id	sid	tid	token	lemma	pos
iajs-2983	1	1	ihjpas	ihjpas	PROPN
iajs-2983	1	2	.	.	PUNCT
iajs-2983	2	1	36(1)2023	36(1)2023	NUM
iajs-2983	2	2	260	260	NUM
iajs-2983	2	3	this	this	DET
iajs-2983	2	4	work	work	NOUN
iajs-2983	2	5	is	be	AUX
iajs-2983	2	6	licensed	license	VERB
iajs-2983	2	7	under	under	ADP
iajs-2983	2	8	a	a	DET
iajs-2983	2	9	creative	creative	ADJ
iajs-2983	2	10	commons	common	NOUN
iajs-2983	2	11	attribution	attribution	NOUN
iajs-2983	2	12	4.0	4.0	NUM
iajs-2983	2	13	international	international	ADJ
iajs-2983	2	14	license	license	NOUN
iajs-2983	2	15	preparation	preparation	NOUN
iajs-2983	2	16	,	,	PUNCT
iajs-2983	2	17	characterization	characterization	NOUN
iajs-2983	2	18	,	,	PUNCT
iajs-2983	2	19	theoretical	theoretical	ADJ
iajs-2983	2	20	and	and	CCONJ
iajs-2983	2	21	biological	biological	ADJ
iajs-2983	2	22	study	study	NOUN
iajs-2983	2	23	of	of	ADP
iajs-2983	2	24	new	new	ADJ
iajs-2983	2	25	complexes	complex	NOUN
iajs-2983	2	26	with	with	ADP
iajs-2983	2	27	mannich	mannich	DET
iajs-2983	2	28	base	base	NOUN
iajs-2983	2	29	,	,	PUNCT
iajs-2983	2	30	2chloro	2chloro	NUM
iajs-2983	2	31	–	–	PUNCT
iajs-2983	2	32	n-5-(piperidin	n-5-(piperidin	VERB
iajs-2983	2	33	-1	-1	NOUN
iajs-2983	2	34	-	-	PUNCT
iajs-2983	2	35	ylmethylthio)-1	ylmethylthio)-1	ADJ
iajs-2983	2	36	,	,	PUNCT
iajs-2983	2	37	3	3	NUM
iajs-2983	2	38	,	,	PUNCT
iajs-2983	2	39	4thiadiazol-2	4thiadiazol-2	ADJ
iajs-2983	2	40	-	-	PUNCT
iajs-2983	2	41	yl)acetamide	yl)acetamide	NOUN
iajs-2983	2	42	abstract	abstract	NOUN
iajs-2983	2	43	a	a	DET
iajs-2983	2	44	new	new	ADJ
iajs-2983	2	45	mannich	mannich	PRON
iajs-2983	2	46	base	base	PROPN
iajs-2983	2	47	ligand	ligand	NOUN
iajs-2983	2	48	was	be	AUX
iajs-2983	2	49	prepared	prepare	VERB
iajs-2983	2	50	by	by	ADP
iajs-2983	2	51	reacting	react	VERB
iajs-2983	2	52	the	the	DET
iajs-2983	2	53	2	2	NUM
iajs-2983	2	54	-	-	PUNCT
iajs-2983	2	55	chloro.-n-(5	chloro.-n-(5	NOUN
iajs-2983	2	56	-	-	PUNCT
iajs-2983	2	57	mercapto-1	mercapto-1	NOUN
iajs-2983	2	58	,	,	PUNCT
iajs-2983	2	59	3	3	NUM
iajs-2983	2	60	,	,	PUNCT
iajs-2983	2	61	4thiadazol	4thiadazol	NUM
iajs-2983	2	62	-2	-2	NOUN
iajs-2983	2	63	-	-	PUNCT
iajs-2983	2	64	yl	yl	NOUN
iajs-2983	2	65	)	)	PUNCT
iajs-2983	2	66	acetamide	acetamide	NOUN
iajs-2983	2	67	and	and	CCONJ
iajs-2983	2	68	piperidine	piperidine	NOUN
iajs-2983	2	69	in	in	ADP
iajs-2983	2	70	the	the	DET
iajs-2983	2	71	presence	presence	NOUN
iajs-2983	2	72	(	(	PUNCT
iajs-2983	2	73	formaldehyde	formaldehyde	NOUN
iajs-2983	2	74	)	)	PUNCT
iajs-2983	2	75	(	(	PUNCT
iajs-2983	2	76	l	l	NOUN
iajs-2983	2	77	)	)	PUNCT
iajs-2983	2	78	ligand	ligand	NOUN
iajs-2983	2	79	.	.	PUNCT
iajs-2983	3	1	a	a	DET
iajs-2983	3	2	series	series	NOUN
iajs-2983	3	3	of	of	ADP
iajs-2983	3	4	ligand	ligand	ADJ
iajs-2983	3	5	complexes	complex	NOUN
iajs-2983	3	6	were	be	AUX
iajs-2983	3	7	prepared	prepare	VERB
iajs-2983	3	8	from	from	ADP
iajs-2983	3	9	(	(	PUNCT
iajs-2983	3	10	l	l	NOUN
iajs-2983	3	11	)	)	PUNCT
iajs-2983	3	12	with	with	ADP
iajs-2983	3	13	the	the	DET
iajs-2983	3	14	metal	metal	NOUN
iajs-2983	3	15	ion	ion	NOUN
iajs-2983	3	16	co	co	X
iajs-2983	3	17	(	(	PUNCT
iajs-2983	3	18	ii	ii	PROPN
iajs-2983	3	19	)	)	PUNCT
iajs-2983	3	20	,	,	PUNCT
iajs-2983	3	21	ni	ni	PROPN
iajs-2983	3	22	(	(	PUNCT
iajs-2983	3	23	ii	ii	PROPN
iajs-2983	3	24	)	)	PUNCT
iajs-2983	3	25	,	,	PUNCT
iajs-2983	3	26	cu	cu	PROPN
iajs-2983	3	27	(	(	PUNCT
iajs-2983	3	28	ii	ii	PROPN
iajs-2983	3	29	)	)	PUNCT
iajs-2983	3	30	,	,	PUNCT
iajs-2983	3	31	pd	pd	PROPN
iajs-2983	3	32	(	(	PUNCT
iajs-2983	3	33	ii	ii	PROPN
iajs-2983	3	34	)	)	PUNCT
iajs-2983	3	35	,	,	PUNCT
iajs-2983	3	36	pt	pt	X
iajs-2983	3	37	(	(	PUNCT
iajs-2983	3	38	iv	iv	NOUN
iajs-2983	3	39	)	)	PUNCT
iajs-2983	3	40	,	,	PUNCT
iajs-2983	3	41	and	and	CCONJ
iajs-2983	3	42	au	au	X
iajs-2983	3	43	(	(	PUNCT
iajs-2983	3	44	iii	iii	NOUN
iajs-2983	3	45	)	)	PUNCT
iajs-2983	3	46	.	.	PUNCT
iajs-2983	4	1	various	various	ADJ
iajs-2983	4	2	spectroscopic	spectroscopic	ADJ
iajs-2983	4	3	techniques	technique	NOUN
iajs-2983	4	4	such	such	ADJ
iajs-2983	4	5	as	as	ADP
iajs-2983	4	6	c.h.n.s	c.h.n.s	PROPN
iajs-2983	4	7	,	,	PUNCT
iajs-2983	4	8	ftir	ftir	PROPN
iajs-2983	4	9	,	,	PUNCT
iajs-2983	4	10	uv	uv	NOUN
iajs-2983	4	11	-	-	PUNCT
iajs-2983	4	12	vis	vis	X
iajs-2983	4	13	,	,	PUNCT
iajs-2983	4	14	,	,	PUNCT
iajs-2983	4	15	1hnmr	1hnmr	NUM
iajs-2983	4	16	,	,	PUNCT
iajs-2983	4	17	13cnmr	13cnmr	NUM
iajs-2983	4	18	,	,	PUNCT
iajs-2983	4	19	magnetic	magnetic	ADJ
iajs-2983	4	20	moment	moment	NOUN
iajs-2983	4	21	,	,	PUNCT
iajs-2983	4	22	and	and	CCONJ
iajs-2983	4	23	molar	molar	ADJ
iajs-2983	4	24	conductivity	conductivity	NOUN
iajs-2983	4	25	successfully	successfully	ADV
iajs-2983	4	26	characterize	characterize	VERB
iajs-2983	4	27	the	the	DET
iajs-2983	4	28	obtained	obtain	VERB
iajs-2983	4	29	compounds	compound	NOUN
iajs-2983	4	30	.	.	PUNCT
iajs-2983	5	1	the	the	DET
iajs-2983	5	2	m	m	NOUN
iajs-2983	5	3	:	:	PUNCT
iajs-2983	5	4	l	l	NOUN
iajs-2983	5	5	ratio	ratio	NOUN
iajs-2983	5	6	was	be	AUX
iajs-2983	5	7	determined	determine	VERB
iajs-2983	5	8	using	use	VERB
iajs-2983	5	9	the	the	DET
iajs-2983	5	10	molar	molar	ADJ
iajs-2983	5	11	ratio	ratio	NOUN
iajs-2983	5	12	method	method	NOUN
iajs-2983	5	13	in	in	ADP
iajs-2983	5	14	solution	solution	NOUN
iajs-2983	5	15	.	.	PUNCT
iajs-2983	6	1	all	all	DET
iajs-2983	6	2	prepared	prepare	VERB
iajs-2983	6	3	compounds	compound	NOUN
iajs-2983	6	4	'	'	PART
iajs-2983	6	5	antibacterial	antibacterial	ADJ
iajs-2983	6	6	and	and	CCONJ
iajs-2983	6	7	antifungal	antifungal	ADJ
iajs-2983	6	8	activity	activity	NOUN
iajs-2983	6	9	was	be	AUX
iajs-2983	6	10	studied	study	VERB
iajs-2983	6	11	against	against	ADP
iajs-2983	6	12	two	two	NUM
iajs-2983	6	13	types	type	NOUN
iajs-2983	6	14	of	of	ADP
iajs-2983	6	15	bacteria	bacteria	NOUN
iajs-2983	6	16	and	and	CCONJ
iajs-2983	6	17	one	one	NUM
iajs-2983	6	18	type	type	NOUN
iajs-2983	6	19	of	of	ADP
iajs-2983	6	20	fungi	fungus	NOUN
iajs-2983	6	21	at	at	ADP
iajs-2983	6	22	a	a	DET
iajs-2983	6	23	rate	rate	NOUN
iajs-2983	6	24	of	of	ADP
iajs-2983	6	25	0.02	0.02	NUM
iajs-2983	6	26	m.	m.	NOUN
iajs-2983	6	27	the	the	DET
iajs-2983	6	28	standard	standard	NOUN
iajs-2983	6	29	δh	δh	NOUN
iajs-2983	6	30	°	°	PROPN
iajs-2983	6	31	f	f	PROPN
iajs-2983	6	32	and	and	CCONJ
iajs-2983	6	33	δeb	δeb	NOUN
iajs-2983	6	34	of	of	ADP
iajs-2983	6	35	the	the	DET
iajs-2983	6	36	ligands	ligand	NOUN
iajs-2983	6	37	and	and	CCONJ
iajs-2983	6	38	all	all	DET
iajs-2983	6	39	the	the	DET
iajs-2983	6	40	prepared	prepared	ADJ
iajs-2983	6	41	complexes	complex	NOUN
iajs-2983	6	42	were	be	AUX
iajs-2983	6	43	calculated	calculate	VERB
iajs-2983	6	44	using	use	VERB
iajs-2983	6	45	hyperchem	hyperchem	NOUN
iajs-2983	6	46	8.0.7	8.0.7	NUM
iajs-2983	6	47	program	program	NOUN
iajs-2983	6	48	,	,	PUNCT
iajs-2983	6	49	and	and	CCONJ
iajs-2983	6	50	the	the	DET
iajs-2983	6	51	study	study	NOUN
iajs-2983	6	52	proved	prove	VERB
iajs-2983	6	53	that	that	SCONJ
iajs-2983	6	54	the	the	DET
iajs-2983	6	55	complexes	complex	NOUN
iajs-2983	6	56	are	be	AUX
iajs-2983	6	57	more	more	ADV
iajs-2983	6	58	stable	stable	ADJ
iajs-2983	6	59	than	than	ADP
iajs-2983	6	60	the	the	DET
iajs-2983	6	61	ligands	ligand	NOUN
iajs-2983	6	62	.	.	PUNCT
iajs-2983	7	1	in	in	ADP
iajs-2983	7	2	addition	addition	NOUN
iajs-2983	7	3	,	,	PUNCT
iajs-2983	7	4	the	the	DET
iajs-2983	7	5	vibrational	vibrational	ADJ
iajs-2983	7	6	frequencies	frequency	NOUN
iajs-2983	7	7	of	of	ADP
iajs-2983	7	8	the	the	DET
iajs-2983	7	9	ligand	ligand	NOUN
iajs-2983	7	10	were	be	AUX
iajs-2983	7	11	calculated	calculate	VERB
iajs-2983	7	12	,	,	PUNCT
iajs-2983	7	13	and	and	CCONJ
iajs-2983	7	14	the	the	DET
iajs-2983	7	15	theoretical	theoretical	ADJ
iajs-2983	7	16	error	error	NOUN
iajs-2983	7	17	rate	rate	NOUN
iajs-2983	7	18	of	of	ADP
iajs-2983	7	19	the	the	DET
iajs-2983	7	20	process	process	NOUN
iajs-2983	7	21	was	be	AUX
iajs-2983	7	22	calculated	calculate	VERB
iajs-2983	7	23	.	.	PUNCT
iajs-2983	8	1	keywords	keyword	NOUN
iajs-2983	8	2	:	:	PUNCT
iajs-2983	8	3	transition	transition	NOUN
iajs-2983	8	4	metal	metal	NOUN
iajs-2983	8	5	complexes	complex	NOUN
iajs-2983	8	6	,	,	PUNCT
iajs-2983	8	7	mannich	mannich	PRON
iajs-2983	8	8	base	base	NOUN
iajs-2983	8	9	,	,	PUNCT
iajs-2983	8	10	1,3,4	1,3,4	NUM
iajs-2983	8	11	-	-	PUNCT
iajs-2983	8	12	thiadazole	thiadazole	NOUN
iajs-2983	8	13	antibacterial	antibacterial	NOUN
iajs-2983	8	14	and	and	CCONJ
iajs-2983	8	15	antifungal	antifungal	ADJ
iajs-2983	8	16	.	.	PUNCT
iajs-2983	9	1	doi.org/10.30526/36.1.2983	doi.org/10.30526/36.1.2983	NOUN
iajs-2983	9	2	article	article	NOUN
iajs-2983	9	3	history	history	NOUN
iajs-2983	9	4	:	:	PUNCT
iajs-2983	9	5	received	receive	VERB
iajs-2983	9	6	23	23	NUM
iajs-2983	9	7	augest	aug	ADJ
iajs-2983	9	8	2022	2022	NUM
iajs-2983	9	9	,	,	PUNCT
iajs-2983	9	10	accepted	accept	VERB
iajs-2983	9	11	25	25	NUM
iajs-2983	9	12	september	september	PROPN
iajs-2983	9	13	2022	2022	NUM
iajs-2983	9	14	,	,	PUNCT
iajs-2983	9	15	published	publish	VERB
iajs-2983	9	16	in	in	ADP
iajs-2983	9	17	january	january	PROPN
iajs-2983	9	18	2023	2023	NUM
iajs-2983	9	19	.	.	PUNCT
iajs-2983	10	1	ibn	ibn	PROPN
iajs-2983	10	2	al	al	PROPN
iajs-2983	10	3	-	-	PUNCT
iajs-2983	10	4	haitham	haitham	PROPN
iajs-2983	10	5	journal	journal	PROPN
iajs-2983	10	6	for	for	ADP
iajs-2983	10	7	pure	pure	ADJ
iajs-2983	10	8	and	and	CCONJ
iajs-2983	10	9	applied	applied	ADJ
iajs-2983	10	10	sciences	sciences	PROPN
iajs-2983	10	11	journal	journal	PROPN
iajs-2983	10	12	homepage	homepage	NOUN
iajs-2983	10	13	:	:	PUNCT
iajs-2983	10	14	jih.uobaghdad.edu.iq	jih.uobaghdad.edu.iq	PROPN
iajs-2983	10	15	noor	noor	PROPN
iajs-2983	10	16	ali	ali	PROPN
iajs-2983	10	17	hasan	hasan	PROPN
iajs-2983	10	18	department	department	PROPN
iajs-2983	10	19	of	of	ADP
iajs-2983	10	20	chemstry	chemstry	NOUN
iajs-2983	10	21	,	,	PUNCT
iajs-2983	10	22	college	college	NOUN
iajs-2983	10	23	of	of	ADP
iajs-2983	10	24	science	science	NOUN
iajs-2983	10	25	for	for	ADP
iajs-2983	10	26	women	woman	NOUN
iajs-2983	10	27	,	,	PUNCT
iajs-2983	10	28	university	university	NOUN
iajs-2983	10	29	of	of	ADP
iajs-2983	10	30	baghdad	baghdad	PROPN
iajs-2983	10	31	,	,	PUNCT
iajs-2983	10	32	baghdad	baghdad	PROPN
iajs-2983	10	33	,	,	PUNCT
iajs-2983	10	34	iraq	iraq	PROPN
iajs-2983	10	35	.	.	PUNCT
iajs-2983	11	1	nour.ali1205a@csw.uobaghdad.edu.iq	nour.ali1205a@csw.uobaghdad.edu.iq	PROPN
iajs-2983	11	2	shaymaa	shaymaa	PROPN
iajs-2983	11	3	r.	r.	PROPN
iajs-2983	11	4	baqer	baqer	PROPN
iajs-2983	11	5	department	department	PROPN
iajs-2983	11	6	of	of	ADP
iajs-2983	11	7	chemstry	chemstry	NOUN
iajs-2983	11	8	,	,	PUNCT
iajs-2983	11	9	college	college	NOUN
iajs-2983	11	10	of	of	ADP
iajs-2983	11	11	science	science	NOUN
iajs-2983	11	12	for	for	ADP
iajs-2983	11	13	women	woman	NOUN
iajs-2983	11	14	,	,	PUNCT
iajs-2983	11	15	university	university	NOUN
iajs-2983	11	16	of	of	ADP
iajs-2983	11	17	baghdad	baghdad	PROPN
iajs-2983	11	18	,	,	PUNCT
iajs-2983	11	19	baghdad	baghdad	PROPN
iajs-2983	11	20	,	,	PUNCT
iajs-2983	11	21	iraq	iraq	PROPN
iajs-2983	11	22	.	.	PUNCT
iajs-2983	12	1	shyma0213@gmail.com	shyma0213@gmail.com	X
iajs-2983	13	1	https://creativecommons.org/licenses/by/4.0/	https://creativecommons.org/licenses/by/4.0/	PROPN
iajs-2983	13	2	mailto:nour.ali1205a@csw.uobaghdad.edu.iq	mailto:nour.ali1205a@csw.uobaghdad.edu.iq	PROPN
iajs-2983	13	3	mailto:shyma0213@gmail.com	mailto:shyma0213@gmail.com	PROPN
iajs-2983	13	4	ihjpas	ihjpa	NOUN
iajs-2983	13	5	.	.	PUNCT
iajs-2983	14	1	36(1)2023	36(1)2023	NUM
iajs-2983	14	2	261	261	NUM
iajs-2983	14	3	1	1	NUM
iajs-2983	14	4	.	.	PUNCT
iajs-2983	14	5	introduction	introduction	NOUN
iajs-2983	14	6	the	the	DET
iajs-2983	14	7	thiosemicarbazide	thiosemicarbazide	NOUN
iajs-2983	14	8	compound	compound	NOUN
iajs-2983	14	9	with	with	ADP
iajs-2983	14	10	the	the	DET
iajs-2983	14	11	molecular	molecular	ADJ
iajs-2983	14	12	formula	formula	NOUN
iajs-2983	14	13	(	(	PUNCT
iajs-2983	14	14	ch5n3s	ch5n3s	PROPN
iajs-2983	14	15	)	)	PUNCT
iajs-2983	14	16	and	and	CCONJ
iajs-2983	14	17	its	its	PRON
iajs-2983	14	18	complexes	complex	NOUN
iajs-2983	14	19	are	be	AUX
iajs-2983	14	20	of	of	ADP
iajs-2983	14	21	great	great	ADJ
iajs-2983	14	22	biological	biological	ADJ
iajs-2983	14	23	importance	importance	NOUN
iajs-2983	14	24	due	due	ADP
iajs-2983	14	25	to	to	ADP
iajs-2983	14	26	their	their	PRON
iajs-2983	14	27	wide	wide	ADJ
iajs-2983	14	28	uses	use	NOUN
iajs-2983	14	29	[	[	X
iajs-2983	14	30	1	1	NUM
iajs-2983	14	31	]	]	PUNCT
iajs-2983	14	32	.	.	PUNCT
iajs-2983	15	1	the	the	DET
iajs-2983	15	2	compound	compound	NOUN
iajs-2983	15	3	thiodiazole	thiodiazole	NOUN
iajs-2983	15	4	compound	compound	NOUN
iajs-2983	15	5	with	with	ADP
iajs-2983	15	6	the	the	DET
iajs-2983	15	7	molecular	molecular	ADJ
iajs-2983	15	8	formula	formula	NOUN
iajs-2983	15	9	(	(	PUNCT
iajs-2983	15	10	c2h2sn2	c2h2sn2	NOUN
iajs-2983	15	11	)	)	PUNCT
iajs-2983	15	12	is	be	AUX
iajs-2983	15	13	a	a	DET
iajs-2983	15	14	heterogeneous	heterogeneous	ADJ
iajs-2983	15	15	compound	compound	NOUN
iajs-2983	15	16	because	because	SCONJ
iajs-2983	15	17	it	it	PRON
iajs-2983	15	18	contains	contain	VERB
iajs-2983	15	19	two	two	NUM
iajs-2983	15	20	atoms	atom	NOUN
iajs-2983	15	21	of	of	ADP
iajs-2983	15	22	carbone	carbone	NOUN
iajs-2983	15	23	,	,	PUNCT
iajs-2983	15	24	two	two	NUM
iajs-2983	15	25	atoms	atom	NOUN
iajs-2983	15	26	of	of	ADP
iajs-2983	15	27	nitrogen	nitrogen	NOUN
iajs-2983	15	28	,	,	PUNCT
iajs-2983	15	29	and	and	CCONJ
iajs-2983	15	30	one	one	NUM
iajs-2983	15	31	sulfur	sulfur	NOUN
iajs-2983	15	32	atom	atom	NOUN
iajs-2983	16	1	[	[	X
iajs-2983	16	2	2	2	NUM
iajs-2983	16	3	]	]	PUNCT
iajs-2983	16	4	.	.	PUNCT
iajs-2983	17	1	two	two	NUM
iajs-2983	17	2	nitrogen	nitrogen	NOUN
iajs-2983	17	3	atoms	atom	NOUN
iajs-2983	17	4	and	and	CCONJ
iajs-2983	17	5	the	the	DET
iajs-2983	17	6	sulfur	sulfur	NOUN
iajs-2983	17	7	atom	atom	NOUN
iajs-2983	17	8	are	be	AUX
iajs-2983	17	9	electron	electron	NOUN
iajs-2983	17	10	-	-	PUNCT
iajs-2983	17	11	donating	donating	NOUN
iajs-2983	17	12	[	[	X
iajs-2983	17	13	3	3	NUM
iajs-2983	17	14	]	]	PUNCT
iajs-2983	17	15	and	and	CCONJ
iajs-2983	17	16	are	be	AUX
iajs-2983	17	17	essential	essential	ADJ
iajs-2983	17	18	ligands	ligand	NOUN
iajs-2983	17	19	in	in	ADP
iajs-2983	17	20	complexes	complex	NOUN
iajs-2983	17	21	when	when	SCONJ
iajs-2983	17	22	they	they	PRON
iajs-2983	17	23	bond	bond	VERB
iajs-2983	17	24	with	with	ADP
iajs-2983	17	25	metal	metal	NOUN
iajs-2983	17	26	elements	element	NOUN
iajs-2983	17	27	[	[	X
iajs-2983	17	28	2	2	NUM
iajs-2983	17	29	]	]	PUNCT
iajs-2983	17	30	.	.	PUNCT
iajs-2983	18	1	it	it	PRON
iajs-2983	18	2	has	have	VERB
iajs-2983	18	3	several	several	ADJ
iajs-2983	18	4	types	type	NOUN
iajs-2983	18	5	,	,	PUNCT
iajs-2983	18	6	one	one	NUM
iajs-2983	18	7	of	of	ADP
iajs-2983	18	8	which	which	PRON
iajs-2983	18	9	is	be	AUX
iajs-2983	18	10	the	the	DET
iajs-2983	18	11	compound	compound	NOUN
iajs-2983	18	12	1,3,4thiadiazole	1,3,4thiadiazole	NUM
iajs-2983	18	13	,	,	PUNCT
iajs-2983	18	14	which	which	PRON
iajs-2983	18	15	is	be	AUX
iajs-2983	18	16	applied	apply	VERB
iajs-2983	18	17	as	as	ADP
iajs-2983	18	18	anti	anti	ADJ
iajs-2983	18	19	-	-	ADJ
iajs-2983	18	20	tumor	tumor	ADJ
iajs-2983	18	21	medicine	medicine	NOUN
iajs-2983	18	22	.	.	PUNCT
iajs-2983	19	1	several	several	ADJ
iajs-2983	19	2	derivatives	derivative	NOUN
iajs-2983	19	3	are	be	AUX
iajs-2983	19	4	used	use	VERB
iajs-2983	19	5	as	as	ADP
iajs-2983	19	6	carbonic	carbonic	ADJ
iajs-2983	19	7	anhydrase	anhydrase	NOUN
iajs-2983	19	8	inhibitors	inhibitor	NOUN
iajs-2983	19	9	and	and	CCONJ
iajs-2983	19	10	antiparkinsonian	antiparkinsonian	ADJ
iajs-2983	19	11	agents	agent	NOUN
iajs-2983	19	12	[	[	X
iajs-2983	19	13	3	3	NUM
iajs-2983	19	14	]	]	PUNCT
iajs-2983	19	15	.	.	PUNCT
iajs-2983	20	1	industrial	industrial	ADJ
iajs-2983	20	2	and	and	CCONJ
iajs-2983	20	3	biological	biological	ADJ
iajs-2983	20	4	in	in	ADP
iajs-2983	20	5	the	the	DET
iajs-2983	20	6	medical	medical	ADJ
iajs-2983	20	7	field	field	NOUN
iajs-2983	20	8	,	,	PUNCT
iajs-2983	20	9	compound	compound	NOUN
iajs-2983	20	10	1,3,4	1,3,4	NUM
iajs-2983	20	11	has	have	VERB
iajs-2983	20	12	many	many	ADJ
iajs-2983	20	13	applications	application	NOUN
iajs-2983	20	14	against	against	ADP
iajs-2983	20	15	bacteria	bacteria	NOUN
iajs-2983	20	16	[	[	X
iajs-2983	20	17	4	4	NUM
iajs-2983	20	18	]	]	PUNCT
iajs-2983	20	19	,	,	PUNCT
iajs-2983	20	20	fungi	fungi	VERB
iajs-2983	20	21	[	[	X
iajs-2983	20	22	5	5	NUM
iajs-2983	20	23	]	]	PUNCT
iajs-2983	20	24	,	,	PUNCT
iajs-2983	20	25	and	and	CCONJ
iajs-2983	20	26	cancer	cancer	NOUN
iajs-2983	21	1	[	[	X
iajs-2983	21	2	6	6	NUM
iajs-2983	21	3	]	]	PUNCT
iajs-2983	21	4	.	.	PUNCT
iajs-2983	22	1	the	the	DET
iajs-2983	22	2	mannich	mannich	PROPN
iajs-2983	22	3	reaction	reaction	NOUN
iajs-2983	22	4	is	be	AUX
iajs-2983	22	5	of	of	ADP
iajs-2983	22	6	significant	significant	ADJ
iajs-2983	22	7	importance	importance	NOUN
iajs-2983	22	8	reactions	reaction	NOUN
iajs-2983	22	9	in	in	ADP
iajs-2983	22	10	chemistry	chemistry	NOUN
iajs-2983	22	11	.	.	PUNCT
iajs-2983	23	1	it	it	PRON
iajs-2983	23	2	is	be	AUX
iajs-2983	23	3	a	a	DET
iajs-2983	23	4	reaction	reaction	NOUN
iajs-2983	23	5	that	that	PRON
iajs-2983	23	6	includes	include	VERB
iajs-2983	23	7	three	three	NUM
iajs-2983	23	8	or	or	CCONJ
iajs-2983	23	9	more	more	ADJ
iajs-2983	23	10	components	component	NOUN
iajs-2983	23	11	of	of	ADP
iajs-2983	23	12	a	a	DET
iajs-2983	23	13	substance	substance	NOUN
iajs-2983	23	14	or	or	CCONJ
iajs-2983	23	15	solvent	solvent	NOUN
iajs-2983	23	16	[	[	X
iajs-2983	23	17	7	7	NUM
iajs-2983	23	18	]	]	PUNCT
iajs-2983	23	19	,	,	PUNCT
iajs-2983	23	20	and	and	CCONJ
iajs-2983	23	21	it	it	PRON
iajs-2983	23	22	is	be	AUX
iajs-2983	23	23	one	one	NUM
iajs-2983	23	24	of	of	ADP
iajs-2983	23	25	the	the	DET
iajs-2983	23	26	early	early	ADJ
iajs-2983	23	27	examples	example	NOUN
iajs-2983	23	28	of	of	ADP
iajs-2983	23	29	a	a	DET
iajs-2983	23	30	three	three	NUM
iajs-2983	23	31	-	-	PUNCT
iajs-2983	23	32	component	component	NOUN
iajs-2983	23	33	reaction	reaction	NOUN
iajs-2983	23	34	[	[	X
iajs-2983	23	35	8	8	NUM
iajs-2983	23	36	]	]	PUNCT
iajs-2983	23	37	.	.	PUNCT
iajs-2983	24	1	in	in	ADP
iajs-2983	24	2	the	the	DET
iajs-2983	24	3	past	past	ADJ
iajs-2983	24	4	years	year	NOUN
iajs-2983	24	5	,	,	PUNCT
iajs-2983	24	6	the	the	DET
iajs-2983	24	7	focus	focus	NOUN
iajs-2983	24	8	has	have	AUX
iajs-2983	24	9	been	be	AUX
iajs-2983	24	10	on	on	ADP
iajs-2983	24	11	the	the	DET
iajs-2983	24	12	complexes	complex	NOUN
iajs-2983	24	13	of	of	ADP
iajs-2983	24	14	mannich	mannich	PRON
iajs-2983	24	15	bases	basis	NOUN
iajs-2983	24	16	that	that	PRON
iajs-2983	24	17	have	have	VERB
iajs-2983	24	18	heterogeneous	heterogeneous	ADJ
iajs-2983	24	19	rings	ring	NOUN
iajs-2983	24	20	,	,	PUNCT
iajs-2983	24	21	taking	take	VERB
iajs-2983	24	22	into	into	ADP
iajs-2983	24	23	account	account	NOUN
iajs-2983	24	24	the	the	DET
iajs-2983	24	25	amino	amino	NOUN
iajs-2983	24	26	-	-	PUNCT
iajs-2983	24	27	methyl	methyl	NOUN
iajs-2983	24	28	group	group	NOUN
iajs-2983	24	29	and	and	CCONJ
iajs-2983	24	30	studying	study	VERB
iajs-2983	24	31	the	the	DET
iajs-2983	24	32	relationship	relationship	NOUN
iajs-2983	24	33	of	of	ADP
iajs-2983	24	34	structure	structure	NOUN
iajs-2983	24	35	,	,	PUNCT
iajs-2983	24	36	its	its	PRON
iajs-2983	24	37	effect	effect	NOUN
iajs-2983	24	38	on	on	ADP
iajs-2983	24	39	the	the	DET
iajs-2983	24	40	biological	biological	ADJ
iajs-2983	24	41	activity	activity	NOUN
iajs-2983	24	42	as	as	ADP
iajs-2983	24	43	anticancer	anticancer	NOUN
iajs-2983	24	44	agents	agent	NOUN
iajs-2983	24	45	and	and	CCONJ
iajs-2983	24	46	toxic	toxic	ADJ
iajs-2983	24	47	to	to	ADP
iajs-2983	24	48	cancer	cancer	NOUN
iajs-2983	24	49	cells	cell	NOUN
iajs-2983	24	50	[	[	X
iajs-2983	24	51	9,10	9,10	NUM
iajs-2983	24	52	]	]	PUNCT
iajs-2983	24	53	.	.	PUNCT
iajs-2983	25	1	there	there	PRON
iajs-2983	25	2	was	be	VERB
iajs-2983	25	3	also	also	ADV
iajs-2983	25	4	a	a	DET
iajs-2983	25	5	focus	focus	NOUN
iajs-2983	25	6	on	on	ADP
iajs-2983	25	7	studying	study	VERB
iajs-2983	25	8	their	their	PRON
iajs-2983	25	9	importance	importance	NOUN
iajs-2983	25	10	as	as	ADP
iajs-2983	25	11	antibacterial	antibacterial	ADJ
iajs-2983	25	12	and	and	CCONJ
iajs-2983	25	13	antifungals[11	antifungals[11	ADP
iajs-2983	25	14	]	]	PUNCT
iajs-2983	25	15	,	,	PUNCT
iajs-2983	25	16	anticonvulsants	anticonvulsant	NOUN
iajs-2983	25	17	,	,	PUNCT
iajs-2983	25	18	anti	anti	ADJ
iajs-2983	25	19	-	-	ADJ
iajs-2983	25	20	inflammatory	inflammatory	ADJ
iajs-2983	25	21	[	[	X
iajs-2983	25	22	9	9	NUM
iajs-2983	25	23	]	]	PUNCT
iajs-2983	25	24	,	,	PUNCT
iajs-2983	25	25	analgesic	analgesic	ADJ
iajs-2983	25	26	,	,	PUNCT
iajs-2983	25	27	and	and	CCONJ
iajs-2983	25	28	antioxidant	antioxidant	ADJ
iajs-2983	25	29	activities	activity	NOUN
iajs-2983	25	30	[	[	X
iajs-2983	25	31	10	10	NUM
iajs-2983	25	32	]	]	PUNCT
iajs-2983	25	33	.	.	PUNCT
iajs-2983	26	1	the	the	DET
iajs-2983	26	2	complexes	complex	NOUN
iajs-2983	26	3	of	of	ADP
iajs-2983	26	4	mannich	mannich	PRON
iajs-2983	26	5	's	's	PART
iajs-2983	26	6	bases	basis	NOUN
iajs-2983	26	7	are	be	AUX
iajs-2983	26	8	essential	essential	ADJ
iajs-2983	26	9	and	and	CCONJ
iajs-2983	26	10	have	have	VERB
iajs-2983	26	11	wide	wide	ADJ
iajs-2983	26	12	applications	application	NOUN
iajs-2983	26	13	in	in	ADP
iajs-2983	26	14	the	the	DET
iajs-2983	26	15	medical	medical	ADJ
iajs-2983	26	16	and	and	CCONJ
iajs-2983	26	17	biological	biological	ADJ
iajs-2983	26	18	fields	field	NOUN
iajs-2983	26	19	[	[	X
iajs-2983	26	20	11	11	NUM
iajs-2983	26	21	]	]	PUNCT
iajs-2983	26	22	.	.	PUNCT
iajs-2983	27	1	they	they	PRON
iajs-2983	27	2	are	be	AUX
iajs-2983	27	3	used	use	VERB
iajs-2983	27	4	as	as	ADP
iajs-2983	27	5	antioxidants	antioxidant	NOUN
iajs-2983	27	6	[	[	X
iajs-2983	27	7	10	10	NUM
iajs-2983	27	8	]	]	PUNCT
iajs-2983	27	9	,	,	PUNCT
iajs-2983	27	10	anticancer	anticancer	NOUN
iajs-2983	27	11	,	,	PUNCT
iajs-2983	27	12	antibacterial	antibacterial	ADJ
iajs-2983	27	13	,	,	PUNCT
iajs-2983	27	14	and	and	CCONJ
iajs-2983	27	15	antifungal	antifungal	ADJ
iajs-2983	28	1	[	[	X
iajs-2983	28	2	12	12	NUM
iajs-2983	28	3	]	]	PUNCT
iajs-2983	28	4	,	,	PUNCT
iajs-2983	28	5	and	and	CCONJ
iajs-2983	28	6	they	they	PRON
iajs-2983	28	7	have	have	AUX
iajs-2983	28	8	proven	prove	VERB
iajs-2983	28	9	their	their	PRON
iajs-2983	28	10	effectiveness	effectiveness	NOUN
iajs-2983	28	11	in	in	ADP
iajs-2983	28	12	all	all	DET
iajs-2983	28	13	biological	biological	ADJ
iajs-2983	28	14	and	and	CCONJ
iajs-2983	28	15	medical	medical	ADJ
iajs-2983	28	16	fields	field	NOUN
iajs-2983	28	17	[	[	X
iajs-2983	28	18	13	13	NUM
iajs-2983	28	19	]	]	SYM
iajs-2983	28	20	.	.	PUNCT
iajs-2983	29	1	2	2	X
iajs-2983	29	2	.	.	X
iajs-2983	29	3	materials	material	NOUN
iajs-2983	29	4	and	and	CCONJ
iajs-2983	29	5	methods	method	NOUN
iajs-2983	29	6	in	in	ADP
iajs-2983	29	7	this	this	DET
iajs-2983	29	8	paper	paper	NOUN
iajs-2983	29	9	,	,	PUNCT
iajs-2983	29	10	high	high	ADJ
iajs-2983	29	11	-	-	PUNCT
iajs-2983	29	12	purity	purity	NOUN
iajs-2983	29	13	chemicals	chemical	NOUN
iajs-2983	29	14	were	be	AUX
iajs-2983	29	15	used	use	VERB
iajs-2983	29	16	.	.	PUNCT
iajs-2983	30	1	chns	chns	PROPN
iajs-2983	30	2	elemental	elemental	PROPN
iajs-2983	30	3	data	datum	NOUN
iajs-2983	30	4	were	be	AUX
iajs-2983	30	5	measured	measure	VERB
iajs-2983	30	6	using	use	VERB
iajs-2983	30	7	an	an	DET
iajs-2983	30	8	eager300	eager300	PROPN
iajs-2983	30	9	elemental	elemental	ADJ
iajs-2983	30	10	analyzer	analyzer	NOUN
iajs-2983	30	11	.	.	PUNCT
iajs-2983	31	1	the	the	DET
iajs-2983	31	2	mineral	mineral	NOUN
iajs-2983	31	3	content	content	NOUN
iajs-2983	31	4	was	be	AUX
iajs-2983	31	5	determined	determine	VERB
iajs-2983	31	6	using	use	VERB
iajs-2983	31	7	a	a	DET
iajs-2983	31	8	shimadzu	shimadzu	ADJ
iajs-2983	31	9	670	670	NUM
iajs-2983	31	10	flam	flam	NOUN
iajs-2983	31	11	atomic	atomic	ADJ
iajs-2983	31	12	absorber	absorber	NOUN
iajs-2983	31	13	spectrophotometer	spectrophotometer	NOUN
iajs-2983	31	14	.	.	PUNCT
iajs-2983	32	1	conductivity	conductivity	NOUN
iajs-2983	32	2	data	datum	NOUN
iajs-2983	32	3	were	be	AUX
iajs-2983	32	4	acquired	acquire	VERB
iajs-2983	32	5	at	at	ADP
iajs-2983	32	6	10	10	NUM
iajs-2983	32	7	-	-	SYM
iajs-2983	32	8	3	3	NUM
iajs-2983	32	9	m	m	NOUN
iajs-2983	32	10	in	in	ADP
iajs-2983	32	11	the	the	DET
iajs-2983	32	12	dmf	dmf	PROPN
iajs-2983	32	13	solution	solution	NOUN
iajs-2983	32	14	of	of	ADP
iajs-2983	32	15	the	the	DET
iajs-2983	32	16	complexes	complex	NOUN
iajs-2983	32	17	using	use	VERB
iajs-2983	32	18	a	a	DET
iajs-2983	32	19	wtw	wtw	ADJ
iajs-2983	32	20	conductance	conductance	NOUN
iajs-2983	32	21	meter	meter	NOUN
iajs-2983	32	22	at	at	ADP
iajs-2983	32	23	25	25	NUM
iajs-2983	32	24	°	°	NOUN
iajs-2983	32	25	c	c	NOUN
iajs-2983	32	26	.	.	PUNCT
iajs-2983	33	1	ft	ft	PROPN
iajs-2983	33	2	-	-	PUNCT
iajs-2983	33	3	ir	ir	PROPN
iajs-2983	33	4	spectra	spectra	NOUN
iajs-2983	33	5	were	be	AUX
iajs-2983	33	6	measured	measure	VERB
iajs-2983	33	7	with	with	ADP
iajs-2983	33	8	a	a	DET
iajs-2983	33	9	shimadzu	shimadzu	NOUN
iajs-2983	33	10	and	and	CCONJ
iajs-2983	33	11	perkin	perkin	PROPN
iajs-2983	33	12	elmer	elmer	PROPN
iajs-2983	33	13	ft	ft	PROPN
iajs-2983	33	14	infrared	infrared	ADJ
iajs-2983	33	15	spectrophotometer	spectrophotometer	NOUN
iajs-2983	33	16	using	use	VERB
iajs-2983	33	17	csi	csi	PROPN
iajs-2983	33	18	(	(	PUNCT
iajs-2983	33	19	4000	4000	NUM
iajs-2983	33	20	-	-	SYM
iajs-2983	33	21	200	200	NUM
iajs-2983	33	22	)	)	PUNCT
iajs-2983	33	23	cm-1	cm-1	PROPN
iajs-2983	33	24	.	.	PUNCT
iajs-2983	33	25	tablet	tablet	PROPN
iajs-2983	33	26	.	.	PUNCT
iajs-2983	34	1	absorption	absorption	NOUN
iajs-2983	34	2	in	in	ADP
iajs-2983	34	3	the	the	DET
iajs-2983	34	4	uv	uv	NOUN
iajs-2983	34	5	-	-	PUNCT
iajs-2983	34	6	visible	visible	ADJ
iajs-2983	34	7	region	region	NOUN
iajs-2983	34	8	was	be	AUX
iajs-2983	34	9	recorded	record	VERB
iajs-2983	34	10	in	in	ADP
iajs-2983	34	11	ethanol	ethanol	NOUN
iajs-2983	34	12	solution	solution	NOUN
iajs-2983	34	13	using	use	VERB
iajs-2983	34	14	uv	uv	NOUN
iajs-2983	34	15	-	-	PUNCT
iajs-2983	34	16	vis	vis	X
iajs-2983	34	17	.	.	X
iajs-2983	34	18	shimadzu	shimadzu	ADJ
iajs-2983	34	19	spectrophotometer	spectrophotometer	NOUN
iajs-2983	34	20	1800pcs	1800pcs	PROPN
iajs-2983	34	21	.	.	PUNCT
iajs-2983	35	1	the	the	DET
iajs-2983	35	2	magnetic	magnetic	ADJ
iajs-2983	35	3	susceptibility	susceptibility	NOUN
iajs-2983	35	4	measurement	measurement	NOUN
iajs-2983	35	5	of	of	ADP
iajs-2983	35	6	the	the	DET
iajs-2983	35	7	complexes	complex	NOUN
iajs-2983	35	8	was	be	AUX
iajs-2983	35	9	carried	carry	VERB
iajs-2983	35	10	out	out	ADP
iajs-2983	35	11	using	use	VERB
iajs-2983	35	12	the	the	DET
iajs-2983	35	13	faraday	faraday	PROPN
iajs-2983	35	14	method	method	NOUN
iajs-2983	35	15	,	,	PUNCT
iajs-2983	35	16	and	and	CCONJ
iajs-2983	35	17	the	the	DET
iajs-2983	35	18	magnetic	magnetic	ADJ
iajs-2983	35	19	correction	correction	NOUN
iajs-2983	35	20	factor	factor	NOUN
iajs-2983	35	21	(	(	PUNCT
iajs-2983	35	22	d	d	X
iajs-2983	35	23	)	)	PUNCT
iajs-2983	35	24	was	be	AUX
iajs-2983	35	25	calculated	calculate	VERB
iajs-2983	35	26	using	use	VERB
iajs-2983	35	27	the	the	DET
iajs-2983	35	28	pascal	pascal	ADJ
iajs-2983	35	29	constants	constant	NOUN
iajs-2983	35	30	of	of	ADP
iajs-2983	35	31	the	the	DET
iajs-2983	35	32	atoms	atom	NOUN
iajs-2983	35	33	that	that	PRON
iajs-2983	35	34	made	make	VERB
iajs-2983	35	35	up	up	ADP
iajs-2983	35	36	the	the	DET
iajs-2983	35	37	prepared	prepare	VERB
iajs-2983	35	38	complexes	complex	NOUN
iajs-2983	35	39	and	and	CCONJ
iajs-2983	35	40	the	the	DET
iajs-2983	35	41	brukar	brukar	PROPN
iajs-2983	35	42	magent	magent	PROPN
iajs-2983	35	43	bm6	bm6	PROPN
iajs-2983	35	44	device	device	NOUN
iajs-2983	35	45	.	.	PUNCT
iajs-2983	36	1	1h	1h	NUM
iajs-2983	36	2	,	,	PUNCT
iajs-2983	36	3	13cnmr	13cnmr	NUM
iajs-2983	36	4	for	for	ADP
iajs-2983	36	5	compounds	compound	NOUN
iajs-2983	36	6	were	be	AUX
iajs-2983	36	7	at	at	ADP
iajs-2983	36	8	25	25	NUM
iajs-2983	36	9	°	°	NOUN
iajs-2983	36	10	c	c	NOUN
iajs-2983	36	11	using	use	VERB
iajs-2983	36	12	the	the	DET
iajs-2983	36	13	brukar400mhz	brukar400mhz	ADJ
iajs-2983	36	14	.	.	PUNCT
iajs-2983	37	1	the	the	DET
iajs-2983	37	2	grade	grade	NOUN
iajs-2983	37	3	of	of	ADP
iajs-2983	37	4	all	all	DET
iajs-2983	37	5	prepared	prepare	VERB
iajs-2983	37	6	compounds	compound	NOUN
iajs-2983	37	7	was	be	AUX
iajs-2983	37	8	measured	measure	VERB
iajs-2983	37	9	by	by	ADP
iajs-2983	37	10	gallen	gallen	PROPN
iajs-2983	37	11	kamp	kamp	PROPN
iajs-2983	37	12	mf.b-6	mf.b-6	PROPN
iajs-2983	37	13	.	.	PUNCT
iajs-2983	38	1	preparation	preparation	NOUN
iajs-2983	38	2	of	of	ADP
iajs-2983	38	3	starting	start	VERB
iajs-2983	38	4	material	material	NOUN
iajs-2983	38	5	2	2	NUM
iajs-2983	38	6	-	-	PUNCT
iajs-2983	38	7	amino	amino	ADJ
iajs-2983	38	8	5	5	NUM
iajs-2983	38	9	-	-	PUNCT
iajs-2983	38	10	mercapto	mercapto	NOUN
iajs-2983	38	11	1,3,4	1,3,4	NUM
iajs-2983	38	12	thiadiazole	thiadiazole	NOUN
iajs-2983	38	13	(	(	PUNCT
iajs-2983	38	14	s1	s1	PROPN
iajs-2983	38	15	)	)	PUNCT
iajs-2983	38	16	in	in	ADP
iajs-2983	38	17	a	a	DET
iajs-2983	38	18	round	round	ADJ
iajs-2983	38	19	bottom	bottom	ADJ
iajs-2983	38	20	flask	flask	NOUN
iajs-2983	38	21	,	,	PUNCT
iajs-2983	38	22	(	(	PUNCT
iajs-2983	38	23	2gm,0.02mol	2gm,0.02mol	NUM
iajs-2983	38	24	)	)	PUNCT
iajs-2983	38	25	of	of	ADP
iajs-2983	38	26	thiosimcarbazide	thiosimcarbazide	NOUN
iajs-2983	38	27	was	be	AUX
iajs-2983	38	28	dissolved	dissolve	VERB
iajs-2983	38	29	in	in	ADP
iajs-2983	38	30	(	(	PUNCT
iajs-2983	38	31	25ml	25ml	ADJ
iajs-2983	38	32	)	)	PUNCT
iajs-2983	38	33	ethanol	ethanol	NOUN
iajs-2983	38	34	(	(	PUNCT
iajs-2983	38	35	0.016gm,0.0002mol	0.016gm,0.0002mol	PROPN
iajs-2983	38	36	)	)	PUNCT
iajs-2983	38	37	of	of	ADP
iajs-2983	38	38	anhydrous	anhydrous	ADJ
iajs-2983	38	39	sodium	sodium	NOUN
iajs-2983	38	40	carbonate	carbonate	NOUN
iajs-2983	38	41	.	.	PUNCT
iajs-2983	39	1	(	(	PUNCT
iajs-2983	39	2	4.712	4.712	NUM
iajs-2983	39	3	gm	gm	PROPN
iajs-2983	39	4	,	,	PUNCT
iajs-2983	39	5	0.062	0.062	NUM
iajs-2983	39	6	mol	mol	NOUN
iajs-2983	39	7	)	)	PUNCT
iajs-2983	39	8	of	of	ADP
iajs-2983	39	9	(	(	PUNCT
iajs-2983	39	10	cs2	cs2	NOUN
iajs-2983	39	11	)	)	PUNCT
iajs-2983	39	12	was	be	AUX
iajs-2983	39	13	added	add	VERB
iajs-2983	39	14	with	with	ADP
iajs-2983	39	15	stirring	stir	VERB
iajs-2983	39	16	and	and	CCONJ
iajs-2983	39	17	heating	heating	NOUN
iajs-2983	39	18	at	at	ADP
iajs-2983	39	19	(	(	PUNCT
iajs-2983	39	20	40c0	40c0	NUM
iajs-2983	39	21	)	)	PUNCT
iajs-2983	39	22	for	for	ADP
iajs-2983	39	23	an	an	DET
iajs-2983	39	24	hour	hour	NOUN
iajs-2983	39	25	.	.	PUNCT
iajs-2983	40	1	then	then	ADV
iajs-2983	40	2	,	,	PUNCT
iajs-2983	40	3	the	the	DET
iajs-2983	40	4	mixture	mixture	NOUN
iajs-2983	40	5	was	be	AUX
iajs-2983	40	6	raised	raise	VERB
iajs-2983	40	7	for	for	ADP
iajs-2983	40	8	7	7	NUM
iajs-2983	40	9	hours	hour	NOUN
iajs-2983	40	10	after	after	SCONJ
iajs-2983	40	11	the	the	DET
iajs-2983	40	12	solvent	solvent	NOUN
iajs-2983	40	13	was	be	AUX
iajs-2983	40	14	evaporated	evaporate	VERB
iajs-2983	40	15	(	(	PUNCT
iajs-2983	40	16	50ml	50ml	NOUN
iajs-2983	40	17	)	)	PUNCT
iajs-2983	40	18	in	in	ADP
iajs-2983	40	19	distilled	distilled	ADJ
iajs-2983	40	20	water	water	NOUN
iajs-2983	40	21	,	,	PUNCT
iajs-2983	40	22	and	and	CCONJ
iajs-2983	40	23	drops	drop	NOUN
iajs-2983	40	24	of	of	ADP
iajs-2983	40	25	concentrated	concentrated	ADJ
iajs-2983	40	26	hydrochloric	hydrochloric	ADJ
iajs-2983	40	27	acid	acid	NOUN
iajs-2983	40	28	were	be	AUX
iajs-2983	40	29	added	add	VERB
iajs-2983	40	30	.	.	PUNCT
iajs-2983	41	1	a	a	DET
iajs-2983	41	2	greenish	greenish	ADJ
iajs-2983	41	3	-	-	PUNCT
iajs-2983	41	4	yellow	yellow	NOUN
iajs-2983	41	5	was	be	AUX
iajs-2983	41	6	the	the	DET
iajs-2983	41	7	precipitate	precipitate	NOUN
iajs-2983	41	8	.	.	PUNCT
iajs-2983	42	1	the	the	DET
iajs-2983	42	2	color	color	NOUN
iajs-2983	42	3	of	of	ADP
iajs-2983	42	4	the	the	DET
iajs-2983	42	5	precipitate	precipitate	NOUN
iajs-2983	42	6	(	(	PUNCT
iajs-2983	42	7	was	be	AUX
iajs-2983	42	8	yellowish	yellowish	ADJ
iajs-2983	42	9	white	white	ADJ
iajs-2983	42	10	,	,	PUNCT
iajs-2983	42	11	with	with	ADP
iajs-2983	42	12	a	a	DET
iajs-2983	42	13	melting	melting	NOUN
iajs-2983	42	14	point	point	NOUN
iajs-2983	42	15	of	of	ADP
iajs-2983	42	16	(	(	PUNCT
iajs-2983	42	17	229	229	NUM
iajs-2983	42	18	-	-	SYM
iajs-2983	42	19	231	231	NUM
iajs-2983	42	20	)	)	PUNCT
iajs-2983	42	21	c	c	NOUN
iajs-2983	42	22	°	°	NUM
iajs-2983	42	23	and	and	CCONJ
iajs-2983	42	24	the	the	DET
iajs-2983	42	25	molecular	molecular	ADJ
iajs-2983	42	26	formula	formula	NOUN
iajs-2983	42	27	(	(	PUNCT
iajs-2983	42	28	c2h3n3s2	c2h3n3s2	NOUN
iajs-2983	42	29	)	)	PUNCT
iajs-2983	43	1	[	[	X
iajs-2983	43	2	14	14	NUM
iajs-2983	43	3	]	]	PUNCT
iajs-2983	43	4	.	.	PUNCT
iajs-2983	44	1	the	the	DET
iajs-2983	44	2	sediment	sediment	NOUN
iajs-2983	44	3	was	be	AUX
iajs-2983	44	4	washed	wash	VERB
iajs-2983	44	5	,	,	PUNCT
iajs-2983	44	6	and	and	CCONJ
iajs-2983	44	7	the	the	DET
iajs-2983	44	8	precipitate	precipitate	NOUN
iajs-2983	44	9	was	be	AUX
iajs-2983	44	10	filtered	filter	VERB
iajs-2983	44	11	with	with	ADP
iajs-2983	44	12	a	a	DET
iajs-2983	44	13	quantity	quantity	NOUN
iajs-2983	44	14	of	of	ADP
iajs-2983	44	15	distilled	distil	VERB
iajs-2983	44	16	water	water	NOUN
iajs-2983	44	17	to	to	PART
iajs-2983	44	18	get	get	AUX
iajs-2983	44	19	rid	rid	VERB
iajs-2983	44	20	of	of	ADP
iajs-2983	44	21	the	the	DET
iajs-2983	44	22	excess	excess	ADJ
iajs-2983	44	23	acid	acid	NOUN
iajs-2983	44	24	.	.	PUNCT
iajs-2983	45	1	it	it	PRON
iajs-2983	45	2	was	be	AUX
iajs-2983	45	3	recrystallized	recrystallize	VERB
iajs-2983	45	4	with	with	ADP
iajs-2983	45	5	the	the	DET
iajs-2983	45	6	solvent	solvent	NOUN
iajs-2983	45	7	ethanol	ethanol	NOUN
iajs-2983	45	8	.	.	PUNCT
iajs-2983	46	1	ihjpas	ihjpas	PROPN
iajs-2983	46	2	.	.	PUNCT
iajs-2983	47	1	36(1)2023	36(1)2023	NUM
iajs-2983	47	2	262	262	NUM
iajs-2983	47	3	preparation	preparation	NOUN
iajs-2983	47	4	of	of	ADP
iajs-2983	47	5	2	2	NUM
iajs-2983	47	6	-	-	PUNCT
iajs-2983	47	7	chloro	chloro	NOUN
iajs-2983	47	8	-	-	PUNCT
iajs-2983	47	9	n-(5	n-(5	NOUN
iajs-2983	47	10	-	-	PUNCT
iajs-2983	47	11	mercapto-1,3,4	mercapto-1,3,4	NOUN
iajs-2983	47	12	-	-	PUNCT
iajs-2983	47	13	thiadiazol-2	thiadiazol-2	NUM
iajs-2983	47	14	-	-	PUNCT
iajs-2983	47	15	yl)acetamide	yl)acetamide	NOUN
iajs-2983	47	16	(	(	PUNCT
iajs-2983	47	17	s2	s2	PROPN
iajs-2983	47	18	)	)	PUNCT
iajs-2983	47	19	dissolved	dissolve	VERB
iajs-2983	47	20	(	(	PUNCT
iajs-2983	47	21	0.1gm	0.1gm	PROPN
iajs-2983	47	22	,	,	PUNCT
iajs-2983	47	23	0.01	0.01	NUM
iajs-2983	47	24	m	m	NOUN
iajs-2983	47	25	)	)	PUNCT
iajs-2983	47	26	of	of	ADP
iajs-2983	47	27	2	2	NUM
iajs-2983	47	28	-	-	PUNCT
iajs-2983	47	29	amino	amino	ADJ
iajs-2983	47	30	5	5	NUM
iajs-2983	47	31	-	-	PUNCT
iajs-2983	47	32	mercapto	mercapto	NOUN
iajs-2983	47	33	1,3,4	1,3,4	NUM
iajs-2983	47	34	thiadiazole	thiadiazole	NOUN
iajs-2983	47	35	(	(	PUNCT
iajs-2983	47	36	s1	s1	NOUN
iajs-2983	47	37	)	)	PUNCT
iajs-2983	47	38	in	in	ADP
iajs-2983	47	39	ethanol	ethanol	NOUN
iajs-2983	47	40	was	be	AUX
iajs-2983	47	41	added	add	VERB
iajs-2983	47	42	with	with	ADP
iajs-2983	47	43	stirring	stir	VERB
iajs-2983	47	44	(	(	PUNCT
iajs-2983	47	45	0.1	0.1	NUM
iajs-2983	47	46	g	g	NOUN
iajs-2983	47	47	,	,	PUNCT
iajs-2983	47	48	0.02	0.02	NUM
iajs-2983	47	49	m	m	NOUN
iajs-2983	47	50	)	)	PUNCT
iajs-2983	47	51	of	of	ADP
iajs-2983	47	52	chloroacetyl	chloroacetyl	PROPN
iajs-2983	47	53	chloride	chloride	NOUN
iajs-2983	47	54	)	)	PUNCT
iajs-2983	47	55	in	in	ADP
iajs-2983	47	56	an	an	DET
iajs-2983	47	57	ice	ice	NOUN
iajs-2983	47	58	bath	bath	NOUN
iajs-2983	47	59	.	.	PUNCT
iajs-2983	48	1	the	the	DET
iajs-2983	48	2	mixture	mixture	NOUN
iajs-2983	48	3	was	be	AUX
iajs-2983	48	4	refluxed	refluxe	VERB
iajs-2983	48	5	with	with	ADP
iajs-2983	48	6	heating	heat	VERB
iajs-2983	48	7	for	for	ADP
iajs-2983	48	8	3	3	NUM
iajs-2983	48	9	hours	hour	NOUN
iajs-2983	48	10	.	.	PUNCT
iajs-2983	49	1	the	the	DET
iajs-2983	49	2	resulting	result	VERB
iajs-2983	49	3	precipitate	precipitate	NOUN
iajs-2983	49	4	was	be	AUX
iajs-2983	49	5	washed	wash	VERB
iajs-2983	49	6	with	with	ADP
iajs-2983	49	7	distilled	distil	VERB
iajs-2983	49	8	water	water	NOUN
iajs-2983	49	9	and	and	CCONJ
iajs-2983	49	10	recrystallized	recrystallize	VERB
iajs-2983	49	11	with	with	ADP
iajs-2983	49	12	ethanol	ethanol	NOUN
iajs-2983	49	13	.	.	PUNCT
iajs-2983	50	1	a	a	DET
iajs-2983	50	2	yellowish	yellowish	ADJ
iajs-2983	50	3	-	-	PUNCT
iajs-2983	50	4	white	white	ADJ
iajs-2983	50	5	precipitate	precipitate	NOUN
iajs-2983	50	6	was	be	AUX
iajs-2983	50	7	obtained	obtain	VERB
iajs-2983	50	8	with	with	ADP
iajs-2983	50	9	a	a	DET
iajs-2983	50	10	molecular	molecular	ADJ
iajs-2983	50	11	formula	formula	NOUN
iajs-2983	50	12	c4h4n3s2ocl	c4h4n3s2ocl	NOUN
iajs-2983	50	13	and	and	CCONJ
iajs-2983	50	14	a	a	DET
iajs-2983	50	15	melting	melting	NOUN
iajs-2983	50	16	point	point	NOUN
iajs-2983	50	17	of	of	ADP
iajs-2983	50	18	(	(	PUNCT
iajs-2983	50	19	250	250	NUM
iajs-2983	50	20	-	-	SYM
iajs-2983	50	21	253	253	NUM
iajs-2983	50	22	)	)	PUNCT
iajs-2983	50	23	c0	c0	NOUN
iajs-2983	50	24	.	.	PUNCT
iajs-2983	51	1	synthesis	synthesis	NOUN
iajs-2983	51	2	of	of	ADP
iajs-2983	51	3	2chloro	2chloro	NUM
iajs-2983	51	4	–	–	PUNCT
iajs-2983	51	5	n-5-(piperidine1	n-5-(piperidine1	PROPN
iajs-2983	51	6	-	-	PUNCT
iajs-2983	51	7	ylmethylthio)-1,3,4thiadiazol-2	ylmethylthio)-1,3,4thiadiazol-2	ADJ
iajs-2983	51	8	-	-	PUNCT
iajs-2983	51	9	yl)acetamide	yl)acetamide	NOUN
iajs-2983	51	10	ligand	ligand	NOUN
iajs-2983	51	11	(	(	PUNCT
iajs-2983	51	12	mannich	mannich	DET
iajs-2983	51	13	ligand)(l	ligand)(l	NOUN
iajs-2983	51	14	)	)	PUNCT
iajs-2983	51	15	dissolved	dissolve	VERB
iajs-2983	51	16	of	of	ADP
iajs-2983	51	17	(	(	PUNCT
iajs-2983	51	18	0.145	0.145	NUM
iajs-2983	51	19	gm	gm	PROPN
iajs-2983	51	20	,	,	PUNCT
iajs-2983	51	21	0.04	0.04	NUM
iajs-2983	51	22	m	m	NOUN
iajs-2983	51	23	)	)	PUNCT
iajs-2983	51	24	of	of	ADP
iajs-2983	51	25	2	2	NUM
iajs-2983	51	26	-	-	PUNCT
iajs-2983	51	27	chloro	chloro	NOUN
iajs-2983	51	28	-	-	PUNCT
iajs-2983	51	29	n-(5	n-(5	NOUN
iajs-2983	51	30	-	-	PUNCT
iajs-2983	51	31	mercapto-1,3,4	mercapto-1,3,4	NOUN
iajs-2983	51	32	-	-	PUNCT
iajs-2983	51	33	thiadiazol-2	thiadiazol-2	NUM
iajs-2983	51	34	-	-	PUNCT
iajs-2983	51	35	yl)acetamide	yl)acetamide	NOUN
iajs-2983	51	36	in	in	ADP
iajs-2983	51	37	(	(	PUNCT
iajs-2983	51	38	10ml	10ml	NOUN
iajs-2983	51	39	)	)	PUNCT
iajs-2983	51	40	of	of	ADP
iajs-2983	51	41	ethanol	ethanol	NOUN
iajs-2983	51	42	solvent	solvent	NOUN
iajs-2983	51	43	was	be	AUX
iajs-2983	51	44	added	add	VERB
iajs-2983	51	45	with	with	ADP
iajs-2983	51	46	stirring	stir	VERB
iajs-2983	51	47	and	and	CCONJ
iajs-2983	51	48	cooling	cool	VERB
iajs-2983	51	49	(	(	PUNCT
iajs-2983	51	50	8ml	8ml	NOUN
iajs-2983	51	51	)	)	PUNCT
iajs-2983	51	52	from	from	ADP
iajs-2983	51	53	formaldehyde	formaldehyde	NOUN
iajs-2983	51	54	and	and	CCONJ
iajs-2983	51	55	(	(	PUNCT
iajs-2983	51	56	0.08	0.08	NUM
iajs-2983	51	57	g	g	NOUN
iajs-2983	51	58	,	,	PUNCT
iajs-2983	51	59	0.03	0.03	NUM
iajs-2983	51	60	m	m	NOUN
iajs-2983	51	61	)	)	PUNCT
iajs-2983	51	62	piperidine	piperidine	NOUN
iajs-2983	51	63	.	.	PUNCT
iajs-2983	52	1	the	the	DET
iajs-2983	52	2	mixture	mixture	NOUN
iajs-2983	52	3	was	be	AUX
iajs-2983	52	4	refluxed	refluxe	VERB
iajs-2983	52	5	and	and	CCONJ
iajs-2983	52	6	heated	heat	VERB
iajs-2983	52	7	for	for	ADP
iajs-2983	52	8	six	six	NUM
iajs-2983	52	9	hours	hour	NOUN
iajs-2983	52	10	,	,	PUNCT
iajs-2983	52	11	leaving	leave	VERB
iajs-2983	52	12	the	the	DET
iajs-2983	52	13	solution	solution	NOUN
iajs-2983	52	14	to	to	PART
iajs-2983	52	15	dry	dry	VERB
iajs-2983	52	16	.	.	PUNCT
iajs-2983	53	1	the	the	DET
iajs-2983	53	2	sediment	sediment	NOUN
iajs-2983	53	3	was	be	AUX
iajs-2983	53	4	recrystallized	recrystallize	VERB
iajs-2983	53	5	in	in	ADP
iajs-2983	53	6	ethanol	ethanol	NOUN
iajs-2983	53	7	.	.	PUNCT
iajs-2983	54	1	the	the	DET
iajs-2983	54	2	precipitate	precipitate	NOUN
iajs-2983	54	3	has	have	VERB
iajs-2983	54	4	a	a	DET
iajs-2983	54	5	brown	brown	ADJ
iajs-2983	54	6	color	color	NOUN
iajs-2983	54	7	,	,	PUNCT
iajs-2983	54	8	a	a	DET
iajs-2983	54	9	molecular	molecular	ADJ
iajs-2983	54	10	formula	formula	NOUN
iajs-2983	54	11	c10h15cln4os2	c10h15cln4os2	NOUN
iajs-2983	54	12	,	,	PUNCT
iajs-2983	54	13	and	and	CCONJ
iajs-2983	54	14	a	a	DET
iajs-2983	54	15	melting	melting	NOUN
iajs-2983	54	16	point	point	NOUN
iajs-2983	54	17	of	of	ADP
iajs-2983	54	18	over	over	ADP
iajs-2983	54	19	300	300	NUM
iajs-2983	54	20	c0	c0	NOUN
iajs-2983	54	21	.	.	PUNCT
iajs-2983	55	1	h2n	h2n	VERB
iajs-2983	55	2	-	-	PUNCT
iajs-2983	55	3	c	c	NOUN
iajs-2983	55	4	-	-	PUNCT
iajs-2983	55	5	nh.nh2	nh.nh2	PUNCT
iajs-2983	55	6	+	+	NUM
iajs-2983	55	7	cs2	cs2	NOUN
iajs-2983	55	8	na	na	ADP
iajs-2983	55	9	2	2	NUM
iajs-2983	55	10	co	co	X
iajs-2983	55	11	3	3	NUM
iajs-2983	55	12	,	,	PUNCT
iajs-2983	55	13	c	c	PROPN
iajs-2983	55	14	2	2	NUM
iajs-2983	55	15	h	h	NOUN
iajs-2983	55	16	5	5	NUM
iajs-2983	56	1	oh	oh	INTJ
iajs-2983	56	2	hcl	hcl	PROPN
iajs-2983	56	3	s	s	PROPN
iajs-2983	56	4	nn	nn	PROPN
iajs-2983	56	5	s	s	PROPN
iajs-2983	56	6	nh2hs	nh2hs	PROPN
iajs-2983	56	7	nn	nn	PROPN
iajs-2983	56	8	s	s	PROPN
iajs-2983	56	9	nh2hs	nh2hs	PROPN
iajs-2983	56	10	clch2ccl	clch2ccl	NOUN
iajs-2983	56	11	o	o	X
iajs-2983	56	12	nn	nn	X
iajs-2983	56	13	s	s	PROPN
iajs-2983	56	14	n	n	PRON
iajs-2983	56	15	h	h	NOUN
iajs-2983	56	16	hs	hs	PROPN
iajs-2983	56	17	c	c	PROPN
iajs-2983	56	18	ch2cl	ch2cl	NOUN
iajs-2983	56	19	o	o	NOUN
iajs-2983	56	20	2	2	NUM
iajs-2983	56	21	-	-	PUNCT
iajs-2983	56	22	chloro	chloro	NOUN
iajs-2983	56	23	-	-	PUNCT
iajs-2983	56	24	n	n	PRON
iajs-2983	56	25	-(5	-(5	NOUN
iajs-2983	56	26	-	-	PUNCT
iajs-2983	56	27	mercapto-1,3,4	mercapto-1,3,4	NOUN
iajs-2983	56	28	-	-	PUNCT
iajs-2983	56	29	thiadiazol-2	thiadiazol-2	NUM
iajs-2983	56	30	-	-	PUNCT
iajs-2983	56	31	yl)acetamide	yl)acetamide	NOUN
iajs-2983	56	32	2	2	NUM
iajs-2983	56	33	-	-	PUNCT
iajs-2983	56	34	amino-5	amino-5	NUM
iajs-2983	56	35	-	-	PUNCT
iajs-2983	56	36	mercapto-1,3,4	mercapto-1,3,4	ADJ
iajs-2983	56	37	thiadiazole	thiadiazole	PROPN
iajs-2983	56	38	nn	nn	PROPN
iajs-2983	56	39	s	s	PROPN
iajs-2983	56	40	n	n	PROPN
iajs-2983	56	41	h	h	NOUN
iajs-2983	56	42	hs	hs	PROPN
iajs-2983	56	43	c	c	PROPN
iajs-2983	56	44	ch2cl	ch2cl	PROPN
iajs-2983	56	45	o	o	NOUN
iajs-2983	56	46	n	n	CCONJ
iajs-2983	56	47	h	h	NOUN
iajs-2983	56	48	hcoh	hcoh	NOUN
iajs-2983	56	49	n	n	CCONJ
iajs-2983	57	1	n	n	PROPN
iajs-2983	57	2	s	s	NOUN
iajs-2983	57	3	s	s	NOUN
iajs-2983	57	4	h	h	NOUN
iajs-2983	57	5	ncclh2c	ncclh2c	PROPN
iajs-2983	58	1	o	o	PROPN
iajs-2983	58	2	h2	h2	PROPN
iajs-2983	58	3	c	c	PROPN
iajs-2983	58	4	n	n	CCONJ
iajs-2983	58	5	2	2	NUM
iajs-2983	58	6	-	-	PUNCT
iajs-2983	58	7	chloro	chloro	NOUN
iajs-2983	58	8	-	-	PUNCT
iajs-2983	58	9	n	n	NOUN
iajs-2983	58	10	-(5-(piperidin-1	-(5-(piperidin-1	NOUN
iajs-2983	58	11	-	-	PUNCT
iajs-2983	58	12	ylmethylthio)-1,3,4	ylmethylthio)-1,3,4	ADJ
iajs-2983	58	13	-	-	PUNCT
iajs-2983	58	14	thiadiazol-2	thiadiazol-2	NUM
iajs-2983	58	15	-	-	PUNCT
iajs-2983	58	16	yl)acetamide	yl)acetamide	NOUN
iajs-2983	58	17	reflux	reflux	NOUN
iajs-2983	58	18	3hrs	3hrs	NUM
iajs-2983	58	19	°	°	PROPN
iajs-2983	58	20	reflux	reflux	NOUN
iajs-2983	58	21	6hrs	6hrs	NUM
iajs-2983	58	22	scheme	scheme	NOUN
iajs-2983	58	23	1	1	NUM
iajs-2983	58	24	.	.	PUNCT
iajs-2983	58	25	synthesis	synthesis	NOUN
iajs-2983	58	26	of	of	ADP
iajs-2983	58	27	mannich	mannich	PRON
iajs-2983	58	28	base	base	NOUN
iajs-2983	58	29	,	,	PUNCT
iajs-2983	58	30	2chloro	2chloro	NUM
iajs-2983	58	31	–	–	PUNCT
iajs-2983	58	32	n-5-(piperidin	n-5-(piperidin	VERB
iajs-2983	58	33	-1	-1	NOUN
iajs-2983	58	34	-	-	PUNCT
iajs-2983	58	35	ylmethylthio)-1	ylmethylthio)-1	ADJ
iajs-2983	58	36	,	,	PUNCT
iajs-2983	58	37	3	3	NUM
iajs-2983	58	38	,	,	PUNCT
iajs-2983	58	39	4thiadiazol-2	4thiadiazol-2	NUM
iajs-2983	58	40	-	-	PUNCT
iajs-2983	58	41	yl)acetamide	yl)acetamide	NOUN
iajs-2983	58	42	(	(	PUNCT
iajs-2983	58	43	l	l	NOUN
iajs-2983	58	44	)	)	PUNCT
iajs-2983	58	45	2.2	2.2	NUM
iajs-2983	58	46	.	.	PUNCT
iajs-2983	59	1	synthesis	synthesis	NOUN
iajs-2983	59	2	of	of	ADP
iajs-2983	59	3	complexes	complex	NOUN
iajs-2983	59	4	in	in	ADP
iajs-2983	59	5	the	the	DET
iajs-2983	59	6	presence	presence	NOUN
iajs-2983	59	7	of	of	ADP
iajs-2983	59	8	ethyl	ethyl	PROPN
iajs-2983	59	9	alcohol	alcohol	NOUN
iajs-2983	59	10	solvent	solvent	NOUN
iajs-2983	59	11	,	,	PUNCT
iajs-2983	59	12	some	some	DET
iajs-2983	59	13	mannich	mannich	NOUN
iajs-2983	59	14	base	base	NOUN
iajs-2983	59	15	complexes	complex	NOUN
iajs-2983	59	16	can	can	AUX
iajs-2983	59	17	be	be	AUX
iajs-2983	59	18	prepared	prepare	VERB
iajs-2983	59	19	.	.	PUNCT
iajs-2983	60	1	the	the	DET
iajs-2983	60	2	ratio	ratio	NOUN
iajs-2983	60	3	1:1	1:1	NUM
iajs-2983	60	4	of	of	ADP
iajs-2983	60	5	cocl2.6h2o	cocl2.6h2o	NOUN
iajs-2983	60	6	,	,	PUNCT
iajs-2983	60	7	nicl2.6h2o	nicl2.6h2o	NOUN
iajs-2983	60	8	,	,	PUNCT
iajs-2983	60	9	cucl2.2h2o	cucl2.2h2o	NOUN
iajs-2983	60	10	,	,	PUNCT
iajs-2983	60	11	pdcl2	pdcl2	NOUN
iajs-2983	60	12	,	,	PUNCT
iajs-2983	60	13	h2ptcl6.6h2o	h2ptcl6.6h2o	NOUN
iajs-2983	60	14	,	,	PUNCT
iajs-2983	60	15	and	and	CCONJ
iajs-2983	60	16	haucl4.h2o	haucl4.h2o	NOUN
iajs-2983	60	17	and	and	CCONJ
iajs-2983	60	18	ligand	ligand	NOUN
iajs-2983	60	19	.	.	PUNCT
iajs-2983	61	1	then	then	ADV
iajs-2983	61	2	the	the	DET
iajs-2983	61	3	mixture	mixture	NOUN
iajs-2983	61	4	was	be	AUX
iajs-2983	61	5	refluxed	refluxe	VERB
iajs-2983	61	6	for	for	ADP
iajs-2983	61	7	3	3	NUM
iajs-2983	61	8	hours	hour	NOUN
iajs-2983	61	9	.	.	PUNCT
iajs-2983	62	1	the	the	DET
iajs-2983	62	2	resulting	result	VERB
iajs-2983	62	3	solids	solid	NOUN
iajs-2983	62	4	compounds	compound	NOUN
iajs-2983	62	5	were	be	AUX
iajs-2983	62	6	filtered	filter	VERB
iajs-2983	62	7	off	off	ADP
iajs-2983	62	8	,	,	PUNCT
iajs-2983	62	9	washed	wash	VERB
iajs-2983	62	10	with	with	ADP
iajs-2983	62	11	distilled	distil	VERB
iajs-2983	62	12	water	water	NOUN
iajs-2983	62	13	and	and	CCONJ
iajs-2983	62	14	ethanol	ethanol	NOUN
iajs-2983	62	15	,	,	PUNCT
iajs-2983	62	16	and	and	CCONJ
iajs-2983	62	17	dried	dry	VERB
iajs-2983	62	18	in	in	ADP
iajs-2983	62	19	a	a	DET
iajs-2983	62	20	desiccator	desiccator	NOUN
iajs-2983	62	21	.	.	PUNCT
iajs-2983	63	1	some	some	DET
iajs-2983	63	2	physical	physical	ADJ
iajs-2983	63	3	properties	property	NOUN
iajs-2983	63	4	can	can	AUX
iajs-2983	63	5	be	be	AUX
iajs-2983	63	6	observed	observe	VERB
iajs-2983	63	7	in	in	ADP
iajs-2983	63	8	table	table	NOUN
iajs-2983	63	9	1	1	NUM
iajs-2983	63	10	.	.	PUNCT
iajs-2983	64	1	ihjpas	ihjpas	PROPN
iajs-2983	64	2	.	.	PUNCT
iajs-2983	65	1	36(1)2023	36(1)2023	NUM
iajs-2983	65	2	263	263	NUM
iajs-2983	65	3	table	table	NOUN
iajs-2983	65	4	1	1	NUM
iajs-2983	65	5	.	.	PUNCT
iajs-2983	66	1	the	the	DET
iajs-2983	66	2	physical	physical	ADJ
iajs-2983	66	3	properties	property	NOUN
iajs-2983	66	4	of	of	ADP
iajs-2983	66	5	color	color	NOUN
iajs-2983	66	6	and	and	CCONJ
iajs-2983	66	7	melting	melting	NOUN
iajs-2983	66	8	point	point	NOUN
iajs-2983	66	9	in	in	ADP
iajs-2983	66	10	addition	addition	NOUN
iajs-2983	66	11	to	to	ADP
iajs-2983	66	12	the	the	DET
iajs-2983	66	13	values	value	NOUN
iajs-2983	66	14	of	of	ADP
iajs-2983	66	15	c.h.n.s	c.h.n.s	PROPN
iajs-2983	66	16	and	and	CCONJ
iajs-2983	66	17	the	the	DET
iajs-2983	66	18	percentage	percentage	NOUN
iajs-2983	66	19	of	of	ADP
iajs-2983	66	20	all	all	DET
iajs-2983	66	21	prepared	prepare	VERB
iajs-2983	66	22	compounds	compound	NOUN
iajs-2983	66	23	elemental	elemental	ADJ
iajs-2983	66	24	analysis	analysis	NOUN
iajs-2983	66	25	calc	calc	NOUN
iajs-2983	66	26	.	.	PUNCT
iajs-2983	67	1	(	(	PUNCT
iajs-2983	67	2	found	find	VERB
iajs-2983	67	3	)	)	PUNCT
iajs-2983	67	4	atomic	atomic	ADJ
iajs-2983	67	5	abs.%	abs.%	NOUN
iajs-2983	67	6	cal.(found	cal.(found	NOUN
iajs-2983	67	7	)	)	PUNCT
iajs-2983	67	8	yield	yield	NOUN
iajs-2983	67	9	%	%	INTJ
iajs-2983	67	10	m.p	m.p	PROPN
iajs-2983	67	11	/	/	SYM
iajs-2983	67	12	c0	c0	PROPN
iajs-2983	67	13	color	color	PROPN
iajs-2983	67	14	comp	comp	PROPN
iajs-2983	67	15	.	.	PUNCT
iajs-2983	68	1	s	s	VERB
iajs-2983	68	2	n	n	DET
iajs-2983	68	3	h	h	NOUN
iajs-2983	68	4	c	c	NOUN
iajs-2983	68	5	20.85	20.85	NUM
iajs-2983	68	6	(	(	PUNCT
iajs-2983	68	7	21.34	21.34	NUM
iajs-2983	68	8	)	)	PUNCT
iajs-2983	68	9	18.25	18.25	NUM
iajs-2983	68	10	(	(	PUNCT
iajs-2983	68	11	19.01	19.01	NUM
iajs-2983	68	12	)	)	PUNCT
iajs-2983	68	13	4.88	4.88	NUM
iajs-2983	68	14	(	(	PUNCT
iajs-2983	68	15	3.98	3.98	NUM
iajs-2983	68	16	)	)	PUNCT
iajs-2983	68	17	39.10	39.10	NUM
iajs-2983	68	18	(	(	PUNCT
iajs-2983	68	19	38.66	38.66	NUM
iajs-2983	68	20	)	)	PUNCT
iajs-2983	68	21	---76	---76	X
iajs-2983	68	22	over	over	ADP
iajs-2983	68	23	300	300	NUM
iajs-2983	68	24	brown	brown	ADJ
iajs-2983	68	25	mannich	mannich	NOUN
iajs-2983	68	26	(	(	PUNCT
iajs-2983	68	27	l	l	NOUN
iajs-2983	68	28	)	)	PUNCT
iajs-2983	68	29	13.28	13.28	NUM
iajs-2983	68	30	(	(	PUNCT
iajs-2983	68	31	14.00	14.00	NUM
iajs-2983	68	32	)	)	PUNCT
iajs-2983	68	33	11.62	11.62	NUM
iajs-2983	68	34	(	(	PUNCT
iajs-2983	68	35	12.78	12.78	NUM
iajs-2983	68	36	)	)	PUNCT
iajs-2983	68	37	4.15	4.15	NUM
iajs-2983	68	38	(	(	PUNCT
iajs-2983	68	39	3.76	3.76	NUM
iajs-2983	68	40	)	)	PUNCT
iajs-2983	68	41	24.90	24.90	NUM
iajs-2983	68	42	(	(	PUNCT
iajs-2983	68	43	23.78	23.78	NUM
iajs-2983	68	44	)	)	PUNCT
iajs-2983	68	45	12.22	12.22	NUM
iajs-2983	68	46	80	80	NUM
iajs-2983	68	47	118	118	NUM
iajs-2983	68	48	-	-	SYM
iajs-2983	68	49	120	120	NUM
iajs-2983	68	50	dark	dark	ADJ
iajs-2983	68	51	green	green	PROPN
iajs-2983	68	52	col	col	PROPN
iajs-2983	68	53	13.04	13.04	NUM
iajs-2983	68	54	(	(	PUNCT
iajs-2983	68	55	12.87	12.87	NUM
iajs-2983	68	56	)	)	PUNCT
iajs-2983	68	57	11.00	11.00	NUM
iajs-2983	68	58	(	(	PUNCT
iajs-2983	68	59	10.94	10.94	NUM
iajs-2983	68	60	)	)	PUNCT
iajs-2983	68	61	3.87	3.87	NUM
iajs-2983	68	62	(	(	PUNCT
iajs-2983	68	63	4.08	4.08	NUM
iajs-2983	68	64	)	)	PUNCT
iajs-2983	68	65	24.46	24.46	NUM
iajs-2983	68	66	(	(	PUNCT
iajs-2983	68	67	25.11	25.11	NUM
iajs-2983	68	68	)	)	PUNCT
iajs-2983	68	69	11.96	11.96	NUM
iajs-2983	68	70	76	76	NUM
iajs-2983	68	71	182	182	NUM
iajs-2983	68	72	-	-	SYM
iajs-2983	68	73	185	185	NUM
iajs-2983	68	74	light	light	ADJ
iajs-2983	68	75	green	green	ADJ
iajs-2983	68	76	nil	nil	NOUN
iajs-2983	68	77	12.92	12.92	NUM
iajs-2983	68	78	(	(	PUNCT
iajs-2983	68	79	13.67	13.67	NUM
iajs-2983	68	80	)	)	PUNCT
iajs-2983	68	81	10.90	10.90	NUM
iajs-2983	68	82	(	(	PUNCT
iajs-2983	68	83	11.05	11.05	NUM
iajs-2983	68	84	)	)	PUNCT
iajs-2983	68	85	4.23	4.23	NUM
iajs-2983	68	86	(	(	PUNCT
iajs-2983	68	87	5.12	5.12	NUM
iajs-2983	68	88	)	)	PUNCT
iajs-2983	68	89	24.22	24.22	NUM
iajs-2983	68	90	(	(	PUNCT
iajs-2983	68	91	23.20	23.20	NUM
iajs-2983	68	92	)	)	PUNCT
iajs-2983	68	93	12.81	12.81	NUM
iajs-2983	68	94	84	84	NUM
iajs-2983	68	95	167	167	NUM
iajs-2983	68	96	-	-	SYM
iajs-2983	68	97	170	170	NUM
iajs-2983	68	98	dark	dark	ADJ
iajs-2983	68	99	brown	brown	PROPN
iajs-2983	68	100	cul	cul	PROPN
iajs-2983	68	101	10.51	10.51	NUM
iajs-2983	68	102	(	(	PUNCT
iajs-2983	68	103	11.41	11.41	NUM
iajs-2983	68	104	)	)	PUNCT
iajs-2983	68	105	8.87	8.87	NUM
iajs-2983	68	106	(	(	PUNCT
iajs-2983	68	107	9.11	9.11	NUM
iajs-2983	68	108	)	)	PUNCT
iajs-2983	68	109	2.46	2.46	NUM
iajs-2983	68	110	(	(	PUNCT
iajs-2983	68	111	3.45	3.45	NUM
iajs-2983	68	112	)	)	PUNCT
iajs-2983	68	113	19.72	19.72	NUM
iajs-2983	68	114	(	(	PUNCT
iajs-2983	68	115	18.77	18.77	NUM
iajs-2983	68	116	)	)	PUNCT
iajs-2983	68	117	32.06	32.06	NUM
iajs-2983	68	118	67	67	NUM
iajs-2983	68	119	218	218	NUM
iajs-2983	68	120	-	-	SYM
iajs-2983	68	121	221	221	NUM
iajs-2983	68	122	brown	brown	ADJ
iajs-2983	68	123	pdl	pdl	PROPN
iajs-2983	68	124	12.74	12.74	NUM
iajs-2983	68	125	(	(	PUNCT
iajs-2983	68	126	11.93	11.93	NUM
iajs-2983	68	127	)	)	PUNCT
iajs-2983	68	128	10.75	10.75	NUM
iajs-2983	68	129	(	(	PUNCT
iajs-2983	68	130	11.44	11.44	NUM
iajs-2983	68	131	)	)	PUNCT
iajs-2983	68	132	3.38	3.38	NUM
iajs-2983	68	133	(	(	PUNCT
iajs-2983	68	134	4.18	4.18	NUM
iajs-2983	68	135	)	)	PUNCT
iajs-2983	68	136	23.89	23.89	NUM
iajs-2983	68	137	(	(	PUNCT
iajs-2983	68	138	24.02	24.02	NUM
iajs-2983	68	139	)	)	PUNCT
iajs-2983	68	140	21.88	21.88	NUM
iajs-2983	68	141	74	74	NUM
iajs-2983	68	142	202	202	NUM
iajs-2983	68	143	-	-	SYM
iajs-2983	68	144	205	205	NUM
iajs-2983	68	145	dark	dark	ADJ
iajs-2983	68	146	brown	brown	NOUN
iajs-2983	68	147	ptl	ptl	PROPN
iajs-2983	68	148	10.48	10.48	NUM
iajs-2983	68	149	(	(	PUNCT
iajs-2983	68	150	11.05	11.05	NUM
iajs-2983	68	151	)	)	PUNCT
iajs-2983	68	152	8.84	8.84	NUM
iajs-2983	68	153	(	(	PUNCT
iajs-2983	68	154	9.94	9.94	NUM
iajs-2983	68	155	)	)	PUNCT
iajs-2983	68	156	2.45	2.45	NUM
iajs-2983	68	157	(	(	PUNCT
iajs-2983	68	158	3.04	3.04	NUM
iajs-2983	68	159	)	)	PUNCT
iajs-2983	68	160	19.62	19.62	NUM
iajs-2983	68	161	(	(	PUNCT
iajs-2983	68	162	18.56	18.56	NUM
iajs-2983	68	163	)	)	PUNCT
iajs-2983	68	164	32.27	32.27	NUM
iajs-2983	68	165	77	77	NUM
iajs-2983	68	166	212	212	NUM
iajs-2983	68	167	-	-	SYM
iajs-2983	68	168	215	215	NUM
iajs-2983	68	169	green	green	ADJ
iajs-2983	68	170	aul	aul	NOUN
iajs-2983	68	171	theortical	theortical	ADJ
iajs-2983	68	172	study	study	NOUN
iajs-2983	68	173	in	in	ADP
iajs-2983	68	174	the	the	DET
iajs-2983	68	175	theoretical	theoretical	ADJ
iajs-2983	68	176	study	study	NOUN
iajs-2983	68	177	and	and	CCONJ
iajs-2983	68	178	using	use	VERB
iajs-2983	68	179	the	the	DET
iajs-2983	68	180	hyperchem	hyperchem	NOUN
iajs-2983	68	181	8.0.7	8.0.7	NUM
iajs-2983	68	182	program	program	NOUN
iajs-2983	68	183	,	,	PUNCT
iajs-2983	68	184	the	the	DET
iajs-2983	68	185	standard	standard	ADJ
iajs-2983	68	186	heat	heat	NOUN
iajs-2983	68	187	of	of	ADP
iajs-2983	68	188	formation	formation	NOUN
iajs-2983	68	189	and	and	CCONJ
iajs-2983	68	190	binding	bind	VERB
iajs-2983	68	191	energy	energy	NOUN
iajs-2983	68	192	was	be	AUX
iajs-2983	68	193	calculated	calculate	VERB
iajs-2983	68	194	for	for	ADP
iajs-2983	68	195	all	all	DET
iajs-2983	68	196	prepared	prepare	VERB
iajs-2983	68	197	compounds	compound	NOUN
iajs-2983	68	198	by	by	ADP
iajs-2983	68	199	pm3	pm3	PROPN
iajs-2983	68	200	,	,	PUNCT
iajs-2983	68	201	zindo\i	zindo\i	NOUN
iajs-2983	68	202	,	,	PUNCT
iajs-2983	68	203	and	and	CCONJ
iajs-2983	68	204	amber	amber	PROPN
iajs-2983	68	205	.	.	PUNCT
iajs-2983	69	1	the	the	DET
iajs-2983	69	2	homo	homo	NOUN
iajs-2983	69	3	and	and	CCONJ
iajs-2983	69	4	lumo	lumo	NOUN
iajs-2983	69	5	were	be	AUX
iajs-2983	69	6	calculated	calculate	VERB
iajs-2983	69	7	to	to	PART
iajs-2983	69	8	determine	determine	VERB
iajs-2983	69	9	the	the	DET
iajs-2983	69	10	active	active	ADJ
iajs-2983	69	11	sites	site	NOUN
iajs-2983	69	12	in	in	ADP
iajs-2983	69	13	the	the	DET
iajs-2983	69	14	ligand	ligand	ADJ
iajs-2983	69	15	molecule	molecule	NOUN
iajs-2983	69	16	.	.	PUNCT
iajs-2983	70	1	the	the	DET
iajs-2983	70	2	vibration	vibration	NOUN
iajs-2983	70	3	frequencies	frequency	NOUN
iajs-2983	70	4	were	be	AUX
iajs-2983	70	5	calculated	calculate	VERB
iajs-2983	70	6	theoretically	theoretically	ADV
iajs-2983	70	7	for	for	ADP
iajs-2983	70	8	the	the	DET
iajs-2983	70	9	ligand	ligand	ADJ
iajs-2983	70	10	pm3	pm3	PROPN
iajs-2983	70	11	method	method	NOUN
iajs-2983	70	12	,	,	PUNCT
iajs-2983	70	13	the	the	DET
iajs-2983	70	14	practical	practical	ADJ
iajs-2983	70	15	results	result	NOUN
iajs-2983	70	16	were	be	AUX
iajs-2983	70	17	compared	compare	VERB
iajs-2983	70	18	with	with	ADP
iajs-2983	70	19	the	the	DET
iajs-2983	70	20	theoretical	theoretical	ADJ
iajs-2983	70	21	results	result	NOUN
iajs-2983	70	22	,	,	PUNCT
iajs-2983	70	23	and	and	CCONJ
iajs-2983	70	24	the	the	DET
iajs-2983	70	25	error	error	NOUN
iajs-2983	70	26	ratio	ratio	NOUN
iajs-2983	70	27	between	between	ADP
iajs-2983	70	28	them	they	PRON
iajs-2983	70	29	was	be	AUX
iajs-2983	70	30	calculated	calculate	VERB
iajs-2983	70	31	,	,	PUNCT
iajs-2983	70	32	which	which	PRON
iajs-2983	70	33	was	be	AUX
iajs-2983	70	34	acceptable	acceptable	ADJ
iajs-2983	70	35	.	.	PUNCT
iajs-2983	71	1	antibacterial	antibacterial	ADJ
iajs-2983	71	2	and	and	CCONJ
iajs-2983	71	3	antifungal	antifungal	ADJ
iajs-2983	71	4	activity	activity	NOUN
iajs-2983	71	5	1.40	1.40	NUM
iajs-2983	71	6	g	g	NOUN
iajs-2983	71	7	of	of	ADP
iajs-2983	71	8	culture	culture	NOUN
iajs-2983	71	9	medium	medium	NOUN
iajs-2983	71	10	for	for	ADP
iajs-2983	71	11	bacteria	bacteria	NOUN
iajs-2983	71	12	and	and	CCONJ
iajs-2983	71	13	fungi	fungus	NOUN
iajs-2983	71	14	was	be	AUX
iajs-2983	71	15	dissolved	dissolve	VERB
iajs-2983	71	16	in	in	ADP
iajs-2983	71	17	a	a	DET
iajs-2983	71	18	liter	liter	NOUN
iajs-2983	71	19	of	of	ADP
iajs-2983	71	20	distilled	distilled	ADJ
iajs-2983	71	21	water	water	NOUN
iajs-2983	71	22	,	,	PUNCT
iajs-2983	71	23	as	as	ADP
iajs-2983	71	24	the	the	DET
iajs-2983	71	25	culture	culture	NOUN
iajs-2983	71	26	medium	medium	NOUN
iajs-2983	71	27	used	use	VERB
iajs-2983	71	28	for	for	ADP
iajs-2983	71	29	bacteria	bacteria	NOUN
iajs-2983	71	30	(	(	PUNCT
iajs-2983	71	31	agar	agar	NOUN
iajs-2983	71	32	mueller	mueller	PROPN
iajs-2983	71	33	hinton	hinton	PROPN
iajs-2983	71	34	)	)	PUNCT
iajs-2983	71	35	and	and	CCONJ
iajs-2983	71	36	for	for	ADP
iajs-2983	71	37	fungi	fungi	PROPN
iajs-2983	71	38	(	(	PUNCT
iajs-2983	71	39	sabroid	sabroid	NOUN
iajs-2983	71	40	dextroes	dextroe	VERB
iajs-2983	71	41	agar	agar	NOUN
iajs-2983	71	42	)	)	PUNCT
iajs-2983	71	43	.	.	PUNCT
iajs-2983	72	1	2.after	2.after	NUM
iajs-2983	72	2	dissolving	dissolve	VERB
iajs-2983	72	3	by	by	ADP
iajs-2983	72	4	heating	heating	NOUN
iajs-2983	72	5	,	,	PUNCT
iajs-2983	72	6	the	the	DET
iajs-2983	72	7	culture	culture	NOUN
iajs-2983	72	8	medium	medium	NOUN
iajs-2983	72	9	was	be	AUX
iajs-2983	72	10	placed	place	VERB
iajs-2983	72	11	in	in	ADP
iajs-2983	72	12	the	the	DET
iajs-2983	72	13	sterilizer	sterilizer	NOUN
iajs-2983	72	14	for	for	ADP
iajs-2983	72	15	15	15	NUM
iajs-2983	72	16	minutes	minute	NOUN
iajs-2983	72	17	,	,	PUNCT
iajs-2983	72	18	then	then	ADV
iajs-2983	72	19	poured	pour	VERB
iajs-2983	72	20	into	into	ADP
iajs-2983	72	21	sterilized	sterilize	VERB
iajs-2983	72	22	plastic	plastic	ADJ
iajs-2983	72	23	dishes	dish	NOUN
iajs-2983	72	24	and	and	CCONJ
iajs-2983	72	25	left	leave	VERB
iajs-2983	72	26	to	to	PART
iajs-2983	72	27	solidify	solidify	VERB
iajs-2983	72	28	.	.	PUNCT
iajs-2983	73	1	3.a	3.a	NUM
iajs-2983	73	2	hole	hole	NOUN
iajs-2983	73	3	was	be	AUX
iajs-2983	73	4	made	make	VERB
iajs-2983	73	5	using	use	VERB
iajs-2983	73	6	a	a	DET
iajs-2983	73	7	cork	cork	NOUN
iajs-2983	73	8	drill	drill	NOUN
iajs-2983	73	9	with	with	ADP
iajs-2983	73	10	a	a	DET
iajs-2983	73	11	diameter	diameter	NOUN
iajs-2983	73	12	of	of	ADP
iajs-2983	73	13	8	8	NUM
iajs-2983	73	14	mm	mm	NOUN
iajs-2983	73	15	to	to	PART
iajs-2983	73	16	add	add	VERB
iajs-2983	73	17	the	the	DET
iajs-2983	73	18	material	material	NOUN
iajs-2983	73	19	that	that	PRON
iajs-2983	73	20	inhibited	inhibit	VERB
iajs-2983	73	21	the	the	DET
iajs-2983	73	22	growth	growth	NOUN
iajs-2983	73	23	of	of	ADP
iajs-2983	73	24	bacteria	bacteria	NOUN
iajs-2983	73	25	and	and	CCONJ
iajs-2983	73	26	fungi	fungus	NOUN
iajs-2983	73	27	.	.	PUNCT
iajs-2983	74	1	4.the	4.the	DET
iajs-2983	74	2	prepared	prepare	VERB
iajs-2983	74	3	ligands	ligand	NOUN
iajs-2983	74	4	and	and	CCONJ
iajs-2983	74	5	complexes	complex	NOUN
iajs-2983	74	6	dissolved	dissolve	VERB
iajs-2983	74	7	in	in	ADP
iajs-2983	74	8	dmso	dmso	NOUN
iajs-2983	74	9	at	at	ADP
iajs-2983	74	10	a	a	DET
iajs-2983	74	11	concentration	concentration	NOUN
iajs-2983	74	12	of	of	ADP
iajs-2983	74	13	0.02	0.02	NUM
iajs-2983	74	14	m	m	VERB
iajs-2983	74	15	were	be	AUX
iajs-2983	74	16	injected	inject	VERB
iajs-2983	74	17	into	into	ADP
iajs-2983	74	18	the	the	DET
iajs-2983	74	19	pits	pit	NOUN
iajs-2983	74	20	of	of	ADP
iajs-2983	74	21	the	the	DET
iajs-2983	74	22	culture	culture	NOUN
iajs-2983	74	23	medium	medium	NOUN
iajs-2983	74	24	.	.	PUNCT
iajs-2983	75	1	5.the	5.the	DET
iajs-2983	75	2	dishes	dish	NOUN
iajs-2983	75	3	were	be	AUX
iajs-2983	75	4	placed	place	VERB
iajs-2983	75	5	in	in	ADP
iajs-2983	75	6	the	the	DET
iajs-2983	75	7	incubator	incubator	NOUN
iajs-2983	75	8	at	at	ADP
iajs-2983	75	9	37	37	NUM
iajs-2983	75	10	°	°	NOUN
iajs-2983	75	11	c	c	NOUN
iajs-2983	75	12	for	for	ADP
iajs-2983	75	13	24	24	NUM
iajs-2983	75	14	hour	hour	NOUN
iajs-2983	75	15	for	for	ADP
iajs-2983	75	16	antibacterial	antibacterial	ADJ
iajs-2983	75	17	activity	activity	NOUN
iajs-2983	75	18	and	and	CCONJ
iajs-2983	75	19	72	72	NUM
iajs-2983	75	20	hours	hour	NOUN
iajs-2983	75	21	for	for	ADP
iajs-2983	75	22	antifungal	antifungal	ADJ
iajs-2983	75	23	activity	activity	NOUN
iajs-2983	75	24	,	,	PUNCT
iajs-2983	75	25	then	then	ADV
iajs-2983	75	26	the	the	DET
iajs-2983	75	27	inhibition	inhibition	NOUN
iajs-2983	75	28	diameters	diameter	NOUN
iajs-2983	75	29	were	be	AUX
iajs-2983	75	30	measured	measure	VERB
iajs-2983	75	31	using	use	VERB
iajs-2983	75	32	a	a	DET
iajs-2983	75	33	ruler	ruler	NOUN
iajs-2983	75	34	in	in	ADP
iajs-2983	75	35	mm	mm	PROPN
iajs-2983	75	36	for	for	ADP
iajs-2983	75	37	each	each	PRON
iajs-2983	75	38	of	of	ADP
iajs-2983	75	39	the	the	DET
iajs-2983	75	40	prepared	prepare	VERB
iajs-2983	75	41	compounds	compound	NOUN
iajs-2983	75	42	.	.	PUNCT
iajs-2983	76	1	3	3	X
iajs-2983	76	2	.	.	NOUN
iajs-2983	76	3	results	result	NOUN
iajs-2983	76	4	and	and	CCONJ
iajs-2983	76	5	discussion	discussion	NOUN
iajs-2983	76	6	all	all	DET
iajs-2983	76	7	complexes	complex	NOUN
iajs-2983	76	8	were	be	AUX
iajs-2983	76	9	soluble	soluble	ADJ
iajs-2983	76	10	in	in	ADP
iajs-2983	76	11	organic	organic	ADJ
iajs-2983	76	12	solvents	solvent	NOUN
iajs-2983	76	13	dmf	dmf	PROPN
iajs-2983	76	14	&	&	CCONJ
iajs-2983	76	15	dmso	dmso	PROPN
iajs-2983	76	16	.	.	PUNCT
iajs-2983	77	1	the	the	DET
iajs-2983	77	2	ratio	ratio	NOUN
iajs-2983	77	3	of	of	ADP
iajs-2983	77	4	metal	metal	NOUN
iajs-2983	77	5	-	-	PUNCT
iajs-2983	77	6	ligand	ligand	NOUN
iajs-2983	77	7	was	be	AUX
iajs-2983	77	8	(	(	PUNCT
iajs-2983	77	9	1:1	1:1	NUM
iajs-2983	77	10	)	)	PUNCT
iajs-2983	77	11	the	the	DET
iajs-2983	77	12	ligand	ligand	NOUN
iajs-2983	77	13	,	,	PUNCT
iajs-2983	77	14	and	and	CCONJ
iajs-2983	77	15	their	their	PRON
iajs-2983	77	16	metal	metal	NOUN
iajs-2983	77	17	complexes	complex	NOUN
iajs-2983	77	18	were	be	AUX
iajs-2983	77	19	characterized	characterize	VERB
iajs-2983	77	20	:	:	PUNCT
iajs-2983	77	21	(	(	PUNCT
iajs-2983	77	22	ft	ft	PROPN
iajs-2983	77	23	-	-	PUNCT
iajs-2983	77	24	ir	ir	NOUN
iajs-2983	77	25	)	)	PUNCT
iajs-2983	77	26	,	,	PUNCT
iajs-2983	77	27	(	(	PUNCT
iajs-2983	77	28	uv	uv	NOUN
iajs-2983	77	29	-	-	PUNCT
iajs-2983	77	30	vis	vis	X
iajs-2983	77	31	)	)	PUNCT
iajs-2983	77	32	(	(	PUNCT
iajs-2983	77	33	1hnmr	1hnmr	NUM
iajs-2983	77	34	1hnmr	1hnmr	NUM
iajs-2983	77	35	and	and	CCONJ
iajs-2983	77	36	13cnmr	13cnmr	NUM
iajs-2983	77	37	,	,	PUNCT
iajs-2983	77	38	magnetic	magnetic	ADJ
iajs-2983	77	39	susceptibility	susceptibility	NOUN
iajs-2983	77	40	,	,	PUNCT
iajs-2983	77	41	and	and	CCONJ
iajs-2983	77	42	conductivity	conductivity	NOUN
iajs-2983	77	43	.	.	PUNCT
iajs-2983	78	1	ihjpas	ihjpas	PROPN
iajs-2983	78	2	.	.	PUNCT
iajs-2983	79	1	36(1)2023	36(1)2023	NUM
iajs-2983	79	2	264	264	NUM
iajs-2983	79	3	fourier	fourier	NOUN
iajs-2983	79	4	transforms	transform	VERB
iajs-2983	79	5	spectroscopy	spectroscopy	NOUN
iajs-2983	79	6	(	(	PUNCT
iajs-2983	79	7	ft	ft	NOUN
iajs-2983	79	8	-	-	PUNCT
iajs-2983	79	9	ir	ir	NOUN
iajs-2983	79	10	)	)	PUNCT
iajs-2983	79	11	of	of	ADP
iajs-2983	79	12	mannich	mannich	DET
iajs-2983	79	13	ligand	ligand	NOUN
iajs-2983	79	14	(	(	PUNCT
iajs-2983	79	15	l	l	NOUN
iajs-2983	79	16	)	)	PUNCT
iajs-2983	79	17	,	,	PUNCT
iajs-2983	79	18	and	and	CCONJ
iajs-2983	79	19	metal	metal	NOUN
iajs-2983	79	20	complexes	complex	NOUN
iajs-2983	79	21	ft	ft	PROPN
iajs-2983	79	22	-	-	PUNCT
iajs-2983	79	23	ir	ir	NOUN
iajs-2983	79	24	spectra	spectra	NOUN
iajs-2983	79	25	of	of	ADP
iajs-2983	79	26	all	all	DET
iajs-2983	79	27	prepared	prepared	ADJ
iajs-2983	79	28	compounds	compound	NOUN
iajs-2983	79	29	were	be	AUX
iajs-2983	79	30	carried	carry	VERB
iajs-2983	79	31	out	out	ADP
iajs-2983	79	32	in	in	ADP
iajs-2983	79	33	4000	4000	NUM
iajs-2983	79	34	to	to	ADP
iajs-2983	79	35	200	200	NUM
iajs-2983	79	36	cm-1	cm-1	NOUN
iajs-2983	79	37	.	.	PUNCT
iajs-2983	80	1	the	the	DET
iajs-2983	80	2	infrared	infrared	ADJ
iajs-2983	80	3	spectra	spectra	NOUN
iajs-2983	80	4	of	of	ADP
iajs-2983	80	5	mannich	mannich	DET
iajs-2983	80	6	ligand	ligand	PROPN
iajs-2983	80	7	l	l	NOUN
iajs-2983	80	8	and	and	CCONJ
iajs-2983	80	9	metal	metal	NOUN
iajs-2983	80	10	complexes	complex	NOUN
iajs-2983	80	11	appeared	appear	VERB
iajs-2983	80	12	the	the	DET
iajs-2983	80	13	active	active	ADJ
iajs-2983	80	14	site	site	NOUN
iajs-2983	80	15	number	number	NOUN
iajs-2983	80	16	at	at	ADP
iajs-2983	80	17	1701	1701	NUM
iajs-2983	80	18	,	,	PUNCT
iajs-2983	80	19	720,1161	720,1161	NUM
iajs-2983	80	20	,	,	PUNCT
iajs-2983	80	21	2943	2943	NUM
iajs-2983	80	22	,	,	PUNCT
iajs-2983	80	23	2854	2854	NUM
iajs-2983	80	24	,	,	PUNCT
iajs-2983	80	25	and	and	CCONJ
iajs-2983	80	26	1620	1620	NUM
iajs-2983	80	27	)	)	PUNCT
iajs-2983	80	28	cm-1which	cm-1which	PROPN
iajs-2983	80	29	was	be	AUX
iajs-2983	80	30	due	due	ADJ
iajs-2983	80	31	to	to	ADP
iajs-2983	80	32	[	[	X
iajs-2983	80	33	(	(	PUNCT
iajs-2983	80	34	υ	υ	PROPN
iajs-2983	80	35	co)υ	co)υ	PROPN
iajs-2983	80	36	,	,	PUNCT
iajs-2983	80	37	cs))υ	cs))υ	PROPN
iajs-2983	80	38	,	,	PUNCT
iajs-2983	80	39	c	c	PROPN
iajs-2983	80	40	s	s	PROPN
iajs-2983	80	41	c	c	NOUN
iajs-2983	80	42	)	)	PUNCT
iajs-2983	80	43	υ	υ	NOUN
iajs-2983	80	44	ch2n	ch2n	PROPN
iajs-2983	80	45	and	and	CCONJ
iajs-2983	80	46	c	c	NOUN
iajs-2983	80	47	=	=	NOUN
iajs-2983	80	48	n1,3,4thio	n1,3,4thio	NOUN
iajs-2983	80	49	.	.	PUNCT
iajs-2983	80	50	]	]	PUNCT
iajs-2983	81	1	sequentially[15].when	sequentially[15].when	ADV
iajs-2983	81	2	a	a	DET
iajs-2983	81	3	metal	metal	NOUN
iajs-2983	81	4	ion	ion	NOUN
iajs-2983	81	5	was	be	AUX
iajs-2983	81	6	bonded	bond	VERB
iajs-2983	81	7	to	to	ADP
iajs-2983	81	8	the	the	DET
iajs-2983	81	9	ligand	ligand	NOUN
iajs-2983	81	10	through	through	ADP
iajs-2983	81	11	the	the	DET
iajs-2983	81	12	nitrogen	nitrogen	NOUN
iajs-2983	81	13	atom	atom	NOUN
iajs-2983	81	14	of	of	ADP
iajs-2983	81	15	c	c	NOUN
iajs-2983	81	16	=	=	NOUN
iajs-2983	81	17	n	n	PRON
iajs-2983	81	18	1,3	1,3	NUM
iajs-2983	81	19	,	,	PUNCT
iajs-2983	81	20	4thio	4thio	NUM
iajs-2983	81	21	absorption	absorption	NOUN
iajs-2983	81	22	bands	band	NOUN
iajs-2983	81	23	shifted	shift	VERB
iajs-2983	81	24	towards	towards	ADP
iajs-2983	81	25	frequencies	frequency	NOUN
iajs-2983	81	26	within	within	ADP
iajs-2983	81	27	the	the	DET
iajs-2983	81	28	range	range	NOUN
iajs-2983	81	29	(	(	PUNCT
iajs-2983	81	30	1602	1602	NUM
iajs-2983	81	31	-	-	SYM
iajs-2983	81	32	1658	1658	NUM
iajs-2983	81	33	)	)	PUNCT
iajs-2983	81	34	cm-1	cm-1	PROPN
iajs-2983	81	35	in	in	ADP
iajs-2983	81	36	cobalt	cobalt	NOUN
iajs-2983	81	37	,	,	PUNCT
iajs-2983	81	38	nickel	nickel	NOUN
iajs-2983	81	39	,	,	PUNCT
iajs-2983	81	40	copper	copper	NOUN
iajs-2983	81	41	,	,	PUNCT
iajs-2983	81	42	palladium	palladium	NOUN
iajs-2983	81	43	,	,	PUNCT
iajs-2983	81	44	platin	platin	NOUN
iajs-2983	81	45	,	,	PUNCT
iajs-2983	81	46	and	and	CCONJ
iajs-2983	81	47	gold	gold	NOUN
iajs-2983	81	48	complexes	complex	NOUN
iajs-2983	81	49	,	,	PUNCT
iajs-2983	81	50	respectively	respectively	ADV
iajs-2983	81	51	.	.	PUNCT
iajs-2983	82	1	in	in	ADP
iajs-2983	82	2	other	other	ADJ
iajs-2983	82	3	absorption	absorption	NOUN
iajs-2983	82	4	bands	band	NOUN
iajs-2983	82	5	,	,	PUNCT
iajs-2983	82	6	the	the	DET
iajs-2983	82	7	carbonyl	carbonyl	NOUN
iajs-2983	82	8	group	group	NOUN
iajs-2983	82	9	(	(	PUNCT
iajs-2983	82	10	c	c	NOUN
iajs-2983	82	11	=	=	NOUN
iajs-2983	82	12	o	o	NOUN
iajs-2983	82	13	)	)	PUNCT
iajs-2983	82	14	has	have	AUX
iajs-2983	82	15	been	be	AUX
iajs-2983	82	16	shifted	shift	VERB
iajs-2983	82	17	according	accord	VERB
iajs-2983	82	18	to	to	ADP
iajs-2983	82	19	the	the	DET
iajs-2983	82	20	frequencies	frequency	NOUN
iajs-2983	82	21	(	(	PUNCT
iajs-2983	82	22	1728	1728	NUM
iajs-2983	82	23	,	,	PUNCT
iajs-2983	82	24	1728	1728	NUM
iajs-2983	82	25	,	,	PUNCT
iajs-2983	82	26	1691	1691	NUM
iajs-2983	82	27	,	,	PUNCT
iajs-2983	82	28	1690	1690	NUM
iajs-2983	82	29	,	,	PUNCT
iajs-2983	82	30	1686	1686	NUM
iajs-2983	82	31	,	,	PUNCT
iajs-2983	82	32	1722	1722	NUM
iajs-2983	82	33	)	)	PUNCT
iajs-2983	82	34	cm-1	cm-1	PROPN
iajs-2983	82	35	.	.	PUNCT
iajs-2983	83	1	in	in	ADP
iajs-2983	83	2	all	all	DET
iajs-2983	83	3	the	the	DET
iajs-2983	83	4	prepared	prepared	ADJ
iajs-2983	83	5	complexes	complex	NOUN
iajs-2983	83	6	oxygen	oxygen	NOUN
iajs-2983	83	7	of	of	ADP
iajs-2983	83	8	carbonyl	carbonyl	NOUN
iajs-2983	83	9	,	,	PUNCT
iajs-2983	83	10	υ	υ	NOUN
iajs-2983	83	11	c	c	NOUN
iajs-2983	83	12	=	=	NOUN
iajs-2983	83	13	o	o	NOUN
iajs-2983	83	14	took	take	VERB
iajs-2983	83	15	place	place	NOUN
iajs-2983	83	16	in	in	ADP
iajs-2983	83	17	coordination	coordination	NOUN
iajs-2983	83	18	.	.	PUNCT
iajs-2983	84	1	this	this	DET
iajs-2983	84	2	supported	support	VERB
iajs-2983	84	3	compatibility	compatibility	NOUN
iajs-2983	84	4	with	with	ADP
iajs-2983	84	5	the	the	DET
iajs-2983	84	6	c	c	PROPN
iajs-2983	84	7	=	=	PROPN
iajs-2983	84	8	o	o	NOUN
iajs-2983	84	9	group	group	NOUN
iajs-2983	84	10	[	[	X
iajs-2983	84	11	16	16	NUM
iajs-2983	84	12	]	]	PUNCT
iajs-2983	84	13	.	.	PUNCT
iajs-2983	85	1	we	we	PRON
iajs-2983	85	2	also	also	ADV
iajs-2983	85	3	noticed	notice	VERB
iajs-2983	85	4	a	a	DET
iajs-2983	85	5	shift	shift	NOUN
iajs-2983	85	6	in	in	ADP
iajs-2983	85	7	cs	cs	PROPN
iajs-2983	85	8	and	and	CCONJ
iajs-2983	85	9	csc	csc	PROPN
iajs-2983	85	10	groups	group	NOUN
iajs-2983	85	11	for	for	ADP
iajs-2983	85	12	each	each	PRON
iajs-2983	85	13	of	of	ADP
iajs-2983	85	14	the	the	DET
iajs-2983	85	15	co(ii	co(ii	PROPN
iajs-2983	85	16	)	)	PUNCT
iajs-2983	85	17	,	,	PUNCT
iajs-2983	85	18	ni(ii	ni(ii	PROPN
iajs-2983	85	19	)	)	PUNCT
iajs-2983	85	20	,	,	PUNCT
iajs-2983	85	21	cu(ii	cu(ii	PROPN
iajs-2983	85	22	)	)	PUNCT
iajs-2983	85	23	,	,	PUNCT
iajs-2983	85	24	pd(ii	pd(ii	PROPN
iajs-2983	85	25	)	)	PUNCT
iajs-2983	85	26	,	,	PUNCT
iajs-2983	85	27	pt(iv	pt(iv	PROPN
iajs-2983	85	28	)	)	PUNCT
iajs-2983	85	29	,	,	PUNCT
iajs-2983	85	30	and	and	CCONJ
iajs-2983	85	31	au(iii	au(iii	X
iajs-2983	85	32	)	)	PUNCT
iajs-2983	85	33	complexes	complex	NOUN
iajs-2983	85	34	,	,	PUNCT
iajs-2983	85	35	which	which	PRON
iajs-2983	85	36	indicated	indicate	VERB
iajs-2983	85	37	the	the	DET
iajs-2983	85	38	occurrence	occurrence	NOUN
iajs-2983	85	39	of	of	ADP
iajs-2983	85	40	coordination	coordination	NOUN
iajs-2983	85	41	through	through	ADP
iajs-2983	85	42	them	they	PRON
iajs-2983	85	43	.	.	PUNCT
iajs-2983	86	1	according	accord	VERB
iajs-2983	86	2	to	to	ADP
iajs-2983	86	3	these	these	DET
iajs-2983	86	4	results	result	NOUN
iajs-2983	86	5	,	,	PUNCT
iajs-2983	86	6	the	the	DET
iajs-2983	86	7	coordination	coordination	NOUN
iajs-2983	86	8	made	make	VERB
iajs-2983	86	9	of	of	ADP
iajs-2983	86	10	this	this	DET
iajs-2983	86	11	ligand	ligand	NOUN
iajs-2983	86	12	was	be	AUX
iajs-2983	86	13	predicted	predict	VERB
iajs-2983	86	14	as	as	ADP
iajs-2983	86	15	a	a	DET
iajs-2983	86	16	tridentate	tridentate	NOUN
iajs-2983	86	17	through	through	ADP
iajs-2983	86	18	νc	νc	X
iajs-2983	86	19	=	=	SYM
iajs-2983	86	20	n	n	CCONJ
iajs-2983	86	21	,	,	PUNCT
iajs-2983	86	22	νc	νc	NOUN
iajs-2983	86	23	=	=	ADJ
iajs-2983	86	24	o	o	NOUN
iajs-2983	86	25	group	group	NOUN
iajs-2983	86	26	,	,	PUNCT
iajs-2983	86	27	and	and	CCONJ
iajs-2983	86	28	sulfur	sulfur	NOUN
iajs-2983	86	29	[	[	X
iajs-2983	86	30	17	17	NUM
iajs-2983	86	31	]	]	PUNCT
iajs-2983	86	32	.	.	PUNCT
iajs-2983	87	1	other	other	ADJ
iajs-2983	87	2	bands	band	NOUN
iajs-2983	87	3	could	could	AUX
iajs-2983	87	4	be	be	AUX
iajs-2983	87	5	attributed	attribute	VERB
iajs-2983	87	6	to	to	ADP
iajs-2983	87	7	νm	νm	NOUN
iajs-2983	87	8	–	–	PUNCT
iajs-2983	87	9	n	n	CCONJ
iajs-2983	87	10	,	,	PUNCT
iajs-2983	87	11	νm	νm	INTJ
iajs-2983	87	12	–	–	PUNCT
iajs-2983	87	13	o	o	NOUN
iajs-2983	87	14	,	,	PUNCT
iajs-2983	87	15	νm	νm	INTJ
iajs-2983	87	16	–	–	PUNCT
iajs-2983	87	17	s	s	NOUN
iajs-2983	87	18	,	,	PUNCT
iajs-2983	87	19	and	and	CCONJ
iajs-2983	87	20	νm	νm	ADJ
iajs-2983	87	21	–	–	PUNCT
iajs-2983	87	22	cl	cl	NOUN
iajs-2983	87	23	for	for	ADP
iajs-2983	87	24	complexes	complex	NOUN
iajs-2983	87	25	[	[	PUNCT
iajs-2983	87	26	13	13	NUM
iajs-2983	87	27	]	]	PUNCT
iajs-2983	87	28	.	.	PUNCT
iajs-2983	88	1	other	other	ADJ
iajs-2983	88	2	bands	band	NOUN
iajs-2983	88	3	can	can	AUX
iajs-2983	88	4	be	be	AUX
iajs-2983	88	5	shown	show	VERB
iajs-2983	88	6	in	in	ADP
iajs-2983	88	7	table	table	NOUN
iajs-2983	88	8	2	2	NUM
iajs-2983	88	9	.	.	PUNCT
iajs-2983	89	1	also	also	ADV
iajs-2983	89	2	,	,	PUNCT
iajs-2983	89	3	other	other	ADJ
iajs-2983	89	4	bands	band	NOUN
iajs-2983	89	5	belonging	belong	VERB
iajs-2983	89	6	to	to	ADP
iajs-2983	89	7	the	the	DET
iajs-2983	89	8	νnh	νnh	ADJ
iajs-2983	89	9	group	group	NOUN
iajs-2983	89	10	and	and	CCONJ
iajs-2983	89	11	the	the	DET
iajs-2983	89	12	νch2	νch2	PROPN
iajs-2983	89	13	-	-	PUNCT
iajs-2983	89	14	n	n	NOUN
iajs-2983	89	15	group	group	NOUN
iajs-2983	89	16	appeared	appear	VERB
iajs-2983	89	17	that	that	SCONJ
iajs-2983	89	18	they	they	PRON
iajs-2983	89	19	did	do	AUX
iajs-2983	89	20	not	not	PART
iajs-2983	89	21	have	have	VERB
iajs-2983	89	22	a	a	DET
iajs-2983	89	23	displacement	displacement	NOUN
iajs-2983	89	24	when	when	SCONJ
iajs-2983	89	25	the	the	DET
iajs-2983	89	26	coordination	coordination	NOUN
iajs-2983	89	27	occurred	occur	VERB
iajs-2983	89	28	,	,	PUNCT
iajs-2983	89	29	indicating	indicate	VERB
iajs-2983	89	30	non	non	NOUN
iajs-2983	89	31	-	-	NOUN
iajs-2983	89	32	coordination	coordination	NOUN
iajs-2983	89	33	through	through	ADP
iajs-2983	89	34	them	they	PRON
iajs-2983	89	35	[	[	X
iajs-2983	89	36	16	16	NUM
iajs-2983	89	37	]	]	PUNCT
iajs-2983	89	38	.	.	PUNCT
iajs-2983	90	1	table	table	NOUN
iajs-2983	90	2	2	2	NUM
iajs-2983	90	3	.	.	PUNCT
iajs-2983	91	1	the	the	DET
iajs-2983	91	2	main	main	ADJ
iajs-2983	91	3	absorption	absorption	NOUN
iajs-2983	91	4	bands	band	NOUN
iajs-2983	91	5	of	of	ADP
iajs-2983	91	6	the	the	DET
iajs-2983	91	7	infrared	infrared	ADJ
iajs-2983	91	8	spectrum	spectrum	NOUN
iajs-2983	91	9	of	of	ADP
iajs-2983	91	10	ligand	ligand	NOUN
iajs-2983	91	11	(	(	PUNCT
iajs-2983	91	12	l	l	NOUN
iajs-2983	91	13	)	)	PUNCT
iajs-2983	91	14	,	,	PUNCT
iajs-2983	91	15	and	and	CCONJ
iajs-2983	91	16	its	its	PRON
iajs-2983	91	17	metal	metal	NOUN
iajs-2983	91	18	complexes	complex	NOUN
iajs-2983	91	19	(	(	PUNCT
iajs-2983	91	20	cm-1	cm-1	X
iajs-2983	91	21	)	)	PUNCT
iajs-2983	91	22	ν	ν	PROPN
iajs-2983	91	23	m	m	NOUN
iajs-2983	91	24	-	-	NOUN
iajs-2983	91	25	cl	cl	ADJ
iajs-2983	91	26	νm	νm	NOUN
iajs-2983	91	27	-	-	PUNCT
iajs-2983	91	28	s	s	PART
iajs-2983	91	29	νm	νm	ADJ
iajs-2983	91	30	-	-	PUNCT
iajs-2983	91	31	n	n	PRON
iajs-2983	91	32	νm	νm	ADJ
iajs-2983	91	33	-	-	ADJ
iajs-2983	91	34	o	o	NOUN
iajs-2983	91	35	νcs	νcs	NOUN
iajs-2983	91	36	νcsc	νcsc	PROPN
iajs-2983	91	37	ν	ν	X
iajs-2983	91	38	c	c	NOUN
iajs-2983	91	39	=	=	PROPN
iajs-2983	91	40	n	n	PROPN
iajs-2983	91	41	1,3,4thio	1,3,4thio	NUM
iajs-2983	91	42	.	.	PUNCT
iajs-2983	92	1	νch2	νch2	NOUN
iajs-2983	92	2	-	-	PUNCT
iajs-2983	92	3	n	n	NOUN
iajs-2983	92	4	ν	ν	NOUN
iajs-2983	92	5	c	c	NOUN
iajs-2983	92	6	=	=	NOUN
iajs-2983	92	7	o	o	NOUN
iajs-2983	92	8	comp	comp	NOUN
iajs-2983	92	9	.	.	PUNCT
iajs-2983	93	1	------------702	------------702	PROPN
iajs-2983	93	2	1161	1161	NUM
iajs-2983	93	3	1620	1620	NUM
iajs-2983	93	4	2943	2943	NUM
iajs-2983	93	5	2854	2854	NUM
iajs-2983	93	6	1701	1701	NUM
iajs-2983	93	7	l	l	NOUN
iajs-2983	93	8	345	345	NUM
iajs-2983	93	9	478	478	NUM
iajs-2983	93	10	520	520	NUM
iajs-2983	93	11	586	586	NUM
iajs-2983	93	12	678	678	NUM
iajs-2983	93	13	1145	1145	NUM
iajs-2983	93	14	1602	1602	NUM
iajs-2983	93	15	2943	2943	NUM
iajs-2983	93	16	broad	broad	ADJ
iajs-2983	93	17	1728	1728	NUM
iajs-2983	93	18	col	col	NOUN
iajs-2983	93	19	337	337	NUM
iajs-2983	93	20	416	416	NUM
iajs-2983	93	21	513	513	NUM
iajs-2983	93	22	547	547	NUM
iajs-2983	93	23	686	686	NUM
iajs-2983	93	24	1153	1153	NUM
iajs-2983	93	25	1658	1658	NUM
iajs-2983	93	26	2943	2943	NUM
iajs-2983	93	27	1728	1728	NUM
iajs-2983	93	28	nil	nil	NOUN
iajs-2983	93	29	320	320	NUM
iajs-2983	93	30	470	470	NUM
iajs-2983	93	31	513	513	NUM
iajs-2983	93	32	590	590	NUM
iajs-2983	93	33	729	729	NUM
iajs-2983	93	34	1175	1175	NUM
iajs-2983	93	35	1639	1639	NUM
iajs-2983	93	36	2942	2942	NUM
iajs-2983	93	37	1691	1691	NUM
iajs-2983	93	38	cul	cul	PROPN
iajs-2983	93	39	345	345	NUM
iajs-2983	93	40	482	482	NUM
iajs-2983	93	41	520	520	NUM
iajs-2983	93	42	540	540	NUM
iajs-2983	93	43	77	77	NUM
iajs-2983	93	44	1171	1171	NUM
iajs-2983	93	45	1608	1608	NUM
iajs-2983	93	46	2947	2947	NUM
iajs-2983	93	47	2854	2854	NUM
iajs-2983	93	48	1690	1690	NUM
iajs-2983	94	1	pdl	pdl	PROPN
iajs-2983	94	2	310	310	NUM
iajs-2983	94	3	451	451	NUM
iajs-2983	94	4	516	516	NUM
iajs-2983	94	5	559	559	NUM
iajs-2983	94	6	744	744	NUM
iajs-2983	94	7	1190	1190	NUM
iajs-2983	94	8	1608	1608	NUM
iajs-2983	94	9	2943	2943	NUM
iajs-2983	94	10	2858	2858	NUM
iajs-2983	94	11	1686	1686	NUM
iajs-2983	94	12	ptl	ptl	PROPN
iajs-2983	94	13	337	337	NUM
iajs-2983	94	14	470	470	NUM
iajs-2983	94	15	516	516	NUM
iajs-2983	94	16	540	540	NUM
iajs-2983	94	17	786	786	NUM
iajs-2983	94	18	1188	1188	NUM
iajs-2983	94	19	1639	1639	NUM
iajs-2983	94	20	2947	2947	NUM
iajs-2983	94	21	1722	1722	NUM
iajs-2983	94	22	aul	aul	NOUN
iajs-2983	94	23	uv	uv	NOUN
iajs-2983	94	24	-	-	PUNCT
iajs-2983	94	25	vis	vis	X
iajs-2983	94	26	spectra	spectra	PROPN
iajs-2983	94	27	,	,	PUNCT
iajs-2983	94	28	magnetic	magnetic	ADJ
iajs-2983	94	29	susceptibility	susceptibility	NOUN
iajs-2983	94	30	and	and	CCONJ
iajs-2983	94	31	molar	molar	ADJ
iajs-2983	94	32	conductivity	conductivity	NOUN
iajs-2983	94	33	the	the	DET
iajs-2983	94	34	electronic	electronic	ADJ
iajs-2983	94	35	spectra	spectra	NOUN
iajs-2983	94	36	of	of	ADP
iajs-2983	94	37	all	all	DET
iajs-2983	94	38	prepared	prepared	ADJ
iajs-2983	94	39	compounds	compound	NOUN
iajs-2983	94	40	are	be	AUX
iajs-2983	94	41	shown	show	VERB
iajs-2983	94	42	in	in	ADP
iajs-2983	94	43	table	table	NOUN
iajs-2983	94	44	(	(	PUNCT
iajs-2983	94	45	3	3	NUM
iajs-2983	94	46	)	)	PUNCT
iajs-2983	94	47	.	.	PUNCT
iajs-2983	95	1	the	the	DET
iajs-2983	95	2	uv	uv	NOUN
iajs-2983	95	3	-	-	PUNCT
iajs-2983	95	4	vis	vis	X
iajs-2983	95	5	spectrum	spectrum	NOUN
iajs-2983	95	6	of	of	ADP
iajs-2983	95	7	the	the	DET
iajs-2983	95	8	free	free	ADJ
iajs-2983	95	9	ligand	ligand	NOUN
iajs-2983	95	10	displayed	display	VERB
iajs-2983	95	11	a	a	DET
iajs-2983	95	12	sharp	sharp	ADJ
iajs-2983	95	13	band	band	NOUN
iajs-2983	95	14	at	at	ADP
iajs-2983	95	15	(	(	PUNCT
iajs-2983	95	16	25773	25773	NUM
iajs-2983	95	17	)	)	PUNCT
iajs-2983	95	18	cm-1	cm-1	X
iajs-2983	95	19	is	be	AUX
iajs-2983	95	20	attributed	attribute	VERB
iajs-2983	95	21	to	to	ADP
iajs-2983	95	22	n	n	DET
iajs-2983	95	23	→π	→π	NOUN
iajs-2983	95	24	*	*	NOUN
iajs-2983	95	25	transition	transition	NOUN
iajs-2983	95	26	.	.	PUNCT
iajs-2983	96	1	transitions	transition	NOUN
iajs-2983	96	2	appeared	appear	VERB
iajs-2983	96	3	in	in	ADP
iajs-2983	96	4	the	the	DET
iajs-2983	96	5	region	region	NOUN
iajs-2983	96	6	(	(	PUNCT
iajs-2983	96	7	33112	33112	NUM
iajs-2983	96	8	)	)	PUNCT
iajs-2983	96	9	cm-1	cm-1	PROPN
iajs-2983	96	10	and	and	CCONJ
iajs-2983	96	11	37314	37314	NUM
iajs-2983	96	12	cm-1	cm-1	VERB
iajs-2983	96	13	is	be	AUX
iajs-2983	96	14	attributed	attribute	VERB
iajs-2983	96	15	to	to	ADP
iajs-2983	96	16	π	π	PROPN
iajs-2983	97	1	→	→	PUNCT
iajs-2983	97	2	π*transitions	π*transition	NOUN
iajs-2983	98	1	[	[	X
iajs-2983	98	2	18	18	NUM
iajs-2983	98	3	]	]	PUNCT
iajs-2983	98	4	.	.	PUNCT
iajs-2983	99	1	in	in	ADP
iajs-2983	99	2	the	the	DET
iajs-2983	99	3	uvvisible	uvvisible	ADJ
iajs-2983	99	4	spectrum	spectrum	NOUN
iajs-2983	99	5	of	of	ADP
iajs-2983	99	6	dark	dark	ADJ
iajs-2983	99	7	green	green	PROPN
iajs-2983	99	8	co	co	PROPN
iajs-2983	99	9	(	(	PUNCT
iajs-2983	99	10	ii	ii	NOUN
iajs-2983	99	11	)	)	PUNCT
iajs-2983	99	12	complex	complex	NOUN
iajs-2983	99	13	,	,	PUNCT
iajs-2983	99	14	two	two	NUM
iajs-2983	99	15	peaks	peak	NOUN
iajs-2983	99	16	were	be	AUX
iajs-2983	99	17	observed	observe	VERB
iajs-2983	99	18	at	at	ADP
iajs-2983	99	19	(	(	PUNCT
iajs-2983	99	20	10240	10240	NUM
iajs-2983	99	21	,	,	PUNCT
iajs-2983	99	22	19230	19230	NUM
iajs-2983	99	23	cm-1	cm-1	NOUN
iajs-2983	99	24	)	)	PUNCT
iajs-2983	99	25	dedicated	dedicate	VERB
iajs-2983	99	26	to	to	ADP
iajs-2983	99	27	4t1	4t1	NUM
iajs-2983	99	28	g	g	PROPN
iajs-2983	99	29	→	→	SYM
iajs-2983	99	30	4t2	4t2	NUM
iajs-2983	99	31	g	g	NOUN
iajs-2983	99	32	,	,	PUNCT
iajs-2983	99	33	4t1	4t1	NUM
iajs-2983	99	34	g	g	NOUN
iajs-2983	99	35	→	→	SYM
iajs-2983	99	36	4	4	NUM
iajs-2983	99	37	t2	t2	NOUN
iajs-2983	99	38	g	g	NOUN
iajs-2983	99	39	(	(	PUNCT
iajs-2983	99	40	p	p	NOUN
iajs-2983	99	41	)	)	PUNCT
iajs-2983	99	42	transitions	transition	NOUN
iajs-2983	99	43	sequentially	sequentially	ADV
iajs-2983	99	44	and	and	CCONJ
iajs-2983	99	45	(	(	PUNCT
iajs-2983	99	46	28659	28659	NUM
iajs-2983	99	47	,	,	PUNCT
iajs-2983	99	48	41838	41838	NUM
iajs-2983	99	49	)	)	PUNCT
iajs-2983	99	50	cm-1	cm-1	PROPN
iajs-2983	99	51	.	.	PUNCT
iajs-2983	100	1	it	it	PRON
iajs-2983	100	2	was	be	AUX
iajs-2983	100	3	due	due	ADJ
iajs-2983	100	4	to	to	ADP
iajs-2983	100	5	the	the	DET
iajs-2983	100	6	transition	transition	NOUN
iajs-2983	100	7	il	il	PROPN
iajs-2983	100	8	→	→	SYM
iajs-2983	100	9	co	co	NOUN
iajs-2983	100	10	ct	ct	PROPN
iajs-2983	100	11	,	,	PUNCT
iajs-2983	100	12	which	which	PRON
iajs-2983	100	13	indicated	indicate	VERB
iajs-2983	100	14	the	the	DET
iajs-2983	100	15	octahedral	octahedral	ADJ
iajs-2983	100	16	geometry	geometry	NOUN
iajs-2983	100	17	of	of	ADP
iajs-2983	100	18	co	co	PROPN
iajs-2983	100	19	(	(	PUNCT
iajs-2983	100	20	ii	ii	NOUN
iajs-2983	100	21	)	)	PUNCT
iajs-2983	100	22	.	.	PUNCT
iajs-2983	101	1	magnetic	magnetic	ADJ
iajs-2983	101	2	moment	moment	NOUN
iajs-2983	101	3	.	.	PUNCT
iajs-2983	102	1	(	(	PUNCT
iajs-2983	102	2	4.00	4.00	NUM
iajs-2983	102	3	)	)	PUNCT
iajs-2983	102	4	b.m	b.m	NOUN
iajs-2983	102	5	showed	show	VERB
iajs-2983	102	6	a	a	DET
iajs-2983	102	7	higher	high	ADJ
iajs-2983	102	8	orbital	orbital	ADJ
iajs-2983	102	9	contribution	contribution	NOUN
iajs-2983	102	10	.	.	PUNCT
iajs-2983	103	1	conductivity	conductivity	NOUN
iajs-2983	103	2	measurement	measurement	NOUN
iajs-2983	103	3	in	in	ADP
iajs-2983	103	4	dmf	dmf	PROPN
iajs-2983	103	5	(	(	PUNCT
iajs-2983	103	6	67	67	NUM
iajs-2983	103	7	μs.cm-1	μs.cm-1	NOUN
iajs-2983	103	8	)	)	PUNCT
iajs-2983	103	9	showed	show	VERB
iajs-2983	103	10	that	that	SCONJ
iajs-2983	103	11	the	the	DET
iajs-2983	103	12	complex	complex	NOUN
iajs-2983	103	13	was	be	AUX
iajs-2983	103	14	ionic	ionic	ADJ
iajs-2983	103	15	.	.	PUNCT
iajs-2983	104	1	the	the	DET
iajs-2983	104	2	electronic	electronic	ADJ
iajs-2983	104	3	spectrum	spectrum	NOUN
iajs-2983	104	4	of	of	ADP
iajs-2983	104	5	this	this	DET
iajs-2983	104	6	complex	complex	NOUN
iajs-2983	104	7	can	can	AUX
iajs-2983	104	8	be	be	AUX
iajs-2983	104	9	seen	see	VERB
iajs-2983	104	10	in	in	ADP
iajs-2983	104	11	table	table	NOUN
iajs-2983	104	12	(	(	PUNCT
iajs-2983	104	13	3	3	NUM
iajs-2983	104	14	)	)	PUNCT
iajs-2983	104	15	[	[	X
iajs-2983	104	16	19	19	NUM
iajs-2983	104	17	]	]	PUNCT
iajs-2983	104	18	.	.	PUNCT
iajs-2983	105	1	in	in	ADP
iajs-2983	105	2	the	the	DET
iajs-2983	105	3	uvvisible	uvvisible	NOUN
iajs-2983	105	4	of	of	ADP
iajs-2983	105	5	ni	ni	PROPN
iajs-2983	105	6	(	(	PUNCT
iajs-2983	105	7	ii	ii	PROPN
iajs-2983	105	8	)	)	PUNCT
iajs-2983	105	9	complex	complex	NOUN
iajs-2983	105	10	,	,	PUNCT
iajs-2983	105	11	three	three	NUM
iajs-2983	105	12	peaks	peak	NOUN
iajs-2983	105	13	were	be	AUX
iajs-2983	105	14	observed	observe	VERB
iajs-2983	105	15	at	at	ADP
iajs-2983	105	16	(	(	PUNCT
iajs-2983	105	17	10582	10582	NUM
iajs-2983	105	18	,	,	PUNCT
iajs-2983	105	19	15772	15772	NUM
iajs-2983	105	20	,	,	PUNCT
iajs-2983	105	21	24875	24875	NUM
iajs-2983	105	22	cm-1	cm-1	NOUN
iajs-2983	105	23	)	)	PUNCT
iajs-2983	105	24	.	.	PUNCT
iajs-2983	106	1	they	they	PRON
iajs-2983	106	2	were	be	AUX
iajs-2983	106	3	dedicated	dedicate	VERB
iajs-2983	106	4	to	to	ADP
iajs-2983	106	5	3a2	3a2	NUM
iajs-2983	106	6	g	g	NOUN
iajs-2983	106	7	→	→	SYM
iajs-2983	106	8	3t2	3t2	NUM
iajs-2983	106	9	g	g	NOUN
iajs-2983	106	10	,	,	PUNCT
iajs-2983	106	11	3a2	3a2	NUM
iajs-2983	106	12	g	g	NOUN
iajs-2983	106	13	→	→	SYM
iajs-2983	106	14	3t1	3t1	PROPN
iajs-2983	106	15	g	g	NOUN
iajs-2983	106	16	(	(	PUNCT
iajs-2983	106	17	f	f	PROPN
iajs-2983	106	18	)	)	PUNCT
iajs-2983	106	19	,	,	PUNCT
iajs-2983	106	20	3a2	3a2	NUM
iajs-2983	106	21	g	g	NOUN
iajs-2983	106	22	→	→	SYM
iajs-2983	106	23	3t1	3t1	PROPN
iajs-2983	106	24	g	g	NOUN
iajs-2983	106	25	(	(	PUNCT
iajs-2983	106	26	p	p	NOUN
iajs-2983	106	27	)	)	PUNCT
iajs-2983	106	28	sequentially	sequentially	ADV
iajs-2983	106	29	and	and	CCONJ
iajs-2983	106	30	(	(	PUNCT
iajs-2983	106	31	26109	26109	NUM
iajs-2983	106	32	,	,	PUNCT
iajs-2983	106	33	40983	40983	NUM
iajs-2983	106	34	)	)	PUNCT
iajs-2983	106	35	cm-1	cm-1	X
iajs-2983	106	36	was	be	AUX
iajs-2983	106	37	due	due	ADJ
iajs-2983	106	38	to	to	ADP
iajs-2983	106	39	il	il	PROPN
iajs-2983	106	40	→	→	SYM
iajs-2983	106	41	nict	nict	NOUN
iajs-2983	106	42	which	which	PRON
iajs-2983	106	43	indicated	indicate	VERB
iajs-2983	106	44	the	the	DET
iajs-2983	106	45	octahedral	octahedral	ADJ
iajs-2983	106	46	geometry	geometry	NOUN
iajs-2983	106	47	of	of	ADP
iajs-2983	106	48	ni	ni	PROPN
iajs-2983	106	49	.	.	PUNCT
iajs-2983	107	1	the	the	DET
iajs-2983	107	2	magnetic	magnetic	ADJ
iajs-2983	107	3	moment	moment	NOUN
iajs-2983	107	4	,	,	PUNCT
iajs-2983	107	5	(	(	PUNCT
iajs-2983	107	6	3.09	3.09	NUM
iajs-2983	107	7	)	)	PUNCT
iajs-2983	107	8	b.m	b.m	NOUN
iajs-2983	107	9	showed	show	VERB
iajs-2983	107	10	a	a	DET
iajs-2983	107	11	higher	high	ADJ
iajs-2983	107	12	orbital	orbital	ADJ
iajs-2983	107	13	contribution	contribution	NOUN
iajs-2983	107	14	[	[	X
iajs-2983	107	15	20]conductivity	20]conductivity	NUM
iajs-2983	107	16	measurement	measurement	NOUN
iajs-2983	107	17	in	in	ADP
iajs-2983	107	18	dmf	dmf	PROPN
iajs-2983	107	19	(	(	PUNCT
iajs-2983	107	20	21	21	NUM
iajs-2983	107	21	μs.cm-1	μs.cm-1	NOUN
iajs-2983	107	22	)	)	PUNCT
iajs-2983	107	23	appearing	appear	VERB
iajs-2983	107	24	that	that	SCONJ
iajs-2983	107	25	the	the	DET
iajs-2983	107	26	complex	complex	NOUN
iajs-2983	107	27	was	be	AUX
iajs-2983	107	28	nonionic	nonionic	ADJ
iajs-2983	107	29	[	[	X
iajs-2983	107	30	19	19	NUM
iajs-2983	107	31	]	]	PUNCT
iajs-2983	107	32	.	.	PUNCT
iajs-2983	108	1	light	light	ADJ
iajs-2983	108	2	green	green	ADJ
iajs-2983	108	3	complex	complex	NOUN
iajs-2983	108	4	showed	show	VERB
iajs-2983	108	5	paramagnetic	paramagnetic	ADJ
iajs-2983	108	6	and	and	CCONJ
iajs-2983	108	7	high	high	ADJ
iajs-2983	108	8	spin	spin	NOUN
iajs-2983	108	9	octahedral	octahedral	NOUN
iajs-2983	108	10	.	.	PUNCT
iajs-2983	109	1	the	the	DET
iajs-2983	109	2	electronic	electronic	ADJ
iajs-2983	109	3	spectrum	spectrum	NOUN
iajs-2983	109	4	of	of	ADP
iajs-2983	109	5	this	this	DET
iajs-2983	109	6	complex	complex	NOUN
iajs-2983	109	7	,	,	PUNCT
iajs-2983	109	8	can	can	AUX
iajs-2983	109	9	be	be	AUX
iajs-2983	109	10	seen	see	VERB
iajs-2983	109	11	in	in	ADP
iajs-2983	109	12	table	table	NOUN
iajs-2983	109	13	(	(	PUNCT
iajs-2983	109	14	3	3	NUM
iajs-2983	109	15	)	)	PUNCT
iajs-2983	109	16	.	.	PUNCT
iajs-2983	110	1	ihjpas	ihjpas	PROPN
iajs-2983	110	2	.	.	PUNCT
iajs-2983	111	1	36(1)2023	36(1)2023	NUM
iajs-2983	111	2	265	265	NUM
iajs-2983	111	3	in	in	ADP
iajs-2983	111	4	the	the	DET
iajs-2983	111	5	uvvisible	uvvisible	ADJ
iajs-2983	111	6	region	region	NOUN
iajs-2983	111	7	of	of	ADP
iajs-2983	111	8	the	the	DET
iajs-2983	111	9	cu(ii	cu(ii	PROPN
iajs-2983	111	10	)	)	PUNCT
iajs-2983	111	11	complex	complex	NOUN
iajs-2983	111	12	,	,	PUNCT
iajs-2983	111	13	one	one	NUM
iajs-2983	111	14	peak	peak	NOUN
iajs-2983	111	15	was	be	AUX
iajs-2983	111	16	observed	observe	VERB
iajs-2983	111	17	at	at	ADP
iajs-2983	111	18	(	(	PUNCT
iajs-2983	111	19	15197	15197	NUM
iajs-2983	111	20	cm-1	cm-1	NOUN
iajs-2983	111	21	)	)	PUNCT
iajs-2983	111	22	,	,	PUNCT
iajs-2983	111	23	dedicated	dedicate	VERB
iajs-2983	111	24	to	to	ADP
iajs-2983	111	25	2eg	2eg	NOUN
iajs-2983	111	26	→	→	SYM
iajs-2983	111	27	2t2	2t2	NUM
iajs-2983	111	28	g	g	NOUN
iajs-2983	111	29	,	,	PUNCT
iajs-2983	111	30	and	and	CCONJ
iajs-2983	111	31	(	(	PUNCT
iajs-2983	111	32	27629	27629	NUM
iajs-2983	111	33	,	,	PUNCT
iajs-2983	111	34	29069	29069	NUM
iajs-2983	111	35	,	,	PUNCT
iajs-2983	111	36	42918	42918	NUM
iajs-2983	111	37	)	)	PUNCT
iajs-2983	111	38	cm-1	cm-1	VERB
iajs-2983	111	39	was	be	AUX
iajs-2983	111	40	due	due	ADJ
iajs-2983	111	41	to	to	ADP
iajs-2983	111	42	il	il	PROPN
iajs-2983	111	43	→	→	PUNCT
iajs-2983	111	44	cuct	cuct	NOUN
iajs-2983	111	45	which	which	PRON
iajs-2983	111	46	indicated	indicate	VERB
iajs-2983	111	47	the	the	DET
iajs-2983	111	48	octahedral	octahedral	ADJ
iajs-2983	111	49	geometry	geometry	NOUN
iajs-2983	111	50	of	of	ADP
iajs-2983	111	51	cu	cu	PROPN
iajs-2983	111	52	(	(	PUNCT
iajs-2983	111	53	ii	ii	PROPN
iajs-2983	111	54	)	)	PUNCT
iajs-2983	112	1	[	[	X
iajs-2983	112	2	20	20	NUM
iajs-2983	112	3	]	]	PUNCT
iajs-2983	112	4	.	.	PUNCT
iajs-2983	113	1	magnetic	magnetic	ADJ
iajs-2983	113	2	moment	moment	NOUN
iajs-2983	113	3	,	,	PUNCT
iajs-2983	113	4	(	(	PUNCT
iajs-2983	113	5	1.78	1.78	NUM
iajs-2983	113	6	)	)	PUNCT
iajs-2983	113	7	b.m	b.m	PROPN
iajs-2983	114	1	[	[	X
iajs-2983	114	2	21	21	NUM
iajs-2983	114	3	]	]	PUNCT
iajs-2983	114	4	.	.	PUNCT
iajs-2983	115	1	conductivity	conductivity	NOUN
iajs-2983	115	2	measurement	measurement	NOUN
iajs-2983	115	3	in	in	ADP
iajs-2983	115	4	dmf	dmf	PROPN
iajs-2983	115	5	(	(	PUNCT
iajs-2983	115	6	61	61	NUM
iajs-2983	115	7	μs.cm-1	μs.cm-1	NOUN
iajs-2983	115	8	)	)	PUNCT
iajs-2983	115	9	showed	show	VERB
iajs-2983	115	10	that	that	SCONJ
iajs-2983	115	11	the	the	DET
iajs-2983	115	12	complex	complex	NOUN
iajs-2983	115	13	was	be	AUX
iajs-2983	115	14	ionic	ionic	ADJ
iajs-2983	115	15	.	.	PUNCT
iajs-2983	116	1	dark	dark	ADJ
iajs-2983	116	2	brown	brown	ADJ
iajs-2983	116	3	complex	complex	NOUN
iajs-2983	116	4	showed	show	VERB
iajs-2983	116	5	paramagnetic	paramagnetic	ADJ
iajs-2983	116	6	and	and	CCONJ
iajs-2983	116	7	high	high	ADJ
iajs-2983	116	8	spin	spin	NOUN
iajs-2983	116	9	octahedral	octahedral	NOUN
iajs-2983	116	10	.	.	PUNCT
iajs-2983	117	1	the	the	DET
iajs-2983	117	2	electronic	electronic	ADJ
iajs-2983	117	3	spectrum	spectrum	NOUN
iajs-2983	117	4	of	of	ADP
iajs-2983	117	5	this	this	PRON
iajs-2983	117	6	,	,	PUNCT
iajs-2983	117	7	complex	complex	NOUN
iajs-2983	117	8	can	can	AUX
iajs-2983	117	9	be	be	AUX
iajs-2983	117	10	seen	see	VERB
iajs-2983	117	11	in	in	ADP
iajs-2983	117	12	table	table	NOUN
iajs-2983	117	13	(	(	PUNCT
iajs-2983	117	14	3	3	NUM
iajs-2983	117	15	)	)	PUNCT
iajs-2983	117	16	.	.	PUNCT
iajs-2983	118	1	in	in	ADP
iajs-2983	118	2	the	the	DET
iajs-2983	118	3	uv	uv	NOUN
iajs-2983	118	4	-	-	PUNCT
iajs-2983	118	5	visible	visible	ADJ
iajs-2983	118	6	region	region	NOUN
iajs-2983	118	7	of	of	ADP
iajs-2983	118	8	the	the	DET
iajs-2983	118	9	pd	pd	PROPN
iajs-2983	118	10	(	(	PUNCT
iajs-2983	118	11	ii	ii	PROPN
iajs-2983	118	12	)	)	PUNCT
iajs-2983	118	13	complex	complex	NOUN
iajs-2983	118	14	,	,	PUNCT
iajs-2983	118	15	one	one	NUM
iajs-2983	118	16	peak	peak	NOUN
iajs-2983	118	17	was	be	AUX
iajs-2983	118	18	observed	observe	VERB
iajs-2983	118	19	at	at	ADP
iajs-2983	118	20	(	(	PUNCT
iajs-2983	118	21	24038cm-1	24038cm-1	NOUN
iajs-2983	118	22	)	)	PUNCT
iajs-2983	118	23	,	,	PUNCT
iajs-2983	118	24	dedicated	dedicate	VERB
iajs-2983	118	25	to	to	ADP
iajs-2983	118	26	1a1	1a1	NUM
iajs-2983	118	27	g	g	PROPN
iajs-2983	118	28	→	→	SYM
iajs-2983	118	29	1b1	1b1	NUM
iajs-2983	118	30	g	g	NOUN
iajs-2983	118	31	transition	transition	NOUN
iajs-2983	118	32	,	,	PUNCT
iajs-2983	118	33	and	and	CCONJ
iajs-2983	118	34	(	(	PUNCT
iajs-2983	118	35	31446	31446	NUM
iajs-2983	118	36	,	,	PUNCT
iajs-2983	118	37	45248	45248	NUM
iajs-2983	118	38	)	)	PUNCT
iajs-2983	118	39	cm-1	cm-1	X
iajs-2983	118	40	was	be	AUX
iajs-2983	118	41	due	due	ADJ
iajs-2983	118	42	to	to	ADP
iajs-2983	118	43	il	il	PROPN
iajs-2983	118	44	→	→	SYM
iajs-2983	118	45	pdct	pdct	NOUN
iajs-2983	118	46	,	,	PUNCT
iajs-2983	118	47	which	which	PRON
iajs-2983	118	48	indicated	indicate	VERB
iajs-2983	118	49	square	square	ADJ
iajs-2983	118	50	planer	planer	NOUN
iajs-2983	118	51	geometry	geometry	NOUN
iajs-2983	118	52	of	of	ADP
iajs-2983	118	53	pd	pd	PROPN
iajs-2983	118	54	(	(	PUNCT
iajs-2983	118	55	ii	ii	PROPN
iajs-2983	118	56	)	)	PUNCT
iajs-2983	119	1	[	[	X
iajs-2983	119	2	19	19	NUM
iajs-2983	119	3	]	]	PUNCT
iajs-2983	119	4	.	.	PUNCT
iajs-2983	120	1	magnetic	magnetic	ADJ
iajs-2983	120	2	moment	moment	NOUN
iajs-2983	120	3	(	(	PUNCT
iajs-2983	120	4	0	0	X
iajs-2983	120	5	)	)	PUNCT
iajs-2983	120	6	b.m	b.m	PROPN
iajs-2983	120	7	.	.	PROPN
iajs-2983	120	8	conductivity	conductivity	NOUN
iajs-2983	120	9	measurement	measurement	NOUN
iajs-2983	120	10	in	in	ADP
iajs-2983	120	11	dmf	dmf	PROPN
iajs-2983	120	12	(	(	PUNCT
iajs-2983	120	13	70	70	NUM
iajs-2983	120	14	μs.cm-1	μs.cm-1	NOUN
iajs-2983	120	15	)	)	PUNCT
iajs-2983	120	16	showed	show	VERB
iajs-2983	120	17	that	that	SCONJ
iajs-2983	120	18	the	the	DET
iajs-2983	120	19	complex	complex	NOUN
iajs-2983	120	20	was	be	AUX
iajs-2983	120	21	ionic	ionic	ADJ
iajs-2983	120	22	,	,	PUNCT
iajs-2983	120	23	low	low	ADJ
iajs-2983	120	24	spin	spin	NOUN
iajs-2983	120	25	and	and	CCONJ
iajs-2983	120	26	square	square	ADJ
iajs-2983	120	27	planer	planer	NOUN
iajs-2983	120	28	geometry	geometry	NOUN
iajs-2983	121	1	[	[	X
iajs-2983	121	2	22	22	NUM
iajs-2983	121	3	]	]	PUNCT
iajs-2983	121	4	.	.	PUNCT
iajs-2983	122	1	the	the	DET
iajs-2983	122	2	electronic	electronic	ADJ
iajs-2983	122	3	spectrum	spectrum	NOUN
iajs-2983	122	4	of	of	ADP
iajs-2983	122	5	this	this	DET
iajs-2983	122	6	complex	complex	NOUN
iajs-2983	122	7	,	,	PUNCT
iajs-2983	122	8	can	can	AUX
iajs-2983	122	9	be	be	AUX
iajs-2983	122	10	seen	see	VERB
iajs-2983	122	11	in	in	ADP
iajs-2983	122	12	table	table	NOUN
iajs-2983	122	13	(	(	PUNCT
iajs-2983	122	14	3	3	NUM
iajs-2983	122	15	)	)	PUNCT
iajs-2983	122	16	.	.	PUNCT
iajs-2983	123	1	in	in	ADP
iajs-2983	123	2	the	the	DET
iajs-2983	123	3	uvvisible	uvvisible	ADJ
iajs-2983	123	4	region	region	NOUN
iajs-2983	123	5	of	of	ADP
iajs-2983	123	6	the	the	DET
iajs-2983	123	7	pt(ii	pt(ii	ADJ
iajs-2983	123	8	)	)	PUNCT
iajs-2983	123	9	complex	complex	ADJ
iajs-2983	123	10	two	two	NUM
iajs-2983	123	11	peaks	peak	NOUN
iajs-2983	123	12	were	be	AUX
iajs-2983	123	13	observed	observe	VERB
iajs-2983	123	14	at	at	ADP
iajs-2983	123	15	(	(	PUNCT
iajs-2983	123	16	10812	10812	NUM
iajs-2983	123	17	,	,	PUNCT
iajs-2983	123	18	12050	12050	NUM
iajs-2983	123	19	cm-1	cm-1	NOUN
iajs-2983	123	20	)	)	PUNCT
iajs-2983	123	21	was	be	AUX
iajs-2983	123	22	assigned	assign	VERB
iajs-2983	123	23	to	to	ADP
iajs-2983	123	24	1a1	1a1	NUM
iajs-2983	123	25	g	g	NOUN
iajs-2983	123	26	→	→	SYM
iajs-2983	123	27	3t2	3t2	NUM
iajs-2983	123	28	g	g	NOUN
iajs-2983	123	29	,	,	PUNCT
iajs-2983	123	30	(	(	PUNCT
iajs-2983	123	31	23980	23980	NUM
iajs-2983	123	32	cm-1	cm-1	NOUN
iajs-2983	123	33	)	)	PUNCT
iajs-2983	123	34	was	be	AUX
iajs-2983	123	35	assigned	assign	VERB
iajs-2983	123	36	to	to	ADP
iajs-2983	123	37	1a1	1a1	NUM
iajs-2983	123	38	g	g	NOUN
iajs-2983	123	39	→	→	SYM
iajs-2983	123	40	1t1	1t1	NUM
iajs-2983	123	41	g	g	NOUN
iajs-2983	123	42	,	,	PUNCT
iajs-2983	123	43	transitions	transition	NOUN
iajs-2983	123	44	which	which	PRON
iajs-2983	123	45	indicated	indicate	VERB
iajs-2983	123	46	the	the	DET
iajs-2983	123	47	octahedral	octahedral	ADJ
iajs-2983	123	48	geometry	geometry	NOUN
iajs-2983	123	49	of	of	ADP
iajs-2983	123	50	pt	pt	X
iajs-2983	123	51	(	(	PUNCT
iajs-2983	123	52	iv	iv	NOUN
iajs-2983	123	53	)	)	PUNCT
iajs-2983	123	54	.	.	PUNCT
iajs-2983	124	1	magnetic	magnetic	ADJ
iajs-2983	124	2	moment	moment	NOUN
iajs-2983	124	3	,	,	PUNCT
iajs-2983	124	4	(	(	PUNCT
iajs-2983	124	5	0	0	X
iajs-2983	124	6	)	)	PUNCT
iajs-2983	124	7	b.m	b.m	NOUN
iajs-2983	125	1	[	[	X
iajs-2983	125	2	23	23	NUM
iajs-2983	125	3	]	]	PUNCT
iajs-2983	125	4	.	.	PUNCT
iajs-2983	126	1	conductivity	conductivity	NOUN
iajs-2983	126	2	measurement	measurement	NOUN
iajs-2983	126	3	in	in	ADP
iajs-2983	126	4	dmf	dmf	PROPN
iajs-2983	126	5	(	(	PUNCT
iajs-2983	126	6	69	69	NUM
iajs-2983	126	7	μs.cm-1	μs.cm-1	NOUN
iajs-2983	126	8	)	)	PUNCT
iajs-2983	126	9	showed	show	VERB
iajs-2983	126	10	that	that	SCONJ
iajs-2983	126	11	the	the	DET
iajs-2983	126	12	complex	complex	NOUN
iajs-2983	126	13	was	be	AUX
iajs-2983	126	14	ionic	ionic	ADJ
iajs-2983	126	15	[	[	X
iajs-2983	126	16	24	24	NUM
iajs-2983	126	17	]	]	PUNCT
iajs-2983	126	18	.	.	PUNCT
iajs-2983	127	1	in	in	ADP
iajs-2983	127	2	the	the	DET
iajs-2983	127	3	uvvisible	uvvisible	ADJ
iajs-2983	127	4	region	region	NOUN
iajs-2983	127	5	of	of	ADP
iajs-2983	127	6	the	the	DET
iajs-2983	127	7	au	au	X
iajs-2983	127	8	(	(	PUNCT
iajs-2983	127	9	iii	iii	NOUN
iajs-2983	127	10	)	)	PUNCT
iajs-2983	127	11	complex	complex	NOUN
iajs-2983	127	12	,	,	PUNCT
iajs-2983	127	13	two	two	NUM
iajs-2983	127	14	peaks	peak	NOUN
iajs-2983	127	15	were	be	AUX
iajs-2983	127	16	observed	observe	VERB
iajs-2983	127	17	at	at	ADP
iajs-2983	127	18	(	(	PUNCT
iajs-2983	127	19	251889	251889	NUM
iajs-2983	127	20	,	,	PUNCT
iajs-2983	127	21	30030cm1	30030cm1	NUM
iajs-2983	127	22	)	)	PUNCT
iajs-2983	127	23	dedicated	dedicate	VERB
iajs-2983	127	24	to	to	ADP
iajs-2983	127	25	1a1	1a1	NUM
iajs-2983	127	26	g	g	PROPN
iajs-2983	127	27	→	→	SYM
iajs-2983	127	28	1b1	1b1	NUM
iajs-2983	127	29	g	g	NOUN
iajs-2983	127	30	and	and	CCONJ
iajs-2983	127	31	1a1	1a1	NUM
iajs-2983	127	32	g	g	PROPN
iajs-2983	127	33	→	→	SYM
iajs-2983	127	34	1eg	1eg	ADJ
iajs-2983	127	35	transitions	transition	NOUN
iajs-2983	127	36	sequentially	sequentially	ADV
iajs-2983	127	37	and	and	CCONJ
iajs-2983	127	38	(	(	PUNCT
iajs-2983	127	39	40983	40983	NUM
iajs-2983	127	40	)	)	PUNCT
iajs-2983	127	41	cm-1	cm-1	X
iajs-2983	127	42	was	be	AUX
iajs-2983	127	43	due	due	ADJ
iajs-2983	127	44	to	to	ADP
iajs-2983	127	45	il	il	PROPN
iajs-2983	127	46	→	→	SYM
iajs-2983	127	47	auct	auct	NOUN
iajs-2983	127	48	which	which	PRON
iajs-2983	127	49	indicated	indicate	VERB
iajs-2983	127	50	the	the	DET
iajs-2983	127	51	square	square	ADJ
iajs-2983	127	52	planner	planner	NOUN
iajs-2983	127	53	geometry	geometry	NOUN
iajs-2983	127	54	au	au	X
iajs-2983	127	55	(	(	PUNCT
iajs-2983	127	56	iii	iii	NOUN
iajs-2983	127	57	)	)	PUNCT
iajs-2983	127	58	.	.	PUNCT
iajs-2983	128	1	the	the	DET
iajs-2983	128	2	magnetic	magnetic	ADJ
iajs-2983	128	3	moment	moment	NOUN
iajs-2983	128	4	was	be	AUX
iajs-2983	128	5	(	(	PUNCT
iajs-2983	128	6	0	0	X
iajs-2983	128	7	)	)	PUNCT
iajs-2983	128	8	b.m	b.m	NOUN
iajs-2983	128	9	[	[	X
iajs-2983	128	10	25	25	NUM
iajs-2983	128	11	]	]	PUNCT
iajs-2983	128	12	.	.	PUNCT
iajs-2983	129	1	the	the	DET
iajs-2983	129	2	conductivity	conductivity	NOUN
iajs-2983	129	3	measurement	measurement	NOUN
iajs-2983	129	4	in	in	ADP
iajs-2983	129	5	dmf	dmf	PROPN
iajs-2983	129	6	was	be	AUX
iajs-2983	129	7	(	(	PUNCT
iajs-2983	129	8	88	88	NUM
iajs-2983	129	9	μs.cm-1	μs.cm-1	NOUN
iajs-2983	129	10	)	)	PUNCT
iajs-2983	130	1	[	[	X
iajs-2983	130	2	22	22	NUM
iajs-2983	130	3	]	]	PUNCT
iajs-2983	130	4	.this	.this	PRON
iajs-2983	130	5	complex	complex	NOUN
iajs-2983	130	6	was	be	AUX
iajs-2983	130	7	ionic	ionic	ADJ
iajs-2983	130	8	,	,	PUNCT
iajs-2983	130	9	low	low	ADJ
iajs-2983	130	10	spin	spin	NOUN
iajs-2983	130	11	and	and	CCONJ
iajs-2983	130	12	square	square	ADJ
iajs-2983	130	13	planer	planer	NOUN
iajs-2983	130	14	geometry	geometry	NOUN
iajs-2983	130	15	.	.	PUNCT
iajs-2983	131	1	the	the	DET
iajs-2983	131	2	electronic	electronic	ADJ
iajs-2983	131	3	spectrum	spectrum	NOUN
iajs-2983	131	4	of	of	ADP
iajs-2983	131	5	this	this	DET
iajs-2983	131	6	complex	complex	NOUN
iajs-2983	131	7	can	can	AUX
iajs-2983	131	8	be	be	AUX
iajs-2983	131	9	seen	see	VERB
iajs-2983	131	10	in	in	ADP
iajs-2983	131	11	table	table	NOUN
iajs-2983	131	12	3	3	NUM
iajs-2983	131	13	[	[	X
iajs-2983	131	14	26	26	NUM
iajs-2983	131	15	]	]	PUNCT
iajs-2983	131	16	.	.	PUNCT
iajs-2983	132	1	table	table	NOUN
iajs-2983	132	2	3	3	NUM
iajs-2983	132	3	.	.	PUNCT
iajs-2983	133	1	the	the	DET
iajs-2983	133	2	electronic	electronic	ADJ
iajs-2983	133	3	spectra	spectra	NOUN
iajs-2983	133	4	,	,	PUNCT
iajs-2983	133	5	μeff	μeff	NOUN
iajs-2983	133	6	of	of	ADP
iajs-2983	133	7	complexes	complex	NOUN
iajs-2983	133	8	,	,	PUNCT
iajs-2983	133	9	conductivity	conductivity	NOUN
iajs-2983	133	10	and	and	CCONJ
iajs-2983	133	11	suggested	suggest	VERB
iajs-2983	133	12	geometry	geometry	NOUN
iajs-2983	133	13	for	for	ADP
iajs-2983	133	14	ligand	ligand	NOUN
iajs-2983	133	15	and	and	CCONJ
iajs-2983	133	16	its	its	PRON
iajs-2983	133	17	metal	metal	NOUN
iajs-2983	133	18	complexes	complex	NOUN
iajs-2983	133	19	suggested	suggest	VERB
iajs-2983	133	20	geometry	geometry	NOUN
iajs-2983	133	21	conductivity	conductivity	NOUN
iajs-2983	133	22	μs.cm-1	μs.cm-1	PROPN
iajs-2983	133	23	μeeff	μeeff	PROPN
iajs-2983	133	24	b.m	b.m	PROPN
iajs-2983	133	25	.	.	PROPN
iajs-2983	133	26	assignments	assignments	PROPN
iajs-2983	133	27	absorption	absorption	PROPN
iajs-2983	133	28	cm-1	cm-1	X
iajs-2983	133	29	comp	comp	PROPN
iajs-2983	133	30	.	.	PUNCT
iajs-2983	133	31	---------n	---------n	PUNCT
iajs-2983	134	1	→	→	PUNCT
iajs-2983	134	2	π	π	X
iajs-2983	134	3	*	*	PUNCT
iajs-2983	134	4	π	π	X
iajs-2983	134	5	→	→	SYM
iajs-2983	134	6	π	π	PROPN
iajs-2983	134	7	*	*	PUNCT
iajs-2983	134	8	π	π	X
iajs-2983	134	9	→	→	SYM
iajs-2983	134	10	π	π	PROPN
iajs-2983	134	11	*	*	PROPN
iajs-2983	134	12	25773	25773	NUM
iajs-2983	134	13	33112	33112	NUM
iajs-2983	134	14	37314	37314	NUM
iajs-2983	134	15	l	l	NOUN
iajs-2983	134	16	octahedral	octahedral	NOUN
iajs-2983	134	17	67	67	NUM
iajs-2983	134	18	4.00	4.00	NUM
iajs-2983	134	19	(	(	PUNCT
iajs-2983	134	20	3.87	3.87	NUM
iajs-2983	134	21	)	)	PUNCT
iajs-2983	134	22	4t1	4t1	NUM
iajs-2983	134	23	g	g	NOUN
iajs-2983	134	24	→	→	SYM
iajs-2983	134	25	4t2	4t2	NUM
iajs-2983	134	26	g	g	NOUN
iajs-2983	134	27	4t1	4t1	NUM
iajs-2983	134	28	g	g	PROPN
iajs-2983	134	29	→	→	SYM
iajs-2983	134	30	4t1g(p	4t1g(p	NUM
iajs-2983	134	31	)	)	PUNCT
iajs-2983	134	32	il	il	PROPN
iajs-2983	134	33	→	→	SYM
iajs-2983	134	34	coct	coct	PROPN
iajs-2983	134	35	il	il	PROPN
iajs-2983	134	36	→	→	SYM
iajs-2983	134	37	coct	coct	NOUN
iajs-2983	134	38	10240	10240	NUM
iajs-2983	134	39	19230	19230	NUM
iajs-2983	134	40	28659	28659	NUM
iajs-2983	134	41	41838	41838	NUM
iajs-2983	134	42	col	col	NOUN
iajs-2983	134	43	octahedral	octahedral	NOUN
iajs-2983	134	44	21	21	NUM
iajs-2983	134	45	3.09	3.09	NUM
iajs-2983	134	46	(	(	PUNCT
iajs-2983	134	47	2.82	2.82	NUM
iajs-2983	134	48	)	)	PUNCT
iajs-2983	134	49	3a2	3a2	NUM
iajs-2983	134	50	g	g	NOUN
iajs-2983	134	51	→	→	SYM
iajs-2983	134	52	3t2	3t2	NUM
iajs-2983	134	53	g	g	ADP
iajs-2983	134	54	3a2	3a2	NUM
iajs-2983	134	55	g	g	NOUN
iajs-2983	134	56	→	→	SYM
iajs-2983	134	57	1t1g(f	1t1g(f	NUM
iajs-2983	134	58	)	)	PUNCT
iajs-2983	134	59	3a2	3a2	NUM
iajs-2983	134	60	g	g	NOUN
iajs-2983	134	61	→	→	SYM
iajs-2983	134	62	3t1	3t1	PROPN
iajs-2983	134	63	g	g	NOUN
iajs-2983	134	64	(	(	PUNCT
iajs-2983	134	65	p	p	NOUN
iajs-2983	134	66	)	)	PUNCT
iajs-2983	134	67	il	il	PROPN
iajs-2983	134	68	→	→	SYM
iajs-2983	134	69	ni	ni	PROPN
iajs-2983	134	70	ct	ct	PROPN
iajs-2983	134	71	il	il	PROPN
iajs-2983	134	72	→	→	SYM
iajs-2983	134	73	ni	ni	PROPN
iajs-2983	134	74	ct	ct	PROPN
iajs-2983	134	75	10582	10582	NUM
iajs-2983	134	76	15772	15772	NUM
iajs-2983	134	77	24875	24875	NUM
iajs-2983	134	78	26109	26109	NUM
iajs-2983	134	79	40983	40983	NUM
iajs-2983	134	80	nil	nil	NOUN
iajs-2983	134	81	octahedral	octahedral	ADJ
iajs-2983	134	82	61	61	NUM
iajs-2983	134	83	1.78	1.78	NUM
iajs-2983	134	84	(	(	PUNCT
iajs-2983	134	85	1.73	1.73	NUM
iajs-2983	134	86	)	)	PUNCT
iajs-2983	134	87	2eg	2eg	NOUN
iajs-2983	134	88	→	→	SYM
iajs-2983	134	89	2t2	2t2	NUM
iajs-2983	134	90	g	g	PROPN
iajs-2983	134	91	il	il	PROPN
iajs-2983	134	92	→	→	SYM
iajs-2983	134	93	cu	cu	PROPN
iajs-2983	134	94	ct	ct	PROPN
iajs-2983	134	95	il	il	PROPN
iajs-2983	134	96	→	→	SYM
iajs-2983	134	97	cu	cu	PROPN
iajs-2983	134	98	ct	ct	PROPN
iajs-2983	134	99	il	il	PROPN
iajs-2983	134	100	→	→	SYM
iajs-2983	134	101	cu	cu	PROPN
iajs-2983	134	102	ct	ct	PROPN
iajs-2983	134	103	15197	15197	NUM
iajs-2983	134	104	27629	27629	NUM
iajs-2983	134	105	29069	29069	NUM
iajs-2983	134	106	42918	42918	NUM
iajs-2983	134	107	cul	cul	PROPN
iajs-2983	134	108	square	square	PROPN
iajs-2983	134	109	planer	planer	NOUN
iajs-2983	134	110	73	73	NUM
iajs-2983	134	111	0.00	0.00	NUM
iajs-2983	134	112	1a1	1a1	NUM
iajs-2983	134	113	g	g	NOUN
iajs-2983	134	114	→	→	SYM
iajs-2983	134	115	1b1	1b1	NUM
iajs-2983	134	116	g	g	PROPN
iajs-2983	134	117	il	il	PROPN
iajs-2983	134	118	→	→	SYM
iajs-2983	134	119	pd	pd	PROPN
iajs-2983	134	120	ct	ct	PROPN
iajs-2983	134	121	il	il	PROPN
iajs-2983	134	122	→	→	SYM
iajs-2983	134	123	pd	pd	PROPN
iajs-2983	134	124	ct	ct	NUM
iajs-2983	134	125	24038	24038	NUM
iajs-2983	134	126	31446	31446	NUM
iajs-2983	134	127	45248	45248	NUM
iajs-2983	134	128	pdl	pdl	NOUN
iajs-2983	134	129	octahedral	octahedral	NOUN
iajs-2983	134	130	69	69	NUM
iajs-2983	134	131	0.00	0.00	NUM
iajs-2983	134	132	1a1	1a1	NUM
iajs-2983	134	133	g	g	NOUN
iajs-2983	134	134	→	→	SYM
iajs-2983	134	135	3t2	3t2	NUM
iajs-2983	134	136	g	g	NOUN
iajs-2983	134	137	1a1	1a1	NUM
iajs-2983	134	138	g	g	NOUN
iajs-2983	134	139	→	→	SYM
iajs-2983	134	140	3t1	3t1	PROPN
iajs-2983	134	141	g	g	NOUN
iajs-2983	134	142	1a1	1a1	NUM
iajs-2983	134	143	g	g	NOUN
iajs-2983	134	144	→	→	SYM
iajs-2983	134	145	1t1	1t1	NUM
iajs-2983	134	146	g	g	PROPN
iajs-2983	134	147	il	il	PROPN
iajs-2983	134	148	→	→	SYM
iajs-2983	134	149	pt	pt	PROPN
iajs-2983	134	150	ct	ct	PROPN
iajs-2983	134	151	il	il	PROPN
iajs-2983	134	152	→	→	SYM
iajs-2983	134	153	pt	pt	X
iajs-2983	134	154	ct	ct	PROPN
iajs-2983	134	155	il	il	PROPN
iajs-2983	134	156	→	→	SYM
iajs-2983	134	157	pt	pt	PROPN
iajs-2983	135	1	ct	ct	NUM
iajs-2983	135	2	108551	108551	NUM
iajs-2983	135	3	12050	12050	NUM
iajs-2983	135	4	23980	23980	NUM
iajs-2983	135	5	26881	26881	NUM
iajs-2983	135	6	34602	34602	NUM
iajs-2983	135	7	45662	45662	NUM
iajs-2983	135	8	ptl	ptl	PROPN
iajs-2983	135	9	square	square	PROPN
iajs-2983	135	10	planer	planer	NOUN
iajs-2983	135	11	88	88	NUM
iajs-2983	135	12	0.00	0.00	NUM
iajs-2983	135	13	1a1	1a1	NUM
iajs-2983	135	14	g	g	NOUN
iajs-2983	135	15	→	→	SYM
iajs-2983	135	16	1b1	1b1	NUM
iajs-2983	135	17	g	g	NOUN
iajs-2983	135	18	1a1	1a1	NUM
iajs-2983	135	19	g	g	NOUN
iajs-2983	135	20	→	→	SYM
iajs-2983	135	21	1eg	1eg	PROPN
iajs-2983	135	22	il	il	PROPN
iajs-2983	135	23	→	→	SYM
iajs-2983	135	24	au	au	PROPN
iajs-2983	135	25	ct	ct	PROPN
iajs-2983	135	26	25575	25575	NUM
iajs-2983	135	27	27624	27624	NUM
iajs-2983	135	28	aul	aul	NOUN
iajs-2983	135	29	ihjpas	ihjpa	NOUN
iajs-2983	135	30	.	.	PUNCT
iajs-2983	136	1	36(1)2023	36(1)2023	NUM
iajs-2983	136	2	266	266	NUM
iajs-2983	136	3	the	the	DET
iajs-2983	136	4	1h	1h	NUM
iajs-2983	136	5	-	-	PUNCT
iajs-2983	136	6	nmr	nmr	NOUN
iajs-2983	136	7	spectra	spectra	NOUN
iajs-2983	136	8	of	of	ADP
iajs-2983	136	9	2	2	NUM
iajs-2983	136	10	-	-	PUNCT
iajs-2983	136	11	chloro	chloro	NOUN
iajs-2983	136	12	–	–	PUNCT
iajs-2983	136	13	n-5-(piperidin-1	n-5-(piperidin-1	NUM
iajs-2983	136	14	-	-	NUM
iajs-2983	136	15	ylmethylthio)-1,3,4thiadiazol-2yl)acetimde	ylmethylthio)-1,3,4thiadiazol-2yl)acetimde	NOUN
iajs-2983	136	16	the	the	DET
iajs-2983	136	17	1h	1h	NUM
iajs-2983	136	18	-	-	PUNCT
iajs-2983	136	19	nmr	nmr	NOUN
iajs-2983	136	20	spectrum	spectrum	NOUN
iajs-2983	136	21	of	of	ADP
iajs-2983	136	22	the	the	DET
iajs-2983	136	23	l	l	NOUN
iajs-2983	136	24	can	can	AUX
iajs-2983	136	25	be	be	AUX
iajs-2983	136	26	observed	observe	VERB
iajs-2983	136	27	in	in	ADP
iajs-2983	136	28	table	table	NOUN
iajs-2983	136	29	4	4	NUM
iajs-2983	136	30	in	in	ADP
iajs-2983	136	31	dmso	dmso	NOUN
iajs-2983	136	32	-	-	NOUN
iajs-2983	136	33	d6	d6	NOUN
iajs-2983	136	34	.	.	PUNCT
iajs-2983	137	1	the	the	DET
iajs-2983	137	2	proton	proton	NOUN
iajs-2983	137	3	nuclear	nuclear	ADJ
iajs-2983	137	4	resonance	resonance	NOUN
iajs-2983	137	5	(	(	PUNCT
iajs-2983	137	6	1h	1h	NUM
iajs-2983	137	7	-	-	PUNCT
iajs-2983	137	8	nmr	nmr	NOUN
iajs-2983	137	9	)	)	PUNCT
iajs-2983	137	10	spectrum	spectrum	NOUN
iajs-2983	137	11	of	of	ADP
iajs-2983	137	12	ligand	ligand	NOUN
iajs-2983	137	13	showed	show	VERB
iajs-2983	137	14	some	some	DET
iajs-2983	137	15	signals	signal	NOUN
iajs-2983	137	16	in	in	ADP
iajs-2983	137	17	ppm	ppm	NOUN
iajs-2983	137	18	.	.	PUNCT
iajs-2983	138	1	two	two	NUM
iajs-2983	138	2	signals	signal	NOUN
iajs-2983	138	3	appeared	appear	VERB
iajs-2983	138	4	at	at	ADP
iajs-2983	138	5	(	(	PUNCT
iajs-2983	138	6	1.54	1.54	NUM
iajs-2983	138	7	,	,	PUNCT
iajs-2983	138	8	1.64	1.64	NUM
iajs-2983	138	9	)	)	PUNCT
iajs-2983	138	10	ppm	ppm	NOUN
iajs-2983	138	11	and	and	CCONJ
iajs-2983	138	12	another	another	DET
iajs-2983	138	13	signals	signal	NOUN
iajs-2983	138	14	appeared	appear	VERB
iajs-2983	138	15	at	at	ADP
iajs-2983	138	16	(	(	PUNCT
iajs-2983	138	17	2.42,2.43.2.45	2.42,2.43.2.45	NUM
iajs-2983	138	18	)	)	PUNCT
iajs-2983	138	19	ppm	ppm	NOUN
iajs-2983	138	20	,	,	PUNCT
iajs-2983	138	21	attributed	attribute	VERB
iajs-2983	138	22	to	to	ADP
iajs-2983	138	23	the	the	DET
iajs-2983	138	24	proton	proton	NOUN
iajs-2983	138	25	of	of	ADP
iajs-2983	138	26	piperidin	piperidin	VERB
iajs-2983	138	27	[	[	X
iajs-2983	138	28	11	11	NUM
iajs-2983	138	29	]	]	PUNCT
iajs-2983	138	30	.	.	PUNCT
iajs-2983	139	1	the	the	DET
iajs-2983	139	2	proton	proton	NOUN
iajs-2983	139	3	of	of	ADP
iajs-2983	139	4	ch2	ch2	PROPN
iajs-2983	139	5	-	-	PUNCT
iajs-2983	139	6	n	n	NOUN
iajs-2983	139	7	and	and	CCONJ
iajs-2983	139	8	ch2	ch2	PROPN
iajs-2983	139	9	-	-	PUNCT
iajs-2983	139	10	cl	cl	NOUN
iajs-2983	139	11	groups	group	NOUN
iajs-2983	139	12	appared	appare	VERB
iajs-2983	139	13	at	at	ADP
iajs-2983	139	14	(	(	PUNCT
iajs-2983	139	15	4.49	4.49	NUM
iajs-2983	139	16	)	)	PUNCT
iajs-2983	139	17	ppm	ppm	NOUN
iajs-2983	139	18	and	and	CCONJ
iajs-2983	139	19	(	(	PUNCT
iajs-2983	139	20	3.97	3.97	NUM
iajs-2983	139	21	)	)	PUNCT
iajs-2983	139	22	ppm	ppm	NOUN
iajs-2983	139	23	.	.	PUNCT
iajs-2983	140	1	the	the	DET
iajs-2983	140	2	signal	signal	NOUN
iajs-2983	140	3	at	at	ADP
iajs-2983	140	4	(	(	PUNCT
iajs-2983	140	5	12.39	12.39	NUM
iajs-2983	140	6	)	)	PUNCT
iajs-2983	140	7	ppm	ppm	NOUN
iajs-2983	140	8	was	be	AUX
iajs-2983	140	9	attributed	attribute	VERB
iajs-2983	140	10	to	to	ADP
iajs-2983	140	11	proton	proton	NOUN
iajs-2983	140	12	of	of	ADP
iajs-2983	140	13	nh	nh	PROPN
iajs-2983	140	14	group	group	NOUN
iajs-2983	140	15	table	table	NOUN
iajs-2983	140	16	4	4	NUM
iajs-2983	140	17	.	.	PUNCT
iajs-2983	141	1	the	the	DET
iajs-2983	141	2	13cnmr	13cnmr	PROPN
iajs-2983	141	3	spectra	spectra	NOUN
iajs-2983	141	4	of	of	ADP
iajs-2983	141	5	2	2	NUM
iajs-2983	141	6	-	-	PUNCT
iajs-2983	141	7	chloro	chloro	NOUN
iajs-2983	141	8	–	–	PUNCT
iajs-2983	141	9	n-5-(piperidine1	n-5-(piperidine1	NOUN
iajs-2983	141	10	-	-	NOUN
iajs-2983	141	11	ylmethylthio)-1,3,4thiadiazol-2yl)acetimde	ylmethylthio)-1,3,4thiadiazol-2yl)acetimde	NOUN
iajs-2983	141	12	the	the	DET
iajs-2983	141	13	13cnmr	13cnmr	NUM
iajs-2983	141	14	spectrum	spectrum	NOUN
iajs-2983	141	15	of	of	ADP
iajs-2983	141	16	ligand	ligand	NOUN
iajs-2983	141	17	showed	show	VERB
iajs-2983	141	18	some	some	DET
iajs-2983	141	19	signal	signal	NOUN
iajs-2983	141	20	.	.	PUNCT
iajs-2983	142	1	the	the	DET
iajs-2983	142	2	signal	signal	NOUN
iajs-2983	142	3	at	at	ADP
iajs-2983	142	4	43.7	43.7	NUM
iajs-2983	142	5	can	can	AUX
iajs-2983	142	6	be	be	AUX
iajs-2983	142	7	assigned	assign	VERB
iajs-2983	142	8	to	to	ADP
iajs-2983	142	9	carbon	carbon	NOUN
iajs-2983	142	10	of	of	ADP
iajs-2983	142	11	(	(	PUNCT
iajs-2983	142	12	ch2	ch2	NOUN
iajs-2983	142	13	-	-	PUNCT
iajs-2983	142	14	cl	cl	NOUN
iajs-2983	142	15	)	)	PUNCT
iajs-2983	142	16	group.the	group.the	DET
iajs-2983	142	17	signals	signal	NOUN
iajs-2983	142	18	at	at	ADP
iajs-2983	142	19	23.1,24.4	23.1,24.4	NUM
iajs-2983	142	20	and	and	CCONJ
iajs-2983	142	21	54.1	54.1	NUM
iajs-2983	142	22	ppm	ppm	NOUN
iajs-2983	142	23	returned	return	VERB
iajs-2983	142	24	to	to	ADP
iajs-2983	142	25	carbon	carbon	NOUN
iajs-2983	142	26	of	of	ADP
iajs-2983	142	27	ch2	ch2	NOUN
iajs-2983	142	28	of	of	ADP
iajs-2983	142	29	piperidin	piperidin	VERB
iajs-2983	142	30	and	and	CCONJ
iajs-2983	142	31	ch2	ch2	PROPN
iajs-2983	142	32	-	-	PUNCT
iajs-2983	142	33	n	n	NOUN
iajs-2983	142	34	of	of	ADP
iajs-2983	142	35	piperidin	piperidin	VERB
iajs-2983	142	36	[	[	X
iajs-2983	142	37	3	3	NUM
iajs-2983	142	38	]	]	PUNCT
iajs-2983	142	39	.	.	PUNCT
iajs-2983	143	1	other	other	ADJ
iajs-2983	143	2	signals	signal	NOUN
iajs-2983	143	3	appeared	appear	VERB
iajs-2983	143	4	at	at	ADP
iajs-2983	143	5	163.2	163.2	NUM
iajs-2983	143	6	and	and	CCONJ
iajs-2983	143	7	168.4	168.4	NUM
iajs-2983	143	8	can	can	AUX
iajs-2983	143	9	be	be	AUX
iajs-2983	143	10	assigned	assign	VERB
iajs-2983	143	11	to	to	ADP
iajs-2983	143	12	carbon	carbon	NOUN
iajs-2983	143	13	of	of	ADP
iajs-2983	143	14	(	(	PUNCT
iajs-2983	143	15	c	c	NOUN
iajs-2983	143	16	-	-	PUNCT
iajs-2983	143	17	s,1,3,4	s,1,3,4	NUM
iajs-2983	143	18	thio	thio	NOUN
iajs-2983	143	19	.	.	PUNCT
iajs-2983	143	20	)	)	PUNCT
iajs-2983	143	21	group	group	NOUN
iajs-2983	143	22	and	and	CCONJ
iajs-2983	143	23	carbon	carbon	NOUN
iajs-2983	143	24	of	of	ADP
iajs-2983	143	25	carbonyl	carbonyl	NOUN
iajs-2983	143	26	group	group	NOUN
iajs-2983	143	27	,	,	PUNCT
iajs-2983	143	28	respectively	respectively	ADV
iajs-2983	143	29	[	[	X
iajs-2983	143	30	4	4	NUM
iajs-2983	143	31	]	]	PUNCT
iajs-2983	143	32	.	.	PUNCT
iajs-2983	144	1	another	another	DET
iajs-2983	144	2	peak	peak	NOUN
iajs-2983	144	3	can	can	AUX
iajs-2983	144	4	be	be	AUX
iajs-2983	144	5	observed	observe	VERB
iajs-2983	144	6	in	in	ADP
iajs-2983	144	7	table	table	NOUN
iajs-2983	144	8	4	4	NUM
iajs-2983	144	9	.	.	PUNCT
iajs-2983	144	10	table	table	NOUN
iajs-2983	144	11	4	4	NUM
iajs-2983	144	12	.	.	PUNCT
iajs-2983	144	13	1h	1h	NUM
iajs-2983	144	14	and	and	CCONJ
iajs-2983	144	15	13c	13c	NOUN
iajs-2983	144	16	nuclear	nuclear	ADJ
iajs-2983	144	17	magnetic	magnetic	ADJ
iajs-2983	144	18	resonance	resonance	NOUN
iajs-2983	144	19	spectra	spectra	NOUN
iajs-2983	144	20	of	of	ADP
iajs-2983	144	21	mannich	mannich	DET
iajs-2983	144	22	base	base	PROPN
iajs-2983	144	23	ligand	ligand	NOUN
iajs-2983	144	24	(	(	PUNCT
iajs-2983	144	25	l	l	NOUN
iajs-2983	144	26	)	)	PUNCT
iajs-2983	145	1	1hnmr	1hnmr	NUM
iajs-2983	145	2	13cnmr	13cnmr	NUM
iajs-2983	145	3	1hnmr(dmsod6	1hnmr(dmsod6	NUM
iajs-2983	145	4	)	)	PUNCT
iajs-2983	145	5	δ	δ	PROPN
iajs-2983	145	6	ppm:2.42,2.43,2.45	ppm:2.42,2.43,2.45	X
iajs-2983	145	7	(	(	PUNCT
iajs-2983	145	8	d,2h	d,2h	PROPN
iajs-2983	145	9	,	,	PUNCT
iajs-2983	145	10	ch2	ch2	NOUN
iajs-2983	145	11	of	of	ADP
iajs-2983	145	12	piperidine	piperidine	NOUN
iajs-2983	145	13	)	)	PUNCT
iajs-2983	145	14	1.64	1.64	NUM
iajs-2983	145	15	and	and	CCONJ
iajs-2983	145	16	1.54	1.54	NUM
iajs-2983	145	17	(	(	PUNCT
iajs-2983	145	18	d,2h	d,2h	PROPN
iajs-2983	145	19	,	,	PUNCT
iajs-2983	145	20	ch2	ch2	NOUN
iajs-2983	145	21	of	of	ADP
iajs-2983	145	22	piperidine	piperidine	NOUN
iajs-2983	145	23	)	)	PUNCT
iajs-2983	145	24	,	,	PUNCT
iajs-2983	145	25	12.39	12.39	NUM
iajs-2983	145	26	(	(	PUNCT
iajs-2983	145	27	s	s	PROPN
iajs-2983	145	28	,	,	PUNCT
iajs-2983	145	29	h	h	NOUN
iajs-2983	145	30	,	,	PUNCT
iajs-2983	145	31	nh	nh	PROPN
iajs-2983	145	32	)	)	PUNCT
iajs-2983	145	33	of	of	ADP
iajs-2983	145	34	amide	amide	NOUN
iajs-2983	145	35	,	,	PUNCT
iajs-2983	145	36	3.97,4.49	3.97,4.49	NUM
iajs-2983	145	37	(	(	PUNCT
iajs-2983	145	38	s	s	PROPN
iajs-2983	145	39	,	,	PUNCT
iajs-2983	145	40	h	h	NOUN
iajs-2983	145	41	,	,	PUNCT
iajs-2983	145	42	ch2	ch2	PROPN
iajs-2983	145	43	alphatic	alphatic	NOUN
iajs-2983	145	44	of	of	ADP
iajs-2983	145	45	ch2	ch2	PROPN
iajs-2983	145	46	-	-	PUNCT
iajs-2983	145	47	n	n	NOUN
iajs-2983	145	48	and	and	CCONJ
iajs-2983	145	49	ch2	ch2	NOUN
iajs-2983	145	50	-	-	PUNCT
iajs-2983	145	51	cl	cl	NOUN
iajs-2983	145	52	respectively	respectively	ADV
iajs-2983	145	53	mannich	mannich	NOUN
iajs-2983	145	54	(	(	PUNCT
iajs-2983	145	55	l	l	NOUN
iajs-2983	145	56	)	)	PUNCT
iajs-2983	145	57	:	:	PUNCT
iajs-2983	145	58	13cnmr	13cnmr	NUM
iajs-2983	145	59	(	(	PUNCT
iajs-2983	145	60	dmso	dmso	ADJ
iajs-2983	145	61	-	-	PUNCT
iajs-2983	145	62	d6	d6	NOUN
iajs-2983	145	63	)	)	PUNCT
iajs-2983	145	64	δppm:43.7	δppm:43.7	NOUN
iajs-2983	145	65	(	(	PUNCT
iajs-2983	145	66	ch2	ch2	NOUN
iajs-2983	145	67	-	-	PUNCT
iajs-2983	145	68	cl	cl	NOUN
iajs-2983	145	69	)	)	PUNCT
iajs-2983	145	70	,	,	PUNCT
iajs-2983	145	71	23.1,24.4	23.1,24.4	NUM
iajs-2983	145	72	(	(	PUNCT
iajs-2983	145	73	ch2	ch2	NOUN
iajs-2983	145	74	of	of	ADP
iajs-2983	145	75	piperidine	piperidine	NOUN
iajs-2983	145	76	)	)	PUNCT
iajs-2983	145	77	,	,	PUNCT
iajs-2983	145	78	53.1	53.1	NUM
iajs-2983	145	79	(	(	PUNCT
iajs-2983	145	80	ch2	ch2	PROPN
iajs-2983	145	81	-	-	PUNCT
iajs-2983	145	82	n	n	NOUN
iajs-2983	145	83	of	of	ADP
iajs-2983	145	84	piperidine	piperidine	NOUN
iajs-2983	145	85	)	)	PUNCT
iajs-2983	145	86	,	,	PUNCT
iajs-2983	145	87	54.1	54.1	NUM
iajs-2983	145	88	(	(	PUNCT
iajs-2983	145	89	ch2	ch2	NOUN
iajs-2983	145	90	-	-	PUNCT
iajs-2983	145	91	n	n	CCONJ
iajs-2983	145	92	)	)	PUNCT
iajs-2983	145	93	of	of	ADP
iajs-2983	145	94	methylene	methylene	NOUN
iajs-2983	145	95	group	group	NOUN
iajs-2983	145	96	,	,	PUNCT
iajs-2983	145	97	163.2	163.2	NUM
iajs-2983	145	98	(	(	PUNCT
iajs-2983	145	99	s	s	NOUN
iajs-2983	145	100	-	-	PUNCT
iajs-2983	145	101	c	c	NOUN
iajs-2983	145	102	of	of	ADP
iajs-2983	145	103	1,3,4	1,3,4	NUM
iajs-2983	145	104	thiadiazole	thiadiazole	NOUN
iajs-2983	145	105	group	group	NOUN
iajs-2983	145	106	,	,	PUNCT
iajs-2983	145	107	168.4	168.4	NUM
iajs-2983	145	108	(	(	PUNCT
iajs-2983	145	109	c	c	NOUN
iajs-2983	145	110	=	=	NOUN
iajs-2983	145	111	o	o	NOUN
iajs-2983	145	112	group	group	NOUN
iajs-2983	145	113	)	)	PUNCT
iajs-2983	145	114	.	.	PUNCT
iajs-2983	146	1	figure	figure	NOUN
iajs-2983	146	2	1	1	NUM
iajs-2983	146	3	.	.	PUNCT
iajs-2983	147	1	the	the	DET
iajs-2983	147	2	proposed	propose	VERB
iajs-2983	147	3	geometry	geometry	NOUN
iajs-2983	147	4	of	of	ADP
iajs-2983	147	5	the	the	DET
iajs-2983	147	6	prepared	prepared	ADJ
iajs-2983	147	7	complexes	complex	NOUN
iajs-2983	147	8	ihjpas	ihjpa	VERB
iajs-2983	147	9	.	.	PUNCT
iajs-2983	148	1	36(1)2023	36(1)2023	NUM
iajs-2983	148	2	267	267	NUM
iajs-2983	148	3	molar	molar	ADJ
iajs-2983	148	4	ratio	ratio	NOUN
iajs-2983	148	5	method	method	NOUN
iajs-2983	148	6	in	in	ADP
iajs-2983	148	7	the	the	DET
iajs-2983	148	8	solution	solution	NOUN
iajs-2983	148	9	state	state	NOUN
iajs-2983	148	10	,	,	PUNCT
iajs-2983	148	11	the	the	DET
iajs-2983	148	12	ratio	ratio	NOUN
iajs-2983	148	13	metal	metal	NOUN
iajs-2983	148	14	to	to	PART
iajs-2983	148	15	ligand	ligand	VERB
iajs-2983	148	16	can	can	AUX
iajs-2983	148	17	be	be	AUX
iajs-2983	148	18	calculated	calculate	VERB
iajs-2983	148	19	using	use	VERB
iajs-2983	148	20	molar	molar	ADJ
iajs-2983	148	21	ratio	ratio	NOUN
iajs-2983	148	22	method	method	NOUN
iajs-2983	148	23	at	at	ADP
iajs-2983	148	24	the	the	DET
iajs-2983	148	25	maximum	maximum	ADJ
iajs-2983	148	26	wavelength	wavelength	NOUN
iajs-2983	148	27	,	,	PUNCT
iajs-2983	148	28	and	and	CCONJ
iajs-2983	148	29	at	at	ADP
iajs-2983	148	30	concentration	concentration	NOUN
iajs-2983	148	31	1x10	1x10	NUM
iajs-2983	148	32	-	-	PUNCT
iajs-2983	148	33	3of	3of	NOUN
iajs-2983	148	34	all	all	DET
iajs-2983	148	35	the	the	DET
iajs-2983	148	36	prepared	prepared	ADJ
iajs-2983	148	37	complexes	complex	NOUN
iajs-2983	148	38	.	.	PUNCT
iajs-2983	149	1	the	the	DET
iajs-2983	149	2	results	result	NOUN
iajs-2983	149	3	proved	prove	VERB
iajs-2983	149	4	that	that	SCONJ
iajs-2983	149	5	the	the	DET
iajs-2983	149	6	ratio	ratio	NOUN
iajs-2983	149	7	of	of	ADP
iajs-2983	149	8	metal	metal	NOUN
iajs-2983	149	9	to	to	ADP
iajs-2983	149	10	ligands	ligand	NOUN
iajs-2983	149	11	was	be	AUX
iajs-2983	149	12	(	(	PUNCT
iajs-2983	149	13	1:1	1:1	NUM
iajs-2983	149	14	)	)	PUNCT
iajs-2983	149	15	.	.	PUNCT
iajs-2983	150	1	figure	figure	NOUN
iajs-2983	150	2	2	2	NUM
iajs-2983	150	3	.	.	PUNCT
iajs-2983	151	1	molar	molar	ADJ
iajs-2983	151	2	ratio	ratio	NOUN
iajs-2983	151	3	plot	plot	NOUN
iajs-2983	151	4	of	of	ADP
iajs-2983	151	5	,	,	PUNCT
iajs-2983	151	6	l	l	NOUN
iajs-2983	151	7	metal	metal	NOUN
iajs-2983	151	8	complexes	complexe	VERB
iajs-2983	151	9	4	4	NUM
iajs-2983	151	10	.	.	NOUN
iajs-2983	151	11	antibacterial	antibacterial	ADJ
iajs-2983	151	12	and	and	CCONJ
iajs-2983	151	13	antifungal	antifungal	ADJ
iajs-2983	151	14	activity	activity	NOUN
iajs-2983	151	15	the	the	DET
iajs-2983	151	16	biological	biological	ADJ
iajs-2983	151	17	activity	activity	NOUN
iajs-2983	151	18	of	of	ADP
iajs-2983	151	19	all	all	DET
iajs-2983	151	20	prepared	prepared	ADJ
iajs-2983	151	21	compounds	compound	NOUN
iajs-2983	151	22	was	be	AUX
iajs-2983	151	23	tested	test	VERB
iajs-2983	151	24	by	by	ADP
iajs-2983	151	25	two	two	NUM
iajs-2983	151	26	types	type	NOUN
iajs-2983	151	27	of	of	ADP
iajs-2983	151	28	bacteria	bacteria	NOUN
iajs-2983	151	29	and	and	CCONJ
iajs-2983	151	30	one	one	NUM
iajs-2983	151	31	type	type	NOUN
iajs-2983	151	32	of	of	ADP
iajs-2983	151	33	fungi	fungus	NOUN
iajs-2983	151	34	at	at	ADP
iajs-2983	151	35	a	a	DET
iajs-2983	151	36	concentration	concentration	NOUN
iajs-2983	151	37	of	of	ADP
iajs-2983	151	38	0.02	0.02	NUM
iajs-2983	151	39	m.	m.	NOUN
iajs-2983	151	40	the	the	DET
iajs-2983	151	41	results	result	NOUN
iajs-2983	151	42	obtained	obtain	VERB
iajs-2983	151	43	for	for	ADP
iajs-2983	151	44	the	the	DET
iajs-2983	151	45	antibacterial	antibacterial	ADJ
iajs-2983	151	46	and	and	CCONJ
iajs-2983	151	47	antifungal	antifungal	ADJ
iajs-2983	151	48	of	of	ADP
iajs-2983	151	49	the	the	DET
iajs-2983	151	50	mannich	mannich	PROPN
iajs-2983	151	51	ligand	ligand	NOUN
iajs-2983	151	52	and	and	CCONJ
iajs-2983	151	53	its	its	PRON
iajs-2983	151	54	new	new	ADJ
iajs-2983	151	55	complexes	complex	NOUN
iajs-2983	151	56	are	be	AUX
iajs-2983	151	57	presented	present	VERB
iajs-2983	151	58	in	in	ADP
iajs-2983	151	59	table	table	NOUN
iajs-2983	151	60	5	5	NUM
iajs-2983	151	61	.	.	PUNCT
iajs-2983	152	1	the	the	DET
iajs-2983	152	2	diameter	diameter	NOUN
iajs-2983	152	3	of	of	ADP
iajs-2983	152	4	the	the	DET
iajs-2983	152	5	inhibition	inhibition	NOUN
iajs-2983	152	6	zone	zone	NOUN
iajs-2983	152	7	was	be	AUX
iajs-2983	152	8	measured	measure	VERB
iajs-2983	152	9	in	in	ADP
iajs-2983	152	10	(	(	PUNCT
iajs-2983	152	11	mm	mm	INTJ
iajs-2983	152	12	)	)	PUNCT
iajs-2983	152	13	using	use	VERB
iajs-2983	152	14	amoxicillin	amoxicillin	NOUN
iajs-2983	152	15	and	and	CCONJ
iajs-2983	152	16	metronidazole	metronidazole	NOUN
iajs-2983	152	17	as	as	ADP
iajs-2983	152	18	standard	standard	ADJ
iajs-2983	152	19	drugs	drug	NOUN
iajs-2983	152	20	for	for	ADP
iajs-2983	152	21	bacteria	bacteria	NOUN
iajs-2983	152	22	and	and	CCONJ
iajs-2983	152	23	fungi	fungus	NOUN
iajs-2983	152	24	,	,	PUNCT
iajs-2983	152	25	respectively	respectively	ADV
iajs-2983	152	26	.	.	PUNCT
iajs-2983	153	1	the	the	DET
iajs-2983	153	2	ligand	ligand	NOUN
iajs-2983	153	3	and	and	CCONJ
iajs-2983	153	4	complexes	complex	NOUN
iajs-2983	153	5	generally	generally	ADV
iajs-2983	153	6	showed	show	VERB
iajs-2983	153	7	moderate	moderate	ADJ
iajs-2983	153	8	activity	activity	NOUN
iajs-2983	153	9	,	,	PUNCT
iajs-2983	153	10	and	and	CCONJ
iajs-2983	153	11	some	some	PRON
iajs-2983	153	12	were	be	AUX
iajs-2983	153	13	high	high	ADJ
iajs-2983	153	14	towards	towards	ADP
iajs-2983	153	15	bacteria	bacteria	NOUN
iajs-2983	153	16	and	and	CCONJ
iajs-2983	153	17	fungi	fungus	NOUN
iajs-2983	153	18	tested	test	VERB
iajs-2983	153	19	.	.	PUNCT
iajs-2983	154	1	the	the	DET
iajs-2983	154	2	nickel	nickel	NOUN
iajs-2983	154	3	complex	complex	NOUN
iajs-2983	154	4	showed	show	VERB
iajs-2983	154	5	higher	high	ADJ
iajs-2983	154	6	activity	activity	NOUN
iajs-2983	154	7	against	against	ADP
iajs-2983	154	8	all	all	DET
iajs-2983	154	9	bacteria	bacteria	NOUN
iajs-2983	154	10	and	and	CCONJ
iajs-2983	154	11	fungi	fungus	NOUN
iajs-2983	154	12	than	than	ADP
iajs-2983	154	13	standard	standard	ADJ
iajs-2983	154	14	drugs	drug	NOUN
iajs-2983	154	15	.	.	PUNCT
iajs-2983	155	1	this	this	PRON
iajs-2983	155	2	would	would	AUX
iajs-2983	155	3	suggest	suggest	VERB
iajs-2983	155	4	that	that	SCONJ
iajs-2983	155	5	the	the	DET
iajs-2983	155	6	chelation	chelation	NOUN
iajs-2983	155	7	could	could	AUX
iajs-2983	155	8	facilitate	facilitate	VERB
iajs-2983	155	9	the	the	DET
iajs-2983	155	10	ability	ability	NOUN
iajs-2983	155	11	of	of	ADP
iajs-2983	155	12	a	a	DET
iajs-2983	155	13	complex	complex	NOUN
iajs-2983	155	14	to	to	ADP
iajs-2983	155	15	cross	cross	NOUN
iajs-2983	155	16	-	-	NOUN
iajs-2983	155	17	brand	brand	NOUN
iajs-2983	155	18	into	into	ADP
iajs-2983	155	19	the	the	DET
iajs-2983	155	20	cell	cell	NOUN
iajs-2983	155	21	wall	wall	NOUN
iajs-2983	155	22	of	of	ADP
iajs-2983	155	23	bacteria	bacteria	NOUN
iajs-2983	155	24	and	and	CCONJ
iajs-2983	155	25	fungi	fungus	NOUN
iajs-2983	155	26	and	and	CCONJ
iajs-2983	155	27	kill	kill	VERB
iajs-2983	155	28	them	they	PRON
iajs-2983	156	1	[	[	X
iajs-2983	156	2	27	27	NUM
iajs-2983	156	3	]	]	PUNCT
iajs-2983	156	4	.	.	PUNCT
iajs-2983	157	1	table	table	NOUN
iajs-2983	157	2	5	5	NUM
iajs-2983	157	3	.	.	PUNCT
iajs-2983	157	4	antibacterial	antibacterial	ADJ
iajs-2983	157	5	activity	activity	NOUN
iajs-2983	157	6	of	of	ADP
iajs-2983	157	7	l	l	NOUN
iajs-2983	157	8	and	and	CCONJ
iajs-2983	157	9	its	its	PRON
iajs-2983	157	10	metal	metal	NOUN
iajs-2983	157	11	complexes	complex	NOUN
iajs-2983	157	12	at	at	ADP
iajs-2983	157	13	0.02	0.02	NUM
iajs-2983	157	14	m	m	NOUN
iajs-2983	157	15	inhibition	inhibition	NOUN
iajs-2983	157	16	zone	zone	NOUN
iajs-2983	157	17	(	(	PUNCT
iajs-2983	157	18	mm	mm	PROPN
iajs-2983	157	19	.	.	PUNCT
iajs-2983	157	20	)	)	PUNCT
iajs-2983	157	21	fungi	fungi	VERB
iajs-2983	157	22	gram	gram	NUM
iajs-2983	157	23	negative	negative	ADJ
iajs-2983	157	24	gram	gram	PROPN
iajs-2983	157	25	positive	positive	ADJ
iajs-2983	157	26	compounds	compound	NOUN
iajs-2983	157	27	candida	candida	PROPN
iajs-2983	157	28	klebsiella	klebsiella	PROPN
iajs-2983	157	29	e.coli	e.coli	NOUN
iajs-2983	157	30	bacillus	bacillus	NOUN
iajs-2983	157	31	staph	staph	NOUN
iajs-2983	157	32	24	24	NUM
iajs-2983	157	33	20	20	NUM
iajs-2983	157	34	16	16	NUM
iajs-2983	157	35	29	29	NUM
iajs-2983	157	36	27	27	NUM
iajs-2983	157	37	col	col	NOUN
iajs-2983	157	38	1	1	NUM
iajs-2983	157	39	27	27	NUM
iajs-2983	157	40	22	22	NUM
iajs-2983	157	41	32	32	NUM
iajs-2983	157	42	27	27	NUM
iajs-2983	157	43	35	35	NUM
iajs-2983	157	44	nil	nil	NOUN
iajs-2983	157	45	2	2	NUM
iajs-2983	157	46	18	18	NUM
iajs-2983	157	47	14	14	NUM
iajs-2983	157	48	22	22	NUM
iajs-2983	157	49	18	18	NUM
iajs-2983	157	50	21	21	NUM
iajs-2983	157	51	cul	cul	NOUN
iajs-2983	157	52	3	3	NUM
iajs-2983	157	53	21	21	NUM
iajs-2983	157	54	14	14	NUM
iajs-2983	157	55	14	14	NUM
iajs-2983	157	56	17	17	NUM
iajs-2983	157	57	18	18	NUM
iajs-2983	157	58	pdl	pdl	NOUN
iajs-2983	157	59	4	4	NUM
iajs-2983	157	60	15	15	NUM
iajs-2983	157	61	13	13	NUM
iajs-2983	157	62	15	15	NUM
iajs-2983	157	63	15	15	NUM
iajs-2983	157	64	20	20	NUM
iajs-2983	157	65	ptl	ptl	PROPN
iajs-2983	157	66	5	5	NUM
iajs-2983	157	67	15	15	NUM
iajs-2983	157	68	15	15	NUM
iajs-2983	157	69	20	20	NUM
iajs-2983	157	70	12	12	NUM
iajs-2983	157	71	20	20	NUM
iajs-2983	157	72	aul	aul	NOUN
iajs-2983	157	73	6	6	NUM
iajs-2983	157	74	-ve	-ve	NOUN
iajs-2983	157	75	-ve	-ve	NOUN
iajs-2983	157	76	-ve	-ve	NOUN
iajs-2983	157	77	-ve	-ve	NOUN
iajs-2983	157	78	-ve	-ve	NOUN
iajs-2983	157	79	dmso	dmso	NOUN
iajs-2983	157	80	7	7	NUM
iajs-2983	157	81	25	25	NUM
iajs-2983	157	82	21	21	NUM
iajs-2983	157	83	25	25	NUM
iajs-2983	157	84	25	25	NUM
iajs-2983	157	85	28	28	NUM
iajs-2983	157	86	l	l	NOUN
iajs-2983	157	87	8	8	NUM
iajs-2983	157	88	---11	---11	SYM
iajs-2983	157	89	13	13	NUM
iajs-2983	157	90	12	12	NUM
iajs-2983	157	91	12	12	NUM
iajs-2983	157	92	amoxicillin	amoxicillin	NOUN
iajs-2983	157	93	10	10	NUM
iajs-2983	157	94	13	13	NUM
iajs-2983	157	95	------------metronidazole	------------metronidazole	SYM
iajs-2983	157	96	11	11	NUM
iajs-2983	157	97	ihjpas	ihjpa	NOUN
iajs-2983	157	98	.	.	PUNCT
iajs-2983	158	1	36(1)2023	36(1)2023	NUM
iajs-2983	158	2	268	268	NUM
iajs-2983	158	3	table	table	NOUN
iajs-2983	158	4	6	6	NUM
iajs-2983	158	5	.	.	PUNCT
iajs-2983	159	1	the	the	DET
iajs-2983	159	2	vibrational	vibrational	ADJ
iajs-2983	159	3	frequencies	frequency	NOUN
iajs-2983	159	4	of	of	ADP
iajs-2983	159	5	l	l	NOUN
iajs-2983	159	6	using	use	VERB
iajs-2983	159	7	hyperchem-8.0.7	hyperchem-8.0.7	NUM
iajs-2983	159	8	program	program	NOUN
iajs-2983	159	9	symb	symb	NOUN
iajs-2983	159	10	.	.	PUNCT
iajs-2983	160	1	ν(c	ν(c	PROPN
iajs-2983	160	2	=	=	SYM
iajs-2983	160	3	n	n	CCONJ
iajs-2983	160	4	)	)	PUNCT
iajs-2983	160	5	ring	ring	NOUN
iajs-2983	160	6	νc	νc	NOUN
iajs-2983	160	7	=	=	NOUN
iajs-2983	160	8	o	o	X
iajs-2983	160	9	νcsc	νcsc	PROPN
iajs-2983	160	10	νch2	νch2	PROPN
iajs-2983	160	11	-	-	PUNCT
iajs-2983	160	12	n	n	CCONJ
iajs-2983	160	13	νcs	νcs	NOUN
iajs-2983	160	14	experimental	experimental	ADJ
iajs-2983	160	15	1620	1620	NUM
iajs-2983	160	16	1701	1701	NUM
iajs-2983	160	17	1161	1161	NUM
iajs-2983	160	18	2854	2854	NUM
iajs-2983	160	19	2943	2943	NUM
iajs-2983	160	20	702	702	NUM
iajs-2983	160	21	theoretical	theoretical	ADJ
iajs-2983	160	22	*	*	NUM
iajs-2983	160	23	1623	1623	NUM
iajs-2983	160	24	1768	1768	NUM
iajs-2983	160	25	*	*	SYM
iajs-2983	160	26	1190	1190	NUM
iajs-2983	160	27	*	*	SYM
iajs-2983	160	28	2928	2928	NUM
iajs-2983	160	29	2998	2998	NUM
iajs-2983	160	30	*	*	PUNCT
iajs-2983	161	1	*	*	PUNCT
iajs-2983	161	2	739	739	NUM
iajs-2983	161	3	percentage	percentage	NOUN
iajs-2983	161	4	of	of	ADP
iajs-2983	161	5	error	error	NOUN
iajs-2983	161	6	(	(	PUNCT
iajs-2983	161	7	0.18	0.18	NUM
iajs-2983	161	8	)	)	PUNCT
iajs-2983	161	9	(	(	PUNCT
iajs-2983	161	10	3.78	3.78	NUM
iajs-2983	161	11	)	)	PUNCT
iajs-2983	161	12	(	(	PUNCT
iajs-2983	161	13	2.43	2.43	NUM
iajs-2983	161	14	)	)	PUNCT
iajs-2983	161	15	(	(	PUNCT
iajs-2983	161	16	-1.49	-1.49	INTJ
iajs-2983	161	17	)	)	PUNCT
iajs-2983	161	18	(	(	PUNCT
iajs-2983	161	19	1.83	1.83	NUM
iajs-2983	161	20	)	)	PUNCT
iajs-2983	161	21	(	(	PUNCT
iajs-2983	161	22	5.00	5.00	NUM
iajs-2983	161	23	)	)	PUNCT
iajs-2983	161	24	figure	figure	NOUN
iajs-2983	161	25	3	3	NUM
iajs-2983	161	26	.	.	PUNCT
iajs-2983	161	27	vibration	vibration	NOUN
iajs-2983	161	28	spectra	spectra	NOUN
iajs-2983	161	29	of	of	ADP
iajs-2983	161	30	ligand	ligand	PROPN
iajs-2983	161	31	mannich	mannich	PRON
iajs-2983	161	32	base	base	NOUN
iajs-2983	161	33	(	(	PUNCT
iajs-2983	161	34	l	l	NOUN
iajs-2983	161	35	)	)	PUNCT
iajs-2983	161	36	ν	ν	PROPN
iajs-2983	161	37	nh	nh	NOUN
iajs-2983	161	38	ν	ν	X
iajs-2983	161	39	c	c	NOUN
iajs-2983	161	40	=	=	X
iajs-2983	161	41	o	o	X
iajs-2983	161	42	ν	ν	X
iajs-2983	161	43	ch2	ch2	NOUN
iajs-2983	161	44	aroma	aroma	NOUN
iajs-2983	161	45	.	.	PUNCT
iajs-2983	162	1	ν	ν	X
iajs-2983	162	2	ch2	ch2	PROPN
iajs-2983	162	3	-	-	PUNCT
iajs-2983	162	4	n	n	NOUN
iajs-2983	162	5	ν	ν	NOUN
iajs-2983	162	6	c	c	X
iajs-2983	162	7	=	=	NOUN
iajs-2983	162	8	n	n	PRON
iajs-2983	162	9	ν	ν	X
iajs-2983	162	10	ch2	ch2	NOUN
iajs-2983	162	11	-	-	PUNCT
iajs-2983	162	12	alip	alip	NOUN
iajs-2983	162	13	.	.	PUNCT
iajs-2983	163	1	ν	ν	X
iajs-2983	163	2	nh	nh	PROPN
iajs-2983	163	3	ν	ν	X
iajs-2983	163	4	c	c	NOUN
iajs-2983	163	5	=	=	X
iajs-2983	163	6	o	o	X
iajs-2983	163	7	ν	ν	X
iajs-2983	163	8	ch2	ch2	NOUN
iajs-2983	163	9	aroma	aroma	NOUN
iajs-2983	163	10	.	.	PUNCT
iajs-2983	164	1	ihjpas	ihjpas	PROPN
iajs-2983	164	2	.	.	PUNCT
iajs-2983	165	1	36(1)2023	36(1)2023	NUM
iajs-2983	165	2	269	269	NUM
iajs-2983	165	3	figure	figure	NOUN
iajs-2983	165	4	4	4	NUM
iajs-2983	165	5	.	.	PUNCT
iajs-2983	165	6	homo	homo	NOUN
iajs-2983	165	7	,	,	PUNCT
iajs-2983	165	8	lumo	lumo	NOUN
iajs-2983	165	9	and	and	CCONJ
iajs-2983	165	10	,	,	PUNCT
iajs-2983	165	11	electrostatic	electrostatic	ADJ
iajs-2983	165	12	potential	potential	NOUN
iajs-2983	165	13	of	of	ADP
iajs-2983	165	14	ligand	ligand	ADJ
iajs-2983	165	15	l	l	PROPN
iajs-2983	165	16	table	table	NOUN
iajs-2983	165	17	7	7	NUM
iajs-2983	165	18	.	.	X
iajs-2983	165	19	heat	heat	NOUN
iajs-2983	165	20	of	of	ADP
iajs-2983	165	21	formation	formation	NOUN
iajs-2983	165	22	,	,	PUNCT
iajs-2983	165	23	binding	bind	VERB
iajs-2983	165	24	energy	energy	NOUN
iajs-2983	165	25	(	(	PUNCT
iajs-2983	165	26	in	in	ADP
iajs-2983	165	27	kj.mol-1	kj.mol-1	NUM
iajs-2983	165	28	)	)	PUNCT
iajs-2983	165	29	and	and	CCONJ
iajs-2983	165	30	dipole	dipole	NOUN
iajs-2983	165	31	,	,	PUNCT
iajs-2983	165	32	moment	moment	NOUN
iajs-2983	165	33	(	(	PUNCT
iajs-2983	165	34	in	in	ADP
iajs-2983	165	35	debye	debye	ADJ
iajs-2983	165	36	)	)	PUNCT
iajs-2983	165	37	for	for	ADP
iajs-2983	165	38	ligand	ligand	ADJ
iajs-2983	165	39	,	,	PUNCT
iajs-2983	165	40	(	(	PUNCT
iajs-2983	165	41	l	l	NOUN
iajs-2983	165	42	)	)	PUNCT
iajs-2983	165	43	and	and	CCONJ
iajs-2983	165	44	it	it	PRON
iajs-2983	165	45	's	be	AUX
iajs-2983	165	46	metal	metal	NOUN
iajs-2983	165	47	complexes	complex	NOUN
iajs-2983	165	48	,	,	PUNCT
iajs-2983	165	49	using	use	VERB
iajs-2983	165	50	hyperchem-8.0.7	hyperchem-8.0.7	NUM
iajs-2983	165	51	program	program	NOUN
iajs-2983	165	52	pm3	pm3	PROPN
iajs-2983	165	53	zindo/1	zindo/1	PROPN
iajs-2983	165	54	amber	amber	PROPN
iajs-2983	165	55	comp	comp	PROPN
iajs-2983	165	56	.	.	PUNCT
iajs-2983	166	1	δh	δh	PROPN
iajs-2983	166	2	°	°	PROPN
iajs-2983	166	3	f	f	PROPN
iajs-2983	166	4	δeb	δeb	NOUN
iajs-2983	166	5	µ	µ	PRON
iajs-2983	166	6	δh	δh	NOUN
iajs-2983	166	7	°	°	PROPN
iajs-2983	166	8	f	f	PROPN
iajs-2983	166	9	δeb	δeb	NOUN
iajs-2983	166	10	µ	µ	PROPN
iajs-2983	166	11	δeb=	δeb=	PUNCT
iajs-2983	166	12	δh	δh	NOUN
iajs-2983	166	13	°	°	NOUN
iajs-2983	166	14	f	f	PROPN
iajs-2983	166	15	µ	µ	X
iajs-2983	166	16	l	l	NOUN
iajs-2983	166	17	17.09737	17.09737	NUM
iajs-2983	166	18	3146.681621.73	3146.681621.73	NOUN
iajs-2983	166	19	-8705.7206	-8705.7206	PROPN
iajs-2983	166	20	-12205.5026	-12205.5026	PROPN
iajs-2983	166	21	3.23	3.23	NUM
iajs-2983	166	22	------	------	PUNCT
iajs-2983	166	23	col	col	PROPN
iajs-2983	167	1	330.35853953.053574.78	330.35853953.053574.78	NOUN
iajs-2983	167	2	-6958.85848	-6958.85848	INTJ
iajs-2983	167	3	-10581.55348	-10581.55348	PROPN
iajs-2983	167	4	9.57	9.57	NUM
iajs-2983	167	5	------	------	PUNCT
iajs-2983	167	6	nil	nil	ADJ
iajs-2983	167	7	185.61811	185.61811	NUM
iajs-2983	167	8	-	-	SYM
iajs-2983	167	9	3673.94011	3673.94011	NUM
iajs-2983	167	10	4.32	4.32	NUM
iajs-2983	167	11	-6893.90242	-6893.90242	NOUN
iajs-2983	167	12	-10382.22442	-10382.22442	PROPN
iajs-2983	168	1	6.30	6.30	NUM
iajs-2983	168	2	------	------	PUNCT
iajs-2983	168	3	cul	cul	PROPN
iajs-2983	168	4	175.427553776.422552.22	175.427553776.422552.22	NUM
iajs-2983	168	5	-6999.43292	-6999.43292	NOUN
iajs-2983	168	6	-10600.42792	-10600.42792	PROPN
iajs-2983	168	7	5.17	5.17	NUM
iajs-2983	168	8	------	------	PUNCT
iajs-2983	168	9	pdl	pdl	NOUN
iajs-2983	168	10	------------------88.4691	------------------88.4691	PROPN
iajs-2983	168	11	3.35	3.35	NUM
iajs-2983	168	12	ptl	ptl	PROPN
iajs-2983	168	13	------------------255.7924	------------------255.7924	PROPN
iajs-2983	168	14	4.06	4.06	NUM
iajs-2983	168	15	aul	aul	NOUN
iajs-2983	168	16	------------------89.5963	------------------89.5963	PROPN
iajs-2983	168	17	3.22	3.22	NUM
iajs-2983	168	18	5	5	NUM
iajs-2983	168	19	.	.	PUNCT
iajs-2983	169	1	conclusion	conclusion	NOUN
iajs-2983	169	2	mannich	mannich	SCONJ
iajs-2983	169	3	base	base	PROPN
iajs-2983	169	4	ligand	ligand	NOUN
iajs-2983	169	5	complexes	complex	NOUN
iajs-2983	169	6	have	have	AUX
iajs-2983	169	7	been	be	AUX
iajs-2983	169	8	successfully	successfully	ADV
iajs-2983	169	9	synthesized	synthesize	VERB
iajs-2983	169	10	using	use	VERB
iajs-2983	169	11	the	the	DET
iajs-2983	169	12	conventional	conventional	ADJ
iajs-2983	169	13	method	method	NOUN
iajs-2983	169	14	.	.	PUNCT
iajs-2983	170	1	the	the	DET
iajs-2983	170	2	assembly	assembly	NOUN
iajs-2983	170	3	of	of	ADP
iajs-2983	170	4	the	the	DET
iajs-2983	170	5	six	six	NUM
iajs-2983	170	6	proposed	propose	VERB
iajs-2983	170	7	complexes	complex	NOUN
iajs-2983	170	8	was	be	AUX
iajs-2983	170	9	successfully	successfully	ADV
iajs-2983	170	10	achieved	achieve	VERB
iajs-2983	170	11	by	by	ADP
iajs-2983	170	12	the	the	DET
iajs-2983	170	13	procedures	procedure	NOUN
iajs-2983	170	14	previously	previously	ADV
iajs-2983	170	15	described	describe	VERB
iajs-2983	170	16	.	.	PUNCT
iajs-2983	171	1	the	the	DET
iajs-2983	171	2	results	result	NOUN
iajs-2983	171	3	obtained	obtain	VERB
iajs-2983	171	4	from	from	ADP
iajs-2983	171	5	this	this	DET
iajs-2983	171	6	investigation	investigation	NOUN
iajs-2983	171	7	were	be	AUX
iajs-2983	171	8	obtained	obtain	VERB
iajs-2983	171	9	according	accord	VERB
iajs-2983	171	10	to	to	ADP
iajs-2983	171	11	the	the	DET
iajs-2983	171	12	data	datum	NOUN
iajs-2983	171	13	presented	present	VERB
iajs-2983	171	14	by	by	ADP
iajs-2983	171	15	the	the	DET
iajs-2983	171	16	physical	physical	ADJ
iajs-2983	171	17	and	and	CCONJ
iajs-2983	171	18	chemical	chemical	NOUN
iajs-2983	171	19	analysis	analysis	NOUN
iajs-2983	171	20	.	.	PUNCT
iajs-2983	172	1	the	the	DET
iajs-2983	172	2	results	result	NOUN
iajs-2983	172	3	showed	show	VERB
iajs-2983	172	4	that	that	SCONJ
iajs-2983	172	5	the	the	DET
iajs-2983	172	6	complexes	complex	NOUN
iajs-2983	172	7	have	have	VERB
iajs-2983	172	8	an	an	DET
iajs-2983	172	9	octahedral	octahedral	ADJ
iajs-2983	172	10	geometry	geometry	NOUN
iajs-2983	172	11	for	for	ADP
iajs-2983	172	12	the	the	DET
iajs-2983	172	13	cobalt	cobalt	NOUN
iajs-2983	172	14	,	,	PUNCT
iajs-2983	172	15	nickel	nickel	NOUN
iajs-2983	172	16	,	,	PUNCT
iajs-2983	172	17	copper	copper	NOUN
iajs-2983	172	18	,	,	PUNCT
iajs-2983	172	19	and	and	CCONJ
iajs-2983	172	20	platinum	platinum	NOUN
iajs-2983	172	21	complexes	complex	NOUN
iajs-2983	172	22	and	and	CCONJ
iajs-2983	172	23	a	a	DET
iajs-2983	172	24	square	square	ADJ
iajs-2983	172	25	-	-	PUNCT
iajs-2983	172	26	planer	planer	NOUN
iajs-2983	172	27	geometry	geometry	NOUN
iajs-2983	172	28	for	for	ADP
iajs-2983	172	29	the	the	DET
iajs-2983	172	30	palladium	palladium	NOUN
iajs-2983	172	31	and	and	CCONJ
iajs-2983	172	32	gold	gold	NOUN
iajs-2983	172	33	complexes	complex	NOUN
iajs-2983	172	34	.	.	PUNCT
iajs-2983	173	1	ni	ni	PROPN
iajs-2983	173	2	complex	complex	PROPN
iajs-2983	173	3	showed	show	VERB
iajs-2983	173	4	good	good	ADJ
iajs-2983	173	5	activity	activity	NOUN
iajs-2983	173	6	against	against	ADP
iajs-2983	173	7	positive	positive	ADJ
iajs-2983	173	8	and	and	CCONJ
iajs-2983	173	9	negative	negative	ADJ
iajs-2983	173	10	bacteria	bacteria	NOUN
iajs-2983	173	11	and	and	CCONJ
iajs-2983	173	12	fungi	fungus	NOUN
iajs-2983	173	13	compared	compare	VERB
iajs-2983	173	14	to	to	ADP
iajs-2983	173	15	amoxicillin	amoxicillin	PROPN
iajs-2983	173	16	and	and	CCONJ
iajs-2983	173	17	metronidazol	metronidazol	VERB
iajs-2983	173	18	.	.	PUNCT
iajs-2983	174	1	the	the	DET
iajs-2983	174	2	standard	standard	ADJ
iajs-2983	174	3	heat	heat	NOUN
iajs-2983	174	4	of	of	ADP
iajs-2983	174	5	formation	formation	NOUN
iajs-2983	174	6	and	and	CCONJ
iajs-2983	174	7	binding	bind	VERB
iajs-2983	174	8	energy	energy	NOUN
iajs-2983	174	9	was	be	AUX
iajs-2983	174	10	calculated	calculate	VERB
iajs-2983	174	11	using	use	VERB
iajs-2983	174	12	the	the	DET
iajs-2983	174	13	hyperchem	hyperchem	NOUN
iajs-2983	174	14	8.0.7	8.0.7	NUM
iajs-2983	174	15	program	program	NOUN
iajs-2983	174	16	,	,	PUNCT
iajs-2983	174	17	proving	prove	VERB
iajs-2983	174	18	that	that	SCONJ
iajs-2983	174	19	the	the	DET
iajs-2983	174	20	complexes	complex	NOUN
iajs-2983	174	21	are	be	AUX
iajs-2983	174	22	more	more	ADV
iajs-2983	174	23	stable	stable	ADJ
iajs-2983	174	24	than	than	ADP
iajs-2983	174	25	the	the	DET
iajs-2983	174	26	ligand	ligand	NOUN
iajs-2983	174	27	.	.	PUNCT
iajs-2983	175	1	ihjpas	ihjpas	PROPN
iajs-2983	175	2	.	.	PUNCT
iajs-2983	176	1	36(1)2023	36(1)2023	NUM
iajs-2983	176	2	270	270	NUM
iajs-2983	176	3	references	reference	NOUN
iajs-2983	176	4	1	1	NUM
iajs-2983	176	5	.	.	PUNCT
iajs-2983	176	6	jia	jia	PROPN
iajs-2983	176	7	,	,	PUNCT
iajs-2983	176	8	x.	x.	PROPN
iajs-2983	176	9	;	;	PUNCT
iajs-2983	176	10	liu	liu	PROPN
iajs-2983	176	11	,	,	PUNCT
iajs-2983	176	12	q.	q.	PROPN
iajs-2983	176	13	;	;	PUNCT
iajs-2983	176	14	wang	wang	PROPN
iajs-2983	176	15	,	,	PUNCT
iajs-2983	176	16	s.	s.	PROPN
iajs-2983	176	17	;	;	PUNCT
iajs-2983	176	18	zeng	zeng	PROPN
iajs-2983	176	19	,	,	PUNCT
iajs-2983	176	20	b.	b.	PROPN
iajs-2983	176	21	;	;	PUNCT
iajs-2983	176	22	du	du	PROPN
iajs-2983	176	23	,	,	PUNCT
iajs-2983	176	24	g.	g.	PROPN
iajs-2983	176	25	;	;	PUNCT
iajs-2983	176	26	zhang	zhang	PROPN
iajs-2983	176	27	,	,	PUNCT
iajs-2983	176	28	c.	c.	PROPN
iajs-2983	176	29	;	;	PUNCT
iajs-2983	176	30	li	li	PROPN
iajs-2983	176	31	,	,	PUNCT
iajs-2983	176	32	y.	y.	PROPN
iajs-2983	176	33	synthesis	synthesis	NOUN
iajs-2983	176	34	,	,	PUNCT
iajs-2983	176	35	cytotoxicity	cytotoxicity	NOUN
iajs-2983	176	36	,	,	PUNCT
iajs-2983	176	37	and	and	CCONJ
iajs-2983	176	38	in	in	ADP
iajs-2983	176	39	vivo	vivo	ADJ
iajs-2983	176	40	antitumor	antitumor	NOUN
iajs-2983	176	41	activity	activity	NOUN
iajs-2983	176	42	study	study	NOUN
iajs-2983	176	43	of	of	ADP
iajs-2983	176	44	parthenolide	parthenolide	ADJ
iajs-2983	176	45	semicarbazones	semicarbazone	NOUN
iajs-2983	176	46	and	and	CCONJ
iajs-2983	176	47	thiosemicarbazones	thiosemicarbazone	NOUN
iajs-2983	176	48	.	.	PUNCT
iajs-2983	177	1	bioorganic	bioorganic	PROPN
iajs-2983	177	2	&	&	CCONJ
iajs-2983	177	3	medicinal	medicinal	ADJ
iajs-2983	177	4	chemistry	chemistry	NOUN
iajs-2983	177	5	2020	2020	NUM
iajs-2983	177	6	,	,	PUNCT
iajs-2983	177	7	28	28	NUM
iajs-2983	177	8	,	,	PUNCT
iajs-2983	177	9	115557	115557	NUM
iajs-2983	177	10	,	,	PUNCT
iajs-2983	177	11	doi:10.1016	doi:10.1016	PROPN
iajs-2983	177	12	/	/	SYM
iajs-2983	177	13	j.bmc.2020.115557	j.bmc.2020.115557	PROPN
iajs-2983	177	14	.	.	PUNCT
iajs-2983	178	1	2	2	X
iajs-2983	178	2	.	.	X
iajs-2983	178	3	roder	roder	PROPN
iajs-2983	178	4	,	,	PUNCT
iajs-2983	178	5	c.	c.	PROPN
iajs-2983	178	6	;	;	PUNCT
iajs-2983	178	7	thomson	thomson	PROPN
iajs-2983	178	8	,	,	PUNCT
iajs-2983	178	9	m.j	m.j	PROPN
iajs-2983	178	10	.	.	PROPN
iajs-2983	178	11	auranofin	auranofin	PROPN
iajs-2983	178	12	:	:	PUNCT
iajs-2983	178	13	repurposing	repurpose	VERB
iajs-2983	178	14	an	an	DET
iajs-2983	178	15	old	old	ADJ
iajs-2983	178	16	drug	drug	NOUN
iajs-2983	178	17	for	for	ADP
iajs-2983	178	18	a	a	DET
iajs-2983	178	19	golden	golden	ADJ
iajs-2983	178	20	new	new	ADJ
iajs-2983	178	21	age	age	NOUN
iajs-2983	178	22	.	.	PUNCT
iajs-2983	179	1	drugs	drug	NOUN
iajs-2983	179	2	r	r	NOUN
iajs-2983	179	3	d	d	PROPN
iajs-2983	179	4	2015	2015	NUM
iajs-2983	179	5	,	,	PUNCT
iajs-2983	179	6	15	15	NUM
iajs-2983	179	7	,	,	PUNCT
iajs-2983	179	8	13–20	13–20	NUM
iajs-2983	179	9	,	,	PUNCT
iajs-2983	179	10	doi:10.1007	doi:10.1007	NOUN
iajs-2983	179	11	/	/	SYM
iajs-2983	179	12	s40268	s40268	NOUN
iajs-2983	179	13	-	-	PUNCT
iajs-2983	179	14	015	015	NUM
iajs-2983	179	15	-	-	PUNCT
iajs-2983	179	16	0083	0083	NUM
iajs-2983	179	17	-	-	PUNCT
iajs-2983	179	18	y.	y.	NOUN
iajs-2983	179	19	3	3	PROPN
iajs-2983	179	20	.	.	PUNCT
iajs-2983	179	21	jain	jain	PROPN
iajs-2983	179	22	,	,	PUNCT
iajs-2983	179	23	a.k	a.k	PROPN
iajs-2983	179	24	.	.	PROPN
iajs-2983	179	25	;	;	PUNCT
iajs-2983	179	26	sharma	sharma	PROPN
iajs-2983	179	27	,	,	PUNCT
iajs-2983	179	28	s.	s.	PROPN
iajs-2983	179	29	;	;	PUNCT
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iajs-2983	179	32	a.	a.	NOUN
iajs-2983	179	33	;	;	PUNCT
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iajs-2983	179	35	,	,	PUNCT
iajs-2983	179	36	v.	v.	ADV
iajs-2983	179	37	;	;	PUNCT
iajs-2983	179	38	agrawal	agrawal	PROPN
iajs-2983	179	39	,	,	PUNCT
iajs-2983	179	40	r.k	r.k	PROPN
iajs-2983	179	41	.	.	PROPN
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iajs-2983	179	43	-	-	NOUN
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iajs-2983	179	45	and	and	CCONJ
iajs-2983	179	46	its	its	PRON
iajs-2983	179	47	derivatives	derivative	NOUN
iajs-2983	179	48	:	:	PUNCT
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iajs-2983	179	50	review	review	NOUN
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iajs-2983	179	53	progress	progress	NOUN
iajs-2983	179	54	in	in	ADP
iajs-2983	179	55	biological	biological	ADJ
iajs-2983	179	56	activities	activity	NOUN
iajs-2983	179	57	.	.	PUNCT
iajs-2983	180	1	chemical	chemical	NOUN
iajs-2983	180	2	biology	biology	PROPN
iajs-2983	180	3	&	&	CCONJ
iajs-2983	180	4	drug	drug	PROPN
iajs-2983	180	5	design	design	PROPN
iajs-2983	180	6	2013	2013	NUM
iajs-2983	180	7	,	,	PUNCT
iajs-2983	180	8	81	81	NUM
iajs-2983	180	9	,	,	PUNCT
iajs-2983	180	10	557–576	557–576	NUM
iajs-2983	180	11	,	,	PUNCT
iajs-2983	181	1	doi:10.1111	doi:10.1111	NOUN
iajs-2983	181	2	/	/	SYM
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iajs-2983	181	4	.	.	NOUN
iajs-2983	182	1	4	4	NUM
iajs-2983	182	2	.	.	X
iajs-2983	182	3	ainsworth	ainsworth	PROPN
iajs-2983	182	4	,	,	PUNCT
iajs-2983	182	5	c.	c.	PROPN
iajs-2983	182	6	the	the	DET
iajs-2983	182	7	condensation	condensation	NOUN
iajs-2983	182	8	of	of	ADP
iajs-2983	182	9	aryl	aryl	NOUN
iajs-2983	182	10	carboxylic	carboxylic	ADJ
iajs-2983	182	11	acid	acid	NOUN
iajs-2983	182	12	hydrazides	hydrazide	NOUN
iajs-2983	182	13	with	with	ADP
iajs-2983	182	14	orthoesters	orthoester	NOUN
iajs-2983	182	15	.	.	PUNCT
iajs-2983	183	1	j	j	PROPN
iajs-2983	183	2	am	be	AUX
iajs-2983	183	3	chem	chem	NOUN
iajs-2983	183	4	soc	soc	NOUN
iajs-2983	183	5	1955	1955	NUM
iajs-2983	183	6	,	,	PUNCT
iajs-2983	183	7	77	77	NUM
iajs-2983	183	8	,	,	PUNCT
iajs-2983	183	9	1148–1150	1148–1150	NUM
iajs-2983	183	10	,	,	PUNCT
iajs-2983	183	11	doi:10.1021	doi:10.1021	PROPN
iajs-2983	183	12	/	/	SYM
iajs-2983	183	13	ja01610a019	ja01610a019	PROPN
iajs-2983	183	14	.	.	PUNCT
iajs-2983	184	1	5	5	X
iajs-2983	184	2	.	.	X
iajs-2983	184	3	de	de	PROPN
iajs-2983	184	4	andrade	andrade	PROPN
iajs-2983	184	5	danin	danin	PROPN
iajs-2983	184	6	barbosa	barbosa	PROPN
iajs-2983	184	7	,	,	PUNCT
iajs-2983	184	8	g.	g.	PROPN
iajs-2983	184	9	;	;	PUNCT
iajs-2983	184	10	palermo	palermo	PROPN
iajs-2983	184	11	de	de	X
iajs-2983	184	12	aguiar	aguiar	PROPN
iajs-2983	184	13	,	,	PUNCT
iajs-2983	184	14	a.	a.	NOUN
iajs-2983	184	15	synthesis	synthesis	NOUN
iajs-2983	184	16	of	of	ADP
iajs-2983	184	17	1,3,4	1,3,4	NUM
iajs-2983	184	18	-	-	PUNCT
iajs-2983	184	19	thiadiazole	thiadiazole	NOUN
iajs-2983	184	20	derivatives	derivative	NOUN
iajs-2983	184	21	and	and	CCONJ
iajs-2983	184	22	microbiological	microbiological	ADJ
iajs-2983	184	23	activities	activity	NOUN
iajs-2983	184	24	:	:	PUNCT
iajs-2983	184	25	a	a	DET
iajs-2983	184	26	review	review	NOUN
iajs-2983	184	27	.	.	PUNCT
iajs-2983	185	1	revista	revista	PROPN
iajs-2983	185	2	virtual	virtual	PROPN
iajs-2983	185	3	de	de	PROPN
iajs-2983	185	4	química	química	PROPN
iajs-2983	185	5	2019	2019	NUM
iajs-2983	185	6	,	,	PUNCT
iajs-2983	185	7	11	11	NUM
iajs-2983	185	8	,	,	PUNCT
iajs-2983	185	9	806–848	806–848	NUM
iajs-2983	185	10	,	,	PUNCT
iajs-2983	185	11	doi:10.21577/19846835.20190058	doi:10.21577/19846835.20190058	NOUN
iajs-2983	185	12	.	.	PUNCT
iajs-2983	186	1	6	6	NUM
iajs-2983	186	2	.	.	X
iajs-2983	186	3	pandey	pandey	PROPN
iajs-2983	186	4	,	,	PUNCT
iajs-2983	186	5	a.	a.	NOUN
iajs-2983	186	6	;	;	PUNCT
iajs-2983	186	7	rajavel	rajavel	VERB
iajs-2983	186	8	,	,	PUNCT
iajs-2983	186	9	r.	r.	PROPN
iajs-2983	186	10	;	;	PUNCT
iajs-2983	186	11	chandraker	chandraker	PROPN
iajs-2983	186	12	,	,	PUNCT
iajs-2983	186	13	s.	s.	PROPN
iajs-2983	186	14	;	;	PUNCT
iajs-2983	186	15	dash	dash	NOUN
iajs-2983	186	16	,	,	PUNCT
iajs-2983	186	17	d.	d.	NOUN
iajs-2983	186	18	synthesis	synthesis	NOUN
iajs-2983	186	19	of	of	ADP
iajs-2983	186	20	schiff	schiff	NOUN
iajs-2983	186	21	bases	basis	NOUN
iajs-2983	186	22	of	of	ADP
iajs-2983	186	23	2	2	NUM
iajs-2983	186	24	-	-	PUNCT
iajs-2983	186	25	amino-5	amino-5	NUM
iajs-2983	186	26	-	-	PUNCT
iajs-2983	186	27	aryl-1,3,4thiadiazole	aryl-1,3,4thiadiazole	PROPN
iajs-2983	186	28	and	and	CCONJ
iajs-2983	186	29	its	its	PRON
iajs-2983	186	30	analgesic	analgesic	ADJ
iajs-2983	186	31	,	,	PUNCT
iajs-2983	186	32	anti	anti	ADJ
iajs-2983	186	33	-	-	ADJ
iajs-2983	186	34	inflammatory	inflammatory	ADJ
iajs-2983	186	35	and	and	CCONJ
iajs-2983	186	36	anti	anti	ADJ
iajs-2983	186	37	-	-	ADJ
iajs-2983	186	38	bacterial	bacterial	ADJ
iajs-2983	186	39	activity	activity	NOUN
iajs-2983	186	40	.	.	PUNCT
iajs-2983	187	1	e	e	X
iajs-2983	187	2	-	-	NOUN
iajs-2983	187	3	journal	journal	NOUN
iajs-2983	187	4	of	of	ADP
iajs-2983	187	5	chemistry	chemistry	NOUN
iajs-2983	187	6	2012	2012	NUM
iajs-2983	187	7	,	,	PUNCT
iajs-2983	187	8	9	9	NUM
iajs-2983	187	9	,	,	PUNCT
iajs-2983	187	10	2524–2531	2524–2531	NUM
iajs-2983	187	11	,	,	PUNCT
iajs-2983	187	12	doi:10.1155/2012/145028	doi:10.1155/2012/145028	PROPN
iajs-2983	187	13	.	.	PUNCT
iajs-2983	188	1	7	7	X
iajs-2983	188	2	.	.	NUM
iajs-2983	188	3	schweinfurth	schweinfurth	NOUN
iajs-2983	188	4	,	,	PUNCT
iajs-2983	188	5	d.	d.	PROPN
iajs-2983	188	6	;	;	PUNCT
iajs-2983	188	7	krzystek	krzystek	PROPN
iajs-2983	188	8	,	,	PUNCT
iajs-2983	188	9	j.	j.	PROPN
iajs-2983	188	10	;	;	PUNCT
iajs-2983	188	11	schapiro	schapiro	PROPN
iajs-2983	188	12	,	,	PUNCT
iajs-2983	188	13	i.	i.	NOUN
iajs-2983	188	14	;	;	PUNCT
iajs-2983	188	15	demeshko	demeshko	PROPN
iajs-2983	188	16	,	,	PUNCT
iajs-2983	188	17	s.	s.	PROPN
iajs-2983	188	18	;	;	PUNCT
iajs-2983	188	19	klein	klein	PROPN
iajs-2983	188	20	,	,	PUNCT
iajs-2983	188	21	j.	j.	PROPN
iajs-2983	188	22	;	;	PUNCT
iajs-2983	188	23	telser	telser	PROPN
iajs-2983	188	24	,	,	PUNCT
iajs-2983	188	25	j.	j.	PROPN
iajs-2983	188	26	;	;	PUNCT
iajs-2983	189	1	ozarowski	ozarowski	ADJ
iajs-2983	189	2	,	,	PUNCT
iajs-2983	189	3	a.	a.	NOUN
iajs-2983	189	4	;	;	PUNCT
iajs-2983	189	5	su	su	PROPN
iajs-2983	189	6	,	,	PUNCT
iajs-2983	189	7	c.y	c.y	PROPN
iajs-2983	189	8	.	.	PROPN
iajs-2983	189	9	;	;	PUNCT
iajs-2983	189	10	meyer	meyer	PROPN
iajs-2983	189	11	,	,	PUNCT
iajs-2983	189	12	f.	f.	PROPN
iajs-2983	189	13	;	;	PUNCT
iajs-2983	189	14	atanasov	atanasov	NOUN
iajs-2983	189	15	,	,	PUNCT
iajs-2983	189	16	m.	m.	NOUN
iajs-2983	189	17	;	;	PUNCT
iajs-2983	189	18	et	et	PROPN
iajs-2983	189	19	al	al	PROPN
iajs-2983	189	20	.	.	PROPN
iajs-2983	189	21	electronic	electronic	ADJ
iajs-2983	189	22	structures	structure	NOUN
iajs-2983	189	23	of	of	ADP
iajs-2983	189	24	octahedral	octahedral	ADJ
iajs-2983	189	25	ni(ii	ni(ii	PROPN
iajs-2983	189	26	)	)	PUNCT
iajs-2983	189	27	complexes	complex	NOUN
iajs-2983	189	28	with	with	ADP
iajs-2983	189	29	“	"	PUNCT
iajs-2983	189	30	click	click	VERB
iajs-2983	189	31	”	"	PUNCT
iajs-2983	189	32	derived	derive	VERB
iajs-2983	189	33	triazole	triazole	NOUN
iajs-2983	189	34	ligands	ligand	NOUN
iajs-2983	189	35	:	:	PUNCT
iajs-2983	189	36	a	a	DET
iajs-2983	189	37	combined	combine	VERB
iajs-2983	189	38	structural	structural	ADJ
iajs-2983	189	39	,	,	PUNCT
iajs-2983	189	40	magnetometric	magnetometric	ADJ
iajs-2983	189	41	,	,	PUNCT
iajs-2983	189	42	spectroscopic	spectroscopic	NOUN
iajs-2983	189	43	,	,	PUNCT
iajs-2983	189	44	and	and	CCONJ
iajs-2983	189	45	theoretical	theoretical	ADJ
iajs-2983	189	46	study	study	NOUN
iajs-2983	189	47	.	.	PUNCT
iajs-2983	190	1	inorganic	inorganic	ADJ
iajs-2983	190	2	chemistry	chemistry	NOUN
iajs-2983	190	3	2013	2013	NUM
iajs-2983	190	4	,	,	PUNCT
iajs-2983	190	5	52	52	NUM
iajs-2983	190	6	,	,	PUNCT
iajs-2983	190	7	6880–6892	6880–6892	NOUN
iajs-2983	190	8	,	,	PUNCT
iajs-2983	190	9	doi:10.1021	doi:10.1021	ADJ
iajs-2983	190	10	/	/	SYM
iajs-2983	190	11	ic3026123	ic3026123	NOUN
iajs-2983	190	12	.	.	PUNCT
iajs-2983	191	1	8	8	X
iajs-2983	191	2	.	.	PUNCT
iajs-2983	191	3	g.	g.	PROPN
iajs-2983	191	4	pyne	pyne	PROPN
iajs-2983	191	5	,	,	PUNCT
iajs-2983	191	6	s.	s.	PROPN
iajs-2983	191	7	;	;	PUNCT
iajs-2983	191	8	tang	tang	PROPN
iajs-2983	191	9	,	,	PUNCT
iajs-2983	191	10	m.	m.	NOUN
iajs-2983	191	11	the	the	DET
iajs-2983	191	12	boronic	boronic	ADJ
iajs-2983	191	13	acid	acid	PROPN
iajs-2983	191	14	mannich	mannich	PROPN
iajs-2983	191	15	reaction	reaction	NOUN
iajs-2983	191	16	.	.	PUNCT
iajs-2983	192	1	in	in	ADP
iajs-2983	192	2	organic	organic	ADJ
iajs-2983	192	3	reactions	reaction	NOUN
iajs-2983	192	4	,	,	PUNCT
iajs-2983	192	5	john	john	PROPN
iajs-2983	192	6	wiley	wiley	PROPN
iajs-2983	192	7	&	&	CCONJ
iajs-2983	192	8	sons	sons	PROPN
iajs-2983	192	9	,	,	PUNCT
iajs-2983	192	10	inc	inc	PROPN
iajs-2983	192	11	.	.	PROPN
iajs-2983	192	12	:	:	PUNCT
iajs-2983	192	13	hoboken	hoboken	PROPN
iajs-2983	192	14	,	,	PUNCT
iajs-2983	192	15	nj	nj	PROPN
iajs-2983	192	16	,	,	PUNCT
iajs-2983	192	17	usa	usa	PROPN
iajs-2983	192	18	,	,	PUNCT
iajs-2983	192	19	2013	2013	NUM
iajs-2983	192	20	,	,	PUNCT
iajs-2983	192	21	211–498	211–498	NUM
iajs-2983	192	22	.	.	PUNCT
iajs-2983	193	1	9	9	X
iajs-2983	193	2	.	.	X
iajs-2983	193	3	singh	singh	PROPN
iajs-2983	193	4	,	,	PUNCT
iajs-2983	193	5	b.n	b.n	PROPN
iajs-2983	193	6	.	.	PROPN
iajs-2983	193	7	;	;	PUNCT
iajs-2983	193	8	shukla	shukla	NOUN
iajs-2983	193	9	,	,	PUNCT
iajs-2983	193	10	s.k	s.k	PROPN
iajs-2983	193	11	.	.	PROPN
iajs-2983	193	12	;	;	PUNCT
iajs-2983	193	13	singh	singh	PROPN
iajs-2983	193	14	,	,	PUNCT
iajs-2983	193	15	m.	m.	NOUN
iajs-2983	193	16	synthesis	synthesis	NOUN
iajs-2983	193	17	and	and	CCONJ
iajs-2983	193	18	biological	biological	ADJ
iajs-2983	193	19	activity	activity	NOUN
iajs-2983	193	20	of	of	ADP
iajs-2983	193	21	sulphadiazine	sulphadiazine	ADJ
iajs-2983	193	22	schiff\	schiff\	PROPN
iajs-2983	193	23	’	'	PUNCT
iajs-2983	193	24	{	{	PUNCT
iajs-2983	193	25	}	}	PUNCT
iajs-2983	193	26	s	s	PART
iajs-2983	193	27	bases	basis	NOUN
iajs-2983	193	28	of	of	ADP
iajs-2983	193	29	isatin	isatin	NOUN
iajs-2983	193	30	and	and	CCONJ
iajs-2983	193	31	their	their	PRON
iajs-2983	193	32	n	n	CCONJ
iajs-2983	193	33	-	-	PUNCT
iajs-2983	193	34	mannich	mannich	NOUN
iajs-2983	193	35	bases	basis	NOUN
iajs-2983	193	36	.	.	PUNCT
iajs-2983	194	1	asian	asian	ADJ
iajs-2983	194	2	journal	journal	NOUN
iajs-2983	194	3	of	of	ADP
iajs-2983	194	4	chemistry	chemistry	NOUN
iajs-2983	194	5	2007	2007	NUM
iajs-2983	194	6	,	,	PUNCT
iajs-2983	194	7	19	19	NUM
iajs-2983	194	8	,	,	PUNCT
iajs-2983	194	9	5013	5013	NUM
iajs-2983	194	10	.	.	PUNCT
iajs-2983	195	1	10	10	NUM
iajs-2983	195	2	.	.	X
iajs-2983	195	3	sumrra	sumrra	PROPN
iajs-2983	195	4	,	,	PUNCT
iajs-2983	195	5	s.h	s.h	PROPN
iajs-2983	195	6	.	.	PROPN
iajs-2983	195	7	;	;	PUNCT
iajs-2983	195	8	arshad	arshad	PROPN
iajs-2983	195	9	,	,	PUNCT
iajs-2983	195	10	z.	z.	PROPN
iajs-2983	195	11	;	;	PUNCT
iajs-2983	195	12	zafar	zafar	PROPN
iajs-2983	195	13	,	,	PUNCT
iajs-2983	195	14	w.	w.	PROPN
iajs-2983	195	15	;	;	PUNCT
iajs-2983	195	16	mahmood	mahmood	PROPN
iajs-2983	195	17	,	,	PUNCT
iajs-2983	195	18	k.	k.	PROPN
iajs-2983	195	19	;	;	PUNCT
iajs-2983	195	20	ashfaq	ashfaq	NOUN
iajs-2983	195	21	,	,	PUNCT
iajs-2983	195	22	m.	m.	NOUN
iajs-2983	195	23	;	;	PUNCT
iajs-2983	195	24	hassan	hassan	PROPN
iajs-2983	195	25	,	,	PUNCT
iajs-2983	195	26	a.u	a.u	PROPN
iajs-2983	195	27	.	.	PROPN
iajs-2983	195	28	;	;	PUNCT
iajs-2983	195	29	mughal	mughal	PROPN
iajs-2983	195	30	,	,	PUNCT
iajs-2983	195	31	e.u	e.u	PROPN
iajs-2983	195	32	.	.	PROPN
iajs-2983	195	33	;	;	PUNCT
iajs-2983	196	1	irfan	irfan	PROPN
iajs-2983	196	2	,	,	PUNCT
iajs-2983	196	3	a.	a.	NOUN
iajs-2983	196	4	;	;	PUNCT
iajs-2983	196	5	imran	imran	PROPN
iajs-2983	196	6	,	,	PUNCT
iajs-2983	196	7	m.	m.	NOUN
iajs-2983	196	8	metal	metal	NOUN
iajs-2983	196	9	incorporated	incorporate	VERB
iajs-2983	196	10	aminothiazole	aminothiazole	ADV
iajs-2983	196	11	-	-	PUNCT
iajs-2983	196	12	derived	derive	VERB
iajs-2983	196	13	compounds	compound	NOUN
iajs-2983	196	14	:	:	PUNCT
iajs-2983	196	15	synthesis	synthesis	NOUN
iajs-2983	196	16	,	,	PUNCT
iajs-2983	196	17	density	density	NOUN
iajs-2983	196	18	function	function	NOUN
iajs-2983	196	19	theory	theory	NOUN
iajs-2983	196	20	analysis	analysis	NOUN
iajs-2983	196	21	,	,	PUNCT
iajs-2983	196	22	in	in	ADP
iajs-2983	196	23	vitro	vitro	X
iajs-2983	196	24	antibacterial	antibacterial	ADJ
iajs-2983	196	25	and	and	CCONJ
iajs-2983	196	26	antioxidant	antioxidant	ADJ
iajs-2983	196	27	evaluation	evaluation	NOUN
iajs-2983	196	28	.	.	PUNCT
iajs-2983	197	1	royal	royal	ADJ
iajs-2983	197	2	society	society	PROPN
iajs-2983	197	3	open	open	VERB
iajs-2983	197	4	science	science	NOUN
iajs-2983	197	5	2021	2021	NUM
iajs-2983	197	6	,	,	PUNCT
iajs-2983	197	7	8	8	NUM
iajs-2983	197	8	,	,	PUNCT
iajs-2983	197	9	doi:10.1098	doi:10.1098	PROPN
iajs-2983	197	10	/	/	SYM
iajs-2983	197	11	rsos.210910	rsos.210910	NOUN
iajs-2983	197	12	.	.	NOUN
iajs-2983	197	13	11	11	NUM
iajs-2983	197	14	.	.	PUNCT
iajs-2983	198	1	rehman	rehman	NOUN
iajs-2983	198	2	,	,	PUNCT
iajs-2983	198	3	m.	m.	NOUN
iajs-2983	198	4	ur	ur	INTJ
iajs-2983	198	5	metal	metal	NOUN
iajs-2983	198	6	-	-	PUNCT
iajs-2983	198	7	based	base	VERB
iajs-2983	198	8	antimicrobial	antimicrobial	ADJ
iajs-2983	198	9	agents	agent	NOUN
iajs-2983	198	10	:	:	PUNCT
iajs-2983	198	11	synthesis	synthesis	NOUN
iajs-2983	198	12	,	,	PUNCT
iajs-2983	198	13	characterization	characterization	NOUN
iajs-2983	198	14	and	and	CCONJ
iajs-2983	198	15	biological	biological	ADJ
iajs-2983	198	16	studies	study	NOUN
iajs-2983	198	17	of	of	ADP
iajs-2983	198	18	mannich	mannich	DET
iajs-2983	198	19	base	base	NOUN
iajs-2983	198	20	derivatives	derivative	NOUN
iajs-2983	198	21	of	of	ADP
iajs-2983	198	22	benzimidazole	benzimidazole	NOUN
iajs-2983	198	23	and	and	CCONJ
iajs-2983	198	24	their	their	PRON
iajs-2983	198	25	metal	metal	NOUN
iajs-2983	198	26	complexes	complex	NOUN
iajs-2983	198	27	.	.	PUNCT
iajs-2983	199	1	science	science	NOUN
iajs-2983	199	2	journal	journal	PROPN
iajs-2983	199	3	of	of	ADP
iajs-2983	199	4	chemistry	chemistry	NOUN
iajs-2983	199	5	2013	2013	NUM
iajs-2983	199	6	,	,	PUNCT
iajs-2983	199	7	1	1	NUM
iajs-2983	199	8	,	,	PUNCT
iajs-2983	199	9	56	56	NUM
iajs-2983	199	10	,	,	PUNCT
iajs-2983	199	11	doi:10.11648	doi:10.11648	PROPN
iajs-2983	199	12	/	/	SYM
iajs-2983	199	13	j.sjc.20130105.12	j.sjc.20130105.12	PROPN
iajs-2983	199	14	.	.	PROPN
iajs-2983	199	15	12	12	NUM
iajs-2983	199	16	.	.	PUNCT
iajs-2983	200	1	pishawikar	pishawikar	PROPN
iajs-2983	200	2	,	,	PUNCT
iajs-2983	200	3	s.a	s.a	PROPN
iajs-2983	200	4	.	.	PROPN
iajs-2983	200	5	;	;	PUNCT
iajs-2983	200	6	more	more	ADJ
iajs-2983	200	7	,	,	PUNCT
iajs-2983	200	8	h.n	h.n	PROPN
iajs-2983	200	9	.	.	NOUN
iajs-2983	200	10	synthesis	synthesis	NOUN
iajs-2983	200	11	,	,	PUNCT
iajs-2983	200	12	docking	docking	NOUN
iajs-2983	200	13	and	and	CCONJ
iajs-2983	200	14	,	,	PUNCT
iajs-2983	200	15	in	in	ADP
iajs-2983	200	16	-	-	PUNCT
iajs-2983	200	17	vitro	vitro	X
iajs-2983	200	18	screening	screening	NOUN
iajs-2983	200	19	,	,	PUNCT
iajs-2983	200	20	of	of	ADP
iajs-2983	200	21	mannich	mannich	DET
iajs-2983	200	22	bases	basis	NOUN
iajs-2983	200	23	of	of	ADP
iajs-2983	200	24	thiosemicarbazide	thiosemicarbazide	NOUN
iajs-2983	200	25	,	,	PUNCT
iajs-2983	200	26	for	for	ADP
iajs-2983	200	27	anti	anti	ADJ
iajs-2983	200	28	-	-	ADJ
iajs-2983	200	29	fungal	fungal	ADJ
iajs-2983	200	30	activity	activity	NOUN
iajs-2983	200	31	.	.	PUNCT
iajs-2983	201	1	arabian	arabian	ADJ
iajs-2983	201	2	journal	journal	PROPN
iajs-2983	201	3	of	of	ADP
iajs-2983	201	4	chemistry	chemistry	PROPN
iajs-2983	201	5	2017	2017	NUM
iajs-2983	201	6	,	,	PUNCT
iajs-2983	201	7	10	10	NUM
iajs-2983	201	8	,	,	PUNCT
iajs-2983	201	9	s2714	s2714	NOUN
iajs-2983	201	10	–	–	PUNCT
iajs-2983	201	11	s2722	s2722	NOUN
iajs-2983	201	12	,	,	PUNCT
iajs-2983	201	13	doi:10.1016	doi:10.1016	PROPN
iajs-2983	201	14	/	/	SYM
iajs-2983	201	15	j.arabjc.2013.10.016	j.arabjc.2013.10.016	PROPN
iajs-2983	201	16	.	.	PROPN
iajs-2983	202	1	13	13	NUM
iajs-2983	202	2	.	.	PUNCT
iajs-2983	203	1	evans	evans	PROPN
iajs-2983	203	2	,	,	PUNCT
iajs-2983	203	3	a.	a.	PROPN
iajs-2983	203	4	;	;	PUNCT
iajs-2983	203	5	kavanagh	kavanagh	PROPN
iajs-2983	203	6	,	,	PUNCT
iajs-2983	203	7	k.a	k.a	PROPN
iajs-2983	203	8	.	.	PROPN
iajs-2983	203	9	evaluation	evaluation	NOUN
iajs-2983	203	10	of	of	ADP
iajs-2983	203	11	metal	metal	NOUN
iajs-2983	203	12	-	-	PUNCT
iajs-2983	203	13	based	base	VERB
iajs-2983	203	14	antimicrobial	antimicrobial	ADJ
iajs-2983	203	15	,	,	PUNCT
iajs-2983	203	16	compounds	compound	VERB
iajs-2983	203	17	for	for	ADP
iajs-2983	203	18	the	the	DET
iajs-2983	203	19	treatment	treatment	NOUN
iajs-2983	203	20	of	of	ADP
iajs-2983	203	21	bacterial	bacterial	ADJ
iajs-2983	203	22	,	,	PUNCT
iajs-2983	203	23	pathogens	pathogen	NOUN
iajs-2983	203	24	.	.	PUNCT
iajs-2983	204	1	journal	journal	PROPN
iajs-2983	204	2	of	of	ADP
iajs-2983	204	3	medical	medical	ADJ
iajs-2983	204	4	microbiology	microbiology	NOUN
iajs-2983	204	5	2021	2021	NUM
iajs-2983	204	6	,	,	PUNCT
iajs-2983	204	7	70	70	NUM
iajs-2983	204	8	,	,	PUNCT
iajs-2983	204	9	doi:10.1099	doi:10.1099	ADJ
iajs-2983	204	10	/	/	SYM
iajs-2983	204	11	jmm.0.001363	jmm.0.001363	NOUN
iajs-2983	204	12	.	.	PUNCT
iajs-2983	205	1	14	14	NUM
iajs-2983	205	2	.	.	PUNCT
iajs-2983	206	1	hadeel	hadeel	PROPN
iajs-2983	206	2	hamid	hamid	PROPN
iajs-2983	206	3	mahmood	mahmood	PROPN
iajs-2983	206	4	,	,	PUNCT
iajs-2983	206	5	s.r.b	s.r.b	NOUN
iajs-2983	206	6	.	.	PROPN
iajs-2983	206	7	preparation	preparation	NOUN
iajs-2983	206	8	,	,	PUNCT
iajs-2983	206	9	physicochemical	physicochemical	ADJ
iajs-2983	206	10	,	,	PUNCT
iajs-2983	206	11	and	and	CCONJ
iajs-2983	206	12	biological	biological	ADJ
iajs-2983	206	13	study	study	NOUN
iajs-2983	206	14	of	of	ADP
iajs-2983	206	15	schiff	schiff	NOUN
iajs-2983	206	16	base	base	NOUN
iajs-2983	206	17	derived	derive	VERB
iajs-2983	206	18	,	,	PUNCT
iajs-2983	206	19	from	from	ADP
iajs-2983	206	20	2amino-5	2amino-5	NUM
iajs-2983	206	21	-	-	PUNCT
iajs-2983	206	22	mercpto-1,3,4	mercpto-1,3,4	PROPN
iajs-2983	206	23	thiadiazole	thiadiazole	PROPN
iajs-2983	206	24	with	with	ADP
iajs-2983	206	25	,	,	PUNCT
iajs-2983	206	26	some	some	DET
iajs-2983	206	27	metal	metal	NOUN
iajs-2983	206	28	ions	ion	NOUN
iajs-2983	206	29	.	.	PUNCT
iajs-2983	207	1	biochem	biochem	PROPN
iajs-2983	207	2	.	.	PUNCT
iajs-2983	208	1	cell	cell	NOUN
iajs-2983	208	2	.	.	PUNCT
iajs-2983	209	1	arch	arch	ADJ
iajs-2983	209	2	2021	2021	NUM
iajs-2983	209	3	.	.	PUNCT
iajs-2983	210	1	15	15	NUM
iajs-2983	210	2	.	.	PUNCT
iajs-2983	211	1	karcz	karcz	PROPN
iajs-2983	211	2	,	,	PUNCT
iajs-2983	211	3	d.	d.	PROPN
iajs-2983	211	4	;	;	PUNCT
iajs-2983	211	5	matwijczuk	matwijczuk	PROPN
iajs-2983	211	6	,	,	PUNCT
iajs-2983	211	7	a.	a.	NOUN
iajs-2983	211	8	;	;	PUNCT
iajs-2983	211	9	kamiński	kamiński	PROPN
iajs-2983	211	10	,	,	PUNCT
iajs-2983	211	11	d.	d.	PROPN
iajs-2983	211	12	;	;	PUNCT
iajs-2983	211	13	creaven	creaven	ADJ
iajs-2983	211	14	,	,	PUNCT
iajs-2983	211	15	b.	b.	PROPN
iajs-2983	211	16	;	;	PUNCT
iajs-2983	211	17	ciszkowicz	ciszkowicz	PROPN
iajs-2983	211	18	,	,	PUNCT
iajs-2983	211	19	e.	e.	PROPN
iajs-2983	211	20	;	;	PUNCT
iajs-2983	211	21	lecka	lecka	PROPN
iajs-2983	211	22	-	-	PUNCT
iajs-2983	211	23	szlachta	szlachta	PROPN
iajs-2983	211	24	,	,	PUNCT
iajs-2983	211	25	k.	k.	PROPN
iajs-2983	211	26	starzak	starzak	PROPN
iajs-2983	211	27	,	,	PUNCT
iajs-2983	211	28	k.	k.	PROPN
iajs-2983	211	29	structural	structural	PROPN
iajs-2983	211	30	features	feature	NOUN
iajs-2983	211	31	of	of	ADP
iajs-2983	211	32	1,3,4	1,3,4	NUM
iajs-2983	211	33	-	-	PUNCT
iajs-2983	211	34	thiadiazole	thiadiazole	NOUN
iajs-2983	211	35	-	-	PUNCT
iajs-2983	211	36	derived	derive	VERB
iajs-2983	211	37	,	,	PUNCT
iajs-2983	211	38	ligands	ligand	NOUN
iajs-2983	211	39	and	and	CCONJ
iajs-2983	211	40	their	their	PRON
iajs-2983	211	41	zn(ii	zn(ii	NOUN
iajs-2983	211	42	)	)	PUNCT
iajs-2983	211	43	and	and	CCONJ
iajs-2983	211	44	cu(ii	cu(ii	PROPN
iajs-2983	211	45	)	)	PUNCT
iajs-2983	211	46	,	,	PUNCT
iajs-2983	211	47	complexes	complex	NOUN
iajs-2983	211	48	which	which	PRON
iajs-2983	211	49	demonstrate	demonstrate	VERB
iajs-2983	211	50	synergistic	synergistic	ADJ
iajs-2983	211	51	antibacterial	antibacterial	ADJ
iajs-2983	211	52	effects	effect	NOUN
iajs-2983	211	53	with	with	ADP
iajs-2983	211	54	kanamycin	kanamycin	PROPN
iajs-2983	211	55	,	,	PUNCT
iajs-2983	211	56	.	.	PUNCT
iajs-2983	212	1	international	international	ADJ
iajs-2983	212	2	journal	journal	NOUN
iajs-2983	212	3	of	of	ADP
iajs-2983	212	4	molecular	molecular	ADJ
iajs-2983	212	5	sciences	science	NOUN
iajs-2983	212	6	2020	2020	NUM
iajs-2983	212	7	,	,	PUNCT
iajs-2983	212	8	21	21	NUM
iajs-2983	212	9	,	,	PUNCT
iajs-2983	212	10	5735	5735	NUM
iajs-2983	212	11	,	,	PUNCT
iajs-2983	212	12	doi:10.3390	doi:10.3390	NOUN
iajs-2983	212	13	/	/	SYM
iajs-2983	212	14	ijms21165735	ijms21165735	NOUN
iajs-2983	212	15	.	.	PUNCT
iajs-2983	213	1	16	16	NUM
iajs-2983	213	2	.	.	PUNCT
iajs-2983	214	1	guo	guo	PROPN
iajs-2983	214	2	,	,	PUNCT
iajs-2983	214	3	j.	j.	PROPN
iajs-2983	214	4	;	;	PUNCT
iajs-2983	214	5	zhou	zhou	PROPN
iajs-2983	214	6	,	,	PUNCT
iajs-2983	214	7	j.	j.	PROPN
iajs-2983	214	8	;	;	PUNCT
iajs-2983	214	9	guorui	guorui	PROPN
iajs-2983	214	10	,	,	PUNCT
iajs-2983	214	11	fu	fu	NOUN
iajs-2983	214	12	;	;	PUNCT
iajs-2983	214	13	he	he	PRON
iajs-2983	214	14	,	,	PUNCT
iajs-2983	214	15	y.	y.	PROPN
iajs-2983	214	16	;	;	PUNCT
iajs-2983	214	17	li	li	PROPN
iajs-2983	214	18	,	,	PUNCT
iajs-2983	214	19	w.	w.	PROPN
iajs-2983	214	20	;	;	PUNCT
iajs-2983	214	21	lü	lü	PROPN
iajs-2983	214	22	,	,	PUNCT
iajs-2983	214	23	x.	x.	NOUN
iajs-2983	214	24	two	two	NUM
iajs-2983	214	25	efficient	efficient	ADJ
iajs-2983	214	26	near	near	ADV
iajs-2983	214	27	-	-	PUNCT
iajs-2983	214	28	infrared	infrared	ADJ
iajs-2983	214	29	(	(	PUNCT
iajs-2983	214	30	nir	nir	NOUN
iajs-2983	214	31	)	)	PUNCT
iajs-2983	214	32	luminescent	luminescent	NOUN
iajs-2983	215	1	[	[	X
iajs-2983	215	2	ir(c^n)2(n^o)]-characteristic	ir(c^n)2(n^o)]-characteristic	ADJ
iajs-2983	215	3	,	,	PUNCT
iajs-2983	215	4	complexes	complex	NOUN
iajs-2983	215	5	with	with	ADP
iajs-2983	215	6	8	8	NUM
iajs-2983	215	7	-	-	PUNCT
iajs-2983	215	8	hydroxyquinoline	hydroxyquinoline	NOUN
iajs-2983	215	9	(	(	PUNCT
iajs-2983	215	10	8	8	NUM
iajs-2983	215	11	-	-	NUM
iajs-2983	215	12	hq	hq	NOUN
iajs-2983	215	13	)	)	PUNCT
iajs-2983	215	14	as	as	ADP
iajs-2983	215	15	,	,	PUNCT
iajs-2983	215	16	the	the	DET
iajs-2983	215	17	ancillary	ancillary	ADJ
iajs-2983	215	18	ligand	ligand	NOUN
iajs-2983	215	19	.	.	PUNCT
iajs-2983	216	1	inorganic	inorganic	ADJ
iajs-2983	216	2	chemistry	chemistry	NOUN
iajs-2983	216	3	communications	communication	NOUN
iajs-2983	216	4	2019	2019	NUM
iajs-2983	216	5	,	,	PUNCT
iajs-2983	216	6	101	101	NUM
iajs-2983	216	7	,	,	PUNCT
iajs-2983	216	8	69–73	69–73	NUM
iajs-2983	216	9	,	,	PUNCT
iajs-2983	216	10	doi:10.1016	doi:10.1016	PROPN
iajs-2983	216	11	/	/	SYM
iajs-2983	216	12	j.inoche.2019.01.019	j.inoche.2019.01.019	PROPN
iajs-2983	216	13	.	.	PUNCT
iajs-2983	217	1	17	17	NUM
iajs-2983	217	2	.	.	PUNCT
iajs-2983	217	3	lotfi	lotfi	PROPN
iajs-2983	217	4	,	,	PUNCT
iajs-2983	217	5	s.	s.	PROPN
iajs-2983	217	6	;	;	PUNCT
iajs-2983	217	7	brgoch	brgoch	PROPN
iajs-2983	217	8	,	,	PUNCT
iajs-2983	218	1	j.	j.	PROPN
iajs-2983	218	2	predicting	predict	VERB
iajs-2983	218	3	pressure	pressure	NOUN
iajs-2983	218	4	-	-	PUNCT
iajs-2983	218	5	stabilized	stabilize	VERB
iajs-2983	218	6	alkali	alkali	ADJ
iajs-2983	218	7	,	,	PUNCT
iajs-2983	218	8	metal	metal	NOUN
iajs-2983	218	9	iridides	iridide	NOUN
iajs-2983	218	10	:	:	PUNCT
iajs-2983	218	11	a−ir	a−ir	ADJ
iajs-2983	218	12	(	(	PUNCT
iajs-2983	218	13	a	a	DET
iajs-2983	218	14	 	 	SPACE
iajs-2983	218	15	=	=	NOUN
iajs-2983	218	16	 	 	SPACE
iajs-2983	218	17	rb	rb	PROPN
iajs-2983	218	18	,	,	PUNCT
iajs-2983	218	19	cs	cs	NOUN
iajs-2983	218	20	)	)	PUNCT
iajs-2983	218	21	.	.	PUNCT
iajs-2983	219	1	computational	computational	ADJ
iajs-2983	219	2	materials	material	NOUN
iajs-2983	219	3	,	,	PUNCT
iajs-2983	219	4	science	science	NOUN
iajs-2983	219	5	2019	2019	NUM
iajs-2983	219	6	,	,	PUNCT
iajs-2983	219	7	158	158	NUM
iajs-2983	219	8	,	,	PUNCT
iajs-2983	219	9	124–129	124–129	NUM
iajs-2983	219	10	,	,	PUNCT
iajs-2983	219	11	doi	doi	NOUN
iajs-2983	219	12	:	:	PUNCT
iajs-2983	219	13	,	,	PUNCT
iajs-2983	219	14	10.1016	10.1016	NUM
iajs-2983	219	15	/	/	SYM
iajs-2983	219	16	j.commatsci.2018.11.018	j.commatsci.2018.11.018	PROPN
iajs-2983	219	17	.	.	PUNCT
iajs-2983	219	18	ihjpas	ihjpas	PROPN
iajs-2983	219	19	.	.	PUNCT
iajs-2983	220	1	36(1)2023	36(1)2023	NUM
iajs-2983	220	2	271	271	NUM
iajs-2983	220	3	18	18	NUM
iajs-2983	220	4	.	.	PUNCT
iajs-2983	221	1	guo	guo	PROPN
iajs-2983	221	2	,	,	PUNCT
iajs-2983	221	3	j.	j.	PROPN
iajs-2983	221	4	;	;	PUNCT
iajs-2983	221	5	zhou	zhou	PROPN
iajs-2983	221	6	,	,	PUNCT
iajs-2983	221	7	j.	j.	PROPN
iajs-2983	221	8	;	;	PUNCT
iajs-2983	221	9	guorui	guorui	PROPN
iajs-2983	221	10	fu	fu	PROPN
iajs-2983	221	11	;	;	PUNCT
iajs-2983	221	12	he	he	PRON
iajs-2983	221	13	,	,	PUNCT
iajs-2983	221	14	y.	y.	PROPN
iajs-2983	221	15	;	;	PUNCT
iajs-2983	221	16	li	li	PROPN
iajs-2983	221	17	,	,	PUNCT
iajs-2983	221	18	w.	w.	PROPN
iajs-2983	221	19	;	;	PUNCT
iajs-2983	221	20	lü	lü	PROPN
iajs-2983	221	21	,	,	PUNCT
iajs-2983	221	22	x.	x.	NOUN
iajs-2983	221	23	two	two	NUM
iajs-2983	221	24	efficient	efficient	ADJ
iajs-2983	221	25	,	,	PUNCT
iajs-2983	221	26	near	near	ADV
iajs-2983	221	27	-	-	PUNCT
iajs-2983	221	28	infrared	infrared	ADJ
iajs-2983	221	29	(	(	PUNCT
iajs-2983	221	30	nir	nir	NOUN
iajs-2983	221	31	)	)	PUNCT
iajs-2983	221	32	luminescent	luminescent	NOUN
iajs-2983	222	1	[	[	X
iajs-2983	222	2	ir(c^n)2(n^o)]-characteristic	ir(c^n)2(n^o)]-characteristic	ADJ
iajs-2983	222	3	complexes	complex	NOUN
iajs-2983	222	4	,	,	PUNCT
iajs-2983	222	5	with	with	ADP
iajs-2983	222	6	8	8	NUM
iajs-2983	222	7	-	-	PUNCT
iajs-2983	222	8	hydroxyquinoline	hydroxyquinoline	NOUN
iajs-2983	222	9	(	(	PUNCT
iajs-2983	222	10	8	8	NUM
iajs-2983	222	11	-	-	NUM
iajs-2983	222	12	hq	hq	NOUN
iajs-2983	222	13	)	)	PUNCT
iajs-2983	222	14	as	as	ADP
iajs-2983	222	15	the	the	DET
iajs-2983	222	16	ancillary	ancillary	ADJ
iajs-2983	222	17	,	,	PUNCT
iajs-2983	222	18	ligand	ligand	NOUN
iajs-2983	222	19	.	.	PUNCT
iajs-2983	223	1	inorganic	inorganic	ADJ
iajs-2983	223	2	chemistry	chemistry	NOUN
iajs-2983	223	3	,	,	PUNCT
iajs-2983	223	4	communications	communication	NOUN
iajs-2983	223	5	2019	2019	NUM
iajs-2983	223	6	,	,	PUNCT
iajs-2983	223	7	101	101	NUM
iajs-2983	223	8	,	,	PUNCT
iajs-2983	223	9	69–73	69–73	NUM
iajs-2983	223	10	,	,	PUNCT
iajs-2983	223	11	doi:10.1016	doi:10.1016	PROPN
iajs-2983	223	12	/	/	SYM
iajs-2983	223	13	j.inoche.2019.01.019	j.inoche.2019.01.019	PROPN
iajs-2983	223	14	.	.	PROPN
iajs-2983	224	1	19	19	NUM
iajs-2983	224	2	.	.	X
iajs-2983	224	3	ibraheem	ibraheem	PROPN
iajs-2983	224	4	,	,	PUNCT
iajs-2983	224	5	i.h	i.h	PROPN
iajs-2983	224	6	.	.	PROPN
iajs-2983	224	7	;	;	PUNCT
iajs-2983	225	1	sadiq	sadiq	PROPN
iajs-2983	225	2	,	,	PUNCT
iajs-2983	225	3	a.s	a.s	PROPN
iajs-2983	225	4	.	.	PROPN
iajs-2983	225	5	;	;	PUNCT
iajs-2983	225	6	al	al	PROPN
iajs-2983	225	7	-	-	PUNCT
iajs-2983	225	8	tameemi	tameemi	PROPN
iajs-2983	225	9	,	,	PUNCT
iajs-2983	225	10	m.	m.	NOUN
iajs-2983	225	11	;	;	PUNCT
iajs-2983	225	12	alias	alia	NOUN
iajs-2983	225	13	,	,	PUNCT
iajs-2983	225	14	m.f	m.f	PROPN
iajs-2983	225	15	.	.	PUNCT
iajs-2983	225	16	synthesis	synthesis	NOUN
iajs-2983	225	17	,	,	PUNCT
iajs-2983	225	18	spectral	spectral	ADJ
iajs-2983	225	19	,	,	PUNCT
iajs-2983	225	20	identification	identification	NOUN
iajs-2983	225	21	,	,	PUNCT
iajs-2983	225	22	antibacterial	antibacterial	ADJ
iajs-2983	225	23	evaluationand	evaluationand	NOUN
iajs-2983	225	24	theoretical	theoretical	ADJ
iajs-2983	225	25	,	,	PUNCT
iajs-2983	225	26	study	study	NOUN
iajs-2983	225	27	of	of	ADP
iajs-2983	225	28	co	co	PROPN
iajs-2983	225	29	,	,	PUNCT
iajs-2983	225	30	fe	fe	X
iajs-2983	225	31	,	,	PUNCT
iajs-2983	225	32	rh	rh	PROPN
iajs-2983	225	33	and	and	CCONJ
iajs-2983	225	34	pd	pd	PROPN
iajs-2983	225	35	complexes	complex	NOUN
iajs-2983	225	36	for	for	ADP
iajs-2983	225	37	2benzoylthiobenzimidazol	2benzoylthiobenzimidazol	NUM
iajs-2983	225	38	.	.	PUNCT
iajs-2983	225	39	baghdad	baghdad	PROPN
iajs-2983	225	40	science	science	PROPN
iajs-2983	225	41	journal	journal	PROPN
iajs-2983	225	42	2022	2022	NUM
iajs-2983	225	43	,	,	PUNCT
iajs-2983	225	44	1326–1334	1326–1334	NUM
iajs-2983	225	45	,	,	PUNCT
iajs-2983	225	46	doi:10.21123	doi:10.21123	NOUN
iajs-2983	225	47	/	/	SYM
iajs-2983	225	48	bsj.2022.6704	bsj.2022.6704	PROPN
iajs-2983	225	49	.	.	PUNCT
iajs-2983	226	1	20	20	NUM
iajs-2983	226	2	.	.	PUNCT
iajs-2983	227	1	baqer	baqer	PROPN
iajs-2983	227	2	,	,	PUNCT
iajs-2983	227	3	s.r	s.r	PROPN
iajs-2983	227	4	.	.	PROPN
iajs-2983	227	5	;	;	PUNCT
iajs-2983	228	1	hassan	hassan	PROPN
iajs-2983	228	2	,	,	PUNCT
iajs-2983	228	3	s.s	s.s	PROPN
iajs-2983	228	4	.	.	PROPN
iajs-2983	228	5	;	;	PUNCT
iajs-2983	228	6	hassan	hassan	PROPN
iajs-2983	228	7	,	,	PUNCT
iajs-2983	228	8	n.m	n.m	PROPN
iajs-2983	228	9	.	.	PROPN
iajs-2983	228	10	;	;	PUNCT
iajs-2983	228	11	saleh	saleh	PROPN
iajs-2983	228	12	,	,	PUNCT
iajs-2983	228	13	a.m.	a.m.	PROPN
iajs-2983	228	14	biological	biological	NOUN
iajs-2983	228	15	,	,	PUNCT
iajs-2983	228	16	evaluation	evaluation	NOUN
iajs-2983	228	17	,	,	PUNCT
iajs-2983	228	18	and	and	CCONJ
iajs-2983	228	19	theoretical	theoretical	ADJ
iajs-2983	228	20	study	study	NOUN
iajs-2983	228	21	of	of	ADP
iajs-2983	228	22	bi	bi	ADJ
iajs-2983	228	23	-	-	ADJ
iajs-2983	228	24	dentate	dentate	ADJ
iajs-2983	228	25	ligand	ligand	NOUN
iajs-2983	228	26	,	,	PUNCT
iajs-2983	228	27	for	for	ADP
iajs-2983	228	28	amoxicillin	amoxicillin	NOUN
iajs-2983	228	29	,	,	PUNCT
iajs-2983	228	30	derivative	derivative	NOUN
iajs-2983	228	31	with	with	ADP
iajs-2983	228	32	some	some	DET
iajs-2983	228	33	,	,	PUNCT
iajs-2983	228	34	metal	metal	NOUN
iajs-2983	228	35	ions	ion	NOUN
iajs-2983	228	36	.	.	PUNCT
iajs-2983	229	1	baghdad	baghdad	PROPN
iajs-2983	229	2	science	science	PROPN
iajs-2983	229	3	journal	journal	PROPN
iajs-2983	229	4	2021	2021	NUM
iajs-2983	229	5	,	,	PUNCT
iajs-2983	229	6	18	18	NUM
iajs-2983	229	7	,	,	PUNCT
iajs-2983	229	8	doi:10.21123	doi:10.21123	PROPN
iajs-2983	229	9	/	/	SYM
iajs-2983	229	10	bsj.2021.18.4.1269	bsj.2021.18.4.1269	PROPN
iajs-2983	229	11	.	.	PROPN
iajs-2983	229	12	21	21	NUM
iajs-2983	229	13	.	.	PUNCT
iajs-2983	230	1	gülfen	gülfen	NOUN
iajs-2983	230	2	,	,	PUNCT
iajs-2983	230	3	m.	m.	NOUN
iajs-2983	230	4	;	;	PUNCT
iajs-2983	230	5	özdemir	özdemir	NOUN
iajs-2983	230	6	,	,	PUNCT
iajs-2983	230	7	a.	a.	NOUN
iajs-2983	230	8	monitoring	monitoring	NOUN
iajs-2983	230	9	cu(ii)-insulin	cu(ii)-insulin	PROPN
iajs-2983	230	10	,	,	PUNCT
iajs-2983	230	11	and	and	CCONJ
iajs-2983	230	12	mn(ii)-insulin	mn(ii)-insulin	PROPN
iajs-2983	230	13	complexes	complex	NOUN
iajs-2983	230	14	using	use	VERB
iajs-2983	230	15	potentiometric	potentiometric	ADJ
iajs-2983	230	16	,	,	PUNCT
iajs-2983	230	17	chromatographic	chromatographic	ADJ
iajs-2983	230	18	,	,	PUNCT
iajs-2983	230	19	uv	uv	INTJ
iajs-2983	230	20	–	–	PUNCT
iajs-2983	230	21	vis	vis	X
iajs-2983	230	22	absorption	absorption	NOUN
iajs-2983	230	23	and	and	CCONJ
iajs-2983	230	24	fluorescence	fluorescence	NOUN
iajs-2983	230	25	,	,	PUNCT
iajs-2983	230	26	emission	emission	NOUN
iajs-2983	230	27	spectroscopic	spectroscopic	NOUN
iajs-2983	230	28	techniques	technique	NOUN
iajs-2983	230	29	.	.	PUNCT
iajs-2983	231	1	journal	journal	NOUN
iajs-2983	231	2	of	of	ADP
iajs-2983	231	3	molecular	molecular	ADJ
iajs-2983	231	4	structure	structure	NOUN
iajs-2983	231	5	2022	2022	NUM
iajs-2983	231	6	,	,	PUNCT
iajs-2983	231	7	1259	1259	NUM
iajs-2983	231	8	,	,	PUNCT
iajs-2983	231	9	132763	132763	NUM
iajs-2983	231	10	,	,	PUNCT
iajs-2983	231	11	doi:10.1016	doi:10.1016	PROPN
iajs-2983	231	12	/	/	SYM
iajs-2983	231	13	j.molstruc.2022.132763	j.molstruc.2022.132763	PROPN
iajs-2983	231	14	.	.	PUNCT
iajs-2983	232	1	22	22	NUM
iajs-2983	232	2	.	.	PUNCT
iajs-2983	233	1	alias	alias	PROPN
iajs-2983	233	2	,	,	PUNCT
iajs-2983	233	3	m.f	m.f	PROPN
iajs-2983	233	4	.	.	PROPN
iajs-2983	233	5	;	;	PUNCT
iajs-2983	233	6	murtadha	murtadha	PROPN
iajs-2983	233	7	,	,	PUNCT
iajs-2983	233	8	j.h	j.h	PROPN
iajs-2983	233	9	.	.	PROPN
iajs-2983	233	10	;	;	PUNCT
iajs-2983	233	11	abdul	abdul	PROPN
iajs-2983	233	12	alrazzaq	alrazzaq	PROPN
iajs-2983	233	13	,	,	PUNCT
iajs-2983	233	14	i.h	i.h	PROPN
iajs-2983	233	15	.	.	PROPN
iajs-2983	233	16	study	study	NOUN
iajs-2983	233	17	of	of	ADP
iajs-2983	233	18	cytotoxic	cytotoxic	ADJ
iajs-2983	233	19	,	,	PUNCT
iajs-2983	233	20	effect	effect	NOUN
iajs-2983	233	21	of	of	ADP
iajs-2983	233	22	aqueous	aqueous	ADJ
iajs-2983	233	23	extract	extract	NOUN
iajs-2983	233	24	fenugreek	fenugreek	NOUN
iajs-2983	233	25	,	,	PUNCT
iajs-2983	233	26	(	(	PUNCT
iajs-2983	233	27	trigonella	trigonella	NOUN
iajs-2983	233	28	foenum	foenum	ADJ
iajs-2983	233	29	graecum	graecum	NOUN
iajs-2983	233	30	l.s	l.s	NOUN
iajs-2983	233	31	)	)	PUNCT
iajs-2983	233	32	seeds	seed	NOUN
iajs-2983	233	33	and	and	CCONJ
iajs-2983	233	34	the	the	DET
iajs-2983	233	35	new	new	ADJ
iajs-2983	233	36	,	,	PUNCT
iajs-2983	233	37	complexes	complex	NOUN
iajs-2983	233	38	of	of	ADP
iajs-2983	233	39	rh	rh	PROPN
iajs-2983	233	40	(	(	PUNCT
iajs-2983	233	41	ii	ii	PROPN
iajs-2983	233	42	)	)	PUNCT
iajs-2983	233	43	and	and	CCONJ
iajs-2983	233	44	pd	pd	PROPN
iajs-2983	233	45	(	(	PUNCT
iajs-2983	233	46	ii	ii	PROPN
iajs-2983	233	47	)	)	PUNCT
iajs-2983	233	48	on	on	ADP
iajs-2983	233	49	cancer	cancer	NOUN
iajs-2983	233	50	cell	cell	NOUN
iajs-2983	233	51	lines	line	NOUN
iajs-2983	233	52	,	,	PUNCT
iajs-2983	233	53	.	.	PUNCT
iajs-2983	234	1	baghdad	baghdad	PROPN
iajs-2983	234	2	science	science	PROPN
iajs-2983	234	3	journal	journal	PROPN
iajs-2983	234	4	2018	2018	NUM
iajs-2983	234	5	,	,	PUNCT
iajs-2983	234	6	9	9	NUM
iajs-2983	234	7	,	,	PUNCT
iajs-2983	234	8	289–295	289–295	NUM
iajs-2983	234	9	.	.	NOUN
iajs-2983	234	10	23	23	NUM
iajs-2983	234	11	.	.	PUNCT
iajs-2983	235	1	mortazavi	mortazavi	PROPN
iajs-2983	235	2	,	,	PUNCT
iajs-2983	235	3	s.z	s.z	PROPN
iajs-2983	235	4	.	.	PROPN
iajs-2983	235	5	;	;	PUNCT
iajs-2983	235	6	parvin	parvin	PROPN
iajs-2983	235	7	,	,	PUNCT
iajs-2983	235	8	p.	p.	NOUN
iajs-2983	235	9	;	;	PUNCT
iajs-2983	235	10	reyhani	reyhani	PROPN
iajs-2983	235	11	,	,	PUNCT
iajs-2983	235	12	a.	a.	NOUN
iajs-2983	235	13	;	;	PUNCT
iajs-2983	235	14	golikand	golikand	PROPN
iajs-2983	235	15	,	,	PUNCT
iajs-2983	235	16	a.n	a.n	PROPN
iajs-2983	235	17	.	.	PROPN
iajs-2983	235	18	;	;	PUNCT
iajs-2983	235	19	mirershadi	mirershadi	PROPN
iajs-2983	235	20	,	,	PUNCT
iajs-2983	235	21	s.	s.	PROPN
iajs-2983	235	22	effect	effect	NOUN
iajs-2983	235	23	of	of	ADP
iajs-2983	235	24	laser	laser	NOUN
iajs-2983	235	25	,	,	PUNCT
iajs-2983	235	26	wavelength	wavelength	NOUN
iajs-2983	235	27	at	at	ADP
iajs-2983	235	28	ir	ir	PROPN
iajs-2983	235	29	(	(	PUNCT
iajs-2983	235	30	1064	1064	NUM
iajs-2983	235	31	nm	nm	NOUN
iajs-2983	235	32	)	)	PUNCT
iajs-2983	235	33	and	and	CCONJ
iajs-2983	235	34	uv	uv	INTJ
iajs-2983	235	35	(	(	PUNCT
iajs-2983	235	36	193	193	NUM
iajs-2983	235	37	nm	nm	NOUN
iajs-2983	235	38	)	)	PUNCT
iajs-2983	235	39	on	on	ADP
iajs-2983	235	40	the	the	DET
iajs-2983	235	41	structural	structural	ADJ
iajs-2983	235	42	formation	formation	NOUN
iajs-2983	235	43	,	,	PUNCT
iajs-2983	235	44	of	of	ADP
iajs-2983	235	45	palladium	palladium	NOUN
iajs-2983	235	46	nanoparticles	nanoparticle	NOUN
iajs-2983	235	47	in	in	ADP
iajs-2983	235	48	deionized	deionize	VERB
iajs-2983	235	49	water	water	NOUN
iajs-2983	235	50	.	.	PUNCT
iajs-2983	236	1	the	the	DET
iajs-2983	236	2	journal	journal	NOUN
iajs-2983	236	3	of	of	ADP
iajs-2983	236	4	physical	physical	ADJ
iajs-2983	236	5	chemistry	chemistry	NOUN
iajs-2983	236	6	c	c	PROPN
iajs-2983	236	7	2011	2011	NUM
iajs-2983	236	8	,	,	PUNCT
iajs-2983	236	9	115	115	NUM
iajs-2983	236	10	,	,	PUNCT
iajs-2983	236	11	5049–5057	5049–5057	NUM
iajs-2983	236	12	,	,	PUNCT
iajs-2983	236	13	doi:10.1021	doi:10.1021	ADJ
iajs-2983	236	14	/	/	SYM
iajs-2983	236	15	jp1091224	jp1091224	PROPN
iajs-2983	236	16	.	.	PUNCT
iajs-2983	237	1	24	24	NUM
iajs-2983	237	2	.	.	PUNCT
iajs-2983	237	3	lopez	lopez	NOUN
iajs-2983	237	4	,	,	PUNCT
iajs-2983	237	5	t.	t.	PROPN
iajs-2983	237	6	;	;	PUNCT
iajs-2983	237	7	villa	villa	PROPN
iajs-2983	237	8	,	,	PUNCT
iajs-2983	237	9	m.	m.	NOUN
iajs-2983	237	10	;	;	PUNCT
iajs-2983	237	11	gomez	gomez	PROPN
iajs-2983	237	12	,	,	PUNCT
iajs-2983	237	13	r.	r.	PROPN
iajs-2983	237	14	uv	uv	PROPN
iajs-2983	237	15	-	-	PUNCT
iajs-2983	237	16	visible	visible	ADJ
iajs-2983	237	17	diffuse	diffuse	NOUN
iajs-2983	237	18	reflectance	reflectance	NOUN
iajs-2983	237	19	,	,	PUNCT
iajs-2983	237	20	spectroscopic	spectroscopic	ADJ
iajs-2983	237	21	study	study	NOUN
iajs-2983	237	22	of	of	ADP
iajs-2983	237	23	platinum	platinum	NOUN
iajs-2983	237	24	,	,	PUNCT
iajs-2983	237	25	palladium	palladium	NOUN
iajs-2983	237	26	,	,	PUNCT
iajs-2983	237	27	and	and	CCONJ
iajs-2983	237	28	ruthenium	ruthenium	NOUN
iajs-2983	237	29	,	,	PUNCT
iajs-2983	237	30	catalysts	catalyst	NOUN
iajs-2983	237	31	supported	support	VERB
iajs-2983	237	32	on	on	ADP
iajs-2983	237	33	silica	silica	NOUN
iajs-2983	237	34	.	.	PUNCT
iajs-2983	238	1	the	the	DET
iajs-2983	238	2	journal	journal	PROPN
iajs-2983	238	3	of	of	ADP
iajs-2983	238	4	,	,	PUNCT
iajs-2983	238	5	physical	physical	ADJ
iajs-2983	238	6	chemistry	chemistry	NOUN
iajs-2983	238	7	1991	1991	NUM
iajs-2983	238	8	,	,	PUNCT
iajs-2983	238	9	95	95	NUM
iajs-2983	238	10	,	,	PUNCT
iajs-2983	238	11	1690–1693	1690–1693	NUM
iajs-2983	238	12	,	,	PUNCT
iajs-2983	238	13	doi:10.1021	doi:10.1021	ADJ
iajs-2983	238	14	/	/	SYM
iajs-2983	238	15	j100157a038	j100157a038	PROPN
iajs-2983	238	16	.	.	PUNCT
iajs-2983	239	1	25	25	NUM
iajs-2983	239	2	.	.	PUNCT
iajs-2983	239	3	phillips	phillips	PROPN
iajs-2983	239	4	,	,	PUNCT
iajs-2983	239	5	j.p	j.p	PROPN
iajs-2983	239	6	.	.	PROPN
iajs-2983	239	7	;	;	PUNCT
iajs-2983	239	8	mackey	mackey	PROPN
iajs-2983	239	9	,	,	PUNCT
iajs-2983	239	10	n.m	n.m	PROPN
iajs-2983	239	11	.	.	PROPN
iajs-2983	239	12	;	;	PUNCT
iajs-2983	239	13	confait	confait	PROPN
iajs-2983	239	14	,	,	PUNCT
iajs-2983	239	15	b.s	b.s	PROPN
iajs-2983	239	16	.	.	PROPN
iajs-2983	239	17	;	;	PUNCT
iajs-2983	239	18	heaps	heap	NOUN
iajs-2983	239	19	,	,	PUNCT
iajs-2983	239	20	,	,	PUNCT
iajs-2983	239	21	d.t	d.t	PROPN
iajs-2983	239	22	.	.	PROPN
iajs-2983	239	23	;	;	PUNCT
iajs-2983	239	24	deng	deng	PROPN
iajs-2983	239	25	,	,	PUNCT
iajs-2983	239	26	x.	x.	PROPN
iajs-2983	239	27	;	;	PUNCT
iajs-2983	239	28	todd	todd	PROPN
iajs-2983	239	29	,	,	PUNCT
iajs-2983	239	30	m.l	m.l	PROPN
iajs-2983	239	31	.	.	PROPN
iajs-2983	239	32	;	;	PUNCT
iajs-2983	239	33	stevenson	stevenson	PROPN
iajs-2983	239	34	,	,	PUNCT
iajs-2983	239	35	s.	s.	PROPN
iajs-2983	239	36	;	;	PUNCT
iajs-2983	239	37	zhou	zhou	PROPN
iajs-2983	239	38	,	,	PUNCT
iajs-2983	239	39	h.	h.	PROPN
iajs-2983	239	40	;	;	PUNCT
iajs-2983	239	41	hoyle	hoyle	PROPN
iajs-2983	239	42	,	,	PUNCT
iajs-2983	239	43	c.e	c.e	PROPN
iajs-2983	239	44	.	.	PROPN
iajs-2983	239	45	dispersion	dispersion	NOUN
iajs-2983	239	46	of	of	ADP
iajs-2983	239	47	gold	gold	NOUN
iajs-2983	239	48	,	,	PUNCT
iajs-2983	239	49	nanoparticles	nanoparticle	NOUN
iajs-2983	239	50	in	in	ADP
iajs-2983	239	51	uv	uv	NOUN
iajs-2983	239	52	-	-	PUNCT
iajs-2983	239	53	cured	cure	VERB
iajs-2983	239	54	,	,	PUNCT
iajs-2983	239	55	thiol−ene	thiol−ene	PROPN
iajs-2983	239	56	films	film	NOUN
iajs-2983	239	57	by	by	ADP
iajs-2983	239	58	,	,	PUNCT
iajs-2983	239	59	precomplexation	precomplexation	NOUN
iajs-2983	239	60	of	of	ADP
iajs-2983	239	61	gold−thiol	gold−thiol	PROPN
iajs-2983	239	62	.	.	PUNCT
iajs-2983	240	1	chemistry	chemistry	NOUN
iajs-2983	240	2	,	,	PUNCT
iajs-2983	240	3	of	of	ADP
iajs-2983	240	4	materials	material	NOUN
iajs-2983	240	5	2008	2008	NUM
iajs-2983	240	6	,	,	PUNCT
iajs-2983	240	7	20	20	NUM
iajs-2983	240	8	,	,	PUNCT
iajs-2983	240	9	5240–5245	5240–5245	NUM
iajs-2983	240	10	,	,	PUNCT
iajs-2983	240	11	doi:10.1021	doi:10.1021	ADJ
iajs-2983	240	12	/	/	SYM
iajs-2983	240	13	cm8007842	cm8007842	NOUN
iajs-2983	240	14	.	.	PUNCT
iajs-2983	241	1	26	26	NUM
iajs-2983	241	2	.	.	X
iajs-2983	242	1	zhao	zhao	PROPN
iajs-2983	242	2	,	,	PUNCT
iajs-2983	242	3	x.	x.	PROPN
iajs-2983	242	4	;	;	PUNCT
iajs-2983	242	5	zhan	zhan	NUM
iajs-2983	242	6	,	,	PUNCT
iajs-2983	242	7	x.	x.	PROPN
iajs-2983	242	8	;	;	PUNCT
iajs-2983	242	9	zhang	zhang	PROPN
iajs-2983	242	10	,	,	PUNCT
iajs-2983	242	11	h.	h.	PROPN
iajs-2983	242	12	;	;	PUNCT
iajs-2983	242	13	wan	wan	PROPN
iajs-2983	242	14	,	,	PUNCT
iajs-2983	242	15	y.	y.	PROPN
iajs-2983	242	16	;	;	PUNCT
iajs-2983	242	17	yang	yang	PROPN
iajs-2983	242	18	,	,	PUNCT
iajs-2983	242	19	h.	h.	PROPN
iajs-2983	242	20	;	;	PUNCT
iajs-2983	242	21	wang	wang	PROPN
iajs-2983	242	22	,	,	PUNCT
iajs-2983	242	23	,	,	PUNCT
iajs-2983	242	24	y.	y.	PROPN
iajs-2983	242	25	;	;	PUNCT
iajs-2983	242	26	chen	chen	PROPN
iajs-2983	242	27	,	,	PUNCT
iajs-2983	242	28	y.	y.	PROPN
iajs-2983	242	29	;	;	PUNCT
iajs-2983	242	30	xie	xie	PROPN
iajs-2983	242	31	,	,	PUNCT
iajs-2983	242	32	w.	w.	NOUN
iajs-2983	242	33	synthesis	synthesis	NOUN
iajs-2983	242	34	and	and	CCONJ
iajs-2983	242	35	biological	biological	ADJ
iajs-2983	242	36	evaluation	evaluation	NOUN
iajs-2983	242	37	,	,	PUNCT
iajs-2983	242	38	of	of	ADP
iajs-2983	242	39	isatin	isatin	ADJ
iajs-2983	242	40	derivatives	derivative	NOUN
iajs-2983	242	41	containing	contain	VERB
iajs-2983	242	42	1,3,4	1,3,4	NUM
iajs-2983	242	43	-	-	PUNCT
iajs-2983	242	44	thiadiazole	thiadiazole	NOUN
iajs-2983	242	45	as	as	ADP
iajs-2983	242	46	,	,	PUNCT
iajs-2983	242	47	potent	potent	ADJ
iajs-2983	242	48	a	a	DET
iajs-2983	242	49	-	-	PUNCT
iajs-2983	242	50	glucosidase	glucosidase	ADJ
iajs-2983	242	51	inhibitors	inhibitor	NOUN
iajs-2983	242	52	.	.	PUNCT
iajs-2983	243	1	bioorganic	bioorganic	PROPN
iajs-2983	243	2	&	&	CCONJ
iajs-2983	243	3	medicinal	medicinal	ADJ
iajs-2983	243	4	,	,	PUNCT
iajs-2983	243	5	chemistry	chemistry	NOUN
iajs-2983	243	6	letters	letter	NOUN
iajs-2983	243	7	2021	2021	NUM
iajs-2983	243	8	,	,	PUNCT
iajs-2983	243	9	54	54	NUM
iajs-2983	243	10	,	,	PUNCT
iajs-2983	243	11	128447	128447	NUM
iajs-2983	243	12	,	,	PUNCT
iajs-2983	243	13	doi:10.1016	doi:10.1016	PROPN
iajs-2983	243	14	/	/	SYM
iajs-2983	243	15	j.bmcl.2021.128447	j.bmcl.2021.128447	PROPN
iajs-2983	243	16	27	27	NUM
iajs-2983	243	17	.	.	PUNCT
iajs-2983	244	1	r.	r.	PROPN
iajs-2983	244	2	a.	a.	PROPN
iajs-2983	244	3	m.	m.	PROPN
iajs-2983	244	4	al	al	PROPN
iajs-2983	244	5	-	-	PUNCT
iajs-2983	244	6	hasani	hasani	PROPN
iajs-2983	244	7	mannich	mannich	PROPN
iajs-2983	244	8	base	base	NOUN
iajs-2983	244	9	,	,	PUNCT
iajs-2983	244	10	derived	derive	VERB
iajs-2983	244	11	from	from	ADP
iajs-2983	244	12	1,3,4	1,3,4	NUM
iajs-2983	244	13	-	-	PUNCT
iajs-2983	244	14	thiadiazole	thiadiazole	NOUN
iajs-2983	244	15	as	as	ADP
iajs-2983	244	16	,	,	PUNCT
iajs-2983	244	17	chelating	chelating	NOUN
iajs-2983	244	18	ligand	ligand	NOUN
iajs-2983	244	19	for	for	ADP
iajs-2983	244	20	some	some	DET
iajs-2983	244	21	transition	transition	NOUN
iajs-2983	244	22	metal	metal	NOUN
iajs-2983	244	23	,	,	PUNCT
iajs-2983	244	24	complexes	complex	NOUN
iajs-2983	244	25	.	.	PUNCT
iajs-2983	245	1	anjs	anj	NOUN
iajs-2983	245	2	2008	2008	NUM
iajs-2983	245	3	,	,	PUNCT
iajs-2983	245	4	11	11	NUM
iajs-2983	245	5	,	,	PUNCT
iajs-2983	245	6	42–56	42–56	NUM
iajs-2983	245	7	,	,	PUNCT
iajs-2983	245	8	doi:10.22401	doi:10.22401	NOUN
iajs-2983	245	9	/	/	SYM
iajs-2983	245	10	jnus.11.2.06	jnus.11.2.06	PROPN
iajs-2983	245	11	.	.	PUNCT
iajs-2983	246	1	https://anjs.edu.iq/index.php/anjs/article/view/1347/1192	https://anjs.edu.iq/index.php/anjs/article/view/1347/1192	PROPN