id	sid	tid	token	lemma	pos
iajs-3279	1	1	242	242	NUM
iajs-3279	1	2	this	this	DET
iajs-3279	1	3	work	work	NOUN
iajs-3279	1	4	is	be	AUX
iajs-3279	1	5	licensed	license	VERB
iajs-3279	1	6	under	under	ADP
iajs-3279	1	7	a	a	DET
iajs-3279	1	8	creative	creative	ADJ
iajs-3279	1	9	commons	common	NOUN
iajs-3279	1	10	attribution	attribution	NOUN
iajs-3279	1	11	4.0	4.0	NUM
iajs-3279	1	12	international	international	ADJ
iajs-3279	1	13	license	license	NOUN
iajs-3279	1	14	ihjpas.37	ihjpas.37	PROPN
iajs-3279	1	15	(	(	PUNCT
iajs-3279	1	16	2	2	NUM
iajs-3279	1	17	)	)	PUNCT
iajs-3279	1	18	2024	2024	NUM
iajs-3279	1	19	ibn	ibn	PROPN
iajs-3279	1	20	al	al	PROPN
iajs-3279	1	21	-	-	PUNCT
iajs-3279	1	22	haitham	haitham	PROPN
iajs-3279	1	23	journal	journal	PROPN
iajs-3279	1	24	for	for	ADP
iajs-3279	1	25	pure	pure	ADJ
iajs-3279	1	26	and	and	CCONJ
iajs-3279	1	27	applied	applied	ADJ
iajs-3279	1	28	sciences	sciences	PROPN
iajs-3279	1	29	journal	journal	PROPN
iajs-3279	1	30	homepage	homepage	NOUN
iajs-3279	1	31	:	:	PUNCT
iajs-3279	1	32	jih.uobaghdad.edu.iq	jih.uobaghdad.edu.iq	NOUN
iajs-3279	1	33	pissn	pissn	ADJ
iajs-3279	1	34	:	:	PUNCT
iajs-3279	1	35	1609	1609	NUM
iajs-3279	1	36	-	-	SYM
iajs-3279	1	37	4042	4042	NUM
iajs-3279	1	38	,	,	PUNCT
iajs-3279	1	39	eissn	eissn	NOUN
iajs-3279	1	40	:	:	PUNCT
iajs-3279	1	41	2521	2521	NUM
iajs-3279	1	42	-	-	SYM
iajs-3279	1	43	3407	3407	NUM
iajs-3279	1	44	amnah	amnah	PROPN
iajs-3279	1	45	mahdi	mahdi	PROPN
iajs-3279	1	46	abdullah	abdullah	PROPN
iajs-3279	1	47	1	1	NUM
iajs-3279	1	48	*	*	PUNCT
iajs-3279	1	49	,	,	PUNCT
iajs-3279	1	50	abbas	abbas	PROPN
iajs-3279	1	51	ali	ali	PROPN
iajs-3279	1	52	salih	salih	PROPN
iajs-3279	1	53	al	al	PROPN
iajs-3279	1	54	-	-	PUNCT
iajs-3279	1	55	hamdani	hamdani	PROPN
iajs-3279	1	56	2	2	NUM
iajs-3279	1	57	and	and	CCONJ
iajs-3279	1	58	wail	wail	PROPN
iajs-3279	1	59	al	al	PROPN
iajs-3279	1	60	zoubi	zoubi	PROPN
iajs-3279	1	61	3	3	NUM
iajs-3279	1	62	1,2	1,2	NUM
iajs-3279	1	63	department	department	NOUN
iajs-3279	1	64	of	of	ADP
iajs-3279	1	65	chemistry	chemistry	NOUN
iajs-3279	1	66	,	,	PUNCT
iajs-3279	1	67	college	college	NOUN
iajs-3279	1	68	of	of	ADP
iajs-3279	1	69	science	science	NOUN
iajs-3279	1	70	for	for	ADP
iajs-3279	1	71	women	woman	NOUN
iajs-3279	1	72	,	,	PUNCT
iajs-3279	1	73	university	university	NOUN
iajs-3279	1	74	of	of	ADP
iajs-3279	1	75	baghdad	baghdad	PROPN
iajs-3279	1	76	,	,	PUNCT
iajs-3279	1	77	baghdad	baghdad	PROPN
iajs-3279	1	78	,	,	PUNCT
iajs-3279	1	79	iraq	iraq	PROPN
iajs-3279	1	80	.	.	PUNCT
iajs-3279	2	1	3	3	NUM
iajs-3279	2	2	school	school	NOUN
iajs-3279	2	3	of	of	ADP
iajs-3279	2	4	materials	material	NOUN
iajs-3279	2	5	science	science	NOUN
iajs-3279	2	6	and	and	CCONJ
iajs-3279	2	7	engineering	engineering	NOUN
iajs-3279	2	8	,	,	PUNCT
iajs-3279	2	9	yeungnam	yeungnam	PROPN
iajs-3279	2	10	university	university	NOUN
iajs-3279	2	11	,	,	PUNCT
iajs-3279	2	12	gyeongsan	gyeongsan	VERB
iajs-3279	2	13	712	712	NUM
iajs-3279	2	14	-	-	SYM
iajs-3279	2	15	749	749	NUM
iajs-3279	2	16	,	,	PUNCT
iajs-3279	2	17	south	south	ADJ
iajs-3279	2	18	koria	koria	NOUN
iajs-3279	2	19	.	.	PUNCT
iajs-3279	3	1	*	*	PUNCT
iajs-3279	3	2	corresponding	correspond	VERB
iajs-3279	3	3	author	author	NOUN
iajs-3279	3	4	.	.	PUNCT
iajs-3279	4	1	abstract	abstract	ADJ
iajs-3279	4	2	diazotization	diazotization	NOUN
iajs-3279	4	3	reaction	reaction	NOUN
iajs-3279	4	4	between	between	ADP
iajs-3279	4	5	1-(2,4,6	1-(2,4,6	NUM
iajs-3279	4	6	-	-	PUNCT
iajs-3279	4	7	trihydroxy	trihydroxy	NOUN
iajs-3279	4	8	-	-	PUNCT
iajs-3279	4	9	phenyl)-ethanone	phenyl)-ethanone	NOUN
iajs-3279	4	10	and	and	CCONJ
iajs-3279	4	11	diazonium	diazonium	NOUN
iajs-3279	4	12	salts	salt	NOUN
iajs-3279	4	13	produced	produce	VERB
iajs-3279	4	14	the	the	DET
iajs-3279	4	15	ligand	ligand	NOUN
iajs-3279	4	16	4-(3	4-(3	PROPN
iajs-3279	4	17	-	-	PUNCT
iajs-3279	4	18	acetyl-2,4,6	acetyl-2,4,6	NOUN
iajs-3279	4	19	-	-	PUNCT
iajs-3279	4	20	trihydroxy	trihydroxy	NOUN
iajs-3279	4	21	-	-	PUNCT
iajs-3279	4	22	phenylazo)-n-(5	phenylazo)-n-(5	VERB
iajs-3279	4	23	-	-	PUNCT
iajs-3279	4	24	methyl	methyl	NOUN
iajs-3279	4	25	-	-	PUNCT
iajs-3279	4	26	isoxazol-3	isoxazol-3	NOUN
iajs-3279	4	27	-	-	PUNCT
iajs-3279	4	28	yl)benzenesulfonamide	yl)benzenesulfonamide	NOUN
iajs-3279	4	29	,	,	PUNCT
iajs-3279	4	30	which	which	PRON
iajs-3279	4	31	in	in	ADP
iajs-3279	4	32	turn	turn	NOUN
iajs-3279	4	33	reacted	react	VERB
iajs-3279	4	34	with	with	ADP
iajs-3279	4	35	the	the	DET
iajs-3279	4	36	metal	metal	NOUN
iajs-3279	4	37	ions	ion	NOUN
iajs-3279	4	38	(	(	PUNCT
iajs-3279	4	39	ni	ni	PROPN
iajs-3279	4	40	2	2	NUM
iajs-3279	4	41	+	+	PROPN
iajs-3279	4	42	,	,	PUNCT
iajs-3279	4	43	zn	zn	PROPN
iajs-3279	4	44	2	2	NUM
iajs-3279	4	45	+	+	NUM
iajs-3279	4	46	,	,	PUNCT
iajs-3279	4	47	pd	pd	PROPN
iajs-3279	4	48	2	2	NUM
iajs-3279	4	49	+	+	NUM
iajs-3279	4	50	and	and	CCONJ
iajs-3279	4	51	pt	pt	INTJ
iajs-3279	4	52	4	4	NUM
iajs-3279	4	53	+	+	CCONJ
iajs-3279	4	54	)	)	PUNCT
iajs-3279	4	55	forming	form	VERB
iajs-3279	4	56	stable	stable	ADJ
iajs-3279	4	57	complexes	complex	NOUN
iajs-3279	4	58	with	with	ADP
iajs-3279	4	59	octahedral	octahedral	ADJ
iajs-3279	4	60	geometry	geometry	NOUN
iajs-3279	4	61	suggest	suggest	NOUN
iajs-3279	4	62	of	of	ADP
iajs-3279	4	63	(	(	PUNCT
iajs-3279	4	64	ni	ni	PROPN
iajs-3279	4	65	2	2	NUM
iajs-3279	4	66	+	+	NUM
iajs-3279	4	67	and	and	CCONJ
iajs-3279	4	68	pt	pt	INTJ
iajs-3279	4	69	4	4	NUM
iajs-3279	4	70	+	+	NUM
iajs-3279	4	71	)	)	PUNCT
iajs-3279	4	72	,	,	PUNCT
iajs-3279	4	73	zn	zn	PROPN
iajs-3279	4	74	2	2	NUM
iajs-3279	4	75	+	+	CCONJ
iajs-3279	4	76	complex	complex	ADJ
iajs-3279	4	77	tetrahedral	tetrahedral	ADJ
iajs-3279	4	78	and	and	CCONJ
iajs-3279	4	79	pd	pd	PROPN
iajs-3279	4	80	2	2	NUM
iajs-3279	4	81	+	+	CCONJ
iajs-3279	4	82	complex	complex	ADJ
iajs-3279	4	83	square	square	ADJ
iajs-3279	4	84	planer	planer	NOUN
iajs-3279	4	85	.	.	PUNCT
iajs-3279	5	1	the	the	DET
iajs-3279	5	2	creation	creation	NOUN
iajs-3279	5	3	of	of	ADP
iajs-3279	5	4	such	such	ADJ
iajs-3279	5	5	complexes	complex	NOUN
iajs-3279	5	6	was	be	AUX
iajs-3279	5	7	detected	detect	VERB
iajs-3279	5	8	by	by	ADP
iajs-3279	5	9	employing	employ	VERB
iajs-3279	5	10	spectroscopic	spectroscopic	ADJ
iajs-3279	5	11	means	mean	NOUN
iajs-3279	5	12	involving	involve	VERB
iajs-3279	5	13	ultraviolet	ultraviolet	NOUN
iajs-3279	5	14	-	-	PUNCT
iajs-3279	5	15	visible	visible	ADJ
iajs-3279	5	16	,	,	PUNCT
iajs-3279	5	17	which	which	PRON
iajs-3279	5	18	proved	prove	VERB
iajs-3279	5	19	the	the	DET
iajs-3279	5	20	obtained	obtain	VERB
iajs-3279	5	21	geometries	geometry	NOUN
iajs-3279	5	22	;	;	PUNCT
iajs-3279	5	23	ft	ft	PROPN
iajs-3279	5	24	-	-	PUNCT
iajs-3279	5	25	ir	ir	PROPN
iajs-3279	5	26	confirmed	confirm	VERB
iajs-3279	5	27	the	the	DET
iajs-3279	5	28	formation	formation	NOUN
iajs-3279	5	29	of	of	ADP
iajs-3279	5	30	the	the	DET
iajs-3279	5	31	azo	azo	NOUN
iajs-3279	5	32	group	group	NOUN
iajs-3279	5	33	and	and	CCONJ
iajs-3279	5	34	the	the	DET
iajs-3279	5	35	coordination	coordination	NOUN
iajs-3279	5	36	with	with	ADP
iajs-3279	5	37	metal	metal	NOUN
iajs-3279	5	38	ions	ion	NOUN
iajs-3279	5	39	through	through	ADP
iajs-3279	5	40	it	it	PRON
iajs-3279	5	41	.	.	PUNCT
iajs-3279	6	1	thermogravimetric	thermogravimetric	ADJ
iajs-3279	6	2	analysis	analysis	NOUN
iajs-3279	6	3	studies	study	NOUN
iajs-3279	6	4	demonstrated	demonstrate	VERB
iajs-3279	6	5	the	the	DET
iajs-3279	6	6	coordination	coordination	NOUN
iajs-3279	6	7	of	of	ADP
iajs-3279	6	8	water	water	NOUN
iajs-3279	6	9	residues	residue	NOUN
iajs-3279	6	10	(	(	PUNCT
iajs-3279	6	11	aqua	aqua	NOUN
iajs-3279	6	12	or	or	CCONJ
iajs-3279	6	13	hydrate	hydrate	NOUN
iajs-3279	6	14	)	)	PUNCT
iajs-3279	6	15	with	with	ADP
iajs-3279	6	16	metal	metal	NOUN
iajs-3279	6	17	ions	ion	NOUN
iajs-3279	6	18	inside	inside	ADP
iajs-3279	6	19	the	the	DET
iajs-3279	6	20	coordination	coordination	NOUN
iajs-3279	6	21	sphere	sphere	ADV
iajs-3279	6	22	,	,	PUNCT
iajs-3279	6	23	as	as	ADV
iajs-3279	6	24	well	well	ADV
iajs-3279	6	25	as	as	ADP
iajs-3279	6	26	used	use	VERB
iajs-3279	6	27	curve	curve	NOUN
iajs-3279	6	28	dsc	dsc	NOUN
iajs-3279	6	29	to	to	PART
iajs-3279	6	30	calculate	calculate	VERB
iajs-3279	6	31	the	the	DET
iajs-3279	6	32	thermodynamic	thermodynamic	ADJ
iajs-3279	6	33	parameters	parameter	NOUN
iajs-3279	6	34	δh	δh	ADP
iajs-3279	6	35	,	,	PUNCT
iajs-3279	6	36	δs	δs	NOUN
iajs-3279	6	37	,	,	PUNCT
iajs-3279	6	38	and	and	CCONJ
iajs-3279	6	39	δg	δg	VERB
iajs-3279	6	40	.	.	PROPN
iajs-3279	7	1	moreover	moreover	ADV
iajs-3279	7	2	,	,	PUNCT
iajs-3279	7	3	element	element	NOUN
iajs-3279	7	4	microanalysis	microanalysis	NOUN
iajs-3279	7	5	and	and	CCONJ
iajs-3279	7	6	atomic	atomic	ADJ
iajs-3279	7	7	absorption	absorption	NOUN
iajs-3279	7	8	gave	give	VERB
iajs-3279	7	9	corresponding	correspond	VERB
iajs-3279	7	10	outcomes	outcome	NOUN
iajs-3279	7	11	with	with	ADP
iajs-3279	7	12	theoretically	theoretically	ADV
iajs-3279	7	13	counting	count	VERB
iajs-3279	7	14	outcomes	outcome	NOUN
iajs-3279	7	15	.	.	PUNCT
iajs-3279	8	1	neuclearmagnatic	neuclearmagnatic	ADJ
iajs-3279	8	2	resonances	resonance	NOUN
iajs-3279	8	3	for	for	ADP
iajs-3279	8	4	1	1	NUM
iajs-3279	8	5	h	h	NOUN
iajs-3279	8	6	and	and	CCONJ
iajs-3279	8	7	13	13	NUM
iajs-3279	8	8	c	c	NOUN
iajs-3279	8	9	,	,	PUNCT
iajs-3279	8	10	chlorine	chlorine	NOUN
iajs-3279	8	11	atoms	atom	NOUN
iajs-3279	8	12	,	,	PUNCT
iajs-3279	8	13	and	and	CCONJ
iajs-3279	8	14	magnetic	magnetic	ADJ
iajs-3279	8	15	moment	moment	NOUN
iajs-3279	8	16	quantifications	quantification	NOUN
iajs-3279	8	17	also	also	ADV
iajs-3279	8	18	indicate	indicate	VERB
iajs-3279	8	19	the	the	DET
iajs-3279	8	20	formation	formation	NOUN
iajs-3279	8	21	of	of	ADP
iajs-3279	8	22	azo	azo	NOUN
iajs-3279	8	23	dye	dye	PROPN
iajs-3279	8	24	ligand	ligand	NOUN
iajs-3279	8	25	.	.	PUNCT
iajs-3279	9	1	the	the	DET
iajs-3279	9	2	ligand	ligand	ADJ
iajs-3279	9	3	and	and	CCONJ
iajs-3279	9	4	new	new	ADJ
iajs-3279	9	5	complexes	complex	NOUN
iajs-3279	9	6	showed	show	VERB
iajs-3279	9	7	antioxidant	antioxidant	ADJ
iajs-3279	9	8	abilities	ability	NOUN
iajs-3279	9	9	to	to	PART
iajs-3279	9	10	scavenge	scavenge	VERB
iajs-3279	9	11	free	free	ADJ
iajs-3279	9	12	radicals	radical	NOUN
iajs-3279	9	13	.	.	PUNCT
iajs-3279	10	1	keywords	keyword	NOUN
iajs-3279	10	2	:	:	PUNCT
iajs-3279	10	3	antioxidant	antioxidant	ADJ
iajs-3279	10	4	,	,	PUNCT
iajs-3279	10	5	mass	mass	NOUN
iajs-3279	10	6	spectroscopy	spectroscopy	NOUN
iajs-3279	10	7	,	,	PUNCT
iajs-3279	10	8	azo	azo	NOUN
iajs-3279	10	9	dye	dye	PROPN
iajs-3279	10	10	,	,	PUNCT
iajs-3279	10	11	1-(2,4,6	1-(2,4,6	NUM
iajs-3279	10	12	-	-	PUNCT
iajs-3279	10	13	trihydroxy	trihydroxy	NOUN
iajs-3279	10	14	-	-	PUNCT
iajs-3279	10	15	phenyl)-ethanone	phenyl)-ethanone	NOUN
iajs-3279	10	16	,	,	PUNCT
iajs-3279	10	17	thermal	thermal	ADJ
iajs-3279	10	18	analysis	analysis	NOUN
iajs-3279	10	19	.	.	PUNCT
iajs-3279	11	1	1	1	X
iajs-3279	11	2	.	.	X
iajs-3279	11	3	introduction	introduction	NOUN
iajs-3279	11	4	until	until	ADP
iajs-3279	11	5	the	the	DET
iajs-3279	11	6	middle	middle	NOUN
iajs-3279	11	7	of	of	ADP
iajs-3279	11	8	the	the	DET
iajs-3279	11	9	19	19	NUM
iajs-3279	11	10	th	th	NUM
iajs-3279	11	11	century	century	NOUN
iajs-3279	11	12	,	,	PUNCT
iajs-3279	11	13	all	all	DET
iajs-3279	11	14	coloring	color	VERB
iajs-3279	11	15	materials	material	NOUN
iajs-3279	11	16	were	be	AUX
iajs-3279	11	17	supplied	supply	VERB
iajs-3279	11	18	from	from	ADP
iajs-3279	11	19	natural	natural	ADJ
iajs-3279	11	20	sources	source	NOUN
iajs-3279	11	21	such	such	ADJ
iajs-3279	11	22	as	as	ADP
iajs-3279	11	23	inorganic	inorganic	ADJ
iajs-3279	11	24	dyes	dye	NOUN
iajs-3279	11	25	[	[	X
iajs-3279	11	26	1	1	NUM
iajs-3279	11	27	]	]	PUNCT
iajs-3279	11	28	.	.	PUNCT
iajs-3279	12	1	as	as	ADP
iajs-3279	12	2	for	for	ADP
iajs-3279	12	3	natural	natural	ADJ
iajs-3279	12	4	organic	organic	ADJ
iajs-3279	12	5	dyes	dye	NOUN
iajs-3279	12	6	,	,	PUNCT
iajs-3279	12	7	they	they	PRON
iajs-3279	12	8	also	also	ADV
iajs-3279	12	9	have	have	VERB
iajs-3279	12	10	an	an	DET
iajs-3279	12	11	ancient	ancient	ADJ
iajs-3279	12	12	history	history	NOUN
iajs-3279	12	13	of	of	ADP
iajs-3279	12	14	use	use	NOUN
iajs-3279	12	15	,	,	PUNCT
iajs-3279	12	16	especially	especially	ADV
iajs-3279	12	17	in	in	ADP
iajs-3279	12	18	tissues	tissue	NOUN
iajs-3279	12	19	dyeing	dyeing	NOUN
iajs-3279	12	20	[	[	X
iajs-3279	12	21	2	2	NUM
iajs-3279	12	22	]	]	PUNCT
iajs-3279	12	23	.	.	PUNCT
iajs-3279	13	1	heterogeneous	heterogeneous	ADJ
iajs-3279	13	2	azo	azo	NOUN
iajs-3279	13	3	compounds	compound	NOUN
iajs-3279	13	4	,	,	PUNCT
iajs-3279	13	5	in	in	ADP
iajs-3279	13	6	particular	particular	ADJ
iajs-3279	13	7	,	,	PUNCT
iajs-3279	13	8	won	win	VERB
iajs-3279	13	9	a	a	DET
iajs-3279	13	10	wide	wide	ADJ
iajs-3279	13	11	area	area	NOUN
iajs-3279	13	12	in	in	ADP
iajs-3279	13	13	several	several	ADJ
iajs-3279	13	14	fields	field	NOUN
iajs-3279	13	15	because	because	SCONJ
iajs-3279	13	16	they	they	PRON
iajs-3279	13	17	contain	contain	VERB
iajs-3279	13	18	more	more	ADJ
iajs-3279	13	19	than	than	ADP
iajs-3279	13	20	one	one	NUM
iajs-3279	13	21	active	active	ADJ
iajs-3279	13	22	group	group	NOUN
iajs-3279	13	23	that	that	PRON
iajs-3279	13	24	has	have	VERB
iajs-3279	13	25	the	the	DET
iajs-3279	13	26	ability	ability	NOUN
iajs-3279	13	27	to	to	PART
iajs-3279	13	28	form	form	VERB
iajs-3279	13	29	complexes	complex	NOUN
iajs-3279	13	30	of	of	ADP
iajs-3279	13	31	colored	colored	ADJ
iajs-3279	13	32	aggregates	aggregate	NOUN
iajs-3279	13	33	,	,	PUNCT
iajs-3279	13	34	which	which	PRON
iajs-3279	13	35	facilitates	facilitate	VERB
iajs-3279	13	36	the	the	DET
iajs-3279	13	37	spectroscopic	spectroscopic	ADJ
iajs-3279	13	38	determination	determination	NOUN
iajs-3279	13	39	of	of	ADP
iajs-3279	13	40	very	very	ADV
iajs-3279	13	41	small	small	ADJ
iajs-3279	13	42	concentrations	concentration	NOUN
iajs-3279	13	43	of	of	ADP
iajs-3279	13	44	metal	metal	NOUN
iajs-3279	13	45	ions	ion	NOUN
iajs-3279	13	46	using	use	VERB
iajs-3279	13	47	the	the	DET
iajs-3279	13	48	visible	visible	ADJ
iajs-3279	13	49	-	-	PUNCT
iajs-3279	13	50	ultraviolet	ultraviolet	NOUN
iajs-3279	13	51	spectra	spectra	NOUN
iajs-3279	14	1	[	[	X
iajs-3279	14	2	3	3	NUM
iajs-3279	14	3	-	-	SYM
iajs-3279	14	4	5	5	NUM
iajs-3279	14	5	]	]	PUNCT
iajs-3279	14	6	.	.	PUNCT
iajs-3279	15	1	this	this	PRON
iajs-3279	15	2	led	lead	VERB
iajs-3279	15	3	to	to	ADP
iajs-3279	15	4	the	the	DET
iajs-3279	15	5	emergence	emergence	NOUN
iajs-3279	15	6	of	of	ADP
iajs-3279	15	7	new	new	ADJ
iajs-3279	15	8	dyes	dye	NOUN
iajs-3279	15	9	,	,	PUNCT
iajs-3279	15	10	and	and	CCONJ
iajs-3279	15	11	kekule	kekule	NOUN
iajs-3279	15	12	's	's	PART
iajs-3279	15	13	discovery	discovery	NOUN
iajs-3279	15	14	of	of	ADP
iajs-3279	15	15	the	the	DET
iajs-3279	15	16	molecular	molecular	ADJ
iajs-3279	15	17	structure	structure	NOUN
iajs-3279	15	18	of	of	ADP
iajs-3279	15	19	benzene	benzene	NOUN
iajs-3279	15	20	in	in	ADP
iajs-3279	15	21	1865	1865	NUM
iajs-3279	15	22	had	have	VERB
iajs-3279	15	23	a	a	DET
iajs-3279	15	24	great	great	ADJ
iajs-3279	15	25	impact	impact	NOUN
iajs-3279	15	26	on	on	ADP
iajs-3279	15	27	the	the	DET
iajs-3279	15	28	development	development	NOUN
iajs-3279	15	29	of	of	ADP
iajs-3279	15	30	dyes	dye	NOUN
iajs-3279	15	31	until	until	ADP
iajs-3279	15	32	the	the	DET
iajs-3279	15	33	beginning	beginning	NOUN
iajs-3279	15	34	of	of	ADP
iajs-3279	15	35	the	the	DET
iajs-3279	15	36	twentieth	twentieth	ADJ
iajs-3279	15	37	century	century	NOUN
iajs-3279	16	1	[	[	X
iajs-3279	16	2	6,7	6,7	NUM
iajs-3279	16	3	]	]	PUNCT
iajs-3279	16	4	.	.	PUNCT
iajs-3279	17	1	received:7	received:7	ADP
iajs-3279	17	2	february	february	PROPN
iajs-3279	17	3	2023	2023	NUM
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iajs-3279	17	13	and	and	CCONJ
iajs-3279	17	14	determination	determination	NOUN
iajs-3279	17	15	antioxidant	antioxidant	NOUN
iajs-3279	17	16	activities	activity	NOUN
iajs-3279	17	17	for	for	ADP
iajs-3279	17	18	new	new	ADJ
iajs-3279	17	19	azo	azo	NOUN
iajs-3279	17	20	dyederived	dyederive	VERB
iajs-3279	17	21	from	from	ADP
iajs-3279	17	22	sulfamethoxazole	sulfamethoxazole	NOUN
iajs-3279	17	23	and	and	CCONJ
iajs-3279	17	24	some	some	DET
iajs-3279	17	25	metal	metal	NOUN
iajs-3279	17	26	ion	ion	NOUN
iajs-3279	17	27	complexes	complex	NOUN
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iajs-3279	17	33	mailto:abbasas_chem@csw.uobaghdad.edu.iq	mailto:abbasas_chem@csw.uobaghdad.edu.iq	PROPN
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iajs-3279	17	41	mailto:wwailalzoubi@yahoo.com	mailto:wwailalzoubi@yahoo.com	PROPN
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iajs-3279	17	45	mailto:abbasas_chem@csw.uobaghdad.edu.iq	mailto:abbasas_chem@csw.uobaghdad.edu.iq	PROPN
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iajs-3279	18	3	https://orcid.org/0000-0002-9187-2677	https://orcid.org/0000-0002-9187-2677	PROPN
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iajs-3279	18	6	mailto:abbasas_chem@csw.uobaghdad.edu.iq	mailto:abbasas_chem@csw.uobaghdad.edu.iq	PROPN
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iajs-3279	18	8	mailto:wwailalzoubi@yahoo.com	mailto:wwailalzoubi@yahoo.com	PROPN
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iajs-3279	18	12	mailto:abbasas_chem@csw.uobaghdad.edu.iq	mailto:abbasas_chem@csw.uobaghdad.edu.iq	PROPN
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iajs-3279	18	14	mailto:wwailalzoubi@yahoo.com	mailto:wwailalzoubi@yahoo.com	PROPN
iajs-3279	18	15	https://orcid.org/0000-0002-9187-2677	https://orcid.org/0000-0002-9187-2677	PROPN
iajs-3279	18	16	mailto:amnah.mahdi.abdullah@gmail.com	mailto:amnah.mahdi.abdullah@gmail.com	PROPN
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iajs-3279	18	18	mailto:abbasas_chem@csw.uobaghdad.edu.iq	mailto:abbasas_chem@csw.uobaghdad.edu.iq	PROPN
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iajs-3279	18	20	mailto:wwailalzoubi@yahoo.com	mailto:wwailalzoubi@yahoo.com	PROPN
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iajs-3279	18	22	mailto:amnah.mahdi.abdullah@gmail.com	mailto:amnah.mahdi.abdullah@gmail.com	PROPN
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iajs-3279	18	24	mailto:abbasas_chem@csw.uobaghdad.edu.iq	mailto:abbasas_chem@csw.uobaghdad.edu.iq	PROPN
iajs-3279	18	25	https://orcid.org/0000-0002-9959-1431	https://orcid.org/0000-0002-9959-1431	PROPN
iajs-3279	18	26	mailto:wwailalzoubi@yahoo.com	mailto:wwailalzoubi@yahoo.com	PROPN
iajs-3279	18	27	https://orcid.org/0000-0002-9187-2677	https://orcid.org/0000-0002-9187-2677	PROPN
iajs-3279	18	28	mailto:amnah.mahdi.abdullah@gmail.com	mailto:amnah.mahdi.abdullah@gmail.com	PROPN
iajs-3279	18	29	https://orcid.org/0000-0002-2506-986x	https://orcid.org/0000-0002-2506-986x	PROPN
iajs-3279	18	30	mailto:abbasas_chem@csw.uobaghdad.edu.iq	mailto:abbasas_chem@csw.uobaghdad.edu.iq	PROPN
iajs-3279	18	31	https://orcid.org/0000-0002-9959-1431	https://orcid.org/0000-0002-9959-1431	PROPN
iajs-3279	18	32	mailto:wwailalzoubi@yahoo.com	mailto:wwailalzoubi@yahoo.com	PROPN
iajs-3279	18	33	https://orcid.org/0000-0002-9187-2677	https://orcid.org/0000-0002-9187-2677	PROPN
iajs-3279	18	34	mailto:amnah.mahdi.abdullah@gmail.com	mailto:amnah.mahdi.abdullah@gmail.com	PROPN
iajs-3279	18	35	https://orcid.org/0000-0002-2506-986x	https://orcid.org/0000-0002-2506-986x	PROPN
iajs-3279	18	36	mailto:abbasas_chem@csw.uobaghdad.edu.iq	mailto:abbasas_chem@csw.uobaghdad.edu.iq	PROPN
iajs-3279	18	37	https://orcid.org/0000-0002-9959-1431	https://orcid.org/0000-0002-9959-1431	PROPN
iajs-3279	18	38	mailto:wwailalzoubi@yahoo.com	mailto:wwailalzoubi@yahoo.com	PROPN
iajs-3279	18	39	https://orcid.org/0000-0002-9187-2677	https://orcid.org/0000-0002-9187-2677	PROPN
iajs-3279	18	40	mailto:amnah.mahdi.abdullah@gmail.com	mailto:amnah.mahdi.abdullah@gmail.com	PROPN
iajs-3279	18	41	https://orcid.org/0000-0002-2506-986x	https://orcid.org/0000-0002-2506-986x	PROPN
iajs-3279	18	42	mailto:abbasas_chem@csw.uobaghdad.edu.iq	mailto:abbasas_chem@csw.uobaghdad.edu.iq	PROPN
iajs-3279	18	43	https://orcid.org/0000-0002-9959-1431	https://orcid.org/0000-0002-9959-1431	PROPN
iajs-3279	18	44	mailto:wwailalzoubi@yahoo.com	mailto:wwailalzoubi@yahoo.com	PROPN
iajs-3279	18	45	https://orcid.org/0000-0002-9187-2677	https://orcid.org/0000-0002-9187-2677	PROPN
iajs-3279	18	46	mailto:amnah.mahdi.abdullah@gmail.com	mailto:amnah.mahdi.abdullah@gmail.com	PROPN
iajs-3279	18	47	https://orcid.org/0000-0002-2506-986x	https://orcid.org/0000-0002-2506-986x	PROPN
iajs-3279	18	48	mailto:abbasas_chem@csw.uobaghdad.edu.iq	mailto:abbasas_chem@csw.uobaghdad.edu.iq	PROPN
iajs-3279	18	49	https://orcid.org/0000-0002-9959-1431	https://orcid.org/0000-0002-9959-1431	PROPN
iajs-3279	18	50	mailto:wwailalzoubi@yahoo.com	mailto:wwailalzoubi@yahoo.com	PROPN
iajs-3279	18	51	https://orcid.org/0000-0002-9187-2677	https://orcid.org/0000-0002-9187-2677	PROPN
iajs-3279	18	52	mailto:amnah.mahdi.abdullah@gmail.com	mailto:amnah.mahdi.abdullah@gmail.com	PROPN
iajs-3279	18	53	https://orcid.org/0000-0002-2506-986x	https://orcid.org/0000-0002-2506-986x	PROPN
iajs-3279	18	54	mailto:abbasas_chem@csw.uobaghdad.edu.iq	mailto:abbasas_chem@csw.uobaghdad.edu.iq	PROPN
iajs-3279	18	55	https://orcid.org/0000-0002-9959-1431	https://orcid.org/0000-0002-9959-1431	PROPN
iajs-3279	18	56	mailto:wwailalzoubi@yahoo.com	mailto:wwailalzoubi@yahoo.com	PROPN
iajs-3279	18	57	https://orcid.org/0000-0002-9187-2677	https://orcid.org/0000-0002-9187-2677	PROPN
iajs-3279	18	58	mailto:amnah.mahdi.abdullah@gmail.com	mailto:amnah.mahdi.abdullah@gmail.com	PROPN
iajs-3279	18	59	https://orcid.org/0000-0002-2506-986x	https://orcid.org/0000-0002-2506-986x	PROPN
iajs-3279	18	60	mailto:abbasas_chem@csw.uobaghdad.edu.iq	mailto:abbasas_chem@csw.uobaghdad.edu.iq	PROPN
iajs-3279	18	61	https://orcid.org/0000-0002-9959-1431	https://orcid.org/0000-0002-9959-1431	PROPN
iajs-3279	18	62	mailto:wwailalzoubi@yahoo.com	mailto:wwailalzoubi@yahoo.com	PROPN
iajs-3279	18	63	https://orcid.org/0000-0002-9187-2677	https://orcid.org/0000-0002-9187-2677	PROPN
iajs-3279	18	64	mailto:amnah.mahdi.abdullah@gmail.com	mailto:amnah.mahdi.abdullah@gmail.com	PROPN
iajs-3279	18	65	https://orcid.org/0000-0002-2506-986x	https://orcid.org/0000-0002-2506-986x	PROPN
iajs-3279	18	66	mailto:abbasas_chem@csw.uobaghdad.edu.iq	mailto:abbasas_chem@csw.uobaghdad.edu.iq	PROPN
iajs-3279	18	67	https://orcid.org/0000-0002-9959-1431	https://orcid.org/0000-0002-9959-1431	PROPN
iajs-3279	18	68	mailto:wwailalzoubi@yahoo.com	mailto:wwailalzoubi@yahoo.com	PROPN
iajs-3279	18	69	https://orcid.org/0000-0002-9187-2677	https://orcid.org/0000-0002-9187-2677	PROPN
iajs-3279	18	70	mailto:amnah.mahdi.abdullah@gmail.com	mailto:amnah.mahdi.abdullah@gmail.com	PROPN
iajs-3279	18	71	https://orcid.org/0000-0002-2506-986x	https://orcid.org/0000-0002-2506-986x	PROPN
iajs-3279	18	72	mailto:abbasas_chem@csw.uobaghdad.edu.iq	mailto:abbasas_chem@csw.uobaghdad.edu.iq	PROPN
iajs-3279	18	73	https://orcid.org/0000-0002-9959-1431	https://orcid.org/0000-0002-9959-1431	PROPN
iajs-3279	18	74	mailto:wwailalzoubi@yahoo.com	mailto:wwailalzoubi@yahoo.com	PROPN
iajs-3279	18	75	ihjpas.37	ihjpas.37	PROPN
iajs-3279	18	76	(	(	PUNCT
iajs-3279	18	77	2	2	NUM
iajs-3279	18	78	)	)	PUNCT
iajs-3279	18	79	2024	2024	NUM
iajs-3279	18	80	244	244	NUM
iajs-3279	18	81	thus	thus	ADV
iajs-3279	18	82	,	,	PUNCT
iajs-3279	18	83	natural	natural	ADJ
iajs-3279	18	84	dyes	dye	NOUN
iajs-3279	18	85	were	be	AUX
iajs-3279	18	86	replaced	replace	VERB
iajs-3279	18	87	by	by	ADP
iajs-3279	18	88	synthetic	synthetic	ADJ
iajs-3279	18	89	dyes	dye	NOUN
iajs-3279	18	90	[	[	X
iajs-3279	18	91	8	8	NUM
iajs-3279	18	92	]	]	PUNCT
iajs-3279	18	93	.	.	PUNCT
iajs-3279	19	1	azo	azo	PROPN
iajs-3279	19	2	dyes	dye	NOUN
iajs-3279	19	3	are	be	AUX
iajs-3279	19	4	organic	organic	ADJ
iajs-3279	19	5	substances	substance	NOUN
iajs-3279	19	6	consisting	consist	VERB
iajs-3279	19	7	of	of	ADP
iajs-3279	19	8	two	two	NUM
iajs-3279	19	9	organic	organic	ADJ
iajs-3279	19	10	groups	group	NOUN
iajs-3279	19	11	linked	link	VERB
iajs-3279	19	12	through	through	ADP
iajs-3279	19	13	coupling	couple	VERB
iajs-3279	19	14	reactions	reaction	NOUN
iajs-3279	19	15	with	with	ADP
iajs-3279	19	16	an	an	DET
iajs-3279	19	17	azo	azo	NOUN
iajs-3279	19	18	group	group	NOUN
iajs-3279	19	19	to	to	PART
iajs-3279	19	20	give	give	VERB
iajs-3279	19	21	colored	colored	ADJ
iajs-3279	19	22	compounds	compound	NOUN
iajs-3279	19	23	that	that	PRON
iajs-3279	19	24	are	be	AUX
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iajs-3279	19	26	in	in	ADP
iajs-3279	19	27	the	the	DET
iajs-3279	19	28	visible	visible	ADJ
iajs-3279	19	29	and	and	CCONJ
iajs-3279	19	30	ultraviolet	ultraviolet	ADJ
iajs-3279	19	31	regions	region	NOUN
iajs-3279	19	32	[	[	X
iajs-3279	19	33	9	9	NUM
iajs-3279	19	34	-	-	SYM
iajs-3279	19	35	12	12	NUM
iajs-3279	19	36	]	]	PUNCT
iajs-3279	19	37	.	.	PUNCT
iajs-3279	20	1	azo	azo	PROPN
iajs-3279	20	2	dyes	dye	NOUN
iajs-3279	20	3	are	be	AUX
iajs-3279	20	4	considered	consider	VERB
iajs-3279	20	5	the	the	DET
iajs-3279	20	6	most	most	ADV
iajs-3279	20	7	significant	significant	ADJ
iajs-3279	20	8	group	group	NOUN
iajs-3279	20	9	within	within	ADP
iajs-3279	20	10	organic	organic	ADJ
iajs-3279	20	11	dyes	dye	NOUN
iajs-3279	20	12	,	,	PUNCT
iajs-3279	20	13	which	which	PRON
iajs-3279	20	14	are	be	AUX
iajs-3279	20	15	prepared	prepare	VERB
iajs-3279	20	16	industrially	industrially	ADV
iajs-3279	20	17	and	and	CCONJ
iajs-3279	20	18	can	can	AUX
iajs-3279	20	19	add	add	VERB
iajs-3279	20	20	colors	color	NOUN
iajs-3279	20	21	to	to	ADP
iajs-3279	20	22	fibers	fiber	NOUN
iajs-3279	20	23	[	[	X
iajs-3279	20	24	13	13	NUM
iajs-3279	20	25	]	]	PUNCT
iajs-3279	20	26	.	.	PUNCT
iajs-3279	21	1	they	they	PRON
iajs-3279	21	2	contain	contain	VERB
iajs-3279	21	3	an	an	DET
iajs-3279	21	4	azo	azo	NOUN
iajs-3279	21	5	group	group	NOUN
iajs-3279	21	6	–	–	PUNCT
iajs-3279	21	7	n	n	NOUN
iajs-3279	21	8	=	=	SYM
iajs-3279	21	9	n	n	CCONJ
iajs-3279	21	10	–	–	PUNCT
iajs-3279	21	11	as	as	SCONJ
iajs-3279	21	12	nitrogen	nitrogen	NOUN
iajs-3279	21	13	atoms	atom	NOUN
iajs-3279	21	14	are	be	AUX
iajs-3279	21	15	linked	link	VERB
iajs-3279	21	16	to	to	ADP
iajs-3279	21	17	carbon	carbon	NOUN
iajs-3279	21	18	atoms	atom	NOUN
iajs-3279	21	19	with	with	ADP
iajs-3279	21	20	sphybridization	sphybridization	NOUN
iajs-3279	21	21	and	and	CCONJ
iajs-3279	21	22	at	at	ADV
iajs-3279	21	23	least	least	ADJ
iajs-3279	21	24	one	one	NUM
iajs-3279	21	25	carbon	carbon	NOUN
iajs-3279	21	26	atom	atom	NOUN
iajs-3279	21	27	is	be	AUX
iajs-3279	21	28	connected	connect	VERB
iajs-3279	21	29	to	to	ADP
iajs-3279	21	30	a	a	DET
iajs-3279	21	31	ring	ring	NOUN
iajs-3279	21	32	(	(	PUNCT
iajs-3279	21	33	usually	usually	ADV
iajs-3279	21	34	benzene	benzene	NOUN
iajs-3279	21	35	or	or	CCONJ
iajs-3279	21	36	naphthalene	naphthalene	NOUN
iajs-3279	21	37	derivatives	derivative	NOUN
iajs-3279	21	38	)	)	PUNCT
iajs-3279	21	39	or	or	CCONJ
iajs-3279	21	40	polycyclic	polycyclic	NOUN
iajs-3279	21	41	such	such	ADJ
iajs-3279	21	42	as	as	ADP
iajs-3279	21	43	(	(	PUNCT
iajs-3279	21	44	pyrazolone	pyrazolone	NOUN
iajs-3279	21	45	or	or	CCONJ
iajs-3279	21	46	thiazole	thiazole	NOUN
iajs-3279	21	47	)	)	PUNCT
iajs-3279	22	1	[	[	X
iajs-3279	22	2	14	14	NUM
iajs-3279	22	3	]	]	PUNCT
iajs-3279	22	4	.	.	PUNCT
iajs-3279	23	1	studies	study	NOUN
iajs-3279	23	2	have	have	AUX
iajs-3279	23	3	shown	show	VERB
iajs-3279	23	4	that	that	SCONJ
iajs-3279	23	5	these	these	DET
iajs-3279	23	6	compounds	compound	NOUN
iajs-3279	23	7	represent	represent	VERB
iajs-3279	23	8	essential	essential	ADJ
iajs-3279	23	9	drugs	drug	NOUN
iajs-3279	23	10	,	,	PUNCT
iajs-3279	23	11	as	as	SCONJ
iajs-3279	23	12	they	they	PRON
iajs-3279	23	13	were	be	AUX
iajs-3279	23	14	found	find	VERB
iajs-3279	23	15	to	to	PART
iajs-3279	23	16	have	have	VERB
iajs-3279	23	17	properties	property	NOUN
iajs-3279	23	18	that	that	PRON
iajs-3279	23	19	inhibit	inhibit	VERB
iajs-3279	23	20	the	the	DET
iajs-3279	23	21	growth	growth	NOUN
iajs-3279	23	22	of	of	ADP
iajs-3279	23	23	bacteria	bacteria	NOUN
iajs-3279	23	24	[	[	X
iajs-3279	23	25	15	15	NUM
iajs-3279	23	26	-	-	SYM
iajs-3279	23	27	17	17	NUM
iajs-3279	23	28	]	]	PUNCT
iajs-3279	23	29	.	.	PUNCT
iajs-3279	24	1	due	due	ADP
iajs-3279	24	2	to	to	ADP
iajs-3279	24	3	the	the	DET
iajs-3279	24	4	importance	importance	NOUN
iajs-3279	24	5	of	of	ADP
iajs-3279	24	6	these	these	DET
iajs-3279	24	7	compounds	compound	NOUN
iajs-3279	24	8	,	,	PUNCT
iajs-3279	24	9	the	the	DET
iajs-3279	24	10	current	current	ADJ
iajs-3279	24	11	research	research	NOUN
iajs-3279	24	12	included	include	VERB
iajs-3279	24	13	the	the	DET
iajs-3279	24	14	preparation	preparation	NOUN
iajs-3279	24	15	and	and	CCONJ
iajs-3279	24	16	identification	identification	NOUN
iajs-3279	24	17	of	of	ADP
iajs-3279	24	18	a	a	DET
iajs-3279	24	19	new	new	ADJ
iajs-3279	24	20	azo	azo	NOUN
iajs-3279	24	21	dye	dye	NOUN
iajs-3279	24	22	derived	derive	VERB
iajs-3279	24	23	from	from	ADP
iajs-3279	24	24	1(2,4,6	1(2,4,6	NUM
iajs-3279	24	25	-	-	PUNCT
iajs-3279	24	26	trihydroxy	trihydroxy	NOUN
iajs-3279	24	27	-	-	PUNCT
iajs-3279	24	28	phenyl)-ethanone	phenyl)-ethanone	NOUN
iajs-3279	24	29	and	and	CCONJ
iajs-3279	24	30	sulfamethoxazole	sulfamethoxazole	NOUN
iajs-3279	24	31	.	.	PUNCT
iajs-3279	25	1	this	this	DET
iajs-3279	25	2	work	work	NOUN
iajs-3279	25	3	aims	aim	VERB
iajs-3279	25	4	to	to	PART
iajs-3279	25	5	synthesize	synthesize	VERB
iajs-3279	25	6	new	new	ADJ
iajs-3279	25	7	metal	metal	NOUN
iajs-3279	25	8	ions	ion	NOUN
iajs-3279	25	9	complexes	complex	NOUN
iajs-3279	25	10	(	(	PUNCT
iajs-3279	25	11	ni	ni	PROPN
iajs-3279	25	12	2	2	NUM
iajs-3279	25	13	+	+	PROPN
iajs-3279	25	14	,	,	PUNCT
iajs-3279	25	15	zn	zn	PROPN
iajs-3279	25	16	2	2	NUM
iajs-3279	25	17	+	+	NUM
iajs-3279	25	18	,	,	PUNCT
iajs-3279	25	19	pd	pd	PROPN
iajs-3279	25	20	2	2	NUM
iajs-3279	25	21	+	+	NUM
iajs-3279	25	22	and	and	CCONJ
iajs-3279	25	23	pt	pt	INTJ
iajs-3279	25	24	4	4	NUM
iajs-3279	25	25	+	+	CCONJ
iajs-3279	25	26	)	)	PUNCT
iajs-3279	25	27	from	from	ADP
iajs-3279	25	28	azo	azo	PROPN
iajs-3279	25	29	ligand	ligand	NOUN
iajs-3279	25	30	h3l	h3l	PRON
iajs-3279	25	31	as	as	ADV
iajs-3279	25	32	well	well	ADV
iajs-3279	25	33	as	as	ADP
iajs-3279	25	34	characterization	characterization	NOUN
iajs-3279	25	35	with	with	ADP
iajs-3279	25	36	spectroscopic	spectroscopic	ADJ
iajs-3279	25	37	analysis	analysis	NOUN
iajs-3279	25	38	and	and	CCONJ
iajs-3279	25	39	studying	study	VERB
iajs-3279	25	40	thermal	thermal	ADJ
iajs-3279	25	41	decomposition	decomposition	NOUN
iajs-3279	25	42	and	and	CCONJ
iajs-3279	25	43	thermal	thermal	ADJ
iajs-3279	25	44	stability	stability	NOUN
iajs-3279	25	45	by	by	ADP
iajs-3279	25	46	using	use	VERB
iajs-3279	25	47	dsc	dsc	NOUN
iajs-3279	25	48	and	and	CCONJ
iajs-3279	25	49	tga	tga	PROPN
iajs-3279	25	50	curve	curve	NOUN
iajs-3279	25	51	.	.	PUNCT
iajs-3279	26	1	this	this	DET
iajs-3279	26	2	study	study	NOUN
iajs-3279	26	3	uses	use	VERB
iajs-3279	26	4	curve	curve	NOUN
iajs-3279	26	5	dsc	dsc	PROPN
iajs-3279	26	6	to	to	PART
iajs-3279	26	7	calculate	calculate	VERB
iajs-3279	26	8	the	the	DET
iajs-3279	26	9	thermodynamic	thermodynamic	ADJ
iajs-3279	26	10	parameters	parameter	NOUN
iajs-3279	26	11	∆h	∆h	PROPN
iajs-3279	26	12	,	,	PUNCT
iajs-3279	26	13	∆s	∆s	PROPN
iajs-3279	26	14	and	and	CCONJ
iajs-3279	26	15	∆g	∆g	PROPN
iajs-3279	26	16	then	then	ADV
iajs-3279	26	17	antioxidant	antioxidant	ADJ
iajs-3279	26	18	activity	activity	NOUN
iajs-3279	26	19	of	of	ADP
iajs-3279	26	20	these	these	DET
iajs-3279	26	21	compounds	compound	NOUN
iajs-3279	26	22	against	against	ADP
iajs-3279	26	23	the	the	DET
iajs-3279	26	24	dpph	dpph	NOUN
iajs-3279	26	25	radicals	radical	NOUN
iajs-3279	26	26	and	and	CCONJ
iajs-3279	26	27	compare	compare	VERB
iajs-3279	26	28	to	to	ADP
iajs-3279	26	29	those	those	PRON
iajs-3279	26	30	of	of	ADP
iajs-3279	26	31	the	the	DET
iajs-3279	26	32	natural	natural	ADJ
iajs-3279	26	33	antioxidant	antioxidant	ADJ
iajs-3279	26	34	gallic	gallic	NOUN
iajs-3279	26	35	acid	acid	NOUN
iajs-3279	26	36	.	.	PUNCT
iajs-3279	27	1	2	2	X
iajs-3279	27	2	.	.	X
iajs-3279	27	3	materials	material	NOUN
iajs-3279	27	4	and	and	CCONJ
iajs-3279	27	5	methods	method	NOUN
iajs-3279	27	6	materials	material	NOUN
iajs-3279	27	7	have	have	AUX
iajs-3279	27	8	been	be	AUX
iajs-3279	27	9	obtained	obtain	VERB
iajs-3279	27	10	from	from	ADP
iajs-3279	27	11	the	the	DET
iajs-3279	27	12	trading	trading	NOUN
iajs-3279	27	13	suppliers	supplier	NOUN
iajs-3279	27	14	(	(	PUNCT
iajs-3279	27	15	sigma	sigma	PROPN
iajs-3279	27	16	aldrich	aldrich	PROPN
iajs-3279	27	17	,	,	PUNCT
iajs-3279	27	18	merck	merck	PROPN
iajs-3279	27	19	,	,	PUNCT
iajs-3279	27	20	and	and	CCONJ
iajs-3279	27	21	others	other	NOUN
iajs-3279	27	22	)	)	PUNCT
iajs-3279	27	23	.	.	PUNCT
iajs-3279	28	1	the	the	DET
iajs-3279	28	2	eurovectormodel	eurovectormodel	PROPN
iajs-3279	28	3	ea/3000	ea/3000	PROPN
iajs-3279	28	4	,	,	PUNCT
iajs-3279	28	5	singlev3o	singlev3o	PROPN
iajs-3279	28	6	,	,	PUNCT
iajs-3279	28	7	has	have	AUX
iajs-3279	28	8	been	be	AUX
iajs-3279	28	9	employed	employ	VERB
iajs-3279	28	10	to	to	PART
iajs-3279	28	11	achieve	achieve	VERB
iajs-3279	28	12	(	(	PUNCT
iajs-3279	28	13	c.h.n.s	c.h.n.s	PROPN
iajs-3279	28	14	and	and	CCONJ
iajs-3279	28	15	o	o	NOUN
iajs-3279	28	16	)	)	PUNCT
iajs-3279	28	17	.	.	PUNCT
iajs-3279	29	1	mineral	mineral	NOUN
iajs-3279	29	2	-	-	PUNCT
iajs-3279	29	3	ions	ion	NOUN
iajs-3279	29	4	have	have	AUX
iajs-3279	29	5	determined	determine	VERB
iajs-3279	29	6	as	as	ADP
iajs-3279	29	7	m	m	NOUN
iajs-3279	29	8	-	-	NOUN
iajs-3279	29	9	o	o	NOUN
iajs-3279	29	10	using	use	VERB
iajs-3279	29	11	a	a	DET
iajs-3279	29	12	gravimetric	gravimetric	ADJ
iajs-3279	29	13	-	-	PUNCT
iajs-3279	29	14	approaches	approach	NOUN
iajs-3279	29	15	.	.	PUNCT
iajs-3279	30	1	molar	molar	ADJ
iajs-3279	30	2	conductivity	conductivity	NOUN
iajs-3279	30	3	has	have	AUX
iajs-3279	30	4	been	be	AUX
iajs-3279	30	5	estimated	estimate	VERB
iajs-3279	30	6	by	by	ADP
iajs-3279	30	7	operating	operate	VERB
iajs-3279	30	8	conduct	conduct	NOUN
iajs-3279	30	9	meter	meter	NOUN
iajs-3279	30	10	w	w	PROPN
iajs-3279	30	11	-	-	PUNCT
iajs-3279	30	12	t	t	PROPN
iajs-3279	30	13	-	-	PUNCT
iajs-3279	30	14	w	w	NOUN
iajs-3279	30	15	,	,	PUNCT
iajs-3279	30	16	at	at	ADP
iajs-3279	30	17	room	room	NOUN
iajs-3279	30	18	temperature	temperature	NOUN
iajs-3279	30	19	,	,	PUNCT
iajs-3279	30	20	1×10	1×10	NUM
iajs-3279	30	21	-	-	SYM
iajs-3279	30	22	3	3	NUM
iajs-3279	30	23	m.	m.	NOUN
iajs-3279	30	24	dmso	dmso	NOUN
iajs-3279	30	25	has	have	AUX
iajs-3279	30	26	been	be	AUX
iajs-3279	30	27	employed	employ	VERB
iajs-3279	30	28	as	as	ADP
iajs-3279	30	29	solvent	solvent	NOUN
iajs-3279	30	30	.	.	PUNCT
iajs-3279	31	1	mass	mass	PROPN
iajs-3279	31	2	spectra	spectra	NOUN
iajs-3279	31	3	for	for	ADP
iajs-3279	31	4	substances	substance	NOUN
iajs-3279	31	5	have	have	AUX
iajs-3279	31	6	been	be	AUX
iajs-3279	31	7	collected	collect	VERB
iajs-3279	31	8	using	use	VERB
iajs-3279	31	9	mass	mass	ADJ
iajs-3279	31	10	spectrometry	spectrometry	NOUN
iajs-3279	31	11	(	(	PUNCT
iajs-3279	31	12	ms	ms	PROPN
iajs-3279	31	13	)	)	PUNCT
iajs-3279	31	14	q	q	ADJ
iajs-3279	31	15	-	-	PUNCT
iajs-3279	31	16	p-50	p-50	ADJ
iajs-3279	31	17	-	-	PUNCT
iajs-3279	31	18	a	a	DET
iajs-3279	31	19	-	-	PUNCT
iajs-3279	31	20	d	d	NOUN
iajs-3279	31	21	-	-	PUNCT
iajs-3279	31	22	i	i	PRON
iajs-3279	31	23	analysis	analysis	NOUN
iajs-3279	31	24	shimadzu	shimadzu	ADJ
iajs-3279	31	25	qp	qp	ADP
iajs-3279	31	26	(	(	PUNCT
iajs-3279	31	27	e170ev	e170ev	PROPN
iajs-3279	31	28	)	)	PUNCT
iajs-3279	31	29	-2010	-2010	NOUN
iajs-3279	31	30	-	-	PUNCT
iajs-3279	31	31	pluss	pluss	ADJ
iajs-3279	31	32	spectrometer	spectrometer	NOUN
iajs-3279	31	33	.	.	PUNCT
iajs-3279	32	1	the	the	DET
iajs-3279	32	2	uv	uv	NOUN
iajs-3279	32	3	-	-	PUNCT
iajs-3279	32	4	visible	visible	ADJ
iajs-3279	32	5	absorption	absorption	NOUN
iajs-3279	32	6	spectra	spectra	NOUN
iajs-3279	32	7	were	be	AUX
iajs-3279	32	8	obtained	obtain	VERB
iajs-3279	32	9	using	use	VERB
iajs-3279	32	10	a	a	DET
iajs-3279	32	11	uv-1800	uv-1800	ADJ
iajs-3279	32	12	shimadzu	shimadzu	ADJ
iajs-3279	32	13	spectrophotometer	spectrophotometer	NOUN
iajs-3279	32	14	.	.	PUNCT
iajs-3279	33	1	the	the	DET
iajs-3279	33	2	brucker	brucker	NOUN
iajs-3279	33	3	(	(	PUNCT
iajs-3279	33	4	400	400	NUM
iajs-3279	33	5	mhz	mhz	NOUN
iajs-3279	33	6	)	)	PUNCT
iajs-3279	33	7	spectrometer	spectrometer	NOUN
iajs-3279	33	8	was	be	AUX
iajs-3279	33	9	used	use	VERB
iajs-3279	33	10	to	to	PART
iajs-3279	33	11	obtain	obtain	VERB
iajs-3279	33	12	the	the	DET
iajs-3279	33	13	1	1	NUM
iajs-3279	33	14	h	h	NOUN
iajs-3279	33	15	and	and	CCONJ
iajs-3279	33	16	13	13	NUM
iajs-3279	33	17	c	c	PROPN
iajs-3279	33	18	nmr	nmr	NOUN
iajs-3279	33	19	spectra	spectra	PROPN
iajs-3279	33	20	.	.	PUNCT
iajs-3279	34	1	the	the	DET
iajs-3279	34	2	ir	ir	PROPN
iajs-3279	34	3	prestige-21	prestige-21	PROPN
iajs-3279	34	4	was	be	AUX
iajs-3279	34	5	used	use	VERB
iajs-3279	34	6	to	to	PART
iajs-3279	34	7	investigate	investigate	VERB
iajs-3279	34	8	the	the	DET
iajs-3279	34	9	fourier	fourier	NOUN
iajs-3279	34	10	transform	transform	NOUN
iajs-3279	34	11	infrared	infrared	ADJ
iajs-3279	34	12	(	(	PUNCT
iajs-3279	34	13	ftir	ftir	PROPN
iajs-3279	34	14	)	)	PUNCT
iajs-3279	34	15	spectra	spectra	NOUN
iajs-3279	34	16	,	,	PUNCT
iajs-3279	34	17	where	where	SCONJ
iajs-3279	34	18	the	the	DET
iajs-3279	34	19	device	device	NOUN
iajs-3279	34	20	was	be	AUX
iajs-3279	34	21	used	use	VERB
iajs-3279	34	22	shimadzu	shimadzu	NOUN
iajs-3279	34	23	4000	4000	NUM
iajs-3279	34	24	-	-	SYM
iajs-3279	34	25	200	200	NUM
iajs-3279	34	26	cm	cm	NOUN
iajs-3279	34	27	-1	-1	PUNCT
iajs-3279	34	28	by	by	ADP
iajs-3279	34	29	csi	csi	PROPN
iajs-3279	34	30	and	and	CCONJ
iajs-3279	34	31	bruker	bruker	X
iajs-3279	34	32	4000500	4000500	NUM
iajs-3279	34	33	cm	cm	NOUN
iajs-3279	34	34	-1	-1	NOUN
iajs-3279	34	35	by	by	ADP
iajs-3279	34	36	kbr	kbr	PROPN
iajs-3279	34	37	.	.	PUNCT
iajs-3279	35	1	the	the	DET
iajs-3279	35	2	f.a.a	f.a.a	PROPN
iajs-3279	35	3	.	.	PROPN
iajs-3279	35	4	determined	determine	VERB
iajs-3279	35	5	the	the	DET
iajs-3279	35	6	metal	metal	NOUN
iajs-3279	35	7	percentage	percentage	NOUN
iajs-3279	35	8	.	.	PUNCT
iajs-3279	36	1	the	the	DET
iajs-3279	36	2	balancing	balance	VERB
iajs-3279	36	3	susceptibility	susceptibility	NOUN
iajs-3279	36	4	model	model	PROPN
iajs-3279	36	5	msr	msr	PROPN
iajs-3279	36	6	-	-	PUNCT
iajs-3279	36	7	mki	mki	PROPN
iajs-3279	36	8	utilized	utilize	VERB
iajs-3279	36	9	magnetic	magnetic	ADJ
iajs-3279	36	10	characteristics	characteristic	NOUN
iajs-3279	36	11	.	.	PUNCT
iajs-3279	37	1	perkin	perkin	PROPN
iajs-3279	37	2	-	-	PUNCT
iajs-3279	37	3	elmer	elmer	PROPN
iajs-3279	37	4	pyris	pyris	PROPN
iajs-3279	37	5	diamond	diamond	PROPN
iajs-3279	37	6	dsc	dsc	PROPN
iajs-3279	37	7	/	/	SYM
iajs-3279	37	8	tga	tga	PROPN
iajs-3279	37	9	was	be	AUX
iajs-3279	37	10	used	use	VERB
iajs-3279	37	11	for	for	ADP
iajs-3279	37	12	all	all	DET
iajs-3279	37	13	prior	prior	ADJ
iajs-3279	37	14	sorts	sort	NOUN
iajs-3279	37	15	of	of	ADP
iajs-3279	37	16	thermal	thermal	ADJ
iajs-3279	37	17	analysis	analysis	NOUN
iajs-3279	37	18	.	.	PUNCT
iajs-3279	38	1	the	the	DET
iajs-3279	38	2	chlorine	chlorine	NOUN
iajs-3279	38	3	content	content	NOUN
iajs-3279	38	4	of	of	ADP
iajs-3279	38	5	the	the	DET
iajs-3279	38	6	prepared	prepared	ADJ
iajs-3279	38	7	complexes	complex	NOUN
iajs-3279	38	8	was	be	AUX
iajs-3279	38	9	measured	measure	VERB
iajs-3279	38	10	using	use	VERB
iajs-3279	38	11	moore	moore	PROPN
iajs-3279	38	12	's	's	PART
iajs-3279	38	13	method	method	NOUN
iajs-3279	38	14	686	686	ADV
iajs-3279	38	15	-	-	PUNCT
iajs-3279	38	16	titro	titro	VERB
iajs-3279	38	17	processor-665	processor-665	NOUN
iajs-3279	38	18	.	.	PUNCT
iajs-3279	39	1	the	the	DET
iajs-3279	39	2	magnetic	magnetic	ADJ
iajs-3279	39	3	sensitivity	sensitivity	NOUN
iajs-3279	39	4	was	be	AUX
iajs-3279	39	5	also	also	ADV
iajs-3279	39	6	measured	measure	VERB
iajs-3279	39	7	using	use	VERB
iajs-3279	39	8	the	the	DET
iajs-3279	39	9	magnetic	magnetic	ADJ
iajs-3279	39	10	susceptibility	susceptibility	NOUN
iajs-3279	39	11	balance	balance	NOUN
iajs-3279	39	12	model	model	NOUN
iajs-3279	39	13	(	(	PUNCT
iajs-3279	39	14	msb	msb	PROPN
iajs-3279	39	15	-	-	PUNCT
iajs-3279	39	16	mki	mki	PROPN
iajs-3279	39	17	)	)	PUNCT
iajs-3279	39	18	device	device	NOUN
iajs-3279	39	19	.	.	PUNCT
iajs-3279	40	1	2.1	2.1	NUM
iajs-3279	40	2	synthesis	synthesis	NOUN
iajs-3279	40	3	of	of	ADP
iajs-3279	40	4	azo	azo	NOUN
iajs-3279	40	5	dye	dye	PROPN
iajs-3279	40	6	ligand	ligand	NOUN
iajs-3279	40	7	[	[	X
iajs-3279	40	8	4-(3	4-(3	PROPN
iajs-3279	40	9	-	-	PUNCT
iajs-3279	40	10	acetyl-2,4,6	acetyl-2,4,6	NOUN
iajs-3279	40	11	-	-	PUNCT
iajs-3279	40	12	trihydroxy	trihydroxy	NOUN
iajs-3279	40	13	-	-	PUNCT
iajs-3279	40	14	phenylazo)-n-(5	phenylazo)-n-(5	NOUN
iajs-3279	40	15	-	-	PUNCT
iajs-3279	40	16	methyl	methyl	NOUN
iajs-3279	40	17	–	–	PUNCT
iajs-3279	40	18	isoxazol-3	isoxazol-3	NUM
iajs-3279	40	19	-	-	PUNCT
iajs-3279	40	20	yl)–benzenesulfonamide	yl)–benzenesulfonamide	NOUN
iajs-3279	40	21	]	]	X
iajs-3279	40	22	sulfamethoxazole	sulfamethoxazole	NOUN
iajs-3279	40	23	(	(	PUNCT
iajs-3279	40	24	1	1	NUM
iajs-3279	40	25	g	g	NOUN
iajs-3279	40	26	,	,	PUNCT
iajs-3279	40	27	3.948	3.948	NUM
iajs-3279	40	28	mmol	mmol	NOUN
iajs-3279	40	29	)	)	PUNCT
iajs-3279	40	30	was	be	AUX
iajs-3279	40	31	dissolved	dissolve	VERB
iajs-3279	40	32	in	in	ADP
iajs-3279	40	33	(	(	PUNCT
iajs-3279	40	34	2	2	NUM
iajs-3279	40	35	ml	ml	NOUN
iajs-3279	40	36	of	of	ADP
iajs-3279	40	37	hcl	hcl	PROPN
iajs-3279	40	38	and	and	CCONJ
iajs-3279	40	39	10	10	NUM
iajs-3279	40	40	ml	ml	NOUN
iajs-3279	40	41	of	of	ADP
iajs-3279	40	42	ethanol	ethanol	NOUN
iajs-3279	40	43	)	)	PUNCT
iajs-3279	40	44	at	at	ADP
iajs-3279	40	45	0	0	NUM
iajs-3279	40	46	-	-	SYM
iajs-3279	40	47	5	5	NUM
iajs-3279	40	48	°	°	NOUN
iajs-3279	40	49	c	c	NOUN
iajs-3279	40	50	,	,	PUNCT
iajs-3279	40	51	gradually	gradually	ADV
iajs-3279	40	52	added	add	VERB
iajs-3279	40	53	(	(	PUNCT
iajs-3279	40	54	10	10	NUM
iajs-3279	40	55	%	%	NOUN
iajs-3279	40	56	,	,	PUNCT
iajs-3279	40	57	1	1	NUM
iajs-3279	40	58	g	g	NOUN
iajs-3279	40	59	,	,	PUNCT
iajs-3279	40	60	14.49	14.49	NUM
iajs-3279	40	61	mmol	mmol	NOUN
iajs-3279	40	62	)	)	PUNCT
iajs-3279	40	63	nano2	nano2	NOUN
iajs-3279	40	64	stirred	stir	VERB
iajs-3279	40	65	for	for	ADP
iajs-3279	40	66	approximately	approximately	ADV
iajs-3279	40	67	45	45	NUM
iajs-3279	40	68	minutes	minute	NOUN
iajs-3279	40	69	,	,	PUNCT
iajs-3279	40	70	then	then	ADV
iajs-3279	40	71	,	,	PUNCT
iajs-3279	40	72	the	the	DET
iajs-3279	40	73	(	(	PUNCT
iajs-3279	40	74	0.663	0.663	NUM
iajs-3279	40	75	g	g	NOUN
iajs-3279	40	76	,	,	PUNCT
iajs-3279	40	77	3.948	3.948	NUM
iajs-3279	40	78	mmol	mmol	NOUN
iajs-3279	40	79	)	)	PUNCT
iajs-3279	40	80	of	of	ADP
iajs-3279	40	81	1-(2,4,6	1-(2,4,6	NUM
iajs-3279	40	82	-	-	PUNCT
iajs-3279	40	83	trihydroxy	trihydroxy	NOUN
iajs-3279	40	84	-	-	PUNCT
iajs-3279	40	85	phenyl)-ethanone	phenyl)-ethanone	NOUN
iajs-3279	40	86	dissolved	dissolve	VERB
iajs-3279	40	87	in	in	ADP
iajs-3279	40	88	15	15	NUM
iajs-3279	40	89	ml	ml	NOUN
iajs-3279	40	90	of	of	ADP
iajs-3279	40	91	ethanol	ethanol	NOUN
iajs-3279	40	92	was	be	AUX
iajs-3279	40	93	added	add	VERB
iajs-3279	40	94	.	.	PUNCT
iajs-3279	41	1	the	the	DET
iajs-3279	41	2	change	change	NOUN
iajs-3279	41	3	to	to	ADP
iajs-3279	41	4	a	a	DET
iajs-3279	41	5	dark	dark	ADV
iajs-3279	41	6	-	-	PUNCT
iajs-3279	41	7	colored	color	VERB
iajs-3279	41	8	solution	solution	NOUN
iajs-3279	41	9	was	be	AUX
iajs-3279	41	10	observed	observe	VERB
iajs-3279	41	11	after	after	ADP
iajs-3279	41	12	stirring	stir	VERB
iajs-3279	41	13	for	for	ADP
iajs-3279	41	14	30	30	NUM
iajs-3279	41	15	minutes	minute	NOUN
iajs-3279	41	16	.	.	PUNCT
iajs-3279	42	1	this	this	DET
iajs-3279	42	2	product	product	NOUN
iajs-3279	42	3	is	be	AUX
iajs-3279	42	4	collected	collect	VERB
iajs-3279	42	5	after	after	ADP
iajs-3279	42	6	being	be	AUX
iajs-3279	42	7	filtered	filter	VERB
iajs-3279	42	8	and	and	CCONJ
iajs-3279	42	9	dried	dry	VERB
iajs-3279	42	10	.	.	PUNCT
iajs-3279	43	1	its	its	PRON
iajs-3279	43	2	melting	melting	NOUN
iajs-3279	43	3	point	point	NOUN
iajs-3279	43	4	was	be	AUX
iajs-3279	43	5	(	(	PUNCT
iajs-3279	43	6	146148)	146148)	NUM
iajs-3279	43	7	°	°	ADP
iajs-3279	43	8	c	c	NOUN
iajs-3279	43	9	and	and	CCONJ
iajs-3279	43	10	the	the	DET
iajs-3279	43	11	color	color	NOUN
iajs-3279	43	12	of	of	ADP
iajs-3279	43	13	precipitate	precipitate	NOUN
iajs-3279	43	14	was	be	AUX
iajs-3279	43	15	orange	orange	ADJ
iajs-3279	43	16	,	,	PUNCT
iajs-3279	43	17	its	its	PRON
iajs-3279	43	18	yield	yield	NOUN
iajs-3279	43	19	was	be	AUX
iajs-3279	43	20	93	93	NUM
iajs-3279	43	21	%	%	NOUN
iajs-3279	43	22	.	.	PUNCT
iajs-3279	44	1	scheme	scheme	NOUN
iajs-3279	44	2	1	1	NUM
iajs-3279	44	3	shows	show	VERB
iajs-3279	44	4	the	the	DET
iajs-3279	44	5	formation	formation	NOUN
iajs-3279	44	6	of	of	ADP
iajs-3279	44	7	the	the	DET
iajs-3279	44	8	ligand	ligand	ADJ
iajs-3279	44	9	azo	azo	PROPN
iajs-3279	44	10	dye	dye	PROPN
iajs-3279	44	11	.	.	PUNCT
iajs-3279	45	1	the	the	DET
iajs-3279	45	2	ligand	ligand	NOUN
iajs-3279	45	3	showed	show	VERB
iajs-3279	45	4	bands	band	NOUN
iajs-3279	45	5	at	at	ADP
iajs-3279	45	6	3503	3503	NUM
iajs-3279	45	7	,	,	PUNCT
iajs-3279	45	8	3281,3014	3281,3014	NUM
iajs-3279	45	9	,	,	PUNCT
iajs-3279	45	10	2979	2979	NUM
iajs-3279	45	11	,	,	PUNCT
iajs-3279	45	12	1635	1635	NUM
iajs-3279	45	13	and	and	CCONJ
iajs-3279	45	14	(	(	PUNCT
iajs-3279	45	15	1088	1088	NUM
iajs-3279	45	16	-	-	SYM
iajs-3279	45	17	1015	1015	NUM
iajs-3279	45	18	)	)	PUNCT
iajs-3279	45	19	cm	cm	NOUN
iajs-3279	45	20	-1	-1	ADP
iajs-3279	45	21	that	that	PRON
iajs-3279	45	22	were	be	AUX
iajs-3279	45	23	ascribed	ascribe	VERB
iajs-3279	45	24	to	to	ADP
iajs-3279	45	25	the	the	DET
iajs-3279	45	26	ν	ν	NOUN
iajs-3279	45	27	(	(	PUNCT
iajs-3279	45	28	oh	oh	INTJ
iajs-3279	45	29	)	)	PUNCT
iajs-3279	45	30	phenolic	phenolic	NOUN
iajs-3279	45	31	,	,	PUNCT
iajs-3279	45	32	ν	ν	X
iajs-3279	45	33	(	(	PUNCT
iajs-3279	45	34	nh	nh	PROPN
iajs-3279	45	35	)	)	PUNCT
iajs-3279	45	36	,	,	PUNCT
iajs-3279	45	37	ν	ν	X
iajs-3279	45	38	(	(	PUNCT
iajs-3279	45	39	c	c	NOUN
iajs-3279	45	40	-	-	PUNCT
iajs-3279	45	41	h	h	NOUN
iajs-3279	45	42	)	)	PUNCT
iajs-3279	45	43	aromatic	aromatic	NOUN
iajs-3279	45	44	,	,	PUNCT
iajs-3279	45	45	ν	ν	X
iajs-3279	45	46	(	(	PUNCT
iajs-3279	45	47	c	c	NOUN
iajs-3279	45	48	-	-	PUNCT
iajs-3279	45	49	h	h	NOUN
iajs-3279	45	50	)	)	PUNCT
iajs-3279	45	51	aliphatic	aliphatic	ADJ
iajs-3279	45	52	,	,	PUNCT
iajs-3279	45	53	ν	ν	X
iajs-3279	45	54	(	(	PUNCT
iajs-3279	45	55	c	c	NOUN
iajs-3279	45	56	=	=	NOUN
iajs-3279	45	57	o	o	NOUN
iajs-3279	45	58	)	)	PUNCT
iajs-3279	45	59	and	and	CCONJ
iajs-3279	45	60	ν	ν	X
iajs-3279	45	61	(	(	PUNCT
iajs-3279	45	62	so2	so2	PROPN
iajs-3279	45	63	)	)	PUNCT
iajs-3279	45	64	.	.	PUNCT
iajs-3279	46	1	the	the	DET
iajs-3279	46	2	infrared	infrared	PROPN
iajs-3279	46	3	spectrum	spectrum	NOUN
iajs-3279	46	4	of	of	ADP
iajs-3279	46	5	the	the	DET
iajs-3279	46	6	ligand	ligand	NOUN
iajs-3279	46	7	showed	show	VERB
iajs-3279	46	8	a	a	DET
iajs-3279	46	9	medium	medium	ADJ
iajs-3279	46	10	-	-	PUNCT
iajs-3279	46	11	intensity	intensity	NOUN
iajs-3279	46	12	ihjpas	ihjpa	NOUN
iajs-3279	46	13	.	.	PUNCT
iajs-3279	47	1	37(2)2024	37(2)2024	NUM
iajs-3279	47	2	245	245	NUM
iajs-3279	47	3	stretch	stretch	NOUN
iajs-3279	47	4	band	band	NOUN
iajs-3279	47	5	at	at	ADP
iajs-3279	47	6	a	a	DET
iajs-3279	47	7	frequency	frequency	NOUN
iajs-3279	47	8	of	of	ADP
iajs-3279	47	9	1485	1485	NUM
iajs-3279	47	10	cm	cm	NOUN
iajs-3279	47	11	-1	-1	NOUN
iajs-3279	47	12	,	,	PUNCT
iajs-3279	47	13	which	which	PRON
iajs-3279	47	14	was	be	AUX
iajs-3279	47	15	attributed	attribute	VERB
iajs-3279	47	16	to	to	ADP
iajs-3279	47	17	the	the	DET
iajs-3279	47	18	vibrational	vibrational	ADJ
iajs-3279	47	19	frequencies	frequency	NOUN
iajs-3279	47	20	of	of	ADP
iajs-3279	47	21	the	the	DET
iajs-3279	47	22	double	double	ADJ
iajs-3279	47	23	bond	bond	NOUN
iajs-3279	47	24	n	n	CCONJ
iajs-3279	47	25	=	=	NOUN
iajs-3279	47	26	n.	n.	NOUN
iajs-3279	47	27	the	the	DET
iajs-3279	47	28	uv	uv	NOUN
iajs-3279	47	29	-	-	PUNCT
iajs-3279	47	30	vis	vis	X
iajs-3279	47	31	spectrum	spectrum	NOUN
iajs-3279	47	32	exhibits	exhibit	VERB
iajs-3279	47	33	strong	strong	ADJ
iajs-3279	47	34	absorbance	absorbance	NOUN
iajs-3279	47	35	at	at	ADP
iajs-3279	47	36	(	(	PUNCT
iajs-3279	47	37	286	286	NUM
iajs-3279	47	38	nm	nm	NOUN
iajs-3279	47	39	,	,	PUNCT
iajs-3279	47	40	34965.04	34965.04	NUM
iajs-3279	47	41	cm	cm	NOUN
iajs-3279	47	42	-1	-1	PUNCT
iajs-3279	47	43	)	)	PUNCT
iajs-3279	47	44	,	,	PUNCT
iajs-3279	47	45	ascribed	ascribe	VERB
iajs-3279	47	46	to	to	ADP
iajs-3279	47	47	the	the	DET
iajs-3279	47	48	π	π	PROPN
iajs-3279	47	49	⟶	⟶	NOUN
iajs-3279	47	50	π	π	PROPN
iajs-3279	47	51	*	*	PUNCT
iajs-3279	47	52	transition	transition	NOUN
iajs-3279	47	53	and	and	CCONJ
iajs-3279	47	54	peak	peak	NOUN
iajs-3279	47	55	at	at	ADP
iajs-3279	47	56	(	(	PUNCT
iajs-3279	47	57	392	392	NUM
iajs-3279	47	58	nm	nm	NOUN
iajs-3279	47	59	,	,	PUNCT
iajs-3279	47	60	25510.20	25510.20	NUM
iajs-3279	47	61	cm	cm	NOUN
iajs-3279	47	62	-1	-1	PUNCT
iajs-3279	47	63	)	)	PUNCT
iajs-3279	47	64	attributed	attribute	VERB
iajs-3279	47	65	to	to	ADP
iajs-3279	47	66	the	the	DET
iajs-3279	47	67	n⟶π	n⟶π	NOUN
iajs-3279	47	68	*	*	PROPN
iajs-3279	47	69	transition	transition	NOUN
iajs-3279	47	70	peak	peak	NOUN
iajs-3279	47	71	[	[	X
iajs-3279	47	72	18	18	NUM
iajs-3279	47	73	]	]	PUNCT
iajs-3279	47	74	.	.	PUNCT
iajs-3279	48	1	the	the	DET
iajs-3279	48	2	1	1	NUM
iajs-3279	48	3	h	h	NOUN
iajs-3279	48	4	-	-	PUNCT
iajs-3279	48	5	nmr	nmr	NOUN
iajs-3279	48	6	and	and	CCONJ
iajs-3279	48	7	13	13	NUM
iajs-3279	48	8	c	c	NOUN
iajs-3279	48	9	-	-	PUNCT
iajs-3279	48	10	nmr	nmr	NOUN
iajs-3279	48	11	spectra	spectra	NOUN
iajs-3279	48	12	of	of	ADP
iajs-3279	48	13	newazo	newazo	PROPN
iajs-3279	48	14	,	,	PUNCT
iajs-3279	48	15	which	which	PRON
iajs-3279	48	16	can	can	AUX
iajs-3279	48	17	be	be	AUX
iajs-3279	48	18	seen	see	VERB
iajs-3279	48	19	in	in	ADP
iajs-3279	48	20	figure	figure	NOUN
iajs-3279	48	21	1	1	NUM
iajs-3279	48	22	,	,	PUNCT
iajs-3279	48	23	demonstrate	demonstrate	VERB
iajs-3279	48	24	the	the	DET
iajs-3279	48	25	chemical	chemical	ADJ
iajs-3279	48	26	shifts	shift	NOUN
iajs-3279	48	27	of	of	ADP
iajs-3279	48	28	these	these	DET
iajs-3279	48	29	spectra	spectra	NOUN
iajs-3279	48	30	.	.	PROPN
iajs-3279	48	31	1	1	NUM
iajs-3279	48	32	h	h	NOUN
iajs-3279	48	33	-	-	PUNCT
iajs-3279	48	34	nmr	nmr	NOUN
iajs-3279	48	35	(	(	PUNCT
iajs-3279	48	36	dmso	dmso	NOUN
iajs-3279	48	37	-	-	PUNCT
iajs-3279	48	38	d6	d6	NOUN
iajs-3279	48	39	,	,	PUNCT
iajs-3279	48	40	ppm):1.92	ppm):1.92	PROPN
iajs-3279	48	41	ppm	ppm	NOUN
iajs-3279	48	42	(	(	PUNCT
iajs-3279	48	43	3h	3h	NUM
iajs-3279	48	44	,	,	PUNCT
iajs-3279	48	45	s	s	X
iajs-3279	48	46	,	,	PUNCT
iajs-3279	48	47	ch3	ch3	PROPN
iajs-3279	48	48	)	)	PUNCT
iajs-3279	48	49	,	,	PUNCT
iajs-3279	48	50	2.08	2.08	NUM
iajs-3279	48	51	ppm	ppm	NOUN
iajs-3279	48	52	(	(	PUNCT
iajs-3279	48	53	3h	3h	NUM
iajs-3279	48	54	,	,	PUNCT
iajs-3279	48	55	s	s	NOUN
iajs-3279	48	56	,	,	PUNCT
iajs-3279	48	57	ch3co	ch3co	ADJ
iajs-3279	48	58	)	)	PUNCT
iajs-3279	48	59	,	,	PUNCT
iajs-3279	48	60	ch3,6.43	ch3,6.43	NOUN
iajs-3279	48	61	ppm	ppm	NOUN
iajs-3279	48	62	,	,	PUNCT
iajs-3279	48	63	(	(	PUNCT
iajs-3279	48	64	1h	1h	NUM
iajs-3279	48	65	,	,	PUNCT
iajs-3279	48	66	s	s	X
iajs-3279	48	67	,	,	PUNCT
iajs-3279	48	68	c	c	NOUN
iajs-3279	48	69	-	-	PUNCT
iajs-3279	48	70	h	h	NOUN
iajs-3279	48	71	)	)	PUNCT
iajs-3279	48	72	isoxazole	isoxazole	NOUN
iajs-3279	48	73	ring	ring	NOUN
iajs-3279	48	74	[	[	X
iajs-3279	48	75	the	the	DET
iajs-3279	48	76	rest	rest	NOUN
iajs-3279	48	77	of	of	ADP
iajs-3279	48	78	the	the	DET
iajs-3279	48	79	1	1	NUM
iajs-3279	48	80	hnmr	hnmr	NOUN
iajs-3279	48	81	signals	signal	NOUN
iajs-3279	48	82	are	be	AUX
iajs-3279	48	83	arranged	arrange	VERB
iajs-3279	48	84	in	in	ADP
iajs-3279	48	85	this	this	DET
iajs-3279	48	86	manner	manner	NOUN
iajs-3279	48	87	,	,	PUNCT
iajs-3279	48	88	6.77	6.77	NUM
iajs-3279	48	89	ppm	ppm	NOUN
iajs-3279	48	90	,	,	PUNCT
iajs-3279	48	91	(	(	PUNCT
iajs-3279	48	92	1h	1h	NUM
iajs-3279	48	93	,	,	PUNCT
iajs-3279	48	94	s	s	NOUN
iajs-3279	48	95	,	,	PUNCT
iajs-3279	48	96	ch	ch	NOUN
iajs-3279	48	97	aromatic	aromatic	NOUN
iajs-3279	48	98	)	)	PUNCT
iajs-3279	48	99	beside	beside	ADP
iajs-3279	48	100	oh	oh	INTJ
iajs-3279	48	101	,	,	PUNCT
iajs-3279	48	102	(	(	PUNCT
iajs-3279	48	103	7.26	7.26	NUM
iajs-3279	48	104	-	-	SYM
iajs-3279	48	105	8.1	8.1	NUM
iajs-3279	48	106	)	)	PUNCT
iajs-3279	48	107	ppm	ppm	NOUN
iajs-3279	48	108	(	(	PUNCT
iajs-3279	48	109	4h	4h	NUM
iajs-3279	48	110	,	,	PUNCT
iajs-3279	48	111	dd	dd	NOUN
iajs-3279	48	112	,	,	PUNCT
iajs-3279	48	113	aromatic	aromatic	ADJ
iajs-3279	48	114	)	)	PUNCT
iajs-3279	48	115	,	,	PUNCT
iajs-3279	48	116	8.11	8.11	NUM
iajs-3279	48	117	ppm	ppm	NOUN
iajs-3279	48	118	(	(	PUNCT
iajs-3279	48	119	1h	1h	NUM
iajs-3279	48	120	,	,	PUNCT
iajs-3279	48	121	s	s	X
iajs-3279	48	122	,	,	PUNCT
iajs-3279	48	123	nh	nh	PROPN
iajs-3279	48	124	)	)	PUNCT
iajs-3279	48	125	,	,	PUNCT
iajs-3279	48	126	8.74	8.74	NUM
iajs-3279	48	127	ppm	ppm	NOUN
iajs-3279	48	128	(	(	PUNCT
iajs-3279	48	129	1h)s	1h)s	NUM
iajs-3279	48	130	,	,	PUNCT
iajs-3279	48	131	(	(	PUNCT
iajs-3279	48	132	oh	oh	INTJ
iajs-3279	48	133	)	)	PUNCT
iajs-3279	48	134	phenolic	phenolic	NOUN
iajs-3279	48	135	beside	beside	ADV
iajs-3279	48	136	(	(	PUNCT
iajs-3279	48	137	n	n	CCONJ
iajs-3279	48	138	=	=	NUM
iajs-3279	48	139	n	n	NUM
iajs-3279	48	140	)	)	PUNCT
iajs-3279	48	141	,	,	PUNCT
iajs-3279	48	142	8.75	8.75	NUM
iajs-3279	48	143	ppm	ppm	NOUN
iajs-3279	48	144	,	,	PUNCT
iajs-3279	48	145	(	(	PUNCT
iajs-3279	48	146	1h)s	1h)s	NUM
iajs-3279	48	147	(	(	PUNCT
iajs-3279	48	148	oh	oh	INTJ
iajs-3279	48	149	)	)	PUNCT
iajs-3279	48	150	phenolic	phenolic	NOUN
iajs-3279	48	151	beside	beside	ADV
iajs-3279	48	152	(	(	PUNCT
iajs-3279	48	153	n	n	CCONJ
iajs-3279	48	154	=	=	SYM
iajs-3279	48	155	n	n	CCONJ
iajs-3279	48	156	)	)	PUNCT
iajs-3279	48	157	and	and	CCONJ
iajs-3279	48	158	it	it	PRON
iajs-3279	48	159	belongs	belong	VERB
iajs-3279	48	160	to	to	ADP
iajs-3279	48	161	nh	nh	PROPN
iajs-3279	48	162	,	,	PUNCT
iajs-3279	48	163	(	(	PUNCT
iajs-3279	48	164	oh	oh	INTJ
iajs-3279	48	165	)	)	PUNCT
iajs-3279	48	166	phenolic	phenolic	NOUN
iajs-3279	48	167	beside	beside	ADP
iajs-3279	48	168	coch3	coch3	PROPN
iajs-3279	48	169	.	.	PUNCT
iajs-3279	49	1	13	13	NUM
iajs-3279	49	2	c	c	NOUN
iajs-3279	49	3	-	-	PUNCT
iajs-3279	49	4	nmr	nmr	NOUN
iajs-3279	49	5	:	:	PUNCT
iajs-3279	49	6	33.62(c1	33.62(c1	NUM
iajs-3279	49	7	)	)	PUNCT
iajs-3279	49	8	,	,	PUNCT
iajs-3279	49	9	49.71(c18	49.71(c18	NUM
iajs-3279	49	10	)	)	PUNCT
iajs-3279	49	11	,	,	PUNCT
iajs-3279	49	12	106.90(c13	106.90(c13	NUM
iajs-3279	49	13	)	)	PUNCT
iajs-3279	49	14	,	,	PUNCT
iajs-3279	49	15	118.20(c3	118.20(c3	NUM
iajs-3279	49	16	)	)	PUNCT
iajs-3279	49	17	,	,	PUNCT
iajs-3279	49	18	127.48(c15	127.48(c15	NUM
iajs-3279	49	19	)	)	PUNCT
iajs-3279	49	20	,	,	PUNCT
iajs-3279	49	21	132.21(c11	132.21(c11	NOUN
iajs-3279	49	22	)	)	PUNCT
iajs-3279	49	23	,	,	PUNCT
iajs-3279	49	24	137.27(c9	137.27(c9	NUM
iajs-3279	49	25	)	)	PUNCT
iajs-3279	49	26	,	,	PUNCT
iajs-3279	49	27	145.00(c7	145.00(c7	NUM
iajs-3279	49	28	)	)	PUNCT
iajs-3279	49	29	,	,	PUNCT
iajs-3279	49	30	148.96(c10	148.96(c10	NUM
iajs-3279	49	31	)	)	PUNCT
iajs-3279	49	32	,	,	PUNCT
iajs-3279	49	33	155.15(c6	155.15(c6	NUM
iajs-3279	49	34	)	)	PUNCT
iajs-3279	49	35	,	,	PUNCT
iajs-3279	49	36	157.23(c5	157.23(c5	NUM
iajs-3279	49	37	)	)	PUNCT
iajs-3279	49	38	,	,	PUNCT
iajs-3279	49	39	165.30(c4	165.30(c4	NUM
iajs-3279	49	40	)	)	PUNCT
iajs-3279	49	41	,	,	PUNCT
iajs-3279	49	42	169.75(c16	169.75(c16	NUM
iajs-3279	49	43	)	)	PUNCT
iajs-3279	49	44	,	,	PUNCT
iajs-3279	49	45	172.24(c8	172.24(c8	NUM
iajs-3279	49	46	)	)	PUNCT
iajs-3279	49	47	,	,	PUNCT
iajs-3279	49	48	178.10(c12	178.10(c12	NUM
iajs-3279	49	49	)	)	PUNCT
iajs-3279	49	50	,	,	PUNCT
iajs-3279	49	51	181.97(c2	181.97(c2	NUM
iajs-3279	49	52	)	)	PUNCT
iajs-3279	49	53	,	,	PUNCT
iajs-3279	49	54	189.75(c14	189.75(c14	NUM
iajs-3279	49	55	)	)	PUNCT
iajs-3279	49	56	and	and	CCONJ
iajs-3279	49	57	196.20	196.20	NUM
iajs-3279	49	58	(	(	PUNCT
iajs-3279	49	59	c17	c17	NOUN
iajs-3279	49	60	)	)	PUNCT
iajs-3279	50	1	[	[	X
iajs-3279	50	2	19,20	19,20	X
iajs-3279	50	3	]	]	PUNCT
iajs-3279	50	4	.	.	PUNCT
iajs-3279	51	1	lc	lc	PROPN
iajs-3279	51	2	mass	mass	PROPN
iajs-3279	51	3	spectrum	spectrum	PROPN
iajs-3279	51	4	was	be	AUX
iajs-3279	51	5	tested	test	VERB
iajs-3279	51	6	using	use	VERB
iajs-3279	51	7	an	an	DET
iajs-3279	51	8	lc	lc	NOUN
iajs-3279	51	9	-	-	PUNCT
iajs-3279	51	10	mass	mass	NOUN
iajs-3279	51	11	device	device	NOUN
iajs-3279	51	12	;	;	PUNCT
iajs-3279	51	13	this	this	DET
iajs-3279	51	14	approach	approach	NOUN
iajs-3279	51	15	is	be	AUX
iajs-3279	51	16	one	one	NUM
iajs-3279	51	17	of	of	ADP
iajs-3279	51	18	the	the	DET
iajs-3279	51	19	most	most	ADV
iajs-3279	51	20	essential	essential	ADJ
iajs-3279	51	21	approaches	approach	NOUN
iajs-3279	51	22	in	in	ADP
iajs-3279	51	23	characterization	characterization	NOUN
iajs-3279	51	24	and	and	CCONJ
iajs-3279	51	25	complementary	complementary	ADJ
iajs-3279	51	26	to	to	ADP
iajs-3279	51	27	the	the	DET
iajs-3279	51	28	rest	rest	NOUN
iajs-3279	51	29	of	of	ADP
iajs-3279	51	30	the	the	DET
iajs-3279	51	31	approaches	approach	NOUN
iajs-3279	51	32	by	by	ADP
iajs-3279	51	33	which	which	PRON
iajs-3279	51	34	the	the	DET
iajs-3279	51	35	molecular	molecular	ADJ
iajs-3279	51	36	weight	weight	NOUN
iajs-3279	51	37	of	of	ADP
iajs-3279	51	38	the	the	DET
iajs-3279	51	39	compound	compound	NOUN
iajs-3279	51	40	is	be	AUX
iajs-3279	51	41	estimated	estimate	VERB
iajs-3279	51	42	according	accord	VERB
iajs-3279	51	43	to	to	ADP
iajs-3279	51	44	the	the	DET
iajs-3279	51	45	relation	relation	NOUN
iajs-3279	51	46	(	(	PUNCT
iajs-3279	51	47	m	m	PROPN
iajs-3279	51	48	/	/	SYM
iajs-3279	51	49	z	z	NOUN
iajs-3279	51	50	)	)	PUNCT
iajs-3279	51	51	.	.	PUNCT
iajs-3279	52	1	mass	mass	ADJ
iajs-3279	52	2	information	information	NOUN
iajs-3279	52	3	of	of	ADP
iajs-3279	52	4	the	the	DET
iajs-3279	52	5	ligand	ligand	NOUN
iajs-3279	52	6	in	in	ADP
iajs-3279	52	7	scheme	scheme	NOUN
iajs-3279	52	8	1	1	NUM
iajs-3279	52	9	shows	show	VERB
iajs-3279	52	10	the	the	DET
iajs-3279	52	11	fragmentation	fragmentation	NOUN
iajs-3279	52	12	pattern	pattern	NOUN
iajs-3279	52	13	and	and	CCONJ
iajs-3279	52	14	the	the	DET
iajs-3279	52	15	extracted	extract	VERB
iajs-3279	52	16	mass	mass	NOUN
iajs-3279	52	17	for	for	ADP
iajs-3279	52	18	each	each	DET
iajs-3279	52	19	pattern	pattern	NOUN
iajs-3279	52	20	.	.	PUNCT
iajs-3279	53	1	it	it	PRON
iajs-3279	53	2	can	can	AUX
iajs-3279	53	3	be	be	AUX
iajs-3279	53	4	clearly	clearly	ADV
iajs-3279	53	5	observed	observe	VERB
iajs-3279	53	6	the	the	DET
iajs-3279	53	7	molecular	molecular	ADJ
iajs-3279	53	8	ion	ion	NOUN
iajs-3279	53	9	peak	peak	NOUN
iajs-3279	53	10	[	[	X
iajs-3279	53	11	m	m	X
iajs-3279	53	12	]	]	X
iajs-3279	53	13	+	+	CCONJ
iajs-3279	53	14	for	for	ADP
iajs-3279	53	15	the	the	DET
iajs-3279	53	16	fragment	fragment	ADJ
iajs-3279	53	17	c14h10n2o6s•+	c14h10n2o6s•+	NOUN
iajs-3279	53	18	and	and	CCONJ
iajs-3279	53	19	its	its	PRON
iajs-3279	53	20	relative	relative	ADJ
iajs-3279	53	21	abundance	abundance	NOUN
iajs-3279	53	22	of	of	ADP
iajs-3279	53	23	about	about	ADV
iajs-3279	53	24	66	66	NUM
iajs-3279	53	25	%	%	NOUN
iajs-3279	53	26	in	in	ADP
iajs-3279	53	27	figure	figure	NOUN
iajs-3279	53	28	2	2	NUM
iajs-3279	53	29	,	,	PUNCT
iajs-3279	53	30	in	in	ADP
iajs-3279	53	31	addition	addition	NOUN
iajs-3279	53	32	to	to	ADP
iajs-3279	53	33	other	other	ADJ
iajs-3279	53	34	abundances	abundance	NOUN
iajs-3279	53	35	for	for	ADP
iajs-3279	53	36	the	the	DET
iajs-3279	53	37	rest	rest	NOUN
iajs-3279	53	38	of	of	ADP
iajs-3279	53	39	peaks	peak	NOUN
iajs-3279	53	40	including	include	VERB
iajs-3279	53	41	c8h8n2o4	c8h8n2o4	PROPN
iajs-3279	53	42	•+	•+	PROPN
iajs-3279	53	43	,	,	PUNCT
iajs-3279	53	44	c6h4o2s	c6h4o2s	PROPN
iajs-3279	53	45	•+	•+	PROPN
iajs-3279	53	46	and	and	CCONJ
iajs-3279	53	47	c4h4n2o	c4h4n2o	PROPN
iajs-3279	53	48	•+	•+	PROPN
iajs-3279	53	49	,	,	PUNCT
iajs-3279	53	50	corresponded	correspond	VERB
iajs-3279	53	51	the	the	DET
iajs-3279	53	52	next	next	ADJ
iajs-3279	53	53	abundances	abundance	NOUN
iajs-3279	53	54	:	:	PUNCT
iajs-3279	53	55	47	47	NUM
iajs-3279	53	56	%	%	NOUN
iajs-3279	53	57	,	,	PUNCT
iajs-3279	53	58	33	33	NUM
iajs-3279	53	59	%	%	NOUN
iajs-3279	53	60	and	and	CCONJ
iajs-3279	53	61	79	79	NUM
iajs-3279	53	62	%	%	NOUN
iajs-3279	53	63	respectively	respectively	ADV
iajs-3279	53	64	[	[	X
iajs-3279	53	65	21	21	NUM
iajs-3279	53	66	]	]	PUNCT
iajs-3279	53	67	.	.	PUNCT
iajs-3279	54	1	figure	figure	NOUN
iajs-3279	54	2	1	1	NUM
iajs-3279	54	3	.	.	PUNCT
iajs-3279	55	1	the	the	DET
iajs-3279	55	2	1	1	NUM
iajs-3279	55	3	h	h	NOUN
iajs-3279	55	4	and	and	CCONJ
iajs-3279	55	5	13	13	NUM
iajs-3279	55	6	c	c	NOUN
iajs-3279	55	7	-	-	PUNCT
iajs-3279	55	8	nmr	nmr	NOUN
iajs-3279	55	9	spectra	spectra	NOUN
iajs-3279	55	10	of	of	ADP
iajs-3279	55	11	ligand	ligand	PROPN
iajs-3279	55	12	(	(	PUNCT
iajs-3279	55	13	h3l	h3l	NOUN
iajs-3279	55	14	)	)	PUNCT
iajs-3279	55	15	.	.	PUNCT
iajs-3279	56	1	ihjpas	ihjpas	PROPN
iajs-3279	56	2	.	.	PUNCT
iajs-3279	57	1	37(2)2024	37(2)2024	NUM
iajs-3279	57	2	246	246	NUM
iajs-3279	57	3	figure	figure	NOUN
iajs-3279	57	4	2	2	NUM
iajs-3279	57	5	.	.	PUNCT
iajs-3279	57	6	mass	mass	PROPN
iajs-3279	57	7	spectrum	spectrum	NOUN
iajs-3279	57	8	of	of	ADP
iajs-3279	57	9	ligand	ligand	NOUN
iajs-3279	57	10	.	.	PUNCT
iajs-3279	58	1	scheme	scheme	NOUN
iajs-3279	58	2	1	1	NUM
iajs-3279	58	3	.	.	PUNCT
iajs-3279	58	4	pattern	pattern	NOUN
iajs-3279	58	5	of	of	ADP
iajs-3279	58	6	fragmentation	fragmentation	NOUN
iajs-3279	58	7	of	of	ADP
iajs-3279	58	8	ligand	ligand	NOUN
iajs-3279	58	9	.	.	PUNCT
iajs-3279	59	1	2.2	2.2	NUM
iajs-3279	59	2	general	general	ADJ
iajs-3279	59	3	approach	approach	NOUN
iajs-3279	59	4	for	for	ADP
iajs-3279	59	5	complexes	complex	NOUN
iajs-3279	59	6	synthesis	synthesis	VERB
iajs-3279	59	7	the	the	DET
iajs-3279	59	8	metal	metal	NOUN
iajs-3279	59	9	salt	salt	NOUN
iajs-3279	59	10	(	(	PUNCT
iajs-3279	59	11	1	1	NUM
iajs-3279	59	12	mmol	mmol	NOUN
iajs-3279	59	13	)	)	PUNCT
iajs-3279	59	14	of	of	ADP
iajs-3279	59	15	[	[	X
iajs-3279	59	16	0.1979	0.1979	NUM
iajs-3279	59	17	g	g	ADP
iajs-3279	59	18	nicl2.6h2o	nicl2.6h2o	NOUN
iajs-3279	59	19	,	,	PUNCT
iajs-3279	59	20	0.1364	0.1364	NUM
iajs-3279	59	21	g	g	NOUN
iajs-3279	59	22	zncl2	zncl2	PROPN
iajs-3279	59	23	,	,	PUNCT
iajs-3279	59	24	0.17742	0.17742	NUM
iajs-3279	59	25	g	g	NOUN
iajs-3279	59	26	pdcl2	pdcl2	NOUN
iajs-3279	59	27	and	and	CCONJ
iajs-3279	59	28	0.5178	0.5178	NUM
iajs-3279	59	29	g	g	PROPN
iajs-3279	59	30	h2ptcl6.6h2o	h2ptcl6.6h2o	NOUN
iajs-3279	59	31	]	]	PUNCT
iajs-3279	59	32	was	be	AUX
iajs-3279	59	33	dissolved	dissolve	VERB
iajs-3279	59	34	in	in	ADP
iajs-3279	59	35	15	15	NUM
iajs-3279	59	36	ml	ml	NOUN
iajs-3279	59	37	of	of	ADP
iajs-3279	59	38	hot	hot	ADJ
iajs-3279	59	39	ethanol	ethanol	NOUN
iajs-3279	59	40	.	.	PUNCT
iajs-3279	60	1	then	then	ADV
iajs-3279	60	2	(	(	PUNCT
iajs-3279	60	3	0.432	0.432	NUM
iajs-3279	60	4	g	g	NOUN
iajs-3279	60	5	,	,	PUNCT
iajs-3279	60	6	1	1	NUM
iajs-3279	60	7	mmol	mmol	NOUN
iajs-3279	60	8	)	)	PUNCT
iajs-3279	60	9	of	of	ADP
iajs-3279	60	10	azo	azo	NOUN
iajs-3279	60	11	dye	dye	NOUN
iajs-3279	60	12	in	in	ADP
iajs-3279	60	13	15	15	NUM
iajs-3279	60	14	ml	ml	NOUN
iajs-3279	60	15	of	of	ADP
iajs-3279	60	16	hot	hot	ADJ
iajs-3279	60	17	ethanol	ethanol	NOUN
iajs-3279	60	18	was	be	AUX
iajs-3279	60	19	added	add	VERB
iajs-3279	60	20	drop	drop	NOUN
iajs-3279	60	21	by	by	ADP
iajs-3279	60	22	drop	drop	NOUN
iajs-3279	60	23	.	.	PUNCT
iajs-3279	61	1	the	the	DET
iajs-3279	61	2	mixture	mixture	NOUN
iajs-3279	61	3	washeated	washeate	VERB
iajs-3279	61	4	under	under	ADP
iajs-3279	61	5	reflux	reflux	NOUN
iajs-3279	61	6	for	for	ADP
iajs-3279	61	7	6	6	NUM
iajs-3279	61	8	hours	hour	NOUN
iajs-3279	61	9	up	up	ADP
iajs-3279	61	10	to	to	PART
iajs-3279	61	11	40	40	NUM
iajs-3279	61	12	-	-	SYM
iajs-3279	61	13	50	50	NUM
iajs-3279	61	14	°	°	NUM
iajs-3279	61	15	c	c	NOUN
iajs-3279	61	16	.	.	PUNCT
iajs-3279	62	1	the	the	DET
iajs-3279	62	2	solid	solid	ADJ
iajs-3279	62	3	complexes	complex	NOUN
iajs-3279	62	4	were	be	AUX
iajs-3279	62	5	separated	separate	VERB
iajs-3279	62	6	and	and	CCONJ
iajs-3279	62	7	any	any	DET
iajs-3279	62	8	non	non	ADJ
iajs-3279	62	9	-	-	ADJ
iajs-3279	62	10	apostate	apostate	ADJ
iajs-3279	62	11	ingredients	ingredient	NOUN
iajs-3279	62	12	are	be	AUX
iajs-3279	62	13	removed	remove	VERB
iajs-3279	62	14	by	by	ADP
iajs-3279	62	15	immersing	immerse	VERB
iajs-3279	62	16	them	they	PRON
iajs-3279	62	17	shortly	shortly	ADV
iajs-3279	62	18	in	in	ADP
iajs-3279	62	19	the	the	DET
iajs-3279	62	20	hot	hot	ADJ
iajs-3279	62	21	ethanol	ethanol	NOUN
iajs-3279	62	22	.	.	PUNCT
iajs-3279	63	1	the	the	DET
iajs-3279	63	2	complexes	complex	NOUN
iajs-3279	63	3	were	be	AUX
iajs-3279	63	4	collected	collect	VERB
iajs-3279	63	5	,	,	PUNCT
iajs-3279	63	6	dried	dry	VERB
iajs-3279	63	7	and	and	CCONJ
iajs-3279	63	8	weighed	weigh	VERB
iajs-3279	63	9	.	.	PUNCT
iajs-3279	64	1	schem	schem	PROPN
iajs-3279	64	2	2	2	NUM
iajs-3279	64	3	shows	show	VERB
iajs-3279	64	4	the	the	DET
iajs-3279	64	5	formation	formation	NOUN
iajs-3279	64	6	of	of	ADP
iajs-3279	64	7	the	the	DET
iajs-3279	64	8	metal	metal	NOUN
iajs-3279	64	9	ions	ion	NOUN
iajs-3279	64	10	complexes	complex	NOUN
iajs-3279	64	11	.	.	PUNCT
iajs-3279	65	1	ihjpas	ihjpas	PROPN
iajs-3279	65	2	.	.	PUNCT
iajs-3279	66	1	37(2)2024	37(2)2024	NUM
iajs-3279	66	2	247	247	NUM
iajs-3279	66	3	scheme	scheme	NOUN
iajs-3279	66	4	2	2	NUM
iajs-3279	66	5	.	.	X
iajs-3279	66	6	formation	formation	NOUN
iajs-3279	66	7	for	for	ADP
iajs-3279	66	8	ligand	ligand	NOUN
iajs-3279	66	9	and	and	CCONJ
iajs-3279	66	10	their	their	PRON
iajs-3279	66	11	metal	metal	NOUN
iajs-3279	66	12	complexes	complex	NOUN
iajs-3279	66	13	.	.	PUNCT
iajs-3279	67	1	3	3	X
iajs-3279	67	2	.	.	NOUN
iajs-3279	67	3	results	result	NOUN
iajs-3279	67	4	and	and	CCONJ
iajs-3279	67	5	discussion	discussion	NOUN
iajs-3279	67	6	3.1	3.1	NUM
iajs-3279	67	7	physical	physical	ADJ
iajs-3279	67	8	and	and	CCONJ
iajs-3279	67	9	analytical	analytical	ADJ
iajs-3279	67	10	data	datum	NOUN
iajs-3279	67	11	for	for	ADP
iajs-3279	67	12	ligand	ligand	NOUN
iajs-3279	67	13	and	and	CCONJ
iajs-3279	67	14	the	the	DET
iajs-3279	67	15	synthesized	synthesize	VERB
iajs-3279	67	16	complexes	complex	NOUN
iajs-3279	67	17	reactions	reaction	NOUN
iajs-3279	67	18	of	of	ADP
iajs-3279	67	19	metal	metal	NOUN
iajs-3279	67	20	salts	salt	NOUN
iajs-3279	67	21	with	with	ADP
iajs-3279	67	22	ligands	ligand	NOUN
iajs-3279	67	23	gave	give	VERB
iajs-3279	67	24	the	the	DET
iajs-3279	67	25	synthetic	synthetic	ADJ
iajs-3279	67	26	complexes	complex	NOUN
iajs-3279	67	27	,	,	PUNCT
iajs-3279	67	28	as	as	SCONJ
iajs-3279	67	29	shown	show	VERB
iajs-3279	67	30	in	in	ADP
iajs-3279	67	31	scheme	scheme	NOUN
iajs-3279	67	32	1	1	NUM
iajs-3279	67	33	.	.	PUNCT
iajs-3279	68	1	the	the	DET
iajs-3279	68	2	results	result	NOUN
iajs-3279	68	3	of	of	ADP
iajs-3279	68	4	the	the	DET
iajs-3279	68	5	elemental	elemental	ADJ
iajs-3279	68	6	analysis	analysis	NOUN
iajs-3279	68	7	demonstrate	demonstrate	VERB
iajs-3279	68	8	1:1	1:1	NUM
iajs-3279	68	9	m	m	NOUN
iajs-3279	68	10	:	:	PUNCT
iajs-3279	68	11	l	l	NOUN
iajs-3279	68	12	stoichiometry	stoichiometry	NOUN
iajs-3279	68	13	for	for	ADP
iajs-3279	68	14	all	all	DET
iajs-3279	68	15	complexes	complex	NOUN
iajs-3279	68	16	.	.	PUNCT
iajs-3279	69	1	the	the	DET
iajs-3279	69	2	elemental	elemental	ADJ
iajs-3279	69	3	analysis	analysis	NOUN
iajs-3279	69	4	results	result	NOUN
iajs-3279	69	5	were	be	AUX
iajs-3279	69	6	compatible	compatible	ADJ
iajs-3279	69	7	with	with	ADP
iajs-3279	69	8	the	the	DET
iajs-3279	69	9	theoretical	theoretical	ADJ
iajs-3279	69	10	calculated	calculate	VERB
iajs-3279	69	11	results	result	NOUN
iajs-3279	69	12	,	,	PUNCT
iajs-3279	69	13	as	as	SCONJ
iajs-3279	69	14	denoted	denote	VERB
iajs-3279	69	15	in	in	ADP
iajs-3279	69	16	table	table	NOUN
iajs-3279	69	17	1	1	NUM
iajs-3279	69	18	.	.	PUNCT
iajs-3279	69	19	table	table	NOUN
iajs-3279	69	20	1	1	NUM
iajs-3279	69	21	.	.	PUNCT
iajs-3279	70	1	some	some	DET
iajs-3279	70	2	physical	physical	ADJ
iajs-3279	70	3	propertiesand	propertiesand	NOUN
iajs-3279	70	4	element	element	PROPN
iajs-3279	70	5	micro	micro	PROPN
iajs-3279	70	6	analysis	analysis	NOUN
iajs-3279	70	7	studies	study	NOUN
iajs-3279	70	8	of	of	ADP
iajs-3279	70	9	ligand	ligand	NOUN
iajs-3279	70	10	and	and	CCONJ
iajs-3279	70	11	complexes	complex	NOUN
iajs-3279	70	12	.	.	PUNCT
iajs-3279	71	1	micro	micro	ADJ
iajs-3279	71	2	elemental	elemental	ADJ
iajs-3279	71	3	analysis	analysis	NOUN
iajs-3279	71	4	(	(	PUNCT
iajs-3279	71	5	found	find	VERB
iajs-3279	71	6	)	)	PUNCT
iajs-3279	71	7	and	and	CCONJ
iajs-3279	71	8	calculated	calculate	VERB
iajs-3279	71	9	%	%	NOUN
iajs-3279	71	10	compounds	compound	NOUN
iajs-3279	71	11	formula	formula	NOUN
iajs-3279	71	12	m.wt	m.wt	VERB
iajs-3279	71	13	m.p	m.p	PROPN
iajs-3279	71	14	°	°	PROPN
iajs-3279	71	15	c	c	NOUN
iajs-3279	71	16	color	color	NOUN
iajs-3279	71	17	cl	cl	NOUN
iajs-3279	72	1	m	m	NOUN
iajs-3279	72	2	s	s	NOUN
iajs-3279	72	3	o	o	NOUN
iajs-3279	73	1	n	n	NUM
iajs-3279	73	2	h	h	NOUN
iajs-3279	73	3	c	c	PROPN
iajs-3279	73	4	146148	146148	NUM
iajs-3279	73	5	orange	orange	NOUN
iajs-3279	73	6	--(6.70	--(6.70	PROPN
iajs-3279	73	7	)	)	PUNCT
iajs-3279	73	8	7.42	7.42	NUM
iajs-3279	73	9	(	(	PUNCT
iajs-3279	73	10	25.10	25.10	NUM
iajs-3279	73	11	)	)	PUNCT
iajs-3279	73	12	25.90	25.90	NUM
iajs-3279	73	13	(	(	PUNCT
iajs-3279	73	14	14.00	14.00	NUM
iajs-3279	73	15	)	)	PUNCT
iajs-3279	73	16	12.96	12.96	NUM
iajs-3279	73	17	(	(	PUNCT
iajs-3279	73	18	4.01	4.01	NUM
iajs-3279	73	19	)	)	PUNCT
iajs-3279	73	20	3.72	3.72	NUM
iajs-3279	73	21	(	(	PUNCT
iajs-3279	73	22	50.55	50.55	NUM
iajs-3279	73	23	)	)	PUNCT
iajs-3279	73	24	50.00	50.00	NUM
iajs-3279	73	25	h3l=	h3l=	NOUN
iajs-3279	73	26	c18h16n4o7s	c18h16n4o7s	NOUN
iajs-3279	73	27	432	432	NUM
iajs-3279	73	28	=	=	SYM
iajs-3279	73	29	196	196	NUM
iajs-3279	73	30	d	d	NOUN
iajs-3279	73	31	brown	brown	NOUN
iajs-3279	73	32	(	(	PUNCT
iajs-3279	73	33	7.03	7.03	NUM
iajs-3279	73	34	)	)	PUNCT
iajs-3279	73	35	6.33	6.33	NUM
iajs-3279	73	36	(	(	PUNCT
iajs-3279	73	37	11.09	11.09	NUM
iajs-3279	73	38	)	)	PUNCT
iajs-3279	73	39	10.46	10.46	NUM
iajs-3279	73	40	(	(	PUNCT
iajs-3279	73	41	6.05	6.05	NUM
iajs-3279	73	42	)	)	PUNCT
iajs-3279	73	43	5.70	5.70	NUM
iajs-3279	73	44	(	(	PUNCT
iajs-3279	73	45	26.01	26.01	NUM
iajs-3279	73	46	)	)	PUNCT
iajs-3279	73	47	25.66	25.66	NUM
iajs-3279	73	48	(	(	PUNCT
iajs-3279	73	49	10.96	10.96	NUM
iajs-3279	73	50	)	)	PUNCT
iajs-3279	73	51	9.98	9.98	NUM
iajs-3279	73	52	(	(	PUNCT
iajs-3279	73	53	4.09	4.09	NUM
iajs-3279	73	54	)	)	PUNCT
iajs-3279	73	55	3.38	3.38	NUM
iajs-3279	73	56	(	(	PUNCT
iajs-3279	73	57	37.77	37.77	NUM
iajs-3279	73	58	)	)	PUNCT
iajs-3279	73	59	38.49	38.49	NUM
iajs-3279	73	60	c18h19n4o9scln	c18h19n4o9scln	NOUN
iajs-3279	74	1	i	i	NOUN
iajs-3279	74	2	=	=	SYM
iajs-3279	74	3	561.1934	561.1934	NUM
iajs-3279	74	4	259	259	NUM
iajs-3279	74	5	d	d	NOUN
iajs-3279	74	6	brown	brown	NOUN
iajs-3279	74	7	(	(	PUNCT
iajs-3279	74	8	6.00	6.00	NUM
iajs-3279	74	9	)	)	PUNCT
iajs-3279	74	10	6.46	6.46	NUM
iajs-3279	74	11	(	(	PUNCT
iajs-3279	74	12	11.10	11.10	NUM
iajs-3279	74	13	)	)	PUNCT
iajs-3279	74	14	11.89	11.89	NUM
iajs-3279	74	15	(	(	PUNCT
iajs-3279	74	16	5.62	5.62	NUM
iajs-3279	74	17	)	)	PUNCT
iajs-3279	74	18	5.82	5.82	NUM
iajs-3279	74	19	(	(	PUNCT
iajs-3279	74	20	22.66	22.66	NUM
iajs-3279	74	21	)	)	PUNCT
iajs-3279	74	22	23.28	23.28	NUM
iajs-3279	74	23	(	(	PUNCT
iajs-3279	74	24	11.61	11.61	NUM
iajs-3279	74	25	)	)	PUNCT
iajs-3279	74	26	10.18	10.18	NUM
iajs-3279	74	27	(	(	PUNCT
iajs-3279	74	28	3.00	3.00	NUM
iajs-3279	74	29	)	)	PUNCT
iajs-3279	74	30	3.09	3.09	NUM
iajs-3279	74	31	(	(	PUNCT
iajs-3279	74	32	40.01	40.01	NUM
iajs-3279	74	33	)	)	PUNCT
iajs-3279	74	34	39.28	39.28	NUM
iajs-3279	74	35	c18h17n4o8sclz	c18h17n4o8sclz	X
iajs-3279	74	36	n=	n=	X
iajs-3279	74	37	549.909	549.909	NUM
iajs-3279	74	38	220	220	NUM
iajs-3279	74	39	d	d	NOUN
iajs-3279	74	40	light	light	ADJ
iajs-3279	74	41	brown	brown	NOUN
iajs-3279	74	42	(	(	PUNCT
iajs-3279	74	43	7.08	7.08	NUM
iajs-3279	74	44	)	)	PUNCT
iajs-3279	74	45	6.19	6.19	NUM
iajs-3279	74	46	(	(	PUNCT
iajs-3279	74	47	16.69	16.69	NUM
iajs-3279	74	48	)	)	PUNCT
iajs-3279	74	49	18.58	18.58	NUM
iajs-3279	74	50	(	(	PUNCT
iajs-3279	74	51	6.09	6.09	NUM
iajs-3279	74	52	)	)	PUNCT
iajs-3279	74	53	5.60	5.60	NUM
iajs-3279	74	54	(	(	PUNCT
iajs-3279	74	55	18.91	18.91	NUM
iajs-3279	74	56	)	)	PUNCT
iajs-3279	74	57	19.54	19.54	NUM
iajs-3279	74	58	(	(	PUNCT
iajs-3279	74	59	10.67	10.67	NUM
iajs-3279	74	60	)	)	PUNCT
iajs-3279	74	61	9.77	9.77	NUM
iajs-3279	74	62	(	(	PUNCT
iajs-3279	74	63	2.09	2.09	NUM
iajs-3279	74	64	)	)	PUNCT
iajs-3279	74	65	2.64	2.64	NUM
iajs-3279	74	66	(	(	PUNCT
iajs-3279	74	67	38.65	38.65	NUM
iajs-3279	74	68	)	)	PUNCT
iajs-3279	74	69	37.68	37.68	NUM
iajs-3279	74	70	c18h15n4o7sclp	c18h15n4o7sclp	VERB
iajs-3279	74	71	572.92	572.92	NUM
iajs-3279	74	72	=	=	SYM
iajs-3279	74	73	d	d	PROPN
iajs-3279	74	74	186	186	NUM
iajs-3279	74	75	d	d	PROPN
iajs-3279	74	76	dark	dark	ADJ
iajs-3279	74	77	brown	brown	NOUN
iajs-3279	74	78	(	(	PUNCT
iajs-3279	74	79	13.69	13.69	NUM
iajs-3279	74	80	)	)	PUNCT
iajs-3279	74	81	14.54	14.54	NUM
iajs-3279	74	82	(	(	PUNCT
iajs-3279	74	83	25.67	25.67	NUM
iajs-3279	74	84	)	)	PUNCT
iajs-3279	74	85	26.63	26.63	NUM
iajs-3279	74	86	(	(	PUNCT
iajs-3279	74	87	5.05	5.05	NUM
iajs-3279	74	88	)	)	PUNCT
iajs-3279	74	89	4.37	4.37	NUM
iajs-3279	74	90	(	(	PUNCT
iajs-3279	74	91	15.21	15.21	NUM
iajs-3279	74	92	)	)	PUNCT
iajs-3279	74	93	15.29	15.29	NUM
iajs-3279	74	94	(	(	PUNCT
iajs-3279	74	95	8.01	8.01	NUM
iajs-3279	74	96	)	)	PUNCT
iajs-3279	74	97	7.64	7.64	NUM
iajs-3279	74	98	(	(	PUNCT
iajs-3279	74	99	2.41	2.41	NUM
iajs-3279	74	100	)	)	PUNCT
iajs-3279	74	101	2.05	2.05	NUM
iajs-3279	74	102	(	(	PUNCT
iajs-3279	74	103	30.01	30.01	NUM
iajs-3279	74	104	)	)	PUNCT
iajs-3279	74	105	29.48	29.48	NUM
iajs-3279	74	106	c18h15n4o7scl3	c18h15n4o7scl3	NOUN
iajs-3279	74	107	pt	pt	NOUN
iajs-3279	75	1	=	=	SYM
iajs-3279	75	2	732.578	732.578	NUM
iajs-3279	75	3	d	d	PUNCT
iajs-3279	75	4	=	=	NOUN
iajs-3279	75	5	decompose	decompose	NOUN
iajs-3279	75	6	.	.	PUNCT
iajs-3279	76	1	3.2	3.2	NUM
iajs-3279	76	2	the	the	DET
iajs-3279	76	3	uv	uv	NOUN
iajs-3279	76	4	-	-	PUNCT
iajs-3279	76	5	vis	vis	X
iajs-3279	76	6	studies	study	NOUN
iajs-3279	76	7	of	of	ADP
iajs-3279	76	8	the	the	DET
iajs-3279	76	9	complexes	complex	NOUN
iajs-3279	76	10	the	the	DET
iajs-3279	76	11	uv	uv	NOUN
iajs-3279	76	12	-	-	PUNCT
iajs-3279	76	13	vis	vis	X
iajs-3279	76	14	spectrum	spectrum	NOUN
iajs-3279	76	15	exhibits	exhibit	VERB
iajs-3279	76	16	the	the	DET
iajs-3279	76	17	electronic	electronic	ADJ
iajs-3279	76	18	transition	transition	NOUN
iajs-3279	76	19	of	of	ADP
iajs-3279	76	20	pt	pt	PROPN
iajs-3279	76	21	4	4	NUM
iajs-3279	76	22	+	+	NUM
iajs-3279	76	23	complex	complex	ADJ
iajs-3279	76	24	show	show	NOUN
iajs-3279	76	25	in	in	ADP
iajs-3279	76	26	figure	figure	NOUN
iajs-3279	76	27	4	4	NUM
iajs-3279	76	28	depicts	depict	VERB
iajs-3279	76	29	a	a	DET
iajs-3279	76	30	peak	peak	NOUN
iajs-3279	76	31	of	of	ADP
iajs-3279	76	32	(	(	PUNCT
iajs-3279	76	33	288	288	NUM
iajs-3279	76	34	,	,	PUNCT
iajs-3279	76	35	375	375	NUM
iajs-3279	76	36	,	,	PUNCT
iajs-3279	76	37	615	615	NUM
iajs-3279	76	38	,	,	PUNCT
iajs-3279	76	39	632	632	NUM
iajs-3279	76	40	and	and	CCONJ
iajs-3279	76	41	680	680	NUM
iajs-3279	76	42	)	)	PUNCT
iajs-3279	76	43	nm	nm	NOUN
iajs-3279	76	44	assigned	assign	VERB
iajs-3279	76	45	to	to	ADP
iajs-3279	76	46	π→	π→	PROPN
iajs-3279	76	47	π	π	PROPN
iajs-3279	76	48	*	*	PROPN
iajs-3279	76	49	,	,	PUNCT
iajs-3279	76	50	n→	n→	ADV
iajs-3279	76	51	π	π	PROPN
iajs-3279	76	52	*	*	NOUN
iajs-3279	76	53	,	,	PUNCT
iajs-3279	76	54	1	1	NUM
iajs-3279	76	55	a1g→	a1g→	PROPN
iajs-3279	76	56	1	1	NUM
iajs-3279	76	57	t1	t1	NOUN
iajs-3279	76	58	g	g	NOUN
iajs-3279	76	59	,	,	PUNCT
iajs-3279	76	60	1	1	NUM
iajs-3279	76	61	a1g→	a1g→	PROPN
iajs-3279	76	62	1	1	NUM
iajs-3279	76	63	t2	t2	NOUN
iajs-3279	76	64	g	g	NOUN
iajs-3279	76	65	and	and	CCONJ
iajs-3279	76	66	1	1	NUM
iajs-3279	76	67	a1g→	a1g→	PROPN
iajs-3279	76	68	3	3	NUM
iajs-3279	76	69	t2	t2	NOUN
iajs-3279	76	70	g	g	NOUN
iajs-3279	76	71	respectively	respectively	ADV
iajs-3279	76	72	which	which	PRON
iajs-3279	76	73	indicative	indicative	ADJ
iajs-3279	76	74	of	of	ADP
iajs-3279	76	75	a	a	DET
iajs-3279	76	76	octahedral	octahedral	ADJ
iajs-3279	76	77	geometry	geometry	NOUN
iajs-3279	76	78	,	,	PUNCT
iajs-3279	76	79	it	it	PRON
iajs-3279	76	80	has	have	VERB
iajs-3279	76	81	a	a	DET
iajs-3279	76	82	magnetic	magnetic	ADJ
iajs-3279	76	83	moment	moment	NOUN
iajs-3279	76	84	of	of	ADP
iajs-3279	76	85	diamagnatic	diamagnatic	NOUN
iajs-3279	76	86	.	.	PUNCT
iajs-3279	77	1	the	the	DET
iajs-3279	77	2	ni	ni	PROPN
iajs-3279	77	3	2	2	NUM
iajs-3279	77	4	+	+	NUM
iajs-3279	77	5	complex	complex	ADJ
iajs-3279	77	6	show	show	NOUN
iajs-3279	77	7	in	in	ADP
iajs-3279	77	8	figure	figure	NOUN
iajs-3279	77	9	3	3	NUM
iajs-3279	77	10	exhibited	exhibit	VERB
iajs-3279	77	11	peaks	peak	NOUN
iajs-3279	77	12	of	of	ADP
iajs-3279	77	13	(	(	PUNCT
iajs-3279	77	14	220	220	NUM
iajs-3279	77	15	,	,	PUNCT
iajs-3279	77	16	270	270	NUM
iajs-3279	77	17	,	,	PUNCT
iajs-3279	77	18	418	418	NUM
iajs-3279	77	19	,	,	PUNCT
iajs-3279	77	20	614	614	NUM
iajs-3279	77	21	,	,	PUNCT
iajs-3279	77	22	730	730	NUM
iajs-3279	77	23	and	and	CCONJ
iajs-3279	77	24	ihjpas	ihjpa	NOUN
iajs-3279	77	25	.	.	PUNCT
iajs-3279	78	1	37(2)2024	37(2)2024	NUM
iajs-3279	78	2	248	248	NUM
iajs-3279	78	3	840	840	NUM
iajs-3279	78	4	)	)	PUNCT
iajs-3279	78	5	nm	nm	NOUN
iajs-3279	78	6	ascribed	ascribe	VERB
iajs-3279	78	7	to	to	ADP
iajs-3279	78	8	the	the	DET
iajs-3279	78	9	π→π	π→π	PROPN
iajs-3279	78	10	*	*	PROPN
iajs-3279	78	11	,	,	PUNCT
iajs-3279	78	12	n→π	n→π	NOUN
iajs-3279	78	13	*	*	NUM
iajs-3279	78	14	,	,	PUNCT
iajs-3279	78	15	c.t	c.t	PROPN
iajs-3279	78	16	m→l	m→l	PROPN
iajs-3279	78	17	,	,	PUNCT
iajs-3279	78	18	3	3	NUM
iajs-3279	78	19	a1g→	a1g→	PROPN
iajs-3279	78	20	3	3	NUM
iajs-3279	78	21	t2g(f	t2g(f	PROPN
iajs-3279	78	22	)	)	PUNCT
iajs-3279	78	23	,	,	PUNCT
iajs-3279	78	24	3	3	NUM
iajs-3279	78	25	a1g→	a1g→	PROPN
iajs-3279	78	26	3	3	NUM
iajs-3279	78	27	t1g(f	t1g(f	NOUN
iajs-3279	78	28	)	)	PUNCT
iajs-3279	78	29	and	and	CCONJ
iajs-3279	78	30	3	3	NUM
iajs-3279	78	31	a2g→	a2g→	ADP
iajs-3279	78	32	3	3	NUM
iajs-3279	78	33	t1g(p	t1g(p	NOUN
iajs-3279	78	34	)	)	PUNCT
iajs-3279	78	35	respectively	respectively	ADV
iajs-3279	78	36	is	be	AUX
iajs-3279	78	37	in	in	ADP
iajs-3279	78	38	good	good	ADJ
iajs-3279	78	39	agreement	agreement	NOUN
iajs-3279	78	40	with	with	ADP
iajs-3279	78	41	prior	prior	ADJ
iajs-3279	78	42	work	work	NOUN
iajs-3279	78	43	on	on	ADP
iajs-3279	78	44	octahedral	octahedral	ADJ
iajs-3279	78	45	geometry	geometry	NOUN
iajs-3279	78	46	,	,	PUNCT
iajs-3279	78	47	it	it	PRON
iajs-3279	78	48	has	have	VERB
iajs-3279	78	49	a	a	DET
iajs-3279	78	50	magnetic	magnetic	ADJ
iajs-3279	78	51	moment	moment	NOUN
iajs-3279	78	52	of	of	ADP
iajs-3279	78	53	2.13	2.13	NUM
iajs-3279	79	1	[	[	X
iajs-3279	79	2	22	22	NUM
iajs-3279	79	3	]	]	PUNCT
iajs-3279	79	4	.	.	PUNCT
iajs-3279	80	1	the	the	DET
iajs-3279	80	2	electronic	electronic	ADJ
iajs-3279	80	3	absorption	absorption	NOUN
iajs-3279	80	4	of	of	ADP
iajs-3279	80	5	zn	zn	PROPN
iajs-3279	80	6	2	2	NUM
iajs-3279	80	7	+	+	PROPN
iajs-3279	80	8	complexe	complexe	PROPN
iajs-3279	80	9	exhibited	exhibit	VERB
iajs-3279	80	10	peaks	peak	NOUN
iajs-3279	80	11	of	of	ADP
iajs-3279	80	12	(	(	PUNCT
iajs-3279	80	13	263	263	NUM
iajs-3279	80	14	,	,	PUNCT
iajs-3279	80	15	368	368	NUM
iajs-3279	80	16	and	and	CCONJ
iajs-3279	80	17	447	447	NUM
iajs-3279	80	18	)	)	PUNCT
iajs-3279	80	19	nm	nm	NOUN
iajs-3279	80	20	ascribed	ascribe	VERB
iajs-3279	80	21	to	to	ADP
iajs-3279	80	22	the	the	DET
iajs-3279	80	23	π	π	PROPN
iajs-3279	80	24	→π*,n→π	→π*,n→π	NOUN
iajs-3279	80	25	*	*	PUNCT
iajs-3279	80	26	and	and	CCONJ
iajs-3279	80	27	c.tm→l	c.tm→l	VERB
iajs-3279	80	28	respectively	respectively	ADV
iajs-3279	80	29	which	which	PRON
iajs-3279	80	30	is	be	AUX
iajs-3279	80	31	indicative	indicative	ADJ
iajs-3279	80	32	of	of	ADP
iajs-3279	80	33	a	a	DET
iajs-3279	80	34	tetrahedral	tetrahedral	ADJ
iajs-3279	80	35	geometry	geometry	NOUN
iajs-3279	80	36	,	,	PUNCT
iajs-3279	80	37	it	it	PRON
iajs-3279	80	38	has	have	VERB
iajs-3279	80	39	a	a	DET
iajs-3279	80	40	magnetic	magnetic	ADJ
iajs-3279	80	41	moment	moment	NOUN
iajs-3279	80	42	of	of	ADP
iajs-3279	80	43	diamagnetic	diamagnetic	ADJ
iajs-3279	80	44	[	[	X
iajs-3279	80	45	23	23	NUM
iajs-3279	80	46	]	]	PUNCT
iajs-3279	80	47	.	.	PUNCT
iajs-3279	81	1	the	the	DET
iajs-3279	81	2	pd	pd	PROPN
iajs-3279	81	3	2	2	NUM
iajs-3279	81	4	+	+	PROPN
iajs-3279	81	5	complexe	complexe	PROPN
iajs-3279	81	6	exhibited	exhibit	VERB
iajs-3279	81	7	peaks	peak	NOUN
iajs-3279	81	8	at	at	ADP
iajs-3279	81	9	(	(	PUNCT
iajs-3279	81	10	262	262	NUM
iajs-3279	81	11	,	,	PUNCT
iajs-3279	81	12	363	363	NUM
iajs-3279	81	13	,	,	PUNCT
iajs-3279	81	14	421	421	NUM
iajs-3279	81	15	,	,	PUNCT
iajs-3279	81	16	700	700	NUM
iajs-3279	81	17	and	and	CCONJ
iajs-3279	81	18	804	804	NUM
iajs-3279	81	19	)	)	PUNCT
iajs-3279	81	20	nm	nm	NOUN
iajs-3279	81	21	ascribed	ascribe	VERB
iajs-3279	81	22	to	to	ADP
iajs-3279	81	23	the	the	DET
iajs-3279	81	24	π→	π→	PROPN
iajs-3279	81	25	π	π	PROPN
iajs-3279	81	26	*	*	PROPN
iajs-3279	81	27	,	,	PUNCT
iajs-3279	81	28	n→	n→	ADV
iajs-3279	81	29	π	π	PROPN
iajs-3279	81	30	*	*	NOUN
iajs-3279	81	31	,	,	PUNCT
iajs-3279	81	32	c.tm→l	c.tm→l	VERB
iajs-3279	81	33	,	,	PUNCT
iajs-3279	81	34	1	1	NUM
iajs-3279	81	35	a1g→	a1g→	PROPN
iajs-3279	81	36	1	1	NUM
iajs-3279	81	37	b1	b1	NOUN
iajs-3279	81	38	g	g	PROPN
iajs-3279	81	39	and	and	CCONJ
iajs-3279	81	40	1	1	NUM
iajs-3279	81	41	a1g→	a1g→	PROPN
iajs-3279	81	42	1	1	NUM
iajs-3279	81	43	a2	a2	PROPN
iajs-3279	81	44	g	g	PROPN
iajs-3279	81	45	respectively	respectively	ADV
iajs-3279	81	46	is	be	AUX
iajs-3279	81	47	in	in	ADP
iajs-3279	81	48	good	good	ADJ
iajs-3279	81	49	agreement	agreement	NOUN
iajs-3279	81	50	with	with	ADP
iajs-3279	81	51	prior	prior	ADJ
iajs-3279	81	52	work	work	NOUN
iajs-3279	81	53	on	on	ADP
iajs-3279	81	54	squar	squar	NOUN
iajs-3279	81	55	planer	planer	NOUN
iajs-3279	81	56	geometry	geometry	NOUN
iajs-3279	81	57	it	it	PRON
iajs-3279	81	58	has	have	VERB
iajs-3279	81	59	a	a	DET
iajs-3279	81	60	magnetic	magnetic	ADJ
iajs-3279	81	61	moment	moment	NOUN
iajs-3279	81	62	of	of	ADP
iajs-3279	81	63	diamagnetic	diamagnetic	ADJ
iajs-3279	81	64	[	[	X
iajs-3279	81	65	24	24	NUM
iajs-3279	81	66	]	]	PUNCT
iajs-3279	81	67	.	.	PUNCT
iajs-3279	82	1	table	table	NOUN
iajs-3279	82	2	2	2	NUM
iajs-3279	82	3	displays	display	VERB
iajs-3279	82	4	the	the	DET
iajs-3279	82	5	electronic	electronic	ADJ
iajs-3279	82	6	assignmentfor	assignmentfor	ADP
iajs-3279	82	7	metal	metal	NOUN
iajs-3279	82	8	complexes	complex	NOUN
iajs-3279	82	9	.	.	PUNCT
iajs-3279	83	1	figure	figure	NOUN
iajs-3279	83	2	3	3	NUM
iajs-3279	83	3	.	.	PUNCT
iajs-3279	84	1	the	the	DET
iajs-3279	84	2	uv	uv	NOUN
iajs-3279	84	3	-	-	PUNCT
iajs-3279	84	4	vis	vis	X
iajs-3279	84	5	spectrum	spectrum	NOUN
iajs-3279	84	6	of	of	ADP
iajs-3279	84	7	ni	ni	NOUN
iajs-3279	84	8	-	-	PUNCT
iajs-3279	84	9	complex	complex	ADJ
iajs-3279	84	10	.	.	PUNCT
iajs-3279	85	1	figure	figure	NOUN
iajs-3279	85	2	4	4	NUM
iajs-3279	85	3	.	.	PUNCT
iajs-3279	86	1	the	the	DET
iajs-3279	86	2	uv	uv	NOUN
iajs-3279	86	3	-	-	PUNCT
iajs-3279	86	4	vis	vis	X
iajs-3279	86	5	spectrum	spectrum	NOUN
iajs-3279	86	6	of	of	ADP
iajs-3279	86	7	pt	pt	NOUN
iajs-3279	86	8	-	-	PUNCT
iajs-3279	86	9	complex	complex	ADJ
iajs-3279	86	10	.	.	PUNCT
iajs-3279	86	11	table	table	NOUN
iajs-3279	86	12	2	2	NUM
iajs-3279	86	13	.	.	PUNCT
iajs-3279	87	1	the	the	DET
iajs-3279	87	2	uv	uv	NOUN
iajs-3279	87	3	-	-	PUNCT
iajs-3279	87	4	vis	vis	X
iajs-3279	87	5	spectra	spectra	PROPN
iajs-3279	87	6	,	,	PUNCT
iajs-3279	87	7	magnetic	magnetic	ADJ
iajs-3279	87	8	moments	moment	NOUN
iajs-3279	87	9	and	and	CCONJ
iajs-3279	87	10	molar	molar	ADJ
iajs-3279	87	11	conductivity	conductivity	NOUN
iajs-3279	87	12	for	for	ADP
iajs-3279	87	13	metal	metal	NOUN
iajs-3279	87	14	complexes	complex	NOUN
iajs-3279	87	15	.	.	PUNCT
iajs-3279	88	1	ʌms	ʌms	NOUN
iajs-3279	88	2	.	.	PUNCT
iajs-3279	89	1	cm	cm	NUM
iajs-3279	89	2	2	2	NUM
iajs-3279	89	3	.	.	PUNCT
iajs-3279	90	1	mol	mol	ADP
iajs-3279	90	2	-1	-1	PUNCT
iajs-3279	91	1	µeff	µeff	PROPN
iajs-3279	91	2	(	(	PUNCT
iajs-3279	91	3	b.m	b.m	PROPN
iajs-3279	91	4	)	)	PUNCT
iajs-3279	91	5	assignment	assignment	NOUN
iajs-3279	91	6	ɛmax	ɛmax	PUNCT
iajs-3279	91	7	l	l	PROPN
iajs-3279	91	8	mol	mol	ADP
iajs-3279	91	9	1	1	NUM
iajs-3279	91	10	cm	cm	NOUN
iajs-3279	91	11	-1	-1	PUNCT
iajs-3279	91	12	abs	ab	VERB
iajs-3279	91	13	ύ	ύ	DET
iajs-3279	91	14	cm	cm	NOUN
iajs-3279	91	15	-1	-1	PUNCT
iajs-3279	92	1	λ	λ	PROPN
iajs-3279	92	2	nm	nm	NOUN
iajs-3279	92	3	compound	compound	VERB
iajs-3279	92	4	13	13	NUM
iajs-3279	92	5	2.13	2.13	NUM
iajs-3279	92	6	π→π	π→π	NUM
iajs-3279	92	7	*	*	SYM
iajs-3279	92	8	n→π	n→π	NUM
iajs-3279	92	9	*	*	ADJ
iajs-3279	92	10	c.t	c.t	PROPN
iajs-3279	92	11	m→l	m→l	PROPN
iajs-3279	92	12	3	3	NUM
iajs-3279	92	13	a1g→	a1g→	PROPN
iajs-3279	92	14	3	3	NUM
iajs-3279	92	15	t2g(f	t2g(f	PROPN
iajs-3279	92	16	)	)	PUNCT
iajs-3279	92	17	3	3	NUM
iajs-3279	92	18	a1g→	a1g→	PROPN
iajs-3279	92	19	3	3	NUM
iajs-3279	92	20	t1g(f	t1g(f	NOUN
iajs-3279	92	21	)	)	PUNCT
iajs-3279	92	22	3	3	NUM
iajs-3279	92	23	a2g→	a2g→	ADP
iajs-3279	92	24	3	3	NUM
iajs-3279	92	25	t1g(p	t1g(p	NOUN
iajs-3279	92	26	)	)	PUNCT
iajs-3279	92	27	4000	4000	NUM
iajs-3279	92	28	9500	9500	NUM
iajs-3279	92	29	12380	12380	NUM
iajs-3279	92	30	5500	5500	NUM
iajs-3279	92	31	4850	4850	NUM
iajs-3279	92	32	3800	3800	NUM
iajs-3279	92	33	0.400	0.400	NUM
iajs-3279	92	34	0.950	0.950	NUM
iajs-3279	92	35	1.238	1.238	NUM
iajs-3279	92	36	0.550	0.550	NUM
iajs-3279	92	37	0.485	0.485	NUM
iajs-3279	92	38	0.380	0.380	NUM
iajs-3279	92	39	45454.55	45454.55	NUM
iajs-3279	92	40	37037.04	37037.04	NUM
iajs-3279	92	41	23923.45	23923.45	NUM
iajs-3279	92	42	16286.65	16286.65	NUM
iajs-3279	92	43	13698.63	13698.63	NUM
iajs-3279	92	44	11904.76	11904.76	NUM
iajs-3279	92	45	220	220	NUM
iajs-3279	92	46	270	270	NUM
iajs-3279	92	47	418	418	NUM
iajs-3279	92	48	614	614	NUM
iajs-3279	92	49	730	730	NUM
iajs-3279	92	50	840	840	NUM
iajs-3279	93	1	[	[	X
iajs-3279	93	2	ni(h2l)(h2o)2cl	ni(h2l)(h2o)2cl	X
iajs-3279	93	3	]	]	X
iajs-3279	93	4	octahedral	octahedral	ADJ
iajs-3279	93	5	16	16	NUM
iajs-3279	93	6	diamagnatic	diamagnatic	ADJ
iajs-3279	93	7	π→π	π→π	PROPN
iajs-3279	93	8	*	*	SYM
iajs-3279	93	9	n→π	n→π	NUM
iajs-3279	93	10	*	*	ADJ
iajs-3279	93	11	c.t	c.t	PROPN
iajs-3279	93	12	m→l	m→l	PROPN
iajs-3279	93	13	14000	14000	NUM
iajs-3279	93	14	10630	10630	NUM
iajs-3279	93	15	15810	15810	NUM
iajs-3279	93	16	1.400	1.400	NUM
iajs-3279	93	17	1.063	1.063	NUM
iajs-3279	93	18	1.581	1.581	NUM
iajs-3279	93	19	38022.81	38022.81	NUM
iajs-3279	93	20	27173.91	27173.91	NUM
iajs-3279	93	21	22371.36	22371.36	NUM
iajs-3279	93	22	263	263	NUM
iajs-3279	93	23	368	368	NUM
iajs-3279	93	24	447	447	NUM
iajs-3279	93	25	[	[	X
iajs-3279	93	26	zn(h2l)(h2o)cl	zn(h2l)(h2o)cl	X
iajs-3279	93	27	]	]	X
iajs-3279	93	28	tetrahedral	tetrahedral	ADJ
iajs-3279	93	29	13	13	NUM
iajs-3279	93	30	diamagnatic	diamagnatic	ADJ
iajs-3279	93	31	π→π	π→π	PROPN
iajs-3279	93	32	*	*	SYM
iajs-3279	93	33	n→π	n→π	NUM
iajs-3279	93	34	*	*	ADJ
iajs-3279	93	35	c.t	c.t	PROPN
iajs-3279	93	36	m→l	m→l	PROPN
iajs-3279	93	37	1	1	NUM
iajs-3279	93	38	a1g→	a1g→	PROPN
iajs-3279	93	39	1	1	NUM
iajs-3279	93	40	b1	b1	NOUN
iajs-3279	93	41	g	g	PROPN
iajs-3279	93	42	1	1	NUM
iajs-3279	93	43	a1g→	a1g→	PROPN
iajs-3279	93	44	1	1	NUM
iajs-3279	93	45	a2	a2	PROPN
iajs-3279	93	46	g	g	ADP
iajs-3279	93	47	5400	5400	NUM
iajs-3279	93	48	3550	3550	NUM
iajs-3279	93	49	6100	6100	NUM
iajs-3279	93	50	380	380	NUM
iajs-3279	93	51	400	400	NUM
iajs-3279	93	52	0.540	0.540	NUM
iajs-3279	93	53	0.355	0.355	NUM
iajs-3279	93	54	0.610	0.610	NUM
iajs-3279	93	55	0.038	0.038	NUM
iajs-3279	93	56	0.040	0.040	NUM
iajs-3279	93	57	38167.942	38167.942	NUM
iajs-3279	93	58	7548.2123	7548.2123	NOUN
iajs-3279	93	59	752.97142	752.97142	NUM
iajs-3279	93	60	85.711243	85.711243	NUM
iajs-3279	93	61	7.81	7.81	NUM
iajs-3279	93	62	262	262	NUM
iajs-3279	93	63	363	363	NUM
iajs-3279	93	64	421	421	NUM
iajs-3279	93	65	700	700	NUM
iajs-3279	93	66	804	804	NUM
iajs-3279	93	67	[	[	X
iajs-3279	93	68	pd(h2l)cl	pd(h2l)cl	X
iajs-3279	93	69	]	]	X
iajs-3279	93	70	square	square	ADJ
iajs-3279	93	71	planer	planer	NOUN
iajs-3279	93	72	20	20	NUM
iajs-3279	93	73	diamagnatic	diamagnatic	ADJ
iajs-3279	93	74	π→π	π→π	PROPN
iajs-3279	93	75	*	*	SYM
iajs-3279	93	76	n→π	n→π	NUM
iajs-3279	93	77	*	*	SYM
iajs-3279	93	78	1	1	NUM
iajs-3279	93	79	a1g→	a1g→	PROPN
iajs-3279	93	80	1	1	NUM
iajs-3279	93	81	t1	t1	NOUN
iajs-3279	93	82	g	g	PROPN
iajs-3279	93	83	1	1	NUM
iajs-3279	93	84	a1g→	a1g→	PROPN
iajs-3279	93	85	1	1	NUM
iajs-3279	93	86	t2	t2	NOUN
iajs-3279	93	87	g	g	PROPN
iajs-3279	93	88	1	1	NUM
iajs-3279	93	89	a1g→	a1g→	PROPN
iajs-3279	93	90	3	3	NUM
iajs-3279	93	91	t2	t2	NOUN
iajs-3279	93	92	g	g	PROPN
iajs-3279	93	93	3400	3400	NUM
iajs-3279	93	94	4850	4850	NUM
iajs-3279	93	95	1440	1440	NUM
iajs-3279	93	96	1600	1600	NUM
iajs-3279	93	97	1800	1800	NUM
iajs-3279	93	98	0.340	0.340	NUM
iajs-3279	93	99	0.485	0.485	NUM
iajs-3279	93	100	0.144	0.144	NUM
iajs-3279	93	101	0.160	0.160	NUM
iajs-3279	93	102	0.180	0.180	NUM
iajs-3279	93	103	34722.22	34722.22	NUM
iajs-3279	93	104	26666.66	26666.66	NUM
iajs-3279	93	105	16260.16	16260.16	NUM
iajs-3279	93	106	15822.78	15822.78	NUM
iajs-3279	93	107	14705.88	14705.88	NUM
iajs-3279	93	108	288	288	NUM
iajs-3279	93	109	375	375	NUM
iajs-3279	93	110	615	615	NUM
iajs-3279	93	111	632	632	NUM
iajs-3279	93	112	680	680	NUM
iajs-3279	94	1	[	[	X
iajs-3279	94	2	pt(h2l)cl3]o	pt(h2l)cl3]o	PROPN
iajs-3279	94	3	octahedral	octahedral	ADJ
iajs-3279	94	4	ihjpas	ihjpa	NOUN
iajs-3279	94	5	.	.	PUNCT
iajs-3279	95	1	37(2)2024	37(2)2024	NUM
iajs-3279	95	2	249	249	NUM
iajs-3279	95	3	3.3	3.3	NUM
iajs-3279	95	4	the	the	DET
iajs-3279	95	5	lc	lc	NOUN
iajs-3279	95	6	-	-	PUNCT
iajs-3279	95	7	mass	mass	NOUN
iajs-3279	95	8	spectrum	spectrum	NOUN
iajs-3279	95	9	of	of	ADP
iajs-3279	95	10	complexes	complex	NOUN
iajs-3279	95	11	the	the	DET
iajs-3279	95	12	lc	lc	NOUN
iajs-3279	95	13	-	-	PUNCT
iajs-3279	95	14	mass	mass	NOUN
iajs-3279	95	15	spectrum	spectrum	NOUN
iajs-3279	95	16	of	of	ADP
iajs-3279	95	17	the	the	DET
iajs-3279	95	18	products	product	NOUN
iajs-3279	95	19	were	be	AUX
iajs-3279	95	20	tested	test	VERB
iajs-3279	95	21	using	use	VERB
iajs-3279	95	22	lc	lc	NOUN
iajs-3279	95	23	-	-	PUNCT
iajs-3279	95	24	mass	mass	NOUN
iajs-3279	95	25	device	device	NOUN
iajs-3279	95	26	,	,	PUNCT
iajs-3279	95	27	this	this	DET
iajs-3279	95	28	approach	approach	NOUN
iajs-3279	95	29	is	be	AUX
iajs-3279	95	30	one	one	NUM
iajs-3279	95	31	of	of	ADP
iajs-3279	95	32	the	the	DET
iajs-3279	95	33	most	most	ADV
iajs-3279	95	34	essential	essential	ADJ
iajs-3279	95	35	approaches	approach	NOUN
iajs-3279	95	36	in	in	ADP
iajs-3279	95	37	characterization	characterization	NOUN
iajs-3279	95	38	and	and	CCONJ
iajs-3279	95	39	complementary	complementary	ADJ
iajs-3279	95	40	for	for	ADP
iajs-3279	95	41	the	the	DET
iajs-3279	95	42	rest	rest	NOUN
iajs-3279	95	43	approaches	approach	NOUN
iajs-3279	95	44	by	by	ADP
iajs-3279	95	45	which	which	PRON
iajs-3279	95	46	the	the	DET
iajs-3279	95	47	molecular	molecular	ADJ
iajs-3279	95	48	weight	weight	NOUN
iajs-3279	95	49	of	of	ADP
iajs-3279	95	50	the	the	DET
iajs-3279	95	51	compound	compound	NOUN
iajs-3279	95	52	is	be	AUX
iajs-3279	95	53	estimated	estimate	VERB
iajs-3279	95	54	according	accord	VERB
iajs-3279	95	55	to	to	ADP
iajs-3279	95	56	the	the	DET
iajs-3279	95	57	relation	relation	NOUN
iajs-3279	95	58	(	(	PUNCT
iajs-3279	95	59	m	m	PROPN
iajs-3279	95	60	/	/	SYM
iajs-3279	95	61	z	z	NOUN
iajs-3279	95	62	)	)	PUNCT
iajs-3279	95	63	.	.	PUNCT
iajs-3279	96	1	for	for	ADP
iajs-3279	96	2	[	[	X
iajs-3279	96	3	ni(h2l)(h2o)2cl	ni(h2l)(h2o)2cl	NOUN
iajs-3279	96	4	]	]	X
iajs-3279	96	5	,	,	PUNCT
iajs-3279	96	6	figure	figure	VERB
iajs-3279	96	7	5	5	NUM
iajs-3279	96	8	and	and	CCONJ
iajs-3279	96	9	scheme	scheme	NOUN
iajs-3279	96	10	3	3	NUM
iajs-3279	96	11	,	,	PUNCT
iajs-3279	96	12	it	it	PRON
iajs-3279	96	13	can	can	AUX
iajs-3279	96	14	also	also	ADV
iajs-3279	96	15	be	be	AUX
iajs-3279	96	16	detected	detect	VERB
iajs-3279	96	17	the	the	DET
iajs-3279	96	18	molecular	molecular	ADJ
iajs-3279	96	19	ion	ion	NOUN
iajs-3279	96	20	peak	peak	NOUN
iajs-3279	96	21	(	(	PUNCT
iajs-3279	96	22	m	m	PROPN
iajs-3279	96	23	+	+	CCONJ
iajs-3279	96	24	)	)	PUNCT
iajs-3279	96	25	at	at	ADP
iajs-3279	96	26	559.99	559.99	NUM
iajs-3279	96	27	m	m	NOUN
iajs-3279	96	28	/	/	SYM
iajs-3279	96	29	z	z	PROPN
iajs-3279	96	30	with	with	ADP
iajs-3279	96	31	the	the	DET
iajs-3279	96	32	relative	relative	ADJ
iajs-3279	96	33	abundance	abundance	NOUN
iajs-3279	96	34	of	of	ADP
iajs-3279	96	35	10	10	NUM
iajs-3279	96	36	%	%	NOUN
iajs-3279	96	37	and	and	CCONJ
iajs-3279	96	38	following	follow	VERB
iajs-3279	96	39	patterns	pattern	NOUN
iajs-3279	96	40	:	:	PUNCT
iajs-3279	96	41	c18h15cln4nio7s	c18h15cln4nio7s	PROPN
iajs-3279	96	42	+	+	X
iajs-3279	96	43	,	,	PUNCT
iajs-3279	96	44	c14h10cln2nio4	c14h10cln2nio4	PROPN
iajs-3279	96	45	•+	•+	NOUN
iajs-3279	96	46	,	,	PUNCT
iajs-3279	96	47	c6h6cln2nio2	c6h6cln2nio2	PROPN
iajs-3279	96	48	•+	•+	NOUN
iajs-3279	96	49	,	,	PUNCT
iajs-3279	96	50	c4h4n2o3s	c4h4n2o3s	NOUN
iajs-3279	96	51	•+	•+	NOUN
iajs-3279	96	52	and	and	CCONJ
iajs-3279	96	53	c8h7o2	c8h7o2	PROPN
iajs-3279	96	54	+	+	CCONJ
iajs-3279	96	55	,	,	PUNCT
iajs-3279	96	56	which	which	PRON
iajs-3279	96	57	corresponded	correspond	VERB
iajs-3279	96	58	to	to	ADP
iajs-3279	96	59	523.97	523.97	NUM
iajs-3279	96	60	m	m	NOUN
iajs-3279	96	61	/	/	SYM
iajs-3279	96	62	z	z	PROPN
iajs-3279	96	63	,	,	PUNCT
iajs-3279	96	64	362.97	362.97	NUM
iajs-3279	96	65	m	m	NOUN
iajs-3279	96	66	/	/	SYM
iajs-3279	96	67	z	z	PROPN
iajs-3279	96	68	,	,	PUNCT
iajs-3279	96	69	230.95	230.95	NUM
iajs-3279	96	70	m	m	NOUN
iajs-3279	96	71	/	/	SYM
iajs-3279	96	72	z	z	PROPN
iajs-3279	96	73	,	,	PUNCT
iajs-3279	96	74	159.99	159.99	NUM
iajs-3279	96	75	m	m	NOUN
iajs-3279	96	76	/	/	SYM
iajs-3279	96	77	z	z	PROPN
iajs-3279	96	78	and	and	CCONJ
iajs-3279	96	79	135.04	135.04	NUM
iajs-3279	96	80	m	m	NOUN
iajs-3279	96	81	/	/	SYM
iajs-3279	96	82	z	z	NOUN
iajs-3279	96	83	respectively	respectively	ADV
iajs-3279	96	84	[	[	X
iajs-3279	96	85	25	25	NUM
iajs-3279	96	86	]	]	PUNCT
iajs-3279	96	87	.	.	PUNCT
iajs-3279	97	1	for	for	ADP
iajs-3279	97	2	[	[	X
iajs-3279	97	3	pd(h2l	pd(h2l	ADJ
iajs-3279	97	4	)	)	PUNCT
iajs-3279	97	5	cl	cl	NOUN
iajs-3279	97	6	]	]	PUNCT
iajs-3279	97	7	complex	complex	NOUN
iajs-3279	97	8	in	in	ADP
iajs-3279	97	9	figure	figure	NOUN
iajs-3279	97	10	6	6	NUM
iajs-3279	97	11	and	and	CCONJ
iajs-3279	97	12	scheme	scheme	VERB
iajs-3279	97	13	4	4	NUM
iajs-3279	97	14	illustrate	illustrate	VERB
iajs-3279	97	15	the	the	DET
iajs-3279	97	16	following	follow	VERB
iajs-3279	97	17	fragments	fragment	NOUN
iajs-3279	97	18	:	:	PUNCT
iajs-3279	97	19	(	(	PUNCT
iajs-3279	97	20	m	m	VERB
iajs-3279	97	21	+	+	CCONJ
iajs-3279	97	22	)	)	PUNCT
iajs-3279	97	23	at	at	ADP
iajs-3279	97	24	571.94	571.94	NUM
iajs-3279	97	25	m	m	NOUN
iajs-3279	97	26	/	/	SYM
iajs-3279	97	27	z	z	PROPN
iajs-3279	97	28	with	with	ADP
iajs-3279	97	29	the	the	DET
iajs-3279	97	30	relative	relative	ADJ
iajs-3279	97	31	abundance	abundance	NOUN
iajs-3279	97	32	of	of	ADP
iajs-3279	97	33	21	21	NUM
iajs-3279	97	34	%	%	NOUN
iajs-3279	97	35	,	,	PUNCT
iajs-3279	97	36	c18h15n4o7pds	c18h15n4o7pds	PROPN
iajs-3279	97	37	•+	•+	PROPN
iajs-3279	97	38	,	,	PUNCT
iajs-3279	97	39	c5h6o3pd	c5h6o3pd	PROPN
iajs-3279	97	40	•+	•+	PROPN
iajs-3279	97	41	,	,	PUNCT
iajs-3279	97	42	c6h5no2s	c6h5no2s	PROPN
iajs-3279	97	43	•+	•+	NOUN
iajs-3279	97	44	,	,	PUNCT
iajs-3279	97	45	c3h4n2o	c3h4n2o	PROPN
iajs-3279	97	46	•+	•+	PROPN
iajs-3279	97	47	,	,	PUNCT
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iajs-3279	97	49	c4h4no	c4h4no	VERB
iajs-3279	98	1	+	+	CCONJ
iajs-3279	98	2	that	that	PRON
iajs-3279	98	3	correspond	correspond	VERB
iajs-3279	98	4	to	to	ADP
iajs-3279	98	5	536.97	536.97	NUM
iajs-3279	98	6	m	m	NOUN
iajs-3279	98	7	/	/	SYM
iajs-3279	98	8	z	z	PROPN
iajs-3279	98	9	,	,	PUNCT
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iajs-3279	98	11	m	m	NOUN
iajs-3279	98	12	/	/	SYM
iajs-3279	98	13	z	z	PROPN
iajs-3279	98	14	,	,	PUNCT
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iajs-3279	98	16	m	m	NOUN
iajs-3279	98	17	/	/	SYM
iajs-3279	98	18	z	z	PROPN
iajs-3279	98	19	,	,	PUNCT
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iajs-3279	98	21	m	m	NOUN
iajs-3279	98	22	/	/	SYM
iajs-3279	98	23	z	z	PROPN
iajs-3279	98	24	and	and	CCONJ
iajs-3279	98	25	82.03	82.03	NUM
iajs-3279	98	26	m	m	PROPN
iajs-3279	98	27	/	/	SYM
iajs-3279	98	28	z	z	NOUN
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iajs-3279	98	30	[	[	X
iajs-3279	98	31	26	26	NUM
iajs-3279	98	32	]	]	PUNCT
iajs-3279	98	33	.	.	PUNCT
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iajs-3279	99	2	,	,	PUNCT
iajs-3279	99	3	[	[	X
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iajs-3279	99	5	]	]	X
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iajs-3279	99	7	in	in	ADP
iajs-3279	99	8	figure	figure	NOUN
iajs-3279	99	9	7	7	NUM
iajs-3279	99	10	and	and	CCONJ
iajs-3279	99	11	scheme	scheme	NOUN
iajs-3279	99	12	5	5	NUM
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iajs-3279	99	14	the	the	DET
iajs-3279	99	15	following	follow	VERB
iajs-3279	99	16	fragments	fragment	NOUN
iajs-3279	99	17	:	:	PUNCT
iajs-3279	99	18	(	(	PUNCT
iajs-3279	99	19	m	m	VERB
iajs-3279	99	20	+	+	CCONJ
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iajs-3279	99	22	at	at	ADP
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iajs-3279	99	24	m	m	NOUN
iajs-3279	99	25	/	/	SYM
iajs-3279	99	26	z	z	PROPN
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iajs-3279	99	28	the	the	DET
iajs-3279	99	29	relative	relative	ADJ
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iajs-3279	99	34	,	,	PUNCT
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iajs-3279	99	36	+	+	X
iajs-3279	99	37	,	,	PUNCT
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iajs-3279	99	39	•+	•+	PROPN
iajs-3279	99	40	,	,	PUNCT
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iajs-3279	99	42	•+	•+	NOUN
iajs-3279	99	43	,	,	PUNCT
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iajs-3279	99	45	•+	•+	PROPN
iajs-3279	99	46	and	and	CCONJ
iajs-3279	99	47	c4h4no	c4h4no	VERB
iajs-3279	100	1	+	+	CCONJ
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iajs-3279	100	4	to	to	ADP
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iajs-3279	100	6	m	m	PROPN
iajs-3279	100	7	/	/	SYM
iajs-3279	100	8	z	z	PROPN
iajs-3279	100	9	,	,	PUNCT
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iajs-3279	100	11	m	m	NOUN
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iajs-3279	100	13	z	z	PROPN
iajs-3279	100	14	,	,	PUNCT
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iajs-3279	100	17	/	/	SYM
iajs-3279	100	18	z	z	PROPN
iajs-3279	100	19	,	,	PUNCT
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iajs-3279	100	21	m	m	NOUN
iajs-3279	100	22	/	/	SYM
iajs-3279	100	23	z	z	PROPN
iajs-3279	100	24	and	and	CCONJ
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iajs-3279	100	26	m	m	PROPN
iajs-3279	100	27	/	/	SYM
iajs-3279	100	28	z	z	NOUN
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iajs-3279	100	30	[	[	X
iajs-3279	100	31	27	27	NUM
iajs-3279	100	32	]	]	PUNCT
iajs-3279	100	33	.	.	PUNCT
iajs-3279	101	1	figure	figure	NOUN
iajs-3279	101	2	5	5	NUM
iajs-3279	101	3	.	.	PUNCT
iajs-3279	101	4	mass	mass	PROPN
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iajs-3279	101	7	ni	ni	NOUN
iajs-3279	101	8	-	-	PUNCT
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iajs-3279	101	10	.	.	PUNCT
iajs-3279	102	1	figure	figure	NOUN
iajs-3279	102	2	6	6	NUM
iajs-3279	102	3	.	.	PUNCT
iajs-3279	102	4	mass	mass	PROPN
iajs-3279	102	5	spectrum	spectrum	NOUN
iajs-3279	102	6	of	of	ADP
iajs-3279	102	7	pd	pd	NOUN
iajs-3279	102	8	-	-	PUNCT
iajs-3279	102	9	complex	complex	NOUN
iajs-3279	102	10	.	.	PUNCT
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iajs-3279	104	4	7	7	NUM
iajs-3279	104	5	.	.	PUNCT
iajs-3279	104	6	mass	mass	PROPN
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iajs-3279	104	8	of	of	ADP
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iajs-3279	104	10	-	-	PUNCT
iajs-3279	104	11	complex	complex	NOUN
iajs-3279	104	12	.	.	PUNCT
iajs-3279	105	1	scheme	scheme	NOUN
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iajs-3279	105	7	of	of	ADP
iajs-3279	105	8	ni	ni	NOUN
iajs-3279	105	9	-	-	PUNCT
iajs-3279	105	10	complex	complex	NOUN
iajs-3279	105	11	.	.	PUNCT
iajs-3279	106	1	scheme	scheme	NOUN
iajs-3279	106	2	5	5	NUM
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iajs-3279	106	7	of	of	ADP
iajs-3279	106	8	pt	pt	NOUN
iajs-3279	106	9	-	-	PUNCT
iajs-3279	106	10	complex	complex	NOUN
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iajs-3279	107	1	scheme	scheme	NOUN
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iajs-3279	107	7	of	of	ADP
iajs-3279	107	8	pd	pd	NOUN
iajs-3279	107	9	-	-	PUNCT
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iajs-3279	107	11	.	.	PUNCT
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iajs-3279	110	9	.	.	PUNCT
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iajs-3279	111	3	(	(	PUNCT
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iajs-3279	111	8	z	z	PROPN
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iajs-3279	111	14	[	[	X
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iajs-3279	111	17	47	47	NUM
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iajs-3279	111	19	[	[	X
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iajs-3279	111	22	+	+	CCONJ
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iajs-3279	111	28	•+	•+	VERB
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iajs-3279	111	38	•+	•+	VERB
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iajs-3279	111	42	•+	•+	VERB
iajs-3279	111	43	[	[	X
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iajs-3279	111	46	+	+	NUM
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iajs-3279	111	54	[	[	X
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iajs-3279	111	57	•+	•+	VERB
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iajs-3279	111	63	•+	•+	VERB
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iajs-3279	111	68	]	]	X
iajs-3279	111	69	•+	•+	VERB
iajs-3279	111	70	35	35	NUM
iajs-3279	111	71	84.03	84.03	NUM
iajs-3279	112	1	[	[	X
iajs-3279	112	2	c3h4n2o	c3h4n2o	X
iajs-3279	112	3	]	]	PUNCT
iajs-3279	112	4	•+	•+	VERB
iajs-3279	112	5	34	34	NUM
iajs-3279	112	6	82.03	82.03	NUM
iajs-3279	112	7	[	[	X
iajs-3279	112	8	c4h4no	c4h4no	X
iajs-3279	112	9	]	]	X
iajs-3279	112	10	+	+	CCONJ
iajs-3279	112	11	29	29	NUM
iajs-3279	112	12	730.94	730.94	NUM
iajs-3279	112	13	[	[	SYM
iajs-3279	112	14	c18h15cl3n4o7pts	c18h15cl3n4o7pt	NOUN
iajs-3279	112	15	]	]	X
iajs-3279	112	16	36	36	NUM
iajs-3279	112	17	626.03	626.03	NUM
iajs-3279	112	18	[	[	X
iajs-3279	112	19	c18h15n4o7pts	c18h15n4o7pts	X
iajs-3279	112	20	]	]	X
iajs-3279	112	21	+	+	CCONJ
iajs-3279	112	22	35	35	NUM
iajs-3279	112	23	309.00	309.00	NUM
iajs-3279	112	24	[	[	X
iajs-3279	112	25	c5h6o3pt	c5h6o3pt	X
iajs-3279	112	26	]	]	PUNCT
iajs-3279	112	27	•+	•+	VERB
iajs-3279	112	28	77	77	NUM
iajs-3279	112	29	155.00	155.00	NUM
iajs-3279	112	30	[	[	X
iajs-3279	112	31	c6h5no2s	c6h5no2s	X
iajs-3279	112	32	]	]	X
iajs-3279	112	33	•+	•+	VERB
iajs-3279	112	34	76	76	NUM
iajs-3279	112	35	84.03	84.03	NUM
iajs-3279	113	1	[	[	X
iajs-3279	113	2	c3h4n2o	c3h4n2o	X
iajs-3279	113	3	]	]	PUNCT
iajs-3279	113	4	•+	•+	VERB
iajs-3279	113	5	87	87	NUM
iajs-3279	113	6	82.03	82.03	NUM
iajs-3279	113	7	[	[	X
iajs-3279	113	8	c4h4no	c4h4no	X
iajs-3279	113	9	]	]	X
iajs-3279	113	10	+	+	CCONJ
iajs-3279	113	11	3.4	3.4	NUM
iajs-3279	113	12	infrared	infrared	ADJ
iajs-3279	113	13	spectra	spectra	ADJ
iajs-3279	113	14	measurements	measurement	NOUN
iajs-3279	113	15	the	the	DET
iajs-3279	113	16	infrared	infrared	ADJ
iajs-3279	113	17	spectra	spectra	NOUN
iajs-3279	113	18	of	of	ADP
iajs-3279	113	19	metal	metal	NOUN
iajs-3279	113	20	complexes	complex	NOUN
iajs-3279	113	21	were	be	AUX
iajs-3279	113	22	recorded	record	VERB
iajs-3279	113	23	with	with	ADP
iajs-3279	113	24	ni	ni	PROPN
iajs-3279	113	25	2	2	PROPN
iajs-3279	113	26	+	+	PROPN
iajs-3279	113	27	,	,	PUNCT
iajs-3279	113	28	zn	zn	PROPN
iajs-3279	113	29	2	2	NUM
iajs-3279	113	30	+	+	NUM
iajs-3279	113	31	,	,	PUNCT
iajs-3279	113	32	pd	pd	PROPN
iajs-3279	113	33	2	2	NUM
iajs-3279	113	34	+	+	NUM
iajs-3279	113	35	and	and	CCONJ
iajs-3279	113	36	pt	pt	NUM
iajs-3279	113	37	4	4	NUM
iajs-3279	113	38	+	+	NUM
iajs-3279	113	39	have	have	AUX
iajs-3279	113	40	been	be	AUX
iajs-3279	113	41	compiled	compile	VERB
iajs-3279	113	42	,	,	PUNCT
iajs-3279	113	43	show	show	VERB
iajs-3279	113	44	in	in	ADP
iajs-3279	113	45	figure	figure	NOUN
iajs-3279	113	46	8	8	NUM
iajs-3279	113	47	for	for	ADP
iajs-3279	113	48	zn	zn	PROPN
iajs-3279	113	49	complex	complex	NOUN
iajs-3279	113	50	,	,	PUNCT
iajs-3279	113	51	figure	figure	NOUN
iajs-3279	113	52	9	9	NUM
iajs-3279	113	53	for	for	ADP
iajs-3279	113	54	pd	pd	PROPN
iajs-3279	113	55	complex	complex	NOUN
iajs-3279	113	56	and	and	CCONJ
iajs-3279	113	57	the	the	DET
iajs-3279	113	58	data	datum	NOUN
iajs-3279	113	59	has	have	AUX
iajs-3279	113	60	been	be	AUX
iajs-3279	113	61	organized	organize	VERB
iajs-3279	113	62	in	in	ADP
iajs-3279	113	63	table	table	NOUN
iajs-3279	113	64	4	4	NUM
iajs-3279	113	65	.	.	PUNCT
iajs-3279	114	1	the	the	DET
iajs-3279	114	2	infrared	infrared	ADJ
iajs-3279	114	3	spectrum	spectrum	NOUN
iajs-3279	114	4	of	of	ADP
iajs-3279	114	5	metal	metal	NOUN
iajs-3279	114	6	complexes	complex	NOUN
iajs-3279	114	7	showed	show	VERB
iajs-3279	114	8	the	the	DET
iajs-3279	114	9	vibration	vibration	NOUN
iajs-3279	114	10	frequencies	frequency	NOUN
iajs-3279	114	11	of	of	ADP
iajs-3279	114	12	the	the	DET
iajs-3279	114	13	double	double	ADJ
iajs-3279	114	14	bond	bond	NOUN
iajs-3279	114	15	n	n	CCONJ
iajs-3279	114	16	=	=	NOUN
iajs-3279	114	17	n	n	NUM
iajs-3279	114	18	;	;	PUNCT
iajs-3279	114	19	this	this	DET
iajs-3279	114	20	band	band	NOUN
iajs-3279	114	21	suffered	suffer	VERB
iajs-3279	114	22	a	a	DET
iajs-3279	114	23	remarkable	remarkable	ADJ
iajs-3279	114	24	change	change	NOUN
iajs-3279	114	25	in	in	ADP
iajs-3279	114	26	shape	shape	NOUN
iajs-3279	114	27	,	,	PUNCT
iajs-3279	114	28	intensity	intensity	NOUN
iajs-3279	114	29	,	,	PUNCT
iajs-3279	114	30	and	and	CCONJ
iajs-3279	114	31	position	position	NOUN
iajs-3279	114	32	in	in	ADP
iajs-3279	114	33	the	the	DET
iajs-3279	114	34	spectra	spectra	NOUN
iajs-3279	114	35	of	of	ADP
iajs-3279	114	36	the	the	DET
iajs-3279	114	37	chelate	chelate	NOUN
iajs-3279	114	38	complexes	complex	NOUN
iajs-3279	114	39	,	,	PUNCT
iajs-3279	114	40	which	which	PRON
iajs-3279	114	41	indicates	indicate	VERB
iajs-3279	114	42	the	the	DET
iajs-3279	114	43	intercalation	intercalation	NOUN
iajs-3279	114	44	of	of	ADP
iajs-3279	114	45	the	the	DET
iajs-3279	114	46	electron	electron	NOUN
iajs-3279	114	47	pair	pair	NOUN
iajs-3279	114	48	of	of	ADP
iajs-3279	114	49	the	the	DET
iajs-3279	114	50	nitrogen	nitrogen	NOUN
iajs-3279	114	51	atom	atom	NOUN
iajs-3279	114	52	of	of	ADP
iajs-3279	114	53	the	the	DET
iajs-3279	114	54	azo	azo	PROPN
iajs-3279	114	55	bridge	bridge	PROPN
iajs-3279	114	56	group	group	NOUN
iajs-3279	114	57	in	in	ADP
iajs-3279	114	58	the	the	DET
iajs-3279	114	59	coordination	coordination	NOUN
iajs-3279	114	60	process	process	NOUN
iajs-3279	114	61	where	where	SCONJ
iajs-3279	114	62	n	n	CCONJ
iajs-3279	114	63	=	=	NOUN
iajs-3279	114	64	n	n	NOUN
iajs-3279	114	65	and	and	CCONJ
iajs-3279	114	66	c	c	NOUN
iajs-3279	114	67	=	=	NOUN
iajs-3279	114	68	o	o	NOUN
iajs-3279	114	69	shift	shift	NOUN
iajs-3279	114	70	,	,	PUNCT
iajs-3279	114	71	oh	oh	INTJ
iajs-3279	114	72	disappears	disappear	VERB
iajs-3279	114	73	and	and	CCONJ
iajs-3279	114	74	oh	oh	INTJ
iajs-3279	114	75	water	water	NOUN
iajs-3279	114	76	bands	band	NOUN
iajs-3279	114	77	appear	appear	VERB
iajs-3279	114	78	in	in	ADP
iajs-3279	114	79	addition	addition	NOUN
iajs-3279	114	80	to	to	ADP
iajs-3279	114	81	the	the	DET
iajs-3279	114	82	emergence	emergence	NOUN
iajs-3279	114	83	of	of	ADP
iajs-3279	114	84	new	new	ADJ
iajs-3279	114	85	packages	package	NOUN
iajs-3279	114	86	called	call	VERB
iajs-3279	114	87	the	the	DET
iajs-3279	114	88	coordination	coordination	NOUN
iajs-3279	114	89	process	process	NOUN
iajs-3279	114	90	,	,	PUNCT
iajs-3279	114	91	which	which	PRON
iajs-3279	114	92	are	be	AUX
iajs-3279	114	93	m	m	NOUN
iajs-3279	114	94	-	-	PUNCT
iajs-3279	114	95	n	n	CCONJ
iajs-3279	114	96	,	,	PUNCT
iajs-3279	114	97	m	m	PROPN
iajs-3279	114	98	-	-	NOUN
iajs-3279	114	99	o	o	NOUN
iajs-3279	114	100	and	and	CCONJ
iajs-3279	114	101	m	m	NOUN
iajs-3279	114	102	-	-	NOUN
iajs-3279	114	103	cl	cl	NOUN
iajs-3279	114	104	.	.	PUNCT
iajs-3279	115	1	after	after	ADP
iajs-3279	115	2	this	this	PRON
iajs-3279	115	3	,	,	PUNCT
iajs-3279	115	4	the	the	DET
iajs-3279	115	5	ir	ir	PROPN
iajs-3279	115	6	spectra	spectra	NOUN
iajs-3279	115	7	of	of	ADP
iajs-3279	115	8	all	all	DET
iajs-3279	115	9	produced	produce	VERB
iajs-3279	115	10	compounds	compound	NOUN
iajs-3279	115	11	revealed	reveal	VERB
iajs-3279	115	12	that	that	SCONJ
iajs-3279	115	13	the	the	DET
iajs-3279	115	14	azo	azo	NOUN
iajs-3279	115	15	-	-	PUNCT
iajs-3279	115	16	dye	dye	NOUN
iajs-3279	115	17	ligand	ligand	NOUN
iajs-3279	115	18	connected	connect	VERB
iajs-3279	115	19	to	to	ADP
iajs-3279	115	20	metal	metal	NOUN
iajs-3279	115	21	ions	ion	NOUN
iajs-3279	115	22	through	through	ADP
iajs-3279	115	23	two	two	NUM
iajs-3279	115	24	sites	site	NOUN
iajs-3279	115	25	:	:	PUNCT
iajs-3279	115	26	the	the	DET
iajs-3279	115	27	azo	azo	PROPN
iajs-3279	115	28	group	group	NOUN
iajs-3279	115	29	's	's	PART
iajs-3279	115	30	nitrogen	nitrogen	NOUN
iajs-3279	115	31	site	site	NOUN
iajs-3279	115	32	,	,	PUNCT
iajs-3279	115	33	and	and	CCONJ
iajs-3279	115	34	oxygen	oxygen	NOUN
iajs-3279	115	35	site	site	NOUN
iajs-3279	115	36	via	via	ADP
iajs-3279	115	37	deprotonation	deprotonation	NOUN
iajs-3279	115	38	of	of	ADP
iajs-3279	115	39	of	of	ADP
iajs-3279	115	40	one	one	NUM
iajs-3279	115	41	of	of	ADP
iajs-3279	115	42	the	the	DET
iajs-3279	115	43	hydroxyl	hydroxyl	NOUN
iajs-3279	115	44	groups	group	NOUN
iajs-3279	115	45	of	of	ADP
iajs-3279	115	46	the	the	DET
iajs-3279	115	47	aromatic	aromatic	ADJ
iajs-3279	115	48	ring	ring	NOUN
iajs-3279	115	49	[	[	X
iajs-3279	115	50	28	28	NUM
iajs-3279	115	51	]	]	PUNCT
iajs-3279	115	52	.	.	PUNCT
iajs-3279	116	1	ihjpas	ihjpas	PROPN
iajs-3279	116	2	.	.	PUNCT
iajs-3279	117	1	37(2)2024	37(2)2024	NUM
iajs-3279	117	2	252	252	NUM
iajs-3279	117	3	figure	figure	NOUN
iajs-3279	117	4	8	8	NUM
iajs-3279	117	5	.	.	PUNCT
iajs-3279	118	1	the	the	DET
iajs-3279	118	2	ft	ft	PROPN
iajs-3279	118	3	-	-	PUNCT
iajs-3279	118	4	ir	ir	NOUN
iajs-3279	118	5	spectrum	spectrum	NOUN
iajs-3279	118	6	of	of	ADP
iajs-3279	118	7	zn	zn	PROPN
iajs-3279	118	8	-	-	PUNCT
iajs-3279	118	9	complex	complex	ADJ
iajs-3279	118	10	.	.	PUNCT
iajs-3279	119	1	figure	figure	NOUN
iajs-3279	119	2	9	9	NUM
iajs-3279	119	3	.	.	PUNCT
iajs-3279	120	1	the	the	DET
iajs-3279	120	2	ft	ft	PROPN
iajs-3279	120	3	-	-	PUNCT
iajs-3279	120	4	ir	ir	NOUN
iajs-3279	120	5	spectrum	spectrum	NOUN
iajs-3279	120	6	of	of	ADP
iajs-3279	120	7	pd	pd	NOUN
iajs-3279	120	8	-	-	PUNCT
iajs-3279	120	9	complex	complex	ADJ
iajs-3279	120	10	.	.	PUNCT
iajs-3279	120	11	table	table	NOUN
iajs-3279	120	12	4	4	NUM
iajs-3279	120	13	.	.	PUNCT
iajs-3279	121	1	the	the	DET
iajs-3279	121	2	ir	ir	PROPN
iajs-3279	121	3	spectral	spectral	PROPN
iajs-3279	121	4	data	datum	NOUN
iajs-3279	121	5	(	(	PUNCT
iajs-3279	121	6	cm	cm	NOUN
iajs-3279	121	7	-1	-1	NOUN
iajs-3279	121	8	)	)	PUNCT
iajs-3279	121	9	of	of	ADP
iajs-3279	121	10	complexes	complex	NOUN
iajs-3279	121	11	.	.	PUNCT
iajs-3279	122	1	m	m	NOUN
iajs-3279	122	2	-	-	PUNCT
iajs-3279	122	3	n	n	PRON
iajs-3279	122	4	m	m	PROPN
iajs-3279	122	5	-	-	NOUN
iajs-3279	122	6	o	o	NOUN
iajs-3279	122	7	m	m	NOUN
iajs-3279	122	8	-	-	NOUN
iajs-3279	122	9	cl	cl	ADJ
iajs-3279	122	10	ν	ν	NOUN
iajs-3279	122	11	(	(	PUNCT
iajs-3279	122	12	so2	so2	PROPN
iajs-3279	122	13	)	)	PUNCT
iajs-3279	122	14	ν	ν	NOUN
iajs-3279	122	15	(	(	PUNCT
iajs-3279	122	16	n	n	CCONJ
iajs-3279	122	17	=	=	SYM
iajs-3279	122	18	n	n	CCONJ
iajs-3279	122	19	)	)	PUNCT
iajs-3279	122	20	ν	ν	NOUN
iajs-3279	122	21	(	(	PUNCT
iajs-3279	122	22	c	c	NOUN
iajs-3279	122	23	=	=	NOUN
iajs-3279	122	24	o	o	NOUN
iajs-3279	122	25	)	)	PUNCT
iajs-3279	122	26	ν	ν	NOUN
iajs-3279	122	27	(	(	PUNCT
iajs-3279	122	28	c	c	NOUN
iajs-3279	122	29	-	-	PUNCT
iajs-3279	122	30	h	h	NOUN
iajs-3279	122	31	)	)	PUNCT
iajs-3279	122	32	aromatic	aromatic	ADJ
iajs-3279	122	33	aliphatic	aliphatic	ADJ
iajs-3279	122	34	ν	ν	NOUN
iajs-3279	122	35	(	(	PUNCT
iajs-3279	122	36	nh	nh	NOUN
iajs-3279	122	37	)	)	PUNCT
iajs-3279	122	38	ν	ν	NOUN
iajs-3279	122	39	(	(	PUNCT
iajs-3279	122	40	oh	oh	INTJ
iajs-3279	122	41	)	)	PUNCT
iajs-3279	122	42	phenolic	phenolic	NOUN
iajs-3279	122	43	ν	ν	NOUN
iajs-3279	122	44	(	(	PUNCT
iajs-3279	122	45	h2o	h2o	PROPN
iajs-3279	122	46	)	)	PUNCT
iajs-3279	122	47	aqua	aqua	NOUN
iajs-3279	122	48	compounds	compound	VERB
iajs-3279	122	49	507	507	NUM
iajs-3279	122	50	459	459	NUM
iajs-3279	122	51	369	369	NUM
iajs-3279	122	52	1088	1088	NUM
iajs-3279	122	53	1008	1008	NUM
iajs-3279	122	54	1471	1471	NUM
iajs-3279	122	55	1612	1612	NUM
iajs-3279	122	56	3067	3067	NUM
iajs-3279	122	57	2980	2980	NUM
iajs-3279	122	58	3287	3287	NUM
iajs-3279	122	59	3506	3506	NUM
iajs-3279	122	60	3757	3757	NUM
iajs-3279	122	61	ni(h2l)(h2o)2cl	ni(h2l)(h2o)2cl	NOUN
iajs-3279	122	62	]	]	X
iajs-3279	122	63	]	]	X
iajs-3279	122	64	528	528	NUM
iajs-3279	122	65	403	403	NUM
iajs-3279	122	66	331	331	NUM
iajs-3279	122	67	1088	1088	NUM
iajs-3279	122	68	1015	1015	NUM
iajs-3279	122	69	1467	1467	NUM
iajs-3279	122	70	1633	1633	NUM
iajs-3279	122	71	3061	3061	NUM
iajs-3279	122	72	2979	2979	NUM
iajs-3279	122	73	3281	3281	NUM
iajs-3279	122	74	3503	3503	NUM
iajs-3279	122	75	3739	3739	NUM
iajs-3279	122	76	zn(h2l)(h2o)cl	zn(h2l)(h2o)cl	NOUN
iajs-3279	122	77	]	]	X
iajs-3279	122	78	]	]	X
iajs-3279	122	79	510	510	NUM
iajs-3279	122	80	433	433	NUM
iajs-3279	122	81	370	370	NUM
iajs-3279	122	82	1087	1087	NUM
iajs-3279	122	83	1470	1470	NUM
iajs-3279	122	84	1607	1607	NUM
iajs-3279	122	85	3063	3063	NUM
iajs-3279	122	86	2983	2983	NUM
iajs-3279	122	87	3284	3284	NUM
iajs-3279	122	88	3514	3514	NUM
iajs-3279	122	89	_	_	PUNCT
iajs-3279	123	1	[	[	X
iajs-3279	123	2	pd(h2l)cl	pd(h2l)cl	X
iajs-3279	123	3	]	]	X
iajs-3279	123	4	514	514	NUM
iajs-3279	123	5	405	405	NUM
iajs-3279	123	6	324	324	NUM
iajs-3279	123	7	1094	1094	NUM
iajs-3279	123	8	1009	1009	NUM
iajs-3279	123	9	1470	1470	NUM
iajs-3279	123	10	1608	1608	NUM
iajs-3279	123	11	3057	3057	NUM
iajs-3279	123	12	2978	2978	NUM
iajs-3279	123	13	3289	3289	NUM
iajs-3279	123	14	3489	3489	NUM
iajs-3279	124	1	_	_	PUNCT
iajs-3279	125	1	[	[	X
iajs-3279	125	2	pt(h2l)cl3	pt(h2l)cl3	X
iajs-3279	125	3	]	]	X
iajs-3279	125	4	ihjpas	ihjpas	PROPN
iajs-3279	125	5	.	.	PUNCT
iajs-3279	126	1	37(2)2024	37(2)2024	NUM
iajs-3279	126	2	253	253	NUM
iajs-3279	126	3	3.5	3.5	NUM
iajs-3279	126	4	thermalstudy	thermalstudy	NOUN
iajs-3279	126	5	data	datum	NOUN
iajs-3279	126	6	the	the	DET
iajs-3279	126	7	results	result	NOUN
iajs-3279	126	8	obtained	obtain	VERB
iajs-3279	126	9	for	for	ADP
iajs-3279	126	10	the	the	DET
iajs-3279	126	11	thermal	thermal	ADJ
iajs-3279	126	12	analysis	analysis	NOUN
iajs-3279	126	13	for	for	ADP
iajs-3279	126	14	ligand	ligand	NOUN
iajs-3279	126	15	(	(	PUNCT
iajs-3279	126	16	h3l	h3l	NOUN
iajs-3279	126	17	)	)	PUNCT
iajs-3279	126	18	and	and	CCONJ
iajs-3279	126	19	their	their	PRON
iajs-3279	126	20	synthesized	synthesize	VERB
iajs-3279	126	21	complexes	complex	NOUN
iajs-3279	126	22	were	be	AUX
iajs-3279	126	23	displayed	display	VERB
iajs-3279	126	24	in	in	ADP
iajs-3279	126	25	tables	table	NOUN
iajs-3279	126	26	5	5	NUM
iajs-3279	126	27	and	and	CCONJ
iajs-3279	126	28	6	6	NUM
iajs-3279	126	29	,	,	PUNCT
iajs-3279	126	30	and	and	CCONJ
iajs-3279	126	31	figures	figure	VERB
iajs-3279	126	32	10	10	NUM
iajs-3279	126	33	-	-	SYM
iajs-3279	126	34	13	13	NUM
iajs-3279	126	35	respectively	respectively	ADV
iajs-3279	126	36	.	.	PUNCT
iajs-3279	127	1	tentative	tentative	ADJ
iajs-3279	127	2	decomposition	decomposition	NOUN
iajs-3279	127	3	reaction	reaction	NOUN
iajs-3279	127	4	of	of	ADP
iajs-3279	127	5	metal	metal	NOUN
iajs-3279	127	6	complexes	complex	NOUN
iajs-3279	127	7	summarize	summarize	VERB
iajs-3279	127	8	in	in	ADP
iajs-3279	127	9	schemes	scheme	NOUN
iajs-3279	127	10	6	6	NUM
iajs-3279	127	11	.	.	PUNCT
iajs-3279	127	12	decomposition	decomposition	NOUN
iajs-3279	127	13	stages	stage	NOUN
iajs-3279	127	14	,	,	PUNCT
iajs-3279	127	15	temperature	temperature	NOUN
iajs-3279	127	16	ranges	range	NOUN
iajs-3279	127	17	,	,	PUNCT
iajs-3279	127	18	decomposition	decomposition	NOUN
iajs-3279	127	19	products	product	NOUN
iajs-3279	127	20	,	,	PUNCT
iajs-3279	127	21	and	and	CCONJ
iajs-3279	127	22	weight	weight	NOUN
iajs-3279	127	23	loss	loss	NOUN
iajs-3279	127	24	complex	complex	ADJ
iajs-3279	127	25	percentages	percentage	NOUN
iajs-3279	127	26	were	be	AUX
iajs-3279	127	27	computed	compute	VERB
iajs-3279	127	28	based	base	VERB
iajs-3279	127	29	on	on	ADP
iajs-3279	127	30	the	the	DET
iajs-3279	127	31	thermograms	thermogram	NOUN
iajs-3279	127	32	,	,	PUNCT
iajs-3279	127	33	and	and	CCONJ
iajs-3279	127	34	they	they	PRON
iajs-3279	127	35	showed	show	VERB
iajs-3279	127	36	agreement	agreement	NOUN
iajs-3279	127	37	.	.	PUNCT
iajs-3279	128	1	between	between	ADP
iajs-3279	128	2	their	their	PRON
iajs-3279	128	3	thermal	thermal	ADJ
iajs-3279	128	4	decomposition	decomposition	NOUN
iajs-3279	128	5	results	result	NOUN
iajs-3279	128	6	and	and	CCONJ
iajs-3279	128	7	calculated	calculate	VERB
iajs-3279	128	8	values	value	NOUN
iajs-3279	128	9	,	,	PUNCT
iajs-3279	128	10	that	that	PRON
iajs-3279	128	11	validates	validate	VERB
iajs-3279	128	12	elemental	elemental	ADJ
iajs-3279	128	13	analysis	analysis	NOUN
iajs-3279	128	14	results	result	NOUN
iajs-3279	128	15	and	and	CCONJ
iajs-3279	128	16	suggested	suggest	VERB
iajs-3279	128	17	equations	equation	NOUN
iajs-3279	128	18	[	[	X
iajs-3279	128	19	29	29	NUM
iajs-3279	128	20	]	]	PUNCT
iajs-3279	128	21	.	.	PUNCT
iajs-3279	129	1	in	in	ADP
iajs-3279	129	2	this	this	DET
iajs-3279	129	3	work	work	NOUN
iajs-3279	129	4	,	,	PUNCT
iajs-3279	129	5	it	it	PRON
iajs-3279	129	6	was	be	AUX
iajs-3279	129	7	noted	note	VERB
iajs-3279	129	8	that	that	SCONJ
iajs-3279	129	9	the	the	DET
iajs-3279	129	10	remaining	remain	VERB
iajs-3279	129	11	ligand	ligand	NOUN
iajs-3279	129	12	was	be	AUX
iajs-3279	129	13	carbon	carbon	NOUN
iajs-3279	129	14	and	and	CCONJ
iajs-3279	129	15	the	the	DET
iajs-3279	129	16	remaining	remain	VERB
iajs-3279	129	17	metal	metal	NOUN
iajs-3279	129	18	oxide	oxide	NOUN
iajs-3279	129	19	in	in	ADP
iajs-3279	129	20	the	the	DET
iajs-3279	129	21	ligand	ligand	ADJ
iajs-3279	129	22	and	and	CCONJ
iajs-3279	129	23	metal	metal	NOUN
iajs-3279	129	24	complexes	complex	NOUN
iajs-3279	129	25	of	of	ADP
iajs-3279	129	26	ni	ni	PROPN
iajs-3279	129	27	2	2	PROPN
iajs-3279	129	28	+	+	PROPN
iajs-3279	129	29	,	,	PUNCT
iajs-3279	129	30	pd	pd	PROPN
iajs-3279	129	31	2	2	NUM
iajs-3279	129	32	+	+	NUM
iajs-3279	129	33	and	and	CCONJ
iajs-3279	129	34	pt	pt	INTJ
iajs-3279	129	35	4	4	NUM
iajs-3279	129	36	+	+	NUM
iajs-3279	129	37	.	.	PUNCT
iajs-3279	130	1	according	accord	VERB
iajs-3279	130	2	to	to	ADP
iajs-3279	130	3	the	the	DET
iajs-3279	130	4	results	result	NOUN
iajs-3279	130	5	of	of	ADP
iajs-3279	130	6	the	the	DET
iajs-3279	130	7	thermo	thermo	NOUN
iajs-3279	130	8	gravimetric	gravimetric	ADJ
iajs-3279	130	9	tests	test	NOUN
iajs-3279	130	10	,	,	PUNCT
iajs-3279	130	11	the	the	DET
iajs-3279	130	12	complexes	complex	NOUN
iajs-3279	130	13	and	and	CCONJ
iajs-3279	130	14	the	the	DET
iajs-3279	130	15	ligand	ligand	NOUN
iajs-3279	130	16	decompose	decompose	NOUN
iajs-3279	130	17	in	in	ADP
iajs-3279	130	18	(	(	PUNCT
iajs-3279	130	19	1	1	NUM
iajs-3279	130	20	to	to	PART
iajs-3279	130	21	4	4	NUM
iajs-3279	130	22	)	)	PUNCT
iajs-3279	130	23	phases	phase	NOUN
iajs-3279	130	24	.	.	PUNCT
iajs-3279	131	1	the	the	DET
iajs-3279	131	2	thermodynamic	thermodynamic	ADJ
iajs-3279	131	3	parameters	parameter	NOUN
iajs-3279	131	4	δh	δh	ADP
iajs-3279	131	5	,	,	PUNCT
iajs-3279	131	6	δs	δs	NOUN
iajs-3279	131	7	and	and	CCONJ
iajs-3279	131	8	δg	δg	PROPN
iajs-3279	131	9	were	be	AUX
iajs-3279	131	10	computed	compute	VERB
iajs-3279	131	11	using	use	VERB
iajs-3279	131	12	the	the	DET
iajs-3279	131	13	dcs	dcs	PROPN
iajs-3279	131	14	curve	curve	PROPN
iajs-3279	131	15	.	.	PUNCT
iajs-3279	132	1	figure	figure	NOUN
iajs-3279	132	2	10	10	NUM
iajs-3279	132	3	.	.	PUNCT
iajs-3279	133	1	the	the	DET
iajs-3279	133	2	tga	tga	PROPN
iajs-3279	133	3	and	and	CCONJ
iajs-3279	133	4	dsc	dsc	NOUN
iajs-3279	133	5	curve	curve	NOUN
iajs-3279	133	6	of	of	ADP
iajs-3279	133	7	ligand	ligand	NOUN
iajs-3279	133	8	(	(	PUNCT
iajs-3279	133	9	h3l	h3l	NOUN
iajs-3279	133	10	)	)	PUNCT
iajs-3279	133	11	.	.	PUNCT
iajs-3279	134	1	figure	figure	VERB
iajs-3279	134	2	11	11	NUM
iajs-3279	134	3	.	.	PUNCT
iajs-3279	135	1	the	the	DET
iajs-3279	135	2	tga	tga	PROPN
iajs-3279	135	3	and	and	CCONJ
iajs-3279	135	4	dsc	dsc	NOUN
iajs-3279	135	5	curve	curve	NOUN
iajs-3279	135	6	of	of	ADP
iajs-3279	135	7	ni	ni	NOUN
iajs-3279	135	8	-	-	PUNCT
iajs-3279	135	9	complex	complex	NOUN
iajs-3279	135	10	.	.	PUNCT
iajs-3279	136	1	ihjpas	ihjpas	PROPN
iajs-3279	136	2	.	.	PUNCT
iajs-3279	137	1	37(2)2024	37(2)2024	NUM
iajs-3279	137	2	254	254	NUM
iajs-3279	137	3	figure	figure	NOUN
iajs-3279	137	4	12	12	NUM
iajs-3279	137	5	.	.	PUNCT
iajs-3279	138	1	the	the	DET
iajs-3279	138	2	tga	tga	PROPN
iajs-3279	138	3	and	and	CCONJ
iajs-3279	138	4	dsc	dsc	NOUN
iajs-3279	138	5	curve	curve	NOUN
iajs-3279	138	6	of	of	ADP
iajs-3279	138	7	pd	pd	ADJ
iajs-3279	138	8	-	-	PUNCT
iajs-3279	138	9	complex	complex	ADJ
iajs-3279	138	10	figure	figure	NOUN
iajs-3279	138	11	13	13	NUM
iajs-3279	138	12	.	.	PUNCT
iajs-3279	139	1	the	the	DET
iajs-3279	139	2	tga	tga	PROPN
iajs-3279	139	3	and	and	CCONJ
iajs-3279	139	4	dsc	dsc	NOUN
iajs-3279	139	5	curve	curve	NOUN
iajs-3279	139	6	of	of	ADP
iajs-3279	139	7	pt	pt	NOUN
iajs-3279	139	8	-	-	PUNCT
iajs-3279	139	9	complex	complex	NOUN
iajs-3279	139	10	.	.	PUNCT
iajs-3279	140	1	scheme	scheme	NOUN
iajs-3279	140	2	6	6	NUM
iajs-3279	140	3	.	.	PUNCT
iajs-3279	140	4	tentative	tentative	ADJ
iajs-3279	140	5	decomposition	decomposition	NOUN
iajs-3279	140	6	reaction	reaction	NOUN
iajs-3279	140	7	of	of	ADP
iajs-3279	140	8	ligand	ligand	ADJ
iajs-3279	140	9	and	and	CCONJ
iajs-3279	140	10	metal	metal	NOUN
iajs-3279	140	11	complexes	complex	NOUN
iajs-3279	140	12	.	.	PUNCT
iajs-3279	141	1	ihjpas	ihjpas	PROPN
iajs-3279	141	2	.	.	PUNCT
iajs-3279	142	1	37(2)2024	37(2)2024	NUM
iajs-3279	142	2	255	255	NUM
iajs-3279	142	3	table	table	NOUN
iajs-3279	142	4	5	5	NUM
iajs-3279	142	5	.	.	PUNCT
iajs-3279	143	1	the	the	DET
iajs-3279	143	2	tga	tga	PROPN
iajs-3279	143	3	data	datum	NOUN
iajs-3279	143	4	of	of	ADP
iajs-3279	143	5	the	the	DET
iajs-3279	143	6	ligand	ligand	ADJ
iajs-3279	143	7	h3l	h3l	PROPN
iajs-3279	143	8	and	and	CCONJ
iajs-3279	143	9	some	some	DET
iajs-3279	143	10	complexes	complex	NOUN
iajs-3279	143	11	.	.	PUNCT
iajs-3279	144	1	reaction	reaction	NOUN
iajs-3279	144	2	weight	weight	NOUN
iajs-3279	144	3	mass	mass	NOUN
iajs-3279	144	4	loss%	loss%	PUNCT
iajs-3279	144	5	tmax	tmax	ADP
iajs-3279	144	6	tf/	tf/	ADV
iajs-3279	144	7	°	°	ADP
iajs-3279	144	8	c	c	NOUN
iajs-3279	144	9	ti/	ti/	NOUN
iajs-3279	144	10	°	°	NOUN
iajs-3279	144	11	c	c	NOUN
iajs-3279	144	12	step	step	NOUN
iajs-3279	144	13	complexes	complex	NOUN
iajs-3279	144	14	found	find	VERB
iajs-3279	144	15	calc	calc	NOUN
iajs-3279	144	16	-c17h16n4o7s	-c17h16n4o7s	PROPN
iajs-3279	144	17	97.7560	97.7560	NUM
iajs-3279	144	18	97.2248	97.2248	NUM
iajs-3279	144	19	347.362	347.362	NUM
iajs-3279	144	20	597.747	597.747	NUM
iajs-3279	144	21	111.021	111.021	NUM
iajs-3279	144	22	1	1	NUM
iajs-3279	144	23	ligand	ligand	NOUN
iajs-3279	145	1	c	c	NOUN
iajs-3279	145	2	calculated:97.2248%final=2.7752%;estimated97.7560%final=2.244	calculated:97.2248%final=2.7752%;estimated97.7560%final=2.244	NOUN
iajs-3279	146	1	%	%	NOUN
iajs-3279	146	2	-2h2o	-2h2o	VERB
iajs-3279	146	3	5.5804	5.5804	NUM
iajs-3279	146	4	6.4286	6.4286	NUM
iajs-3279	146	5	76.362	76.362	NUM
iajs-3279	146	6	100.044	100.044	NUM
iajs-3279	146	7	32.102	32.102	NUM
iajs-3279	146	8	1	1	NUM
iajs-3279	146	9	ni	ni	ADJ
iajs-3279	146	10	-	-	PUNCT
iajs-3279	146	11	complex	complex	ADJ
iajs-3279	146	12	-cl	-cl	NOUN
iajs-3279	146	13	,	,	PUNCT
iajs-3279	146	14	-so2	-so2	PROPN
iajs-3279	146	15	17.1778	17.1778	NUM
iajs-3279	146	16	17.7681	17.7681	NUM
iajs-3279	146	17	149.952	149.952	NUM
iajs-3279	146	18	207.473	207.473	NUM
iajs-3279	146	19	100.011	100.011	NUM
iajs-3279	146	20	2	2	NUM
iajs-3279	146	21	-c8h6n2o	-c8h6n2o	SYM
iajs-3279	146	22	27.5320	27.5320	NUM
iajs-3279	146	23	26.0718	26.0718	NUM
iajs-3279	146	24	288.764	288.764	NUM
iajs-3279	146	25	349.75	349.75	NUM
iajs-3279	146	26	208.223	208.223	NUM
iajs-3279	146	27	3	3	NUM
iajs-3279	146	28	-c10h9n2o3	-c10h9n2o3	PROPN
iajs-3279	146	29	35.7711	35.7711	NUM
iajs-3279	146	30	36.6077	36.6077	NUM
iajs-3279	146	31	480.362	480.362	NUM
iajs-3279	146	32	593.805	593.805	NUM
iajs-3279	146	33	350.412	350.412	NUM
iajs-3279	146	34	4	4	NUM
iajs-3279	146	35	oni	oni	NOUN
iajs-3279	146	36	calculated:86.8762	calculated:86.8762	NOUN
iajs-3279	146	37	%	%	NOUN
iajs-3279	146	38	final	final	ADJ
iajs-3279	146	39	=	=	NUM
iajs-3279	146	40	13.1238%;estimated	13.1238%;estimated	NUM
iajs-3279	146	41	86.0613	86.0613	NUM
iajs-3279	146	42	%	%	NOUN
iajs-3279	146	43	final	final	ADJ
iajs-3279	146	44	=	=	NOUN
iajs-3279	146	45	13.9387	13.9387	NUM
iajs-3279	146	46	%	%	NOUN
iajs-3279	146	47	-cl,-2co2,co	-cl,-2co2,co	NOUN
iajs-3279	146	48	,	,	PUNCT
iajs-3279	146	49	n2o	n2o	NOUN
iajs-3279	146	50	33.7361	33.7361	NUM
iajs-3279	146	51	34.1819	34.1819	NUM
iajs-3279	146	52	301.762	301.762	NUM
iajs-3279	146	53	393.362	393.362	NUM
iajs-3279	146	54	268.200	268.200	NUM
iajs-3279	146	55	1	1	NUM
iajs-3279	146	56	pd	pd	NOUN
iajs-3279	146	57	-	-	PUNCT
iajs-3279	146	58	complex	complex	ADJ
iajs-3279	146	59	-c15h15n2s	-c15h15n2s	PROPN
iajs-3279	146	60	43.3984	43.3984	NUM
iajs-3279	146	61	42.8366	42.8366	NUM
iajs-3279	146	62	476.453	476.453	NUM
iajs-3279	146	63	593.384	593.384	NUM
iajs-3279	146	64	402.998	402.998	NUM
iajs-3279	146	65	2	2	NUM
iajs-3279	146	66	opd	opd	PROPN
iajs-3279	146	67	calculated:77.0185	calculated:77.0185	PROPN
iajs-3279	146	68	%	%	NOUN
iajs-3279	146	69	final	final	ADJ
iajs-3279	146	70	=	=	NUM
iajs-3279	146	71	22.9815%;estimated	22.9815%;estimate	VERB
iajs-3279	146	72	77.1345	77.1345	NUM
iajs-3279	146	73	%	%	NOUN
iajs-3279	146	74	final	final	ADJ
iajs-3279	146	75	=	=	NOUN
iajs-3279	146	76	22.8655	22.8655	NUM
iajs-3279	146	77	%	%	NOUN
iajs-3279	146	78	-cl3,-so2,2co2	-cl3,-so2,2co2	NOUN
iajs-3279	146	79	,	,	PUNCT
iajs-3279	146	80	-c7h6n2	-c7h6n2	NUM
iajs-3279	146	81	49.8662	49.8662	NUM
iajs-3279	146	82	51.5090	51.5090	NUM
iajs-3279	146	83	207.936	207.936	NUM
iajs-3279	146	84	331.868	331.868	NUM
iajs-3279	146	85	132.111	132.111	NUM
iajs-3279	146	86	1	1	NUM
iajs-3279	146	87	pt	pt	NOUN
iajs-3279	146	88	-	-	PUNCT
iajs-3279	146	89	complex	complex	NOUN
iajs-3279	146	90	-c9h9n2	-c9h9n2	PUNCT
iajs-3279	146	91	20.5410	20.5410	NUM
iajs-3279	146	92	19.8374	19.8374	NUM
iajs-3279	146	93	461.395	461.395	NUM
iajs-3279	146	94	590.862	590.862	NUM
iajs-3279	146	95	331.001	331.001	NUM
iajs-3279	146	96	2	2	NUM
iajs-3279	146	97	opt	opt	VERB
iajs-3279	146	98	calculated:71.3464	calculated:71.3464	ADV
iajs-3279	146	99	%	%	NOUN
iajs-3279	146	100	final	final	ADJ
iajs-3279	146	101	=	=	NUM
iajs-3279	146	102	28.6536%;estimated	28.6536%;estimate	VERB
iajs-3279	146	103	70.4072	70.4072	NUM
iajs-3279	146	104	%	%	NOUN
iajs-3279	146	105	final	final	ADJ
iajs-3279	146	106	=	=	NOUN
iajs-3279	146	107	29.5928	29.5928	NUM
iajs-3279	146	108	%	%	NOUN
iajs-3279	146	109	table	table	NOUN
iajs-3279	146	110	6	6	NUM
iajs-3279	146	111	.	.	PUNCT
iajs-3279	146	112	thermal	thermal	ADJ
iajs-3279	146	113	decomposition	decomposition	NOUN
iajs-3279	146	114	dsc	dsc	NOUN
iajs-3279	146	115	of	of	ADP
iajs-3279	146	116	ligand	ligand	NOUN
iajs-3279	146	117	and	and	CCONJ
iajs-3279	146	118	some	some	DET
iajs-3279	146	119	complexes	complex	NOUN
iajs-3279	146	120	.	.	PUNCT
iajs-3279	147	1	type	type	NOUN
iajs-3279	147	2	δg	δg	PROPN
iajs-3279	147	3	j	j	PROPN
iajs-3279	147	4	/	/	SYM
iajs-3279	147	5	mol	mol	ADP
iajs-3279	147	6	δs	δs	PROPN
iajs-3279	147	7	j	j	PROPN
iajs-3279	147	8	/	/	SYM
iajs-3279	147	9	k.mol	k.mol	PROPN
iajs-3279	147	10	δh	δh	ADP
iajs-3279	147	11	j	j	PROPN
iajs-3279	147	12	/	/	SYM
iajs-3279	147	13	mol	mol	ADP
iajs-3279	147	14	maximum	maximum	ADJ
iajs-3279	147	15	temperature	temperature	NOUN
iajs-3279	147	16	point	point	NOUN
iajs-3279	147	17	°	°	ADP
iajs-3279	147	18	c	c	NOUN
iajs-3279	147	19	tf/	tf/	ADV
iajs-3279	147	20	°	°	NOUN
iajs-3279	147	21	c	c	NOUN
iajs-3279	147	22	ti/	ti/	NOUN
iajs-3279	147	23	°	°	NOUN
iajs-3279	147	24	c	c	NOUN
iajs-3279	147	25	compound	compound	NOUN
iajs-3279	147	26	endothermic	endothermic	NOUN
iajs-3279	147	27	694.399	694.399	NUM
iajs-3279	147	28	-1.804	-1.804	NOUN
iajs-3279	147	29	-13.49	-13.49	NUM
iajs-3279	147	30	392.40	392.40	NUM
iajs-3279	147	31	395.13	395.13	NUM
iajs-3279	147	32	387.65	387.65	NUM
iajs-3279	147	33	l3h	l3h	ADP
iajs-3279	147	34	endothermic	endothermic	PROPN
iajs-3279	147	35	38.6225	38.6225	NUM
iajs-3279	147	36	-0.8431	-0.8431	SYM
iajs-3279	148	1	-3.17	-3.17	NUM
iajs-3279	148	2	49.57	49.57	NUM
iajs-3279	148	3	49.99	49.99	NUM
iajs-3279	148	4	46.23	46.23	NUM
iajs-3279	149	1	[	[	X
iajs-3279	149	2	ni(h2l)(h2o)2cl	ni(h2l)(h2o)2cl	X
iajs-3279	149	3	]	]	X
iajs-3279	149	4	endothermic	endothermic	PROPN
iajs-3279	149	5	115.3452	115.3452	NUM
iajs-3279	149	6	-1.5844	-1.5844	NOUN
iajs-3279	149	7	-39.72	-39.72	NOUN
iajs-3279	149	8	97.87	97.87	NUM
iajs-3279	149	9	108.46	108.46	NUM
iajs-3279	149	10	83.39	83.39	NUM
iajs-3279	149	11	endothermic	endothermic	NOUN
iajs-3279	149	12	endothermic	endothermic	NOUN
iajs-3279	149	13	exothermic	exothermic	ADJ
iajs-3279	149	14	exothermic	exothermic	ADJ
iajs-3279	149	15	39.6314	39.6314	NUM
iajs-3279	149	16	316.6206	316.6206	NUM
iajs-3279	149	17	-545.504	-545.504	PROPN
iajs-3279	149	18	2608.568	2608.568	NUM
iajs-3279	149	19	-0.2647	-0.2647	NOUN
iajs-3279	149	20	-1.3381	-1.3381	VERB
iajs-3279	149	21	1.9843	1.9843	NUM
iajs-3279	149	22	8.7952	8.7952	NUM
iajs-3279	149	23	-3.61	-3.61	NOUN
iajs-3279	149	24	-40.05	-40.05	PROPN
iajs-3279	149	25	42.96	42.96	NUM
iajs-3279	149	26	616.28	616.28	NUM
iajs-3279	149	27	163.36	163.36	NUM
iajs-3279	149	28	266.55	266.55	NUM
iajs-3279	149	29	296.56	296.56	NUM
iajs-3279	149	30	366.66	366.66	NUM
iajs-3279	149	31	170.04	170.04	NUM
iajs-3279	149	32	276.99	276.99	NUM
iajs-3279	149	33	306.96	306.96	NUM
iajs-3279	149	34	396.74	396.74	NUM
iajs-3279	149	35	156.40	156.40	NUM
iajs-3279	149	36	247.06	247.06	NUM
iajs-3279	149	37	285.31	285.31	NUM
iajs-3279	149	38	326.67	326.67	NUM
iajs-3279	149	39	endothermic	endothermic	NOUN
iajs-3279	149	40	24.0122	24.0122	NUM
iajs-3279	149	41	-0.2288	-0.2288	NOUN
iajs-3279	149	42	-2.19	-2.19	NUM
iajs-3279	149	43	114.52	114.52	NUM
iajs-3279	149	44	115.51	115.51	NUM
iajs-3279	149	45	105.94	105.94	NUM
iajs-3279	149	46	[	[	X
iajs-3279	149	47	pd(h2l)cl	pd(h2l)cl	X
iajs-3279	149	48	]	]	X
iajs-3279	149	49	endothermic	endothermic	NOUN
iajs-3279	149	50	21.8952	21.8952	NUM
iajs-3279	149	51	-0.1456	-0.1456	NOUN
iajs-3279	149	52	-0.75	-0.75	NUM
iajs-3279	149	53	155.53	155.53	NUM
iajs-3279	149	54	156.31	156.31	NUM
iajs-3279	149	55	151.16	151.16	NUM
iajs-3279	149	56	endothermic	endothermic	NOUN
iajs-3279	149	57	399.6495	399.6495	NUM
iajs-3279	149	58	-1.2806	-1.2806	NOUN
iajs-3279	149	59	-5.75	-5.75	X
iajs-3279	149	60	316.57	316.57	NUM
iajs-3279	149	61	319.54	319.54	NUM
iajs-3279	149	62	315.05	315.05	NUM
iajs-3279	149	63	endothermic	endothermic	NOUN
iajs-3279	149	64	59.0595	59.0595	NUM
iajs-3279	149	65	-1.5097	-1.5097	NOUN
iajs-3279	150	1	-90.28	-90.28	PUNCT
iajs-3279	151	1	98.92	98.92	NUM
iajs-3279	151	2	126.07	126.07	NUM
iajs-3279	151	3	66.27	66.27	NUM
iajs-3279	151	4	[	[	X
iajs-3279	151	5	pt(h2l)cl3	pt(h2l)cl3	X
iajs-3279	151	6	]	]	X
iajs-3279	151	7	3.6	3.6	NUM
iajs-3279	151	8	investigation	investigation	NOUN
iajs-3279	151	9	of	of	ADP
iajs-3279	151	10	antioxidant	antioxidant	ADJ
iajs-3279	151	11	activity	activity	NOUN
iajs-3279	151	12	the	the	DET
iajs-3279	151	13	assay	assay	NOUN
iajs-3279	151	14	was	be	AUX
iajs-3279	151	15	used	use	VERB
iajs-3279	151	16	to	to	PART
iajs-3279	151	17	determine	determine	VERB
iajs-3279	151	18	how	how	SCONJ
iajs-3279	151	19	well	well	ADJ
iajs-3279	151	20	antioxidants	antioxidant	NOUN
iajs-3279	151	21	can	can	AUX
iajs-3279	151	22	scavenge	scavenge	VERB
iajs-3279	151	23	it	it	PRON
iajs-3279	151	24	.	.	PUNCT
iajs-3279	152	1	antioxidants	antioxidant	NOUN
iajs-3279	152	2	provide	provide	VERB
iajs-3279	152	3	a	a	DET
iajs-3279	152	4	hydrogen	hydrogen	NOUN
iajs-3279	152	5	atom	atom	NOUN
iajs-3279	152	6	to1-(2,4,6	to1-(2,4,6	PROPN
iajs-3279	152	7	-	-	PUNCT
iajs-3279	152	8	trihydroxy	trihydroxy	NOUN
iajs-3279	152	9	-	-	PUNCT
iajs-3279	152	10	phenyl)-ethanone	phenyl)-ethanone	NOUN
iajs-3279	152	11	,	,	PUNCT
iajs-3279	152	12	which	which	PRON
iajs-3279	152	13	reduces	reduce	VERB
iajs-3279	152	14	the	the	DET
iajs-3279	152	15	single	single	ADJ
iajs-3279	152	16	electrons	electron	NOUN
iajs-3279	152	17	from	from	ADP
iajs-3279	152	18	nitrogen	nitrogen	NOUN
iajs-3279	152	19	atoms	atom	NOUN
iajs-3279	152	20	in	in	ADP
iajs-3279	152	21	dpph	dpph	PROPN
iajs-3279	152	22	.	.	PUNCT
iajs-3279	153	1	when	when	SCONJ
iajs-3279	153	2	the	the	DET
iajs-3279	153	3	dpph	dpph	PROPN
iajs-3279	153	4	radical	radical	ADJ
iajs-3279	153	5	solution	solution	NOUN
iajs-3279	153	6	is	be	AUX
iajs-3279	153	7	combined	combine	VERB
iajs-3279	153	8	with	with	ADP
iajs-3279	153	9	the	the	DET
iajs-3279	153	10	antioxidant	antioxidant	NOUN
iajs-3279	153	11	,	,	PUNCT
iajs-3279	153	12	the	the	DET
iajs-3279	153	13	color	color	NOUN
iajs-3279	153	14	of	of	ADP
iajs-3279	153	15	the	the	DET
iajs-3279	153	16	corresponding	correspond	VERB
iajs-3279	153	17	hydrazine	hydrazine	NOUN
iajs-3279	153	18	changes	change	NOUN
iajs-3279	153	19	from	from	ADP
iajs-3279	153	20	violet	violet	NOUN
iajs-3279	153	21	to	to	PART
iajs-3279	153	22	yellow	yellow	VERB
iajs-3279	153	23	,	,	PUNCT
iajs-3279	153	24	which	which	PRON
iajs-3279	153	25	is	be	AUX
iajs-3279	153	26	characterized	characterize	VERB
iajs-3279	153	27	by	by	ADP
iajs-3279	153	28	an	an	DET
iajs-3279	153	29	absorption	absorption	NOUN
iajs-3279	153	30	band	band	NOUN
iajs-3279	153	31	in	in	ADP
iajs-3279	153	32	an	an	DET
iajs-3279	153	33	ethanol	ethanol	NOUN
iajs-3279	153	34	solution	solution	NOUN
iajs-3279	153	35	centered	center	VERB
iajs-3279	153	36	at	at	ADP
iajs-3279	153	37	approximately	approximately	ADV
iajs-3279	153	38	(	(	PUNCT
iajs-3279	153	39	517	517	NUM
iajs-3279	153	40	nm	nm	NOUN
iajs-3279	153	41	)	)	PUNCT
iajs-3279	153	42	.	.	PUNCT
iajs-3279	154	1	electron	electron	NOUN
iajs-3279	154	2	delocalization	delocalization	NOUN
iajs-3279	154	3	also	also	ADV
iajs-3279	154	4	produces	produce	VERB
iajs-3279	154	5	dark	dark	ADJ
iajs-3279	154	6	purple	purple	NOUN
iajs-3279	155	1	[	[	X
iajs-3279	155	2	30	30	NUM
iajs-3279	155	3	]	]	PUNCT
iajs-3279	155	4	.	.	PUNCT
iajs-3279	156	1	the	the	DET
iajs-3279	156	2	interaction	interaction	NOUN
iajs-3279	156	3	of	of	ADP
iajs-3279	156	4	[	[	X
iajs-3279	156	5	ni(h2l)(h2o)2cl	ni(h2l)(h2o)2cl	NOUN
iajs-3279	156	6	]	]	X
iajs-3279	156	7	,	,	PUNCT
iajs-3279	156	8	[	[	X
iajs-3279	156	9	zn(h2l)(h2o)cl],[pd(h2l)cl	zn(h2l)(h2o)cl],[pd(h2l)cl	X
iajs-3279	156	10	]	]	PUNCT
iajs-3279	156	11	and	and	CCONJ
iajs-3279	156	12	[	[	X
iajs-3279	156	13	pt(h2l)cl3	pt(h2l)cl3	X
iajs-3279	156	14	]	]	PUNCT
iajs-3279	156	15	complexes	complex	NOUN
iajs-3279	156	16	with	with	ADP
iajs-3279	156	17	dpph	dpph	PROPN
iajs-3279	156	18	radicals	radical	NOUN
iajs-3279	156	19	and	and	CCONJ
iajs-3279	156	20	subsequent	subsequent	ADJ
iajs-3279	156	21	hydrogen	hydrogen	NOUN
iajs-3279	156	22	donation	donation	NOUN
iajs-3279	156	23	to	to	PART
iajs-3279	156	24	scavenge	scavenge	VERB
iajs-3279	156	25	the	the	DET
iajs-3279	156	26	radicals	radical	NOUN
iajs-3279	156	27	were	be	AUX
iajs-3279	156	28	displayed	display	VERB
iajs-3279	156	29	with	with	ADP
iajs-3279	156	30	table	table	NOUN
iajs-3279	156	31	7	7	NUM
iajs-3279	156	32	.	.	PUNCT
iajs-3279	156	33	effective	effective	ADJ
iajs-3279	156	34	dpph	dpph	PROPN
iajs-3279	156	35	radical	radical	ADJ
iajs-3279	156	36	scavenging	scavenging	NOUN
iajs-3279	156	37	is	be	AUX
iajs-3279	156	38	indicated	indicate	VERB
iajs-3279	156	39	by	by	ADP
iajs-3279	156	40	a	a	DET
iajs-3279	156	41	lower	low	ADJ
iajs-3279	156	42	ic50	ic50	PROPN
iajs-3279	156	43	value	value	NOUN
iajs-3279	156	44	.	.	PUNCT
iajs-3279	157	1	in	in	ADP
iajs-3279	157	2	the	the	DET
iajs-3279	157	3	dpph	dpph	PROPN
iajs-3279	157	4	assay	assay	PROPN
iajs-3279	157	5	,	,	PUNCT
iajs-3279	157	6	the	the	DET
iajs-3279	157	7	practically	practically	ADV
iajs-3279	157	8	ptcomplex	ptcomplex	NOUN
iajs-3279	157	9	has	have	VERB
iajs-3279	157	10	more	more	ADJ
iajs-3279	157	11	antioxidant	antioxidant	ADJ
iajs-3279	157	12	activity	activity	NOUN
iajs-3279	157	13	than	than	ADP
iajs-3279	157	14	the	the	DET
iajs-3279	157	15	othermetal	othermetal	ADJ
iajs-3279	157	16	complexes	complex	NOUN
iajs-3279	157	17	[	[	X
iajs-3279	157	18	31,32	31,32	NUM
iajs-3279	157	19	]	]	PUNCT
iajs-3279	157	20	.	.	PUNCT
iajs-3279	158	1	ihjpas	ihjpas	PROPN
iajs-3279	158	2	.	.	PUNCT
iajs-3279	159	1	37(2)2024	37(2)2024	NUM
iajs-3279	159	2	256	256	NUM
iajs-3279	159	3	table	table	NOUN
iajs-3279	159	4	7	7	NUM
iajs-3279	159	5	.	.	PUNCT
iajs-3279	159	6	antioxidant	antioxidant	ADJ
iajs-3279	159	7	activity	activity	NOUN
iajs-3279	159	8	of	of	ADP
iajs-3279	159	9	azo	azo	NOUN
iajs-3279	159	10	dye	dye	NOUN
iajs-3279	159	11	and	and	CCONJ
iajs-3279	159	12	its	its	PRON
iajs-3279	159	13	complexes	complex	NOUN
iajs-3279	159	14	.	.	PUNCT
iajs-3279	160	1	compounds	compound	NOUN
iajs-3279	160	2	compounds	compound	NOUN
iajs-3279	160	3	mean	mean	VERB
iajs-3279	160	4	standard	standard	ADJ
iajs-3279	160	5	deviation	deviation	NOUN
iajs-3279	160	6	coefficient	coefficient	NOUN
iajs-3279	160	7	of	of	ADP
iajs-3279	160	8	variation%	variation%	PROPN
iajs-3279	160	9	correlation	correlation	NOUN
iajs-3279	160	10	coefficient	coefficient	NOUN
iajs-3279	160	11	ic50(m	ic50(m	PROPN
iajs-3279	160	12	)	)	PUNCT
iajs-3279	160	13	ga	ga	PROPN
iajs-3279	160	14	93.5600	93.5600	NUM
iajs-3279	160	15	2.0846	2.0846	NUM
iajs-3279	160	16	12.2281	12.2281	NUM
iajs-3279	160	17	0.9993	0.9993	NUM
iajs-3279	160	18	6.1135	6.1135	NUM
iajs-3279	160	19	h3	h3	NOUN
iajs-3279	160	20	l	l	NOUN
iajs-3279	160	21	85.7600	85.7600	NUM
iajs-3279	161	1	3.0663	3.0663	NUM
iajs-3279	161	2	13.3521	13.3521	NUM
iajs-3279	161	3	0.9938	0.9938	NUM
iajs-3279	161	4	4.6630	4.6630	NUM
iajs-3279	161	5	[	[	X
iajs-3279	161	6	ni(h2l)(h2o)2cl	ni(h2l)(h2o)2cl	X
iajs-3279	161	7	]	]	X
iajs-3279	161	8	68.8311	68.8311	NUM
iajs-3279	161	9	4.2753	4.2753	NUM
iajs-3279	161	10	13.1762	13.1762	NUM
iajs-3279	161	11	0.9988	0.9988	NUM
iajs-3279	161	12	3.1625	3.1625	NUM
iajs-3279	161	13	[	[	X
iajs-3279	161	14	zn(h2l)(h2o)cl	zn(h2l)(h2o)cl	X
iajs-3279	161	15	]	]	PUNCT
iajs-3279	161	16	65.4423	65.4423	NUM
iajs-3279	161	17	3.8123	3.8123	NUM
iajs-3279	161	18	17.6531	17.6531	NUM
iajs-3279	161	19	0.9991	0.9991	NUM
iajs-3279	161	20	4.0109	4.0109	NUM
iajs-3279	162	1	[	[	X
iajs-3279	162	2	pd(h2l)cl	pd(h2l)cl	X
iajs-3279	162	3	]	]	X
iajs-3279	162	4	83.1152	83.1152	NUM
iajs-3279	162	5	3.3796	3.3796	NUM
iajs-3279	162	6	15.5221	15.5221	NUM
iajs-3279	162	7	0.9981	0.9981	NUM
iajs-3279	162	8	3.0025	3.0025	NUM
iajs-3279	162	9	[	[	X
iajs-3279	162	10	pt(h2l)cl3	pt(h2l)cl3	X
iajs-3279	162	11	]	]	X
iajs-3279	162	12	71.3217	71.3217	NUM
iajs-3279	162	13	2.2009	2.2009	NUM
iajs-3279	162	14	14.4119	14.4119	NUM
iajs-3279	162	15	0.9975	0.9975	NUM
iajs-3279	162	16	2.704	2.704	NUM
iajs-3279	162	17	4	4	NUM
iajs-3279	162	18	.	.	PUNCT
iajs-3279	162	19	conclusion	conclusion	NOUN
iajs-3279	162	20	in	in	ADP
iajs-3279	162	21	summary	summary	NOUN
iajs-3279	163	1	,	,	PUNCT
iajs-3279	163	2	this	this	DET
iajs-3279	163	3	study	study	NOUN
iajs-3279	163	4	has	have	AUX
iajs-3279	163	5	successfully	successfully	ADV
iajs-3279	163	6	synthesized	synthesize	VERB
iajs-3279	163	7	a	a	DET
iajs-3279	163	8	new	new	ADJ
iajs-3279	163	9	azo	azo	NOUN
iajs-3279	163	10	ligand	ligand	NOUN
iajs-3279	163	11	derivative	derivative	NOUN
iajs-3279	163	12	of	of	ADP
iajs-3279	163	13	sulfamethoxazole	sulfamethoxazole	NOUN
iajs-3279	163	14	by	by	ADP
iajs-3279	163	15	simple	simple	ADJ
iajs-3279	163	16	substitution	substitution	NOUN
iajs-3279	163	17	reaction	reaction	NOUN
iajs-3279	163	18	with	with	ADP
iajs-3279	163	19	1-(2,4,6	1-(2,4,6	NUM
iajs-3279	163	20	-	-	PUNCT
iajs-3279	163	21	trihydroxy	trihydroxy	NOUN
iajs-3279	163	22	-	-	PUNCT
iajs-3279	163	23	phenyl)-ethanone	phenyl)-ethanone	NOUN
iajs-3279	163	24	.	.	PUNCT
iajs-3279	164	1	then	then	ADV
iajs-3279	164	2	characterized	characterize	VERB
iajs-3279	164	3	ligand	ligand	NOUN
iajs-3279	164	4	and	and	CCONJ
iajs-3279	164	5	metal	metal	NOUN
iajs-3279	164	6	complexes	complex	NOUN
iajs-3279	164	7	by	by	ADP
iajs-3279	164	8	various	various	ADJ
iajs-3279	164	9	analytical	analytical	ADJ
iajs-3279	164	10	techniques	technique	NOUN
iajs-3279	164	11	,	,	PUNCT
iajs-3279	164	12	like	like	ADP
iajs-3279	164	13	elemental	elemental	ADJ
iajs-3279	164	14	microanalysis	microanalysis	NOUN
iajs-3279	164	15	,	,	PUNCT
iajs-3279	164	16	metal	metal	NOUN
iajs-3279	164	17	–	–	PUNCT
iajs-3279	164	18	chloride	chloride	NOUN
iajs-3279	164	19	containing	containing	NOUN
iajs-3279	164	20	,	,	PUNCT
iajs-3279	164	21	electrical	electrical	ADJ
iajs-3279	164	22	conductivity	conductivity	NOUN
iajs-3279	164	23	measurement	measurement	NOUN
iajs-3279	164	24	,	,	PUNCT
iajs-3279	164	25	magnetic	magnetic	ADJ
iajs-3279	164	26	susceptibility	susceptibility	NOUN
iajs-3279	164	27	,	,	PUNCT
iajs-3279	164	28	1	1	NUM
iajs-3279	164	29	h	h	NOUN
iajs-3279	164	30	and	and	CCONJ
iajs-3279	164	31	13	13	NUM
iajs-3279	164	32	cnmr	cnmr	NOUN
iajs-3279	164	33	,	,	PUNCT
iajs-3279	164	34	ft	ft	PROPN
iajs-3279	164	35	-	-	PUNCT
iajs-3279	164	36	ir	ir	NOUN
iajs-3279	164	37	,	,	PUNCT
iajs-3279	164	38	uv	uv	NOUN
iajs-3279	164	39	-	-	PUNCT
iajs-3279	164	40	vis	vis	X
iajs-3279	164	41	,	,	PUNCT
iajs-3279	164	42	mass	mass	NOUN
iajs-3279	164	43	spectroscopy	spectroscopy	NOUN
iajs-3279	164	44	,	,	PUNCT
iajs-3279	164	45	and	and	CCONJ
iajs-3279	164	46	thermal	thermal	ADJ
iajs-3279	164	47	analysis	analysis	NOUN
iajs-3279	164	48	(	(	PUNCT
iajs-3279	164	49	tga	tga	NOUN
iajs-3279	164	50	and	and	CCONJ
iajs-3279	164	51	dsc	dsc	NOUN
iajs-3279	164	52	)	)	PUNCT
iajs-3279	164	53	curves	curve	NOUN
iajs-3279	164	54	.	.	PUNCT
iajs-3279	165	1	the	the	DET
iajs-3279	165	2	dcs	dcs	PROPN
iajs-3279	165	3	curve	curve	NOUN
iajs-3279	165	4	was	be	AUX
iajs-3279	165	5	used	use	VERB
iajs-3279	165	6	to	to	PART
iajs-3279	165	7	calculated	calculate	VERB
iajs-3279	165	8	the	the	DET
iajs-3279	165	9	thermodynamic	thermodynamic	ADJ
iajs-3279	165	10	parameters	parameter	NOUN
iajs-3279	165	11	δh	δh	ADP
iajs-3279	165	12	,	,	PUNCT
iajs-3279	165	13	δs	δs	NOUN
iajs-3279	165	14	,	,	PUNCT
iajs-3279	165	15	and	and	CCONJ
iajs-3279	165	16	δg.the	δg.the	DET
iajs-3279	165	17	yield	yield	NOUN
iajs-3279	165	18	of	of	ADP
iajs-3279	165	19	the	the	DET
iajs-3279	165	20	synthesized	synthesize	VERB
iajs-3279	165	21	compounds	compound	NOUN
iajs-3279	165	22	was	be	AUX
iajs-3279	165	23	found	find	VERB
iajs-3279	165	24	to	to	PART
iajs-3279	165	25	be	be	AUX
iajs-3279	165	26	in	in	ADP
iajs-3279	165	27	the	the	DET
iajs-3279	165	28	range	range	NOUN
iajs-3279	165	29	from	from	ADP
iajs-3279	165	30	60	60	NUM
iajs-3279	165	31	-	-	PUNCT
iajs-3279	165	32	80%.the	80%.the	NUM
iajs-3279	165	33	molar	molar	ADJ
iajs-3279	165	34	conductivity	conductivity	NOUN
iajs-3279	165	35	results	result	NOUN
iajs-3279	165	36	showed	show	VERB
iajs-3279	165	37	that	that	SCONJ
iajs-3279	165	38	none	none	NOUN
iajs-3279	165	39	of	of	ADP
iajs-3279	165	40	the	the	DET
iajs-3279	165	41	produced	produce	VERB
iajs-3279	165	42	complexes	complex	NOUN
iajs-3279	165	43	are	be	AUX
iajs-3279	165	44	electrolytes	electrolyte	NOUN
iajs-3279	165	45	,	,	PUNCT
iajs-3279	165	46	and	and	CCONJ
iajs-3279	165	47	the	the	DET
iajs-3279	165	48	atomic	atomic	PROPN
iajs-3279	165	49	n	n	CCONJ
iajs-3279	165	50	,	,	PUNCT
iajs-3279	165	51	o	o	PROPN
iajs-3279	165	52	and	and	CCONJ
iajs-3279	165	53	o	o	PROPN
iajs-3279	165	54	tridentate	tridentate	NOUN
iajs-3279	165	55	coordination	coordination	NOUN
iajs-3279	165	56	sites	site	NOUN
iajs-3279	165	57	in	in	ADP
iajs-3279	165	58	the	the	DET
iajs-3279	165	59	ligand	ligand	NOUN
iajs-3279	165	60	were	be	AUX
iajs-3279	165	61	identified	identify	VERB
iajs-3279	165	62	by	by	ADP
iajs-3279	165	63	comparing	compare	VERB
iajs-3279	165	64	their	their	PRON
iajs-3279	165	65	ir	ir	NOUN
iajs-3279	165	66	spectra	spectra	NOUN
iajs-3279	165	67	to	to	ADP
iajs-3279	165	68	those	those	PRON
iajs-3279	165	69	of	of	ADP
iajs-3279	165	70	the	the	DET
iajs-3279	165	71	metal	metal	NOUN
iajs-3279	165	72	complexes	complex	NOUN
iajs-3279	165	73	.	.	PUNCT
iajs-3279	166	1	the	the	DET
iajs-3279	166	2	m	m	NOUN
iajs-3279	166	3	:	:	PUNCT
iajs-3279	166	4	l	l	NOUN
iajs-3279	166	5	ratio	ratio	NOUN
iajs-3279	166	6	in	in	ADP
iajs-3279	166	7	every	every	DET
iajs-3279	166	8	compound	compound	NOUN
iajs-3279	166	9	was	be	AUX
iajs-3279	166	10	[	[	X
iajs-3279	166	11	1:1	1:1	NUM
iajs-3279	166	12	]	]	PUNCT
iajs-3279	166	13	.	.	PUNCT
iajs-3279	167	1	according	accord	VERB
iajs-3279	167	2	to	to	ADP
iajs-3279	167	3	the	the	DET
iajs-3279	167	4	results	result	NOUN
iajs-3279	167	5	,	,	PUNCT
iajs-3279	167	6	octahedral	octahedral	ADJ
iajs-3279	167	7	geometry	geometry	NOUN
iajs-3279	167	8	suggests	suggest	VERB
iajs-3279	167	9	(	(	PUNCT
iajs-3279	167	10	ni	ni	PROPN
iajs-3279	167	11	2	2	NUM
iajs-3279	167	12	+	+	NUM
iajs-3279	167	13	and	and	CCONJ
iajs-3279	167	14	pt	pt	INTJ
iajs-3279	167	15	4	4	NUM
iajs-3279	167	16	+	+	NUM
iajs-3279	167	17	)	)	PUNCT
iajs-3279	167	18	,	,	PUNCT
iajs-3279	167	19	tetrahedral	tetrahedral	NOUN
iajs-3279	167	20	of	of	ADP
iajs-3279	167	21	zn	zn	PROPN
iajs-3279	167	22	2	2	NUM
iajs-3279	167	23	+	+	CCONJ
iajs-3279	167	24	complex	complex	ADJ
iajs-3279	167	25	,	,	PUNCT
iajs-3279	167	26	and	and	CCONJ
iajs-3279	167	27	square	square	ADJ
iajs-3279	167	28	planer	planer	NOUN
iajs-3279	167	29	of	of	ADP
iajs-3279	167	30	pd	pd	PROPN
iajs-3279	167	31	2	2	NUM
iajs-3279	167	32	+	+	NUM
iajs-3279	167	33	.	.	PUNCT
iajs-3279	168	1	the	the	DET
iajs-3279	168	2	antioxidant	antioxidant	ADJ
iajs-3279	168	3	activity	activity	NOUN
iajs-3279	168	4	of	of	ADP
iajs-3279	168	5	the	the	DET
iajs-3279	168	6	synthetic	synthetic	ADJ
iajs-3279	168	7	compounds	compound	NOUN
iajs-3279	168	8	was	be	AUX
iajs-3279	168	9	evaluated	evaluate	VERB
iajs-3279	168	10	against	against	ADP
iajs-3279	168	11	the	the	DET
iajs-3279	168	12	dpph	dpph	PROPN
iajs-3279	168	13	radical	radical	ADJ
iajs-3279	168	14	(	(	PUNCT
iajs-3279	168	15	1.1	1.1	NUM
iajs-3279	168	16	-	-	PUNCT
iajs-3279	168	17	diphenyl-2	diphenyl-2	NOUN
iajs-3279	168	18	-	-	NOUN
iajs-3279	168	19	picrylhydrazyl	picrylhydrazyl	NOUN
iajs-3279	168	20	)	)	PUNCT
iajs-3279	168	21	,	,	PUNCT
iajs-3279	168	22	and	and	CCONJ
iajs-3279	168	23	the	the	DET
iajs-3279	168	24	results	result	NOUN
iajs-3279	168	25	were	be	AUX
iajs-3279	168	26	contrasted	contrast	VERB
iajs-3279	168	27	with	with	ADP
iajs-3279	168	28	those	those	PRON
iajs-3279	168	29	of	of	ADP
iajs-3279	168	30	gallic	gallic	ADJ
iajs-3279	168	31	acid	acid	NOUN
iajs-3279	168	32	,	,	PUNCT
iajs-3279	168	33	a	a	DET
iajs-3279	168	34	widely	widely	ADV
iajs-3279	168	35	used	use	VERB
iajs-3279	168	36	natural	natural	ADJ
iajs-3279	168	37	antioxidant	antioxidant	NOUN
iajs-3279	168	38	.	.	PUNCT
iajs-3279	169	1	results	result	NOUN
iajs-3279	169	2	show	show	VERB
iajs-3279	169	3	how	how	SCONJ
iajs-3279	169	4	efficient	efficient	ADJ
iajs-3279	169	5	metal	metal	NOUN
iajs-3279	169	6	complexes	complex	NOUN
iajs-3279	169	7	are	be	AUX
iajs-3279	169	8	in	in	ADP
iajs-3279	169	9	scavenging	scavenge	VERB
iajs-3279	169	10	free	free	ADJ
iajs-3279	169	11	radicals	radical	NOUN
iajs-3279	169	12	.	.	PUNCT
iajs-3279	170	1	acknowledgment	acknowledgment	NOUN
iajs-3279	170	2	the	the	DET
iajs-3279	170	3	authors	author	NOUN
iajs-3279	170	4	would	would	AUX
iajs-3279	170	5	like	like	VERB
iajs-3279	170	6	to	to	PART
iajs-3279	170	7	thank	thank	VERB
iajs-3279	170	8	everyone	everyone	PRON
iajs-3279	170	9	who	who	PRON
iajs-3279	170	10	contributed	contribute	VERB
iajs-3279	170	11	to	to	ADP
iajs-3279	170	12	the	the	DET
iajs-3279	170	13	success	success	NOUN
iajs-3279	170	14	of	of	ADP
iajs-3279	170	15	this	this	DET
iajs-3279	170	16	review	review	NOUN
iajs-3279	170	17	article	article	NOUN
iajs-3279	170	18	.	.	PUNCT
iajs-3279	171	1	department	department	PROPN
iajs-3279	171	2	of	of	ADP
iajs-3279	171	3	chemistry	chemistry	NOUN
iajs-3279	171	4	,	,	PUNCT
iajs-3279	171	5	college	college	NOUN
iajs-3279	171	6	of	of	ADP
iajs-3279	171	7	science	science	NOUN
iajs-3279	171	8	for	for	ADP
iajs-3279	171	9	women	woman	NOUN
iajs-3279	171	10	,	,	PUNCT
iajs-3279	171	11	baghdad	baghdad	PROPN
iajs-3279	171	12	university	university	PROPN
iajs-3279	171	13	,	,	PUNCT
iajs-3279	171	14	prof	prof	PROPN
iajs-3279	171	15	.	.	PUNCT
iajs-3279	172	1	dr	dr	PROPN
iajs-3279	172	2	.	.	PROPN
iajs-3279	172	3	abbas	abbas	PROPN
iajs-3279	172	4	ali	ali	PROPN
iajs-3279	172	5	salih	salih	PROPN
iajs-3279	172	6	al	al	PROPN
iajs-3279	172	7	-	-	PUNCT
iajs-3279	172	8	hamdani	hamdani	PROPN
iajs-3279	172	9	,	,	PUNCT
iajs-3279	172	10	ministry	ministry	NOUN
iajs-3279	172	11	of	of	ADP
iajs-3279	172	12	higher	high	ADJ
iajs-3279	172	13	education	education	NOUN
iajs-3279	172	14	&	&	CCONJ
iajs-3279	172	15	scientific	scientific	ADJ
iajs-3279	172	16	research	research	NOUN
iajs-3279	172	17	and	and	CCONJ
iajs-3279	172	18	ministry	ministry	PROPN
iajs-3279	172	19	of	of	ADP
iajs-3279	172	20	science	science	NOUN
iajs-3279	172	21	and	and	CCONJ
iajs-3279	172	22	technology	technology	NOUN
iajs-3279	172	23	,	,	PUNCT
iajs-3279	172	24	directorate	directorate	NOUN
iajs-3279	172	25	of	of	ADP
iajs-3279	172	26	environment	environment	NOUN
iajs-3279	172	27	and	and	CCONJ
iajs-3279	172	28	water	water	NOUN
iajs-3279	172	29	.	.	PUNCT
iajs-3279	173	1	conflict	conflict	NOUN
iajs-3279	173	2	of	of	ADP
iajs-3279	173	3	interest	interest	NOUN
iajs-3279	173	4	none	none	NOUN
iajs-3279	173	5	funding	fund	VERB
iajs-3279	173	6	there	there	PRON
iajs-3279	173	7	is	be	VERB
iajs-3279	173	8	no	no	DET
iajs-3279	173	9	financial	financial	ADJ
iajs-3279	173	10	support	support	NOUN
iajs-3279	173	11	.	.	PUNCT
iajs-3279	174	1	ethical	ethical	ADJ
iajs-3279	174	2	clearance	clearance	NOUN
iajs-3279	174	3	this	this	DET
iajs-3279	174	4	work	work	NOUN
iajs-3279	174	5	has	have	AUX
iajs-3279	174	6	been	be	AUX
iajs-3279	174	7	approved	approve	VERB
iajs-3279	174	8	by	by	ADP
iajs-3279	174	9	the	the	DET
iajs-3279	174	10	scientific	scientific	ADJ
iajs-3279	174	11	committee	committee	NOUN
iajs-3279	174	12	at	at	ADP
iajs-3279	174	13	the	the	DET
iajs-3279	174	14	university	university	NOUN
iajs-3279	174	15	of	of	ADP
iajs-3279	174	16	baghdad/	baghdad/	NUM
iajs-3279	174	17	college	college	NOUN
iajs-3279	174	18	of	of	ADP
iajs-3279	174	19	science	science	NOUN
iajs-3279	174	20	for	for	ADP
iajs-3279	174	21	women	woman	NOUN
iajs-3279	174	22	.	.	PUNCT
iajs-3279	175	1	ihjpas	ihjpas	PROPN
iajs-3279	175	2	.	.	PUNCT
iajs-3279	176	1	37(2)2024	37(2)2024	NUM
iajs-3279	176	2	257	257	NUM
iajs-3279	176	3	references	reference	NOUN
iajs-3279	176	4	1	1	NUM
iajs-3279	176	5	.	.	PUNCT
iajs-3279	177	1	al	al	PROPN
iajs-3279	177	2	-	-	PUNCT
iajs-3279	177	3	hamdani	hamdani	PROPN
iajs-3279	177	4	,	,	PUNCT
iajs-3279	177	5	a.a.s	a.a.s	PROPN
iajs-3279	177	6	.	.	PROPN
iajs-3279	177	7	;	;	PUNCT
iajs-3279	178	1	balkhi	balkhi	PROPN
iajs-3279	178	2	,	,	PUNCT
iajs-3279	178	3	a.m.	a.m.	ADV
iajs-3279	178	4	,	,	PUNCT
iajs-3279	178	5	shaker	shaker	NOUN
iajs-3279	178	6	,	,	PUNCT
iajs-3279	178	7	a.f.s.a	a.f.s.a	NOUN
iajs-3279	178	8	.	.	NOUN
iajs-3279	178	9	synthesis	synthesis	NOUN
iajs-3279	178	10	and	and	CCONJ
iajs-3279	178	11	investigation	investigation	NOUN
iajs-3279	178	12	of	of	ADP
iajs-3279	178	13	thermal	thermal	ADJ
iajs-3279	178	14	properties	property	NOUN
iajs-3279	178	15	of	of	ADP
iajs-3279	178	16	vanadyl	vanadyl	NOUN
iajs-3279	178	17	complexes	complex	NOUN
iajs-3279	178	18	with	with	ADP
iajs-3279	178	19	azo	azo	NOUN
iajs-3279	178	20	-	-	PUNCT
iajs-3279	178	21	containing	contain	VERB
iajs-3279	178	22	schiff	schiff	NOUN
iajs-3279	178	23	-	-	PUNCT
iajs-3279	178	24	base	base	NOUN
iajs-3279	178	25	dyes	dye	NOUN
iajs-3279	178	26	.	.	PUNCT
iajs-3279	179	1	journal	journal	PROPN
iajs-3279	179	2	of	of	ADP
iajs-3279	179	3	saudi	saudi	PROPN
iajs-3279	179	4	chemical	chemical	PROPN
iajs-3279	179	5	society	society	NOUN
iajs-3279	179	6	2016	2016	NUM
iajs-3279	179	7	,	,	PUNCT
iajs-3279	179	8	20(5	20(5	NUM
iajs-3279	179	9	)	)	PUNCT
iajs-3279	179	10	,	,	PUNCT
iajs-3279	179	11	487	487	NUM
iajs-3279	179	12	-	-	SYM
iajs-3279	179	13	501	501	NUM
iajs-3279	179	14	.	.	PUNCT
iajs-3279	180	1	https://doi.org/10.1016/j.jscs.2012.08.001	https://doi.org/10.1016/j.jscs.2012.08.001	NOUN
iajs-3279	180	2	.	.	PUNCT
iajs-3279	181	1	2	2	NUM
iajs-3279	181	2	.	.	X
iajs-3279	181	3	resheed	resheed	PROPN
iajs-3279	181	4	,	,	PUNCT
iajs-3279	181	5	f.a	f.a	PROPN
iajs-3279	181	6	.	.	PROPN
iajs-3279	181	7	;	;	PUNCT
iajs-3279	182	1	al	al	PROPN
iajs-3279	182	2	-	-	PUNCT
iajs-3279	182	3	hamdani	hamdani	PROPN
iajs-3279	182	4	,	,	PUNCT
iajs-3279	182	5	a.a.s	a.a.s	PROPN
iajs-3279	182	6	.	.	PUNCT
iajs-3279	182	7	;	;	PUNCT
iajs-3279	183	1	abdullah	abdullah	PROPN
iajs-3279	183	2	,	,	PUNCT
iajs-3279	183	3	s.m	s.m	PROPN
iajs-3279	183	4	.	.	PROPN
iajs-3279	183	5	green	green	ADJ
iajs-3279	183	6	synthesis	synthesis	NOUN
iajs-3279	183	7	zinc	zinc	NOUN
iajs-3279	183	8	nanoparticles	nanoparticle	NOUN
iajs-3279	183	9	in	in	ADP
iajs-3279	183	10	the	the	DET
iajs-3279	183	11	treatment	treatment	NOUN
iajs-3279	183	12	of	of	ADP
iajs-3279	183	13	heavy	heavy	ADJ
iajs-3279	183	14	metals	metal	NOUN
iajs-3279	183	15	in	in	ADP
iajs-3279	183	16	the	the	DET
iajs-3279	183	17	form	form	NOUN
iajs-3279	183	18	of	of	ADP
iajs-3279	183	19	complexes	complex	NOUN
iajs-3279	183	20	.	.	PUNCT
iajs-3279	184	1	ibn	ibn	PROPN
iajs-3279	184	2	al	al	PROPN
iajs-3279	184	3	-	-	PUNCT
iajs-3279	184	4	haitham	haitham	PROPN
iajs-3279	184	5	journal	journal	PROPN
iajs-3279	184	6	for	for	ADP
iajs-3279	184	7	pure	pure	ADJ
iajs-3279	184	8	and	and	CCONJ
iajs-3279	184	9	applied	applied	ADJ
iajs-3279	184	10	sciences	science	NOUN
iajs-3279	184	11	2023	2023	NUM
iajs-3279	184	12	,	,	PUNCT
iajs-3279	184	13	36(3),201	36(3),201	NUM
iajs-3279	184	14	-	-	SYM
iajs-3279	184	15	213	213	NUM
iajs-3279	184	16	.	.	PUNCT
iajs-3279	185	1	https://doi.org/10.30526/36.3.3056	https://doi.org/10.30526/36.3.3056	X
iajs-3279	185	2	.	.	NOUN
iajs-3279	185	3	3	3	X
iajs-3279	185	4	.	.	X
iajs-3279	185	5	malik	malik	PROPN
iajs-3279	185	6	,	,	PUNCT
iajs-3279	185	7	h.	h.	PROPN
iajs-3279	185	8	;	;	PUNCT
iajs-3279	185	9	akhter	akhter	PROPN
iajs-3279	185	10	,	,	PUNCT
iajs-3279	185	11	z.	z.	PROPN
iajs-3279	185	12	;	;	PUNCT
iajs-3279	185	13	shahbaz	shahbaz	PROPN
iajs-3279	185	14	,	,	PUNCT
iajs-3279	185	15	m.	m.	NOUN
iajs-3279	185	16	;	;	PUNCT
iajs-3279	185	17	yousuf	yousuf	PROPN
iajs-3279	185	18	,	,	PUNCT
iajs-3279	185	19	s.	s.	PROPN
iajs-3279	185	20	;	;	PUNCT
iajs-3279	185	21	munawar	munawar	PROPN
iajs-3279	185	22	,	,	PUNCT
iajs-3279	185	23	k.s	k.s	PROPN
iajs-3279	185	24	.	.	PROPN
iajs-3279	185	25	;	;	PUNCT
iajs-3279	185	26	muhammad	muhammad	PROPN
iajs-3279	185	27	,	,	PUNCT
iajs-3279	185	28	s.	s.	PROPN
iajs-3279	185	29	;	;	PUNCT
iajs-3279	185	30	ahmad	ahmad	PROPN
iajs-3279	185	31	,	,	PUNCT
iajs-3279	185	32	t.	t.	NOUN
iajs-3279	185	33	synthesis	synthesis	NOUN
iajs-3279	185	34	,	,	PUNCT
iajs-3279	185	35	spectroscopic	spectroscopic	ADJ
iajs-3279	185	36	characterization	characterization	NOUN
iajs-3279	185	37	,	,	PUNCT
iajs-3279	185	38	single	single	ADJ
iajs-3279	185	39	crystal	crystal	NOUN
iajs-3279	185	40	,	,	PUNCT
iajs-3279	185	41	theoretical	theoretical	ADJ
iajs-3279	185	42	investigation	investigation	NOUN
iajs-3279	185	43	,	,	PUNCT
iajs-3279	185	44	and	and	CCONJ
iajs-3279	185	45	biological	biological	ADJ
iajs-3279	185	46	screenings	screening	NOUN
iajs-3279	185	47	of	of	ADP
iajs-3279	185	48	azobased	azobase	VERB
iajs-3279	185	49	moieties	moiety	NOUN
iajs-3279	185	50	.	.	PUNCT
iajs-3279	186	1	journal	journal	NOUN
iajs-3279	186	2	of	of	ADP
iajs-3279	186	3	molecular	molecular	ADJ
iajs-3279	186	4	structure	structure	NOUN
iajs-3279	186	5	2022	2022	NUM
iajs-3279	186	6	,	,	PUNCT
iajs-3279	186	7	1270	1270	NUM
iajs-3279	186	8	,	,	PUNCT
iajs-3279	186	9	133867	133867	NUM
iajs-3279	186	10	.	.	PUNCT
iajs-3279	187	1	https://doi	https://doi	X
iajs-3279	187	2	.	.	PUNCT
iajs-3279	188	1	10.1016	10.1016	NUM
iajs-3279	188	2	/	/	SYM
iajs-3279	188	3	j.molstruc.2022.13386	j.molstruc.2022.13386	PROPN
iajs-3279	188	4	.	.	PUNCT
iajs-3279	189	1	4	4	X
iajs-3279	189	2	.	.	NUM
iajs-3279	189	3	nagasundaram	nagasundaram	NOUN
iajs-3279	189	4	,	,	PUNCT
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iajs-3279	189	6	,	,	PUNCT
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iajs-3279	190	6	,	,	PUNCT
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iajs-3279	190	8	.	.	PUNCT
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iajs-3279	191	2	.	.	PUNCT
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iajs-3279	192	2	.	.	X
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iajs-3279	192	8	.	.	PUNCT
iajs-3279	192	9	;	;	PUNCT
iajs-3279	193	1	al	al	PROPN
iajs-3279	193	2	-	-	PUNCT
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iajs-3279	194	6	-	-	SYM
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iajs-3279	194	8	.	.	PUNCT
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iajs-3279	195	2	.	.	PROPN
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iajs-3279	196	2	.	.	X
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iajs-3279	197	6	al	al	PROPN
iajs-3279	197	7	-	-	PUNCT
iajs-3279	197	8	hamdani	hamdani	PROPN
iajs-3279	197	9	aas	aas	PROPN
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iajs-3279	197	20	some	some	DET
iajs-3279	197	21	transition	transition	NOUN
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iajs-3279	197	26	azo	azo	NOUN
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iajs-3279	198	4	,	,	PUNCT
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iajs-3279	198	9	-	-	SYM
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iajs-3279	198	11	.	.	PUNCT
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iajs-3279	200	2	.	.	X
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iajs-3279	201	9	a	a	DET
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iajs-3279	201	17	.	.	PUNCT
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iajs-3279	202	5	,	,	PUNCT
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iajs-3279	202	7	-	-	SYM
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iajs-3279	202	9	.	.	PUNCT
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iajs-3279	203	4	.	.	PUNCT
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iajs-3279	205	7	-	-	SYM
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iajs-3279	205	9	.	.	PUNCT
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iajs-3279	206	2	.	.	PUNCT
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iajs-3279	207	2	.	.	X
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iajs-3279	207	31	)	)	PUNCT
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iajs-3279	207	45	)	)	PUNCT
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iajs-3279	207	48	.	.	PUNCT
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iajs-3279	209	7	,	,	PUNCT
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iajs-3279	209	9	-	-	SYM
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iajs-3279	211	2	.	.	PUNCT
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iajs-3279	212	5	;	;	PUNCT
iajs-3279	212	6	al	al	PROPN
iajs-3279	212	7	-	-	PUNCT
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iajs-3279	212	12	;	;	PUNCT
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iajs-3279	213	2	,	,	PUNCT
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iajs-3279	213	4	.	.	PROPN
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iajs-3279	213	10	:	:	PUNCT
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iajs-3279	214	8	-	-	SYM
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iajs-3279	214	10	.	.	PUNCT
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iajs-3279	215	2	.	.	PUNCT
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iajs-3279	216	2	.	.	PUNCT
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iajs-3279	217	5	;	;	PUNCT
iajs-3279	217	6	al	al	PROPN
iajs-3279	217	7	-	-	PUNCT
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iajs-3279	246	25	)	)	PUNCT
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iajs-3279	246	28	)	)	PUNCT
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iajs-3279	246	31	)	)	PUNCT
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iajs-3279	246	34	)	)	PUNCT
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iajs-3279	246	40	)	)	PUNCT
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iajs-3279	246	44	)	)	PUNCT
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iajs-3279	249	5	;	;	PUNCT
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iajs-3279	249	7	-	-	PUNCT
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iajs-3279	249	19	;	;	PUNCT
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iajs-3279	249	21	,	,	PUNCT
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iajs-3279	249	23	;	;	PUNCT
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iajs-3279	252	12	;	;	PUNCT
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iajs-3279	269	36	several	several	ADJ
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iajs-3279	269	39	of	of	ADP
iajs-3279	269	40	(	(	PUNCT
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iajs-3279	269	42	-	-	PUNCT
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iajs-3279	269	46	-	-	PUNCT
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iajs-3279	269	50	-	-	PUNCT
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iajs-3279	269	53	.	.	PUNCT
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iajs-3279	270	5	,	,	PUNCT
iajs-3279	270	6	144,109776	144,109776	NUM
iajs-3279	270	7	.	.	PUNCT
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iajs-3279	272	2	.	.	PUNCT
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iajs-3279	273	7	;	;	PUNCT
iajs-3279	273	8	al	al	PROPN
iajs-3279	273	9	-	-	PUNCT
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iajs-3279	273	21	,	,	PUNCT
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iajs-3279	273	23	;	;	PUNCT
iajs-3279	273	24	al	al	PROPN
iajs-3279	273	25	-	-	PUNCT
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iajs-3279	273	44	,	,	PUNCT
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iajs-3279	273	46	-	-	PUNCT
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iajs-3279	273	48	(	(	PUNCT
iajs-3279	273	49	3hydroxyphenyl	3hydroxyphenyl	NUM
iajs-3279	273	50	)	)	PUNCT
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iajs-3279	273	52	.	.	PUNCT
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iajs-3279	274	6	,	,	PUNCT
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iajs-3279	274	8	.	.	PUNCT
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iajs-3279	275	4	.	.	PUNCT
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iajs-3279	276	2	.	.	X
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iajs-3279	276	8	al	al	PROPN
iajs-3279	276	9	-	-	PUNCT
iajs-3279	276	10	hamdani	hamdani	PROPN
iajs-3279	276	11	,	,	PUNCT
iajs-3279	276	12	a.a.s	a.a.s	PROPN
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iajs-3279	276	14	;	;	PUNCT
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iajs-3279	276	16	,	,	PUNCT
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iajs-3279	276	21	,	,	PUNCT
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iajs-3279	276	35	,	,	PUNCT
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iajs-3279	281	5	,	,	PUNCT
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iajs-3279	281	9	-	-	SYM
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iajs-3279	281	11	.	.	PUNCT
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iajs-3279	284	30	,	,	PUNCT
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iajs-3279	285	12	,	,	PUNCT
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iajs-3279	285	16	.	.	PUNCT
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iajs-3279	288	13	.	.	PUNCT
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iajs-3279	290	5	.	.	PUNCT
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iajs-3279	291	4	.	.	PUNCT
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iajs-3279	292	4	.	.	PUNCT
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iajs-3279	293	2	.	.	PUNCT
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iajs-3279	294	2	.	.	PROPN
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iajs-3279	295	2	.	.	PROPN
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iajs-3279	298	6	.	.	PUNCT
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iajs-3279	300	3	.	.	PUNCT
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iajs-3279	305	5	.	.	PUNCT
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iajs-3279	307	2	.	.	PUNCT
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iajs-3279	308	4	.	.	PUNCT
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iajs-3279	316	2	.	.	PUNCT
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iajs-3279	317	2	.	.	PUNCT
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iajs-3279	329	5	.	.	PUNCT
iajs-3279	330	1	https://doi.org/10.1002/poc.3916	https://doi.org/10.1002/poc.3916	PROPN
iajs-3279	330	2	.	.	PUNCT
iajs-3279	331	1	https://doi.org/10.21123/bsj.2023.7708	https://doi.org/10.21123/bsj.2023.7708	ADJ
iajs-3279	331	2	https://doi.org/10.21123/bsj.2023.7629	https://doi.org/10.21123/bsj.2023.7629	NOUN
iajs-3279	331	3	.	.	PUNCT
iajs-3279	332	1	https://doi.org/10.21123/bsj.2023.7629	https://doi.org/10.21123/bsj.2023.7629	NOUN
iajs-3279	332	2	.	.	PUNCT
iajs-3279	333	1	https://doi.org/10.30526/36.3.3068	https://doi.org/10.30526/36.3.3068	PUNCT