id	sid	tid	token	lemma	pos
hjic-751	1	1	hungarian	hungarian	ADJ
hjic-751	1	2	journal	journal	NOUN
hjic-751	1	3	of	of	ADP
hjic-751	1	4	industry	industry	NOUN
hjic-751	1	5	and	and	CCONJ
hjic-751	1	6	chemistry	chemistry	NOUN
hjic-751	1	7	vol	vol	NOUN
hjic-751	1	8	.	.	PUNCT
hjic-751	1	9	45(1	45(1	NOUN
hjic-751	1	10	)	)	PUNCT
hjic-751	1	11	pp	pp	ADP
hjic-751	1	12	.	.	PUNCT
hjic-751	2	1	29–36	29–36	NUM
hjic-751	2	2	(	(	PUNCT
hjic-751	2	3	2017	2017	NUM
hjic-751	2	4	)	)	PUNCT
hjic-751	2	5	hjic.mk.uni-pannon.hu	hjic.mk.uni-pannon.hu	NOUN
hjic-751	2	6	doi	doi	NOUN
hjic-751	2	7	:	:	PUNCT
hjic-751	2	8	10.1515	10.1515	NUM
hjic-751	2	9	/	/	SYM
hjic-751	2	10	hjic-2017	hjic-2017	NOUN
hjic-751	2	11	-	-	PUNCT
hjic-751	2	12	0006	0006	NUM
hjic-751	2	13	formation	formation	NOUN
hjic-751	2	14	,	,	PUNCT
hjic-751	2	15	photophysics	photophysic	NOUN
hjic-751	2	16	,	,	PUNCT
hjic-751	2	17	photochemistry	photochemistry	NOUN
hjic-751	2	18	and	and	CCONJ
hjic-751	2	19	quantum	quantum	ADJ
hjic-751	2	20	chemistry	chemistry	NOUN
hjic-751	2	21	of	of	ADP
hjic-751	2	22	the	the	DET
hjic-751	2	23	out	out	ADJ
hjic-751	2	24	-	-	PUNCT
hjic-751	2	25	of	of	ADP
hjic-751	2	26	-	-	PUNCT
hjic-751	2	27	plane	plane	NOUN
hjic-751	2	28	metalloporphyrins	metalloporphyrin	NOUN
hjic-751	2	29	zsolt	zsolt	PROPN
hjic-751	2	30	valicsek	valicsek	PROPN
hjic-751	2	31	,	,	PUNCT
hjic-751	2	32	1	1	NUM
hjic-751	2	33	*	*	PUNCT
hjic-751	2	34	melitta	melitta	PROPN
hjic-751	2	35	p.	p.	PROPN
hjic-751	2	36	kiss	kiss	PROPN
hjic-751	2	37	,	,	PUNCT
hjic-751	2	38	1	1	NUM
hjic-751	2	39	melinda	melinda	PROPN
hjic-751	2	40	a.	a.	PROPN
hjic-751	2	41	fodor	fodor	PROPN
hjic-751	2	42	,	,	PUNCT
hjic-751	2	43	1	1	NUM
hjic-751	2	44	muhammad	muhammad	PROPN
hjic-751	2	45	imran	imran	PROPN
hjic-751	2	46	,	,	PUNCT
hjic-751	2	47	2	2	NUM
hjic-751	2	48	and	and	CCONJ
hjic-751	2	49	ottó	ottó	NOUN
hjic-751	2	50	horváth	horváth	PROPN
hjic-751	2	51	1	1	NUM
hjic-751	2	52	1	1	NUM
hjic-751	2	53	department	department	NOUN
hjic-751	2	54	of	of	ADP
hjic-751	2	55	general	general	ADJ
hjic-751	2	56	and	and	CCONJ
hjic-751	2	57	inorganic	inorganic	ADJ
hjic-751	2	58	chemistry	chemistry	NOUN
hjic-751	2	59	,	,	PUNCT
hjic-751	2	60	institute	institute	NOUN
hjic-751	2	61	of	of	ADP
hjic-751	2	62	chemistry	chemistry	NOUN
hjic-751	2	63	,	,	PUNCT
hjic-751	2	64	faculty	faculty	NOUN
hjic-751	2	65	of	of	ADP
hjic-751	2	66	engineering	engineering	NOUN
hjic-751	2	67	,	,	PUNCT
hjic-751	2	68	university	university	PROPN
hjic-751	2	69	of	of	ADP
hjic-751	2	70	pannonia	pannonia	PROPN
hjic-751	2	71	,	,	PUNCT
hjic-751	2	72	egyetem	egyetem	NOUN
hjic-751	2	73	u.	u.	PROPN
hjic-751	2	74	10	10	NUM
hjic-751	2	75	.	.	PUNCT
hjic-751	2	76	,	,	PUNCT
hjic-751	2	77	h-8200	h-8200	PROPN
hjic-751	2	78	veszprém	veszprém	NOUN
hjic-751	2	79	,	,	PUNCT
hjic-751	2	80	hungary	hungary	PROPN
hjic-751	2	81	2	2	NUM
hjic-751	2	82	department	department	NOUN
hjic-751	2	83	of	of	ADP
hjic-751	2	84	chemistry	chemistry	NOUN
hjic-751	2	85	,	,	PUNCT
hjic-751	2	86	baghdad	baghdad	PROPN
hjic-751	2	87	-	-	PUNCT
hjic-751	2	88	ul	ul	NOUN
hjic-751	2	89	-	-	PUNCT
hjic-751	2	90	jadeed	jadeed	NOUN
hjic-751	2	91	campus	campus	NOUN
hjic-751	2	92	,	,	PUNCT
hjic-751	2	93	the	the	DET
hjic-751	2	94	islamia	islamia	PROPN
hjic-751	2	95	university	university	PROPN
hjic-751	2	96	of	of	ADP
hjic-751	2	97	bahawalpur	bahawalpur	PROPN
hjic-751	2	98	,	,	PUNCT
hjic-751	2	99	63100	63100	NUM
hjic-751	2	100	bahawalpur	bahawalpur	NOUN
hjic-751	2	101	,	,	PUNCT
hjic-751	2	102	pakistan	pakistan	PROPN
hjic-751	2	103	among	among	ADP
hjic-751	2	104	the	the	DET
hjic-751	2	105	complexes	complex	NOUN
hjic-751	2	106	of	of	ADP
hjic-751	2	107	porphyrins	porphyrin	NOUN
hjic-751	2	108	,	,	PUNCT
hjic-751	2	109	special	special	ADJ
hjic-751	2	110	attention	attention	NOUN
hjic-751	2	111	has	have	AUX
hjic-751	2	112	been	be	AUX
hjic-751	2	113	paid	pay	VERB
hjic-751	2	114	to	to	ADP
hjic-751	2	115	those	those	PRON
hjic-751	2	116	possessing	possess	VERB
hjic-751	2	117	out	out	ADP
hjic-751	2	118	-	-	PUNCT
hjic-751	2	119	of	of	ADP
hjic-751	2	120	-	-	PUNCT
hjic-751	2	121	plane	plane	NOUN
hjic-751	2	122	(	(	PUNCT
hjic-751	2	123	oop	oop	NOUN
hjic-751	2	124	)	)	PUNCT
hjic-751	2	125	structures	structure	NOUN
hjic-751	2	126	,	,	PUNCT
hjic-751	2	127	for	for	ADP
hjic-751	2	128	the	the	DET
hjic-751	2	129	formation	formation	NOUN
hjic-751	2	130	of	of	ADP
hjic-751	2	131	which	which	PRON
hjic-751	2	132	the	the	DET
hjic-751	2	133	size	size	NOUN
hjic-751	2	134	,	,	PUNCT
hjic-751	2	135	as	as	ADV
hjic-751	2	136	well	well	ADV
hjic-751	2	137	as	as	ADP
hjic-751	2	138	the	the	DET
hjic-751	2	139	coordinative	coordinative	ADJ
hjic-751	2	140	character	character	NOUN
hjic-751	2	141	of	of	ADP
hjic-751	2	142	the	the	DET
hjic-751	2	143	metal	metal	NOUN
hjic-751	2	144	center	center	NOUN
hjic-751	2	145	are	be	AUX
hjic-751	2	146	responsible	responsible	ADJ
hjic-751	2	147	.	.	PUNCT
hjic-751	3	1	in	in	ADP
hjic-751	3	2	these	these	DET
hjic-751	3	3	coordination	coordination	NOUN
hjic-751	3	4	compounds	compound	NOUN
hjic-751	3	5	,	,	PUNCT
hjic-751	3	6	the	the	DET
hjic-751	3	7	central	central	ADJ
hjic-751	3	8	atom	atom	NOUN
hjic-751	3	9	can	can	AUX
hjic-751	3	10	not	not	PART
hjic-751	3	11	fit	fit	VERB
hjic-751	3	12	coplanarly	coplanarly	ADV
hjic-751	3	13	into	into	ADP
hjic-751	3	14	the	the	DET
hjic-751	3	15	cavity	cavity	NOUN
hjic-751	3	16	of	of	ADP
hjic-751	3	17	the	the	DET
hjic-751	3	18	ligand	ligand	NOUN
hjic-751	3	19	,	,	PUNCT
hjic-751	3	20	hence	hence	ADV
hjic-751	3	21	,	,	PUNCT
hjic-751	3	22	it	it	PRON
hjic-751	3	23	is	be	AUX
hjic-751	3	24	located	locate	VERB
hjic-751	3	25	above	above	ADP
hjic-751	3	26	the	the	DET
hjic-751	3	27	porphyrin	porphyrin	NOUN
hjic-751	3	28	plane	plane	NOUN
hjic-751	3	29	,	,	PUNCT
hjic-751	3	30	distorting	distort	VERB
hjic-751	3	31	it	it	PRON
hjic-751	3	32	.	.	PUNCT
hjic-751	4	1	equilibria	equilibrium	NOUN
hjic-751	4	2	and	and	CCONJ
hjic-751	4	3	kinetics	kinetic	NOUN
hjic-751	4	4	of	of	ADP
hjic-751	4	5	the	the	DET
hjic-751	4	6	complex	complex	ADJ
hjic-751	4	7	formation	formation	NOUN
hjic-751	4	8	,	,	PUNCT
hjic-751	4	9	spectrophotometric	spectrophotometric	ADJ
hjic-751	4	10	,	,	PUNCT
hjic-751	4	11	photophysical	photophysical	ADJ
hjic-751	4	12	and	and	CCONJ
hjic-751	4	13	primary	primary	ADJ
hjic-751	4	14	photochemical	photochemical	ADJ
hjic-751	4	15	properties	property	NOUN
hjic-751	4	16	of	of	ADP
hjic-751	4	17	post	post	ADJ
hjic-751	4	18	-	-	NOUN
hjic-751	4	19	transition	transition	NOUN
hjic-751	4	20	and	and	CCONJ
hjic-751	4	21	lanthanide	lanthanide	ADJ
hjic-751	4	22	oop	oop	NOUN
hjic-751	4	23	metalloporphyrins	metalloporphyrin	NOUN
hjic-751	4	24	were	be	AUX
hjic-751	4	25	investigated	investigate	VERB
hjic-751	4	26	,	,	PUNCT
hjic-751	4	27	in	in	ADP
hjic-751	4	28	addition	addition	NOUN
hjic-751	4	29	electronic	electronic	ADJ
hjic-751	4	30	structural	structural	ADJ
hjic-751	4	31	calculations	calculation	NOUN
hjic-751	4	32	were	be	AUX
hjic-751	4	33	performed	perform	VERB
hjic-751	4	34	;	;	PUNCT
hjic-751	4	35	hence	hence	ADV
hjic-751	4	36	,	,	PUNCT
hjic-751	4	37	the	the	DET
hjic-751	4	38	general	general	ADJ
hjic-751	4	39	oop	oop	PROPN
hjic-751	4	40	characteristics	characteristic	NOUN
hjic-751	4	41	were	be	AUX
hjic-751	4	42	determined.meanwhile	determined.meanwhile	ADJ
hjic-751	4	43	,	,	PUNCT
hjic-751	4	44	few	few	ADJ
hjic-751	4	45	doubtful	doubtful	ADJ
hjic-751	4	46	questions	question	NOUN
hjic-751	4	47	have	have	AUX
hjic-751	4	48	attempted	attempt	VERB
hjic-751	4	49	to	to	PART
hjic-751	4	50	be	be	AUX
hjic-751	4	51	answered	answer	VERB
hjic-751	4	52	concerning	concern	VERB
hjic-751	4	53	the	the	DET
hjic-751	4	54	categorization	categorization	NOUN
hjic-751	4	55	of	of	ADP
hjic-751	4	56	metalloporphyrins	metalloporphyrin	NOUN
hjic-751	4	57	,	,	PUNCT
hjic-751	4	58	the	the	DET
hjic-751	4	59	borderline	borderline	NOUN
hjic-751	4	60	case	case	NOUN
hjic-751	4	61	complexes	complex	NOUN
hjic-751	4	62	and	and	CCONJ
hjic-751	4	63	hyperporphyrins	hyperporphyrin	NOUN
hjic-751	4	64	.	.	PUNCT
hjic-751	5	1	keywords	keyword	NOUN
hjic-751	5	2	:	:	PUNCT
hjic-751	5	3	out	out	ADJ
hjic-751	5	4	-	-	PUNCT
hjic-751	5	5	of	of	ADP
hjic-751	5	6	-	-	PUNCT
hjic-751	5	7	plane	plane	NOUN
hjic-751	5	8	metalloporphyrins	metalloporphyrin	NOUN
hjic-751	5	9	,	,	PUNCT
hjic-751	5	10	formation	formation	NOUN
hjic-751	5	11	kinetics	kinetic	NOUN
hjic-751	5	12	,	,	PUNCT
hjic-751	5	13	uv	uv	NOUN
hjic-751	5	14	-	-	PUNCT
hjic-751	5	15	vis	vis	X
hjic-751	5	16	spectrophotometry	spectrophotometry	NOUN
hjic-751	5	17	,	,	PUNCT
hjic-751	5	18	photochemistry	photochemistry	NOUN
hjic-751	5	19	,	,	PUNCT
hjic-751	5	20	borderline	borderline	NOUN
hjic-751	5	21	case	case	NOUN
hjic-751	5	22	complexes	complexe	VERB
hjic-751	5	23	1	1	NUM
hjic-751	5	24	.	.	PUNCT
hjic-751	5	25	introduction	introduction	NOUN
hjic-751	5	26	porphyrins	porphyrin	NOUN
hjic-751	5	27	and	and	CCONJ
hjic-751	5	28	their	their	PRON
hjic-751	5	29	derivatives	derivative	NOUN
hjic-751	5	30	play	play	VERB
hjic-751	5	31	important	important	ADJ
hjic-751	5	32	roles	role	NOUN
hjic-751	5	33	in	in	ADP
hjic-751	5	34	several	several	ADJ
hjic-751	5	35	biochemical	biochemical	ADJ
hjic-751	5	36	systems	system	NOUN
hjic-751	5	37	.	.	PUNCT
hjic-751	6	1	four	four	NUM
hjic-751	6	2	pyrroles	pyrrole	NOUN
hjic-751	6	3	are	be	AUX
hjic-751	6	4	connected	connect	VERB
hjic-751	6	5	through	through	ADP
hjic-751	6	6	methylidine	methylidine	NOUN
hjic-751	6	7	bridges	bridge	NOUN
hjic-751	6	8	,	,	PUNCT
hjic-751	6	9	forming	form	VERB
hjic-751	6	10	the	the	DET
hjic-751	6	11	porphin	porphin	ADJ
hjic-751	6	12	ring	ring	NOUN
hjic-751	6	13	.	.	PUNCT
hjic-751	7	1	its	its	PRON
hjic-751	7	2	planar	planar	ADJ
hjic-751	7	3	structure	structure	NOUN
hjic-751	7	4	with	with	ADP
hjic-751	7	5	an	an	DET
hjic-751	7	6	extended	extended	ADJ
hjic-751	7	7	conjugated	conjugate	VERB
hjic-751	7	8	π	π	PROPN
hjic-751	7	9	-	-	PUNCT
hjic-751	7	10	electron	electron	NOUN
hjic-751	7	11	system	system	NOUN
hjic-751	7	12	provides	provide	VERB
hjic-751	7	13	aromatic	aromatic	ADJ
hjic-751	7	14	characteristics	characteristic	NOUN
hjic-751	7	15	and	and	CCONJ
hjic-751	7	16	a	a	DET
hjic-751	7	17	special	special	ADJ
hjic-751	7	18	coordination	coordination	NOUN
hjic-751	7	19	cavity	cavity	NOUN
hjic-751	7	20	for	for	ADP
hjic-751	7	21	the	the	DET
hjic-751	7	22	binding	binding	NOUN
hjic-751	7	23	of	of	ADP
hjic-751	7	24	metal	metal	NOUN
hjic-751	7	25	ions	ion	NOUN
hjic-751	7	26	of	of	ADP
hjic-751	7	27	suitable	suitable	ADJ
hjic-751	7	28	radius	radius	NOUN
hjic-751	7	29	[	[	X
hjic-751	7	30	1	1	NUM
hjic-751	7	31	-	-	SYM
hjic-751	7	32	2	2	NUM
hjic-751	7	33	]	]	PUNCT
hjic-751	7	34	.	.	PUNCT
hjic-751	8	1	metalloporphyrins	metalloporphyrin	NOUN
hjic-751	8	2	are	be	AUX
hjic-751	8	3	the	the	DET
hjic-751	8	4	central	central	ADJ
hjic-751	8	5	parts	part	NOUN
hjic-751	8	6	of	of	ADP
hjic-751	8	7	naturally	naturally	ADV
hjic-751	8	8	important	important	ADJ
hjic-751	8	9	compounds	compound	NOUN
hjic-751	8	10	,	,	PUNCT
hjic-751	8	11	e.g.	e.g.	ADV
hjic-751	8	12	,	,	PUNCT
hjic-751	8	13	magnesium(ii	magnesium(ii	ADJ
hjic-751	8	14	)	)	PUNCT
hjic-751	8	15	chlorins	chlorin	NOUN
hjic-751	8	16	in	in	ADP
hjic-751	8	17	bacteriochlorophylls	bacteriochlorophyll	NOUN
hjic-751	8	18	and	and	CCONJ
hjic-751	8	19	chlorophylls	chlorophyll	VERB
hjic-751	8	20	;	;	PUNCT
hjic-751	8	21	iron(ii	iron(ii	X
hjic-751	8	22	)	)	PUNCT
hjic-751	8	23	protoporphyrin	protoporphyrin	NOUN
hjic-751	8	24	in	in	ADP
hjic-751	8	25	hemoglobin	hemoglobin	NOUN
hjic-751	8	26	;	;	PUNCT
hjic-751	8	27	and	and	CCONJ
hjic-751	8	28	iron(iii	iron(iii	NOUN
hjic-751	8	29	)	)	PUNCT
hjic-751	8	30	protoporphyrins	protoporphyrin	NOUN
hjic-751	8	31	in	in	ADP
hjic-751	8	32	myoglobin	myoglobin	NOUN
hjic-751	8	33	,	,	PUNCT
hjic-751	8	34	cytochromes	cytochrome	NOUN
hjic-751	8	35	,	,	PUNCT
hjic-751	8	36	oxidase	oxidase	NOUN
hjic-751	8	37	,	,	PUNCT
hjic-751	8	38	peroxidase	peroxidase	NOUN
hjic-751	8	39	,	,	PUNCT
hjic-751	8	40	catalase	catalase	NOUN
hjic-751	8	41	,	,	PUNCT
hjic-751	8	42	and	and	CCONJ
hjic-751	8	43	oxoanion	oxoanion	NOUN
hjic-751	8	44	reductase	reductase	NOUN
hjic-751	8	45	enzymes	enzyme	NOUN
hjic-751	8	46	.	.	PUNCT
hjic-751	9	1	ringed	ring	VERB
hjic-751	9	2	tetrapyrroles	tetrapyrrole	NOUN
hjic-751	9	3	provide	provide	VERB
hjic-751	9	4	strong	strong	ADJ
hjic-751	9	5	chelating	chelating	NOUN
hjic-751	9	6	effect	effect	NOUN
hjic-751	9	7	which	which	PRON
hjic-751	9	8	can	can	AUX
hjic-751	9	9	promote	promote	VERB
hjic-751	9	10	the	the	DET
hjic-751	9	11	hyperaccumulation	hyperaccumulation	NOUN
hjic-751	9	12	of	of	ADP
hjic-751	9	13	rare	rare	ADJ
hjic-751	9	14	metal	metal	NOUN
hjic-751	9	15	ions	ion	NOUN
hjic-751	9	16	in	in	ADP
hjic-751	9	17	living	living	NOUN
hjic-751	9	18	cells	cell	NOUN
hjic-751	9	19	,	,	PUNCT
hjic-751	9	20	and	and	CCONJ
hjic-751	9	21	also	also	ADV
hjic-751	9	22	in	in	ADP
hjic-751	9	23	abiotic	abiotic	ADJ
hjic-751	9	24	environments	environment	NOUN
hjic-751	9	25	,	,	PUNCT
hjic-751	9	26	e.g.	e.g.	ADV
hjic-751	9	27	in	in	ADP
hjic-751	9	28	kerogens	kerogen	NOUN
hjic-751	9	29	.	.	PUNCT
hjic-751	10	1	in	in	ADP
hjic-751	10	2	porphyrins	porphyrin	NOUN
hjic-751	10	3	the	the	DET
hjic-751	10	4	conjugation	conjugation	NOUN
hjic-751	10	5	favors	favor	VERB
hjic-751	10	6	a	a	DET
hjic-751	10	7	planar	planar	ADJ
hjic-751	10	8	structure	structure	NOUN
hjic-751	10	9	.	.	PUNCT
hjic-751	11	1	however	however	ADV
hjic-751	11	2	,	,	PUNCT
hjic-751	11	3	peripheral	peripheral	ADJ
hjic-751	11	4	substituents	substituent	NOUN
hjic-751	11	5	or	or	CCONJ
hjic-751	11	6	the	the	DET
hjic-751	11	7	metal	metal	NOUN
hjic-751	11	8	center	center	NOUN
hjic-751	11	9	(	(	PUNCT
hjic-751	11	10	originating	originate	VERB
hjic-751	11	11	from	from	ADP
hjic-751	11	12	its	its	PRON
hjic-751	11	13	size	size	NOUN
hjic-751	11	14	or	or	CCONJ
hjic-751	11	15	axial	axial	ADJ
hjic-751	11	16	ligand	ligand	NOUN
hjic-751	11	17	)	)	PUNCT
hjic-751	11	18	can	can	AUX
hjic-751	11	19	cause	cause	VERB
hjic-751	11	20	geometrical	geometrical	ADJ
hjic-751	11	21	distortion	distortion	NOUN
hjic-751	11	22	.	.	PUNCT
hjic-751	12	1	this	this	PRON
hjic-751	12	2	certainly	certainly	ADV
hjic-751	12	3	affects	affect	VERB
hjic-751	12	4	the	the	DET
hjic-751	12	5	functions	function	NOUN
hjic-751	12	6	of	of	ADP
hjic-751	12	7	enzymes	enzyme	NOUN
hjic-751	12	8	,	,	PUNCT
hjic-751	12	9	as	as	ADV
hjic-751	12	10	well	well	ADV
hjic-751	12	11	as	as	ADP
hjic-751	12	12	the	the	DET
hjic-751	12	13	biosynthesis	biosynthesis	NOUN
hjic-751	12	14	of	of	ADP
hjic-751	12	15	metalloporphyrins	metalloporphyrin	NOUN
hjic-751	12	16	.	.	PUNCT
hjic-751	13	1	in	in	ADP
hjic-751	13	2	chemical	chemical	ADJ
hjic-751	13	3	research	research	NOUN
hjic-751	13	4	,	,	PUNCT
hjic-751	13	5	due	due	ADP
hjic-751	13	6	to	to	ADP
hjic-751	13	7	distortion	distortion	NOUN
hjic-751	13	8	,	,	PUNCT
hjic-751	13	9	redox	redox	NOUN
hjic-751	13	10	potentials	potential	NOUN
hjic-751	13	11	,	,	PUNCT
hjic-751	13	12	basicity	basicity	NOUN
hjic-751	13	13	,	,	PUNCT
hjic-751	13	14	reactivity	reactivity	NOUN
hjic-751	13	15	,	,	PUNCT
hjic-751	13	16	catalytic	catalytic	ADJ
hjic-751	13	17	*	*	NOUN
hjic-751	13	18	correspondence	correspondence	NOUN
hjic-751	13	19	:	:	PUNCT
hjic-751	13	20	valicsek@almos.uni-pannon.hu	valicsek@almos.uni-pannon.hu	NOUN
hjic-751	13	21	activity	activity	NOUN
hjic-751	13	22	and	and	CCONJ
hjic-751	13	23	coordinative	coordinative	ADJ
hjic-751	13	24	abilities	ability	NOUN
hjic-751	13	25	of	of	ADP
hjic-751	13	26	porphyrins	porphyrin	NOUN
hjic-751	13	27	can	can	AUX
hjic-751	13	28	be	be	AUX
hjic-751	13	29	modified	modify	VERB
hjic-751	13	30	.	.	PUNCT
hjic-751	14	1	also	also	ADV
hjic-751	14	2	,	,	PUNCT
hjic-751	14	3	due	due	ADP
hjic-751	14	4	to	to	ADP
hjic-751	14	5	the	the	DET
hjic-751	14	6	distortion	distortion	NOUN
hjic-751	14	7	,	,	PUNCT
hjic-751	14	8	the	the	DET
hjic-751	14	9	degree	degree	NOUN
hjic-751	14	10	of	of	ADP
hjic-751	14	11	symmetry	symmetry	NOUN
hjic-751	14	12	decreases	decrease	VERB
hjic-751	14	13	,	,	PUNCT
hjic-751	14	14	resulting	result	VERB
hjic-751	14	15	in	in	ADP
hjic-751	14	16	characteristic	characteristic	ADJ
hjic-751	14	17	spectral	spectral	ADJ
hjic-751	14	18	changes	change	NOUN
hjic-751	14	19	in	in	ADP
hjic-751	14	20	various	various	ADJ
hjic-751	14	21	ranges	range	NOUN
hjic-751	14	22	of	of	ADP
hjic-751	14	23	the	the	DET
hjic-751	14	24	electromagnetic	electromagnetic	ADJ
hjic-751	14	25	spectrum	spectrum	NOUN
hjic-751	14	26	.	.	PUNCT
hjic-751	15	1	the	the	DET
hjic-751	15	2	most	most	ADV
hjic-751	15	3	frequent	frequent	ADJ
hjic-751	15	4	types	type	NOUN
hjic-751	15	5	of	of	ADP
hjic-751	15	6	distortions	distortion	NOUN
hjic-751	15	7	are	be	AUX
hjic-751	15	8	dome	dome	ADJ
hjic-751	15	9	,	,	PUNCT
hjic-751	15	10	saddle	saddle	NOUN
hjic-751	15	11	,	,	PUNCT
hjic-751	15	12	ruffled	ruffled	ADJ
hjic-751	15	13	and	and	CCONJ
hjic-751	15	14	wave	wave	NOUN
hjic-751	15	15	(	(	PUNCT
hjic-751	15	16	chair	chair	NOUN
hjic-751	15	17	-	-	PUNCT
hjic-751	15	18	like	like	ADJ
hjic-751	15	19	)	)	PUNCT
hjic-751	16	1	[	[	X
hjic-751	16	2	3	3	NUM
hjic-751	16	3	]	]	PUNCT
hjic-751	16	4	.	.	PUNCT
hjic-751	17	1	overcrowded	overcrowded	ADJ
hjic-751	17	2	substitution	substitution	NOUN
hjic-751	17	3	on	on	ADP
hjic-751	17	4	the	the	DET
hjic-751	17	5	periphery	periphery	NOUN
hjic-751	17	6	[	[	X
hjic-751	17	7	3	3	NUM
hjic-751	17	8	-	-	SYM
hjic-751	17	9	4	4	NUM
hjic-751	17	10	]	]	PUNCT
hjic-751	17	11	or	or	CCONJ
hjic-751	17	12	insufficiently	insufficiently	ADV
hjic-751	17	13	short	short	ADJ
hjic-751	17	14	metal	metal	NOUN
hjic-751	17	15	-	-	PUNCT
hjic-751	17	16	nitrogen	nitrogen	NOUN
hjic-751	17	17	bonds	bond	NOUN
hjic-751	17	18	due	due	ADP
hjic-751	17	19	to	to	ADP
hjic-751	17	20	the	the	DET
hjic-751	17	21	shrinkage	shrinkage	NOUN
hjic-751	17	22	of	of	ADP
hjic-751	17	23	the	the	DET
hjic-751	17	24	coordination	coordination	NOUN
hjic-751	17	25	cavity	cavity	NOUN
hjic-751	17	26	can	can	AUX
hjic-751	17	27	cause	cause	VERB
hjic-751	17	28	the	the	DET
hjic-751	17	29	ruffled	ruffled	ADJ
hjic-751	17	30	or	or	CCONJ
hjic-751	17	31	saddled	saddle	VERB
hjic-751	17	32	deformation	deformation	NOUN
hjic-751	17	33	[	[	X
hjic-751	17	34	2	2	NUM
hjic-751	17	35	,	,	PUNCT
hjic-751	17	36	5	5	NUM
hjic-751	17	37	-	-	SYM
hjic-751	17	38	7	7	NUM
hjic-751	17	39	]	]	PUNCT
hjic-751	17	40	.	.	PUNCT
hjic-751	18	1	if	if	SCONJ
hjic-751	18	2	,	,	PUNCT
hjic-751	18	3	however	however	ADV
hjic-751	18	4	,	,	PUNCT
hjic-751	18	5	the	the	DET
hjic-751	18	6	m	m	PROPN
hjic-751	18	7	-	-	PUNCT
hjic-751	18	8	n	n	NOUN
hjic-751	18	9	bonds	bond	NOUN
hjic-751	18	10	are	be	AUX
hjic-751	18	11	significantly	significantly	ADV
hjic-751	18	12	longer	long	ADJ
hjic-751	18	13	than	than	ADP
hjic-751	18	14	half	half	DET
hjic-751	18	15	the	the	DET
hjic-751	18	16	length	length	NOUN
hjic-751	18	17	of	of	ADP
hjic-751	18	18	the	the	DET
hjic-751	18	19	diagonal	diagonal	ADJ
hjic-751	18	20	n	n	CCONJ
hjic-751	18	21	-	-	PUNCT
hjic-751	18	22	n	n	PRON
hjic-751	18	23	distance	distance	NOUN
hjic-751	18	24	in	in	ADP
hjic-751	18	25	the	the	DET
hjic-751	18	26	free	free	ADJ
hjic-751	18	27	-	-	PUNCT
hjic-751	18	28	base	base	NOUN
hjic-751	18	29	porphyrin	porphyrin	NOUN
hjic-751	18	30	,	,	PUNCT
hjic-751	18	31	dome	dome	ADJ
hjic-751	18	32	deformation	deformation	NOUN
hjic-751	18	33	can	can	AUX
hjic-751	18	34	occur	occur	VERB
hjic-751	18	35	.	.	PUNCT
hjic-751	19	1	this	this	PRON
hjic-751	19	2	happens	happen	VERB
hjic-751	19	3	if	if	SCONJ
hjic-751	19	4	the	the	DET
hjic-751	19	5	radius	radius	NOUN
hjic-751	19	6	of	of	ADP
hjic-751	19	7	the	the	DET
hjic-751	19	8	metal	metal	NOUN
hjic-751	19	9	center	center	NOUN
hjic-751	19	10	exceeds	exceed	VERB
hjic-751	19	11	the	the	DET
hjic-751	19	12	critical	critical	ADJ
hjic-751	19	13	value	value	NOUN
hjic-751	19	14	of	of	ADP
hjic-751	19	15	about	about	ADV
hjic-751	19	16	75	75	NUM
hjic-751	19	17	-	-	SYM
hjic-751	19	18	90	90	NUM
hjic-751	19	19	pm	pm	NOUN
hjic-751	19	20	(	(	PUNCT
hjic-751	19	21	depending	depend	VERB
hjic-751	19	22	on	on	ADP
hjic-751	19	23	the	the	DET
hjic-751	19	24	type	type	NOUN
hjic-751	19	25	of	of	ADP
hjic-751	19	26	porphyrin	porphyrin	NOUN
hjic-751	19	27	ligand	ligand	NOUN
hjic-751	19	28	)	)	PUNCT
hjic-751	19	29	or	or	CCONJ
hjic-751	19	30	square	square	ADJ
hjic-751	19	31	planar	planar	ADJ
hjic-751	19	32	coordination	coordination	NOUN
hjic-751	19	33	is	be	AUX
hjic-751	19	34	not	not	PART
hjic-751	19	35	preferred	prefer	VERB
hjic-751	19	36	.	.	PUNCT
hjic-751	20	1	such	such	ADJ
hjic-751	20	2	metal	metal	NOUN
hjic-751	20	3	ions	ion	NOUN
hjic-751	20	4	are	be	AUX
hjic-751	20	5	too	too	ADV
hjic-751	20	6	big	big	ADJ
hjic-751	20	7	to	to	PART
hjic-751	20	8	fit	fit	VERB
hjic-751	20	9	into	into	ADP
hjic-751	20	10	the	the	DET
hjic-751	20	11	ligand	ligand	ADJ
hjic-751	20	12	cavity	cavity	NOUN
hjic-751	20	13	.	.	PUNCT
hjic-751	21	1	hence	hence	ADV
hjic-751	21	2	they	they	PRON
hjic-751	21	3	are	be	AUX
hjic-751	21	4	located	locate	VERB
hjic-751	21	5	above	above	ADP
hjic-751	21	6	the	the	DET
hjic-751	21	7	plane	plane	NOUN
hjic-751	21	8	of	of	ADP
hjic-751	21	9	the	the	DET
hjic-751	21	10	pyrrolic	pyrrolic	ADJ
hjic-751	21	11	nitrogens	nitrogen	NOUN
hjic-751	21	12	;	;	PUNCT
hjic-751	21	13	forming	form	VERB
hjic-751	21	14	sitting	sit	VERB
hjic-751	21	15	-	-	PUNCT
hjic-751	21	16	atop	atop	NOUN
hjic-751	21	17	(	(	PUNCT
hjic-751	21	18	sat	sit	VERB
hjic-751	21	19	)	)	PUNCT
hjic-751	21	20	or	or	CCONJ
hjic-751	21	21	out	out	ADV
hjic-751	21	22	-	-	PUNCT
hjic-751	21	23	of	of	ADP
hjic-751	21	24	-	-	PUNCT
hjic-751	21	25	plane	plane	NOUN
hjic-751	21	26	(	(	PUNCT
hjic-751	21	27	oop	oop	ADV
hjic-751	21	28	see	see	VERB
hjic-751	21	29	fig.1	fig.1	PROPN
hjic-751	21	30	)	)	PUNCT
hjic-751	21	31	complexes	complex	NOUN
hjic-751	21	32	,	,	PUNCT
hjic-751	21	33	displaying	display	VERB
hjic-751	21	34	thermodynamic	thermodynamic	ADJ
hjic-751	21	35	instability	instability	NOUN
hjic-751	21	36	,	,	PUNCT
hjic-751	21	37	kinetic	kinetic	ADJ
hjic-751	21	38	lability	lability	NOUN
hjic-751	21	39	,	,	PUNCT
hjic-751	21	40	typical	typical	ADJ
hjic-751	21	41	photophysical	photophysical	ADJ
hjic-751	21	42	features	feature	NOUN
hjic-751	21	43	and	and	CCONJ
hjic-751	21	44	photochemical	photochemical	ADJ
hjic-751	21	45	reactivity	reactivity	NOUN
hjic-751	21	46	[	[	X
hjic-751	21	47	89	89	NUM
hjic-751	21	48	]	]	PUNCT
hjic-751	21	49	.	.	PUNCT
hjic-751	22	1	in	in	ADP
hjic-751	22	2	this	this	DET
hjic-751	22	3	work	work	NOUN
hjic-751	22	4	,	,	PUNCT
hjic-751	22	5	we	we	PRON
hjic-751	22	6	review	review	VERB
hjic-751	22	7	our	our	PRON
hjic-751	22	8	recent	recent	ADJ
hjic-751	22	9	results	result	NOUN
hjic-751	22	10	regarding	regard	VERB
hjic-751	22	11	the	the	DET
hjic-751	22	12	formation	formation	NOUN
hjic-751	22	13	,	,	PUNCT
hjic-751	22	14	structure	structure	NOUN
hjic-751	22	15	and	and	CCONJ
hjic-751	22	16	photoinduced	photoinduce	VERB
hjic-751	22	17	behavior	behavior	NOUN
hjic-751	22	18	of	of	ADP
hjic-751	22	19	water	water	NOUN
hjic-751	22	20	-	-	PUNCT
hjic-751	22	21	soluble	soluble	ADJ
hjic-751	22	22	oop	oop	NOUN
hjic-751	22	23	metalloporphyrins	metalloporphyrin	NOUN
hjic-751	22	24	.	.	PUNCT
hjic-751	23	1	these	these	DET
hjic-751	23	2	complexes	complex	NOUN
hjic-751	23	3	with	with	ADP
hjic-751	23	4	a	a	DET
hjic-751	23	5	diverse	diverse	ADJ
hjic-751	23	6	range	range	NOUN
hjic-751	23	7	of	of	ADP
hjic-751	23	8	metal	metal	NOUN
hjic-751	23	9	ions	ion	NOUN
hjic-751	23	10	can	can	AUX
hjic-751	23	11	be	be	AUX
hjic-751	23	12	more	more	ADV
hjic-751	23	13	simply	simply	ADV
hjic-751	23	14	produced	produce	VERB
hjic-751	23	15	in	in	ADP
hjic-751	23	16	aqueous	aqueous	ADJ
hjic-751	23	17	systems	system	NOUN
hjic-751	23	18	than	than	ADP
hjic-751	23	19	in	in	ADP
hjic-751	23	20	organic	organic	ADJ
hjic-751	23	21	solvents	solvent	NOUN
hjic-751	23	22	.	.	PUNCT
hjic-751	24	1	in	in	ADP
hjic-751	24	2	this	this	DET
hjic-751	24	3	regard	regard	NOUN
hjic-751	24	4	one	one	NUM
hjic-751	24	5	of	of	ADP
hjic-751	24	6	the	the	DET
hjic-751	24	7	most	most	ADV
hjic-751	24	8	suitable	suitable	ADJ
hjic-751	24	9	free	free	ADJ
hjic-751	24	10	-	-	PUNCT
hjic-751	24	11	base	base	NOUN
hjic-751	24	12	ligands	ligand	NOUN
hjic-751	24	13	is	be	AUX
hjic-751	24	14	the	the	DET
hjic-751	24	15	anionic	anionic	ADJ
hjic-751	24	16	5,10,15,20	5,10,15,20	NUM
hjic-751	24	17	-	-	PUNCT
hjic-751	24	18	tetrakis(4sulfonatophenyl)porphyrin	tetrakis(4sulfonatophenyl)porphyrin	NOUN
hjic-751	24	19	(	(	PUNCT
hjic-751	24	20	h2tspp4	h2tspp4	PROPN
hjic-751	24	21	–	–	PUNCT
hjic-751	24	22	see	see	VERB
hjic-751	24	23	fig.1	fig.1	PROPN
hjic-751	24	24	)	)	PUNCT
hjic-751	24	25	due	due	ADJ
hjic-751	24	26	valicsek	valicsek	ADJ
hjic-751	24	27	,	,	PUNCT
hjic-751	24	28	kiss	kiss	PROPN
hjic-751	24	29	,	,	PUNCT
hjic-751	24	30	fodor	fodor	PROPN
hjic-751	24	31	,	,	PUNCT
hjic-751	24	32	imran	imran	ADJ
hjic-751	24	33	,	,	PUNCT
hjic-751	24	34	and	and	CCONJ
hjic-751	24	35	horváth	horváth	PROPN
hjic-751	24	36	hungarian	hungarian	ADJ
hjic-751	24	37	journal	journal	NOUN
hjic-751	24	38	of	of	ADP
hjic-751	24	39	industry	industry	NOUN
hjic-751	24	40	and	and	CCONJ
hjic-751	24	41	chemistry	chemistry	NOUN
hjic-751	24	42	30	30	NUM
hjic-751	24	43	to	to	ADP
hjic-751	24	44	its	its	PRON
hjic-751	24	45	negative	negative	ADJ
hjic-751	24	46	charge	charge	NOUN
hjic-751	24	47	promoting	promote	VERB
hjic-751	24	48	the	the	DET
hjic-751	24	49	coordination	coordination	NOUN
hjic-751	24	50	of	of	ADP
hjic-751	24	51	positively	positively	ADV
hjic-751	24	52	charged	charge	VERB
hjic-751	24	53	metal	metal	NOUN
hjic-751	24	54	ions	ion	NOUN
hjic-751	24	55	.	.	PUNCT
hjic-751	25	1	besides	besides	SCONJ
hjic-751	25	2	,	,	PUNCT
hjic-751	25	3	this	this	DET
hjic-751	25	4	ligand	ligand	NOUN
hjic-751	25	5	is	be	AUX
hjic-751	25	6	the	the	DET
hjic-751	25	7	most	most	ADV
hjic-751	25	8	frequently	frequently	ADV
hjic-751	25	9	used	use	VERB
hjic-751	25	10	reagent	reagent	NOUN
hjic-751	25	11	among	among	ADP
hjic-751	25	12	the	the	DET
hjic-751	25	13	free	free	ADJ
hjic-751	25	14	-	-	PUNCT
hjic-751	25	15	base	base	NOUN
hjic-751	25	16	porphyrins	porphyrin	NOUN
hjic-751	25	17	[	[	X
hjic-751	25	18	1	1	NUM
hjic-751	25	19	]	]	PUNCT
hjic-751	25	20	.	.	PUNCT
hjic-751	26	1	2	2	X
hjic-751	26	2	.	.	X
hjic-751	26	3	experimental	experimental	ADJ
hjic-751	26	4	analytical	analytical	ADJ
hjic-751	26	5	grade	grade	NOUN
hjic-751	26	6	tetrasodium	tetrasodium	NOUN
hjic-751	26	7	5,10,15,20	5,10,15,20	NUM
hjic-751	26	8	-	-	PUNCT
hjic-751	26	9	tetrakis(4sulfonatophenyl)porphyrin	tetrakis(4sulfonatophenyl)porphyrin	NOUN
hjic-751	26	10	(	(	PUNCT
hjic-751	26	11	c44h26n4o12s4na4·12h2o	c44h26n4o12s4na4·12h2o	NOUN
hjic-751	26	12	=	=	SYM
hjic-751	26	13	na4h2tspp·12h2o	na4h2tspp·12h2o	NOUN
hjic-751	26	14	)	)	PUNCT
hjic-751	26	15	(	(	PUNCT
hjic-751	26	16	sigma	sigma	PROPN
hjic-751	26	17	–	–	PUNCT
hjic-751	26	18	aldrich	aldrich	NOUN
hjic-751	26	19	)	)	PUNCT
hjic-751	26	20	and	and	CCONJ
hjic-751	26	21	simple	simple	ADJ
hjic-751	26	22	metal	metal	NOUN
hjic-751	26	23	salts	salt	NOUN
hjic-751	26	24	such	such	ADJ
hjic-751	26	25	as	as	ADP
hjic-751	26	26	nitrate	nitrate	NOUN
hjic-751	26	27	,	,	PUNCT
hjic-751	26	28	sulfate	sulfate	NOUN
hjic-751	26	29	,	,	PUNCT
hjic-751	26	30	chloride	chloride	NOUN
hjic-751	26	31	or	or	CCONJ
hjic-751	26	32	perchlorate	perchlorate	NOUN
hjic-751	26	33	were	be	AUX
hjic-751	26	34	used	use	VERB
hjic-751	26	35	for	for	ADP
hjic-751	26	36	the	the	DET
hjic-751	26	37	experiments	experiment	NOUN
hjic-751	26	38	.	.	PUNCT
hjic-751	27	1	the	the	DET
hjic-751	27	2	solvent	solvent	NOUN
hjic-751	27	3	was	be	AUX
hjic-751	27	4	double	double	ADJ
hjic-751	27	5	-	-	PUNCT
hjic-751	27	6	distilled	distil	VERB
hjic-751	27	7	water	water	NOUN
hjic-751	27	8	purified	purify	VERB
hjic-751	27	9	with	with	ADP
hjic-751	27	10	a	a	DET
hjic-751	27	11	millipore	millipore	PROPN
hjic-751	27	12	milli	milli	ADJ
hjic-751	27	13	-	-	PUNCT
hjic-751	27	14	q	q	NOUN
hjic-751	27	15	system	system	NOUN
hjic-751	27	16	.	.	PUNCT
hjic-751	28	1	the	the	DET
hjic-751	28	2	ph	ph	NOUN
hjic-751	28	3	of	of	ADP
hjic-751	28	4	the	the	DET
hjic-751	28	5	majority	majority	NOUN
hjic-751	28	6	of	of	ADP
hjic-751	28	7	the	the	DET
hjic-751	28	8	metalloporphyrin	metalloporphyrin	NOUN
hjic-751	28	9	solutions	solution	NOUN
hjic-751	28	10	was	be	AUX
hjic-751	28	11	adjusted	adjust	VERB
hjic-751	28	12	to	to	ADP
hjic-751	28	13	8	8	NUM
hjic-751	28	14	by	by	ADP
hjic-751	28	15	application	application	NOUN
hjic-751	28	16	of	of	ADP
hjic-751	28	17	a	a	DET
hjic-751	28	18	borate	borate	NOUN
hjic-751	28	19	buffer	buffer	NOUN
hjic-751	28	20	,	,	PUNCT
hjic-751	28	21	whilst	whilst	SCONJ
hjic-751	28	22	maintaining	maintain	VERB
hjic-751	28	23	the	the	DET
hjic-751	28	24	ionic	ionic	ADJ
hjic-751	28	25	strength	strength	NOUN
hjic-751	28	26	at	at	ADP
hjic-751	28	27	a	a	DET
hjic-751	28	28	constant	constant	ADJ
hjic-751	28	29	value	value	NOUN
hjic-751	28	30	of	of	ADP
hjic-751	28	31	0.01	0.01	NUM
hjic-751	28	32	m.	m.	NOUN
hjic-751	28	33	in	in	ADP
hjic-751	28	34	a	a	DET
hjic-751	28	35	few	few	ADJ
hjic-751	28	36	cases	case	NOUN
hjic-751	28	37	,	,	PUNCT
hjic-751	28	38	the	the	DET
hjic-751	28	39	ph	ph	NOUN
hjic-751	28	40	was	be	AUX
hjic-751	28	41	regulated	regulate	VERB
hjic-751	28	42	to	to	ADP
hjic-751	28	43	6	6	NUM
hjic-751	28	44	,	,	PUNCT
hjic-751	28	45	and	and	CCONJ
hjic-751	28	46	the	the	DET
hjic-751	28	47	ionic	ionic	ADJ
hjic-751	28	48	strength	strength	NOUN
hjic-751	28	49	to	to	ADP
hjic-751	28	50	1	1	NUM
hjic-751	28	51	m	m	NOUN
hjic-751	28	52	,	,	PUNCT
hjic-751	28	53	by	by	ADP
hjic-751	28	54	an	an	DET
hjic-751	28	55	acetate	acetate	NOUN
hjic-751	28	56	buffer	buffer	NOUN
hjic-751	28	57	,	,	PUNCT
hjic-751	28	58	to	to	PART
hjic-751	28	59	hinder	hinder	VERB
hjic-751	28	60	hydrolysis	hydrolysis	NOUN
hjic-751	28	61	.	.	PUNCT
hjic-751	29	1	the	the	DET
hjic-751	29	2	absorption	absorption	NOUN
hjic-751	29	3	spectra	spectra	NOUN
hjic-751	29	4	were	be	AUX
hjic-751	29	5	recorded	record	VERB
hjic-751	29	6	and	and	CCONJ
hjic-751	29	7	the	the	DET
hjic-751	29	8	spectrophotometric	spectrophotometric	ADJ
hjic-751	29	9	titrations	titration	NOUN
hjic-751	29	10	were	be	AUX
hjic-751	29	11	monitored	monitor	VERB
hjic-751	29	12	by	by	ADP
hjic-751	29	13	using	use	VERB
hjic-751	29	14	a	a	DET
hjic-751	29	15	specord	specord	NOUN
hjic-751	29	16	s-100	s-100	NOUN
hjic-751	29	17	or	or	CCONJ
hjic-751	29	18	a	a	DET
hjic-751	29	19	specord	specord	NOUN
hjic-751	29	20	s-600	s-600	PRON
hjic-751	29	21	diode	diode	NOUN
hjic-751	29	22	array	array	NOUN
hjic-751	29	23	spectrophotometer	spectrophotometer	NOUN
hjic-751	29	24	.	.	PUNCT
hjic-751	30	1	for	for	ADP
hjic-751	30	2	the	the	DET
hjic-751	30	3	measurement	measurement	NOUN
hjic-751	30	4	of	of	ADP
hjic-751	30	5	fluorescence	fluorescence	PROPN
hjic-751	30	6	spectra	spectra	PROPN
hjic-751	30	7	,	,	PUNCT
hjic-751	30	8	a	a	DET
hjic-751	30	9	perkin	perkin	PROPN
hjic-751	30	10	elmer	elmer	PROPN
hjic-751	30	11	ls-50b	ls-50b	PROPN
hjic-751	30	12	or	or	CCONJ
hjic-751	30	13	a	a	DET
hjic-751	30	14	horiba	horiba	PROPN
hjic-751	30	15	jobin	jobin	PROPN
hjic-751	30	16	yvon	yvon	PROPN
hjic-751	30	17	fluoromax-4	fluoromax-4	PROPN
hjic-751	30	18	spectrofluorometer	spectrofluorometer	NOUN
hjic-751	30	19	was	be	AUX
hjic-751	30	20	applied	apply	VERB
hjic-751	30	21	.	.	PUNCT
hjic-751	31	1	the	the	DET
hjic-751	31	2	latter	latter	ADJ
hjic-751	31	3	piece	piece	NOUN
hjic-751	31	4	of	of	ADP
hjic-751	31	5	equipment	equipment	NOUN
hjic-751	31	6	supplemented	supplement	VERB
hjic-751	31	7	with	with	ADP
hjic-751	31	8	a	a	DET
hjic-751	31	9	time	time	NOUN
hjic-751	31	10	-	-	PUNCT
hjic-751	31	11	correlated	correlate	VERB
hjic-751	31	12	single	single	ADJ
hjic-751	31	13	photon	photon	NOUN
hjic-751	31	14	counting	counting	NOUN
hjic-751	31	15	(	(	PUNCT
hjic-751	31	16	tcspc	tcspc	NOUN
hjic-751	31	17	)	)	PUNCT
hjic-751	31	18	accessory	accessory	NOUN
hjic-751	31	19	was	be	AUX
hjic-751	31	20	utilized	utilize	VERB
hjic-751	31	21	to	to	PART
hjic-751	31	22	determine	determine	VERB
hjic-751	31	23	fluorescence	fluorescence	NOUN
hjic-751	31	24	lifetimes	lifetime	NOUN
hjic-751	31	25	,	,	PUNCT
hjic-751	31	26	too	too	ADV
hjic-751	31	27	.	.	PUNCT
hjic-751	32	1	uv	uv	NOUN
hjic-751	32	2	-	-	PUNCT
hjic-751	32	3	vis	vis	X
hjic-751	32	4	spectrophotometric	spectrophotometric	ADJ
hjic-751	32	5	data	datum	NOUN
hjic-751	32	6	(	(	PUNCT
hjic-751	32	7	molar	molar	ADJ
hjic-751	32	8	absorption	absorption	NOUN
hjic-751	32	9	,	,	PUNCT
hjic-751	32	10	fluorescence	fluorescence	ADJ
hjic-751	32	11	quantum	quantum	NOUN
hjic-751	32	12	yields	yield	NOUN
hjic-751	32	13	and	and	CCONJ
hjic-751	32	14	lifetimes	lifetime	NOUN
hjic-751	32	15	)	)	PUNCT
hjic-751	32	16	of	of	ADP
hjic-751	32	17	the	the	DET
hjic-751	32	18	free	free	ADJ
hjic-751	32	19	-	-	PUNCT
hjic-751	32	20	base	base	NOUN
hjic-751	32	21	porphyrin	porphyrin	NOUN
hjic-751	32	22	were	be	AUX
hjic-751	32	23	used	use	VERB
hjic-751	32	24	as	as	ADP
hjic-751	32	25	references	reference	NOUN
hjic-751	32	26	for	for	ADP
hjic-751	32	27	the	the	DET
hjic-751	32	28	determination	determination	NOUN
hjic-751	32	29	of	of	ADP
hjic-751	32	30	those	those	PRON
hjic-751	32	31	of	of	ADP
hjic-751	32	32	metalloporphyrin	metalloporphyrin	NOUN
hjic-751	32	33	complexes	complex	NOUN
hjic-751	32	34	[	[	X
hjic-751	32	35	1	1	NUM
hjic-751	32	36	]	]	PUNCT
hjic-751	32	37	.	.	PUNCT
hjic-751	33	1	for	for	ADP
hjic-751	33	2	the	the	DET
hjic-751	33	3	determination	determination	NOUN
hjic-751	33	4	of	of	ADP
hjic-751	33	5	photochemical	photochemical	ADJ
hjic-751	33	6	properties	property	NOUN
hjic-751	33	7	via	via	ADP
hjic-751	33	8	continuous	continuous	ADJ
hjic-751	33	9	irradiations	irradiation	NOUN
hjic-751	33	10	,	,	PUNCT
hjic-751	33	11	a	a	DET
hjic-751	33	12	piece	piece	NOUN
hjic-751	33	13	of	of	ADP
hjic-751	33	14	amko	amko	NOUN
hjic-751	33	15	lti	lti	PROPN
hjic-751	33	16	photolysis	photolysis	NOUN
hjic-751	33	17	equipment	equipment	NOUN
hjic-751	33	18	(	(	PUNCT
hjic-751	33	19	containing	contain	VERB
hjic-751	33	20	a	a	DET
hjic-751	33	21	200w	200w	PROPN
hjic-751	33	22	xe	xe	PROPN
hjic-751	33	23	–	–	PUNCT
hjic-751	33	24	hg	hg	NOUN
hjic-751	33	25	lamp	lamp	NOUN
hjic-751	33	26	and	and	CCONJ
hjic-751	33	27	a	a	DET
hjic-751	33	28	monochromator	monochromator	NOUN
hjic-751	33	29	)	)	PUNCT
hjic-751	33	30	was	be	AUX
hjic-751	33	31	applied	apply	VERB
hjic-751	33	32	.	.	PUNCT
hjic-751	34	1	for	for	ADP
hjic-751	34	2	the	the	DET
hjic-751	34	3	electronic	electronic	ADJ
hjic-751	34	4	structural	structural	ADJ
hjic-751	34	5	calculations	calculation	NOUN
hjic-751	34	6	,	,	PUNCT
hjic-751	34	7	the	the	DET
hjic-751	34	8	b3lyp	b3lyp	NUM
hjic-751	34	9	density	density	NOUN
hjic-751	34	10	functional	functional	ADJ
hjic-751	34	11	theory	theory	NOUN
hjic-751	34	12	(	(	PUNCT
hjic-751	34	13	dft	dft	NOUN
hjic-751	34	14	)	)	PUNCT
hjic-751	34	15	method	method	NOUN
hjic-751	34	16	and	and	CCONJ
hjic-751	34	17	the	the	DET
hjic-751	34	18	lanl2dz	lanl2dz	NOUN
hjic-751	34	19	basis	basis	NOUN
hjic-751	34	20	set	set	NOUN
hjic-751	34	21	were	be	AUX
hjic-751	34	22	used	use	VERB
hjic-751	34	23	.	.	PUNCT
hjic-751	35	1	on	on	ADP
hjic-751	35	2	the	the	DET
hjic-751	35	3	basis	basis	NOUN
hjic-751	35	4	of	of	ADP
hjic-751	35	5	our	our	PRON
hjic-751	35	6	earlier	early	ADJ
hjic-751	35	7	quantum	quantum	ADJ
hjic-751	35	8	chemistry	chemistry	NOUN
hjic-751	35	9	experiences	experience	NOUN
hjic-751	35	10	,	,	PUNCT
hjic-751	35	11	the	the	DET
hjic-751	35	12	sulfonatophenyl	sulfonatophenyl	NOUN
hjic-751	35	13	substituents	substituent	NOUN
hjic-751	35	14	exhibit	exhibit	VERB
hjic-751	35	15	negligible	negligible	ADJ
hjic-751	35	16	effects	effect	NOUN
hjic-751	35	17	on	on	ADP
hjic-751	35	18	the	the	DET
hjic-751	35	19	coordination	coordination	NOUN
hjic-751	35	20	of	of	ADP
hjic-751	35	21	the	the	DET
hjic-751	35	22	metal	metal	NOUN
hjic-751	35	23	center	center	NOUN
hjic-751	35	24	in	in	ADP
hjic-751	35	25	the	the	DET
hjic-751	35	26	cavity	cavity	NOUN
hjic-751	35	27	;	;	PUNCT
hjic-751	35	28	thus	thus	ADV
hjic-751	35	29	,	,	PUNCT
hjic-751	35	30	the	the	DET
hjic-751	35	31	anionic	anionic	ADJ
hjic-751	35	32	porphyrin	porphyrin	NOUN
hjic-751	35	33	(	(	PUNCT
hjic-751	35	34	h2tspp4−	h2tspp4−	PROPN
hjic-751	35	35	)	)	PUNCT
hjic-751	35	36	can	can	AUX
hjic-751	35	37	be	be	AUX
hjic-751	35	38	modeled	model	VERB
hjic-751	35	39	on	on	ADP
hjic-751	35	40	the	the	DET
hjic-751	35	41	unsubstituted	unsubstituted	ADJ
hjic-751	35	42	porphin	porphin	NOUN
hjic-751	35	43	(	(	PUNCT
hjic-751	35	44	h2p	h2p	PROPN
hjic-751	35	45	)	)	PUNCT
hjic-751	36	1	[	[	X
hjic-751	36	2	4	4	NUM
hjic-751	36	3	,	,	PUNCT
hjic-751	36	4	10	10	NUM
hjic-751	36	5	]	]	PUNCT
hjic-751	36	6	.	.	PUNCT
hjic-751	37	1	3	3	X
hjic-751	37	2	.	.	NOUN
hjic-751	37	3	results	result	NOUN
hjic-751	37	4	and	and	CCONJ
hjic-751	37	5	discussion	discussion	NOUN
hjic-751	37	6	3.1	3.1	NUM
hjic-751	37	7	.	.	PUNCT
hjic-751	38	1	uv	uv	NOUN
hjic-751	38	2	-	-	PUNCT
hjic-751	38	3	vis	vis	X
hjic-751	38	4	spectrophotometry	spectrophotometry	NOUN
hjic-751	38	5	porphyrins	porphyrin	NOUN
hjic-751	38	6	and	and	CCONJ
hjic-751	38	7	their	their	PRON
hjic-751	38	8	derivatives	derivative	NOUN
hjic-751	38	9	belong	belong	VERB
hjic-751	38	10	to	to	ADP
hjic-751	38	11	the	the	DET
hjic-751	38	12	strongest	strong	ADJ
hjic-751	38	13	light	light	ADJ
hjic-751	38	14	-	-	PUNCT
hjic-751	38	15	absorbing	absorb	VERB
hjic-751	38	16	materials	material	NOUN
hjic-751	38	17	(	(	PUNCT
hjic-751	38	18	both	both	CCONJ
hjic-751	38	19	natural	natural	ADJ
hjic-751	38	20	and	and	CCONJ
hjic-751	38	21	artificial	artificial	ADJ
hjic-751	38	22	)	)	PUNCT
hjic-751	38	23	,	,	PUNCT
hjic-751	38	24	therefore	therefore	ADV
hjic-751	38	25	,	,	PUNCT
hjic-751	38	26	ultraviolet	ultraviolet	ADJ
hjic-751	38	27	-	-	PUNCT
hjic-751	38	28	visible	visible	ADJ
hjic-751	38	29	spectrophotometry	spectrophotometry	NOUN
hjic-751	38	30	is	be	AUX
hjic-751	38	31	one	one	NUM
hjic-751	38	32	of	of	ADP
hjic-751	38	33	the	the	DET
hjic-751	38	34	most	most	ADV
hjic-751	38	35	fundamental	fundamental	ADJ
hjic-751	38	36	,	,	PUNCT
hjic-751	38	37	in	in	ADP
hjic-751	38	38	addition	addition	NOUN
hjic-751	38	39	,	,	PUNCT
hjic-751	38	40	most	most	ADV
hjic-751	38	41	informative	informative	ADJ
hjic-751	38	42	spectroscopic	spectroscopic	ADJ
hjic-751	38	43	techniques	technique	NOUN
hjic-751	38	44	in	in	ADP
hjic-751	38	45	porphyrin	porphyrin	NOUN
hjic-751	38	46	chemistry	chemistry	NOUN
hjic-751	38	47	.	.	PUNCT
hjic-751	39	1	they	they	PRON
hjic-751	39	2	possess	possess	VERB
hjic-751	39	3	two	two	NUM
hjic-751	39	4	ππ	ππ	NOUN
hjic-751	39	5	*	*	ADJ
hjic-751	39	6	electronic	electronic	ADJ
hjic-751	39	7	transitions	transition	NOUN
hjic-751	39	8	in	in	ADP
hjic-751	39	9	the	the	DET
hjic-751	39	10	visible	visible	ADJ
hjic-751	39	11	range	range	NOUN
hjic-751	39	12	of	of	ADP
hjic-751	39	13	the	the	DET
hjic-751	39	14	electromagnetic	electromagnetic	ADJ
hjic-751	39	15	spectrum	spectrum	NOUN
hjic-751	39	16	:	:	PUNCT
hjic-751	39	17	bor	bor	PROPN
hjic-751	39	18	soret	soret	PROPN
hjic-751	39	19	band	band	NOUN
hjic-751	39	20	at	at	ADP
hjic-751	39	21	about	about	ADV
hjic-751	39	22	350	350	NUM
hjic-751	39	23	-	-	SYM
hjic-751	39	24	500	500	NUM
hjic-751	39	25	nm	nm	NOUN
hjic-751	39	26	,	,	PUNCT
hjic-751	39	27	usually	usually	ADV
hjic-751	39	28	with	with	ADP
hjic-751	39	29	a	a	DET
hjic-751	39	30	molar	molar	ADJ
hjic-751	39	31	absorbance	absorbance	NOUN
hjic-751	39	32	of	of	ADP
hjic-751	39	33	105	105	NUM
hjic-751	39	34	m-1cm-1	m-1cm-1	PROPN
hjic-751	39	35	(	(	PUNCT
hjic-751	39	36	fig.2	fig.2	PROPN
hjic-751	39	37	)	)	PUNCT
hjic-751	39	38	,	,	PUNCT
hjic-751	39	39	and	and	CCONJ
hjic-751	39	40	q	q	NOUN
hjic-751	39	41	bands	band	NOUN
hjic-751	39	42	at	at	ADP
hjic-751	39	43	500	500	NUM
hjic-751	39	44	-	-	SYM
hjic-751	39	45	750	750	NUM
hjic-751	39	46	nm	nm	NOUN
hjic-751	39	47	generally	generally	ADV
hjic-751	39	48	with	with	ADP
hjic-751	39	49	intensities	intensity	NOUN
hjic-751	39	50	of	of	ADP
hjic-751	39	51	one	one	NUM
hjic-751	39	52	order	order	NOUN
hjic-751	39	53	of	of	ADP
hjic-751	39	54	magnitude	magnitude	NOUN
hjic-751	39	55	less	less	ADJ
hjic-751	39	56	.	.	PUNCT
hjic-751	40	1	these	these	DET
hjic-751	40	2	latter	latter	ADJ
hjic-751	40	3	bands	band	NOUN
hjic-751	40	4	in	in	ADP
hjic-751	40	5	free	free	ADJ
hjic-751	40	6	-	-	PUNCT
hjic-751	40	7	base	base	NOUN
hjic-751	40	8	ligands	ligand	NOUN
hjic-751	40	9	split	split	VERB
hjic-751	40	10	due	due	ADP
hjic-751	40	11	to	to	ADP
hjic-751	40	12	the	the	DET
hjic-751	40	13	presence	presence	NOUN
hjic-751	40	14	of	of	ADP
hjic-751	40	15	protons	proton	NOUN
hjic-751	40	16	on	on	ADP
hjic-751	40	17	two	two	NUM
hjic-751	40	18	diagonally	diagonally	ADV
hjic-751	40	19	situated	situate	VERB
hjic-751	40	20	pyrrolic	pyrrolic	ADJ
hjic-751	40	21	nitrogens	nitrogen	NOUN
hjic-751	40	22	,	,	PUNCT
hjic-751	40	23	to	to	PART
hjic-751	40	24	be	be	AUX
hjic-751	40	25	more	more	ADV
hjic-751	40	26	precise	precise	ADJ
hjic-751	40	27	,	,	PUNCT
hjic-751	40	28	as	as	ADP
hjic-751	40	29	a	a	DET
hjic-751	40	30	result	result	NOUN
hjic-751	40	31	of	of	ADP
hjic-751	40	32	the	the	DET
hjic-751	40	33	reduced	reduce	VERB
hjic-751	40	34	symmetry	symmetry	NOUN
hjic-751	40	35	(	(	PUNCT
hjic-751	40	36	because	because	SCONJ
hjic-751	40	37	of	of	ADP
hjic-751	40	38	the	the	DET
hjic-751	40	39	disappearance	disappearance	NOUN
hjic-751	40	40	of	of	ADP
hjic-751	40	41	the	the	DET
hjic-751	40	42	four	four	NUM
hjic-751	40	43	-	-	ADJ
hjic-751	40	44	fold	fold	ADJ
hjic-751	40	45	rotation	rotation	NOUN
hjic-751	40	46	axis	axis	NOUN
hjic-751	40	47	)	)	PUNCT
hjic-751	40	48	compared	compare	VERB
hjic-751	40	49	to	to	ADP
hjic-751	40	50	the	the	DET
hjic-751	40	51	metallated	metallated	ADJ
hjic-751	40	52	or	or	CCONJ
hjic-751	40	53	deprotonated	deprotonated	ADJ
hjic-751	40	54	forms	form	NOUN
hjic-751	40	55	.	.	PUNCT
hjic-751	41	1	this	this	DET
hjic-751	41	2	split	split	NOUN
hjic-751	41	3	is	be	AUX
hjic-751	41	4	not	not	PART
hjic-751	41	5	detectable	detectable	ADJ
hjic-751	41	6	in	in	ADP
hjic-751	41	7	the	the	DET
hjic-751	41	8	soret	soret	NOUN
hjic-751	41	9	range	range	NOUN
hjic-751	41	10	,	,	PUNCT
hjic-751	41	11	hence	hence	ADV
hjic-751	41	12	,	,	PUNCT
hjic-751	41	13	these	these	DET
hjic-751	41	14	two	two	NUM
hjic-751	41	15	types	type	NOUN
hjic-751	41	16	of	of	ADP
hjic-751	41	17	bands	band	NOUN
hjic-751	41	18	in	in	ADP
hjic-751	41	19	the	the	DET
hjic-751	41	20	visible	visible	ADJ
hjic-751	41	21	region	region	NOUN
hjic-751	41	22	are	be	AUX
hjic-751	41	23	remarkably	remarkably	ADV
hjic-751	41	24	different	different	ADJ
hjic-751	41	25	[	[	X
hjic-751	41	26	1	1	NUM
hjic-751	41	27	]	]	PUNCT
hjic-751	41	28	.	.	PUNCT
hjic-751	42	1	in	in	ADP
hjic-751	42	2	the	the	DET
hjic-751	42	3	soret	soret	PROPN
hjic-751	42	4	region	region	NOUN
hjic-751	42	5	,	,	PUNCT
hjic-751	42	6	compared	compare	VERB
hjic-751	42	7	to	to	ADP
hjic-751	42	8	the	the	DET
hjic-751	42	9	corresponding	corresponding	ADJ
hjic-751	42	10	free	free	ADJ
hjic-751	42	11	-	-	PUNCT
hjic-751	42	12	base	base	NOUN
hjic-751	42	13	ligands	ligand	NOUN
hjic-751	42	14	,	,	PUNCT
hjic-751	42	15	the	the	DET
hjic-751	42	16	typical	typical	ADJ
hjic-751	42	17	in	in	ADP
hjic-751	42	18	-	-	PUNCT
hjic-751	42	19	plane	plane	NOUN
hjic-751	42	20	metalloporphyrins	metalloporphyrin	NOUN
hjic-751	42	21	(	(	PUNCT
hjic-751	42	22	e.g.	e.g.	ADV
hjic-751	42	23	fe3	fe3	VERB
hjic-751	42	24	+	+	PROPN
hjic-751	42	25	,	,	PUNCT
hjic-751	42	26	au3	au3	PROPN
hjic-751	42	27	+	+	NOUN
hjic-751	42	28	,	,	PUNCT
hjic-751	42	29	cu2	cu2	NOUN
hjic-751	42	30	+	+	PROPN
hjic-751	42	31	,	,	PUNCT
hjic-751	42	32	pd2	pd2	NOUN
hjic-751	42	33	+	+	NOUN
hjic-751	42	34	)	)	PUNCT
hjic-751	42	35	exhibit	exhibit	NOUN
hjic-751	42	36	blueshifts	blueshift	NOUN
hjic-751	42	37	because	because	SCONJ
hjic-751	42	38	the	the	DET
hjic-751	42	39	atomic	atomic	ADJ
hjic-751	42	40	orbitals	orbital	NOUN
hjic-751	42	41	of	of	ADP
hjic-751	42	42	their	their	PRON
hjic-751	42	43	metal	metal	NOUN
hjic-751	42	44	centers	center	NOUN
hjic-751	42	45	which	which	PRON
hjic-751	42	46	are	be	AUX
hjic-751	42	47	covalently	covalently	ADV
hjic-751	42	48	bonded	bond	VERB
hjic-751	42	49	in	in	ADP
hjic-751	42	50	the	the	DET
hjic-751	42	51	plane	plane	NOUN
hjic-751	42	52	can	can	AUX
hjic-751	42	53	overlap	overlap	VERB
hjic-751	42	54	more	more	ADV
hjic-751	42	55	strongly	strongly	ADV
hjic-751	42	56	with	with	ADP
hjic-751	42	57	the	the	DET
hjic-751	42	58	highest	high	ADJ
hjic-751	42	59	occupied	occupy	VERB
hjic-751	42	60	molecular	molecular	ADJ
hjic-751	42	61	orbitals	orbital	NOUN
hjic-751	42	62	(	(	PUNCT
hjic-751	42	63	homo	homo	NOUN
hjic-751	42	64	)	)	PUNCT
hjic-751	42	65	of	of	ADP
hjic-751	42	66	the	the	DET
hjic-751	42	67	ligand	ligand	NOUN
hjic-751	42	68	,	,	PUNCT
hjic-751	42	69	resulting	result	VERB
hjic-751	42	70	in	in	ADP
hjic-751	42	71	a	a	DET
hjic-751	42	72	stronger	strong	ADJ
hjic-751	42	73	reduction	reduction	NOUN
hjic-751	42	74	in	in	ADP
hjic-751	42	75	energy	energy	NOUN
hjic-751	42	76	;	;	PUNCT
hjic-751	42	77	whereas	whereas	SCONJ
hjic-751	42	78	the	the	DET
hjic-751	42	79	lowest	low	ADJ
hjic-751	42	80	unoccupied	unoccupied	ADJ
hjic-751	42	81	molecular	molecular	ADJ
hjic-751	42	82	orbitals	orbital	NOUN
hjic-751	42	83	(	(	PUNCT
hjic-751	42	84	lumo	lumo	NOUN
hjic-751	42	85	)	)	PUNCT
hjic-751	42	86	do	do	AUX
hjic-751	42	87	not	not	PART
hjic-751	42	88	change	change	VERB
hjic-751	42	89	.	.	PUNCT
hjic-751	43	1	thus	thus	ADV
hjic-751	43	2	,	,	PUNCT
hjic-751	43	3	the	the	DET
hjic-751	43	4	energy	energy	NOUN
hjic-751	43	5	gaps	gap	NOUN
hjic-751	43	6	between	between	ADP
hjic-751	43	7	the	the	DET
hjic-751	43	8	excited	excited	ADJ
hjic-751	43	9	and	and	CCONJ
hjic-751	43	10	ground	ground	NOUN
hjic-751	43	11	states	state	NOUN
hjic-751	43	12	become	become	VERB
hjic-751	43	13	greater	great	ADJ
hjic-751	43	14	.	.	PUNCT
hjic-751	44	1	in	in	ADP
hjic-751	44	2	the	the	DET
hjic-751	44	3	oop	oop	NOUN
hjic-751	44	4	complexes	complex	NOUN
hjic-751	44	5	,	,	PUNCT
hjic-751	44	6	the	the	DET
hjic-751	44	7	atomic	atomic	ADJ
hjic-751	44	8	orbitals	orbital	NOUN
hjic-751	44	9	of	of	ADP
hjic-751	44	10	the	the	DET
hjic-751	44	11	more	more	ADV
hjic-751	44	12	weakly	weakly	ADJ
hjic-751	44	13	bonded	bond	VERB
hjic-751	44	14	metal	metal	NOUN
hjic-751	44	15	ions	ion	NOUN
hjic-751	44	16	(	(	PUNCT
hjic-751	44	17	e.g.	e.g.	ADV
hjic-751	44	18	cd2	cd2	VERB
hjic-751	44	19	+	+	PROPN
hjic-751	44	20	,	,	PUNCT
hjic-751	44	21	hg2	hg2	PROPN
hjic-751	44	22	+	+	PROPN
hjic-751	44	23	,	,	PUNCT
hjic-751	44	24	tl3	tl3	PROPN
hjic-751	44	25	+	+	NOUN
hjic-751	44	26	)	)	PUNCT
hjic-751	44	27	may	may	AUX
hjic-751	44	28	slightly	slightly	ADV
hjic-751	44	29	affect	affect	VERB
hjic-751	44	30	the	the	DET
hjic-751	44	31	unoccupied	unoccupied	ADJ
hjic-751	44	32	mos	mos	NOUN
hjic-751	44	33	and	and	CCONJ
hjic-751	44	34	to	to	ADP
hjic-751	44	35	a	a	DET
hjic-751	44	36	lesser	less	ADJ
hjic-751	44	37	extent	extent	NOUN
hjic-751	44	38	the	the	DET
hjic-751	44	39	occupied	occupy	VERB
hjic-751	44	40	ones	one	NOUN
hjic-751	44	41	,	,	PUNCT
hjic-751	44	42	leading	lead	VERB
hjic-751	44	43	to	to	ADP
hjic-751	44	44	a	a	DET
hjic-751	44	45	reduction	reduction	NOUN
hjic-751	44	46	of	of	ADP
hjic-751	44	47	the	the	DET
hjic-751	44	48	energy	energy	NOUN
hjic-751	44	49	gaps	gap	NOUN
hjic-751	44	50	,	,	PUNCT
hjic-751	44	51	i.e.	i.e.	X
hjic-751	44	52	an	an	DET
hjic-751	44	53	increase	increase	NOUN
hjic-751	44	54	in	in	ADP
hjic-751	44	55	the	the	DET
hjic-751	44	56	corresponding	correspond	VERB
hjic-751	44	57	wavelengths	wavelength	NOUN
hjic-751	44	58	(	(	PUNCT
hjic-751	44	59	scheme	scheme	NOUN
hjic-751	44	60	1	1	NUM
hjic-751	44	61	)	)	PUNCT
hjic-751	45	1	[	[	X
hjic-751	45	2	1	1	NUM
hjic-751	45	3	,	,	PUNCT
hjic-751	45	4	9	9	NUM
hjic-751	45	5	]	]	PUNCT
hjic-751	45	6	.	.	PUNCT
hjic-751	46	1	a	a	DET
hjic-751	46	2	)	)	PUNCT
hjic-751	46	3	b	b	NOUN
hjic-751	46	4	)	)	PUNCT
hjic-751	46	5	figure	figure	NOUN
hjic-751	46	6	1	1	NUM
hjic-751	46	7	.	.	PUNCT
hjic-751	46	8	structure	structure	NOUN
hjic-751	46	9	of	of	ADP
hjic-751	46	10	an	an	DET
hjic-751	46	11	in	in	ADP
hjic-751	46	12	-	-	PUNCT
hjic-751	46	13	plane	plane	NOUN
hjic-751	46	14	metalloporphyrin	metalloporphyrin	NOUN
hjic-751	46	15	{	{	PUNCT
hjic-751	46	16	mtspp	mtspp	NOUN
hjic-751	46	17	=	=	NOUN
hjic-751	46	18	metallo-5,10,15,20	metallo-5,10,15,20	NOUN
hjic-751	46	19	-	-	NOUN
hjic-751	46	20	tetrakis(4sulfonatophenyl)porphyrin	tetrakis(4sulfonatophenyl)porphyrin	NOUN
hjic-751	46	21	}	}	PUNCT
hjic-751	46	22	(	(	PUNCT
hjic-751	46	23	a	a	NOUN
hjic-751	46	24	)	)	PUNCT
hjic-751	46	25	;	;	PUNCT
hjic-751	46	26	and	and	CCONJ
hjic-751	46	27	that	that	PRON
hjic-751	46	28	of	of	ADP
hjic-751	46	29	an	an	DET
hjic-751	46	30	out	out	ADJ
hjic-751	46	31	-	-	PUNCT
hjic-751	46	32	of	of	ADP
hjic-751	46	33	-	-	PUNCT
hjic-751	46	34	plane	plane	NOUN
hjic-751	46	35	complex	complex	NOUN
hjic-751	46	36	(	(	PUNCT
hjic-751	46	37	b	b	NOUN
hjic-751	46	38	)	)	PUNCT
hjic-751	47	1	[	[	X
hjic-751	47	2	9	9	NUM
hjic-751	47	3	]	]	PUNCT
hjic-751	47	4	.	.	PUNCT
hjic-751	48	1	study	study	NOUN
hjic-751	48	2	of	of	ADP
hjic-751	48	3	the	the	DET
hjic-751	48	4	out	out	NOUN
hjic-751	48	5	-	-	PUNCT
hjic-751	48	6	of	of	ADP
hjic-751	48	7	-	-	PUNCT
hjic-751	48	8	plane	plane	NOUN
hjic-751	48	9	metalloporphyrins	metalloporphyrin	NOUN
hjic-751	48	10	45(1	45(1	NOUN
hjic-751	48	11	)	)	PUNCT
hjic-751	48	12	pp	pp	ADV
hjic-751	48	13	.	.	PUNCT
hjic-751	49	1	29–36	29–36	NUM
hjic-751	49	2	(	(	PUNCT
hjic-751	49	3	2017	2017	NUM
hjic-751	49	4	)	)	PUNCT
hjic-751	49	5	31	31	NUM
hjic-751	49	6	beside	beside	ADP
hjic-751	49	7	electronic	electronic	ADJ
hjic-751	49	8	factors	factor	NOUN
hjic-751	49	9	,	,	PUNCT
hjic-751	49	10	due	due	ADP
hjic-751	49	11	to	to	ADP
hjic-751	49	12	the	the	DET
hjic-751	49	13	rigidity	rigidity	NOUN
hjic-751	49	14	of	of	ADP
hjic-751	49	15	the	the	DET
hjic-751	49	16	porphyrins	porphyrin	NOUN
hjic-751	49	17	’	'	PUNCT
hjic-751	49	18	ringed	ringed	ADJ
hjic-751	49	19	structure	structure	NOUN
hjic-751	49	20	,	,	PUNCT
hjic-751	49	21	steric	steric	ADJ
hjic-751	49	22	effects	effect	NOUN
hjic-751	49	23	also	also	ADV
hjic-751	49	24	influence	influence	VERB
hjic-751	49	25	the	the	DET
hjic-751	49	26	spectra	spectra	NOUN
hjic-751	49	27	:	:	PUNCT
hjic-751	49	28	the	the	DET
hjic-751	49	29	redshift	redshift	NOUN
hjic-751	49	30	of	of	ADP
hjic-751	49	31	absorption	absorption	NOUN
hjic-751	49	32	bands	band	NOUN
hjic-751	49	33	is	be	AUX
hjic-751	49	34	one	one	NUM
hjic-751	49	35	of	of	ADP
hjic-751	49	36	the	the	DET
hjic-751	49	37	most	most	ADV
hjic-751	49	38	common	common	ADJ
hjic-751	49	39	spectroscopic	spectroscopic	ADJ
hjic-751	49	40	consequences	consequence	NOUN
hjic-751	49	41	of	of	ADP
hjic-751	49	42	the	the	DET
hjic-751	49	43	non	non	NOUN
hjic-751	49	44	-	-	NOUN
hjic-751	49	45	planarity	planarity	NOUN
hjic-751	49	46	of	of	ADP
hjic-751	49	47	porphyrin	porphyrin	NOUN
hjic-751	50	1	[	[	X
hjic-751	50	2	3	3	NUM
hjic-751	50	3	]	]	PUNCT
hjic-751	50	4	.	.	PUNCT
hjic-751	51	1	octabrominated	octabrominated	ADJ
hjic-751	51	2	freebase	freebase	NOUN
hjic-751	51	3	porphyrin	porphyrin	NOUN
hjic-751	51	4	,	,	PUNCT
hjic-751	51	5	h2tsppbr8	h2tsppbr8	PROPN
hjic-751	51	6	4	4	NUM
hjic-751	51	7	–	–	PUNCT
hjic-751	51	8	,	,	PUNCT
hjic-751	51	9	was	be	AUX
hjic-751	51	10	applied	apply	VERB
hjic-751	51	11	to	to	PART
hjic-751	51	12	investigate	investigate	VERB
hjic-751	51	13	the	the	DET
hjic-751	51	14	spectrophotometric	spectrophotometric	ADJ
hjic-751	51	15	effects	effect	NOUN
hjic-751	51	16	of	of	ADP
hjic-751	51	17	the	the	DET
hjic-751	51	18	macrocycle	macrocycle	NOUN
hjic-751	51	19	’s	’s	PART
hjic-751	51	20	highly	highly	ADV
hjic-751	51	21	saddle	saddle	NOUN
hjic-751	51	22	-	-	PUNCT
hjic-751	51	23	distorted	distort	VERB
hjic-751	51	24	structure	structure	NOUN
hjic-751	51	25	(	(	PUNCT
hjic-751	51	26	fig.2	fig.2	PROPN
hjic-751	51	27	)	)	PUNCT
hjic-751	51	28	.	.	PUNCT
hjic-751	52	1	in	in	ADP
hjic-751	52	2	porphyrins	porphyrin	NOUN
hjic-751	52	3	with	with	ADP
hjic-751	52	4	aryl	aryl	NOUN
hjic-751	52	5	substituents	substituent	NOUN
hjic-751	52	6	,	,	PUNCT
hjic-751	52	7	this	this	DET
hjic-751	52	8	distortion	distortion	NOUN
hjic-751	52	9	can	can	AUX
hjic-751	52	10	lead	lead	VERB
hjic-751	52	11	to	to	ADP
hjic-751	52	12	the	the	DET
hjic-751	52	13	extension	extension	NOUN
hjic-751	52	14	of	of	ADP
hjic-751	52	15	delocalization	delocalization	NOUN
hjic-751	52	16	by	by	ADP
hjic-751	52	17	the	the	DET
hjic-751	52	18	twisting	twisting	NOUN
hjic-751	52	19	of	of	ADP
hjic-751	52	20	aryl	aryl	NOUN
hjic-751	52	21	substituents	substituent	NOUN
hjic-751	52	22	from	from	ADP
hjic-751	52	23	a	a	DET
hjic-751	52	24	nearly	nearly	ADV
hjic-751	52	25	perpendicular	perpendicular	ADJ
hjic-751	52	26	orientation	orientation	NOUN
hjic-751	52	27	closer	close	ADV
hjic-751	52	28	to	to	ADP
hjic-751	52	29	the	the	DET
hjic-751	52	30	porphyrin	porphyrin	NOUN
hjic-751	52	31	plane	plane	NOUN
hjic-751	52	32	(	(	PUNCT
hjic-751	52	33	fig.1	fig.1	PROPN
hjic-751	52	34	)	)	PUNCT
hjic-751	53	1	[	[	X
hjic-751	53	2	4	4	NUM
hjic-751	53	3	]	]	PUNCT
hjic-751	53	4	.	.	PUNCT
hjic-751	54	1	the	the	DET
hjic-751	54	2	larger	large	ADJ
hjic-751	54	3	,	,	PUNCT
hjic-751	54	4	post	post	ADJ
hjic-751	54	5	-	-	ADJ
hjic-751	54	6	transition	transition	ADJ
hjic-751	54	7	metal	metal	NOUN
hjic-751	54	8	ions	ion	NOUN
hjic-751	54	9	,	,	PUNCT
hjic-751	54	10	e.g.	e.g.	ADV
hjic-751	54	11	thallium(i	thallium(i	NOUN
hjic-751	54	12	)	)	PUNCT
hjic-751	54	13	,	,	PUNCT
hjic-751	54	14	lead(ii	lead(ii	NOUN
hjic-751	54	15	)	)	PUNCT
hjic-751	54	16	and	and	CCONJ
hjic-751	54	17	bismuth(iii	bismuth(iii	NOUN
hjic-751	54	18	)	)	PUNCT
hjic-751	54	19	ions	ion	NOUN
hjic-751	54	20	,	,	PUNCT
hjic-751	54	21	can	can	AUX
hjic-751	54	22	cause	cause	VERB
hjic-751	54	23	a	a	DET
hjic-751	54	24	similarly	similarly	ADV
hjic-751	54	25	large	large	ADJ
hjic-751	54	26	redshift	redshift	NOUN
hjic-751	54	27	of	of	ADP
hjic-751	54	28	the	the	DET
hjic-751	54	29	porphyrins	porphyrin	NOUN
hjic-751	54	30	’	'	PUNCT
hjic-751	54	31	absorption	absorption	NOUN
hjic-751	54	32	bands	band	NOUN
hjic-751	54	33	.	.	PUNCT
hjic-751	55	1	since	since	SCONJ
hjic-751	55	2	their	their	PRON
hjic-751	55	3	complexes	complex	NOUN
hjic-751	55	4	possess	possess	VERB
hjic-751	55	5	the	the	DET
hjic-751	55	6	most	most	ADV
hjic-751	55	7	highly	highly	ADV
hjic-751	55	8	dome	dome	NOUN
hjic-751	55	9	-	-	PUNCT
hjic-751	55	10	distorted	distort	VERB
hjic-751	55	11	structures	structure	NOUN
hjic-751	55	12	,	,	PUNCT
hjic-751	55	13	also	also	ADV
hjic-751	55	14	a	a	DET
hjic-751	55	15	ruffled	ruffle	VERB
hjic-751	55	16	-	-	PUNCT
hjic-751	55	17	like	like	ADJ
hjic-751	55	18	deformation	deformation	NOUN
hjic-751	55	19	of	of	ADP
hjic-751	55	20	the	the	DET
hjic-751	55	21	periphery	periphery	NOUN
hjic-751	55	22	superposes	superpose	NOUN
hjic-751	55	23	on	on	ADP
hjic-751	55	24	this	this	DET
hjic-751	55	25	high	high	ADJ
hjic-751	55	26	degree	degree	NOUN
hjic-751	55	27	of	of	ADP
hjic-751	55	28	doming	doming	NOUN
hjic-751	55	29	.	.	PUNCT
hjic-751	56	1	considering	consider	VERB
hjic-751	56	2	the	the	DET
hjic-751	56	3	spectral	spectral	ADJ
hjic-751	56	4	effects	effect	NOUN
hjic-751	56	5	(	(	PUNCT
hjic-751	56	6	bathochromic	bathochromic	ADJ
hjic-751	56	7	or	or	CCONJ
hjic-751	56	8	not	not	PART
hjic-751	56	9	quite	quite	ADV
hjic-751	56	10	exactly	exactly	ADV
hjic-751	56	11	hyperchromic	hyperchromic	ADJ
hjic-751	56	12	effects	effect	NOUN
hjic-751	56	13	)	)	PUNCT
hjic-751	56	14	,	,	PUNCT
hjic-751	56	15	the	the	DET
hjic-751	56	16	complexes	complex	NOUN
hjic-751	56	17	possessing	possess	VERB
hjic-751	56	18	such	such	ADJ
hjic-751	56	19	highly	highly	ADV
hjic-751	56	20	redshifted	redshifte	VERB
hjic-751	56	21	absorption	absorption	NOUN
hjic-751	56	22	bands	band	NOUN
hjic-751	56	23	used	use	VERB
hjic-751	56	24	to	to	PART
hjic-751	56	25	be	be	AUX
hjic-751	56	26	referred	refer	VERB
hjic-751	56	27	to	to	ADP
hjic-751	56	28	as	as	ADP
hjic-751	56	29	hyperporphyrins	hyperporphyrin	NOUN
hjic-751	56	30	;	;	PUNCT
hjic-751	56	31	depending	depend	VERB
hjic-751	56	32	on	on	ADP
hjic-751	56	33	the	the	DET
hjic-751	56	34	highest	high	ADJ
hjic-751	56	35	occupied	occupy	VERB
hjic-751	56	36	electron	electron	NOUN
hjic-751	56	37	subshell	subshell	NOUN
hjic-751	56	38	of	of	ADP
hjic-751	56	39	the	the	DET
hjic-751	56	40	metal	metal	NOUN
hjic-751	56	41	center	center	NOUN
hjic-751	56	42	,	,	PUNCT
hjic-751	56	43	por	por	NOUN
hjic-751	56	44	d	d	ADJ
hjic-751	56	45	-	-	PUNCT
hjic-751	56	46	type	type	NOUN
hjic-751	56	47	hyperporphyrins	hyperporphyrin	NOUN
hjic-751	56	48	.	.	PUNCT
hjic-751	57	1	previously	previously	ADV
hjic-751	57	2	in	in	ADP
hjic-751	57	3	terms	term	NOUN
hjic-751	57	4	of	of	ADP
hjic-751	57	5	this	this	DET
hjic-751	57	6	categorization	categorization	NOUN
hjic-751	57	7	of	of	ADP
hjic-751	57	8	metalloporphyrins	metalloporphyrin	NOUN
hjic-751	57	9	,	,	PUNCT
hjic-751	57	10	only	only	ADV
hjic-751	57	11	the	the	DET
hjic-751	57	12	electronic	electronic	ADJ
hjic-751	57	13	effects	effect	NOUN
hjic-751	57	14	of	of	ADP
hjic-751	57	15	the	the	DET
hjic-751	57	16	metal	metal	NOUN
hjic-751	57	17	ion	ion	NOUN
hjic-751	57	18	(	(	PUNCT
hjic-751	57	19	through	through	ADP
hjic-751	57	20	its	its	PRON
hjic-751	57	21	electron	electron	NOUN
hjic-751	57	22	configuration	configuration	NOUN
hjic-751	57	23	)	)	PUNCT
hjic-751	57	24	were	be	AUX
hjic-751	57	25	taken	take	VERB
hjic-751	57	26	into	into	ADP
hjic-751	57	27	consideration	consideration	NOUN
hjic-751	57	28	and	and	CCONJ
hjic-751	57	29	not	not	PART
hjic-751	57	30	steric	steric	ADJ
hjic-751	57	31	(	(	PUNCT
hjic-751	57	32	distorting	distort	VERB
hjic-751	57	33	)	)	PUNCT
hjic-751	57	34	effects	effect	NOUN
hjic-751	58	1	[	[	X
hjic-751	58	2	1	1	NUM
hjic-751	58	3	]	]	PUNCT
hjic-751	58	4	.	.	PUNCT
hjic-751	59	1	nevertheless	nevertheless	ADV
hjic-751	59	2	,	,	PUNCT
hjic-751	59	3	in	in	ADP
hjic-751	59	4	the	the	DET
hjic-751	59	5	typical	typical	ADJ
hjic-751	59	6	d	d	ADJ
hjic-751	59	7	-	-	PUNCT
hjic-751	59	8	type	type	NOUN
hjic-751	59	9	hyperporphyrins	hyperporphyrin	NOUN
hjic-751	59	10	,	,	PUNCT
hjic-751	59	11	e.g.	e.g.	ADV
hjic-751	59	12	the	the	DET
hjic-751	59	13	low	low	ADJ
hjic-751	59	14	-	-	PUNCT
hjic-751	59	15	spin	spin	NOUN
hjic-751	59	16	chromium(iii	chromium(iii	NOUN
hjic-751	59	17	)	)	PUNCT
hjic-751	59	18	,	,	PUNCT
hjic-751	59	19	manganese(iii	manganese(iii	NOUN
hjic-751	59	20	)	)	PUNCT
hjic-751	59	21	,	,	PUNCT
hjic-751	59	22	nickel(ii	nickel(ii	ADJ
hjic-751	59	23	)	)	PUNCT
hjic-751	59	24	and	and	CCONJ
hjic-751	59	25	cobalt(iii	cobalt(iii	NOUN
hjic-751	59	26	)	)	PUNCT
hjic-751	59	27	porphyrins	porphyrin	NOUN
hjic-751	59	28	,	,	PUNCT
hjic-751	59	29	the	the	DET
hjic-751	59	30	radius	radius	NOUN
hjic-751	59	31	of	of	ADP
hjic-751	59	32	the	the	DET
hjic-751	59	33	metal	metal	NOUN
hjic-751	59	34	center	center	NOUN
hjic-751	59	35	,	,	PUNCT
hjic-751	59	36	and	and	CCONJ
hjic-751	59	37	thus	thus	ADV
hjic-751	59	38	,	,	PUNCT
hjic-751	59	39	the	the	DET
hjic-751	59	40	metal	metal	NOUN
hjic-751	59	41	-	-	PUNCT
hjic-751	59	42	nitrogen	nitrogen	NOUN
hjic-751	59	43	bonds	bond	NOUN
hjic-751	59	44	are	be	AUX
hjic-751	59	45	too	too	ADV
hjic-751	59	46	short	short	ADJ
hjic-751	59	47	,	,	PUNCT
hjic-751	59	48	resulting	result	VERB
hjic-751	59	49	in	in	ADP
hjic-751	59	50	the	the	DET
hjic-751	59	51	contraction	contraction	NOUN
hjic-751	59	52	of	of	ADP
hjic-751	59	53	the	the	DET
hjic-751	59	54	coordination	coordination	NOUN
hjic-751	59	55	cavity	cavity	NOUN
hjic-751	59	56	,	,	PUNCT
hjic-751	59	57	along	along	ADP
hjic-751	59	58	with	with	ADP
hjic-751	59	59	the	the	DET
hjic-751	59	60	ruffled	ruffled	ADJ
hjic-751	59	61	deformation	deformation	NOUN
hjic-751	59	62	of	of	ADP
hjic-751	59	63	the	the	DET
hjic-751	59	64	macrocycle	macrocycle	NOUN
hjic-751	59	65	[	[	X
hjic-751	59	66	2	2	NUM
hjic-751	59	67	,	,	PUNCT
hjic-751	59	68	5	5	NUM
hjic-751	59	69	-	-	SYM
hjic-751	59	70	7	7	NUM
hjic-751	59	71	]	]	PUNCT
hjic-751	59	72	.	.	PUNCT
hjic-751	60	1	3.2	3.2	NUM
hjic-751	60	2	.	.	PUNCT
hjic-751	60	3	equilibrium	equilibrium	NOUN
hjic-751	60	4	and	and	CCONJ
hjic-751	60	5	kinetics	kinetic	NOUN
hjic-751	60	6	of	of	ADP
hjic-751	60	7	complex	complex	ADJ
hjic-751	60	8	formation	formation	NOUN
hjic-751	60	9	porphyrins	porphyrin	NOUN
hjic-751	60	10	are	be	AUX
hjic-751	60	11	peculiar	peculiar	ADJ
hjic-751	60	12	ligands	ligand	NOUN
hjic-751	60	13	in	in	ADP
hjic-751	60	14	terms	term	NOUN
hjic-751	60	15	of	of	ADP
hjic-751	60	16	complexation	complexation	NOUN
hjic-751	60	17	due	due	ADP
hjic-751	60	18	to	to	ADP
hjic-751	60	19	their	their	PRON
hjic-751	60	20	planar	planar	ADJ
hjic-751	60	21	,	,	PUNCT
hjic-751	60	22	cyclic	cyclic	ADJ
hjic-751	60	23	,	,	PUNCT
hjic-751	60	24	rigid	rigid	ADJ
hjic-751	60	25	,	,	PUNCT
hjic-751	60	26	aromatic	aromatic	ADJ
hjic-751	60	27	,	,	PUNCT
hjic-751	60	28	tetradentate	tetradentate	NOUN
hjic-751	60	29	,	,	PUNCT
hjic-751	60	30	as	as	ADV
hjic-751	60	31	well	well	ADV
hjic-751	60	32	as	as	ADP
hjic-751	60	33	protonated	protonated	ADJ
hjic-751	60	34	structure	structure	NOUN
hjic-751	60	35	.	.	PUNCT
hjic-751	61	1	the	the	DET
hjic-751	61	2	formation	formation	NOUN
hjic-751	61	3	of	of	ADP
hjic-751	61	4	an	an	DET
hjic-751	61	5	out	out	ADV
hjic-751	61	6	-	-	PUNCT
hjic-751	61	7	of	of	ADP
hjic-751	61	8	-	-	PUNCT
hjic-751	61	9	plane	plane	NOUN
hjic-751	61	10	complex	complex	NOUN
hjic-751	61	11	of	of	ADP
hjic-751	61	12	a	a	DET
hjic-751	61	13	large	large	ADJ
hjic-751	61	14	metal	metal	NOUN
hjic-751	61	15	ion	ion	NOUN
hjic-751	61	16	is	be	AUX
hjic-751	61	17	usually	usually	ADV
hjic-751	61	18	at	at	ADP
hjic-751	61	19	least	least	ADV
hjic-751	61	20	two	two	NUM
hjic-751	61	21	orders	order	NOUN
hjic-751	61	22	of	of	ADP
hjic-751	61	23	magnitude	magnitude	NOUN
hjic-751	61	24	faster	fast	ADV
hjic-751	61	25	than	than	ADP
hjic-751	61	26	that	that	PRON
hjic-751	61	27	of	of	ADP
hjic-751	61	28	an	an	DET
hjic-751	61	29	in	in	ADP
hjic-751	61	30	-	-	PUNCT
hjic-751	61	31	plane	plane	NOUN
hjic-751	61	32	one	one	NOUN
hjic-751	61	33	since	since	SCONJ
hjic-751	61	34	a	a	DET
hjic-751	61	35	smaller	small	ADJ
hjic-751	61	36	metal	metal	NOUN
hjic-751	61	37	ion	ion	NOUN
hjic-751	61	38	is	be	AUX
hjic-751	61	39	not	not	PART
hjic-751	61	40	able	able	ADJ
hjic-751	61	41	to	to	PART
hjic-751	61	42	coordinate	coordinate	VERB
hjic-751	61	43	to	to	ADP
hjic-751	61	44	all	all	DET
hjic-751	61	45	four	four	NUM
hjic-751	61	46	pyrrolic	pyrrolic	ADJ
hjic-751	61	47	nitrogens	nitrogen	NOUN
hjic-751	61	48	of	of	ADP
hjic-751	61	49	the	the	DET
hjic-751	61	50	reaction	reaction	NOUN
hjic-751	61	51	intermediate	intermediate	ADJ
hjic-751	61	52	,	,	PUNCT
hjic-751	61	53	in	in	ADP
hjic-751	61	54	the	the	DET
hjic-751	61	55	cavity	cavity	NOUN
hjic-751	61	56	of	of	ADP
hjic-751	61	57	which	which	PRON
hjic-751	61	58	the	the	DET
hjic-751	61	59	two	two	NUM
hjic-751	61	60	protons	proton	NOUN
hjic-751	61	61	also	also	ADV
hjic-751	61	62	remain	remain	VERB
hjic-751	61	63	{	{	PUNCT
hjic-751	61	64	h2	h2	NOUN
hjic-751	61	65	-	-	PUNCT
hjic-751	61	66	p	p	PROPN
hjic-751	61	67	-	-	PUNCT
hjic-751	61	68	m	m	NOUN
hjic-751	61	69	}	}	PUNCT
hjic-751	61	70	.	.	PUNCT
hjic-751	62	1	therefore	therefore	ADV
hjic-751	62	2	,	,	PUNCT
hjic-751	62	3	dissociation	dissociation	NOUN
hjic-751	62	4	of	of	ADP
hjic-751	62	5	the	the	DET
hjic-751	62	6	metal	metal	NOUN
hjic-751	62	7	ion	ion	NOUN
hjic-751	62	8	is	be	AUX
hjic-751	62	9	more	more	ADV
hjic-751	62	10	favorable	favorable	ADJ
hjic-751	62	11	than	than	ADP
hjic-751	62	12	that	that	PRON
hjic-751	62	13	of	of	ADP
hjic-751	62	14	the	the	DET
hjic-751	62	15	protons	proton	NOUN
hjic-751	62	16	.	.	PUNCT
hjic-751	63	1	besides	besides	SCONJ
hjic-751	63	2	the	the	DET
hjic-751	63	3	insertion	insertion	NOUN
hjic-751	63	4	of	of	ADP
hjic-751	63	5	a	a	DET
hjic-751	63	6	smaller	small	ADJ
hjic-751	63	7	metal	metal	NOUN
hjic-751	63	8	ion	ion	NOUN
hjic-751	63	9	,	,	PUNCT
hjic-751	63	10	its	its	PRON
hjic-751	63	11	dissociation	dissociation	NOUN
hjic-751	63	12	from	from	ADP
hjic-751	63	13	the	the	DET
hjic-751	63	14	in	in	ADP
hjic-751	63	15	-	-	PUNCT
hjic-751	63	16	plane	plane	NOUN
hjic-751	63	17	complex	complex	NOUN
hjic-751	63	18	of	of	ADP
hjic-751	63	19	the	the	DET
hjic-751	63	20	endproduct	endproduct	NOUN
hjic-751	63	21	may	may	AUX
hjic-751	63	22	be	be	AUX
hjic-751	63	23	kinetically	kinetically	ADV
hjic-751	63	24	hindered	hinder	VERB
hjic-751	63	25	due	due	ADP
hjic-751	63	26	to	to	ADP
hjic-751	63	27	the	the	DET
hjic-751	63	28	rigidity	rigidity	NOUN
hjic-751	63	29	of	of	ADP
hjic-751	63	30	the	the	DET
hjic-751	63	31	macrocycle	macrocycle	NOUN
hjic-751	64	1	[	[	X
hjic-751	64	2	1	1	NUM
hjic-751	64	3	]	]	PUNCT
hjic-751	64	4	.	.	PUNCT
hjic-751	65	1	formation	formation	NOUN
hjic-751	65	2	of	of	ADP
hjic-751	65	3	the	the	DET
hjic-751	65	4	in	in	ADP
hjic-751	65	5	-	-	PUNCT
hjic-751	65	6	plane	plane	NOUN
hjic-751	65	7	complexes	complex	NOUN
hjic-751	65	8	used	use	VERB
hjic-751	65	9	to	to	PART
hjic-751	65	10	be	be	AUX
hjic-751	65	11	enhanced	enhance	VERB
hjic-751	65	12	by	by	ADP
hjic-751	65	13	the	the	DET
hjic-751	65	14	addition	addition	NOUN
hjic-751	65	15	of	of	ADP
hjic-751	65	16	a	a	DET
hjic-751	65	17	small	small	ADJ
hjic-751	65	18	concentration	concentration	NOUN
hjic-751	65	19	of	of	ADP
hjic-751	65	20	a	a	DET
hjic-751	65	21	metal	metal	NOUN
hjic-751	65	22	ion	ion	NOUN
hjic-751	65	23	with	with	ADP
hjic-751	65	24	larger	large	ADJ
hjic-751	65	25	ionic	ionic	ADJ
hjic-751	65	26	radius	radius	NOUN
hjic-751	65	27	(	(	PUNCT
hjic-751	65	28	e.g.	e.g.	ADV
hjic-751	65	29	cd2	cd2	VERB
hjic-751	65	30	+	+	PROPN
hjic-751	65	31	,	,	PUNCT
hjic-751	65	32	hg2	hg2	PROPN
hjic-751	65	33	+	+	PROPN
hjic-751	65	34	,	,	PUNCT
hjic-751	65	35	pb2	pb2	PROPN
hjic-751	65	36	+	+	NOUN
hjic-751	65	37	)	)	PUNCT
hjic-751	65	38	to	to	ADP
hjic-751	65	39	the	the	DET
hjic-751	65	40	solution	solution	NOUN
hjic-751	65	41	of	of	ADP
hjic-751	65	42	the	the	DET
hjic-751	65	43	smaller	small	ADJ
hjic-751	65	44	one	one	NOUN
hjic-751	65	45	because	because	SCONJ
hjic-751	65	46	the	the	DET
hjic-751	65	47	insertion	insertion	NOUN
hjic-751	65	48	of	of	ADP
hjic-751	65	49	the	the	DET
hjic-751	65	50	larger	large	ADJ
hjic-751	65	51	metal	metal	NOUN
hjic-751	65	52	ion	ion	NOUN
hjic-751	65	53	into	into	ADP
hjic-751	65	54	the	the	DET
hjic-751	65	55	ligand	ligand	ADJ
hjic-751	65	56	cavity	cavity	NOUN
hjic-751	65	57	is	be	AUX
hjic-751	65	58	much	much	ADV
hjic-751	65	59	faster	fast	ADV
hjic-751	65	60	.	.	PUNCT
hjic-751	66	1	however	however	ADV
hjic-751	66	2	,	,	PUNCT
hjic-751	66	3	the	the	DET
hjic-751	66	4	oop	oop	NOUN
hjic-751	66	5	complex	complex	NOUN
hjic-751	66	6	is	be	AUX
hjic-751	66	7	considerably	considerably	ADV
hjic-751	66	8	less	less	ADV
hjic-751	66	9	stable	stable	ADJ
hjic-751	66	10	.	.	PUNCT
hjic-751	67	1	in	in	ADP
hjic-751	67	2	its	its	PRON
hjic-751	67	3	dome	dome	NOUN
hjic-751	67	4	-	-	PUNCT
hjic-751	67	5	distorted	distort	VERB
hjic-751	67	6	structure	structure	NOUN
hjic-751	67	7	,	,	PUNCT
hjic-751	67	8	two	two	NUM
hjic-751	67	9	diagonal	diagonal	ADJ
hjic-751	67	10	pyrrolic	pyrrolic	ADJ
hjic-751	67	11	nitrogens	nitrogen	NOUN
hjic-751	67	12	are	be	AUX
hjic-751	67	13	more	more	ADV
hjic-751	67	14	accessible	accessible	ADJ
hjic-751	67	15	from	from	ADP
hjic-751	67	16	the	the	DET
hjic-751	67	17	other	other	ADJ
hjic-751	67	18	side	side	NOUN
hjic-751	67	19	of	of	ADP
hjic-751	67	20	the	the	DET
hjic-751	67	21	ligand	ligand	NOUN
hjic-751	67	22	,	,	PUNCT
hjic-751	67	23	owing	owe	VERB
hjic-751	67	24	to	to	ADP
hjic-751	67	25	the	the	DET
hjic-751	67	26	enhancement	enhancement	NOUN
hjic-751	67	27	of	of	ADP
hjic-751	67	28	their	their	PRON
hjic-751	67	29	sp3	sp3	ADJ
hjic-751	67	30	hybridization	hybridization	NOUN
hjic-751	67	31	,	,	PUNCT
hjic-751	67	32	hence	hence	ADV
hjic-751	67	33	,	,	PUNCT
hjic-751	67	34	the	the	DET
hjic-751	67	35	metal	metal	NOUN
hjic-751	67	36	center	center	NOUN
hjic-751	67	37	can	can	AUX
hjic-751	67	38	be	be	AUX
hjic-751	67	39	easily	easily	ADV
hjic-751	67	40	exchanged	exchange	VERB
hjic-751	67	41	for	for	ADP
hjic-751	67	42	the	the	DET
hjic-751	67	43	smaller	small	ADJ
hjic-751	67	44	one	one	NOUN
hjic-751	67	45	[	[	X
hjic-751	67	46	1	1	NUM
hjic-751	67	47	-	-	SYM
hjic-751	67	48	2	2	NUM
hjic-751	67	49	,	,	PUNCT
hjic-751	67	50	9	9	NUM
hjic-751	67	51	]	]	PUNCT
hjic-751	67	52	.	.	PUNCT
hjic-751	68	1	this	this	DET
hjic-751	68	2	accessibility	accessibility	NOUN
hjic-751	68	3	makes	make	VERB
hjic-751	68	4	the	the	DET
hjic-751	68	5	realization	realization	NOUN
hjic-751	68	6	of	of	ADP
hjic-751	68	7	dinuclear	dinuclear	ADJ
hjic-751	68	8	out	out	ADP
hjic-751	68	9	-	-	PUNCT
hjic-751	68	10	of	of	ADP
hjic-751	68	11	-	-	PUNCT
hjic-751	68	12	plane	plane	NOUN
hjic-751	68	13	monoporphyrins	monoporphyrin	NOUN
hjic-751	68	14	(	(	PUNCT
hjic-751	68	15	2:1	2:1	NUM
hjic-751	68	16	complexes	complex	NOUN
hjic-751	68	17	)	)	PUNCT
hjic-751	68	18	possible	possible	ADJ
hjic-751	68	19	if	if	SCONJ
hjic-751	68	20	the	the	DET
hjic-751	68	21	metal	metal	NOUN
hjic-751	68	22	ion	ion	NOUN
hjic-751	68	23	possesses	possess	VERB
hjic-751	68	24	a	a	DET
hjic-751	68	25	low	low	ADJ
hjic-751	68	26	(	(	PUNCT
hjic-751	68	27	single	single	ADJ
hjic-751	68	28	)	)	PUNCT
hjic-751	68	29	positive	positive	ADJ
hjic-751	68	30	charge	charge	NOUN
hjic-751	68	31	and	and	CCONJ
hjic-751	68	32	is	be	AUX
hjic-751	68	33	large	large	ADJ
hjic-751	68	34	,	,	PUNCT
hjic-751	68	35	i.e.	i.e.	X
hjic-751	68	36	its	its	PRON
hjic-751	68	37	charge	charge	NOUN
hjic-751	68	38	density	density	NOUN
hjic-751	68	39	is	be	AUX
hjic-751	68	40	small	small	ADJ
hjic-751	68	41	enough	enough	ADV
hjic-751	68	42	,	,	PUNCT
hjic-751	68	43	e.g.	e.g.	ADV
hjic-751	68	44	mercury(i	mercury(i	PROPN
hjic-751	68	45	)	)	PUNCT
hjic-751	68	46	,	,	PUNCT
hjic-751	68	47	silver(i	silver(i	PROPN
hjic-751	68	48	)	)	PUNCT
hjic-751	68	49	and	and	CCONJ
hjic-751	68	50	thallium(i	thallium(i	NOUN
hjic-751	68	51	)	)	PUNCT
hjic-751	68	52	ions	ion	NOUN
hjic-751	68	53	[	[	X
hjic-751	68	54	1	1	NUM
hjic-751	68	55	,	,	PUNCT
hjic-751	68	56	8	8	NUM
hjic-751	68	57	-	-	SYM
hjic-751	68	58	9	9	NUM
hjic-751	68	59	]	]	PUNCT
hjic-751	68	60	.	.	PUNCT
hjic-751	69	1	moreover	moreover	ADV
hjic-751	69	2	,	,	PUNCT
hjic-751	69	3	the	the	DET
hjic-751	69	4	out	out	ADV
hjic-751	69	5	-	-	PUNCT
hjic-751	69	6	of	of	ADP
hjic-751	69	7	-	-	PUNCT
hjic-751	69	8	plane	plane	NOUN
hjic-751	69	9	position	position	NOUN
hjic-751	69	10	of	of	ADP
hjic-751	69	11	the	the	DET
hjic-751	69	12	metal	metal	NOUN
hjic-751	69	13	center	center	NOUN
hjic-751	69	14	,	,	PUNCT
hjic-751	69	15	together	together	ADV
hjic-751	69	16	with	with	ADP
hjic-751	69	17	the	the	DET
hjic-751	69	18	dome	dome	NOUN
hjic-751	69	19	-	-	PUNCT
hjic-751	69	20	distorted	distort	VERB
hjic-751	69	21	structure	structure	NOUN
hjic-751	69	22	(	(	PUNCT
hjic-751	69	23	owing	owe	VERB
hjic-751	69	24	to	to	ADP
hjic-751	69	25	the	the	DET
hjic-751	69	26	twisting	twisting	NOUN
hjic-751	69	27	of	of	ADP
hjic-751	69	28	aromatic	aromatic	ADJ
hjic-751	69	29	substituents	substituent	NOUN
hjic-751	69	30	from	from	ADP
hjic-751	69	31	a	a	DET
hjic-751	69	32	nearly	nearly	ADV
hjic-751	69	33	perpendicular	perpendicular	ADJ
hjic-751	69	34	position	position	NOUN
hjic-751	69	35	closer	close	ADV
hjic-751	69	36	to	to	ADP
hjic-751	69	37	the	the	DET
hjic-751	69	38	porphyrin	porphyrin	NOUN
hjic-751	69	39	plane	plane	NOUN
hjic-751	69	40	)	)	PUNCT
hjic-751	69	41	may	may	AUX
hjic-751	69	42	promote	promote	VERB
hjic-751	69	43	the	the	DET
hjic-751	69	44	formation	formation	NOUN
hjic-751	69	45	of	of	ADP
hjic-751	69	46	so	so	ADV
hjic-751	69	47	-	-	PUNCT
hjic-751	69	48	called	call	VERB
hjic-751	69	49	sandwich	sandwich	NOUN
hjic-751	69	50	complexes	complex	NOUN
hjic-751	69	51	of	of	ADP
hjic-751	69	52	various	various	ADJ
hjic-751	69	53	compositions	composition	NOUN
hjic-751	69	54	,	,	PUNCT
hjic-751	69	55	in	in	ADP
hjic-751	69	56	which	which	PRON
hjic-751	69	57	two	two	NUM
hjic-751	69	58	metal	metal	NOUN
hjic-751	69	59	ions	ion	NOUN
hjic-751	69	60	can	can	AUX
hjic-751	69	61	coordinate	coordinate	VERB
hjic-751	69	62	to	to	ADP
hjic-751	69	63	one	one	NUM
hjic-751	69	64	macrocycle	macrocycle	NOUN
hjic-751	69	65	,	,	PUNCT
hjic-751	69	66	and	and	CCONJ
hjic-751	69	67	,	,	PUNCT
hjic-751	69	68	reversely	reversely	ADV
hjic-751	69	69	,	,	PUNCT
hjic-751	69	70	one	one	NUM
hjic-751	69	71	metal	metal	NOUN
hjic-751	69	72	ion	ion	NOUN
hjic-751	69	73	can	can	AUX
hjic-751	69	74	concomitantly	concomitantly	ADV
hjic-751	69	75	coordinate	coordinate	VERB
hjic-751	69	76	to	to	ADP
hjic-751	69	77	two	two	NUM
hjic-751	69	78	ligands	ligand	NOUN
hjic-751	69	79	,	,	PUNCT
hjic-751	69	80	(	(	PUNCT
hjic-751	69	81	fig.3	fig.3	PROPN
hjic-751	69	82	)	)	PUNCT
hjic-751	70	1	[	[	X
hjic-751	70	2	1	1	NUM
hjic-751	70	3	-	-	SYM
hjic-751	70	4	2	2	NUM
hjic-751	70	5	,	,	PUNCT
hjic-751	70	6	9	9	NUM
hjic-751	70	7	]	]	PUNCT
hjic-751	70	8	.	.	PUNCT
hjic-751	70	9	lanthanide(iii	lanthanide(iii	PROPN
hjic-751	70	10	)	)	PUNCT
hjic-751	70	11	ions	ion	NOUN
hjic-751	70	12	form	form	VERB
hjic-751	70	13	typical	typical	ADJ
hjic-751	70	14	examples	example	NOUN
hjic-751	70	15	of	of	ADP
hjic-751	70	16	metallo	metallo	NOUN
hjic-751	70	17	-	-	PUNCT
hjic-751	70	18	oligoporphyrins	oligoporphyrin	NOUN
hjic-751	70	19	because	because	SCONJ
hjic-751	70	20	they	they	PRON
hjic-751	70	21	are	be	AUX
hjic-751	70	22	inclined	inclined	ADJ
hjic-751	70	23	to	to	PART
hjic-751	70	24	form	form	VERB
hjic-751	70	25	complexes	complex	NOUN
hjic-751	70	26	of	of	ADP
hjic-751	70	27	higher	high	ADJ
hjic-751	70	28	coordination	coordination	NOUN
hjic-751	70	29	number	number	NOUN
hjic-751	70	30	(	(	PUNCT
hjic-751	70	31	8	8	NUM
hjic-751	70	32	-	-	SYM
hjic-751	70	33	12	12	NUM
hjic-751	70	34	)	)	PUNCT
hjic-751	70	35	.	.	PUNCT
hjic-751	71	1	however	however	ADV
hjic-751	71	2	,	,	PUNCT
hjic-751	71	3	they	they	PRON
hjic-751	71	4	are	be	AUX
hjic-751	71	5	hard	hard	ADJ
hjic-751	71	6	lewis	lewis	PROPN
hjic-751	71	7	acids	acid	NOUN
hjic-751	71	8	,	,	PUNCT
hjic-751	71	9	hence	hence	ADV
hjic-751	71	10	,	,	PUNCT
hjic-751	71	11	their	their	PRON
hjic-751	71	12	insertion	insertion	NOUN
hjic-751	71	13	into	into	ADP
hjic-751	71	14	the	the	DET
hjic-751	71	15	coordination	coordination	NOUN
hjic-751	71	16	cavity	cavity	NOUN
hjic-751	71	17	of	of	ADP
hjic-751	71	18	the	the	DET
hjic-751	71	19	softer	soft	ADJ
hjic-751	71	20	n	n	CCONJ
hjic-751	71	21	-	-	PUNCT
hjic-751	71	22	donor	donor	NOUN
hjic-751	71	23	porphyrin	porphyrin	NOUN
hjic-751	71	24	ligand	ligand	NOUN
hjic-751	71	25	is	be	AUX
hjic-751	71	26	a	a	DET
hjic-751	71	27	slow	slow	ADJ
hjic-751	71	28	and	and	CCONJ
hjic-751	71	29	complicated	complicated	ADJ
hjic-751	71	30	process	process	NOUN
hjic-751	71	31	in	in	ADP
hjic-751	71	32	aqueous	aqueous	ADJ
hjic-751	71	33	solutions	solution	NOUN
hjic-751	71	34	.	.	PUNCT
hjic-751	72	1	this	this	DET
hjic-751	72	2	scheme	scheme	NOUN
hjic-751	72	3	1	1	NUM
hjic-751	72	4	.	.	PUNCT
hjic-751	72	5	simplified	simplify	VERB
hjic-751	72	6	energy	energy	NOUN
hjic-751	72	7	level	level	NOUN
hjic-751	72	8	diagram	diagram	NOUN
hjic-751	72	9	for	for	ADP
hjic-751	72	10	the	the	DET
hjic-751	72	11	change	change	NOUN
hjic-751	72	12	of	of	ADP
hjic-751	72	13	the	the	DET
hjic-751	72	14	porphyrin	porphyrin	NOUN
hjic-751	72	15	’s	’s	PART
hjic-751	72	16	molecular	molecular	ADJ
hjic-751	72	17	orbitals	orbital	NOUN
hjic-751	72	18	in	in	ADP
hjic-751	72	19	different	different	ADJ
hjic-751	72	20	types	type	NOUN
hjic-751	72	21	of	of	ADP
hjic-751	72	22	complexes	complex	NOUN
hjic-751	72	23	[	[	X
hjic-751	72	24	9	9	NUM
hjic-751	72	25	]	]	PUNCT
hjic-751	72	26	.	.	PUNCT
hjic-751	73	1	figure	figure	NOUN
hjic-751	73	2	2	2	NUM
hjic-751	73	3	.	.	PUNCT
hjic-751	74	1	absorption	absorption	NOUN
hjic-751	74	2	spectra	spectra	NOUN
hjic-751	74	3	of	of	ADP
hjic-751	74	4	the	the	DET
hjic-751	74	5	free	free	ADJ
hjic-751	74	6	base	base	NOUN
hjic-751	74	7	(	(	PUNCT
hjic-751	74	8	h2tspp4	h2tspp4	PROPN
hjic-751	74	9	–	–	PUNCT
hjic-751	74	10	)	)	PUNCT
hjic-751	74	11	;	;	PUNCT
hjic-751	74	12	the	the	DET
hjic-751	74	13	highly	highly	ADV
hjic-751	74	14	distorted	distorted	ADJ
hjic-751	74	15	,	,	PUNCT
hjic-751	74	16	octabrominated	octabrominated	ADJ
hjic-751	74	17	free	free	ADJ
hjic-751	74	18	base	base	NOUN
hjic-751	74	19	(	(	PUNCT
hjic-751	74	20	h2tsppbr8	h2tsppbr8	PROPN
hjic-751	74	21	4	4	NUM
hjic-751	74	22	–	–	PUNCT
hjic-751	74	23	)	)	PUNCT
hjic-751	74	24	;	;	PUNCT
hjic-751	74	25	a	a	DET
hjic-751	74	26	typical	typical	ADJ
hjic-751	74	27	in	in	ADP
hjic-751	74	28	-	-	PUNCT
hjic-751	74	29	plane	plane	NOUN
hjic-751	74	30	(	(	PUNCT
hjic-751	74	31	pdiitspp4	pdiitspp4	PROPN
hjic-751	74	32	–	–	PUNCT
hjic-751	74	33	)	)	PUNCT
hjic-751	74	34	;	;	PUNCT
hjic-751	74	35	and	and	CCONJ
hjic-751	74	36	a	a	DET
hjic-751	74	37	typical	typical	ADJ
hjic-751	74	38	out	out	ADV
hjic-751	74	39	-	-	PUNCT
hjic-751	74	40	of	of	ADP
hjic-751	74	41	-	-	PUNCT
hjic-751	74	42	plane	plane	NOUN
hjic-751	74	43	metalloporphyrin	metalloporphyrin	NOUN
hjic-751	74	44	(	(	PUNCT
hjic-751	74	45	hgiitspp4	hgiitspp4	PROPN
hjic-751	74	46	–	–	PUNCT
hjic-751	74	47	)	)	PUNCT
hjic-751	74	48	within	within	ADP
hjic-751	74	49	the	the	DET
hjic-751	74	50	soret	soret	NOUN
hjic-751	74	51	range	range	NOUN
hjic-751	75	1	[	[	X
hjic-751	75	2	1	1	NUM
hjic-751	75	3	]	]	PUNCT
hjic-751	75	4	.	.	PUNCT
hjic-751	76	1	valicsek	valicsek	PROPN
hjic-751	76	2	,	,	PUNCT
hjic-751	76	3	kiss	kiss	PROPN
hjic-751	76	4	,	,	PUNCT
hjic-751	76	5	fodor	fodor	PROPN
hjic-751	76	6	,	,	PUNCT
hjic-751	76	7	imran	imran	ADJ
hjic-751	76	8	,	,	PUNCT
hjic-751	76	9	and	and	CCONJ
hjic-751	76	10	horváth	horváth	PROPN
hjic-751	76	11	hungarian	hungarian	ADJ
hjic-751	76	12	journal	journal	NOUN
hjic-751	76	13	of	of	ADP
hjic-751	76	14	industry	industry	NOUN
hjic-751	76	15	and	and	CCONJ
hjic-751	76	16	chemistry	chemistry	NOUN
hjic-751	76	17	32	32	NUM
hjic-751	76	18	phenomenon	phenomenon	NOUN
hjic-751	76	19	partly	partly	ADV
hjic-751	76	20	originates	originate	NOUN
hjic-751	76	21	from	from	ADP
hjic-751	76	22	the	the	DET
hjic-751	76	23	stability	stability	NOUN
hjic-751	76	24	of	of	ADP
hjic-751	76	25	their	their	PRON
hjic-751	76	26	aqua	aqua	NOUN
hjic-751	76	27	complexes	complex	NOUN
hjic-751	76	28	.	.	PUNCT
hjic-751	77	1	due	due	ADP
hjic-751	77	2	to	to	ADP
hjic-751	77	3	the	the	DET
hjic-751	77	4	consequence	consequence	NOUN
hjic-751	77	5	of	of	ADP
hjic-751	77	6	their	their	PRON
hjic-751	77	7	pearson	pearson	NOUN
hjic-751	77	8	-	-	PUNCT
hjic-751	77	9	type	type	NOUN
hjic-751	77	10	hard	hard	ADJ
hjic-751	77	11	character	character	NOUN
hjic-751	77	12	,	,	PUNCT
hjic-751	77	13	they	they	PRON
hjic-751	77	14	coordinate	coordinate	VERB
hjic-751	77	15	rather	rather	ADV
hjic-751	77	16	to	to	ADP
hjic-751	77	17	the	the	DET
hjic-751	77	18	peripheral	peripheral	ADJ
hjic-751	77	19	substituents	substituent	NOUN
hjic-751	77	20	of	of	ADP
hjic-751	77	21	porphyrin	porphyrin	NOUN
hjic-751	77	22	(	(	PUNCT
hjic-751	77	23	instead	instead	ADV
hjic-751	77	24	of	of	ADP
hjic-751	77	25	the	the	DET
hjic-751	77	26	pyrrolic	pyrrolic	ADJ
hjic-751	77	27	nitrogens	nitrogen	NOUN
hjic-751	77	28	)	)	PUNCT
hjic-751	77	29	,	,	PUNCT
hjic-751	77	30	i.e.	i.e.	X
hjic-751	77	31	to	to	ADP
hjic-751	77	32	the	the	DET
hjic-751	77	33	ionic	ionic	ADJ
hjic-751	77	34	group	group	NOUN
hjic-751	77	35	ensuring	ensure	VERB
hjic-751	77	36	water	water	NOUN
hjic-751	77	37	-	-	PUNCT
hjic-751	77	38	solubility	solubility	NOUN
hjic-751	77	39	if	if	SCONJ
hjic-751	77	40	they	they	PRON
hjic-751	77	41	possess	possess	VERB
hjic-751	77	42	similarly	similarly	ADV
hjic-751	77	43	hard	hard	ADJ
hjic-751	77	44	o	o	ADJ
hjic-751	77	45	-	-	ADJ
hjic-751	77	46	donor	donor	ADJ
hjic-751	77	47	atoms	atom	NOUN
hjic-751	77	48	(	(	PUNCT
hjic-751	77	49	e.g.	e.g.	ADV
hjic-751	77	50	carboxy	carboxy	ADJ
hjic-751	77	51	or	or	CCONJ
hjic-751	77	52	sulfonatophenyl	sulfonatophenyl	NOUN
hjic-751	77	53	groups	group	NOUN
hjic-751	77	54	)	)	PUNCT
hjic-751	77	55	.	.	PUNCT
hjic-751	78	1	at	at	ADP
hjic-751	78	2	lower	low	ADJ
hjic-751	78	3	temperatures	temperature	NOUN
hjic-751	78	4	,	,	PUNCT
hjic-751	78	5	under	under	ADP
hjic-751	78	6	kinetic	kinetic	ADJ
hjic-751	78	7	control	control	NOUN
hjic-751	78	8	,	,	PUNCT
hjic-751	78	9	the	the	DET
hjic-751	78	10	early	early	ADJ
hjic-751	78	11	lanthanide(iii	lanthanide(iii	NOUN
hjic-751	78	12	)	)	PUNCT
hjic-751	78	13	ions	ion	NOUN
hjic-751	78	14	are	be	AUX
hjic-751	78	15	not	not	PART
hjic-751	78	16	able	able	ADJ
hjic-751	78	17	to	to	PART
hjic-751	78	18	coordinate	coordinate	VERB
hjic-751	78	19	into	into	ADP
hjic-751	78	20	the	the	DET
hjic-751	78	21	cavity	cavity	NOUN
hjic-751	78	22	,	,	PUNCT
hjic-751	78	23	rather	rather	ADV
hjic-751	78	24	to	to	ADP
hjic-751	78	25	the	the	DET
hjic-751	78	26	periphery	periphery	NOUN
hjic-751	78	27	;	;	PUNCT
hjic-751	78	28	resulting	result	VERB
hjic-751	78	29	in	in	ADP
hjic-751	78	30	the	the	DET
hjic-751	78	31	formation	formation	NOUN
hjic-751	78	32	of	of	ADP
hjic-751	78	33	the	the	DET
hjic-751	78	34	tail	tail	NOUN
hjic-751	78	35	-	-	PUNCT
hjic-751	78	36	to	to	ADP
hjic-751	78	37	-	-	PUNCT
hjic-751	78	38	tail	tail	NOUN
hjic-751	78	39	dimer	dimer	NOUN
hjic-751	78	40	of	of	ADP
hjic-751	78	41	free	free	ADJ
hjic-751	78	42	-	-	PUNCT
hjic-751	78	43	base	base	NOUN
hjic-751	78	44	ligands	ligand	NOUN
hjic-751	78	45	(	(	PUNCT
hjic-751	78	46	as	as	ADP
hjic-751	78	47	the	the	DET
hjic-751	78	48	tail	tail	NOUN
hjic-751	78	49	used	use	VERB
hjic-751	78	50	to	to	PART
hjic-751	78	51	be	be	AUX
hjic-751	78	52	referred	refer	VERB
hjic-751	78	53	to	to	ADP
hjic-751	78	54	as	as	ADP
hjic-751	78	55	the	the	DET
hjic-751	78	56	periphery	periphery	NOUN
hjic-751	78	57	)	)	PUNCT
hjic-751	78	58	.	.	PUNCT
hjic-751	79	1	higher	high	ADJ
hjic-751	79	2	temperatures	temperature	NOUN
hjic-751	79	3	and	and	CCONJ
hjic-751	79	4	thermodynamic	thermodynamic	ADJ
hjic-751	79	5	control	control	NOUN
hjic-751	79	6	are	be	AUX
hjic-751	79	7	also	also	ADV
hjic-751	79	8	necessary	necessary	ADJ
hjic-751	79	9	for	for	ADP
hjic-751	79	10	the	the	DET
hjic-751	79	11	insertion	insertion	NOUN
hjic-751	79	12	of	of	ADP
hjic-751	79	13	metal	metal	NOUN
hjic-751	79	14	ions	ion	NOUN
hjic-751	79	15	into	into	ADP
hjic-751	79	16	the	the	DET
hjic-751	79	17	cavity	cavity	NOUN
hjic-751	79	18	produced	produce	VERB
hjic-751	79	19	by	by	ADP
hjic-751	79	20	four	four	NUM
hjic-751	79	21	pyrrolic	pyrrolic	ADJ
hjic-751	79	22	nitrogens	nitrogen	NOUN
hjic-751	79	23	;	;	PUNCT
hjic-751	79	24	resulting	result	VERB
hjic-751	79	25	in	in	ADP
hjic-751	79	26	the	the	DET
hjic-751	79	27	formation	formation	NOUN
hjic-751	79	28	of	of	ADP
hjic-751	79	29	typical	typical	ADJ
hjic-751	79	30	metalloporphyrin	metalloporphyrin	NOUN
hjic-751	79	31	complexes	complex	NOUN
hjic-751	79	32	.	.	PUNCT
hjic-751	80	1	after	after	ADP
hjic-751	80	2	the	the	DET
hjic-751	80	3	discovery	discovery	NOUN
hjic-751	80	4	of	of	ADP
hjic-751	80	5	the	the	DET
hjic-751	80	6	possible	possible	ADJ
hjic-751	80	7	coordination	coordination	NOUN
hjic-751	80	8	bonds	bond	NOUN
hjic-751	80	9	between	between	ADP
hjic-751	80	10	lanthanide	lanthanide	ADJ
hjic-751	80	11	ions	ion	NOUN
hjic-751	80	12	and	and	CCONJ
hjic-751	80	13	sulfonato	sulfonato	NOUN
hjic-751	80	14	substituents	substituent	NOUN
hjic-751	80	15	,	,	PUNCT
hjic-751	80	16	the	the	DET
hjic-751	80	17	formation	formation	NOUN
hjic-751	80	18	of	of	ADP
hjic-751	80	19	lanthanide	lanthanide	ADJ
hjic-751	80	20	bisporphyrins	bisporphyrin	NOUN
hjic-751	80	21	may	may	AUX
hjic-751	80	22	be	be	AUX
hjic-751	80	23	realized	realize	VERB
hjic-751	80	24	as	as	ADP
hjic-751	80	25	a	a	DET
hjic-751	80	26	tail	tail	NOUN
hjic-751	80	27	-	-	PUNCT
hjic-751	80	28	to	to	ADP
hjic-751	80	29	-	-	PUNCT
hjic-751	80	30	tail	tail	NOUN
hjic-751	80	31	dimerization	dimerization	NOUN
hjic-751	80	32	of	of	ADP
hjic-751	80	33	two	two	NUM
hjic-751	80	34	metallomonoporphyrin	metallomonoporphyrin	ADJ
hjic-751	80	35	complexes	complex	NOUN
hjic-751	80	36	through	through	ADP
hjic-751	80	37	a	a	DET
hjic-751	80	38	metal	metal	NOUN
hjic-751	80	39	bridge	bridge	NOUN
hjic-751	80	40	;	;	PUNCT
hjic-751	80	41	deviating	deviate	VERB
hjic-751	80	42	from	from	ADP
hjic-751	80	43	the	the	DET
hjic-751	80	44	head	head	NOUN
hjic-751	80	45	-	-	PUNCT
hjic-751	80	46	to	to	ADP
hjic-751	80	47	-	-	PUNCT
hjic-751	80	48	head	head	NOUN
hjic-751	80	49	connection	connection	NOUN
hjic-751	80	50	as	as	ADP
hjic-751	80	51	in	in	ADP
hjic-751	80	52	the	the	DET
hjic-751	80	53	case	case	NOUN
hjic-751	80	54	of	of	ADP
hjic-751	80	55	typical	typical	ADJ
hjic-751	80	56	sandwich	sandwich	NOUN
hjic-751	80	57	complexes	complex	NOUN
hjic-751	80	58	(	(	PUNCT
hjic-751	80	59	head	head	NOUN
hjic-751	80	60	refers	refer	VERB
hjic-751	80	61	to	to	ADP
hjic-751	80	62	the	the	DET
hjic-751	80	63	cavity	cavity	NOUN
hjic-751	80	64	;	;	PUNCT
hjic-751	80	65	see	see	VERB
hjic-751	80	66	fig.3	fig.3	PROPN
hjic-751	80	67	)	)	PUNCT
hjic-751	80	68	.	.	PUNCT
hjic-751	81	1	on	on	ADP
hjic-751	81	2	the	the	DET
hjic-751	81	3	basis	basis	NOUN
hjic-751	81	4	of	of	ADP
hjic-751	81	5	our	our	PRON
hjic-751	81	6	previous	previous	ADJ
hjic-751	81	7	experiences	experience	NOUN
hjic-751	81	8	,	,	PUNCT
hjic-751	81	9	the	the	DET
hjic-751	81	10	coordination	coordination	NOUN
hjic-751	81	11	position	position	NOUN
hjic-751	81	12	of	of	ADP
hjic-751	81	13	lanthanide	lanthanide	ADJ
hjic-751	81	14	ions	ion	NOUN
hjic-751	81	15	was	be	AUX
hjic-751	81	16	influenced	influence	VERB
hjic-751	81	17	by	by	ADP
hjic-751	81	18	the	the	DET
hjic-751	81	19	change	change	NOUN
hjic-751	81	20	in	in	ADP
hjic-751	81	21	temperature	temperature	NOUN
hjic-751	81	22	[	[	X
hjic-751	81	23	1	1	NUM
hjic-751	81	24	-	-	SYM
hjic-751	81	25	2	2	NUM
hjic-751	81	26	]	]	PUNCT
hjic-751	81	27	,	,	PUNCT
hjic-751	81	28	[	[	X
hjic-751	81	29	1113	1113	NUM
hjic-751	81	30	]	]	PUNCT
hjic-751	81	31	.	.	PUNCT
hjic-751	82	1	during	during	ADP
hjic-751	82	2	the	the	DET
hjic-751	82	3	investigation	investigation	NOUN
hjic-751	82	4	of	of	ADP
hjic-751	82	5	the	the	DET
hjic-751	82	6	formation	formation	NOUN
hjic-751	82	7	of	of	ADP
hjic-751	82	8	“	"	PUNCT
hjic-751	82	9	typical	typical	ADJ
hjic-751	82	10	p	p	NOUN
hjic-751	82	11	-	-	PUNCT
hjic-751	82	12	type	type	NOUN
hjic-751	82	13	hyperporphyrin	hyperporphyrin	NOUN
hjic-751	82	14	”	"	PUNCT
hjic-751	82	15	complexes	complex	NOUN
hjic-751	82	16	(	(	PUNCT
hjic-751	82	17	e.g.	e.g.	ADV
hjic-751	82	18	tl+	tl+	NOUN
hjic-751	82	19	,	,	PUNCT
hjic-751	82	20	pb2	pb2	PROPN
hjic-751	82	21	+	+	PROPN
hjic-751	82	22	,	,	PUNCT
hjic-751	82	23	bi3	bi3	NOUN
hjic-751	82	24	+	+	PROPN
hjic-751	82	25	)	)	PUNCT
hjic-751	82	26	,	,	PUNCT
hjic-751	82	27	the	the	DET
hjic-751	82	28	species	specie	NOUN
hjic-751	82	29	possessing	possess	VERB
hjic-751	82	30	highly	highly	ADV
hjic-751	82	31	redshifted	redshifte	VERB
hjic-751	82	32	absorption	absorption	NOUN
hjic-751	82	33	bands	band	NOUN
hjic-751	82	34	are	be	AUX
hjic-751	82	35	the	the	DET
hjic-751	82	36	end	end	NOUN
hjic-751	82	37	-	-	PUNCT
hjic-751	82	38	products	product	NOUN
hjic-751	82	39	of	of	ADP
hjic-751	82	40	metalation	metalation	NOUN
hjic-751	82	41	only	only	ADV
hjic-751	82	42	in	in	ADP
hjic-751	82	43	hydrophobic	hydrophobic	NOUN
hjic-751	82	44	solvents	solvent	NOUN
hjic-751	82	45	,	,	PUNCT
hjic-751	82	46	since	since	SCONJ
hjic-751	82	47	they	they	PRON
hjic-751	82	48	can	can	AUX
hjic-751	82	49	appear	appear	VERB
hjic-751	82	50	in	in	ADP
hjic-751	82	51	aqueous	aqueous	ADJ
hjic-751	82	52	solutions	solution	NOUN
hjic-751	82	53	as	as	ADP
hjic-751	82	54	intermediates	intermediate	NOUN
hjic-751	82	55	with	with	ADP
hjic-751	82	56	shorter	short	ADJ
hjic-751	82	57	or	or	CCONJ
hjic-751	82	58	longer	long	ADJ
hjic-751	82	59	lifetimes	lifetime	NOUN
hjic-751	82	60	depending	depend	VERB
hjic-751	82	61	on	on	ADP
hjic-751	82	62	the	the	DET
hjic-751	82	63	metal	metal	NOUN
hjic-751	82	64	ion	ion	NOUN
hjic-751	82	65	.	.	PUNCT
hjic-751	83	1	the	the	DET
hjic-751	83	2	absorption	absorption	NOUN
hjic-751	83	3	spectra	spectra	NOUN
hjic-751	83	4	of	of	ADP
hjic-751	83	5	the	the	DET
hjic-751	83	6	end	end	NOUN
hjic-751	83	7	-	-	PUNCT
hjic-751	83	8	products	product	NOUN
hjic-751	83	9	of	of	ADP
hjic-751	83	10	these	these	DET
hjic-751	83	11	transformation	transformation	NOUN
hjic-751	83	12	reactions	reaction	NOUN
hjic-751	83	13	are	be	AUX
hjic-751	83	14	very	very	ADV
hjic-751	83	15	similar	similar	ADJ
hjic-751	83	16	(	(	PUNCT
hjic-751	83	17	less	less	ADV
hjic-751	83	18	redshifted	redshifte	VERB
hjic-751	83	19	)	)	PUNCT
hjic-751	83	20	to	to	ADP
hjic-751	83	21	those	those	PRON
hjic-751	83	22	of	of	ADP
hjic-751	83	23	the	the	DET
hjic-751	83	24	typical	typical	ADJ
hjic-751	83	25	,	,	PUNCT
hjic-751	83	26	common	common	ADJ
hjic-751	83	27	out	out	ADV
hjic-751	83	28	-	-	PUNCT
hjic-751	83	29	of	of	ADP
hjic-751	83	30	-	-	PUNCT
hjic-751	83	31	plane	plane	NOUN
hjic-751	83	32	metallo	metallo	NOUN
hjic-751	83	33	-	-	PUNCT
hjic-751	83	34	monoporphyrins	monoporphyrin	NOUN
hjic-751	83	35	(	(	PUNCT
hjic-751	83	36	e.g.	e.g.	ADV
hjic-751	83	37	hgii	hgii	NOUN
hjic-751	83	38	-	-	PUNCT
hjic-751	83	39	porphyrin	porphyrin	NOUN
hjic-751	83	40	in	in	ADP
hjic-751	83	41	fig.2	fig.2	PROPN
hjic-751	83	42	)	)	PUNCT
hjic-751	83	43	.	.	PUNCT
hjic-751	84	1	this	this	DET
hjic-751	84	2	phenomenon	phenomenon	NOUN
hjic-751	84	3	may	may	AUX
hjic-751	84	4	be	be	AUX
hjic-751	84	5	accounted	account	VERB
hjic-751	84	6	for	for	ADP
hjic-751	84	7	to	to	ADP
hjic-751	84	8	the	the	DET
hjic-751	84	9	considerable	considerable	ADJ
hjic-751	84	10	coordination	coordination	NOUN
hjic-751	84	11	ability	ability	NOUN
hjic-751	84	12	or	or	CCONJ
hjic-751	84	13	the	the	DET
hjic-751	84	14	polarizing	polarizing	NOUN
hjic-751	84	15	effect	effect	NOUN
hjic-751	84	16	of	of	ADP
hjic-751	84	17	water	water	NOUN
hjic-751	84	18	molecules	molecule	NOUN
hjic-751	84	19	,	,	PUNCT
hjic-751	84	20	which	which	PRON
hjic-751	84	21	can	can	AUX
hjic-751	84	22	enable	enable	VERB
hjic-751	84	23	the	the	DET
hjic-751	84	24	complex	complex	NOUN
hjic-751	84	25	to	to	PART
hjic-751	84	26	overcome	overcome	VERB
hjic-751	84	27	the	the	DET
hjic-751	84	28	kinetic	kinetic	ADJ
hjic-751	84	29	energy	energy	NOUN
hjic-751	84	30	barrier	barrier	NOUN
hjic-751	84	31	towards	towards	ADP
hjic-751	84	32	the	the	DET
hjic-751	84	33	formation	formation	NOUN
hjic-751	84	34	of	of	ADP
hjic-751	84	35	the	the	DET
hjic-751	84	36	more	more	ADV
hjic-751	84	37	stable	stable	ADJ
hjic-751	84	38	structure	structure	NOUN
hjic-751	84	39	,	,	PUNCT
hjic-751	84	40	in	in	ADP
hjic-751	84	41	which	which	PRON
hjic-751	84	42	the	the	DET
hjic-751	84	43	metal	metal	NOUN
hjic-751	84	44	center	center	NOUN
hjic-751	84	45	is	be	AUX
hjic-751	84	46	located	locate	VERB
hjic-751	84	47	closer	close	ADV
hjic-751	84	48	to	to	ADP
hjic-751	84	49	the	the	DET
hjic-751	84	50	ligand	ligand	ADJ
hjic-751	84	51	plane	plane	NOUN
hjic-751	84	52	,	,	PUNCT
hjic-751	84	53	resulting	result	VERB
hjic-751	84	54	in	in	ADP
hjic-751	84	55	decreases	decrease	NOUN
hjic-751	84	56	in	in	ADP
hjic-751	84	57	distortion	distortion	NOUN
hjic-751	84	58	,	,	PUNCT
hjic-751	84	59	as	as	ADV
hjic-751	84	60	well	well	ADV
hjic-751	84	61	as	as	ADP
hjic-751	84	62	redshift	redshift	NOUN
hjic-751	84	63	.	.	PUNCT
hjic-751	85	1	furthermore	furthermore	ADV
hjic-751	85	2	,	,	PUNCT
hjic-751	85	3	“	"	PUNCT
hjic-751	85	4	hyperporphyrins	hyperporphyrin	NOUN
hjic-751	85	5	”	"	PUNCT
hjic-751	85	6	can	can	AUX
hjic-751	85	7	appear	appear	VERB
hjic-751	85	8	as	as	ADP
hjic-751	85	9	intermediates	intermediate	NOUN
hjic-751	85	10	in	in	ADP
hjic-751	85	11	smaller	small	ADJ
hjic-751	85	12	amounts	amount	NOUN
hjic-751	85	13	during	during	ADP
hjic-751	85	14	the	the	DET
hjic-751	85	15	formation	formation	NOUN
hjic-751	85	16	of	of	ADP
hjic-751	85	17	typical	typical	ADJ
hjic-751	85	18	,	,	PUNCT
hjic-751	85	19	common	common	ADJ
hjic-751	85	20	out	out	ADV
hjic-751	85	21	-	-	PUNCT
hjic-751	85	22	of	of	ADP
hjic-751	85	23	-	-	PUNCT
hjic-751	85	24	plane	plane	NOUN
hjic-751	85	25	metallomonoporphyrins	metallomonoporphyrin	NOUN
hjic-751	85	26	as	as	ADV
hjic-751	85	27	well	well	ADV
hjic-751	85	28	[	[	X
hjic-751	85	29	1	1	NUM
hjic-751	85	30	,	,	PUNCT
hjic-751	85	31	14	14	NUM
hjic-751	85	32	]	]	PUNCT
hjic-751	85	33	.	.	PUNCT
hjic-751	86	1	in	in	ADP
hjic-751	86	2	the	the	DET
hjic-751	86	3	case	case	NOUN
hjic-751	86	4	of	of	ADP
hjic-751	86	5	“	"	PUNCT
hjic-751	86	6	d	d	ADJ
hjic-751	86	7	-	-	PUNCT
hjic-751	86	8	type	type	ADJ
hjic-751	86	9	hyperporphyrin	hyperporphyrin	NOUN
hjic-751	86	10	”	"	PUNCT
hjic-751	86	11	complexes	complex	NOUN
hjic-751	86	12	(	(	PUNCT
hjic-751	86	13	e.g.	e.g.	ADV
hjic-751	86	14	mn3	mn3	NOUN
hjic-751	86	15	+	+	NOUN
hjic-751	86	16	,	,	PUNCT
hjic-751	86	17	co3	co3	PROPN
hjic-751	86	18	+	+	PROPN
hjic-751	86	19	,	,	PUNCT
hjic-751	86	20	ni2	ni2	NOUN
hjic-751	86	21	+	+	NOUN
hjic-751	86	22	)	)	PUNCT
hjic-751	86	23	,	,	PUNCT
hjic-751	86	24	the	the	DET
hjic-751	86	25	low	low	ADJ
hjic-751	86	26	-	-	PUNCT
hjic-751	86	27	spin	spin	NOUN
hjic-751	86	28	and	and	CCONJ
hjic-751	86	29	ruffled	ruffled	ADJ
hjic-751	86	30	complex	complex	NOUN
hjic-751	86	31	with	with	ADP
hjic-751	86	32	a	a	DET
hjic-751	86	33	contracted	contract	VERB
hjic-751	86	34	cavity	cavity	NOUN
hjic-751	86	35	can	can	AUX
hjic-751	86	36	exist	exist	VERB
hjic-751	86	37	in	in	ADP
hjic-751	86	38	a	a	DET
hjic-751	86	39	spinisomerization	spinisomerization	NOUN
hjic-751	86	40	equilibrium	equilibrium	NOUN
hjic-751	86	41	with	with	ADP
hjic-751	86	42	the	the	DET
hjic-751	86	43	high	high	ADJ
hjic-751	86	44	-	-	PUNCT
hjic-751	86	45	spin	spin	NOUN
hjic-751	86	46	and	and	CCONJ
hjic-751	86	47	planar	planar	ADJ
hjic-751	86	48	forms	form	NOUN
hjic-751	86	49	,	,	PUNCT
hjic-751	86	50	which	which	PRON
hjic-751	86	51	not	not	PART
hjic-751	86	52	only	only	ADV
hjic-751	86	53	exhibits	exhibit	VERB
hjic-751	86	54	less	less	ADJ
hjic-751	86	55	redshift	redshift	NOUN
hjic-751	86	56	,	,	PUNCT
hjic-751	86	57	but	but	CCONJ
hjic-751	86	58	rather	rather	ADV
hjic-751	86	59	blueshifted	blueshifted	ADJ
hjic-751	86	60	absorption	absorption	NOUN
hjic-751	86	61	bands	band	NOUN
hjic-751	86	62	compared	compare	VERB
hjic-751	86	63	to	to	ADP
hjic-751	86	64	those	those	PRON
hjic-751	86	65	of	of	ADP
hjic-751	86	66	the	the	DET
hjic-751	86	67	free	free	ADJ
hjic-751	86	68	-	-	PUNCT
hjic-751	86	69	base	base	NOUN
hjic-751	86	70	ligand	ligand	NOUN
hjic-751	86	71	.	.	PUNCT
hjic-751	87	1	this	this	DET
hjic-751	87	2	reaction	reaction	NOUN
hjic-751	87	3	can	can	AUX
hjic-751	87	4	be	be	AUX
hjic-751	87	5	influenced	influence	VERB
hjic-751	87	6	by	by	ADP
hjic-751	87	7	the	the	DET
hjic-751	87	8	strength	strength	NOUN
hjic-751	87	9	of	of	ADP
hjic-751	87	10	the	the	DET
hjic-751	87	11	m	m	PROPN
hjic-751	87	12	-	-	PUNCT
hjic-751	87	13	n	n	PROPN
hjic-751	87	14	bonds	bond	NOUN
hjic-751	87	15	(	(	PUNCT
hjic-751	87	16	owing	owe	VERB
hjic-751	87	17	to	to	ADP
hjic-751	87	18	the	the	DET
hjic-751	87	19	electronic	electronic	ADJ
hjic-751	87	20	effects	effect	NOUN
hjic-751	87	21	of	of	ADP
hjic-751	87	22	peripheral	peripheral	ADJ
hjic-751	87	23	or	or	CCONJ
hjic-751	87	24	axial	axial	ADJ
hjic-751	87	25	substituents	substituent	NOUN
hjic-751	87	26	)	)	PUNCT
hjic-751	87	27	,	,	PUNCT
hjic-751	87	28	due	due	ADP
hjic-751	87	29	to	to	ADP
hjic-751	87	30	the	the	DET
hjic-751	87	31	size	size	NOUN
hjic-751	87	32	of	of	ADP
hjic-751	87	33	the	the	DET
hjic-751	87	34	coordination	coordination	NOUN
hjic-751	87	35	cavity	cavity	NOUN
hjic-751	87	36	(	(	PUNCT
hjic-751	87	37	owing	owe	VERB
hjic-751	87	38	to	to	ADP
hjic-751	87	39	the	the	DET
hjic-751	87	40	substitution	substitution	NOUN
hjic-751	87	41	or	or	CCONJ
hjic-751	87	42	saturation	saturation	NOUN
hjic-751	87	43	of	of	ADP
hjic-751	87	44	methylidene	methylidene	NOUN
hjic-751	87	45	bridges	bridge	NOUN
hjic-751	87	46	or	or	CCONJ
hjic-751	87	47	pyrrolic	pyrrolic	ADJ
hjic-751	87	48	carbons	carbon	NOUN
hjic-751	87	49	)	)	PUNCT
hjic-751	88	1	[	[	X
hjic-751	88	2	1	1	NUM
hjic-751	88	3	-	-	SYM
hjic-751	88	4	2	2	NUM
hjic-751	88	5	,	,	PUNCT
hjic-751	88	6	5	5	NUM
hjic-751	88	7	-	-	SYM
hjic-751	88	8	7	7	NUM
hjic-751	88	9	]	]	PUNCT
hjic-751	88	10	.	.	PUNCT
hjic-751	89	1	3.3	3.3	NUM
hjic-751	89	2	.	.	PUNCT
hjic-751	90	1	photophysics	photophysic	NOUN
hjic-751	90	2	porphyrins	porphyrin	NOUN
hjic-751	90	3	represent	represent	VERB
hjic-751	90	4	one	one	NUM
hjic-751	90	5	of	of	ADP
hjic-751	90	6	the	the	DET
hjic-751	90	7	most	most	ADV
hjic-751	90	8	interesting	interesting	ADJ
hjic-751	90	9	groups	group	NOUN
hjic-751	90	10	of	of	ADP
hjic-751	90	11	compounds	compound	NOUN
hjic-751	90	12	in	in	ADP
hjic-751	90	13	terms	term	NOUN
hjic-751	90	14	of	of	ADP
hjic-751	90	15	photophysical	photophysical	ADJ
hjic-751	90	16	properties	property	NOUN
hjic-751	90	17	and	and	CCONJ
hjic-751	90	18	biological	biological	ADJ
hjic-751	90	19	significance	significance	NOUN
hjic-751	90	20	.	.	PUNCT
hjic-751	91	1	due	due	ADP
hjic-751	91	2	to	to	ADP
hjic-751	91	3	their	their	PRON
hjic-751	91	4	rigid	rigid	ADJ
hjic-751	91	5	structure	structure	NOUN
hjic-751	91	6	and	and	CCONJ
hjic-751	91	7	aromatic	aromatic	ADJ
hjic-751	91	8	electronic	electronic	ADJ
hjic-751	91	9	system	system	NOUN
hjic-751	91	10	,	,	PUNCT
hjic-751	91	11	they	they	PRON
hjic-751	91	12	display	display	VERB
hjic-751	91	13	two	two	NUM
hjic-751	91	14	types	type	NOUN
hjic-751	91	15	of	of	ADP
hjic-751	91	16	fluorescence	fluorescence	NOUN
hjic-751	91	17	:	:	PUNCT
hjic-751	91	18	beside	beside	ADP
hjic-751	91	19	their	their	PRON
hjic-751	91	20	relatively	relatively	ADV
hjic-751	91	21	strong	strong	ADJ
hjic-751	91	22	singlet-1	singlet-1	PUNCT
hjic-751	91	23	fluorescence	fluorescence	NOUN
hjic-751	91	24	in	in	ADP
hjic-751	91	25	the	the	DET
hjic-751	91	26	range	range	NOUN
hjic-751	91	27	of	of	ADP
hjic-751	91	28	550–800	550–800	NUM
hjic-751	91	29	nm	nm	NOUN
hjic-751	91	30	,	,	PUNCT
hjic-751	91	31	weak	weak	ADJ
hjic-751	91	32	and	and	CCONJ
hjic-751	91	33	rare	rare	ADJ
hjic-751	91	34	singlet-2	singlet-2	NUM
hjic-751	91	35	luminescence	luminescence	NOUN
hjic-751	91	36	is	be	AUX
hjic-751	91	37	observable	observable	ADJ
hjic-751	91	38	between	between	ADP
hjic-751	91	39	400	400	NUM
hjic-751	91	40	and	and	CCONJ
hjic-751	91	41	550	550	NUM
hjic-751	91	42	nm	nm	NOUN
hjic-751	91	43	upon	upon	SCONJ
hjic-751	91	44	excitation	excitation	NOUN
hjic-751	91	45	of	of	ADP
hjic-751	91	46	the	the	DET
hjic-751	91	47	soret	soret	NOUN
hjic-751	91	48	band	band	NOUN
hjic-751	91	49	(	(	PUNCT
hjic-751	91	50	scheme	scheme	NOUN
hjic-751	91	51	1	1	NUM
hjic-751	91	52	)	)	PUNCT
hjic-751	92	1	[	[	X
hjic-751	92	2	1	1	NUM
hjic-751	92	3	]	]	PUNCT
hjic-751	92	4	.	.	PUNCT
hjic-751	93	1	the	the	DET
hjic-751	93	2	quantum	quantum	ADJ
hjic-751	93	3	yields	yield	NOUN
hjic-751	93	4	of	of	ADP
hjic-751	93	5	s2	s2	NOUN
hjic-751	93	6	-	-	PUNCT
hjic-751	93	7	fluorescence	fluorescence	NOUN
hjic-751	93	8	are	be	AUX
hjic-751	93	9	about	about	ADV
hjic-751	93	10	3	3	NUM
hjic-751	93	11	orders	order	NOUN
hjic-751	93	12	of	of	ADP
hjic-751	93	13	magnitude	magnitude	NOUN
hjic-751	93	14	lower	low	ADJ
hjic-751	93	15	than	than	ADP
hjic-751	93	16	those	those	PRON
hjic-751	93	17	of	of	ADP
hjic-751	93	18	s1	s1	NOUN
hjic-751	93	19	-	-	PUNCT
hjic-751	93	20	fluorescence	fluorescence	NOUN
hjic-751	93	21	in	in	ADP
hjic-751	93	22	the	the	DET
hjic-751	93	23	case	case	NOUN
hjic-751	93	24	of	of	ADP
hjic-751	93	25	free	free	ADJ
hjic-751	93	26	-	-	PUNCT
hjic-751	93	27	base	base	NOUN
hjic-751	93	28	porphyrins	porphyrin	NOUN
hjic-751	93	29	,	,	PUNCT
hjic-751	93	30	especially	especially	ADV
hjic-751	93	31	~1200fold	~1200fold	PUNCT
hjic-751	93	32	for	for	ADP
hjic-751	93	33	h2tspp4(6.3×10	h2tspp4(6.3×10	NOUN
hjic-751	93	34	-	-	SYM
hjic-751	93	35	5	5	NUM
hjic-751	93	36	vs.	vs.	ADP
hjic-751	93	37	7.5	7.5	NUM
hjic-751	93	38	%	%	NOUN
hjic-751	93	39	)	)	PUNCT
hjic-751	93	40	.	.	PUNCT
hjic-751	94	1	however	however	ADV
hjic-751	94	2	,	,	PUNCT
hjic-751	94	3	this	this	DET
hjic-751	94	4	ratio	ratio	NOUN
hjic-751	94	5	decreases	decrease	VERB
hjic-751	94	6	with	with	ADP
hjic-751	94	7	metalation	metalation	NOUN
hjic-751	94	8	,	,	PUNCT
hjic-751	94	9	mainly	mainly	ADV
hjic-751	94	10	in	in	ADP
hjic-751	94	11	the	the	DET
hjic-751	94	12	case	case	NOUN
hjic-751	94	13	of	of	ADP
hjic-751	94	14	the	the	DET
hjic-751	94	15	formation	formation	NOUN
hjic-751	94	16	of	of	ADP
hjic-751	94	17	out	out	ADV
hjic-751	94	18	-	-	PUNCT
hjic-751	94	19	of	of	ADP
hjic-751	94	20	-	-	PUNCT
hjic-751	94	21	plane	plane	NOUN
hjic-751	94	22	complexes	complex	NOUN
hjic-751	94	23	.	.	PUNCT
hjic-751	95	1	since	since	SCONJ
hjic-751	95	2	the	the	DET
hjic-751	95	3	structure	structure	NOUN
hjic-751	95	4	of	of	ADP
hjic-751	95	5	s2	s2	NOUN
hjic-751	95	6	-	-	PUNCT
hjic-751	95	7	excited	excite	VERB
hjic-751	95	8	porphyrins	porphyrin	NOUN
hjic-751	95	9	may	may	AUX
hjic-751	95	10	be	be	AUX
hjic-751	95	11	close	close	ADJ
hjic-751	95	12	to	to	ADP
hjic-751	95	13	that	that	PRON
hjic-751	95	14	of	of	ADP
hjic-751	95	15	the	the	DET
hjic-751	95	16	dome	dome	NOUN
hjic-751	95	17	-	-	PUNCT
hjic-751	95	18	distorted	distort	VERB
hjic-751	95	19	oop	oop	NOUN
hjic-751	95	20	complexes	complex	NOUN
hjic-751	95	21	that	that	PRON
hjic-751	95	22	are	be	AUX
hjic-751	95	23	already	already	ADV
hjic-751	95	24	in	in	ADP
hjic-751	95	25	the	the	DET
hjic-751	95	26	electronic	electronic	ADJ
hjic-751	95	27	ground	ground	NOUN
hjic-751	95	28	state	state	NOUN
hjic-751	95	29	.	.	PUNCT
hjic-751	96	1	another	another	DET
hjic-751	96	2	consequence	consequence	NOUN
hjic-751	96	3	of	of	ADP
hjic-751	96	4	this	this	DET
hjic-751	96	5	structural	structural	ADJ
hjic-751	96	6	similarity	similarity	NOUN
hjic-751	96	7	(	(	PUNCT
hjic-751	96	8	namely	namely	ADV
hjic-751	96	9	small	small	ADJ
hjic-751	96	10	stokes	stoke	NOUN
hjic-751	96	11	shift	shift	NOUN
hjic-751	96	12	)	)	PUNCT
hjic-751	96	13	is	be	AUX
hjic-751	96	14	that	that	SCONJ
hjic-751	96	15	the	the	DET
hjic-751	96	16	directions	direction	NOUN
hjic-751	96	17	of	of	ADP
hjic-751	96	18	the	the	DET
hjic-751	96	19	shifts	shift	NOUN
hjic-751	96	20	of	of	ADP
hjic-751	96	21	s2	s2	NOUN
hjic-751	96	22	-	-	PUNCT
hjic-751	96	23	fluorescence	fluorescence	NOUN
hjic-751	96	24	bands	band	NOUN
hjic-751	96	25	invert	invert	NOUN
hjic-751	96	26	(	(	PUNCT
hjic-751	96	27	according	accord	VERB
hjic-751	96	28	to	to	ADP
hjic-751	96	29	soret	soret	VERB
hjic-751	96	30	absorption	absorption	NOUN
hjic-751	96	31	)	)	PUNCT
hjic-751	96	32	between	between	ADP
hjic-751	96	33	the	the	DET
hjic-751	96	34	inplane	inplane	NOUN
hjic-751	96	35	(	(	PUNCT
hjic-751	96	36	redshifted	redshifte	VERB
hjic-751	96	37	)	)	PUNCT
hjic-751	96	38	and	and	CCONJ
hjic-751	96	39	out	out	ADV
hjic-751	96	40	-	-	PUNCT
hjic-751	96	41	of	of	ADP
hjic-751	96	42	-	-	PUNCT
hjic-751	96	43	plane	plane	NOUN
hjic-751	96	44	(	(	PUNCT
hjic-751	96	45	blueshifted	blueshifted	ADJ
hjic-751	96	46	)	)	PUNCT
hjic-751	96	47	complexes	complex	NOUN
hjic-751	96	48	when	when	SCONJ
hjic-751	96	49	compared	compare	VERB
hjic-751	96	50	to	to	ADP
hjic-751	96	51	the	the	DET
hjic-751	96	52	free	free	ADJ
hjic-751	96	53	-	-	PUNCT
hjic-751	96	54	base	base	NOUN
hjic-751	96	55	ligand	ligand	NOUN
hjic-751	96	56	[	[	X
hjic-751	96	57	1	1	NUM
hjic-751	96	58	]	]	PUNCT
hjic-751	96	59	.	.	PUNCT
hjic-751	97	1	singlet-1	singlet-1	AUX
hjic-751	97	2	fluorescence	fluorescence	NOUN
hjic-751	97	3	bands	band	NOUN
hjic-751	97	4	exhibit	exhibit	VERB
hjic-751	97	5	blueshifts	blueshift	NOUN
hjic-751	97	6	in	in	ADP
hjic-751	97	7	both	both	DET
hjic-751	97	8	types	type	NOUN
hjic-751	97	9	(	(	PUNCT
hjic-751	97	10	in	in	ADP
hjic-751	97	11	-	-	PUNCT
hjic-751	97	12	plane	plane	NOUN
hjic-751	97	13	and	and	CCONJ
hjic-751	97	14	out	out	ADP
hjic-751	97	15	-	-	PUNCT
hjic-751	97	16	of	of	ADP
hjic-751	97	17	-	-	PUNCT
hjic-751	97	18	plane	plane	NOUN
hjic-751	97	19	)	)	PUNCT
hjic-751	97	20	of	of	ADP
hjic-751	97	21	metalloporphyrins	metalloporphyrin	NOUN
hjic-751	97	22	,	,	PUNCT
hjic-751	97	23	as	as	ADP
hjic-751	97	24	a	a	DET
hjic-751	97	25	consequence	consequence	NOUN
hjic-751	97	26	of	of	ADP
hjic-751	97	27	the	the	DET
hjic-751	97	28	aforementioned	aforementioned	ADJ
hjic-751	97	29	split	split	NOUN
hjic-751	97	30	in	in	ADP
hjic-751	97	31	free	free	ADJ
hjic-751	97	32	-	-	PUNCT
hjic-751	97	33	base	base	NOUN
hjic-751	97	34	ligands	ligand	NOUN
hjic-751	97	35	because	because	SCONJ
hjic-751	97	36	of	of	ADP
hjic-751	97	37	the	the	DET
hjic-751	97	38	presence	presence	NOUN
hjic-751	97	39	of	of	ADP
hjic-751	97	40	two	two	NUM
hjic-751	97	41	protons	proton	NOUN
hjic-751	97	42	,	,	PUNCT
hjic-751	97	43	as	as	ADV
hjic-751	97	44	well	well	ADV
hjic-751	97	45	as	as	ADP
hjic-751	97	46	their	their	PRON
hjic-751	97	47	reduced	reduce	VERB
hjic-751	97	48	symmetry	symmetry	NOUN
hjic-751	97	49	(	(	PUNCT
hjic-751	97	50	scheme	scheme	NOUN
hjic-751	97	51	1	1	NUM
hjic-751	97	52	)	)	PUNCT
hjic-751	97	53	.	.	PUNCT
hjic-751	98	1	furthermore	furthermore	ADV
hjic-751	98	2	,	,	PUNCT
hjic-751	98	3	almost	almost	ADV
hjic-751	98	4	all	all	DET
hjic-751	98	5	complexes	complex	NOUN
hjic-751	98	6	exhibit	exhibit	VERB
hjic-751	98	7	similarly	similarly	ADV
hjic-751	98	8	large	large	ADJ
hjic-751	98	9	stokes	stoke	NOUN
hjic-751	98	10	shifts	shift	NOUN
hjic-751	98	11	,	,	PUNCT
hjic-751	98	12	as	as	ADV
hjic-751	98	13	well	well	ADV
hjic-751	98	14	as	as	ADP
hjic-751	98	15	lifetimes	lifetime	NOUN
hjic-751	98	16	and	and	CCONJ
hjic-751	98	17	quantum	quantum	NOUN
hjic-751	98	18	yields	yield	NOUN
hjic-751	98	19	.	.	PUNCT
hjic-751	99	1	in	in	ADP
hjic-751	99	2	the	the	DET
hjic-751	99	3	case	case	NOUN
hjic-751	99	4	of	of	ADP
hjic-751	99	5	in	in	ADP
hjic-751	99	6	-	-	PUNCT
hjic-751	99	7	plane	plane	NOUN
hjic-751	99	8	a	a	NOUN
hjic-751	99	9	)	)	PUNCT
hjic-751	99	10	b	b	NOUN
hjic-751	99	11	)	)	PUNCT
hjic-751	99	12	figure	figure	NOUN
hjic-751	99	13	3	3	NUM
hjic-751	99	14	.	.	PUNCT
hjic-751	99	15	potential	potential	ADJ
hjic-751	99	16	structures	structure	NOUN
hjic-751	99	17	of	of	ADP
hjic-751	99	18	3:2	3:2	NUM
hjic-751	99	19	bisporphyrin	bisporphyrin	NOUN
hjic-751	99	20	:	:	PUNCT
hjic-751	99	21	(	(	PUNCT
hjic-751	99	22	a	a	X
hjic-751	99	23	)	)	PUNCT
hjic-751	99	24	head	head	NOUN
hjic-751	99	25	-	-	PUNCT
hjic-751	99	26	to	to	ADP
hjic-751	99	27	-	-	PUNCT
hjic-751	99	28	head	head	NOUN
hjic-751	99	29	or	or	CCONJ
hjic-751	99	30	(	(	PUNCT
hjic-751	99	31	b	b	NOUN
hjic-751	99	32	)	)	PUNCT
hjic-751	99	33	tail	tail	NOUN
hjic-751	99	34	-	-	PUNCT
hjic-751	99	35	to	to	ADP
hjic-751	99	36	-	-	PUNCT
hjic-751	99	37	tail	tail	NOUN
hjic-751	99	38	[	[	X
hjic-751	99	39	2	2	NUM
hjic-751	99	40	]	]	PUNCT
hjic-751	99	41	.	.	PUNCT
hjic-751	100	1	study	study	NOUN
hjic-751	100	2	of	of	ADP
hjic-751	100	3	the	the	DET
hjic-751	100	4	out	out	NOUN
hjic-751	100	5	-	-	PUNCT
hjic-751	100	6	of	of	ADP
hjic-751	100	7	-	-	PUNCT
hjic-751	100	8	plane	plane	NOUN
hjic-751	100	9	metalloporphyrins	metalloporphyrin	NOUN
hjic-751	100	10	45(1	45(1	NOUN
hjic-751	100	11	)	)	PUNCT
hjic-751	100	12	pp	pp	ADV
hjic-751	100	13	.	.	PUNCT
hjic-751	101	1	29–36	29–36	NUM
hjic-751	101	2	(	(	PUNCT
hjic-751	101	3	2017	2017	NUM
hjic-751	101	4	)	)	PUNCT
hjic-751	101	5	33	33	NUM
hjic-751	101	6	metal	metal	NOUN
hjic-751	101	7	centers	center	NOUN
hjic-751	101	8	,	,	PUNCT
hjic-751	101	9	the	the	DET
hjic-751	101	10	spin	spin	NOUN
hjic-751	101	11	-	-	PUNCT
hjic-751	101	12	orbit	orbit	NOUN
hjic-751	101	13	coupling	coupling	NOUN
hjic-751	101	14	,	,	PUNCT
hjic-751	101	15	as	as	ADP
hjic-751	101	16	an	an	DET
hjic-751	101	17	electronic	electronic	ADJ
hjic-751	101	18	quenching	quenching	NOUN
hjic-751	101	19	effect	effect	NOUN
hjic-751	101	20	,	,	PUNCT
hjic-751	101	21	may	may	AUX
hjic-751	101	22	be	be	AUX
hjic-751	101	23	dominant	dominant	ADJ
hjic-751	101	24	.	.	PUNCT
hjic-751	102	1	whereas	whereas	SCONJ
hjic-751	102	2	for	for	ADP
hjic-751	102	3	typical	typical	ADJ
hjic-751	102	4	out	out	ADP
hjic-751	102	5	-	-	PUNCT
hjic-751	102	6	of	of	ADP
hjic-751	102	7	-	-	PUNCT
hjic-751	102	8	plane	plane	NOUN
hjic-751	102	9	metalloporphyrins	metalloporphyrin	NOUN
hjic-751	102	10	,	,	PUNCT
hjic-751	102	11	the	the	DET
hjic-751	102	12	distortion	distortion	NOUN
hjic-751	102	13	,	,	PUNCT
hjic-751	102	14	as	as	ADP
hjic-751	102	15	a	a	DET
hjic-751	102	16	steric	steric	ADJ
hjic-751	102	17	effect	effect	NOUN
hjic-751	102	18	,	,	PUNCT
hjic-751	102	19	can	can	AUX
hjic-751	102	20	enhance	enhance	VERB
hjic-751	102	21	their	their	PRON
hjic-751	102	22	non	non	ADJ
hjic-751	102	23	-	-	ADJ
hjic-751	102	24	radiative	radiative	ADJ
hjic-751	102	25	decay	decay	NOUN
hjic-751	102	26	.	.	PUNCT
hjic-751	103	1	the	the	DET
hjic-751	103	2	highly	highly	ADV
hjic-751	103	3	distorted	distorted	ADJ
hjic-751	103	4	(	(	PUNCT
hjic-751	103	5	dand	dand	NOUN
hjic-751	103	6	p	p	NOUN
hjic-751	103	7	-	-	PUNCT
hjic-751	103	8	type	type	NOUN
hjic-751	103	9	)	)	PUNCT
hjic-751	103	10	hyperporphyrins	hyperporphyrin	NOUN
hjic-751	103	11	,	,	PUNCT
hjic-751	103	12	the	the	DET
hjic-751	103	13	paramagnetic	paramagnetic	ADJ
hjic-751	103	14	in	in	ADP
hjic-751	103	15	-	-	PUNCT
hjic-751	103	16	plane	plane	NOUN
hjic-751	103	17	complexes	complex	NOUN
hjic-751	103	18	(	(	PUNCT
hjic-751	103	19	e.g.	e.g.	ADV
hjic-751	103	20	feiiitspp3-	feiiitspp3-	VERB
hjic-751	103	21	)	)	PUNCT
hjic-751	103	22	,	,	PUNCT
hjic-751	103	23	as	as	ADV
hjic-751	103	24	well	well	ADV
hjic-751	103	25	as	as	ADP
hjic-751	103	26	the	the	DET
hjic-751	103	27	head	head	NOUN
hjic-751	103	28	-	-	PUNCT
hjic-751	103	29	to	to	ADP
hjic-751	103	30	-	-	PUNCT
hjic-751	103	31	head	head	NOUN
hjic-751	103	32	-	-	PUNCT
hjic-751	103	33	type	type	NOUN
hjic-751	103	34	oop	oop	NOUN
hjic-751	103	35	bisporphyrins	bisporphyrin	NOUN
hjic-751	103	36	{	{	PUNCT
hjic-751	103	37	e.g.	e.g.	ADV
hjic-751	103	38	hgii	hgii	NOUN
hjic-751	103	39	3(tspp)2	3(tspp)2	NUM
hjic-751	103	40	6-	6-	NUM
hjic-751	103	41	}	}	PUNCT
hjic-751	103	42	do	do	AUX
hjic-751	103	43	not	not	PART
hjic-751	103	44	exhibit	exhibit	VERB
hjic-751	103	45	significant	significant	ADJ
hjic-751	103	46	levels	level	NOUN
hjic-751	103	47	of	of	ADP
hjic-751	103	48	luminescence	luminescence	NOUN
hjic-751	103	49	at	at	ADP
hjic-751	103	50	room	room	NOUN
hjic-751	103	51	temperature	temperature	NOUN
hjic-751	103	52	.	.	PUNCT
hjic-751	104	1	conversely	conversely	ADV
hjic-751	104	2	,	,	PUNCT
hjic-751	104	3	the	the	DET
hjic-751	104	4	paramagnetic	paramagnetic	ADJ
hjic-751	104	5	out	out	ADP
hjic-751	104	6	-	-	PUNCT
hjic-751	104	7	of	of	ADP
hjic-751	104	8	-	-	PUNCT
hjic-751	104	9	plane	plane	NOUN
hjic-751	104	10	complexes	complex	NOUN
hjic-751	104	11	(	(	PUNCT
hjic-751	104	12	e.g.	e.g.	ADV
hjic-751	104	13	lniiitspp3-	lniiitspp3-	AUX
hjic-751	104	14	)	)	PUNCT
hjic-751	104	15	possess	possess	VERB
hjic-751	104	16	similar	similar	ADJ
hjic-751	104	17	fluorescence	fluorescence	NOUN
hjic-751	104	18	properties	property	NOUN
hjic-751	104	19	to	to	ADP
hjic-751	104	20	that	that	PRON
hjic-751	104	21	of	of	ADP
hjic-751	104	22	the	the	DET
hjic-751	104	23	diamagnetic	diamagnetic	ADJ
hjic-751	104	24	ones	one	NOUN
hjic-751	104	25	because	because	SCONJ
hjic-751	104	26	a	a	DET
hjic-751	104	27	paramagnetic	paramagnetic	ADJ
hjic-751	104	28	metal	metal	NOUN
hjic-751	104	29	ion	ion	NOUN
hjic-751	104	30	can	can	AUX
hjic-751	104	31	cause	cause	VERB
hjic-751	104	32	the	the	DET
hjic-751	104	33	disappearance	disappearance	NOUN
hjic-751	104	34	of	of	ADP
hjic-751	104	35	fluorescence	fluorescence	NOUN
hjic-751	104	36	by	by	ADP
hjic-751	104	37	spin	spin	NOUN
hjic-751	104	38	-	-	PUNCT
hjic-751	104	39	orbit	orbit	NOUN
hjic-751	104	40	coupling	coupling	NOUN
hjic-751	104	41	only	only	ADV
hjic-751	104	42	if	if	SCONJ
hjic-751	104	43	it	it	PRON
hjic-751	104	44	is	be	AUX
hjic-751	104	45	located	locate	VERB
hjic-751	104	46	in	in	ADP
hjic-751	104	47	the	the	DET
hjic-751	104	48	plane	plane	NOUN
hjic-751	104	49	.	.	PUNCT
hjic-751	105	1	in	in	ADP
hjic-751	105	2	the	the	DET
hjic-751	105	3	oop	oop	NOUN
hjic-751	105	4	position	position	NOUN
hjic-751	105	5	,	,	PUNCT
hjic-751	105	6	it	it	PRON
hjic-751	105	7	is	be	AUX
hjic-751	105	8	not	not	PART
hjic-751	105	9	able	able	ADJ
hjic-751	105	10	to	to	PART
hjic-751	105	11	perturb	perturb	VERB
hjic-751	105	12	as	as	ADV
hjic-751	105	13	efficiently	efficiently	ADV
hjic-751	105	14	the	the	DET
hjic-751	105	15	molecule	molecule	NOUN
hjic-751	105	16	orbitals	orbital	NOUN
hjic-751	105	17	of	of	ADP
hjic-751	105	18	the	the	DET
hjic-751	105	19	macrocycle	macrocycle	NOUN
hjic-751	105	20	that	that	PRON
hjic-751	105	21	result	result	VERB
hjic-751	105	22	in	in	ADP
hjic-751	105	23	the	the	DET
hjic-751	105	24	common	common	ADJ
hjic-751	105	25	absorption	absorption	NOUN
hjic-751	105	26	and	and	CCONJ
hjic-751	105	27	emission	emission	VERB
hjic-751	105	28	out	out	ADP
hjic-751	105	29	-	-	PUNCT
hjic-751	105	30	of	of	ADP
hjic-751	105	31	-	-	PUNCT
hjic-751	105	32	plane	plane	NOUN
hjic-751	105	33	characteristics	characteristic	NOUN
hjic-751	105	34	[	[	X
hjic-751	105	35	1	1	NUM
hjic-751	105	36	-	-	SYM
hjic-751	105	37	2	2	NUM
hjic-751	105	38	,	,	PUNCT
hjic-751	105	39	9	9	NUM
hjic-751	105	40	]	]	PUNCT
hjic-751	105	41	.	.	PUNCT
hjic-751	106	1	lanthanide(iii	lanthanide(iii	NOUN
hjic-751	106	2	)	)	PUNCT
hjic-751	106	3	bisporphyrins	bisporphyrin	NOUN
hjic-751	106	4	{	{	PUNCT
hjic-751	106	5	lniii	lniii	VERB
hjic-751	106	6	3(tspp)2	3(tspp)2	NUM
hjic-751	106	7	3-	3-	NOUN
hjic-751	106	8	}	}	PUNCT
hjic-751	106	9	have	have	VERB
hjic-751	106	10	many	many	ADJ
hjic-751	106	11	similarities	similarity	NOUN
hjic-751	106	12	in	in	ADP
hjic-751	106	13	terms	term	NOUN
hjic-751	106	14	of	of	ADP
hjic-751	106	15	absorption	absorption	NOUN
hjic-751	106	16	and	and	CCONJ
hjic-751	106	17	emission	emission	NOUN
hjic-751	106	18	properties	property	NOUN
hjic-751	106	19	to	to	ADP
hjic-751	106	20	those	those	PRON
hjic-751	106	21	of	of	ADP
hjic-751	106	22	monoporphyrin	monoporphyrin	NOUN
hjic-751	106	23	complexes	complex	NOUN
hjic-751	106	24	(	(	PUNCT
hjic-751	106	25	lniiitspp3-	lniiitspp3-	NOUN
hjic-751	106	26	)	)	PUNCT
hjic-751	106	27	.	.	PUNCT
hjic-751	107	1	these	these	PRON
hjic-751	107	2	may	may	AUX
hjic-751	107	3	only	only	ADV
hjic-751	107	4	originate	originate	VERB
hjic-751	107	5	from	from	ADP
hjic-751	107	6	the	the	DET
hjic-751	107	7	very	very	ADV
hjic-751	107	8	weak	weak	ADJ
hjic-751	107	9	π	π	NOUN
hjic-751	107	10	–	–	PUNCT
hjic-751	107	11	π	π	NOUN
hjic-751	107	12	interactions	interaction	NOUN
hjic-751	107	13	between	between	ADP
hjic-751	107	14	the	the	DET
hjic-751	107	15	macrocycles	macrocycle	NOUN
hjic-751	107	16	in	in	ADP
hjic-751	107	17	the	the	DET
hjic-751	107	18	tail	tail	NOUN
hjic-751	107	19	-	-	PUNCT
hjic-751	107	20	to	to	ADP
hjic-751	107	21	-	-	PUNCT
hjic-751	107	22	tail	tail	NOUN
hjic-751	107	23	-	-	PUNCT
hjic-751	107	24	type	type	NOUN
hjic-751	107	25	aggregations	aggregation	NOUN
hjic-751	107	26	(	(	PUNCT
hjic-751	107	27	fig.3	fig.3	PROPN
hjic-751	107	28	)	)	PUNCT
hjic-751	108	1	[	[	X
hjic-751	108	2	1	1	NUM
hjic-751	108	3	-	-	SYM
hjic-751	108	4	2	2	NUM
hjic-751	108	5	,	,	PUNCT
hjic-751	108	6	11	11	NUM
hjic-751	108	7	-	-	SYM
hjic-751	108	8	13	13	NUM
hjic-751	108	9	]	]	PUNCT
hjic-751	108	10	.	.	PUNCT
hjic-751	109	1	3.4	3.4	NUM
hjic-751	109	2	.	.	PUNCT
hjic-751	109	3	photochemistry	photochemistry	NOUN
hjic-751	109	4	porphyrin	porphyrin	NOUN
hjic-751	109	5	derivatives	derivative	NOUN
hjic-751	109	6	are	be	AUX
hjic-751	109	7	the	the	DET
hjic-751	109	8	main	main	ADJ
hjic-751	109	9	components	component	NOUN
hjic-751	109	10	of	of	ADP
hjic-751	109	11	photosynthesis	photosynthesis	NOUN
hjic-751	109	12	,	,	PUNCT
hjic-751	109	13	synthetically	synthetically	ADV
hjic-751	109	14	as	as	ADV
hjic-751	109	15	well	well	ADV
hjic-751	109	16	.	.	PUNCT
hjic-751	110	1	since	since	SCONJ
hjic-751	110	2	the	the	DET
hjic-751	110	3	overall	overall	ADJ
hjic-751	110	4	quantum	quantum	ADJ
hjic-751	110	5	yield	yield	NOUN
hjic-751	110	6	of	of	ADP
hjic-751	110	7	fluorescence	fluorescence	NOUN
hjic-751	110	8	and	and	CCONJ
hjic-751	110	9	intersystem	intersystem	NOUN
hjic-751	110	10	crossing	crossing	NOUN
hjic-751	110	11	resulting	result	VERB
hjic-751	110	12	in	in	ADP
hjic-751	110	13	the	the	DET
hjic-751	110	14	formation	formation	NOUN
hjic-751	110	15	of	of	ADP
hjic-751	110	16	triplet	triplet	NOUN
hjic-751	110	17	states	state	NOUN
hjic-751	110	18	is	be	AUX
hjic-751	110	19	in	in	ADP
hjic-751	110	20	excess	excess	NOUN
hjic-751	110	21	of	of	ADP
hjic-751	110	22	95	95	NUM
hjic-751	110	23	%	%	NOUN
hjic-751	110	24	,	,	PUNCT
hjic-751	110	25	merely	merely	ADV
hjic-751	110	26	a	a	DET
hjic-751	110	27	slight	slight	ADJ
hjic-751	110	28	proportion	proportion	NOUN
hjic-751	110	29	of	of	ADP
hjic-751	110	30	excitation	excitation	NOUN
hjic-751	110	31	energy	energy	NOUN
hjic-751	110	32	is	be	AUX
hjic-751	110	33	dissipated	dissipate	VERB
hjic-751	110	34	as	as	ADP
hjic-751	110	35	heat	heat	NOUN
hjic-751	110	36	from	from	ADP
hjic-751	110	37	singlet	singlet	ADJ
hjic-751	110	38	states	state	NOUN
hjic-751	110	39	.	.	PUNCT
hjic-751	111	1	this	this	DET
hjic-751	111	2	ratio	ratio	NOUN
hjic-751	111	3	is	be	AUX
hjic-751	111	4	the	the	DET
hjic-751	111	5	major	major	ADJ
hjic-751	111	6	reason	reason	NOUN
hjic-751	111	7	why	why	SCONJ
hjic-751	111	8	porphyrins	porphyrin	NOUN
hjic-751	111	9	are	be	AUX
hjic-751	111	10	efficient	efficient	ADJ
hjic-751	111	11	in	in	ADP
hjic-751	111	12	terms	term	NOUN
hjic-751	111	13	of	of	ADP
hjic-751	111	14	optical	optical	ADJ
hjic-751	111	15	sensations	sensation	NOUN
hjic-751	111	16	and	and	CCONJ
hjic-751	111	17	photosensitizations	photosensitization	NOUN
hjic-751	111	18	.	.	PUNCT
hjic-751	112	1	free	free	ADJ
hjic-751	112	2	-	-	PUNCT
hjic-751	112	3	base	base	NOUN
hjic-751	112	4	and	and	CCONJ
hjic-751	112	5	kinetically	kinetically	ADV
hjic-751	112	6	inert	inert	ADJ
hjic-751	112	7	in	in	ADP
hjic-751	112	8	-	-	PUNCT
hjic-751	112	9	plane	plane	NOUN
hjic-751	112	10	metalloporphyrins	metalloporphyrin	NOUN
hjic-751	112	11	may	may	AUX
hjic-751	112	12	be	be	AUX
hjic-751	112	13	appropriate	appropriate	ADJ
hjic-751	112	14	candidates	candidate	NOUN
hjic-751	112	15	to	to	PART
hjic-751	112	16	be	be	AUX
hjic-751	112	17	applied	apply	VERB
hjic-751	112	18	in	in	ADP
hjic-751	112	19	photocatalytic	photocatalytic	ADJ
hjic-751	112	20	systems	system	NOUN
hjic-751	112	21	based	base	VERB
hjic-751	112	22	on	on	ADP
hjic-751	112	23	outer	outer	ADJ
hjic-751	112	24	-	-	PUNCT
hjic-751	112	25	sphere	sphere	NOUN
hjic-751	112	26	electron	electron	NOUN
hjic-751	112	27	transfer	transfer	NOUN
hjic-751	112	28	.	.	PUNCT
hjic-751	113	1	d	d	X
hjic-751	113	2	-	-	PUNCT
hjic-751	113	3	type	type	NOUN
hjic-751	113	4	hyperporphyrins	hyperporphyrin	NOUN
hjic-751	113	5	can	can	AUX
hjic-751	113	6	be	be	AUX
hjic-751	113	7	particularly	particularly	ADV
hjic-751	113	8	promising	promise	VERB
hjic-751	113	9	from	from	ADP
hjic-751	113	10	this	this	DET
hjic-751	113	11	viewpoint	viewpoint	NOUN
hjic-751	113	12	owing	owe	VERB
hjic-751	113	13	to	to	ADP
hjic-751	113	14	their	their	PRON
hjic-751	113	15	distorted	distort	VERB
hjic-751	113	16	structure	structure	NOUN
hjic-751	113	17	which	which	PRON
hjic-751	113	18	may	may	AUX
hjic-751	113	19	enhance	enhance	VERB
hjic-751	113	20	the	the	DET
hjic-751	113	21	(	(	PUNCT
hjic-751	113	22	photo)redox	photo)redox	ADJ
hjic-751	113	23	reactivity	reactivity	NOUN
hjic-751	113	24	of	of	ADP
hjic-751	113	25	these	these	DET
hjic-751	113	26	coordination	coordination	NOUN
hjic-751	113	27	compounds	compound	NOUN
hjic-751	113	28	.	.	PUNCT
hjic-751	114	1	in	in	ADP
hjic-751	114	2	the	the	DET
hjic-751	114	3	presence	presence	NOUN
hjic-751	114	4	of	of	ADP
hjic-751	114	5	a	a	DET
hjic-751	114	6	suitable	suitable	ADJ
hjic-751	114	7	electron	electron	NOUN
hjic-751	114	8	acceptor	acceptor	NOUN
hjic-751	114	9	(	(	PUNCT
hjic-751	114	10	methylviologen	methylviologen	NOUN
hjic-751	114	11	,	,	PUNCT
hjic-751	114	12	mv2	mv2	PROPN
hjic-751	114	13	+	+	NOUN
hjic-751	114	14	)	)	PUNCT
hjic-751	114	15	and	and	CCONJ
hjic-751	114	16	donor	donor	NOUN
hjic-751	114	17	(	(	PUNCT
hjic-751	114	18	e.g.	e.g.	ADV
hjic-751	114	19	triethanolamine	triethanolamine	NOUN
hjic-751	114	20	,	,	PUNCT
hjic-751	114	21	teoa	teoa	PROPN
hjic-751	114	22	)	)	PUNCT
hjic-751	114	23	,	,	PUNCT
hjic-751	114	24	these	these	DET
hjic-751	114	25	complexes	complex	NOUN
hjic-751	114	26	proved	prove	VERB
hjic-751	114	27	to	to	PART
hjic-751	114	28	be	be	AUX
hjic-751	114	29	efficaciousl	efficaciousl	PRON
hjic-751	114	30	photocatalysts	photocatalyst	NOUN
hjic-751	114	31	that	that	PRON
hjic-751	114	32	transfer	transfer	VERB
hjic-751	114	33	electrons	electron	NOUN
hjic-751	114	34	between	between	ADP
hjic-751	114	35	the	the	DET
hjic-751	114	36	ground	ground	NOUN
hjic-751	114	37	-	-	PUNCT
hjic-751	114	38	state	state	NOUN
hjic-751	114	39	reactants	reactant	NOUN
hjic-751	114	40	through	through	ADP
hjic-751	114	41	an	an	DET
hjic-751	114	42	outersphere	outersphere	ADJ
hjic-751	114	43	mechanism	mechanism	NOUN
hjic-751	114	44	,	,	PUNCT
hjic-751	114	45	generating	generate	VERB
hjic-751	114	46	the	the	DET
hjic-751	114	47	mv•+	mv•+	NOUN
hjic-751	114	48	radical	radical	ADJ
hjic-751	114	49	cation	cation	NOUN
hjic-751	114	50	.	.	PUNCT
hjic-751	115	1	this	this	DET
hjic-751	115	2	system	system	NOUN
hjic-751	115	3	can	can	AUX
hjic-751	115	4	be	be	AUX
hjic-751	115	5	applied	apply	VERB
hjic-751	115	6	for	for	ADP
hjic-751	115	7	the	the	DET
hjic-751	115	8	production	production	NOUN
hjic-751	115	9	of	of	ADP
hjic-751	115	10	hydrogen	hydrogen	NOUN
hjic-751	115	11	from	from	ADP
hjic-751	115	12	water	water	NOUN
hjic-751	115	13	[	[	X
hjic-751	115	14	2	2	NUM
hjic-751	115	15	,	,	PUNCT
hjic-751	115	16	5	5	NUM
hjic-751	115	17	-	-	SYM
hjic-751	115	18	7	7	NUM
hjic-751	115	19	]	]	PUNCT
hjic-751	115	20	.	.	PUNCT
hjic-751	116	1	contrarily	contrarily	ADV
hjic-751	116	2	,	,	PUNCT
hjic-751	116	3	the	the	DET
hjic-751	116	4	inner	inner	ADJ
hjic-751	116	5	-	-	PUNCT
hjic-751	116	6	sphere	sphere	NOUN
hjic-751	116	7	photoredox	photoredox	NOUN
hjic-751	116	8	reactions	reaction	NOUN
hjic-751	116	9	are	be	AUX
hjic-751	116	10	characteristic	characteristic	ADJ
hjic-751	116	11	of	of	ADP
hjic-751	116	12	the	the	DET
hjic-751	116	13	out	out	NOUN
hjic-751	116	14	-	-	PUNCT
hjic-751	116	15	of	of	ADP
hjic-751	116	16	-	-	PUNCT
hjic-751	116	17	plane	plane	NOUN
hjic-751	116	18	metalloporphyrins	metalloporphyrin	NOUN
hjic-751	116	19	because	because	SCONJ
hjic-751	116	20	of	of	ADP
hjic-751	116	21	this	this	DET
hjic-751	116	22	special	special	ADJ
hjic-751	116	23	coordination	coordination	NOUN
hjic-751	116	24	(	(	PUNCT
hjic-751	116	25	scheme	scheme	NOUN
hjic-751	116	26	2	2	NUM
hjic-751	116	27	):	):	PUNCT
hjic-751	116	28	an	an	DET
hjic-751	116	29	irreversible	irreversible	ADJ
hjic-751	116	30	photoinduced	photoinduce	VERB
hjic-751	116	31	charge	charge	NOUN
hjic-751	116	32	-	-	PUNCT
hjic-751	116	33	transfer	transfer	NOUN
hjic-751	116	34	from	from	ADP
hjic-751	116	35	the	the	DET
hjic-751	116	36	ligand	ligand	NOUN
hjic-751	116	37	to	to	ADP
hjic-751	116	38	the	the	DET
hjic-751	116	39	metal	metal	NOUN
hjic-751	116	40	center	center	NOUN
hjic-751	116	41	(	(	PUNCT
hjic-751	116	42	ligand	ligand	NOUN
hjic-751	116	43	-	-	PUNCT
hjic-751	116	44	to	to	ADP
hjic-751	116	45	-	-	PUNCT
hjic-751	116	46	metal	metal	NOUN
hjic-751	116	47	charge	charge	NOUN
hjic-751	116	48	transfer	transfer	NOUN
hjic-751	116	49	,	,	PUNCT
hjic-751	116	50	lmct	lmct	NOUN
hjic-751	116	51	)	)	PUNCT
hjic-751	116	52	improves	improve	VERB
hjic-751	116	53	the	the	DET
hjic-751	116	54	efficiency	efficiency	NOUN
hjic-751	116	55	of	of	ADP
hjic-751	116	56	charge	charge	NOUN
hjic-751	116	57	separation	separation	NOUN
hjic-751	116	58	,	,	PUNCT
hjic-751	116	59	which	which	PRON
hjic-751	116	60	allows	allow	VERB
hjic-751	116	61	their	their	PRON
hjic-751	116	62	utilization	utilization	NOUN
hjic-751	116	63	as	as	ADP
hjic-751	116	64	catalysts	catalyst	NOUN
hjic-751	116	65	in	in	ADP
hjic-751	116	66	cyclic	cyclic	ADJ
hjic-751	116	67	processes	process	NOUN
hjic-751	116	68	for	for	ADP
hjic-751	116	69	the	the	DET
hjic-751	116	70	synthesis	synthesis	NOUN
hjic-751	116	71	of	of	ADP
hjic-751	116	72	chemicals	chemical	NOUN
hjic-751	116	73	capable	capable	ADJ
hjic-751	116	74	of	of	ADP
hjic-751	116	75	conserving	conserve	VERB
hjic-751	116	76	light	light	ADJ
hjic-751	116	77	energy	energy	NOUN
hjic-751	116	78	,	,	PUNCT
hjic-751	116	79	hopefully	hopefully	ADV
hjic-751	116	80	in	in	ADP
hjic-751	116	81	terms	term	NOUN
hjic-751	116	82	of	of	ADP
hjic-751	116	83	the	the	DET
hjic-751	116	84	photochemical	photochemical	ADJ
hjic-751	116	85	cleavage	cleavage	NOUN
hjic-751	116	86	of	of	ADP
hjic-751	116	87	water	water	NOUN
hjic-751	116	88	.	.	PUNCT
hjic-751	117	1	due	due	ADP
hjic-751	117	2	to	to	ADP
hjic-751	117	3	photoinduced	photoinduced	ADJ
hjic-751	117	4	lmct	lmct	AUX
hjic-751	117	5	the	the	DET
hjic-751	117	6	charge	charge	NOUN
hjic-751	117	7	of	of	ADP
hjic-751	117	8	the	the	DET
hjic-751	117	9	metal	metal	NOUN
hjic-751	117	10	center	center	NOUN
hjic-751	117	11	decreases	decrease	VERB
hjic-751	117	12	and	and	CCONJ
hjic-751	117	13	its	its	PRON
hjic-751	117	14	size	size	NOUN
hjic-751	117	15	increases	increase	NOUN
hjic-751	117	16	,	,	PUNCT
hjic-751	117	17	overall	overall	ADV
hjic-751	117	18	its	its	PRON
hjic-751	117	19	charge	charge	NOUN
hjic-751	117	20	density	density	NOUN
hjic-751	117	21	diminishes	diminish	VERB
hjic-751	117	22	,	,	PUNCT
hjic-751	117	23	hence	hence	ADV
hjic-751	117	24	,	,	PUNCT
hjic-751	117	25	the	the	DET
hjic-751	117	26	coordinative	coordinative	ADJ
hjic-751	117	27	bonds	bond	NOUN
hjic-751	117	28	can	can	AUX
hjic-751	117	29	easily	easily	ADV
hjic-751	117	30	split	split	VERB
hjic-751	117	31	.	.	PUNCT
hjic-751	118	1	the	the	DET
hjic-751	118	2	reduced	reduce	VERB
hjic-751	118	3	metal	metal	NOUN
hjic-751	118	4	ion	ion	NOUN
hjic-751	118	5	can	can	AUX
hjic-751	118	6	leave	leave	VERB
hjic-751	118	7	the	the	DET
hjic-751	118	8	cavity	cavity	NOUN
hjic-751	118	9	,	,	PUNCT
hjic-751	118	10	primarily	primarily	ADV
hjic-751	118	11	in	in	ADP
hjic-751	118	12	polar	polar	ADJ
hjic-751	118	13	solvents	solvent	NOUN
hjic-751	118	14	,	,	PUNCT
hjic-751	118	15	and	and	CCONJ
hjic-751	118	16	induce	induce	VERB
hjic-751	118	17	further	further	ADJ
hjic-751	118	18	redox	redox	ADJ
hjic-751	118	19	reactions	reaction	NOUN
hjic-751	118	20	.	.	PUNCT
hjic-751	119	1	the	the	DET
hjic-751	119	2	latter	latter	ADJ
hjic-751	119	3	processes	process	NOUN
hjic-751	119	4	strongly	strongly	ADV
hjic-751	119	5	depend	depend	VERB
hjic-751	119	6	on	on	ADP
hjic-751	119	7	the	the	DET
hjic-751	119	8	stability	stability	NOUN
hjic-751	119	9	of	of	ADP
hjic-751	119	10	the	the	DET
hjic-751	119	11	reduced	reduce	VERB
hjic-751	119	12	metalion	metalion	NOUN
hjic-751	119	13	in	in	ADP
hjic-751	119	14	the	the	DET
hjic-751	119	15	actual	actual	ADJ
hjic-751	119	16	medium	medium	NOUN
hjic-751	119	17	.	.	PUNCT
hjic-751	120	1	the	the	DET
hjic-751	120	2	oxidized	oxidize	VERB
hjic-751	120	3	and	and	CCONJ
hjic-751	120	4	metal	metal	NOUN
hjic-751	120	5	-	-	PUNCT
hjic-751	120	6	free	free	ADJ
hjic-751	120	7	(	(	PUNCT
hjic-751	120	8	cat)ionic	cat)ionic	ADJ
hjic-751	120	9	radical	radical	NOUN
hjic-751	120	10	of	of	ADP
hjic-751	120	11	porphyrin	porphyrin	NOUN
hjic-751	120	12	is	be	AUX
hjic-751	120	13	a	a	DET
hjic-751	120	14	very	very	ADV
hjic-751	120	15	strong	strong	ADJ
hjic-751	120	16	base	base	NOUN
hjic-751	120	17	:	:	PUNCT
hjic-751	120	18	it	it	PRON
hjic-751	120	19	is	be	AUX
hjic-751	120	20	immediately	immediately	ADV
hjic-751	120	21	protonated	protonate	VERB
hjic-751	120	22	and	and	CCONJ
hjic-751	120	23	forms	form	VERB
hjic-751	120	24	the	the	DET
hjic-751	120	25	free	free	ADJ
hjic-751	120	26	-	-	PUNCT
hjic-751	120	27	base	base	NOUN
hjic-751	120	28	radical	radical	NOUN
hjic-751	120	29	,	,	PUNCT
hjic-751	120	30	which	which	PRON
hjic-751	120	31	is	be	AUX
hjic-751	120	32	a	a	DET
hjic-751	120	33	long	long	ADV
hjic-751	120	34	-	-	PUNCT
hjic-751	120	35	lived	live	VERB
hjic-751	120	36	and	and	CCONJ
hjic-751	120	37	rather	rather	ADV
hjic-751	120	38	strong	strong	ADJ
hjic-751	120	39	electron	electron	NOUN
hjic-751	120	40	acceptor	acceptor	NOUN
hjic-751	120	41	,	,	PUNCT
hjic-751	120	42	especally	especally	ADV
hjic-751	120	43	in	in	ADP
hjic-751	120	44	deaerated	deaerate	VERB
hjic-751	120	45	solutions	solution	NOUN
hjic-751	120	46	.	.	PUNCT
hjic-751	121	1	since	since	SCONJ
hjic-751	121	2	it	it	PRON
hjic-751	121	3	would	would	AUX
hjic-751	121	4	only	only	ADV
hjic-751	121	5	oxidize	oxidize	VERB
hjic-751	121	6	water	water	NOUN
hjic-751	121	7	to	to	PART
hjic-751	121	8	oxygen	oxygen	VERB
hjic-751	121	9	at	at	ADP
hjic-751	121	10	higher	high	ADJ
hjic-751	121	11	phs	phs	NOUN
hjic-751	121	12	,	,	PUNCT
hjic-751	121	13	a	a	DET
hjic-751	121	14	slightly	slightly	ADV
hjic-751	121	15	more	more	ADJ
hjic-751	121	16	efficent	efficent	ADJ
hjic-751	121	17	reducer	reducer	NOUN
hjic-751	121	18	(	(	PUNCT
hjic-751	121	19	such	such	ADJ
hjic-751	121	20	as	as	ADP
hjic-751	121	21	alcohols	alcohol	NOUN
hjic-751	121	22	or	or	CCONJ
hjic-751	121	23	aldehydes	aldehyde	NOUN
hjic-751	121	24	of	of	ADP
hjic-751	121	25	low	low	ADJ
hjic-751	121	26	molecular	molecular	ADJ
hjic-751	121	27	weight	weight	NOUN
hjic-751	121	28	)	)	PUNCT
hjic-751	121	29	is	be	AUX
hjic-751	121	30	needed	need	VERB
hjic-751	121	31	,	,	PUNCT
hjic-751	121	32	from	from	ADP
hjic-751	121	33	which	which	PRON
hjic-751	121	34	useful	useful	ADJ
hjic-751	121	35	byproducts	byproduct	NOUN
hjic-751	121	36	can	can	AUX
hjic-751	121	37	be	be	AUX
hjic-751	121	38	produced	produce	VERB
hjic-751	121	39	in	in	ADP
hjic-751	121	40	terms	term	NOUN
hjic-751	121	41	of	of	ADP
hjic-751	121	42	photocatalytic	photocatalytic	ADJ
hjic-751	121	43	hydrogen	hydrogen	NOUN
hjic-751	121	44	generation	generation	NOUN
hjic-751	121	45	.	.	PUNCT
hjic-751	122	1	in	in	ADP
hjic-751	122	2	the	the	DET
hjic-751	122	3	absence	absence	NOUN
hjic-751	122	4	of	of	ADP
hjic-751	122	5	any	any	DET
hjic-751	122	6	electron	electron	NOUN
hjic-751	122	7	donor	donor	NOUN
hjic-751	122	8	that	that	PRON
hjic-751	122	9	promotes	promote	VERB
hjic-751	122	10	the	the	DET
hjic-751	122	11	regeneration	regeneration	NOUN
hjic-751	122	12	of	of	ADP
hjic-751	122	13	the	the	DET
hjic-751	122	14	porphyrin	porphyrin	NOUN
hjic-751	122	15	,	,	PUNCT
hjic-751	122	16	it	it	PRON
hjic-751	122	17	undergoes	undergo	VERB
hjic-751	122	18	the	the	DET
hjic-751	122	19	primary	primary	ADJ
hjic-751	122	20	photochemical	photochemical	ADJ
hjic-751	122	21	processes	process	NOUN
hjic-751	122	22	;	;	PUNCT
hjic-751	122	23	an	an	DET
hjic-751	122	24	overall	overall	ADJ
hjic-751	122	25	four	four	NUM
hjic-751	122	26	-	-	PUNCT
hjic-751	122	27	electron	electron	NOUN
hjic-751	122	28	oxidation	oxidation	NOUN
hjic-751	122	29	involving	involve	VERB
hjic-751	122	30	a	a	DET
hjic-751	122	31	ring	ring	NOUN
hjic-751	122	32	-	-	PUNCT
hjic-751	122	33	cleavage	cleavage	NOUN
hjic-751	122	34	,	,	PUNCT
hjic-751	122	35	the	the	DET
hjic-751	122	36	end	end	NOUN
hjic-751	122	37	-	-	PUNCT
hjic-751	122	38	product	product	NOUN
hjic-751	122	39	of	of	ADP
hjic-751	122	40	which	which	PRON
hjic-751	122	41	is	be	AUX
hjic-751	122	42	a	a	DET
hjic-751	122	43	dioxotetrapyrrole	dioxotetrapyrrole	ADJ
hjic-751	122	44	derivative	derivative	NOUN
hjic-751	122	45	(	(	PUNCT
hjic-751	122	46	bilindione	bilindione	NOUN
hjic-751	122	47	)	)	PUNCT
hjic-751	122	48	.	.	PUNCT
hjic-751	123	1	this	this	DET
hjic-751	123	2	ring	ring	NOUN
hjic-751	123	3	-	-	PUNCT
hjic-751	123	4	opening	opening	NOUN
hjic-751	123	5	process	process	NOUN
hjic-751	123	6	can	can	AUX
hjic-751	123	7	be	be	AUX
hjic-751	123	8	followed	follow	VERB
hjic-751	123	9	by	by	ADP
hjic-751	123	10	spectrophotometry	spectrophotometry	NOUN
hjic-751	123	11	owing	owe	VERB
hjic-751	123	12	to	to	ADP
hjic-751	123	13	the	the	DET
hjic-751	123	14	disappearance	disappearance	NOUN
hjic-751	123	15	of	of	ADP
hjic-751	123	16	the	the	DET
hjic-751	123	17	soret	soret	NOUN
hjic-751	123	18	band	band	NOUN
hjic-751	123	19	,	,	PUNCT
hjic-751	123	20	as	as	ADV
hjic-751	123	21	well	well	ADV
hjic-751	123	22	as	as	ADP
hjic-751	123	23	the	the	DET
hjic-751	123	24	typical	typical	ADJ
hjic-751	123	25	change	change	NOUN
hjic-751	123	26	in	in	ADP
hjic-751	123	27	the	the	DET
hjic-751	123	28	region	region	NOUN
hjic-751	123	29	of	of	ADP
hjic-751	123	30	q	q	PROPN
hjic-751	123	31	bands	band	NOUN
hjic-751	123	32	[	[	X
hjic-751	123	33	2	2	NUM
hjic-751	123	34	,	,	PUNCT
hjic-751	123	35	4	4	NUM
hjic-751	123	36	,	,	PUNCT
hjic-751	123	37	8	8	NUM
hjic-751	123	38	-	-	SYM
hjic-751	123	39	16	16	NUM
hjic-751	123	40	]	]	PUNCT
hjic-751	123	41	.	.	PUNCT
hjic-751	124	1	photochemical	photochemical	ADJ
hjic-751	124	2	quantum	quantum	ADJ
hjic-751	124	3	yields	yield	NOUN
hjic-751	124	4	of	of	ADP
hjic-751	124	5	this	this	DET
hjic-751	124	6	ring	ring	NOUN
hjic-751	124	7	-	-	PUNCT
hjic-751	124	8	opening	open	VERB
hjic-751	124	9	reaction	reaction	NOUN
hjic-751	124	10	(	(	PUNCT
hjic-751	124	11	without	without	ADP
hjic-751	124	12	regeneration	regeneration	NOUN
hjic-751	124	13	)	)	PUNCT
hjic-751	124	14	are	be	AUX
hjic-751	124	15	about	about	ADV
hjic-751	124	16	2	2	NUM
hjic-751	124	17	-	-	SYM
hjic-751	124	18	3	3	NUM
hjic-751	124	19	orders	order	NOUN
hjic-751	124	20	of	of	ADP
hjic-751	124	21	magnitude	magnitude	NOUN
hjic-751	124	22	higher	high	ADJ
hjic-751	124	23	for	for	ADP
hjic-751	124	24	the	the	DET
hjic-751	124	25	out	out	ADJ
hjic-751	124	26	-	-	PUNCT
hjic-751	124	27	of	of	ADP
hjic-751	124	28	-	-	PUNCT
hjic-751	124	29	plane	plane	NOUN
hjic-751	124	30	complexes	complex	NOUN
hjic-751	124	31	(	(	PUNCT
hjic-751	124	32	10	10	NUM
hjic-751	124	33	-	-	SYM
hjic-751	124	34	4	4	NUM
hjic-751	124	35	–	–	PUNCT
hjic-751	124	36	10	10	NUM
hjic-751	124	37	-	-	SYM
hjic-751	124	38	2	2	NUM
hjic-751	124	39	)	)	PUNCT
hjic-751	124	40	than	than	ADP
hjic-751	124	41	for	for	ADP
hjic-751	124	42	the	the	DET
hjic-751	124	43	free	free	ADJ
hjic-751	124	44	-	-	PUNCT
hjic-751	124	45	base	base	NOUN
hjic-751	124	46	and	and	CCONJ
hjic-751	124	47	in	in	ADP
hjic-751	124	48	-	-	PUNCT
hjic-751	124	49	plane	plane	NOUN
hjic-751	124	50	metalloporphyrins	metalloporphyrin	NOUN
hjic-751	124	51	(	(	PUNCT
hjic-751	124	52	10	10	NUM
hjic-751	124	53	-	-	SYM
hjic-751	124	54	6	6	NUM
hjic-751	124	55	–	–	PUNCT
hjic-751	124	56	10	10	NUM
hjic-751	124	57	-	-	SYM
hjic-751	124	58	5	5	NUM
hjic-751	124	59	)	)	PUNCT
hjic-751	124	60	.	.	PUNCT
hjic-751	125	1	in	in	ADP
hjic-751	125	2	addition	addition	NOUN
hjic-751	125	3	,	,	PUNCT
hjic-751	125	4	in	in	ADP
hjic-751	125	5	the	the	DET
hjic-751	125	6	case	case	NOUN
hjic-751	125	7	of	of	ADP
hjic-751	125	8	out	out	ADV
hjic-751	125	9	-	-	PUNCT
hjic-751	125	10	of	of	ADP
hjic-751	125	11	-	-	PUNCT
hjic-751	125	12	plane	plane	NOUN
hjic-751	125	13	complexes	complex	NOUN
hjic-751	125	14	,	,	PUNCT
hjic-751	125	15	photoinduced	photoinduce	VERB
hjic-751	125	16	dissociation	dissociation	NOUN
hjic-751	125	17	in	in	ADP
hjic-751	125	18	scheme	scheme	NOUN
hjic-751	125	19	2	2	NUM
hjic-751	125	20	.	.	PUNCT
hjic-751	125	21	simplified	simplify	VERB
hjic-751	125	22	demonstration	demonstration	NOUN
hjic-751	125	23	of	of	ADP
hjic-751	125	24	the	the	DET
hjic-751	125	25	mechanism	mechanism	NOUN
hjic-751	125	26	for	for	ADP
hjic-751	125	27	the	the	DET
hjic-751	125	28	inner	inner	ADJ
hjic-751	125	29	-	-	PUNCT
hjic-751	125	30	sphere	sphere	NOUN
hjic-751	125	31	photoredox	photoredox	NOUN
hjic-751	125	32	reaction	reaction	NOUN
hjic-751	125	33	of	of	ADP
hjic-751	125	34	an	an	DET
hjic-751	125	35	out	out	ADJ
hjic-751	125	36	-	-	PUNCT
hjic-751	125	37	ofplane	ofplane	NOUN
hjic-751	125	38	metalloporphyrin	metalloporphyrin	NOUN
hjic-751	125	39	[	[	X
hjic-751	125	40	8	8	NUM
hjic-751	125	41	]	]	PUNCT
hjic-751	125	42	.	.	PUNCT
hjic-751	126	1	valicsek	valicsek	PROPN
hjic-751	126	2	,	,	PUNCT
hjic-751	126	3	kiss	kiss	PROPN
hjic-751	126	4	,	,	PUNCT
hjic-751	126	5	fodor	fodor	PROPN
hjic-751	126	6	,	,	PUNCT
hjic-751	126	7	imran	imran	ADJ
hjic-751	126	8	,	,	PUNCT
hjic-751	126	9	and	and	CCONJ
hjic-751	126	10	horváth	horváth	PROPN
hjic-751	126	11	hungarian	hungarian	ADJ
hjic-751	126	12	journal	journal	NOUN
hjic-751	126	13	of	of	ADP
hjic-751	126	14	industry	industry	NOUN
hjic-751	126	15	and	and	CCONJ
hjic-751	126	16	chemistry	chemistry	NOUN
hjic-751	126	17	34	34	NUM
hjic-751	126	18	the	the	DET
hjic-751	126	19	absence	absence	NOUN
hjic-751	126	20	of	of	ADP
hjic-751	126	21	a	a	DET
hjic-751	126	22	redox	redox	ADJ
hjic-751	126	23	reaction	reaction	NOUN
hjic-751	126	24	can	can	AUX
hjic-751	126	25	occur	occur	VERB
hjic-751	126	26	,	,	PUNCT
hjic-751	126	27	originating	originate	VERB
hjic-751	126	28	from	from	ADP
hjic-751	126	29	their	their	PRON
hjic-751	126	30	lability	lability	NOUN
hjic-751	126	31	,	,	PUNCT
hjic-751	126	32	and	and	CCONJ
hjic-751	126	33	structural	structural	ADJ
hjic-751	126	34	transformations	transformation	NOUN
hjic-751	126	35	to	to	ADP
hjic-751	126	36	another	another	DET
hjic-751	126	37	complex	complex	ADJ
hjic-751	126	38	form	form	NOUN
hjic-751	126	39	or	or	CCONJ
hjic-751	126	40	conformer	conformer	NOUN
hjic-751	126	41	were	be	AUX
hjic-751	126	42	observed	observe	VERB
hjic-751	126	43	in	in	ADP
hjic-751	126	44	some	some	DET
hjic-751	126	45	cases	case	NOUN
hjic-751	126	46	as	as	ADP
hjic-751	126	47	a	a	DET
hjic-751	126	48	photoinduced	photoinduced	ADJ
hjic-751	126	49	change	change	NOUN
hjic-751	126	50	of	of	ADP
hjic-751	126	51	the	the	DET
hjic-751	126	52	type	type	NOUN
hjic-751	126	53	or	or	CCONJ
hjic-751	126	54	measure	measure	NOUN
hjic-751	126	55	of	of	ADP
hjic-751	126	56	distortion	distortion	NOUN
hjic-751	126	57	(	(	PUNCT
hjic-751	126	58	e.g.	e.g.	ADV
hjic-751	126	59	dand	dand	NOUN
hjic-751	126	60	p	p	ADJ
hjic-751	126	61	-	-	PUNCT
hjic-751	126	62	type	type	NOUN
hjic-751	126	63	hyperporphyrins	hyperporphyrin	NOUN
hjic-751	126	64	)	)	PUNCT
hjic-751	127	1	[	[	X
hjic-751	127	2	2	2	NUM
hjic-751	127	3	,	,	PUNCT
hjic-751	127	4	4	4	NUM
hjic-751	127	5	,	,	PUNCT
hjic-751	127	6	8	8	NUM
hjic-751	127	7	-	-	SYM
hjic-751	127	8	10	10	NUM
hjic-751	127	9	,	,	PUNCT
hjic-751	127	10	14	14	NUM
hjic-751	127	11	-	-	SYM
hjic-751	127	12	16	16	NUM
hjic-751	127	13	]	]	PUNCT
hjic-751	127	14	.	.	PUNCT
hjic-751	128	1	besides	besides	SCONJ
hjic-751	128	2	the	the	DET
hjic-751	128	3	typical	typical	ADJ
hjic-751	128	4	post	post	ADJ
hjic-751	128	5	-	-	ADJ
hjic-751	128	6	transition	transition	ADJ
hjic-751	128	7	metal	metal	NOUN
hjic-751	128	8	ions	ion	NOUN
hjic-751	128	9	,	,	PUNCT
hjic-751	128	10	lanthanide(iii	lanthanide(iii	NOUN
hjic-751	128	11	)	)	PUNCT
hjic-751	128	12	ions	ion	NOUN
hjic-751	128	13	were	be	AUX
hjic-751	128	14	also	also	ADV
hjic-751	128	15	applied	apply	VERB
hjic-751	128	16	for	for	ADP
hjic-751	128	17	out	out	ADV
hjic-751	128	18	-	-	PUNCT
hjic-751	128	19	of	of	ADP
hjic-751	128	20	-	-	PUNCT
hjic-751	128	21	plane	plane	NOUN
hjic-751	128	22	coordination	coordination	NOUN
hjic-751	128	23	because	because	SCONJ
hjic-751	128	24	their	their	PRON
hjic-751	128	25	contraction	contraction	NOUN
hjic-751	128	26	makes	make	VERB
hjic-751	128	27	the	the	DET
hjic-751	128	28	finetuning	finetuning	NOUN
hjic-751	128	29	of	of	ADP
hjic-751	128	30	the	the	DET
hjic-751	128	31	out	out	ADJ
hjic-751	128	32	-	-	PUNCT
hjic-751	128	33	of	of	ADP
hjic-751	128	34	-	-	PUNCT
hjic-751	128	35	plane	plane	NOUN
hjic-751	128	36	distance	distance	NOUN
hjic-751	128	37	possible	possible	ADJ
hjic-751	128	38	,	,	PUNCT
hjic-751	128	39	and	and	CCONJ
hjic-751	128	40	their	their	PRON
hjic-751	128	41	high	high	ADJ
hjic-751	128	42	negative	negative	ADJ
hjic-751	128	43	redox	redox	ADJ
hjic-751	128	44	potentials	potential	NOUN
hjic-751	128	45	promote	promote	VERB
hjic-751	128	46	the	the	DET
hjic-751	128	47	photoinduced	photoinduced	ADJ
hjic-751	128	48	cleavage	cleavage	NOUN
hjic-751	128	49	of	of	ADP
hjic-751	128	50	water	water	NOUN
hjic-751	128	51	.	.	PUNCT
hjic-751	129	1	photochemical	photochemical	ADJ
hjic-751	129	2	activities	activity	NOUN
hjic-751	129	3	of	of	ADP
hjic-751	129	4	their	their	PRON
hjic-751	129	5	complexes	complex	NOUN
hjic-751	129	6	confirm	confirm	VERB
hjic-751	129	7	that	that	SCONJ
hjic-751	129	8	the	the	DET
hjic-751	129	9	redox	redox	ADJ
hjic-751	129	10	potentials	potential	NOUN
hjic-751	129	11	of	of	ADP
hjic-751	129	12	the	the	DET
hjic-751	129	13	metal	metal	NOUN
hjic-751	129	14	centers	center	NOUN
hjic-751	129	15	are	be	AUX
hjic-751	129	16	not	not	PART
hjic-751	129	17	the	the	DET
hjic-751	129	18	main	main	ADJ
hjic-751	129	19	determining	determine	VERB
hjic-751	129	20	factor	factor	NOUN
hjic-751	129	21	,	,	PUNCT
hjic-751	129	22	rather	rather	ADV
hjic-751	129	23	their	their	PRON
hjic-751	129	24	out	out	ADV
hjic-751	129	25	-	-	PUNCT
hjic-751	129	26	of	of	ADP
hjic-751	129	27	-	-	PUNCT
hjic-751	129	28	plane	plane	NOUN
hjic-751	129	29	distances	distance	NOUN
hjic-751	129	30	[	[	X
hjic-751	129	31	2	2	NUM
hjic-751	129	32	,	,	PUNCT
hjic-751	129	33	11	11	NUM
hjic-751	129	34	-	-	SYM
hjic-751	129	35	13	13	NUM
hjic-751	129	36	]	]	PUNCT
hjic-751	129	37	.	.	PUNCT
hjic-751	130	1	deviating	deviate	VERB
hjic-751	130	2	from	from	ADP
hjic-751	130	3	the	the	DET
hjic-751	130	4	oop	oop	NOUN
hjic-751	130	5	complexes	complex	NOUN
hjic-751	130	6	of	of	ADP
hjic-751	130	7	posttransition	posttransition	NOUN
hjic-751	130	8	metal	metal	NOUN
hjic-751	130	9	ions	ion	NOUN
hjic-751	130	10	,	,	PUNCT
hjic-751	130	11	another	another	DET
hjic-751	130	12	stable	stable	ADJ
hjic-751	130	13	photoproduct	photoproduct	NOUN
hjic-751	130	14	was	be	AUX
hjic-751	130	15	observable	observable	ADJ
hjic-751	130	16	during	during	ADP
hjic-751	130	17	the	the	DET
hjic-751	130	18	photolysis	photolysis	NOUN
hjic-751	130	19	of	of	ADP
hjic-751	130	20	lanthanide(iii	lanthanide(iii	NOUN
hjic-751	130	21	)	)	PUNCT
hjic-751	130	22	porphyrins	porphyrin	NOUN
hjic-751	130	23	.	.	PUNCT
hjic-751	131	1	it	it	PRON
hjic-751	131	2	displays	display	VERB
hjic-751	131	3	a	a	DET
hjic-751	131	4	typical	typical	ADJ
hjic-751	131	5	absorption	absorption	NOUN
hjic-751	131	6	band	band	NOUN
hjic-751	131	7	in	in	ADP
hjic-751	131	8	the	the	DET
hjic-751	131	9	q	q	NOUN
hjic-751	131	10	range	range	NOUN
hjic-751	131	11	(	(	PUNCT
hjic-751	131	12	at	at	ADP
hjic-751	131	13	~600	~600	NUM
hjic-751	131	14	nm	nm	NOUN
hjic-751	131	15	)	)	PUNCT
hjic-751	131	16	,	,	PUNCT
hjic-751	131	17	which	which	PRON
hjic-751	131	18	may	may	AUX
hjic-751	131	19	be	be	AUX
hjic-751	131	20	assigned	assign	VERB
hjic-751	131	21	as	as	ADP
hjic-751	131	22	a	a	DET
hjic-751	131	23	charge	charge	NOUN
hjic-751	131	24	transfer	transfer	NOUN
hjic-751	131	25	between	between	ADP
hjic-751	131	26	the	the	DET
hjic-751	131	27	metal	metal	NOUN
hjic-751	131	28	ion	ion	NOUN
hjic-751	131	29	and	and	CCONJ
hjic-751	131	30	open	open	ADJ
hjic-751	131	31	-	-	PUNCT
hjic-751	131	32	chain	chain	NOUN
hjic-751	131	33	,	,	PUNCT
hjic-751	131	34	dioxo	dioxo	NOUN
hjic-751	131	35	-	-	PUNCT
hjic-751	131	36	tetrapyrrole	tetrapyrrole	NOUN
hjic-751	131	37	derivative	derivative	NOUN
hjic-751	131	38	(	(	PUNCT
hjic-751	131	39	bilindione	bilindione	NOUN
hjic-751	131	40	,	,	PUNCT
hjic-751	131	41	see	see	VERB
hjic-751	131	42	scheme	scheme	NOUN
hjic-751	131	43	2	2	NUM
hjic-751	131	44	)	)	PUNCT
hjic-751	131	45	.	.	PUNCT
hjic-751	132	1	its	its	PRON
hjic-751	132	2	oxo	oxo	NOUN
hjic-751	132	3	-	-	PUNCT
hjic-751	132	4	groups	group	NOUN
hjic-751	132	5	,	,	PUNCT
hjic-751	132	6	as	as	ADP
hjic-751	132	7	donor	donor	NOUN
hjic-751	132	8	atoms	atom	NOUN
hjic-751	132	9	,	,	PUNCT
hjic-751	132	10	may	may	AUX
hjic-751	132	11	coordinate	coordinate	VERB
hjic-751	132	12	with	with	ADP
hjic-751	132	13	the	the	DET
hjic-751	132	14	lanthanide	lanthanide	ADJ
hjic-751	132	15	ions	ion	NOUN
hjic-751	132	16	,	,	PUNCT
hjic-751	132	17	as	as	ADP
hjic-751	132	18	a	a	DET
hjic-751	132	19	consequence	consequence	NOUN
hjic-751	132	20	of	of	ADP
hjic-751	132	21	their	their	PRON
hjic-751	132	22	similar	similar	ADJ
hjic-751	132	23	pearson	pearson	NOUN
hjic-751	132	24	-	-	PUNCT
hjic-751	132	25	type	type	NOUN
hjic-751	132	26	hard	hard	ADJ
hjic-751	132	27	characteristics	characteristic	NOUN
hjic-751	132	28	,	,	PUNCT
hjic-751	132	29	contrary	contrary	ADV
hjic-751	132	30	to	to	ADP
hjic-751	132	31	the	the	DET
hjic-751	132	32	softer	soft	ADJ
hjic-751	132	33	post	post	ADJ
hjic-751	132	34	-	-	ADJ
hjic-751	132	35	transition	transition	ADJ
hjic-751	132	36	metal	metal	NOUN
hjic-751	132	37	ions	ion	NOUN
hjic-751	132	38	[	[	X
hjic-751	132	39	2	2	NUM
hjic-751	132	40	,	,	PUNCT
hjic-751	132	41	11	11	NUM
hjic-751	132	42	]	]	PUNCT
hjic-751	132	43	.	.	PUNCT
hjic-751	133	1	during	during	ADP
hjic-751	133	2	the	the	DET
hjic-751	133	3	photolysis	photolysis	NOUN
hjic-751	133	4	experiments	experiment	NOUN
hjic-751	133	5	,	,	PUNCT
hjic-751	133	6	only	only	ADV
hjic-751	133	7	small	small	ADJ
hjic-751	133	8	differences	difference	NOUN
hjic-751	133	9	appeared	appear	VERB
hjic-751	133	10	between	between	ADP
hjic-751	133	11	lanthanide(iii	lanthanide(iii	NOUN
hjic-751	133	12	)	)	PUNCT
hjic-751	133	13	monoand	monoand	NOUN
hjic-751	133	14	bisporphyrin	bisporphyrin	NOUN
hjic-751	133	15	complexes	complex	NOUN
hjic-751	133	16	,	,	PUNCT
hjic-751	133	17	which	which	PRON
hjic-751	133	18	might	might	AUX
hjic-751	133	19	confirm	confirm	VERB
hjic-751	133	20	a	a	DET
hjic-751	133	21	special	special	ADJ
hjic-751	133	22	type	type	NOUN
hjic-751	133	23	of	of	ADP
hjic-751	133	24	aggregation	aggregation	NOUN
hjic-751	133	25	through	through	ADP
hjic-751	133	26	the	the	DET
hjic-751	133	27	peripheral	peripheral	ADJ
hjic-751	133	28	sulfonato	sulfonato	NOUN
hjic-751	133	29	substituents	substituent	NOUN
hjic-751	133	30	with	with	ADP
hjic-751	133	31	weak	weak	ADJ
hjic-751	133	32	π	π	PROPN
hjic-751	133	33	-	-	PUNCT
hjic-751	133	34	π	π	ADJ
hjic-751	133	35	interactions	interaction	NOUN
hjic-751	133	36	(	(	PUNCT
hjic-751	133	37	tail	tail	NOUN
hjic-751	133	38	-	-	PUNCT
hjic-751	133	39	to	to	ADP
hjic-751	133	40	-	-	PUNCT
hjic-751	133	41	tail	tail	NOUN
hjic-751	133	42	,	,	PUNCT
hjic-751	133	43	see	see	VERB
hjic-751	133	44	fig.3	fig.3	PROPN
hjic-751	133	45	)	)	PUNCT
hjic-751	134	1	[	[	X
hjic-751	134	2	2	2	NUM
hjic-751	134	3	,	,	PUNCT
hjic-751	134	4	11	11	NUM
hjic-751	134	5	-	-	SYM
hjic-751	134	6	13	13	NUM
hjic-751	134	7	]	]	PUNCT
hjic-751	134	8	.	.	PUNCT
hjic-751	135	1	deviating	deviate	VERB
hjic-751	135	2	from	from	ADP
hjic-751	135	3	these	these	DET
hjic-751	135	4	observations	observation	NOUN
hjic-751	135	5	,	,	PUNCT
hjic-751	135	6	the	the	DET
hjic-751	135	7	differences	difference	NOUN
hjic-751	135	8	are	be	AUX
hjic-751	135	9	much	much	ADV
hjic-751	135	10	more	more	ADV
hjic-751	135	11	significant	significant	ADJ
hjic-751	135	12	in	in	ADP
hjic-751	135	13	the	the	DET
hjic-751	135	14	case	case	NOUN
hjic-751	135	15	of	of	ADP
hjic-751	135	16	the	the	DET
hjic-751	135	17	most	most	ADV
hjic-751	135	18	typical	typical	ADJ
hjic-751	135	19	,	,	PUNCT
hjic-751	135	20	post	post	ADJ
hjic-751	135	21	-	-	ADJ
hjic-751	135	22	transition	transition	ADJ
hjic-751	135	23	metallo	metallo	NOUN
hjic-751	135	24	-	-	PUNCT
hjic-751	135	25	bisporphyrin	bisporphyrin	NOUN
hjic-751	135	26	compared	compare	VERB
hjic-751	135	27	to	to	ADP
hjic-751	135	28	the	the	DET
hjic-751	135	29	monoporphyrin	monoporphyrin	NOUN
hjic-751	135	30	equivalent	equivalent	ADJ
hjic-751	135	31	;	;	PUNCT
hjic-751	135	32	namely	namely	ADV
hjic-751	135	33	between	between	ADP
hjic-751	135	34	hgii	hgii	NOUN
hjic-751	135	35	3(tspp)2	3(tspp)2	NUM
hjic-751	135	36	6and	6and	NUM
hjic-751	135	37	hgiitspp4-	hgiitspp4-	NOUN
hjic-751	135	38	.	.	PUNCT
hjic-751	136	1	the	the	DET
hjic-751	136	2	overall	overall	ADJ
hjic-751	136	3	quantum	quantum	ADJ
hjic-751	136	4	yield	yield	NOUN
hjic-751	136	5	is	be	AUX
hjic-751	136	6	~2	~2	NOUN
hjic-751	136	7	orders	order	NOUN
hjic-751	136	8	of	of	ADP
hjic-751	136	9	magnitude	magnitude	NOUN
hjic-751	136	10	higher	high	ADJ
hjic-751	136	11	and	and	CCONJ
hjic-751	136	12	the	the	DET
hjic-751	136	13	photoinduced	photoinduce	VERB
hjic-751	136	14	dissociation	dissociation	NOUN
hjic-751	136	15	of	of	ADP
hjic-751	136	16	a	a	DET
hjic-751	136	17	metal	metal	NOUN
hjic-751	136	18	ion	ion	NOUN
hjic-751	136	19	became	become	VERB
hjic-751	136	20	the	the	DET
hjic-751	136	21	dominant	dominant	ADJ
hjic-751	136	22	reaction	reaction	NOUN
hjic-751	136	23	in	in	ADP
hjic-751	136	24	the	the	DET
hjic-751	136	25	head	head	NOUN
hjic-751	136	26	-	-	PUNCT
hjic-751	136	27	to	to	ADP
hjic-751	136	28	-	-	PUNCT
hjic-751	136	29	head	head	NOUN
hjic-751	136	30	sandwich	sandwich	NOUN
hjic-751	136	31	complex	complex	NOUN
hjic-751	136	32	as	as	ADP
hjic-751	136	33	a	a	DET
hjic-751	136	34	consequence	consequence	NOUN
hjic-751	136	35	of	of	ADP
hjic-751	136	36	the	the	DET
hjic-751	136	37	strong	strong	ADJ
hjic-751	136	38	π	π	PROPN
hjic-751	136	39	-	-	PUNCT
hjic-751	136	40	π	π	ADJ
hjic-751	136	41	interactions	interaction	NOUN
hjic-751	137	1	[	[	X
hjic-751	137	2	9	9	NUM
hjic-751	137	3	-	-	SYM
hjic-751	137	4	10	10	NUM
hjic-751	137	5	]	]	PUNCT
hjic-751	137	6	.	.	PUNCT
hjic-751	138	1	3.5	3.5	NUM
hjic-751	138	2	.	.	PUNCT
hjic-751	138	3	quantum	quantum	PROPN
hjic-751	138	4	chemical	chemical	NOUN
hjic-751	138	5	calculations	calculation	NOUN
hjic-751	138	6	the	the	DET
hjic-751	138	7	main	main	ADJ
hjic-751	138	8	aims	aim	NOUN
hjic-751	138	9	of	of	ADP
hjic-751	138	10	our	our	PRON
hjic-751	138	11	electronic	electronic	ADJ
hjic-751	138	12	structural	structural	ADJ
hjic-751	138	13	calculations	calculation	NOUN
hjic-751	138	14	were	be	AUX
hjic-751	138	15	to	to	PART
hjic-751	138	16	determine	determine	VERB
hjic-751	138	17	the	the	DET
hjic-751	138	18	primary	primary	ADJ
hjic-751	138	19	consequences	consequence	NOUN
hjic-751	138	20	for	for	ADP
hjic-751	138	21	the	the	DET
hjic-751	138	22	outof	outof	ADJ
hjic-751	138	23	-	-	PUNCT
hjic-751	138	24	plane	plane	NOUN
hjic-751	138	25	position	position	NOUN
hjic-751	138	26	of	of	ADP
hjic-751	138	27	a	a	DET
hjic-751	138	28	metal	metal	NOUN
hjic-751	138	29	center	center	NOUN
hjic-751	138	30	,	,	PUNCT
hjic-751	138	31	and	and	CCONJ
hjic-751	138	32	confirm	confirm	VERB
hjic-751	138	33	the	the	DET
hjic-751	138	34	experimentally	experimentally	ADV
hjic-751	138	35	observed	observe	VERB
hjic-751	138	36	correlation	correlation	NOUN
hjic-751	138	37	between	between	ADP
hjic-751	138	38	the	the	DET
hjic-751	138	39	uvvis	uvvis	ADJ
hjic-751	138	40	spectral	spectral	ADJ
hjic-751	138	41	shifts	shift	NOUN
hjic-751	138	42	and	and	CCONJ
hjic-751	138	43	the	the	DET
hjic-751	138	44	coordination	coordination	NOUN
hjic-751	138	45	position	position	NOUN
hjic-751	138	46	of	of	ADP
hjic-751	138	47	the	the	DET
hjic-751	138	48	metal	metal	NOUN
hjic-751	138	49	center	center	NOUN
hjic-751	138	50	(	(	PUNCT
hjic-751	138	51	in	in	ADP
hjic-751	138	52	-	-	PUNCT
hjic-751	138	53	plane	plane	NOUN
hjic-751	138	54	or	or	CCONJ
hjic-751	138	55	out	out	ADP
hjic-751	138	56	-	-	PUNCT
hjic-751	138	57	of	of	ADP
hjic-751	138	58	-	-	PUNCT
hjic-751	138	59	plane	plane	NOUN
hjic-751	138	60	)	)	PUNCT
hjic-751	138	61	.	.	PUNCT
hjic-751	139	1	in	in	ADP
hjic-751	139	2	the	the	DET
hjic-751	139	3	light	light	NOUN
hjic-751	139	4	of	of	ADP
hjic-751	139	5	these	these	DET
hjic-751	139	6	aspects	aspect	NOUN
hjic-751	139	7	,	,	PUNCT
hjic-751	139	8	the	the	DET
hjic-751	139	9	unsubstituted	unsubstituted	ADJ
hjic-751	139	10	porphin	porphin	NOUN
hjic-751	139	11	(	(	PUNCT
hjic-751	139	12	h2p	h2p	PROPN
hjic-751	139	13	,	,	PUNCT
hjic-751	139	14	c20h14n4	c20h14n4	PROPN
hjic-751	139	15	)	)	PUNCT
hjic-751	139	16	was	be	AUX
hjic-751	139	17	used	use	VERB
hjic-751	139	18	as	as	ADP
hjic-751	139	19	a	a	DET
hjic-751	139	20	model	model	NOUN
hjic-751	139	21	for	for	ADP
hjic-751	139	22	the	the	DET
hjic-751	139	23	calculations	calculation	NOUN
hjic-751	139	24	,	,	PUNCT
hjic-751	139	25	instead	instead	ADV
hjic-751	139	26	of	of	ADP
hjic-751	139	27	the	the	DET
hjic-751	139	28	tetrakis(sulfonatophenyl)porphyrin	tetrakis(sulfonatophenyl)porphyrin	NOUN
hjic-751	139	29	(	(	PUNCT
hjic-751	139	30	h2tspp4	h2tspp4	PROPN
hjic-751	139	31	–	–	PUNCT
hjic-751	139	32	,	,	PUNCT
hjic-751	139	33	c44h26n4o12s4	c44h26n4o12s4	PROPN
hjic-751	139	34	4-	4-	PROPN
hjic-751	139	35	)	)	PUNCT
hjic-751	139	36	.	.	PUNCT
hjic-751	140	1	on	on	ADP
hjic-751	140	2	the	the	DET
hjic-751	140	3	basis	basis	NOUN
hjic-751	140	4	of	of	ADP
hjic-751	140	5	the	the	DET
hjic-751	140	6	few	few	ADJ
hjic-751	140	7	comparative	comparative	ADJ
hjic-751	140	8	calculations	calculation	NOUN
hjic-751	140	9	that	that	PRON
hjic-751	140	10	were	be	AUX
hjic-751	140	11	conducted	conduct	VERB
hjic-751	140	12	,	,	PUNCT
hjic-751	140	13	the	the	DET
hjic-751	140	14	phenyl-	phenyl-	NOUN
hjic-751	140	15	,	,	PUNCT
hjic-751	140	16	as	as	ADV
hjic-751	140	17	well	well	ADV
hjic-751	140	18	as	as	ADP
hjic-751	140	19	the	the	DET
hjic-751	140	20	sulfonatophenyl	sulfonatophenyl	NOUN
hjic-751	140	21	substituents	substituent	NOUN
hjic-751	140	22	have	have	VERB
hjic-751	140	23	negligible	negligible	ADJ
hjic-751	140	24	effects	effect	NOUN
hjic-751	140	25	on	on	ADP
hjic-751	140	26	the	the	DET
hjic-751	140	27	coordination	coordination	NOUN
hjic-751	140	28	of	of	ADP
hjic-751	140	29	the	the	DET
hjic-751	140	30	metal	metal	NOUN
hjic-751	140	31	center	center	NOUN
hjic-751	140	32	in	in	ADP
hjic-751	140	33	the	the	DET
hjic-751	140	34	cavity	cavity	NOUN
hjic-751	140	35	.	.	PUNCT
hjic-751	141	1	however	however	ADV
hjic-751	141	2	,	,	PUNCT
hjic-751	141	3	they	they	PRON
hjic-751	141	4	can	can	AUX
hjic-751	141	5	significantly	significantly	ADV
hjic-751	141	6	influence	influence	VERB
hjic-751	141	7	the	the	DET
hjic-751	141	8	formation	formation	NOUN
hjic-751	141	9	of	of	ADP
hjic-751	141	10	bisporphyrin	bisporphyrin	NOUN
hjic-751	141	11	complexes	complex	NOUN
hjic-751	141	12	,	,	PUNCT
hjic-751	141	13	even	even	ADV
hjic-751	141	14	in	in	ADP
hjic-751	141	15	the	the	DET
hjic-751	141	16	case	case	NOUN
hjic-751	141	17	of	of	ADP
hjic-751	141	18	head	head	NOUN
hjic-751	141	19	-	-	PUNCT
hjic-751	141	20	tohead	tohead	ADJ
hjic-751	141	21	structures	structure	NOUN
hjic-751	141	22	[	[	X
hjic-751	141	23	4	4	NUM
hjic-751	141	24	,	,	PUNCT
hjic-751	141	25	10	10	NUM
hjic-751	141	26	]	]	PUNCT
hjic-751	141	27	.	.	PUNCT
hjic-751	142	1	according	accord	VERB
hjic-751	142	2	to	to	ADP
hjic-751	142	3	our	our	PRON
hjic-751	142	4	quantum	quantum	ADJ
hjic-751	142	5	chemical	chemical	NOUN
hjic-751	142	6	experience	experience	NOUN
hjic-751	142	7	,	,	PUNCT
hjic-751	142	8	the	the	DET
hjic-751	142	9	value	value	NOUN
hjic-751	142	10	of	of	ADP
hjic-751	142	11	the	the	DET
hjic-751	142	12	critical	critical	ADJ
hjic-751	142	13	radius	radius	NOUN
hjic-751	142	14	became	become	VERB
hjic-751	142	15	~100	~100	NUM
hjic-751	142	16	pm	pm	NOUN
hjic-751	142	17	instead	instead	ADV
hjic-751	142	18	of	of	ADP
hjic-751	142	19	the	the	DET
hjic-751	142	20	experimentally	experimentally	ADV
hjic-751	142	21	suggested	suggest	VERB
hjic-751	142	22	~75	~75	ADJ
hjic-751	142	23	-	-	SYM
hjic-751	142	24	90	90	NUM
hjic-751	142	25	pm	pm	NOUN
hjic-751	142	26	as	as	ADP
hjic-751	142	27	a	a	DET
hjic-751	142	28	consequence	consequence	NOUN
hjic-751	142	29	of	of	ADP
hjic-751	142	30	the	the	DET
hjic-751	142	31	significant	significant	ADJ
hjic-751	142	32	expansion	expansion	NOUN
hjic-751	142	33	of	of	ADP
hjic-751	142	34	the	the	DET
hjic-751	142	35	coordination	coordination	NOUN
hjic-751	142	36	cavity	cavity	NOUN
hjic-751	142	37	to	to	PART
hjic-751	142	38	coplanarly	coplanarly	ADV
hjic-751	142	39	incorporate	incorporate	VERB
hjic-751	142	40	the	the	DET
hjic-751	142	41	metal	metal	NOUN
hjic-751	142	42	ions	ion	NOUN
hjic-751	142	43	.	.	PUNCT
hjic-751	143	1	the	the	DET
hjic-751	143	2	proportion	proportion	NOUN
hjic-751	143	3	of	of	ADP
hjic-751	143	4	borderline	borderline	NOUN
hjic-751	143	5	cases	case	NOUN
hjic-751	143	6	,	,	PUNCT
hjic-751	143	7	i.e.	i.e.	X
hjic-751	143	8	complexes	complex	NOUN
hjic-751	143	9	with	with	ADP
hjic-751	143	10	questionable	questionable	ADJ
hjic-751	143	11	structures	structure	NOUN
hjic-751	143	12	(	(	PUNCT
hjic-751	143	13	somewhere	somewhere	ADV
hjic-751	143	14	between	between	ADP
hjic-751	143	15	inplane	inplane	NOUN
hjic-751	143	16	and	and	CCONJ
hjic-751	143	17	out	out	ADP
hjic-751	143	18	-	-	PUNCT
hjic-751	143	19	of	of	ADP
hjic-751	143	20	-	-	PUNCT
hjic-751	143	21	plane	plane	NOUN
hjic-751	143	22	)	)	PUNCT
hjic-751	143	23	,	,	PUNCT
hjic-751	143	24	increased	increase	VERB
hjic-751	143	25	with	with	ADP
hjic-751	143	26	further	further	ADJ
hjic-751	143	27	posttransition	posttransition	NOUN
hjic-751	143	28	metal	metal	NOUN
hjic-751	143	29	ions	ion	NOUN
hjic-751	143	30	(	(	PUNCT
hjic-751	143	31	e.g.	e.g.	ADV
hjic-751	143	32	ag2	ag2	PROPN
hjic-751	143	33	+	+	X
hjic-751	144	1	[	[	X
hjic-751	144	2	15	15	NUM
hjic-751	144	3	]	]	PUNCT
hjic-751	144	4	,	,	PUNCT
hjic-751	144	5	cd2	cd2	PROPN
hjic-751	144	6	+	+	X
hjic-751	145	1	[	[	X
hjic-751	145	2	4	4	NUM
hjic-751	145	3	]	]	PUNCT
hjic-751	145	4	,	,	PUNCT
hjic-751	145	5	tl3	tl3	PROPN
hjic-751	145	6	+	+	X
hjic-751	146	1	[	[	X
hjic-751	146	2	16	16	NUM
hjic-751	146	3	]	]	PUNCT
hjic-751	146	4	)	)	PUNCT
hjic-751	146	5	that	that	PRON
hjic-751	146	6	possess	possess	VERB
hjic-751	146	7	ionic	ionic	ADJ
hjic-751	146	8	radii	radius	NOUN
hjic-751	146	9	of	of	ADP
hjic-751	146	10	~90	~90	NOUN
hjic-751	146	11	-	-	PUNCT
hjic-751	146	12	95	95	NUM
hjic-751	146	13	pm	pm	NOUN
hjic-751	146	14	.	.	PUNCT
hjic-751	147	1	calculated	calculate	VERB
hjic-751	147	2	bond	bond	NOUN
hjic-751	147	3	lengths	length	NOUN
hjic-751	147	4	(	(	PUNCT
hjic-751	147	5	m	m	NOUN
hjic-751	147	6	-	-	PUNCT
hjic-751	147	7	n	n	CCONJ
hjic-751	147	8	)	)	PUNCT
hjic-751	147	9	and	and	CCONJ
hjic-751	147	10	atomic	atomic	ADJ
hjic-751	147	11	distances	distance	NOUN
hjic-751	147	12	(	(	PUNCT
hjic-751	147	13	n	n	CCONJ
hjic-751	147	14	-	-	PUNCT
hjic-751	147	15	n	n	CCONJ
hjic-751	147	16	)	)	PUNCT
hjic-751	147	17	considerably	considerably	ADV
hjic-751	147	18	deviate	deviate	VERB
hjic-751	147	19	from	from	ADP
hjic-751	147	20	the	the	DET
hjic-751	147	21	expected	expect	VERB
hjic-751	147	22	ones	one	NOUN
hjic-751	147	23	supposed	suppose	VERB
hjic-751	147	24	on	on	ADP
hjic-751	147	25	the	the	DET
hjic-751	147	26	basis	basis	NOUN
hjic-751	147	27	of	of	ADP
hjic-751	147	28	the	the	DET
hjic-751	147	29	values	value	NOUN
hjic-751	147	30	of	of	ADP
hjic-751	147	31	the	the	DET
hjic-751	147	32	deprotonated	deprotonated	ADJ
hjic-751	147	33	porphyrins	porphyrin	NOUN
hjic-751	147	34	(	(	PUNCT
hjic-751	147	35	p2-	p2-	NOUN
hjic-751	147	36	)	)	PUNCT
hjic-751	147	37	.	.	PUNCT
hjic-751	148	1	to	to	PART
hjic-751	148	2	describe	describe	VERB
hjic-751	148	3	this	this	DET
hjic-751	148	4	phenomenon	phenomenon	NOUN
hjic-751	148	5	,	,	PUNCT
hjic-751	148	6	an	an	DET
hjic-751	148	7	axial	axial	ADJ
hjic-751	148	8	ligand	ligand	NOUN
hjic-751	148	9	was	be	AUX
hjic-751	148	10	applied	apply	VERB
hjic-751	148	11	to	to	ADP
hjic-751	148	12	these	these	DET
hjic-751	148	13	metal	metal	NOUN
hjic-751	148	14	centers	center	NOUN
hjic-751	148	15	to	to	PART
hjic-751	148	16	extract	extract	VERB
hjic-751	148	17	them	they	PRON
hjic-751	148	18	out	out	ADP
hjic-751	148	19	of	of	ADP
hjic-751	148	20	the	the	DET
hjic-751	148	21	cavity	cavity	NOUN
hjic-751	148	22	.	.	PUNCT
hjic-751	149	1	consequently	consequently	ADV
hjic-751	149	2	,	,	PUNCT
hjic-751	149	3	expansion	expansion	NOUN
hjic-751	149	4	stopped	stop	VERB
hjic-751	149	5	,	,	PUNCT
hjic-751	149	6	and	and	CCONJ
hjic-751	149	7	the	the	DET
hjic-751	149	8	out	out	ADV
hjic-751	149	9	-	-	PUNCT
hjic-751	149	10	of	of	ADP
hjic-751	149	11	-	-	PUNCT
hjic-751	149	12	plane	plane	NOUN
hjic-751	149	13	distance	distance	NOUN
hjic-751	149	14	increased	increase	VERB
hjic-751	149	15	dramatically	dramatically	ADV
hjic-751	149	16	together	together	ADV
hjic-751	149	17	with	with	ADP
hjic-751	149	18	the	the	DET
hjic-751	149	19	degree	degree	NOUN
hjic-751	149	20	of	of	ADP
hjic-751	149	21	dome	dome	ADJ
hjic-751	149	22	distortion	distortion	NOUN
hjic-751	149	23	and	and	CCONJ
hjic-751	149	24	redshifts	redshift	NOUN
hjic-751	149	25	of	of	ADP
hjic-751	149	26	absorption	absorption	NOUN
hjic-751	149	27	bands	band	NOUN
hjic-751	149	28	.	.	PUNCT
hjic-751	150	1	from	from	ADP
hjic-751	150	2	this	this	DET
hjic-751	150	3	point	point	NOUN
hjic-751	150	4	of	of	ADP
hjic-751	150	5	view	view	NOUN
hjic-751	150	6	,	,	PUNCT
hjic-751	150	7	two	two	NUM
hjic-751	150	8	possible	possible	ADJ
hjic-751	150	9	explanations	explanation	NOUN
hjic-751	150	10	can	can	AUX
hjic-751	150	11	be	be	AUX
hjic-751	150	12	supposed	suppose	VERB
hjic-751	150	13	for	for	ADP
hjic-751	150	14	the	the	DET
hjic-751	150	15	borderline	borderline	NOUN
hjic-751	150	16	-	-	PUNCT
hjic-751	150	17	case	case	NOUN
hjic-751	150	18	complexes	complex	NOUN
hjic-751	150	19	:	:	PUNCT
hjic-751	150	20	the	the	DET
hjic-751	150	21	experimentally	experimentally	ADV
hjic-751	150	22	observed	observe	VERB
hjic-751	150	23	common	common	ADJ
hjic-751	150	24	oop	oop	NOUN
hjic-751	150	25	characteristics	characteristic	NOUN
hjic-751	150	26	may	may	AUX
hjic-751	150	27	originate	originate	VERB
hjic-751	150	28	from	from	ADP
hjic-751	150	29	this	this	DET
hjic-751	150	30	expansion	expansion	NOUN
hjic-751	150	31	,	,	PUNCT
hjic-751	150	32	tension	tension	NOUN
hjic-751	150	33	;	;	PUNCT
hjic-751	150	34	and	and	CCONJ
hjic-751	150	35	small	small	ADJ
hjic-751	150	36	perturbations	perturbation	NOUN
hjic-751	150	37	(	(	PUNCT
hjic-751	150	38	e.g.	e.g.	ADV
hjic-751	150	39	the	the	DET
hjic-751	150	40	axial	axial	ADJ
hjic-751	150	41	coordination	coordination	NOUN
hjic-751	150	42	in	in	ADP
hjic-751	150	43	the	the	DET
hjic-751	150	44	calculation	calculation	NOUN
hjic-751	150	45	or	or	CCONJ
hjic-751	150	46	photoexcitation	photoexcitation	NOUN
hjic-751	150	47	in	in	ADP
hjic-751	150	48	the	the	DET
hjic-751	150	49	experiments	experiment	NOUN
hjic-751	150	50	)	)	PUNCT
hjic-751	150	51	may	may	AUX
hjic-751	150	52	facilitate	facilitate	VERB
hjic-751	150	53	the	the	DET
hjic-751	150	54	metal	metal	NOUN
hjic-751	150	55	center	center	NOUN
hjic-751	150	56	to	to	PART
hjic-751	150	57	adopt	adopt	VERB
hjic-751	150	58	an	an	DET
hjic-751	150	59	out	out	ADV
hjic-751	150	60	-	-	PUNCT
hjic-751	150	61	of	of	ADP
hjic-751	150	62	-	-	PUNCT
hjic-751	150	63	plane	plane	NOUN
hjic-751	150	64	position	position	NOUN
hjic-751	150	65	,	,	PUNCT
hjic-751	150	66	too	too	ADV
hjic-751	150	67	.	.	PUNCT
hjic-751	151	1	another	another	DET
hjic-751	151	2	possibility	possibility	NOUN
hjic-751	151	3	is	be	AUX
hjic-751	151	4	that	that	SCONJ
hjic-751	151	5	the	the	DET
hjic-751	151	6	method	method	NOUN
hjic-751	151	7	of	of	ADP
hjic-751	151	8	calculation	calculation	NOUN
hjic-751	151	9	strongly	strongly	ADV
hjic-751	151	10	prefers	prefer	VERB
hjic-751	151	11	planar	planar	ADJ
hjic-751	151	12	structures	structure	NOUN
hjic-751	151	13	.	.	PUNCT
hjic-751	152	1	in	in	ADP
hjic-751	152	2	our	our	PRON
hjic-751	152	3	time	time	NOUN
hjic-751	152	4	-	-	PUNCT
hjic-751	152	5	dependent	dependent	ADJ
hjic-751	152	6	density	density	NOUN
hjic-751	152	7	functional	functional	ADJ
hjic-751	152	8	theory	theory	NOUN
hjic-751	152	9	(	(	PUNCT
hjic-751	152	10	td	td	NOUN
hjic-751	152	11	-	-	PUNCT
hjic-751	152	12	dft	dft	NOUN
hjic-751	152	13	)	)	PUNCT
hjic-751	152	14	calculations	calculation	NOUN
hjic-751	152	15	,	,	PUNCT
hjic-751	152	16	the	the	DET
hjic-751	152	17	correlation	correlation	NOUN
hjic-751	152	18	found	find	VERB
hjic-751	152	19	between	between	ADP
hjic-751	152	20	the	the	DET
hjic-751	152	21	measured	measure	VERB
hjic-751	152	22	and	and	CCONJ
hjic-751	152	23	calculated	calculate	VERB
hjic-751	152	24	shifts	shift	NOUN
hjic-751	152	25	associated	associate	VERB
hjic-751	152	26	with	with	ADP
hjic-751	152	27	the	the	DET
hjic-751	152	28	position	position	NOUN
hjic-751	152	29	of	of	ADP
hjic-751	152	30	the	the	DET
hjic-751	152	31	metal	metal	NOUN
hjic-751	152	32	center	center	NOUN
hjic-751	152	33	was	be	AUX
hjic-751	152	34	not	not	PART
hjic-751	152	35	totally	totally	ADV
hjic-751	152	36	linear	linear	ADJ
hjic-751	152	37	,	,	PUNCT
hjic-751	152	38	but	but	CCONJ
hjic-751	152	39	nevertheless	nevertheless	ADV
hjic-751	152	40	acceptable	acceptable	ADJ
hjic-751	152	41	.	.	PUNCT
hjic-751	153	1	the	the	DET
hjic-751	153	2	main	main	ADJ
hjic-751	153	3	exceptions	exception	NOUN
hjic-751	153	4	were	be	AUX
hjic-751	153	5	the	the	DET
hjic-751	153	6	borderline	borderline	NOUN
hjic-751	153	7	cases	case	NOUN
hjic-751	153	8	(	(	PUNCT
hjic-751	153	9	high	high	ADJ
hjic-751	153	10	-	-	PUNCT
hjic-751	153	11	spin	spin	NOUN
hjic-751	153	12	mn2	mn2	VERB
hjic-751	153	13	+	+	PROPN
hjic-751	153	14	,	,	PUNCT
hjic-751	153	15	fe2	fe2	X
hjic-751	153	16	+	+	NUM
hjic-751	153	17	and	and	CCONJ
hjic-751	153	18	zn2	zn2	PROPN
hjic-751	153	19	+	+	NOUN
hjic-751	153	20	)	)	PUNCT
hjic-751	153	21	and	and	CCONJ
hjic-751	153	22	the	the	DET
hjic-751	153	23	d	d	ADJ
hjic-751	153	24	-	-	PUNCT
hjic-751	153	25	type	type	NOUN
hjic-751	153	26	hyperporphyrins	hyperporphyrin	NOUN
hjic-751	153	27	(	(	PUNCT
hjic-751	153	28	because	because	SCONJ
hjic-751	153	29	their	their	PRON
hjic-751	153	30	structures	structure	NOUN
hjic-751	153	31	were	be	AUX
hjic-751	153	32	determined	determine	VERB
hjic-751	153	33	to	to	PART
hjic-751	153	34	be	be	AUX
hjic-751	153	35	totally	totally	ADV
hjic-751	153	36	planar	planar	ADJ
hjic-751	153	37	)	)	PUNCT
hjic-751	153	38	,	,	PUNCT
hjic-751	153	39	as	as	ADV
hjic-751	153	40	well	well	ADV
hjic-751	153	41	as	as	ADP
hjic-751	153	42	the	the	DET
hjic-751	153	43	p	p	NOUN
hjic-751	153	44	-	-	PUNCT
hjic-751	153	45	type	type	NOUN
hjic-751	153	46	hyperporphyrins	hyperporphyrin	NOUN
hjic-751	153	47	(	(	PUNCT
hjic-751	153	48	because	because	SCONJ
hjic-751	153	49	a	a	DET
hjic-751	153	50	ruffled	ruffle	VERB
hjic-751	153	51	-	-	PUNCT
hjic-751	153	52	like	like	ADJ
hjic-751	153	53	deformation	deformation	NOUN
hjic-751	153	54	did	do	AUX
hjic-751	153	55	not	not	PART
hjic-751	153	56	superpose	superpose	VERB
hjic-751	153	57	on	on	ADP
hjic-751	153	58	their	their	PRON
hjic-751	153	59	dome	dome	NOUN
hjic-751	153	60	-	-	PUNCT
hjic-751	153	61	like	like	ADJ
hjic-751	153	62	structure	structure	NOUN
hjic-751	153	63	)	)	PUNCT
hjic-751	153	64	.	.	PUNCT
hjic-751	154	1	the	the	DET
hjic-751	154	2	regression	regression	NOUN
hjic-751	154	3	of	of	ADP
hjic-751	154	4	correlation	correlation	NOUN
hjic-751	154	5	was	be	AUX
hjic-751	154	6	much	much	ADV
hjic-751	154	7	worse	bad	ADJ
hjic-751	154	8	within	within	ADP
hjic-751	154	9	the	the	DET
hjic-751	154	10	soret	soret	NOUN
hjic-751	154	11	band	band	NOUN
hjic-751	154	12	than	than	ADP
hjic-751	154	13	in	in	ADP
hjic-751	154	14	the	the	DET
hjic-751	154	15	case	case	NOUN
hjic-751	154	16	of	of	ADP
hjic-751	154	17	the	the	DET
hjic-751	154	18	q	q	NOUN
hjic-751	154	19	bands	band	NOUN
hjic-751	154	20	.	.	PUNCT
hjic-751	155	1	the	the	DET
hjic-751	155	2	soret	soret	PROPN
hjic-751	155	3	band	band	NOUN
hjic-751	155	4	was	be	AUX
hjic-751	155	5	also	also	ADV
hjic-751	155	6	split	split	VERB
hjic-751	155	7	in	in	ADP
hjic-751	155	8	the	the	DET
hjic-751	155	9	calculations	calculation	NOUN
hjic-751	155	10	,	,	PUNCT
hjic-751	155	11	which	which	PRON
hjic-751	155	12	can	can	AUX
hjic-751	155	13	not	not	PART
hjic-751	155	14	be	be	AUX
hjic-751	155	15	detected	detect	VERB
hjic-751	155	16	experimentally	experimentally	ADV
hjic-751	155	17	.	.	PUNCT
hjic-751	156	1	on	on	ADP
hjic-751	156	2	the	the	DET
hjic-751	156	3	basis	basis	NOUN
hjic-751	156	4	of	of	ADP
hjic-751	156	5	further	further	ADJ
hjic-751	156	6	experimental	experimental	ADJ
hjic-751	156	7	observations	observation	NOUN
hjic-751	156	8	and	and	CCONJ
hjic-751	156	9	doubts	doubt	NOUN
hjic-751	156	10	in	in	ADP
hjic-751	156	11	the	the	DET
hjic-751	156	12	literature	literature	NOUN
hjic-751	156	13	,	,	PUNCT
hjic-751	156	14	the	the	DET
hjic-751	156	15	validity	validity	NOUN
hjic-751	156	16	of	of	ADP
hjic-751	156	17	the	the	DET
hjic-751	156	18	theoretical	theoretical	ADJ
hjic-751	156	19	model	model	NOUN
hjic-751	156	20	in	in	ADP
hjic-751	156	21	use	use	NOUN
hjic-751	156	22	at	at	ADP
hjic-751	156	23	present	present	ADJ
hjic-751	156	24	is	be	AUX
hjic-751	156	25	questionable	questionable	ADJ
hjic-751	156	26	.	.	PUNCT
hjic-751	157	1	hence	hence	ADV
hjic-751	157	2	,	,	PUNCT
hjic-751	157	3	the	the	DET
hjic-751	157	4	development	development	NOUN
hjic-751	157	5	of	of	ADP
hjic-751	157	6	a	a	DET
hjic-751	157	7	more	more	ADV
hjic-751	157	8	suitable	suitable	ADJ
hjic-751	157	9	one	one	NUM
hjic-751	157	10	is	be	AUX
hjic-751	157	11	in	in	ADP
hjic-751	157	12	progress	progress	NOUN
hjic-751	157	13	.	.	PUNCT
hjic-751	158	1	4	4	X
hjic-751	158	2	.	.	X
hjic-751	158	3	conclusion	conclusion	NOUN
hjic-751	158	4	in	in	ADP
hjic-751	158	5	conclusion	conclusion	NOUN
hjic-751	158	6	,	,	PUNCT
hjic-751	158	7	it	it	PRON
hjic-751	158	8	can	can	AUX
hjic-751	158	9	be	be	AUX
hjic-751	158	10	declared	declare	VERB
hjic-751	158	11	that	that	SCONJ
hjic-751	158	12	the	the	DET
hjic-751	158	13	categorization	categorization	NOUN
hjic-751	158	14	of	of	ADP
hjic-751	158	15	metalloporphyrins	metalloporphyrin	NOUN
hjic-751	158	16	was	be	AUX
hjic-751	158	17	complemented	complement	VERB
hjic-751	158	18	by	by	ADP
hjic-751	158	19	the	the	DET
hjic-751	158	20	role	role	NOUN
hjic-751	158	21	of	of	ADP
hjic-751	158	22	their	their	PRON
hjic-751	158	23	distortion	distortion	NOUN
hjic-751	158	24	,	,	PUNCT
hjic-751	158	25	which	which	PRON
hjic-751	158	26	is	be	AUX
hjic-751	158	27	primarily	primarily	ADV
hjic-751	158	28	responsible	responsible	ADJ
hjic-751	158	29	for	for	ADP
hjic-751	158	30	their	their	PRON
hjic-751	158	31	spectral	spectral	ADJ
hjic-751	158	32	features	feature	NOUN
hjic-751	158	33	,	,	PUNCT
hjic-751	158	34	whereas	whereas	SCONJ
hjic-751	158	35	the	the	DET
hjic-751	158	36	electronic	electronic	ADJ
hjic-751	158	37	structure	structure	NOUN
hjic-751	158	38	of	of	ADP
hjic-751	158	39	their	their	PRON
hjic-751	158	40	metal	metal	NOUN
hjic-751	158	41	centers	center	NOUN
hjic-751	158	42	is	be	AUX
hjic-751	158	43	a	a	DET
hjic-751	158	44	secondary	secondary	ADJ
hjic-751	158	45	factor	factor	NOUN
hjic-751	158	46	,	,	PUNCT
hjic-751	158	47	with	with	ADP
hjic-751	158	48	a	a	DET
hjic-751	158	49	considerable	considerable	ADJ
hjic-751	158	50	level	level	NOUN
hjic-751	158	51	of	of	ADP
hjic-751	158	52	emphasis	emphasis	NOUN
hjic-751	158	53	on	on	ADP
hjic-751	158	54	the	the	DET
hjic-751	158	55	in	in	ADP
hjic-751	158	56	-	-	PUNCT
hjic-751	158	57	plane	plane	NOUN
hjic-751	158	58	complexes	complex	NOUN
hjic-751	158	59	.	.	PUNCT
hjic-751	159	1	the	the	DET
hjic-751	159	2	position	position	NOUN
hjic-751	159	3	of	of	ADP
hjic-751	159	4	the	the	DET
hjic-751	159	5	metal	metal	NOUN
hjic-751	159	6	center	center	NOUN
hjic-751	159	7	(	(	PUNCT
hjic-751	159	8	in	in	ADP
hjic-751	159	9	-	-	PUNCT
hjic-751	159	10	plane	plane	NOUN
hjic-751	159	11	or	or	CCONJ
hjic-751	159	12	out	out	ADP
hjic-751	159	13	-	-	PUNCT
hjic-751	159	14	of	of	ADP
hjic-751	159	15	-	-	PUNCT
hjic-751	159	16	plane	plane	NOUN
hjic-751	159	17	)	)	PUNCT
hjic-751	159	18	in	in	ADP
hjic-751	159	19	the	the	DET
hjic-751	159	20	monoporphyrin	monoporphyrin	NOUN
hjic-751	159	21	complexes	complex	NOUN
hjic-751	159	22	,	,	PUNCT
hjic-751	159	23	as	as	ADV
hjic-751	159	24	well	well	ADV
hjic-751	159	25	as	as	ADP
hjic-751	159	26	the	the	DET
hjic-751	159	27	type	type	NOUN
hjic-751	159	28	(	(	PUNCT
hjic-751	159	29	head	head	NOUN
hjic-751	159	30	-	-	PUNCT
hjic-751	159	31	to	to	ADP
hjic-751	159	32	-	-	PUNCT
hjic-751	159	33	head	head	NOUN
hjic-751	159	34	or	or	CCONJ
hjic-751	159	35	tail	tail	NOUN
hjic-751	159	36	-	-	PUNCT
hjic-751	159	37	to	to	ADP
hjic-751	159	38	-	-	PUNCT
hjic-751	159	39	tail	tail	NOUN
hjic-751	159	40	)	)	PUNCT
hjic-751	159	41	of	of	ADP
hjic-751	159	42	the	the	DET
hjic-751	159	43	bisporphyrin	bisporphyrin	NOUN
hjic-751	159	44	complexes	complex	NOUN
hjic-751	159	45	can	can	AUX
hjic-751	159	46	be	be	AUX
hjic-751	159	47	determined	determine	VERB
hjic-751	159	48	on	on	ADP
hjic-751	159	49	the	the	DET
hjic-751	159	50	basis	basis	NOUN
hjic-751	159	51	of	of	ADP
hjic-751	159	52	their	their	PRON
hjic-751	159	53	uv	uv	NOUN
hjic-751	159	54	-	-	PUNCT
hjic-751	159	55	vis	vis	X
hjic-751	159	56	absorption	absorption	NOUN
hjic-751	159	57	and	and	CCONJ
hjic-751	159	58	emission	emission	NOUN
hjic-751	159	59	properties	property	NOUN
hjic-751	159	60	.	.	PUNCT
hjic-751	160	1	study	study	NOUN
hjic-751	160	2	of	of	ADP
hjic-751	160	3	the	the	DET
hjic-751	160	4	out	out	NOUN
hjic-751	160	5	-	-	PUNCT
hjic-751	160	6	of	of	ADP
hjic-751	160	7	-	-	PUNCT
hjic-751	160	8	plane	plane	NOUN
hjic-751	160	9	metalloporphyrins	metalloporphyrin	NOUN
hjic-751	160	10	45(1	45(1	NOUN
hjic-751	160	11	)	)	PUNCT
hjic-751	160	12	pp	pp	ADV
hjic-751	160	13	.	.	PUNCT
hjic-751	161	1	29–36	29–36	NUM
hjic-751	161	2	(	(	PUNCT
hjic-751	161	3	2017	2017	NUM
hjic-751	161	4	)	)	PUNCT
hjic-751	161	5	35	35	NUM
hjic-751	161	6	hyperporphyrin	hyperporphyrin	NOUN
hjic-751	161	7	spectra	spectra	NOUN
hjic-751	161	8	can	can	AUX
hjic-751	161	9	appear	appear	VERB
hjic-751	161	10	,	,	PUNCT
hjic-751	161	11	owing	owe	VERB
hjic-751	161	12	to	to	ADP
hjic-751	161	13	the	the	DET
hjic-751	161	14	peripheral	peripheral	ADJ
hjic-751	161	15	substitution	substitution	NOUN
hjic-751	161	16	(	(	PUNCT
hjic-751	161	17	octabromination	octabromination	NOUN
hjic-751	161	18	)	)	PUNCT
hjic-751	161	19	of	of	ADP
hjic-751	161	20	free	free	ADJ
hjic-751	161	21	-	-	PUNCT
hjic-751	161	22	base	base	NOUN
hjic-751	161	23	ligands	ligand	NOUN
hjic-751	161	24	.	.	PUNCT
hjic-751	162	1	furthermore	furthermore	ADV
hjic-751	162	2	,	,	PUNCT
hjic-751	162	3	the	the	DET
hjic-751	162	4	high	high	ADJ
hjic-751	162	5	degree	degree	NOUN
hjic-751	162	6	of	of	ADP
hjic-751	162	7	redshift	redshift	NOUN
hjic-751	162	8	may	may	AUX
hjic-751	162	9	disappear	disappear	VERB
hjic-751	162	10	during	during	ADP
hjic-751	162	11	the	the	DET
hjic-751	162	12	spin	spin	NOUN
hjic-751	162	13	isomerization	isomerization	NOUN
hjic-751	162	14	of	of	ADP
hjic-751	162	15	d	d	ADJ
hjic-751	162	16	-	-	PUNCT
hjic-751	162	17	type	type	NOUN
hjic-751	162	18	metalloporphyrins	metalloporphyrin	NOUN
hjic-751	162	19	or	or	CCONJ
hjic-751	162	20	the	the	DET
hjic-751	162	21	transformation	transformation	NOUN
hjic-751	162	22	of	of	ADP
hjic-751	162	23	p	p	NOUN
hjic-751	162	24	-	-	PUNCT
hjic-751	162	25	type	type	NOUN
hjic-751	162	26	ones	one	NOUN
hjic-751	162	27	.	.	PUNCT
hjic-751	163	1	consequently	consequently	ADV
hjic-751	163	2	,	,	PUNCT
hjic-751	163	3	the	the	DET
hjic-751	163	4	real	real	ADJ
hjic-751	163	5	origin	origin	NOUN
hjic-751	163	6	can	can	AUX
hjic-751	163	7	not	not	PART
hjic-751	163	8	be	be	AUX
hjic-751	163	9	an	an	DET
hjic-751	163	10	electronic	electronic	ADJ
hjic-751	163	11	but	but	CCONJ
hjic-751	163	12	rather	rather	ADV
hjic-751	163	13	a	a	DET
hjic-751	163	14	steric	steric	ADJ
hjic-751	163	15	effect	effect	NOUN
hjic-751	163	16	,	,	PUNCT
hjic-751	163	17	namely	namely	ADV
hjic-751	163	18	the	the	DET
hjic-751	163	19	measure	measure	NOUN
hjic-751	163	20	of	of	ADP
hjic-751	163	21	distortion	distortion	NOUN
hjic-751	163	22	,	,	PUNCT
hjic-751	163	23	which	which	PRON
hjic-751	163	24	can	can	AUX
hjic-751	163	25	confirm	confirm	VERB
hjic-751	163	26	the	the	DET
hjic-751	163	27	absence	absence	NOUN
hjic-751	163	28	of	of	ADP
hjic-751	163	29	their	their	PRON
hjic-751	163	30	fluorescence	fluorescence	NOUN
hjic-751	163	31	.	.	PUNCT
hjic-751	164	1	in	in	ADP
hjic-751	164	2	terms	term	NOUN
hjic-751	164	3	of	of	ADP
hjic-751	164	4	photochemical	photochemical	ADJ
hjic-751	164	5	activity	activity	NOUN
hjic-751	164	6	,	,	PUNCT
hjic-751	164	7	several	several	ADJ
hjic-751	164	8	dissimilarities	dissimilarity	NOUN
hjic-751	164	9	were	be	AUX
hjic-751	164	10	found	find	VERB
hjic-751	164	11	between	between	ADP
hjic-751	164	12	the	the	DET
hjic-751	164	13	in	in	ADP
hjic-751	164	14	-	-	PUNCT
hjic-751	164	15	plane	plane	NOUN
hjic-751	164	16	and	and	CCONJ
hjic-751	164	17	outof	outof	ADJ
hjic-751	164	18	-	-	PUNCT
hjic-751	164	19	plane	plane	NOUN
hjic-751	164	20	metalloporphyrins	metalloporphyrin	NOUN
hjic-751	164	21	;	;	PUNCT
hjic-751	164	22	the	the	DET
hjic-751	164	23	most	most	ADV
hjic-751	164	24	remarkable	remarkable	ADJ
hjic-751	164	25	of	of	ADP
hjic-751	164	26	them	they	PRON
hjic-751	164	27	was	be	AUX
hjic-751	164	28	the	the	DET
hjic-751	164	29	mechanism	mechanism	NOUN
hjic-751	164	30	of	of	ADP
hjic-751	164	31	their	their	PRON
hjic-751	164	32	photoredox	photoredox	NOUN
hjic-751	164	33	reactions	reaction	NOUN
hjic-751	164	34	:	:	PUNCT
hjic-751	164	35	outer	outer	ADJ
hjic-751	164	36	-	-	PUNCT
hjic-751	164	37	sphere	sphere	NOUN
hjic-751	164	38	electron	electron	NOUN
hjic-751	164	39	transfer	transfer	NOUN
hjic-751	164	40	is	be	AUX
hjic-751	164	41	typical	typical	ADJ
hjic-751	164	42	of	of	ADP
hjic-751	164	43	the	the	DET
hjic-751	164	44	previous	previous	ADJ
hjic-751	164	45	ones	one	NOUN
hjic-751	164	46	,	,	PUNCT
hjic-751	164	47	while	while	SCONJ
hjic-751	164	48	the	the	DET
hjic-751	164	49	inner	inner	ADJ
hjic-751	164	50	-	-	PUNCT
hjic-751	164	51	sphere	sphere	NOUN
hjic-751	164	52	equivalent	equivalent	NOUN
hjic-751	164	53	is	be	AUX
hjic-751	164	54	most	most	ADV
hjic-751	164	55	prevalent	prevalent	ADJ
hjic-751	164	56	for	for	ADP
hjic-751	164	57	the	the	DET
hjic-751	164	58	latter	latter	ADJ
hjic-751	164	59	ones	one	NOUN
hjic-751	164	60	.	.	PUNCT
hjic-751	165	1	as	as	ADP
hjic-751	165	2	a	a	DET
hjic-751	165	3	further	further	ADJ
hjic-751	165	4	consequence	consequence	NOUN
hjic-751	165	5	of	of	ADP
hjic-751	165	6	the	the	DET
hjic-751	165	7	oop	oop	NOUN
hjic-751	165	8	position	position	NOUN
hjic-751	165	9	of	of	ADP
hjic-751	165	10	the	the	DET
hjic-751	165	11	metal	metal	NOUN
hjic-751	165	12	center	center	NOUN
hjic-751	165	13	,	,	PUNCT
hjic-751	165	14	photoinduced	photoinduce	VERB
hjic-751	165	15	dissociation	dissociation	NOUN
hjic-751	165	16	and	and	CCONJ
hjic-751	165	17	transformation	transformation	NOUN
hjic-751	165	18	reactions	reaction	NOUN
hjic-751	165	19	can	can	AUX
hjic-751	165	20	occur	occur	VERB
hjic-751	165	21	within	within	ADP
hjic-751	165	22	their	their	PRON
hjic-751	165	23	complexes	complex	NOUN
hjic-751	165	24	.	.	PUNCT
hjic-751	166	1	in	in	ADP
hjic-751	166	2	our	our	PRON
hjic-751	166	3	electronic	electronic	ADJ
hjic-751	166	4	structural	structural	ADJ
hjic-751	166	5	calculations	calculation	NOUN
hjic-751	166	6	,	,	PUNCT
hjic-751	166	7	the	the	DET
hjic-751	166	8	number	number	NOUN
hjic-751	166	9	of	of	ADP
hjic-751	166	10	borderline	borderline	NOUN
hjic-751	166	11	-	-	PUNCT
hjic-751	166	12	case	case	NOUN
hjic-751	166	13	complexes	complex	NOUN
hjic-751	166	14	expanded	expand	VERB
hjic-751	166	15	,	,	PUNCT
hjic-751	166	16	on	on	ADP
hjic-751	166	17	the	the	DET
hjic-751	166	18	basis	basis	NOUN
hjic-751	166	19	of	of	ADP
hjic-751	166	20	which	which	PRON
hjic-751	166	21	common	common	ADJ
hjic-751	166	22	oop	oop	NOUN
hjic-751	166	23	characteristics	characteristic	NOUN
hjic-751	166	24	that	that	PRON
hjic-751	166	25	can	can	AUX
hjic-751	166	26	be	be	AUX
hjic-751	166	27	experimentally	experimentally	ADV
hjic-751	166	28	observed	observe	VERB
hjic-751	166	29	may	may	AUX
hjic-751	166	30	acquire	acquire	VERB
hjic-751	166	31	a	a	DET
hjic-751	166	32	novel	novel	ADJ
hjic-751	166	33	explanation	explanation	NOUN
hjic-751	166	34	.	.	PUNCT
hjic-751	167	1	acknowledgement	acknowledgement	NOUN
hjic-751	167	2	this	this	DET
hjic-751	167	3	research	research	NOUN
hjic-751	167	4	was	be	AUX
hjic-751	167	5	supported	support	VERB
hjic-751	167	6	by	by	ADP
hjic-751	167	7	the	the	DET
hjic-751	167	8	széchenyi	széchenyi	PROPN
hjic-751	167	9	2020	2020	NUM
hjic-751	167	10	fund	fund	NOUN
hjic-751	167	11	under	under	ADP
hjic-751	167	12	the	the	DET
hjic-751	167	13	ginop-2.3.2	ginop-2.3.2	NOUN
hjic-751	167	14	-	-	PUNCT
hjic-751	167	15	15	15	NUM
hjic-751	167	16	-	-	PUNCT
hjic-751	167	17	2016	2016	NUM
hjic-751	167	18	-	-	PUNCT
hjic-751	167	19	00016	00016	NUM
hjic-751	167	20	and	and	CCONJ
hjic-751	167	21	efop-3.6.1	efop-3.6.1	NUM
hjic-751	167	22	-	-	SYM
hjic-751	167	23	16	16	NUM
hjic-751	167	24	-	-	PUNCT
hjic-751	167	25	2016	2016	NUM
hjic-751	167	26	-	-	PUNCT
hjic-751	167	27	00015	00015	NUM
hjic-751	167	28	projects	project	NOUN
hjic-751	167	29	.	.	PUNCT
hjic-751	168	1	assistance	assistance	NOUN
hjic-751	168	2	with	with	ADP
hjic-751	168	3	quantum	quantum	ADJ
hjic-751	168	4	chemical	chemical	NOUN
hjic-751	168	5	calculations	calculation	NOUN
hjic-751	168	6	provided	provide	VERB
hjic-751	168	7	by	by	ADP
hjic-751	168	8	professor	professor	NOUN
hjic-751	168	9	györgy	györgy	PROPN
hjic-751	168	10	lendvay	lendvay	PROPN
hjic-751	168	11	(	(	PUNCT
hjic-751	168	12	research	research	NOUN
hjic-751	168	13	centre	centre	NOUN
hjic-751	168	14	for	for	ADP
hjic-751	168	15	natural	natural	ADJ
hjic-751	168	16	sciences	science	NOUN
hjic-751	168	17	,	,	PUNCT
hjic-751	168	18	hungarian	hungarian	ADJ
hjic-751	168	19	academy	academy	NOUN
hjic-751	168	20	of	of	ADP
hjic-751	168	21	sciences	sciences	PROPN
hjic-751	168	22	)	)	PUNCT
hjic-751	168	23	is	be	AUX
hjic-751	168	24	gratefully	gratefully	ADV
hjic-751	168	25	acknowledged	acknowledge	VERB
hjic-751	168	26	.	.	PUNCT
hjic-751	169	1	finally	finally	ADV
hjic-751	169	2	,	,	PUNCT
hjic-751	169	3	this	this	DET
hjic-751	169	4	manuscript	manuscript	NOUN
hjic-751	169	5	is	be	AUX
hjic-751	169	6	dedicated	dedicate	VERB
hjic-751	169	7	to	to	ADP
hjic-751	169	8	the	the	DET
hjic-751	169	9	memory	memory	NOUN
hjic-751	169	10	of	of	ADP
hjic-751	169	11	professor	professor	NOUN
hjic-751	169	12	jános	jáno	VERB
hjic-751	169	13	liszi	liszi	PROPN
hjic-751	169	14	,	,	PUNCT
hjic-751	169	15	who	who	PRON
hjic-751	169	16	,	,	PUNCT
hjic-751	169	17	as	as	ADP
hjic-751	169	18	the	the	DET
hjic-751	169	19	head	head	NOUN
hjic-751	169	20	of	of	ADP
hjic-751	169	21	the	the	DET
hjic-751	169	22	doctoral	doctoral	ADJ
hjic-751	169	23	school	school	NOUN
hjic-751	169	24	for	for	ADP
hjic-751	169	25	chemistry	chemistry	NOUN
hjic-751	169	26	at	at	ADP
hjic-751	169	27	the	the	DET
hjic-751	169	28	university	university	PROPN
hjic-751	169	29	of	of	ADP
hjic-751	169	30	veszprém	veszprém	NOUN
hjic-751	169	31	,	,	PUNCT
hjic-751	169	32	praised	praise	VERB
hjic-751	169	33	the	the	DET
hjic-751	169	34	corresponding	corresponding	ADJ
hjic-751	169	35	author	author	NOUN
hjic-751	169	36	’s	’s	PART
hjic-751	169	37	phd	phd	NOUN
hjic-751	169	38	dissertation	dissertation	NOUN
hjic-751	169	39	of	of	ADP
hjic-751	169	40	a	a	DET
hjic-751	169	41	similar	similar	ADJ
hjic-751	169	42	title	title	NOUN
hjic-751	169	43	in	in	ADP
hjic-751	169	44	2007	2007	NUM
hjic-751	169	45	.	.	PUNCT
hjic-751	170	1	references	reference	NOUN
hjic-751	170	2	[	[	X
hjic-751	170	3	1	1	NUM
hjic-751	170	4	]	]	X
hjic-751	170	5	valicsek	valicsek	PROPN
hjic-751	170	6	,	,	PUNCT
hjic-751	170	7	z.	z.	PROPN
hjic-751	170	8	;	;	PUNCT
hjic-751	170	9	horváth	horváth	PROPN
hjic-751	170	10	,	,	PUNCT
hjic-751	170	11	o.	o.	NOUN
hjic-751	170	12	:	:	PUNCT
hjic-751	170	13	application	application	NOUN
hjic-751	170	14	of	of	ADP
hjic-751	170	15	the	the	DET
hjic-751	170	16	electronic	electronic	ADJ
hjic-751	170	17	spectra	spectra	NOUN
hjic-751	170	18	of	of	ADP
hjic-751	170	19	porphyrins	porphyrin	NOUN
hjic-751	170	20	for	for	ADP
hjic-751	170	21	analytical	analytical	ADJ
hjic-751	170	22	purposes	purpose	NOUN
hjic-751	170	23	:	:	PUNCT
hjic-751	170	24	the	the	DET
hjic-751	170	25	effects	effect	NOUN
hjic-751	170	26	of	of	ADP
hjic-751	170	27	metal	metal	NOUN
hjic-751	170	28	ions	ion	NOUN
hjic-751	170	29	and	and	CCONJ
hjic-751	170	30	structural	structural	ADJ
hjic-751	170	31	distortions	distortion	NOUN
hjic-751	170	32	,	,	PUNCT
hjic-751	170	33	microchem	microchem	NOUN
hjic-751	170	34	.	.	PUNCT
hjic-751	171	1	j.	j.	PROPN
hjic-751	171	2	,	,	PUNCT
hjic-751	171	3	2013	2013	NUM
hjic-751	171	4	107	107	NUM
hjic-751	171	5	,	,	PUNCT
hjic-751	171	6	47–62	47–62	NUM
hjic-751	171	7	doi	doi	NOUN
hjic-751	171	8	:	:	PUNCT
hjic-751	171	9	10.1016	10.1016	NUM
hjic-751	171	10	/	/	SYM
hjic-751	171	11	j.microc.2012.07.002	j.microc.2012.07.002	PROPN
hjic-751	172	1	[	[	X
hjic-751	172	2	2	2	NUM
hjic-751	172	3	]	]	PUNCT
hjic-751	172	4	horváth	horváth	NOUN
hjic-751	172	5	,	,	PUNCT
hjic-751	172	6	o.	o.	PROPN
hjic-751	172	7	;	;	PUNCT
hjic-751	172	8	valicsek	valicsek	VERB
hjic-751	172	9	,	,	PUNCT
hjic-751	172	10	z.	z.	PROPN
hjic-751	172	11	;	;	PUNCT
hjic-751	172	12	fodor	fodor	PROPN
hjic-751	172	13	,	,	PUNCT
hjic-751	172	14	m.a	m.a	PROPN
hjic-751	172	15	.	.	PROPN
hjic-751	172	16	;	;	PUNCT
hjic-751	172	17	major	major	PROPN
hjic-751	172	18	,	,	PUNCT
hjic-751	172	19	m.m	m.m	PROPN
hjic-751	172	20	.	.	PROPN
hjic-751	172	21	;	;	PUNCT
hjic-751	172	22	imran	imran	PROPN
hjic-751	172	23	,	,	PUNCT
hjic-751	172	24	m.	m.	NOUN
hjic-751	172	25	;	;	PUNCT
hjic-751	172	26	grampp	grampp	PROPN
hjic-751	172	27	,	,	PUNCT
hjic-751	172	28	g.	g.	PROPN
hjic-751	172	29	;	;	PUNCT
hjic-751	172	30	wankmüller	wankmüller	NOUN
hjic-751	172	31	,	,	PUNCT
hjic-751	172	32	a.	a.	NOUN
hjic-751	172	33	:	:	PUNCT
hjic-751	172	34	visible	visible	ADJ
hjic-751	172	35	light	light	NOUN
hjic-751	172	36	-	-	PUNCT
hjic-751	172	37	driven	drive	VERB
hjic-751	172	38	photophysics	photophysic	NOUN
hjic-751	172	39	and	and	CCONJ
hjic-751	172	40	photochemistry	photochemistry	NOUN
hjic-751	172	41	of	of	ADP
hjic-751	172	42	water	water	NOUN
hjic-751	172	43	-	-	PUNCT
hjic-751	172	44	soluble	soluble	ADJ
hjic-751	172	45	metalloporphyrins	metalloporphyrin	NOUN
hjic-751	172	46	,	,	PUNCT
hjic-751	172	47	coord	coord	NOUN
hjic-751	172	48	.	.	PUNCT
hjic-751	173	1	chem	chem	PROPN
hjic-751	173	2	.	.	PUNCT
hjic-751	174	1	rev	rev	PROPN
hjic-751	174	2	.	.	PROPN
hjic-751	174	3	,	,	PUNCT
hjic-751	174	4	2016	2016	NUM
hjic-751	174	5	325	325	NUM
hjic-751	174	6	,	,	PUNCT
hjic-751	174	7	59–66	59–66	NUM
hjic-751	174	8	doi	doi	NOUN
hjic-751	174	9	:	:	PUNCT
hjic-751	175	1	10.1016	10.1016	NUM
hjic-751	175	2	/	/	SYM
hjic-751	175	3	j.ccr.2015.12.011	j.ccr.2015.12.011	PROPN
hjic-751	176	1	[	[	X
hjic-751	176	2	3	3	NUM
hjic-751	176	3	]	]	X
hjic-751	176	4	shelnutt	shelnutt	NOUN
hjic-751	176	5	,	,	PUNCT
hjic-751	176	6	j.a	j.a	PROPN
hjic-751	176	7	.	.	PROPN
hjic-751	176	8	;	;	PUNCT
hjic-751	176	9	song	song	NOUN
hjic-751	176	10	,	,	PUNCT
hjic-751	176	11	x.-z	x.-z	PROPN
hjic-751	176	12	.	.	PUNCT
hjic-751	176	13	;	;	PUNCT
hjic-751	176	14	ma	ma	PROPN
hjic-751	176	15	,	,	PUNCT
hjic-751	176	16	j.-g	j.-g	PROPN
hjic-751	176	17	.	.	PROPN
hjic-751	176	18	;	;	PUNCT
hjic-751	176	19	jia	jia	PROPN
hjic-751	176	20	,	,	PUNCT
hjic-751	176	21	s.-l	s.-l	NOUN
hjic-751	176	22	.	.	PUNCT
hjic-751	177	1	;	;	PUNCT
hjic-751	177	2	jentzen	jentzen	PROPN
hjic-751	177	3	,	,	PUNCT
hjic-751	177	4	w.	w.	PROPN
hjic-751	177	5	;	;	PUNCT
hjic-751	177	6	medforth	medforth	NOUN
hjic-751	177	7	,	,	PUNCT
hjic-751	177	8	c.j	c.j	PROPN
hjic-751	177	9	.	.	PROPN
hjic-751	177	10	:	:	PUNCT
hjic-751	177	11	nonplanar	nonplanar	NOUN
hjic-751	177	12	porphyrins	porphyrin	NOUN
hjic-751	177	13	and	and	CCONJ
hjic-751	177	14	their	their	PRON
hjic-751	177	15	significance	significance	NOUN
hjic-751	177	16	in	in	ADP
hjic-751	177	17	proteins	protein	NOUN
hjic-751	177	18	,	,	PUNCT
hjic-751	177	19	chem	chem	NOUN
hjic-751	177	20	.	.	PUNCT
hjic-751	178	1	soc	soc	PROPN
hjic-751	178	2	.	.	PUNCT
hjic-751	179	1	rev	rev	PROPN
hjic-751	179	2	.	.	PROPN
hjic-751	179	3	,	,	PUNCT
hjic-751	179	4	1998	1998	NUM
hjic-751	179	5	27	27	NUM
hjic-751	179	6	,	,	PUNCT
hjic-751	179	7	31–41	31–41	NUM
hjic-751	179	8	doi	doi	NOUN
hjic-751	179	9	:	:	PUNCT
hjic-751	179	10	10.1039	10.1039	NUM
hjic-751	179	11	/	/	SYM
hjic-751	179	12	a827031z	a827031z	X
hjic-751	180	1	[	[	X
hjic-751	180	2	4	4	NUM
hjic-751	180	3	]	]	X
hjic-751	180	4	valicsek	valicsek	VERB
hjic-751	180	5	,	,	PUNCT
hjic-751	180	6	z.	z.	PROPN
hjic-751	180	7	;	;	PUNCT
hjic-751	180	8	horváth	horváth	PROPN
hjic-751	180	9	,	,	PUNCT
hjic-751	180	10	o.	o.	PROPN
hjic-751	180	11	;	;	PUNCT
hjic-751	180	12	lendvay	lendvay	NOUN
hjic-751	180	13	,	,	PUNCT
hjic-751	180	14	g.	g.	PROPN
hjic-751	180	15	;	;	PUNCT
hjic-751	180	16	kikaš	kikaš	PROPN
hjic-751	180	17	,	,	PUNCT
hjic-751	180	18	i.	i.	PROPN
hjic-751	180	19	;	;	PUNCT
hjic-751	180	20	škorić	škorić	NOUN
hjic-751	180	21	,	,	PUNCT
hjic-751	180	22	i.	i.	NOUN
hjic-751	180	23	:	:	PUNCT
hjic-751	181	1	formation	formation	NOUN
hjic-751	181	2	,	,	PUNCT
hjic-751	181	3	photophysics	photophysic	NOUN
hjic-751	181	4	,	,	PUNCT
hjic-751	181	5	and	and	CCONJ
hjic-751	181	6	photochemistry	photochemistry	NOUN
hjic-751	181	7	of	of	ADP
hjic-751	181	8	cadmium(ii	cadmium(ii	NOUN
hjic-751	181	9	)	)	PUNCT
hjic-751	181	10	complexes	complex	NOUN
hjic-751	181	11	with	with	ADP
hjic-751	181	12	5,10,15,20	5,10,15,20	NUM
hjic-751	181	13	-	-	PUNCT
hjic-751	181	14	tetrakis(4	tetrakis(4	NOUN
hjic-751	181	15	-	-	PUNCT
hjic-751	181	16	sulfonatophenyl)porphyrin	sulfonatophenyl)porphyrin	PROPN
hjic-751	181	17	and	and	CCONJ
hjic-751	181	18	its	its	PRON
hjic-751	181	19	octabromo	octabromo	NOUN
hjic-751	181	20	derivative	derivative	NOUN
hjic-751	181	21	:	:	PUNCT
hjic-751	181	22	the	the	DET
hjic-751	181	23	effects	effect	NOUN
hjic-751	181	24	of	of	ADP
hjic-751	181	25	bromination	bromination	NOUN
hjic-751	181	26	and	and	CCONJ
hjic-751	181	27	the	the	DET
hjic-751	181	28	axial	axial	ADJ
hjic-751	181	29	hydroxo	hydroxo	NOUN
hjic-751	181	30	ligand	ligand	PROPN
hjic-751	181	31	,	,	PUNCT
hjic-751	181	32	j.	j.	PROPN
hjic-751	181	33	photochem	photochem	PROPN
hjic-751	181	34	.	.	PUNCT
hjic-751	182	1	photobiol	photobiol	PROPN
hjic-751	182	2	.	.	PUNCT
hjic-751	183	1	a	a	DET
hjic-751	183	2	,	,	PUNCT
hjic-751	183	3	2011	2011	NUM
hjic-751	183	4	218	218	NUM
hjic-751	183	5	,	,	PUNCT
hjic-751	183	6	143–155	143–155	NUM
hjic-751	183	7	doi	doi	NOUN
hjic-751	183	8	:	:	PUNCT
hjic-751	183	9	10.1016	10.1016	NUM
hjic-751	183	10	/	/	SYM
hjic-751	183	11	j.jphotochem.2010.12.014	j.jphotochem.2010.12.014	PROPN
hjic-751	184	1	[	[	X
hjic-751	184	2	5	5	NUM
hjic-751	184	3	]	]	X
hjic-751	184	4	fodor	fodor	PROPN
hjic-751	184	5	,	,	PUNCT
hjic-751	184	6	m.a	m.a	PROPN
hjic-751	184	7	.	.	PROPN
hjic-751	184	8	;	;	PUNCT
hjic-751	184	9	horváth	horváth	PROPN
hjic-751	184	10	,	,	PUNCT
hjic-751	184	11	o.	o.	PROPN
hjic-751	184	12	;	;	PUNCT
hjic-751	184	13	fodor	fodor	PROPN
hjic-751	184	14	,	,	PUNCT
hjic-751	184	15	l.	l.	PROPN
hjic-751	184	16	;	;	PUNCT
hjic-751	184	17	grampp	grampp	PROPN
hjic-751	184	18	,	,	PUNCT
hjic-751	184	19	g.	g.	PROPN
hjic-751	184	20	;	;	PUNCT
hjic-751	184	21	wankmüller	wankmüller	NOUN
hjic-751	184	22	,	,	PUNCT
hjic-751	184	23	a.	a.	NOUN
hjic-751	184	24	:	:	PUNCT
hjic-751	184	25	photophysical	photophysical	ADJ
hjic-751	184	26	and	and	CCONJ
hjic-751	184	27	photocatalytic	photocatalytic	ADJ
hjic-751	184	28	behavior	behavior	NOUN
hjic-751	184	29	of	of	ADP
hjic-751	184	30	cobalt(iii	cobalt(iii	NOUN
hjic-751	184	31	)	)	PUNCT
hjic-751	184	32	5,10,15,20	5,10,15,20	NUM
hjic-751	184	33	-	-	PUNCT
hjic-751	184	34	tetrakis(1methylpyridinium-4	tetrakis(1methylpyridinium-4	VERB
hjic-751	184	35	-	-	PUNCT
hjic-751	184	36	yl)porphyrin	yl)porphyrin	NOUN
hjic-751	184	37	,	,	PUNCT
hjic-751	184	38	inorg	inorg	PROPN
hjic-751	184	39	.	.	PUNCT
hjic-751	184	40	chem	chem	PROPN
hjic-751	184	41	.	.	PUNCT
hjic-751	185	1	commun	commun	PROPN
hjic-751	185	2	.	.	PROPN
hjic-751	185	3	,	,	PUNCT
hjic-751	185	4	2014	2014	NUM
hjic-751	185	5	50	50	NUM
hjic-751	185	6	,	,	PUNCT
hjic-751	185	7	110–112	110–112	NUM
hjic-751	185	8	doi	doi	NOUN
hjic-751	185	9	:	:	PUNCT
hjic-751	185	10	10.1016	10.1016	NUM
hjic-751	185	11	/	/	SYM
hjic-751	185	12	j.inoche.2014.10.029	j.inoche.2014.10.029	NOUN
hjic-751	186	1	[	[	X
hjic-751	186	2	6	6	NUM
hjic-751	186	3	]	]	X
hjic-751	186	4	fodor	fodor	PROPN
hjic-751	186	5	,	,	PUNCT
hjic-751	186	6	m.a	m.a	PROPN
hjic-751	186	7	.	.	PROPN
hjic-751	186	8	;	;	PUNCT
hjic-751	186	9	horváth	horváth	PROPN
hjic-751	186	10	,	,	PUNCT
hjic-751	186	11	o.	o.	PROPN
hjic-751	186	12	;	;	PUNCT
hjic-751	186	13	fodor	fodor	PROPN
hjic-751	186	14	,	,	PUNCT
hjic-751	186	15	l.	l.	PROPN
hjic-751	186	16	;	;	PUNCT
hjic-751	186	17	vazdar	vazdar	PROPN
hjic-751	186	18	,	,	PUNCT
hjic-751	186	19	k.	k.	PROPN
hjic-751	186	20	;	;	PUNCT
hjic-751	186	21	grampp	grampp	PROPN
hjic-751	186	22	,	,	PUNCT
hjic-751	186	23	g.	g.	PROPN
hjic-751	186	24	;	;	PUNCT
hjic-751	186	25	wankmüller	wankmüller	NOUN
hjic-751	186	26	,	,	PUNCT
hjic-751	186	27	a.	a.	NOUN
hjic-751	186	28	:	:	PUNCT
hjic-751	186	29	photophysical	photophysical	ADJ
hjic-751	186	30	and	and	CCONJ
hjic-751	186	31	photochemical	photochemical	ADJ
hjic-751	186	32	properties	property	NOUN
hjic-751	186	33	of	of	ADP
hjic-751	186	34	manganese	manganese	ADJ
hjic-751	186	35	complexes	complex	NOUN
hjic-751	186	36	with	with	ADP
hjic-751	186	37	cationic	cationic	ADJ
hjic-751	186	38	porphyrin	porphyrin	NOUN
hjic-751	186	39	ligands	ligand	NOUN
hjic-751	186	40	:	:	PUNCT
hjic-751	186	41	effects	effect	NOUN
hjic-751	186	42	of	of	ADP
hjic-751	186	43	alkyl	alkyl	ADJ
hjic-751	186	44	substituents	substituent	NOUN
hjic-751	186	45	and	and	CCONJ
hjic-751	186	46	micellar	micellar	NOUN
hjic-751	186	47	environment	environment	NOUN
hjic-751	186	48	,	,	PUNCT
hjic-751	186	49	j.	j.	PROPN
hjic-751	186	50	photochem	photochem	PROPN
hjic-751	186	51	.	.	PUNCT
hjic-751	187	1	photobiol	photobiol	PROPN
hjic-751	187	2	.	.	PUNCT
hjic-751	188	1	a	a	DET
hjic-751	188	2	,	,	PUNCT
hjic-751	188	3	2016	2016	NUM
hjic-751	188	4	328	328	NUM
hjic-751	188	5	,	,	PUNCT
hjic-751	188	6	233–239	233–239	NUM
hjic-751	188	7	doi	doi	NOUN
hjic-751	188	8	:	:	PUNCT
hjic-751	188	9	10.1016	10.1016	NUM
hjic-751	188	10	/	/	SYM
hjic-751	188	11	j.jphotochem.2016.06.011	j.jphotochem.2016.06.011	X
hjic-751	189	1	[	[	X
hjic-751	189	2	7	7	NUM
hjic-751	189	3	]	]	X
hjic-751	189	4	major	major	ADJ
hjic-751	189	5	,	,	PUNCT
hjic-751	189	6	m.m	m.m	PROPN
hjic-751	189	7	.	.	PROPN
hjic-751	189	8	;	;	PUNCT
hjic-751	189	9	horváth	horváth	PROPN
hjic-751	189	10	,	,	PUNCT
hjic-751	189	11	o.	o.	PROPN
hjic-751	189	12	;	;	PUNCT
hjic-751	189	13	fodor	fodor	PROPN
hjic-751	189	14	,	,	PUNCT
hjic-751	189	15	m.a	m.a	PROPN
hjic-751	189	16	.	.	PROPN
hjic-751	189	17	;	;	PUNCT
hjic-751	189	18	fodor	fodor	PROPN
hjic-751	189	19	,	,	PUNCT
hjic-751	189	20	l.	l.	PROPN
hjic-751	189	21	;	;	PUNCT
hjic-751	189	22	valicsek	valicsek	PROPN
hjic-751	189	23	,	,	PUNCT
hjic-751	189	24	z.	z.	PROPN
hjic-751	189	25	;	;	PUNCT
hjic-751	189	26	grampp	grampp	PROPN
hjic-751	189	27	,	,	PUNCT
hjic-751	189	28	g.	g.	PROPN
hjic-751	189	29	;	;	PUNCT
hjic-751	189	30	wankmüller	wankmüller	NOUN
hjic-751	189	31	,	,	PUNCT
hjic-751	189	32	a.	a.	NOUN
hjic-751	189	33	:	:	PUNCT
hjic-751	189	34	photophysical	photophysical	ADJ
hjic-751	189	35	and	and	CCONJ
hjic-751	189	36	photocatalytic	photocatalytic	ADJ
hjic-751	189	37	behavior	behavior	NOUN
hjic-751	189	38	of	of	ADP
hjic-751	189	39	nickel(ii	nickel(ii	NOUN
hjic-751	189	40	)	)	PUNCT
hjic-751	189	41	5,10,15,20	5,10,15,20	PROPN
hjic-751	189	42	-	-	PUNCT
hjic-751	189	43	tetrakis(1	tetrakis(1	NOUN
hjic-751	189	44	-	-	PUNCT
hjic-751	189	45	methylpyridinium-4	methylpyridinium-4	NUM
hjic-751	189	46	-	-	PUNCT
hjic-751	189	47	yl	yl	NOUN
hjic-751	189	48	)	)	PUNCT
hjic-751	189	49	porphyrin	porphyrin	NOUN
hjic-751	189	50	,	,	PUNCT
hjic-751	189	51	inorg	inorg	PROPN
hjic-751	189	52	.	.	PUNCT
hjic-751	190	1	chem	chem	PROPN
hjic-751	190	2	.	.	PUNCT
hjic-751	191	1	commun	commun	PROPN
hjic-751	191	2	.	.	PROPN
hjic-751	191	3	,	,	PUNCT
hjic-751	191	4	2016	2016	NUM
hjic-751	191	5	73	73	NUM
hjic-751	191	6	,	,	PUNCT
hjic-751	191	7	1–3	1–3	NUM
hjic-751	191	8	doi	doi	NOUN
hjic-751	191	9	:	:	PUNCT
hjic-751	192	1	10.1016	10.1016	NUM
hjic-751	192	2	/	/	SYM
hjic-751	192	3	j.inoche.2016.09.001	j.inoche.2016.09.001	PROPN
hjic-751	193	1	[	[	X
hjic-751	193	2	8	8	NUM
hjic-751	193	3	]	]	PUNCT
hjic-751	193	4	horváth	horváth	NOUN
hjic-751	193	5	,	,	PUNCT
hjic-751	193	6	o.	o.	PROPN
hjic-751	193	7	;	;	PUNCT
hjic-751	193	8	valicsek	valicsek	VERB
hjic-751	193	9	,	,	PUNCT
hjic-751	193	10	z.	z.	PROPN
hjic-751	193	11	;	;	PUNCT
hjic-751	193	12	harrach	harrach	PROPN
hjic-751	193	13	,	,	PUNCT
hjic-751	193	14	g.	g.	PROPN
hjic-751	193	15	;	;	PUNCT
hjic-751	193	16	lendvay	lendvay	PROPN
hjic-751	193	17	,	,	PUNCT
hjic-751	193	18	g.	g.	PROPN
hjic-751	193	19	;	;	PUNCT
hjic-751	193	20	fodor	fodor	PROPN
hjic-751	193	21	,	,	PUNCT
hjic-751	193	22	m.a	m.a	PROPN
hjic-751	193	23	.	.	PROPN
hjic-751	193	24	:	:	PUNCT
hjic-751	193	25	spectroscopic	spectroscopic	ADJ
hjic-751	193	26	and	and	CCONJ
hjic-751	193	27	photochemical	photochemical	ADJ
hjic-751	193	28	properties	property	NOUN
hjic-751	193	29	of	of	ADP
hjic-751	193	30	water	water	NOUN
hjic-751	193	31	-	-	PUNCT
hjic-751	193	32	soluble	soluble	ADJ
hjic-751	193	33	metalloporphyrins	metalloporphyrin	NOUN
hjic-751	193	34	of	of	ADP
hjic-751	193	35	distorted	distorted	ADJ
hjic-751	193	36	structure	structure	NOUN
hjic-751	193	37	,	,	PUNCT
hjic-751	193	38	coord	coord	NOUN
hjic-751	193	39	.	.	PUNCT
hjic-751	194	1	chem	chem	PROPN
hjic-751	194	2	.	.	PUNCT
hjic-751	195	1	rev	rev	PROPN
hjic-751	195	2	.	.	PROPN
hjic-751	195	3	,	,	PUNCT
hjic-751	195	4	2012	2012	NUM
hjic-751	195	5	256	256	NUM
hjic-751	195	6	,	,	PUNCT
hjic-751	195	7	1531–1545	1531–1545	NUM
hjic-751	195	8	doi	doi	NOUN
hjic-751	195	9	:	:	PUNCT
hjic-751	195	10	10.1016	10.1016	NUM
hjic-751	195	11	/	/	SYM
hjic-751	195	12	j.ccr.2012.02.011	j.ccr.2012.02.011	NOUN
hjic-751	195	13	[	[	PUNCT
hjic-751	195	14	9	9	NUM
hjic-751	195	15	]	]	PUNCT
hjic-751	195	16	horváth	horváth	NOUN
hjic-751	195	17	,	,	PUNCT
hjic-751	195	18	o.	o.	PROPN
hjic-751	195	19	;	;	PUNCT
hjic-751	195	20	huszánk	huszánk	PROPN
hjic-751	195	21	,	,	PUNCT
hjic-751	195	22	r.	r.	PROPN
hjic-751	195	23	;	;	PUNCT
hjic-751	195	24	valicsek	valicsek	VERB
hjic-751	195	25	,	,	PUNCT
hjic-751	195	26	z.	z.	PROPN
hjic-751	195	27	;	;	PUNCT
hjic-751	196	1	lendvay	lendvay	PROPN
hjic-751	196	2	,	,	PUNCT
hjic-751	196	3	g.	g.	PROPN
hjic-751	196	4	:	:	PUNCT
hjic-751	196	5	photophysics	photophysic	NOUN
hjic-751	196	6	and	and	CCONJ
hjic-751	196	7	photochemistry	photochemistry	NOUN
hjic-751	196	8	of	of	ADP
hjic-751	196	9	kinetically	kinetically	ADV
hjic-751	196	10	labile	labile	ADJ
hjic-751	196	11	,	,	PUNCT
hjic-751	196	12	water	water	NOUN
hjic-751	196	13	-	-	PUNCT
hjic-751	196	14	soluble	soluble	ADJ
hjic-751	196	15	porphyrin	porphyrin	NOUN
hjic-751	196	16	complexes	complex	NOUN
hjic-751	196	17	,	,	PUNCT
hjic-751	196	18	coord	coord	NOUN
hjic-751	196	19	.	.	PUNCT
hjic-751	197	1	chem	chem	PROPN
hjic-751	197	2	.	.	PUNCT
hjic-751	198	1	rev	rev	PROPN
hjic-751	198	2	.	.	PROPN
hjic-751	198	3	,	,	PUNCT
hjic-751	198	4	2006	2006	NUM
hjic-751	198	5	250	250	NUM
hjic-751	198	6	,	,	PUNCT
hjic-751	198	7	1792–1803	1792–1803	NUM
hjic-751	198	8	doi	doi	NOUN
hjic-751	198	9	:	:	PUNCT
hjic-751	199	1	10.1016	10.1016	NUM
hjic-751	199	2	/	/	SYM
hjic-751	199	3	j.ccr.2006.02.014	j.ccr.2006.02.014	PROPN
hjic-751	200	1	[	[	X
hjic-751	200	2	10	10	NUM
hjic-751	200	3	]	]	X
hjic-751	200	4	valicsek	valicsek	PROPN
hjic-751	200	5	,	,	PUNCT
hjic-751	200	6	z.	z.	PROPN
hjic-751	200	7	;	;	PUNCT
hjic-751	200	8	lendvay	lendvay	PROPN
hjic-751	200	9	,	,	PUNCT
hjic-751	200	10	g.	g.	PROPN
hjic-751	200	11	;	;	PUNCT
hjic-751	200	12	horváth	horváth	PROPN
hjic-751	200	13	,	,	PUNCT
hjic-751	200	14	o.	o.	NOUN
hjic-751	200	15	:	:	PUNCT
hjic-751	200	16	equilibrium	equilibrium	NOUN
hjic-751	200	17	,	,	PUNCT
hjic-751	200	18	photophysical	photophysical	ADJ
hjic-751	200	19	,	,	PUNCT
hjic-751	200	20	photochemical	photochemical	ADJ
hjic-751	200	21	and	and	CCONJ
hjic-751	200	22	quantum	quantum	ADJ
hjic-751	200	23	chemical	chemical	NOUN
hjic-751	200	24	examination	examination	NOUN
hjic-751	200	25	of	of	ADP
hjic-751	200	26	anionic	anionic	PROPN
hjic-751	200	27	mercury(ii	mercury(ii	PROPN
hjic-751	200	28	)	)	PUNCT
hjic-751	200	29	monoand	monoand	NOUN
hjic-751	200	30	bisporphyrins	bisporphyrin	NOUN
hjic-751	200	31	,	,	PUNCT
hjic-751	200	32	j.	j.	PROPN
hjic-751	200	33	phys	phys	PROPN
hjic-751	200	34	.	.	PUNCT
hjic-751	201	1	chem	chem	PROPN
hjic-751	201	2	.	.	PUNCT
hjic-751	202	1	b	b	X
hjic-751	202	2	,	,	PUNCT
hjic-751	202	3	2008	2008	NUM
hjic-751	202	4	112(46	112(46	NUM
hjic-751	202	5	)	)	PUNCT
hjic-751	202	6	,	,	PUNCT
hjic-751	202	7	14509–14524	14509–14524	NUM
hjic-751	202	8	doi	doi	NOUN
hjic-751	202	9	:	:	PUNCT
hjic-751	202	10	10.1021	10.1021	NUM
hjic-751	202	11	/	/	SYM
hjic-751	202	12	jp804039s	jp804039s	PROPN
hjic-751	203	1	[	[	X
hjic-751	203	2	11	11	NUM
hjic-751	203	3	]	]	SYM
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hjic-751	203	5	,	,	PUNCT
hjic-751	203	6	m.	m.	NOUN
hjic-751	203	7	;	;	PUNCT
hjic-751	203	8	szentgyörgyi	szentgyörgyi	PROPN
hjic-751	203	9	,	,	PUNCT
hjic-751	203	10	c.	c.	PROPN
hjic-751	203	11	;	;	PUNCT
hjic-751	203	12	eller	eller	PROPN
hjic-751	203	13	,	,	PUNCT
hjic-751	203	14	g.	g.	PROPN
hjic-751	203	15	;	;	PUNCT
hjic-751	203	16	valicsek	valicsek	VERB
hjic-751	203	17	,	,	PUNCT
hjic-751	203	18	z.	z.	PROPN
hjic-751	203	19	;	;	PUNCT
hjic-751	203	20	horváth	horváth	PROPN
hjic-751	203	21	,	,	PUNCT
hjic-751	203	22	o.	o.	PROPN
hjic-751	203	23	:	:	PUNCT
hjic-751	203	24	peculiar	peculiar	ADJ
hjic-751	203	25	photoinduced	photoinduce	VERB
hjic-751	203	26	properties	property	NOUN
hjic-751	203	27	of	of	ADP
hjic-751	203	28	water	water	NOUN
hjic-751	203	29	-	-	PUNCT
hjic-751	203	30	soluble	soluble	ADJ
hjic-751	203	31	,	,	PUNCT
hjic-751	203	32	early	early	ADJ
hjic-751	203	33	lanthanide(iii	lanthanide(iii	NOUN
hjic-751	203	34	)	)	PUNCT
hjic-751	203	35	porphyrins	porphyrin	NOUN
hjic-751	203	36	,	,	PUNCT
hjic-751	203	37	inorg	inorg	PROPN
hjic-751	203	38	.	.	PUNCT
hjic-751	204	1	chem	chem	PROPN
hjic-751	204	2	.	.	PUNCT
hjic-751	205	1	commun	commun	PROPN
hjic-751	205	2	.	.	PROPN
hjic-751	205	3	,	,	PUNCT
hjic-751	205	4	2015	2015	NUM
hjic-751	205	5	52	52	NUM
hjic-751	205	6	,	,	PUNCT
hjic-751	205	7	60–63	60–63	NUM
hjic-751	205	8	doi	doi	NOUN
hjic-751	205	9	:	:	PUNCT
hjic-751	205	10	10.1016	10.1016	NUM
hjic-751	205	11	/	/	SYM
hjic-751	205	12	j.inoche.2014.12.016	j.inoche.2014.12.016	PROPN
hjic-751	206	1	[	[	X
hjic-751	206	2	12	12	NUM
hjic-751	206	3	]	]	X
hjic-751	206	4	kiss	kiss	NOUN
hjic-751	206	5	,	,	PUNCT
hjic-751	206	6	m.p	m.p	PROPN
hjic-751	206	7	.	.	PROPN
hjic-751	206	8	;	;	PUNCT
hjic-751	206	9	imran	imran	PROPN
hjic-751	206	10	,	,	PUNCT
hjic-751	206	11	m.	m.	NOUN
hjic-751	206	12	;	;	PUNCT
hjic-751	206	13	szentgyörgyi	szentgyörgyi	PROPN
hjic-751	206	14	,	,	PUNCT
hjic-751	206	15	c.	c.	PROPN
hjic-751	206	16	;	;	PUNCT
hjic-751	206	17	valicsek	valicsek	VERB
hjic-751	206	18	,	,	PUNCT
hjic-751	206	19	z.	z.	PROPN
hjic-751	206	20	;	;	PUNCT
hjic-751	206	21	horváth	horváth	PROPN
hjic-751	206	22	,	,	PUNCT
hjic-751	206	23	o.	o.	NOUN
hjic-751	206	24	:	:	PUNCT
hjic-751	206	25	peculiarities	peculiarity	NOUN
hjic-751	206	26	of	of	ADP
hjic-751	206	27	the	the	DET
hjic-751	206	28	reactions	reaction	NOUN
hjic-751	206	29	between	between	ADP
hjic-751	206	30	early	early	ADJ
hjic-751	206	31	lanthanide(iii	lanthanide(iii	NOUN
hjic-751	206	32	)	)	PUNCT
hjic-751	206	33	ions	ion	NOUN
hjic-751	206	34	and	and	CCONJ
hjic-751	206	35	an	an	DET
hjic-751	206	36	anionic	anionic	ADJ
hjic-751	206	37	porphyrin	porphyrin	NOUN
hjic-751	206	38	,	,	PUNCT
hjic-751	206	39	inorg	inorg	PROPN
hjic-751	206	40	.	.	PUNCT
hjic-751	207	1	chem	chem	PROPN
hjic-751	207	2	.	.	PUNCT
hjic-751	208	1	commun	commun	PROPN
hjic-751	208	2	.	.	PROPN
hjic-751	208	3	,	,	PUNCT
hjic-751	208	4	2014	2014	NUM
hjic-751	208	5	48	48	NUM
hjic-751	208	6	,	,	PUNCT
hjic-751	208	7	22–25	22–25	NUM
hjic-751	208	8	doi	doi	NOUN
hjic-751	208	9	:	:	PUNCT
hjic-751	208	10	10.1016	10.1016	NUM
hjic-751	208	11	/	/	SYM
hjic-751	209	1	j.inoche.2014.08.001	j.inoche.2014.08.001	NOUN
hjic-751	210	1	[	[	X
hjic-751	210	2	13	13	NUM
hjic-751	210	3	]	]	PUNCT
hjic-751	210	4	valicsek	valicsek	PROPN
hjic-751	210	5	,	,	PUNCT
hjic-751	210	6	z.	z.	PROPN
hjic-751	210	7	;	;	PUNCT
hjic-751	210	8	eller	eller	PROPN
hjic-751	210	9	,	,	PUNCT
hjic-751	210	10	g.	g.	PROPN
hjic-751	210	11	;	;	PUNCT
hjic-751	210	12	horváth	horváth	PROPN
hjic-751	210	13	,	,	PUNCT
hjic-751	210	14	o.	o.	NOUN
hjic-751	210	15	:	:	PUNCT
hjic-751	210	16	equilibrium	equilibrium	NOUN
hjic-751	210	17	,	,	PUNCT
hjic-751	210	18	photophysical	photophysical	ADJ
hjic-751	210	19	and	and	CCONJ
hjic-751	210	20	photochemical	photochemical	ADJ
hjic-751	210	21	examination	examination	NOUN
hjic-751	210	22	of	of	ADP
hjic-751	210	23	anionic	anionic	PROPN
hjic-751	210	24	lanthanum(iii	lanthanum(iii	PROPN
hjic-751	210	25	)	)	PUNCT
hjic-751	210	26	monoand	monoand	NOUN
hjic-751	210	27	bisporphyrins	bisporphyrin	NOUN
hjic-751	210	28	:	:	PUNCT
hjic-751	210	29	the	the	DET
hjic-751	210	30	effects	effect	NOUN
hjic-751	210	31	of	of	ADP
hjic-751	210	32	the	the	DET
hjic-751	210	33	out	out	NOUN
hjic-751	210	34	-	-	PUNCT
hjic-751	210	35	of	of	ADP
hjic-751	210	36	-	-	PUNCT
hjic-751	210	37	plane	plane	NOUN
hjic-751	210	38	structure	structure	NOUN
hjic-751	210	39	,	,	PUNCT
hjic-751	210	40	dalton	dalton	PROPN
hjic-751	210	41	trans	trans	PROPN
hjic-751	210	42	.	.	PROPN
hjic-751	210	43	,	,	PUNCT
hjic-751	210	44	2012	2012	NUM
hjic-751	210	45	41	41	NUM
hjic-751	210	46	,	,	PUNCT
hjic-751	210	47	13120–13131	13120–13131	NUM
hjic-751	210	48	doi	doi	NOUN
hjic-751	210	49	:	:	PUNCT
hjic-751	210	50	10.1039	10.1039	NUM
hjic-751	210	51	/	/	SYM
hjic-751	210	52	c2dt31189e	c2dt31189e	PROPN
hjic-751	211	1	[	[	X
hjic-751	211	2	14	14	NUM
hjic-751	211	3	]	]	X
hjic-751	211	4	valicsek	valicsek	PROPN
hjic-751	211	5	,	,	PUNCT
hjic-751	211	6	z.	z.	PROPN
hjic-751	211	7	;	;	PUNCT
hjic-751	211	8	horváth	horváth	PROPN
hjic-751	211	9	,	,	PUNCT
hjic-751	211	10	o.	o.	PROPN
hjic-751	211	11	;	;	PUNCT
hjic-751	211	12	patonay	patonay	NOUN
hjic-751	211	13	,	,	PUNCT
hjic-751	211	14	k.	k.	NOUN
hjic-751	211	15	:	:	PUNCT
hjic-751	212	1	formation	formation	NOUN
hjic-751	212	2	,	,	PUNCT
hjic-751	212	3	photophysical	photophysical	ADJ
hjic-751	212	4	and	and	CCONJ
hjic-751	212	5	photochemical	photochemical	ADJ
hjic-751	212	6	properties	property	NOUN
hjic-751	212	7	of	of	ADP
hjic-751	212	8	water	water	NOUN
hjic-751	212	9	-	-	PUNCT
hjic-751	212	10	soluble	soluble	ADJ
hjic-751	212	11	bismuth(iii	bismuth(iii	NOUN
hjic-751	212	12	)	)	PUNCT
hjic-751	212	13	porphyrins	porphyrin	VERB
hjic-751	212	14	:	:	PUNCT
hjic-751	212	15	the	the	DET
hjic-751	212	16	role	role	NOUN
hjic-751	212	17	of	of	ADP
hjic-751	212	18	the	the	DET
hjic-751	212	19	charge	charge	NOUN
hjic-751	212	20	and	and	CCONJ
hjic-751	212	21	structure	structure	NOUN
hjic-751	212	22	,	,	PUNCT
hjic-751	212	23	j.	j.	PROPN
hjic-751	212	24	photochem	photochem	PROPN
hjic-751	212	25	.	.	PUNCT
hjic-751	213	1	photobiol	photobiol	PROPN
hjic-751	213	2	.	.	PUNCT
hjic-751	214	1	a	a	DET
hjic-751	214	2	,	,	PUNCT
hjic-751	214	3	2011	2011	NUM
hjic-751	214	4	226	226	NUM
hjic-751	214	5	,	,	PUNCT
hjic-751	214	6	23	23	NUM
hjic-751	214	7	–	–	PUNCT
hjic-751	214	8	35	35	NUM
hjic-751	214	9	doi	doi	NOUN
hjic-751	214	10	:	:	PUNCT
hjic-751	214	11	10.1016	10.1016	NUM
hjic-751	214	12	/	/	SYM
hjic-751	214	13	j.jphotochem.2011.10.011	j.jphotochem.2011.10.011	X
hjic-751	214	14	valicsek	valicsek	VERB
hjic-751	214	15	,	,	PUNCT
hjic-751	214	16	kiss	kiss	PROPN
hjic-751	214	17	,	,	PUNCT
hjic-751	214	18	fodor	fodor	PROPN
hjic-751	214	19	,	,	PUNCT
hjic-751	214	20	imran	imran	ADJ
hjic-751	214	21	,	,	PUNCT
hjic-751	214	22	and	and	CCONJ
hjic-751	214	23	horváth	horváth	PROPN
hjic-751	214	24	hungarian	hungarian	ADJ
hjic-751	214	25	journal	journal	NOUN
hjic-751	214	26	of	of	ADP
hjic-751	214	27	industry	industry	NOUN
hjic-751	214	28	and	and	CCONJ
hjic-751	214	29	chemistry	chemistry	NOUN
hjic-751	214	30	36	36	NUM
hjic-751	214	31	[	[	X
hjic-751	214	32	15	15	NUM
hjic-751	214	33	]	]	X
hjic-751	214	34	harrach	harrach	NOUN
hjic-751	214	35	,	,	PUNCT
hjic-751	214	36	g.	g.	PROPN
hjic-751	214	37	;	;	PUNCT
hjic-751	214	38	valicsek	valicsek	VERB
hjic-751	214	39	,	,	PUNCT
hjic-751	214	40	z.	z.	PROPN
hjic-751	214	41	;	;	PUNCT
hjic-751	214	42	horváth	horváth	PROPN
hjic-751	214	43	,	,	PUNCT
hjic-751	214	44	o.	o.	PROPN
hjic-751	214	45	:	:	PUNCT
hjic-751	214	46	watersoluble	watersoluble	PROPN
hjic-751	214	47	silver(ii	silver(ii	PROPN
hjic-751	214	48	)	)	PUNCT
hjic-751	214	49	and	and	CCONJ
hjic-751	214	50	gold(iii	gold(iii	NOUN
hjic-751	214	51	)	)	PUNCT
hjic-751	214	52	porphyrins	porphyrin	VERB
hjic-751	214	53	:	:	PUNCT
hjic-751	214	54	the	the	DET
hjic-751	214	55	effect	effect	NOUN
hjic-751	214	56	of	of	ADP
hjic-751	214	57	structural	structural	ADJ
hjic-751	214	58	distortion	distortion	NOUN
hjic-751	214	59	on	on	ADP
hjic-751	214	60	the	the	DET
hjic-751	214	61	photophysical	photophysical	ADJ
hjic-751	214	62	and	and	CCONJ
hjic-751	214	63	photochemical	photochemical	ADJ
hjic-751	214	64	behavior	behavior	NOUN
hjic-751	214	65	,	,	PUNCT
hjic-751	214	66	inorg	inorg	PROPN
hjic-751	214	67	.	.	PUNCT
hjic-751	215	1	chem	chem	PROPN
hjic-751	215	2	.	.	PUNCT
hjic-751	216	1	commun	commun	PROPN
hjic-751	216	2	.	.	PUNCT
hjic-751	217	1	2011	2011	NUM
hjic-751	217	2	14	14	NUM
hjic-751	217	3	,	,	PUNCT
hjic-751	217	4	1756–1761	1756–1761	NUM
hjic-751	217	5	doi	doi	NOUN
hjic-751	217	6	:	:	PUNCT
hjic-751	217	7	10.1016	10.1016	NUM
hjic-751	217	8	/	/	SYM
hjic-751	217	9	j.inoche.2011.08.003	j.inoche.2011.08.003	NOUN
hjic-751	218	1	[	[	X
hjic-751	218	2	16	16	NUM
hjic-751	218	3	]	]	X
hjic-751	218	4	valicsek	valicsek	PROPN
hjic-751	218	5	,	,	PUNCT
hjic-751	218	6	z.	z.	PROPN
hjic-751	218	7	;	;	PUNCT
hjic-751	218	8	horváth	horváth	PROPN
hjic-751	218	9	,	,	PUNCT
hjic-751	218	10	o.	o.	NOUN
hjic-751	218	11	:	:	PUNCT
hjic-751	218	12	formation	formation	NOUN
hjic-751	218	13	,	,	PUNCT
hjic-751	218	14	photophysics	photophysic	NOUN
hjic-751	218	15	and	and	CCONJ
hjic-751	218	16	photochemistry	photochemistry	NOUN
hjic-751	218	17	of	of	ADP
hjic-751	218	18	thallium(iii	thallium(iii	NOUN
hjic-751	218	19	)	)	PUNCT
hjic-751	218	20	5,10,15,20tetrakis(4	5,10,15,20tetrakis(4	NOUN
hjic-751	218	21	-	-	PUNCT
hjic-751	218	22	sulphonatophenyl)porphyrin	sulphonatophenyl)porphyrin	NOUN
hjic-751	218	23	:	:	PUNCT
hjic-751	218	24	new	new	ADJ
hjic-751	218	25	supports	support	NOUN
hjic-751	218	26	of	of	ADP
hjic-751	218	27	typical	typical	ADJ
hjic-751	218	28	sitting	sitting	NOUN
hjic-751	218	29	-	-	PUNCT
hjic-751	218	30	atop	atop	NOUN
hjic-751	218	31	features	feature	NOUN
hjic-751	218	32	,	,	PUNCT
hjic-751	218	33	j.	j.	PROPN
hjic-751	218	34	photochem	photochem	PROPN
hjic-751	218	35	.	.	PUNCT
hjic-751	219	1	photobiol	photobiol	PROPN
hjic-751	219	2	.	.	PUNCT
hjic-751	220	1	a	a	PRON
hjic-751	220	2	,	,	PUNCT
hjic-751	220	3	2007	2007	NUM
hjic-751	220	4	186	186	NUM
hjic-751	220	5	,	,	PUNCT
hjic-751	220	6	1–7	1–7	NUM
hjic-751	220	7	doi	doi	NOUN
hjic-751	220	8	:	:	PUNCT
hjic-751	220	9	10.1016	10.1016	NUM
hjic-751	220	10	/	/	SYM
hjic-751	220	11	j.jphotochem.2006.07.003	j.jphotochem.2006.07.003	PROPN