I GEOL. CROAT . I 50/1 I 33 - 48 I J 9 Figs. I I ZAGREB 1997 The Development of the Eocene Platform Carbonates from Wells in the Middle Adriatic Off-Shore Area, Croatia Vlasta TAR! KOVACIC Key WOI-ds: Eocene, Platform carbonates, Wirelinc logs, Adriatic o IT-shore, Croatia. Abstract [n the Middle Adriatic deep off-shore wells th e following sedi­ mentary f:lCi cs ex isl: fenestral :H1d Charophyte limestone facies (X): facies of foraminiferal wackestone-packstone. ostracod marls and fine grained breccia cong lomerate (A): facies of foraminiferal packstonc­ grai nstone (B) and milio lidal mudstone-wackestone (C): fac ies of porous limestone?, grai nstone? (V): facies of fossi liferous mudstone­ p;lckstonc (D); alga l bOtlnd stonc/bindstonc and wackestone fac ies (E): facies o f the fOraminiferal mudstone-packstone (F); NlI/nll/IlIiTeS­ Di.H·Ot:ydillu flo;ttstone-pacbtone and g rainstone-r ud stone faci es (G). The sedi ment s were deposited close to the carbonat e platform marg in. Beds of facies X hav e an uncertain str- ~ AC ~ 90msec/ft o ~ 120 - ~ ~. \ ' / I , E - / ~ \ ~ o i? o ~ LITHOLOGY \ 8. f----- 7. I-- 8. 7. I-- z .. >- w >- 6. ~ I-- 5. 3. 1. z .. !!i " u o· o Q. Legend: Nummutitids Alveotinids v=::J Discocyclinids c::=:') Miliolids L1 Conical foraminifers &- Benthic foraminifers (y Planktonic torams J Algae @ Corals P Bryozoans 35 Echmids ~'-...L? Shells' debris Rudis-ts Charophyta Microcodium Ostracods Dessication cracks Caliche Birds eyes Ooids I "-.;'110 I 1 '--hi Fig. 2 Scqucncc of Palaeogene carbonates in the deep well Komali Morc-4. Legend: I) facies of fenestra! and CharopfJy/rl limestone (X); salt and brackish marshes, tidal /lat cnvironment; 2) facies of foraminiferal wackestone-packstone, marl with ostracods and fille grainecl breccia conglomeratc (A): coastal environme nt with repeated shal lowing and emersions: 3) facies of foraminiferal packstone-grainstone limestone and miliolidal mudstone-wackestone limestone (8 and C); coastal env ironment with repeated shallowing and emersiOIlS: 4) facies of porous limestone - ?grainstonc (Y); ?beaches: 5) facies of fossi liferous mudstone-packstone limestone (D); shallow platform and mud mounds envi­ ronment; 6) facies of algal boundstone (bindslonc) and wackestone (E); platform margin buildups; 7) facies of the foraminiferal l1ludstone­ packstone (F): foreslopc environment: 8) facies of NlllillIlII!ites-Discocyciina floatstone-packstonc and grainstone-rudstone (0); foreslope environmcnt: 9) shallow marinc mudstone-wackestone; [0) shallow marine packstone-grainstone; II) core samples: 12) mud samples. arc filled with bitumen. The sed iments were deposited in a pericoastal environment with repeated shallowing and emersions. ]n the Jadran-9 well core mierocodium and pisolitic wackestone-packstone alternate with some bauxite and fossiliferous packstone-wackestone with shell debris, bryozoans, red and green algae and benthic forami ­ nifers in argillaceous mudstone and caliche. Microcod i­ lim is developed by mycorrhizal calcification (symbio­ sis of fungi and cortical cel ls of the plant roots) and caliche typical of [hc limestonc paJacosoil (KLAPPA, 1978) , so they often occur together in the sed iment. 16 E g o N o 1\l N KATE - 1 15 GR ~ f--..,j. --- - - - -- ....I... AC 75 mcs/ft Sp 1'- ~ .: ~ -- f -? ~ ~G -~ , ~ ~, .-, > , F ~ < ,---' ~ F:2m \. ~ ~ , > ~G -, , 1 , , , I ; , E , I , , . I , , ~? J ':. , { , <' , '-" 0 V> '" LITHOLOGY ~ .. ~ .. V> -I :;i 1 I lev @ :1! -jp f-p 'J- .. I .1'&',., !z ! ;; '" " Z '" .. ISL. 8. - 7. I- Z 7. .. -& N I- 8. _. a: a: I- .. - '" 6 . , z I- .. - I- W I- 5. " ~ 3.- z .. I- iii 2 . B 1 g - w ~ 3 . :. 5 . z " - ;: z !.! a: l­ V> .. " '" Fig. 3 Sequence of Pa laeogene carbonates in the deep we ll Kate- I. For legend sec Fig. 2. Such facies indicates :1 coastal environme nt with varia­ lion s of the sea leve l over a low lying plain. Coas tal (supratidal) sed iments alternate wi th sed iments indica­ t ive o f highly reduc tive s wamps thai are seasonal ly JADRAN -9 GR :I: I- Ae .. .. 0 0 i 0 0 '" Geologia C rO:l1ica 50/1 I- Z '" ~ LITHOLOGY ~ a: ;; Z w 7. 8 . 5 . 3. 2 . " .. I- w l- " ~ z .. '" " U ~ z o z w V> Fig. 4 Sequence of Palaeogene carbonates in the deep well Jad .. "n-9 . For legend sec Fig. 2. dried and occasionally with marine mitotid limestone due 10 minor sea level rise (DAVIS, 1985). Geochemical studies of the core samples determined that anlOrphous huminil c/vi trinite kerogen (>95 % ) is the dominant form of organic matte r (Corg 0.26- 0.43 % ), and it is therefore assumed that it was de ve­ loped by the biodegradation or a te rres tria l p recursor. The deposits do not exhibi t the source rock characteris­ tics as the major part of the organi c mallcr has bee n oxidiscd (high HI) within the sed imentary environme nt. The maturation parameter T U13X (407 -41 O°C ) indicates an especia lly low degree of thermal transformation, and the re fore these sed ime nts cannot be cons idered as the source rocks. Mud samples in ot her intervals or Kornali Morc-4 , Kate- I and Jadran-9 wells (Figs. 2, 3 and 4) havc s imi­ lar charac te ri s tics to thc rocks in the cored in tc rvals . The thickness of th is facies varies between 10-26111. T;Hi KovaCic: The Development orlhe Eocene Plalfonn Carbon~ tes from Well s ... ~ >­.. w o o o ~ o o ., JADRAN - 3 10 API GR 60 U) ---- - ----------~--- w AC 9?mcs/ m 50 ~ .. "' '" '" LITHOLOGY :. w ,. z i1 ;; z w 6 . 5. w (!) « >­ w >­ ::> ~ z 3 . '" 2 . 1. Pc? z '" z o z W Fig. 5 Sequence of Palaeogcne carbonates in the deep well Jadran-3. For legend see r ig. 2. Sed imentary faeies 10 which the sediments of the wirel ine log facies A belong to, are sediments of coastal plain wi th fresh water flow s, swamps that occasionally dry ou t, and the beaches that are flooded by the sha llow sea that fo rms shallow res tricted lagoons. Due to the lack of index fo ssils the age is roughly de term inat ed as Lower and /or Middl e Cuis ian on the basis o f Caskinolina sp. , Fallate//a sp. , Spirolina sp. , discorb ids, rOl alid s, sma ll miliolids , ostracod s and green algae, and because the sediments o f facies A are confo rmably overlain by younger sediments of a deter­ minable age without any sedimentation break. 3.3. Facies Band C - sedimentary facies of foraminifera l packstone-grainstone (Facies B) and miliolid mudstone-wackestone (Facies C) (the t idal flat environment) This fac ies is composed by alternation of facies B and C in a ll the we ll s. The density , po ros ity and acoust ic logs show th e good correlation of the two facies in a ll wells except in the Kate- l well (Figs. 3 and I ~ >­.. w o o ~ SUSAK MORE - 1 G R 20API 120 (I) .J. ___ _ __ ....1. W 100 .AC m$C/It ~ 5( ~ '" LITHOLOGY T I REVERSE F LT >­z ! ~ w ~ '" o ~ I-- 4. 3. I-- 2. 37 w z w g ::; o , w Z w @ z '" iii '5 () o· 1. ~ .. "' 4 . - 3. I-- 2 . 1 . .. "' z '" z ! w () z '" :; () () Fig. 6 Seq ucnce of Pal aeogene carbonat cs in the decp well Susak More-I . For legc nd sec Fi g. 2. 8) where the exchanges are more frequent in relation to the thickness of both faci es. Porosity in faci es B varies from 1010 25%, density 2. 35-2.60 g/cm3 and acoustics 38 Geologi:l Croalica 50/1 2 FACIES "A" ~\O'!. 2.2 IADRAN -l( o) CO, C., (1174-11S!hn) XATB.I ( 0) (237S-2J"m) 25 ~ 2.4 ~ ~ ~C()~' ~ 2.6 C~~ .. ~ '" 2.8 3 -5 o 5 10 15 20 25 CO:MPENSATED NEUTRON POROSITY (%) 100 0 0 0 F~CIES '''A'' 0 90 80 0 JADRAN-J ( 0 ) 0 (17S9-1774m) 0 0 KATE-I Co) (2375-238Sm) ~ • gg .. ;: 0 ·E~o~ ! o 0 , ~; 20 o'V ", 0 10 o so 60 70 80 90 100 110 120 ACOUSTIC (~s I it) from 197-230.10.6 slm (60-70 mes/ fL ). The values of these parameters in the Susak Morc-l well (Fig. 6) arc not re liable because of the cavernous borehole, but the charac te ristics of the Band C faci es a rc still visible. The gamma ray curve cloes nol reflect the changes in these facie s in any of the wells. In the lower part of the interval the va lues arc hi gher between 30 and 70 API. In Lhe upper parL , Lhey do noL exceed 30 A PI uniLs. Only in the Susak More - 1 well the va lues arc very hi gh , among 50 and 100 API uniLs. The facies was cored only in the Jadran-9 well, but in the tectonicaly rcpcated section in the interval 1342- 1345.2 m. Bauxitc oolites point to emcrs ion and/or the vic inity of karstificd coast, while fo ssilifc rous wacke­ stone-packstonc and grainstone limestone with benthic foramin ifers and eeilinids, algae and shell debris indi- 30 - - 130 140 a b foi g.7 Facies A: a) cross pl ot response showi ng car­ bonate point di stribution; b) GR/AC cross plOl response. ca te high energy shallow water environment. Facics C was cored in Lhe inLerval 1029- 1032 m. Li ghL brown miliolid wackcslone-packs LOne alte rnates with dark grcy and brown fe nes tral wackestone with gastropods. Fencstrae arc fill ed wit h internal sed im ent and mosaic drusy ca lcite cement. Shallow karstified surfaces and geopctal fabr ics we re al so noted. T he environm en tal energy was low. The mud samples of the samc facies in the Ka tc-I well also contain ostracods and oncoids. BOLh raeies arc Lypieal for Lhe Lidal flaL , Lheir appear­ ance and development can be connected to thc a ltcrna­ ti on of the sed iments depositcd in tidal channels (facies B) wiLh Lhose from Lh e shelLered lagoons (ponds) of hi gher salinity (facies C). The regularity of the alterna­ tion or both fac ies in all the we ll s (exccpt thc Katc-l well ) is curious. It is impossible to determinc whether T"ri Kov;ti;ic: The Development of the Eocene PI::l!fonn Carbonatcs from Wells ... 39 2 ,----- - - ----- - - ------, 2.2 'a ~ 2.4 ~,,~ 2.6 ~ 2.8 FACIES "B" JADRAN - 3 (.) (1730-1759m) KORNAll MORE _ 4 (.) (I690-1710lD) 3 ,-__ . -5 o 5 10 15 20 25 COMPENSATED NElITRON POROSITY (%) 00 90 FACIES "B" 80 JADRAN-3 ( 0 ) (17S9-1774m) a 30 b 1- KORNATIMORE-4 <.) f-- (237S-238Sm) 60 . ":.. '. -'. 30 \i~~~ 20 -" ... 10 0 40 '0 60 70 80 90 100 110 120 ACOUSTIC (~S 1ft) they represen t shallowing upward cycles or sto rm tide deposits. Onl y in the the Kate- I well are facies Band C also recognised be low facies X (Pi gs. 3 and 17). According to LUCIe ( 1993) this prese nt s the only known Palaeocene tidal nat deposit in the Adriatic off-shore. The forami niferal association with Coskillolillo per­ pera HOTTINGER & DROBNE ancl Cilry.wlidil/a lIIakarskac (van SOEST), determined the age as Lower Eocene (Middle - Upper Cuisian). 3.4. Facies Y - sedimentary facies of porous limestone - '!grainstone (? beaches) Facies Y was iso latcd only in the Susak More- l well (Fig. 6), on ly on the gamma ray and acollstic logs, because during the drilling at the depth of 775 m (in the 1- 130 140 Fig. R Facics 13 : a) cross pt ol response showi ng car­ bonale poinl dislri bulion; b) GR/AC c ross pial responsc. lOp of this facies), the com plete loss of mud occurred , and due to cavernous borehole the porosity and density values are invalid . As the well samples were not available the determi­ nat ion or the facies charac teristics and the sed imentary envi ronment was not possible. Although, [he physical characteristics of scdimcnts enable certain assumptions. The decrease of gamma radiation is visible as well as the increase in acoustic value in relation to the facies B in the base. Such charac teristi cs corespond to the po rOlls limestone (?grainstone) developed in the hi gh energy envjronmcnt , where the mud component was washed out. If that is the case, following the Walter 's low (WILSON , 1975) on the lateral and vcrtical changes of the facies, these deposits could be interpret­ ed as the beach sands deposited over the tidal fla t facies 40 Geologia Cromie:! 50/1 2 FACIES "D" S\.0 1> 2.2 JADRAN -3(o) (1604-1 67Sm) KATE· I (0) (221S-2299m) '8 2.4 ~ ~ ~ ~C\)), ~ 2.6 C~;!>." " S "' 2.8 3 L-____________________ ~~~~ ~ 0 5 10 15 W ~ ~ a COMPENSATED NEumON POROSITY (%) 80 FACIES "0" JADRAN - 3 ( 0) (1604-167Sm) KATE-! Co) (221S-2299m) KORNATIMORE-4 C, ) (IS7S-163Sm) ,,~::, 'F 0 '0 60 70 80 90 100 110 ACOUSTIC (~s I ft) 13 and C presenting regrcsive part of the sequence. 3.5. Facies D - sed imentary facies of fossiliferous mudstone - packstone limestone (the shallow phltform and mud mounds environment) 120 In the north-western part of the carbonate platform the sedimentary sequence ends wit h the emersion by the end or the Lower Eocene (facies Y in the S usak Morc- I well). In the other areas the sedimentat ion con­ tinues during the gradual sea level ri sco f-ac ies D fol ­ lows con formably on the facies B in the KOlllati More- 4, Kate- I, Jad ran -9 and Jadran-3 wells (Figs . 2, 3, 4, 5 and 9). The lower part of (he interval is composed of sedi ­ ment s with porosity vary ing between 3-18%, density of 2.50-2.65 g/em and aco List ics bct ween 197-230· 10.6 s/m (60 and 70 mes/h ). [n the upper part of the inte rv a l, 130 b Fig. 9 Facics D: a) cross pl ot response showi ng car- 14{) bonate poi nt di stri blltion: b) GR/AC c ross plO L responsc. which has been developed in a ll the wells except the Jadran-9 well , the sediments are of hi ghe r dens ity (2.60-2.70 g/cm), lower porosity ( 1-8%) and aeo List ics ( 184- 197.10-6 s/m, i.e. 56-60 mes/ft ). Gamma ray inten­ si ty is low: 10-20 API. In the Jadran-9 well the thi ck­ ness of these sediments is 8-22 m, whi Ie e lsewhere is 58-80 m. The fac ies has not bee n cored. Accord ing to the anal ys is of mud samples, m udsto ne, wackestone and packstone containing miliolicls, conica l and large foraminifers and shells and corals debris, were deposi­ ted in the subtidal zone beneath the normal wawe base on the shallow platform. The fra gments of coral s and she ll s probably originate from di stant shoals (facies E) or from the mud mounds. Tn the upper part of the facies D of the Jadran-3 well (Fig. 5), mostly in the mudstone and wackestone/Ooat- 'I\l ri Kov;lcic: '111e Developmelll of the Eocene PI:lIfonn C:Hbona l c.~ from Wells ... 100 90 FACIES "E" 80 - KATE-I (.) (2168-221Sm) - KORNATIMORE - 4 (.) ( ISIS-1S7Sm) 30 20 -~-.~ - P' , ,. .. ~ . • ' \0 o 2.8 2.6 2.4 2.2 DENSITY (glcm') stone, new faunal clcments appear: corals and plankto­ nic foraminifera. T hese sedim ents can be compared with the Illud hu mmocky cross lami nation in the rcef base (ELLOY , 1982) where they arc actually located. It is important that the foraminiferal community changes in this faci cs . NumJllulites sp., Opercu/il/(f sp., A ssilina sp., and Discocyc!illa sp. of Ihe Midd le Eocene (Lut etian) age appcar for thc first lim c. The boundary between thc Cui s ian and Lu tclian coincides wit h the change of facies Band C into facies D. 3.6. Facies E - sedimentary facies of algal boundstone (bindstone) and wackestone (marginal platform buildups) The sedim ents of thi s facies arc developed in the Komati More-4, Kate- I and Jadran-3 wells (Figs. 2, 3, 5 and 10). On the wi re- li nc logs the typical scrrated curvc shows acoustics 56-90 mcs/ft , po rosity 3-30 % and dens ity 2. 35-2.70 g/cm3 . The gamm a ray value is less than 10 API. 'fh e faci es in Jadran-3 well was tcs ted by the mech­ anical core in the interval 1565-1565.3 m (Pi g. 12). Fi£. I I Ostracode mtt d)o,tone-wackes tone. facies A. Earl y Eocene (Cuisian). Jadran -3. 1764 m, 25X. 41 --- 2 Fig. 10 Facies E: GR/DEN cro ss plot response. The rock is classified as al ga l bound stone (bind ­ stone) and wackestone according to the classification of EMBRY & KLOVA N ( 1971 ). It con tain s large foramini fera (NulJIlJIlIlites, Discocyclill(l , Amphistegina and Operculina), fin e benthic foraminifers, planktoni c foraminifers , bryozoans , corals, she ll s, echinids and encrusting red algae. As only a small interval of the fac ies was tes ted by coring (30 cm), it is diffi cult to determine is that the truc rcc f o r some o ther k ind o f margi nal platform bui ldup. According to the reg ional position and the appearance on the se ismi c lines, and also to the vertical and lateral spreading of the consid­ ered faci es, it may be det ermined as the marg inal plat­ form buildup. The changeable porosity is typical for reefs and also for peri -reefal facies. The literature describes in detail the complex processes that des troy primary and/or [0 1111 the secondary poros ity (LAPORTE, 1974; BAB IC & ZUPANIC, 1979; TOOM EY, 1981; ELLOY , 1982; SELLEY, 1985). In Komati MoreA accordin g 10 the Illud cuttings the sedime nt s are dolomitized (a lso expressed all the dens ity and porosity logs) . In the Kate- I we ll , the karst development and open active Fig. 12 N/lII/II/IlIi{l 'S-Lilllo{lwl/lllilllll bindstone- floatstonc, facies E, M iddle Eocene (Lute ti an). Jadrnn-3, 1565 m . 28X. 42 00 90 I 80 FACIES "F" KATE- t (0) (2070-2168m) KORNATIMORE-4 <.) (1470-1515m) 60 30 20 +-~-0 40 so 60 70 80 90 100 110 120 ACOUSTIC (~s/ft) fracture systems are visible on the photo-electrical absorption curve (PEF). The rise or the curve value PEF from 5 (limestone) to 7-9 in a rew intervals was caused by baroid drilling mud infiltration. In the Jadran-3 well this facies is the final member of the carbonate succession. The sedi mentat ion contin­ ues with siliciclastic turbidites, in the deeper sedimenta­ ryenvironment. 3.7. Facies F - sedimentary facies of the foramini­ feral mudstone-packstone (foresiope environment) Facies F overlies on the reefal limestone in the Kor­ nati More-4 and Kate-l wells (Figs. 2, 3 and 13). It appears in the Jadran-9 well (Fig. 4) between the two intervals of the facies G, while in the Kale-J well (Fig. 3) it alternates with facies G. The wire-l ine log facies almost looks like facies D. Porosi ty varies between 1- 6%, density from 2.55-2.70 g/cm3 and acoustics appro­ ximately 60 mcs/ft. The value of gamma ray intensity doesn 't excecd 15 API units. Fig. 14 Di.H:ocydina grainstone-packstone, facies F, Middle Eocene (Lutetian), Jadran-9, 1445 Ill, 25X. Geologia Croatica 50/ 1 130 140 Fig. 13 Facies F: GR/AC cross plot response. This facies hasn't been cored. According to the mud samples (Fig. 14) there are foraminiferal mudstone, wackestone-floatstone and packstone with coralli­ nacean and bryozoan debris. Its thickness is 46-98 meters. Sediments from this facies are of Lutetian age (Spilaerogypsil/a globula (REUS), ASlerigeril/a rOlula KAUFMANN, Diseoeyclil/a sella D' ARCHIAC, Lepi­ docyclina sp., Nummulites sp., Turborotalia cerroasu­ leI/sis possagl/oensis (TOUMARKINE & BOLLI), Globigerina sc/1I1i (BECKMANN». They developed on the very edge of the platform toward the slope and basin, and they are laterally and vertically (Waltcr' s Law) the first neighbouring member of facies E and G of the transgressive sequence. The main criterion for determining the sedimentary environment was the fossil contenl. Bioclastic deposits in which the association of Discocyclina, Nummulites, Asterieyclilla and Sphacrogipsina dominate, with the significant presence of planktonic foraminifers, undoubtedly shows the foreslope and toe of slope envi- Fig. [5 NllliIlIllllites-Discocycfina grainstone, facies G, Middle Eo­ cene (Lutctian), Jadran-9, 92 [ 111, 28X. Tari Kovacic: '111e Dc"clopmClll of the Eocene Pl:Ltfonn Caroon;llcs frolll Wells ... ronm en t beneath the wave base (B IGNOT, 1972; GHOSE, 1977; DROBNE et aI., J 991). 3.8. Facies G - sedimentary faci es of Nu mmulites­ Discocyclillo floatstone-packstone and grainstone-rudstone (open platform shoals) Facies G overlies facies D in the Jadran-9 well (Fig. 4). In Kornati MoreA and Kate-l wel ls (Figs. 2 and 3) it slicceeds facies F. In the Kornati More- I and Jadran- 9 wells it cyclically alternates facies F. The wire-line log characterist ics or fac ies G are poros it y of 3-10% in the Kate-I well , up to 25% in Kornati Mo re-4 we ll and up to 19% in the Jad ran-9 well. The density var ies from 2.35-2.55 g/cm3 and acoust ics from 164- 197· 10 " s/m (50-60 mes/ft) . Gam­ ma r3Y intensity is approximatc ly 10 API. Facies G was studied in mechan ica l cores in Kate-! well between 2028-2046 m. According to the lithofa­ cies and sedimentological interpre tation the rock is composcd of NtllIlI1l11lites-D iscocyclhw noatstone/ packstone wi th occasionally hi gher con ten t of corall i­ naceans and bryozoans and fragments or ech inoderms and shells. The matrix contains fine-grained fossil frag­ ments and carbonatc mud, and rarcly mosa ic drusy cal­ ci te cement. Grainstone/rudstone typcs appear very often. Primary intraskeletal porosity is hi gh but it was diminished because o f the ceme ntation of intraskeietai cavities. Oil shows are connected with frac tures or sty­ lolitic su rface s and tec tonic fabrics wit h variable impregnation of the surrounding rock, especially where there arc dissolution hol es developed. Limestone of this fac ies was sed ime nt ed in the open piali'orm shallow water environment. In the ladran ~9 well, the same fac ies was s tudied be tween 915-92 1 m. According to pet rograph ic and lithological ana lyses, the rock is forami nifera l grai n­ stone-packstone (Pig. 15) and occasionally glauconitic. Because of the high energy environment, there are only a few planktonic foraminifera, whi le large foraminifers (mostly NUII/IIII/lires) are abundant. In the vertical sequence, the sed iments of facies G in Ihe wells Kale- ! , Kornati More-4 and Jadran-9 aggradationally alt ernate with fac ies F o f the forereef environment, like the re fl ection of platform pu lsi ng before its final drowning uncler the s ilic iclastic flysch deposits. Sedimen ts of the facies G arc of the Lutetian age, and in the Kate- I well they are somewhat younger - Lutetian to I3iarritzian (Operclf/illa biaricensis OPPENHEIM, NII/mlll/lires lIIi//ecapl/f I30UBEE, NllIIl­ /lllIlires dll}i'ello)'i D' ARCHIAC & HElM E). 4. lJISCUSSION 4.1. Co .... elation in Wells A schemat ic correlation cross secti on (Pig. 16) shows the extent of the considered deposi ts along the 43 Dinaric st ructural trend, from the Susak More- l well in the north-west to the Kate - I well in the sou th ~eas t. They represent the older (carbonate) part of the trans­ gress ive megasequence of the Palaeogene and Neogene beds. Facies X, A, B and C a rc easi ly corrclatable ac ross a ll the we ll s. They were deposi ted in the coastal e nvi­ ronment (facies X and A), and in the tidal nat (facies B and C). In the Susak More-l well area, the sedimen tary sequence of th e Eocene carbonates was int errupted a t the beginning or the Lutetian because of the uplifting of the ca rbonate platform , caus ing the emersion which lasted till the e nd of the Upper Eocene, when the depo­ si tion of carbonate sediments continues again. The sed i­ me nts of the Upper C re taceo us, Eocene and Lower O ligocene were repeated twice in the well due to a reve rse fault at the depth of approx imately 945 m. The to ta l thi ckness of the Eocene sequence in the th rus ted part is 140 m and in the autocht hon 142 m. Toward the south and south-cas t the res t of the car­ bonate plat form was oscillating and slow ly drown ing, wit h the te nde ncy of increasing thickness or regarded dcposits. The transgressive sequence continues through the Luteti an with fac ies D, E, F and G, and the env iron­ men t changes from int ernal shallow platform toward platform edge. The thicknesses oj" the Lutetian depos its in Jadran-9 well arc 276, 132 and 157 m (tecton ica lly repeated sequcnces), in the Jadran-3 well is 288 111 , in Kornati More-4 we ll 369 111 , and in the Kate- I well 395 m. In the Jadran-3 well area fac ies E (p latform marg in bu il dup) completes the ca lcareolls part of the transgres­ sive mcgaseq uence, wh ich continues with fly sch sedi­ ment ation. Facies G and F in the ladran-9, Kornati MoreA and Kate-l wells arc repeated cyclically. Shoals or open sha llow waters pass in to sedime nts of the fo re­ reef e nvi ro nme nt. Such an a lte rnation of facies is the result o f multiple, rela tive osc illa tions of sea level (Pig. 17) that do not correspond wit h the eustat ic c urve of the sea level change (HAQ e t a I. , 1987) . Thi s reflects the pulsing of the platform before its fin a l drowni ng (SCIILAGER , 1981) because of the subsidence in front of the growing thrust structures of the Dinaridcs in the East. Because of fo ld ing ( recumbent fold ) and thrusting, in the Jadran-9 well, the same Palaeogene earbonale sediments were drilled in three intervals, with the mid­ dle interval being inverse. In all three inlcrvals the sequence of facies from X to G is identical. The thi ck~ ness of the inverted intcrval (132 m) is smaller in rela­ lion to the other two intervals because of the overbur­ den compaction and the structural dip of deposits. 4.2. Correlation wHh On-shore Sediments According to their facia l characteristics, off-shore facie s X, A, and B can be com pared to the Liburnian and miliolidal limestone (SIKIC & POLSAK, 1973; BIG NOT, 1972; DROBNE, 1979) in l stria (Fig. 17). 44 SUSAK MORE - 1 GR III = 2 JAORAN-3 GR L E ~ 3 8 4 KORNATI MOR E - 4 GR G E N 0 ' [E • . ,@.: 5 o • 0' .IIJ ~ 6 Geologia Croatica 50/1 KA TE · 1 GR D 7 • - - - - - 8 o 50 100 150 m VERTICAL SCALE HORIZONTAL : NOT IN SCALE Fig. 16 Facies display: I) perit idal deposits: 2) coastHl deposi ts; 3) lidal flat deposits: 4) shallow platform deposi ts: 5) ope n platform shoals: 6) ?bcach deposits: 7) platform margin bu ildups: 8) foreslopc deposits: 9) fl ysc h. However on the Koromacno cape in the base or the Li bu rni an sedi ments, there are poiimiclic brecc ia COIl ­ g lomerates 15 In thick, that arc also in a transgress ive relations hi p to the Upper Cretaceous limes tone. The breccia conglomerate is complete ly ullsorted, and CO I1 - tains met re, c1ccimetre and centimetre sized c lasts of the Cre taceous and Pa laeocene (Kozina type) lim estone, and la rge c lasts of thick dark red and orange ca lc it e veins in the calcarenite matrix. O n the Los inj island, in the base of the miliolid (m udstonc-wackcstonc and packstone-grainstone) lime­ stone, the re a re al so transgressive breccias, approx i­ mately I mthick, with clasts of Cretaccotls limestone. The posit ion o f the breccia conglomerate is ident ical 1'01' bot h o utc rops, so it is poss ible that they were fonned during the same event as the facies X in the off­ shore Ad riat ic. On the islands of Pasman , Ugljan and Kornati the facie s 1\, Band Care reduccd to a thickness of 3 m. MAMUZIC & NEDE LA- DEVIDE (1973) describe this as a tran sg ress ion ex pressed by basa l brecc ias in the " terra rossa" or recl c lay matrix up to 20 cm thick. The unconformity is almost unnoticeable. Brown platy lime­ stone that is similar to the Liburnian beds, with abu n­ dant small gastropods and mil iolids is depos ited on this transgress ive mate ri al. Even this level is not thicke r than 20 cm. The follo wing 2.5 m consis ts o f light brown, sli ghtly chal ky limestone w ith mili ol ids and some gastropods. There is a similar development of the same sediments on the islands of Ugljan and Losinj. The transgressive contact between the C re taceous and Eocene in the Ravni Kotari area is characterised by a karstified surface with bauxite or by supratidal fenes­ tral and intertidal miliolid limestone virtually concor­ dant with the underlying depos it s (D ROBNE e t a I. , 1991); so fac ies X and A arc reduced (Fig. 18) . Facies Band C arc of similar thickness to those [rom the Jad­ ran-9 well (approx. lOO m). Alveoli na and Nummulites limestone o[ the Midd le Eocene, by the ir sed imentolog­ ica l and biostratigraphic characte ri s ti cs, can be com­ pa red with the sedimcnts of fac ies D, F and G in the off-shore. Platform margin lim estone in the we ll s Jadran-3 , Komati More-4 and Kate- I (Figs. 17 and 19) is devel­ oped on the very western edge of the carbonat e plat­ form. The scarse cored samples of th e wire lin e log facies on the buildup , well expressed on the seimic cross sections , do not a llow dete rminati o n of th e reef sens i/ striClO. Rccently publi shed papers (DRAGI­ CEV IC e t aI., 1992) and well dat a fro lll the Sou thern Adriatic indicate that the ree fs are not the exotic c le­ men ts in that area. In the Jadra n-3 well the pl at form Tari KovaCi~: The Development of the Eocene Platfonll Carbonates from WeilL. ,; EUSTATIC CURVE WE L L S , 200 100 0 SM·l ,·3 KM · 4 '"' " -- - - - •• - - • .. • z • z u 0 • • 0 ,. 0 • IC , KATE · l - , 45 OUTCROPS I.Korometno2.Lotinj ).SlIba 4 . U"Jan S .hnkovac II . Skt.din _-~I.:,I~ , • -• e:c.5 x ~X~X RS!ID x~ x ? ~XI~XI (:UJD x 1 55 • 6. 6' THANETIAN • ~ u 110.2 - ----- - ~ ~ DANIAN : II .4 H 61111.1981. ~B"C ? ~6'C , ~B"C Fig. 17 Corrclation o f the on-shore and off-shore deposits. Legen<.l : X) perit idal deposits; XI) subfacies of the facies X in the outcrops: A) coasta l deposits: B+C) tidal nat deposits: D) shall ow plalfonn deposits; E) platfonn margin bui ldups: F) fo reslopc deposits: G) open plat­ form shoals: Y) ?beach deposits. margin was drowncd during the LUlctian, slightly earli ­ er than in other wells, because of the sudden tectoni c subsidcnce. At the same time in the Kornati More-4 and Kate- I wells, buildups first migrate toward the land in prograding transgression, and then they were replaced by shoals that indicate the relative shallowing or the sea level (tcc tonic uplift). Drowning or the platform beneath the fly sch depos it s is timed by nannofossils at the upper part or the Middle Lutetian: NP~15/16 nan nofoss il zone in (stria, in Ravni Kotari somewhat laler (NP~ 16) and in the Split area NP- 17 (BENIC, 1991). Therefore the ear­ bonale sed imcnts or .I3iarritzian age in the Kate- I well can be compared onl y to the sedi ment s sout h of the Krka rive r (in the surroundings of Skradin), and Sou th ~ ern Dalmatia (Peljesac and Cavtat). 4.3. Petroleum potential In the Eocene limestone oj" the Katc ~ I well o il shows were traced in small intervals be tween 2020- 5630 m. In the considered sequence of the Eocene lime­ stone, hyd rocarbon shows occur in the intervals 2020- 2086 III and 2340-245 0 m. Part of the interval frolll 2394~2450 m is of Crctaeeous age. The rese rvoir char­ actcris ti cs were primarily good (facies G) , but they were com ple tely destroyed by diagene tic processes. The oil appears in poorly connected fractures and vugs (secondary, frac tu J"C and "vuggy porosity"). Geochem ical analyses of the oil proved the presence o f su lphur (6-6.8%), and domination of n ~aJkanes . The pristane/phitane ratio is less than 1. The precursor is lhe ke roge ne type 11, lipids of algal and bacterial origi n deposited in a highly reductive environment. The oil from the Eocene limestone is characterised by "napht­ eni e hump" on the gas chromatograph, which is not presellt in Ihe deeper intervals of the well. This is ex plained by the lower kalagenctie degree or transfor~ mation or by possible oil degradation compared to the mature katagenet ic degree of trans forn1ation evaluated in the oil from deeper parts of the well. It is certain that the oil does not originate from the Eocene limestone of facies A. The organ ic matter in the facies A originates from kerogen type III which is dom~ inatcd by amorphous huminite/v itrinite or a tcrres trial precursor in the immaturc stage of the rmal transronna~ tion. In thc Jadran-9 and Jadran-3 wells, becausc of the cond ition s in the sedi mentary environment (peritidal cnvironmen t with occasional bracki sh wate r), most of the organic matter is ox id ised. However, in the Cretaceous sediments in the J adran ~ 9, Jadran~3 and Kate-I well s sourec rocks were detcr~ mined that are in the early stage of the the rmal katage~ netic transformation (the beginning of the oil window) that generate oil. The Upper Cretaceous laminated mudstone of limited extcnt and thickness were deposit~ ed in the anoxic lagoons and conta in heavy isotopes (DC = 22-25%) and kerogen type I and 11. The precur~ sor is the algal~bacterial organi c matter of marine origin from a very rcduced environment, confirmed by the presence of heavy isotopes. The rock is also immature. The Lower Cretaceous source rocks contain kero­ gene type II and subordinately type I, in the early stage of ka tagenctic transformation. Organic rich lami nated stromatolit ic mudstone was depos ited in lagoons of hi gher sali nity and sabkhas. Thi s is confirmed by the pristane/phitane ratio which is lower than 1, the pres­ ence of sulphur rich asphaJtene and by heavy isotopes C ~C == 22%). On the gas chromatogram there is also a charac teri st ic " naphtenic hump", the same as ror the oil from Eocene reservoirs. Com paring the characteri stics of source rocks and oil , it is possible to conclude that oil has migrated into the a rea of Katc- l well from estimated so urce rocks of the Lower Cretaceous evaporite-carbonate beds. 46 -"- - -"- -"-- -"- ~....'L-i:..::J.._ .JL .JL. ....lL. ....:L -"- -"- -"- "" ,, --_ e SM·1 e_ KM·4 o GcologjL. ...:>L ............. L.. ...:L. ....lL...x. ..x.. SM-1- .....IoL.. ->L. L....:.L ~ $... .....\l.. -"4 ...;L .:L ~ -"- ~2 o SOkm -~~~~ ... 3 Fig. 19 Palaeogeograph ic map of LUlctian , faci es E, F and G. Legend: I) shoals; 2) forcslopc; 3) plalform margi n buildups; 4) land; 5) slope. Position of IIle outcrop from the Fig. 17 arc keyed by numbers. 5. SUMMARY The paper is a comprehens ive study of the facies characteri stics of the Eocene Carbonate beds found in the Ce ntral Adriat ic wells: Kate-I, Iadran-3, Kornali More-I , Jadran -9, and Susak More-I. Considering wireline log analysis it has been possi­ ble to identi fy the wirclinc log-hlCics X, A, B, C, Y, D, E, P, G and H. The relevant sedimentary facie s have been de fined based on geo log ical and drilling data - analysis of conventional cores and mud cllttings. Facies X, characterised by tidal flat sediments, rep- Tari KovaCic: The Development of lhc Eocene Phufoml Carbon:l1es from Wells ... resents the firs t brief e pi sode te rminated by emersion. Facies A is thc first member of thc second major trans­ g ress ive sequence with which eventu a ll y te rminates development of the Adria tic (Dinari c) carbonate plat ­ form. It begins w ith a s treak m arke r horizon within a sedimentary fa c ies cha rac te rised by coas ta l lagoons, marshes and beaches. Cyclic alterna tion of Band C facies is cha racte ri stic for the tidal flat. Facies Y is the fin al membe r of the analysed sequence o f beds on the uplifted lstrian platform. Simultaneously, the carbonate p latform g radua ll y subsi ded to the south -east (D facies) . With furthe r transg ressions environment s become more dis tal , thus the fin a l membe rs o f the car­ bona te seque nce are formed by barrier bars, buildups and fores lope deposits ( faci es E, r +G). The s tudied beds have been affec ted by tangential tec toni c eve nt s at the e nd of the Eoccne pe riod. As a result of rolding ancl thru sting, the eas tc rn part of the studied area is upl ifted , wh ile the weste rn is lowered , thus form ing the Dugi Otok depression which has been fill ed with fl ysc h and flyschlike depos it s du ring the younger Palaeogene and in Miocene. Beds of the fac ies X have an uncertain s tratig raphic position, younger than the CrClaceouS but o lclc r than the Cuisian. Tran sg ress ive sequence fro111 A to Y faci es was form ed during C ui sian, whereas the others belong to the Lute tian (and Biarritzian). In corre lation with surface outcrops the synchronous beds, along the Dinaric strike show an al most ident ical deve lopment of the scdime ntary e nvi ronment regardless of how di stant these Illay be (the arca of Labin in Istria and the we ll s ill the Adriatic offshore) . Much closer sedilllen ts on Ihe Komal i islands and in Ravni Kotar outcropping in a perpendicular direc tion to the Dinar­ ides arc d iffe rc nt from the offshore sediments both with regard to composition and thickness. Acknowledgement The autho r wishcs to thank to the INA's Directory having perm itted thc publication o f this study and to G. BU RG EO IS , E. BALAZ, D. STANKOV IC, D. LUCIC , G. BARIC, J. T IS LJ AR and K. DROBNE, whose pa l­ aeontological, sedimento logical and geochemical analy­ ses were L1 sed in thi s paper. The author is espec ially grate ful to D. 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