id sid tid token lemma pos iajs-152 1 1 microsoft microsoft PROPN iajs-152 1 2 word word NOUN iajs-152 1 3 187 187 NUM iajs-152 1 4 - - SYM iajs-152 1 5 203 203 NUM iajs-152 1 6 187 187 NUM iajs-152 1 7 | | NOUN iajs-152 1 8 chemistry chemistry NOUN iajs-152 1 9 2015 2015 NUM iajs-152 1 10 ) ) PUNCT iajs-152 1 11 عام عام ADP iajs-152 1 12 3العدد 3العدد NUM iajs-152 1 13 ( ( PUNCT iajs-152 1 14 28مجلة 28مجلة X iajs-152 1 15 إبن إبن VERB iajs-152 1 16 الھيثم الھيثم NOUN iajs-152 1 17 للعلوم للعلوم NOUN iajs-152 1 18 الصرفة الصرفة NOUN iajs-152 2 1 و و PRON iajs-152 2 2 التطبيقية التطبيقية ADV iajs-152 2 3 المجلد المجلد VERB iajs-152 2 4 ibn ibn PROPN iajs-152 2 5 al al PROPN iajs-152 2 6 - - PUNCT iajs-152 2 7 haitham haitham PROPN iajs-152 2 8 jour jour X iajs-152 2 9 . . PROPN iajs-152 3 1 for for ADP iajs-152 3 2 pure pure ADJ iajs-152 3 3 & & CCONJ iajs-152 3 4 appl appl PROPN iajs-152 3 5 . . PUNCT iajs-152 4 1 sci sci PROPN iajs-152 4 2 . . PUNCT iajs-152 4 3 vol vol NOUN iajs-152 4 4 . . PROPN iajs-152 5 1 28 28 NUM iajs-152 5 2 ( ( PUNCT iajs-152 5 3 3 3 NUM iajs-152 5 4 ) ) SYM iajs-152 5 5 2015 2015 NUM iajs-152 5 6 synthesis synthesis NOUN iajs-152 5 7 and and CCONJ iajs-152 5 8 characterization characterization NOUN iajs-152 5 9 of of ADP iajs-152 5 10 some some DET iajs-152 5 11 mixed mixed ADJ iajs-152 5 12 - - PUNCT iajs-152 5 13 ligand ligand NOUN iajs-152 5 14 complexes complex NOUN iajs-152 5 15 containing contain VERB iajs-152 5 16 azo azo NOUN iajs-152 5 17 dye dye NOUN iajs-152 5 18 and and CCONJ iajs-152 5 19 1,10 1,10 NUM iajs-152 5 20 - - NUM iajs-152 5 21 phenanthroline phenanthroline NOUN iajs-152 5 22 with with ADP iajs-152 5 23 coii coii PROPN iajs-152 5 24 , , PUNCT iajs-152 5 25 znii znii NOUN iajs-152 5 26 , , PUNCT iajs-152 5 27 cdii cdii NOUN iajs-152 5 28 and and CCONJ iajs-152 5 29 hgii hgii NOUN iajs-152 5 30 ions ion NOUN iajs-152 5 31 hasan hasan PROPN iajs-152 5 32 a. a. PROPN iajs-152 5 33 hasan hasan PROPN iajs-152 5 34 wasan wasan PROPN iajs-152 5 35 m. m. PROPN iajs-152 5 36 alwan alwan PROPN iajs-152 5 37 riyadh riyadh PROPN iajs-152 5 38 m. m. PROPN iajs-152 5 39 ahmed ahmed PROPN iajs-152 5 40 enaam enaam PROPN iajs-152 5 41 i.yousif i.yousif ADP iajs-152 5 42 dept dept PROPN iajs-152 5 43 . . PUNCT iajs-152 6 1 of of ADP iajs-152 6 2 chemistry/ chemistry/ NUM iajs-152 6 3 college college NOUN iajs-152 6 4 of of ADP iajs-152 6 5 education education NOUN iajs-152 6 6 for for ADP iajs-152 6 7 pur pur PROPN iajs-152 6 8 sciences science NOUN iajs-152 6 9 ( ( PUNCT iajs-152 6 10 ibn ibn PROPN iajs-152 6 11 -al -al NOUN iajs-152 6 12 - - PUNCT iajs-152 6 13 haitham)/ haitham)/ PROPN iajs-152 6 14 university university NOUN iajs-152 6 15 of of ADP iajs-152 6 16 baghdad baghdad PROPN iajs-152 6 17 received receive VERB iajs-152 6 18 in in ADP iajs-152 6 19 : : PUNCT iajs-152 6 20 10 10 NUM iajs-152 6 21 / / SYM iajs-152 6 22 june/2015 june/2015 PROPN iajs-152 6 23 , , PUNCT iajs-152 6 24 accepted accept VERB iajs-152 6 25 in in ADP iajs-152 6 26 : : PUNCT iajs-152 6 27 19 19 NUM iajs-152 6 28 / / SYM iajs-152 6 29 october/2015 october/2015 NOUN iajs-152 6 30 abstract abstract NOUN iajs-152 6 31 in in ADP iajs-152 6 32 this this DET iajs-152 6 33 work work NOUN iajs-152 6 34 , , PUNCT iajs-152 6 35 the the DET iajs-152 6 36 ligand ligand NOUN iajs-152 6 37 was be AUX iajs-152 6 38 obtained obtain VERB iajs-152 6 39 from from ADP iajs-152 6 40 the the DET iajs-152 6 41 reaction reaction NOUN iajs-152 6 42 of of ADP iajs-152 6 43 diazonium diazonium NOUN iajs-152 6 44 salt salt NOUN iajs-152 6 45 of of ADP iajs-152 6 46 naphthyl naphthyl PROPN iajs-152 6 47 amine amine NOUN iajs-152 6 48 with with ADP iajs-152 6 49 1 1 NUM iajs-152 6 50 - - PUNCT iajs-152 6 51 amino-2 amino-2 NUM iajs-152 6 52 - - PUNCT iajs-152 6 53 naphtol-4 naphtol-4 NUM iajs-152 6 54 - - PUNCT iajs-152 6 55 sulfonic sulfonic ADJ iajs-152 6 56 acid acid NOUN iajs-152 6 57 . . PUNCT iajs-152 7 1 the the DET iajs-152 7 2 bidentate bidentate ADJ iajs-152 7 3 ligand ligand NOUN iajs-152 7 4 type type NOUN iajs-152 7 5 ( ( PUNCT iajs-152 7 6 no no INTJ iajs-152 7 7 ) ) PUNCT iajs-152 7 8 donar donar ADJ iajs-152 7 9 atoms atom NOUN iajs-152 7 10 was be AUX iajs-152 7 11 reacted react VERB iajs-152 7 12 with with ADP iajs-152 7 13 1,10 1,10 NUM iajs-152 7 14 - - ADJ iajs-152 7 15 phenanthroline phenanthroline ADJ iajs-152 7 16 and and CCONJ iajs-152 7 17 matel matel NOUN iajs-152 7 18 salt salt NOUN iajs-152 7 19 in in ADP iajs-152 7 20 a a DET iajs-152 7 21 1:1:1 1:1:1 NUM iajs-152 7 22 mole mole NOUN iajs-152 7 23 ratio ratio NOUN iajs-152 7 24 to to PART iajs-152 7 25 give give VERB iajs-152 7 26 the the DET iajs-152 7 27 complexes complex NOUN iajs-152 7 28 , , PUNCT iajs-152 7 29 using use VERB iajs-152 7 30 naoh naoh NOUN iajs-152 7 31 as as ADP iajs-152 7 32 a a DET iajs-152 7 33 base base NOUN iajs-152 7 34 . . PUNCT iajs-152 8 1 physical physical ADJ iajs-152 8 2 - - PUNCT iajs-152 8 3 chemical chemical NOUN iajs-152 8 4 teqnichas teqnicha NOUN iajs-152 8 5 were be AUX iajs-152 8 6 used use VERB iajs-152 8 7 to to PART iajs-152 8 8 characteriz characteriz VERB iajs-152 8 9 the the DET iajs-152 8 10 prepared prepare VERB iajs-152 8 11 compounds compound NOUN iajs-152 8 12 ft ft PROPN iajs-152 8 13 - - PUNCT iajs-152 8 14 ir ir PROPN iajs-152 8 15 , , PUNCT iajs-152 8 16 u.v u.v PROPN iajs-152 8 17 - - PUNCT iajs-152 8 18 vis vis X iajs-152 8 19 , , PUNCT iajs-152 8 20 fluorescence fluorescence NOUN iajs-152 8 21 and and CCONJ iajs-152 8 22 1hnmr 1hnmr NUM iajs-152 8 23 spectroscopy spectroscopy NOUN iajs-152 8 24 , , PUNCT iajs-152 8 25 atomic atomic ADJ iajs-152 8 26 absorption absorption NOUN iajs-152 8 27 , , PUNCT iajs-152 8 28 chloride chloride NOUN iajs-152 8 29 content content NOUN iajs-152 8 30 along along ADP iajs-152 8 31 with with ADP iajs-152 8 32 conductivity conductivity NOUN iajs-152 8 33 and and CCONJ iajs-152 8 34 melting melting NOUN iajs-152 8 35 point point NOUN iajs-152 8 36 measurements measurement NOUN iajs-152 8 37 .finally .finally ADV iajs-152 8 38 , , PUNCT iajs-152 8 39 thermal thermal ADJ iajs-152 8 40 analysis analysis NOUN iajs-152 8 41 was be AUX iajs-152 8 42 used use VERB iajs-152 8 43 to to PART iajs-152 8 44 confirm confirm VERB iajs-152 8 45 the the DET iajs-152 8 46 presence presence NOUN iajs-152 8 47 of of ADP iajs-152 8 48 coordination coordination NOUN iajs-152 8 49 h2o h2o VERB iajs-152 8 50 molecule molecule NOUN iajs-152 8 51 in in ADP iajs-152 8 52 the the DET iajs-152 8 53 complexes complex NOUN iajs-152 8 54 structure structure NOUN iajs-152 8 55 . . PUNCT iajs-152 9 1 according accord VERB iajs-152 9 2 to to ADP iajs-152 9 3 memtioned memtione VERB iajs-152 9 4 characterization characterization NOUN iajs-152 9 5 methods method NOUN iajs-152 9 6 , , PUNCT iajs-152 9 7 the the DET iajs-152 9 8 general general ADJ iajs-152 9 9 formula formula NOUN iajs-152 9 10 proposed propose VERB iajs-152 9 11 for for ADP iajs-152 9 12 coii coii ADJ iajs-152 9 13 znii znii NOUN iajs-152 9 14 , , PUNCT iajs-152 9 15 cdii cdii NOUN iajs-152 9 16 and and CCONJ iajs-152 9 17 hgii hgii NOUN iajs-152 9 18 complexes complex NOUN iajs-152 9 19 is be AUX iajs-152 9 20 [ [ X iajs-152 9 21 m(l)(phen)(h2o)cl m(l)(phen)(h2o)cl NOUN iajs-152 9 22 ] ] X iajs-152 9 23 . . PUNCT iajs-152 10 1 keywords keyword NOUN iajs-152 10 2 : : PUNCT iajs-152 10 3 azo azo NOUN iajs-152 10 4 - - PUNCT iajs-152 10 5 dye dye NOUN iajs-152 10 6 , , PUNCT iajs-152 10 7 ligand ligand ADJ iajs-152 10 8 , , PUNCT iajs-152 10 9 complex complex ADJ iajs-152 10 10 , , PUNCT iajs-152 10 11 1,10 1,10 NUM iajs-152 10 12 - - NUM iajs-152 10 13 phenanthroline phenanthroline ADJ iajs-152 10 14 188 188 NUM iajs-152 10 15 | | NOUN iajs-152 10 16 chemistry chemistry NOUN iajs-152 10 17 2015 2015 NUM iajs-152 10 18 ) ) PUNCT iajs-152 10 19 عام عام ADP iajs-152 10 20 3العدد 3العدد NUM iajs-152 10 21 ( ( PUNCT iajs-152 10 22 28مجلة 28مجلة X iajs-152 10 23 إبن إبن VERB iajs-152 10 24 الھيثم الھيثم NOUN iajs-152 10 25 للعلوم للعلوم NOUN iajs-152 10 26 الصرفة الصرفة NOUN iajs-152 11 1 و و PRON iajs-152 11 2 التطبيقية التطبيقية ADV iajs-152 11 3 المجلد المجلد VERB iajs-152 11 4 ibn ibn PROPN iajs-152 11 5 al al PROPN iajs-152 11 6 - - PUNCT iajs-152 11 7 haitham haitham PROPN iajs-152 11 8 jour jour X iajs-152 11 9 . . PROPN iajs-152 12 1 for for ADP iajs-152 12 2 pure pure ADJ iajs-152 12 3 & & CCONJ iajs-152 12 4 appl appl PROPN iajs-152 12 5 . . PUNCT iajs-152 13 1 sci sci PROPN iajs-152 13 2 . . PUNCT iajs-152 13 3 vol vol NOUN iajs-152 13 4 . . PROPN iajs-152 14 1 28 28 NUM iajs-152 14 2 ( ( PUNCT iajs-152 14 3 3 3 NUM iajs-152 14 4 ) ) SYM iajs-152 14 5 2015 2015 NUM iajs-152 14 6 introduction introduction NOUN iajs-152 14 7 azo azo NOUN iajs-152 14 8 compounds compound NOUN iajs-152 14 9 are be AUX iajs-152 14 10 a a DET iajs-152 14 11 very very ADV iajs-152 14 12 important important ADJ iajs-152 14 13 class class NOUN iajs-152 14 14 of of ADP iajs-152 14 15 chemical chemical NOUN iajs-152 14 16 compounds compound NOUN iajs-152 14 17 that that PRON iajs-152 14 18 received receive VERB iajs-152 14 19 attention attention NOUN iajs-152 14 20 in in ADP iajs-152 14 21 scientific scientific ADJ iajs-152 14 22 research research NOUN iajs-152 14 23 . . PUNCT iajs-152 15 1 they they PRON iajs-152 15 2 are be AUX iajs-152 15 3 highly highly ADV iajs-152 15 4 colored colored ADJ iajs-152 15 5 and and CCONJ iajs-152 15 6 have have AUX iajs-152 15 7 been be AUX iajs-152 15 8 used use VERB iajs-152 15 9 as as ADP iajs-152 15 10 dyes dye NOUN iajs-152 15 11 and and CCONJ iajs-152 15 12 pigments pigment NOUN iajs-152 15 13 for for ADP iajs-152 15 14 a a DET iajs-152 15 15 long long ADJ iajs-152 15 16 time time NOUN iajs-152 15 17 [ [ X iajs-152 15 18 1,2 1,2 NUM iajs-152 15 19 ] ] PUNCT iajs-152 15 20 . . PUNCT iajs-152 16 1 furthermore furthermore ADV iajs-152 16 2 , , PUNCT iajs-152 16 3 they they PRON iajs-152 16 4 have have AUX iajs-152 16 5 been be AUX iajs-152 16 6 studied study VERB iajs-152 16 7 widely widely ADV iajs-152 16 8 because because SCONJ iajs-152 16 9 of of ADP iajs-152 16 10 their their PRON iajs-152 16 11 excellent excellent ADJ iajs-152 16 12 thermal thermal ADJ iajs-152 16 13 and and CCONJ iajs-152 16 14 optical optical ADJ iajs-152 16 15 properties property NOUN iajs-152 16 16 in in ADP iajs-152 16 17 applications application NOUN iajs-152 16 18 such such ADJ iajs-152 16 19 as as ADP iajs-152 16 20 optical optical ADJ iajs-152 16 21 recording recording NOUN iajs-152 16 22 medium medium NOUN iajs-152 16 23 [ [ X iajs-152 16 24 3 3 NUM iajs-152 16 25 - - SYM iajs-152 16 26 6 6 NUM iajs-152 16 27 ] ] PUNCT iajs-152 16 28 , , PUNCT iajs-152 16 29 link link NOUN iajs-152 16 30 - - PUNCT iajs-152 16 31 jet jet NOUN iajs-152 16 32 printing[7,8 printing[7,8 NOUN iajs-152 16 33 ] ] PUNCT iajs-152 16 34 and and CCONJ iajs-152 16 35 oilsolution oilsolution VERB iajs-152 16 36 light light ADJ iajs-152 16 37 fast fast ADJ iajs-152 16 38 dyes dye NOUN iajs-152 17 1 [ [ X iajs-152 17 2 9 9 NUM iajs-152 17 3 ] ] PUNCT iajs-152 17 4 . . PUNCT iajs-152 18 1 1,10phenanthroline 1,10phenanthroline NUM iajs-152 18 2 has have VERB iajs-152 18 3 a a DET iajs-152 18 4 rigid rigid ADJ iajs-152 18 5 framework framework NOUN iajs-152 18 6 and and CCONJ iajs-152 18 7 possesses possess VERB iajs-152 18 8 a a DET iajs-152 18 9 super super ADJ iajs-152 18 10 , , PUNCT iajs-152 18 11 ability ability NOUN iajs-152 18 12 to to PART iajs-152 18 13 chelate chelate VERB iajs-152 18 14 many many ADJ iajs-152 18 15 metale metale NOUN iajs-152 18 16 ions ion NOUN iajs-152 18 17 via via ADP iajs-152 18 18 two two NUM iajs-152 18 19 nitrogen nitrogen NOUN iajs-152 18 20 donors donor NOUN iajs-152 18 21 , , PUNCT iajs-152 18 22 which which PRON iajs-152 18 23 shows show VERB iajs-152 18 24 potential potential NOUN iajs-152 18 25 for for ADP iajs-152 18 26 technological technological ADJ iajs-152 18 27 applications application NOUN iajs-152 18 28 , , PUNCT iajs-152 18 29 due due ADP iajs-152 18 30 to to ADP iajs-152 18 31 their their PRON iajs-152 18 32 high high ADJ iajs-152 18 33 charge charge NOUN iajs-152 18 34 transfer transfer NOUN iajs-152 18 35 mobility mobility NOUN iajs-152 18 36 , , PUNCT iajs-152 18 37 bright bright ADJ iajs-152 18 38 light light ADJ iajs-152 18 39 - - PUNCT iajs-152 18 40 emission emission NOUN iajs-152 18 41 and and CCONJ iajs-152 18 42 good good ADJ iajs-152 18 43 electroand electroand PROPN iajs-152 18 44 photo photo NOUN iajs-152 18 45 -active -active PROPN iajs-152 18 46 properties property NOUN iajs-152 18 47 [ [ X iajs-152 18 48 10 10 NUM iajs-152 18 49 - - SYM iajs-152 18 50 15 15 NUM iajs-152 18 51 ] ] PUNCT iajs-152 18 52 . . PUNCT iajs-152 19 1 azo azo NOUN iajs-152 19 2 metal metal NOUN iajs-152 19 3 chelates chelate NOUN iajs-152 19 4 have have AUX iajs-152 19 5 also also ADV iajs-152 19 6 attracted attract VERB iajs-152 19 7 increasing increase VERB iajs-152 19 8 attention attention NOUN iajs-152 19 9 due due ADP iajs-152 19 10 to to ADP iajs-152 19 11 their their PRON iajs-152 19 12 interesting interesting ADJ iajs-152 19 13 electronic electronic ADJ iajs-152 19 14 and and CCONJ iajs-152 19 15 geometrical geometrical ADJ iajs-152 19 16 features feature NOUN iajs-152 19 17 in in ADP iajs-152 19 18 connection connection NOUN iajs-152 19 19 with with ADP iajs-152 19 20 their their PRON iajs-152 19 21 application application NOUN iajs-152 19 22 for for ADP iajs-152 19 23 molecular molecular ADJ iajs-152 19 24 memory memory NOUN iajs-152 19 25 storage storage NOUN iajs-152 19 26 , , PUNCT iajs-152 19 27 nonlinear nonlinear ADJ iajs-152 19 28 optical optical ADJ iajs-152 19 29 elements element NOUN iajs-152 19 30 and and CCONJ iajs-152 19 31 printing printing NOUN iajs-152 19 32 systems system NOUN iajs-152 19 33 [ [ X iajs-152 19 34 4],[6]and[16].the 4],[6]and[16].the DET iajs-152 19 35 presence presence NOUN iajs-152 19 36 of of ADP iajs-152 19 37 aromatic aromatic ADJ iajs-152 19 38 and and CCONJ iajs-152 19 39 /or /or ADP iajs-152 19 40 heteroaromatic heteroaromatic ADJ iajs-152 19 41 groups group NOUN iajs-152 19 42 in in ADP iajs-152 19 43 the the DET iajs-152 19 44 structure structure NOUN iajs-152 19 45 of of ADP iajs-152 19 46 nitrogen nitrogen NOUN iajs-152 19 47 donors donor NOUN iajs-152 19 48 gives give VERB iajs-152 19 49 these these DET iajs-152 19 50 ligands ligand NOUN iajs-152 19 51 additional additional ADJ iajs-152 19 52 properties property NOUN iajs-152 19 53 , , PUNCT iajs-152 19 54 for for ADP iajs-152 19 55 instance instance NOUN iajs-152 19 56 , , PUNCT iajs-152 19 57 poly poly ADJ iajs-152 19 58 nitrogen nitrogen NOUN iajs-152 19 59 donors donor NOUN iajs-152 19 60 containing contain VERB iajs-152 19 61 aromatic aromatic ADJ iajs-152 19 62 and/or and/or CCONJ iajs-152 19 63 heteroaromatic heteroaromatic ADJ iajs-152 19 64 groups group NOUN iajs-152 19 65 conjugate conjugate VERB iajs-152 19 66 the the DET iajs-152 19 67 ligational ligational ADJ iajs-152 19 68 ability ability NOUN iajs-152 19 69 with with ADP iajs-152 19 70 the the DET iajs-152 19 71 photophysical photophysical ADJ iajs-152 19 72 properties property NOUN iajs-152 19 73 typical typical ADJ iajs-152 19 74 of of ADP iajs-152 19 75 these these DET iajs-152 19 76 groups group NOUN iajs-152 19 77 and and CCONJ iajs-152 19 78 accordingly accordingly ADV iajs-152 19 79 , , PUNCT iajs-152 19 80 they they PRON iajs-152 19 81 have have AUX iajs-152 19 82 been be AUX iajs-152 19 83 widely widely ADV iajs-152 19 84 used use VERB iajs-152 19 85 as as ADP iajs-152 19 86 chemosensors chemosensor NOUN iajs-152 19 87 for for ADP iajs-152 19 88 metal metal NOUN iajs-152 19 89 ions ion NOUN iajs-152 19 90 in in ADP iajs-152 19 91 solution solution NOUN iajs-152 19 92 , , PUNCT iajs-152 19 93 since since SCONJ iajs-152 19 94 their their PRON iajs-152 19 95 coordination coordination NOUN iajs-152 19 96 may may AUX iajs-152 19 97 affect affect VERB iajs-152 19 98 the the DET iajs-152 19 99 properties property NOUN iajs-152 19 100 of of ADP iajs-152 19 101 the the DET iajs-152 19 102 photosensitive photosensitive ADJ iajs-152 19 103 group group NOUN iajs-152 19 104 giving give VERB iajs-152 19 105 rise rise NOUN iajs-152 19 106 to to ADP iajs-152 19 107 an an DET iajs-152 19 108 optical optical ADJ iajs-152 19 109 response response NOUN iajs-152 20 1 [ [ X iajs-152 20 2 17 17 NUM iajs-152 20 3 - - SYM iajs-152 20 4 19 19 NUM iajs-152 20 5 ] ] PUNCT iajs-152 20 6 . . PUNCT iajs-152 21 1 recently recently ADV iajs-152 21 2 man man VERB iajs-152 21 3 singh singh PROPN iajs-152 21 4 and and CCONJ iajs-152 21 5 sushma sushma PROPN iajs-152 21 6 anant anant PROPN iajs-152 21 7 prepared prepare VERB iajs-152 21 8 a a DET iajs-152 21 9 new new ADJ iajs-152 21 10 azo azo NOUN iajs-152 21 11 dye dye NOUN iajs-152 21 12 , , PUNCT iajs-152 21 13 n n CCONJ iajs-152 21 14 , , PUNCT iajs-152 21 15 ndimethylazoleucine ndimethylazoleucine NOUN iajs-152 21 16 , , PUNCT iajs-152 21 17 composed compose VERB iajs-152 21 18 of of ADP iajs-152 21 19 leucine leucine NOUN iajs-152 21 20 ( ( PUNCT iajs-152 21 21 nh2ch-(ch2ch(c2h6))cooh nh2ch-(ch2ch(c2h6))cooh NOUN iajs-152 21 22 ) ) PUNCT iajs-152 21 23 as as ADP iajs-152 21 24 basic basic ADJ iajs-152 21 25 moiety moiety NOUN iajs-152 21 26 and and CCONJ iajs-152 21 27 1,2 1,2 NUM iajs-152 21 28 - - PUNCT iajs-152 21 29 dimethyl dimethyl NOUN iajs-152 21 30 aniline aniline NOUN iajs-152 21 31 ( ( PUNCT iajs-152 21 32 c6h5n(ch3)2 c6h5n(ch3)2 PROPN iajs-152 21 33 ) ) PUNCT iajs-152 21 34 and and CCONJ iajs-152 21 35 its its PRON iajs-152 21 36 pr(iii pr(iii NOUN iajs-152 21 37 ) ) PUNCT iajs-152 21 38 complex complex NOUN iajs-152 21 39 with with ADP iajs-152 21 40 1,10 1,10 NUM iajs-152 21 41 phenanthroline phenanthroline NOUN iajs-152 21 42 ( ( PUNCT iajs-152 21 43 heterocyclic heterocyclic ADJ iajs-152 21 44 compound compound NOUN iajs-152 21 45 ) ) PUNCT iajs-152 21 46 adduct adduct NOUN iajs-152 21 47 to to PART iajs-152 21 48 assess assess VERB iajs-152 21 49 the the DET iajs-152 21 50 possibilities possibility NOUN iajs-152 21 51 of of ADP iajs-152 21 52 pr(iii pr(iii NOUN iajs-152 21 53 ) ) PUNCT iajs-152 21 54 complexes complexe VERB iajs-152 21 55 formation formation NOUN iajs-152 21 56 and and CCONJ iajs-152 21 57 spectral spectral ADJ iajs-152 21 58 changes change NOUN iajs-152 21 59 that that PRON iajs-152 21 60 occur occur VERB iajs-152 21 61 due due ADJ iajs-152 21 62 to to ADP iajs-152 21 63 complexation complexation NOUN iajs-152 21 64 [ [ X iajs-152 21 65 20].in 20].in NUM iajs-152 21 66 this this DET iajs-152 21 67 paper paper NOUN iajs-152 21 68 , , PUNCT iajs-152 21 69 preparation preparation NOUN iajs-152 21 70 of of ADP iajs-152 21 71 new new ADJ iajs-152 21 72 complexes complex NOUN iajs-152 21 73 of of ADP iajs-152 21 74 mixed mixed ADJ iajs-152 21 75 ligand ligand NOUN iajs-152 21 76 containing(2-(2-(naphthalen-5 containing(2-(2-(naphthalen-5 PROPN iajs-152 21 77 - - PUNCT iajs-152 21 78 yl)diazenyl)-4 yl)diazenyl)-4 VERB iajs-152 21 79 - - PUNCT iajs-152 21 80 amino-3hydroxynaphthalene-1 amino-3hydroxynaphthalene-1 NOUN iajs-152 21 81 - - ADJ iajs-152 21 82 sulfonic sulfonic ADJ iajs-152 21 83 acid acid NOUN iajs-152 21 84 ) ) PUNCT iajs-152 21 85 and and CCONJ iajs-152 21 86 1,10 1,10 NUM iajs-152 21 87 - - NUM iajs-152 21 88 phenanthroline phenanthroline NOUN iajs-152 21 89 were be AUX iajs-152 21 90 reported report VERB iajs-152 21 91 , , PUNCT iajs-152 21 92 the the DET iajs-152 21 93 fluorescence fluorescence NOUN iajs-152 21 94 properties property NOUN iajs-152 21 95 of of ADP iajs-152 21 96 the the DET iajs-152 21 97 prepared prepare VERB iajs-152 21 98 compound compound NOUN iajs-152 21 99 were be AUX iajs-152 21 100 studied study VERB iajs-152 21 101 . . PUNCT iajs-152 22 1 experimental experimental ADJ iajs-152 22 2 an an DET iajs-152 22 3 electro electro ADJ iajs-152 22 4 thermal thermal ADJ iajs-152 22 5 apparatus apparatus NOUN iajs-152 22 6 stuart stuart PROPN iajs-152 22 7 melting melting NOUN iajs-152 22 8 point point NOUN iajs-152 22 9 was be AUX iajs-152 22 10 used use VERB iajs-152 22 11 to to PART iajs-152 22 12 measure measure VERB iajs-152 22 13 the the DET iajs-152 22 14 melting melting NOUN iajs-152 22 15 points point NOUN iajs-152 22 16 . . PUNCT iajs-152 23 1 infrared infrared PROPN iajs-152 23 2 spectra spectra PROPN iajs-152 23 3 were be AUX iajs-152 23 4 performed perform VERB iajs-152 23 5 using use VERB iajs-152 23 6 fi fi PROPN iajs-152 23 7 - - ADJ iajs-152 23 8 ir ir ADJ iajs-152 23 9 testscan testscan NOUN iajs-152 23 10 shimadzu shimadzu NOUN iajs-152 23 11 ( ( PUNCT iajs-152 23 12 ft ft NOUN iajs-152 23 13 - - PUNCT iajs-152 23 14 ir)8300 ir)8300 PROPN iajs-152 23 15 series series NOUN iajs-152 23 16 spectrophotometer spectrophotometer NOUN iajs-152 23 17 in in ADP iajs-152 23 18 the the DET iajs-152 23 19 range range NOUN iajs-152 23 20 ( ( PUNCT iajs-152 23 21 4000 4000 NUM iajs-152 23 22 – – PUNCT iajs-152 23 23 400 400 NUM iajs-152 23 24 cm–1 cm–1 NOUN iajs-152 23 25 ) ) PUNCT iajs-152 23 26 ; ; PUNCT iajs-152 23 27 spectra spectra PROPN iajs-152 23 28 were be AUX iajs-152 23 29 recorded record VERB iajs-152 23 30 as as ADP iajs-152 23 31 potassium potassium NOUN iajs-152 23 32 bromide bromide NOUN iajs-152 23 33 discs disc NOUN iajs-152 23 34 at at ADP iajs-152 23 35 college college NOUN iajs-152 23 36 of of ADP iajs-152 23 37 education education NOUN iajs-152 23 38 for for ADP iajs-152 23 39 pure pure ADJ iajs-152 23 40 science science NOUN iajs-152 23 41 ibnalhaitham/ ibnalhaitham/ NUM iajs-152 23 42 baghdad baghdad PROPN iajs-152 23 43 university university NOUN iajs-152 23 44 . . PUNCT iajs-152 24 1 the the DET iajs-152 24 2 electronic electronic ADJ iajs-152 24 3 spectra spectra NOUN iajs-152 24 4 of of ADP iajs-152 24 5 the the DET iajs-152 24 6 compounds compound NOUN iajs-152 24 7 were be AUX iajs-152 24 8 obtained obtain VERB iajs-152 24 9 using use VERB iajs-152 24 10 ( ( PUNCT iajs-152 24 11 u.v u.v PROPN iajs-152 24 12 – – PUNCT iajs-152 24 13 vis vis X iajs-152 24 14 ) ) PUNCT iajs-152 24 15 spectrophotometer spectrophotometer NOUN iajs-152 24 16 uv-1800 uv-1800 NOUN iajs-152 24 17 , , PUNCT iajs-152 24 18 in in ADP iajs-152 24 19 the the DET iajs-152 24 20 range range NOUN iajs-152 24 21 ( ( PUNCT iajs-152 24 22 1100 1100 NUM iajs-152 24 23 – – PUNCT iajs-152 24 24 200 200 NUM iajs-152 24 25 nm nm NOUN iajs-152 24 26 ) ) PUNCT iajs-152 24 27 using use VERB iajs-152 24 28 quartz quartz NOUN iajs-152 24 29 cell cell NOUN iajs-152 24 30 of of ADP iajs-152 24 31 ( ( PUNCT iajs-152 24 32 1.0 1.0 NUM iajs-152 24 33 ) ) PUNCT iajs-152 24 34 cm cm NOUN iajs-152 24 35 length length NOUN iajs-152 24 36 with with ADP iajs-152 24 37 concentration concentration NOUN iajs-152 24 38 ( ( PUNCT iajs-152 24 39 10–3 10–3 NUM iajs-152 24 40 ) ) PUNCT iajs-152 24 41 mole mole NOUN iajs-152 24 42 l–1 l–1 PROPN iajs-152 24 43 of of ADP iajs-152 24 44 samples sample NOUN iajs-152 24 45 in in ADP iajs-152 24 46 dmso dmso NOUN iajs-152 24 47 at at ADP iajs-152 24 48 25c 25c NUM iajs-152 24 49 and and CCONJ iajs-152 24 50 fluorescense fluorescense NOUN iajs-152 24 51 spectrophotometer spectrophotometer PROPN iajs-152 24 52 type type PROPN iajs-152 24 53 agilent agilent PROPN iajs-152 24 54 , , PUNCT iajs-152 24 55 the the DET iajs-152 24 56 measurement measurement NOUN iajs-152 24 57 conducted conduct VERB iajs-152 24 58 was be AUX iajs-152 24 59 in in ADP iajs-152 24 60 central central ADJ iajs-152 24 61 labrotary labrotary NOUN iajs-152 24 62 of of ADP iajs-152 24 63 college college NOUN iajs-152 24 64 of of ADP iajs-152 24 65 education education NOUN iajs-152 24 66 for for ADP iajs-152 24 67 pure pure ADJ iajs-152 24 68 science science NOUN iajs-152 24 69 ibnalhaitham ibnalhaitham PROPN iajs-152 24 70 bagdad bagdad PROPN iajs-152 24 71 university university PROPN iajs-152 24 72 .atomic .atomic ADJ iajs-152 24 73 absorption absorption NOUN iajs-152 24 74 and and CCONJ iajs-152 24 75 chloride chloride NOUN iajs-152 24 76 content content NOUN iajs-152 24 77 were be AUX iajs-152 24 78 determined determine VERB iajs-152 24 79 by by ADP iajs-152 24 80 potentiometric potentiometric ADJ iajs-152 24 81 titration titration NOUN iajs-152 24 82 method method NOUN iajs-152 24 83 on on ADP iajs-152 24 84 ( ( PUNCT iajs-152 24 85 686 686 NUM iajs-152 24 86 - - PUNCT iajs-152 24 87 titro titro VERB iajs-152 24 88 proceccor-665 proceccor-665 ADJ iajs-152 24 89 dosinat dosinat NOUN iajs-152 24 90 metrome metrome PROPN iajs-152 24 91 swiss swiss PROPN iajs-152 24 92 ) ) PUNCT iajs-152 24 93 in in ADP iajs-152 24 94 ibn ibn PROPN iajs-152 24 95 sina sina PROPN iajs-152 24 96 company company PROPN iajs-152 24 97 ministary ministary ADJ iajs-152 24 98 of of ADP iajs-152 24 99 industary industary ADJ iajs-152 24 100 baghdad baghdad PROPN iajs-152 24 101 iraq iraq PROPN iajs-152 24 102 . . PUNCT iajs-152 25 1 electrical electrical ADJ iajs-152 25 2 conductivity conductivity NOUN iajs-152 25 3 measurements measurement NOUN iajs-152 25 4 of of ADP iajs-152 25 5 the the DET iajs-152 25 6 complexes complex NOUN iajs-152 25 7 were be AUX iajs-152 25 8 recorded record VERB iajs-152 25 9 at at ADP iajs-152 25 10 ( ( PUNCT iajs-152 25 11 25c 25c NUM iajs-152 25 12 ) ) PUNCT iajs-152 25 13 for for ADP iajs-152 25 14 ( ( PUNCT iajs-152 25 15 10–3–10–5 10–3–10–5 X iajs-152 25 16 ) ) PUNCT iajs-152 25 17 m m NOUN iajs-152 25 18 solutions solution NOUN iajs-152 25 19 of of ADP iajs-152 25 20 the the DET iajs-152 25 21 samples sample NOUN iajs-152 25 22 in in ADP iajs-152 25 23 dmso dmso NOUN iajs-152 25 24 using use VERB iajs-152 25 25 eutech eutech NOUN iajs-152 25 26 150 150 NUM iajs-152 25 27 conductivity conductivity NOUN iajs-152 25 28 meter meter NOUN iajs-152 25 29 . . PUNCT iajs-152 26 1 1hnmr 1hnmr NUM iajs-152 26 2 , , PUNCT iajs-152 26 3     SPACE iajs-152 26 4 spectra spectra NOUN iajs-152 26 5 for for ADP iajs-152 26 6 the the DET iajs-152 26 7 ligand ligand ADJ iajs-152 26 8 and and CCONJ iajs-152 26 9 cdii cdii NOUN iajs-152 26 10 complex complex NOUN iajs-152 26 11 were be AUX iajs-152 26 12 recorded record VERB iajs-152 26 13 in in ADP iajs-152 26 14 dmso dmso NOUN iajs-152 26 15 - - ADJ iajs-152 26 16 d6 d6 NOUN iajs-152 26 17 using use VERB iajs-152 26 18 brucker brucker NOUN iajs-152 26 19 , , PUNCT iajs-152 26 20 model model NOUN iajs-152 26 21 : : PUNCT iajs-152 26 22 ultra ultra ADJ iajs-152 26 23 sheild sheild ADJ iajs-152 26 24 400 400 NUM iajs-152 26 25 mhz mhz NOUN iajs-152 26 26 , , PUNCT iajs-152 26 27 origin origin NOUN iajs-152 26 28 : : PUNCT iajs-152 26 29 switzerland switzerland NOUN iajs-152 26 30 and and CCONJ iajs-152 26 31 are be AUX iajs-152 26 32 reported report VERB iajs-152 26 33 in in ADP iajs-152 26 34 ppm ppm PROPN iajs-152 26 35 ( ( PUNCT iajs-152 26 36 s s NOUN iajs-152 26 37 ) ) PUNCT iajs-152 26 38 , , PUNCT iajs-152 26 39 at at ADP iajs-152 26 40 kashan kashan PROPN iajs-152 26 41 university university PROPN iajs-152 26 42 iran iran PROPN iajs-152 26 43 , , PUNCT iajs-152 26 44 tg tg PROPN iajs-152 26 45 and and CCONJ iajs-152 26 46 dsc dsc PROPN iajs-152 26 47 , , PUNCT iajs-152 26 48 thermograph thermograph PROPN iajs-152 26 49 were be AUX iajs-152 26 50 obtained obtain VERB iajs-152 26 51 using use VERB iajs-152 26 52 apparatus apparatus NOUN iajs-152 26 53 type type NOUN iajs-152 26 54 sta sta PROPN iajs-152 26 55 pt-1000 pt-1000 PROPN iajs-152 26 56 linseis linseis PROPN iajs-152 26 57 as as ADP iajs-152 26 58 the the DET iajs-152 26 59 temperature temperature NOUN iajs-152 26 60 range range NOUN iajs-152 26 61 of of ADP iajs-152 26 62 30 30 NUM iajs-152 26 63 - - SYM iajs-152 26 64 600c0 600c0 NUM iajs-152 26 65 , , PUNCT iajs-152 26 66 the the DET iajs-152 26 67 measurement measurement NOUN iajs-152 26 68 obtained obtain VERB iajs-152 26 69 in in ADP iajs-152 26 70 central central ADJ iajs-152 26 71 laboratory laboratory NOUN iajs-152 26 72 , , PUNCT iajs-152 26 73 college college NOUN iajs-152 26 74 of of ADP iajs-152 26 75 education education NOUN iajs-152 26 76 for for ADP iajs-152 26 77 pure pure ADJ iajs-152 26 78 science science NOUN iajs-152 26 79 ibnalhaitham ibnalhaitham PROPN iajs-152 26 80 bagdad bagdad PROPN iajs-152 26 81 university university PROPN iajs-152 26 82 . . PUNCT iajs-152 27 1 synthesis synthesis NOUN iajs-152 27 2 of of ADP iajs-152 27 3 the the DET iajs-152 27 4 ligand ligand NOUN iajs-152 27 5 ( ( PUNCT iajs-152 27 6 hl hl NOUN iajs-152 27 7 ) ) PUNCT iajs-152 27 8 this this DET iajs-152 27 9 compound compound NOUN iajs-152 27 10 was be AUX iajs-152 27 11 prepared prepare VERB iajs-152 27 12 as as SCONJ iajs-152 27 13 described describe VERB iajs-152 27 14 in in ADP iajs-152 27 15 the the DET iajs-152 27 16 literature literature NOUN iajs-152 28 1 [ [ X iajs-152 28 2 21,22 21,22 X iajs-152 28 3 ] ] X iajs-152 28 4 . . PUNCT iajs-152 29 1 a a DET iajs-152 29 2 mixture mixture NOUN iajs-152 29 3 of of ADP iajs-152 29 4 1 1 NUM iajs-152 29 5 - - PUNCT iajs-152 29 6 naphthyl naphthyl NOUN iajs-152 29 7 amine amine NOUN iajs-152 29 8 ( ( PUNCT iajs-152 29 9 1 1 NUM iajs-152 29 10 g g NOUN iajs-152 29 11 , , PUNCT iajs-152 29 12 6.98 6.98 NUM iajs-152 29 13 mmol mmol NOUN iajs-152 29 14 ) ) PUNCT iajs-152 29 15 in in ADP iajs-152 29 16 water water NOUN iajs-152 29 17 ( ( PUNCT iajs-152 29 18 10 10 NUM iajs-152 29 19 ml ml NOUN iajs-152 29 20 ) ) PUNCT iajs-152 29 21 and and CCONJ iajs-152 29 22 concentrated concentrated ADJ iajs-152 29 23 hydrochloric hydrochloric ADJ iajs-152 29 24 acid acid NOUN iajs-152 29 25 ( ( PUNCT iajs-152 29 26 2.62 2.62 NUM iajs-152 29 27 ml ml NOUN iajs-152 29 28 , , PUNCT iajs-152 29 29 30.00 30.00 NUM iajs-152 29 30 mmol mmol NOUN iajs-152 29 31 ) ) PUNCT iajs-152 29 32 was be AUX iajs-152 29 33 stirred stir VERB iajs-152 29 34 until until SCONJ iajs-152 29 35 a a DET iajs-152 29 36 clear clear ADJ iajs-152 29 37 solution solution NOUN iajs-152 29 38 was be AUX iajs-152 29 39 obtained.the obtained.the DET iajs-152 29 40 mixture mixture NOUN iajs-152 29 41 was be AUX iajs-152 29 42 cooled cool VERB iajs-152 29 43 to to ADP iajs-152 29 44 0 0 NUM iajs-152 29 45 – – PUNCT iajs-152 29 46 5c 5c PROPN iajs-152 29 47 and and CCONJ iajs-152 29 48 a a DET iajs-152 29 49 solution solution NOUN iajs-152 29 50 of of ADP iajs-152 29 51 sodium sodium NOUN iajs-152 29 52 nitrite nitrite NOUN iajs-152 29 53 ( ( PUNCT iajs-152 29 54 0.76 0.76 NUM iajs-152 29 55 g g NOUN iajs-152 29 56 , , PUNCT iajs-152 29 57 11.00 11.00 NUM iajs-152 29 58 mmol mmol NOUN iajs-152 29 59 ) ) PUNCT iajs-152 29 60 in in ADP iajs-152 29 61 water water NOUN iajs-152 29 62 ( ( PUNCT iajs-152 29 63 5 5 NUM iajs-152 29 64 ml ml NOUN iajs-152 29 65 ) ) PUNCT iajs-152 29 66 was be AUX iajs-152 29 67 then then ADV iajs-152 29 68 added add VERB iajs-152 29 69 dropwise dropwise NOUN iajs-152 29 70 , , PUNCT iajs-152 29 71 maintaining maintain VERB iajs-152 29 72 the the DET iajs-152 29 73 temperature temperature NOUN iajs-152 29 74 below below ADP iajs-152 29 75 5c 5c PROPN iajs-152 29 76 . . PUNCT iajs-152 30 1 the the DET iajs-152 30 2 resulting result VERB iajs-152 30 3 mixture mixture NOUN iajs-152 30 4 was be AUX iajs-152 30 5 stirred stir VERB iajs-152 30 6 for for ADP iajs-152 30 7 an an DET iajs-152 30 8 additional additional ADJ iajs-152 30 9 1h 1h NUM iajs-152 30 10 in in ADP iajs-152 30 11 an an DET iajs-152 30 12 ice ice NOUN iajs-152 30 13 bath bath NOUN iajs-152 30 14 and and CCONJ iajs-152 30 15 then then ADV iajs-152 30 16 a a DET iajs-152 30 17 little little ADJ iajs-152 30 18 urea urea NOUN iajs-152 30 19 was be AUX iajs-152 30 20 added add VERB iajs-152 30 21 and and CCONJ iajs-152 30 22 was be AUX iajs-152 30 23 buffered buffer VERB iajs-152 30 24 ( ( PUNCT iajs-152 30 25 ph ph NOUN iajs-152 30 26 6–7 6–7 NOUN iajs-152 30 27 ) ) PUNCT iajs-152 30 28 with with ADP iajs-152 30 29 solid solid ADJ iajs-152 30 30 sodium sodium NOUN iajs-152 30 31 acetate acetate NOUN iajs-152 30 32 ( ( PUNCT iajs-152 30 33 solution solution NOUN iajs-152 30 34 1 1 NUM iajs-152 30 35 ) ) PUNCT iajs-152 30 36 . . PUNCT iajs-152 31 1 1 1 NUM iajs-152 31 2 - - PUNCT iajs-152 31 3 amino-2 amino-2 NUM iajs-152 31 4 - - PUNCT iajs-152 31 5 naphtol-4sulfonic naphtol-4sulfonic NOUN iajs-152 31 6 acid acid NOUN iajs-152 31 7 ( ( PUNCT iajs-152 31 8 1.67 1.67 NUM iajs-152 31 9 g g NOUN iajs-152 31 10 , , PUNCT iajs-152 31 11 6.98 6.98 NUM iajs-152 31 12 mmol mmol NOUN iajs-152 31 13 ) ) PUNCT iajs-152 31 14 was be AUX iajs-152 31 15 dissolved dissolve VERB iajs-152 31 16 in in ADP iajs-152 31 17 10 10 NUM iajs-152 31 18 ml ml NOUN iajs-152 31 19 aqueous aqueous ADJ iajs-152 31 20 naoh naoh NOUN iajs-152 31 21 ( ( PUNCT iajs-152 31 22 10 10 NUM iajs-152 31 23 mmol mmol NOUN iajs-152 31 24 ) ) PUNCT iajs-152 31 25 solution solution NOUN iajs-152 31 26 , , PUNCT iajs-152 31 27 cooled cool VERB iajs-152 31 28 to to ADP iajs-152 31 29 0 0 NUM iajs-152 31 30 5c 5c PROPN iajs-152 31 31 in in ADP iajs-152 31 32 an an DET iajs-152 31 33 ice ice NOUN iajs-152 31 34 bath bath NOUN iajs-152 31 35 ( ( PUNCT iajs-152 31 36 solution solution NOUN iajs-152 31 37 2).the 2).the DET iajs-152 31 38 solution solution NOUN iajs-152 31 39 was be AUX iajs-152 31 40 then then ADV iajs-152 31 41 gradually gradually ADV iajs-152 31 42 added add VERB iajs-152 31 43 to to ADP iajs-152 31 44 the the DET iajs-152 31 45 cold cold ADJ iajs-152 31 46 solution solution NOUN iajs-152 31 47 1 1 NUM iajs-152 31 48 , , PUNCT iajs-152 31 49 and and CCONJ iajs-152 31 50     SPACE iajs-152 31 51 189 189 NUM iajs-152 31 52 | | NOUN iajs-152 31 53 chemistry chemistry NOUN iajs-152 31 54 2015 2015 NUM iajs-152 31 55 ) ) PUNCT iajs-152 31 56 عام عام ADP iajs-152 31 57 3العدد 3العدد NUM iajs-152 31 58 ( ( PUNCT iajs-152 31 59 28مجلة 28مجلة X iajs-152 31 60 إبن إبن VERB iajs-152 32 1 الھيثم الھيثم NOUN iajs-152 32 2 للعلوم للعلوم NOUN iajs-152 32 3 الصرفة الصرفة NOUN iajs-152 33 1 و و PRON iajs-152 33 2 التطبيقية التطبيقية ADV iajs-152 33 3 المجلد المجلد VERB iajs-152 33 4 ibn ibn PROPN iajs-152 33 5 al al PROPN iajs-152 33 6 - - PUNCT iajs-152 33 7 haitham haitham PROPN iajs-152 33 8 jour jour X iajs-152 33 9 . . PROPN iajs-152 34 1 for for ADP iajs-152 34 2 pure pure ADJ iajs-152 34 3 & & CCONJ iajs-152 34 4 appl appl PROPN iajs-152 34 5 . . PUNCT iajs-152 35 1 sci sci PROPN iajs-152 35 2 . . PUNCT iajs-152 35 3 vol vol NOUN iajs-152 35 4 . . PROPN iajs-152 36 1 28 28 NUM iajs-152 36 2 ( ( PUNCT iajs-152 36 3 3 3 NUM iajs-152 36 4 ) ) PUNCT iajs-152 36 5 2015 2015 NUM iajs-152 36 6 the the DET iajs-152 36 7 resulting result VERB iajs-152 36 8 mixture mixture NOUN iajs-152 36 9 was be AUX iajs-152 36 10 continually continually ADV iajs-152 36 11 stirred stir VERB iajs-152 36 12 at at ADP iajs-152 36 13 05c 05c NOUN iajs-152 36 14 for for ADP iajs-152 36 15 2 2 NUM iajs-152 36 16 hrs hrs NOUN iajs-152 36 17 . . PUNCT iajs-152 37 1 the the DET iajs-152 37 2 resulting result VERB iajs-152 37 3 crude crude ADJ iajs-152 37 4 precipitate precipitate NOUN iajs-152 37 5 was be AUX iajs-152 37 6 filtered filter VERB iajs-152 37 7 by by ADP iajs-152 37 8 acidification acidification NOUN iajs-152 37 9 and and CCONJ iajs-152 37 10 washed wash VERB iajs-152 37 11 several several ADJ iajs-152 37 12 times time NOUN iajs-152 37 13 with with ADP iajs-152 37 14 cold cold ADJ iajs-152 37 15 water.yield water.yield VERB iajs-152 37 16 72%,m.p(290c 72%,m.p(290c NUM iajs-152 37 17 dec dec PROPN iajs-152 37 18 . . PROPN iajs-152 37 19 ) ) PUNCT iajs-152 37 20 . . PUNCT iajs-152 38 1 synthesis synthesis NOUN iajs-152 38 2 of of ADP iajs-152 38 3 the the DET iajs-152 38 4 complex complex NOUN iajs-152 38 5 [ [ X iajs-152 38 6 co(l)(phen co(l)(phen NOUN iajs-152 38 7 ) ) PUNCT iajs-152 38 8 ( ( PUNCT iajs-152 38 9 h2o)cl h2o)cl NOUN iajs-152 38 10 ] ] X iajs-152 38 11 to to ADP iajs-152 38 12 a a DET iajs-152 38 13 solution solution NOUN iajs-152 38 14 of of ADP iajs-152 38 15 ( ( PUNCT iajs-152 38 16 0.5 0.5 NUM iajs-152 38 17 g,1.27 g,1.27 PROPN iajs-152 38 18 mmol mmol NOUN iajs-152 38 19 ) ) PUNCT iajs-152 38 20 of of ADP iajs-152 38 21 the the DET iajs-152 38 22 ligand ligand NOUN iajs-152 38 23 dissolved dissolve VERB iajs-152 38 24 in in ADP iajs-152 38 25 15 15 NUM iajs-152 38 26 ml ml NOUN iajs-152 38 27 of of ADP iajs-152 38 28 methanol methanol NOUN iajs-152 38 29 , , PUNCT iajs-152 38 30 it it PRON iajs-152 38 31 was be AUX iajs-152 38 32 added add VERB iajs-152 38 33 ( ( PUNCT iajs-152 38 34 0.051 0.051 NUM iajs-152 38 35 g g NOUN iajs-152 38 36 , , PUNCT iajs-152 38 37 1.27 1.27 NUM iajs-152 38 38 mmol mmol NOUN iajs-152 38 39 ) ) PUNCT iajs-152 38 40 of of ADP iajs-152 38 41 sodium sodium NOUN iajs-152 38 42 hydroxide hydroxide NOUN iajs-152 38 43 dissolved dissolve VERB iajs-152 38 44 in in ADP iajs-152 38 45 10 10 NUM iajs-152 38 46 ml ml NOUN iajs-152 38 47 methanol methanol NOUN iajs-152 38 48 and and CCONJ iajs-152 38 49 ( ( PUNCT iajs-152 38 50 0.25 0.25 NUM iajs-152 38 51 gm gm PROPN iajs-152 38 52 , , PUNCT iajs-152 38 53 1.27 1.27 NUM iajs-152 38 54 mmol mmol NOUN iajs-152 38 55 ) ) PUNCT iajs-152 38 56 of of ADP iajs-152 38 57 1,10 1,10 NUM iajs-152 38 58 - - NUM iajs-152 38 59 phenanthroline phenanthroline NOUN iajs-152 38 60 in in ADP iajs-152 38 61 10 10 NUM iajs-152 38 62 mlwith mlwith NOUN iajs-152 38 63 stirring stirring NOUN iajs-152 38 64 and and CCONJ iajs-152 38 65 heating heating NOUN iajs-152 38 66 , , PUNCT iajs-152 38 67 of of ADP iajs-152 38 68 cobalt cobalt NOUN iajs-152 38 69 ( ( PUNCT iajs-152 38 70 ii ii NOUN iajs-152 38 71 ) ) PUNCT iajs-152 38 72 chloride chloride NOUN iajs-152 38 73 ( ( PUNCT iajs-152 38 74 0.30 0.30 NUM iajs-152 38 75 g g NOUN iajs-152 38 76 , , PUNCT iajs-152 38 77 1.26 1.26 NUM iajs-152 38 78 mmol mmol NOUN iajs-152 38 79 ) ) PUNCT iajs-152 38 80 hexahydrate hexahydrate NOUN iajs-152 38 81 dissolved dissolve VERB iajs-152 38 82 in in ADP iajs-152 38 83 10 10 NUM iajs-152 38 84 ml ml NOUN iajs-152 38 85 methanol methanol NOUN iajs-152 38 86 was be AUX iajs-152 38 87 added add VERB iajs-152 38 88 to to ADP iajs-152 38 89 the the DET iajs-152 38 90 a a DET iajs-152 38 91 bove bove NOUN iajs-152 38 92 solution solution NOUN iajs-152 38 93 .the .the SCONJ iajs-152 38 94 resulting result VERB iajs-152 38 95 mixture mixture NOUN iajs-152 38 96 was be AUX iajs-152 38 97 refluxed refluxe VERB iajs-152 38 98 for for ADP iajs-152 38 99 2 2 NUM iajs-152 38 100 hrs hrs NOUN iajs-152 38 101 . . PUNCT iajs-152 38 102 , , PUNCT iajs-152 38 103 the the DET iajs-152 38 104 product product NOUN iajs-152 38 105 was be AUX iajs-152 38 106 filtered filter VERB iajs-152 38 107 off off ADP iajs-152 38 108 , , PUNCT iajs-152 38 109 washed wash VERB iajs-152 38 110 with with ADP iajs-152 38 111 absolute absolute ADJ iajs-152 38 112 methanol methanol NOUN iajs-152 38 113 and and CCONJ iajs-152 38 114 recrystallized recrystallize VERB iajs-152 38 115 from from ADP iajs-152 38 116 methanol.yield methanol.yield PROPN iajs-152 38 117 77%,m.p(over 77%,m.p(over NUM iajs-152 38 118 320 320 NUM iajs-152 38 119 c c VERB iajs-152 38 120 dec dec NOUN iajs-152 38 121 ) ) PUNCT iajs-152 38 122 . . PUNCT iajs-152 39 1 synthesis synthesis NOUN iajs-152 39 2 of of ADP iajs-152 39 3 the the DET iajs-152 39 4 complexes complex NOUN iajs-152 39 5 [ [ X iajs-152 39 6 zn(l)(phen)(h2o)cl zn(l)(phen)(h2o)cl X iajs-152 39 7 ] ] PUNCT iajs-152 39 8 , , PUNCT iajs-152 39 9 [ [ X iajs-152 39 10 cd(l)(phen cd(l)(phen ADV iajs-152 39 11 ) ) PUNCT iajs-152 39 12 ( ( PUNCT iajs-152 39 13 h2o h2o PROPN iajs-152 39 14 ) ) PUNCT iajs-152 39 15 cl cl NOUN iajs-152 39 16 ] ] PUNCT iajs-152 39 17 and and CCONJ iajs-152 39 18 [ [ X iajs-152 39 19 hg(l hg(l X iajs-152 39 20 ) ) PUNCT iajs-152 39 21 ( ( PUNCT iajs-152 39 22 phen phen NOUN iajs-152 39 23 ) ) PUNCT iajs-152 39 24 ( ( PUNCT iajs-152 39 25 h2o h2o PROPN iajs-152 39 26 ) ) PUNCT iajs-152 39 27 cl cl NOUN iajs-152 39 28 ] ] PUNCT iajs-152 39 29 a a DET iajs-152 39 30 similar similar ADJ iajs-152 39 31 produce produce NOUN iajs-152 39 32 described describe VERB iajs-152 39 33 to to ADP iajs-152 39 34 that that PRON iajs-152 39 35 mentioned mention VERB iajs-152 39 36 in in ADP iajs-152 39 37 preparation preparation NOUN iajs-152 39 38 of of ADP iajs-152 39 39 coii coii ADJ iajs-152 39 40 complex complex NOUN iajs-152 39 41 was be AUX iajs-152 39 42 used use VERB iajs-152 39 43 to to PART iajs-152 39 44 prepare prepare VERB iajs-152 39 45 the the DET iajs-152 39 46 complexes complex NOUN iajs-152 39 47 of of ADP iajs-152 39 48 [ [ X iajs-152 39 49 hl hl X iajs-152 39 50 ] ] X iajs-152 39 51 with with ADP iajs-152 39 52 [ [ X iajs-152 39 53 znii znii NOUN iajs-152 39 54 , , PUNCT iajs-152 39 55 cdii cdii NOUN iajs-152 39 56 and and CCONJ iajs-152 39 57 hgii],ions hgii],ion NOUN iajs-152 39 58 . . PUNCT iajs-152 40 1 table table NOUN iajs-152 40 2 no.(1 no.(1 NOUN iajs-152 40 3 ) ) PUNCT iajs-152 40 4 shows show VERB iajs-152 40 5 some some DET iajs-152 40 6 physical physical ADJ iajs-152 40 7 properties property NOUN iajs-152 40 8 of of ADP iajs-152 40 9 the the DET iajs-152 40 10 prepared prepared ADJ iajs-152 40 11 [ [ X iajs-152 40 12 hl hl X iajs-152 40 13 ] ] X iajs-152 40 14 , , PUNCT iajs-152 40 15 and and CCONJ iajs-152 40 16 its its PRON iajs-152 40 17 complexes complex NOUN iajs-152 40 18 and and CCONJ iajs-152 40 19 their their PRON iajs-152 40 20 reactants reactant NOUN iajs-152 40 21 quantities quantity NOUN iajs-152 40 22 . . PUNCT iajs-152 41 1 results result NOUN iajs-152 41 2 and and CCONJ iajs-152 41 3 discussion discussion NOUN iajs-152 41 4 mixed mix VERB iajs-152 41 5 potentially potentially ADV iajs-152 41 6 bidentate bidentate ADJ iajs-152 41 7 ligand ligand NOUN iajs-152 41 8 type type NOUN iajs-152 41 9 no no DET iajs-152 41 10 donor donor NOUN iajs-152 41 11 atoms atom NOUN iajs-152 41 12 and and CCONJ iajs-152 41 13 1,10 1,10 NUM iajs-152 41 14 - - NUM iajs-152 41 15 phenanthroline phenanthroline NOUN iajs-152 41 16 with with ADP iajs-152 41 17 metal metal NOUN iajs-152 41 18 salt salt NOUN iajs-152 41 19 were be AUX iajs-152 41 20 used use VERB iajs-152 41 21 in in ADP iajs-152 41 22 a a DET iajs-152 41 23 1:1:1 1:1:1 NUM iajs-152 41 24 molar molar ADJ iajs-152 41 25 ratio ratio NOUN iajs-152 41 26 to to ADP iajs-152 41 27 synthesiz synthesiz ADJ iajs-152 41 28 complexes complex NOUN iajs-152 41 29 using use VERB iajs-152 41 30 methanol methanol NOUN iajs-152 41 31 as as ADP iajs-152 41 32 a a DET iajs-152 41 33 solvent solvent NOUN iajs-152 41 34 as as SCONJ iajs-152 41 35 shown show VERB iajs-152 41 36 in in ADP iajs-152 41 37 schem schem NOUN iajs-152 41 38 no.(2 no.(2 NOUN iajs-152 41 39 ) ) PUNCT iajs-152 41 40 . . PUNCT iajs-152 42 1 the the DET iajs-152 42 2 ligand ligand NOUN iajs-152 42 3 contains contain VERB iajs-152 42 4 labile labile ADJ iajs-152 42 5 proton proton NOUN iajs-152 43 1 [ [ X iajs-152 43 2 hl hl X iajs-152 43 3 ] ] X iajs-152 43 4 and and CCONJ iajs-152 43 5 by by ADP iajs-152 43 6 removing remove VERB iajs-152 43 7 this this DET iajs-152 43 8 proton proton NOUN iajs-152 43 9 an an DET iajs-152 43 10 ionic(-1 ionic(-1 NOUN iajs-152 43 11 ) ) PUNCT iajs-152 43 12 bidentate bidentate NOUN iajs-152 43 13 system system NOUN iajs-152 43 14 is be AUX iajs-152 43 15 formed form VERB iajs-152 43 16 . . PUNCT iajs-152 44 1 the the DET iajs-152 44 2 ligand ligand NOUN iajs-152 44 3 [ [ X iajs-152 44 4 hl hl X iajs-152 44 5 ] ] X iajs-152 44 6 was be AUX iajs-152 44 7 synthesized synthesize VERB iajs-152 44 8 by by ADP iajs-152 44 9 the the DET iajs-152 44 10 reaction reaction NOUN iajs-152 44 11 of of ADP iajs-152 44 12 diazonium diazonium NOUN iajs-152 44 13 salt salt NOUN iajs-152 44 14 with with ADP iajs-152 44 15 1amino-2 1amino-2 NUM iajs-152 44 16 - - PUNCT iajs-152 44 17 naphtol-4 naphtol-4 NUM iajs-152 44 18 - - PUNCT iajs-152 44 19 sulfonic sulfonic ADJ iajs-152 44 20 acid acid NOUN iajs-152 44 21 in in ADP iajs-152 44 22 a a DET iajs-152 44 23 1:1 1:1 NUM iajs-152 44 24 molar molar ADJ iajs-152 44 25 ratio ratio NOUN iajs-152 44 26 using use VERB iajs-152 44 27 methanol methanol NOUN iajs-152 44 28 as as ADP iajs-152 44 29 a a DET iajs-152 44 30 solvent solvent NOUN iajs-152 44 31 as as SCONJ iajs-152 44 32 shown show VERB iajs-152 44 33 in in ADP iajs-152 44 34 schem schem NOUN iajs-152 44 35 no.(1 no.(1 NOUN iajs-152 44 36 ) ) PUNCT iajs-152 44 37 . . PUNCT iajs-152 45 1 i.r i.r PROPN iajs-152 45 2 . . PROPN iajs-152 45 3 spectrum spectrum VERB iajs-152 45 4 for for ADP iajs-152 45 5 ligand ligand NOUN iajs-152 45 6 [ [ X iajs-152 45 7 hl hl X iajs-152 45 8 ] ] X iajs-152 45 9 , , PUNCT iajs-152 45 10 figure figure NOUN iajs-152 45 11 no.(1 no.(1 NOUN iajs-152 45 12 ) ) PUNCT iajs-152 45 13 , , PUNCT iajs-152 45 14 displayed display VERB iajs-152 45 15 a a DET iajs-152 45 16 band band NOUN iajs-152 45 17 at at ADP iajs-152 45 18 ( ( PUNCT iajs-152 45 19 3234.62 3234.62 NUM iajs-152 45 20 ) ) PUNCT iajs-152 45 21 cm–1 cm–1 PROPN iajs-152 45 22 may may AUX iajs-152 45 23 be be AUX iajs-152 45 24 attributed attribute VERB iajs-152 45 25 to to ADP iajs-152 45 26 the the DET iajs-152 45 27 interference interference NOUN iajs-152 45 28 of of ADP iajs-152 45 29 the the DET iajs-152 45 30 v(n.h)asym v(n.h)asym PROPN iajs-152 45 31 and and CCONJ iajs-152 45 32 v(n.h v(n.h PROPN iajs-152 45 33 ) ) PUNCT iajs-152 45 34 sym sym NOUN iajs-152 45 35 bands band NOUN iajs-152 45 36 of of ADP iajs-152 45 37 ( ( PUNCT iajs-152 45 38 nh2 nh2 PROPN iajs-152 45 39 ) ) PUNCT iajs-152 45 40 group group NOUN iajs-152 46 1 [ [ X iajs-152 46 2 23 23 NUM iajs-152 46 3 ] ] PUNCT iajs-152 46 4 .the .the PRON iajs-152 46 5 band band NOUN iajs-152 46 6 at at ADP iajs-152 46 7 ( ( PUNCT iajs-152 46 8 3095.75)cm-1 3095.75)cm-1 PROPN iajs-152 46 9 may may AUX iajs-152 46 10 be be AUX iajs-152 46 11 referred refer VERB iajs-152 46 12 to to ADP iajs-152 46 13 aromatic aromatic ADJ iajs-152 46 14 ( ( PUNCT iajs-152 46 15 c c NOUN iajs-152 46 16 - - PUNCT iajs-152 46 17 h h NOUN iajs-152 46 18 ) ) PUNCT iajs-152 47 1 [ [ X iajs-152 47 2 24 24 NUM iajs-152 47 3 ] ] PUNCT iajs-152 47 4 . . PUNCT iajs-152 48 1 a a DET iajs-152 48 2 broad broad ADJ iajs-152 48 3 band band NOUN iajs-152 48 4 at at ADP iajs-152 48 5 ( ( PUNCT iajs-152 48 6 2912.51)cm-1 2912.51)cm-1 PROPN iajs-152 48 7 may may AUX iajs-152 48 8 refer refer VERB iajs-152 48 9 to to ADP iajs-152 48 10 the the DET iajs-152 48 11 phenolic phenolic ADJ iajs-152 48 12 oh oh INTJ iajs-152 48 13 group group NOUN iajs-152 49 1 [ [ X iajs-152 49 2 25 25 NUM iajs-152 49 3 - - SYM iajs-152 49 4 27 27 NUM iajs-152 49 5 ] ] PUNCT iajs-152 49 6 . . PUNCT iajs-152 50 1 this this DET iajs-152 50 2 band band NOUN iajs-152 50 3 was be AUX iajs-152 50 4 ascribed ascribe VERB iajs-152 50 5 of of ADP iajs-152 50 6 intramolecular intramolecular ADJ iajs-152 50 7 hydrogen hydrogen NOUN iajs-152 50 8 bonding bonding NOUN iajs-152 50 9 ( ( PUNCT iajs-152 50 10 n n CCONJ iajs-152 50 11 … … SYM iajs-152 50 12 ho ho ADJ iajs-152 50 13 ) ) PUNCT iajs-152 50 14 and and CCONJ iajs-152 50 15 ( ( PUNCT iajs-152 50 16 nh nh NOUN iajs-152 50 17 … … PROPN iajs-152 50 18 o o NOUN iajs-152 50 19 - - NOUN iajs-152 50 20 h h NOUN iajs-152 50 21 ) ) PUNCT iajs-152 50 22 groups group NOUN iajs-152 50 23 [ [ X iajs-152 50 24 28 28 NUM iajs-152 50 25 ] ] PUNCT iajs-152 50 26 .the .the PRON iajs-152 50 27 spectrum spectrum PROPN iajs-152 50 28 showed show VERB iajs-152 50 29 a a DET iajs-152 50 30 weak weak ADJ iajs-152 50 31 band band NOUN iajs-152 50 32 at at ADP iajs-152 50 33 ( ( PUNCT iajs-152 50 34 1656.85)cm-1 1656.85)cm-1 NUM iajs-152 50 35 referred refer VERB iajs-152 50 36 to to ADP iajs-152 50 37 the the DET iajs-152 50 38 bending bending NOUN iajs-152 50 39 of of ADP iajs-152 50 40 ( ( PUNCT iajs-152 50 41 n n CCONJ iajs-152 50 42 - - PUNCT iajs-152 50 43 h h NOUN iajs-152 50 44 ) ) PUNCT iajs-152 50 45 group group NOUN iajs-152 50 46 . . PUNCT iajs-152 51 1 the the DET iajs-152 51 2 medium medium NOUN iajs-152 51 3 bands band NOUN iajs-152 51 4 at at ADP iajs-152 51 5 ( ( PUNCT iajs-152 51 6 1598.99 1598.99 NUM iajs-152 51 7 - - SYM iajs-152 51 8 1527.62)cm-1 1527.62)cm-1 PROPN iajs-152 51 9 assigned assign VERB iajs-152 51 10 to to ADP iajs-152 51 11 ( ( PUNCT iajs-152 51 12 c c X iajs-152 51 13 = = SYM iajs-152 51 14 c c NOUN iajs-152 51 15 ) ) PUNCT iajs-152 51 16 stretching stretching NOUN iajs-152 51 17 of of ADP iajs-152 51 18 aromatic aromatic ADJ iajs-152 51 19 rings ring NOUN iajs-152 51 20 [ [ X iajs-152 51 21 24 24 NUM iajs-152 51 22 ] ] PUNCT iajs-152 51 23 . . PUNCT iajs-152 52 1 while while SCONJ iajs-152 52 2 band band NOUN iajs-152 52 3 at at ADP iajs-152 52 4 ( ( PUNCT iajs-152 52 5 1467.83)cm-1 1467.83)cm-1 PROPN iajs-152 52 6 can can AUX iajs-152 52 7 be be AUX iajs-152 52 8 attributed attribute VERB iajs-152 52 9 to to ADP iajs-152 52 10 ( ( PUNCT iajs-152 52 11 n n CCONJ iajs-152 52 12 = = SYM iajs-152 52 13 n n CCONJ iajs-152 52 14 ) ) PUNCT iajs-152 52 15 azo azo NOUN iajs-152 52 16 group group NOUN iajs-152 52 17 [ [ X iajs-152 52 18 29 29 NUM iajs-152 52 19 ] ] PUNCT iajs-152 52 20 . . PUNCT iajs-152 53 1 the the DET iajs-152 53 2 spectrum spectrum NOUN iajs-152 53 3 showed show VERB iajs-152 53 4 band band NOUN iajs-152 53 5 at at ADP iajs-152 53 6 ( ( PUNCT iajs-152 53 7 1352.10)cm-1 1352.10)cm-1 PROPN iajs-152 53 8 attributed attribute VERB iajs-152 53 9 to to ADP iajs-152 53 10 phenolic phenolic NOUN iajs-152 53 11 ( ( PUNCT iajs-152 53 12 c c NOUN iajs-152 53 13 - - PUNCT iajs-152 53 14 o o NOUN iajs-152 53 15 ) ) PUNCT iajs-152 53 16 stretching stretch VERB iajs-152 53 17 [ [ X iajs-152 53 18 23 23 NUM iajs-152 53 19 ] ] PUNCT iajs-152 53 20 . . PUNCT iajs-152 54 1 finally finally ADV iajs-152 54 2 the the DET iajs-152 54 3 spectrum spectrum NOUN iajs-152 54 4 showed show VERB iajs-152 54 5 two two NUM iajs-152 54 6 bands band NOUN iajs-152 54 7 at at ADP iajs-152 54 8 ( ( PUNCT iajs-152 54 9 1166.93 1166.93 NUM iajs-152 54 10 and and CCONJ iajs-152 54 11 1043.49)cm-1can 1043.49)cm-1can NUM iajs-152 54 12 be be AUX iajs-152 54 13 attributed attribute VERB iajs-152 54 14 to to ADP iajs-152 54 15 the the DET iajs-152 54 16 v(so3h)asym v(so3h)asym PROPN iajs-152 54 17 , , PUNCT iajs-152 54 18 v(so3h)sym v(so3h)sym PROPN iajs-152 54 19 stretching stretch VERB iajs-152 54 20 respectively respectively ADV iajs-152 54 21 [ [ X iajs-152 54 22 30 30 NUM iajs-152 54 23 ] ] PUNCT iajs-152 54 24 . . PUNCT iajs-152 55 1 the the DET iajs-152 55 2 spectrum spectrum NOUN iajs-152 55 3 of of ADP iajs-152 55 4 the the DET iajs-152 55 5 1,10 1,10 NUM iajs-152 55 6 - - PUNCT iajs-152 55 7 phenanthroline phenanthroline NOUN iajs-152 55 8 . . PUNCT iajs-152 56 1 figure figure NOUN iajs-152 56 2 no.(2 no.(2 NOUN iajs-152 56 3 ) ) PUNCT iajs-152 56 4 shows show VERB iajs-152 56 5 the the DET iajs-152 56 6 band band NOUN iajs-152 56 7 at at ADP iajs-152 56 8 ( ( PUNCT iajs-152 56 9 3363.86)cm-1 3363.86)cm-1 PROPN iajs-152 56 10 attributed attribute VERB iajs-152 56 11 to to ADP iajs-152 56 12 oh oh PROPN iajs-152 56 13 group group NOUN iajs-152 56 14 of of ADP iajs-152 56 15 the the DET iajs-152 56 16 adsorbed adsorb VERB iajs-152 56 17 water water NOUN iajs-152 56 18 molecules molecule NOUN iajs-152 56 19 ( ( PUNCT iajs-152 56 20 c12h8n2.h2o c12h8n2.h2o PROPN iajs-152 56 21 ) ) PUNCT iajs-152 56 22 and and CCONJ iajs-152 56 23 bands band NOUN iajs-152 56 24 at at ADP iajs-152 56 25 ( ( PUNCT iajs-152 56 26 3062.96)cm-1 3062.96)cm-1 NUM iajs-152 56 27 , , PUNCT iajs-152 56 28 ( ( PUNCT iajs-152 56 29 1645.28)cm-1 1645.28)cm-1 NUM iajs-152 56 30 and and CCONJ iajs-152 56 31 ( ( PUNCT iajs-152 56 32 1585.49 1585.49 NUM iajs-152 56 33 - - SYM iajs-152 56 34 1525.70)cm-1 1525.70)cm-1 NUM iajs-152 56 35 may may AUX iajs-152 56 36 be be AUX iajs-152 56 37 assigned assign VERB iajs-152 56 38 to to ADP iajs-152 56 39 v(c v(c ADJ iajs-152 56 40 - - PUNCT iajs-152 56 41 h)aro h)aro NOUN iajs-152 56 42 . . PUNCT iajs-152 57 1 , , PUNCT iajs-152 57 2 v(c v(c PROPN iajs-152 57 3 = = SYM iajs-152 57 4 n)phen n)phen NOUN iajs-152 57 5 . . PUNCT iajs-152 58 1 and and CCONJ iajs-152 58 2 v(c v(c PROPN iajs-152 58 3 = = NOUN iajs-152 58 4 c)aro c)aro NOUN iajs-152 58 5 groups group NOUN iajs-152 58 6 respectively respectively ADV iajs-152 58 7 , , PUNCT iajs-152 58 8 while while SCONJ iajs-152 58 9 the the DET iajs-152 58 10 bands band NOUN iajs-152 58 11 at at ADP iajs-152 58 12 ( ( PUNCT iajs-152 58 13 1344.38 1344.38 NUM iajs-152 58 14 - - SYM iajs-152 58 15 1217.08)cm-1 1217.08)cm-1 NUM iajs-152 58 16 may may AUX iajs-152 58 17 be be AUX iajs-152 58 18 assigned assign VERB iajs-152 58 19 to to ADP iajs-152 58 20 the the DET iajs-152 58 21 v(c v(c PROPN iajs-152 58 22 - - PUNCT iajs-152 58 23 n n CCONJ iajs-152 58 24 ) ) PUNCT iajs-152 58 25 stretching stretching NOUN iajs-152 58 26 , , PUNCT iajs-152 58 27 the the DET iajs-152 58 28 assignment assignment NOUN iajs-152 58 29 of of ADP iajs-152 58 30 characteristic characteristic ADJ iajs-152 58 31 bands band NOUN iajs-152 58 32 are be AUX iajs-152 58 33 summarized summarize VERB iajs-152 58 34 in in ADP iajs-152 58 35 table table NOUN iajs-152 58 36 no.(2 no.(2 NOUN iajs-152 58 37 ) ) PUNCT iajs-152 58 38 . . PUNCT iajs-152 59 1 the the DET iajs-152 59 2 i.r i.r PROPN iajs-152 59 3 . . PROPN iajs-152 59 4 spectra spectra PROPN iajs-152 59 5 for for ADP iajs-152 59 6 complexes complex NOUN iajs-152 59 7 of of ADP iajs-152 59 8 coii coii PROPN iajs-152 59 9 , , PUNCT iajs-152 59 10 znii znii NOUN iajs-152 59 11 , , PUNCT iajs-152 59 12 cdii cdii NOUN iajs-152 59 13 and and CCONJ iajs-152 59 14 hgii hgii NOUN iajs-152 59 15 are be AUX iajs-152 59 16 shown show VERB iajs-152 59 17 in in ADP iajs-152 59 18 figures figure NOUN iajs-152 59 19 no.(3),(4),(5 no.(3),(4),(5 NOUN iajs-152 59 20 ) ) PUNCT iajs-152 59 21 and and CCONJ iajs-152 59 22 ( ( PUNCT iajs-152 59 23 6 6 NUM iajs-152 59 24 ) ) PUNCT iajs-152 59 25 respectively respectively ADV iajs-152 59 26 . . PUNCT iajs-152 60 1 the the DET iajs-152 60 2 bands band NOUN iajs-152 60 3 arising arise VERB iajs-152 60 4 due due ADP iajs-152 60 5 to to ADP iajs-152 60 6 vibrational vibrational ADJ iajs-152 60 7 v(c v(c ADJ iajs-152 60 8 = = SYM iajs-152 60 9 n)phen n)phen NOUN iajs-152 60 10 . . PUNCT iajs-152 61 1 mode mode PROPN iajs-152 61 2 at at ADP iajs-152 61 3 ( ( PUNCT iajs-152 61 4 1645.28)cm-1 1645.28)cm-1 NUM iajs-152 61 5 frequency frequency NOUN iajs-152 61 6 in in ADP iajs-152 61 7 the the DET iajs-152 61 8 free free ADJ iajs-152 61 9 1,10 1,10 NUM iajs-152 61 10 - - ADJ iajs-152 61 11 phenanthroline phenanthroline NOUN iajs-152 61 12 were be AUX iajs-152 61 13 observed observe VERB iajs-152 61 14 to to PART iajs-152 61 15 be be AUX iajs-152 61 16 shifted shift VERB iajs-152 61 17 to to ADP iajs-152 61 18 lower low ADJ iajs-152 61 19 frequencies frequency NOUN iajs-152 61 20 , , PUNCT iajs-152 61 21 and and CCONJ iajs-152 61 22 appears appear VERB iajs-152 61 23 at at ADP iajs-152 61 24 ( ( PUNCT iajs-152 61 25 1620.21)cm-1,(1624.06)cm-1 1620.21)cm-1,(1624.06)cm-1 NUM iajs-152 61 26 , , PUNCT iajs-152 61 27 ( ( PUNCT iajs-152 61 28 1618)cm-1 1618)cm-1 NUM iajs-152 61 29 and and CCONJ iajs-152 61 30 ( ( PUNCT iajs-152 61 31 1614.42)cm-1 1614.42)cm-1 NUM iajs-152 61 32 for for ADP iajs-152 61 33 complexes complex NOUN iajs-152 61 34 of of ADP iajs-152 61 35 coii coii PROPN iajs-152 61 36 , , PUNCT iajs-152 61 37 znii znii NOUN iajs-152 61 38 , , PUNCT iajs-152 61 39 cdii cdii NOUN iajs-152 61 40 and and CCONJ iajs-152 61 41 hgii hgii NOUN iajs-152 61 42 respectively respectively ADV iajs-152 61 43 .the .the DET iajs-152 61 44 movement movement NOUN iajs-152 61 45 of of ADP iajs-152 61 46 v(n v(n NOUN iajs-152 61 47 = = SYM iajs-152 61 48 n n CCONJ iajs-152 61 49 ) ) PUNCT iajs-152 61 50 stretch stretch NOUN iajs-152 61 51 of of ADP iajs-152 61 52 the the DET iajs-152 61 53 complexes complex NOUN iajs-152 61 54 to to ADP iajs-152 61 55 relatively relatively ADV iajs-152 61 56 lower low ADJ iajs-152 61 57 frequencies frequency NOUN iajs-152 61 58 , , PUNCT iajs-152 61 59 at at ADP iajs-152 61 60 ( ( PUNCT iajs-152 61 61 1425.04 1425.04 NUM iajs-152 61 62 ) ) PUNCT iajs-152 61 63 , , PUNCT iajs-152 61 64 ( ( PUNCT iajs-152 61 65 1423.47 1423.47 NUM iajs-152 61 66 ) ) PUNCT iajs-152 61 67 , , PUNCT iajs-152 61 68 ( ( PUNCT iajs-152 61 69 1421 1421 NUM iajs-152 61 70 ) ) PUNCT iajs-152 61 71 and and CCONJ iajs-152 61 72 ( ( PUNCT iajs-152 61 73 1450.47)cm-1 1450.47)cm-1 PROPN iajs-152 61 74 for for ADP iajs-152 61 75 complexes complex NOUN iajs-152 61 76 coii coii PROPN iajs-152 61 77 , , PUNCT iajs-152 61 78 znii znii NOUN iajs-152 61 79 , , PUNCT iajs-152 61 80 cdii cdii NOUN iajs-152 61 81 and and CCONJ iajs-152 61 82 hgii hgii NOUN iajs-152 61 83 respectively respectively ADV iajs-152 61 84 , , PUNCT iajs-152 61 85 compared compare VERB iajs-152 61 86 to to ADP iajs-152 61 87 that that PRON iajs-152 61 88 of of ADP iajs-152 61 89 free free ADJ iajs-152 61 90 dyes dye NOUN iajs-152 61 91 or or CCONJ iajs-152 61 92 ligand ligand NOUN iajs-152 61 93 indicates indicate VERB iajs-152 61 94 coordination coordination NOUN iajs-152 61 95 via via ADP iajs-152 61 96 the the DET iajs-152 61 97 n n NOUN iajs-152 61 98 = = NOUN iajs-152 61 99 n n PROPN iajs-152 61 100 group group NOUN iajs-152 62 1 [ [ X iajs-152 62 2 31 31 NUM iajs-152 62 3 - - SYM iajs-152 62 4 33 33 NUM iajs-152 62 5 ] ] PUNCT iajs-152 62 6 . . PUNCT iajs-152 63 1 on on ADP iajs-152 63 2 the the DET iajs-152 63 3 other other ADJ iajs-152 63 4 hand hand NOUN iajs-152 63 5 the the DET iajs-152 63 6 band band NOUN iajs-152 63 7 at at ADP iajs-152 63 8 ( ( PUNCT iajs-152 63 9 1352.10)cm-1 1352.10)cm-1 NUM iajs-152 63 10 referred refer VERB iajs-152 63 11 to to ADP iajs-152 63 12 v(c v(c PROPN iajs-152 63 13 - - PUNCT iajs-152 63 14 o o NOUN iajs-152 63 15 ) ) PUNCT iajs-152 63 16 of of ADP iajs-152 63 17 free free ADJ iajs-152 63 18 ligand ligand NOUN iajs-152 63 19 , , PUNCT iajs-152 63 20 shifted shift VERB iajs-152 63 21 to to ADP iajs-152 63 22 lower low ADJ iajs-152 63 23 frequency frequency NOUN iajs-152 63 24 and and CCONJ iajs-152 63 25 appeared appear VERB iajs-152 63 26 at at ADP iajs-152 63 27 ( ( PUNCT iajs-152 63 28 1280.37 1280.37 NUM iajs-152 63 29 ) ) PUNCT iajs-152 63 30 , , PUNCT iajs-152 63 31 ( ( PUNCT iajs-152 63 32 1296.16 1296.16 NUM iajs-152 63 33 ) ) PUNCT iajs-152 63 34 , , PUNCT iajs-152 63 35 ( ( PUNCT iajs-152 63 36 1230 1230 NUM iajs-152 63 37 ) ) PUNCT iajs-152 63 38 and and CCONJ iajs-152 63 39 ( ( PUNCT iajs-152 63 40 1257.59)cm-1 1257.59)cm-1 NUM iajs-152 63 41 for for ADP iajs-152 63 42 complexes complex NOUN iajs-152 63 43 of of ADP iajs-152 63 44 coii coii PROPN iajs-152 63 45 , , PUNCT iajs-152 63 46 znii znii NOUN iajs-152 63 47 , , PUNCT iajs-152 63 48 cdii cdii NOUN iajs-152 63 49 and and CCONJ iajs-152 63 50 hgii hgii NOUN iajs-152 63 51 respectively.the respectively.the DET iajs-152 63 52 see see NOUN iajs-152 63 53 result result NOUN iajs-152 63 54 indicaties indicatie VERB iajs-152 63 55 the the DET iajs-152 63 56 involvement involvement NOUN iajs-152 63 57 of of ADP iajs-152 63 58 nitrogen nitrogen NOUN iajs-152 63 59 of of ADP iajs-152 63 60 pyridime pyridime NOUN iajs-152 63 61 ring ring NOUN iajs-152 63 62 oxygen oxygen NOUN iajs-152 63 63 and and CCONJ iajs-152 63 64 nitrogen nitrogen NOUN iajs-152 63 65 the the DET iajs-152 63 66 azo azo NOUN iajs-152 63 67 ligand ligand NOUN iajs-152 63 68 in in ADP iajs-152 63 69 the the DET iajs-152 63 70 190 190 NUM iajs-152 63 71 | | NOUN iajs-152 63 72 chemistry chemistry NOUN iajs-152 63 73 2015 2015 NUM iajs-152 63 74 ) ) PUNCT iajs-152 63 75 عام عام ADP iajs-152 63 76 3العدد 3العدد NUM iajs-152 63 77 ( ( PUNCT iajs-152 63 78 28مجلة 28مجلة X iajs-152 63 79 إبن إبن VERB iajs-152 64 1 الھيثم الھيثم NOUN iajs-152 64 2 للعلوم للعلوم NOUN iajs-152 64 3 الصرفة الصرفة NOUN iajs-152 65 1 و و PRON iajs-152 65 2 التطبيقية التطبيقية ADV iajs-152 65 3 المجلد المجلد VERB iajs-152 65 4 ibn ibn PROPN iajs-152 65 5 al al PROPN iajs-152 65 6 - - PUNCT iajs-152 65 7 haitham haitham PROPN iajs-152 65 8 jour jour X iajs-152 65 9 . . PROPN iajs-152 66 1 for for ADP iajs-152 66 2 pure pure ADJ iajs-152 66 3 & & CCONJ iajs-152 66 4 appl appl PROPN iajs-152 66 5 . . PUNCT iajs-152 67 1 sci sci PROPN iajs-152 67 2 . . PUNCT iajs-152 67 3 vol vol NOUN iajs-152 67 4 . . PROPN iajs-152 68 1 28 28 NUM iajs-152 68 2 ( ( PUNCT iajs-152 68 3 3 3 NUM iajs-152 68 4 ) ) SYM iajs-152 68 5 2015 2015 NUM iajs-152 68 6 complex complex ADJ iajs-152 68 7 formation[34 formation[34 PROPN iajs-152 68 8 - - PUNCT iajs-152 68 9 36 36 NUM iajs-152 68 10 ] ] PUNCT iajs-152 68 11 . . PUNCT iajs-152 69 1 the the DET iajs-152 69 2 spectra spectra NOUN iajs-152 69 3 of of ADP iajs-152 69 4 complexes complex NOUN iajs-152 69 5 displayed display VERB iajs-152 69 6 a a DET iajs-152 69 7 band band NOUN iajs-152 69 8 at at ADP iajs-152 69 9 ( ( PUNCT iajs-152 69 10 3215.34),(3307.92 3215.34),(3307.92 NUM iajs-152 69 11 ) ) PUNCT iajs-152 69 12 and and CCONJ iajs-152 69 13 ( ( PUNCT iajs-152 69 14 3273.20)cm-1 3273.20)cm-1 NUM iajs-152 69 15 for for ADP iajs-152 69 16 complexes complex NOUN iajs-152 69 17 of of ADP iajs-152 69 18 co co NOUN iajs-152 69 19 , , PUNCT iajs-152 69 20 zn zn PROPN iajs-152 69 21 , , PUNCT iajs-152 69 22 cd cd PROPN iajs-152 69 23 and and CCONJ iajs-152 69 24 hg hg NOUN iajs-152 69 25 respectively respectively ADV iajs-152 69 26 can can AUX iajs-152 69 27 be be AUX iajs-152 69 28 attributed attribute VERB iajs-152 69 29 to to ADP iajs-152 69 30 v(nh2 v(nh2 NOUN iajs-152 69 31 ) ) PUNCT iajs-152 69 32 group[24 group[24 NOUN iajs-152 69 33 ] ] PUNCT iajs-152 69 34 . . PUNCT iajs-152 70 1 while while SCONJ iajs-152 70 2 the the DET iajs-152 70 3 band band NOUN iajs-152 70 4 at at ADP iajs-152 70 5 ( ( PUNCT iajs-152 70 6 3431)cm-1 3431)cm-1 NUM iajs-152 70 7 in in ADP iajs-152 70 8 cd cd PROPN iajs-152 70 9 complex complex NOUN iajs-152 70 10 spectrum spectrum NOUN iajs-152 70 11 may may AUX iajs-152 70 12 assign assign VERB iajs-152 70 13 to to PART iajs-152 70 14 interference interference VERB iajs-152 70 15 of of ADP iajs-152 70 16 v(nh2 v(nh2 NOUN iajs-152 70 17 ) ) PUNCT iajs-152 70 18 stretch stretch NOUN iajs-152 70 19 with with ADP iajs-152 70 20 the the DET iajs-152 70 21 oh oh PROPN iajs-152 70 22 group group NOUN iajs-152 70 23 of of ADP iajs-152 70 24 the the DET iajs-152 70 25 coordinated coordinate VERB iajs-152 70 26 water water NOUN iajs-152 70 27 molecule molecule NOUN iajs-152 70 28 [ [ X iajs-152 70 29 23].the 23].the DET iajs-152 70 30 spectrum spectrum NOUN iajs-152 70 31 of of ADP iajs-152 70 32 co co PROPN iajs-152 70 33 complex complex PROPN iajs-152 70 34 displayed display VERB iajs-152 70 35 a a DET iajs-152 70 36 band band NOUN iajs-152 70 37 at at ADP iajs-152 70 38 ( ( PUNCT iajs-152 70 39 3379.29 3379.29 NUM iajs-152 70 40 ) ) PUNCT iajs-152 70 41 cm-1 cm-1 PUNCT iajs-152 70 42 may may AUX iajs-152 70 43 indicates indicate VERB iajs-152 70 44 oh oh INTJ iajs-152 70 45 group group NOUN iajs-152 70 46 of of ADP iajs-152 70 47 the the DET iajs-152 70 48 coordinated coordinate VERB iajs-152 70 49 water water NOUN iajs-152 70 50 molecules[23].finally molecules[23].finally ADV iajs-152 70 51 the the DET iajs-152 70 52 spectra spectra NOUN iajs-152 70 53 showed show VERB iajs-152 70 54 new new ADJ iajs-152 70 55 bands band NOUN iajs-152 70 56 at at ADP iajs-152 70 57 [ [ X iajs-152 70 58 ( ( PUNCT iajs-152 70 59 653.87 653.87 NUM iajs-152 70 60 , , PUNCT iajs-152 70 61 657.73 657.73 NUM iajs-152 70 62 , , PUNCT iajs-152 70 63 675 675 NUM iajs-152 70 64 and and CCONJ iajs-152 70 65 665.44 665.44 NUM iajs-152 70 66 ) ) PUNCT iajs-152 70 67 ] ] PUNCT iajs-152 70 68 ; ; PUNCT iajs-152 71 1 [ [ X iajs-152 71 2 ( ( PUNCT iajs-152 71 3 601.79 601.79 NUM iajs-152 71 4 , , PUNCT iajs-152 71 5 634.58 634.58 NUM iajs-152 71 6 , , PUNCT iajs-152 71 7 621 621 NUM iajs-152 71 8 and and CCONJ iajs-152 71 9 663.15 663.15 NUM iajs-152 71 10 ) ) PUNCT iajs-152 71 11 ] ] PUNCT iajs-152 71 12 and and CCONJ iajs-152 71 13 [ [ X iajs-152 71 14 ( ( PUNCT iajs-152 71 15 551.64 551.64 NUM iajs-152 71 16 , , PUNCT iajs-152 71 17 611.43 611.43 NUM iajs-152 71 18 , , PUNCT iajs-152 71 19 523 523 NUM iajs-152 71 20 and and CCONJ iajs-152 71 21 561.29 561.29 NUM iajs-152 71 22 ) ) PUNCT iajs-152 71 23 ] ] PUNCT iajs-152 71 24 cm-1 cm-1 X iajs-152 71 25 can can AUX iajs-152 71 26 be be AUX iajs-152 71 27 refer refer VERB iajs-152 71 28 to to ADP iajs-152 71 29 v(m v(m NOUN iajs-152 71 30 - - PUNCT iajs-152 71 31 n)azo n)azo ADV iajs-152 71 32 . . NOUN iajs-152 71 33 , , PUNCT iajs-152 71 34 v(m v(m NOUN iajs-152 71 35 - - PUNCT iajs-152 71 36 n)phen n)phen NOUN iajs-152 71 37 . . PUNCT iajs-152 72 1 and and CCONJ iajs-152 72 2 v(m v(m NOUN iajs-152 72 3 - - PUNCT iajs-152 72 4 o o NOUN iajs-152 72 5 ) ) PUNCT iajs-152 72 6 for for ADP iajs-152 72 7 complexes complex NOUN iajs-152 72 8 co co PROPN iajs-152 72 9 , , PUNCT iajs-152 72 10 zn zn PROPN iajs-152 72 11 , , PUNCT iajs-152 72 12 cd cd PROPN iajs-152 72 13 and and CCONJ iajs-152 72 14 hg hg NOUN iajs-152 72 15 respectively respectively ADV iajs-152 72 16 . . PUNCT iajs-152 73 1 the the DET iajs-152 73 2 new new ADJ iajs-152 73 3 bands band NOUN iajs-152 73 4 also also ADV iajs-152 73 5 supported support VERB iajs-152 73 6 the the DET iajs-152 73 7 coordination coordination NOUN iajs-152 73 8 of of ADP iajs-152 73 9 the the DET iajs-152 73 10 ligand ligand NOUN iajs-152 73 11 to to ADP iajs-152 73 12 the the DET iajs-152 73 13 metal metal NOUN iajs-152 73 14 center center NOUN iajs-152 73 15 through through ADP iajs-152 73 16 azo azo PROPN iajs-152 73 17 group group PROPN iajs-152 73 18 nitrogen nitrogen PROPN iajs-152 73 19 , , PUNCT iajs-152 73 20 phen phen PROPN iajs-152 73 21 . . PUNCT iajs-152 74 1 group group NOUN iajs-152 74 2 nitrogens nitrogen NOUN iajs-152 74 3 and and CCONJ iajs-152 74 4 phenolic phenolic ADJ iajs-152 74 5 oxygen oxygen NOUN iajs-152 74 6 atoms atom NOUN iajs-152 74 7 . . PUNCT iajs-152 75 1 these these DET iajs-152 75 2 results result NOUN iajs-152 75 3 are be AUX iajs-152 75 4 supported support VERB iajs-152 75 5 by by ADP iajs-152 75 6 several several ADJ iajs-152 75 7 reports report NOUN iajs-152 75 8 [ [ PUNCT iajs-152 75 9 37,38 37,38 NOUN iajs-152 75 10 ] ] PUNCT iajs-152 75 11 . . PUNCT iajs-152 76 1 the the DET iajs-152 76 2 characteristic characteristic ADJ iajs-152 76 3 bands band NOUN iajs-152 76 4 are be AUX iajs-152 76 5 summarized summarize VERB iajs-152 76 6 in in ADP iajs-152 76 7 table table NOUN iajs-152 76 8 no.(2 no.(2 NOUN iajs-152 76 9 ) ) PUNCT iajs-152 76 10 . . PUNCT iajs-152 77 1 the the DET iajs-152 77 2 u.v u.v PROPN iajs-152 77 3 - - PUNCT iajs-152 77 4 vis vis X iajs-152 77 5 spectrum spectrum NOUN iajs-152 77 6 for for ADP iajs-152 77 7 [ [ X iajs-152 77 8 hl hl X iajs-152 77 9 ] ] X iajs-152 77 10 , , PUNCT iajs-152 77 11 figure figure NOUN iajs-152 77 12 no.(7 no.(7 NOUN iajs-152 77 13 ) ) PUNCT iajs-152 77 14 , , PUNCT iajs-152 77 15 shows show VERB iajs-152 77 16 peak peak NOUN iajs-152 77 17 at at ADP iajs-152 77 18 ( ( PUNCT iajs-152 77 19 253 253 NUM iajs-152 77 20 nm nm NOUN iajs-152 77 21 ) ) PUNCT iajs-152 77 22 ( ( PUNCT iajs-152 77 23 39525 39525 NUM iajs-152 77 24 cm-1 cm-1 NOUN iajs-152 77 25 ) ) PUNCT iajs-152 77 26 ( ( PUNCT iajs-152 77 27 max= max= VERB iajs-152 77 28 3843molar-1 3843molar-1 NUM iajs-152 77 29 cm-1 cm-1 NOUN iajs-152 77 30 ) ) PUNCT iajs-152 77 31 assigned assign VERB iajs-152 77 32 to to ADP iajs-152 77 33 – – NOUN iajs-152 77 34 * * PUNCT iajs-152 77 35 transition transition NOUN iajs-152 77 36 of of ADP iajs-152 77 37 the the DET iajs-152 77 38 aromatic aromatic ADJ iajs-152 77 39 ring ring NOUN iajs-152 77 40 [ [ X iajs-152 77 41 23 23 NUM iajs-152 77 42 ] ] PUNCT iajs-152 77 43 . . PUNCT iajs-152 78 1 peak peak NOUN iajs-152 78 2 at at ADP iajs-152 78 3 ( ( PUNCT iajs-152 78 4 333 333 NUM iajs-152 78 5 nm nm NOUN iajs-152 78 6 ) ) PUNCT iajs-152 78 7 ( ( PUNCT iajs-152 78 8 30030 30030 NUM iajs-152 78 9 cm-1 cm-1 NOUN iajs-152 78 10 ) ) PUNCT iajs-152 78 11 ( ( PUNCT iajs-152 78 12 max= max= PROPN iajs-152 78 13 2750molar-1 2750molar-1 NUM iajs-152 78 14 cm-1 cm-1 NOUN iajs-152 78 15 ) ) PUNCT iajs-152 78 16 assigned assign VERB iajs-152 78 17 n– n– NOUN iajs-152 78 18 * * SYM iajs-152 78 19 transition transition NOUN iajs-152 78 20 . . PUNCT iajs-152 79 1 finally finally ADV iajs-152 79 2 peak peak VERB iajs-152 79 3 at(437nm)(22883 at(437nm)(22883 PROPN iajs-152 79 4 cm-1)(max= cm-1)(max= ADJ iajs-152 79 5 1063molar-1cm-1 1063molar-1cm-1 NUM iajs-152 79 6 in in ADP iajs-152 79 7 ligand ligand NOUN iajs-152 79 8 spectrum spectrum NOUN iajs-152 79 9 may may AUX iajs-152 79 10 be be AUX iajs-152 79 11 attributed attribute VERB iajs-152 79 12 to to ADP iajs-152 79 13 the the DET iajs-152 79 14 azo azo NOUN iajs-152 79 15 group group NOUN iajs-152 79 16 ( ( PUNCT iajs-152 79 17 n n CCONJ iajs-152 79 18 = = SYM iajs-152 79 19 n n CCONJ iajs-152 79 20 ) ) PUNCT iajs-152 80 1 [ [ X iajs-152 80 2 27 27 NUM iajs-152 80 3 ] ] PUNCT iajs-152 80 4 . . PUNCT iajs-152 81 1 u.v u.v PROPN iajs-152 81 2 - - PUNCT iajs-152 81 3 vis vis X iajs-152 81 4 spectrum spectrum NOUN iajs-152 81 5 for for ADP iajs-152 81 6 1,10 1,10 NUM iajs-152 81 7 - - ADJ iajs-152 81 8 phenanthroline phenanthroline NOUN iajs-152 81 9 , , PUNCT iajs-152 81 10 figure figure NOUN iajs-152 81 11 no.(8 no.(8 PROPN iajs-152 81 12 ) ) PUNCT iajs-152 81 13 , , PUNCT iajs-152 81 14 shows show VERB iajs-152 81 15 peak peak NOUN iajs-152 81 16 of of ADP iajs-152 81 17 shortest short ADJ iajs-152 81 18 wave wave NOUN iajs-152 81 19 length length NOUN iajs-152 81 20 presenting present VERB iajs-152 81 21 at at ADP iajs-152 81 22 ( ( PUNCT iajs-152 81 23 257 257 NUM iajs-152 81 24 nm nm NOUN iajs-152 81 25 ) ) PUNCT iajs-152 81 26 ( ( PUNCT iajs-152 81 27 38910 38910 NUM iajs-152 81 28 cm-1 cm-1 NOUN iajs-152 81 29 ) ) PUNCT iajs-152 81 30 ( ( PUNCT iajs-152 81 31 max= max= PROPN iajs-152 81 32 1352molar-1 1352molar-1 NUM iajs-152 81 33 cm-1 cm-1 NOUN iajs-152 81 34 ) ) PUNCT iajs-152 81 35 may may AUX iajs-152 81 36 be be AUX iajs-152 81 37 assigned assign VERB iajs-152 81 38 to to ADP iajs-152 81 39 over over ADP iajs-152 81 40 lape lape NOUN iajs-152 81 41 of of ADP iajs-152 81 42 n– n– NOUN iajs-152 81 43 * * NOUN iajs-152 81 44 and and CCONJ iajs-152 81 45 – – NOUN iajs-152 81 46 * * PUNCT iajs-152 81 47 transition transition NOUN iajs-152 81 48 , , PUNCT iajs-152 82 1 [ [ X iajs-152 82 2 39 39 NUM iajs-152 82 3 - - SYM iajs-152 82 4 41 41 NUM iajs-152 82 5 ] ] PUNCT iajs-152 82 6 .the .the PUNCT iajs-152 82 7 absorption absorption NOUN iajs-152 82 8 data datum NOUN iajs-152 82 9 of of ADP iajs-152 82 10 the the DET iajs-152 82 11 ligand ligand NOUN iajs-152 82 12 and and CCONJ iajs-152 82 13 1,10 1,10 NUM iajs-152 82 14 - - NUM iajs-152 82 15 phenanthroline phenanthroline NOUN iajs-152 82 16 are be AUX iajs-152 82 17 given give VERB iajs-152 82 18 in in ADP iajs-152 82 19 table table NOUN iajs-152 82 20 no.(3 no.(3 PROPN iajs-152 82 21 ) ) PUNCT iajs-152 82 22 figures figure NOUN iajs-152 82 23 no.(9),(10 no.(9),(10 VERB iajs-152 82 24 ) ) PUNCT iajs-152 82 25 , , PUNCT iajs-152 82 26 ( ( PUNCT iajs-152 82 27 11 11 NUM iajs-152 82 28 ) ) PUNCT iajs-152 82 29 and and CCONJ iajs-152 82 30 ( ( PUNCT iajs-152 82 31 12 12 NUM iajs-152 82 32 ) ) PUNCT iajs-152 82 33 show show VERB iajs-152 82 34 the the DET iajs-152 82 35 ( ( PUNCT iajs-152 82 36 u.v u.v PROPN iajs-152 82 37 - - PUNCT iajs-152 82 38 vis vis X iajs-152 82 39 ) ) PUNCT iajs-152 82 40 spectra spectra NOUN iajs-152 82 41 of of ADP iajs-152 82 42 the the DET iajs-152 82 43 complexes complex NOUN iajs-152 82 44 co co NOUN iajs-152 82 45 , , PUNCT iajs-152 82 46 zn zn PROPN iajs-152 82 47 , , PUNCT iajs-152 82 48 cd cd PROPN iajs-152 82 49 and and CCONJ iajs-152 82 50 hg hg NOUN iajs-152 82 51 respectively respectively ADV iajs-152 82 52 . . PUNCT iajs-152 83 1 table table NOUN iajs-152 83 2 no.(3 no.(3 NOUN iajs-152 83 3 ) ) PUNCT iajs-152 83 4 summarized summarize VERB iajs-152 83 5 the the DET iajs-152 83 6 absorption absorption NOUN iajs-152 83 7 peaks peak NOUN iajs-152 83 8 of of ADP iajs-152 83 9 the the DET iajs-152 83 10 complexes complex NOUN iajs-152 83 11 , , PUNCT iajs-152 83 12 in in ADP iajs-152 83 13 each each DET iajs-152 83 14 case case NOUN iajs-152 83 15 the the DET iajs-152 83 16 spectrum spectrum NOUN iajs-152 83 17 showed show VERB iajs-152 83 18 intense intense ADJ iajs-152 83 19 peaks peak NOUN iajs-152 83 20 in in ADP iajs-152 83 21 the the DET iajs-152 83 22 ( ( PUNCT iajs-152 83 23 u.v u.v PROPN iajs-152 83 24 ) ) PUNCT iajs-152 83 25 region region NOUN iajs-152 83 26 at at ADP iajs-152 83 27 ( ( PUNCT iajs-152 83 28 260 260 NUM iajs-152 83 29 nm nm NOUN iajs-152 83 30 ) ) PUNCT iajs-152 83 31 ( ( PUNCT iajs-152 83 32 38461 38461 NUM iajs-152 83 33 cm-1 cm-1 NOUN iajs-152 83 34 ) ) PUNCT iajs-152 83 35 ( ( PUNCT iajs-152 83 36 max= max= PROPN iajs-152 83 37 3933molar-1 3933molar-1 NUM iajs-152 83 38 cm-1 cm-1 NOUN iajs-152 83 39 ) ) PUNCT iajs-152 83 40 ; ; PUNCT iajs-152 83 41 ( ( PUNCT iajs-152 83 42 298 298 NUM iajs-152 83 43 nm nm NOUN iajs-152 83 44 ) ) PUNCT iajs-152 83 45 ( ( PUNCT iajs-152 83 46 33557 33557 NUM iajs-152 83 47 cm-1 cm-1 NOUN iajs-152 83 48 ) ) PUNCT iajs-152 83 49 ( ( PUNCT iajs-152 83 50 max= max= VERB iajs-152 83 51 3887molar-1 3887molar-1 NUM iajs-152 83 52 cm-1 cm-1 NOUN iajs-152 83 53 ) ) PUNCT iajs-152 83 54 ; ; PUNCT iajs-152 83 55 ( ( PUNCT iajs-152 83 56 244 244 NUM iajs-152 83 57 nm nm NOUN iajs-152 83 58 ) ) PUNCT iajs-152 83 59 ( ( PUNCT iajs-152 83 60 40983 40983 NUM iajs-152 83 61 cm-1 cm-1 NOUN iajs-152 83 62 ) ) PUNCT iajs-152 83 63 ( ( PUNCT iajs-152 83 64 max= max= PROPN iajs-152 83 65 1756molar-1 1756molar-1 NUM iajs-152 83 66 cm-1 cm-1 NOUN iajs-152 83 67 ) ) PUNCT iajs-152 83 68 and and CCONJ iajs-152 83 69 ( ( PUNCT iajs-152 83 70 228 228 NUM iajs-152 83 71 nm nm NOUN iajs-152 83 72 ) ) PUNCT iajs-152 83 73 ( ( PUNCT iajs-152 83 74 43859 43859 NUM iajs-152 83 75 cm-1 cm-1 NOUN iajs-152 83 76 ) ) PUNCT iajs-152 83 77 ( ( PUNCT iajs-152 83 78 max= max= VERB iajs-152 83 79 735molar-1 735molar-1 NUM iajs-152 83 80 cm-1 cm-1 NOUN iajs-152 83 81 ) ) PUNCT iajs-152 83 82 for for ADP iajs-152 83 83 complexes complex NOUN iajs-152 83 84 of of ADP iajs-152 83 85 co co NOUN iajs-152 83 86 , , PUNCT iajs-152 83 87 zn zn PROPN iajs-152 83 88 , , PUNCT iajs-152 83 89 cd cd PROPN iajs-152 83 90 and and CCONJ iajs-152 83 91 hg hg NOUN iajs-152 83 92 respectively respectively ADV iajs-152 83 93 , , PUNCT iajs-152 83 94 which which PRON iajs-152 83 95 can can AUX iajs-152 83 96 be be AUX iajs-152 83 97 assigned assign VERB iajs-152 83 98 to to ADP iajs-152 83 99 – – NOUN iajs-152 83 100 * * PUNCT iajs-152 83 101 transition transition NOUN iajs-152 84 1 [ [ X iajs-152 84 2 23 23 NUM iajs-152 84 3 ] ] PUNCT iajs-152 84 4 . . PUNCT iajs-152 85 1 the the DET iajs-152 85 2 peaks peak NOUN iajs-152 85 3 at at ADP iajs-152 85 4 ( ( PUNCT iajs-152 85 5 260 260 NUM iajs-152 85 6 nm nm NOUN iajs-152 85 7 ) ) PUNCT iajs-152 85 8 ( ( PUNCT iajs-152 85 9 38461 38461 NUM iajs-152 85 10 cm-1 cm-1 NOUN iajs-152 85 11 ) ) PUNCT iajs-152 85 12 ( ( PUNCT iajs-152 85 13 max= max= PROPN iajs-152 85 14 3933molar-1 3933molar-1 NUM iajs-152 85 15 cm-1 cm-1 NOUN iajs-152 85 16 ) ) PUNCT iajs-152 85 17 ; ; PUNCT iajs-152 85 18 ( ( PUNCT iajs-152 85 19 300 300 NUM iajs-152 85 20 nm nm NOUN iajs-152 85 21 ) ) PUNCT iajs-152 85 22 ( ( PUNCT iajs-152 85 23 33557 33557 NUM iajs-152 85 24 cm-1 cm-1 NOUN iajs-152 85 25 ) ) PUNCT iajs-152 85 26 ( ( PUNCT iajs-152 85 27 max= max= VERB iajs-152 85 28 3887molar-1 3887molar-1 NUM iajs-152 85 29 cm-1 cm-1 NOUN iajs-152 85 30 ) ) PUNCT iajs-152 85 31 ; ; PUNCT iajs-152 85 32 ( ( PUNCT iajs-152 85 33 293 293 NUM iajs-152 85 34 nm nm NOUN iajs-152 85 35 ) ) PUNCT iajs-152 85 36 ( ( PUNCT iajs-152 85 37 34129 34129 NUM iajs-152 85 38 cm-1 cm-1 NOUN iajs-152 85 39 ) ) PUNCT iajs-152 85 40 ( ( PUNCT iajs-152 85 41 max= max= PROPN iajs-152 85 42 3952molar-1 3952molar-1 NUM iajs-152 85 43 cm-1 cm-1 NOUN iajs-152 85 44 ) ) PUNCT iajs-152 85 45 and and CCONJ iajs-152 85 46 ( ( PUNCT iajs-152 85 47 302 302 NUM iajs-152 85 48 nm nm NOUN iajs-152 85 49 ) ) PUNCT iajs-152 85 50 ( ( PUNCT iajs-152 85 51 43859 43859 NUM iajs-152 85 52 cm-1 cm-1 NOUN iajs-152 85 53 ) ) PUNCT iajs-152 85 54 ( ( PUNCT iajs-152 85 55 max= max= VERB iajs-152 85 56 735molar-1 735molar-1 NUM iajs-152 85 57 cm-1 cm-1 NOUN iajs-152 85 58 ) ) PUNCT iajs-152 85 59 for for ADP iajs-152 85 60 complexes complex NOUN iajs-152 85 61 of of ADP iajs-152 85 62 co co NOUN iajs-152 85 63 , , PUNCT iajs-152 85 64 zn zn PROPN iajs-152 85 65 , , PUNCT iajs-152 85 66 cd cd PROPN iajs-152 85 67 and and CCONJ iajs-152 85 68 hg hg NOUN iajs-152 85 69 respectively respectively ADV iajs-152 85 70 , , PUNCT iajs-152 85 71 assigned assign VERB iajs-152 85 72 the the DET iajs-152 85 73 n– n– NOUN iajs-152 85 74 * * SYM iajs-152 85 75 transition transition NOUN iajs-152 85 76 .the .the X iajs-152 86 1 bands band NOUN iajs-152 86 2 at at ADP iajs-152 86 3 ( ( PUNCT iajs-152 86 4 339 339 NUM iajs-152 86 5 nm nm NOUN iajs-152 86 6 ) ) PUNCT iajs-152 86 7 ( ( PUNCT iajs-152 86 8 29498 29498 NUM iajs-152 86 9 cm-1 cm-1 PROPN iajs-152 86 10 ) ) PUNCT iajs-152 86 11 ( ( PUNCT iajs-152 86 12 max= max= VERB iajs-152 86 13 4000molar-1 4000molar-1 NUM iajs-152 86 14 cm-1 cm-1 NOUN iajs-152 86 15 ) ) PUNCT iajs-152 86 16 ; ; PUNCT iajs-152 86 17 ( ( PUNCT iajs-152 86 18 345nm)(28985cm-1 345nm)(28985cm-1 NUM iajs-152 86 19 ) ) PUNCT iajs-152 86 20 ( ( PUNCT iajs-152 86 21 max= max= PROPN iajs-152 86 22 3730molar-1 3730molar-1 NUM iajs-152 86 23 cm-1 cm-1 NOUN iajs-152 86 24 ) ) PUNCT iajs-152 86 25 ; ; PUNCT iajs-152 86 26 ( ( PUNCT iajs-152 86 27 310 310 NUM iajs-152 86 28 nm nm NOUN iajs-152 86 29 ) ) PUNCT iajs-152 86 30 ( ( PUNCT iajs-152 86 31 32258 32258 NUM iajs-152 86 32 cm-1 cm-1 NOUN iajs-152 86 33 ) ) PUNCT iajs-152 86 34 ( ( PUNCT iajs-152 86 35 max= max= VERB iajs-152 86 36 1833molar-1 1833molar-1 NUM iajs-152 86 37 cm-1 cm-1 NOUN iajs-152 86 38 ) ) PUNCT iajs-152 86 39 and and CCONJ iajs-152 86 40 ( ( PUNCT iajs-152 86 41 425 425 NUM iajs-152 86 42 nm nm NOUN iajs-152 86 43 ) ) PUNCT iajs-152 86 44 ( ( PUNCT iajs-152 86 45 23529 23529 NUM iajs-152 86 46 cm-1 cm-1 PROPN iajs-152 86 47 ) ) PUNCT iajs-152 86 48 ( ( PUNCT iajs-152 86 49 max= max= PROPN iajs-152 86 50 755molar-1 755molar-1 NUM iajs-152 86 51 cm-1 cm-1 NOUN iajs-152 86 52 ) ) PUNCT iajs-152 86 53 for for ADP iajs-152 86 54 complexes complex NOUN iajs-152 86 55 of of ADP iajs-152 86 56 co co NOUN iajs-152 86 57 , , PUNCT iajs-152 86 58 zn zn PROPN iajs-152 86 59 , , PUNCT iajs-152 86 60 cd cd PROPN iajs-152 86 61 and and CCONJ iajs-152 86 62 hg hg NOUN iajs-152 86 63 respectively respectively ADV iajs-152 86 64 , , PUNCT iajs-152 86 65 may may AUX iajs-152 86 66 assigned assign VERB iajs-152 86 67 to to ADP iajs-152 86 68 ml ml NOUN iajs-152 86 69 charge charge NOUN iajs-152 86 70 transfer transfer NOUN iajs-152 86 71 transition transition NOUN iajs-152 86 72 [ [ X iajs-152 86 73 23].the 23].the NUM iajs-152 86 74 n n CCONJ iajs-152 86 75 = = NOUN iajs-152 86 76 n n PRON iajs-152 86 77 band band NOUN iajs-152 86 78 of of ADP iajs-152 86 79 the the DET iajs-152 86 80 free free ADJ iajs-152 86 81 ligand ligand NOUN iajs-152 86 82 at at ADP iajs-152 86 83 ( ( PUNCT iajs-152 86 84 437 437 NUM iajs-152 86 85 nm nm NOUN iajs-152 86 86 ) ) PUNCT iajs-152 86 87 ( ( PUNCT iajs-152 86 88 22883 22883 NUM iajs-152 86 89 cm-1 cm-1 NOUN iajs-152 86 90 ) ) PUNCT iajs-152 86 91 ( ( PUNCT iajs-152 86 92 max= max= PROPN iajs-152 86 93 1063molar-1 1063molar-1 NUM iajs-152 86 94 cm-1 cm-1 NOUN iajs-152 86 95 ) ) PUNCT iajs-152 86 96 shifted shift VERB iajs-152 86 97 to to ADP iajs-152 86 98 lower low ADJ iajs-152 86 99 wave wave NOUN iajs-152 86 100 lengthes lengthe NOUN iajs-152 86 101 in in ADP iajs-152 86 102 the the DET iajs-152 86 103 complexes complex NOUN iajs-152 86 104 and and CCONJ iajs-152 86 105 appeared appear VERB iajs-152 86 106 at at ADP iajs-152 86 107 ( ( PUNCT iajs-152 86 108 403 403 NUM iajs-152 86 109 nm nm NOUN iajs-152 86 110 ) ) PUNCT iajs-152 86 111 ( ( PUNCT iajs-152 86 112 24813 24813 NUM iajs-152 86 113 cm-1 cm-1 NOUN iajs-152 86 114 ) ) PUNCT iajs-152 86 115 ( ( PUNCT iajs-152 86 116 max= max= PROPN iajs-152 86 117 3032molar-1 3032molar-1 NUM iajs-152 86 118 cm-1 cm-1 NOUN iajs-152 86 119 ) ) PUNCT iajs-152 86 120 ; ; PUNCT iajs-152 86 121 ( ( PUNCT iajs-152 86 122 421 421 NUM iajs-152 86 123 nm nm NOUN iajs-152 86 124 ) ) PUNCT iajs-152 86 125 ( ( PUNCT iajs-152 86 126 23752 23752 NUM iajs-152 86 127 cm-1 cm-1 NOUN iajs-152 86 128 ) ) PUNCT iajs-152 86 129 ( ( PUNCT iajs-152 86 130 max= max= PROPN iajs-152 86 131 2037molar1 2037molar1 NUM iajs-152 86 132 cm-1 cm-1 NOUN iajs-152 86 133 ) ) PUNCT iajs-152 86 134 ; ; PUNCT iajs-152 86 135 ( ( PUNCT iajs-152 86 136 411 411 NUM iajs-152 86 137 nm nm NOUN iajs-152 86 138 ) ) PUNCT iajs-152 86 139 ( ( PUNCT iajs-152 86 140 24330 24330 NUM iajs-152 86 141 cm-1 cm-1 NOUN iajs-152 86 142 ) ) PUNCT iajs-152 86 143 ( ( PUNCT iajs-152 86 144 max= max= PROPN iajs-152 86 145 951molar-1 951molar-1 NUM iajs-152 86 146 cm-1 cm-1 NOUN iajs-152 86 147 ) ) PUNCT iajs-152 86 148 and and CCONJ iajs-152 86 149 ( ( PUNCT iajs-152 86 150 441 441 NUM iajs-152 86 151 nm nm NOUN iajs-152 86 152 ) ) PUNCT iajs-152 86 153 ( ( PUNCT iajs-152 86 154 22675 22675 NUM iajs-152 86 155 cm-1 cm-1 NOUN iajs-152 86 156 ) ) PUNCT iajs-152 86 157 ( ( PUNCT iajs-152 86 158 max= max= PROPN iajs-152 86 159 755molar-1 755molar-1 NUM iajs-152 86 160 cm-1 cm-1 NOUN iajs-152 86 161 ) ) PUNCT iajs-152 86 162 for for ADP iajs-152 86 163 complexes complex NOUN iajs-152 86 164 of of ADP iajs-152 86 165 co co NOUN iajs-152 86 166 , , PUNCT iajs-152 86 167 zn zn PROPN iajs-152 86 168 , , PUNCT iajs-152 86 169 cd cd PROPN iajs-152 86 170 and and CCONJ iajs-152 86 171 hg hg NOUN iajs-152 86 172 respectively respectively ADV iajs-152 86 173 as as ADP iajs-152 86 174 a a DET iajs-152 86 175 consequence consequence NOUN iajs-152 86 176 of of ADP iajs-152 86 177 coordination coordination NOUN iajs-152 86 178 when when SCONJ iajs-152 86 179 binding bind VERB iajs-152 86 180 with with ADP iajs-152 86 181 a a DET iajs-152 86 182 metal metal NOUN iajs-152 86 183 , , PUNCT iajs-152 86 184 confirming confirm VERB iajs-152 86 185 that that SCONJ iajs-152 86 186 the the DET iajs-152 86 187 azo azo PROPN iajs-152 86 188 nitrogen nitrogen NOUN iajs-152 86 189 was be AUX iajs-152 86 190 coordinat coordinat NOUN iajs-152 86 191 to to ADP iajs-152 86 192 the the DET iajs-152 86 193 metal metal NOUN iajs-152 86 194 atom atom NOUN iajs-152 86 195 . . PUNCT iajs-152 87 1 the the DET iajs-152 87 2 peak peak NOUN iajs-152 87 3 in in ADP iajs-152 87 4 the the DET iajs-152 87 5 visible visible ADJ iajs-152 87 6 region region NOUN iajs-152 87 7 can can AUX iajs-152 87 8 be be AUX iajs-152 87 9 associated associate VERB iajs-152 87 10 with with ADP iajs-152 87 11 d d PROPN iajs-152 87 12 - - PUNCT iajs-152 87 13 d d NOUN iajs-152 87 14 transition transition NOUN iajs-152 87 15 . . PUNCT iajs-152 88 1 the the DET iajs-152 88 2 coii coii ADJ iajs-152 88 3 complex complex NOUN iajs-152 88 4 shows show VERB iajs-152 88 5 a a DET iajs-152 88 6 band band NOUN iajs-152 88 7 at at ADP iajs-152 88 8 ( ( PUNCT iajs-152 88 9 620 620 NUM iajs-152 88 10 nm nm NOUN iajs-152 88 11 ) ) PUNCT iajs-152 88 12 ( ( PUNCT iajs-152 88 13 16129 16129 NUM iajs-152 88 14 cm-1 cm-1 NOUN iajs-152 88 15 ) ) PUNCT iajs-152 88 16 ( ( PUNCT iajs-152 88 17 max= max= VERB iajs-152 88 18 1788molar-1 1788molar-1 NUM iajs-152 88 19 cm-1 cm-1 NOUN iajs-152 88 20 ) ) PUNCT iajs-152 88 21 assignable assignable ADJ iajs-152 88 22 to to ADP iajs-152 88 23 4t1g(f)4a2g(f 4t1g(f)4a2g(f NUM iajs-152 88 24 ) ) PUNCT iajs-152 88 25 suggesting suggest VERB iajs-152 88 26 distorted distort VERB iajs-152 88 27 octahedral octahedral ADJ iajs-152 88 28 geometry geometry NOUN iajs-152 88 29 around around ADP iajs-152 88 30 coii coii ADJ iajs-152 88 31 ion ion NOUN iajs-152 88 32 . . PUNCT iajs-152 89 1 finally finally ADV iajs-152 89 2 znii znii PROPN iajs-152 89 3 , , PUNCT iajs-152 89 4 hgii hgii NOUN iajs-152 89 5 and and CCONJ iajs-152 89 6 cdii cdii NOUN iajs-152 89 7 complexes complex NOUN iajs-152 89 8 with with ADP iajs-152 89 9 an an DET iajs-152 89 10 electronic electronic ADJ iajs-152 89 11 configuration configuration NOUN iajs-152 89 12 of of ADP iajs-152 89 13 d10 d10 PROPN iajs-152 89 14 did do AUX iajs-152 89 15 not not PART iajs-152 89 16 show show VERB iajs-152 89 17 any any DET iajs-152 89 18 ( ( PUNCT iajs-152 89 19 d d NOUN iajs-152 89 20 - - PUNCT iajs-152 89 21 d d NOUN iajs-152 89 22 ) ) PUNCT iajs-152 89 23 transitions transition NOUN iajs-152 89 24 . . PUNCT iajs-152 90 1 instead instead ADV iajs-152 90 2 the the DET iajs-152 90 3 absorption absorption NOUN iajs-152 90 4 bands band NOUN iajs-152 90 5 in in ADP iajs-152 90 6 the the DET iajs-152 90 7 spectra spectra NOUN iajs-152 90 8 were be AUX iajs-152 90 9 due due ADJ iajs-152 90 10 to to PART iajs-152 90 11 charge charge NOUN iajs-152 90 12 transfer transfer NOUN iajs-152 90 13 transitions transition NOUN iajs-152 90 14 which which PRON iajs-152 90 15 suffered suffer VERB iajs-152 90 16 from from ADP iajs-152 90 17 blue blue ADJ iajs-152 90 18 shift shift NOUN iajs-152 90 19 with with ADP iajs-152 90 20 hyper hyper ADJ iajs-152 90 21 chromic chromic ADJ iajs-152 90 22 effect effect NOUN iajs-152 90 23 [ [ X iajs-152 90 24 42 42 NUM iajs-152 90 25 ] ] PUNCT iajs-152 90 26 . . PUNCT iajs-152 91 1 the the DET iajs-152 91 2 1hnmr 1hnmr NUM iajs-152 91 3 spectra spectra NOUN iajs-152 91 4 of of ADP iajs-152 91 5 dmso dmso ADJ iajs-152 91 6 - - ADJ iajs-152 91 7 d6 d6 ADJ iajs-152 91 8 solution solution NOUN iajs-152 91 9 of of ADP iajs-152 91 10 ligand ligand NOUN iajs-152 91 11 and and CCONJ iajs-152 91 12 it it PRON iajs-152 91 13 cdii cdii VERB iajs-152 91 14 complex complex NOUN iajs-152 91 15 showed show VERB iajs-152 91 16 well well ADV iajs-152 91 17 resolved resolve VERB iajs-152 91 18 signals signal NOUN iajs-152 91 19 figure(13 figure(13 NOUN iajs-152 91 20 ) ) PUNCT iajs-152 91 21 and and CCONJ iajs-152 91 22 figure(14 figure(14 NOUN iajs-152 91 23 ) ) PUNCT iajs-152 91 24 , , PUNCT iajs-152 91 25 table(4 table(4 PROPN iajs-152 91 26 ) ) PUNCT iajs-152 91 27 .the .the PUNCT iajs-152 92 1 spectrum spectrum NOUN iajs-152 92 2 of of ADP iajs-152 92 3 the the DET iajs-152 92 4 free free ADJ iajs-152 92 5 ligand ligand NOUN iajs-152 92 6 showed show VERB iajs-152 92 7 multiplet multiplet NOUN iajs-152 92 8 chemical chemical NOUN iajs-152 92 9 shift shift NOUN iajs-152 92 10 at at ADP iajs-152 92 11 the the DET iajs-152 92 12 range range NOUN iajs-152 92 13 ( ( PUNCT iajs-152 92 14   NUM iajs-152 92 15 = = NUM iajs-152 92 16 7.3 7.3 NUM iajs-152 92 17 - - SYM iajs-152 92 18 7.8 7.8 NUM iajs-152 92 19 ppm ppm NOUN iajs-152 92 20 ) ) PUNCT iajs-152 92 21 assigned assign VERB iajs-152 92 22 to to ADP iajs-152 92 23 aromatic aromatic ADJ iajs-152 92 24 protons proton NOUN iajs-152 92 25 . . PUNCT iajs-152 93 1 the the DET iajs-152 93 2 characteristic characteristic ADJ iajs-152 93 3 signals signal NOUN iajs-152 93 4 at( at( NOUN iajs-152 93 5 = = SYM iajs-152 93 6 8.8 8.8 NUM iajs-152 93 7 ppm ppm NOUN iajs-152 93 8 ) ) PUNCT iajs-152 93 9 and and CCONJ iajs-152 93 10 ( ( PUNCT iajs-152 93 11   NUM iajs-152 93 12 = = SYM iajs-152 93 13 11.1 11.1 NUM iajs-152 93 14 ppm ppm NOUN iajs-152 93 15 ) ) PUNCT iajs-152 93 16 were be AUX iajs-152 93 17 assigned assign VERB iajs-152 93 18 to to ADP iajs-152 93 19 nh2 nh2 PROPN iajs-152 93 20 and and CCONJ iajs-152 93 21 oh oh INTJ iajs-152 93 22 191 191 NUM iajs-152 94 1 | | ADV iajs-152 94 2 chemistry chemistry NOUN iajs-152 94 3 2015 2015 NUM iajs-152 94 4 ) ) PUNCT iajs-152 94 5 عام عام ADP iajs-152 94 6 3العدد 3العدد NUM iajs-152 94 7 ( ( PUNCT iajs-152 94 8 28مجلة 28مجلة X iajs-152 94 9 إبن إبن VERB iajs-152 94 10 الھيثم الھيثم NOUN iajs-152 94 11 للعلوم للعلوم NOUN iajs-152 94 12 الصرفة الصرفة NOUN iajs-152 95 1 و و PRON iajs-152 95 2 التطبيقية التطبيقية ADV iajs-152 95 3 المجلد المجلد VERB iajs-152 95 4 ibn ibn PROPN iajs-152 95 5 al al PROPN iajs-152 95 6 - - PUNCT iajs-152 95 7 haitham haitham PROPN iajs-152 95 8 jour jour X iajs-152 95 9 . . PROPN iajs-152 96 1 for for ADP iajs-152 96 2 pure pure ADJ iajs-152 96 3 & & CCONJ iajs-152 96 4 appl appl PROPN iajs-152 96 5 . . PUNCT iajs-152 97 1 sci sci PROPN iajs-152 97 2 . . PUNCT iajs-152 97 3 vol vol NOUN iajs-152 97 4 . . PROPN iajs-152 98 1 28 28 NUM iajs-152 98 2 ( ( PUNCT iajs-152 98 3 3 3 NUM iajs-152 98 4 ) ) PUNCT iajs-152 98 5 2015 2015 NUM iajs-152 98 6 phenolic phenolic NOUN iajs-152 98 7 groups group NOUN iajs-152 98 8 respectively respectively ADV iajs-152 98 9 , , PUNCT iajs-152 98 10 because because SCONJ iajs-152 98 11 of of ADP iajs-152 98 12 intramolecular intramolecular ADJ iajs-152 98 13 hydrogen hydrogen NOUN iajs-152 98 14 bonding bonding NOUN iajs-152 98 15 with with ADP iajs-152 98 16 the the DET iajs-152 98 17 nitrogen nitrogen NOUN iajs-152 98 18 atom atom NOUN iajs-152 98 19 on on ADP iajs-152 98 20 the the DET iajs-152 98 21 phenolic phenolic ADJ iajs-152 98 22 ring ring NOUN iajs-152 98 23 [ [ X iajs-152 98 24 23 23 NUM iajs-152 98 25 ] ] PUNCT iajs-152 98 26 . . PUNCT iajs-152 99 1 the the DET iajs-152 99 2 1hnmr 1hnmr NUM iajs-152 99 3 spectrum spectrum NOUN iajs-152 99 4 of of ADP iajs-152 99 5 cdii cdii NOUN iajs-152 99 6 complex complex NOUN iajs-152 99 7 showed show VERB iajs-152 99 8 the the DET iajs-152 99 9 aromatic aromatic ADJ iajs-152 99 10 protons proton NOUN iajs-152 99 11 at at ADP iajs-152 99 12 chemical chemical ADJ iajs-152 99 13 shifts shift NOUN iajs-152 99 14 at at ADP iajs-152 99 15 the the DET iajs-152 99 16 range( range( NOUN iajs-152 99 17 = = PUNCT iajs-152 99 18 7.2 7.2 NUM iajs-152 99 19 - - SYM iajs-152 99 20 8.2 8.2 NUM iajs-152 99 21 ppm ppm NOUN iajs-152 99 22 ) ) PUNCT iajs-152 99 23 , , PUNCT iajs-152 99 24 signal signal VERB iajs-152 99 25 observed observe VERB iajs-152 99 26 at at ADP iajs-152 99 27 ( ( PUNCT iajs-152 99 28   NUM iajs-152 99 29 = = PROPN iajs-152 99 30 8.8 8.8 NUM iajs-152 99 31 ppm ppm NOUN iajs-152 99 32 ) ) PUNCT iajs-152 99 33 assigned assign VERB iajs-152 99 34 to to ADP iajs-152 99 35 nh2 nh2 PROPN iajs-152 99 36 group group NOUN iajs-152 99 37 and and CCONJ iajs-152 99 38 ( ( PUNCT iajs-152 99 39   NUM iajs-152 99 40 = = SYM iajs-152 99 41 9.2 9.2 NUM iajs-152 99 42 ppm ppm NOUN iajs-152 99 43 ) ) PUNCT iajs-152 99 44 assigned assign VERB iajs-152 99 45 to to ADP iajs-152 99 46 nh nh PROPN iajs-152 99 47 proton proton NOUN iajs-152 99 48 of of ADP iajs-152 99 49 azo azo PROPN iajs-152 99 50 group group NOUN iajs-152 99 51 , , PUNCT iajs-152 99 52 this this DET iajs-152 99 53 information information NOUN iajs-152 99 54 supports support VERB iajs-152 99 55 the the DET iajs-152 99 56 fact fact NOUN iajs-152 99 57 that that SCONJ iajs-152 99 58 there there PRON iajs-152 99 59 is be VERB iajs-152 99 60 keto keto NOUN iajs-152 99 61 hydrazone hydrazone NOUN iajs-152 99 62 tautomer tautomer NOUN iajs-152 99 63 for for ADP iajs-152 99 64 the the DET iajs-152 99 65 synthesized synthesize VERB iajs-152 99 66 ligand ligand NOUN iajs-152 99 67 [ [ X iajs-152 99 68 43 43 NUM iajs-152 99 69 ] ] PUNCT iajs-152 99 70 . . PUNCT iajs-152 100 1 the the DET iajs-152 100 2 chemical chemical ADJ iajs-152 100 3 shifts shift NOUN iajs-152 100 4 at( at( VERB iajs-152 100 5 = = SYM iajs-152 100 6 11.1 11.1 NUM iajs-152 100 7 ppm ppm NOUN iajs-152 100 8 ) ) PUNCT iajs-152 100 9 which which PRON iajs-152 100 10 can can AUX iajs-152 100 11 be be AUX iajs-152 100 12 attributed attribute VERB iajs-152 100 13 to to ADP iajs-152 100 14 the the DET iajs-152 100 15 proton proton NOUN iajs-152 100 16 of of ADP iajs-152 100 17 the the DET iajs-152 100 18 phenolic phenolic ADJ iajs-152 100 19 group group NOUN iajs-152 100 20 in in ADP iajs-152 100 21 the the DET iajs-152 100 22 ligand ligand NOUN iajs-152 100 23 spectrum spectrum NOUN iajs-152 100 24 , , PUNCT iajs-152 100 25 disappeared disappear VERB iajs-152 100 26 in in ADP iajs-152 100 27 the the DET iajs-152 100 28 complex complex ADJ iajs-152 100 29 spectrum spectrum NOUN iajs-152 100 30 due due ADP iajs-152 100 31 to to ADP iajs-152 100 32 the the DET iajs-152 100 33 deprotonation deprotonation NOUN iajs-152 100 34 process process NOUN iajs-152 100 35 . . PUNCT iajs-152 101 1 fluorescence fluorescence PROPN iajs-152 101 2 emission emission PROPN iajs-152 101 3 spectra spectra NOUN iajs-152 101 4 the the DET iajs-152 101 5 emission emission NOUN iajs-152 101 6 spectra spectra NOUN iajs-152 101 7 of of ADP iajs-152 101 8 the the DET iajs-152 101 9 ligand ligand NOUN iajs-152 101 10 and and CCONJ iajs-152 101 11 1,10 1,10 NUM iajs-152 101 12 - - PUNCT iajs-152 101 13 phenonthroline phenonthroline NOUN iajs-152 101 14 are be AUX iajs-152 101 15 shown show VERB iajs-152 101 16 in in ADP iajs-152 101 17 figure figure NOUN iajs-152 101 18 ( ( PUNCT iajs-152 101 19 15 15 NUM iajs-152 101 20 ) ) PUNCT iajs-152 101 21 and and CCONJ iajs-152 101 22 figure(16 figure(16 NOUN iajs-152 101 23 ) ) PUNCT iajs-152 101 24 , , PUNCT iajs-152 101 25 respectively respectively ADV iajs-152 101 26 complexes complexe VERB iajs-152 101 27 spectra spectra NOUN iajs-152 101 28 are be AUX iajs-152 101 29 shown show VERB iajs-152 101 30 in in ADP iajs-152 101 31 figures figure NOUN iajs-152 101 32 ( ( PUNCT iajs-152 101 33 17 17 NUM iajs-152 101 34 - - SYM iajs-152 101 35 20).the 20).the NUM iajs-152 101 36 fluorescence fluorescence NOUN iajs-152 101 37 emission emission NOUN iajs-152 101 38 spectra spectra NOUN iajs-152 101 39 of of ADP iajs-152 101 40 ligand ligand PROPN iajs-152 101 41 display display NOUN iajs-152 101 42 maximum maximum ADJ iajs-152 101 43 emission emission NOUN iajs-152 101 44 wavelengths wavelength NOUN iajs-152 101 45 ( ( PUNCT iajs-152 101 46 λem λem ADJ iajs-152 101 47 , , PUNCT iajs-152 101 48 max max PROPN iajs-152 101 49 ) ) PUNCT iajs-152 101 50 at at ADP iajs-152 101 51 455 455 NUM iajs-152 101 52 nm nm NOUN iajs-152 101 53 with with ADP iajs-152 101 54 excitation excitation NOUN iajs-152 101 55 wavelengths wavelength NOUN iajs-152 101 56 at at ADP iajs-152 101 57 437 437 NUM iajs-152 101 58 nm nm NOUN iajs-152 101 59 , , PUNCT iajs-152 101 60 while while SCONJ iajs-152 101 61 1,10 1,10 NUM iajs-152 101 62 - - PUNCT iajs-152 101 63 phenonthroline phenonthroline NOUN iajs-152 101 64 shows show VERB iajs-152 101 65 maximum maximum ADJ iajs-152 101 66 emission emission NOUN iajs-152 101 67 wavelengths wavelength NOUN iajs-152 101 68 ( ( PUNCT iajs-152 101 69 λem λem ADJ iajs-152 101 70 , , PUNCT iajs-152 101 71 max max PROPN iajs-152 101 72 ) ) PUNCT iajs-152 101 73 at at ADP iajs-152 101 74 348 348 NUM iajs-152 101 75 nm nm NOUN iajs-152 101 76 with with ADP iajs-152 101 77 excitation excitation NOUN iajs-152 101 78 wavelengths wavelength NOUN iajs-152 101 79 at at ADP iajs-152 101 80 257 257 NUM iajs-152 101 81 nm nm NOUN iajs-152 101 82 the the DET iajs-152 101 83 complexes complex NOUN iajs-152 101 84 ( ( PUNCT iajs-152 101 85 coii coii PROPN iajs-152 101 86 , , PUNCT iajs-152 101 87 znii znii NOUN iajs-152 101 88 , , PUNCT iajs-152 101 89 cdii cdii NOUN iajs-152 101 90 and and CCONJ iajs-152 101 91 hgii hgii NOUN iajs-152 101 92 ) ) PUNCT iajs-152 101 93 exhibit exhibit VERB iajs-152 101 94 maximum maximum ADJ iajs-152 101 95 fluorescence fluorescence NOUN iajs-152 101 96 emission emission NOUN iajs-152 101 97 wavelengths wavelength NOUN iajs-152 101 98 ( ( PUNCT iajs-152 101 99 λem λem ADJ iajs-152 101 100 , , PUNCT iajs-152 101 101 max max PROPN iajs-152 101 102 ) ) PUNCT iajs-152 101 103 at at ADP iajs-152 101 104 340,330,340 340,330,340 NUM iajs-152 101 105 and and CCONJ iajs-152 101 106 324 324 NUM iajs-152 101 107 nm nm NOUN iajs-152 101 108 with with ADP iajs-152 101 109 excitation excitation NOUN iajs-152 101 110 wavelengths wavelength NOUN iajs-152 101 111 at at ADP iajs-152 101 112 339,300,310 339,300,310 NUM iajs-152 101 113 and and CCONJ iajs-152 101 114 302 302 NUM iajs-152 101 115 nm nm NOUN iajs-152 101 116 respectively respectively ADV iajs-152 101 117 . . PUNCT iajs-152 102 1 the the DET iajs-152 102 2 coii coii ADJ iajs-152 102 3 and and CCONJ iajs-152 102 4 cdii cdii NOUN iajs-152 102 5 show show VERB iajs-152 102 6 very very ADV iajs-152 102 7 good good ADJ iajs-152 102 8 fluorescence fluorescence NOUN iajs-152 102 9 emission emission NOUN iajs-152 102 10 behavior behavior NOUN iajs-152 102 11 upon upon SCONJ iajs-152 102 12 excitation excitation NOUN iajs-152 102 13 of of ADP iajs-152 102 14 the the DET iajs-152 102 15 intraligand intraligand NOUN iajs-152 102 16 charge charge NOUN iajs-152 102 17 transfer transfer NOUN iajs-152 102 18 band band NOUN iajs-152 102 19 [ [ X iajs-152 102 20 44 44 NUM iajs-152 102 21 ] ] PUNCT iajs-152 102 22 . . PUNCT iajs-152 103 1 the the DET iajs-152 103 2 shifts shift NOUN iajs-152 103 3 in in ADP iajs-152 103 4 complexes complex NOUN iajs-152 103 5 data datum NOUN iajs-152 103 6 compared compare VERB iajs-152 103 7 with with ADP iajs-152 103 8 ligand ligand NOUN iajs-152 103 9 indicate indicate VERB iajs-152 103 10 that that SCONJ iajs-152 103 11 the the DET iajs-152 103 12 ligand ligand NOUN iajs-152 103 13 successfully successfully ADV iajs-152 103 14 chelated chelate VERB iajs-152 103 15 to to ADP iajs-152 103 16 metal metal NOUN iajs-152 103 17 ions ion NOUN iajs-152 103 18 . . PUNCT iajs-152 104 1 fluorescence fluorescence PROPN iajs-152 104 2 spectral spectral ADJ iajs-152 104 3 data datum NOUN iajs-152 104 4 are be AUX iajs-152 104 5 shown show VERB iajs-152 104 6 in in ADP iajs-152 104 7 table table NOUN iajs-152 104 8 ( ( PUNCT iajs-152 104 9 5 5 NUM iajs-152 104 10 ) ) PUNCT iajs-152 104 11 . . PUNCT iajs-152 105 1 molar molar ADJ iajs-152 105 2 conductivity conductivity NOUN iajs-152 105 3 measurement measurement NOUN iajs-152 105 4 for for ADP iajs-152 105 5 the the DET iajs-152 105 6 complexes complex NOUN iajs-152 105 7 in in ADP iajs-152 105 8 ( ( PUNCT iajs-152 105 9 dmso dmso NOUN iajs-152 105 10 ) ) PUNCT iajs-152 105 11 are be AUX iajs-152 105 12 summarized summarize VERB iajs-152 105 13 in in ADP iajs-152 105 14 table table NOUN iajs-152 105 15 ( ( PUNCT iajs-152 105 16 6 6 NUM iajs-152 105 17 ) ) PUNCT iajs-152 105 18 . . PUNCT iajs-152 106 1 thermal thermal ADJ iajs-152 106 2 analysis analysis NOUN iajs-152 106 3 studies study NOUN iajs-152 106 4 the the DET iajs-152 106 5 tga tga PROPN iajs-152 106 6 thermal thermal ADJ iajs-152 106 7 analysis analysis NOUN iajs-152 106 8 curves curve NOUN iajs-152 106 9 for for ADP iajs-152 106 10 [ [ X iajs-152 106 11 co(l)(phen)(h2o)cl]and co(l)(phen)(h2o)cl]and NOUN iajs-152 106 12 [ [ X iajs-152 106 13 cd(l cd(l X iajs-152 106 14 ) ) PUNCT iajs-152 106 15 ) ) PUNCT iajs-152 106 16 ( ( PUNCT iajs-152 106 17 phen)(h2o)cl phen)(h2o)cl NOUN iajs-152 106 18 ] ] PUNCT iajs-152 106 19 complexes complex NOUN iajs-152 106 20 is be AUX iajs-152 106 21 shown show VERB iajs-152 106 22 in in ADP iajs-152 106 23 figures figure NOUN iajs-152 106 24 ( ( PUNCT iajs-152 106 25 21 21 NUM iajs-152 106 26 ) ) PUNCT iajs-152 106 27 and and CCONJ iajs-152 106 28 ( ( PUNCT iajs-152 106 29 22),and 22),and NOUN iajs-152 106 30 data datum NOUN iajs-152 106 31 are be AUX iajs-152 106 32 listed list VERB iajs-152 106 33 in in ADP iajs-152 106 34 table(7 table(7 PROPN iajs-152 106 35 ) ) PUNCT iajs-152 106 36 . . PUNCT iajs-152 107 1 the the DET iajs-152 107 2 coii coii ADJ iajs-152 107 3 complex complex ADJ iajs-152 107 4 decomposes decompose NOUN iajs-152 107 5 in in ADP iajs-152 107 6 three three NUM iajs-152 107 7 steps step NOUN iajs-152 107 8 . . PUNCT iajs-152 108 1 the the DET iajs-152 108 2 first first ADJ iajs-152 108 3 stage stage NOUN iajs-152 108 4 is be AUX iajs-152 108 5 the the DET iajs-152 108 6 loss loss NOUN iajs-152 108 7 ( ( PUNCT iajs-152 108 8 h2o h2o PROPN iajs-152 108 9 + + NOUN iajs-152 108 10 n2+nh3 n2+nh3 NOUN iajs-152 108 11 ) ) PUNCT iajs-152 108 12 with with ADP iajs-152 108 13 mass mass ADJ iajs-152 108 14 losses loss NOUN iajs-152 108 15 of of ADP iajs-152 108 16 9.25897 9.25897 NUM iajs-152 108 17 % % NOUN iajs-152 108 18 ( ( PUNCT iajs-152 108 19 calc calc NOUN iajs-152 108 20 . . PUNCT iajs-152 109 1 = = SYM iajs-152 109 2 8.918766978 8.918766978 NUM iajs-152 109 3 % % NOUN iajs-152 109 4 ) ) PUNCT iajs-152 109 5 within within ADP iajs-152 109 6 a a DET iajs-152 109 7 temperature temperature NOUN iajs-152 109 8 range range NOUN iajs-152 109 9 of of ADP iajs-152 109 10 30 30 NUM iajs-152 109 11 - - SYM iajs-152 109 12 248.930c 248.930c NUM iajs-152 109 13 , , PUNCT iajs-152 109 14 the the DET iajs-152 109 15 decomposition decomposition NOUN iajs-152 109 16 of of ADP iajs-152 109 17 the the DET iajs-152 109 18 complex complex NOUN iajs-152 109 19 in in ADP iajs-152 109 20 the the DET iajs-152 109 21 30 30 NUM iajs-152 109 22 - - SYM iajs-152 109 23 248.930c 248.930c NUM iajs-152 109 24 range range NOUN iajs-152 109 25 is be AUX iajs-152 109 26 indicated indicate VERB iajs-152 109 27 by by ADP iajs-152 109 28 endothermic endothermic NOUN iajs-152 109 29 processes process NOUN iajs-152 109 30 at at ADP iajs-152 109 31 84.5 84.5 NUM iajs-152 109 32 0c 0c NOUN iajs-152 109 33 the the DET iajs-152 109 34 second second ADJ iajs-152 109 35 step step NOUN iajs-152 109 36 involves involve VERB iajs-152 109 37 the the DET iajs-152 109 38 loss loss NOUN iajs-152 109 39 of of ADP iajs-152 109 40 the the DET iajs-152 109 41 organic organic ADJ iajs-152 109 42 fraction fraction NOUN iajs-152 109 43 , , PUNCT iajs-152 109 44 ( ( PUNCT iajs-152 109 45 c10h8+nacl c10h8+nacl INTJ iajs-152 109 46 ) ) PUNCT iajs-152 109 47 within within ADP iajs-152 109 48 the the DET iajs-152 109 49 temperature temperature NOUN iajs-152 109 50 range range NOUN iajs-152 109 51 of of ADP iajs-152 109 52 248.93 248.93 NUM iajs-152 109 53 - - SYM iajs-152 109 54 446.80 446.80 NUM iajs-152 109 55 0c 0c NOUN iajs-152 109 56 , , PUNCT iajs-152 109 57 the the DET iajs-152 109 58 decomposition decomposition NOUN iajs-152 109 59 of of ADP iajs-152 109 60 the the DET iajs-152 109 61 complex complex NOUN iajs-152 109 62 in in ADP iajs-152 109 63 the the DET iajs-152 109 64 248.93446.800c 248.93446.800c PROPN iajs-152 109 65 range range NOUN iajs-152 109 66 is be AUX iajs-152 109 67 indicated indicate VERB iajs-152 109 68 by by ADP iajs-152 109 69 exothermic exothermic ADJ iajs-152 109 70 processes process NOUN iajs-152 109 71 at at ADP iajs-152 109 72 311.60c 311.60c NUM iajs-152 109 73 , , PUNCT iajs-152 109 74 with with ADP iajs-152 109 75 mass mass ADJ iajs-152 109 76 losses loss NOUN iajs-152 109 77 of of ADP iajs-152 109 78 26.2889 26.2889 NUM iajs-152 109 79 % % NOUN iajs-152 109 80 ( ( PUNCT iajs-152 109 81 calc calc NOUN iajs-152 109 82 . . PUNCT iajs-152 110 1 = = PRON iajs-152 110 2 26.40114529 26.40114529 NUM iajs-152 110 3 % % NOUN iajs-152 110 4 ) ) PUNCT iajs-152 110 5 . . PUNCT iajs-152 111 1 the the DET iajs-152 111 2 final final ADJ iajs-152 111 3 weight weight NOUN iajs-152 111 4 of of ADP iajs-152 111 5 the the DET iajs-152 111 6 compound compound NOUN iajs-152 111 7 observed observe VERB iajs-152 111 8 at at ADP iajs-152 111 9 57.1701 57.1701 NUM iajs-152 111 10 % % NOUN iajs-152 111 11 ( ( PUNCT iajs-152 111 12 calc calc NOUN iajs-152 111 13 . . PUNCT iajs-152 112 1 = = PRON iajs-152 112 2 64.68001614 64.68001614 NUM iajs-152 112 3 % % NOUN iajs-152 112 4 ) ) PUNCT iajs-152 112 5 within within ADP iajs-152 112 6 a a DET iajs-152 112 7 temperature temperature NOUN iajs-152 112 8 range range NOUN iajs-152 112 9 of of ADP iajs-152 112 10 446.80 446.80 NUM iajs-152 112 11 - - SYM iajs-152 112 12 572.340c 572.340c NUM iajs-152 112 13 . . PUNCT iajs-152 113 1 the the DET iajs-152 113 2 difference difference NOUN iajs-152 113 3 in in ADP iajs-152 113 4 the the DET iajs-152 113 5 calculations calculation NOUN iajs-152 113 6 in in ADP iajs-152 113 7 observed observe VERB iajs-152 113 8 of of ADP iajs-152 113 9 the the DET iajs-152 113 10 residue residue NOUN iajs-152 113 11 weight weight NOUN iajs-152 113 12 may may AUX iajs-152 113 13 be be AUX iajs-152 113 14 related relate VERB iajs-152 113 15 to to ADP iajs-152 113 16 the the DET iajs-152 113 17 sublimation sublimation NOUN iajs-152 113 18 upon upon SCONJ iajs-152 113 19 thermal thermal ADJ iajs-152 113 20 decomposition decomposition NOUN iajs-152 113 21 .the .the PRON iajs-152 113 22 cdii cdii NOUN iajs-152 113 23 complex complex ADJ iajs-152 113 24 decomposes decompose NOUN iajs-152 113 25 in in ADP iajs-152 113 26 two two NUM iajs-152 113 27 steps step NOUN iajs-152 113 28 . . PUNCT iajs-152 114 1 stage stage NOUN iajs-152 114 2 one one NUM iajs-152 114 3 is be AUX iajs-152 114 4 the the DET iajs-152 114 5 loss loss NOUN iajs-152 114 6 ( ( PUNCT iajs-152 114 7 1,10phenanthroline+c10h8+h2o+n2+nh3+cl+so3na 1,10phenanthroline+c10h8+h2o+n2+nh3+cl+so3na NUM iajs-152 114 8 ) ) PUNCT iajs-152 114 9 within within ADP iajs-152 114 10 the the DET iajs-152 114 11 temperature temperature NOUN iajs-152 114 12 range range NOUN iajs-152 114 13 of of ADP iajs-152 114 14 30402.120c 30402.120c NUM iajs-152 114 15 , , PUNCT iajs-152 114 16 the the DET iajs-152 114 17 decomposition decomposition NOUN iajs-152 114 18 of of ADP iajs-152 114 19 the the DET iajs-152 114 20 complex complex NOUN iajs-152 114 21 in in ADP iajs-152 114 22 the the DET iajs-152 114 23 30 30 NUM iajs-152 114 24 - - PUNCT iajs-152 114 25 402.120c 402.120c NUM iajs-152 114 26 range range NOUN iajs-152 114 27 is be AUX iajs-152 114 28 indicated indicate VERB iajs-152 114 29 by by ADP iajs-152 114 30 endothermic endothermic NOUN iajs-152 114 31 and and CCONJ iajs-152 114 32 exothermic exothermic ADJ iajs-152 114 33 respectively respectively ADV iajs-152 114 34 processes process NOUN iajs-152 114 35 at at ADP iajs-152 114 36 130.8c0 130.8c0 NUM iajs-152 114 37 and and CCONJ iajs-152 114 38 363.20c 363.20c NUM iajs-152 114 39 , , PUNCT iajs-152 114 40 within within ADP iajs-152 114 41 mass mass ADJ iajs-152 114 42 losses loss NOUN iajs-152 114 43 of of ADP iajs-152 114 44 68.4125%(calc 68.4125%(calc NUM iajs-152 114 45 . . PUNCT iajs-152 115 1 = = NOUN iajs-152 115 2 69.44892265 69.44892265 NUM iajs-152 115 3 % % NOUN iajs-152 115 4 ) ) PUNCT iajs-152 115 5 . . PUNCT iajs-152 116 1 the the DET iajs-152 116 2 final final ADJ iajs-152 116 3 stage stage NOUN iajs-152 116 4 is be AUX iajs-152 116 5 the the DET iajs-152 116 6 loss loss NOUN iajs-152 116 7 ( ( PUNCT iajs-152 116 8 mo mo NOUN iajs-152 116 9 ) ) PUNCT iajs-152 116 10 within within ADP iajs-152 116 11 the the DET iajs-152 116 12 temperature temperature NOUN iajs-152 116 13 range range NOUN iajs-152 116 14 of of ADP iajs-152 116 15 402.12 402.12 NUM iajs-152 116 16 - - SYM iajs-152 116 17 593.610c 593.610c NUM iajs-152 116 18 within within ADP iajs-152 116 19 mass mass ADJ iajs-152 116 20 losses loss NOUN iajs-152 116 21 of of ADP iajs-152 116 22 16.0405 16.0405 NUM iajs-152 116 23 % % NOUN iajs-152 116 24 ( ( PUNCT iajs-152 116 25 calc calc NOUN iajs-152 116 26 . . PUNCT iajs-152 117 1 = = PRON iajs-152 117 2 16.8993 16.8993 NUM iajs-152 117 3 % % NOUN iajs-152 117 4 ) ) PUNCT iajs-152 117 5 , , PUNCT iajs-152 117 6 the the DET iajs-152 117 7 difference difference NOUN iajs-152 117 8 in in ADP iajs-152 117 9 the the DET iajs-152 117 10 calculations calculation NOUN iajs-152 117 11 in in ADP iajs-152 117 12 observed observe VERB iajs-152 117 13 of of ADP iajs-152 117 14 the the DET iajs-152 117 15 residue residue NOUN iajs-152 117 16 weight weight NOUN iajs-152 117 17 may may AUX iajs-152 117 18 be be AUX iajs-152 117 19 related relate VERB iajs-152 117 20 to to ADP iajs-152 117 21 the the DET iajs-152 117 22 sublimation sublimation NOUN iajs-152 117 23 upon upon SCONJ iajs-152 117 24 thermal thermal ADJ iajs-152 117 25 decomposition[44 decomposition[44 VERB iajs-152 117 26 ] ] PUNCT iajs-152 117 27 . . PUNCT iajs-152 118 1 192 192 NUM iajs-152 118 2 | | ADV iajs-152 118 3 chemistry chemistry NOUN iajs-152 118 4 2015 2015 NUM iajs-152 118 5 ) ) PUNCT iajs-152 118 6 عام عام ADP iajs-152 118 7 3العدد 3العدد NUM iajs-152 118 8 ( ( PUNCT iajs-152 118 9 28مجلة 28مجلة X iajs-152 118 10 إبن إبن VERB iajs-152 118 11 الھيثم الھيثم NOUN iajs-152 118 12 للعلوم للعلوم NOUN iajs-152 118 13 الصرفة الصرفة NOUN iajs-152 119 1 و و PRON iajs-152 119 2 التطبيقية التطبيقية ADV iajs-152 119 3 المجلد المجلد VERB iajs-152 119 4 ibn ibn PROPN iajs-152 119 5 al al PROPN iajs-152 119 6 - - PUNCT iajs-152 119 7 haitham haitham PROPN iajs-152 119 8 jour jour X iajs-152 119 9 . . PROPN iajs-152 120 1 for for ADP iajs-152 120 2 pure pure ADJ iajs-152 120 3 & & CCONJ iajs-152 120 4 appl appl PROPN iajs-152 120 5 . . PUNCT iajs-152 121 1 sci sci PROPN iajs-152 121 2 . . PUNCT iajs-152 121 3 vol vol NOUN iajs-152 121 4 . . PROPN iajs-152 122 1 28 28 NUM iajs-152 122 2 ( ( PUNCT iajs-152 122 3 3 3 NUM iajs-152 122 4 ) ) PUNCT iajs-152 122 5 2015 2015 NUM iajs-152 122 6 reference reference NOUN iajs-152 122 7 1koh 1koh NUM iajs-152 122 8 , , PUNCT iajs-152 122 9 j. j. PROPN iajs-152 122 10 and and CCONJ iajs-152 122 11 greaves greave NOUN iajs-152 122 12 . . PUNCT iajs-152 123 1 a.j a.j PROPN iajs-152 123 2 , , PUNCT iajs-152 123 3 ( ( PUNCT iajs-152 123 4 2001 2001 NUM iajs-152 123 5 ) ) PUNCT iajs-152 123 6 , , PUNCT iajs-152 123 7 synthesis synthesis NOUN iajs-152 123 8 and and CCONJ iajs-152 123 9 application application NOUN iajs-152 123 10 of of ADP iajs-152 123 11 an an DET iajs-152 123 12 alkali alkali ADJ iajs-152 123 13 - - PUNCT iajs-152 123 14 clearable clearable ADJ iajs-152 123 15 azo azo NOUN iajs-152 123 16 disperse disperse NOUN iajs-152 123 17 dye dye NOUN iajs-152 123 18 containing contain VERB iajs-152 123 19 a a DET iajs-152 123 20 fluorosulfonyl fluorosulfonyl ADJ iajs-152 123 21 group group NOUN iajs-152 123 22 and and CCONJ iajs-152 123 23 analysis analysis NOUN iajs-152 123 24 of of ADP iajs-152 123 25 its its PRON iajs-152 123 26 alkali alkali ADJ iajs-152 123 27 - - PUNCT iajs-152 123 28 hydrolysis hydrolysis NOUN iajs-152 123 29 kinetics kinetic NOUN iajs-152 123 30 , , PUNCT iajs-152 123 31 dyes dye NOUN iajs-152 123 32 pigments pigment NOUN iajs-152 123 33 50 50 NUM iajs-152 123 34 , , PUNCT iajs-152 123 35 117 117 NUM iajs-152 123 36 - - SYM iajs-152 123 37 126 126 NUM iajs-152 123 38 . . PUNCT iajs-152 124 1 2sekar 2sekar NUM iajs-152 124 2 , , PUNCT iajs-152 124 3 n. n. NOUN iajs-152 124 4 ( ( PUNCT iajs-152 124 5 1999),colourage 1999),colourage NUM iajs-152 124 6 46 46 NUM iajs-152 124 7 , , PUNCT iajs-152 124 8 63 63 NUM iajs-152 124 9 - - SYM iajs-152 124 10 65 65 NUM iajs-152 124 11 . . PUNCT iajs-152 125 1 3katz 3katz NUM iajs-152 125 2 , , PUNCT iajs-152 125 3 h.e h.e PROPN iajs-152 125 4 , , PUNCT iajs-152 125 5 singe singe PROPN iajs-152 125 6 k.d k.d PROPN iajs-152 125 7 . . PUNCT iajs-152 126 1 r r PROPN iajs-152 126 2 , , PUNCT iajs-152 126 3 sohn sohn PROPN iajs-152 126 4 .j.e .j.e PROPN iajs-152 126 5 , , PUNCT iajs-152 126 6 dirk dirk PROPN iajs-152 126 7 .c.w .c.w PROPN iajs-152 126 8 , , PUNCT iajs-152 126 9 king king NOUN iajs-152 126 10 .l.a .l.a PROPN iajs-152 126 11 and and CCONJ iajs-152 126 12 gordon gordon PROPN iajs-152 126 13 .h.m,(1987 .h.m,(1987 PROPN iajs-152 126 14 ) ) PUNCT iajs-152 126 15 , , PUNCT iajs-152 126 16 j. j. PROPN iajs-152 126 17 am.chem am.chem PROPN iajs-152 126 18 . . PUNCT iajs-152 126 19 soc soc PROPN iajs-152 126 20 . . PUNCT iajs-152 127 1 109 109 NUM iajs-152 127 2 ( ( PUNCT iajs-152 127 3 21),6561 21),6561 NUM iajs-152 127 4 - - SYM iajs-152 127 5 6563 6563 NUM iajs-152 127 6 . . PUNCT iajs-152 128 1 4abe 4abe NUM iajs-152 128 2 , , PUNCT iajs-152 128 3 t. t. PROPN iajs-152 128 4 ; ; PUNCT iajs-152 128 5 mano mano PROPN iajs-152 128 6 . . PUNCT iajs-152 129 1 s. s. PROPN iajs-152 129 2 ; ; PUNCT iajs-152 129 3 yamada yamada PROPN iajs-152 129 4 , , PUNCT iajs-152 129 5 y. y. PROPN iajs-152 129 6 and and CCONJ iajs-152 129 7 tomotake tomotake NOUN iajs-152 129 8 . . PUNCT iajs-152 130 1 a a DET iajs-152 130 2 , , PUNCT iajs-152 130 3 ( ( PUNCT iajs-152 130 4 1999 1999 NUM iajs-152 130 5 ) ) PUNCT iajs-152 130 6 , , PUNCT iajs-152 130 7 j. j. PROPN iajs-152 130 8 imag imag PROPN iajs-152 130 9 . . PUNCT iajs-152 131 1 sci sci PROPN iajs-152 131 2 . . PUNCT iajs-152 131 3 tech tech PROPN iajs-152 131 4 . . PUNCT iajs-152 132 1 43 43 NUM iajs-152 132 2 , , PUNCT iajs-152 132 3 339 339 NUM iajs-152 132 4 - - SYM iajs-152 132 5 344 344 NUM iajs-152 132 6 . . PUNCT iajs-152 133 1 5chino.t 5chino.t NUM iajs-152 133 2 and and CCONJ iajs-152 133 3 yamada yamada PROPN iajs-152 133 4 m m PROPN iajs-152 133 5 , , PUNCT iajs-152 133 6 ( ( PUNCT iajs-152 133 7 2002 2002 NUM iajs-152 133 8 ) ) PUNCT iajs-152 133 9 , , PUNCT iajs-152 133 10 jp jp NOUN iajs-152 133 11 2001220519 2001220519 NUM iajs-152 133 12 . . PUNCT iajs-152 134 1 6wang 6wang NUM iajs-152 134 2 , , PUNCT iajs-152 134 3 s. s. PROPN iajs-152 134 4 ; ; PUNCT iajs-152 134 5 shen shen PROPN iajs-152 134 6 , , PUNCT iajs-152 134 7 s. s. PROPN iajs-152 134 8 and and CCONJ iajs-152 134 9 xu xu PROPN iajs-152 134 10 .h .h PROPN iajs-152 134 11 , , PUNCT iajs-152 134 12 ( ( PUNCT iajs-152 134 13 2000 2000 NUM iajs-152 134 14 ) ) PUNCT iajs-152 134 15 , , PUNCT iajs-152 134 16 dyes dye NOUN iajs-152 134 17 pigments pigment NOUN iajs-152 134 18 44 44 NUM iajs-152 134 19 , , PUNCT iajs-152 134 20 195 195 NUM iajs-152 134 21 - - SYM iajs-152 134 22 198 198 NUM iajs-152 134 23 . . PUNCT iajs-152 135 1 7hallas 7hallas NUM iajs-152 135 2 , , PUNCT iajs-152 135 3 g. g. PROPN iajs-152 135 4 and and CCONJ iajs-152 135 5 choi choi PROPN iajs-152 135 6 , , PUNCT iajs-152 135 7 j.h j.h PROPN iajs-152 135 8 . . PROPN iajs-152 135 9 ; ; PUNCT iajs-152 135 10 synthesis synthesis NOUN iajs-152 135 11 and and CCONJ iajs-152 135 12 properties property NOUN iajs-152 135 13 of of ADP iajs-152 135 14 novel novel ADJ iajs-152 135 15 aziridinyl aziridinyl NOUN iajs-152 135 16 azo azo NOUN iajs-152 135 17 from from ADP iajs-152 135 18 2amino 2amino NUM iajs-152 135 19 thiophenes thiophene NOUN iajs-152 135 20 - - PUNCT iajs-152 135 21 part part NOUN iajs-152 135 22 2 2 NUM iajs-152 135 23 , , PUNCT iajs-152 135 24 application application NOUN iajs-152 135 25 of of ADP iajs-152 135 26 some some DET iajs-152 135 27 disperse disperse ADJ iajs-152 135 28 azo azo NOUN iajs-152 135 29 dyes dye NOUN iajs-152 135 30 to to ADP iajs-152 135 31 polyester polyester NOUN iajs-152 135 32 fibres fibre NOUN iajs-152 135 33 , , PUNCT iajs-152 135 34 ( ( PUNCT iajs-152 135 35 1999 1999 NUM iajs-152 135 36 ) ) PUNCT iajs-152 135 37 , , PUNCT iajs-152 135 38 dyes dye NOUN iajs-152 135 39 pigments pigment NOUN iajs-152 135 40 40 40 NUM iajs-152 135 41 , , PUNCT iajs-152 135 42 119 119 NUM iajs-152 135 43 - - SYM iajs-152 135 44 129 129 NUM iajs-152 135 45 . . PUNCT iajs-152 136 1 8gregory 8gregory NUM iajs-152 136 2 , , PUNCT iajs-152 136 3 p. p. NOUN iajs-152 136 4 ; ; PUNCT iajs-152 136 5 waring waring NOUN iajs-152 136 6 , , PUNCT iajs-152 136 7 d.r d.r PROPN iajs-152 136 8 . . PROPN iajs-152 136 9 and and CCONJ iajs-152 136 10 hallos hallos PROPN iajs-152 136 11 .g .g PROPN iajs-152 136 12 , , PUNCT iajs-152 136 13 ( ( PUNCT iajs-152 136 14 1990 1990 NUM iajs-152 136 15 ) ) PUNCT iajs-152 136 16 , , PUNCT iajs-152 136 17 ‘ ' PUNCT iajs-152 136 18 the the DET iajs-152 136 19 chemistry chemistry NOUN iajs-152 136 20 and and CCONJ iajs-152 136 21 application application NOUN iajs-152 136 22 of of ADP iajs-152 136 23 dyes dye NOUN iajs-152 136 24 ’ ' PUNCT iajs-152 136 25 , , PUNCT iajs-152 136 26 18 18 NUM iajs-152 136 27 - - SYM iajs-152 136 28 20 20 NUM iajs-152 136 29 , , PUNCT iajs-152 136 30 plenum plenum PROPN iajs-152 136 31 press press PROPN iajs-152 136 32 , , PUNCT iajs-152 136 33 london london PROPN iajs-152 136 34 . . PUNCT iajs-152 137 1 9kandil 9kandil NUM iajs-152 137 2 , , PUNCT iajs-152 137 3 s.s s.s PROPN iajs-152 137 4 . . PROPN iajs-152 137 5 ( ( PUNCT iajs-152 137 6 1998 1998 NUM iajs-152 137 7 ) ) PUNCT iajs-152 137 8 , , PUNCT iajs-152 137 9 trans trans PROPN iajs-152 137 10 . . PROPN iajs-152 137 11 met meet VERB iajs-152 137 12 . . PUNCT iajs-152 138 1 chem chem NOUN iajs-152 138 2 . . PUNCT iajs-152 139 1 23 23 NUM iajs-152 139 2 , , PUNCT iajs-152 139 3 461 461 NUM iajs-152 139 4 - - SYM iajs-152 139 5 465 465 NUM iajs-152 139 6 . . PUNCT iajs-152 140 1 10williams 10williams NUM iajs-152 140 2 , , PUNCT iajs-152 140 3 a a DET iajs-152 140 4 f. f. PROPN iajs-152 140 5 ; ; PUNCT iajs-152 140 6 piguet piguet PROPN iajs-152 140 7 , , PUNCT iajs-152 140 8 c. c. PROPN iajs-152 140 9 and and CCONJ iajs-152 140 10 bernardinelli bernardinelli PROPN iajs-152 140 11 . . PUNCT iajs-152 141 1 g,(1991 g,(1991 PROPN iajs-152 141 2 ) ) PUNCT iajs-152 141 3 , , PUNCT iajs-152 141 4 angew angew NOUN iajs-152 141 5 . . PUNCT iajs-152 142 1 chem chem PROPN iajs-152 142 2 . . PUNCT iajs-152 143 1 int int NOUN iajs-152 143 2 . . PUNCT iajs-152 144 1 edit edit PROPN iajs-152 144 2 . . PUNCT iajs-152 145 1 30 30 NUM iajs-152 145 2 1490 1490 NUM iajs-152 145 3 . . PUNCT iajs-152 146 1 11hurley 11hurley NUM iajs-152 146 2 , , PUNCT iajs-152 146 3 d d NOUN iajs-152 146 4 j. j. PROPN iajs-152 146 5 and and CCONJ iajs-152 146 6 tor tor PROPN iajs-152 146 7 , , PUNCT iajs-152 146 8 y y PROPN iajs-152 146 9 , , PUNCT iajs-152 146 10 ( ( PUNCT iajs-152 146 11 2002 2002 NUM iajs-152 146 12 ) ) PUNCT iajs-152 146 13 , , PUNCT iajs-152 146 14 j. j. PROPN iajs-152 146 15 am am PROPN iajs-152 146 16 . . PUNCT iajs-152 147 1 chem chem NOUN iajs-152 147 2 . . PUNCT iajs-152 148 1 soc soc PROPN iajs-152 148 2 . . PUNCT iajs-152 149 1 124 124 NUM iajs-152 149 2 3749 3749 NUM iajs-152 149 3 . . PUNCT iajs-152 150 1 12felder 12felder NUM iajs-152 150 2 . . PUNCT iajs-152 151 1 d d X iajs-152 151 2 , , PUNCT iajs-152 151 3 nierengarten nierengarten VERB iajs-152 151 4 . . PUNCT iajs-152 152 1 j j PROPN iajs-152 152 2 f f X iajs-152 152 3 , , PUNCT iajs-152 152 4 barigelletti barigelletti NOUN iajs-152 152 5 . . PUNCT iajs-152 153 1 f f X iajs-152 153 2 , , PUNCT iajs-152 153 3 ventura ventura PROPN iajs-152 153 4 b b PROPN iajs-152 153 5 and and CCONJ iajs-152 153 6 armaroli armaroli PROPN iajs-152 153 7 n n CCONJ iajs-152 153 8 , , PUNCT iajs-152 153 9 ( ( PUNCT iajs-152 153 10 2001 2001 NUM iajs-152 153 11 ) ) PUNCT iajs-152 153 12 , , PUNCT iajs-152 153 13 highly highly ADV iajs-152 153 14 luminescent luminescent ADJ iajs-152 153 15 cu(i)-phenanthroline cu(i)-phenanthroline ADJ iajs-152 153 16 complexes complex NOUN iajs-152 153 17 in in ADP iajs-152 153 18 rigid rigid ADJ iajs-152 153 19 matrix matrix NOUN iajs-152 153 20 and and CCONJ iajs-152 153 21 temperature temperature NOUN iajs-152 153 22 dependence dependence NOUN iajs-152 153 23 of of ADP iajs-152 153 24 the the DET iajs-152 153 25 photophysical photophysical ADJ iajs-152 153 26 properties property NOUN iajs-152 153 27 . . PUNCT iajs-152 153 28 , , PUNCT iajs-152 153 29 j. j. PROPN iajs-152 153 30 am am PROPN iajs-152 153 31 . . PUNCT iajs-152 154 1 chem chem PROPN iajs-152 154 2 . . PUNCT iajs-152 155 1 soc.123 soc.123 PROPN iajs-152 155 2 6291 6291 NUM iajs-152 155 3 . . PUNCT iajs-152 156 1 13baek 13baek X iajs-152 156 2 . . PUNCT iajs-152 157 1 n n CCONJ iajs-152 157 2 , , PUNCT iajs-152 157 3 kim kim PROPN iajs-152 157 4 h h PROPN iajs-152 157 5 , , PUNCT iajs-152 157 6 hwang hwang PROPN iajs-152 157 7 . . PUNCT iajs-152 158 1 g g PROPN iajs-152 158 2 and and CCONJ iajs-152 158 3 kim kim PROPN iajs-152 158 4 . . PUNCT iajs-152 159 1 b b PROPN iajs-152 159 2 , , PUNCT iajs-152 159 3 ( ( PUNCT iajs-152 159 4 2001 2001 NUM iajs-152 159 5 ) ) PUNCT iajs-152 159 6 , , PUNCT iajs-152 159 7 mol.cryst mol.cryst NOUN iajs-152 159 8 . . PUNCT iajs-152 160 1 liq liq NOUN iajs-152 160 2 . . PUNCT iajs-152 161 1 cryst cryst PROPN iajs-152 161 2 . . PUNCT iajs-152 162 1 370 370 NUM iajs-152 162 2 387 387 NUM iajs-152 162 3 . . PUNCT iajs-152 163 1 14connors 14connors X iajs-152 163 2 . . PUNCT iajs-152 164 1 p p X iajs-152 164 2 j j PROPN iajs-152 164 3 , , PUNCT iajs-152 164 4 tzalis tzalis PROPN iajs-152 164 5 . . PUNCT iajs-152 165 1 j j PROPN iajs-152 165 2 d d PROPN iajs-152 165 3 , , PUNCT iajs-152 165 4 dunnick dunnick NOUN iajs-152 165 5 . . PUNCT iajs-152 166 1 a a DET iajs-152 166 2 l l NOUN iajs-152 166 3 and and CCONJ iajs-152 166 4 tor tor NOUN iajs-152 166 5 . . PUNCT iajs-152 167 1 y,(1998 y,(1998 X iajs-152 167 2 ) ) PUNCT iajs-152 167 3 , , PUNCT iajs-152 168 1 inorg inorg PROPN iajs-152 168 2 . . PUNCT iajs-152 169 1 chem chem PROPN iajs-152 169 2 . . PUNCT iajs-152 170 1 37 37 NUM iajs-152 170 2 1121 1121 NUM iajs-152 170 3 . . PUNCT iajs-152 171 1 15liu 15liu X iajs-152 171 2 . . PUNCT iajs-152 171 3 q q PUNCT iajs-152 172 1 d d NOUN iajs-152 172 2 , , PUNCT iajs-152 172 3 jia jia PROPN iajs-152 172 4 . . PROPN iajs-152 172 5 w w PROPN iajs-152 172 6 l l PROPN iajs-152 172 7 and and CCONJ iajs-152 172 8 wang wang PROPN iajs-152 172 9 . . PUNCT iajs-152 172 10 s s PART iajs-152 172 11 n n CCONJ iajs-152 172 12 , , PUNCT iajs-152 172 13 ( ( PUNCT iajs-152 172 14 2005 2005 NUM iajs-152 172 15 ) ) PUNCT iajs-152 172 16 , , PUNCT iajs-152 172 17 inorg inorg NOUN iajs-152 172 18 . . PUNCT iajs-152 173 1 chem.44 chem.44 NOUN iajs-152 173 2 1332 1332 NUM iajs-152 173 3 . . PUNCT iajs-152 174 1 16wu 16wu ADJ iajs-152 174 2 . . PUNCT iajs-152 175 1 s s X iajs-152 175 2 , , PUNCT iajs-152 175 3 qian qian PROPN iajs-152 175 4 . . PUNCT iajs-152 176 1 w w PROPN iajs-152 176 2 , , PUNCT iajs-152 176 3 xia xia PROPN iajs-152 176 4 . . PUNCT iajs-152 177 1 z z X iajs-152 177 2 , , PUNCT iajs-152 177 3 zou zou PROPN iajs-152 177 4 . . PUNCT iajs-152 178 1 y. y. PROPN iajs-152 178 2 , , PUNCT iajs-152 178 3 wan wan PROPN iajs-152 178 4 . . PUNCT iajs-152 178 5 s. s. PROPN iajs-152 178 6 gan gan PROPN iajs-152 178 7 shen shen PROPN iajs-152 178 8 . . PUNCT iajs-152 179 1 ds ds ADJ iajs-152 179 2 , , PUNCT iajs-152 179 3 ( ( PUNCT iajs-152 179 4 2000),chem 2000),chem NUM iajs-152 179 5 . . PUNCT iajs-152 180 1 phys phy NOUN iajs-152 180 2 . . PUNCT iajs-152 181 1 lett lett PROPN iajs-152 181 2 . . PUNCT iajs-152 182 1 330,535 330,535 NUM iajs-152 182 2 - - SYM iajs-152 182 3 540 540 NUM iajs-152 182 4 . . PUNCT iajs-152 183 1 17bazzicalupi 17bazzicalupi X iajs-152 183 2 . . PUNCT iajs-152 184 1 c c X iajs-152 184 2 , , PUNCT iajs-152 184 3 a. a. NOUN iajs-152 184 4 bianchi bianchi PROPN iajs-152 184 5 , , PUNCT iajs-152 184 6 giorgi giorgi PROPN iajs-152 184 7 .c .c PROPN iajs-152 184 8 and and CCONJ iajs-152 184 9 valtancoli valtancoli ADV iajs-152 184 10 .b .b PROPN iajs-152 184 11 , , PUNCT iajs-152 184 12 ( ( PUNCT iajs-152 184 13 2012 2012 NUM iajs-152 184 14 ) ) PUNCT iajs-152 184 15 , , PUNCT iajs-152 184 16 inorg inorg PROPN iajs-152 184 17 . . PUNCT iajs-152 185 1 chim chim PROPN iajs-152 185 2 . . PUNCT iajs-152 186 1 acta acta PROPN iajs-152 186 2 , , PUNCT iajs-152 186 3 381 381 NUM iajs-152 186 4 229 229 NUM iajs-152 186 5 . . PUNCT iajs-152 187 1 18motlagh 18motlagh NUM iajs-152 187 2 , , PUNCT iajs-152 187 3 m.k m.k INTJ iajs-152 187 4 ; ; PUNCT iajs-152 187 5 noroozifar noroozifar ADV iajs-152 187 6 , , PUNCT iajs-152 187 7 m. m. NOUN iajs-152 187 8 ; ; PUNCT iajs-152 187 9 moodi moodi NOUN iajs-152 187 10 , , PUNCT iajs-152 187 11 a. a. NOUN iajs-152 187 12 ; ; PUNCT iajs-152 187 13 niroomand niroomand PROPN iajs-152 187 14 , , PUNCT iajs-152 187 15 s s PART iajs-152 187 16 .(2013 .(2013 NUM iajs-152 187 17 ) ) PUNCT iajs-152 187 18 , , PUNCT iajs-152 187 19 j. j. PROPN iajs-152 187 20 photochem photochem PROPN iajs-152 187 21 . . PUNCT iajs-152 188 1 and and CCONJ iajs-152 188 2 photobio photobio NOUN iajs-152 188 3 . . PUNCT iajs-152 189 1 b b X iajs-152 189 2 : : PUNCT iajs-152 189 3 biology biology NOUN iajs-152 189 4 , , PUNCT iajs-152 189 5 ( ( PUNCT iajs-152 189 6 2013 2013 NUM iajs-152 189 7 ) ) PUNCT iajs-152 189 8 , , PUNCT iajs-152 189 9 article article NOUN iajs-152 189 10 in in ADP iajs-152 189 11 press press NOUN iajs-152 189 12 . . PUNCT iajs-152 190 1 19 19 NUM iajs-152 190 2 – – PUNCT iajs-152 190 3 devereux devereux PROPN iajs-152 190 4 . . PUNCT iajs-152 191 1 m m PROPN iajs-152 191 2 , , PUNCT iajs-152 191 3 mccann mccann PROPN iajs-152 191 4 . . PUNCT iajs-152 191 5 m m PROPN iajs-152 191 6 , , PUNCT iajs-152 191 7 kellett.a kellett.a PROPN iajs-152 191 8 . . PROPN iajs-152 191 9 , , PUNCT iajs-152 191 10 ( ( PUNCT iajs-152 191 11 2007 2007 NUM iajs-152 191 12 ) ) PUNCT iajs-152 191 13 , , PUNCT iajs-152 191 14 synthesis synthesis NOUN iajs-152 191 15 , , PUNCT iajs-152 191 16 x x ADJ iajs-152 191 17 - - NOUN iajs-152 191 18 ray ray NOUN iajs-152 191 19 crystal crystal NOUN iajs-152 191 20 structures structure NOUN iajs-152 191 21 and and CCONJ iajs-152 191 22 biomimetic biomimetic ADJ iajs-152 191 23 and and CCONJ iajs-152 191 24 anticancer anticancer NOUN iajs-152 191 25 activities activity NOUN iajs-152 191 26 of of ADP iajs-152 191 27 novel novel ADJ iajs-152 191 28 copper(ii)benzoate copper(ii)benzoate NOUN iajs-152 191 29 complexes complex NOUN iajs-152 191 30 incorporating incorporate VERB iajs-152 191 31 2-(4'thiazolyl)benzimidazole 2-(4'thiazolyl)benzimidazole NUM iajs-152 191 32 ( ( PUNCT iajs-152 191 33 thiabendazole thiabendazole NOUN iajs-152 191 34 ) ) PUNCT iajs-152 191 35 , , PUNCT iajs-152 191 36 2-(2 2-(2 NOUN iajs-152 191 37 - - PUNCT iajs-152 191 38 pyridyl)benzimidazole pyridyl)benzimidazole ADJ iajs-152 191 39 and and CCONJ iajs-152 191 40 1,10 1,10 NUM iajs-152 191 41 - - NUM iajs-152 191 42 phenanthroline phenanthroline NOUN iajs-152 191 43 as as ADP iajs-152 191 44 chelating chelate VERB iajs-152 191 45 nitrogen nitrogen NOUN iajs-152 191 46 donor donor NOUN iajs-152 191 47 ligands ligand NOUN iajs-152 191 48 . . PUNCT iajs-152 192 1 , , PUNCT iajs-152 192 2 j. j. PROPN iajs-152 192 3 inorg inorg PROPN iajs-152 192 4 . . PUNCT iajs-152 192 5 biochem biochem PROPN iajs-152 192 6 . . PUNCT iajs-152 193 1 101 101 NUM iajs-152 193 2 881 881 NUM iajs-152 193 3 . . PUNCT iajs-152 194 1 20singh 20singh NUM iajs-152 194 2 , , PUNCT iajs-152 194 3 m m PROPN iajs-152 194 4 and and CCONJ iajs-152 194 5 anant anant PROPN iajs-152 194 6 . . PUNCT iajs-152 195 1 s s X iajs-152 195 2 , , PUNCT iajs-152 195 3 ( ( PUNCT iajs-152 195 4 2012 2012 NUM iajs-152 195 5 ) ) PUNCT iajs-152 195 6 , , PUNCT iajs-152 195 7 synthesis synthesis NOUN iajs-152 195 8 and and CCONJ iajs-152 195 9 spectral spectral ADJ iajs-152 195 10 characterization characterization NOUN iajs-152 195 11 of of ADP iajs-152 195 12 praseodymium(iii praseodymium(iii ADJ iajs-152 195 13 ) ) PUNCT iajs-152 195 14 complex complex NOUN iajs-152 195 15 with with ADP iajs-152 195 16 new new ADJ iajs-152 195 17 amino amino NOUN iajs-152 195 18 acid acid NOUN iajs-152 195 19 - - PUNCT iajs-152 195 20 based base VERB iajs-152 195 21 azo azo NOUN iajs-152 195 22 dye dye PROPN iajs-152 195 23 , , PUNCT iajs-152 195 24 international international ADJ iajs-152 195 25 journal journal NOUN iajs-152 195 26 of of ADP iajs-152 195 27 inorganic inorganic ADJ iajs-152 195 28 chemistry chemistry NOUN iajs-152 195 29 , , PUNCT iajs-152 195 30 2012,id 2012,id PROPN iajs-152 195 31 767080 767080 NUM iajs-152 195 32 , , PUNCT iajs-152 195 33 6 6 NUM iajs-152 195 34 pages page NOUN iajs-152 195 35 , , PUNCT iajs-152 195 36 doi:10.1155/2012/767080 doi:10.1155/2012/767080 NOUN iajs-152 195 37 . . PUNCT iajs-152 196 1 21kocaokutgen 21kocaokutgen PROPN iajs-152 196 2 . . PUNCT iajs-152 197 1 h h PROPN iajs-152 197 2 and and CCONJ iajs-152 197 3 erdem erdem PROPN iajs-152 197 4 . . PUNCT iajs-152 198 1 e e X iajs-152 198 2 , , PUNCT iajs-152 198 3 ( ( PUNCT iajs-152 198 4 2004),synth 2004),synth X iajs-152 198 5 . . PUNCT iajs-152 199 1 react react VERB iajs-152 199 2 . . PUNCT iajs-152 200 1 inorg inorg PROPN iajs-152 200 2 . . PUNCT iajs-152 200 3 met meet VERB iajs-152 200 4 - - PUNCT iajs-152 200 5 org org NOUN iajs-152 200 6 . . PUNCT iajs-152 200 7 chem chem PROPN iajs-152 200 8 . . PUNCT iajs-152 201 1 , , PUNCT iajs-152 201 2 34 34 NUM iajs-152 201 3 - - SYM iajs-152 201 4 1843 1843 NUM iajs-152 201 5 . . PUNCT iajs-152 202 1 22law 22law PROPN iajs-152 202 2 , , PUNCT iajs-152 202 3 ky ky PROPN iajs-152 202 4 . . PROPN iajs-152 202 5 ; ; PUNCT iajs-152 202 6 tarnawskyj tarnawskyj NOUN iajs-152 202 7 , , PUNCT iajs-152 202 8 iw iw PROPN iajs-152 202 9 . . PUNCT iajs-152 202 10 and and CCONJ iajs-152 202 11 lubberts lubbert NOUN iajs-152 202 12 , , PUNCT iajs-152 202 13 pt pt X iajs-152 202 14 . . PROPN iajs-152 202 15 ( ( PUNCT iajs-152 202 16 1993 1993 NUM iajs-152 202 17 ) ) PUNCT iajs-152 202 18 , , PUNCT iajs-152 202 19 dyes dye NOUN iajs-152 202 20 pigment pigment NOUN iajs-152 202 21 , , PUNCT iajs-152 202 22 23 23 NUM iajs-152 202 23 - - SYM iajs-152 202 24 243 243 NUM iajs-152 202 25 . . PUNCT iajs-152 203 1 23erdem 23erdem NUM iajs-152 203 2 , , PUNCT iajs-152 203 3 e. e. PROPN iajs-152 203 4 ; ; PUNCT iajs-152 203 5 sari sari PROPN iajs-152 203 6 , , PUNCT iajs-152 203 7 e.y e.y PROPN iajs-152 203 8 . . PROPN iajs-152 203 9 ; ; PUNCT iajs-152 203 10 kilinçarslan kilinçarslan PROPN iajs-152 203 11 , , PUNCT iajs-152 203 12 r. r. PROPN iajs-152 203 13 and and CCONJ iajs-152 203 14 kabay kabay PROPN iajs-152 203 15 , , PUNCT iajs-152 203 16 n.(2009 n.(2009 PROPN iajs-152 203 17 ) ) PUNCT iajs-152 203 18 , , PUNCT iajs-152 203 19 kılınçarslan kılınçarslan PROPN iajs-152 203 20 , , PUNCT iajs-152 203 21 r. r. PROPN iajs-152 203 22 and and CCONJ iajs-152 203 23 kabay kabay PROPN iajs-152 203 24 , , PUNCT iajs-152 203 25 n. n. NOUN iajs-152 203 26 ‘ ' PUNCT iajs-152 203 27 synthesis synthesis NOUN iajs-152 203 28 and and CCONJ iajs-152 203 29 characterization characterization NOUN iajs-152 203 30 of of ADP iajs-152 203 31 azo azo NOUN iajs-152 203 32 - - PUNCT iajs-152 203 33 linked link VERB iajs-152 203 34 schiff schiff NOUN iajs-152 203 35 bases basis NOUN iajs-152 203 36 and and CCONJ iajs-152 203 37 their their PRON iajs-152 203 38 nickel(ii nickel(ii NOUN iajs-152 203 39 ) ) PUNCT iajs-152 203 40 and and CCONJ iajs-152 203 41 zinc(ii zinc(ii NOUN iajs-152 203 42 ) ) PUNCT iajs-152 203 43 complexes complex NOUN iajs-152 203 44 ’ ' PUNCT iajs-152 203 45 , , PUNCT iajs-152 203 46 transition transition NOUN iajs-152 203 47 metal metal NOUN iajs-152 203 48 chemistry chemistry NOUN iajs-152 203 49 , , PUNCT iajs-152 203 50 trans trans PROPN iajs-152 203 51 . . PROPN iajs-152 203 52 met meet VERB iajs-152 203 53 . . PUNCT iajs-152 204 1 chem chem NOUN iajs-152 204 2 . . PUNCT iajs-152 204 3 , , PUNCT iajs-152 204 4 34 34 NUM iajs-152 204 5 , , PUNCT iajs-152 204 6 167174 167174 NUM iajs-152 204 7 . . PUNCT iajs-152 205 1 24socrates 24socrates NUM iajs-152 205 2 , , PUNCT iajs-152 205 3 g.(1980 g.(1980 NOUN iajs-152 205 4 ) ) PUNCT iajs-152 205 5 , , PUNCT iajs-152 205 6 “ " PUNCT iajs-152 205 7 infrared infrared ADJ iajs-152 205 8 characteristic characteristic ADJ iajs-152 205 9 group group NOUN iajs-152 205 10 frequencies frequency NOUN iajs-152 205 11 ” " PUNCT iajs-152 205 12 , , PUNCT iajs-152 205 13 wiley wiley PROPN iajs-152 205 14 , , PUNCT iajs-152 205 15 new new PROPN iajs-152 205 16 york york PROPN iajs-152 205 17 . . PUNCT iajs-152 206 1 25karipcin 25karipcin PROPN iajs-152 206 2 , , PUNCT iajs-152 206 3 f. f. PROPN iajs-152 206 4 and and CCONJ iajs-152 206 5 kabalcilar kabalcilar PROPN iajs-152 206 6 . . PUNCT iajs-152 207 1 e,(2007 e,(2007 ADJ iajs-152 207 2 ) ) PUNCT iajs-152 207 3 , , PUNCT iajs-152 207 4 acta acta PROPN iajs-152 207 5 . . PUNCT iajs-152 208 1 chim chim PROPN iajs-152 208 2 . . PUNCT iajs-152 208 3 slov slov PROPN iajs-152 208 4 . . PROPN iajs-152 208 5 , , PUNCT iajs-152 208 6 54 54 NUM iajs-152 208 7 , , PUNCT iajs-152 208 8 242 242 NUM iajs-152 208 9 - - SYM iajs-152 208 10 247 247 NUM iajs-152 208 11 . . PUNCT iajs-152 209 1 26parikh 26parikh NUM iajs-152 209 2 . . PUNCT iajs-152 210 1 v.m v.m PROPN iajs-152 210 2 , , PUNCT iajs-152 210 3 ( ( PUNCT iajs-152 210 4 1985 1985 NUM iajs-152 210 5 ) ) PUNCT iajs-152 210 6 , , PUNCT iajs-152 210 7 “ " PUNCT iajs-152 210 8 absorption absorption NOUN iajs-152 210 9 spectroscopy spectroscopy NOUN iajs-152 210 10 of of ADP iajs-152 210 11 organic organic ADJ iajs-152 210 12 molecules molecule NOUN iajs-152 210 13 ” " PUNCT iajs-152 210 14 , , PUNCT iajs-152 210 15 translated translate VERB iajs-152 210 16 by by ADP iajs-152 210 17 abdul abdul PROPN iajs-152 210 18 hussain hussain PROPN iajs-152 210 19 khuthier khuthier PROPN iajs-152 210 20 , , PUNCT iajs-152 210 21 jasim jasim NOUN iajs-152 210 22 , , PUNCT iajs-152 210 23 m.a m.a PROPN iajs-152 210 24 . . PROPN iajs-152 210 25 , , PUNCT iajs-152 210 26 al al PROPN iajs-152 210 27 - - PUNCT iajs-152 210 28 rawi rawi PROPN iajs-152 210 29 , , PUNCT iajs-152 210 30 and and CCONJ iajs-152 210 31 mahammed mahammed PROPN iajs-152 210 32 a. a. PROPN iajs-152 210 33 al al PROPN iajs-152 210 34 - - PUNCT iajs-152 210 35 iraqi iraqi PROPN iajs-152 210 36 . . PUNCT iajs-152 211 1 27silverschtien 27silverschtien NUM iajs-152 211 2 , , PUNCT iajs-152 211 3 r.m r.m PROPN iajs-152 211 4 . . PROPN iajs-152 211 5 ; ; PUNCT iajs-152 211 6 bassler bassler NOUN iajs-152 211 7 , , PUNCT iajs-152 211 8 and and CCONJ iajs-152 211 9 morril morril PROPN iajs-152 211 10 , , PUNCT iajs-152 211 11 ( ( PUNCT iajs-152 211 12 1981 1981 NUM iajs-152 211 13 ) ) PUNCT iajs-152 211 14 , , PUNCT iajs-152 211 15 “ " PUNCT iajs-152 211 16 spectrophotometers spectrophotometer VERB iajs-152 211 17 indentification indentification NOUN iajs-152 211 18 of of ADP iajs-152 211 19 organic organic ADJ iajs-152 211 20 compound compound NOUN iajs-152 211 21 ” " PUNCT iajs-152 211 22 , , PUNCT iajs-152 211 23 translated translate VERB iajs-152 211 24 by by ADP iajs-152 211 25 ali ali PROPN iajs-152 211 26 hussain hussain PROPN iajs-152 211 27 and and CCONJ iajs-152 211 28 suphi suphi VERB iajs-152 211 29 al al PROPN iajs-152 211 30 - - PUNCT iajs-152 211 31 azawi azawi PROPN iajs-152 211 32 . . PUNCT iajs-152 212 1 193 193 NUM iajs-152 212 2 | | ADV iajs-152 212 3 chemistry chemistry NOUN iajs-152 212 4 2015 2015 NUM iajs-152 212 5 ) ) PUNCT iajs-152 212 6 عام عام ADP iajs-152 212 7 3العدد 3العدد NUM iajs-152 212 8 ( ( PUNCT iajs-152 212 9 28مجلة 28مجلة X iajs-152 212 10 إبن إبن VERB iajs-152 212 11 الھيثم الھيثم NOUN iajs-152 212 12 للعلوم للعلوم NOUN iajs-152 212 13 الصرفة الصرفة NOUN iajs-152 213 1 و و PRON iajs-152 213 2 التطبيقية التطبيقية ADV iajs-152 213 3 المجلد المجلد VERB iajs-152 213 4 ibn ibn PROPN iajs-152 213 5 al al PROPN iajs-152 213 6 - - PUNCT iajs-152 213 7 haitham haitham PROPN iajs-152 213 8 jour jour X iajs-152 213 9 . . PROPN iajs-152 214 1 for for ADP iajs-152 214 2 pure pure ADJ iajs-152 214 3 & & CCONJ iajs-152 214 4 appl appl PROPN iajs-152 214 5 . . PUNCT iajs-152 215 1 sci sci PROPN iajs-152 215 2 . . PUNCT iajs-152 215 3 vol vol NOUN iajs-152 215 4 . . PROPN iajs-152 216 1 28 28 NUM iajs-152 216 2 ( ( PUNCT iajs-152 216 3 3 3 NUM iajs-152 216 4 ) ) PUNCT iajs-152 216 5 2015 2015 NUM iajs-152 216 6 28souza 28souza NUM iajs-152 216 7 , , PUNCT iajs-152 216 8 p.;jose p.;jose PROPN iajs-152 216 9 , , PUNCT iajs-152 216 10 a. a. NOUN iajs-152 216 11 ; ; PUNCT iajs-152 216 12 vazguez vazguez NOUN iajs-152 216 13 , , PUNCT iajs-152 216 14 g.and g.and PROPN iajs-152 216 15 masaguer masaguer PROPN iajs-152 216 16 , , PUNCT iajs-152 216 17 jr jr PROPN iajs-152 216 18 . . PROPN iajs-152 216 19 ( ( PUNCT iajs-152 216 20 1985 1985 NUM iajs-152 216 21 ) ) PUNCT iajs-152 216 22 , , PUNCT iajs-152 216 23 trans trans PROPN iajs-152 216 24 . . PROPN iajs-152 216 25 met meet VERB iajs-152 216 26 . . PUNCT iajs-152 217 1 chem chem NOUN iajs-152 217 2 . . PUNCT iajs-152 218 1 , , PUNCT iajs-152 218 2 10 10 NUM iajs-152 218 3 - - SYM iajs-152 218 4 410 410 NUM iajs-152 218 5 . . PUNCT iajs-152 219 1 29swati 29swati NUM iajs-152 219 2 , , PUNCT iajs-152 219 3 p. p. NOUN iajs-152 219 4 ; ; PUNCT iajs-152 220 1 singh singh PROPN iajs-152 220 2 , , PUNCT iajs-152 220 3 r. r. PROPN iajs-152 220 4 ; ; PUNCT iajs-152 220 5 karnawat karnawat PROPN iajs-152 220 6 , , PUNCT iajs-152 220 7 i.k i.k PROPN iajs-152 220 8 ; ; PUNCT iajs-152 220 9 sharma sharma NOUN iajs-152 220 10 , , PUNCT iajs-152 220 11 and and CCONJ iajs-152 220 12 verma verma PROPN iajs-152 220 13 , , PUNCT iajs-152 220 14 p.s(2011 p.s(2011 NOUN iajs-152 220 15 ) ) PUNCT iajs-152 220 16 , , PUNCT iajs-152 220 17 synthesis synthesis NOUN iajs-152 220 18 , , PUNCT iajs-152 220 19 electrochemical electrochemical ADJ iajs-152 220 20 and and CCONJ iajs-152 220 21 antimicrobial antimicrobial ADJ iajs-152 220 22 studies study NOUN iajs-152 220 23 of of ADP iajs-152 220 24 2 2 NUM iajs-152 220 25 - - PUNCT iajs-152 220 26 phenylazo-1 phenylazo-1 NOUN iajs-152 220 27 - - PUNCT iajs-152 220 28 naphthol-4 naphthol-4 NUM iajs-152 220 29 - - PUNCT iajs-152 220 30 sulphonic sulphonic ADJ iajs-152 220 31 acid acid NOUN iajs-152 220 32 , , PUNCT iajs-152 220 33 int int NOUN iajs-152 220 34 . . PUNCT iajs-152 221 1 j. j. PROPN iajs-152 221 2 chem chem PROPN iajs-152 221 3 . . PUNCT iajs-152 222 1 tech.res tech.re NOUN iajs-152 222 2 . . PROPN iajs-152 222 3 , , PUNCT iajs-152 222 4 3 3 NUM iajs-152 222 5 , , PUNCT iajs-152 222 6 3 3 NUM iajs-152 222 7 , , PUNCT iajs-152 222 8 1164 1164 NUM iajs-152 222 9 - - SYM iajs-152 222 10 1171 1171 NUM iajs-152 222 11 . . PUNCT iajs-152 223 1 30al 30al ADJ iajs-152 223 2 - - PUNCT iajs-152 223 3 rubaie rubaie NOUN iajs-152 223 4 , , PUNCT iajs-152 223 5 l.a.r.and l.a.r.and X iajs-152 223 6 mhessn mhessn PROPN iajs-152 223 7 , , PUNCT iajs-152 223 8 r. r. PROPN iajs-152 223 9 j j PROPN iajs-152 223 10 , , PUNCT iajs-152 223 11 ( ( PUNCT iajs-152 223 12 2012 2012 NUM iajs-152 223 13 ) ) PUNCT iajs-152 223 14 , , PUNCT iajs-152 223 15 synthesis synthesis NOUN iajs-152 223 16 and and CCONJ iajs-152 223 17 characterization characterization NOUN iajs-152 223 18 of of ADP iajs-152 223 19 azo azo NOUN iajs-152 223 20 dye dye NOUN iajs-152 223 21 para para NOUN iajs-152 223 22 red red ADJ iajs-152 223 23 and and CCONJ iajs-152 223 24 new new ADJ iajs-152 223 25 derivatives derivative NOUN iajs-152 223 26 , , PUNCT iajs-152 223 27 e e NOUN iajs-152 223 28 - - PROPN iajs-152 223 29 j. j. PROPN iajs-152 223 30 chem chem PROPN iajs-152 223 31 . . PUNCT iajs-152 223 32 , , PUNCT iajs-152 223 33 9 9 NUM iajs-152 223 34 , , PUNCT iajs-152 223 35 1 1 NUM iajs-152 223 36 , , PUNCT iajs-152 223 37 465 465 NUM iajs-152 223 38 - - SYM iajs-152 223 39 470 470 NUM iajs-152 223 40 . . PUNCT iajs-152 224 1 31masoud 31masoud NUM iajs-152 224 2 , , PUNCT iajs-152 224 3 m.s m.s PROPN iajs-152 224 4 . . PROPN iajs-152 224 5 and and CCONJ iajs-152 224 6 muhamed muhamed PROPN iajs-152 224 7 , , PUNCT iajs-152 224 8 g.b g.b PROPN iajs-152 224 9 , , PUNCT iajs-152 224 10 ( ( PUNCT iajs-152 224 11 2002 2002 NUM iajs-152 224 12 ) ) PUNCT iajs-152 224 13 , , PUNCT iajs-152 224 14 spectral spectral ADJ iajs-152 224 15 , , PUNCT iajs-152 224 16 magnetic magnetic ADJ iajs-152 224 17 and and CCONJ iajs-152 224 18 thermal thermal ADJ iajs-152 224 19 properties property NOUN iajs-152 224 20 of of ADP iajs-152 224 21 some some DET iajs-152 224 22 thiazolylazo thiazolylazo NOUN iajs-152 224 23 complexes complex NOUN iajs-152 224 24 , , PUNCT iajs-152 224 25 j. j. PROPN iajs-152 224 26 korean korean PROPN iajs-152 224 27 . . PUNCT iajs-152 225 1 chem chem PROPN iajs-152 225 2 . . PUNCT iajs-152 226 1 soc soc PROPN iajs-152 226 2 . . PUNCT iajs-152 227 1 2 2 NUM iajs-152 227 2 , , PUNCT iajs-152 227 3 99 99 NUM iajs-152 227 4 - - SYM iajs-152 227 5 116 116 NUM iajs-152 227 6 . . PUNCT iajs-152 228 1 32maiti 32maiti NUM iajs-152 228 2 , , PUNCT iajs-152 228 3 d. d. PROPN iajs-152 228 4 ; ; PUNCT iajs-152 228 5 paul paul PROPN iajs-152 228 6 , , PUNCT iajs-152 228 7 h. h. PROPN iajs-152 228 8 ; ; PUNCT iajs-152 228 9 chanda chanda PROPN iajs-152 228 10 , , PUNCT iajs-152 228 11 n. n. PROPN iajs-152 228 12 and and CCONJ iajs-152 228 13 chakraborty chakraborty PROPN iajs-152 228 14 , , PUNCT iajs-152 228 15 s. s. PROPN iajs-152 228 16 , , PUNCT iajs-152 228 17 ( ( PUNCT iajs-152 228 18 2004 2004 NUM iajs-152 228 19 ) ) PUNCT iajs-152 228 20 , , PUNCT iajs-152 228 21 polyhedron polyhedron NOUN iajs-152 228 22 23 23 NUM iajs-152 228 23 , , PUNCT iajs-152 228 24 831 831 NUM iajs-152 228 25 - - SYM iajs-152 228 26 840 840 NUM iajs-152 228 27 . . PUNCT iajs-152 229 1 33ertanan 33ertanan NUM iajs-152 229 2 , , PUNCT iajs-152 229 3 n. n. PROPN iajs-152 230 1 d d PROPN iajs-152 230 2 p. p. NOUN iajs-152 230 3 , , PUNCT iajs-152 230 4 g¨urkan,(1997),d g¨urkan,(1997),d PROPN iajs-152 230 5 yes yes INTJ iajs-152 230 6 pigments pigment NOUN iajs-152 230 7 33 33 NUM iajs-152 230 8 , , PUNCT iajs-152 230 9 137 137 NUM iajs-152 230 10 - - SYM iajs-152 230 11 147 147 NUM iajs-152 230 12 . . PUNCT iajs-152 231 1 34rentschler 34rentschler NUM iajs-152 231 2 . . PUNCT iajs-152 232 1 e e X iajs-152 232 2 , , PUNCT iajs-152 232 3 von von PROPN iajs-152 232 4 malotki malotki PROPN iajs-152 232 5 . . PUNCT iajs-152 233 1 c c X iajs-152 233 2 , , PUNCT iajs-152 233 3 ( ( PUNCT iajs-152 233 4 2008 2008 NUM iajs-152 233 5 ) ) PUNCT iajs-152 233 6 , , PUNCT iajs-152 233 7 inorg inorg PROPN iajs-152 233 8 . . PUNCT iajs-152 234 1 chimica chimica PROPN iajs-152 234 2 . . PUNCT iajs-152 235 1 acta acta PROPN iajs-152 235 2 , , PUNCT iajs-152 235 3 361 361 NUM iajs-152 235 4 , , PUNCT iajs-152 235 5 3646 3646 NUM iajs-152 235 6 . . PUNCT iajs-152 236 1 35dilip 35dilip NUM iajs-152 236 2 , , PUNCT iajs-152 236 3 c.s c.s PROPN iajs-152 236 4 , , PUNCT iajs-152 236 5 kumar kumar PROPN iajs-152 236 6 . . PUNCT iajs-152 237 1 v. v. PROPN iajs-152 237 2 s s PROPN iajs-152 237 3 , , PUNCT iajs-152 237 4 venison venison NOUN iajs-152 237 5 . . PUNCT iajs-152 238 1 s.j s.j PROPN iajs-152 238 2 . . PROPN iajs-152 238 3 , , PUNCT iajs-152 238 4 potheher potheher NOUN iajs-152 238 5 i.v i.v PROPN iajs-152 238 6 , , PUNCT iajs-152 238 7 subahashini subahashini PROPN iajs-152 238 8 . . PUNCT iajs-152 239 1 d. d. PROPN iajs-152 239 2 r r PROPN iajs-152 239 3 , , PUNCT iajs-152 239 4 ( ( PUNCT iajs-152 239 5 2013 2013 NUM iajs-152 239 6 ) ) PUNCT iajs-152 239 7 , , PUNCT iajs-152 239 8 synthesis synthesis NOUN iajs-152 239 9 , , PUNCT iajs-152 239 10 structural structural ADJ iajs-152 239 11 characterisation characterisation NOUN iajs-152 239 12 , , PUNCT iajs-152 239 13 bio bio ADJ iajs-152 239 14 - - ADJ iajs-152 239 15 potential potential ADJ iajs-152 239 16 efficiency efficiency NOUN iajs-152 239 17 and and CCONJ iajs-152 239 18 dna dna NOUN iajs-152 239 19 cleavage cleavage NOUN iajs-152 239 20 applications application NOUN iajs-152 239 21 of of ADP iajs-152 239 22 nicotinamide nicotinamide NOUN iajs-152 239 23 metal metal NOUN iajs-152 239 24 complexes complex NOUN iajs-152 239 25 , , PUNCT iajs-152 239 26 j. j. PROPN iajs-152 239 27 mol mol PROPN iajs-152 239 28 . . PROPN iajs-152 240 1 str str NOUN iajs-152 240 2 . . PUNCT iajs-152 240 3 , , PUNCT iajs-152 240 4 1040 1040 NUM iajs-152 240 5 , , PUNCT iajs-152 240 6 192 192 NUM iajs-152 240 7 . . PUNCT iajs-152 241 1 36el 36el NOUN iajs-152 241 2 - - PUNCT iajs-152 241 3 ghamry ghamry NOUN iajs-152 241 4 , , PUNCT iajs-152 241 5 m.a m.a PROPN iajs-152 241 6 .. .. PROPN iajs-152 241 7 ;saleh ;saleh PROPN iajs-152 241 8 , , PUNCT iajs-152 241 9 a.a a.a PROPN iajs-152 241 10 . . PROPN iajs-152 241 11 ; ; PUNCT iajs-152 241 12 khalil khalil PROPN iajs-152 241 13 . . PUNCT iajs-152 242 1 s.m.e s.m.e PROPN iajs-152 242 2 . . PROPN iajs-152 242 3 ; ; PUNCT iajs-152 242 4 mohammed mohammed PROPN iajs-152 242 5 , , PUNCT iajs-152 242 6 a.a a.a PROPN iajs-152 242 7 , , PUNCT iajs-152 242 8 ( ( PUNCT iajs-152 242 9 2013 2013 NUM iajs-152 242 10 ) ) PUNCT iajs-152 242 11 , , PUNCT iajs-152 242 12 mono mono PROPN iajs-152 242 13 , , PUNCT iajs-152 242 14 biand biand NOUN iajs-152 242 15 trinuclear trinuclear NOUN iajs-152 242 16 metal metal NOUN iajs-152 242 17 complexes complex NOUN iajs-152 242 18 derived derive VERB iajs-152 242 19 from from ADP iajs-152 242 20 new new ADJ iajs-152 242 21 benzene-1,4 benzene-1,4 NOUN iajs-152 242 22 - - PUNCT iajs-152 242 23 bis(3 bis(3 NOUN iajs-152 242 24 - - PUNCT iajs-152 242 25 pyridin-2 pyridin-2 NUM iajs-152 242 26 - - PUNCT iajs-152 242 27 ylurea ylurea NOUN iajs-152 242 28 ) ) PUNCT iajs-152 242 29 ligand ligand NOUN iajs-152 242 30 . . PUNCT iajs-152 243 1 spectral spectral ADJ iajs-152 243 2 , , PUNCT iajs-152 243 3 magnetic magnetic ADJ iajs-152 243 4 , , PUNCT iajs-152 243 5 thermal thermal ADJ iajs-152 243 6 and and CCONJ iajs-152 243 7 3d 3d NUM iajs-152 243 8 molecular molecular ADJ iajs-152 243 9 modeling modeling NOUN iajs-152 243 10 studies study NOUN iajs-152 243 11 . . PUNCT iajs-152 243 12 , , PUNCT iajs-152 243 13 spectrochim spectrochim PROPN iajs-152 243 14 . . PUNCT iajs-152 244 1 acta acta PROPN iajs-152 244 2 a a PRON iajs-152 244 3 , , PUNCT iajs-152 244 4 110 110 NUM iajs-152 244 5 205 205 NUM iajs-152 244 6 . . PUNCT iajs-152 245 1 37addison 37addison NUM iajs-152 245 2 , , PUNCT iajs-152 245 3 a.w a.w PROPN iajs-152 245 4 . . PROPN iajs-152 245 5 ; ; PUNCT iajs-152 245 6 rao rao PROPN iajs-152 245 7 , , PUNCT iajs-152 245 8 t.n t.n PROPN iajs-152 245 9 . . PROPN iajs-152 245 10 and and CCONJ iajs-152 245 11 sinn sinn PROPN iajs-152 245 12 , , PUNCT iajs-152 245 13 e. e. PROPN iajs-152 245 14 , , PUNCT iajs-152 245 15 ( ( PUNCT iajs-152 245 16 1984 1984 NUM iajs-152 245 17 ) ) PUNCT iajs-152 245 18 , , PUNCT iajs-152 245 19 inorg inorg PROPN iajs-152 245 20 . . PUNCT iajs-152 246 1 chem chem PROPN iajs-152 246 2 . . PUNCT iajs-152 247 1 , , PUNCT iajs-152 247 2 23 23 NUM iajs-152 247 3 , , PUNCT iajs-152 247 4 1957 1957 NUM iajs-152 247 5 - - SYM iajs-152 247 6 1967 1967 NUM iajs-152 247 7 . . PUNCT iajs-152 248 1 38preti 38preti NUM iajs-152 248 2 , , PUNCT iajs-152 248 3 c c X iajs-152 248 4 .. .. PUNCT iajs-152 248 5 and and CCONJ iajs-152 248 6 tosi tosi NOUN iajs-152 248 7 , , PUNCT iajs-152 248 8 g. g. PROPN iajs-152 248 9 , , PUNCT iajs-152 248 10 ( ( PUNCT iajs-152 248 11 1977 1977 NUM iajs-152 248 12 ) ) PUNCT iajs-152 248 13 can can AUX iajs-152 248 14 , , PUNCT iajs-152 248 15 j. j. PROPN iajs-152 248 16 chem chem PROPN iajs-152 248 17 , , PUNCT iajs-152 248 18 55 55 NUM iajs-152 248 19 , , PUNCT iajs-152 248 20 1409 1409 NUM iajs-152 248 21 . . PUNCT iajs-152 249 1 39vukovic 39vukovic NUM iajs-152 249 2 . . PUNCT iajs-152 250 1 n n CCONJ iajs-152 250 2 , , PUNCT iajs-152 250 3 sukdolak sukdolak NOUN iajs-152 250 4 . . PUNCT iajs-152 251 1 s s X iajs-152 251 2 , , PUNCT iajs-152 251 3 solujic solujic PROPN iajs-152 251 4 . . PUNCT iajs-152 252 1 s s PROPN iajs-152 252 2 , , PUNCT iajs-152 252 3 milosevic milosevic PROPN iajs-152 252 4 . . PUNCT iajs-152 253 1 t t PROPN iajs-152 253 2 , , PUNCT iajs-152 253 3 ( ( PUNCT iajs-152 253 4 2008 2008 NUM iajs-152 253 5 ) ) PUNCT iajs-152 253 6 , , PUNCT iajs-152 253 7 synthesis synthesis NOUN iajs-152 253 8 and and CCONJ iajs-152 253 9 antimicrobial antimicrobial ADJ iajs-152 253 10 evaluation evaluation NOUN iajs-152 253 11 of of ADP iajs-152 253 12 some some DET iajs-152 253 13 novel novel ADJ iajs-152 253 14 2 2 NUM iajs-152 253 15 - - PUNCT iajs-152 253 16 aminothiazole aminothiazole ADJ iajs-152 253 17 derivatives derivative NOUN iajs-152 253 18 of of ADP iajs-152 253 19 4 4 NUM iajs-152 253 20 - - PUNCT iajs-152 253 21 hydroxy hydroxy VERB iajs-152 253 22 - - PUNCT iajs-152 253 23 chromene-2 chromene-2 NUM iajs-152 253 24 - - PUNCT iajs-152 253 25 one one NUM iajs-152 253 26 , , PUNCT iajs-152 253 27 arch arch NOUN iajs-152 253 28 . . PUNCT iajs-152 254 1 pharm pharm NOUN iajs-152 254 2 . . PUNCT iajs-152 254 3 , , PUNCT iajs-152 254 4 341 341 NUM iajs-152 254 5 , , PUNCT iajs-152 254 6 491 491 NUM iajs-152 254 7 . . PUNCT iajs-152 255 1 40rover 40rover PRON iajs-152 255 2 , , PUNCT iajs-152 255 3 s.cesura s.cesura NOUN iajs-152 255 4 . . PUNCT iajs-152 256 1 m.a m.a PROPN iajs-152 256 2 , , PUNCT iajs-152 256 3 huguenin huguenin PROPN iajs-152 256 4 . . PUNCT iajs-152 257 1 p p X iajs-152 257 2 , , PUNCT iajs-152 257 3 szente szente NOUN iajs-152 257 4 . . PUNCT iajs-152 258 1 a a PRON iajs-152 258 2 , , PUNCT iajs-152 258 3 ( ( PUNCT iajs-152 258 4 1997 1997 NUM iajs-152 258 5 ) ) PUNCT iajs-152 258 6 , , PUNCT iajs-152 258 7 synthesis synthesis NOUN iajs-152 258 8 and and CCONJ iajs-152 258 9 biochemical biochemical ADJ iajs-152 258 10 evaluation evaluation NOUN iajs-152 258 11 of of ADP iajs-152 258 12 n-(4 n-(4 ADV iajs-152 258 13 - - PUNCT iajs-152 258 14 phenylthiazol-2 phenylthiazol-2 NOUN iajs-152 258 15 - - PUNCT iajs-152 258 16 yl)benzenesulfonamides yl)benzenesulfonamide NOUN iajs-152 258 17 as as ADP iajs-152 258 18 high high ADJ iajs-152 258 19 - - PUNCT iajs-152 258 20 affinity affinity NOUN iajs-152 258 21 inhibitors inhibitor NOUN iajs-152 258 22 of of ADP iajs-152 258 23 kynurenine kynurenine NOUN iajs-152 258 24 3hydroxylase 3hydroxylase NUM iajs-152 258 25 , , PUNCT iajs-152 258 26 j. j. PROPN iajs-152 258 27 med med PROPN iajs-152 258 28 . . PROPN iajs-152 258 29 chem chem PROPN iajs-152 258 30 . . PUNCT iajs-152 258 31 , , PUNCT iajs-152 258 32 40 40 NUM iajs-152 258 33 , , PUNCT iajs-152 258 34 4378 4378 NUM iajs-152 258 35 . . PUNCT iajs-152 259 1 41panico 41panico NUM iajs-152 259 2 . . PUNCT iajs-152 260 1 a.m a.m PROPN iajs-152 260 2 , , PUNCT iajs-152 260 3 geronikaki geronikaki PROPN iajs-152 260 4 . . PUNCT iajs-152 261 1 a. a. NOUN iajs-152 261 2 , , PUNCT iajs-152 261 3 mgonzo mgonzo NOUN iajs-152 261 4 . . PUNCT iajs-152 262 1 r r NOUN iajs-152 262 2 , , PUNCT iajs-152 262 3 cardile cardile ADJ iajs-152 262 4 .v .v ADJ iajs-152 262 5 , , PUNCT iajs-152 262 6 gentile gentile NOUN iajs-152 262 7 . . PUNCT iajs-152 263 1 b b NOUN iajs-152 263 2 and and CCONJ iajs-152 263 3 i. i. PROPN iajs-152 263 4 doytchinova doytchinova PROPN iajs-152 263 5 , , PUNCT iajs-152 263 6 ( ( PUNCT iajs-152 263 7 2003 2003 NUM iajs-152 263 8 ) ) PUNCT iajs-152 263 9 , , PUNCT iajs-152 263 10 aminothiazole aminothiazole ADJ iajs-152 263 11 derivatives derivative NOUN iajs-152 263 12 with with ADP iajs-152 263 13 antidegenerative antidegenerative ADJ iajs-152 263 14 activity activity NOUN iajs-152 263 15 on on ADP iajs-152 263 16 cartilage cartilage NOUN iajs-152 263 17 . . PUNCT iajs-152 264 1 , , PUNCT iajs-152 264 2 bioorg bioorg PROPN iajs-152 264 3 . . PUNCT iajs-152 265 1 med med PROPN iajs-152 265 2 . . PROPN iajs-152 265 3 chem chem PROPN iajs-152 265 4 . . PUNCT iajs-152 265 5 , , PUNCT iajs-152 265 6 11 11 NUM iajs-152 265 7 , , PUNCT iajs-152 265 8 2983 2983 NUM iajs-152 265 9 . . PUNCT iajs-152 266 1 42lever 42lever NUM iajs-152 266 2 , , PUNCT iajs-152 266 3 a.b.p a.b.p ADV iajs-152 266 4 . . PUNCT iajs-152 266 5 ( ( PUNCT iajs-152 266 6 1968 1968 NUM iajs-152 266 7 ) ) PUNCT iajs-152 266 8 , , PUNCT iajs-152 266 9 inorganic inorganic ADJ iajs-152 266 10 electronic electronic ADJ iajs-152 266 11 spectroscopy spectroscopy NOUN iajs-152 266 12 . . PUNCT iajs-152 267 1 amsterdam amsterdam PROPN iajs-152 267 2 : : PUNCT iajs-152 267 3 elsevier elsevier PROPN iajs-152 267 4 publishing publishing PROPN iajs-152 267 5 . . PUNCT iajs-152 268 1 co. co. PROPN iajs-152 268 2 ltd ltd PROPN iajs-152 268 3 . . PUNCT iajs-152 269 1 43tunçel 43tunçel NUM iajs-152 269 2 . . PUNCT iajs-152 270 1 mand mand PROPN iajs-152 270 2 serin serin PROPN iajs-152 270 3 . . PUNCT iajs-152 271 1 s s X iajs-152 271 2 , , PUNCT iajs-152 271 3 ( ( PUNCT iajs-152 271 4 2006 2006 NUM iajs-152 271 5 ) ) PUNCT iajs-152 271 6 , , PUNCT iajs-152 271 7 synthesis synthesis NOUN iajs-152 271 8 and and CCONJ iajs-152 271 9 characterization characterization NOUN iajs-152 271 10 of of ADP iajs-152 271 11 new new ADJ iajs-152 271 12 azo azo NOUN iajs-152 271 13 - - PUNCT iajs-152 271 14 linked link VERB iajs-152 271 15 schiff schiff NOUN iajs-152 271 16 bases basis NOUN iajs-152 271 17 and and CCONJ iajs-152 271 18 their their PRON iajs-152 271 19 cobalt(ii cobalt(ii NOUN iajs-152 271 20 ) ) PUNCT iajs-152 271 21 , , PUNCT iajs-152 271 22 copper(ii copper(ii PROPN iajs-152 271 23 ) ) PUNCT iajs-152 271 24 and and CCONJ iajs-152 271 25 nickel(ii nickel(ii ADJ iajs-152 271 26 ) ) PUNCT iajs-152 271 27 complexes complex NOUN iajs-152 271 28 , , PUNCT iajs-152 271 29 trans tran NOUN iajs-152 271 30 . . PROPN iajs-152 271 31 met meet VERB iajs-152 271 32 . . PUNCT iajs-152 272 1 chem chem NOUN iajs-152 272 2 . . PUNCT iajs-152 272 3 , , PUNCT iajs-152 272 4 31 31 NUM iajs-152 272 5 , , PUNCT iajs-152 272 6 805 805 NUM iajs-152 272 7 - - SYM iajs-152 272 8 812 812 NUM iajs-152 272 9 . . PROPN iajs-152 272 10 44 44 NUM iajs-152 272 11 yan yan PROPN iajs-152 272 12 . . PUNCT iajs-152 273 1 he he PRON iajs-152 273 2 , , PUNCT iajs-152 273 3 chaofan chaofan PROPN iajs-152 273 4 zhong zhong PROPN iajs-152 273 5 * * PROPN iajs-152 273 6 , , PUNCT iajs-152 273 7 zhou zhou PROPN iajs-152 273 8 . . PUNCT iajs-152 273 9 yu yu PROPN iajs-152 273 10 and and CCONJ iajs-152 273 11 hailiang hailiang PROPN iajs-152 273 12 zhang zhang PROPN iajs-152 273 13 , , PUNCT iajs-152 273 14 ( ( PUNCT iajs-152 273 15 2009 2009 NUM iajs-152 273 16 ) ) PUNCT iajs-152 273 17 , , PUNCT iajs-152 273 18 synthesis synthesis NOUN iajs-152 273 19 and and CCONJ iajs-152 273 20 luminescent luminescent NOUN iajs-152 273 21 properties property NOUN iajs-152 273 22 of of ADP iajs-152 273 23 novel novel ADJ iajs-152 273 24 cu cu PROPN iajs-152 273 25 ( ( PUNCT iajs-152 273 26 ii ii PROPN iajs-152 273 27 ) ) PUNCT iajs-152 273 28 , , PUNCT iajs-152 273 29 zn zn PROPN iajs-152 273 30 ( ( PUNCT iajs-152 273 31 ii)polymeric ii)polymeric NOUN iajs-152 273 32 complexes complex NOUN iajs-152 273 33 based base VERB iajs-152 273 34 on on ADP iajs-152 273 35 1,10phenanthroline 1,10phenanthroline NUM iajs-152 273 36 and and CCONJ iajs-152 273 37 biphenyl biphenyl NOUN iajs-152 273 38 groups group NOUN iajs-152 273 39 , , PUNCT iajs-152 273 40 j. j. PROPN iajs-152 273 41 chem chem PROPN iajs-152 273 42 . . PUNCT iajs-152 274 1 sci sci PROPN iajs-152 274 2 . . PROPN iajs-152 274 3 , , PUNCT iajs-152 274 4 121,4,407–412 121,4,407–412 NUM iajs-152 274 5 . . PUNCT iajs-152 275 1 45walaa 45walaa PROPN iajs-152 276 1 mahmoud1 mahmoud1 NOUN iajs-152 276 2 . . PUNCT iajs-152 277 1 h h NOUN iajs-152 277 2 , , PUNCT iajs-152 277 3 gehad gehad PROPN iajs-152 277 4 mohamed1 mohamed1 PROPN iajs-152 277 5 * * PROPN iajs-152 277 6 . . PUNCT iajs-152 278 1 g g PROPN iajs-152 278 2 , , PUNCT iajs-152 278 3 maher maher PROPN iajs-152 278 4 el el PROPN iajs-152 278 5 - - PUNCT iajs-152 278 6 dessouky1 dessouky1 PROPN iajs-152 278 7 ] ] PUNCT iajs-152 278 8 . . PUNCT iajs-152 279 1 m.i.(2014 m.i.(2014 X iajs-152 279 2 ) ) PUNCT iajs-152 280 1 , , PUNCT iajs-152 280 2 synthesis synthesis NOUN iajs-152 280 3 , , PUNCT iajs-152 280 4 characterization characterization NOUN iajs-152 280 5 and and CCONJ iajs-152 280 6 in in ADP iajs-152 280 7 vitro vitro X iajs-152 280 8 biological biological ADJ iajs-152 280 9 activity activity NOUN iajs-152 280 10 of of ADP iajs-152 280 11 mixed mixed ADJ iajs-152 280 12 transition transition NOUN iajs-152 280 13 metal metal NOUN iajs-152 280 14 complexes complex NOUN iajs-152 280 15 of of ADP iajs-152 280 16 lornoxicam lornoxicam NOUN iajs-152 280 17 with with ADP iajs-152 280 18 1,10 1,10 NUM iajs-152 280 19 - - ADJ iajs-152 280 20 phenanthroline phenanthroline NOUN iajs-152 280 21 , , PUNCT iajs-152 280 22 int int NOUN iajs-152 280 23 . . PUNCT iajs-152 281 1 j. j. PROPN iajs-152 281 2 electrochem electrochem PROPN iajs-152 281 3 . . PUNCT iajs-152 282 1 sci sci PROPN iajs-152 282 2 . . PROPN iajs-152 282 3 , , PUNCT iajs-152 282 4 9 9 NUM iajs-152 282 5 , , PUNCT iajs-152 282 6 1415 1415 NUM iajs-152 282 7 – – PUNCT iajs-152 282 8 1438 1438 NUM iajs-152 282 9 . . PUNCT iajs-152 283 1 194 194 NUM iajs-152 283 2 | | ADV iajs-152 283 3 chemistry chemistry NOUN iajs-152 283 4 2015 2015 NUM iajs-152 283 5 ) ) PUNCT iajs-152 283 6 عام عام ADP iajs-152 283 7 3العدد 3العدد NUM iajs-152 283 8 ( ( PUNCT iajs-152 283 9 28مجلة 28مجلة X iajs-152 283 10 إبن إبن VERB iajs-152 283 11 الھيثم الھيثم NOUN iajs-152 283 12 للعلوم للعلوم NOUN iajs-152 283 13 الصرفة الصرفة NOUN iajs-152 284 1 و و PRON iajs-152 284 2 التطبيقية التطبيقية ADV iajs-152 284 3 المجلد المجلد VERB iajs-152 284 4 ibn ibn PROPN iajs-152 284 5 al al PROPN iajs-152 284 6 - - PUNCT iajs-152 284 7 haitham haitham PROPN iajs-152 284 8 jour jour X iajs-152 284 9 . . PROPN iajs-152 285 1 for for ADP iajs-152 285 2 pure pure ADJ iajs-152 285 3 & & CCONJ iajs-152 285 4 appl appl PROPN iajs-152 285 5 . . PUNCT iajs-152 286 1 sci sci PROPN iajs-152 286 2 . . PUNCT iajs-152 286 3 vol vol NOUN iajs-152 286 4 . . 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PROPN iajs-152 314 1 for for ADP iajs-152 314 2 pure pure ADJ iajs-152 314 3 & & CCONJ iajs-152 314 4 appl appl PROPN iajs-152 314 5 . . PUNCT iajs-152 315 1 sci sci PROPN iajs-152 315 2 . . PUNCT iajs-152 315 3 vol vol NOUN iajs-152 315 4 . . PROPN iajs-152 316 1 28 28 NUM iajs-152 316 2 ( ( PUNCT iajs-152 316 3 3 3 NUM iajs-152 316 4 ) ) PUNCT iajs-152 316 5 2015 2015 NUM iajs-152 316 6 scheme scheme NOUN iajs-152 316 7 ( ( PUNCT iajs-152 316 8 1 1 NUM iajs-152 316 9 ): ): PUNCT iajs-152 316 10 synthesis synthesis NOUN iajs-152 316 11 of of ADP iajs-152 316 12 the the DET iajs-152 316 13 ligand ligand NOUN iajs-152 316 14 ( ( PUNCT iajs-152 316 15 hl hl NOUN iajs-152 316 16 ) ) PUNCT iajs-152 316 17 n n CCONJ iajs-152 316 18 n n PRON iajs-152 316 19 nh2 nh2 NOUN iajs-152 316 20 so3h so3h PROPN iajs-152 316 21 + + CCONJ iajs-152 316 22 ho ho PROPN iajs-152 316 23 n n CCONJ iajs-152 316 24 n n CCONJ iajs-152 316 25 n n CCONJ iajs-152 316 26 n n CCONJ iajs-152 316 27 n n CCONJ iajs-152 316 28 n n ADV iajs-152 316 29 nh2 nh2 PROPN iajs-152 316 30 o o NOUN iajs-152 316 31 so3na so3na PROPN iajs-152 316 32 m m PROPN iajs-152 316 33 ch3cooh ch3cooh NOUN iajs-152 316 34 , , PUNCT iajs-152 316 35 glacial glacial ADJ iajs-152 316 36 meoh meoh PROPN iajs-152 316 37 , , PUNCT iajs-152 316 38 naoh naoh NOUN iajs-152 316 39 ref ref NOUN iajs-152 316 40 lux lux VERB iajs-152 316 41 where where SCONJ iajs-152 316 42 : : PUNCT iajs-152 316 43 m= m= X iajs-152 316 44 coii coii PROPN iajs-152 316 45 , , PUNCT iajs-152 316 46 znii znii NOUN iajs-152 316 47 , , PUNCT iajs-152 316 48 cdii cdii NOUN iajs-152 316 49 , , PUNCT iajs-152 316 50 hgii hgii NOUN iajs-152 316 51 clh2o clh2o X iajs-152 316 52 scheme scheme NOUN iajs-152 316 53 ( ( PUNCT iajs-152 316 54 2 2 NUM iajs-152 316 55 ): ): PUNCT iajs-152 316 56 synthesis synthesis NOUN iajs-152 316 57 of of ADP iajs-152 316 58 the the DET iajs-152 316 59 complexe complexe PROPN iajs-152 316 60 fig fig NOUN iajs-152 316 61 ( ( PUNCT iajs-152 316 62 1 1 NUM iajs-152 316 63 ): ): PUNCT iajs-152 316 64 ir ir PROPN iajs-152 316 65 spectrum spectrum NOUN iajs-152 316 66 of of ADP iajs-152 316 67 the the DET iajs-152 316 68 ligand(hl ligand(hl NOUN iajs-152 316 69 ) ) PUNCT iajs-152 316 70 fig fig NOUN iajs-152 316 71 ( ( PUNCT iajs-152 316 72 2 2 NUM iajs-152 316 73 ): ): PUNCT iajs-152 316 74 ir ir PROPN iajs-152 316 75 spectrum spectrum NOUN iajs-152 316 76 of of ADP iajs-152 316 77 the the DET iajs-152 316 78 1,10 1,10 NUM iajs-152 316 79 - - PUNCT iajs-152 316 80 phenanthrolin phenanthrolin NOUN iajs-152 316 81 [ [ X iajs-152 316 82 w w X iajs-152 316 83 ] ] X iajs-152 316 84 nano2 nano2 NOUN iajs-152 316 85 ice ice NOUN iajs-152 316 86 bath bath NOUN iajs-152 316 87 ( ( PUNCT iajs-152 316 88 0 0 NUM iajs-152 316 89 co co NOUN iajs-152 316 90 ) ) PUNCT iajs-152 316 91 hcl hcl PROPN iajs-152 316 92 con con PROPN iajs-152 316 93 . . PUNCT iajs-152 317 1 n n PROPN iajs-152 317 2 nnh2 nnh2 PROPN iajs-152 317 3 1 1 NUM iajs-152 317 4 - - PUNCT iajs-152 317 5 naphthyl naphthyl NOUN iajs-152 317 6 amine amine ADJ iajs-152 317 7 sodium sodium NOUN iajs-152 317 8 nitrite nitrite NOUN iajs-152 317 9 diazonium diazonium NOUN iajs-152 317 10 salt salt NOUN iajs-152 317 11 n n CCONJ iajs-152 317 12 n n CCONJ iajs-152 317 13 ho ho ADJ iajs-152 317 14 so3h so3h PROPN iajs-152 317 15 nh2 nh2 NOUN iajs-152 317 16 diazonium diazonium NOUN iajs-152 317 17 salt salt NOUN iajs-152 317 18 1 1 NUM iajs-152 317 19 - - PUNCT iajs-152 317 20 amino-2 amino-2 NUM iajs-152 317 21 - - PUNCT iajs-152 317 22 naphtol-4 naphtol-4 NUM iajs-152 317 23 - - PUNCT iajs-152 317 24 sulfonic sulfonic ADJ iajs-152 317 25 acid acid NOUN iajs-152 317 26 [ [ X iajs-152 317 27 dissolved dissolve VERB iajs-152 317 28 in in ADP iajs-152 317 29 10 10 NUM iajs-152 317 30 ml ml NOUN iajs-152 317 31 aqueous aqueous ADJ iajs-152 317 32 naoh naoh NOUN iajs-152 317 33 ( ( PUNCT iajs-152 317 34 10 10 NUM iajs-152 317 35 mmol mmol NOUN iajs-152 317 36 ) ) PUNCT iajs-152 317 37 ] ] PUNCT iajs-152 318 1 ho ho PROPN iajs-152 319 1 so3h so3h PROPN iajs-152 319 2 nh2 nh2 PROPN iajs-152 319 3 n n CCONJ iajs-152 319 4 n n PRON iajs-152 319 5 ice ice NOUN iajs-152 319 6 bath bath NOUN iajs-152 319 7 ( ( PUNCT iajs-152 319 8 0 0 NUM iajs-152 319 9 co co NOUN iajs-152 319 10 ) ) PUNCT iajs-152 319 11 2-(2-(naphthalen-5 2-(2-(naphthalen-5 NUM iajs-152 319 12 - - PUNCT iajs-152 319 13 yl)diazenyl yl)diazenyl NOUN iajs-152 319 14 ) ) PUNCT iajs-152 319 15 -4 -4 PROPN iajs-152 319 16 - - PUNCT iajs-152 319 17 amino-3 amino-3 NOUN iajs-152 319 18 - - PUNCT iajs-152 319 19 hydroxynaphthalene-1 hydroxynaphthalene-1 NOUN iajs-152 319 20 - - PUNCT iajs-152 319 21 sulfonic sulfonic ADJ iajs-152 319 22 acid acid NOUN iajs-152 319 23 cl cl NOUN iajs-152 319 24 cl cl NOUN iajs-152 319 25 198 198 NUM iajs-152 319 26 | | NOUN iajs-152 319 27 chemistry chemistry NOUN iajs-152 319 28 2015 2015 NUM iajs-152 319 29 ) ) PUNCT iajs-152 319 30 عام عام ADP iajs-152 319 31 3العدد 3العدد NUM iajs-152 319 32 ( ( PUNCT iajs-152 319 33 28مجلة 28مجلة X iajs-152 319 34 إبن إبن VERB iajs-152 319 35 الھيثم الھيثم NOUN iajs-152 319 36 للعلوم للعلوم NOUN iajs-152 319 37 الصرفة الصرفة NOUN iajs-152 320 1 و و PRON iajs-152 320 2 التطبيقية التطبيقية ADV iajs-152 320 3 المجلد المجلد VERB iajs-152 320 4 ibn ibn PROPN iajs-152 320 5 al al PROPN iajs-152 320 6 - - PUNCT iajs-152 320 7 haitham haitham PROPN iajs-152 320 8 jour jour X iajs-152 320 9 . . 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PROPN iajs-152 323 1 28 28 NUM iajs-152 323 2 ( ( PUNCT iajs-152 323 3 3 3 NUM iajs-152 323 4 ) ) PUNCT iajs-152 323 5 2015 2015 NUM iajs-152 323 6 fig fig NOUN iajs-152 323 7 ( ( PUNCT iajs-152 323 8 3):ir 3):ir NUM iajs-152 323 9 spectrum spectrum NOUN iajs-152 323 10 of of ADP iajs-152 323 11 the the DET iajs-152 323 12 [ [ NOUN iajs-152 323 13 co(l)(phen)(h2o)cl co(l)(phen)(h2o)cl NOUN iajs-152 323 14 ] ] PUNCT iajs-152 323 15 fig fig NOUN iajs-152 323 16 ( ( PUNCT iajs-152 323 17 4 4 NUM iajs-152 323 18 ): ): PUNCT iajs-152 323 19 ir ir PROPN iajs-152 323 20 spectrum spectrum NOUN iajs-152 323 21 of of ADP iajs-152 323 22 the[zn(l)(phen)(h2o)cl the[zn(l)(phen)(h2o)cl NOUN iajs-152 323 23 ] ] X iajs-152 323 24 fig fig NOUN iajs-152 323 25 ( ( PUNCT iajs-152 323 26 5 5 NUM iajs-152 323 27 ): ): PUNCT iajs-152 323 28 ir ir PROPN iajs-152 323 29 spectrum spectrum NOUN iajs-152 323 30 of of ADP iajs-152 323 31 the[cd(l)(phen)(h2o)cl the[cd(l)(phen)(h2o)cl NOUN iajs-152 323 32 ] ] PUNCT iajs-152 323 33 fig fig NOUN iajs-152 323 34 ( ( PUNCT iajs-152 323 35 6 6 NUM iajs-152 323 36 ): ): PUNCT iajs-152 323 37 ir ir PROPN iajs-152 323 38 spectrum spectrum NOUN iajs-152 323 39 of of ADP iajs-152 323 40 the[hg(l)(phen)(h2o)cl the[hg(l)(phen)(h2o)cl PROPN iajs-152 323 41 ] ] X iajs-152 323 42 fig fig NOUN iajs-152 323 43 ( ( PUNCT iajs-152 323 44 7 7 NUM iajs-152 323 45 ): ): PUNCT iajs-152 323 46 uv uv NOUN iajs-152 323 47 spectrum spectrum NOUN iajs-152 323 48 of of ADP iajs-152 323 49 the the DET iajs-152 323 50 ligand ligand ADJ iajs-152 323 51 199 199 NUM iajs-152 323 52 | | NOUN iajs-152 323 53 chemistry chemistry NOUN iajs-152 323 54 2015 2015 NUM iajs-152 323 55 ) ) PUNCT iajs-152 323 56 عام عام ADP iajs-152 323 57 3العدد 3العدد NUM iajs-152 323 58 ( ( PUNCT iajs-152 323 59 28مجلة 28مجلة X iajs-152 323 60 إبن إبن VERB iajs-152 323 61 الھيثم الھيثم NOUN iajs-152 323 62 للعلوم للعلوم NOUN iajs-152 323 63 الصرفة الصرفة NOUN iajs-152 323 64 و و PRON iajs-152 324 1 التطبيقية التطبيقية ADV iajs-152 324 2 المجلد المجلد VERB iajs-152 324 3 ibn ibn PROPN iajs-152 324 4 al al PROPN iajs-152 324 5 - - PUNCT iajs-152 324 6 haitham haitham PROPN iajs-152 324 7 jour jour X iajs-152 324 8 . . PROPN iajs-152 325 1 for for ADP iajs-152 325 2 pure pure ADJ iajs-152 325 3 & & CCONJ iajs-152 325 4 appl appl PROPN iajs-152 325 5 . . PUNCT iajs-152 326 1 sci sci PROPN iajs-152 326 2 . . PUNCT iajs-152 326 3 vol vol NOUN iajs-152 326 4 . . PROPN iajs-152 327 1 28 28 NUM iajs-152 327 2 ( ( PUNCT iajs-152 327 3 3 3 NUM iajs-152 327 4 ) ) PUNCT iajs-152 327 5 2015 2015 NUM iajs-152 327 6 fig fig NOUN iajs-152 327 7 ( ( PUNCT iajs-152 327 8 8) 8) NUM iajs-152 327 9 : : PUNCT iajs-152 327 10 uv uv NOUN iajs-152 327 11 spectrum spectrum NOUN iajs-152 327 12 of of ADP iajs-152 327 13 the the DET iajs-152 327 14 1,10 1,10 NUM iajs-152 327 15 - - PUNCT iajs-152 327 16 phenanthrolin phenanthrolin NOUN iajs-152 327 17 fig fig NOUN iajs-152 327 18 ( ( PUNCT iajs-152 327 19 9 9 NUM iajs-152 327 20 ): ): PUNCT iajs-152 327 21 uv uv NOUN iajs-152 327 22 spectrum spectrum NOUN iajs-152 327 23 of of ADP iajs-152 327 24 the the DET iajs-152 327 25 complex complex ADJ iajs-152 327 26 [ [ X iajs-152 327 27 co(l)(phen)(h2o)cl co(l)(phen)(h2o)cl NOUN iajs-152 327 28 ] ] PUNCT iajs-152 327 29 fig fig NOUN iajs-152 327 30 ( ( PUNCT iajs-152 327 31 10):uv 10):uv NUM iajs-152 327 32 spectrum spectrum NOUN iajs-152 327 33 of of ADP iajs-152 327 34 the the DET iajs-152 327 35 complex complex NOUN iajs-152 327 36 [ [ X iajs-152 327 37 zn(l)(phen)(h2o)cl zn(l)(phen)(h2o)cl X iajs-152 327 38 ] ] X iajs-152 327 39 fig fig NOUN iajs-152 327 40 ( ( PUNCT iajs-152 327 41 11 11 NUM iajs-152 327 42 ): ): PUNCT iajs-152 327 43 uv uv NOUN iajs-152 327 44 spectrum spectrum NOUN iajs-152 327 45 of of ADP iajs-152 327 46 the the DET iajs-152 327 47 complex complex ADJ iajs-152 327 48 [ [ X iajs-152 327 49 cd(l)(phen)(h2o)cl cd(l)(phen)(h2o)cl NOUN iajs-152 327 50 ] ] X iajs-152 327 51 fig fig NOUN iajs-152 327 52 ( ( PUNCT iajs-152 327 53 12 12 NUM iajs-152 327 54 ): ): PUNCT iajs-152 327 55 uv uv NOUN iajs-152 327 56 spectrum spectrum NOUN iajs-152 327 57 of of ADP iajs-152 327 58 the the DET iajs-152 327 59 complex complex NOUN iajs-152 327 60 [ [ X iajs-152 327 61 hg(l)(phen)(h2o)cl hg(l)(phen)(h2o)cl NOUN iajs-152 327 62 ] ] X iajs-152 327 63 200 200 NUM iajs-152 327 64 | | ADV iajs-152 327 65 chemistry chemistry NOUN iajs-152 327 66 2015 2015 NUM iajs-152 327 67 ) ) PUNCT iajs-152 327 68 عام عام ADP iajs-152 327 69 3العدد 3العدد NUM iajs-152 327 70 ( ( PUNCT iajs-152 327 71 28مجلة 28مجلة X iajs-152 327 72 إبن إبن VERB iajs-152 327 73 الھيثم الھيثم NOUN iajs-152 327 74 للعلوم للعلوم NOUN iajs-152 327 75 الصرفة الصرفة NOUN iajs-152 327 76 و و PRON iajs-152 328 1 التطبيقية التطبيقية ADV iajs-152 328 2 المجلد المجلد VERB iajs-152 328 3 ibn ibn PROPN iajs-152 328 4 al al PROPN iajs-152 328 5 - - PUNCT iajs-152 328 6 haitham haitham PROPN iajs-152 328 7 jour jour X iajs-152 328 8 . . 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PROPN iajs-152 341 1 for for ADP iajs-152 341 2 pure pure ADJ iajs-152 341 3 & & CCONJ iajs-152 341 4 appl appl PROPN iajs-152 341 5 . . PUNCT iajs-152 342 1 sci sci PROPN iajs-152 342 2 . . PUNCT iajs-152 342 3 vol vol NOUN iajs-152 342 4 . . PROPN iajs-152 343 1 28 28 NUM iajs-152 343 2 ( ( PUNCT iajs-152 343 3 3 3 NUM iajs-152 343 4 ) ) PUNCT iajs-152 343 5 2015 2015 NUM iajs-152 343 6 -1,10معقدات -1,10معقدات X iajs-152 343 7 حاوية حاوية NOUN iajs-152 343 8 على على NOUN iajs-152 343 9 ليكندات ليكندات NOUN iajs-152 343 10 مختلطة مختلطة NOUN iajs-152 343 11 من من NOUN iajs-152 343 12 صبغة صبغة ADJ iajs-152 343 13 االزو االزو PROPN iajs-152 343 14 و و PRON iajs-152 343 15 تحضير تحضير ADJ iajs-152 343 16 وتشخيص وتشخيص PROPN iajs-152 343 17 الثنائية الثنائية PROPN iajs-152 343 18 التكافؤ التكافؤ PROPN iajs-152 343 19 الكوبلت الكوبلت PROPN iajs-152 343 20 ، ، PROPN iajs-152 343 21 الكادميوم الكادميوم PROPN iajs-152 343 22 ، ، PROPN iajs-152 343 23 الخارصين الخارصين PROPN iajs-152 343 24 ، ، PROPN iajs-152 343 25 الزئبقفينانثرولين الزئبقفينانثرولين PROPN iajs-152 343 26 مع مع PROPN iajs-152 343 27 ايونات ايونات PROPN iajs-152 343 28 حسن حسن PROPN iajs-152 343 29 احمد احمد PROPN iajs-152 343 30 حسن حسن NOUN iajs-152 343 31 وسن وسن ADP iajs-152 343 32 محمد محمد PROPN iajs-152 343 33 علوان علوان ADJ iajs-152 343 34 رياض رياض NOUN iajs-152 343 35 محمود محمود PROPN iajs-152 343 36 احمد احمد PROPN iajs-152 343 37 انعام انعام PROPN iajs-152 343 38 اسماعيل اسماعيل PROPN iajs-152 343 39 يوسف يوسف PROPN iajs-152 343 40 جامعة جامعة PROPN iajs-152 343 41 بغداد بغداد PROPN iajs-152 343 42 / / SYM iajs-152 343 43 الھيثم الھيثم PROPN iajs-152 343 44 ) ) PUNCT iajs-152 343 45 قسم قسم PROPN iajs-152 343 46 الكيمياء الكيمياء PROPN iajs-152 343 47 /كلية /كلية PROPN iajs-152 343 48 التربية التربية PROPN iajs-152 343 49 للعلوم للعلوم NOUN iajs-152 343 50 الصرفة الصرفة NOUN iajs-152 343 51 ( ( PUNCT iajs-152 343 52 ابن ابن X iajs-152 343 53 2015//تشرين 2015//تشرين NUM iajs-152 343 54 االول19البحث االول19البحث NOUN iajs-152 343 55 في في NOUN iajs-152 343 56 : : PUNCT iajs-152 343 57 ، ، PROPN iajs-152 343 58 قبل2015 قبل2015 PROPN iajs-152 343 59 / / SYM iajs-152 343 60 حزيران/10استلم حزيران/10استلم PROPN iajs-152 343 61 البحث البحث VERB iajs-152 343 62 في في NOUN iajs-152 343 63 : : PUNCT iajs-152 343 64 الخالصة الخالصة NOUN iajs-152 343 65 4 4 NUM iajs-152 343 66 - - PUNCT iajs-152 343 67 نفثول-2امينوتفاعل نفثول-2امينوتفاعل NOUN iajs-152 343 68 اتضمن اتضمن NOUN iajs-152 343 69 العمل العمل X iajs-152 343 70 تحضيرمعقدات تحضيرمعقدات PROPN iajs-152 343 71 حاوية حاوية NOUN iajs-152 343 72 على على NOUN iajs-152 343 73 ليكاندات ليكاندات NOUN iajs-152 343 74 مختلطة مختلطة NOUN iajs-152 343 75 من من ADP iajs-152 343 76 صبغة صبغة ADJ iajs-152 343 77 االزو االزو PROPN iajs-152 343 78 المحضرة المحضرة PROPN iajs-152 344 1 من من DET iajs-152 344 2 كليكاند كليكاند PROPN iajs-152 344 3 ثانوي ثانوي NOUN iajs-152 344 4 مع مع PROPN iajs-152 344 5 امالح امالح NOUN iajs-152 344 6 فينانثرولين-10,1السن فينانثرولين-10,1السن PUNCT iajs-152 344 7 و و PRON iajs-152 344 8 نفثايل نفثايل VERB iajs-152 344 9 امين امين PROPN iajs-152 344 10 كليكاند كليكاند PROPN iajs-152 344 11 اولي اولي PROPN iajs-152 344 12 ثنائي ثنائي PROPN iajs-152 345 1 -1سلفونيك -1سلفونيك PUNCT iajs-152 345 2 اسيد اسيد PROPN iajs-152 345 3 مع مع PROPN iajs-152 345 4 ملح ملح PROPN iajs-152 345 5 الدايزونيوم الدايزونيوم PROPN iajs-152 345 6 وباستعمال وباستعمال ADJ iajs-152 345 7 ھايدروكسيد ھايدروكسيد PROPN iajs-152 345 8 الصوديوم الصوديوم PROPN iajs-152 345 9 كوسط كوسط PROPN iajs-152 345 10 قاعدي قاعدي NOUN iajs-152 345 11 . . PUNCT iajs-152 346 1 1:1:1 1:1:1 NUM iajs-152 346 2 ) ) PUNCT iajs-152 346 3 للحصول للحصول NOUN iajs-152 346 4 على على PROPN iajs-152 346 5 المعقدات المعقدات PROPN iajs-152 346 6 بنسبة بنسبة PROPN iajs-152 346 7 1:1:1الفلزات 1:1:1الفلزات NUM iajs-152 346 8 وبنسبة وبنسبة NOUN iajs-152 346 9 ( ( PUNCT iajs-152 346 10 الفيزيائية الفيزيائية NOUN iajs-152 346 11 في في ADP iajs-152 346 12 تشخيص تشخيص PROPN iajs-152 346 13 المركبات المركبات PROPN iajs-152 346 14 المحضرة المحضرة PROPN iajs-152 346 15 بوساطة بوساطة PROPN iajs-152 346 16 اطياف اطياف ADJ iajs-152 346 17 االشعة االشعة PROPN iajs-152 346 18 تحت تحت PROPN iajs-152 346 19 الحمراء الحمراء PROPN iajs-152 346 20 وفوق وفوق VERB iajs-152 346 21 – – PUNCT iajs-152 346 22 واستعملت واستعملت PROPN iajs-152 346 23 التقنيات التقنيات PROPN iajs-152 346 24 الكيميائية الكيميائية PROPN iajs-152 346 25 والفلورة والفلورة PROPN iajs-152 346 26 وطيف وطيف PROPN iajs-152 346 27 الرنين الرنين PROPN iajs-152 346 28 النووي النووي PROPN iajs-152 346 29 المغناطيسي المغناطيسي PROPN iajs-152 346 30 واالمتصاص واالمتصاص PROPN iajs-152 346 31 الذري الذري PROPN iajs-152 346 32 ومحتوى ومحتوى PROPN iajs-152 346 33 الكلور الكلور PROPN iajs-152 346 34 وقياسات وقياسات PROPN iajs-152 346 35 التوصيلية التوصيلية PROPN iajs-152 346 36 المرئية المرئية PROPN iajs-152 346 37 - - PUNCT iajs-152 346 38 يةالبنفسج يةالبنفسج NOUN iajs-152 346 39 الكھربائية الكھربائية NOUN iajs-152 346 40 مع مع NOUN iajs-152 346 41 درجات درجات PROPN iajs-152 346 42 االنصھار.كما االنصھار.كما X iajs-152 346 43 استعملت استعملت PROPN iajs-152 346 44 تقنية تقنية PROPN iajs-152 346 45 التحليل التحليل PROPN iajs-152 346 46 الحراري الحراري PROPN iajs-152 346 47 في في ADP iajs-152 346 48 اثبات اثبات PROPN iajs-152 346 49 وجود وجود VERB iajs-152 346 50 جزيئات جزيئات PROPN iajs-152 346 51 الماء الماء NOUN iajs-152 346 52 المتناسقة المتناسقة VERB iajs-152 346 53 في في DET iajs-152 346 54 تركيب تركيب PROPN iajs-152 346 55 الخارصين الخارصين PROPN iajs-152 346 56 الثنائيالثنائي الثنائيالثنائي PROPN iajs-152 347 1 و و PRON iajs-152 347 2 معقدات معقدات VERB iajs-152 347 3 الكوبلت الكوبلت NOUN iajs-152 347 4 الثنائي الثنائي PRON iajs-152 347 5 والكادميومالمعقدات والكادميومالمعقدات PROPN iajs-152 348 1 وبناًء وبناًء PROPN iajs-152 348 2 على على NOUN iajs-152 348 3 ما ما ADP iajs-152 348 4 سبق سبق ADJ iajs-152 348 5 اقترحت اقترحت ADJ iajs-152 348 6 الصيغة الصيغة NOUN iajs-152 348 7 االتية االتية VERB iajs-152 348 8 ل ل ADJ iajs-152 348 9 o)cl]2[m(l)(phen)(hالثنائي o)cl]2[m(l)(phen)(hالثنائي NOUN iajs-152 348 10 . . PUNCT iajs-152 349 1 والزئبق والزئبق NOUN iajs-152 349 2 فينانثرولين فينانثرولين NOUN iajs-152 349 3 -10 -10 X iajs-152 349 4 ، ، NOUN iajs-152 350 1 1االزو 1االزو NUM iajs-152 350 2 ، ، PROPN iajs-152 350 3 ليكاند ليكاند PROPN iajs-152 350 4 ، ، PROPN iajs-152 350 5 معقد معقد PROPN iajs-152 350 6 ، ، NOUN iajs-152 350 7 – – PUNCT iajs-152 350 8 صبغة صبغة ADJ iajs-152 350 9 : : PUNCT iajs-152 350 10 المفتاحيةالكلمات المفتاحيةالكلمات ADJ