Geological Survey of Denmark and Greenland Bulletin 4, s 2003, pp 13-16 13 GESTCO is an acronym for European potential for the Geological Storage of CO2 from fossil fuel combustion. The project formed part of the ENERGIE Programme of the European Union 5th Framework and was concluded in 2003. The Geological Survey of Denmark and Greenland (GEUS) led the project, with the national geological surveys of Belgium, France, Germany, Greece, the Netherlands, Norway and UK as research partners (Fig. 1). The primary goal of the GESTCO project was to deter- mine whether the geological storage of carbon dioxide cap- tured at large industrial plants is a viable method of reducing greenhouse gas emissions in Europe (Christensen 2000; Gale et al. 2001; Christensen & Holloway 2003). This was evalua- ted by a series of case studies that assessed the CO2 storage potential of saline aquifers, geothermal reservoirs, coal seams and oil and gas reservoirs. The case study approach was used so that currently available, largely theoretical, generic infor- mation could be applied to real geological situations. In addi- tion aspects of safety and environment, conflicts of using underground space and public and stakeholder perception were evaluated. Secondary goals of the GESTCO project were to establish an inventory of major CO2 point sources in Europe and a Decision Support System (DSS) to serve as an economic analysis tool for CO2 storage in Europe. Inventory of large CO2 point sources Major industrial sources of CO2 in the participating coun- tries were identified and compiled into a database. In almost all countries, the major sources of CO2 are power plants, Fig. 1. Map of Europe showing the participating countries and offshore study areas included in the GESTCO project. Geological Survey of Denmark and Greenland Bulletin 4, 13–16 (2004) © GEUS, 2004 Assessing the European potential for geological storage of CO2: the GESTCO project Niels Peter Christensen and Michael Larsen 14 integrated steel plants, refineries/petrochemical complexes and cement works. The exception is Norway, where many of the major sources of CO2 are generators at offshore oil and gas fields. The location and details of the sources of CO2 are compiled into a Geographic Information system (GIS) ena- bling qualified search routines. In Denmark, the annual emission of greenhouse gases is close to 60 Mt of which approximately half originates from fossil fuel combustion related to power and heat generation. Major CO2 point sources were identified based on yearly reports to the Danish Energy Authority. These point sources alone contribute 29 Mt CO2 of the total CO2 emission in Denmark. The largest single source is the coal-fired power plant Asnæsværket in Kalundborg, with an average yearly emission of 5.8 Mt CO2 in the period 1994–1999. Conside- ring CO2 sequestration from Asnæsværket could thus ac- count for approximately half of the greenhouse gas reductions required for Denmark in the Kyoto agreement (Larsen et al. 2003a). European storage capacities Underground storage capacities in the case study areas were evaluated by seismic mapping, analysis of well logs and reser- voir simulation. The results are summarised in Christensen & Holloway (2003). The major part of the mapped storage capacity was related to deep saline aquifers in onshore and nearshore sedimentary basins in Denmark, Germany, south- ern UK and northern France. In the Netherlands and Bel- gium the storage potential is primarily related to exhausted gas fields and coalmines. A huge potential exists in aquifers offshore Norway, and it is likely that very large additional off- shore aquifer potential exists in British and Danish sectors of the North Sea. The Greek storage potential is composed of aquifers as well as a few hydrocarbon fields. Significant stor- age capacity is related to the gas and oil fields of northern Europe, particularly in the North Sea and onshore in the Netherlands and Germany. Geological storage capacities in Denmark The potential storage capacity in Denmark was evaluated through case studies of onshore and nearshore saline aquifers, and hydrocarbon fields of the Danish North Sea sector. Deep saline aquifers Large sedimentary basins of Late Palaeozoic – Cenozoic age are present in Denmark and provide a potential for CO2 stor- age. In the onshore or nearshore Danish area the reservoir units comprise porous sandstone layers of the Lower Triassic Bunter Sandstone Formation / Skagerrak Formation, the Upper Triassic – Lower Jurassic Gassum Formation, the Middle Jurassic Haldager Sand Formation, and the Upper Jurassic Lower Cretaceous Frederikshavn Formation. Map- ping and initial description of these units has been under- taken in the search for hydrocarbons and geothermal reservoirs (cf. Nielsen et al. 2004, this volume). The GESTCO aquifer study was focused on sandstone for- mations within a depth range of 900–2500 m, i.e. between the depth required for CO2 to become a dense fluid and the depth below which reservoir quality typically deteriorates due to diagenetically induced reduction of porosity and permea- bility. The total storage capacity of unconfined aquifers in Denmark has been estimated to be 47 Gt of CO2, although only a small part of the volume was related to structural clo- sures (Holloway et al. 1996). In order to gain public and 15 political acceptance, structural traps are considered essential, at least initially, when considering storage onshore Denmark, and consequently the GESTCO study was focused on eleven large structures (Fig. 2; Table 1). These structures were mapped from seismic surveys and evaluated using data from existing deep wells to assess the storage potential (Larsen et al. 2003b). Based on many years of experience from aquifer storage of natural gas in Denmark, Germany and France, it is assumed that 40% of the total pore volume within a trap could be filled with CO2. This effective storage capacity will depend on a number of parameters including the geometry of the trap (e.g. difference in height between top point and spill point), the number of injection wells, injection rates and reservoir characteristics. The initial calculations carried out in the present study suggest that the eleven structures alone may provide storage for at least 16 Gt of CO2 (Table 1; Larsen et al. 2003b). Note that almost two thirds of the calculated aquifer storage capacity is present in the Thisted/Legind structure. As well as a proper reservoir, a tight cap rock is needed when considering underground storage of CO2. Geological formations with good sealing properties are lacustrine and marine mudrocks, evaporites and carbonates. In Denmark the most important sealing rock type is marine mudstone, which often forms units several hundred metres thick and is present at several stratigraphic levels. In addition to the pri- mary cap rock, chalk of Late Cretaceous – Danian age forms a possible secondary seal in most of the Danish area. The sea- ling effect of the chalk is dependent on chemical reactions between dissolved CO2 and the carbonate rock. Detailed site surveys will be needed in order to test the integrity of the seal at any future storage site. Storage in oil and gas fields Although the potential storage capacity of deep saline aquifers is many times greater than that of hydrocarbon structures, there are some distinct advantages of using deple- ted hydrocarbon fields as storage sites. First, the hydrocarbon fields have proved their capability to retain fluids and gases, in many cases for millions of years. Secondly, the reservoir is well understood due to intensive data gathering before and during the productive life of the field, and finally infrastruc- ture for the production and transport of fluids and gases is already in place. With some modifications, this infrastructure may often be re-usable for delivery and injection of CO2 for storage. The reserve figures for 14 chalk fields and three sandstone fields of the Danish sector were included in the GESTCO project (Christensen & Holloway 2003). These comprise detailed estimates of the expected ultimate (initial) reserves, and rounded figures for low and high case reserves as given by the Danish Energy Authority (DEA 2002). The storage capacity of hydrocarbon reservoirs is calculated from the underground volume of ultimately recoverable oil or gas. The calculation assumes that the entire underground volume of recoverable hydrocarbons can be replaced by CO2. For gas reservoirs, this is a straightforward assumption, since most gas reservoirs are of a closed nature. Formation water (the aquifer) does not significantly replace the drained gas during Fig. 2. Map showing the position and outline of the eleven structural closures mapped in the Danish aquifer case study of the GESTCO project. Black dots indicate the position of deep exploration wells used in the evaluation of the reservoirs. Modified from Larsen et al. (2003a). 16 the producing field life. For oil reservoirs, it is assumed that the amount of CO2 that can be stored in the reservoir is approximately 30% of the oil initially in place. Since the Ultimate Recovery (UR) of most oil fields (as initially re- ported) also approximates 30–35%, the storage capacity can be approximated by the initial proven reserves (or UR). In addition to the volumetric estimates special concern is needed when considering storage of CO2 in chalk, as chemi- cal and physical reactions are likely to occur between CO2 in solution and carbonate rocks. Based on the above assumptions, the Danish storage capacity for existing oil and gas fields is estimated to be 629 Mt CO2. Of this, 452 Mt can replace natural gas, while 176 Mt can replace oil (Christensen & Holloway 2003). How- ever, all of the investigated fields of the Danish North Sea are in the production phase, and CO2 injection will probably not be possible in the near future unless applied through En- hanced Oil Recovery (EOR) operations. The EOR option of the North Sea is currently under investigation and prelimi- nary results have been presented by Markussen et al. (2003). The vision of the project is to capture CO2 from the Danish power plants and export it through an extensive pipeline sy- stem to the offshore industry. Implementation of the EOR technology would have great impact on the lifecycle of Danish oil and gas production. Conclusions The inventory of major point sources of CO2 and the geo- logical storage potential mapped in the GESTCO project indicate that the eight European countries could make a sig- nificant impact on their national CO2 emissions by captu- ring the emissions from a relatively small number of the largest point sources and storing them underground. In Denmark, mapping of geological structures suitable for underground storage of CO2 suggests that enough storage volume is present within the subsurface to store several hun- dred years of total CO2 emissions from Danish industry and power production. Detailed site surveys and risk analysis, including long term monitoring, are needed to validate these storage capacities and should be the focus of future studies. Acknowledgements The project formed part of the ENERGIE Programme of the European Union 5th Framework Programme for Research & Development, Project No. ENK6-CT-1999-00010, and was 50% funded by the Programme. In addition to the principal research partners, valuable contributions to the project were made by the Flemish Institute for Technological Research (Vito, Belgium), Public Power Corporation of Greece, Com- pagnie Française de Geothermie (CFG), Danish Oil and Natural Gas Company (DONG), CE-Transform (the Netherlands) and the Tyndall Centre (UK). Further contributions to the project were given by BEB (now EMPG), BP, Danish Energy Authority, Gaz de France, IEA Greenhouse Gas R&D Programme, Norsk Hydro, Norwegian Petroleum Directorate, Shell, Statoil, Total-FinaElf, the UK Department of Trade and Industry, and Vattenfall. References Christensen, N.P. 2000: The GESTCO Project: assessing European poten- tial for geological storage of CO2 from fossil fuel combustion. In: Williams, D. et al. (eds): Proceedings of the Fifth International Conference on Greenhouse Control Technologies (GHGT-5), 261–265. Cairns, Australia: CSIRO Publishing. Christensen, N.P. & Holloway, S. 2003: Geological storage of CO2 from combustion of fossil fuel. European Union Fifth Framework Programme for Research and Development, summary report, 34 pp. Copenhagen, Denmark: Geological Survey of Denmark and Green- land. DEA 2002: Oil and gas production in Denmark 2001, 98 pp. Copen- hagen, Denmark: Danish Energy Authority. Gale, J., Christensen, N.P., Cutler, A. & Torp, T.A. 2001: Demonstrating the potential for geological storage of CO2: the Sleipner and Gestco Projects. Environmental Geosciences 8, 160–165. Holloway, S. et al. 1996: The underground disposal of carbon dioxide. Joule II project No. CT92-0031, summary report, 24 pp. Keyworth, Nottingham, UK: British Geological Survey. Larsen, M., Bidstrup, T. & Christensen, N.P. 2003a: Saline aquifer storage of CO2 from major point sources – a Danish case study. In: Gale, J. & Kaya, Y. (eds): Greenhouse gas control technologies. Proceedings of the Sixth International Conference (GHGT-6), Kyoto, October 2002, 657–661. Larsen, M., Bidstrup, T. & Dalhoff, F. 2003b: CO2 storage potential of selected saline aquifers in Denmark. Danmarks og Grønlands Geo- logiske Undersøgelse Rapport 2003/39, 83 pp. Markussen, P., Austell, J.M. & Hustad, C.-W. 2003: A CO2-infrastructure for EOR in the North Sea (CENS): Macroeconomic implications for host countries. In: Gale, J. & Kaya, Y. (eds): Greenhouse gas control technologies.Proceedings of the Sixth International Conference (GHGT-6), Kyoto, October 2002, 1077–1082. Nielsen, L.H., Mathiesen, A. & Bidstrup, B. 2004: Geothermal energy in Denmark. Geological Survey of Denmark and Greenland Bulletin 4, 17–26 (this volume). Authors’ address Geological Survey of Denmark and Greenland, Øster Voldgade 10, DK-1350 Copenhagen K, Denmark. 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