id	sid	tid	token	lemma	pos
eurjchem-990	1	1	untitled	untitle	VERB
eurjchem-990	1	2	european	european	PROPN
eurjchem-990	1	3	journal	journal	PROPN
eurjchem-990	1	4	of	of	ADP
eurjchem-990	1	5	chemistry	chemistry	NOUN
eurjchem-990	1	6	5	5	NUM
eurjchem-990	1	7	(	(	PUNCT
eurjchem-990	1	8	2	2	NUM
eurjchem-990	1	9	)	)	PUNCT
eurjchem-990	1	10	(	(	PUNCT
eurjchem-990	1	11	2014	2014	NUM
eurjchem-990	1	12	)	)	PUNCT
eurjchem-990	1	13	252‐259	252‐259	PROPN
eurjchem-990	1	14	european	european	PROPN
eurjchem-990	1	15	journal	journal	PROPN
eurjchem-990	1	16	of	of	ADP
eurjchem-990	1	17	chemistry	chemistry	NOUN
eurjchem-990	1	18	issn	issn	PROPN
eurjchem-990	1	19	2153‐2249	2153‐2249	PROPN
eurjchem-990	1	20	(	(	PUNCT
eurjchem-990	1	21	print	print	NOUN
eurjchem-990	1	22	)	)	PUNCT
eurjchem-990	1	23	/	/	SYM
eurjchem-990	1	24	issn	issn	PROPN
eurjchem-990	1	25	2153‐2257	2153‐2257	NUM
eurjchem-990	1	26	(	(	PUNCT
eurjchem-990	1	27	online	online	ADJ
eurjchem-990	1	28	)	)	PUNCT
eurjchem-990	1	29			NOUN
eurjchem-990	1	30	2014	2014	NUM
eurjchem-990	2	1	eurjchem	eurjchem	PROPN
eurjchem-990	2	2	publishing	publish	VERB
eurjchem-990	2	3	‐	‐	NOUN
eurjchem-990	2	4	printed	print	VERB
eurjchem-990	2	5	in	in	ADP
eurjchem-990	2	6	the	the	DET
eurjchem-990	2	7	usa	usa	PROPN
eurjchem-990	2	8	http://dx.doi.org/10.5155/eurjchem.5.2.252‐259.990	http://dx.doi.org/10.5155/eurjchem.5.2.252‐259.990	PROPN
eurjchem-990	2	9	european	european	PROPN
eurjchem-990	2	10	journal	journal	PROPN
eurjchem-990	2	11	of	of	ADP
eurjchem-990	2	12	chemistry	chemistry	PROPN
eurjchem-990	2	13	journal	journal	PROPN
eurjchem-990	2	14	homepage	homepage	NOUN
eurjchem-990	2	15	:	:	PUNCT
eurjchem-990	2	16	www.eurjchem.com	www.eurjchem.com	X
eurjchem-990	2	17	characterization	characterization	NOUN
eurjchem-990	2	18	and	and	CCONJ
eurjchem-990	2	19	biological	biological	ADJ
eurjchem-990	2	20	activity	activity	NOUN
eurjchem-990	2	21	studies	study	NOUN
eurjchem-990	2	22	on	on	ADP
eurjchem-990	2	23	some	some	DET
eurjchem-990	2	24	transition	transition	NOUN
eurjchem-990	2	25	metal	metal	NOUN
eurjchem-990	2	26	complexes	complex	NOUN
eurjchem-990	2	27	of	of	ADP
eurjchem-990	2	28	thiosemicarbazide	thiosemicarbazide	NOUN
eurjchem-990	2	29	derived	derive	VERB
eurjchem-990	2	30	from	from	ADP
eurjchem-990	2	31	2‐picolinic	2‐picolinic	ADJ
eurjchem-990	2	32	acid	acid	NOUN
eurjchem-990	2	33	hydrazide	hydrazide	ADJ
eurjchem-990	2	34	eshraga	eshraga	PROPN
eurjchem-990	2	35	eltayeb	eltayeb	PROPN
eurjchem-990	2	36	mohamed	mohame	VERB
eurjchem-990	2	37	a	a	PROPN
eurjchem-990	2	38	,	,	PUNCT
eurjchem-990	2	39	abeer	abeer	PROPN
eurjchem-990	2	40	taha	taha	PROPN
eurjchem-990	3	1	abedelkarim	abedelkarim	PROPN
eurjchem-990	3	2	b	b	PROPN
eurjchem-990	3	3	,	,	PUNCT
eurjchem-990	3	4	yahia	yahia	PROPN
eurjchem-990	3	5	hassan	hassan	PROPN
eurjchem-990	3	6	elmalik	elmalik	VERB
eurjchem-990	3	7	a	a	DET
eurjchem-990	3	8	,	,	PUNCT
eurjchem-990	3	9	amna	amna	PROPN
eurjchem-990	3	10	elamin	elamin	PROPN
eurjchem-990	3	11	mohamed	mohame	VERB
eurjchem-990	3	12	a	a	PROPN
eurjchem-990	3	13	and	and	CCONJ
eurjchem-990	3	14	mutlaq	mutlaq	NOUN
eurjchem-990	3	15	sheeded	sheede	VERB
eurjchem-990	3	16	aljahdali	aljahdali	PROPN
eurjchem-990	3	17	c	c	PROPN
eurjchem-990	3	18	a	a	DET
eurjchem-990	3	19	department	department	NOUN
eurjchem-990	3	20	of	of	ADP
eurjchem-990	3	21	chemistry	chemistry	NOUN
eurjchem-990	3	22	,	,	PUNCT
eurjchem-990	3	23	faculty	faculty	NOUN
eurjchem-990	3	24	of	of	ADP
eurjchem-990	3	25	pharmacy	pharmacy	NOUN
eurjchem-990	3	26	,	,	PUNCT
eurjchem-990	3	27	northern	northern	ADJ
eurjchem-990	3	28	borders	border	NOUN
eurjchem-990	3	29	university	university	PROPN
eurjchem-990	3	30	,	,	PUNCT
eurjchem-990	3	31	rafha	rafha	PROPN
eurjchem-990	3	32	,	,	PUNCT
eurjchem-990	3	33	156	156	NUM
eurjchem-990	3	34	,	,	PUNCT
eurjchem-990	3	35	the	the	DET
eurjchem-990	3	36	kingdom	kingdom	NOUN
eurjchem-990	3	37	of	of	ADP
eurjchem-990	3	38	saudi	saudi	PROPN
eurjchem-990	3	39	arabia	arabia	PROPN
eurjchem-990	3	40	b	b	PROPN
eurjchem-990	3	41	department	department	PROPN
eurjchem-990	3	42	of	of	ADP
eurjchem-990	3	43	chemistry	chemistry	NOUN
eurjchem-990	3	44	,	,	PUNCT
eurjchem-990	3	45	faculty	faculty	NOUN
eurjchem-990	3	46	of	of	ADP
eurjchem-990	3	47	science	science	NOUN
eurjchem-990	3	48	,	,	PUNCT
eurjchem-990	3	49	cairo	cairo	PROPN
eurjchem-990	3	50	university	university	PROPN
eurjchem-990	3	51	,	,	PUNCT
eurjchem-990	3	52	giza	giza	PROPN
eurjchem-990	3	53	,	,	PUNCT
eurjchem-990	3	54	12613	12613	NUM
eurjchem-990	3	55	,	,	PUNCT
eurjchem-990	3	56	egypt	egypt	PROPN
eurjchem-990	3	57	c	c	PROPN
eurjchem-990	3	58	department	department	PROPN
eurjchem-990	3	59	of	of	ADP
eurjchem-990	3	60	chemistry	chemistry	NOUN
eurjchem-990	3	61	,	,	PUNCT
eurjchem-990	3	62	faculty	faculty	NOUN
eurjchem-990	3	63	of	of	ADP
eurjchem-990	3	64	science	science	NOUN
eurjchem-990	3	65	,	,	PUNCT
eurjchem-990	3	66	king	king	PROPN
eurjchem-990	3	67	abd	abd	PROPN
eurjchem-990	3	68	al‐aziz	al‐aziz	PROPN
eurjchem-990	3	69	university	university	PROPN
eurjchem-990	3	70	,	,	PUNCT
eurjchem-990	3	71	jeddah	jeddah	PROPN
eurjchem-990	3	72	,	,	PUNCT
eurjchem-990	3	73	21589	21589	NUM
eurjchem-990	3	74	,	,	PUNCT
eurjchem-990	3	75	the	the	DET
eurjchem-990	3	76	kingdom	kingdom	NOUN
eurjchem-990	3	77	of	of	ADP
eurjchem-990	3	78	saudi	saudi	PROPN
eurjchem-990	3	79	arabia	arabia	PROPN
eurjchem-990	3	80	*	*	PUNCT
eurjchem-990	3	81	corresponding	correspond	VERB
eurjchem-990	3	82	author	author	NOUN
eurjchem-990	3	83	at	at	ADP
eurjchem-990	3	84	:	:	PUNCT
eurjchem-990	3	85	department	department	NOUN
eurjchem-990	3	86	of	of	ADP
eurjchem-990	3	87	chemistry	chemistry	NOUN
eurjchem-990	3	88	,	,	PUNCT
eurjchem-990	3	89	faculty	faculty	NOUN
eurjchem-990	3	90	of	of	ADP
eurjchem-990	3	91	pharmacy	pharmacy	NOUN
eurjchem-990	3	92	,	,	PUNCT
eurjchem-990	3	93	northern	northern	ADJ
eurjchem-990	3	94	borders	border	NOUN
eurjchem-990	3	95	university	university	PROPN
eurjchem-990	3	96	,	,	PUNCT
eurjchem-990	3	97	rafha	rafha	PROPN
eurjchem-990	3	98	,	,	PUNCT
eurjchem-990	3	99	156	156	NUM
eurjchem-990	3	100	,	,	PUNCT
eurjchem-990	3	101	the	the	DET
eurjchem-990	3	102	kingdom	kingdom	NOUN
eurjchem-990	3	103	of	of	ADP
eurjchem-990	3	104	saudi	saudi	PROPN
eurjchem-990	3	105	arabia	arabia	PROPN
eurjchem-990	3	106	.	.	PUNCT
eurjchem-990	4	1	tel	tel	PROPN
eurjchem-990	4	2	.	.	PUNCT
eurjchem-990	4	3	:	:	PUNCT
eurjchem-990	5	1	+9.66.569046250	+9.66.569046250	ADJ
eurjchem-990	5	2	.	.	PUNCT
eurjchem-990	6	1	fax	fax	NOUN
eurjchem-990	6	2	:	:	PUNCT
eurjchem-990	6	3	+9.66	+9.66	PROPN
eurjchem-990	6	4	.	.	PROPN
eurjchem-990	6	5	26952293	26952293	NUM
eurjchem-990	6	6	.	.	PUNCT
eurjchem-990	6	7	e‐mail	e‐mail	PUNCT
eurjchem-990	7	1	address	address	NOUN
eurjchem-990	7	2	:	:	PUNCT
eurjchem-990	7	3	meshraka@yahoo.com	meshraka@yahoo.com	X
eurjchem-990	7	4	(	(	PUNCT
eurjchem-990	7	5	e.e	e.e	PROPN
eurjchem-990	7	6	.	.	PROPN
eurjchem-990	7	7	mohamed	mohamed	PROPN
eurjchem-990	7	8	)	)	PUNCT
eurjchem-990	7	9	.	.	PUNCT
eurjchem-990	8	1	article	article	NOUN
eurjchem-990	8	2	information	information	PROPN
eurjchem-990	8	3	abstract	abstract	ADJ
eurjchem-990	8	4	doi	doi	NOUN
eurjchem-990	8	5	:	:	PUNCT
eurjchem-990	8	6	10.5155	10.5155	NUM
eurjchem-990	8	7	/	/	SYM
eurjchem-990	8	8	eurjchem.5.2.252‐259.990	eurjchem.5.2.252‐259.990	NOUN
eurjchem-990	8	9	received	receive	VERB
eurjchem-990	8	10	:	:	PUNCT
eurjchem-990	8	11	05	05	NUM
eurjchem-990	8	12	december	december	PROPN
eurjchem-990	8	13	2013	2013	NUM
eurjchem-990	8	14	received	receive	VERB
eurjchem-990	8	15	in	in	ADP
eurjchem-990	8	16	revised	revise	VERB
eurjchem-990	8	17	form	form	NOUN
eurjchem-990	8	18	:	:	PUNCT
eurjchem-990	8	19	02	02	NUM
eurjchem-990	8	20	january	january	PROPN
eurjchem-990	8	21	2014	2014	NUM
eurjchem-990	8	22	accepted	accept	VERB
eurjchem-990	8	23	:	:	PUNCT
eurjchem-990	9	1	03	03	NUM
eurjchem-990	9	2	january	january	PROPN
eurjchem-990	9	3	2014	2014	NUM
eurjchem-990	9	4	online	online	NOUN
eurjchem-990	9	5	:	:	PUNCT
eurjchem-990	9	6	30	30	NUM
eurjchem-990	9	7	june	june	PROPN
eurjchem-990	9	8	2014	2014	NUM
eurjchem-990	9	9	keywords	keyword	NOUN
eurjchem-990	9	10	mixed‐ligand	mixed‐ligand	NOUN
eurjchem-990	9	11	bivalent	bivalent	NOUN
eurjchem-990	9	12	transition	transition	NOUN
eurjchem-990	9	13	metal	metal	NOUN
eurjchem-990	9	14	ion	ion	NOUN
eurjchem-990	9	15	complexes	complex	NOUN
eurjchem-990	9	16	with	with	ADP
eurjchem-990	9	17	n‐ethyl‐2‐picolinoyl	n‐ethyl‐2‐picolinoyl	PROPN
eurjchem-990	9	18	hydrazinecarbothioamide	hydrazinecarbothioamide	ADJ
eurjchem-990	9	19	(	(	PUNCT
eurjchem-990	9	20	ephc	ephc	NOUN
eurjchem-990	9	21	)	)	PUNCT
eurjchem-990	9	22	and	and	CCONJ
eurjchem-990	9	23	1,10‐phenanthroline	1,10‐phenanthroline	NUM
eurjchem-990	9	24	(	(	PUNCT
eurjchem-990	9	25	1,10‐phen	1,10‐phen	X
eurjchem-990	9	26	)	)	PUNCT
eurjchem-990	9	27	have	have	AUX
eurjchem-990	9	28	been	be	AUX
eurjchem-990	9	29	synthesized	synthesize	VERB
eurjchem-990	9	30	.	.	PUNCT
eurjchem-990	10	1	the	the	DET
eurjchem-990	10	2	complexes	complex	NOUN
eurjchem-990	10	3	namely	namely	ADV
eurjchem-990	10	4	[	[	X
eurjchem-990	10	5	cu(ephc)(1,10‐phen)(cl)h2o	cu(ephc)(1,10‐phen)(cl)h2o	X
eurjchem-990	10	6	]	]	X
eurjchem-990	10	7	(	(	PUNCT
eurjchem-990	10	8	1	1	NUM
eurjchem-990	10	9	)	)	PUNCT
eurjchem-990	10	10	,	,	PUNCT
eurjchem-990	10	11	[	[	X
eurjchem-990	10	12	ni(ephc)(1,10‐	ni(ephc)(1,10‐	PROPN
eurjchem-990	10	13	phen)(cl)h2o	phen)(cl)h2o	PROPN
eurjchem-990	10	14	]	]	PUNCT
eurjchem-990	10	15	(	(	PUNCT
eurjchem-990	10	16	2	2	NUM
eurjchem-990	10	17	)	)	PUNCT
eurjchem-990	10	18	,	,	PUNCT
eurjchem-990	10	19	[	[	X
eurjchem-990	10	20	mn(ephc)(1,10‐phen)(cl)h2o	mn(ephc)(1,10‐phen)(cl)h2o	X
eurjchem-990	10	21	]	]	X
eurjchem-990	10	22	(	(	PUNCT
eurjchem-990	10	23	3	3	NUM
eurjchem-990	10	24	)	)	PUNCT
eurjchem-990	10	25	and	and	CCONJ
eurjchem-990	10	26	[	[	X
eurjchem-990	10	27	co(ephc)(1,10‐phen)(cl)h2o	co(ephc)(1,10‐phen)(cl)h2o	X
eurjchem-990	10	28	]	]	X
eurjchem-990	10	29	(	(	PUNCT
eurjchem-990	10	30	4	4	X
eurjchem-990	10	31	)	)	PUNCT
eurjchem-990	10	32	were	be	AUX
eurjchem-990	10	33	characterized	characterize	VERB
eurjchem-990	10	34	by	by	ADP
eurjchem-990	10	35	elemental	elemental	ADJ
eurjchem-990	10	36	analysis	analysis	NOUN
eurjchem-990	10	37	,	,	PUNCT
eurjchem-990	10	38	spectral	spectral	ADJ
eurjchem-990	10	39	(	(	PUNCT
eurjchem-990	10	40	ir	ir	PROPN
eurjchem-990	10	41	,	,	PUNCT
eurjchem-990	10	42	1h	1h	NUM
eurjchem-990	10	43	nmr	nmr	NOUN
eurjchem-990	10	44	and	and	CCONJ
eurjchem-990	10	45	uv‐vis	uv‐vi	NOUN
eurjchem-990	10	46	)	)	PUNCT
eurjchem-990	10	47	and	and	CCONJ
eurjchem-990	10	48	magnetic	magnetic	ADJ
eurjchem-990	10	49	moment	moment	NOUN
eurjchem-990	10	50	measurements	measurement	NOUN
eurjchem-990	10	51	.	.	PUNCT
eurjchem-990	11	1	the	the	DET
eurjchem-990	11	2	magnetic	magnetic	ADJ
eurjchem-990	11	3	and	and	CCONJ
eurjchem-990	11	4	spectral	spectral	ADJ
eurjchem-990	11	5	data	datum	NOUN
eurjchem-990	11	6	indicates	indicate	VERB
eurjchem-990	11	7	octahedral	octahedral	ADJ
eurjchem-990	11	8	structure	structure	NOUN
eurjchem-990	11	9	for	for	ADP
eurjchem-990	11	10	all	all	DET
eurjchem-990	11	11	complexes	complex	NOUN
eurjchem-990	11	12	.	.	PUNCT
eurjchem-990	12	1	metal	metal	NOUN
eurjchem-990	12	2	complexes	complex	NOUN
eurjchem-990	12	3	have	have	AUX
eurjchem-990	12	4	been	be	AUX
eurjchem-990	12	5	modeled	model	VERB
eurjchem-990	12	6	using	use	VERB
eurjchem-990	12	7	parameterized	parameterized	ADJ
eurjchem-990	12	8	pm3	pm3	PROPN
eurjchem-990	12	9	semi‐empirical	semi‐empirical	ADJ
eurjchem-990	12	10	method	method	NOUN
eurjchem-990	12	11	.	.	PUNCT
eurjchem-990	13	1	the	the	DET
eurjchem-990	13	2	free	free	ADJ
eurjchem-990	13	3	ligand	ligand	NOUN
eurjchem-990	13	4	and	and	CCONJ
eurjchem-990	13	5	its	its	PRON
eurjchem-990	13	6	m(ii)‐chelates	m(ii)‐chelate	NOUN
eurjchem-990	13	7	have	have	AUX
eurjchem-990	13	8	been	be	AUX
eurjchem-990	13	9	screened	screen	VERB
eurjchem-990	13	10	for	for	ADP
eurjchem-990	13	11	their	their	PRON
eurjchem-990	13	12	antimicrobial	antimicrobial	ADJ
eurjchem-990	13	13	activities	activity	NOUN
eurjchem-990	13	14	.	.	PUNCT
eurjchem-990	14	1	the	the	DET
eurjchem-990	14	2	antibacterial	antibacterial	ADJ
eurjchem-990	14	3	screening	screening	NOUN
eurjchem-990	14	4	demonstrated	demonstrate	VERB
eurjchem-990	14	5	that	that	SCONJ
eurjchem-990	14	6	,	,	PUNCT
eurjchem-990	14	7	the	the	DET
eurjchem-990	14	8	cu(ii	cu(ii	PROPN
eurjchem-990	14	9	)	)	PUNCT
eurjchem-990	14	10	complex	complex	NOUN
eurjchem-990	14	11	have	have	VERB
eurjchem-990	14	12	the	the	DET
eurjchem-990	14	13	maximum	maximum	ADJ
eurjchem-990	14	14	and	and	CCONJ
eurjchem-990	14	15	broad	broad	ADJ
eurjchem-990	14	16	activities	activity	NOUN
eurjchem-990	14	17	among	among	ADP
eurjchem-990	14	18	the	the	DET
eurjchem-990	14	19	investigated	investigate	VERB
eurjchem-990	14	20	complexes	complex	NOUN
eurjchem-990	14	21	.	.	PUNCT
eurjchem-990	15	1	complex	complex	ADJ
eurjchem-990	15	2	antifungal	antifungal	ADJ
eurjchem-990	15	3	picolinic	picolinic	ADJ
eurjchem-990	15	4	acid	acid	NOUN
eurjchem-990	15	5	antibacterial	antibacterial	ADJ
eurjchem-990	15	6	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-990	15	7	molecular	molecular	ADJ
eurjchem-990	15	8	modeling	model	VERB
eurjchem-990	15	9	1	1	NUM
eurjchem-990	15	10	.	.	PUNCT
eurjchem-990	16	1	introduction	introduction	NOUN
eurjchem-990	16	2	thiosemicarbazones	thiosemicarbazone	NOUN
eurjchem-990	16	3	have	have	AUX
eurjchem-990	16	4	been	be	AUX
eurjchem-990	16	5	extensively	extensively	ADV
eurjchem-990	16	6	studied	study	VERB
eurjchem-990	16	7	because	because	SCONJ
eurjchem-990	16	8	they	they	PRON
eurjchem-990	16	9	have	have	VERB
eurjchem-990	16	10	a	a	DET
eurjchem-990	16	11	wide	wide	ADJ
eurjchem-990	16	12	range	range	NOUN
eurjchem-990	16	13	of	of	ADP
eurjchem-990	16	14	actual	actual	ADJ
eurjchem-990	16	15	or	or	CCONJ
eurjchem-990	16	16	potential	potential	ADJ
eurjchem-990	16	17	medical	medical	ADJ
eurjchem-990	16	18	applications	application	NOUN
eurjchem-990	17	1	[	[	X
eurjchem-990	17	2	1‐3	1‐3	X
eurjchem-990	17	3	]	]	PUNCT
eurjchem-990	18	1	which	which	PRON
eurjchem-990	18	2	include	include	VERB
eurjchem-990	18	3	notably	notably	ADV
eurjchem-990	18	4	antiparasital	antiparasital	ADJ
eurjchem-990	18	5	[	[	X
eurjchem-990	18	6	3	3	NUM
eurjchem-990	18	7	]	]	PUNCT
eurjchem-990	18	8	,	,	PUNCT
eurjchem-990	18	9	antibacterial	antibacterial	ADJ
eurjchem-990	18	10	[	[	X
eurjchem-990	18	11	4	4	NUM
eurjchem-990	18	12	]	]	X
eurjchem-990	18	13	antitumor	antitumor	NOUN
eurjchem-990	18	14	activities	activity	NOUN
eurjchem-990	18	15	[	[	X
eurjchem-990	18	16	5	5	NUM
eurjchem-990	18	17	]	]	PUNCT
eurjchem-990	18	18	,	,	PUNCT
eurjchem-990	18	19	antiviral	antiviral	NOUN
eurjchem-990	18	20	[	[	X
eurjchem-990	18	21	6	6	NUM
eurjchem-990	18	22	]	]	PUNCT
eurjchem-990	18	23	,	,	PUNCT
eurjchem-990	18	24	fungicidal	fungicidal	NOUN
eurjchem-990	18	25	[	[	X
eurjchem-990	18	26	7	7	NUM
eurjchem-990	18	27	]	]	PUNCT
eurjchem-990	18	28	and	and	CCONJ
eurjchem-990	18	29	antineoplastic	antineoplastic	ADJ
eurjchem-990	18	30	[	[	X
eurjchem-990	18	31	8	8	NUM
eurjchem-990	18	32	]	]	PUNCT
eurjchem-990	18	33	.	.	PUNCT
eurjchem-990	19	1	thiosemicarbazones	thiosemicarbazone	NOUN
eurjchem-990	19	2	derived	derive	VERB
eurjchem-990	19	3	from	from	ADP
eurjchem-990	19	4	2‐	2‐	NUM
eurjchem-990	19	5	picolinic	picolinic	ADJ
eurjchem-990	19	6	acid	acid	NOUN
eurjchem-990	19	7	hydrazide	hydrazide	NOUN
eurjchem-990	19	8	and	and	CCONJ
eurjchem-990	19	9	its	its	PRON
eurjchem-990	19	10	derivatives	derivative	NOUN
eurjchem-990	19	11	are	be	AUX
eurjchem-990	19	12	classes	class	NOUN
eurjchem-990	19	13	of	of	ADP
eurjchem-990	19	14	versatile	versatile	ADJ
eurjchem-990	19	15	tridentate	tridentate	ADJ
eurjchem-990	19	16	nns	nns	NOUN
eurjchem-990	19	17	donors	donor	NOUN
eurjchem-990	19	18	capable	capable	ADJ
eurjchem-990	19	19	of	of	ADP
eurjchem-990	19	20	stabilizing	stabilize	VERB
eurjchem-990	19	21	both	both	CCONJ
eurjchem-990	19	22	higher	high	ADJ
eurjchem-990	19	23	and	and	CCONJ
eurjchem-990	19	24	lower	low	ADJ
eurjchem-990	19	25	oxidation	oxidation	NOUN
eurjchem-990	19	26	states	state	NOUN
eurjchem-990	19	27	of	of	ADP
eurjchem-990	19	28	transition	transition	NOUN
eurjchem-990	19	29	metal	metal	NOUN
eurjchem-990	19	30	ions	ion	NOUN
eurjchem-990	19	31	[	[	X
eurjchem-990	19	32	9,10	9,10	NUM
eurjchem-990	19	33	]	]	X
eurjchem-990	19	34	.	.	PUNCT
eurjchem-990	20	1	in	in	ADP
eurjchem-990	20	2	general	general	ADJ
eurjchem-990	20	3	,	,	PUNCT
eurjchem-990	20	4	thiosemicarbazones	thiosemicarbazone	NOUN
eurjchem-990	20	5	are	be	AUX
eurjchem-990	20	6	obtained	obtain	VERB
eurjchem-990	20	7	by	by	ADP
eurjchem-990	20	8	condensation	condensation	NOUN
eurjchem-990	20	9	of	of	ADP
eurjchem-990	20	10	the	the	DET
eurjchem-990	20	11	corresponding	correspond	VERB
eurjchem-990	20	12	thiosemicarbazide	thiosemicarbazide	NOUN
eurjchem-990	20	13	with	with	ADP
eurjchem-990	20	14	aldehydes	aldehyde	NOUN
eurjchem-990	20	15	or	or	CCONJ
eurjchem-990	20	16	ketones	ketone	NOUN
eurjchem-990	20	17	.	.	PUNCT
eurjchem-990	21	1	thiosemicarbazones	thiosemicarbazone	NOUN
eurjchem-990	21	2	(	(	PUNCT
eurjchem-990	21	3	tscns	tscns	NOUN
eurjchem-990	21	4	)	)	PUNCT
eurjchem-990	21	5	exist	exist	VERB
eurjchem-990	21	6	in	in	ADP
eurjchem-990	21	7	the	the	DET
eurjchem-990	21	8	tautomeric	tautomeric	ADJ
eurjchem-990	21	9	thione	thione	NOUN
eurjchem-990	21	10	(	(	PUNCT
eurjchem-990	21	11	a	a	NOUN
eurjchem-990	21	12	)	)	PUNCT
eurjchem-990	21	13	and	and	CCONJ
eurjchem-990	21	14	thiol	thiol	PROPN
eurjchem-990	21	15	(	(	PUNCT
eurjchem-990	21	16	b	b	X
eurjchem-990	21	17	)	)	PUNCT
eurjchem-990	21	18	forms	form	NOUN
eurjchem-990	21	19	(	(	PUNCT
eurjchem-990	21	20	scheme	scheme	NOUN
eurjchem-990	21	21	1	1	NUM
eurjchem-990	21	22	)	)	PUNCT
eurjchem-990	21	23	.	.	PUNCT
eurjchem-990	22	1	(	(	PUNCT
eurjchem-990	22	2	a	a	X
eurjchem-990	22	3	)	)	PUNCT
eurjchem-990	22	4	(	(	PUNCT
eurjchem-990	22	5	b	b	NOUN
eurjchem-990	22	6	)	)	PUNCT
eurjchem-990	22	7	scheme	scheme	NOUN
eurjchem-990	22	8	1	1	NUM
eurjchem-990	22	9	the	the	DET
eurjchem-990	22	10	chemistry	chemistry	NOUN
eurjchem-990	22	11	of	of	ADP
eurjchem-990	22	12	transition	transition	NOUN
eurjchem-990	22	13	metal	metal	NOUN
eurjchem-990	22	14	complexes	complex	NOUN
eurjchem-990	22	15	of	of	ADP
eurjchem-990	22	16	heterocyclic	heterocyclic	ADJ
eurjchem-990	22	17	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-990	22	18	ligands	ligand	NOUN
eurjchem-990	22	19	have	have	AUX
eurjchem-990	22	20	been	be	AUX
eurjchem-990	22	21	receiving	receive	VERB
eurjchem-990	22	22	considerable	considerable	ADJ
eurjchem-990	22	23	attention	attention	NOUN
eurjchem-990	22	24	primarily	primarily	ADV
eurjchem-990	22	25	because	because	SCONJ
eurjchem-990	22	26	of	of	ADP
eurjchem-990	22	27	their	their	PRON
eurjchem-990	22	28	bioinorganic	bioinorganic	NOUN
eurjchem-990	22	29	relevance	relevance	NOUN
eurjchem-990	22	30	[	[	X
eurjchem-990	22	31	11,12	11,12	NUM
eurjchem-990	22	32	]	]	PUNCT
eurjchem-990	22	33	.	.	PUNCT
eurjchem-990	23	1	there	there	PRON
eurjchem-990	23	2	have	have	AUX
eurjchem-990	23	3	been	be	AUX
eurjchem-990	23	4	attempts	attempt	NOUN
eurjchem-990	23	5	to	to	PART
eurjchem-990	23	6	determine	determine	VERB
eurjchem-990	23	7	structural	structural	ADJ
eurjchem-990	23	8	correlation	correlation	NOUN
eurjchem-990	23	9	’s	’s	NOUN
eurjchem-990	23	10	between	between	ADP
eurjchem-990	23	11	transition	transition	NOUN
eurjchem-990	23	12	metal	metal	NOUN
eurjchem-990	23	13	ion	ion	NOUN
eurjchem-990	23	14	complexes	complex	NOUN
eurjchem-990	23	15	of	of	ADP
eurjchem-990	23	16	heterocyclic	heterocyclic	ADJ
eurjchem-990	23	17	thiosemicarbazones	thiosemicarbazone	NOUN
eurjchem-990	23	18	and	and	CCONJ
eurjchem-990	23	19	their	their	PRON
eurjchem-990	23	20	wide	wide	ADJ
eurjchem-990	23	21	spectrum	spectrum	NOUN
eurjchem-990	23	22	of	of	ADP
eurjchem-990	23	23	biological	biological	ADJ
eurjchem-990	23	24	applications	application	NOUN
eurjchem-990	23	25	[	[	X
eurjchem-990	23	26	13	13	NUM
eurjchem-990	23	27	]	]	PUNCT
eurjchem-990	23	28	.	.	PUNCT
eurjchem-990	24	1	in	in	ADP
eurjchem-990	24	2	several	several	ADJ
eurjchem-990	24	3	cases	case	NOUN
eurjchem-990	24	4	,	,	PUNCT
eurjchem-990	24	5	the	the	DET
eurjchem-990	24	6	pharma‐	pharma‐	NOUN
eurjchem-990	24	7	cological	cological	ADJ
eurjchem-990	24	8	action	action	NOUN
eurjchem-990	24	9	of	of	ADP
eurjchem-990	24	10	the	the	DET
eurjchem-990	24	11	thiosemicarbazons	thiosemicarbazon	NOUN
eurjchem-990	24	12	is	be	AUX
eurjchem-990	24	13	enhanced	enhance	VERB
eurjchem-990	24	14	due	due	ADP
eurjchem-990	24	15	to	to	ADP
eurjchem-990	24	16	their	their	PRON
eurjchem-990	24	17	ability	ability	NOUN
eurjchem-990	24	18	to	to	PART
eurjchem-990	24	19	chelate	chelate	VERB
eurjchem-990	24	20	transition	transition	NOUN
eurjchem-990	24	21	metal	metal	NOUN
eurjchem-990	24	22	ions	ion	NOUN
eurjchem-990	24	23	[	[	X
eurjchem-990	24	24	14,15	14,15	NUM
eurjchem-990	24	25	]	]	PUNCT
eurjchem-990	24	26	.	.	PUNCT
eurjchem-990	25	1	it	it	PRON
eurjchem-990	25	2	is	be	AUX
eurjchem-990	25	3	well	well	ADV
eurjchem-990	25	4	authenticated	authenticate	VERB
eurjchem-990	25	5	that	that	SCONJ
eurjchem-990	25	6	a	a	DET
eurjchem-990	25	7	nns	nns	NOUN
eurjchem-990	25	8	tridentate	tridentate	NOUN
eurjchem-990	25	9	system	system	NOUN
eurjchem-990	25	10	is	be	AUX
eurjchem-990	25	11	present	present	ADJ
eurjchem-990	25	12	in	in	ADP
eurjchem-990	25	13	most	most	ADJ
eurjchem-990	25	14	of	of	ADP
eurjchem-990	25	15	the	the	DET
eurjchem-990	25	16	thiosemicarbazones	thiosemicarbazone	NOUN
eurjchem-990	25	17	having	have	VERB
eurjchem-990	25	18	carcinostatic	carcinostatic	ADJ
eurjchem-990	25	19	potency	potency	NOUN
eurjchem-990	25	20	and	and	CCONJ
eurjchem-990	25	21	possessing	possess	VERB
eurjchem-990	25	22	substantial	substantial	ADJ
eurjchem-990	25	23	in	in	ADP
eurjchem-990	25	24	vitro	vitro	X
eurjchem-990	25	25	activity	activity	NOUN
eurjchem-990	25	26	against	against	ADP
eurjchem-990	25	27	various	various	ADJ
eurjchem-990	25	28	human	human	ADJ
eurjchem-990	25	29	tumor	tumor	NOUN
eurjchem-990	25	30	lines	line	NOUN
eurjchem-990	25	31	[	[	X
eurjchem-990	25	32	16,17	16,17	NUM
eurjchem-990	25	33	]	]	PUNCT
eurjchem-990	25	34	.	.	PUNCT
eurjchem-990	26	1	in	in	ADP
eurjchem-990	26	2	the	the	DET
eurjchem-990	26	3	past	past	NOUN
eurjchem-990	26	4	,	,	PUNCT
eurjchem-990	26	5	it	it	PRON
eurjchem-990	26	6	has	have	AUX
eurjchem-990	26	7	been	be	AUX
eurjchem-990	26	8	shown	show	VERB
eurjchem-990	26	9	that	that	SCONJ
eurjchem-990	26	10	the	the	DET
eurjchem-990	26	11	metal	metal	NOUN
eurjchem-990	26	12	complexes	complex	NOUN
eurjchem-990	26	13	are	be	AUX
eurjchem-990	26	14	more	more	ADV
eurjchem-990	26	15	effective	effective	ADJ
eurjchem-990	26	16	than	than	ADP
eurjchem-990	26	17	their	their	PRON
eurjchem-990	26	18	parent	parent	NOUN
eurjchem-990	26	19	ligands	ligand	NOUN
eurjchem-990	26	20	in	in	ADP
eurjchem-990	26	21	anticancer	anticancer	NOUN
eurjchem-990	26	22	activity	activity	NOUN
eurjchem-990	27	1	[	[	X
eurjchem-990	27	2	18,19	18,19	NUM
eurjchem-990	27	3	]	]	PUNCT
eurjchem-990	27	4	.	.	PUNCT
eurjchem-990	28	1	the	the	DET
eurjchem-990	28	2	inhibitory	inhibitory	ADJ
eurjchem-990	28	3	action	action	NOUN
eurjchem-990	28	4	of	of	ADP
eurjchem-990	28	5	these	these	DET
eurjchem-990	28	6	compounds	compound	NOUN
eurjchem-990	28	7	is	be	AUX
eurjchem-990	28	8	attributed	attribute	VERB
eurjchem-990	28	9	to	to	ADP
eurjchem-990	28	10	their	their	PRON
eurjchem-990	28	11	chelating	chelating	NOUN
eurjchem-990	28	12	properties	property	NOUN
eurjchem-990	28	13	to	to	ADP
eurjchem-990	28	14	different	different	ADJ
eurjchem-990	28	15	metal	metal	NOUN
eurjchem-990	28	16	ions	ion	NOUN
eurjchem-990	28	17	that	that	PRON
eurjchem-990	28	18	can	can	AUX
eurjchem-990	28	19	be	be	AUX
eurjchem-990	28	20	found	find	VERB
eurjchem-990	28	21	in	in	ADP
eurjchem-990	28	22	biological	biological	ADJ
eurjchem-990	28	23	systems	system	NOUN
eurjchem-990	28	24	[	[	X
eurjchem-990	28	25	20	20	NUM
eurjchem-990	28	26	]	]	PUNCT
eurjchem-990	28	27	.	.	PUNCT
eurjchem-990	29	1	additionally	additionally	ADV
eurjchem-990	29	2	,	,	PUNCT
eurjchem-990	29	3	one	one	NUM
eurjchem-990	29	4	of	of	ADP
eurjchem-990	29	5	the	the	DET
eurjchem-990	29	6	many	many	ADJ
eurjchem-990	29	7	reasons	reason	NOUN
eurjchem-990	29	8	is	be	AUX
eurjchem-990	29	9	that	that	SCONJ
eurjchem-990	29	10	the	the	DET
eurjchem-990	29	11	binding	bind	VERB
eurjchem-990	29	12	affinity	affinity	NOUN
eurjchem-990	29	13	of	of	ADP
eurjchem-990	29	14	metals	metal	NOUN
eurjchem-990	29	15	to	to	ADP
eurjchem-990	29	16	proteins	protein	NOUN
eurjchem-990	29	17	or	or	CCONJ
eurjchem-990	29	18	enzymes	enzyme	NOUN
eurjchem-990	29	19	will	will	AUX
eurjchem-990	29	20	change	change	VERB
eurjchem-990	29	21	the	the	DET
eurjchem-990	29	22	interaction	interaction	NOUN
eurjchem-990	29	23	process	process	NOUN
eurjchem-990	29	24	of	of	ADP
eurjchem-990	29	25	them	they	PRON
eurjchem-990	29	26	with	with	ADP
eurjchem-990	29	27	dna	dna	PROPN
eurjchem-990	29	28	,	,	PUNCT
eurjchem-990	29	29	thereby	thereby	ADV
eurjchem-990	29	30	affecting	affect	VERB
eurjchem-990	29	31	the	the	DET
eurjchem-990	29	32	dna	dna	PROPN
eurjchem-990	29	33	replication	replication	NOUN
eurjchem-990	29	34	and	and	CCONJ
eurjchem-990	29	35	cell	cell	NOUN
eurjchem-990	29	36	proliferation	proliferation	NOUN
eurjchem-990	29	37	[	[	X
eurjchem-990	29	38	19	19	NUM
eurjchem-990	29	39	]	]	PUNCT
eurjchem-990	29	40	.	.	PUNCT
eurjchem-990	30	1	mohamed	mohamed	PROPN
eurjchem-990	30	2	et	et	PROPN
eurjchem-990	30	3	al	al	PROPN
eurjchem-990	30	4	.	.	PUNCT
eurjchem-990	30	5	/	/	SYM
eurjchem-990	30	6	european	european	PROPN
eurjchem-990	30	7	journal	journal	PROPN
eurjchem-990	30	8	of	of	ADP
eurjchem-990	30	9	chemistry	chemistry	NOUN
eurjchem-990	30	10	5	5	NUM
eurjchem-990	30	11	(	(	PUNCT
eurjchem-990	30	12	2	2	NUM
eurjchem-990	30	13	)	)	PUNCT
eurjchem-990	30	14	(	(	PUNCT
eurjchem-990	30	15	2014	2014	NUM
eurjchem-990	30	16	)	)	PUNCT
eurjchem-990	30	17	252‐259	252‐259	NOUN
eurjchem-990	30	18	253	253	NUM
eurjchem-990	30	19	scheme	scheme	NOUN
eurjchem-990	30	20	2	2	NUM
eurjchem-990	30	21	scheme	scheme	NOUN
eurjchem-990	30	22	3	3	NUM
eurjchem-990	30	23	earlier	early	ADJ
eurjchem-990	30	24	studies	study	NOUN
eurjchem-990	30	25	on	on	ADP
eurjchem-990	30	26	the	the	DET
eurjchem-990	30	27	biological	biological	ADJ
eurjchem-990	30	28	properties	property	NOUN
eurjchem-990	30	29	of	of	ADP
eurjchem-990	30	30	thiosemicarbazones	thiosemicarbazone	NOUN
eurjchem-990	30	31	and	and	CCONJ
eurjchem-990	30	32	their	their	PRON
eurjchem-990	30	33	metal	metal	NOUN
eurjchem-990	30	34	complexes	complex	NOUN
eurjchem-990	30	35	have	have	AUX
eurjchem-990	30	36	concluded	conclude	VERB
eurjchem-990	30	37	that	that	SCONJ
eurjchem-990	30	38	the	the	DET
eurjchem-990	30	39	biologically	biologically	ADV
eurjchem-990	30	40	active	active	ADJ
eurjchem-990	30	41	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-990	30	42	molecules	molecule	NOUN
eurjchem-990	30	43	are	be	AUX
eurjchem-990	30	44	planar	planar	ADJ
eurjchem-990	30	45	and	and	CCONJ
eurjchem-990	30	46	contain	contain	VERB
eurjchem-990	30	47	a	a	DET
eurjchem-990	30	48	pyridine	pyridine	NOUN
eurjchem-990	30	49	ring	ring	NOUN
eurjchem-990	30	50	or	or	CCONJ
eurjchem-990	30	51	derivatives	derivative	NOUN
eurjchem-990	30	52	giving	give	VERB
eurjchem-990	30	53	rise	rise	NOUN
eurjchem-990	30	54	to	to	ADP
eurjchem-990	30	55	nns	nn	NOUN
eurjchem-990	30	56	tridentate	tridentate	NOUN
eurjchem-990	30	57	system	system	NOUN
eurjchem-990	31	1	[	[	X
eurjchem-990	31	2	21,22	21,22	X
eurjchem-990	31	3	]	]	X
eurjchem-990	31	4	.	.	PUNCT
eurjchem-990	32	1	1,10‐phenanthroline	1,10‐phenanthroline	NUM
eurjchem-990	32	2	is	be	AUX
eurjchem-990	32	3	the	the	DET
eurjchem-990	32	4	parent	parent	NOUN
eurjchem-990	32	5	of	of	ADP
eurjchem-990	32	6	an	an	DET
eurjchem-990	32	7	important	important	ADJ
eurjchem-990	32	8	class	class	NOUN
eurjchem-990	32	9	of	of	ADP
eurjchem-990	32	10	chelating	chelating	NOUN
eurjchem-990	32	11	agents	agent	NOUN
eurjchem-990	32	12	.	.	PUNCT
eurjchem-990	33	1	the	the	DET
eurjchem-990	33	2	choice	choice	NOUN
eurjchem-990	33	3	of	of	ADP
eurjchem-990	33	4	phenanthroline	phenanthroline	NOUN
eurjchem-990	33	5	is	be	AUX
eurjchem-990	33	6	mainly	mainly	ADV
eurjchem-990	33	7	due	due	ADP
eurjchem-990	33	8	to	to	ADP
eurjchem-990	33	9	two	two	NUM
eurjchem-990	33	10	factors	factor	NOUN
eurjchem-990	33	11	.	.	PUNCT
eurjchem-990	34	1	this	this	DET
eurjchem-990	34	2	hetero‐	hetero‐	VERB
eurjchem-990	34	3	aromatic	aromatic	ADJ
eurjchem-990	34	4	moiety	moiety	NOUN
eurjchem-990	34	5	can	can	AUX
eurjchem-990	34	6	provide	provide	VERB
eurjchem-990	34	7	a	a	DET
eurjchem-990	34	8	further	further	ADJ
eurjchem-990	34	9	binding	bind	VERB
eurjchem-990	34	10	site	site	NOUN
eurjchem-990	34	11	for	for	ADP
eurjchem-990	34	12	metal	metal	NOUN
eurjchem-990	34	13	cations	cation	NOUN
eurjchem-990	34	14	.	.	PUNCT
eurjchem-990	35	1	it	it	PRON
eurjchem-990	35	2	is	be	AUX
eurjchem-990	35	3	rigid	rigid	ADJ
eurjchem-990	35	4	,	,	PUNCT
eurjchem-990	35	5	and	and	CCONJ
eurjchem-990	35	6	provides	provide	VERB
eurjchem-990	35	7	two	two	NUM
eurjchem-990	35	8	aromatic	aromatic	ADJ
eurjchem-990	35	9	nitrogens	nitrogen	NOUN
eurjchem-990	35	10	whose	whose	DET
eurjchem-990	35	11	unshared	unshared	ADJ
eurjchem-990	35	12	electron	electron	NOUN
eurjchem-990	35	13	pairs	pair	NOUN
eurjchem-990	35	14	can	can	AUX
eurjchem-990	35	15	act	act	VERB
eurjchem-990	35	16	co‐operatively	co‐operatively	ADV
eurjchem-990	35	17	in	in	ADP
eurjchem-990	35	18	binding	binding	ADJ
eurjchem-990	35	19	cations	cation	NOUN
eurjchem-990	35	20	[	[	X
eurjchem-990	35	21	23	23	NUM
eurjchem-990	35	22	]	]	PUNCT
eurjchem-990	35	23	.	.	PUNCT
eurjchem-990	36	1	moreover	moreover	ADV
eurjchem-990	36	2	,	,	PUNCT
eurjchem-990	36	3	1,10‐phenanthroline	1,10‐phenanthroline	NUM
eurjchem-990	36	4	,	,	PUNCT
eurjchem-990	36	5	the	the	DET
eurjchem-990	36	6	ligand	ligand	ADJ
eurjchem-990	36	7	moiety	moiety	NOUN
eurjchem-990	36	8	of	of	ADP
eurjchem-990	36	9	the	the	DET
eurjchem-990	36	10	ternary	ternary	ADJ
eurjchem-990	36	11	complexes	complex	NOUN
eurjchem-990	36	12	presented	present	VERB
eurjchem-990	36	13	in	in	ADP
eurjchem-990	36	14	this	this	DET
eurjchem-990	36	15	work	work	NOUN
eurjchem-990	36	16	is	be	AUX
eurjchem-990	36	17	of	of	ADP
eurjchem-990	36	18	considerable	considerable	ADJ
eurjchem-990	36	19	interest	interest	NOUN
eurjchem-990	36	20	also	also	ADV
eurjchem-990	36	21	according	accord	VERB
eurjchem-990	36	22	to	to	ADP
eurjchem-990	36	23	the	the	DET
eurjchem-990	36	24	biological	biological	ADJ
eurjchem-990	36	25	or	or	CCONJ
eurjchem-990	36	26	pharmacological	pharmacological	ADJ
eurjchem-990	36	27	properties	property	NOUN
eurjchem-990	36	28	(	(	PUNCT
eurjchem-990	36	29	antifungal	antifungal	ADJ
eurjchem-990	36	30	,	,	PUNCT
eurjchem-990	36	31	antimycoplasma	antimycoplasma	NOUN
eurjchem-990	36	32	and	and	CCONJ
eurjchem-990	36	33	antiviral	antiviral	ADJ
eurjchem-990	36	34	)	)	PUNCT
eurjchem-990	36	35	of	of	ADP
eurjchem-990	36	36	some	some	PRON
eurjchem-990	36	37	of	of	ADP
eurjchem-990	36	38	its	its	PRON
eurjchem-990	36	39	metal	metal	NOUN
eurjchem-990	36	40	complexes	complex	NOUN
eurjchem-990	36	41	[	[	X
eurjchem-990	36	42	24	24	NUM
eurjchem-990	36	43	]	]	PUNCT
eurjchem-990	36	44	.	.	PUNCT
eurjchem-990	37	1	with	with	ADP
eurjchem-990	37	2	this	this	PRON
eurjchem-990	37	3	in	in	ADP
eurjchem-990	37	4	mind	mind	NOUN
eurjchem-990	37	5	,	,	PUNCT
eurjchem-990	37	6	it	it	PRON
eurjchem-990	37	7	seems	seem	VERB
eurjchem-990	37	8	therefore	therefore	ADV
eurjchem-990	37	9	of	of	ADP
eurjchem-990	37	10	considerable	considerable	ADJ
eurjchem-990	37	11	interest	interest	NOUN
eurjchem-990	37	12	to	to	PART
eurjchem-990	37	13	synthesize	synthesize	VERB
eurjchem-990	37	14	and	and	CCONJ
eurjchem-990	37	15	characterize	characterize	VERB
eurjchem-990	37	16	m(ii	m(ii	PROPN
eurjchem-990	37	17	)	)	PUNCT
eurjchem-990	37	18	complexes	complex	NOUN
eurjchem-990	37	19	with	with	ADP
eurjchem-990	37	20	the	the	DET
eurjchem-990	37	21	novel	novel	NOUN
eurjchem-990	37	22	n‐ethyl‐2‐picolinoylhydrazinecarbothioamide	n‐ethyl‐2‐picolinoylhydrazinecarbothioamide	ADP
eurjchem-990	37	23	(	(	PUNCT
eurjchem-990	37	24	ephc	ephc	NOUN
eurjchem-990	37	25	)	)	PUNCT
eurjchem-990	37	26	and	and	CCONJ
eurjchem-990	37	27	1,10‐phenanthroline	1,10‐phenanthroline	NUM
eurjchem-990	37	28	(	(	PUNCT
eurjchem-990	37	29	1,10‐phen	1,10‐phen	X
eurjchem-990	37	30	)	)	PUNCT
eurjchem-990	37	31	with	with	ADP
eurjchem-990	37	32	different	different	ADJ
eurjchem-990	37	33	bivalent	bivalent	ADJ
eurjchem-990	37	34	transition	transition	NOUN
eurjchem-990	37	35	metal	metal	NOUN
eurjchem-990	37	36	ions	ion	NOUN
eurjchem-990	37	37	co(ii	co(ii	PROPN
eurjchem-990	37	38	)	)	PUNCT
eurjchem-990	37	39	,	,	PUNCT
eurjchem-990	37	40	cu(ii	cu(ii	PROPN
eurjchem-990	37	41	)	)	PUNCT
eurjchem-990	37	42	,	,	PUNCT
eurjchem-990	37	43	mn(ii	mn(ii	PROPN
eurjchem-990	37	44	)	)	PUNCT
eurjchem-990	37	45	and	and	CCONJ
eurjchem-990	37	46	ni(ii	ni(ii	NOUN
eurjchem-990	37	47	)	)	PUNCT
eurjchem-990	37	48	.	.	PUNCT
eurjchem-990	38	1	additionally	additionally	ADV
eurjchem-990	38	2	,	,	PUNCT
eurjchem-990	38	3	our	our	PRON
eurjchem-990	38	4	objective	objective	NOUN
eurjchem-990	38	5	is	be	AUX
eurjchem-990	38	6	also	also	ADV
eurjchem-990	38	7	to	to	PART
eurjchem-990	38	8	study	study	VERB
eurjchem-990	38	9	the	the	DET
eurjchem-990	38	10	antibacterial	antibacterial	ADJ
eurjchem-990	38	11	,	,	PUNCT
eurjchem-990	38	12	antifungal	antifungal	ADJ
eurjchem-990	38	13	and	and	CCONJ
eurjchem-990	38	14	antitumor	antitumor	PROPN
eurjchem-990	38	15	activities	activity	NOUN
eurjchem-990	38	16	of	of	ADP
eurjchem-990	38	17	the	the	DET
eurjchem-990	38	18	synthesized	synthesize	VERB
eurjchem-990	38	19	compounds	compound	NOUN
eurjchem-990	38	20	.	.	PUNCT
eurjchem-990	39	1	2	2	X
eurjchem-990	39	2	.	.	X
eurjchem-990	39	3	experimental	experimental	ADJ
eurjchem-990	39	4	2.1	2.1	NUM
eurjchem-990	39	5	.	.	PUNCT
eurjchem-990	39	6	materials	material	NOUN
eurjchem-990	39	7	and	and	CCONJ
eurjchem-990	39	8	instrumentation	instrumentation	NOUN
eurjchem-990	39	9	all	all	PRON
eurjchem-990	39	10	starting	start	VERB
eurjchem-990	39	11	materials	material	NOUN
eurjchem-990	39	12	were	be	AUX
eurjchem-990	39	13	purchased	purchase	VERB
eurjchem-990	39	14	from	from	ADP
eurjchem-990	39	15	fluka	fluka	NOUN
eurjchem-990	39	16	,	,	PUNCT
eurjchem-990	39	17	riedel	riedel	NOUN
eurjchem-990	39	18	and	and	CCONJ
eurjchem-990	39	19	merck	merck	PROPN
eurjchem-990	39	20	and	and	CCONJ
eurjchem-990	39	21	used	use	VERB
eurjchem-990	39	22	as	as	SCONJ
eurjchem-990	39	23	received	receive	VERB
eurjchem-990	39	24	.	.	PUNCT
eurjchem-990	40	1	the	the	DET
eurjchem-990	40	2	analyses	analysis	NOUN
eurjchem-990	40	3	were	be	AUX
eurjchem-990	40	4	performed	perform	VERB
eurjchem-990	40	5	twice	twice	ADV
eurjchem-990	40	6	to	to	PART
eurjchem-990	40	7	check	check	VERB
eurjchem-990	40	8	the	the	DET
eurjchem-990	40	9	accuracy	accuracy	NOUN
eurjchem-990	40	10	of	of	ADP
eurjchem-990	40	11	the	the	DET
eurjchem-990	40	12	analyses	analysis	NOUN
eurjchem-990	40	13	data	datum	NOUN
eurjchem-990	40	14	.	.	PUNCT
eurjchem-990	41	1	infrared	infrared	PROPN
eurjchem-990	41	2	spectra	spectra	PROPN
eurjchem-990	41	3	were	be	AUX
eurjchem-990	41	4	recorded	record	VERB
eurjchem-990	41	5	on	on	ADP
eurjchem-990	41	6	ft‐ir	ft‐ir	NUM
eurjchem-990	41	7	shimadzu	shimadzu	ADJ
eurjchem-990	41	8	spectrophotometer	spectrophotometer	NOUN
eurjchem-990	41	9	(	(	PUNCT
eurjchem-990	41	10	8001‐pc	8001‐pc	NUM
eurjchem-990	41	11	)	)	PUNCT
eurjchem-990	41	12	using	use	VERB
eurjchem-990	41	13	kbr	kbr	PROPN
eurjchem-990	41	14	pellets	pellet	NOUN
eurjchem-990	41	15	.	.	PUNCT
eurjchem-990	42	1	the	the	DET
eurjchem-990	42	2	solid	solid	ADJ
eurjchem-990	42	3	reflectance	reflectance	NOUN
eurjchem-990	42	4	spectra	spectra	NOUN
eurjchem-990	42	5	were	be	AUX
eurjchem-990	42	6	measured	measure	VERB
eurjchem-990	42	7	on	on	ADP
eurjchem-990	42	8	a	a	DET
eurjchem-990	42	9	shimadzu	shimadzu	ADJ
eurjchem-990	42	10	3101	3101	NUM
eurjchem-990	42	11	pc	pc	NOUN
eurjchem-990	42	12	spectrophotometer	spectrophotometer	NOUN
eurjchem-990	42	13	.	.	PUNCT
eurjchem-990	43	1	the	the	DET
eurjchem-990	43	2	room	room	NOUN
eurjchem-990	43	3	temperature	temperature	NOUN
eurjchem-990	43	4	magnetic	magnetic	ADJ
eurjchem-990	43	5	susceptibility	susceptibility	NOUN
eurjchem-990	43	6	measurements	measurement	NOUN
eurjchem-990	43	7	for	for	ADP
eurjchem-990	43	8	the	the	DET
eurjchem-990	43	9	complexes	complex	NOUN
eurjchem-990	43	10	were	be	AUX
eurjchem-990	43	11	determined	determine	VERB
eurjchem-990	43	12	by	by	ADP
eurjchem-990	43	13	the	the	DET
eurjchem-990	43	14	gouy	gouy	PROPN
eurjchem-990	43	15	balance	balance	NOUN
eurjchem-990	43	16	using	use	VERB
eurjchem-990	43	17	hg[co(scn)4	hg[co(scn)4	NOUN
eurjchem-990	43	18	]	]	PUNCT
eurjchem-990	43	19	as	as	ADP
eurjchem-990	43	20	a	a	DET
eurjchem-990	43	21	calibrant	calibrant	NOUN
eurjchem-990	43	22	.	.	PUNCT
eurjchem-990	44	1	electron	electron	NOUN
eurjchem-990	44	2	paramagnetic	paramagnetic	ADJ
eurjchem-990	44	3	resonance	resonance	NOUN
eurjchem-990	44	4	(	(	PUNCT
eurjchem-990	44	5	epr	epr	PROPN
eurjchem-990	44	6	)	)	PUNCT
eurjchem-990	44	7	has	have	AUX
eurjchem-990	44	8	matured	mature	VERB
eurjchem-990	44	9	into	into	ADP
eurjchem-990	44	10	a	a	DET
eurjchem-990	44	11	powerful	powerful	ADJ
eurjchem-990	44	12	,	,	PUNCT
eurjchem-990	44	13	versatile	versatile	ADJ
eurjchem-990	44	14	,	,	PUNCT
eurjchem-990	44	15	non‐destructive	non‐destructive	ADJ
eurjchem-990	44	16	,	,	PUNCT
eurjchem-990	44	17	and	and	CCONJ
eurjchem-990	44	18	non‐intrusive	non‐intrusive	ADJ
eurjchem-990	44	19	analytical	analytical	ADJ
eurjchem-990	44	20	method	method	NOUN
eurjchem-990	44	21	.	.	PUNCT
eurjchem-990	45	1	epr	epr	PROPN
eurjchem-990	45	2	signals	signal	NOUN
eurjchem-990	45	3	were	be	AUX
eurjchem-990	45	4	recorded	record	VERB
eurjchem-990	45	5	at	at	ADP
eurjchem-990	45	6	room	room	NOUN
eurjchem-990	45	7	temperature	temperature	NOUN
eurjchem-990	45	8	by	by	ADP
eurjchem-990	45	9	using	use	VERB
eurjchem-990	45	10	a	a	DET
eurjchem-990	45	11	bruker	bruker	NOUN
eurjchem-990	45	12	emx	emx	NOUN
eurjchem-990	45	13	spectrometer	spectrometer	NOUN
eurjchem-990	45	14	(	(	PUNCT
eurjchem-990	45	15	x‐band	x‐band	NUM
eurjchem-990	45	16	)	)	PUNCT
eurjchem-990	45	17	product	product	NOUN
eurjchem-990	45	18	of	of	ADP
eurjchem-990	45	19	bruker	bruker	PROPN
eurjchem-990	45	20	,	,	PUNCT
eurjchem-990	45	21	germany	germany	PROPN
eurjchem-990	45	22	.	.	PUNCT
eurjchem-990	46	1	the	the	DET
eurjchem-990	46	2	operating	operating	NOUN
eurjchem-990	46	3	conditions	condition	NOUN
eurjchem-990	46	4	are	be	AUX
eurjchem-990	46	5	,	,	PUNCT
eurjchem-990	46	6	microwave	microwave	NOUN
eurjchem-990	46	7	power	power	NOUN
eurjchem-990	46	8	=	=	PUNCT
eurjchem-990	46	9	0.201	0.201	NUM
eurjchem-990	46	10	mw	mw	PROPN
eurjchem-990	46	11	,	,	PUNCT
eurjchem-990	46	12	modulation	modulation	NOUN
eurjchem-990	46	13	amplitude	amplitude	NOUN
eurjchem-990	46	14	=	=	SYM
eurjchem-990	46	15	4.00	4.00	NUM
eurjchem-990	46	16	gauss	gauss	NOUN
eurjchem-990	46	17	,	,	PUNCT
eurjchem-990	46	18	modulation	modulation	NOUN
eurjchem-990	46	19	frequency	frequency	NOUN
eurjchem-990	46	20	=	=	SYM
eurjchem-990	46	21	100	100	NUM
eurjchem-990	46	22	khz	khz	NOUN
eurjchem-990	46	23	,	,	PUNCT
eurjchem-990	46	24	sweep	sweep	VERB
eurjchem-990	46	25	width	width	NOUN
eurjchem-990	46	26	=	=	SYM
eurjchem-990	46	27	200	200	NUM
eurjchem-990	46	28	gauss	gauss	ADJ
eurjchem-990	46	29	,	,	PUNCT
eurjchem-990	46	30	microwave	microwave	NOUN
eurjchem-990	46	31	frequency	frequency	NOUN
eurjchem-990	46	32	=	=	SYM
eurjchem-990	46	33	9.775	9.775	NUM
eurjchem-990	46	34	ghz	ghz	NOUN
eurjchem-990	46	35	,	,	PUNCT
eurjchem-990	46	36	time	time	NOUN
eurjchem-990	46	37	constant	constant	ADJ
eurjchem-990	46	38	=	=	SYM
eurjchem-990	46	39	81.92	81.92	NUM
eurjchem-990	46	40	ms	ms	NOUN
eurjchem-990	46	41	and	and	CCONJ
eurjchem-990	46	42	sweep	sweep	VERB
eurjchem-990	46	43	time	time	NOUN
eurjchem-990	46	44	=	=	SYM
eurjchem-990	46	45	20.97	20.97	NUM
eurjchem-990	46	46	s.	s.	NOUN
eurjchem-990	46	47	the	the	DET
eurjchem-990	46	48	detection	detection	NOUN
eurjchem-990	46	49	limits	limit	NOUN
eurjchem-990	46	50	of	of	ADP
eurjchem-990	46	51	epr	epr	PROPN
eurjchem-990	46	52	technique	technique	NOUN
eurjchem-990	46	53	depends	depend	VERB
eurjchem-990	46	54	on	on	ADP
eurjchem-990	46	55	the	the	DET
eurjchem-990	46	56	type	type	NOUN
eurjchem-990	46	57	of	of	ADP
eurjchem-990	46	58	sample	sample	NOUN
eurjchem-990	46	59	,	,	PUNCT
eurjchem-990	46	60	sample	sample	NOUN
eurjchem-990	46	61	size	size	NOUN
eurjchem-990	46	62	,	,	PUNCT
eurjchem-990	46	63	detector	detector	NOUN
eurjchem-990	46	64	sensitivity	sensitivity	NOUN
eurjchem-990	46	65	,	,	PUNCT
eurjchem-990	46	66	frequency	frequency	NOUN
eurjchem-990	46	67	of	of	ADP
eurjchem-990	46	68	the	the	DET
eurjchem-990	46	69	incident	incident	NOUN
eurjchem-990	46	70	microwave	microwave	NOUN
eurjchem-990	46	71	radiation	radiation	NOUN
eurjchem-990	46	72	.	.	PUNCT
eurjchem-990	47	1	2.2	2.2	NUM
eurjchem-990	47	2	.	.	PUNCT
eurjchem-990	47	3	synthesis	synthesis	NOUN
eurjchem-990	47	4	2.2.1	2.2.1	NUM
eurjchem-990	47	5	.	.	PUNCT
eurjchem-990	48	1	synthesis	synthesis	NOUN
eurjchem-990	48	2	of	of	ADP
eurjchem-990	48	3	n‐ethyl‐2‐picolinoylhydrazine	n‐ethyl‐2‐picolinoylhydrazine	NOUN
eurjchem-990	48	4	carbothioamide	carbothioamide	NOUN
eurjchem-990	48	5	(	(	PUNCT
eurjchem-990	48	6	ephc	ephc	PROPN
eurjchem-990	48	7	)	)	PUNCT
eurjchem-990	48	8	n‐ethyl‐2‐picolinoylhydrazinecarbothioamide	n‐ethyl‐2‐picolinoylhydrazinecarbothioamide	ADV
eurjchem-990	48	9	(	(	PUNCT
eurjchem-990	48	10	ephc	ephc	NOUN
eurjchem-990	48	11	)	)	PUNCT
eurjchem-990	48	12	is	be	AUX
eurjchem-990	48	13	prepared	prepare	VERB
eurjchem-990	48	14	in	in	ADP
eurjchem-990	48	15	two	two	NUM
eurjchem-990	48	16	steps	step	NOUN
eurjchem-990	48	17	as	as	ADP
eurjchem-990	48	18	follow	follow	NOUN
eurjchem-990	48	19	:	:	PUNCT
eurjchem-990	48	20	step	step	NOUN
eurjchem-990	48	21	1	1	NUM
eurjchem-990	48	22	:	:	PUNCT
eurjchem-990	48	23	preparation	preparation	NOUN
eurjchem-990	48	24	of	of	ADP
eurjchem-990	48	25	2‐picolinic	2‐picolinic	ADJ
eurjchem-990	48	26	acid	acid	NOUN
eurjchem-990	48	27	hydrazide	hydrazide	NOUN
eurjchem-990	48	28	2‐picolinic	2‐picolinic	ADJ
eurjchem-990	48	29	acid	acid	NOUN
eurjchem-990	48	30	hydrazide	hydrazide	NOUN
eurjchem-990	48	31	was	be	AUX
eurjchem-990	48	32	prepared	prepare	VERB
eurjchem-990	48	33	by	by	ADP
eurjchem-990	48	34	refluxing	refluxing	NOUN
eurjchem-990	48	35	ethyl	ethyl	PROPN
eurjchem-990	48	36	picolinate	picolinate	NOUN
eurjchem-990	48	37	and	and	CCONJ
eurjchem-990	48	38	hydrazine	hydrazine	NOUN
eurjchem-990	48	39	hydrate	hydrate	NOUN
eurjchem-990	48	40	as	as	SCONJ
eurjchem-990	48	41	shown	show	VERB
eurjchem-990	48	42	in	in	ADP
eurjchem-990	48	43	scheme	scheme	NOUN
eurjchem-990	48	44	2	2	NUM
eurjchem-990	49	1	.	.	PUNCT
eurjchem-990	49	2	step	step	NOUN
eurjchem-990	49	3	2	2	NUM
eurjchem-990	49	4	:	:	PUNCT
eurjchem-990	49	5	preparation	preparation	NOUN
eurjchem-990	49	6	of	of	ADP
eurjchem-990	49	7	n‐ethyl‐2‐picolinoylhydrazine	n‐ethyl‐2‐picolinoylhydrazine	NOUN
eurjchem-990	49	8	carbothioamide	carbothioamide	NOUN
eurjchem-990	49	9	(	(	PUNCT
eurjchem-990	49	10	ephc	ephc	NOUN
eurjchem-990	49	11	)	)	PUNCT
eurjchem-990	49	12	ephc	ephc	NOUN
eurjchem-990	49	13	was	be	AUX
eurjchem-990	49	14	synthesized	synthesize	VERB
eurjchem-990	49	15	by	by	ADP
eurjchem-990	49	16	boiling	boil	VERB
eurjchem-990	49	17	1	1	NUM
eurjchem-990	49	18	mmol	mmol	NOUN
eurjchem-990	49	19	of	of	ADP
eurjchem-990	49	20	2‐picolinic	2‐picolinic	ADJ
eurjchem-990	49	21	acid	acid	NOUN
eurjchem-990	49	22	hydrazide	hydrazide	ADV
eurjchem-990	49	23	with	with	ADP
eurjchem-990	49	24	1	1	NUM
eurjchem-990	49	25	mmol	mmol	NOUN
eurjchem-990	49	26	ethyl	ethyl	PROPN
eurjchem-990	49	27	isothiocyanate	isothiocyanate	NOUN
eurjchem-990	49	28	in	in	ADP
eurjchem-990	49	29	ethanol	ethanol	NOUN
eurjchem-990	49	30	under	under	ADP
eurjchem-990	49	31	reflux	reflux	NOUN
eurjchem-990	49	32	for	for	ADP
eurjchem-990	49	33	3	3	NUM
eurjchem-990	49	34	h	h	NOUN
eurjchem-990	49	35	as	as	SCONJ
eurjchem-990	49	36	given	give	VERB
eurjchem-990	49	37	in	in	ADP
eurjchem-990	49	38	scheme	scheme	NOUN
eurjchem-990	49	39	3	3	NUM
eurjchem-990	49	40	.	.	PUNCT
eurjchem-990	49	41	2.2.2	2.2.2	NUM
eurjchem-990	49	42	.	.	PUNCT
eurjchem-990	50	1	synthesis	synthesis	NOUN
eurjchem-990	50	2	of	of	ADP
eurjchem-990	50	3	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-990	50	4	complexes	complexe	VERB
eurjchem-990	50	5	all	all	DET
eurjchem-990	50	6	complexes	complex	NOUN
eurjchem-990	50	7	were	be	AUX
eurjchem-990	50	8	prepared	prepare	VERB
eurjchem-990	50	9	by	by	ADP
eurjchem-990	50	10	refluxing	refluxe	VERB
eurjchem-990	50	11	an	an	DET
eurjchem-990	50	12	ethanolic	ethanolic	ADJ
eurjchem-990	50	13	solution	solution	NOUN
eurjchem-990	50	14	of	of	ADP
eurjchem-990	50	15	the	the	DET
eurjchem-990	50	16	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-990	50	17	(	(	PUNCT
eurjchem-990	50	18	ephc	ephc	PROPN
eurjchem-990	50	19	)	)	PUNCT
eurjchem-990	50	20	ligand	ligand	NOUN
eurjchem-990	50	21	(	(	PUNCT
eurjchem-990	50	22	1	1	NUM
eurjchem-990	50	23	mmol	mmol	NOUN
eurjchem-990	50	24	;	;	PUNCT
eurjchem-990	50	25	0.224	0.224	NUM
eurjchem-990	50	26	g	g	NOUN
eurjchem-990	50	27	)	)	PUNCT
eurjchem-990	50	28	and	and	CCONJ
eurjchem-990	50	29	1,10‐phenanthroline	1,10‐phenanthroline	NUM
eurjchem-990	50	30	heterocyclic	heterocyclic	ADJ
eurjchem-990	50	31	base	base	NOUN
eurjchem-990	50	32	(	(	PUNCT
eurjchem-990	50	33	1	1	NUM
eurjchem-990	50	34	mmol	mmol	NOUN
eurjchem-990	50	35	;	;	PUNCT
eurjchem-990	50	36	0.1982	0.1982	NUM
eurjchem-990	50	37	g	g	NOUN
eurjchem-990	50	38	)	)	PUNCT
eurjchem-990	50	39	with	with	ADP
eurjchem-990	50	40	an	an	DET
eurjchem-990	50	41	ethanolic	ethanolic	ADJ
eurjchem-990	50	42	solution	solution	NOUN
eurjchem-990	50	43	of	of	ADP
eurjchem-990	50	44	metal	metal	NOUN
eurjchem-990	50	45	salt	salt	NOUN
eurjchem-990	50	46	(	(	PUNCT
eurjchem-990	50	47	1	1	NUM
eurjchem-990	50	48	mmol	mmol	NOUN
eurjchem-990	50	49	,	,	PUNCT
eurjchem-990	50	50	cucl2.2h2o	cucl2.2h2o	NOUN
eurjchem-990	50	51	,	,	PUNCT
eurjchem-990	50	52	0.1702	0.1702	NUM
eurjchem-990	50	53	g	g	NOUN
eurjchem-990	50	54	;	;	PUNCT
eurjchem-990	50	55	cocl2.6h2o	cocl2.6h2o	NOUN
eurjchem-990	50	56	,	,	PUNCT
eurjchem-990	50	57	0.238	0.238	NUM
eurjchem-990	50	58	g	g	NOUN
eurjchem-990	50	59	;	;	PUNCT
eurjchem-990	50	60	nicl2.6h2o	nicl2.6h2o	NOUN
eurjchem-990	50	61	,	,	PUNCT
eurjchem-990	50	62	0.237	0.237	NUM
eurjchem-990	50	63	g	g	NOUN
eurjchem-990	50	64	;	;	PUNCT
eurjchem-990	50	65	mncl2.4h2o	mncl2.4h2o	NOUN
eurjchem-990	50	66	,	,	PUNCT
eurjchem-990	50	67	0.1979	0.1979	NUM
eurjchem-990	50	68	)	)	PUNCT
eurjchem-990	50	69	in	in	ADP
eurjchem-990	50	70	the	the	DET
eurjchem-990	50	71	molar	molar	ADJ
eurjchem-990	50	72	ratio	ratio	NOUN
eurjchem-990	50	73	1:1:1	1:1:1	PROPN
eurjchem-990	50	74	(	(	PUNCT
eurjchem-990	50	75	w	w	NOUN
eurjchem-990	50	76	:	:	PUNCT
eurjchem-990	50	77	w	w	ADJ
eurjchem-990	50	78	:	:	PUNCT
eurjchem-990	50	79	w	w	NOUN
eurjchem-990	50	80	)	)	PUNCT
eurjchem-990	50	81	.	.	PUNCT
eurjchem-990	51	1	the	the	DET
eurjchem-990	51	2	reaction	reaction	NOUN
eurjchem-990	51	3	mixtures	mixture	NOUN
eurjchem-990	51	4	were	be	AUX
eurjchem-990	51	5	refluxed	refluxe	VERB
eurjchem-990	51	6	on	on	ADP
eurjchem-990	51	7	a	a	DET
eurjchem-990	51	8	water	water	NOUN
eurjchem-990	51	9	bath	bath	NOUN
eurjchem-990	51	10	for	for	ADP
eurjchem-990	51	11	4	4	NUM
eurjchem-990	51	12	h	h	NOUN
eurjchem-990	51	13	and	and	CCONJ
eurjchem-990	51	14	allowed	allow	VERB
eurjchem-990	51	15	to	to	PART
eurjchem-990	51	16	cool	cool	VERB
eurjchem-990	51	17	to	to	PART
eurjchem-990	51	18	room	room	VERB
eurjchem-990	51	19	temperature	temperature	NOUN
eurjchem-990	51	20	overnight	overnight	ADV
eurjchem-990	51	21	.	.	PUNCT
eurjchem-990	52	1	the	the	DET
eurjchem-990	52	2	precipitated	precipitate	VERB
eurjchem-990	52	3	complexes	complex	NOUN
eurjchem-990	52	4	were	be	AUX
eurjchem-990	52	5	then	then	ADV
eurjchem-990	52	6	filtered	filter	VERB
eurjchem-990	52	7	off	off	ADP
eurjchem-990	52	8	,	,	PUNCT
eurjchem-990	52	9	washed	wash	VERB
eurjchem-990	52	10	with	with	ADP
eurjchem-990	52	11	petroleum	petroleum	NOUN
eurjchem-990	52	12	ether	ether	NOUN
eurjchem-990	52	13	and	and	CCONJ
eurjchem-990	52	14	dried	dry	VERB
eurjchem-990	52	15	overnight	overnight	ADV
eurjchem-990	52	16	in	in	ADP
eurjchem-990	52	17	a	a	DET
eurjchem-990	52	18	vacuum	vacuum	NOUN
eurjchem-990	52	19	desiccator	desiccator	NOUN
eurjchem-990	52	20	.	.	PUNCT
eurjchem-990	53	1	2.3	2.3	NUM
eurjchem-990	53	2	.	.	PUNCT
eurjchem-990	54	1	molecular	molecular	ADJ
eurjchem-990	54	2	modeling	model	VERB
eurjchem-990	54	3	an	an	DET
eurjchem-990	54	4	attempt	attempt	NOUN
eurjchem-990	54	5	to	to	PART
eurjchem-990	54	6	gain	gain	VERB
eurjchem-990	54	7	a	a	DET
eurjchem-990	54	8	better	well	ADJ
eurjchem-990	54	9	insight	insight	NOUN
eurjchem-990	54	10	on	on	ADP
eurjchem-990	54	11	the	the	DET
eurjchem-990	54	12	molecular	molecular	ADJ
eurjchem-990	54	13	structure	structure	NOUN
eurjchem-990	54	14	of	of	ADP
eurjchem-990	54	15	these	these	DET
eurjchem-990	54	16	synthesized	synthesize	VERB
eurjchem-990	54	17	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-990	54	18	compounds	compound	NOUN
eurjchem-990	54	19	and	and	CCONJ
eurjchem-990	54	20	their	their	PRON
eurjchem-990	54	21	m(ii)‐complexes	m(ii)‐complexe	NOUN
eurjchem-990	54	22	,	,	PUNCT
eurjchem-990	54	23	geometric	geometric	ADJ
eurjchem-990	54	24	optimization	optimization	NOUN
eurjchem-990	54	25	and	and	CCONJ
eurjchem-990	54	26	conformation	conformation	NOUN
eurjchem-990	54	27	analysis	analysis	NOUN
eurjchem-990	54	28	has	have	AUX
eurjchem-990	54	29	performed	perform	VERB
eurjchem-990	54	30	using	use	VERB
eurjchem-990	54	31	semiempirical	semiempirical	ADJ
eurjchem-990	54	32	parameterized	parameterized	ADJ
eurjchem-990	54	33	pm3	pm3	PROPN
eurjchem-990	54	34	method	method	NOUN
eurjchem-990	54	35	as	as	SCONJ
eurjchem-990	54	36	implemented	implement	VERB
eurjchem-990	54	37	in	in	ADP
eurjchem-990	54	38	hyperchem	hyperchem	NOUN
eurjchem-990	54	39	7.5	7.5	NUM
eurjchem-990	55	1	[	[	X
eurjchem-990	55	2	25	25	NUM
eurjchem-990	55	3	]	]	PUNCT
eurjchem-990	55	4	.	.	PUNCT
eurjchem-990	56	1	convergence	convergence	NOUN
eurjchem-990	56	2	criteria	criterion	NOUN
eurjchem-990	56	3	were	be	AUX
eurjchem-990	56	4	set	set	VERB
eurjchem-990	56	5	to	to	ADP
eurjchem-990	56	6	0.01	0.01	NUM
eurjchem-990	56	7	kcal	kcal	NOUN
eurjchem-990	56	8	/	/	SYM
eurjchem-990	56	9	mol.å	mol.å	PROPN
eurjchem-990	56	10	for	for	ADP
eurjchem-990	56	11	pm3	pm3	PROPN
eurjchem-990	56	12	calculations	calculation	NOUN
eurjchem-990	56	13	.	.	PUNCT
eurjchem-990	57	1	2.4	2.4	NUM
eurjchem-990	57	2	.	.	PUNCT
eurjchem-990	57	3	biological	biological	ADJ
eurjchem-990	57	4	activity	activity	NOUN
eurjchem-990	57	5	the	the	DET
eurjchem-990	57	6	antibacterial	antibacterial	ADJ
eurjchem-990	57	7	investigation	investigation	NOUN
eurjchem-990	57	8	of	of	ADP
eurjchem-990	57	9	the	the	DET
eurjchem-990	57	10	free	free	ADJ
eurjchem-990	57	11	(	(	PUNCT
eurjchem-990	57	12	ephc	ephc	NOUN
eurjchem-990	57	13	)	)	PUNCT
eurjchem-990	57	14	ligand	ligand	NOUN
eurjchem-990	57	15	or	or	CCONJ
eurjchem-990	57	16	its	its	PRON
eurjchem-990	57	17	mn(ii	mn(ii	NOUN
eurjchem-990	57	18	)	)	PUNCT
eurjchem-990	57	19	,	,	PUNCT
eurjchem-990	57	20	co(ii	co(ii	PROPN
eurjchem-990	57	21	)	)	PUNCT
eurjchem-990	57	22	,	,	PUNCT
eurjchem-990	57	23	cu(ii	cu(ii	PROPN
eurjchem-990	57	24	)	)	PUNCT
eurjchem-990	57	25	and	and	CCONJ
eurjchem-990	57	26	ni(ii	ni(ii	ADJ
eurjchem-990	57	27	)	)	PUNCT
eurjchem-990	57	28	complexes	complex	NOUN
eurjchem-990	57	29	was	be	AUX
eurjchem-990	57	30	carried	carry	VERB
eurjchem-990	57	31	out	out	ADP
eurjchem-990	57	32	using	use	VERB
eurjchem-990	57	33	a	a	DET
eurjchem-990	57	34	modified	modify	VERB
eurjchem-990	57	35	kirby‐bauer	kirby‐bauer	NOUN
eurjchem-990	57	36	disc	disc	NOUN
eurjchem-990	57	37	diffusion	diffusion	NOUN
eurjchem-990	57	38	method	method	NOUN
eurjchem-990	57	39	[	[	X
eurjchem-990	57	40	26	26	NUM
eurjchem-990	57	41	]	]	PUNCT
eurjchem-990	57	42	.	.	PUNCT
eurjchem-990	58	1	the	the	DET
eurjchem-990	58	2	test	test	NOUN
eurjchem-990	58	3	was	be	AUX
eurjchem-990	58	4	done	do	VERB
eurjchem-990	58	5	against	against	ADP
eurjchem-990	58	6	filamentous	filamentous	ADJ
eurjchem-990	58	7	fungi	fungus	NOUN
eurjchem-990	58	8	as	as	ADP
eurjchem-990	58	9	(	(	PUNCT
eurjchem-990	58	10	aspergillus	aspergillus	NOUN
eurjchem-990	58	11	flavus	flavus	NOUN
eurjchem-990	58	12	rcmb	rcmb	PROPN
eurjchem-990	58	13	02568	02568	NUM
eurjchem-990	58	14	,	,	PUNCT
eurjchem-990	58	15	pencicillium	pencicillium	NOUN
eurjchem-990	58	16	italicum	italicum	NOUN
eurjchem-990	58	17	(	(	PUNCT
eurjchem-990	58	18	rcmb	rcmb	NOUN
eurjchem-990	58	19	03924	03924	NUM
eurjchem-990	58	20	)	)	PUNCT
eurjchem-990	58	21	,	,	PUNCT
eurjchem-990	58	22	aspergillus	aspergillus	NOUN
eurjchem-990	58	23	flavus	flavus	NOUN
eurjchem-990	58	24	(	(	PUNCT
eurjchem-990	58	25	rcmb	rcmb	NOUN
eurjchem-990	58	26	02568	02568	NUM
eurjchem-990	58	27	)	)	PUNCT
eurjchem-990	58	28	)	)	PUNCT
eurjchem-990	58	29	at	at	ADP
eurjchem-990	58	30	30	30	NUM
eurjchem-990	58	31	°	°	ADP
eurjchem-990	58	32	c	c	NOUN
eurjchem-990	58	33	for	for	ADP
eurjchem-990	58	34	24‐48	24‐48	NUM
eurjchem-990	58	35	hours	hour	NOUN
eurjchem-990	58	36	;	;	PUNCT
eurjchem-990	58	37	gram	gram	NOUN
eurjchem-990	58	38	(	(	PUNCT
eurjchem-990	58	39	+	+	NOUN
eurjchem-990	58	40	)	)	PUNCT
eurjchem-990	58	41	bacteria	bacteria	NOUN
eurjchem-990	58	42	as	as	SCONJ
eurjchem-990	58	43	(	(	PUNCT
eurjchem-990	58	44	bacillus	bacillus	NOUN
eurjchem-990	58	45	subtillis	subtilli	VERB
eurjchem-990	58	46	rcmb	rcmb	PROPN
eurjchem-990	58	47	010067	010067	NUM
eurjchem-990	58	48	,	,	PUNCT
eurjchem-990	58	49	staphylococcus	staphylococcus	NOUN
eurjchem-990	58	50	aureus	aureus	NOUN
eurjchem-990	58	51	rcmb	rcmb	PROPN
eurjchem-990	58	52	010028	010028	NUM
eurjchem-990	58	53	)	)	PUNCT
eurjchem-990	58	54	;	;	PUNCT
eurjchem-990	58	55	gram	gram	NOUN
eurjchem-990	58	56	(	(	PUNCT
eurjchem-990	58	57	‐	‐	NOUN
eurjchem-990	58	58	)	)	PUNCT
eurjchem-990	58	59	bacteria	bacteria	NOUN
eurjchem-990	58	60	as	as	ADP
eurjchem-990	58	61	(	(	PUNCT
eurjchem-990	58	62	pseudomonas	pseudomona	NOUN
eurjchem-990	58	63	aeuroginosa	aeuroginosa	PROPN
eurjchem-990	58	64	rcmb	rcmb	PROPN
eurjchem-990	58	65	010043	010043	PROPN
eurjchem-990	58	66	,	,	PUNCT
eurjchem-990	58	67	escherichia	escherichia	NOUN
eurjchem-990	58	68	coli	coli	NOUN
eurjchem-990	58	69	rcmb	rcmb	NOUN
eurjchem-990	58	70	010052	010052	NUM
eurjchem-990	58	71	)	)	PUNCT
eurjchem-990	58	72	.	.	PUNCT
eurjchem-990	59	1	the	the	DET
eurjchem-990	59	2	standard	standard	ADJ
eurjchem-990	59	3	antibacterial	antibacterial	ADJ
eurjchem-990	59	4	agents	agent	NOUN
eurjchem-990	59	5	used	use	VERB
eurjchem-990	59	6	are	be	AUX
eurjchem-990	59	7	gentamicin	gentamicin	VERB
eurjchem-990	59	8	for	for	ADP
eurjchem-990	59	9	g‐	g‐	PROPN
eurjchem-990	59	10	,	,	PUNCT
eurjchem-990	59	11	ampicillin	ampicillin	NOUN
eurjchem-990	59	12	for	for	ADP
eurjchem-990	59	13	g+	g+	NOUN
eurjchem-990	59	14	and	and	CCONJ
eurjchem-990	59	15	amphotericin	amphotericin	ADP
eurjchem-990	59	16	b	b	X
eurjchem-990	59	17	(	(	PUNCT
eurjchem-990	59	18	antifungal	antifungal	ADJ
eurjchem-990	59	19	agent	agent	NOUN
eurjchem-990	59	20	)	)	PUNCT
eurjchem-990	59	21	served	serve	VERB
eurjchem-990	59	22	as	as	ADP
eurjchem-990	59	23	positive	positive	ADJ
eurjchem-990	59	24	controls	control	NOUN
eurjchem-990	59	25	while	while	SCONJ
eurjchem-990	59	26	dmso	dmso	NOUN
eurjchem-990	59	27	,	,	PUNCT
eurjchem-990	59	28	which	which	PRON
eurjchem-990	59	29	exhibited	exhibit	VERB
eurjchem-990	59	30	no	no	DET
eurjchem-990	59	31	antimicrobial	antimicrobial	ADJ
eurjchem-990	59	32	activity	activity	NOUN
eurjchem-990	59	33	,	,	PUNCT
eurjchem-990	59	34	was	be	AUX
eurjchem-990	59	35	used	use	VERB
eurjchem-990	59	36	as	as	ADP
eurjchem-990	59	37	a	a	DET
eurjchem-990	59	38	negative	negative	ADJ
eurjchem-990	59	39	control	control	NOUN
eurjchem-990	59	40	.	.	PUNCT
eurjchem-990	60	1	the	the	DET
eurjchem-990	60	2	agar	agar	NOUN
eurjchem-990	60	3	used	use	VERB
eurjchem-990	60	4	is	be	AUX
eurjchem-990	60	5	mueller‐hinton	mueller‐hinton	NOUN
eurjchem-990	60	6	agar	agar	NOUN
eurjchem-990	60	7	that	that	PRON
eurjchem-990	60	8	is	be	AUX
eurjchem-990	60	9	rigorously	rigorously	ADV
eurjchem-990	60	10	tested	test	VERB
eurjchem-990	60	11	for	for	ADP
eurjchem-990	60	12	composition	composition	NOUN
eurjchem-990	60	13	and	and	CCONJ
eurjchem-990	60	14	ph	ph	NOUN
eurjchem-990	60	15	.	.	PROPN
eurjchem-990	60	16	254	254	NUM
eurjchem-990	60	17	mohamed	mohame	VERB
eurjchem-990	60	18	et	et	PROPN
eurjchem-990	60	19	al	al	PROPN
eurjchem-990	60	20	.	.	PUNCT
eurjchem-990	60	21	/	/	SYM
eurjchem-990	60	22	european	european	PROPN
eurjchem-990	60	23	journal	journal	PROPN
eurjchem-990	60	24	of	of	ADP
eurjchem-990	60	25	chemistry	chemistry	NOUN
eurjchem-990	60	26	5	5	NUM
eurjchem-990	60	27	(	(	PUNCT
eurjchem-990	60	28	2	2	NUM
eurjchem-990	60	29	)	)	PUNCT
eurjchem-990	60	30	(	(	PUNCT
eurjchem-990	60	31	2014	2014	NUM
eurjchem-990	60	32	)	)	PUNCT
eurjchem-990	60	33	252‐259	252‐259	NOUN
eurjchem-990	60	34	table	table	NOUN
eurjchem-990	60	35	1	1	NUM
eurjchem-990	60	36	.	.	PUNCT
eurjchem-990	60	37	analytical	analytical	ADJ
eurjchem-990	60	38	and	and	CCONJ
eurjchem-990	60	39	physical	physical	ADJ
eurjchem-990	60	40	data	datum	NOUN
eurjchem-990	60	41	of	of	ADP
eurjchem-990	60	42	synthesized	synthesize	VERB
eurjchem-990	60	43	compounds	compound	NOUN
eurjchem-990	60	44	.	.	PUNCT
eurjchem-990	61	1	compound	compound	NOUN
eurjchem-990	61	2	formula	formula	NOUN
eurjchem-990	61	3	yield	yield	NOUN
eurjchem-990	61	4	(	(	PUNCT
eurjchem-990	61	5	%	%	INTJ
eurjchem-990	61	6	)	)	PUNCT
eurjchem-990	61	7	%	%	NOUN
eurjchem-990	61	8	calculated	calculated	ADJ
eurjchem-990	61	9	(	(	PUNCT
eurjchem-990	61	10	found	find	VERB
eurjchem-990	61	11	)	)	PUNCT
eurjchem-990	62	1	c	c	PROPN
eurjchem-990	62	2	h	h	NOUN
eurjchem-990	63	1	n	n	NOUN
eurjchem-990	63	2	s	s	PROPN
eurjchem-990	63	3	cl	cl	NOUN
eurjchem-990	63	4	ephc	ephc	NOUN
eurjchem-990	63	5	c9h12n4os	c9h12n4o	VERB
eurjchem-990	63	6	77	77	NUM
eurjchem-990	63	7	48.20	48.20	NUM
eurjchem-990	63	8	(	(	PUNCT
eurjchem-990	63	9	48.18	48.18	NUM
eurjchem-990	63	10	)	)	PUNCT
eurjchem-990	63	11	5.39	5.39	NUM
eurjchem-990	63	12	(	(	PUNCT
eurjchem-990	63	13	5.36	5.36	NUM
eurjchem-990	63	14	)	)	PUNCT
eurjchem-990	63	15	24.98	24.98	NUM
eurjchem-990	63	16	(	(	PUNCT
eurjchem-990	63	17	24.82	24.82	NUM
eurjchem-990	63	18	)	)	PUNCT
eurjchem-990	63	19	14.30	14.30	NUM
eurjchem-990	63	20	(	(	PUNCT
eurjchem-990	63	21	14.28	14.28	NUM
eurjchem-990	63	22	)	)	PUNCT
eurjchem-990	63	23	‐	‐	NOUN
eurjchem-990	63	24	(	(	PUNCT
eurjchem-990	63	25	‐	‐	NOUN
eurjchem-990	63	26	)	)	PUNCT
eurjchem-990	64	1	[	[	X
eurjchem-990	64	2	cu(ephc)(1,10‐phen)cl	cu(ephc)(1,10‐phen)cl	X
eurjchem-990	64	3	]	]	X
eurjchem-990	64	4	(	(	PUNCT
eurjchem-990	64	5	1	1	X
eurjchem-990	64	6	)	)	PUNCT
eurjchem-990	64	7	c21h19n6oscucl	c21h19n6oscucl	NOUN
eurjchem-990	64	8	85	85	NUM
eurjchem-990	64	9	50.15	50.15	NUM
eurjchem-990	64	10	(	(	PUNCT
eurjchem-990	64	11	50.21	50.21	NUM
eurjchem-990	64	12	)	)	PUNCT
eurjchem-990	64	13	3.78	3.78	NUM
eurjchem-990	64	14	(	(	PUNCT
eurjchem-990	64	15	3.80	3.80	NUM
eurjchem-990	64	16	)	)	PUNCT
eurjchem-990	64	17	16.71	16.71	NUM
eurjchem-990	64	18	(	(	PUNCT
eurjchem-990	64	19	16.70	16.70	NUM
eurjchem-990	64	20	)	)	PUNCT
eurjchem-990	64	21	6.36	6.36	NUM
eurjchem-990	64	22	(	(	PUNCT
eurjchem-990	64	23	6.47	6.47	NUM
eurjchem-990	64	24	)	)	PUNCT
eurjchem-990	64	25	7.06	7.06	NUM
eurjchem-990	64	26	(	(	PUNCT
eurjchem-990	64	27	7.09	7.09	NUM
eurjchem-990	64	28	)	)	PUNCT
eurjchem-990	65	1	[	[	X
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eurjchem-990	65	3	(	(	PUNCT
eurjchem-990	65	4	2	2	NUM
eurjchem-990	65	5	)	)	PUNCT
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eurjchem-990	65	9	(	(	PUNCT
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eurjchem-990	65	11	)	)	PUNCT
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eurjchem-990	65	13	(	(	PUNCT
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eurjchem-990	65	15	)	)	PUNCT
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eurjchem-990	65	17	(	(	PUNCT
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eurjchem-990	65	19	)	)	PUNCT
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eurjchem-990	65	21	(	(	PUNCT
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eurjchem-990	65	25	(	(	PUNCT
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eurjchem-990	65	27	)	)	PUNCT
eurjchem-990	66	1	[	[	X
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eurjchem-990	66	3	(	(	PUNCT
eurjchem-990	66	4	3	3	NUM
eurjchem-990	66	5	)	)	PUNCT
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eurjchem-990	66	9	(	(	PUNCT
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eurjchem-990	66	11	)	)	PUNCT
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eurjchem-990	66	13	(	(	PUNCT
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eurjchem-990	66	15	)	)	PUNCT
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eurjchem-990	66	17	(	(	PUNCT
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eurjchem-990	66	19	)	)	PUNCT
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eurjchem-990	66	21	(	(	PUNCT
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eurjchem-990	66	23	)	)	PUNCT
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eurjchem-990	66	25	(	(	PUNCT
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eurjchem-990	66	27	)	)	PUNCT
eurjchem-990	67	1	[	[	X
eurjchem-990	67	2	mn(ephc)(1,10‐phen)cl].2h2o	mn(ephc)(1,10‐phen)cl].2h2o	NOUN
eurjchem-990	67	3	(	(	PUNCT
eurjchem-990	67	4	4	4	NUM
eurjchem-990	67	5	)	)	PUNCT
eurjchem-990	67	6	c21h19n6osmncl.2h2o	c21h19n6osmncl.2h2o	VERB
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eurjchem-990	67	9	(	(	PUNCT
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eurjchem-990	67	11	)	)	PUNCT
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eurjchem-990	67	13	(	(	PUNCT
eurjchem-990	67	14	4.40	4.40	NUM
eurjchem-990	67	15	)	)	PUNCT
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eurjchem-990	67	17	(	(	PUNCT
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eurjchem-990	67	19	)	)	PUNCT
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eurjchem-990	67	21	(	(	PUNCT
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eurjchem-990	67	23	)	)	PUNCT
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eurjchem-990	67	25	(	(	PUNCT
eurjchem-990	67	26	6.76	6.76	NUM
eurjchem-990	67	27	)	)	PUNCT
eurjchem-990	67	28	table	table	NOUN
eurjchem-990	67	29	2	2	NUM
eurjchem-990	67	30	.	.	PUNCT
eurjchem-990	67	31	tentative	tentative	ADJ
eurjchem-990	67	32	assignment	assignment	NOUN
eurjchem-990	67	33	of	of	ADP
eurjchem-990	67	34	the	the	DET
eurjchem-990	67	35	important	important	ADJ
eurjchem-990	67	36	infrared	infrared	ADJ
eurjchem-990	67	37	bands	band	NOUN
eurjchem-990	67	38	of	of	ADP
eurjchem-990	67	39	the	the	DET
eurjchem-990	67	40	synthesized	synthesize	VERB
eurjchem-990	67	41	complexes	complex	NOUN
eurjchem-990	67	42	.	.	PUNCT
eurjchem-990	68	1	compounds	compound	VERB
eurjchem-990	68	2	υh2o	υh2o	VERB
eurjchem-990	68	3	δ(c	δ(c	PROPN
eurjchem-990	68	4	=	=	SYM
eurjchem-990	68	5	n	n	CCONJ
eurjchem-990	68	6	)	)	PUNCT
eurjchem-990	68	7	py	py	ADP
eurjchem-990	68	8	υ(c	υ(c	PROPN
eurjchem-990	68	9	=	=	SYM
eurjchem-990	68	10	n)py	n)py	PROPN
eurjchem-990	68	11	υc	υc	PROPN
eurjchem-990	68	12	=	=	NOUN
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eurjchem-990	68	14	υn‐n	υn‐n	PROPN
eurjchem-990	68	15	υ(n	υ(n	PROPN
eurjchem-990	68	16	=	=	SYM
eurjchem-990	68	17	c	c	NOUN
eurjchem-990	68	18	)	)	PUNCT
eurjchem-990	68	19	*	*	PUNCT
eurjchem-990	69	1	υ(m‐n)py	υ(m‐n)py	PROPN
eurjchem-990	69	2	υ(c	υ(c	PROPN
eurjchem-990	69	3	=	=	PROPN
eurjchem-990	69	4	n)phen	n)phen	PROPN
eurjchem-990	69	5	υm‐n	υm‐n	PROPN
eurjchem-990	69	6	υm‐s	υm‐s	PART
eurjchem-990	69	7	υm‐cl	υm‐cl	PUNCT
eurjchem-990	69	8	ephc	ephc	PROPN
eurjchem-990	69	9	/	/	SYM
eurjchem-990	69	10	phen	phen	PROPN
eurjchem-990	69	11	‐	‐	VERB
eurjchem-990	69	12	615	615	NUM
eurjchem-990	69	13	1608	1608	NUM
eurjchem-990	69	14	1290	1290	NUM
eurjchem-990	69	15	,	,	PUNCT
eurjchem-990	69	16	830	830	NUM
eurjchem-990	69	17	1115	1115	NUM
eurjchem-990	69	18	‐	‐	NOUN
eurjchem-990	69	19	‐	‐	ADP
eurjchem-990	69	20	1570	1570	NUM
eurjchem-990	69	21	‐	‐	NOUN
eurjchem-990	69	22	‐	‐	ADV
eurjchem-990	69	23	‐	‐	ADV
eurjchem-990	69	24	[	[	X
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eurjchem-990	69	26	]	]	X
eurjchem-990	69	27	(	(	PUNCT
eurjchem-990	69	28	1	1	X
eurjchem-990	69	29	)	)	PUNCT
eurjchem-990	69	30	‐	‐	ADV
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eurjchem-990	69	34	,	,	PUNCT
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eurjchem-990	69	40	444	444	NUM
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eurjchem-990	69	43	[	[	X
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eurjchem-990	69	45	(	(	PUNCT
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eurjchem-990	69	47	)	)	PUNCT
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eurjchem-990	69	52	,	,	PUNCT
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eurjchem-990	69	56	278	278	NUM
eurjchem-990	69	57	1550	1550	NUM
eurjchem-990	69	58	438	438	NUM
eurjchem-990	69	59	323	323	NUM
eurjchem-990	69	60	238	238	NUM
eurjchem-990	70	1	[	[	X
eurjchem-990	70	2	co(ephc)(1,10‐phen)cl].h2o	co(ephc)(1,10‐phen)cl].h2o	NOUN
eurjchem-990	70	3	(	(	PUNCT
eurjchem-990	70	4	3	3	NUM
eurjchem-990	70	5	)	)	PUNCT
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eurjchem-990	70	10	,	,	PUNCT
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eurjchem-990	70	19	[	[	NOUN
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eurjchem-990	70	21	(	(	PUNCT
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eurjchem-990	70	23	)	)	PUNCT
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eurjchem-990	70	47	the	the	DET
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eurjchem-990	70	50	the	the	DET
eurjchem-990	70	51	(	(	PUNCT
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eurjchem-990	70	54	s	s	NOUN
eurjchem-990	70	55	)	)	PUNCT
eurjchem-990	70	56	group	group	NOUN
eurjchem-990	70	57	.	.	PUNCT
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eurjchem-990	71	2	were	be	AUX
eurjchem-990	71	3	incubated	incubate	VERB
eurjchem-990	71	4	with	with	ADP
eurjchem-990	71	5	filamentous	filamentous	ADJ
eurjchem-990	71	6	fungi	fungus	NOUN
eurjchem-990	71	7	at	at	ADP
eurjchem-990	71	8	30	30	NUM
eurjchem-990	71	9	°	°	ADP
eurjchem-990	71	10	c	c	NOUN
eurjchem-990	71	11	for	for	ADP
eurjchem-990	71	12	24‐48	24‐48	NUM
eurjchem-990	71	13	hours	hour	NOUN
eurjchem-990	71	14	and	and	CCONJ
eurjchem-990	71	15	with	with	ADP
eurjchem-990	71	16	bacteria	bacteria	NOUN
eurjchem-990	71	17	at	at	ADP
eurjchem-990	71	18	35‐37	35‐37	NUM
eurjchem-990	71	19	°	°	ADP
eurjchem-990	71	20	c	c	NOUN
eurjchem-990	71	21	for	for	ADP
eurjchem-990	71	22	24‐48	24‐48	NUM
eurjchem-990	71	23	hours	hour	NOUN
eurjchem-990	71	24	[	[	X
eurjchem-990	71	25	27	27	NUM
eurjchem-990	71	26	]	]	PUNCT
eurjchem-990	71	27	and	and	CCONJ
eurjchem-990	71	28	then	then	ADV
eurjchem-990	71	29	the	the	DET
eurjchem-990	71	30	diameters	diameter	NOUN
eurjchem-990	71	31	of	of	ADP
eurjchem-990	71	32	inhibition	inhibition	NOUN
eurjchem-990	71	33	zones	zone	NOUN
eurjchem-990	71	34	were	be	AUX
eurjchem-990	71	35	measured	measure	VERB
eurjchem-990	71	36	in	in	ADP
eurjchem-990	71	37	millimeters	millimeter	NOUN
eurjchem-990	71	38	using	use	VERB
eurjchem-990	71	39	slipping	slip	VERB
eurjchem-990	71	40	calipers	caliper	NOUN
eurjchem-990	71	41	of	of	ADP
eurjchem-990	71	42	the	the	DET
eurjchem-990	71	43	national	national	PROPN
eurjchem-990	71	44	committee	committee	PROPN
eurjchem-990	71	45	for	for	ADP
eurjchem-990	71	46	clinical	clinical	ADJ
eurjchem-990	71	47	laboratory	laboratory	NOUN
eurjchem-990	71	48	standards	standard	NOUN
eurjchem-990	71	49	(	(	PUNCT
eurjchem-990	71	50	nccls	nccls	NOUN
eurjchem-990	71	51	)	)	PUNCT
eurjchem-990	72	1	[	[	X
eurjchem-990	72	2	28,29	28,29	X
eurjchem-990	72	3	]	]	X
eurjchem-990	72	4	.	.	PUNCT
eurjchem-990	73	1	3	3	X
eurjchem-990	73	2	.	.	NOUN
eurjchem-990	73	3	results	result	NOUN
eurjchem-990	73	4	and	and	CCONJ
eurjchem-990	73	5	discussion	discussion	VERB
eurjchem-990	73	6	the	the	DET
eurjchem-990	73	7	isolated	isolated	ADJ
eurjchem-990	73	8	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-990	73	9	compound	compound	NOUN
eurjchem-990	73	10	is	be	AUX
eurjchem-990	73	11	formed	form	VERB
eurjchem-990	73	12	by	by	ADP
eurjchem-990	73	13	the	the	DET
eurjchem-990	73	14	interaction	interaction	NOUN
eurjchem-990	73	15	of	of	ADP
eurjchem-990	73	16	2‐picolinic	2‐picolinic	ADJ
eurjchem-990	73	17	acid	acid	NOUN
eurjchem-990	73	18	hydrazide	hydrazide	ADV
eurjchem-990	73	19	with	with	ADP
eurjchem-990	73	20	ethyl	ethyl	PROPN
eurjchem-990	73	21	isothio‐	isothio‐	NOUN
eurjchem-990	73	22	cyanate	cyanate	VERB
eurjchem-990	73	23	under	under	ADP
eurjchem-990	73	24	reflux	reflux	NOUN
eurjchem-990	73	25	conditions	condition	NOUN
eurjchem-990	73	26	(	(	PUNCT
eurjchem-990	73	27	scheme	scheme	NOUN
eurjchem-990	73	28	3	3	NUM
eurjchem-990	73	29	)	)	PUNCT
eurjchem-990	73	30	.	.	PUNCT
eurjchem-990	74	1	the	the	DET
eurjchem-990	74	2	formulation	formulation	NOUN
eurjchem-990	74	3	of	of	ADP
eurjchem-990	74	4	the	the	DET
eurjchem-990	74	5	isolated	isolate	VERB
eurjchem-990	74	6	compounds	compound	NOUN
eurjchem-990	74	7	based	base	VERB
eurjchem-990	74	8	on	on	ADP
eurjchem-990	74	9	the	the	DET
eurjchem-990	74	10	elemental	elemental	ADJ
eurjchem-990	74	11	analysis	analysis	NOUN
eurjchem-990	74	12	(	(	PUNCT
eurjchem-990	74	13	table	table	NOUN
eurjchem-990	74	14	1	1	NUM
eurjchem-990	74	15	)	)	PUNCT
eurjchem-990	74	16	,	,	PUNCT
eurjchem-990	74	17	ir	ir	PROPN
eurjchem-990	74	18	,	,	PUNCT
eurjchem-990	74	19	and	and	CCONJ
eurjchem-990	74	20	electronic	electronic	ADJ
eurjchem-990	74	21	spectra	spectra	NOUN
eurjchem-990	74	22	.	.	PUNCT
eurjchem-990	75	1	the	the	DET
eurjchem-990	75	2	solid	solid	ADJ
eurjchem-990	75	3	compounds	compound	NOUN
eurjchem-990	75	4	are	be	AUX
eurjchem-990	75	5	air	air	NOUN
eurjchem-990	75	6	stable	stable	ADJ
eurjchem-990	75	7	.	.	PUNCT
eurjchem-990	76	1	these	these	DET
eurjchem-990	76	2	compounds	compound	NOUN
eurjchem-990	76	3	are	be	AUX
eurjchem-990	76	4	colored	color	VERB
eurjchem-990	76	5	,	,	PUNCT
eurjchem-990	76	6	insoluble	insoluble	ADJ
eurjchem-990	76	7	in	in	ADP
eurjchem-990	76	8	h2o	h2o	PROPN
eurjchem-990	76	9	and	and	CCONJ
eurjchem-990	76	10	other	other	ADJ
eurjchem-990	76	11	common	common	ADJ
eurjchem-990	76	12	organic	organic	ADJ
eurjchem-990	76	13	solvents	solvent	NOUN
eurjchem-990	76	14	like	like	ADP
eurjchem-990	76	15	methanol	methanol	NOUN
eurjchem-990	76	16	and	and	CCONJ
eurjchem-990	76	17	ethanol	ethanol	NOUN
eurjchem-990	76	18	but	but	CCONJ
eurjchem-990	76	19	soluble	soluble	ADJ
eurjchem-990	76	20	in	in	ADP
eurjchem-990	76	21	dimethylformamide	dimethylformamide	NOUN
eurjchem-990	76	22	(	(	PUNCT
eurjchem-990	76	23	dmf	dmf	PROPN
eurjchem-990	76	24	)	)	PUNCT
eurjchem-990	76	25	and	and	CCONJ
eurjchem-990	76	26	dimethylsulphoxide	dimethylsulphoxide	NOUN
eurjchem-990	76	27	(	(	PUNCT
eurjchem-990	76	28	dmso	dmso	PROPN
eurjchem-990	76	29	)	)	PUNCT
eurjchem-990	76	30	.	.	PUNCT
eurjchem-990	77	1	attempts	attempt	VERB
eurjchem-990	77	2	to	to	PART
eurjchem-990	77	3	obtain	obtain	VERB
eurjchem-990	77	4	single	single	ADJ
eurjchem-990	77	5	crystal	crystal	NOUN
eurjchem-990	77	6	suitable	suitable	ADJ
eurjchem-990	77	7	for	for	ADP
eurjchem-990	77	8	x‐ray	x‐ray	ADJ
eurjchem-990	77	9	determination	determination	NOUN
eurjchem-990	77	10	were	be	AUX
eurjchem-990	77	11	unsuccessful	unsuccessful	ADJ
eurjchem-990	77	12	,	,	PUNCT
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eurjchem-990	77	14	molecular	molecular	ADJ
eurjchem-990	77	15	modeling	modeling	NOUN
eurjchem-990	77	16	for	for	ADP
eurjchem-990	77	17	ephc	ephc	NOUN
eurjchem-990	77	18	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-990	77	19	compound	compound	NOUN
eurjchem-990	77	20	and	and	CCONJ
eurjchem-990	77	21	its	its	PRON
eurjchem-990	77	22	m(ii)‐complexes	m(ii)‐complexe	NOUN
eurjchem-990	77	23	were	be	AUX
eurjchem-990	77	24	investigated	investigate	VERB
eurjchem-990	77	25	.	.	PUNCT
eurjchem-990	78	1	3.1	3.1	NUM
eurjchem-990	78	2	.	.	PUNCT
eurjchem-990	78	3	infrared	infrared	PROPN
eurjchem-990	78	4	spectra	spectra	PROPN
eurjchem-990	78	5	the	the	DET
eurjchem-990	78	6	tentative	tentative	ADJ
eurjchem-990	78	7	assignments	assignment	NOUN
eurjchem-990	78	8	of	of	ADP
eurjchem-990	78	9	the	the	DET
eurjchem-990	78	10	significant	significant	ADJ
eurjchem-990	78	11	ir	ir	PROPN
eurjchem-990	78	12	spectral	spectral	ADJ
eurjchem-990	78	13	bands	band	NOUN
eurjchem-990	78	14	of	of	ADP
eurjchem-990	78	15	the	the	DET
eurjchem-990	78	16	free	free	ADJ
eurjchem-990	78	17	ephc	ephc	NOUN
eurjchem-990	78	18	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-990	78	19	compound	compound	NOUN
eurjchem-990	78	20	and	and	CCONJ
eurjchem-990	78	21	its	its	PRON
eurjchem-990	78	22	metal(ii	metal(ii	NOUN
eurjchem-990	78	23	)	)	PUNCT
eurjchem-990	78	24	complexes	complex	NOUN
eurjchem-990	78	25	are	be	AUX
eurjchem-990	78	26	listed	list	VERB
eurjchem-990	78	27	in	in	ADP
eurjchem-990	78	28	table	table	NOUN
eurjchem-990	78	29	2	2	NUM
eurjchem-990	78	30	.	.	PUNCT
eurjchem-990	79	1	the	the	DET
eurjchem-990	79	2	characteristic	characteristic	ADJ
eurjchem-990	79	3	ir	ir	PROPN
eurjchem-990	79	4	peaks	peak	NOUN
eurjchem-990	79	5	reveal	reveal	VERB
eurjchem-990	79	6	each	each	PRON
eurjchem-990	79	7	of	of	ADP
eurjchem-990	79	8	the	the	DET
eurjchem-990	79	9	following	following	NOUN
eurjchem-990	79	10	:	:	PUNCT
eurjchem-990	79	11	in	in	ADP
eurjchem-990	79	12	the	the	DET
eurjchem-990	79	13	spectra	spectra	NOUN
eurjchem-990	79	14	of	of	ADP
eurjchem-990	79	15	ephc	ephc	PROPN
eurjchem-990	79	16	,	,	PUNCT
eurjchem-990	79	17	the	the	DET
eurjchem-990	79	18	band	band	NOUN
eurjchem-990	79	19	observed	observe	VERB
eurjchem-990	79	20	at	at	ADP
eurjchem-990	79	21	1115	1115	NUM
eurjchem-990	79	22	cm‐1	cm‐1	NOUN
eurjchem-990	79	23	is	be	AUX
eurjchem-990	79	24	assigned	assign	VERB
eurjchem-990	79	25	to	to	ADP
eurjchem-990	79	26	ν(n‐n	ν(n‐n	NUM
eurjchem-990	79	27	)	)	PUNCT
eurjchem-990	79	28	.	.	PUNCT
eurjchem-990	80	1	the	the	DET
eurjchem-990	80	2	increase	increase	NOUN
eurjchem-990	80	3	in	in	ADP
eurjchem-990	80	4	frequency	frequency	NOUN
eurjchem-990	80	5	of	of	ADP
eurjchem-990	80	6	this	this	DET
eurjchem-990	80	7	band	band	NOUN
eurjchem-990	80	8	in	in	ADP
eurjchem-990	80	9	the	the	DET
eurjchem-990	80	10	spectra	spectra	NOUN
eurjchem-990	80	11	of	of	ADP
eurjchem-990	80	12	complexes	complex	NOUN
eurjchem-990	80	13	due	due	ADP
eurjchem-990	80	14	to	to	ADP
eurjchem-990	80	15	the	the	DET
eurjchem-990	80	16	increase	increase	NOUN
eurjchem-990	80	17	in	in	ADP
eurjchem-990	80	18	the	the	DET
eurjchem-990	80	19	double	double	ADJ
eurjchem-990	80	20	bond	bond	NOUN
eurjchem-990	80	21	character	character	NOUN
eurjchem-990	80	22	of	of	ADP
eurjchem-990	80	23	n‐n	n‐n	ADP
eurjchem-990	80	24	[	[	X
eurjchem-990	80	25	30	30	NUM
eurjchem-990	80	26	]	]	PUNCT
eurjchem-990	80	27	is	be	AUX
eurjchem-990	80	28	an	an	DET
eurjchem-990	80	29	evidence	evidence	NOUN
eurjchem-990	80	30	for	for	ADP
eurjchem-990	80	31	the	the	DET
eurjchem-990	80	32	enethiolization	enethiolization	NOUN
eurjchem-990	80	33	of	of	ADP
eurjchem-990	80	34	the	the	DET
eurjchem-990	80	35	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-990	80	36	ligand	ligand	NOUN
eurjchem-990	80	37	and	and	CCONJ
eurjchem-990	80	38	the	the	DET
eurjchem-990	80	39	coordination	coordination	NOUN
eurjchem-990	80	40	via	via	ADP
eurjchem-990	80	41	the	the	DET
eurjchem-990	80	42	azomethine	azomethine	NOUN
eurjchem-990	80	43	nitrogen	nitrogen	NOUN
eurjchem-990	80	44	.	.	PUNCT
eurjchem-990	81	1	the	the	DET
eurjchem-990	81	2	ir	ir	PROPN
eurjchem-990	81	3	spectrum	spectrum	NOUN
eurjchem-990	81	4	of	of	ADP
eurjchem-990	81	5	ephc	ephc	PROPN
eurjchem-990	81	6	ligand	ligand	PROPN
eurjchem-990	81	7	exhibits	exhibit	VERB
eurjchem-990	81	8	a	a	DET
eurjchem-990	81	9	band	band	NOUN
eurjchem-990	81	10	at	at	ADP
eurjchem-990	81	11	3510	3510	NUM
eurjchem-990	81	12	cm‐1	cm‐1	NOUN
eurjchem-990	81	13	due	due	ADP
eurjchem-990	81	14	to	to	ADP
eurjchem-990	81	15	ν(oh	ν(oh	NOUN
eurjchem-990	81	16	)	)	PUNCT
eurjchem-990	81	17	in	in	ADP
eurjchem-990	81	18	addition	addition	NOUN
eurjchem-990	81	19	to	to	ADP
eurjchem-990	81	20	ν(co	ν(co	NOUN
eurjchem-990	81	21	)	)	PUNCT
eurjchem-990	81	22	at	at	ADP
eurjchem-990	81	23	1665	1665	NUM
eurjchem-990	81	24	cm‐1	cm‐1	NOUN
eurjchem-990	81	25	suggested	suggest	VERB
eurjchem-990	81	26	the	the	DET
eurjchem-990	81	27	keto‐enol	keto‐enol	ADJ
eurjchem-990	81	28	tautomerism	tautomerism	NOUN
eurjchem-990	81	29	.	.	PUNCT
eurjchem-990	82	1	on	on	ADP
eurjchem-990	82	2	complexation	complexation	NOUN
eurjchem-990	82	3	the	the	DET
eurjchem-990	82	4	band	band	NOUN
eurjchem-990	82	5	due	due	ADP
eurjchem-990	82	6	to	to	ADP
eurjchem-990	82	7	ν(co	ν(co	X
eurjchem-990	82	8	)	)	PUNCT
eurjchem-990	82	9	is	be	AUX
eurjchem-990	82	10	absent	absent	ADJ
eurjchem-990	82	11	indicating	indicate	VERB
eurjchem-990	82	12	the	the	DET
eurjchem-990	82	13	coordination	coordination	NOUN
eurjchem-990	82	14	of	of	ADP
eurjchem-990	82	15	ephc	ephc	PROPN
eurjchem-990	82	16	ligand	ligand	NOUN
eurjchem-990	82	17	in	in	ADP
eurjchem-990	82	18	enol	enol	NOUN
eurjchem-990	82	19	form	form	NOUN
eurjchem-990	82	20	.	.	PUNCT
eurjchem-990	83	1	the	the	DET
eurjchem-990	83	2	pyridine	pyridine	ADJ
eurjchem-990	83	3	in‐plane	in‐plane	ADJ
eurjchem-990	83	4	deformation	deformation	NOUN
eurjchem-990	83	5	mode	mode	NOUN
eurjchem-990	83	6	at	at	ADP
eurjchem-990	83	7	615	615	NUM
eurjchem-990	83	8	cm‐1	cm‐1	NOUN
eurjchem-990	83	9	in	in	ADP
eurjchem-990	83	10	the	the	DET
eurjchem-990	83	11	spectrum	spectrum	NOUN
eurjchem-990	83	12	of	of	ADP
eurjchem-990	83	13	the	the	DET
eurjchem-990	83	14	ligand	ligand	ADJ
eurjchem-990	83	15	shifts	shift	NOUN
eurjchem-990	83	16	to	to	ADP
eurjchem-990	83	17	623‐	623‐	NUM
eurjchem-990	83	18	638	638	NUM
eurjchem-990	83	19	cm‐1	cm‐1	NOUN
eurjchem-990	83	20	in	in	ADP
eurjchem-990	83	21	spectra	spectra	NOUN
eurjchem-990	83	22	of	of	ADP
eurjchem-990	83	23	the	the	DET
eurjchem-990	83	24	above	above	ADJ
eurjchem-990	83	25	complexes	complex	NOUN
eurjchem-990	83	26	,	,	PUNCT
eurjchem-990	83	27	suggesting	suggest	VERB
eurjchem-990	83	28	coordination	coordination	NOUN
eurjchem-990	83	29	of	of	ADP
eurjchem-990	83	30	the	the	DET
eurjchem-990	83	31	heteroaromatic	heteroaromatic	ADJ
eurjchem-990	83	32	nitrogen	nitrogen	NOUN
eurjchem-990	83	33	.	.	PUNCT
eurjchem-990	84	1	in	in	ADP
eurjchem-990	84	2	the	the	DET
eurjchem-990	84	3	spectra	spectra	NOUN
eurjchem-990	84	4	of	of	ADP
eurjchem-990	84	5	all	all	DET
eurjchem-990	84	6	complexes	complex	NOUN
eurjchem-990	84	7	,	,	PUNCT
eurjchem-990	84	8	the	the	DET
eurjchem-990	84	9	bands	band	NOUN
eurjchem-990	84	10	assigned	assign	VERB
eurjchem-990	84	11	to	to	ADP
eurjchem-990	84	12	the	the	DET
eurjchem-990	84	13	newly	newly	ADV
eurjchem-990	84	14	formed	form	VERB
eurjchem-990	84	15	(	(	PUNCT
eurjchem-990	84	16	n	n	CCONJ
eurjchem-990	84	17	=	=	SYM
eurjchem-990	84	18	c	c	NOUN
eurjchem-990	84	19	)	)	PUNCT
eurjchem-990	84	20	*	*	PUNCT
eurjchem-990	84	21	band	band	NOUN
eurjchem-990	84	22	due	due	ADP
eurjchem-990	84	23	to	to	ADP
eurjchem-990	84	24	the	the	DET
eurjchem-990	84	25	thiolating	thiolating	NOUN
eurjchem-990	84	26	of	of	ADP
eurjchem-990	84	27	the	the	DET
eurjchem-990	84	28	(	(	PUNCT
eurjchem-990	84	29	c	c	NOUN
eurjchem-990	84	30	=	=	SYM
eurjchem-990	84	31	s	s	NOUN
eurjchem-990	84	32	)	)	PUNCT
eurjchem-990	84	33	groups	group	NOUN
eurjchem-990	84	34	are	be	AUX
eurjchem-990	84	35	located	locate	VERB
eurjchem-990	84	36	in	in	ADP
eurjchem-990	84	37	the	the	DET
eurjchem-990	84	38	range	range	NOUN
eurjchem-990	84	39	1619‐1630	1619‐1630	NUM
eurjchem-990	84	40	cm‐1	cm‐1	NOUN
eurjchem-990	84	41	.	.	PUNCT
eurjchem-990	85	1	the	the	DET
eurjchem-990	85	2	two	two	NUM
eurjchem-990	85	3	bands	band	NOUN
eurjchem-990	85	4	assigned	assign	VERB
eurjchem-990	85	5	to	to	ADP
eurjchem-990	85	6	δ(c	δ(c	PROPN
eurjchem-990	85	7	=	=	SYM
eurjchem-990	85	8	s	s	PART
eurjchem-990	85	9	)	)	PUNCT
eurjchem-990	85	10	and	and	CCONJ
eurjchem-990	85	11	ν(c	ν(c	PROPN
eurjchem-990	85	12	=	=	SYM
eurjchem-990	85	13	s	s	PART
eurjchem-990	85	14	)	)	PUNCT
eurjchem-990	85	15	appear	appear	VERB
eurjchem-990	85	16	at	at	ADP
eurjchem-990	85	17	the	the	DET
eurjchem-990	85	18	frequencies	frequency	NOUN
eurjchem-990	85	19	1290	1290	NUM
eurjchem-990	85	20	and	and	CCONJ
eurjchem-990	85	21	830	830	NUM
eurjchem-990	85	22	cm‐1	cm‐1	NOUN
eurjchem-990	85	23	respectively	respectively	ADV
eurjchem-990	85	24	[	[	X
eurjchem-990	85	25	31,32	31,32	NUM
eurjchem-990	85	26	]	]	PUNCT
eurjchem-990	85	27	.	.	PUNCT
eurjchem-990	86	1	in	in	ADP
eurjchem-990	86	2	all	all	DET
eurjchem-990	86	3	complexes	complex	NOUN
eurjchem-990	86	4	,	,	PUNCT
eurjchem-990	86	5	these	these	DET
eurjchem-990	86	6	two	two	NUM
eurjchem-990	86	7	bands	band	NOUN
eurjchem-990	86	8	undergo	undergo	VERB
eurjchem-990	86	9	weakness	weakness	NOUN
eurjchem-990	86	10	and	and	CCONJ
eurjchem-990	86	11	shift	shift	VERB
eurjchem-990	86	12	to	to	ADP
eurjchem-990	86	13	lower	low	ADJ
eurjchem-990	86	14	frequencies	frequency	NOUN
eurjchem-990	86	15	appearing	appear	VERB
eurjchem-990	86	16	in	in	ADP
eurjchem-990	86	17	the	the	DET
eurjchem-990	86	18	range	range	NOUN
eurjchem-990	86	19	(	(	PUNCT
eurjchem-990	86	20	1249‐1260	1249‐1260	NOUN
eurjchem-990	86	21	cm‐1	cm‐1	NOUN
eurjchem-990	86	22	)	)	PUNCT
eurjchem-990	86	23	and	and	CCONJ
eurjchem-990	86	24	(	(	PUNCT
eurjchem-990	86	25	802‐810	802‐810	NUM
eurjchem-990	86	26	cm‐1	cm‐1	NOUN
eurjchem-990	86	27	)	)	PUNCT
eurjchem-990	86	28	,	,	PUNCT
eurjchem-990	86	29	respectively	respectively	ADV
eurjchem-990	86	30	,	,	PUNCT
eurjchem-990	86	31	confirming	confirm	VERB
eurjchem-990	86	32	the	the	DET
eurjchem-990	86	33	coordination	coordination	NOUN
eurjchem-990	86	34	via	via	ADP
eurjchem-990	86	35	the	the	DET
eurjchem-990	86	36	thiolate	thiolate	ADJ
eurjchem-990	86	37	sulfur	sulfur	NOUN
eurjchem-990	86	38	atom	atom	NOUN
eurjchem-990	86	39	[	[	X
eurjchem-990	86	40	33,34	33,34	NOUN
eurjchem-990	86	41	]	]	PUNCT
eurjchem-990	86	42	.	.	PUNCT
eurjchem-990	87	1	the	the	DET
eurjchem-990	87	2	ir	ir	PROPN
eurjchem-990	87	3	spectrum	spectrum	NOUN
eurjchem-990	87	4	of	of	ADP
eurjchem-990	87	5	the	the	DET
eurjchem-990	87	6	free	free	PROPN
eurjchem-990	87	7	1,10‐phen	1,10‐phen	PROPN
eurjchem-990	87	8	ligand	ligand	NOUN
eurjchem-990	87	9	shows	show	VERB
eurjchem-990	87	10	a	a	DET
eurjchem-990	87	11	very	very	ADV
eurjchem-990	87	12	stronger	strong	ADJ
eurjchem-990	87	13	bands	band	NOUN
eurjchem-990	87	14	at	at	ADP
eurjchem-990	87	15	~1570	~1570	NUM
eurjchem-990	87	16	cm‐1	cm‐1	NOUN
eurjchem-990	87	17	due	due	ADP
eurjchem-990	87	18	to	to	ADP
eurjchem-990	87	19	stretching	stretch	VERB
eurjchem-990	87	20	frequency	frequency	NOUN
eurjchem-990	87	21	of	of	ADP
eurjchem-990	87	22	>	>	X
eurjchem-990	87	23	c	c	PROPN
eurjchem-990	87	24	=	=	NOUN
eurjchem-990	87	25	n	n	PRON
eurjchem-990	87	26	present	present	ADJ
eurjchem-990	87	27	in	in	ADP
eurjchem-990	87	28	1,10‐phenanthroline	1,10‐phenanthroline	NUM
eurjchem-990	87	29	moiety	moiety	NOUN
eurjchem-990	87	30	.	.	PUNCT
eurjchem-990	88	1	this	this	DET
eurjchem-990	88	2	band	band	NOUN
eurjchem-990	88	3	was	be	AUX
eurjchem-990	88	4	shifted	shift	VERB
eurjchem-990	88	5	to	to	ADP
eurjchem-990	88	6	lower	low	ADJ
eurjchem-990	88	7	frequencies	frequency	NOUN
eurjchem-990	88	8	in	in	ADP
eurjchem-990	88	9	the	the	DET
eurjchem-990	88	10	complexes	complex	NOUN
eurjchem-990	88	11	~16‐24	~16‐24	X
eurjchem-990	88	12	cm‐1	cm‐1	PROPN
eurjchem-990	88	13	,	,	PUNCT
eurjchem-990	88	14	which	which	PRON
eurjchem-990	88	15	clearly	clearly	ADV
eurjchem-990	88	16	indicate	indicate	VERB
eurjchem-990	88	17	that	that	SCONJ
eurjchem-990	88	18	the	the	DET
eurjchem-990	88	19	coordination	coordination	NOUN
eurjchem-990	88	20	of	of	ADP
eurjchem-990	88	21	the	the	DET
eurjchem-990	88	22	two	two	NUM
eurjchem-990	88	23	nitrogen	nitrogen	NOUN
eurjchem-990	88	24	atoms	atom	NOUN
eurjchem-990	88	25	of	of	ADP
eurjchem-990	88	26	the	the	DET
eurjchem-990	88	27	neutral	neutral	ADJ
eurjchem-990	88	28	1,10‐phen	1,10‐phen	PROPN
eurjchem-990	88	29	ligand	ligand	NOUN
eurjchem-990	88	30	to	to	ADP
eurjchem-990	88	31	m(ii	m(ii	NOUN
eurjchem-990	88	32	)	)	PUNCT
eurjchem-990	88	33	ion	ion	NOUN
eurjchem-990	88	34	upon	upon	SCONJ
eurjchem-990	88	35	complexation	complexation	NOUN
eurjchem-990	88	36	[	[	X
eurjchem-990	88	37	32	32	NUM
eurjchem-990	88	38	]	]	PUNCT
eurjchem-990	88	39	.	.	PUNCT
eurjchem-990	89	1	the	the	DET
eurjchem-990	89	2	coordination	coordination	NOUN
eurjchem-990	89	3	positions	position	NOUN
eurjchem-990	89	4	of	of	ADP
eurjchem-990	89	5	the	the	DET
eurjchem-990	89	6	ephc	ephc	NOUN
eurjchem-990	89	7	thiosemi‐	thiosemi‐	PRON
eurjchem-990	89	8	carbazone	carbazone	NOUN
eurjchem-990	89	9	in	in	ADP
eurjchem-990	89	10	the	the	DET
eurjchem-990	89	11	m(ii	m(ii	NOUN
eurjchem-990	89	12	)	)	PUNCT
eurjchem-990	89	13	complexes	complex	NOUN
eurjchem-990	89	14	are	be	AUX
eurjchem-990	89	15	confirmed	confirm	VERB
eurjchem-990	89	16	by	by	ADP
eurjchem-990	89	17	assigning	assign	VERB
eurjchem-990	89	18	the	the	DET
eurjchem-990	89	19	strong	strong	ADJ
eurjchem-990	89	20	bands	band	NOUN
eurjchem-990	89	21	observed	observe	VERB
eurjchem-990	89	22	in	in	ADP
eurjchem-990	89	23	the	the	DET
eurjchem-990	89	24	far	far	PROPN
eurjchem-990	89	25	ir	ir	PROPN
eurjchem-990	89	26	spectra	spectra	NOUN
eurjchem-990	89	27	of	of	ADP
eurjchem-990	89	28	the	the	DET
eurjchem-990	89	29	complexes	complex	NOUN
eurjchem-990	89	30	.	.	PUNCT
eurjchem-990	90	1	the	the	DET
eurjchem-990	90	2	bands	band	NOUN
eurjchem-990	90	3	observed	observe	VERB
eurjchem-990	90	4	at	at	ADP
eurjchem-990	90	5	(	(	PUNCT
eurjchem-990	90	6	430‐444	430‐444	NUM
eurjchem-990	90	7	)	)	PUNCT
eurjchem-990	90	8	and	and	CCONJ
eurjchem-990	90	9	(	(	PUNCT
eurjchem-990	90	10	323‐335	323‐335	NUM
eurjchem-990	90	11	)	)	PUNCT
eurjchem-990	90	12	cm‐1	cm‐1	NOUN
eurjchem-990	90	13	are	be	AUX
eurjchem-990	90	14	assigned	assign	VERB
eurjchem-990	90	15	to	to	ADP
eurjchem-990	90	16	ν(m‐n	ν(m‐n	PROPN
eurjchem-990	90	17	)	)	PUNCT
eurjchem-990	91	1	[	[	X
eurjchem-990	91	2	35	35	NUM
eurjchem-990	91	3	]	]	PUNCT
eurjchem-990	91	4	and	and	CCONJ
eurjchem-990	91	5	ν(m‐s	ν(m‐s	NUM
eurjchem-990	91	6	)	)	PUNCT
eurjchem-990	91	7	as	as	SCONJ
eurjchem-990	91	8	suggested	suggest	VERB
eurjchem-990	91	9	by	by	ADP
eurjchem-990	91	10	lever	lever	NOUN
eurjchem-990	92	1	[	[	X
eurjchem-990	92	2	36	36	NUM
eurjchem-990	92	3	]	]	PUNCT
eurjchem-990	92	4	,	,	PUNCT
eurjchem-990	92	5	respectively	respectively	ADV
eurjchem-990	92	6	.	.	PUNCT
eurjchem-990	93	1	the	the	DET
eurjchem-990	93	2	broad	broad	ADJ
eurjchem-990	93	3	band	band	NOUN
eurjchem-990	93	4	centered	center	VERB
eurjchem-990	93	5	at	at	ADP
eurjchem-990	93	6	3428‐	3428‐	NUM
eurjchem-990	93	7	3460	3460	NUM
eurjchem-990	93	8	cm‐1	cm‐1	NOUN
eurjchem-990	93	9	in	in	ADP
eurjchem-990	93	10	the	the	DET
eurjchem-990	93	11	spectra	spectra	NOUN
eurjchem-990	93	12	of	of	ADP
eurjchem-990	93	13	complexes	complex	NOUN
eurjchem-990	93	14	may	may	AUX
eurjchem-990	93	15	be	be	AUX
eurjchem-990	93	16	due	due	ADJ
eurjchem-990	93	17	to	to	ADP
eurjchem-990	93	18	hydrated	hydrated	ADJ
eurjchem-990	93	19	water	water	NOUN
eurjchem-990	93	20	.	.	PUNCT
eurjchem-990	94	1	in	in	ADP
eurjchem-990	94	2	the	the	DET
eurjchem-990	94	3	literature	literature	NOUN
eurjchem-990	94	4	,	,	PUNCT
eurjchem-990	94	5	the	the	DET
eurjchem-990	94	6	bands	band	NOUN
eurjchem-990	94	7	appearing	appear	VERB
eurjchem-990	94	8	between	between	ADP
eurjchem-990	94	9	160	160	NUM
eurjchem-990	94	10	and	and	CCONJ
eurjchem-990	94	11	300	300	NUM
eurjchem-990	94	12	cm‐1	cm‐1	NOUN
eurjchem-990	94	13	are	be	AUX
eurjchem-990	94	14	allotted	allot	VERB
eurjchem-990	94	15	to	to	ADP
eurjchem-990	94	16	the	the	DET
eurjchem-990	94	17	vibration	vibration	NOUN
eurjchem-990	94	18	of	of	ADP
eurjchem-990	94	19	the	the	DET
eurjchem-990	94	20	m‐x	m‐x	NOUN
eurjchem-990	94	21	bonds	bond	NOUN
eurjchem-990	94	22	where	where	SCONJ
eurjchem-990	94	23	m	m	NOUN
eurjchem-990	94	24	=	=	VERB
eurjchem-990	94	25	metal	metal	NOUN
eurjchem-990	94	26	and	and	CCONJ
eurjchem-990	94	27	x	x	X
eurjchem-990	94	28	=	=	X
eurjchem-990	94	29	cl	cl	NOUN
eurjchem-990	94	30	or	or	CCONJ
eurjchem-990	94	31	br	br	X
eurjchem-990	95	1	[	[	X
eurjchem-990	95	2	37,38	37,38	NOUN
eurjchem-990	95	3	]	]	PUNCT
eurjchem-990	95	4	.	.	PUNCT
eurjchem-990	96	1	in	in	ADP
eurjchem-990	96	2	our	our	PRON
eurjchem-990	96	3	case	case	NOUN
eurjchem-990	96	4	the	the	DET
eurjchem-990	96	5	ν(m‐cl	ν(m‐cl	NOUN
eurjchem-990	96	6	)	)	PUNCT
eurjchem-990	96	7	frequencies	frequency	NOUN
eurjchem-990	96	8	appearing	appear	VERB
eurjchem-990	96	9	between	between	ADP
eurjchem-990	96	10	225‐240	225‐240	PROPN
eurjchem-990	96	11	cm‐1	cm‐1	NOUN
eurjchem-990	96	12	are	be	AUX
eurjchem-990	96	13	in	in	ADP
eurjchem-990	96	14	good	good	ADJ
eurjchem-990	96	15	agreement	agreement	NOUN
eurjchem-990	96	16	with	with	ADP
eurjchem-990	96	17	the	the	DET
eurjchem-990	96	18	reported	report	VERB
eurjchem-990	96	19	values	value	NOUN
eurjchem-990	96	20	in	in	ADP
eurjchem-990	96	21	the	the	DET
eurjchem-990	96	22	literature	literature	NOUN
eurjchem-990	96	23	.	.	PUNCT
eurjchem-990	97	1	based	base	VERB
eurjchem-990	97	2	on	on	ADP
eurjchem-990	97	3	the	the	DET
eurjchem-990	97	4	above	above	ADJ
eurjchem-990	97	5	spectral	spectral	ADJ
eurjchem-990	97	6	evidences	evidence	NOUN
eurjchem-990	97	7	,	,	PUNCT
eurjchem-990	97	8	it	it	PRON
eurjchem-990	97	9	is	be	AUX
eurjchem-990	97	10	confirmed	confirm	VERB
eurjchem-990	97	11	that	that	SCONJ
eurjchem-990	97	12	the	the	DET
eurjchem-990	97	13	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-990	97	14	ligands	ligand	NOUN
eurjchem-990	97	15	lost	lose	VERB
eurjchem-990	97	16	the	the	DET
eurjchem-990	97	17	nh	nh	PROPN
eurjchem-990	97	18	proton	proton	NOUN
eurjchem-990	97	19	attached	attach	VERB
eurjchem-990	97	20	to	to	ADP
eurjchem-990	97	21	c	c	PROPN
eurjchem-990	97	22	=	=	VERB
eurjchem-990	97	23	s	s	X
eurjchem-990	97	24	and	and	CCONJ
eurjchem-990	97	25	coordinated	coordinate	VERB
eurjchem-990	97	26	to	to	ADP
eurjchem-990	97	27	the	the	DET
eurjchem-990	97	28	m(ii	m(ii	NOUN
eurjchem-990	97	29	)	)	PUNCT
eurjchem-990	97	30	ion	ion	NOUN
eurjchem-990	97	31	as	as	ADP
eurjchem-990	97	32	mononegative	mononegative	ADJ
eurjchem-990	97	33	tridentate	tridentate	NOUN
eurjchem-990	97	34	anion	anion	NOUN
eurjchem-990	97	35	,	,	PUNCT
eurjchem-990	97	36	coordinating	coordinate	VERB
eurjchem-990	97	37	via	via	ADP
eurjchem-990	97	38	the	the	DET
eurjchem-990	97	39	azomethine	azomethine	NOUN
eurjchem-990	97	40	and	and	CCONJ
eurjchem-990	97	41	pyridine	pyridine	ADJ
eurjchem-990	97	42	nitrogen	nitrogen	NOUN
eurjchem-990	97	43	atoms	atom	NOUN
eurjchem-990	97	44	and	and	CCONJ
eurjchem-990	97	45	the	the	DET
eurjchem-990	97	46	thiolate	thiolate	ADJ
eurjchem-990	97	47	sulfur	sulfur	NOUN
eurjchem-990	97	48	atom	atom	NOUN
eurjchem-990	97	49	after	after	ADP
eurjchem-990	97	50	deprotonation	deprotonation	NOUN
eurjchem-990	97	51	.	.	PUNCT
eurjchem-990	98	1	3.2	3.2	NUM
eurjchem-990	98	2	.	.	PUNCT
eurjchem-990	98	3	electronic	electronic	ADJ
eurjchem-990	98	4	spectra	spectra	NOUN
eurjchem-990	98	5	the	the	DET
eurjchem-990	98	6	probable	probable	ADJ
eurjchem-990	98	7	assignments	assignment	NOUN
eurjchem-990	98	8	for	for	ADP
eurjchem-990	98	9	the	the	DET
eurjchem-990	98	10	bands	band	NOUN
eurjchem-990	98	11	in	in	ADP
eurjchem-990	98	12	the	the	DET
eurjchem-990	98	13	region	region	NOUN
eurjchem-990	98	14	28150	28150	NUM
eurjchem-990	98	15	and	and	CCONJ
eurjchem-990	98	16	33242	33242	NUM
eurjchem-990	98	17	cm‐1	cm‐1	NOUN
eurjchem-990	98	18	are	be	AUX
eurjchem-990	98	19	due	due	ADJ
eurjchem-990	98	20	to	to	ADP
eurjchem-990	98	21	the	the	DET
eurjchem-990	98	22	n	n	NOUN
eurjchem-990	98	23	→	→	SYM
eurjchem-990	98	24	π	π	PROPN
eurjchem-990	98	25	*	*	PUNCT
eurjchem-990	98	26	and	and	CCONJ
eurjchem-990	98	27	π	π	PROPN
eurjchem-990	98	28	→	→	SYM
eurjchem-990	98	29	π	π	PROPN
eurjchem-990	98	30	*	*	NOUN
eurjchem-990	98	31	transitions	transition	NOUN
eurjchem-990	98	32	of	of	ADP
eurjchem-990	98	33	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-990	98	34	compound	compound	NOUN
eurjchem-990	98	35	respectively	respectively	ADV
eurjchem-990	98	36	.	.	PUNCT
eurjchem-990	99	1	always	always	ADV
eurjchem-990	99	2	n	n	PROPN
eurjchem-990	99	3	→	→	SYM
eurjchem-990	99	4	π	π	PROPN
eurjchem-990	99	5	*	*	NOUN
eurjchem-990	99	6	transitions	transition	NOUN
eurjchem-990	99	7	occurs	occur	VERB
eurjchem-990	99	8	at	at	ADP
eurjchem-990	99	9	a	a	DET
eurjchem-990	99	10	lower	low	ADJ
eurjchem-990	99	11	energy	energy	NOUN
eurjchem-990	99	12	than	than	ADP
eurjchem-990	99	13	π	π	PROPN
eurjchem-990	99	14	→	→	SYM
eurjchem-990	99	15	π	π	PROPN
eurjchem-990	99	16	*	*	NOUN
eurjchem-990	99	17	transitions	transition	NOUN
eurjchem-990	99	18	[	[	X
eurjchem-990	99	19	39	39	NUM
eurjchem-990	99	20	]	]	PUNCT
eurjchem-990	99	21	.	.	PUNCT
eurjchem-990	100	1	in	in	ADP
eurjchem-990	100	2	the	the	DET
eurjchem-990	100	3	spectra	spectra	NOUN
eurjchem-990	100	4	of	of	ADP
eurjchem-990	100	5	m(ii	m(ii	PROPN
eurjchem-990	100	6	)	)	PUNCT
eurjchem-990	100	7	complexes	complexe	VERB
eurjchem-990	100	8	the	the	DET
eurjchem-990	100	9	bands	band	NOUN
eurjchem-990	100	10	observed	observe	VERB
eurjchem-990	100	11	in	in	ADP
eurjchem-990	100	12	the	the	DET
eurjchem-990	100	13	region	region	NOUN
eurjchem-990	100	14	27320‐27880	27320‐27880	NUM
eurjchem-990	100	15	cm‐1	cm‐1	NOUN
eurjchem-990	100	16	are	be	AUX
eurjchem-990	100	17	assigned	assign	VERB
eurjchem-990	100	18	to	to	ADP
eurjchem-990	100	19	s	s	PROPN
eurjchem-990	100	20	→	→	SYM
eurjchem-990	100	21	m	m	NOUN
eurjchem-990	100	22	charge‐transfer	charge‐transfer	NOUN
eurjchem-990	100	23	band	band	NOUN
eurjchem-990	101	1	[	[	X
eurjchem-990	101	2	40	40	NUM
eurjchem-990	101	3	]	]	PUNCT
eurjchem-990	101	4	.	.	PUNCT
eurjchem-990	102	1	the	the	DET
eurjchem-990	102	2	bands	band	NOUN
eurjchem-990	102	3	in	in	ADP
eurjchem-990	102	4	the	the	DET
eurjchem-990	102	5	range	range	NOUN
eurjchem-990	102	6	31260‐	31260‐	NUM
eurjchem-990	102	7	31588	31588	NUM
eurjchem-990	102	8	cm‐1	cm‐1	NOUN
eurjchem-990	102	9	observed	observe	VERB
eurjchem-990	102	10	in	in	ADP
eurjchem-990	102	11	the	the	DET
eurjchem-990	102	12	spectra	spectra	NOUN
eurjchem-990	102	13	of	of	ADP
eurjchem-990	102	14	all	all	DET
eurjchem-990	102	15	m(ii	m(ii	NOUN
eurjchem-990	102	16	)	)	PUNCT
eurjchem-990	102	17	complexes	complex	NOUN
eurjchem-990	102	18	are	be	AUX
eurjchem-990	102	19	assigned	assign	VERB
eurjchem-990	102	20	as	as	ADP
eurjchem-990	102	21	cl	cl	NOUN
eurjchem-990	102	22	→	→	SYM
eurjchem-990	102	23	m	m	NOUN
eurjchem-990	102	24	charge‐transfer	charge‐transfer	NOUN
eurjchem-990	102	25	transitions	transition	NOUN
eurjchem-990	102	26	[	[	X
eurjchem-990	102	27	41	41	NUM
eurjchem-990	102	28	]	]	PUNCT
eurjchem-990	102	29	.	.	PUNCT
eurjchem-990	103	1	the	the	DET
eurjchem-990	103	2	shift	shift	NOUN
eurjchem-990	103	3	of	of	ADP
eurjchem-990	103	4	the	the	DET
eurjchem-990	103	5	π	π	PROPN
eurjchem-990	103	6	→	→	SYM
eurjchem-990	103	7	π	π	PROPN
eurjchem-990	103	8	*	*	NOUN
eurjchem-990	103	9	bands	band	NOUN
eurjchem-990	103	10	to	to	ADP
eurjchem-990	103	11	the	the	DET
eurjchem-990	103	12	longer	long	ADJ
eurjchem-990	103	13	wavelength	wavelength	NOUN
eurjchem-990	103	14	region	region	NOUN
eurjchem-990	103	15	is	be	AUX
eurjchem-990	103	16	the	the	DET
eurjchem-990	103	17	result	result	NOUN
eurjchem-990	103	18	of	of	ADP
eurjchem-990	103	19	the	the	DET
eurjchem-990	103	20	c	c	AUX
eurjchem-990	103	21	=	=	NOUN
eurjchem-990	103	22	s	s	PART
eurjchem-990	103	23	bond	bond	NOUN
eurjchem-990	103	24	being	be	AUX
eurjchem-990	103	25	weakened	weaken	VERB
eurjchem-990	103	26	and	and	CCONJ
eurjchem-990	103	27	conjugation	conjugation	NOUN
eurjchem-990	103	28	system	system	NOUN
eurjchem-990	103	29	being	be	AUX
eurjchem-990	103	30	enhanced	enhance	VERB
eurjchem-990	103	31	after	after	ADP
eurjchem-990	103	32	the	the	DET
eurjchem-990	103	33	formation	formation	NOUN
eurjchem-990	103	34	of	of	ADP
eurjchem-990	103	35	the	the	DET
eurjchem-990	103	36	complex	complex	NOUN
eurjchem-990	103	37	[	[	X
eurjchem-990	103	38	42	42	NUM
eurjchem-990	103	39	]	]	PUNCT
eurjchem-990	103	40	.	.	PUNCT
eurjchem-990	104	1	the	the	DET
eurjchem-990	104	2	magnetic	magnetic	ADJ
eurjchem-990	104	3	moment	moment	NOUN
eurjchem-990	104	4	of	of	ADP
eurjchem-990	104	5	mn(ii	mn(ii	NOUN
eurjchem-990	104	6	)	)	PUNCT
eurjchem-990	104	7	complex	complex	NOUN
eurjchem-990	104	8	(	(	PUNCT
eurjchem-990	104	9	6.11	6.11	NUM
eurjchem-990	104	10	b.m	b.m	NOUN
eurjchem-990	104	11	.	.	PROPN
eurjchem-990	104	12	)	)	PUNCT
eurjchem-990	104	13	is	be	AUX
eurjchem-990	104	14	corresponding	correspond	VERB
eurjchem-990	104	15	to	to	ADP
eurjchem-990	104	16	five	five	NUM
eurjchem-990	104	17	unpaired	unpaired	ADJ
eurjchem-990	104	18	electrons	electron	NOUN
eurjchem-990	104	19	,	,	PUNCT
eurjchem-990	104	20	as	as	SCONJ
eurjchem-990	104	21	expected	expect	VERB
eurjchem-990	104	22	for	for	ADP
eurjchem-990	104	23	high	high	ADJ
eurjchem-990	104	24	spin	spin	NOUN
eurjchem-990	104	25	3d5	3d5	NUM
eurjchem-990	104	26	system	system	NOUN
eurjchem-990	104	27	[	[	X
eurjchem-990	104	28	43	43	NUM
eurjchem-990	104	29	]	]	PUNCT
eurjchem-990	104	30	.	.	PUNCT
eurjchem-990	105	1	the	the	DET
eurjchem-990	105	2	electronic	electronic	ADJ
eurjchem-990	105	3	spectrum	spectrum	NOUN
eurjchem-990	105	4	of	of	ADP
eurjchem-990	105	5	this	this	DET
eurjchem-990	105	6	complex	complex	ADJ
eurjchem-990	105	7	show	show	VERB
eurjchem-990	105	8	two	two	NUM
eurjchem-990	105	9	bands	band	NOUN
eurjchem-990	105	10	at	at	ADP
eurjchem-990	105	11	20,250	20,250	NUM
eurjchem-990	105	12	and	and	CCONJ
eurjchem-990	105	13	24,850	24,850	NUM
eurjchem-990	105	14	cm‐1	cm‐1	NOUN
eurjchem-990	105	15	attributable	attributable	ADJ
eurjchem-990	105	16	to	to	ADP
eurjchem-990	105	17	6a1	6a1	NUM
eurjchem-990	105	18	g	g	NOUN
eurjchem-990	105	19	→	→	SYM
eurjchem-990	105	20	6t1g(g	6t1g(g	NUM
eurjchem-990	105	21	)	)	PUNCT
eurjchem-990	105	22	and	and	CCONJ
eurjchem-990	105	23	6a1	6a1	NUM
eurjchem-990	105	24	g	g	NOUN
eurjchem-990	105	25	→	→	SYM
eurjchem-990	105	26	6t2g(g	6t2g(g	NUM
eurjchem-990	105	27	)	)	PUNCT
eurjchem-990	105	28	,	,	PUNCT
eurjchem-990	105	29	respectively	respectively	ADV
eurjchem-990	105	30	,	,	PUNCT
eurjchem-990	105	31	suggesting	suggest	VERB
eurjchem-990	105	32	an	an	DET
eurjchem-990	105	33	octahedral	octahedral	ADJ
eurjchem-990	105	34	structure	structure	NOUN
eurjchem-990	105	35	[	[	X
eurjchem-990	105	36	43	43	NUM
eurjchem-990	105	37	]	]	PUNCT
eurjchem-990	105	38	.	.	PUNCT
eurjchem-990	106	1	the	the	DET
eurjchem-990	106	2	co(ii	co(ii	PROPN
eurjchem-990	106	3	)	)	PUNCT
eurjchem-990	106	4	complexes	complex	NOUN
eurjchem-990	106	5	generally	generally	ADV
eurjchem-990	106	6	give	give	VERB
eurjchem-990	106	7	rise	rise	NOUN
eurjchem-990	106	8	to	to	ADP
eurjchem-990	106	9	three	three	NUM
eurjchem-990	106	10	absorption	absorption	NOUN
eurjchem-990	106	11	bands	band	NOUN
eurjchem-990	106	12	in	in	ADP
eurjchem-990	106	13	the	the	DET
eurjchem-990	106	14	visible	visible	ADJ
eurjchem-990	106	15	region	region	NOUN
eurjchem-990	106	16	under	under	ADP
eurjchem-990	106	17	the	the	DET
eurjchem-990	106	18	influence	influence	NOUN
eurjchem-990	106	19	of	of	ADP
eurjchem-990	106	20	the	the	DET
eurjchem-990	106	21	octahedral	octahedral	ADJ
eurjchem-990	106	22	field	field	NOUN
eurjchem-990	106	23	by	by	ADP
eurjchem-990	106	24	the	the	DET
eurjchem-990	106	25	excitation	excitation	NOUN
eurjchem-990	106	26	of	of	ADP
eurjchem-990	106	27	the	the	DET
eurjchem-990	106	28	electron	electron	NOUN
eurjchem-990	106	29	from	from	ADP
eurjchem-990	106	30	the	the	DET
eurjchem-990	106	31	ground	ground	NOUN
eurjchem-990	106	32	state	state	NOUN
eurjchem-990	106	33	4t1	4t1	NUM
eurjchem-990	106	34	g	g	NOUN
eurjchem-990	106	35	(	(	PUNCT
eurjchem-990	106	36	f	f	NOUN
eurjchem-990	106	37	)	)	PUNCT
eurjchem-990	106	38	to	to	ADP
eurjchem-990	106	39	the	the	DET
eurjchem-990	106	40	excited	excited	ADJ
eurjchem-990	106	41	states	state	NOUN
eurjchem-990	107	1	4t2	4t2	NUM
eurjchem-990	107	2	g	g	NOUN
eurjchem-990	107	3	(	(	PUNCT
eurjchem-990	107	4	f	f	PROPN
eurjchem-990	107	5	)	)	PUNCT
eurjchem-990	107	6	,	,	PUNCT
eurjchem-990	107	7	4a2	4a2	NUM
eurjchem-990	107	8	g	g	NOUN
eurjchem-990	107	9	(	(	PUNCT
eurjchem-990	107	10	f	f	NOUN
eurjchem-990	107	11	)	)	PUNCT
eurjchem-990	107	12	and	and	CCONJ
eurjchem-990	107	13	4t1	4t1	NUM
eurjchem-990	107	14	g	g	NOUN
eurjchem-990	107	15	(	(	PUNCT
eurjchem-990	107	16	p	p	NOUN
eurjchem-990	107	17	)	)	PUNCT
eurjchem-990	107	18	.	.	PUNCT
eurjchem-990	108	1	mohamed	mohamed	PROPN
eurjchem-990	108	2	et	et	PROPN
eurjchem-990	108	3	al	al	PROPN
eurjchem-990	108	4	.	.	PUNCT
eurjchem-990	108	5	/	/	SYM
eurjchem-990	108	6	european	european	PROPN
eurjchem-990	108	7	journal	journal	PROPN
eurjchem-990	108	8	of	of	ADP
eurjchem-990	108	9	chemistry	chemistry	NOUN
eurjchem-990	108	10	5	5	NUM
eurjchem-990	108	11	(	(	PUNCT
eurjchem-990	108	12	2	2	NUM
eurjchem-990	108	13	)	)	PUNCT
eurjchem-990	108	14	(	(	PUNCT
eurjchem-990	108	15	2014	2014	NUM
eurjchem-990	108	16	)	)	PUNCT
eurjchem-990	108	17	252‐259	252‐259	NOUN
eurjchem-990	108	18	255	255	NUM
eurjchem-990	108	19	table	table	NOUN
eurjchem-990	108	20	3	3	NUM
eurjchem-990	108	21	.	.	PUNCT
eurjchem-990	108	22	molar	molar	ADJ
eurjchem-990	108	23	conductance	conductance	NOUN
eurjchem-990	108	24	,	,	PUNCT
eurjchem-990	108	25	magnetic	magnetic	ADJ
eurjchem-990	108	26	moment	moment	NOUN
eurjchem-990	108	27	and	and	CCONJ
eurjchem-990	108	28	electronic	electronic	ADJ
eurjchem-990	108	29	spectral	spectral	ADJ
eurjchem-990	108	30	data	datum	NOUN
eurjchem-990	108	31	(	(	PUNCT
eurjchem-990	108	32	cm‐1	cm‐1	NOUN
eurjchem-990	108	33	)	)	PUNCT
eurjchem-990	108	34	of	of	ADP
eurjchem-990	108	35	the	the	DET
eurjchem-990	108	36	complexes	complex	NOUN
eurjchem-990	108	37	.	.	PUNCT
eurjchem-990	109	1	compounds	compound	NOUN
eurjchem-990	109	2	λma	λma	VERB
eurjchem-990	109	3	µeff	µeff	NOUN
eurjchem-990	109	4	.	.	PUNCT
eurjchem-990	110	1	(	(	PUNCT
eurjchem-990	110	2	b.m	b.m	PROPN
eurjchem-990	110	3	.	.	PUNCT
eurjchem-990	110	4	)	)	PUNCT
eurjchem-990	111	1	d‐d	d‐d	NUM
eurjchem-990	111	2	transitions	transition	NOUN
eurjchem-990	111	3	[	[	X
eurjchem-990	111	4	cu(ephc)(1,10‐phen)cl	cu(ephc)(1,10‐phen)cl	X
eurjchem-990	111	5	]	]	X
eurjchem-990	111	6	(	(	PUNCT
eurjchem-990	111	7	1	1	NUM
eurjchem-990	111	8	)	)	PUNCT
eurjchem-990	111	9	3.15	3.15	NUM
eurjchem-990	111	10	1.82	1.82	NUM
eurjchem-990	111	11	14585	14585	NUM
eurjchem-990	111	12	2b1g→2eg	2b1g→2eg	NUM
eurjchem-990	111	13	[	[	X
eurjchem-990	111	14	ni(ephc)(1,10‐phen)cl	ni(ephc)(1,10‐phen)cl	X
eurjchem-990	111	15	]	]	X
eurjchem-990	111	16	(	(	PUNCT
eurjchem-990	111	17	2	2	X
eurjchem-990	111	18	)	)	PUNCT
eurjchem-990	111	19	4.99	4.99	NUM
eurjchem-990	111	20	3.11	3.11	NUM
eurjchem-990	111	21	10265	10265	NUM
eurjchem-990	111	22	16940	16940	NUM
eurjchem-990	111	23	3a2g→3t1g(f	3a2g→3t1g(f	NUM
eurjchem-990	111	24	)	)	PUNCT
eurjchem-990	111	25	3a2g→3t1g(p	3a2g→3t1g(p	NUM
eurjchem-990	111	26	)	)	PUNCT
eurjchem-990	112	1	[	[	X
eurjchem-990	112	2	co(ephc)(1,10‐phen)cl].h2o	co(ephc)(1,10‐phen)cl].h2o	NOUN
eurjchem-990	112	3	(	(	PUNCT
eurjchem-990	112	4	3	3	NUM
eurjchem-990	112	5	)	)	PUNCT
eurjchem-990	112	6	5.35	5.35	NUM
eurjchem-990	112	7	4.63	4.63	NUM
eurjchem-990	112	8	9725	9725	NUM
eurjchem-990	112	9	21010	21010	NUM
eurjchem-990	112	10	4t1g(f	4t1g(f	NUM
eurjchem-990	112	11	)	)	PUNCT
eurjchem-990	112	12	→4t2g(f	→4t2g(f	NUM
eurjchem-990	112	13	)	)	PUNCT
eurjchem-990	112	14	4t1g(f	4t1g(f	NUM
eurjchem-990	112	15	)	)	PUNCT
eurjchem-990	112	16	→4t1g(p	→4t1g(p	PUNCT
eurjchem-990	112	17	)	)	PUNCT
eurjchem-990	113	1	[	[	X
eurjchem-990	113	2	mn(ephc)(1,10‐phen)cl].h2o	mn(ephc)(1,10‐phen)cl].h2o	X
eurjchem-990	113	3	(	(	PUNCT
eurjchem-990	113	4	4	4	NUM
eurjchem-990	113	5	)	)	PUNCT
eurjchem-990	113	6	6.97	6.97	NUM
eurjchem-990	113	7	6.11	6.11	NUM
eurjchem-990	113	8	20250	20250	NUM
eurjchem-990	113	9	24850	24850	NUM
eurjchem-990	113	10	6a1	6a1	NUM
eurjchem-990	113	11	g	g	PROPN
eurjchem-990	113	12	→	→	SYM
eurjchem-990	113	13	6t1g(g	6t1g(g	NUM
eurjchem-990	113	14	)	)	PUNCT
eurjchem-990	113	15	6a1	6a1	NUM
eurjchem-990	113	16	g	g	NOUN
eurjchem-990	113	17	→	→	SYM
eurjchem-990	113	18	6t2g(g	6t2g(g	NOUN
eurjchem-990	113	19	)	)	PUNCT
eurjchem-990	114	1	a	a	DET
eurjchem-990	114	2	molar	molar	ADJ
eurjchem-990	114	3	conductance	conductance	NOUN
eurjchem-990	114	4	measured	measure	VERB
eurjchem-990	114	5	for	for	ADP
eurjchem-990	114	6	10‐3	10‐3	NUM
eurjchem-990	114	7	m	m	PROPN
eurjchem-990	114	8	dmso	dmso	NOUN
eurjchem-990	114	9	solution	solution	NOUN
eurjchem-990	114	10	,	,	PUNCT
eurjchem-990	114	11	ω‐1	ω‐1	DET
eurjchem-990	114	12	cm2	cm2	NOUN
eurjchem-990	114	13	mol‐1	mol‐1	NOUN
eurjchem-990	114	14	.	.	PUNCT
eurjchem-990	115	1	in	in	ADP
eurjchem-990	115	2	the	the	DET
eurjchem-990	115	3	co(ii	co(ii	ADJ
eurjchem-990	115	4	)	)	PUNCT
eurjchem-990	115	5	complex	complex	NOUN
eurjchem-990	115	6	,	,	PUNCT
eurjchem-990	115	7	only	only	ADV
eurjchem-990	115	8	two	two	NUM
eurjchem-990	115	9	bands	band	NOUN
eurjchem-990	115	10	are	be	AUX
eurjchem-990	115	11	observed	observe	VERB
eurjchem-990	115	12	at	at	ADP
eurjchem-990	115	13	9725	9725	NUM
eurjchem-990	115	14	cm–1	cm–1	CCONJ
eurjchem-990	115	15	4t1g(f	4t1g(f	NUM
eurjchem-990	115	16	)	)	PUNCT
eurjchem-990	116	1	→	→	SYM
eurjchem-990	116	2	4t2g(f	4t2g(f	NUM
eurjchem-990	116	3	)	)	PUNCT
eurjchem-990	116	4	(	(	PUNCT
eurjchem-990	116	5	1	1	PROPN
eurjchem-990	116	6	)	)	PUNCT
eurjchem-990	116	7	and	and	CCONJ
eurjchem-990	116	8	21,010	21,010	NUM
eurjchem-990	116	9	cm–1	cm–1	SYM
eurjchem-990	116	10	4t1g(f	4t1g(f	NUM
eurjchem-990	116	11	)	)	PUNCT
eurjchem-990	116	12	→	→	SYM
eurjchem-990	116	13	4t1g(p	4t1g(p	NUM
eurjchem-990	116	14	)	)	PUNCT
eurjchem-990	116	15	(	(	PUNCT
eurjchem-990	116	16	3	3	PROPN
eurjchem-990	116	17	)	)	PUNCT
eurjchem-990	116	18	as	as	SCONJ
eurjchem-990	116	19	reported	report	VERB
eurjchem-990	116	20	in	in	ADP
eurjchem-990	116	21	many	many	ADJ
eurjchem-990	116	22	octahedral	octahedral	ADJ
eurjchem-990	116	23	cobalt(ii	cobalt(ii	ADJ
eurjchem-990	116	24	)	)	PUNCT
eurjchem-990	116	25	complexes	complex	NOUN
eurjchem-990	116	26	[	[	X
eurjchem-990	116	27	44,45	44,45	X
eurjchem-990	116	28	]	]	X
eurjchem-990	116	29	.	.	PUNCT
eurjchem-990	117	1	the	the	DET
eurjchem-990	117	2	ν2	ν2	PROPN
eurjchem-990	117	3	transition	transition	NOUN
eurjchem-990	117	4	was	be	AUX
eurjchem-990	117	5	not	not	PART
eurjchem-990	117	6	observed	observe	VERB
eurjchem-990	117	7	due	due	ADJ
eurjchem-990	117	8	to	to	ADP
eurjchem-990	117	9	very	very	ADV
eurjchem-990	117	10	weak	weak	ADJ
eurjchem-990	117	11	intensity	intensity	NOUN
eurjchem-990	117	12	.	.	PUNCT
eurjchem-990	118	1	the	the	DET
eurjchem-990	118	2	value	value	NOUN
eurjchem-990	118	3	of	of	ADP
eurjchem-990	118	4	the	the	DET
eurjchem-990	118	5	magnetic	magnetic	ADJ
eurjchem-990	118	6	moment	moment	NOUN
eurjchem-990	118	7	4.63	4.63	NUM
eurjchem-990	118	8	b.m	b.m	PROPN
eurjchem-990	118	9	.	.	PUNCT
eurjchem-990	119	1	(	(	PUNCT
eurjchem-990	119	2	normal	normal	ADJ
eurjchem-990	119	3	range	range	NOUN
eurjchem-990	119	4	for	for	ADP
eurjchem-990	119	5	octahedral	octahedral	ADJ
eurjchem-990	119	6	co(ii	co(ii	PROPN
eurjchem-990	119	7	)	)	PUNCT
eurjchem-990	119	8	complexes	complex	NOUN
eurjchem-990	119	9	is	be	AUX
eurjchem-990	119	10	4.3‐5.2	4.3‐5.2	NUM
eurjchem-990	119	11	b.m	b.m	PROPN
eurjchem-990	119	12	.	.	PUNCT
eurjchem-990	119	13	)	)	PUNCT
eurjchem-990	120	1	is	be	AUX
eurjchem-990	120	2	an	an	DET
eurjchem-990	120	3	additional	additional	ADJ
eurjchem-990	120	4	evidence	evidence	NOUN
eurjchem-990	120	5	for	for	ADP
eurjchem-990	120	6	an	an	DET
eurjchem-990	120	7	octahedral	octahedral	ADJ
eurjchem-990	120	8	geometry	geometry	NOUN
eurjchem-990	120	9	around	around	ADP
eurjchem-990	120	10	the	the	DET
eurjchem-990	120	11	co(ii	co(ii	PROPN
eurjchem-990	120	12	)	)	PUNCT
eurjchem-990	120	13	ion	ion	NOUN
eurjchem-990	120	14	[	[	X
eurjchem-990	120	15	46	46	NUM
eurjchem-990	120	16	]	]	PUNCT
eurjchem-990	120	17	.	.	PUNCT
eurjchem-990	121	1	the	the	DET
eurjchem-990	121	2	copper(ii	copper(ii	NOUN
eurjchem-990	121	3	)	)	PUNCT
eurjchem-990	121	4	complex	complex	ADJ
eurjchem-990	121	5	exhibit	exhibit	NOUN
eurjchem-990	121	6	magnetic	magnetic	ADJ
eurjchem-990	121	7	moment	moment	NOUN
eurjchem-990	121	8	of	of	ADP
eurjchem-990	121	9	1.82	1.82	NUM
eurjchem-990	121	10	b.m	b.m	NOUN
eurjchem-990	121	11	.	.	PUNCT
eurjchem-990	121	12	at	at	ADP
eurjchem-990	121	13	room	room	NOUN
eurjchem-990	121	14	temperature	temperature	NOUN
eurjchem-990	121	15	.	.	PUNCT
eurjchem-990	122	1	this	this	DET
eurjchem-990	122	2	value	value	NOUN
eurjchem-990	122	3	is	be	AUX
eurjchem-990	122	4	quite	quite	ADV
eurjchem-990	122	5	close	close	ADJ
eurjchem-990	122	6	to	to	ADP
eurjchem-990	122	7	the	the	DET
eurjchem-990	122	8	spin	spin	NOUN
eurjchem-990	122	9	allowed	allow	VERB
eurjchem-990	122	10	values	value	NOUN
eurjchem-990	122	11	expected	expect	VERB
eurjchem-990	122	12	for	for	ADP
eurjchem-990	122	13	a	a	DET
eurjchem-990	122	14	s	s	NOUN
eurjchem-990	122	15	=	=	SYM
eurjchem-990	122	16	1/2	1/2	NUM
eurjchem-990	122	17	system	system	NOUN
eurjchem-990	122	18	and	and	CCONJ
eurjchem-990	122	19	may	may	AUX
eurjchem-990	122	20	be	be	AUX
eurjchem-990	122	21	indicative	indicative	ADJ
eurjchem-990	122	22	of	of	ADP
eurjchem-990	122	23	a	a	DET
eurjchem-990	122	24	distorted	distorted	ADJ
eurjchem-990	122	25	octahedral	octahedral	ADJ
eurjchem-990	122	26	geometry	geometry	NOUN
eurjchem-990	122	27	around	around	ADP
eurjchem-990	122	28	copper(ii	copper(ii	PROPN
eurjchem-990	122	29	)	)	PUNCT
eurjchem-990	122	30	ion	ion	NOUN
eurjchem-990	122	31	.	.	PUNCT
eurjchem-990	123	1	this	this	DET
eurjchem-990	123	2	copper(ii	copper(ii	NOUN
eurjchem-990	123	3	)	)	PUNCT
eurjchem-990	123	4	complex	complex	NOUN
eurjchem-990	123	5	displays	display	VERB
eurjchem-990	123	6	a	a	DET
eurjchem-990	123	7	broad	broad	ADJ
eurjchem-990	123	8	band	band	NOUN
eurjchem-990	123	9	at	at	ADP
eurjchem-990	123	10	14,585	14,585	NUM
eurjchem-990	123	11	cm‐1	cm‐1	NOUN
eurjchem-990	123	12	due	due	ADP
eurjchem-990	123	13	to	to	ADP
eurjchem-990	123	14	2b1	2b1	NUM
eurjchem-990	123	15	g	g	NOUN
eurjchem-990	123	16	→	→	SYM
eurjchem-990	123	17	2eg	2eg	NOUN
eurjchem-990	123	18	assigned	assign	VERB
eurjchem-990	123	19	to	to	ADP
eurjchem-990	123	20	d‐d	d‐d	PRON
eurjchem-990	123	21	transitions	transition	NOUN
eurjchem-990	123	22	of	of	ADP
eurjchem-990	123	23	a	a	DET
eurjchem-990	123	24	distorted	distorted	ADJ
eurjchem-990	123	25	octahedral	octahedral	ADJ
eurjchem-990	123	26	environment	environment	NOUN
eurjchem-990	123	27	[	[	X
eurjchem-990	123	28	47,48	47,48	NUM
eurjchem-990	123	29	]	]	X
eurjchem-990	123	30	.	.	PUNCT
eurjchem-990	124	1	the	the	DET
eurjchem-990	124	2	electronic	electronic	ADJ
eurjchem-990	124	3	spectra	spectra	NOUN
eurjchem-990	124	4	of	of	ADP
eurjchem-990	124	5	the	the	DET
eurjchem-990	124	6	nickel(ii	nickel(ii	NOUN
eurjchem-990	124	7	)	)	PUNCT
eurjchem-990	124	8	complexes	complex	NOUN
eurjchem-990	124	9	exhibited	exhibit	VERB
eurjchem-990	124	10	absorption	absorption	NOUN
eurjchem-990	124	11	bands	band	NOUN
eurjchem-990	124	12	at	at	ADP
eurjchem-990	124	13	10,265	10,265	NUM
eurjchem-990	124	14	and	and	CCONJ
eurjchem-990	124	15	16,940	16,940	NUM
eurjchem-990	124	16	cm‐1	cm‐1	NOUN
eurjchem-990	124	17	,	,	PUNCT
eurjchem-990	124	18	attributable	attributable	ADJ
eurjchem-990	124	19	to	to	ADP
eurjchem-990	124	20	3a2	3a2	NUM
eurjchem-990	124	21	g	g	NOUN
eurjchem-990	124	22	→	→	SYM
eurjchem-990	124	23	3t1g(f	3t1g(f	NUM
eurjchem-990	124	24	)	)	PUNCT
eurjchem-990	124	25	and	and	CCONJ
eurjchem-990	124	26	3a2	3a2	NUM
eurjchem-990	124	27	g	g	NOUN
eurjchem-990	124	28	→	→	SYM
eurjchem-990	124	29	3t1g(p	3t1g(p	NUM
eurjchem-990	124	30	)	)	PUNCT
eurjchem-990	124	31	,	,	PUNCT
eurjchem-990	124	32	transitions	transition	NOUN
eurjchem-990	124	33	,	,	PUNCT
eurjchem-990	124	34	respectively	respectively	ADV
eurjchem-990	124	35	,	,	PUNCT
eurjchem-990	124	36	in	in	ADP
eurjchem-990	124	37	an	an	DET
eurjchem-990	124	38	octahedral	octahedral	ADJ
eurjchem-990	124	39	geometry	geometry	NOUN
eurjchem-990	124	40	[	[	X
eurjchem-990	124	41	44,48	44,48	NOUN
eurjchem-990	124	42	]	]	PUNCT
eurjchem-990	124	43	.	.	PUNCT
eurjchem-990	125	1	also	also	ADV
eurjchem-990	125	2	,	,	PUNCT
eurjchem-990	125	3	the	the	DET
eurjchem-990	125	4	value	value	NOUN
eurjchem-990	125	5	of	of	ADP
eurjchem-990	125	6	the	the	DET
eurjchem-990	125	7	magnetic	magnetic	ADJ
eurjchem-990	125	8	moment	moment	NOUN
eurjchem-990	125	9	(	(	PUNCT
eurjchem-990	125	10	3.11	3.11	NUM
eurjchem-990	125	11	b.m	b.m	NOUN
eurjchem-990	125	12	.	.	PROPN
eurjchem-990	125	13	)	)	PUNCT
eurjchem-990	125	14	may	may	AUX
eurjchem-990	125	15	be	be	AUX
eurjchem-990	125	16	taken	take	VERB
eurjchem-990	125	17	as	as	ADP
eurjchem-990	125	18	additional	additional	ADJ
eurjchem-990	125	19	evidence	evidence	NOUN
eurjchem-990	125	20	for	for	ADP
eurjchem-990	125	21	their	their	PRON
eurjchem-990	125	22	octahedral	octahedral	ADJ
eurjchem-990	125	23	structure	structure	NOUN
eurjchem-990	125	24	.	.	PUNCT
eurjchem-990	126	1	on	on	ADP
eurjchem-990	126	2	the	the	DET
eurjchem-990	126	3	basis	basis	NOUN
eurjchem-990	126	4	of	of	ADP
eurjchem-990	126	5	the	the	DET
eurjchem-990	126	6	above	above	ADJ
eurjchem-990	126	7	observations	observation	NOUN
eurjchem-990	126	8	,	,	PUNCT
eurjchem-990	126	9	it	it	PRON
eurjchem-990	126	10	is	be	AUX
eurjchem-990	126	11	tentatively	tentatively	ADV
eurjchem-990	126	12	suggested	suggest	VERB
eurjchem-990	126	13	that	that	SCONJ
eurjchem-990	126	14	all	all	PRON
eurjchem-990	126	15	of	of	ADP
eurjchem-990	126	16	the	the	DET
eurjchem-990	126	17	complexes	complex	NOUN
eurjchem-990	126	18	show	show	VERB
eurjchem-990	126	19	an	an	DET
eurjchem-990	126	20	octahedral	octahedral	ADJ
eurjchem-990	126	21	geometry	geometry	NOUN
eurjchem-990	126	22	in	in	ADP
eurjchem-990	126	23	which	which	PRON
eurjchem-990	126	24	the	the	DET
eurjchem-990	126	25	ephc	ephc	NOUN
eurjchem-990	126	26	thiosemicarbazone	thiosemicarbazone	PROPN
eurjchem-990	126	27	ligand	ligand	PROPN
eurjchem-990	126	28	act	act	NOUN
eurjchem-990	126	29	as	as	ADP
eurjchem-990	126	30	monoanion	monoanion	NOUN
eurjchem-990	126	31	tridentate	tridentate	NOUN
eurjchem-990	126	32	ligand	ligand	NOUN
eurjchem-990	126	33	,	,	PUNCT
eurjchem-990	126	34	1,10‐phen	1,10‐phen	NOUN
eurjchem-990	126	35	acts	act	VERB
eurjchem-990	126	36	as	as	ADP
eurjchem-990	126	37	bidentate	bidentate	NOUN
eurjchem-990	126	38	ligand	ligand	NOUN
eurjchem-990	126	39	and	and	CCONJ
eurjchem-990	126	40	in	in	ADP
eurjchem-990	126	41	addition	addition	NOUN
eurjchem-990	126	42	to	to	ADP
eurjchem-990	126	43	the	the	DET
eurjchem-990	126	44	monodentate	monodentate	ADJ
eurjchem-990	126	45	chloride	chloride	NOUN
eurjchem-990	126	46	ion	ion	NOUN
eurjchem-990	126	47	.	.	PUNCT
eurjchem-990	127	1	these	these	PRON
eurjchem-990	127	2	possibly	possibly	ADV
eurjchem-990	127	3	accommodate	accommodate	VERB
eurjchem-990	127	4	themselves	themselves	PRON
eurjchem-990	127	5	around	around	ADP
eurjchem-990	127	6	the	the	DET
eurjchem-990	127	7	metal	metal	NOUN
eurjchem-990	127	8	atom	atom	NOUN
eurjchem-990	127	9	in	in	ADP
eurjchem-990	127	10	such	such	DET
eurjchem-990	127	11	a	a	DET
eurjchem-990	127	12	way	way	NOUN
eurjchem-990	127	13	that	that	PRON
eurjchem-990	127	14	a	a	DET
eurjchem-990	127	15	stable	stable	ADJ
eurjchem-990	127	16	chelate	chelate	NOUN
eurjchem-990	127	17	ring	ring	NOUN
eurjchem-990	127	18	is	be	AUX
eurjchem-990	127	19	formed	form	VERB
eurjchem-990	127	20	giving	give	VERB
eurjchem-990	127	21	,	,	PUNCT
eurjchem-990	127	22	in	in	ADP
eurjchem-990	127	23	turn	turn	NOUN
eurjchem-990	127	24	,	,	PUNCT
eurjchem-990	127	25	stability	stability	NOUN
eurjchem-990	127	26	to	to	ADP
eurjchem-990	127	27	the	the	DET
eurjchem-990	127	28	metal	metal	NOUN
eurjchem-990	127	29	complexes	complex	NOUN
eurjchem-990	127	30	.	.	PUNCT
eurjchem-990	128	1	3.3	3.3	NUM
eurjchem-990	128	2	.	.	PUNCT
eurjchem-990	129	1	esr	esr	PROPN
eurjchem-990	129	2	spectrum	spectrum	NOUN
eurjchem-990	129	3	of	of	ADP
eurjchem-990	129	4	[	[	X
eurjchem-990	129	5	cu(ephc)(1,0‐phen)cl	cu(ephc)(1,0‐phen)cl	NOUN
eurjchem-990	129	6	]	]	X
eurjchem-990	129	7	complex	complex	ADJ
eurjchem-990	129	8	esr	esr	PROPN
eurjchem-990	129	9	spectroscopy	spectroscopy	NOUN
eurjchem-990	129	10	is	be	AUX
eurjchem-990	129	11	a	a	DET
eurjchem-990	129	12	direct	direct	ADJ
eurjchem-990	129	13	measurement	measurement	NOUN
eurjchem-990	129	14	of	of	ADP
eurjchem-990	129	15	electron	electron	NOUN
eurjchem-990	129	16	spin	spin	NOUN
eurjchem-990	129	17	when	when	SCONJ
eurjchem-990	129	18	there	there	PRON
eurjchem-990	129	19	are	be	VERB
eurjchem-990	129	20	unpaired	unpaired	ADJ
eurjchem-990	129	21	electrons	electron	NOUN
eurjchem-990	129	22	within	within	ADP
eurjchem-990	129	23	a	a	DET
eurjchem-990	129	24	chemical	chemical	NOUN
eurjchem-990	129	25	structure	structure	NOUN
eurjchem-990	129	26	and	and	CCONJ
eurjchem-990	129	27	thus	thus	ADV
eurjchem-990	129	28	provides	provide	VERB
eurjchem-990	129	29	a	a	DET
eurjchem-990	129	30	way	way	NOUN
eurjchem-990	129	31	to	to	PART
eurjchem-990	129	32	investigate	investigate	VERB
eurjchem-990	129	33	the	the	DET
eurjchem-990	129	34	electronic	electronic	ADJ
eurjchem-990	129	35	spin	spin	NOUN
eurjchem-990	129	36	state	state	NOUN
eurjchem-990	129	37	and	and	CCONJ
eurjchem-990	129	38	oxidation	oxidation	NOUN
eurjchem-990	129	39	state	state	NOUN
eurjchem-990	129	40	of	of	ADP
eurjchem-990	129	41	the	the	DET
eurjchem-990	129	42	coordinated	coordinate	VERB
eurjchem-990	129	43	metal	metal	NOUN
eurjchem-990	129	44	ion	ion	NOUN
eurjchem-990	129	45	.	.	PUNCT
eurjchem-990	130	1	also	also	ADV
eurjchem-990	130	2	,	,	PUNCT
eurjchem-990	130	3	the	the	DET
eurjchem-990	130	4	esr	esr	PROPN
eurjchem-990	130	5	spectra	spectra	NOUN
eurjchem-990	130	6	of	of	ADP
eurjchem-990	130	7	the	the	DET
eurjchem-990	130	8	complexes	complex	NOUN
eurjchem-990	130	9	is	be	AUX
eurjchem-990	130	10	important	important	ADJ
eurjchem-990	130	11	in	in	ADP
eurjchem-990	130	12	studying	study	VERB
eurjchem-990	130	13	the	the	DET
eurjchem-990	130	14	metal	metal	NOUN
eurjchem-990	130	15	ion	ion	NOUN
eurjchem-990	130	16	environment	environment	NOUN
eurjchem-990	130	17	in	in	ADP
eurjchem-990	130	18	the	the	DET
eurjchem-990	130	19	complexes	complex	NOUN
eurjchem-990	130	20	,	,	PUNCT
eurjchem-990	130	21	such	such	ADJ
eurjchem-990	130	22	as	as	ADP
eurjchem-990	130	23	geometry	geometry	NOUN
eurjchem-990	130	24	,	,	PUNCT
eurjchem-990	130	25	nature	nature	NOUN
eurjchem-990	130	26	of	of	ADP
eurjchem-990	130	27	ligation	ligation	NOUN
eurjchem-990	130	28	sites	site	NOUN
eurjchem-990	130	29	from	from	ADP
eurjchem-990	130	30	the	the	DET
eurjchem-990	130	31	ligand	ligand	NOUN
eurjchem-990	130	32	to	to	ADP
eurjchem-990	130	33	the	the	DET
eurjchem-990	130	34	metal	metal	NOUN
eurjchem-990	130	35	,	,	PUNCT
eurjchem-990	130	36	and	and	CCONJ
eurjchem-990	130	37	the	the	DET
eurjchem-990	130	38	degree	degree	NOUN
eurjchem-990	130	39	of	of	ADP
eurjchem-990	130	40	covalence	covalence	NOUN
eurjchem-990	130	41	of	of	ADP
eurjchem-990	130	42	the	the	DET
eurjchem-990	130	43	metal‐ligand	metal‐ligand	NOUN
eurjchem-990	130	44	bonds	bond	NOUN
eurjchem-990	130	45	.	.	PUNCT
eurjchem-990	131	1	the	the	DET
eurjchem-990	131	2	room	room	NOUN
eurjchem-990	131	3	temperature	temperature	NOUN
eurjchem-990	131	4	powder	powder	NOUN
eurjchem-990	131	5	esr	esr	PROPN
eurjchem-990	131	6	spectrum	spectrum	NOUN
eurjchem-990	131	7	of	of	ADP
eurjchem-990	131	8	[	[	X
eurjchem-990	131	9	cu(ephc)(1,10‐phen)cl	cu(ephc)(1,10‐phen)cl	X
eurjchem-990	131	10	]	]	PUNCT
eurjchem-990	131	11	exhibits	exhibit	VERB
eurjchem-990	131	12	an	an	DET
eurjchem-990	131	13	axial	axial	ADJ
eurjchem-990	131	14	signal	signal	NOUN
eurjchem-990	131	15	with	with	ADP
eurjchem-990	131	16	two	two	NUM
eurjchem-990	131	17	g	g	NOUN
eurjchem-990	131	18	values	value	NOUN
eurjchem-990	131	19	(	(	PUNCT
eurjchem-990	131	20	g||	g||	NOUN
eurjchem-990	131	21	=	=	NOUN
eurjchem-990	131	22	2.281	2.281	NUM
eurjchem-990	131	23	,	,	PUNCT
eurjchem-990	131	24	g	g	NOUN
eurjchem-990	131	25	┴	┴	NOUN
eurjchem-990	131	26	=	=	PUNCT
eurjchem-990	131	27	2.065	2.065	NUM
eurjchem-990	131	28	)	)	PUNCT
eurjchem-990	131	29	.	.	PUNCT
eurjchem-990	132	1	the	the	DET
eurjchem-990	132	2	g||	g||	NOUN
eurjchem-990	132	3	and	and	CCONJ
eurjchem-990	132	4	g	g	ADP
eurjchem-990	132	5	┴	┴	NOUN
eurjchem-990	132	6	values	value	NOUN
eurjchem-990	132	7	are	be	AUX
eurjchem-990	132	8	computed	compute	VERB
eurjchem-990	132	9	from	from	ADP
eurjchem-990	132	10	the	the	DET
eurjchem-990	132	11	spectrum	spectrum	NOUN
eurjchem-990	132	12	using	use	VERB
eurjchem-990	132	13	dpph	dpph	PROPN
eurjchem-990	132	14	free	free	ADJ
eurjchem-990	132	15	radical	radical	ADJ
eurjchem-990	132	16	as	as	ADP
eurjchem-990	132	17	"	"	PUNCT
eurjchem-990	132	18	g	g	NOUN
eurjchem-990	132	19	"	"	PUNCT
eurjchem-990	132	20	marker	marker	NOUN
eurjchem-990	132	21	.	.	PUNCT
eurjchem-990	133	1	the	the	DET
eurjchem-990	133	2	ordering	ordering	NOUN
eurjchem-990	133	3	of	of	ADP
eurjchem-990	133	4	g	g	NOUN
eurjchem-990	133	5	values	value	NOUN
eurjchem-990	133	6	(	(	PUNCT
eurjchem-990	133	7	g||	g||	NOUN
eurjchem-990	133	8	>	>	X
eurjchem-990	133	9	g	g	PROPN
eurjchem-990	133	10	┴	┴	NOUN
eurjchem-990	133	11	>	>	X
eurjchem-990	133	12	2.003	2.003	NUM
eurjchem-990	133	13	)	)	PUNCT
eurjchem-990	133	14	observed	observe	VERB
eurjchem-990	133	15	for	for	ADP
eurjchem-990	133	16	copper(ii	copper(ii	NOUN
eurjchem-990	133	17	)	)	PUNCT
eurjchem-990	133	18	complex	complex	NOUN
eurjchem-990	133	19	indicates	indicate	VERB
eurjchem-990	133	20	that	that	SCONJ
eurjchem-990	133	21	the	the	DET
eurjchem-990	133	22	unpaired	unpaired	ADJ
eurjchem-990	133	23	electron	electron	NOUN
eurjchem-990	133	24	is	be	AUX
eurjchem-990	133	25	localized	localize	VERB
eurjchem-990	133	26	in	in	ADP
eurjchem-990	133	27	(	(	PUNCT
eurjchem-990	133	28	dx2‐y2	dx2‐y2	NOUN
eurjchem-990	133	29	)	)	PUNCT
eurjchem-990	133	30	orbital	orbital	NOUN
eurjchem-990	134	1	[	[	X
eurjchem-990	134	2	49	49	NUM
eurjchem-990	134	3	]	]	PUNCT
eurjchem-990	134	4	of	of	ADP
eurjchem-990	134	5	the	the	DET
eurjchem-990	134	6	cu(ii	cu(ii	PROPN
eurjchem-990	134	7	)	)	PUNCT
eurjchem-990	134	8	ion	ion	NOUN
eurjchem-990	134	9	(	(	PUNCT
eurjchem-990	134	10	spectroscopic	spectroscopic	ADJ
eurjchem-990	134	11	state	state	NOUN
eurjchem-990	134	12	2b1	2b1	NUM
eurjchem-990	134	13	g	g	NOUN
eurjchem-990	134	14	)	)	PUNCT
eurjchem-990	134	15	and	and	CCONJ
eurjchem-990	134	16	the	the	DET
eurjchem-990	134	17	spectral	spectral	ADJ
eurjchem-990	134	18	features	feature	NOUN
eurjchem-990	134	19	are	be	AUX
eurjchem-990	134	20	characteristics	characteristic	NOUN
eurjchem-990	134	21	of	of	ADP
eurjchem-990	134	22	axial	axial	ADJ
eurjchem-990	134	23	symmetry	symmetry	NOUN
eurjchem-990	134	24	[	[	X
eurjchem-990	134	25	50	50	NUM
eurjchem-990	134	26	]	]	PUNCT
eurjchem-990	134	27	.	.	PUNCT
eurjchem-990	135	1	g||	g||	NOUN
eurjchem-990	135	2	is	be	AUX
eurjchem-990	135	3	a	a	DET
eurjchem-990	135	4	moderately	moderately	ADV
eurjchem-990	135	5	sensitive	sensitive	ADJ
eurjchem-990	135	6	function	function	NOUN
eurjchem-990	135	7	for	for	ADP
eurjchem-990	135	8	m‐l	m‐l	PROPN
eurjchem-990	135	9	bond	bond	NOUN
eurjchem-990	135	10	nature	nature	NOUN
eurjchem-990	135	11	.	.	PUNCT
eurjchem-990	136	1	the	the	DET
eurjchem-990	136	2	g||	g||	NOUN
eurjchem-990	136	3	value	value	NOUN
eurjchem-990	136	4	is	be	AUX
eurjchem-990	136	5	a	a	DET
eurjchem-990	136	6	moderately	moderately	ADV
eurjchem-990	136	7	sensitive	sensitive	ADJ
eurjchem-990	136	8	function	function	NOUN
eurjchem-990	136	9	for	for	ADP
eurjchem-990	136	10	m‐l	m‐l	PROPN
eurjchem-990	136	11	bond	bond	NOUN
eurjchem-990	136	12	nature	nature	NOUN
eurjchem-990	136	13	i.e.	i.e.	X
eurjchem-990	136	14	,	,	PUNCT
eurjchem-990	136	15	the	the	DET
eurjchem-990	136	16	g||	g||	NOUN
eurjchem-990	136	17	value	value	NOUN
eurjchem-990	136	18	<	<	X
eurjchem-990	136	19	2.3	2.3	NUM
eurjchem-990	136	20	g||	g||	NOUN
eurjchem-990	136	21	value	value	NOUN
eurjchem-990	136	22	>	>	X
eurjchem-990	136	23	2.3	2.3	NUM
eurjchem-990	136	24	are	be	AUX
eurjchem-990	136	25	characterized	characterize	VERB
eurjchem-990	136	26	for	for	ADP
eurjchem-990	136	27	covalent	covalent	NOUN
eurjchem-990	136	28	and	and	CCONJ
eurjchem-990	136	29	ionic	ionic	ADJ
eurjchem-990	136	30	metal‐ligand	metal‐ligand	NOUN
eurjchem-990	136	31	bonds	bond	NOUN
eurjchem-990	136	32	respectively	respectively	ADV
eurjchem-990	136	33	.	.	PUNCT
eurjchem-990	137	1	by	by	ADP
eurjchem-990	137	2	applying	apply	VERB
eurjchem-990	137	3	this	this	DET
eurjchem-990	137	4	criterion	criterion	NOUN
eurjchem-990	137	5	,	,	PUNCT
eurjchem-990	137	6	the	the	DET
eurjchem-990	137	7	g||	g||	NOUN
eurjchem-990	137	8	value	value	NOUN
eurjchem-990	137	9	is	be	AUX
eurjchem-990	137	10	less	less	ADJ
eurjchem-990	137	11	than	than	ADP
eurjchem-990	137	12	2.3	2.3	NUM
eurjchem-990	137	13	is	be	AUX
eurjchem-990	137	14	an	an	DET
eurjchem-990	137	15	indication	indication	NOUN
eurjchem-990	137	16	of	of	ADP
eurjchem-990	137	17	significant	significant	ADJ
eurjchem-990	137	18	covalent	covalent	NOUN
eurjchem-990	137	19	bonding	bonding	NOUN
eurjchem-990	137	20	in	in	ADP
eurjchem-990	137	21	copper(ii	copper(ii	NOUN
eurjchem-990	137	22	)	)	PUNCT
eurjchem-990	137	23	complex	complex	NOUN
eurjchem-990	137	24	.	.	PUNCT
eurjchem-990	138	1	based	base	VERB
eurjchem-990	138	2	on	on	ADP
eurjchem-990	138	3	elemental	elemental	ADJ
eurjchem-990	138	4	analysis	analysis	NOUN
eurjchem-990	138	5	,	,	PUNCT
eurjchem-990	138	6	ir	ir	INTJ
eurjchem-990	138	7	,	,	PUNCT
eurjchem-990	138	8	electronic	electronic	ADJ
eurjchem-990	138	9	spectra	spectra	NOUN
eurjchem-990	138	10	and	and	CCONJ
eurjchem-990	138	11	esr	esr	PROPN
eurjchem-990	138	12	data	data	PROPN
eurjchem-990	138	13	,	,	PUNCT
eurjchem-990	138	14	cu(ii	cu(ii	PROPN
eurjchem-990	138	15	)	)	PUNCT
eurjchem-990	138	16	complex	complex	NOUN
eurjchem-990	138	17	has	have	VERB
eurjchem-990	138	18	octahedral	octahedral	ADJ
eurjchem-990	138	19	structure	structure	NOUN
eurjchem-990	138	20	.	.	PUNCT
eurjchem-990	139	1	the	the	DET
eurjchem-990	139	2	geometric	geometric	ADJ
eurjchem-990	139	3	parameter	parameter	NOUN
eurjchem-990	139	4	g	g	NOUN
eurjchem-990	139	5	,	,	PUNCT
eurjchem-990	139	6	which	which	PRON
eurjchem-990	139	7	is	be	AUX
eurjchem-990	139	8	a	a	DET
eurjchem-990	139	9	measure	measure	NOUN
eurjchem-990	139	10	of	of	ADP
eurjchem-990	139	11	the	the	DET
eurjchem-990	139	12	exchange	exchange	NOUN
eurjchem-990	139	13	interaction	interaction	NOUN
eurjchem-990	139	14	between	between	ADP
eurjchem-990	139	15	copper	copper	NOUN
eurjchem-990	139	16	centers	center	NOUN
eurjchem-990	139	17	in	in	ADP
eurjchem-990	139	18	the	the	DET
eurjchem-990	139	19	polycrystalline	polycrystalline	ADJ
eurjchem-990	139	20	compound	compound	NOUN
eurjchem-990	139	21	,	,	PUNCT
eurjchem-990	139	22	is	be	AUX
eurjchem-990	139	23	calculated	calculate	VERB
eurjchem-990	139	24	using	use	VERB
eurjchem-990	139	25	hathway	hathway	NOUN
eurjchem-990	139	26	expression	expression	NOUN
eurjchem-990	139	27	(	(	PUNCT
eurjchem-990	139	28	g	g	NOUN
eurjchem-990	139	29	=	=	SYM
eurjchem-990	139	30	g||‐2.0023	g||‐2.0023	PROPN
eurjchem-990	139	31	/	/	SYM
eurjchem-990	139	32	g	g	NOUN
eurjchem-990	139	33	┴	┴	NOUN
eurjchem-990	139	34	‐2.0023	‐2.0023	NOUN
eurjchem-990	139	35	)	)	PUNCT
eurjchem-990	140	1	[	[	X
eurjchem-990	140	2	51	51	NUM
eurjchem-990	140	3	]	]	PUNCT
eurjchem-990	140	4	.	.	PUNCT
eurjchem-990	141	1	according	accord	VERB
eurjchem-990	141	2	to	to	ADP
eurjchem-990	141	3	hathway	hathway	PROPN
eurjchem-990	141	4	,	,	PUNCT
eurjchem-990	141	5	if	if	SCONJ
eurjchem-990	141	6	the	the	DET
eurjchem-990	141	7	value	value	NOUN
eurjchem-990	141	8	of	of	ADP
eurjchem-990	141	9	g	g	PROPN
eurjchem-990	141	10	>	>	X
eurjchem-990	141	11	4	4	NUM
eurjchem-990	141	12	,	,	PUNCT
eurjchem-990	141	13	the	the	DET
eurjchem-990	141	14	exchange	exchange	NOUN
eurjchem-990	141	15	interaction	interaction	NOUN
eurjchem-990	141	16	is	be	AUX
eurjchem-990	141	17	negligible	negligible	ADJ
eurjchem-990	141	18	in	in	ADP
eurjchem-990	141	19	solid	solid	ADJ
eurjchem-990	141	20	complexes	complex	NOUN
eurjchem-990	141	21	but	but	CCONJ
eurjchem-990	141	22	g	g	NOUN
eurjchem-990	141	23	<	<	X
eurjchem-990	141	24	4	4	NUM
eurjchem-990	141	25	indicates	indicate	VERB
eurjchem-990	141	26	considerable	considerable	ADJ
eurjchem-990	141	27	interaction	interaction	NOUN
eurjchem-990	141	28	in	in	ADP
eurjchem-990	141	29	solid	solid	ADJ
eurjchem-990	141	30	complexes	complex	NOUN
eurjchem-990	141	31	[	[	X
eurjchem-990	141	32	51	51	NUM
eurjchem-990	141	33	]	]	PUNCT
eurjchem-990	141	34	.	.	PUNCT
eurjchem-990	142	1	in	in	ADP
eurjchem-990	142	2	the	the	DET
eurjchem-990	142	3	cu(ii	cu(ii	PROPN
eurjchem-990	142	4	)	)	PUNCT
eurjchem-990	142	5	complex	complex	NOUN
eurjchem-990	142	6	reported	report	VERB
eurjchem-990	142	7	in	in	ADP
eurjchem-990	142	8	this	this	DET
eurjchem-990	142	9	paper	paper	NOUN
eurjchem-990	142	10	,	,	PUNCT
eurjchem-990	142	11	the	the	DET
eurjchem-990	142	12	g	g	PROPN
eurjchem-990	142	13	value	value	NOUN
eurjchem-990	142	14	(	(	PUNCT
eurjchem-990	142	15	4.445	4.445	NUM
eurjchem-990	142	16	)	)	PUNCT
eurjchem-990	142	17	>	>	X
eurjchem-990	142	18	4	4	NUM
eurjchem-990	142	19	,	,	PUNCT
eurjchem-990	142	20	suggesting	suggest	VERB
eurjchem-990	142	21	the	the	DET
eurjchem-990	142	22	absence	absence	NOUN
eurjchem-990	142	23	of	of	ADP
eurjchem-990	142	24	copper‐copper	copper‐copper	ADJ
eurjchem-990	142	25	exchange	exchange	NOUN
eurjchem-990	142	26	interactions	interaction	NOUN
eurjchem-990	142	27	in	in	ADP
eurjchem-990	142	28	the	the	DET
eurjchem-990	142	29	solid	solid	ADJ
eurjchem-990	142	30	state	state	NOUN
eurjchem-990	142	31	.	.	PUNCT
eurjchem-990	143	1	3.4	3.4	NUM
eurjchem-990	143	2	.	.	PUNCT
eurjchem-990	143	3	conductivity	conductivity	NOUN
eurjchem-990	143	4	measurements	measurement	NOUN
eurjchem-990	143	5	conductivity	conductivity	NOUN
eurjchem-990	143	6	measurements	measurement	NOUN
eurjchem-990	143	7	in	in	ADP
eurjchem-990	143	8	non‐aqueous	non‐aqueous	ADJ
eurjchem-990	143	9	solutions	solution	NOUN
eurjchem-990	143	10	have	have	AUX
eurjchem-990	143	11	frequently	frequently	ADV
eurjchem-990	143	12	been	be	AUX
eurjchem-990	143	13	used	use	VERB
eurjchem-990	143	14	in	in	ADP
eurjchem-990	143	15	structural	structural	ADJ
eurjchem-990	143	16	studies	study	NOUN
eurjchem-990	143	17	of	of	ADP
eurjchem-990	143	18	metal	metal	NOUN
eurjchem-990	143	19	chelates	chelate	NOUN
eurjchem-990	143	20	within	within	ADP
eurjchem-990	143	21	the	the	DET
eurjchem-990	143	22	limits	limit	NOUN
eurjchem-990	143	23	of	of	ADP
eurjchem-990	143	24	their	their	PRON
eurjchem-990	143	25	solubility	solubility	NOUN
eurjchem-990	143	26	.	.	PUNCT
eurjchem-990	144	1	these	these	DET
eurjchem-990	144	2	measurements	measurement	NOUN
eurjchem-990	144	3	were	be	AUX
eurjchem-990	144	4	provided	provide	VERB
eurjchem-990	144	5	a	a	DET
eurjchem-990	144	6	method	method	NOUN
eurjchem-990	144	7	for	for	ADP
eurjchem-990	144	8	testing	test	VERB
eurjchem-990	144	9	the	the	DET
eurjchem-990	144	10	degree	degree	NOUN
eurjchem-990	144	11	of	of	ADP
eurjchem-990	144	12	ionization	ionization	NOUN
eurjchem-990	144	13	of	of	ADP
eurjchem-990	144	14	the	the	DET
eurjchem-990	144	15	complexes	complex	NOUN
eurjchem-990	144	16	,	,	PUNCT
eurjchem-990	144	17	the	the	DET
eurjchem-990	144	18	molar	molar	ADJ
eurjchem-990	144	19	ions	ion	NOUN
eurjchem-990	144	20	that	that	PRON
eurjchem-990	144	21	a	a	DET
eurjchem-990	144	22	complex	complex	NOUN
eurjchem-990	144	23	liberates	liberate	VERB
eurjchem-990	144	24	in	in	ADP
eurjchem-990	144	25	solution	solution	NOUN
eurjchem-990	144	26	,	,	PUNCT
eurjchem-990	144	27	the	the	DET
eurjchem-990	144	28	higher	high	ADJ
eurjchem-990	144	29	will	will	AUX
eurjchem-990	144	30	be	be	AUX
eurjchem-990	144	31	its	its	PRON
eurjchem-990	144	32	molar	molar	ADJ
eurjchem-990	144	33	conductivity	conductivity	NOUN
eurjchem-990	144	34	and	and	CCONJ
eurjchem-990	144	35	vice	vice	NOUN
eurjchem-990	144	36	versa	versa	ADV
eurjchem-990	144	37	.	.	PUNCT
eurjchem-990	145	1	the	the	DET
eurjchem-990	145	2	non‐ionized	non‐ionized	ADJ
eurjchem-990	145	3	complexes	complex	NOUN
eurjchem-990	145	4	have	have	VERB
eurjchem-990	145	5	negligible	negligible	ADJ
eurjchem-990	145	6	value	value	NOUN
eurjchem-990	145	7	of	of	ADP
eurjchem-990	145	8	molar	molar	ADJ
eurjchem-990	145	9	conductance	conductance	NOUN
eurjchem-990	145	10	.	.	PUNCT
eurjchem-990	146	1	it	it	PRON
eurjchem-990	146	2	is	be	AUX
eurjchem-990	146	3	clear	clear	ADJ
eurjchem-990	146	4	from	from	ADP
eurjchem-990	146	5	the	the	DET
eurjchem-990	146	6	conductivity	conductivity	NOUN
eurjchem-990	146	7	data	datum	NOUN
eurjchem-990	146	8	(	(	PUNCT
eurjchem-990	146	9	table	table	NOUN
eurjchem-990	146	10	3	3	NUM
eurjchem-990	146	11	)	)	PUNCT
eurjchem-990	146	12	that	that	SCONJ
eurjchem-990	146	13	the	the	DET
eurjchem-990	146	14	complexes	complex	NOUN
eurjchem-990	146	15	present	present	NOUN
eurjchem-990	146	16	seem	seem	VERB
eurjchem-990	146	17	to	to	PART
eurjchem-990	146	18	be	be	AUX
eurjchem-990	146	19	nonelectrolytes	nonelectrolyte	NOUN
eurjchem-990	146	20	(	(	PUNCT
eurjchem-990	146	21	3.15‐	3.15‐	NUM
eurjchem-990	146	22	6.97	6.97	NUM
eurjchem-990	146	23	ω‐1.cm2.mol‐1	ω‐1.cm2.mol‐1	NUM
eurjchem-990	146	24	)	)	PUNCT
eurjchem-990	146	25	.	.	PUNCT
eurjchem-990	147	1	also	also	ADV
eurjchem-990	147	2	the	the	DET
eurjchem-990	147	3	molar	molar	ADJ
eurjchem-990	147	4	conductance	conductance	NOUN
eurjchem-990	147	5	values	value	NOUN
eurjchem-990	147	6	indicate	indicate	VERB
eurjchem-990	147	7	that	that	SCONJ
eurjchem-990	147	8	the	the	DET
eurjchem-990	147	9	anions	anion	NOUN
eurjchem-990	147	10	were	be	AUX
eurjchem-990	147	11	existed	exist	VERB
eurjchem-990	147	12	inside	inside	ADP
eurjchem-990	147	13	the	the	DET
eurjchem-990	147	14	coordination	coordination	NOUN
eurjchem-990	147	15	sphere	sphere	NOUN
eurjchem-990	147	16	,	,	PUNCT
eurjchem-990	147	17	which	which	PRON
eurjchem-990	147	18	was	be	AUX
eurjchem-990	147	19	also	also	ADV
eurjchem-990	147	20	confirmed	confirm	VERB
eurjchem-990	147	21	from	from	ADP
eurjchem-990	147	22	the	the	DET
eurjchem-990	147	23	chemical	chemical	ADJ
eurjchem-990	147	24	analysis	analysis	NOUN
eurjchem-990	147	25	and	and	CCONJ
eurjchem-990	147	26	also	also	ADV
eurjchem-990	147	27	cl−	cl−	NUM
eurjchem-990	147	28	ion	ion	NOUN
eurjchem-990	147	29	is	be	AUX
eurjchem-990	147	30	not	not	PART
eurjchem-990	147	31	precipitated	precipitate	VERB
eurjchem-990	147	32	by	by	ADP
eurjchem-990	147	33	addition	addition	NOUN
eurjchem-990	147	34	of	of	ADP
eurjchem-990	147	35	agno3	agno3	NOUN
eurjchem-990	147	36	solution	solution	NOUN
eurjchem-990	147	37	.	.	PUNCT
eurjchem-990	148	1	hence	hence	ADV
eurjchem-990	148	2	,	,	PUNCT
eurjchem-990	148	3	the	the	DET
eurjchem-990	148	4	conductivity	conductivity	NOUN
eurjchem-990	148	5	measurements	measurement	NOUN
eurjchem-990	148	6	of	of	ADP
eurjchem-990	148	7	the	the	DET
eurjchem-990	148	8	metal(ii)‐chelates	metal(ii)‐chelate	NOUN
eurjchem-990	148	9	confirm	confirm	VERB
eurjchem-990	148	10	the	the	DET
eurjchem-990	148	11	proposed	propose	VERB
eurjchem-990	148	12	general	general	ADJ
eurjchem-990	148	13	formulae	formulae	NOUN
eurjchem-990	148	14	of	of	ADP
eurjchem-990	148	15	those	those	DET
eurjchem-990	148	16	chelates	chelate	NOUN
eurjchem-990	148	17	as	as	SCONJ
eurjchem-990	148	18	suggested	suggest	VERB
eurjchem-990	148	19	depending	depend	VERB
eurjchem-990	148	20	upon	upon	SCONJ
eurjchem-990	148	21	the	the	DET
eurjchem-990	148	22	results	result	NOUN
eurjchem-990	148	23	of	of	ADP
eurjchem-990	148	24	elemental	elemental	ADJ
eurjchem-990	148	25	analyses	analysis	NOUN
eurjchem-990	148	26	,	,	PUNCT
eurjchem-990	148	27	uv‐vis	uv‐vis	PROPN
eurjchem-990	148	28	,	,	PUNCT
eurjchem-990	148	29	esr	esr	PROPN
eurjchem-990	148	30	and	and	CCONJ
eurjchem-990	148	31	ir	ir	PROPN
eurjchem-990	148	32	spectra	spectra	PROPN
eurjchem-990	148	33	.	.	PROPN
eurjchem-990	149	1	3.5	3.5	NUM
eurjchem-990	149	2	.	.	PUNCT
eurjchem-990	149	3	antimicrobial	antimicrobial	ADJ
eurjchem-990	149	4	activity	activity	NOUN
eurjchem-990	149	5	to	to	PART
eurjchem-990	149	6	assess	assess	VERB
eurjchem-990	149	7	the	the	DET
eurjchem-990	149	8	biological	biological	ADJ
eurjchem-990	149	9	potential	potential	NOUN
eurjchem-990	149	10	of	of	ADP
eurjchem-990	149	11	the	the	DET
eurjchem-990	149	12	synthesized	synthesize	VERB
eurjchem-990	149	13	compounds	compound	NOUN
eurjchem-990	149	14	,	,	PUNCT
eurjchem-990	149	15	the	the	DET
eurjchem-990	149	16	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-990	149	17	ligands	ligand	NOUN
eurjchem-990	149	18	and	and	CCONJ
eurjchem-990	149	19	their	their	PRON
eurjchem-990	149	20	metal	metal	NOUN
eurjchem-990	149	21	complexes	complex	NOUN
eurjchem-990	149	22	were	be	AUX
eurjchem-990	149	23	tested	test	VERB
eurjchem-990	149	24	against	against	ADP
eurjchem-990	149	25	different	different	ADJ
eurjchem-990	149	26	species	specie	NOUN
eurjchem-990	149	27	of	of	ADP
eurjchem-990	149	28	bacteria	bacteria	NOUN
eurjchem-990	149	29	and	and	CCONJ
eurjchem-990	149	30	fungi	fungus	NOUN
eurjchem-990	149	31	.	.	PUNCT
eurjchem-990	150	1	the	the	DET
eurjchem-990	150	2	parent	parent	NOUN
eurjchem-990	150	3	(	(	PUNCT
eurjchem-990	150	4	ephc	ephc	PROPN
eurjchem-990	150	5	)	)	PUNCT
eurjchem-990	150	6	ligand	ligand	NOUN
eurjchem-990	150	7	and	and	CCONJ
eurjchem-990	150	8	its	its	PRON
eurjchem-990	150	9	complexes	complex	NOUN
eurjchem-990	150	10	are	be	AUX
eurjchem-990	150	11	water	water	NOUN
eurjchem-990	150	12	insoluble	insoluble	ADJ
eurjchem-990	150	13	;	;	PUNCT
eurjchem-990	150	14	therefore	therefore	ADV
eurjchem-990	150	15	,	,	PUNCT
eurjchem-990	150	16	the	the	DET
eurjchem-990	150	17	antimicrobial	antimicrobial	ADJ
eurjchem-990	150	18	test	test	NOUN
eurjchem-990	150	19	was	be	AUX
eurjchem-990	150	20	carried	carry	VERB
eurjchem-990	150	21	out	out	ADP
eurjchem-990	150	22	in	in	ADP
eurjchem-990	150	23	dmso	dmso	NOUN
eurjchem-990	150	24	.	.	PUNCT
eurjchem-990	151	1	the	the	DET
eurjchem-990	151	2	results	result	NOUN
eurjchem-990	151	3	of	of	ADP
eurjchem-990	151	4	the	the	DET
eurjchem-990	151	5	antimicrobial	antimicrobial	ADJ
eurjchem-990	151	6	test	test	NOUN
eurjchem-990	151	7	of	of	ADP
eurjchem-990	151	8	the	the	DET
eurjchem-990	151	9	parent	parent	NOUN
eurjchem-990	151	10	ligand	ligand	NOUN
eurjchem-990	151	11	and	and	CCONJ
eurjchem-990	151	12	its	its	PRON
eurjchem-990	151	13	metal	metal	NOUN
eurjchem-990	151	14	complexes	complex	NOUN
eurjchem-990	151	15	against	against	ADP
eurjchem-990	151	16	gram	gram	NOUN
eurjchem-990	151	17	positive	positive	ADJ
eurjchem-990	151	18	and	and	CCONJ
eurjchem-990	151	19	gram	gram	NOUN
eurjchem-990	151	20	negative	negative	NOUN
eurjchem-990	151	21	are	be	AUX
eurjchem-990	151	22	given	give	VERB
eurjchem-990	151	23	in	in	ADP
eurjchem-990	151	24	table	table	NOUN
eurjchem-990	151	25	4	4	NUM
eurjchem-990	151	26	while	while	SCONJ
eurjchem-990	151	27	the	the	DET
eurjchem-990	151	28	results	result	NOUN
eurjchem-990	151	29	of	of	ADP
eurjchem-990	151	30	the	the	DET
eurjchem-990	151	31	antifungal	antifungal	ADJ
eurjchem-990	151	32	activity	activity	NOUN
eurjchem-990	151	33	against	against	ADP
eurjchem-990	151	34	was	be	AUX
eurjchem-990	151	35	given	give	VERB
eurjchem-990	151	36	in	in	ADP
eurjchem-990	151	37	table	table	NOUN
eurjchem-990	151	38	5	5	NUM
eurjchem-990	151	39	.	.	PUNCT
eurjchem-990	152	1	in	in	ADP
eurjchem-990	152	2	testing	test	VERB
eurjchem-990	152	3	the	the	DET
eurjchem-990	152	4	antimicrobial	antimicrobial	ADJ
eurjchem-990	152	5	activity	activity	NOUN
eurjchem-990	152	6	of	of	ADP
eurjchem-990	152	7	these	these	DET
eurjchem-990	152	8	compounds	compound	NOUN
eurjchem-990	152	9	,	,	PUNCT
eurjchem-990	152	10	we	we	PRON
eurjchem-990	152	11	used	use	VERB
eurjchem-990	152	12	more	more	ADJ
eurjchem-990	152	13	than	than	ADP
eurjchem-990	152	14	one	one	NUM
eurjchem-990	152	15	test	test	NOUN
eurjchem-990	152	16	organism	organism	NOUN
eurjchem-990	152	17	to	to	PART
eurjchem-990	152	18	increase	increase	VERB
eurjchem-990	152	19	the	the	DET
eurjchem-990	152	20	chance	chance	NOUN
eurjchem-990	152	21	of	of	ADP
eurjchem-990	152	22	detecting	detect	VERB
eurjchem-990	152	23	antibiotic	antibiotic	ADJ
eurjchem-990	152	24	principles	principle	NOUN
eurjchem-990	152	25	in	in	ADP
eurjchem-990	152	26	tested	test	VERB
eurjchem-990	152	27	materials	material	NOUN
eurjchem-990	152	28	.	.	PUNCT
eurjchem-990	153	1	the	the	DET
eurjchem-990	153	2	organisms	organism	NOUN
eurjchem-990	153	3	used	use	VERB
eurjchem-990	153	4	in	in	ADP
eurjchem-990	153	5	the	the	DET
eurjchem-990	153	6	present	present	ADJ
eurjchem-990	153	7	investigations	investigation	NOUN
eurjchem-990	153	8	included	include	VERB
eurjchem-990	153	9	two	two	NUM
eurjchem-990	153	10	gram	gram	NOUN
eurjchem-990	153	11	positive	positive	ADJ
eurjchem-990	153	12	(	(	PUNCT
eurjchem-990	153	13	staphylococcus	staphylococcus	NOUN
eurjchem-990	153	14	aureus	aureus	NOUN
eurjchem-990	153	15	and	and	CCONJ
eurjchem-990	153	16	bacillus	bacillus	NOUN
eurjchem-990	153	17	subtillis	subtillis	PROPN
eurjchem-990	153	18	)	)	PUNCT
eurjchem-990	153	19	and	and	CCONJ
eurjchem-990	153	20	two	two	NUM
eurjchem-990	153	21	gram	gram	NOUN
eurjchem-990	153	22	negative	negative	ADJ
eurjchem-990	153	23	(	(	PUNCT
eurjchem-990	153	24	pseudomonas	pseudomona	NOUN
eurjchem-990	153	25	aeruguinosa	aeruguinosa	PROPN
eurjchem-990	153	26	and	and	CCONJ
eurjchem-990	153	27	escherichia	escherichia	NOUN
eurjchem-990	153	28	coli	coli	NOUN
eurjchem-990	153	29	)	)	PUNCT
eurjchem-990	153	30	.	.	PUNCT
eurjchem-990	154	1	the	the	DET
eurjchem-990	154	2	diffusion	diffusion	NOUN
eurjchem-990	154	3	agar	agar	NOUN
eurjchem-990	154	4	technique	technique	NOUN
eurjchem-990	154	5	was	be	AUX
eurjchem-990	154	6	used	use	VERB
eurjchem-990	154	7	to	to	PART
eurjchem-990	154	8	evaluate	evaluate	VERB
eurjchem-990	154	9	the	the	DET
eurjchem-990	154	10	antibacterial	antibacterial	ADJ
eurjchem-990	154	11	activity	activity	NOUN
eurjchem-990	154	12	of	of	ADP
eurjchem-990	154	13	the	the	DET
eurjchem-990	154	14	synthesized	synthesize	VERB
eurjchem-990	154	15	mixed	mixed	ADJ
eurjchem-990	154	16	ligand	ligand	ADJ
eurjchem-990	154	17	complexes	complex	NOUN
eurjchem-990	154	18	[	[	X
eurjchem-990	154	19	52‐55	52‐55	NUM
eurjchem-990	154	20	]	]	PUNCT
eurjchem-990	154	21	.	.	PUNCT
eurjchem-990	155	1	the	the	DET
eurjchem-990	155	2	medium	medium	NOUN
eurjchem-990	155	3	used	use	VERB
eurjchem-990	155	4	for	for	ADP
eurjchem-990	155	5	growing	grow	VERB
eurjchem-990	155	6	the	the	DET
eurjchem-990	155	7	culture	culture	NOUN
eurjchem-990	155	8	was	be	AUX
eurjchem-990	155	9	nutrient	nutrient	ADJ
eurjchem-990	155	10	agar	agar	NOUN
eurjchem-990	155	11	.	.	PUNCT
eurjchem-990	156	1	the	the	DET
eurjchem-990	156	2	results	result	NOUN
eurjchem-990	156	3	of	of	ADP
eurjchem-990	156	4	the	the	DET
eurjchem-990	156	5	antibacterial	antibacterial	ADJ
eurjchem-990	156	6	activity	activity	NOUN
eurjchem-990	156	7	of	of	ADP
eurjchem-990	156	8	the	the	DET
eurjchem-990	156	9	synthesized	synthesize	VERB
eurjchem-990	156	10	compounds	compound	NOUN
eurjchem-990	156	11	are	be	AUX
eurjchem-990	156	12	recorded	record	VERB
eurjchem-990	156	13	in	in	ADP
eurjchem-990	156	14	tables	table	NOUN
eurjchem-990	156	15	4	4	NUM
eurjchem-990	156	16	and	and	CCONJ
eurjchem-990	156	17	5	5	NUM
eurjchem-990	156	18	.	.	X
eurjchem-990	156	19	metal	metal	NOUN
eurjchem-990	156	20	ions	ion	NOUN
eurjchem-990	156	21	are	be	AUX
eurjchem-990	156	22	adsorbed	adsorb	VERB
eurjchem-990	156	23	on	on	ADP
eurjchem-990	156	24	the	the	DET
eurjchem-990	156	25	cell	cell	NOUN
eurjchem-990	156	26	walls	wall	NOUN
eurjchem-990	156	27	of	of	ADP
eurjchem-990	156	28	the	the	DET
eurjchem-990	156	29	microorganisms	microorganism	NOUN
eurjchem-990	156	30	,	,	PUNCT
eurjchem-990	156	31	disturbing	disturb	VERB
eurjchem-990	156	32	the	the	DET
eurjchem-990	156	33	respiration	respiration	NOUN
eurjchem-990	156	34	processes	process	NOUN
eurjchem-990	156	35	of	of	ADP
eurjchem-990	156	36	the	the	DET
eurjchem-990	156	37	cells	cell	NOUN
eurjchem-990	156	38	and	and	CCONJ
eurjchem-990	156	39	thus	thus	ADV
eurjchem-990	156	40	blocking	block	VERB
eurjchem-990	156	41	the	the	DET
eurjchem-990	156	42	protein	protein	NOUN
eurjchem-990	156	43	synthesis	synthesis	NOUN
eurjchem-990	156	44	that	that	PRON
eurjchem-990	156	45	is	be	AUX
eurjchem-990	156	46	required	require	VERB
eurjchem-990	156	47	for	for	ADP
eurjchem-990	156	48	further	further	ADJ
eurjchem-990	156	49	growth	growth	NOUN
eurjchem-990	156	50	of	of	ADP
eurjchem-990	156	51	the	the	DET
eurjchem-990	156	52	organisms	organism	NOUN
eurjchem-990	156	53	.	.	PUNCT
eurjchem-990	157	1	hence	hence	ADV
eurjchem-990	157	2	,	,	PUNCT
eurjchem-990	157	3	metal	metal	NOUN
eurjchem-990	157	4	ions	ion	NOUN
eurjchem-990	157	5	are	be	AUX
eurjchem-990	157	6	essential	essential	ADJ
eurjchem-990	157	7	for	for	ADP
eurjchem-990	157	8	the	the	DET
eurjchem-990	157	9	growth‐	growth‐	ADJ
eurjchem-990	157	10	inhibitory	inhibitory	ADJ
eurjchem-990	157	11	effects	effect	NOUN
eurjchem-990	157	12	[	[	X
eurjchem-990	157	13	56	56	NUM
eurjchem-990	157	14	]	]	PUNCT
eurjchem-990	157	15	.	.	PUNCT
eurjchem-990	158	1	the	the	DET
eurjchem-990	158	2	synthesized	synthesize	VERB
eurjchem-990	158	3	compounds	compound	NOUN
eurjchem-990	158	4	were	be	AUX
eurjchem-990	158	5	found	find	VERB
eurjchem-990	158	6	to	to	PART
eurjchem-990	158	7	be	be	AUX
eurjchem-990	158	8	more	more	ADV
eurjchem-990	158	9	toxic	toxic	ADJ
eurjchem-990	158	10	compared	compare	VERB
eurjchem-990	158	11	with	with	ADP
eurjchem-990	158	12	their	their	PRON
eurjchem-990	158	13	parent	parent	NOUN
eurjchem-990	158	14	free	free	ADJ
eurjchem-990	158	15	ligands	ligand	NOUN
eurjchem-990	158	16	against	against	ADP
eurjchem-990	158	17	the	the	DET
eurjchem-990	158	18	same	same	ADJ
eurjchem-990	158	19	micro‐organism	micro‐organism	NOUN
eurjchem-990	158	20	and	and	CCONJ
eurjchem-990	158	21	under	under	ADP
eurjchem-990	158	22	the	the	DET
eurjchem-990	158	23	identical	identical	ADJ
eurjchem-990	158	24	experimental	experimental	ADJ
eurjchem-990	158	25	conditions	condition	NOUN
eurjchem-990	158	26	.	.	PUNCT
eurjchem-990	159	1	256	256	NUM
eurjchem-990	159	2	mohamed	mohame	VERB
eurjchem-990	159	3	et	et	PROPN
eurjchem-990	159	4	al	al	PROPN
eurjchem-990	159	5	.	.	PUNCT
eurjchem-990	159	6	/	/	SYM
eurjchem-990	159	7	european	european	PROPN
eurjchem-990	159	8	journal	journal	PROPN
eurjchem-990	159	9	of	of	ADP
eurjchem-990	159	10	chemistry	chemistry	NOUN
eurjchem-990	159	11	5	5	NUM
eurjchem-990	159	12	(	(	PUNCT
eurjchem-990	159	13	2	2	NUM
eurjchem-990	159	14	)	)	PUNCT
eurjchem-990	159	15	(	(	PUNCT
eurjchem-990	159	16	2014	2014	NUM
eurjchem-990	159	17	)	)	PUNCT
eurjchem-990	159	18	252‐259	252‐259	NOUN
eurjchem-990	159	19	table	table	NOUN
eurjchem-990	159	20	4	4	NUM
eurjchem-990	159	21	.	.	PUNCT
eurjchem-990	159	22	antibacterial	antibacterial	ADJ
eurjchem-990	159	23	activity	activity	NOUN
eurjchem-990	159	24	of	of	ADP
eurjchem-990	159	25	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-990	159	26	ligand	ligand	NOUN
eurjchem-990	159	27	and	and	CCONJ
eurjchem-990	159	28	its	its	PRON
eurjchem-990	159	29	metal	metal	NOUN
eurjchem-990	159	30	complexes	complex	NOUN
eurjchem-990	159	31	.	.	PUNCT
eurjchem-990	160	1	compounds	compound	VERB
eurjchem-990	160	2	diameter	diameter	NOUN
eurjchem-990	160	3	of	of	ADP
eurjchem-990	160	4	inhibition	inhibition	NOUN
eurjchem-990	160	5	zone	zone	NOUN
eurjchem-990	160	6	(	(	PUNCT
eurjchem-990	160	7	in	in	ADP
eurjchem-990	160	8	mm	mm	PROPN
eurjchem-990	160	9	)	)	PUNCT
eurjchem-990	160	10	a	a	DET
eurjchem-990	160	11	(	(	PUNCT
eurjchem-990	160	12	g‐	g‐	NOUN
eurjchem-990	160	13	)	)	PUNCT
eurjchem-990	160	14	(	(	PUNCT
eurjchem-990	160	15	g+	g+	NOUN
eurjchem-990	160	16	)	)	PUNCT
eurjchem-990	160	17	escherichia	escherichia	NOUN
eurjchem-990	160	18	coli	coli	NOUN
eurjchem-990	160	19	(	(	PUNCT
eurjchem-990	160	20	rcmb	rcmb	NOUN
eurjchem-990	160	21	010052	010052	NUM
eurjchem-990	160	22	)	)	PUNCT
eurjchem-990	160	23	pseudomonas	pseudomona	VERB
eurjchem-990	160	24	aeuroginosa	aeuroginosa	NOUN
eurjchem-990	160	25	(	(	PUNCT
eurjchem-990	160	26	rcmb	rcmb	NOUN
eurjchem-990	160	27	010043	010043	NUM
eurjchem-990	160	28	)	)	PUNCT
eurjchem-990	160	29	staphylococcus	staphylococcus	NOUN
eurjchem-990	160	30	aureus	aureus	NOUN
eurjchem-990	160	31	(	(	PUNCT
eurjchem-990	160	32	rcmb	rcmb	NOUN
eurjchem-990	160	33	010028	010028	NUM
eurjchem-990	160	34	)	)	PUNCT
eurjchem-990	161	1	bacillus	bacillus	NOUN
eurjchem-990	161	2	subtillis	subtillis	NOUN
eurjchem-990	161	3	(	(	PUNCT
eurjchem-990	161	4	rcmb	rcmb	NOUN
eurjchem-990	161	5	010067	010067	NUM
eurjchem-990	161	6	)	)	PUNCT
eurjchem-990	161	7	ephc	ephc	NOUN
eurjchem-990	161	8	11.2±0.52	11.2±0.52	NUM
eurjchem-990	161	9	12.2±0.34	12.2±0.34	NUM
eurjchem-990	161	10	20.1±0.45	20.1±0.45	NUM
eurjchem-990	161	11	19.9±0.79	19.9±0.79	NUM
eurjchem-990	162	1	[	[	X
eurjchem-990	162	2	cu(ephc)(1,10‐phen)cl	cu(ephc)(1,10‐phen)cl	X
eurjchem-990	162	3	]	]	X
eurjchem-990	162	4	(	(	PUNCT
eurjchem-990	162	5	1	1	X
eurjchem-990	162	6	)	)	PUNCT
eurjchem-990	162	7	19.9±0.47	19.9±0.47	NUM
eurjchem-990	162	8	17.1±0.19	17.1±0.19	NUM
eurjchem-990	162	9	31.2±0.25	31.2±0.25	NUM
eurjchem-990	162	10	26.7±0.62	26.7±0.62	NUM
eurjchem-990	162	11	[	[	X
eurjchem-990	162	12	ni(ephc)(1,10‐phen)cl].h2o	ni(ephc)(1,10‐phen)cl].h2o	PROPN
eurjchem-990	162	13	(	(	PUNCT
eurjchem-990	162	14	2	2	NUM
eurjchem-990	162	15	)	)	PUNCT
eurjchem-990	162	16	16.4±0.44	16.4±0.44	NUM
eurjchem-990	162	17	16.4±0.22	16.4±0.22	NUM
eurjchem-990	162	18	28.7±0.24	28.7±0.24	NUM
eurjchem-990	162	19	25.3±0.32	25.3±0.32	NUM
eurjchem-990	163	1	[	[	X
eurjchem-990	163	2	co(ephc)(1,10‐phen)cl].h2o	co(ephc)(1,10‐phen)cl].h2o	NOUN
eurjchem-990	163	3	(	(	PUNCT
eurjchem-990	163	4	3	3	NUM
eurjchem-990	163	5	)	)	PUNCT
eurjchem-990	163	6	15.8±0.53	15.8±0.53	NUM
eurjchem-990	163	7	13.8±0.34	13.8±0.34	NUM
eurjchem-990	163	8	24.9±0.65	24.9±0.65	NUM
eurjchem-990	163	9	22.3±0.69	22.3±0.69	NUM
eurjchem-990	163	10	[	[	X
eurjchem-990	163	11	mn(ephc)(1,10‐phen)cl].2h2o	mn(ephc)(1,10‐phen)cl].2h2o	NOUN
eurjchem-990	163	12	(	(	PUNCT
eurjchem-990	163	13	4	4	NUM
eurjchem-990	163	14	)	)	PUNCT
eurjchem-990	163	15	14.5±0.25	14.5±0.25	NUM
eurjchem-990	163	16	13.1±0.25	13.1±0.25	NUM
eurjchem-990	163	17	23.8±0.39	23.8±0.39	NUM
eurjchem-990	163	18	20.8±0.87	20.8±0.87	NUM
eurjchem-990	163	19	standard	standard	ADJ
eurjchem-990	163	20	b	b	PROPN
eurjchem-990	163	21	22.3±0.18	22.3±0.18	NUM
eurjchem-990	163	22	17.3±0.15	17.3±0.15	NUM
eurjchem-990	163	23	32.4±0.10	32.4±0.10	NUM
eurjchem-990	163	24	27.4±0.18	27.4±0.18	NUM
eurjchem-990	163	25	a	a	DET
eurjchem-990	163	26	mean	mean	ADJ
eurjchem-990	163	27	zone	zone	NOUN
eurjchem-990	163	28	of	of	ADP
eurjchem-990	163	29	inhibition	inhibition	NOUN
eurjchem-990	163	30	in	in	ADP
eurjchem-990	163	31	mm±standard	mm±standard	NOUN
eurjchem-990	163	32	deviation	deviation	NOUN
eurjchem-990	163	33	beyond	beyond	ADP
eurjchem-990	163	34	well	well	INTJ
eurjchem-990	163	35	diameter	diameter	NOUN
eurjchem-990	163	36	(	(	PUNCT
eurjchem-990	163	37	6	6	NUM
eurjchem-990	163	38	mm	mm	NOUN
eurjchem-990	163	39	)	)	PUNCT
eurjchem-990	163	40	produced	produce	VERB
eurjchem-990	163	41	on	on	ADP
eurjchem-990	163	42	a	a	DET
eurjchem-990	163	43	range	range	NOUN
eurjchem-990	163	44	of	of	ADP
eurjchem-990	163	45	environmental	environmental	ADJ
eurjchem-990	163	46	and	and	CCONJ
eurjchem-990	163	47	clinically	clinically	ADV
eurjchem-990	163	48	pathogenic	pathogenic	ADJ
eurjchem-990	163	49	microorganisms	microorganism	NOUN
eurjchem-990	163	50	using	use	VERB
eurjchem-990	163	51	(	(	PUNCT
eurjchem-990	163	52	1	1	NUM
eurjchem-990	163	53	mg	mg	NUM
eurjchem-990	163	54	/	/	SYM
eurjchem-990	163	55	ml	ml	NOUN
eurjchem-990	163	56	)	)	PUNCT
eurjchem-990	163	57	concentration	concentration	NOUN
eurjchem-990	163	58	of	of	ADP
eurjchem-990	163	59	tested	test	VERB
eurjchem-990	163	60	samples	sample	NOUN
eurjchem-990	163	61	.	.	PUNCT
eurjchem-990	164	1	b	b	X
eurjchem-990	164	2	the	the	DET
eurjchem-990	164	3	standard	standard	ADJ
eurjchem-990	164	4	antibacterial	antibacterial	ADJ
eurjchem-990	164	5	agents	agent	NOUN
eurjchem-990	164	6	used	use	VERB
eurjchem-990	164	7	are	be	AUX
eurjchem-990	164	8	gentamicin	gentamicin	VERB
eurjchem-990	164	9	for	for	ADP
eurjchem-990	164	10	g‐	g‐	PROPN
eurjchem-990	164	11	and	and	CCONJ
eurjchem-990	164	12	ampicillin	ampicillin	NOUN
eurjchem-990	164	13	for	for	ADP
eurjchem-990	164	14	g+	g+	PROPN
eurjchem-990	164	15	.	.	PUNCT
eurjchem-990	164	16	table	table	NOUN
eurjchem-990	165	1	5	5	NUM
eurjchem-990	165	2	.	.	PUNCT
eurjchem-990	165	3	antifungal	antifungal	ADJ
eurjchem-990	165	4	activity	activity	NOUN
eurjchem-990	165	5	of	of	ADP
eurjchem-990	165	6	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-990	165	7	ligand	ligand	NOUN
eurjchem-990	165	8	and	and	CCONJ
eurjchem-990	165	9	its	its	PRON
eurjchem-990	165	10	metal	metal	NOUN
eurjchem-990	165	11	complexes	complex	NOUN
eurjchem-990	165	12	.	.	PUNCT
eurjchem-990	166	1	compounds	compound	VERB
eurjchem-990	166	2	diameter	diameter	NOUN
eurjchem-990	166	3	of	of	ADP
eurjchem-990	166	4	inhibition	inhibition	NOUN
eurjchem-990	166	5	zone	zone	NOUN
eurjchem-990	166	6	(	(	PUNCT
eurjchem-990	166	7	in	in	ADP
eurjchem-990	166	8	mm	mm	PROPN
eurjchem-990	166	9	)	)	PUNCT
eurjchem-990	166	10	a	a	DET
eurjchem-990	166	11	aspergillus	aspergillus	NOUN
eurjchem-990	166	12	flavus	flavus	NOUN
eurjchem-990	166	13	(	(	PUNCT
eurjchem-990	166	14	rcmb	rcmb	NOUN
eurjchem-990	166	15	02568	02568	NUM
eurjchem-990	166	16	)	)	PUNCT
eurjchem-990	167	1	pencicillium	pencicillium	NOUN
eurjchem-990	167	2	italicum	italicum	NOUN
eurjchem-990	167	3	(	(	PUNCT
eurjchem-990	167	4	rcmb	rcmb	NOUN
eurjchem-990	167	5	03924	03924	NUM
eurjchem-990	167	6	)	)	PUNCT
eurjchem-990	167	7	geotricum	geotricum	NOUN
eurjchem-990	167	8	candidum	candidum	NOUN
eurjchem-990	167	9	(	(	PUNCT
eurjchem-990	167	10	rcmb	rcmb	NOUN
eurjchem-990	167	11	05097	05097	NUM
eurjchem-990	167	12	)	)	PUNCT
eurjchem-990	167	13	ephc	ephc	NOUN
eurjchem-990	167	14	12.6±0.58	12.6±0.58	NUM
eurjchem-990	167	15	13.2±0.24	13.2±0.24	NUM
eurjchem-990	167	16	15.7±0.29	15.7±0.29	NUM
eurjchem-990	167	17	[	[	X
eurjchem-990	167	18	cu(ephc)(1,10‐phen)cl	cu(ephc)(1,10‐phen)cl	X
eurjchem-990	167	19	]	]	X
eurjchem-990	167	20	(	(	PUNCT
eurjchem-990	167	21	1	1	X
eurjchem-990	167	22	)	)	PUNCT
eurjchem-990	167	23	22.9±0.50	22.9±0.50	NUM
eurjchem-990	167	24	18.2±0.38	18.2±0.38	NUM
eurjchem-990	167	25	26.5±0.18	26.5±0.18	NUM
eurjchem-990	167	26	[	[	PUNCT
eurjchem-990	167	27	ni(ephc)(1,10‐phen)cl].h2o	ni(ephc)(1,10‐phen)cl].h2o	PROPN
eurjchem-990	167	28	(	(	PUNCT
eurjchem-990	167	29	2	2	NUM
eurjchem-990	167	30	)	)	PUNCT
eurjchem-990	167	31	21.2±0.58	21.2±0.58	NUM
eurjchem-990	167	32	16.9±0.54	16.9±0.54	NUM
eurjchem-990	167	33	24.4±0.32	24.4±0.32	NUM
eurjchem-990	168	1	[	[	X
eurjchem-990	168	2	co(ephc)(1,10‐phen)cl].h2o	co(ephc)(1,10‐phen)cl].h2o	NOUN
eurjchem-990	168	3	(	(	PUNCT
eurjchem-990	168	4	3	3	NUM
eurjchem-990	168	5	)	)	PUNCT
eurjchem-990	168	6	20.6±0.25	20.6±0.25	NUM
eurjchem-990	168	7	14.7±0.24	14.7±0.24	NUM
eurjchem-990	168	8	21.7±0.75	21.7±0.75	NUM
eurjchem-990	169	1	[	[	NOUN
eurjchem-990	169	2	mn(ephc)(1,10‐phen)cl].2h2o	mn(ephc)(1,10‐phen)cl].2h2o	NOUN
eurjchem-990	169	3	(	(	PUNCT
eurjchem-990	169	4	4	4	NUM
eurjchem-990	169	5	)	)	PUNCT
eurjchem-990	169	6	18.6±0.47	18.6±0.47	NUM
eurjchem-990	169	7	14.1±0.37	14.1±0.37	NUM
eurjchem-990	169	8	19.8±0.53	19.8±0.53	NUM
eurjchem-990	169	9	amphotericin	amphotericin	ADP
eurjchem-990	169	10	(	(	PUNCT
eurjchem-990	169	11	b	b	NOUN
eurjchem-990	169	12	)	)	PUNCT
eurjchem-990	169	13	23.7±0.10	23.7±0.10	NUM
eurjchem-990	169	14	21.9±0.12	21.9±0.12	NUM
eurjchem-990	169	15	28.7±0.22	28.7±0.22	NUM
eurjchem-990	169	16	a	a	DET
eurjchem-990	169	17	mean	mean	ADJ
eurjchem-990	169	18	zone	zone	NOUN
eurjchem-990	169	19	of	of	ADP
eurjchem-990	169	20	inhibition	inhibition	NOUN
eurjchem-990	169	21	in	in	ADP
eurjchem-990	169	22	mm±standard	mm±standard	NOUN
eurjchem-990	169	23	deviation	deviation	NOUN
eurjchem-990	169	24	beyond	beyond	ADP
eurjchem-990	169	25	well	well	INTJ
eurjchem-990	169	26	diameter	diameter	NOUN
eurjchem-990	169	27	(	(	PUNCT
eurjchem-990	169	28	6	6	NUM
eurjchem-990	169	29	mm	mm	NOUN
eurjchem-990	169	30	)	)	PUNCT
eurjchem-990	169	31	produced	produce	VERB
eurjchem-990	169	32	on	on	ADP
eurjchem-990	169	33	a	a	DET
eurjchem-990	169	34	range	range	NOUN
eurjchem-990	169	35	of	of	ADP
eurjchem-990	169	36	environmental	environmental	ADJ
eurjchem-990	169	37	and	and	CCONJ
eurjchem-990	169	38	clinically	clinically	ADV
eurjchem-990	169	39	pathogenic	pathogenic	ADJ
eurjchem-990	169	40	microorganisms	microorganism	NOUN
eurjchem-990	169	41	using	use	VERB
eurjchem-990	169	42	(	(	PUNCT
eurjchem-990	169	43	1	1	NUM
eurjchem-990	169	44	mg	mg	NUM
eurjchem-990	169	45	/	/	SYM
eurjchem-990	169	46	ml	ml	NOUN
eurjchem-990	169	47	)	)	PUNCT
eurjchem-990	169	48	concentration	concentration	NOUN
eurjchem-990	169	49	of	of	ADP
eurjchem-990	169	50	tested	test	VERB
eurjchem-990	169	51	samples	sample	NOUN
eurjchem-990	169	52	.	.	PUNCT
eurjchem-990	170	1	according	accord	VERB
eurjchem-990	170	2	to	to	ADP
eurjchem-990	170	3	overtone	overtone	NOUN
eurjchem-990	170	4	’s	’s	PART
eurjchem-990	170	5	concept	concept	NOUN
eurjchem-990	170	6	of	of	ADP
eurjchem-990	170	7	cell	cell	NOUN
eurjchem-990	170	8	permeability	permeability	NOUN
eurjchem-990	170	9	,	,	PUNCT
eurjchem-990	170	10	the	the	DET
eurjchem-990	170	11	lipid	lipid	NOUN
eurjchem-990	170	12	membrane	membrane	NOUN
eurjchem-990	170	13	that	that	PRON
eurjchem-990	170	14	surrounds	surround	VERB
eurjchem-990	170	15	the	the	DET
eurjchem-990	170	16	cell	cell	NOUN
eurjchem-990	170	17	favors	favor	VERB
eurjchem-990	170	18	the	the	DET
eurjchem-990	170	19	passage	passage	NOUN
eurjchem-990	170	20	of	of	ADP
eurjchem-990	170	21	only	only	ADJ
eurjchem-990	170	22	lipid‐soluble	lipid‐soluble	ADJ
eurjchem-990	170	23	materials	material	NOUN
eurjchem-990	170	24	,	,	PUNCT
eurjchem-990	170	25	so	so	CCONJ
eurjchem-990	170	26	lipophilicity	lipophilicity	NOUN
eurjchem-990	170	27	is	be	AUX
eurjchem-990	170	28	an	an	DET
eurjchem-990	170	29	important	important	ADJ
eurjchem-990	170	30	factor	factor	NOUN
eurjchem-990	170	31	controlling	control	VERB
eurjchem-990	170	32	the	the	DET
eurjchem-990	170	33	antifungal	antifungal	ADJ
eurjchem-990	170	34	activity	activity	NOUN
eurjchem-990	170	35	.	.	PUNCT
eurjchem-990	171	1	upon	upon	SCONJ
eurjchem-990	171	2	chelating	chelating	NOUN
eurjchem-990	171	3	,	,	PUNCT
eurjchem-990	171	4	the	the	DET
eurjchem-990	171	5	polarity	polarity	NOUN
eurjchem-990	171	6	of	of	ADP
eurjchem-990	171	7	the	the	DET
eurjchem-990	171	8	metal	metal	NOUN
eurjchem-990	171	9	ion	ion	NOUN
eurjchem-990	171	10	will	will	AUX
eurjchem-990	171	11	be	be	AUX
eurjchem-990	171	12	reduced	reduce	VERB
eurjchem-990	171	13	due	due	ADP
eurjchem-990	171	14	to	to	ADP
eurjchem-990	171	15	the	the	DET
eurjchem-990	171	16	overlap	overlap	NOUN
eurjchem-990	171	17	of	of	ADP
eurjchem-990	171	18	the	the	DET
eurjchem-990	171	19	ligand	ligand	NOUN
eurjchem-990	171	20	orbitals	orbital	NOUN
eurjchem-990	171	21	and	and	CCONJ
eurjchem-990	171	22	partial	partial	ADJ
eurjchem-990	171	23	sharing	sharing	NOUN
eurjchem-990	171	24	of	of	ADP
eurjchem-990	171	25	the	the	DET
eurjchem-990	171	26	positive	positive	ADJ
eurjchem-990	171	27	charge	charge	NOUN
eurjchem-990	171	28	of	of	ADP
eurjchem-990	171	29	the	the	DET
eurjchem-990	171	30	metal	metal	NOUN
eurjchem-990	171	31	ion	ion	NOUN
eurjchem-990	171	32	with	with	ADP
eurjchem-990	171	33	donor	donor	NOUN
eurjchem-990	171	34	groups	group	NOUN
eurjchem-990	171	35	.	.	PUNCT
eurjchem-990	172	1	in	in	ADP
eurjchem-990	172	2	addition	addition	NOUN
eurjchem-990	172	3	,	,	PUNCT
eurjchem-990	172	4	chelation	chelation	NOUN
eurjchem-990	172	5	allows	allow	VERB
eurjchem-990	172	6	for	for	ADP
eurjchem-990	172	7	the	the	DET
eurjchem-990	172	8	delocalization	delocalization	NOUN
eurjchem-990	172	9	of	of	ADP
eurjchem-990	172	10	π‐electrons	π‐electron	NOUN
eurjchem-990	172	11	over	over	ADP
eurjchem-990	172	12	the	the	DET
eurjchem-990	172	13	entire	entire	ADJ
eurjchem-990	172	14	chelate	chelate	NOUN
eurjchem-990	172	15	ring	ring	NOUN
eurjchem-990	172	16	and	and	CCONJ
eurjchem-990	172	17	enhances	enhance	VERB
eurjchem-990	172	18	the	the	DET
eurjchem-990	172	19	lipophilicity	lipophilicity	NOUN
eurjchem-990	172	20	of	of	ADP
eurjchem-990	172	21	the	the	DET
eurjchem-990	172	22	complexes	complex	NOUN
eurjchem-990	172	23	.	.	PUNCT
eurjchem-990	173	1	this	this	DET
eurjchem-990	173	2	increased	increase	VERB
eurjchem-990	173	3	lipophilicity	lipophilicity	NOUN
eurjchem-990	173	4	facilitates	facilitate	VERB
eurjchem-990	173	5	the	the	DET
eurjchem-990	173	6	penetration	penetration	NOUN
eurjchem-990	173	7	of	of	ADP
eurjchem-990	173	8	the	the	DET
eurjchem-990	173	9	complexes	complex	NOUN
eurjchem-990	173	10	into	into	ADP
eurjchem-990	173	11	lipid	lipid	ADJ
eurjchem-990	173	12	membranes	membrane	NOUN
eurjchem-990	173	13	,	,	PUNCT
eurjchem-990	173	14	further	far	ADV
eurjchem-990	173	15	restricting	restrict	VERB
eurjchem-990	173	16	proliferation	proliferation	NOUN
eurjchem-990	173	17	of	of	ADP
eurjchem-990	173	18	the	the	DET
eurjchem-990	173	19	microorganisms	microorganism	NOUN
eurjchem-990	173	20	.	.	PUNCT
eurjchem-990	174	1	the	the	DET
eurjchem-990	174	2	variation	variation	NOUN
eurjchem-990	174	3	in	in	ADP
eurjchem-990	174	4	the	the	DET
eurjchem-990	174	5	effectiveness	effectiveness	NOUN
eurjchem-990	174	6	of	of	ADP
eurjchem-990	174	7	different	different	ADJ
eurjchem-990	174	8	compounds	compound	NOUN
eurjchem-990	174	9	against	against	ADP
eurjchem-990	174	10	different	different	ADJ
eurjchem-990	174	11	organisms	organism	NOUN
eurjchem-990	174	12	depends	depend	VERB
eurjchem-990	174	13	either	either	CCONJ
eurjchem-990	174	14	on	on	ADP
eurjchem-990	174	15	the	the	DET
eurjchem-990	174	16	impermeability	impermeability	NOUN
eurjchem-990	174	17	of	of	ADP
eurjchem-990	174	18	the	the	DET
eurjchem-990	174	19	microbial	microbial	ADJ
eurjchem-990	174	20	cells	cell	NOUN
eurjchem-990	174	21	or	or	CCONJ
eurjchem-990	174	22	on	on	ADP
eurjchem-990	174	23	differences	difference	NOUN
eurjchem-990	174	24	in	in	ADP
eurjchem-990	174	25	the	the	DET
eurjchem-990	174	26	ribosomes	ribosome	NOUN
eurjchem-990	174	27	of	of	ADP
eurjchem-990	174	28	the	the	DET
eurjchem-990	174	29	cells	cell	NOUN
eurjchem-990	174	30	[	[	X
eurjchem-990	174	31	57‐59	57‐59	NUM
eurjchem-990	174	32	]	]	PUNCT
eurjchem-990	174	33	.	.	PUNCT
eurjchem-990	175	1	all	all	PRON
eurjchem-990	175	2	of	of	ADP
eurjchem-990	175	3	the	the	DET
eurjchem-990	175	4	metal	metal	NOUN
eurjchem-990	175	5	complexes	complex	NOUN
eurjchem-990	175	6	possess	possess	VERB
eurjchem-990	175	7	higher	high	ADJ
eurjchem-990	175	8	antifungal	antifungal	ADJ
eurjchem-990	175	9	activity	activity	NOUN
eurjchem-990	175	10	than	than	ADP
eurjchem-990	175	11	the	the	DET
eurjchem-990	175	12	ligand	ligand	NOUN
eurjchem-990	175	13	[	[	X
eurjchem-990	175	14	60‐63	60‐63	NUM
eurjchem-990	175	15	]	]	PUNCT
eurjchem-990	175	16	.	.	PUNCT
eurjchem-990	176	1	although	although	SCONJ
eurjchem-990	176	2	the	the	DET
eurjchem-990	176	3	exact	exact	ADJ
eurjchem-990	176	4	biochemical	biochemical	ADJ
eurjchem-990	176	5	mechanism	mechanism	NOUN
eurjchem-990	176	6	is	be	AUX
eurjchem-990	176	7	not	not	PART
eurjchem-990	176	8	completely	completely	ADV
eurjchem-990	176	9	understood	understand	VERB
eurjchem-990	176	10	,	,	PUNCT
eurjchem-990	176	11	the	the	DET
eurjchem-990	176	12	mode	mode	NOUN
eurjchem-990	176	13	of	of	ADP
eurjchem-990	176	14	action	action	NOUN
eurjchem-990	176	15	of	of	ADP
eurjchem-990	176	16	antimicrobials	antimicrobial	NOUN
eurjchem-990	176	17	may	may	AUX
eurjchem-990	176	18	involve	involve	VERB
eurjchem-990	176	19	various	various	ADJ
eurjchem-990	176	20	targets	target	NOUN
eurjchem-990	176	21	in	in	ADP
eurjchem-990	176	22	the	the	DET
eurjchem-990	176	23	microorganisms	microorganism	NOUN
eurjchem-990	176	24	.	.	PUNCT
eurjchem-990	177	1	these	these	DET
eurjchem-990	177	2	targets	target	NOUN
eurjchem-990	177	3	include	include	VERB
eurjchem-990	177	4	the	the	DET
eurjchem-990	177	5	following	following	NOUN
eurjchem-990	177	6	.	.	PUNCT
eurjchem-990	178	1	(	(	PUNCT
eurjchem-990	178	2	i	i	NOUN
eurjchem-990	178	3	)	)	PUNCT
eurjchem-990	178	4	the	the	DET
eurjchem-990	178	5	higher	high	ADJ
eurjchem-990	178	6	activity	activity	NOUN
eurjchem-990	178	7	of	of	ADP
eurjchem-990	178	8	the	the	DET
eurjchem-990	178	9	metal	metal	NOUN
eurjchem-990	178	10	complexes	complex	NOUN
eurjchem-990	178	11	may	may	AUX
eurjchem-990	178	12	be	be	AUX
eurjchem-990	178	13	due	due	ADJ
eurjchem-990	178	14	to	to	ADP
eurjchem-990	178	15	the	the	DET
eurjchem-990	178	16	different	different	ADJ
eurjchem-990	178	17	properties	property	NOUN
eurjchem-990	178	18	of	of	ADP
eurjchem-990	178	19	the	the	DET
eurjchem-990	178	20	metal	metal	NOUN
eurjchem-990	178	21	ions	ion	NOUN
eurjchem-990	178	22	upon	upon	SCONJ
eurjchem-990	178	23	chelation	chelation	NOUN
eurjchem-990	178	24	.	.	PUNCT
eurjchem-990	179	1	the	the	DET
eurjchem-990	179	2	polarity	polarity	NOUN
eurjchem-990	179	3	of	of	ADP
eurjchem-990	179	4	the	the	DET
eurjchem-990	179	5	metal	metal	NOUN
eurjchem-990	179	6	ions	ion	NOUN
eurjchem-990	179	7	will	will	AUX
eurjchem-990	179	8	be	be	AUX
eurjchem-990	179	9	reduced	reduce	VERB
eurjchem-990	179	10	due	due	ADP
eurjchem-990	179	11	to	to	ADP
eurjchem-990	179	12	the	the	DET
eurjchem-990	179	13	overlap	overlap	NOUN
eurjchem-990	179	14	of	of	ADP
eurjchem-990	179	15	the	the	DET
eurjchem-990	179	16	ligand	ligand	NOUN
eurjchem-990	179	17	orbitals	orbital	NOUN
eurjchem-990	179	18	and	and	CCONJ
eurjchem-990	179	19	partial	partial	ADJ
eurjchem-990	179	20	sharing	sharing	NOUN
eurjchem-990	179	21	of	of	ADP
eurjchem-990	179	22	the	the	DET
eurjchem-990	179	23	positive	positive	ADJ
eurjchem-990	179	24	charge	charge	NOUN
eurjchem-990	179	25	of	of	ADP
eurjchem-990	179	26	the	the	DET
eurjchem-990	179	27	metal	metal	NOUN
eurjchem-990	179	28	ion	ion	NOUN
eurjchem-990	179	29	with	with	ADP
eurjchem-990	179	30	donor	donor	NOUN
eurjchem-990	179	31	groups	group	NOUN
eurjchem-990	179	32	.	.	PUNCT
eurjchem-990	180	1	thus	thus	ADV
eurjchem-990	180	2	,	,	PUNCT
eurjchem-990	180	3	chelation	chelation	NOUN
eurjchem-990	180	4	enhances	enhance	VERB
eurjchem-990	180	5	the	the	DET
eurjchem-990	180	6	penetration	penetration	NOUN
eurjchem-990	180	7	of	of	ADP
eurjchem-990	180	8	the	the	DET
eurjchem-990	180	9	complexes	complex	NOUN
eurjchem-990	180	10	into	into	ADP
eurjchem-990	180	11	lipid	lipid	ADJ
eurjchem-990	180	12	membranes	membrane	NOUN
eurjchem-990	180	13	and	and	CCONJ
eurjchem-990	180	14	the	the	DET
eurjchem-990	180	15	blockage	blockage	NOUN
eurjchem-990	180	16	of	of	ADP
eurjchem-990	180	17	metal	metal	NOUN
eurjchem-990	180	18	binding	bind	VERB
eurjchem-990	180	19	sites	site	NOUN
eurjchem-990	180	20	in	in	ADP
eurjchem-990	180	21	the	the	DET
eurjchem-990	180	22	enzymes	enzyme	NOUN
eurjchem-990	180	23	of	of	ADP
eurjchem-990	180	24	the	the	DET
eurjchem-990	180	25	microorganisms	microorganism	NOUN
eurjchem-990	180	26	[	[	X
eurjchem-990	180	27	64	64	NUM
eurjchem-990	180	28	]	]	PUNCT
eurjchem-990	180	29	.	.	PUNCT
eurjchem-990	181	1	(	(	PUNCT
eurjchem-990	181	2	ii	ii	X
eurjchem-990	181	3	)	)	PUNCT
eurjchem-990	181	4	tweedy	tweedy	PROPN
eurjchem-990	181	5	’s	’s	PART
eurjchem-990	181	6	chelation	chelation	NOUN
eurjchem-990	181	7	theory	theory	NOUN
eurjchem-990	181	8	predicts	predict	VERB
eurjchem-990	181	9	that	that	SCONJ
eurjchem-990	181	10	chelation	chelation	NOUN
eurjchem-990	181	11	reduces	reduce	VERB
eurjchem-990	181	12	the	the	DET
eurjchem-990	181	13	polarity	polarity	NOUN
eurjchem-990	181	14	of	of	ADP
eurjchem-990	181	15	the	the	DET
eurjchem-990	181	16	metal	metal	NOUN
eurjchem-990	181	17	atom	atom	NOUN
eurjchem-990	181	18	mainly	mainly	ADV
eurjchem-990	181	19	because	because	SCONJ
eurjchem-990	181	20	of	of	ADP
eurjchem-990	181	21	partial	partial	ADJ
eurjchem-990	181	22	sharing	sharing	NOUN
eurjchem-990	181	23	of	of	ADP
eurjchem-990	181	24	its	its	PRON
eurjchem-990	181	25	positive	positive	ADJ
eurjchem-990	181	26	charge	charge	NOUN
eurjchem-990	181	27	with	with	ADP
eurjchem-990	181	28	donor	donor	NOUN
eurjchem-990	181	29	groups	group	NOUN
eurjchem-990	181	30	and	and	CCONJ
eurjchem-990	181	31	possible	possible	ADJ
eurjchem-990	181	32	electron	electron	NOUN
eurjchem-990	181	33	delocalization	delocalization	NOUN
eurjchem-990	181	34	over	over	ADP
eurjchem-990	181	35	the	the	DET
eurjchem-990	181	36	entire	entire	ADJ
eurjchem-990	181	37	ring	ring	NOUN
eurjchem-990	181	38	.	.	PUNCT
eurjchem-990	182	1	this	this	PRON
eurjchem-990	182	2	consequently	consequently	ADV
eurjchem-990	182	3	increases	increase	VERB
eurjchem-990	182	4	the	the	DET
eurjchem-990	182	5	lipophilic	lipophilic	ADJ
eurjchem-990	182	6	character	character	NOUN
eurjchem-990	182	7	of	of	ADP
eurjchem-990	182	8	the	the	DET
eurjchem-990	182	9	chelates	chelate	NOUN
eurjchem-990	182	10	,	,	PUNCT
eurjchem-990	182	11	favoring	favor	VERB
eurjchem-990	182	12	their	their	PRON
eurjchem-990	182	13	permeation	permeation	NOUN
eurjchem-990	182	14	through	through	ADP
eurjchem-990	182	15	the	the	DET
eurjchem-990	182	16	lipid	lipid	ADJ
eurjchem-990	182	17	layers	layer	NOUN
eurjchem-990	182	18	of	of	ADP
eurjchem-990	182	19	the	the	DET
eurjchem-990	182	20	bacterial	bacterial	ADJ
eurjchem-990	182	21	membrane	membrane	NOUN
eurjchem-990	182	22	[	[	X
eurjchem-990	182	23	65	65	NUM
eurjchem-990	182	24	]	]	PUNCT
eurjchem-990	182	25	.	.	PUNCT
eurjchem-990	183	1	(	(	PUNCT
eurjchem-990	183	2	iii	iii	X
eurjchem-990	183	3	)	)	PUNCT
eurjchem-990	183	4	interference	interference	NOUN
eurjchem-990	183	5	with	with	ADP
eurjchem-990	183	6	the	the	DET
eurjchem-990	183	7	synthesis	synthesis	NOUN
eurjchem-990	183	8	of	of	ADP
eurjchem-990	183	9	cellular	cellular	ADJ
eurjchem-990	183	10	walls	wall	NOUN
eurjchem-990	183	11	,	,	PUNCT
eurjchem-990	183	12	causing	cause	VERB
eurjchem-990	183	13	damage	damage	NOUN
eurjchem-990	183	14	that	that	PRON
eurjchem-990	183	15	can	can	AUX
eurjchem-990	183	16	lead	lead	VERB
eurjchem-990	183	17	to	to	ADP
eurjchem-990	183	18	altered	altered	ADJ
eurjchem-990	183	19	cell	cell	NOUN
eurjchem-990	183	20	permeability	permeability	NOUN
eurjchem-990	183	21	characteristics	characteristic	NOUN
eurjchem-990	183	22	or	or	CCONJ
eurjchem-990	183	23	disorganized	disorganized	ADJ
eurjchem-990	183	24	lipoprotein	lipoprotein	ADJ
eurjchem-990	183	25	arrangements	arrangement	NOUN
eurjchem-990	183	26	,	,	PUNCT
eurjchem-990	183	27	ultimately	ultimately	ADV
eurjchem-990	183	28	resulting	result	VERB
eurjchem-990	183	29	in	in	ADP
eurjchem-990	183	30	cell	cell	NOUN
eurjchem-990	183	31	death	death	NOUN
eurjchem-990	183	32	.	.	PUNCT
eurjchem-990	184	1	(	(	PUNCT
eurjchem-990	184	2	iv	iv	X
eurjchem-990	184	3	)	)	PUNCT
eurjchem-990	184	4	deactivation	deactivation	NOUN
eurjchem-990	184	5	of	of	ADP
eurjchem-990	184	6	various	various	ADJ
eurjchem-990	184	7	cellular	cellular	ADJ
eurjchem-990	184	8	enzymes	enzyme	NOUN
eurjchem-990	184	9	that	that	PRON
eurjchem-990	184	10	play	play	VERB
eurjchem-990	184	11	a	a	DET
eurjchem-990	184	12	vital	vital	ADJ
eurjchem-990	184	13	role	role	NOUN
eurjchem-990	184	14	in	in	ADP
eurjchem-990	184	15	the	the	DET
eurjchem-990	184	16	metabolic	metabolic	NOUN
eurjchem-990	184	17	pathways	pathway	NOUN
eurjchem-990	184	18	of	of	ADP
eurjchem-990	184	19	these	these	DET
eurjchem-990	184	20	microorganisms	microorganism	NOUN
eurjchem-990	184	21	.	.	PUNCT
eurjchem-990	185	1	(	(	PUNCT
eurjchem-990	185	2	v	v	NOUN
eurjchem-990	185	3	)	)	PUNCT
eurjchem-990	185	4	denaturation	denaturation	NOUN
eurjchem-990	185	5	of	of	ADP
eurjchem-990	185	6	one	one	NUM
eurjchem-990	185	7	or	or	CCONJ
eurjchem-990	185	8	more	more	ADJ
eurjchem-990	185	9	cellular	cellular	ADJ
eurjchem-990	185	10	proteins	protein	NOUN
eurjchem-990	185	11	,	,	PUNCT
eurjchem-990	185	12	causing	cause	VERB
eurjchem-990	185	13	the	the	DET
eurjchem-990	185	14	normal	normal	ADJ
eurjchem-990	185	15	cellular	cellular	ADJ
eurjchem-990	185	16	processes	process	NOUN
eurjchem-990	185	17	to	to	PART
eurjchem-990	185	18	be	be	AUX
eurjchem-990	185	19	impaired	impaired	ADJ
eurjchem-990	185	20	.	.	PUNCT
eurjchem-990	186	1	(	(	PUNCT
eurjchem-990	186	2	vi	vi	NOUN
eurjchem-990	186	3	)	)	PUNCT
eurjchem-990	186	4	formation	formation	NOUN
eurjchem-990	186	5	of	of	ADP
eurjchem-990	186	6	a	a	DET
eurjchem-990	186	7	hydrogen	hydrogen	NOUN
eurjchem-990	186	8	bond	bond	NOUN
eurjchem-990	186	9	through	through	ADP
eurjchem-990	186	10	the	the	DET
eurjchem-990	186	11	azomethine	azomethine	NOUN
eurjchem-990	186	12	group	group	NOUN
eurjchem-990	186	13	with	with	ADP
eurjchem-990	186	14	the	the	DET
eurjchem-990	186	15	active	active	ADJ
eurjchem-990	186	16	centers	center	NOUN
eurjchem-990	186	17	of	of	ADP
eurjchem-990	186	18	various	various	ADJ
eurjchem-990	186	19	cellular	cellular	ADJ
eurjchem-990	186	20	constituents	constituent	NOUN
eurjchem-990	186	21	,	,	PUNCT
eurjchem-990	186	22	resulting	result	VERB
eurjchem-990	186	23	in	in	ADP
eurjchem-990	186	24	interference	interference	NOUN
eurjchem-990	186	25	with	with	ADP
eurjchem-990	186	26	normal	normal	ADJ
eurjchem-990	186	27	cellular	cellular	ADJ
eurjchem-990	186	28	processes	process	NOUN
eurjchem-990	186	29	[	[	X
eurjchem-990	186	30	66‐68	66‐68	NOUN
eurjchem-990	186	31	]	]	PUNCT
eurjchem-990	186	32	.	.	PUNCT
eurjchem-990	187	1	the	the	DET
eurjchem-990	187	2	tested	test	VERB
eurjchem-990	187	3	complexes	complex	NOUN
eurjchem-990	187	4	were	be	AUX
eurjchem-990	187	5	more	more	ADV
eurjchem-990	187	6	active	active	ADJ
eurjchem-990	187	7	against	against	ADP
eurjchem-990	187	8	gram‐positive	gram‐positive	ADJ
eurjchem-990	187	9	than	than	ADP
eurjchem-990	187	10	gram‐negative	gram‐negative	ADJ
eurjchem-990	187	11	bacteria	bacteria	NOUN
eurjchem-990	187	12	,	,	PUNCT
eurjchem-990	187	13	it	it	PRON
eurjchem-990	187	14	may	may	AUX
eurjchem-990	187	15	be	be	AUX
eurjchem-990	187	16	concluded	conclude	VERB
eurjchem-990	187	17	that	that	SCONJ
eurjchem-990	187	18	the	the	DET
eurjchem-990	187	19	antibacterial	antibacterial	ADJ
eurjchem-990	187	20	activity	activity	NOUN
eurjchem-990	187	21	of	of	ADP
eurjchem-990	187	22	the	the	DET
eurjchem-990	187	23	compounds	compound	NOUN
eurjchem-990	187	24	is	be	AUX
eurjchem-990	187	25	related	relate	VERB
eurjchem-990	187	26	to	to	ADP
eurjchem-990	187	27	cell	cell	NOUN
eurjchem-990	187	28	wall	wall	NOUN
eurjchem-990	187	29	structure	structure	NOUN
eurjchem-990	187	30	of	of	ADP
eurjchem-990	187	31	the	the	DET
eurjchem-990	187	32	bacteria	bacteria	NOUN
eurjchem-990	187	33	(	(	PUNCT
eurjchem-990	187	34	figure	figure	NOUN
eurjchem-990	187	35	1	1	NUM
eurjchem-990	187	36	and	and	CCONJ
eurjchem-990	187	37	2	2	NUM
eurjchem-990	187	38	)	)	PUNCT
eurjchem-990	187	39	.	.	PUNCT
eurjchem-990	188	1	figure	figure	NOUN
eurjchem-990	188	2	1	1	NUM
eurjchem-990	188	3	.	.	PUNCT
eurjchem-990	188	4	antibacterial	antibacterial	ADJ
eurjchem-990	188	5	activity	activity	NOUN
eurjchem-990	188	6	of	of	ADP
eurjchem-990	188	7	m(ii)‐complexes	m(ii)‐complexe	NOUN
eurjchem-990	188	8	towards	towards	ADP
eurjchem-990	188	9	different	different	ADJ
eurjchem-990	188	10	types	type	NOUN
eurjchem-990	188	11	of	of	ADP
eurjchem-990	188	12	bacterial	bacterial	ADJ
eurjchem-990	188	13	strains	strain	NOUN
eurjchem-990	188	14	.	.	PUNCT
eurjchem-990	189	1	figure	figure	NOUN
eurjchem-990	189	2	2	2	NUM
eurjchem-990	189	3	.	.	PUNCT
eurjchem-990	189	4	antifungal	antifungal	ADJ
eurjchem-990	189	5	activity	activity	NOUN
eurjchem-990	189	6	of	of	ADP
eurjchem-990	189	7	m(ii)‐complexes	m(ii)‐complexe	NOUN
eurjchem-990	189	8	towards	towards	ADP
eurjchem-990	189	9	different	different	ADJ
eurjchem-990	189	10	types	type	NOUN
eurjchem-990	189	11	of	of	ADP
eurjchem-990	189	12	fungal	fungal	ADJ
eurjchem-990	189	13	strains	strain	NOUN
eurjchem-990	189	14	.	.	PUNCT
eurjchem-990	190	1	it	it	PRON
eurjchem-990	190	2	is	be	AUX
eurjchem-990	190	3	possible	possible	ADJ
eurjchem-990	190	4	because	because	SCONJ
eurjchem-990	190	5	the	the	DET
eurjchem-990	190	6	cell	cell	NOUN
eurjchem-990	190	7	wall	wall	NOUN
eurjchem-990	190	8	is	be	AUX
eurjchem-990	190	9	essential	essential	ADJ
eurjchem-990	190	10	to	to	ADP
eurjchem-990	190	11	the	the	DET
eurjchem-990	190	12	survival	survival	NOUN
eurjchem-990	190	13	of	of	ADP
eurjchem-990	190	14	bacteria	bacteria	NOUN
eurjchem-990	190	15	and	and	CCONJ
eurjchem-990	190	16	some	some	DET
eurjchem-990	190	17	antibiotics	antibiotic	NOUN
eurjchem-990	190	18	are	be	AUX
eurjchem-990	190	19	able	able	ADJ
eurjchem-990	190	20	to	to	PART
eurjchem-990	190	21	kill	kill	VERB
eurjchem-990	190	22	bacteria	bacteria	NOUN
eurjchem-990	190	23	by	by	ADP
eurjchem-990	190	24	inhibiting	inhibit	VERB
eurjchem-990	190	25	a	a	DET
eurjchem-990	190	26	step	step	NOUN
eurjchem-990	190	27	in	in	ADP
eurjchem-990	190	28	the	the	DET
eurjchem-990	190	29	synthesis	synthesis	NOUN
eurjchem-990	190	30	of	of	ADP
eurjchem-990	190	31	peptidoglycan	peptidoglycan	ADJ
eurjchem-990	190	32	.	.	PUNCT
eurjchem-990	191	1	gram‐positive	gram‐positive	ADJ
eurjchem-990	191	2	bacteria	bacteria	NOUN
eurjchem-990	191	3	possess	possess	VERB
eurjchem-990	191	4	a	a	DET
eurjchem-990	191	5	thick	thick	ADJ
eurjchem-990	191	6	cell	cell	NOUN
eurjchem-990	191	7	wall	wall	NOUN
eurjchem-990	191	8	containing	contain	VERB
eurjchem-990	191	9	many	many	ADJ
eurjchem-990	191	10	layers	layer	NOUN
eurjchem-990	191	11	of	of	ADP
eurjchem-990	191	12	peptidoglycan	peptidoglycan	ADJ
eurjchem-990	191	13	and	and	CCONJ
eurjchem-990	191	14	teichoic	teichoic	ADJ
eurjchem-990	191	15	acids	acid	NOUN
eurjchem-990	191	16	,	,	PUNCT
eurjchem-990	191	17	but	but	CCONJ
eurjchem-990	191	18	in	in	ADP
eurjchem-990	191	19	contrast	contrast	NOUN
eurjchem-990	191	20	,	,	PUNCT
eurjchem-990	191	21	gram	gram	PROPN
eurjchem-990	191	22	negative	negative	ADJ
eurjchem-990	191	23	bacteria	bacteria	NOUN
eurjchem-990	191	24	have	have	VERB
eurjchem-990	191	25	a	a	DET
eurjchem-990	191	26	relatively	relatively	ADV
eurjchem-990	191	27	thin	thin	ADJ
eurjchem-990	191	28	cell	cell	NOUN
eurjchem-990	191	29	wall	wall	NOUN
eurjchem-990	191	30	consisting	consist	VERB
eurjchem-990	191	31	of	of	ADP
eurjchem-990	191	32	a	a	DET
eurjchem-990	191	33	few	few	ADJ
eurjchem-990	191	34	layers	layer	NOUN
eurjchem-990	191	35	of	of	ADP
eurjchem-990	191	36	peptidoglycan	peptidoglycan	PROPN
eurjchem-990	191	37	surrounded	surround	VERB
eurjchem-990	191	38	by	by	ADP
eurjchem-990	191	39	a	a	DET
eurjchem-990	191	40	second	second	ADJ
eurjchem-990	191	41	lipid	lipid	NOUN
eurjchem-990	191	42	membrane	membrane	NOUN
eurjchem-990	191	43	containing	contain	VERB
eurjchem-990	191	44	lipopolysaccharides	lipopolysaccharide	NOUN
eurjchem-990	191	45	and	and	CCONJ
eurjchem-990	191	46	lipoproteins	lipoprotein	NOUN
eurjchem-990	191	47	.	.	PUNCT
eurjchem-990	192	1	mohamed	mohamed	PROPN
eurjchem-990	192	2	et	et	PROPN
eurjchem-990	192	3	al	al	PROPN
eurjchem-990	192	4	.	.	PUNCT
eurjchem-990	192	5	/	/	SYM
eurjchem-990	192	6	european	european	PROPN
eurjchem-990	192	7	journal	journal	PROPN
eurjchem-990	192	8	of	of	ADP
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eurjchem-990	192	11	(	(	PUNCT
eurjchem-990	192	12	2	2	NUM
eurjchem-990	192	13	)	)	PUNCT
eurjchem-990	192	14	(	(	PUNCT
eurjchem-990	192	15	2014	2014	NUM
eurjchem-990	192	16	)	)	PUNCT
eurjchem-990	192	17	252‐259	252‐259	NOUN
eurjchem-990	192	18	257	257	NUM
eurjchem-990	192	19	table	table	NOUN
eurjchem-990	192	20	6	6	NUM
eurjchem-990	192	21	.	.	PUNCT
eurjchem-990	193	1	some	some	DET
eurjchem-990	193	2	energetic	energetic	ADJ
eurjchem-990	193	3	properties	property	NOUN
eurjchem-990	193	4	of	of	ADP
eurjchem-990	193	5	ephc	ephc	NOUN
eurjchem-990	193	6	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-990	193	7	and	and	CCONJ
eurjchem-990	193	8	its	its	PRON
eurjchem-990	193	9	complexes	complex	NOUN
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eurjchem-990	193	11	by	by	ADP
eurjchem-990	193	12	pm3	pm3	PROPN
eurjchem-990	193	13	method	method	NOUN
eurjchem-990	193	14	.	.	PUNCT
eurjchem-990	194	1	ligand	ligand	PROPN
eurjchem-990	194	2	total	total	ADJ
eurjchem-990	194	3	energy	energy	NOUN
eurjchem-990	194	4	(	(	PUNCT
eurjchem-990	194	5	kcal	kcal	NOUN
eurjchem-990	194	6	/	/	SYM
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eurjchem-990	194	8	)	)	PUNCT
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eurjchem-990	194	10	energy	energy	NOUN
eurjchem-990	194	11	(	(	PUNCT
eurjchem-990	194	12	kcal	kcal	NOUN
eurjchem-990	194	13	/	/	SYM
eurjchem-990	194	14	mol	mol	NOUN
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eurjchem-990	194	16	electronic	electronic	ADJ
eurjchem-990	194	17	energy	energy	NOUN
eurjchem-990	194	18	(	(	PUNCT
eurjchem-990	194	19	kcal	kcal	NOUN
eurjchem-990	194	20	/	/	SYM
eurjchem-990	194	21	mol	mol	NOUN
eurjchem-990	194	22	)	)	PUNCT
eurjchem-990	194	23	dipole	dipole	NOUN
eurjchem-990	194	24	moment	moment	NOUN
eurjchem-990	194	25	(	(	PUNCT
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eurjchem-990	194	27	)	)	PUNCT
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eurjchem-990	194	29	(	(	PUNCT
eurjchem-990	194	30	ev	ev	NOUN
eurjchem-990	194	31	)	)	PUNCT
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eurjchem-990	194	33	(	(	PUNCT
eurjchem-990	194	34	ev	ev	INTJ
eurjchem-990	194	35	)	)	PUNCT
eurjchem-990	194	36	ephc	ephc	PROPN
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eurjchem-990	194	38	‐2698.41	‐2698.41	PUNCT
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eurjchem-990	194	41	‐9.02	‐9.02	NUM
eurjchem-990	194	42	‐0.90	‐0.90	PROPN
eurjchem-990	195	1	[	[	X
eurjchem-990	195	2	cu(ephc)(1,10‐phen)cl	cu(ephc)(1,10‐phen)cl	X
eurjchem-990	195	3	]	]	X
eurjchem-990	195	4	(	(	PUNCT
eurjchem-990	195	5	1	1	NUM
eurjchem-990	195	6	)	)	PUNCT
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eurjchem-990	196	4	2	2	NUM
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eurjchem-990	196	8	‐1128540.07	‐1128540.07	X
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eurjchem-990	197	1	[	[	X
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eurjchem-990	197	3	(	(	PUNCT
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eurjchem-990	198	1	[	[	X
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eurjchem-990	201	5	å	å	NOUN
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eurjchem-990	201	11	)	)	PUNCT
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eurjchem-990	201	13	)	)	PUNCT
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eurjchem-990	201	40	)	)	PUNCT
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eurjchem-990	201	43	)	)	PUNCT
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eurjchem-990	201	45	c(11)‐n(10)‐n(9	c(11)‐n(10)‐n(9	NOUN
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eurjchem-990	202	5	n(10)‐n(9)‐c(7	n(10)‐n(9)‐c(7	ADJ
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eurjchem-990	202	48	)	)	PUNCT
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eurjchem-990	202	51	)	)	PUNCT
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eurjchem-990	202	54	)	)	PUNCT
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eurjchem-990	202	57	)	)	PUNCT
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eurjchem-990	202	60	)	)	PUNCT
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eurjchem-990	202	63	)	)	PUNCT
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eurjchem-990	202	69	wall	wall	NOUN
eurjchem-990	202	70	structure	structure	NOUN
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eurjchem-990	202	72	produce	produce	VERB
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eurjchem-990	202	80	can	can	AUX
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eurjchem-990	202	83	gram‐positive	gram‐positive	ADJ
eurjchem-990	202	84	bacteria	bacteria	NOUN
eurjchem-990	202	85	and	and	CCONJ
eurjchem-990	202	86	is	be	AUX
eurjchem-990	202	87	ineffective	ineffective	ADJ
eurjchem-990	202	88	against	against	ADP
eurjchem-990	202	89	gram‐negative	gram‐negative	ADJ
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eurjchem-990	202	91	[	[	X
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eurjchem-990	202	93	]	]	PUNCT
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eurjchem-990	203	2	is	be	AUX
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eurjchem-990	203	4	noting	note	VERB
eurjchem-990	203	5	that	that	SCONJ
eurjchem-990	203	6	the	the	DET
eurjchem-990	203	7	comparison	comparison	NOUN
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eurjchem-990	203	13	compounds	compound	NOUN
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eurjchem-990	203	15	the	the	DET
eurjchem-990	203	16	selected	select	VERB
eurjchem-990	203	17	types	type	NOUN
eurjchem-990	203	18	of	of	ADP
eurjchem-990	203	19	microorganisms	microorganism	NOUN
eurjchem-990	203	20	indicate	indicate	VERB
eurjchem-990	203	21	that	that	SCONJ
eurjchem-990	203	22	cu(ii	cu(ii	PROPN
eurjchem-990	203	23	)	)	PUNCT
eurjchem-990	203	24	>	>	X
eurjchem-990	204	1	ni(ii	ni(ii	PROPN
eurjchem-990	204	2	)	)	PUNCT
eurjchem-990	204	3	>	>	PUNCT
eurjchem-990	204	4	co(ii	co(ii	PROPN
eurjchem-990	204	5	)	)	PUNCT
eurjchem-990	204	6	>	>	X
eurjchem-990	204	7	mn(ii	mn(ii	PROPN
eurjchem-990	204	8	)	)	PUNCT
eurjchem-990	204	9	.	.	PUNCT
eurjchem-990	205	1	3.6	3.6	NUM
eurjchem-990	205	2	.	.	X
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eurjchem-990	206	2	modeling	model	VERB
eurjchem-990	206	3	the	the	DET
eurjchem-990	206	4	atomic	atomic	ADJ
eurjchem-990	206	5	numbering	numbering	NOUN
eurjchem-990	206	6	scheme	scheme	NOUN
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eurjchem-990	206	10	figure	figure	NOUN
eurjchem-990	206	11	3‐5	3‐5	PROPN
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eurjchem-990	206	14	theoretical	theoretical	ADJ
eurjchem-990	206	15	geometry	geometry	NOUN
eurjchem-990	206	16	structures	structure	NOUN
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eurjchem-990	206	18	the	the	DET
eurjchem-990	206	19	ligand	ligand	NOUN
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eurjchem-990	206	23	its	its	PRON
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eurjchem-990	206	25	complexes	complex	NOUN
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eurjchem-990	207	2	molecular	molecular	ADJ
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eurjchem-990	207	12	atomic	atomic	ADJ
eurjchem-990	207	13	energy	energy	NOUN
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eurjchem-990	207	16	energy	energy	NOUN
eurjchem-990	207	17	,	,	PUNCT
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eurjchem-990	207	23	moment	moment	NOUN
eurjchem-990	207	24	,	,	PUNCT
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eurjchem-990	207	27	lumo	lumo	NOUN
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eurjchem-990	207	30	and	and	CCONJ
eurjchem-990	207	31	represented	represent	VERB
eurjchem-990	207	32	in	in	ADP
eurjchem-990	207	33	table	table	NOUN
eurjchem-990	207	34	6	6	NUM
eurjchem-990	207	35	.	.	PUNCT
eurjchem-990	208	1	a	a	DET
eurjchem-990	208	2	comparison	comparison	NOUN
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eurjchem-990	208	4	the	the	DET
eurjchem-990	208	5	bond	bond	NOUN
eurjchem-990	208	6	length	length	NOUN
eurjchem-990	208	7	of	of	ADP
eurjchem-990	208	8	the	the	DET
eurjchem-990	208	9	ligand	ligand	NOUN
eurjchem-990	208	10	and	and	CCONJ
eurjchem-990	208	11	its	its	PRON
eurjchem-990	208	12	complexes	complex	NOUN
eurjchem-990	208	13	is	be	AUX
eurjchem-990	208	14	illustrated	illustrate	VERB
eurjchem-990	208	15	.	.	PUNCT
eurjchem-990	209	1	all	all	DET
eurjchem-990	209	2	the	the	DET
eurjchem-990	209	3	active	active	ADJ
eurjchem-990	209	4	groups	group	NOUN
eurjchem-990	209	5	taking	take	VERB
eurjchem-990	209	6	part	part	NOUN
eurjchem-990	209	7	in	in	ADP
eurjchem-990	209	8	coordination	coordination	NOUN
eurjchem-990	209	9	have	have	VERB
eurjchem-990	209	10	bonds	bond	NOUN
eurjchem-990	209	11	longer	long	ADJ
eurjchem-990	209	12	than	than	SCONJ
eurjchem-990	209	13	that	that	PRON
eurjchem-990	209	14	already	already	ADV
eurjchem-990	209	15	exist	exist	VERB
eurjchem-990	209	16	in	in	ADP
eurjchem-990	209	17	the	the	DET
eurjchem-990	209	18	ligand	ligand	NOUN
eurjchem-990	209	19	(	(	PUNCT
eurjchem-990	209	20	like	like	ADP
eurjchem-990	209	21	c	c	NOUN
eurjchem-990	209	22	=	=	SYM
eurjchem-990	209	23	n	n	X
eurjchem-990	209	24	,	,	PUNCT
eurjchem-990	209	25	c	c	PROPN
eurjchem-990	209	26	=	=	SYM
eurjchem-990	209	27	s	s	NOUN
eurjchem-990	209	28	)	)	PUNCT
eurjchem-990	209	29	.	.	PUNCT
eurjchem-990	210	1	the	the	DET
eurjchem-990	210	2	lower	low	ADJ
eurjchem-990	210	3	homo	homo	NOUN
eurjchem-990	210	4	energy	energy	NOUN
eurjchem-990	210	5	values	value	NOUN
eurjchem-990	210	6	show	show	VERB
eurjchem-990	210	7	that	that	SCONJ
eurjchem-990	210	8	molecule	molecule	NOUN
eurjchem-990	210	9	donating	donating	NOUN
eurjchem-990	210	10	electron	electron	NOUN
eurjchem-990	210	11	ability	ability	NOUN
eurjchem-990	210	12	is	be	AUX
eurjchem-990	210	13	the	the	DET
eurjchem-990	210	14	weaker	weak	ADJ
eurjchem-990	210	15	.	.	PUNCT
eurjchem-990	211	1	on	on	ADP
eurjchem-990	211	2	contrary	contrary	PROPN
eurjchem-990	211	3	,	,	PUNCT
eurjchem-990	211	4	the	the	DET
eurjchem-990	211	5	higher	high	ADJ
eurjchem-990	211	6	homo	homo	NOUN
eurjchem-990	211	7	energy	energy	NOUN
eurjchem-990	211	8	implies	imply	VERB
eurjchem-990	211	9	that	that	SCONJ
eurjchem-990	211	10	the	the	DET
eurjchem-990	211	11	molecule	molecule	NOUN
eurjchem-990	211	12	is	be	AUX
eurjchem-990	211	13	a	a	DET
eurjchem-990	211	14	good	good	ADJ
eurjchem-990	211	15	electron	electron	NOUN
eurjchem-990	211	16	donor	donor	NOUN
eurjchem-990	211	17	.	.	PUNCT
eurjchem-990	212	1	lumo	lumo	NOUN
eurjchem-990	212	2	energy	energy	NOUN
eurjchem-990	212	3	presents	present	VERB
eurjchem-990	212	4	the	the	DET
eurjchem-990	212	5	ability	ability	NOUN
eurjchem-990	212	6	of	of	ADP
eurjchem-990	212	7	a	a	DET
eurjchem-990	212	8	molecule	molecule	NOUN
eurjchem-990	212	9	receiving	receive	VERB
eurjchem-990	212	10	electron	electron	NOUN
eurjchem-990	212	11	[	[	X
eurjchem-990	212	12	22,71	22,71	NUM
eurjchem-990	212	13	]	]	PUNCT
eurjchem-990	212	14	.	.	PUNCT
eurjchem-990	213	1	figure	figure	NOUN
eurjchem-990	213	2	3	3	NUM
eurjchem-990	213	3	.	.	PUNCT
eurjchem-990	214	1	the	the	DET
eurjchem-990	214	2	optimized	optimize	VERB
eurjchem-990	214	3	structural	structural	ADJ
eurjchem-990	214	4	geometry	geometry	NOUN
eurjchem-990	214	5	of	of	ADP
eurjchem-990	214	6	ephc	ephc	NOUN
eurjchem-990	214	7	along	along	ADP
eurjchem-990	214	8	with	with	ADP
eurjchem-990	214	9	the	the	DET
eurjchem-990	214	10	atom	atom	NOUN
eurjchem-990	214	11	numbering	numbering	NOUN
eurjchem-990	214	12	scheme	scheme	NOUN
eurjchem-990	214	13	.	.	PUNCT
eurjchem-990	215	1	figure	figure	NOUN
eurjchem-990	215	2	4	4	NUM
eurjchem-990	215	3	.	.	PUNCT
eurjchem-990	216	1	the	the	DET
eurjchem-990	216	2	optimized	optimize	VERB
eurjchem-990	216	3	structural	structural	ADJ
eurjchem-990	216	4	geometry	geometry	NOUN
eurjchem-990	216	5	of	of	ADP
eurjchem-990	216	6	[	[	X
eurjchem-990	216	7	ni(ephc)(1,10‐phen)cl	ni(ephc)(1,10‐phen)cl	NOUN
eurjchem-990	216	8	]	]	X
eurjchem-990	216	9	(	(	PUNCT
eurjchem-990	216	10	2	2	NUM
eurjchem-990	216	11	)	)	PUNCT
eurjchem-990	216	12	along	along	ADP
eurjchem-990	216	13	with	with	ADP
eurjchem-990	216	14	the	the	DET
eurjchem-990	216	15	atom	atom	NOUN
eurjchem-990	216	16	numbering	numbering	NOUN
eurjchem-990	216	17	scheme	scheme	NOUN
eurjchem-990	216	18	.	.	PUNCT
eurjchem-990	217	1	the	the	DET
eurjchem-990	217	2	bond	bond	NOUN
eurjchem-990	217	3	lengths	length	NOUN
eurjchem-990	217	4	and	and	CCONJ
eurjchem-990	217	5	bond	bond	NOUN
eurjchem-990	217	6	angles	angle	NOUN
eurjchem-990	217	7	of	of	ADP
eurjchem-990	217	8	ephc‐thiosemi‐	ephc‐thiosemi‐	SYM
eurjchem-990	217	9	carbazone	carbazone	NOUN
eurjchem-990	217	10	ligand	ligand	NOUN
eurjchem-990	217	11	and	and	CCONJ
eurjchem-990	217	12	[	[	X
eurjchem-990	217	13	mn(ephc)(1,10‐phen)cl	mn(ephc)(1,10‐phen)cl	NOUN
eurjchem-990	217	14	]	]	X
eurjchem-990	217	15	complex	complex	NOUN
eurjchem-990	217	16	as	as	ADP
eurjchem-990	217	17	a	a	DET
eurjchem-990	217	18	representative	representative	ADJ
eurjchem-990	217	19	example	example	NOUN
eurjchem-990	217	20	of	of	ADP
eurjchem-990	217	21	m(ii	m(ii	NOUN
eurjchem-990	217	22	)	)	PUNCT
eurjchem-990	217	23	compounds	compound	NOUN
eurjchem-990	217	24	are	be	AUX
eurjchem-990	217	25	given	give	VERB
eurjchem-990	217	26	in	in	ADP
eurjchem-990	217	27	table	table	NOUN
eurjchem-990	217	28	7	7	NUM
eurjchem-990	217	29	and	and	CCONJ
eurjchem-990	217	30	8	8	NUM
eurjchem-990	217	31	,	,	PUNCT
eurjchem-990	217	32	respectively	respectively	ADV
eurjchem-990	217	33	.	.	PUNCT
eurjchem-990	218	1	a	a	DET
eurjchem-990	218	2	drawing	drawing	NOUN
eurjchem-990	218	3	of	of	ADP
eurjchem-990	218	4	ephc‐thiosemicarbazone	ephc‐thiosemicarbazone	NOUN
eurjchem-990	218	5	ligand	ligand	NOUN
eurjchem-990	218	6	is	be	AUX
eurjchem-990	218	7	shown	show	VERB
eurjchem-990	218	8	in	in	ADP
eurjchem-990	218	9	figure	figure	NOUN
eurjchem-990	218	10	3	3	NUM
eurjchem-990	218	11	while	while	SCONJ
eurjchem-990	218	12	ni(ii	ni(ii	NOUN
eurjchem-990	218	13	)	)	PUNCT
eurjchem-990	218	14	and	and	CCONJ
eurjchem-990	218	15	co(ii	co(ii	ADJ
eurjchem-990	218	16	)	)	PUNCT
eurjchem-990	218	17	complexes	complex	NOUN
eurjchem-990	218	18	with	with	ADP
eurjchem-990	218	19	the	the	DET
eurjchem-990	218	20	atomic	atomic	ADJ
eurjchem-990	218	21	numbering	numbering	NOUN
eurjchem-990	218	22	scheme	scheme	NOUN
eurjchem-990	218	23	is	be	AUX
eurjchem-990	218	24	shown	show	VERB
eurjchem-990	218	25	in	in	ADP
eurjchem-990	218	26	figure	figure	NOUN
eurjchem-990	218	27	4	4	NUM
eurjchem-990	218	28	and	and	CCONJ
eurjchem-990	218	29	5	5	NUM
eurjchem-990	218	30	,	,	PUNCT
eurjchem-990	218	31	respectively	respectively	ADV
eurjchem-990	218	32	.	.	PUNCT
eurjchem-990	219	1	the	the	DET
eurjchem-990	219	2	coordination	coordination	NOUN
eurjchem-990	219	3	results	result	VERB
eurjchem-990	219	4	in	in	ADP
eurjchem-990	219	5	the	the	DET
eurjchem-990	219	6	changes	change	NOUN
eurjchem-990	219	7	of	of	ADP
eurjchem-990	219	8	bond	bond	NOUN
eurjchem-990	219	9	lengths	length	NOUN
eurjchem-990	219	10	and	and	CCONJ
eurjchem-990	219	11	angles	angle	NOUN
eurjchem-990	219	12	of	of	ADP
eurjchem-990	219	13	the	the	DET
eurjchem-990	219	14	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-990	219	15	moiety	moiety	NOUN
eurjchem-990	219	16	,	,	PUNCT
eurjchem-990	219	17	as	as	SCONJ
eurjchem-990	219	18	expected	expect	VERB
eurjchem-990	219	19	,	,	PUNCT
eurjchem-990	219	20	thus	thus	ADV
eurjchem-990	219	21	when	when	SCONJ
eurjchem-990	219	22	the	the	DET
eurjchem-990	219	23	bond	bond	NOUN
eurjchem-990	219	24	lengths	length	NOUN
eurjchem-990	219	25	in	in	ADP
eurjchem-990	219	26	the	the	DET
eurjchem-990	219	27	coordinated	coordinated	ADJ
eurjchem-990	219	28	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-990	219	29	ligand	ligand	NOUN
eurjchem-990	219	30	are	be	AUX
eurjchem-990	219	31	compared	compare	VERB
eurjchem-990	219	32	with	with	ADP
eurjchem-990	219	33	those	those	PRON
eurjchem-990	219	34	in	in	ADP
eurjchem-990	219	35	the	the	DET
eurjchem-990	219	36	free	free	ADJ
eurjchem-990	219	37	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-990	219	38	ligand	ligand	NOUN
eurjchem-990	219	39	,	,	PUNCT
eurjchem-990	219	40	it	it	PRON
eurjchem-990	219	41	is	be	AUX
eurjchem-990	219	42	seen	see	VERB
eurjchem-990	219	43	that	that	SCONJ
eurjchem-990	219	44	coordination	coordination	NOUN
eurjchem-990	219	45	elongates	elongate	VERB
eurjchem-990	219	46	the	the	DET
eurjchem-990	219	47	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-990	219	48	moiety	moiety	NOUN
eurjchem-990	219	49	’s	’s	PART
eurjchem-990	219	50	c	c	NOUN
eurjchem-990	219	51	–	–	PUNCT
eurjchem-990	219	52	s	s	VERB
eurjchem-990	219	53	bond	bond	NOUN
eurjchem-990	219	54	from	from	ADP
eurjchem-990	219	55	1.660	1.660	NUM
eurjchem-990	219	56	å	å	NOUN
eurjchem-990	219	57	to	to	ADP
eurjchem-990	219	58	1.729‐1.811	1.729‐1.811	NUM
eurjchem-990	219	59	å	å	NOUN
eurjchem-990	219	60	and	and	CCONJ
eurjchem-990	219	61	contracts	contract	NOUN
eurjchem-990	219	62	adjacent	adjacent	ADJ
eurjchem-990	219	63	n	n	CCONJ
eurjchem-990	219	64	–	–	PUNCT
eurjchem-990	219	65	c(s	c(s	ADJ
eurjchem-990	219	66	)	)	PUNCT
eurjchem-990	219	67	bond	bond	NOUN
eurjchem-990	219	68	from	from	ADP
eurjchem-990	219	69	1.426	1.426	NUM
eurjchem-990	219	70	å	å	NOUN
eurjchem-990	219	71	to	to	ADP
eurjchem-990	219	72	1.313‐1.361	1.313‐1.361	NUM
eurjchem-990	219	73	å	å	PROPN
eurjchem-990	219	74	in	in	ADV
eurjchem-990	219	75	,	,	PUNCT
eurjchem-990	219	76	which	which	PRON
eurjchem-990	219	77	is	be	AUX
eurjchem-990	219	78	consistent	consistent	ADJ
eurjchem-990	219	79	with	with	ADP
eurjchem-990	219	80	the	the	DET
eurjchem-990	219	81	c	c	PROPN
eurjchem-990	219	82	–	–	PUNCT
eurjchem-990	219	83	s	s	AUX
eurjchem-990	219	84	acquiring	acquire	VERB
eurjchem-990	219	85	a	a	DET
eurjchem-990	219	86	partial	partial	ADJ
eurjchem-990	219	87	single	single	ADJ
eurjchem-990	219	88	bond	bond	NOUN
eurjchem-990	219	89	and	and	CCONJ
eurjchem-990	219	90	n	n	CCONJ
eurjchem-990	219	91	–	–	PUNCT
eurjchem-990	219	92	c(s	c(s	X
eurjchem-990	219	93	)	)	PUNCT
eurjchem-990	219	94	a	a	DET
eurjchem-990	219	95	partial	partial	ADJ
eurjchem-990	219	96	double	double	ADJ
eurjchem-990	219	97	bond	bond	NOUN
eurjchem-990	219	98	character	character	NOUN
eurjchem-990	219	99	.	.	PUNCT
eurjchem-990	220	1	these	these	DET
eurjchem-990	220	2	changes	change	NOUN
eurjchem-990	220	3	in	in	ADP
eurjchem-990	220	4	bond	bond	NOUN
eurjchem-990	220	5	lengths	length	NOUN
eurjchem-990	220	6	are	be	AUX
eurjchem-990	220	7	attributable	attributable	ADJ
eurjchem-990	220	8	to	to	ADP
eurjchem-990	220	9	stabilization	stabilization	NOUN
eurjchem-990	220	10	of	of	ADP
eurjchem-990	220	11	the	the	DET
eurjchem-990	220	12	iminothiolate	iminothiolate	NOUN
eurjchem-990	220	13	form	form	NOUN
eurjchem-990	220	14	of	of	ADP
eurjchem-990	220	15	the	the	DET
eurjchem-990	220	16	thiosemi‐	thiosemi‐	X
eurjchem-990	220	17	carbazone	carbazone	NOUN
eurjchem-990	220	18	ligand	ligand	NOUN
eurjchem-990	220	19	upon	upon	SCONJ
eurjchem-990	220	20	complexation	complexation	NOUN
eurjchem-990	220	21	via	via	ADP
eurjchem-990	220	22	loss	loss	NOUN
eurjchem-990	220	23	of	of	ADP
eurjchem-990	220	24	the	the	DET
eurjchem-990	220	25	hydrazinic	hydrazinic	ADJ
eurjchem-990	220	26	proton	proton	NOUN
eurjchem-990	220	27	[	[	X
eurjchem-990	220	28	72	72	NUM
eurjchem-990	220	29	]	]	SYM
eurjchem-990	220	30	.	.	PUNCT
eurjchem-990	221	1	258	258	NUM
eurjchem-990	221	2	mohamed	mohame	VERB
eurjchem-990	221	3	et	et	PROPN
eurjchem-990	221	4	al	al	PROPN
eurjchem-990	221	5	.	.	PUNCT
eurjchem-990	221	6	/	/	SYM
eurjchem-990	221	7	european	european	PROPN
eurjchem-990	221	8	journal	journal	PROPN
eurjchem-990	221	9	of	of	ADP
eurjchem-990	221	10	chemistry	chemistry	NOUN
eurjchem-990	221	11	5	5	NUM
eurjchem-990	221	12	(	(	PUNCT
eurjchem-990	221	13	2	2	NUM
eurjchem-990	221	14	)	)	PUNCT
eurjchem-990	221	15	(	(	PUNCT
eurjchem-990	221	16	2014	2014	NUM
eurjchem-990	221	17	)	)	PUNCT
eurjchem-990	221	18	252‐259	252‐259	NOUN
eurjchem-990	221	19	table	table	NOUN
eurjchem-990	221	20	8	8	NUM
eurjchem-990	221	21	.	.	PUNCT
eurjchem-990	222	1	bond	bond	NOUN
eurjchem-990	222	2	distances	distance	NOUN
eurjchem-990	222	3	(	(	PUNCT
eurjchem-990	222	4	å	å	NOUN
eurjchem-990	222	5	)	)	PUNCT
eurjchem-990	222	6	and	and	CCONJ
eurjchem-990	222	7	angles	angle	NOUN
eurjchem-990	222	8	(	(	PUNCT
eurjchem-990	222	9	o	o	NOUN
eurjchem-990	222	10	)	)	PUNCT
eurjchem-990	222	11	for	for	ADP
eurjchem-990	222	12	[	[	X
eurjchem-990	222	13	mn(ephc)(phen)cl	mn(ephc)(phen)cl	NOUN
eurjchem-990	222	14	]	]	X
eurjchem-990	222	15	complex	complex	ADJ
eurjchem-990	222	16	.	.	PUNCT
eurjchem-990	223	1	atoms	atom	NOUN
eurjchem-990	223	2	bond	bond	NOUN
eurjchem-990	223	3	distances	distance	NOUN
eurjchem-990	223	4	(	(	PUNCT
eurjchem-990	223	5	å	å	NOUN
eurjchem-990	223	6	)	)	PUNCT
eurjchem-990	223	7	atoms	atom	NOUN
eurjchem-990	223	8	angle	angle	NOUN
eurjchem-990	223	9	(	(	PUNCT
eurjchem-990	223	10	°	°	NOUN
eurjchem-990	223	11	)	)	PUNCT
eurjchem-990	223	12	atoms	atom	NOUN
eurjchem-990	223	13	angle	angle	NOUN
eurjchem-990	223	14	(	(	PUNCT
eurjchem-990	223	15	°	°	NOUN
eurjchem-990	223	16	)	)	PUNCT
eurjchem-990	223	17	c(30)‐n(31	c(30)‐n(31	NOUN
eurjchem-990	223	18	)	)	PUNCT
eurjchem-990	223	19	1.4013	1.4013	NUM
eurjchem-990	223	20	c(30)‐n(31)‐c(26	c(30)‐n(31)‐c(26	NOUN
eurjchem-990	223	21	)	)	PUNCT
eurjchem-990	223	22	115.3974	115.3974	NUM
eurjchem-990	223	23	c(16)‐n(15)‐c(13	c(16)‐n(15)‐c(13	NOUN
eurjchem-990	223	24	)	)	PUNCT
eurjchem-990	223	25	122.7854	122.7854	NUM
eurjchem-990	223	26	c(29)‐c(30	c(29)‐c(30	NOUN
eurjchem-990	223	27	)	)	PUNCT
eurjchem-990	223	28	1.3793	1.3793	NUM
eurjchem-990	223	29	c(30)‐n(31)‐mn(11	c(30)‐n(31)‐mn(11	NOUN
eurjchem-990	223	30	)	)	PUNCT
eurjchem-990	223	31	129.9560	129.9560	NUM
eurjchem-990	223	32	c(13)‐s(14)‐mn(11	c(13)‐s(14)‐mn(11	NUM
eurjchem-990	223	33	)	)	PUNCT
eurjchem-990	223	34	93.9839	93.9839	NUM
eurjchem-990	223	35	c(28)‐c(29	c(28)‐c(29	NOUN
eurjchem-990	223	36	)	)	PUNCT
eurjchem-990	223	37	1.4036	1.4036	NUM
eurjchem-990	223	38	c(26)‐n(31)‐mn(11	c(26)‐n(31)‐mn(11	NOUN
eurjchem-990	223	39	)	)	PUNCT
eurjchem-990	223	40	114.4310	114.4310	NUM
eurjchem-990	223	41	n(15)‐c(13)‐s(14	n(15)‐c(13)‐s(14	ADJ
eurjchem-990	223	42	)	)	PUNCT
eurjchem-990	223	43	119.6797	119.6797	NUM
eurjchem-990	223	44	c(27)‐c(28	c(27)‐c(28	NOUN
eurjchem-990	223	45	)	)	PUNCT
eurjchem-990	223	46	1.4005	1.4005	NUM
eurjchem-990	223	47	n(31)‐c(30)‐c(29	n(31)‐c(30)‐c(29	NOUN
eurjchem-990	223	48	)	)	PUNCT
eurjchem-990	223	49	121.5916	121.5916	NUM
eurjchem-990	223	50	n(15)‐c(13)‐n(9	n(15)‐c(13)‐n(9	NUM
eurjchem-990	223	51	)	)	PUNCT
eurjchem-990	223	52	116.4556	116.4556	NUM
eurjchem-990	223	53	c(26)‐n(31	c(26)‐n(31	NOUN
eurjchem-990	223	54	)	)	PUNCT
eurjchem-990	223	55	1.4166	1.4166	NUM
eurjchem-990	223	56	c(30)‐c(29)‐c(28	c(30)‐c(29)‐c(28	NOUN
eurjchem-990	223	57	)	)	PUNCT
eurjchem-990	223	58	122.0829	122.0829	NUM
eurjchem-990	223	59	s(14)‐c(13)‐n(9	s(14)‐c(13)‐n(9	NUM
eurjchem-990	223	60	)	)	PUNCT
eurjchem-990	224	1	123.8348	123.8348	NUM
eurjchem-990	224	2	c(26)‐c(27	c(26)‐c(27	X
eurjchem-990	224	3	)	)	PUNCT
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eurjchem-990	224	5	c(29)‐c(28)‐c(27	c(29)‐c(28)‐c(27	NUM
eurjchem-990	224	6	)	)	PUNCT
eurjchem-990	224	7	118.8145	118.8145	NUM
eurjchem-990	224	8	n(31)‐mn(11)‐n(22	n(31)‐mn(11)‐n(22	ADJ
eurjchem-990	224	9	)	)	PUNCT
eurjchem-990	224	10	85.1370	85.1370	NUM
eurjchem-990	224	11	c(24)‐c(25	c(24)‐c(25	NOUN
eurjchem-990	224	12	)	)	PUNCT
eurjchem-990	224	13	1.3735	1.3735	NUM
eurjchem-990	224	14	c(28)‐c(27)‐c(26	c(28)‐c(27)‐c(26	NOUN
eurjchem-990	224	15	)	)	PUNCT
eurjchem-990	224	16	117.8240	117.8240	NUM
eurjchem-990	224	17	n(31)‐mn(11)‐s(14	n(31)‐mn(11)‐s(14	NOUN
eurjchem-990	224	18	)	)	PUNCT
eurjchem-990	224	19	103.5590	103.5590	NUM
eurjchem-990	224	20	c(23)‐c(24	c(23)‐c(24	NOUN
eurjchem-990	224	21	)	)	PUNCT
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eurjchem-990	224	23	c(28)‐c(27)‐c(19	c(28)‐c(27)‐c(19	NOUN
eurjchem-990	224	24	)	)	PUNCT
eurjchem-990	224	25	124.6801	124.6801	NUM
eurjchem-990	224	26	n(31)‐mn(11)‐cl(12	n(31)‐mn(11)‐cl(12	NUM
eurjchem-990	224	27	)	)	PUNCT
eurjchem-990	224	28	156.8913	156.8913	NUM
eurjchem-990	224	29	n(22)‐c(23	n(22)‐c(23	NOUN
eurjchem-990	224	30	)	)	PUNCT
eurjchem-990	224	31	1.3367	1.3367	NUM
eurjchem-990	224	32	c(26)‐c(27)‐c(19	c(26)‐c(27)‐c(19	NOUN
eurjchem-990	224	33	)	)	PUNCT
eurjchem-990	224	34	117.4928	117.4928	NUM
eurjchem-990	224	35	n(31)‐mn(11)‐n(8	n(31)‐mn(11)‐n(8	NOUN
eurjchem-990	224	36	)	)	PUNCT
eurjchem-990	224	37	101.1144	101.1144	NUM
eurjchem-990	224	38	c(21)‐n(22	c(21)‐n(22	PROPN
eurjchem-990	224	39	)	)	PUNCT
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eurjchem-990	224	41	n(31)‐c(26)‐c(27	n(31)‐c(26)‐c(27	NOUN
eurjchem-990	224	42	)	)	PUNCT
eurjchem-990	224	43	124.2319	124.2319	NUM
eurjchem-990	224	44	n(31)‐mn(11)‐n(7	n(31)‐mn(11)‐n(7	NOUN
eurjchem-990	224	45	)	)	PUNCT
eurjchem-990	224	46	85.2175	85.2175	NUM
eurjchem-990	224	47	c(21)‐c(26	c(21)‐c(26	NOUN
eurjchem-990	224	48	)	)	PUNCT
eurjchem-990	224	49	1.4135	1.4135	NUM
eurjchem-990	224	50	n(31)‐c(26)‐c(21	n(31)‐c(26)‐c(21	ADJ
eurjchem-990	224	51	)	)	PUNCT
eurjchem-990	224	52	115.1995	115.1995	NUM
eurjchem-990	224	53	n(22)‐mn(11)‐s(14	n(22)‐mn(11)‐s(14	NOUN
eurjchem-990	224	54	)	)	PUNCT
eurjchem-990	224	55	90.8034	90.8034	NUM
eurjchem-990	224	56	c(20)‐c(25	c(20)‐c(25	NOUN
eurjchem-990	224	57	)	)	PUNCT
eurjchem-990	224	58	1.4159	1.4159	NUM
eurjchem-990	224	59	c(27)‐c(26)‐c(21	c(27)‐c(26)‐c(21	NOUN
eurjchem-990	224	60	)	)	PUNCT
eurjchem-990	224	61	120.5656	120.5656	NUM
eurjchem-990	224	62	n(22)‐mn(11)‐cl(12	n(22)‐mn(11)‐cl(12	NUM
eurjchem-990	224	63	)	)	PUNCT
eurjchem-990	224	64	85.0861	85.0861	NUM
eurjchem-990	224	65	c(20)‐c(21	c(20)‐c(21	NOUN
eurjchem-990	224	66	)	)	PUNCT
eurjchem-990	224	67	1.4060	1.4060	NUM
eurjchem-990	224	68	c(24)‐c(25)‐c(20	c(24)‐c(25)‐c(20	NOUN
eurjchem-990	224	69	)	)	PUNCT
eurjchem-990	224	70	119.1748	119.1748	NUM
eurjchem-990	224	71	n(22)‐mn(11)‐n(8	n(22)‐mn(11)‐n(8	NOUN
eurjchem-990	224	72	)	)	PUNCT
eurjchem-990	224	73	173.7317	173.7317	NUM
eurjchem-990	224	74	c(19)‐c(27	c(19)‐c(27	X
eurjchem-990	224	75	)	)	PUNCT
eurjchem-990	224	76	1.4349	1.4349	NUM
eurjchem-990	224	77	c(25)‐c(24)‐c(23	c(25)‐c(24)‐c(23	NOUN
eurjchem-990	224	78	)	)	PUNCT
eurjchem-990	224	79	121.2291	121.2291	NUM
eurjchem-990	224	80	n(22)‐mn(11)‐n(7	n(22)‐mn(11)‐n(7	NUM
eurjchem-990	224	81	)	)	PUNCT
eurjchem-990	224	82	99.6526	99.6526	NUM
eurjchem-990	224	83	c(18)‐c(20	c(18)‐c(20	PROPN
eurjchem-990	224	84	)	)	PUNCT
eurjchem-990	224	85	1.4266	1.4266	NUM
eurjchem-990	224	86	c(24)‐c(23)‐n(22	c(24)‐c(23)‐n(22	NOUN
eurjchem-990	224	87	)	)	PUNCT
eurjchem-990	224	88	121.4085	121.4085	NUM
eurjchem-990	224	89	s(14)‐mn(11)‐cl(12	s(14)‐mn(11)‐cl(12	NUM
eurjchem-990	224	90	)	)	PUNCT
eurjchem-990	224	91	97.4653	97.4653	NUM
eurjchem-990	224	92	c(18)‐c(19	c(18)‐c(19	NOUN
eurjchem-990	224	93	)	)	PUNCT
eurjchem-990	225	1	1.3662	1.3662	NUM
eurjchem-990	225	2	c(23)‐n(22)‐c(21	c(23)‐n(22)‐c(21	ADJ
eurjchem-990	225	3	)	)	PUNCT
eurjchem-990	225	4	117.3742	117.3742	NUM
eurjchem-990	225	5	s(14)‐mn(11)‐n(8	s(14)‐mn(11)‐n(8	NOUN
eurjchem-990	225	6	)	)	PUNCT
eurjchem-990	225	7	87.2966	87.2966	NUM
eurjchem-990	225	8	c(16)‐c(17	c(16)‐c(17	NOUN
eurjchem-990	225	9	)	)	PUNCT
eurjchem-990	225	10	1.5154	1.5154	NUM
eurjchem-990	225	11	c(23)‐n(22)‐mn(11	c(23)‐n(22)‐mn(11	NUM
eurjchem-990	225	12	)	)	PUNCT
eurjchem-990	225	13	132.2493	132.2493	NUM
eurjchem-990	225	14	s(14)‐mn(11)‐n(7	s(14)‐mn(11)‐n(7	NOUN
eurjchem-990	225	15	)	)	PUNCT
eurjchem-990	225	16	166.9528	166.9528	NUM
eurjchem-990	225	17	n(15)‐c(16	n(15)‐c(16	NOUN
eurjchem-990	225	18	)	)	PUNCT
eurjchem-990	225	19	1.4831	1.4831	NUM
eurjchem-990	225	20	c(21)‐n(22)‐mn(11	c(21)‐n(22)‐mn(11	NOUN
eurjchem-990	225	21	)	)	PUNCT
eurjchem-990	225	22	110.3765	110.3765	NUM
eurjchem-990	225	23	cl(12)‐mn(11)‐n(8	cl(12)‐mn(11)‐n(8	NOUN
eurjchem-990	225	24	)	)	PUNCT
eurjchem-990	225	25	89.2363	89.2363	NUM
eurjchem-990	225	26	c(13)‐n(15	c(13)‐n(15	NOUN
eurjchem-990	225	27	)	)	PUNCT
eurjchem-990	225	28	1.3786	1.3786	NUM
eurjchem-990	225	29	c(26)‐c(21)‐n(22	c(26)‐c(21)‐n(22	NOUN
eurjchem-990	225	30	)	)	PUNCT
eurjchem-990	225	31	114.8215	114.8215	NUM
eurjchem-990	225	32	cl(12)‐mn(11)‐n(7	cl(12)‐mn(11)‐n(7	NOUN
eurjchem-990	225	33	)	)	PUNCT
eurjchem-990	225	34	75.8655	75.8655	NUM
eurjchem-990	225	35	c(13)‐s(14	c(13)‐s(14	NOUN
eurjchem-990	225	36	)	)	PUNCT
eurjchem-990	225	37	1.7919	1.7919	NUM
eurjchem-990	225	38	c(26)‐c(21)‐c(20	c(26)‐c(21)‐c(20	NOUN
eurjchem-990	225	39	)	)	PUNCT
eurjchem-990	225	40	121.3150	121.3150	NUM
eurjchem-990	225	41	n(8)‐mn(11)‐n(7	n(8)‐mn(11)‐n(7	NOUN
eurjchem-990	225	42	)	)	PUNCT
eurjchem-990	225	43	81.4774	81.4774	NUM
eurjchem-990	225	44	mn(11)‐n(31	mn(11)‐n(31	NOUN
eurjchem-990	225	45	)	)	PUNCT
eurjchem-990	225	46	1.8500	1.8500	NUM
eurjchem-990	225	47	n(22)‐c(21)‐c(20	n(22)‐c(21)‐c(20	NOUN
eurjchem-990	225	48	)	)	PUNCT
eurjchem-990	225	49	123.8621	123.8621	NUM
eurjchem-990	225	50	c(13)‐n(9)‐n(8	c(13)‐n(9)‐n(8	NOUN
eurjchem-990	225	51	)	)	PUNCT
eurjchem-990	225	52	113.3163	113.3163	NUM
eurjchem-990	225	53	mn(11)‐n(22	mn(11)‐n(22	SYM
eurjchem-990	225	54	)	)	PUNCT
eurjchem-990	225	55	1.9985	1.9985	NUM
eurjchem-990	225	56	c(25)‐c(20)‐c(21	c(25)‐c(20)‐c(21	NOUN
eurjchem-990	225	57	)	)	PUNCT
eurjchem-990	225	58	116.9490	116.9490	NUM
eurjchem-990	225	59	mn(11)‐n(8)‐n(9	mn(11)‐n(8)‐n(9	NOUN
eurjchem-990	225	60	)	)	PUNCT
eurjchem-990	225	61	121.5031	121.5031	NUM
eurjchem-990	225	62	mn(11)‐s(14	mn(11)‐s(14	SYM
eurjchem-990	225	63	)	)	PUNCT
eurjchem-990	225	64	2.2451	2.2451	NUM
eurjchem-990	225	65	c(25)‐c(20)‐c(18	c(25)‐c(20)‐c(18	NOUN
eurjchem-990	225	66	)	)	PUNCT
eurjchem-990	225	67	125.3884	125.3884	NUM
eurjchem-990	225	68	mn(11)‐n(8)‐c(1	mn(11)‐n(8)‐c(1	NOUN
eurjchem-990	225	69	)	)	PUNCT
eurjchem-990	225	70	116.6753	116.6753	NUM
eurjchem-990	225	71	mn(11)‐cl(12	mn(11)‐cl(12	NOUN
eurjchem-990	225	72	)	)	PUNCT
eurjchem-990	225	73	2.3074	2.3074	NUM
eurjchem-990	225	74	c(21)‐c(20)‐c(18	c(21)‐c(20)‐c(18	NOUN
eurjchem-990	225	75	)	)	PUNCT
eurjchem-990	225	76	117.6625	117.6625	NUM
eurjchem-990	225	77	n(9)‐n(8)‐c(1	n(9)‐n(8)‐c(1	NUM
eurjchem-990	225	78	)	)	PUNCT
eurjchem-990	225	79	121.3887	121.3887	NUM
eurjchem-990	225	80	n(9)‐c(13	n(9)‐c(13	NOUN
eurjchem-990	225	81	)	)	PUNCT
eurjchem-990	225	82	1.3510	1.3510	NUM
eurjchem-990	225	83	c(27)‐c(19)‐c(18	c(27)‐c(19)‐c(18	NOUN
eurjchem-990	225	84	)	)	PUNCT
eurjchem-990	225	85	121.6815	121.6815	NUM
eurjchem-990	225	86	mn(11)‐n(7)‐c(6	mn(11)‐n(7)‐c(6	NUM
eurjchem-990	225	87	)	)	PUNCT
eurjchem-990	225	88	128.1585	128.1585	NUM
eurjchem-990	225	89	n(8)‐mn(11	n(8)‐mn(11	NOUN
eurjchem-990	225	90	)	)	PUNCT
eurjchem-990	225	91	1.9519	1.9519	NUM
eurjchem-990	225	92	c(20)‐c(18)‐c(19	c(20)‐c(18)‐c(19	NUM
eurjchem-990	225	93	)	)	PUNCT
eurjchem-990	225	94	121.2692	121.2692	NUM
eurjchem-990	225	95	mn(11)‐n(7)‐c(2	mn(11)‐n(7)‐c(2	NUM
eurjchem-990	225	96	)	)	PUNCT
eurjchem-990	225	97	113.2535	113.2535	NUM
eurjchem-990	225	98	n(8)‐n(9	n(8)‐n(9	NOUN
eurjchem-990	225	99	)	)	PUNCT
eurjchem-990	225	100	1.3831	1.3831	NUM
eurjchem-990	225	101	c(17)‐c(16)‐n(15	c(17)‐c(16)‐n(15	NOUN
eurjchem-990	225	102	)	)	PUNCT
eurjchem-990	225	103	111.0054	111.0054	NUM
eurjchem-990	225	104	c(6)‐n(7)‐c(2	c(6)‐n(7)‐c(2	NUM
eurjchem-990	225	105	)	)	PUNCT
eurjchem-990	225	106	118.5623	118.5623	NUM
eurjchem-990	225	107	n(7)‐mn(11	n(7)‐mn(11	PROPN
eurjchem-990	225	108	)	)	PUNCT
eurjchem-990	225	109	2.0087	2.0087	NUM
eurjchem-990	225	110	n(7)‐c(6)‐c(5	n(7)‐c(6)‐c(5	NUM
eurjchem-990	225	111	)	)	PUNCT
eurjchem-990	225	112	121.5164	121.5164	NUM
eurjchem-990	225	113	c(6)‐n(7	c(6)‐n(7	NOUN
eurjchem-990	225	114	)	)	PUNCT
eurjchem-990	225	115	1.3620	1.3620	NUM
eurjchem-990	225	116	c(6)‐c(5)‐c(4	c(6)‐c(5)‐c(4	NUM
eurjchem-990	225	117	)	)	PUNCT
eurjchem-990	225	118	119.7913	119.7913	NUM
eurjchem-990	225	119	c(5)‐c(6	c(5)‐c(6	PROPN
eurjchem-990	225	120	)	)	PUNCT
eurjchem-990	225	121	1.3935	1.3935	NUM
eurjchem-990	225	122	c(5)‐c(4)‐c(3	c(5)‐c(4)‐c(3	NOUN
eurjchem-990	225	123	)	)	PUNCT
eurjchem-990	225	124	119.5456	119.5456	NUM
eurjchem-990	225	125	c(4)‐c(5	c(4)‐c(5	NOUN
eurjchem-990	225	126	)	)	PUNCT
eurjchem-990	225	127	1.3923	1.3923	NUM
eurjchem-990	225	128	c(4)‐c(3)‐c(2	c(4)‐c(3)‐c(2	NUM
eurjchem-990	225	129	)	)	PUNCT
eurjchem-990	225	130	118.9493	118.9493	NUM
eurjchem-990	225	131	c(3)‐c(4	c(3)‐c(4	NOUN
eurjchem-990	225	132	)	)	PUNCT
eurjchem-990	225	133	1.3903	1.3903	NUM
eurjchem-990	225	134	n(7)‐c(2)‐c(3	n(7)‐c(2)‐c(3	NUM
eurjchem-990	225	135	)	)	PUNCT
eurjchem-990	225	136	121.6342	121.6342	NUM
eurjchem-990	225	137	c(2)‐c(3	c(2)‐c(3	NOUN
eurjchem-990	225	138	)	)	PUNCT
eurjchem-990	225	139	1.3974	1.3974	NUM
eurjchem-990	225	140	n(7)‐c(2)‐c(1	n(7)‐c(2)‐c(1	NUM
eurjchem-990	225	141	)	)	PUNCT
eurjchem-990	225	142	113.6817	113.6817	NUM
eurjchem-990	225	143	c(2)‐n(7	c(2)‐n(7	NUM
eurjchem-990	225	144	)	)	PUNCT
eurjchem-990	225	145	1.3861	1.3861	NUM
eurjchem-990	225	146	c(3)‐c(2)‐c(1	c(3)‐c(2)‐c(1	NUM
eurjchem-990	225	147	)	)	PUNCT
eurjchem-990	225	148	124.6731	124.6731	NUM
eurjchem-990	225	149	c(1)‐o(10	c(1)‐o(10	NOUN
eurjchem-990	225	150	)	)	PUNCT
eurjchem-990	225	151	1.3655	1.3655	NUM
eurjchem-990	225	152	o(10)‐c(1)‐n(8	o(10)‐c(1)‐n(8	NUM
eurjchem-990	225	153	)	)	PUNCT
eurjchem-990	225	154	127.3163	127.3163	NUM
eurjchem-990	225	155	c(1)‐n(8	c(1)‐n(8	PROPN
eurjchem-990	225	156	)	)	PUNCT
eurjchem-990	225	157	1.3318	1.3318	NUM
eurjchem-990	225	158	o(10)‐c(1)‐c(2	o(10)‐c(1)‐c(2	NUM
eurjchem-990	225	159	)	)	PUNCT
eurjchem-990	225	160	117.8329	117.8329	NUM
eurjchem-990	225	161	c(1)‐c(2	c(1)‐c(2	X
eurjchem-990	225	162	)	)	PUNCT
eurjchem-990	225	163	1.4682	1.4682	NUM
eurjchem-990	225	164	n(8)‐c(1)‐c(2	n(8)‐c(1)‐c(2	NUM
eurjchem-990	225	165	)	)	PUNCT
eurjchem-990	225	166	114.8259	114.8259	NUM
eurjchem-990	225	167	figure	figure	NOUN
eurjchem-990	225	168	5	5	NUM
eurjchem-990	225	169	.	.	PUNCT
eurjchem-990	226	1	the	the	DET
eurjchem-990	226	2	optimized	optimize	VERB
eurjchem-990	226	3	structural	structural	ADJ
eurjchem-990	226	4	geometry	geometry	NOUN
eurjchem-990	226	5	of	of	ADP
eurjchem-990	226	6	[	[	X
eurjchem-990	226	7	co(ephc)(1,10‐phen)cl	co(ephc)(1,10‐phen)cl	X
eurjchem-990	226	8	]	]	X
eurjchem-990	226	9	(	(	PUNCT
eurjchem-990	226	10	3	3	NUM
eurjchem-990	226	11	)	)	PUNCT
eurjchem-990	226	12	along	along	ADP
eurjchem-990	226	13	with	with	ADP
eurjchem-990	226	14	the	the	DET
eurjchem-990	226	15	atom	atom	NOUN
eurjchem-990	226	16	numbering	numbering	NOUN
eurjchem-990	226	17	scheme	scheme	NOUN
eurjchem-990	226	18	.	.	PUNCT
eurjchem-990	227	1	this	this	PRON
eurjchem-990	227	2	means	mean	VERB
eurjchem-990	227	3	that	that	SCONJ
eurjchem-990	227	4	,	,	PUNCT
eurjchem-990	227	5	c	c	X
eurjchem-990	227	6	–	–	PUNCT
eurjchem-990	227	7	s	s	NOUN
eurjchem-990	227	8	distances	distance	NOUN
eurjchem-990	227	9	which	which	PRON
eurjchem-990	227	10	are	be	AUX
eurjchem-990	227	11	in	in	ADP
eurjchem-990	227	12	the	the	DET
eurjchem-990	227	13	range	range	NOUN
eurjchem-990	227	14	of	of	ADP
eurjchem-990	227	15	single	single	ADJ
eurjchem-990	227	16	bond	bond	NOUN
eurjchem-990	227	17	character	character	NOUN
eurjchem-990	227	18	being	be	AUX
eurjchem-990	227	19	some	some	PRON
eurjchem-990	227	20	of	of	ADP
eurjchem-990	227	21	the	the	DET
eurjchem-990	227	22	largest	large	ADJ
eurjchem-990	227	23	found	find	VERB
eurjchem-990	227	24	for	for	ADP
eurjchem-990	227	25	m(ii	m(ii	NOUN
eurjchem-990	227	26	)	)	PUNCT
eurjchem-990	227	27	complexes	complex	NOUN
eurjchem-990	227	28	(	(	PUNCT
eurjchem-990	227	29	typical	typical	ADJ
eurjchem-990	227	30	bond	bond	NOUN
eurjchem-990	227	31	lengths	length	NOUN
eurjchem-990	227	32	being	be	AUX
eurjchem-990	227	33	c(sp2)–s	c(sp2)–	VERB
eurjchem-990	227	34	1.706	1.706	NUM
eurjchem-990	227	35	å	å	PROPN
eurjchem-990	227	36	in	in	ADP
eurjchem-990	227	37	(	(	PUNCT
eurjchem-990	227	38	mes)2c	mes)2c	PROPN
eurjchem-990	227	39	=	=	SYM
eurjchem-990	227	40	c(sme)2	c(sme)2	X
eurjchem-990	227	41	and	and	CCONJ
eurjchem-990	227	42	c	c	X
eurjchem-990	227	43	=	=	SYM
eurjchem-990	227	44	s	s	PART
eurjchem-990	227	45	1.630	1.630	NUM
eurjchem-990	227	46	å	å	NOUN
eurjchem-990	227	47	in	in	ADP
eurjchem-990	227	48	naphthylphenyl	naphthylphenyl	ADJ
eurjchem-990	227	49	thioketone	thioketone	NOUN
eurjchem-990	227	50	)	)	PUNCT
eurjchem-990	228	1	[	[	X
eurjchem-990	228	2	73,74	73,74	NOUN
eurjchem-990	228	3	]	]	PUNCT
eurjchem-990	228	4	.	.	PUNCT
eurjchem-990	229	1	this	this	PRON
eurjchem-990	229	2	also	also	ADV
eurjchem-990	229	3	confirms	confirm	VERB
eurjchem-990	229	4	the	the	DET
eurjchem-990	229	5	ir	ir	PROPN
eurjchem-990	229	6	and	and	CCONJ
eurjchem-990	229	7	spectral	spectral	ADJ
eurjchem-990	229	8	data	datum	NOUN
eurjchem-990	229	9	which	which	PRON
eurjchem-990	229	10	assumed	assume	VERB
eurjchem-990	229	11	that	that	SCONJ
eurjchem-990	229	12	the	the	DET
eurjchem-990	229	13	c	c	NOUN
eurjchem-990	229	14	=	=	NOUN
eurjchem-990	229	15	s	s	X
eurjchem-990	229	16	on	on	ADP
eurjchem-990	229	17	coordination	coordination	NOUN
eurjchem-990	229	18	gains	gain	NOUN
eurjchem-990	229	19	c	c	NOUN
eurjchem-990	229	20	–	–	PUNCT
eurjchem-990	229	21	s	s	PART
eurjchem-990	229	22	character	character	NOUN
eurjchem-990	229	23	.	.	PUNCT
eurjchem-990	230	1	similar	similar	ADJ
eurjchem-990	230	2	structural	structural	ADJ
eurjchem-990	230	3	features	feature	NOUN
eurjchem-990	230	4	are	be	AUX
eurjchem-990	230	5	known	know	VERB
eurjchem-990	230	6	for	for	ADP
eurjchem-990	230	7	other	other	ADJ
eurjchem-990	230	8	metal	metal	NOUN
eurjchem-990	230	9	complexes	complex	NOUN
eurjchem-990	230	10	of	of	ADP
eurjchem-990	230	11	such	such	ADJ
eurjchem-990	230	12	ligands	ligand	NOUN
eurjchem-990	230	13	that	that	PRON
eurjchem-990	230	14	have	have	VERB
eurjchem-990	230	15	the	the	DET
eurjchem-990	230	16	same	same	ADJ
eurjchem-990	230	17	coordination	coordination	NOUN
eurjchem-990	230	18	sites	site	NOUN
eurjchem-990	230	19	[	[	X
eurjchem-990	230	20	75,76	75,76	NOUN
eurjchem-990	230	21	]	]	X
eurjchem-990	230	22	.	.	PUNCT
eurjchem-990	231	1	the	the	DET
eurjchem-990	231	2	other	other	ADJ
eurjchem-990	231	3	bond	bond	NOUN
eurjchem-990	231	4	lengths	length	NOUN
eurjchem-990	231	5	and	and	CCONJ
eurjchem-990	231	6	angles	angle	NOUN
eurjchem-990	231	7	also	also	ADV
eurjchem-990	231	8	suffer	suffer	VERB
eurjchem-990	231	9	some	some	DET
eurjchem-990	231	10	changes	change	NOUN
eurjchem-990	231	11	,	,	PUNCT
eurjchem-990	231	12	but	but	CCONJ
eurjchem-990	231	13	not	not	PART
eurjchem-990	231	14	significantly	significantly	ADV
eurjchem-990	231	15	.	.	PUNCT
eurjchem-990	232	1	in	in	ADP
eurjchem-990	232	2	general	general	ADJ
eurjchem-990	232	3	,	,	PUNCT
eurjchem-990	232	4	the	the	DET
eurjchem-990	232	5	m	m	PROPN
eurjchem-990	232	6	–	–	PUNCT
eurjchem-990	232	7	s	s	PART
eurjchem-990	232	8	bond	bond	NOUN
eurjchem-990	232	9	length	length	NOUN
eurjchem-990	232	10	is	be	AUX
eurjchem-990	232	11	longer	long	ADJ
eurjchem-990	232	12	than	than	ADP
eurjchem-990	232	13	that	that	PRON
eurjchem-990	232	14	of	of	ADP
eurjchem-990	232	15	m	m	PROPN
eurjchem-990	232	16	–	–	PUNCT
eurjchem-990	232	17	cl	cl	NOUN
eurjchem-990	232	18	for	for	ADP
eurjchem-990	232	19	the	the	DET
eurjchem-990	232	20	all	all	DET
eurjchem-990	232	21	m(ii	m(ii	PROPN
eurjchem-990	232	22	)	)	PUNCT
eurjchem-990	232	23	complexes	complex	NOUN
eurjchem-990	232	24	and	and	CCONJ
eurjchem-990	232	25	the	the	DET
eurjchem-990	232	26	m	m	PROPN
eurjchem-990	232	27	–	–	PUNCT
eurjchem-990	232	28	n	n	PRON
eurjchem-990	232	29	bond	bond	NOUN
eurjchem-990	232	30	length	length	NOUN
eurjchem-990	232	31	is	be	AUX
eurjchem-990	232	32	shorter	short	ADJ
eurjchem-990	232	33	than	than	ADP
eurjchem-990	232	34	m	m	PROPN
eurjchem-990	232	35	–	–	PUNCT
eurjchem-990	232	36	cl	cl	NOUN
eurjchem-990	232	37	bond	bond	NOUN
eurjchem-990	232	38	length	length	NOUN
eurjchem-990	232	39	showing	show	VERB
eurjchem-990	232	40	that	that	SCONJ
eurjchem-990	232	41	the	the	DET
eurjchem-990	232	42	bond	bond	NOUN
eurjchem-990	232	43	length	length	NOUN
eurjchem-990	232	44	obeyed	obey	VERB
eurjchem-990	232	45	this	this	DET
eurjchem-990	232	46	order	order	NOUN
eurjchem-990	232	47	m	m	PRON
eurjchem-990	232	48	–	–	PUNCT
eurjchem-990	232	49	s	s	PART
eurjchem-990	232	50	>	>	X
eurjchem-990	232	51	m	m	PROPN
eurjchem-990	232	52	–	–	PUNCT
eurjchem-990	232	53	cl	cl	NOUN
eurjchem-990	232	54	>	>	X
eurjchem-990	232	55	m	m	PROPN
eurjchem-990	232	56	–	–	PUNCT
eurjchem-990	232	57	n.	n.	NOUN
eurjchem-990	232	58	in	in	ADP
eurjchem-990	232	59	all	all	DET
eurjchem-990	232	60	complexes	complex	NOUN
eurjchem-990	232	61	,	,	PUNCT
eurjchem-990	232	62	c	c	X
eurjchem-990	232	63	=	=	SYM
eurjchem-990	232	64	npy	npy	PROPN
eurjchem-990	232	65	bond	bond	NOUN
eurjchem-990	232	66	distance	distance	NOUN
eurjchem-990	232	67	of	of	ADP
eurjchem-990	232	68	the	the	DET
eurjchem-990	232	69	pyridine	pyridine	NOUN
eurjchem-990	232	70	ring	ring	NOUN
eurjchem-990	232	71	is	be	AUX
eurjchem-990	232	72	elongated	elongate	VERB
eurjchem-990	232	73	.	.	PUNCT
eurjchem-990	233	1	owing	owe	VERB
eurjchem-990	233	2	to	to	ADP
eurjchem-990	233	3	the	the	DET
eurjchem-990	233	4	formation	formation	NOUN
eurjchem-990	233	5	of	of	ADP
eurjchem-990	233	6	the	the	DET
eurjchem-990	233	7	m‐n	m‐n	PROPN
eurjchem-990	233	8	bond	bond	NOUN
eurjchem-990	233	9	which	which	PRON
eurjchem-990	233	10	makes	make	VERB
eurjchem-990	233	11	the	the	DET
eurjchem-990	233	12	c	c	NOUN
eurjchem-990	233	13	=	=	NOUN
eurjchem-990	233	14	n	n	PRON
eurjchem-990	233	15	bond	bond	NOUN
eurjchem-990	233	16	weaker	weak	ADJ
eurjchem-990	233	17	as	as	ADP
eurjchem-990	233	18	a	a	DET
eurjchem-990	233	19	result	result	NOUN
eurjchem-990	233	20	of	of	ADP
eurjchem-990	233	21	coordination	coordination	NOUN
eurjchem-990	233	22	.	.	PUNCT
eurjchem-990	234	1	the	the	DET
eurjchem-990	234	2	bond	bond	NOUN
eurjchem-990	234	3	angles	angle	NOUN
eurjchem-990	234	4	of	of	ADP
eurjchem-990	234	5	the	the	DET
eurjchem-990	234	6	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-990	234	7	moiety	moiety	NOUN
eurjchem-990	234	8	of	of	ADP
eurjchem-990	234	9	ephc	ephc	NOUN
eurjchem-990	234	10	are	be	AUX
eurjchem-990	234	11	altered	alter	VERB
eurjchem-990	234	12	somewhat	somewhat	ADV
eurjchem-990	234	13	upon	upon	SCONJ
eurjchem-990	234	14	coordination	coordination	NOUN
eurjchem-990	234	15	and	and	CCONJ
eurjchem-990	234	16	may	may	AUX
eurjchem-990	234	17	be	be	AUX
eurjchem-990	234	18	reduced	reduce	VERB
eurjchem-990	234	19	or	or	CCONJ
eurjchem-990	234	20	increased	increase	VERB
eurjchem-990	234	21	on	on	ADP
eurjchem-990	234	22	complex	complex	ADJ
eurjchem-990	234	23	formation	formation	NOUN
eurjchem-990	234	24	as	as	ADP
eurjchem-990	234	25	a	a	DET
eurjchem-990	234	26	consequence	consequence	NOUN
eurjchem-990	234	27	of	of	ADP
eurjchem-990	234	28	bonding	bonding	NOUN
eurjchem-990	234	29	.	.	PUNCT
eurjchem-990	235	1	the	the	DET
eurjchem-990	235	2	bond	bond	NOUN
eurjchem-990	235	3	angles	angle	VERB
eurjchem-990	235	4	around	around	ADP
eurjchem-990	235	5	the	the	DET
eurjchem-990	235	6	m(ii	m(ii	NOUN
eurjchem-990	235	7	)	)	PUNCT
eurjchem-990	235	8	center	center	NOUN
eurjchem-990	235	9	(	(	PUNCT
eurjchem-990	235	10	≃90	≃90	PROPN
eurjchem-990	235	11	)	)	PUNCT
eurjchem-990	235	12	prove	prove	VERB
eurjchem-990	235	13	that	that	SCONJ
eurjchem-990	235	14	the	the	DET
eurjchem-990	235	15	geometric	geometric	NOUN
eurjchem-990	235	16	is	be	AUX
eurjchem-990	235	17	octahedral	octahedral	ADJ
eurjchem-990	235	18	as	as	SCONJ
eurjchem-990	235	19	proposed	propose	VERB
eurjchem-990	235	20	by	by	ADP
eurjchem-990	235	21	the	the	DET
eurjchem-990	235	22	different	different	ADJ
eurjchem-990	235	23	tools	tool	NOUN
eurjchem-990	235	24	of	of	ADP
eurjchem-990	235	25	analysis	analysis	NOUN
eurjchem-990	235	26	mentioned	mention	VERB
eurjchem-990	235	27	previously	previously	ADV
eurjchem-990	235	28	.	.	PUNCT
eurjchem-990	236	1	finally	finally	ADV
eurjchem-990	236	2	,	,	PUNCT
eurjchem-990	236	3	from	from	ADP
eurjchem-990	236	4	the	the	DET
eurjchem-990	236	5	interpretation	interpretation	NOUN
eurjchem-990	236	6	of	of	ADP
eurjchem-990	236	7	elemental	elemental	ADJ
eurjchem-990	236	8	analysis	analysis	NOUN
eurjchem-990	236	9	,	,	PUNCT
eurjchem-990	236	10	spectral	spectral	ADJ
eurjchem-990	236	11	data	datum	NOUN
eurjchem-990	236	12	(	(	PUNCT
eurjchem-990	236	13	infrared	infrared	ADJ
eurjchem-990	236	14	,	,	PUNCT
eurjchem-990	236	15	electronic	electronic	ADJ
eurjchem-990	236	16	and	and	CCONJ
eurjchem-990	236	17	esr	esr	NOUN
eurjchem-990	236	18	)	)	PUNCT
eurjchem-990	236	19	as	as	ADV
eurjchem-990	236	20	well	well	ADV
eurjchem-990	236	21	as	as	ADP
eurjchem-990	236	22	magnetic	magnetic	ADJ
eurjchem-990	236	23	susceptibility	susceptibility	NOUN
eurjchem-990	236	24	measurements	measurement	NOUN
eurjchem-990	236	25	at	at	ADP
eurjchem-990	236	26	room	room	NOUN
eurjchem-990	236	27	temperature	temperature	NOUN
eurjchem-990	236	28	,	,	PUNCT
eurjchem-990	236	29	conductivity	conductivity	NOUN
eurjchem-990	236	30	measurements	measurement	NOUN
eurjchem-990	236	31	and	and	CCONJ
eurjchem-990	236	32	qm	qm	PROPN
eurjchem-990	236	33	calculations	calculation	NOUN
eurjchem-990	236	34	,	,	PUNCT
eurjchem-990	236	35	it	it	PRON
eurjchem-990	236	36	is	be	AUX
eurjchem-990	236	37	possible	possible	ADJ
eurjchem-990	236	38	to	to	PART
eurjchem-990	236	39	draw	draw	VERB
eurjchem-990	236	40	up	up	ADP
eurjchem-990	236	41	the	the	DET
eurjchem-990	236	42	tentative	tentative	ADJ
eurjchem-990	236	43	octahedral	octahedral	ADJ
eurjchem-990	236	44	structures	structure	NOUN
eurjchem-990	236	45	of	of	ADP
eurjchem-990	236	46	the	the	DET
eurjchem-990	236	47	metal	metal	NOUN
eurjchem-990	236	48	complexes	complex	NOUN
eurjchem-990	236	49	.	.	PUNCT
eurjchem-990	237	1	4	4	X
eurjchem-990	237	2	.	.	X
eurjchem-990	237	3	conclusions	conclusion	NOUN
eurjchem-990	237	4	the	the	DET
eurjchem-990	237	5	reaction	reaction	NOUN
eurjchem-990	237	6	of	of	ADP
eurjchem-990	237	7	2‐picolinic	2‐picolinic	ADJ
eurjchem-990	237	8	acid	acid	NOUN
eurjchem-990	237	9	hydrazide	hydrazide	ADV
eurjchem-990	237	10	with	with	ADP
eurjchem-990	237	11	ethyl	ethyl	PROPN
eurjchem-990	237	12	isothiocyanate	isothiocyanate	NOUN
eurjchem-990	237	13	afforded	afford	VERB
eurjchem-990	237	14	the	the	DET
eurjchem-990	237	15	corresponding	correspond	VERB
eurjchem-990	237	16	n‐ethyl‐2‐picolinoyl	n‐ethyl‐2‐picolinoyl	PROPN
eurjchem-990	237	17	hydrazinecarbothioamide	hydrazinecarbothioamide	ADJ
eurjchem-990	237	18	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-990	237	19	compound	compound	NOUN
eurjchem-990	237	20	.	.	PUNCT
eurjchem-990	238	1	the	the	DET
eurjchem-990	238	2	bonding	bonding	NOUN
eurjchem-990	238	3	of	of	ADP
eurjchem-990	238	4	ligands	ligand	NOUN
eurjchem-990	238	5	to	to	ADP
eurjchem-990	238	6	the	the	DET
eurjchem-990	238	7	metal	metal	NOUN
eurjchem-990	238	8	ion	ion	NOUN
eurjchem-990	238	9	is	be	AUX
eurjchem-990	238	10	confirmed	confirm	VERB
eurjchem-990	238	11	by	by	ADP
eurjchem-990	238	12	analytical	analytical	ADJ
eurjchem-990	238	13	,	,	PUNCT
eurjchem-990	238	14	spectral	spectral	ADJ
eurjchem-990	238	15	and	and	CCONJ
eurjchem-990	238	16	magnetic	magnetic	ADJ
eurjchem-990	238	17	measurements	measurement	NOUN
eurjchem-990	238	18	.	.	PUNCT
eurjchem-990	239	1	the	the	DET
eurjchem-990	239	2	ir	ir	PROPN
eurjchem-990	239	3	spectra	spectra	PROPN
eurjchem-990	239	4	showed	show	VERB
eurjchem-990	239	5	that	that	SCONJ
eurjchem-990	239	6	,	,	PUNCT
eurjchem-990	239	7	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-990	239	8	compound	compound	NOUN
eurjchem-990	239	9	present	present	ADJ
eurjchem-990	239	10	in	in	ADP
eurjchem-990	239	11	the	the	DET
eurjchem-990	239	12	thione	thione	ADJ
eurjchem-990	239	13	form	form	NOUN
eurjchem-990	239	14	in	in	ADP
eurjchem-990	239	15	the	the	DET
eurjchem-990	239	16	solid	solid	ADJ
eurjchem-990	239	17	state	state	NOUN
eurjchem-990	239	18	.	.	PUNCT
eurjchem-990	240	1	in	in	ADP
eurjchem-990	240	2	the	the	DET
eurjchem-990	240	3	absence	absence	NOUN
eurjchem-990	240	4	of	of	ADP
eurjchem-990	240	5	x‐ray	x‐ray	PROPN
eurjchem-990	240	6	single	single	ADJ
eurjchem-990	240	7	crystal	crystal	PROPN
eurjchem-990	240	8	data	datum	NOUN
eurjchem-990	240	9	of	of	ADP
eurjchem-990	240	10	the	the	DET
eurjchem-990	240	11	current	current	ADJ
eurjchem-990	240	12	synthesized	synthesize	VERB
eurjchem-990	240	13	complexes	complex	NOUN
eurjchem-990	240	14	and	and	CCONJ
eurjchem-990	240	15	based	base	VERB
eurjchem-990	240	16	on	on	ADP
eurjchem-990	240	17	the	the	DET
eurjchem-990	240	18	physicochemical	physicochemical	ADJ
eurjchem-990	240	19	studies	study	NOUN
eurjchem-990	240	20	and	and	CCONJ
eurjchem-990	240	21	geometrical	geometrical	ADJ
eurjchem-990	240	22	optimization	optimization	NOUN
eurjchem-990	240	23	,	,	PUNCT
eurjchem-990	240	24	a	a	DET
eurjchem-990	240	25	tentative	tentative	ADJ
eurjchem-990	240	26	structure	structure	NOUN
eurjchem-990	240	27	could	could	AUX
eurjchem-990	240	28	be	be	AUX
eurjchem-990	240	29	proposed	propose	VERB
eurjchem-990	240	30	as	as	SCONJ
eurjchem-990	240	31	shown	show	VERB
eurjchem-990	240	32	in	in	ADP
eurjchem-990	240	33	figures	figure	NOUN
eurjchem-990	240	34	3‐5	3‐5	NUM
eurjchem-990	240	35	.	.	PUNCT
eurjchem-990	241	1	m(ii)‐complexes	m(ii)‐complexe	NOUN
eurjchem-990	241	2	are	be	AUX
eurjchem-990	241	3	formulated	formulate	VERB
eurjchem-990	241	4	as	as	ADP
eurjchem-990	241	5	[	[	X
eurjchem-990	241	6	m(ephc)(1,10‐	m(ephc)(1,10‐	PROPN
eurjchem-990	241	7	phen)cl].nh2o	phen)cl].nh2o	NOUN
eurjchem-990	241	8	where	where	SCONJ
eurjchem-990	241	9	ephc	ephc	NOUN
eurjchem-990	241	10	is	be	AUX
eurjchem-990	241	11	the	the	DET
eurjchem-990	241	12	deprotonated	deprotonate	VERB
eurjchem-990	241	13	thiosemi‐	thiosemi‐	PRON
eurjchem-990	241	14	carbazone	carbazone	NOUN
eurjchem-990	241	15	ligand	ligand	NOUN
eurjchem-990	241	16	.	.	PUNCT
eurjchem-990	242	1	in	in	ADP
eurjchem-990	242	2	these	these	DET
eurjchem-990	242	3	complexes	complex	NOUN
eurjchem-990	242	4	the	the	DET
eurjchem-990	242	5	thiosemicarbazone	thiosemicarbazone	NOUN
eurjchem-990	242	6	ligand	ligand	NOUN
eurjchem-990	242	7	is	be	AUX
eurjchem-990	242	8	coordinated	coordinate	VERB
eurjchem-990	242	9	to	to	ADP
eurjchem-990	242	10	the	the	DET
eurjchem-990	242	11	metal	metal	NOUN
eurjchem-990	242	12	(	(	PUNCT
eurjchem-990	242	13	ii	ii	NOUN
eurjchem-990	242	14	)	)	PUNCT
eurjchem-990	242	15	ion	ion	NOUN
eurjchem-990	242	16	as	as	ADP
eurjchem-990	242	17	a	a	DET
eurjchem-990	242	18	tridentate	tridentate	NOUN
eurjchem-990	242	19	anion	anion	NOUN
eurjchem-990	242	20	,	,	PUNCT
eurjchem-990	242	21	coordinating	coordinate	VERB
eurjchem-990	242	22	via	via	ADP
eurjchem-990	242	23	the	the	DET
eurjchem-990	242	24	azomethine	azomethine	NOUN
eurjchem-990	242	25	nitrogen	nitrogen	NOUN
eurjchem-990	242	26	,	,	PUNCT
eurjchem-990	242	27	pyridine	pyridine	ADJ
eurjchem-990	242	28	nitrogen	nitrogen	NOUN
eurjchem-990	242	29	atoms	atom	NOUN
eurjchem-990	242	30	and	and	CCONJ
eurjchem-990	242	31	the	the	DET
eurjchem-990	242	32	thiolate	thiolate	ADJ
eurjchem-990	242	33	sulfur	sulfur	NOUN
eurjchem-990	242	34	atom	atom	NOUN
eurjchem-990	242	35	after	after	ADP
eurjchem-990	242	36	deprotonation	deprotonation	NOUN
eurjchem-990	242	37	.	.	PUNCT
eurjchem-990	243	1	from	from	ADP
eurjchem-990	243	2	elemental	elemental	ADJ
eurjchem-990	243	3	analysis	analysis	NOUN
eurjchem-990	243	4	,	,	PUNCT
eurjchem-990	243	5	ir	ir	INTJ
eurjchem-990	243	6	,	,	PUNCT
eurjchem-990	243	7	spectral	spectral	ADJ
eurjchem-990	243	8	,	,	PUNCT
eurjchem-990	243	9	thermal	thermal	ADJ
eurjchem-990	243	10	analysis	analysis	NOUN
eurjchem-990	243	11	,	,	PUNCT
eurjchem-990	243	12	magnetic	magnetic	ADJ
eurjchem-990	243	13	and	and	CCONJ
eurjchem-990	243	14	conductance	conductance	NOUN
eurjchem-990	243	15	measurements	measurement	NOUN
eurjchem-990	243	16	,	,	PUNCT
eurjchem-990	243	17	all	all	DET
eurjchem-990	243	18	m(ii)‐complexes	m(ii)‐complexe	NOUN
eurjchem-990	243	19	are	be	AUX
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eurjchem-990	243	22	octahedral	octahedral	ADJ
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eurjchem-990	244	2	this	this	DET
eurjchem-990	244	3	work	work	NOUN
eurjchem-990	244	4	,	,	PUNCT
eurjchem-990	244	5	it	it	PRON
eurjchem-990	244	6	was	be	AUX
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eurjchem-990	244	16	5	5	NUM
eurjchem-990	244	17	(	(	PUNCT
eurjchem-990	244	18	2	2	NUM
eurjchem-990	244	19	)	)	PUNCT
eurjchem-990	244	20	(	(	PUNCT
eurjchem-990	244	21	2014	2014	NUM
eurjchem-990	244	22	)	)	PUNCT
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eurjchem-990	244	24	259	259	NUM
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eurjchem-990	244	28	m(ii	m(ii	PROPN
eurjchem-990	244	29	)	)	PUNCT
eurjchem-990	244	30	compounds	compound	NOUN
eurjchem-990	244	31	show	show	VERB
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eurjchem-990	244	33	different	different	ADJ
eurjchem-990	244	34	levels	level	NOUN
eurjchem-990	244	35	of	of	ADP
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eurjchem-990	245	4	antifungal	antifungal	PROPN
eurjchem-990	245	5	,	,	PUNCT
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eurjchem-990	245	9	that	that	SCONJ
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eurjchem-990	245	12	compounds	compound	NOUN
eurjchem-990	245	13	are	be	AUX
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eurjchem-990	245	15	antimicrobial	antimicrobial	ADJ
eurjchem-990	245	16	agents	agent	NOUN
eurjchem-990	245	17	.	.	PUNCT
eurjchem-990	246	1	references	reference	NOUN
eurjchem-990	246	2	[	[	X
eurjchem-990	246	3	1	1	NUM
eurjchem-990	246	4	]	]	PUNCT
eurjchem-990	246	5	.	.	PUNCT
eurjchem-990	247	1	lakshmi	lakshmi	PROPN
eurjchem-990	247	2	,	,	PUNCT
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eurjchem-990	247	8	g.	g.	PROPN
eurjchem-990	247	9	;	;	PUNCT
eurjchem-990	247	10	shivananda	shivananda	PROPN
eurjchem-990	247	11	,	,	PUNCT
eurjchem-990	247	12	k.	k.	PROPN
eurjchem-990	247	13	n.	n.	PROPN
eurjchem-990	247	14	;	;	PUNCT
eurjchem-990	247	15	nagella	nagella	ADV
eurjchem-990	247	16	,	,	PUNCT
eurjchem-990	247	17	p.	p.	NOUN
eurjchem-990	247	18	;	;	PUNCT
eurjchem-990	247	19	manohar	manohar	PROPN
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eurjchem-990	247	21	s.	s.	PROPN
eurjchem-990	247	22	h.	h.	PROPN
eurjchem-990	247	23	;	;	PUNCT
eurjchem-990	247	24	mahendra	mahendra	PROPN
eurjchem-990	247	25	,	,	PUNCT
eurjchem-990	247	26	k.	k.	PROPN
eurjchem-990	247	27	n.	n.	PROPN
eurjchem-990	247	28	polyhedron	polyhedron	PROPN
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eurjchem-990	247	30	,	,	PUNCT
eurjchem-990	247	31	30	30	NUM
eurjchem-990	247	32	,	,	PUNCT
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eurjchem-990	247	34	.	.	PUNCT
eurjchem-990	248	1	[	[	X
eurjchem-990	248	2	2	2	NUM
eurjchem-990	248	3	]	]	PUNCT
eurjchem-990	248	4	.	.	PUNCT
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eurjchem-990	249	6	,	,	PUNCT
eurjchem-990	249	7	y.	y.	PROPN
eurjchem-990	249	8	;	;	PUNCT
eurjchem-990	249	9	liu	liu	PROPN
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eurjchem-990	249	12	;	;	PUNCT
eurjchem-990	249	13	afrasiabi	afrasiabi	NOUN
eurjchem-990	249	14	,	,	PUNCT
eurjchem-990	249	15	z.	z.	PROPN
eurjchem-990	249	16	;	;	PUNCT
eurjchem-990	249	17	sinn	sinn	PROPN
eurjchem-990	249	18	,	,	PUNCT
eurjchem-990	249	19	e.	e.	PROPN
eurjchem-990	249	20	;	;	PUNCT
eurjchem-990	249	21	padhye	padhye	NOUN
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eurjchem-990	249	23	s.	s.	PROPN
eurjchem-990	249	24	;	;	PUNCT
eurjchem-990	249	25	ma	ma	PROPN
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eurjchem-990	249	27	y.	y.	PROPN
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eurjchem-990	250	1	appl	appl	PROPN
eurjchem-990	250	2	.	.	PUNCT
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eurjchem-990	251	2	.	.	PUNCT
eurjchem-990	252	1	2004	2004	NUM
eurjchem-990	252	2	,	,	PUNCT
eurjchem-990	252	3	197	197	NUM
eurjchem-990	252	4	,	,	PUNCT
eurjchem-990	252	5	40‐48	40‐48	NUM
eurjchem-990	252	6	.	.	PUNCT
eurjchem-990	253	1	[	[	X
eurjchem-990	253	2	3	3	NUM
eurjchem-990	253	3	]	]	PUNCT
eurjchem-990	253	4	.	.	PUNCT
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eurjchem-990	254	7	h.	h.	PROPN
eurjchem-990	254	8	;	;	PUNCT
eurjchem-990	254	9	wiggall	wiggall	PROPN
eurjchem-990	254	10	,	,	PUNCT
eurjchem-990	254	11	k.	k.	PROPN
eurjchem-990	254	12	j.	j.	PROPN
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eurjchem-990	255	1	zhang	zhang	PROPN
eurjchem-990	255	2	,	,	PUNCT
eurjchem-990	255	3	l.	l.	PROPN
eurjchem-990	255	4	;	;	PUNCT
eurjchem-990	255	5	luengo	luengo	PROPN
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eurjchem-990	255	7	j.	j.	PROPN
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eurjchem-990	255	9	j.	j.	PROPN
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eurjchem-990	256	1	2002	2002	NUM
eurjchem-990	256	2	,	,	PUNCT
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eurjchem-990	256	4	,	,	PUNCT
eurjchem-990	256	5	3573‐3575	3573‐3575	NUM
eurjchem-990	256	6	.	.	PUNCT
eurjchem-990	257	1	[	[	X
eurjchem-990	257	2	4	4	NUM
eurjchem-990	257	3	]	]	PUNCT
eurjchem-990	257	4	.	.	PUNCT
eurjchem-990	257	5	du	du	PROPN
eurjchem-990	257	6	,	,	PUNCT
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eurjchem-990	257	8	;	;	PUNCT
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eurjchem-990	257	45	.	.	PUNCT
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eurjchem-990	258	2	,	,	PUNCT
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eurjchem-990	258	4	,	,	PUNCT
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eurjchem-990	259	3	]	]	PUNCT
eurjchem-990	259	4	.	.	PUNCT
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eurjchem-990	261	23	.	.	PUNCT
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eurjchem-990	262	2	,	,	PUNCT
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eurjchem-990	263	1	[	[	X
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eurjchem-990	263	3	]	]	PUNCT
eurjchem-990	263	4	.	.	PUNCT
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eurjchem-990	264	5	scovill	scovill	PROPN
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eurjchem-990	265	2	,	,	PUNCT
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eurjchem-990	265	4	,	,	PUNCT
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eurjchem-990	265	6	.	.	PUNCT
eurjchem-990	266	1	[	[	X
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eurjchem-990	266	4	.	.	PUNCT
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eurjchem-990	266	7	d.	d.	PROPN
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eurjchem-990	267	2	.	.	PUNCT
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eurjchem-990	268	2	,	,	PUNCT
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eurjchem-990	268	4	,	,	PUNCT
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eurjchem-990	268	6	.	.	PUNCT
eurjchem-990	269	1	[	[	X
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eurjchem-990	269	3	]	]	PUNCT
eurjchem-990	269	4	.	.	PUNCT
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eurjchem-990	269	29	.	.	PUNCT
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eurjchem-990	271	2	,	,	PUNCT
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eurjchem-990	271	4	,	,	PUNCT
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eurjchem-990	271	6	.	.	PUNCT
eurjchem-990	272	1	[	[	X
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eurjchem-990	316	3	,	,	PUNCT
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eurjchem-990	316	5	,	,	PUNCT
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eurjchem-990	316	7	.	.	PUNCT
eurjchem-990	317	1	[	[	X
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eurjchem-990	317	3	]	]	PUNCT
eurjchem-990	317	4	.	.	PUNCT
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eurjchem-990	320	4	,	,	PUNCT
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eurjchem-990	321	3	]	]	PUNCT
eurjchem-990	321	4	.	.	PUNCT
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eurjchem-990	323	3	]	]	PUNCT
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eurjchem-990	326	4	.	.	PUNCT
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eurjchem-990	327	2	,	,	PUNCT
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eurjchem-990	327	15	turck	turck	ADV
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eurjchem-990	328	1	j.	j.	PROPN
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eurjchem-990	329	2	.	.	PUNCT
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eurjchem-990	330	2	,	,	PUNCT
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eurjchem-990	330	4	,	,	PUNCT
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eurjchem-990	331	1	[	[	X
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eurjchem-990	331	3	]	]	PUNCT
eurjchem-990	331	4	.	.	PUNCT
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eurjchem-990	333	2	.	.	PUNCT
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eurjchem-990	334	2	.	.	PUNCT
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eurjchem-990	335	2	,	,	PUNCT
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eurjchem-990	335	4	,	,	PUNCT
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eurjchem-990	335	6	.	.	PUNCT
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eurjchem-990	336	3	]	]	PUNCT
eurjchem-990	336	4	.	.	PUNCT
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eurjchem-990	337	7	,	,	PUNCT
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eurjchem-990	337	19	j.	j.	PROPN
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eurjchem-990	338	2	.	.	PUNCT
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eurjchem-990	339	2	,	,	PUNCT
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eurjchem-990	339	4	,	,	PUNCT
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eurjchem-990	339	6	.	.	PUNCT
eurjchem-990	340	1	[	[	X
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eurjchem-990	340	3	]	]	PUNCT
eurjchem-990	340	4	.	.	PUNCT
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eurjchem-990	342	1	[	[	X
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eurjchem-990	342	3	]	]	PUNCT
eurjchem-990	342	4	.	.	PUNCT
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eurjchem-990	345	6	.	.	PUNCT
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eurjchem-990	346	4	.	.	PUNCT
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eurjchem-990	349	2	,	,	PUNCT
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eurjchem-990	350	4	.	.	PUNCT
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eurjchem-990	353	2	,	,	PUNCT
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eurjchem-990	353	4	,	,	PUNCT
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eurjchem-990	353	6	.	.	PUNCT
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eurjchem-990	354	4	.	.	PUNCT
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eurjchem-990	355	18	.	.	PUNCT
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eurjchem-990	357	2	,	,	PUNCT
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eurjchem-990	358	4	.	.	PUNCT
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eurjchem-990	362	2	.	.	PUNCT
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eurjchem-990	364	2	,	,	PUNCT
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eurjchem-990	365	4	.	.	PUNCT
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eurjchem-990	366	9	;	;	PUNCT
eurjchem-990	366	10	rajakannan	rajakannan	NOUN
eurjchem-990	366	11	,	,	PUNCT
eurjchem-990	366	12	v.	v.	PROPN
eurjchem-990	366	13	;	;	PUNCT
eurjchem-990	366	14	ajith	ajith	PROPN
eurjchem-990	366	15	,	,	PUNCT
eurjchem-990	366	16	t.	t.	PROPN
eurjchem-990	366	17	a.	a.	NOUN
eurjchem-990	366	18	;	;	PUNCT
eurjchem-990	366	19	kurup	kurup	NOUN
eurjchem-990	366	20	,	,	PUNCT
eurjchem-990	366	21	m.	m.	PROPN
eurjchem-990	366	22	r.	r.	PROPN
eurjchem-990	366	23	p.	p.	PROPN
eurjchem-990	366	24	polyhedron	polyhedron	PROPN
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eurjchem-990	366	26	,	,	PUNCT
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eurjchem-990	366	28	,	,	PUNCT
eurjchem-990	366	29	2549‐2559	2549‐2559	NUM
eurjchem-990	366	30	.	.	PUNCT
eurjchem-990	367	1	[	[	X
eurjchem-990	367	2	36	36	NUM
eurjchem-990	367	3	]	]	PUNCT
eurjchem-990	367	4	.	.	PUNCT
eurjchem-990	368	1	sreekanth	sreekanth	ADJ
eurjchem-990	368	2	,	,	PUNCT
eurjchem-990	368	3	a.	a.	NOUN
eurjchem-990	368	4	;	;	PUNCT
eurjchem-990	368	5	joseph	joseph	PROPN
eurjchem-990	368	6	,	,	PUNCT
eurjchem-990	368	7	m.	m.	NOUN
eurjchem-990	368	8	;	;	PUNCT
eurjchem-990	368	9	fun	fun	NOUN
eurjchem-990	368	10	,	,	PUNCT
eurjchem-990	368	11	h.	h.	PROPN
eurjchem-990	368	12	k.	k.	PROPN
eurjchem-990	368	13	;	;	PUNCT
eurjchem-990	368	14	kurup	kurup	NOUN
eurjchem-990	368	15	,	,	PUNCT
eurjchem-990	368	16	m.	m.	PROPN
eurjchem-990	368	17	r.	r.	PROPN
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eurjchem-990	368	19	polyhedron	polyhedron	PROPN
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eurjchem-990	368	21	,	,	PUNCT
eurjchem-990	368	22	25	25	NUM
eurjchem-990	368	23	,	,	PUNCT
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eurjchem-990	368	25	.	.	PUNCT
eurjchem-990	369	1	[	[	X
eurjchem-990	369	2	37	37	NUM
eurjchem-990	369	3	]	]	PUNCT
eurjchem-990	369	4	.	.	PUNCT
eurjchem-990	370	1	philip	philip	PROPN
eurjchem-990	370	2	,	,	PUNCT
eurjchem-990	370	3	v.	v.	PROPN
eurjchem-990	370	4	;	;	PUNCT
eurjchem-990	370	5	suni	suni	X
eurjchem-990	370	6	,	,	PUNCT
eurjchem-990	370	7	v.	v.	ADP
eurjchem-990	370	8	;	;	PUNCT
eurjchem-990	370	9	kurup	kurup	NOUN
eurjchem-990	370	10	,	,	PUNCT
eurjchem-990	370	11	m.	m.	PROPN
eurjchem-990	370	12	r.	r.	PROPN
eurjchem-990	370	13	p.	p.	PROPN
eurjchem-990	370	14	;	;	PUNCT
eurjchem-990	370	15	nethaji	nethaji	PROPN
eurjchem-990	370	16	,	,	PUNCT
eurjchem-990	370	17	m.	m.	NOUN
eurjchem-990	370	18	polyhedron	polyhedron	NOUN
eurjchem-990	370	19	2004	2004	NUM
eurjchem-990	370	20	,	,	PUNCT
eurjchem-990	370	21	23	23	NUM
eurjchem-990	370	22	,	,	PUNCT
eurjchem-990	370	23	1225‐1233	1225‐1233	NUM
eurjchem-990	370	24	.	.	PUNCT
eurjchem-990	371	1	[	[	X
eurjchem-990	371	2	38	38	NUM
eurjchem-990	371	3	]	]	PUNCT
eurjchem-990	371	4	.	.	PUNCT
eurjchem-990	372	1	lever	lever	PROPN
eurjchem-990	372	2	,	,	PUNCT
eurjchem-990	372	3	a.	a.	PROPN
eurjchem-990	372	4	b.	b.	PROPN
eurjchem-990	372	5	p.	p.	PROPN
eurjchem-990	372	6	inorganic	inorganic	ADJ
eurjchem-990	372	7	electronic	electronic	ADJ
eurjchem-990	372	8	spectroscopy	spectroscopy	NOUN
eurjchem-990	372	9	,	,	PUNCT
eurjchem-990	372	10	2nd	2nd	ADJ
eurjchem-990	372	11	edition	edition	NOUN
eurjchem-990	372	12	,	,	PUNCT
eurjchem-990	372	13	elsevier	elsevier	NOUN
eurjchem-990	372	14	,	,	PUNCT
eurjchem-990	372	15	amsterdam	amsterdam	PROPN
eurjchem-990	372	16	,	,	PUNCT
eurjchem-990	372	17	1984	1984	NUM
eurjchem-990	372	18	.	.	PUNCT
eurjchem-990	373	1	[	[	X
eurjchem-990	373	2	39	39	NUM
eurjchem-990	373	3	]	]	PUNCT
eurjchem-990	373	4	.	.	PUNCT
eurjchem-990	374	1	el‐sherif	el‐sherif	PROPN
eurjchem-990	374	2	,	,	PUNCT
eurjchem-990	374	3	a.	a.	NOUN
eurjchem-990	374	4	a.	a.	NOUN
eurjchem-990	374	5	;	;	PUNCT
eurjchem-990	374	6	shoukry	shoukry	NOUN
eurjchem-990	374	7	,	,	PUNCT
eurjchem-990	374	8	m.	m.	NOUN
eurjchem-990	374	9	m.	m.	NOUN
eurjchem-990	374	10	;	;	PUNCT
eurjchem-990	374	11	abd‐elgawad	abd‐elgawad	NOUN
eurjchem-990	374	12	,	,	PUNCT
eurjchem-990	374	13	m.	m.	NOUN
eurjchem-990	374	14	m.	m.	PROPN
eurjchem-990	374	15	a.	a.	PROPN
eurjchem-990	374	16	spectrochim	spectrochim	PROPN
eurjchem-990	374	17	.	.	PUNCT
eurjchem-990	375	1	acta	acta	PROPN
eurjchem-990	375	2	a	a	DET
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eurjchem-990	375	4	,	,	PUNCT
eurjchem-990	375	5	98	98	NUM
eurjchem-990	375	6	,	,	PUNCT
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eurjchem-990	375	8	.	.	PUNCT
eurjchem-990	376	1	[	[	X
eurjchem-990	376	2	40	40	NUM
eurjchem-990	376	3	]	]	PUNCT
eurjchem-990	376	4	.	.	PUNCT
eurjchem-990	377	1	nakamoto	nakamoto	PROPN
eurjchem-990	377	2	,	,	PUNCT
eurjchem-990	377	3	k.	k.	PROPN
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eurjchem-990	377	13	,	,	PUNCT
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eurjchem-990	377	18	,	,	PUNCT
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eurjchem-990	377	20	.	.	PUNCT
eurjchem-990	378	1	[	[	X
eurjchem-990	378	2	41	41	NUM
eurjchem-990	378	3	]	]	PUNCT
eurjchem-990	378	4	.	.	PUNCT
eurjchem-990	379	1	philip	philip	PROPN
eurjchem-990	379	2	,	,	PUNCT
eurjchem-990	379	3	v.	v.	PROPN
eurjchem-990	379	4	;	;	PUNCT
eurjchem-990	379	5	suni	suni	X
eurjchem-990	379	6	,	,	PUNCT
eurjchem-990	379	7	v.	v.	ADP
eurjchem-990	379	8	;	;	PUNCT
eurjchem-990	379	9	kurup	kurup	NOUN
eurjchem-990	379	10	,	,	PUNCT
eurjchem-990	379	11	m.	m.	PROPN
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eurjchem-990	379	13	p.	p.	PROPN
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eurjchem-990	379	16	,	,	PUNCT
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eurjchem-990	379	18	,	,	PUNCT
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eurjchem-990	379	20	.	.	PUNCT
eurjchem-990	380	1	[	[	X
eurjchem-990	380	2	42	42	NUM
eurjchem-990	380	3	]	]	PUNCT
eurjchem-990	380	4	.	.	PUNCT
eurjchem-990	381	1	sankaraperumal	sankaraperumal	PROPN
eurjchem-990	381	2	,	,	PUNCT
eurjchem-990	381	3	a.	a.	NOUN
eurjchem-990	381	4	;	;	PUNCT
eurjchem-990	381	5	karthikeyan	karthikeyan	PROPN
eurjchem-990	381	6	,	,	PUNCT
eurjchem-990	381	7	j.	j.	PROPN
eurjchem-990	381	8	;	;	PUNCT
eurjchem-990	381	9	shetty	shetty	PROPN
eurjchem-990	381	10	,	,	PUNCT
eurjchem-990	381	11	a.	a.	PROPN
eurjchem-990	381	12	n.	n.	PROPN
eurjchem-990	381	13	;	;	PUNCT
eurjchem-990	381	14	lakshmisundaram	lakshmisundaram	PROPN
eurjchem-990	381	15	,	,	PUNCT
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eurjchem-990	381	17	polyhedron	polyhedron	PROPN
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eurjchem-990	381	19	,	,	PUNCT
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eurjchem-990	381	21	,	,	PUNCT
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eurjchem-990	381	23	.	.	PUNCT
eurjchem-990	382	1	[	[	X
eurjchem-990	382	2	43	43	NUM
eurjchem-990	382	3	]	]	PUNCT
eurjchem-990	382	4	.	.	PUNCT
eurjchem-990	383	1	suzuki	suzuki	PROPN
eurjchem-990	383	2	,	,	PUNCT
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eurjchem-990	383	4	;	;	PUNCT
eurjchem-990	383	5	kanatomi	kanatomi	PROPN
eurjchem-990	383	6	,	,	PUNCT
eurjchem-990	383	7	h.	h.	PROPN
eurjchem-990	383	8	;	;	PUNCT
eurjchem-990	383	9	koyama	koyama	PROPN
eurjchem-990	383	10	,	,	PUNCT
eurjchem-990	383	11	h.	h.	PROPN
eurjchem-990	383	12	;	;	PUNCT
eurjchem-990	383	13	murase	murase	PROPN
eurjchem-990	383	14	,	,	PUNCT
eurjchem-990	383	15	i.	i.	PROPN
eurjchem-990	383	16	bull	bull	PROPN
eurjchem-990	383	17	.	.	PUNCT
eurjchem-990	384	1	chem	chem	PROPN
eurjchem-990	384	2	.	.	PUNCT
eurjchem-990	385	1	soc	soc	PROPN
eurjchem-990	385	2	.	.	PUNCT
eurjchem-990	386	1	japan	japan	PROPN
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eurjchem-990	386	3	,	,	PUNCT
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eurjchem-990	386	5	,	,	PUNCT
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eurjchem-990	386	7	.	.	PUNCT
eurjchem-990	387	1	[	[	X
eurjchem-990	387	2	44	44	NUM
eurjchem-990	387	3	]	]	PUNCT
eurjchem-990	387	4	.	.	PUNCT
eurjchem-990	388	1	li	li	PROPN
eurjchem-990	388	2	,	,	PUNCT
eurjchem-990	388	3	q.	q.	PROPN
eurjchem-990	388	4	;	;	PUNCT
eurjchem-990	388	5	tang	tang	PROPN
eurjchem-990	388	6	,	,	PUNCT
eurjchem-990	388	7	h.	h.	PROPN
eurjchem-990	388	8	;	;	PUNCT
eurjchem-990	388	9	li	li	PROPN
eurjchem-990	388	10	,	,	PUNCT
eurjchem-990	388	11	y.	y.	PROPN
eurjchem-990	388	12	;	;	PUNCT
eurjchem-990	388	13	wang	wang	PROPN
eurjchem-990	388	14	,	,	PUNCT
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eurjchem-990	388	19	l.	l.	PROPN
eurjchem-990	388	20	;	;	PUNCT
eurjchem-990	388	21	xia	xia	PROPN
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eurjchem-990	388	26	.	.	PUNCT
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eurjchem-990	389	2	.	.	PUNCT
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eurjchem-990	390	2	,	,	PUNCT
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eurjchem-990	390	4	,	,	PUNCT
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eurjchem-990	390	6	.	.	PUNCT
eurjchem-990	391	1	[	[	X
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eurjchem-990	391	3	]	]	PUNCT
eurjchem-990	391	4	.	.	PUNCT
eurjchem-990	392	1	mohan	mohan	PROPN
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eurjchem-990	392	5	kumar	kumar	PROPN
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eurjchem-990	393	1	chem	chem	NOUN
eurjchem-990	393	2	.	.	PUNCT
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eurjchem-990	394	2	,	,	PUNCT
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eurjchem-990	394	4	,	,	PUNCT
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eurjchem-990	394	6	.	.	PUNCT
eurjchem-990	395	1	[	[	X
eurjchem-990	395	2	46	46	NUM
eurjchem-990	395	3	]	]	PUNCT
eurjchem-990	395	4	.	.	PUNCT
eurjchem-990	396	1	singh	singh	PROPN
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eurjchem-990	396	3	v.	v.	PROPN
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eurjchem-990	396	5	;	;	PUNCT
eurjchem-990	396	6	katiyar	katiyar	PROPN
eurjchem-990	396	7	,	,	PUNCT
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eurjchem-990	396	9	j.	j.	PROPN
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eurjchem-990	396	11	.	.	PUNCT
eurjchem-990	397	1	biochem	biochem	PROPN
eurjchem-990	397	2	.	.	PUNCT
eurjchem-990	398	1	phys	phy	NOUN
eurjchem-990	398	2	.	.	PUNCT
eurjchem-990	399	1	2008	2008	NUM
eurjchem-990	399	2	,	,	PUNCT
eurjchem-990	399	3	92	92	NUM
eurjchem-990	399	4	,	,	PUNCT
eurjchem-990	399	5	8‐14	8‐14	NUM
eurjchem-990	399	6	.	.	PUNCT
eurjchem-990	400	1	[	[	X
eurjchem-990	400	2	47	47	NUM
eurjchem-990	400	3	]	]	PUNCT
eurjchem-990	400	4	.	.	PUNCT
eurjchem-990	401	1	el‐sherif	el‐sherif	PROPN
eurjchem-990	401	2	,	,	PUNCT
eurjchem-990	401	3	a.	a.	NOUN
eurjchem-990	401	4	a.	a.	NOUN
eurjchem-990	401	5	;	;	PUNCT
eurjchem-990	401	6	eldebss	eldebs	NOUN
eurjchem-990	401	7	,	,	PUNCT
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eurjchem-990	401	11	.	.	PUNCT
eurjchem-990	402	1	acta	acta	PROPN
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eurjchem-990	402	4	,	,	PUNCT
eurjchem-990	402	5	79	79	NUM
eurjchem-990	402	6	,	,	PUNCT
eurjchem-990	402	7	1803‐	1803‐	NUM
eurjchem-990	402	8	1814	1814	NUM
eurjchem-990	402	9	.	.	PUNCT
eurjchem-990	403	1	[	[	X
eurjchem-990	403	2	48	48	NUM
eurjchem-990	403	3	]	]	PUNCT
eurjchem-990	403	4	.	.	PUNCT
eurjchem-990	404	1	niswander	niswander	PROPN
eurjchem-990	404	2	,	,	PUNCT
eurjchem-990	404	3	r.	r.	PROPN
eurjchem-990	404	4	h.	h.	PROPN
eurjchem-990	404	5	;	;	PUNCT
eurjchem-990	404	6	st	st	PROPN
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eurjchem-990	404	8	a.	a.	PROPN
eurjchem-990	404	9	k.	k.	PROPN
eurjchem-990	404	10	;	;	PUNCT
eurjchem-990	404	11	edmondson	edmondson	PROPN
eurjchem-990	404	12	,	,	PUNCT
eurjchem-990	404	13	s.	s.	PROPN
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eurjchem-990	404	15	;	;	PUNCT
eurjchem-990	404	16	taylor	taylor	PROPN
eurjchem-990	404	17	,	,	PUNCT
eurjchem-990	404	18	l.	l.	PROPN
eurjchem-990	404	19	t.	t.	PROPN
eurjchem-990	404	20	inorg	inorg	PROPN
eurjchem-990	404	21	.	.	PUNCT
eurjchem-990	405	1	chem	chem	PROPN
eurjchem-990	405	2	.	.	PUNCT
eurjchem-990	406	1	1975	1975	NUM
eurjchem-990	406	2	,	,	PUNCT
eurjchem-990	406	3	14	14	NUM
eurjchem-990	406	4	,	,	PUNCT
eurjchem-990	406	5	478‐482	478‐482	PROPN
eurjchem-990	406	6	.	.	PUNCT
eurjchem-990	407	1	[	[	X
eurjchem-990	407	2	49	49	NUM
eurjchem-990	407	3	]	]	PUNCT
eurjchem-990	407	4	.	.	PUNCT
eurjchem-990	408	1	lever	lever	PROPN
eurjchem-990	408	2	,	,	PUNCT
eurjchem-990	409	1	a.	a.	PROPN
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eurjchem-990	409	3	p.	p.	PROPN
eurjchem-990	409	4	;	;	PUNCT
eurjchem-990	410	1	lewis	lewis	PROPN
eurjchem-990	410	2	,	,	PUNCT
eurjchem-990	410	3	j.	j.	PROPN
eurjchem-990	410	4	;	;	PUNCT
eurjchem-990	410	5	nyholm	nyholm	PROPN
eurjchem-990	410	6	,	,	PUNCT
eurjchem-990	410	7	r.	r.	PROPN
eurjchem-990	410	8	s.	s.	PROPN
eurjchem-990	410	9	j.	j.	PROPN
eurjchem-990	410	10	chem	chem	PROPN
eurjchem-990	410	11	.	.	PUNCT
eurjchem-990	411	1	soc	soc	PROPN
eurjchem-990	411	2	.	.	PUNCT
eurjchem-990	412	1	1963	1963	NUM
eurjchem-990	412	2	,	,	PUNCT
eurjchem-990	412	3	2552‐2556	2552‐2556	NUM
eurjchem-990	412	4	.	.	PUNCT
eurjchem-990	413	1	[	[	X
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eurjchem-990	413	3	]	]	PUNCT
eurjchem-990	413	4	.	.	PUNCT
eurjchem-990	414	1	ballhausen	ballhausen	PROPN
eurjchem-990	414	2	,	,	PUNCT
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eurjchem-990	415	1	an	an	DET
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eurjchem-990	415	6	;	;	PUNCT
eurjchem-990	415	7	3rd	3rd	ADJ
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eurjchem-990	415	9	.	.	PUNCT
eurjchem-990	415	10	,	,	PUNCT
eurjchem-990	415	11	mcgraw	mcgraw	PROPN
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eurjchem-990	415	17	.	.	PUNCT
eurjchem-990	416	1	[	[	X
eurjchem-990	416	2	51	51	NUM
eurjchem-990	416	3	]	]	PUNCT
eurjchem-990	416	4	.	.	PUNCT
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eurjchem-990	417	2	,	,	PUNCT
eurjchem-990	417	3	b.	b.	PROPN
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eurjchem-990	417	5	;	;	PUNCT
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eurjchem-990	417	7	,	,	PUNCT
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eurjchem-990	417	12	.	.	PUNCT
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eurjchem-990	419	2	.	.	PROPN
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eurjchem-990	419	4	,	,	PUNCT
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eurjchem-990	419	6	,	,	PUNCT
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eurjchem-990	419	9	.	.	PUNCT
eurjchem-990	420	1	[	[	X
eurjchem-990	420	2	52	52	NUM
eurjchem-990	420	3	]	]	PUNCT
eurjchem-990	420	4	.	.	PUNCT
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eurjchem-990	421	2	,	,	PUNCT
eurjchem-990	421	3	b.	b.	PROPN
eurjchem-990	421	4	;	;	PUNCT
eurjchem-990	421	5	krishnan	krishnan	PROPN
eurjchem-990	421	6	,	,	PUNCT
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eurjchem-990	421	13	,	,	PUNCT
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eurjchem-990	421	15	.	.	PUNCT
eurjchem-990	422	1	[	[	X
eurjchem-990	422	2	53	53	NUM
eurjchem-990	422	3	]	]	PUNCT
eurjchem-990	422	4	.	.	PUNCT
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eurjchem-990	423	2	,	,	PUNCT
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eurjchem-990	423	5	;	;	PUNCT
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eurjchem-990	423	7	,	,	PUNCT
eurjchem-990	423	8	b.	b.	PROPN
eurjchem-990	423	9	j.	j.	PROPN
eurjchem-990	423	10	j.	j.	PROPN
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eurjchem-990	423	12	.	.	PUNCT
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eurjchem-990	424	2	.	.	PUNCT
eurjchem-990	425	1	a	a	DET
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eurjchem-990	425	3	,	,	PUNCT
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eurjchem-990	425	5	.	.	PUNCT
eurjchem-990	426	1	[	[	X
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eurjchem-990	426	3	]	]	PUNCT
eurjchem-990	426	4	.	.	PUNCT
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eurjchem-990	427	2	,	,	PUNCT
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eurjchem-990	427	5	;	;	PUNCT
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eurjchem-990	427	7	,	,	PUNCT
eurjchem-990	427	8	s.	s.	PROPN
eurjchem-990	427	9	;	;	PUNCT
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eurjchem-990	427	11	,	,	PUNCT
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eurjchem-990	427	13	;	;	PUNCT
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eurjchem-990	427	33	l.	l.	PROPN
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eurjchem-990	428	1	chim	chim	PROPN
eurjchem-990	428	2	.	.	PUNCT
eurjchem-990	429	1	acta	acta	PROPN
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eurjchem-990	429	3	,	,	PUNCT
eurjchem-990	429	4	286	286	NUM
eurjchem-990	429	5	,	,	PUNCT
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eurjchem-990	429	7	.	.	PUNCT
eurjchem-990	430	1	[	[	X
eurjchem-990	430	2	55	55	NUM
eurjchem-990	430	3	]	]	PUNCT
eurjchem-990	430	4	.	.	PUNCT
eurjchem-990	431	1	jayabalakrishnan	jayabalakrishnan	PROPN
eurjchem-990	431	2	,	,	PUNCT
eurjchem-990	431	3	c.	c.	PROPN
eurjchem-990	431	4	;	;	PUNCT
eurjchem-990	431	5	natarjan	natarjan	PROPN
eurjchem-990	431	6	,	,	PUNCT
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eurjchem-990	431	8	synth	synth	PROPN
eurjchem-990	431	9	.	.	PUNCT
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eurjchem-990	432	2	.	.	PUNCT
eurjchem-990	433	1	inorg	inorg	PROPN
eurjchem-990	433	2	.	.	PUNCT
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eurjchem-990	434	2	.	.	PUNCT
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eurjchem-990	435	2	.	.	PUNCT
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eurjchem-990	435	4	.	.	PUNCT
eurjchem-990	436	1	2001	2001	NUM
eurjchem-990	436	2	,	,	PUNCT
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eurjchem-990	436	4	,	,	PUNCT
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eurjchem-990	436	6	.	.	PUNCT
eurjchem-990	437	1	[	[	X
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eurjchem-990	437	3	]	]	SYM
eurjchem-990	437	4	.	.	PUNCT
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eurjchem-990	438	2	,	,	PUNCT
eurjchem-990	438	3	t.	t.	PROPN
eurjchem-990	438	4	;	;	PUNCT
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eurjchem-990	438	6	,	,	PUNCT
eurjchem-990	438	7	h.	h.	PROPN
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eurjchem-990	438	10	;	;	PUNCT
eurjchem-990	438	11	bhowon	bhowon	PROPN
eurjchem-990	438	12	,	,	PUNCT
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eurjchem-990	438	17	,	,	PUNCT
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eurjchem-990	438	21	,	,	PUNCT
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eurjchem-990	438	24	.	.	PUNCT
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eurjchem-990	439	2	.	.	PUNCT
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eurjchem-990	440	2	.	.	PUNCT
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eurjchem-990	441	2	.	.	PUNCT
eurjchem-990	442	1	org	org	NOUN
eurjchem-990	442	2	.	.	PUNCT
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eurjchem-990	442	4	.	.	PUNCT
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eurjchem-990	443	2	,	,	PUNCT
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eurjchem-990	443	4	,	,	PUNCT
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eurjchem-990	443	6	.	.	PUNCT
eurjchem-990	444	1	[	[	X
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eurjchem-990	444	3	]	]	PUNCT
eurjchem-990	444	4	.	.	PUNCT
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eurjchem-990	445	2	,	,	PUNCT
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eurjchem-990	445	4	;	;	PUNCT
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eurjchem-990	445	6	,	,	PUNCT
eurjchem-990	445	7	p.	p.	PROPN
eurjchem-990	445	8	;	;	PUNCT
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eurjchem-990	445	10	,	,	PUNCT
eurjchem-990	445	11	k.	k.	PROPN
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eurjchem-990	445	13	.	.	PUNCT
eurjchem-990	446	1	met	meet	VERB
eurjchem-990	446	2	.	.	PUNCT
eurjchem-990	447	1	chem	chem	NOUN
eurjchem-990	447	2	.	.	PUNCT
eurjchem-990	448	1	2001	2001	NUM
eurjchem-990	448	2	,	,	PUNCT
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eurjchem-990	448	4	,	,	PUNCT
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eurjchem-990	448	6	.	.	PUNCT
eurjchem-990	449	1	[	[	X
eurjchem-990	449	2	58	58	NUM
eurjchem-990	449	3	]	]	PUNCT
eurjchem-990	449	4	.	.	PUNCT
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eurjchem-990	449	10	.	.	PUNCT
eurjchem-990	450	1	chim	chim	PROPN
eurjchem-990	450	2	.	.	PUNCT
eurjchem-990	451	1	acta	acta	PROPN
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eurjchem-990	451	3	,	,	PUNCT
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eurjchem-990	451	5	,	,	PUNCT
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eurjchem-990	451	7	.	.	PUNCT
eurjchem-990	452	1	[	[	X
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eurjchem-990	452	3	]	]	PUNCT
eurjchem-990	452	4	.	.	PUNCT
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eurjchem-990	453	5	;	;	PUNCT
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eurjchem-990	453	7	,	,	PUNCT
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eurjchem-990	454	4	,	,	PUNCT
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eurjchem-990	454	8	.	.	PUNCT
eurjchem-990	455	1	[	[	X
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eurjchem-990	455	3	]	]	PUNCT
eurjchem-990	455	4	.	.	PUNCT
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eurjchem-990	455	6	,	,	PUNCT
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eurjchem-990	456	2	.	.	PUNCT
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eurjchem-990	457	2	,	,	PUNCT
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eurjchem-990	457	4	)	)	PUNCT
eurjchem-990	457	5	,	,	PUNCT
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eurjchem-990	457	7	.	.	PUNCT
eurjchem-990	458	1	[	[	X
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eurjchem-990	458	8	;	;	PUNCT
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eurjchem-990	458	10	,	,	PUNCT
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eurjchem-990	458	14	,	,	PUNCT
eurjchem-990	458	15	s.	s.	PROPN
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eurjchem-990	459	4	,	,	PUNCT
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eurjchem-990	459	6	)	)	PUNCT
eurjchem-990	459	7	,	,	PUNCT
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eurjchem-990	460	3	]	]	PUNCT
eurjchem-990	460	4	.	.	PUNCT
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eurjchem-990	461	1	inorg	inorg	PROPN
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eurjchem-990	462	2	.	.	PUNCT
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eurjchem-990	463	2	.	.	PUNCT
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eurjchem-990	463	4	.	.	PUNCT
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eurjchem-990	464	2	,	,	PUNCT
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eurjchem-990	464	4	,	,	PUNCT
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eurjchem-990	464	6	.	.	PUNCT
eurjchem-990	465	1	[	[	X
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eurjchem-990	465	3	]	]	PUNCT
eurjchem-990	465	4	.	.	PUNCT
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eurjchem-990	467	4	,	,	PUNCT
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eurjchem-990	467	8	.	.	PUNCT
eurjchem-990	468	1	[	[	X
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eurjchem-990	468	4	.	.	PUNCT
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eurjchem-990	471	2	,	,	PUNCT
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eurjchem-990	472	3	]	]	PUNCT
eurjchem-990	472	4	.	.	PUNCT
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eurjchem-990	473	2	,	,	PUNCT
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eurjchem-990	473	16	.	.	PUNCT
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eurjchem-990	475	2	.	.	PUNCT
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eurjchem-990	476	6	)	)	PUNCT
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eurjchem-990	476	9	.	.	PUNCT
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eurjchem-990	477	3	]	]	PUNCT
eurjchem-990	477	4	.	.	PUNCT
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eurjchem-990	479	8	.	.	PUNCT
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eurjchem-990	480	3	]	]	PUNCT
eurjchem-990	480	4	.	.	PUNCT
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eurjchem-990	482	3	.	.	PUNCT
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eurjchem-990	483	2	,	,	PUNCT
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eurjchem-990	483	4	)	)	PUNCT
eurjchem-990	483	5	,	,	PUNCT
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eurjchem-990	483	7	.	.	PUNCT
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eurjchem-990	484	3	]	]	PUNCT
eurjchem-990	484	4	.	.	PUNCT
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eurjchem-990	485	2	,	,	PUNCT
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eurjchem-990	485	6	,	,	PUNCT
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eurjchem-990	485	8	;	;	PUNCT
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eurjchem-990	485	10	,	,	PUNCT
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eurjchem-990	485	13	.	.	PUNCT
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eurjchem-990	487	2	,	,	PUNCT
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eurjchem-990	487	4	)	)	PUNCT
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eurjchem-990	487	7	.	.	PUNCT
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eurjchem-990	488	3	]	]	PUNCT
eurjchem-990	488	4	.	.	PUNCT
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eurjchem-990	490	3	]	]	PUNCT
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eurjchem-990	491	1	a	a	DET
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eurjchem-990	491	3	,	,	PUNCT
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eurjchem-990	491	5	,	,	PUNCT
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eurjchem-990	491	8	.	.	PUNCT
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eurjchem-990	494	4	,	,	PUNCT
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eurjchem-990	494	6	,	,	PUNCT
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eurjchem-990	494	8	.	.	PUNCT
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eurjchem-990	495	4	.	.	PUNCT
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eurjchem-990	498	2	73	73	NUM
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eurjchem-990	498	4	.	.	PUNCT
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eurjchem-990	499	2	,	,	PUNCT
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eurjchem-990	499	10	,	,	PUNCT
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eurjchem-990	502	8	;	;	PUNCT
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eurjchem-990	502	10	,	,	PUNCT
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eurjchem-990	503	2	,	,	PUNCT
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eurjchem-990	503	4	,	,	PUNCT
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eurjchem-990	504	3	]	]	PUNCT
eurjchem-990	504	4	.	.	PUNCT
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eurjchem-990	505	4	;	;	PUNCT
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eurjchem-990	506	3	,	,	PUNCT
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eurjchem-990	506	5	,	,	PUNCT
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eurjchem-990	507	4	.	.	PUNCT
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eurjchem-990	510	2	,	,	PUNCT
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eurjchem-990	510	4	,	,	PUNCT
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