id	sid	tid	token	lemma	pos
eurjchem-952	1	1	untitled	untitle	VERB
eurjchem-952	1	2	european	european	PROPN
eurjchem-952	1	3	journal	journal	PROPN
eurjchem-952	1	4	of	of	ADP
eurjchem-952	1	5	chemistry	chemistry	NOUN
eurjchem-952	1	6	5	5	NUM
eurjchem-952	1	7	(	(	PUNCT
eurjchem-952	1	8	2	2	NUM
eurjchem-952	1	9	)	)	PUNCT
eurjchem-952	1	10	(	(	PUNCT
eurjchem-952	1	11	2014	2014	NUM
eurjchem-952	1	12	)	)	PUNCT
eurjchem-952	1	13	201‐208	201‐208	NUM
eurjchem-952	1	14	european	european	ADJ
eurjchem-952	1	15	journal	journal	NOUN
eurjchem-952	1	16	of	of	ADP
eurjchem-952	1	17	chemistry	chemistry	NOUN
eurjchem-952	1	18	issn	issn	PROPN
eurjchem-952	1	19	2153‐2249	2153‐2249	PROPN
eurjchem-952	1	20	(	(	PUNCT
eurjchem-952	1	21	print	print	NOUN
eurjchem-952	1	22	)	)	PUNCT
eurjchem-952	1	23	/	/	SYM
eurjchem-952	1	24	issn	issn	PROPN
eurjchem-952	1	25	2153‐2257	2153‐2257	NUM
eurjchem-952	1	26	(	(	PUNCT
eurjchem-952	1	27	online	online	ADJ
eurjchem-952	1	28	)	)	PUNCT
eurjchem-952	1	29			NOUN
eurjchem-952	1	30	2014	2014	NUM
eurjchem-952	2	1	eurjchem	eurjchem	PROPN
eurjchem-952	2	2	publishing	publish	VERB
eurjchem-952	2	3	‐	‐	NOUN
eurjchem-952	2	4	printed	print	VERB
eurjchem-952	2	5	in	in	ADP
eurjchem-952	2	6	the	the	DET
eurjchem-952	2	7	usa	usa	PROPN
eurjchem-952	2	8	http://dx.doi.org/10.5155/eurjchem.5.2.201‐208.952	http://dx.doi.org/10.5155/eurjchem.5.2.201‐208.952	PROPN
eurjchem-952	2	9	european	european	PROPN
eurjchem-952	2	10	journal	journal	PROPN
eurjchem-952	2	11	of	of	ADP
eurjchem-952	2	12	chemistry	chemistry	PROPN
eurjchem-952	2	13	journal	journal	PROPN
eurjchem-952	2	14	homepage	homepage	NOUN
eurjchem-952	2	15	:	:	PUNCT
eurjchem-952	2	16	www.eurjchem.com	www.eurjchem.com	X
eurjchem-952	2	17	synthesis	synthesis	NOUN
eurjchem-952	2	18	of	of	ADP
eurjchem-952	2	19	some	some	DET
eurjchem-952	2	20	transition	transition	NOUN
eurjchem-952	2	21	metal	metal	NOUN
eurjchem-952	2	22	complexes	complex	NOUN
eurjchem-952	2	23	of	of	ADP
eurjchem-952	2	24	novel	novel	NOUN
eurjchem-952	2	25	1‐methylpyrazole‐3‐	1‐methylpyrazole‐3‐	NUM
eurjchem-952	2	26	aldehyde‐4‐(2‐pyridyl	aldehyde‐4‐(2‐pyridyl	NOUN
eurjchem-952	2	27	)	)	PUNCT
eurjchem-952	2	28	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-952	2	29	:	:	PUNCT
eurjchem-952	2	30	spectroscopic	spectroscopic	NOUN
eurjchem-952	2	31	and	and	CCONJ
eurjchem-952	2	32	in	in	ADP
eurjchem-952	2	33	vitro	vitro	X
eurjchem-952	2	34	biological	biological	ADJ
eurjchem-952	2	35	activity	activity	NOUN
eurjchem-952	2	36	studies	study	NOUN
eurjchem-952	2	37	mutlaq	mutlaq	NOUN
eurjchem-952	2	38	shedeed	shedeed	VERB
eurjchem-952	2	39	aljahdali	aljahdali	PROPN
eurjchem-952	2	40	a	a	DET
eurjchem-952	2	41	,	,	PUNCT
eurjchem-952	2	42	*	*	PROPN
eurjchem-952	2	43	,	,	PUNCT
eurjchem-952	2	44	yahia	yahia	PROPN
eurjchem-952	2	45	hassan	hassan	PROPN
eurjchem-952	2	46	elmalik	elmalik	VERB
eurjchem-952	2	47	b	b	PROPN
eurjchem-952	2	48	and	and	CCONJ
eurjchem-952	2	49	gaber	gaber	PROPN
eurjchem-952	2	50	mohamed	mohamed	PROPN
eurjchem-952	2	51	abu	abu	PROPN
eurjchem-952	3	1	el‐reash	el‐reash	PROPN
eurjchem-952	3	2	c	c	PROPN
eurjchem-952	3	3	a	a	DET
eurjchem-952	3	4	department	department	NOUN
eurjchem-952	3	5	of	of	ADP
eurjchem-952	3	6	chemistry	chemistry	NOUN
eurjchem-952	3	7	,	,	PUNCT
eurjchem-952	3	8	faculty	faculty	NOUN
eurjchem-952	3	9	of	of	ADP
eurjchem-952	3	10	science	science	NOUN
eurjchem-952	3	11	,	,	PUNCT
eurjchem-952	3	12	king	king	PROPN
eurjchem-952	3	13	abdulaziz	abdulaziz	PROPN
eurjchem-952	3	14	university	university	PROPN
eurjchem-952	3	15	,	,	PUNCT
eurjchem-952	3	16	jeddah	jeddah	PROPN
eurjchem-952	3	17	21589	21589	NUM
eurjchem-952	3	18	,	,	PUNCT
eurjchem-952	3	19	the	the	DET
eurjchem-952	3	20	kingdom	kingdom	NOUN
eurjchem-952	3	21	of	of	ADP
eurjchem-952	3	22	saudi	saudi	PROPN
eurjchem-952	3	23	arabia	arabia	PROPN
eurjchem-952	3	24	b	b	PROPN
eurjchem-952	3	25	department	department	PROPN
eurjchem-952	3	26	of	of	ADP
eurjchem-952	3	27	chemistry	chemistry	NOUN
eurjchem-952	3	28	,	,	PUNCT
eurjchem-952	3	29	faculty	faculty	NOUN
eurjchem-952	3	30	of	of	ADP
eurjchem-952	3	31	pharmacy	pharmacy	NOUN
eurjchem-952	3	32	,	,	PUNCT
eurjchem-952	3	33	northern	northern	ADJ
eurjchem-952	3	34	borders	border	NOUN
eurjchem-952	3	35	university	university	PROPN
eurjchem-952	3	36	,	,	PUNCT
eurjchem-952	3	37	rafhan	rafhan	NOUN
eurjchem-952	3	38	city	city	NOUN
eurjchem-952	3	39	156	156	NUM
eurjchem-952	3	40	,	,	PUNCT
eurjchem-952	3	41	the	the	DET
eurjchem-952	3	42	kingdom	kingdom	NOUN
eurjchem-952	3	43	of	of	ADP
eurjchem-952	3	44	saudi	saudi	PROPN
eurjchem-952	3	45	arabia	arabia	PROPN
eurjchem-952	3	46	c	c	PROPN
eurjchem-952	3	47	department	department	PROPN
eurjchem-952	3	48	of	of	ADP
eurjchem-952	3	49	chemistry	chemistry	NOUN
eurjchem-952	3	50	,	,	PUNCT
eurjchem-952	3	51	faculty	faculty	NOUN
eurjchem-952	3	52	of	of	ADP
eurjchem-952	3	53	science	science	NOUN
eurjchem-952	3	54	,	,	PUNCT
eurjchem-952	3	55	mansoura	mansoura	PROPN
eurjchem-952	3	56	university	university	NOUN
eurjchem-952	3	57	,	,	PUNCT
eurjchem-952	3	58	mansoura	mansoura	ADJ
eurjchem-952	3	59	city	city	NOUN
eurjchem-952	3	60	,	,	PUNCT
eurjchem-952	3	61	002	002	NUM
eurjchem-952	3	62	,	,	PUNCT
eurjchem-952	3	63	egypt	egypt	PROPN
eurjchem-952	3	64	*	*	PUNCT
eurjchem-952	3	65	corresponding	correspond	VERB
eurjchem-952	3	66	author	author	NOUN
eurjchem-952	3	67	at	at	ADP
eurjchem-952	3	68	:	:	PUNCT
eurjchem-952	3	69	department	department	NOUN
eurjchem-952	3	70	of	of	ADP
eurjchem-952	3	71	chemistry	chemistry	NOUN
eurjchem-952	3	72	,	,	PUNCT
eurjchem-952	3	73	faculty	faculty	NOUN
eurjchem-952	3	74	of	of	ADP
eurjchem-952	3	75	science	science	NOUN
eurjchem-952	3	76	,	,	PUNCT
eurjchem-952	3	77	king	king	PROPN
eurjchem-952	3	78	abdulaziz	abdulaziz	PROPN
eurjchem-952	3	79	university	university	PROPN
eurjchem-952	3	80	,	,	PUNCT
eurjchem-952	3	81	jeddah	jeddah	PROPN
eurjchem-952	3	82	21589	21589	NUM
eurjchem-952	3	83	,	,	PUNCT
eurjchem-952	3	84	the	the	DET
eurjchem-952	3	85	kingdom	kingdom	NOUN
eurjchem-952	3	86	of	of	ADP
eurjchem-952	3	87	saudi	saudi	PROPN
eurjchem-952	3	88	arabia	arabia	PROPN
eurjchem-952	3	89	.	.	PUNCT
eurjchem-952	4	1	tel	tel	PROPN
eurjchem-952	4	2	.	.	PUNCT
eurjchem-952	4	3	:	:	PUNCT
eurjchem-952	5	1	+9.66.503617791	+9.66.503617791	X
eurjchem-952	5	2	.	.	PUNCT
eurjchem-952	6	1	fax	fax	NOUN
eurjchem-952	6	2	:	:	PUNCT
eurjchem-952	6	3	+9.66.26952293	+9.66.26952293	ADJ
eurjchem-952	6	4	.	.	PUNCT
eurjchem-952	6	5	e‐mail	e‐mail	PUNCT
eurjchem-952	7	1	address	address	NOUN
eurjchem-952	7	2	:	:	PUNCT
eurjchem-952	7	3	mutlaqaljahdali@yahoo.com	mutlaqaljahdali@yahoo.com	X
eurjchem-952	7	4	(	(	PUNCT
eurjchem-952	7	5	m.s	m.s	PROPN
eurjchem-952	7	6	.	.	PROPN
eurjchem-952	7	7	aljahdali	aljahdali	PROPN
eurjchem-952	7	8	)	)	PUNCT
eurjchem-952	7	9	.	.	PUNCT
eurjchem-952	8	1	article	article	NOUN
eurjchem-952	8	2	information	information	PROPN
eurjchem-952	8	3	abstract	abstract	ADJ
eurjchem-952	8	4	doi	doi	NOUN
eurjchem-952	8	5	:	:	PUNCT
eurjchem-952	8	6	10.5155	10.5155	NUM
eurjchem-952	8	7	/	/	SYM
eurjchem-952	8	8	eurjchem.5.2.201‐208.952	eurjchem.5.2.201‐208.952	NOUN
eurjchem-952	8	9	received	receive	VERB
eurjchem-952	8	10	:	:	PUNCT
eurjchem-952	8	11	22	22	NUM
eurjchem-952	8	12	october	october	PROPN
eurjchem-952	8	13	2013	2013	NUM
eurjchem-952	8	14	received	receive	VERB
eurjchem-952	8	15	in	in	ADP
eurjchem-952	8	16	revised	revise	VERB
eurjchem-952	8	17	form	form	NOUN
eurjchem-952	8	18	:	:	PUNCT
eurjchem-952	8	19	22	22	NUM
eurjchem-952	8	20	november	november	NOUN
eurjchem-952	8	21	2013	2013	NUM
eurjchem-952	8	22	accepted	accept	VERB
eurjchem-952	8	23	:	:	PUNCT
eurjchem-952	8	24	26	26	NUM
eurjchem-952	8	25	november	november	PROPN
eurjchem-952	8	26	2013	2013	NUM
eurjchem-952	8	27	online	online	NOUN
eurjchem-952	8	28	:	:	PUNCT
eurjchem-952	8	29	30	30	NUM
eurjchem-952	8	30	june	june	PROPN
eurjchem-952	8	31	2014	2014	NUM
eurjchem-952	8	32	keywords	keyword	VERB
eurjchem-952	8	33	four	four	NUM
eurjchem-952	8	34	new	new	ADJ
eurjchem-952	8	35	mixed	mixed	ADJ
eurjchem-952	8	36	ligand	ligand	NOUN
eurjchem-952	8	37	metal(ii	metal(ii	PROPN
eurjchem-952	8	38	)	)	PUNCT
eurjchem-952	8	39	complexes	complex	NOUN
eurjchem-952	8	40	with	with	ADP
eurjchem-952	8	41	1‐methylpyrazole‐3‐aldehyde‐4‐(2‐	1‐methylpyrazole‐3‐aldehyde‐4‐(2‐	NUM
eurjchem-952	8	42	pyridyl)thiosemicarbazone	pyridyl)thiosemicarbazone	NUM
eurjchem-952	8	43	(	(	PUNCT
eurjchem-952	8	44	mpapt	mpapt	ADJ
eurjchem-952	8	45	)	)	PUNCT
eurjchem-952	8	46	and	and	CCONJ
eurjchem-952	8	47	1,10‐phenanthroline	1,10‐phenanthroline	NUM
eurjchem-952	8	48	are	be	AUX
eurjchem-952	8	49	reported	report	VERB
eurjchem-952	8	50	.	.	PUNCT
eurjchem-952	9	1	these	these	PRON
eurjchem-952	9	2	complexes	complexe	VERB
eurjchem-952	9	3	namely	namely	ADV
eurjchem-952	9	4	cu(mpapt)(1,10‐phen)(cl	cu(mpapt)(1,10‐phen)(cl	NOUN
eurjchem-952	9	5	)	)	PUNCT
eurjchem-952	9	6	]	]	PUNCT
eurjchem-952	9	7	(	(	PUNCT
eurjchem-952	9	8	1	1	NUM
eurjchem-952	9	9	)	)	PUNCT
eurjchem-952	9	10	,	,	PUNCT
eurjchem-952	10	1	[	[	X
eurjchem-952	10	2	ni(mpapt)(1,10‐phen)(cl	ni(mpapt)(1,10‐phen)(cl	X
eurjchem-952	10	3	)	)	PUNCT
eurjchem-952	10	4	]	]	PUNCT
eurjchem-952	10	5	(	(	PUNCT
eurjchem-952	10	6	2	2	NUM
eurjchem-952	10	7	)	)	PUNCT
eurjchem-952	10	8	,	,	PUNCT
eurjchem-952	10	9	[	[	X
eurjchem-952	10	10	mn(mpapt)(1,10‐phen)(cl)].h2o	mn(mpapt)(1,10‐phen)(cl)].h2o	NOUN
eurjchem-952	10	11	(	(	PUNCT
eurjchem-952	10	12	3	3	NUM
eurjchem-952	10	13	)	)	PUNCT
eurjchem-952	10	14	and	and	CCONJ
eurjchem-952	10	15	[	[	X
eurjchem-952	10	16	co(mpapt)(1,10‐phen)(cl)].h2o	co(mpapt)(1,10‐phen)(cl)].h2o	NOUN
eurjchem-952	10	17	(	(	PUNCT
eurjchem-952	10	18	4	4	NUM
eurjchem-952	10	19	)	)	PUNCT
eurjchem-952	10	20	,	,	PUNCT
eurjchem-952	10	21	were	be	AUX
eurjchem-952	10	22	characterized	characterize	VERB
eurjchem-952	10	23	by	by	ADP
eurjchem-952	10	24	elemental	elemental	ADJ
eurjchem-952	10	25	analysis	analysis	NOUN
eurjchem-952	10	26	,	,	PUNCT
eurjchem-952	10	27	spectral	spectral	ADJ
eurjchem-952	10	28	(	(	PUNCT
eurjchem-952	10	29	ir	ir	PROPN
eurjchem-952	10	30	,	,	PUNCT
eurjchem-952	10	31	1h	1h	NUM
eurjchem-952	10	32	nmr	nmr	NOUN
eurjchem-952	10	33	and	and	CCONJ
eurjchem-952	10	34	uv‐vis	uv‐vi	NOUN
eurjchem-952	10	35	)	)	PUNCT
eurjchem-952	10	36	and	and	CCONJ
eurjchem-952	10	37	magnetic	magnetic	ADJ
eurjchem-952	10	38	moment	moment	NOUN
eurjchem-952	10	39	measurements	measurement	NOUN
eurjchem-952	10	40	.	.	PUNCT
eurjchem-952	11	1	the	the	DET
eurjchem-952	11	2	magnetic	magnetic	ADJ
eurjchem-952	11	3	and	and	CCONJ
eurjchem-952	11	4	spectral	spectral	ADJ
eurjchem-952	11	5	data	datum	NOUN
eurjchem-952	11	6	indicates	indicate	VERB
eurjchem-952	11	7	octahedral	octahedral	ADJ
eurjchem-952	11	8	structure	structure	NOUN
eurjchem-952	11	9	for	for	ADP
eurjchem-952	11	10	all	all	DET
eurjchem-952	11	11	complexes	complex	NOUN
eurjchem-952	11	12	.	.	PUNCT
eurjchem-952	12	1	metal	metal	NOUN
eurjchem-952	12	2	complexes	complex	NOUN
eurjchem-952	12	3	have	have	AUX
eurjchem-952	12	4	been	be	AUX
eurjchem-952	12	5	modeled	model	VERB
eurjchem-952	12	6	using	use	VERB
eurjchem-952	12	7	parameterized	parameterized	ADJ
eurjchem-952	12	8	pm3	pm3	PROPN
eurjchem-952	12	9	semi‐	semi‐	CCONJ
eurjchem-952	12	10	empirical	empirical	ADJ
eurjchem-952	12	11	method	method	NOUN
eurjchem-952	12	12	.	.	PUNCT
eurjchem-952	13	1	the	the	DET
eurjchem-952	13	2	free	free	ADJ
eurjchem-952	13	3	ligand	ligand	NOUN
eurjchem-952	13	4	and	and	CCONJ
eurjchem-952	13	5	its	its	PRON
eurjchem-952	13	6	m(ii	m(ii	NOUN
eurjchem-952	13	7	)	)	PUNCT
eurjchem-952	13	8	chelates	chelate	NOUN
eurjchem-952	13	9	have	have	AUX
eurjchem-952	13	10	been	be	AUX
eurjchem-952	13	11	screened	screen	VERB
eurjchem-952	13	12	for	for	ADP
eurjchem-952	13	13	their	their	PRON
eurjchem-952	13	14	antimicrobial	antimicrobial	ADJ
eurjchem-952	13	15	activities	activity	NOUN
eurjchem-952	13	16	.	.	PUNCT
eurjchem-952	14	1	the	the	DET
eurjchem-952	14	2	antimicrobial	antimicrobial	ADJ
eurjchem-952	14	3	screening	screening	NOUN
eurjchem-952	14	4	demonstrated	demonstrate	VERB
eurjchem-952	14	5	that	that	SCONJ
eurjchem-952	14	6	,	,	PUNCT
eurjchem-952	14	7	the	the	DET
eurjchem-952	14	8	cu(ii	cu(ii	PROPN
eurjchem-952	14	9	)	)	PUNCT
eurjchem-952	14	10	complex	complex	NOUN
eurjchem-952	14	11	have	have	VERB
eurjchem-952	14	12	the	the	DET
eurjchem-952	14	13	maximum	maximum	ADJ
eurjchem-952	14	14	and	and	CCONJ
eurjchem-952	14	15	broad	broad	ADJ
eurjchem-952	14	16	activities	activity	NOUN
eurjchem-952	14	17	among	among	ADP
eurjchem-952	14	18	the	the	DET
eurjchem-952	14	19	investigated	investigate	VERB
eurjchem-952	14	20	complexes	complex	NOUN
eurjchem-952	14	21	.	.	PUNCT
eurjchem-952	15	1	spectra	spectra	ADJ
eurjchem-952	15	2	synthesis	synthesis	NOUN
eurjchem-952	15	3	antifungal	antifungal	ADJ
eurjchem-952	15	4	activity	activity	NOUN
eurjchem-952	15	5	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-952	15	6	molecular	molecular	ADJ
eurjchem-952	15	7	modeling	model	VERB
eurjchem-952	15	8	antibacterial	antibacterial	ADJ
eurjchem-952	15	9	activity	activity	NOUN
eurjchem-952	15	10	1	1	NUM
eurjchem-952	15	11	.	.	PUNCT
eurjchem-952	16	1	introduction	introduction	NOUN
eurjchem-952	16	2	thiosemicarbazones	thiosemicarbazone	NOUN
eurjchem-952	16	3	have	have	AUX
eurjchem-952	16	4	been	be	AUX
eurjchem-952	16	5	extensively	extensively	ADV
eurjchem-952	16	6	studied	study	VERB
eurjchem-952	16	7	because	because	SCONJ
eurjchem-952	16	8	they	they	PRON
eurjchem-952	16	9	have	have	VERB
eurjchem-952	16	10	a	a	DET
eurjchem-952	16	11	wide	wide	ADJ
eurjchem-952	16	12	range	range	NOUN
eurjchem-952	16	13	of	of	ADP
eurjchem-952	16	14	actual	actual	ADJ
eurjchem-952	16	15	or	or	CCONJ
eurjchem-952	16	16	potential	potential	ADJ
eurjchem-952	16	17	medical	medical	ADJ
eurjchem-952	16	18	applications	application	NOUN
eurjchem-952	16	19	[	[	X
eurjchem-952	16	20	1‐6	1‐6	X
eurjchem-952	16	21	]	]	PUNCT
eurjchem-952	16	22	which	which	PRON
eurjchem-952	16	23	include	include	VERB
eurjchem-952	16	24	notably	notably	ADV
eurjchem-952	16	25	antiparasital	antiparasital	ADJ
eurjchem-952	17	1	[	[	X
eurjchem-952	17	2	5	5	NUM
eurjchem-952	17	3	]	]	PUNCT
eurjchem-952	17	4	,	,	PUNCT
eurjchem-952	17	5	antibacterial	antibacterial	ADJ
eurjchem-952	17	6	[	[	X
eurjchem-952	17	7	6	6	NUM
eurjchem-952	17	8	]	]	X
eurjchem-952	17	9	antitumor	antitumor	NOUN
eurjchem-952	17	10	activities	activity	NOUN
eurjchem-952	17	11	[	[	X
eurjchem-952	17	12	7	7	NUM
eurjchem-952	17	13	]	]	PUNCT
eurjchem-952	17	14	,	,	PUNCT
eurjchem-952	17	15	antiviral	antiviral	NOUN
eurjchem-952	17	16	[	[	X
eurjchem-952	17	17	8	8	NUM
eurjchem-952	17	18	]	]	PUNCT
eurjchem-952	17	19	,	,	PUNCT
eurjchem-952	17	20	fungicidal	fungicidal	NOUN
eurjchem-952	17	21	[	[	X
eurjchem-952	17	22	9	9	NUM
eurjchem-952	17	23	]	]	PUNCT
eurjchem-952	17	24	and	and	CCONJ
eurjchem-952	17	25	antineoplastic	antineoplastic	ADJ
eurjchem-952	17	26	[	[	X
eurjchem-952	17	27	10	10	NUM
eurjchem-952	17	28	]	]	PUNCT
eurjchem-952	17	29	.	.	PUNCT
eurjchem-952	18	1	in	in	ADP
eurjchem-952	18	2	general	general	ADJ
eurjchem-952	18	3	,	,	PUNCT
eurjchem-952	18	4	thiosemicarbazones	thiosemicarbazone	NOUN
eurjchem-952	18	5	are	be	AUX
eurjchem-952	18	6	obtained	obtain	VERB
eurjchem-952	18	7	by	by	ADP
eurjchem-952	18	8	condensation	condensation	NOUN
eurjchem-952	18	9	of	of	ADP
eurjchem-952	18	10	the	the	DET
eurjchem-952	18	11	corresponding	corresponding	ADJ
eurjchem-952	18	12	thiosemi‐	thiosemi‐	PUNCT
eurjchem-952	18	13	carbazide	carbazide	NOUN
eurjchem-952	18	14	with	with	ADP
eurjchem-952	18	15	aldehydes	aldehyde	NOUN
eurjchem-952	18	16	or	or	CCONJ
eurjchem-952	18	17	ketones	ketone	NOUN
eurjchem-952	18	18	.	.	PUNCT
eurjchem-952	19	1	thiosemicarbazones	thiosemicarbazone	NOUN
eurjchem-952	19	2	(	(	PUNCT
eurjchem-952	19	3	tscns	tscns	NOUN
eurjchem-952	19	4	)	)	PUNCT
eurjchem-952	19	5	exist	exist	VERB
eurjchem-952	19	6	in	in	ADP
eurjchem-952	19	7	the	the	DET
eurjchem-952	19	8	tautomeric	tautomeric	ADJ
eurjchem-952	19	9	thione	thione	NOUN
eurjchem-952	19	10	(	(	PUNCT
eurjchem-952	19	11	a	a	NOUN
eurjchem-952	19	12	)	)	PUNCT
eurjchem-952	19	13	and	and	CCONJ
eurjchem-952	19	14	thiol	thiol	PROPN
eurjchem-952	19	15	(	(	PUNCT
eurjchem-952	19	16	b	b	X
eurjchem-952	19	17	)	)	PUNCT
eurjchem-952	19	18	forms	form	NOUN
eurjchem-952	19	19	(	(	PUNCT
eurjchem-952	19	20	scheme	scheme	NOUN
eurjchem-952	19	21	1	1	NUM
eurjchem-952	19	22	)	)	PUNCT
eurjchem-952	19	23	.	.	PUNCT
eurjchem-952	20	1	scheme	scheme	NOUN
eurjchem-952	20	2	1	1	NUM
eurjchem-952	20	3	the	the	DET
eurjchem-952	20	4	chemistry	chemistry	NOUN
eurjchem-952	20	5	of	of	ADP
eurjchem-952	20	6	transition	transition	NOUN
eurjchem-952	20	7	metal	metal	NOUN
eurjchem-952	20	8	complexes	complex	NOUN
eurjchem-952	20	9	of	of	ADP
eurjchem-952	20	10	heterocyclic	heterocyclic	ADJ
eurjchem-952	20	11	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-952	20	12	ligands	ligand	NOUN
eurjchem-952	20	13	has	have	AUX
eurjchem-952	20	14	been	be	AUX
eurjchem-952	20	15	receiving	receive	VERB
eurjchem-952	20	16	considerable	considerable	ADJ
eurjchem-952	20	17	attention	attention	NOUN
eurjchem-952	20	18	primarily	primarily	ADV
eurjchem-952	20	19	because	because	SCONJ
eurjchem-952	20	20	of	of	ADP
eurjchem-952	20	21	their	their	PRON
eurjchem-952	20	22	bioinorganic	bioinorganic	NOUN
eurjchem-952	20	23	relevance	relevance	NOUN
eurjchem-952	21	1	[	[	X
eurjchem-952	21	2	11,12	11,12	NUM
eurjchem-952	21	3	]	]	PUNCT
eurjchem-952	21	4	.	.	PUNCT
eurjchem-952	22	1	there	there	PRON
eurjchem-952	22	2	have	have	AUX
eurjchem-952	22	3	been	be	AUX
eurjchem-952	22	4	attempts	attempt	NOUN
eurjchem-952	22	5	[	[	X
eurjchem-952	22	6	13	13	NUM
eurjchem-952	22	7	]	]	PUNCT
eurjchem-952	22	8	to	to	PART
eurjchem-952	22	9	determine	determine	VERB
eurjchem-952	22	10	structural	structural	ADJ
eurjchem-952	22	11	correlation	correlation	NOUN
eurjchem-952	22	12	’s	’s	NOUN
eurjchem-952	22	13	between	between	ADP
eurjchem-952	22	14	transition	transition	NOUN
eurjchem-952	22	15	metal	metal	NOUN
eurjchem-952	22	16	ion	ion	NOUN
eurjchem-952	22	17	complexes	complex	NOUN
eurjchem-952	22	18	of	of	ADP
eurjchem-952	22	19	heterocyclic	heterocyclic	ADJ
eurjchem-952	22	20	thiosemicarbazones	thiosemicarbazone	NOUN
eurjchem-952	22	21	and	and	CCONJ
eurjchem-952	22	22	their	their	PRON
eurjchem-952	22	23	wide	wide	ADJ
eurjchem-952	22	24	spectrum	spectrum	NOUN
eurjchem-952	22	25	of	of	ADP
eurjchem-952	22	26	biological	biological	ADJ
eurjchem-952	22	27	applications	application	NOUN
eurjchem-952	22	28	.	.	PUNCT
eurjchem-952	23	1	in	in	ADP
eurjchem-952	23	2	several	several	ADJ
eurjchem-952	23	3	cases	case	NOUN
eurjchem-952	23	4	,	,	PUNCT
eurjchem-952	23	5	the	the	DET
eurjchem-952	23	6	pharmacological	pharmacological	ADJ
eurjchem-952	23	7	action	action	NOUN
eurjchem-952	23	8	of	of	ADP
eurjchem-952	23	9	the	the	DET
eurjchem-952	23	10	thiosemicarbazons	thiosemicarbazon	NOUN
eurjchem-952	23	11	is	be	AUX
eurjchem-952	23	12	enhanced	enhance	VERB
eurjchem-952	23	13	due	due	ADP
eurjchem-952	23	14	to	to	ADP
eurjchem-952	23	15	their	their	PRON
eurjchem-952	23	16	ability	ability	NOUN
eurjchem-952	23	17	to	to	PART
eurjchem-952	23	18	chelate	chelate	VERB
eurjchem-952	23	19	transition	transition	NOUN
eurjchem-952	23	20	metal	metal	NOUN
eurjchem-952	23	21	ions	ion	NOUN
eurjchem-952	23	22	[	[	X
eurjchem-952	23	23	14,15	14,15	NUM
eurjchem-952	23	24	]	]	PUNCT
eurjchem-952	23	25	.	.	PUNCT
eurjchem-952	24	1	it	it	PRON
eurjchem-952	24	2	is	be	AUX
eurjchem-952	24	3	well	well	ADV
eurjchem-952	24	4	authenticated	authenticate	VERB
eurjchem-952	24	5	that	that	SCONJ
eurjchem-952	24	6	a	a	DET
eurjchem-952	24	7	nns	nns	NOUN
eurjchem-952	24	8	tridentate	tridentate	NOUN
eurjchem-952	24	9	system	system	NOUN
eurjchem-952	24	10	is	be	AUX
eurjchem-952	24	11	present	present	ADJ
eurjchem-952	24	12	in	in	ADP
eurjchem-952	24	13	most	most	ADJ
eurjchem-952	24	14	of	of	ADP
eurjchem-952	24	15	the	the	DET
eurjchem-952	24	16	thiosemi‐	thiosemi‐	PROPN
eurjchem-952	24	17	carbazones	carbazone	NOUN
eurjchem-952	24	18	having	have	VERB
eurjchem-952	24	19	carcinostatic	carcinostatic	ADJ
eurjchem-952	24	20	potency	potency	NOUN
eurjchem-952	24	21	and	and	CCONJ
eurjchem-952	24	22	possessing	possess	VERB
eurjchem-952	24	23	substantial	substantial	ADJ
eurjchem-952	24	24	in	in	ADP
eurjchem-952	24	25	vitro	vitro	X
eurjchem-952	24	26	activity	activity	NOUN
eurjchem-952	24	27	against	against	ADP
eurjchem-952	24	28	various	various	ADJ
eurjchem-952	24	29	human	human	ADJ
eurjchem-952	24	30	tumour	tumour	NOUN
eurjchem-952	24	31	lines	line	NOUN
eurjchem-952	25	1	[	[	X
eurjchem-952	25	2	16,17	16,17	NUM
eurjchem-952	25	3	]	]	PUNCT
eurjchem-952	25	4	.	.	PUNCT
eurjchem-952	26	1	in	in	ADP
eurjchem-952	26	2	the	the	DET
eurjchem-952	26	3	past	past	NOUN
eurjchem-952	26	4	,	,	PUNCT
eurjchem-952	26	5	it	it	PRON
eurjchem-952	26	6	has	have	AUX
eurjchem-952	26	7	been	be	AUX
eurjchem-952	26	8	shown	show	VERB
eurjchem-952	26	9	that	that	SCONJ
eurjchem-952	26	10	the	the	DET
eurjchem-952	26	11	metal	metal	NOUN
eurjchem-952	26	12	complexes	complex	NOUN
eurjchem-952	26	13	are	be	AUX
eurjchem-952	26	14	more	more	ADV
eurjchem-952	26	15	effective	effective	ADJ
eurjchem-952	26	16	than	than	ADP
eurjchem-952	26	17	their	their	PRON
eurjchem-952	26	18	parent	parent	NOUN
eurjchem-952	26	19	ligands	ligand	NOUN
eurjchem-952	26	20	in	in	ADP
eurjchem-952	26	21	anticancer	anticancer	NOUN
eurjchem-952	26	22	activity	activity	NOUN
eurjchem-952	27	1	[	[	X
eurjchem-952	27	2	18,19	18,19	NUM
eurjchem-952	27	3	]	]	PUNCT
eurjchem-952	27	4	.	.	PUNCT
eurjchem-952	28	1	the	the	DET
eurjchem-952	28	2	inhibitory	inhibitory	ADJ
eurjchem-952	28	3	action	action	NOUN
eurjchem-952	28	4	of	of	ADP
eurjchem-952	28	5	these	these	DET
eurjchem-952	28	6	compounds	compound	NOUN
eurjchem-952	28	7	is	be	AUX
eurjchem-952	28	8	attributed	attribute	VERB
eurjchem-952	28	9	to	to	ADP
eurjchem-952	28	10	their	their	PRON
eurjchem-952	28	11	chelating	chelating	NOUN
eurjchem-952	28	12	properties	property	NOUN
eurjchem-952	28	13	to	to	ADP
eurjchem-952	28	14	different	different	ADJ
eurjchem-952	28	15	metal	metal	NOUN
eurjchem-952	28	16	ions	ion	NOUN
eurjchem-952	28	17	that	that	PRON
eurjchem-952	28	18	can	can	AUX
eurjchem-952	28	19	be	be	AUX
eurjchem-952	28	20	found	find	VERB
eurjchem-952	28	21	in	in	ADP
eurjchem-952	28	22	biological	biological	ADJ
eurjchem-952	28	23	systems	system	NOUN
eurjchem-952	28	24	,	,	PUNCT
eurjchem-952	28	25	which	which	PRON
eurjchem-952	28	26	microorganisms	microorganism	NOUN
eurjchem-952	28	27	need	need	VERB
eurjchem-952	28	28	in	in	ADP
eurjchem-952	28	29	their	their	PRON
eurjchem-952	28	30	metabolism	metabolism	NOUN
eurjchem-952	28	31	[	[	X
eurjchem-952	28	32	20	20	NUM
eurjchem-952	28	33	]	]	PUNCT
eurjchem-952	28	34	.	.	PUNCT
eurjchem-952	29	1	additionally	additionally	ADV
eurjchem-952	29	2	,	,	PUNCT
eurjchem-952	29	3	one	one	NUM
eurjchem-952	29	4	of	of	ADP
eurjchem-952	29	5	the	the	DET
eurjchem-952	29	6	many	many	ADJ
eurjchem-952	29	7	reasons	reason	NOUN
eurjchem-952	29	8	is	be	AUX
eurjchem-952	29	9	that	that	SCONJ
eurjchem-952	29	10	the	the	DET
eurjchem-952	29	11	binding	bind	VERB
eurjchem-952	29	12	affinity	affinity	NOUN
eurjchem-952	29	13	of	of	ADP
eurjchem-952	29	14	metals	metal	NOUN
eurjchem-952	29	15	to	to	ADP
eurjchem-952	29	16	proteins	protein	NOUN
eurjchem-952	29	17	or	or	CCONJ
eurjchem-952	29	18	enzymes	enzyme	NOUN
eurjchem-952	29	19	will	will	AUX
eurjchem-952	29	20	change	change	VERB
eurjchem-952	29	21	the	the	DET
eurjchem-952	29	22	interaction	interaction	NOUN
eurjchem-952	29	23	process	process	NOUN
eurjchem-952	29	24	of	of	ADP
eurjchem-952	29	25	them	they	PRON
eurjchem-952	29	26	with	with	ADP
eurjchem-952	29	27	dna	dna	PROPN
eurjchem-952	29	28	,	,	PUNCT
eurjchem-952	29	29	thereby	thereby	ADV
eurjchem-952	29	30	affecting	affect	VERB
eurjchem-952	29	31	the	the	DET
eurjchem-952	29	32	dna	dna	PROPN
eurjchem-952	29	33	replication	replication	NOUN
eurjchem-952	29	34	and	and	CCONJ
eurjchem-952	29	35	cell	cell	NOUN
eurjchem-952	29	36	proliferation	proliferation	NOUN
eurjchem-952	29	37	[	[	X
eurjchem-952	29	38	19	19	NUM
eurjchem-952	29	39	]	]	PUNCT
eurjchem-952	29	40	.	.	PUNCT
eurjchem-952	30	1	earlier	early	ADJ
eurjchem-952	30	2	studies	study	NOUN
eurjchem-952	30	3	on	on	ADP
eurjchem-952	30	4	the	the	DET
eurjchem-952	30	5	biological	biological	ADJ
eurjchem-952	30	6	properties	property	NOUN
eurjchem-952	30	7	of	of	ADP
eurjchem-952	30	8	thiosemicarbazones	thiosemicarbazone	NOUN
eurjchem-952	30	9	and	and	CCONJ
eurjchem-952	30	10	their	their	PRON
eurjchem-952	30	11	metal	metal	NOUN
eurjchem-952	30	12	complexes	complex	NOUN
eurjchem-952	30	13	have	have	AUX
eurjchem-952	30	14	concluded	conclude	VERB
eurjchem-952	30	15	that	that	SCONJ
eurjchem-952	30	16	the	the	DET
eurjchem-952	30	17	biologically	biologically	ADV
eurjchem-952	30	18	active	active	ADJ
eurjchem-952	30	19	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-952	30	20	molecules	molecule	NOUN
eurjchem-952	30	21	are	be	AUX
eurjchem-952	30	22	planar	planar	ADJ
eurjchem-952	30	23	and	and	CCONJ
eurjchem-952	30	24	contain	contain	VERB
eurjchem-952	30	25	a	a	DET
eurjchem-952	30	26	pyridine	pyridine	NOUN
eurjchem-952	30	27	ring	ring	NOUN
eurjchem-952	30	28	or	or	CCONJ
eurjchem-952	30	29	derivatives	derivative	NOUN
eurjchem-952	30	30	giving	give	VERB
eurjchem-952	30	31	rise	rise	NOUN
eurjchem-952	30	32	to	to	ADP
eurjchem-952	30	33	nns	nn	NOUN
eurjchem-952	30	34	tridentate	tridentate	NOUN
eurjchem-952	30	35	system	system	NOUN
eurjchem-952	30	36	[	[	X
eurjchem-952	30	37	21,22	21,22	X
eurjchem-952	30	38	]	]	X
eurjchem-952	30	39	.	.	PUNCT
eurjchem-952	31	1	202	202	NUM
eurjchem-952	31	2	aljahdali	aljahdali	PROPN
eurjchem-952	31	3	et	et	PROPN
eurjchem-952	31	4	al	al	PROPN
eurjchem-952	31	5	.	.	PUNCT
eurjchem-952	31	6	/	/	SYM
eurjchem-952	31	7	european	european	PROPN
eurjchem-952	31	8	journal	journal	PROPN
eurjchem-952	31	9	of	of	ADP
eurjchem-952	31	10	chemistry	chemistry	NOUN
eurjchem-952	31	11	5	5	NUM
eurjchem-952	31	12	(	(	PUNCT
eurjchem-952	31	13	2	2	NUM
eurjchem-952	31	14	)	)	PUNCT
eurjchem-952	31	15	(	(	PUNCT
eurjchem-952	31	16	2014	2014	NUM
eurjchem-952	31	17	)	)	PUNCT
eurjchem-952	31	18	201‐208	201‐208	NUM
eurjchem-952	31	19	scheme	scheme	NOUN
eurjchem-952	31	20	2	2	NUM
eurjchem-952	31	21	1,10‐phenanthroline	1,10‐phenanthroline	NUM
eurjchem-952	31	22	(	(	PUNCT
eurjchem-952	31	23	scheme	scheme	NOUN
eurjchem-952	31	24	2	2	NUM
eurjchem-952	31	25	)	)	PUNCT
eurjchem-952	31	26	is	be	AUX
eurjchem-952	31	27	the	the	DET
eurjchem-952	31	28	parent	parent	NOUN
eurjchem-952	31	29	of	of	ADP
eurjchem-952	31	30	an	an	DET
eurjchem-952	31	31	important	important	ADJ
eurjchem-952	31	32	class	class	NOUN
eurjchem-952	31	33	of	of	ADP
eurjchem-952	31	34	chelating	chelating	NOUN
eurjchem-952	31	35	agents	agent	NOUN
eurjchem-952	31	36	.	.	PUNCT
eurjchem-952	32	1	the	the	DET
eurjchem-952	32	2	choice	choice	NOUN
eurjchem-952	32	3	of	of	ADP
eurjchem-952	32	4	phenanthroline	phenanthroline	NOUN
eurjchem-952	32	5	is	be	AUX
eurjchem-952	32	6	mainly	mainly	ADV
eurjchem-952	32	7	due	due	ADP
eurjchem-952	32	8	to	to	ADP
eurjchem-952	32	9	two	two	NUM
eurjchem-952	32	10	factors	factor	NOUN
eurjchem-952	32	11	.	.	PUNCT
eurjchem-952	33	1	this	this	DET
eurjchem-952	33	2	heteroaromatic	heteroaromatic	ADJ
eurjchem-952	33	3	moiety	moiety	NOUN
eurjchem-952	33	4	can	can	AUX
eurjchem-952	33	5	provide	provide	VERB
eurjchem-952	33	6	a	a	DET
eurjchem-952	33	7	further	further	ADJ
eurjchem-952	33	8	binding	bind	VERB
eurjchem-952	33	9	site	site	NOUN
eurjchem-952	33	10	for	for	ADP
eurjchem-952	33	11	metal	metal	NOUN
eurjchem-952	33	12	cations	cation	NOUN
eurjchem-952	33	13	.	.	PUNCT
eurjchem-952	34	1	it	it	PRON
eurjchem-952	34	2	is	be	AUX
eurjchem-952	34	3	rigid	rigid	ADJ
eurjchem-952	34	4	,	,	PUNCT
eurjchem-952	34	5	and	and	CCONJ
eurjchem-952	34	6	provides	provide	VERB
eurjchem-952	34	7	two	two	NUM
eurjchem-952	34	8	aromatic	aromatic	ADJ
eurjchem-952	34	9	nitrogens	nitrogen	NOUN
eurjchem-952	34	10	whose	whose	DET
eurjchem-952	34	11	unshared	unshared	ADJ
eurjchem-952	34	12	electron	electron	NOUN
eurjchem-952	34	13	pairs	pair	NOUN
eurjchem-952	34	14	can	can	AUX
eurjchem-952	34	15	act	act	VERB
eurjchem-952	34	16	co‐operatively	co‐operatively	ADV
eurjchem-952	34	17	in	in	ADP
eurjchem-952	34	18	binding	binding	ADJ
eurjchem-952	34	19	cations	cation	NOUN
eurjchem-952	34	20	[	[	X
eurjchem-952	34	21	23	23	NUM
eurjchem-952	34	22	]	]	PUNCT
eurjchem-952	34	23	.	.	PUNCT
eurjchem-952	35	1	the	the	DET
eurjchem-952	35	2	π‐electron	π‐electron	PUNCT
eurjchem-952	35	3	deficiency	deficiency	NOUN
eurjchem-952	35	4	makes	make	VERB
eurjchem-952	35	5	phenanthroline	phenanthroline	VERB
eurjchem-952	35	6	an	an	DET
eurjchem-952	35	7	excellent	excellent	ADJ
eurjchem-952	35	8	π‐acceptor	π‐acceptor	PUNCT
eurjchem-952	35	9	.	.	PUNCT
eurjchem-952	36	1	moreover	moreover	ADV
eurjchem-952	36	2	,	,	PUNCT
eurjchem-952	36	3	1,10‐	1,10‐	NUM
eurjchem-952	36	4	phenanthroline	phenanthroline	NOUN
eurjchem-952	36	5	,	,	PUNCT
eurjchem-952	36	6	the	the	DET
eurjchem-952	36	7	ligand	ligand	ADJ
eurjchem-952	36	8	moiety	moiety	NOUN
eurjchem-952	36	9	of	of	ADP
eurjchem-952	36	10	the	the	DET
eurjchem-952	36	11	ternary	ternary	ADJ
eurjchem-952	36	12	complexes	complex	NOUN
eurjchem-952	36	13	presented	present	VERB
eurjchem-952	36	14	in	in	ADP
eurjchem-952	36	15	this	this	DET
eurjchem-952	36	16	work	work	NOUN
eurjchem-952	36	17	is	be	AUX
eurjchem-952	36	18	of	of	ADP
eurjchem-952	36	19	considerable	considerable	ADJ
eurjchem-952	36	20	interest	interest	NOUN
eurjchem-952	36	21	also	also	ADV
eurjchem-952	36	22	according	accord	VERB
eurjchem-952	36	23	to	to	ADP
eurjchem-952	36	24	the	the	DET
eurjchem-952	36	25	biological	biological	ADJ
eurjchem-952	36	26	or	or	CCONJ
eurjchem-952	36	27	pharmacological	pharmacological	ADJ
eurjchem-952	36	28	properties	property	NOUN
eurjchem-952	36	29	(	(	PUNCT
eurjchem-952	36	30	antifungal	antifungal	ADJ
eurjchem-952	36	31	,	,	PUNCT
eurjchem-952	36	32	antimycoplasma	antimycoplasma	NOUN
eurjchem-952	36	33	and	and	CCONJ
eurjchem-952	36	34	antiviral	antiviral	ADJ
eurjchem-952	36	35	)	)	PUNCT
eurjchem-952	36	36	of	of	ADP
eurjchem-952	36	37	some	some	PRON
eurjchem-952	36	38	of	of	ADP
eurjchem-952	36	39	its	its	PRON
eurjchem-952	36	40	metal	metal	NOUN
eurjchem-952	36	41	complexes	complex	NOUN
eurjchem-952	36	42	[	[	X
eurjchem-952	36	43	24	24	NUM
eurjchem-952	36	44	]	]	PUNCT
eurjchem-952	36	45	.	.	PUNCT
eurjchem-952	37	1	with	with	ADP
eurjchem-952	37	2	this	this	PRON
eurjchem-952	37	3	in	in	ADP
eurjchem-952	37	4	mind	mind	NOUN
eurjchem-952	37	5	,	,	PUNCT
eurjchem-952	37	6	it	it	PRON
eurjchem-952	37	7	seems	seem	VERB
eurjchem-952	37	8	therefore	therefore	ADV
eurjchem-952	37	9	of	of	ADP
eurjchem-952	37	10	considerable	considerable	ADJ
eurjchem-952	37	11	interest	interest	NOUN
eurjchem-952	37	12	to	to	PART
eurjchem-952	37	13	synthesize	synthesize	VERB
eurjchem-952	37	14	and	and	CCONJ
eurjchem-952	37	15	characterize	characterize	VERB
eurjchem-952	37	16	m(ii	m(ii	PROPN
eurjchem-952	37	17	)	)	PUNCT
eurjchem-952	37	18	complexes	complex	NOUN
eurjchem-952	37	19	with	with	ADP
eurjchem-952	37	20	the	the	DET
eurjchem-952	37	21	novel	novel	ADJ
eurjchem-952	37	22	1‐methylpyrazole‐3‐aldehyde‐4‐(2‐	1‐methylpyrazole‐3‐aldehyde‐4‐(2‐	NUM
eurjchem-952	37	23	pyridyl)thiosemicarbazone	pyridyl)thiosemicarbazone	NOUN
eurjchem-952	37	24	(	(	PUNCT
eurjchem-952	37	25	mpapt	mpapt	ADJ
eurjchem-952	37	26	)	)	PUNCT
eurjchem-952	37	27	and	and	CCONJ
eurjchem-952	37	28	1,10‐phenanthroline	1,10‐phenanthroline	NUM
eurjchem-952	37	29	(	(	PUNCT
eurjchem-952	37	30	1,10‐phen	1,10‐phen	X
eurjchem-952	37	31	)	)	PUNCT
eurjchem-952	37	32	with	with	ADP
eurjchem-952	37	33	different	different	ADJ
eurjchem-952	37	34	bivalent	bivalent	ADJ
eurjchem-952	37	35	transition	transition	NOUN
eurjchem-952	37	36	metal	metal	NOUN
eurjchem-952	37	37	ions	ion	NOUN
eurjchem-952	37	38	co(ii	co(ii	PROPN
eurjchem-952	37	39	)	)	PUNCT
eurjchem-952	37	40	,	,	PUNCT
eurjchem-952	37	41	cu(ii	cu(ii	PROPN
eurjchem-952	37	42	)	)	PUNCT
eurjchem-952	37	43	,	,	PUNCT
eurjchem-952	37	44	mn(ii	mn(ii	PROPN
eurjchem-952	37	45	)	)	PUNCT
eurjchem-952	37	46	and	and	CCONJ
eurjchem-952	37	47	ni(ii	ni(ii	NOUN
eurjchem-952	37	48	)	)	PUNCT
eurjchem-952	37	49	.	.	PUNCT
eurjchem-952	38	1	additionally	additionally	ADV
eurjchem-952	38	2	,	,	PUNCT
eurjchem-952	38	3	our	our	PRON
eurjchem-952	38	4	objective	objective	NOUN
eurjchem-952	38	5	is	be	AUX
eurjchem-952	38	6	also	also	ADV
eurjchem-952	38	7	to	to	PART
eurjchem-952	38	8	study	study	VERB
eurjchem-952	38	9	the	the	DET
eurjchem-952	38	10	antibacterial	antibacterial	ADJ
eurjchem-952	38	11	,	,	PUNCT
eurjchem-952	38	12	antifungal	antifungal	ADJ
eurjchem-952	38	13	and	and	CCONJ
eurjchem-952	38	14	antitumor	antitumor	PROPN
eurjchem-952	38	15	activities	activity	NOUN
eurjchem-952	38	16	of	of	ADP
eurjchem-952	38	17	the	the	DET
eurjchem-952	38	18	synthesized	synthesize	VERB
eurjchem-952	38	19	compounds	compound	NOUN
eurjchem-952	38	20	.	.	PUNCT
eurjchem-952	39	1	2	2	X
eurjchem-952	39	2	.	.	X
eurjchem-952	39	3	experimental	experimental	ADJ
eurjchem-952	39	4	2.1	2.1	NUM
eurjchem-952	39	5	.	.	PUNCT
eurjchem-952	39	6	materials	material	NOUN
eurjchem-952	39	7	and	and	CCONJ
eurjchem-952	39	8	instrumentation	instrumentation	NOUN
eurjchem-952	39	9	all	all	PRON
eurjchem-952	39	10	starting	start	VERB
eurjchem-952	39	11	materials	material	NOUN
eurjchem-952	39	12	were	be	AUX
eurjchem-952	39	13	purchased	purchase	VERB
eurjchem-952	39	14	from	from	ADP
eurjchem-952	39	15	fluka	fluka	NOUN
eurjchem-952	39	16	,	,	PUNCT
eurjchem-952	39	17	riedel	riedel	NOUN
eurjchem-952	39	18	and	and	CCONJ
eurjchem-952	39	19	merck	merck	PROPN
eurjchem-952	39	20	and	and	CCONJ
eurjchem-952	39	21	used	use	VERB
eurjchem-952	39	22	as	as	SCONJ
eurjchem-952	39	23	received	receive	VERB
eurjchem-952	39	24	.	.	PUNCT
eurjchem-952	40	1	the	the	DET
eurjchem-952	40	2	microchemical	microchemical	ADJ
eurjchem-952	40	3	analysis	analysis	NOUN
eurjchem-952	40	4	of	of	ADP
eurjchem-952	40	5	the	the	DET
eurjchem-952	40	6	separated	separate	VERB
eurjchem-952	40	7	solid	solid	ADJ
eurjchem-952	40	8	compounds	compound	NOUN
eurjchem-952	40	9	was	be	AUX
eurjchem-952	40	10	carried	carry	VERB
eurjchem-952	40	11	out	out	ADP
eurjchem-952	40	12	at	at	ADP
eurjchem-952	40	13	the	the	DET
eurjchem-952	40	14	department	department	NOUN
eurjchem-952	40	15	of	of	ADP
eurjchem-952	40	16	chemistry	chemistry	NOUN
eurjchem-952	40	17	,	,	PUNCT
eurjchem-952	40	18	faculty	faculty	NOUN
eurjchem-952	40	19	of	of	ADP
eurjchem-952	40	20	science	science	NOUN
eurjchem-952	40	21	,	,	PUNCT
eurjchem-952	40	22	king	king	NOUN
eurjchem-952	40	23	abdul‐aziz	abdul‐aziz	PROPN
eurjchem-952	40	24	university	university	PROPN
eurjchem-952	40	25	,	,	PUNCT
eurjchem-952	40	26	jeddah	jeddah	PROPN
eurjchem-952	40	27	,	,	PUNCT
eurjchem-952	40	28	21589	21589	NUM
eurjchem-952	40	29	,	,	PUNCT
eurjchem-952	40	30	ksa	ksa	PROPN
eurjchem-952	40	31	.	.	PUNCT
eurjchem-952	41	1	the	the	DET
eurjchem-952	41	2	analyses	analysis	NOUN
eurjchem-952	41	3	were	be	AUX
eurjchem-952	41	4	performed	perform	VERB
eurjchem-952	41	5	twice	twice	ADV
eurjchem-952	41	6	to	to	PART
eurjchem-952	41	7	check	check	VERB
eurjchem-952	41	8	the	the	DET
eurjchem-952	41	9	accuracy	accuracy	NOUN
eurjchem-952	41	10	of	of	ADP
eurjchem-952	41	11	the	the	DET
eurjchem-952	41	12	analyses	analysis	NOUN
eurjchem-952	41	13	data	datum	NOUN
eurjchem-952	41	14	.	.	PUNCT
eurjchem-952	42	1	infrared	infrared	PROPN
eurjchem-952	42	2	spectra	spectra	PROPN
eurjchem-952	42	3	were	be	AUX
eurjchem-952	42	4	recorded	record	VERB
eurjchem-952	42	5	on	on	ADP
eurjchem-952	42	6	8001‐pc	8001‐pc	PROPN
eurjchem-952	42	7	ft‐ir	ft‐ir	NOUN
eurjchem-952	42	8	shimadzu	shimadzu	ADJ
eurjchem-952	42	9	spectrophotometer	spectrophotometer	NOUN
eurjchem-952	42	10	using	use	VERB
eurjchem-952	42	11	kbr	kbr	PROPN
eurjchem-952	42	12	pellets	pellet	NOUN
eurjchem-952	42	13	.	.	PUNCT
eurjchem-952	43	1	the	the	DET
eurjchem-952	43	2	solid	solid	ADJ
eurjchem-952	43	3	reflectance	reflectance	NOUN
eurjchem-952	43	4	spectra	spectra	NOUN
eurjchem-952	43	5	were	be	AUX
eurjchem-952	43	6	measured	measure	VERB
eurjchem-952	43	7	on	on	ADP
eurjchem-952	43	8	a	a	DET
eurjchem-952	43	9	shimadzu	shimadzu	ADJ
eurjchem-952	43	10	3101	3101	NUM
eurjchem-952	43	11	pc	pc	NOUN
eurjchem-952	43	12	spectro‐	spectro‐	NOUN
eurjchem-952	43	13	photometer	photometer	NOUN
eurjchem-952	43	14	.	.	PUNCT
eurjchem-952	44	1	the	the	DET
eurjchem-952	44	2	room	room	NOUN
eurjchem-952	44	3	temperature	temperature	NOUN
eurjchem-952	44	4	magnetic	magnetic	ADJ
eurjchem-952	44	5	susceptibility	susceptibility	NOUN
eurjchem-952	44	6	measurements	measurement	NOUN
eurjchem-952	44	7	for	for	ADP
eurjchem-952	44	8	the	the	DET
eurjchem-952	44	9	complexes	complex	NOUN
eurjchem-952	44	10	were	be	AUX
eurjchem-952	44	11	determined	determine	VERB
eurjchem-952	44	12	by	by	ADP
eurjchem-952	44	13	the	the	DET
eurjchem-952	44	14	gouy	gouy	PROPN
eurjchem-952	44	15	balance	balance	NOUN
eurjchem-952	44	16	using	use	VERB
eurjchem-952	44	17	hg[co(scn)4	hg[co(scn)4	NOUN
eurjchem-952	44	18	]	]	PUNCT
eurjchem-952	44	19	as	as	ADP
eurjchem-952	44	20	a	a	DET
eurjchem-952	44	21	calibrant	calibrant	NOUN
eurjchem-952	44	22	.	.	PUNCT
eurjchem-952	45	1	electron	electron	NOUN
eurjchem-952	45	2	paramagnetic	paramagnetic	ADJ
eurjchem-952	45	3	resonance	resonance	NOUN
eurjchem-952	45	4	(	(	PUNCT
eurjchem-952	45	5	epr	epr	PROPN
eurjchem-952	45	6	)	)	PUNCT
eurjchem-952	45	7	has	have	AUX
eurjchem-952	45	8	matured	mature	VERB
eurjchem-952	45	9	into	into	ADP
eurjchem-952	45	10	a	a	DET
eurjchem-952	45	11	powerful	powerful	ADJ
eurjchem-952	45	12	,	,	PUNCT
eurjchem-952	45	13	versatile	versatile	ADJ
eurjchem-952	45	14	,	,	PUNCT
eurjchem-952	45	15	non‐destructive	non‐destructive	ADJ
eurjchem-952	45	16	,	,	PUNCT
eurjchem-952	45	17	and	and	CCONJ
eurjchem-952	45	18	non‐intrusive	non‐intrusive	ADJ
eurjchem-952	45	19	analytical	analytical	ADJ
eurjchem-952	45	20	method	method	NOUN
eurjchem-952	45	21	.	.	PUNCT
eurjchem-952	46	1	epr	epr	PROPN
eurjchem-952	46	2	signals	signal	NOUN
eurjchem-952	46	3	were	be	AUX
eurjchem-952	46	4	recorded	record	VERB
eurjchem-952	46	5	at	at	ADP
eurjchem-952	46	6	room	room	NOUN
eurjchem-952	46	7	temperature	temperature	NOUN
eurjchem-952	46	8	by	by	ADP
eurjchem-952	46	9	using	use	VERB
eurjchem-952	46	10	a	a	DET
eurjchem-952	46	11	bruker	bruker	NOUN
eurjchem-952	46	12	emx	emx	NOUN
eurjchem-952	46	13	spectrometer	spectrometer	NOUN
eurjchem-952	46	14	(	(	PUNCT
eurjchem-952	46	15	x‐band	x‐band	NUM
eurjchem-952	46	16	)	)	PUNCT
eurjchem-952	46	17	product	product	NOUN
eurjchem-952	46	18	of	of	ADP
eurjchem-952	46	19	bruker	bruker	PROPN
eurjchem-952	46	20	,	,	PUNCT
eurjchem-952	46	21	germany	germany	PROPN
eurjchem-952	46	22	.	.	PUNCT
eurjchem-952	47	1	the	the	DET
eurjchem-952	47	2	operating	operating	NOUN
eurjchem-952	47	3	conditions	condition	NOUN
eurjchem-952	47	4	are	be	AUX
eurjchem-952	47	5	,	,	PUNCT
eurjchem-952	47	6	microwave	microwave	NOUN
eurjchem-952	47	7	power	power	NOUN
eurjchem-952	47	8	=	=	PUNCT
eurjchem-952	47	9	0.201	0.201	NUM
eurjchem-952	47	10	mw	mw	PROPN
eurjchem-952	47	11	,	,	PUNCT
eurjchem-952	47	12	modulation	modulation	NOUN
eurjchem-952	47	13	amplitude	amplitude	NOUN
eurjchem-952	47	14	=	=	SYM
eurjchem-952	47	15	4.00	4.00	NUM
eurjchem-952	47	16	gauss	gauss	NOUN
eurjchem-952	47	17	,	,	PUNCT
eurjchem-952	47	18	modulation	modulation	NOUN
eurjchem-952	47	19	frequency	frequency	NOUN
eurjchem-952	47	20	=	=	SYM
eurjchem-952	47	21	100	100	NUM
eurjchem-952	47	22	khz	khz	NOUN
eurjchem-952	47	23	,	,	PUNCT
eurjchem-952	47	24	sweep	sweep	VERB
eurjchem-952	47	25	width	width	NOUN
eurjchem-952	47	26	=	=	SYM
eurjchem-952	47	27	200	200	NUM
eurjchem-952	47	28	gauss	gauss	ADJ
eurjchem-952	47	29	,	,	PUNCT
eurjchem-952	47	30	microwave	microwave	NOUN
eurjchem-952	47	31	frequency	frequency	NOUN
eurjchem-952	47	32	=	=	SYM
eurjchem-952	47	33	9.775	9.775	NUM
eurjchem-952	47	34	ghz	ghz	NOUN
eurjchem-952	47	35	,	,	PUNCT
eurjchem-952	47	36	time	time	NOUN
eurjchem-952	47	37	constant	constant	ADJ
eurjchem-952	47	38	=	=	SYM
eurjchem-952	47	39	81.92	81.92	NUM
eurjchem-952	47	40	ms	ms	NOUN
eurjchem-952	47	41	and	and	CCONJ
eurjchem-952	47	42	sweep	sweep	VERB
eurjchem-952	47	43	time	time	NOUN
eurjchem-952	47	44	=	=	SYM
eurjchem-952	47	45	20.97	20.97	NUM
eurjchem-952	47	46	s.	s.	NOUN
eurjchem-952	47	47	the	the	DET
eurjchem-952	47	48	detection	detection	NOUN
eurjchem-952	47	49	limits	limit	NOUN
eurjchem-952	47	50	of	of	ADP
eurjchem-952	47	51	epr	epr	PROPN
eurjchem-952	47	52	technique	technique	NOUN
eurjchem-952	47	53	depends	depend	VERB
eurjchem-952	47	54	on	on	ADP
eurjchem-952	47	55	the	the	DET
eurjchem-952	47	56	type	type	NOUN
eurjchem-952	47	57	of	of	ADP
eurjchem-952	47	58	sample	sample	NOUN
eurjchem-952	47	59	,	,	PUNCT
eurjchem-952	47	60	sample	sample	NOUN
eurjchem-952	47	61	size	size	NOUN
eurjchem-952	47	62	,	,	PUNCT
eurjchem-952	47	63	detector	detector	NOUN
eurjchem-952	47	64	sensitivity	sensitivity	NOUN
eurjchem-952	47	65	,	,	PUNCT
eurjchem-952	47	66	frequency	frequency	NOUN
eurjchem-952	47	67	of	of	ADP
eurjchem-952	47	68	the	the	DET
eurjchem-952	47	69	incident	incident	NOUN
eurjchem-952	47	70	microwave	microwave	NOUN
eurjchem-952	47	71	radiation	radiation	NOUN
eurjchem-952	47	72	.	.	PUNCT
eurjchem-952	48	1	2.2	2.2	NUM
eurjchem-952	48	2	.	.	PUNCT
eurjchem-952	48	3	synthesis	synthesis	NOUN
eurjchem-952	48	4	2.2.1	2.2.1	NUM
eurjchem-952	48	5	.	.	PUNCT
eurjchem-952	48	6	synthesis	synthesis	NOUN
eurjchem-952	48	7	of	of	ADP
eurjchem-952	48	8	4‐(2‐pyridyl)‐3‐thiosemicarbazone	4‐(2‐pyridyl)‐3‐thiosemicarbazone	NUM
eurjchem-952	48	9	4‐(2‐pyridyl)‐3‐thiosemicarbazone	4‐(2‐pyridyl)‐3‐thiosemicarbazone	NOUN
eurjchem-952	48	10	is	be	AUX
eurjchem-952	48	11	prepared	prepare	VERB
eurjchem-952	48	12	in	in	ADP
eurjchem-952	48	13	three	three	NUM
eurjchem-952	48	14	steps	step	NOUN
eurjchem-952	48	15	as	as	ADP
eurjchem-952	48	16	follow	follow	NOUN
eurjchem-952	48	17	(	(	PUNCT
eurjchem-952	48	18	scheme	scheme	NOUN
eurjchem-952	48	19	2	2	NUM
eurjchem-952	48	20	)	)	PUNCT
eurjchem-952	48	21	.	.	PUNCT
eurjchem-952	49	1	step	step	NOUN
eurjchem-952	49	2	1	1	NUM
eurjchem-952	49	3	:	:	PUNCT
eurjchem-952	49	4	preparation	preparation	NOUN
eurjchem-952	49	5	of	of	ADP
eurjchem-952	49	6	triethylammonium	triethylammonium	NOUN
eurjchem-952	49	7	n‐2‐pyridyldithio	n‐2‐pyridyldithio	PROPN
eurjchem-952	49	8	carbamate	carbamate	NOUN
eurjchem-952	49	9	:	:	PUNCT
eurjchem-952	49	10	2‐aminopyridine	2‐aminopyridine	NUM
eurjchem-952	49	11	(	(	PUNCT
eurjchem-952	49	12	0.3	0.3	NUM
eurjchem-952	49	13	mol	mol	NOUN
eurjchem-952	49	14	,	,	PUNCT
eurjchem-952	49	15	27.5	27.5	NUM
eurjchem-952	49	16	g	g	NOUN
eurjchem-952	49	17	)	)	PUNCT
eurjchem-952	49	18	,	,	PUNCT
eurjchem-952	49	19	carbon	carbon	NOUN
eurjchem-952	49	20	disulphide	disulphide	ADV
eurjchem-952	49	21	(	(	PUNCT
eurjchem-952	49	22	0.3	0.3	NUM
eurjchem-952	49	23	mol	mol	NOUN
eurjchem-952	49	24	,	,	PUNCT
eurjchem-952	49	25	18	18	NUM
eurjchem-952	49	26	ml	ml	NOUN
eurjchem-952	49	27	)	)	PUNCT
eurjchem-952	49	28	and	and	CCONJ
eurjchem-952	49	29	triethylamine	triethylamine	NOUN
eurjchem-952	49	30	(	(	PUNCT
eurjchem-952	49	31	0.3	0.3	NUM
eurjchem-952	49	32	mol	mol	NOUN
eurjchem-952	49	33	,	,	PUNCT
eurjchem-952	49	34	45	45	NUM
eurjchem-952	49	35	ml	ml	NOUN
eurjchem-952	49	36	)	)	PUNCT
eurjchem-952	49	37	were	be	AUX
eurjchem-952	49	38	warmed	warm	VERB
eurjchem-952	49	39	to	to	PART
eurjchem-952	49	40	give	give	VERB
eurjchem-952	49	41	a	a	DET
eurjchem-952	49	42	clear	clear	ADJ
eurjchem-952	49	43	solution	solution	NOUN
eurjchem-952	49	44	.	.	PUNCT
eurjchem-952	50	1	two	two	NUM
eurjchem-952	50	2	phases	phase	NOUN
eurjchem-952	50	3	separated	separate	VERB
eurjchem-952	50	4	rapidly	rapidly	ADV
eurjchem-952	50	5	and	and	CCONJ
eurjchem-952	50	6	the	the	DET
eurjchem-952	50	7	whole	whole	ADJ
eurjchem-952	50	8	mixture	mixture	NOUN
eurjchem-952	50	9	was	be	AUX
eurjchem-952	50	10	shaken	shake	VERB
eurjchem-952	50	11	at	at	ADP
eurjchem-952	50	12	room	room	NOUN
eurjchem-952	50	13	temperature	temperature	NOUN
eurjchem-952	50	14	for	for	ADP
eurjchem-952	50	15	24	24	NUM
eurjchem-952	50	16	h	h	NOUN
eurjchem-952	50	17	,	,	PUNCT
eurjchem-952	50	18	the	the	DET
eurjchem-952	50	19	whole	whole	NOUN
eurjchem-952	50	20	had	have	AUX
eurjchem-952	50	21	then	then	ADV
eurjchem-952	50	22	solidified	solidify	VERB
eurjchem-952	50	23	.	.	PUNCT
eurjchem-952	51	1	the	the	DET
eurjchem-952	51	2	product	product	NOUN
eurjchem-952	51	3	was	be	AUX
eurjchem-952	51	4	filtered	filter	VERB
eurjchem-952	51	5	and	and	CCONJ
eurjchem-952	51	6	then	then	ADV
eurjchem-952	51	7	washed	wash	VERB
eurjchem-952	51	8	with	with	ADP
eurjchem-952	51	9	ether	ether	NOUN
eurjchem-952	51	10	and	and	CCONJ
eurjchem-952	51	11	air‐dried	air‐drie	VERB
eurjchem-952	51	12	.	.	PUNCT
eurjchem-952	52	1	the	the	DET
eurjchem-952	52	2	lemon‐yellow	lemon‐yellow	ADJ
eurjchem-952	52	3	plates	plate	NOUN
eurjchem-952	52	4	formed	form	VERB
eurjchem-952	52	5	were	be	AUX
eurjchem-952	52	6	triethylammonium	triethylammonium	ADV
eurjchem-952	52	7	n‐2‐	n‐2‐	ADJ
eurjchem-952	52	8	pyridyldithiocarbamate	pyridyldithiocarbamate	NOUN
eurjchem-952	52	9	,	,	PUNCT
eurjchem-952	52	10	m.p	m.p	PROPN
eurjchem-952	52	11	.	.	PROPN
eurjchem-952	52	12	:	:	PUNCT
eurjchem-952	52	13	85	85	NUM
eurjchem-952	52	14	oc	oc	NOUN
eurjchem-952	52	15	.	.	PUNCT
eurjchem-952	52	16	step	step	NOUN
eurjchem-952	52	17	2	2	NUM
eurjchem-952	52	18	:	:	PUNCT
eurjchem-952	52	19	preparation	preparation	NOUN
eurjchem-952	52	20	of	of	ADP
eurjchem-952	52	21	methyl‐2‐pyridyldithiocarbamate	methyl‐2‐pyridyldithiocarbamate	PROPN
eurjchem-952	52	22	:	:	PUNCT
eurjchem-952	52	23	methanol	methanol	NOUN
eurjchem-952	52	24	(	(	PUNCT
eurjchem-952	52	25	100	100	NUM
eurjchem-952	52	26	ml	ml	NOUN
eurjchem-952	52	27	)	)	PUNCT
eurjchem-952	52	28	was	be	AUX
eurjchem-952	52	29	added	add	VERB
eurjchem-952	52	30	to	to	PART
eurjchem-952	52	31	triethylammonium	triethylammonium	VERB
eurjchem-952	52	32	n‐2‐	n‐2‐	ADJ
eurjchem-952	52	33	pyridyldithiocarbamate	pyridyldithiocarbamate	NOUN
eurjchem-952	52	34	(	(	PUNCT
eurjchem-952	52	35	49.0	49.0	NUM
eurjchem-952	52	36	g	g	NOUN
eurjchem-952	52	37	,	,	PUNCT
eurjchem-952	52	38	0.18	0.18	NUM
eurjchem-952	52	39	mol	mol	NOUN
eurjchem-952	52	40	)	)	PUNCT
eurjchem-952	52	41	,	,	PUNCT
eurjchem-952	52	42	followed	follow	VERB
eurjchem-952	52	43	by	by	ADP
eurjchem-952	52	44	methyl	methyl	NOUN
eurjchem-952	52	45	iodide	iodide	NOUN
eurjchem-952	52	46	(	(	PUNCT
eurjchem-952	52	47	13	13	NUM
eurjchem-952	52	48	ml	ml	NOUN
eurjchem-952	52	49	,	,	PUNCT
eurjchem-952	52	50	0.2	0.2	NUM
eurjchem-952	52	51	mol	mol	NOUN
eurjchem-952	52	52	)	)	PUNCT
eurjchem-952	52	53	.	.	PUNCT
eurjchem-952	53	1	after	after	ADP
eurjchem-952	53	2	1	1	NUM
eurjchem-952	53	3	h	h	NOUN
eurjchem-952	53	4	,	,	PUNCT
eurjchem-952	53	5	water	water	NOUN
eurjchem-952	53	6	was	be	AUX
eurjchem-952	53	7	added	add	VERB
eurjchem-952	53	8	into	into	ADP
eurjchem-952	53	9	the	the	DET
eurjchem-952	53	10	solution	solution	NOUN
eurjchem-952	53	11	and	and	CCONJ
eurjchem-952	53	12	pale	pale	ADJ
eurjchem-952	53	13	yellow	yellow	ADJ
eurjchem-952	53	14	needles	needle	NOUN
eurjchem-952	53	15	of	of	ADP
eurjchem-952	53	16	methyl‐2‐pyridyldithio	methyl‐2‐pyridyldithio	NUM
eurjchem-952	53	17	carbamate	carbamate	NOUN
eurjchem-952	53	18	were	be	AUX
eurjchem-952	53	19	formed	form	VERB
eurjchem-952	53	20	,	,	PUNCT
eurjchem-952	53	21	m.p	m.p	PROPN
eurjchem-952	53	22	.	.	PROPN
eurjchem-952	53	23	:	:	PUNCT
eurjchem-952	54	1	101	101	NUM
eurjchem-952	54	2	oc	oc	NOUN
eurjchem-952	54	3	.	.	PUNCT
eurjchem-952	55	1	step	step	VERB
eurjchem-952	55	2	3	3	NUM
eurjchem-952	55	3	:	:	PUNCT
eurjchem-952	55	4	preparation	preparation	NOUN
eurjchem-952	55	5	of	of	ADP
eurjchem-952	55	6	4‐(2‐pyridyl)‐3‐thiosemicarbazide	4‐(2‐pyridyl)‐3‐thiosemicarbazide	NUM
eurjchem-952	55	7	:	:	PUNCT
eurjchem-952	55	8	a	a	DET
eurjchem-952	55	9	mixture	mixture	NOUN
eurjchem-952	55	10	of	of	ADP
eurjchem-952	55	11	0.26	0.26	NUM
eurjchem-952	55	12	mol	mol	NOUN
eurjchem-952	55	13	(	(	PUNCT
eurjchem-952	55	14	50.0	50.0	NUM
eurjchem-952	55	15	g	g	NOUN
eurjchem-952	55	16	)	)	PUNCT
eurjchem-952	55	17	of	of	ADP
eurjchem-952	55	18	methyl‐2‐pyridyldithio	methyl‐2‐pyridyldithio	NUM
eurjchem-952	55	19	carbamate	carbamate	NOUN
eurjchem-952	55	20	and	and	CCONJ
eurjchem-952	55	21	26	26	NUM
eurjchem-952	55	22	ml	ml	NOUN
eurjchem-952	55	23	(	(	PUNCT
eurjchem-952	55	24	0.80	0.80	NUM
eurjchem-952	55	25	mol	mol	NOUN
eurjchem-952	55	26	)	)	PUNCT
eurjchem-952	55	27	of	of	ADP
eurjchem-952	55	28	hydrazine	hydrazine	NOUN
eurjchem-952	55	29	hydrate	hydrate	NOUN
eurjchem-952	55	30	in	in	ADP
eurjchem-952	55	31	20	20	NUM
eurjchem-952	55	32	ml	ml	NOUN
eurjchem-952	55	33	of	of	ADP
eurjchem-952	55	34	absolute	absolute	ADJ
eurjchem-952	55	35	ethanol	ethanol	NOUN
eurjchem-952	55	36	was	be	AUX
eurjchem-952	55	37	heated	heat	VERB
eurjchem-952	55	38	for	for	ADP
eurjchem-952	55	39	10	10	NUM
eurjchem-952	55	40	min	min	NOUN
eurjchem-952	55	41	.	.	PUNCT
eurjchem-952	56	1	an	an	DET
eurjchem-952	56	2	abundant	abundant	ADJ
eurjchem-952	56	3	amount	amount	NOUN
eurjchem-952	56	4	of	of	ADP
eurjchem-952	56	5	crystalline	crystalline	ADJ
eurjchem-952	56	6	precipitate	precipitate	NOUN
eurjchem-952	56	7	of	of	ADP
eurjchem-952	56	8	4‐(2‐pyridyl)‐3‐thiosemi	4‐(2‐pyridyl)‐3‐thiosemi	NUM
eurjchem-952	56	9	carbazide	carbazide	NOUN
eurjchem-952	56	10	was	be	AUX
eurjchem-952	56	11	formed	form	VERB
eurjchem-952	56	12	,	,	PUNCT
eurjchem-952	56	13	m.p	m.p	PROPN
eurjchem-952	56	14	.	.	PROPN
eurjchem-952	56	15	:	:	PUNCT
eurjchem-952	56	16	193	193	NUM
eurjchem-952	56	17	°	°	SYM
eurjchem-952	56	18	c	c	NOUN
eurjchem-952	56	19	.	.	PUNCT
eurjchem-952	57	1	anal	anal	ADJ
eurjchem-952	57	2	.	.	PUNCT
eurjchem-952	57	3	calcd	calcd	NOUN
eurjchem-952	57	4	.	.	PUNCT
eurjchem-952	58	1	for	for	SCONJ
eurjchem-952	58	2	c6h8n4s	c6h8n4s	PROPN
eurjchem-952	58	3	:	:	PUNCT
eurjchem-952	58	4	c	c	X
eurjchem-952	58	5	,	,	PUNCT
eurjchem-952	58	6	42.84	42.84	NUM
eurjchem-952	58	7	;	;	PUNCT
eurjchem-952	58	8	h	h	NOUN
eurjchem-952	58	9	,	,	PUNCT
eurjchem-952	58	10	4.79	4.79	NUM
eurjchem-952	58	11	;	;	PUNCT
eurjchem-952	58	12	n	n	CCONJ
eurjchem-952	58	13	,	,	PUNCT
eurjchem-952	58	14	33.31	33.31	NUM
eurjchem-952	58	15	.	.	PUNCT
eurjchem-952	58	16	found	find	VERB
eurjchem-952	58	17	:	:	PUNCT
eurjchem-952	59	1	c	c	X
eurjchem-952	59	2	,	,	PUNCT
eurjchem-952	59	3	42.30	42.30	NUM
eurjchem-952	59	4	;	;	PUNCT
eurjchem-952	59	5	h	h	NOUN
eurjchem-952	59	6	,	,	PUNCT
eurjchem-952	59	7	4.62	4.62	NUM
eurjchem-952	59	8	;	;	PUNCT
eurjchem-952	59	9	n	n	CCONJ
eurjchem-952	59	10	,	,	PUNCT
eurjchem-952	59	11	33.10	33.10	NUM
eurjchem-952	59	12	%	%	NOUN
eurjchem-952	59	13	.	.	PUNCT
eurjchem-952	60	1	2.2.2	2.2.2	X
eurjchem-952	60	2	.	.	X
eurjchem-952	60	3	synthesis	synthesis	NOUN
eurjchem-952	60	4	of	of	ADP
eurjchem-952	60	5	1‐methylpyrazole‐3‐aldehyde‐4‐(2‐	1‐methylpyrazole‐3‐aldehyde‐4‐(2‐	NUM
eurjchem-952	60	6	pyridyl)thiosemicarbazone	pyridyl)thiosemicarbazone	NOUN
eurjchem-952	60	7	(	(	PUNCT
eurjchem-952	60	8	mpapt	mpapt	NOUN
eurjchem-952	60	9	)	)	PUNCT
eurjchem-952	60	10	the	the	DET
eurjchem-952	60	11	general	general	ADJ
eurjchem-952	60	12	route	route	NOUN
eurjchem-952	60	13	of	of	ADP
eurjchem-952	60	14	synthesis	synthesis	NOUN
eurjchem-952	60	15	(	(	PUNCT
eurjchem-952	60	16	scheme	scheme	NOUN
eurjchem-952	60	17	3	3	NUM
eurjchem-952	60	18	)	)	PUNCT
eurjchem-952	60	19	is	be	AUX
eurjchem-952	60	20	shown	show	VERB
eurjchem-952	60	21	in	in	ADP
eurjchem-952	60	22	the	the	DET
eurjchem-952	60	23	following	following	NOUN
eurjchem-952	60	24	:	:	PUNCT
eurjchem-952	60	25	equimolar	equimolar	NOUN
eurjchem-952	60	26	amounts	amount	NOUN
eurjchem-952	60	27	of	of	ADP
eurjchem-952	60	28	4‐(2‐pyridyl)‐3‐	4‐(2‐pyridyl)‐3‐	NUM
eurjchem-952	60	29	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-952	60	30	(	(	PUNCT
eurjchem-952	60	31	0.1682	0.1682	NUM
eurjchem-952	60	32	g	g	NOUN
eurjchem-952	60	33	,	,	PUNCT
eurjchem-952	60	34	1	1	NUM
eurjchem-952	60	35	mmol	mmol	NOUN
eurjchem-952	60	36	)	)	PUNCT
eurjchem-952	60	37	in	in	ADP
eurjchem-952	60	38	25	25	NUM
eurjchem-952	60	39	ml	ml	NOUN
eurjchem-952	60	40	ethanol	ethanol	NOUN
eurjchem-952	60	41	with	with	ADP
eurjchem-952	60	42	an	an	DET
eurjchem-952	60	43	ethanolic	ethanolic	ADJ
eurjchem-952	60	44	solution	solution	NOUN
eurjchem-952	60	45	(	(	PUNCT
eurjchem-952	60	46	25	25	NUM
eurjchem-952	60	47	ml	ml	NOUN
eurjchem-952	60	48	)	)	PUNCT
eurjchem-952	60	49	of	of	ADP
eurjchem-952	60	50	1‐methyl‐1‐h‐pyrazole‐5‐	1‐methyl‐1‐h‐pyrazole‐5‐	NUM
eurjchem-952	60	51	carboxaldehyde	carboxaldehyde	NOUN
eurjchem-952	60	52	(	(	PUNCT
eurjchem-952	60	53	0.110	0.110	NUM
eurjchem-952	60	54	g	g	NOUN
eurjchem-952	60	55	,	,	PUNCT
eurjchem-952	60	56	1	1	NUM
eurjchem-952	60	57	mmol	mmol	NOUN
eurjchem-952	60	58	)	)	PUNCT
eurjchem-952	60	59	.	.	PUNCT
eurjchem-952	61	1	the	the	DET
eurjchem-952	61	2	reaction	reaction	NOUN
eurjchem-952	61	3	mixture	mixture	NOUN
eurjchem-952	61	4	was	be	AUX
eurjchem-952	61	5	then	then	ADV
eurjchem-952	61	6	refluxed	refluxe	VERB
eurjchem-952	61	7	on	on	ADP
eurjchem-952	61	8	a	a	DET
eurjchem-952	61	9	hot	hot	ADJ
eurjchem-952	61	10	plate	plate	NOUN
eurjchem-952	61	11	for	for	ADP
eurjchem-952	61	12	2‐3	2‐3	NUM
eurjchem-952	61	13	h.	h.	NOUN
eurjchem-952	61	14	the	the	DET
eurjchem-952	61	15	obtained	obtain	VERB
eurjchem-952	61	16	precipitates	precipitate	NOUN
eurjchem-952	61	17	were	be	AUX
eurjchem-952	61	18	separated	separate	VERB
eurjchem-952	61	19	out	out	ADP
eurjchem-952	61	20	,	,	PUNCT
eurjchem-952	61	21	filtered	filter	VERB
eurjchem-952	61	22	off	off	ADP
eurjchem-952	61	23	,	,	PUNCT
eurjchem-952	61	24	washed	wash	VERB
eurjchem-952	61	25	with	with	ADP
eurjchem-952	61	26	diethyl	diethyl	NOUN
eurjchem-952	61	27	ether	ether	NOUN
eurjchem-952	61	28	and	and	CCONJ
eurjchem-952	61	29	dried	dry	VERB
eurjchem-952	61	30	overnight	overnight	ADV
eurjchem-952	61	31	under	under	ADP
eurjchem-952	61	32	silica	silica	NOUN
eurjchem-952	61	33	gel	gel	NOUN
eurjchem-952	61	34	.	.	PUNCT
eurjchem-952	62	1	the	the	DET
eurjchem-952	62	2	proposed	propose	VERB
eurjchem-952	62	3	chemical	chemical	NOUN
eurjchem-952	62	4	structure	structure	NOUN
eurjchem-952	62	5	of	of	ADP
eurjchem-952	62	6	the	the	DET
eurjchem-952	62	7	prepared	prepare	VERB
eurjchem-952	62	8	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-952	62	9	compound	compound	NOUN
eurjchem-952	62	10	is	be	AUX
eurjchem-952	62	11	in	in	ADP
eurjchem-952	62	12	a	a	DET
eurjchem-952	62	13	good	good	ADJ
eurjchem-952	62	14	agreement	agreement	NOUN
eurjchem-952	62	15	with	with	ADP
eurjchem-952	62	16	the	the	DET
eurjchem-952	62	17	stoichiometries	stoichiometry	NOUN
eurjchem-952	62	18	concluded	conclude	VERB
eurjchem-952	62	19	from	from	ADP
eurjchem-952	62	20	their	their	PRON
eurjchem-952	62	21	analytical	analytical	ADJ
eurjchem-952	62	22	data	datum	NOUN
eurjchem-952	62	23	and	and	CCONJ
eurjchem-952	62	24	confirmed	confirm	VERB
eurjchem-952	62	25	by	by	ADP
eurjchem-952	62	26	the	the	DET
eurjchem-952	62	27	ir	ir	PROPN
eurjchem-952	62	28	spectral	spectral	PROPN
eurjchem-952	62	29	data	data	PROPN
eurjchem-952	62	30	.	.	PUNCT
eurjchem-952	63	1	ft‐ir	ft‐ir	NOUN
eurjchem-952	63	2	(	(	PUNCT
eurjchem-952	63	3	kbr	kbr	PROPN
eurjchem-952	63	4	,	,	PUNCT
eurjchem-952	63	5	ν	ν	PROPN
eurjchem-952	63	6	,	,	PUNCT
eurjchem-952	63	7	cm‐1	cm‐1	PROPN
eurjchem-952	63	8	):	):	PUNCT
eurjchem-952	63	9	3188	3188	NUM
eurjchem-952	63	10	(	(	PUNCT
eurjchem-952	63	11	νn1h	νn1h	NOUN
eurjchem-952	63	12	)	)	PUNCT
eurjchem-952	63	13	,	,	PUNCT
eurjchem-952	63	14	3168	3168	NUM
eurjchem-952	63	15	(	(	PUNCT
eurjchem-952	63	16	νn2h	νn2h	PROPN
eurjchem-952	63	17	)	)	PUNCT
eurjchem-952	63	18	,	,	PUNCT
eurjchem-952	63	19	1648	1648	NUM
eurjchem-952	63	20	(	(	PUNCT
eurjchem-952	63	21	νc	νc	NOUN
eurjchem-952	63	22	=	=	NOUN
eurjchem-952	63	23	nazomethine	nazomethine	NOUN
eurjchem-952	63	24	)	)	PUNCT
eurjchem-952	63	25	,	,	PUNCT
eurjchem-952	63	26	1549	1549	NUM
eurjchem-952	63	27	(	(	PUNCT
eurjchem-952	63	28	νc	νc	NOUN
eurjchem-952	63	29	=	=	NOUN
eurjchem-952	63	30	npyridine	npyridine	NOUN
eurjchem-952	63	31	)	)	PUNCT
eurjchem-952	63	32	,	,	PUNCT
eurjchem-952	63	33	1300	1300	NUM
eurjchem-952	63	34	,	,	PUNCT
eurjchem-952	63	35	825	825	NUM
eurjchem-952	63	36	(	(	PUNCT
eurjchem-952	63	37	νc	νc	NOUN
eurjchem-952	63	38	=	=	SYM
eurjchem-952	63	39	s	s	NOUN
eurjchem-952	63	40	)	)	PUNCT
eurjchem-952	63	41	,	,	PUNCT
eurjchem-952	63	42	1068	1068	NUM
eurjchem-952	63	43	(	(	PUNCT
eurjchem-952	63	44	νn‐n	νn‐n	NUM
eurjchem-952	63	45	)	)	PUNCT
eurjchem-952	63	46	,	,	PUNCT
eurjchem-952	63	47	622	622	NUM
eurjchem-952	63	48	(	(	PUNCT
eurjchem-952	63	49	δc	δc	NOUN
eurjchem-952	63	50	=	=	NOUN
eurjchem-952	63	51	npyridine	npyridine	NOUN
eurjchem-952	63	52	)	)	PUNCT
eurjchem-952	63	53	.	.	PUNCT
eurjchem-952	64	1	anal	anal	PROPN
eurjchem-952	64	2	.	.	PUNCT
eurjchem-952	64	3	calcd	calcd	NOUN
eurjchem-952	64	4	.	.	PUNCT
eurjchem-952	65	1	for	for	ADP
eurjchem-952	65	2	c11h12n6s	c11h12n6s	PRON
eurjchem-952	65	3	:	:	PUNCT
eurjchem-952	65	4	c	c	X
eurjchem-952	65	5	,	,	PUNCT
eurjchem-952	65	6	50.75	50.75	NUM
eurjchem-952	65	7	;	;	PUNCT
eurjchem-952	65	8	h	h	NOUN
eurjchem-952	65	9	,	,	PUNCT
eurjchem-952	65	10	4.65	4.65	NUM
eurjchem-952	65	11	;	;	PUNCT
eurjchem-952	65	12	n	n	CCONJ
eurjchem-952	65	13	,	,	PUNCT
eurjchem-952	65	14	32.28	32.28	NUM
eurjchem-952	65	15	.	.	PUNCT
eurjchem-952	65	16	found	find	VERB
eurjchem-952	65	17	:	:	PUNCT
eurjchem-952	66	1	c	c	X
eurjchem-952	66	2	,	,	PUNCT
eurjchem-952	66	3	50.90	50.90	NUM
eurjchem-952	66	4	;	;	PUNCT
eurjchem-952	66	5	h	h	NOUN
eurjchem-952	66	6	,	,	PUNCT
eurjchem-952	66	7	4.70	4.70	NUM
eurjchem-952	66	8	;	;	PUNCT
eurjchem-952	66	9	n	n	CCONJ
eurjchem-952	66	10	,	,	PUNCT
eurjchem-952	66	11	32.38	32.38	NUM
eurjchem-952	66	12	%	%	NOUN
eurjchem-952	66	13	.	.	PUNCT
eurjchem-952	67	1	aljahdali	aljahdali	PROPN
eurjchem-952	67	2	et	et	PROPN
eurjchem-952	67	3	al	al	PROPN
eurjchem-952	67	4	.	.	PUNCT
eurjchem-952	67	5	/	/	SYM
eurjchem-952	67	6	european	european	PROPN
eurjchem-952	67	7	journal	journal	PROPN
eurjchem-952	67	8	of	of	ADP
eurjchem-952	67	9	chemistry	chemistry	NOUN
eurjchem-952	67	10	5	5	NUM
eurjchem-952	67	11	(	(	PUNCT
eurjchem-952	67	12	2	2	NUM
eurjchem-952	67	13	)	)	PUNCT
eurjchem-952	67	14	(	(	PUNCT
eurjchem-952	67	15	2014	2014	NUM
eurjchem-952	67	16	)	)	PUNCT
eurjchem-952	68	1	201‐208	201‐208	NUM
eurjchem-952	68	2	203	203	NUM
eurjchem-952	68	3	n	n	CCONJ
eurjchem-952	68	4	n	n	PRON
eurjchem-952	68	5	h	h	NOUN
eurjchem-952	68	6	s	s	PART
eurjchem-952	68	7	n	n	ADV
eurjchem-952	68	8	h	h	NOUN
eurjchem-952	68	9	nh2	nh2	PROPN
eurjchem-952	68	10	+	+	CCONJ
eurjchem-952	68	11	n	n	CCONJ
eurjchem-952	68	12	n	n	PRON
eurjchem-952	68	13	o	o	NOUN
eurjchem-952	68	14	h	h	NOUN
eurjchem-952	68	15	ch3	ch3	PROPN
eurjchem-952	68	16	n	n	CCONJ
eurjchem-952	68	17	n	n	PROPN
eurjchem-952	68	18	ch3	ch3	PROPN
eurjchem-952	68	19	n	n	CCONJ
eurjchem-952	68	20	n	n	NOUN
eurjchem-952	68	21	h	h	NOUN
eurjchem-952	68	22	s	s	PART
eurjchem-952	68	23	n	n	NUM
eurjchem-952	68	24	h	h	NOUN
eurjchem-952	68	25	n	n	NOUN
eurjchem-952	68	26	h	h	NOUN
eurjchem-952	68	27	scheme	scheme	NOUN
eurjchem-952	68	28	3	3	NUM
eurjchem-952	68	29	2.2.3	2.2.3	NUM
eurjchem-952	68	30	.	.	PUNCT
eurjchem-952	69	1	synthesis	synthesis	NOUN
eurjchem-952	69	2	of	of	ADP
eurjchem-952	69	3	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-952	69	4	complexes	complexe	VERB
eurjchem-952	69	5	all	all	DET
eurjchem-952	69	6	complexes	complex	NOUN
eurjchem-952	69	7	were	be	AUX
eurjchem-952	69	8	prepared	prepare	VERB
eurjchem-952	69	9	by	by	ADP
eurjchem-952	69	10	refluxing	refluxe	VERB
eurjchem-952	69	11	an	an	DET
eurjchem-952	69	12	ethanolic	ethanolic	ADJ
eurjchem-952	69	13	solution	solution	NOUN
eurjchem-952	69	14	of	of	ADP
eurjchem-952	69	15	the	the	DET
eurjchem-952	69	16	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-952	69	17	(	(	PUNCT
eurjchem-952	69	18	mpapt	mpapt	ADJ
eurjchem-952	69	19	)	)	PUNCT
eurjchem-952	69	20	ligand	ligand	NOUN
eurjchem-952	69	21	(	(	PUNCT
eurjchem-952	69	22	1	1	NUM
eurjchem-952	69	23	mmol	mmol	NOUN
eurjchem-952	69	24	)	)	PUNCT
eurjchem-952	69	25	and	and	CCONJ
eurjchem-952	69	26	1,10‐phenanthroline	1,10‐phenanthroline	NUM
eurjchem-952	69	27	heterocyclic	heterocyclic	ADJ
eurjchem-952	69	28	base	base	NOUN
eurjchem-952	69	29	(	(	PUNCT
eurjchem-952	69	30	1	1	NUM
eurjchem-952	69	31	mmol	mmol	NOUN
eurjchem-952	69	32	)	)	PUNCT
eurjchem-952	69	33	with	with	ADP
eurjchem-952	69	34	an	an	DET
eurjchem-952	69	35	ethanolic	ethanolic	ADJ
eurjchem-952	69	36	solution	solution	NOUN
eurjchem-952	69	37	of	of	ADP
eurjchem-952	69	38	metal	metal	NOUN
eurjchem-952	69	39	salt	salt	NOUN
eurjchem-952	69	40	(	(	PUNCT
eurjchem-952	69	41	1	1	NUM
eurjchem-952	69	42	mmol	mmol	NOUN
eurjchem-952	69	43	)	)	PUNCT
eurjchem-952	69	44	in	in	ADP
eurjchem-952	69	45	the	the	DET
eurjchem-952	69	46	molar	molar	ADJ
eurjchem-952	69	47	ratio	ratio	NOUN
eurjchem-952	69	48	1:1:1	1:1:1	PROPN
eurjchem-952	69	49	.	.	PUNCT
eurjchem-952	70	1	the	the	DET
eurjchem-952	70	2	reaction	reaction	NOUN
eurjchem-952	70	3	mixtures	mixture	NOUN
eurjchem-952	70	4	were	be	AUX
eurjchem-952	70	5	refluxed	refluxe	VERB
eurjchem-952	70	6	on	on	ADP
eurjchem-952	70	7	a	a	DET
eurjchem-952	70	8	water	water	NOUN
eurjchem-952	70	9	bath	bath	NOUN
eurjchem-952	70	10	for	for	ADP
eurjchem-952	70	11	4	4	NUM
eurjchem-952	70	12	h	h	NOUN
eurjchem-952	70	13	and	and	CCONJ
eurjchem-952	70	14	allowed	allow	VERB
eurjchem-952	70	15	to	to	PART
eurjchem-952	70	16	cool	cool	VERB
eurjchem-952	70	17	to	to	PART
eurjchem-952	70	18	room	room	VERB
eurjchem-952	70	19	temperature	temperature	NOUN
eurjchem-952	70	20	overnight	overnight	ADV
eurjchem-952	70	21	.	.	PUNCT
eurjchem-952	71	1	the	the	DET
eurjchem-952	71	2	precipitated	precipitate	VERB
eurjchem-952	71	3	complexes	complex	NOUN
eurjchem-952	71	4	were	be	AUX
eurjchem-952	71	5	then	then	ADV
eurjchem-952	71	6	filtered	filter	VERB
eurjchem-952	71	7	off	off	ADP
eurjchem-952	71	8	,	,	PUNCT
eurjchem-952	71	9	washed	wash	VERB
eurjchem-952	71	10	with	with	ADP
eurjchem-952	71	11	petroleum	petroleum	NOUN
eurjchem-952	71	12	ether	ether	NOUN
eurjchem-952	71	13	and	and	CCONJ
eurjchem-952	71	14	dried	dry	VERB
eurjchem-952	71	15	overnight	overnight	ADV
eurjchem-952	71	16	in	in	ADP
eurjchem-952	71	17	a	a	DET
eurjchem-952	71	18	vacuum	vacuum	NOUN
eurjchem-952	71	19	desiccator	desiccator	NOUN
eurjchem-952	71	20	.	.	PUNCT
eurjchem-952	72	1	[	[	X
eurjchem-952	72	2	cu(mpapt)(1,10‐phen)(cl	cu(mpapt)(1,10‐phen)(cl	NOUN
eurjchem-952	72	3	)	)	PUNCT
eurjchem-952	72	4	]	]	X
eurjchem-952	72	5	complex	complex	ADJ
eurjchem-952	72	6	(	(	PUNCT
eurjchem-952	72	7	1	1	NUM
eurjchem-952	72	8	):	):	PUNCT
eurjchem-952	72	9	yield	yield	NOUN
eurjchem-952	72	10	:	:	PUNCT
eurjchem-952	72	11	77	77	NUM
eurjchem-952	72	12	%	%	NOUN
eurjchem-952	72	13	.	.	PUNCT
eurjchem-952	73	1	ft‐ir	ft‐ir	NOUN
eurjchem-952	73	2	(	(	PUNCT
eurjchem-952	73	3	kbr	kbr	PROPN
eurjchem-952	73	4	,	,	PUNCT
eurjchem-952	73	5	ν	ν	PROPN
eurjchem-952	73	6	,	,	PUNCT
eurjchem-952	73	7	cm‐1	cm‐1	PROPN
eurjchem-952	73	8	):	):	PUNCT
eurjchem-952	73	9	3208	3208	NUM
eurjchem-952	73	10	(	(	PUNCT
eurjchem-952	73	11	νn1h	νn1h	NOUN
eurjchem-952	73	12	)	)	PUNCT
eurjchem-952	73	13	,	,	PUNCT
eurjchem-952	73	14	1602	1602	NUM
eurjchem-952	73	15	(	(	PUNCT
eurjchem-952	73	16	νc	νc	NOUN
eurjchem-952	73	17	=	=	NOUN
eurjchem-952	73	18	nazomethine	nazomethine	NOUN
eurjchem-952	73	19	)	)	PUNCT
eurjchem-952	73	20	,	,	PUNCT
eurjchem-952	73	21	1591	1591	NUM
eurjchem-952	73	22	(	(	PUNCT
eurjchem-952	73	23	νn	νn	NOUN
eurjchem-952	73	24	=	=	SYM
eurjchem-952	73	25	c	c	NOUN
eurjchem-952	73	26	)	)	PUNCT
eurjchem-952	73	27	,	,	PUNCT
eurjchem-952	73	28	1525	1525	NUM
eurjchem-952	73	29	(	(	PUNCT
eurjchem-952	73	30	νc	νc	NOUN
eurjchem-952	73	31	=	=	NOUN
eurjchem-952	73	32	npyridine	npyridine	NOUN
eurjchem-952	73	33	)	)	PUNCT
eurjchem-952	73	34	,	,	PUNCT
eurjchem-952	73	35	1279	1279	NUM
eurjchem-952	73	36	,	,	PUNCT
eurjchem-952	73	37	825	825	NUM
eurjchem-952	73	38	(	(	PUNCT
eurjchem-952	73	39	νc	νc	NOUN
eurjchem-952	73	40	=	=	SYM
eurjchem-952	73	41	s	s	NOUN
eurjchem-952	73	42	)	)	PUNCT
eurjchem-952	73	43	,	,	PUNCT
eurjchem-952	73	44	1070	1070	NUM
eurjchem-952	73	45	(	(	PUNCT
eurjchem-952	73	46	νn‐n	νn‐n	NUM
eurjchem-952	73	47	)	)	PUNCT
eurjchem-952	73	48	,	,	PUNCT
eurjchem-952	73	49	615	615	NUM
eurjchem-952	73	50	(	(	PUNCT
eurjchem-952	73	51	δc	δc	NOUN
eurjchem-952	73	52	=	=	NOUN
eurjchem-952	73	53	npyridine	npyridine	NOUN
eurjchem-952	73	54	)	)	PUNCT
eurjchem-952	73	55	,	,	PUNCT
eurjchem-952	73	56	452	452	NUM
eurjchem-952	73	57	(	(	PUNCT
eurjchem-952	73	58	νm‐n	νm‐n	NUM
eurjchem-952	73	59	)	)	PUNCT
eurjchem-952	73	60	,	,	PUNCT
eurjchem-952	73	61	275	275	NUM
eurjchem-952	73	62	(	(	PUNCT
eurjchem-952	73	63	νm‐npy	νm‐npy	PROPN
eurjchem-952	73	64	)	)	PUNCT
eurjchem-952	73	65	,	,	PUNCT
eurjchem-952	73	66	343	343	NUM
eurjchem-952	73	67	(	(	PUNCT
eurjchem-952	73	68	νm‐s	νm‐s	PROPN
eurjchem-952	73	69	)	)	PUNCT
eurjchem-952	73	70	,	,	PUNCT
eurjchem-952	73	71	250	250	NUM
eurjchem-952	73	72	(	(	PUNCT
eurjchem-952	73	73	νm‐cl	νm‐cl	NOUN
eurjchem-952	73	74	)	)	PUNCT
eurjchem-952	73	75	.	.	PUNCT
eurjchem-952	74	1	anal	anal	PROPN
eurjchem-952	74	2	.	.	PUNCT
eurjchem-952	74	3	calcd	calcd	NOUN
eurjchem-952	74	4	.	.	PUNCT
eurjchem-952	75	1	for	for	ADP
eurjchem-952	75	2	c23h19n8scucl	c23h19n8scucl	NOUN
eurjchem-952	75	3	:	:	PUNCT
eurjchem-952	76	1	c	c	X
eurjchem-952	76	2	,	,	PUNCT
eurjchem-952	76	3	51.30	51.30	NUM
eurjchem-952	76	4	;	;	PUNCT
eurjchem-952	76	5	h	h	NOUN
eurjchem-952	76	6	,	,	PUNCT
eurjchem-952	76	7	3.56	3.56	NUM
eurjchem-952	76	8	;	;	PUNCT
eurjchem-952	76	9	n	n	CCONJ
eurjchem-952	76	10	,	,	PUNCT
eurjchem-952	76	11	20.81	20.81	NUM
eurjchem-952	76	12	.	.	PUNCT
eurjchem-952	76	13	found	find	VERB
eurjchem-952	76	14	:	:	PUNCT
eurjchem-952	77	1	c	c	X
eurjchem-952	77	2	,	,	PUNCT
eurjchem-952	77	3	51.21	51.21	NUM
eurjchem-952	77	4	;	;	PUNCT
eurjchem-952	77	5	h	h	NOUN
eurjchem-952	77	6	,	,	PUNCT
eurjchem-952	77	7	3.46	3.46	NUM
eurjchem-952	77	8	;	;	PUNCT
eurjchem-952	77	9	n	n	CCONJ
eurjchem-952	77	10	,	,	PUNCT
eurjchem-952	77	11	20.70	20.70	NUM
eurjchem-952	77	12	%	%	NOUN
eurjchem-952	77	13	.	.	PUNCT
eurjchem-952	78	1	[	[	X
eurjchem-952	78	2	ni(mpapt)(1,10‐phen)(cl	ni(mpapt)(1,10‐phen)(cl	X
eurjchem-952	78	3	)	)	PUNCT
eurjchem-952	78	4	]	]	X
eurjchem-952	78	5	complex	complex	ADJ
eurjchem-952	78	6	(	(	PUNCT
eurjchem-952	78	7	2	2	NUM
eurjchem-952	78	8	):	):	PUNCT
eurjchem-952	78	9	yield	yield	NOUN
eurjchem-952	78	10	:	:	PUNCT
eurjchem-952	78	11	73	73	NUM
eurjchem-952	78	12	%	%	NOUN
eurjchem-952	78	13	.	.	PUNCT
eurjchem-952	79	1	ft‐ir	ft‐ir	NOUN
eurjchem-952	79	2	(	(	PUNCT
eurjchem-952	79	3	kbr	kbr	PROPN
eurjchem-952	79	4	,	,	PUNCT
eurjchem-952	79	5	ν	ν	PROPN
eurjchem-952	79	6	,	,	PUNCT
eurjchem-952	79	7	cm‐1	cm‐1	PROPN
eurjchem-952	79	8	):	):	PUNCT
eurjchem-952	79	9	3215	3215	NUM
eurjchem-952	79	10	(	(	PUNCT
eurjchem-952	79	11	νn1h	νn1h	NOUN
eurjchem-952	79	12	)	)	PUNCT
eurjchem-952	79	13	,	,	PUNCT
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eurjchem-952	79	15	(	(	PUNCT
eurjchem-952	79	16	νc	νc	NOUN
eurjchem-952	79	17	=	=	NOUN
eurjchem-952	79	18	nazomethine	nazomethine	NOUN
eurjchem-952	79	19	)	)	PUNCT
eurjchem-952	79	20	,	,	PUNCT
eurjchem-952	79	21	1581	1581	NUM
eurjchem-952	79	22	(	(	PUNCT
eurjchem-952	79	23	νn	νn	NOUN
eurjchem-952	79	24	=	=	SYM
eurjchem-952	79	25	c	c	NOUN
eurjchem-952	79	26	)	)	PUNCT
eurjchem-952	79	27	,	,	PUNCT
eurjchem-952	79	28	1527	1527	NUM
eurjchem-952	79	29	(	(	PUNCT
eurjchem-952	79	30	νc	νc	NOUN
eurjchem-952	79	31	=	=	NOUN
eurjchem-952	79	32	npyridine	npyridine	NOUN
eurjchem-952	79	33	)	)	PUNCT
eurjchem-952	79	34	,	,	PUNCT
eurjchem-952	79	35	1270	1270	NUM
eurjchem-952	79	36	,	,	PUNCT
eurjchem-952	79	37	810	810	NUM
eurjchem-952	79	38	(	(	PUNCT
eurjchem-952	79	39	νc	νc	X
eurjchem-952	79	40	=	=	SYM
eurjchem-952	79	41	s	s	NOUN
eurjchem-952	79	42	)	)	PUNCT
eurjchem-952	79	43	,	,	PUNCT
eurjchem-952	79	44	1070	1070	NUM
eurjchem-952	79	45	(	(	PUNCT
eurjchem-952	79	46	νn‐n	νn‐n	NUM
eurjchem-952	79	47	)	)	PUNCT
eurjchem-952	79	48	,	,	PUNCT
eurjchem-952	79	49	612	612	NUM
eurjchem-952	79	50	(	(	PUNCT
eurjchem-952	79	51	δc	δc	NOUN
eurjchem-952	79	52	=	=	NOUN
eurjchem-952	79	53	npyridine	npyridine	NOUN
eurjchem-952	79	54	)	)	PUNCT
eurjchem-952	79	55	,	,	PUNCT
eurjchem-952	79	56	448	448	NUM
eurjchem-952	79	57	(	(	PUNCT
eurjchem-952	79	58	νm‐n	νm‐n	NUM
eurjchem-952	79	59	)	)	PUNCT
eurjchem-952	79	60	,	,	PUNCT
eurjchem-952	79	61	340	340	NUM
eurjchem-952	79	62	(	(	PUNCT
eurjchem-952	79	63	νm‐s	νm‐s	PROPN
eurjchem-952	79	64	)	)	PUNCT
eurjchem-952	79	65	,	,	PUNCT
eurjchem-952	79	66	283	283	NUM
eurjchem-952	79	67	(	(	PUNCT
eurjchem-952	79	68	νm‐npy	νm‐npy	PROPN
eurjchem-952	79	69	)	)	PUNCT
eurjchem-952	79	70	,	,	PUNCT
eurjchem-952	79	71	248	248	NUM
eurjchem-952	79	72	(	(	PUNCT
eurjchem-952	79	73	νm‐cl	νm‐cl	NOUN
eurjchem-952	79	74	)	)	PUNCT
eurjchem-952	79	75	.	.	PUNCT
eurjchem-952	80	1	anal	anal	PROPN
eurjchem-952	80	2	.	.	PUNCT
eurjchem-952	80	3	calcd	calcd	NOUN
eurjchem-952	80	4	.	.	PUNCT
eurjchem-952	81	1	for	for	ADP
eurjchem-952	81	2	c23h19n8snicl	c23h19n8snicl	NOUN
eurjchem-952	81	3	:	:	PUNCT
eurjchem-952	81	4	c	c	X
eurjchem-952	81	5	,	,	PUNCT
eurjchem-952	81	6	51.76	51.76	NUM
eurjchem-952	81	7	;	;	PUNCT
eurjchem-952	81	8	h	h	NOUN
eurjchem-952	81	9	,	,	PUNCT
eurjchem-952	81	10	3.59	3.59	NUM
eurjchem-952	81	11	;	;	PUNCT
eurjchem-952	81	12	n	n	CCONJ
eurjchem-952	81	13	,	,	PUNCT
eurjchem-952	81	14	21.00	21.00	NUM
eurjchem-952	81	15	.	.	PUNCT
eurjchem-952	81	16	found	find	VERB
eurjchem-952	81	17	:	:	PUNCT
eurjchem-952	82	1	c	c	X
eurjchem-952	82	2	,	,	PUNCT
eurjchem-952	82	3	51.71	51.71	NUM
eurjchem-952	82	4	;	;	PUNCT
eurjchem-952	82	5	h	h	NOUN
eurjchem-952	82	6	,	,	PUNCT
eurjchem-952	82	7	3.46	3.46	NUM
eurjchem-952	82	8	;	;	PUNCT
eurjchem-952	82	9	n	n	CCONJ
eurjchem-952	82	10	,	,	PUNCT
eurjchem-952	82	11	21.01	21.01	NUM
eurjchem-952	82	12	%	%	NOUN
eurjchem-952	82	13	.	.	PUNCT
eurjchem-952	83	1	[	[	X
eurjchem-952	83	2	co(mpapt)(1,10‐phen)(cl)].h2o	co(mpapt)(1,10‐phen)(cl)].h2o	NOUN
eurjchem-952	83	3	complex	complex	NOUN
eurjchem-952	83	4	(	(	PUNCT
eurjchem-952	83	5	3	3	NUM
eurjchem-952	83	6	):	):	PUNCT
eurjchem-952	83	7	yield	yield	NOUN
eurjchem-952	83	8	:	:	PUNCT
eurjchem-952	83	9	70	70	NUM
eurjchem-952	83	10	%	%	NOUN
eurjchem-952	83	11	.	.	PUNCT
eurjchem-952	84	1	ft‐ir	ft‐ir	NOUN
eurjchem-952	84	2	(	(	PUNCT
eurjchem-952	84	3	kbr	kbr	PROPN
eurjchem-952	84	4	,	,	PUNCT
eurjchem-952	84	5	ν	ν	PROPN
eurjchem-952	84	6	,	,	PUNCT
eurjchem-952	84	7	cm‐1	cm‐1	PROPN
eurjchem-952	84	8	):	):	PUNCT
eurjchem-952	84	9	3220	3220	NUM
eurjchem-952	84	10	(	(	PUNCT
eurjchem-952	84	11	νn1h	νn1h	PROPN
eurjchem-952	84	12	)	)	PUNCT
eurjchem-952	84	13	,	,	PUNCT
eurjchem-952	84	14	1601	1601	NUM
eurjchem-952	84	15	(	(	PUNCT
eurjchem-952	84	16	νc	νc	NOUN
eurjchem-952	84	17	=	=	NOUN
eurjchem-952	84	18	nazomethine	nazomethine	NOUN
eurjchem-952	84	19	)	)	PUNCT
eurjchem-952	84	20	,	,	PUNCT
eurjchem-952	84	21	1580	1580	NUM
eurjchem-952	84	22	(	(	PUNCT
eurjchem-952	84	23	νn	νn	NOUN
eurjchem-952	84	24	=	=	SYM
eurjchem-952	84	25	c	c	NOUN
eurjchem-952	84	26	)	)	PUNCT
eurjchem-952	84	27	,	,	PUNCT
eurjchem-952	84	28	1530	1530	NUM
eurjchem-952	84	29	(	(	PUNCT
eurjchem-952	84	30	νc	νc	NOUN
eurjchem-952	84	31	=	=	NOUN
eurjchem-952	84	32	npyridine	npyridine	NOUN
eurjchem-952	84	33	)	)	PUNCT
eurjchem-952	84	34	,	,	PUNCT
eurjchem-952	84	35	1268	1268	NUM
eurjchem-952	84	36	,	,	PUNCT
eurjchem-952	84	37	805	805	NUM
eurjchem-952	84	38	(	(	PUNCT
eurjchem-952	84	39	νc	νc	X
eurjchem-952	84	40	=	=	SYM
eurjchem-952	84	41	s	s	NOUN
eurjchem-952	84	42	)	)	PUNCT
eurjchem-952	84	43	,	,	PUNCT
eurjchem-952	84	44	1082	1082	NUM
eurjchem-952	84	45	(	(	PUNCT
eurjchem-952	84	46	νn‐n	νn‐n	NUM
eurjchem-952	84	47	)	)	PUNCT
eurjchem-952	84	48	,	,	PUNCT
eurjchem-952	84	49	613	613	NUM
eurjchem-952	84	50	(	(	PUNCT
eurjchem-952	84	51	δc	δc	NOUN
eurjchem-952	84	52	=	=	NOUN
eurjchem-952	84	53	npyridine	npyridine	NOUN
eurjchem-952	84	54	)	)	PUNCT
eurjchem-952	84	55	,	,	PUNCT
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eurjchem-952	84	57	(	(	PUNCT
eurjchem-952	84	58	νm‐n	νm‐n	NUM
eurjchem-952	84	59	)	)	PUNCT
eurjchem-952	84	60	,	,	PUNCT
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eurjchem-952	84	62	(	(	PUNCT
eurjchem-952	84	63	νm‐s	νm‐s	PROPN
eurjchem-952	84	64	)	)	PUNCT
eurjchem-952	84	65	,	,	PUNCT
eurjchem-952	84	66	287	287	NUM
eurjchem-952	84	67	(	(	PUNCT
eurjchem-952	84	68	νm‐npy	νm‐npy	PROPN
eurjchem-952	84	69	)	)	PUNCT
eurjchem-952	84	70	,	,	PUNCT
eurjchem-952	84	71	255(νm‐cl	255(νm‐cl	NUM
eurjchem-952	84	72	)	)	PUNCT
eurjchem-952	84	73	.	.	PUNCT
eurjchem-952	85	1	anal	anal	PROPN
eurjchem-952	85	2	.	.	PUNCT
eurjchem-952	85	3	calcd	calcd	NOUN
eurjchem-952	85	4	.	.	PUNCT
eurjchem-952	86	1	for	for	ADP
eurjchem-952	86	2	c23h19n8scocl.h2o	c23h19n8scocl.h2o	NOUN
eurjchem-952	86	3	:	:	PUNCT
eurjchem-952	86	4	c	c	X
eurjchem-952	86	5	,	,	PUNCT
eurjchem-952	86	6	50.05	50.05	NUM
eurjchem-952	86	7	;	;	PUNCT
eurjchem-952	87	1	h	h	NOUN
eurjchem-952	87	2	,	,	PUNCT
eurjchem-952	87	3	3.84	3.84	NUM
eurjchem-952	87	4	;	;	PUNCT
eurjchem-952	87	5	n	n	CCONJ
eurjchem-952	87	6	,	,	PUNCT
eurjchem-952	87	7	20.31	20.31	NUM
eurjchem-952	87	8	.	.	PUNCT
eurjchem-952	87	9	found	find	VERB
eurjchem-952	87	10	:	:	PUNCT
eurjchem-952	88	1	c	c	X
eurjchem-952	88	2	,	,	PUNCT
eurjchem-952	88	3	50.01	50.01	NUM
eurjchem-952	88	4	;	;	PUNCT
eurjchem-952	88	5	h	h	NOUN
eurjchem-952	88	6	,	,	PUNCT
eurjchem-952	88	7	3.76	3.76	NUM
eurjchem-952	88	8	;	;	PUNCT
eurjchem-952	88	9	n	n	CCONJ
eurjchem-952	88	10	,	,	PUNCT
eurjchem-952	88	11	20.27	20.27	NUM
eurjchem-952	88	12	%	%	NOUN
eurjchem-952	88	13	.	.	PUNCT
eurjchem-952	89	1	[	[	X
eurjchem-952	89	2	mn(mpapt)(1,10‐phen)(cl)].h2o	mn(mpapt)(1,10‐phen)(cl)].h2o	NOUN
eurjchem-952	89	3	complex	complex	NOUN
eurjchem-952	89	4	(	(	PUNCT
eurjchem-952	89	5	4	4	NUM
eurjchem-952	89	6	):	):	PUNCT
eurjchem-952	89	7	yield	yield	NOUN
eurjchem-952	89	8	:	:	PUNCT
eurjchem-952	89	9	77	77	NUM
eurjchem-952	89	10	%	%	NOUN
eurjchem-952	89	11	.	.	PUNCT
eurjchem-952	90	1	ft‐ir	ft‐ir	NOUN
eurjchem-952	90	2	(	(	PUNCT
eurjchem-952	90	3	kbr	kbr	PROPN
eurjchem-952	90	4	,	,	PUNCT
eurjchem-952	90	5	ν	ν	PROPN
eurjchem-952	90	6	,	,	PUNCT
eurjchem-952	90	7	cm‐1	cm‐1	PROPN
eurjchem-952	90	8	):	):	PUNCT
eurjchem-952	90	9	3222	3222	NUM
eurjchem-952	90	10	(	(	PUNCT
eurjchem-952	90	11	νn1h	νn1h	PROPN
eurjchem-952	90	12	)	)	PUNCT
eurjchem-952	90	13	,	,	PUNCT
eurjchem-952	90	14	1610	1610	NUM
eurjchem-952	90	15	(	(	PUNCT
eurjchem-952	90	16	νc	νc	NOUN
eurjchem-952	90	17	=	=	NOUN
eurjchem-952	90	18	nazomethine	nazomethine	NOUN
eurjchem-952	90	19	)	)	PUNCT
eurjchem-952	90	20	,	,	PUNCT
eurjchem-952	90	21	1575	1575	NUM
eurjchem-952	90	22	(	(	PUNCT
eurjchem-952	90	23	νn	νn	PROPN
eurjchem-952	90	24	=	=	SYM
eurjchem-952	90	25	c	c	NOUN
eurjchem-952	90	26	)	)	PUNCT
eurjchem-952	90	27	,	,	PUNCT
eurjchem-952	90	28	1529	1529	NUM
eurjchem-952	90	29	(	(	PUNCT
eurjchem-952	90	30	νc	νc	NOUN
eurjchem-952	90	31	=	=	NOUN
eurjchem-952	90	32	npyridine	npyridine	NOUN
eurjchem-952	90	33	)	)	PUNCT
eurjchem-952	90	34	,	,	PUNCT
eurjchem-952	90	35	1271	1271	NUM
eurjchem-952	90	36	,	,	PUNCT
eurjchem-952	90	37	811	811	NUM
eurjchem-952	90	38	(	(	PUNCT
eurjchem-952	90	39	νc	νc	X
eurjchem-952	90	40	=	=	SYM
eurjchem-952	90	41	s	s	NOUN
eurjchem-952	90	42	)	)	PUNCT
eurjchem-952	90	43	,	,	PUNCT
eurjchem-952	90	44	1080	1080	NUM
eurjchem-952	90	45	(	(	PUNCT
eurjchem-952	90	46	νn‐n	νn‐n	NUM
eurjchem-952	90	47	)	)	PUNCT
eurjchem-952	90	48	,	,	PUNCT
eurjchem-952	90	49	611	611	NUM
eurjchem-952	90	50	(	(	PUNCT
eurjchem-952	90	51	δc	δc	NOUN
eurjchem-952	90	52	=	=	NOUN
eurjchem-952	90	53	npyridine	npyridine	NOUN
eurjchem-952	90	54	)	)	PUNCT
eurjchem-952	90	55	,	,	PUNCT
eurjchem-952	90	56	448	448	NUM
eurjchem-952	90	57	(	(	PUNCT
eurjchem-952	90	58	νm‐n	νm‐n	NUM
eurjchem-952	90	59	)	)	PUNCT
eurjchem-952	90	60	,	,	PUNCT
eurjchem-952	90	61	345	345	NUM
eurjchem-952	90	62	(	(	PUNCT
eurjchem-952	90	63	νm‐s	νm‐s	PROPN
eurjchem-952	90	64	)	)	PUNCT
eurjchem-952	90	65	,	,	PUNCT
eurjchem-952	90	66	290	290	NUM
eurjchem-952	90	67	(	(	PUNCT
eurjchem-952	90	68	νm‐npy	νm‐npy	PROPN
eurjchem-952	90	69	)	)	PUNCT
eurjchem-952	90	70	,	,	PUNCT
eurjchem-952	90	71	263	263	NUM
eurjchem-952	90	72	(	(	PUNCT
eurjchem-952	90	73	νm‐cl	νm‐cl	NOUN
eurjchem-952	90	74	)	)	PUNCT
eurjchem-952	90	75	.	.	PUNCT
eurjchem-952	91	1	anal	anal	PROPN
eurjchem-952	91	2	.	.	PUNCT
eurjchem-952	91	3	calcd	calcd	NOUN
eurjchem-952	91	4	.	.	PUNCT
eurjchem-952	92	1	for	for	ADP
eurjchem-952	92	2	c23h19n8smncl.h2o	c23h19n8smncl.h2o	NOUN
eurjchem-952	92	3	:	:	PUNCT
eurjchem-952	92	4	c	c	NOUN
eurjchem-952	92	5	,	,	PUNCT
eurjchem-952	92	6	50.42	50.42	NUM
eurjchem-952	92	7	;	;	PUNCT
eurjchem-952	92	8	h	h	NOUN
eurjchem-952	92	9	,	,	PUNCT
eurjchem-952	92	10	3.86	3.86	NUM
eurjchem-952	92	11	;	;	PUNCT
eurjchem-952	92	12	n	n	CCONJ
eurjchem-952	92	13	,	,	PUNCT
eurjchem-952	92	14	20.45	20.45	NUM
eurjchem-952	92	15	.	.	PUNCT
eurjchem-952	93	1	found	find	VERB
eurjchem-952	93	2	:	:	PUNCT
eurjchem-952	94	1	c	c	X
eurjchem-952	94	2	,	,	PUNCT
eurjchem-952	94	3	50.38	50.38	NUM
eurjchem-952	94	4	;	;	PUNCT
eurjchem-952	95	1	h	h	NOUN
eurjchem-952	95	2	,	,	PUNCT
eurjchem-952	95	3	3.43	3.43	NUM
eurjchem-952	95	4	;	;	PUNCT
eurjchem-952	95	5	n	n	CCONJ
eurjchem-952	95	6	,	,	PUNCT
eurjchem-952	95	7	20.38	20.38	NUM
eurjchem-952	95	8	%	%	NOUN
eurjchem-952	95	9	.	.	PUNCT
eurjchem-952	96	1	2.3	2.3	NUM
eurjchem-952	96	2	.	.	PUNCT
eurjchem-952	97	1	molecular	molecular	ADJ
eurjchem-952	97	2	modeling	model	VERB
eurjchem-952	97	3	an	an	DET
eurjchem-952	97	4	attempt	attempt	NOUN
eurjchem-952	97	5	to	to	PART
eurjchem-952	97	6	gain	gain	VERB
eurjchem-952	97	7	a	a	DET
eurjchem-952	97	8	better	well	ADJ
eurjchem-952	97	9	insight	insight	NOUN
eurjchem-952	97	10	on	on	ADP
eurjchem-952	97	11	the	the	DET
eurjchem-952	97	12	molecular	molecular	ADJ
eurjchem-952	97	13	structure	structure	NOUN
eurjchem-952	97	14	of	of	ADP
eurjchem-952	97	15	these	these	DET
eurjchem-952	97	16	synthesized	synthesize	VERB
eurjchem-952	97	17	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-952	97	18	compounds	compound	NOUN
eurjchem-952	97	19	and	and	CCONJ
eurjchem-952	97	20	their	their	PRON
eurjchem-952	97	21	m(ii)‐complexes	m(ii)‐complexe	NOUN
eurjchem-952	97	22	,	,	PUNCT
eurjchem-952	97	23	geometric	geometric	ADJ
eurjchem-952	97	24	optimization	optimization	NOUN
eurjchem-952	97	25	and	and	CCONJ
eurjchem-952	97	26	conformation	conformation	NOUN
eurjchem-952	97	27	analysis	analysis	NOUN
eurjchem-952	97	28	has	have	AUX
eurjchem-952	97	29	performed	perform	VERB
eurjchem-952	97	30	using	use	VERB
eurjchem-952	97	31	semiempirical	semiempirical	ADJ
eurjchem-952	97	32	parameterized	parameterized	ADJ
eurjchem-952	97	33	pm3	pm3	PROPN
eurjchem-952	97	34	method	method	NOUN
eurjchem-952	97	35	as	as	SCONJ
eurjchem-952	97	36	implemented	implement	VERB
eurjchem-952	97	37	in	in	ADP
eurjchem-952	97	38	hyperchem	hyperchem	NOUN
eurjchem-952	97	39	7.5	7.5	NUM
eurjchem-952	98	1	[	[	X
eurjchem-952	98	2	25	25	NUM
eurjchem-952	98	3	]	]	PUNCT
eurjchem-952	98	4	.	.	PUNCT
eurjchem-952	99	1	convergence	convergence	NOUN
eurjchem-952	99	2	criteria	criterion	NOUN
eurjchem-952	99	3	were	be	AUX
eurjchem-952	99	4	set	set	VERB
eurjchem-952	99	5	to	to	ADP
eurjchem-952	99	6	0.01	0.01	NUM
eurjchem-952	99	7	kcal	kcal	NOUN
eurjchem-952	99	8	/	/	SYM
eurjchem-952	99	9	mol.å	mol.å	PROPN
eurjchem-952	99	10	for	for	ADP
eurjchem-952	99	11	pm3	pm3	PROPN
eurjchem-952	99	12	calculations	calculation	NOUN
eurjchem-952	99	13	.	.	PUNCT
eurjchem-952	100	1	2.4	2.4	NUM
eurjchem-952	100	2	.	.	PUNCT
eurjchem-952	100	3	biological	biological	ADJ
eurjchem-952	100	4	activity	activity	NOUN
eurjchem-952	100	5	2.4.1	2.4.1	NUM
eurjchem-952	100	6	.	.	PUNCT
eurjchem-952	101	1	antibacterial	antibacterial	ADJ
eurjchem-952	101	2	and	and	CCONJ
eurjchem-952	101	3	antifungal	antifungal	ADJ
eurjchem-952	101	4	activities	activity	NOUN
eurjchem-952	101	5	the	the	DET
eurjchem-952	101	6	antibacterial	antibacterial	ADJ
eurjchem-952	101	7	investigation	investigation	NOUN
eurjchem-952	101	8	of	of	ADP
eurjchem-952	101	9	the	the	DET
eurjchem-952	101	10	free	free	ADJ
eurjchem-952	101	11	(	(	PUNCT
eurjchem-952	101	12	mpapt	mpapt	ADJ
eurjchem-952	101	13	)	)	PUNCT
eurjchem-952	101	14	ligand	ligand	NOUN
eurjchem-952	101	15	or	or	CCONJ
eurjchem-952	101	16	its	its	PRON
eurjchem-952	101	17	mn(ii	mn(ii	NOUN
eurjchem-952	101	18	)	)	PUNCT
eurjchem-952	101	19	,	,	PUNCT
eurjchem-952	101	20	co(ii	co(ii	PROPN
eurjchem-952	101	21	)	)	PUNCT
eurjchem-952	101	22	,	,	PUNCT
eurjchem-952	101	23	cu(ii	cu(ii	PROPN
eurjchem-952	101	24	)	)	PUNCT
eurjchem-952	101	25	and	and	CCONJ
eurjchem-952	101	26	ni(ii	ni(ii	ADJ
eurjchem-952	101	27	)	)	PUNCT
eurjchem-952	101	28	complexes	complex	NOUN
eurjchem-952	101	29	was	be	AUX
eurjchem-952	101	30	carried	carry	VERB
eurjchem-952	101	31	out	out	ADP
eurjchem-952	101	32	using	use	VERB
eurjchem-952	101	33	a	a	DET
eurjchem-952	101	34	modified	modify	VERB
eurjchem-952	101	35	kirby‐bauer	kirby‐bauer	NOUN
eurjchem-952	101	36	disc	disc	NOUN
eurjchem-952	101	37	diffusion	diffusion	NOUN
eurjchem-952	101	38	method	method	NOUN
eurjchem-952	101	39	[	[	X
eurjchem-952	101	40	26	26	NUM
eurjchem-952	101	41	]	]	PUNCT
eurjchem-952	101	42	.	.	PUNCT
eurjchem-952	102	1	the	the	DET
eurjchem-952	102	2	test	test	NOUN
eurjchem-952	102	3	was	be	AUX
eurjchem-952	102	4	done	do	VERB
eurjchem-952	102	5	against	against	ADP
eurjchem-952	102	6	filamentous	filamentous	ADJ
eurjchem-952	102	7	fungi	fungus	NOUN
eurjchem-952	102	8	as	as	ADP
eurjchem-952	102	9	(	(	PUNCT
eurjchem-952	102	10	aspergillus	aspergillus	NOUN
eurjchem-952	102	11	flavus	flavus	NOUN
eurjchem-952	102	12	(	(	PUNCT
eurjchem-952	102	13	rcmb	rcmb	NOUN
eurjchem-952	102	14	02568	02568	NUM
eurjchem-952	102	15	)	)	PUNCT
eurjchem-952	102	16	,	,	PUNCT
eurjchem-952	102	17	pencicillium	pencicillium	NOUN
eurjchem-952	102	18	italicum	italicum	PROPN
eurjchem-952	102	19	(	(	PUNCT
eurjchem-952	102	20	rcmb	rcmb	NOUN
eurjchem-952	102	21	03924	03924	NUM
eurjchem-952	102	22	)	)	PUNCT
eurjchem-952	102	23	,	,	PUNCT
eurjchem-952	102	24	and	and	CCONJ
eurjchem-952	102	25	aspergillus	aspergillus	NOUN
eurjchem-952	102	26	flavus	flavus	NOUN
eurjchem-952	102	27	(	(	PUNCT
eurjchem-952	102	28	rcmb	rcmb	NOUN
eurjchem-952	102	29	02568	02568	NUM
eurjchem-952	102	30	)	)	PUNCT
eurjchem-952	102	31	)	)	PUNCT
eurjchem-952	102	32	at	at	ADP
eurjchem-952	102	33	30	30	NUM
eurjchem-952	102	34	°	°	ADP
eurjchem-952	102	35	c	c	NOUN
eurjchem-952	102	36	for	for	ADP
eurjchem-952	102	37	24‐48	24‐48	NUM
eurjchem-952	102	38	hours	hour	NOUN
eurjchem-952	102	39	;	;	PUNCT
eurjchem-952	102	40	gram	gram	NOUN
eurjchem-952	102	41	(	(	PUNCT
eurjchem-952	102	42	+	+	NOUN
eurjchem-952	102	43	)	)	PUNCT
eurjchem-952	102	44	bacteria	bacteria	NOUN
eurjchem-952	102	45	as	as	SCONJ
eurjchem-952	102	46	(	(	PUNCT
eurjchem-952	102	47	bacillus	bacillus	NOUN
eurjchem-952	102	48	subtillis	subtilli	VERB
eurjchem-952	102	49	rcmb	rcmb	NOUN
eurjchem-952	102	50	010067	010067	NUM
eurjchem-952	102	51	and	and	CCONJ
eurjchem-952	102	52	staphylococcus	staphylococcus	NOUN
eurjchem-952	102	53	aureus	aureus	PROPN
eurjchem-952	102	54	rcmb	rcmb	PROPN
eurjchem-952	102	55	010028	010028	NUM
eurjchem-952	102	56	)	)	PUNCT
eurjchem-952	102	57	;	;	PUNCT
eurjchem-952	102	58	gram	gram	NOUN
eurjchem-952	102	59	(	(	PUNCT
eurjchem-952	102	60	‐	‐	NOUN
eurjchem-952	102	61	)	)	PUNCT
eurjchem-952	102	62	bacteria	bacteria	NOUN
eurjchem-952	102	63	as	as	ADP
eurjchem-952	102	64	(	(	PUNCT
eurjchem-952	102	65	pseudomonas	pseudomona	NOUN
eurjchem-952	102	66	aeuroginosa	aeuroginosa	NOUN
eurjchem-952	102	67	(	(	PUNCT
eurjchem-952	102	68	rcmb	rcmb	NOUN
eurjchem-952	102	69	010043	010043	NUM
eurjchem-952	102	70	)	)	PUNCT
eurjchem-952	102	71	,	,	PUNCT
eurjchem-952	102	72	and	and	CCONJ
eurjchem-952	102	73	escherichia	escherichia	NOUN
eurjchem-952	102	74	coli	coli	NOUN
eurjchem-952	102	75	(	(	PUNCT
eurjchem-952	102	76	rcmb	rcmb	NOUN
eurjchem-952	102	77	010052	010052	NUM
eurjchem-952	102	78	)	)	PUNCT
eurjchem-952	102	79	)	)	PUNCT
eurjchem-952	102	80	.	.	PUNCT
eurjchem-952	103	1	the	the	DET
eurjchem-952	103	2	standard	standard	ADJ
eurjchem-952	103	3	antibacterial	antibacterial	ADJ
eurjchem-952	103	4	agents	agent	NOUN
eurjchem-952	103	5	used	use	VERB
eurjchem-952	103	6	are	be	AUX
eurjchem-952	103	7	gentamicin	gentamicin	VERB
eurjchem-952	103	8	for	for	ADP
eurjchem-952	103	9	gram‐	gram‐	PROPN
eurjchem-952	103	10	,	,	PUNCT
eurjchem-952	103	11	ampicillin	ampicillin	PROPN
eurjchem-952	103	12	for	for	ADP
eurjchem-952	103	13	gram+	gram+	PROPN
eurjchem-952	103	14	and	and	CCONJ
eurjchem-952	103	15	amphotericin	amphotericin	ADP
eurjchem-952	103	16	b	b	X
eurjchem-952	103	17	(	(	PUNCT
eurjchem-952	103	18	antifungal	antifungal	ADJ
eurjchem-952	103	19	agent	agent	NOUN
eurjchem-952	103	20	)	)	PUNCT
eurjchem-952	103	21	served	serve	VERB
eurjchem-952	103	22	as	as	ADP
eurjchem-952	103	23	positive	positive	ADJ
eurjchem-952	103	24	controls	control	NOUN
eurjchem-952	103	25	while	while	SCONJ
eurjchem-952	103	26	dmso	dmso	NOUN
eurjchem-952	103	27	,	,	PUNCT
eurjchem-952	103	28	which	which	PRON
eurjchem-952	103	29	exhibited	exhibit	VERB
eurjchem-952	103	30	no	no	DET
eurjchem-952	103	31	antimicrobial	antimicrobial	ADJ
eurjchem-952	103	32	activity	activity	NOUN
eurjchem-952	103	33	,	,	PUNCT
eurjchem-952	103	34	was	be	AUX
eurjchem-952	103	35	used	use	VERB
eurjchem-952	103	36	as	as	ADP
eurjchem-952	103	37	a	a	DET
eurjchem-952	103	38	negative	negative	ADJ
eurjchem-952	103	39	control	control	NOUN
eurjchem-952	103	40	.	.	PUNCT
eurjchem-952	104	1	the	the	DET
eurjchem-952	104	2	agar	agar	NOUN
eurjchem-952	104	3	used	use	VERB
eurjchem-952	104	4	is	be	AUX
eurjchem-952	104	5	mueller‐hinton	mueller‐hinton	NOUN
eurjchem-952	104	6	agar	agar	NOUN
eurjchem-952	104	7	that	that	PRON
eurjchem-952	104	8	is	be	AUX
eurjchem-952	104	9	rigorously	rigorously	ADV
eurjchem-952	104	10	tested	test	VERB
eurjchem-952	104	11	for	for	ADP
eurjchem-952	104	12	composition	composition	NOUN
eurjchem-952	104	13	and	and	CCONJ
eurjchem-952	104	14	ph	ph	NOUN
eurjchem-952	104	15	.	.	PROPN
eurjchem-952	104	16	plates	plate	NOUN
eurjchem-952	104	17	were	be	AUX
eurjchem-952	104	18	incubated	incubate	VERB
eurjchem-952	104	19	with	with	ADP
eurjchem-952	104	20	filamentous	filamentous	ADJ
eurjchem-952	104	21	fungi	fungus	NOUN
eurjchem-952	104	22	at	at	ADP
eurjchem-952	104	23	30	30	NUM
eurjchem-952	104	24	°	°	ADP
eurjchem-952	104	25	c	c	NOUN
eurjchem-952	104	26	for	for	ADP
eurjchem-952	104	27	24‐48	24‐48	NUM
eurjchem-952	104	28	hours	hour	NOUN
eurjchem-952	104	29	and	and	CCONJ
eurjchem-952	104	30	with	with	ADP
eurjchem-952	104	31	bacteria	bacteria	NOUN
eurjchem-952	104	32	at	at	ADP
eurjchem-952	104	33	35‐37	35‐37	NUM
eurjchem-952	104	34	°	°	ADP
eurjchem-952	104	35	c	c	NOUN
eurjchem-952	104	36	for	for	ADP
eurjchem-952	104	37	24‐48	24‐48	NUM
eurjchem-952	104	38	hours	hour	NOUN
eurjchem-952	104	39	[	[	X
eurjchem-952	104	40	27	27	NUM
eurjchem-952	104	41	]	]	PUNCT
eurjchem-952	104	42	and	and	CCONJ
eurjchem-952	104	43	then	then	ADV
eurjchem-952	104	44	the	the	DET
eurjchem-952	104	45	diameters	diameter	NOUN
eurjchem-952	104	46	of	of	ADP
eurjchem-952	104	47	inhibition	inhibition	NOUN
eurjchem-952	104	48	zones	zone	NOUN
eurjchem-952	104	49	were	be	AUX
eurjchem-952	104	50	measured	measure	VERB
eurjchem-952	104	51	in	in	ADP
eurjchem-952	104	52	millimeters	millimeter	NOUN
eurjchem-952	104	53	using	use	VERB
eurjchem-952	104	54	slipping	slip	VERB
eurjchem-952	104	55	calipers	caliper	NOUN
eurjchem-952	104	56	of	of	ADP
eurjchem-952	104	57	the	the	DET
eurjchem-952	104	58	national	national	PROPN
eurjchem-952	104	59	committee	committee	PROPN
eurjchem-952	104	60	for	for	ADP
eurjchem-952	104	61	clinical	clinical	ADJ
eurjchem-952	104	62	laboratory	laboratory	NOUN
eurjchem-952	104	63	standards	standard	NOUN
eurjchem-952	104	64	(	(	PUNCT
eurjchem-952	104	65	nccls	nccls	NOUN
eurjchem-952	104	66	)	)	PUNCT
eurjchem-952	105	1	[	[	X
eurjchem-952	105	2	28,29	28,29	X
eurjchem-952	105	3	]	]	PUNCT
eurjchem-952	105	4	.	.	PUNCT
eurjchem-952	106	1	2.4.2	2.4.2	X
eurjchem-952	106	2	.	.	PUNCT
eurjchem-952	107	1	in	in	ADP
eurjchem-952	107	2	vitro	vitro	X
eurjchem-952	107	3	cytotoxicity	cytotoxicity	NOUN
eurjchem-952	107	4	the	the	DET
eurjchem-952	107	5	synthesized	synthesize	VERB
eurjchem-952	107	6	m(ii	m(ii	NOUN
eurjchem-952	107	7	)	)	PUNCT
eurjchem-952	107	8	complexes	complex	NOUN
eurjchem-952	107	9	were	be	AUX
eurjchem-952	107	10	screened	screen	VERB
eurjchem-952	107	11	for	for	ADP
eurjchem-952	107	12	their	their	PRON
eurjchem-952	107	13	cytotoxicity	cytotoxicity	NOUN
eurjchem-952	107	14	against	against	ADP
eurjchem-952	107	15	colon	colon	NOUN
eurjchem-952	107	16	carcinoma	carcinoma	NOUN
eurjchem-952	107	17	(	(	PUNCT
eurjchem-952	107	18	hct116	hct116	PROPN
eurjchem-952	107	19	)	)	PUNCT
eurjchem-952	107	20	and	and	CCONJ
eurjchem-952	107	21	larynx	larynx	NOUN
eurjchem-952	107	22	carcinoma	carcinoma	NOUN
eurjchem-952	107	23	(	(	PUNCT
eurjchem-952	107	24	hep2	hep2	PROPN
eurjchem-952	107	25	)	)	PUNCT
eurjchem-952	107	26	cells	cell	NOUN
eurjchem-952	107	27	by	by	ADP
eurjchem-952	107	28	using	use	VERB
eurjchem-952	107	29	the	the	DET
eurjchem-952	107	30	protocol	protocol	NOUN
eurjchem-952	107	31	of	of	ADP
eurjchem-952	107	32	srb	srb	PROPN
eurjchem-952	107	33	assay	assay	VERB
eurjchem-952	108	1	[	[	X
eurjchem-952	108	2	30	30	NUM
eurjchem-952	108	3	]	]	PUNCT
eurjchem-952	108	4	.	.	PUNCT
eurjchem-952	109	1	cells	cell	NOUN
eurjchem-952	109	2	were	be	AUX
eurjchem-952	109	3	plated	plate	VERB
eurjchem-952	109	4	in	in	ADP
eurjchem-952	109	5	96‐multiwell	96‐multiwell	NUM
eurjchem-952	109	6	plate	plate	NOUN
eurjchem-952	109	7	(	(	PUNCT
eurjchem-952	109	8	104	104	NUM
eurjchem-952	109	9	cells	cell	NOUN
eurjchem-952	109	10	/	/	SYM
eurjchem-952	109	11	well	well	INTJ
eurjchem-952	109	12	)	)	PUNCT
eurjchem-952	109	13	for	for	ADP
eurjchem-952	109	14	24	24	NUM
eurjchem-952	109	15	h	h	NOUN
eurjchem-952	109	16	before	before	ADP
eurjchem-952	109	17	treatment	treatment	NOUN
eurjchem-952	109	18	with	with	ADP
eurjchem-952	109	19	the	the	DET
eurjchem-952	109	20	compounds	compound	NOUN
eurjchem-952	109	21	to	to	PART
eurjchem-952	109	22	allow	allow	VERB
eurjchem-952	109	23	attachment	attachment	NOUN
eurjchem-952	109	24	of	of	ADP
eurjchem-952	109	25	cells	cell	NOUN
eurjchem-952	109	26	to	to	ADP
eurjchem-952	109	27	the	the	DET
eurjchem-952	109	28	wall	wall	NOUN
eurjchem-952	109	29	of	of	ADP
eurjchem-952	109	30	plate	plate	NOUN
eurjchem-952	109	31	.	.	PUNCT
eurjchem-952	110	1	different	different	ADJ
eurjchem-952	110	2	concentrations	concentration	NOUN
eurjchem-952	110	3	of	of	ADP
eurjchem-952	110	4	the	the	DET
eurjchem-952	110	5	test	test	NOUN
eurjchem-952	110	6	chemical	chemical	NOUN
eurjchem-952	110	7	compound	compound	NOUN
eurjchem-952	110	8	were	be	AUX
eurjchem-952	110	9	added	add	VERB
eurjchem-952	110	10	to	to	ADP
eurjchem-952	110	11	the	the	DET
eurjchem-952	110	12	cell	cell	NOUN
eurjchem-952	110	13	monolayer	monolayer	NOUN
eurjchem-952	110	14	.	.	PUNCT
eurjchem-952	111	1	triplicate	triplicate	VERB
eurjchem-952	111	2	wells	well	NOUN
eurjchem-952	111	3	were	be	AUX
eurjchem-952	111	4	prepared	prepare	VERB
eurjchem-952	111	5	for	for	SCONJ
eurjchem-952	111	6	each	each	DET
eurjchem-952	111	7	individual	individual	NOUN
eurjchem-952	111	8	dose	dose	NOUN
eurjchem-952	111	9	and	and	CCONJ
eurjchem-952	111	10	ic50	ic50	PROPN
eurjchem-952	111	11	is	be	AUX
eurjchem-952	111	12	the	the	DET
eurjchem-952	111	13	mean	mean	NOUN
eurjchem-952	111	14	of	of	ADP
eurjchem-952	111	15	three	three	NUM
eurjchem-952	111	16	values	value	NOUN
eurjchem-952	111	17	.	.	PUNCT
eurjchem-952	112	1	monolayer	monolayer	NOUN
eurjchem-952	112	2	cells	cell	NOUN
eurjchem-952	112	3	were	be	AUX
eurjchem-952	112	4	incubated	incubate	VERB
eurjchem-952	112	5	for	for	ADP
eurjchem-952	112	6	48	48	NUM
eurjchem-952	112	7	h	h	NOUN
eurjchem-952	112	8	at	at	ADP
eurjchem-952	112	9	37	37	NUM
eurjchem-952	112	10	°	°	NOUN
eurjchem-952	112	11	c	c	NOUN
eurjchem-952	112	12	in	in	ADP
eurjchem-952	112	13	air	air	NOUN
eurjchem-952	112	14	with	with	ADP
eurjchem-952	112	15	5	5	NUM
eurjchem-952	112	16	%	%	NOUN
eurjchem-952	112	17	co2	co2	NOUN
eurjchem-952	112	18	.	.	PUNCT
eurjchem-952	113	1	after	after	ADP
eurjchem-952	113	2	48	48	NUM
eurjchem-952	113	3	h	h	NOUN
eurjchem-952	113	4	,	,	PUNCT
eurjchem-952	113	5	cells	cell	NOUN
eurjchem-952	113	6	were	be	AUX
eurjchem-952	113	7	fixed	fix	VERB
eurjchem-952	113	8	,	,	PUNCT
eurjchem-952	113	9	washed	wash	VERB
eurjchem-952	113	10	and	and	CCONJ
eurjchem-952	113	11	stained	stain	VERB
eurjchem-952	113	12	with	with	ADP
eurjchem-952	113	13	sulfo‐rhodamine‐b	sulfo‐rhodamine‐b	NOUN
eurjchem-952	113	14	stain	stain	NOUN
eurjchem-952	113	15	.	.	PUNCT
eurjchem-952	114	1	excess	excess	ADJ
eurjchem-952	114	2	stain	stain	NOUN
eurjchem-952	114	3	was	be	AUX
eurjchem-952	114	4	washed	wash	VERB
eurjchem-952	114	5	with	with	ADP
eurjchem-952	114	6	acetic	acetic	ADJ
eurjchem-952	114	7	acid	acid	NOUN
eurjchem-952	114	8	and	and	CCONJ
eurjchem-952	114	9	attached	attached	ADJ
eurjchem-952	114	10	stain	stain	NOUN
eurjchem-952	114	11	was	be	AUX
eurjchem-952	114	12	recovered	recover	VERB
eurjchem-952	114	13	with	with	ADP
eurjchem-952	114	14	tris‐edta	tris‐edta	NOUN
eurjchem-952	114	15	buffer	buffer	NOUN
eurjchem-952	114	16	.	.	PUNCT
eurjchem-952	115	1	color	color	NOUN
eurjchem-952	115	2	intensity	intensity	NOUN
eurjchem-952	115	3	is	be	AUX
eurjchem-952	115	4	measured	measure	VERB
eurjchem-952	115	5	in	in	ADP
eurjchem-952	115	6	an	an	DET
eurjchem-952	115	7	elisa	elisa	NOUN
eurjchem-952	115	8	reader	reader	NOUN
eurjchem-952	115	9	.	.	PUNCT
eurjchem-952	116	1	the	the	DET
eurjchem-952	116	2	average	average	ADJ
eurjchem-952	116	3	drug	drug	NOUN
eurjchem-952	116	4	concentration	concentration	NOUN
eurjchem-952	116	5	(	(	PUNCT
eurjchem-952	116	6	µg	µg	NOUN
eurjchem-952	116	7	/	/	SYM
eurjchem-952	116	8	cm3	cm3	NOUN
eurjchem-952	116	9	)	)	PUNCT
eurjchem-952	116	10	for	for	ADP
eurjchem-952	116	11	50	50	NUM
eurjchem-952	116	12	%	%	NOUN
eurjchem-952	116	13	inhibition	inhibition	NOUN
eurjchem-952	116	14	of	of	ADP
eurjchem-952	116	15	tumor	tumor	NOUN
eurjchem-952	116	16	cell‐growth	cell‐growth	NOUN
eurjchem-952	116	17	was	be	AUX
eurjchem-952	116	18	determined	determine	VERB
eurjchem-952	116	19	by	by	ADP
eurjchem-952	116	20	plotting	plot	VERB
eurjchem-952	116	21	the	the	DET
eurjchem-952	116	22	surviving	survive	VERB
eurjchem-952	116	23	fraction	fraction	NOUN
eurjchem-952	116	24	versus	versus	ADP
eurjchem-952	116	25	drug	drug	NOUN
eurjchem-952	116	26	concentration	concentration	NOUN
eurjchem-952	116	27	for	for	ADP
eurjchem-952	116	28	each	each	DET
eurjchem-952	116	29	tumor	tumor	NOUN
eurjchem-952	116	30	cell	cell	NOUN
eurjchem-952	116	31	line	line	NOUN
eurjchem-952	116	32	.	.	PUNCT
eurjchem-952	117	1	3	3	X
eurjchem-952	117	2	.	.	NOUN
eurjchem-952	117	3	results	result	NOUN
eurjchem-952	117	4	and	and	CCONJ
eurjchem-952	117	5	discussion	discussion	VERB
eurjchem-952	117	6	the	the	DET
eurjchem-952	117	7	isolated	isolated	ADJ
eurjchem-952	117	8	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-952	117	9	compound	compound	NOUN
eurjchem-952	117	10	is	be	AUX
eurjchem-952	117	11	formed	form	VERB
eurjchem-952	117	12	by	by	ADP
eurjchem-952	117	13	the	the	DET
eurjchem-952	117	14	interaction	interaction	NOUN
eurjchem-952	117	15	of	of	ADP
eurjchem-952	117	16	4‐(2‐pyridyl)‐3‐thiosemicarbazone	4‐(2‐pyridyl)‐3‐thiosemicarbazone	NOUN
eurjchem-952	117	17	with	with	ADP
eurjchem-952	117	18	1‐	1‐	NUM
eurjchem-952	117	19	methyl‐1h‐pyrazole‐5‐carboxaldehyde	methyl‐1h‐pyrazole‐5‐carboxaldehyde	PROPN
eurjchem-952	117	20	in	in	ADP
eurjchem-952	117	21	a	a	DET
eurjchem-952	117	22	molar	molar	ADJ
eurjchem-952	117	23	ratio	ratio	NOUN
eurjchem-952	117	24	1:1	1:1	NUM
eurjchem-952	117	25	under	under	ADP
eurjchem-952	117	26	reflux	reflux	NOUN
eurjchem-952	117	27	conditions	condition	NOUN
eurjchem-952	117	28	(	(	PUNCT
eurjchem-952	117	29	scheme	scheme	NOUN
eurjchem-952	117	30	3	3	NUM
eurjchem-952	117	31	)	)	PUNCT
eurjchem-952	117	32	.	.	PUNCT
eurjchem-952	118	1	the	the	DET
eurjchem-952	118	2	formulation	formulation	NOUN
eurjchem-952	118	3	of	of	ADP
eurjchem-952	118	4	the	the	DET
eurjchem-952	118	5	isolated	isolate	VERB
eurjchem-952	118	6	compounds	compound	NOUN
eurjchem-952	118	7	based	base	VERB
eurjchem-952	118	8	on	on	ADP
eurjchem-952	118	9	the	the	DET
eurjchem-952	118	10	elemental	elemental	ADJ
eurjchem-952	118	11	analysis	analysis	NOUN
eurjchem-952	118	12	,	,	PUNCT
eurjchem-952	118	13	ir	ir	NOUN
eurjchem-952	118	14	,	,	PUNCT
eurjchem-952	118	15	and	and	CCONJ
eurjchem-952	118	16	electronic	electronic	ADJ
eurjchem-952	118	17	spectra	spectra	NOUN
eurjchem-952	118	18	.	.	PUNCT
eurjchem-952	119	1	the	the	DET
eurjchem-952	119	2	solid	solid	ADJ
eurjchem-952	119	3	compounds	compound	NOUN
eurjchem-952	119	4	are	be	AUX
eurjchem-952	119	5	air	air	NOUN
eurjchem-952	119	6	stable	stable	ADJ
eurjchem-952	119	7	.	.	PUNCT
eurjchem-952	120	1	these	these	DET
eurjchem-952	120	2	compounds	compound	NOUN
eurjchem-952	120	3	are	be	AUX
eurjchem-952	120	4	colored	color	VERB
eurjchem-952	120	5	,	,	PUNCT
eurjchem-952	120	6	insoluble	insoluble	ADJ
eurjchem-952	120	7	in	in	ADP
eurjchem-952	120	8	h2o	h2o	PROPN
eurjchem-952	120	9	and	and	CCONJ
eurjchem-952	120	10	other	other	ADJ
eurjchem-952	120	11	common	common	ADJ
eurjchem-952	120	12	organic	organic	ADJ
eurjchem-952	120	13	solvents	solvent	NOUN
eurjchem-952	120	14	like	like	ADP
eurjchem-952	120	15	methanol	methanol	NOUN
eurjchem-952	120	16	and	and	CCONJ
eurjchem-952	120	17	ethanol	ethanol	NOUN
eurjchem-952	120	18	but	but	CCONJ
eurjchem-952	120	19	soluble	soluble	ADJ
eurjchem-952	120	20	in	in	ADP
eurjchem-952	120	21	dimethylformamide	dimethylformamide	NOUN
eurjchem-952	120	22	(	(	PUNCT
eurjchem-952	120	23	dmf	dmf	PROPN
eurjchem-952	120	24	)	)	PUNCT
eurjchem-952	120	25	and	and	CCONJ
eurjchem-952	120	26	dimethylsulphoxide	dimethylsulphoxide	NOUN
eurjchem-952	120	27	(	(	PUNCT
eurjchem-952	120	28	dmso	dmso	PROPN
eurjchem-952	120	29	)	)	PUNCT
eurjchem-952	120	30	.	.	PUNCT
eurjchem-952	121	1	attempts	attempt	VERB
eurjchem-952	121	2	to	to	PART
eurjchem-952	121	3	obtain	obtain	VERB
eurjchem-952	121	4	single	single	ADJ
eurjchem-952	121	5	crystal	crystal	NOUN
eurjchem-952	121	6	suitable	suitable	ADJ
eurjchem-952	121	7	for	for	ADP
eurjchem-952	121	8	x‐ray	x‐ray	ADJ
eurjchem-952	121	9	determination	determination	NOUN
eurjchem-952	121	10	were	be	AUX
eurjchem-952	121	11	unsuccessful	unsuccessful	ADJ
eurjchem-952	121	12	,	,	PUNCT
eurjchem-952	121	13	thus	thus	ADV
eurjchem-952	121	14	molecular	molecular	ADJ
eurjchem-952	121	15	modeling	modeling	NOUN
eurjchem-952	121	16	for	for	ADP
eurjchem-952	121	17	mpapt	mpapt	ADJ
eurjchem-952	121	18	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-952	121	19	compound	compound	NOUN
eurjchem-952	121	20	and	and	CCONJ
eurjchem-952	121	21	its	its	PRON
eurjchem-952	121	22	m(ii)‐complexes	m(ii)‐complexe	NOUN
eurjchem-952	121	23	were	be	AUX
eurjchem-952	121	24	investigated	investigate	VERB
eurjchem-952	121	25	.	.	PUNCT
eurjchem-952	122	1	3.1	3.1	NUM
eurjchem-952	122	2	.	.	PUNCT
eurjchem-952	122	3	infrared	infrared	PROPN
eurjchem-952	122	4	spectra	spectra	PROPN
eurjchem-952	123	1	the	the	DET
eurjchem-952	123	2	characteristic	characteristic	ADJ
eurjchem-952	123	3	ir	ir	NOUN
eurjchem-952	123	4	peaks	peak	NOUN
eurjchem-952	123	5	of	of	ADP
eurjchem-952	123	6	the	the	DET
eurjchem-952	123	7	free	free	ADJ
eurjchem-952	123	8	mpapt	mpapt	ADJ
eurjchem-952	123	9	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-952	123	10	compound	compound	NOUN
eurjchem-952	123	11	and	and	CCONJ
eurjchem-952	123	12	its	its	PRON
eurjchem-952	123	13	metal(ii	metal(ii	NOUN
eurjchem-952	123	14	)	)	PUNCT
eurjchem-952	123	15	complexes	complex	NOUN
eurjchem-952	123	16	reveal	reveal	VERB
eurjchem-952	123	17	each	each	PRON
eurjchem-952	123	18	of	of	ADP
eurjchem-952	123	19	the	the	DET
eurjchem-952	123	20	following	following	NOUN
eurjchem-952	123	21	:	:	PUNCT
eurjchem-952	123	22	the	the	DET
eurjchem-952	123	23	stretching	stretch	VERB
eurjchem-952	123	24	vibrations	vibration	NOUN
eurjchem-952	123	25	of	of	ADP
eurjchem-952	123	26	azomethine	azomethine	NOUN
eurjchem-952	123	27	functionality	functionality	NOUN
eurjchem-952	123	28	ν(c	ν(c	PROPN
eurjchem-952	123	29	=	=	SYM
eurjchem-952	123	30	n	n	CCONJ
eurjchem-952	123	31	)	)	PUNCT
eurjchem-952	123	32	was	be	AUX
eurjchem-952	123	33	observed	observe	VERB
eurjchem-952	123	34	near	near	ADP
eurjchem-952	123	35	1648	1648	NUM
eurjchem-952	123	36	cm‐1	cm‐1	NOUN
eurjchem-952	123	37	.	.	PUNCT
eurjchem-952	124	1	the	the	DET
eurjchem-952	124	2	lower	low	ADJ
eurjchem-952	124	3	shift	shift	NOUN
eurjchem-952	124	4	of	of	ADP
eurjchem-952	124	5	ν(c	ν(c	PROPN
eurjchem-952	124	6	=	=	SYM
eurjchem-952	124	7	n	n	CCONJ
eurjchem-952	124	8	)	)	PUNCT
eurjchem-952	124	9	stretching	stretch	VERB
eurjchem-952	124	10	vibration	vibration	NOUN
eurjchem-952	124	11	of	of	ADP
eurjchem-952	124	12	the	the	DET
eurjchem-952	124	13	azomethine	azomethine	NOUN
eurjchem-952	124	14	in	in	ADP
eurjchem-952	124	15	the	the	DET
eurjchem-952	124	16	complexes	complex	NOUN
eurjchem-952	124	17	indicating	indicate	VERB
eurjchem-952	124	18	the	the	DET
eurjchem-952	124	19	participation	participation	NOUN
eurjchem-952	124	20	of	of	ADP
eurjchem-952	124	21	the	the	DET
eurjchem-952	124	22	azomethine	azomethine	NOUN
eurjchem-952	124	23	nitrogen	nitrogen	NOUN
eurjchem-952	124	24	in	in	ADP
eurjchem-952	124	25	coordination	coordination	NOUN
eurjchem-952	124	26	[	[	X
eurjchem-952	124	27	31	31	NUM
eurjchem-952	124	28	]	]	PUNCT
eurjchem-952	124	29	.	.	PUNCT
eurjchem-952	125	1	the	the	DET
eurjchem-952	125	2	ν(n‐n	ν(n‐n	NUM
eurjchem-952	125	3	)	)	PUNCT
eurjchem-952	125	4	of	of	ADP
eurjchem-952	125	5	the	the	DET
eurjchem-952	125	6	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-952	125	7	ligand	ligand	NOUN
eurjchem-952	125	8	is	be	AUX
eurjchem-952	125	9	found	find	VERB
eurjchem-952	125	10	at	at	ADP
eurjchem-952	125	11	1068	1068	NUM
eurjchem-952	125	12	cm‐1	cm‐1	NOUN
eurjchem-952	125	13	.	.	PUNCT
eurjchem-952	126	1	the	the	DET
eurjchem-952	126	2	increase	increase	NOUN
eurjchem-952	126	3	in	in	ADP
eurjchem-952	126	4	frequency	frequency	NOUN
eurjchem-952	126	5	of	of	ADP
eurjchem-952	126	6	this	this	DET
eurjchem-952	126	7	band	band	NOUN
eurjchem-952	126	8	in	in	ADP
eurjchem-952	126	9	the	the	DET
eurjchem-952	126	10	spectra	spectra	NOUN
eurjchem-952	126	11	of	of	ADP
eurjchem-952	126	12	complexes	complex	NOUN
eurjchem-952	126	13	due	due	ADP
eurjchem-952	126	14	to	to	ADP
eurjchem-952	126	15	the	the	DET
eurjchem-952	126	16	increase	increase	NOUN
eurjchem-952	126	17	in	in	ADP
eurjchem-952	126	18	the	the	DET
eurjchem-952	126	19	double	double	ADJ
eurjchem-952	126	20	bond	bond	NOUN
eurjchem-952	126	21	character	character	NOUN
eurjchem-952	126	22	of	of	ADP
eurjchem-952	126	23	n‐n	n‐n	ADP
eurjchem-952	126	24	[	[	X
eurjchem-952	126	25	32	32	NUM
eurjchem-952	126	26	]	]	PUNCT
eurjchem-952	126	27	is	be	AUX
eurjchem-952	126	28	an	an	DET
eurjchem-952	126	29	evidence	evidence	NOUN
eurjchem-952	126	30	for	for	ADP
eurjchem-952	126	31	the	the	DET
eurjchem-952	126	32	enethiolization	enethiolization	NOUN
eurjchem-952	126	33	of	of	ADP
eurjchem-952	126	34	the	the	DET
eurjchem-952	126	35	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-952	126	36	ligand	ligand	NOUN
eurjchem-952	126	37	and	and	CCONJ
eurjchem-952	126	38	the	the	DET
eurjchem-952	126	39	coordination	coordination	NOUN
eurjchem-952	126	40	via	via	ADP
eurjchem-952	126	41	the	the	DET
eurjchem-952	126	42	azomethine	azomethine	NOUN
eurjchem-952	126	43	nitrogen	nitrogen	NOUN
eurjchem-952	126	44	.	.	PUNCT
eurjchem-952	127	1	the	the	DET
eurjchem-952	127	2	ν(n1h	ν(n1h	NOUN
eurjchem-952	127	3	)	)	PUNCT
eurjchem-952	127	4	and	and	CCONJ
eurjchem-952	127	5	hydrazine	hydrazine	NOUN
eurjchem-952	127	6	ν(n2h	ν(n2h	PROPN
eurjchem-952	127	7	)	)	PUNCT
eurjchem-952	127	8	were	be	AUX
eurjchem-952	127	9	observed	observe	VERB
eurjchem-952	127	10	at	at	ADP
eurjchem-952	127	11	3188	3188	NUM
eurjchem-952	127	12	and	and	CCONJ
eurjchem-952	127	13	3168	3168	NUM
eurjchem-952	127	14	cm‐1	cm‐1	NOUN
eurjchem-952	127	15	.	.	PUNCT
eurjchem-952	128	1	the	the	DET
eurjchem-952	128	2	pyridine	pyridine	ADJ
eurjchem-952	128	3	in‐plane	in‐plane	ADJ
eurjchem-952	128	4	deformation	deformation	NOUN
eurjchem-952	128	5	mode	mode	NOUN
eurjchem-952	128	6	at	at	ADP
eurjchem-952	128	7	622	622	NUM
eurjchem-952	128	8	cm‐1	cm‐1	NOUN
eurjchem-952	128	9	in	in	ADP
eurjchem-952	128	10	the	the	DET
eurjchem-952	128	11	spectrum	spectrum	NOUN
eurjchem-952	128	12	of	of	ADP
eurjchem-952	128	13	the	the	DET
eurjchem-952	128	14	ligand	ligand	ADJ
eurjchem-952	128	15	shifts	shift	NOUN
eurjchem-952	128	16	to	to	ADP
eurjchem-952	128	17	611‐615	611‐615	PROPN
eurjchem-952	128	18	cm‐1	cm‐1	PROPN
eurjchem-952	128	19	in	in	ADP
eurjchem-952	128	20	spectra	spectra	NOUN
eurjchem-952	128	21	of	of	ADP
eurjchem-952	128	22	204	204	NUM
eurjchem-952	128	23	aljahdali	aljahdali	PROPN
eurjchem-952	128	24	et	et	PROPN
eurjchem-952	128	25	al	al	PROPN
eurjchem-952	128	26	.	.	PUNCT
eurjchem-952	128	27	/	/	SYM
eurjchem-952	128	28	european	european	PROPN
eurjchem-952	128	29	journal	journal	PROPN
eurjchem-952	128	30	of	of	ADP
eurjchem-952	128	31	chemistry	chemistry	NOUN
eurjchem-952	128	32	5	5	NUM
eurjchem-952	128	33	(	(	PUNCT
eurjchem-952	128	34	2	2	NUM
eurjchem-952	128	35	)	)	PUNCT
eurjchem-952	128	36	(	(	PUNCT
eurjchem-952	128	37	2014	2014	NUM
eurjchem-952	128	38	)	)	PUNCT
eurjchem-952	128	39	201‐208	201‐208	NOUN
eurjchem-952	128	40	the	the	DET
eurjchem-952	128	41	above	above	ADJ
eurjchem-952	128	42	complexes	complex	NOUN
eurjchem-952	128	43	,	,	PUNCT
eurjchem-952	128	44	suggesting	suggest	VERB
eurjchem-952	128	45	coordination	coordination	NOUN
eurjchem-952	128	46	of	of	ADP
eurjchem-952	128	47	the	the	DET
eurjchem-952	128	48	heteroaromatic	heteroaromatic	ADJ
eurjchem-952	128	49	nitrogen	nitrogen	NOUN
eurjchem-952	128	50	.	.	PUNCT
eurjchem-952	129	1	in	in	ADP
eurjchem-952	129	2	the	the	DET
eurjchem-952	129	3	spectra	spectra	NOUN
eurjchem-952	129	4	of	of	ADP
eurjchem-952	129	5	all	all	DET
eurjchem-952	129	6	complexes	complex	NOUN
eurjchem-952	129	7	,	,	PUNCT
eurjchem-952	129	8	the	the	DET
eurjchem-952	129	9	bands	band	NOUN
eurjchem-952	129	10	assigned	assign	VERB
eurjchem-952	129	11	to	to	ADP
eurjchem-952	129	12	the	the	DET
eurjchem-952	129	13	newly	newly	ADV
eurjchem-952	129	14	formed	form	VERB
eurjchem-952	129	15	(	(	PUNCT
eurjchem-952	129	16	n	n	CCONJ
eurjchem-952	129	17	=	=	SYM
eurjchem-952	129	18	c	c	NOUN
eurjchem-952	129	19	)	)	PUNCT
eurjchem-952	129	20	*	*	PUNCT
eurjchem-952	129	21	band	band	NOUN
eurjchem-952	129	22	due	due	ADP
eurjchem-952	129	23	to	to	ADP
eurjchem-952	129	24	the	the	DET
eurjchem-952	129	25	thiolating	thiolating	NOUN
eurjchem-952	129	26	of	of	ADP
eurjchem-952	129	27	the	the	DET
eurjchem-952	129	28	(	(	PUNCT
eurjchem-952	129	29	c	c	NOUN
eurjchem-952	129	30	=	=	SYM
eurjchem-952	129	31	s	s	NOUN
eurjchem-952	129	32	)	)	PUNCT
eurjchem-952	129	33	groups	group	NOUN
eurjchem-952	129	34	are	be	AUX
eurjchem-952	129	35	located	locate	VERB
eurjchem-952	129	36	in	in	ADP
eurjchem-952	129	37	the	the	DET
eurjchem-952	129	38	range	range	NOUN
eurjchem-952	129	39	1575‐	1575‐	NUM
eurjchem-952	129	40	1591	1591	NUM
eurjchem-952	129	41	cm‐1	cm‐1	NOUN
eurjchem-952	129	42	.	.	PUNCT
eurjchem-952	130	1	the	the	DET
eurjchem-952	130	2	ir	ir	PROPN
eurjchem-952	130	3	spectrum	spectrum	NOUN
eurjchem-952	130	4	of	of	ADP
eurjchem-952	130	5	the	the	DET
eurjchem-952	130	6	free	free	PROPN
eurjchem-952	130	7	1,10‐phen	1,10‐phen	PROPN
eurjchem-952	130	8	ligand	ligand	NOUN
eurjchem-952	130	9	shows	show	VERB
eurjchem-952	130	10	a	a	DET
eurjchem-952	130	11	very	very	ADV
eurjchem-952	130	12	stronger	strong	ADJ
eurjchem-952	130	13	bands	band	NOUN
eurjchem-952	130	14	at	at	ADP
eurjchem-952	130	15	~1570	~1570	NUM
eurjchem-952	130	16	cm‐1	cm‐1	NOUN
eurjchem-952	130	17	due	due	ADP
eurjchem-952	130	18	to	to	ADP
eurjchem-952	130	19	stretching	stretch	VERB
eurjchem-952	130	20	frequency	frequency	NOUN
eurjchem-952	130	21	of	of	ADP
eurjchem-952	130	22	>	>	X
eurjchem-952	130	23	c	c	PROPN
eurjchem-952	130	24	=	=	NOUN
eurjchem-952	130	25	n	n	PRON
eurjchem-952	130	26	present	present	ADJ
eurjchem-952	130	27	in	in	ADP
eurjchem-952	130	28	1,10‐phenanthroline	1,10‐phenanthroline	NUM
eurjchem-952	130	29	moiety	moiety	NOUN
eurjchem-952	130	30	.	.	PUNCT
eurjchem-952	131	1	this	this	DET
eurjchem-952	131	2	band	band	NOUN
eurjchem-952	131	3	was	be	AUX
eurjchem-952	131	4	shifted	shift	VERB
eurjchem-952	131	5	to	to	ADP
eurjchem-952	131	6	lower	low	ADJ
eurjchem-952	131	7	frequencies	frequency	NOUN
eurjchem-952	131	8	in	in	ADP
eurjchem-952	131	9	the	the	DET
eurjchem-952	131	10	complexes	complex	NOUN
eurjchem-952	131	11	~25‐28	~25‐28	NUM
eurjchem-952	131	12	cm‐1	cm‐1	NOUN
eurjchem-952	131	13	,	,	PUNCT
eurjchem-952	131	14	which	which	PRON
eurjchem-952	131	15	clearly	clearly	ADV
eurjchem-952	131	16	indicate	indicate	VERB
eurjchem-952	131	17	that	that	SCONJ
eurjchem-952	131	18	the	the	DET
eurjchem-952	131	19	coordination	coordination	NOUN
eurjchem-952	131	20	of	of	ADP
eurjchem-952	131	21	the	the	DET
eurjchem-952	131	22	two	two	NUM
eurjchem-952	131	23	nitrogen	nitrogen	NOUN
eurjchem-952	131	24	atoms	atom	NOUN
eurjchem-952	131	25	of	of	ADP
eurjchem-952	131	26	the	the	DET
eurjchem-952	131	27	neutral	neutral	ADJ
eurjchem-952	131	28	1,10‐phen	1,10‐phen	PROPN
eurjchem-952	131	29	ligand	ligand	NOUN
eurjchem-952	131	30	to	to	ADP
eurjchem-952	131	31	m(ii	m(ii	NOUN
eurjchem-952	131	32	)	)	PUNCT
eurjchem-952	131	33	ion	ion	NOUN
eurjchem-952	131	34	upon	upon	SCONJ
eurjchem-952	131	35	complexation	complexation	NOUN
eurjchem-952	131	36	[	[	X
eurjchem-952	131	37	33	33	NUM
eurjchem-952	131	38	]	]	PUNCT
eurjchem-952	131	39	.	.	PUNCT
eurjchem-952	132	1	in	in	ADP
eurjchem-952	132	2	the	the	DET
eurjchem-952	132	3	ligand	ligand	NOUN
eurjchem-952	132	4	spectra	spectra	NOUN
eurjchem-952	132	5	,	,	PUNCT
eurjchem-952	132	6	the	the	DET
eurjchem-952	132	7	strong	strong	ADJ
eurjchem-952	132	8	band	band	NOUN
eurjchem-952	132	9	observed	observe	VERB
eurjchem-952	132	10	in	in	ADP
eurjchem-952	132	11	the	the	DET
eurjchem-952	132	12	range	range	NOUN
eurjchem-952	132	13	1549	1549	NUM
eurjchem-952	132	14	cm‐1	cm‐1	NOUN
eurjchem-952	132	15	is	be	AUX
eurjchem-952	132	16	assigned	assign	VERB
eurjchem-952	132	17	to	to	ADP
eurjchem-952	132	18	ν(c	ν(c	NOUN
eurjchem-952	132	19	=	=	SYM
eurjchem-952	132	20	n	n	CCONJ
eurjchem-952	132	21	)	)	PUNCT
eurjchem-952	132	22	stretching	stretch	VERB
eurjchem-952	132	23	vibration	vibration	NOUN
eurjchem-952	132	24	[	[	X
eurjchem-952	132	25	34	34	NUM
eurjchem-952	132	26	]	]	PUNCT
eurjchem-952	132	27	of	of	ADP
eurjchem-952	132	28	pyridine	pyridine	NOUN
eurjchem-952	132	29	ring	ring	NOUN
eurjchem-952	132	30	.	.	PUNCT
eurjchem-952	133	1	in	in	ADP
eurjchem-952	133	2	the	the	DET
eurjchem-952	133	3	spectra	spectra	NOUN
eurjchem-952	133	4	of	of	ADP
eurjchem-952	133	5	complexes	complex	NOUN
eurjchem-952	133	6	,	,	PUNCT
eurjchem-952	133	7	this	this	DET
eurjchem-952	133	8	band	band	NOUN
eurjchem-952	133	9	was	be	AUX
eurjchem-952	133	10	not	not	PART
eurjchem-952	133	11	observed	observe	VERB
eurjchem-952	133	12	at	at	ADP
eurjchem-952	133	13	the	the	DET
eurjchem-952	133	14	same	same	ADJ
eurjchem-952	133	15	frequencies	frequency	NOUN
eurjchem-952	133	16	and	and	CCONJ
eurjchem-952	133	17	the	the	DET
eurjchem-952	133	18	same	same	ADJ
eurjchem-952	133	19	intensities	intensity	NOUN
eurjchem-952	133	20	.	.	PUNCT
eurjchem-952	134	1	it	it	PRON
eurjchem-952	134	2	shifted	shift	VERB
eurjchem-952	134	3	after	after	ADP
eurjchem-952	134	4	coordination	coordination	NOUN
eurjchem-952	134	5	to	to	PART
eurjchem-952	134	6	lower	lower	VERB
eurjchem-952	134	7	energies	energy	NOUN
eurjchem-952	134	8	by	by	ADP
eurjchem-952	134	9	ca	ca	PROPN
eurjchem-952	134	10	.	.	PUNCT
eurjchem-952	135	1	19‐24	19‐24	PROPN
eurjchem-952	135	2	cm‐1	cm‐1	PROPN
eurjchem-952	135	3	,	,	PUNCT
eurjchem-952	135	4	indicating	indicate	VERB
eurjchem-952	135	5	coordination	coordination	NOUN
eurjchem-952	135	6	via	via	ADP
eurjchem-952	135	7	azomethine	azomethine	PROPN
eurjchem-952	135	8	nitrogen	nitrogen	NOUN
eurjchem-952	136	1	[	[	X
eurjchem-952	136	2	35	35	NUM
eurjchem-952	136	3	]	]	PUNCT
eurjchem-952	136	4	.	.	PUNCT
eurjchem-952	137	1	the	the	DET
eurjchem-952	137	2	coordination	coordination	NOUN
eurjchem-952	137	3	positions	position	NOUN
eurjchem-952	137	4	of	of	ADP
eurjchem-952	137	5	the	the	DET
eurjchem-952	137	6	mpapt	mpapt	ADJ
eurjchem-952	137	7	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-952	137	8	in	in	ADP
eurjchem-952	137	9	the	the	DET
eurjchem-952	137	10	m(ii	m(ii	NOUN
eurjchem-952	137	11	)	)	PUNCT
eurjchem-952	137	12	complexes	complex	NOUN
eurjchem-952	137	13	are	be	AUX
eurjchem-952	137	14	confirmed	confirm	VERB
eurjchem-952	137	15	by	by	ADP
eurjchem-952	137	16	assigning	assign	VERB
eurjchem-952	137	17	the	the	DET
eurjchem-952	137	18	strong	strong	ADJ
eurjchem-952	137	19	bands	band	NOUN
eurjchem-952	137	20	observed	observe	VERB
eurjchem-952	137	21	in	in	ADP
eurjchem-952	137	22	the	the	DET
eurjchem-952	137	23	far	far	PROPN
eurjchem-952	137	24	ir	ir	PROPN
eurjchem-952	137	25	spectra	spectra	NOUN
eurjchem-952	137	26	of	of	ADP
eurjchem-952	137	27	the	the	DET
eurjchem-952	137	28	complexes	complex	NOUN
eurjchem-952	137	29	.	.	PUNCT
eurjchem-952	138	1	the	the	DET
eurjchem-952	138	2	bands	band	NOUN
eurjchem-952	138	3	observed	observe	VERB
eurjchem-952	138	4	at	at	ADP
eurjchem-952	138	5	448‐455	448‐455	PROPN
eurjchem-952	138	6	and	and	CCONJ
eurjchem-952	138	7	340‐345	340‐345	NUM
eurjchem-952	138	8	cm‐1	cm‐1	NOUN
eurjchem-952	138	9	are	be	AUX
eurjchem-952	138	10	assigned	assign	VERB
eurjchem-952	138	11	to	to	ADP
eurjchem-952	138	12	ν(m‐n	ν(m‐n	PROPN
eurjchem-952	138	13	)	)	PUNCT
eurjchem-952	139	1	[	[	X
eurjchem-952	139	2	36	36	NUM
eurjchem-952	139	3	]	]	PUNCT
eurjchem-952	139	4	and	and	CCONJ
eurjchem-952	139	5	ν(m‐s	ν(m‐s	NUM
eurjchem-952	139	6	)	)	PUNCT
eurjchem-952	139	7	as	as	SCONJ
eurjchem-952	139	8	suggested	suggest	VERB
eurjchem-952	139	9	by	by	ADP
eurjchem-952	139	10	lever	lever	NOUN
eurjchem-952	139	11	[	[	X
eurjchem-952	139	12	37	37	NUM
eurjchem-952	139	13	]	]	PUNCT
eurjchem-952	139	14	,	,	PUNCT
eurjchem-952	139	15	respectively	respectively	ADV
eurjchem-952	139	16	.	.	PUNCT
eurjchem-952	140	1	the	the	DET
eurjchem-952	140	2	broad	broad	ADJ
eurjchem-952	140	3	band	band	NOUN
eurjchem-952	140	4	centered	center	VERB
eurjchem-952	140	5	at	at	ADP
eurjchem-952	140	6	3460‐3490	3460‐3490	NUM
eurjchem-952	140	7	cm‐1	cm‐1	NOUN
eurjchem-952	140	8	in	in	ADP
eurjchem-952	140	9	the	the	DET
eurjchem-952	140	10	spectra	spectra	NOUN
eurjchem-952	140	11	of	of	ADP
eurjchem-952	140	12	both	both	DET
eurjchem-952	140	13	co(ii	co(ii	PROPN
eurjchem-952	140	14	)	)	PUNCT
eurjchem-952	140	15	and	and	CCONJ
eurjchem-952	140	16	mn(ii	mn(ii	NOUN
eurjchem-952	140	17	)	)	PUNCT
eurjchem-952	140	18	complexes	complex	NOUN
eurjchem-952	140	19	may	may	AUX
eurjchem-952	140	20	be	be	AUX
eurjchem-952	140	21	due	due	ADJ
eurjchem-952	140	22	to	to	ADP
eurjchem-952	140	23	hydrated	hydrated	ADJ
eurjchem-952	140	24	water	water	NOUN
eurjchem-952	140	25	.	.	PUNCT
eurjchem-952	141	1	in	in	ADP
eurjchem-952	141	2	the	the	DET
eurjchem-952	141	3	literature	literature	NOUN
eurjchem-952	141	4	,	,	PUNCT
eurjchem-952	141	5	the	the	DET
eurjchem-952	141	6	bands	band	NOUN
eurjchem-952	141	7	appearing	appear	VERB
eurjchem-952	141	8	between	between	ADP
eurjchem-952	141	9	160	160	NUM
eurjchem-952	141	10	and	and	CCONJ
eurjchem-952	141	11	300	300	NUM
eurjchem-952	141	12	cm‐1	cm‐1	NOUN
eurjchem-952	141	13	are	be	AUX
eurjchem-952	141	14	allotted	allot	VERB
eurjchem-952	141	15	to	to	ADP
eurjchem-952	141	16	the	the	DET
eurjchem-952	141	17	vibration	vibration	NOUN
eurjchem-952	141	18	of	of	ADP
eurjchem-952	141	19	the	the	DET
eurjchem-952	141	20	m‐x	m‐x	NOUN
eurjchem-952	141	21	bonds	bond	NOUN
eurjchem-952	141	22	where	where	SCONJ
eurjchem-952	141	23	m	m	NOUN
eurjchem-952	141	24	=	=	VERB
eurjchem-952	141	25	metal	metal	NOUN
eurjchem-952	141	26	and	and	CCONJ
eurjchem-952	141	27	x	x	X
eurjchem-952	141	28	=	=	X
eurjchem-952	141	29	cl	cl	NOUN
eurjchem-952	141	30	or	or	CCONJ
eurjchem-952	141	31	br	br	NOUN
eurjchem-952	142	1	[	[	X
eurjchem-952	142	2	38,39	38,39	NOUN
eurjchem-952	142	3	]	]	X
eurjchem-952	142	4	.	.	PUNCT
eurjchem-952	143	1	in	in	ADP
eurjchem-952	143	2	our	our	PRON
eurjchem-952	143	3	case	case	NOUN
eurjchem-952	143	4	the	the	DET
eurjchem-952	143	5	ν(m‐cl	ν(m‐cl	NOUN
eurjchem-952	143	6	)	)	PUNCT
eurjchem-952	143	7	frequencies	frequency	NOUN
eurjchem-952	143	8	appearing	appear	VERB
eurjchem-952	143	9	between	between	ADP
eurjchem-952	143	10	248‐263	248‐263	PROPN
eurjchem-952	143	11	cm‐1	cm‐1	NOUN
eurjchem-952	143	12	are	be	AUX
eurjchem-952	143	13	in	in	ADP
eurjchem-952	143	14	good	good	ADJ
eurjchem-952	143	15	agreement	agreement	NOUN
eurjchem-952	143	16	with	with	ADP
eurjchem-952	143	17	the	the	DET
eurjchem-952	143	18	reported	report	VERB
eurjchem-952	143	19	values	value	NOUN
eurjchem-952	143	20	in	in	ADP
eurjchem-952	143	21	the	the	DET
eurjchem-952	143	22	literature	literature	NOUN
eurjchem-952	143	23	.	.	PUNCT
eurjchem-952	144	1	based	base	VERB
eurjchem-952	144	2	on	on	ADP
eurjchem-952	144	3	the	the	DET
eurjchem-952	144	4	above	above	ADJ
eurjchem-952	144	5	spectral	spectral	ADJ
eurjchem-952	144	6	evidences	evidence	NOUN
eurjchem-952	144	7	,	,	PUNCT
eurjchem-952	144	8	it	it	PRON
eurjchem-952	144	9	is	be	AUX
eurjchem-952	144	10	confirmed	confirm	VERB
eurjchem-952	144	11	that	that	SCONJ
eurjchem-952	144	12	the	the	DET
eurjchem-952	144	13	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-952	144	14	ligands	ligand	NOUN
eurjchem-952	144	15	lost	lose	VERB
eurjchem-952	144	16	the	the	DET
eurjchem-952	144	17	n2	n2	ADJ
eurjchem-952	144	18	proton	proton	NOUN
eurjchem-952	144	19	and	and	CCONJ
eurjchem-952	144	20	coordinated	coordinate	VERB
eurjchem-952	144	21	to	to	ADP
eurjchem-952	144	22	the	the	DET
eurjchem-952	144	23	m(ii	m(ii	NOUN
eurjchem-952	144	24	)	)	PUNCT
eurjchem-952	144	25	ion	ion	NOUN
eurjchem-952	144	26	as	as	ADP
eurjchem-952	144	27	mononegative	mononegative	ADJ
eurjchem-952	144	28	tridentate	tridentate	NOUN
eurjchem-952	144	29	anion	anion	NOUN
eurjchem-952	144	30	,	,	PUNCT
eurjchem-952	144	31	coordinating	coordinate	VERB
eurjchem-952	144	32	via	via	ADP
eurjchem-952	144	33	the	the	DET
eurjchem-952	144	34	azomethine	azomethine	NOUN
eurjchem-952	144	35	and	and	CCONJ
eurjchem-952	144	36	pyridine	pyridine	ADJ
eurjchem-952	144	37	nitrogen	nitrogen	NOUN
eurjchem-952	144	38	atoms	atom	NOUN
eurjchem-952	144	39	and	and	CCONJ
eurjchem-952	144	40	the	the	DET
eurjchem-952	144	41	thiolate	thiolate	ADJ
eurjchem-952	144	42	sulfur	sulfur	NOUN
eurjchem-952	144	43	atom	atom	NOUN
eurjchem-952	144	44	after	after	ADP
eurjchem-952	144	45	deprotonation	deprotonation	NOUN
eurjchem-952	144	46	.	.	PUNCT
eurjchem-952	145	1	3.2	3.2	NUM
eurjchem-952	145	2	.	.	PUNCT
eurjchem-952	145	3	electronic	electronic	ADJ
eurjchem-952	145	4	spectra	spectra	NOUN
eurjchem-952	145	5	the	the	DET
eurjchem-952	145	6	probable	probable	ADJ
eurjchem-952	145	7	assignments	assignment	NOUN
eurjchem-952	145	8	for	for	ADP
eurjchem-952	145	9	the	the	DET
eurjchem-952	145	10	bands	band	NOUN
eurjchem-952	145	11	in	in	ADP
eurjchem-952	145	12	the	the	DET
eurjchem-952	145	13	region	region	NOUN
eurjchem-952	145	14	27345	27345	NUM
eurjchem-952	145	15	and	and	CCONJ
eurjchem-952	145	16	32989	32989	NUM
eurjchem-952	145	17	cm‐1	cm‐1	NOUN
eurjchem-952	145	18	are	be	AUX
eurjchem-952	145	19	due	due	ADJ
eurjchem-952	145	20	to	to	ADP
eurjchem-952	145	21	the	the	DET
eurjchem-952	145	22	n	n	NOUN
eurjchem-952	145	23	→	→	SYM
eurjchem-952	145	24	π	π	PROPN
eurjchem-952	145	25	*	*	PUNCT
eurjchem-952	145	26	and	and	CCONJ
eurjchem-952	145	27	π	π	PROPN
eurjchem-952	145	28	→	→	SYM
eurjchem-952	145	29	π	π	PROPN
eurjchem-952	145	30	*	*	NOUN
eurjchem-952	145	31	transitions	transition	NOUN
eurjchem-952	145	32	of	of	ADP
eurjchem-952	145	33	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-952	145	34	compound	compound	NOUN
eurjchem-952	145	35	respectively	respectively	ADV
eurjchem-952	145	36	.	.	PUNCT
eurjchem-952	146	1	always	always	ADV
eurjchem-952	146	2	n	n	PROPN
eurjchem-952	146	3	→	→	SYM
eurjchem-952	146	4	π	π	PROPN
eurjchem-952	146	5	*	*	NOUN
eurjchem-952	146	6	transitions	transition	NOUN
eurjchem-952	146	7	occurs	occur	VERB
eurjchem-952	146	8	at	at	ADP
eurjchem-952	146	9	a	a	DET
eurjchem-952	146	10	lower	low	ADJ
eurjchem-952	146	11	energy	energy	NOUN
eurjchem-952	146	12	than	than	ADP
eurjchem-952	146	13	π	π	PROPN
eurjchem-952	146	14	→	→	SYM
eurjchem-952	146	15	π	π	PROPN
eurjchem-952	146	16	*	*	NOUN
eurjchem-952	146	17	transitions	transition	NOUN
eurjchem-952	146	18	[	[	X
eurjchem-952	146	19	40	40	NUM
eurjchem-952	146	20	]	]	PUNCT
eurjchem-952	146	21	.	.	PUNCT
eurjchem-952	147	1	in	in	ADP
eurjchem-952	147	2	the	the	DET
eurjchem-952	147	3	spectra	spectra	NOUN
eurjchem-952	147	4	of	of	ADP
eurjchem-952	147	5	m(ii	m(ii	PROPN
eurjchem-952	147	6	)	)	PUNCT
eurjchem-952	147	7	complexes	complexe	VERB
eurjchem-952	147	8	the	the	DET
eurjchem-952	147	9	bands	band	NOUN
eurjchem-952	147	10	observed	observe	VERB
eurjchem-952	147	11	in	in	ADP
eurjchem-952	147	12	the	the	DET
eurjchem-952	147	13	region	region	NOUN
eurjchem-952	147	14	26521‐26920	26521‐26920	NUM
eurjchem-952	147	15	cm‐1	cm‐1	NOUN
eurjchem-952	147	16	are	be	AUX
eurjchem-952	147	17	assigned	assign	VERB
eurjchem-952	147	18	to	to	ADP
eurjchem-952	147	19	s→m	s→m	VERB
eurjchem-952	147	20	charge‐transfer	charge‐transfer	NOUN
eurjchem-952	147	21	band	band	NOUN
eurjchem-952	148	1	[	[	X
eurjchem-952	148	2	41	41	NUM
eurjchem-952	148	3	]	]	PUNCT
eurjchem-952	148	4	.	.	PUNCT
eurjchem-952	149	1	the	the	DET
eurjchem-952	149	2	bands	band	NOUN
eurjchem-952	149	3	in	in	ADP
eurjchem-952	149	4	the	the	DET
eurjchem-952	149	5	range	range	NOUN
eurjchem-952	149	6	30870‐	30870‐	NUM
eurjchem-952	149	7	31108	31108	NUM
eurjchem-952	149	8	cm‐1	cm‐1	NOUN
eurjchem-952	149	9	observed	observe	VERB
eurjchem-952	149	10	in	in	ADP
eurjchem-952	149	11	the	the	DET
eurjchem-952	149	12	spectra	spectra	NOUN
eurjchem-952	149	13	of	of	ADP
eurjchem-952	149	14	all	all	DET
eurjchem-952	149	15	m(ii	m(ii	NOUN
eurjchem-952	149	16	)	)	PUNCT
eurjchem-952	149	17	complexes	complex	NOUN
eurjchem-952	149	18	are	be	AUX
eurjchem-952	149	19	assigned	assign	VERB
eurjchem-952	149	20	as	as	ADP
eurjchem-952	149	21	cl	cl	NOUN
eurjchem-952	149	22	→	→	SYM
eurjchem-952	149	23	m	m	NOUN
eurjchem-952	149	24	charge‐transfer	charge‐transfer	NOUN
eurjchem-952	149	25	transitions	transition	NOUN
eurjchem-952	149	26	[	[	X
eurjchem-952	149	27	42	42	NUM
eurjchem-952	149	28	]	]	PUNCT
eurjchem-952	149	29	.	.	PUNCT
eurjchem-952	150	1	the	the	DET
eurjchem-952	150	2	shift	shift	NOUN
eurjchem-952	150	3	of	of	ADP
eurjchem-952	150	4	the	the	DET
eurjchem-952	150	5	π	π	PROPN
eurjchem-952	150	6	→	→	SYM
eurjchem-952	150	7	π	π	PROPN
eurjchem-952	150	8	*	*	NOUN
eurjchem-952	150	9	bands	band	NOUN
eurjchem-952	150	10	to	to	ADP
eurjchem-952	150	11	the	the	DET
eurjchem-952	150	12	longer	long	ADJ
eurjchem-952	150	13	wavelength	wavelength	NOUN
eurjchem-952	150	14	region	region	NOUN
eurjchem-952	150	15	is	be	AUX
eurjchem-952	150	16	the	the	DET
eurjchem-952	150	17	result	result	NOUN
eurjchem-952	150	18	of	of	ADP
eurjchem-952	150	19	the	the	DET
eurjchem-952	150	20	c	c	AUX
eurjchem-952	150	21	=	=	NOUN
eurjchem-952	150	22	s	s	PART
eurjchem-952	150	23	bond	bond	NOUN
eurjchem-952	150	24	being	be	AUX
eurjchem-952	150	25	weakened	weaken	VERB
eurjchem-952	150	26	and	and	CCONJ
eurjchem-952	150	27	conjugation	conjugation	NOUN
eurjchem-952	150	28	system	system	NOUN
eurjchem-952	150	29	being	be	AUX
eurjchem-952	150	30	enhanced	enhance	VERB
eurjchem-952	150	31	after	after	ADP
eurjchem-952	150	32	the	the	DET
eurjchem-952	150	33	formation	formation	NOUN
eurjchem-952	150	34	of	of	ADP
eurjchem-952	150	35	the	the	DET
eurjchem-952	150	36	complex	complex	NOUN
eurjchem-952	150	37	[	[	X
eurjchem-952	150	38	43	43	NUM
eurjchem-952	150	39	]	]	PUNCT
eurjchem-952	150	40	.	.	PUNCT
eurjchem-952	151	1	the	the	DET
eurjchem-952	151	2	magnetic	magnetic	ADJ
eurjchem-952	151	3	moment	moment	NOUN
eurjchem-952	151	4	of	of	ADP
eurjchem-952	151	5	mn(ii	mn(ii	NOUN
eurjchem-952	151	6	)	)	PUNCT
eurjchem-952	151	7	complex	complex	NOUN
eurjchem-952	151	8	(	(	PUNCT
eurjchem-952	151	9	6.01	6.01	NUM
eurjchem-952	151	10	b.m	b.m	NOUN
eurjchem-952	151	11	.	.	PUNCT
eurjchem-952	151	12	)	)	PUNCT
eurjchem-952	151	13	is	be	AUX
eurjchem-952	151	14	corresponding	correspond	VERB
eurjchem-952	151	15	to	to	ADP
eurjchem-952	151	16	five	five	NUM
eurjchem-952	151	17	unpaired	unpaired	ADJ
eurjchem-952	151	18	electrons	electron	NOUN
eurjchem-952	151	19	,	,	PUNCT
eurjchem-952	151	20	as	as	SCONJ
eurjchem-952	151	21	expected	expect	VERB
eurjchem-952	151	22	for	for	ADP
eurjchem-952	151	23	high	high	ADJ
eurjchem-952	151	24	spin	spin	NOUN
eurjchem-952	151	25	3d5	3d5	NUM
eurjchem-952	151	26	systems	system	NOUN
eurjchem-952	151	27	[	[	X
eurjchem-952	151	28	44	44	NUM
eurjchem-952	151	29	]	]	PUNCT
eurjchem-952	151	30	.	.	PUNCT
eurjchem-952	152	1	the	the	DET
eurjchem-952	152	2	electronic	electronic	ADJ
eurjchem-952	152	3	spectrum	spectrum	NOUN
eurjchem-952	152	4	of	of	ADP
eurjchem-952	152	5	this	this	DET
eurjchem-952	152	6	complex	complex	ADJ
eurjchem-952	152	7	show	show	VERB
eurjchem-952	152	8	two	two	NUM
eurjchem-952	152	9	bands	band	NOUN
eurjchem-952	152	10	at	at	ADP
eurjchem-952	152	11	20850	20850	NUM
eurjchem-952	152	12	and	and	CCONJ
eurjchem-952	152	13	24120	24120	NUM
eurjchem-952	152	14	cm‐1	cm‐1	NOUN
eurjchem-952	152	15	attributable	attributable	ADJ
eurjchem-952	152	16	to	to	ADP
eurjchem-952	152	17	6a1	6a1	NUM
eurjchem-952	152	18	g	g	NOUN
eurjchem-952	152	19	→	→	SYM
eurjchem-952	152	20	6t1g(g	6t1g(g	NUM
eurjchem-952	152	21	)	)	PUNCT
eurjchem-952	152	22	and	and	CCONJ
eurjchem-952	152	23	6a1	6a1	NUM
eurjchem-952	152	24	g	g	NOUN
eurjchem-952	152	25	→	→	SYM
eurjchem-952	152	26	6t2g(g	6t2g(g	NUM
eurjchem-952	152	27	)	)	PUNCT
eurjchem-952	152	28	,	,	PUNCT
eurjchem-952	152	29	respectively	respectively	ADV
eurjchem-952	152	30	,	,	PUNCT
eurjchem-952	152	31	suggesting	suggest	VERB
eurjchem-952	152	32	an	an	DET
eurjchem-952	152	33	octahedral	octahedral	ADJ
eurjchem-952	152	34	structure	structure	NOUN
eurjchem-952	152	35	[	[	X
eurjchem-952	152	36	44	44	NUM
eurjchem-952	152	37	]	]	PUNCT
eurjchem-952	152	38	.	.	PUNCT
eurjchem-952	153	1	the	the	DET
eurjchem-952	153	2	co(ii	co(ii	PROPN
eurjchem-952	153	3	)	)	PUNCT
eurjchem-952	153	4	complexes	complex	NOUN
eurjchem-952	153	5	generally	generally	ADV
eurjchem-952	153	6	give	give	VERB
eurjchem-952	153	7	rise	rise	NOUN
eurjchem-952	153	8	to	to	ADP
eurjchem-952	153	9	three	three	NUM
eurjchem-952	153	10	absorption	absorption	NOUN
eurjchem-952	153	11	bands	band	NOUN
eurjchem-952	153	12	in	in	ADP
eurjchem-952	153	13	the	the	DET
eurjchem-952	153	14	visible	visible	ADJ
eurjchem-952	153	15	region	region	NOUN
eurjchem-952	153	16	under	under	ADP
eurjchem-952	153	17	the	the	DET
eurjchem-952	153	18	influence	influence	NOUN
eurjchem-952	153	19	of	of	ADP
eurjchem-952	153	20	the	the	DET
eurjchem-952	153	21	octahedral	octahedral	ADJ
eurjchem-952	153	22	field	field	NOUN
eurjchem-952	153	23	by	by	ADP
eurjchem-952	153	24	the	the	DET
eurjchem-952	153	25	excitation	excitation	NOUN
eurjchem-952	153	26	of	of	ADP
eurjchem-952	153	27	the	the	DET
eurjchem-952	153	28	electron	electron	NOUN
eurjchem-952	153	29	from	from	ADP
eurjchem-952	153	30	the	the	DET
eurjchem-952	153	31	ground	ground	NOUN
eurjchem-952	153	32	state	state	NOUN
eurjchem-952	153	33	4t1	4t1	NUM
eurjchem-952	153	34	g	g	NOUN
eurjchem-952	153	35	(	(	PUNCT
eurjchem-952	153	36	f	f	NOUN
eurjchem-952	153	37	)	)	PUNCT
eurjchem-952	153	38	to	to	ADP
eurjchem-952	153	39	the	the	DET
eurjchem-952	153	40	excited	excited	ADJ
eurjchem-952	153	41	states	state	NOUN
eurjchem-952	154	1	4t2	4t2	NUM
eurjchem-952	154	2	g	g	NOUN
eurjchem-952	154	3	(	(	PUNCT
eurjchem-952	154	4	f	f	PROPN
eurjchem-952	154	5	)	)	PUNCT
eurjchem-952	154	6	,	,	PUNCT
eurjchem-952	154	7	4a2	4a2	NUM
eurjchem-952	154	8	g	g	NOUN
eurjchem-952	154	9	(	(	PUNCT
eurjchem-952	154	10	f	f	NOUN
eurjchem-952	154	11	)	)	PUNCT
eurjchem-952	154	12	and	and	CCONJ
eurjchem-952	154	13	4t1	4t1	NUM
eurjchem-952	154	14	g	g	NOUN
eurjchem-952	154	15	(	(	PUNCT
eurjchem-952	154	16	p	p	NOUN
eurjchem-952	154	17	)	)	PUNCT
eurjchem-952	154	18	.	.	PUNCT
eurjchem-952	155	1	in	in	ADP
eurjchem-952	155	2	the	the	DET
eurjchem-952	155	3	co(ii	co(ii	ADJ
eurjchem-952	155	4	)	)	PUNCT
eurjchem-952	155	5	complex	complex	NOUN
eurjchem-952	155	6	,	,	PUNCT
eurjchem-952	155	7	only	only	ADV
eurjchem-952	155	8	two	two	NUM
eurjchem-952	155	9	bands	band	NOUN
eurjchem-952	155	10	are	be	AUX
eurjchem-952	155	11	observed	observe	VERB
eurjchem-952	155	12	at	at	ADP
eurjchem-952	155	13	9935	9935	NUM
eurjchem-952	155	14	cm–1	cm–1	PROPN
eurjchem-952	155	15	4t1g(f	4t1g(f	NUM
eurjchem-952	155	16	)	)	PUNCT
eurjchem-952	156	1	→	→	SYM
eurjchem-952	156	2	4t2g(f	4t2g(f	NUM
eurjchem-952	156	3	)	)	PUNCT
eurjchem-952	156	4	(	(	PUNCT
eurjchem-952	156	5	1	1	PROPN
eurjchem-952	156	6	)	)	PUNCT
eurjchem-952	156	7	and	and	CCONJ
eurjchem-952	156	8	20,423	20,423	NUM
eurjchem-952	156	9	cm–1	cm–1	NOUN
eurjchem-952	156	10	4t1g(f	4t1g(f	NUM
eurjchem-952	156	11	)	)	PUNCT
eurjchem-952	156	12	→	→	SYM
eurjchem-952	156	13	4t1g(p	4t1g(p	NUM
eurjchem-952	156	14	)	)	PUNCT
eurjchem-952	156	15	(	(	PUNCT
eurjchem-952	156	16	3	3	PROPN
eurjchem-952	156	17	)	)	PUNCT
eurjchem-952	156	18	as	as	SCONJ
eurjchem-952	156	19	reported	report	VERB
eurjchem-952	156	20	in	in	ADP
eurjchem-952	156	21	many	many	ADJ
eurjchem-952	156	22	octahedral	octahedral	ADJ
eurjchem-952	156	23	cobalt(ii	cobalt(ii	ADJ
eurjchem-952	156	24	)	)	PUNCT
eurjchem-952	156	25	complexes	complex	NOUN
eurjchem-952	156	26	[	[	X
eurjchem-952	156	27	45,46	45,46	NOUN
eurjchem-952	156	28	]	]	PUNCT
eurjchem-952	156	29	.	.	PUNCT
eurjchem-952	157	1	the	the	DET
eurjchem-952	157	2	ν2	ν2	PROPN
eurjchem-952	157	3	transition	transition	NOUN
eurjchem-952	157	4	was	be	AUX
eurjchem-952	157	5	not	not	PART
eurjchem-952	157	6	observed	observe	VERB
eurjchem-952	157	7	due	due	ADJ
eurjchem-952	157	8	to	to	ADP
eurjchem-952	157	9	very	very	ADV
eurjchem-952	157	10	weak	weak	ADJ
eurjchem-952	157	11	intensity	intensity	NOUN
eurjchem-952	157	12	.	.	PUNCT
eurjchem-952	158	1	the	the	DET
eurjchem-952	158	2	value	value	NOUN
eurjchem-952	158	3	of	of	ADP
eurjchem-952	158	4	the	the	DET
eurjchem-952	158	5	magnetic	magnetic	ADJ
eurjchem-952	158	6	moment	moment	NOUN
eurjchem-952	158	7	4.71	4.71	NUM
eurjchem-952	158	8	b.m	b.m	PROPN
eurjchem-952	158	9	.	.	PUNCT
eurjchem-952	159	1	(	(	PUNCT
eurjchem-952	159	2	normal	normal	ADJ
eurjchem-952	159	3	range	range	NOUN
eurjchem-952	159	4	for	for	ADP
eurjchem-952	159	5	octahedral	octahedral	ADJ
eurjchem-952	159	6	co(ii	co(ii	PROPN
eurjchem-952	159	7	)	)	PUNCT
eurjchem-952	159	8	complexes	complex	NOUN
eurjchem-952	159	9	is	be	AUX
eurjchem-952	159	10	4.3‐5.2	4.3‐5.2	NUM
eurjchem-952	159	11	b.m	b.m	PROPN
eurjchem-952	159	12	.	.	PUNCT
eurjchem-952	159	13	)	)	PUNCT
eurjchem-952	160	1	is	be	AUX
eurjchem-952	160	2	additional	additional	ADJ
eurjchem-952	160	3	evidence	evidence	NOUN
eurjchem-952	160	4	for	for	ADP
eurjchem-952	160	5	an	an	DET
eurjchem-952	160	6	octahedral	octahedral	ADJ
eurjchem-952	160	7	geometry	geometry	NOUN
eurjchem-952	160	8	around	around	ADP
eurjchem-952	160	9	the	the	DET
eurjchem-952	160	10	co(ii	co(ii	PROPN
eurjchem-952	160	11	)	)	PUNCT
eurjchem-952	160	12	ion	ion	NOUN
eurjchem-952	160	13	[	[	X
eurjchem-952	160	14	47	47	NUM
eurjchem-952	160	15	]	]	PUNCT
eurjchem-952	160	16	.	.	PUNCT
eurjchem-952	161	1	the	the	DET
eurjchem-952	161	2	copper(ii	copper(ii	NOUN
eurjchem-952	161	3	)	)	PUNCT
eurjchem-952	161	4	complex	complex	ADJ
eurjchem-952	161	5	exhibit	exhibit	NOUN
eurjchem-952	161	6	magnetic	magnetic	ADJ
eurjchem-952	161	7	moment	moment	NOUN
eurjchem-952	161	8	of	of	ADP
eurjchem-952	161	9	1.82	1.82	NUM
eurjchem-952	161	10	b.m	b.m	NOUN
eurjchem-952	161	11	.	.	PUNCT
eurjchem-952	161	12	at	at	ADP
eurjchem-952	161	13	room	room	NOUN
eurjchem-952	161	14	temperature	temperature	NOUN
eurjchem-952	161	15	.	.	PUNCT
eurjchem-952	162	1	this	this	DET
eurjchem-952	162	2	value	value	NOUN
eurjchem-952	162	3	is	be	AUX
eurjchem-952	162	4	quite	quite	ADV
eurjchem-952	162	5	close	close	ADJ
eurjchem-952	162	6	to	to	ADP
eurjchem-952	162	7	the	the	DET
eurjchem-952	162	8	spin	spin	NOUN
eurjchem-952	162	9	allowed	allow	VERB
eurjchem-952	162	10	values	value	NOUN
eurjchem-952	162	11	expected	expect	VERB
eurjchem-952	162	12	for	for	ADP
eurjchem-952	162	13	a	a	DET
eurjchem-952	162	14	s	s	NOUN
eurjchem-952	162	15	=	=	SYM
eurjchem-952	162	16	1/2	1/2	NUM
eurjchem-952	162	17	system	system	NOUN
eurjchem-952	162	18	and	and	CCONJ
eurjchem-952	162	19	may	may	AUX
eurjchem-952	162	20	be	be	AUX
eurjchem-952	162	21	indicative	indicative	ADJ
eurjchem-952	162	22	of	of	ADP
eurjchem-952	162	23	a	a	DET
eurjchem-952	162	24	distorted	distorted	ADJ
eurjchem-952	162	25	octahedral	octahedral	ADJ
eurjchem-952	162	26	geometry	geometry	NOUN
eurjchem-952	162	27	around	around	ADP
eurjchem-952	162	28	copper(ii	copper(ii	PROPN
eurjchem-952	162	29	)	)	PUNCT
eurjchem-952	162	30	ion	ion	NOUN
eurjchem-952	162	31	.	.	PUNCT
eurjchem-952	163	1	this	this	DET
eurjchem-952	163	2	copper(ii	copper(ii	NOUN
eurjchem-952	163	3	)	)	PUNCT
eurjchem-952	163	4	complex	complex	NOUN
eurjchem-952	163	5	displays	display	VERB
eurjchem-952	163	6	a	a	DET
eurjchem-952	163	7	broad	broad	ADJ
eurjchem-952	163	8	band	band	NOUN
eurjchem-952	163	9	at	at	ADP
eurjchem-952	163	10	14585	14585	NUM
eurjchem-952	163	11	cm‐1	cm‐1	NOUN
eurjchem-952	163	12	due	due	ADP
eurjchem-952	163	13	to	to	ADP
eurjchem-952	163	14	2b1	2b1	NUM
eurjchem-952	163	15	g	g	NOUN
eurjchem-952	163	16	→	→	SYM
eurjchem-952	163	17	2eg	2eg	NOUN
eurjchem-952	163	18	assigned	assign	VERB
eurjchem-952	163	19	to	to	ADP
eurjchem-952	163	20	d‐d	d‐d	PRON
eurjchem-952	163	21	transitions	transition	NOUN
eurjchem-952	163	22	of	of	ADP
eurjchem-952	163	23	a	a	DET
eurjchem-952	163	24	distorted	distorted	ADJ
eurjchem-952	163	25	octahedral	octahedral	ADJ
eurjchem-952	163	26	environment	environment	NOUN
eurjchem-952	163	27	[	[	X
eurjchem-952	163	28	48,49	48,49	X
eurjchem-952	163	29	]	]	PUNCT
eurjchem-952	163	30	.	.	PUNCT
eurjchem-952	164	1	the	the	DET
eurjchem-952	164	2	electronic	electronic	ADJ
eurjchem-952	164	3	spectra	spectra	NOUN
eurjchem-952	164	4	of	of	ADP
eurjchem-952	164	5	the	the	DET
eurjchem-952	164	6	nickel(ii	nickel(ii	NOUN
eurjchem-952	164	7	)	)	PUNCT
eurjchem-952	164	8	complexes	complex	NOUN
eurjchem-952	164	9	exhibited	exhibit	VERB
eurjchem-952	164	10	absorption	absorption	NOUN
eurjchem-952	164	11	bands	band	NOUN
eurjchem-952	164	12	at	at	ADP
eurjchem-952	164	13	10675	10675	NUM
eurjchem-952	164	14	and	and	CCONJ
eurjchem-952	164	15	17540	17540	NUM
eurjchem-952	164	16	cm‐1	cm‐1	NOUN
eurjchem-952	164	17	,	,	PUNCT
eurjchem-952	164	18	attributable	attributable	ADJ
eurjchem-952	164	19	to	to	ADP
eurjchem-952	164	20	3a2	3a2	NUM
eurjchem-952	164	21	g	g	NOUN
eurjchem-952	164	22	→	→	SYM
eurjchem-952	164	23	3t1g(f	3t1g(f	NUM
eurjchem-952	164	24	)	)	PUNCT
eurjchem-952	164	25	and	and	CCONJ
eurjchem-952	164	26	3a2	3a2	NUM
eurjchem-952	164	27	g	g	NOUN
eurjchem-952	164	28	→	→	SYM
eurjchem-952	164	29	3t1g(p	3t1g(p	NUM
eurjchem-952	164	30	)	)	PUNCT
eurjchem-952	164	31	,	,	PUNCT
eurjchem-952	164	32	transitions	transition	NOUN
eurjchem-952	164	33	,	,	PUNCT
eurjchem-952	164	34	respectively	respectively	ADV
eurjchem-952	164	35	,	,	PUNCT
eurjchem-952	164	36	in	in	ADP
eurjchem-952	164	37	an	an	DET
eurjchem-952	164	38	octahedral	octahedral	ADJ
eurjchem-952	164	39	geometry	geometry	NOUN
eurjchem-952	164	40	[	[	X
eurjchem-952	164	41	45,49	45,49	NOUN
eurjchem-952	164	42	]	]	PUNCT
eurjchem-952	164	43	.	.	PUNCT
eurjchem-952	165	1	also	also	ADV
eurjchem-952	165	2	,	,	PUNCT
eurjchem-952	165	3	the	the	DET
eurjchem-952	165	4	value	value	NOUN
eurjchem-952	165	5	of	of	ADP
eurjchem-952	165	6	the	the	DET
eurjchem-952	165	7	magnetic	magnetic	ADJ
eurjchem-952	165	8	moment	moment	NOUN
eurjchem-952	165	9	(	(	PUNCT
eurjchem-952	165	10	3.21	3.21	NUM
eurjchem-952	165	11	b.m	b.m	PROPN
eurjchem-952	165	12	.	.	PROPN
eurjchem-952	165	13	)	)	PUNCT
eurjchem-952	165	14	may	may	AUX
eurjchem-952	165	15	be	be	AUX
eurjchem-952	165	16	taken	take	VERB
eurjchem-952	165	17	as	as	ADP
eurjchem-952	165	18	additional	additional	ADJ
eurjchem-952	165	19	evidence	evidence	NOUN
eurjchem-952	165	20	for	for	ADP
eurjchem-952	165	21	their	their	PRON
eurjchem-952	165	22	octahedral	octahedral	ADJ
eurjchem-952	165	23	structure	structure	NOUN
eurjchem-952	165	24	.	.	PUNCT
eurjchem-952	166	1	on	on	ADP
eurjchem-952	166	2	the	the	DET
eurjchem-952	166	3	basis	basis	NOUN
eurjchem-952	166	4	of	of	ADP
eurjchem-952	166	5	the	the	DET
eurjchem-952	166	6	above	above	ADJ
eurjchem-952	166	7	observations	observation	NOUN
eurjchem-952	166	8	,	,	PUNCT
eurjchem-952	166	9	it	it	PRON
eurjchem-952	166	10	is	be	AUX
eurjchem-952	166	11	tentatively	tentatively	ADV
eurjchem-952	166	12	suggested	suggest	VERB
eurjchem-952	166	13	that	that	SCONJ
eurjchem-952	166	14	all	all	PRON
eurjchem-952	166	15	of	of	ADP
eurjchem-952	166	16	the	the	DET
eurjchem-952	166	17	complexes	complex	NOUN
eurjchem-952	166	18	show	show	VERB
eurjchem-952	166	19	an	an	DET
eurjchem-952	166	20	octahedral	octahedral	ADJ
eurjchem-952	166	21	geometry	geometry	NOUN
eurjchem-952	166	22	in	in	ADP
eurjchem-952	166	23	which	which	PRON
eurjchem-952	166	24	the	the	DET
eurjchem-952	166	25	mpapt	mpapt	ADJ
eurjchem-952	166	26	thiosemicarbazone	thiosemicarbazone	PROPN
eurjchem-952	166	27	ligand	ligand	NOUN
eurjchem-952	166	28	act	act	NOUN
eurjchem-952	166	29	as	as	ADP
eurjchem-952	166	30	monoanion	monoanion	NOUN
eurjchem-952	166	31	tridentate	tridentate	NOUN
eurjchem-952	166	32	ligand	ligand	NOUN
eurjchem-952	166	33	,	,	PUNCT
eurjchem-952	166	34	1,10‐phen	1,10‐phen	NOUN
eurjchem-952	166	35	acts	act	VERB
eurjchem-952	166	36	as	as	ADP
eurjchem-952	166	37	bidentate	bidentate	NOUN
eurjchem-952	166	38	ligand	ligand	NOUN
eurjchem-952	166	39	and	and	CCONJ
eurjchem-952	166	40	in	in	ADP
eurjchem-952	166	41	addition	addition	NOUN
eurjchem-952	166	42	to	to	ADP
eurjchem-952	166	43	the	the	DET
eurjchem-952	166	44	monodentate	monodentate	ADJ
eurjchem-952	166	45	chloride	chloride	NOUN
eurjchem-952	166	46	ion	ion	NOUN
eurjchem-952	166	47	.	.	PUNCT
eurjchem-952	167	1	these	these	PRON
eurjchem-952	167	2	possibly	possibly	ADV
eurjchem-952	167	3	accommodate	accommodate	VERB
eurjchem-952	167	4	themselves	themselves	PRON
eurjchem-952	167	5	around	around	ADP
eurjchem-952	167	6	the	the	DET
eurjchem-952	167	7	metal	metal	NOUN
eurjchem-952	167	8	atom	atom	NOUN
eurjchem-952	167	9	in	in	ADP
eurjchem-952	167	10	such	such	DET
eurjchem-952	167	11	a	a	DET
eurjchem-952	167	12	way	way	NOUN
eurjchem-952	167	13	that	that	PRON
eurjchem-952	167	14	a	a	DET
eurjchem-952	167	15	stable	stable	ADJ
eurjchem-952	167	16	chelate	chelate	NOUN
eurjchem-952	167	17	ring	ring	NOUN
eurjchem-952	167	18	is	be	AUX
eurjchem-952	167	19	formed	form	VERB
eurjchem-952	167	20	giving	give	VERB
eurjchem-952	167	21	,	,	PUNCT
eurjchem-952	167	22	in	in	ADP
eurjchem-952	167	23	turn	turn	NOUN
eurjchem-952	167	24	,	,	PUNCT
eurjchem-952	167	25	stability	stability	NOUN
eurjchem-952	167	26	to	to	ADP
eurjchem-952	167	27	the	the	DET
eurjchem-952	167	28	metal	metal	NOUN
eurjchem-952	167	29	complexes	complex	NOUN
eurjchem-952	167	30	.	.	PUNCT
eurjchem-952	168	1	3.3	3.3	NUM
eurjchem-952	168	2	.	.	PUNCT
eurjchem-952	169	1	esr	esr	PROPN
eurjchem-952	169	2	spectrum	spectrum	NOUN
eurjchem-952	169	3	of	of	ADP
eurjchem-952	169	4	[	[	X
eurjchem-952	169	5	cu(mpapt)(1,0‐phen)cl	cu(mpapt)(1,0‐phen)cl	NOUN
eurjchem-952	169	6	]	]	X
eurjchem-952	169	7	complex	complex	ADJ
eurjchem-952	169	8	esr	esr	PROPN
eurjchem-952	169	9	spectroscopy	spectroscopy	NOUN
eurjchem-952	169	10	is	be	AUX
eurjchem-952	169	11	a	a	DET
eurjchem-952	169	12	direct	direct	ADJ
eurjchem-952	169	13	measurement	measurement	NOUN
eurjchem-952	169	14	of	of	ADP
eurjchem-952	169	15	electron	electron	NOUN
eurjchem-952	169	16	spin	spin	NOUN
eurjchem-952	169	17	when	when	SCONJ
eurjchem-952	169	18	there	there	PRON
eurjchem-952	169	19	are	be	VERB
eurjchem-952	169	20	unpaired	unpaired	ADJ
eurjchem-952	169	21	electrons	electron	NOUN
eurjchem-952	169	22	within	within	ADP
eurjchem-952	169	23	a	a	DET
eurjchem-952	169	24	chemical	chemical	NOUN
eurjchem-952	169	25	structure	structure	NOUN
eurjchem-952	169	26	and	and	CCONJ
eurjchem-952	169	27	thus	thus	ADV
eurjchem-952	169	28	provides	provide	VERB
eurjchem-952	169	29	a	a	DET
eurjchem-952	169	30	way	way	NOUN
eurjchem-952	169	31	to	to	PART
eurjchem-952	169	32	investigate	investigate	VERB
eurjchem-952	169	33	the	the	DET
eurjchem-952	169	34	electronic	electronic	ADJ
eurjchem-952	169	35	spin	spin	NOUN
eurjchem-952	169	36	state	state	NOUN
eurjchem-952	169	37	and	and	CCONJ
eurjchem-952	169	38	oxidation	oxidation	NOUN
eurjchem-952	169	39	state	state	NOUN
eurjchem-952	169	40	of	of	ADP
eurjchem-952	169	41	the	the	DET
eurjchem-952	169	42	coordinated	coordinate	VERB
eurjchem-952	169	43	metal	metal	NOUN
eurjchem-952	169	44	ion	ion	NOUN
eurjchem-952	169	45	.	.	PUNCT
eurjchem-952	170	1	also	also	ADV
eurjchem-952	170	2	,	,	PUNCT
eurjchem-952	170	3	the	the	DET
eurjchem-952	170	4	esr	esr	PROPN
eurjchem-952	170	5	spectra	spectra	NOUN
eurjchem-952	170	6	of	of	ADP
eurjchem-952	170	7	the	the	DET
eurjchem-952	170	8	complexes	complex	NOUN
eurjchem-952	170	9	is	be	AUX
eurjchem-952	170	10	important	important	ADJ
eurjchem-952	170	11	in	in	ADP
eurjchem-952	170	12	studying	study	VERB
eurjchem-952	170	13	the	the	DET
eurjchem-952	170	14	metal	metal	NOUN
eurjchem-952	170	15	ion	ion	NOUN
eurjchem-952	170	16	environment	environment	NOUN
eurjchem-952	170	17	in	in	ADP
eurjchem-952	170	18	the	the	DET
eurjchem-952	170	19	complexes	complex	NOUN
eurjchem-952	170	20	,	,	PUNCT
eurjchem-952	170	21	such	such	ADJ
eurjchem-952	170	22	as	as	ADP
eurjchem-952	170	23	geometry	geometry	NOUN
eurjchem-952	170	24	,	,	PUNCT
eurjchem-952	170	25	nature	nature	NOUN
eurjchem-952	170	26	of	of	ADP
eurjchem-952	170	27	ligation	ligation	NOUN
eurjchem-952	170	28	sites	site	NOUN
eurjchem-952	170	29	from	from	ADP
eurjchem-952	170	30	the	the	DET
eurjchem-952	170	31	ligand	ligand	NOUN
eurjchem-952	170	32	to	to	ADP
eurjchem-952	170	33	the	the	DET
eurjchem-952	170	34	metal	metal	NOUN
eurjchem-952	170	35	,	,	PUNCT
eurjchem-952	170	36	and	and	CCONJ
eurjchem-952	170	37	the	the	DET
eurjchem-952	170	38	degree	degree	NOUN
eurjchem-952	170	39	of	of	ADP
eurjchem-952	170	40	covalence	covalence	NOUN
eurjchem-952	170	41	of	of	ADP
eurjchem-952	170	42	the	the	DET
eurjchem-952	170	43	metal‐ligand	metal‐ligand	NOUN
eurjchem-952	170	44	bonds	bond	NOUN
eurjchem-952	170	45	.	.	PUNCT
eurjchem-952	171	1	the	the	DET
eurjchem-952	171	2	room	room	NOUN
eurjchem-952	171	3	temperature	temperature	NOUN
eurjchem-952	171	4	powder	powder	NOUN
eurjchem-952	171	5	esr	esr	PROPN
eurjchem-952	171	6	spectrum	spectrum	NOUN
eurjchem-952	171	7	of	of	ADP
eurjchem-952	171	8	[	[	X
eurjchem-952	171	9	cu(mpapt)(1,10‐phen)cl	cu(mpapt)(1,10‐phen)cl	NOUN
eurjchem-952	171	10	]	]	PUNCT
eurjchem-952	171	11	exhibits	exhibit	VERB
eurjchem-952	171	12	an	an	DET
eurjchem-952	171	13	axial	axial	ADJ
eurjchem-952	171	14	signal	signal	NOUN
eurjchem-952	171	15	with	with	ADP
eurjchem-952	171	16	two	two	NUM
eurjchem-952	171	17	g	g	NOUN
eurjchem-952	171	18	values	value	NOUN
eurjchem-952	171	19	(	(	PUNCT
eurjchem-952	171	20	g||	g||	NOUN
eurjchem-952	171	21	=	=	NOUN
eurjchem-952	171	22	2.140	2.140	NUM
eurjchem-952	171	23	,	,	PUNCT
eurjchem-952	171	24	g	g	NOUN
eurjchem-952	171	25	┴	┴	NOUN
eurjchem-952	171	26	=	=	PUNCT
eurjchem-952	171	27	2.031	2.031	NUM
eurjchem-952	171	28	)	)	PUNCT
eurjchem-952	171	29	.	.	PUNCT
eurjchem-952	172	1	the	the	DET
eurjchem-952	172	2	g||	g||	NOUN
eurjchem-952	172	3	and	and	CCONJ
eurjchem-952	172	4	g	g	ADP
eurjchem-952	172	5	┴	┴	NOUN
eurjchem-952	172	6	values	value	NOUN
eurjchem-952	172	7	are	be	AUX
eurjchem-952	172	8	computed	compute	VERB
eurjchem-952	172	9	from	from	ADP
eurjchem-952	172	10	the	the	DET
eurjchem-952	172	11	spectrum	spectrum	NOUN
eurjchem-952	172	12	using	use	VERB
eurjchem-952	172	13	dpph	dpph	PROPN
eurjchem-952	172	14	free	free	ADJ
eurjchem-952	172	15	radical	radical	ADJ
eurjchem-952	172	16	as	as	ADP
eurjchem-952	172	17	"	"	PUNCT
eurjchem-952	172	18	g	g	NOUN
eurjchem-952	172	19	"	"	PUNCT
eurjchem-952	172	20	marker	marker	NOUN
eurjchem-952	172	21	.	.	PUNCT
eurjchem-952	173	1	the	the	DET
eurjchem-952	173	2	ordering	ordering	NOUN
eurjchem-952	173	3	of	of	ADP
eurjchem-952	173	4	g	g	NOUN
eurjchem-952	173	5	values	value	NOUN
eurjchem-952	173	6	(	(	PUNCT
eurjchem-952	173	7	g||	g||	NOUN
eurjchem-952	173	8	>	>	X
eurjchem-952	173	9	g	g	PROPN
eurjchem-952	173	10	┴	┴	NOUN
eurjchem-952	173	11	>	>	X
eurjchem-952	173	12	2.003	2.003	NUM
eurjchem-952	173	13	)	)	PUNCT
eurjchem-952	173	14	observed	observe	VERB
eurjchem-952	173	15	for	for	ADP
eurjchem-952	173	16	copper(ii	copper(ii	NOUN
eurjchem-952	173	17	)	)	PUNCT
eurjchem-952	173	18	complex	complex	NOUN
eurjchem-952	173	19	indicates	indicate	VERB
eurjchem-952	173	20	that	that	SCONJ
eurjchem-952	173	21	the	the	DET
eurjchem-952	173	22	unpaired	unpaired	ADJ
eurjchem-952	173	23	electron	electron	NOUN
eurjchem-952	173	24	is	be	AUX
eurjchem-952	173	25	localized	localize	VERB
eurjchem-952	173	26	in	in	ADP
eurjchem-952	173	27	(	(	PUNCT
eurjchem-952	173	28	dx2‐y2	dx2‐y2	NOUN
eurjchem-952	173	29	)	)	PUNCT
eurjchem-952	173	30	orbital	orbital	NOUN
eurjchem-952	174	1	[	[	X
eurjchem-952	174	2	50	50	NUM
eurjchem-952	174	3	]	]	PUNCT
eurjchem-952	174	4	of	of	ADP
eurjchem-952	174	5	the	the	DET
eurjchem-952	174	6	cu(ii	cu(ii	PROPN
eurjchem-952	174	7	)	)	PUNCT
eurjchem-952	174	8	ion	ion	NOUN
eurjchem-952	174	9	(	(	PUNCT
eurjchem-952	174	10	spectroscopic	spectroscopic	ADJ
eurjchem-952	174	11	state	state	NOUN
eurjchem-952	174	12	2b1	2b1	NUM
eurjchem-952	174	13	g	g	NOUN
eurjchem-952	174	14	)	)	PUNCT
eurjchem-952	174	15	and	and	CCONJ
eurjchem-952	174	16	the	the	DET
eurjchem-952	174	17	spectral	spectral	ADJ
eurjchem-952	174	18	features	feature	NOUN
eurjchem-952	174	19	are	be	AUX
eurjchem-952	174	20	characteristics	characteristic	NOUN
eurjchem-952	174	21	of	of	ADP
eurjchem-952	174	22	axial	axial	ADJ
eurjchem-952	174	23	symmetry	symmetry	NOUN
eurjchem-952	175	1	[	[	X
eurjchem-952	175	2	51	51	NUM
eurjchem-952	175	3	]	]	PUNCT
eurjchem-952	175	4	.	.	PUNCT
eurjchem-952	176	1	g||	g||	NOUN
eurjchem-952	176	2	is	be	AUX
eurjchem-952	176	3	a	a	DET
eurjchem-952	176	4	moderately	moderately	ADV
eurjchem-952	176	5	sensitive	sensitive	ADJ
eurjchem-952	176	6	function	function	NOUN
eurjchem-952	176	7	for	for	ADP
eurjchem-952	176	8	m‐l	m‐l	PROPN
eurjchem-952	176	9	bond	bond	NOUN
eurjchem-952	176	10	nature	nature	NOUN
eurjchem-952	176	11	.	.	PUNCT
eurjchem-952	177	1	kivelson	kivelson	PROPN
eurjchem-952	177	2	and	and	CCONJ
eurjchem-952	177	3	neiman	neiman	PROPN
eurjchem-952	178	1	[	[	X
eurjchem-952	178	2	40	40	NUM
eurjchem-952	178	3	]	]	PUNCT
eurjchem-952	178	4	have	have	AUX
eurjchem-952	178	5	reported	report	VERB
eurjchem-952	178	6	the	the	DET
eurjchem-952	178	7	g||	g||	NOUN
eurjchem-952	178	8	value	value	NOUN
eurjchem-952	178	9	<	<	X
eurjchem-952	178	10	2.3	2.3	NUM
eurjchem-952	178	11	for	for	ADP
eurjchem-952	178	12	covalent	covalent	ADJ
eurjchem-952	178	13	character	character	NOUN
eurjchem-952	178	14	of	of	ADP
eurjchem-952	178	15	metal‐ligand	metal‐ligand	PROPN
eurjchem-952	178	16	bond	bond	NOUN
eurjchem-952	178	17	and	and	CCONJ
eurjchem-952	178	18	g||	g||	NOUN
eurjchem-952	178	19	value	value	NOUN
eurjchem-952	178	20	>	>	X
eurjchem-952	178	21	2.3	2.3	NUM
eurjchem-952	178	22	for	for	ADP
eurjchem-952	178	23	ionic	ionic	ADJ
eurjchem-952	178	24	character	character	NOUN
eurjchem-952	178	25	.	.	PUNCT
eurjchem-952	179	1	by	by	ADP
eurjchem-952	179	2	applying	apply	VERB
eurjchem-952	179	3	this	this	DET
eurjchem-952	179	4	criterion	criterion	NOUN
eurjchem-952	179	5	,	,	PUNCT
eurjchem-952	179	6	the	the	DET
eurjchem-952	179	7	g||	g||	NOUN
eurjchem-952	179	8	value	value	NOUN
eurjchem-952	179	9	is	be	AUX
eurjchem-952	179	10	less	less	ADJ
eurjchem-952	179	11	than	than	ADP
eurjchem-952	179	12	2.3	2.3	NUM
eurjchem-952	179	13	is	be	AUX
eurjchem-952	179	14	an	an	DET
eurjchem-952	179	15	indication	indication	NOUN
eurjchem-952	179	16	of	of	ADP
eurjchem-952	179	17	significant	significant	ADJ
eurjchem-952	179	18	covalent	covalent	NOUN
eurjchem-952	179	19	bonding	bonding	NOUN
eurjchem-952	179	20	in	in	ADP
eurjchem-952	179	21	copper(ii	copper(ii	NOUN
eurjchem-952	179	22	)	)	PUNCT
eurjchem-952	179	23	complex	complex	NOUN
eurjchem-952	179	24	.	.	PUNCT
eurjchem-952	180	1	based	base	VERB
eurjchem-952	180	2	on	on	ADP
eurjchem-952	180	3	elemental	elemental	ADJ
eurjchem-952	180	4	analysis	analysis	NOUN
eurjchem-952	180	5	,	,	PUNCT
eurjchem-952	180	6	ir	ir	INTJ
eurjchem-952	180	7	,	,	PUNCT
eurjchem-952	180	8	electronic	electronic	ADJ
eurjchem-952	180	9	spectra	spectra	NOUN
eurjchem-952	180	10	and	and	CCONJ
eurjchem-952	180	11	esr	esr	PROPN
eurjchem-952	180	12	data	data	PROPN
eurjchem-952	180	13	,	,	PUNCT
eurjchem-952	180	14	cu(ii	cu(ii	PROPN
eurjchem-952	180	15	)	)	PUNCT
eurjchem-952	180	16	complex	complex	NOUN
eurjchem-952	180	17	has	have	VERB
eurjchem-952	180	18	octahedral	octahedral	ADJ
eurjchem-952	180	19	structure	structure	NOUN
eurjchem-952	180	20	.	.	PUNCT
eurjchem-952	181	1	the	the	DET
eurjchem-952	181	2	geometric	geometric	ADJ
eurjchem-952	181	3	parameter	parameter	NOUN
eurjchem-952	181	4	g	g	NOUN
eurjchem-952	181	5	,	,	PUNCT
eurjchem-952	181	6	which	which	PRON
eurjchem-952	181	7	is	be	AUX
eurjchem-952	181	8	a	a	DET
eurjchem-952	181	9	measure	measure	NOUN
eurjchem-952	181	10	of	of	ADP
eurjchem-952	181	11	the	the	DET
eurjchem-952	181	12	exchange	exchange	NOUN
eurjchem-952	181	13	interaction	interaction	NOUN
eurjchem-952	181	14	between	between	ADP
eurjchem-952	181	15	copper	copper	NOUN
eurjchem-952	181	16	centers	center	NOUN
eurjchem-952	181	17	in	in	ADP
eurjchem-952	181	18	the	the	DET
eurjchem-952	181	19	polycrystalline	polycrystalline	ADJ
eurjchem-952	181	20	compound	compound	NOUN
eurjchem-952	181	21	,	,	PUNCT
eurjchem-952	181	22	is	be	AUX
eurjchem-952	181	23	calculated	calculate	VERB
eurjchem-952	181	24	using	use	VERB
eurjchem-952	181	25	hathway	hathway	NOUN
eurjchem-952	181	26	expression	expression	NOUN
eurjchem-952	181	27	(	(	PUNCT
eurjchem-952	181	28	g	g	NOUN
eurjchem-952	181	29	=	=	PUNCT
eurjchem-952	182	1	g||‐	g||‐	PROPN
eurjchem-952	182	2	2.0023	2.0023	NUM
eurjchem-952	182	3	/	/	SYM
eurjchem-952	182	4	g	g	PROPN
eurjchem-952	182	5	┴	┴	NOUN
eurjchem-952	182	6	‐2.0023	‐2.0023	NOUN
eurjchem-952	182	7	)	)	PUNCT
eurjchem-952	183	1	[	[	X
eurjchem-952	183	2	52	52	NUM
eurjchem-952	183	3	]	]	PUNCT
eurjchem-952	183	4	.	.	PUNCT
eurjchem-952	184	1	according	accord	VERB
eurjchem-952	184	2	to	to	ADP
eurjchem-952	184	3	hathway	hathway	PROPN
eurjchem-952	184	4	,	,	PUNCT
eurjchem-952	184	5	if	if	SCONJ
eurjchem-952	184	6	the	the	DET
eurjchem-952	184	7	value	value	NOUN
eurjchem-952	184	8	of	of	ADP
eurjchem-952	184	9	g	g	PROPN
eurjchem-952	184	10	>	>	X
eurjchem-952	184	11	4	4	NUM
eurjchem-952	184	12	,	,	PUNCT
eurjchem-952	184	13	the	the	DET
eurjchem-952	184	14	exchange	exchange	NOUN
eurjchem-952	184	15	interaction	interaction	NOUN
eurjchem-952	184	16	is	be	AUX
eurjchem-952	184	17	negligible	negligible	ADJ
eurjchem-952	184	18	in	in	ADP
eurjchem-952	184	19	solid	solid	ADJ
eurjchem-952	184	20	complexes	complex	NOUN
eurjchem-952	184	21	but	but	CCONJ
eurjchem-952	184	22	g	g	NOUN
eurjchem-952	184	23	<	<	X
eurjchem-952	184	24	4	4	NUM
eurjchem-952	184	25	indicates	indicate	VERB
eurjchem-952	184	26	considerable	considerable	ADJ
eurjchem-952	184	27	interaction	interaction	NOUN
eurjchem-952	184	28	in	in	ADP
eurjchem-952	184	29	solid	solid	ADJ
eurjchem-952	184	30	complexes	complex	NOUN
eurjchem-952	184	31	.	.	PUNCT
eurjchem-952	185	1	in	in	ADP
eurjchem-952	185	2	the	the	DET
eurjchem-952	185	3	cu(ii	cu(ii	PROPN
eurjchem-952	185	4	)	)	PUNCT
eurjchem-952	185	5	complex	complex	NOUN
eurjchem-952	185	6	reported	report	VERB
eurjchem-952	185	7	in	in	ADP
eurjchem-952	185	8	this	this	DET
eurjchem-952	185	9	paper	paper	NOUN
eurjchem-952	185	10	the	the	DET
eurjchem-952	185	11	g	g	PROPN
eurjchem-952	185	12	value	value	NOUN
eurjchem-952	185	13	(	(	PUNCT
eurjchem-952	185	14	4.797	4.797	NUM
eurjchem-952	185	15	)	)	PUNCT
eurjchem-952	185	16	>	>	X
eurjchem-952	185	17	4	4	NUM
eurjchem-952	185	18	,	,	PUNCT
eurjchem-952	185	19	suggesting	suggest	VERB
eurjchem-952	185	20	the	the	DET
eurjchem-952	185	21	absence	absence	NOUN
eurjchem-952	185	22	of	of	ADP
eurjchem-952	185	23	copper‐copper	copper‐copper	ADJ
eurjchem-952	185	24	exchange	exchange	NOUN
eurjchem-952	185	25	interactions	interaction	NOUN
eurjchem-952	185	26	in	in	ADP
eurjchem-952	185	27	the	the	DET
eurjchem-952	185	28	solid	solid	ADJ
eurjchem-952	185	29	state	state	NOUN
eurjchem-952	185	30	.	.	PUNCT
eurjchem-952	186	1	3.4	3.4	NUM
eurjchem-952	186	2	.	.	PUNCT
eurjchem-952	186	3	conductivity	conductivity	NOUN
eurjchem-952	186	4	measurements	measurement	NOUN
eurjchem-952	186	5	conductivity	conductivity	NOUN
eurjchem-952	186	6	measurements	measurement	NOUN
eurjchem-952	186	7	in	in	ADP
eurjchem-952	186	8	non‐aqueous	non‐aqueous	ADJ
eurjchem-952	186	9	solutions	solution	NOUN
eurjchem-952	186	10	have	have	AUX
eurjchem-952	186	11	frequently	frequently	ADV
eurjchem-952	186	12	been	be	AUX
eurjchem-952	186	13	used	use	VERB
eurjchem-952	186	14	in	in	ADP
eurjchem-952	186	15	structural	structural	ADJ
eurjchem-952	186	16	studies	study	NOUN
eurjchem-952	186	17	of	of	ADP
eurjchem-952	186	18	metal	metal	NOUN
eurjchem-952	186	19	chelates	chelate	NOUN
eurjchem-952	186	20	within	within	ADP
eurjchem-952	186	21	the	the	DET
eurjchem-952	186	22	limits	limit	NOUN
eurjchem-952	186	23	of	of	ADP
eurjchem-952	186	24	their	their	PRON
eurjchem-952	186	25	solubility	solubility	NOUN
eurjchem-952	186	26	.	.	PUNCT
eurjchem-952	187	1	these	these	DET
eurjchem-952	187	2	measurements	measurement	NOUN
eurjchem-952	187	3	were	be	AUX
eurjchem-952	187	4	provided	provide	VERB
eurjchem-952	187	5	a	a	DET
eurjchem-952	187	6	method	method	NOUN
eurjchem-952	187	7	for	for	ADP
eurjchem-952	187	8	testing	test	VERB
eurjchem-952	187	9	the	the	DET
eurjchem-952	187	10	degree	degree	NOUN
eurjchem-952	187	11	of	of	ADP
eurjchem-952	187	12	ionization	ionization	NOUN
eurjchem-952	187	13	of	of	ADP
eurjchem-952	187	14	the	the	DET
eurjchem-952	187	15	complexes	complex	NOUN
eurjchem-952	187	16	,	,	PUNCT
eurjchem-952	187	17	the	the	DET
eurjchem-952	187	18	molar	molar	ADJ
eurjchem-952	187	19	ions	ion	NOUN
eurjchem-952	187	20	that	that	PRON
eurjchem-952	187	21	a	a	DET
eurjchem-952	187	22	complex	complex	NOUN
eurjchem-952	187	23	liberates	liberate	VERB
eurjchem-952	187	24	in	in	ADP
eurjchem-952	187	25	solution	solution	NOUN
eurjchem-952	187	26	,	,	PUNCT
eurjchem-952	187	27	the	the	DET
eurjchem-952	187	28	higher	high	ADJ
eurjchem-952	187	29	will	will	AUX
eurjchem-952	187	30	be	be	AUX
eurjchem-952	187	31	its	its	PRON
eurjchem-952	187	32	molar	molar	ADJ
eurjchem-952	187	33	conductivity	conductivity	NOUN
eurjchem-952	187	34	and	and	CCONJ
eurjchem-952	187	35	vice	vice	NOUN
eurjchem-952	187	36	versa	versa	ADV
eurjchem-952	187	37	.	.	PUNCT
eurjchem-952	188	1	the	the	DET
eurjchem-952	188	2	non‐ionized	non‐ionized	ADJ
eurjchem-952	188	3	complexes	complex	NOUN
eurjchem-952	188	4	have	have	VERB
eurjchem-952	188	5	negligible	negligible	ADJ
eurjchem-952	188	6	value	value	NOUN
eurjchem-952	188	7	of	of	ADP
eurjchem-952	188	8	molar	molar	ADJ
eurjchem-952	188	9	conductance	conductance	NOUN
eurjchem-952	188	10	.	.	PUNCT
eurjchem-952	189	1	it	it	PRON
eurjchem-952	189	2	is	be	AUX
eurjchem-952	189	3	clear	clear	ADJ
eurjchem-952	189	4	from	from	ADP
eurjchem-952	189	5	the	the	DET
eurjchem-952	189	6	conductivity	conductivity	NOUN
eurjchem-952	189	7	data	datum	NOUN
eurjchem-952	189	8	(	(	PUNCT
eurjchem-952	189	9	table	table	NOUN
eurjchem-952	189	10	1	1	NUM
eurjchem-952	189	11	)	)	PUNCT
eurjchem-952	189	12	that	that	SCONJ
eurjchem-952	189	13	the	the	DET
eurjchem-952	189	14	complexes	complex	NOUN
eurjchem-952	189	15	present	present	NOUN
eurjchem-952	189	16	seem	seem	VERB
eurjchem-952	189	17	to	to	PART
eurjchem-952	189	18	be	be	AUX
eurjchem-952	189	19	nonelectrolytes	nonelectrolyte	NOUN
eurjchem-952	189	20	(	(	PUNCT
eurjchem-952	189	21	2.01‐	2.01‐	NUM
eurjchem-952	189	22	3.81	3.81	NUM
eurjchem-952	189	23	ω‐1.cm2.mol‐1	ω‐1.cm2.mol‐1	NUM
eurjchem-952	189	24	)	)	PUNCT
eurjchem-952	189	25	.	.	PUNCT
eurjchem-952	190	1	also	also	ADV
eurjchem-952	190	2	the	the	DET
eurjchem-952	190	3	molar	molar	ADJ
eurjchem-952	190	4	conductance	conductance	NOUN
eurjchem-952	190	5	values	value	NOUN
eurjchem-952	190	6	indicate	indicate	VERB
eurjchem-952	190	7	that	that	SCONJ
eurjchem-952	190	8	the	the	DET
eurjchem-952	190	9	anions	anion	NOUN
eurjchem-952	190	10	were	be	AUX
eurjchem-952	190	11	existed	exist	VERB
eurjchem-952	190	12	inside	inside	ADP
eurjchem-952	190	13	the	the	DET
eurjchem-952	190	14	coordination	coordination	NOUN
eurjchem-952	190	15	sphere	sphere	NOUN
eurjchem-952	190	16	which	which	PRON
eurjchem-952	190	17	was	be	AUX
eurjchem-952	190	18	also	also	ADV
eurjchem-952	190	19	confirmed	confirm	VERB
eurjchem-952	190	20	from	from	ADP
eurjchem-952	190	21	the	the	DET
eurjchem-952	190	22	chemical	chemical	ADJ
eurjchem-952	190	23	analysis	analysis	NOUN
eurjchem-952	190	24	and	and	CCONJ
eurjchem-952	190	25	also	also	ADV
eurjchem-952	190	26	cl‐	cl‐	VERB
eurjchem-952	190	27	ion	ion	NOUN
eurjchem-952	190	28	is	be	AUX
eurjchem-952	190	29	not	not	PART
eurjchem-952	190	30	precipitated	precipitate	VERB
eurjchem-952	190	31	by	by	ADP
eurjchem-952	190	32	addition	addition	NOUN
eurjchem-952	190	33	of	of	ADP
eurjchem-952	190	34	agno3	agno3	NOUN
eurjchem-952	190	35	solution	solution	NOUN
eurjchem-952	190	36	.	.	PUNCT
eurjchem-952	191	1	hence	hence	ADV
eurjchem-952	191	2	,	,	PUNCT
eurjchem-952	191	3	the	the	DET
eurjchem-952	191	4	conductivity	conductivity	NOUN
eurjchem-952	191	5	measurements	measurement	NOUN
eurjchem-952	191	6	of	of	ADP
eurjchem-952	191	7	the	the	DET
eurjchem-952	191	8	metal(ii)‐chelates	metal(ii)‐chelate	NOUN
eurjchem-952	191	9	confirm	confirm	VERB
eurjchem-952	191	10	the	the	DET
eurjchem-952	191	11	proposed	propose	VERB
eurjchem-952	191	12	general	general	ADJ
eurjchem-952	191	13	formulae	formulae	NOUN
eurjchem-952	191	14	of	of	ADP
eurjchem-952	191	15	those	those	DET
eurjchem-952	191	16	chelates	chelate	NOUN
eurjchem-952	191	17	as	as	SCONJ
eurjchem-952	191	18	suggested	suggest	VERB
eurjchem-952	191	19	depending	depend	VERB
eurjchem-952	191	20	upon	upon	SCONJ
eurjchem-952	191	21	the	the	DET
eurjchem-952	191	22	results	result	NOUN
eurjchem-952	191	23	of	of	ADP
eurjchem-952	191	24	elemental	elemental	ADJ
eurjchem-952	191	25	analyses	analysis	NOUN
eurjchem-952	191	26	,	,	PUNCT
eurjchem-952	191	27	uv‐vis	uv‐vis	PROPN
eurjchem-952	191	28	,	,	PUNCT
eurjchem-952	191	29	esr	esr	PROPN
eurjchem-952	191	30	and	and	CCONJ
eurjchem-952	191	31	ir	ir	PROPN
eurjchem-952	191	32	spectra	spectra	PROPN
eurjchem-952	191	33	.	.	PROPN
eurjchem-952	192	1	aljahdali	aljahdali	PROPN
eurjchem-952	192	2	et	et	PROPN
eurjchem-952	192	3	al	al	PROPN
eurjchem-952	192	4	.	.	PUNCT
eurjchem-952	192	5	/	/	SYM
eurjchem-952	192	6	european	european	PROPN
eurjchem-952	192	7	journal	journal	PROPN
eurjchem-952	192	8	of	of	ADP
eurjchem-952	192	9	chemistry	chemistry	NOUN
eurjchem-952	192	10	5	5	NUM
eurjchem-952	192	11	(	(	PUNCT
eurjchem-952	192	12	2	2	NUM
eurjchem-952	192	13	)	)	PUNCT
eurjchem-952	192	14	(	(	PUNCT
eurjchem-952	192	15	2014	2014	NUM
eurjchem-952	192	16	)	)	PUNCT
eurjchem-952	192	17	201‐208	201‐208	NUM
eurjchem-952	192	18	205	205	NUM
eurjchem-952	192	19	table	table	NOUN
eurjchem-952	192	20	1	1	NUM
eurjchem-952	192	21	.	.	PUNCT
eurjchem-952	192	22	molar	molar	ADJ
eurjchem-952	192	23	conductance	conductance	NOUN
eurjchem-952	192	24	,	,	PUNCT
eurjchem-952	192	25	magnetic	magnetic	ADJ
eurjchem-952	192	26	moment	moment	NOUN
eurjchem-952	192	27	and	and	CCONJ
eurjchem-952	192	28	electronic	electronic	ADJ
eurjchem-952	192	29	spectral	spectral	ADJ
eurjchem-952	192	30	data	datum	NOUN
eurjchem-952	192	31	(	(	PUNCT
eurjchem-952	192	32	cm‐1	cm‐1	NOUN
eurjchem-952	192	33	)	)	PUNCT
eurjchem-952	192	34	of	of	ADP
eurjchem-952	192	35	the	the	DET
eurjchem-952	192	36	complexes	complex	NOUN
eurjchem-952	192	37	.	.	PUNCT
eurjchem-952	193	1	compounds	compound	NOUN
eurjchem-952	193	2	λm	λm	ADP
eurjchem-952	193	3	a	a	DET
eurjchem-952	193	4	µeff	µeff	NOUN
eurjchem-952	193	5	.	.	PUNCT
eurjchem-952	194	1	(	(	PUNCT
eurjchem-952	194	2	b.m	b.m	PROPN
eurjchem-952	194	3	.	.	PUNCT
eurjchem-952	194	4	)	)	PUNCT
eurjchem-952	195	1	d‐d	d‐d	NUM
eurjchem-952	195	2	transitions	transition	NOUN
eurjchem-952	195	3	[	[	X
eurjchem-952	195	4	cu(mpapt)(1,10‐phen)cl	cu(mpapt)(1,10‐phen)cl	X
eurjchem-952	195	5	]	]	X
eurjchem-952	195	6	(	(	PUNCT
eurjchem-952	195	7	1	1	X
eurjchem-952	195	8	)	)	PUNCT
eurjchem-952	195	9	2.01	2.01	NUM
eurjchem-952	195	10	1.82	1.82	NUM
eurjchem-952	195	11	14585	14585	NUM
eurjchem-952	195	12	2b1g→2eg	2b1g→2eg	NUM
eurjchem-952	195	13	[	[	X
eurjchem-952	195	14	ni(mpapt)(1,10‐phen)cl	ni(mpapt)(1,10‐phen)cl	NOUN
eurjchem-952	195	15	]	]	X
eurjchem-952	195	16	(	(	PUNCT
eurjchem-952	195	17	2	2	NUM
eurjchem-952	195	18	)	)	PUNCT
eurjchem-952	195	19	2.54	2.54	NUM
eurjchem-952	195	20	3.21	3.21	NUM
eurjchem-952	195	21	10675	10675	NUM
eurjchem-952	195	22	17540	17540	NUM
eurjchem-952	195	23	3a2g→3t1g(f	3a2g→3t1g(f	NUM
eurjchem-952	195	24	)	)	PUNCT
eurjchem-952	195	25	3a2g→3t1g(p	3a2g→3t1g(p	NUM
eurjchem-952	195	26	)	)	PUNCT
eurjchem-952	196	1	[	[	X
eurjchem-952	196	2	co(mpapt)(1,10‐phen)cl].h2o	co(mpapt)(1,10‐phen)cl].h2o	X
eurjchem-952	196	3	(	(	PUNCT
eurjchem-952	196	4	3	3	NUM
eurjchem-952	196	5	)	)	PUNCT
eurjchem-952	196	6	3.15	3.15	NUM
eurjchem-952	196	7	4.71	4.71	NUM
eurjchem-952	196	8	9935	9935	NUM
eurjchem-952	196	9	20423	20423	NUM
eurjchem-952	196	10	4t1g(f)4t2g(f	4t1g(f)4t2g(f	NUM
eurjchem-952	196	11	)	)	PUNCT
eurjchem-952	196	12	4t1g(f)4t1g(p	4t1g(f)4t1g(p	NUM
eurjchem-952	196	13	)	)	PUNCT
eurjchem-952	197	1	[	[	X
eurjchem-952	197	2	mn(mpapt)(1,10‐phen)cl].h2o	mn(mpapt)(1,10‐phen)cl].h2o	NOUN
eurjchem-952	197	3	(	(	PUNCT
eurjchem-952	197	4	4	4	NUM
eurjchem-952	197	5	)	)	PUNCT
eurjchem-952	197	6	3.81	3.81	NUM
eurjchem-952	197	7	6.01	6.01	NUM
eurjchem-952	197	8	20850	20850	NUM
eurjchem-952	197	9	24120	24120	NUM
eurjchem-952	197	10	6a1	6a1	NUM
eurjchem-952	197	11	g	g	NOUN
eurjchem-952	197	12	→	→	SYM
eurjchem-952	197	13	6t1g(g	6t1g(g	NUM
eurjchem-952	197	14	)	)	PUNCT
eurjchem-952	197	15	6a1	6a1	NUM
eurjchem-952	197	16	g	g	NOUN
eurjchem-952	197	17	→	→	SYM
eurjchem-952	197	18	6t2g(g	6t2g(g	NOUN
eurjchem-952	197	19	)	)	PUNCT
eurjchem-952	198	1	a	a	DET
eurjchem-952	198	2	molar	molar	ADJ
eurjchem-952	198	3	conductance	conductance	NOUN
eurjchem-952	198	4	measured	measure	VERB
eurjchem-952	198	5	for	for	ADP
eurjchem-952	198	6	10‐3	10‐3	NUM
eurjchem-952	198	7	m	m	PROPN
eurjchem-952	198	8	dmso	dmso	NOUN
eurjchem-952	198	9	solution	solution	NOUN
eurjchem-952	198	10	,	,	PUNCT
eurjchem-952	198	11	ω‐1	ω‐1	DET
eurjchem-952	198	12	cm2	cm2	NOUN
eurjchem-952	198	13	mol‐1	mol‐1	NOUN
eurjchem-952	198	14	.	.	PUNCT
eurjchem-952	198	15	table	table	NOUN
eurjchem-952	198	16	2	2	NUM
eurjchem-952	198	17	.	.	PUNCT
eurjchem-952	198	18	antibacterial	antibacterial	ADJ
eurjchem-952	198	19	activity	activity	NOUN
eurjchem-952	198	20	of	of	ADP
eurjchem-952	198	21	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-952	198	22	ligand	ligand	NOUN
eurjchem-952	198	23	and	and	CCONJ
eurjchem-952	198	24	its	its	PRON
eurjchem-952	198	25	metal	metal	NOUN
eurjchem-952	198	26	complexes	complex	NOUN
eurjchem-952	198	27	.	.	PUNCT
eurjchem-952	199	1	compounds	compound	VERB
eurjchem-952	199	2	diameter	diameter	NOUN
eurjchem-952	199	3	of	of	ADP
eurjchem-952	199	4	inhibition	inhibition	NOUN
eurjchem-952	199	5	zone	zone	NOUN
eurjchem-952	199	6	(	(	PUNCT
eurjchem-952	199	7	in	in	ADP
eurjchem-952	199	8	mm	mm	PROPN
eurjchem-952	199	9	)	)	PUNCT
eurjchem-952	199	10	a	a	DET
eurjchem-952	199	11	g(‐	g(‐	NUM
eurjchem-952	199	12	)	)	PUNCT
eurjchem-952	199	13	g(+	g(+	NOUN
eurjchem-952	199	14	)	)	PUNCT
eurjchem-952	199	15	pseudomonas	pseudomona	VERB
eurjchem-952	199	16	aeuroginosa	aeuroginosa	NOUN
eurjchem-952	199	17	(	(	PUNCT
eurjchem-952	199	18	rcmb	rcmb	NOUN
eurjchem-952	199	19	010043	010043	NUM
eurjchem-952	199	20	)	)	PUNCT
eurjchem-952	199	21	escherichia	escherichia	NOUN
eurjchem-952	199	22	coli	coli	NOUN
eurjchem-952	199	23	(	(	PUNCT
eurjchem-952	199	24	rcmb	rcmb	NOUN
eurjchem-952	199	25	010052	010052	NUM
eurjchem-952	199	26	)	)	PUNCT
eurjchem-952	199	27	bacillus	bacillus	NOUN
eurjchem-952	199	28	subtillis	subtillis	NOUN
eurjchem-952	199	29	(	(	PUNCT
eurjchem-952	199	30	rcmb	rcmb	NOUN
eurjchem-952	199	31	010067	010067	NUM
eurjchem-952	199	32	)	)	PUNCT
eurjchem-952	199	33	staphylococcus	staphylococcus	NOUN
eurjchem-952	199	34	aureus	aureus	NOUN
eurjchem-952	199	35	(	(	PUNCT
eurjchem-952	199	36	rcmb	rcmb	NOUN
eurjchem-952	199	37	010028	010028	NUM
eurjchem-952	199	38	)	)	PUNCT
eurjchem-952	199	39	mpapt	mpapt	ADJ
eurjchem-952	200	1	13.2±0.34	13.2±0.34	NUM
eurjchem-952	200	2	‐	‐	NOUN
eurjchem-952	200	3	19.4±0.44	19.4±0.44	NUM
eurjchem-952	200	4	18.1±0.25	18.1±0.25	NUM
eurjchem-952	200	5	[	[	X
eurjchem-952	200	6	cu(mpapt)(1,10‐phen)cl	cu(mpapt)(1,10‐phen)cl	X
eurjchem-952	200	7	]	]	X
eurjchem-952	200	8	(	(	PUNCT
eurjchem-952	200	9	1	1	NUM
eurjchem-952	200	10	)	)	PUNCT
eurjchem-952	200	11	17.7±0.19	17.7±0.19	NUM
eurjchem-952	200	12	14.1±0.37	14.1±0.37	NUM
eurjchem-952	200	13	24.7±0.52	24.7±0.52	NUM
eurjchem-952	200	14	27.2±0.45	27.2±0.45	NUM
eurjchem-952	200	15	[	[	X
eurjchem-952	200	16	ni(mpapt)(1,10‐phen)cl	ni(mpapt)(1,10‐phen)cl	NOUN
eurjchem-952	200	17	]	]	X
eurjchem-952	200	18	(	(	PUNCT
eurjchem-952	200	19	2	2	X
eurjchem-952	200	20	)	)	PUNCT
eurjchem-952	200	21	15.4±0.22	15.4±0.22	NUM
eurjchem-952	200	22	12.2±0.14	12.2±0.14	NUM
eurjchem-952	200	23	21.5±0.42	21.5±0.42	NUM
eurjchem-952	200	24	24.7±0.14	24.7±0.14	NUM
eurjchem-952	201	1	[	[	X
eurjchem-952	201	2	co(mpapt)(1,10‐phen)cl].h2o	co(mpapt)(1,10‐phen)cl].h2o	NOUN
eurjchem-952	201	3	(	(	PUNCT
eurjchem-952	201	4	3	3	X
eurjchem-952	201	5	)	)	PUNCT
eurjchem-952	201	6	14.2±0.34	14.2±0.34	NUM
eurjchem-952	201	7	11.1±0.43	11.1±0.43	NUM
eurjchem-952	201	8	20.3±0.49	20.3±0.49	NUM
eurjchem-952	201	9	22.9±0.35	22.9±0.35	NUM
eurjchem-952	202	1	[	[	X
eurjchem-952	202	2	mn(mpapt)(1,10‐phen)cl].h2o	mn(mpapt)(1,10‐phen)cl].h2o	NOUN
eurjchem-952	202	3	(	(	PUNCT
eurjchem-952	202	4	4	4	NUM
eurjchem-952	202	5	)	)	PUNCT
eurjchem-952	202	6	12.7±0.25	12.7±0.25	NUM
eurjchem-952	202	7	10.1±0.25	10.1±0.25	NUM
eurjchem-952	202	8	18.8±0.57	18.8±0.57	NUM
eurjchem-952	202	9	21.8±0.39	21.8±0.39	NUM
eurjchem-952	202	10	standard	standard	PROPN
eurjchem-952	202	11	b	b	PROPN
eurjchem-952	202	12	17.3±0.15	17.3±0.15	NUM
eurjchem-952	202	13	22.3±0.18	22.3±0.18	NUM
eurjchem-952	202	14	27.4±0.18	27.4±0.18	NUM
eurjchem-952	202	15	32.4±0.10	32.4±0.10	NUM
eurjchem-952	202	16	a	a	DET
eurjchem-952	202	17	mean	mean	ADJ
eurjchem-952	202	18	zone	zone	NOUN
eurjchem-952	202	19	of	of	ADP
eurjchem-952	202	20	inhibition	inhibition	NOUN
eurjchem-952	202	21	in	in	ADP
eurjchem-952	202	22	mm±standard	mm±standard	NOUN
eurjchem-952	202	23	deviation	deviation	NOUN
eurjchem-952	202	24	beyond	beyond	ADP
eurjchem-952	202	25	well	well	INTJ
eurjchem-952	202	26	diameter	diameter	NOUN
eurjchem-952	202	27	(	(	PUNCT
eurjchem-952	202	28	6	6	NUM
eurjchem-952	202	29	mm	mm	NOUN
eurjchem-952	202	30	)	)	PUNCT
eurjchem-952	202	31	produced	produce	VERB
eurjchem-952	202	32	on	on	ADP
eurjchem-952	202	33	a	a	DET
eurjchem-952	202	34	range	range	NOUN
eurjchem-952	202	35	of	of	ADP
eurjchem-952	202	36	environmental	environmental	ADJ
eurjchem-952	202	37	and	and	CCONJ
eurjchem-952	202	38	clinically	clinically	ADV
eurjchem-952	202	39	pathogenic	pathogenic	ADJ
eurjchem-952	202	40	microorganisms	microorganism	NOUN
eurjchem-952	202	41	using	use	VERB
eurjchem-952	202	42	(	(	PUNCT
eurjchem-952	202	43	1	1	NUM
eurjchem-952	202	44	mg	mg	NUM
eurjchem-952	202	45	/	/	SYM
eurjchem-952	202	46	ml	ml	NOUN
eurjchem-952	202	47	)	)	PUNCT
eurjchem-952	202	48	concentration	concentration	NOUN
eurjchem-952	202	49	of	of	ADP
eurjchem-952	202	50	tested	test	VERB
eurjchem-952	202	51	samples	sample	NOUN
eurjchem-952	202	52	.	.	PUNCT
eurjchem-952	203	1	b	b	X
eurjchem-952	203	2	the	the	DET
eurjchem-952	203	3	standard	standard	ADJ
eurjchem-952	203	4	antibacterial	antibacterial	ADJ
eurjchem-952	203	5	agents	agent	NOUN
eurjchem-952	203	6	are	be	AUX
eurjchem-952	203	7	gentamicin	gentamicin	VERB
eurjchem-952	203	8	for	for	ADP
eurjchem-952	203	9	g(‐	g(‐	NUM
eurjchem-952	203	10	)	)	PUNCT
eurjchem-952	203	11	and	and	CCONJ
eurjchem-952	203	12	ampicillin	ampicillin	NOUN
eurjchem-952	203	13	for	for	ADP
eurjchem-952	203	14	g(+	g(+	NOUN
eurjchem-952	203	15	)	)	PUNCT
eurjchem-952	203	16	.	.	PUNCT
eurjchem-952	204	1	table	table	NOUN
eurjchem-952	204	2	3	3	NUM
eurjchem-952	204	3	.	.	PUNCT
eurjchem-952	204	4	antifungal	antifungal	ADJ
eurjchem-952	204	5	activity	activity	NOUN
eurjchem-952	204	6	of	of	ADP
eurjchem-952	204	7	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-952	204	8	ligand	ligand	NOUN
eurjchem-952	204	9	and	and	CCONJ
eurjchem-952	204	10	its	its	PRON
eurjchem-952	204	11	metal	metal	NOUN
eurjchem-952	204	12	complexes	complex	NOUN
eurjchem-952	204	13	.	.	PUNCT
eurjchem-952	205	1	compounds	compound	VERB
eurjchem-952	205	2	diameter	diameter	NOUN
eurjchem-952	205	3	of	of	ADP
eurjchem-952	205	4	inhibition	inhibition	NOUN
eurjchem-952	205	5	zone	zone	NOUN
eurjchem-952	205	6	(	(	PUNCT
eurjchem-952	205	7	in	in	ADP
eurjchem-952	205	8	mm	mm	PROPN
eurjchem-952	205	9	)	)	PUNCT
eurjchem-952	205	10	a	a	DET
eurjchem-952	205	11	aspergillus	aspergillus	NOUN
eurjchem-952	205	12	flavus	flavus	NOUN
eurjchem-952	205	13	(	(	PUNCT
eurjchem-952	205	14	rcmb	rcmb	NOUN
eurjchem-952	205	15	02568	02568	NUM
eurjchem-952	205	16	)	)	PUNCT
eurjchem-952	206	1	pencicillium	pencicillium	NOUN
eurjchem-952	206	2	italicum	italicum	NOUN
eurjchem-952	206	3	(	(	PUNCT
eurjchem-952	206	4	rcmb	rcmb	NOUN
eurjchem-952	206	5	03924	03924	NUM
eurjchem-952	206	6	)	)	PUNCT
eurjchem-952	206	7	geotricum	geotricum	NOUN
eurjchem-952	206	8	candidum	candidum	NOUN
eurjchem-952	206	9	(	(	PUNCT
eurjchem-952	206	10	rcmb	rcmb	NOUN
eurjchem-952	206	11	05097	05097	NUM
eurjchem-952	206	12	)	)	PUNCT
eurjchem-952	206	13	mpapt	mpapt	ADJ
eurjchem-952	206	14	14.6±0.38	14.6±0.38	PROPN
eurjchem-952	206	15	15.4±0.24	15.4±0.24	NUM
eurjchem-952	206	16	17.7±0.24	17.7±0.24	NUM
eurjchem-952	207	1	[	[	X
eurjchem-952	207	2	cu(mpapt)(1,10‐phen)cl	cu(mpapt)(1,10‐phen)cl	X
eurjchem-952	207	3	]	]	X
eurjchem-952	207	4	(	(	PUNCT
eurjchem-952	207	5	1	1	X
eurjchem-952	207	6	)	)	PUNCT
eurjchem-952	207	7	19.6±0.50	19.6±0.50	NUM
eurjchem-952	207	8	19.2±0.38	19.2±0.38	NUM
eurjchem-952	207	9	24.5±0.15	24.5±0.15	NUM
eurjchem-952	208	1	[	[	X
eurjchem-952	208	2	ni(mpapt)(1,10‐phen)cl	ni(mpapt)(1,10‐phen)cl	X
eurjchem-952	208	3	]	]	X
eurjchem-952	208	4	(	(	PUNCT
eurjchem-952	208	5	2	2	NUM
eurjchem-952	208	6	)	)	PUNCT
eurjchem-952	208	7	17.8±0.28	17.8±0.28	NUM
eurjchem-952	208	8	16.5±0.54	16.5±0.54	NUM
eurjchem-952	208	9	22.4±0.32	22.4±0.32	NUM
eurjchem-952	208	10	[	[	X
eurjchem-952	208	11	co(mpapt)(1,10‐phen)cl].h2o	co(mpapt)(1,10‐phen)cl].h2o	X
eurjchem-952	208	12	(	(	PUNCT
eurjchem-952	208	13	3	3	NUM
eurjchem-952	208	14	)	)	PUNCT
eurjchem-952	208	15	16.6±0.45	16.6±0.45	NUM
eurjchem-952	208	16	15.7±0.24	15.7±0.24	NUM
eurjchem-952	208	17	20.6±0.75	20.6±0.75	NUM
eurjchem-952	209	1	[	[	X
eurjchem-952	209	2	mn(mpapt)(1,10‐phen)cl].h2o	mn(mpapt)(1,10‐phen)cl].h2o	NOUN
eurjchem-952	209	3	(	(	PUNCT
eurjchem-952	209	4	4	4	NUM
eurjchem-952	209	5	)	)	PUNCT
eurjchem-952	209	6	15.6±0.37	15.6±0.37	NUM
eurjchem-952	209	7	14.8±0.37	14.8±0.37	NUM
eurjchem-952	209	8	17.8±0.73	17.8±0.73	NUM
eurjchem-952	209	9	amphotericin	amphotericin	ADP
eurjchem-952	209	10	(	(	PUNCT
eurjchem-952	209	11	b	b	NOUN
eurjchem-952	209	12	)	)	PUNCT
eurjchem-952	209	13	23.7±0.10	23.7±0.10	NUM
eurjchem-952	209	14	21.9±0.12	21.9±0.12	NUM
eurjchem-952	209	15	28.7±0.22	28.7±0.22	NUM
eurjchem-952	209	16	a	a	DET
eurjchem-952	209	17	mean	mean	ADJ
eurjchem-952	209	18	zone	zone	NOUN
eurjchem-952	209	19	of	of	ADP
eurjchem-952	209	20	inhibition	inhibition	NOUN
eurjchem-952	209	21	in	in	ADP
eurjchem-952	209	22	mm±standard	mm±standard	NOUN
eurjchem-952	209	23	deviation	deviation	NOUN
eurjchem-952	209	24	beyond	beyond	ADP
eurjchem-952	209	25	well	well	INTJ
eurjchem-952	209	26	diameter	diameter	NOUN
eurjchem-952	209	27	(	(	PUNCT
eurjchem-952	209	28	6	6	NUM
eurjchem-952	209	29	mm	mm	NOUN
eurjchem-952	209	30	)	)	PUNCT
eurjchem-952	209	31	produced	produce	VERB
eurjchem-952	209	32	on	on	ADP
eurjchem-952	209	33	a	a	DET
eurjchem-952	209	34	range	range	NOUN
eurjchem-952	209	35	of	of	ADP
eurjchem-952	209	36	environmental	environmental	ADJ
eurjchem-952	209	37	and	and	CCONJ
eurjchem-952	209	38	clinically	clinically	ADV
eurjchem-952	209	39	pathogenic	pathogenic	ADJ
eurjchem-952	209	40	microorganisms	microorganism	NOUN
eurjchem-952	209	41	using	use	VERB
eurjchem-952	209	42	(	(	PUNCT
eurjchem-952	209	43	1	1	NUM
eurjchem-952	209	44	mg	mg	NUM
eurjchem-952	209	45	/	/	SYM
eurjchem-952	209	46	ml	ml	NOUN
eurjchem-952	209	47	)	)	PUNCT
eurjchem-952	209	48	concentration	concentration	NOUN
eurjchem-952	209	49	of	of	ADP
eurjchem-952	209	50	tested	test	VERB
eurjchem-952	209	51	samples	sample	NOUN
eurjchem-952	209	52	.	.	PUNCT
eurjchem-952	210	1	3.5	3.5	NUM
eurjchem-952	210	2	.	.	PUNCT
eurjchem-952	211	1	biological	biological	ADJ
eurjchem-952	211	2	studies	study	NOUN
eurjchem-952	211	3	3.5.1	3.5.1	NUM
eurjchem-952	211	4	.	.	PUNCT
eurjchem-952	211	5	antimicrobial	antimicrobial	ADJ
eurjchem-952	211	6	activity	activity	NOUN
eurjchem-952	211	7	to	to	PART
eurjchem-952	211	8	assess	assess	VERB
eurjchem-952	211	9	the	the	DET
eurjchem-952	211	10	biological	biological	ADJ
eurjchem-952	211	11	potential	potential	NOUN
eurjchem-952	211	12	of	of	ADP
eurjchem-952	211	13	the	the	DET
eurjchem-952	211	14	synthesized	synthesize	VERB
eurjchem-952	211	15	compounds	compound	NOUN
eurjchem-952	211	16	,	,	PUNCT
eurjchem-952	211	17	the	the	DET
eurjchem-952	211	18	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-952	211	19	ligand	ligand	NOUN
eurjchem-952	211	20	and	and	CCONJ
eurjchem-952	211	21	its	its	PRON
eurjchem-952	211	22	metal	metal	NOUN
eurjchem-952	211	23	complexes	complex	NOUN
eurjchem-952	211	24	were	be	AUX
eurjchem-952	211	25	tested	test	VERB
eurjchem-952	211	26	against	against	ADP
eurjchem-952	211	27	different	different	ADJ
eurjchem-952	211	28	species	specie	NOUN
eurjchem-952	211	29	of	of	ADP
eurjchem-952	211	30	bacteria	bacteria	NOUN
eurjchem-952	211	31	and	and	CCONJ
eurjchem-952	211	32	fungi	fungus	NOUN
eurjchem-952	211	33	.	.	PUNCT
eurjchem-952	212	1	the	the	DET
eurjchem-952	212	2	parent	parent	NOUN
eurjchem-952	212	3	(	(	PUNCT
eurjchem-952	212	4	mpapt	mpapt	ADJ
eurjchem-952	212	5	)	)	PUNCT
eurjchem-952	212	6	ligand	ligand	NOUN
eurjchem-952	212	7	and	and	CCONJ
eurjchem-952	212	8	its	its	PRON
eurjchem-952	212	9	complexes	complex	NOUN
eurjchem-952	212	10	are	be	AUX
eurjchem-952	212	11	water	water	NOUN
eurjchem-952	212	12	insoluble	insoluble	ADJ
eurjchem-952	212	13	;	;	PUNCT
eurjchem-952	212	14	therefore	therefore	ADV
eurjchem-952	212	15	,	,	PUNCT
eurjchem-952	212	16	the	the	DET
eurjchem-952	212	17	antimicrobial	antimicrobial	ADJ
eurjchem-952	212	18	test	test	NOUN
eurjchem-952	212	19	was	be	AUX
eurjchem-952	212	20	carried	carry	VERB
eurjchem-952	212	21	out	out	ADP
eurjchem-952	212	22	in	in	ADP
eurjchem-952	212	23	dmso	dmso	NOUN
eurjchem-952	212	24	.	.	PUNCT
eurjchem-952	213	1	the	the	DET
eurjchem-952	213	2	results	result	NOUN
eurjchem-952	213	3	of	of	ADP
eurjchem-952	213	4	the	the	DET
eurjchem-952	213	5	antimicrobial	antimicrobial	ADJ
eurjchem-952	213	6	test	test	NOUN
eurjchem-952	213	7	of	of	ADP
eurjchem-952	213	8	the	the	DET
eurjchem-952	213	9	parent	parent	NOUN
eurjchem-952	213	10	ligand	ligand	NOUN
eurjchem-952	213	11	and	and	CCONJ
eurjchem-952	213	12	its	its	PRON
eurjchem-952	213	13	metal	metal	NOUN
eurjchem-952	213	14	complexes	complex	NOUN
eurjchem-952	213	15	against	against	ADP
eurjchem-952	213	16	gram	gram	NOUN
eurjchem-952	213	17	positive	positive	ADJ
eurjchem-952	213	18	and	and	CCONJ
eurjchem-952	213	19	gram	gram	NOUN
eurjchem-952	213	20	negative	negative	NOUN
eurjchem-952	213	21	are	be	AUX
eurjchem-952	213	22	given	give	VERB
eurjchem-952	213	23	in	in	ADP
eurjchem-952	213	24	table	table	NOUN
eurjchem-952	213	25	2	2	NUM
eurjchem-952	213	26	while	while	SCONJ
eurjchem-952	213	27	the	the	DET
eurjchem-952	213	28	results	result	NOUN
eurjchem-952	213	29	of	of	ADP
eurjchem-952	213	30	the	the	DET
eurjchem-952	213	31	antifungal	antifungal	ADJ
eurjchem-952	213	32	activity	activity	NOUN
eurjchem-952	213	33	against	against	ADP
eurjchem-952	213	34	was	be	AUX
eurjchem-952	213	35	given	give	VERB
eurjchem-952	213	36	in	in	ADP
eurjchem-952	213	37	table	table	NOUN
eurjchem-952	213	38	3	3	NUM
eurjchem-952	213	39	.	.	PUNCT
eurjchem-952	214	1	in	in	ADP
eurjchem-952	214	2	testing	test	VERB
eurjchem-952	214	3	the	the	DET
eurjchem-952	214	4	antimicrobial	antimicrobial	ADJ
eurjchem-952	214	5	activity	activity	NOUN
eurjchem-952	214	6	of	of	ADP
eurjchem-952	214	7	these	these	DET
eurjchem-952	214	8	compounds	compound	NOUN
eurjchem-952	214	9	,	,	PUNCT
eurjchem-952	214	10	we	we	PRON
eurjchem-952	214	11	used	use	VERB
eurjchem-952	214	12	more	more	ADJ
eurjchem-952	214	13	than	than	ADP
eurjchem-952	214	14	one	one	NUM
eurjchem-952	214	15	test	test	NOUN
eurjchem-952	214	16	organism	organism	NOUN
eurjchem-952	214	17	to	to	PART
eurjchem-952	214	18	increase	increase	VERB
eurjchem-952	214	19	the	the	DET
eurjchem-952	214	20	chance	chance	NOUN
eurjchem-952	214	21	of	of	ADP
eurjchem-952	214	22	detecting	detect	VERB
eurjchem-952	214	23	antibiotic	antibiotic	ADJ
eurjchem-952	214	24	principles	principle	NOUN
eurjchem-952	214	25	in	in	ADP
eurjchem-952	214	26	tested	test	VERB
eurjchem-952	214	27	materials	material	NOUN
eurjchem-952	214	28	.	.	PUNCT
eurjchem-952	215	1	the	the	DET
eurjchem-952	215	2	organisms	organism	NOUN
eurjchem-952	215	3	used	use	VERB
eurjchem-952	215	4	in	in	ADP
eurjchem-952	215	5	the	the	DET
eurjchem-952	215	6	present	present	ADJ
eurjchem-952	215	7	investigations	investigation	NOUN
eurjchem-952	215	8	included	include	VERB
eurjchem-952	215	9	two	two	NUM
eurjchem-952	215	10	gram	gram	NOUN
eurjchem-952	215	11	positive	positive	ADJ
eurjchem-952	215	12	(	(	PUNCT
eurjchem-952	215	13	staphylococcus	staphylococcus	NOUN
eurjchem-952	215	14	aureus	aureus	NOUN
eurjchem-952	215	15	and	and	CCONJ
eurjchem-952	215	16	bacillus	bacillus	NOUN
eurjchem-952	215	17	subtillis	subtillis	PROPN
eurjchem-952	215	18	)	)	PUNCT
eurjchem-952	215	19	and	and	CCONJ
eurjchem-952	215	20	two	two	NUM
eurjchem-952	215	21	gram	gram	NOUN
eurjchem-952	215	22	negative	negative	ADJ
eurjchem-952	215	23	(	(	PUNCT
eurjchem-952	215	24	pseudomonas	pseudomona	NOUN
eurjchem-952	215	25	aeruguinosa	aeruguinosa	PROPN
eurjchem-952	215	26	and	and	CCONJ
eurjchem-952	215	27	escherichia	escherichia	NOUN
eurjchem-952	215	28	coli	coli	NOUN
eurjchem-952	215	29	)	)	PUNCT
eurjchem-952	215	30	.	.	PUNCT
eurjchem-952	216	1	the	the	DET
eurjchem-952	216	2	diffusion	diffusion	NOUN
eurjchem-952	216	3	agar	agar	NOUN
eurjchem-952	216	4	technique	technique	NOUN
eurjchem-952	216	5	was	be	AUX
eurjchem-952	216	6	used	use	VERB
eurjchem-952	216	7	to	to	PART
eurjchem-952	216	8	evaluate	evaluate	VERB
eurjchem-952	216	9	the	the	DET
eurjchem-952	216	10	antibacterial	antibacterial	ADJ
eurjchem-952	216	11	activity	activity	NOUN
eurjchem-952	216	12	of	of	ADP
eurjchem-952	216	13	the	the	DET
eurjchem-952	216	14	synthesized	synthesize	VERB
eurjchem-952	216	15	mixed	mixed	ADJ
eurjchem-952	216	16	ligand	ligand	ADJ
eurjchem-952	216	17	complexes	complex	NOUN
eurjchem-952	216	18	[	[	X
eurjchem-952	216	19	53‐56	53‐56	NUM
eurjchem-952	216	20	]	]	PUNCT
eurjchem-952	216	21	.	.	PUNCT
eurjchem-952	217	1	the	the	DET
eurjchem-952	217	2	medium	medium	NOUN
eurjchem-952	217	3	used	use	VERB
eurjchem-952	217	4	for	for	ADP
eurjchem-952	217	5	growing	grow	VERB
eurjchem-952	217	6	the	the	DET
eurjchem-952	217	7	culture	culture	NOUN
eurjchem-952	217	8	was	be	AUX
eurjchem-952	217	9	nutrient	nutrient	ADJ
eurjchem-952	217	10	agar	agar	NOUN
eurjchem-952	217	11	.	.	PUNCT
eurjchem-952	218	1	metal	metal	NOUN
eurjchem-952	218	2	ions	ion	NOUN
eurjchem-952	218	3	are	be	AUX
eurjchem-952	218	4	adsorbed	adsorb	VERB
eurjchem-952	218	5	on	on	ADP
eurjchem-952	218	6	the	the	DET
eurjchem-952	218	7	cell	cell	NOUN
eurjchem-952	218	8	walls	wall	NOUN
eurjchem-952	218	9	of	of	ADP
eurjchem-952	218	10	the	the	DET
eurjchem-952	218	11	microorganisms	microorganism	NOUN
eurjchem-952	218	12	,	,	PUNCT
eurjchem-952	218	13	disturbing	disturb	VERB
eurjchem-952	218	14	the	the	DET
eurjchem-952	218	15	respiration	respiration	NOUN
eurjchem-952	218	16	processes	process	NOUN
eurjchem-952	218	17	of	of	ADP
eurjchem-952	218	18	the	the	DET
eurjchem-952	218	19	cells	cell	NOUN
eurjchem-952	218	20	and	and	CCONJ
eurjchem-952	218	21	thus	thus	ADV
eurjchem-952	218	22	blocking	block	VERB
eurjchem-952	218	23	the	the	DET
eurjchem-952	218	24	protein	protein	NOUN
eurjchem-952	218	25	synthesis	synthesis	NOUN
eurjchem-952	218	26	that	that	PRON
eurjchem-952	218	27	is	be	AUX
eurjchem-952	218	28	required	require	VERB
eurjchem-952	218	29	for	for	ADP
eurjchem-952	218	30	further	further	ADJ
eurjchem-952	218	31	growth	growth	NOUN
eurjchem-952	218	32	of	of	ADP
eurjchem-952	218	33	the	the	DET
eurjchem-952	218	34	organisms	organism	NOUN
eurjchem-952	218	35	.	.	PUNCT
eurjchem-952	219	1	hence	hence	ADV
eurjchem-952	219	2	,	,	PUNCT
eurjchem-952	219	3	metal	metal	NOUN
eurjchem-952	219	4	ions	ion	NOUN
eurjchem-952	219	5	are	be	AUX
eurjchem-952	219	6	essential	essential	ADJ
eurjchem-952	219	7	for	for	ADP
eurjchem-952	219	8	the	the	DET
eurjchem-952	219	9	growth‐inhibitory	growth‐inhibitory	NOUN
eurjchem-952	219	10	effects	effect	NOUN
eurjchem-952	219	11	[	[	X
eurjchem-952	219	12	57	57	NUM
eurjchem-952	219	13	]	]	PUNCT
eurjchem-952	219	14	.	.	PUNCT
eurjchem-952	220	1	the	the	DET
eurjchem-952	220	2	synthesized	synthesize	VERB
eurjchem-952	220	3	compounds	compound	NOUN
eurjchem-952	220	4	were	be	AUX
eurjchem-952	220	5	found	find	VERB
eurjchem-952	220	6	to	to	PART
eurjchem-952	220	7	be	be	AUX
eurjchem-952	220	8	more	more	ADV
eurjchem-952	220	9	toxic	toxic	ADJ
eurjchem-952	220	10	compared	compare	VERB
eurjchem-952	220	11	with	with	ADP
eurjchem-952	220	12	the	the	DET
eurjchem-952	220	13	parent	parent	NOUN
eurjchem-952	220	14	free	free	ADJ
eurjchem-952	220	15	ligand	ligand	NOUN
eurjchem-952	220	16	against	against	ADP
eurjchem-952	220	17	the	the	DET
eurjchem-952	220	18	same	same	ADJ
eurjchem-952	220	19	micro‐organism	micro‐organism	NOUN
eurjchem-952	220	20	and	and	CCONJ
eurjchem-952	220	21	under	under	ADP
eurjchem-952	220	22	the	the	DET
eurjchem-952	220	23	identical	identical	ADJ
eurjchem-952	220	24	experimental	experimental	ADJ
eurjchem-952	220	25	conditions	condition	NOUN
eurjchem-952	220	26	.	.	PUNCT
eurjchem-952	221	1	according	accord	VERB
eurjchem-952	221	2	to	to	ADP
eurjchem-952	221	3	overtone	overtone	NOUN
eurjchem-952	221	4	’s	’s	PART
eurjchem-952	221	5	concept	concept	NOUN
eurjchem-952	221	6	of	of	ADP
eurjchem-952	221	7	cell	cell	NOUN
eurjchem-952	221	8	permeability	permeability	NOUN
eurjchem-952	221	9	,	,	PUNCT
eurjchem-952	221	10	the	the	DET
eurjchem-952	221	11	lipid	lipid	NOUN
eurjchem-952	221	12	membrane	membrane	NOUN
eurjchem-952	221	13	that	that	PRON
eurjchem-952	221	14	surrounds	surround	VERB
eurjchem-952	221	15	the	the	DET
eurjchem-952	221	16	cell	cell	NOUN
eurjchem-952	221	17	favors	favor	VERB
eurjchem-952	221	18	the	the	DET
eurjchem-952	221	19	passage	passage	NOUN
eurjchem-952	221	20	of	of	ADP
eurjchem-952	221	21	only	only	ADJ
eurjchem-952	221	22	lipid‐soluble	lipid‐soluble	ADJ
eurjchem-952	221	23	materials	material	NOUN
eurjchem-952	221	24	,	,	PUNCT
eurjchem-952	221	25	so	so	CCONJ
eurjchem-952	221	26	lipophilicity	lipophilicity	NOUN
eurjchem-952	221	27	is	be	AUX
eurjchem-952	221	28	an	an	DET
eurjchem-952	221	29	important	important	ADJ
eurjchem-952	221	30	factor	factor	NOUN
eurjchem-952	221	31	controlling	control	VERB
eurjchem-952	221	32	the	the	DET
eurjchem-952	221	33	antifungal	antifungal	ADJ
eurjchem-952	221	34	activity	activity	NOUN
eurjchem-952	221	35	.	.	PUNCT
eurjchem-952	222	1	upon	upon	SCONJ
eurjchem-952	222	2	chelating	chelating	NOUN
eurjchem-952	222	3	,	,	PUNCT
eurjchem-952	222	4	the	the	DET
eurjchem-952	222	5	polarity	polarity	NOUN
eurjchem-952	222	6	of	of	ADP
eurjchem-952	222	7	the	the	DET
eurjchem-952	222	8	metal	metal	NOUN
eurjchem-952	222	9	ion	ion	NOUN
eurjchem-952	222	10	will	will	AUX
eurjchem-952	222	11	be	be	AUX
eurjchem-952	222	12	reduced	reduce	VERB
eurjchem-952	222	13	due	due	ADP
eurjchem-952	222	14	to	to	ADP
eurjchem-952	222	15	the	the	DET
eurjchem-952	222	16	overlap	overlap	NOUN
eurjchem-952	222	17	of	of	ADP
eurjchem-952	222	18	the	the	DET
eurjchem-952	222	19	ligand	ligand	NOUN
eurjchem-952	222	20	orbitals	orbital	NOUN
eurjchem-952	222	21	and	and	CCONJ
eurjchem-952	222	22	partial	partial	ADJ
eurjchem-952	222	23	sharing	sharing	NOUN
eurjchem-952	222	24	of	of	ADP
eurjchem-952	222	25	the	the	DET
eurjchem-952	222	26	positive	positive	ADJ
eurjchem-952	222	27	charge	charge	NOUN
eurjchem-952	222	28	of	of	ADP
eurjchem-952	222	29	the	the	DET
eurjchem-952	222	30	metal	metal	NOUN
eurjchem-952	222	31	ion	ion	NOUN
eurjchem-952	222	32	with	with	ADP
eurjchem-952	222	33	donor	donor	NOUN
eurjchem-952	222	34	groups	group	NOUN
eurjchem-952	222	35	.	.	PUNCT
eurjchem-952	223	1	in	in	ADP
eurjchem-952	223	2	addition	addition	NOUN
eurjchem-952	223	3	,	,	PUNCT
eurjchem-952	223	4	chelation	chelation	NOUN
eurjchem-952	223	5	allows	allow	VERB
eurjchem-952	223	6	for	for	ADP
eurjchem-952	223	7	the	the	DET
eurjchem-952	223	8	delocalization	delocalization	NOUN
eurjchem-952	223	9	of	of	ADP
eurjchem-952	223	10	π‐electrons	π‐electron	NOUN
eurjchem-952	223	11	over	over	ADP
eurjchem-952	223	12	the	the	DET
eurjchem-952	223	13	entire	entire	ADJ
eurjchem-952	223	14	chelate	chelate	NOUN
eurjchem-952	223	15	ring	ring	NOUN
eurjchem-952	223	16	and	and	CCONJ
eurjchem-952	223	17	enhances	enhance	VERB
eurjchem-952	223	18	the	the	DET
eurjchem-952	223	19	lipophilicity	lipophilicity	NOUN
eurjchem-952	223	20	of	of	ADP
eurjchem-952	223	21	the	the	DET
eurjchem-952	223	22	complexes	complex	NOUN
eurjchem-952	223	23	.	.	PUNCT
eurjchem-952	224	1	this	this	DET
eurjchem-952	224	2	increased	increase	VERB
eurjchem-952	224	3	lipophilicity	lipophilicity	NOUN
eurjchem-952	224	4	facilitates	facilitate	VERB
eurjchem-952	224	5	the	the	DET
eurjchem-952	224	6	penetration	penetration	NOUN
eurjchem-952	224	7	of	of	ADP
eurjchem-952	224	8	the	the	DET
eurjchem-952	224	9	complexes	complex	NOUN
eurjchem-952	224	10	into	into	ADP
eurjchem-952	224	11	lipid	lipid	ADJ
eurjchem-952	224	12	membranes	membrane	NOUN
eurjchem-952	224	13	,	,	PUNCT
eurjchem-952	224	14	further	far	ADV
eurjchem-952	224	15	restricting	restrict	VERB
eurjchem-952	224	16	proliferation	proliferation	NOUN
eurjchem-952	224	17	of	of	ADP
eurjchem-952	224	18	the	the	DET
eurjchem-952	224	19	microorganisms	microorganism	NOUN
eurjchem-952	224	20	.	.	PUNCT
eurjchem-952	225	1	the	the	DET
eurjchem-952	225	2	variation	variation	NOUN
eurjchem-952	225	3	in	in	ADP
eurjchem-952	225	4	the	the	DET
eurjchem-952	225	5	effectiveness	effectiveness	NOUN
eurjchem-952	225	6	of	of	ADP
eurjchem-952	225	7	different	different	ADJ
eurjchem-952	225	8	compounds	compound	NOUN
eurjchem-952	225	9	against	against	ADP
eurjchem-952	225	10	different	different	ADJ
eurjchem-952	225	11	organisms	organism	NOUN
eurjchem-952	225	12	depends	depend	VERB
eurjchem-952	225	13	either	either	CCONJ
eurjchem-952	225	14	on	on	ADP
eurjchem-952	225	15	the	the	DET
eurjchem-952	225	16	impermeability	impermeability	NOUN
eurjchem-952	225	17	of	of	ADP
eurjchem-952	225	18	the	the	DET
eurjchem-952	225	19	microbial	microbial	ADJ
eurjchem-952	225	20	cells	cell	NOUN
eurjchem-952	225	21	or	or	CCONJ
eurjchem-952	225	22	on	on	ADP
eurjchem-952	225	23	differences	difference	NOUN
eurjchem-952	225	24	in	in	ADP
eurjchem-952	225	25	the	the	DET
eurjchem-952	225	26	ribosomes	ribosome	NOUN
eurjchem-952	225	27	of	of	ADP
eurjchem-952	225	28	the	the	DET
eurjchem-952	225	29	cells	cell	NOUN
eurjchem-952	225	30	[	[	X
eurjchem-952	225	31	58	58	NUM
eurjchem-952	225	32	]	]	PUNCT
eurjchem-952	225	33	.	.	PUNCT
eurjchem-952	226	1	all	all	PRON
eurjchem-952	226	2	of	of	ADP
eurjchem-952	226	3	the	the	DET
eurjchem-952	226	4	metal	metal	NOUN
eurjchem-952	226	5	complexes	complex	NOUN
eurjchem-952	226	6	possess	possess	VERB
eurjchem-952	226	7	higher	high	ADJ
eurjchem-952	226	8	antifungal	antifungal	ADJ
eurjchem-952	226	9	activity	activity	NOUN
eurjchem-952	226	10	than	than	ADP
eurjchem-952	226	11	the	the	DET
eurjchem-952	226	12	free	free	ADJ
eurjchem-952	226	13	ligand	ligand	NOUN
eurjchem-952	226	14	[	[	X
eurjchem-952	226	15	59,60	59,60	NUM
eurjchem-952	226	16	]	]	PUNCT
eurjchem-952	226	17	.	.	PUNCT
eurjchem-952	227	1	although	although	SCONJ
eurjchem-952	227	2	the	the	DET
eurjchem-952	227	3	exact	exact	ADJ
eurjchem-952	227	4	biochemical	biochemical	ADJ
eurjchem-952	227	5	mechanism	mechanism	NOUN
eurjchem-952	227	6	is	be	AUX
eurjchem-952	227	7	not	not	PART
eurjchem-952	227	8	completely	completely	ADV
eurjchem-952	227	9	understood	understand	VERB
eurjchem-952	227	10	,	,	PUNCT
eurjchem-952	227	11	the	the	DET
eurjchem-952	227	12	mode	mode	NOUN
eurjchem-952	227	13	of	of	ADP
eurjchem-952	227	14	action	action	NOUN
eurjchem-952	227	15	of	of	ADP
eurjchem-952	227	16	antimicrobials	antimicrobial	NOUN
eurjchem-952	227	17	may	may	AUX
eurjchem-952	227	18	involve	involve	VERB
eurjchem-952	227	19	various	various	ADJ
eurjchem-952	227	20	targets	target	NOUN
eurjchem-952	227	21	in	in	ADP
eurjchem-952	227	22	the	the	DET
eurjchem-952	227	23	microorganisms	microorganism	NOUN
eurjchem-952	227	24	.	.	PUNCT
eurjchem-952	228	1	these	these	DET
eurjchem-952	228	2	targets	target	NOUN
eurjchem-952	228	3	include	include	VERB
eurjchem-952	228	4	the	the	DET
eurjchem-952	228	5	following	following	NOUN
eurjchem-952	228	6	.	.	PUNCT
eurjchem-952	229	1	(	(	PUNCT
eurjchem-952	229	2	i	i	NOUN
eurjchem-952	229	3	)	)	PUNCT
eurjchem-952	229	4	the	the	DET
eurjchem-952	229	5	higher	high	ADJ
eurjchem-952	229	6	activity	activity	NOUN
eurjchem-952	229	7	of	of	ADP
eurjchem-952	229	8	the	the	DET
eurjchem-952	229	9	metal	metal	NOUN
eurjchem-952	229	10	complexes	complex	NOUN
eurjchem-952	229	11	may	may	AUX
eurjchem-952	229	12	be	be	AUX
eurjchem-952	229	13	due	due	ADJ
eurjchem-952	229	14	to	to	ADP
eurjchem-952	229	15	the	the	DET
eurjchem-952	229	16	different	different	ADJ
eurjchem-952	229	17	properties	property	NOUN
eurjchem-952	229	18	of	of	ADP
eurjchem-952	229	19	the	the	DET
eurjchem-952	229	20	metal	metal	NOUN
eurjchem-952	229	21	ions	ion	NOUN
eurjchem-952	229	22	upon	upon	SCONJ
eurjchem-952	229	23	chelation	chelation	NOUN
eurjchem-952	229	24	.	.	PUNCT
eurjchem-952	230	1	the	the	DET
eurjchem-952	230	2	polarity	polarity	NOUN
eurjchem-952	230	3	of	of	ADP
eurjchem-952	230	4	the	the	DET
eurjchem-952	230	5	metal	metal	NOUN
eurjchem-952	230	6	ions	ion	NOUN
eurjchem-952	230	7	will	will	AUX
eurjchem-952	230	8	be	be	AUX
eurjchem-952	230	9	reduced	reduce	VERB
eurjchem-952	230	10	due	due	ADP
eurjchem-952	230	11	to	to	ADP
eurjchem-952	230	12	the	the	DET
eurjchem-952	230	13	overlap	overlap	NOUN
eurjchem-952	230	14	of	of	ADP
eurjchem-952	230	15	the	the	DET
eurjchem-952	230	16	ligand	ligand	NOUN
eurjchem-952	230	17	orbitals	orbital	NOUN
eurjchem-952	230	18	and	and	CCONJ
eurjchem-952	230	19	partial	partial	ADJ
eurjchem-952	230	20	sharing	sharing	NOUN
eurjchem-952	230	21	of	of	ADP
eurjchem-952	230	22	the	the	DET
eurjchem-952	230	23	positive	positive	ADJ
eurjchem-952	230	24	charge	charge	NOUN
eurjchem-952	230	25	of	of	ADP
eurjchem-952	230	26	the	the	DET
eurjchem-952	230	27	metal	metal	NOUN
eurjchem-952	230	28	ion	ion	NOUN
eurjchem-952	230	29	with	with	ADP
eurjchem-952	230	30	donor	donor	NOUN
eurjchem-952	230	31	groups	group	NOUN
eurjchem-952	230	32	.	.	PUNCT
eurjchem-952	231	1	thus	thus	ADV
eurjchem-952	231	2	,	,	PUNCT
eurjchem-952	231	3	chelation	chelation	NOUN
eurjchem-952	231	4	enhances	enhance	VERB
eurjchem-952	231	5	the	the	DET
eurjchem-952	231	6	penetration	penetration	NOUN
eurjchem-952	231	7	of	of	ADP
eurjchem-952	231	8	the	the	DET
eurjchem-952	231	9	complexes	complex	NOUN
eurjchem-952	231	10	into	into	ADP
eurjchem-952	231	11	lipid	lipid	ADJ
eurjchem-952	231	12	membranes	membrane	NOUN
eurjchem-952	231	13	and	and	CCONJ
eurjchem-952	231	14	the	the	DET
eurjchem-952	231	15	blockage	blockage	NOUN
eurjchem-952	231	16	of	of	ADP
eurjchem-952	231	17	metal	metal	NOUN
eurjchem-952	231	18	binding	bind	VERB
eurjchem-952	231	19	sites	site	NOUN
eurjchem-952	231	20	in	in	ADP
eurjchem-952	231	21	the	the	DET
eurjchem-952	231	22	enzymes	enzyme	NOUN
eurjchem-952	231	23	of	of	ADP
eurjchem-952	231	24	the	the	DET
eurjchem-952	231	25	microorganisms	microorganism	NOUN
eurjchem-952	231	26	[	[	X
eurjchem-952	231	27	61	61	NUM
eurjchem-952	231	28	]	]	PUNCT
eurjchem-952	231	29	.	.	PUNCT
eurjchem-952	232	1	(	(	PUNCT
eurjchem-952	232	2	ii	ii	X
eurjchem-952	232	3	)	)	PUNCT
eurjchem-952	232	4	tweedy	tweedy	PROPN
eurjchem-952	232	5	’s	’s	PART
eurjchem-952	232	6	chelation	chelation	NOUN
eurjchem-952	232	7	theory	theory	NOUN
eurjchem-952	232	8	predicts	predict	VERB
eurjchem-952	232	9	that	that	SCONJ
eurjchem-952	232	10	chelation	chelation	NOUN
eurjchem-952	232	11	reduces	reduce	VERB
eurjchem-952	232	12	the	the	DET
eurjchem-952	232	13	polarity	polarity	NOUN
eurjchem-952	232	14	of	of	ADP
eurjchem-952	232	15	the	the	DET
eurjchem-952	232	16	metal	metal	NOUN
eurjchem-952	232	17	atom	atom	NOUN
eurjchem-952	232	18	mainly	mainly	ADV
eurjchem-952	232	19	because	because	SCONJ
eurjchem-952	232	20	of	of	ADP
eurjchem-952	232	21	partial	partial	ADJ
eurjchem-952	232	22	sharing	sharing	NOUN
eurjchem-952	232	23	of	of	ADP
eurjchem-952	232	24	its	its	PRON
eurjchem-952	232	25	positive	positive	ADJ
eurjchem-952	232	26	charge	charge	NOUN
eurjchem-952	232	27	with	with	ADP
eurjchem-952	232	28	donor	donor	NOUN
eurjchem-952	232	29	groups	group	NOUN
eurjchem-952	232	30	and	and	CCONJ
eurjchem-952	232	31	possible	possible	ADJ
eurjchem-952	232	32	electron	electron	NOUN
eurjchem-952	232	33	delocalization	delocalization	NOUN
eurjchem-952	232	34	over	over	ADP
eurjchem-952	232	35	the	the	DET
eurjchem-952	232	36	entire	entire	ADJ
eurjchem-952	232	37	ring	ring	NOUN
eurjchem-952	232	38	.	.	PUNCT
eurjchem-952	233	1	this	this	PRON
eurjchem-952	233	2	consequently	consequently	ADV
eurjchem-952	233	3	increases	increase	VERB
eurjchem-952	233	4	the	the	DET
eurjchem-952	233	5	lipophilic	lipophilic	ADJ
eurjchem-952	233	6	character	character	NOUN
eurjchem-952	233	7	of	of	ADP
eurjchem-952	233	8	the	the	DET
eurjchem-952	233	9	chelates	chelate	NOUN
eurjchem-952	233	10	,	,	PUNCT
eurjchem-952	233	11	favoring	favor	VERB
eurjchem-952	233	12	their	their	PRON
eurjchem-952	233	13	permeation	permeation	NOUN
eurjchem-952	233	14	through	through	ADP
eurjchem-952	233	15	the	the	DET
eurjchem-952	233	16	lipid	lipid	ADJ
eurjchem-952	233	17	layers	layer	NOUN
eurjchem-952	233	18	of	of	ADP
eurjchem-952	233	19	the	the	DET
eurjchem-952	233	20	bacterial	bacterial	ADJ
eurjchem-952	233	21	membrane	membrane	NOUN
eurjchem-952	233	22	[	[	X
eurjchem-952	233	23	62	62	NUM
eurjchem-952	233	24	]	]	PUNCT
eurjchem-952	233	25	.	.	PUNCT
eurjchem-952	234	1	(	(	PUNCT
eurjchem-952	234	2	iii	iii	X
eurjchem-952	234	3	)	)	PUNCT
eurjchem-952	234	4	interference	interference	NOUN
eurjchem-952	234	5	with	with	ADP
eurjchem-952	234	6	the	the	DET
eurjchem-952	234	7	synthesis	synthesis	NOUN
eurjchem-952	234	8	of	of	ADP
eurjchem-952	234	9	cellular	cellular	ADJ
eurjchem-952	234	10	walls	wall	NOUN
eurjchem-952	234	11	,	,	PUNCT
eurjchem-952	234	12	causing	cause	VERB
eurjchem-952	234	13	damage	damage	NOUN
eurjchem-952	234	14	that	that	PRON
eurjchem-952	234	15	can	can	AUX
eurjchem-952	234	16	lead	lead	VERB
eurjchem-952	234	17	to	to	ADP
eurjchem-952	234	18	altered	altered	ADJ
eurjchem-952	234	19	cell	cell	NOUN
eurjchem-952	234	20	permeability	permeability	NOUN
eurjchem-952	234	21	206	206	NUM
eurjchem-952	234	22	aljahdali	aljahdali	PROPN
eurjchem-952	234	23	et	et	PROPN
eurjchem-952	234	24	al	al	PROPN
eurjchem-952	234	25	.	.	PUNCT
eurjchem-952	234	26	/	/	SYM
eurjchem-952	234	27	european	european	PROPN
eurjchem-952	234	28	journal	journal	PROPN
eurjchem-952	234	29	of	of	ADP
eurjchem-952	234	30	chemistry	chemistry	NOUN
eurjchem-952	234	31	5	5	NUM
eurjchem-952	234	32	(	(	PUNCT
eurjchem-952	234	33	2	2	NUM
eurjchem-952	234	34	)	)	PUNCT
eurjchem-952	234	35	(	(	PUNCT
eurjchem-952	234	36	2014	2014	NUM
eurjchem-952	234	37	)	)	PUNCT
eurjchem-952	234	38	201‐208	201‐208	NUM
eurjchem-952	234	39	table	table	NOUN
eurjchem-952	234	40	4	4	NUM
eurjchem-952	234	41	.	.	PUNCT
eurjchem-952	234	42	effect	effect	NOUN
eurjchem-952	234	43	of	of	ADP
eurjchem-952	234	44	synthesized	synthesize	VERB
eurjchem-952	234	45	metal	metal	NOUN
eurjchem-952	234	46	complexes	complex	NOUN
eurjchem-952	234	47	on	on	ADP
eurjchem-952	234	48	tumor	tumor	NOUN
eurjchem-952	234	49	cell	cell	NOUN
eurjchem-952	234	50	growth	growth	NOUN
eurjchem-952	234	51	in	in	ADP
eurjchem-952	234	52	vitro	vitro	X
eurjchem-952	234	53	(	(	PUNCT
eurjchem-952	234	54	ic50	ic50	PROPN
eurjchem-952	234	55	values	value	NOUN
eurjchem-952	234	56	in	in	ADP
eurjchem-952	234	57	μg	μg	PROPN
eurjchem-952	234	58	/	/	SYM
eurjchem-952	234	59	ml	ml	NOUN
eurjchem-952	234	60	)	)	PUNCT
eurjchem-952	234	61	.	.	PUNCT
eurjchem-952	235	1	compounds	compound	VERB
eurjchem-952	235	2	ic50	ic50	PROPN
eurjchem-952	235	3	hct116	hct116	PROPN
eurjchem-952	235	4	hep2	hep2	PROPN
eurjchem-952	235	5	[	[	X
eurjchem-952	235	6	cu(mpapt)(1,10‐phen)cl	cu(mpapt)(1,10‐phen)cl	X
eurjchem-952	235	7	]	]	X
eurjchem-952	235	8	(	(	PUNCT
eurjchem-952	235	9	1	1	NUM
eurjchem-952	235	10	)	)	PUNCT
eurjchem-952	235	11	0.63	0.63	NUM
eurjchem-952	235	12	0.41	0.41	NUM
eurjchem-952	236	1	[	[	X
eurjchem-952	236	2	ni(mpapt)(1,10‐phen)cl	ni(mpapt)(1,10‐phen)cl	X
eurjchem-952	236	3	]	]	X
eurjchem-952	236	4	(	(	PUNCT
eurjchem-952	236	5	2	2	NUM
eurjchem-952	236	6	)	)	PUNCT
eurjchem-952	236	7	0.91	0.91	NUM
eurjchem-952	236	8	0.66	0.66	NUM
eurjchem-952	237	1	[	[	X
eurjchem-952	237	2	co(mpapt)(1,10‐phen)cl].h2o	co(mpapt)(1,10‐phen)cl].h2o	X
eurjchem-952	237	3	(	(	PUNCT
eurjchem-952	237	4	3	3	NUM
eurjchem-952	237	5	)	)	PUNCT
eurjchem-952	237	6	1.11	1.11	NUM
eurjchem-952	237	7	0.78	0.78	NUM
eurjchem-952	237	8	[	[	X
eurjchem-952	237	9	mn(mpapt)(1,10‐phen)cl].h2o	mn(mpapt)(1,10‐phen)cl].h2o	NOUN
eurjchem-952	237	10	(	(	PUNCT
eurjchem-952	237	11	4	4	NUM
eurjchem-952	237	12	)	)	PUNCT
eurjchem-952	237	13	1.35	1.35	NUM
eurjchem-952	237	14	0.81	0.81	NUM
eurjchem-952	237	15	doxorubicin	doxorubicin	PROPN
eurjchem-952	237	16	(	(	PUNCT
eurjchem-952	237	17	standard	standard	NOUN
eurjchem-952	237	18	)	)	PUNCT
eurjchem-952	237	19	0.69	0.69	NUM
eurjchem-952	237	20	0.40	0.40	NUM
eurjchem-952	237	21	ic50	ic50	PROPN
eurjchem-952	237	22	=	=	SYM
eurjchem-952	237	23	cytotoxic	cytotoxic	NOUN
eurjchem-952	237	24	dose	dose	VERB
eurjchem-952	237	25	at	at	ADP
eurjchem-952	237	26	50	50	NUM
eurjchem-952	237	27	%	%	NOUN
eurjchem-952	237	28	,	,	PUNCT
eurjchem-952	237	29	i.e.	i.e.	X
eurjchem-952	237	30	the	the	DET
eurjchem-952	237	31	drug	drug	NOUN
eurjchem-952	237	32	concentration	concentration	NOUN
eurjchem-952	237	33	to	to	PART
eurjchem-952	237	34	inhibit	inhibit	VERB
eurjchem-952	237	35	the	the	DET
eurjchem-952	237	36	growth	growth	NOUN
eurjchem-952	237	37	of	of	ADP
eurjchem-952	237	38	the	the	DET
eurjchem-952	237	39	cancer	cancer	NOUN
eurjchem-952	237	40	cells	cell	NOUN
eurjchem-952	237	41	by	by	ADP
eurjchem-952	237	42	50	50	NUM
eurjchem-952	237	43	%	%	NOUN
eurjchem-952	237	44	.	.	PUNCT
eurjchem-952	238	1	characteristics	characteristic	NOUN
eurjchem-952	238	2	or	or	CCONJ
eurjchem-952	238	3	disorganized	disorganized	ADJ
eurjchem-952	238	4	lipoprotein	lipoprotein	ADJ
eurjchem-952	238	5	arrangements	arrangement	NOUN
eurjchem-952	238	6	,	,	PUNCT
eurjchem-952	238	7	ultimately	ultimately	ADV
eurjchem-952	238	8	resulting	result	VERB
eurjchem-952	238	9	in	in	ADP
eurjchem-952	238	10	cell	cell	NOUN
eurjchem-952	238	11	death	death	NOUN
eurjchem-952	238	12	.	.	PUNCT
eurjchem-952	239	1	(	(	PUNCT
eurjchem-952	239	2	iv	iv	X
eurjchem-952	239	3	)	)	PUNCT
eurjchem-952	239	4	deactivation	deactivation	NOUN
eurjchem-952	239	5	of	of	ADP
eurjchem-952	239	6	various	various	ADJ
eurjchem-952	239	7	cellular	cellular	ADJ
eurjchem-952	239	8	enzymes	enzyme	NOUN
eurjchem-952	239	9	that	that	PRON
eurjchem-952	239	10	play	play	VERB
eurjchem-952	239	11	a	a	DET
eurjchem-952	239	12	vital	vital	ADJ
eurjchem-952	239	13	role	role	NOUN
eurjchem-952	239	14	in	in	ADP
eurjchem-952	239	15	the	the	DET
eurjchem-952	239	16	metabolic	metabolic	NOUN
eurjchem-952	239	17	pathways	pathway	NOUN
eurjchem-952	239	18	of	of	ADP
eurjchem-952	239	19	these	these	DET
eurjchem-952	239	20	microorganisms	microorganism	NOUN
eurjchem-952	239	21	.	.	PUNCT
eurjchem-952	240	1	(	(	PUNCT
eurjchem-952	240	2	v	v	NOUN
eurjchem-952	240	3	)	)	PUNCT
eurjchem-952	240	4	denaturation	denaturation	NOUN
eurjchem-952	240	5	of	of	ADP
eurjchem-952	240	6	one	one	NUM
eurjchem-952	240	7	or	or	CCONJ
eurjchem-952	240	8	more	more	ADJ
eurjchem-952	240	9	cellular	cellular	ADJ
eurjchem-952	240	10	proteins	protein	NOUN
eurjchem-952	240	11	,	,	PUNCT
eurjchem-952	240	12	causing	cause	VERB
eurjchem-952	240	13	the	the	DET
eurjchem-952	240	14	normal	normal	ADJ
eurjchem-952	240	15	cellular	cellular	ADJ
eurjchem-952	240	16	processes	process	NOUN
eurjchem-952	240	17	to	to	PART
eurjchem-952	240	18	be	be	AUX
eurjchem-952	240	19	impaired	impaired	ADJ
eurjchem-952	240	20	.	.	PUNCT
eurjchem-952	241	1	(	(	PUNCT
eurjchem-952	241	2	vi	vi	NOUN
eurjchem-952	241	3	)	)	PUNCT
eurjchem-952	241	4	formation	formation	NOUN
eurjchem-952	241	5	of	of	ADP
eurjchem-952	241	6	a	a	DET
eurjchem-952	241	7	hydrogen	hydrogen	NOUN
eurjchem-952	241	8	bond	bond	NOUN
eurjchem-952	241	9	through	through	ADP
eurjchem-952	241	10	the	the	DET
eurjchem-952	241	11	azomethine	azomethine	NOUN
eurjchem-952	241	12	group	group	NOUN
eurjchem-952	241	13	with	with	ADP
eurjchem-952	241	14	the	the	DET
eurjchem-952	241	15	active	active	ADJ
eurjchem-952	241	16	centers	center	NOUN
eurjchem-952	241	17	of	of	ADP
eurjchem-952	241	18	various	various	ADJ
eurjchem-952	241	19	cellular	cellular	ADJ
eurjchem-952	241	20	constituents	constituent	NOUN
eurjchem-952	241	21	,	,	PUNCT
eurjchem-952	241	22	resulting	result	VERB
eurjchem-952	241	23	in	in	ADP
eurjchem-952	241	24	interference	interference	NOUN
eurjchem-952	241	25	with	with	ADP
eurjchem-952	241	26	normal	normal	ADJ
eurjchem-952	241	27	cellular	cellular	ADJ
eurjchem-952	241	28	processes	process	NOUN
eurjchem-952	241	29	[	[	X
eurjchem-952	241	30	63‐65	63‐65	NUM
eurjchem-952	241	31	]	]	PUNCT
eurjchem-952	241	32	.	.	PUNCT
eurjchem-952	242	1	the	the	DET
eurjchem-952	242	2	tested	test	VERB
eurjchem-952	242	3	complexes	complex	NOUN
eurjchem-952	242	4	were	be	AUX
eurjchem-952	242	5	more	more	ADV
eurjchem-952	242	6	active	active	ADJ
eurjchem-952	242	7	against	against	ADP
eurjchem-952	242	8	gram(+	gram(+	NOUN
eurjchem-952	242	9	)	)	PUNCT
eurjchem-952	242	10	than	than	ADP
eurjchem-952	242	11	gram(‐	gram(‐	NOUN
eurjchem-952	242	12	)	)	PUNCT
eurjchem-952	242	13	bacteria	bacteria	NOUN
eurjchem-952	242	14	,	,	PUNCT
eurjchem-952	242	15	it	it	PRON
eurjchem-952	242	16	may	may	AUX
eurjchem-952	242	17	be	be	AUX
eurjchem-952	242	18	concluded	conclude	VERB
eurjchem-952	242	19	that	that	SCONJ
eurjchem-952	242	20	the	the	DET
eurjchem-952	242	21	antibac‐	antibac‐	ADJ
eurjchem-952	242	22	terial	terial	ADJ
eurjchem-952	242	23	activity	activity	NOUN
eurjchem-952	242	24	of	of	ADP
eurjchem-952	242	25	the	the	DET
eurjchem-952	242	26	compounds	compound	NOUN
eurjchem-952	242	27	is	be	AUX
eurjchem-952	242	28	related	relate	VERB
eurjchem-952	242	29	to	to	ADP
eurjchem-952	242	30	cell	cell	NOUN
eurjchem-952	242	31	wall	wall	NOUN
eurjchem-952	242	32	structure	structure	NOUN
eurjchem-952	242	33	of	of	ADP
eurjchem-952	242	34	the	the	DET
eurjchem-952	242	35	bacteria	bacteria	NOUN
eurjchem-952	242	36	.	.	PUNCT
eurjchem-952	243	1	it	it	PRON
eurjchem-952	243	2	is	be	AUX
eurjchem-952	243	3	possible	possible	ADJ
eurjchem-952	243	4	because	because	SCONJ
eurjchem-952	243	5	the	the	DET
eurjchem-952	243	6	cell	cell	NOUN
eurjchem-952	243	7	wall	wall	NOUN
eurjchem-952	243	8	is	be	AUX
eurjchem-952	243	9	essential	essential	ADJ
eurjchem-952	243	10	to	to	ADP
eurjchem-952	243	11	the	the	DET
eurjchem-952	243	12	survival	survival	NOUN
eurjchem-952	243	13	of	of	ADP
eurjchem-952	243	14	bacteria	bacteria	NOUN
eurjchem-952	243	15	and	and	CCONJ
eurjchem-952	243	16	some	some	DET
eurjchem-952	243	17	antibiotics	antibiotic	NOUN
eurjchem-952	243	18	are	be	AUX
eurjchem-952	243	19	able	able	ADJ
eurjchem-952	243	20	to	to	PART
eurjchem-952	243	21	kill	kill	VERB
eurjchem-952	243	22	bacteria	bacteria	NOUN
eurjchem-952	243	23	by	by	ADP
eurjchem-952	243	24	inhibiting	inhibit	VERB
eurjchem-952	243	25	a	a	DET
eurjchem-952	243	26	step	step	NOUN
eurjchem-952	243	27	in	in	ADP
eurjchem-952	243	28	the	the	DET
eurjchem-952	243	29	synthesis	synthesis	NOUN
eurjchem-952	243	30	of	of	ADP
eurjchem-952	243	31	peptidoglycan	peptidoglycan	ADJ
eurjchem-952	243	32	.	.	PUNCT
eurjchem-952	244	1	gram‐positive	gram‐positive	ADJ
eurjchem-952	244	2	bacteria	bacteria	NOUN
eurjchem-952	244	3	possess	possess	VERB
eurjchem-952	244	4	a	a	DET
eurjchem-952	244	5	thick	thick	ADJ
eurjchem-952	244	6	cell	cell	NOUN
eurjchem-952	244	7	wall	wall	NOUN
eurjchem-952	244	8	containing	contain	VERB
eurjchem-952	244	9	many	many	ADJ
eurjchem-952	244	10	layers	layer	NOUN
eurjchem-952	244	11	of	of	ADP
eurjchem-952	244	12	peptidoglycan	peptidoglycan	ADJ
eurjchem-952	244	13	and	and	CCONJ
eurjchem-952	244	14	teichoic	teichoic	ADJ
eurjchem-952	244	15	acids	acid	NOUN
eurjchem-952	244	16	,	,	PUNCT
eurjchem-952	244	17	but	but	CCONJ
eurjchem-952	244	18	in	in	ADP
eurjchem-952	244	19	contrast	contrast	NOUN
eurjchem-952	244	20	,	,	PUNCT
eurjchem-952	244	21	gram	gram	PROPN
eurjchem-952	244	22	negative	negative	ADJ
eurjchem-952	244	23	bacteria	bacteria	NOUN
eurjchem-952	244	24	have	have	VERB
eurjchem-952	244	25	a	a	DET
eurjchem-952	244	26	relatively	relatively	ADV
eurjchem-952	244	27	thin	thin	ADJ
eurjchem-952	244	28	cell	cell	NOUN
eurjchem-952	244	29	wall	wall	NOUN
eurjchem-952	244	30	consisting	consist	VERB
eurjchem-952	244	31	of	of	ADP
eurjchem-952	244	32	a	a	DET
eurjchem-952	244	33	few	few	ADJ
eurjchem-952	244	34	layers	layer	NOUN
eurjchem-952	244	35	of	of	ADP
eurjchem-952	244	36	peptidoglycan	peptidoglycan	PROPN
eurjchem-952	244	37	surrounded	surround	VERB
eurjchem-952	244	38	by	by	ADP
eurjchem-952	244	39	a	a	DET
eurjchem-952	244	40	second	second	ADJ
eurjchem-952	244	41	lipid	lipid	NOUN
eurjchem-952	244	42	membrane	membrane	NOUN
eurjchem-952	244	43	containing	contain	VERB
eurjchem-952	244	44	lipopolysaccharides	lipopolysaccharide	NOUN
eurjchem-952	244	45	and	and	CCONJ
eurjchem-952	244	46	lipoproteins	lipoprotein	NOUN
eurjchem-952	244	47	.	.	PUNCT
eurjchem-952	245	1	these	these	DET
eurjchem-952	245	2	differences	difference	NOUN
eurjchem-952	245	3	in	in	ADP
eurjchem-952	245	4	cell	cell	NOUN
eurjchem-952	245	5	wall	wall	NOUN
eurjchem-952	245	6	structure	structure	NOUN
eurjchem-952	245	7	can	can	AUX
eurjchem-952	245	8	produce	produce	VERB
eurjchem-952	245	9	differences	difference	NOUN
eurjchem-952	245	10	in	in	ADP
eurjchem-952	245	11	antibacterial	antibacterial	ADJ
eurjchem-952	245	12	susceptibility	susceptibility	NOUN
eurjchem-952	245	13	and	and	CCONJ
eurjchem-952	245	14	some	some	DET
eurjchem-952	245	15	antibiotics	antibiotic	NOUN
eurjchem-952	245	16	can	can	AUX
eurjchem-952	245	17	kill	kill	VERB
eurjchem-952	245	18	only	only	ADV
eurjchem-952	245	19	gram‐positive	gram‐positive	ADJ
eurjchem-952	245	20	bacteria	bacteria	NOUN
eurjchem-952	245	21	and	and	CCONJ
eurjchem-952	245	22	is	be	AUX
eurjchem-952	245	23	ineffective	ineffective	ADJ
eurjchem-952	245	24	against	against	ADP
eurjchem-952	245	25	gram‐negative	gram‐negative	ADJ
eurjchem-952	245	26	pathogens	pathogen	NOUN
eurjchem-952	245	27	[	[	X
eurjchem-952	245	28	66,67	66,67	NOUN
eurjchem-952	245	29	]	]	PUNCT
eurjchem-952	245	30	.	.	PUNCT
eurjchem-952	246	1	it	it	PRON
eurjchem-952	246	2	is	be	AUX
eurjchem-952	246	3	worth	worth	ADJ
eurjchem-952	246	4	noting	note	VERB
eurjchem-952	246	5	that	that	SCONJ
eurjchem-952	246	6	the	the	DET
eurjchem-952	246	7	comparison	comparison	NOUN
eurjchem-952	246	8	of	of	ADP
eurjchem-952	246	9	antimicrobial	antimicrobial	ADJ
eurjchem-952	246	10	activity	activity	NOUN
eurjchem-952	246	11	of	of	ADP
eurjchem-952	246	12	the	the	DET
eurjchem-952	246	13	compounds	compound	NOUN
eurjchem-952	246	14	against	against	ADP
eurjchem-952	246	15	the	the	DET
eurjchem-952	246	16	selected	select	VERB
eurjchem-952	246	17	types	type	NOUN
eurjchem-952	246	18	of	of	ADP
eurjchem-952	246	19	bacteria	bacteria	NOUN
eurjchem-952	246	20	(	(	PUNCT
eurjchem-952	246	21	figure	figure	NOUN
eurjchem-952	246	22	1	1	NUM
eurjchem-952	246	23	and	and	CCONJ
eurjchem-952	246	24	2	2	NUM
eurjchem-952	246	25	)	)	PUNCT
eurjchem-952	246	26	indicates	indicate	VERB
eurjchem-952	246	27	that	that	SCONJ
eurjchem-952	246	28	cu(ii	cu(ii	PROPN
eurjchem-952	246	29	)	)	PUNCT
eurjchem-952	246	30			PROPN
eurjchem-952	246	31	ni(ii	ni(ii	PROPN
eurjchem-952	246	32	)	)	PUNCT
eurjchem-952	246	33			PROPN
eurjchem-952	246	34	co(ii	co(ii	PROPN
eurjchem-952	246	35	)	)	PUNCT
eurjchem-952	246	36			PROPN
eurjchem-952	246	37	mn(ii	mn(ii	PROPN
eurjchem-952	246	38	)	)	PUNCT
eurjchem-952	246	39	.	.	PUNCT
eurjchem-952	247	1	figure	figure	NOUN
eurjchem-952	247	2	1	1	NUM
eurjchem-952	247	3	.	.	PUNCT
eurjchem-952	247	4	antibacterial	antibacterial	ADJ
eurjchem-952	247	5	activity	activity	NOUN
eurjchem-952	247	6	of	of	ADP
eurjchem-952	247	7	m(ii)‐complexes	m(ii)‐complexe	NOUN
eurjchem-952	247	8	towards	towards	ADP
eurjchem-952	247	9	different	different	ADJ
eurjchem-952	247	10	types	type	NOUN
eurjchem-952	247	11	of	of	ADP
eurjchem-952	247	12	bacterial	bacterial	ADJ
eurjchem-952	247	13	strains	strain	NOUN
eurjchem-952	247	14	.	.	PUNCT
eurjchem-952	248	1	figure	figure	NOUN
eurjchem-952	248	2	2	2	NUM
eurjchem-952	248	3	.	.	PUNCT
eurjchem-952	248	4	antifungal	antifungal	ADJ
eurjchem-952	248	5	activity	activity	NOUN
eurjchem-952	248	6	of	of	ADP
eurjchem-952	248	7	m(ii)‐complexes	m(ii)‐complexe	NOUN
eurjchem-952	248	8	towards	towards	ADP
eurjchem-952	248	9	different	different	ADJ
eurjchem-952	248	10	types	type	NOUN
eurjchem-952	248	11	of	of	ADP
eurjchem-952	248	12	fungal	fungal	ADJ
eurjchem-952	248	13	strains	strain	NOUN
eurjchem-952	248	14	.	.	PUNCT
eurjchem-952	249	1	3.5.2	3.5.2	X
eurjchem-952	249	2	.	.	PUNCT
eurjchem-952	249	3	cytotoxic	cytotoxic	ADJ
eurjchem-952	249	4	activities	activity	NOUN
eurjchem-952	249	5	cytotoxic	cytotoxic	ADJ
eurjchem-952	249	6	study	study	NOUN
eurjchem-952	249	7	of	of	ADP
eurjchem-952	249	8	the	the	DET
eurjchem-952	249	9	compounds	compound	NOUN
eurjchem-952	249	10	against	against	ADP
eurjchem-952	249	11	colon	colon	NOUN
eurjchem-952	249	12	carcinoma	carcinoma	NOUN
eurjchem-952	249	13	(	(	PUNCT
eurjchem-952	249	14	hct116	hct116	PROPN
eurjchem-952	249	15	)	)	PUNCT
eurjchem-952	249	16	and	and	CCONJ
eurjchem-952	249	17	larynx	larynx	NOUN
eurjchem-952	249	18	carcinoma	carcinoma	NOUN
eurjchem-952	249	19	(	(	PUNCT
eurjchem-952	249	20	hep2	hep2	PROPN
eurjchem-952	249	21	)	)	PUNCT
eurjchem-952	249	22	cells	cell	NOUN
eurjchem-952	249	23	indicate	indicate	VERB
eurjchem-952	249	24	that	that	SCONJ
eurjchem-952	249	25	,	,	PUNCT
eurjchem-952	249	26	[	[	X
eurjchem-952	249	27	cu(mpapt)(1,10‐phen)cl	cu(mpapt)(1,10‐phen)cl	NOUN
eurjchem-952	249	28	]	]	X
eurjchem-952	249	29	complex	complex	ADJ
eurjchem-952	249	30	show	show	VERB
eurjchem-952	249	31	significant	significant	ADJ
eurjchem-952	249	32	activity	activity	NOUN
eurjchem-952	249	33	against	against	ADP
eurjchem-952	249	34	(	(	PUNCT
eurjchem-952	249	35	hct116	hct116	PROPN
eurjchem-952	249	36	)	)	PUNCT
eurjchem-952	249	37	and	and	CCONJ
eurjchem-952	249	38	(	(	PUNCT
eurjchem-952	249	39	hep2	hep2	PROPN
eurjchem-952	249	40	)	)	PUNCT
eurjchem-952	249	41	cells	cell	NOUN
eurjchem-952	249	42	with	with	ADP
eurjchem-952	249	43	ic50	ic50	PROPN
eurjchem-952	249	44	values	value	NOUN
eurjchem-952	249	45	of	of	ADP
eurjchem-952	249	46	0.41	0.41	NUM
eurjchem-952	249	47	g	g	NOUN
eurjchem-952	249	48	/	/	SYM
eurjchem-952	249	49	ml	ml	PROPN
eurjchem-952	249	50	(	(	PUNCT
eurjchem-952	249	51	figure	figure	NOUN
eurjchem-952	249	52	3	3	NUM
eurjchem-952	249	53	)	)	PUNCT
eurjchem-952	249	54	and	and	CCONJ
eurjchem-952	249	55	0.63	0.63	NUM
eurjchem-952	249	56	g	g	NOUN
eurjchem-952	249	57	/	/	SYM
eurjchem-952	249	58	ml	ml	X
eurjchem-952	249	59	respectively	respectively	ADV
eurjchem-952	249	60	.	.	PUNCT
eurjchem-952	250	1	thus	thus	ADV
eurjchem-952	250	2	,	,	PUNCT
eurjchem-952	250	3	[	[	X
eurjchem-952	250	4	cu(mpapt)(1,10‐phen)cl	cu(mpapt)(1,10‐phen)cl	NOUN
eurjchem-952	250	5	]	]	X
eurjchem-952	250	6	complex	complex	NOUN
eurjchem-952	250	7	is	be	AUX
eurjchem-952	250	8	chemotherapeutically	chemotherapeutically	ADV
eurjchem-952	250	9	significant	significant	ADJ
eurjchem-952	250	10	(	(	PUNCT
eurjchem-952	250	11	table	table	NOUN
eurjchem-952	250	12	4	4	NUM
eurjchem-952	250	13	)	)	PUNCT
eurjchem-952	250	14	.	.	PUNCT
eurjchem-952	251	1	ic50	ic50	PROPN
eurjchem-952	251	2	is	be	AUX
eurjchem-952	251	3	the	the	DET
eurjchem-952	251	4	concentration	concentration	NOUN
eurjchem-952	251	5	which	which	PRON
eurjchem-952	251	6	can	can	AUX
eurjchem-952	251	7	reduce	reduce	VERB
eurjchem-952	251	8	the	the	DET
eurjchem-952	251	9	growth	growth	NOUN
eurjchem-952	251	10	of	of	ADP
eurjchem-952	251	11	cancer	cancer	NOUN
eurjchem-952	251	12	cells	cell	NOUN
eurjchem-952	251	13	by	by	ADP
eurjchem-952	251	14	50	50	NUM
eurjchem-952	251	15	%	%	NOUN
eurjchem-952	251	16	.	.	PUNCT
eurjchem-952	252	1	results	result	NOUN
eurjchem-952	252	2	show	show	VERB
eurjchem-952	252	3	that	that	SCONJ
eurjchem-952	252	4	the	the	DET
eurjchem-952	252	5	growth	growth	NOUN
eurjchem-952	252	6	inhibition	inhibition	NOUN
eurjchem-952	252	7	of	of	ADP
eurjchem-952	252	8	tumor	tumor	NOUN
eurjchem-952	252	9	cells	cell	NOUN
eurjchem-952	252	10	is	be	AUX
eurjchem-952	252	11	due	due	ADJ
eurjchem-952	252	12	to	to	ADP
eurjchem-952	252	13	apoptosis	apoptosis	NOUN
eurjchem-952	252	14	(	(	PUNCT
eurjchem-952	252	15	programmed	program	VERB
eurjchem-952	252	16	cell	cell	NOUN
eurjchem-952	252	17	death	death	NOUN
eurjchem-952	252	18	)	)	PUNCT
eurjchem-952	252	19	in	in	ADP
eurjchem-952	252	20	all	all	DET
eurjchem-952	252	21	m(ii)‐complexes	m(ii)‐complexe	NOUN
eurjchem-952	252	22	.	.	PUNCT
eurjchem-952	253	1	induction	induction	NOUN
eurjchem-952	253	2	of	of	ADP
eurjchem-952	253	3	apoptosis	apoptosis	NOUN
eurjchem-952	253	4	was	be	AUX
eurjchem-952	253	5	recently	recently	ADV
eurjchem-952	253	6	thought	think	VERB
eurjchem-952	253	7	to	to	PART
eurjchem-952	253	8	be	be	AUX
eurjchem-952	253	9	one	one	NUM
eurjchem-952	253	10	of	of	ADP
eurjchem-952	253	11	the	the	DET
eurjchem-952	253	12	mechanisms	mechanism	NOUN
eurjchem-952	253	13	of	of	ADP
eurjchem-952	253	14	the	the	DET
eurjchem-952	253	15	antitumor	antitumor	PROPN
eurjchem-952	253	16	effect	effect	NOUN
eurjchem-952	253	17	of	of	ADP
eurjchem-952	253	18	cis‐platin	cis‐platin	PROPN
eurjchem-952	253	19	[	[	X
eurjchem-952	253	20	68	68	NUM
eurjchem-952	253	21	]	]	PUNCT
eurjchem-952	253	22	.	.	PUNCT
eurjchem-952	254	1	figure	figure	NOUN
eurjchem-952	254	2	3	3	NUM
eurjchem-952	254	3	.	.	PUNCT
eurjchem-952	254	4	effect	effect	NOUN
eurjchem-952	254	5	of	of	ADP
eurjchem-952	254	6	cu(ii	cu(ii	PROPN
eurjchem-952	254	7	)	)	PUNCT
eurjchem-952	254	8	complex	complex	NOUN
eurjchem-952	254	9	on	on	ADP
eurjchem-952	254	10	surviving	survive	VERB
eurjchem-952	254	11	fraction	fraction	NOUN
eurjchem-952	254	12	of	of	ADP
eurjchem-952	254	13	hep2	hep2	PROPN
eurjchem-952	254	14	tumor	tumor	NOUN
eurjchem-952	254	15	cell	cell	NOUN
eurjchem-952	254	16	.	.	PUNCT
eurjchem-952	255	1	3.6	3.6	NUM
eurjchem-952	255	2	.	.	X
eurjchem-952	256	1	molecular	molecular	ADJ
eurjchem-952	256	2	modeling	model	VERB
eurjchem-952	256	3	the	the	DET
eurjchem-952	256	4	atomic	atomic	ADJ
eurjchem-952	256	5	numbering	numbering	NOUN
eurjchem-952	256	6	scheme	scheme	NOUN
eurjchem-952	256	7	as	as	SCONJ
eurjchem-952	256	8	given	give	VERB
eurjchem-952	256	9	in	in	ADP
eurjchem-952	256	10	figures	figure	NOUN
eurjchem-952	256	11	4‐6	4‐6	PROPN
eurjchem-952	256	12	and	and	CCONJ
eurjchem-952	256	13	the	the	DET
eurjchem-952	256	14	theoretical	theoretical	ADJ
eurjchem-952	256	15	geometry	geometry	NOUN
eurjchem-952	256	16	structures	structure	NOUN
eurjchem-952	256	17	for	for	ADP
eurjchem-952	256	18	the	the	DET
eurjchem-952	256	19	ligand	ligand	NOUN
eurjchem-952	256	20	and	and	CCONJ
eurjchem-952	256	21	some	some	PRON
eurjchem-952	256	22	of	of	ADP
eurjchem-952	256	23	its	its	PRON
eurjchem-952	256	24	metal	metal	NOUN
eurjchem-952	256	25	complexes	complex	NOUN
eurjchem-952	256	26	are	be	AUX
eurjchem-952	256	27	calculated	calculate	VERB
eurjchem-952	256	28	.	.	PUNCT
eurjchem-952	257	1	the	the	DET
eurjchem-952	257	2	molecular	molecular	ADJ
eurjchem-952	257	3	parameters	parameter	NOUN
eurjchem-952	257	4	:	:	PUNCT
eurjchem-952	257	5	total	total	ADJ
eurjchem-952	257	6	energy	energy	NOUN
eurjchem-952	257	7	,	,	PUNCT
eurjchem-952	257	8	binding	bind	VERB
eurjchem-952	257	9	energy	energy	NOUN
eurjchem-952	257	10	,	,	PUNCT
eurjchem-952	257	11	isolated	isolate	VERB
eurjchem-952	257	12	atomic	atomic	ADJ
eurjchem-952	257	13	energy	energy	NOUN
eurjchem-952	257	14	,	,	PUNCT
eurjchem-952	257	15	electronic	electronic	ADJ
eurjchem-952	257	16	energy	energy	NOUN
eurjchem-952	257	17	,	,	PUNCT
eurjchem-952	257	18	heat	heat	NOUN
eurjchem-952	257	19	of	of	ADP
eurjchem-952	257	20	formation	formation	NOUN
eurjchem-952	257	21	,	,	PUNCT
eurjchem-952	257	22	dipole	dipole	NOUN
eurjchem-952	257	23	moment	moment	NOUN
eurjchem-952	257	24	,	,	PUNCT
eurjchem-952	257	25	homo	homo	NOUN
eurjchem-952	257	26	and	and	CCONJ
eurjchem-952	257	27	lumo	lumo	NOUN
eurjchem-952	257	28	were	be	AUX
eurjchem-952	257	29	calculated	calculate	VERB
eurjchem-952	257	30	and	and	CCONJ
eurjchem-952	257	31	represented	represent	VERB
eurjchem-952	257	32	in	in	ADP
eurjchem-952	257	33	table	table	NOUN
eurjchem-952	257	34	5	5	NUM
eurjchem-952	257	35	.	.	PUNCT
eurjchem-952	258	1	a	a	DET
eurjchem-952	258	2	comparison	comparison	NOUN
eurjchem-952	258	3	between	between	ADP
eurjchem-952	258	4	the	the	DET
eurjchem-952	258	5	bond	bond	NOUN
eurjchem-952	258	6	length	length	NOUN
eurjchem-952	258	7	of	of	ADP
eurjchem-952	258	8	the	the	DET
eurjchem-952	258	9	ligand	ligand	NOUN
eurjchem-952	258	10	and	and	CCONJ
eurjchem-952	258	11	its	its	PRON
eurjchem-952	258	12	complexes	complex	NOUN
eurjchem-952	258	13	is	be	AUX
eurjchem-952	258	14	illustrated	illustrate	VERB
eurjchem-952	258	15	.	.	PUNCT
eurjchem-952	259	1	all	all	DET
eurjchem-952	259	2	the	the	DET
eurjchem-952	259	3	active	active	ADJ
eurjchem-952	259	4	groups	group	NOUN
eurjchem-952	259	5	taking	take	VERB
eurjchem-952	259	6	part	part	NOUN
eurjchem-952	259	7	in	in	ADP
eurjchem-952	259	8	coordination	coordination	NOUN
eurjchem-952	259	9	have	have	VERB
eurjchem-952	259	10	bonds	bond	NOUN
eurjchem-952	259	11	longer	long	ADJ
eurjchem-952	259	12	than	than	SCONJ
eurjchem-952	259	13	that	that	PRON
eurjchem-952	259	14	already	already	ADV
eurjchem-952	259	15	exist	exist	VERB
eurjchem-952	259	16	in	in	ADP
eurjchem-952	259	17	the	the	DET
eurjchem-952	259	18	ligand	ligand	NOUN
eurjchem-952	259	19	(	(	PUNCT
eurjchem-952	259	20	like	like	ADP
eurjchem-952	259	21	c	c	NOUN
eurjchem-952	259	22	=	=	NOUN
eurjchem-952	259	23	n	n	NOUN
eurjchem-952	259	24	and	and	CCONJ
eurjchem-952	259	25	c	c	NOUN
eurjchem-952	259	26	=	=	SYM
eurjchem-952	259	27	s	s	NOUN
eurjchem-952	259	28	)	)	PUNCT
eurjchem-952	259	29	.	.	PUNCT
eurjchem-952	260	1	the	the	DET
eurjchem-952	260	2	lower	low	ADJ
eurjchem-952	260	3	homo	homo	NOUN
eurjchem-952	260	4	energy	energy	NOUN
eurjchem-952	260	5	values	value	NOUN
eurjchem-952	260	6	show	show	VERB
eurjchem-952	260	7	that	that	SCONJ
eurjchem-952	260	8	molecule	molecule	NOUN
eurjchem-952	260	9	donating	donating	NOUN
eurjchem-952	260	10	electron	electron	NOUN
eurjchem-952	260	11	ability	ability	NOUN
eurjchem-952	260	12	is	be	AUX
eurjchem-952	260	13	the	the	DET
eurjchem-952	260	14	weaker	weak	ADJ
eurjchem-952	260	15	.	.	PUNCT
eurjchem-952	261	1	on	on	ADP
eurjchem-952	261	2	contrary	contrary	PROPN
eurjchem-952	261	3	,	,	PUNCT
eurjchem-952	261	4	the	the	DET
eurjchem-952	261	5	higher	high	ADJ
eurjchem-952	261	6	homo	homo	NOUN
eurjchem-952	261	7	energy	energy	NOUN
eurjchem-952	261	8	implies	imply	VERB
eurjchem-952	261	9	that	that	SCONJ
eurjchem-952	261	10	the	the	DET
eurjchem-952	261	11	molecule	molecule	NOUN
eurjchem-952	261	12	is	be	AUX
eurjchem-952	261	13	a	a	DET
eurjchem-952	261	14	good	good	ADJ
eurjchem-952	261	15	electron	electron	NOUN
eurjchem-952	261	16	donor	donor	NOUN
eurjchem-952	261	17	.	.	PUNCT
eurjchem-952	262	1	lumo	lumo	NOUN
eurjchem-952	262	2	energy	energy	NOUN
eurjchem-952	262	3	presents	present	VERB
eurjchem-952	262	4	the	the	DET
eurjchem-952	262	5	ability	ability	NOUN
eurjchem-952	262	6	of	of	ADP
eurjchem-952	262	7	a	a	DET
eurjchem-952	262	8	molecule	molecule	NOUN
eurjchem-952	262	9	receiving	receive	VERB
eurjchem-952	262	10	electron	electron	NOUN
eurjchem-952	262	11	[	[	X
eurjchem-952	262	12	69	69	NUM
eurjchem-952	262	13	]	]	PUNCT
eurjchem-952	262	14	.	.	PUNCT
eurjchem-952	263	1	figure	figure	NOUN
eurjchem-952	263	2	4	4	NUM
eurjchem-952	263	3	.	.	PUNCT
eurjchem-952	264	1	the	the	DET
eurjchem-952	264	2	optimized	optimize	VERB
eurjchem-952	264	3	structural	structural	ADJ
eurjchem-952	264	4	geometry	geometry	NOUN
eurjchem-952	264	5	of	of	ADP
eurjchem-952	264	6	mpapt	mpapt	ADJ
eurjchem-952	264	7	along	along	ADP
eurjchem-952	264	8	with	with	ADP
eurjchem-952	264	9	the	the	DET
eurjchem-952	264	10	atom	atom	NOUN
eurjchem-952	264	11	numbering	numbering	NOUN
eurjchem-952	264	12	scheme	scheme	NOUN
eurjchem-952	264	13	.	.	PUNCT
eurjchem-952	265	1	aljahdali	aljahdali	PROPN
eurjchem-952	265	2	et	et	PROPN
eurjchem-952	265	3	al	al	PROPN
eurjchem-952	265	4	.	.	PUNCT
eurjchem-952	265	5	/	/	SYM
eurjchem-952	265	6	european	european	PROPN
eurjchem-952	265	7	journal	journal	PROPN
eurjchem-952	265	8	of	of	ADP
eurjchem-952	265	9	chemistry	chemistry	NOUN
eurjchem-952	265	10	5	5	NUM
eurjchem-952	265	11	(	(	PUNCT
eurjchem-952	265	12	2	2	NUM
eurjchem-952	265	13	)	)	PUNCT
eurjchem-952	265	14	(	(	PUNCT
eurjchem-952	265	15	2014	2014	NUM
eurjchem-952	265	16	)	)	PUNCT
eurjchem-952	266	1	201‐208	201‐208	NUM
eurjchem-952	266	2	207	207	NUM
eurjchem-952	266	3	table	table	NOUN
eurjchem-952	266	4	5	5	NUM
eurjchem-952	266	5	.	.	PUNCT
eurjchem-952	267	1	some	some	DET
eurjchem-952	267	2	energetic	energetic	ADJ
eurjchem-952	267	3	properties	property	NOUN
eurjchem-952	267	4	of	of	ADP
eurjchem-952	267	5	mpapt	mpapt	ADJ
eurjchem-952	267	6	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-952	267	7	and	and	CCONJ
eurjchem-952	267	8	its	its	PRON
eurjchem-952	267	9	complexes	complex	NOUN
eurjchem-952	267	10	calculated	calculate	VERB
eurjchem-952	267	11	by	by	ADP
eurjchem-952	267	12	pm3	pm3	PROPN
eurjchem-952	267	13	method	method	NOUN
eurjchem-952	267	14	.	.	PUNCT
eurjchem-952	268	1	ligand	ligand	PROPN
eurjchem-952	268	2	total	total	ADJ
eurjchem-952	268	3	energy	energy	NOUN
eurjchem-952	268	4	(	(	PUNCT
eurjchem-952	268	5	kcal	kcal	NOUN
eurjchem-952	268	6	/	/	SYM
eurjchem-952	268	7	mol	mol	NOUN
eurjchem-952	268	8	)	)	PUNCT
eurjchem-952	268	9	binding	bind	VERB
eurjchem-952	268	10	energy	energy	NOUN
eurjchem-952	268	11	(	(	PUNCT
eurjchem-952	268	12	kcal	kcal	NOUN
eurjchem-952	268	13	/	/	SYM
eurjchem-952	268	14	mol	mol	NOUN
eurjchem-952	268	15	)	)	PUNCT
eurjchem-952	268	16	electronic	electronic	ADJ
eurjchem-952	268	17	energy	energy	NOUN
eurjchem-952	268	18	(	(	PUNCT
eurjchem-952	268	19	kcal	kcal	NOUN
eurjchem-952	268	20	/	/	SYM
eurjchem-952	268	21	mol	mol	NOUN
eurjchem-952	268	22	)	)	PUNCT
eurjchem-952	268	23	dipole	dipole	NOUN
eurjchem-952	268	24	moment	moment	NOUN
eurjchem-952	268	25	(	(	PUNCT
eurjchem-952	268	26	debye	debye	ADJ
eurjchem-952	268	27	)	)	PUNCT
eurjchem-952	268	28	homo	homo	NOUN
eurjchem-952	268	29	(	(	PUNCT
eurjchem-952	268	30	ev	ev	NOUN
eurjchem-952	268	31	)	)	PUNCT
eurjchem-952	268	32	lumo	lumo	NOUN
eurjchem-952	268	33	(	(	PUNCT
eurjchem-952	268	34	ev	ev	INTJ
eurjchem-952	268	35	)	)	PUNCT
eurjchem-952	268	36	mpapt	mpapt	NOUN
eurjchem-952	268	37	‐60965.8	‐60965.8	NOUN
eurjchem-952	268	38	‐3093.26	‐3093.26	NUM
eurjchem-952	268	39	‐4001356.6	‐4001356.6	PROPN
eurjchem-952	268	40	4.55	4.55	NUM
eurjchem-952	268	41	‐8.94	‐8.94	NOUN
eurjchem-952	268	42	‐1.51	‐1.51	PUNCT
eurjchem-952	269	1	[	[	X
eurjchem-952	269	2	cu(mpapt)(1,10‐phen)cl	cu(mpapt)(1,10‐phen)cl	X
eurjchem-952	269	3	]	]	X
eurjchem-952	269	4	(	(	PUNCT
eurjchem-952	269	5	1	1	NUM
eurjchem-952	269	6	)	)	PUNCT
eurjchem-952	269	7	‐138355.50	‐138355.50	NUM
eurjchem-952	269	8	‐5845.52	‐5845.52	PROPN
eurjchem-952	269	9	‐1299306.8	‐1299306.8	NUM
eurjchem-952	269	10	7.91	7.91	NUM
eurjchem-952	269	11	‐3.95	‐3.95	NOUN
eurjchem-952	269	12	‐1.45	‐1.45	NOUN
eurjchem-952	269	13	[	[	X
eurjchem-952	269	14	ni(mpapt)(1,10‐phen)cl	ni(mpapt)(1,10‐phen)cl	X
eurjchem-952	269	15	]	]	X
eurjchem-952	269	16	(	(	PUNCT
eurjchem-952	269	17	2	2	NUM
eurjchem-952	269	18	)	)	PUNCT
eurjchem-952	269	19	‐135067.27	‐135067.27	X
eurjchem-952	269	20	‐5967.66	‐5967.66	NUM
eurjchem-952	269	21	‐1268318.8	‐1268318.8	NOUN
eurjchem-952	269	22	19.47	19.47	NUM
eurjchem-952	269	23	‐6.36	‐6.36	NOUN
eurjchem-952	269	24	‐2.29	‐2.29	NOUN
eurjchem-952	269	25	[	[	X
eurjchem-952	269	26	co(mpapt)(1,10‐phen)cl].h2o	co(mpapt)(1,10‐phen)cl].h2o	X
eurjchem-952	269	27	(	(	PUNCT
eurjchem-952	269	28	3	3	NUM
eurjchem-952	269	29	)	)	PUNCT
eurjchem-952	269	30	‐129390.70	‐129390.70	NUM
eurjchem-952	269	31	‐6156.55	‐6156.55	ADP
eurjchem-952	269	32	‐1231416.2	‐1231416.2	PROPN
eurjchem-952	269	33	8.50	8.50	NUM
eurjchem-952	269	34	‐3.62	‐3.62	NOUN
eurjchem-952	269	35	‐1.55	‐1.55	NOUN
eurjchem-952	269	36	[	[	X
eurjchem-952	269	37	mn(mpapt)(1,10‐phen)cl].h2o	mn(mpapt)(1,10‐phen)cl].h2o	NOUN
eurjchem-952	269	38	(	(	PUNCT
eurjchem-952	269	39	4	4	NUM
eurjchem-952	269	40	)	)	PUNCT
eurjchem-952	269	41	‐120098.41	‐120098.41	NUM
eurjchem-952	269	42	‐5907.57	‐5907.57	X
eurjchem-952	270	1	‐1181854.9	‐1181854.9	NOUN
eurjchem-952	270	2	10.19	10.19	NUM
eurjchem-952	270	3	‐4.30	‐4.30	NUM
eurjchem-952	270	4	‐1.31	‐1.31	NOUN
eurjchem-952	270	5	figure	figure	VERB
eurjchem-952	270	6	5	5	NUM
eurjchem-952	270	7	.	.	PUNCT
eurjchem-952	271	1	the	the	DET
eurjchem-952	271	2	optimized	optimize	VERB
eurjchem-952	271	3	structural	structural	ADJ
eurjchem-952	271	4	geometry	geometry	NOUN
eurjchem-952	271	5	of	of	ADP
eurjchem-952	271	6	[	[	X
eurjchem-952	271	7	co(mpapt)(1,10‐phen)cl	co(mpapt)(1,10‐phen)cl	NOUN
eurjchem-952	271	8	]	]	X
eurjchem-952	271	9	(	(	PUNCT
eurjchem-952	271	10	3	3	NUM
eurjchem-952	271	11	)	)	PUNCT
eurjchem-952	271	12	along	along	ADP
eurjchem-952	271	13	with	with	ADP
eurjchem-952	271	14	the	the	DET
eurjchem-952	271	15	atom	atom	NOUN
eurjchem-952	271	16	numbering	numbering	NOUN
eurjchem-952	271	17	scheme	scheme	NOUN
eurjchem-952	271	18	.	.	PUNCT
eurjchem-952	272	1	figure	figure	NOUN
eurjchem-952	272	2	6	6	NUM
eurjchem-952	272	3	.	.	PUNCT
eurjchem-952	273	1	the	the	DET
eurjchem-952	273	2	optimized	optimize	VERB
eurjchem-952	273	3	structural	structural	ADJ
eurjchem-952	273	4	geometry	geometry	NOUN
eurjchem-952	273	5	of	of	ADP
eurjchem-952	273	6	[	[	X
eurjchem-952	273	7	mn(mpapt)(1,10‐phen)cl	mn(mpapt)(1,10‐phen)cl	NOUN
eurjchem-952	273	8	]	]	X
eurjchem-952	273	9	(	(	PUNCT
eurjchem-952	273	10	4	4	NUM
eurjchem-952	273	11	)	)	PUNCT
eurjchem-952	273	12	along	along	ADP
eurjchem-952	273	13	with	with	ADP
eurjchem-952	273	14	the	the	DET
eurjchem-952	273	15	atom	atom	NOUN
eurjchem-952	273	16	numbering	numbering	NOUN
eurjchem-952	273	17	scheme	scheme	NOUN
eurjchem-952	273	18	.	.	PUNCT
eurjchem-952	274	1	the	the	DET
eurjchem-952	274	2	bond	bond	NOUN
eurjchem-952	274	3	lengths	length	NOUN
eurjchem-952	274	4	and	and	CCONJ
eurjchem-952	274	5	bond	bond	NOUN
eurjchem-952	274	6	angles	angle	NOUN
eurjchem-952	274	7	of	of	ADP
eurjchem-952	274	8	[	[	X
eurjchem-952	274	9	co(mpapt)(1,10‐	co(mpapt)(1,10‐	PROPN
eurjchem-952	274	10	phen)cl	phen)cl	NOUN
eurjchem-952	274	11	]	]	PUNCT
eurjchem-952	274	12	complex	complex	NOUN
eurjchem-952	274	13	as	as	ADP
eurjchem-952	274	14	a	a	DET
eurjchem-952	274	15	representative	representative	ADJ
eurjchem-952	274	16	example	example	NOUN
eurjchem-952	274	17	of	of	ADP
eurjchem-952	274	18	m(ii	m(ii	NOUN
eurjchem-952	274	19	)	)	PUNCT
eurjchem-952	274	20	compounds	compound	NOUN
eurjchem-952	274	21	are	be	AUX
eurjchem-952	274	22	given	give	VERB
eurjchem-952	274	23	in	in	ADP
eurjchem-952	274	24	supplementary	supplementary	ADJ
eurjchem-952	274	25	data	datum	NOUN
eurjchem-952	274	26	.	.	PUNCT
eurjchem-952	275	1	a	a	DET
eurjchem-952	275	2	drawing	drawing	NOUN
eurjchem-952	275	3	of	of	ADP
eurjchem-952	275	4	mpapt‐thiosemicarbazone	mpapt‐thiosemicarbazone	NOUN
eurjchem-952	275	5	ligand	ligand	NOUN
eurjchem-952	275	6	is	be	AUX
eurjchem-952	275	7	shown	show	VERB
eurjchem-952	275	8	in	in	ADP
eurjchem-952	275	9	figure	figure	NOUN
eurjchem-952	275	10	4	4	NUM
eurjchem-952	275	11	while	while	SCONJ
eurjchem-952	275	12	co(ii	co(ii	ADJ
eurjchem-952	275	13	)	)	PUNCT
eurjchem-952	275	14	and	and	CCONJ
eurjchem-952	275	15	ni(ii	ni(ii	ADJ
eurjchem-952	275	16	)	)	PUNCT
eurjchem-952	275	17	complexes	complex	NOUN
eurjchem-952	275	18	with	with	ADP
eurjchem-952	275	19	the	the	DET
eurjchem-952	275	20	atomic	atomic	ADJ
eurjchem-952	275	21	numbering	numbering	NOUN
eurjchem-952	275	22	scheme	scheme	NOUN
eurjchem-952	275	23	are	be	AUX
eurjchem-952	275	24	shown	show	VERB
eurjchem-952	275	25	in	in	ADP
eurjchem-952	275	26	figures	figure	NOUN
eurjchem-952	275	27	5	5	NUM
eurjchem-952	275	28	and	and	CCONJ
eurjchem-952	275	29	6	6	NUM
eurjchem-952	275	30	.	.	PUNCT
eurjchem-952	276	1	the	the	DET
eurjchem-952	276	2	coordination	coordination	NOUN
eurjchem-952	276	3	results	result	VERB
eurjchem-952	276	4	in	in	ADP
eurjchem-952	276	5	the	the	DET
eurjchem-952	276	6	changes	change	NOUN
eurjchem-952	276	7	of	of	ADP
eurjchem-952	276	8	bond	bond	NOUN
eurjchem-952	276	9	lengths	length	NOUN
eurjchem-952	276	10	and	and	CCONJ
eurjchem-952	276	11	angles	angle	NOUN
eurjchem-952	276	12	of	of	ADP
eurjchem-952	276	13	the	the	DET
eurjchem-952	276	14	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-952	276	15	moiety	moiety	NOUN
eurjchem-952	276	16	,	,	PUNCT
eurjchem-952	276	17	as	as	SCONJ
eurjchem-952	276	18	expected	expect	VERB
eurjchem-952	276	19	,	,	PUNCT
eurjchem-952	276	20	thus	thus	ADV
eurjchem-952	276	21	when	when	SCONJ
eurjchem-952	276	22	the	the	DET
eurjchem-952	276	23	bond	bond	NOUN
eurjchem-952	276	24	lengths	length	NOUN
eurjchem-952	276	25	in	in	ADP
eurjchem-952	276	26	the	the	DET
eurjchem-952	276	27	coordinated	coordinated	ADJ
eurjchem-952	276	28	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-952	276	29	ligand	ligand	NOUN
eurjchem-952	276	30	are	be	AUX
eurjchem-952	276	31	compared	compare	VERB
eurjchem-952	276	32	with	with	ADP
eurjchem-952	276	33	those	those	PRON
eurjchem-952	276	34	in	in	ADP
eurjchem-952	276	35	the	the	DET
eurjchem-952	276	36	free	free	ADJ
eurjchem-952	276	37	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-952	276	38	ligand	ligand	NOUN
eurjchem-952	276	39	,	,	PUNCT
eurjchem-952	276	40	it	it	PRON
eurjchem-952	276	41	is	be	AUX
eurjchem-952	276	42	seen	see	VERB
eurjchem-952	276	43	that	that	SCONJ
eurjchem-952	276	44	coordination	coordination	NOUN
eurjchem-952	276	45	elongates	elongate	VERB
eurjchem-952	276	46	the	the	DET
eurjchem-952	276	47	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-952	276	48	moiety	moiety	NOUN
eurjchem-952	276	49	’s	’s	PART
eurjchem-952	276	50	c	c	NOUN
eurjchem-952	276	51	–	–	PUNCT
eurjchem-952	276	52	s	s	VERB
eurjchem-952	276	53	bond	bond	NOUN
eurjchem-952	276	54	from	from	ADP
eurjchem-952	276	55	1.664	1.664	NUM
eurjchem-952	276	56	å	å	NOUN
eurjchem-952	276	57	to	to	ADP
eurjchem-952	276	58	1.709‐1.787	1.709‐1.787	NUM
eurjchem-952	276	59	å	å	NOUN
eurjchem-952	276	60	and	and	CCONJ
eurjchem-952	276	61	contracts	contract	NOUN
eurjchem-952	276	62	adjacent	adjacent	ADJ
eurjchem-952	276	63	n	n	CCONJ
eurjchem-952	276	64	–	–	PUNCT
eurjchem-952	276	65	c(s	c(s	ADJ
eurjchem-952	276	66	)	)	PUNCT
eurjchem-952	276	67	bond	bond	NOUN
eurjchem-952	276	68	from	from	ADP
eurjchem-952	276	69	1.420	1.420	NUM
eurjchem-952	276	70	å	å	NOUN
eurjchem-952	276	71	to	to	ADP
eurjchem-952	276	72	1.325‐1.347	1.325‐1.347	NUM
eurjchem-952	276	73	å	å	PROPN
eurjchem-952	276	74	in	in	ADP
eurjchem-952	276	75	which	which	PRON
eurjchem-952	276	76	is	be	AUX
eurjchem-952	276	77	consistent	consistent	ADJ
eurjchem-952	276	78	with	with	ADP
eurjchem-952	276	79	the	the	DET
eurjchem-952	276	80	c	c	PROPN
eurjchem-952	276	81	–	–	PUNCT
eurjchem-952	276	82	s	s	AUX
eurjchem-952	276	83	acquiring	acquire	VERB
eurjchem-952	276	84	a	a	DET
eurjchem-952	276	85	partial	partial	ADJ
eurjchem-952	276	86	single	single	ADJ
eurjchem-952	276	87	bond	bond	NOUN
eurjchem-952	276	88	and	and	CCONJ
eurjchem-952	276	89	n	n	CCONJ
eurjchem-952	276	90	–	–	PUNCT
eurjchem-952	276	91	c(s	c(s	X
eurjchem-952	276	92	)	)	PUNCT
eurjchem-952	276	93	a	a	DET
eurjchem-952	276	94	partial	partial	ADJ
eurjchem-952	276	95	double	double	ADJ
eurjchem-952	276	96	bond	bond	NOUN
eurjchem-952	276	97	character	character	NOUN
eurjchem-952	276	98	.	.	PUNCT
eurjchem-952	277	1	these	these	DET
eurjchem-952	277	2	changes	change	NOUN
eurjchem-952	277	3	in	in	ADP
eurjchem-952	277	4	bond	bond	NOUN
eurjchem-952	277	5	lengths	length	NOUN
eurjchem-952	277	6	are	be	AUX
eurjchem-952	277	7	attributable	attributable	ADJ
eurjchem-952	277	8	to	to	ADP
eurjchem-952	277	9	stabilization	stabilization	NOUN
eurjchem-952	277	10	of	of	ADP
eurjchem-952	277	11	the	the	DET
eurjchem-952	277	12	iminothiolate	iminothiolate	NOUN
eurjchem-952	277	13	form	form	NOUN
eurjchem-952	277	14	of	of	ADP
eurjchem-952	277	15	the	the	DET
eurjchem-952	277	16	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-952	277	17	ligand	ligand	NOUN
eurjchem-952	277	18	upon	upon	SCONJ
eurjchem-952	277	19	complexation	complexation	NOUN
eurjchem-952	277	20	via	via	ADP
eurjchem-952	277	21	loss	loss	NOUN
eurjchem-952	277	22	of	of	ADP
eurjchem-952	277	23	the	the	DET
eurjchem-952	277	24	hydrazinic	hydrazinic	ADJ
eurjchem-952	277	25	proton	proton	NOUN
eurjchem-952	277	26	[	[	X
eurjchem-952	277	27	70	70	NUM
eurjchem-952	277	28	]	]	PUNCT
eurjchem-952	277	29	.	.	PUNCT
eurjchem-952	278	1	this	this	PRON
eurjchem-952	278	2	means	mean	VERB
eurjchem-952	278	3	that	that	SCONJ
eurjchem-952	278	4	,	,	PUNCT
eurjchem-952	278	5	c	c	X
eurjchem-952	278	6	–	–	PUNCT
eurjchem-952	278	7	s	s	NOUN
eurjchem-952	278	8	distances	distance	NOUN
eurjchem-952	278	9	which	which	PRON
eurjchem-952	278	10	are	be	AUX
eurjchem-952	278	11	in	in	ADP
eurjchem-952	278	12	the	the	DET
eurjchem-952	278	13	range	range	NOUN
eurjchem-952	278	14	of	of	ADP
eurjchem-952	278	15	single	single	ADJ
eurjchem-952	278	16	bond	bond	NOUN
eurjchem-952	278	17	character	character	NOUN
eurjchem-952	278	18	being	be	AUX
eurjchem-952	278	19	some	some	PRON
eurjchem-952	278	20	of	of	ADP
eurjchem-952	278	21	the	the	DET
eurjchem-952	278	22	largest	large	ADJ
eurjchem-952	278	23	found	find	VERB
eurjchem-952	278	24	for	for	ADP
eurjchem-952	278	25	m(ii	m(ii	NOUN
eurjchem-952	278	26	)	)	PUNCT
eurjchem-952	278	27	complexes	complex	NOUN
eurjchem-952	278	28	(	(	PUNCT
eurjchem-952	278	29	typical	typical	ADJ
eurjchem-952	278	30	bond	bond	NOUN
eurjchem-952	278	31	lengths	length	NOUN
eurjchem-952	278	32	being	be	AUX
eurjchem-952	278	33	c(sp2)–s	c(sp2)–	VERB
eurjchem-952	278	34	1.706	1.706	NUM
eurjchem-952	278	35	å	å	PROPN
eurjchem-952	278	36	in	in	ADP
eurjchem-952	278	37	(	(	PUNCT
eurjchem-952	278	38	mes)2c	mes)2c	PROPN
eurjchem-952	278	39	=	=	SYM
eurjchem-952	278	40	c(sme)2	c(sme)2	X
eurjchem-952	278	41	and	and	CCONJ
eurjchem-952	278	42	c	c	X
eurjchem-952	278	43	=	=	SYM
eurjchem-952	278	44	s	s	PART
eurjchem-952	278	45	1.630	1.630	NUM
eurjchem-952	278	46	å	å	X
eurjchem-952	278	47	in	in	ADP
eurjchem-952	278	48	naphthylphenylthioketone	naphthylphenylthioketone	NOUN
eurjchem-952	278	49	)	)	PUNCT
eurjchem-952	279	1	[	[	X
eurjchem-952	279	2	71,72	71,72	X
eurjchem-952	279	3	]	]	X
eurjchem-952	279	4	.	.	PUNCT
eurjchem-952	280	1	this	this	PRON
eurjchem-952	280	2	also	also	ADV
eurjchem-952	280	3	confirms	confirm	VERB
eurjchem-952	280	4	the	the	DET
eurjchem-952	280	5	ir	ir	PROPN
eurjchem-952	280	6	and	and	CCONJ
eurjchem-952	280	7	spectral	spectral	ADJ
eurjchem-952	280	8	data	datum	NOUN
eurjchem-952	280	9	which	which	PRON
eurjchem-952	280	10	assumed	assume	VERB
eurjchem-952	280	11	that	that	SCONJ
eurjchem-952	280	12	the	the	DET
eurjchem-952	280	13	c	c	NOUN
eurjchem-952	280	14	=	=	NOUN
eurjchem-952	280	15	s	s	X
eurjchem-952	280	16	on	on	ADP
eurjchem-952	280	17	coordination	coordination	NOUN
eurjchem-952	280	18	gains	gain	NOUN
eurjchem-952	280	19	c	c	NOUN
eurjchem-952	280	20	–	–	PUNCT
eurjchem-952	280	21	s	s	PART
eurjchem-952	280	22	character	character	NOUN
eurjchem-952	280	23	.	.	PUNCT
eurjchem-952	281	1	similar	similar	ADJ
eurjchem-952	281	2	structural	structural	ADJ
eurjchem-952	281	3	features	feature	NOUN
eurjchem-952	281	4	are	be	AUX
eurjchem-952	281	5	known	know	VERB
eurjchem-952	281	6	for	for	ADP
eurjchem-952	281	7	other	other	ADJ
eurjchem-952	281	8	metal	metal	NOUN
eurjchem-952	281	9	complexes	complex	NOUN
eurjchem-952	281	10	of	of	ADP
eurjchem-952	281	11	such	such	ADJ
eurjchem-952	281	12	ligands	ligand	NOUN
eurjchem-952	281	13	that	that	PRON
eurjchem-952	281	14	have	have	VERB
eurjchem-952	281	15	the	the	DET
eurjchem-952	281	16	same	same	ADJ
eurjchem-952	281	17	coordination	coordination	NOUN
eurjchem-952	281	18	sites	site	NOUN
eurjchem-952	281	19	[	[	X
eurjchem-952	281	20	70,73	70,73	NOUN
eurjchem-952	281	21	]	]	PUNCT
eurjchem-952	281	22	.	.	PUNCT
eurjchem-952	282	1	the	the	DET
eurjchem-952	282	2	other	other	ADJ
eurjchem-952	282	3	bond	bond	NOUN
eurjchem-952	282	4	lengths	length	NOUN
eurjchem-952	282	5	and	and	CCONJ
eurjchem-952	282	6	angles	angle	NOUN
eurjchem-952	282	7	also	also	ADV
eurjchem-952	282	8	suffer	suffer	VERB
eurjchem-952	282	9	some	some	DET
eurjchem-952	282	10	changes	change	NOUN
eurjchem-952	282	11	,	,	PUNCT
eurjchem-952	282	12	but	but	CCONJ
eurjchem-952	282	13	not	not	PART
eurjchem-952	282	14	significantly	significantly	ADV
eurjchem-952	282	15	.	.	PUNCT
eurjchem-952	283	1	in	in	ADP
eurjchem-952	283	2	general	general	ADJ
eurjchem-952	283	3	,	,	PUNCT
eurjchem-952	283	4	the	the	DET
eurjchem-952	283	5	m	m	PROPN
eurjchem-952	283	6	–	–	PUNCT
eurjchem-952	283	7	s	s	PART
eurjchem-952	283	8	bond	bond	NOUN
eurjchem-952	283	9	length	length	NOUN
eurjchem-952	283	10	is	be	AUX
eurjchem-952	283	11	longer	long	ADJ
eurjchem-952	283	12	than	than	ADP
eurjchem-952	283	13	that	that	PRON
eurjchem-952	283	14	of	of	ADP
eurjchem-952	283	15	m	m	PROPN
eurjchem-952	283	16	–	–	PUNCT
eurjchem-952	283	17	cl	cl	NOUN
eurjchem-952	283	18	for	for	ADP
eurjchem-952	283	19	the	the	DET
eurjchem-952	283	20	all	all	DET
eurjchem-952	283	21	m(ii	m(ii	PROPN
eurjchem-952	283	22	)	)	PUNCT
eurjchem-952	283	23	complexes	complex	NOUN
eurjchem-952	283	24	and	and	CCONJ
eurjchem-952	283	25	the	the	DET
eurjchem-952	283	26	m	m	PROPN
eurjchem-952	283	27	–	–	PUNCT
eurjchem-952	283	28	n	n	PRON
eurjchem-952	283	29	bond	bond	NOUN
eurjchem-952	283	30	length	length	NOUN
eurjchem-952	283	31	is	be	AUX
eurjchem-952	283	32	shorter	short	ADJ
eurjchem-952	283	33	than	than	ADP
eurjchem-952	283	34	m	m	PROPN
eurjchem-952	283	35	–	–	PUNCT
eurjchem-952	283	36	cl	cl	NOUN
eurjchem-952	283	37	bond	bond	NOUN
eurjchem-952	283	38	length	length	NOUN
eurjchem-952	283	39	showing	show	VERB
eurjchem-952	283	40	that	that	SCONJ
eurjchem-952	283	41	the	the	DET
eurjchem-952	283	42	bond	bond	NOUN
eurjchem-952	283	43	length	length	NOUN
eurjchem-952	283	44	obeyed	obey	VERB
eurjchem-952	283	45	this	this	DET
eurjchem-952	283	46	order	order	NOUN
eurjchem-952	283	47	m	m	PRON
eurjchem-952	283	48	–	–	PUNCT
eurjchem-952	283	49	s	s	PART
eurjchem-952	283	50	>	>	X
eurjchem-952	283	51	m	m	PROPN
eurjchem-952	283	52	–	–	PUNCT
eurjchem-952	283	53	cl	cl	NOUN
eurjchem-952	283	54	>	>	X
eurjchem-952	283	55	m	m	PROPN
eurjchem-952	283	56	–	–	PUNCT
eurjchem-952	283	57	n.	n.	NOUN
eurjchem-952	283	58	in	in	ADP
eurjchem-952	283	59	all	all	DET
eurjchem-952	283	60	complexes	complex	NOUN
eurjchem-952	283	61	,	,	PUNCT
eurjchem-952	283	62	c	c	X
eurjchem-952	283	63	=	=	SYM
eurjchem-952	283	64	npy	npy	PROPN
eurjchem-952	283	65	bond	bond	NOUN
eurjchem-952	283	66	distance	distance	NOUN
eurjchem-952	283	67	of	of	ADP
eurjchem-952	283	68	the	the	DET
eurjchem-952	283	69	pyridine	pyridine	NOUN
eurjchem-952	283	70	ring	ring	NOUN
eurjchem-952	283	71	is	be	AUX
eurjchem-952	283	72	elongated	elongate	VERB
eurjchem-952	283	73	.	.	PUNCT
eurjchem-952	284	1	owing	owe	VERB
eurjchem-952	284	2	to	to	ADP
eurjchem-952	284	3	the	the	DET
eurjchem-952	284	4	formation	formation	NOUN
eurjchem-952	284	5	of	of	ADP
eurjchem-952	284	6	the	the	DET
eurjchem-952	284	7	m‐n	m‐n	PROPN
eurjchem-952	284	8	bond	bond	NOUN
eurjchem-952	284	9	which	which	PRON
eurjchem-952	284	10	makes	make	VERB
eurjchem-952	284	11	the	the	DET
eurjchem-952	284	12	c	c	NOUN
eurjchem-952	284	13	=	=	NOUN
eurjchem-952	284	14	n	n	PRON
eurjchem-952	284	15	bond	bond	NOUN
eurjchem-952	284	16	weaker	weak	ADJ
eurjchem-952	284	17	as	as	ADP
eurjchem-952	284	18	a	a	DET
eurjchem-952	284	19	result	result	NOUN
eurjchem-952	284	20	of	of	ADP
eurjchem-952	284	21	coordination	coordination	NOUN
eurjchem-952	284	22	.	.	PUNCT
eurjchem-952	285	1	the	the	DET
eurjchem-952	285	2	bond	bond	NOUN
eurjchem-952	285	3	angles	angle	NOUN
eurjchem-952	285	4	of	of	ADP
eurjchem-952	285	5	the	the	DET
eurjchem-952	285	6	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-952	285	7	moiety	moiety	NOUN
eurjchem-952	285	8	of	of	ADP
eurjchem-952	285	9	mpapt	mpapt	NOUN
eurjchem-952	285	10	are	be	AUX
eurjchem-952	285	11	altered	alter	VERB
eurjchem-952	285	12	somewhat	somewhat	ADV
eurjchem-952	285	13	upon	upon	SCONJ
eurjchem-952	285	14	coordination	coordination	NOUN
eurjchem-952	285	15	and	and	CCONJ
eurjchem-952	285	16	may	may	AUX
eurjchem-952	285	17	be	be	AUX
eurjchem-952	285	18	reduced	reduce	VERB
eurjchem-952	285	19	or	or	CCONJ
eurjchem-952	285	20	increased	increase	VERB
eurjchem-952	285	21	on	on	ADP
eurjchem-952	285	22	complex	complex	ADJ
eurjchem-952	285	23	formation	formation	NOUN
eurjchem-952	285	24	as	as	ADP
eurjchem-952	285	25	a	a	DET
eurjchem-952	285	26	consequence	consequence	NOUN
eurjchem-952	285	27	of	of	ADP
eurjchem-952	285	28	bonding	bonding	NOUN
eurjchem-952	285	29	.	.	PUNCT
eurjchem-952	286	1	the	the	DET
eurjchem-952	286	2	bond	bond	NOUN
eurjchem-952	286	3	angles	angle	VERB
eurjchem-952	286	4	around	around	ADP
eurjchem-952	286	5	the	the	DET
eurjchem-952	286	6	m(ii	m(ii	NOUN
eurjchem-952	286	7	)	)	PUNCT
eurjchem-952	286	8	center	center	NOUN
eurjchem-952	286	9	(	(	PUNCT
eurjchem-952	286	10	≃90	≃90	PROPN
eurjchem-952	286	11	°	°	PROPN
eurjchem-952	286	12	)	)	PUNCT
eurjchem-952	286	13	prove	prove	VERB
eurjchem-952	286	14	that	that	SCONJ
eurjchem-952	286	15	the	the	DET
eurjchem-952	286	16	geometric	geometric	NOUN
eurjchem-952	286	17	is	be	AUX
eurjchem-952	286	18	octahedral	octahedral	ADJ
eurjchem-952	286	19	as	as	SCONJ
eurjchem-952	286	20	proposed	propose	VERB
eurjchem-952	286	21	by	by	ADP
eurjchem-952	286	22	the	the	DET
eurjchem-952	286	23	different	different	ADJ
eurjchem-952	286	24	tools	tool	NOUN
eurjchem-952	286	25	of	of	ADP
eurjchem-952	286	26	analysis	analysis	NOUN
eurjchem-952	286	27	mentioned	mention	VERB
eurjchem-952	286	28	previously	previously	ADV
eurjchem-952	286	29	.	.	PUNCT
eurjchem-952	287	1	finally	finally	ADV
eurjchem-952	287	2	,	,	PUNCT
eurjchem-952	287	3	from	from	ADP
eurjchem-952	287	4	the	the	DET
eurjchem-952	287	5	interpretation	interpretation	NOUN
eurjchem-952	287	6	of	of	ADP
eurjchem-952	287	7	elemental	elemental	ADJ
eurjchem-952	287	8	analysis	analysis	NOUN
eurjchem-952	287	9	,	,	PUNCT
eurjchem-952	287	10	spectral	spectral	ADJ
eurjchem-952	287	11	data	datum	NOUN
eurjchem-952	287	12	(	(	PUNCT
eurjchem-952	287	13	infrared	infrared	ADJ
eurjchem-952	287	14	,	,	PUNCT
eurjchem-952	287	15	electronic	electronic	ADJ
eurjchem-952	287	16	and	and	CCONJ
eurjchem-952	287	17	esr	esr	NOUN
eurjchem-952	287	18	)	)	PUNCT
eurjchem-952	287	19	as	as	ADV
eurjchem-952	287	20	well	well	ADV
eurjchem-952	287	21	as	as	ADP
eurjchem-952	287	22	magnetic	magnetic	ADJ
eurjchem-952	287	23	susceptibility	susceptibility	NOUN
eurjchem-952	287	24	measure‐	measure‐	NOUN
eurjchem-952	287	25	ments	ment	NOUN
eurjchem-952	287	26	at	at	ADP
eurjchem-952	287	27	room	room	NOUN
eurjchem-952	287	28	temperature	temperature	NOUN
eurjchem-952	287	29	,	,	PUNCT
eurjchem-952	287	30	conductivity	conductivity	NOUN
eurjchem-952	287	31	measurements	measurement	NOUN
eurjchem-952	287	32	and	and	CCONJ
eurjchem-952	287	33	qm	qm	PROPN
eurjchem-952	287	34	calculations	calculation	NOUN
eurjchem-952	287	35	,	,	PUNCT
eurjchem-952	287	36	it	it	PRON
eurjchem-952	287	37	is	be	AUX
eurjchem-952	287	38	possible	possible	ADJ
eurjchem-952	287	39	to	to	PART
eurjchem-952	287	40	draw	draw	VERB
eurjchem-952	287	41	up	up	ADP
eurjchem-952	287	42	the	the	DET
eurjchem-952	287	43	tentative	tentative	ADJ
eurjchem-952	287	44	octahedral	octahedral	ADJ
eurjchem-952	287	45	structures	structure	NOUN
eurjchem-952	287	46	of	of	ADP
eurjchem-952	287	47	the	the	DET
eurjchem-952	287	48	metal	metal	NOUN
eurjchem-952	287	49	complexes	complex	NOUN
eurjchem-952	287	50	.	.	PUNCT
eurjchem-952	288	1	4	4	X
eurjchem-952	288	2	.	.	X
eurjchem-952	288	3	conclusions	conclusion	NOUN
eurjchem-952	288	4	the	the	DET
eurjchem-952	288	5	condensation	condensation	NOUN
eurjchem-952	288	6	reaction	reaction	NOUN
eurjchem-952	288	7	of	of	ADP
eurjchem-952	288	8	4‐(2‐pyridyl)‐3‐thiosemi‐	4‐(2‐pyridyl)‐3‐thiosemi‐	NUM
eurjchem-952	288	9	carbazone	carbazone	NOUN
eurjchem-952	288	10	with	with	ADP
eurjchem-952	288	11	1‐methyl‐1h‐pyrazole‐5‐carbox‐aldehyde	1‐methyl‐1h‐pyrazole‐5‐carbox‐aldehyde	PROPN
eurjchem-952	288	12	in	in	ADP
eurjchem-952	288	13	the	the	DET
eurjchem-952	288	14	molar	molar	ADJ
eurjchem-952	288	15	ratio	ratio	NOUN
eurjchem-952	288	16	(	(	PUNCT
eurjchem-952	288	17	1:1	1:1	NUM
eurjchem-952	288	18	)	)	PUNCT
eurjchem-952	288	19	afforded	afford	VERB
eurjchem-952	288	20	the	the	DET
eurjchem-952	288	21	corresponding	correspond	VERB
eurjchem-952	288	22	1‐methylpyrazole‐3‐aldehyde‐4‐(2‐pyridyl)thiosemicarbazone	1‐methylpyrazole‐3‐aldehyde‐4‐(2‐pyridyl)thiosemicarbazone	NUM
eurjchem-952	288	23	compound	compound	NOUN
eurjchem-952	288	24	(	(	PUNCT
eurjchem-952	288	25	mpapt	mpapt	ADJ
eurjchem-952	288	26	)	)	PUNCT
eurjchem-952	288	27	.	.	PUNCT
eurjchem-952	289	1	the	the	DET
eurjchem-952	289	2	bonding	bonding	NOUN
eurjchem-952	289	3	of	of	ADP
eurjchem-952	289	4	ligands	ligand	NOUN
eurjchem-952	289	5	to	to	ADP
eurjchem-952	289	6	the	the	DET
eurjchem-952	289	7	metal	metal	NOUN
eurjchem-952	289	8	ion	ion	NOUN
eurjchem-952	289	9	is	be	AUX
eurjchem-952	289	10	confirmed	confirm	VERB
eurjchem-952	289	11	by	by	ADP
eurjchem-952	289	12	analytical	analytical	ADJ
eurjchem-952	289	13	,	,	PUNCT
eurjchem-952	289	14	spectral	spectral	ADJ
eurjchem-952	289	15	and	and	CCONJ
eurjchem-952	289	16	magnetic	magnetic	ADJ
eurjchem-952	289	17	measurements	measurement	NOUN
eurjchem-952	289	18	.	.	PUNCT
eurjchem-952	290	1	the	the	DET
eurjchem-952	290	2	ir	ir	PROPN
eurjchem-952	290	3	spectra	spectra	PROPN
eurjchem-952	290	4	showed	show	VERB
eurjchem-952	290	5	that	that	SCONJ
eurjchem-952	290	6	,	,	PUNCT
eurjchem-952	290	7	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-952	290	8	compound	compound	NOUN
eurjchem-952	290	9	present	present	ADJ
eurjchem-952	290	10	in	in	ADP
eurjchem-952	290	11	the	the	DET
eurjchem-952	290	12	thione	thione	ADJ
eurjchem-952	290	13	form	form	NOUN
eurjchem-952	290	14	in	in	ADP
eurjchem-952	290	15	the	the	DET
eurjchem-952	290	16	solid	solid	ADJ
eurjchem-952	290	17	state	state	NOUN
eurjchem-952	290	18	.	.	PUNCT
eurjchem-952	291	1	in	in	ADP
eurjchem-952	291	2	the	the	DET
eurjchem-952	291	3	absence	absence	NOUN
eurjchem-952	291	4	of	of	ADP
eurjchem-952	291	5	x‐	x‐	PROPN
eurjchem-952	291	6	ray	ray	PROPN
eurjchem-952	291	7	single	single	PROPN
eurjchem-952	291	8	crystal	crystal	PROPN
eurjchem-952	291	9	data	datum	NOUN
eurjchem-952	291	10	of	of	ADP
eurjchem-952	291	11	the	the	DET
eurjchem-952	291	12	current	current	ADJ
eurjchem-952	291	13	synthesized	synthesize	VERB
eurjchem-952	291	14	complexes	complex	NOUN
eurjchem-952	291	15	and	and	CCONJ
eurjchem-952	291	16	based	base	VERB
eurjchem-952	291	17	on	on	ADP
eurjchem-952	291	18	the	the	DET
eurjchem-952	291	19	physicochemical	physicochemical	ADJ
eurjchem-952	291	20	studies	study	NOUN
eurjchem-952	291	21	and	and	CCONJ
eurjchem-952	291	22	geometrical	geometrical	ADJ
eurjchem-952	291	23	optimization	optimization	NOUN
eurjchem-952	291	24	,	,	PUNCT
eurjchem-952	291	25	a	a	DET
eurjchem-952	291	26	tentative	tentative	ADJ
eurjchem-952	291	27	structure	structure	NOUN
eurjchem-952	291	28	could	could	AUX
eurjchem-952	291	29	be	be	AUX
eurjchem-952	291	30	proposed	propose	VERB
eurjchem-952	291	31	as	as	SCONJ
eurjchem-952	291	32	shown	show	VERB
eurjchem-952	291	33	in	in	ADP
eurjchem-952	291	34	figures	figure	NOUN
eurjchem-952	291	35	4‐6	4‐6	PROPN
eurjchem-952	291	36	.	.	PUNCT
eurjchem-952	292	1	m(ii)‐complexes	m(ii)‐complexe	NOUN
eurjchem-952	292	2	are	be	AUX
eurjchem-952	292	3	formulated	formulate	VERB
eurjchem-952	292	4	as	as	ADP
eurjchem-952	292	5	[	[	X
eurjchem-952	292	6	m(mpapt	m(mpapt	X
eurjchem-952	292	7	)	)	PUNCT
eurjchem-952	292	8	(	(	PUNCT
eurjchem-952	292	9	1,10‐phen)cl].nh2o	1,10‐phen)cl].nh2o	NUM
eurjchem-952	292	10	where	where	SCONJ
eurjchem-952	292	11	mpapt	mpapt	PROPN
eurjchem-952	292	12	is	be	AUX
eurjchem-952	292	13	the	the	DET
eurjchem-952	292	14	deprotonated	deprotonated	ADJ
eurjchem-952	292	15	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-952	292	16	ligand	ligand	NOUN
eurjchem-952	292	17	.	.	PUNCT
eurjchem-952	293	1	in	in	ADP
eurjchem-952	293	2	these	these	DET
eurjchem-952	293	3	complexes	complex	NOUN
eurjchem-952	293	4	the	the	DET
eurjchem-952	293	5	thiosemi‐	thiosemi‐	PROPN
eurjchem-952	293	6	carbazone	carbazone	NOUN
eurjchem-952	293	7	ligand	ligand	NOUN
eurjchem-952	293	8	is	be	AUX
eurjchem-952	293	9	coordinated	coordinate	VERB
eurjchem-952	293	10	to	to	ADP
eurjchem-952	293	11	the	the	DET
eurjchem-952	293	12	metal(ii	metal(ii	NOUN
eurjchem-952	293	13	)	)	PUNCT
eurjchem-952	293	14	ion	ion	NOUN
eurjchem-952	293	15	as	as	ADP
eurjchem-952	293	16	a	a	DET
eurjchem-952	293	17	tridentate	tridentate	NOUN
eurjchem-952	293	18	anion	anion	NOUN
eurjchem-952	293	19	,	,	PUNCT
eurjchem-952	293	20	coordinating	coordinate	VERB
eurjchem-952	293	21	via	via	ADP
eurjchem-952	293	22	the	the	DET
eurjchem-952	293	23	azomethine	azomethine	NOUN
eurjchem-952	293	24	nitrogen	nitrogen	NOUN
eurjchem-952	293	25	,	,	PUNCT
eurjchem-952	293	26	pyridine	pyridine	ADJ
eurjchem-952	293	27	nitrogen	nitrogen	NOUN
eurjchem-952	293	28	atoms	atom	NOUN
eurjchem-952	293	29	and	and	CCONJ
eurjchem-952	293	30	the	the	DET
eurjchem-952	293	31	thiolate	thiolate	ADJ
eurjchem-952	293	32	sulfur	sulfur	NOUN
eurjchem-952	293	33	atom	atom	NOUN
eurjchem-952	293	34	after	after	ADP
eurjchem-952	293	35	deprotonation	deprotonation	NOUN
eurjchem-952	293	36	.	.	PUNCT
eurjchem-952	294	1	1,10‐phen	1,10‐phen	ADJ
eurjchem-952	294	2	is	be	AUX
eurjchem-952	294	3	coordinated	coordinate	VERB
eurjchem-952	294	4	as	as	ADP
eurjchem-952	294	5	neutral	neutral	ADJ
eurjchem-952	294	6	bidentate	bidentate	NOUN
eurjchem-952	294	7	ligand	ligand	NOUN
eurjchem-952	294	8	via	via	ADP
eurjchem-952	294	9	the	the	DET
eurjchem-952	294	10	two	two	NUM
eurjchem-952	294	11	pyridine	pyridine	ADJ
eurjchem-952	294	12	nitrogen	nitrogen	NOUN
eurjchem-952	294	13	atoms	atom	NOUN
eurjchem-952	294	14	.	.	PUNCT
eurjchem-952	295	1	208	208	NUM
eurjchem-952	295	2	aljahdali	aljahdali	PROPN
eurjchem-952	295	3	et	et	PROPN
eurjchem-952	295	4	al	al	PROPN
eurjchem-952	295	5	.	.	PUNCT
eurjchem-952	295	6	/	/	SYM
eurjchem-952	295	7	european	european	PROPN
eurjchem-952	295	8	journal	journal	PROPN
eurjchem-952	295	9	of	of	ADP
eurjchem-952	295	10	chemistry	chemistry	NOUN
eurjchem-952	295	11	5	5	NUM
eurjchem-952	295	12	(	(	PUNCT
eurjchem-952	295	13	2	2	NUM
eurjchem-952	295	14	)	)	PUNCT
eurjchem-952	295	15	(	(	PUNCT
eurjchem-952	295	16	2014	2014	NUM
eurjchem-952	295	17	)	)	PUNCT
eurjchem-952	295	18	201‐208	201‐208	NUM
eurjchem-952	295	19	from	from	ADP
eurjchem-952	295	20	elemental	elemental	ADJ
eurjchem-952	295	21	analysis	analysis	NOUN
eurjchem-952	295	22	,	,	PUNCT
eurjchem-952	295	23	ir	ir	INTJ
eurjchem-952	295	24	,	,	PUNCT
eurjchem-952	295	25	spectral	spectral	ADJ
eurjchem-952	295	26	,	,	PUNCT
eurjchem-952	295	27	thermal	thermal	ADJ
eurjchem-952	295	28	analysis	analysis	NOUN
eurjchem-952	295	29	,	,	PUNCT
eurjchem-952	295	30	magnetic	magnetic	ADJ
eurjchem-952	295	31	and	and	CCONJ
eurjchem-952	295	32	conductance	conductance	NOUN
eurjchem-952	295	33	measurements	measurement	NOUN
eurjchem-952	295	34	,	,	PUNCT
eurjchem-952	295	35	all	all	DET
eurjchem-952	295	36	m(ii)‐complexes	m(ii)‐complexe	NOUN
eurjchem-952	295	37	are	be	AUX
eurjchem-952	295	38	nonelectrolytes	nonelectrolyte	NOUN
eurjchem-952	295	39	with	with	ADP
eurjchem-952	295	40	octahedral	octahedral	ADJ
eurjchem-952	295	41	structure	structure	NOUN
eurjchem-952	295	42	.	.	PUNCT
eurjchem-952	296	1	in	in	ADP
eurjchem-952	296	2	this	this	DET
eurjchem-952	296	3	work	work	NOUN
eurjchem-952	296	4	,	,	PUNCT
eurjchem-952	296	5	it	it	PRON
eurjchem-952	296	6	was	be	AUX
eurjchem-952	296	7	found	find	VERB
eurjchem-952	296	8	that	that	SCONJ
eurjchem-952	296	9	the	the	DET
eurjchem-952	296	10	m(ii	m(ii	PROPN
eurjchem-952	296	11	)	)	PUNCT
eurjchem-952	296	12	compounds	compound	NOUN
eurjchem-952	296	13	show	show	VERB
eurjchem-952	296	14	significantly	significantly	ADV
eurjchem-952	296	15	different	different	ADJ
eurjchem-952	296	16	levels	level	NOUN
eurjchem-952	296	17	of	of	ADP
eurjchem-952	296	18	biological	biological	ADJ
eurjchem-952	296	19	activity	activity	NOUN
eurjchem-952	296	20	.	.	PUNCT
eurjchem-952	297	1	the	the	PRON
eurjchem-952	297	2	antibacterial	antibacterial	ADJ
eurjchem-952	297	3	,	,	PUNCT
eurjchem-952	297	4	antifungal	antifungal	PROPN
eurjchem-952	297	5	,	,	PUNCT
eurjchem-952	297	6	screening	screen	VERB
eurjchem-952	297	7	data	datum	NOUN
eurjchem-952	297	8	revealed	reveal	VERB
eurjchem-952	297	9	that	that	SCONJ
eurjchem-952	297	10	newly	newly	ADV
eurjchem-952	297	11	generated	generate	VERB
eurjchem-952	297	12	compounds	compound	NOUN
eurjchem-952	297	13	are	be	AUX
eurjchem-952	297	14	potential	potential	ADJ
eurjchem-952	297	15	antimicrobial	antimicrobial	ADJ
eurjchem-952	297	16	agents	agent	NOUN
eurjchem-952	297	17	.	.	PUNCT
eurjchem-952	298	1	cu(ii	cu(ii	ADJ
eurjchem-952	298	2	)	)	PUNCT
eurjchem-952	298	3	complex	complex	NOUN
eurjchem-952	298	4	showed	show	VERB
eurjchem-952	298	5	a	a	DET
eurjchem-952	298	6	higher	high	ADJ
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eurjchem-952	298	8	activity	activity	NOUN
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eurjchem-952	298	11	carcinoma	carcinoma	NOUN
eurjchem-952	298	12	.	.	PUNCT
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eurjchem-952	299	2	material	material	NOUN
eurjchem-952	299	3	supporting	support	VERB
eurjchem-952	299	4	information	information	NOUN
eurjchem-952	299	5	for	for	ADP
eurjchem-952	299	6	this	this	DET
eurjchem-952	299	7	article	article	NOUN
eurjchem-952	299	8	is	be	AUX
eurjchem-952	299	9	available	available	ADJ
eurjchem-952	299	10	on	on	ADP
eurjchem-952	299	11	the	the	DET
eurjchem-952	299	12	www	www	NOUN
eurjchem-952	299	13	under	under	ADP
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eurjchem-952	299	17	author	author	NOUN
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eurjchem-952	300	5	bond	bond	NOUN
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eurjchem-952	300	8	[	[	X
eurjchem-952	300	9	co(mpapt)(1,10‐phen)cl	co(mpapt)(1,10‐phen)cl	NOUN
eurjchem-952	300	10	]	]	X
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eurjchem-952	300	17	m(ii	m(ii	NOUN
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eurjchem-952	300	22	in	in	ADP
eurjchem-952	300	23	table	table	NOUN
eurjchem-952	300	24	s1	s1	NOUN
eurjchem-952	300	25	.	.	PUNCT
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eurjchem-952	301	2	[	[	X
eurjchem-952	301	3	1	1	NUM
eurjchem-952	301	4	]	]	PUNCT
eurjchem-952	301	5	.	.	PUNCT
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eurjchem-952	302	2	,	,	PUNCT
eurjchem-952	302	3	i.	i.	PROPN
eurjchem-952	302	4	;	;	PUNCT
eurjchem-952	302	5	cokmus	cokmus	PROPN
eurjchem-952	302	6	,	,	PUNCT
eurjchem-952	302	7	c.	c.	NOUN
eurjchem-952	302	8	;	;	PUNCT
eurjchem-952	302	9	atalan	atalan	PROPN
eurjchem-952	302	10	,	,	PUNCT
eurjchem-952	302	11	e.	e.	PROPN
eurjchem-952	302	12	mikrobiologia	mikrobiologia	PROPN
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eurjchem-952	302	14	,	,	PUNCT
eurjchem-952	302	15	72	72	NUM
eurjchem-952	302	16	,	,	PUNCT
eurjchem-952	302	17	54‐55	54‐55	NUM
eurjchem-952	302	18	.	.	PUNCT
eurjchem-952	303	1	[	[	X
eurjchem-952	303	2	2	2	NUM
eurjchem-952	303	3	]	]	PUNCT
eurjchem-952	303	4	.	.	PUNCT
eurjchem-952	304	1	harbottle	harbottle	PROPN
eurjchem-952	304	2	,	,	PUNCT
eurjchem-952	304	3	h.	h.	PROPN
eurjchem-952	304	4	;	;	PUNCT
eurjchem-952	304	5	thakur	thakur	PROPN
eurjchem-952	304	6	,	,	PUNCT
eurjchem-952	304	7	s.	s.	PROPN
eurjchem-952	304	8	;	;	PUNCT
eurjchem-952	304	9	zhao	zhao	X
eurjchem-952	304	10	,	,	PUNCT
eurjchem-952	304	11	white	white	PROPN
eurjchem-952	304	12	,	,	PUNCT
eurjchem-952	304	13	d.	d.	PROPN
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eurjchem-952	304	15	anim	anim	PROPN
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eurjchem-952	304	18	.	.	PUNCT
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eurjchem-952	305	2	,	,	PUNCT
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eurjchem-952	305	4	,	,	PUNCT
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eurjchem-952	305	6	.	.	PUNCT
eurjchem-952	306	1	[	[	X
eurjchem-952	306	2	3	3	NUM
eurjchem-952	306	3	]	]	PUNCT
eurjchem-952	306	4	.	.	PUNCT
eurjchem-952	306	5	lakshmi	lakshmi	PROPN
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eurjchem-952	306	7	b.	b.	PROPN
eurjchem-952	306	8	;	;	PUNCT
eurjchem-952	306	9	avaji	avaji	PROPN
eurjchem-952	306	10	,	,	PUNCT
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eurjchem-952	306	12	g.	g.	PROPN
eurjchem-952	306	13	;	;	PUNCT
eurjchem-952	306	14	shivananda	shivananda	PROPN
eurjchem-952	306	15	,	,	PUNCT
eurjchem-952	306	16	k.	k.	PROPN
eurjchem-952	306	17	n.	n.	PROPN
eurjchem-952	306	18	;	;	PUNCT
eurjchem-952	306	19	nagella	nagella	ADV
eurjchem-952	306	20	,	,	PUNCT
eurjchem-952	306	21	p.	p.	NOUN
eurjchem-952	306	22	;	;	PUNCT
eurjchem-952	306	23	manohar	manohar	PROPN
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eurjchem-952	306	25	s.	s.	PROPN
eurjchem-952	306	26	h.	h.	PROPN
eurjchem-952	306	27	;	;	PUNCT
eurjchem-952	306	28	mahendra	mahendra	PROPN
eurjchem-952	306	29	,	,	PUNCT
eurjchem-952	306	30	k.	k.	PROPN
eurjchem-952	306	31	n.	n.	PROPN
eurjchem-952	306	32	polyhedron	polyhedron	PROPN
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eurjchem-952	306	34	,	,	PUNCT
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eurjchem-952	306	36	,	,	PUNCT
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eurjchem-952	306	38	.	.	PUNCT
eurjchem-952	307	1	[	[	X
eurjchem-952	307	2	4	4	NUM
eurjchem-952	307	3	]	]	PUNCT
eurjchem-952	307	4	.	.	PUNCT
eurjchem-952	308	1	chan	chan	PROPN
eurjchem-952	308	2	,	,	PUNCT
eurjchem-952	308	3	j.	j.	PROPN
eurjchem-952	308	4	;	;	PUNCT
eurjchem-952	308	5	huang	huang	PROPN
eurjchem-952	308	6	,	,	PUNCT
eurjchem-952	308	7	y.	y.	PROPN
eurjchem-952	308	8	;	;	PUNCT
eurjchem-952	308	9	liu	liu	PROPN
eurjchem-952	308	10	,	,	PUNCT
eurjchem-952	308	11	g.	g.	PROPN
eurjchem-952	308	12	;	;	PUNCT
eurjchem-952	308	13	afrasiabi	afrasiabi	NOUN
eurjchem-952	308	14	,	,	PUNCT
eurjchem-952	308	15	z.	z.	PROPN
eurjchem-952	308	16	;	;	PUNCT
eurjchem-952	308	17	sinn	sinn	PROPN
eurjchem-952	308	18	,	,	PUNCT
eurjchem-952	308	19	e.	e.	PROPN
eurjchem-952	308	20	;	;	PUNCT
eurjchem-952	308	21	padhye	padhye	NOUN
eurjchem-952	308	22	,	,	PUNCT
eurjchem-952	308	23	s.	s.	PROPN
eurjchem-952	308	24	;	;	PUNCT
eurjchem-952	308	25	ma	ma	PROPN
eurjchem-952	308	26	,	,	PUNCT
eurjchem-952	308	27	y.	y.	PROPN
eurjchem-952	308	28	toxicol	toxicol	PROPN
eurjchem-952	308	29	.	.	PUNCT
eurjchem-952	309	1	appl	appl	PROPN
eurjchem-952	309	2	.	.	PUNCT
eurjchem-952	310	1	pharm	pharm	PROPN
eurjchem-952	310	2	.	.	PUNCT
eurjchem-952	311	1	2004	2004	NUM
eurjchem-952	311	2	,	,	PUNCT
eurjchem-952	311	3	197	197	NUM
eurjchem-952	311	4	,	,	PUNCT
eurjchem-952	311	5	40‐48	40‐48	NUM
eurjchem-952	311	6	.	.	PUNCT
eurjchem-952	312	1	[	[	X
eurjchem-952	312	2	5	5	NUM
eurjchem-952	312	3	]	]	PUNCT
eurjchem-952	312	4	.	.	PUNCT
eurjchem-952	313	1	rosen	rosen	PROPN
eurjchem-952	313	2	,	,	PUNCT
eurjchem-952	313	3	j.	j.	PROPN
eurjchem-952	313	4	;	;	PUNCT
eurjchem-952	313	5	smith	smith	PROPN
eurjchem-952	313	6	,	,	PUNCT
eurjchem-952	313	7	h.	h.	PROPN
eurjchem-952	313	8	;	;	PUNCT
eurjchem-952	313	9	wiggall	wiggall	PROPN
eurjchem-952	313	10	,	,	PUNCT
eurjchem-952	313	11	k.	k.	PROPN
eurjchem-952	313	12	j.	j.	PROPN
eurjchem-952	313	13	;	;	PUNCT
eurjchem-952	314	1	zhang	zhang	PROPN
eurjchem-952	314	2	,	,	PUNCT
eurjchem-952	314	3	l.	l.	PROPN
eurjchem-952	314	4	;	;	PUNCT
eurjchem-952	314	5	luengo	luengo	PROPN
eurjchem-952	314	6	,	,	PUNCT
eurjchem-952	314	7	j.	j.	PROPN
eurjchem-952	314	8	i.	i.	PROPN
eurjchem-952	314	9	j.	j.	PROPN
eurjchem-952	314	10	med	med	PROPN
eurjchem-952	314	11	.	.	PROPN
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eurjchem-952	314	13	.	.	PUNCT
eurjchem-952	315	1	2002	2002	NUM
eurjchem-952	315	2	,	,	PUNCT
eurjchem-952	315	3	45	45	NUM
eurjchem-952	315	4	,	,	PUNCT
eurjchem-952	315	5	3573‐3575	3573‐3575	NUM
eurjchem-952	315	6	.	.	PUNCT
eurjchem-952	316	1	[	[	X
eurjchem-952	316	2	6	6	NUM
eurjchem-952	316	3	]	]	PUNCT
eurjchem-952	316	4	.	.	PUNCT
eurjchem-952	317	1	du	du	PROPN
eurjchem-952	317	2	,	,	PUNCT
eurjchem-952	317	3	x.	x.	PROPN
eurjchem-952	317	4	;	;	PUNCT
eurjchem-952	317	5	guo	guo	PROPN
eurjchem-952	317	6	,	,	PUNCT
eurjchem-952	317	7	c.	c.	PROPN
eurjchem-952	317	8	;	;	PUNCT
eurjchem-952	317	9	hansel	hansel	PROPN
eurjchem-952	317	10	,	,	PUNCT
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eurjchem-952	317	12	;	;	PUNCT
eurjchem-952	317	13	doyle	doyle	PROPN
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eurjchem-952	317	18	caffrey	caffrey	PROPN
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eurjchem-952	317	20	c.	c.	PROPN
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eurjchem-952	317	22	;	;	PUNCT
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eurjchem-952	317	24	,	,	PUNCT
eurjchem-952	317	25	t.	t.	PROPN
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eurjchem-952	317	27	;	;	PUNCT
eurjchem-952	317	28	mckerrow	mckerrow	PROPN
eurjchem-952	317	29	,	,	PUNCT
eurjchem-952	317	30	j.	j.	PROPN
eurjchem-952	317	31	h.	h.	PROPN
eurjchem-952	317	32	;	;	PUNCT
eurjchem-952	317	33	cohen	cohen	PROPN
eurjchem-952	317	34	,	,	PUNCT
eurjchem-952	317	35	f.	f.	PROPN
eurjchem-952	317	36	e.	e.	PROPN
eurjchem-952	317	37	j.	j.	PROPN
eurjchem-952	317	38	med	med	PROPN
eurjchem-952	317	39	.	.	PROPN
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eurjchem-952	317	41	.	.	PUNCT
eurjchem-952	318	1	2002	2002	NUM
eurjchem-952	318	2	,	,	PUNCT
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eurjchem-952	318	4	,	,	PUNCT
eurjchem-952	318	5	2695‐2707	2695‐2707	NUM
eurjchem-952	318	6	.	.	PUNCT
eurjchem-952	319	1	[	[	X
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eurjchem-952	319	4	.	.	PUNCT
eurjchem-952	320	1	kovala‐demertzi	kovala‐demertzi	PROPN
eurjchem-952	320	2	,	,	PUNCT
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eurjchem-952	320	4	;	;	PUNCT
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eurjchem-952	320	9	;	;	PUNCT
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eurjchem-952	320	11	,	,	PUNCT
eurjchem-952	320	12	e.	e.	PROPN
eurjchem-952	320	13	;	;	PUNCT
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eurjchem-952	320	15	,	,	PUNCT
eurjchem-952	320	16	a.	a.	NOUN
eurjchem-952	320	17	a.	a.	PROPN
eurjchem-952	320	18	;	;	PUNCT
eurjchem-952	320	19	yadav	yadav	PROPN
eurjchem-952	320	20	,	,	PUNCT
eurjchem-952	320	21	p.	p.	PROPN
eurjchem-952	320	22	n.	n.	PROPN
eurjchem-952	320	23	;	;	PUNCT
eurjchem-952	320	24	miller	miller	PROPN
eurjchem-952	320	25	,	,	PUNCT
eurjchem-952	320	26	j.	j.	PROPN
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eurjchem-952	320	28	;	;	PUNCT
eurjchem-952	320	29	zheng	zheng	PROPN
eurjchem-952	320	30	,	,	PUNCT
eurjchem-952	320	31	y.	y.	PROPN
eurjchem-952	320	32	;	;	PUNCT
eurjchem-952	320	33	kyriakidis	kyriakidi	NOUN
eurjchem-952	320	34	,	,	PUNCT
eurjchem-952	320	35	d.	d.	PROPN
eurjchem-952	320	36	a.	a.	PROPN
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eurjchem-952	320	39	,	,	PUNCT
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eurjchem-952	320	41	,	,	PUNCT
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eurjchem-952	320	43	.	.	PUNCT
eurjchem-952	321	1	[	[	X
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eurjchem-952	321	4	.	.	PUNCT
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eurjchem-952	321	6	,	,	PUNCT
eurjchem-952	321	7	j.	j.	PROPN
eurjchem-952	321	8	p.	p.	PROPN
eurjchem-952	321	9	;	;	PUNCT
eurjchem-952	321	10	klayman	klayman	PROPN
eurjchem-952	321	11	,	,	PUNCT
eurjchem-952	321	12	d.	d.	PROPN
eurjchem-952	321	13	l.	l.	PROPN
eurjchem-952	321	14	;	;	PUNCT
eurjchem-952	321	15	franchino	franchino	PROPN
eurjchem-952	321	16	,	,	PUNCT
eurjchem-952	321	17	d.	d.	PROPN
eurjchem-952	321	18	g.	g.	PROPN
eurjchem-952	321	19	j.	j.	PROPN
eurjchem-952	321	20	med	med	PROPN
eurjchem-952	321	21	.	.	PROPN
eurjchem-952	321	22	chem	chem	PROPN
eurjchem-952	321	23	.	.	PUNCT
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eurjchem-952	322	2	,	,	PUNCT
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eurjchem-952	322	4	,	,	PUNCT
eurjchem-952	322	5	1261‐1264	1261‐1264	NUM
eurjchem-952	322	6	.	.	PUNCT
eurjchem-952	323	1	[	[	X
eurjchem-952	323	2	9	9	NUM
eurjchem-952	323	3	]	]	PUNCT
eurjchem-952	323	4	.	.	PUNCT
eurjchem-952	324	1	klayman	klayman	PROPN
eurjchem-952	324	2	,	,	PUNCT
eurjchem-952	324	3	l.	l.	PROPN
eurjchem-952	324	4	;	;	PUNCT
eurjchem-952	324	5	scovill	scovill	PROPN
eurjchem-952	324	6	,	,	PUNCT
eurjchem-952	324	7	j.	j.	PROPN
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eurjchem-952	324	9	;	;	PUNCT
eurjchem-952	324	10	bartosevich	bartosevich	PROPN
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eurjchem-952	324	12	j.	j.	PROPN
eurjchem-952	324	13	f.	f.	PROPN
eurjchem-952	324	14	;	;	PUNCT
eurjchem-952	324	15	bruce	bruce	PROPN
eurjchem-952	324	16	,	,	PUNCT
eurjchem-952	324	17	j.	j.	PROPN
eurjchem-952	324	18	j.	j.	PROPN
eurjchem-952	324	19	med	med	PROPN
eurjchem-952	324	20	.	.	PROPN
eurjchem-952	324	21	chem	chem	PROPN
eurjchem-952	324	22	.	.	PUNCT
eurjchem-952	325	1	1983	1983	NUM
eurjchem-952	325	2	,	,	PUNCT
eurjchem-952	325	3	26	26	NUM
eurjchem-952	325	4	,	,	PUNCT
eurjchem-952	325	5	35‐39	35‐39	NOUN
eurjchem-952	325	6	.	.	PUNCT
eurjchem-952	326	1	[	[	X
eurjchem-952	326	2	10	10	NUM
eurjchem-952	326	3	]	]	PUNCT
eurjchem-952	326	4	.	.	PUNCT
eurjchem-952	326	5	demertzi	demertzi	PROPN
eurjchem-952	326	6	,	,	PUNCT
eurjchem-952	326	7	d.	d.	PROPN
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eurjchem-952	326	9	;	;	PUNCT
eurjchem-952	326	10	demertzis	demertzis	PROPN
eurjchem-952	326	11	,	,	PUNCT
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eurjchem-952	326	13	a.	a.	PROPN
eurjchem-952	326	14	;	;	PUNCT
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eurjchem-952	326	16	,	,	PUNCT
eurjchem-952	326	17	j.	j.	PROPN
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eurjchem-952	326	19	;	;	PUNCT
eurjchem-952	326	20	papadopoulou	papadopoulou	PROPN
eurjchem-952	326	21	,	,	PUNCT
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eurjchem-952	326	23	;	;	PUNCT
eurjchem-952	326	24	dodorou	dodorou	PROPN
eurjchem-952	326	25	,	,	PUNCT
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eurjchem-952	326	27	;	;	PUNCT
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eurjchem-952	326	29	,	,	PUNCT
eurjchem-952	326	30	g.	g.	PROPN
eurjchem-952	326	31	j.	j.	PROPN
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eurjchem-952	326	33	.	.	PUNCT
eurjchem-952	327	1	biochem	biochem	PROPN
eurjchem-952	327	2	.	.	PUNCT
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eurjchem-952	328	2	,	,	PUNCT
eurjchem-952	328	3	86	86	NUM
eurjchem-952	328	4	,	,	PUNCT
eurjchem-952	328	5	555‐563	555‐563	PROPN
eurjchem-952	328	6	.	.	PUNCT
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eurjchem-952	332	2	,	,	PUNCT
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eurjchem-952	333	3	]	]	PUNCT
eurjchem-952	333	4	.	.	PUNCT
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eurjchem-952	336	2	,	,	PUNCT
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eurjchem-952	336	4	,	,	PUNCT
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eurjchem-952	336	6	.	.	PUNCT
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eurjchem-952	337	3	]	]	PUNCT
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eurjchem-952	338	11	,	,	PUNCT
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eurjchem-952	338	15	,	,	PUNCT
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eurjchem-952	338	17	w.	w.	PROPN
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eurjchem-952	339	4	.	.	PUNCT
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eurjchem-952	340	2	,	,	PUNCT
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eurjchem-952	340	4	,	,	PUNCT
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eurjchem-952	340	6	.	.	PUNCT
eurjchem-952	341	1	[	[	X
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eurjchem-952	341	3	]	]	SYM
eurjchem-952	341	4	.	.	PUNCT
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eurjchem-952	342	2	,	,	PUNCT
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eurjchem-952	342	6	,	,	PUNCT
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eurjchem-952	342	13	j.	j.	PROPN
eurjchem-952	342	14	saudi	saudi	PROPN
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eurjchem-952	342	16	.	.	PUNCT
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eurjchem-952	343	2	.	.	PUNCT
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eurjchem-952	344	2	,	,	PUNCT
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eurjchem-952	344	4	)	)	PUNCT
eurjchem-952	344	5	,	,	PUNCT
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eurjchem-952	344	7	.	.	PUNCT
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eurjchem-952	345	3	]	]	SYM
eurjchem-952	345	4	.	.	PUNCT
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eurjchem-952	346	2	,	,	PUNCT
eurjchem-952	346	3	s.	s.	PROPN
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eurjchem-952	346	6	,	,	PUNCT
eurjchem-952	346	7	u.	u.	PROPN
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eurjchem-952	346	10	,	,	PUNCT
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eurjchem-952	346	12	s.	s.	PROPN
eurjchem-952	346	13	oriental	oriental	PROPN
eurjchem-952	346	14	j.	j.	PROPN
eurjchem-952	346	15	chem	chem	PROPN
eurjchem-952	346	16	.	.	PUNCT
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eurjchem-952	347	2	,	,	PUNCT
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eurjchem-952	347	7	,	,	PUNCT
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eurjchem-952	347	9	.	.	PUNCT
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eurjchem-952	348	3	]	]	PUNCT
eurjchem-952	348	4	.	.	PUNCT
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eurjchem-952	348	6	,	,	PUNCT
eurjchem-952	348	7	n.	n.	PROPN
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eurjchem-952	348	9	;	;	PUNCT
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eurjchem-952	348	11	,	,	PUNCT
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eurjchem-952	348	14	;	;	PUNCT
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eurjchem-952	348	16	,	,	PUNCT
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eurjchem-952	348	20	,	,	PUNCT
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eurjchem-952	348	24	,	,	PUNCT
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eurjchem-952	349	1	[	[	X
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eurjchem-952	349	4	.	.	PUNCT
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eurjchem-952	350	2	,	,	PUNCT
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eurjchem-952	350	6	,	,	PUNCT
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eurjchem-952	350	8	;	;	PUNCT
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eurjchem-952	350	10	,	,	PUNCT
eurjchem-952	350	11	v.	v.	PROPN
eurjchem-952	350	12	p.	p.	PROPN
eurjchem-952	350	13	;	;	PUNCT
eurjchem-952	350	14	raizada	raizada	PROPN
eurjchem-952	350	15	,	,	PUNCT
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eurjchem-952	350	17	synth	synth	PROPN
eurjchem-952	350	18	.	.	PUNCT
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eurjchem-952	350	20	.	.	PUNCT
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eurjchem-952	351	2	.	.	PUNCT
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eurjchem-952	352	2	.	.	PUNCT
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eurjchem-952	353	2	.	.	PUNCT
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eurjchem-952	353	4	.	.	PUNCT
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eurjchem-952	354	2	,	,	PUNCT
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eurjchem-952	354	4	)	)	PUNCT
eurjchem-952	354	5	,	,	PUNCT
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eurjchem-952	354	7	.	.	PUNCT
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eurjchem-952	355	3	]	]	PUNCT
eurjchem-952	355	4	.	.	PUNCT
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eurjchem-952	355	6	,	,	PUNCT
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eurjchem-952	355	8	;	;	PUNCT
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eurjchem-952	355	16	;	;	PUNCT
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eurjchem-952	355	18	,	,	PUNCT
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eurjchem-952	356	2	.	.	PUNCT
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eurjchem-952	357	3	,	,	PUNCT
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eurjchem-952	357	5	,	,	PUNCT
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eurjchem-952	358	4	.	.	PUNCT
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eurjchem-952	359	2	,	,	PUNCT
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eurjchem-952	360	3	,	,	PUNCT
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eurjchem-952	360	5	,	,	PUNCT
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eurjchem-952	361	4	.	.	PUNCT
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eurjchem-952	361	14	;	;	PUNCT
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eurjchem-952	361	25	,	,	PUNCT
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eurjchem-952	361	28	.	.	PUNCT
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eurjchem-952	362	4	.	.	PUNCT
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eurjchem-952	363	2	,	,	PUNCT
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eurjchem-952	363	5	;	;	PUNCT
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eurjchem-952	363	17	,	,	PUNCT
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eurjchem-952	363	22	,	,	PUNCT
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eurjchem-952	363	24	;	;	PUNCT
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eurjchem-952	363	26	,	,	PUNCT
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eurjchem-952	364	2	.	.	PUNCT
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eurjchem-952	365	2	,	,	PUNCT
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eurjchem-952	365	4	,	,	PUNCT
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eurjchem-952	365	6	.	.	PUNCT
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eurjchem-952	366	4	.	.	PUNCT
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eurjchem-952	367	2	,	,	PUNCT
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eurjchem-952	367	5	;	;	PUNCT
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eurjchem-952	367	11	.	.	PUNCT
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eurjchem-952	368	2	.	.	PUNCT
eurjchem-952	369	1	acta	acta	PROPN
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eurjchem-952	369	3	,	,	PUNCT
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eurjchem-952	369	5	,	,	PUNCT
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eurjchem-952	369	7	.	.	PUNCT
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eurjchem-952	370	4	.	.	PUNCT
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eurjchem-952	372	2	.	.	PUNCT
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eurjchem-952	373	2	.	.	PROPN
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eurjchem-952	373	4	,	,	PUNCT
eurjchem-952	373	5	23	23	NUM
eurjchem-952	373	6	,	,	PUNCT
eurjchem-952	373	7	327‐334	327‐334	NUM
eurjchem-952	373	8	.	.	PUNCT
eurjchem-952	374	1	[	[	X
eurjchem-952	374	2	24	24	NUM
eurjchem-952	374	3	]	]	PUNCT
eurjchem-952	374	4	.	.	PUNCT
eurjchem-952	375	1	farrell	farrell	PROPN
eurjchem-952	375	2	,	,	PUNCT
eurjchem-952	375	3	n.	n.	PROPN
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eurjchem-952	375	6	complexes	complex	NOUN
eurjchem-952	375	7	as	as	ADP
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eurjchem-952	375	12	,	,	PUNCT
eurjchem-952	375	13	kluwer	kluwer	NOUN
eurjchem-952	375	14	academic	academic	NOUN
eurjchem-952	375	15	,	,	PUNCT
eurjchem-952	375	16	dordrecht	dordrecht	PROPN
eurjchem-952	375	17	,	,	PUNCT
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eurjchem-952	375	19	.	.	PUNCT
eurjchem-952	376	1	[	[	X
eurjchem-952	376	2	25	25	NUM
eurjchem-952	376	3	]	]	PUNCT
eurjchem-952	376	4	.	.	PUNCT
eurjchem-952	377	1	hyper	hyper	PROPN
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eurjchem-952	377	3	.	.	PUNCT
eurjchem-952	378	1	version	version	NOUN
eurjchem-952	378	2	7.5	7.5	NUM
eurjchem-952	378	3	hypercube	hypercube	NOUN
eurjchem-952	378	4	,	,	PUNCT
eurjchem-952	378	5	inc	inc	PROPN
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eurjchem-952	378	7	,	,	PUNCT
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eurjchem-952	378	9	.	.	PUNCT
eurjchem-952	379	1	[	[	X
eurjchem-952	379	2	26	26	NUM
eurjchem-952	379	3	]	]	PUNCT
eurjchem-952	379	4	.	.	PUNCT
eurjchem-952	380	1	bauer	bauer	PROPN
eurjchem-952	380	2	,	,	PUNCT
eurjchem-952	380	3	a.	a.	PROPN
eurjchem-952	380	4	w.	w.	PROPN
eurjchem-952	380	5	;	;	PUNCT
eurjchem-952	380	6	kirby	kirby	PROPN
eurjchem-952	380	7	,	,	PUNCT
eurjchem-952	380	8	w.	w.	PROPN
eurjchem-952	380	9	m.	m.	NOUN
eurjchem-952	380	10	;	;	PUNCT
eurjchem-952	380	11	sherris	sherris	PROPN
eurjchem-952	380	12	,	,	PUNCT
eurjchem-952	380	13	c.	c.	PROPN
eurjchem-952	380	14	;	;	PUNCT
eurjchem-952	380	15	turck	turck	ADV
eurjchem-952	380	16	,	,	PUNCT
eurjchem-952	380	17	m.	m.	NOUN
eurjchem-952	380	18	am	be	AUX
eurjchem-952	380	19	.	.	PUNCT
eurjchem-952	381	1	j.	j.	PROPN
eurjchem-952	381	2	clin	clin	PROPN
eurjchem-952	381	3	.	.	PUNCT
eurjchem-952	382	1	pathol	pathol	PROPN
eurjchem-952	382	2	.	.	PUNCT
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eurjchem-952	383	2	,	,	PUNCT
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eurjchem-952	383	4	,	,	PUNCT
eurjchem-952	383	5	493‐496	493‐496	NOUN
eurjchem-952	383	6	.	.	PUNCT
eurjchem-952	384	1	[	[	X
eurjchem-952	384	2	27	27	NUM
eurjchem-952	384	3	]	]	PUNCT
eurjchem-952	384	4	.	.	PUNCT
eurjchem-952	385	1	liebowitz	liebowitz	PROPN
eurjchem-952	385	2	,	,	PUNCT
eurjchem-952	385	3	l.	l.	PROPN
eurjchem-952	385	4	d.	d.	PROPN
eurjchem-952	385	5	;	;	PUNCT
eurjchem-952	385	6	ashbee	ashbee	PROPN
eurjchem-952	385	7	,	,	PUNCT
eurjchem-952	385	8	h.	h.	PROPN
eurjchem-952	385	9	r.	r.	PROPN
eurjchem-952	385	10	;	;	PUNCT
eurjchem-952	385	11	evans	evans	PROPN
eurjchem-952	385	12	,	,	PUNCT
eurjchem-952	385	13	e.	e.	PROPN
eurjchem-952	385	14	g.	g.	PROPN
eurjchem-952	385	15	v.	v.	PROPN
eurjchem-952	385	16	;	;	PUNCT
eurjchem-952	385	17	chong	chong	PROPN
eurjchem-952	385	18	,	,	PUNCT
eurjchem-952	385	19	y.	y.	PROPN
eurjchem-952	385	20	;	;	PUNCT
eurjchem-952	385	21	mallatova	mallatova	PROPN
eurjchem-952	385	22	,	,	PUNCT
eurjchem-952	385	23	n.	n.	NOUN
eurjchem-952	385	24	;	;	PUNCT
eurjchem-952	385	25	zaidi	zaidi	PROPN
eurjchem-952	385	26	,	,	PUNCT
eurjchem-952	385	27	m.	m.	NOUN
eurjchem-952	385	28	;	;	PUNCT
eurjchem-952	385	29	gibbs	gibbs	PROPN
eurjchem-952	385	30	,	,	PUNCT
eurjchem-952	385	31	d.	d.	PROPN
eurjchem-952	385	32	microbiol	microbiol	PROPN
eurjchem-952	385	33	.	.	PUNCT
eurjchem-952	386	1	infet	infet	PROPN
eurjchem-952	386	2	.	.	PUNCT
eurjchem-952	387	1	dis	dis	PROPN
eurjchem-952	387	2	.	.	PUNCT
eurjchem-952	388	1	2001	2001	NUM
eurjchem-952	388	2	,	,	PUNCT
eurjchem-952	388	3	24	24	NUM
eurjchem-952	388	4	,	,	PUNCT
eurjchem-952	388	5	27‐33	27‐33	NUM
eurjchem-952	388	6	.	.	PUNCT
eurjchem-952	389	1	[	[	X
eurjchem-952	389	2	28	28	NUM
eurjchem-952	389	3	]	]	PUNCT
eurjchem-952	389	4	.	.	PUNCT
eurjchem-952	390	1	pfaller	pfaller	NOUN
eurjchem-952	390	2	,	,	PUNCT
eurjchem-952	390	3	m.	m.	NOUN
eurjchem-952	390	4	a.	a.	NOUN
eurjchem-952	390	5	;	;	PUNCT
eurjchem-952	390	6	burmeister	burmeister	NOUN
eurjchem-952	390	7	,	,	PUNCT
eurjchem-952	390	8	l.	l.	PROPN
eurjchem-952	390	9	;	;	PUNCT
eurjchem-952	390	10	bartlett	bartlett	PROPN
eurjchem-952	390	11	,	,	PUNCT
eurjchem-952	390	12	m.	m.	NOUN
eurjchem-952	390	13	a.	a.	PROPN
eurjchem-952	390	14	;	;	PUNCT
eurjchem-952	390	15	rinaldi	rinaldi	PROPN
eurjchem-952	390	16	,	,	PUNCT
eurjchem-952	390	17	m.	m.	NOUN
eurjchem-952	390	18	g.	g.	PROPN
eurjchem-952	390	19	j.	j.	PROPN
eurjchem-952	390	20	clin	clin	PROPN
eurjchem-952	390	21	.	.	PUNCT
eurjchem-952	391	1	microbiol	microbiol	PROPN
eurjchem-952	391	2	.	.	PUNCT
eurjchem-952	392	1	1988	1988	NUM
eurjchem-952	392	2	,	,	PUNCT
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eurjchem-952	392	4	,	,	PUNCT
eurjchem-952	392	5	1437‐1441	1437‐1441	NUM
eurjchem-952	392	6	.	.	PUNCT
eurjchem-952	393	1	[	[	X
eurjchem-952	393	2	29	29	NUM
eurjchem-952	393	3	]	]	PUNCT
eurjchem-952	393	4	.	.	PUNCT
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eurjchem-952	394	7	,	,	PUNCT
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eurjchem-952	394	10	for	for	ADP
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eurjchem-952	394	13	antifungal	antifungal	ADJ
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eurjchem-952	394	20	:	:	PUNCT
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eurjchem-952	394	23	m38‐a	m38‐a	PROPN
eurjchem-952	394	24	,	,	PUNCT
eurjchem-952	394	25	nccls	nccls	PROPN
eurjchem-952	394	26	,	,	PUNCT
eurjchem-952	394	27	wayne	wayne	PROPN
eurjchem-952	394	28	,	,	PUNCT
eurjchem-952	394	29	pa	pa	PROPN
eurjchem-952	394	30	,	,	PUNCT
eurjchem-952	394	31	usa	usa	PROPN
eurjchem-952	394	32	,	,	PUNCT
eurjchem-952	394	33	2002	2002	NUM
eurjchem-952	394	34	.	.	PUNCT
eurjchem-952	395	1	[	[	X
eurjchem-952	395	2	30	30	NUM
eurjchem-952	395	3	]	]	PUNCT
eurjchem-952	395	4	.	.	PUNCT
eurjchem-952	396	1	skehan	skehan	PROPN
eurjchem-952	396	2	,	,	PUNCT
eurjchem-952	396	3	p.	p.	NOUN
eurjchem-952	396	4	;	;	PUNCT
eurjchem-952	396	5	storeng	storeng	PROPN
eurjchem-952	396	6	,	,	PUNCT
eurjchem-952	396	7	r.	r.	PROPN
eurjchem-952	396	8	;	;	PUNCT
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eurjchem-952	396	10	,	,	PUNCT
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eurjchem-952	396	12	;	;	PUNCT
eurjchem-952	396	13	monks	monk	NOUN
eurjchem-952	396	14	,	,	PUNCT
eurjchem-952	396	15	a.	a.	NOUN
eurjchem-952	396	16	;	;	PUNCT
eurjchem-952	396	17	mcmahon	mcmahon	PROPN
eurjchem-952	396	18	,	,	PUNCT
eurjchem-952	396	19	j.	j.	PROPN
eurjchem-952	396	20	;	;	PUNCT
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eurjchem-952	396	22	,	,	PUNCT
eurjchem-952	396	23	d.	d.	PROPN
eurjchem-952	396	24	;	;	PUNCT
eurjchem-952	396	25	warren	warren	PROPN
eurjchem-952	396	26	,	,	PUNCT
eurjchem-952	396	27	j.	j.	PROPN
eurjchem-952	396	28	t.	t.	PROPN
eurjchem-952	396	29	;	;	PUNCT
eurjchem-952	396	30	bokesch	bokesch	PROPN
eurjchem-952	396	31	,	,	PUNCT
eurjchem-952	396	32	h.	h.	PROPN
eurjchem-952	396	33	;	;	PUNCT
eurjchem-952	396	34	kenney	kenney	PROPN
eurjchem-952	396	35	,	,	PUNCT
eurjchem-952	396	36	s.	s.	PROPN
eurjchem-952	396	37	;	;	PUNCT
eurjchem-952	396	38	boyd	boyd	PROPN
eurjchem-952	396	39	,	,	PUNCT
eurjchem-952	396	40	m.	m.	PROPN
eurjchem-952	396	41	r.	r.	PROPN
eurjchem-952	396	42	j.	j.	PROPN
eurjchem-952	396	43	natl	natl	PROPN
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eurjchem-952	396	45	inst	inst	PROPN
eurjchem-952	396	46	.	.	PUNCT
eurjchem-952	397	1	1990	1990	NUM
eurjchem-952	397	2	,	,	PUNCT
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eurjchem-952	397	4	,	,	PUNCT
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eurjchem-952	397	6	.	.	PUNCT
eurjchem-952	398	1	[	[	X
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eurjchem-952	398	3	]	]	PUNCT
eurjchem-952	398	4	.	.	PUNCT
eurjchem-952	399	1	el‐sherif	el‐sherif	PROPN
eurjchem-952	399	2	,	,	PUNCT
eurjchem-952	399	3	a.	a.	NOUN
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eurjchem-952	399	5	;	;	PUNCT
eurjchem-952	399	6	shehata	shehata	NOUN
eurjchem-952	399	7	,	,	PUNCT
eurjchem-952	399	8	m.	m.	NOUN
eurjchem-952	399	9	r.	r.	PROPN
eurjchem-952	399	10	;	;	PUNCT
eurjchem-952	399	11	shoukry	shoukry	NOUN
eurjchem-952	399	12	,	,	PUNCT
eurjchem-952	399	13	m.	m.	NOUN
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eurjchem-952	399	15	;	;	PUNCT
eurjchem-952	399	16	barakat	barakat	PROPN
eurjchem-952	399	17	,	,	PUNCT
eurjchem-952	399	18	m.	m.	PROPN
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eurjchem-952	399	20	j.	j.	PROPN
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eurjchem-952	399	22	.	.	PUNCT
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eurjchem-952	400	2	a	a	DET
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eurjchem-952	400	4	,	,	PUNCT
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eurjchem-952	400	6	,	,	PUNCT
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eurjchem-952	400	8	.	.	PUNCT
eurjchem-952	401	1	[	[	X
eurjchem-952	401	2	32	32	NUM
eurjchem-952	401	3	]	]	PUNCT
eurjchem-952	401	4	.	.	PUNCT
eurjchem-952	402	1	aljahdali	aljahdali	PROPN
eurjchem-952	402	2	,	,	PUNCT
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eurjchem-952	402	4	s.	s.	PROPN
eurjchem-952	402	5	eur	eur	PROPN
eurjchem-952	402	6	.	.	PUNCT
eurjchem-952	403	1	j.	j.	PROPN
eurjchem-952	403	2	chem	chem	PROPN
eurjchem-952	403	3	.	.	PUNCT
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eurjchem-952	404	2	,	,	PUNCT
eurjchem-952	404	3	4(4	4(4	NUM
eurjchem-952	404	4	)	)	PUNCT
eurjchem-952	404	5	,	,	PUNCT
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eurjchem-952	404	7	.	.	PUNCT
eurjchem-952	405	1	[	[	X
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eurjchem-952	405	3	]	]	PUNCT
eurjchem-952	405	4	.	.	PUNCT
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eurjchem-952	406	2	,	,	PUNCT
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eurjchem-952	406	5	;	;	PUNCT
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eurjchem-952	406	7	,	,	PUNCT
eurjchem-952	406	8	d.	d.	PROPN
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eurjchem-952	406	10	;	;	PUNCT
eurjchem-952	406	11	jaiswal	jaiswal	PROPN
eurjchem-952	406	12	,	,	PUNCT
eurjchem-952	406	13	s.	s.	PROPN
eurjchem-952	406	14	k.	k.	PROPN
eurjchem-952	406	15	;	;	PUNCT
eurjchem-952	406	16	dubey	dubey	PROPN
eurjchem-952	406	17	,	,	PUNCT
eurjchem-952	406	18	j.	j.	PROPN
eurjchem-952	406	19	synth	synth	PROPN
eurjchem-952	406	20	.	.	PUNCT
eurjchem-952	407	1	react	react	VERB
eurjchem-952	407	2	.	.	PUNCT
eurjchem-952	408	1	inorg	inorg	PROPN
eurjchem-952	408	2	.	.	PUNCT
eurjchem-952	409	1	met	meet	VERB
eurjchem-952	409	2	.	.	PUNCT
eurjchem-952	410	1	org	org	NOUN
eurjchem-952	410	2	.	.	PUNCT
eurjchem-952	410	3	chem	chem	PROPN
eurjchem-952	410	4	.	.	PUNCT
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eurjchem-952	411	2	,	,	PUNCT
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eurjchem-952	411	4	,	,	PUNCT
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eurjchem-952	411	6	.	.	PUNCT
eurjchem-952	412	1	[	[	X
eurjchem-952	412	2	34	34	NUM
eurjchem-952	412	3	]	]	PUNCT
eurjchem-952	412	4	.	.	PUNCT
eurjchem-952	412	5	el‐sherif	el‐sherif	PROPN
eurjchem-952	412	6	,	,	PUNCT
eurjchem-952	412	7	a.	a.	NOUN
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eurjchem-952	412	9	;	;	PUNCT
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eurjchem-952	412	12	t.	t.	PROPN
eurjchem-952	412	13	m.	m.	PROPN
eurjchem-952	412	14	spectrochim	spectrochim	PROPN
eurjchem-952	412	15	.	.	PUNCT
eurjchem-952	413	1	acta	acta	PROPN
eurjchem-952	413	2	a	a	DET
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eurjchem-952	413	4	,	,	PUNCT
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eurjchem-952	413	6	,	,	PUNCT
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eurjchem-952	414	1	[	[	X
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eurjchem-952	414	3	]	]	SYM
eurjchem-952	414	4	.	.	PUNCT
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eurjchem-952	415	2	,	,	PUNCT
eurjchem-952	415	3	m.	m.	PROPN
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eurjchem-952	415	5	p.	p.	PROPN
eurjchem-952	415	6	;	;	PUNCT
eurjchem-952	415	7	joseph	joseph	PROPN
eurjchem-952	415	8	,	,	PUNCT
eurjchem-952	415	9	m.	m.	NOUN
eurjchem-952	415	10	synth	synth	NOUN
eurjchem-952	415	11	.	.	PUNCT
eurjchem-952	416	1	react	react	VERB
eurjchem-952	416	2	.	.	PUNCT
eurjchem-952	417	1	inorg	inorg	PROPN
eurjchem-952	417	2	.	.	PUNCT
eurjchem-952	418	1	met	meet	VERB
eurjchem-952	418	2	.	.	PUNCT
eurjchem-952	419	1	org	org	NOUN
eurjchem-952	419	2	.	.	PUNCT
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eurjchem-952	419	4	.	.	PUNCT
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eurjchem-952	420	2	,	,	PUNCT
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eurjchem-952	420	4	,	,	PUNCT
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eurjchem-952	420	6	.	.	PUNCT
eurjchem-952	421	1	[	[	X
eurjchem-952	421	2	36	36	NUM
eurjchem-952	421	3	]	]	PUNCT
eurjchem-952	421	4	.	.	PUNCT
eurjchem-952	422	1	philip	philip	PROPN
eurjchem-952	422	2	,	,	PUNCT
eurjchem-952	422	3	v.	v.	PROPN
eurjchem-952	422	4	;	;	PUNCT
eurjchem-952	422	5	suni	suni	X
eurjchem-952	422	6	,	,	PUNCT
eurjchem-952	422	7	v.	v.	ADP
eurjchem-952	422	8	;	;	PUNCT
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eurjchem-952	422	10	,	,	PUNCT
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eurjchem-952	422	13	p.	p.	PROPN
eurjchem-952	422	14	;	;	PUNCT
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eurjchem-952	422	20	,	,	PUNCT
eurjchem-952	422	21	23	23	NUM
eurjchem-952	422	22	,	,	PUNCT
eurjchem-952	422	23	1225‐1233	1225‐1233	NUM
eurjchem-952	422	24	.	.	PUNCT
eurjchem-952	423	1	[	[	X
eurjchem-952	423	2	37	37	NUM
eurjchem-952	423	3	]	]	PUNCT
eurjchem-952	423	4	.	.	PUNCT
eurjchem-952	424	1	lever	lever	PROPN
eurjchem-952	424	2	,	,	PUNCT
eurjchem-952	424	3	a.	a.	PROPN
eurjchem-952	424	4	b.	b.	PROPN
eurjchem-952	424	5	p.	p.	PROPN
eurjchem-952	424	6	inorganic	inorganic	ADJ
eurjchem-952	424	7	electronic	electronic	ADJ
eurjchem-952	424	8	spectroscopy	spectroscopy	NOUN
eurjchem-952	424	9	,	,	PUNCT
eurjchem-952	424	10	2nd	2nd	ADJ
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eurjchem-952	424	12	,	,	PUNCT
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eurjchem-952	424	14	,	,	PUNCT
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eurjchem-952	424	16	,	,	PUNCT
eurjchem-952	424	17	1984	1984	NUM
eurjchem-952	424	18	.	.	PUNCT
eurjchem-952	425	1	[	[	X
eurjchem-952	425	2	38	38	NUM
eurjchem-952	425	3	]	]	PUNCT
eurjchem-952	425	4	.	.	PUNCT
eurjchem-952	426	1	el‐sherif	el‐sherif	PROPN
eurjchem-952	426	2	,	,	PUNCT
eurjchem-952	426	3	a.	a.	NOUN
eurjchem-952	426	4	a.	a.	NOUN
eurjchem-952	426	5	;	;	PUNCT
eurjchem-952	426	6	shoukry	shoukry	NOUN
eurjchem-952	426	7	,	,	PUNCT
eurjchem-952	426	8	m.	m.	NOUN
eurjchem-952	426	9	m.	m.	NOUN
eurjchem-952	426	10	;	;	PUNCT
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eurjchem-952	426	12	,	,	PUNCT
eurjchem-952	426	13	m.	m.	NOUN
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eurjchem-952	426	15	a.	a.	PROPN
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eurjchem-952	426	17	.	.	PUNCT
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eurjchem-952	427	4	,	,	PUNCT
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eurjchem-952	427	6	,	,	PUNCT
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eurjchem-952	428	1	[	[	X
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eurjchem-952	428	3	]	]	PUNCT
eurjchem-952	428	4	.	.	PUNCT
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eurjchem-952	429	2	,	,	PUNCT
eurjchem-952	429	3	k.	k.	PROPN
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eurjchem-952	429	13	,	,	PUNCT
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eurjchem-952	429	18	,	,	PUNCT
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eurjchem-952	429	20	.	.	PUNCT
eurjchem-952	430	1	[	[	X
eurjchem-952	430	2	40	40	NUM
eurjchem-952	430	3	]	]	PUNCT
eurjchem-952	430	4	.	.	PUNCT
eurjchem-952	431	1	philip	philip	PROPN
eurjchem-952	431	2	,	,	PUNCT
eurjchem-952	431	3	v.	v.	PROPN
eurjchem-952	431	4	;	;	PUNCT
eurjchem-952	431	5	suni	suni	X
eurjchem-952	431	6	,	,	PUNCT
eurjchem-952	431	7	v.	v.	ADP
eurjchem-952	431	8	;	;	PUNCT
eurjchem-952	431	9	kurup	kurup	NOUN
eurjchem-952	431	10	,	,	PUNCT
eurjchem-952	431	11	m.	m.	PROPN
eurjchem-952	431	12	r.	r.	PROPN
eurjchem-952	431	13	p.	p.	PROPN
eurjchem-952	431	14	polyhedron	polyhedron	PROPN
eurjchem-952	431	15	2006	2006	NUM
eurjchem-952	431	16	,	,	PUNCT
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eurjchem-952	431	18	,	,	PUNCT
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eurjchem-952	431	20	.	.	PUNCT
eurjchem-952	432	1	[	[	X
eurjchem-952	432	2	41	41	NUM
eurjchem-952	432	3	]	]	PUNCT
eurjchem-952	432	4	.	.	PUNCT
eurjchem-952	433	1	sankaraperumal	sankaraperumal	PROPN
eurjchem-952	433	2	,	,	PUNCT
eurjchem-952	433	3	a.	a.	NOUN
eurjchem-952	433	4	;	;	PUNCT
eurjchem-952	433	5	karthikeyan	karthikeyan	PROPN
eurjchem-952	433	6	,	,	PUNCT
eurjchem-952	433	7	j.	j.	PROPN
eurjchem-952	433	8	;	;	PUNCT
eurjchem-952	433	9	shetty	shetty	PROPN
eurjchem-952	433	10	,	,	PUNCT
eurjchem-952	433	11	a.	a.	PROPN
eurjchem-952	433	12	n.	n.	PROPN
eurjchem-952	433	13	;	;	PUNCT
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eurjchem-952	433	15	,	,	PUNCT
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eurjchem-952	433	17	polyhedron	polyhedron	PROPN
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eurjchem-952	433	19	,	,	PUNCT
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eurjchem-952	433	21	,	,	PUNCT
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eurjchem-952	433	23	.	.	PUNCT
eurjchem-952	434	1	[	[	X
eurjchem-952	434	2	42	42	NUM
eurjchem-952	434	3	]	]	PUNCT
eurjchem-952	434	4	.	.	PUNCT
eurjchem-952	435	1	suzuki	suzuki	PROPN
eurjchem-952	435	2	,	,	PUNCT
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eurjchem-952	435	4	;	;	PUNCT
eurjchem-952	435	5	kanatomi	kanatomi	PROPN
eurjchem-952	435	6	,	,	PUNCT
eurjchem-952	435	7	h.	h.	PROPN
eurjchem-952	435	8	;	;	PUNCT
eurjchem-952	435	9	koyama	koyama	PROPN
eurjchem-952	435	10	,	,	PUNCT
eurjchem-952	435	11	h.	h.	PROPN
eurjchem-952	435	12	;	;	PUNCT
eurjchem-952	435	13	murase	murase	PROPN
eurjchem-952	435	14	,	,	PUNCT
eurjchem-952	435	15	i.	i.	PROPN
eurjchem-952	435	16	bull	bull	PROPN
eurjchem-952	435	17	.	.	PUNCT
eurjchem-952	436	1	chem	chem	PROPN
eurjchem-952	436	2	.	.	PUNCT
eurjchem-952	437	1	soc	soc	PROPN
eurjchem-952	437	2	.	.	PUNCT
eurjchem-952	438	1	japan	japan	PROPN
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eurjchem-952	438	3	,	,	PUNCT
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eurjchem-952	438	5	,	,	PUNCT
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eurjchem-952	438	7	.	.	PUNCT
eurjchem-952	439	1	[	[	X
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eurjchem-952	439	3	]	]	PUNCT
eurjchem-952	439	4	.	.	PUNCT
eurjchem-952	440	1	li	li	PROPN
eurjchem-952	440	2	,	,	PUNCT
eurjchem-952	440	3	q.	q.	PROPN
eurjchem-952	440	4	;	;	PUNCT
eurjchem-952	440	5	tang	tang	PROPN
eurjchem-952	440	6	,	,	PUNCT
eurjchem-952	440	7	h.	h.	PROPN
eurjchem-952	440	8	;	;	PUNCT
eurjchem-952	440	9	li	li	PROPN
eurjchem-952	440	10	,	,	PUNCT
eurjchem-952	440	11	y.	y.	PROPN
eurjchem-952	440	12	;	;	PUNCT
eurjchem-952	440	13	wang	wang	PROPN
eurjchem-952	440	14	,	,	PUNCT
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eurjchem-952	440	19	l.	l.	PROPN
eurjchem-952	440	20	;	;	PUNCT
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eurjchem-952	440	23	c.	c.	PROPN
eurjchem-952	440	24	j.	j.	PROPN
eurjchem-952	440	25	inorg	inorg	PROPN
eurjchem-952	440	26	.	.	PUNCT
eurjchem-952	441	1	biochem	biochem	PROPN
eurjchem-952	441	2	.	.	PUNCT
eurjchem-952	442	1	2000	2000	NUM
eurjchem-952	442	2	,	,	PUNCT
eurjchem-952	442	3	78	78	NUM
eurjchem-952	442	4	,	,	PUNCT
eurjchem-952	442	5	167‐178	167‐178	NUM
eurjchem-952	442	6	.	.	PUNCT
eurjchem-952	443	1	[	[	X
eurjchem-952	443	2	44	44	NUM
eurjchem-952	443	3	]	]	PUNCT
eurjchem-952	443	4	.	.	PUNCT
eurjchem-952	444	1	mohan	mohan	PROPN
eurjchem-952	444	2	,	,	PUNCT
eurjchem-952	444	3	m.	m.	NOUN
eurjchem-952	444	4	;	;	PUNCT
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eurjchem-952	444	6	,	,	PUNCT
eurjchem-952	444	7	m.	m.	PROPN
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eurjchem-952	445	2	.	.	PUNCT
eurjchem-952	446	1	1985	1985	NUM
eurjchem-952	446	2	,	,	PUNCT
eurjchem-952	446	3	10	10	NUM
eurjchem-952	446	4	,	,	PUNCT
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eurjchem-952	446	6	.	.	PUNCT
eurjchem-952	447	1	[	[	X
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eurjchem-952	447	3	]	]	PUNCT
eurjchem-952	447	4	.	.	PUNCT
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eurjchem-952	448	2	,	,	PUNCT
eurjchem-952	448	3	v.	v.	PROPN
eurjchem-952	448	4	p.	p.	NOUN
eurjchem-952	448	5	;	;	PUNCT
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eurjchem-952	448	7	,	,	PUNCT
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eurjchem-952	448	9	j.	j.	PROPN
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eurjchem-952	448	12	.	.	PUNCT
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eurjchem-952	449	2	.	.	PUNCT
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eurjchem-952	450	2	,	,	PUNCT
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eurjchem-952	450	4	,	,	PUNCT
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eurjchem-952	451	3	]	]	PUNCT
eurjchem-952	451	4	.	.	PUNCT
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eurjchem-952	451	8	;	;	PUNCT
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eurjchem-952	452	6	.	.	PUNCT
eurjchem-952	453	1	j.	j.	PROPN
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eurjchem-952	453	3	.	.	PUNCT
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eurjchem-952	454	2	,	,	PUNCT
eurjchem-952	454	3	4(4	4(4	NUM
eurjchem-952	454	4	)	)	PUNCT
eurjchem-952	454	5	,	,	PUNCT
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eurjchem-952	454	8	.	.	PUNCT
eurjchem-952	455	1	[	[	X
eurjchem-952	455	2	47	47	NUM
eurjchem-952	455	3	]	]	PUNCT
eurjchem-952	455	4	.	.	PUNCT
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eurjchem-952	456	8	.	.	PUNCT
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eurjchem-952	457	2	,	,	PUNCT
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eurjchem-952	457	4	,	,	PUNCT
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eurjchem-952	457	6	.	.	PUNCT
eurjchem-952	458	1	[	[	X
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eurjchem-952	458	3	]	]	PUNCT
eurjchem-952	458	4	.	.	PUNCT
eurjchem-952	459	1	lever	lever	PROPN
eurjchem-952	459	2	,	,	PUNCT
eurjchem-952	460	1	a.	a.	PROPN
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eurjchem-952	460	4	;	;	PUNCT
eurjchem-952	461	1	lewis	lewis	PROPN
eurjchem-952	461	2	,	,	PUNCT
eurjchem-952	461	3	j.	j.	PROPN
eurjchem-952	461	4	;	;	PUNCT
eurjchem-952	461	5	nyholm	nyholm	PROPN
eurjchem-952	461	6	,	,	PUNCT
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eurjchem-952	461	8	s.	s.	PROPN
eurjchem-952	461	9	j.	j.	PROPN
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eurjchem-952	462	2	.	.	PUNCT
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eurjchem-952	463	2	,	,	PUNCT
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eurjchem-952	463	5	.	.	PUNCT
eurjchem-952	464	1	[	[	X
eurjchem-952	464	2	49	49	NUM
eurjchem-952	464	3	]	]	PUNCT
eurjchem-952	464	4	.	.	PUNCT
eurjchem-952	465	1	ballhausen	ballhausen	PROPN
eurjchem-952	465	2	,	,	PUNCT
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eurjchem-952	466	16	,	,	PUNCT
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eurjchem-952	467	1	[	[	X
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eurjchem-952	467	3	]	]	PUNCT
eurjchem-952	467	4	.	.	PUNCT
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eurjchem-952	468	2	,	,	PUNCT
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eurjchem-952	468	5	;	;	PUNCT
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eurjchem-952	468	7	,	,	PUNCT
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eurjchem-952	468	9	a.	a.	PROPN
eurjchem-952	468	10	g.	g.	PROPN
eurjchem-952	468	11	coord	coord	PROPN
eurjchem-952	468	12	.	.	PUNCT
eurjchem-952	469	1	chem	chem	PROPN
eurjchem-952	469	2	.	.	PUNCT
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eurjchem-952	470	2	.	.	PROPN
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eurjchem-952	470	4	,	,	PUNCT
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eurjchem-952	470	6	,	,	PUNCT
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eurjchem-952	470	9	.	.	PUNCT
eurjchem-952	471	1	[	[	X
eurjchem-952	471	2	51	51	NUM
eurjchem-952	471	3	]	]	PUNCT
eurjchem-952	471	4	.	.	PUNCT
eurjchem-952	472	1	balasubramanian	balasubramanian	PROPN
eurjchem-952	472	2	,	,	PUNCT
eurjchem-952	472	3	b.	b.	PROPN
eurjchem-952	472	4	;	;	PUNCT
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eurjchem-952	472	6	,	,	PUNCT
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eurjchem-952	472	8	n.	n.	PROPN
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eurjchem-952	472	11	,	,	PUNCT
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eurjchem-952	472	15	.	.	PUNCT
eurjchem-952	473	1	[	[	X
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eurjchem-952	473	4	.	.	PUNCT
eurjchem-952	474	1	dudley	dudley	PROPN
eurjchem-952	474	2	,	,	PUNCT
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eurjchem-952	474	5	;	;	PUNCT
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eurjchem-952	474	7	,	,	PUNCT
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eurjchem-952	474	9	j.	j.	PROPN
eurjchem-952	474	10	j.	j.	PROPN
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eurjchem-952	474	12	.	.	PUNCT
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eurjchem-952	475	2	.	.	PUNCT
eurjchem-952	476	1	a	a	DET
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eurjchem-952	476	3	,	,	PUNCT
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eurjchem-952	476	5	.	.	PUNCT
eurjchem-952	477	1	[	[	X
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eurjchem-952	479	2	.	.	PUNCT
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eurjchem-952	480	3	,	,	PUNCT
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eurjchem-952	481	3	]	]	PUNCT
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eurjchem-952	486	4	.	.	PUNCT
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eurjchem-952	487	2	,	,	PUNCT
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eurjchem-952	488	3	]	]	PUNCT
eurjchem-952	488	4	.	.	PUNCT
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eurjchem-952	489	2	,	,	PUNCT
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eurjchem-952	489	24	.	.	PUNCT
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eurjchem-952	490	2	.	.	PUNCT
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eurjchem-952	492	2	.	.	PUNCT
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eurjchem-952	493	2	.	.	PUNCT
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eurjchem-952	493	4	.	.	PUNCT
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eurjchem-952	494	2	,	,	PUNCT
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eurjchem-952	494	4	,	,	PUNCT
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eurjchem-952	494	6	.	.	PUNCT
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eurjchem-952	495	3	]	]	PUNCT
eurjchem-952	495	4	.	.	PUNCT
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eurjchem-952	496	2	,	,	PUNCT
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eurjchem-952	497	2	.	.	PUNCT
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eurjchem-952	498	2	,	,	PUNCT
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eurjchem-952	498	4	,	,	PUNCT
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eurjchem-952	498	6	.	.	PUNCT
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eurjchem-952	499	3	]	]	SYM
eurjchem-952	499	4	.	.	PUNCT
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eurjchem-952	499	17	.	.	PUNCT
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eurjchem-952	500	2	.	.	PROPN
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eurjchem-952	500	4	,	,	PUNCT
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eurjchem-952	501	3	]	]	PUNCT
eurjchem-952	501	4	.	.	PUNCT
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eurjchem-952	501	6	,	,	PUNCT
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eurjchem-952	502	2	.	.	PUNCT
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eurjchem-952	503	2	.	.	PUNCT
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eurjchem-952	504	2	.	.	PUNCT
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eurjchem-952	505	2	.	.	PUNCT
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eurjchem-952	505	4	.	.	PUNCT
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eurjchem-952	506	2	,	,	PUNCT
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eurjchem-952	506	4	,	,	PUNCT
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eurjchem-952	506	6	.	.	PUNCT
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eurjchem-952	507	3	]	]	PUNCT
eurjchem-952	507	4	.	.	PUNCT
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eurjchem-952	508	2	,	,	PUNCT
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eurjchem-952	508	22	.	.	PUNCT
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eurjchem-952	509	2	.	.	PUNCT
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eurjchem-952	510	2	.	.	PUNCT
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eurjchem-952	511	2	,	,	PUNCT
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eurjchem-952	512	4	.	.	PUNCT
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eurjchem-952	513	16	.	.	PUNCT
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eurjchem-952	515	4	.	.	PUNCT
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eurjchem-952	516	2	,	,	PUNCT
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eurjchem-952	517	4	.	.	PUNCT
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eurjchem-952	517	6	,	,	PUNCT
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eurjchem-952	517	25	,	,	PUNCT
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eurjchem-952	518	2	.	.	PROPN
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eurjchem-952	518	4	,	,	PUNCT
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eurjchem-952	519	4	.	.	PUNCT
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eurjchem-952	520	2	,	,	PUNCT
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eurjchem-952	520	5	,	,	PUNCT
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eurjchem-952	521	4	.	.	PUNCT
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eurjchem-952	522	13	.	.	PUNCT
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eurjchem-952	524	7	.	.	PUNCT
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eurjchem-952	525	3	]	]	PUNCT
eurjchem-952	525	4	.	.	PUNCT
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eurjchem-952	527	10	,	,	PUNCT
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eurjchem-952	528	3	,	,	PUNCT
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eurjchem-952	528	5	,	,	PUNCT
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eurjchem-952	529	4	.	.	PUNCT
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