id sid tid token lemma pos iajs-1794 1 1 microsoft microsoft PROPN iajs-1794 1 2 word word NOUN iajs-1794 1 3 206 206 NUM iajs-1794 1 4 - - SYM iajs-1794 1 5 220 220 NUM iajs-1794 1 6 ihsciconf ihsciconf NOUN iajs-1794 1 7 2017 2017 NUM iajs-1794 1 8 special special ADJ iajs-1794 1 9 issue issue NOUN iajs-1794 1 10 ibn ibn PROPN iajs-1794 1 11 al al PROPN iajs-1794 1 12 - - PUNCT iajs-1794 1 13 haitham haitham PROPN iajs-1794 1 14 journal journal PROPN iajs-1794 1 15 for for ADP iajs-1794 1 16 pure pure ADJ iajs-1794 1 17 and and CCONJ iajs-1794 1 18 applied apply VERB iajs-1794 1 19 science science NOUN iajs-1794 1 20 https:// https:// PROPN iajs-1794 1 21 doi.org/ doi.org/ ADP iajs-1794 1 22 10.30526/2017.ihsciconf.1794 10.30526/2017.ihsciconf.1794 NOUN iajs-1794 1 23 for for ADP iajs-1794 1 24 more more ADJ iajs-1794 1 25 information information NOUN iajs-1794 1 26 about about ADP iajs-1794 1 27 the the DET iajs-1794 1 28 conference conference NOUN iajs-1794 1 29 please please INTJ iajs-1794 1 30 visit visit VERB iajs-1794 1 31 the the DET iajs-1794 1 32 websites website NOUN iajs-1794 1 33 : : PUNCT iajs-1794 1 34 http://www.ihsciconf.org/conf/ http://www.ihsciconf.org/conf/ VERB iajs-1794 1 35     SPACE iajs-1794 1 36 www.ihsciconf.org www.ihsciconf.org ADJ iajs-1794 1 37       SPACE iajs-1794 1 38 chemistry|206 chemistry|206 NOUN iajs-1794 1 39         SPACE iajs-1794 1 40 synthesis synthesis NOUN iajs-1794 1 41 , , PUNCT iajs-1794 1 42 characterization characterization NOUN iajs-1794 1 43 and and CCONJ iajs-1794 1 44 thermal thermal ADJ iajs-1794 1 45 study study NOUN iajs-1794 1 46 of of ADP iajs-1794 1 47 some some DET iajs-1794 1 48 transition transition NOUN iajs-1794 1 49 metal metal NOUN iajs-1794 1 50 complexes complex NOUN iajs-1794 1 51 derived derive VERB iajs-1794 1 52 from from ADP iajs-1794 1 53 quinoxaline2,3 quinoxaline2,3 PROPN iajs-1794 1 54 - - PUNCT iajs-1794 1 55 dione dione NOUN iajs-1794 1 56 taghreed taghreed NOUN iajs-1794 1 57 m. m. NOUN iajs-1794 1 58 musa musa PROPN iajs-1794 1 59 taghreedmohya@uomustansiriyah.edu.iq taghreedmohya@uomustansiriyah.edu.iq NOUN iajs-1794 2 1 taghreedmohya@yahoo.com taghreedmohya@yahoo.com PROPN iajs-1794 2 2 mahmoud mahmoud PROPN iajs-1794 2 3 najim najim PROPN iajs-1794 2 4 a. a. PROPN iajs-1794 2 5 al al PROPN iajs-1794 2 6 - - PUNCT iajs-1794 2 7 jibouri jibouri PROPN iajs-1794 2 8 mahmoud_inor71@uomustansiriyah.edu.iq mahmoud_inor71@uomustansiriyah.edu.iq PROPN iajs-1794 2 9 bayader bayader NOUN iajs-1794 2 10 fadhil fadhil PROPN iajs-1794 2 11 abbas abbas PROPN iajs-1794 2 12 bayaderfadhil@gmail.com bayaderfadhil@gmail.com PROPN iajs-1794 2 13     SPACE iajs-1794 2 14 dept dept NOUN iajs-1794 2 15 . . PUNCT iajs-1794 3 1 of of ADP iajs-1794 3 2 chemistry/ chemistry/ NUM iajs-1794 3 3 college college NOUN iajs-1794 3 4 of of ADP iajs-1794 3 5 science/ science/ NUM iajs-1794 3 6 university university PROPN iajs-1794 3 7 of of ADP iajs-1794 3 8 mustansiriyah mustansiriyah NOUN iajs-1794 3 9 abstract abstract ADP iajs-1794 3 10 the the DET iajs-1794 3 11 present present ADJ iajs-1794 3 12 paper paper NOUN iajs-1794 3 13 describes describe VERB iajs-1794 3 14 the the DET iajs-1794 3 15 synthesis synthesis NOUN iajs-1794 3 16 and and CCONJ iajs-1794 3 17 structural structural ADJ iajs-1794 3 18 studies study NOUN iajs-1794 3 19 of of ADP iajs-1794 3 20 new new ADJ iajs-1794 3 21 transition transition NOUN iajs-1794 3 22 metal metal NOUN iajs-1794 3 23 complexes complex NOUN iajs-1794 3 24 of of ADP iajs-1794 3 25 cobalt(ii cobalt(ii PROPN iajs-1794 3 26 ) ) PUNCT iajs-1794 3 27 , , PUNCT iajs-1794 3 28 nickel(ii nickel(ii PROPN iajs-1794 3 29 ) ) PUNCT iajs-1794 3 30 , , PUNCT iajs-1794 3 31 copper(ii copper(ii PROPN iajs-1794 3 32 ) ) PUNCT iajs-1794 3 33 and and CCONJ iajs-1794 3 34 cadmium(ii cadmium(ii NOUN iajs-1794 3 35 ) ) PUNCT iajs-1794 3 36 with with ADP iajs-1794 3 37 two two NUM iajs-1794 3 38 bi bi ADJ iajs-1794 3 39 dentate dentate NOUN iajs-1794 3 40 ligands ligand NOUN iajs-1794 3 41 derived derive VERB iajs-1794 3 42 from from ADP iajs-1794 3 43 quinoxaline-2,3 quinoxaline-2,3 NOUN iajs-1794 3 44 - - PUNCT iajs-1794 3 45 dione dione NOUN iajs-1794 3 46 . . PUNCT iajs-1794 4 1 the the DET iajs-1794 4 2 two two NUM iajs-1794 4 3 ligands ligand NOUN iajs-1794 4 4 were be AUX iajs-1794 4 5 fully fully ADV iajs-1794 4 6 identified identify VERB iajs-1794 4 7 by by ADP iajs-1794 4 8 elemental elemental ADJ iajs-1794 4 9 analyses analysis NOUN iajs-1794 4 10 , , PUNCT iajs-1794 4 11 ft ft PROPN iajs-1794 4 12 - - PUNCT iajs-1794 4 13 ir ir NOUN iajs-1794 4 14 , , PUNCT iajs-1794 4 15 nmr nmr NOUN iajs-1794 4 16 and and CCONJ iajs-1794 4 17 uv uv NOUN iajs-1794 4 18 - - PUNCT iajs-1794 4 19 visible visible ADJ iajs-1794 4 20 spectra spectra NOUN iajs-1794 4 21 . . PUNCT iajs-1794 5 1 the the DET iajs-1794 5 2 metal metal NOUN iajs-1794 5 3 complexes complex NOUN iajs-1794 5 4 of of ADP iajs-1794 5 5 co(ii co(ii PROPN iajs-1794 5 6 ) ) PUNCT iajs-1794 5 7 , , PUNCT iajs-1794 5 8 ni(ii ni(ii PROPN iajs-1794 5 9 ) ) PUNCT iajs-1794 5 10 , , PUNCT iajs-1794 5 11 cu(ii cu(ii PROPN iajs-1794 5 12 ) ) PUNCT iajs-1794 5 13 and and CCONJ iajs-1794 5 14 cd(ii cd(ii PROPN iajs-1794 5 15 ) ) PUNCT iajs-1794 5 16 were be AUX iajs-1794 5 17 isolated isolate VERB iajs-1794 5 18 in in ADP iajs-1794 5 19 the the DET iajs-1794 5 20 solid solid ADJ iajs-1794 5 21 state state NOUN iajs-1794 5 22 after after ADP iajs-1794 5 23 reactions reaction NOUN iajs-1794 5 24 of of ADP iajs-1794 5 25 their their PRON iajs-1794 5 26 metal metal NOUN iajs-1794 5 27 chlorides chloride NOUN iajs-1794 5 28 with with ADP iajs-1794 5 29 the the DET iajs-1794 5 30 ligands ligand NOUN iajs-1794 5 31 in in ADP iajs-1794 5 32 2:1 2:1 NUM iajs-1794 5 33 mole mole NOUN iajs-1794 5 34 ratio ratio NOUN iajs-1794 5 35 . . PUNCT iajs-1794 6 1 the the DET iajs-1794 6 2 isolated isolated ADJ iajs-1794 6 3 solid solid ADJ iajs-1794 6 4 metal metal NOUN iajs-1794 6 5 complexes complex NOUN iajs-1794 6 6 were be AUX iajs-1794 6 7 characterized characterize VERB iajs-1794 6 8 with with ADP iajs-1794 6 9 the the DET iajs-1794 6 10 help help NOUN iajs-1794 6 11 of of ADP iajs-1794 6 12 elemental elemental ADJ iajs-1794 6 13 analyses analysis NOUN iajs-1794 6 14 , , PUNCT iajs-1794 6 15 nmr nmr NOUN iajs-1794 6 16 , , PUNCT iajs-1794 6 17 ft ft PROPN iajs-1794 6 18 - - PUNCT iajs-1794 6 19 ir ir NOUN iajs-1794 6 20 and and CCONJ iajs-1794 6 21 uv uv NOUN iajs-1794 6 22 - - PUNCT iajs-1794 6 23 visible visible ADJ iajs-1794 6 24 spectra spectra NOUN iajs-1794 6 25 . . PUNCT iajs-1794 7 1 as as ADV iajs-1794 7 2 well well ADV iajs-1794 7 3 as as ADP iajs-1794 7 4 the the DET iajs-1794 7 5 thermal thermal ADJ iajs-1794 7 6 stability stability NOUN iajs-1794 7 7 of of ADP iajs-1794 7 8 the the DET iajs-1794 7 9 coordinated coordinate VERB iajs-1794 7 10 quinoxaline quinoxaline ADJ iajs-1794 7 11 polymers polymer NOUN iajs-1794 7 12 were be AUX iajs-1794 7 13 tested test VERB iajs-1794 7 14 by by ADP iajs-1794 7 15 tg tg PROPN iajs-1794 7 16 - - PUNCT iajs-1794 7 17 dsc dsc NOUN iajs-1794 7 18 analysis analysis NOUN iajs-1794 7 19 and and CCONJ iajs-1794 7 20 it it PRON iajs-1794 7 21 is be AUX iajs-1794 7 22 found find VERB iajs-1794 7 23 that that SCONJ iajs-1794 7 24 cleavage cleavage NOUN iajs-1794 7 25 of of ADP iajs-1794 7 26 terminal terminal ADJ iajs-1794 7 27 moiety moiety NOUN iajs-1794 7 28 was be AUX iajs-1794 7 29 investigated investigate VERB iajs-1794 7 30 , , PUNCT iajs-1794 7 31 the the DET iajs-1794 7 32 strong strong ADJ iajs-1794 7 33 coordinated coordinated ADJ iajs-1794 7 34 bonds bond NOUN iajs-1794 7 35 between between ADP iajs-1794 7 36 oxygen oxygen NOUN iajs-1794 7 37 donor donor NOUN iajs-1794 7 38 atoms atom NOUN iajs-1794 7 39 in in ADP iajs-1794 7 40 l1 l1 PROPN iajs-1794 7 41 while while SCONJ iajs-1794 7 42 nitrogen nitrogen NOUN iajs-1794 7 43 donor donor NOUN iajs-1794 7 44 atoms atom NOUN iajs-1794 7 45 of of ADP iajs-1794 7 46 quinoxaline quinoxaline ADJ iajs-1794 7 47 ring ring NOUN iajs-1794 7 48 in in ADP iajs-1794 7 49 the the DET iajs-1794 7 50 l2 l2 NOUN iajs-1794 7 51 with with ADP iajs-1794 7 52 the the DET iajs-1794 7 53 metal metal NOUN iajs-1794 7 54 ions ion NOUN iajs-1794 7 55 . . PUNCT iajs-1794 8 1 furthermore furthermore ADV iajs-1794 8 2 , , PUNCT iajs-1794 8 3 the the DET iajs-1794 8 4 thermal thermal ADJ iajs-1794 8 5 stability stability NOUN iajs-1794 8 6 of of ADP iajs-1794 8 7 cobalt(ii cobalt(ii PROPN iajs-1794 8 8 ) ) PUNCT iajs-1794 8 9 , , PUNCT iajs-1794 8 10 nickel(ii nickel(ii PROPN iajs-1794 8 11 ) ) PUNCT iajs-1794 8 12 , , PUNCT iajs-1794 8 13 copper(ii copper(ii NOUN iajs-1794 8 14 ) ) PUNCT iajs-1794 8 15 and and CCONJ iajs-1794 8 16 cd(ii cd(ii ADJ iajs-1794 8 17 ) ) PUNCT iajs-1794 8 18 complexes complex NOUN iajs-1794 8 19 were be AUX iajs-1794 8 20 screened screen VERB iajs-1794 8 21 by by ADP iajs-1794 8 22 tg tg PROPN iajs-1794 8 23 - - PUNCT iajs-1794 8 24 dsc dsc NOUN iajs-1794 8 25 analysis analysis NOUN iajs-1794 8 26 and and CCONJ iajs-1794 8 27 the the DET iajs-1794 8 28 results result NOUN iajs-1794 8 29 helped help VERB iajs-1794 8 30 us we PRON iajs-1794 8 31 in in ADP iajs-1794 8 32 the the DET iajs-1794 8 33 investigation investigation NOUN iajs-1794 8 34 of of ADP iajs-1794 8 35 the the DET iajs-1794 8 36 proposed propose VERB iajs-1794 8 37 structure structure NOUN iajs-1794 8 38 of of ADP iajs-1794 8 39 the the DET iajs-1794 8 40 prepared prepared ADJ iajs-1794 8 41 complexes complex NOUN iajs-1794 8 42 in in ADP iajs-1794 8 43 the the DET iajs-1794 8 44 formula formula NOUN iajs-1794 9 1 [ [ X iajs-1794 9 2 m(l)2cl2].xh2o m(l)2cl2].xh2o NOUN iajs-1794 9 3 and and CCONJ iajs-1794 9 4 [ [ X iajs-1794 9 5 cd(l)2]cl2 cd(l)2]cl2 ADP iajs-1794 9 6 where where SCONJ iajs-1794 9 7 l= l= PROPN iajs-1794 9 8 l1 l1 PROPN iajs-1794 9 9 and and CCONJ iajs-1794 9 10 l2 l2 NOUN iajs-1794 9 11 ligands ligand NOUN iajs-1794 9 12 derived derive VERB iajs-1794 9 13 from from ADP iajs-1794 9 14 quinoxaline2,3 quinoxaline2,3 PROPN iajs-1794 9 15 - - NOUN iajs-1794 9 16 dione dione NOUN iajs-1794 9 17 . . PUNCT iajs-1794 10 1 keywords keyword NOUN iajs-1794 10 2 : : PUNCT iajs-1794 10 3 coordination coordination NOUN iajs-1794 10 4 polymers polymer NOUN iajs-1794 10 5 , , PUNCT iajs-1794 10 6 transition transition NOUN iajs-1794 10 7 metal metal NOUN iajs-1794 10 8 copolymers copolymer NOUN iajs-1794 10 9 , , PUNCT iajs-1794 10 10 inorganic inorganic ADJ iajs-1794 10 11 polymers polymer NOUN iajs-1794 10 12 of of ADP iajs-1794 10 13 quinoxaline quinoxaline NOUN iajs-1794 10 14 . . PUNCT iajs-1794 11 1 ihsciconf ihsciconf PROPN iajs-1794 11 2 2017 2017 NUM iajs-1794 11 3 special special ADJ iajs-1794 11 4 issue issue NOUN iajs-1794 11 5 ibn ibn PROPN iajs-1794 11 6 al al PROPN iajs-1794 11 7 - - PUNCT iajs-1794 11 8 haitham haitham PROPN iajs-1794 11 9 journal journal PROPN iajs-1794 11 10 for for ADP iajs-1794 11 11 pure pure ADJ iajs-1794 11 12 and and CCONJ iajs-1794 11 13 applied apply VERB iajs-1794 11 14 science science NOUN iajs-1794 11 15 https:// https:// PROPN iajs-1794 11 16 doi.org/ doi.org/ ADP iajs-1794 11 17 10.30526/2017.ihsciconf.1794 10.30526/2017.ihsciconf.1794 NOUN iajs-1794 11 18 for for ADP iajs-1794 11 19 more more ADJ iajs-1794 11 20 information information NOUN iajs-1794 11 21 about about ADP iajs-1794 11 22 the the DET iajs-1794 11 23 conference conference NOUN iajs-1794 11 24 please please INTJ iajs-1794 11 25 visit visit VERB iajs-1794 11 26 the the DET iajs-1794 11 27 websites website NOUN iajs-1794 11 28 : : PUNCT iajs-1794 11 29 http://www.ihsciconf.org/conf/ http://www.ihsciconf.org/conf/ VERB iajs-1794 11 30     SPACE iajs-1794 11 31 www.ihsciconf.org www.ihsciconf.org ADJ iajs-1794 11 32       SPACE iajs-1794 11 33 chemistry|207 chemistry|207 NOUN iajs-1794 11 34         SPACE iajs-1794 11 35 1 1 NUM iajs-1794 11 36 . . PUNCT iajs-1794 12 1 introduction introduction NOUN iajs-1794 12 2 most most ADJ iajs-1794 12 3 of of ADP iajs-1794 12 4 coordination coordination NOUN iajs-1794 12 5 polymers polymer NOUN iajs-1794 12 6 formed form VERB iajs-1794 12 7 with with ADP iajs-1794 12 8 heterocyclic heterocyclic ADJ iajs-1794 12 9 derivatives derivative NOUN iajs-1794 12 10 [ [ X iajs-1794 12 11 1 1 NUM iajs-1794 12 12 - - SYM iajs-1794 12 13 3 3 NUM iajs-1794 12 14 ] ] PUNCT iajs-1794 12 15 belongs belong VERB iajs-1794 12 16 to to ADP iajs-1794 12 17 organic organic ADJ iajs-1794 12 18 - - PUNCT iajs-1794 12 19 inorganic inorganic ADJ iajs-1794 12 20 hybrid hybrid ADJ iajs-1794 12 21 materials material NOUN iajs-1794 12 22 . . PUNCT iajs-1794 13 1 the the DET iajs-1794 13 2 variety variety NOUN iajs-1794 13 3 of of ADP iajs-1794 13 4 their their PRON iajs-1794 13 5 structures structure NOUN iajs-1794 13 6 leads lead VERB iajs-1794 13 7 to to ADP iajs-1794 13 8 one one NUM iajs-1794 13 9 of of ADP iajs-1794 13 10 functional functional ADJ iajs-1794 13 11 performances performance NOUN iajs-1794 13 12 and and CCONJ iajs-1794 13 13 thus thus ADV iajs-1794 13 14 the the DET iajs-1794 13 15 studies study NOUN iajs-1794 13 16 on on ADP iajs-1794 13 17 them they PRON iajs-1794 13 18 have have AUX iajs-1794 13 19 aroused arouse VERB iajs-1794 13 20 interest interest NOUN iajs-1794 13 21 . . PUNCT iajs-1794 14 1 the the DET iajs-1794 14 2 involvement involvement NOUN iajs-1794 14 3 of of ADP iajs-1794 14 4 bridge bridge NOUN iajs-1794 14 5 ligands ligand NOUN iajs-1794 14 6 in in ADP iajs-1794 14 7 the the DET iajs-1794 14 8 skeletal skeletal NOUN iajs-1794 14 9 of of ADP iajs-1794 14 10 metal metal NOUN iajs-1794 14 11 complexes complex NOUN iajs-1794 14 12 of of ADP iajs-1794 14 13 pyrazine pyrazine ADJ iajs-1794 14 14 moiety moiety NOUN iajs-1794 14 15 may may AUX iajs-1794 14 16 have have AUX iajs-1794 14 17 affected affect VERB iajs-1794 14 18 on on ADP iajs-1794 14 19 the the DET iajs-1794 14 20 physical physical ADJ iajs-1794 14 21 properties property NOUN iajs-1794 14 22 of of ADP iajs-1794 14 23 coordination coordination NOUN iajs-1794 14 24 polymers polymer NOUN iajs-1794 14 25 [ [ X iajs-1794 14 26 4 4 NUM iajs-1794 14 27 ] ] PUNCT iajs-1794 14 28 . . PUNCT iajs-1794 15 1 however however ADV iajs-1794 15 2 , , PUNCT iajs-1794 15 3 the the DET iajs-1794 15 4 polymers polymer NOUN iajs-1794 15 5 involving involve VERB iajs-1794 15 6 quinoxaline quinoxaline PROPN iajs-1794 15 7 moiety moiety PROPN iajs-1794 15 8 have have AUX iajs-1794 15 9 been be AUX iajs-1794 15 10 interested interested ADJ iajs-1794 15 11 in in ADP iajs-1794 15 12 the the DET iajs-1794 15 13 field field NOUN iajs-1794 15 14 of of ADP iajs-1794 15 15 diodes diode NOUN iajs-1794 15 16 and and CCONJ iajs-1794 15 17 semiconductors semiconductor NOUN iajs-1794 15 18 [ [ X iajs-1794 15 19 5 5 NUM iajs-1794 15 20 ] ] PUNCT iajs-1794 15 21 . . PUNCT iajs-1794 16 1 the the DET iajs-1794 16 2 significant significant ADJ iajs-1794 16 3 research research NOUN iajs-1794 16 4 efforts effort NOUN iajs-1794 16 5 have have AUX iajs-1794 16 6 been be AUX iajs-1794 16 7 devoted devote VERB iajs-1794 16 8 to to ADP iajs-1794 16 9 the the DET iajs-1794 16 10 synthesis synthesis NOUN iajs-1794 16 11 of of ADP iajs-1794 16 12 these these DET iajs-1794 16 13 new new ADJ iajs-1794 16 14 versions version NOUN iajs-1794 16 15 of of ADP iajs-1794 16 16 conjugated conjugated ADJ iajs-1794 16 17 polymers polymer NOUN iajs-1794 16 18 [ [ X iajs-1794 16 19 6 6 NUM iajs-1794 16 20 - - SYM iajs-1794 16 21 8 8 NUM iajs-1794 16 22 ] ] PUNCT iajs-1794 16 23 . . PUNCT iajs-1794 17 1 as as ADV iajs-1794 17 2 well well ADV iajs-1794 17 3 as as ADP iajs-1794 17 4 the the DET iajs-1794 17 5 development development NOUN iajs-1794 17 6 of of ADP iajs-1794 17 7 chelation chelation NOUN iajs-1794 17 8 of of ADP iajs-1794 17 9 transition transition NOUN iajs-1794 17 10 elements element NOUN iajs-1794 17 11 of of ADP iajs-1794 17 12 the the DET iajs-1794 17 13 first first ADJ iajs-1794 17 14 row row NOUN iajs-1794 17 15 with with ADP iajs-1794 17 16 poly poly ADJ iajs-1794 17 17 dentate dentate ADJ iajs-1794 17 18 ligands ligand NOUN iajs-1794 17 19 of of ADP iajs-1794 17 20 quinoxaline quinoxaline NOUN iajs-1794 17 21 have have AUX iajs-1794 17 22 introduced introduce VERB iajs-1794 17 23 novel novel ADJ iajs-1794 17 24 applications application NOUN iajs-1794 17 25 in in ADP iajs-1794 17 26 the the DET iajs-1794 17 27 bioinorganic bioinorganic ADJ iajs-1794 17 28 chemistry chemistry NOUN iajs-1794 17 29 [ [ X iajs-1794 17 30 10 10 NUM iajs-1794 17 31 ] ] PUNCT iajs-1794 17 32 . . PUNCT iajs-1794 18 1 recently recently ADV iajs-1794 18 2 , , PUNCT iajs-1794 18 3 the the DET iajs-1794 18 4 introduction introduction NOUN iajs-1794 18 5 of of ADP iajs-1794 18 6 secondary secondary ADJ iajs-1794 18 7 nitrogencontaining nitrogencontaining NOUN iajs-1794 18 8 ligands ligand NOUN iajs-1794 18 9 into into ADP iajs-1794 18 10 the the DET iajs-1794 18 11 metal metal NOUN iajs-1794 18 12 - - PUNCT iajs-1794 18 13 carboxylate carboxylate NOUN iajs-1794 18 14 system system NOUN iajs-1794 18 15 has have AUX iajs-1794 18 16 been be AUX iajs-1794 18 17 of of ADP iajs-1794 18 18 interest interest NOUN iajs-1794 18 19 not not PART iajs-1794 18 20 only only ADV iajs-1794 18 21 because because SCONJ iajs-1794 18 22 the the DET iajs-1794 18 23 use use NOUN iajs-1794 18 24 of of ADP iajs-1794 18 25 mixed mixed ADJ iajs-1794 18 26 components component NOUN iajs-1794 18 27 can can AUX iajs-1794 18 28 lead lead VERB iajs-1794 18 29 to to ADP iajs-1794 18 30 novel novel ADJ iajs-1794 18 31 structural structural ADJ iajs-1794 18 32 features feature NOUN iajs-1794 18 33 and and CCONJ iajs-1794 18 34 interesting interesting ADJ iajs-1794 18 35 properties property NOUN iajs-1794 18 36 but but CCONJ iajs-1794 18 37 also also ADV iajs-1794 18 38 to to PART iajs-1794 18 39 make make VERB iajs-1794 18 40 the the DET iajs-1794 18 41 construction construction NOUN iajs-1794 18 42 process process NOUN iajs-1794 18 43 more more ADV iajs-1794 18 44 controllable controllable ADJ iajs-1794 18 45 than than ADP iajs-1794 18 46 with with ADP iajs-1794 18 47 only only ADV iajs-1794 18 48 a a DET iajs-1794 18 49 single single ADJ iajs-1794 18 50 ligand ligand NOUN iajs-1794 19 1 [ [ X iajs-1794 19 2 11,12 11,12 NUM iajs-1794 19 3 ] ] PUNCT iajs-1794 19 4 . . PUNCT iajs-1794 20 1 however however ADV iajs-1794 20 2 , , PUNCT iajs-1794 20 3 syntheses synthesis NOUN iajs-1794 20 4 involving involve VERB iajs-1794 20 5 mixed mixed ADJ iajs-1794 20 6 ligands ligand NOUN iajs-1794 20 7 are be AUX iajs-1794 20 8 more more ADV iajs-1794 20 9 difficult difficult ADJ iajs-1794 20 10 due due ADP iajs-1794 20 11 to to ADP iajs-1794 20 12 the the DET iajs-1794 20 13 different different ADJ iajs-1794 20 14 solubility solubility NOUN iajs-1794 20 15 of of ADP iajs-1794 20 16 mixed mixed ADJ iajs-1794 20 17 organic organic ADJ iajs-1794 20 18 ligands ligand NOUN iajs-1794 20 19 and and CCONJ iajs-1794 20 20 the the DET iajs-1794 20 21 competition competition NOUN iajs-1794 20 22 between between ADP iajs-1794 20 23 different different ADJ iajs-1794 20 24 organic organic ADJ iajs-1794 20 25 ligands ligand NOUN iajs-1794 20 26 for for ADP iajs-1794 20 27 the the DET iajs-1794 20 28 metal metal NOUN iajs-1794 20 29 [ [ X iajs-1794 20 30 13 13 NUM iajs-1794 20 31 ] ] PUNCT iajs-1794 20 32 . . PUNCT iajs-1794 21 1 2 2 X iajs-1794 21 2 . . X iajs-1794 21 3 experimental experimental ADJ iajs-1794 21 4 material material NOUN iajs-1794 21 5 and and CCONJ iajs-1794 21 6 methods method NOUN iajs-1794 21 7 elemental elemental VERB iajs-1794 21 8 microanalysis microanalysis NOUN iajs-1794 21 9 ( ( PUNCT iajs-1794 21 10 c.h.n c.h.n NOUN iajs-1794 21 11 ) ) PUNCT iajs-1794 21 12 was be AUX iajs-1794 21 13 performed perform VERB iajs-1794 21 14 on on ADP iajs-1794 21 15 , , PUNCT iajs-1794 21 16 euro euro NOUN iajs-1794 21 17 vector vector NOUN iajs-1794 21 18 e e PROPN iajs-1794 21 19 a a DET iajs-1794 21 20 3000 3000 NUM iajs-1794 21 21 a a NOUN iajs-1794 21 22 , , PUNCT iajs-1794 21 23 al al PROPN iajs-1794 21 24 al al PROPN iajs-1794 21 25 bayt bayt VERB iajs-1794 21 26 university university PROPN iajs-1794 21 27 ( ( PUNCT iajs-1794 21 28 jordan jordan PROPN iajs-1794 21 29 ) ) PUNCT iajs-1794 21 30 . . PUNCT iajs-1794 22 1 the the DET iajs-1794 22 2 ftir ftir PROPN iajs-1794 22 3 spectra spectra PROPN iajs-1794 22 4 of of ADP iajs-1794 22 5 the the DET iajs-1794 22 6 solid solid ADJ iajs-1794 22 7 compounds compound NOUN iajs-1794 22 8 were be AUX iajs-1794 22 9 done do VERB iajs-1794 22 10 on on ADP iajs-1794 22 11 a a DET iajs-1794 22 12 ( ( PUNCT iajs-1794 22 13 shimadzu shimadzu NOUN iajs-1794 22 14 ) ) PUNCT iajs-1794 22 15 ft ft NOUN iajs-1794 22 16 - - PUNCT iajs-1794 22 17 ir-8400s ir-8400s NOUN iajs-1794 22 18 spectrophotometer spectrophotometer NOUN iajs-1794 22 19 . . PUNCT iajs-1794 23 1 solid solid ADJ iajs-1794 23 2 samples sample NOUN iajs-1794 23 3 were be AUX iajs-1794 23 4 run run VERB iajs-1794 23 5 at at ADP iajs-1794 23 6 al al PROPN iajs-1794 23 7 - - PUNCT iajs-1794 23 8 mustansiriyah mustansiriyah PROPN iajs-1794 23 9 university university NOUN iajs-1794 23 10 . . PUNCT iajs-1794 24 1 the1h the1h NOUN iajs-1794 24 2 -nmr -nmr NUM iajs-1794 24 3 was be AUX iajs-1794 24 4 recorded record VERB iajs-1794 24 5 in in ADP iajs-1794 24 6 dmso dmso NOUN iajs-1794 24 7 using use VERB iajs-1794 24 8 a a DET iajs-1794 24 9 ultra ultra ADJ iajs-1794 24 10 - - ADJ iajs-1794 24 11 shield shield ADJ iajs-1794 24 12 bruker bruker NOUN iajs-1794 24 13 300 300 NUM iajs-1794 24 14 - - PUNCT iajs-1794 24 15 mhz mhz NOUN iajs-1794 24 16 spectrometer spectrometer NOUN iajs-1794 24 17 at at ADP iajs-1794 24 18 al al PROPN iajs-1794 24 19 - - PUNCT iajs-1794 24 20 bayt bayt ADJ iajs-1794 24 21 university university NOUN iajs-1794 24 22 ( ( PUNCT iajs-1794 24 23 jordan jordan PROPN iajs-1794 24 24 ) ) PUNCT iajs-1794 24 25 . . PUNCT iajs-1794 25 1 the the DET iajs-1794 25 2 mass mass PROPN iajs-1794 25 3 spectra spectra NOUN iajs-1794 25 4 were be AUX iajs-1794 25 5 done do VERB iajs-1794 25 6 on on ADP iajs-1794 25 7 gc gc PROPN iajs-1794 25 8 ms ms PROPN iajs-1794 25 9 – – PUNCT iajs-1794 25 10 qp qp ADP iajs-1794 25 11 2010 2010 NUM iajs-1794 25 12 vltra vltra NOUN iajs-1794 25 13 at at ADP iajs-1794 25 14 department department NOUN iajs-1794 25 15 of of ADP iajs-1794 25 16 chemistry chemistry NOUN iajs-1794 25 17 , , PUNCT iajs-1794 25 18 college college NOUN iajs-1794 25 19 of of ADP iajs-1794 25 20 science science PROPN iajs-1794 25 21 al al PROPN iajs-1794 25 22 - - PUNCT iajs-1794 25 23 mustansiriyah mustansiriyah PROPN iajs-1794 25 24 university university NOUN iajs-1794 25 25 . . PUNCT iajs-1794 26 1 the the DET iajs-1794 26 2 electronic electronic ADJ iajs-1794 26 3 spectra spectra NOUN iajs-1794 26 4 of of ADP iajs-1794 26 5 the the DET iajs-1794 26 6 ligands ligand NOUN iajs-1794 26 7 and and CCONJ iajs-1794 26 8 its its PRON iajs-1794 26 9 complexes complex NOUN iajs-1794 26 10 in in ADP iajs-1794 26 11 various various ADJ iajs-1794 26 12 solvents solvent NOUN iajs-1794 26 13 ( ( PUNCT iajs-1794 26 14 0.001 0.001 NUM iajs-1794 26 15 m m NOUN iajs-1794 26 16 ) ) PUNCT iajs-1794 26 17 were be AUX iajs-1794 26 18 recorded record VERB iajs-1794 26 19 on on ADP iajs-1794 26 20 a a DET iajs-1794 26 21 shimadzu shimadzu ADJ iajs-1794 26 22 uv uv NOUN iajs-1794 26 23 - - PUNCT iajs-1794 26 24 vis vis X iajs-1794 26 25 spectrophotometer spectrophotometer NOUN iajs-1794 26 26 at at ADP iajs-1794 26 27 al al PROPN iajs-1794 26 28 - - PUNCT iajs-1794 26 29 mustansiriya mustansiriya PROPN iajs-1794 26 30 university university NOUN iajs-1794 26 31 . . PUNCT iajs-1794 27 1 the the DET iajs-1794 27 2 molar molar ADJ iajs-1794 27 3 conductance conductance NOUN iajs-1794 27 4 of of ADP iajs-1794 27 5 complexes complex NOUN iajs-1794 27 6 was be AUX iajs-1794 27 7 measured measure VERB iajs-1794 27 8 on on ADP iajs-1794 27 9 hana hana PROPN iajs-1794 27 10 conductivity conductivity NOUN iajs-1794 27 11 meter meter NOUN iajs-1794 27 12 in in ADP iajs-1794 27 13 dmso dmso NOUN iajs-1794 27 14 . . PUNCT iajs-1794 28 1 tg tg PROPN iajs-1794 28 2 and and CCONJ iajs-1794 28 3 dsc dsc PROPN iajs-1794 28 4 ( ( PUNCT iajs-1794 28 5 differential differential NOUN iajs-1794 28 6 scanning scanning NOUN iajs-1794 28 7 colurimetry colurimetry NOUN iajs-1794 28 8 ) ) PUNCT iajs-1794 28 9 thermo thermo NOUN iajs-1794 28 10 grams gram NOUN iajs-1794 28 11 in in ADP iajs-1794 28 12 different different ADJ iajs-1794 28 13 ranges range NOUN iajs-1794 28 14 were be AUX iajs-1794 28 15 carried carry VERB iajs-1794 28 16 out out ADP iajs-1794 28 17 at at ADP iajs-1794 28 18 ( ( PUNCT iajs-1794 28 19 r.t r.t PROPN iajs-1794 28 20 ) ) PUNCT iajs-1794 28 21 heating heating NOUN iajs-1794 28 22 rate rate NOUN iajs-1794 28 23 = = SYM iajs-1794 28 24 10c0/ 10c0/ NUM iajs-1794 28 25 min min NOUN iajs-1794 28 26 ( ( PUNCT iajs-1794 28 27 linseis linseis NOUN iajs-1794 28 28 sta sta PROPN iajs-1794 28 29 pt-1000 pt-1000 PROPN iajs-1794 28 30 ) ) PUNCT iajs-1794 28 31 were be AUX iajs-1794 28 32 run run VERB iajs-1794 28 33 in in ADP iajs-1794 28 34 college college NOUN iajs-1794 28 35 of of ADP iajs-1794 28 36 education education NOUN iajs-1794 28 37 for for ADP iajs-1794 28 38 pure pure ADJ iajs-1794 28 39 science science NOUN iajs-1794 28 40 \ibn \ibn PROPN iajs-1794 28 41 - - PUNCT iajs-1794 28 42 haitham haitham PROPN iajs-1794 28 43 . . PUNCT iajs-1794 29 1 the the DET iajs-1794 29 2 metal metal NOUN iajs-1794 29 3 contents content NOUN iajs-1794 29 4 of of ADP iajs-1794 29 5 the the DET iajs-1794 29 6 complexes complex NOUN iajs-1794 29 7 were be AUX iajs-1794 29 8 determined determine VERB iajs-1794 29 9 by by ADP iajs-1794 29 10 atomic atomic ADJ iajs-1794 29 11 absorption absorption NOUN iajs-1794 29 12 measurements measurement NOUN iajs-1794 29 13 were be AUX iajs-1794 29 14 performed perform VERB iajs-1794 29 15 by by ADP iajs-1794 29 16 using use VERB iajs-1794 29 17 the the DET iajs-1794 29 18 instrument instrument NOUN iajs-1794 29 19 analytic analytic ADJ iajs-1794 29 20 jena jena NOUN iajs-1794 29 21 / / PUNCT iajs-1794 29 22 a a DET iajs-1794 29 23 spect spect NOUN iajs-1794 29 24 ls ls ADJ iajs-1794 29 25 /fl /fl NOUN iajs-1794 30 1 1.3.0.0 1.3.0.0 NUM iajs-1794 30 2 , , PUNCT iajs-1794 30 3 a a DET iajs-1794 30 4 bnsina bnsina ADJ iajs-1794 30 5 center center NOUN iajs-1794 30 6 , , PUNCT iajs-1794 30 7 ministry ministry NOUN iajs-1794 30 8 of of ADP iajs-1794 30 9 industry industry NOUN iajs-1794 30 10 . . PUNCT iajs-1794 31 1 magnetic magnetic ADJ iajs-1794 31 2 moment moment NOUN iajs-1794 31 3 for for ADP iajs-1794 31 4 a a DET iajs-1794 31 5 prepared prepared ADJ iajs-1794 31 6 complex complex NOUN iajs-1794 31 7 in in ADP iajs-1794 31 8 the the DET iajs-1794 31 9 solid solid ADJ iajs-1794 31 10 state state NOUN iajs-1794 31 11 at at ADP iajs-1794 31 12 room room NOUN iajs-1794 31 13 temperature temperature NOUN iajs-1794 31 14 were be AUX iajs-1794 31 15 measured measure VERB iajs-1794 31 16 according accord VERB iajs-1794 31 17 to to ADP iajs-1794 31 18 faraday faraday PROPN iajs-1794 31 19 ’s ’s PART iajs-1794 31 20 method method NOUN iajs-1794 31 21 using use VERB iajs-1794 31 22 : : PUNCT iajs-1794 31 23 auto auto NOUN iajs-1794 31 24 magnetic magnetic ADJ iajs-1794 31 25 susceptibility susceptibility NOUN iajs-1794 31 26 balance balance NOUN iajs-1794 31 27 sherwood sherwood PROPN iajs-1794 31 28 scientific scientific PROPN iajs-1794 31 29 . . PUNCT iajs-1794 32 1 almustansiriyah almustansiriyah PROPN iajs-1794 32 2 university university PROPN iajs-1794 32 3 . . PUNCT iajs-1794 33 1 the the DET iajs-1794 33 2 chloride chloride PROPN iajs-1794 33 3 content content NOUN iajs-1794 33 4 for for ADP iajs-1794 33 5 complexes complex NOUN iajs-1794 33 6 were be AUX iajs-1794 33 7 determined determine VERB iajs-1794 33 8 by by ADP iajs-1794 33 9 mohr mohr PROPN iajs-1794 33 10 ’s ’s PART iajs-1794 33 11 method method NOUN iajs-1794 33 12 . . PUNCT iajs-1794 34 1 mass mass PROPN iajs-1794 34 2 spectra spectra PROPN iajs-1794 34 3 were be AUX iajs-1794 34 4 performed perform VERB iajs-1794 34 5 using use VERB iajs-1794 34 6 the the DET iajs-1794 34 7 instrument instrument NOUN iajs-1794 34 8 : : PUNCT iajs-1794 34 9 gc gc PROPN iajs-1794 34 10 ms ms PROPN iajs-1794 34 11 – – PUNCT iajs-1794 34 12 qp qp PROPN iajs-1794 34 13 2010 2010 NUM iajs-1794 34 14 vltra vltra NOUN iajs-1794 34 15 , , PUNCT iajs-1794 34 16 almustansiriyah almustansiriyah PROPN iajs-1794 34 17 university university PROPN iajs-1794 34 18 . . PUNCT iajs-1794 35 1 purity purity NOUN iajs-1794 35 2 of of ADP iajs-1794 35 3 products product NOUN iajs-1794 35 4 was be AUX iajs-1794 35 5 detected detect VERB iajs-1794 35 6 using use VERB iajs-1794 35 7 t t PROPN iajs-1794 35 8 lc lc NOUN iajs-1794 35 9 techniques technique NOUN iajs-1794 35 10 using use VERB iajs-1794 35 11 a a DET iajs-1794 35 12 mixture mixture NOUN iajs-1794 35 13 of of ADP iajs-1794 35 14 chloroforms chloroform NOUN iajs-1794 35 15 : : PUNCT iajs-1794 35 16 methanol methanol NOUN iajs-1794 35 17 ( ( PUNCT iajs-1794 35 18 4:1 4:1 NUM iajs-1794 35 19 v v NOUN iajs-1794 35 20 / / SYM iajs-1794 35 21 v v NOUN iajs-1794 35 22 ) ) PUNCT iajs-1794 35 23 , , PUNCT iajs-1794 35 24 and and CCONJ iajs-1794 35 25 ethyl ethyl PROPN iajs-1794 35 26 acetate acetate NOUN iajs-1794 35 27 : : PUNCT iajs-1794 35 28 methanol methanol NOUN iajs-1794 35 29 ( ( PUNCT iajs-1794 35 30 3:2 3:2 NUM iajs-1794 35 31 v v NOUN iajs-1794 35 32 / / SYM iajs-1794 35 33 v v NOUN iajs-1794 35 34 ) ) PUNCT iajs-1794 35 35 , , PUNCT iajs-1794 35 36 and and CCONJ iajs-1794 35 37 iodine iodine NOUN iajs-1794 35 38 chamber chamber NOUN iajs-1794 35 39 for for ADP iajs-1794 35 40 spot spot NOUN iajs-1794 35 41 location location NOUN iajs-1794 35 42 . . PUNCT iajs-1794 36 1 the the DET iajs-1794 36 2 metal metal NOUN iajs-1794 36 3 chloride chloride NOUN iajs-1794 36 4 cocl2ꞏ6h2o cocl2ꞏ6h2o NOUN iajs-1794 36 5 , , PUNCT iajs-1794 36 6 nicl2ꞏ6h2o nicl2ꞏ6h2o NUM iajs-1794 36 7 , , PUNCT iajs-1794 36 8 cucl2ꞏ2h2o cucl2ꞏ2h2o NOUN iajs-1794 36 9 and and CCONJ iajs-1794 36 10 cdcl2.2h2o cdcl2.2h2o NOUN iajs-1794 36 11 , , PUNCT iajs-1794 36 12 were be AUX iajs-1794 36 13 provided provide VERB iajs-1794 36 14 from from ADP iajs-1794 36 15 sigma sigma PROPN iajs-1794 36 16 - - PUNCT iajs-1794 36 17 aldrich aldrich PROPN iajs-1794 36 18 company company NOUN iajs-1794 36 19 ( ( PUNCT iajs-1794 36 20 uae uae PROPN iajs-1794 36 21 ) ) PUNCT iajs-1794 36 22 , , PUNCT iajs-1794 36 23 1 1 NUM iajs-1794 36 24 , , PUNCT iajs-1794 36 25 4 4 NUM iajs-1794 36 26 - - PUNCT iajs-1794 36 27 phenylenediamine phenylenediamine NOUN iajs-1794 36 28 and and CCONJ iajs-1794 36 29 solvents solvent NOUN iajs-1794 36 30 were be AUX iajs-1794 36 31 supplied supply VERB iajs-1794 36 32 from from ADP iajs-1794 36 33 fluka fluka PROPN iajs-1794 36 34 company company NOUN iajs-1794 36 35 in in ADP iajs-1794 36 36 99 99 NUM iajs-1794 36 37 % % NOUN iajs-1794 36 38 purity purity NOUN iajs-1794 36 39 . . PUNCT iajs-1794 37 1 all all DET iajs-1794 37 2 other other ADJ iajs-1794 37 3 chemicals chemical NOUN iajs-1794 37 4 used use VERB iajs-1794 37 5 were be AUX iajs-1794 37 6 of of ADP iajs-1794 37 7 annular annular ADJ iajs-1794 37 8 grade grade NOUN iajs-1794 37 9 . . PUNCT iajs-1794 38 1 the the DET iajs-1794 38 2 thermal thermal ADJ iajs-1794 38 3 analyses analysis NOUN iajs-1794 38 4 were be AUX iajs-1794 38 5 scanned scan VERB iajs-1794 38 6 with with ADP iajs-1794 38 7 differential differential NOUN iajs-1794 38 8 scanning scan VERB iajs-1794 38 9 calorimetric calorimetric ADJ iajs-1794 38 10 ( ( PUNCT iajs-1794 38 11 dsc dsc NOUN iajs-1794 38 12 ) ) PUNCT iajs-1794 38 13 on on ADP iajs-1794 38 14 sta sta PROPN iajs-1794 38 15 pt-1000 pt-1000 PROPN iajs-1794 38 16 lenses lense NOUN iajs-1794 38 17 company company PROPN iajs-1794 38 18 / / SYM iajs-1794 38 19 germany germany PROPN iajs-1794 38 20 . . 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PUNCT iajs-1794 84 1 the the DET iajs-1794 84 2 metal metal NOUN iajs-1794 84 3 complexes complex NOUN iajs-1794 84 4 in in ADP iajs-1794 84 5 dmso dmso ADJ iajs-1794 84 6 solutions solution NOUN iajs-1794 84 7 showed show VERB iajs-1794 84 8 molar molar ADJ iajs-1794 84 9 conductance conductance NOUN iajs-1794 84 10 in in ADP iajs-1794 84 11 the the DET iajs-1794 84 12 region region NOUN iajs-1794 84 13 ( ( PUNCT iajs-1794 84 14 19 19 NUM iajs-1794 84 15 - - SYM iajs-1794 84 16 73 73 NUM iajs-1794 84 17 ) ) PUNCT iajs-1794 84 18 ohm-1.cm2.mol-1 ohm-1.cm2.mol-1 NOUN iajs-1794 84 19 indicating indicate VERB iajs-1794 84 20 that that SCONJ iajs-1794 84 21 all all DET iajs-1794 84 22 complexes complex NOUN iajs-1794 84 23 were be AUX iajs-1794 84 24 neutral neutral ADJ iajs-1794 84 25 except except SCONJ iajs-1794 84 26 cadmium cadmium NOUN iajs-1794 84 27 ( ( PUNCT iajs-1794 84 28 ii ii NOUN iajs-1794 84 29 ) ) PUNCT iajs-1794 84 30 complexes complex NOUN iajs-1794 84 31 which which PRON iajs-1794 84 32 were be AUX iajs-1794 84 33 electrolytes electrolyte NOUN iajs-1794 84 34 due due ADP iajs-1794 84 35 to to ADP iajs-1794 84 36 the the DET iajs-1794 84 37 presence presence NOUN iajs-1794 84 38 of of ADP iajs-1794 84 39 chloride chloride NOUN iajs-1794 84 40 species specie NOUN iajs-1794 84 41 as as ADP iajs-1794 84 42 counter counter ADJ iajs-1794 84 43 ions ion NOUN iajs-1794 84 44 in in ADP iajs-1794 84 45 the the DET iajs-1794 84 46 structure structure NOUN iajs-1794 84 47 of of ADP iajs-1794 84 48 their their PRON iajs-1794 84 49 structures structure NOUN iajs-1794 84 50 [ [ X iajs-1794 84 51 16 16 NUM iajs-1794 84 52 ] ] PUNCT iajs-1794 84 53 . . PUNCT iajs-1794 85 1 as as ADV iajs-1794 85 2 well well ADV iajs-1794 85 3 as as ADP iajs-1794 85 4 the the DET iajs-1794 85 5 metal metal NOUN iajs-1794 85 6 estimation estimation NOUN iajs-1794 85 7 measured measure VERB iajs-1794 85 8 via via ADP iajs-1794 85 9 faas faas PROPN iajs-1794 85 10 indicated indicate VERB iajs-1794 85 11 formula formula NOUN iajs-1794 85 12 of of ADP iajs-1794 85 13 complexes complex NOUN iajs-1794 85 14 and and CCONJ iajs-1794 85 15 the the DET iajs-1794 85 16 molar molar ADJ iajs-1794 85 17 ratio ratio NOUN iajs-1794 85 18 2:1 2:1 NUM iajs-1794 86 1 ( ( PUNCT iajs-1794 86 2 l l NOUN iajs-1794 86 3 : : PUNCT iajs-1794 86 4 m m VERB iajs-1794 86 5 ) ) PUNCT iajs-1794 86 6 in in ADP iajs-1794 86 7 all all DET iajs-1794 86 8 metal metal NOUN iajs-1794 86 9 complexes complex NOUN iajs-1794 86 10 . . 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PUNCT iajs-1794 89 1 the the DET iajs-1794 89 2 l1 l1 PROPN iajs-1794 89 3 exhibited exhibit VERB iajs-1794 89 4 strong strong ADJ iajs-1794 89 5 bands band NOUN iajs-1794 89 6 around around ADP iajs-1794 89 7 1660 1660 NUM iajs-1794 89 8 and and CCONJ iajs-1794 89 9 1600 1600 NUM iajs-1794 89 10 cm-1 cm-1 VERB iajs-1794 89 11 assigning assign VERB iajs-1794 89 12 to to ADP iajs-1794 89 13 vibration vibration NOUN iajs-1794 89 14 modes mode NOUN iajs-1794 89 15 of of ADP iajs-1794 89 16 carbonyl carbonyl NOUN iajs-1794 89 17 and and CCONJ iajs-1794 89 18 immine immine NOUN iajs-1794 89 19 respectively respectively ADV iajs-1794 89 20 [ [ X iajs-1794 89 21 13,14 13,14 NUM iajs-1794 89 22 ] ] X iajs-1794 89 23 . . PUNCT iajs-1794 90 1 as as ADV iajs-1794 90 2 well well ADV iajs-1794 90 3 as as ADP iajs-1794 90 4 the the DET iajs-1794 90 5 appearance appearance NOUN iajs-1794 90 6 of of ADP iajs-1794 90 7 medium medium ADJ iajs-1794 90 8 absorptions absorption NOUN iajs-1794 90 9 around around ADP iajs-1794 90 10 3200 3200 NUM iajs-1794 90 11 - - SYM iajs-1794 90 12 3300 3300 NUM iajs-1794 90 13 cm-1 cm-1 NOUN iajs-1794 90 14 confirms confirm VERB iajs-1794 90 15 the the DET iajs-1794 90 16 stretching stretching NOUN iajs-1794 90 17 of of ADP iajs-1794 90 18 amino amino NOUN iajs-1794 90 19 – – PUNCT iajs-1794 90 20 nh2moiety nh2moiety NOUN iajs-1794 90 21 . . PUNCT iajs-1794 91 1 the the DET iajs-1794 91 2 remarkable remarkable ADJ iajs-1794 91 3 changes change NOUN iajs-1794 91 4 in in ADP iajs-1794 91 5 these these DET iajs-1794 91 6 functional functional ADJ iajs-1794 91 7 groups group NOUN iajs-1794 91 8 in in ADP iajs-1794 91 9 the the DET iajs-1794 91 10 ir ir PROPN iajs-1794 91 11 spectra spectra NOUN iajs-1794 91 12 of of ADP iajs-1794 91 13 complexes complex NOUN iajs-1794 91 14 to to ADP iajs-1794 91 15 ( ( PUNCT iajs-1794 91 16 1640 1640 NUM iajs-1794 91 17 - - SYM iajs-1794 91 18 1654 1654 NUM iajs-1794 91 19 ) ) PUNCT iajs-1794 91 20 and and CCONJ iajs-1794 91 21 ( ( PUNCT iajs-1794 91 22 1585 1585 NUM iajs-1794 91 23 - - SYM iajs-1794 91 24 1610 1610 NUM iajs-1794 91 25 ) ) PUNCT iajs-1794 91 26 cm-1 cm-1 PUNCT iajs-1794 91 27 confirms confirm VERB iajs-1794 91 28 the the DET iajs-1794 91 29 coordination coordination NOUN iajs-1794 91 30 of of ADP iajs-1794 91 31 such such ADJ iajs-1794 91 32 active active ADJ iajs-1794 91 33 sites site NOUN iajs-1794 91 34 with with ADP iajs-1794 91 35 the the DET iajs-1794 91 36 metal metal NOUN iajs-1794 91 37 ions ion NOUN iajs-1794 91 38 . . PUNCT iajs-1794 92 1 in in ADP iajs-1794 92 2 addition addition NOUN iajs-1794 92 3 to to ADP iajs-1794 92 4 the the DET iajs-1794 92 5 weak weak ADJ iajs-1794 92 6 bands band NOUN iajs-1794 92 7 around around ADP iajs-1794 92 8 3074 3074 NUM iajs-1794 92 9 , , PUNCT iajs-1794 92 10 2960 2960 NUM iajs-1794 92 11 - - SYM iajs-1794 92 12 2877 2877 NUM iajs-1794 92 13 cm-1 cm-1 NOUN iajs-1794 92 14 and and CCONJ iajs-1794 92 15 780 780 NUM iajs-1794 92 16 - - SYM iajs-1794 92 17 900 900 NUM iajs-1794 92 18 cm-1 cm-1 VERB iajs-1794 92 19 could could AUX iajs-1794 92 20 be be AUX iajs-1794 92 21 due due ADJ iajs-1794 92 22 to to ADP iajs-1794 92 23 the the DET iajs-1794 92 24 vibration vibration NOUN iajs-1794 92 25 of of ADP iajs-1794 92 26 -c -c PROPN iajs-1794 92 27 - - PUNCT iajs-1794 92 28 h h NOUN iajs-1794 92 29 and and CCONJ iajs-1794 92 30 c c NOUN iajs-1794 92 31 - - PUNCT iajs-1794 92 32 n[17 n[17 PROPN iajs-1794 92 33 ] ] PUNCT iajs-1794 92 34 of of ADP iajs-1794 92 35 pyrazine pyrazine ADJ iajs-1794 92 36 moiety moiety NOUN iajs-1794 92 37 ring ring NOUN iajs-1794 92 38 respectively respectively ADV iajs-1794 92 39 . . PUNCT iajs-1794 93 1 the the DET iajs-1794 93 2 appearance appearance NOUN iajs-1794 93 3 of of ADP iajs-1794 93 4 new new ADJ iajs-1794 93 5 absorptions absorption NOUN iajs-1794 93 6 in in ADP iajs-1794 93 7 the the DET iajs-1794 93 8 regions region NOUN iajs-1794 93 9 ( ( PUNCT iajs-1794 93 10 1070 1070 NUM iajs-1794 93 11 - - SYM iajs-1794 93 12 1093 1093 NUM iajs-1794 93 13 ) ) PUNCT iajs-1794 93 14 , , PUNCT iajs-1794 93 15 ( ( PUNCT iajs-1794 93 16 1330 1330 NUM iajs-1794 93 17 - - SYM iajs-1794 93 18 1381 1381 NUM iajs-1794 93 19 ) ) PUNCT iajs-1794 93 20 , , PUNCT iajs-1794 93 21 and and CCONJ iajs-1794 93 22 ( ( PUNCT iajs-1794 93 23 1616 1616 NUM iajs-1794 93 24 - - SYM iajs-1794 93 25 1577 1577 NUM iajs-1794 93 26 ) ) PUNCT iajs-1794 93 27 cm-1 cm-1 VERB iajs-1794 93 28 assigning assign VERB iajs-1794 93 29 to to PART iajs-1794 93 30 νnh2 νnh2 PROPN iajs-1794 93 31 , , PUNCT iajs-1794 93 32 ν ν PROPN iajs-1794 93 33 - - PUNCT iajs-1794 93 34 c c NOUN iajs-1794 93 35 = = NOUN iajs-1794 93 36 o o NOUN iajs-1794 93 37 , , PUNCT iajs-1794 93 38 and and CCONJ iajs-1794 93 39 ν ν NOUN iajs-1794 93 40 - - PUNCT iajs-1794 93 41 c c NOUN iajs-1794 93 42 = = NOUN iajs-1794 93 43 n n PRON iajs-1794 93 44 modes mode NOUN iajs-1794 93 45 respectively respectively ADV iajs-1794 93 46 thereby thereby ADV iajs-1794 93 47 support support VERB iajs-1794 93 48 the the DET iajs-1794 93 49 ring ring NOUN iajs-1794 93 50 closure closure NOUN iajs-1794 93 51 to to PART iajs-1794 93 52 afford afford VERB iajs-1794 93 53 the the DET iajs-1794 93 54 quinoxaline quinoxaline PROPN iajs-1794 93 55 ring ring NOUN iajs-1794 93 56 . . PUNCT iajs-1794 94 1 the the DET iajs-1794 94 2 infra infra NOUN iajs-1794 94 3 - - PUNCT iajs-1794 94 4 red red ADJ iajs-1794 94 5 spectra spectra NOUN iajs-1794 94 6 of of ADP iajs-1794 94 7 the the DET iajs-1794 94 8 metal metal NOUN iajs-1794 94 9 complexes complex NOUN iajs-1794 94 10 formed form VERB iajs-1794 94 11 with with ADP iajs-1794 94 12 the the DET iajs-1794 94 13 two two NUM iajs-1794 94 14 ligands ligand NOUN iajs-1794 94 15 exhibited exhibit VERB iajs-1794 94 16 significant significant ADJ iajs-1794 94 17 variations variation NOUN iajs-1794 94 18 in in ADP iajs-1794 94 19 the the DET iajs-1794 94 20 modes mode NOUN iajs-1794 94 21 of of ADP iajs-1794 94 22 – – PUNCT iajs-1794 94 23 nhand nhand NOUN iajs-1794 94 24 – – PUNCT iajs-1794 94 25 c c NOUN iajs-1794 94 26 = = X iajs-1794 94 27 o o X iajs-1794 94 28 in in ADP iajs-1794 94 29 the the DET iajs-1794 94 30 ranges range NOUN iajs-1794 94 31 3200 3200 NUM iajs-1794 94 32 - - SYM iajs-1794 94 33 3300 3300 NUM iajs-1794 94 34 cm-1 cm-1 NOUN iajs-1794 94 35 and and CCONJ iajs-1794 94 36 1650 1650 NUM iajs-1794 94 37 - - SYM iajs-1794 94 38 1640 1640 NUM iajs-1794 94 39 cm-1 cm-1 NOUN iajs-1794 94 40 respectively respectively ADV iajs-1794 94 41 . . PUNCT iajs-1794 95 1 furthermore furthermore ADV iajs-1794 95 2 , , PUNCT iajs-1794 95 3 the the DET iajs-1794 95 4 new new ADJ iajs-1794 95 5 bands band NOUN iajs-1794 95 6 appeared appear VERB iajs-1794 95 7 around around ADP iajs-1794 95 8 400460 400460 NUM iajs-1794 95 9 and and CCONJ iajs-1794 95 10 477 477 NUM iajs-1794 95 11 - - SYM iajs-1794 95 12 590 590 NUM iajs-1794 95 13 cm-1 cm-1 VERB iajs-1794 95 14 could could AUX iajs-1794 95 15 be be AUX iajs-1794 95 16 assigned assign VERB iajs-1794 95 17 to to ADP iajs-1794 95 18 m m NOUN iajs-1794 95 19 - - NOUN iajs-1794 95 20 o o X iajs-1794 95 21 and and CCONJ iajs-1794 95 22 m m PROPN iajs-1794 95 23 - - PUNCT iajs-1794 95 24 n n NOUN iajs-1794 95 25 bonds bond NOUN iajs-1794 95 26 respectively respectively ADV iajs-1794 95 27 . . PUNCT iajs-1794 96 1 ihsciconf ihsciconf PROPN iajs-1794 96 2 2017 2017 NUM iajs-1794 96 3 special special ADJ iajs-1794 96 4 issue issue NOUN iajs-1794 96 5 ibn ibn PROPN iajs-1794 96 6 al al PROPN iajs-1794 96 7 - - PUNCT iajs-1794 96 8 haitham haitham PROPN iajs-1794 96 9 journal journal PROPN iajs-1794 96 10 for for ADP iajs-1794 96 11 pure pure ADJ iajs-1794 96 12 and and CCONJ iajs-1794 96 13 applied apply VERB iajs-1794 96 14 science science NOUN iajs-1794 96 15 https:// https:// PROPN iajs-1794 96 16 doi.org/ doi.org/ ADP iajs-1794 96 17 10.30526/2017.ihsciconf.1794 10.30526/2017.ihsciconf.1794 NOUN iajs-1794 96 18 for for ADP iajs-1794 96 19 more more ADJ iajs-1794 96 20 information information NOUN iajs-1794 96 21 about about ADP iajs-1794 96 22 the the DET iajs-1794 96 23 conference conference NOUN iajs-1794 96 24 please please INTJ iajs-1794 96 25 visit visit VERB iajs-1794 96 26 the the DET iajs-1794 96 27 websites website NOUN iajs-1794 96 28 : : PUNCT iajs-1794 96 29 http://www.ihsciconf.org/conf/ http://www.ihsciconf.org/conf/ VERB iajs-1794 96 30     SPACE iajs-1794 96 31 www.ihsciconf.org www.ihsciconf.org ADJ iajs-1794 96 32       SPACE iajs-1794 96 33 chemistry|211 chemistry|211 PROPN iajs-1794 96 34         SPACE iajs-1794 96 35 nmr nmr NOUN iajs-1794 96 36 study study VERB iajs-1794 96 37 the the DET iajs-1794 96 38 1h 1h NUM iajs-1794 96 39 nmr nmr NOUN iajs-1794 96 40 of of ADP iajs-1794 96 41 the the DET iajs-1794 96 42 two two NUM iajs-1794 96 43 ligands ligand NOUN iajs-1794 96 44 were be AUX iajs-1794 96 45 shown show VERB iajs-1794 96 46 in in ADP iajs-1794 96 47 figures figure NOUN iajs-1794 96 48 ( ( PUNCT iajs-1794 96 49 1,2 1,2 NUM iajs-1794 96 50 ) ) PUNCT iajs-1794 96 51 where where SCONJ iajs-1794 96 52 the the DET iajs-1794 96 53 variable variable ADJ iajs-1794 96 54 peaks peak NOUN iajs-1794 96 55 around around ADV iajs-1794 96 56 ( ( PUNCT iajs-1794 96 57 8.30.1 8.30.1 NUM iajs-1794 96 58 - - SYM iajs-1794 96 59 7.9 7.9 NUM iajs-1794 96 60 ) ) PUNCT iajs-1794 96 61 , , PUNCT iajs-1794 96 62 ( ( PUNCT iajs-1794 96 63 8 8 NUM iajs-1794 96 64 . . NOUN iajs-1794 96 65 5 5 NUM iajs-1794 96 66 - - SYM iajs-1794 96 67 8.90 8.90 NUM iajs-1794 96 68 ) ) PUNCT iajs-1794 96 69 and and CCONJ iajs-1794 96 70 ( ( PUNCT iajs-1794 96 71 9.02 9.02 NUM iajs-1794 96 72 - - SYM iajs-1794 96 73 9.253 9.253 NUM iajs-1794 96 74 ) ) PUNCT iajs-1794 96 75 ppm ppm NOUN iajs-1794 96 76 were be AUX iajs-1794 96 77 assigned assign VERB iajs-1794 96 78 to to ADP iajs-1794 96 79 the the DET iajs-1794 96 80 resonance resonance NOUN iajs-1794 96 81 of of ADP iajs-1794 96 82 aromatic aromatic ADJ iajs-1794 96 83 and and CCONJ iajs-1794 96 84 pyrazine pyrazine ADJ iajs-1794 96 85 protons proton NOUN iajs-1794 96 86 in in ADP iajs-1794 96 87 the the DET iajs-1794 96 88 structure structure NOUN iajs-1794 96 89 of of ADP iajs-1794 96 90 two two NUM iajs-1794 96 91 ligand ligand ADJ iajs-1794 96 92 l1 l1 PROPN iajs-1794 96 93 . . PUNCT iajs-1794 97 1 furthermore furthermore ADV iajs-1794 97 2 , , PUNCT iajs-1794 97 3 the the DET iajs-1794 97 4 absorptions absorption NOUN iajs-1794 97 5 around around ADV iajs-1794 97 6 ( ( PUNCT iajs-1794 97 7 2.20 2.20 NUM iajs-1794 97 8 - - SYM iajs-1794 97 9 3.74 3.74 NUM iajs-1794 97 10 ) ) PUNCT iajs-1794 97 11 , , PUNCT iajs-1794 97 12 ( ( PUNCT iajs-1794 97 13 4.02 4.02 NUM iajs-1794 97 14 - - SYM iajs-1794 97 15 4.70 4.70 NUM iajs-1794 97 16 ) ) PUNCT iajs-1794 97 17 and and CCONJ iajs-1794 97 18 ( ( PUNCT iajs-1794 97 19 5.20 5.20 NUM iajs-1794 97 20 - - SYM iajs-1794 97 21 8.20 8.20 NUM iajs-1794 97 22 ) ) PUNCT iajs-1794 97 23 ppm ppm NOUN iajs-1794 97 24 may may AUX iajs-1794 97 25 be be AUX iajs-1794 97 26 ascribed ascribe VERB iajs-1794 97 27 to to ADP iajs-1794 97 28 spincoupling spincouple VERB iajs-1794 97 29 methylene methylene NOUN iajs-1794 97 30 – – PUNCT iajs-1794 97 31 ch2 ch2 NOUN iajs-1794 97 32 - - PUNCT iajs-1794 97 33 ch2moiety ch2moiety NOUN iajs-1794 97 34 , , PUNCT iajs-1794 97 35 -nhand -nhand ADJ iajs-1794 97 36 the the DET iajs-1794 97 37 aromatic aromatic ADJ iajs-1794 97 38 ar ar PROPN iajs-1794 97 39 - - ADJ iajs-1794 97 40 h h NOUN iajs-1794 97 41 protons proton NOUN iajs-1794 97 42 respectively respectively ADV iajs-1794 97 43 in in ADP iajs-1794 97 44 the the DET iajs-1794 97 45 structure structure NOUN iajs-1794 97 46 of of ADP iajs-1794 97 47 l2 l2 NOUN iajs-1794 97 48 ligand ligand NOUN iajs-1794 98 1 [ [ X iajs-1794 98 2 13,18 13,18 NUM iajs-1794 98 3 ] ] PUNCT iajs-1794 98 4 . . PUNCT iajs-1794 99 1 uv uv NOUN iajs-1794 99 2 - - PUNCT iajs-1794 99 3 visible visible ADJ iajs-1794 99 4 spectra spectra NOUN iajs-1794 99 5 the the DET iajs-1794 99 6 electronic electronic ADJ iajs-1794 99 7 spectra spectra NOUN iajs-1794 99 8 of of ADP iajs-1794 99 9 the the DET iajs-1794 99 10 ligands ligand NOUN iajs-1794 99 11 l1 l1 PROPN iajs-1794 99 12 , , PUNCT iajs-1794 99 13 l2 l2 NOUN iajs-1794 99 14 and and CCONJ iajs-1794 99 15 their their PRON iajs-1794 99 16 solution solution NOUN iajs-1794 99 17 metal metal NOUN iajs-1794 99 18 complexes complex NOUN iajs-1794 99 19 were be AUX iajs-1794 99 20 recorded record VERB iajs-1794 99 21 in in ADP iajs-1794 99 22 ethanol ethanol NOUN iajs-1794 99 23 and and CCONJ iajs-1794 99 24 dmso dmso ADJ iajs-1794 99 25 solutions solution NOUN iajs-1794 99 26 . . PUNCT iajs-1794 100 1 the the DET iajs-1794 100 2 quinoxaline quinoxaline PROPN iajs-1794 100 3 base base PROPN iajs-1794 100 4 ligand ligand PROPN iajs-1794 100 5 l1 l1 PROPN iajs-1794 100 6 exhibits exhibit VERB iajs-1794 100 7 an an DET iajs-1794 100 8 absorption absorption NOUN iajs-1794 100 9 around around ADV iajs-1794 100 10 and and CCONJ iajs-1794 100 11 in in ADP iajs-1794 100 12 the the DET iajs-1794 100 13 220 220 NUM iajs-1794 100 14 nm nm NOUN iajs-1794 100 15 region region NOUN iajs-1794 100 16 assigning assign VERB iajs-1794 100 17 to to ADP iajs-1794 100 18 the the DET iajs-1794 100 19   NOUN iajs-1794 100 20 * * PUNCT iajs-1794 100 21 transition transition NOUN iajs-1794 100 22 which which PRON iajs-1794 100 23 is be AUX iajs-1794 100 24 remained remain VERB iajs-1794 100 25 in in ADP iajs-1794 100 26 the the DET iajs-1794 100 27 spectra spectra NOUN iajs-1794 100 28 of of ADP iajs-1794 100 29 all all DET iajs-1794 100 30 complexes complex NOUN iajs-1794 100 31 . . PUNCT iajs-1794 101 1 the the DET iajs-1794 101 2 peaks peak NOUN iajs-1794 101 3 around around ADP iajs-1794 101 4 290 290 NUM iajs-1794 101 5 and and CCONJ iajs-1794 101 6 350 350 NUM iajs-1794 101 7 nm nm NOUN iajs-1794 101 8 are be AUX iajs-1794 101 9 assigned assign VERB iajs-1794 101 10 to to ADP iajs-1794 101 11 nπ nπ NOUN iajs-1794 101 12 * * NOUN iajs-1794 101 13 transitions transition NOUN iajs-1794 101 14 of of ADP iajs-1794 101 15 ( ( PUNCT iajs-1794 101 16 -c -c PROPN iajs-1794 101 17 = = SYM iajs-1794 101 18 n- n- X iajs-1794 101 19 , , PUNCT iajs-1794 101 20 -c -c PUNCT iajs-1794 101 21 = = SYM iajs-1794 101 22 c c NOUN iajs-1794 101 23 ) ) PUNCT iajs-1794 101 24 groups group NOUN iajs-1794 101 25 and and CCONJ iajs-1794 101 26 intra intra ADJ iajs-1794 101 27 - - ADJ iajs-1794 101 28 ligand ligand ADJ iajs-1794 101 29 charge charge NOUN iajs-1794 101 30 transfer[15].the transfer[15].the DET iajs-1794 101 31 electronic electronic ADJ iajs-1794 101 32 spectra spectra NOUN iajs-1794 101 33 of of ADP iajs-1794 101 34 cobalt(ii cobalt(ii PROPN iajs-1794 101 35 ) ) PUNCT iajs-1794 101 36 complex complex NOUN iajs-1794 101 37 in in ADP iajs-1794 101 38 dmso dmso ADJ iajs-1794 101 39 solution solution NOUN iajs-1794 101 40 exhibited exhibit VERB iajs-1794 101 41 spin spin NOUN iajs-1794 101 42 - - PUNCT iajs-1794 101 43 allowed allow VERB iajs-1794 101 44 d d ADJ iajs-1794 101 45 - - PUNCT iajs-1794 101 46 d d NOUN iajs-1794 101 47 transitions transition NOUN iajs-1794 101 48 at at ADP iajs-1794 101 49 650 650 NUM iajs-1794 101 50 and and CCONJ iajs-1794 101 51 550 550 NUM iajs-1794 101 52 nm nm NOUN iajs-1794 101 53 assigning assign VERB iajs-1794 101 54 to to ADP iajs-1794 101 55 the the DET iajs-1794 101 56 4t1g→ 4t1g→ NUM iajs-1794 101 57 4t2 4t2 NUM iajs-1794 101 58 g g NOUN iajs-1794 101 59 and and CCONJ iajs-1794 101 60 4t1 4t1 NUM iajs-1794 101 61 g g PROPN iajs-1794 101 62 → → SYM iajs-1794 101 63 4t1g(p 4t1g(p NUM iajs-1794 101 64 ) ) PUNCT iajs-1794 101 65 transitions transition NOUN iajs-1794 101 66 respectively respectively ADV iajs-1794 101 67 , , PUNCT iajs-1794 101 68 indicating indicate VERB iajs-1794 101 69 the the DET iajs-1794 101 70 octahedral octahedral ADJ iajs-1794 101 71 geometry geometry NOUN iajs-1794 101 72 around around ADP iajs-1794 101 73 cobalt(ii cobalt(ii PROPN iajs-1794 101 74 ) ) PUNCT iajs-1794 101 75 ion ion NOUN iajs-1794 101 76 [ [ X iajs-1794 101 77 19 19 NUM iajs-1794 101 78 ] ] PUNCT iajs-1794 101 79 . . PUNCT iajs-1794 102 1 moreover moreover ADV iajs-1794 102 2 , , PUNCT iajs-1794 102 3 the the DET iajs-1794 102 4 pale pale ADJ iajs-1794 102 5 green green ADJ iajs-1794 102 6 solution solution NOUN iajs-1794 102 7 of of ADP iajs-1794 102 8 nickel(ii nickel(ii ADJ iajs-1794 102 9 ) ) PUNCT iajs-1794 102 10 complexes complex NOUN iajs-1794 102 11 in in ADP iajs-1794 102 12 dmso dmso NOUN iajs-1794 102 13 showed show VERB iajs-1794 102 14 a a DET iajs-1794 102 15 spin spin NOUN iajs-1794 102 16 - - PUNCT iajs-1794 102 17 allowed allow VERB iajs-1794 102 18 peak peak NOUN iajs-1794 102 19 around around ADP iajs-1794 102 20 700 700 NUM iajs-1794 102 21 - - SYM iajs-1794 102 22 670 670 NUM iajs-1794 102 23 nm nm NOUN iajs-1794 102 24 and and CCONJ iajs-1794 102 25 two two NUM iajs-1794 102 26 intense intense ADJ iajs-1794 102 27 peaks peak NOUN iajs-1794 102 28 around around ADP iajs-1794 102 29 280 280 NUM iajs-1794 102 30 and and CCONJ iajs-1794 102 31 218 218 NUM iajs-1794 102 32 nm nm NOUN iajs-1794 102 33 which which PRON iajs-1794 102 34 are be AUX iajs-1794 102 35 assigned assign VERB iajs-1794 102 36 to to ADP iajs-1794 102 37 3a2 3a2 NUM iajs-1794 102 38 g g NOUN iajs-1794 102 39 → → SYM iajs-1794 102 40 3t2 3t2 NUM iajs-1794 102 41 g g NOUN iajs-1794 102 42 and and CCONJ iajs-1794 102 43 intra intra ADJ iajs-1794 102 44 - - ADJ iajs-1794 102 45 ligand ligand ADJ iajs-1794 102 46 charge charge NOUN iajs-1794 102 47 transfer transfer NOUN iajs-1794 102 48 which which PRON iajs-1794 102 49 is be AUX iajs-1794 102 50 overlapped overlap VERB iajs-1794 102 51 with with ADP iajs-1794 102 52 π π PROPN iajs-1794 102 53 - - PUNCT iajs-1794 102 54 π π PROPN iajs-1794 102 55 * * VERB iajs-1794 102 56 respectively respectively ADV iajs-1794 102 57 supporting support VERB iajs-1794 102 58 an an DET iajs-1794 102 59 octahedral octahedral ADJ iajs-1794 102 60 environment environment NOUN iajs-1794 102 61 around around ADP iajs-1794 102 62 nickel(ii nickel(ii ADJ iajs-1794 102 63 ) ) PUNCT iajs-1794 102 64 ion ion NOUN iajs-1794 102 65 . . PUNCT iajs-1794 103 1 however however ADV iajs-1794 103 2 , , PUNCT iajs-1794 103 3 the the DET iajs-1794 103 4 brownish brownish ADJ iajs-1794 103 5 solution solution NOUN iajs-1794 103 6 of of ADP iajs-1794 103 7 copper copper NOUN iajs-1794 103 8 ( ( PUNCT iajs-1794 103 9 ii ii NOUN iajs-1794 103 10 ) ) PUNCT iajs-1794 103 11 complexes complex NOUN iajs-1794 103 12 displayed display VERB iajs-1794 103 13 shoulder shoulder NOUN iajs-1794 103 14 band band NOUN iajs-1794 103 15 in in ADP iajs-1794 103 16 the the DET iajs-1794 103 17 visible visible ADJ iajs-1794 103 18 region region NOUN iajs-1794 103 19 definitely definitely ADV iajs-1794 103 20 around around ADV iajs-1794 103 21 790 790 NUM iajs-1794 103 22 - - SYM iajs-1794 103 23 835 835 NUM iajs-1794 103 24 nm nm NOUN iajs-1794 103 25 that that PRON iajs-1794 103 26 are be AUX iajs-1794 103 27 assigned assign VERB iajs-1794 103 28 to to ADP iajs-1794 103 29 2b1g→2a1 2b1g→2a1 NUM iajs-1794 103 30 g g NOUN iajs-1794 103 31 transition transition NOUN iajs-1794 103 32 . . PUNCT iajs-1794 104 1 as as ADV iajs-1794 104 2 well well ADV iajs-1794 104 3 as as ADP iajs-1794 104 4 the the DET iajs-1794 104 5 high high ADJ iajs-1794 104 6 energy energy NOUN iajs-1794 104 7 bands band NOUN iajs-1794 104 8 in in ADP iajs-1794 104 9 the the DET iajs-1794 104 10 region region NOUN iajs-1794 104 11 400 400 NUM iajs-1794 104 12 - - SYM iajs-1794 104 13 390 390 NUM iajs-1794 104 14 nm nm NOUN iajs-1794 104 15 could could AUX iajs-1794 104 16 be be AUX iajs-1794 104 17 ascribed ascribe VERB iajs-1794 104 18 to to ADP iajs-1794 104 19 the the DET iajs-1794 104 20 overlapping overlapping NOUN iajs-1794 104 21 of of ADP iajs-1794 104 22 the the DET iajs-1794 104 23 resolute resolute ADJ iajs-1794 104 24 d d PROPN iajs-1794 104 25 - - PUNCT iajs-1794 104 26 d d ADJ iajs-1794 104 27 transition transition NOUN iajs-1794 104 28 of of ADP iajs-1794 104 29 the2b1g→2eg the2b1g→2eg NOUN iajs-1794 104 30 type type NOUN iajs-1794 104 31 with with ADP iajs-1794 104 32 lmct lmct NOUN iajs-1794 104 33 transition transition NOUN iajs-1794 104 34 due due ADP iajs-1794 104 35 to to ADP iajs-1794 104 36 the the DET iajs-1794 104 37 pi pi NOUN iajs-1794 104 38 bonding bonding NOUN iajs-1794 104 39 of of ADP iajs-1794 104 40 imine imine ADJ iajs-1794 104 41 moiety moiety NOUN iajs-1794 104 42 of of ADP iajs-1794 104 43 quinoxaline quinoxaline NOUN iajs-1794 104 44 that that PRON iajs-1794 104 45 has have AUX iajs-1794 104 46 been be AUX iajs-1794 104 47 bonded bond VERB iajs-1794 104 48 to to ADP iajs-1794 104 49 the the DET iajs-1794 104 50 central central ADJ iajs-1794 104 51 metal metal NOUN iajs-1794 104 52 ion ion NOUN iajs-1794 104 53 . . PUNCT iajs-1794 105 1 the the DET iajs-1794 105 2 solutions solution NOUN iajs-1794 105 3 of of ADP iajs-1794 105 4 cadmium cadmium NOUN iajs-1794 105 5 ( ( PUNCT iajs-1794 105 6 ii ii NOUN iajs-1794 105 7 ) ) PUNCT iajs-1794 105 8 complexes complex NOUN iajs-1794 105 9 in in ADP iajs-1794 105 10 dmso dmso NOUN iajs-1794 105 11 ( ( PUNCT iajs-1794 105 12 10 10 NUM iajs-1794 105 13 - - SYM iajs-1794 105 14 3 3 NUM iajs-1794 105 15 m m NOUN iajs-1794 105 16 ) ) PUNCT iajs-1794 105 17 recorded record VERB iajs-1794 105 18 high high ADJ iajs-1794 105 19 intensity intensity NOUN iajs-1794 105 20 peaks peak NOUN iajs-1794 105 21 around around ADP iajs-1794 105 22 390 390 NUM iajs-1794 105 23 - - SYM iajs-1794 105 24 310 310 NUM iajs-1794 105 25 and and CCONJ iajs-1794 105 26 210 210 NUM iajs-1794 105 27 - - SYM iajs-1794 105 28 244 244 NUM iajs-1794 105 29 nm nm NOUN iajs-1794 105 30 which which PRON iajs-1794 105 31 are be AUX iajs-1794 105 32 concerning concern VERB iajs-1794 105 33 with with ADP iajs-1794 105 34 the the DET iajs-1794 105 35 transitions transition NOUN iajs-1794 105 36 of of ADP iajs-1794 105 37 π π PROPN iajs-1794 105 38 - - PUNCT iajs-1794 105 39 π π PROPN iajs-1794 105 40 * * PUNCT iajs-1794 105 41 , , PUNCT iajs-1794 105 42 benzopyrazine benzopyrazine NOUN iajs-1794 105 43 bands band NOUN iajs-1794 105 44 and and CCONJ iajs-1794 105 45 ligand ligand VERB iajs-1794 105 46 to to PART iajs-1794 105 47 metal metal NOUN iajs-1794 105 48 charge charge NOUN iajs-1794 105 49 transfer transfer NOUN iajs-1794 105 50 respectively[17,19 respectively[17,19 NOUN iajs-1794 105 51 ] ] PUNCT iajs-1794 105 52 . . PUNCT iajs-1794 106 1 the the DET iajs-1794 106 2 magnetic magnetic ADJ iajs-1794 106 3 moments moment NOUN iajs-1794 106 4 of of ADP iajs-1794 106 5 the the DET iajs-1794 106 6 solid solid ADJ iajs-1794 106 7 complexes complex NOUN iajs-1794 106 8 were be AUX iajs-1794 106 9 measured measure VERB iajs-1794 106 10 by by ADP iajs-1794 106 11 farady farady PROPN iajs-1794 106 12 ’s ’s PART iajs-1794 106 13 method method NOUN iajs-1794 106 14 at at ADP iajs-1794 106 15 300 300 NUM iajs-1794 106 16 k0 k0 PROPN iajs-1794 106 17 and and CCONJ iajs-1794 106 18 the the DET iajs-1794 106 19 values value NOUN iajs-1794 106 20 observed observe VERB iajs-1794 106 21 for for ADP iajs-1794 106 22 copper(ii copper(ii NOUN iajs-1794 106 23 ) ) PUNCT iajs-1794 106 24 and and CCONJ iajs-1794 106 25 nickel(ii nickel(ii ADJ iajs-1794 106 26 ) ) PUNCT iajs-1794 106 27 complexes complex NOUN iajs-1794 106 28 were be AUX iajs-1794 106 29 ( ( PUNCT iajs-1794 106 30 1.65 1.65 NUM iajs-1794 106 31 - - SYM iajs-1794 106 32 1.80 1.80 NUM iajs-1794 106 33 ) ) PUNCT iajs-1794 106 34 and and CCONJ iajs-1794 106 35 ( ( PUNCT iajs-1794 106 36 2.80 2.80 NUM iajs-1794 106 37 - - SYM iajs-1794 106 38 2.76 2.76 NUM iajs-1794 106 39 ) ) PUNCT iajs-1794 106 40 bm bm PROPN iajs-1794 106 41 which which PRON iajs-1794 106 42 fall fall VERB iajs-1794 106 43 in in ADP iajs-1794 106 44 the the DET iajs-1794 106 45 expected expect VERB iajs-1794 106 46 of of ADP iajs-1794 106 47 one one NUM iajs-1794 106 48 and and CCONJ iajs-1794 106 49 two two NUM iajs-1794 106 50 odd odd ADJ iajs-1794 106 51 electrons electron NOUN iajs-1794 106 52 for for ADP iajs-1794 106 53 d9 d9 PROPN iajs-1794 106 54 and and CCONJ iajs-1794 106 55 d8 d8 ADJ iajs-1794 106 56 configurations configuration NOUN iajs-1794 106 57 [ [ X iajs-1794 106 58 20 20 NUM iajs-1794 106 59 ] ] PUNCT iajs-1794 106 60 . . PUNCT iajs-1794 107 1 however however ADV iajs-1794 107 2 , , PUNCT iajs-1794 107 3 the the DET iajs-1794 107 4 increased increase VERB iajs-1794 107 5 magnetic magnetic ADJ iajs-1794 107 6 susceptibility susceptibility NOUN iajs-1794 107 7 of of ADP iajs-1794 107 8 cobalt(ii cobalt(ii ADJ iajs-1794 107 9 ) ) PUNCT iajs-1794 107 10 complexes complex NOUN iajs-1794 107 11 in in ADP iajs-1794 107 12 the the DET iajs-1794 107 13 ( ( PUNCT iajs-1794 107 14 4.75 4.75 NUM iajs-1794 107 15 - - SYM iajs-1794 107 16 4.85 4.85 NUM iajs-1794 107 17 ) ) PUNCT iajs-1794 107 18 bm bm PROPN iajs-1794 107 19 region region PROPN iajs-1794 107 20 supporting support VERB iajs-1794 107 21 the the DET iajs-1794 107 22 octahedral octahedral ADJ iajs-1794 107 23 geometry geometry NOUN iajs-1794 107 24 around around ADP iajs-1794 107 25 co(ii co(ii PROPN iajs-1794 107 26 ) ) PUNCT iajs-1794 107 27 ion ion NOUN iajs-1794 107 28 due due ADP iajs-1794 107 29 to to ADP iajs-1794 107 30 orbital orbital ADJ iajs-1794 107 31 contribution contribution NOUN iajs-1794 107 32 , , PUNCT iajs-1794 107 33 table table NOUN iajs-1794 107 34 ( ( PUNCT iajs-1794 107 35 3 3 NUM iajs-1794 107 36 ) ) PUNCT iajs-1794 107 37 . . PUNCT iajs-1794 108 1 mass mass PROPN iajs-1794 108 2 spectra spectra PROPN iajs-1794 108 3 : : PUNCT iajs-1794 108 4 the the DET iajs-1794 108 5 figures figure NOUN iajs-1794 108 6 ( ( PUNCT iajs-1794 108 7 3,4 3,4 NUM iajs-1794 108 8 ) ) PUNCT iajs-1794 108 9 shows show VERB iajs-1794 108 10 the the DET iajs-1794 108 11 mass mass ADJ iajs-1794 108 12 spectra spectra NOUN iajs-1794 108 13 of of ADP iajs-1794 108 14 the the DET iajs-1794 108 15 two two NUM iajs-1794 108 16 ligands ligand NOUN iajs-1794 108 17 , , PUNCT iajs-1794 108 18 hence hence ADV iajs-1794 108 19 , , PUNCT iajs-1794 108 20 supports support VERB iajs-1794 108 21 the the DET iajs-1794 108 22 molecular molecular ADJ iajs-1794 108 23 formula formula NOUN iajs-1794 108 24 of of ADP iajs-1794 108 25 their their PRON iajs-1794 108 26 proposed propose VERB iajs-1794 108 27 structures structure NOUN iajs-1794 108 28 . . PUNCT iajs-1794 109 1 the the DET iajs-1794 109 2 mass mass ADJ iajs-1794 109 3 spectra spectra NOUN iajs-1794 109 4 of of ADP iajs-1794 109 5 the the DET iajs-1794 109 6 ligand ligand NOUN iajs-1794 109 7 ( ( PUNCT iajs-1794 109 8 l1 l1 PROPN iajs-1794 109 9 ) ) PUNCT iajs-1794 109 10 , , PUNCT iajs-1794 109 11 showed show VERB iajs-1794 109 12 the the DET iajs-1794 109 13 parent parent NOUN iajs-1794 109 14 ion ion NOUN iajs-1794 109 15 peak peak NOUN iajs-1794 109 16 at at ADP iajs-1794 109 17 ( ( PUNCT iajs-1794 109 18 m m NOUN iajs-1794 109 19 / / SYM iajs-1794 109 20 z z NOUN iajs-1794 109 21 = = NOUN iajs-1794 109 22 311 311 NUM iajs-1794 109 23 ) ) PUNCT iajs-1794 109 24 which which PRON iajs-1794 109 25 corresponded correspond VERB iajs-1794 109 26 to to ADP iajs-1794 109 27 [ [ X iajs-1794 109 28 m- m- X iajs-1794 109 29 ] ] X iajs-1794 109 30 . . PUNCT iajs-1794 110 1 other other ADJ iajs-1794 110 2 characteristic characteristic ADJ iajs-1794 110 3 peaks peak NOUN iajs-1794 110 4 were be AUX iajs-1794 110 5 assigned assign VERB iajs-1794 110 6 to to ADP iajs-1794 110 7 the the DET iajs-1794 110 8 fragments fragment NOUN iajs-1794 110 9 shown show VERB iajs-1794 110 10 in in ADP iajs-1794 110 11 scheme scheme NOUN iajs-1794 110 12 ( ( PUNCT iajs-1794 110 13 6 6 NUM iajs-1794 110 14 ) ) PUNCT iajs-1794 110 15 . . PUNCT iajs-1794 111 1 the the DET iajs-1794 111 2 mass mass ADJ iajs-1794 111 3 spectra spectra NOUN iajs-1794 111 4 of of ADP iajs-1794 111 5 ligand ligand ADJ iajs-1794 111 6 l2 l2 NOUN iajs-1794 111 7 illustrates illustrate VERB iajs-1794 111 8 the the DET iajs-1794 111 9 parent parent NOUN iajs-1794 111 10 ion ion NOUN iajs-1794 111 11 peak peak NOUN iajs-1794 111 12 at at ADP iajs-1794 111 13 at at ADP iajs-1794 111 14 m m PROPN iajs-1794 111 15 / / SYM iajs-1794 111 16 z= z= NUM iajs-1794 111 17 262 262 NUM iajs-1794 111 18 as as SCONJ iajs-1794 111 19 the the DET iajs-1794 111 20 most most ADV iajs-1794 111 21 stable stable ADJ iajs-1794 111 22 species specie NOUN iajs-1794 111 23 detected detect VERB iajs-1794 111 24 the the DET iajs-1794 111 25 other other ADJ iajs-1794 111 26 peaks peak NOUN iajs-1794 111 27 detected detect VERB iajs-1794 111 28 236 236 NUM iajs-1794 111 29 , , PUNCT iajs-1794 111 30 174 174 NUM iajs-1794 111 31 , , PUNCT iajs-1794 111 32 120 120 NUM iajs-1794 111 33 correspond correspond NOUN iajs-1794 111 34 to to ADP iajs-1794 111 35 [ [ PUNCT iajs-1794 111 36 c11 c11 NOUN iajs-1794 111 37 h14 h14 NOUN iajs-1794 111 38 n3 n3 PROPN iajs-1794 111 39 o3]+ o3]+ PROPN iajs-1794 111 40 , , PUNCT iajs-1794 112 1 [ [ X iajs-1794 112 2 c9 c9 NOUN iajs-1794 112 3 h7 h7 PROPN iajs-1794 112 4 n2 n2 PROPN iajs-1794 112 5 o2]and o2]and PROPN iajs-1794 112 6 [ [ X iajs-1794 112 7 c7h8 c7h8 X iajs-1794 112 8 n2 n2 NOUN iajs-1794 112 9 ] ] PUNCT iajs-1794 112 10 respectively respectively ADV iajs-1794 112 11 . . PUNCT iajs-1794 113 1 the the DET iajs-1794 113 2 proposed propose VERB iajs-1794 113 3 fragment fragment NOUN iajs-1794 113 4 ion ion NOUN iajs-1794 113 5 pattern pattern NOUN iajs-1794 113 6 is be AUX iajs-1794 113 7 out out ADP iajs-1794 113 8 line line NOUN iajs-1794 113 9 in in ADP iajs-1794 113 10 figure figure NOUN iajs-1794 113 11 ( ( PUNCT iajs-1794 113 12 4 4 NUM iajs-1794 113 13 ) ) PUNCT iajs-1794 113 14 . . PUNCT iajs-1794 114 1 ihsciconf ihsciconf PROPN iajs-1794 114 2 2017 2017 NUM iajs-1794 114 3 special special ADJ iajs-1794 114 4 issue issue NOUN iajs-1794 114 5 ibn ibn PROPN iajs-1794 114 6 al al PROPN iajs-1794 114 7 - - PUNCT iajs-1794 114 8 haitham haitham PROPN iajs-1794 114 9 journal journal PROPN iajs-1794 114 10 for for ADP iajs-1794 114 11 pure pure ADJ iajs-1794 114 12 and and CCONJ iajs-1794 114 13 applied apply VERB iajs-1794 114 14 science science NOUN iajs-1794 114 15 https:// https:// PROPN iajs-1794 114 16 doi.org/ doi.org/ ADP iajs-1794 114 17 10.30526/2017.ihsciconf.1794 10.30526/2017.ihsciconf.1794 NOUN iajs-1794 114 18 for for ADP iajs-1794 114 19 more more ADJ iajs-1794 114 20 information information NOUN iajs-1794 114 21 about about ADP iajs-1794 114 22 the the DET iajs-1794 114 23 conference conference NOUN iajs-1794 114 24 please please INTJ iajs-1794 114 25 visit visit VERB iajs-1794 114 26 the the DET iajs-1794 114 27 websites website NOUN iajs-1794 114 28 : : PUNCT iajs-1794 114 29 http://www.ihsciconf.org/conf/ http://www.ihsciconf.org/conf/ VERB iajs-1794 114 30     SPACE iajs-1794 114 31 www.ihsciconf.org www.ihsciconf.org ADV iajs-1794 114 32       SPACE iajs-1794 114 33 chemistry|212 chemistry|212 NOUN iajs-1794 114 34         SPACE iajs-1794 114 35 n n PROPN iajs-1794 114 36 h h NOUN iajs-1794 114 37 nh nh PROPN iajs-1794 114 38 2 2 NUM iajs-1794 114 39 o o NOUN iajs-1794 114 40 o o NOUN iajs-1794 114 41 n n CCONJ iajs-1794 114 42 n n NOUN iajs-1794 114 43 h h NOUN iajs-1794 115 1 o o NOUN iajs-1794 115 2 n n CCONJ iajs-1794 115 3 h h NOUN iajs-1794 115 4 nh nh PROPN iajs-1794 115 5 2 2 NUM iajs-1794 115 6 n n NUM iajs-1794 115 7 n n NOUN iajs-1794 115 8 . . PUNCT iajs-1794 116 1 o o INTJ iajs-1794 116 2 o o INTJ iajs-1794 116 3 -nh -nh ADP iajs-1794 116 4 2 2 NUM iajs-1794 116 5 , , PUNCT iajs-1794 116 6 c c PROPN iajs-1794 116 7 = = X iajs-1794 116 8 o o X iajs-1794 116 9 -44 -44 PROPN iajs-1794 116 10 m m PROPN iajs-1794 116 11 / / SYM iajs-1794 116 12 z= z= PROPN iajs-1794 116 13 311 311 NUM iajs-1794 116 14 m m PROPN iajs-1794 116 15 / / SYM iajs-1794 116 16 z=266 z=266 NUM iajs-1794 116 17 . . PUNCT iajs-1794 117 1 n n PRON iajs-1794 117 2 nnh nnh ADJ iajs-1794 117 3 o o PROPN iajs-1794 117 4 m/ m/ NOUN iajs-1794 117 5 z z NOUN iajs-1794 118 1 = = NOUN iajs-1794 118 2 239 239 NUM iajs-1794 118 3 -nh -nh ADP iajs-1794 118 4 2 2 NUM iajs-1794 118 5 , , PUNCT iajs-1794 118 6 2 2 NUM iajs-1794 118 7 ( ( PUNCT iajs-1794 118 8 c= c= NOUN iajs-1794 118 9 o o NOUN iajs-1794 118 10 ) ) PUNCT iajs-1794 118 11 -72 -72 PUNCT iajs-1794 119 1 o o NOUN iajs-1794 119 2 n n CCONJ iajs-1794 119 3 n n NOUN iajs-1794 119 4 h h NOUN iajs-1794 120 1 o o X iajs-1794 120 2 o o X iajs-1794 120 3 m m NOUN iajs-1794 120 4 / / SYM iajs-1794 120 5 z z PROPN iajs-1794 120 6 = = NUM iajs-1794 120 7 204.4 204.4 NUM iajs-1794 120 8 -106 -106 NUM iajs-1794 120 9 c c NOUN iajs-1794 120 10 6h 6h NOUN iajs-1794 120 11 6n 6n NOUN iajs-1794 120 12 2 2 NUM iajs-1794 120 13 o o NOUN iajs-1794 120 14 n n NOUN iajs-1794 120 15 . . PUNCT iajs-1794 121 1 n n X iajs-1794 121 2 . . PUNCT iajs-1794 122 1 o o NOUN iajs-1794 122 2 m m PROPN iajs-1794 122 3 / / SYM iajs-1794 122 4 z=159.2 z=159.2 PROPN iajs-1794 122 5 45n 45n NOUN iajs-1794 122 6 . . PUNCT iajs-1794 123 1 n n X iajs-1794 123 2 . . PUNCT iajs-1794 124 1 m m PROPN iajs-1794 124 2 / / SYM iajs-1794 124 3 z=104 z=104 PROPN iajs-1794 124 4 -56 -56 NUM iajs-1794 124 5 2 2 X iajs-1794 124 6 ( ( PUNCT iajs-1794 124 7 -c -c PROPN iajs-1794 124 8 = = NOUN iajs-1794 124 9 o o NOUN iajs-1794 124 10 ) ) PUNCT iajs-1794 125 1 + + NUM iajs-1794 125 2 c c NOUN iajs-1794 125 3 2h 2h NUM iajs-1794 125 4 5o 5o PROPN iajs-1794 125 5 scheme scheme NOUN iajs-1794 125 6 ( ( PUNCT iajs-1794 125 7 6 6 NUM iajs-1794 125 8 ): ): PUNCT iajs-1794 125 9 other other ADJ iajs-1794 125 10 synthesis synthesis NOUN iajs-1794 125 11 thermal thermal ADJ iajs-1794 125 12 analysis analysis NOUN iajs-1794 125 13 : : PUNCT iajs-1794 125 14 the the DET iajs-1794 125 15 thermal thermal ADJ iajs-1794 125 16 degradation degradation NOUN iajs-1794 125 17 of of ADP iajs-1794 125 18 cobalt(ii cobalt(ii PROPN iajs-1794 125 19 ) ) PUNCT iajs-1794 125 20 of of ADP iajs-1794 125 21 l1 l1 PROPN iajs-1794 125 22 ligand ligand PROPN iajs-1794 125 23 and and CCONJ iajs-1794 125 24 nickel(ii nickel(ii PROPN iajs-1794 125 25 ) ) PUNCT iajs-1794 125 26 of of ADP iajs-1794 125 27 l2 l2 NOUN iajs-1794 125 28 complexes complex NOUN iajs-1794 125 29 was be AUX iajs-1794 125 30 studied study VERB iajs-1794 125 31 by by ADP iajs-1794 125 32 thermo thermo NOUN iajs-1794 125 33 gravimetric gravimetric ADJ iajs-1794 125 34 analysis analysis NOUN iajs-1794 125 35 ( ( PUNCT iajs-1794 125 36 tg tg INTJ iajs-1794 125 37 ) ) PUNCT iajs-1794 125 38 from from ADP iajs-1794 125 39 ambient ambient ADJ iajs-1794 125 40 temperature temperature NOUN iajs-1794 125 41 to to ADP iajs-1794 125 42 600 600 NUM iajs-1794 125 43 ° ° NOUN iajs-1794 125 44 c c NOUN iajs-1794 125 45 . . PUNCT iajs-1794 126 1 while while SCONJ iajs-1794 126 2 the the DET iajs-1794 126 3 thermal thermal ADJ iajs-1794 126 4 degradation degradation NOUN iajs-1794 126 5 of of ADP iajs-1794 126 6 nickel(ii nickel(ii NOUN iajs-1794 126 7 ) ) PUNCT iajs-1794 126 8 and and CCONJ iajs-1794 126 9 copper(ii copper(ii PROPN iajs-1794 126 10 ) ) PUNCT iajs-1794 126 11 of of ADP iajs-1794 126 12 ligand ligand NOUN iajs-1794 127 1 [ [ X iajs-1794 127 2 l1 l1 X iajs-1794 127 3 ] ] PUNCT iajs-1794 127 4 and and CCONJ iajs-1794 127 5 cobalt(ii cobalt(ii PROPN iajs-1794 127 6 ) ) PUNCT iajs-1794 127 7 of of ADP iajs-1794 127 8 [ [ X iajs-1794 127 9 l2 l2 NOUN iajs-1794 127 10 ] ] PUNCT iajs-1794 127 11 ligand ligand NOUN iajs-1794 127 12 at at ADP iajs-1794 127 13 3550c 3550c NUM iajs-1794 127 14 . . PUNCT iajs-1794 128 1 the the DET iajs-1794 128 2 data datum NOUN iajs-1794 128 3 from from ADP iajs-1794 128 4 the the DET iajs-1794 128 5 thermo thermo NOUN iajs-1794 128 6 gravimetric gravimetric ADJ iajs-1794 128 7 analysis analysis NOUN iajs-1794 128 8 clearly clearly ADV iajs-1794 128 9 indicated indicate VERB iajs-1794 128 10 that that SCONJ iajs-1794 128 11 the the DET iajs-1794 128 12 decomposition decomposition NOUN iajs-1794 128 13 of of ADP iajs-1794 128 14 the the DET iajs-1794 128 15 complexes complex NOUN iajs-1794 128 16 proceeds proceed VERB iajs-1794 128 17 in in ADP iajs-1794 128 18 four four NUM iajs-1794 128 19 or or CCONJ iajs-1794 128 20 five five NUM iajs-1794 128 21 steps step NOUN iajs-1794 128 22 . . PUNCT iajs-1794 129 1 the the DET iajs-1794 129 2 losing losing NOUN iajs-1794 129 3 of of ADP iajs-1794 129 4 hydrated hydrated ADJ iajs-1794 129 5 water water NOUN iajs-1794 129 6 molecules molecule NOUN iajs-1794 129 7 was be AUX iajs-1794 129 8 investigated investigate VERB iajs-1794 129 9 from from ADP iajs-1794 129 10 the the DET iajs-1794 129 11 exothermic exothermic ADJ iajs-1794 129 12 peak peak NOUN iajs-1794 129 13 around around ADP iajs-1794 129 14 50 50 NUM iajs-1794 129 15 250 250 NUM iajs-1794 129 16 ° ° ADP iajs-1794 129 17 c c NOUN iajs-1794 129 18 temperature temperature NOUN iajs-1794 129 19 hence hence ADV iajs-1794 129 20 , , PUNCT iajs-1794 129 21 the the DET iajs-1794 129 22 formation formation NOUN iajs-1794 129 23 of of ADP iajs-1794 129 24 copper copper NOUN iajs-1794 129 25 oxide oxide NOUN iajs-1794 129 26 cuo cuo PROPN iajs-1794 129 27 was be AUX iajs-1794 129 28 residue residue ADJ iajs-1794 129 29 above above ADP iajs-1794 129 30 600 600 NUM iajs-1794 129 31 ° ° NOUN iajs-1794 129 32 c c NOUN iajs-1794 129 33 , , PUNCT iajs-1794 129 34 figure figure NOUN iajs-1794 129 35 ( ( PUNCT iajs-1794 129 36 5,6 5,6 NUM iajs-1794 129 37 ) ) PUNCT iajs-1794 129 38 . . PUNCT iajs-1794 130 1 for for ADP iajs-1794 130 2 these these DET iajs-1794 130 3 complexes complex NOUN iajs-1794 130 4 , , PUNCT iajs-1794 130 5 the the DET iajs-1794 130 6 removal removal NOUN iajs-1794 130 7 of of ADP iajs-1794 130 8 water water NOUN iajs-1794 130 9 can can AUX iajs-1794 130 10 proceed proceed VERB iajs-1794 130 11 in in ADP iajs-1794 130 12 one one NUM iajs-1794 130 13 or or CCONJ iajs-1794 130 14 two two NUM iajs-1794 130 15 steps step NOUN iajs-1794 130 16 [ [ X iajs-1794 130 17 17,18 17,18 X iajs-1794 130 18 ] ] PUNCT iajs-1794 130 19 . . PUNCT iajs-1794 131 1 all all DET iajs-1794 131 2 complexes complex NOUN iajs-1794 131 3 lost lose VERB iajs-1794 131 4 hydration hydration NOUN iajs-1794 131 5 water water NOUN iajs-1794 131 6 between between ADP iajs-1794 131 7 50 50 NUM iajs-1794 131 8 and and CCONJ iajs-1794 131 9 120 120 NUM iajs-1794 131 10 ° ° NOUN iajs-1794 131 11 c c NOUN iajs-1794 131 12 , , PUNCT iajs-1794 131 13 and and CCONJ iajs-1794 131 14 then then ADV iajs-1794 131 15 the the DET iajs-1794 131 16 coordinated coordinated ADJ iajs-1794 131 17 water water NOUN iajs-1794 131 18 molecule molecule NOUN iajs-1794 131 19 was be AUX iajs-1794 131 20 lost lose VERB iajs-1794 131 21 above above ADP iajs-1794 131 22 ≥200 ≥200 NOUN iajs-1794 131 23 ° ° PROPN iajs-1794 131 24 . . PUNCT iajs-1794 132 1 the the DET iajs-1794 132 2 decomposition decomposition NOUN iajs-1794 132 3 was be AUX iajs-1794 132 4 complete complete ADJ iajs-1794 132 5 at at ADP iajs-1794 132 6 350 350 NUM iajs-1794 132 7 - - SYM iajs-1794 132 8 600 600 NUM iajs-1794 132 9 ° ° ADP iajs-1794 132 10 c c NOUN iajs-1794 132 11 for for ADP iajs-1794 132 12 all all DET iajs-1794 132 13 complexes complex NOUN iajs-1794 132 14 . . PUNCT iajs-1794 133 1 furthermore furthermore ADV iajs-1794 133 2 , , PUNCT iajs-1794 133 3 the the DET iajs-1794 133 4 dsc dsc NOUN iajs-1794 133 5 analysis analysis NOUN iajs-1794 133 6 of of ADP iajs-1794 133 7 nickel(ii nickel(ii NOUN iajs-1794 133 8 ) ) PUNCT iajs-1794 133 9 complexes complex NOUN iajs-1794 133 10 showed show VERB iajs-1794 133 11 the the DET iajs-1794 133 12 stability stability NOUN iajs-1794 133 13 of of ADP iajs-1794 133 14 complexes complex NOUN iajs-1794 133 15 in in ADP iajs-1794 133 16 inert inert ADJ iajs-1794 133 17 helium helium NOUN iajs-1794 133 18 gas gas NOUN iajs-1794 133 19 and and CCONJ iajs-1794 133 20 the the DET iajs-1794 133 21 peaks peak NOUN iajs-1794 133 22 as as ADP iajs-1794 133 23 exothermic exothermic ADJ iajs-1794 133 24 were be AUX iajs-1794 133 25 very very ADV iajs-1794 133 26 important important ADJ iajs-1794 133 27 to to PART iajs-1794 133 28 estimate estimate VERB iajs-1794 133 29 some some DET iajs-1794 133 30 thermodynamic thermodynamic ADJ iajs-1794 133 31 terms term NOUN iajs-1794 133 32 like like ADP iajs-1794 133 33 entropy entropy NOUN iajs-1794 133 34 , , PUNCT iajs-1794 133 35 enthalpy enthalpy NOUN iajs-1794 133 36 and and CCONJ iajs-1794 133 37 gibbs gibbs PROPN iajs-1794 133 38 - - PUNCT iajs-1794 133 39 free free ADJ iajs-1794 133 40 energy energy NOUN iajs-1794 133 41 [ [ X iajs-1794 133 42 18,21 18,21 NUM iajs-1794 133 43 ] ] PUNCT iajs-1794 133 44 . . PUNCT iajs-1794 134 1 the the DET iajs-1794 134 2 activation activation NOUN iajs-1794 134 3 energy energy NOUN iajs-1794 134 4 e e NOUN iajs-1794 134 5 * * NOUN iajs-1794 134 6 of of ADP iajs-1794 134 7 the the DET iajs-1794 134 8 thermal thermal ADJ iajs-1794 134 9 behavior behavior NOUN iajs-1794 134 10 of of ADP iajs-1794 134 11 the the DET iajs-1794 134 12 copper copper NOUN iajs-1794 134 13 ( ( PUNCT iajs-1794 134 14 ii ii NOUN iajs-1794 134 15 ) ) PUNCT iajs-1794 134 16 , , PUNCT iajs-1794 134 17 and and CCONJ iajs-1794 134 18 nickel nickel NOUN iajs-1794 134 19 ( ( PUNCT iajs-1794 134 20 ii ii NOUN iajs-1794 134 21 ) ) PUNCT iajs-1794 134 22 complexes complex NOUN iajs-1794 134 23 , , PUNCT iajs-1794 134 24 figures figure NOUN iajs-1794 134 25 ( ( PUNCT iajs-1794 134 26 5 5 NUM iajs-1794 134 27 - - SYM iajs-1794 134 28 9 9 NUM iajs-1794 134 29 ) ) PUNCT iajs-1794 134 30 . . PUNCT iajs-1794 135 1 the the PRON iajs-1794 135 2 in in ADP iajs-1794 135 3 the the DET iajs-1794 135 4 different different ADJ iajs-1794 135 5 stages stage NOUN iajs-1794 135 6 is be AUX iajs-1794 135 7 in in ADP iajs-1794 135 8 the the DET iajs-1794 135 9 range range NOUN iajs-1794 135 10 of of ADP iajs-1794 135 11 31.14–333.95 31.14–333.95 NOUN iajs-1794 135 12 kjmol‒1 kjmol‒1 NOUN iajs-1794 135 13 may may AUX iajs-1794 135 14 agree agree VERB iajs-1794 135 15 with with ADP iajs-1794 135 16 their their PRON iajs-1794 135 17 stability stability NOUN iajs-1794 135 18 in in ADP iajs-1794 135 19 air air NOUN iajs-1794 135 20 and and CCONJ iajs-1794 135 21 their their PRON iajs-1794 135 22 spontaneous spontaneous ADJ iajs-1794 135 23 preparation preparation NOUN iajs-1794 135 24 in in ADP iajs-1794 135 25 the the DET iajs-1794 135 26 solid solid ADJ iajs-1794 135 27 state state NOUN iajs-1794 135 28 . . PUNCT iajs-1794 136 1 ihsciconf ihsciconf PROPN iajs-1794 136 2 2017 2017 NUM iajs-1794 136 3 special special ADJ iajs-1794 136 4 issue issue NOUN iajs-1794 136 5 ibn ibn PROPN iajs-1794 136 6 al al PROPN iajs-1794 136 7 - - PUNCT iajs-1794 136 8 haitham haitham PROPN iajs-1794 136 9 journal journal PROPN iajs-1794 136 10 for for ADP iajs-1794 136 11 pure pure ADJ iajs-1794 136 12 and and CCONJ iajs-1794 136 13 applied apply VERB iajs-1794 136 14 science science NOUN iajs-1794 136 15 https:// https:// PROPN iajs-1794 136 16 doi.org/ doi.org/ ADP iajs-1794 136 17 10.30526/2017.ihsciconf.1794 10.30526/2017.ihsciconf.1794 NOUN iajs-1794 136 18 for for ADP iajs-1794 136 19 more more ADJ iajs-1794 136 20 information information NOUN iajs-1794 136 21 about about ADP iajs-1794 136 22 the the DET iajs-1794 136 23 conference conference NOUN iajs-1794 136 24 please please INTJ iajs-1794 136 25 visit visit VERB iajs-1794 136 26 the the DET iajs-1794 136 27 websites website NOUN iajs-1794 136 28 : : PUNCT iajs-1794 136 29 http://www.ihsciconf.org/conf/ http://www.ihsciconf.org/conf/ VERB iajs-1794 136 30     SPACE iajs-1794 136 31 www.ihsciconf.org www.ihsciconf.org ADJ iajs-1794 136 32       SPACE iajs-1794 136 33 chemistry|213 chemistry|213 NOUN iajs-1794 136 34         SPACE iajs-1794 136 35 table table NOUN iajs-1794 136 36 ( ( PUNCT iajs-1794 136 37 1 1 NUM iajs-1794 136 38 ): ): PUNCT iajs-1794 136 39 physical physical ADJ iajs-1794 136 40 properties property NOUN iajs-1794 136 41 and and CCONJ iajs-1794 136 42 elemental elemental ADJ iajs-1794 136 43 analysis analysis NOUN iajs-1794 136 44 of of ADP iajs-1794 136 45 the the DET iajs-1794 136 46 prepared prepared ADJ iajs-1794 136 47 ligand ligand NOUN iajs-1794 136 48 l1and l1and PROPN iajs-1794 136 49 l2 l2 PROPN iajs-1794 136 50 and and CCONJ iajs-1794 136 51 their their PRON iajs-1794 136 52 metal metal NOUN iajs-1794 136 53 complexes complex NOUN iajs-1794 136 54 . . PUNCT iajs-1794 137 1 compound compound VERB iajs-1794 137 2 mwt mwt PROPN iajs-1794 137 3 colour colour PROPN iajs-1794 137 4 m.p m.p PROPN iajs-1794 137 5 . . PROPN iajs-1794 137 6 0c 0c PROPN iajs-1794 137 7 elemental elemental ADJ iajs-1794 137 8 analysis analysis NOUN iajs-1794 137 9 ( ( PUNCT iajs-1794 137 10 found find VERB iajs-1794 137 11 ) ) PUNCT iajs-1794 137 12 calculate calculate NOUN iajs-1794 137 13 % % NOUN iajs-1794 137 14 10 10 NUM iajs-1794 137 15 - - SYM iajs-1794 137 16 3 3 NUM iajs-1794 137 17 m m NOUN iajs-1794 137 18 dmsoλ dmsoλ NOUN iajs-1794 137 19 ohm-1cm2 ohm-1cm2 NOUN iajs-1794 137 20 mol-1 mol-1 PUNCT iajs-1794 137 21 c c NOUN iajs-1794 137 22 h h NOUN iajs-1794 137 23 n n NOUN iajs-1794 137 24 m m PROPN iajs-1794 137 25 cl cl NOUN iajs-1794 137 26 l1 l1 PROPN iajs-1794 137 27 ( ( PUNCT iajs-1794 137 28 c16h14n4o3 c16h14n4o3 PROPN iajs-1794 137 29 ) ) PUNCT iajs-1794 137 30 310 310 NUM iajs-1794 137 31 beige beige NOUN iajs-1794 137 32 198 198 NUM iajs-1794 137 33 ( ( PUNCT iajs-1794 137 34 60.69 60.69 NUM iajs-1794 137 35 ) ) PUNCT iajs-1794 137 36 61.93 61.93 NUM iajs-1794 137 37 ( ( PUNCT iajs-1794 137 38 4.21 4.21 NUM iajs-1794 137 39 ) ) PUNCT iajs-1794 137 40 4.55 4.55 NUM iajs-1794 137 41 ( ( PUNCT iajs-1794 137 42 18.4 18.4 NUM iajs-1794 137 43 ) ) PUNCT iajs-1794 137 44 18.06 18.06 NUM iajs-1794 137 45 [ [ X iajs-1794 137 46 co(l1 co(l1 NOUN iajs-1794 137 47 ) ) PUNCT iajs-1794 137 48 cl2 cl2 NOUN iajs-1794 137 49 ] ] X iajs-1794 137 50 h2o h2o PROPN iajs-1794 137 51 ( ( PUNCT iajs-1794 137 52 c32h30n8o7cl2 c32h30n8o7cl2 X iajs-1794 137 53 co co NOUN iajs-1794 137 54 ) ) PUNCT iajs-1794 137 55 768 768 NUM iajs-1794 137 56 red red ADJ iajs-1794 137 57 brown brown NOUN iajs-1794 137 58 > > X iajs-1794 137 59 300dec 300dec NUM iajs-1794 137 60 ( ( PUNCT iajs-1794 137 61 49.53 49.53 NUM iajs-1794 137 62 ) ) PUNCT iajs-1794 137 63 50.01 50.01 NUM iajs-1794 137 64 ( ( PUNCT iajs-1794 137 65 3.78 3.78 NUM iajs-1794 137 66 ) ) PUNCT iajs-1794 137 67 3.93 3.93 NUM iajs-1794 137 68 ( ( PUNCT iajs-1794 137 69 14.69 14.69 NUM iajs-1794 137 70 ) ) PUNCT iajs-1794 137 71 14.58 14.58 NUM iajs-1794 137 72 ( ( PUNCT iajs-1794 137 73 8.72 8.72 NUM iajs-1794 137 74 ) ) PUNCT iajs-1794 137 75 7.67 7.67 NUM iajs-1794 137 76 ( ( PUNCT iajs-1794 137 77 8.56 8.56 NUM iajs-1794 137 78 ) ) PUNCT iajs-1794 137 79 9.23 9.23 NUM iajs-1794 137 80 41 41 NUM iajs-1794 138 1 [ [ X iajs-1794 138 2 ni ni INTJ iajs-1794 138 3 ( ( PUNCT iajs-1794 138 4 l1)2cl2 l1)2cl2 PROPN iajs-1794 138 5 ] ] X iajs-1794 138 6 ( ( PUNCT iajs-1794 138 7 c32h28n8o6cl2 c32h28n8o6cl2 X iajs-1794 138 8 ni ni NOUN iajs-1794 138 9 ) ) PUNCT iajs-1794 138 10 768 768 NUM iajs-1794 138 11 dark dark ADJ iajs-1794 138 12 green green ADJ iajs-1794 138 13 > > X iajs-1794 138 14 272dec 272dec NUM iajs-1794 138 15 ( ( PUNCT iajs-1794 138 16 48.75 48.75 NUM iajs-1794 138 17 ) ) PUNCT iajs-1794 138 18 51.23 51.23 NUM iajs-1794 138 19 ( ( PUNCT iajs-1794 138 20 3.73 3.73 NUM iajs-1794 138 21 ) ) PUNCT iajs-1794 138 22 3.76 3.76 NUM iajs-1794 138 23 ( ( PUNCT iajs-1794 138 24 15.22 15.22 NUM iajs-1794 138 25 ) ) PUNCT iajs-1794 138 26 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PUNCT iajs-1794 187 1 mayadevi mayadevi PROPN iajs-1794 187 2 ; ; PUNCT iajs-1794 187 3 s.yusuff s.yusuff NOUN iajs-1794 187 4 , , PUNCT iajs-1794 187 5 k.k.m k.k.m PROPN iajs-1794 187 6 . . PUNCT iajs-1794 187 7 synthesis synthesis NOUN iajs-1794 187 8 and and CCONJ iajs-1794 187 9 reactivity reactivity NOUN iajs-1794 187 10 in in ADP iajs-1794 187 11 inorganic inorganic ADJ iajs-1794 187 12 and and CCONJ iajs-1794 187 13 metalorganic metalorganic ADJ iajs-1794 187 14 chemistry chemistry NOUN iajs-1794 187 15 . . PUNCT iajs-1794 187 16 , , PUNCT iajs-1794 187 17 27 27 NUM iajs-1794 187 18 , , PUNCT iajs-1794 187 19 319 319 NUM iajs-1794 187 20 - - SYM iajs-1794 187 21 324 324 NUM iajs-1794 187 22 . . PUNCT iajs-1794 188 1 1997 1997 NUM iajs-1794 189 1 [ [ X iajs-1794 189 2 8 8 NUM iajs-1794 189 3 ] ] PUNCT iajs-1794 189 4 . . PUNCT iajs-1794 190 1 v. v. PROPN iajs-1794 190 2 k. k. PROPN iajs-1794 190 3 naveen naveen PROPN iajs-1794 190 4 ; ; PUNCT iajs-1794 190 5 s. s. 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NOUN iajs-1794 191 10 hugar hugar NOUN iajs-1794 191 11 , , PUNCT iajs-1794 191 12 ” " PUNCT iajs-1794 191 13 transition transition NOUN iajs-1794 191 14 metal metal NOUN iajs-1794 191 15 complexes complex NOUN iajs-1794 191 16 of of ADP iajs-1794 191 17 thiosemicarbazone thiosemicarbazone NOUN iajs-1794 191 18 with with ADP iajs-1794 191 19 quinoxaline quinoxaline PROPN iajs-1794 191 20 hub hub PROPN iajs-1794 191 21 : : PUNCT iajs-1794 191 22 an an DET iajs-1794 191 23 emphasis emphasis NOUN iajs-1794 191 24 on on ADP iajs-1794 191 25 antidiabetic antidiabetic ADJ iajs-1794 191 26 property property NOUN iajs-1794 191 27 ” " PUNCT iajs-1794 191 28 med.chem.res med.chem.re NOUN iajs-1794 191 29 . . PUNCT iajs-1794 192 1 ,21,663 ,21,663 NOUN iajs-1794 192 2 - - PUNCT iajs-1794 192 3 671 671 NUM iajs-1794 192 4 . . PUNCT iajs-1794 193 1 2012 2012 NUM iajs-1794 194 1 [ [ X iajs-1794 194 2 9 9 NUM iajs-1794 194 3 ] ] PUNCT iajs-1794 194 4 . . PUNCT iajs-1794 195 1 n.a n.a PROPN iajs-1794 195 2 . . PROPN iajs-1794 195 3 mahmoud mahmoud PROPN iajs-1794 195 4 , , PUNCT iajs-1794 195 5 eur.chem.bull eur.chem.bull PROPN iajs-1794 195 6 . . NOUN iajs-1794 195 7 2014,3(4 2014,3(4 NOUN iajs-1794 195 8 ) ) PUNCT iajs-1794 195 9 , , PUNCT iajs-1794 195 10 384 384 NUM iajs-1794 195 11 - - SYM iajs-1794 195 12 389 389 NUM iajs-1794 195 13 . . PUNCT iajs-1794 196 1 [ [ X iajs-1794 196 2 10 10 NUM iajs-1794 196 3 ] ] PUNCT iajs-1794 196 4 . . PUNCT iajs-1794 197 1 e. e. PROPN iajs-1794 197 2 afnan afnan PROPN iajs-1794 197 3 , , PUNCT iajs-1794 197 4 abdul.munim abdul.munim PROPN iajs-1794 197 5 , , PUNCT iajs-1794 197 6 m.sc m.sc PROPN iajs-1794 197 7 . . PUNCT iajs-1794 198 1 thesis thesis PROPN iajs-1794 198 2 , , PUNCT iajs-1794 198 3 mustansiriya mustansiriya PROPN iajs-1794 198 4 university university NOUN iajs-1794 198 5 , , PUNCT iajs-1794 198 6 college college NOUN iajs-1794 198 7 of of ADP iajs-1794 198 8 science,2013 science,2013 NOUN iajs-1794 198 9 . . PUNCT iajs-1794 199 1 [ [ X iajs-1794 199 2 11 11 NUM iajs-1794 199 3 ] ] PUNCT iajs-1794 199 4 . . PUNCT iajs-1794 200 1 i.k i.k PROPN iajs-1794 200 2 . . PROPN iajs-1794 200 3 , , PUNCT iajs-1794 200 4 chung chung PROPN iajs-1794 200 5 ; ; PUNCT iajs-1794 201 1 j.h j.h PROPN iajs-1794 201 2 . . PROPN iajs-1794 201 3 kim kim PROPN iajs-1794 201 4 ; ; PUNCT iajs-1794 201 5 s.w s.w PROPN iajs-1794 201 6 . . PROPN iajs-1794 201 7 kim kim PROPN iajs-1794 201 8 , , PUNCT iajs-1794 201 9 and and CCONJ iajs-1794 201 10 g.e g.e PROPN iajs-1794 201 11 . . PROPN iajs-1794 201 12 lee lee PROPN iajs-1794 201 13 , , PUNCT iajs-1794 201 14 , , PUNCT iajs-1794 201 15 identification identification NOUN iajs-1794 201 16 of of ADP iajs-1794 201 17 a a DET iajs-1794 201 18 quinoxaline quinoxaline ADJ iajs-1794 201 19 derivative derivative NOUN iajs-1794 201 20 that that PRON iajs-1794 201 21 is be AUX iajs-1794 201 22 a a DET iajs-1794 201 23 potent potent ADJ iajs-1794 201 24 telomerase telomerase NOUN iajs-1794 201 25 inhibitor inhibitor NOUN iajs-1794 201 26 leading lead VERB iajs-1794 201 27 to to ADP iajs-1794 201 28 cellular cellular ADJ iajs-1794 201 29 senescence senescence NOUN iajs-1794 201 30 of of ADP iajs-1794 201 31 human human ADJ iajs-1794 201 32 cancer cancer NOUN iajs-1794 201 33 cells.biochem cells.biochem PROPN iajs-1794 201 34 . . PUNCT iajs-1794 202 1 j j PROPN iajs-1794 202 2 , , PUNCT iajs-1794 202 3 373 373 NUM iajs-1794 202 4 , , PUNCT iajs-1794 202 5 523 523 NUM iajs-1794 202 6 - - SYM iajs-1794 202 7 529 529 NUM iajs-1794 202 8 . . PUNCT iajs-1794 202 9 , , PUNCT iajs-1794 202 10 2003 2003 NUM iajs-1794 203 1 [ [ X iajs-1794 203 2 12 12 NUM iajs-1794 203 3 ] ] PUNCT iajs-1794 203 4 . . PUNCT iajs-1794 204 1 a. a. PROPN iajs-1794 204 2 mahmoud mahmoud PROPN iajs-1794 204 3 ; ; PUNCT iajs-1794 204 4 m.k.youssef m.k.youssef NOUN iajs-1794 204 5 , , PUNCT iajs-1794 204 6 " " PUNCT iajs-1794 204 7 use use NOUN iajs-1794 204 8 of of ADP iajs-1794 204 9 modern modern ADJ iajs-1794 204 10 technique technique NOUN iajs-1794 204 11 for for ADP iajs-1794 204 12 synthesis synthesis NOUN iajs-1794 204 13 of of ADP iajs-1794 204 14 quinoxaline quinoxaline ADJ iajs-1794 204 15 derivatives derivative NOUN iajs-1794 204 16 as as ADP iajs-1794 204 17 potential potential ADJ iajs-1794 204 18 anti anti ADJ iajs-1794 204 19 - - ADJ iajs-1794 204 20 virus virus NOUN iajs-1794 204 21 compounds compound NOUN iajs-1794 204 22 " " PUNCT iajs-1794 204 23 der der ADJ iajs-1794 204 24 pharma pharma PROPN iajs-1794 204 25 chemica chemica PROPN iajs-1794 204 26 , , PUNCT iajs-1794 204 27 , , PUNCT iajs-1794 204 28 4(3 4(3 NUM iajs-1794 204 29 ) ) PUNCT iajs-1794 204 30 , , PUNCT iajs-1794 204 31 1323 1323 NUM iajs-1794 204 32 - - SYM iajs-1794 204 33 1329 1329 NUM iajs-1794 204 34 . . 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PROPN iajs-1794 215 25 bonnet bonnet NOUN iajs-1794 215 26 , , PUNCT iajs-1794 215 27 “ " PUNCT iajs-1794 215 28 new new ADJ iajs-1794 215 29 imidazo imidazo NOUN iajs-1794 215 30 [ [ X iajs-1794 215 31 1 1 NUM iajs-1794 215 32 , , PUNCT iajs-1794 215 33 2 2 NUM iajs-1794 215 34 - - PUNCT iajs-1794 215 35 a]quinoxaline a]quinoxaline PRON iajs-1794 215 36 derivatives derivative NOUN iajs-1794 215 37 : : PUNCT iajs-1794 215 38 synthesis synthesis NOUN iajs-1794 215 39 and and CCONJ iajs-1794 215 40 in in ADP iajs-1794 215 41 vitro vitro X iajs-1794 215 42 activity activity NOUN iajs-1794 215 43 against against ADP iajs-1794 215 44 human human ADJ iajs-1794 215 45 melanoma melanoma NOUN iajs-1794 215 46 ” " PUNCT iajs-1794 215 47 . . PUNCT iajs-1794 216 1 eur eur PROPN iajs-1794 216 2 j j PROPN iajs-1794 216 3 med med PROPN iajs-1794 216 4 chem chem NOUN iajs-1794 216 5 . . 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PROPN iajs-1794 219 7 koch koch PROPN iajs-1794 219 8 , , PUNCT iajs-1794 219 9 “ " PUNCT iajs-1794 219 10 absolute absolute ADJ iajs-1794 219 11 determination determination NOUN iajs-1794 219 12 of of ADP iajs-1794 219 13 electrolytic electrolytic ADJ iajs-1794 219 14 conductivity conductivity NOUN iajs-1794 219 15 for for ADP iajs-1794 219 16 primary primary ADJ iajs-1794 219 17 standard standard ADJ iajs-1794 219 18 kcl kcl PROPN iajs-1794 219 19 solutions solution NOUN iajs-1794 219 20 from from ADP iajs-1794 219 21 0 0 NUM iajs-1794 219 22 to to ADP iajs-1794 219 23 50 50 NUM iajs-1794 219 24 8c 8c NOUN iajs-1794 219 25 ” " PUNCT iajs-1794 219 26 , , PUNCT iajs-1794 219 27 j. j. PROPN iajs-1794 219 28 soln soln PROPN iajs-1794 219 29 . . PUNCT iajs-1794 220 1 chem chem PROPN iajs-1794 220 2 . . 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PUNCT iajs-1794 224 1 spectrosc spectrosc PROPN iajs-1794 224 2 lett lett PROPN iajs-1794 224 3 2010 2010 NUM iajs-1794 224 4 , , PUNCT iajs-1794 224 5 43 43 NUM iajs-1794 224 6 , , PUNCT iajs-1794 224 7 235 235 NUM iajs-1794 224 8 - - SYM iajs-1794 224 9 246 246 NUM iajs-1794 224 10 . . PUNCT iajs-1794 225 1 [ [ X iajs-1794 225 2 18 18 NUM iajs-1794 225 3 ] ] PUNCT iajs-1794 225 4 . . PUNCT iajs-1794 226 1 jc jc PROPN iajs-1794 226 2 . . PROPN iajs-1794 226 3 bailar bailar PROPN iajs-1794 226 4 ; ; PUNCT iajs-1794 226 5 hj hj PROPN iajs-1794 226 6 . . PROPN iajs-1794 226 7 emeleus emeleus PROPN iajs-1794 226 8 ; ; PUNCT iajs-1794 226 9 sr sr PROPN iajs-1794 226 10 . . PUNCT iajs-1794 227 1 nyholm nyholm PROPN iajs-1794 227 2 ; ; PUNCT iajs-1794 227 3 dickenson dickenson PROPN iajs-1794 227 4 aft aft PROPN iajs-1794 227 5 . . PUNCT iajs-1794 227 6 " " PUNCT iajs-1794 227 7 comprehensive comprehensive ADJ iajs-1794 227 8 inorganic inorganic ADJ iajs-1794 227 9 chemistry chemistry NOUN iajs-1794 227 10 " " PUNCT iajs-1794 227 11 . . PUNCT iajs-1794 228 1 pergamon pergamon PROPN iajs-1794 228 2 press press PROPN iajs-1794 228 3 , , PUNCT iajs-1794 228 4 newyork newyork NOUN iajs-1794 228 5 , , PUNCT iajs-1794 228 6 pp pp ADJ iajs-1794 228 7 . . PUNCT iajs-1794 229 1 1975,3 1975,3 NUM iajs-1794 229 2 - - SYM iajs-1794 229 3 12 12 NUM iajs-1794 229 4 . . PUNCT iajs-1794 230 1 [ [ X iajs-1794 230 2 19 19 NUM iajs-1794 230 3 ] ] PUNCT iajs-1794 230 4 . . PUNCT iajs-1794 231 1 m. m. PROPN iajs-1794 231 2 sebastian sebastian PROPN iajs-1794 231 3 ; ; PUNCT iajs-1794 231 4 v. v. ADP iajs-1794 231 5 arun arun PROPN iajs-1794 231 6 ; ; PUNCT iajs-1794 231 7 p.p p.p PROPN iajs-1794 231 8 . . PROPN iajs-1794 231 9 robinson robinson PROPN iajs-1794 231 10 ; ; PUNCT iajs-1794 231 11 p. p. NOUN iajs-1794 231 12 leeju leeju NOUN iajs-1794 231 13 ; ; PUNCT iajs-1794 231 14 d. d. PROPN iajs-1794 231 15 varghese varghese PROPN iajs-1794 231 16 ; ; PUNCT iajs-1794 231 17 g. g. PROPN iajs-1794 231 18 varsha varsha PROPN iajs-1794 231 19 ; ; PUNCT iajs-1794 231 20 k.k.m k.k.m PROPN iajs-1794 231 21 . . PUNCT iajs-1794 231 22 yusuff yusuff PROPN iajs-1794 231 23 and and CCONJ iajs-1794 231 24 j.coord.chem.63 j.coord.chem.63 PROPN iajs-1794 231 25 , , PUNCT iajs-1794 231 26 , , PUNCT iajs-1794 231 27 307 307 NUM iajs-1794 231 28 - - SYM iajs-1794 231 29 313 313 NUM iajs-1794 231 30 . . PUNCT iajs-1794 232 1 2010 2010 NUM iajs-1794 233 1 [ [ X iajs-1794 233 2 20 20 NUM iajs-1794 233 3 ] ] PUNCT iajs-1794 233 4 . . PUNCT iajs-1794 234 1 m. m. PROPN iajs-1794 234 2 sebastian sebastian PROPN iajs-1794 234 3 ; ; PUNCT iajs-1794 234 4 v. v. ADP iajs-1794 234 5 arun arun PROPN iajs-1794 234 6 ; ; PUNCT iajs-1794 234 7 p.p p.p PROPN iajs-1794 234 8 . . PROPN iajs-1794 234 9 robinson robinson PROPN iajs-1794 234 10 ; ; PUNCT iajs-1794 234 11 a.a a.a PROPN iajs-1794 234 12 . . PROPN iajs-1794 234 13 varghese varghese PROPN iajs-1794 234 14 ; ; PUNCT iajs-1794 234 15 r. r. PROPN iajs-1794 234 16 abraham abraham PROPN iajs-1794 234 17 ; ; PUNCT iajs-1794 234 18 e. e. PROPN iajs-1794 234 19 suresh suresh PROPN iajs-1794 234 20 and and CCONJ iajs-1794 234 21 k.k.m k.k.m PROPN iajs-1794 234 22 . . PUNCT iajs-1794 234 23 yusuff yusuff PROPN iajs-1794 234 24 . . PUNCT iajs-1794 235 1 polyhedron polyhedron NOUN iajs-1794 235 2 , , PUNCT iajs-1794 235 3 29,3014 29,3014 NUM iajs-1794 235 4 - - PUNCT iajs-1794 235 5 2020 2020 NUM iajs-1794 235 6 . . PUNCT iajs-1794 236 1 2010 2010 NUM iajs-1794 237 1 [ [ X iajs-1794 237 2 21 21 NUM iajs-1794 237 3 ] ] PUNCT iajs-1794 237 4 . . PUNCT iajs-1794 238 1 f.a f.a PROPN iajs-1794 238 2 . . PROPN iajs-1794 238 3 cotton cotton NOUN iajs-1794 238 4 and and CCONJ iajs-1794 238 5 g. g. PROPN iajs-1794 238 6 wilkinson wilkinson PROPN iajs-1794 238 7 , , PUNCT iajs-1794 238 8 “ " PUNCT iajs-1794 238 9 advanced advanced ADJ iajs-1794 238 10 inorganic inorganic ADJ iajs-1794 238 11 chemistry chemistry NOUN iajs-1794 238 12 , , PUNCT iajs-1794 238 13 4th 4th ADJ iajs-1794 238 14 edn edn NOUN iajs-1794 238 15 . . PUNCT iajs-1794 239 1 interscience interscience NOUN iajs-1794 239 2 publishers publisher NOUN iajs-1794 239 3 , , PUNCT iajs-1794 239 4 new new PROPN iajs-1794 239 5 york york PROPN iajs-1794 239 6 , , PUNCT iajs-1794 239 7 , , PUNCT iajs-1794 239 8 7,16 7,16 PROPN iajs-1794 239 9 - - SYM iajs-1794 239 10 721 721 NUM iajs-1794 239 11 . . PUNCT iajs-1794 240 1 1980 1980 NUM iajs-1794 241 1 [ [ X iajs-1794 241 2 22 22 NUM iajs-1794 241 3 ] ] PUNCT iajs-1794 241 4 . . PUNCT iajs-1794 242 1 s. s. PROPN iajs-1794 242 2 mayadevi mayadevi PROPN iajs-1794 242 3 ; ; PUNCT iajs-1794 242 4 k.k.m k.k.m PROPN iajs-1794 242 5 . . PUNCT iajs-1794 242 6 yusuff yusuff PROPN iajs-1794 242 7 . . PUNCT iajs-1794 243 1 synthesis synthesis NOUN iajs-1794 243 2 and and CCONJ iajs-1794 243 3 reactivity reactivity NOUN iajs-1794 243 4 in in ADP iajs-1794 243 5 inorganic inorganic ADJ iajs-1794 243 6 and and CCONJ iajs-1794 243 7 metalorganic metalorganic ADJ iajs-1794 243 8 chemistry chemistry NOUN iajs-1794 243 9 , , PUNCT iajs-1794 243 10 27 27 NUM iajs-1794 243 11 , , PUNCT iajs-1794 243 12 319 319 NUM iajs-1794 243 13 - - SYM iajs-1794 243 14 325 325 NUM iajs-1794 243 15 . . PUNCT iajs-1794 243 16 1997 1997 NUM