Microsoft Word - numero_52_art_10_2710 A. Laureys et alii, Frattura ed Integrità Strutturale, 52 (2020) 113-127; DOI: 10.3221/IGF-ESIS.52.10 113 Focussed on the 1st Benelux Network Meeting and Workshop on Damage and Fracture Mechanics Initiation of hydrogen induced cracks at secondary phase particles A. Laureys, M. Pinson, L. Claeys, T. De Seranno, T. Depover, K. Verbeken Ghent University, Department of Materials, Textiles and Chemical Engineering, Technologiepark 46, 9052 Zwijnaarde, Belgium aurelie.laureys@ugent.be, margot.pinson@ugent.be, lisa.claeys@ugent.be, tim.deseranno@ugent.be tom.depover@ugent.be (https://orcid.org/0000-0002-8856-1122) kim.verbeken@ugent.be (https://orcid.org/0000-0002-5190-016X) ABSTRACT. The goal of this work is to propose a general mechanism for hydrogen induced crack initiation in steels based on a microstructural study of multiple steel grades. Four types of steels with strongly varying microstructures are studied for this purpose, i.e. ultra low carbon (ULC) steel, TRIP (transformation induced plasticity) steel, Fe-C-Ti generic alloy, and pressure vessel steel. A strong dependency of the initiation of hydrogen induced cracks on the microstructural features in the materials is observed. By use of SEM-EBSD characterization, initiation is found to always occur at the hard secondary phase particles in the materials. KEYWORDS. Blisters; Hydrogen induced cracking; particles; Secondary phase; Scanning electron microscopy. Citation: Laureys, L., Pinson, M., Claeys, L., De Seranno, T., Depover, T., Verbeken, K., Initiation of hydrogen induced cracks at secondary phase particles, Frattura ed Integrità Strutturale, 52 (2020) 113-127. Received: 18.12.2019 Accepted: 26.01.2020 Published: 01.04.2020 Copyright: © 2020 This is an open access article under the terms of the CC-BY 4.0, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited. INTRODUCTION xperimental electrochemical charging of steels with hydrogen mimics, on the one hand, well hydrogen generation and entry in the material from sources such as corrosion or applications such as arc welding [1]. Small amounts of hydrogen in a metal in combination with external or residual stresses can lead to hydrogen embrittlement (HE) or hydrogen assisted cracking (HAC), which results in subcritical failure of the materials [2, 3, 4]. On the other hand, intensive electrochemical charging can induce both surface and internal damage in a material [5]. The hydrogen charging procedure can consequently be applied to simulate situations where hydrogen induced cracking (HIC) takes place. Hydrogen induced internal cracking and blistering can occur in metals subjected to high fugacity hydrogen environments, such as high pressure hydrogen gas environments or under extreme cathodic charging conditions, even without the application of an external load or residual stress, though such stresses can contribute to HIC [5, 6]. HIC occurs, for instance, in oil and gas sour service pipelines where hydrogen ingress into steel from H2S occurs [7]. Also hydrogen flakes as found in reactor pressure vessels [8] are an example of HIC and could be artificially reproduced by intensive electrochemical hydrogen charging [9]. HIC occurs when the hydrogen concentration in the steel matrix exceeds a threshold hydrogen concentration. The threshold hydrogen concentration might be considered as a parameter unique to a given material and strongly depends on the type, shape and amount of inclusions and segregation in the matrix [10, 11, 12, 13]. The internal pressure theory [14, 15, 16] explains the phenomenon of HIC in high fugacity hydrogen environments. The theory states that HIC results from the formation of high pressure hydrogen gas bubbles in internal voids and microcracks. When an alloy is exposed to a hydrogen E https://youtu.be/kKaDSKOgCfU A. Laureys et alii, Frattura ed Integrità Strutturale, 52 (2020) 113-127; DOI: 10.3221/IGF-ESIS.52.10 114 containing environment, atomic hydrogen can be absorbed in the metal and hence diffuses inside the metal. Its movement can be interrupted or hindered by microstructural discontinuities, such as voids, dislocations, second phase particles (such as MnS [17] inclusions), grain boundaries, and microcracks, which act as trap sites [18]. At such sites, atomic hydrogen can recombine to form molecular gaseous hydrogen, which is incapable of further migration and locally creates a high internal pressure [14, 19]. A large amount of hydrogen can hence diffuse with time into the traps resulting in a continuously increasing hydrogen pressure. This process is active until an equilibrium in the chemical potential is achieved between the molecular hydrogen in the trap and the hydrogen in the lattice [20]. The result is the formation of overpressurized gas-filled cavities, which cause plastic deformation of the surrounding lattice and promote crack formation. If the internal pressure rises to levels which exceed the tensile strength, crack propagation occurs, even in the absence of externally applied loads. Additionally, lattice hydrogen could facilitate crack propagation at stresses lower than the actual tensile stress of the material by several mechanisms, such as hydrogen-enhanced decohesion (HEDE) [21], hydrogen-enhanced localized plasticity (HELP) [22] or hydrogen-enhanced vacancy formation [23]. The internal pressure is temporarily relieved due to crack propagation, which therefore occurs discontinuously. As proof, some wavy lines perpendicular to the crack propagating directions were observed on the fracture surface of a blister [24, 25]. In a next stage microcracks propagate further and connect, creating a series of stepwise cracks through the material [26]. When the phenomenon takes place close to the sample surface, it is referred to as blistering. The high pressure then pushes material upwards, resulting in a surface blister [5]. Different blister initiation sites and initiation mechanisms have been proposed in literature for alloys charged in a high fugacity hydrogen environment. Numerous studies [5, 6, 24, 25, 27, 28] revealed that non-metallic inclusions and second phase particles, such as MnS and Al2O3, in steels act as major nucleation sites for blisters. Such inclusions typically serve as irreversible trap sites with high binding energies for hydrogen [29, 30], where hydrogen can accumulate. The non-metallic inclusions in steel are usually formed during the steel manufacturing, deoxidation and desulfurization process. Cracking occurs if locally a critical hydrogen concentration necessary for crack initiation is reached [31, 32]. Huang et al. [33] stated that the more hydrogen entrapment occurs in the steel, the more the steel is susceptible to HIC. Elboujdaini and Revie found that a linear relationship exists between the threshold hydrogen concentration in a material and the quantity of inclusions in the steel. Domizzi et al. [34] studied different grades of pipeline steel with various inclusion contents and degrees of microstructural banding through thickness and concluded that the presence of hard bands is more critical than inclusions for HIC. Multiple authors [1, 35, 36] state that the presence of a second phase is not a prerequisite for blister formation and claim that vacancy-hydrogen interaction plays a role in the initiation process as well. Garofalo et al. [37] stated that the hydrogen induced propagation of internal cracks in steel is promoted by hydrogen gas in voids or microcracks which may be formed by plastic deformation or are present as porosities from the casting process. Griesche et al. [1] visualized small pores with diameters of ~1 µm all over the hydrogen induced crack surfaces. These pores were located along grain boundaries, which are strong hydrogen traps. In summary, crack nucleation during hydrogen charging has been related to a localized concentration and subsequent recombination of hydrogen at suitable heterogeneities such as grain boundaries, second phase particles, microvoids and tangled dislocations [38]. This investigation gives an overview of previous work [6, 9, 39, 40] in order to bring together results obtained on different materials, compare the initiation mechanism for hydrogen induced cracking and as such give new insights on an important topic. The study compares the blistering behavior of four different types of materials, i.e. ultra low carbon (ULC) steel [6], TRIP (transformation induced plasticity)-assisted steel [40], generic Fe-C-Ti alloy [39], and pressure vessel steels [9]. These materials exhibit strongly varying microstructural features, such as different type of inclusions, precipitates and phases. All these microstructural components interact differently with hydrogen and exhibit a specific critical hydrogen concentration [6]. The aim of this work is to describe a general mechanism for hydrogen induced crack initiation in steels. It is essential to understand the microstructure dependence of HIC to help guide future microstructural design and alloy applications. The materials were cathodically charged as such that damage formed and cross sectional analysis allowed to estimate the initiating internal damage. A thorough microstructural characterization of blisters and internal cracks was performed by optical microscopy, scanning electron microscopy (SEM) and electron backscatter diffraction (EBSD). EXPERIMENTAL PROCEDURE Materials he hydrogen induced cracking behavior of five different steel alloys was compared during the current investigation, i.e. ultra-low carbon (ULC) steel, TRIP (transformation induced plasticity)-assisted steel, generic Fe-C-Ti alloy and two types of pressure vessel steels. The chemical compositions of these materials are given in Tab. 1 and 2. T A. Laureys et alii, Frattura ed Integrità Strutturale, 52 (2020) 113-127; DOI: 10.3221/IGF-ESIS.52.10 115 Wt% S C N P Mn Ti Al Si Fe ULC steel 38 ppm 214 ppm 88 ppm 73 ppm 0.25 0.002 0.047 Balance TRIP steel 0.17 0.04-0.1 1.60 1-2 0.40 Balance Fe-C-Ti steel 0.1 50 ppm 0.38 0.03 Balance Table 1: Chemical composition of ULC steel, TRIP-assisted steel and Fe-C-Ti steel. Wt% C Si Mn P S Cr ≤0.25 0.10-0.30 1.15-1.55 ≤0.015 ≤0.012 ≤0.25 Wt% Cu Mo Ni V Al Fe ≤0.20 0.45-0.55 0.50-0.80 ≤0.03 ≤0.04 Balance Table 2: Chemical composition range specifications for the two pressure vessel alloys (wt%). Ultra-low carbon steel was used as a material of study in order to avoid the effect of complex microstructural characteristics on blister/internal crack characterization. A cold deformed ULC steel is studied in the current study, since controllable introduction of blisters is possible in this material [6]. The corresponding microstructure is shown in Fig. 1. This material consists of deformed ferrite grains and a small number of Al2O3 inclusions. Only a few hydrogen trapping sites are present in this material, i.e. grain boundaries, dislocations, vacancies, microvoids and additionally, some inclusions. Figure 1: Dark field optical microscopy image of cold deformed ULC steel. Reprinted with permission from Ref. [6]. Figure 2: SEM image of a) TRIP assisted steel (RA: retained austenite, M: martensite, F: ferrite, B: bainite) and b) original AlN inclusions/voids in the steel. Reprinted with permission from Ref. [40]. Contrary to ULC steel, TRIP-assisted steel has a complex multiphase microstructure with a ferritic matrix and a dispersion of multiphase grains of bainite, retained austenite and some martensiet [41] (Fig. 2). The ferritic grains appear as big, flat A. Laureys et alii, Frattura ed Integrità Strutturale, 52 (2020) 113-127; DOI: 10.3221/IGF-ESIS.52.10 116 grains. The retained austenite grains remain unetched so they exhibit a smooth appearance, while martensite exhibits a rough appearance. Finally, bainite can be detected by its lamellar structure containing bainitic ferrite and retained austenite [42]. Additionally, some large voids and inclusions were found in the material as well, as shown in Fig. 2b. The inclusions were characterized as AlN by energy dispersive X-ray analysis. A laboratory cast, hot and cold rolled ferritic Fe-C-Ti material was also investigated. The generic lab-cast alloy possesses a well-specified chemical composition and was submitted to a well-defined thermal treatment. Carbides/carbonitrides in a coarse grained recrystallized ferritic matrix were as such obtained (Fig. 3)., which allows to study the effect of precipitates without the additional trapping effects of phase boundaries, such as martensitic lath boundaries, or the presence of an increased dislocation density. Large incoherent carbonitrides (2-5 µm), medium-sized carbonitrides (Ti(C,N)) (100-700 nm) and small carbides (2-24 nm) were found in the material (Fig. 3 and 4) [39]. Figure 3: Bright field optical microscopy image of the microstructure of a generic Fe-C-Ti alloy. Reprinted with permission from Ref. [39] . Figure 4: Bright field STEM images of a) small TiC, b) larger spherical Ti(C,N), and c) square Ti(C,N) (indicated with arrows). Reprinted with permission from Ref. [39]. Two industrial pressure vessel steels were studied as well (material A and B). The essential difference in composition for these two alloys is the sulphur content, which was 0.003 wt% for material A and 0.008 wt% for material B. These high hardenability steels were demonstrated to be severely prone to hydrogen induced cracking [43]. These materials exhibit large segregation zones, both macro- and micro-segregation, since they originate from large forgings. Such segregation zones are formed during the casting process and are further deformed by the subsequent manufacturing processes, such as forging [8]. Due to the long time required for solidification, large ingots tend to have a larger degree of segregation compared to smaller ingots. Internal stresses are created as a result of cooling, applied strain and phase transformation. Due to the enrichment in alloying elements in these regions, a significant amount of MnS is present. The shape and the location of the macro- and micro-segregation zones differed for both materials due to a different manufacturing history, i.e. hollow ingot casting for material A and solid ingot casting followed by a piercing operation for material B. The microstructure of material A and B was nevertheless very similar and the banded structure is visualized in Fig. 5, where the darker regions are the micro-segregation regions, i.e. ghost lines. The segregation areas solidified last after casting and are, therefore, enriched with A. Laureys et alii, Frattura ed Integrità Strutturale, 52 (2020) 113-127; DOI: 10.3221/IGF-ESIS.52.10 117 solutes. Non-segregated regions exhibited a tempered bainitic microstructure with little ferrite, while segregation zones consist of tempered martensite and bainite originating from the last solidified regions. In the segregation zones inclusions were found and identified as manganese sulfides (MnS) (Fig. 6). Comparing both materials, it is found that material A exhibited a lower number density of inclusions than material B. This can be correlated to the lower sulfur content of material A compared to material B, which does not influence the particle size, but does influence the number of particles [44]. Additionally, the inclusions were also more strongly elongated in material B compared to material A. The corresponding elongation ratios were 3.68 and 2.46, respectively. The average prior austenite grain sizes were 20.0 µm and 15.4 µm for material A and B, respectively. Due to the strongly heterogeneous distribution of the micro-segregation areas in the materials, the precise quantification of the phase fractions could not be characterized in a reliable manner. After a qualitative study, it was clear that material A exhibited more tempered martensite in the segregated zones than material B [9]. Electrochemical hydrogen charging Oval shaped samples with a major axis of 20 mm and a minor axis of 15 mm were machined from the plate materials (for TRIP-assisted steels (0.65 mm thickness), ULC steel (1.2 mm thickness) and Fe-C-Ti steel (1 mm thickness). The major axis of the samples coincides with the rolling direction of the plates. For the pressure vessel steels, circular (20 mm diameter) samples were machined from the macro-segregated areas in a large forging, which contain local micro-segregated zones, i.e. ghost lines. Subsequently, the samples were ground to a final thickness of 1.1 mm. The samples’ surfaces and edges were ground prior to hydrogen charging to remove possible oxides. The removal of surface oxides is required, since they exhibit an inhibiting effect on hydrogen transport to the metal surface and as such possibly affect the nucleation and propagation of hydrogen induced cracks [45]. The samples were cathodically charged with hydrogen in a polycarbonate cell containing 0.5 M H2SO4 and 1 g/l thiourea electrolyte. Thiourea was added to the electrolyte in order to promote hydrogen atom absorption into the metal rather than hydrogen recombination to its molecular form at the surface. The sample was connected as a cathode and positioned symmetrically in between two platinum anodes. Samples were charged at room temperature using a charging current density of 10 mA/cm². The charging times varied for different materials (ranging from 1 to 4 days), since the materials each had a different sensitivity to hydrogen induced damage and optimal charging times were selected to induce hydrogen cracks into the samples. Each specific charging condition was applied multiple times to confirm the repeatability of the crack characteristics. Hydrogen induced crack investigation Surface imaging by optical microscopy allowed the detection of blisters on the sample surfaces. Cross sections along the transverse direction plane were analyzed in order to obtain information on the internal cracks in the hydrogen charged samples. These sections were polished using standard metallographic techniques and subsequently etched with Nital 2% for 10s. A first preliminary investigation of the internal microstructural damage was performed by optical microscopy, followed by a SEM study. Subsequently, the most interesting features were investigated with EBSD using a scan step size ranging from 0.05 and 0.1 µm on a hexagonal grid. For the EBSD investigation, an additional polishing step with colloidal silica was required. In the current study two OIM data processing maps, namely phase map and kernel average image quality (KAIQ) were implemented and analyzed. Kernel average image quality was used to make a clear distinction between martensite and cracks in TRIP-assisted steels, which is complicated because they both exhibit a confidence index (CI) lower than 0.1. RESULTS AND DISCUSSION he five materials were charged at 10 mA/cm² for certain charging times (Fig. 7), so to induce a considerable amount of hydrogen induced damage in the materials. As such, cross sections would allow to study in depth the mechanisms of crack initiation. Since each material had a different sensitivity to hydrogen induced damage, charging times varied. The variable sensitivity is caused by the different microstructures of the materials, which exhibit varying hydrogen trapping characteristics. Huang et al. [46] and Dong et al. [47] actually revealed that the HIC susceptibility depends on the hydrogen entrapment in steel. The surface distribution of the blisters will be discussed in more detail for each material separately, together with cross section analysis in the next section, so that the distribution can be related to the microstructure of the material. T A. Laureys et alii, Frattura ed Integrità Strutturale, 52 (2020) 113-127; DOI: 10.3221/IGF-ESIS.52.10 118 Figure 5: a) banded structure, b) non-segregated region, and c) micro-segregated region typically observed in material A. Material B showed similar microstructure. Reprinted with permission from Ref. [9]. A. Laureys et alii, Frattura ed Integrità Strutturale, 52 (2020) 113-127; DOI: 10.3221/IGF-ESIS.52.10 119 Figure 6: MnS inclusions in a segregation region in material A and B. The samples were polished to better distinguish the MnS inclusions. Reprinted with permission from Ref. [9]. Figure 7: a) Deformed ULC steel hydrogen charged at 10 mA/cm² for 2 days; b) TRIP-assisted steel hydrogen charged at 10 mA/cm² for 3 days, c) Fe-C-Ti alloy hydrogen charged at 10 mA/cm² for 1 day, d) and f) pressure vessel steel material A and B, respectively, charged with hydrogen at 10 mA/cm² for 4 days. Reprinted with permission from Ref. [6, 39]. Hydrogen induced crack initiation was studied for the different materials by analyzing cross sections of hydrogen charged materials under the conditions of Fig. 7. A strong dependence of hydrogen induced cracking to the microstructure was found. The initiation will be discussed for each separate material, followed by a comparative study. In order to further characterize the role of microstructural features on blister formation, cross sections were studied by a combination of SEM and EBSD. ULC steel Crack initiation in cold deformed ULC steel was often observed at inclusions (Fig. 8). More specifically, interface debonding led to the initiation of cracks. The particles were identified by energy dispersive X-ray spectroscopy (EDX) as alumina particles, which originate from the typically performed desoxidation step in the steel production process. Cracks were often observed with large alumina particles along them (Fig. 8b). A. Laureys et alii, Frattura ed Integrità Strutturale, 52 (2020) 113-127; DOI: 10.3221/IGF-ESIS.52.10 120 Figure 8: a) Crack initiation at alumina particle and b) particles along cracks in deformed ULC steel. Reprinted with permission from Ref. [6]. Tiegel et al. [25] proposed a mechanism which could explain the observed phenomenon. They stated that hydrogen accumulation occurs at the incoherent particle interfaces, causing interface failure. Subsequently, vacancy stabilization at the interfaces occurs due to the increased hydrogen concentration, as such providing space around the inclusions for hydrogen atoms to form molecular hydrogen. The resulting internal pressure then drives the material to form a crack. The proposed mechanism is illustrated in Fig. 9, which is similar to what was observed in the samples (Fig. 8a). Moreover, Jin et al. [11] and Kim et al. [48] stated that relatively big voids exist between an inclusion and the steel substrate, which acts as sinks for the hydrogen atoms, resulting in high local stress concentration due to formation of hydrogen molecules. Consequently, interfacial decohesion is stimulated with increasing hydrogen segregation. Figure 9: Sketch of proposed mechanism for crack initiation by Tiegel et al. [25]. Reprinted with permission from Ref. [6]. Fig. 7 shows that deformed ULC steel is very sensitive to crack initiation, since numerous small blisters are found on the surface of hydrogen charged samples, even though only a limited amount of inclusions are present in the material. In cold deformed material, inclusions will exhibit an increased concentration of dislocation tangles at the interface with the matrix due to impingement. A resulting local increase in the hydrogen concentration as such exists at the interface, leading to enhanced crack initiation. Additionally, in cold deformed material a larger number of vacancies is present, which will equally accelerate the abovementioned mechanism. All the blisters observed on the surface cannot be initiated at inclusions, since the number of inclusions in the material is not that high. Initiating cracks were also found on slip planes or grain boundaries, not in the immediate vicinity of inclusions (Fig. 10). In a strongly deformed material such as the ULC steel studied here, dislocation tangles could also act as hydrogen induced crack initiation locations. More details concerning the blistering behavior of deformed ULD steel can be found in [6]. A. Laureys et alii, Frattura ed Integrità Strutturale, 52 (2020) 113-127; DOI: 10.3221/IGF-ESIS.52.10 121 Figure 10: Early stage of cracking in hydrogen charged cold deformed ULC steel (5 mA/cm²- 2 days). a) SEM image, b) IQ map with HAGBs (>15°) in green and LAGBs (low angle grain boundaries) (5-15 °) in red. Reprinted with permission from Ref. [6]. Figure 11: TRIP-assisted steel hydrogen charged for 1 day at 10 mA/cm²: a) SEM image and b) Kernel average image quality (KAIQ) overlapped with an IQ map of the investigated zone (Blue: cavity (610> /ColorImageDict << /QFactor 0.15 /HSamples [1 1 1 1] /VSamples [1 1 1 1] >> /JPEG2000ColorACSImageDict << /TileWidth 256 /TileHeight 256 /Quality 30 >> /JPEG2000ColorImageDict << /TileWidth 256 /TileHeight 256 /Quality 30 >> /AntiAliasGrayImages false /CropGrayImages true /GrayImageMinResolution 300 /GrayImageMinResolutionPolicy /OK /DownsampleGrayImages true /GrayImageDownsampleType /Bicubic /GrayImageResolution 300 /GrayImageDepth -1 /GrayImageMinDownsampleDepth 2 /GrayImageDownsampleThreshold 1.50000 /EncodeGrayImages true /GrayImageFilter /DCTEncode /AutoFilterGrayImages true /GrayImageAutoFilterStrategy /JPEG /GrayACSImageDict << /QFactor 0.15 /HSamples [1 1 1 1] /VSamples [1 1 1 1] >> /GrayImageDict << /QFactor 0.15 /HSamples [1 1 1 1] /VSamples [1 1 1 1] >> /JPEG2000GrayACSImageDict << /TileWidth 256 /TileHeight 256 /Quality 30 >> /JPEG2000GrayImageDict << /TileWidth 256 /TileHeight 256 /Quality 30 >> /AntiAliasMonoImages false /CropMonoImages true /MonoImageMinResolution 1200 /MonoImageMinResolutionPolicy /OK /DownsampleMonoImages true /MonoImageDownsampleType /Bicubic /MonoImageResolution 1200 /MonoImageDepth -1 /MonoImageDownsampleThreshold 1.50000 /EncodeMonoImages true /MonoImageFilter /CCITTFaxEncode /MonoImageDict << /K -1 >> /AllowPSXObjects false /CheckCompliance [ /None ] /PDFX1aCheck false /PDFX3Check false /PDFXCompliantPDFOnly false /PDFXNoTrimBoxError true /PDFXTrimBoxToMediaBoxOffset [ 0.00000 0.00000 0.00000 0.00000 ] /PDFXSetBleedBoxToMediaBox true /PDFXBleedBoxToTrimBoxOffset [ 0.00000 0.00000 0.00000 0.00000 ] /PDFXOutputIntentProfile () /PDFXOutputConditionIdentifier () /PDFXOutputCondition () /PDFXRegistryName () /PDFXTrapped /False /CreateJDFFile false /Description << /ARA /BGR /CHS /CHT /CZE /DAN /DEU /ESP /ETI /FRA /GRE /HEB /HRV (Za stvaranje Adobe PDF dokumenata najpogodnijih za visokokvalitetni ispis prije tiskanja koristite ove postavke. Stvoreni PDF dokumenti mogu se otvoriti Acrobat i Adobe Reader 5.0 i kasnijim verzijama.) /HUN /ITA /JPN /KOR /LTH /LVI /NLD (Gebruik deze instellingen om Adobe PDF-documenten te maken die zijn geoptimaliseerd voor prepress-afdrukken van hoge kwaliteit. De gemaakte PDF-documenten kunnen worden geopend met Acrobat en Adobe Reader 5.0 en hoger.) /NOR /POL /PTB /RUM /RUS /SKY /SLV /SUO /SVE /TUR /UKR /ENU (Use these settings to create Adobe PDF documents best suited for high-quality prepress printing. Created PDF documents can be opened with Acrobat and Adobe Reader 5.0 and later.) >> /Namespace [ (Adobe) (Common) (1.0) ] /OtherNamespaces [ << /AsReaderSpreads false /CropImagesToFrames true /ErrorControl /WarnAndContinue /FlattenerIgnoreSpreadOverrides false /IncludeGuidesGrids false /IncludeNonPrinting false /IncludeSlug false /Namespace [ (Adobe) (InDesign) (4.0) ] /OmitPlacedBitmaps false /OmitPlacedEPS false /OmitPlacedPDF false /SimulateOverprint /Legacy >> << /AddBleedMarks false /AddColorBars false /AddCropMarks false /AddPageInfo false /AddRegMarks false /ConvertColors /ConvertToCMYK /DestinationProfileName () /DestinationProfileSelector /DocumentCMYK /Downsample16BitImages true /FlattenerPreset << /PresetSelector /MediumResolution >> /FormElements false /GenerateStructure false /IncludeBookmarks false /IncludeHyperlinks false /IncludeInteractive false /IncludeLayers false /IncludeProfiles false /MultimediaHandling /UseObjectSettings /Namespace [ (Adobe) (CreativeSuite) (2.0) ] /PDFXOutputIntentProfileSelector /DocumentCMYK /PreserveEditing true /UntaggedCMYKHandling /LeaveUntagged /UntaggedRGBHandling /UseDocumentProfile /UseDocumentBleed false >> ] >> setdistillerparams << /HWResolution [2400 2400] /PageSize [612.000 792.000] >> setpagedevice