id	sid	tid	token	lemma	pos
iajs-3313	1	1	283	283	NUM
iajs-3313	1	2	this	this	DET
iajs-3313	1	3	work	work	NOUN
iajs-3313	1	4	is	be	AUX
iajs-3313	1	5	licensed	license	VERB
iajs-3313	1	6	under	under	ADP
iajs-3313	1	7	a	a	DET
iajs-3313	1	8	creative	creative	ADJ
iajs-3313	1	9	commons	common	NOUN
iajs-3313	1	10	attribution	attribution	NOUN
iajs-3313	1	11	4.0	4.0	NUM
iajs-3313	1	12	international	international	ADJ
iajs-3313	1	13	license	license	NOUN
iajs-3313	1	14	ihjpas	ihjpa	NOUN
iajs-3313	1	15	.	.	PUNCT
iajs-3313	2	1	37	37	NUM
iajs-3313	2	2	(	(	PUNCT
iajs-3313	2	3	2	2	NUM
iajs-3313	2	4	)	)	PUNCT
iajs-3313	2	5	2024	2024	NUM
iajs-3313	2	6	ibn	ibn	PROPN
iajs-3313	2	7	al	al	PROPN
iajs-3313	2	8	-	-	PUNCT
iajs-3313	2	9	haitham	haitham	PROPN
iajs-3313	2	10	journal	journal	PROPN
iajs-3313	2	11	for	for	ADP
iajs-3313	2	12	pure	pure	ADJ
iajs-3313	2	13	and	and	CCONJ
iajs-3313	2	14	applied	applied	ADJ
iajs-3313	2	15	sciences	sciences	PROPN
iajs-3313	2	16	journal	journal	PROPN
iajs-3313	2	17	homepage	homepage	NOUN
iajs-3313	2	18	:	:	PUNCT
iajs-3313	2	19	jih.uobaghdad.edu.iq	jih.uobaghdad.edu.iq	NOUN
iajs-3313	2	20	pissn	pissn	ADJ
iajs-3313	2	21	:	:	PUNCT
iajs-3313	2	22	1609	1609	NUM
iajs-3313	2	23	-	-	SYM
iajs-3313	2	24	4042	4042	NUM
iajs-3313	2	25	,	,	PUNCT
iajs-3313	2	26	eissn	eissn	NOUN
iajs-3313	2	27	:	:	PUNCT
iajs-3313	2	28	2521	2521	NUM
iajs-3313	2	29	-	-	SYM
iajs-3313	2	30	3407	3407	NUM
iajs-3313	2	31	abdullah	abdullah	PROPN
iajs-3313	2	32	sh	sh	PROPN
iajs-3313	2	33	.	.	PROPN
iajs-3313	2	34	abdullah	abdullah	PROPN
iajs-3313	2	35	alani	alani	PROPN
iajs-3313	2	36	1	1	NUM
iajs-3313	2	37	*	*	PUNCT
iajs-3313	2	38	,	,	PUNCT
iajs-3313	2	39	basima	basima	PROPN
iajs-3313	2	40	muhsen	muhsen	NOUN
iajs-3313	2	41	sarhan	sarhan	ADP
iajs-3313	2	42	2	2	NUM
iajs-3313	2	43	and	and	CCONJ
iajs-3313	2	44	vishwa	vishwa	PROPN
iajs-3313	2	45	deepak	deepak	PROPN
iajs-3313	2	46	tripathi	tripathi	PROPN
iajs-3313	2	47	3	3	NUM
iajs-3313	2	48	1	1	NUM
iajs-3313	2	49	directorate	directorate	NOUN
iajs-3313	2	50	of	of	ADP
iajs-3313	2	51	institutional	institutional	ADJ
iajs-3313	2	52	development	development	NOUN
iajs-3313	2	53	and	and	CCONJ
iajs-3313	2	54	government	government	NOUN
iajs-3313	2	55	coordination	coordination	NOUN
iajs-3313	2	56	,	,	PUNCT
iajs-3313	2	57	iraqi	iraqi	ADJ
iajs-3313	2	58	ministry	ministry	PROPN
iajs-3313	2	59	of	of	ADP
iajs-3313	2	60	education	education	PROPN
iajs-3313	2	61	,	,	PUNCT
iajs-3313	2	62	baghdad	baghdad	PROPN
iajs-3313	2	63	,	,	PUNCT
iajs-3313	2	64	iraq	iraq	PROPN
iajs-3313	2	65	.	.	PUNCT
iajs-3313	3	1	2	2	NUM
iajs-3313	3	2	department	department	NOUN
iajs-3313	3	3	of	of	ADP
iajs-3313	3	4	chemistry	chemistry	NOUN
iajs-3313	3	5	,	,	PUNCT
iajs-3313	3	6	college	college	NOUN
iajs-3313	3	7	of	of	ADP
iajs-3313	3	8	education	education	NOUN
iajs-3313	3	9	for	for	ADP
iajs-3313	3	10	pure	pure	ADJ
iajs-3313	3	11	science	science	NOUN
iajs-3313	3	12	(	(	PUNCT
iajs-3313	3	13	ibn	ibn	PROPN
iajs-3313	3	14	al	al	PROPN
iajs-3313	3	15	–	–	PUNCT
iajs-3313	3	16	haitham	haitham	PROPN
iajs-3313	3	17	)	)	PUNCT
iajs-3313	3	18	,	,	PUNCT
iajs-3313	3	19	university	university	NOUN
iajs-3313	3	20	of	of	ADP
iajs-3313	3	21	baghdad	baghdad	PROPN
iajs-3313	3	22	,	,	PUNCT
iajs-3313	3	23	baghdad	baghdad	PROPN
iajs-3313	3	24	,	,	PUNCT
iajs-3313	3	25	iraq	iraq	PROPN
iajs-3313	3	26	.	.	PUNCT
iajs-3313	4	1	3	3	NUM
iajs-3313	4	2	department	department	NOUN
iajs-3313	4	3	of	of	ADP
iajs-3313	4	4	chemstry	chemstry	PROPN
iajs-3313	4	5	,	,	PUNCT
iajs-3313	4	6	c.m	c.m	PROPN
iajs-3313	4	7	.	.	PROPN
iajs-3313	4	8	science	science	PROPN
iajs-3313	4	9	college	college	PROPN
iajs-3313	4	10	,	,	PUNCT
iajs-3313	4	11	lalit	lalit	PROPN
iajs-3313	4	12	narayan	narayan	PROPN
iajs-3313	4	13	mithila	mithila	PROPN
iajs-3313	4	14	university	university	PROPN
iajs-3313	4	15	,	,	PUNCT
iajs-3313	4	16	darbhanga	darbhanga	NOUN
iajs-3313	4	17	,	,	PUNCT
iajs-3313	4	18	bihar	bihar	PROPN
iajs-3313	4	19	,	,	PUNCT
iajs-3313	4	20	india	india	PROPN
iajs-3313	4	21	.	.	PUNCT
iajs-3313	5	1	*	*	PUNCT
iajs-3313	5	2	corresponding	correspond	VERB
iajs-3313	5	3	author	author	NOUN
iajs-3313	5	4	.	.	PUNCT
iajs-3313	6	1	abstract	abstract	ADJ
iajs-3313	6	2	this	this	DET
iajs-3313	6	3	study	study	NOUN
iajs-3313	6	4	included	include	VERB
iajs-3313	6	5	the	the	DET
iajs-3313	6	6	preparation	preparation	NOUN
iajs-3313	6	7	and	and	CCONJ
iajs-3313	6	8	characterization	characterization	NOUN
iajs-3313	6	9	of	of	ADP
iajs-3313	6	10	the	the	DET
iajs-3313	6	11	new	new	ADJ
iajs-3313	6	12	guanine	guanine	NOUN
iajs-3313	6	13	derivative	derivative	NOUN
iajs-3313	6	14	(	(	PUNCT
iajs-3313	6	15	n((6	n((6	NOUN
iajs-3313	6	16	-	-	PUNCT
iajs-3313	6	17	oxo-6,9	oxo-6,9	ADJ
iajs-3313	6	18	-	-	PUNCT
iajs-3313	6	19	dihydro-1h	dihydro-1h	NOUN
iajs-3313	6	20	-	-	PUNCT
iajs-3313	6	21	purin-2	purin-2	NOUN
iajs-3313	6	22	-	-	PUNCT
iajs-3313	6	23	yl)carbamothioyl)propionamide	yl)carbamothioyl)propionamide	NOUN
iajs-3313	6	24	)	)	PUNCT
iajs-3313	6	25	,	,	PUNCT
iajs-3313	6	26	with	with	ADP
iajs-3313	6	27	an	an	DET
iajs-3313	6	28	exciting	exciting	ADJ
iajs-3313	6	29	chemical	chemical	NOUN
iajs-3313	6	30	structure	structure	NOUN
iajs-3313	6	31	.	.	PUNCT
iajs-3313	7	1	the	the	DET
iajs-3313	7	2	guanine	guanine	NOUN
iajs-3313	7	3	part	part	NOUN
iajs-3313	7	4	is	be	AUX
iajs-3313	7	5	a	a	DET
iajs-3313	7	6	bicyclic	bicyclic	ADJ
iajs-3313	7	7	heterocyclic	heterocyclic	ADJ
iajs-3313	7	8	base	base	NOUN
iajs-3313	7	9	that	that	PRON
iajs-3313	7	10	is	be	AUX
iajs-3313	7	11	connected	connect	VERB
iajs-3313	7	12	to	to	ADP
iajs-3313	7	13	a	a	DET
iajs-3313	7	14	carbamothioyl	carbamothioyl	ADJ
iajs-3313	7	15	group	group	NOUN
iajs-3313	7	16	by	by	ADP
iajs-3313	7	17	a	a	DET
iajs-3313	7	18	propionamide	propionamide	NOUN
iajs-3313	7	19	linker	linker	NOUN
iajs-3313	7	20	.	.	PUNCT
iajs-3313	8	1	this	this	DET
iajs-3313	8	2	nitrogenous	nitrogenous	ADJ
iajs-3313	8	3	base	base	NOUN
iajs-3313	8	4	derivative	derivative	NOUN
iajs-3313	8	5	is	be	AUX
iajs-3313	8	6	prepared	prepare	VERB
iajs-3313	8	7	in	in	ADP
iajs-3313	8	8	two	two	NUM
iajs-3313	8	9	steps	step	NOUN
iajs-3313	8	10	:	:	PUNCT
iajs-3313	8	11	the	the	DET
iajs-3313	8	12	first	first	ADJ
iajs-3313	8	13	step	step	NOUN
iajs-3313	8	14	involves	involve	VERB
iajs-3313	8	15	the	the	DET
iajs-3313	8	16	synthesis	synthesis	NOUN
iajs-3313	8	17	of	of	ADP
iajs-3313	8	18	propionyl	propionyl	NOUN
iajs-3313	8	19	isothiocyanate	isothiocyanate	NOUN
iajs-3313	8	20	from	from	ADP
iajs-3313	8	21	the	the	DET
iajs-3313	8	22	reaction	reaction	NOUN
iajs-3313	8	23	of	of	ADP
iajs-3313	8	24	propionyl	propionyl	NOUN
iajs-3313	8	25	chloride	chloride	NOUN
iajs-3313	8	26	with	with	ADP
iajs-3313	8	27	ammonium	ammonium	NOUN
iajs-3313	8	28	thiocyanate	thiocyanate	NOUN
iajs-3313	8	29	in	in	ADP
iajs-3313	8	30	acetone	acetone	NOUN
iajs-3313	8	31	.	.	PUNCT
iajs-3313	9	1	in	in	ADP
iajs-3313	9	2	contrast	contrast	NOUN
iajs-3313	9	3	,	,	PUNCT
iajs-3313	9	4	the	the	DET
iajs-3313	9	5	second	second	ADJ
iajs-3313	9	6	step	step	NOUN
iajs-3313	9	7	consists	consist	VERB
iajs-3313	9	8	of	of	ADP
iajs-3313	9	9	the	the	DET
iajs-3313	9	10	reaction	reaction	NOUN
iajs-3313	9	11	of	of	ADP
iajs-3313	9	12	ammonium	ammonium	NOUN
iajs-3313	9	13	thiocyanate	thiocyanate	NOUN
iajs-3313	9	14	with	with	ADP
iajs-3313	9	15	guanine	guanine	NOUN
iajs-3313	9	16	to	to	PART
iajs-3313	9	17	obtain	obtain	VERB
iajs-3313	9	18	the	the	DET
iajs-3313	9	19	ligand	ligand	NOUN
iajs-3313	9	20	.	.	PUNCT
iajs-3313	10	1	the	the	DET
iajs-3313	10	2	study	study	NOUN
iajs-3313	10	3	also	also	ADV
iajs-3313	10	4	includes	include	VERB
iajs-3313	10	5	the	the	DET
iajs-3313	10	6	preparation	preparation	NOUN
iajs-3313	10	7	of	of	ADP
iajs-3313	10	8	new	new	ADJ
iajs-3313	10	9	complexes	complex	NOUN
iajs-3313	10	10	of	of	ADP
iajs-3313	10	11	metal	metal	NOUN
iajs-3313	10	12	ions	ion	NOUN
iajs-3313	10	13	(	(	PUNCT
iajs-3313	10	14	mn	mn	NOUN
iajs-3313	10	15	+2	+2	PROPN
iajs-3313	10	16	,	,	PUNCT
iajs-3313	10	17	co	co	VERB
iajs-3313	10	18	+2	+2	PROPN
iajs-3313	10	19	,	,	PUNCT
iajs-3313	10	20	ni	ni	PROPN
iajs-3313	10	21	+2	+2	PROPN
iajs-3313	10	22	,	,	PUNCT
iajs-3313	10	23	cu	cu	PROPN
iajs-3313	10	24	+2	+2	PROPN
iajs-3313	10	25	,	,	PUNCT
iajs-3313	10	26	zn	zn	INTJ
iajs-3313	10	27	+2	+2	PROPN
iajs-3313	10	28	,	,	PUNCT
iajs-3313	10	29	cd	cd	VERB
iajs-3313	10	30	+2	+2	PRON
iajs-3313	10	31	,	,	PUNCT
iajs-3313	10	32	and	and	CCONJ
iajs-3313	10	33	pd	pd	PROPN
iajs-3313	10	34	+2	+2	PROPN
iajs-3313	10	35	)	)	PUNCT
iajs-3313	10	36	with	with	ADP
iajs-3313	10	37	a	a	DET
iajs-3313	10	38	prepared	prepared	ADJ
iajs-3313	10	39	guanine	guanine	NOUN
iajs-3313	10	40	derivative	derivative	NOUN
iajs-3313	10	41	.	.	PUNCT
iajs-3313	11	1	the	the	DET
iajs-3313	11	2	ligand	ligand	NOUN
iajs-3313	11	3	and	and	CCONJ
iajs-3313	11	4	complexes	complex	NOUN
iajs-3313	11	5	were	be	AUX
iajs-3313	11	6	characterized	characterize	VERB
iajs-3313	11	7	by	by	ADP
iajs-3313	11	8	using	use	VERB
iajs-3313	11	9	infrared	infrared	ADJ
iajs-3313	11	10	spectra	spectra	PROPN
iajs-3313	11	11	,	,	PUNCT
iajs-3313	11	12	ultraviolet	ultraviolet	ADJ
iajs-3313	11	13	-	-	PUNCT
iajs-3313	11	14	visible	visible	ADJ
iajs-3313	11	15	spectra	spectra	NOUN
iajs-3313	11	16	,	,	PUNCT
iajs-3313	11	17	1	1	NUM
iajs-3313	11	18	h	h	NOUN
iajs-3313	11	19	-	-	PUNCT
iajs-3313	11	20	n.m.r	n.m.r	NOUN
iajs-3313	11	21	.	.	PUNCT
iajs-3313	11	22	,	,	PUNCT
iajs-3313	11	23	13	13	NUM
iajs-3313	11	24	c	c	NOUN
iajs-3313	11	25	-	-	PUNCT
iajs-3313	11	26	n.m.r	n.m.r	ADJ
iajs-3313	11	27	.	.	PUNCT
iajs-3313	11	28	spectra	spectra	PROPN
iajs-3313	11	29	,	,	PUNCT
iajs-3313	11	30	and	and	CCONJ
iajs-3313	11	31	elemental	elemental	ADJ
iajs-3313	11	32	analysis	analysis	NOUN
iajs-3313	11	33	(	(	PUNCT
iajs-3313	11	34	c.h.n.s	c.h.n.s	PROPN
iajs-3313	11	35	.	.	PROPN
iajs-3313	11	36	):	):	PUNCT
iajs-3313	11	37	molar	molar	ADJ
iajs-3313	11	38	conductivity	conductivity	NOUN
iajs-3313	11	39	measurement	measurement	NOUN
iajs-3313	11	40	,	,	PUNCT
iajs-3313	11	41	magnetic	magnetic	ADJ
iajs-3313	11	42	susceptibility	susceptibility	NOUN
iajs-3313	11	43	,	,	PUNCT
iajs-3313	11	44	atomic	atomic	ADJ
iajs-3313	11	45	absorption	absorption	NOUN
iajs-3313	11	46	,	,	PUNCT
iajs-3313	11	47	and	and	CCONJ
iajs-3313	11	48	melting	melting	NOUN
iajs-3313	11	49	point	point	NOUN
iajs-3313	11	50	.	.	PUNCT
iajs-3313	12	1	the	the	DET
iajs-3313	12	2	results	result	NOUN
iajs-3313	12	3	of	of	ADP
iajs-3313	12	4	these	these	DET
iajs-3313	12	5	studies	study	NOUN
iajs-3313	12	6	showed	show	VERB
iajs-3313	12	7	that	that	SCONJ
iajs-3313	12	8	general	general	ADJ
iajs-3313	12	9	formulas	formula	NOUN
iajs-3313	12	10	for	for	ADP
iajs-3313	12	11	these	these	DET
iajs-3313	12	12	complexes	complex	NOUN
iajs-3313	12	13	were	be	AUX
iajs-3313	12	14	given	give	VERB
iajs-3313	12	15	[	[	PUNCT
iajs-3313	12	16	mcl2(o.p.p.)2	mcl2(o.p.p.)2	NOUN
iajs-3313	12	17	]	]	X
iajs-3313	12	18	,	,	PUNCT
iajs-3313	12	19	m	m	VERB
iajs-3313	12	20	=	=	SYM
iajs-3313	12	21	(	(	PUNCT
iajs-3313	12	22	mn	mn	PROPN
iajs-3313	12	23	+2	+2	PROPN
iajs-3313	12	24	,	,	PUNCT
iajs-3313	12	25	co	co	VERB
iajs-3313	12	26	+2	+2	PROPN
iajs-3313	12	27	,	,	PUNCT
iajs-3313	12	28	ni	ni	PROPN
iajs-3313	12	29	+2	+2	PROPN
iajs-3313	12	30	,	,	PUNCT
iajs-3313	12	31	cu	cu	PROPN
iajs-3313	12	32	+2	+2	PROPN
iajs-3313	12	33	,	,	PUNCT
iajs-3313	12	34	zn	zn	INTJ
iajs-3313	12	35	+2	+2	PROPN
iajs-3313	12	36	,	,	PUNCT
iajs-3313	12	37	cd	cd	VERB
iajs-3313	12	38	+2	+2	PRON
iajs-3313	12	39	,	,	PUNCT
iajs-3313	12	40	and	and	CCONJ
iajs-3313	12	41	pd	pd	NOUN
iajs-3313	12	42	+2	+2	PROPN
iajs-3313	12	43	)	)	PUNCT
iajs-3313	12	44	.	.	PUNCT
iajs-3313	13	1	it	it	PRON
iajs-3313	13	2	was	be	AUX
iajs-3313	13	3	found	find	VERB
iajs-3313	13	4	that	that	SCONJ
iajs-3313	13	5	the	the	DET
iajs-3313	13	6	geometric	geometric	ADJ
iajs-3313	13	7	shape	shape	NOUN
iajs-3313	13	8	of	of	ADP
iajs-3313	13	9	all	all	DET
iajs-3313	13	10	the	the	DET
iajs-3313	13	11	prepared	prepared	ADJ
iajs-3313	13	12	complexes	complex	NOUN
iajs-3313	13	13	was	be	AUX
iajs-3313	13	14	an	an	DET
iajs-3313	13	15	octahedron	octahedron	NOUN
iajs-3313	13	16	.	.	PUNCT
iajs-3313	14	1	keywords	keyword	NOUN
iajs-3313	14	2	:	:	PUNCT
iajs-3313	14	3	guanine	guanine	NOUN
iajs-3313	14	4	,	,	PUNCT
iajs-3313	14	5	propionyl	propionyl	NOUN
iajs-3313	14	6	chloride	chloride	NOUN
iajs-3313	14	7	,	,	PUNCT
iajs-3313	14	8	isothiocyanate	isothiocyanate	NOUN
iajs-3313	14	9	,	,	PUNCT
iajs-3313	14	10	coordination	coordination	NOUN
iajs-3313	14	11	complexes	complex	NOUN
iajs-3313	14	12	,	,	PUNCT
iajs-3313	14	13	organometallic	organometallic	ADJ
iajs-3313	14	14	compounds	compound	NOUN
iajs-3313	14	15	.	.	PUNCT
iajs-3313	15	1	1	1	X
iajs-3313	15	2	.	.	X
iajs-3313	15	3	introduction	introduction	NOUN
iajs-3313	15	4	bioinorganic	bioinorganic	NOUN
iajs-3313	15	5	chemistry	chemistry	NOUN
iajs-3313	15	6	is	be	AUX
iajs-3313	15	7	a	a	DET
iajs-3313	15	8	field	field	NOUN
iajs-3313	15	9	of	of	ADP
iajs-3313	15	10	chemistry	chemistry	NOUN
iajs-3313	15	11	that	that	PRON
iajs-3313	15	12	focuses	focus	VERB
iajs-3313	15	13	on	on	ADP
iajs-3313	15	14	the	the	DET
iajs-3313	15	15	study	study	NOUN
iajs-3313	15	16	of	of	ADP
iajs-3313	15	17	the	the	DET
iajs-3313	15	18	interactions	interaction	NOUN
iajs-3313	15	19	between	between	ADP
iajs-3313	15	20	inorganic	inorganic	ADJ
iajs-3313	15	21	molecules	molecule	NOUN
iajs-3313	15	22	and	and	CCONJ
iajs-3313	15	23	biological	biological	ADJ
iajs-3313	15	24	systems	system	NOUN
iajs-3313	15	25	.	.	PUNCT
iajs-3313	16	1	it	it	PRON
iajs-3313	16	2	involves	involve	VERB
iajs-3313	16	3	the	the	DET
iajs-3313	16	4	study	study	NOUN
iajs-3313	16	5	of	of	ADP
iajs-3313	16	6	metal	metal	NOUN
iajs-3313	16	7	ions	ion	NOUN
iajs-3313	16	8	and	and	CCONJ
iajs-3313	16	9	their	their	PRON
iajs-3313	16	10	coordination	coordination	NOUN
iajs-3313	16	11	chemistry	chemistry	NOUN
iajs-3313	16	12	in	in	ADP
iajs-3313	16	13	biological	biological	ADJ
iajs-3313	16	14	systems	system	NOUN
iajs-3313	16	15	,	,	PUNCT
iajs-3313	16	16	as	as	ADV
iajs-3313	16	17	well	well	ADV
iajs-3313	16	18	as	as	ADP
iajs-3313	16	19	the	the	DET
iajs-3313	16	20	role	role	NOUN
iajs-3313	16	21	of	of	ADP
iajs-3313	16	22	inorganic	inorganic	ADJ
iajs-3313	16	23	elements	element	NOUN
iajs-3313	16	24	and	and	CCONJ
iajs-3313	16	25	compounds	compound	NOUN
iajs-3313	16	26	in	in	ADP
iajs-3313	16	27	biological	biological	ADJ
iajs-3313	16	28	processes	process	NOUN
iajs-3313	16	29	[	[	X
iajs-3313	16	30	1,2	1,2	NUM
iajs-3313	16	31	]	]	PUNCT
iajs-3313	16	32	.	.	PUNCT
iajs-3313	17	1	received	receive	VERB
iajs-3313	17	2	:	:	PUNCT
iajs-3313	17	3	6	6	NUM
iajs-3313	17	4	march	march	NOUN
iajs-3313	17	5	2023	2023	NUM
iajs-3313	17	6	accepted	accept	VERB
iajs-3313	17	7	:	:	PUNCT
iajs-3313	17	8	23	23	NUM
iajs-3313	17	9	may	may	AUX
iajs-3313	17	10	2023	2023	NUM
iajs-3313	17	11	published	publish	VERB
iajs-3313	17	12	:	:	PUNCT
iajs-3313	17	13	20	20	NUM
iajs-3313	17	14	april	april	PROPN
iajs-3313	17	15	2024	2024	NUM
iajs-3313	17	16	synthesis	synthesis	NOUN
iajs-3313	17	17	and	and	CCONJ
iajs-3313	17	18	spectral	spectral	ADJ
iajs-3313	17	19	study	study	NOUN
iajs-3313	17	20	of	of	ADP
iajs-3313	17	21	new	new	ADJ
iajs-3313	17	22	guanine	guanine	NOUN
iajs-3313	17	23	derivative	derivative	NOUN
iajs-3313	17	24	(	(	PUNCT
iajs-3313	17	25	n-((6	n-((6	NUM
iajs-3313	17	26	-	-	PUNCT
iajs-3313	17	27	oxo-6,9	oxo-6,9	ADJ
iajs-3313	17	28	-	-	PUNCT
iajs-3313	17	29	dihydro1h	dihydro1h	NOUN
iajs-3313	17	30	-	-	PUNCT
iajs-3313	17	31	purin-2	purin-2	NOUN
iajs-3313	17	32	-	-	NOUN
iajs-3313	17	33	yl)carbamothioyl)propionamide	yl)carbamothioyl)propionamide	NOUN
iajs-3313	17	34	)	)	PUNCT
iajs-3313	17	35	and	and	CCONJ
iajs-3313	17	36	its	its	PRON
iajs-3313	17	37	complexes	complex	NOUN
iajs-3313	17	38	with	with	ADP
iajs-3313	17	39	some	some	DET
iajs-3313	17	40	metals	metal	NOUN
iajs-3313	17	41	ion	ion	NOUN
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iajs-3313	17	45	mailto:abdulaalany@googlemail.com	mailto:abdulaalany@googlemail.com	PROPN
iajs-3313	17	46	https://orcid.org/0000-0003-3813-5982	https://orcid.org/0000-0003-3813-5982	PROPN
iajs-3313	17	47	mailto:bmsarhan@yahoo.com	mailto:bmsarhan@yahoo.com	PROPN
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iajs-3313	17	49	mailto:vdtmkclnmu@gmail.com	mailto:vdtmkclnmu@gmail.com	PROPN
iajs-3313	17	50	https://orcid.org/0000-0002-4820-0859	https://orcid.org/0000-0002-4820-0859	PROPN
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iajs-3313	17	52	https://orcid.org/0000-0003-3813-5982	https://orcid.org/0000-0003-3813-5982	PROPN
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iajs-3313	17	55	mailto:vdtmkclnmu@gmail.com	mailto:vdtmkclnmu@gmail.com	PROPN
iajs-3313	17	56	https://orcid.org/0000-0002-4820-0859	https://orcid.org/0000-0002-4820-0859	PROPN
iajs-3313	17	57	mailto:abdulaalany@googlemail.com	mailto:abdulaalany@googlemail.com	PROPN
iajs-3313	17	58	https://orcid.org/0000-0003-3813-5982	https://orcid.org/0000-0003-3813-5982	PROPN
iajs-3313	17	59	mailto:bmsarhan@yahoo.com	mailto:bmsarhan@yahoo.com	PROPN
iajs-3313	18	1	https://orcid.org/0000-0003-2802-0292	https://orcid.org/0000-0003-2802-0292	PROPN
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iajs-3313	19	14	mailto:vdtmkclnmu@gmail.com	mailto:vdtmkclnmu@gmail.com	PROPN
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iajs-3313	19	20	mailto:vdtmkclnmu@gmail.com	mailto:vdtmkclnmu@gmail.com	PROPN
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iajs-3313	19	22	mailto:abdulaalany@googlemail.com	mailto:abdulaalany@googlemail.com	PROPN
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iajs-3313	19	24	mailto:bmsarhan@yahoo.com	mailto:bmsarhan@yahoo.com	PROPN
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iajs-3313	19	26	mailto:vdtmkclnmu@gmail.com	mailto:vdtmkclnmu@gmail.com	PROPN
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iajs-3313	19	34	mailto:abdulaalany@googlemail.com	mailto:abdulaalany@googlemail.com	PROPN
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iajs-3313	19	36	mailto:bmsarhan@yahoo.com	mailto:bmsarhan@yahoo.com	PROPN
iajs-3313	19	37	https://orcid.org/0000-0003-2802-0292	https://orcid.org/0000-0003-2802-0292	PROPN
iajs-3313	19	38	mailto:vdtmkclnmu@gmail.com	mailto:vdtmkclnmu@gmail.com	PROPN
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iajs-3313	19	41	https://orcid.org/0000-0003-3813-5982	https://orcid.org/0000-0003-3813-5982	PROPN
iajs-3313	19	42	mailto:bmsarhan@yahoo.com	mailto:bmsarhan@yahoo.com	PROPN
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iajs-3313	19	44	mailto:vdtmkclnmu@gmail.com	mailto:vdtmkclnmu@gmail.com	PROPN
iajs-3313	19	45	https://orcid.org/0000-0002-4820-0859	https://orcid.org/0000-0002-4820-0859	PROPN
iajs-3313	19	46	mailto:abdulaalany@googlemail.com	mailto:abdulaalany@googlemail.com	PROPN
iajs-3313	19	47	https://orcid.org/0000-0003-3813-5982	https://orcid.org/0000-0003-3813-5982	PROPN
iajs-3313	19	48	mailto:bmsarhan@yahoo.com	mailto:bmsarhan@yahoo.com	PROPN
iajs-3313	19	49	https://orcid.org/0000-0003-2802-0292	https://orcid.org/0000-0003-2802-0292	PROPN
iajs-3313	19	50	mailto:vdtmkclnmu@gmail.com	mailto:vdtmkclnmu@gmail.com	PROPN
iajs-3313	19	51	https://orcid.org/0000-0002-4820-0859	https://orcid.org/0000-0002-4820-0859	PROPN
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iajs-3313	19	55	https://orcid.org/0000-0003-2802-0292	https://orcid.org/0000-0003-2802-0292	PROPN
iajs-3313	19	56	mailto:vdtmkclnmu@gmail.com	mailto:vdtmkclnmu@gmail.com	PROPN
iajs-3313	19	57	https://orcid.org/0000-0002-4820-0859	https://orcid.org/0000-0002-4820-0859	PROPN
iajs-3313	19	58	mailto:abdulaalany@googlemail.com	mailto:abdulaalany@googlemail.com	PROPN
iajs-3313	19	59	https://orcid.org/0000-0003-3813-5982	https://orcid.org/0000-0003-3813-5982	PROPN
iajs-3313	19	60	mailto:bmsarhan@yahoo.com	mailto:bmsarhan@yahoo.com	PROPN
iajs-3313	19	61	https://orcid.org/0000-0003-2802-0292	https://orcid.org/0000-0003-2802-0292	PROPN
iajs-3313	19	62	mailto:vdtmkclnmu@gmail.com	mailto:vdtmkclnmu@gmail.com	PROPN
iajs-3313	19	63	https://orcid.org/0000-0002-4820-0859	https://orcid.org/0000-0002-4820-0859	PROPN
iajs-3313	19	64	mailto:abdulaalany@googlemail.com	mailto:abdulaalany@googlemail.com	PROPN
iajs-3313	19	65	https://orcid.org/0000-0003-3813-5982	https://orcid.org/0000-0003-3813-5982	PROPN
iajs-3313	19	66	mailto:bmsarhan@yahoo.com	mailto:bmsarhan@yahoo.com	PROPN
iajs-3313	19	67	https://orcid.org/0000-0003-2802-0292	https://orcid.org/0000-0003-2802-0292	PROPN
iajs-3313	19	68	mailto:vdtmkclnmu@gmail.com	mailto:vdtmkclnmu@gmail.com	PROPN
iajs-3313	19	69	ihjpas	ihjpas	PROPN
iajs-3313	19	70	.	.	PUNCT
iajs-3313	20	1	37	37	NUM
iajs-3313	20	2	(	(	PUNCT
iajs-3313	20	3	2	2	NUM
iajs-3313	20	4	)	)	PUNCT
iajs-3313	20	5	2024	2024	NUM
iajs-3313	20	6	286	286	NUM
iajs-3313	20	7	the	the	DET
iajs-3313	20	8	preparation	preparation	NOUN
iajs-3313	20	9	of	of	ADP
iajs-3313	20	10	metallic	metallic	ADJ
iajs-3313	20	11	coordination	coordination	NOUN
iajs-3313	20	12	complexes	complex	NOUN
iajs-3313	20	13	with	with	ADP
iajs-3313	20	14	biological	biological	ADJ
iajs-3313	20	15	molecules	molecule	NOUN
iajs-3313	20	16	is	be	AUX
iajs-3313	20	17	an	an	DET
iajs-3313	20	18	active	active	ADJ
iajs-3313	20	19	area	area	NOUN
iajs-3313	20	20	of	of	ADP
iajs-3313	20	21	research	research	NOUN
iajs-3313	20	22	in	in	ADP
iajs-3313	20	23	bioinorganic	bioinorganic	ADJ
iajs-3313	20	24	chemistry	chemistry	NOUN
iajs-3313	20	25	because	because	SCONJ
iajs-3313	20	26	these	these	DET
iajs-3313	20	27	complexes	complex	NOUN
iajs-3313	20	28	can	can	AUX
iajs-3313	20	29	have	have	VERB
iajs-3313	20	30	a	a	DET
iajs-3313	20	31	variety	variety	NOUN
iajs-3313	20	32	of	of	ADP
iajs-3313	20	33	biological	biological	ADJ
iajs-3313	20	34	applications	application	NOUN
iajs-3313	20	35	.	.	PUNCT
iajs-3313	21	1	for	for	ADP
iajs-3313	21	2	example	example	NOUN
iajs-3313	21	3	,	,	PUNCT
iajs-3313	21	4	some	some	PRON
iajs-3313	21	5	of	of	ADP
iajs-3313	21	6	these	these	DET
iajs-3313	21	7	complexes	complex	NOUN
iajs-3313	21	8	have	have	AUX
iajs-3313	21	9	been	be	AUX
iajs-3313	21	10	studied	study	VERB
iajs-3313	21	11	for	for	ADP
iajs-3313	21	12	their	their	PRON
iajs-3313	21	13	potential	potential	ADJ
iajs-3313	21	14	use	use	NOUN
iajs-3313	21	15	as	as	ADP
iajs-3313	21	16	anticancer	anticancer	NOUN
iajs-3313	21	17	agents	agent	NOUN
iajs-3313	21	18	,	,	PUNCT
iajs-3313	21	19	antibacterials	antibacterial	NOUN
iajs-3313	21	20	,	,	PUNCT
iajs-3313	21	21	antifungals	antifungal	NOUN
iajs-3313	21	22	,	,	PUNCT
iajs-3313	21	23	or	or	CCONJ
iajs-3313	21	24	catalysts	catalyst	NOUN
iajs-3313	21	25	for	for	ADP
iajs-3313	21	26	important	important	ADJ
iajs-3313	21	27	biological	biological	ADJ
iajs-3313	21	28	reactions	reaction	NOUN
iajs-3313	21	29	[	[	X
iajs-3313	21	30	3–10	3–10	NOUN
iajs-3313	21	31	]	]	PUNCT
iajs-3313	21	32	.	.	PUNCT
iajs-3313	22	1	the	the	DET
iajs-3313	22	2	preparation	preparation	NOUN
iajs-3313	22	3	of	of	ADP
iajs-3313	22	4	these	these	DET
iajs-3313	22	5	complexes	complex	NOUN
iajs-3313	22	6	often	often	ADV
iajs-3313	22	7	involves	involve	VERB
iajs-3313	22	8	modifying	modify	VERB
iajs-3313	22	9	the	the	DET
iajs-3313	22	10	biological	biological	ADJ
iajs-3313	22	11	molecules	molecule	NOUN
iajs-3313	22	12	to	to	PART
iajs-3313	22	13	create	create	VERB
iajs-3313	22	14	ligands	ligand	NOUN
iajs-3313	22	15	that	that	PRON
iajs-3313	22	16	can	can	AUX
iajs-3313	22	17	coordinate	coordinate	VERB
iajs-3313	22	18	with	with	ADP
iajs-3313	22	19	metal	metal	NOUN
iajs-3313	22	20	ions	ion	NOUN
iajs-3313	22	21	and	and	CCONJ
iajs-3313	22	22	form	form	VERB
iajs-3313	22	23	stable	stable	ADJ
iajs-3313	22	24	complexes	complex	NOUN
iajs-3313	22	25	[	[	X
iajs-3313	22	26	3,10–14	3,10–14	NUM
iajs-3313	22	27	]	]	PUNCT
iajs-3313	22	28	.	.	PUNCT
iajs-3313	23	1	this	this	PRON
iajs-3313	23	2	can	can	AUX
iajs-3313	23	3	affect	affect	VERB
iajs-3313	23	4	the	the	DET
iajs-3313	23	5	use	use	NOUN
iajs-3313	23	6	of	of	ADP
iajs-3313	23	7	synthetic	synthetic	ADJ
iajs-3313	23	8	organic	organic	ADJ
iajs-3313	23	9	chemistry	chemistry	NOUN
iajs-3313	23	10	techniques	technique	NOUN
iajs-3313	23	11	to	to	PART
iajs-3313	23	12	develop	develop	VERB
iajs-3313	23	13	modified	modified	ADJ
iajs-3313	23	14	versions	version	NOUN
iajs-3313	23	15	of	of	ADP
iajs-3313	23	16	naturally	naturally	ADV
iajs-3313	23	17	occurring	occur	VERB
iajs-3313	23	18	biological	biological	ADJ
iajs-3313	23	19	molecules	molecule	NOUN
iajs-3313	23	20	or	or	CCONJ
iajs-3313	23	21	the	the	DET
iajs-3313	23	22	development	development	NOUN
iajs-3313	23	23	of	of	ADP
iajs-3313	23	24	entirely	entirely	ADV
iajs-3313	23	25	new	new	ADJ
iajs-3313	23	26	ligands	ligand	NOUN
iajs-3313	23	27	that	that	PRON
iajs-3313	23	28	can	can	AUX
iajs-3313	23	29	alter	alter	VERB
iajs-3313	23	30	the	the	DET
iajs-3313	23	31	properties	property	NOUN
iajs-3313	23	32	of	of	ADP
iajs-3313	23	33	biological	biological	ADJ
iajs-3313	23	34	molecules	molecule	NOUN
iajs-3313	23	35	[	[	X
iajs-3313	23	36	4,15–17	4,15–17	NUM
iajs-3313	23	37	]	]	PUNCT
iajs-3313	23	38	.	.	PUNCT
iajs-3313	24	1	the	the	DET
iajs-3313	24	2	objective	objective	NOUN
iajs-3313	24	3	of	of	ADP
iajs-3313	24	4	this	this	DET
iajs-3313	24	5	study	study	NOUN
iajs-3313	24	6	is	be	AUX
iajs-3313	24	7	to	to	PART
iajs-3313	24	8	synthesize	synthesize	VERB
iajs-3313	24	9	and	and	CCONJ
iajs-3313	24	10	analyze	analyze	VERB
iajs-3313	24	11	the	the	DET
iajs-3313	24	12	properties	property	NOUN
iajs-3313	24	13	of	of	ADP
iajs-3313	24	14	a	a	DET
iajs-3313	24	15	novel	novel	ADJ
iajs-3313	24	16	ligand	ligand	NOUN
iajs-3313	24	17	(	(	PUNCT
iajs-3313	24	18	opp	opp	PROPN
iajs-3313	24	19	)	)	PUNCT
iajs-3313	24	20	(	(	PUNCT
iajs-3313	24	21	n-((6	n-((6	NUM
iajs-3313	24	22	-	-	PUNCT
iajs-3313	24	23	oxo-6,9	oxo-6,9	ADJ
iajs-3313	24	24	-	-	PUNCT
iajs-3313	24	25	dihydro-1h	dihydro-1h	NOUN
iajs-3313	24	26	-	-	PUNCT
iajs-3313	24	27	purin-2	purin-2	NOUN
iajs-3313	24	28	-	-	PUNCT
iajs-3313	24	29	yl)carbamothioyl)propionamide	yl)carbamothioyl)propionamide	NOUN
iajs-3313	24	30	)	)	PUNCT
iajs-3313	24	31	,	,	PUNCT
iajs-3313	24	32	and	and	CCONJ
iajs-3313	24	33	its	its	PRON
iajs-3313	24	34	complexes	complex	NOUN
iajs-3313	24	35	with	with	ADP
iajs-3313	24	36	some	some	DET
iajs-3313	24	37	metal	metal	NOUN
iajs-3313	24	38	ions	ion	NOUN
iajs-3313	24	39	.	.	PUNCT
iajs-3313	25	1	2	2	X
iajs-3313	25	2	.	.	X
iajs-3313	25	3	materials	material	NOUN
iajs-3313	25	4	and	and	CCONJ
iajs-3313	25	5	methods	method	NOUN
iajs-3313	25	6	2.1	2.1	NUM
iajs-3313	25	7	chemicals	chemical	NOUN
iajs-3313	25	8	all	all	DET
iajs-3313	25	9	reagents	reagent	NOUN
iajs-3313	25	10	,	,	PUNCT
iajs-3313	25	11	chemicals	chemical	NOUN
iajs-3313	25	12	,	,	PUNCT
iajs-3313	25	13	metal	metal	NOUN
iajs-3313	25	14	chloride	chloride	NOUN
iajs-3313	25	15	salts	salt	NOUN
iajs-3313	25	16	,	,	PUNCT
iajs-3313	25	17	and	and	CCONJ
iajs-3313	25	18	solvents	solvent	NOUN
iajs-3313	25	19	were	be	AUX
iajs-3313	25	20	purchased	purchase	VERB
iajs-3313	25	21	from	from	ADP
iajs-3313	25	22	merck	merck	PROPN
iajs-3313	25	23	,	,	PUNCT
iajs-3313	25	24	fluorochem	fluorochem	NOUN
iajs-3313	25	25	,	,	PUNCT
iajs-3313	25	26	fluka	fluka	NOUN
iajs-3313	25	27	,	,	PUNCT
iajs-3313	25	28	sigma	sigma	PROPN
iajs-3313	25	29	-	-	PUNCT
iajs-3313	25	30	aldrich	aldrich	PROPN
iajs-3313	25	31	,	,	PUNCT
iajs-3313	25	32	j.t	j.t	PROPN
iajs-3313	25	33	.	.	PROPN
iajs-3313	25	34	baker	baker	PROPN
iajs-3313	25	35	,	,	PUNCT
iajs-3313	25	36	bdh	bdh	NOUN
iajs-3313	25	37	,	,	PUNCT
iajs-3313	25	38	riedel	riedel	NOUN
iajs-3313	25	39	-	-	PUNCT
iajs-3313	25	40	de	de	PROPN
iajs-3313	25	41	haen	haen	PROPN
iajs-3313	25	42	merk	merk	PROPN
iajs-3313	25	43	,	,	PUNCT
iajs-3313	25	44	and	and	CCONJ
iajs-3313	25	45	honeywell	honeywell	VERB
iajs-3313	25	46	with	with	ADP
iajs-3313	25	47	high	high	ADJ
iajs-3313	25	48	purity	purity	NOUN
iajs-3313	25	49	.	.	PUNCT
iajs-3313	26	1	2.2	2.2	NUM
iajs-3313	26	2	synthesis	synthesis	NOUN
iajs-3313	26	3	of	of	ADP
iajs-3313	26	4	the	the	DET
iajs-3313	26	5	ligand	ligand	NOUN
iajs-3313	26	6	(	(	PUNCT
iajs-3313	26	7	opp	opp	PROPN
iajs-3313	26	8	)	)	PUNCT
iajs-3313	26	9	aabout	aabout	PROPN
iajs-3313	26	10	30	30	NUM
iajs-3313	26	11	mmol	mmol	NOUN
iajs-3313	26	12	,	,	PUNCT
iajs-3313	26	13	2.28	2.28	NUM
iajs-3313	26	14	g	g	NOUN
iajs-3313	26	15	of	of	ADP
iajs-3313	26	16	ammonium	ammonium	NOUN
iajs-3313	26	17	thiocyanate	thiocyanate	NOUN
iajs-3313	26	18	was	be	AUX
iajs-3313	26	19	dissolved	dissolve	VERB
iajs-3313	26	20	in	in	ADP
iajs-3313	26	21	20	20	NUM
iajs-3313	26	22	ml	ml	NOUN
iajs-3313	26	23	of	of	ADP
iajs-3313	26	24	acetone	acetone	NOUN
iajs-3313	26	25	with	with	ADP
iajs-3313	26	26	stirring	stirring	NOUN
iajs-3313	26	27	,	,	PUNCT
iajs-3313	26	28	then	then	ADV
iajs-3313	26	29	30	30	NUM
iajs-3313	26	30	mmol	mmol	NOUN
iajs-3313	26	31	,	,	PUNCT
iajs-3313	26	32	2.77	2.77	NUM
iajs-3313	26	33	ml	ml	NOUN
iajs-3313	26	34	of	of	ADP
iajs-3313	26	35	propionyl	propionyl	NOUN
iajs-3313	26	36	chloride	chloride	NOUN
iajs-3313	26	37	was	be	AUX
iajs-3313	26	38	added	add	VERB
iajs-3313	26	39	to	to	ADP
iajs-3313	26	40	the	the	DET
iajs-3313	26	41	solution	solution	NOUN
iajs-3313	26	42	and	and	CCONJ
iajs-3313	26	43	stirred	stir	VERB
iajs-3313	26	44	for	for	ADP
iajs-3313	26	45	about	about	ADV
iajs-3313	26	46	3	3	NUM
iajs-3313	26	47	hours	hour	NOUN
iajs-3313	26	48	,	,	PUNCT
iajs-3313	26	49	then	then	ADV
iajs-3313	26	50	filter	filter	VERB
iajs-3313	26	51	.	.	PUNCT
iajs-3313	27	1	the	the	DET
iajs-3313	27	2	product	product	NOUN
iajs-3313	27	3	was	be	AUX
iajs-3313	27	4	a	a	DET
iajs-3313	27	5	yellow	yellow	ADJ
iajs-3313	27	6	solution	solution	NOUN
iajs-3313	27	7	.	.	PUNCT
iajs-3313	28	1	babout	babout	NOUN
iajs-3313	28	2	30	30	NUM
iajs-3313	28	3	mmol	mmol	NOUN
iajs-3313	28	4	,	,	PUNCT
iajs-3313	28	5	4.53	4.53	NUM
iajs-3313	28	6	g	g	NOUN
iajs-3313	28	7	of	of	ADP
iajs-3313	28	8	guanine	guanine	NOUN
iajs-3313	28	9	was	be	AUX
iajs-3313	28	10	dissolved	dissolve	VERB
iajs-3313	28	11	in	in	ADP
iajs-3313	28	12	20	20	NUM
iajs-3313	28	13	ml	ml	NOUN
iajs-3313	28	14	of	of	ADP
iajs-3313	28	15	acetone	acetone	NOUN
iajs-3313	28	16	,	,	PUNCT
iajs-3313	28	17	then	then	ADV
iajs-3313	28	18	mixed	mix	VERB
iajs-3313	28	19	with	with	ADP
iajs-3313	28	20	the	the	DET
iajs-3313	28	21	former	former	ADJ
iajs-3313	28	22	solution	solution	NOUN
iajs-3313	28	23	above	above	ADV
iajs-3313	28	24	,	,	PUNCT
iajs-3313	28	25	refluxed	refluxe	VERB
iajs-3313	28	26	the	the	DET
iajs-3313	28	27	mixture	mixture	NOUN
iajs-3313	28	28	with	with	ADP
iajs-3313	28	29	a	a	DET
iajs-3313	28	30	water	water	NOUN
iajs-3313	28	31	bath	bath	NOUN
iajs-3313	28	32	for	for	ADP
iajs-3313	28	33	6	6	NUM
iajs-3313	28	34	hours	hour	NOUN
iajs-3313	28	35	,	,	PUNCT
iajs-3313	28	36	let	let	VERB
iajs-3313	28	37	dry	dry	ADJ
iajs-3313	28	38	,	,	PUNCT
iajs-3313	28	39	and	and	CCONJ
iajs-3313	28	40	then	then	ADV
iajs-3313	28	41	recrystallized	recrystallize	VERB
iajs-3313	28	42	with	with	ADP
iajs-3313	28	43	ethanol	ethanol	NOUN
iajs-3313	28	44	[	[	X
iajs-3313	28	45	18,19	18,19	NUM
iajs-3313	28	46	]	]	X
iajs-3313	28	47	,	,	PUNCT
iajs-3313	28	48	as	as	ADP
iajs-3313	28	49	in	in	ADP
iajs-3313	28	50	scheme	scheme	NOUN
iajs-3313	28	51	1	1	NUM
iajs-3313	28	52	.	.	PUNCT
iajs-3313	29	1	scheme1	scheme1	NOUN
iajs-3313	29	2	.	.	PUNCT
iajs-3313	29	3	preparation	preparation	NOUN
iajs-3313	29	4	of	of	ADP
iajs-3313	29	5	ligand	ligand	PROPN
iajs-3313	29	6	(	(	PUNCT
iajs-3313	29	7	opp	opp	PROPN
iajs-3313	29	8	)	)	PUNCT
iajs-3313	29	9	.	.	PUNCT
iajs-3313	30	1	the	the	DET
iajs-3313	30	2	product	product	NOUN
iajs-3313	30	3	was	be	AUX
iajs-3313	30	4	orange	orange	ADJ
iajs-3313	30	5	gummy	gummy	ADJ
iajs-3313	30	6	,	,	PUNCT
iajs-3313	30	7	yield	yield	NOUN
iajs-3313	30	8	(	(	PUNCT
iajs-3313	30	9	63	63	NUM
iajs-3313	30	10	%	%	NOUN
iajs-3313	30	11	)	)	PUNCT
iajs-3313	30	12	,	,	PUNCT
iajs-3313	30	13	m.p	m.p	X
iajs-3313	30	14	(	(	PUNCT
iajs-3313	30	15	134	134	NUM
iajs-3313	30	16	°	°	NOUN
iajs-3313	30	17	c	c	NOUN
iajs-3313	30	18	)	)	PUNCT
iajs-3313	30	19	,	,	PUNCT
iajs-3313	30	20	c%	c%	VERB
iajs-3313	30	21	found	find	VERB
iajs-3313	30	22	(	(	PUNCT
iajs-3313	30	23	40.48	40.48	NUM
iajs-3313	30	24	)	)	PUNCT
iajs-3313	30	25	calc.(40.60	calc.(40.60	PROPN
iajs-3313	30	26	)	)	PUNCT
iajs-3313	30	27	,	,	PUNCT
iajs-3313	30	28	h%	h%	PROPN
iajs-3313	30	29	was	be	AUX
iajs-3313	30	30	found	find	VERB
iajs-3313	30	31	(	(	PUNCT
iajs-3313	30	32	3.47	3.47	X
iajs-3313	30	33	)	)	PUNCT
iajs-3313	30	34	calc.(3.79	calc.(3.79	PROPN
iajs-3313	30	35	)	)	PUNCT
iajs-3313	30	36	,	,	PUNCT
iajs-3313	30	37	n%	n%	PROPN
iajs-3313	30	38	was	be	AUX
iajs-3313	30	39	found	find	VERB
iajs-3313	30	40	(	(	PUNCT
iajs-3313	30	41	31.33	31.33	NUM
iajs-3313	30	42	)	)	PUNCT
iajs-3313	30	43	calc.(31.56	calc.(31.56	NOUN
iajs-3313	30	44	)	)	PUNCT
iajs-3313	30	45	,	,	PUNCT
iajs-3313	30	46	s%	s%	PROPN
iajs-3313	30	47	was	be	AUX
iajs-3313	30	48	found	find	VERB
iajs-3313	30	49	(	(	PUNCT
iajs-3313	30	50	12.39	12.39	NUM
iajs-3313	30	51	)	)	PUNCT
iajs-3313	30	52	calc.(12.04	calc.(12.04	NOUN
iajs-3313	30	53	)	)	PUNCT
iajs-3313	30	54	,	,	PUNCT
iajs-3313	30	55	and	and	CCONJ
iajs-3313	30	56	o%	o%	NOUN
iajs-3313	30	57	was	be	AUX
iajs-3313	30	58	found	find	VERB
iajs-3313	30	59	(	(	PUNCT
iajs-3313	30	60	12.39	12.39	NUM
iajs-3313	30	61	)	)	PUNCT
iajs-3313	30	62	calc.(12.02	calc.(12.02	NOUN
iajs-3313	30	63	)	)	PUNCT
iajs-3313	30	64	.	.	PUNCT
iajs-3313	31	1	ihjpas	ihjpas	PROPN
iajs-3313	31	2	.	.	PUNCT
iajs-3313	32	1	37	37	NUM
iajs-3313	32	2	(	(	PUNCT
iajs-3313	32	3	2	2	NUM
iajs-3313	32	4	)	)	PUNCT
iajs-3313	32	5	2024	2024	NUM
iajs-3313	32	6	287	287	NUM
iajs-3313	32	7	2.3	2.3	NUM
iajs-3313	32	8	synthesis	synthesis	NOUN
iajs-3313	32	9	of	of	ADP
iajs-3313	32	10	metal	metal	NOUN
iajs-3313	32	11	complexes	complex	NOUN
iajs-3313	32	12	aabout	aabout	PROPN
iajs-3313	32	13	2	2	NUM
iajs-3313	32	14	mmol	mmol	NOUN
iajs-3313	32	15	,	,	PUNCT
iajs-3313	32	16	0.532	0.532	NUM
iajs-3313	32	17	g	g	NOUN
iajs-3313	32	18	of	of	ADP
iajs-3313	32	19	the	the	DET
iajs-3313	32	20	guanine	guanine	NOUN
iajs-3313	32	21	derivative	derivative	NOUN
iajs-3313	32	22	was	be	AUX
iajs-3313	32	23	dissolved	dissolve	VERB
iajs-3313	32	24	in	in	ADP
iajs-3313	32	25	10	10	NUM
iajs-3313	32	26	ml	ml	NOUN
iajs-3313	32	27	of	of	ADP
iajs-3313	32	28	ethanol	ethanol	NOUN
iajs-3313	32	29	.	.	PUNCT
iajs-3313	33	1	babout	babout	NOUN
iajs-3313	33	2	1	1	NUM
iajs-3313	33	3	mmol	mmol	NOUN
iajs-3313	33	4	of	of	ADP
iajs-3313	33	5	the	the	DET
iajs-3313	33	6	metal	metal	NOUN
iajs-3313	33	7	salts	salt	NOUN
iajs-3313	33	8	(	(	PUNCT
iajs-3313	33	9	0.197	0.197	NUM
iajs-3313	33	10	g	g	NOUN
iajs-3313	33	11	of	of	ADP
iajs-3313	33	12	mncl2.4h2o	mncl2.4h2o	NOUN
iajs-3313	33	13	,	,	PUNCT
iajs-3313	33	14	0.237	0.237	NUM
iajs-3313	33	15	g	g	NOUN
iajs-3313	33	16	of	of	ADP
iajs-3313	33	17	cocl2.6h2o	cocl2.6h2o	NOUN
iajs-3313	33	18	,	,	PUNCT
iajs-3313	33	19	0.237	0.237	NUM
iajs-3313	33	20	g	g	NOUN
iajs-3313	33	21	of	of	ADP
iajs-3313	33	22	nicl2.6h2o	nicl2.6h2o	NOUN
iajs-3313	33	23	,	,	PUNCT
iajs-3313	33	24	0.170	0.170	NUM
iajs-3313	33	25	g	g	NOUN
iajs-3313	33	26	of	of	ADP
iajs-3313	33	27	cucl2.2h2o	cucl2.2h2o	NOUN
iajs-3313	33	28	,	,	PUNCT
iajs-3313	33	29	0.136	0.136	NUM
iajs-3313	33	30	g	g	NOUN
iajs-3313	33	31	of	of	ADP
iajs-3313	33	32	zncl2	zncl2	PROPN
iajs-3313	33	33	,	,	PUNCT
iajs-3313	33	34	0.201	0.201	NUM
iajs-3313	33	35	g	g	NOUN
iajs-3313	33	36	of	of	ADP
iajs-3313	33	37	cdcl2.h2o	cdcl2.h2o	NOUN
iajs-3313	33	38	,	,	PUNCT
iajs-3313	33	39	and	and	CCONJ
iajs-3313	33	40	0.177	0.177	NUM
iajs-3313	33	41	g	g	NOUN
iajs-3313	33	42	of	of	ADP
iajs-3313	33	43	pdcl2.h2o	pdcl2.h2o	NOUN
iajs-3313	33	44	)	)	PUNCT
iajs-3313	33	45	were	be	AUX
iajs-3313	33	46	dissolved	dissolve	VERB
iajs-3313	33	47	in	in	ADP
iajs-3313	33	48	the	the	DET
iajs-3313	33	49	least	least	ADJ
iajs-3313	33	50	amount	amount	NOUN
iajs-3313	33	51	of	of	ADP
iajs-3313	33	52	ethanol	ethanol	NOUN
iajs-3313	33	53	,	,	PUNCT
iajs-3313	33	54	then	then	ADV
iajs-3313	33	55	this	this	DET
iajs-3313	33	56	solution	solution	NOUN
iajs-3313	33	57	was	be	AUX
iajs-3313	33	58	added	add	VERB
iajs-3313	33	59	to	to	ADP
iajs-3313	33	60	the	the	DET
iajs-3313	33	61	solution	solution	NOUN
iajs-3313	33	62	obtained	obtain	VERB
iajs-3313	33	63	from	from	ADP
iajs-3313	33	64	the	the	DET
iajs-3313	33	65	previous	previous	ADJ
iajs-3313	33	66	step	step	NOUN
iajs-3313	33	67	and	and	CCONJ
iajs-3313	33	68	the	the	DET
iajs-3313	33	69	mixture	mixture	NOUN
iajs-3313	33	70	stirred	stir	VERB
iajs-3313	33	71	for	for	ADP
iajs-3313	33	72	4	4	NUM
iajs-3313	33	73	hours	hour	NOUN
iajs-3313	33	74	to	to	PART
iajs-3313	33	75	form	form	VERB
iajs-3313	33	76	a	a	DET
iajs-3313	33	77	precipitate	precipitate	NOUN
iajs-3313	33	78	that	that	PRON
iajs-3313	33	79	is	be	AUX
iajs-3313	33	80	separated	separate	VERB
iajs-3313	33	81	by	by	ADP
iajs-3313	33	82	filtration	filtration	NOUN
iajs-3313	33	83	,	,	PUNCT
iajs-3313	33	84	washed	wash	VERB
iajs-3313	33	85	with	with	ADP
iajs-3313	33	86	ethanol	ethanol	NOUN
iajs-3313	33	87	,	,	PUNCT
iajs-3313	33	88	and	and	CCONJ
iajs-3313	33	89	leave	leave	VERB
iajs-3313	33	90	to	to	PART
iajs-3313	33	91	dry	dry	VERB
iajs-3313	33	92	[	[	X
iajs-3313	33	93	19,20	19,20	NOUN
iajs-3313	33	94	]	]	PUNCT
iajs-3313	33	95	.	.	PUNCT
iajs-3313	34	1	table	table	NOUN
iajs-3313	34	2	1	1	NUM
iajs-3313	34	3	shows	show	VERB
iajs-3313	34	4	some	some	DET
iajs-3313	34	5	physical	physical	ADJ
iajs-3313	34	6	properties	property	NOUN
iajs-3313	34	7	of	of	ADP
iajs-3313	34	8	the	the	DET
iajs-3313	34	9	prepared	prepared	ADJ
iajs-3313	34	10	complexes	complex	NOUN
iajs-3313	34	11	.	.	PUNCT
iajs-3313	35	1	3	3	X
iajs-3313	35	2	.	.	NOUN
iajs-3313	35	3	results	result	NOUN
iajs-3313	35	4	and	and	CCONJ
iajs-3313	35	5	discussion	discussion	VERB
iajs-3313	35	6	the	the	DET
iajs-3313	35	7	solid	solid	ADJ
iajs-3313	35	8	complexes	complex	NOUN
iajs-3313	35	9	that	that	PRON
iajs-3313	35	10	were	be	AUX
iajs-3313	35	11	synthesized	synthesize	VERB
iajs-3313	35	12	displayed	display	VERB
iajs-3313	35	13	solubility	solubility	NOUN
iajs-3313	35	14	in	in	ADP
iajs-3313	35	15	certain	certain	ADJ
iajs-3313	35	16	typical	typical	ADJ
iajs-3313	35	17	solvents	solvent	NOUN
iajs-3313	35	18	,	,	PUNCT
iajs-3313	35	19	including	include	VERB
iajs-3313	35	20	dimethyl	dimethyl	NOUN
iajs-3313	35	21	formamide	formamide	ADV
iajs-3313	35	22	and	and	CCONJ
iajs-3313	35	23	dimethyl	dimethyl	NOUN
iajs-3313	35	24	sulphoxide	sulphoxide	NOUN
iajs-3313	35	25	,	,	PUNCT
iajs-3313	35	26	and	and	CCONJ
iajs-3313	35	27	exhibited	exhibit	VERB
iajs-3313	35	28	considerable	considerable	ADJ
iajs-3313	35	29	thermal	thermal	ADJ
iajs-3313	35	30	stability	stability	NOUN
iajs-3313	35	31	.	.	PUNCT
iajs-3313	36	1	when	when	SCONJ
iajs-3313	36	2	dissolved	dissolve	VERB
iajs-3313	36	3	in	in	ADP
iajs-3313	36	4	dmso	dmso	NOUN
iajs-3313	36	5	,	,	PUNCT
iajs-3313	36	6	all	all	DET
iajs-3313	36	7	complexes	complex	NOUN
iajs-3313	36	8	demonstrated	demonstrate	VERB
iajs-3313	36	9	non	non	ADJ
iajs-3313	36	10	-	-	ADJ
iajs-3313	36	11	electrolytic	electrolytic	ADJ
iajs-3313	36	12	behavior	behavior	NOUN
iajs-3313	36	13	,	,	PUNCT
iajs-3313	36	14	as	as	SCONJ
iajs-3313	36	15	evidenced	evidence	VERB
iajs-3313	36	16	by	by	ADP
iajs-3313	36	17	their	their	PRON
iajs-3313	36	18	molar	molar	ADJ
iajs-3313	36	19	conductivity	conductivity	NOUN
iajs-3313	36	20	.	.	PUNCT
iajs-3313	37	1	table	table	NOUN
iajs-3313	37	2	1	1	NUM
iajs-3313	37	3	shows	show	VERB
iajs-3313	37	4	the	the	DET
iajs-3313	37	5	percentage	percentage	NOUN
iajs-3313	37	6	of	of	ADP
iajs-3313	37	7	physical	physical	ADJ
iajs-3313	37	8	properties	property	NOUN
iajs-3313	37	9	and	and	CCONJ
iajs-3313	37	10	metals	metal	NOUN
iajs-3313	37	11	in	in	ADP
iajs-3313	37	12	complexes	complex	NOUN
iajs-3313	37	13	and	and	CCONJ
iajs-3313	37	14	the	the	DET
iajs-3313	37	15	molar	molar	ADJ
iajs-3313	37	16	conductivity	conductivity	NOUN
iajs-3313	37	17	of	of	ADP
iajs-3313	37	18	the	the	DET
iajs-3313	37	19	ligand	ligand	NOUN
iajs-3313	37	20	and	and	CCONJ
iajs-3313	37	21	its	its	PRON
iajs-3313	37	22	metallic	metallic	ADJ
iajs-3313	37	23	complexes	complex	NOUN
iajs-3313	37	24	.	.	PUNCT
iajs-3313	38	1	table	table	NOUN
iajs-3313	38	2	1	1	NUM
iajs-3313	38	3	.	.	PUNCT
iajs-3313	39	1	the	the	DET
iajs-3313	39	2	physical	physical	ADJ
iajs-3313	39	3	properties	property	NOUN
iajs-3313	39	4	of	of	ADP
iajs-3313	39	5	the	the	DET
iajs-3313	39	6	ligand	ligand	NOUN
iajs-3313	39	7	and	and	CCONJ
iajs-3313	39	8	its	its	PRON
iajs-3313	39	9	metallic	metallic	ADJ
iajs-3313	39	10	complexes	complex	NOUN
iajs-3313	39	11	.	.	PUNCT
iajs-3313	40	1	compound	compound	NOUN
iajs-3313	40	2	color	color	NOUN
iajs-3313	40	3	m.wt	m.wt	PROPN
iajs-3313	40	4	(	(	PUNCT
iajs-3313	40	5	g	g	NOUN
iajs-3313	40	6	/	/	SYM
iajs-3313	40	7	mol	mol	NOUN
iajs-3313	40	8	)	)	PUNCT
iajs-3313	40	9	m.p.(dec	m.p.(dec	PROPN
iajs-3313	40	10	.	.	PUNCT
iajs-3313	40	11	)	)	PUNCT
iajs-3313	41	1	°	°	ADP
iajs-3313	41	2	c	c	PROPN
iajs-3313	41	3	m%	m%	PROPN
iajs-3313	41	4	calculation	calculation	NOUN
iajs-3313	41	5	(	(	PUNCT
iajs-3313	41	6	found	find	VERB
iajs-3313	41	7	)	)	PUNCT
iajs-3313	41	8	molar	molar	ADJ
iajs-3313	41	9	condu	condu	NOUN
iajs-3313	41	10	.	.	PUNCT
iajs-3313	42	1	ohm	ohm	PROPN
iajs-3313	42	2	-1	-1	PUNCT
iajs-3313	42	3	cm	cm	PROPN
iajs-3313	42	4	2	2	NUM
iajs-3313	42	5	mol	mol	ADP
iajs-3313	42	6	-1	-1	PUNCT
iajs-3313	42	7	(	(	PUNCT
iajs-3313	42	8	opp	opp	PROPN
iajs-3313	42	9	)	)	PUNCT
iajs-3313	42	10	orange	orange	PROPN
iajs-3313	43	1	266.28	266.28	NUM
iajs-3313	43	2	134	134	NUM
iajs-3313	43	3	-	-	PUNCT
iajs-3313	43	4	(	(	PUNCT
iajs-3313	43	5	--	--	PUNCT
iajs-3313	43	6	)	)	PUNCT
iajs-3313	43	7	--	--	PUNCT
iajs-3313	44	1	[	[	X
iajs-3313	44	2	mncl2(opp)2	mncl2(opp)2	X
iajs-3313	44	3	]	]	X
iajs-3313	44	4	yellow	yellow	NOUN
iajs-3313	44	5	658.40	658.40	NUM
iajs-3313	44	6	142	142	NUM
iajs-3313	44	7	8.34	8.34	NUM
iajs-3313	44	8	(	(	PUNCT
iajs-3313	44	9	8.58	8.58	NUM
iajs-3313	44	10	)	)	PUNCT
iajs-3313	44	11	14	14	NUM
iajs-3313	45	1	[	[	X
iajs-3313	45	2	cocl2(opp)2	cocl2(opp)2	X
iajs-3313	45	3	]	]	X
iajs-3313	45	4	blue	blue	NOUN
iajs-3313	45	5	662.39	662.39	NUM
iajs-3313	45	6	164	164	NUM
iajs-3313	45	7	9.80	9.80	NUM
iajs-3313	45	8	(	(	PUNCT
iajs-3313	45	9	9.72	9.72	NUM
iajs-3313	45	10	)	)	PUNCT
iajs-3313	45	11	12	12	NUM
iajs-3313	46	1	[	[	X
iajs-3313	46	2	nicl2(opp)2	nicl2(opp)2	NOUN
iajs-3313	46	3	]	]	X
iajs-3313	46	4	green	green	NOUN
iajs-3313	46	5	662.15	662.15	NUM
iajs-3313	46	6	168	168	NUM
iajs-3313	46	7	8.86	8.86	NUM
iajs-3313	46	8	(	(	PUNCT
iajs-3313	46	9	9.01	9.01	NUM
iajs-3313	46	10	)	)	PUNCT
iajs-3313	46	11	18	18	NUM
iajs-3313	47	1	[	[	X
iajs-3313	47	2	cucl2(opp)2	cucl2(opp)2	NOUN
iajs-3313	47	3	]	]	X
iajs-3313	47	4	blue	blue	NOUN
iajs-3313	47	5	667.00	667.00	NUM
iajs-3313	47	6	--	--	PUNCT
iajs-3313	47	7	(	(	PUNCT
iajs-3313	47	8	182	182	NUM
iajs-3313	47	9	)	)	PUNCT
iajs-3313	47	10	9.53	9.53	NUM
iajs-3313	47	11	(	(	PUNCT
iajs-3313	47	12	9.77	9.77	NUM
iajs-3313	47	13	)	)	PUNCT
iajs-3313	47	14	12	12	NUM
iajs-3313	48	1	[	[	X
iajs-3313	48	2	zncl2(opp)2	zncl2(opp)2	X
iajs-3313	48	3	]	]	X
iajs-3313	48	4	white	white	X
iajs-3313	48	5	688.84	688.84	NUM
iajs-3313	48	6	--	--	PUNCT
iajs-3313	48	7	(	(	PUNCT
iajs-3313	48	8	168	168	NUM
iajs-3313	48	9	)	)	PUNCT
iajs-3313	48	10	9.78	9.78	NUM
iajs-3313	48	11	(	(	PUNCT
iajs-3313	48	12	9.72	9.72	NUM
iajs-3313	48	13	)	)	PUNCT
iajs-3313	48	14	10	10	NUM
iajs-3313	49	1	[	[	X
iajs-3313	49	2	cdcl2(opp)2	cdcl2(opp)2	X
iajs-3313	49	3	]	]	X
iajs-3313	49	4	white	white	ADJ
iajs-3313	49	5	715.87	715.87	NUM
iajs-3313	49	6	--	--	PUNCT
iajs-3313	49	7	(	(	PUNCT
iajs-3313	49	8	192	192	NUM
iajs-3313	49	9	)	)	PUNCT
iajs-3313	49	10	15.70	15.70	NUM
iajs-3313	49	11	(	(	PUNCT
iajs-3313	49	12	15.83	15.83	NUM
iajs-3313	49	13	)	)	PUNCT
iajs-3313	49	14	8	8	NUM
iajs-3313	50	1	[	[	X
iajs-3313	50	2	pdcl2(opp)2	pdcl2(opp)2	NOUN
iajs-3313	50	3	]	]	X
iajs-3313	50	4	brown	brown	NOUN
iajs-3313	50	5	709.88	709.88	NUM
iajs-3313	50	6	--	--	PUNCT
iajs-3313	50	7	(	(	PUNCT
iajs-3313	50	8	188	188	NUM
iajs-3313	50	9	)	)	PUNCT
iajs-3313	50	10	14.99	14.99	NUM
iajs-3313	50	11	(	(	PUNCT
iajs-3313	50	12	15.08	15.08	NUM
iajs-3313	50	13	)	)	PUNCT
iajs-3313	50	14	2	2	NUM
iajs-3313	50	15	the	the	DET
iajs-3313	50	16	ft	ft	PROPN
iajs-3313	50	17	-	-	PUNCT
iajs-3313	50	18	ir	ir	NOUN
iajs-3313	50	19	spectrum	spectrum	NOUN
iajs-3313	50	20	for	for	ADP
iajs-3313	50	21	free	free	ADJ
iajs-3313	50	22	ligand	ligand	NOUN
iajs-3313	50	23	opp	opp	PROPN
iajs-3313	50	24	in	in	ADP
iajs-3313	50	25	figure	figure	NOUN
iajs-3313	50	26	1	1	NUM
iajs-3313	50	27	,	,	PUNCT
iajs-3313	50	28	detected	detect	VERB
iajs-3313	50	29	a	a	DET
iajs-3313	50	30	medium	medium	ADJ
iajs-3313	50	31	band	band	NOUN
iajs-3313	50	32	at	at	ADP
iajs-3313	50	33	(	(	PUNCT
iajs-3313	50	34	3160	3160	NUM
iajs-3313	50	35	cm	cm	NOUN
iajs-3313	50	36	-1	-1	PUNCT
iajs-3313	50	37	)	)	PUNCT
iajs-3313	50	38	for	for	ADP
iajs-3313	50	39	υ(nh	υ(nh	NOUN
iajs-3313	50	40	)	)	PUNCT
iajs-3313	50	41	,	,	PUNCT
iajs-3313	50	42	medium	medium	ADJ
iajs-3313	50	43	band	band	NOUN
iajs-3313	50	44	at	at	ADP
iajs-3313	50	45	(	(	PUNCT
iajs-3313	50	46	1604	1604	NUM
iajs-3313	50	47	cm	cm	NOUN
iajs-3313	50	48	-1	-1	PUNCT
iajs-3313	50	49	)	)	PUNCT
iajs-3313	50	50	for	for	ADP
iajs-3313	50	51	υ(c	υ(c	PROPN
iajs-3313	50	52	=	=	PROPN
iajs-3313	50	53	o	o	X
iajs-3313	50	54	amidic	amidic	NOUN
iajs-3313	50	55	)	)	PUNCT
iajs-3313	50	56	and	and	CCONJ
iajs-3313	50	57	another	another	DET
iajs-3313	50	58	bands	band	NOUN
iajs-3313	50	59	at	at	ADP
iajs-3313	50	60	(	(	PUNCT
iajs-3313	50	61	1226	1226	NUM
iajs-3313	50	62	cm	cm	NOUN
iajs-3313	50	63	-1	-1	PUNCT
iajs-3313	50	64	)	)	PUNCT
iajs-3313	50	65	for	for	ADP
iajs-3313	50	66	υ(c	υ(c	PROPN
iajs-3313	50	67	=	=	SYM
iajs-3313	50	68	s	s	PART
iajs-3313	50	69	)	)	PUNCT
iajs-3313	50	70	and	and	CCONJ
iajs-3313	50	71	a	a	DET
iajs-3313	50	72	strong	strong	ADJ
iajs-3313	50	73	band	band	NOUN
iajs-3313	50	74	at	at	ADP
iajs-3313	50	75	(	(	PUNCT
iajs-3313	50	76	1695	1695	NUM
iajs-3313	50	77	cm	cm	NOUN
iajs-3313	50	78	-1	-1	PUNCT
iajs-3313	50	79	)	)	PUNCT
iajs-3313	50	80	for	for	ADP
iajs-3313	50	81	υ(c	υ(c	PROPN
iajs-3313	50	82	=	=	NOUN
iajs-3313	50	83	o	o	NOUN
iajs-3313	50	84	)	)	PUNCT
iajs-3313	50	85	of	of	ADP
iajs-3313	50	86	the	the	DET
iajs-3313	50	87	guanine	guanine	NOUN
iajs-3313	50	88	ring	ring	NOUN
iajs-3313	51	1	[	[	X
iajs-3313	51	2	22	22	NUM
iajs-3313	51	3	]	]	PUNCT
iajs-3313	51	4	,	,	PUNCT
iajs-3313	51	5	table	table	NOUN
iajs-3313	51	6	2	2	NUM
iajs-3313	51	7	and	and	CCONJ
iajs-3313	51	8	figure	figure	VERB
iajs-3313	51	9	1	1	NUM
iajs-3313	51	10	.	.	PUNCT
iajs-3313	51	11	table	table	NOUN
iajs-3313	51	12	2	2	NUM
iajs-3313	51	13	.	.	PUNCT
iajs-3313	52	1	the	the	DET
iajs-3313	52	2	ft	ft	PROPN
iajs-3313	52	3	-	-	PUNCT
iajs-3313	52	4	ir	ir	NOUN
iajs-3313	52	5	bands	band	NOUN
iajs-3313	52	6	for	for	ADP
iajs-3313	52	7	guanine	guanine	NOUN
iajs-3313	52	8	and	and	CCONJ
iajs-3313	52	9	free	free	ADJ
iajs-3313	52	10	ligand	ligand	NOUN
iajs-3313	52	11	opp	opp	PROPN
iajs-3313	52	12	.	.	PUNCT
iajs-3313	53	1	compound	compound	PROPN
iajs-3313	53	2	ν(n	ν(n	PROPN
iajs-3313	53	3	-	-	PUNCT
iajs-3313	53	4	h2+oh	h2+oh	NOUN
iajs-3313	53	5	)	)	PUNCT
iajs-3313	53	6	ν(n	ν(n	PROPN
iajs-3313	53	7	-	-	PUNCT
iajs-3313	53	8	h+oh	h+oh	NOUN
iajs-3313	53	9	)	)	PUNCT
iajs-3313	53	10	ν(c	ν(c	PROPN
iajs-3313	53	11	=	=	SYM
iajs-3313	53	12	o	o	NOUN
iajs-3313	53	13	)	)	PUNCT
iajs-3313	53	14	amide	amide	NOUN
iajs-3313	53	15	ν(c	ν(c	PROPN
iajs-3313	53	16	=	=	SYM
iajs-3313	53	17	s	s	PART
iajs-3313	53	18	)	)	PUNCT
iajs-3313	53	19	ν(c	ν(c	PROPN
iajs-3313	53	20	=	=	SYM
iajs-3313	53	21	o	o	NOUN
iajs-3313	53	22	)	)	PUNCT
iajs-3313	53	23	in	in	ADP
iajs-3313	53	24	purin	purin	NOUN
iajs-3313	53	25	ring	ring	NOUN
iajs-3313	53	26	guanine	guanine	NOUN
iajs-3313	53	27	3321(m	3321(m	NUM
iajs-3313	53	28	)	)	PUNCT
iajs-3313	53	29	3116(m	3116(m	NOUN
iajs-3313	53	30	)	)	PUNCT
iajs-3313	53	31	----1693(s	----1693(s	PROPN
iajs-3313	53	32	)	)	PUNCT
iajs-3313	53	33	opp	opp	PROPN
iajs-3313	53	34	----3160(m	----3160(m	NOUN
iajs-3313	53	35	)	)	PUNCT
iajs-3313	53	36	1604(s	1604(s	NUM
iajs-3313	53	37	)	)	PUNCT
iajs-3313	53	38	1226(s	1226(s	NUM
iajs-3313	53	39	)	)	PUNCT
iajs-3313	53	40	1695(s	1695(s	NUM
iajs-3313	53	41	)	)	PUNCT
iajs-3313	53	42	ihjpas	ihjpas	PROPN
iajs-3313	53	43	.	.	PUNCT
iajs-3313	54	1	37	37	NUM
iajs-3313	54	2	(	(	PUNCT
iajs-3313	54	3	2	2	NUM
iajs-3313	54	4	)	)	PUNCT
iajs-3313	54	5	2024	2024	NUM
iajs-3313	54	6	288	288	NUM
iajs-3313	54	7	figure	figure	NOUN
iajs-3313	54	8	1	1	NUM
iajs-3313	54	9	.	.	PUNCT
iajs-3313	55	1	the	the	DET
iajs-3313	55	2	ft	ft	PROPN
iajs-3313	55	3	-	-	PUNCT
iajs-3313	55	4	ir	ir	NOUN
iajs-3313	55	5	spectrum	spectrum	NOUN
iajs-3313	55	6	of	of	ADP
iajs-3313	55	7	ligand	ligand	PROPN
iajs-3313	55	8	(	(	PUNCT
iajs-3313	55	9	opp	opp	PROPN
iajs-3313	55	10	)	)	PUNCT
iajs-3313	55	11	.	.	PUNCT
iajs-3313	56	1	the	the	DET
iajs-3313	56	2	1	1	NUM
iajs-3313	56	3	h	h	NUM
iajs-3313	56	4	-	-	PUNCT
iajs-3313	56	5	nmr	nmr	NOUN
iajs-3313	56	6	spectrum	spectrum	NOUN
iajs-3313	56	7	of	of	ADP
iajs-3313	56	8	ligand	ligand	PROPN
iajs-3313	56	9	(	(	PUNCT
iajs-3313	56	10	opp	opp	PROPN
iajs-3313	56	11	)	)	PUNCT
iajs-3313	56	12	in	in	ADP
iajs-3313	56	13	dmso	dmso	NOUN
iajs-3313	56	14	-	-	ADJ
iajs-3313	56	15	d6	d6	NOUN
iajs-3313	56	16	in	in	ADP
iajs-3313	56	17	figure	figure	NOUN
iajs-3313	56	18	3	3	NUM
iajs-3313	56	19	showed	show	VERB
iajs-3313	56	20	a	a	DET
iajs-3313	56	21	doublet	doublet	ADJ
iajs-3313	56	22	signal	signal	NOUN
iajs-3313	56	23	at	at	ADP
iajs-3313	56	24	δ(1.03	δ(1.03	PROPN
iajs-3313	56	25	)	)	PUNCT
iajs-3313	56	26	ppm	ppm	NOUN
iajs-3313	56	27	for	for	ADP
iajs-3313	56	28	(	(	PUNCT
iajs-3313	56	29	3h	3h	NUM
iajs-3313	56	30	,	,	PUNCT
iajs-3313	56	31	of	of	ADP
iajs-3313	56	32	ch3	ch3	PROPN
iajs-3313	56	33	methyl	methyl	PROPN
iajs-3313	56	34	)	)	PUNCT
iajs-3313	56	35	,	,	PUNCT
iajs-3313	56	36	a	a	DET
iajs-3313	56	37	pentet	pentet	NOUN
iajs-3313	56	38	signal	signal	NOUN
iajs-3313	56	39	at	at	ADP
iajs-3313	56	40	δ(2.145	δ(2.145	NOUN
iajs-3313	56	41	)	)	PUNCT
iajs-3313	56	42	ppm	ppm	NOUN
iajs-3313	56	43	for	for	ADP
iajs-3313	56	44	two	two	NUM
iajs-3313	56	45	protons	proton	NOUN
iajs-3313	56	46	in	in	ADP
iajs-3313	56	47	(	(	PUNCT
iajs-3313	56	48	ch2	ch2	PROPN
iajs-3313	56	49	,	,	PUNCT
iajs-3313	56	50	methylene	methylene	NOUN
iajs-3313	56	51	)	)	PUNCT
iajs-3313	56	52	,	,	PUNCT
iajs-3313	56	53	a	a	DET
iajs-3313	56	54	single	single	ADJ
iajs-3313	56	55	signal	signal	NOUN
iajs-3313	56	56	at	at	ADP
iajs-3313	56	57	δ(2.51	δ(2.51	PROPN
iajs-3313	56	58	)	)	PUNCT
iajs-3313	56	59	ppm	ppm	VERB
iajs-3313	56	60	for	for	ADP
iajs-3313	56	61	(	(	PUNCT
iajs-3313	56	62	dmso	dmso	NOUN
iajs-3313	56	63	)	)	PUNCT
iajs-3313	56	64	,	,	PUNCT
iajs-3313	56	65	a	a	DET
iajs-3313	56	66	single	single	ADJ
iajs-3313	56	67	signal	signal	NOUN
iajs-3313	56	68	at	at	ADP
iajs-3313	56	69	δ(7.02	δ(7.02	NOUN
iajs-3313	56	70	)	)	PUNCT
iajs-3313	56	71	ppm	ppm	NOUN
iajs-3313	56	72	for	for	ADP
iajs-3313	56	73	one	one	NUM
iajs-3313	56	74	proton	proton	NOUN
iajs-3313	56	75	of	of	ADP
iajs-3313	56	76	(	(	PUNCT
iajs-3313	56	77	n	n	CCONJ
iajs-3313	56	78	-	-	PUNCT
iajs-3313	56	79	h	h	NOUN
iajs-3313	56	80	imidazole	imidazole	NOUN
iajs-3313	56	81	ring	ring	NOUN
iajs-3313	56	82	)	)	PUNCT
iajs-3313	56	83	,	,	PUNCT
iajs-3313	56	84	a	a	DET
iajs-3313	56	85	single	single	ADJ
iajs-3313	56	86	signal	signal	NOUN
iajs-3313	56	87	at	at	ADP
iajs-3313	56	88	δ(7.28	δ(7.28	NOUN
iajs-3313	56	89	)	)	PUNCT
iajs-3313	56	90	ppm	ppm	NOUN
iajs-3313	56	91	for	for	ADP
iajs-3313	56	92	one	one	NUM
iajs-3313	56	93	proton	proton	NOUN
iajs-3313	56	94	(	(	PUNCT
iajs-3313	56	95	c	c	NOUN
iajs-3313	56	96	-	-	PUNCT
iajs-3313	56	97	h	h	NOUN
iajs-3313	56	98	in	in	ADP
iajs-3313	56	99	imidazole	imidazole	NOUN
iajs-3313	56	100	ring	ring	NOUN
iajs-3313	56	101	)	)	PUNCT
iajs-3313	56	102	,	,	PUNCT
iajs-3313	56	103	a	a	DET
iajs-3313	56	104	single	single	ADJ
iajs-3313	56	105	signal	signal	NOUN
iajs-3313	56	106	at	at	ADP
iajs-3313	56	107	δ(9.34	δ(9.34	NOUN
iajs-3313	56	108	)	)	PUNCT
iajs-3313	56	109	ppm	ppm	NOUN
iajs-3313	56	110	for	for	ADP
iajs-3313	56	111	one	one	NUM
iajs-3313	56	112	proton	proton	NOUN
iajs-3313	56	113	of	of	ADP
iajs-3313	56	114	(	(	PUNCT
iajs-3313	56	115	nh	nh	PROPN
iajs-3313	56	116	,	,	PUNCT
iajs-3313	56	117	amine	amine	NOUN
iajs-3313	56	118	)	)	PUNCT
iajs-3313	56	119	,	,	PUNCT
iajs-3313	56	120	a	a	DET
iajs-3313	56	121	single	single	ADJ
iajs-3313	56	122	signal	signal	NOUN
iajs-3313	56	123	at	at	ADP
iajs-3313	56	124	δ(9.64	δ(9.64	PROPN
iajs-3313	56	125	)	)	PUNCT
iajs-3313	56	126	ppm	ppm	NOUN
iajs-3313	56	127	for	for	ADP
iajs-3313	56	128	one	one	NUM
iajs-3313	56	129	proton	proton	NOUN
iajs-3313	56	130	in	in	ADP
iajs-3313	56	131	(	(	PUNCT
iajs-3313	56	132	nh	nh	NOUN
iajs-3313	56	133	,	,	PUNCT
iajs-3313	56	134	amide	amide	NOUN
iajs-3313	56	135	)	)	PUNCT
iajs-3313	56	136	.	.	PUNCT
iajs-3313	57	1	also	also	ADV
iajs-3313	57	2	,	,	PUNCT
iajs-3313	57	3	a	a	DET
iajs-3313	57	4	single	single	ADJ
iajs-3313	57	5	signal	signal	NOUN
iajs-3313	57	6	at	at	ADP
iajs-3313	57	7	δ(11.048	δ(11.048	NOUN
iajs-3313	57	8	)	)	PUNCT
iajs-3313	57	9	ppm	ppm	NOUN
iajs-3313	57	10	for	for	ADP
iajs-3313	57	11	one	one	NUM
iajs-3313	57	12	proton	proton	NOUN
iajs-3313	57	13	in	in	ADP
iajs-3313	57	14	(	(	PUNCT
iajs-3313	57	15	nh	nh	PROPN
iajs-3313	57	16	,	,	PUNCT
iajs-3313	57	17	guanidine	guanidine	NOUN
iajs-3313	57	18	)	)	PUNCT
iajs-3313	58	1	[	[	X
iajs-3313	58	2	22	22	NUM
iajs-3313	58	3	]	]	PUNCT
iajs-3313	58	4	,	,	PUNCT
iajs-3313	58	5	table	table	NOUN
iajs-3313	58	6	2	2	NUM
iajs-3313	58	7	.	.	PUNCT
iajs-3313	58	8	figure	figure	NOUN
iajs-3313	58	9	2	2	NUM
iajs-3313	58	10	.	.	PUNCT
iajs-3313	59	1	the	the	DET
iajs-3313	59	2	1	1	NUM
iajs-3313	59	3	h	h	NOUN
iajs-3313	59	4	-	-	PUNCT
iajs-3313	59	5	nmr	nmr	NOUN
iajs-3313	59	6	spectrum	spectrum	NOUN
iajs-3313	59	7	of	of	ADP
iajs-3313	59	8	ligand	ligand	NOUN
iajs-3313	59	9	(	(	PUNCT
iajs-3313	59	10	opp	opp	PROPN
iajs-3313	59	11	)	)	PUNCT
iajs-3313	59	12	.	.	PUNCT
iajs-3313	60	1	table	table	NOUN
iajs-3313	60	2	3	3	NUM
iajs-3313	60	3	.	.	PUNCT
iajs-3313	61	1	the	the	DET
iajs-3313	61	2	1	1	NUM
iajs-3313	61	3	hnmr	hnmr	NOUN
iajs-3313	61	4	signals	signal	NOUN
iajs-3313	61	5	for	for	ADP
iajs-3313	61	6	ligand	ligand	NOUN
iajs-3313	61	7	(	(	PUNCT
iajs-3313	61	8	opp	opp	PROPN
iajs-3313	61	9	)	)	PUNCT
iajs-3313	61	10	.	.	PUNCT
iajs-3313	62	1	symbol	symbol	NOUN
iajs-3313	62	2	δppm	δppm	PROPN
iajs-3313	62	3	signal	signal	PROPN
iajs-3313	62	4	no.of	no.of	PROPN
iajs-3313	62	5	point	point	NOUN
iajs-3313	62	6	group	group	NOUN
iajs-3313	62	7	a	a	DET
iajs-3313	62	8	1.03	1.03	NUM
iajs-3313	62	9	doublet	doublet	NOUN
iajs-3313	62	10	3h	3h	NUM
iajs-3313	62	11	ch3	ch3	PROPN
iajs-3313	62	12	,	,	PUNCT
iajs-3313	62	13	methyl	methyl	PROPN
iajs-3313	62	14	b	b	PROPN
iajs-3313	62	15	2.145	2.145	NUM
iajs-3313	62	16	pentlet	pentlet	ADJ
iajs-3313	62	17	2h	2h	NUM
iajs-3313	62	18	ch2	ch2	PROPN
iajs-3313	62	19	,	,	PUNCT
iajs-3313	62	20	methylene	methylene	NOUN
iajs-3313	62	21	c	c	PROPN
iajs-3313	62	22	7.02	7.02	NUM
iajs-3313	62	23	singlet	singlet	NOUN
iajs-3313	62	24	1h	1h	NUM
iajs-3313	62	25	n	n	CCONJ
iajs-3313	62	26	-	-	PUNCT
iajs-3313	62	27	h	h	NOUN
iajs-3313	62	28	,	,	PUNCT
iajs-3313	62	29	imidazole	imidazole	NOUN
iajs-3313	62	30	ring	ring	NOUN
iajs-3313	62	31	d	d	PROPN
iajs-3313	62	32	7.28	7.28	NUM
iajs-3313	62	33	singlet	singlet	NOUN
iajs-3313	62	34	1h	1h	NUM
iajs-3313	62	35	c	c	NOUN
iajs-3313	62	36	-	-	PUNCT
iajs-3313	62	37	h	h	NOUN
iajs-3313	62	38	,	,	PUNCT
iajs-3313	62	39	imidazole	imidazole	NOUN
iajs-3313	62	40	ring	ring	NOUN
iajs-3313	62	41	e	e	PROPN
iajs-3313	62	42	9.34	9.34	NUM
iajs-3313	62	43	singlet	singlet	NOUN
iajs-3313	62	44	1h	1h	NUM
iajs-3313	62	45	n	n	CCONJ
iajs-3313	62	46	-	-	PUNCT
iajs-3313	62	47	h	h	NOUN
iajs-3313	62	48	,	,	PUNCT
iajs-3313	62	49	amine	amine	ADJ
iajs-3313	62	50	f	f	NOUN
iajs-3313	62	51	9.64	9.64	NUM
iajs-3313	62	52	singlet	singlet	NOUN
iajs-3313	62	53	1h	1h	NUM
iajs-3313	62	54	n	n	CCONJ
iajs-3313	62	55	-	-	PUNCT
iajs-3313	62	56	h	h	NOUN
iajs-3313	62	57	,	,	PUNCT
iajs-3313	62	58	amide	amide	NOUN
iajs-3313	62	59	g	g	ADP
iajs-3313	62	60	11.04	11.04	NUM
iajs-3313	62	61	singlet	singlet	NOUN
iajs-3313	62	62	1h	1h	NUM
iajs-3313	62	63	n	n	CCONJ
iajs-3313	62	64	-	-	PUNCT
iajs-3313	62	65	h	h	NOUN
iajs-3313	62	66	,	,	PUNCT
iajs-3313	62	67	guanidine	guanidine	NOUN
iajs-3313	62	68	ihjpas	ihjpa	NOUN
iajs-3313	62	69	.	.	PUNCT
iajs-3313	63	1	37	37	NUM
iajs-3313	63	2	(	(	PUNCT
iajs-3313	63	3	2	2	NUM
iajs-3313	63	4	)	)	PUNCT
iajs-3313	63	5	2024	2024	NUM
iajs-3313	63	6	289	289	NUM
iajs-3313	63	7	while	while	SCONJ
iajs-3313	63	8	the	the	DET
iajs-3313	63	9	13	13	NUM
iajs-3313	63	10	c	c	NOUN
iajs-3313	63	11	-	-	PUNCT
iajs-3313	63	12	nmr	nmr	NOUN
iajs-3313	63	13	spectrum	spectrum	NOUN
iajs-3313	63	14	of	of	ADP
iajs-3313	63	15	ligand	ligand	NOUN
iajs-3313	63	16	opp	opp	PROPN
iajs-3313	63	17	in	in	ADP
iajs-3313	63	18	figure	figure	NOUN
iajs-3313	63	19	4	4	NUM
iajs-3313	63	20	,	,	PUNCT
iajs-3313	63	21	dmso	dmso	NOUN
iajs-3313	63	22	-	-	PUNCT
iajs-3313	63	23	d6	d6	NOUN
iajs-3313	63	24	showed	show	VERB
iajs-3313	63	25	a	a	DET
iajs-3313	63	26	single	single	ADJ
iajs-3313	63	27	signal	signal	NOUN
iajs-3313	63	28	at	at	ADP
iajs-3313	63	29	δ(10.23	δ(10.23	PROPN
iajs-3313	63	30	)	)	PUNCT
iajs-3313	63	31	ppm	ppm	VERB
iajs-3313	63	32	for	for	ADP
iajs-3313	63	33	(	(	PUNCT
iajs-3313	63	34	ch3	ch3	PROPN
iajs-3313	63	35	,	,	PUNCT
iajs-3313	63	36	methyl	methyl	NOUN
iajs-3313	63	37	)	)	PUNCT
iajs-3313	63	38	,	,	PUNCT
iajs-3313	63	39	a	a	DET
iajs-3313	63	40	single	single	ADJ
iajs-3313	63	41	signal	signal	NOUN
iajs-3313	63	42	at	at	ADP
iajs-3313	63	43	δ(30.02	δ(30.02	NOUN
iajs-3313	63	44	)	)	PUNCT
iajs-3313	63	45	ppm	ppm	NOUN
iajs-3313	63	46	for	for	ADP
iajs-3313	63	47	(	(	PUNCT
iajs-3313	63	48	ch2	ch2	PROPN
iajs-3313	63	49	methylene	methylene	NOUN
iajs-3313	63	50	)	)	PUNCT
iajs-3313	63	51	,	,	PUNCT
iajs-3313	63	52	a	a	DET
iajs-3313	63	53	single	single	ADJ
iajs-3313	63	54	signal	signal	NOUN
iajs-3313	63	55	between	between	ADP
iajs-3313	63	56	δ(39.31	δ(39.31	PROPN
iajs-3313	63	57	-	-	PUNCT
iajs-3313	63	58	39.93	39.93	NUM
iajs-3313	63	59	)	)	PUNCT
iajs-3313	63	60	ppm	ppm	NOUN
iajs-3313	63	61	for	for	ADP
iajs-3313	63	62	(	(	PUNCT
iajs-3313	63	63	dmso	dmso	NOUN
iajs-3313	63	64	)	)	PUNCT
iajs-3313	63	65	,	,	PUNCT
iajs-3313	63	66	a	a	DET
iajs-3313	63	67	single	single	ADJ
iajs-3313	63	68	signal	signal	NOUN
iajs-3313	63	69	at	at	ADP
iajs-3313	63	70	δ(124	δ(124	PROPN
iajs-3313	63	71	)	)	PUNCT
iajs-3313	63	72	ppm	ppm	NOUN
iajs-3313	63	73	for	for	ADP
iajs-3313	63	74	(	(	PUNCT
iajs-3313	63	75	c	c	NOUN
iajs-3313	63	76	in	in	ADP
iajs-3313	63	77	imidazole	imidazole	NOUN
iajs-3313	63	78	ring	ring	NOUN
iajs-3313	63	79	)	)	PUNCT
iajs-3313	63	80	,	,	PUNCT
iajs-3313	63	81	a	a	DET
iajs-3313	63	82	single	single	ADJ
iajs-3313	63	83	signal	signal	NOUN
iajs-3313	63	84	at	at	ADP
iajs-3313	63	85	δ(143	δ(143	NOUN
iajs-3313	63	86	)	)	PUNCT
iajs-3313	63	87	ppm	ppm	VERB
iajs-3313	63	88	for	for	ADP
iajs-3313	63	89	(	(	PUNCT
iajs-3313	63	90	ch	ch	NOUN
iajs-3313	63	91	of	of	ADP
iajs-3313	63	92	purine	purine	NOUN
iajs-3313	63	93	ring	ring	NOUN
iajs-3313	63	94	)	)	PUNCT
iajs-3313	63	95	,	,	PUNCT
iajs-3313	63	96	a	a	DET
iajs-3313	63	97	single	single	ADJ
iajs-3313	63	98	signal	signal	NOUN
iajs-3313	63	99	at	at	ADP
iajs-3313	63	100	δ(150	δ(150	PROPN
iajs-3313	63	101	)	)	PUNCT
iajs-3313	63	102	ppm	ppm	NOUN
iajs-3313	63	103	for	for	ADP
iajs-3313	63	104	(	(	PUNCT
iajs-3313	63	105	c	c	NOUN
iajs-3313	63	106	-	-	PUNCT
iajs-3313	63	107	nh	nh	NOUN
iajs-3313	63	108	,	,	PUNCT
iajs-3313	63	109	in	in	ADP
iajs-3313	63	110	purine	purine	NOUN
iajs-3313	63	111	ring	ring	NOUN
iajs-3313	63	112	)	)	PUNCT
iajs-3313	63	113	,	,	PUNCT
iajs-3313	63	114	a	a	DET
iajs-3313	63	115	single	single	ADJ
iajs-3313	63	116	signal	signal	NOUN
iajs-3313	63	117	at	at	ADP
iajs-3313	63	118	δ(159	δ(159	PROPN
iajs-3313	63	119	)	)	PUNCT
iajs-3313	63	120	ppm	ppm	NOUN
iajs-3313	63	121	for	for	ADP
iajs-3313	63	122	(	(	PUNCT
iajs-3313	63	123	c	c	NOUN
iajs-3313	63	124	=	=	SYM
iajs-3313	63	125	o	o	NOUN
iajs-3313	63	126	,	,	PUNCT
iajs-3313	63	127	of	of	ADP
iajs-3313	63	128	purine	purine	NOUN
iajs-3313	63	129	ring	ring	NOUN
iajs-3313	63	130	)	)	PUNCT
iajs-3313	63	131	,	,	PUNCT
iajs-3313	63	132	a	a	DET
iajs-3313	63	133	single	single	ADJ
iajs-3313	63	134	signal	signal	NOUN
iajs-3313	63	135	at	at	ADP
iajs-3313	63	136	δ(166	δ(166	PROPN
iajs-3313	63	137	)	)	PUNCT
iajs-3313	63	138	ppm	ppm	NOUN
iajs-3313	63	139	,	,	PUNCT
iajs-3313	63	140	for	for	ADP
iajs-3313	63	141	(	(	PUNCT
iajs-3313	63	142	c	c	NOUN
iajs-3313	63	143	-	-	PUNCT
iajs-3313	63	144	nh	nh	NOUN
iajs-3313	63	145	,	,	PUNCT
iajs-3313	63	146	in	in	ADP
iajs-3313	63	147	purine	purine	NOUN
iajs-3313	63	148	ring	ring	NOUN
iajs-3313	63	149	)	)	PUNCT
iajs-3313	63	150	,	,	PUNCT
iajs-3313	63	151	a	a	DET
iajs-3313	63	152	single	single	ADJ
iajs-3313	63	153	signal	signal	NOUN
iajs-3313	63	154	at	at	ADP
iajs-3313	63	155	δ(176	δ(176	NOUN
iajs-3313	63	156	)	)	PUNCT
iajs-3313	63	157	ppm	ppm	PROPN
iajs-3313	63	158	,	,	PUNCT
iajs-3313	63	159	for(c	for(c	X
iajs-3313	63	160	=	=	SYM
iajs-3313	63	161	o	o	NOUN
iajs-3313	63	162	,	,	PUNCT
iajs-3313	63	163	amide	amide	NOUN
iajs-3313	63	164	)	)	PUNCT
iajs-3313	63	165	,	,	PUNCT
iajs-3313	63	166	and	and	CCONJ
iajs-3313	63	167	a	a	DET
iajs-3313	63	168	single	single	ADJ
iajs-3313	63	169	signal	signal	NOUN
iajs-3313	63	170	at	at	ADP
iajs-3313	63	171	δ(184	δ(184	PROPN
iajs-3313	63	172	)	)	PUNCT
iajs-3313	63	173	ppm	ppm	NOUN
iajs-3313	63	174	,	,	PUNCT
iajs-3313	63	175	for	for	ADP
iajs-3313	63	176	(	(	PUNCT
iajs-3313	63	177	c	c	NOUN
iajs-3313	63	178	=	=	SYM
iajs-3313	63	179	s	s	NOUN
iajs-3313	63	180	)	)	PUNCT
iajs-3313	63	181	,	,	PUNCT
iajs-3313	63	182	table	table	NOUN
iajs-3313	63	183	3	3	NUM
iajs-3313	63	184	.	.	PUNCT
iajs-3313	63	185	figure	figure	NOUN
iajs-3313	63	186	3	3	NUM
iajs-3313	63	187	.	.	PUNCT
iajs-3313	64	1	the	the	DET
iajs-3313	64	2	13	13	NUM
iajs-3313	64	3	c	c	NOUN
iajs-3313	64	4	-	-	PUNCT
iajs-3313	64	5	nmr	nmr	NOUN
iajs-3313	64	6	spectrum	spectrum	NOUN
iajs-3313	64	7	of	of	ADP
iajs-3313	64	8	ligand	ligand	NOUN
iajs-3313	64	9	(	(	PUNCT
iajs-3313	64	10	opp	opp	PROPN
iajs-3313	64	11	)	)	PUNCT
iajs-3313	64	12	.	.	PUNCT
iajs-3313	65	1	table	table	NOUN
iajs-3313	65	2	4	4	NUM
iajs-3313	65	3	.	.	PUNCT
iajs-3313	66	1	the	the	DET
iajs-3313	66	2	13	13	NUM
iajs-3313	66	3	cnmr	cnmr	NOUN
iajs-3313	66	4	signals	signal	NOUN
iajs-3313	66	5	for	for	ADP
iajs-3313	66	6	ligand	ligand	NOUN
iajs-3313	66	7	(	(	PUNCT
iajs-3313	66	8	opp	opp	PROPN
iajs-3313	66	9	)	)	PUNCT
iajs-3313	66	10	.	.	PUNCT
iajs-3313	67	1	symbol	symbol	NOUN
iajs-3313	67	2	δppm	δppm	PROPN
iajs-3313	67	3	group	group	NOUN
iajs-3313	67	4	a	a	DET
iajs-3313	67	5	10.23	10.23	NUM
iajs-3313	67	6	ch3,methyl	ch3,methyl	PROPN
iajs-3313	67	7	b	b	PROPN
iajs-3313	67	8	30.02	30.02	NUM
iajs-3313	67	9	ch2,methylene	ch2,methylene	NOUN
iajs-3313	67	10	c	c	NOUN
iajs-3313	67	11	124	124	NUM
iajs-3313	67	12	cimidazole	cimidazole	NOUN
iajs-3313	67	13	ring	ring	NOUN
iajs-3313	67	14	d	d	PROPN
iajs-3313	67	15	143	143	NUM
iajs-3313	67	16	ch	ch	NOUN
iajs-3313	67	17	in	in	ADP
iajs-3313	67	18	purine	purine	NOUN
iajs-3313	67	19	ring	ring	NOUN
iajs-3313	67	20	e	e	NOUN
iajs-3313	67	21	150	150	NUM
iajs-3313	67	22	c	c	NOUN
iajs-3313	67	23	-	-	PUNCT
iajs-3313	67	24	nh	nh	NOUN
iajs-3313	67	25	in	in	ADP
iajs-3313	67	26	purine	purine	NOUN
iajs-3313	67	27	ring	ring	NOUN
iajs-3313	67	28	f	f	PROPN
iajs-3313	67	29	159	159	NUM
iajs-3313	67	30	c	c	NOUN
iajs-3313	67	31	=	=	X
iajs-3313	67	32	o	o	NOUN
iajs-3313	67	33	in	in	ADP
iajs-3313	67	34	purine	purine	NOUN
iajs-3313	67	35	ring	ring	NOUN
iajs-3313	67	36	g	g	PROPN
iajs-3313	67	37	166	166	NUM
iajs-3313	67	38	c	c	NOUN
iajs-3313	67	39	-	-	PUNCT
iajs-3313	67	40	nh	nh	NOUN
iajs-3313	67	41	in	in	ADP
iajs-3313	67	42	purine	purine	NOUN
iajs-3313	67	43	ring	ring	NOUN
iajs-3313	67	44	h	h	NOUN
iajs-3313	67	45	176	176	NUM
iajs-3313	67	46	c	c	X
iajs-3313	67	47	=	=	X
iajs-3313	67	48	o	o	NOUN
iajs-3313	67	49	,	,	PUNCT
iajs-3313	67	50	amid	amid	ADP
iajs-3313	67	51	i	i	PRON
iajs-3313	67	52	184	184	NUM
iajs-3313	67	53	c	c	X
iajs-3313	67	54	=	=	X
iajs-3313	67	55	s	s	VERB
iajs-3313	67	56	according	accord	VERB
iajs-3313	67	57	to	to	PART
iajs-3313	67	58	figure	figure	VERB
iajs-3313	67	59	5	5	NUM
iajs-3313	67	60	,	,	PUNCT
iajs-3313	67	61	the	the	DET
iajs-3313	67	62	uv	uv	NOUN
iajs-3313	67	63	-	-	PUNCT
iajs-3313	67	64	visible	visible	ADJ
iajs-3313	67	65	spectra	spectra	NOUN
iajs-3313	67	66	of	of	ADP
iajs-3313	67	67	the	the	DET
iajs-3313	67	68	ligand	ligand	ADJ
iajs-3313	67	69	opp	opp	INTJ
iajs-3313	67	70	(	(	PUNCT
iajs-3313	67	71	0.01	0.01	NUM
iajs-3313	67	72	m	m	NOUN
iajs-3313	67	73	in	in	ADP
iajs-3313	67	74	dmso	dmso	NOUN
iajs-3313	67	75	)	)	PUNCT
iajs-3313	67	76	in	in	ADP
iajs-3313	67	77	table	table	NOUN
iajs-3313	67	78	4	4	NUM
iajs-3313	67	79	displayed	display	VERB
iajs-3313	67	80	a	a	DET
iajs-3313	67	81	band	band	NOUN
iajs-3313	67	82	at	at	ADP
iajs-3313	67	83	(	(	PUNCT
iajs-3313	67	84	36101	36101	NUM
iajs-3313	67	85	)	)	PUNCT
iajs-3313	67	86	cm	cm	NOUN
iajs-3313	67	87	-1	-1	NOUN
iajs-3313	67	88	,	,	PUNCT
iajs-3313	67	89	which	which	PRON
iajs-3313	67	90	was	be	AUX
iajs-3313	67	91	attributed	attribute	VERB
iajs-3313	67	92	to	to	ADP
iajs-3313	67	93	the	the	DET
iajs-3313	67	94	π→π	π→π	PROPN
iajs-3313	67	95	*	*	PROPN
iajs-3313	67	96	transition	transition	NOUN
iajs-3313	67	97	,	,	PUNCT
iajs-3313	67	98	while	while	SCONJ
iajs-3313	67	99	a	a	DET
iajs-3313	67	100	band	band	NOUN
iajs-3313	67	101	at	at	ADP
iajs-3313	67	102	(	(	PUNCT
iajs-3313	67	103	27777	27777	NUM
iajs-3313	67	104	)	)	PUNCT
iajs-3313	67	105	cm	cm	NOUN
iajs-3313	67	106	-1	-1	PUNCT
iajs-3313	67	107	was	be	AUX
iajs-3313	67	108	observed	observe	VERB
iajs-3313	67	109	due	due	ADP
iajs-3313	67	110	to	to	ADP
iajs-3313	67	111	the	the	DET
iajs-3313	67	112	n→	n→	PROPN
iajs-3313	67	113	π	π	PROPN
iajs-3313	67	114	*	*	NOUN
iajs-3313	67	115	transitions	transition	NOUN
iajs-3313	67	116	[	[	X
iajs-3313	67	117	23	23	NUM
iajs-3313	67	118	]	]	PUNCT
iajs-3313	67	119	.	.	PUNCT
iajs-3313	68	1	figure	figure	NOUN
iajs-3313	68	2	5	5	NUM
iajs-3313	68	3	.	.	PUNCT
iajs-3313	69	1	the	the	DET
iajs-3313	69	2	uv	uv	NOUN
iajs-3313	69	3	-	-	PUNCT
iajs-3313	69	4	visible	visible	ADJ
iajs-3313	69	5	spectrum	spectrum	NOUN
iajs-3313	69	6	of	of	ADP
iajs-3313	69	7	ligand	ligand	NOUN
iajs-3313	69	8	(	(	PUNCT
iajs-3313	69	9	opp	opp	PROPN
iajs-3313	69	10	)	)	PUNCT
iajs-3313	69	11	.	.	PUNCT
iajs-3313	70	1	ihjpas	ihjpas	PROPN
iajs-3313	70	2	.	.	PUNCT
iajs-3313	71	1	37	37	NUM
iajs-3313	71	2	(	(	PUNCT
iajs-3313	71	3	2	2	NUM
iajs-3313	71	4	)	)	PUNCT
iajs-3313	71	5	2024	2024	NUM
iajs-3313	71	6	290	290	NUM
iajs-3313	71	7	-[mncl2(opp)2	-[mncl2(opp)2	NOUN
iajs-3313	71	8	]	]	X
iajs-3313	71	9	d	d	X
iajs-3313	71	10	5	5	NUM
iajs-3313	71	11	,	,	PUNCT
iajs-3313	71	12	displayed	display	VERB
iajs-3313	71	13	distinct	distinct	ADJ
iajs-3313	71	14	spectral	spectral	ADJ
iajs-3313	71	15	bands	band	NOUN
iajs-3313	71	16	at	at	ADP
iajs-3313	71	17	(	(	PUNCT
iajs-3313	71	18	35087	35087	NUM
iajs-3313	71	19	)	)	PUNCT
iajs-3313	71	20	,	,	PUNCT
iajs-3313	71	21	(	(	PUNCT
iajs-3313	71	22	28735	28735	NUM
iajs-3313	71	23	)	)	PUNCT
iajs-3313	71	24	,	,	PUNCT
iajs-3313	71	25	and	and	CCONJ
iajs-3313	71	26	(	(	PUNCT
iajs-3313	71	27	10183	10183	NUM
iajs-3313	71	28	)	)	PUNCT
iajs-3313	71	29	cm	cm	NOUN
iajs-3313	71	30	-1	-1	PUNCT
iajs-3313	71	31	were	be	AUX
iajs-3313	71	32	due	due	ADJ
iajs-3313	71	33	to	to	ADP
iajs-3313	71	34	(	(	PUNCT
iajs-3313	71	35	l.f	l.f	PROPN
iajs-3313	71	36	.	.	PROPN
iajs-3313	71	37	)	)	PUNCT
iajs-3313	72	1	transitions	transition	NOUN
iajs-3313	72	2	,	,	PUNCT
iajs-3313	72	3	(	(	PUNCT
iajs-3313	72	4	c.t	c.t	PROPN
iajs-3313	72	5	.	.	PROPN
iajs-3313	72	6	)	)	PUNCT
iajs-3313	72	7	,	,	PUNCT
iajs-3313	72	8	and	and	CCONJ
iajs-3313	72	9	(	(	PUNCT
iajs-3313	72	10	6	6	NUM
iajs-3313	72	11	a1	a1	NOUN
iajs-3313	72	12	g	g	NOUN
iajs-3313	72	13	→	→	SYM
iajs-3313	72	14	4	4	NUM
iajs-3313	72	15	t1(g	t1(g	NUM
iajs-3313	72	16	)	)	PUNCT
iajs-3313	72	17	)	)	PUNCT
iajs-3313	72	18	transitions	transition	NOUN
iajs-3313	72	19	,	,	PUNCT
iajs-3313	72	20	respectively	respectively	ADV
iajs-3313	72	21	[	[	X
iajs-3313	72	22	19,23	19,23	NOUN
iajs-3313	72	23	]	]	PUNCT
iajs-3313	72	24	.	.	PUNCT
iajs-3313	73	1	-[cocl2(opp)2	-[cocl2(opp)2	PUNCT
iajs-3313	73	2	]	]	X
iajs-3313	74	1	d	d	X
iajs-3313	74	2	7	7	NUM
iajs-3313	74	3	in	in	ADP
iajs-3313	74	4	figure	figure	NOUN
iajs-3313	74	5	6	6	NUM
iajs-3313	74	6	,	,	PUNCT
iajs-3313	74	7	exhibited	exhibit	VERB
iajs-3313	74	8	clear	clear	ADJ
iajs-3313	74	9	spectral	spectral	ADJ
iajs-3313	74	10	bands	band	NOUN
iajs-3313	74	11	at	at	ADP
iajs-3313	74	12	(	(	PUNCT
iajs-3313	74	13	34482	34482	NUM
iajs-3313	74	14	)	)	PUNCT
iajs-3313	74	15	,	,	PUNCT
iajs-3313	74	16	(	(	PUNCT
iajs-3313	74	17	28735	28735	NUM
iajs-3313	74	18	)	)	PUNCT
iajs-3313	74	19	,	,	PUNCT
iajs-3313	74	20	(	(	PUNCT
iajs-3313	74	21	34482	34482	NUM
iajs-3313	74	22	)	)	PUNCT
iajs-3313	74	23	,	,	PUNCT
iajs-3313	74	24	and	and	CCONJ
iajs-3313	74	25	(	(	PUNCT
iajs-3313	74	26	14836	14836	NUM
iajs-3313	74	27	)	)	PUNCT
iajs-3313	74	28	cm	cm	NOUN
iajs-3313	74	29	-1	-1	NOUN
iajs-3313	74	30	,	,	PUNCT
iajs-3313	74	31	which	which	PRON
iajs-3313	74	32	were	be	AUX
iajs-3313	74	33	associated	associate	VERB
iajs-3313	74	34	with	with	ADP
iajs-3313	74	35	(	(	PUNCT
iajs-3313	74	36	l.f	l.f	PROPN
iajs-3313	74	37	.	.	PROPN
iajs-3313	74	38	)	)	PUNCT
iajs-3313	74	39	,	,	PUNCT
iajs-3313	74	40	and	and	CCONJ
iajs-3313	74	41	(	(	PUNCT
iajs-3313	74	42	c.t	c.t	PROPN
iajs-3313	74	43	.	.	PROPN
iajs-3313	74	44	)	)	PUNCT
iajs-3313	74	45	that	that	PRON
iajs-3313	74	46	mix	mix	VERB
iajs-3313	74	47	with	with	ADP
iajs-3313	74	48	(	(	PUNCT
iajs-3313	74	49	4	4	NUM
iajs-3313	74	50	t1(f	t1(f	NUM
iajs-3313	74	51	)	)	PUNCT
iajs-3313	74	52	→	→	SYM
iajs-3313	74	53	4	4	NUM
iajs-3313	74	54	t1(p	t1(p	NOUN
iajs-3313	74	55	)	)	PUNCT
iajs-3313	74	56	)	)	PUNCT
iajs-3313	74	57	transitions	transition	NOUN
iajs-3313	74	58	,	,	PUNCT
iajs-3313	74	59	(	(	PUNCT
iajs-3313	74	60	4	4	NUM
iajs-3313	74	61	t1g(f	t1g(f	NOUN
iajs-3313	74	62	)	)	PUNCT
iajs-3313	74	63	→	→	SYM
iajs-3313	74	64	4	4	NUM
iajs-3313	74	65	a2	a2	PROPN
iajs-3313	74	66	g	g	NOUN
iajs-3313	74	67	)	)	PUNCT
iajs-3313	74	68	transitions	transition	NOUN
iajs-3313	74	69	,	,	PUNCT
iajs-3313	74	70	and	and	CCONJ
iajs-3313	74	71	(	(	PUNCT
iajs-3313	74	72	4	4	NUM
iajs-3313	74	73	t1g(f	t1g(f	NOUN
iajs-3313	74	74	)	)	PUNCT
iajs-3313	74	75	→	→	SYM
iajs-3313	74	76	4	4	NUM
iajs-3313	74	77	t2	t2	NOUN
iajs-3313	74	78	g	g	NOUN
iajs-3313	74	79	)	)	PUNCT
iajs-3313	74	80	transitions	transition	NOUN
iajs-3313	74	81	,	,	PUNCT
iajs-3313	74	82	respectively	respectively	ADV
iajs-3313	74	83	[	[	X
iajs-3313	74	84	24,25	24,25	NUM
iajs-3313	74	85	]	]	PUNCT
iajs-3313	74	86	.	.	PUNCT
iajs-3313	75	1	figure	figure	NOUN
iajs-3313	75	2	6	6	NUM
iajs-3313	75	3	.	.	PUNCT
iajs-3313	76	1	the	the	DET
iajs-3313	76	2	uv	uv	NOUN
iajs-3313	76	3	-	-	PUNCT
iajs-3313	76	4	visible	visible	ADJ
iajs-3313	76	5	spectrum	spectrum	NOUN
iajs-3313	76	6	of	of	ADP
iajs-3313	76	7	[	[	X
iajs-3313	76	8	cocl2(opp)2	cocl2(opp)2	X
iajs-3313	76	9	]	]	X
iajs-3313	76	10	.	.	PUNCT
iajs-3313	77	1	-[nicl2(opp)2	-[nicl2(opp)2	PUNCT
iajs-3313	77	2	]	]	X
iajs-3313	77	3	d	d	X
iajs-3313	77	4	8	8	NUM
iajs-3313	77	5	,	,	PUNCT
iajs-3313	77	6	the	the	DET
iajs-3313	77	7	complex	complex	NOUN
iajs-3313	77	8	exhibited	exhibit	VERB
iajs-3313	77	9	distinct	distinct	ADJ
iajs-3313	77	10	spectral	spectral	ADJ
iajs-3313	77	11	bands	band	NOUN
iajs-3313	77	12	at	at	ADP
iajs-3313	77	13	(	(	PUNCT
iajs-3313	77	14	34013	34013	NUM
iajs-3313	77	15	,	,	PUNCT
iajs-3313	77	16	28735	28735	NUM
iajs-3313	77	17	,	,	PUNCT
iajs-3313	77	18	15197	15197	NUM
iajs-3313	77	19	)	)	PUNCT
iajs-3313	77	20	and	and	CCONJ
iajs-3313	77	21	(	(	PUNCT
iajs-3313	77	22	11299	11299	NUM
iajs-3313	77	23	)	)	PUNCT
iajs-3313	77	24	cm	cm	NOUN
iajs-3313	77	25	-1	-1	NOUN
iajs-3313	77	26	,	,	PUNCT
iajs-3313	77	27	which	which	PRON
iajs-3313	77	28	were	be	AUX
iajs-3313	77	29	for	for	ADP
iajs-3313	77	30	ligand	ligand	ADJ
iajs-3313	77	31	field	field	NOUN
iajs-3313	77	32	(	(	PUNCT
iajs-3313	77	33	lf	lf	NOUN
iajs-3313	77	34	)	)	PUNCT
iajs-3313	77	35	,	,	PUNCT
iajs-3313	77	36	charge	charge	NOUN
iajs-3313	77	37	transfer	transfer	NOUN
iajs-3313	77	38	(	(	PUNCT
iajs-3313	77	39	ct	ct	NOUN
iajs-3313	77	40	)	)	PUNCT
iajs-3313	77	41	that	that	PRON
iajs-3313	77	42	mix	mix	VERB
iajs-3313	77	43	with	with	ADP
iajs-3313	77	44	(	(	PUNCT
iajs-3313	77	45	3	3	NUM
iajs-3313	77	46	a1	a1	NOUN
iajs-3313	77	47	g	g	NOUN
iajs-3313	77	48	3	3	NUM
iajs-3313	77	49	t1g(p	t1g(p	NOUN
iajs-3313	77	50	)	)	PUNCT
iajs-3313	77	51	)	)	PUNCT
iajs-3313	77	52	,	,	PUNCT
iajs-3313	77	53	(	(	PUNCT
iajs-3313	77	54	3	3	NUM
iajs-3313	77	55	a2	a2	NOUN
iajs-3313	77	56	g	g	PROPN
iajs-3313	77	57	3	3	NUM
iajs-3313	77	58	t1	t1	NOUN
iajs-3313	77	59	g	g	NOUN
iajs-3313	77	60	)	)	PUNCT
iajs-3313	77	61	,	,	PUNCT
iajs-3313	77	62	and	and	CCONJ
iajs-3313	77	63	(	(	PUNCT
iajs-3313	77	64	3	3	NUM
iajs-3313	77	65	a2	a2	PROPN
iajs-3313	77	66	g	g	NOUN
iajs-3313	77	67	3	3	NUM
iajs-3313	77	68	t2	t2	NOUN
iajs-3313	77	69	g	g	NOUN
iajs-3313	77	70	)	)	PUNCT
iajs-3313	77	71	transitions	transition	NOUN
iajs-3313	77	72	,	,	PUNCT
iajs-3313	77	73	respectively	respectively	ADV
iajs-3313	77	74	[	[	X
iajs-3313	77	75	24,25	24,25	NUM
iajs-3313	77	76	]	]	PUNCT
iajs-3313	77	77	.	.	PUNCT
iajs-3313	78	1	-[pdcl2(opp)2	-[pdcl2(opp)2	NOUN
iajs-3313	78	2	]	]	X
iajs-3313	78	3	d	d	X
iajs-3313	78	4	8	8	NUM
iajs-3313	78	5	in	in	ADP
iajs-3313	78	6	figure	figure	NOUN
iajs-3313	78	7	10	10	NUM
iajs-3313	78	8	,	,	PUNCT
iajs-3313	78	9	the	the	DET
iajs-3313	78	10	complex	complex	NOUN
iajs-3313	78	11	exhibited	exhibit	VERB
iajs-3313	78	12	distinct	distinct	ADJ
iajs-3313	78	13	spectral	spectral	ADJ
iajs-3313	78	14	bands	band	NOUN
iajs-3313	78	15	at	at	ADP
iajs-3313	78	16	(	(	PUNCT
iajs-3313	78	17	34013	34013	NUM
iajs-3313	78	18	,	,	PUNCT
iajs-3313	78	19	28735,15197	28735,15197	NUM
iajs-3313	78	20	)	)	PUNCT
iajs-3313	78	21	,	,	PUNCT
iajs-3313	78	22	and	and	CCONJ
iajs-3313	78	23	11299	11299	NUM
iajs-3313	78	24	)	)	PUNCT
iajs-3313	78	25	cm	cm	NOUN
iajs-3313	78	26	-1	-1	NOUN
iajs-3313	78	27	,	,	PUNCT
iajs-3313	78	28	which	which	PRON
iajs-3313	78	29	were	be	AUX
iajs-3313	78	30	assigned	assign	VERB
iajs-3313	78	31	for	for	ADP
iajs-3313	78	32	(	(	PUNCT
iajs-3313	78	33	l.f	l.f	PROPN
iajs-3313	78	34	.	.	PROPN
iajs-3313	78	35	)	)	PUNCT
iajs-3313	78	36	,	,	PUNCT
iajs-3313	78	37	(	(	PUNCT
iajs-3313	78	38	c.t	c.t	PROPN
iajs-3313	78	39	.	.	PROPN
iajs-3313	78	40	)	)	PUNCT
iajs-3313	78	41	that	that	PRON
iajs-3313	78	42	mix	mix	VERB
iajs-3313	78	43	with	with	ADP
iajs-3313	78	44	the	the	DET
iajs-3313	78	45	(	(	PUNCT
iajs-3313	78	46	3	3	NUM
iajs-3313	78	47	a1	a1	NOUN
iajs-3313	78	48	g	g	NOUN
iajs-3313	78	49	3	3	NUM
iajs-3313	78	50	t1g(p	t1g(p	NOUN
iajs-3313	78	51	)	)	PUNCT
iajs-3313	78	52	)	)	PUNCT
iajs-3313	78	53	,	,	PUNCT
iajs-3313	78	54	(	(	PUNCT
iajs-3313	78	55	3	3	NUM
iajs-3313	78	56	a2	a2	PROPN
iajs-3313	78	57	3	3	NUM
iajs-3313	78	58	t1	t1	NOUN
iajs-3313	78	59	g	g	NOUN
iajs-3313	78	60	)	)	PUNCT
iajs-3313	78	61	,	,	PUNCT
iajs-3313	78	62	and	and	CCONJ
iajs-3313	78	63	(	(	PUNCT
iajs-3313	78	64	3	3	NUM
iajs-3313	78	65	a2	a2	PROPN
iajs-3313	78	66	g	g	NOUN
iajs-3313	78	67	3	3	NUM
iajs-3313	78	68	t2	t2	NOUN
iajs-3313	78	69	g	g	NOUN
iajs-3313	78	70	)	)	PUNCT
iajs-3313	78	71	transitions	transition	NOUN
iajs-3313	78	72	,	,	PUNCT
iajs-3313	78	73	respectively	respectively	ADV
iajs-3313	78	74	[	[	X
iajs-3313	78	75	24,25	24,25	NUM
iajs-3313	78	76	]	]	PUNCT
iajs-3313	78	77	.	.	PUNCT
iajs-3313	79	1	-[cucl2(opp)2	-[cucl2(opp)2	NOUN
iajs-3313	79	2	]	]	X
iajs-3313	79	3	d	d	ADP
iajs-3313	79	4	9	9	NUM
iajs-3313	79	5	in	in	ADP
iajs-3313	79	6	figure	figure	NOUN
iajs-3313	79	7	7	7	NUM
iajs-3313	79	8	,	,	PUNCT
iajs-3313	79	9	displayed	display	VERB
iajs-3313	79	10	distinct	distinct	ADJ
iajs-3313	79	11	spectral	spectral	ADJ
iajs-3313	79	12	bands	band	NOUN
iajs-3313	79	13	at	at	ADP
iajs-3313	79	14	(	(	PUNCT
iajs-3313	79	15	35087	35087	NUM
iajs-3313	79	16	and	and	CCONJ
iajs-3313	79	17	10593	10593	NUM
iajs-3313	79	18	)	)	PUNCT
iajs-3313	79	19	cm	cm	NOUN
iajs-3313	79	20	-1	-1	ADP
iajs-3313	79	21	which	which	PRON
iajs-3313	79	22	were	be	AUX
iajs-3313	79	23	attributed	attribute	VERB
iajs-3313	79	24	to	to	ADP
iajs-3313	79	25	(	(	PUNCT
iajs-3313	79	26	l.f	l.f	PROPN
iajs-3313	79	27	.	.	PROPN
iajs-3313	79	28	)	)	PUNCT
iajs-3313	80	1	and	and	CCONJ
iajs-3313	80	2	(	(	PUNCT
iajs-3313	80	3	2	2	NUM
iajs-3313	80	4	eg	eg	NOUN
iajs-3313	80	5	2	2	NUM
iajs-3313	80	6	t2	t2	NOUN
iajs-3313	80	7	g	g	NOUN
iajs-3313	80	8	)	)	PUNCT
iajs-3313	80	9	transitions	transition	NOUN
iajs-3313	80	10	,	,	PUNCT
iajs-3313	80	11	respectively	respectively	ADV
iajs-3313	80	12	[	[	X
iajs-3313	80	13	23	23	NUM
iajs-3313	80	14	]	]	PUNCT
iajs-3313	80	15	.	.	PUNCT
iajs-3313	81	1	figure	figure	NOUN
iajs-3313	81	2	7	7	NUM
iajs-3313	81	3	.	.	PUNCT
iajs-3313	82	1	the	the	DET
iajs-3313	82	2	uv	uv	NOUN
iajs-3313	82	3	-	-	PUNCT
iajs-3313	82	4	visible	visible	ADJ
iajs-3313	82	5	spectrum	spectrum	NOUN
iajs-3313	82	6	of	of	ADP
iajs-3313	82	7	[	[	X
iajs-3313	82	8	cucl2(opp)2	cucl2(opp)2	NOUN
iajs-3313	82	9	]	]	PUNCT
iajs-3313	82	10	.	.	PUNCT
iajs-3313	83	1	the	the	DET
iajs-3313	83	2	complexes	complex	NOUN
iajs-3313	83	3	of	of	ADP
iajs-3313	83	4	[	[	X
iajs-3313	83	5	zncl2(opp)2	zncl2(opp)2	X
iajs-3313	83	6	]	]	X
iajs-3313	83	7	and	and	CCONJ
iajs-3313	83	8	[	[	X
iajs-3313	83	9	cdcl2(opp)2	cdcl2(opp)2	NOUN
iajs-3313	83	10	]	]	PUNCT
iajs-3313	83	11	in	in	ADP
iajs-3313	83	12	figures	figure	NOUN
iajs-3313	83	13	12	12	NUM
iajs-3313	83	14	and	and	CCONJ
iajs-3313	83	15	13	13	NUM
iajs-3313	83	16	,	,	PUNCT
iajs-3313	83	17	respectively	respectively	ADV
iajs-3313	83	18	,	,	PUNCT
iajs-3313	83	19	showed	show	VERB
iajs-3313	83	20	ligand	ligand	ADJ
iajs-3313	83	21	field	field	NOUN
iajs-3313	83	22	effects	effect	NOUN
iajs-3313	83	23	in	in	ADP
iajs-3313	83	24	the	the	DET
iajs-3313	83	25	range	range	NOUN
iajs-3313	83	26	(	(	PUNCT
iajs-3313	83	27	34129	34129	NUM
iajs-3313	83	28	-	-	SYM
iajs-3313	83	29	34013	34013	NUM
iajs-3313	83	30	)	)	PUNCT
iajs-3313	83	31	cm	cm	NOUN
iajs-3313	83	32	-1	-1	NOUN
iajs-3313	83	33	and	and	CCONJ
iajs-3313	83	34	charge	charge	NOUN
iajs-3313	83	35	transfer	transfer	NOUN
iajs-3313	83	36	of	of	ADP
iajs-3313	83	37	(	(	PUNCT
iajs-3313	83	38	m	m	NOUN
iajs-3313	83	39	l	l	NOUN
iajs-3313	83	40	)	)	PUNCT
iajs-3313	83	41	,	,	PUNCT
iajs-3313	83	42	in	in	ADP
iajs-3313	83	43	the	the	DET
iajs-3313	83	44	range	range	NOUN
iajs-3313	83	45	(	(	PUNCT
iajs-3313	83	46	29735	29735	NUM
iajs-3313	83	47	-	-	SYM
iajs-3313	83	48	28735	28735	NUM
iajs-3313	83	49	)	)	PUNCT
iajs-3313	83	50	cm	cm	NOUN
iajs-3313	83	51	-1	-1	PUNCT
iajs-3313	84	1	[	[	X
iajs-3313	84	2	24	24	NUM
iajs-3313	84	3	]	]	PUNCT
iajs-3313	84	4	.	.	PUNCT
iajs-3313	85	1	ihjpas	ihjpas	PROPN
iajs-3313	85	2	.	.	PUNCT
iajs-3313	86	1	37	37	NUM
iajs-3313	86	2	(	(	PUNCT
iajs-3313	86	3	2	2	NUM
iajs-3313	86	4	)	)	PUNCT
iajs-3313	86	5	2024	2024	NUM
iajs-3313	86	6	291	291	NUM
iajs-3313	86	7	table	table	NOUN
iajs-3313	86	8	5	5	NUM
iajs-3313	86	9	.	.	PUNCT
iajs-3313	87	1	the	the	DET
iajs-3313	87	2	uv	uv	NOUN
iajs-3313	87	3	-	-	PUNCT
iajs-3313	87	4	visible	visible	ADJ
iajs-3313	87	5	spectral	spectral	ADJ
iajs-3313	87	6	data	datum	NOUN
iajs-3313	87	7	of	of	ADP
iajs-3313	87	8	the	the	DET
iajs-3313	87	9	ligand	ligand	ADJ
iajs-3313	87	10	opp	opp	PROPN
iajs-3313	87	11	complexes	complex	NOUN
iajs-3313	87	12	and	and	CCONJ
iajs-3313	87	13	its	its	PRON
iajs-3313	87	14	complexes	complex	NOUN
iajs-3313	87	15	(	(	PUNCT
iajs-3313	87	16	10	10	NUM
iajs-3313	87	17	-3	-3	INTJ
iajs-3313	87	18	m	m	VERB
iajs-3313	87	19	in	in	ADP
iajs-3313	87	20	dmso	dmso	NOUN
iajs-3313	87	21	)	)	PUNCT
iajs-3313	87	22	.	.	PUNCT
iajs-3313	88	1	the	the	DET
iajs-3313	88	2	ft	ft	PROPN
iajs-3313	88	3	-	-	PUNCT
iajs-3313	88	4	ir	ir	NOUN
iajs-3313	88	5	spectra	spectra	NOUN
iajs-3313	88	6	of	of	ADP
iajs-3313	88	7	seven	seven	NUM
iajs-3313	88	8	prepared	prepared	ADJ
iajs-3313	88	9	complexes	complex	NOUN
iajs-3313	88	10	were	be	AUX
iajs-3313	88	11	recorded	record	VERB
iajs-3313	88	12	within	within	ADP
iajs-3313	88	13	the	the	DET
iajs-3313	88	14	range	range	NOUN
iajs-3313	88	15	(	(	PUNCT
iajs-3313	88	16	4000	4000	NUM
iajs-3313	88	17	-	-	SYM
iajs-3313	88	18	200	200	NUM
iajs-3313	88	19	)	)	PUNCT
iajs-3313	88	20	cm	cm	NOUN
iajs-3313	88	21	-1	-1	PUNCT
iajs-3313	88	22	as	as	ADP
iajs-3313	88	23	(	(	PUNCT
iajs-3313	88	24	csi	csi	PROPN
iajs-3313	88	25	)	)	PUNCT
iajs-3313	88	26	discs	disc	NOUN
iajs-3313	88	27	and	and	CCONJ
iajs-3313	88	28	showed	show	VERB
iajs-3313	88	29	significant	significant	ADJ
iajs-3313	88	30	differences	difference	NOUN
iajs-3313	88	31	in	in	ADP
iajs-3313	88	32	the	the	DET
iajs-3313	88	33	bands	band	NOUN
iajs-3313	88	34	associated	associate	VERB
iajs-3313	88	35	with	with	ADP
iajs-3313	88	36	the	the	DET
iajs-3313	88	37	stretching	stretch	VERB
iajs-3313	88	38	vibration	vibration	NOUN
iajs-3313	88	39	at	at	ADP
iajs-3313	88	40	1226	1226	NUM
iajs-3313	88	41	cm	cm	NOUN
iajs-3313	88	42	-1	-1	NOUN
iajs-3313	88	43	in	in	ADP
iajs-3313	88	44	the	the	DET
iajs-3313	88	45	ligand	ligand	NOUN
iajs-3313	88	46	spectrum	spectrum	NOUN
iajs-3313	88	47	,	,	PUNCT
iajs-3313	88	48	which	which	PRON
iajs-3313	88	49	is	be	AUX
iajs-3313	88	50	assigned	assign	VERB
iajs-3313	88	51	to	to	ADP
iajs-3313	88	52	the	the	DET
iajs-3313	88	53	ν(c	ν(c	PROPN
iajs-3313	88	54	=	=	SYM
iajs-3313	88	55	s	s	PART
iajs-3313	88	56	)	)	PUNCT
iajs-3313	88	57	in	in	ADP
iajs-3313	88	58	the	the	DET
iajs-3313	88	59	range	range	NOUN
iajs-3313	88	60	of	of	ADP
iajs-3313	88	61	(	(	PUNCT
iajs-3313	88	62	1182	1182	NUM
iajs-3313	88	63	-	-	SYM
iajs-3313	88	64	1159	1159	NUM
iajs-3313	88	65	)	)	PUNCT
iajs-3313	88	66	cm	cm	NOUN
iajs-3313	88	67	-1	-1	NOUN
iajs-3313	88	68	.	.	PUNCT
iajs-3313	89	1	these	these	DET
iajs-3313	89	2	bands	band	NOUN
iajs-3313	89	3	were	be	AUX
iajs-3313	89	4	shifted	shift	VERB
iajs-3313	89	5	lower	lower	ADV
iajs-3313	89	6	by	by	ADP
iajs-3313	89	7	(	(	PUNCT
iajs-3313	89	8	44	44	NUM
iajs-3313	89	9	-	-	SYM
iajs-3313	89	10	23	23	NUM
iajs-3313	89	11	)	)	PUNCT
iajs-3313	89	12	cm	cm	NOUN
iajs-3313	89	13	-1	-1	NOUN
iajs-3313	89	14	in	in	ADP
iajs-3313	89	15	the	the	DET
iajs-3313	89	16	spectra	spectra	NOUN
iajs-3313	89	17	of	of	ADP
iajs-3313	89	18	the	the	DET
iajs-3313	89	19	complexes	complex	NOUN
iajs-3313	89	20	,	,	PUNCT
iajs-3313	89	21	indicating	indicate	VERB
iajs-3313	89	22	the	the	DET
iajs-3313	89	23	involvement	involvement	NOUN
iajs-3313	89	24	of	of	ADP
iajs-3313	89	25	the	the	DET
iajs-3313	89	26	sulfur	sulfur	NOUN
iajs-3313	89	27	atom	atom	NOUN
iajs-3313	89	28	in	in	ADP
iajs-3313	89	29	the	the	DET
iajs-3313	89	30	thione	thione	NOUN
iajs-3313	89	31	group	group	NOUN
iajs-3313	89	32	in	in	ADP
iajs-3313	89	33	coordination	coordination	NOUN
iajs-3313	89	34	[	[	X
iajs-3313	89	35	26	26	NUM
iajs-3313	89	36	]	]	PUNCT
iajs-3313	89	37	,	,	PUNCT
iajs-3313	89	38	table	table	NOUN
iajs-3313	89	39	5	5	NUM
iajs-3313	89	40	.	.	PUNCT
iajs-3313	90	1	the	the	DET
iajs-3313	90	2	band	band	NOUN
iajs-3313	90	3	caused	cause	VERB
iajs-3313	90	4	by	by	ADP
iajs-3313	90	5	ѵ(c	ѵ(c	NOUN
iajs-3313	90	6	=	=	SYM
iajs-3313	90	7	o	o	NOUN
iajs-3313	90	8	amide	amide	NOUN
iajs-3313	90	9	)	)	PUNCT
iajs-3313	90	10	in	in	ADP
iajs-3313	90	11	the	the	DET
iajs-3313	90	12	range	range	NOUN
iajs-3313	90	13	of	of	ADP
iajs-3313	90	14	(	(	PUNCT
iajs-3313	90	15	1595	1595	NUM
iajs-3313	90	16	-	-	SYM
iajs-3313	90	17	1525	1525	NUM
iajs-3313	90	18	)	)	PUNCT
iajs-3313	90	19	cm	cm	NOUN
iajs-3313	90	20	-1	-1	PUNCT
iajs-3313	90	21	was	be	AUX
iajs-3313	90	22	shifted	shift	VERB
iajs-3313	90	23	to	to	ADP
iajs-3313	90	24	lower	low	ADJ
iajs-3313	90	25	frequencies	frequency	NOUN
iajs-3313	90	26	by	by	ADP
iajs-3313	90	27	(	(	PUNCT
iajs-3313	90	28	79	79	NUM
iajs-3313	90	29	-	-	SYM
iajs-3313	90	30	9	9	NUM
iajs-3313	90	31	)	)	PUNCT
iajs-3313	90	32	cm	cm	NOUN
iajs-3313	90	33	-1	-1	PUNCT
iajs-3313	90	34	,	,	PUNCT
iajs-3313	90	35	suggesting	suggest	VERB
iajs-3313	90	36	the	the	DET
iajs-3313	90	37	possibility	possibility	NOUN
iajs-3313	90	38	of	of	ADP
iajs-3313	90	39	coordination	coordination	NOUN
iajs-3313	90	40	of	of	ADP
iajs-3313	90	41	the	the	DET
iajs-3313	90	42	ligand	ligand	NOUN
iajs-3313	90	43	through	through	ADP
iajs-3313	90	44	the	the	DET
iajs-3313	90	45	o	o	NOUN
iajs-3313	90	46	-	-	NOUN
iajs-3313	90	47	atom	atom	NOUN
iajs-3313	90	48	at	at	ADP
iajs-3313	90	49	the	the	DET
iajs-3313	90	50	carbonyl	carbonyl	NOUN
iajs-3313	90	51	group	group	NOUN
iajs-3313	90	52	the	the	DET
iajs-3313	90	53	metal	metal	NOUN
iajs-3313	90	54	complexes	complex	NOUN
iajs-3313	90	55	[	[	X
iajs-3313	90	56	27,28	27,28	X
iajs-3313	90	57	]	]	PUNCT
iajs-3313	90	58	as	as	ADP
iajs-3313	90	59	in	in	ADP
iajs-3313	90	60	figures	figure	NOUN
iajs-3313	90	61	8	8	NUM
iajs-3313	90	62	and	and	CCONJ
iajs-3313	90	63	9	9	NUM
iajs-3313	90	64	.	.	PUNCT
iajs-3313	91	1	the	the	DET
iajs-3313	91	2	coordination	coordination	NOUN
iajs-3313	91	3	of	of	ADP
iajs-3313	91	4	m	m	PROPN
iajs-3313	91	5	-	-	PROPN
iajs-3313	91	6	o	o	X
iajs-3313	91	7	and	and	CCONJ
iajs-3313	91	8	m	m	NOUN
iajs-3313	91	9	-	-	PUNCT
iajs-3313	91	10	s	s	PART
iajs-3313	91	11	was	be	AUX
iajs-3313	91	12	evidenced	evidence	VERB
iajs-3313	91	13	by	by	ADP
iajs-3313	91	14	the	the	DET
iajs-3313	91	15	appearance	appearance	NOUN
iajs-3313	91	16	of	of	ADP
iajs-3313	91	17	stretching	stretch	VERB
iajs-3313	91	18	vibrations	vibration	NOUN
iajs-3313	91	19	at	at	ADP
iajs-3313	91	20	around	around	ADV
iajs-3313	91	21	(	(	PUNCT
iajs-3313	91	22	487	487	NUM
iajs-3313	91	23	-	-	SYM
iajs-3313	91	24	455	455	NUM
iajs-3313	91	25	)	)	PUNCT
iajs-3313	91	26	cm	cm	NOUN
iajs-3313	91	27	-1	-1	NOUN
iajs-3313	91	28	,	,	PUNCT
iajs-3313	91	29	(	(	PUNCT
iajs-3313	91	30	379	379	NUM
iajs-3313	91	31	-	-	SYM
iajs-3313	91	32	308	308	NUM
iajs-3313	91	33	)	)	PUNCT
iajs-3313	91	34	cm	cm	NOUN
iajs-3313	91	35	-1	-1	NOUN
iajs-3313	91	36	,	,	PUNCT
iajs-3313	91	37	and	and	CCONJ
iajs-3313	91	38	(	(	PUNCT
iajs-3313	91	39	293	293	NUM
iajs-3313	91	40	-	-	SYM
iajs-3313	91	41	262	262	NUM
iajs-3313	91	42	)	)	PUNCT
iajs-3313	91	43	cm	cm	NOUN
iajs-3313	91	44	-1	-1	NOUN
iajs-3313	91	45	,	,	PUNCT
iajs-3313	91	46	respectively	respectively	ADV
iajs-3313	91	47	,	,	PUNCT
iajs-3313	91	48	which	which	PRON
iajs-3313	91	49	correspond	correspond	VERB
iajs-3313	91	50	to	to	ADP
iajs-3313	91	51	υ(m	υ(m	PROPN
iajs-3313	91	52	-	-	PUNCT
iajs-3313	91	53	o	o	NOUN
iajs-3313	91	54	)	)	PUNCT
iajs-3313	91	55	,	,	PUNCT
iajs-3313	91	56	υ(m	υ(m	PROPN
iajs-3313	91	57	-	-	PUNCT
iajs-3313	91	58	s	s	NOUN
iajs-3313	91	59	)	)	PUNCT
iajs-3313	91	60	,	,	PUNCT
iajs-3313	91	61	and	and	CCONJ
iajs-3313	91	62	υ(m	υ(m	PROPN
iajs-3313	91	63	-	-	PUNCT
iajs-3313	91	64	cl	cl	NOUN
iajs-3313	91	65	)	)	PUNCT
iajs-3313	91	66	,	,	PUNCT
iajs-3313	92	1	[	[	X
iajs-3313	92	2	29	29	NUM
iajs-3313	92	3	]	]	PUNCT
iajs-3313	92	4	.	.	PUNCT
iajs-3313	93	1	table	table	NOUN
iajs-3313	93	2	6	6	NUM
iajs-3313	93	3	describes	describe	VERB
iajs-3313	93	4	the	the	DET
iajs-3313	93	5	critical	critical	ADJ
iajs-3313	93	6	bands	band	NOUN
iajs-3313	93	7	and	and	CCONJ
iajs-3313	93	8	their	their	PRON
iajs-3313	93	9	assignments	assignment	NOUN
iajs-3313	93	10	for	for	ADP
iajs-3313	93	11	the	the	DET
iajs-3313	93	12	free	free	ADJ
iajs-3313	93	13	ligand	ligand	NOUN
iajs-3313	93	14	(	(	PUNCT
iajs-3313	93	15	opp	opp	PROPN
iajs-3313	93	16	)	)	PUNCT
iajs-3313	93	17	and	and	CCONJ
iajs-3313	93	18	its	its	PRON
iajs-3313	93	19	complexes	complex	NOUN
iajs-3313	93	20	that	that	PRON
iajs-3313	93	21	were	be	AUX
iajs-3313	93	22	prepared	prepare	VERB
iajs-3313	93	23	.	.	PUNCT
iajs-3313	94	1	compounds	compound	VERB
iajs-3313	94	2	(nm	(nm	PROPN
iajs-3313	94	3	)	)	PUNCT
iajs-3313	94	4	υ	υ	NOUN
iajs-3313	94	5	(	(	PUNCT
iajs-3313	94	6	cm	cm	NOUN
iajs-3313	94	7	-1	-1	PUNCT
iajs-3313	94	8	)	)	PUNCT
iajs-3313	95	1	abc	abc	PROPN
iajs-3313	95	2	εmax	εmax	PROPN
iajs-3313	95	3	molar1	molar1	PROPN
iajs-3313	95	4	cm	cm	PROPN
iajs-3313	95	5	-1	-1	ADP
iajs-3313	95	6	transitions	transition	NOUN
iajs-3313	95	7	(	(	PUNCT
iajs-3313	95	8	opp	opp	INTJ
iajs-3313	95	9	)	)	PUNCT
iajs-3313	95	10	277	277	NUM
iajs-3313	95	11	360	360	NUM
iajs-3313	95	12	36101	36101	NUM
iajs-3313	95	13	27777	27777	NUM
iajs-3313	95	14	2.213	2.213	NUM
iajs-3313	95	15	0.383	0.383	NUM
iajs-3313	95	16	2213	2213	NUM
iajs-3313	95	17	383	383	NUM
iajs-3313	95	18			NOUN
iajs-3313	95	19	*	*	NOUN
iajs-3313	95	20	n	n	PROPN
iajs-3313	95	21	*	*	PUNCT
iajs-3313	95	22	[	[	X
iajs-3313	95	23	mncl2(opp)2	mncl2(opp)2	X
iajs-3313	95	24	]	]	X
iajs-3313	95	25	285	285	NUM
iajs-3313	95	26	348	348	NUM
iajs-3313	95	27	982	982	NUM
iajs-3313	95	28	35087	35087	NUM
iajs-3313	95	29	28735	28735	NUM
iajs-3313	95	30	10183	10183	NUM
iajs-3313	95	31	2.366	2.366	NUM
iajs-3313	95	32	0.837	0.837	NUM
iajs-3313	95	33	0.025	0.025	NUM
iajs-3313	95	34	2366	2366	NUM
iajs-3313	95	35	837	837	NUM
iajs-3313	95	36	25	25	NUM
iajs-3313	95	37	(	(	PUNCT
iajs-3313	95	38	l.f	l.f	PROPN
iajs-3313	95	39	.	.	PROPN
iajs-3313	95	40	)	)	PUNCT
iajs-3313	95	41	(	(	PUNCT
iajs-3313	95	42	c.t	c.t	PROPN
iajs-3313	95	43	)	)	PUNCT
iajs-3313	95	44	6	6	NUM
iajs-3313	95	45	a1	a1	NOUN
iajs-3313	95	46	g	g	NOUN
iajs-3313	95	47	→	→	SYM
iajs-3313	95	48	4	4	NUM
iajs-3313	95	49	t1(g	t1(g	NUM
iajs-3313	95	50	)	)	PUNCT
iajs-3313	96	1	[	[	X
iajs-3313	96	2	cocl2(opp)2	cocl2(opp)2	X
iajs-3313	96	3	]	]	X
iajs-3313	96	4	290	290	NUM
iajs-3313	96	5	348	348	NUM
iajs-3313	96	6	678	678	NUM
iajs-3313	96	7	870	870	NUM
iajs-3313	96	8	34482	34482	NUM
iajs-3313	96	9	28735	28735	NUM
iajs-3313	96	10	14836	14836	NUM
iajs-3313	96	11	34482	34482	NUM
iajs-3313	96	12	2.399	2.399	NUM
iajs-3313	96	13	1.050	1.050	NUM
iajs-3313	96	14	0.110	0.110	NUM
iajs-3313	96	15	0.035	0.035	NUM
iajs-3313	96	16	2399	2399	NUM
iajs-3313	96	17	1050	1050	NUM
iajs-3313	96	18	110	110	NUM
iajs-3313	96	19	35	35	NUM
iajs-3313	96	20	(	(	PUNCT
iajs-3313	96	21	l.f	l.f	PROPN
iajs-3313	96	22	.	.	PROPN
iajs-3313	96	23	)	)	PUNCT
iajs-3313	97	1	(	(	PUNCT
iajs-3313	97	2	c.t.)mix	c.t.)mix	PROPN
iajs-3313	97	3	4	4	NUM
iajs-3313	97	4	t1(f	t1(f	NUM
iajs-3313	97	5	)	)	PUNCT
iajs-3313	97	6	→	→	SYM
iajs-3313	97	7	4	4	NUM
iajs-3313	97	8	t1(p	t1(p	NOUN
iajs-3313	97	9	)	)	PUNCT
iajs-3313	97	10	4	4	NUM
iajs-3313	97	11	t1g(f	t1g(f	NOUN
iajs-3313	97	12	)	)	PUNCT
iajs-3313	97	13	4	4	NUM
iajs-3313	97	14	a2	a2	PROPN
iajs-3313	97	15	g	g	NOUN
iajs-3313	97	16	4	4	NUM
iajs-3313	97	17	t1g(f	t1g(f	NOUN
iajs-3313	97	18	)	)	PUNCT
iajs-3313	97	19	4	4	NUM
iajs-3313	97	20	t2	t2	NOUN
iajs-3313	97	21	g	g	NOUN
iajs-3313	98	1	[	[	X
iajs-3313	98	2	nicl2(opp)2	nicl2(opp)2	NOUN
iajs-3313	98	3	]	]	X
iajs-3313	98	4	294	294	NUM
iajs-3313	98	5	348	348	NUM
iajs-3313	98	6	658	658	NUM
iajs-3313	98	7	885	885	NUM
iajs-3313	98	8	34013	34013	NUM
iajs-3313	98	9	28735	28735	NUM
iajs-3313	98	10	15197	15197	NUM
iajs-3313	98	11	11299	11299	NUM
iajs-3313	98	12	2.416	2.416	NUM
iajs-3313	98	13	1.169	1.169	NUM
iajs-3313	98	14	0.036	0.036	NUM
iajs-3313	98	15	0.035	0.035	NUM
iajs-3313	98	16	2416	2416	NUM
iajs-3313	98	17	1169	1169	NUM
iajs-3313	98	18	36	36	NUM
iajs-3313	98	19	35	35	NUM
iajs-3313	98	20	(	(	PUNCT
iajs-3313	98	21	l.f	l.f	PROPN
iajs-3313	98	22	.	.	PROPN
iajs-3313	98	23	)	)	PUNCT
iajs-3313	99	1	(	(	PUNCT
iajs-3313	99	2	c.t.)mix	c.t.)mix	NOUN
iajs-3313	99	3	3	3	NUM
iajs-3313	99	4	a1	a1	NOUN
iajs-3313	99	5	g	g	NOUN
iajs-3313	99	6	→	→	SYM
iajs-3313	99	7	3	3	NUM
iajs-3313	99	8	t1g(p	t1g(p	PROPN
iajs-3313	99	9	)	)	PUNCT
iajs-3313	99	10	3	3	NUM
iajs-3313	99	11	a2	a2	PROPN
iajs-3313	99	12	g	g	PROPN
iajs-3313	99	13	→	→	SYM
iajs-3313	99	14	3	3	NUM
iajs-3313	99	15	t1	t1	NOUN
iajs-3313	99	16	g	g	PROPN
iajs-3313	99	17	3	3	NUM
iajs-3313	99	18	a2	a2	PROPN
iajs-3313	99	19	g	g	PROPN
iajs-3313	99	20	→	→	SYM
iajs-3313	99	21	3	3	NUM
iajs-3313	99	22	t2	t2	NOUN
iajs-3313	99	23	g	g	NOUN
iajs-3313	99	24	[	[	X
iajs-3313	99	25	cucl2(opp)2	cucl2(opp)2	NOUN
iajs-3313	99	26	]	]	X
iajs-3313	99	27	285	285	NUM
iajs-3313	99	28	944	944	NUM
iajs-3313	99	29	35087	35087	NUM
iajs-3313	99	30	10593	10593	NUM
iajs-3313	99	31	2.369	2.369	NUM
iajs-3313	99	32	0.078	0.078	NUM
iajs-3313	99	33	2369	2369	NUM
iajs-3313	99	34	78	78	NUM
iajs-3313	99	35	(	(	PUNCT
iajs-3313	99	36	l.f	l.f	PROPN
iajs-3313	99	37	.	.	PROPN
iajs-3313	99	38	)	)	PUNCT
iajs-3313	99	39	2	2	NUM
iajs-3313	99	40	eg	eg	NOUN
iajs-3313	99	41	→	→	SYM
iajs-3313	99	42	2	2	NUM
iajs-3313	99	43	t2	t2	NOUN
iajs-3313	99	44	g	g	NOUN
iajs-3313	100	1	[	[	X
iajs-3313	100	2	zncl2(opp)2	zncl2(opp)2	X
iajs-3313	100	3	]	]	X
iajs-3313	100	4	294	294	NUM
iajs-3313	100	5	348	348	NUM
iajs-3313	100	6	34013	34013	NUM
iajs-3313	100	7	28735	28735	NUM
iajs-3313	100	8	2.442	2.442	NUM
iajs-3313	100	9	1.266	1.266	NUM
iajs-3313	100	10	2442	2442	NUM
iajs-3313	100	11	1266	1266	NUM
iajs-3313	100	12	(	(	PUNCT
iajs-3313	100	13	l.f	l.f	PROPN
iajs-3313	100	14	.	.	PROPN
iajs-3313	100	15	)	)	PUNCT
iajs-3313	100	16	(	(	PUNCT
iajs-3313	100	17	c.t	c.t	PROPN
iajs-3313	100	18	.	.	PUNCT
iajs-3313	100	19	)	)	PUNCT
iajs-3313	101	1	[	[	X
iajs-3313	101	2	cdcl2(opp)2	cdcl2(opp)2	X
iajs-3313	101	3	]	]	X
iajs-3313	101	4	293	293	NUM
iajs-3313	101	5	348	348	NUM
iajs-3313	101	6	34129	34129	NUM
iajs-3313	101	7	29735	29735	NUM
iajs-3313	101	8	2.383	2.383	NUM
iajs-3313	101	9	1.050	1.050	NUM
iajs-3313	101	10	2383	2383	NUM
iajs-3313	101	11	1050	1050	NUM
iajs-3313	101	12	(	(	PUNCT
iajs-3313	101	13	l.f	l.f	PROPN
iajs-3313	101	14	.	.	PROPN
iajs-3313	101	15	)	)	PUNCT
iajs-3313	102	1	(	(	PUNCT
iajs-3313	102	2	c.t	c.t	PROPN
iajs-3313	102	3	.	.	PUNCT
iajs-3313	102	4	)	)	PUNCT
iajs-3313	103	1	[	[	X
iajs-3313	103	2	pdcl2(opp)2	pdcl2(opp)2	X
iajs-3313	103	3	]	]	X
iajs-3313	103	4	273	273	NUM
iajs-3313	103	5	352	352	NUM
iajs-3313	103	6	982	982	NUM
iajs-3313	103	7	36630	36630	NUM
iajs-3313	103	8	28409	28409	NUM
iajs-3313	103	9	10183	10183	NUM
iajs-3313	103	10	1.628	1.628	NUM
iajs-3313	103	11	0.552	0.552	NUM
iajs-3313	103	12	0.069	0.069	NUM
iajs-3313	103	13	1628	1628	NUM
iajs-3313	103	14	552	552	NUM
iajs-3313	103	15	69	69	NUM
iajs-3313	103	16	(	(	PUNCT
iajs-3313	103	17	l.f	l.f	PROPN
iajs-3313	103	18	.	.	PROPN
iajs-3313	103	19	)	)	PUNCT
iajs-3313	104	1	(	(	PUNCT
iajs-3313	104	2	c.t.)mix	c.t.)mix	PROPN
iajs-3313	104	3	3	3	NUM
iajs-3313	104	4	a2	a2	PROPN
iajs-3313	104	5	g	g	PROPN
iajs-3313	104	6	→	→	SYM
iajs-3313	104	7	3	3	NUM
iajs-3313	104	8	t1g(p	t1g(p	PROPN
iajs-3313	104	9	)	)	PUNCT
iajs-3313	104	10	3	3	NUM
iajs-3313	104	11	a2	a2	PROPN
iajs-3313	104	12	g	g	NOUN
iajs-3313	104	13	→	→	SYM
iajs-3313	104	14	3	3	NUM
iajs-3313	104	15	t2	t2	NOUN
iajs-3313	104	16	g	g	PROPN
iajs-3313	104	17	ihjpas	ihjpas	PROPN
iajs-3313	104	18	.	.	PUNCT
iajs-3313	105	1	37	37	NUM
iajs-3313	105	2	(	(	PUNCT
iajs-3313	105	3	2	2	NUM
iajs-3313	105	4	)	)	PUNCT
iajs-3313	105	5	2024	2024	NUM
iajs-3313	105	6	292	292	NUM
iajs-3313	105	7	figure	figure	NOUN
iajs-3313	105	8	8	8	NUM
iajs-3313	105	9	.	.	PUNCT
iajs-3313	106	1	the	the	DET
iajs-3313	106	2	ft	ft	PROPN
iajs-3313	106	3	-	-	PUNCT
iajs-3313	106	4	ir	ir	NOUN
iajs-3313	106	5	spectrum	spectrum	NOUN
iajs-3313	106	6	of	of	ADP
iajs-3313	106	7	[	[	X
iajs-3313	106	8	cdcl2(opp)2	cdcl2(opp)2	NOUN
iajs-3313	106	9	]	]	X
iajs-3313	106	10	complexes	complex	NOUN
iajs-3313	106	11	.	.	PUNCT
iajs-3313	107	1	figure	figure	NOUN
iajs-3313	107	2	9	9	NUM
iajs-3313	107	3	.	.	PUNCT
iajs-3313	108	1	the	the	DET
iajs-3313	108	2	ft	ft	PROPN
iajs-3313	108	3	-	-	PUNCT
iajs-3313	108	4	ir	ir	NOUN
iajs-3313	108	5	spectrum	spectrum	NOUN
iajs-3313	108	6	of	of	ADP
iajs-3313	108	7	[	[	X
iajs-3313	108	8	zncl2(opp)2	zncl2(opp)2	NOUN
iajs-3313	108	9	]	]	X
iajs-3313	108	10	complexes	complex	NOUN
iajs-3313	108	11	.	.	PUNCT
iajs-3313	109	1	figure	figure	NOUN
iajs-3313	109	2	10	10	NUM
iajs-3313	109	3	.	.	PUNCT
iajs-3313	110	1	the	the	DET
iajs-3313	110	2	ft	ft	PROPN
iajs-3313	110	3	-	-	PUNCT
iajs-3313	110	4	ir	ir	NOUN
iajs-3313	110	5	spectrum	spectrum	NOUN
iajs-3313	110	6	of	of	ADP
iajs-3313	110	7	[	[	X
iajs-3313	110	8	zncl2(opp)2	zncl2(opp)2	NOUN
iajs-3313	110	9	]	]	X
iajs-3313	110	10	complexes	complex	NOUN
iajs-3313	110	11	.	.	PUNCT
iajs-3313	111	1	ihjpas	ihjpas	PROPN
iajs-3313	111	2	.	.	PUNCT
iajs-3313	112	1	37	37	NUM
iajs-3313	112	2	(	(	PUNCT
iajs-3313	112	3	2	2	NUM
iajs-3313	112	4	)	)	PUNCT
iajs-3313	112	5	2024	2024	NUM
iajs-3313	112	6	293	293	NUM
iajs-3313	112	7	table	table	NOUN
iajs-3313	112	8	6	6	NUM
iajs-3313	112	9	.	.	PUNCT
iajs-3313	113	1	the	the	DET
iajs-3313	113	2	important	important	ADJ
iajs-3313	113	3	bands	band	NOUN
iajs-3313	113	4	and	and	CCONJ
iajs-3313	113	5	assignment	assignment	NOUN
iajs-3313	113	6	for	for	ADP
iajs-3313	113	7	(	(	PUNCT
iajs-3313	113	8	opp	opp	INTJ
iajs-3313	113	9	)	)	PUNCT
iajs-3313	113	10	and	and	CCONJ
iajs-3313	113	11	its	its	PRON
iajs-3313	113	12	metal	metal	NOUN
iajs-3313	113	13	complexes	complex	NOUN
iajs-3313	113	14	.	.	PUNCT
iajs-3313	114	1	compound	compound	NOUN
iajs-3313	114	2	ν(n	ν(n	NOUN
iajs-3313	114	3	-	-	PUNCT
iajs-3313	114	4	h	h	NOUN
iajs-3313	114	5	)	)	PUNCT
iajs-3313	114	6	ν(c	ν(c	PROPN
iajs-3313	114	7	=	=	SYM
iajs-3313	114	8	o	o	NOUN
iajs-3313	114	9	)	)	PUNCT
iajs-3313	114	10	amide	amide	NOUN
iajs-3313	114	11	ν(c	ν(c	PROPN
iajs-3313	114	12	=	=	SYM
iajs-3313	114	13	s	s	PART
iajs-3313	114	14	)	)	PUNCT
iajs-3313	114	15	ν(m	ν(m	PROPN
iajs-3313	114	16	-	-	PUNCT
iajs-3313	114	17	o	o	NOUN
iajs-3313	114	18	)	)	PUNCT
iajs-3313	114	19	ν(m	ν(m	PROPN
iajs-3313	114	20	-	-	PUNCT
iajs-3313	114	21	s	s	NOUN
iajs-3313	114	22	)	)	PUNCT
iajs-3313	114	23	ν(m	ν(m	NOUN
iajs-3313	114	24	-	-	PUNCT
iajs-3313	114	25	cl	cl	NOUN
iajs-3313	114	26	)	)	PUNCT
iajs-3313	114	27	ligand	ligand	NOUN
iajs-3313	114	28	(	(	PUNCT
iajs-3313	114	29	opp	opp	PROPN
iajs-3313	114	30	)	)	PUNCT
iajs-3313	114	31	3160(m	3160(m	NOUN
iajs-3313	114	32	)	)	PUNCT
iajs-3313	114	33	1604(m	1604(m	NUM
iajs-3313	114	34	)	)	PUNCT
iajs-3313	115	1	1226(m	1226(m	PUNCT
iajs-3313	115	2	)	)	PUNCT
iajs-3313	116	1	------------	------------	PUNCT
iajs-3313	117	1	[	[	X
iajs-3313	117	2	mncl2(opp)2	mncl2(opp)2	X
iajs-3313	117	3	]	]	X
iajs-3313	117	4	3163(m	3163(m	NUM
iajs-3313	117	5	)	)	PUNCT
iajs-3313	117	6	1593(s	1593(s	NUM
iajs-3313	117	7	)	)	PUNCT
iajs-3313	117	8	1159(s	1159(s	NOUN
iajs-3313	117	9	)	)	PUNCT
iajs-3313	117	10	480(w	480(w	NOUN
iajs-3313	117	11	)	)	PUNCT
iajs-3313	117	12	379(w	379(w	PROPN
iajs-3313	117	13	)	)	PUNCT
iajs-3313	117	14	293(w	293(w	PROPN
iajs-3313	117	15	)	)	PUNCT
iajs-3313	118	1	[	[	X
iajs-3313	118	2	cocl2(opp)2	cocl2(opp)2	X
iajs-3313	118	3	]	]	X
iajs-3313	118	4	3170(m	3170(m	NOUN
iajs-3313	118	5	)	)	PUNCT
iajs-3313	118	6	1527(s	1527(s	NUM
iajs-3313	118	7	)	)	PUNCT
iajs-3313	119	1	1180(s	1180(s	NUM
iajs-3313	119	2	)	)	PUNCT
iajs-3313	120	1	462(w	462(w	PROPN
iajs-3313	120	2	)	)	PUNCT
iajs-3313	120	3	329(w	329(w	NUM
iajs-3313	120	4	)	)	PUNCT
iajs-3313	120	5	268(w	268(w	PROPN
iajs-3313	120	6	)	)	PUNCT
iajs-3313	121	1	[	[	X
iajs-3313	121	2	nicl2(opp)2	nicl2(opp)2	NOUN
iajs-3313	121	3	]	]	X
iajs-3313	121	4	3170(m	3170(m	NUM
iajs-3313	121	5	)	)	PUNCT
iajs-3313	121	6	1595(s	1595(s	NUM
iajs-3313	121	7	)	)	PUNCT
iajs-3313	121	8	1182(s	1182(s	NUM
iajs-3313	121	9	)	)	PUNCT
iajs-3313	121	10	480(w	480(w	PROPN
iajs-3313	121	11	)	)	PUNCT
iajs-3313	121	12	312(w	312(w	PROPN
iajs-3313	121	13	)	)	PUNCT
iajs-3313	121	14	264(w	264(w	NOUN
iajs-3313	121	15	)	)	PUNCT
iajs-3313	122	1	[	[	X
iajs-3313	122	2	cucl2(opp)2	cucl2(opp)2	NOUN
iajs-3313	122	3	]	]	X
iajs-3313	122	4	3178(m	3178(m	NUM
iajs-3313	122	5	)	)	PUNCT
iajs-3313	122	6	1529(m	1529(m	NUM
iajs-3313	122	7	)	)	PUNCT
iajs-3313	122	8	1161(m	1161(m	X
iajs-3313	122	9	)	)	PUNCT
iajs-3313	122	10	487(w	487(w	PROPN
iajs-3313	122	11	)	)	PUNCT
iajs-3313	122	12	310(w	310(w	PROPN
iajs-3313	122	13	)	)	PUNCT
iajs-3313	122	14	270(w	270(w	PROPN
iajs-3313	122	15	)	)	PUNCT
iajs-3313	123	1	[	[	X
iajs-3313	123	2	zncl2(opp)2	zncl2(opp)2	X
iajs-3313	123	3	]	]	X
iajs-3313	123	4	3180(m	3180(m	NUM
iajs-3313	123	5	)	)	PUNCT
iajs-3313	123	6	1525(m	1525(m	X
iajs-3313	123	7	)	)	PUNCT
iajs-3313	123	8	1163(m	1163(m	NOUN
iajs-3313	123	9	)	)	PUNCT
iajs-3313	123	10	455(w	455(w	NUM
iajs-3313	123	11	)	)	PUNCT
iajs-3313	123	12	308(w	308(w	PROPN
iajs-3313	123	13	)	)	PUNCT
iajs-3313	123	14	271(w	271(w	PROPN
iajs-3313	123	15	)	)	PUNCT
iajs-3313	124	1	[	[	X
iajs-3313	124	2	cdcl2(opp)2	cdcl2(opp)2	X
iajs-3313	124	3	]	]	X
iajs-3313	124	4	3150(m	3150(m	NOUN
iajs-3313	124	5	)	)	PUNCT
iajs-3313	124	6	1544(s	1544(s	NUM
iajs-3313	124	7	)	)	PUNCT
iajs-3313	124	8	1159(s	1159(s	NOUN
iajs-3313	124	9	)	)	PUNCT
iajs-3313	124	10	455(w	455(w	NUM
iajs-3313	124	11	)	)	PUNCT
iajs-3313	124	12	351(w	351(w	NUM
iajs-3313	124	13	)	)	PUNCT
iajs-3313	124	14	262(w	262(w	NOUN
iajs-3313	124	15	)	)	PUNCT
iajs-3313	125	1	[	[	X
iajs-3313	125	2	pdcl2(opp)2	pdcl2(opp)2	X
iajs-3313	125	3	]	]	PUNCT
iajs-3313	125	4	3166(m	3166(m	NUM
iajs-3313	125	5	)	)	PUNCT
iajs-3313	125	6	1535(m	1535(m	X
iajs-3313	125	7	)	)	PUNCT
iajs-3313	125	8	1161	1161	NUM
iajs-3313	125	9	(	(	PUNCT
iajs-3313	125	10	s	s	NOUN
iajs-3313	125	11	)	)	PUNCT
iajs-3313	125	12	462(m	462(m	NOUN
iajs-3313	125	13	)	)	PUNCT
iajs-3313	125	14	351(w	351(w	ADJ
iajs-3313	125	15	)	)	PUNCT
iajs-3313	125	16	258(w	258(w	PROPN
iajs-3313	125	17	)	)	PUNCT
iajs-3313	125	18	the	the	DET
iajs-3313	125	19	magnetic	magnetic	ADJ
iajs-3313	125	20	susceptibilities	susceptibility	NOUN
iajs-3313	125	21	of	of	ADP
iajs-3313	125	22	these	these	DET
iajs-3313	125	23	complexes	complex	NOUN
iajs-3313	125	24	were	be	AUX
iajs-3313	125	25	in	in	ADP
iajs-3313	125	26	good	good	ADJ
iajs-3313	125	27	agreement	agreement	NOUN
iajs-3313	125	28	with	with	ADP
iajs-3313	125	29	the	the	DET
iajs-3313	125	30	values	value	NOUN
iajs-3313	125	31	expected	expect	VERB
iajs-3313	125	32	for	for	ADP
iajs-3313	125	33	high	high	ADJ
iajs-3313	125	34	spin	spin	NOUN
iajs-3313	126	1	[	[	X
iajs-3313	126	2	29,30	29,30	NUM
iajs-3313	126	3	]	]	PUNCT
iajs-3313	126	4	;	;	PUNCT
iajs-3313	126	5	the	the	DET
iajs-3313	126	6	magnetic	magnetic	ADJ
iajs-3313	126	7	susceptibilities	susceptibility	NOUN
iajs-3313	126	8	of	of	ADP
iajs-3313	126	9	these	these	DET
iajs-3313	126	10	complexes	complex	NOUN
iajs-3313	126	11	are	be	AUX
iajs-3313	126	12	listed	list	VERB
iajs-3313	126	13	in	in	ADP
iajs-3313	126	14	table	table	NOUN
iajs-3313	126	15	7	7	NUM
iajs-3313	126	16	.	.	PUNCT
iajs-3313	126	17	table	table	NOUN
iajs-3313	126	18	7	7	NUM
iajs-3313	126	19	.	.	PUNCT
iajs-3313	126	20	magnetic	magnetic	ADJ
iajs-3313	126	21	susceptibilities	susceptibilities	PROPN
iajs-3313	126	22	data	data	PROPN
iajs-3313	126	23	of	of	ADP
iajs-3313	126	24	(	(	PUNCT
iajs-3313	126	25	opp	opp	ADJ
iajs-3313	126	26	)	)	PUNCT
iajs-3313	126	27	complexes	complex	NOUN
iajs-3313	126	28	.	.	PUNCT
iajs-3313	127	1	complexes	complexe	VERB
iajs-3313	127	2	gram	gram	NOUN
iajs-3313	127	3	susce	susce	PROPN
iajs-3313	127	4	.	.	PUNCT
iajs-3313	128	1	xg	xg	PROPN
iajs-3313	129	1	x	x	SYM
iajs-3313	129	2	10	10	NUM
iajs-3313	129	3	-6	-6	INTJ
iajs-3313	129	4	molar	molar	ADJ
iajs-3313	129	5	susce	susce	NOUN
iajs-3313	129	6	.	.	PUNCT
iajs-3313	130	1	xm	xm	PROPN
iajs-3313	130	2	x	x	PUNCT
iajs-3313	131	1	10	10	NUM
iajs-3313	131	2	-6	-6	ADP
iajs-3313	131	3	atomic	atomic	ADJ
iajs-3313	131	4	susce	susce	NOUN
iajs-3313	131	5	.	.	PUNCT
iajs-3313	132	1	xa	xa	PROPN
iajs-3313	133	1	x	x	X
iajs-3313	133	2	10	10	NUM
iajs-3313	134	1	-6	-6	NUM
iajs-3313	134	2	μ	μ	PROPN
iajs-3313	134	3	eff	eff	PROPN
iajs-3313	134	4	(	(	PUNCT
iajs-3313	134	5	b.m	b.m	PROPN
iajs-3313	134	6	)	)	PUNCT
iajs-3313	134	7	no	no	NOUN
iajs-3313	134	8	.	.	PUNCT
iajs-3313	134	9	of	of	ADP
iajs-3313	134	10	unpaired	unpaired	ADJ
iajs-3313	134	11	electrons	electron	NOUN
iajs-3313	134	12	proposed	propose	VERB
iajs-3313	134	13	structure	structure	NOUN
iajs-3313	134	14	[	[	X
iajs-3313	134	15	mncl2(opp)2	mncl2(opp)2	X
iajs-3313	134	16	]	]	X
iajs-3313	134	17	22.46	22.46	NUM
iajs-3313	134	18	1478.4394	1478.4394	NUM
iajs-3313	134	19	14787.4394	14787.4394	NUM
iajs-3313	134	20	5.96	5.96	NUM
iajs-3313	134	21	5	5	NUM
iajs-3313	135	1	oh	oh	INTJ
iajs-3313	136	1	[	[	X
iajs-3313	136	2	cocl2(opp)2	cocl2(opp)2	X
iajs-3313	136	3	]	]	X
iajs-3313	136	4	14.35	14.35	NUM
iajs-3313	136	5	9506.7315	9506.7315	NUM
iajs-3313	136	6	9631.9115	9631.9115	NUM
iajs-3313	136	7	4.79	4.79	NUM
iajs-3313	136	8	3	3	NUM
iajs-3313	137	1	oh	oh	INTJ
iajs-3313	138	1	[	[	X
iajs-3313	138	2	nicl2(opp)2	nicl2(opp)2	NOUN
iajs-3313	138	3	]	]	X
iajs-3313	138	4	5.41	5.41	NUM
iajs-3313	138	5	3582.8807	3582.8807	NUM
iajs-3313	139	1	3708.0607	3708.0607	NUM
iajs-3313	139	2	2.97	2.97	NUM
iajs-3313	139	3	2	2	NUM
iajs-3313	140	1	oh	oh	NUM
iajs-3313	140	2	[	[	X
iajs-3313	140	3	cucl2(opp)2	cucl2(opp)2	NOUN
iajs-3313	140	4	]	]	X
iajs-3313	140	5	1.66	1.66	NUM
iajs-3313	140	6	1107.22	1107.22	NUM
iajs-3313	140	7	1232.4	1232.4	NUM
iajs-3313	140	8	1.71	1.71	NUM
iajs-3313	140	9	1	1	NUM
iajs-3313	140	10	oh	oh	INTJ
iajs-3313	141	1	[	[	X
iajs-3313	141	2	zncl2(opp)2	zncl2(opp)2	X
iajs-3313	141	3	]	]	X
iajs-3313	141	4	0	0	NUM
iajs-3313	141	5	0	0	NUM
iajs-3313	141	6	0	0	NUM
iajs-3313	141	7	0	0	NUM
iajs-3313	141	8	0	0	NUM
iajs-3313	142	1	oh	oh	NUM
iajs-3313	143	1	[	[	X
iajs-3313	143	2	cdcl2(opp)2	cdcl2(opp)2	X
iajs-3313	143	3	]	]	X
iajs-3313	143	4	0	0	NUM
iajs-3313	143	5	0	0	NUM
iajs-3313	143	6	0	0	NUM
iajs-3313	143	7	0	0	NUM
iajs-3313	143	8	0	0	NUM
iajs-3313	144	1	oh	oh	INTJ
iajs-3313	144	2	d	d	NOUN
iajs-3313	144	3	=	=	SYM
iajs-3313	145	1	125.18˟10	125.18˟10	NUM
iajs-3313	145	2	-6	-6	INTJ
iajs-3313	145	3	based	base	VERB
iajs-3313	145	4	on	on	ADP
iajs-3313	145	5	molar	molar	ADJ
iajs-3313	145	6	conductivity	conductivity	NOUN
iajs-3313	145	7	,	,	PUNCT
iajs-3313	145	8	magnetic	magnetic	ADJ
iajs-3313	145	9	moment	moment	NOUN
iajs-3313	145	10	,	,	PUNCT
iajs-3313	145	11	and	and	CCONJ
iajs-3313	145	12	spectroscopic	spectroscopic	ADJ
iajs-3313	145	13	studies	study	NOUN
iajs-3313	145	14	(	(	PUNCT
iajs-3313	145	15	including	include	VERB
iajs-3313	145	16	ft	ft	PROPN
iajs-3313	145	17	-	-	PUNCT
iajs-3313	145	18	ir	ir	NOUN
iajs-3313	145	19	,	,	PUNCT
iajs-3313	145	20	uv	uv	NOUN
iajs-3313	145	21	-	-	PUNCT
iajs-3313	145	22	vis	vis	X
iajs-3313	145	23	,	,	PUNCT
iajs-3313	145	24	1	1	NUM
iajs-3313	145	25	h13	h13	NOUN
iajs-3313	145	26	c	c	NOUN
iajs-3313	145	27	nmr	nmr	NOUN
iajs-3313	145	28	,	,	PUNCT
iajs-3313	145	29	and	and	CCONJ
iajs-3313	145	30	atomic	atomic	ADJ
iajs-3313	145	31	absorption	absorption	NOUN
iajs-3313	145	32	)	)	PUNCT
iajs-3313	145	33	,	,	PUNCT
iajs-3313	145	34	this	this	DET
iajs-3313	145	35	study	study	NOUN
iajs-3313	145	36	determines	determine	VERB
iajs-3313	145	37	that	that	SCONJ
iajs-3313	145	38	the	the	DET
iajs-3313	145	39	ligand	ligand	NOUN
iajs-3313	145	40	opp	opp	PROPN
iajs-3313	145	41	acts	act	VERB
iajs-3313	145	42	as	as	ADP
iajs-3313	145	43	a	a	DET
iajs-3313	145	44	bidentate	bidentate	ADJ
iajs-3313	145	45	ligand	ligand	NOUN
iajs-3313	145	46	when	when	SCONJ
iajs-3313	145	47	coordinating	coordinate	VERB
iajs-3313	145	48	with	with	ADP
iajs-3313	145	49	mn(ii	mn(ii	PROPN
iajs-3313	145	50	)	)	PUNCT
iajs-3313	145	51	,	,	PUNCT
iajs-3313	145	52	co(ii	co(ii	PROPN
iajs-3313	145	53	)	)	PUNCT
iajs-3313	145	54	,	,	PUNCT
iajs-3313	145	55	ni(ii	ni(ii	PROPN
iajs-3313	145	56	)	)	PUNCT
iajs-3313	145	57	,	,	PUNCT
iajs-3313	145	58	cu(ii	cu(ii	PROPN
iajs-3313	145	59	)	)	PUNCT
iajs-3313	145	60	,	,	PUNCT
iajs-3313	145	61	zn(ii	zn(ii	NUM
iajs-3313	145	62	)	)	PUNCT
iajs-3313	145	63	,	,	PUNCT
iajs-3313	145	64	cd(ii	cd(ii	PROPN
iajs-3313	145	65	)	)	PUNCT
iajs-3313	145	66	,	,	PUNCT
iajs-3313	145	67	and	and	CCONJ
iajs-3313	145	68	pd(ii	pd(ii	ADJ
iajs-3313	145	69	)	)	PUNCT
iajs-3313	145	70	ions	ion	NOUN
iajs-3313	145	71	.	.	PUNCT
iajs-3313	146	1	specifically	specifically	ADV
iajs-3313	146	2	,	,	PUNCT
iajs-3313	146	3	the	the	DET
iajs-3313	146	4	oxygen	oxygen	NOUN
iajs-3313	146	5	atom	atom	NOUN
iajs-3313	146	6	of	of	ADP
iajs-3313	146	7	the	the	DET
iajs-3313	146	8	amido	amido	NOUN
iajs-3313	146	9	group	group	NOUN
iajs-3313	146	10	(	(	PUNCT
iajs-3313	146	11	c	c	NOUN
iajs-3313	146	12	=	=	NOUN
iajs-3313	146	13	o	o	NOUN
iajs-3313	146	14	)	)	PUNCT
iajs-3313	146	15	and	and	CCONJ
iajs-3313	146	16	the	the	DET
iajs-3313	146	17	sulfur	sulfur	NOUN
iajs-3313	146	18	atom	atom	NOUN
iajs-3313	146	19	of	of	ADP
iajs-3313	146	20	the	the	DET
iajs-3313	146	21	thioamide	thioamide	ADJ
iajs-3313	146	22	group	group	NOUN
iajs-3313	146	23	(	(	PUNCT
iajs-3313	146	24	c	c	NOUN
iajs-3313	146	25	=	=	SYM
iajs-3313	146	26	s	s	PART
iajs-3313	146	27	)	)	PUNCT
iajs-3313	146	28	are	be	AUX
iajs-3313	146	29	involved	involve	VERB
iajs-3313	146	30	in	in	ADP
iajs-3313	146	31	coordination	coordination	NOUN
iajs-3313	146	32	with	with	ADP
iajs-3313	146	33	the	the	DET
iajs-3313	146	34	metal	metal	NOUN
iajs-3313	146	35	ion	ion	NOUN
iajs-3313	146	36	.	.	PUNCT
iajs-3313	147	1	this	this	PRON
iajs-3313	147	2	suggests	suggest	VERB
iajs-3313	147	3	an	an	DET
iajs-3313	147	4	octahedral	octahedral	ADJ
iajs-3313	147	5	geometry	geometry	NOUN
iajs-3313	147	6	around	around	ADP
iajs-3313	147	7	the	the	DET
iajs-3313	147	8	metal	metal	NOUN
iajs-3313	147	9	ion	ion	NOUN
iajs-3313	147	10	for	for	ADP
iajs-3313	147	11	all	all	PRON
iajs-3313	147	12	of	of	ADP
iajs-3313	147	13	the	the	DET
iajs-3313	147	14	prepared	prepared	ADJ
iajs-3313	147	15	complexes	complex	NOUN
iajs-3313	147	16	,	,	PUNCT
iajs-3313	147	17	scheme	scheme	NOUN
iajs-3313	147	18	2	2	NUM
iajs-3313	147	19	.	.	PUNCT
iajs-3313	147	20	additionally	additionally	ADV
iajs-3313	147	21	,	,	PUNCT
iajs-3313	147	22	ft	ft	PROPN
iajs-3313	147	23	-	-	PUNCT
iajs-3313	147	24	ir	ir	NOUN
iajs-3313	147	25	studies	study	NOUN
iajs-3313	147	26	for	for	ADP
iajs-3313	147	27	the	the	DET
iajs-3313	147	28	opp	opp	PROPN
iajs-3313	147	29	ligand	ligand	NOUN
iajs-3313	147	30	show	show	VERB
iajs-3313	147	31	that	that	SCONJ
iajs-3313	147	32	it	it	PRON
iajs-3313	147	33	is	be	AUX
iajs-3313	147	34	coordinates	coordinate	NOUN
iajs-3313	147	35	with	with	ADP
iajs-3313	147	36	the	the	DET
iajs-3313	147	37	mentioned	mention	VERB
iajs-3313	147	38	functional	functional	ADJ
iajs-3313	147	39	groups	group	NOUN
iajs-3313	147	40	.	.	PUNCT
iajs-3313	148	1	scheme	scheme	NOUN
iajs-3313	148	2	2	2	NUM
iajs-3313	148	3	.	.	PUNCT
iajs-3313	148	4	octahedral	octahedral	ADJ
iajs-3313	148	5	geometry	geometry	NOUN
iajs-3313	148	6	of	of	ADP
iajs-3313	148	7	complexes	complex	NOUN
iajs-3313	148	8	.	.	PUNCT
iajs-3313	149	1	ihjpas	ihjpas	PROPN
iajs-3313	149	2	.	.	PUNCT
iajs-3313	150	1	37	37	NUM
iajs-3313	150	2	(	(	PUNCT
iajs-3313	150	3	2	2	NUM
iajs-3313	150	4	)	)	PUNCT
iajs-3313	150	5	2024	2024	NUM
iajs-3313	150	6	294	294	NUM
iajs-3313	150	7	4	4	NUM
iajs-3313	150	8	.	.	PUNCT
iajs-3313	150	9	conclusion	conclusion	NOUN
iajs-3313	150	10	this	this	DET
iajs-3313	150	11	study	study	NOUN
iajs-3313	150	12	utilizes	utilize	VERB
iajs-3313	150	13	a	a	DET
iajs-3313	150	14	variety	variety	NOUN
iajs-3313	150	15	of	of	ADP
iajs-3313	150	16	analytical	analytical	ADJ
iajs-3313	150	17	techniques	technique	NOUN
iajs-3313	150	18	to	to	PART
iajs-3313	150	19	determine	determine	VERB
iajs-3313	150	20	that	that	SCONJ
iajs-3313	150	21	the	the	DET
iajs-3313	150	22	opp	opp	PROPN
iajs-3313	150	23	ligand	ligand	NOUN
iajs-3313	150	24	acts	act	VERB
iajs-3313	150	25	as	as	ADP
iajs-3313	150	26	a	a	DET
iajs-3313	150	27	bidentate	bidentate	ADJ
iajs-3313	150	28	ligand	ligand	NOUN
iajs-3313	150	29	when	when	SCONJ
iajs-3313	150	30	coordinating	coordinate	VERB
iajs-3313	150	31	with	with	ADP
iajs-3313	150	32	mn(ii	mn(ii	PROPN
iajs-3313	150	33	)	)	PUNCT
iajs-3313	150	34	,	,	PUNCT
iajs-3313	150	35	co(ii	co(ii	PROPN
iajs-3313	150	36	)	)	PUNCT
iajs-3313	150	37	,	,	PUNCT
iajs-3313	150	38	ni(ii	ni(ii	PROPN
iajs-3313	150	39	)	)	PUNCT
iajs-3313	150	40	,	,	PUNCT
iajs-3313	150	41	cu(ii	cu(ii	PROPN
iajs-3313	150	42	)	)	PUNCT
iajs-3313	150	43	,	,	PUNCT
iajs-3313	150	44	zn(ii	zn(ii	NUM
iajs-3313	150	45	)	)	PUNCT
iajs-3313	150	46	,	,	PUNCT
iajs-3313	150	47	cd(ii	cd(ii	PROPN
iajs-3313	150	48	)	)	PUNCT
iajs-3313	150	49	,	,	PUNCT
iajs-3313	150	50	and	and	CCONJ
iajs-3313	150	51	pd(ii	pd(ii	ADJ
iajs-3313	150	52	)	)	PUNCT
iajs-3313	150	53	ions	ion	NOUN
iajs-3313	150	54	.	.	PUNCT
iajs-3313	151	1	the	the	DET
iajs-3313	151	2	amido	amido	NOUN
iajs-3313	151	3	group	group	NOUN
iajs-3313	151	4	's	's	PART
iajs-3313	151	5	oxygen	oxygen	NOUN
iajs-3313	151	6	atom	atom	NOUN
iajs-3313	151	7	(	(	PUNCT
iajs-3313	151	8	c	c	NOUN
iajs-3313	151	9	=	=	NOUN
iajs-3313	151	10	o	o	NOUN
iajs-3313	151	11	)	)	PUNCT
iajs-3313	151	12	and	and	CCONJ
iajs-3313	151	13	the	the	DET
iajs-3313	151	14	thioamide	thioamide	ADJ
iajs-3313	151	15	group	group	NOUN
iajs-3313	151	16	's	's	PART
iajs-3313	151	17	sulfur	sulfur	NOUN
iajs-3313	151	18	atom	atom	NOUN
iajs-3313	151	19	(	(	PUNCT
iajs-3313	151	20	c	c	NOUN
iajs-3313	151	21	=	=	SYM
iajs-3313	151	22	s	s	PART
iajs-3313	151	23	)	)	PUNCT
iajs-3313	151	24	coordinated	coordinate	VERB
iajs-3313	151	25	with	with	ADP
iajs-3313	151	26	the	the	DET
iajs-3313	151	27	metal	metal	NOUN
iajs-3313	151	28	ion	ion	NOUN
iajs-3313	151	29	,	,	PUNCT
iajs-3313	151	30	resulting	result	VERB
iajs-3313	151	31	in	in	ADP
iajs-3313	151	32	an	an	DET
iajs-3313	151	33	octahedral	octahedral	ADJ
iajs-3313	151	34	geometry	geometry	NOUN
iajs-3313	151	35	around	around	ADP
iajs-3313	151	36	the	the	DET
iajs-3313	151	37	metal	metal	NOUN
iajs-3313	151	38	ion	ion	NOUN
iajs-3313	151	39	for	for	ADP
iajs-3313	151	40	all	all	DET
iajs-3313	151	41	prepared	prepared	ADJ
iajs-3313	151	42	complexes	complex	NOUN
iajs-3313	151	43	,	,	PUNCT
iajs-3313	151	44	as	as	SCONJ
iajs-3313	151	45	shown	show	VERB
iajs-3313	151	46	in	in	ADP
iajs-3313	151	47	scheme	scheme	NOUN
iajs-3313	151	48	2	2	NUM
iajs-3313	151	49	.	.	PUNCT
iajs-3313	152	1	furthermore	furthermore	ADV
iajs-3313	152	2	,	,	PUNCT
iajs-3313	152	3	the	the	DET
iajs-3313	152	4	opp	opp	PROPN
iajs-3313	152	5	ligand	ligand	NOUN
iajs-3313	152	6	showed	show	VERB
iajs-3313	152	7	that	that	SCONJ
iajs-3313	152	8	coordination	coordination	NOUN
iajs-3313	152	9	occurred	occur	VERB
iajs-3313	152	10	through	through	ADP
iajs-3313	152	11	the	the	DET
iajs-3313	152	12	mentioned	mention	VERB
iajs-3313	152	13	functional	functional	ADJ
iajs-3313	152	14	groups	group	NOUN
iajs-3313	152	15	and	and	CCONJ
iajs-3313	152	16	the	the	DET
iajs-3313	152	17	formation	formation	NOUN
iajs-3313	152	18	of	of	ADP
iajs-3313	152	19	hexagonal	hexagonal	ADJ
iajs-3313	152	20	rings	ring	NOUN
iajs-3313	152	21	between	between	ADP
iajs-3313	152	22	the	the	DET
iajs-3313	152	23	ligands	ligand	NOUN
iajs-3313	152	24	and	and	CCONJ
iajs-3313	152	25	metal	metal	NOUN
iajs-3313	152	26	ions	ion	NOUN
iajs-3313	152	27	,	,	PUNCT
iajs-3313	152	28	which	which	PRON
iajs-3313	152	29	increased	increase	VERB
iajs-3313	152	30	the	the	DET
iajs-3313	152	31	stability	stability	NOUN
iajs-3313	152	32	of	of	ADP
iajs-3313	152	33	these	these	DET
iajs-3313	152	34	complexes	complex	NOUN
iajs-3313	152	35	.	.	PUNCT
iajs-3313	153	1	in	in	ADP
iajs-3313	153	2	summary	summary	NOUN
iajs-3313	153	3	,	,	PUNCT
iajs-3313	153	4	this	this	DET
iajs-3313	153	5	study	study	NOUN
iajs-3313	153	6	provides	provide	VERB
iajs-3313	153	7	comprehensive	comprehensive	ADJ
iajs-3313	153	8	insights	insight	NOUN
iajs-3313	153	9	into	into	ADP
iajs-3313	153	10	the	the	DET
iajs-3313	153	11	coordination	coordination	NOUN
iajs-3313	153	12	behavior	behavior	NOUN
iajs-3313	153	13	of	of	ADP
iajs-3313	153	14	the	the	DET
iajs-3313	153	15	opp	opp	PROPN
iajs-3313	153	16	ligand	ligand	NOUN
iajs-3313	153	17	with	with	ADP
iajs-3313	153	18	various	various	ADJ
iajs-3313	153	19	metal	metal	NOUN
iajs-3313	153	20	ions	ion	NOUN
iajs-3313	153	21	.	.	PUNCT
iajs-3313	154	1	it	it	PRON
iajs-3313	154	2	offers	offer	VERB
iajs-3313	154	3	a	a	DET
iajs-3313	154	4	detailed	detailed	ADJ
iajs-3313	154	5	understanding	understanding	NOUN
iajs-3313	154	6	of	of	ADP
iajs-3313	154	7	the	the	DET
iajs-3313	154	8	structures	structure	NOUN
iajs-3313	154	9	of	of	ADP
iajs-3313	154	10	the	the	DET
iajs-3313	154	11	prepared	prepared	ADJ
iajs-3313	154	12	complexes	complex	NOUN
iajs-3313	154	13	using	use	VERB
iajs-3313	154	14	multiple	multiple	ADJ
iajs-3313	154	15	analytical	analytical	ADJ
iajs-3313	154	16	techniques	technique	NOUN
iajs-3313	154	17	.	.	PUNCT
iajs-3313	155	1	acknowledgment	acknowledgment	NOUN
iajs-3313	155	2	the	the	DET
iajs-3313	155	3	authors	author	NOUN
iajs-3313	155	4	thank	thank	VERB
iajs-3313	155	5	all	all	DET
iajs-3313	155	6	those	those	PRON
iajs-3313	155	7	who	who	PRON
iajs-3313	155	8	contributed	contribute	VERB
iajs-3313	155	9	to	to	ADP
iajs-3313	155	10	the	the	DET
iajs-3313	155	11	completion	completion	NOUN
iajs-3313	155	12	of	of	ADP
iajs-3313	155	13	this	this	DET
iajs-3313	155	14	research	research	NOUN
iajs-3313	155	15	project	project	NOUN
iajs-3313	155	16	.	.	PUNCT
iajs-3313	156	1	first	first	ADV
iajs-3313	156	2	and	and	CCONJ
iajs-3313	156	3	foremost	foremost	ADV
iajs-3313	156	4	,	,	PUNCT
iajs-3313	156	5	they	they	PRON
iajs-3313	156	6	extend	extend	VERB
iajs-3313	156	7	their	their	PRON
iajs-3313	156	8	heartfelt	heartfelt	ADJ
iajs-3313	156	9	appreciation	appreciation	NOUN
iajs-3313	156	10	to	to	PART
iajs-3313	156	11	basima	basima	VERB
iajs-3313	156	12	muhsen	muhsen	NOUN
iajs-3313	156	13	sarhan	sarhan	ADV
iajs-3313	156	14	and	and	CCONJ
iajs-3313	156	15	vishwa	vishwa	PROPN
iajs-3313	156	16	deepak	deepak	PROPN
iajs-3313	156	17	tripathi	tripathi	PROPN
iajs-3313	156	18	for	for	ADP
iajs-3313	156	19	their	their	PRON
iajs-3313	156	20	invaluable	invaluable	ADJ
iajs-3313	156	21	guidance	guidance	NOUN
iajs-3313	156	22	,	,	PUNCT
iajs-3313	156	23	encouragement	encouragement	NOUN
iajs-3313	156	24	,	,	PUNCT
iajs-3313	156	25	and	and	CCONJ
iajs-3313	156	26	expertise	expertise	NOUN
iajs-3313	156	27	throughout	throughout	ADP
iajs-3313	156	28	this	this	DET
iajs-3313	156	29	research	research	NOUN
iajs-3313	156	30	.	.	PUNCT
iajs-3313	157	1	their	their	PRON
iajs-3313	157	2	insightful	insightful	ADJ
iajs-3313	157	3	feedback	feedback	NOUN
iajs-3313	157	4	and	and	CCONJ
iajs-3313	157	5	unwavering	unwavere	VERB
iajs-3313	157	6	support	support	NOUN
iajs-3313	157	7	were	be	AUX
iajs-3313	157	8	instrumental	instrumental	ADJ
iajs-3313	157	9	in	in	ADP
iajs-3313	157	10	shaping	shape	VERB
iajs-3313	157	11	the	the	DET
iajs-3313	157	12	direction	direction	NOUN
iajs-3313	157	13	of	of	ADP
iajs-3313	157	14	this	this	DET
iajs-3313	157	15	work	work	NOUN
iajs-3313	157	16	.	.	PUNCT
iajs-3313	158	1	they	they	PRON
iajs-3313	158	2	also	also	ADV
iajs-3313	158	3	thank	thank	VERB
iajs-3313	158	4	their	their	PRON
iajs-3313	158	5	colleagues	colleague	NOUN
iajs-3313	158	6	and	and	CCONJ
iajs-3313	158	7	collaborators	collaborator	NOUN
iajs-3313	158	8	for	for	ADP
iajs-3313	158	9	their	their	PRON
iajs-3313	158	10	assistance	assistance	NOUN
iajs-3313	158	11	and	and	CCONJ
iajs-3313	158	12	valuable	valuable	ADJ
iajs-3313	158	13	discussions	discussion	NOUN
iajs-3313	158	14	,	,	PUNCT
iajs-3313	158	15	which	which	PRON
iajs-3313	158	16	significantly	significantly	ADV
iajs-3313	158	17	contributed	contribute	VERB
iajs-3313	158	18	to	to	ADP
iajs-3313	158	19	the	the	DET
iajs-3313	158	20	development	development	NOUN
iajs-3313	158	21	and	and	CCONJ
iajs-3313	158	22	refinement	refinement	NOUN
iajs-3313	158	23	of	of	ADP
iajs-3313	158	24	their	their	PRON
iajs-3313	158	25	ideas	idea	NOUN
iajs-3313	158	26	.	.	PUNCT
iajs-3313	159	1	lastly	lastly	ADV
iajs-3313	159	2	,	,	PUNCT
iajs-3313	159	3	the	the	DET
iajs-3313	159	4	authors	author	NOUN
iajs-3313	159	5	would	would	AUX
iajs-3313	159	6	like	like	VERB
iajs-3313	159	7	to	to	PART
iajs-3313	159	8	acknowledge	acknowledge	VERB
iajs-3313	159	9	the	the	DET
iajs-3313	159	10	anonymous	anonymous	ADJ
iajs-3313	159	11	reviewers	reviewer	NOUN
iajs-3313	159	12	,	,	PUNCT
iajs-3313	159	13	whose	whose	DET
iajs-3313	159	14	constructive	constructive	ADJ
iajs-3313	159	15	feedback	feedback	NOUN
iajs-3313	159	16	and	and	CCONJ
iajs-3313	159	17	suggestions	suggestion	NOUN
iajs-3313	159	18	helped	help	VERB
iajs-3313	159	19	strengthen	strengthen	VERB
iajs-3313	159	20	the	the	DET
iajs-3313	159	21	manuscript	manuscript	NOUN
iajs-3313	159	22	.	.	PUNCT
iajs-3313	160	1	conflict	conflict	NOUN
iajs-3313	160	2	of	of	ADP
iajs-3313	160	3	interest	interest	NOUN
iajs-3313	160	4	the	the	DET
iajs-3313	160	5	authors	author	NOUN
iajs-3313	160	6	declare	declare	VERB
iajs-3313	160	7	that	that	SCONJ
iajs-3313	160	8	they	they	PRON
iajs-3313	160	9	have	have	VERB
iajs-3313	160	10	no	no	DET
iajs-3313	160	11	conflicts	conflict	NOUN
iajs-3313	160	12	of	of	ADP
iajs-3313	160	13	interest	interest	NOUN
iajs-3313	160	14	.	.	PUNCT
iajs-3313	161	1	funding	funding	NOUN
iajs-3313	161	2	there	there	PRON
iajs-3313	161	3	is	be	VERB
iajs-3313	161	4	no	no	DET
iajs-3313	161	5	financial	financial	ADJ
iajs-3313	161	6	support	support	NOUN
iajs-3313	161	7	.	.	PUNCT
iajs-3313	162	1	ethical	ethical	ADJ
iajs-3313	162	2	clearance	clearance	NOUN
iajs-3313	162	3	this	this	DET
iajs-3313	162	4	work	work	NOUN
iajs-3313	162	5	has	have	AUX
iajs-3313	162	6	been	be	AUX
iajs-3313	162	7	approved	approve	VERB
iajs-3313	162	8	by	by	ADP
iajs-3313	162	9	the	the	DET
iajs-3313	162	10	scientific	scientific	ADJ
iajs-3313	162	11	committee	committee	NOUN
iajs-3313	162	12	at	at	ADP
iajs-3313	162	13	the	the	DET
iajs-3313	162	14	university	university	NOUN
iajs-3313	162	15	of	of	ADP
iajs-3313	162	16	baghdad/	baghdad/	NUM
iajs-3313	162	17	college	college	NOUN
iajs-3313	162	18	of	of	ADP
iajs-3313	162	19	education	education	NOUN
iajs-3313	162	20	for	for	ADP
iajs-3313	162	21	pure	pure	ADJ
iajs-3313	162	22	science	science	NOUN
iajs-3313	162	23	(	(	PUNCT
iajs-3313	162	24	ibn	ibn	PROPN
iajs-3313	162	25	al	al	PROPN
iajs-3313	162	26	-	-	PUNCT
iajs-3313	162	27	haiham	haiham	PROPN
iajs-3313	162	28	)	)	PUNCT
iajs-3313	162	29	.	.	PUNCT
iajs-3313	163	1	references	reference	NOUN
iajs-3313	163	2	1	1	NUM
iajs-3313	163	3	.	.	PUNCT
iajs-3313	164	1	berg	berg	PROPN
iajs-3313	164	2	,	,	PUNCT
iajs-3313	164	3	j.m	j.m	PROPN
iajs-3313	164	4	.	.	PROPN
iajs-3313	164	5	principles	principle	NOUN
iajs-3313	164	6	of	of	ADP
iajs-3313	164	7	bioinorganic	bioinorganic	ADJ
iajs-3313	164	8	chemistry	chemistry	NOUN
iajs-3313	164	9	,	,	PUNCT
iajs-3313	164	10	university	university	NOUN
iajs-3313	164	11	science	science	NOUN
iajs-3313	164	12	books	book	NOUN
iajs-3313	164	13	,	,	PUNCT
iajs-3313	164	14	mill	mill	NOUN
iajs-3313	164	15	valley	valley	NOUN
iajs-3313	164	16	,	,	PUNCT
iajs-3313	164	17	california	california	PROPN
iajs-3313	164	18	,	,	PUNCT
iajs-3313	164	19	1994	1994	NUM
iajs-3313	164	20	;	;	PUNCT
iajs-3313	164	21	pp	pp	X
iajs-3313	164	22	.	.	PUNCT
iajs-3313	165	1	1–6	1–6	X
iajs-3313	165	2	.	.	PUNCT
iajs-3313	165	3	https://iubmb.onlinelibrary.wiley.com/doi/pdf/10.1016/0307-4412%2895%2990685-1	https://iubmb.onlinelibrary.wiley.com/doi/pdf/10.1016/0307-4412%2895%2990685-1	PROPN
iajs-3313	165	4	2	2	NUM
iajs-3313	165	5	.	.	PUNCT
iajs-3313	165	6	li	li	PROPN
iajs-3313	165	7	,	,	PUNCT
iajs-3313	165	8	c.	c.	PROPN
iajs-3313	165	9	;	;	PUNCT
iajs-3313	165	10	krautler	krautler	PROPN
iajs-3313	165	11	,	,	PUNCT
iajs-3313	165	12	b.	b.	PROPN
iajs-3313	165	13	transition	transition	NOUN
iajs-3313	165	14	metal	metal	NOUN
iajs-3313	165	15	complexes	complex	NOUN
iajs-3313	165	16	of	of	ADP
iajs-3313	165	17	phyllobilinsa	phyllobilinsa	ADJ
iajs-3313	165	18	new	new	ADJ
iajs-3313	165	19	realm	realm	NOUN
iajs-3313	165	20	of	of	ADP
iajs-3313	165	21	bioinorganic	bioinorganic	ADJ
iajs-3313	165	22	chemistry	chemistry	NOUN
iajs-3313	165	23	.	.	PUNCT
iajs-3313	166	1	dalt	dalt	NOUN
iajs-3313	166	2	trans	tran	NOUN
iajs-3313	166	3	2015	2015	NUM
iajs-3313	166	4	,	,	PUNCT
iajs-3313	166	5	44(22),10116–10127	44(22),10116–10127	NUM
iajs-3313	166	6	.	.	PUNCT
iajs-3313	167	1	https://doi	https://doi	ADJ
iajs-3313	167	2	:	:	PUNCT
iajs-3313	167	3	10.1039	10.1039	NUM
iajs-3313	167	4	/	/	SYM
iajs-3313	167	5	c5dt00474h	c5dt00474h	PROPN
iajs-3313	167	6	.	.	PROPN
iajs-3313	168	1	3	3	X
iajs-3313	168	2	.	.	X
iajs-3313	168	3	bagchi	bagchi	PROPN
iajs-3313	168	4	,	,	PUNCT
iajs-3313	168	5	a.n	a.n	PROPN
iajs-3313	168	6	.	.	PROPN
iajs-3313	168	7	;	;	PUNCT
iajs-3313	168	8	mukherjee	mukherjee	PROPN
iajs-3313	168	9	,	,	PUNCT
iajs-3313	168	10	p.r	p.r	PROPN
iajs-3313	168	11	.	.	PROPN
iajs-3313	168	12	;	;	PUNCT
iajs-3313	168	13	raha	raha	PROPN
iajs-3313	168	14	,	,	PUNCT
iajs-3313	168	15	a.n	a.n	PROPN
iajs-3313	168	16	.	.	PROPN
iajs-3313	169	1	a	a	DET
iajs-3313	169	2	review	review	NOUN
iajs-3313	169	3	on	on	ADP
iajs-3313	169	4	transition	transition	NOUN
iajs-3313	169	5	metal	metal	NOUN
iajs-3313	169	6	complex	complex	ADJ
iajs-3313	169	7	-	-	PUNCT
iajs-3313	169	8	mordern	mordern	ADJ
iajs-3313	169	9	weapon	weapon	NOUN
iajs-3313	169	10	in	in	ADP
iajs-3313	169	11	medicine	medicine	NOUN
iajs-3313	169	12	.	.	PUNCT
iajs-3313	170	1	int	int	NOUN
iajs-3313	170	2	j	j	PROPN
iajs-3313	170	3	recent	recent	ADJ
iajs-3313	170	4	adv	adv	PROPN
iajs-3313	170	5	pharm	pharm	NOUN
iajs-3313	170	6	res	re	NOUN
iajs-3313	170	7	2015	2015	NUM
iajs-3313	170	8	,	,	PUNCT
iajs-3313	170	9	5,171	5,171	NUM
iajs-3313	170	10	-	-	SYM
iajs-3313	170	11	180	180	NUM
iajs-3313	170	12	.	.	NOUN
iajs-3313	170	13	4	4	NUM
iajs-3313	170	14	.	.	X
iajs-3313	170	15	hunsaker	hunsaker	PROPN
iajs-3313	170	16	,	,	PUNCT
iajs-3313	170	17	e.w	e.w	PROPN
iajs-3313	170	18	.	.	PROPN
iajs-3313	170	19	;	;	PUNCT
iajs-3313	170	20	franz	franz	PROPN
iajs-3313	170	21	,	,	PUNCT
iajs-3313	170	22	k.j	k.j	PROPN
iajs-3313	170	23	.	.	PUNCT
iajs-3313	171	1	emerging	emerge	VERB
iajs-3313	171	2	opportunities	opportunity	NOUN
iajs-3313	171	3	to	to	PART
iajs-3313	171	4	manipulate	manipulate	VERB
iajs-3313	171	5	metal	metal	NOUN
iajs-3313	171	6	trafficking	trafficking	NOUN
iajs-3313	171	7	for	for	ADP
iajs-3313	171	8	therapeutic	therapeutic	ADJ
iajs-3313	171	9	benefit	benefit	NOUN
iajs-3313	171	10	.	.	PUNCT
iajs-3313	172	1	inorg	inorg	PROPN
iajs-3313	172	2	chem	chem	NOUN
iajs-3313	172	3	2019	2019	NUM
iajs-3313	172	4	,	,	PUNCT
iajs-3313	172	5	58(20),13528–13545	58(20),13528–13545	NUM
iajs-3313	172	6	.	.	PUNCT
iajs-3313	173	1	https://doi.org/10.1021/acs.inorgchem.9b01029	https://doi.org/10.1021/acs.inorgchem.9b01029	NOUN
iajs-3313	173	2	.	.	PUNCT
iajs-3313	174	1	5	5	X
iajs-3313	174	2	.	.	X
iajs-3313	174	3	spencer	spencer	PROPN
iajs-3313	174	4	,	,	PUNCT
iajs-3313	174	5	j.	j.	PROPN
iajs-3313	174	6	;	;	PUNCT
iajs-3313	174	7	read	read	VERB
iajs-3313	174	8	,	,	PUNCT
iajs-3313	174	9	j.	j.	PROPN
iajs-3313	174	10	;	;	PUNCT
iajs-3313	174	11	sessions	session	NOUN
iajs-3313	174	12	,	,	PUNCT
iajs-3313	174	13	r.b	r.b	PROPN
iajs-3313	174	14	.	.	PROPN
iajs-3313	174	15	;	;	PUNCT
iajs-3313	175	1	howell	howell	PROPN
iajs-3313	175	2	,	,	PUNCT
iajs-3313	175	3	s.	s.	PROPN
iajs-3313	175	4	;	;	PUNCT
iajs-3313	175	5	blackburn	blackburn	PROPN
iajs-3313	175	6	,	,	PUNCT
iajs-3313	175	7	g.m.;gamblin	g.m.;gamblin	PROPN
iajs-3313	175	8	,	,	PUNCT
iajs-3313	175	9	s.j	s.j	PROPN
iajs-3313	175	10	.	.	PROPN
iajs-3313	175	11	antibiotic	antibiotic	ADJ
iajs-3313	175	12	recognition	recognition	NOUN
iajs-3313	175	13	by	by	ADP
iajs-3313	175	14	binuclear	binuclear	NOUN
iajs-3313	175	15	metallo	metallo	PROPN
iajs-3313	175	16	-	-	PUNCT
iajs-3313	175	17	β	β	NOUN
iajs-3313	175	18	-	-	PUNCT
iajs-3313	175	19	lactamases	lactamase	NOUN
iajs-3313	175	20	revealed	reveal	VERB
iajs-3313	175	21	by	by	ADP
iajs-3313	175	22	x	x	NOUN
iajs-3313	175	23	-	-	NOUN
iajs-3313	175	24	ray	ray	NOUN
iajs-3313	175	25	crystallography	crystallography	NOUN
iajs-3313	175	26	.	.	PUNCT
iajs-3313	176	1	j	j	PROPN
iajs-3313	176	2	am	be	AUX
iajs-3313	176	3	chem	chem	NOUN
iajs-3313	176	4	soc	soc	NOUN
iajs-3313	176	5	2005	2005	NUM
iajs-3313	176	6	,	,	PUNCT
iajs-3313	176	7	127(41),14439–14444	127(41),14439–14444	NOUN
iajs-3313	176	8	.	.	PUNCT
iajs-3313	177	1	https://doi.org/10.1021/ja0536062	https://doi.org/10.1021/ja0536062	X
iajs-3313	177	2	.	.	PUNCT
iajs-3313	178	1	6	6	NUM
iajs-3313	178	2	.	.	X
iajs-3313	178	3	andreini	andreini	PROPN
iajs-3313	178	4	,	,	PUNCT
iajs-3313	178	5	c.;bertini	c.;bertini	PROPN
iajs-3313	178	6	,	,	PUNCT
iajs-3313	178	7	i.;cavallaro	i.;cavallaro	NOUN
iajs-3313	178	8	,	,	PUNCT
iajs-3313	178	9	g.	g.	PROPN
iajs-3313	178	10	;	;	PUNCT
iajs-3313	178	11	holliday	holliday	PROPN
iajs-3313	178	12	,	,	PUNCT
iajs-3313	178	13	g.l	g.l	PROPN
iajs-3313	178	14	.	.	PROPN
iajs-3313	178	15	;	;	PUNCT
iajs-3313	178	16	thornton	thornton	PROPN
iajs-3313	178	17	,	,	PUNCT
iajs-3313	178	18	j.m.metal	j.m.metal	ADJ
iajs-3313	178	19	ions	ion	NOUN
iajs-3313	178	20	in	in	ADP
iajs-3313	178	21	biological	biological	ADJ
iajs-3313	178	22	catalysis	catalysis	NOUN
iajs-3313	178	23	from	from	ADP
iajs-3313	178	24	enzyme	enzyme	NOUN
iajs-3313	178	25	databases	database	NOUN
iajs-3313	178	26	to	to	ADP
iajs-3313	178	27	general	general	ADJ
iajs-3313	178	28	principles	principle	NOUN
iajs-3313	178	29	.	.	PUNCT
iajs-3313	179	1	j	j	PROPN
iajs-3313	179	2	biol	biol	PROPN
iajs-3313	179	3	inorg	inorg	PROPN
iajs-3313	179	4	chem	chem	NOUN
iajs-3313	179	5	2008	2008	NUM
iajs-3313	179	6	,	,	PUNCT
iajs-3313	179	7	13(8),1205–1218	13(8),1205–1218	NUM
iajs-3313	179	8	.	.	PUNCT
iajs-3313	180	1	https://iubmb.onlinelibrary.wiley.com/doi/pdf/10.1016/0307-4412%2895%2990685-1	https://iubmb.onlinelibrary.wiley.com/doi/pdf/10.1016/0307-4412%2895%2990685-1	AUX
iajs-3313	181	1	https://doi.org/10.1039/c5dt00474h	https://doi.org/10.1039/c5dt00474h	PROPN
iajs-3313	181	2	https://doi.org/10.1021/acs.inorgchem.9b01029	https://doi.org/10.1021/acs.inorgchem.9b01029	PROPN
iajs-3313	181	3	https://doi.org/10.1021/ja0536062	https://doi.org/10.1021/ja0536062	PRON
iajs-3313	181	4	ihjpas	ihjpa	VERB
iajs-3313	181	5	.	.	PUNCT
iajs-3313	182	1	37	37	NUM
iajs-3313	182	2	(	(	PUNCT
iajs-3313	182	3	2	2	NUM
iajs-3313	182	4	)	)	PUNCT
iajs-3313	182	5	2024	2024	NUM
iajs-3313	182	6	295	295	NUM
iajs-3313	182	7	https://link.springer.com/article/10.1007/s00775-008-0404-5#article-info	https://link.springer.com/article/10.1007/s00775-008-0404-5#article-info	NOUN
iajs-3313	182	8	.	.	PUNCT
iajs-3313	183	1	7	7	X
iajs-3313	183	2	.	.	X
iajs-3313	183	3	tanaka	tanaka	PROPN
iajs-3313	183	4	,	,	PUNCT
iajs-3313	183	5	y.	y.	PROPN
iajs-3313	183	6	;	;	PUNCT
iajs-3313	183	7	nakagawa	nakagawa	PROPN
iajs-3313	183	8	,	,	PUNCT
iajs-3313	183	9	n.	n.	NOUN
iajs-3313	183	10	;	;	PUNCT
iajs-3313	183	11	kuramitsu	kuramitsu	PROPN
iajs-3313	183	12	,	,	PUNCT
iajs-3313	183	13	s.;yokoyama	s.;yokoyama	PROPN
iajs-3313	183	14	,	,	PUNCT
iajs-3313	183	15	s.	s.	PROPN
iajs-3313	183	16	;	;	PUNCT
iajs-3313	183	17	masui	masui	NOUN
iajs-3313	183	18	,	,	PUNCT
iajs-3313	183	19	r.	r.	PROPN
iajs-3313	183	20	novel	novel	PROPN
iajs-3313	183	21	reaction	reaction	NOUN
iajs-3313	183	22	mechanism	mechanism	NOUN
iajs-3313	183	23	of	of	ADP
iajs-3313	183	24	gtp	gtp	PROPN
iajs-3313	183	25	cyclohydrolase	cyclohydrolase	PROPN
iajs-3313	183	26	i.	i.	PROPN
iajs-3313	183	27	high	high	ADJ
iajs-3313	183	28	-	-	PUNCT
iajs-3313	183	29	resolution	resolution	NOUN
iajs-3313	183	30	x	x	NOUN
iajs-3313	183	31	-	-	NOUN
iajs-3313	183	32	ray	ray	NOUN
iajs-3313	183	33	crystallography	crystallography	NOUN
iajs-3313	183	34	of	of	ADP
iajs-3313	183	35	thermus	thermus	PROPN
iajs-3313	183	36	thermophilus	thermophilus	PROPN
iajs-3313	183	37	hb8	hb8	NOUN
iajs-3313	183	38	enzyme	enzyme	NOUN
iajs-3313	183	39	complexed	complexe	VERB
iajs-3313	183	40	with	with	ADP
iajs-3313	183	41	a	a	DET
iajs-3313	183	42	transition	transition	NOUN
iajs-3313	183	43	state	state	NOUN
iajs-3313	183	44	analogue	analogue	NOUN
iajs-3313	183	45	,	,	PUNCT
iajs-3313	183	46	the	the	DET
iajs-3313	183	47	8	8	NUM
iajs-3313	183	48	-	-	PUNCT
iajs-3313	183	49	oxoguanine	oxoguanine	NOUN
iajs-3313	183	50	derivative	derivative	NOUN
iajs-3313	183	51	.	.	PUNCT
iajs-3313	184	1	j	j	PROPN
iajs-3313	184	2	biochem	biochem	PROPN
iajs-3313	184	3	2005	2005	NUM
iajs-3313	184	4	,	,	PUNCT
iajs-3313	184	5	138(3	138(3	NUM
iajs-3313	184	6	)	)	PUNCT
iajs-3313	184	7	,	,	PUNCT
iajs-3313	184	8	263–275	263–275	NUM
iajs-3313	184	9	.	.	PUNCT
iajs-3313	185	1	https://doi.org/10.1093/jb/mvi120	https://doi.org/10.1093/jb/mvi120	ADJ
iajs-3313	185	2	.	.	NOUN
iajs-3313	186	1	8	8	NUM
iajs-3313	186	2	.	.	X
iajs-3313	187	1	orts	ort	NOUN
iajs-3313	187	2	-	-	PUNCT
iajs-3313	187	3	arroyo	arroyo	NOUN
iajs-3313	187	4	,	,	PUNCT
iajs-3313	187	5	m.	m.	NOUN
iajs-3313	187	6	;	;	PUNCT
iajs-3313	187	7	gutiérrez	gutiérrez	PROPN
iajs-3313	187	8	,	,	PUNCT
iajs-3313	187	9	f.	f.	PROPN
iajs-3313	187	10	;	;	PUNCT
iajs-3313	187	11	gil	gil	PROPN
iajs-3313	187	12	-	-	PUNCT
iajs-3313	187	13	tebar	tebar	PROPN
iajs-3313	187	14	,	,	PUNCT
iajs-3313	187	15	a.	a.	NOUN
iajs-3313	187	16	;	;	PUNCT
iajs-3313	187	17	ibarrola	ibarrola	NOUN
iajs-3313	187	18	-	-	PUNCT
iajs-3313	187	19	villava	villava	NOUN
iajs-3313	187	20	,	,	PUNCT
iajs-3313	187	21	m.	m.	NOUN
iajs-3313	187	22	;	;	PUNCT
iajs-3313	187	23	jiménez	jiménez	NOUN
iajs-3313	187	24	-	-	PUNCT
iajs-3313	187	25	martí	martí	PROPN
iajs-3313	187	26	,	,	PUNCT
iajs-3313	187	27	e.	e.	PROPN
iajs-3313	187	28	;	;	PUNCT
iajs-3313	187	29	silvestrellora	silvestrellora	PROPN
iajs-3313	187	30	,	,	PUNCT
iajs-3313	187	31	a.	a.	NOUN
iajs-3313	187	32	;	;	PUNCT
iajs-3313	187	33	castro	castro	PROPN
iajs-3313	187	34	,	,	PUNCT
iajs-3313	187	35	i.	i.	PROPN
iajs-3313	187	36	;	;	PUNCT
iajs-3313	187	37	ribas	ribas	PROPN
iajs-3313	187	38	,	,	PUNCT
iajs-3313	187	39	g.	g.	PROPN
iajs-3313	187	40	;	;	PUNCT
iajs-3313	187	41	martínez	martínez	PROPN
iajs-3313	187	42	-	-	PUNCT
iajs-3313	187	43	lillo	lillo	PROPN
iajs-3313	187	44	,	,	PUNCT
iajs-3313	187	45	j.	j.	PROPN
iajs-3313	187	46	a	a	DET
iajs-3313	187	47	novel	novel	ADJ
iajs-3313	187	48	adenine	adenine	NOUN
iajs-3313	187	49	-	-	PUNCT
iajs-3313	187	50	based	base	VERB
iajs-3313	187	51	diruthenium	diruthenium	NOUN
iajs-3313	187	52	(	(	PUNCT
iajs-3313	187	53	iii	iii	NOUN
iajs-3313	187	54	)	)	PUNCT
iajs-3313	187	55	complex	complex	ADJ
iajs-3313	187	56	synthesis	synthesis	NOUN
iajs-3313	187	57	,	,	PUNCT
iajs-3313	187	58	crystal	crystal	NOUN
iajs-3313	187	59	structure	structure	NOUN
iajs-3313	187	60	,	,	PUNCT
iajs-3313	187	61	electrochemical	electrochemical	ADJ
iajs-3313	187	62	properties	property	NOUN
iajs-3313	187	63	and	and	CCONJ
iajs-3313	187	64	evaluation	evaluation	NOUN
iajs-3313	187	65	of	of	ADP
iajs-3313	187	66	the	the	DET
iajs-3313	187	67	anticancer	anticancer	NOUN
iajs-3313	187	68	activity	activity	NOUN
iajs-3313	187	69	.	.	PUNCT
iajs-3313	188	1	journal	journal	PROPN
iajs-3313	188	2	of	of	ADP
iajs-3313	188	3	inorganic	inorganic	ADJ
iajs-3313	188	4	biochemistry	biochemistry	NOUN
iajs-3313	188	5	2022	2022	NUM
iajs-3313	188	6	,	,	PUNCT
iajs-3313	188	7	1(232),111812	1(232),111812	NUM
iajs-3313	188	8	.	.	PUNCT
iajs-3313	189	1	https://doi.org/10.1093/jb/mvi120	https://doi.org/10.1093/jb/mvi120	ADJ
iajs-3313	189	2	.	.	NOUN
iajs-3313	190	1	9	9	NUM
iajs-3313	190	2	.	.	X
iajs-3313	190	3	li	li	PROPN
iajs-3313	190	4	,	,	PUNCT
iajs-3313	190	5	y.	y.	PROPN
iajs-3313	190	6	;	;	PUNCT
iajs-3313	190	7	dong	dong	PROPN
iajs-3313	190	8	,	,	PUNCT
iajs-3313	190	9	j.	j.	PROPN
iajs-3313	190	10	;	;	PUNCT
iajs-3313	190	11	zhao	zhao	X
iajs-3313	190	12	,	,	PUNCT
iajs-3313	190	13	p.;hu	p.;hu	ADV
iajs-3313	190	14	,	,	PUNCT
iajs-3313	190	15	p.	p.	PROPN
iajs-3313	190	16	;	;	PUNCT
iajs-3313	191	1	yang	yang	PROPN
iajs-3313	191	2	,	,	PUNCT
iajs-3313	191	3	d.	d.	PROPN
iajs-3313	191	4	;	;	PUNCT
iajs-3313	191	5	gao	gao	PROPN
iajs-3313	191	6	,	,	PUNCT
iajs-3313	191	7	l.	l.	PROPN
iajs-3313	191	8	;	;	PUNCT
iajs-3313	191	9	li	li	PROPN
iajs-3313	191	10	,	,	PUNCT
iajs-3313	191	11	l.	l.	NOUN
iajs-3313	191	12	synthesis	synthesis	NOUN
iajs-3313	191	13	of	of	ADP
iajs-3313	191	14	amino	amino	NOUN
iajs-3313	191	15	acid	acid	NOUN
iajs-3313	191	16	schiff	schiff	NOUN
iajs-3313	191	17	base	base	NOUN
iajs-3313	191	18	nickel	nickel	NOUN
iajs-3313	191	19	(	(	PUNCT
iajs-3313	191	20	ii	ii	NOUN
iajs-3313	191	21	)	)	PUNCT
iajs-3313	191	22	complexes	complex	NOUN
iajs-3313	191	23	as	as	ADP
iajs-3313	191	24	potential	potential	ADJ
iajs-3313	191	25	anticancer	anticancer	NOUN
iajs-3313	191	26	drugs	drug	NOUN
iajs-3313	191	27	in	in	ADP
iajs-3313	191	28	vitro	vitro	X
iajs-3313	191	29	.	.	PUNCT
iajs-3313	192	1	bioinorg	bioinorg	PROPN
iajs-3313	192	2	chem	chem	NOUN
iajs-3313	192	3	appl	appl	NOUN
iajs-3313	192	4	2020	2020	NUM
iajs-3313	192	5	,	,	PUNCT
iajs-3313	192	6	2020	2020	NUM
iajs-3313	192	7	,	,	PUNCT
iajs-3313	192	8	8834859	8834859	NUM
iajs-3313	192	9	.	.	PUNCT
iajs-3313	193	1	https://doi	https://doi	ADJ
iajs-3313	193	2	:	:	PUNCT
iajs-3313	193	3	10.1155/2020/8834859	10.1155/2020/8834859	NUM
iajs-3313	193	4	.	.	NOUN
iajs-3313	193	5	10	10	NUM
iajs-3313	193	6	.	.	PUNCT
iajs-3313	194	1	szymańska	szymańska	ADJ
iajs-3313	194	2	,	,	PUNCT
iajs-3313	194	3	m.	m.	NOUN
iajs-3313	194	4	;	;	PUNCT
iajs-3313	194	5	pospieszna	pospieszna	VERB
iajs-3313	194	6	-	-	PUNCT
iajs-3313	194	7	markiewicz	markiewicz	NOUN
iajs-3313	194	8	,	,	PUNCT
iajs-3313	194	9	i.	i.	NOUN
iajs-3313	194	10	;	;	PUNCT
iajs-3313	194	11	mańka	mańka	PROPN
iajs-3313	194	12	,	,	PUNCT
iajs-3313	194	13	m.	m.	NOUN
iajs-3313	194	14	;	;	PUNCT
iajs-3313	194	15	insińska	insińska	PROPN
iajs-3313	194	16	-	-	PUNCT
iajs-3313	194	17	rak	rak	PROPN
iajs-3313	194	18	,	,	PUNCT
iajs-3313	194	19	m.	m.	NOUN
iajs-3313	194	20	;	;	PUNCT
iajs-3313	194	21	dutkiewicz	dutkiewicz	ADJ
iajs-3313	194	22	,	,	PUNCT
iajs-3313	194	23	g.	g.	PROPN
iajs-3313	194	24	;	;	PUNCT
iajs-3313	194	25	patroniak	patroniak	PROPN
iajs-3313	194	26	,	,	PUNCT
iajs-3313	194	27	v.	v.	PROPN
iajs-3313	194	28	;	;	PUNCT
iajs-3313	194	29	fik	fik	NOUN
iajs-3313	194	30	-	-	PUNCT
iajs-3313	194	31	jaskółka	jaskółka	NOUN
iajs-3313	194	32	,	,	PUNCT
iajs-3313	194	33	m.a	m.a	PROPN
iajs-3313	194	34	.	.	PROPN
iajs-3313	194	35	synthesis	synthesis	NOUN
iajs-3313	194	36	and	and	CCONJ
iajs-3313	194	37	spectroscopic	spectroscopic	ADJ
iajs-3313	194	38	investigations	investigation	NOUN
iajs-3313	194	39	of	of	ADP
iajs-3313	194	40	schiff	schiff	PROPN
iajs-3313	194	41	base	base	PROPN
iajs-3313	194	42	ligand	ligand	NOUN
iajs-3313	194	43	and	and	CCONJ
iajs-3313	194	44	its	its	PRON
iajs-3313	194	45	bimetallic	bimetallic	ADJ
iajs-3313	194	46	ag	ag	PROPN
iajs-3313	194	47	(	(	PUNCT
iajs-3313	194	48	i	i	NOUN
iajs-3313	194	49	)	)	PUNCT
iajs-3313	194	50	complex	complex	ADJ
iajs-3313	194	51	as	as	ADP
iajs-3313	194	52	dna	dna	PROPN
iajs-3313	194	53	and	and	CCONJ
iajs-3313	194	54	bsa	bsa	PROPN
iajs-3313	194	55	binders	binder	NOUN
iajs-3313	194	56	.	.	PUNCT
iajs-3313	195	1	biomolecules	biomolecule	NOUN
iajs-3313	195	2	2021	2021	NUM
iajs-3313	195	3	,	,	PUNCT
iajs-3313	195	4	11(10),1449	11(10),1449	NOUN
iajs-3313	195	5	.	.	PUNCT
iajs-3313	196	1	https://doi.org/10.3390/biom11101449	https://doi.org/10.3390/biom11101449	PROPN
iajs-3313	196	2	.	.	PUNCT
iajs-3313	197	1	11	11	NUM
iajs-3313	197	2	.	.	X
iajs-3313	198	1	chen	chen	PROPN
iajs-3313	198	2	,	,	PUNCT
iajs-3313	198	3	c.k.j	c.k.j	PROPN
iajs-3313	198	4	.	.	PUNCT
iajs-3313	198	5	;	;	PUNCT
iajs-3313	198	6	hambley	hambley	NOUN
iajs-3313	198	7	,	,	PUNCT
iajs-3313	198	8	t.w	t.w	PROPN
iajs-3313	198	9	.	.	PROPN
iajs-3313	198	10	the	the	DET
iajs-3313	198	11	impact	impact	NOUN
iajs-3313	198	12	of	of	ADP
iajs-3313	198	13	highly	highly	ADV
iajs-3313	198	14	electron	electron	NOUN
iajs-3313	198	15	withdrawing	withdraw	VERB
iajs-3313	198	16	carboxylato	carboxylato	NOUN
iajs-3313	198	17	ligands	ligand	NOUN
iajs-3313	198	18	on	on	ADP
iajs-3313	198	19	the	the	DET
iajs-3313	198	20	stability	stability	NOUN
iajs-3313	198	21	and	and	CCONJ
iajs-3313	198	22	activity	activity	NOUN
iajs-3313	198	23	of	of	ADP
iajs-3313	198	24	platinum(iv	platinum(iv	NOUN
iajs-3313	198	25	)	)	PUNCT
iajs-3313	198	26	pro	pro	ADJ
iajs-3313	198	27	-	-	NOUN
iajs-3313	198	28	drugs	drug	NOUN
iajs-3313	198	29	.	.	PUNCT
iajs-3313	199	1	inorganica	inorganica	PROPN
iajs-3313	199	2	chim	chim	PROPN
iajs-3313	199	3	acta	acta	PROPN
iajs-3313	199	4	2019	2019	NUM
iajs-3313	199	5	,	,	PUNCT
iajs-3313	199	6	1(494),84–90	1(494),84–90	NUM
iajs-3313	199	7	.	.	PUNCT
iajs-3313	200	1	https://doi.org/10.1016/j.ica.2019.05.001	https://doi.org/10.1016/j.ica.2019.05.001	PROPN
iajs-3313	200	2	.	.	PUNCT
iajs-3313	201	1	12	12	NUM
iajs-3313	201	2	.	.	X
iajs-3313	202	1	skalnaya	skalnaya	PROPN
iajs-3313	202	2	,	,	PUNCT
iajs-3313	202	3	m.g	m.g	PROPN
iajs-3313	202	4	.	.	PROPN
iajs-3313	202	5	;	;	PUNCT
iajs-3313	202	6	skalny	skalny	PROPN
iajs-3313	202	7	,	,	PUNCT
iajs-3313	202	8	a.v	a.v	PROPN
iajs-3313	202	9	.	.	NOUN
iajs-3313	202	10	essential	essential	ADJ
iajs-3313	202	11	trace	trace	NOUN
iajs-3313	202	12	elements	element	NOUN
iajs-3313	202	13	in	in	ADP
iajs-3313	202	14	human	human	ADJ
iajs-3313	202	15	health	health	NOUN
iajs-3313	202	16	,	,	PUNCT
iajs-3313	202	17	a	a	DET
iajs-3313	202	18	physician	physician	NOUN
iajs-3313	202	19	’s	’s	PART
iajs-3313	202	20	view	view	NOUN
iajs-3313	202	21	.	.	PUNCT
iajs-3313	203	1	tomsk	tomsk	PROPN
iajs-3313	203	2	,	,	PUNCT
iajs-3313	203	3	publishing	publish	VERB
iajs-3313	203	4	house	house	PROPN
iajs-3313	203	5	of	of	ADP
iajs-3313	203	6	tomsk	tomsk	PROPN
iajs-3313	203	7	state	state	PROPN
iajs-3313	203	8	university	university	PROPN
iajs-3313	203	9	2018	2018	NUM
iajs-3313	203	10	;	;	PUNCT
iajs-3313	203	11	s66	s66	NOUN
iajs-3313	203	12	,	,	PUNCT
iajs-3313	203	13	pp	pp	ADJ
iajs-3313	203	14	.	.	PUNCT
iajs-3313	204	1	224	224	NUM
iajs-3313	204	2	.	.	PUNCT
iajs-3313	205	1	https://trace-element.org/sites/default/files/2022-02/essential-trace-elements-in-human-health-aphysician-s-view_124_fr_0.pdf	https://trace-element.org/sites/default/files/2022-02/essential-trace-elements-in-human-health-aphysician-s-view_124_fr_0.pdf	PROPN
iajs-3313	205	2	.	.	PUNCT
iajs-3313	206	1	13	13	NUM
iajs-3313	206	2	.	.	X
iajs-3313	207	1	correa	correa	PROPN
iajs-3313	207	2	,	,	PUNCT
iajs-3313	207	3	r.s	r.s	PROPN
iajs-3313	207	4	.	.	PROPN
iajs-3313	207	5	;	;	PUNCT
iajs-3313	207	6	bomfim	bomfim	NOUN
iajs-3313	207	7	,	,	PUNCT
iajs-3313	207	8	l.m	l.m	PROPN
iajs-3313	207	9	.	.	PROPN
iajs-3313	207	10	;	;	PUNCT
iajs-3313	207	11	oliveira	oliveira	PROPN
iajs-3313	207	12	,	,	PUNCT
iajs-3313	207	13	k.m	k.m	PROPN
iajs-3313	207	14	.	.	PROPN
iajs-3313	207	15	;	;	PUNCT
iajs-3313	207	16	moreira	moreira	PROPN
iajs-3313	207	17	,	,	PUNCT
iajs-3313	207	18	d.r.m	d.r.m	PROPN
iajs-3313	207	19	.	.	PUNCT
iajs-3313	207	20	;	;	PUNCT
iajs-3313	207	21	soares	soare	NOUN
iajs-3313	207	22	,	,	PUNCT
iajs-3313	207	23	m.b.p	m.b.p	PROPN
iajs-3313	207	24	.	.	PROPN
iajs-3313	207	25	;	;	PUNCT
iajs-3313	207	26	ellena	ellena	PROPN
iajs-3313	207	27	,	,	PUNCT
iajs-3313	207	28	j.	j.	PROPN
iajs-3313	207	29	;	;	PUNCT
iajs-3313	207	30	daniel	daniel	PROPN
iajs-3313	207	31	,	,	PUNCT
iajs-3313	207	32	p.	p.	PROPN
iajs-3313	207	33	;	;	PUNCT
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iajs-3313	207	35	,	,	PUNCT
iajs-3313	207	36	a.a.b	a.a.b	PROPN
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iajs-3313	207	38	ru(ii	ru(ii	NOUN
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iajs-3313	207	40	complexes	complex	NOUN
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iajs-3313	207	42	uracil	uracil	ADJ
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iajs-3313	207	44	analogs	analog	NOUN
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iajs-3313	207	46	cytotoxicity	cytotoxicity	NOUN
iajs-3313	207	47	against	against	ADP
iajs-3313	207	48	tumor	tumor	NOUN
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iajs-3313	207	50	.	.	PUNCT
iajs-3313	208	1	j	j	PROPN
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iajs-3313	208	5	,	,	PUNCT
iajs-3313	208	6	198(2),110751	198(2),110751	PROPN
iajs-3313	208	7	.	.	PUNCT
iajs-3313	208	8	https://en.trace-element.org/sites/default/files/2022-02/essential-trace-elements-in-human-health-aphysician-s-view_124_fr_0.pdf	https://en.trace-element.org/sites/default/files/2022-02/essential-trace-elements-in-human-health-aphysician-s-view_124_fr_0.pdf	PROPN
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iajs-3313	209	2	.	.	PUNCT
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iajs-3313	210	2	,	,	PUNCT
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iajs-3313	210	4	;	;	PUNCT
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iajs-3313	210	12	of	of	ADP
iajs-3313	210	13	guanine	guanine	NOUN
iajs-3313	210	14	scaffold	scaffold	NOUN
iajs-3313	210	15	in	in	ADP
iajs-3313	210	16	anticancer	anticancer	NOUN
iajs-3313	210	17	drug	drug	NOUN
iajs-3313	210	18	development	development	NOUN
iajs-3313	210	19	by	by	ADP
iajs-3313	210	20	computational	computational	ADJ
iajs-3313	210	21	repurposing	repurposing	NOUN
iajs-3313	210	22	approach	approach	NOUN
iajs-3313	210	23	.	.	PUNCT
iajs-3313	211	1	sci	sci	PROPN
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iajs-3313	211	4	,	,	PUNCT
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iajs-3313	211	6	-	-	SYM
iajs-3313	211	7	11	11	NUM
iajs-3313	211	8	.	.	PUNCT
iajs-3313	212	1	https://doi:10.1038	https://doi:10.1038	PROPN
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iajs-3313	212	4	-	-	PUNCT
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iajs-3313	212	6	-	-	PUNCT
iajs-3313	212	7	95507	95507	NUM
iajs-3313	212	8	-	-	PUNCT
iajs-3313	212	9	4	4	NUM
iajs-3313	212	10	.	.	NOUN
iajs-3313	212	11	15	15	NUM
iajs-3313	212	12	.	.	PUNCT
iajs-3313	213	1	marotta	marotta	PROPN
iajs-3313	213	2	,	,	PUNCT
iajs-3313	213	3	c.	c.	NOUN
iajs-3313	213	4	;	;	PUNCT
iajs-3313	213	5	giorgi	giorgi	PROPN
iajs-3313	213	6	,	,	PUNCT
iajs-3313	213	7	e.	e.	PROPN
iajs-3313	213	8	;	;	PUNCT
iajs-3313	213	9	binacchi	binacchi	PROPN
iajs-3313	213	10	,	,	PUNCT
iajs-3313	213	11	f.	f.	PROPN
iajs-3313	213	12	;	;	PUNCT
iajs-3313	213	13	cirri	cirri	PROPN
iajs-3313	213	14	,	,	PUNCT
iajs-3313	213	15	d.	d.	PROPN
iajs-3313	213	16	;	;	PUNCT
iajs-3313	213	17	gabbiani	gabbiani	PROPN
iajs-3313	213	18	,	,	PUNCT
iajs-3313	213	19	c.	c.	PROPN
iajs-3313	213	20	;	;	PUNCT
iajs-3313	213	21	pratesi	pratesi	PROPN
iajs-3313	213	22	,	,	PUNCT
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iajs-3313	213	29	in	in	ADP
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iajs-3313	213	31	pt(iv	pt(iv	PROPN
iajs-3313	213	32	)	)	PUNCT
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iajs-3313	213	35	new	new	ADJ
iajs-3313	213	36	smart	smart	ADJ
iajs-3313	213	37	drug	drug	NOUN
iajs-3313	213	38	combinations	combination	NOUN
iajs-3313	213	39	,	,	PUNCT
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iajs-3313	213	42	delivery	delivery	NOUN
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iajs-3313	213	44	.	.	PUNCT
iajs-3313	214	1	inorganica	inorganica	PROPN
iajs-3313	214	2	chim	chim	PROPN
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iajs-3313	214	5	,	,	PUNCT
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iajs-3313	214	7	-	-	SYM
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iajs-3313	214	9	.	.	PUNCT
iajs-3313	215	1	https://doi:10.1016	https://doi:10.1016	PROPN
iajs-3313	215	2	/	/	SYM
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iajs-3313	215	4	.	.	PUNCT
iajs-3313	216	1	16	16	NUM
iajs-3313	216	2	.	.	PUNCT
iajs-3313	217	1	jaber	jaber	PROPN
iajs-3313	217	2	,	,	PUNCT
iajs-3313	217	3	s.s	s.s	PROPN
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iajs-3313	217	17	complexes	complex	NOUN
iajs-3313	217	18	of	of	ADP
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iajs-3313	217	20	propionyl	propionyl	NOUN
iajs-3313	217	21	carbamothioyl	carbamothioyl	NOUN
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iajs-3313	217	23	valine	valine	NOUN
iajs-3313	217	24	(	(	PUNCT
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iajs-3313	217	27	.	.	PUNCT
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iajs-3313	218	2	j	j	PROPN
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iajs-3313	218	7	,	,	PUNCT
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iajs-3313	218	9	.	.	PUNCT
iajs-3313	218	10	https://doi.org/10.53350/pjmhs22164420	https://doi.org/10.53350/pjmhs22164420	PROPN
iajs-3313	218	11	.	.	PUNCT
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iajs-3313	219	2	.	.	X
iajs-3313	220	1	kader	kader	PROPN
iajs-3313	220	2	,	,	PUNCT
iajs-3313	220	3	t.a	t.a	PROPN
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iajs-3313	220	9	.	.	PROPN
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iajs-3313	220	18	)	)	PUNCT
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iajs-3313	220	25	.	.	PUNCT
iajs-3313	221	1	int	int	NOUN
iajs-3313	221	2	j	j	PROPN
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iajs-3313	221	6	2022	2022	NUM
iajs-3313	221	7	,	,	PUNCT
iajs-3313	221	8	6(s2),11716	6(s2),11716	NOUN
iajs-3313	221	9	–	–	PUNCT
iajs-3313	221	10	11728	11728	NUM
iajs-3313	221	11	.	.	PUNCT
iajs-3313	222	1	https://doi:10.53730	https://doi:10.53730	NOUN
iajs-3313	222	2	/	/	SYM
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iajs-3313	222	4	.	.	PUNCT
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iajs-3313	223	2	.	.	X
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iajs-3313	223	4	,	,	PUNCT
iajs-3313	223	5	t.b	t.b	PROPN
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iajs-3313	223	20	[	[	X
iajs-3313	223	21	1-(4	1-(4	NUM
iajs-3313	223	22	-	-	PUNCT
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iajs-3313	223	24	-	-	PUNCT
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iajs-3313	223	26	-	-	PUNCT
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iajs-3313	223	28	-	-	PUNCT
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iajs-3313	223	30	.	.	PUNCT
iajs-3313	224	1	j	j	PROPN
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iajs-3313	224	6	,	,	PUNCT
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iajs-3313	224	8	.	.	PUNCT
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iajs-3313	225	7	-	-	PUNCT
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iajs-3313	225	9	-	-	PUNCT
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iajs-3313	228	22	,	,	PUNCT
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iajs-3313	229	2	.	.	PUNCT
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iajs-3313	230	5	https://www.nature.com/articles/s41598-021-95507-4	https://www.nature.com/articles/s41598-021-95507-4	VERB
iajs-3313	230	6	http://dx.doi.org/10.1016/j.ica.2023.121388	http://dx.doi.org/10.1016/j.ica.2023.121388	PRON
iajs-3313	230	7	https://doi.org/10.53350/pjmhs22164420	https://doi.org/10.53350/pjmhs22164420	PROPN
iajs-3313	230	8	https://dx.doi.org/10.53730/ijhs.v6ns2.8128	https://dx.doi.org/10.53730/ijhs.v6ns2.8128	PROPN
iajs-3313	230	9	https://www.researchgate.net/publication/355486493_synthesis_and_characterization_of_some_metal_complexes_of_1-4-_bromo-2-methyl-phenyl-3-4-methoxybenzoyl-thiourea	https://www.researchgate.net/publication/355486493_synthesis_and_characterization_of_some_metal_complexes_of_1-4-_bromo-2-methyl-phenyl-3-4-methoxybenzoyl-thiourea	PROPN
iajs-3313	230	10	https://www.researchgate.net/publication/355486493_synthesis_and_characterization_of_some_metal_complexes_of_1-4-_bromo-2-methyl-phenyl-3-4-methoxybenzoyl-thiourea	https://www.researchgate.net/publication/355486493_synthesis_and_characterization_of_some_metal_complexes_of_1-4-_bromo-2-methyl-phenyl-3-4-methoxybenzoyl-thiourea	PROPN
iajs-3313	231	1	https://www.iasj.net/iasj/download/4a4ca1072da6558d	https://www.iasj.net/iasj/download/4a4ca1072da6558d	PROPN
iajs-3313	231	2	https://pubs.acs.org/action/dosearch?field1=contrib&text1=hideo++takeuchi	https://pubs.acs.org/action/dosearch?field1=contrib&text1=hideo++takeuchi	PROPN
iajs-3313	231	3	https://pubs.acs.org/action/dosearch?field1=contrib&text1=issei++harada	https://pubs.acs.org/action/dosearch?field1=contrib&text1=issei++harada	NOUN
iajs-3313	231	4	ihjpas	ihjpa	VERB
iajs-3313	231	5	.	.	PUNCT
iajs-3313	232	1	37	37	NUM
iajs-3313	232	2	(	(	PUNCT
iajs-3313	232	3	2	2	NUM
iajs-3313	232	4	)	)	PUNCT
iajs-3313	232	5	2024	2024	NUM
iajs-3313	232	6	296	296	NUM
iajs-3313	232	7	complexes	complex	NOUN
iajs-3313	232	8	of	of	ADP
iajs-3313	232	9	palladium(ii	palladium(ii	NOUN
iajs-3313	232	10	)	)	PUNCT
iajs-3313	232	11	in	in	ADP
iajs-3313	232	12	solution	solution	NOUN
iajs-3313	232	13	:	:	PUNCT
iajs-3313	232	14	pd	pd	NOUN
iajs-3313	232	15	binding	bind	VERB
iajs-3313	232	16	sites	site	NOUN
iajs-3313	232	17	of	of	ADP
iajs-3313	232	18	the	the	DET
iajs-3313	232	19	guanine	guanine	NOUN
iajs-3313	232	20	ring	ring	NOUN
iajs-3313	232	21	and	and	CCONJ
iajs-3313	232	22	formation	formation	NOUN
iajs-3313	232	23	of	of	ADP
iajs-3313	232	24	a	a	DET
iajs-3313	232	25	cyclic	cyclic	ADJ
iajs-3313	232	26	adduct	adduct	NOUN
iajs-3313	232	27	,	,	PUNCT
iajs-3313	232	28	[	[	X
iajs-3313	232	29	{	{	PUNCT
iajs-3313	232	30	pd(en	pd(en	NOUN
iajs-3313	232	31	)	)	PUNCT
iajs-3313	232	32	(	(	PUNCT
iajs-3313	232	33	guanine	guanine	NOUN
iajs-3313	232	34	ring)}4	ring)}4	PROPN
iajs-3313	232	35	]	]	PUNCT
iajs-3313	232	36	.	.	PUNCT
iajs-3313	233	1	inorg	inorg	PROPN
iajs-3313	233	2	chem	chem	NOUN
iajs-3313	233	3	1989	1989	NUM
iajs-3313	233	4	,	,	PUNCT
iajs-3313	233	5	28(11),2067–2073	28(11),2067–2073	NUM
iajs-3313	233	6	.	.	PUNCT
iajs-3313	234	1	https://doi.org/10.1021/ic00310a012	https://doi.org/10.1021/ic00310a012	PROPN
iajs-3313	234	2	.	.	PUNCT
iajs-3313	235	1	21	21	NUM
iajs-3313	235	2	.	.	PUNCT
iajs-3313	236	1	fayyadh	fayyadh	NOUN
iajs-3313	236	2	,	,	PUNCT
iajs-3313	236	3	b.m	b.m	PROPN
iajs-3313	236	4	.	.	PROPN
iajs-3313	236	5	;	;	PUNCT
iajs-3313	236	6	jaafar	jaafar	PROPN
iajs-3313	236	7	,	,	PUNCT
iajs-3313	236	8	w.a	w.a	PROPN
iajs-3313	236	9	.	.	PROPN
iajs-3313	236	10	;	;	PUNCT
iajs-3313	237	1	sarhan	sarhan	PROPN
iajs-3313	237	2	,	,	PUNCT
iajs-3313	237	3	b.m	b.m	PROPN
iajs-3313	237	4	.	.	PROPN
iajs-3313	237	5	synthesis	synthesis	NOUN
iajs-3313	237	6	,	,	PUNCT
iajs-3313	237	7	structural	structural	ADJ
iajs-3313	237	8	study	study	NOUN
iajs-3313	237	9	,	,	PUNCT
iajs-3313	237	10	and	and	CCONJ
iajs-3313	237	11	biological	biological	ADJ
iajs-3313	237	12	activity	activity	NOUN
iajs-3313	237	13	evaluation	evaluation	NOUN
iajs-3313	237	14	of	of	ADP
iajs-3313	237	15	vo(ii	vo(ii	PROPN
iajs-3313	237	16	)	)	PUNCT
iajs-3313	237	17	,	,	PUNCT
iajs-3313	237	18	mn(ii	mn(ii	PROPN
iajs-3313	237	19	)	)	PUNCT
iajs-3313	237	20	,	,	PUNCT
iajs-3313	237	21	co(ii	co(ii	PROPN
iajs-3313	237	22	)	)	PUNCT
iajs-3313	237	23	,	,	PUNCT
iajs-3313	237	24	ni(ii	ni(ii	PROPN
iajs-3313	237	25	)	)	PUNCT
iajs-3313	237	26	,	,	PUNCT
iajs-3313	237	27	cu(ii	cu(ii	PROPN
iajs-3313	237	28	)	)	PUNCT
iajs-3313	237	29	,	,	PUNCT
iajs-3313	237	30	zn(ii	zn(ii	NUM
iajs-3313	237	31	)	)	PUNCT
iajs-3313	237	32	,	,	PUNCT
iajs-3313	237	33	cd(ii	cd(ii	PROPN
iajs-3313	237	34	)	)	PUNCT
iajs-3313	237	35	,	,	PUNCT
iajs-3313	237	36	and	and	CCONJ
iajs-3313	237	37	hg(ii	hg(ii	PROPN
iajs-3313	237	38	)	)	PUNCT
iajs-3313	237	39	complexes	complex	NOUN
iajs-3313	237	40	with	with	ADP
iajs-3313	237	41	new	new	ADJ
iajs-3313	237	42	schiff	schiff	NOUN
iajs-3313	237	43	base	base	PROPN
iajs-3313	237	44	ligand	ligand	NOUN
iajs-3313	237	45	derived	derive	VERB
iajs-3313	237	46	from	from	ADP
iajs-3313	237	47	pyrazine	pyrazine	NOUN
iajs-3313	237	48	.	.	PUNCT
iajs-3313	238	1	international	international	ADJ
iajs-3313	238	2	journal	journal	PROPN
iajs-3313	238	3	of	of	ADP
iajs-3313	238	4	drug	drug	NOUN
iajs-3313	238	5	delivery	delivery	NOUN
iajs-3313	238	6	technologythis	technologythis	PROPN
iajs-3313	238	7	2021	2021	NUM
iajs-3313	238	8	,	,	PUNCT
iajs-3313	238	9	11(1),64–69	11(1),64–69	NUM
iajs-3313	238	10	.	.	PUNCT
iajs-3313	239	1	https://doi	https://doi	ADJ
iajs-3313	239	2	:	:	PUNCT
iajs-3313	239	3	10.25258	10.25258	NUM
iajs-3313	239	4	/	/	SYM
iajs-3313	239	5	ijddt.11.1.11	ijddt.11.1.11	NOUN
iajs-3313	239	6	.	.	NOUN
iajs-3313	239	7	22	22	NUM
iajs-3313	239	8	.	.	PUNCT
iajs-3313	240	1	chennakrishnan	chennakrishnan	PROPN
iajs-3313	240	2	,	,	PUNCT
iajs-3313	240	3	s.	s.	PROPN
iajs-3313	240	4	;	;	PUNCT
iajs-3313	240	5	ravi	ravi	PROPN
iajs-3313	240	6	kumar	kumar	PROPN
iajs-3313	240	7	,	,	PUNCT
iajs-3313	240	8	s.m	s.m	PROPN
iajs-3313	240	9	.	.	PROPN
iajs-3313	240	10	;	;	PUNCT
iajs-3313	240	11	shanthi	shanthi	PROPN
iajs-3313	240	12	,	,	PUNCT
iajs-3313	240	13	c.	c.	PROPN
iajs-3313	240	14	;	;	PUNCT
iajs-3313	240	15	srineevasan	srineevasan	PROPN
iajs-3313	240	16	,	,	PUNCT
iajs-3313	240	17	r.	r.	PROPN
iajs-3313	240	18	;	;	PUNCT
iajs-3313	240	19	kubendiran	kubendiran	NOUN
iajs-3313	240	20	,	,	PUNCT
iajs-3313	240	21	t.	t.	PROPN
iajs-3313	240	22	;	;	PUNCT
iajs-3313	240	23	sivavishnu	sivavishnu	PROPN
iajs-3313	240	24	,	,	PUNCT
iajs-3313	240	25	d.	d.	PROPN
iajs-3313	240	26	;	;	PUNCT
iajs-3313	240	27	packiya	packiya	PROPN
iajs-3313	240	28	raj	raj	PROPN
iajs-3313	240	29	,	,	PUNCT
iajs-3313	240	30	m.	m.	NOUN
iajs-3313	240	31	synthesis	synthesis	NOUN
iajs-3313	240	32	of	of	ADP
iajs-3313	240	33	the	the	DET
iajs-3313	240	34	semi	semi	ADJ
iajs-3313	240	35	-	-	ADJ
iajs-3313	240	36	organic	organic	ADJ
iajs-3313	240	37	nonlinear	nonlinear	ADJ
iajs-3313	240	38	optical	optical	ADJ
iajs-3313	240	39	crystal	crystal	NOUN
iajs-3313	240	40	l	l	ADJ
iajs-3313	240	41	-	-	ADJ
iajs-3313	240	42	glutamic	glutamic	ADJ
iajs-3313	240	43	acid	acid	NOUN
iajs-3313	240	44	zinc	zinc	NOUN
iajs-3313	240	45	chloride	chloride	NOUN
iajs-3313	240	46	and	and	CCONJ
iajs-3313	240	47	investigation	investigation	NOUN
iajs-3313	240	48	of	of	ADP
iajs-3313	240	49	its	its	PRON
iajs-3313	240	50	growth	growth	NOUN
iajs-3313	240	51	and	and	CCONJ
iajs-3313	240	52	physiochemical	physiochemical	ADJ
iajs-3313	240	53	properties	property	NOUN
iajs-3313	240	54	.	.	PUNCT
iajs-3313	241	1	j	j	PROPN
iajs-3313	241	2	taibah	taibah	PROPN
iajs-3313	241	3	univ	univ	PROPN
iajs-3313	241	4	sci	sci	PROPN
iajs-3313	241	5	2017	2017	NUM
iajs-3313	241	6	,	,	PUNCT
iajs-3313	241	7	11(6	11(6	NUM
iajs-3313	241	8	)	)	PUNCT
iajs-3313	241	9	,	,	PUNCT
iajs-3313	241	10	955–965	955–965	NUM
iajs-3313	241	11	.	.	PUNCT
iajs-3313	242	1	https://doi.org/10.1016/j.jtusci.2017.01.001	https://doi.org/10.1016/j.jtusci.2017.01.001	VERB
iajs-3313	242	2	.	.	PUNCT
iajs-3313	243	1	23	23	NUM
iajs-3313	243	2	.	.	X
iajs-3313	244	1	sarhan	sarhan	PROPN
iajs-3313	244	2	,	,	PUNCT
iajs-3313	244	3	b.m	b.m	PROPN
iajs-3313	244	4	.	.	PROPN
iajs-3313	244	5	;	;	PUNCT
iajs-3313	244	6	abed	abe	VERB
iajs-3313	244	7	,	,	PUNCT
iajs-3313	244	8	a.h	a.h	PROPN
iajs-3313	244	9	.	.	PROPN
iajs-3313	244	10	;	;	PUNCT
iajs-3313	244	11	rumez	rumez	PROPN
iajs-3313	244	12	,	,	PUNCT
iajs-3313	244	13	r.m	r.m	PROPN
iajs-3313	244	14	.	.	PROPN
iajs-3313	244	15	synthesis	synthesis	NOUN
iajs-3313	244	16	and	and	CCONJ
iajs-3313	244	17	characterization	characterization	NOUN
iajs-3313	244	18	of	of	ADP
iajs-3313	244	19	some	some	DET
iajs-3313	244	20	mixed	mixed	ADJ
iajs-3313	244	21	ligand	ligand	NOUN
iajs-3313	244	22	complexes	complex	NOUN
iajs-3313	244	23	containing	contain	VERB
iajs-3313	244	24	(	(	PUNCT
iajs-3313	244	25	8	8	NUM
iajs-3313	244	26	-	-	PUNCT
iajs-3313	244	27	hydroxyquinoline	hydroxyquinoline	NOUN
iajs-3313	244	28	)	)	PUNCT
iajs-3313	244	29	and	and	CCONJ
iajs-3313	244	30	(	(	PUNCT
iajs-3313	244	31	2picoline	2picoline	NUM
iajs-3313	244	32	)	)	PUNCT
iajs-3313	244	33	with	with	ADP
iajs-3313	244	34	some	some	DET
iajs-3313	244	35	metal	metal	NOUN
iajs-3313	244	36	ions	ion	NOUN
iajs-3313	244	37	.	.	PUNCT
iajs-3313	245	1	baghdad	baghdad	PROPN
iajs-3313	245	2	sci	sci	PROPN
iajs-3313	245	3	j	j	PROPN
iajs-3313	245	4	2013	2013	NUM
iajs-3313	245	5	,	,	PUNCT
iajs-3313	245	6	10(2),396–404	10(2),396–404	PROPN
iajs-3313	245	7	.	.	PUNCT
iajs-3313	246	1	https://www.iasj.net/iasj/download/f1ef85c3b330c698	https://www.iasj.net/iasj/download/f1ef85c3b330c698	PROPN
iajs-3313	246	2	.	.	PUNCT
iajs-3313	247	1	24	24	NUM
iajs-3313	247	2	.	.	PUNCT
iajs-3313	247	3	gastaca	gastaca	PROPN
iajs-3313	247	4	,	,	PUNCT
iajs-3313	247	5	b.	b.	PROPN
iajs-3313	247	6	;	;	PUNCT
iajs-3313	247	7	galletti	galletti	PROPN
iajs-3313	247	8	,	,	PUNCT
iajs-3313	247	9	g.	g.	PROPN
iajs-3313	247	10	;	;	PUNCT
iajs-3313	247	11	sánchez	sánchez	PROPN
iajs-3313	247	12	,	,	PUNCT
iajs-3313	247	13	h.r	h.r	PROPN
iajs-3313	247	14	.	.	PROPN
iajs-3313	247	15	;	;	PUNCT
iajs-3313	247	16	diez	diez	PROPN
iajs-3313	247	17	,	,	PUNCT
iajs-3313	247	18	r.p	r.p	PROPN
iajs-3313	247	19	.	.	PROPN
iajs-3313	247	20	;	;	PUNCT
iajs-3313	247	21	schiavoni	schiavoni	PROPN
iajs-3313	247	22	,	,	PUNCT
iajs-3313	247	23	m.m	m.m	PROPN
iajs-3313	247	24	.	.	PROPN
iajs-3313	247	25	;	;	PUNCT
iajs-3313	247	26	furlong	furlong	ADJ
iajs-3313	247	27	,	,	PUNCT
iajs-3313	247	28	j.j.p	j.j.p	PROPN
iajs-3313	247	29	.	.	PUNCT
iajs-3313	247	30	gc	gc	PROPN
iajs-3313	247	31	/	/	SYM
iajs-3313	247	32	ms	ms	PROPN
iajs-3313	247	33	analyses	analysis	NOUN
iajs-3313	247	34	of	of	ADP
iajs-3313	247	35	thiosemicarbazones	thiosemicarbazone	NOUN
iajs-3313	247	36	synthesized	synthesize	VERB
iajs-3313	247	37	from	from	ADP
iajs-3313	247	38	acetophenones	acetophenone	NOUN
iajs-3313	247	39	:	:	PUNCT
iajs-3313	247	40	thermal	thermal	ADJ
iajs-3313	247	41	decay	decay	NOUN
iajs-3313	247	42	and	and	CCONJ
iajs-3313	247	43	mass	mass	ADJ
iajs-3313	247	44	spectra	spectra	ADJ
iajs-3313	247	45	features	feature	NOUN
iajs-3313	247	46	.	.	PUNCT
iajs-3313	248	1	int	int	NOUN
iajs-3313	248	2	j	j	PROPN
iajs-3313	248	3	anal	anal	PROPN
iajs-3313	248	4	mass	mass	PROPN
iajs-3313	248	5	spectrom	spectrom	PROPN
iajs-3313	248	6	chromatogr	chromatogr	PROPN
iajs-3313	248	7	2015	2015	NUM
iajs-3313	248	8	,	,	PUNCT
iajs-3313	248	9	3(1),1	3(1),1	PROPN
iajs-3313	248	10	-	-	SYM
iajs-3313	248	11	13	13	NUM
iajs-3313	248	12	.	.	PUNCT
iajs-3313	249	1	https://doi	https://doi	ADJ
iajs-3313	249	2	:	:	PUNCT
iajs-3313	249	3	10.4236	10.4236	NUM
iajs-3313	249	4	/	/	SYM
iajs-3313	249	5	ijamsc.2015.31001	ijamsc.2015.31001	NUM
iajs-3313	249	6	.	.	PUNCT
iajs-3313	250	1	25	25	NUM
iajs-3313	250	2	.	.	X
iajs-3313	250	3	prokopchuk	prokopchuk	PROPN
iajs-3313	250	4	,	,	PUNCT
iajs-3313	250	5	e.d	e.d	PROPN
iajs-3313	250	6	.	.	PROPN
iajs-3313	250	7	;	;	PUNCT
iajs-3313	250	8	sonnenberg	sonnenberg	PROPN
iajs-3313	250	9	,	,	PUNCT
iajs-3313	250	10	f.j	f.j	PROPN
iajs-3313	250	11	.	.	PROPN
iajs-3313	250	12	;	;	PUNCT
iajs-3313	250	13	meyer	meyer	PROPN
iajs-3313	250	14	,	,	PUNCT
iajs-3313	250	15	n.	n.	PROPN
iajs-3313	250	16	;	;	PUNCT
iajs-3313	250	17	zimmer	zimmer	PROPN
iajs-3313	250	18	-	-	PUNCT
iajs-3313	250	19	de	de	X
iajs-3313	250	20	iuliis	iuliis	NOUN
iajs-3313	250	21	,	,	PUNCT
iajs-3313	250	22	m.	m.	NOUN
iajs-3313	250	23	;	;	PUNCT
iajs-3313	250	24	lough	lough	PROPN
iajs-3313	250	25	,	,	PUNCT
iajs-3313	250	26	j.a	j.a	PROPN
iajs-3313	250	27	.	.	PROPN
iajs-3313	250	28	;	;	PUNCT
iajs-3313	250	29	morris	morris	PROPN
iajs-3313	250	30	,	,	PUNCT
iajs-3313	250	31	h.r	h.r	PROPN
iajs-3313	250	32	.	.	PROPN
iajs-3313	250	33	spectroscopic	spectroscopic	PROPN
iajs-3313	250	34	and	and	CCONJ
iajs-3313	250	35	dft	dft	PROPN
iajs-3313	250	36	study	study	NOUN
iajs-3313	250	37	of	of	ADP
iajs-3313	250	38	ferraaziridine	ferraaziridine	NOUN
iajs-3313	250	39	complexes	complex	NOUN
iajs-3313	250	40	formed	form	VERB
iajs-3313	250	41	in	in	ADP
iajs-3313	250	42	the	the	DET
iajs-3313	250	43	transfer	transfer	NOUN
iajs-3313	250	44	hydrogenation	hydrogenation	NOUN
iajs-3313	250	45	of	of	ADP
iajs-3313	250	46	acetophenone	acetophenone	NOUN
iajs-3313	250	47	catalyzed	catalyze	VERB
iajs-3313	250	48	using	use	VERB
iajs-3313	250	49	trans-[fe(co)(ncme)(pph2c6h4ch	trans-[fe(co)(ncme)(pph2c6h4ch	ADP
iajs-3313	250	50	═	═	PROPN
iajs-3313	250	51	nch2−)2	nch2−)2	NOUN
iajs-3313	250	52	-	-	PUNCT
iajs-3313	250	53	κ4p	κ4p	ADJ
iajs-3313	250	54	,	,	PUNCT
iajs-3313	250	55	n	n	CCONJ
iajs-3313	250	56	,	,	PUNCT
iajs-3313	250	57	n	n	CCONJ
iajs-3313	250	58	,	,	PUNCT
iajs-3313	250	59	p](bf4)2	p](bf4)2	NOUN
iajs-3313	250	60	.	.	PUNCT
iajs-3313	251	1	organometallics	organometallic	NOUN
iajs-3313	251	2	2012	2012	NUM
iajs-3313	251	3	,	,	PUNCT
iajs-3313	251	4	31(8	31(8	NUM
iajs-3313	251	5	)	)	PUNCT
iajs-3313	251	6	,	,	PUNCT
iajs-3313	251	7	3056–3064	3056–3064	NUM
iajs-3313	251	8	.	.	PUNCT
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iajs-3313	265	2	.	.	PUNCT
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iajs-3313	270	2	.	.	PUNCT
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iajs-3313	271	2	,	,	PUNCT
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iajs-3313	272	48	.	.	PUNCT
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iajs-3313	273	8	,	,	PUNCT
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