id	sid	tid	token	lemma	pos
iajs-1179	1	1	2009	2009	NUM
iajs-1179	1	2	)	)	PUNCT
iajs-1179	1	3	3	3	NUM
iajs-1179	1	4	(	(	PUNCT
iajs-1179	1	5	22مجلة	22مجلة	NUM
iajs-1179	1	6	ابن	ابن	PROPN
iajs-1179	1	7	الھیثم	الھیثم	PROPN
iajs-1179	1	8	للعلوم	للعلوم	PROPN
iajs-1179	1	9	الصرفة	الصرفة	PROPN
iajs-1179	1	10	والتطبیقیة	والتطبیقیة	PROPN
iajs-1179	1	11	المجلد	المجلد	VERB
iajs-1179	1	12	اي	اي	PROPN
iajs-1179	1	13	یردین	یردین	PROPN
iajs-1179	1	14	ب	ب	SYM
iajs-1179	1	15	2	2	NUM
iajs-1179	1	16	-	-	SYM
iajs-1179	1	17	2ترز	2ترز	NUM
iajs-1179	1	18	)	)	PUNCT
iajs-1179	1	19	ii(یوم	ii(یوم	PROPN
iajs-1179	1	20	ونبین	ونبین	PROPN
iajs-1179	1	21	الروث	الروث	PROPN
iajs-1179	1	22	"	"	PUNCT
iajs-1179	1	23	یانالنتقال	یانالنتقال	NOUN
iajs-1179	1	24	االلكتروني	االلكتروني	PROPN
iajs-1179	1	25	المستحث	المستحث	PROPN
iajs-1179	1	26	فوتو	فوتو	PROPN
iajs-1179	1	27	ا	ا	PROPN
iajs-1179	1	28	ومثیل	ومثیل	PROPN
iajs-1179	1	29	الفایلوجین	الفایلوجین	ADJ
iajs-1179	1	30	هادي	هادي	NOUN
iajs-1179	1	31	جبار	جبار	ADJ
iajs-1179	1	32	مجبل	مجبل	NOUN
iajs-1179	1	33	العكیلي	العكیلي	ADJ
iajs-1179	1	34	ابن	ابن	PROPN
iajs-1179	1	35	الهیثم	الهیثم	PROPN
iajs-1179	1	36	،	،	PROPN
iajs-1179	1	37	جامعة	جامعة	PROPN
iajs-1179	1	38	بغداد	بغداد	PROPN
iajs-1179	1	39	قسم	قسم	PROPN
iajs-1179	1	40	الفیزیاء	الفیزیاء	PROPN
iajs-1179	1	41	،	،	PROPN
iajs-1179	2	1	كلیة	كلیة	PROPN
iajs-1179	2	2	التربیة	التربیة	NOUN
iajs-1179	2	3	الخالصة	الخالصة	PROPN
iajs-1179	2	4	الجزیئـات	الجزیئـات	PROPN
iajs-1179	2	5	،	،	PROPN
iajs-1179	2	6	تتـراوح	تتـراوح	PROPN
iajs-1179	2	7	ث	ث	PROPN
iajs-1179	2	8	في	في	ADP
iajs-1179	2	9	أي	أي	INTJ
iajs-1179	2	10	تشكیلة	تشكیلة	PROPN
iajs-1179	2	11	كبیرة	كبیرة	NOUN
iajs-1179	2	12	من	من	DET
iajs-1179	2	13	دیمثل	دیمثل	ADJ
iajs-1179	2	14	التفاعل	التفاعل	NOUN
iajs-1179	2	15	االبتدائي	االبتدائي	PROPN
iajs-1179	2	16	للعملیات	للعملیات	PROPN
iajs-1179	2	17	الكیمیائیة	الكیمیائیة	PROPN
iajs-1179	2	18	التي	التي	PROPN
iajs-1179	2	19	تح	تح	PROPN
iajs-1179	2	20	االنتقال	االنتقال	PROPN
iajs-1179	2	21	االلكتروني	االلكتروني	PROPN
iajs-1179	2	22	.الى	.الى	PROPN
iajs-1179	2	23	النظام	النظام	PROPN
iajs-1179	2	24	الحیوي	الحیوي	VERB
iajs-1179	3	1	الكبیر	الكبیر	PROPN
iajs-1179	3	2	"	"	PUNCT
iajs-1179	3	3	یة	یة	ADP
iajs-1179	3	4	الصغیرة	الصغیرة	PROPN
iajs-1179	3	5	وصوالاالزواج	وصوالاالزواج	PROPN
iajs-1179	3	6	االیون	االیون	PROPN
iajs-1179	3	7	ـا	ـا	PROPN
iajs-1179	3	8	اللكترو	اللكترو	ADJ
iajs-1179	3	9	نتقـــال	نتقـــال	NOUN
iajs-1179	3	10	االدراســـة	االدراســـة	NOUN
iajs-1179	3	11	النظریــــة	النظریــــة	NOUN
iajs-1179	3	12	لال	لال	PROPN
iajs-1179	4	1	ـــي	ـــي	PROPN
iajs-1179	4	2	المســـتحث	المســـتحث	PROPN
iajs-1179	4	3	فوتوئبـــ	فوتوئبـــ	PROPN
iajs-1179	4	4	2یــــوم	2یــــوم	DET
iajs-1179	4	5	بـــین	بـــین	PROPN
iajs-1179	4	6	الروتون	الروتون	PROPN
iajs-1179	4	7	"	"	PUNCT
iajs-1179	4	8	نـ	نـ	PRON
iajs-1179	4	9	3)(bpyruــالوجی	3)(bpyruــالوجی	NOUN
iajs-1179	4	10	+	+	NOUN
iajs-1179	4	11	mv2	mv2	NOUN
iajs-1179	4	12	نو	نو	PROPN
iajs-1179	4	13	مثیـــل	مثیـــل	PROPN
iajs-1179	4	14	الفــ	الفــ	PROPN
iajs-1179	4	15	.	.	PUNCT
iajs-1179	5	1	حققت	حققت	PROPN
iajs-1179	6	1	هنا	هنا	PROPN
iajs-1179	6	2	معینة	معینة	PROPN
iajs-1179	6	3	لمذیبات	لمذیبات	PROPN
iajs-1179	6	4	مختلفة	مختلفة	ADJ
iajs-1179	6	5	وعند	وعند	PROPN
iajs-1179	6	6	درجة	درجة	ADJ
iajs-1179	6	7	الحرارة	الحرارة	NOUN
iajs-1179	6	8	نمــوذج	نمــوذج	PROPN
iajs-1179	6	9	أ	أ	ADP
iajs-1179	6	10	الضــوء	الضــوء	PROPN
iajs-1179	6	11	المــذیب	المــذیب	ADJ
iajs-1179	6	12	وصـف	وصـف	PROPN
iajs-1179	6	13	مــن	مــن	PROPN
iajs-1179	6	14	خــاللهـذه	خــاللهـذه	VERB
iajs-1179	6	15	الدراســة	الدراســة	PROPN
iajs-1179	6	16	معتمــدة	معتمــدة	NOUN
iajs-1179	6	17	علــى	علــى	PROPN
iajs-1179	6	18	اسـاس	اسـاس	PROPN
iajs-1179	6	19	التنشــیط	التنشــیط	NOUN
iajs-1179	6	20	البصــري	البصــري	PROPN
iajs-1179	6	21	مــن	مــن	PROPN
iajs-1179	6	22	خـالل	خـالل	PROPN
iajs-1179	6	23	امتصــاص	امتصــاص	PROPN
iajs-1179	6	24	.	.	PUNCT
iajs-1179	7	1	دالة	دالة	NOUN
iajs-1179	7	2	الموجة	الموجة	ADP
iajs-1179	7	3	لمن	لمن	ADV
iajs-1179	7	4	خال	خال	PROPN
iajs-1179	7	5	"	"	PUNCT
iajs-1179	7	6	االستمراریة	االستمراریة	PROPN
iajs-1179	7	7	للعوازل	للعوازل	PROPN
iajs-1179	7	8	،	،	PROPN
iajs-1179	7	9	واالنتقال	واالنتقال	PROPN
iajs-1179	7	10	كمیا	كمیا	NOUN
iajs-1179	7	11	ــادة	ــادة	PROPN
iajs-1179	7	12	االلتحــ	االلتحــ	VERB
iajs-1179	7	13	فــي	فــي	ADJ
iajs-1179	7	14	ــیط	ــیط	NOUN
iajs-1179	7	15	،	،	NOUN
iajs-1179	7	16	g،والطاقـــة	g،والطاقـــة	NOUN
iajs-1179	7	17	الحــرة	الحــرة	NOUN
iajs-1179	7	18	ام	ام	NOUN
iajs-1179	7	19	هـــذا	هـــذا	NOUN
iajs-1179	7	20	التطبیــق	التطبیــق	PROPN
iajs-1179	7	21	،	،	PROPN
iajs-1179	7	22	طاقـــة	طاقـــة	PROPN
iajs-1179	7	23	اعـ	اعـ	PROPN
iajs-1179	7	24	ــة	ــة	PROPN
iajs-1179	7	25	التنشـ	التنشـ	PROPN
iajs-1179	7	26	وطاقـ	وطاقـ	PROPN
iajs-1179	7	27	‡	‡	X
iajs-1179	8	1	g	g	PROPN
iajs-1179	8	2	ة	ة	PRON
iajs-1179	8	3	شـــبه	شـــبه	NOUN
iajs-1179	8	4	حســبت	حســبت	PROPN
iajs-1179	8	5	بطریقـــ	بطریقـــ	PROPN
iajs-1179	8	6	هـش	هـش	PROPN
iajs-1179	8	7	ومعـدل	ومعـدل	NOUN
iajs-1179	8	8	–	–	PUNCT
iajs-1179	8	9	اخـذت	اخـذت	ADJ
iajs-1179	8	10	مـن	مـن	PROPN
iajs-1179	8	11	طریقـة	طریقـة	NOUN
iajs-1179	8	12	ملیكـان	ملیكـان	PROPN
iajs-1179	8	13	التـي	التـي	PROPN
iajs-1179	8	14	vda	vda	PROPN
iajs-1179	8	15	االلكترونـيلالنتقـال	االلكترونـيلالنتقـال	ADV
iajs-1179	8	16	ة	ة	PRON
iajs-1179	8	17	عناصـر	عناصـر	PROPN
iajs-1179	8	18	مصـفوفة	مصـفوفة	PROPN
iajs-1179	8	19	االزدواج	االزدواج	ADJ
iajs-1179	8	20	االلكترونـي	االلكترونـي	X
iajs-1179	8	21	یكالسـیك	یكالسـیك	NOUN
iajs-1179	8	22	لنظام	لنظام	ADJ
iajs-1179	8	23	ket	ket	PROPN
iajs-1179	8	24	االنتقال	االنتقال	NOUN
iajs-1179	8	25	االلكتروني	االلكتروني	NOUN
iajs-1179	8	26	22	22	NUM
iajs-1179	8	27	3	3	NUM
iajs-1179	8	28	)	)	PUNCT
iajs-1179	8	29	(	(	PUNCT
iajs-1179	8	30	mvbpyru	mvbpyru	NOUN
iajs-1179	8	31	نموذج	نموذج	NOUN
iajs-1179	8	32	كمي	كمي	X
iajs-1179	8	33	أ	أ	X
iajs-1179	8	34	وفق	وفق	INTJ
iajs-1179	8	35	على	على	NOUN
iajs-1179	8	36	حسبتوالتي	حسبتوالتي	NOUN
iajs-1179	8	37	.	.	PUNCT
iajs-1179	9	1	نتقال	نتقال	VERB
iajs-1179	9	2	االلكتروني	االلكتروني	PROPN
iajs-1179	9	3	لنظام	لنظام	PROPN
iajs-1179	9	4	نتائج	نتائج	PROPN
iajs-1179	9	5	حساباتنا	حساباتنا	PROPN
iajs-1179	9	6	لال	لال	PROPN
iajs-1179	9	7	22	22	NUM
iajs-1179	9	8	3	3	NUM
iajs-1179	9	9	)	)	PUNCT
iajs-1179	9	10	(	(	PUNCT
iajs-1179	9	11	mvbpyru	mvbpyru	NOUN
iajs-1179	9	12	مع	مع	PROPN
iajs-1179	9	13	النتائج	النتائج	PROPN
iajs-1179	9	14	التجریبیة	التجریبیة	PROPN
iajs-1179	9	15	المالحظة	المالحظة	PROPN
iajs-1179	9	16	"	"	PUNCT
iajs-1179	9	17	اظهرت	اظهرت	PROPN
iajs-1179	9	18	تطابقا	تطابقا	PROPN
iajs-1179	9	19	.	.	PUNCT
iajs-1179	10	1	ibn	ibn	PROPN
iajs-1179	10	2	alhaitham	alhaitham	NOUN
iajs-1179	11	1	j.	j.	PROPN
iajs-1179	12	1	fo	fo	ADP
iajs-1179	12	2	r	r	NOUN
iajs-1179	12	3	pure	pure	ADJ
iajs-1179	12	4	&	&	CCONJ
iajs-1179	12	5	appl	appl	PROPN
iajs-1179	12	6	.	.	PUNCT
iajs-1179	13	1	sc	sc	PROPN
iajs-1179	14	1	i	i	PRON
iajs-1179	14	2	vo	vo	INTJ
iajs-1179	14	3	l.22	l.22	X
iajs-1179	14	4	(	(	PUNCT
iajs-1179	14	5	3	3	NUM
iajs-1179	14	6	)	)	PUNCT
iajs-1179	14	7	2009	2009	NUM
iajs-1179	14	8	photo	photo	NOUN
iajs-1179	14	9	-induced	-induce	VERB
iajs-1179	14	10	electron	electron	NOUN
iajs-1179	14	11	transfer	transfer	NOUN
iajs-1179	14	12	between	between	ADP
iajs-1179	14	13	ruthenium	ruthenium	NOUN
iajs-1179	14	14	(	(	PUNCT
iajs-1179	14	15	ii	ii	NOUN
iajs-1179	14	16	)	)	PUNCT
iajs-1179	14	17	tris	tris	NOUN
iajs-1179	14	18	–	–	PUNCT
iajs-1179	14	19	(	(	PUNCT
iajs-1179	14	20	2,2	2,2	NUM
iajs-1179	14	21			ADJ
iajs-1179	14	22	bipyrdine	bipyrdine	NOUN
iajs-1179	14	23	)	)	PUNCT
iajs-1179	14	24	and	and	CCONJ
iajs-1179	14	25	methyl	methyl	NOUN
iajs-1179	14	26	viologen	viologen	NOUN
iajs-1179	14	27	h.j.m.al	h.j.m.al	PROPN
iajs-1179	14	28	-	-	PUNCT
iajs-1179	14	29	agealy	agealy	PROPN
iajs-1179	14	30	department	department	PROPN
iajs-1179	14	31	of	of	ADP
iajs-1179	14	32	physics	physics	PROPN
iajs-1179	14	33	,	,	PUNCT
iajs-1179	14	34	college	college	NOUN
iajs-1179	14	35	of	of	ADP
iajs-1179	14	36	education	education	NOUN
iajs-1179	14	37	ibnal	ibnal	ADJ
iajs-1179	14	38	-	-	PUNCT
iajs-1179	14	39	haitham	haitham	PROPN
iajs-1179	14	40	,	,	PUNCT
iajs-1179	14	41	university	university	PROPN
iajs-1179	14	42	of	of	ADP
iajs-1179	14	43	baghdad	baghdad	PROPN
iajs-1179	14	44	abstract	abstract	ADJ
iajs-1179	14	45	electron	electron	NOUN
iajs-1179	14	46	transfer	transfer	NOUN
iajs-1179	14	47	(	(	PUNCT
iajs-1179	14	48	et	et	NOUN
iajs-1179	14	49	)	)	PUNCT
iajs-1179	14	50	reactions	reaction	NOUN
iajs-1179	14	51	represent	represent	VERB
iajs-1179	14	52	an	an	DET
iajs-1179	14	53	elementary	elementary	ADJ
iajs-1179	14	54	chemical	chemical	NOUN
iajs-1179	14	55	process	process	NOUN
iajs-1179	14	56	which	which	PRON
iajs-1179	14	57	occurs	occur	VERB
iajs-1179	14	58	in	in	ADP
iajs-1179	14	59	a	a	DET
iajs-1179	14	60	large	large	ADJ
iajs-1179	14	61	variety	variety	NOUN
iajs-1179	14	62	of	of	ADP
iajs-1179	14	63	molecules	molecule	NOUN
iajs-1179	14	64	,	,	PUNCT
iajs-1179	14	65	ranging	range	VERB
iajs-1179	14	66	from	from	ADP
iajs-1179	14	67	small	small	ADJ
iajs-1179	14	68	ion	ion	NOUN
iajs-1179	14	69	pairs	pair	NOUN
iajs-1179	14	70	up	up	ADP
iajs-1179	14	71	to	to	ADP
iajs-1179	14	72	large	large	ADJ
iajs-1179	14	73	biological	biological	ADJ
iajs-1179	14	74	system	system	NOUN
iajs-1179	14	75	.	.	PUNCT
iajs-1179	15	1	a	a	DET
iajs-1179	15	2	theoretical	theoretical	ADJ
iajs-1179	15	3	study	study	NOUN
iajs-1179	15	4	of	of	ADP
iajs-1179	15	5	photo	photo	NOUN
iajs-1179	15	6	–	–	PUNCT
iajs-1179	15	7	induced	induce	VERB
iajs-1179	15	8	electron	electron	NOUN
iajs-1179	15	9	transfer	transfer	NOUN
iajs-1179	15	10	between	between	ADP
iajs-1179	15	11	ruthenium	ruthenium	NOUN
iajs-1179	15	12	(	(	PUNCT
iajs-1179	15	13	ii	ii	NOUN
iajs-1179	15	14	)	)	PUNCT
iajs-1179	15	15	tirs	tir	NOUN
iajs-1179	15	16	-	-	PUNCT
iajs-1179	15	17	(	(	PUNCT
iajs-1179	15	18	2,2	2,2	NUM
iajs-1179	15	19			ADJ
iajs-1179	15	20	bipyrdine	bipyrdine	NOUN
iajs-1179	15	21	)	)	PUNCT
iajs-1179	15	22	ru(bpy	ru(bpy	VERB
iajs-1179	15	23	)	)	PUNCT
iajs-1179	16	1	2	2	PROPN
iajs-1179	16	2	3	3	NUM
iajs-1179	16	3	and	and	CCONJ
iajs-1179	16	4	methyl	methyl	NOUN
iajs-1179	16	5	viologen	viologen	NOUN
iajs-1179	16	6	mv2	mv2	PROPN
iajs-1179	17	1	+	+	X
iajs-1179	17	2	in	in	ADP
iajs-1179	17	3	a	a	DET
iajs-1179	17	4	variety	variety	NOUN
iajs-1179	17	5	of	of	ADP
iajs-1179	17	6	solvents	solvent	NOUN
iajs-1179	17	7	at	at	ADP
iajs-1179	17	8	room	room	NOUN
iajs-1179	17	9	temperature	temperature	NOUN
iajs-1179	17	10	is	be	AUX
iajs-1179	17	11	presented	present	VERB
iajs-1179	17	12	.	.	PUNCT
iajs-1179	18	1	this	this	DET
iajs-1179	18	2	study	study	NOUN
iajs-1179	18	3	is	be	AUX
iajs-1179	18	4	based	base	VERB
iajs-1179	18	5	on	on	ADP
iajs-1179	18	6	an	an	DET
iajs-1179	18	7	optical	optical	ADJ
iajs-1179	18	8	activation	activation	NOUN
iajs-1179	18	9	by	by	ADP
iajs-1179	18	10	the	the	DET
iajs-1179	18	11	absorption	absorption	NOUN
iajs-1179	18	12	of	of	ADP
iajs-1179	18	13	light	light	NOUN
iajs-1179	18	14	.the	.the	PRON
iajs-1179	18	15	solvent	solvent	NOUN
iajs-1179	18	16	is	be	AUX
iajs-1179	18	17	described	describe	VERB
iajs-1179	18	18	by	by	ADP
iajs-1179	18	19	a	a	DET
iajs-1179	18	20	dielectric	dielectric	ADJ
iajs-1179	18	21	continuum	continuum	ADJ
iajs-1179	18	22	model	model	NOUN
iajs-1179	18	23	,	,	PUNCT
iajs-1179	18	24	and	and	CCONJ
iajs-1179	18	25	the	the	DET
iajs-1179	18	26	transferring	transferring	NOUN
iajs-1179	18	27	is	be	AUX
iajs-1179	18	28	represented	represent	VERB
iajs-1179	18	29	by	by	ADP
iajs-1179	18	30	a	a	DET
iajs-1179	18	31	quantum	quantum	ADJ
iajs-1179	18	32	mechanical	mechanical	ADJ
iajs-1179	18	33	wave	wave	NOUN
iajs-1179	18	34	function	function	NOUN
iajs-1179	18	35	.	.	PUNCT
iajs-1179	19	1	in	in	ADP
iajs-1179	19	2	this	this	DET
iajs-1179	19	3	application	application	NOUN
iajs-1179	19	4	,	,	PUNCT
iajs-1179	19	5	the	the	DET
iajs-1179	19	6	reorganization	reorganization	NOUN
iajs-1179	19	7	energy	energy	NOUN
iajs-1179	19	8			NOUN
iajs-1179	19	9	,	,	PUNCT
iajs-1179	19	10	the	the	DET
iajs-1179	19	11	driving	drive	VERB
iajs-1179	19	12	free	free	ADJ
iajs-1179	19	13	energy	energy	NOUN
iajs-1179	19	14	g	g	NOUN
iajs-1179	19	15	,	,	PUNCT
iajs-1179	19	16	and	and	CCONJ
iajs-1179	19	17	the	the	DET
iajs-1179	19	18	activation	activation	NOUN
iajs-1179	19	19	free	free	ADJ
iajs-1179	19	20	energy	energy	NOUN
iajs-1179	19	21	g	g	PROPN
iajs-1179	19	22	‡	‡	NOUN
iajs-1179	19	23	are	be	AUX
iajs-1179	19	24	calculated	calculate	VERB
iajs-1179	19	25	with	with	ADP
iajs-1179	19	26	semi	semi	ADJ
iajs-1179	19	27	classical	classical	ADJ
iajs-1179	19	28	model	model	NOUN
iajs-1179	19	29	.	.	PUNCT
iajs-1179	20	1	the	the	DET
iajs-1179	20	2	electronic	electronic	ADJ
iajs-1179	20	3	coupling	coupling	NOUN
iajs-1179	20	4	for	for	ADP
iajs-1179	20	5	the	the	DET
iajs-1179	20	6	electron	electron	NOUN
iajs-1179	20	7	transfer	transfer	NOUN
iajs-1179	20	8	dav	dav	NOUN
iajs-1179	20	9	reaction	reaction	NOUN
iajs-1179	20	10	is	be	AUX
iajs-1179	20	11	taken	take	VERB
iajs-1179	20	12	from	from	ADP
iajs-1179	20	13	mulliken	mulliken	ADJ
iajs-1179	20	14	–	–	PUNCT
iajs-1179	20	15	hush	hush	ADJ
iajs-1179	20	16	method	method	NOUN
iajs-1179	20	17	,	,	PUNCT
iajs-1179	20	18	and	and	CCONJ
iajs-1179	20	19	the	the	DET
iajs-1179	20	20	rate	rate	NOUN
iajs-1179	20	21	of	of	ADP
iajs-1179	20	22	electron	electron	NOUN
iajs-1179	20	23	transfer	transfer	NOUN
iajs-1179	20	24	ket	ket	NOUN
iajs-1179	20	25	in	in	ADP
iajs-1179	20	26			PROPN
iajs-1179	20	27	22	22	NUM
iajs-1179	20	28	3	3	NUM
iajs-1179	20	29	)	)	PUNCT
iajs-1179	20	30	(	(	PUNCT
iajs-1179	20	31	mvbpyru	mvbpyru	NOUN
iajs-1179	20	32	system	system	NOUN
iajs-1179	20	33	are	be	AUX
iajs-1179	20	34	calculated	calculate	VERB
iajs-1179	20	35	with	with	ADP
iajs-1179	20	36	a	a	DET
iajs-1179	20	37	quantum	quantum	ADJ
iajs-1179	20	38	mechanical	mechanical	ADJ
iajs-1179	20	39	model	model	NOUN
iajs-1179	20	40	.	.	PUNCT
iajs-1179	21	1	our	our	PRON
iajs-1179	21	2	calculation	calculation	NOUN
iajs-1179	21	3	results	result	VERB
iajs-1179	21	4	for	for	ADP
iajs-1179	21	5	the	the	DET
iajs-1179	21	6	electron	electron	NOUN
iajs-1179	21	7	transfer	transfer	NOUN
iajs-1179	21	8	in	in	ADP
iajs-1179	21	9			PROPN
iajs-1179	21	10	22	22	NUM
iajs-1179	21	11	3	3	NUM
iajs-1179	21	12	)	)	PUNCT
iajs-1179	21	13	(	(	PUNCT
iajs-1179	21	14	mvbpyru	mvbpyru	NOUN
iajs-1179	21	15	system	system	NOUN
iajs-1179	21	16	show	show	VERB
iajs-1179	21	17	a	a	DET
iajs-1179	21	18	good	good	ADJ
iajs-1179	21	19	agreement	agreement	NOUN
iajs-1179	21	20	with	with	ADP
iajs-1179	21	21	the	the	DET
iajs-1179	21	22	experimentally	experimentally	ADV
iajs-1179	21	23	observed	observe	VERB
iajs-1179	21	24	results	result	NOUN
iajs-1179	21	25	.	.	PUNCT
iajs-1179	22	1	introduction	introduction	NOUN
iajs-1179	22	2	electctron	electctron	NOUN
iajs-1179	22	3	transfer	transfer	NOUN
iajs-1179	22	4	(	(	PUNCT
iajs-1179	22	5	et	et	NOUN
iajs-1179	22	6	)	)	PUNCT
iajs-1179	22	7	on	on	ADP
iajs-1179	22	8	a	a	DET
iajs-1179	22	9	molecular	molecular	ADJ
iajs-1179	22	10	level	level	NOUN
iajs-1179	22	11	is	be	AUX
iajs-1179	22	12	a	a	DET
iajs-1179	22	13	very	very	ADV
iajs-1179	22	14	important	important	ADJ
iajs-1179	22	15	class	class	NOUN
iajs-1179	22	16	of	of	ADP
iajs-1179	22	17	chemical	chemical	ADJ
iajs-1179	22	18	reactions	reaction	NOUN
iajs-1179	22	19	ranging	range	VERB
iajs-1179	22	20	from	from	ADP
iajs-1179	22	21	simple	simple	ADJ
iajs-1179	22	22	bimolecular	bimolecular	ADJ
iajs-1179	22	23	reduction	reduction	NOUN
iajs-1179	22	24	oxidation	oxidation	NOUN
iajs-1179	22	25	reactions	reaction	NOUN
iajs-1179	22	26	to	to	ADP
iajs-1179	22	27	complex	complex	ADJ
iajs-1179	22	28	electron	electron	NOUN
iajs-1179	22	29	transport	transport	NOUN
iajs-1179	22	30	chains	chain	NOUN
iajs-1179	22	31	in	in	ADP
iajs-1179	22	32	protein	protein	NOUN
iajs-1179	22	33	(	(	PUNCT
iajs-1179	22	34	1	1	NUM
iajs-1179	22	35	)	)	PUNCT
iajs-1179	22	36	.	.	PUNCT
iajs-1179	23	1	the	the	DET
iajs-1179	23	2	(	(	PUNCT
iajs-1179	23	3	et	et	NOUN
iajs-1179	23	4	)	)	PUNCT
iajs-1179	23	5	process	process	NOUN
iajs-1179	23	6	is	be	AUX
iajs-1179	23	7	like	like	ADP
iajs-1179	23	8	any	any	DET
iajs-1179	23	9	other	other	ADJ
iajs-1179	23	10	chemical	chemical	NOUN
iajs-1179	23	11	reaction	reaction	NOUN
iajs-1179	23	12	,	,	PUNCT
iajs-1179	23	13	a	a	DET
iajs-1179	23	14	transition	transition	NOUN
iajs-1179	23	15	from	from	ADP
iajs-1179	23	16	a	a	DET
iajs-1179	23	17	metastable	metastable	ADJ
iajs-1179	23	18	initial	initial	NOUN
iajs-1179	23	19	to	to	ADP
iajs-1179	23	20	a	a	DET
iajs-1179	23	21	stable	stable	ADJ
iajs-1179	23	22	final	final	ADJ
iajs-1179	23	23	state	state	NOUN
iajs-1179	23	24	(	(	PUNCT
iajs-1179	23	25	2	2	NUM
iajs-1179	23	26	)	)	PUNCT
iajs-1179	23	27	.	.	PUNCT
iajs-1179	24	1	et	et	PROPN
iajs-1179	24	2	can	can	AUX
iajs-1179	24	3	be	be	AUX
iajs-1179	24	4	optically	optically	ADV
iajs-1179	24	5	or	or	CCONJ
iajs-1179	24	6	/	/	SYM
iajs-1179	24	7	and	and	CCONJ
iajs-1179	24	8	thermally	thermally	ADV
iajs-1179	24	9	activated	activate	VERB
iajs-1179	24	10	and	and	CCONJ
iajs-1179	24	11	triggers	trigger	VERB
iajs-1179	24	12	photosyn	photosyn	NOUN
iajs-1179	24	13	thesis	thesis	NOUN
iajs-1179	24	14	,	,	PUNCT
iajs-1179	24	15	metabolism	metabolism	NOUN
iajs-1179	24	16	,	,	PUNCT
iajs-1179	24	17	polymerization	polymerization	NOUN
iajs-1179	24	18	reactions	reaction	NOUN
iajs-1179	24	19	,	,	PUNCT
iajs-1179	24	20	electrochemical	electrochemical	ADJ
iajs-1179	24	21	reactions(3	reactions(3	NOUN
iajs-1179	24	22	)	)	PUNCT
iajs-1179	24	23	.	.	PUNCT
iajs-1179	25	1	a	a	DET
iajs-1179	25	2	molecular	molecular	ADJ
iajs-1179	25	3	(	(	PUNCT
iajs-1179	25	4	et	et	NOUN
iajs-1179	25	5	)	)	PUNCT
iajs-1179	25	6	reaction	reaction	NOUN
iajs-1179	25	7	involves	involve	VERB
iajs-1179	25	8	an	an	DET
iajs-1179	25	9	oxidation	oxidation	NOUN
iajs-1179	25	10	of	of	ADP
iajs-1179	25	11	a	a	DET
iajs-1179	25	12	donor	donor	NOUN
iajs-1179	25	13	(	(	PUNCT
iajs-1179	25	14	d	d	NOUN
iajs-1179	25	15	)	)	PUNCT
iajs-1179	25	16	molecule	molecule	NOUN
iajs-1179	25	17	and	and	CCONJ
iajs-1179	25	18	reduction	reduction	NOUN
iajs-1179	25	19	of	of	ADP
iajs-1179	25	20	an	an	DET
iajs-1179	25	21	acceptor	acceptor	NOUN
iajs-1179	25	22	molecule	molecule	NOUN
iajs-1179	25	23	(	(	PUNCT
iajs-1179	25	24	a	a	NOUN
iajs-1179	25	25	)	)	PUNCT
iajs-1179	25	26	.	.	PUNCT
iajs-1179	26	1	if	if	SCONJ
iajs-1179	26	2	the	the	DET
iajs-1179	26	3	donor	donor	NOUN
iajs-1179	26	4	and	and	CCONJ
iajs-1179	26	5	acceptor	acceptor	NOUN
iajs-1179	26	6	are	be	AUX
iajs-1179	26	7	freely	freely	ADV
iajs-1179	26	8	diffusing	diffuse	VERB
iajs-1179	26	9	in	in	ADP
iajs-1179	26	10	a	a	DET
iajs-1179	26	11	solvent	solvent	NOUN
iajs-1179	26	12	,	,	PUNCT
iajs-1179	26	13	then	then	ADV
iajs-1179	26	14	prior	prior	ADV
iajs-1179	26	15	to	to	ADP
iajs-1179	26	16	et	et	PRON
iajs-1179	26	17	a	a	DET
iajs-1179	26	18	bimolecular	bimolecular	ADJ
iajs-1179	26	19	diffusion	diffusion	NOUN
iajs-1179	26	20	creats	creat	VERB
iajs-1179	26	21	an	an	DET
iajs-1179	26	22	encounter	encounter	NOUN
iajs-1179	26	23	complex	complex	NOUN
iajs-1179	26	24	.	.	PUNCT
iajs-1179	27	1	in	in	ADP
iajs-1179	27	2	the	the	DET
iajs-1179	27	3	encounter	encounter	NOUN
iajs-1179	27	4	complex	complex	NOUN
iajs-1179	27	5	,	,	PUNCT
iajs-1179	27	6	electron	electron	NOUN
iajs-1179	27	7	transfer	transfer	NOUN
iajs-1179	27	8	reaction	reaction	NOUN
iajs-1179	27	9	occurs	occur	VERB
iajs-1179	27	10	at	at	ADP
iajs-1179	27	11	a	a	DET
iajs-1179	27	12	certain	certain	ADJ
iajs-1179	27	13	distance	distance	NOUN
iajs-1179	27	14	and	and	CCONJ
iajs-1179	27	15	arrangement	arrangement	NOUN
iajs-1179	27	16	.	.	PUNCT
iajs-1179	28	1	the	the	DET
iajs-1179	28	2	encounter	encounter	ADJ
iajs-1179	28	3	complex	complex	NOUN
iajs-1179	28	4	can	can	AUX
iajs-1179	28	5	either	either	CCONJ
iajs-1179	28	6	be	be	AUX
iajs-1179	28	7	in	in	ADP
iajs-1179	28	8	close	close	ADJ
iajs-1179	28	9	contact	contact	NOUN
iajs-1179	28	10	,	,	PUNCT
iajs-1179	28	11	or	or	CCONJ
iajs-1179	28	12	in	in	ADP
iajs-1179	28	13	a	a	DET
iajs-1179	28	14	solvent	solvent	NOUN
iajs-1179	28	15	separated	separate	VERB
iajs-1179	28	16	configuration	configuration	NOUN
iajs-1179	28	17	,	,	PUNCT
iajs-1179	28	18	and	and	CCONJ
iajs-1179	28	19	et	et	NOUN
iajs-1179	28	20	may	may	AUX
iajs-1179	28	21	occur	occur	VERB
iajs-1179	28	22	at	at	ADP
iajs-1179	28	23	a	a	DET
iajs-1179	28	24	distribution	distribution	NOUN
iajs-1179	28	25	of	of	ADP
iajs-1179	28	26	different	different	ADJ
iajs-1179	28	27	donoracceptor	donoracceptor	NOUN
iajs-1179	28	28	configureations	configureation	NOUN
iajs-1179	28	29	.	.	PUNCT
iajs-1179	29	1	if	if	SCONJ
iajs-1179	29	2	the	the	DET
iajs-1179	29	3	donor	donor	NOUN
iajs-1179	29	4	and	and	CCONJ
iajs-1179	29	5	acceptor	acceptor	NOUN
iajs-1179	29	6	are	be	AUX
iajs-1179	29	7	attached	attach	VERB
iajs-1179	29	8	to	to	ADP
iajs-1179	29	9	each	each	DET
iajs-1179	29	10	other	other	ADJ
iajs-1179	29	11	,	,	PUNCT
iajs-1179	29	12	no	no	DET
iajs-1179	29	13	diffusion	diffusion	NOUN
iajs-1179	29	14	processes	process	NOUN
iajs-1179	29	15	are	be	AUX
iajs-1179	29	16	needed	need	VERB
iajs-1179	29	17	prior	prior	ADV
iajs-1179	29	18	to	to	ADP
iajs-1179	29	19	et	et	PRON
iajs-1179	29	20	,	,	PUNCT
iajs-1179	29	21	and	and	CCONJ
iajs-1179	29	22	unimolecular	unimolecular	ADJ
iajs-1179	29	23	et	et	PROPN
iajs-1179	29	24	reaction	reaction	NOUN
iajs-1179	29	25	kinetic	kinetic	NOUN
iajs-1179	29	26	is	be	AUX
iajs-1179	29	27	observed	observe	VERB
iajs-1179	29	28	.	.	PUNCT
iajs-1179	30	1	the	the	DET
iajs-1179	30	2	theory	theory	NOUN
iajs-1179	30	3	describing	describe	VERB
iajs-1179	30	4	et	et	NOUN
iajs-1179	30	5	processes	process	NOUN
iajs-1179	30	6	was	be	AUX
iajs-1179	30	7	developed	develop	VERB
iajs-1179	30	8	from	from	ADP
iajs-1179	30	9	the	the	DET
iajs-1179	30	10	transition	transition	NOUN
iajs-1179	30	11	state	state	NOUN
iajs-1179	30	12	theory	theory	NOUN
iajs-1179	30	13	by	by	ADP
iajs-1179	30	14	marcus	marcus	PROPN
iajs-1179	30	15	.	.	PUNCT
iajs-1179	31	1	for	for	ADP
iajs-1179	31	2	this	this	DET
iajs-1179	31	3	development	development	NOUN
iajs-1179	31	4	marcus	marcus	PROPN
iajs-1179	31	5	was	be	AUX
iajs-1179	31	6	awarded	award	VERB
iajs-1179	31	7	the	the	DET
iajs-1179	31	8	1992	1992	NUM
iajs-1179	31	9	nobel	nobel	PROPN
iajs-1179	31	10	prize	prize	PROPN
iajs-1179	31	11	in	in	ADP
iajs-1179	31	12	chemistry	chemistry	NOUN
iajs-1179	31	13	(	(	PUNCT
iajs-1179	31	14	4,5,6	4,5,6	NUM
iajs-1179	31	15	)	)	PUNCT
iajs-1179	31	16	.	.	PUNCT
iajs-1179	32	1	the	the	DET
iajs-1179	32	2	rate	rate	NOUN
iajs-1179	32	3	of	of	ADP
iajs-1179	32	4	photo	photo	NOUN
iajs-1179	32	5	induced	induce	VERB
iajs-1179	32	6	et	et	NOUN
iajs-1179	32	7	are	be	AUX
iajs-1179	32	8	evaluated	evaluate	VERB
iajs-1179	32	9	depending	depend	VERB
iajs-1179	32	10	on	on	ADP
iajs-1179	32	11	the	the	DET
iajs-1179	32	12	quantum	quantum	ADJ
iajs-1179	32	13	mechanical	mechanical	ADJ
iajs-1179	32	14	theory	theory	NOUN
iajs-1179	32	15	and	and	CCONJ
iajs-1179	32	16	non	non	ADJ
iajs-1179	32	17	adiabatic	adiabatic	ADJ
iajs-1179	32	18	limit	limit	NOUN
iajs-1179	32	19	rda	rda	NOUN
iajs-1179	32	20	=	=	SYM
iajs-1179	32	21	10ao	10ao	NOUN
iajs-1179	32	22	.	.	PUNCT
iajs-1179	33	1	the	the	DET
iajs-1179	33	2	value	value	NOUN
iajs-1179	33	3	of	of	ADP
iajs-1179	33	4	et	et	NOUN
iajs-1179	33	5	rate	rate	NOUN
iajs-1179	33	6	constants	constant	NOUN
iajs-1179	33	7	k	k	PROPN
iajs-1179	33	8	are	be	AUX
iajs-1179	33	9	controlled	control	VERB
iajs-1179	33	10	by	by	ADP
iajs-1179	33	11	:	:	PUNCT
iajs-1179	33	12	ibn	ibn	PROPN
iajs-1179	33	13	alhaitham	alhaitham	NOUN
iajs-1179	34	1	j.	j.	PROPN
iajs-1179	35	1	fo	fo	ADP
iajs-1179	35	2	r	r	NOUN
iajs-1179	35	3	pure	pure	ADJ
iajs-1179	35	4	&	&	CCONJ
iajs-1179	35	5	appl	appl	PROPN
iajs-1179	35	6	.	.	PUNCT
iajs-1179	36	1	sc	sc	PROPN
iajs-1179	37	1	i	i	PRON
iajs-1179	37	2	vo	vo	INTJ
iajs-1179	37	3	l.22	l.22	X
iajs-1179	37	4	(	(	PUNCT
iajs-1179	37	5	3	3	NUM
iajs-1179	37	6	)	)	PUNCT
iajs-1179	37	7	2009	2009	NUM
iajs-1179	37	8	reorganization	reorganization	NOUN
iajs-1179	37	9	energy	energy	NOUN
iajs-1179	37	10			NOUN
iajs-1179	37	11	,	,	PUNCT
iajs-1179	37	12	driving	drive	VERB
iajs-1179	37	13	free	free	ADJ
iajs-1179	37	14	energy	energy	NOUN
iajs-1179	37	15	g	g	NOUN
iajs-1179	37	16	;	;	PUNCT
iajs-1179	37	17	activation	activation	NOUN
iajs-1179	37	18	free	free	ADJ
iajs-1179	37	19	energy	energy	NOUN
iajs-1179	37	20	g	g	PROPN
iajs-1179	37	21	‡	‡	X
iajs-1179	37	22	,	,	PUNCT
iajs-1179	37	23	and	and	CCONJ
iajs-1179	37	24	electronic	electronic	ADJ
iajs-1179	37	25	coupling	coupling	NOUN
iajs-1179	37	26	matrix	matrix	NOUN
iajs-1179	37	27	element	element	NOUN
iajs-1179	37	28	vda	vda	NOUN
iajs-1179	37	29	.	.	PUNCT
iajs-1179	38	1	in	in	ADP
iajs-1179	38	2	this	this	DET
iajs-1179	38	3	research	research	NOUN
iajs-1179	38	4	we	we	PRON
iajs-1179	38	5	will	will	AUX
iajs-1179	38	6	study	study	VERB
iajs-1179	38	7	the	the	DET
iajs-1179	38	8	photo	photo	NOUN
iajs-1179	38	9	induced	induce	VERB
iajs-1179	38	10	et	et	NOUN
iajs-1179	38	11	from	from	ADP
iajs-1179	38	12	2	2	PROPN
iajs-1179	38	13	3)(bpyru	3)(bpyru	PROPN
iajs-1179	38	14	acting	act	VERB
iajs-1179	38	15	as	as	ADP
iajs-1179	38	16	an	an	DET
iajs-1179	38	17	electron	electron	NOUN
iajs-1179	38	18	donor	donor	NOUN
iajs-1179	38	19	to	to	ADP
iajs-1179	38	20	nn	nn	X
iajs-1179	38	21			PROPN
iajs-1179	38	22	dimethyl44	dimethyl44	NOUN
iajs-1179	38	23			PROPN
iajs-1179	38	24	bipyridine	bipyridine	NOUN
iajs-1179	38	25	(	(	PUNCT
iajs-1179	38	26	methyl	methyl	NOUN
iajs-1179	38	27	viologen	viologen	NOUN
iajs-1179	38	28	)	)	PUNCT
iajs-1179	38	29	acting	act	VERB
iajs-1179	38	30	as	as	ADP
iajs-1179	38	31	an	an	DET
iajs-1179	38	32	electron	electron	NOUN
iajs-1179	38	33	acceptor	acceptor	NOUN
iajs-1179	38	34	.	.	PUNCT
iajs-1179	39	1	the	the	DET
iajs-1179	39	2	structures	structure	NOUN
iajs-1179	39	3	of	of	ADP
iajs-1179	39	4	the	the	DET
iajs-1179	39	5	2	2	PROPN
iajs-1179	39	6	3)(bpyru	3)(bpyru	PROPN
iajs-1179	39	7	and	and	CCONJ
iajs-1179	39	8	mv2	mv2	PROPN
iajs-1179	39	9	+	+	NOUN
iajs-1179	39	10	that	that	PRON
iajs-1179	39	11	are	be	AUX
iajs-1179	39	12	used	use	VERB
iajs-1179	39	13	in	in	ADP
iajs-1179	39	14	this	this	DET
iajs-1179	39	15	work	work	NOUN
iajs-1179	39	16	are	be	AUX
iajs-1179	39	17	shown	show	VERB
iajs-1179	39	18	in	in	ADP
iajs-1179	39	19	figure	figure	NOUN
iajs-1179	39	20	(	(	PUNCT
iajs-1179	39	21	1	1	NUM
iajs-1179	39	22	)	)	PUNCT
iajs-1179	39	23	the	the	DET
iajs-1179	39	24	system	system	NOUN
iajs-1179	39	25	ruthenium	ruthenium	NOUN
iajs-1179	39	26	(	(	PUNCT
iajs-1179	39	27	ii	ii	NOUN
iajs-1179	39	28	)	)	PUNCT
iajs-1179	39	29	–	–	PUNCT
iajs-1179	39	30	trisbipyridine	trisbipyridine	VERB
iajs-1179	39	31	2	2	PROPN
iajs-1179	39	32	3)(bpyru	3)(bpyru	PROPN
iajs-1179	39	33	was	be	AUX
iajs-1179	39	34	used	use	VERB
iajs-1179	39	35	in	in	ADP
iajs-1179	39	36	numerous	numerous	ADJ
iajs-1179	39	37	investigations	investigation	NOUN
iajs-1179	39	38	as	as	ADP
iajs-1179	39	39	a	a	DET
iajs-1179	39	40	photosensitizer	photosensitizer	NOUN
iajs-1179	39	41	during	during	ADP
iajs-1179	39	42	the	the	DET
iajs-1179	39	43	last	last	ADJ
iajs-1179	39	44	30	30	NUM
iajs-1179	39	45	years	year	NOUN
iajs-1179	39	46	due	due	ADP
iajs-1179	39	47	to	to	ADP
iajs-1179	39	48	the	the	DET
iajs-1179	39	49	very	very	ADV
iajs-1179	39	50	favorable	favorable	ADJ
iajs-1179	39	51	photochemical	photochemical	ADJ
iajs-1179	39	52	properties	property	NOUN
iajs-1179	39	53	(	(	PUNCT
iajs-1179	39	54	7	7	NUM
iajs-1179	39	55	)	)	PUNCT
iajs-1179	39	56	.	.	PUNCT
iajs-1179	40	1	the	the	DET
iajs-1179	40	2	absorbance	absorbance	NOUN
iajs-1179	40	3	in	in	ADP
iajs-1179	40	4	both	both	CCONJ
iajs-1179	40	5	the	the	DET
iajs-1179	40	6	visible	visible	ADJ
iajs-1179	40	7	and	and	CCONJ
iajs-1179	40	8	uv	uv	NOUN
iajs-1179	40	9	regions	region	NOUN
iajs-1179	40	10	is	be	AUX
iajs-1179	40	11	high	high	ADJ
iajs-1179	40	12	(	(	PUNCT
iajs-1179	40	13	1,11	1,11	NOUN
iajs-1179	40	14	)	)	PUNCT
iajs-1179	40	15	.	.	PUNCT
iajs-1179	41	1	in	in	ADP
iajs-1179	41	2	the	the	DET
iajs-1179	41	3	excited	excited	ADJ
iajs-1179	41	4	state	state	NOUN
iajs-1179	41	5	,	,	PUNCT
iajs-1179	41	6	2	2	PROPN
iajs-1179	41	7	3)(bpyru	3)(bpyru	PROPN
iajs-1179	41	8	is	be	AUX
iajs-1179	41	9	both	both	CCONJ
iajs-1179	41	10	a	a	DET
iajs-1179	41	11	good	good	ADJ
iajs-1179	41	12	reductant	reductant	NOUN
iajs-1179	41	13	and	and	CCONJ
iajs-1179	41	14	oxidant	oxidant	NOUN
iajs-1179	41	15	,	,	PUNCT
iajs-1179	41	16	and	and	CCONJ
iajs-1179	41	17	the	the	DET
iajs-1179	41	18	life	life	NOUN
iajs-1179	41	19	time	time	NOUN
iajs-1179	41	20	is	be	AUX
iajs-1179	41	21	long	long	ADJ
iajs-1179	41	22	enough	enough	ADV
iajs-1179	41	23	to	to	PART
iajs-1179	41	24	be	be	AUX
iajs-1179	41	25	used	use	VERB
iajs-1179	41	26	in	in	ADP
iajs-1179	41	27	bimolecular	bimolecular	ADJ
iajs-1179	41	28	electron	electron	NOUN
iajs-1179	41	29	or	or	CCONJ
iajs-1179	41	30	energy	energy	NOUN
iajs-1179	41	31	transfer	transfer	NOUN
iajs-1179	41	32	reactions	reaction	NOUN
iajs-1179	41	33	.	.	PUNCT
iajs-1179	42	1	in	in	ADP
iajs-1179	42	2	addition	addition	NOUN
iajs-1179	42	3	both	both	CCONJ
iajs-1179	42	4	the	the	DET
iajs-1179	42	5	reduced	reduce	VERB
iajs-1179	42	6	and	and	CCONJ
iajs-1179	42	7	oxidized	oxidize	VERB
iajs-1179	42	8	forms	form	NOUN
iajs-1179	42	9	are	be	AUX
iajs-1179	42	10	relatively	relatively	ADV
iajs-1179	42	11	stable	stable	ADJ
iajs-1179	42	12	towards	towards	ADP
iajs-1179	42	13	degrading	degrading	ADJ
iajs-1179	42	14	reactions	reaction	NOUN
iajs-1179	42	15	(	(	PUNCT
iajs-1179	42	16	7,8	7,8	NUM
iajs-1179	42	17	)	)	PUNCT
iajs-1179	42	18	.	.	PUNCT
iajs-1179	43	1	one	one	NUM
iajs-1179	43	2	way	way	NOUN
iajs-1179	43	3	of	of	ADP
iajs-1179	43	4	inducing	induce	VERB
iajs-1179	43	5	et	et	NOUN
iajs-1179	43	6	is	be	AUX
iajs-1179	43	7	to	to	PART
iajs-1179	43	8	expose	expose	VERB
iajs-1179	43	9	aphotosensitizer	aphotosensitizer	NOUN
iajs-1179	43	10	2	2	PROPN
iajs-1179	43	11	3)(bpyru	3)(bpyru	PROPN
iajs-1179	43	12	to	to	ADP
iajs-1179	43	13	light	light	NOUN
iajs-1179	43	14	of	of	ADP
iajs-1179	43	15	a	a	DET
iajs-1179	43	16	wave	wave	NOUN
iajs-1179	43	17	length	length	NOUN
iajs-1179	43	18	that	that	PRON
iajs-1179	43	19	is	be	AUX
iajs-1179	43	20	absorbed	absorb	VERB
iajs-1179	43	21	by	by	ADP
iajs-1179	43	22	2	2	PROPN
iajs-1179	43	23	3)(bpyru	3)(bpyru	PROPN
iajs-1179	43	24	,	,	PUNCT
iajs-1179	43	25	thus	thus	ADV
iajs-1179	43	26	transferring	transfer	VERB
iajs-1179	43	27	it	it	PRON
iajs-1179	43	28	to	to	ADP
iajs-1179	43	29	an	an	DET
iajs-1179	43	30	excited	excited	ADJ
iajs-1179	43	31	state	state	NOUN
iajs-1179	43	32			ADJ
iajs-1179	43	33	2	2	NUM
iajs-1179	43	34	3)(bpyru	3)(bpyru	NUM
iajs-1179	43	35	eq.[1	eq.[1	NUM
iajs-1179	43	36	]	]	PUNCT
iajs-1179	43	37	(	(	PUNCT
iajs-1179	43	38	9	9	NUM
iajs-1179	43	39	)	)	PUNCT
iajs-1179	43	40	]	]	PUNCT
iajs-1179	44	1	1	1	X
iajs-1179	44	2	.	.	PUNCT
iajs-1179	45	1	[	[	X
iajs-1179	45	2	....................	....................	PUNCT
iajs-1179	45	3	)	)	PUNCT
iajs-1179	45	4	(	(	PUNCT
iajs-1179	45	5	*	*	NOUN
iajs-1179	45	6	)	)	PUNCT
iajs-1179	45	7	(	(	PUNCT
iajs-1179	45	8	2	2	NUM
iajs-1179	45	9	3	3	NUM
iajs-1179	45	10	2	2	NUM
iajs-1179	45	11	3	3	NUM
iajs-1179	45	12			ADJ
iajs-1179	45	13			NOUN
iajs-1179	45	14	bpyruhbpyru	bpyruhbpyru	NOUN
iajs-1179	45	15			PROPN
iajs-1179	45	16	here	here	ADV
iajs-1179	45	17	,	,	PUNCT
iajs-1179	45	18	the	the	DET
iajs-1179	45	19	frequency	frequency	NOUN
iajs-1179	45	20	of	of	ADP
iajs-1179	45	21	the	the	DET
iajs-1179	45	22	spectral	spectral	ADJ
iajs-1179	45	23	absorption	absorption	NOUN
iajs-1179	45	24	maximum	maximum	PROPN
iajs-1179	45	25	max	max	PROPN
iajs-1179	45	26	is	be	AUX
iajs-1179	45	27	given	give	VERB
iajs-1179	45	28	by	by	ADP
iajs-1179	45	29	:	:	PUNCT
iajs-1179	45	30	]	]	X
iajs-1179	45	31	2	2	X
iajs-1179	45	32	.......	.......	PUNCT
iajs-1179	45	33	[	[	X
iajs-1179	45	34	........................................	........................................	X
iajs-1179	45	35	max	max	PROPN
iajs-1179	45	36			PROPN
iajs-1179	45	37	gh	gh	PROPN
iajs-1179	45	38			VERB
iajs-1179	45	39	where	where	SCONJ
iajs-1179	45	40	h	h	NOUN
iajs-1179	45	41	,	,	PUNCT
iajs-1179	45	42	is	be	AUX
iajs-1179	45	43	planck	planck	NOUN
iajs-1179	45	44	constant	constant	ADJ
iajs-1179	45	45	,	,	PUNCT
iajs-1179	45	46	max	max	PROPN
iajs-1179	45	47	is	be	AUX
iajs-1179	45	48	frequency	frequency	NOUN
iajs-1179	45	49	of	of	ADP
iajs-1179	45	50	light	light	NOUN
iajs-1179	45	51	,	,	PUNCT
iajs-1179	45	52			ADJ
iajs-1179	45	53	reorganization	reorganization	NOUN
iajs-1179	45	54	energy	energy	NOUN
iajs-1179	45	55	and	and	CCONJ
iajs-1179	45	56	g	g	NOUN
iajs-1179	45	57	is	be	AUX
iajs-1179	45	58	free	free	ADJ
iajs-1179	45	59	energy	energy	NOUN
iajs-1179	45	60	.	.	PUNCT
iajs-1179	46	1	if	if	SCONJ
iajs-1179	46	2	a	a	DET
iajs-1179	46	3	quencher	quencher	NOUN
iajs-1179	46	4	(	(	PUNCT
iajs-1179	46	5	mv2	mv2	PROPN
iajs-1179	46	6	+	+	NOUN
iajs-1179	46	7	)	)	PUNCT
iajs-1179	46	8	is	be	AUX
iajs-1179	46	9	added	add	VERB
iajs-1179	46	10	to	to	ADP
iajs-1179	46	11	the	the	DET
iajs-1179	46	12	system	system	NOUN
iajs-1179	46	13	,	,	PUNCT
iajs-1179	46	14	this	this	DET
iajs-1179	46	15	molecule	molecule	NOUN
iajs-1179	46	16	is	be	AUX
iajs-1179	46	17	able	able	ADJ
iajs-1179	46	18	to	to	PART
iajs-1179	46	19	quench	quench	VERB
iajs-1179	46	20	the	the	DET
iajs-1179	46	21	excited	excited	ADJ
iajs-1179	46	22	state	state	NOUN
iajs-1179	46	23	of	of	ADP
iajs-1179	46	24	2	2	PROPN
iajs-1179	46	25	3	3	NUM
iajs-1179	46	26	)	)	PUNCT
iajs-1179	46	27	(	(	PUNCT
iajs-1179	46	28	*	*	PUNCT
iajs-1179	46	29	bpyru	bpyru	PROPN
iajs-1179	46	30	.i.e	.i.e	X
iajs-1179	46	31	.	.	PUNCT
iajs-1179	47	1	it	it	PRON
iajs-1179	47	2	is	be	AUX
iajs-1179	47	3	able	able	ADJ
iajs-1179	47	4	to	to	PART
iajs-1179	47	5	remove	remove	VERB
iajs-1179	47	6	the	the	DET
iajs-1179	47	7	excitation	excitation	NOUN
iajs-1179	47	8	energy	energy	NOUN
iajs-1179	47	9	(	(	PUNCT
iajs-1179	47	10	10	10	NUM
iajs-1179	47	11	)	)	PUNCT
iajs-1179	47	12	.	.	PUNCT
iajs-1179	48	1	the	the	DET
iajs-1179	48	2	quenching	quenching	NOUN
iajs-1179	48	3	mechanism	mechanism	NOUN
iajs-1179	48	4	can	can	AUX
iajs-1179	48	5	be	be	AUX
iajs-1179	48	6	et	et	NOUN
iajs-1179	48	7	from	from	ADP
iajs-1179	48	8	the	the	DET
iajs-1179	48	9	system	system	NOUN
iajs-1179	48	10	2	2	X
iajs-1179	48	11	3	3	NUM
iajs-1179	48	12	)	)	PUNCT
iajs-1179	48	13	(	(	PUNCT
iajs-1179	48	14	*	*	PUNCT
iajs-1179	48	15	bpyru	bpyru	NOUN
iajs-1179	48	16	to	to	PART
iajs-1179	48	17	mthyle	mthyle	PROPN
iajs-1179	48	18	viologen	viologen	PROPN
iajs-1179	48	19	mv	mv	PROPN
iajs-1179	48	20	2	2	NUM
iajs-1179	48	21	+	+	CCONJ
iajs-1179	48	22	,	,	PUNCT
iajs-1179	48	23	fig.(2	fig.(2	NUM
iajs-1179	48	24	)	)	PUNCT
iajs-1179	48	25	gives	give	VERB
iajs-1179	48	26	a	a	DET
iajs-1179	48	27	reduced	reduced	ADJ
iajs-1179	48	28	methyle	methyle	NOUN
iajs-1179	48	29	viologen	viologen	PROPN
iajs-1179	48	30	radicl	radicl	PROPN
iajs-1179	48	31	and	and	CCONJ
iajs-1179	48	32	oxidized	oxidize	VERB
iajs-1179	48	33	ruthenium	ruthenium	NOUN
iajs-1179	48	34	3	3	NUM
iajs-1179	48	35	3)(bpyru	3)(bpyru	NUM
iajs-1179	48	36	equation	equation	NOUN
iajs-1179	48	37	[	[	X
iajs-1179	48	38	3	3	X
iajs-1179	48	39	]	]	PUNCT
iajs-1179	48	40	(	(	PUNCT
iajs-1179	48	41	9,10	9,10	NUM
iajs-1179	48	42	)	)	PUNCT
iajs-1179	48	43	.	.	PUNCT
iajs-1179	49	1	]	]	X
iajs-1179	49	2	3	3	NUM
iajs-1179	49	3	[	[	NOUN
iajs-1179	49	4	..............................	..............................	PUNCT
iajs-1179	49	5	)	)	PUNCT
iajs-1179	49	6	(	(	PUNCT
iajs-1179	49	7	)	)	PUNCT
iajs-1179	49	8	(	(	PUNCT
iajs-1179	49	9	*	*	NOUN
iajs-1179	49	10	23	23	NUM
iajs-1179	49	11	3	3	NUM
iajs-1179	49	12	2	2	NUM
iajs-1179	49	13	3	3	NUM
iajs-1179	49	14	2	2	NUM
iajs-1179	49	15			PROPN
iajs-1179	49	16			NOUN
iajs-1179	49	17			ADV
iajs-1179	49	18			PROPN
iajs-1179	49	19			ADJ
iajs-1179	49	20	mvbpyrumvbpyru	mvbpyrumvbpyru	NOUN
iajs-1179	49	21	et	et	PROPN
iajs-1179	49	22	theory	theory	NOUN
iajs-1179	49	23	of	of	ADP
iajs-1179	49	24	electron	electron	NOUN
iajs-1179	49	25	transfer	transfer	NOUN
iajs-1179	49	26	in	in	ADP
iajs-1179	49	27	quantum	quantum	ADJ
iajs-1179	49	28	mechanical	mechanical	ADJ
iajs-1179	49	29	models	model	NOUN
iajs-1179	49	30	the	the	DET
iajs-1179	49	31	golden	golden	ADJ
iajs-1179	49	32	rule	rule	NOUN
iajs-1179	49	33	expression	expression	NOUN
iajs-1179	49	34	for	for	ADP
iajs-1179	49	35	the	the	DET
iajs-1179	49	36	transition	transition	NOUN
iajs-1179	49	37	probability	probability	NOUN
iajs-1179	49	38	between	between	ADP
iajs-1179	49	39	different	different	ADJ
iajs-1179	49	40	electronic	electronic	ADJ
iajs-1179	49	41	states	state	NOUN
iajs-1179	49	42	(	(	PUNCT
iajs-1179	49	43	donoracceptor	donoracceptor	NOUN
iajs-1179	49	44	)	)	PUNCT
iajs-1179	49	45	,	,	PUNCT
iajs-1179	49	46	is	be	AUX
iajs-1179	49	47	often	often	ADV
iajs-1179	49	48	used	use	VERB
iajs-1179	49	49	to	to	PART
iajs-1179	49	50	treat	treat	VERB
iajs-1179	49	51	nonadiabatic	nonadiabatic	ADJ
iajs-1179	49	52	electron	electron	NOUN
iajs-1179	49	53	transfer	transfer	NOUN
iajs-1179	49	54	.	.	PUNCT
iajs-1179	50	1	in	in	ADP
iajs-1179	50	2	the	the	DET
iajs-1179	50	3	high	high	ADJ
iajs-1179	50	4	temperature	temperature	NOUN
iajs-1179	50	5	limit	limit	NOUN
iajs-1179	50	6	,	,	PUNCT
iajs-1179	50	7	when	when	SCONJ
iajs-1179	50	8	the	the	DET
iajs-1179	50	9	energy	energy	NOUN
iajs-1179	50	10	of	of	ADP
iajs-1179	50	11	each	each	DET
iajs-1179	50	12	vibration	vibration	NOUN
iajs-1179	50	13	is	be	AUX
iajs-1179	50	14	considerably	considerably	ADV
iajs-1179	50	15	less	less	ADJ
iajs-1179	50	16	than	than	ADP
iajs-1179	50	17	the	the	DET
iajs-1179	50	18	thermal	thermal	ADJ
iajs-1179	50	19	energy	energy	NOUN
iajs-1179	50	20	,	,	PUNCT
iajs-1179	50	21	tkh	tkh	ADJ
iajs-1179	50	22	b	b	PROPN
iajs-1179	50	23	(	(	PUNCT
iajs-1179	50	24	12,13	12,13	NUM
iajs-1179	50	25	)	)	PUNCT
iajs-1179	50	26	,	,	PUNCT
iajs-1179	50	27	the	the	DET
iajs-1179	50	28	et	et	NOUN
iajs-1179	50	29	rate	rate	NOUN
iajs-1179	50	30	constant	constant	ADJ
iajs-1179	50	31	ket	ket	NOUN
iajs-1179	50	32	between	between	ADP
iajs-1179	50	33	the	the	DET
iajs-1179	50	34	reactants	reactant	NOUN
iajs-1179	50	35	at	at	ADP
iajs-1179	50	36	a	a	DET
iajs-1179	50	37	fixed	fix	VERB
iajs-1179	50	38	distance	distance	NOUN
iajs-1179	50	39	is	be	AUX
iajs-1179	50	40	determined	determine	VERB
iajs-1179	50	41	by	by	ADP
iajs-1179	50	42	three	three	NUM
iajs-1179	50	43	parameters	parameter	NOUN
iajs-1179	50	44	:	:	PUNCT
iajs-1179	50	45	the	the	DET
iajs-1179	50	46	electronic	electronic	ADJ
iajs-1179	50	47	couplong	couplong	NOUN
iajs-1179	50	48	matrix	matrix	NOUN
iajs-1179	50	49	element	element	NOUN
iajs-1179	50	50	vda	vda	NOUN
iajs-1179	50	51	,	,	PUNCT
iajs-1179	50	52	the	the	DET
iajs-1179	50	53	free	free	ADJ
iajs-1179	50	54	energy	energy	NOUN
iajs-1179	50	55	change	change	NOUN
iajs-1179	50	56	of	of	ADP
iajs-1179	50	57	the	the	DET
iajs-1179	50	58	reaction	reaction	NOUN
iajs-1179	50	59	g	g	NOUN
iajs-1179	50	60	,	,	PUNCT
iajs-1179	50	61	and	and	CCONJ
iajs-1179	50	62	the	the	DET
iajs-1179	50	63	reorganization	reorganization	NOUN
iajs-1179	50	64	energy	energy	NOUN
iajs-1179	50	65			NOUN
iajs-1179	50	66	,	,	PUNCT
iajs-1179	50	67	which	which	DET
iajs-1179	50	68	ibn	ibn	PROPN
iajs-1179	50	69	alhaitham	alhaitham	NOUN
iajs-1179	50	70	j.	j.	PROPN
iajs-1179	51	1	fo	fo	ADP
iajs-1179	51	2	r	r	NOUN
iajs-1179	51	3	pure	pure	ADJ
iajs-1179	51	4	&	&	CCONJ
iajs-1179	51	5	appl	appl	PROPN
iajs-1179	51	6	.	.	PUNCT
iajs-1179	52	1	sc	sc	PROPN
iajs-1179	53	1	i	i	PRON
iajs-1179	53	2	vo	vo	INTJ
iajs-1179	53	3	l.22	l.22	X
iajs-1179	53	4	(	(	PUNCT
iajs-1179	53	5	3	3	NUM
iajs-1179	53	6	)	)	PUNCT
iajs-1179	53	7	2009	2009	NUM
iajs-1179	53	8	includes	include	VERB
iajs-1179	53	9	both	both	DET
iajs-1179	53	10	intra	intra	ADJ
iajs-1179	53	11	molecular	molecular	ADJ
iajs-1179	53	12			ADJ
iajs-1179	53	13	in	in	ADV
iajs-1179	53	14	;	;	PUNCT
iajs-1179	53	15	and	and	CCONJ
iajs-1179	53	16	solvent	solvent	PROPN
iajs-1179	53	17	s	s	PROPN
iajs-1179	53	18	out	out	ADP
iajs-1179	53	19	coordinates	coordinate	NOUN
iajs-1179	53	20	,	,	PUNCT
iajs-1179	53	21	the	the	DET
iajs-1179	53	22	expression	expression	NOUN
iajs-1179	53	23	for	for	ADP
iajs-1179	53	24	ket	ket	NOUN
iajs-1179	53	25	(	(	PUNCT
iajs-1179	53	26	14	14	NUM
iajs-1179	53	27	)	)	PUNCT
iajs-1179	53	28	.	.	PUNCT
iajs-1179	54	1	1	1	NUM
iajs-1179	54	2	4	4	NUM
iajs-1179	54	3	2	2	NUM
iajs-1179	54	4	tkk	tkk	NOUN
iajs-1179	54	5	bet	bet	NOUN
iajs-1179	54	6			NUM
iajs-1179	54	7			PROPN
iajs-1179	54	8			NUM
iajs-1179	54	9			PROPN
iajs-1179	54	10	]	]	NOUN
iajs-1179	54	11	4.[	4.[	NUM
iajs-1179	54	12	..........	..........	PUNCT
iajs-1179	54	13	)	)	PUNCT
iajs-1179	54	14	.........	.........	PUNCT
iajs-1179	55	1	exp(2	exp(2	PROPN
iajs-1179	55	2	tk	tk	PROPN
iajs-1179	56	1	g	g	PROPN
iajs-1179	56	2	v	v	PROPN
iajs-1179	56	3	b	b	PROPN
iajs-1179	56	4	da	da	PROPN
iajs-1179	56	5			PROPN
iajs-1179	56	6			NOUN
iajs-1179	56	7	where	where	SCONJ
iajs-1179	56	8			NUM
iajs-1179	56	9	is	be	AUX
iajs-1179	56	10	planck	planck	NOUN
iajs-1179	56	11	,	,	PUNCT
iajs-1179	56	12	s	s	VERB
iajs-1179	56	13	constant	constant	ADJ
iajs-1179	56	14	divided	divide	VERB
iajs-1179	56	15	by	by	ADP
iajs-1179	56	16	bk,2	bk,2	NOUN
iajs-1179	56	17	which	which	PRON
iajs-1179	56	18	is	be	AUX
iajs-1179	56	19	the	the	DET
iajs-1179	56	20	boltzman	boltzman	NOUN
iajs-1179	56	21	constant	constant	ADJ
iajs-1179	56	22	,	,	PUNCT
iajs-1179	56	23	and	and	CCONJ
iajs-1179	56	24	g	g	PROPN
iajs-1179	56	25	‡	‡	NOUN
iajs-1179	56	26	is	be	AUX
iajs-1179	56	27	the	the	DET
iajs-1179	56	28	gibbs	gibbs	PROPN
iajs-1179	56	29	free	free	ADJ
iajs-1179	56	30	energy	energy	NOUN
iajs-1179	56	31	of	of	ADP
iajs-1179	56	32	activation	activation	NOUN
iajs-1179	56	33	.	.	PUNCT
iajs-1179	57	1	the	the	DET
iajs-1179	57	2	potential	potential	ADJ
iajs-1179	57	3	energy	energy	NOUN
iajs-1179	57	4	surfaces	surface	NOUN
iajs-1179	57	5	of	of	ADP
iajs-1179	57	6	the	the	DET
iajs-1179	57	7	reactant	reactant	NOUN
iajs-1179	57	8	and	and	CCONJ
iajs-1179	57	9	product	product	NOUN
iajs-1179	57	10	states	state	NOUN
iajs-1179	57	11	can	can	AUX
iajs-1179	57	12	be	be	AUX
iajs-1179	57	13	described	describe	VERB
iajs-1179	57	14	as	as	ADP
iajs-1179	57	15	free	free	ADJ
iajs-1179	57	16	energy	energy	NOUN
iajs-1179	57	17	surfaces	surface	NOUN
iajs-1179	57	18	,	,	PUNCT
iajs-1179	57	19	and	and	CCONJ
iajs-1179	57	20	et	et	NOUN
iajs-1179	57	21	occurs	occur	VERB
iajs-1179	57	22	at	at	ADP
iajs-1179	57	23	the	the	DET
iajs-1179	57	24	crossing	crossing	NOUN
iajs-1179	57	25	of	of	ADP
iajs-1179	57	26	the	the	DET
iajs-1179	57	27	reactant	reactant	NOUN
iajs-1179	57	28	and	and	CCONJ
iajs-1179	57	29	product	product	NOUN
iajs-1179	57	30	surfaces	surface	NOUN
iajs-1179	57	31	.	.	PUNCT
iajs-1179	58	1	the	the	DET
iajs-1179	58	2	amount	amount	NOUN
iajs-1179	58	3	of	of	ADP
iajs-1179	58	4	free	free	ADJ
iajs-1179	58	5	energy	energy	NOUN
iajs-1179	58	6	required	require	VERB
iajs-1179	58	7	to	to	PART
iajs-1179	58	8	bring	bring	VERB
iajs-1179	58	9	the	the	DET
iajs-1179	58	10	reactant	reactant	NOUN
iajs-1179	58	11	to	to	ADP
iajs-1179	58	12	the	the	DET
iajs-1179	58	13	crossing	crossing	NOUN
iajs-1179	58	14	point	point	NOUN
iajs-1179	58	15	is	be	AUX
iajs-1179	58	16	the	the	DET
iajs-1179	58	17	free	free	ADJ
iajs-1179	58	18	energy	energy	NOUN
iajs-1179	58	19	of	of	ADP
iajs-1179	58	20	activation	activation	NOUN
iajs-1179	58	21	,	,	PUNCT
iajs-1179	58	22	g	g	PROPN
iajs-1179	58	23	‡	‡	X
iajs-1179	58	24	,	,	PUNCT
iajs-1179	58	25	defined	define	VERB
iajs-1179	58	26	as	as	ADP
iajs-1179	58	27	(	(	PUNCT
iajs-1179	58	28	13	13	NUM
iajs-1179	58	29	)	)	PUNCT
iajs-1179	58	30	.	.	PUNCT
iajs-1179	59	1	g	g	PROPN
iajs-1179	59	2	‡=	‡=	PROPN
iajs-1179	59	3			NOUN
iajs-1179	59	4			PROPN
iajs-1179	59	5	]	]	SYM
iajs-1179	59	6	5	5	NUM
iajs-1179	59	7	.......	.......	PUNCT
iajs-1179	59	8	[	[	X
iajs-1179	59	9	....................	....................	PUNCT
iajs-1179	59	10	4	4	NUM
iajs-1179	59	11	2	2	NUM
iajs-1179	59	12			NOUN
iajs-1179	59	13			NOUN
iajs-1179	59	14	g	g	NOUN
iajs-1179	59	15	where	where	SCONJ
iajs-1179	59	16	g	g	PROPN
iajs-1179	59	17	is	be	AUX
iajs-1179	59	18	the	the	DET
iajs-1179	59	19	free	free	ADJ
iajs-1179	59	20	energy	energy	NOUN
iajs-1179	59	21	change	change	NOUN
iajs-1179	59	22	for	for	ADP
iajs-1179	59	23	any	any	DET
iajs-1179	59	24	chemical	chemical	NOUN
iajs-1179	59	25	reaction	reaction	NOUN
iajs-1179	59	26	which	which	PRON
iajs-1179	59	27	is	be	AUX
iajs-1179	59	28	the	the	DET
iajs-1179	59	29	difference	difference	NOUN
iajs-1179	59	30	in	in	ADP
iajs-1179	59	31	the	the	DET
iajs-1179	59	32	energy	energy	NOUN
iajs-1179	59	33	of	of	ADP
iajs-1179	59	34	the	the	DET
iajs-1179	59	35	products	product	NOUN
iajs-1179	59	36	and	and	CCONJ
iajs-1179	59	37	the	the	DET
iajs-1179	59	38	reactants	reactant	NOUN
iajs-1179	59	39	.	.	PUNCT
iajs-1179	60	1	for	for	ADP
iajs-1179	60	2	et	et	NOUN
iajs-1179	60	3	reactions	reaction	NOUN
iajs-1179	60	4	,	,	PUNCT
iajs-1179	60	5	this	this	PRON
iajs-1179	60	6	can	can	AUX
iajs-1179	60	7	be	be	AUX
iajs-1179	60	8	broken	break	VERB
iajs-1179	60	9	into	into	ADP
iajs-1179	60	10	the	the	DET
iajs-1179	60	11	work	work	NOUN
iajs-1179	60	12	it	it	PRON
iajs-1179	60	13	takes	take	VERB
iajs-1179	60	14	to	to	PART
iajs-1179	60	15	bring	bring	VERB
iajs-1179	60	16	the	the	DET
iajs-1179	60	17	donor	donor	NOUN
iajs-1179	60	18	and	and	CCONJ
iajs-1179	60	19	acceptor	acceptor	NOUN
iajs-1179	60	20	together	together	ADV
iajs-1179	60	21	and	and	CCONJ
iajs-1179	60	22	the	the	DET
iajs-1179	60	23	difference	difference	NOUN
iajs-1179	60	24	between	between	ADP
iajs-1179	60	25	the	the	DET
iajs-1179	60	26	reduction	reduction	NOUN
iajs-1179	60	27	potentials	potential	NOUN
iajs-1179	60	28	of	of	ADP
iajs-1179	60	29	the	the	DET
iajs-1179	60	30	acceptor	acceptor	NOUN
iajs-1179	60	31	and	and	CCONJ
iajs-1179	60	32	donor	donor	NOUN
iajs-1179	60	33	.	.	PUNCT
iajs-1179	61	1	the	the	DET
iajs-1179	61	2	reorganization	reorganization	NOUN
iajs-1179	61	3	energy	energy	NOUN
iajs-1179	61	4			X
iajs-1179	61	5	is	be	AUX
iajs-1179	61	6	the	the	DET
iajs-1179	61	7	sum	sum	NOUN
iajs-1179	61	8	of	of	ADP
iajs-1179	61	9	the	the	DET
iajs-1179	61	10	inner	inner	ADJ
iajs-1179	61	11			ADJ
iajs-1179	61	12	in	in	ADP
iajs-1179	61	13	,	,	PUNCT
iajs-1179	61	14	and	and	CCONJ
iajs-1179	61	15	outer	outer	ADJ
iajs-1179	61	16	,	,	PUNCT
iajs-1179	61	17			ADJ
iajs-1179	61	18	out	out	ADV
iajs-1179	61	19	,	,	PUNCT
iajs-1179	61	20	reorganization(15	reorganization(15	NOUN
iajs-1179	61	21	)	)	PUNCT
iajs-1179	61	22			X
iajs-1179	61	23	=	=	SYM
iajs-1179	61	24			X
iajs-1179	61	25	in+	in+	NOUN
iajs-1179	61	26			ADJ
iajs-1179	61	27	out	out	ADP
iajs-1179	61	28	…	…	PUNCT
iajs-1179	61	29	…	…	PUNCT
iajs-1179	61	30	…	…	PUNCT
iajs-1179	61	31	…	…	PUNCT
iajs-1179	61	32	…	…	PUNCT
iajs-1179	61	33	…	…	PUNCT
iajs-1179	61	34	…	…	PUNCT
iajs-1179	61	35	…	…	PUNCT
iajs-1179	61	36	…	…	PUNCT
iajs-1179	61	37	[	[	X
iajs-1179	61	38	6	6	NUM
iajs-1179	61	39	]	]	PUNCT
iajs-1179	61	40	the	the	DET
iajs-1179	61	41	inner	inner	ADJ
iajs-1179	61	42	reorganization	reorganization	NOUN
iajs-1179	61	43	component	component	NOUN
iajs-1179	61	44	is	be	AUX
iajs-1179	61	45	the	the	DET
iajs-1179	61	46	energy	energy	NOUN
iajs-1179	61	47	required	require	VERB
iajs-1179	61	48	to	to	PART
iajs-1179	61	49	alter	alter	VERB
iajs-1179	61	50	bond	bond	NOUN
iajs-1179	61	51	distances	distance	NOUN
iajs-1179	61	52	and	and	CCONJ
iajs-1179	61	53	bond	bond	NOUN
iajs-1179	61	54	angles	angle	NOUN
iajs-1179	61	55	that	that	PRON
iajs-1179	61	56	would	would	AUX
iajs-1179	61	57	change	change	VERB
iajs-1179	61	58	with	with	ADP
iajs-1179	61	59	the	the	DET
iajs-1179	61	60	change	change	NOUN
iajs-1179	61	61	in	in	ADP
iajs-1179	61	62	oxidation	oxidation	NOUN
iajs-1179	61	63	state	state	NOUN
iajs-1179	61	64	.	.	PUNCT
iajs-1179	62	1	the	the	DET
iajs-1179	62	2	outer	outer	ADJ
iajs-1179	62	3	reorganization	reorganization	NOUN
iajs-1179	62	4	energy	energy	NOUN
iajs-1179	62	5	is	be	AUX
iajs-1179	62	6	required	require	VERB
iajs-1179	62	7	for	for	ADP
iajs-1179	62	8	the	the	DET
iajs-1179	62	9	reorientation	reorientation	NOUN
iajs-1179	62	10	of	of	ADP
iajs-1179	62	11	the	the	DET
iajs-1179	62	12	solvent	solvent	NOUN
iajs-1179	62	13	around	around	ADP
iajs-1179	62	14	the	the	DET
iajs-1179	62	15	changed	change	VERB
iajs-1179	62	16	complexes	complex	NOUN
iajs-1179	62	17	(	(	PUNCT
iajs-1179	62	18	15	15	NUM
iajs-1179	62	19	)	)	PUNCT
iajs-1179	62	20	.	.	PUNCT
iajs-1179	63	1	in	in	ADP
iajs-1179	63	2	many	many	ADJ
iajs-1179	63	3	complexes	complex	NOUN
iajs-1179	63	4	or	or	CCONJ
iajs-1179	63	5	big	big	ADJ
iajs-1179	63	6	molecules	molecule	NOUN
iajs-1179	63	7	that	that	PRON
iajs-1179	63	8	have	have	AUX
iajs-1179	63	9	asmall	asmall	VERB
iajs-1179	63	10	inner	inner	ADJ
iajs-1179	63	11	reorganization	reorganization	NOUN
iajs-1179	63	12	,	,	PUNCT
iajs-1179	63	13	such	such	ADJ
iajs-1179	63	14	that	that	SCONJ
iajs-1179	63	15	,	,	PUNCT
iajs-1179	63	16	we	we	PRON
iajs-1179	63	17	can	can	AUX
iajs-1179	63	18	assume	assume	VERB
iajs-1179	63	19			ADJ
iajs-1179	63	20	out	out	PROPN
iajs-1179	63	21	out.	out.	PUNCT
iajs-1179	63	22	can	can	AUX
iajs-1179	63	23	be	be	AUX
iajs-1179	63	24	estimated	estimate	VERB
iajs-1179	63	25	from	from	ADP
iajs-1179	63	26	a	a	DET
iajs-1179	63	27	dielectric	dielectric	ADJ
iajs-1179	63	28	continuum	continuum	ADJ
iajs-1179	63	29	model	model	NOUN
iajs-1179	63	30	for	for	ADP
iajs-1179	63	31	the	the	DET
iajs-1179	63	32	solvent	solvent	NOUN
iajs-1179	63	33	,	,	PUNCT
iajs-1179	63	34	and	and	CCONJ
iajs-1179	63	35	give	give	VERB
iajs-1179	63	36	the	the	DET
iajs-1179	63	37	largest	large	ADJ
iajs-1179	63	38	contribution	contribution	NOUN
iajs-1179	63	39	to	to	ADP
iajs-1179	63	40			NOUN
iajs-1179	63	41	in	in	ADP
iajs-1179	63	42	many	many	ADJ
iajs-1179	63	43	et	et	NOUN
iajs-1179	63	44	reactions	reaction	NOUN
iajs-1179	63	45	in	in	ADP
iajs-1179	63	46	polar	polar	ADJ
iajs-1179	63	47	media	medium	NOUN
iajs-1179	63	48	(	(	PUNCT
iajs-1179	63	49	16	16	NUM
iajs-1179	63	50	)	)	PUNCT
iajs-1179	63	51	.	.	PUNCT
iajs-1179	64	1	the	the	DET
iajs-1179	64	2	solvent	solvent	NOUN
iajs-1179	64	3	reorganization	reorganization	NOUN
iajs-1179	64	4	energy	energy	NOUN
iajs-1179	64	5	in	in	ADP
iajs-1179	64	6	this	this	DET
iajs-1179	64	7	model	model	NOUN
iajs-1179	64	8	is	be	AUX
iajs-1179	64	9	given	give	VERB
iajs-1179	64	10	by	by	ADP
iajs-1179	64	11	(	(	PUNCT
iajs-1179	64	12	16	16	NUM
iajs-1179	64	13	)	)	PUNCT
iajs-1179	64	14	]	]	PUNCT
iajs-1179	65	1	7	7	X
iajs-1179	65	2	.....	.....	PUNCT
iajs-1179	65	3	[	[	X
iajs-1179	65	4	..............................	..............................	PUNCT
iajs-1179	65	5	111	111	NUM
iajs-1179	65	6	2	2	NUM
iajs-1179	65	7	1	1	NUM
iajs-1179	65	8	2	2	NUM
iajs-1179	65	9	1	1	NUM
iajs-1179	65	10	4	4	NUM
iajs-1179	65	11	2	2	NUM
iajs-1179	65	12			PROPN
iajs-1179	65	13			PROPN
iajs-1179	65	14			NOUN
iajs-1179	65	15			PROPN
iajs-1179	65	16			PROPN
iajs-1179	65	17			PROPN
iajs-1179	66	1			PROPN
iajs-1179	66	2			NOUN
iajs-1179	66	3			NOUN
iajs-1179	66	4			PROPN
iajs-1179	66	5			NUM
iajs-1179	66	6			PRON
iajs-1179	66	7			NOUN
iajs-1179	66	8			PROPN
iajs-1179	66	9			PROPN
iajs-1179	66	10			PROPN
iajs-1179	66	11			NOUN
iajs-1179	66	12			PROPN
iajs-1179	66	13			NOUN
iajs-1179	66	14			PROPN
iajs-1179	66	15			PROPN
iajs-1179	66	16	spodaad	spodaad	NOUN
iajs-1179	66	17	rrr	rrr	PROPN
iajs-1179	66	18	e	e	PROPN
iajs-1179	66	19			PROPN
iajs-1179	66	20			NOUN
iajs-1179	66	21	where	where	SCONJ
iajs-1179	66	22	e	e	NOUN
iajs-1179	66	23	is	be	AUX
iajs-1179	66	24	the	the	DET
iajs-1179	66	25	charge	charge	NOUN
iajs-1179	66	26	involved	involve	VERB
iajs-1179	66	27	(	(	PUNCT
iajs-1179	66	28	usually	usually	ADV
iajs-1179	66	29	one	one	NUM
iajs-1179	66	30	electron	electron	NOUN
iajs-1179	66	31	)	)	PUNCT
iajs-1179	66	32	,	,	PUNCT
iajs-1179	66	33			X
iajs-1179	66	34	is	be	AUX
iajs-1179	66	35	the	the	DET
iajs-1179	66	36	vacuum	vacuum	NOUN
iajs-1179	66	37	permittivity	permittivity	NOUN
iajs-1179	66	38	,	,	PUNCT
iajs-1179	66	39	p	p	PROPN
iajs-1179	66	40			NOUN
iajs-1179	66	41	and	and	CCONJ
iajs-1179	66	42	s	s	NOUN
iajs-1179	66	43	is	be	AUX
iajs-1179	66	44	the	the	DET
iajs-1179	66	45	optical	optical	ADJ
iajs-1179	66	46	and	and	CCONJ
iajs-1179	66	47	static	static	ADJ
iajs-1179	66	48	dielectric	dielectric	ADJ
iajs-1179	66	49	constants	constant	NOUN
iajs-1179	66	50	,	,	PUNCT
iajs-1179	66	51	(	(	PUNCT
iajs-1179	66	52	rd	rd	NOUN
iajs-1179	66	53	,	,	PUNCT
iajs-1179	66	54	ra	ra	PROPN
iajs-1179	66	55	,	,	PUNCT
iajs-1179	66	56	)	)	PUNCT
iajs-1179	66	57	are	be	AUX
iajs-1179	66	58	the	the	DET
iajs-1179	66	59	donor	donor	NOUN
iajs-1179	66	60	and	and	CCONJ
iajs-1179	66	61	acceptor	acceptor	NOUN
iajs-1179	66	62	radii	radius	NOUN
iajs-1179	66	63	and	and	CCONJ
iajs-1179	66	64	rda	rda	NOUN
iajs-1179	66	65	is	be	AUX
iajs-1179	66	66	the	the	DET
iajs-1179	66	67	donor	donor	NOUN
iajs-1179	66	68	–	–	PUNCT
iajs-1179	66	69	acceptor	acceptor	NOUN
iajs-1179	66	70	center	center	NOUN
iajs-1179	66	71	to	to	PART
iajs-1179	66	72	center	center	NOUN
iajs-1179	66	73	distance	distance	NOUN
iajs-1179	66	74	.	.	PUNCT
iajs-1179	67	1	results	result	VERB
iajs-1179	67	2	the	the	DET
iajs-1179	67	3	rate	rate	NOUN
iajs-1179	67	4	of	of	ADP
iajs-1179	67	5	et	et	NOUN
iajs-1179	67	6	is	be	AUX
iajs-1179	67	7	determined	determine	VERB
iajs-1179	67	8	by	by	ADP
iajs-1179	67	9	many	many	ADJ
iajs-1179	67	10	parameters	parameter	NOUN
iajs-1179	67	11	.	.	PUNCT
iajs-1179	68	1	the	the	DET
iajs-1179	68	2	effective	effective	ADJ
iajs-1179	68	3	free	free	ADJ
iajs-1179	68	4	energy	energy	NOUN
iajs-1179	68	5	g	g	NOUN
iajs-1179	68	6	for	for	ADP
iajs-1179	68	7	the	the	DET
iajs-1179	68	8	reaction	reaction	NOUN
iajs-1179	68	9	,	,	PUNCT
iajs-1179	68	10	the	the	DET
iajs-1179	68	11	value	value	NOUN
iajs-1179	68	12	of	of	ADP
iajs-1179	68	13	the	the	DET
iajs-1179	68	14	reorganization	reorganization	NOUN
iajs-1179	68	15	energy	energy	NOUN
iajs-1179	68	16	of	of	ADP
iajs-1179	68	17	the	the	DET
iajs-1179	68	18	electron	electron	NOUN
iajs-1179	68	19	donor	donor	NOUN
iajs-1179	68	20	(	(	PUNCT
iajs-1179	68	21	d	d	NOUN
iajs-1179	68	22	)	)	PUNCT
iajs-1179	68	23	and	and	CCONJ
iajs-1179	68	24	acceptor	acceptor	NOUN
iajs-1179	68	25	(	(	PUNCT
iajs-1179	68	26	a	a	NOUN
iajs-1179	68	27	)	)	PUNCT
iajs-1179	68	28	required	require	VERB
iajs-1179	68	29	upon	upon	SCONJ
iajs-1179	68	30	et	et	NOUN
iajs-1179	68	31	,	,	PUNCT
iajs-1179	68	32	activation	activation	NOUN
iajs-1179	68	33	free	free	ADJ
iajs-1179	68	34	energy	energy	NOUN
iajs-1179	68	35	g	g	PROPN
iajs-1179	68	36	‡	‡	X
iajs-1179	68	37	,	,	PUNCT
iajs-1179	68	38	and	and	CCONJ
iajs-1179	68	39	coupling	couple	VERB
iajs-1179	68	40	coefficient	coefficient	NOUN
iajs-1179	68	41	matrix	matrix	NOUN
iajs-1179	68	42	element	element	NOUN
iajs-1179	68	43	of	of	ADP
iajs-1179	68	44	et	et	PROPN
iajs-1179	68	45	,	,	PUNCT
iajs-1179	68	46	vda	vda	VERB
iajs-1179	68	47	a	a	DET
iajs-1179	68	48	more	more	ADV
iajs-1179	68	49	genral	genral	ADJ
iajs-1179	68	50	expression	expression	NOUN
iajs-1179	68	51	equation	equation	NOUN
iajs-1179	68	52	eq.[7	eq.[7	PROPN
iajs-1179	68	53	]	]	PUNCT
iajs-1179	68	54	was	be	AUX
iajs-1179	68	55	applied	apply	VERB
iajs-1179	68	56	to	to	PART
iajs-1179	68	57	evaluate	evaluate	VERB
iajs-1179	68	58	the	the	DET
iajs-1179	68	59	reorganization	reorganization	NOUN
iajs-1179	68	60	energy	energy	NOUN
iajs-1179	68	61			NOUN
iajs-1179	68	62	,	,	PUNCT
iajs-1179	68	63	for	for	ADP
iajs-1179	68	64	a	a	DET
iajs-1179	68	65	donoer	donoer	NOUN
iajs-1179	68	66	2	2	PROPN
iajs-1179	68	67	3)(bpyru	3)(bpyru	NOUN
iajs-1179	68	68	and	and	CCONJ
iajs-1179	68	69	acceptor	acceptor	NOUN
iajs-1179	68	70	mv	mv	PROPN
iajs-1179	68	71	2	2	NUM
iajs-1179	68	72	+	+	NOUN
iajs-1179	68	73	system	system	NOUN
iajs-1179	68	74	in	in	ADP
iajs-1179	68	75	a	a	DET
iajs-1179	68	76	variety	variety	NOUN
iajs-1179	68	77	solvent	solvent	NOUN
iajs-1179	68	78	,	,	PUNCT
iajs-1179	68	79	where	where	SCONJ
iajs-1179	68	80	ibn	ibn	PROPN
iajs-1179	68	81	alhaitham	alhaitham	NOUN
iajs-1179	68	82	j.	j.	PROPN
iajs-1179	68	83	fo	fo	ADP
iajs-1179	68	84	r	r	NOUN
iajs-1179	68	85	pure	pure	ADJ
iajs-1179	68	86	&	&	CCONJ
iajs-1179	68	87	appl	appl	PROPN
iajs-1179	68	88	.	.	PUNCT
iajs-1179	69	1	sc	sc	PROPN
iajs-1179	70	1	i	i	PRON
iajs-1179	70	2	vo	vo	INTJ
iajs-1179	70	3	l.22	l.22	X
iajs-1179	70	4	(	(	PUNCT
iajs-1179	70	5	3	3	NUM
iajs-1179	70	6	)	)	PUNCT
iajs-1179	70	7	2009	2009	NUM
iajs-1179	70	8	radii	radius	NOUN
iajs-1179	70	9	ra=6.5	ra=6.5	VERB
iajs-1179	70	10	a	a	NOUN
iajs-1179	70	11	for	for	ADP
iajs-1179	70	12	acceptor	acceptor	NOUN
iajs-1179	70	13	and	and	CCONJ
iajs-1179	70	14	rd=3.5	rd=3.5	NOUN
iajs-1179	70	15	a	a	NOUN
iajs-1179	70	16	for	for	ADP
iajs-1179	70	17	donor	donor	NOUN
iajs-1179	70	18	(	(	PUNCT
iajs-1179	70	19	17	17	NUM
iajs-1179	70	20	)	)	PUNCT
iajs-1179	70	21	,	,	PUNCT
iajs-1179	70	22	p	p	NOUN
iajs-1179	70	23			NOUN
iajs-1179	70	24	and	and	CCONJ
iajs-1179	70	25	s	s	PROPN
iajs-1179	70	26	are	be	AUX
iajs-1179	70	27	the	the	DET
iajs-1179	70	28	optical	optical	ADJ
iajs-1179	70	29	and	and	CCONJ
iajs-1179	70	30	static	static	ADJ
iajs-1179	70	31	dielectric	dielectric	ADJ
iajs-1179	70	32	constants	constant	NOUN
iajs-1179	70	33	of	of	ADP
iajs-1179	70	34	the	the	DET
iajs-1179	70	35	solvent	solvent	NOUN
iajs-1179	70	36	[	[	PUNCT
iajs-1179	70	37	p	p	PROPN
iajs-1179	70	38			NOUN
iajs-1179	70	39			PROPN
iajs-1179	70	40	1.344	1.344	NUM
iajs-1179	70	41	and	and	CCONJ
iajs-1179	70	42	s	s	ADJ
iajs-1179	70	43	=	=	SYM
iajs-1179	70	44	37.5for	37.5for	PROPN
iajs-1179	70	45	acetonitriale	acetonitriale	NOUN
iajs-1179	70	46	(	(	PUNCT
iajs-1179	70	47	16	16	NUM
iajs-1179	70	48	)	)	PUNCT
iajs-1179	70	49	,	,	PUNCT
iajs-1179	70	50	p	p	VERB
iajs-1179	70	51			NOUN
iajs-1179	70	52	=	=	NOUN
iajs-1179	70	53	1.77	1.77	NUM
iajs-1179	70	54	and	and	CCONJ
iajs-1179	70	55	s	s	NOUN
iajs-1179	70	56	=	=	NOUN
iajs-1179	70	57	78.5	78.5	NUM
iajs-1179	70	58	for	for	ADP
iajs-1179	70	59	water	water	NOUN
iajs-1179	70	60	]	]	PUNCT
iajs-1179	70	61	(	(	PUNCT
iajs-1179	70	62	16,18	16,18	NOUN
iajs-1179	70	63	)	)	PUNCT
iajs-1179	70	64	.	.	PUNCT
iajs-1179	71	1	the	the	DET
iajs-1179	71	2	values	value	NOUN
iajs-1179	71	3	of	of	ADP
iajs-1179	71	4	reorganization	reorganization	NOUN
iajs-1179	71	5	energies	energy	NOUN
iajs-1179	71	6	,	,	PUNCT
iajs-1179	71	7	in	in	ADP
iajs-1179	71	8	the	the	DET
iajs-1179	71	9	present	present	ADJ
iajs-1179	71	10	system	system	NOUN
iajs-1179	71	11	are	be	AUX
iajs-1179	71	12	0.952ev	0.952ev	NUM
iajs-1179	71	13	and	and	CCONJ
iajs-1179	71	14	0.908	0.908	NUM
iajs-1179	71	15	ev	ev	INTJ
iajs-1179	71	16	in	in	ADP
iajs-1179	71	17	acetonetriale	acetonetriale	NOUN
iajs-1179	71	18	and	and	CCONJ
iajs-1179	71	19	water	water	NOUN
iajs-1179	71	20	solvent	solvent	NOUN
iajs-1179	71	21	respectively	respectively	ADV
iajs-1179	71	22	.	.	PUNCT
iajs-1179	72	1	so	so	ADV
iajs-1179	72	2	the	the	DET
iajs-1179	72	3	other	other	ADJ
iajs-1179	72	4	variable	variable	NOUN
iajs-1179	72	5	in	in	ADP
iajs-1179	72	6	the	the	DET
iajs-1179	72	7	rate	rate	NOUN
iajs-1179	72	8	et	et	NOUN
iajs-1179	72	9	expression	expression	NOUN
iajs-1179	72	10	is	be	AUX
iajs-1179	72	11	the	the	DET
iajs-1179	72	12	driving	drive	VERB
iajs-1179	72	13	force	force	NOUN
iajs-1179	72	14	g	g	PROPN
iajs-1179	72	15	(	(	PUNCT
iajs-1179	72	16	effective	effective	ADJ
iajs-1179	72	17	free	free	ADJ
iajs-1179	72	18	energy	energy	NOUN
iajs-1179	72	19	)	)	PUNCT
iajs-1179	72	20	that	that	PRON
iajs-1179	72	21	is	be	AUX
iajs-1179	72	22	p	p	PRON
iajs-1179	72	23	rovided	rovide	VERB
iajs-1179	72	24	by	by	ADP
iajs-1179	72	25	the	the	DET
iajs-1179	72	26	absorp	absorp	PROPN
iajs-1179	72	27	tion	tion	NOUN
iajs-1179	72	28	of	of	ADP
iajs-1179	72	29	light	light	NOUN
iajs-1179	72	30	in	in	ADP
iajs-1179	72	31	2	2	PROPN
iajs-1179	72	32	3)(bpyru	3)(bpyru	PROPN
iajs-1179	72	33	-mv	-mv	PUNCT
iajs-1179	72	34	2	2	NUM
iajs-1179	72	35	+	+	NUM
iajs-1179	72	36	system	system	NOUN
iajs-1179	72	37	that	that	PRON
iajs-1179	72	38	is	be	AUX
iajs-1179	72	39	very	very	ADV
iajs-1179	72	40	clear	clear	ADJ
iajs-1179	72	41	from	from	ADP
iajs-1179	72	42	eq.[2	eq.[2	PROPN
iajs-1179	72	43	]	]	PUNCT
iajs-1179	72	44	and	and	CCONJ
iajs-1179	72	45	figure	figure	NOUN
iajs-1179	72	46	(	(	PUNCT
iajs-1179	72	47	2	2	NUM
iajs-1179	72	48	)	)	PUNCT
iajs-1179	72	49	.	.	PUNCT
iajs-1179	73	1	the	the	DET
iajs-1179	73	2	driving	drive	VERB
iajs-1179	73	3	force	force	NOUN
iajs-1179	73	4	is	be	AUX
iajs-1179	73	5	defined	define	VERB
iajs-1179	73	6	as	as	ADP
iajs-1179	73	7	the	the	DET
iajs-1179	73	8	part	part	NOUN
iajs-1179	73	9	of	of	ADP
iajs-1179	73	10	the	the	DET
iajs-1179	73	11	work	work	NOUN
iajs-1179	73	12	it	it	PRON
iajs-1179	73	13	takes	take	VERB
iajs-1179	73	14	to	to	PART
iajs-1179	73	15	bring	bring	VERB
iajs-1179	73	16	the	the	DET
iajs-1179	73	17	donor	donor	NOUN
iajs-1179	73	18	and	and	CCONJ
iajs-1179	73	19	acceptor	acceptor	NOUN
iajs-1179	73	20	together	together	ADV
iajs-1179	73	21	,	,	PUNCT
iajs-1179	73	22	and	and	CCONJ
iajs-1179	73	23	the	the	DET
iajs-1179	73	24	difference	difference	NOUN
iajs-1179	73	25	between	between	ADP
iajs-1179	73	26	the	the	DET
iajs-1179	73	27	reduction	reduction	NOUN
iajs-1179	73	28	potentials	potential	NOUN
iajs-1179	73	29	of	of	ADP
iajs-1179	73	30	the	the	DET
iajs-1179	73	31	acceptor	acceptor	NOUN
iajs-1179	73	32	and	and	CCONJ
iajs-1179	73	33	donor	donor	NOUN
iajs-1179	73	34	.	.	PUNCT
iajs-1179	74	1	the	the	DET
iajs-1179	74	2	theoretical	theoretical	ADJ
iajs-1179	74	3	calculation	calculation	NOUN
iajs-1179	74	4	values	value	NOUN
iajs-1179	74	5	of	of	ADP
iajs-1179	74	6	the	the	DET
iajs-1179	74	7	free	free	ADJ
iajs-1179	74	8	energy	energy	NOUN
iajs-1179	74	9	can	can	AUX
iajs-1179	74	10	be	be	AUX
iajs-1179	74	11	evaluated	evaluate	VERB
iajs-1179	74	12	by	by	ADP
iajs-1179	74	13	using	use	VERB
iajs-1179	74	14	eq.[2	eq.[2	NOUN
iajs-1179	74	15	]	]	PUNCT
iajs-1179	74	16	,	,	PUNCT
iajs-1179	74	17	where	where	SCONJ
iajs-1179	74	18	e=	e=	X
iajs-1179	74	19	h	h	PROPN
iajs-1179	74	20	is	be	AUX
iajs-1179	74	21	the	the	DET
iajs-1179	74	22	absorption	absorption	NOUN
iajs-1179	74	23	energy	energy	NOUN
iajs-1179	74	24	taken	take	VERB
iajs-1179	74	25	from	from	ADP
iajs-1179	74	26	absorption	absorption	NOUN
iajs-1179	74	27	spectral	spectral	NOUN
iajs-1179	74	28	of	of	ADP
iajs-1179	74	29	2	2	PROPN
iajs-1179	74	30	3)(bpyru	3)(bpyru	PROPN
iajs-1179	74	31	.	.	PUNCT
iajs-1179	75	1	these	these	DET
iajs-1179	75	2	results	result	NOUN
iajs-1179	75	3	of	of	ADP
iajs-1179	75	4	g	g	NOUN
iajs-1179	75	5	(	(	PUNCT
iajs-1179	75	6	ev	ev	PROPN
iajs-1179	75	7	)	)	PUNCT
iajs-1179	75	8	in	in	ADP
iajs-1179	75	9	acetonitrial	acetonitrial	ADJ
iajs-1179	75	10	and	and	CCONJ
iajs-1179	75	11	water	water	NOUN
iajs-1179	75	12	solution	solution	NOUN
iajs-1179	75	13	are	be	AUX
iajs-1179	75	14	sumarized	sumarize	VERB
iajs-1179	75	15	in	in	ADP
iajs-1179	75	16	table	table	NOUN
iajs-1179	75	17	(	(	PUNCT
iajs-1179	75	18	1	1	NUM
iajs-1179	75	19	)	)	PUNCT
iajs-1179	75	20	.	.	PUNCT
iajs-1179	76	1	now	now	ADV
iajs-1179	76	2	,	,	PUNCT
iajs-1179	76	3	by	by	ADP
iajs-1179	76	4	substituting	substitute	VERB
iajs-1179	76	5	the	the	DET
iajs-1179	76	6	values	value	NOUN
iajs-1179	76	7	of	of	ADP
iajs-1179	76	8	the	the	DET
iajs-1179	76	9	driving	drive	VERB
iajs-1179	76	10	force	force	NOUN
iajs-1179	76	11	g	g	PROPN
iajs-1179	76	12	(	(	PUNCT
iajs-1179	76	13	ev	ev	PROPN
iajs-1179	76	14	)	)	PUNCT
iajs-1179	76	15	and	and	CCONJ
iajs-1179	76	16	the	the	DET
iajs-1179	76	17	solvent	solvent	NOUN
iajs-1179	76	18	reorganization	reorganization	NOUN
iajs-1179	76	19	energy	energy	NOUN
iajs-1179	76	20	)	)	PUNCT
iajs-1179	76	21	(	(	PUNCT
iajs-1179	76	22	ev	ev	NOUN
iajs-1179	76	23	for	for	ADP
iajs-1179	76	24	both	both	DET
iajs-1179	76	25	solvents	solvent	NOUN
iajs-1179	76	26	in	in	ADP
iajs-1179	76	27	eq.[5	eq.[5	PROPN
iajs-1179	76	28	]	]	PUNCT
iajs-1179	76	29	we	we	PRON
iajs-1179	76	30	can	can	AUX
iajs-1179	76	31	calculate	calculate	VERB
iajs-1179	76	32	the	the	DET
iajs-1179	76	33	et	et	NOUN
iajs-1179	76	34	activation	activation	NOUN
iajs-1179	76	35	barrier	barrier	NOUN
iajs-1179	76	36	g	g	PROPN
iajs-1179	76	37	‡	‡	X
iajs-1179	76	38	)	)	PUNCT
iajs-1179	76	39	(	(	PUNCT
iajs-1179	76	40	ev	ev	PROPN
iajs-1179	76	41	.these	.these	PUNCT
iajs-1179	76	42	calculated	calculate	VERB
iajs-1179	76	43	values	value	NOUN
iajs-1179	76	44	are	be	AUX
iajs-1179	76	45	summarized	summarize	VERB
iajs-1179	76	46	in	in	ADP
iajs-1179	76	47	table	table	NOUN
iajs-1179	76	48	(	(	PUNCT
iajs-1179	76	49	2	2	NUM
iajs-1179	76	50	)	)	PUNCT
iajs-1179	76	51	.	.	PUNCT
iajs-1179	77	1	another	another	DET
iajs-1179	77	2	important	important	ADJ
iajs-1179	77	3	factor	factor	NOUN
iajs-1179	77	4	for	for	ADP
iajs-1179	77	5	et	et	PROPN
iajs-1179	77	6	are	be	AUX
iajs-1179	77	7	the	the	DET
iajs-1179	77	8	electronic	electronic	ADJ
iajs-1179	77	9	coupling	coupling	NOUN
iajs-1179	77	10	coefficients	coefficient	NOUN
iajs-1179	77	11	,	,	PUNCT
iajs-1179	77	12	vda	vda	PROPN
iajs-1179	77	13	,	,	PUNCT
iajs-1179	77	14	which	which	PRON
iajs-1179	77	15	is	be	AUX
iajs-1179	77	16	the	the	DET
iajs-1179	77	17	most	most	ADV
iajs-1179	77	18	difficult	difficult	ADJ
iajs-1179	77	19	parameter	parameter	NOUN
iajs-1179	77	20	to	to	PART
iajs-1179	77	21	obtain	obtain	VERB
iajs-1179	77	22	experimentally	experimentally	ADV
iajs-1179	77	23	.	.	PUNCT
iajs-1179	78	1	however	however	ADV
iajs-1179	78	2	,	,	PUNCT
iajs-1179	78	3	according	accord	VERB
iajs-1179	78	4	to	to	ADP
iajs-1179	78	5	the	the	DET
iajs-1179	78	6	theory	theory	NOUN
iajs-1179	78	7	by	by	ADP
iajs-1179	78	8	hush	hush	ADJ
iajs-1179	78	9	(	(	PUNCT
iajs-1179	78	10	19	19	NUM
iajs-1179	78	11	)	)	PUNCT
iajs-1179	78	12	,	,	PUNCT
iajs-1179	78	13	and	and	CCONJ
iajs-1179	78	14	the	the	DET
iajs-1179	78	15	assumption	assumption	NOUN
iajs-1179	78	16	that	that	SCONJ
iajs-1179	78	17	the	the	DET
iajs-1179	78	18	reaction	reaction	NOUN
iajs-1179	78	19	is	be	AUX
iajs-1179	78	20	activationless	activationless	NOUN
iajs-1179	78	21	,	,	PUNCT
iajs-1179	78	22	the	the	DET
iajs-1179	78	23	electronic	electronic	ADJ
iajs-1179	78	24	coupling	coupling	NOUN
iajs-1179	78	25	,	,	PUNCT
iajs-1179	78	26	vda	vda	PROPN
iajs-1179	78	27	,	,	PUNCT
iajs-1179	78	28	can	can	AUX
iajs-1179	78	29	be	be	AUX
iajs-1179	78	30	estimated	estimate	VERB
iajs-1179	78	31	to	to	PART
iajs-1179	78	32	be	be	AUX
iajs-1179	78	33	(	(	PUNCT
iajs-1179	78	34	0.01,0.03,0.2	0.01,0.03,0.2	NOUN
iajs-1179	78	35	)	)	PUNCT
iajs-1179	78	36	ev	ev	NOUN
iajs-1179	79	1	finally	finally	ADV
iajs-1179	79	2	we	we	PRON
iajs-1179	79	3	can	can	AUX
iajs-1179	79	4	calculate	calculate	VERB
iajs-1179	79	5	the	the	DET
iajs-1179	79	6	rate	rate	NOUN
iajs-1179	79	7	of	of	ADP
iajs-1179	79	8	the	the	DET
iajs-1179	79	9	photo	photo	NOUN
iajs-1179	79	10	induced	induce	VERB
iajs-1179	79	11	et	et	NOUN
iajs-1179	79	12	values	value	NOUN
iajs-1179	79	13	k	k	X
iajs-1179	79	14	between	between	ADP
iajs-1179	79	15	2	2	PROPN
iajs-1179	79	16	3)(bpyru	3)(bpyru	PROPN
iajs-1179	79	17	and	and	CCONJ
iajs-1179	79	18	methyle	methyle	PROPN
iajs-1179	79	19	viologen	viologen	PROPN
iajs-1179	79	20	mv2	mv2	PROPN
iajs-1179	79	21	+	+	X
iajs-1179	79	22	in	in	ADP
iajs-1179	79	23	a	a	DET
iajs-1179	79	24	different	different	ADJ
iajs-1179	79	25	solvent	solvent	NOUN
iajs-1179	79	26	by	by	ADP
iajs-1179	79	27	inserting	insert	VERB
iajs-1179	79	28	the	the	DET
iajs-1179	79	29	values	value	NOUN
iajs-1179	79	30	of	of	ADP
iajs-1179	79	31	the	the	DET
iajs-1179	79	32	coefficients	coefficient	NOUN
iajs-1179	79	33	)	)	PUNCT
iajs-1179	79	34	(	(	PUNCT
iajs-1179	79	35	ev	ev	NOUN
iajs-1179	79	36	,	,	PUNCT
iajs-1179	79	37	g	g	PROPN
iajs-1179	79	38	(	(	PUNCT
iajs-1179	79	39	ev	ev	PROPN
iajs-1179	79	40	)	)	PUNCT
iajs-1179	79	41	,	,	PUNCT
iajs-1179	79	42	g	g	PROPN
iajs-1179	79	43	‡	‡	X
iajs-1179	79	44	)	)	PUNCT
iajs-1179	79	45	(	(	PUNCT
iajs-1179	79	46	ev	ev	INTJ
iajs-1179	79	47	,	,	PUNCT
iajs-1179	79	48	and	and	CCONJ
iajs-1179	79	49	vda	vda	PROPN
iajs-1179	79	50	)	)	PUNCT
iajs-1179	79	51	(	(	PUNCT
iajs-1179	79	52	ev	ev	X
iajs-1179	79	53	in	in	ADP
iajs-1179	79	54	equation	equation	NOUN
iajs-1179	79	55	eq.[4	eq.[4	PROPN
iajs-1179	79	56	]	]	PUNCT
iajs-1179	79	57	,	,	PUNCT
iajs-1179	79	58	the	the	DET
iajs-1179	79	59	results	result	NOUN
iajs-1179	79	60	of	of	ADP
iajs-1179	79	61	rate	rate	NOUN
iajs-1179	79	62	et	et	NOUN
iajs-1179	79	63	are	be	AUX
iajs-1179	79	64	listed	list	VERB
iajs-1179	79	65	in	in	ADP
iajs-1179	79	66	tables	table	NOUN
iajs-1179	79	67	(	(	PUNCT
iajs-1179	79	68	3	3	NUM
iajs-1179	79	69	-	-	SYM
iajs-1179	79	70	4	4	NUM
iajs-1179	79	71	)	)	PUNCT
iajs-1179	79	72	.	.	PUNCT
iajs-1179	80	1	discussion	discussion	NOUN
iajs-1179	80	2	when	when	SCONJ
iajs-1179	80	3	the	the	DET
iajs-1179	80	4			PROPN
iajs-1179	80	5	22	22	NUM
iajs-1179	80	6	3	3	NUM
iajs-1179	80	7	)	)	PUNCT
iajs-1179	80	8	(	(	PUNCT
iajs-1179	80	9	mvbpyru	mvbpyru	NOUN
iajs-1179	80	10	solution	solution	NOUN
iajs-1179	80	11	systems	system	NOUN
iajs-1179	80	12	are	be	AUX
iajs-1179	80	13	promoted	promote	VERB
iajs-1179	80	14	to	to	PART
iajs-1179	80	15	electronically	electronically	ADV
iajs-1179	80	16	excited	excite	VERB
iajs-1179	80	17	states	state	NOUN
iajs-1179	80	18	by	by	ADP
iajs-1179	80	19	the	the	DET
iajs-1179	80	20	absorption	absorption	NOUN
iajs-1179	80	21	of	of	ADP
iajs-1179	80	22	light	light	NOUN
iajs-1179	80	23	,	,	PUNCT
iajs-1179	80	24	some	some	PRON
iajs-1179	80	25	of	of	ADP
iajs-1179	80	26	this	this	DET
iajs-1179	80	27	absorption	absorption	NOUN
iajs-1179	80	28	energy	energy	NOUN
iajs-1179	80	29	of	of	ADP
iajs-1179	80	30	light	light	NOUN
iajs-1179	80	31	is	be	AUX
iajs-1179	80	32	used	use	VERB
iajs-1179	80	33	to	to	PART
iajs-1179	80	34	distort	distort	VERB
iajs-1179	80	35	the	the	DET
iajs-1179	80	36	nuclear	nuclear	ADJ
iajs-1179	80	37	configuration	configuration	NOUN
iajs-1179	80	38	from	from	ADP
iajs-1179	80	39	and	and	CCONJ
iajs-1179	80	40	its	its	PRON
iajs-1179	80	41	equilibrium	equilibrium	NOUN
iajs-1179	80	42	donor	donor	NOUN
iajs-1179	80	43	state	state	NOUN
iajs-1179	80	44	to	to	ADP
iajs-1179	80	45	the	the	DET
iajs-1179	80	46	acceptor	acceptor	NOUN
iajs-1179	80	47	state	state	NOUN
iajs-1179	80	48	without	without	ADP
iajs-1179	80	49	transfer	transfer	NOUN
iajs-1179	80	50	of	of	ADP
iajs-1179	80	51	an	an	DET
iajs-1179	80	52	electron	electron	NOUN
iajs-1179	80	53	.	.	PUNCT
iajs-1179	81	1	the	the	DET
iajs-1179	81	2	resulting	result	VERB
iajs-1179	81	3	values	value	NOUN
iajs-1179	81	4	of	of	ADP
iajs-1179	81	5	the	the	DET
iajs-1179	81	6	reorganization	reorganization	NOUN
iajs-1179	81	7	energies	energy	NOUN
iajs-1179	81	8	were	be	AUX
iajs-1179	81	9	unusually	unusually	ADV
iajs-1179	81	10	high	high	ADJ
iajs-1179	82	1	[	[	X
iajs-1179	82	2	0.952	0.952	NUM
iajs-1179	82	3	ev	ev	INTJ
iajs-1179	82	4	in	in	ADP
iajs-1179	82	5	acetonitrile	acetonitrile	NOUN
iajs-1179	82	6	and	and	CCONJ
iajs-1179	82	7	0.908ev	0.908ev	NOUN
iajs-1179	82	8	in	in	ADP
iajs-1179	82	9	water	water	NOUN
iajs-1179	82	10	]	]	PUNCT
iajs-1179	82	11	,	,	PUNCT
iajs-1179	82	12	which	which	PRON
iajs-1179	82	13	could	could	AUX
iajs-1179	82	14	indicate	indicate	VERB
iajs-1179	82	15	that	that	SCONJ
iajs-1179	82	16	large	large	ADJ
iajs-1179	82	17	structural	structural	ADJ
iajs-1179	82	18	rearrangements	rearrangement	NOUN
iajs-1179	82	19	are	be	AUX
iajs-1179	82	20	necessary	necessary	ADJ
iajs-1179	82	21	when	when	SCONJ
iajs-1179	82	22	v2	v2	PROPN
iajs-1179	82	23	+	+	CCONJ
iajs-1179	82	24	is	be	AUX
iajs-1179	82	25	oxidized	oxidize	VERB
iajs-1179	82	26	.	.	PUNCT
iajs-1179	83	1	the	the	DET
iajs-1179	83	2	calculation	calculation	NOUN
iajs-1179	83	3	result	result	NOUN
iajs-1179	83	4	of	of	ADP
iajs-1179	83	5	reorganization	reorganization	NOUN
iajs-1179	83	6	energies	energy	NOUN
iajs-1179	83	7	are	be	AUX
iajs-1179	83	8	fitting	fitting	ADJ
iajs-1179	83	9	with	with	ADP
iajs-1179	83	10	theoretical	theoretical	ADJ
iajs-1179	83	11	and	and	CCONJ
iajs-1179	83	12	experimental	experimental	ADJ
iajs-1179	83	13	values	value	NOUN
iajs-1179	83	14	in	in	ADP
iajs-1179	83	15	the	the	DET
iajs-1179	83	16	same	same	ADJ
iajs-1179	83	17	solution	solution	NOUN
iajs-1179	83	18	that	that	PRON
iajs-1179	83	19	is	be	AUX
iajs-1179	83	20	shown	show	VERB
iajs-1179	83	21	in	in	ADP
iajs-1179	83	22	table(5	table(5	PROPN
iajs-1179	83	23	)	)	PUNCT
iajs-1179	83	24	.	.	PUNCT
iajs-1179	84	1	table	table	NOUN
iajs-1179	84	2	(	(	PUNCT
iajs-1179	84	3	1	1	X
iajs-1179	84	4	)	)	PUNCT
iajs-1179	84	5	shows	show	VERB
iajs-1179	84	6	the	the	DET
iajs-1179	84	7	overall	overall	ADJ
iajs-1179	84	8	driving	driving	NOUN
iajs-1179	84	9	force	force	NOUN
iajs-1179	84	10	free	free	ADJ
iajs-1179	84	11	energy	energy	NOUN
iajs-1179	84	12	changes	change	NOUN
iajs-1179	84	13	,	,	PUNCT
iajs-1179	84	14	g	g	NOUN
iajs-1179	84	15	,	,	PUNCT
iajs-1179	84	16	that	that	PRON
iajs-1179	84	17	can	can	AUX
iajs-1179	84	18	be	be	AUX
iajs-1179	84	19	calculated	calculate	VERB
iajs-1179	84	20	for	for	ADP
iajs-1179	84	21	the	the	DET
iajs-1179	84	22	2	2	PROPN
iajs-1179	84	23	3)(bpyru	3)(bpyru	PROPN
iajs-1179	84	24	-mv2	-mv2	PROPN
iajs-1179	84	25	+	+	SYM
iajs-1179	84	26	solution	solution	NOUN
iajs-1179	84	27	system	system	NOUN
iajs-1179	84	28	,	,	PUNCT
iajs-1179	84	29	which	which	PRON
iajs-1179	84	30	correspond	correspond	VERB
iajs-1179	84	31	to	to	ADP
iajs-1179	84	32	the	the	DET
iajs-1179	84	33	inverted	inverted	ADJ
iajs-1179	84	34	region	region	NOUN
iajs-1179	84	35	.	.	PUNCT
iajs-1179	85	1	the	the	DET
iajs-1179	85	2	inverted	inverted	ADJ
iajs-1179	85	3	region	region	NOUN
iajs-1179	85	4	may	may	AUX
iajs-1179	85	5	be	be	AUX
iajs-1179	85	6	observed	observe	VERB
iajs-1179	85	7	when	when	SCONJ
iajs-1179	85	8	the	the	DET
iajs-1179	85	9	driving	drive	VERB
iajs-1179	85	10	force	force	NOUN
iajs-1179	85	11	for	for	ADP
iajs-1179	85	12	reaction	reaction	NOUN
iajs-1179	85	13	is	be	AUX
iajs-1179	85	14	greater	great	ADJ
iajs-1179	85	15	than	than	ADP
iajs-1179	85	16	the	the	DET
iajs-1179	85	17	reorganization	reorganization	NOUN
iajs-1179	85	18	energy	energy	NOUN
iajs-1179	85	19	,	,	PUNCT
iajs-1179	86	1			ADJ
iajs-1179	86	2	g	g	PROPN
iajs-1179	86	3	.consequently	.consequently	ADV
iajs-1179	86	4	inverted	inverted	ADJ
iajs-1179	86	5	region	region	NOUN
iajs-1179	86	6	effects	effect	NOUN
iajs-1179	86	7	are	be	AUX
iajs-1179	86	8	most	most	ADV
iajs-1179	86	9	easily	easily	ADV
iajs-1179	86	10	discerned	discern	VERB
iajs-1179	86	11	for	for	ADP
iajs-1179	86	12	those	those	DET
iajs-1179	86	13	reactions	reaction	NOUN
iajs-1179	86	14	with	with	ADP
iajs-1179	86	15	small	small	ADJ
iajs-1179	86	16	reorganizatioin	reorganizatioin	NOUN
iajs-1179	86	17	energies	energy	NOUN
iajs-1179	86	18	in	in	ADP
iajs-1179	86	19	both	both	DET
iajs-1179	86	20	solution	solution	NOUN
iajs-1179	86	21	and	and	CCONJ
iajs-1179	86	22	ibn	ibn	PROPN
iajs-1179	86	23	alhaitham	alhaitham	NOUN
iajs-1179	86	24	j.	j.	PROPN
iajs-1179	87	1	fo	fo	ADP
iajs-1179	87	2	r	r	NOUN
iajs-1179	87	3	pure	pure	ADJ
iajs-1179	87	4	&	&	CCONJ
iajs-1179	87	5	appl	appl	PROPN
iajs-1179	87	6	.	.	PUNCT
iajs-1179	88	1	sc	sc	PROPN
iajs-1179	89	1	i	i	PRON
iajs-1179	89	2	vo	vo	INTJ
iajs-1179	89	3	l.22	l.22	X
iajs-1179	89	4	(	(	PUNCT
iajs-1179	89	5	3	3	NUM
iajs-1179	89	6	)	)	PUNCT
iajs-1179	89	7	2009	2009	NUM
iajs-1179	89	8	large	large	ADJ
iajs-1179	89	9	driving	driving	NOUN
iajs-1179	89	10	force	force	NOUN
iajs-1179	89	11	,	,	PUNCT
iajs-1179	89	12	which	which	PRON
iajs-1179	89	13	is	be	AUX
iajs-1179	89	14	very	very	ADV
iajs-1179	89	15	clear	clear	ADJ
iajs-1179	89	16	from	from	ADP
iajs-1179	89	17	table	table	NOUN
iajs-1179	89	18	(	(	PUNCT
iajs-1179	89	19	1	1	NUM
iajs-1179	89	20	)	)	PUNCT
iajs-1179	89	21	.	.	PUNCT
iajs-1179	90	1	the	the	DET
iajs-1179	90	2	values	value	NOUN
iajs-1179	90	3	of	of	ADP
iajs-1179	90	4	the	the	DET
iajs-1179	90	5	driving	drive	VERB
iajs-1179	90	6	free	free	ADJ
iajs-1179	90	7	energy	energy	NOUN
iajs-1179	90	8	that	that	PRON
iajs-1179	90	9	are	be	AUX
iajs-1179	90	10	calculated	calculate	VERB
iajs-1179	90	11	theoretically	theoretically	ADV
iajs-1179	90	12	fit	fit	ADJ
iajs-1179	90	13	with	with	ADP
iajs-1179	90	14	experimental	experimental	ADJ
iajs-1179	90	15	values	value	NOUN
iajs-1179	90	16	,	,	PUNCT
iajs-1179	90	17	that	that	PRON
iajs-1179	90	18	are	be	AUX
iajs-1179	90	19	clear	clear	ADJ
iajs-1179	90	20	for	for	ADP
iajs-1179	90	21	awave	awave	NOUN
iajs-1179	90	22	length	length	NOUN
iajs-1179	90	23	460ao	460ao	NOUN
iajs-1179	90	24	,	,	PUNCT
iajs-1179	90	25	g	g	PROPN
iajs-1179	91	1	=	=	PROPN
iajs-1179	91	2	-1,7ev	-1,7ev	PROPN
iajs-1179	91	3	,	,	PUNCT
iajs-1179	91	4	1.73ev	1.73ev	NUM
iajs-1179	91	5	(	(	PUNCT
iajs-1179	91	6	1,11	1,11	NUM
iajs-1179	91	7	)	)	PUNCT
iajs-1179	91	8	.	.	PUNCT
iajs-1179	92	1	tables	table	NOUN
iajs-1179	92	2	(	(	PUNCT
iajs-1179	92	3	4	4	NUM
iajs-1179	92	4	-	-	SYM
iajs-1179	92	5	5	5	NUM
iajs-1179	92	6	)	)	PUNCT
iajs-1179	92	7	and	and	CCONJ
iajs-1179	92	8	(	(	PUNCT
iajs-1179	92	9	1	1	X
iajs-1179	92	10	)	)	PUNCT
iajs-1179	92	11	indicate	indicate	VERB
iajs-1179	92	12	that	that	PRON
iajs-1179	92	13			VERB
iajs-1179	92	14	g	g	PRON
iajs-1179	92	15	increasing	increase	VERB
iajs-1179	92	16	,	,	PUNCT
iajs-1179	92	17	the	the	DET
iajs-1179	92	18	rate	rate	NOUN
iajs-1179	92	19	of	of	ADP
iajs-1179	92	20	et	et	PROPN
iajs-1179	92	21	,	,	PUNCT
iajs-1179	92	22	k	k	PROPN
iajs-1179	92	23	decrease	decrease	NOUN
iajs-1179	92	24	with	with	ADP
iajs-1179	92	25	increasing	increase	VERB
iajs-1179	92	26	g	g	NOUN
iajs-1179	92	27	.	.	PUNCT
iajs-1179	93	1	this	this	DET
iajs-1179	93	2	view	view	NOUN
iajs-1179	93	3	is	be	AUX
iajs-1179	93	4	for	for	ADP
iajs-1179	93	5	two	two	NUM
iajs-1179	93	6	solvents	solvent	NOUN
iajs-1179	93	7	,	,	PUNCT
iajs-1179	93	8	because	because	SCONJ
iajs-1179	93	9	the	the	DET
iajs-1179	93	10	barrier	barrier	NOUN
iajs-1179	93	11	for	for	ADP
iajs-1179	93	12	et	et	NOUN
iajs-1179	93	13	increases	increase	NOUN
iajs-1179	93	14	as	as	ADV
iajs-1179	93	15	also	also	ADV
iajs-1179	93	16	in	in	ADP
iajs-1179	93	17	table(2	table(2	NOUN
iajs-1179	93	18	)	)	PUNCT
iajs-1179	93	19	.	.	PUNCT
iajs-1179	94	1	the	the	DET
iajs-1179	94	2	effect	effect	NOUN
iajs-1179	94	3	of	of	ADP
iajs-1179	94	4	decreasing	decrease	VERB
iajs-1179	94	5	ket	ket	NOUN
iajs-1179	94	6	in	in	ADP
iajs-1179	94	7	the	the	DET
iajs-1179	94	8	inverted	inverted	ADJ
iajs-1179	94	9	region	region	NOUN
iajs-1179	94	10	can	can	AUX
iajs-1179	94	11	be	be	AUX
iajs-1179	94	12	explained	explain	VERB
iajs-1179	94	13	physically	physically	ADV
iajs-1179	94	14	as	as	SCONJ
iajs-1179	94	15	follows	follow	VERB
iajs-1179	94	16	:	:	PUNCT
iajs-1179	94	17	increasing	increase	VERB
iajs-1179	94	18	the	the	DET
iajs-1179	94	19	driving	drive	VERB
iajs-1179	94	20	force	force	NOUN
iajs-1179	94	21	g	g	PROPN
iajs-1179	94	22	to	to	ADP
iajs-1179	94	23	values	value	NOUN
iajs-1179	94	24	learger	learger	NOUN
iajs-1179	94	25	than	than	ADP
iajs-1179	94	26	the	the	DET
iajs-1179	94	27	reorganization	reorganization	NOUN
iajs-1179	94	28	energy	energy	NOUN
iajs-1179	94	29			X
iajs-1179	94	30	leads	lead	VERB
iajs-1179	94	31	to	to	ADP
iajs-1179	94	32	the	the	DET
iajs-1179	94	33	increasing	increasing	NOUN
iajs-1179	94	34	of	of	ADP
iajs-1179	94	35	the	the	DET
iajs-1179	94	36	free	free	ADJ
iajs-1179	94	37	energy	energy	NOUN
iajs-1179	94	38	of	of	ADP
iajs-1179	94	39	activation	activation	NOUN
iajs-1179	94	40	g	g	PROPN
iajs-1179	94	41	‡	‡	X
iajs-1179	94	42	,	,	PUNCT
iajs-1179	94	43	i.e.	i.e.	X
iajs-1179	94	44	barrier	barrier	NOUN
iajs-1179	94	45	of	of	ADP
iajs-1179	94	46	the	the	DET
iajs-1179	94	47	reaction	reaction	NOUN
iajs-1179	94	48	.	.	PUNCT
iajs-1179	95	1	the	the	DET
iajs-1179	95	2	calculation	calculation	NOUN
iajs-1179	95	3	results	result	NOUN
iajs-1179	95	4	of	of	ADP
iajs-1179	95	5	ket	ket	NOUN
iajs-1179	95	6	fit	fit	ADJ
iajs-1179	95	7	well	well	ADV
iajs-1179	95	8	with	with	ADP
iajs-1179	95	9	the	the	DET
iajs-1179	95	10	experimental	experimental	ADJ
iajs-1179	95	11	values	value	NOUN
iajs-1179	95	12	(	(	PUNCT
iajs-1179	95	13	1,11	1,11	NOUN
iajs-1179	95	14	)	)	PUNCT
iajs-1179	95	15	.	.	PUNCT
iajs-1179	96	1	conclusion	conclusion	NOUN
iajs-1179	96	2	in	in	ADP
iajs-1179	96	3	our	our	PRON
iajs-1179	96	4	research	research	NOUN
iajs-1179	96	5	,	,	PUNCT
iajs-1179	96	6	theoretical	theoretical	ADJ
iajs-1179	96	7	studies	study	NOUN
iajs-1179	96	8	to	to	PART
iajs-1179	96	9	calculate	calculate	VERB
iajs-1179	96	10	the	the	DET
iajs-1179	96	11	rate	rate	NOUN
iajs-1179	96	12	of	of	ADP
iajs-1179	96	13	electron	electron	NOUN
iajs-1179	96	14	transfer	transfer	NOUN
iajs-1179	96	15	for	for	ADP
iajs-1179	96	16	the	the	DET
iajs-1179	96	17			PROPN
iajs-1179	96	18	22	22	NUM
iajs-1179	96	19	3	3	NUM
iajs-1179	96	20	)	)	PUNCT
iajs-1179	96	21	(	(	PUNCT
iajs-1179	96	22	mvbpyru	mvbpyru	NOUN
iajs-1179	96	23	solution	solution	NOUN
iajs-1179	96	24	molecules	molecule	NOUN
iajs-1179	96	25	system	system	NOUN
iajs-1179	96	26	in	in	ADP
iajs-1179	96	27	a	a	DET
iajs-1179	96	28	variety	variety	NOUN
iajs-1179	96	29	solvent	solvent	NOUN
iajs-1179	96	30	,	,	PUNCT
iajs-1179	96	31	are	be	AUX
iajs-1179	96	32	promoted	promote	VERB
iajs-1179	96	33	to	to	PART
iajs-1179	96	34	electronically	electronically	ADV
iajs-1179	96	35	excited	excite	VERB
iajs-1179	96	36	states	state	NOUN
iajs-1179	96	37	by	by	ADP
iajs-1179	96	38	the	the	DET
iajs-1179	96	39	absorp	absorp	PROPN
iajs-1179	96	40	tion	tion	NOUN
iajs-1179	96	41	of	of	ADP
iajs-1179	96	42	light	light	NOUN
iajs-1179	96	43	.	.	PUNCT
iajs-1179	97	1	upon	upon	SCONJ
iajs-1179	97	2	light	light	ADJ
iajs-1179	97	3	absorption	absorption	NOUN
iajs-1179	97	4	,	,	PUNCT
iajs-1179	97	5	an	an	DET
iajs-1179	97	6	electron	electron	NOUN
iajs-1179	97	7	is	be	AUX
iajs-1179	97	8	formally	formally	ADV
iajs-1179	97	9	transferred	transfer	VERB
iajs-1179	97	10	from	from	ADP
iajs-1179	97	11	the	the	DET
iajs-1179	97	12	ru(ii	ru(ii	PROPN
iajs-1179	97	13	)	)	PUNCT
iajs-1179	97	14	metal	metal	NOUN
iajs-1179	97	15	center	center	NOUN
iajs-1179	97	16	across	across	ADP
iajs-1179	97	17	one	one	NUM
iajs-1179	97	18	of	of	ADP
iajs-1179	97	19	the	the	DET
iajs-1179	97	20	bipyridine	bipyridine	NOUN
iajs-1179	97	21	ligands	ligand	NOUN
iajs-1179	97	22	to	to	ADP
iajs-1179	97	23	the	the	DET
iajs-1179	97	24	mv	mv	PROPN
iajs-1179	97	25	2	2	NUM
iajs-1179	97	26	+	+	NUM
iajs-1179	97	27	.	.	PUNCT
iajs-1179	98	1	the	the	DET
iajs-1179	98	2	reorganization	reorganization	NOUN
iajs-1179	98	3	energies	energy	NOUN
iajs-1179	98	4	are	be	AUX
iajs-1179	98	5	calculated	calculate	VERB
iajs-1179	98	6	with	with	ADP
iajs-1179	98	7	dielectric	dielectric	ADJ
iajs-1179	98	8	continuum	continuum	ADJ
iajs-1179	98	9	model	model	NOUN
iajs-1179	98	10	and	and	CCONJ
iajs-1179	98	11	are	be	AUX
iajs-1179	98	12	found~	found~	PROPN
iajs-1179	98	13	evev	evev	NOUN
iajs-1179	98	14	908.0952.0	908.0952.0	NUM
iajs-1179	98	15			PROPN
iajs-1179	98	16	for	for	ADP
iajs-1179	98	17	a	a	DET
iajs-1179	98	18	system	system	NOUN
iajs-1179	98	19	in	in	ADP
iajs-1179	98	20	water	water	NOUN
iajs-1179	98	21	and	and	CCONJ
iajs-1179	98	22	acetonitrile	acetonitrile	ADJ
iajs-1179	98	23	solution	solution	NOUN
iajs-1179	98	24	respectively	respectively	ADV
iajs-1179	98	25	.	.	PUNCT
iajs-1179	99	1	this	this	DET
iajs-1179	99	2	result	result	NOUN
iajs-1179	99	3	show	show	VERB
iajs-1179	99	4	large	large	ADJ
iajs-1179	99	5	reorganization	reorganization	NOUN
iajs-1179	99	6	energy	energy	NOUN
iajs-1179	99	7	in	in	ADP
iajs-1179	99	8	more	more	ADV
iajs-1179	99	9	polar	polar	ADJ
iajs-1179	99	10	solvent	solvent	NOUN
iajs-1179	99	11	,	,	PUNCT
iajs-1179	99	12	that	that	PRON
iajs-1179	99	13	means	mean	VERB
iajs-1179	99	14			ADJ
iajs-1179	99	15	is	be	AUX
iajs-1179	99	16	proportional	proportional	ADJ
iajs-1179	99	17	to	to	PART
iajs-1179	99	18	op/1	op/1	NOUN
iajs-1179	99	19	it	it	PRON
iajs-1179	99	20	turned	turn	VERB
iajs-1179	99	21	out	out	ADP
iajs-1179	99	22	that	that	SCONJ
iajs-1179	99	23	the	the	DET
iajs-1179	99	24	mode	mode	NOUN
iajs-1179	99	25	of	of	ADP
iajs-1179	99	26	reaction	reaction	NOUN
iajs-1179	99	27	path	path	NOUN
iajs-1179	99	28	way	way	NOUN
iajs-1179	99	29	strongly	strongly	ADV
iajs-1179	99	30	depends	depend	VERB
iajs-1179	99	31	on	on	ADP
iajs-1179	99	32	the	the	DET
iajs-1179	99	33	solvent	solvent	ADJ
iajs-1179	99	34	polarity	polarity	NOUN
iajs-1179	99	35	whereas	whereas	SCONJ
iajs-1179	99	36	et	et	PROPN
iajs-1179	99	37	is	be	AUX
iajs-1179	99	38	favored	favor	VERB
iajs-1179	99	39	in	in	ADP
iajs-1179	99	40	polar	polar	ADJ
iajs-1179	99	41	solvents	solvent	NOUN
iajs-1179	99	42	.	.	PUNCT
iajs-1179	100	1	also	also	ADV
iajs-1179	100	2	the	the	DET
iajs-1179	100	3	rate	rate	NOUN
iajs-1179	100	4	of	of	ADP
iajs-1179	100	5	et	et	NOUN
iajs-1179	100	6	for	for	ADP
iajs-1179	100	7	system	system	NOUN
iajs-1179	100	8	is	be	AUX
iajs-1179	100	9	a	a	DET
iajs-1179	100	10	function	function	NOUN
iajs-1179	100	11	of	of	ADP
iajs-1179	100	12	the	the	DET
iajs-1179	100	13	height	height	NOUN
iajs-1179	100	14	barrier	barrier	NOUN
iajs-1179	100	15	g	g	PROPN
iajs-1179	100	16	‡.	‡.	VERB
iajs-1179	100	17	when	when	SCONJ
iajs-1179	100	18	a	a	DET
iajs-1179	100	19	treated	treat	VERB
iajs-1179	100	20	quantum	quantum	NOUN
iajs-1179	100	21	mechanically	mechanically	ADV
iajs-1179	100	22	as	as	SCONJ
iajs-1179	100	23	vibrational	vibrational	ADJ
iajs-1179	100	24	wave	wave	NOUN
iajs-1179	100	25	functions	function	NOUN
iajs-1179	100	26	of	of	ADP
iajs-1179	100	27	the	the	DET
iajs-1179	100	28	reactant	reactant	NOUN
iajs-1179	100	29	nuclear	nuclear	ADJ
iajs-1179	100	30	coordinates	coordinate	NOUN
iajs-1179	100	31	to	to	PART
iajs-1179	100	32	coordinate	coordinate	VERB
iajs-1179	100	33	space	space	NOUN
iajs-1179	100	34	that	that	PRON
iajs-1179	100	35	overlaps	overlap	VERB
iajs-1179	100	36	with	with	ADP
iajs-1179	100	37	product	product	NOUN
iajs-1179	100	38	coordinates	coordinate	NOUN
iajs-1179	100	39	space	space	NOUN
iajs-1179	100	40	(	(	PUNCT
iajs-1179	100	41	also	also	ADV
iajs-1179	100	42	referred	refer	VERB
iajs-1179	100	43	to	to	ADP
iajs-1179	100	44	as	as	ADP
iajs-1179	100	45	"	"	PUNCT
iajs-1179	100	46	nuclear	nuclear	ADJ
iajs-1179	100	47	tunnellig	tunnellig	NOUN
iajs-1179	100	48	"	"	PUNCT
iajs-1179	100	49	)	)	PUNCT
iajs-1179	100	50	.	.	PUNCT
iajs-1179	101	1	the	the	DET
iajs-1179	101	2	probability	probability	NOUN
iajs-1179	101	3	to	to	PART
iajs-1179	101	4	bridge	bridge	VERB
iajs-1179	101	5	the	the	DET
iajs-1179	101	6	gab	gab	NOUN
iajs-1179	101	7	between	between	ADP
iajs-1179	101	8	the	the	DET
iajs-1179	101	9	reactant	reactant	NOUN
iajs-1179	101	10	and	and	CCONJ
iajs-1179	101	11	the	the	DET
iajs-1179	101	12	product	product	NOUN
iajs-1179	101	13	g	g	PROPN
iajs-1179	101	14	‡	‡	NOUN
iajs-1179	101	15	is	be	AUX
iajs-1179	101	16	the	the	DET
iajs-1179	101	17	largest	large	ADJ
iajs-1179	101	18	.	.	PUNCT
iajs-1179	102	1	from	from	ADP
iajs-1179	102	2	the	the	DET
iajs-1179	102	3	present	present	ADJ
iajs-1179	102	4	results	result	NOUN
iajs-1179	102	5	that	that	PRON
iajs-1179	102	6	are	be	AUX
iajs-1179	102	7	concluded	conclude	VERB
iajs-1179	102	8	,	,	PUNCT
iajs-1179	102	9	the	the	DET
iajs-1179	102	10	photo	photo	NOUN
iajs-1179	102	11	induced	induce	VERB
iajs-1179	102	12	et	et	NOUN
iajs-1179	102	13	in	in	ADP
iajs-1179	102	14			PROPN
iajs-1179	102	15	22	22	NUM
iajs-1179	102	16	3	3	NUM
iajs-1179	102	17	)	)	PUNCT
iajs-1179	102	18	(	(	PUNCT
iajs-1179	102	19	mvbpyru	mvbpyru	NOUN
iajs-1179	102	20	system	system	NOUN
iajs-1179	102	21	is	be	AUX
iajs-1179	102	22	activated	activate	VERB
iajs-1179	102	23	in	in	ADP
iajs-1179	102	24	the	the	DET
iajs-1179	102	25	inverted	inverted	ADJ
iajs-1179	102	26	region	region	NOUN
iajs-1179	102	27	.	.	PUNCT
iajs-1179	103	1	the	the	DET
iajs-1179	103	2	calculation	calculation	NOUN
iajs-1179	103	3	results	result	VERB
iajs-1179	103	4	for	for	ADP
iajs-1179	103	5	the	the	DET
iajs-1179	103	6	rate	rate	NOUN
iajs-1179	103	7	of	of	ADP
iajs-1179	103	8	et	et	NOUN
iajs-1179	103	9	in	in	ADP
iajs-1179	103	10			PROPN
iajs-1179	103	11	22	22	NUM
iajs-1179	103	12	3	3	NUM
iajs-1179	103	13	)	)	PUNCT
iajs-1179	103	14	(	(	PUNCT
iajs-1179	103	15	mvbpyru	mvbpyru	NOUN
iajs-1179	103	16	solvent	solvent	NOUN
iajs-1179	103	17	system	system	NOUN
iajs-1179	103	18	show	show	VERB
iajs-1179	103	19	a	a	DET
iajs-1179	103	20	good	good	ADJ
iajs-1179	103	21	agreement	agreement	NOUN
iajs-1179	103	22	with	with	ADP
iajs-1179	103	23	the	the	DET
iajs-1179	103	24	experimentally	experimentally	ADV
iajs-1179	103	25	observed	observe	VERB
iajs-1179	103	26	results	result	NOUN
iajs-1179	103	27	.	.	PUNCT
iajs-1179	104	1	references	reference	NOUN
iajs-1179	104	2	1	1	NUM
iajs-1179	104	3	.	.	PUNCT
iajs-1179	105	1	hammarestrom	hammarestrom	PROPN
iajs-1179	105	2	,	,	PUNCT
iajs-1179	105	3	l.	l.	PROPN
iajs-1179	105	4	(	(	PUNCT
iajs-1179	105	5	2001).labrabory	2001).labrabory	NUM
iajs-1179	105	6	experiment	experiment	NOUN
iajs-1179	105	7	for	for	ADP
iajs-1179	105	8	the	the	DET
iajs-1179	105	9	course	course	NOUN
iajs-1179	105	10	,	,	PUNCT
iajs-1179	105	11	laser	laser	NOUN
iajs-1179	105	12	spektroskopi	spektroskopi	PROPN
iajs-1179	105	13	nv	nv	PROPN
iajs-1179	105	14	1	1	NUM
iajs-1179	105	15	,	,	PUNCT
iajs-1179	105	16	dep	dep	NOUN
iajs-1179	105	17	.	.	PROPN
iajs-1179	105	18	of	of	ADP
iajs-1179	105	19	physical	physical	ADJ
iajs-1179	105	20	chemistry	chemistry	NOUN
iajs-1179	105	21	,	,	PUNCT
iajs-1179	105	22	university	university	NOUN
iajs-1179	105	23	of	of	ADP
iajs-1179	105	24	uppsala	uppsala	PROPN
iajs-1179	105	25	2	2	NUM
iajs-1179	105	26	.	.	PUNCT
iajs-1179	105	27	wachsmann	wachsmann	PROPN
iajs-1179	105	28	,	,	PUNCT
iajs-1179	105	29	h.(2001	h.(2001	PROPN
iajs-1179	105	30	)	)	PUNCT
iajs-1179	105	31	.	.	PUNCT
iajs-1179	106	1	vibronic	vibronic	NOUN
iajs-1179	106	2	coupling	coupling	NOUN
iajs-1179	106	3	and	and	CCONJ
iajs-1179	106	4	ultrafast	ultrafast	ADJ
iajs-1179	106	5	et	et	NOUN
iajs-1179	106	6	studied	study	VERB
iajs-1179	106	7	by	by	ADP
iajs-1179	106	8	picosecond	picosecond	NOUN
iajs-1179	106	9	time	time	NOUN
iajs-1179	106	10	–	–	PUNCT
iajs-1179	106	11	resolved	resolve	VERB
iajs-1179	106	12	resonance	resonance	NOUN
iajs-1179	106	13	,	,	PUNCT
iajs-1179	106	14	thesis	thesis	NOUN
iajs-1179	106	15	,	,	PUNCT
iajs-1179	106	16	ph.d	ph.d	PROPN
iajs-1179	106	17	berlin	berlin	PROPN
iajs-1179	106	18	univesity	univesity	PROPN
iajs-1179	106	19	.	.	PUNCT
iajs-1179	107	1	3.chen	3.chen	NUM
iajs-1179	107	2	,	,	PUNCT
iajs-1179	107	3	p.y.meyer	p.y.meyer	NOUN
iajs-1179	107	4	,	,	PUNCT
iajs-1179	107	5	t.(1998).j.chem.rev	t.(1998).j.chem.rev	NOUN
iajs-1179	107	6	,	,	PUNCT
iajs-1179	107	7	98,1439	98,1439	NUM
iajs-1179	107	8	.	.	PUNCT
iajs-1179	108	1	4.barbara	4.barbara	NUM
iajs-1179	108	2	,	,	PUNCT
iajs-1179	108	3	p.f.;meyer	p.f.;meyer	NOUN
iajs-1179	108	4	,	,	PUNCT
iajs-1179	108	5	t.j.and	t.j.and	PROPN
iajs-1179	108	6	ratner	ratner	NOUN
iajs-1179	108	7	,	,	PUNCT
iajs-1179	108	8	m.	m.	NOUN
iajs-1179	108	9	,(1996),j.phys.chem,100	,(1996),j.phys.chem,100	PUNCT
iajs-1179	108	10	:	:	PUNCT
iajs-1179	108	11	1348	1348	NUM
iajs-1179	108	12	.	.	PUNCT
iajs-1179	109	1	5.bixon	5.bixon	NUM
iajs-1179	109	2	,	,	PUNCT
iajs-1179	109	3	m.jortner	m.jortn	ADJ
iajs-1179	109	4	,	,	PUNCT
iajs-1179	109	5	j.(1997).j.chem.phys,107,5154	j.(1997).j.chem.phys,107,5154	NOUN
iajs-1179	109	6	6.jortner	6.jortner	NUM
iajs-1179	109	7	,	,	PUNCT
iajs-1179	109	8	j.and	j.and	PRON
iajs-1179	109	9	bixon	bixon	PROPN
iajs-1179	109	10	,	,	PUNCT
iajs-1179	109	11	m.(1999).adv.chem.phys	m.(1999).adv.chem.phy	NOUN
iajs-1179	109	12	.	.	PUNCT
iajs-1179	110	1	106:35	106:35	NUM
iajs-1179	110	2	.	.	X
iajs-1179	111	1	7.juris	7.juris	NUM
iajs-1179	111	2	,	,	PUNCT
iajs-1179	111	3	a.	a.	NOUN
iajs-1179	111	4	;	;	PUNCT
iajs-1179	111	5	balzani	balzani	PROPN
iajs-1179	111	6	,	,	PUNCT
iajs-1179	111	7	v.	v.	PROPN
iajs-1179	111	8	;	;	PUNCT
iajs-1179	111	9	bargelletti	bargelletti	PROPN
iajs-1179	111	10	,	,	PUNCT
iajs-1179	111	11	f.	f.	PROPN
iajs-1179	111	12	;	;	PUNCT
iajs-1179	111	13	canpagna	canpagna	PROPN
iajs-1179	111	14	,	,	PUNCT
iajs-1179	111	15	s.	s.	PROPN
iajs-1179	111	16	and	and	CCONJ
iajs-1179	111	17	belser	belser	PROPN
iajs-1179	111	18	,	,	PUNCT
iajs-1179	111	19	p.	p.	NOUN
iajs-1179	111	20	(	(	PUNCT
iajs-1179	111	21	1988	1988	NUM
iajs-1179	111	22	)	)	PUNCT
iajs-1179	111	23	.	.	PUNCT
iajs-1179	112	1	vonzelewsky	vonzelewsky	ADJ
iajs-1179	112	2	,	,	PUNCT
iajs-1179	112	3	apl.coord	apl.coord	PRON
iajs-1179	112	4	chem	chem	NOUN
iajs-1179	112	5	.	.	PUNCT
iajs-1179	113	1	rev	rev	PROPN
iajs-1179	113	2	.	.	PROPN
iajs-1179	113	3	84,85	84,85	NUM
iajs-1179	113	4	.	.	PUNCT
iajs-1179	114	1	8	8	NUM
iajs-1179	114	2	.	.	X
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iajs-1179	114	4	,	,	PUNCT
iajs-1179	114	5	k.(1992	k.(1992	PROPN
iajs-1179	114	6	)	)	PUNCT
iajs-1179	114	7	.	.	PUNCT
iajs-1179	115	1	book	book	NOUN
iajs-1179	115	2	,	,	PUNCT
iajs-1179	115	3	academics	academic	NOUN
iajs-1179	115	4	press	press	PROPN
iajs-1179	115	5	london	london	PROPN
iajs-1179	115	6	.	.	PUNCT
iajs-1179	116	1	ibn	ibn	PROPN
iajs-1179	116	2	alhaitham	alhaitham	PROPN
iajs-1179	117	1	j.	j.	PROPN
iajs-1179	118	1	fo	fo	ADP
iajs-1179	118	2	r	r	NOUN
iajs-1179	118	3	pure	pure	ADJ
iajs-1179	118	4	&	&	CCONJ
iajs-1179	118	5	appl	appl	PROPN
iajs-1179	118	6	.	.	PUNCT
iajs-1179	119	1	sc	sc	PROPN
iajs-1179	120	1	i	i	PRON
iajs-1179	120	2	vo	vo	INTJ
iajs-1179	120	3	l.22	l.22	X
iajs-1179	120	4	(	(	PUNCT
iajs-1179	120	5	3	3	NUM
iajs-1179	120	6	)	)	PUNCT
iajs-1179	120	7	2009	2009	NUM
iajs-1179	120	8	9	9	NUM
iajs-1179	120	9	.	.	X
iajs-1179	120	10	de	de	X
iajs-1179	120	11	armond	armond	PROPN
iajs-1179	120	12	,	,	PUNCT
iajs-1179	120	13	m.k	m.k	PROPN
iajs-1179	120	14	.	.	PROPN
iajs-1179	120	15	and	and	CCONJ
iajs-1179	120	16	myrich	myrich	PROPN
iajs-1179	120	17	,	,	PUNCT
iajs-1179	120	18	m.l.(1989	m.l.(1989	PROPN
iajs-1179	120	19	)	)	PUNCT
iajs-1179	120	20	.	.	PUNCT
iajs-1179	121	1	22:364	22:364	NUM
iajs-1179	121	2	.	.	X
iajs-1179	122	1	10	10	NUM
iajs-1179	122	2	.	.	PUNCT
iajs-1179	123	1	meyer	meyer	PROPN
iajs-1179	123	2	,	,	PUNCT
iajs-1179	123	3	t.j.(1986	t.j.(1986	PROPN
iajs-1179	123	4	)	)	PUNCT
iajs-1179	123	5	.	.	PUNCT
iajs-1179	124	1	pure	pure	ADJ
iajs-1179	124	2	and	and	CCONJ
iajs-1179	124	3	appl	appl	ADJ
iajs-1179	124	4	.	.	PUNCT
iajs-1179	124	5	chem	chem	PROPN
iajs-1179	124	6	.	.	PUNCT
iajs-1179	125	1	58:1193	58:1193	X
iajs-1179	125	2	.	.	X
iajs-1179	126	1	11	11	NUM
iajs-1179	126	2	.	.	X
iajs-1179	127	1	helena	helena	PROPN
iajs-1179	127	2	,	,	PUNCT
iajs-1179	127	3	b.(2001),electvon	b.(2001),electvon	NOUN
iajs-1179	127	4	and	and	CCONJ
iajs-1179	127	5	energy	energy	NOUN
iajs-1179	127	6	transfer	transfer	NOUN
iajs-1179	127	7	in	in	ADP
iajs-1179	127	8	supamolecular	supamolecular	ADJ
iajs-1179	127	9	complexes	complex	NOUN
iajs-1179	127	10	designed	design	VERB
iajs-1179	127	11	for	for	ADP
iajs-1179	127	12	arficial	arficial	ADJ
iajs-1179	127	13	photosynthesis	photosynthesis	NOUN
iajs-1179	127	14	thesis	thesis	NOUN
iajs-1179	127	15	,	,	PUNCT
iajs-1179	127	16	acta	acta	PROPN
iajs-1179	127	17	university	university	PROPN
iajs-1179	127	18	,	,	PUNCT
iajs-1179	127	19	upsalla	upsalla	PROPN
iajs-1179	127	20	.	.	PUNCT
iajs-1179	128	1	12	12	NUM
iajs-1179	128	2	.	.	PUNCT
iajs-1179	129	1	jortner	jortner	PROPN
iajs-1179	129	2	,	,	PUNCT
iajs-1179	129	3	j.(1976).j.chem.phys.64,4860	j.(1976).j.chem.phys.64,4860	PROPN
iajs-1179	129	4	.	.	PUNCT
iajs-1179	130	1	13.marcus	13.marcus	NUM
iajs-1179	130	2	,	,	PUNCT
iajs-1179	130	3	r.a.and	r.a.and	PROPN
iajs-1179	130	4	sutin	sutin	PROPN
iajs-1179	130	5	,	,	PUNCT
iajs-1179	130	6	n.(1985).biochim.biophys.acta	n.(1985).biochim.biophys.acta	PROPN
iajs-1179	130	7	.	.	PUNCT
iajs-1179	131	1	14	14	NUM
iajs-1179	131	2	.	.	PUNCT
iajs-1179	132	1	hadi	hadi	PROPN
iajs-1179	132	2	,	,	PUNCT
iajs-1179	132	3	j.m.(2004	j.m.(2004	PROPN
iajs-1179	132	4	)	)	PUNCT
iajs-1179	132	5	.	.	PUNCT
iajs-1179	133	1	thesis	thesis	NOUN
iajs-1179	133	2	,	,	PUNCT
iajs-1179	133	3	ph.d	ph.d	PROPN
iajs-1179	133	4	.	.	PUNCT
iajs-1179	133	5	quantum	quantum	PROPN
iajs-1179	133	6	mechanical	mechanical	ADJ
iajs-1179	133	7	model	model	NOUN
iajs-1179	133	8	for	for	ADP
iajs-1179	133	9	electron	electron	NOUN
iajs-1179	133	10	transfer	transfer	NOUN
iajs-1179	133	11	-	-	PUNCT
iajs-1179	133	12	swiched	swiche	VERB
iajs-1179	133	13	dye	dye	NOUN
iajs-1179	133	14	using	use	VERB
iajs-1179	133	15	in	in	ADP
iajs-1179	133	16	solid	solid	ADJ
iajs-1179	133	17	state	state	NOUN
iajs-1179	133	18	laser	laser	NOUN
iajs-1179	133	19	,	,	PUNCT
iajs-1179	133	20	baghdad	baghdad	PROPN
iajs-1179	133	21	university	university	PROPN
iajs-1179	133	22	.	.	PUNCT
iajs-1179	134	1	15.brunschwig	15.brunschwig	NUM
iajs-1179	134	2	,	,	PUNCT
iajs-1179	134	3	b.s.;ehrensons	b.s.;ehrenson	NOUN
iajs-1179	134	4	,	,	PUNCT
iajs-1179	134	5	s.and	s.and	PROPN
iajs-1179	134	6	sutin	sutin	PROPN
iajs-1179	134	7	,	,	PUNCT
iajs-1179	134	8	n.(1986	n.(1986	PROPN
iajs-1179	134	9	)	)	PUNCT
iajs-1179	134	10	.	.	PUNCT
iajs-1179	135	1	j.phys.chem,90:3657	j.phys.chem,90:3657	PROPN
iajs-1179	135	2	.	.	PUNCT
iajs-1179	136	1	16	16	NUM
iajs-1179	136	2	.	.	PUNCT
iajs-1179	137	1	mikael	mikael	PROPN
iajs-1179	137	2	,	,	PUNCT
iajs-1179	137	3	a.(2000	a.(2000	PROPN
iajs-1179	137	4	)	)	PUNCT
iajs-1179	137	5	.	.	PUNCT
iajs-1179	138	1	thesis	thesis	NOUN
iajs-1179	138	2	,	,	PUNCT
iajs-1179	138	3	ph.d.tuning	ph.d.tune	VERB
iajs-1179	138	4	electron	electron	NOUN
iajs-1179	138	5	transfer	transfer	NOUN
iajs-1179	138	6	reaction	reaction	NOUN
iajs-1179	138	7	by	by	ADP
iajs-1179	138	8	selectivo	selectivo	ADJ
iajs-1179	138	9	excitation	excitation	NOUN
iajs-1179	138	10	in	in	ADP
iajs-1179	138	11	porphyrine	porphyrine	PROPN
iajs-1179	138	12	accee	accee	PROPN
iajs-1179	138	13	ptor	ptor	PROPN
iajs-1179	138	14	assemblies	assembly	NOUN
iajs-1179	138	15	,	,	PUNCT
iajs-1179	138	16	acta	acta	PROPN
iajs-1179	138	17	university	university	PROPN
iajs-1179	138	18	,	,	PUNCT
iajs-1179	138	19	upsala	upsala	PROPN
iajs-1179	138	20	.	.	PUNCT
iajs-1179	138	21	17.glaudi.t.j.;jeffrey	17.glaudi.t.j.;jeffrey	NUM
iajs-1179	138	22	,	,	PUNCT
iajs-1179	138	23	m.z.;yanna	m.z.;yanna	NOUN
iajs-1179	138	24	,	,	PUNCT
iajs-1179	138	25	m.k.and	m.k.and	PROPN
iajs-1179	138	26	daniel	daniel	PROPN
iajs-1179	138	27	,	,	PUNCT
iajs-1179	138	28	g.(1996).j.am.soc	g.(1996).j.am.soc	PROPN
iajs-1179	138	29	.	.	PUNCT
iajs-1179	138	30	118	118	NUM
iajs-1179	138	31	:	:	PUNCT
iajs-1179	138	32	6060	6060	NUM
iajs-1179	138	33	-	-	SYM
iajs-1179	138	34	6062	6062	NUM
iajs-1179	138	35	.	.	PUNCT
iajs-1179	139	1	18	18	NUM
iajs-1179	139	2	.	.	PUNCT
iajs-1179	139	3	kucnuskas	kucnuskas	PROPN
iajs-1179	139	4	,	,	PUNCT
iajs-1179	139	5	et.al	et.al	PROPN
iajs-1179	139	6	,	,	PUNCT
iajs-1179	139	7	(	(	PUNCT
iajs-1179	139	8	2001	2001	NUM
iajs-1179	139	9	)	)	PUNCT
iajs-1179	139	10	.	.	PUNCT
iajs-1179	140	1	j.phys	j.phy	NOUN
iajs-1179	140	2	.	.	PUNCT
iajs-1179	140	3	chem	chem	PROPN
iajs-1179	140	4	.	.	PUNCT
iajs-1179	141	1	b.	b.	PROPN
iajs-1179	142	1	105(2	105(2	NUM
iajs-1179	142	2	):	):	PUNCT
iajs-1179	142	3	400	400	NUM
iajs-1179	142	4	.	.	PUNCT
iajs-1179	143	1	19.chen	19.chen	ADV
iajs-1179	143	2	,	,	PUNCT
iajs-1179	143	3	p.and	p.and	PROPN
iajs-1179	143	4	meyer	meyer	PROPN
iajs-1179	143	5	,	,	PUNCT
iajs-1179	143	6	t.j.(1996).inoeg.chem	t.j.(1996).inoeg.chem	PRON
iajs-1179	143	7	.	.	PUNCT
iajs-1179	144	1	35:5520	35:5520	NUM
iajs-1179	144	2	.	.	PUNCT
iajs-1179	144	3	table	table	NOUN
iajs-1179	144	4	(	(	PUNCT
iajs-1179	144	5	1):the	1):the	DET
iajs-1179	144	6	free	free	ADJ
iajs-1179	144	7	energy	energy	NOUN
iajs-1179	144	8	)	)	PUNCT
iajs-1179	144	9	(	(	PUNCT
iajs-1179	144	10	evg	evg	NOUN
iajs-1179	144	11	for	for	ADP
iajs-1179	144	12	acceptor	acceptor	NOUN
iajs-1179	144	13	mv	mv	PROPN
iajs-1179	144	14	2	2	NUM
iajs-1179	144	15	+	+	CCONJ
iajs-1179	144	16	and	and	CCONJ
iajs-1179	144	17	donor	donor	VERB
iajs-1179	144	18	2	2	PROPN
iajs-1179	144	19	3)(bpyru	3)(bpyru	PROPN
iajs-1179	144	20	wave	wave	NOUN
iajs-1179	144	21	length	length	NOUN
iajs-1179	144	22	(	(	PUNCT
iajs-1179	144	23	nm	nm	NOUN
iajs-1179	144	24	)	)	PUNCT
iajs-1179	144	25	evg	evg	PROPN
iajs-1179	144	26	water	water	PROPN
iajs-1179	144	27	evg	evg	PROPN
iajs-1179	144	28	acet.	acet.	PROPN
iajs-1179	144	29	300	300	NUM
iajs-1179	144	30	-3.173	-3.173	NUM
iajs-1179	144	31	-3.216	-3.216	NUM
iajs-1179	144	32	320	320	NUM
iajs-1179	144	33	-2.915	-2.915	X
iajs-1179	144	34	-2.958	-2.958	SYM
iajs-1179	144	35	340	340	NUM
iajs-1179	144	36	-2.687	-2.687	NOUN
iajs-1179	144	37	-2.737	-2.737	NUM
iajs-1179	144	38	360	360	NUM
iajs-1179	144	39	-2.485	-2.485	NOUN
iajs-1179	144	40	-2.528	-2.528	SYM
iajs-1179	144	41	380	380	NUM
iajs-1179	144	42	-2.304	-2.304	PRON
iajs-1179	144	43	-2.347	-2.347	ADJ
iajs-1179	144	44	400	400	NUM
iajs-1179	144	45	-2.141	-2.141	NUM
iajs-1179	144	46	-2.185	-2.185	NUM
iajs-1179	144	47	420	420	NUM
iajs-1179	144	48	-1.994	-1.994	SYM
iajs-1179	144	49	-2.537	-2.537	X
iajs-1179	144	50	440	440	NUM
iajs-1179	144	51	-1.860	-1.860	X
iajs-1179	144	52	-1.903	-1.903	NUM
iajs-1179	144	53	460	460	NUM
iajs-1179	144	54	-1.737	-1.737	NUM
iajs-1179	144	55	-1.781	-1.781	NUM
iajs-1179	144	56	480	480	NUM
iajs-1179	144	57	-1625	-1625	NOUN
iajs-1179	144	58	-1.669	-1.669	PUNCT
iajs-1179	144	59	500	500	NUM
iajs-1179	144	60	-1.522	-1.522	NOUN
iajs-1179	144	61	-1.566	-1.566	NOUN
iajs-1179	144	62	520	520	NUM
iajs-1179	144	63	-1.427	-1.427	NUM
iajs-1179	144	64	-1.471	-1.471	NUM
iajs-1179	144	65	540	540	NUM
iajs-1179	144	66	-1.339	-1.339	NUM
iajs-1179	144	67	-1.382	-1.382	PUNCT
iajs-1179	144	68	560	560	NUM
iajs-1179	144	69	-1.257	-1.257	NOUN
iajs-1179	144	70	-1.301	-1.301	NUM
iajs-1179	145	1	580	580	NUM
iajs-1179	145	2	-1.181	-1.181	NUM
iajs-1179	145	3	-1.224	-1.224	NUM
iajs-1179	145	4	600	600	NUM
iajs-1179	145	5	-1.110	-1.110	NOUN
iajs-1179	145	6	-1.153	-1.153	NOUN
iajs-1179	145	7	ibn	ibn	PROPN
iajs-1179	145	8	alhaitham	alhaitham	NOUN
iajs-1179	145	9	j.	j.	PROPN
iajs-1179	146	1	fo	fo	ADP
iajs-1179	146	2	r	r	NOUN
iajs-1179	146	3	pure	pure	ADJ
iajs-1179	146	4	&	&	CCONJ
iajs-1179	146	5	appl	appl	PROPN
iajs-1179	146	6	.	.	PUNCT
iajs-1179	147	1	sc	sc	PROPN
iajs-1179	148	1	i	i	PRON
iajs-1179	148	2	vo	vo	INTJ
iajs-1179	148	3	l.22	l.22	X
iajs-1179	148	4	(	(	PUNCT
iajs-1179	148	5	3	3	NUM
iajs-1179	148	6	)	)	PUNCT
iajs-1179	148	7	2009	2009	NUM
iajs-1179	148	8	table	table	NOUN
iajs-1179	148	9	(	(	PUNCT
iajs-1179	148	10	2):the	2):the	DET
iajs-1179	148	11	activation	activation	NOUN
iajs-1179	148	12	free	free	ADJ
iajs-1179	148	13	energy	energy	NOUN
iajs-1179	148	14	g	g	PROPN
iajs-1179	148	15	‡	‡	X
iajs-1179	148	16	)	)	PUNCT
iajs-1179	148	17	(	(	PUNCT
iajs-1179	148	18	ev	ev	INTJ
iajs-1179	148	19	for	for	ADP
iajs-1179	148	20	acceptor	acceptor	NOUN
iajs-1179	148	21	mv	mv	PROPN
iajs-1179	148	22	2	2	NUM
iajs-1179	148	23	+	+	CCONJ
iajs-1179	148	24	and	and	CCONJ
iajs-1179	148	25	donor	donor	VERB
iajs-1179	148	26	2	2	PROPN
iajs-1179	148	27	3)(bpyru	3)(bpyru	PROPN
iajs-1179	148	28	wave	wave	NOUN
iajs-1179	148	29	length	length	NOUN
iajs-1179	148	30			NOUN
iajs-1179	148	31	nm	nm	ADP
iajs-1179	148	32	g	g	ADJ
iajs-1179	148	33	‡	‡	PART
iajs-1179	148	34	evwater	evwater	PROPN
iajs-1179	148	35	g	g	PROPN
iajs-1179	148	36	‡	‡	PUNCT
iajs-1179	148	37	evacet	evacet	PROPN
iajs-1179	148	38	.	.	PUNCT
iajs-1179	149	1	300	300	NUM
iajs-1179	149	2	1.294	1.294	NUM
iajs-1179	149	3	1.345	1.345	NUM
iajs-1179	149	4	320	320	NUM
iajs-1179	149	5	1.010	1.010	NUM
iajs-1179	149	6	1.056	1.056	NUM
iajs-1179	149	7	340	340	NUM
iajs-1179	149	8	0.790	0.790	NUM
iajs-1179	149	9	0.830	0.830	NUM
iajs-1179	149	10	360	360	NUM
iajs-1179	149	11	0.616	0.616	NUM
iajs-1179	149	12	0.652	0.652	NUM
iajs-1179	149	13	380	380	NUM
iajs-1179	149	14	0.479	0.479	NUM
iajs-1179	149	15	0.511	0.511	NUM
iajs-1179	149	16	400	400	NUM
iajs-1179	149	17	0.371	0.371	NUM
iajs-1179	149	18	0.398	0.398	NUM
iajs-1179	149	19	420	420	NUM
iajs-1179	149	20	0.284	0.284	NUM
iajs-1179	149	21	0.309	0.309	NUM
iajs-1179	149	22	440	440	NUM
iajs-1179	149	23	0.216	0.216	NUM
iajs-1179	149	24	0.237	0.237	NUM
iajs-1179	149	25	460	460	NUM
iajs-1179	149	26	0.162	0.162	NUM
iajs-1179	149	27	0.180	0.180	NUM
iajs-1179	149	28	480	480	NUM
iajs-1179	149	29	0.119	0.119	NUM
iajs-1179	149	30	0.135	0.135	NUM
iajs-1179	149	31	500	500	NUM
iajs-1179	149	32	0.085	0.085	NUM
iajs-1179	149	33	0.098	0.098	NUM
iajs-1179	149	34	520	520	NUM
iajs-1179	149	35	0.059	0.059	NUM
iajs-1179	149	36	0.070	0.070	NUM
iajs-1179	149	37	540	540	NUM
iajs-1179	149	38	0.039	0.039	NUM
iajs-1179	149	39	0.048	0.048	NUM
iajs-1179	149	40	560	560	NUM
iajs-1179	149	41	0.024	0.024	NUM
iajs-1179	149	42	0.031	0.031	NUM
iajs-1179	149	43	580	580	NUM
iajs-1179	149	44	0.013	0.013	NUM
iajs-1179	149	45	0.019	0.019	NUM
iajs-1179	149	46	600	600	NUM
iajs-1179	149	47	0.006	0.006	NUM
iajs-1179	149	48	0.010	0.010	NUM
iajs-1179	149	49	table(3	table(3	NOUN
iajs-1179	149	50	):	):	PUNCT
iajs-1179	149	51	rate	rate	NOUN
iajs-1179	149	52	of	of	ADP
iajs-1179	149	53	et	et	NOUN
iajs-1179	149	54	between	between	ADP
iajs-1179	149	55	2	2	PROPN
iajs-1179	149	56	3)(bpyru	3)(bpyru	PROPN
iajs-1179	149	57	and	and	CCONJ
iajs-1179	149	58	mv	mv	PROPN
iajs-1179	149	59	2	2	NUM
iajs-1179	149	60	+	+	CCONJ
iajs-1179	149	61	in	in	ADP
iajs-1179	149	62	water	water	NOUN
iajs-1179	149	63	solvent	solvent	NOUN
iajs-1179	149	64	for	for	ADP
iajs-1179	149	65	different	different	ADJ
iajs-1179	149	66	vda	vda	NOUN
iajs-1179	149	67	wave	wave	NOUN
iajs-1179	149	68	length	length	NOUN
iajs-1179	149	69			NOUN
iajs-1179	149	70	nm	nm	NUM
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iajs-1179	149	72	-1	-1	PUNCT
iajs-1179	150	1	vda=0.02	vda=0.02	ADP
iajs-1179	150	2	ev	ev	INTJ
iajs-1179	150	3	vda=0.03ev	vda=0.03ev	NOUN
iajs-1179	151	1	vda=0.01	vda=0.01	NOUN
iajs-1179	151	2	ev	ev	ADP
iajs-1179	151	3	300	300	NUM
iajs-1179	151	4	2.285x10	2.285x10	NUM
iajs-1179	151	5	-	-	SYM
iajs-1179	151	6	8	8	NUM
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iajs-1179	151	8	x10	x10	NOUN
iajs-1179	151	9	-	-	SYM
iajs-1179	151	10	10	10	NUM
iajs-1179	151	11	5.712	5.712	NUM
iajs-1179	151	12	x10	x10	NOUN
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iajs-1179	151	19	3	3	NUM
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iajs-1179	151	21	x10	x10	NOUN
iajs-1179	151	22	-	-	SYM
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iajs-1179	151	24	4.785	4.785	NUM
iajs-1179	151	25	x10	x10	NOUN
iajs-1179	151	26	-	-	SYM
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iajs-1179	151	43	620413.060	620413.060	NUM
iajs-1179	151	44	420	420	NUM
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iajs-1179	151	46	176241423.9	176241423.9	NUM
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iajs-1179	151	49	1.21308x1011	1.21308x1011	NUM
iajs-1179	151	50	2729448305	2729448305	NUM
iajs-1179	151	51	303272033.9	303272033.9	NUM
iajs-1179	151	52	460	460	NUM
iajs-1179	151	53	1.068855	1.068855	NUM
iajs-1179	151	54	x10	x10	ADP
iajs-1179	151	55	12	12	NUM
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iajs-1179	153	1	x1010	x1010	NUM
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iajs-1179	153	4	x1013	x1013	PUNCT
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iajs-1179	154	5	520	520	NUM
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iajs-1179	154	7	x1013	x1013	NUM
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iajs-1179	154	9	x1012	x1012	PROPN
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iajs-1179	154	11	x1011	x1011	PROPN
iajs-1179	155	1	540	540	NUM
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iajs-1179	155	3	x10	x10	ADP
iajs-1179	155	4	14	14	NUM
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iajs-1179	155	6	x10	x10	NOUN
iajs-1179	155	7	12	12	NUM
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iajs-1179	155	9	x10	x10	ADP
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iajs-1179	157	5	x1014	x1014	PROPN
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iajs-1179	158	1	x1012	x1012	PROPN
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iajs-1179	160	2	r	r	NOUN
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iajs-1179	160	4	&	&	CCONJ
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iajs-1179	161	1	sc	sc	PROPN
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iajs-1179	162	10	4	4	NUM
iajs-1179	162	11	):	):	PUNCT
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iajs-1179	162	14	et	et	NOUN
iajs-1179	162	15	between	between	ADP
iajs-1179	162	16	2	2	PROPN
iajs-1179	162	17	3)(bpyru	3)(bpyru	PROPN
iajs-1179	162	18	and	and	CCONJ
iajs-1179	162	19	mv2	mv2	PROPN
iajs-1179	162	20	+	+	X
iajs-1179	162	21	in	in	ADP
iajs-1179	162	22	acetonitrile	acetonitrile	ADJ
iajs-1179	162	23	solution	solution	NOUN
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iajs-1179	162	25	ch3cn	ch3cn	NOUN
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iajs-1179	162	27	wave	wave	NOUN
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iajs-1179	162	35	vda=0.03ev	vda=0.03ev	PROPN
iajs-1179	162	36	vda=0.01ev	vda=0.01ev	X
iajs-1179	163	1	300	300	NUM
iajs-1179	163	2	3.0020x10	3.0020x10	NUM
iajs-1179	163	3	-9	-9	NUM
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iajs-1179	163	5	x10	x10	NOUN
iajs-1179	163	6	-11	-11	NUM
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iajs-1179	163	9	-12	-12	NUM
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iajs-1179	163	13	-4	-4	PROPN
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iajs-1179	164	3	x10	x10	NOUN
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iajs-1179	166	5	-	-	SYM
iajs-1179	166	6	3	3	NUM
iajs-1179	166	7	360	360	NUM
iajs-1179	166	8	3301.100	3301.100	NUM
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iajs-1179	166	15	400	400	NUM
iajs-1179	166	16	837017.730	837017.730	NUM
iajs-1179	166	17	1883289.894	1883289.894	NUM
iajs-1179	166	18	209254.432	209254.432	NUM
iajs-1179	166	19	420	420	NUM
iajs-1179	166	20	3022181989	3022181989	NUM
iajs-1179	166	21	67999094.64	67999094.64	NUM
iajs-1179	166	22	7555454.96	7555454.96	NUM
iajs-1179	166	23	440	440	NUM
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iajs-1179	166	32	x1010	x1010	PROPN
iajs-1179	166	33	1304665511	1304665511	NUM
iajs-1179	166	34	480	480	NUM
iajs-1179	166	35	3.2207	3.2207	NUM
iajs-1179	166	36	x10	x10	ADP
iajs-1179	166	37	12	12	NUM
iajs-1179	166	38	7.2466	7.2466	NUM
iajs-1179	166	39	x10	x10	ADP
iajs-1179	166	40	10	10	NUM
iajs-1179	166	41	8051873912	8051873912	NUM
iajs-1179	166	42	500	500	NUM
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iajs-1179	166	44	x1013	x1013	NOUN
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iajs-1179	166	46	x1011	x1011	PROPN
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iajs-1179	166	52	9.5059	9.5059	NUM
iajs-1179	166	53	x1012	x1012	PROPN
iajs-1179	166	54	1.0562	1.0562	NUM
iajs-1179	166	55	x1011	x1011	PROPN
iajs-1179	167	1	540	540	NUM
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iajs-1179	167	3	x1014	x1014	PROPN
iajs-1179	167	4	2.2890	2.2890	NUM
iajs-1179	167	5	x1012	x1012	PROPN
iajs-1179	167	6	2.5433	2.5433	NUM
iajs-1179	167	7	x1011	x1011	PROPN
iajs-1179	167	8	560	560	NUM
iajs-1179	167	9	1.9879	1.9879	NUM
iajs-1179	167	10	x10	x10	NUM
iajs-1179	167	11	14	14	NUM
iajs-1179	167	12	4.4728	4.4728	NUM
iajs-1179	167	13	x10	x10	ADP
iajs-1179	167	14	12	12	NUM
iajs-1179	167	15	4.9697x10	4.9697x10	NUM
iajs-1179	167	16	11	11	NUM
iajs-1179	167	17	580	580	NUM
iajs-1179	167	18	3.2685	3.2685	NUM
iajs-1179	167	19	x1014	x1014	PROPN
iajs-1179	167	20	7.3543	7.3543	NUM
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iajs-1179	168	4	x1013	x1013	NUM
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iajs-1179	168	6	x1012	x1012	NOUN
iajs-1179	168	7	table(5):our	table(5):our	NUM
iajs-1179	168	8	result	result	NOUN
iajs-1179	168	9	for	for	ADP
iajs-1179	168	10	reorganization	reorganization	NOUN
iajs-1179	168	11	energies	energy	NOUN
iajs-1179	168	12	compared	compare	VERB
iajs-1179	168	13	with	with	ADP
iajs-1179	168	14	theoretical	theoretical	ADJ
iajs-1179	168	15	and	and	CCONJ
iajs-1179	168	16	experimental	experimental	ADJ
iajs-1179	168	17	values	value	NOUN
iajs-1179	168	18	solvent	solvent	VERB
iajs-1179	168	19	our	our	PRON
iajs-1179	168	20	result	result	NOUN
iajs-1179	168	21			NOUN
iajs-1179	168	22	ev	ev	PUNCT
iajs-1179	168	23	experimental	experimental	ADJ
iajs-1179	168	24			NOUN
iajs-1179	168	25	ev	ev	ADP
iajs-1179	168	26	theoretical	theoretical	ADJ
iajs-1179	168	27			NOUN
iajs-1179	168	28	ev	ev	X
iajs-1179	168	29	water	water	NOUN
iajs-1179	168	30	(	(	PUNCT
iajs-1179	168	31	h2o	h2o	PROPN
iajs-1179	168	32	)	)	PUNCT
iajs-1179	168	33	o.952	o.952	NOUN
iajs-1179	168	34	1.00(11	1.00(11	NUM
iajs-1179	168	35	)	)	PUNCT
iajs-1179	168	36	1(16	1(16	NUM
iajs-1179	168	37	)	)	PUNCT
iajs-1179	168	38	acetonitrile	acetonitrile	NOUN
iajs-1179	168	39	0.908	0.908	NUM
iajs-1179	168	40	~1.0[11	~1.0[11	NUM
iajs-1179	168	41	]	]	PUNCT