	9	10	1	1	NUM
eurjchem-940	9	11	.	.	PUNCT
eurjchem-940	9	12	introduction	introduction	NOUN
eurjchem-940	9	13	the	the	DET
eurjchem-940	9	14	suzuki‐miyaura	suzuki‐miyaura	NOUN
eurjchem-940	9	15	cross‐coupling	cross‐couple	VERB
eurjchem-940	9	16	is	be	AUX
eurjchem-940	9	17	one	one	NUM
eurjchem-940	9	18	of	of	ADP
eurjchem-940	9	19	the	the	DET
eurjchem-940	9	20	most	most	ADV
eurjchem-940	9	21	useful	useful	ADJ
eurjchem-940	9	22	methodologies	methodology	NOUN
eurjchem-940	9	23	for	for	ADP
eurjchem-940	9	24	carbon‐carbon	carbon‐carbon	NOUN
eurjchem-940	9	25	bond	bond	NOUN
eurjchem-940	9	26	formation	formation	NOUN
eurjchem-940	9	27	and	and	CCONJ
eurjchem-940	9	28	it	it	PRON
eurjchem-940	9	29	is	be	AUX
eurjchem-940	9	30	widely	widely	ADV
eurjchem-940	9	31	used	use	VERB
eurjchem-940	9	32	for	for	ADP
eurjchem-940	9	33	biaryl	biaryl	NOUN
eurjchem-940	9	34	synthesis	synthesis	NOUN
eurjchem-940	9	35	.	.	PUNCT
eurjchem-940	10	1	palladium	palladium	NOUN
eurjchem-940	10	2	catalysts	catalyst	NOUN
eurjchem-940	10	3	with	with	ADP
eurjchem-940	10	4	phosphines	phosphine	NOUN
eurjchem-940	10	5	ligands	ligand	NOUN
eurjchem-940	10	6	were	be	AUX
eurjchem-940	10	7	initially	initially	ADV
eurjchem-940	10	8	employed	employ	VERB
eurjchem-940	10	9	and	and	CCONJ
eurjchem-940	10	10	are	be	AUX
eurjchem-940	10	11	still	still	ADV
eurjchem-940	10	12	extensively	extensively	ADV
eurjchem-940	10	13	used	use	VERB
eurjchem-940	10	14	to	to	PART
eurjchem-940	10	15	catalyze	catalyze	NOUN
eurjchem-940	10	16	biaryl	biaryl	NOUN
eurjchem-940	10	17	formation	formation	NOUN
eurjchem-940	10	18	between	between	ADP
eurjchem-940	10	19	aryl	aryl	NOUN
eurjchem-940	10	20	halides	halide	NOUN
eurjchem-940	10	21	,	,	PUNCT
eurjchem-940	10	22	triflates	triflate	NOUN
eurjchem-940	10	23	,	,	PUNCT
eurjchem-940	10	24	and	and	CCONJ
eurjchem-940	10	25	others	other	NOUN
eurjchem-940	10	26	,	,	PUNCT
eurjchem-940	10	27	with	with	ADP
eurjchem-940	10	28	boronic	boronic	ADJ
eurjchem-940	10	29	acids	acid	NOUN
eurjchem-940	10	30	and	and	CCONJ
eurjchem-940	10	31	esters	ester	NOUN
eurjchem-940	11	1	[	[	X
eurjchem-940	11	2	1‐	1‐	NUM
eurjchem-940	11	3	3	3	NUM
eurjchem-940	11	4	]	]	PUNCT
eurjchem-940	11	5	.	.	PUNCT
eurjchem-940	12	1	however	however	ADV
eurjchem-940	12	2	,	,	PUNCT
eurjchem-940	12	3	upon	upon	SCONJ
eurjchem-940	12	4	the	the	DET
eurjchem-940	12	5	report	report	NOUN
eurjchem-940	12	6	of	of	ADP
eurjchem-940	12	7	the	the	DET
eurjchem-940	12	8	first	first	ADJ
eurjchem-940	12	9	isolated	isolate	VERB
eurjchem-940	12	10	n‐heterocyclic	n‐heterocyclic	SYM
eurjchem-940	12	11	carbene	carbene	NOUN
eurjchem-940	12	12	(	(	PUNCT
eurjchem-940	12	13	nhc	nhc	PROPN
eurjchem-940	12	14	)	)	PUNCT
eurjchem-940	13	1	[	[	X
eurjchem-940	13	2	4	4	NUM
eurjchem-940	13	3	]	]	PUNCT
eurjchem-940	13	4	,	,	PUNCT
eurjchem-940	13	5	nhc	nhc	PROPN
eurjchem-940	13	6	’s	’s	PART
eurjchem-940	13	7	properties	property	NOUN
eurjchem-940	13	8	as	as	ADP
eurjchem-940	13	9	ligands	ligand	NOUN
eurjchem-940	13	10	for	for	ADP
eurjchem-940	13	11	metals	metal	NOUN
eurjchem-940	13	12	were	be	AUX
eurjchem-940	13	13	recognized	recognize	VERB
eurjchem-940	13	14	and	and	CCONJ
eurjchem-940	13	15	a	a	DET
eurjchem-940	13	16	new	new	ADJ
eurjchem-940	13	17	venue	venue	NOUN
eurjchem-940	13	18	for	for	ADP
eurjchem-940	13	19	their	their	PRON
eurjchem-940	13	20	complexes	complex	NOUN
eurjchem-940	13	21	in	in	ADP
eurjchem-940	13	22	catalysis	catalysis	NOUN
eurjchem-940	13	23	was	be	AUX
eurjchem-940	13	24	opened	open	VERB
eurjchem-940	13	25	[	[	PUNCT
eurjchem-940	13	26	5	5	NUM
eurjchem-940	13	27	]	]	PUNCT
eurjchem-940	13	28	.	.	PUNCT
eurjchem-940	14	1	nhcs	nhcs	PROPN
eurjchem-940	14	2	became	become	VERB
eurjchem-940	14	3	alternative	alternative	ADJ
eurjchem-940	14	4	ligands	ligand	NOUN
eurjchem-940	14	5	to	to	ADP
eurjchem-940	14	6	phosphines	phosphine	NOUN
eurjchem-940	14	7	for	for	ADP
eurjchem-940	14	8	metal‐catalyzed	metal‐catalyze	VERB
eurjchem-940	14	9	reactions	reaction	NOUN
eurjchem-940	14	10	because	because	SCONJ
eurjchem-940	14	11	they	they	PRON
eurjchem-940	14	12	have	have	VERB
eurjchem-940	14	13	strong	strong	ADJ
eurjchem-940	14	14	σ‐donating	σ‐donating	PUNCT
eurjchem-940	14	15	properties	property	NOUN
eurjchem-940	14	16	and	and	CCONJ
eurjchem-940	14	17	form	form	VERB
eurjchem-940	14	18	stronger	strong	ADJ
eurjchem-940	14	19	bonds	bond	NOUN
eurjchem-940	14	20	with	with	ADP
eurjchem-940	14	21	the	the	DET
eurjchem-940	14	22	metal	metal	NOUN
eurjchem-940	15	1	[	[	X
eurjchem-940	15	2	6,7	6,7	NUM
eurjchem-940	15	3	]	]	PUNCT
eurjchem-940	15	4	.	.	PUNCT
eurjchem-940	16	1	during	during	ADP
eurjchem-940	16	2	the	the	DET
eurjchem-940	16	3	last	last	ADJ
eurjchem-940	16	4	20	20	NUM
eurjchem-940	16	5	years	year	NOUN
eurjchem-940	16	6	,	,	PUNCT
eurjchem-940	16	7	nhc	nhc	PROPN
eurjchem-940	16	8	’s	’s	PART
eurjchem-940	16	9	are	be	AUX
eurjchem-940	16	10	becoming	become	VERB
eurjchem-940	16	11	complementary	complementary	ADJ
eurjchem-940	16	12	ligands	ligand	NOUN
eurjchem-940	16	13	to	to	ADP
eurjchem-940	16	14	phosphines	phosphine	NOUN
eurjchem-940	16	15	.	.	PUNCT
eurjchem-940	17	1	their	their	PRON
eurjchem-940	17	2	catalytic	catalytic	ADJ
eurjchem-940	17	3	activity	activity	NOUN
eurjchem-940	17	4	is	be	AUX
eurjchem-940	17	5	strongly	strongly	ADV
eurjchem-940	17	6	related	relate	VERB
eurjchem-940	17	7	to	to	ADP
eurjchem-940	17	8	the	the	DET
eurjchem-940	17	9	steric	steric	ADJ
eurjchem-940	17	10	environment	environment	NOUN
eurjchem-940	17	11	of	of	ADP
eurjchem-940	17	12	palladium	palladium	NOUN
eurjchem-940	17	13	imposed	impose	VERB
eurjchem-940	17	14	by	by	ADP
eurjchem-940	17	15	the	the	DET
eurjchem-940	17	16	n‐substituents	n‐substituent	NOUN
eurjchem-940	17	17	in	in	ADP
eurjchem-940	17	18	the	the	DET
eurjchem-940	17	19	imidazolidene	imidazolidene	NOUN
eurjchem-940	18	1	[	[	X
eurjchem-940	18	2	8‐10	8‐10	NUM
eurjchem-940	18	3	]	]	X
eurjchem-940	18	4	.	.	PUNCT
eurjchem-940	19	1	nhcs	nhcs	PROPN
eurjchem-940	19	2	have	have	AUX
eurjchem-940	19	3	been	be	AUX
eurjchem-940	19	4	used	use	VERB
eurjchem-940	19	5	intensively	intensively	ADV
eurjchem-940	19	6	for	for	ADP
eurjchem-940	19	7	carbon‐carbon	carbon‐carbon	NOUN
eurjchem-940	19	8	bond	bond	NOUN
eurjchem-940	19	9	formation	formation	NOUN
eurjchem-940	19	10	in	in	ADP
eurjchem-940	19	11	cross‐coupling	cross‐couple	VERB
eurjchem-940	19	12	reactions	reaction	NOUN
eurjchem-940	19	13	[	[	X
eurjchem-940	19	14	7,11,12	7,11,12	NUM
eurjchem-940	19	15	]	]	PUNCT
eurjchem-940	19	16	,	,	PUNCT
eurjchem-940	19	17	even	even	ADV
eurjchem-940	19	18	for	for	ADP
eurjchem-940	19	19	alkyl	alkyl	ADJ
eurjchem-940	19	20	electrophiles	electrophile	NOUN
eurjchem-940	19	21	[	[	X
eurjchem-940	19	22	13	13	NUM
eurjchem-940	19	23	]	]	PUNCT
eurjchem-940	19	24	.	.	PUNCT
eurjchem-940	20	1	they	they	PRON
eurjchem-940	20	2	have	have	AUX
eurjchem-940	20	3	also	also	ADV
eurjchem-940	20	4	been	be	AUX
eurjchem-940	20	5	used	use	VERB
eurjchem-940	20	6	as	as	ADP
eurjchem-940	20	7	ligands	ligand	NOUN
eurjchem-940	20	8	for	for	ADP
eurjchem-940	20	9	ruthenium	ruthenium	NOUN
eurjchem-940	20	10	complexes	complex	NOUN
eurjchem-940	20	11	in	in	ADP
eurjchem-940	20	12	ring	ring	NOUN
eurjchem-940	20	13	closing	closing	NOUN
eurjchem-940	20	14	metathesis	metathesis	NOUN
eurjchem-940	20	15	[	[	X
eurjchem-940	20	16	14‐16	14‐16	NUM
eurjchem-940	20	17	]	]	PUNCT
eurjchem-940	20	18	.	.	PUNCT
eurjchem-940	21	1	while	while	SCONJ
eurjchem-940	21	2	most	most	ADJ
eurjchem-940	21	3	of	of	ADP
eurjchem-940	21	4	nhc	nhc	PROPN
eurjchem-940	21	5	’s	’	VERB
eurjchem-940	21	6	used	use	VERB
eurjchem-940	21	7	in	in	ADP
eurjchem-940	21	8	cross‐coupling	cross‐couple	VERB
eurjchem-940	21	9	reactions	reaction	NOUN
eurjchem-940	21	10	are	be	AUX
eurjchem-940	21	11	symmetrically	symmetrically	ADV
eurjchem-940	21	12	substituted	substitute	VERB
eurjchem-940	21	13	,	,	PUNCT
eurjchem-940	21	14	unsymmetrical	unsymmetrical	ADJ
eurjchem-940	21	15	ligands	ligand	NOUN
eurjchem-940	21	16	allow	allow	VERB
eurjchem-940	21	17	diversification	diversification	NOUN
eurjchem-940	21	18	of	of	ADP
eurjchem-940	21	19	steric	steric	ADJ
eurjchem-940	21	20	bulkiness	bulkiness	NOUN
eurjchem-940	21	21	in	in	ADP
eurjchem-940	21	22	the	the	DET
eurjchem-940	21	23	vicinity	vicinity	NOUN
eurjchem-940	21	24	of	of	ADP
eurjchem-940	21	25	a	a	DET
eurjchem-940	21	26	metal	metal	NOUN
eurjchem-940	21	27	complex	complex	NOUN
eurjchem-940	21	28	allowing	allow	VERB
eurjchem-940	21	29	fine	fine	ADJ
eurjchem-940	21	30	tuning	tuning	NOUN
eurjchem-940	21	31	of	of	ADP
eurjchem-940	21	32	reactivity	reactivity	NOUN
eurjchem-940	21	33	[	[	X
eurjchem-940	21	34	17‐20	17‐20	NUM
eurjchem-940	21	35	]	]	X
eurjchem-940	21	36	.	.	PUNCT
eurjchem-940	22	1	the	the	DET
eurjchem-940	22	2	synthesis	synthesis	NOUN
eurjchem-940	22	3	of	of	ADP
eurjchem-940	22	4	nonsymmetrical	nonsymmetrical	ADJ
eurjchem-940	22	5	carbenes	carbene	NOUN
eurjchem-940	22	6	precursors	precursor	NOUN
eurjchem-940	22	7	can	can	AUX
eurjchem-940	22	8	be	be	AUX
eurjchem-940	22	9	done	do	VERB
eurjchem-940	22	10	by	by	ADP
eurjchem-940	22	11	an	an	DET
eurjchem-940	22	12	imidazole	imidazole	NOUN
eurjchem-940	22	13	alkylation	alkylation	NOUN
eurjchem-940	22	14	,	,	PUNCT
eurjchem-940	22	15	allowing	allow	VERB
eurjchem-940	22	16	the	the	DET
eurjchem-940	22	17	synthesis	synthesis	NOUN
eurjchem-940	22	18	of	of	ADP
eurjchem-940	22	19	several	several	ADJ
eurjchem-940	22	20	nhc	nhc	NOUN
eurjchem-940	22	21	precursors	precursor	NOUN
eurjchem-940	22	22	using	use	VERB
eurjchem-940	22	23	different	different	ADJ
eurjchem-940	22	24	alkyl	alkyl	NOUN
eurjchem-940	22	25	chains	chain	NOUN
eurjchem-940	22	26	[	[	X
eurjchem-940	22	27	18,21‐23	18,21‐23	NUM
eurjchem-940	22	28	]	]	PUNCT
eurjchem-940	22	29	.	.	PUNCT
eurjchem-940	23	1	the	the	DET
eurjchem-940	23	2	use	use	NOUN
eurjchem-940	23	3	of	of	ADP
eurjchem-940	23	4	well‐defined	well‐defined	ADJ
eurjchem-940	23	5	nhc‐palladium	nhc‐palladium	NOUN
eurjchem-940	23	6	complexes	complex	NOUN
eurjchem-940	23	7	avoids	avoid	VERB
eurjchem-940	23	8	the	the	DET
eurjchem-940	23	9	use	use	NOUN
eurjchem-940	23	10	of	of	ADP
eurjchem-940	23	11	an	an	DET
eurjchem-940	23	12	excess	excess	NOUN
eurjchem-940	23	13	of	of	ADP
eurjchem-940	23	14	the	the	DET
eurjchem-940	23	15	ligand	ligand	NOUN
eurjchem-940	23	16	,	,	PUNCT
eurjchem-940	23	17	they	they	PRON
eurjchem-940	23	18	also	also	ADV
eurjchem-940	23	19	have	have	VERB
eurjchem-940	23	20	the	the	DET
eurjchem-940	23	21	advantage	advantage	NOUN
eurjchem-940	23	22	of	of	ADP
eurjchem-940	23	23	their	their	PRON
eurjchem-940	23	24	stability	stability	NOUN
eurjchem-940	23	25	and	and	CCONJ
eurjchem-940	23	26	easy	easy	ADJ
eurjchem-940	23	27	handling	handling	NOUN
eurjchem-940	23	28	[	[	X
eurjchem-940	23	29	24	24	NUM
eurjchem-940	23	30	]	]	PUNCT
eurjchem-940	23	31	.	.	PUNCT
eurjchem-940	24	1	we	we	PRON
eurjchem-940	24	2	previously	previously	ADV
eurjchem-940	24	3	reported	report	VERB
eurjchem-940	24	4	a	a	DET
eurjchem-940	24	5	highly	highly	ADV
eurjchem-940	24	6	active	active	ADJ
eurjchem-940	24	7	palladium‐nhc‐palladacycle	palladium‐nhc‐palladacycle	NUM
eurjchem-940	24	8	complex	complex	NOUN
eurjchem-940	24	9	for	for	ADP
eurjchem-940	24	10	the	the	DET
eurjchem-940	24	11	suzuki‐miyaura	suzuki‐miyaura	NOUN
eurjchem-940	24	12	cross‐coupling	cross‐coupling	NOUN
eurjchem-940	24	13	of	of	ADP
eurjchem-940	24	14	aryl	aryl	NOUN
eurjchem-940	24	15	iodides	iodide	NOUN
eurjchem-940	24	16	reaction	reaction	NOUN
eurjchem-940	24	17	[	[	X
eurjchem-940	24	18	18	18	NUM
eurjchem-940	24	19	]	]	PUNCT
eurjchem-940	24	20	.	.	PUNCT
eurjchem-940	25	1	we	we	PRON
eurjchem-940	25	2	report	report	VERB
eurjchem-940	25	3	herein	herein	NOUN
eurjchem-940	25	4	a	a	DET
eurjchem-940	25	5	new	new	ADJ
eurjchem-940	25	6	well‐defined	well‐defined	ADJ
eurjchem-940	25	7	non‐symmetrical	non‐symmetrical	PRON
eurjchem-940	25	8	[	[	X
eurjchem-940	25	9	(	(	PUNCT
eurjchem-940	25	10	nhc)‐	nhc)‐	PROPN
eurjchem-940	25	11	palladium‐(allyl)cl	palladium‐(allyl)cl	PROPN
eurjchem-940	25	12	]	]	PUNCT
eurjchem-940	25	13	catalyst	catalyst	NOUN
eurjchem-940	25	14	for	for	ADP
eurjchem-940	25	15	the	the	DET
eurjchem-940	25	16	suzuki‐miyaura	suzuki‐miyaura	PROPN
eurjchem-940	25	17	cross‐	cross‐	NOUN
eurjchem-940	25	18	coupling	coupling	NOUN
eurjchem-940	25	19	of	of	ADP
eurjchem-940	25	20	aryl	aryl	NOUN
eurjchem-940	25	21	bromides	bromide	NOUN
eurjchem-940	25	22	and	and	CCONJ
eurjchem-940	25	23	chlorides	chloride	NOUN
eurjchem-940	25	24	.	.	PUNCT
eurjchem-940	26	1	2	2	X
eurjchem-940	26	2	.	.	X
eurjchem-940	26	3	experimental	experimental	ADJ
eurjchem-940	26	4	2.1	2.1	NUM
eurjchem-940	26	5	.	.	PUNCT
eurjchem-940	27	1	instrumentation	instrumentation	NOUN
eurjchem-940	27	2	melting	melting	NOUN
eurjchem-940	27	3	points	point	NOUN
eurjchem-940	27	4	were	be	AUX
eurjchem-940	27	5	recorded	record	VERB
eurjchem-940	27	6	on	on	ADP
eurjchem-940	27	7	a	a	DET
eurjchem-940	27	8	fisher‐johns	fisher‐johns	NOUN
eurjchem-940	27	9	melting	melting	NOUN
eurjchem-940	27	10	point	point	NOUN
eurjchem-940	27	11	apparatus	apparatus	NOUN
eurjchem-940	27	12	and	and	CCONJ
eurjchem-940	27	13	are	be	AUX
eurjchem-940	27	14	uncorrected	uncorrecte	VERB
eurjchem-940	27	15	.	.	PUNCT
eurjchem-940	28	1	1h	1h	NUM
eurjchem-940	28	2	nmr	nmr	NOUN
eurjchem-940	28	3	was	be	AUX
eurjchem-940	28	4	recorded	record	VERB
eurjchem-940	28	5	on	on	ADP
eurjchem-940	28	6	a	a	DET
eurjchem-940	28	7	bruker	bruker	ADJ
eurjchem-940	28	8	ultra	ultra	ADJ
eurjchem-940	28	9	shield‐300	shield‐300	NOUN
eurjchem-940	28	10	(	(	PUNCT
eurjchem-940	28	11	300	300	NUM
eurjchem-940	28	12	mhz	mhz	NOUN
eurjchem-940	28	13	)	)	PUNCT
eurjchem-940	28	14	.	.	PUNCT
eurjchem-940	29	1	chemical	chemical	ADJ
eurjchem-940	29	2	shifts	shift	NOUN
eurjchem-940	29	3	are	be	AUX
eurjchem-940	29	4	reported	report	VERB
eurjchem-940	29	5	in	in	ADP
eurjchem-940	29	6	parts	part	NOUN
eurjchem-940	29	7	per	per	ADP
eurjchem-940	29	8	million	million	NUM
eurjchem-940	29	9	(	(	PUNCT
eurjchem-940	29	10	ppm	ppm	NOUN
eurjchem-940	29	11	)	)	PUNCT
eurjchem-940	29	12	down	down	ADP
eurjchem-940	29	13	field	field	NOUN
eurjchem-940	29	14	from	from	ADP
eurjchem-940	29	15	tms	tms	PROPN
eurjchem-940	29	16	,	,	PUNCT
eurjchem-940	29	17	using	use	VERB
eurjchem-940	29	18	broekemier	broekemier	PROPN
eurjchem-940	29	19	et	et	PROPN
eurjchem-940	29	20	al	al	PROPN
eurjchem-940	29	21	.	.	PUNCT
eurjchem-940	29	22	/	/	SYM
eurjchem-940	29	23	european	european	PROPN
eurjchem-940	29	24	journal	journal	PROPN
eurjchem-940	29	25	of	of	ADP
eurjchem-940	29	26	chemistry	chemistry	NOUN
eurjchem-940	29	27	5	5	NUM
eurjchem-940	29	28	(	(	PUNCT
eurjchem-940	29	29	1	1	NUM
eurjchem-940	29	30	)	)	PUNCT
eurjchem-940	29	31	(	(	PUNCT
eurjchem-940	29	32	2014	2014	NUM
eurjchem-940	29	33	)	)	PUNCT
eurjchem-940	29	34	162‐166	162‐166	PROPN
eurjchem-940	29	35	163	163	NUM
eurjchem-940	29	36	residual	residual	ADJ
eurjchem-940	29	37	cdcl3	cdcl3	NOUN
eurjchem-940	29	38	as	as	ADP
eurjchem-940	29	39	an	an	DET
eurjchem-940	29	40	internal	internal	ADJ
eurjchem-940	29	41	standard	standard	NOUN
eurjchem-940	29	42	(	(	PUNCT
eurjchem-940	29	43	7.24	7.24	NUM
eurjchem-940	29	44	ppm	ppm	NOUN
eurjchem-940	29	45	)	)	PUNCT
eurjchem-940	29	46	.	.	PUNCT
eurjchem-940	30	1	data	datum	NOUN
eurjchem-940	30	2	are	be	AUX
eurjchem-940	30	3	reported	report	VERB
eurjchem-940	30	4	as	as	SCONJ
eurjchem-940	30	5	follows	follow	VERB
eurjchem-940	30	6	:	:	PUNCT
eurjchem-940	30	7	chemical	chemical	NOUN
eurjchem-940	30	8	shift	shift	NOUN
eurjchem-940	30	9	,	,	PUNCT
eurjchem-940	30	10	multiplicity	multiplicity	NOUN
eurjchem-940	30	11	(	(	PUNCT
eurjchem-940	30	12	s	s	NOUN
eurjchem-940	30	13	=	=	NOUN
eurjchem-940	30	14	singlet	singlet	NOUN
eurjchem-940	30	15	,	,	PUNCT
eurjchem-940	30	16	d	d	PROPN
eurjchem-940	30	17	=	=	SYM
eurjchem-940	30	18	doublet	doublet	PROPN
eurjchem-940	30	19	,	,	PUNCT
eurjchem-940	30	20	dd	dd	NOUN
eurjchem-940	30	21	=	=	NOUN
eurjchem-940	30	22	doublet	doublet	NOUN
eurjchem-940	30	23	of	of	ADP
eurjchem-940	30	24	doublets	doublet	NOUN
eurjchem-940	30	25	,	,	PUNCT
eurjchem-940	30	26	t	t	NOUN
eurjchem-940	30	27	=	=	PUNCT
eurjchem-940	30	28	triplet	triplet	NOUN
eurjchem-940	30	29	,	,	PUNCT
eurjchem-940	30	30	q	q	NOUN
eurjchem-940	30	31	=	=	SYM
eurjchem-940	30	32	quartet	quartet	NOUN
eurjchem-940	30	33	,	,	PUNCT
eurjchem-940	30	34	m	m	NOUN
eurjchem-940	30	35	=	=	PUNCT
eurjchem-940	30	36	multiplet	multiplet	NOUN
eurjchem-940	30	37	)	)	PUNCT
eurjchem-940	30	38	,	,	PUNCT
eurjchem-940	30	39	coupling	couple	VERB
eurjchem-940	30	40	constant(s	constant(s	PROPN
eurjchem-940	30	41	)	)	PUNCT
eurjchem-940	30	42	and	and	CCONJ
eurjchem-940	30	43	integration	integration	NOUN
eurjchem-940	30	44	.	.	PUNCT
eurjchem-940	31	1	13c	13c	NOUN
eurjchem-940	31	2	nmr	nmr	NOUN
eurjchem-940	31	3	was	be	AUX
eurjchem-940	31	4	recorded	record	VERB
eurjchem-940	31	5	on	on	ADP
eurjchem-940	31	6	a	a	DET
eurjchem-940	31	7	bruker	bruker	ADJ
eurjchem-940	31	8	ultra	ultra	ADJ
eurjchem-940	31	9	shield	shield	NOUN
eurjchem-940	31	10	(	(	PUNCT
eurjchem-940	31	11	75	75	NUM
eurjchem-940	31	12	mhz	mhz	NOUN
eurjchem-940	31	13	)	)	PUNCT
eurjchem-940	31	14	.	.	PUNCT
eurjchem-940	32	1	chemical	chemical	ADJ
eurjchem-940	32	2	shifts	shift	NOUN
eurjchem-940	32	3	are	be	AUX
eurjchem-940	32	4	reported	report	VERB
eurjchem-940	32	5	in	in	ADP
eurjchem-940	32	6	parts	part	NOUN
eurjchem-940	32	7	per	per	ADP
eurjchem-940	32	8	million	million	NUM
eurjchem-940	32	9	(	(	PUNCT
eurjchem-940	32	10	ppm	ppm	NOUN
eurjchem-940	32	11	)	)	PUNCT
eurjchem-940	32	12	down	down	ADP
eurjchem-940	32	13	field	field	NOUN
eurjchem-940	32	14	from	from	ADP
eurjchem-940	32	15	tms	tms	PROPN
eurjchem-940	32	16	,	,	PUNCT
eurjchem-940	32	17	using	use	VERB
eurjchem-940	32	18	the	the	DET
eurjchem-940	32	19	middle	middle	ADJ
eurjchem-940	32	20	resonance	resonance	NOUN
eurjchem-940	32	21	of	of	ADP
eurjchem-940	32	22	cdcl3	cdcl3	NOUN
eurjchem-940	32	23	(	(	PUNCT
eurjchem-940	32	24	77.23	77.23	NUM
eurjchem-940	32	25	ppm	ppm	NOUN
eurjchem-940	32	26	)	)	PUNCT
eurjchem-940	32	27	as	as	ADP
eurjchem-940	32	28	an	an	DET
eurjchem-940	32	29	internal	internal	ADJ
eurjchem-940	32	30	standard	standard	NOUN
eurjchem-940	32	31	.	.	PUNCT
eurjchem-940	33	1	high‐resolution	high‐resolution	PROPN
eurjchem-940	33	2	mass	mass	PROPN
eurjchem-940	33	3	spectra	spectra	NOUN
eurjchem-940	33	4	(	(	PUNCT
eurjchem-940	33	5	hrms	hrm	NOUN
eurjchem-940	33	6	)	)	PUNCT
eurjchem-940	33	7	were	be	AUX
eurjchem-940	33	8	obtained	obtain	VERB
eurjchem-940	33	9	from	from	ADP
eurjchem-940	33	10	nebraska	nebraska	PROPN
eurjchem-940	33	11	center	center	PROPN
eurjchem-940	33	12	for	for	ADP
eurjchem-940	33	13	mass	mass	ADJ
eurjchem-940	33	14	spectrometry	spectrometry	NOUN
eurjchem-940	33	15	,	,	PUNCT
eurjchem-940	33	16	university	university	NOUN
eurjchem-940	33	17	of	of	ADP
eurjchem-940	33	18	nebraska‐lincoln	nebraska‐lincoln	PROPN
eurjchem-940	33	19	,	,	PUNCT
eurjchem-940	33	20	lincoln	lincoln	PROPN
eurjchem-940	33	21	,	,	PUNCT
eurjchem-940	33	22	ne	ne	PROPN
eurjchem-940	33	23	.	.	PROPN
eurjchem-940	33	24	2.2	2.2	NUM
eurjchem-940	33	25	.	.	PUNCT
eurjchem-940	34	1	synthesis	synthesis	NOUN
eurjchem-940	34	2	all	all	DET
eurjchem-940	34	3	chemicals	chemical	NOUN
eurjchem-940	34	4	were	be	AUX
eurjchem-940	34	5	purchased	purchase	VERB
eurjchem-940	34	6	from	from	ADP
eurjchem-940	34	7	aldrich	aldrich	PROPN
eurjchem-940	34	8	or	or	CCONJ
eurjchem-940	34	9	fisher	fisher	PROPN
eurjchem-940	34	10	and	and	CCONJ
eurjchem-940	34	11	used	use	VERB
eurjchem-940	34	12	as	as	SCONJ
eurjchem-940	34	13	received	receive	VERB
eurjchem-940	34	14	at	at	ADP
eurjchem-940	34	15	least	least	ADJ
eurjchem-940	34	16	otherwise	otherwise	ADV
eurjchem-940	34	17	is	be	AUX
eurjchem-940	34	18	indicated	indicate	VERB
eurjchem-940	34	19	.	.	PUNCT
eurjchem-940	35	1	deuterated	deuterate	VERB
eurjchem-940	35	2	solvents	solvent	NOUN
eurjchem-940	35	3	were	be	AUX
eurjchem-940	35	4	purchased	purchase	VERB
eurjchem-940	35	5	from	from	ADP
eurjchem-940	35	6	cambridge	cambridge	PROPN
eurjchem-940	35	7	isotope	isotope	NOUN
eurjchem-940	35	8	laboratories	laboratory	NOUN
eurjchem-940	35	9	.	.	PUNCT
eurjchem-940	36	1	potassium	potassium	NOUN
eurjchem-940	36	2	tert‐butoxide	tert‐butoxide	NOUN
eurjchem-940	36	3	was	be	AUX
eurjchem-940	36	4	purified	purify	VERB
eurjchem-940	36	5	by	by	ADP
eurjchem-940	36	6	sublimation	sublimation	NOUN
eurjchem-940	36	7	before	before	SCONJ
eurjchem-940	36	8	used	use	VERB
eurjchem-940	36	9	;	;	PUNCT
eurjchem-940	36	10	1‐(2,6‐diisopropylphenyl)‐1h‐imidazole	1‐(2,6‐diisopropylphenyl)‐1h‐imidazole	NUM
eurjchem-940	36	11	was	be	AUX
eurjchem-940	36	12	synthesized	synthesize	VERB
eurjchem-940	36	13	by	by	ADP
eurjchem-940	36	14	a	a	DET
eurjchem-940	36	15	reported	report	VERB
eurjchem-940	36	16	method	method	NOUN
eurjchem-940	36	17	[	[	X
eurjchem-940	36	18	25	25	NUM
eurjchem-940	36	19	]	]	PUNCT
eurjchem-940	36	20	.	.	PUNCT
eurjchem-940	37	1	dichloromethane	dichloromethane	NOUN
eurjchem-940	37	2	was	be	AUX
eurjchem-940	37	3	distilled	distil	VERB
eurjchem-940	37	4	under	under	ADP
eurjchem-940	37	5	nitrogen	nitrogen	NOUN
eurjchem-940	37	6	from	from	ADP
eurjchem-940	37	7	calcium	calcium	NOUN
eurjchem-940	37	8	hydride	hydride	NOUN
eurjchem-940	37	9	prior	prior	ADV
eurjchem-940	37	10	to	to	ADP
eurjchem-940	37	11	its	its	PRON
eurjchem-940	37	12	use	use	NOUN
eurjchem-940	37	13	.	.	PUNCT
eurjchem-940	38	1	all	all	DET
eurjchem-940	38	2	glassware	glassware	NOUN
eurjchem-940	38	3	was	be	AUX
eurjchem-940	38	4	oven	oven	AUX
eurjchem-940	38	5	dried	dry	VERB
eurjchem-940	38	6	.	.	PUNCT
eurjchem-940	39	1	2.2.1	2.2.1	NUM
eurjchem-940	39	2	.	.	PUNCT
eurjchem-940	39	3	synthesis	synthesis	NOUN
eurjchem-940	39	4	of	of	ADP
eurjchem-940	39	5	3‐benzhydryl‐1‐(2,6‐diisopropylphenyl)‐	3‐benzhydryl‐1‐(2,6‐diisopropylphenyl)‐	NUM
eurjchem-940	39	6	1h‐imidazol‐3‐ium	1h‐imidazol‐3‐ium	NUM
eurjchem-940	39	7	chloride	chloride	NOUN
eurjchem-940	39	8	a	a	DET
eurjchem-940	39	9	glass	glass	NOUN
eurjchem-940	39	10	vial	vial	NOUN
eurjchem-940	39	11	(	(	PUNCT
eurjchem-940	39	12	10	10	NUM
eurjchem-940	39	13	ml	ml	NOUN
eurjchem-940	39	14	)	)	PUNCT
eurjchem-940	39	15	provided	provide	VERB
eurjchem-940	39	16	with	with	ADP
eurjchem-940	39	17	a	a	DET
eurjchem-940	39	18	stirring	stir	VERB
eurjchem-940	39	19	bar	bar	NOUN
eurjchem-940	39	20	was	be	AUX
eurjchem-940	39	21	charged	charge	VERB
eurjchem-940	39	22	with	with	ADP
eurjchem-940	39	23	1‐(2,6‐diisopropylphenyl)‐1h‐imidazole	1‐(2,6‐diisopropylphenyl)‐1h‐imidazole	NUM
eurjchem-940	39	24	(	(	PUNCT
eurjchem-940	39	25	1	1	NUM
eurjchem-940	39	26	equivalent	equivalent	NOUN
eurjchem-940	39	27	)	)	PUNCT
eurjchem-940	39	28	and	and	CCONJ
eurjchem-940	39	29	(	(	PUNCT
eurjchem-940	39	30	chloromethylene)dibenzene	chloromethylene)dibenzene	X
eurjchem-940	39	31	(	(	PUNCT
eurjchem-940	39	32	1	1	NUM
eurjchem-940	39	33	equivalent	equivalent	NOUN
eurjchem-940	39	34	)	)	PUNCT
eurjchem-940	39	35	.	.	PUNCT
eurjchem-940	40	1	the	the	DET
eurjchem-940	40	2	vial	vial	ADJ
eurjchem-940	40	3	was	be	AUX
eurjchem-940	40	4	capped	cap	VERB
eurjchem-940	40	5	and	and	CCONJ
eurjchem-940	40	6	heated	heat	VERB
eurjchem-940	40	7	at	at	ADP
eurjchem-940	40	8	100‐110	100‐110	PROPN
eurjchem-940	40	9	°	°	PROPN
eurjchem-940	40	10	c	c	NOUN
eurjchem-940	40	11	overnight	overnight	ADV
eurjchem-940	40	12	.	.	PUNCT
eurjchem-940	41	1	the	the	DET
eurjchem-940	41	2	imidazolium	imidazolium	NOUN
eurjchem-940	41	3	salt	salt	NOUN
eurjchem-940	41	4	was	be	AUX
eurjchem-940	41	5	obtained	obtain	VERB
eurjchem-940	41	6	in	in	ADP
eurjchem-940	41	7	quantitative	quantitative	ADJ
eurjchem-940	41	8	yield	yield	NOUN
eurjchem-940	41	9	and	and	CCONJ
eurjchem-940	41	10	used	use	VERB
eurjchem-940	41	11	without	without	ADP
eurjchem-940	41	12	further	further	ADJ
eurjchem-940	41	13	purification	purification	NOUN
eurjchem-940	41	14	.	.	PUNCT
eurjchem-940	42	1	color	color	NOUN
eurjchem-940	42	2	:	:	PUNCT
eurjchem-940	42	3	white	white	PROPN
eurjchem-940	42	4	solid	solid	ADJ
eurjchem-940	42	5	.	.	PUNCT
eurjchem-940	43	1	m.p	m.p	PROPN
eurjchem-940	43	2	.	.	PROPN
eurjchem-940	43	3	:	:	PUNCT
eurjchem-940	44	1	225.1‐	225.1‐	PROPN
eurjchem-940	44	2	225.9	225.9	NUM
eurjchem-940	44	3	°	°	PROPN
eurjchem-940	44	4	c	c	PROPN
eurjchem-940	44	5	.	.	PUNCT
eurjchem-940	45	1	1h	1h	NUM
eurjchem-940	45	2	nmr	nmr	NOUN
eurjchem-940	45	3	(	(	PUNCT
eurjchem-940	45	4	300	300	NUM
eurjchem-940	45	5	mhz	mhz	NOUN
eurjchem-940	45	6	,	,	PUNCT
eurjchem-940	45	7	cdcl3	cdcl3	PROPN
eurjchem-940	45	8	,	,	PUNCT
eurjchem-940	45	9	δ	δ	PROPN
eurjchem-940	45	10	,	,	PUNCT
eurjchem-940	45	11	ppm	ppm	NUM
eurjchem-940	45	12	):	):	PUNCT
eurjchem-940	45	13	10.22	10.22	NUM
eurjchem-940	45	14	(	(	PUNCT
eurjchem-940	45	15	s	s	PROPN
eurjchem-940	45	16	,	,	PUNCT
eurjchem-940	45	17	1h	1h	NUM
eurjchem-940	45	18	,	,	PUNCT
eurjchem-940	45	19	nch	nch	NOUN
eurjchem-940	45	20	=	=	NOUN
eurjchem-940	45	21	n	n	NUM
eurjchem-940	45	22	)	)	PUNCT
eurjchem-940	45	23	,	,	PUNCT
eurjchem-940	45	24	8.51	8.51	NUM
eurjchem-940	45	25	(	(	PUNCT
eurjchem-940	45	26	s	s	PROPN
eurjchem-940	45	27	,	,	PUNCT
eurjchem-940	45	28	1h	1h	NUM
eurjchem-940	45	29	,	,	PUNCT
eurjchem-940	45	30	c4‐h	c4‐h	NOUN
eurjchem-940	45	31	imidazol‐3‐ium	imidazol‐3‐ium	NOUN
eurjchem-940	45	32	)	)	PUNCT
eurjchem-940	45	33	,	,	PUNCT
eurjchem-940	45	34	7.58	7.58	NUM
eurjchem-940	45	35	(	(	PUNCT
eurjchem-940	45	36	s	s	PROPN
eurjchem-940	45	37	,	,	PUNCT
eurjchem-940	45	38	1h	1h	NUM
eurjchem-940	45	39	,	,	PUNCT
eurjchem-940	45	40	c5‐h	c5‐h	PROPN
eurjchem-940	45	41	imidazol‐3‐ium	imidazol‐3‐ium	PROPN
eurjchem-940	45	42	)	)	PUNCT
eurjchem-940	45	43	,	,	PUNCT
eurjchem-940	45	44	7.45	7.45	NUM
eurjchem-940	45	45	(	(	PUNCT
eurjchem-940	45	46	t	t	PROPN
eurjchem-940	45	47	,	,	PUNCT
eurjchem-940	45	48	1h	1h	NUM
eurjchem-940	45	49	,	,	PUNCT
eurjchem-940	45	50	j	j	PROPN
eurjchem-940	45	51	=	=	SYM
eurjchem-940	45	52	7.8	7.8	NUM
eurjchem-940	45	53	hz	hz	NOUN
eurjchem-940	45	54	,	,	PUNCT
eurjchem-940	45	55	ar‐h	ar‐h	NOUN
eurjchem-940	45	56	)	)	PUNCT
eurjchem-940	45	57	,	,	PUNCT
eurjchem-940	45	58	7.29‐7.37	7.29‐7.37	NUM
eurjchem-940	45	59	(	(	PUNCT
eurjchem-940	45	60	m	m	PROPN
eurjchem-940	45	61	,	,	PUNCT
eurjchem-940	45	62	10h	10h	NUM
eurjchem-940	45	63	,	,	PUNCT
eurjchem-940	45	64	ar‐h	ar‐h	PROPN
eurjchem-940	45	65	)	)	PUNCT
eurjchem-940	45	66	,	,	PUNCT
eurjchem-940	45	67	7.18‐	7.18‐	NUM
eurjchem-940	45	68	7.22	7.22	NUM
eurjchem-940	45	69	(	(	PUNCT
eurjchem-940	45	70	m	m	PROPN
eurjchem-940	45	71	,	,	PUNCT
eurjchem-940	45	72	3h	3h	NUM
eurjchem-940	45	73	,	,	PUNCT
eurjchem-940	45	74	ar‐h	ar‐h	NOUN
eurjchem-940	45	75	,	,	PUNCT
eurjchem-940	45	76	ar‐ch‐ar	ar‐ch‐ar	NOUN
eurjchem-940	45	77	)	)	PUNCT
eurjchem-940	45	78	,	,	PUNCT
eurjchem-940	45	79	2.22‐2.35	2.22‐2.35	NUM
eurjchem-940	45	80	(	(	PUNCT
eurjchem-940	45	81	m	m	PROPN
eurjchem-940	45	82	,	,	PUNCT
eurjchem-940	45	83	2h	2h	NUM
eurjchem-940	45	84	,	,	PUNCT
eurjchem-940	45	85	ch3‐ch‐ch3	ch3‐ch‐ch3	ADJ
eurjchem-940	45	86	)	)	PUNCT
eurjchem-940	45	87	,	,	PUNCT
eurjchem-940	45	88	1.11	1.11	NUM
eurjchem-940	45	89	(	(	PUNCT
eurjchem-940	45	90	t	t	PROPN
eurjchem-940	45	91	,	,	PUNCT
eurjchem-940	45	92	12	12	NUM
eurjchem-940	45	93	h	h	NOUN
eurjchem-940	45	94	,	,	PUNCT
eurjchem-940	45	95	j	j	PROPN
eurjchem-940	45	96	=	=	PROPN
eurjchem-940	45	97	6.6	6.6	NUM
eurjchem-940	45	98	hz	hz	NOUN
eurjchem-940	45	99	,	,	PUNCT
eurjchem-940	45	100	2x[ch3‐ch‐ch3	2x[ch3‐ch‐ch3	ADJ
eurjchem-940	45	101	]	]	PUNCT
eurjchem-940	45	102	)	)	PUNCT
eurjchem-940	45	103	.	.	PUNCT
eurjchem-940	46	1	13c	13c	NOUN
eurjchem-940	46	2	nmr	nmr	NOUN
eurjchem-940	46	3	(	(	PUNCT
eurjchem-940	46	4	75	75	NUM
eurjchem-940	46	5	mhz	mhz	NOUN
eurjchem-940	46	6	,	,	PUNCT
eurjchem-940	46	7	cdcl3	cdcl3	PROPN
eurjchem-940	46	8	,	,	PUNCT
eurjchem-940	46	9	δ	δ	PROPN
eurjchem-940	46	10	,	,	PUNCT
eurjchem-940	46	11	ppm	ppm	NOUN
eurjchem-940	46	12	):	):	PUNCT
eurjchem-940	46	13	145.2	145.2	NUM
eurjchem-940	46	14	,	,	PUNCT
eurjchem-940	46	15	139.2	139.2	NUM
eurjchem-940	46	16	,	,	PUNCT
eurjchem-940	46	17	136.9	136.9	NUM
eurjchem-940	46	18	,	,	PUNCT
eurjchem-940	46	19	131.8	131.8	NUM
eurjchem-940	46	20	,	,	PUNCT
eurjchem-940	46	21	130.2	130.2	NUM
eurjchem-940	46	22	,	,	PUNCT
eurjchem-940	46	23	129.2	129.2	NUM
eurjchem-940	46	24	,	,	PUNCT
eurjchem-940	46	25	129.1	129.1	NUM
eurjchem-940	46	26	,	,	PUNCT
eurjchem-940	46	27	128.3	128.3	NUM
eurjchem-940	46	28	,	,	PUNCT
eurjchem-940	46	29	124.6	124.6	NUM
eurjchem-940	46	30	,	,	PUNCT
eurjchem-940	46	31	123.8	123.8	NUM
eurjchem-940	46	32	,	,	PUNCT
eurjchem-940	46	33	122.3	122.3	NUM
eurjchem-940	46	34	,	,	PUNCT
eurjchem-940	46	35	66.1	66.1	NUM
eurjchem-940	46	36	,	,	PUNCT
eurjchem-940	46	37	22.7	22.7	NUM
eurjchem-940	46	38	,	,	PUNCT
eurjchem-940	46	39	24.3	24.3	NUM
eurjchem-940	46	40	,	,	PUNCT
eurjchem-940	46	41	24.0	24.0	NUM
eurjchem-940	46	42	.	.	PUNCT
eurjchem-940	47	1	hrms	hrm	NOUN
eurjchem-940	47	2	(	(	PUNCT
eurjchem-940	47	3	tof	tof	PROPN
eurjchem-940	47	4	ms	ms	PROPN
eurjchem-940	47	5	ei+	ei+	PROPN
eurjchem-940	47	6	):	):	PUNCT
eurjchem-940	47	7	calculated	calculate	VERB
eurjchem-940	47	8	for	for	ADP
eurjchem-940	47	9	c28h31n2	c28h31n2	PROPN
eurjchem-940	47	10	[	[	X
eurjchem-940	47	11	m‐2h]+	m‐2h]+	PROPN
eurjchem-940	47	12	393.2331	393.2331	NUM
eurjchem-940	47	13	,	,	PUNCT
eurjchem-940	47	14	found	find	VERB
eurjchem-940	47	15	:	:	PUNCT
eurjchem-940	47	16	393.2330	393.2330	NUM
eurjchem-940	47	17	.	.	PUNCT
eurjchem-940	48	1	2.2.2	2.2.2	NUM
eurjchem-940	48	2	.	.	PUNCT
eurjchem-940	49	1	synthesis	synthesis	NOUN
eurjchem-940	49	2	of	of	ADP
eurjchem-940	49	3	allyl(1‐benzhydryl‐3‐(2,6‐diisopropyl	allyl(1‐benzhydryl‐3‐(2,6‐diisopropyl	PROPN
eurjchem-940	49	4	phenyl)‐1,3‐dihydro‐2h‐imidazol‐2‐ylidene)palladium(ii	phenyl)‐1,3‐dihydro‐2h‐imidazol‐2‐ylidene)palladium(ii	PROPN
eurjchem-940	49	5	)	)	PUNCT
eurjchem-940	49	6	chloride	chloride	NOUN
eurjchem-940	49	7	a	a	DET
eurjchem-940	49	8	flame	flame	NOUN
eurjchem-940	49	9	dried	dry	VERB
eurjchem-940	49	10	25	25	NUM
eurjchem-940	49	11	ml	ml	NOUN
eurjchem-940	49	12	round‐bottom	round‐bottom	PROPN
eurjchem-940	49	13	flask	flask	NOUN
eurjchem-940	49	14	provided	provide	VERB
eurjchem-940	49	15	with	with	ADP
eurjchem-940	49	16	a	a	DET
eurjchem-940	49	17	stirring	stir	VERB
eurjchem-940	49	18	bar	bar	NOUN
eurjchem-940	49	19	was	be	AUX
eurjchem-940	49	20	charged	charge	VERB
eurjchem-940	49	21	with	with	ADP
eurjchem-940	49	22	silver	silver	NOUN
eurjchem-940	49	23	(	(	PUNCT
eurjchem-940	49	24	i	i	NOUN
eurjchem-940	49	25	)	)	PUNCT
eurjchem-940	49	26	oxide	oxide	NOUN
eurjchem-940	49	27	(	(	PUNCT
eurjchem-940	49	28	0.368	0.368	NUM
eurjchem-940	49	29	g	g	NOUN
eurjchem-940	49	30	,	,	PUNCT
eurjchem-940	49	31	1.590	1.590	NUM
eurjchem-940	49	32	mmol	mmol	NOUN
eurjchem-940	49	33	)	)	PUNCT
eurjchem-940	49	34	and	and	CCONJ
eurjchem-940	49	35	3‐benzhydryl‐1‐(2,6‐diisopropylphenyl)‐1h‐	3‐benzhydryl‐1‐(2,6‐diisopropylphenyl)‐1h‐	PROPN
eurjchem-940	49	36	imidazol‐3‐ium	imidazol‐3‐ium	NOUN
eurjchem-940	49	37	chloride	chloride	NOUN
eurjchem-940	49	38	(	(	PUNCT
eurjchem-940	49	39	1.202	1.202	NUM
eurjchem-940	49	40	g	g	NOUN
eurjchem-940	49	41	,	,	PUNCT
eurjchem-940	49	42	2.79	2.79	NUM
eurjchem-940	49	43	mmol	mmol	NOUN
eurjchem-940	49	44	)	)	PUNCT
eurjchem-940	49	45	,	,	PUNCT
eurjchem-940	49	46	capped	cap	VERB
eurjchem-940	49	47	with	with	ADP
eurjchem-940	49	48	a	a	DET
eurjchem-940	49	49	rubber	rubber	NOUN
eurjchem-940	49	50	septum	septum	NOUN
eurjchem-940	49	51	and	and	CCONJ
eurjchem-940	49	52	reflushed	reflushe	VERB
eurjchem-940	49	53	with	with	ADP
eurjchem-940	49	54	argon	argon	NOUN
eurjchem-940	49	55	.	.	PUNCT
eurjchem-940	50	1	then	then	ADV
eurjchem-940	50	2	,	,	PUNCT
eurjchem-940	50	3	dichloro	dichloro	PROPN
eurjchem-940	50	4	methane	methane	NOUN
eurjchem-940	50	5	(	(	PUNCT
eurjchem-940	50	6	15	15	NUM
eurjchem-940	50	7	ml	ml	NOUN
eurjchem-940	50	8	)	)	PUNCT
eurjchem-940	50	9	freshly	freshly	ADV
eurjchem-940	50	10	distilled	distil	VERB
eurjchem-940	50	11	from	from	ADP
eurjchem-940	50	12	cah2	cah2	PROPN
eurjchem-940	50	13	under	under	ADP
eurjchem-940	50	14	nitrogen	nitrogen	NOUN
eurjchem-940	50	15	was	be	AUX
eurjchem-940	50	16	added	add	VERB
eurjchem-940	50	17	and	and	CCONJ
eurjchem-940	50	18	the	the	DET
eurjchem-940	50	19	mixture	mixture	NOUN
eurjchem-940	50	20	was	be	AUX
eurjchem-940	50	21	stirred	stir	VERB
eurjchem-940	50	22	under	under	ADP
eurjchem-940	50	23	argon	argon	NOUN
eurjchem-940	50	24	for	for	ADP
eurjchem-940	50	25	12	12	NUM
eurjchem-940	50	26	h.	h.	NOUN
eurjchem-940	50	27	afterwards	afterwards	ADV
eurjchem-940	50	28	,	,	PUNCT
eurjchem-940	50	29	the	the	DET
eurjchem-940	50	30	reaction	reaction	NOUN
eurjchem-940	50	31	mixture	mixture	NOUN
eurjchem-940	50	32	was	be	AUX
eurjchem-940	50	33	filtered	filter	VERB
eurjchem-940	50	34	through	through	ADP
eurjchem-940	50	35	a	a	DET
eurjchem-940	50	36	celite	celite	ADJ
eurjchem-940	50	37	pad	pad	NOUN
eurjchem-940	50	38	and	and	CCONJ
eurjchem-940	50	39	the	the	DET
eurjchem-940	50	40	solution	solution	NOUN
eurjchem-940	50	41	concentrated	concentrate	VERB
eurjchem-940	50	42	under	under	ADP
eurjchem-940	50	43	vacuum	vacuum	NOUN
eurjchem-940	50	44	.	.	PUNCT
eurjchem-940	51	1	the	the	DET
eurjchem-940	51	2	crude	crude	NOUN
eurjchem-940	51	3	was	be	AUX
eurjchem-940	51	4	mixed	mix	VERB
eurjchem-940	51	5	with	with	ADP
eurjchem-940	51	6	pentane	pentane	NOUN
eurjchem-940	51	7	and	and	CCONJ
eurjchem-940	51	8	the	the	DET
eurjchem-940	51	9	solid	solid	ADJ
eurjchem-940	51	10	crushed	crushed	NOUN
eurjchem-940	51	11	,	,	PUNCT
eurjchem-940	51	12	decanting	decant	VERB
eurjchem-940	51	13	the	the	DET
eurjchem-940	51	14	pentane	pentane	NOUN
eurjchem-940	51	15	solution	solution	NOUN
eurjchem-940	51	16	,	,	PUNCT
eurjchem-940	51	17	repeating	repeat	VERB
eurjchem-940	51	18	this	this	DET
eurjchem-940	51	19	procedure	procedure	NOUN
eurjchem-940	51	20	3	3	NUM
eurjchem-940	51	21	times	time	NOUN
eurjchem-940	51	22	.	.	PUNCT
eurjchem-940	52	1	the	the	DET
eurjchem-940	52	2	solid	solid	ADJ
eurjchem-940	52	3	was	be	AUX
eurjchem-940	52	4	dried	dry	VERB
eurjchem-940	52	5	under	under	ADP
eurjchem-940	52	6	high	high	ADJ
eurjchem-940	52	7	vacuum	vacuum	NOUN
eurjchem-940	52	8	and	and	CCONJ
eurjchem-940	52	9	used	use	VERB
eurjchem-940	52	10	for	for	ADP
eurjchem-940	52	11	the	the	DET
eurjchem-940	52	12	next	next	ADJ
eurjchem-940	52	13	reaction	reaction	NOUN
eurjchem-940	52	14	without	without	ADP
eurjchem-940	52	15	isolation	isolation	NOUN
eurjchem-940	52	16	.	.	PUNCT
eurjchem-940	53	1	in	in	ADP
eurjchem-940	53	2	a	a	DET
eurjchem-940	53	3	glove	glove	NOUN
eurjchem-940	53	4	box	box	NOUN
eurjchem-940	53	5	,	,	PUNCT
eurjchem-940	53	6	a	a	DET
eurjchem-940	53	7	flame	flame	NOUN
eurjchem-940	53	8	dried	dry	VERB
eurjchem-940	53	9	25	25	NUM
eurjchem-940	53	10	ml	ml	NOUN
eurjchem-940	53	11	round	round	ADJ
eurjchem-940	53	12	bottom	bottom	ADJ
eurjchem-940	53	13	flask	flask	NOUN
eurjchem-940	53	14	was	be	AUX
eurjchem-940	53	15	charged	charge	VERB
eurjchem-940	53	16	with	with	ADP
eurjchem-940	53	17	mono((3‐benzhydryl‐1‐(2,6‐diisopropylphenyl)‐	mono((3‐benzhydryl‐1‐(2,6‐diisopropylphenyl)‐	NOUN
eurjchem-940	53	18	1h‐imidazol‐3‐ium‐2‐yl)silver(i	1h‐imidazol‐3‐ium‐2‐yl)silver(i	NUM
eurjchem-940	53	19	)	)	PUNCT
eurjchem-940	53	20	)	)	PUNCT
eurjchem-940	53	21	chloride	chloride	NOUN
eurjchem-940	53	22	(	(	PUNCT
eurjchem-940	53	23	1.300	1.300	NUM
eurjchem-940	53	24	g	g	NOUN
eurjchem-940	53	25	,	,	PUNCT
eurjchem-940	53	26	2.417	2.417	NUM
eurjchem-940	53	27	mmol	mmol	NOUN
eurjchem-940	53	28	)	)	PUNCT
eurjchem-940	53	29	and	and	CCONJ
eurjchem-940	53	30	allylpalladium	allylpalladium	ADJ
eurjchem-940	53	31	chloride	chloride	NOUN
eurjchem-940	53	32	dimer	dimer	NOUN
eurjchem-940	53	33	(	(	PUNCT
eurjchem-940	53	34	0.442	0.442	NUM
eurjchem-940	53	35	g	g	NOUN
eurjchem-940	53	36	,	,	PUNCT
eurjchem-940	53	37	1.208	1.208	NUM
eurjchem-940	53	38	mmol	mmol	NOUN
eurjchem-940	53	39	)	)	PUNCT
eurjchem-940	53	40	,	,	PUNCT
eurjchem-940	53	41	and	and	CCONJ
eurjchem-940	53	42	then	then	ADV
eurjchem-940	53	43	dichloromethane	dichloromethane	VERB
eurjchem-940	53	44	(	(	PUNCT
eurjchem-940	53	45	16	16	NUM
eurjchem-940	53	46	ml	ml	NOUN
eurjchem-940	53	47	)	)	PUNCT
eurjchem-940	53	48	was	be	AUX
eurjchem-940	53	49	added	add	VERB
eurjchem-940	53	50	.	.	PUNCT
eurjchem-940	54	1	the	the	DET
eurjchem-940	54	2	reaction	reaction	NOUN
eurjchem-940	54	3	mixture	mixture	NOUN
eurjchem-940	54	4	was	be	AUX
eurjchem-940	54	5	allowed	allow	VERB
eurjchem-940	54	6	to	to	PART
eurjchem-940	54	7	react	react	VERB
eurjchem-940	54	8	for	for	ADP
eurjchem-940	54	9	2	2	NUM
eurjchem-940	54	10	h	h	NOUN
eurjchem-940	54	11	at	at	ADP
eurjchem-940	54	12	rt	rt	PROPN
eurjchem-940	54	13	.	.	PROPN
eurjchem-940	55	1	afterwards	afterwards	ADV
eurjchem-940	55	2	,	,	PUNCT
eurjchem-940	55	3	the	the	DET
eurjchem-940	55	4	reaction	reaction	NOUN
eurjchem-940	55	5	was	be	AUX
eurjchem-940	55	6	filtered	filter	VERB
eurjchem-940	55	7	off	off	ADP
eurjchem-940	55	8	through	through	ADP
eurjchem-940	55	9	a	a	DET
eurjchem-940	55	10	pad	pad	NOUN
eurjchem-940	55	11	of	of	ADP
eurjchem-940	55	12	celite	celite	ADJ
eurjchem-940	55	13	,	,	PUNCT
eurjchem-940	55	14	the	the	DET
eurjchem-940	55	15	filtrate	filtrate	NOUN
eurjchem-940	55	16	concentrated	concentrate	VERB
eurjchem-940	55	17	under	under	ADP
eurjchem-940	55	18	vacuum	vacuum	NOUN
eurjchem-940	55	19	.	.	PUNCT
eurjchem-940	56	1	the	the	DET
eurjchem-940	56	2	crude	crude	NOUN
eurjchem-940	56	3	was	be	AUX
eurjchem-940	56	4	mixed	mix	VERB
eurjchem-940	56	5	with	with	ADP
eurjchem-940	56	6	pentane	pentane	NOUN
eurjchem-940	56	7	and	and	CCONJ
eurjchem-940	56	8	the	the	DET
eurjchem-940	56	9	solid	solid	ADJ
eurjchem-940	56	10	crushed	crushed	NOUN
eurjchem-940	56	11	,	,	PUNCT
eurjchem-940	56	12	decanting	decant	VERB
eurjchem-940	56	13	the	the	DET
eurjchem-940	56	14	pentane	pentane	NOUN
eurjchem-940	56	15	solution	solution	NOUN
eurjchem-940	56	16	,	,	PUNCT
eurjchem-940	56	17	repeating	repeat	VERB
eurjchem-940	56	18	this	this	DET
eurjchem-940	56	19	procedure	procedure	NOUN
eurjchem-940	56	20	3	3	NUM
eurjchem-940	56	21	times	time	NOUN
eurjchem-940	56	22	and	and	CCONJ
eurjchem-940	56	23	purified	purify	VERB
eurjchem-940	56	24	by	by	ADP
eurjchem-940	56	25	column	column	NOUN
eurjchem-940	56	26	chromatography	chromatography	NOUN
eurjchem-940	56	27	using	use	VERB
eurjchem-940	56	28	a	a	DET
eurjchem-940	56	29	mixture	mixture	NOUN
eurjchem-940	56	30	dichloromethane	dichloromethane	NOUN
eurjchem-940	56	31	:	:	PUNCT
eurjchem-940	56	32	acetone	acetone	NOUN
eurjchem-940	56	33	(	(	PUNCT
eurjchem-940	56	34	99:1	99:1	NUM
eurjchem-940	56	35	)	)	PUNCT
eurjchem-940	56	36	.	.	PUNCT
eurjchem-940	57	1	yield	yield	NOUN
eurjchem-940	57	2	:	:	PUNCT
eurjchem-940	57	3	1.367	1.367	NUM
eurjchem-940	57	4	g	g	NOUN
eurjchem-940	57	5	,	,	PUNCT
eurjchem-940	57	6	83	83	NUM
eurjchem-940	57	7	%	%	NOUN
eurjchem-940	57	8	overall	overall	ADJ
eurjchem-940	57	9	yield	yield	NOUN
eurjchem-940	57	10	from	from	ADP
eurjchem-940	57	11	the	the	DET
eurjchem-940	57	12	two	two	NUM
eurjchem-940	57	13	steps	step	NOUN
eurjchem-940	57	14	.	.	PUNCT
eurjchem-940	58	1	color	color	NOUN
eurjchem-940	58	2	:	:	PUNCT
eurjchem-940	58	3	pale	pale	ADJ
eurjchem-940	58	4	yellow	yellow	ADJ
eurjchem-940	58	5	solid	solid	ADJ
eurjchem-940	58	6	.	.	PUNCT
eurjchem-940	59	1	1h	1h	NUM
eurjchem-940	59	2	nmr	nmr	NOUN
eurjchem-940	59	3	(	(	PUNCT
eurjchem-940	59	4	300	300	NUM
eurjchem-940	59	5	mhz	mhz	NOUN
eurjchem-940	59	6	,	,	PUNCT
eurjchem-940	59	7	cdcl3	cdcl3	PROPN
eurjchem-940	59	8	,	,	PUNCT
eurjchem-940	59	9	δ	δ	PROPN
eurjchem-940	59	10	,	,	PUNCT
eurjchem-940	59	11	ppm	ppm	NOUN
eurjchem-940	59	12	):	):	PUNCT
eurjchem-940	59	13	7.93	7.93	NUM
eurjchem-940	59	14	(	(	PUNCT
eurjchem-940	59	15	s	s	PROPN
eurjchem-940	59	16	,	,	PUNCT
eurjchem-940	59	17	1h	1h	NUM
eurjchem-940	59	18	,	,	PUNCT
eurjchem-940	59	19	ar‐ch‐ar	ar‐ch‐ar	NOUN
eurjchem-940	59	20	)	)	PUNCT
eurjchem-940	59	21	,	,	PUNCT
eurjchem-940	59	22	7.17‐7.41	7.17‐7.41	NUM
eurjchem-940	59	23	(	(	PUNCT
eurjchem-940	59	24	m	m	PROPN
eurjchem-940	59	25	,	,	PUNCT
eurjchem-940	59	26	13h	13h	NOUN
eurjchem-940	59	27	,	,	PUNCT
eurjchem-940	59	28	ar‐h	ar‐h	PROPN
eurjchem-940	59	29	)	)	PUNCT
eurjchem-940	59	30	,	,	PUNCT
eurjchem-940	59	31	6.92	6.92	NUM
eurjchem-940	59	32	(	(	PUNCT
eurjchem-940	59	33	d	d	PROPN
eurjchem-940	59	34	,	,	PUNCT
eurjchem-940	59	35	1h	1h	NUM
eurjchem-940	59	36	,	,	PUNCT
eurjchem-940	59	37	j	j	PROPN
eurjchem-940	59	38	=	=	SYM
eurjchem-940	59	39	1.8	1.8	NUM
eurjchem-940	59	40	hz	hz	NOUN
eurjchem-940	59	41	,	,	PUNCT
eurjchem-940	59	42	c4‐h	c4‐h	NOUN
eurjchem-940	59	43	imidazol‐3‐ium	imidazol‐3‐ium	NOUN
eurjchem-940	59	44	)	)	PUNCT
eurjchem-940	59	45	,	,	PUNCT
eurjchem-940	59	46	6.82	6.82	NUM
eurjchem-940	59	47	(	(	PUNCT
eurjchem-940	59	48	d	d	PROPN
eurjchem-940	59	49	,	,	PUNCT
eurjchem-940	59	50	1h	1h	NUM
eurjchem-940	59	51	,	,	PUNCT
eurjchem-940	59	52	j	j	PROPN
eurjchem-940	59	53	=	=	SYM
eurjchem-940	59	54	1.8	1.8	NUM
eurjchem-940	59	55	hz	hz	VERB
eurjchem-940	59	56	,	,	PUNCT
eurjchem-940	59	57	c5‐h	c5‐h	PROPN
eurjchem-940	59	58	imidazol‐	imidazol‐	X
eurjchem-940	59	59	3‐ium	3‐ium	NUM
eurjchem-940	59	60	)	)	PUNCT
eurjchem-940	59	61	,	,	PUNCT
eurjchem-940	59	62	4.6	4.6	NUM
eurjchem-940	59	63	(	(	PUNCT
eurjchem-940	59	64	dddd	dddd	PROPN
eurjchem-940	59	65	,	,	PUNCT
eurjchem-940	59	66	1h	1h	NUM
eurjchem-940	59	67	,	,	PUNCT
eurjchem-940	59	68	j1=13.6	j1=13.6	PROPN
eurjchem-940	59	69	hz	hz	PROPN
eurjchem-940	59	70	,	,	PUNCT
eurjchem-940	59	71	j2	j2	PROPN
eurjchem-940	59	72	=	=	PROPN
eurjchem-940	59	73	12.3	12.3	NUM
eurjchem-940	59	74	hz	hz	NOUN
eurjchem-940	59	75	,	,	PUNCT
eurjchem-940	59	76	j3	j3	PROPN
eurjchem-940	59	77	=	=	PROPN
eurjchem-940	59	78	7.5	7.5	NUM
eurjchem-940	59	79	hz	hz	ADJ
eurjchem-940	59	80	,	,	PUNCT
eurjchem-940	59	81	j4	j4	PROPN
eurjchem-940	59	82	=	=	PROPN
eurjchem-940	59	83	6.9	6.9	NUM
eurjchem-940	59	84	hz	hz	NOUN
eurjchem-940	59	85	,	,	PUNCT
eurjchem-940	59	86	ch2‐ch‐ch2	ch2‐ch‐ch2	PROPN
eurjchem-940	59	87	)	)	PUNCT
eurjchem-940	59	88	,	,	PUNCT
eurjchem-940	59	89	3.98	3.98	NUM
eurjchem-940	59	90	(	(	PUNCT
eurjchem-940	59	91	dd	dd	NOUN
eurjchem-940	59	92	,	,	PUNCT
eurjchem-940	59	93	1h	1h	NUM
eurjchem-940	59	94	,	,	PUNCT
eurjchem-940	59	95	j	j	PROPN
eurjchem-940	59	96	=	=	SYM
eurjchem-940	59	97	7.5	7.5	NUM
eurjchem-940	59	98	,	,	PUNCT
eurjchem-940	59	99	7.2	7.2	NUM
eurjchem-940	59	100	hz	hz	NOUN
eurjchem-940	59	101	,	,	PUNCT
eurjchem-940	59	102	ch2‐ch‐ch2	ch2‐ch‐ch2	PROPN
eurjchem-940	59	103	)	)	PUNCT
eurjchem-940	59	104	,	,	PUNCT
eurjchem-940	59	105	2.95‐	2.95‐	NUM
eurjchem-940	59	106	3.04	3.04	NUM
eurjchem-940	59	107	(	(	PUNCT
eurjchem-940	59	108	m	m	PROPN
eurjchem-940	59	109	,	,	PUNCT
eurjchem-940	59	110	1h	1h	NUM
eurjchem-940	59	111	,	,	PUNCT
eurjchem-940	59	112	ch3‐ch‐ch3	ch3‐ch‐ch3	PROPN
eurjchem-940	59	113	)	)	PUNCT
eurjchem-940	59	114	,	,	PUNCT
eurjchem-940	59	115	2.79	2.79	NUM
eurjchem-940	59	116	(	(	PUNCT
eurjchem-940	59	117	d	d	PROPN
eurjchem-940	59	118	,	,	PUNCT
eurjchem-940	59	119	1h	1h	NUM
eurjchem-940	59	120	,	,	PUNCT
eurjchem-940	59	121	j	j	PROPN
eurjchem-940	59	122	=	=	SYM
eurjchem-940	59	123	13.6	13.6	NUM
eurjchem-940	59	124	hz	hz	VERB
eurjchem-940	59	125	,	,	PUNCT
eurjchem-940	59	126	ch2‐	ch2‐	NOUN
eurjchem-940	59	127	ch‐ch2	ch‐ch2	NOUN
eurjchem-940	59	128	)	)	PUNCT
eurjchem-940	59	129	,	,	PUNCT
eurjchem-940	59	130	2.61	2.61	NUM
eurjchem-940	59	131	(	(	PUNCT
eurjchem-940	59	132	m	m	PROPN
eurjchem-940	59	133	,	,	PUNCT
eurjchem-940	59	134	1h	1h	NUM
eurjchem-940	59	135	,	,	PUNCT
eurjchem-940	59	136	ch3‐ch‐ch3	ch3‐ch‐ch3	PROPN
eurjchem-940	59	137	)	)	PUNCT
eurjchem-940	59	138	,	,	PUNCT
eurjchem-940	59	139	2.54	2.54	NUM
eurjchem-940	59	140	(	(	PUNCT
eurjchem-940	59	141	d	d	PROPN
eurjchem-940	59	142	,	,	PUNCT
eurjchem-940	59	143	1h	1h	NUM
eurjchem-940	59	144	,	,	PUNCT
eurjchem-940	59	145	j	j	PROPN
eurjchem-940	59	146	=	=	PROPN
eurjchem-940	59	147	15.6	15.6	NUM
eurjchem-940	59	148	hz	hz	VERB
eurjchem-940	59	149	,	,	PUNCT
eurjchem-940	59	150	ch2‐ch‐ch2	ch2‐ch‐ch2	PROPN
eurjchem-940	59	151	)	)	PUNCT
eurjchem-940	59	152	,	,	PUNCT
eurjchem-940	59	153	1.33	1.33	NUM
eurjchem-940	59	154	(	(	PUNCT
eurjchem-940	59	155	d	d	PROPN
eurjchem-940	59	156	,	,	PUNCT
eurjchem-940	59	157	3h	3h	NUM
eurjchem-940	59	158	,	,	PUNCT
eurjchem-940	59	159	j	j	PROPN
eurjchem-940	60	1	=	=	PROPN
eurjchem-940	60	2	6.7	6.7	NUM
eurjchem-940	60	3	hz	hz	NOUN
eurjchem-940	60	4	,	,	PUNCT
eurjchem-940	60	5	ch3‐ch‐ch3	ch3‐ch‐ch3	ADJ
eurjchem-940	60	6	)	)	PUNCT
eurjchem-940	60	7	,	,	PUNCT
eurjchem-940	60	8	1.29	1.29	NUM
eurjchem-940	60	9	(	(	PUNCT
eurjchem-940	60	10	d	d	PROPN
eurjchem-940	60	11	,	,	PUNCT
eurjchem-940	60	12	1h	1h	NUM
eurjchem-940	60	13	,	,	PUNCT
eurjchem-940	60	14	j	j	PROPN
eurjchem-940	60	15	=	=	PROPN
eurjchem-940	60	16	12.4	12.4	NUM
eurjchem-940	60	17	hz	hz	VERB
eurjchem-940	60	18	,	,	PUNCT
eurjchem-940	60	19	ch2‐ch‐ch2	ch2‐ch‐ch2	PROPN
eurjchem-940	60	20	)	)	PUNCT
eurjchem-940	60	21	,	,	PUNCT
eurjchem-940	60	22	1.22	1.22	NUM
eurjchem-940	60	23	(	(	PUNCT
eurjchem-940	60	24	d	d	PROPN
eurjchem-940	60	25	,	,	PUNCT
eurjchem-940	60	26	3h	3h	NUM
eurjchem-940	60	27	,	,	PUNCT
eurjchem-940	60	28	j	j	PROPN
eurjchem-940	61	1	=	=	PROPN
eurjchem-940	61	2	6.7	6.7	NUM
eurjchem-940	61	3	hz	hz	NOUN
eurjchem-940	61	4	,	,	PUNCT
eurjchem-940	61	5	ch3‐ch‐ch3	ch3‐ch‐ch3	ADJ
eurjchem-940	61	6	)	)	PUNCT
eurjchem-940	61	7	,	,	PUNCT
eurjchem-940	61	8	1.08	1.08	NUM
eurjchem-940	61	9	(	(	PUNCT
eurjchem-940	61	10	dd	dd	PROPN
eurjchem-940	61	11	,	,	PUNCT
eurjchem-940	61	12	6h	6h	NUM
eurjchem-940	61	13	,	,	PUNCT
eurjchem-940	61	14	j	j	PROPN
eurjchem-940	61	15	=	=	PROPN
eurjchem-940	61	16	7.7	7.7	NUM
eurjchem-940	61	17	,	,	PUNCT
eurjchem-940	61	18	7.3	7.3	NUM
eurjchem-940	61	19	hz	hz	NOUN
eurjchem-940	61	20	,	,	PUNCT
eurjchem-940	61	21	ch3‐ch‐ch3	ch3‐ch‐ch3	ADJ
eurjchem-940	61	22	)	)	PUNCT
eurjchem-940	61	23	.	.	PUNCT
eurjchem-940	62	1	13c	13c	NOUN
eurjchem-940	62	2	nmr	nmr	NOUN
eurjchem-940	62	3	(	(	PUNCT
eurjchem-940	62	4	75	75	NUM
eurjchem-940	62	5	mhz	mhz	NOUN
eurjchem-940	62	6	,	,	PUNCT
eurjchem-940	62	7	cdcl3	cdcl3	PROPN
eurjchem-940	62	8	,	,	PUNCT
eurjchem-940	62	9	δ	δ	PROPN
eurjchem-940	62	10	,	,	PUNCT
eurjchem-940	62	11	ppm	ppm	NOUN
eurjchem-940	62	12	):	):	PUNCT
eurjchem-940	62	13	185.5	185.5	NUM
eurjchem-940	62	14	,	,	PUNCT
eurjchem-940	62	15	146.6	146.6	NUM
eurjchem-940	62	16	,	,	PUNCT
eurjchem-940	62	17	145.8	145.8	NUM
eurjchem-940	62	18	,	,	PUNCT
eurjchem-940	62	19	140.3	140.3	NUM
eurjchem-940	62	20	,	,	PUNCT
eurjchem-940	62	21	139.3	139.3	NUM
eurjchem-940	62	22	,	,	PUNCT
eurjchem-940	62	23	135.9	135.9	NUM
eurjchem-940	62	24	,	,	PUNCT
eurjchem-940	62	25	136.0	136.0	NUM
eurjchem-940	62	26	,	,	PUNCT
eurjchem-940	62	27	129.8	129.8	NUM
eurjchem-940	62	28	,	,	PUNCT
eurjchem-940	62	29	129.4	129.4	NUM
eurjchem-940	62	30	,	,	PUNCT
eurjchem-940	62	31	128.7	128.7	NUM
eurjchem-940	62	32	,	,	PUNCT
eurjchem-940	62	33	128.5	128.5	NUM
eurjchem-940	62	34	,	,	PUNCT
eurjchem-940	62	35	128.2	128.2	NUM
eurjchem-940	62	36	,	,	PUNCT
eurjchem-940	62	37	127.8	127.8	NUM
eurjchem-940	62	38	,	,	PUNCT
eurjchem-940	62	39	124.0	124.0	NUM
eurjchem-940	62	40	,	,	PUNCT
eurjchem-940	62	41	123.5	123.5	NUM
eurjchem-940	62	42	,	,	PUNCT
eurjchem-940	62	43	123.1	123.1	NUM
eurjchem-940	62	44	,	,	PUNCT
eurjchem-940	62	45	120.4	120.4	NUM
eurjchem-940	62	46	,	,	PUNCT
eurjchem-940	62	47	114.6	114.6	NUM
eurjchem-940	62	48	,	,	PUNCT
eurjchem-940	62	49	72.4	72.4	NUM
eurjchem-940	62	50	,	,	PUNCT
eurjchem-940	62	51	67.1	67.1	NUM
eurjchem-940	62	52	,	,	PUNCT
eurjchem-940	62	53	48.7	48.7	NUM
eurjchem-940	62	54	,	,	PUNCT
eurjchem-940	62	55	28.3	28.3	NUM
eurjchem-940	62	56	,	,	PUNCT
eurjchem-940	62	57	26.2	26.2	NUM
eurjchem-940	62	58	,	,	PUNCT
eurjchem-940	62	59	26.0	26.0	NUM
eurjchem-940	62	60	,	,	PUNCT
eurjchem-940	62	61	23.4	23.4	NUM
eurjchem-940	62	62	,	,	PUNCT
eurjchem-940	62	63	22.9	22.9	NUM
eurjchem-940	62	64	.	.	PUNCT
eurjchem-940	63	1	hrms	hrm	NOUN
eurjchem-940	63	2	(	(	PUNCT
eurjchem-940	63	3	tof	tof	PROPN
eurjchem-940	63	4	ms	ms	PROPN
eurjchem-940	63	5	ei+	ei+	PROPN
eurjchem-940	63	6	):	):	PUNCT
eurjchem-940	63	7	calculated	calculate	VERB
eurjchem-940	63	8	for	for	ADP
eurjchem-940	63	9	c31h35n2pd104	c31h35n2pd104	PROPN
eurjchem-940	63	10	539.1841	539.1841	NUM
eurjchem-940	63	11	,	,	PUNCT
eurjchem-940	63	12	found	find	VERB
eurjchem-940	63	13	539.1888	539.1888	NUM
eurjchem-940	63	14	.	.	NOUN
eurjchem-940	63	15	2.2.3	2.2.3	NUM
eurjchem-940	63	16	.	.	PUNCT
eurjchem-940	64	1	general	general	ADJ
eurjchem-940	64	2	procedure	procedure	NOUN
eurjchem-940	64	3	for	for	ADP
eurjchem-940	64	4	the	the	DET
eurjchem-940	64	5	suzuki‐miyaura	suzuki‐miyaura	PROPN
eurjchem-940	64	6	cross‐	cross‐	NOUN
eurjchem-940	64	7	coupling	coupling	NOUN
eurjchem-940	64	8	of	of	ADP
eurjchem-940	64	9	aryl	aryl	NOUN
eurjchem-940	64	10	halides	halide	NOUN
eurjchem-940	64	11	in	in	ADP
eurjchem-940	64	12	a	a	DET
eurjchem-940	64	13	glove	glove	NOUN
eurjchem-940	64	14	box	box	NOUN
eurjchem-940	64	15	a	a	DET
eurjchem-940	64	16	dry	dry	ADJ
eurjchem-940	64	17	vial	vial	NOUN
eurjchem-940	64	18	(	(	PUNCT
eurjchem-940	64	19	10	10	NUM
eurjchem-940	64	20	ml	ml	NOUN
eurjchem-940	64	21	)	)	PUNCT
eurjchem-940	64	22	provided	provide	VERB
eurjchem-940	64	23	with	with	ADP
eurjchem-940	64	24	a	a	DET
eurjchem-940	64	25	stirring	stir	VERB
eurjchem-940	64	26	bar	bar	NOUN
eurjchem-940	64	27	was	be	AUX
eurjchem-940	64	28	charged	charge	VERB
eurjchem-940	64	29	with	with	ADP
eurjchem-940	64	30	kotbu	kotbu	NOUN
eurjchem-940	64	31	(	(	PUNCT
eurjchem-940	64	32	1.1	1.1	NUM
eurjchem-940	64	33	mmol	mmol	NOUN
eurjchem-940	64	34	)	)	PUNCT
eurjchem-940	64	35	,	,	PUNCT
eurjchem-940	64	36	k3po4	k3po4	NOUN
eurjchem-940	64	37	(	(	PUNCT
eurjchem-940	64	38	1.5	1.5	NUM
eurjchem-940	64	39	mmol	mmol	NOUN
eurjchem-940	64	40	)	)	PUNCT
eurjchem-940	64	41	,	,	PUNCT
eurjchem-940	64	42	the	the	DET
eurjchem-940	64	43	aryl	aryl	NOUN
eurjchem-940	64	44	halide	halide	NOUN
eurjchem-940	64	45	(	(	PUNCT
eurjchem-940	64	46	1	1	NUM
eurjchem-940	64	47	mmol	mmol	NOUN
eurjchem-940	64	48	)	)	PUNCT
eurjchem-940	64	49	,	,	PUNCT
eurjchem-940	64	50	2.5	2.5	NUM
eurjchem-940	64	51	ml	ml	NOUN
eurjchem-940	64	52	of	of	ADP
eurjchem-940	64	53	dry	dry	ADJ
eurjchem-940	64	54	isopropyl	isopropyl	NOUN
eurjchem-940	64	55	alcohol	alcohol	NOUN
eurjchem-940	64	56	,	,	PUNCT
eurjchem-940	64	57	and	and	CCONJ
eurjchem-940	64	58	0.5	0.5	NUM
eurjchem-940	64	59	ml	ml	NOUN
eurjchem-940	64	60	of	of	ADP
eurjchem-940	64	61	a	a	DET
eurjchem-940	64	62	stock	stock	NOUN
eurjchem-940	64	63	solution	solution	NOUN
eurjchem-940	64	64	of	of	ADP
eurjchem-940	64	65	the	the	DET
eurjchem-940	64	66	catalyst	catalyst	NOUN
eurjchem-940	64	67	in	in	ADP
eurjchem-940	64	68	isopropanol	isopropanol	NOUN
eurjchem-940	64	69	(	(	PUNCT
eurjchem-940	64	70	1	1	NUM
eurjchem-940	64	71	mol	mol	ADP
eurjchem-940	64	72	%	%	NOUN
eurjchem-940	64	73	)	)	PUNCT
eurjchem-940	64	74	.	.	PUNCT
eurjchem-940	65	1	the	the	DET
eurjchem-940	65	2	mixture	mixture	NOUN
eurjchem-940	65	3	was	be	AUX
eurjchem-940	65	4	capped	cap	VERB
eurjchem-940	65	5	and	and	CCONJ
eurjchem-940	65	6	heated	heat	VERB
eurjchem-940	65	7	at	at	ADP
eurjchem-940	65	8	50	50	NUM
eurjchem-940	65	9	°	°	NOUN
eurjchem-940	65	10	c	c	NOUN
eurjchem-940	65	11	for	for	ADP
eurjchem-940	65	12	2	2	NUM
eurjchem-940	65	13	h.	h.	NOUN
eurjchem-940	65	14	afterwards	afterwards	ADV
eurjchem-940	65	15	,	,	PUNCT
eurjchem-940	65	16	the	the	DET
eurjchem-940	65	17	reaction	reaction	NOUN
eurjchem-940	65	18	solution	solution	NOUN
eurjchem-940	65	19	was	be	AUX
eurjchem-940	65	20	cooled	cool	VERB
eurjchem-940	65	21	down	down	ADP
eurjchem-940	65	22	to	to	ADP
eurjchem-940	65	23	ambient	ambient	ADJ
eurjchem-940	65	24	temperature	temperature	NOUN
eurjchem-940	65	25	,	,	PUNCT
eurjchem-940	65	26	2	2	NUM
eurjchem-940	65	27	ml	ml	NOUN
eurjchem-940	65	28	of	of	ADP
eurjchem-940	65	29	water	water	NOUN
eurjchem-940	65	30	were	be	AUX
eurjchem-940	65	31	added	add	VERB
eurjchem-940	65	32	,	,	PUNCT
eurjchem-940	65	33	the	the	DET
eurjchem-940	65	34	mixture	mixture	NOUN
eurjchem-940	65	35	was	be	AUX
eurjchem-940	65	36	extracted	extract	VERB
eurjchem-940	65	37	with	with	ADP
eurjchem-940	65	38	ethyl	ethyl	PROPN
eurjchem-940	65	39	acetate	acetate	NOUN
eurjchem-940	65	40	,	,	PUNCT
eurjchem-940	65	41	3	3	NUM
eurjchem-940	65	42	times	time	NOUN
eurjchem-940	65	43	x	x	SYM
eurjchem-940	65	44	2	2	NUM
eurjchem-940	65	45	ml	ml	NOUN
eurjchem-940	65	46	.	.	PUNCT
eurjchem-940	66	1	the	the	DET
eurjchem-940	66	2	organic	organic	ADJ
eurjchem-940	66	3	solution	solution	NOUN
eurjchem-940	66	4	was	be	AUX
eurjchem-940	66	5	dried	dry	VERB
eurjchem-940	66	6	with	with	ADP
eurjchem-940	66	7	sodium	sodium	NOUN
eurjchem-940	66	8	sulfate	sulfate	NOUN
eurjchem-940	66	9	,	,	PUNCT
eurjchem-940	66	10	concentrated	concentrate	VERB
eurjchem-940	66	11	in	in	ADP
eurjchem-940	66	12	vacuo	vacuo	NOUN
eurjchem-940	66	13	and	and	CCONJ
eurjchem-940	66	14	purified	purify	VERB
eurjchem-940	66	15	by	by	ADP
eurjchem-940	66	16	column	column	NOUN
eurjchem-940	66	17	chromatography	chromatography	NOUN
eurjchem-940	66	18	using	use	VERB
eurjchem-940	66	19	a	a	DET
eurjchem-940	66	20	mixture	mixture	NOUN
eurjchem-940	66	21	of	of	ADP
eurjchem-940	66	22	0	0	NUM
eurjchem-940	66	23	to	to	PART
eurjchem-940	66	24	20	20	NUM
eurjchem-940	66	25	%	%	NOUN
eurjchem-940	66	26	of	of	ADP
eurjchem-940	66	27	ethyl	ethyl	PROPN
eurjchem-940	66	28	acetate	acetate	NOUN
eurjchem-940	66	29	and	and	CCONJ
eurjchem-940	66	30	hexane	hexane	NOUN
eurjchem-940	66	31	.	.	PUNCT
eurjchem-940	67	1	1‐([1,1'‐biphenyl]‐3‐yl)ethan‐1‐one	1‐([1,1'‐biphenyl]‐3‐yl)ethan‐1‐one	NUM
eurjchem-940	67	2	:	:	PUNCT
eurjchem-940	67	3	yield	yield	NOUN
eurjchem-940	67	4	:	:	PUNCT
eurjchem-940	67	5	93.5	93.5	NUM
eurjchem-940	67	6	%	%	NOUN
eurjchem-940	67	7	.	.	PUNCT
eurjchem-940	68	1	1h	1h	NUM
eurjchem-940	68	2	nmr	nmr	NOUN
eurjchem-940	68	3	(	(	PUNCT
eurjchem-940	68	4	300	300	NUM
eurjchem-940	68	5	mhz	mhz	NOUN
eurjchem-940	68	6	,	,	PUNCT
eurjchem-940	68	7	cdcl3	cdcl3	PROPN
eurjchem-940	68	8	,	,	PUNCT
eurjchem-940	68	9	δ	δ	PROPN
eurjchem-940	68	10	,	,	PUNCT
eurjchem-940	68	11	ppm	ppm	NOUN
eurjchem-940	68	12	):	):	PUNCT
eurjchem-940	68	13	8.17	8.17	NUM
eurjchem-940	68	14	(	(	PUNCT
eurjchem-940	68	15	dd	dd	PROPN
eurjchem-940	68	16	,	,	PUNCT
eurjchem-940	68	17	1h	1h	NUM
eurjchem-940	68	18	,	,	PUNCT
eurjchem-940	68	19	j	j	PROPN
eurjchem-940	68	20	=	=	SYM
eurjchem-940	68	21	1.6	1.6	NUM
eurjchem-940	68	22	,	,	PUNCT
eurjchem-940	68	23	1.3	1.3	NUM
eurjchem-940	68	24	hz	hz	NOUN
eurjchem-940	68	25	,	,	PUNCT
eurjchem-940	68	26	ar‐h	ar‐h	NOUN
eurjchem-940	68	27	)	)	PUNCT
eurjchem-940	68	28	,	,	PUNCT
eurjchem-940	68	29	7.90‐7.94	7.90‐7.94	NUM
eurjchem-940	68	30	(	(	PUNCT
eurjchem-940	68	31	m	m	PROPN
eurjchem-940	68	32	,	,	PUNCT
eurjchem-940	68	33	1h	1h	NUM
eurjchem-940	68	34	,	,	PUNCT
eurjchem-940	68	35	ar‐h	ar‐h	NOUN
eurjchem-940	68	36	)	)	PUNCT
eurjchem-940	68	37	,	,	PUNCT
eurjchem-940	68	38	7.76‐7.79	7.76‐7.79	X
eurjchem-940	68	39	(	(	PUNCT
eurjchem-940	68	40	m	m	PROPN
eurjchem-940	68	41	,	,	PUNCT
eurjchem-940	68	42	1h	1h	NUM
eurjchem-940	68	43	,	,	PUNCT
eurjchem-940	68	44	ar‐h	ar‐h	NOUN
eurjchem-940	68	45	)	)	PUNCT
eurjchem-940	68	46	,	,	PUNCT
eurjchem-940	68	47	7.59‐7.62	7.59‐7.62	NUM
eurjchem-940	68	48	(	(	PUNCT
eurjchem-940	68	49	m	m	PROPN
eurjchem-940	68	50	,	,	PUNCT
eurjchem-940	68	51	2h	2h	NUM
eurjchem-940	68	52	,	,	PUNCT
eurjchem-940	68	53	ar‐h	ar‐h	NOUN
eurjchem-940	68	54	)	)	PUNCT
eurjchem-940	68	55	,	,	PUNCT
eurjchem-940	68	56	7.50	7.50	NUM
eurjchem-940	68	57	(	(	PUNCT
eurjchem-940	68	58	dd	dd	NOUN
eurjchem-940	68	59	,	,	PUNCT
eurjchem-940	68	60	1h	1h	NUM
eurjchem-940	68	61	,	,	PUNCT
eurjchem-940	68	62	j	j	PROPN
eurjchem-940	68	63	=	=	SYM
eurjchem-940	68	64	7.8	7.8	NUM
eurjchem-940	68	65	,	,	PUNCT
eurjchem-940	68	66	7.7	7.7	NUM
eurjchem-940	68	67	hz	hz	NOUN
eurjchem-940	68	68	,	,	PUNCT
eurjchem-940	68	69	ar‐h	ar‐h	NOUN
eurjchem-940	68	70	)	)	PUNCT
eurjchem-940	68	71	,	,	PUNCT
eurjchem-940	68	72	7.43‐7.48	7.43‐7.48	NUM
eurjchem-940	68	73	(	(	PUNCT
eurjchem-940	68	74	m	m	PROPN
eurjchem-940	68	75	,	,	PUNCT
eurjchem-940	68	76	2h	2h	NUM
eurjchem-940	68	77	,	,	PUNCT
eurjchem-940	68	78	ar‐h	ar‐h	NOUN
eurjchem-940	68	79	)	)	PUNCT
eurjchem-940	68	80	,	,	PUNCT
eurjchem-940	68	81	7.34‐7.40	7.34‐7.40	PROPN
eurjchem-940	68	82	(	(	PUNCT
eurjchem-940	68	83	m	m	PROPN
eurjchem-940	68	84	,	,	PUNCT
eurjchem-940	68	85	1h	1h	NUM
eurjchem-940	68	86	,	,	PUNCT
eurjchem-940	68	87	ar‐h	ar‐h	NOUN
eurjchem-940	68	88	)	)	PUNCT
eurjchem-940	68	89	,	,	PUNCT
eurjchem-940	68	90	2.64	2.64	NUM
eurjchem-940	68	91	(	(	PUNCT
eurjchem-940	68	92	s	s	PROPN
eurjchem-940	68	93	,	,	PUNCT
eurjchem-940	68	94	3h	3h	NUM
eurjchem-940	68	95	,	,	PUNCT
eurjchem-940	68	96	arco‐ch3	arco‐ch3	NUM
eurjchem-940	68	97	)	)	PUNCT
eurjchem-940	68	98	.	.	PUNCT
eurjchem-940	69	1	[	[	X
eurjchem-940	69	2	1,1'‐bbiphenyl]‐4‐yl(phenyl)methanone	1,1'‐bbiphenyl]‐4‐yl(phenyl)methanone	NUM
eurjchem-940	69	3	:	:	PUNCT
eurjchem-940	69	4	yield	yield	NOUN
eurjchem-940	69	5	:	:	PUNCT
eurjchem-940	69	6	95.1	95.1	NUM
eurjchem-940	69	7	%	%	NOUN
eurjchem-940	69	8	.	.	PUNCT
eurjchem-940	70	1	1h	1h	NUM
eurjchem-940	70	2	nmr	nmr	NOUN
eurjchem-940	70	3	(	(	PUNCT
eurjchem-940	70	4	300	300	NUM
eurjchem-940	70	5	mhz	mhz	NOUN
eurjchem-940	70	6	,	,	PUNCT
eurjchem-940	70	7	cdcl3	cdcl3	PROPN
eurjchem-940	70	8	,	,	PUNCT
eurjchem-940	70	9	δ	δ	PROPN
eurjchem-940	70	10	,	,	PUNCT
eurjchem-940	70	11	ppm	ppm	NUM
eurjchem-940	70	12	):	):	PUNCT
eurjchem-940	70	13	7.87	7.87	NUM
eurjchem-940	70	14	(	(	PUNCT
eurjchem-940	70	15	dd	dd	NOUN
eurjchem-940	70	16	,	,	PUNCT
eurjchem-940	70	17	2h	2h	NUM
eurjchem-940	70	18	,	,	PUNCT
eurjchem-940	70	19	j	j	PROPN
eurjchem-940	70	20	=	=	SYM
eurjchem-940	70	21	9.6	9.6	NUM
eurjchem-940	70	22	,	,	PUNCT
eurjchem-940	70	23	8.4	8.4	NUM
eurjchem-940	70	24	hz	hz	NOUN
eurjchem-940	70	25	,	,	PUNCT
eurjchem-940	70	26	ar‐	ar‐	PROPN
eurjchem-940	70	27	h	h	NOUN
eurjchem-940	70	28	)	)	PUNCT
eurjchem-940	70	29	,	,	PUNCT
eurjchem-940	70	30	7.81‐7.84	7.81‐7.84	NUM
eurjchem-940	70	31	(	(	PUNCT
eurjchem-940	70	32	m	m	PROPN
eurjchem-940	70	33	,	,	PUNCT
eurjchem-940	70	34	2h	2h	NUM
eurjchem-940	70	35	,	,	PUNCT
eurjchem-940	70	36	ar‐h	ar‐h	NOUN
eurjchem-940	70	37	)	)	PUNCT
eurjchem-940	70	38	,	,	PUNCT
eurjchem-940	70	39	7.55‐7.61	7.55‐7.61	NUM
eurjchem-940	70	40	(	(	PUNCT
eurjchem-940	70	41	m	m	PROPN
eurjchem-940	70	42	,	,	PUNCT
eurjchem-940	70	43	5	5	NUM
eurjchem-940	70	44	h	h	NOUN
eurjchem-940	70	45	,	,	PUNCT
eurjchem-940	70	46	ar‐h	ar‐h	NOUN
eurjchem-940	70	47	)	)	PUNCT
eurjchem-940	70	48	,	,	PUNCT
eurjchem-940	70	49	7.45‐7.51	7.45‐7.51	NUM
eurjchem-940	70	50	(	(	PUNCT
eurjchem-940	70	51	m	m	PROPN
eurjchem-940	70	52	,	,	PUNCT
eurjchem-940	70	53	4h	4h	NUM
eurjchem-940	70	54	,	,	PUNCT
eurjchem-940	70	55	ar‐h	ar‐h	NOUN
eurjchem-940	70	56	)	)	PUNCT
eurjchem-940	70	57	,	,	PUNCT
eurjchem-940	70	58	7.37‐7.42	7.37‐7.42	NUM
eurjchem-940	70	59	(	(	PUNCT
eurjchem-940	70	60	m	m	PROPN
eurjchem-940	70	61	,	,	PUNCT
eurjchem-940	70	62	1h	1h	NUM
eurjchem-940	70	63	,	,	PUNCT
eurjchem-940	70	64	ar‐h	ar‐h	NOUN
eurjchem-940	70	65	)	)	PUNCT
eurjchem-940	70	66	.	.	PUNCT
eurjchem-940	71	1	1‐phenylnaphthalene	1‐phenylnaphthalene	NUM
eurjchem-940	71	2	:	:	PUNCT
eurjchem-940	71	3	yield	yield	NOUN
eurjchem-940	71	4	:	:	PUNCT
eurjchem-940	71	5	80.4	80.4	NUM
eurjchem-940	71	6	%	%	NOUN
eurjchem-940	71	7	.	.	PUNCT
eurjchem-940	72	1	1h	1h	NUM
eurjchem-940	72	2	nmr	nmr	NOUN
eurjchem-940	72	3	(	(	PUNCT
eurjchem-940	72	4	300	300	NUM
eurjchem-940	72	5	mhz	mhz	NOUN
eurjchem-940	72	6	,	,	PUNCT
eurjchem-940	72	7	cdcl3	cdcl3	PROPN
eurjchem-940	72	8	,	,	PUNCT
eurjchem-940	72	9	δ	δ	PROPN
eurjchem-940	72	10	,	,	PUNCT
eurjchem-940	72	11	ppm	ppm	NUM
eurjchem-940	72	12	):	):	PUNCT
eurjchem-940	72	13	7.85‐792	7.85‐792	PROPN
eurjchem-940	72	14	(	(	PUNCT
eurjchem-940	72	15	m	m	PROPN
eurjchem-940	72	16	,	,	PUNCT
eurjchem-940	72	17	3h	3h	NUM
eurjchem-940	72	18	,	,	PUNCT
eurjchem-940	72	19	ar‐h	ar‐h	NOUN
eurjchem-940	72	20	)	)	PUNCT
eurjchem-940	72	21	,	,	PUNCT
eurjchem-940	72	22	7.40‐7.55	7.40‐7.55	NUM
eurjchem-940	72	23	(	(	PUNCT
eurjchem-940	72	24	m	m	PROPN
eurjchem-940	72	25	,	,	PUNCT
eurjchem-940	72	26	9h	9h	NUM
eurjchem-940	72	27	,	,	PUNCT
eurjchem-940	72	28	ar‐h	ar‐h	NOUN
eurjchem-940	72	29	)	)	PUNCT
eurjchem-940	72	30	.	.	PUNCT
eurjchem-940	73	1	4‐methoxy‐1,1'‐biphenyl	4‐methoxy‐1,1'‐biphenyl	NUM
eurjchem-940	73	2	:	:	PUNCT
eurjchem-940	73	3	yield	yield	NOUN
eurjchem-940	73	4	:	:	PUNCT
eurjchem-940	73	5	94.2	94.2	NUM
eurjchem-940	73	6	%	%	NOUN
eurjchem-940	73	7	.	.	PUNCT
eurjchem-940	74	1	1h	1h	NUM
eurjchem-940	74	2	nmr	nmr	NOUN
eurjchem-940	74	3	(	(	PUNCT
eurjchem-940	74	4	300	300	NUM
eurjchem-940	74	5	mhz	mhz	NOUN
eurjchem-940	74	6	,	,	PUNCT
eurjchem-940	74	7	cdcl3	cdcl3	PROPN
eurjchem-940	74	8	,	,	PUNCT
eurjchem-940	74	9	δ	δ	PROPN
eurjchem-940	74	10	,	,	PUNCT
eurjchem-940	74	11	ppm	ppm	NUM
eurjchem-940	74	12	):	):	PUNCT
eurjchem-940	74	13	7.50‐7.56	7.50‐7.56	NUM
eurjchem-940	74	14	(	(	PUNCT
eurjchem-940	74	15	m	m	PROPN
eurjchem-940	74	16	,	,	PUNCT
eurjchem-940	74	17	4h	4h	NUM
eurjchem-940	74	18	,	,	PUNCT
eurjchem-940	74	19	ar‐h	ar‐h	NOUN
eurjchem-940	74	20	)	)	PUNCT
eurjchem-940	74	21	,	,	PUNCT
eurjchem-940	74	22	7.37‐7.43	7.37‐7.43	NUM
eurjchem-940	74	23	(	(	PUNCT
eurjchem-940	74	24	m	m	PROPN
eurjchem-940	74	25	,	,	PUNCT
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eurjchem-940	74	27	,	,	PUNCT
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eurjchem-940	74	29	h	h	NOUN
eurjchem-940	74	30	)	)	PUNCT
eurjchem-940	74	31	,	,	PUNCT
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eurjchem-940	74	33	(	(	PUNCT
eurjchem-940	74	34	m	m	PROPN
eurjchem-940	74	35	,	,	PUNCT
eurjchem-940	74	36	1h	1h	NUM
eurjchem-940	74	37	,	,	PUNCT
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eurjchem-940	74	39	)	)	PUNCT
eurjchem-940	74	40	,	,	PUNCT
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eurjchem-940	74	42	(	(	PUNCT
eurjchem-940	74	43	m	m	PROPN
eurjchem-940	74	44	,	,	PUNCT
eurjchem-940	74	45	2h	2h	NUM
eurjchem-940	74	46	,	,	PUNCT
eurjchem-940	74	47	ar‐h	ar‐h	NOUN
eurjchem-940	74	48	)	)	PUNCT
eurjchem-940	74	49	,	,	PUNCT
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eurjchem-940	74	51	(	(	PUNCT
eurjchem-940	74	52	s	s	PROPN
eurjchem-940	74	53	,	,	PUNCT
eurjchem-940	74	54	3h	3h	NUM
eurjchem-940	74	55	,	,	PUNCT
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eurjchem-940	74	57	)	)	PUNCT
eurjchem-940	74	58	.	.	PUNCT
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eurjchem-940	75	2	:	:	PUNCT
eurjchem-940	75	3	yield	yield	NOUN
eurjchem-940	75	4	:	:	PUNCT
eurjchem-940	75	5	90.3	90.3	NUM
eurjchem-940	75	6	%	%	NOUN
eurjchem-940	75	7	(	(	PUNCT
eurjchem-940	75	8	4‐bromotoluene	4‐bromotoluene	NOUN
eurjchem-940	75	9	)	)	PUNCT
eurjchem-940	75	10	,	,	PUNCT
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eurjchem-940	75	15	)	)	PUNCT
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eurjchem-940	76	3	(	(	PUNCT
eurjchem-940	76	4	300	300	NUM
eurjchem-940	76	5	mhz	mhz	NOUN
eurjchem-940	76	6	,	,	PUNCT
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eurjchem-940	76	8	,	,	PUNCT
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eurjchem-940	76	12	):	):	PUNCT
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eurjchem-940	76	18	,	,	PUNCT
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eurjchem-940	76	20	)	)	PUNCT
eurjchem-940	76	21	,	,	PUNCT
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eurjchem-940	76	23	(	(	PUNCT
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eurjchem-940	76	25	,	,	PUNCT
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eurjchem-940	76	29	)	)	PUNCT
eurjchem-940	76	30	,	,	PUNCT
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eurjchem-940	76	36	,	,	PUNCT
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eurjchem-940	76	38	)	)	PUNCT
eurjchem-940	76	39	,	,	PUNCT
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eurjchem-940	76	41	(	(	PUNCT
eurjchem-940	76	42	m	m	PROPN
eurjchem-940	76	43	,	,	PUNCT
eurjchem-940	76	44	1h	1h	NUM
eurjchem-940	76	45	,	,	PUNCT
eurjchem-940	76	46	ar‐h	ar‐h	NOUN
eurjchem-940	76	47	)	)	PUNCT
eurjchem-940	76	48	,	,	PUNCT
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eurjchem-940	76	51	m	m	PROPN
eurjchem-940	76	52	,	,	PUNCT
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eurjchem-940	76	54	,	,	PUNCT
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eurjchem-940	76	56	)	)	PUNCT
eurjchem-940	76	57	,	,	PUNCT
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eurjchem-940	76	59	(	(	PUNCT
eurjchem-940	76	60	s	s	PROPN
eurjchem-940	76	61	,	,	PUNCT
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eurjchem-940	76	63	,	,	PUNCT
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eurjchem-940	76	65	)	)	PUNCT
eurjchem-940	76	66	.	.	PUNCT
eurjchem-940	77	1	[	[	X
eurjchem-940	77	2	1,1'‐biphenyl]‐4‐carbaldehyde	1,1'‐biphenyl]‐4‐carbaldehyde	NUM
eurjchem-940	77	3	:	:	PUNCT
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eurjchem-940	77	5	:	:	PUNCT
eurjchem-940	77	6	60.8	60.8	NUM
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eurjchem-940	77	8	.	.	PUNCT
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eurjchem-940	78	3	(	(	PUNCT
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eurjchem-940	78	8	,	,	PUNCT
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eurjchem-940	78	20	)	)	PUNCT
eurjchem-940	78	21	,	,	PUNCT
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eurjchem-940	78	23	(	(	PUNCT
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eurjchem-940	78	25	,	,	PUNCT
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eurjchem-940	78	32	,	,	PUNCT
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eurjchem-940	78	34	)	)	PUNCT
eurjchem-940	78	35	,	,	PUNCT
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eurjchem-940	78	46	,	,	PUNCT
eurjchem-940	78	47	ar‐h	ar‐h	NOUN
eurjchem-940	78	48	)	)	PUNCT
eurjchem-940	78	49	,	,	PUNCT
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eurjchem-940	78	58	,	,	PUNCT
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eurjchem-940	78	67	.	.	PUNCT
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eurjchem-940	79	2	:	:	PUNCT
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eurjchem-940	79	4	:	:	PUNCT
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eurjchem-940	80	3	(	(	PUNCT
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eurjchem-940	80	8	,	,	PUNCT
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eurjchem-940	80	10	,	,	PUNCT
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eurjchem-940	80	12	):	):	PUNCT
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eurjchem-940	80	25	,	,	PUNCT
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eurjchem-940	81	2	:	:	PUNCT
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eurjchem-940	81	4	:	:	PUNCT
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eurjchem-940	82	10	,	,	PUNCT
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eurjchem-940	82	12	):	):	PUNCT
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eurjchem-940	82	23	,	,	PUNCT
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eurjchem-940	82	31	,	,	PUNCT
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eurjchem-940	82	39	=	=	PROPN
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eurjchem-940	82	42	,	,	PUNCT
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eurjchem-940	82	44	)	)	PUNCT
eurjchem-940	82	45	,	,	PUNCT
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eurjchem-940	82	47	)	)	PUNCT
eurjchem-940	82	48	,	,	PUNCT
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eurjchem-940	82	50	(	(	PUNCT
eurjchem-940	82	51	m	m	PROPN
eurjchem-940	82	52	,	,	PUNCT
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eurjchem-940	82	54	,	,	PUNCT
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eurjchem-940	82	57	,	,	PUNCT
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eurjchem-940	83	4	:	:	PUNCT
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eurjchem-940	84	3	(	(	PUNCT
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eurjchem-940	84	12	):	):	PUNCT
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eurjchem-940	84	23	,	,	PUNCT
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eurjchem-940	84	25	h(coch3	h(coch3	PROPN
eurjchem-940	84	26	)	)	PUNCT
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eurjchem-940	84	29	)	)	PUNCT
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eurjchem-940	84	41	,	,	PUNCT
eurjchem-940	84	42	ar‐h(coch3	ar‐h(coch3	ADJ
eurjchem-940	84	43	)	)	PUNCT
eurjchem-940	84	44	,	,	PUNCT
eurjchem-940	84	45	meta	meta	X
eurjchem-940	84	46	)	)	PUNCT
eurjchem-940	84	47	,	,	PUNCT
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eurjchem-940	84	50	d	d	PROPN
eurjchem-940	84	51	,	,	PUNCT
eurjchem-940	84	52	2h	2h	NUM
eurjchem-940	84	53	,	,	PUNCT
eurjchem-940	84	54	j	j	PROPN
eurjchem-940	85	1	=	=	SYM
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eurjchem-940	85	7	,	,	PUNCT
eurjchem-940	85	8	meta	meta	X
eurjchem-940	85	9	)	)	PUNCT
eurjchem-940	85	10	,	,	PUNCT
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eurjchem-940	85	14	,	,	PUNCT
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eurjchem-940	85	18	=	=	SYM
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eurjchem-940	85	23	)	)	PUNCT
eurjchem-940	85	24	,	,	PUNCT
eurjchem-940	85	25	ortho	ortho	PROPN
eurjchem-940	85	26	)	)	PUNCT
eurjchem-940	85	27	,	,	PUNCT
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eurjchem-940	85	31	,	,	PUNCT
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eurjchem-940	85	33	,	,	PUNCT
eurjchem-940	85	34	ar‐och3	ar‐och3	PROPN
eurjchem-940	85	35	)	)	PUNCT
eurjchem-940	85	36	,	,	PUNCT
eurjchem-940	85	37	2.61	2.61	NUM
eurjchem-940	85	38	(	(	PUNCT
eurjchem-940	85	39	s	s	PROPN
eurjchem-940	85	40	,	,	PUNCT
eurjchem-940	85	41	3h	3h	NUM
eurjchem-940	85	42	,	,	PUNCT
eurjchem-940	85	43	ar‐	ar‐	PROPN
eurjchem-940	85	44	coch3	coch3	PROPN
eurjchem-940	85	45	)	)	PUNCT
eurjchem-940	85	46	.	.	PUNCT
eurjchem-940	86	1	3	3	X
eurjchem-940	86	2	.	.	NOUN
eurjchem-940	86	3	results	result	NOUN
eurjchem-940	86	4	and	and	CCONJ
eurjchem-940	86	5	discussion	discussion	NOUN
eurjchem-940	86	6	because	because	SCONJ
eurjchem-940	86	7	the	the	DET
eurjchem-940	86	8	bulkiness	bulkiness	NOUN
eurjchem-940	86	9	around	around	ADP
eurjchem-940	86	10	the	the	DET
eurjchem-940	86	11	metal	metal	NOUN
eurjchem-940	86	12	is	be	AUX
eurjchem-940	86	13	critical	critical	ADJ
eurjchem-940	86	14	for	for	ADP
eurjchem-940	86	15	the	the	DET
eurjchem-940	86	16	catalytic	catalytic	ADJ
eurjchem-940	86	17	activity	activity	NOUN
eurjchem-940	86	18	of	of	ADP
eurjchem-940	86	19	palladium‐nhc	palladium‐nhc	NOUN
eurjchem-940	86	20	complexes	complex	NOUN
eurjchem-940	86	21	,	,	PUNCT
eurjchem-940	86	22	we	we	PRON
eurjchem-940	86	23	sought	seek	VERB
eurjchem-940	86	24	to	to	PART
eurjchem-940	86	25	determine	determine	VERB
eurjchem-940	86	26	whether	whether	SCONJ
eurjchem-940	86	27	a	a	DET
eurjchem-940	86	28	combination	combination	NOUN
eurjchem-940	86	29	of	of	ADP
eurjchem-940	86	30	a	a	DET
eurjchem-940	86	31	rigid	rigid	ADJ
eurjchem-940	86	32	n‐2,6‐diisopropyl	n‐2,6‐diisopropyl	NOUN
eurjchem-940	86	33	164	164	NUM
eurjchem-940	86	34	broekemier	broekemier	NOUN
eurjchem-940	86	35	et	et	PROPN
eurjchem-940	86	36	al	al	PROPN
eurjchem-940	86	37	.	.	PUNCT
eurjchem-940	86	38	/	/	SYM
eurjchem-940	86	39	european	european	PROPN
eurjchem-940	86	40	journal	journal	PROPN
eurjchem-940	86	41	of	of	ADP
eurjchem-940	86	42	chemistry	chemistry	NOUN
eurjchem-940	86	43	5	5	NUM
eurjchem-940	86	44	(	(	PUNCT
eurjchem-940	86	45	1	1	NUM
eurjchem-940	86	46	)	)	PUNCT
eurjchem-940	86	47	(	(	PUNCT
eurjchem-940	86	48	2014	2014	NUM
eurjchem-940	86	49	)	)	PUNCT
eurjchem-940	86	50	162‐166	162‐166	PROPN
eurjchem-940	86	51	table	table	NOUN
eurjchem-940	86	52	1	1	NUM
eurjchem-940	86	53	.	.	PUNCT
eurjchem-940	87	1	screening	screen	VERB
eurjchem-940	87	2	of	of	ADP
eurjchem-940	87	3	reaction	reaction	NOUN
eurjchem-940	87	4	conditions	condition	NOUN
eurjchem-940	87	5	.	.	PUNCT
eurjchem-940	88	1	cl	cl	NOUN
eurjchem-940	89	1	o	o	NOUN
eurjchem-940	90	1	+	+	CCONJ
eurjchem-940	90	2	b(oh)2	b(oh)2	PROPN
eurjchem-940	90	3	1	1	NUM
eurjchem-940	90	4	mol%	mol%	PROPN
eurjchem-940	90	5	of	of	ADP
eurjchem-940	90	6	1	1	NUM
eurjchem-940	90	7	solvent	solvent	NOUN
eurjchem-940	90	8	/	/	SYM
eurjchem-940	90	9	base/2	base/2	PROPN
eurjchem-940	90	10	h	h	NOUN
eurjchem-940	90	11	o	o	NOUN
eurjchem-940	90	12	entry	entry	NOUN
eurjchem-940	90	13	a	a	DET
eurjchem-940	90	14	base	base	ADJ
eurjchem-940	90	15	solvent	solvent	NOUN
eurjchem-940	90	16	yield	yield	NOUN
eurjchem-940	90	17	(	(	PUNCT
eurjchem-940	90	18	%	%	INTJ
eurjchem-940	90	19	)	)	PUNCT
eurjchem-940	90	20	b	b	NOUN
eurjchem-940	90	21	1	1	NUM
eurjchem-940	90	22	c	c	PROPN
eurjchem-940	90	23	k3po4	k3po4	NOUN
eurjchem-940	90	24	thf	thf	NOUN
eurjchem-940	90	25	15.5	15.5	NUM
eurjchem-940	90	26	2	2	NUM
eurjchem-940	90	27	c	c	NOUN
eurjchem-940	90	28	k3po4	k3po4	NOUN
eurjchem-940	90	29	thf	thf	PROPN
eurjchem-940	90	30	/	/	SYM
eurjchem-940	90	31	water	water	NOUN
eurjchem-940	90	32	18.3	18.3	NUM
eurjchem-940	90	33	3	3	NUM
eurjchem-940	90	34	c	c	NOUN
eurjchem-940	90	35	,	,	PUNCT
eurjchem-940	90	36	d	d	PRON
eurjchem-940	90	37	k3po4	k3po4	NOUN
eurjchem-940	90	38	dioxane	dioxane	NOUN
eurjchem-940	90	39	21.4	21.4	NUM
eurjchem-940	90	40	4	4	NUM
eurjchem-940	90	41	e	e	NOUN
eurjchem-940	90	42	naoh	naoh	NOUN
eurjchem-940	90	43	iproh	iproh	NOUN
eurjchem-940	90	44	86.4	86.4	NUM
eurjchem-940	90	45	5	5	NUM
eurjchem-940	90	46	kot‐bu	kot‐bu	NOUN
eurjchem-940	90	47	thf	thf	NOUN
eurjchem-940	90	48	0.80	0.80	NUM
eurjchem-940	90	49	6	6	NUM
eurjchem-940	90	50	kot‐bu	kot‐bu	NOUN
eurjchem-940	90	51	toluene	toluene	NOUN
eurjchem-940	90	52	0.80	0.80	NUM
eurjchem-940	90	53	7	7	NUM
eurjchem-940	90	54	d	d	PROPN
eurjchem-940	90	55	,	,	PUNCT
eurjchem-940	90	56	f	f	PROPN
eurjchem-940	90	57	kot‐bu	kot‐bu	PROPN
eurjchem-940	90	58	/	/	SYM
eurjchem-940	90	59	cs2co3	cs2co3	ADJ
eurjchem-940	90	60	dioxane	dioxane	NOUN
eurjchem-940	90	61	64.4	64.4	NUM
eurjchem-940	90	62	8	8	NUM
eurjchem-940	90	63	kot‐bu	kot‐bu	PROPN
eurjchem-940	90	64	iproh	iproh	VERB
eurjchem-940	90	65	88.3	88.3	NUM
eurjchem-940	90	66	9	9	NUM
eurjchem-940	90	67	kot‐bu	kot‐bu	NOUN
eurjchem-940	90	68	etoh	etoh	PROPN
eurjchem-940	90	69	66.4	66.4	NUM
eurjchem-940	90	70	10	10	NUM
eurjchem-940	90	71	kot‐bu	kot‐bu	PROPN
eurjchem-940	90	72	meoh	meoh	NOUN
eurjchem-940	90	73	8.30	8.30	NUM
eurjchem-940	90	74	11	11	NUM
eurjchem-940	90	75	g	g	ADP
eurjchem-940	90	76	kot‐bu	kot‐bu	PROPN
eurjchem-940	90	77	/	/	SYM
eurjchem-940	90	78	k3po4	k3po4	NOUN
eurjchem-940	90	79	iproh	iproh	NOUN
eurjchem-940	90	80	38.7	38.7	NUM
eurjchem-940	90	81	12	12	NUM
eurjchem-940	90	82	h	h	NOUN
eurjchem-940	90	83	kot‐bu	kot‐bu	PROPN
eurjchem-940	90	84	/	/	SYM
eurjchem-940	90	85	k3po4	k3po4	NOUN
eurjchem-940	90	86	iproh	iproh	NOUN
eurjchem-940	90	87	95.0	95.0	NUM
eurjchem-940	90	88	a	a	DET
eurjchem-940	90	89	reaction	reaction	NOUN
eurjchem-940	90	90	conditions	condition	NOUN
eurjchem-940	90	91	:	:	PUNCT
eurjchem-940	90	92	4'‐chloroacetophenone	4'‐chloroacetophenone	NUM
eurjchem-940	90	93	(	(	PUNCT
eurjchem-940	90	94	1	1	NUM
eurjchem-940	90	95	mmol	mmol	NOUN
eurjchem-940	90	96	)	)	PUNCT
eurjchem-940	90	97	,	,	PUNCT
eurjchem-940	90	98	phenylboronic	phenylboronic	ADJ
eurjchem-940	90	99	acid	acid	NOUN
eurjchem-940	90	100	(	(	PUNCT
eurjchem-940	90	101	1.3	1.3	NUM
eurjchem-940	90	102	mmol	mmol	NOUN
eurjchem-940	90	103	)	)	PUNCT
eurjchem-940	90	104	,	,	PUNCT
eurjchem-940	90	105	base	base	NOUN
eurjchem-940	90	106	(	(	PUNCT
eurjchem-940	90	107	1.1	1.1	NUM
eurjchem-940	90	108	mmol	mmol	NOUN
eurjchem-940	90	109	)	)	PUNCT
eurjchem-940	90	110	,	,	PUNCT
eurjchem-940	90	111	3	3	NUM
eurjchem-940	90	112	ml	ml	NOUN
eurjchem-940	90	113	of	of	ADP
eurjchem-940	90	114	solvent	solvent	NOUN
eurjchem-940	90	115	,	,	PUNCT
eurjchem-940	90	116	2	2	NUM
eurjchem-940	90	117	h	h	NOUN
eurjchem-940	90	118	,	,	PUNCT
eurjchem-940	90	119	50	50	NUM
eurjchem-940	90	120	°	°	NOUN
eurjchem-940	90	121	c	c	NOUN
eurjchem-940	90	122	.	.	PUNCT
eurjchem-940	91	1	b	b	X
eurjchem-940	91	2	average	average	ADJ
eurjchem-940	91	3	yield	yield	NOUN
eurjchem-940	91	4	of	of	ADP
eurjchem-940	91	5	two	two	NUM
eurjchem-940	91	6	experiments	experiment	NOUN
eurjchem-940	91	7	,	,	PUNCT
eurjchem-940	91	8	isolated	isolated	ADJ
eurjchem-940	91	9	yields	yield	NOUN
eurjchem-940	91	10	.	.	PUNCT
eurjchem-940	92	1	c	c	NOUN
eurjchem-940	92	2	with	with	ADP
eurjchem-940	92	3	3	3	NUM
eurjchem-940	92	4	equiv	equiv	NOUN
eurjchem-940	92	5	of	of	ADP
eurjchem-940	92	6	k3po4	k3po4	NOUN
eurjchem-940	92	7	.	.	PUNCT
eurjchem-940	93	1	d	d	NOUN
eurjchem-940	93	2	at	at	ADP
eurjchem-940	93	3	80	80	NUM
eurjchem-940	93	4	°	°	NOUN
eurjchem-940	93	5	c	c	NOUN
eurjchem-940	93	6	.	.	PUNCT
eurjchem-940	94	1	e	e	X
eurjchem-940	94	2	with	with	ADP
eurjchem-940	94	3	1.5	1.5	NUM
eurjchem-940	94	4	equiv	equiv	NOUN
eurjchem-940	94	5	.	.	PUNCT
eurjchem-940	95	1	f	f	PROPN
eurjchem-940	95	2	with	with	ADP
eurjchem-940	95	3	10	10	NUM
eurjchem-940	95	4	mol%	mol%	PROPN
eurjchem-940	95	5	of	of	ADP
eurjchem-940	95	6	kotbu	kotbu	PROPN
eurjchem-940	95	7	and	and	CCONJ
eurjchem-940	95	8	1.5	1.5	NUM
eurjchem-940	95	9	mol	mol	NOUN
eurjchem-940	95	10	of	of	ADP
eurjchem-940	95	11	cs2co3	cs2co3	ADJ
eurjchem-940	95	12	.	.	PUNCT
eurjchem-940	96	1	g	g	NOUN
eurjchem-940	96	2	with	with	ADP
eurjchem-940	96	3	10	10	NUM
eurjchem-940	96	4	mol%	mol%	PROPN
eurjchem-940	96	5	of	of	ADP
eurjchem-940	96	6	kotbu	kotbu	PROPN
eurjchem-940	96	7	and	and	CCONJ
eurjchem-940	96	8	3	3	NUM
eurjchem-940	96	9	mol	mol	NOUN
eurjchem-940	96	10	of	of	ADP
eurjchem-940	96	11	k3po4	k3po4	NOUN
eurjchem-940	96	12	.	.	PUNCT
eurjchem-940	97	1	h	h	PROPN
eurjchem-940	97	2	with	with	ADP
eurjchem-940	97	3	1.1	1.1	NUM
eurjchem-940	97	4	mmol	mmol	NOUN
eurjchem-940	97	5	of	of	ADP
eurjchem-940	97	6	kotbu	kotbu	NOUN
eurjchem-940	97	7	and	and	CCONJ
eurjchem-940	97	8	1.5	1.5	NUM
eurjchem-940	97	9	mol	mol	NOUN
eurjchem-940	97	10	of	of	ADP
eurjchem-940	97	11	k3po4	k3po4	NOUN
eurjchem-940	97	12	.	.	PUNCT
eurjchem-940	98	1	scheme	scheme	NOUN
eurjchem-940	98	2	1	1	NUM
eurjchem-940	98	3	phenyl	phenyl	NOUN
eurjchem-940	98	4	substituent	substituent	NOUN
eurjchem-940	98	5	and	and	CCONJ
eurjchem-940	98	6	a	a	DET
eurjchem-940	98	7	flexible	flexible	ADJ
eurjchem-940	98	8	n‐diphenylmethyl	n‐diphenylmethyl	PROPN
eurjchem-940	98	9	substituent	substituent	NOUN
eurjchem-940	98	10	could	could	AUX
eurjchem-940	98	11	give	give	VERB
eurjchem-940	98	12	an	an	DET
eurjchem-940	98	13	active	active	ADJ
eurjchem-940	98	14	catalysts	catalyst	NOUN
eurjchem-940	98	15	for	for	ADP
eurjchem-940	98	16	the	the	DET
eurjchem-940	98	17	suzuki‐miyaura	suzuki‐miyaura	PROPN
eurjchem-940	98	18	cross‐	cross‐	NOUN
eurjchem-940	98	19	coupling	coupling	NOUN
eurjchem-940	98	20	of	of	ADP
eurjchem-940	98	21	aryl	aryl	NOUN
eurjchem-940	98	22	halides	halide	NOUN
eurjchem-940	98	23	.	.	PUNCT
eurjchem-940	99	1	the	the	DET
eurjchem-940	99	2	[	[	X
eurjchem-940	99	3	(	(	PUNCT
eurjchem-940	99	4	nhc)‐palladium‐(allyl)cl	nhc)‐palladium‐(allyl)cl	NOUN
eurjchem-940	99	5	]	]	X
eurjchem-940	99	6	complex	complex	NOUN
eurjchem-940	99	7	was	be	AUX
eurjchem-940	99	8	synthesized	synthesize	VERB
eurjchem-940	99	9	by	by	ADP
eurjchem-940	99	10	the	the	DET
eurjchem-940	99	11	silver	silver	NOUN
eurjchem-940	99	12	transfer	transfer	NOUN
eurjchem-940	99	13	method	method	NOUN
eurjchem-940	99	14	[	[	X
eurjchem-940	99	15	26	26	NUM
eurjchem-940	99	16	]	]	PUNCT
eurjchem-940	99	17	,	,	PUNCT
eurjchem-940	99	18	starting	start	VERB
eurjchem-940	99	19	from	from	ADP
eurjchem-940	99	20	the	the	DET
eurjchem-940	99	21	commercially	commercially	ADV
eurjchem-940	99	22	available	available	ADJ
eurjchem-940	99	23	2,6‐diisopropylaniline	2,6‐diisopropylaniline	NUM
eurjchem-940	99	24	[	[	X
eurjchem-940	99	25	25	25	NUM
eurjchem-940	99	26	]	]	PUNCT
eurjchem-940	99	27	,	,	PUNCT
eurjchem-940	99	28	to	to	PART
eurjchem-940	99	29	provide	provide	VERB
eurjchem-940	99	30	the	the	DET
eurjchem-940	99	31	corresponding	corresponding	ADJ
eurjchem-940	99	32	imidazole	imidazole	NOUN
eurjchem-940	99	33	,	,	PUNCT
eurjchem-940	99	34	which	which	PRON
eurjchem-940	99	35	under	under	ADP
eurjchem-940	99	36	treatment	treatment	NOUN
eurjchem-940	99	37	with	with	ADP
eurjchem-940	99	38	net	net	ADJ
eurjchem-940	99	39	chlorodiphenylmethane	chlorodiphenylmethane	NOUN
eurjchem-940	99	40	provides	provide	VERB
eurjchem-940	99	41	the	the	DET
eurjchem-940	99	42	imidazolium	imidazolium	NOUN
eurjchem-940	99	43	salt	salt	NOUN
eurjchem-940	99	44	1	1	NUM
eurjchem-940	99	45	.	.	PUNCT
eurjchem-940	100	1	the	the	DET
eurjchem-940	100	2	silver	silver	ADJ
eurjchem-940	100	3	complex	complex	NOUN
eurjchem-940	100	4	was	be	AUX
eurjchem-940	100	5	treated	treat	VERB
eurjchem-940	100	6	with	with	ADP
eurjchem-940	100	7	palladium	palladium	NOUN
eurjchem-940	100	8	allyl	allyl	ADJ
eurjchem-940	100	9	chloride	chloride	NOUN
eurjchem-940	100	10	producing	produce	VERB
eurjchem-940	100	11	catalyst	catalyst	NOUN
eurjchem-940	100	12	2	2	NUM
eurjchem-940	100	13	in	in	ADP
eurjchem-940	100	14	good	good	ADJ
eurjchem-940	100	15	yield	yield	NOUN
eurjchem-940	100	16	,	,	PUNCT
eurjchem-940	100	17	scheme	scheme	NOUN
eurjchem-940	100	18	1	1	NUM
eurjchem-940	100	19	.	.	PUNCT
eurjchem-940	101	1	the	the	DET
eurjchem-940	101	2	choice	choice	NOUN
eurjchem-940	101	3	of	of	ADP
eurjchem-940	101	4	solvent	solvent	NOUN
eurjchem-940	101	5	/	/	SYM
eurjchem-940	101	6	base	base	NOUN
eurjchem-940	101	7	is	be	AUX
eurjchem-940	101	8	crucial	crucial	ADJ
eurjchem-940	101	9	for	for	ADP
eurjchem-940	101	10	the	the	DET
eurjchem-940	101	11	yield	yield	NOUN
eurjchem-940	101	12	.	.	PUNCT
eurjchem-940	102	1	using	use	VERB
eurjchem-940	102	2	as	as	ADP
eurjchem-940	102	3	a	a	DET
eurjchem-940	102	4	model	model	NOUN
eurjchem-940	102	5	the	the	DET
eurjchem-940	102	6	reaction	reaction	NOUN
eurjchem-940	102	7	between	between	ADP
eurjchem-940	102	8	4’‐chloroacetophenone	4’‐chloroacetophenone	NUM
eurjchem-940	102	9	and	and	CCONJ
eurjchem-940	102	10	phenylboronic	phenylboronic	ADJ
eurjchem-940	102	11	acid	acid	NOUN
eurjchem-940	102	12	,	,	PUNCT
eurjchem-940	102	13	different	different	ADJ
eurjchem-940	102	14	protic	protic	ADJ
eurjchem-940	102	15	and	and	CCONJ
eurjchem-940	102	16	non	non	ADJ
eurjchem-940	102	17	protic	protic	ADJ
eurjchem-940	102	18	solvents	solvent	NOUN
eurjchem-940	102	19	were	be	AUX
eurjchem-940	102	20	screened	screen	VERB
eurjchem-940	102	21	together	together	ADV
eurjchem-940	102	22	with	with	ADP
eurjchem-940	102	23	distinct	distinct	ADJ
eurjchem-940	102	24	bases	basis	NOUN
eurjchem-940	102	25	,	,	PUNCT
eurjchem-940	102	26	table	table	NOUN
eurjchem-940	102	27	1	1	NUM
eurjchem-940	102	28	.	.	PUNCT
eurjchem-940	103	1	the	the	DET
eurjchem-940	103	2	combination	combination	NOUN
eurjchem-940	103	3	of	of	ADP
eurjchem-940	103	4	non‐protic	non‐protic	ADJ
eurjchem-940	103	5	solvents	solvent	NOUN
eurjchem-940	103	6	with	with	ADP
eurjchem-940	103	7	different	different	ADJ
eurjchem-940	103	8	bases	basis	NOUN
eurjchem-940	103	9	provided	provide	VERB
eurjchem-940	103	10	low	low	ADJ
eurjchem-940	103	11	yields	yield	NOUN
eurjchem-940	103	12	(	(	PUNCT
eurjchem-940	103	13	entries	entry	NOUN
eurjchem-940	103	14	1	1	NUM
eurjchem-940	103	15	,	,	PUNCT
eurjchem-940	103	16	3	3	NUM
eurjchem-940	103	17	,	,	PUNCT
eurjchem-940	103	18	5	5	NUM
eurjchem-940	103	19	,	,	PUNCT
eurjchem-940	103	20	6	6	NUM
eurjchem-940	103	21	)	)	PUNCT
eurjchem-940	103	22	,	,	PUNCT
eurjchem-940	103	23	except	except	SCONJ
eurjchem-940	103	24	for	for	ADP
eurjchem-940	103	25	the	the	DET
eurjchem-940	103	26	combination	combination	NOUN
eurjchem-940	103	27	of	of	ADP
eurjchem-940	103	28	dioxane	dioxane	NOUN
eurjchem-940	103	29	with	with	ADP
eurjchem-940	103	30	kot‐bu	kot‐bu	NOUN
eurjchem-940	103	31	/	/	SYM
eurjchem-940	103	32	cs2co3	cs2co3	ADJ
eurjchem-940	103	33	(	(	PUNCT
eurjchem-940	103	34	entry	entry	NOUN
eurjchem-940	103	35	7	7	NUM
eurjchem-940	103	36	)	)	PUNCT
eurjchem-940	103	37	.	.	PUNCT
eurjchem-940	104	1	isopropanol	isopropanol	NOUN
eurjchem-940	104	2	with	with	ADP
eurjchem-940	104	3	naoh	naoh	NOUN
eurjchem-940	104	4	or	or	CCONJ
eurjchem-940	104	5	kot‐bu	kot‐bu	PROPN
eurjchem-940	104	6	provided	provide	VERB
eurjchem-940	104	7	the	the	DET
eurjchem-940	104	8	highest	high	ADJ
eurjchem-940	104	9	yield	yield	NOUN
eurjchem-940	104	10	,	,	PUNCT
eurjchem-940	104	11	(	(	PUNCT
eurjchem-940	104	12	entries	entry	NOUN
eurjchem-940	104	13	4	4	NUM
eurjchem-940	104	14	and	and	CCONJ
eurjchem-940	104	15	8)	8)	NUM
eurjchem-940	104	16	.	.	PUNCT
eurjchem-940	105	1	the	the	DET
eurjchem-940	105	2	addition	addition	NOUN
eurjchem-940	105	3	of	of	ADP
eurjchem-940	105	4	1.5	1.5	NUM
eurjchem-940	105	5	equivalent	equivalent	NOUN
eurjchem-940	105	6	of	of	ADP
eurjchem-940	105	7	k3po4	k3po4	NOUN
eurjchem-940	105	8	improved	improve	VERB
eurjchem-940	105	9	the	the	DET
eurjchem-940	105	10	yield	yield	NOUN
eurjchem-940	105	11	to	to	ADP
eurjchem-940	105	12	95	95	NUM
eurjchem-940	105	13	%	%	NOUN
eurjchem-940	105	14	,	,	PUNCT
eurjchem-940	105	15	(	(	PUNCT
eurjchem-940	105	16	entry	entry	NOUN
eurjchem-940	105	17	12	12	NUM
eurjchem-940	105	18	)	)	PUNCT
eurjchem-940	105	19	.	.	PUNCT
eurjchem-940	106	1	a	a	DET
eurjchem-940	106	2	catalytic	catalytic	ADJ
eurjchem-940	106	3	amount	amount	NOUN
eurjchem-940	106	4	of	of	ADP
eurjchem-940	106	5	kot‐bu	kot‐bu	NOUN
eurjchem-940	106	6	(	(	PUNCT
eurjchem-940	106	7	10	10	NUM
eurjchem-940	106	8	mol%	mol%	NOUN
eurjchem-940	106	9	)	)	PUNCT
eurjchem-940	106	10	in	in	ADP
eurjchem-940	106	11	combination	combination	NOUN
eurjchem-940	106	12	with	with	ADP
eurjchem-940	106	13	k3po4	k3po4	NOUN
eurjchem-940	106	14	gave	give	VERB
eurjchem-940	106	15	a	a	DET
eurjchem-940	106	16	lower	low	ADJ
eurjchem-940	106	17	yield	yield	NOUN
eurjchem-940	106	18	than	than	ADP
eurjchem-940	106	19	the	the	DET
eurjchem-940	106	20	one	one	NUM
eurjchem-940	106	21	molar	molar	ADJ
eurjchem-940	106	22	amount	amount	NOUN
eurjchem-940	106	23	(	(	PUNCT
eurjchem-940	106	24	entry	entry	NOUN
eurjchem-940	106	25	11	11	NUM
eurjchem-940	106	26	vs.	vs.	ADP
eurjchem-940	106	27	12	12	NUM
eurjchem-940	106	28	)	)	PUNCT
eurjchem-940	106	29	.	.	PUNCT
eurjchem-940	107	1	the	the	DET
eurjchem-940	107	2	high	high	ADJ
eurjchem-940	107	3	activity	activity	NOUN
eurjchem-940	107	4	for	for	ADP
eurjchem-940	107	5	the	the	DET
eurjchem-940	107	6	suzuki‐miyaura	suzuki‐miyaura	PROPN
eurjchem-940	107	7	cross	cross	PROPN
eurjchem-940	107	8	coupling	coupling	NOUN
eurjchem-940	107	9	of	of	ADP
eurjchem-940	107	10	some	some	DET
eurjchem-940	107	11	catalysts	catalyst	NOUN
eurjchem-940	107	12	in	in	ADP
eurjchem-940	107	13	isopropanol	isopropanol	NOUN
eurjchem-940	107	14	with	with	ADP
eurjchem-940	107	15	a	a	DET
eurjchem-940	107	16	base	base	NOUN
eurjchem-940	107	17	,	,	PUNCT
eurjchem-940	107	18	it	it	PRON
eurjchem-940	107	19	has	have	AUX
eurjchem-940	107	20	been	be	AUX
eurjchem-940	107	21	attributed	attribute	VERB
eurjchem-940	107	22	to	to	ADP
eurjchem-940	107	23	the	the	DET
eurjchem-940	107	24	reduction	reduction	NOUN
eurjchem-940	107	25	of	of	ADP
eurjchem-940	107	26	the	the	DET
eurjchem-940	107	27	palladium	palladium	NOUN
eurjchem-940	107	28	complex	complex	NOUN
eurjchem-940	107	29	by	by	ADP
eurjchem-940	107	30	the	the	DET
eurjchem-940	107	31	isopropoxide	isopropoxide	NOUN
eurjchem-940	107	32	formed	form	VERB
eurjchem-940	107	33	from	from	ADP
eurjchem-940	107	34	the	the	DET
eurjchem-940	107	35	reaction	reaction	NOUN
eurjchem-940	107	36	between	between	ADP
eurjchem-940	107	37	the	the	DET
eurjchem-940	107	38	alcohol	alcohol	NOUN
eurjchem-940	107	39	and	and	CCONJ
eurjchem-940	107	40	a	a	DET
eurjchem-940	107	41	base	base	NOUN
eurjchem-940	107	42	[	[	X
eurjchem-940	107	43	27	27	NUM
eurjchem-940	107	44	]	]	PUNCT
eurjchem-940	107	45	.	.	PUNCT
eurjchem-940	108	1	interestingly	interestingly	ADV
eurjchem-940	108	2	,	,	PUNCT
eurjchem-940	108	3	ethanol	ethanol	NOUN
eurjchem-940	108	4	and	and	CCONJ
eurjchem-940	108	5	methanol	methanol	NOUN
eurjchem-940	108	6	gave	give	VERB
eurjchem-940	108	7	lower	low	ADJ
eurjchem-940	108	8	yields	yield	NOUN
eurjchem-940	108	9	,	,	PUNCT
eurjchem-940	108	10	which	which	PRON
eurjchem-940	108	11	may	may	AUX
eurjchem-940	108	12	indicate	indicate	VERB
eurjchem-940	108	13	that	that	DET
eurjchem-940	108	14	ethoxide	ethoxide	NOUN
eurjchem-940	108	15	and	and	CCONJ
eurjchem-940	108	16	methoxide	methoxide	ADJ
eurjchem-940	108	17	ions	ion	NOUN
eurjchem-940	108	18	,	,	PUNCT
eurjchem-940	108	19	formed	form	VERB
eurjchem-940	108	20	from	from	ADP
eurjchem-940	108	21	the	the	DET
eurjchem-940	108	22	reaction	reaction	NOUN
eurjchem-940	108	23	between	between	ADP
eurjchem-940	108	24	the	the	DET
eurjchem-940	108	25	solvent	solvent	NOUN
eurjchem-940	108	26	and	and	CCONJ
eurjchem-940	108	27	the	the	DET
eurjchem-940	108	28	base	base	NOUN
eurjchem-940	108	29	,	,	PUNCT
eurjchem-940	108	30	are	be	AUX
eurjchem-940	108	31	less	less	ADV
eurjchem-940	108	32	efficient	efficient	ADJ
eurjchem-940	108	33	in	in	ADP
eurjchem-940	108	34	reducing	reduce	VERB
eurjchem-940	108	35	the	the	DET
eurjchem-940	108	36	palladium	palladium	NOUN
eurjchem-940	108	37	complex	complex	NOUN
eurjchem-940	108	38	than	than	ADP
eurjchem-940	108	39	kot‐bu	kot‐bu	NOUN
eurjchem-940	108	40	(	(	PUNCT
eurjchem-940	108	41	entries	entry	NOUN
eurjchem-940	108	42	9	9	NUM
eurjchem-940	108	43	and	and	CCONJ
eurjchem-940	108	44	10	10	NUM
eurjchem-940	108	45	vs.	vs.	ADP
eurjchem-940	108	46	12	12	NUM
eurjchem-940	108	47	)	)	PUNCT
eurjchem-940	108	48	.	.	PUNCT
eurjchem-940	109	1	the	the	DET
eurjchem-940	109	2	substrate	substrate	NOUN
eurjchem-940	109	3	scope	scope	NOUN
eurjchem-940	109	4	was	be	AUX
eurjchem-940	109	5	explored	explore	VERB
eurjchem-940	109	6	,	,	PUNCT
eurjchem-940	109	7	finding	find	VERB
eurjchem-940	109	8	out	out	ADP
eurjchem-940	109	9	that	that	DET
eurjchem-940	109	10	catalyst	catalyst	NOUN
eurjchem-940	109	11	2	2	NUM
eurjchem-940	109	12	shows	show	VERB
eurjchem-940	109	13	a	a	DET
eurjchem-940	109	14	good	good	ADJ
eurjchem-940	109	15	catalytic	catalytic	ADJ
eurjchem-940	109	16	activity	activity	NOUN
eurjchem-940	109	17	for	for	ADP
eurjchem-940	109	18	activated	activated	ADJ
eurjchem-940	109	19	aryl	aryl	NOUN
eurjchem-940	109	20	chlorides	chloride	NOUN
eurjchem-940	109	21	,	,	PUNCT
eurjchem-940	109	22	table	table	NOUN
eurjchem-940	109	23	2	2	NUM
eurjchem-940	109	24	(	(	PUNCT
eurjchem-940	109	25	entries	entry	NOUN
eurjchem-940	109	26	9	9	NUM
eurjchem-940	109	27	and	and	CCONJ
eurjchem-940	109	28	10	10	NUM
eurjchem-940	109	29	)	)	PUNCT
eurjchem-940	109	30	.	.	PUNCT
eurjchem-940	110	1	however	however	ADV
eurjchem-940	110	2	,	,	PUNCT
eurjchem-940	110	3	under	under	ADP
eurjchem-940	110	4	these	these	DET
eurjchem-940	110	5	conditions	condition	NOUN
eurjchem-940	110	6	,	,	PUNCT
eurjchem-940	110	7	complex	complex	ADJ
eurjchem-940	110	8	2	2	NUM
eurjchem-940	110	9	provides	provide	VERB
eurjchem-940	110	10	moderate	moderate	ADJ
eurjchem-940	110	11	yields	yield	NOUN
eurjchem-940	110	12	for	for	ADP
eurjchem-940	110	13	non‐activated	non‐activated	ADJ
eurjchem-940	110	14	aryl	aryl	NOUN
eurjchem-940	110	15	chlorides	chloride	NOUN
eurjchem-940	110	16	,	,	PUNCT
eurjchem-940	110	17	(	(	PUNCT
eurjchem-940	110	18	entries	entry	NOUN
eurjchem-940	110	19	8	8	NUM
eurjchem-940	110	20	and	and	CCONJ
eurjchem-940	110	21	11	11	NUM
eurjchem-940	110	22	)	)	PUNCT
eurjchem-940	110	23	.	.	PUNCT
eurjchem-940	111	1	nevertheless	nevertheless	ADV
eurjchem-940	111	2	,	,	PUNCT
eurjchem-940	111	3	the	the	DET
eurjchem-940	111	4	catalyst	catalyst	NOUN
eurjchem-940	111	5	shows	show	VERB
eurjchem-940	111	6	a	a	DET
eurjchem-940	111	7	good	good	ADJ
eurjchem-940	111	8	substrate	substrate	NOUN
eurjchem-940	111	9	scope	scope	NOUN
eurjchem-940	111	10	for	for	ADP
eurjchem-940	111	11	aryl	aryl	NOUN
eurjchem-940	111	12	bromides	bromide	NOUN
eurjchem-940	111	13	with	with	ADP
eurjchem-940	111	14	excellent	excellent	ADJ
eurjchem-940	111	15	yields	yield	NOUN
eurjchem-940	111	16	,	,	PUNCT
eurjchem-940	111	17	even	even	ADV
eurjchem-940	111	18	for	for	ADP
eurjchem-940	111	19	deactivated	deactivated	ADJ
eurjchem-940	111	20	substrates	substrate	NOUN
eurjchem-940	111	21	(	(	PUNCT
eurjchem-940	111	22	entries	entry	NOUN
eurjchem-940	111	23	3	3	NUM
eurjchem-940	111	24	to	to	PART
eurjchem-940	111	25	5	5	NUM
eurjchem-940	111	26	)	)	PUNCT
eurjchem-940	111	27	.	.	PUNCT
eurjchem-940	112	1	compared	compare	VERB
eurjchem-940	112	2	with	with	ADP
eurjchem-940	112	3	other	other	ADJ
eurjchem-940	112	4	symmetric	symmetric	ADJ
eurjchem-940	112	5	[	[	X
eurjchem-940	112	6	28,29	28,29	X
eurjchem-940	112	7	]	]	PUNCT
eurjchem-940	112	8	and	and	CCONJ
eurjchem-940	112	9	non‐symmetric	non‐symmetric	ADJ
eurjchem-940	112	10	catalysts	catalyst	NOUN
eurjchem-940	112	11	[	[	X
eurjchem-940	112	12	30,31	30,31	NOUN
eurjchem-940	112	13	]	]	PUNCT
eurjchem-940	112	14	,	,	PUNCT
eurjchem-940	112	15	complex	complex	ADJ
eurjchem-940	112	16	2	2	NUM
eurjchem-940	112	17	performs	perform	VERB
eurjchem-940	112	18	better	well	ADV
eurjchem-940	112	19	,	,	PUNCT
eurjchem-940	112	20	working	work	VERB
eurjchem-940	112	21	under	under	ADP
eurjchem-940	112	22	milder	mild	ADJ
eurjchem-940	112	23	conditions	condition	NOUN
eurjchem-940	112	24	and	and	CCONJ
eurjchem-940	112	25	wider	wide	ADJ
eurjchem-940	112	26	substrate	substrate	NOUN
eurjchem-940	112	27	scope	scope	NOUN
eurjchem-940	112	28	.	.	PUNCT
eurjchem-940	113	1	the	the	DET
eurjchem-940	113	2	bulkiness	bulkiness	NOUN
eurjchem-940	113	3	of	of	ADP
eurjchem-940	113	4	the	the	DET
eurjchem-940	113	5	substituents	substituent	NOUN
eurjchem-940	113	6	distort	distort	VERB
eurjchem-940	113	7	their	their	PRON
eurjchem-940	113	8	position	position	NOUN
eurjchem-940	113	9	in	in	ADP
eurjchem-940	113	10	the	the	DET
eurjchem-940	113	11	complex	complex	NOUN
eurjchem-940	113	12	,	,	PUNCT
eurjchem-940	113	13	making	make	VERB
eurjchem-940	113	14	the	the	DET
eurjchem-940	113	15	isopropyl	isopropyl	NOUN
eurjchem-940	113	16	and	and	CCONJ
eurjchem-940	113	17	phenyl	phenyl	NOUN
eurjchem-940	113	18	groups	group	NOUN
eurjchem-940	113	19	magnetically	magnetically	ADV
eurjchem-940	113	20	non‐equivalent	non‐equivalent	ADV
eurjchem-940	113	21	,	,	PUNCT
eurjchem-940	113	22	as	as	SCONJ
eurjchem-940	113	23	it	it	PRON
eurjchem-940	113	24	is	be	AUX
eurjchem-940	113	25	shown	show	VERB
eurjchem-940	113	26	by	by	ADP
eurjchem-940	113	27	the	the	DET
eurjchem-940	113	28	1h	1h	NUM
eurjchem-940	113	29	and	and	CCONJ
eurjchem-940	113	30	13c	13c	NOUN
eurjchem-940	113	31	nmr	nmr	NOUN
eurjchem-940	113	32	spectra	spectra	NOUN
eurjchem-940	113	33	of	of	ADP
eurjchem-940	113	34	complex	complex	ADJ
eurjchem-940	113	35	2	2	NUM
eurjchem-940	113	36	.	.	PUNCT
eurjchem-940	113	37	intrigued	intrigue	VERB
eurjchem-940	113	38	for	for	ADP
eurjchem-940	113	39	the	the	DET
eurjchem-940	113	40	nmr	nmr	NOUN
eurjchem-940	113	41	results	result	NOUN
eurjchem-940	113	42	,	,	PUNCT
eurjchem-940	113	43	we	we	PRON
eurjchem-940	113	44	wanted	want	VERB
eurjchem-940	113	45	to	to	PART
eurjchem-940	113	46	observe	observe	VERB
eurjchem-940	113	47	the	the	DET
eurjchem-940	113	48	spatial	spatial	ADJ
eurjchem-940	113	49	distributions	distribution	NOUN
eurjchem-940	113	50	of	of	ADP
eurjchem-940	113	51	the	the	DET
eurjchem-940	113	52	groups	group	NOUN
eurjchem-940	113	53	around	around	ADP
eurjchem-940	113	54	the	the	DET
eurjchem-940	113	55	palladium	palladium	NOUN
eurjchem-940	113	56	center	center	NOUN
eurjchem-940	113	57	in	in	ADP
eurjchem-940	113	58	the	the	DET
eurjchem-940	113	59	solid	solid	ADJ
eurjchem-940	113	60	state	state	NOUN
eurjchem-940	113	61	.	.	PUNCT
eurjchem-940	114	1	crystals	crystal	NOUN
eurjchem-940	114	2	suitable	suitable	ADJ
eurjchem-940	114	3	for	for	ADP
eurjchem-940	114	4	single‐crystal	single‐crystal	ADJ
eurjchem-940	114	5	x‐ray	x‐ray	PROPN
eurjchem-940	114	6	diffraction	diffraction	NOUN
eurjchem-940	114	7	were	be	AUX
eurjchem-940	114	8	obtained	obtain	VERB
eurjchem-940	114	9	from	from	ADP
eurjchem-940	114	10	acetone	acetone	NOUN
eurjchem-940	114	11	,	,	PUNCT
eurjchem-940	114	12	figure	figure	NOUN
eurjchem-940	114	13	1	1	NUM
eurjchem-940	114	14	.	.	PUNCT
eurjchem-940	115	1	in	in	ADP
eurjchem-940	115	2	this	this	DET
eurjchem-940	115	3	structure	structure	NOUN
eurjchem-940	115	4	,	,	PUNCT
eurjchem-940	115	5	the	the	DET
eurjchem-940	115	6	isopropyl	isopropyl	NOUN
eurjchem-940	115	7	and	and	CCONJ
eurjchem-940	115	8	phenyl	phenyl	NOUN
eurjchem-940	115	9	groups	group	NOUN
eurjchem-940	115	10	are	be	AUX
eurjchem-940	115	11	above	above	ADP
eurjchem-940	115	12	and	and	CCONJ
eurjchem-940	115	13	below	below	ADP
eurjchem-940	115	14	the	the	DET
eurjchem-940	115	15	plane	plane	NOUN
eurjchem-940	115	16	,	,	PUNCT
eurjchem-940	115	17	fitting	fit	VERB
eurjchem-940	115	18	around	around	ADP
eurjchem-940	115	19	the	the	DET
eurjchem-940	115	20	metal	metal	NOUN
eurjchem-940	115	21	center	center	NOUN
eurjchem-940	115	22	.	.	PUNCT
eurjchem-940	116	1	however	however	ADV
eurjchem-940	116	2	,	,	PUNCT
eurjchem-940	116	3	they	they	PRON
eurjchem-940	116	4	do	do	AUX
eurjchem-940	116	5	not	not	PART
eurjchem-940	116	6	surround	surround	VERB
eurjchem-940	116	7	tightly	tightly	ADV
eurjchem-940	116	8	the	the	DET
eurjchem-940	116	9	metal	metal	NOUN
eurjchem-940	116	10	center	center	NOUN
eurjchem-940	116	11	as	as	ADP
eurjchem-940	116	12	in	in	ADP
eurjchem-940	116	13	other	other	ADJ
eurjchem-940	116	14	cases	case	NOUN
eurjchem-940	116	15	[	[	X
eurjchem-940	116	16	8,10	8,10	X
eurjchem-940	116	17	]	]	PUNCT
eurjchem-940	116	18	.	.	PUNCT
eurjchem-940	117	1	this	this	DET
eurjchem-940	117	2	fact	fact	NOUN
eurjchem-940	117	3	could	could	AUX
eurjchem-940	117	4	explain	explain	VERB
eurjchem-940	117	5	why	why	SCONJ
eurjchem-940	117	6	the	the	DET
eurjchem-940	117	7	catalyst	catalyst	NOUN
eurjchem-940	117	8	is	be	AUX
eurjchem-940	117	9	active	active	ADJ
eurjchem-940	117	10	for	for	ADP
eurjchem-940	117	11	aryl	aryl	NOUN
eurjchem-940	117	12	bromides	bromide	NOUN
eurjchem-940	117	13	and	and	CCONJ
eurjchem-940	117	14	activated	activate	VERB
eurjchem-940	117	15	aryl	aryl	NOUN
eurjchem-940	117	16	chlorides	chloride	NOUN
eurjchem-940	117	17	,	,	PUNCT
eurjchem-940	117	18	but	but	CCONJ
eurjchem-940	117	19	moderately	moderately	ADV
eurjchem-940	117	20	active	active	ADJ
eurjchem-940	117	21	for	for	ADP
eurjchem-940	117	22	non‐activated	non‐activate	VERB
eurjchem-940	117	23	aryl	aryl	NOUN
eurjchem-940	117	24	chlorides	chloride	NOUN
eurjchem-940	117	25	,	,	PUNCT
eurjchem-940	117	26	under	under	ADP
eurjchem-940	117	27	the	the	DET
eurjchem-940	117	28	conditions	condition	NOUN
eurjchem-940	117	29	employed	employ	VERB
eurjchem-940	117	30	.	.	PUNCT
eurjchem-940	118	1	in	in	ADP
eurjchem-940	118	2	fact	fact	NOUN
eurjchem-940	118	3	,	,	PUNCT
eurjchem-940	118	4	catalysts	catalyst	NOUN
eurjchem-940	118	5	with	with	ADP
eurjchem-940	118	6	more	more	ADV
eurjchem-940	118	7	sterically	sterically	ADV
eurjchem-940	118	8	demanding	demand	VERB
eurjchem-940	118	9	ligands	ligand	NOUN
eurjchem-940	118	10	are	be	AUX
eurjchem-940	118	11	more	more	ADV
eurjchem-940	118	12	active	active	ADJ
eurjchem-940	118	13	even	even	ADV
eurjchem-940	118	14	for	for	ADP
eurjchem-940	118	15	sterically	sterically	ADV
eurjchem-940	118	16	demanding	demand	VERB
eurjchem-940	118	17	aryl	aryl	NOUN
eurjchem-940	118	18	chlorides	chloride	NOUN
eurjchem-940	118	19	[	[	X
eurjchem-940	118	20	32,33	32,33	NUM
eurjchem-940	118	21	]	]	PUNCT
eurjchem-940	118	22	.	.	PUNCT
eurjchem-940	119	1	the	the	DET
eurjchem-940	119	2	bulkiness	bulkiness	NOUN
eurjchem-940	119	3	around	around	ADP
eurjchem-940	119	4	the	the	DET
eurjchem-940	119	5	metal	metal	NOUN
eurjchem-940	119	6	could	could	AUX
eurjchem-940	119	7	be	be	AUX
eurjchem-940	119	8	responsible	responsible	ADJ
eurjchem-940	119	9	for	for	ADP
eurjchem-940	119	10	the	the	DET
eurjchem-940	119	11	catalytic	catalytic	ADJ
eurjchem-940	119	12	activity	activity	NOUN
eurjchem-940	119	13	of	of	ADP
eurjchem-940	119	14	the	the	DET
eurjchem-940	119	15	complex	complex	NOUN
eurjchem-940	119	16	.	.	PUNCT
eurjchem-940	120	1	currently	currently	ADV
eurjchem-940	120	2	,	,	PUNCT
eurjchem-940	120	3	we	we	PRON
eurjchem-940	120	4	are	be	AUX
eurjchem-940	120	5	synthesizing	synthesize	VERB
eurjchem-940	120	6	other	other	ADJ
eurjchem-940	120	7	complexes	complex	NOUN
eurjchem-940	120	8	with	with	ADP
eurjchem-940	120	9	different	different	ADJ
eurjchem-940	120	10	groups	group	NOUN
eurjchem-940	120	11	around	around	ADP
eurjchem-940	120	12	the	the	DET
eurjchem-940	120	13	carbene	carbene	NOUN
eurjchem-940	120	14	.	.	PUNCT
eurjchem-940	121	1	4	4	X
eurjchem-940	121	2	.	.	X
eurjchem-940	121	3	conclusion	conclusion	NOUN
eurjchem-940	121	4	we	we	PRON
eurjchem-940	121	5	have	have	AUX
eurjchem-940	121	6	synthesized	synthesize	VERB
eurjchem-940	121	7	a	a	DET
eurjchem-940	121	8	unsymmetrical	unsymmetrical	ADJ
eurjchem-940	121	9	,	,	PUNCT
eurjchem-940	121	10	well‐defined	well‐defined	ADJ
eurjchem-940	121	11	n‐	n‐	NOUN
eurjchem-940	121	12	heterocyclic	heterocyclic	NOUN
eurjchem-940	121	13	carbene‐palladium‐η3‐allyl	carbene‐palladium‐η3‐allyl	ADJ
eurjchem-940	121	14	chloride	chloride	NOUN
eurjchem-940	121	15	complex	complex	NOUN
eurjchem-940	121	16	,	,	PUNCT
eurjchem-940	121	17	the	the	DET
eurjchem-940	121	18	catalysts	catalyst	NOUN
eurjchem-940	121	19	at	at	ADP
eurjchem-940	121	20	a	a	DET
eurjchem-940	121	21	concentration	concentration	NOUN
eurjchem-940	121	22	of	of	ADP
eurjchem-940	121	23	1	1	NUM
eurjchem-940	121	24	mol	mol	NOUN
eurjchem-940	121	25	%	%	NOUN
eurjchem-940	121	26	promotes	promote	VERB
eurjchem-940	121	27	the	the	DET
eurjchem-940	121	28	cross‐	cross‐	NOUN
eurjchem-940	121	29	coupling	coupling	NOUN
eurjchem-940	121	30	of	of	ADP
eurjchem-940	121	31	aryl	aryl	NOUN
eurjchem-940	121	32	bromides	bromide	NOUN
eurjchem-940	121	33	and	and	CCONJ
eurjchem-940	121	34	activated	activate	VERB
eurjchem-940	121	35	aryl	aryl	NOUN
eurjchem-940	121	36	chlorides	chloride	NOUN
eurjchem-940	121	37	with	with	ADP
eurjchem-940	121	38	boronic	boronic	ADJ
eurjchem-940	121	39	acids	acid	NOUN
eurjchem-940	121	40	,	,	PUNCT
eurjchem-940	121	41	under	under	ADP
eurjchem-940	121	42	moderate	moderate	ADJ
eurjchem-940	121	43	conditions	condition	NOUN
eurjchem-940	121	44	,	,	PUNCT
eurjchem-940	121	45	with	with	ADP
eurjchem-940	121	46	high	high	ADJ
eurjchem-940	121	47	yields	yield	NOUN
eurjchem-940	121	48	.	.	PUNCT
eurjchem-940	122	1	broekemier	broekemier	NOUN
eurjchem-940	122	2	et	et	PROPN
eurjchem-940	122	3	al	al	PROPN
eurjchem-940	122	4	.	.	PUNCT
eurjchem-940	122	5	/	/	SYM
eurjchem-940	122	6	european	european	PROPN
eurjchem-940	122	7	journal	journal	PROPN
eurjchem-940	122	8	of	of	ADP
eurjchem-940	122	9	chemistry	chemistry	NOUN
eurjchem-940	122	10	5	5	NUM
eurjchem-940	122	11	(	(	PUNCT
eurjchem-940	122	12	1	1	NUM
eurjchem-940	122	13	)	)	PUNCT
eurjchem-940	122	14	(	(	PUNCT
eurjchem-940	122	15	2014	2014	NUM
eurjchem-940	122	16	)	)	PUNCT
eurjchem-940	122	17	162‐166	162‐166	PROPN
eurjchem-940	122	18	165	165	NUM
eurjchem-940	122	19	table	table	NOUN
eurjchem-940	122	20	2	2	NUM
eurjchem-940	122	21	.	.	PUNCT
eurjchem-940	122	22	suzuki‐miyaura	suzuki‐miyaura	PROPN
eurjchem-940	122	23	cross‐coupling	cross‐coupling	NOUN
eurjchem-940	122	24	of	of	ADP
eurjchem-940	122	25	aryl	aryl	NOUN
eurjchem-940	122	26	halides	halide	NOUN
eurjchem-940	122	27	with	with	ADP
eurjchem-940	122	28	boronic	boronic	ADJ
eurjchem-940	122	29	acids	acid	NOUN
eurjchem-940	122	30	,	,	PUNCT
eurjchem-940	122	31	catalyzed	catalyze	VERB
eurjchem-940	122	32	by	by	ADP
eurjchem-940	122	33	complex2	complex2	PROPN
eurjchem-940	122	34	.	.	PUNCT
eurjchem-940	123	1	entry	entry	NOUN
eurjchem-940	123	2	a	a	DET
eurjchem-940	123	3	aryl	aryl	NOUN
eurjchem-940	123	4	halide	halide	NOUN
eurjchem-940	123	5	product	product	NOUN
eurjchem-940	123	6	yield	yield	NOUN
eurjchem-940	123	7	(	(	PUNCT
eurjchem-940	123	8	%	%	INTJ
eurjchem-940	123	9	)	)	PUNCT
eurjchem-940	123	10	b	b	NOUN
eurjchem-940	123	11	1	1	NUM
eurjchem-940	123	12	93.5	93.5	NUM
eurjchem-940	123	13	2	2	NUM
eurjchem-940	123	14	95.1	95.1	NUM
eurjchem-940	123	15	3	3	NUM
eurjchem-940	123	16	80.4	80.4	NUM
eurjchem-940	123	17	4	4	NUM
eurjchem-940	123	18	och3ph	och3ph	PROPN
eurjchem-940	123	19	94.2	94.2	NUM
eurjchem-940	123	20	5	5	NUM
eurjchem-940	123	21	90.3	90.3	NUM
eurjchem-940	123	22	6	6	NUM
eurjchem-940	123	23	60.8	60.8	NUM
eurjchem-940	123	24	(	(	PUNCT
eurjchem-940	123	25	93.0	93.0	NUM
eurjchem-940	123	26	)	)	PUNCT
eurjchem-940	123	27	c	c	NOUN
eurjchem-940	123	28	7	7	NUM
eurjchem-940	123	29	50.1	50.1	NUM
eurjchem-940	123	30	8	8	NUM
eurjchem-940	123	31	95.0	95.0	NUM
eurjchem-940	123	32	9	9	NUM
eurjchem-940	123	33	93.0	93.0	NUM
eurjchem-940	123	34	10	10	NUM
eurjchem-940	123	35	48.5	48.5	NUM
eurjchem-940	123	36	a	a	DET
eurjchem-940	123	37	reaction	reaction	NOUN
eurjchem-940	123	38	conditions	condition	NOUN
eurjchem-940	123	39	:	:	PUNCT
eurjchem-940	123	40	arx	arx	PROPN
eurjchem-940	123	41	(	(	PUNCT
eurjchem-940	123	42	1	1	NUM
eurjchem-940	123	43	mmol	mmol	NOUN
eurjchem-940	123	44	)	)	PUNCT
eurjchem-940	123	45	,	,	PUNCT
eurjchem-940	123	46	arb(oh)2	arb(oh)2	NOUN
eurjchem-940	123	47	(	(	PUNCT
eurjchem-940	123	48	1.3	1.3	NUM
eurjchem-940	123	49	mmol	mmol	NOUN
eurjchem-940	123	50	)	)	PUNCT
eurjchem-940	123	51	,	,	PUNCT
eurjchem-940	123	52	kotbu	kotbu	PROPN
eurjchem-940	123	53	/	/	SYM
eurjchem-940	123	54	k3po4	k3po4	NOUN
eurjchem-940	123	55	(	(	PUNCT
eurjchem-940	123	56	1.1/1.5	1.1/1.5	NUM
eurjchem-940	123	57	equiv	equiv	NOUN
eurjchem-940	123	58	)	)	PUNCT
eurjchem-940	123	59	,	,	PUNCT
eurjchem-940	123	60	3	3	NUM
eurjchem-940	123	61	ml	ml	NOUN
eurjchem-940	123	62	of	of	ADP
eurjchem-940	123	63	iproh	iproh	NOUN
eurjchem-940	123	64	,	,	PUNCT
eurjchem-940	123	65	2	2	NUM
eurjchem-940	123	66	h	h	NOUN
eurjchem-940	123	67	,	,	PUNCT
eurjchem-940	123	68	50	50	NUM
eurjchem-940	123	69	°	°	NOUN
eurjchem-940	123	70	c	c	NOUN
eurjchem-940	123	71	.	.	PUNCT
eurjchem-940	124	1	b	b	X
eurjchem-940	124	2	average	average	ADJ
eurjchem-940	124	3	yield	yield	NOUN
eurjchem-940	124	4	of	of	ADP
eurjchem-940	124	5	two	two	NUM
eurjchem-940	124	6	experiments	experiment	NOUN
eurjchem-940	124	7	,	,	PUNCT
eurjchem-940	124	8	isolated	isolated	ADJ
eurjchem-940	124	9	yields	yield	NOUN
eurjchem-940	124	10	.	.	PUNCT
eurjchem-940	125	1	c	c	PROPN
eurjchem-940	125	2	determined	determine	VERB
eurjchem-940	125	3	by	by	ADP
eurjchem-940	125	4	nmr	nmr	NOUN
eurjchem-940	125	5	.	.	PUNCT
eurjchem-940	126	1	the	the	DET
eurjchem-940	126	2	straight	straight	ADJ
eurjchem-940	126	3	forward	forward	ADJ
eurjchem-940	126	4	synthesis	synthesis	NOUN
eurjchem-940	126	5	makes	make	VERB
eurjchem-940	126	6	it	it	PRON
eurjchem-940	126	7	attractive	attractive	ADJ
eurjchem-940	126	8	to	to	PART
eurjchem-940	126	9	prepare	prepare	VERB
eurjchem-940	126	10	families	family	NOUN
eurjchem-940	126	11	of	of	ADP
eurjchem-940	126	12	n‐heterocyclic	n‐heterocyclic	CCONJ
eurjchem-940	126	13	carbene	carbene	NOUN
eurjchem-940	126	14	(	(	PUNCT
eurjchem-940	126	15	nhc	nhc	NOUN
eurjchem-940	126	16	)	)	PUNCT
eurjchem-940	126	17	precursors	precursor	NOUN
eurjchem-940	126	18	to	to	PART
eurjchem-940	126	19	moderate	moderate	VERB
eurjchem-940	126	20	the	the	DET
eurjchem-940	126	21	steric	steric	ADJ
eurjchem-940	126	22	characteristics	characteristic	NOUN
eurjchem-940	126	23	and	and	CCONJ
eurjchem-940	126	24	electronic	electronic	ADJ
eurjchem-940	126	25	properties	property	NOUN
eurjchem-940	126	26	around	around	ADP
eurjchem-940	126	27	a	a	DET
eurjchem-940	126	28	metal	metal	NOUN
eurjchem-940	126	29	center‐nhc	center‐nhc	NOUN
eurjchem-940	126	30	complex	complex	ADJ
eurjchem-940	126	31	.	.	PUNCT
eurjchem-940	127	1	figure	figure	NOUN
eurjchem-940	127	2	1	1	NUM
eurjchem-940	127	3	.	.	PUNCT
eurjchem-940	128	1	ortep	ortep	NOUN
eurjchem-940	128	2	of	of	ADP
eurjchem-940	128	3	the	the	DET
eurjchem-940	128	4	complex	complex	ADJ
eurjchem-940	128	5	2	2	NUM
eurjchem-940	128	6	.	.	PUNCT
eurjchem-940	129	1	acknowledgements	acknowledgement	NOUN
eurjchem-940	129	2	support	support	NOUN
eurjchem-940	129	3	of	of	ADP
eurjchem-940	129	4	this	this	DET
eurjchem-940	129	5	work	work	NOUN
eurjchem-940	129	6	by	by	ADP
eurjchem-940	129	7	an	an	DET
eurjchem-940	129	8	award	award	NOUN
eurjchem-940	129	9	from	from	ADP
eurjchem-940	129	10	the	the	DET
eurjchem-940	129	11	research	research	NOUN
eurjchem-940	129	12	corporation	corporation	NOUN
eurjchem-940	129	13	for	for	ADP
eurjchem-940	129	14	science	science	NOUN
eurjchem-940	129	15	advancement	advancement	NOUN
eurjchem-940	129	16	is	be	AUX
eurjchem-940	129	17	gratefully	gratefully	ADV
eurjchem-940	129	18	acknowledged	acknowledge	VERB
eurjchem-940	129	19	.	.	PUNCT
eurjchem-940	130	1	support	support	NOUN
eurjchem-940	130	2	from	from	ADP
eurjchem-940	130	3	unk	unk	NOUN
eurjchem-940	130	4	through	through	ADP
eurjchem-940	130	5	the	the	DET
eurjchem-940	130	6	office	office	NOUN
eurjchem-940	130	7	of	of	ADP
eurjchem-940	130	8	sponsored	sponsor	VERB
eurjchem-940	130	9	programs	program	NOUN
eurjchem-940	130	10	and	and	CCONJ
eurjchem-940	130	11	the	the	DET
eurjchem-940	130	12	department	department	NOUN
eurjchem-940	130	13	of	of	ADP
eurjchem-940	130	14	chemistry	chemistry	NOUN
eurjchem-940	130	15	is	be	AUX
eurjchem-940	130	16	also	also	ADV
eurjchem-940	130	17	acknowledged	acknowledge	VERB
eurjchem-940	130	18	.	.	PUNCT
eurjchem-940	131	1	the	the	DET
eurjchem-940	131	2	authors	author	NOUN
eurjchem-940	131	3	thank	thank	VERB
eurjchem-940	131	4	professor	professor	PROPN
eurjchem-940	131	5	bruce	bruce	PROPN
eurjchem-940	131	6	storhoff	storhoff	PROPN
eurjchem-940	131	7	for	for	ADP
eurjchem-940	131	8	his	his	PRON
eurjchem-940	131	9	encouragement	encouragement	NOUN
eurjchem-940	131	10	.	.	PUNCT
eurjchem-940	132	1	supplementary	supplementary	ADJ
eurjchem-940	132	2	material	material	PROPN
eurjchem-940	132	3	ccdc	ccdc	PROPN
eurjchem-940	132	4	959838	959838	NUM
eurjchem-940	132	5	contains	contain	VERB
eurjchem-940	132	6	the	the	DET
eurjchem-940	132	7	supplementary	supplementary	ADJ
eurjchem-940	132	8	crystallographic	crystallographic	ADJ
eurjchem-940	132	9	data	datum	NOUN
eurjchem-940	132	10	for	for	ADP
eurjchem-940	132	11	this	this	DET
eurjchem-940	132	12	paper	paper	NOUN
eurjchem-940	132	13	.	.	PUNCT
eurjchem-940	133	1	these	these	DET
eurjchem-940	133	2	data	datum	NOUN
eurjchem-940	133	3	can	can	AUX
eurjchem-940	133	4	be	be	AUX
eurjchem-940	133	5	obtained	obtain	VERB
eurjchem-940	133	6	free	free	ADJ
eurjchem-940	133	7	of	of	ADP
eurjchem-940	133	8	charge	charge	NOUN
eurjchem-940	133	9	via	via	ADP
eurjchem-940	133	10	www.ccdc.cam.ac.uk/data_request/cif	www.ccdc.cam.ac.uk/data_request/cif	NOUN
eurjchem-940	133	11	,	,	PUNCT
eurjchem-940	133	12	or	or	CCONJ
eurjchem-940	133	13	by	by	ADP
eurjchem-940	133	14	e‐mailing	e‐maile	VERB
eurjchem-940	133	15	data_request@ccdc.cam.ac.uk	data_request@ccdc.cam.ac.uk	VERB
eurjchem-940	133	16	,	,	PUNCT
eurjchem-940	133	17	or	or	CCONJ
eurjchem-940	133	18	by	by	ADP
eurjchem-940	133	19	contacting	contact	VERB
eurjchem-940	133	20	the	the	DET
eurjchem-940	133	21	cambridge	cambridge	PROPN
eurjchem-940	133	22	crystallographic	crystallographic	PROPN
eurjchem-940	133	23	data	data	PROPN
eurjchem-940	133	24	centre	centre	NOUN
eurjchem-940	133	25	,	,	PUNCT
eurjchem-940	133	26	12	12	NUM
eurjchem-940	133	27	union	union	NOUN
eurjchem-940	133	28	road	road	NOUN
eurjchem-940	133	29	,	,	PUNCT
eurjchem-940	133	30	cambridge	cambridge	PROPN
eurjchem-940	133	31	cb2	cb2	PROPN
eurjchem-940	133	32	1ez	1ez	PROPN
eurjchem-940	133	33	,	,	PUNCT
eurjchem-940	133	34	uk	uk	PROPN
eurjchem-940	133	35	;	;	PUNCT
eurjchem-940	133	36	fax	fax	NOUN
eurjchem-940	133	37	:	:	PUNCT
eurjchem-940	133	38	+44(0)1223‐336033	+44(0)1223‐336033	ADJ
eurjchem-940	133	39	.	.	PUNCT
eurjchem-940	133	40	references	reference	NOUN
eurjchem-940	133	41	[	[	X
eurjchem-940	133	42	1	1	NUM
eurjchem-940	133	43	]	]	PUNCT
eurjchem-940	133	44	.	.	PUNCT
eurjchem-940	134	1	suzuki	suzuki	PROPN
eurjchem-940	134	2	,	,	PUNCT
eurjchem-940	134	3	a.	a.	PROPN
eurjchem-940	134	4	j.	j.	PROPN
eurjchem-940	134	5	organomet	organomet	PROPN
eurjchem-940	134	6	.	.	PUNCT
eurjchem-940	135	1	chem	chem	NOUN
eurjchem-940	135	2	.	.	PUNCT
eurjchem-940	136	1	1999	1999	NUM
eurjchem-940	136	2	,	,	PUNCT
eurjchem-940	136	3	576(1‐2	576(1‐2	NUM
eurjchem-940	136	4	)	)	PUNCT
eurjchem-940	136	5	,	,	PUNCT
eurjchem-940	136	6	147‐168	147‐168	NUM
eurjchem-940	136	7	.	.	PUNCT
eurjchem-940	137	1	[	[	X
eurjchem-940	137	2	2	2	NUM
eurjchem-940	137	3	]	]	PUNCT
eurjchem-940	137	4	.	.	PUNCT
eurjchem-940	137	5	miyaura	miyaura	PROPN
eurjchem-940	137	6	,	,	PUNCT
eurjchem-940	137	7	n.	n.	NOUN
eurjchem-940	137	8	;	;	PUNCT
eurjchem-940	137	9	suzuki	suzuki	PROPN
eurjchem-940	137	10	chem	chem	PROPN
eurjchem-940	137	11	.	.	PUNCT
eurjchem-940	138	1	rev	rev	PROPN
eurjchem-940	138	2	.	.	PROPN
eurjchem-940	138	3	1995	1995	NUM
eurjchem-940	138	4	,	,	PUNCT
eurjchem-940	138	5	95	95	NUM
eurjchem-940	138	6	,	,	PUNCT
eurjchem-940	138	7	2457‐2483	2457‐2483	NUM
eurjchem-940	138	8	.	.	PUNCT
eurjchem-940	139	1	[	[	X
eurjchem-940	139	2	3	3	NUM
eurjchem-940	139	3	]	]	PUNCT
eurjchem-940	139	4	.	.	PUNCT
eurjchem-940	140	1	suzuki	suzuki	PROPN
eurjchem-940	140	2	,	,	PUNCT
eurjchem-940	140	3	a.	a.	NOUN
eurjchem-940	140	4	overview	overview	NOUN
eurjchem-940	140	5	of	of	ADP
eurjchem-940	140	6	the	the	DET
eurjchem-940	140	7	suzuki	suzuki	NOUN
eurjchem-940	140	8	protocol	protocol	NOUN
eurjchem-940	140	9	with	with	ADP
eurjchem-940	140	10	b	b	PROPN
eurjchem-940	140	11	,	,	PUNCT
eurjchem-940	140	12	in	in	ADP
eurjchem-940	140	13	handbook	handbook	NOUN
eurjchem-940	140	14	of	of	ADP
eurjchem-940	140	15	organopalladium	organopalladium	NOUN
eurjchem-940	140	16	chemistry	chemistry	NOUN
eurjchem-940	140	17	for	for	ADP
eurjchem-940	140	18	organic	organic	ADJ
eurjchem-940	140	19	synthesis	synthesis	NOUN
eurjchem-940	140	20	,	,	PUNCT
eurjchem-940	140	21	e.	e.	PROPN
eurjchem-940	140	22	‐i	‐i	PROPN
eurjchem-940	140	23	.	.	PUNCT
eurjchem-940	141	1	negishi	negishi	PROPN
eurjchem-940	141	2	,	,	PUNCT
eurjchem-940	141	3	editor	editor	NOUN
eurjchem-940	141	4	.	.	PUNCT
eurjchem-940	142	1	john	john	PROPN
eurjchem-940	142	2	wiley	wiley	PROPN
eurjchem-940	142	3	&	&	CCONJ
eurjchem-940	142	4	sons	son	NOUN
eurjchem-940	142	5	,	,	PUNCT
eurjchem-940	142	6	2002	2002	NUM
eurjchem-940	142	7	,	,	PUNCT
eurjchem-940	142	8	p.	p.	NOUN
eurjchem-940	142	9	249‐262	249‐262	NUM
eurjchem-940	142	10	.	.	PUNCT
eurjchem-940	143	1	[	[	X
eurjchem-940	143	2	4	4	NUM
eurjchem-940	143	3	]	]	PUNCT
eurjchem-940	143	4	.	.	PUNCT
eurjchem-940	143	5	arduengo	arduengo	PROPN
eurjchem-940	143	6	,	,	PUNCT
eurjchem-940	143	7	a.	a.	PROPN
eurjchem-940	143	8	j.	j.	PROPN
eurjchem-940	143	9	iii	iii	PROPN
eurjchem-940	143	10	;	;	PUNCT
eurjchem-940	143	11	harlow	harlow	PROPN
eurjchem-940	143	12	,	,	PUNCT
eurjchem-940	143	13	r.	r.	PROPN
eurjchem-940	143	14	l.	l.	PROPN
eurjchem-940	143	15	;	;	PUNCT
eurjchem-940	143	16	kline	kline	PROPN
eurjchem-940	143	17	,	,	PUNCT
eurjchem-940	143	18	m.	m.	PROPN
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eurjchem-940	145	2	.	.	PUNCT
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eurjchem-940	161	2	,	,	PUNCT
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eurjchem-940	162	3	]	]	PUNCT
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eurjchem-940	170	2	.	.	PUNCT
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eurjchem-940	171	2	,	,	PUNCT
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eurjchem-940	182	2	.	.	PUNCT
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eurjchem-940	187	2	.	.	PUNCT
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eurjchem-940	188	2	,	,	PUNCT
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eurjchem-940	192	2	.	.	PUNCT
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eurjchem-940	193	2	,	,	PUNCT
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eurjchem-940	195	15	,	,	PUNCT
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eurjchem-940	195	17	a.	a.	PROPN
eurjchem-940	195	18	angew	angew	PROPN
eurjchem-940	195	19	.	.	PUNCT
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eurjchem-940	196	2	.	.	PUNCT
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eurjchem-940	197	2	.	.	PUNCT
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eurjchem-940	198	2	.	.	PROPN
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eurjchem-940	199	2	,	,	PUNCT
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eurjchem-940	199	4	,	,	PUNCT
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eurjchem-940	199	6	.	.	PUNCT
eurjchem-940	200	1	[	[	X
eurjchem-940	200	2	17	17	NUM
eurjchem-940	200	3	]	]	PUNCT
eurjchem-940	200	4	.	.	PUNCT
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eurjchem-940	201	2	,	,	PUNCT
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eurjchem-940	201	6	,	,	PUNCT
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eurjchem-940	201	14	,	,	PUNCT
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eurjchem-940	201	18	,	,	PUNCT
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eurjchem-940	201	20	;	;	PUNCT
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eurjchem-940	201	26	,	,	PUNCT
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eurjchem-940	201	30	.	.	PUNCT
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eurjchem-940	202	3	]	]	PUNCT
eurjchem-940	202	4	.	.	PUNCT
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eurjchem-940	203	2	,	,	PUNCT
eurjchem-940	203	3	h.	h.	PROPN
eurjchem-940	203	4	;	;	PUNCT
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eurjchem-940	203	6	,	,	PUNCT
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eurjchem-940	203	8	;	;	PUNCT
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eurjchem-940	203	10	,	,	PUNCT
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eurjchem-940	203	15	.	.	PUNCT
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eurjchem-940	204	2	,	,	PUNCT
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eurjchem-940	204	4	,	,	PUNCT
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eurjchem-940	204	6	.	.	PUNCT
eurjchem-940	205	1	[	[	X
eurjchem-940	205	2	19	19	NUM
eurjchem-940	205	3	]	]	PUNCT
eurjchem-940	205	4	.	.	PUNCT
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eurjchem-940	206	2	,	,	PUNCT
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eurjchem-940	206	5	;	;	PUNCT
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eurjchem-940	206	7	,	,	PUNCT
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eurjchem-940	208	3	,	,	PUNCT
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eurjchem-940	208	5	,	,	PUNCT
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eurjchem-940	208	7	.	.	PUNCT
eurjchem-940	209	1	[	[	X
eurjchem-940	209	2	20	20	NUM
eurjchem-940	209	3	]	]	PUNCT
eurjchem-940	209	4	.	.	PUNCT
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eurjchem-940	210	2	,	,	PUNCT
eurjchem-940	210	3	j.	j.	PROPN
eurjchem-940	210	4	;	;	PUNCT
eurjchem-940	210	5	kannenberg	kannenberg	PROPN
eurjchem-940	210	6	,	,	PUNCT
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eurjchem-940	210	8	;	;	PUNCT
eurjchem-940	210	9	blechert	blechert	PROPN
eurjchem-940	210	10	,	,	PUNCT
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eurjchem-940	210	13	trans	trans	PROPN
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eurjchem-940	211	2	,	,	PUNCT
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eurjchem-940	211	4	,	,	PUNCT
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eurjchem-940	211	6	.	.	PUNCT
eurjchem-940	212	1	[	[	X
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eurjchem-940	212	3	]	]	PUNCT
eurjchem-940	212	4	.	.	PUNCT
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eurjchem-940	213	2	,	,	PUNCT
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eurjchem-940	213	4	;	;	PUNCT
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eurjchem-940	213	6	,	,	PUNCT
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eurjchem-940	213	8	;	;	PUNCT
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eurjchem-940	213	10	,	,	PUNCT
eurjchem-940	213	11	l.	l.	PROPN
eurjchem-940	213	12	;	;	PUNCT
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eurjchem-940	213	14	,	,	PUNCT
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eurjchem-940	213	16	;	;	PUNCT
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eurjchem-940	213	18	,	,	PUNCT
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eurjchem-940	213	21	trans	trans	PROPN
eurjchem-940	213	22	.	.	PROPN
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eurjchem-940	214	2	,	,	PUNCT
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eurjchem-940	214	4	,	,	PUNCT
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eurjchem-940	214	6	.	.	PUNCT
eurjchem-940	215	1	[	[	X
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eurjchem-940	215	3	]	]	PUNCT
eurjchem-940	215	4	.	.	PUNCT
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eurjchem-940	216	2	,	,	PUNCT
eurjchem-940	216	3	b.	b.	PROPN
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eurjchem-940	216	5	;	;	PUNCT
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eurjchem-940	216	7	,	,	PUNCT
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eurjchem-940	216	9	;	;	PUNCT
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eurjchem-940	217	2	,	,	PUNCT
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eurjchem-940	217	4	,	,	PUNCT
eurjchem-940	217	5	5041‐	5041‐	NUM
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eurjchem-940	217	7	.	.	PUNCT
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eurjchem-940	218	3	]	]	PUNCT
eurjchem-940	218	4	.	.	PUNCT
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eurjchem-940	219	2	,	,	PUNCT
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eurjchem-940	219	5	;	;	PUNCT
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eurjchem-940	220	2	,	,	PUNCT
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eurjchem-940	220	7	,	,	PUNCT
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eurjchem-940	220	9	,	,	PUNCT
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eurjchem-940	220	12	.	.	PUNCT
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eurjchem-940	221	3	]	]	PUNCT
eurjchem-940	221	4	.	.	PUNCT
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eurjchem-940	222	2	,	,	PUNCT
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eurjchem-940	222	4	;	;	PUNCT
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eurjchem-940	222	6	,	,	PUNCT
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eurjchem-940	222	8	p.	p.	PROPN
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eurjchem-940	222	12	.	.	PUNCT
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eurjchem-940	223	2	.	.	PROPN
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eurjchem-940	223	4	,	,	PUNCT
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eurjchem-940	223	6	,	,	PUNCT
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eurjchem-940	223	8	.	.	PUNCT
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eurjchem-940	224	15	(	(	PUNCT
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eurjchem-940	224	17	)	)	PUNCT
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eurjchem-940	225	3	]	]	PUNCT
eurjchem-940	225	4	.	.	PUNCT
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eurjchem-940	226	2	,	,	PUNCT
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eurjchem-940	226	4	;	;	PUNCT
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eurjchem-940	226	6	,	,	PUNCT
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eurjchem-940	226	8	;	;	PUNCT
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eurjchem-940	226	10	,	,	PUNCT
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eurjchem-940	226	12	;	;	PUNCT
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eurjchem-940	226	14	,	,	PUNCT
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eurjchem-940	226	16	;	;	PUNCT
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eurjchem-940	226	18	,	,	PUNCT
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eurjchem-940	226	20	;	;	PUNCT
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eurjchem-940	226	22	,	,	PUNCT
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eurjchem-940	226	26	,	,	PUNCT
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eurjchem-940	226	28	,	,	PUNCT
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eurjchem-940	226	30	.	.	PUNCT
eurjchem-940	227	1	[	[	X
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eurjchem-940	227	3	]	]	PUNCT
eurjchem-940	227	4	.	.	PUNCT
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eurjchem-940	228	2	,	,	PUNCT
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eurjchem-940	228	6	;	;	PUNCT
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eurjchem-940	228	8	,	,	PUNCT
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eurjchem-940	228	14	,	,	PUNCT
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eurjchem-940	228	16	,	,	PUNCT
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eurjchem-940	228	18	.	.	PUNCT
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eurjchem-940	229	3	]	]	PUNCT
eurjchem-940	229	4	.	.	PUNCT
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eurjchem-940	230	2	,	,	PUNCT
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eurjchem-940	230	4	;	;	PUNCT
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eurjchem-940	230	10	.	.	PUNCT
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eurjchem-940	231	2	.	.	PUNCT
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eurjchem-940	232	3	,	,	PUNCT
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eurjchem-940	232	5	,	,	PUNCT
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eurjchem-940	232	7	.	.	PUNCT
eurjchem-940	233	1	[	[	X
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eurjchem-940	233	3	]	]	PUNCT
eurjchem-940	233	4	.	.	PUNCT
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eurjchem-940	234	2	,	,	PUNCT
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eurjchem-940	234	5	;	;	PUNCT
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eurjchem-940	234	7	,	,	PUNCT
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eurjchem-940	234	9	;	;	PUNCT
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eurjchem-940	234	15	;	;	PUNCT
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eurjchem-940	234	17	,	,	PUNCT
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eurjchem-940	234	22	,	,	PUNCT
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eurjchem-940	234	24	,	,	PUNCT
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eurjchem-940	235	3	]	]	PUNCT
eurjchem-940	235	4	.	.	PUNCT
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eurjchem-940	236	2	,	,	PUNCT
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eurjchem-940	236	4	;	;	PUNCT
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eurjchem-940	236	6	,	,	PUNCT
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eurjchem-940	236	9	;	;	PUNCT
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eurjchem-940	236	11	,	,	PUNCT
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eurjchem-940	236	16	.	.	PUNCT
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eurjchem-940	237	2	.	.	PUNCT
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eurjchem-940	238	2	,	,	PUNCT
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eurjchem-940	238	6	)	)	PUNCT
eurjchem-940	238	7	,	,	PUNCT
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eurjchem-940	238	9	.	.	PUNCT
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eurjchem-940	239	3	]	]	PUNCT
eurjchem-940	239	4	.	.	PUNCT
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eurjchem-940	240	2	,	,	PUNCT
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eurjchem-940	240	6	,	,	PUNCT
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eurjchem-940	240	8	x.	x.	PROPN
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eurjchem-940	240	11	,	,	PUNCT
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eurjchem-940	240	13	,	,	PUNCT
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eurjchem-940	241	3	]	]	PUNCT
eurjchem-940	241	4	.	.	PUNCT
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eurjchem-940	242	6	;	;	PUNCT
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eurjchem-940	243	2	,	,	PUNCT
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eurjchem-940	243	5	;	;	PUNCT
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eurjchem-940	243	7	,	,	PUNCT
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