id	sid	tid	token	lemma	pos
iajs-3629	1	1	249	249	NUM
iajs-3629	1	2	©	©	ADP
iajs-3629	1	3	2025	2025	NUM
iajs-3629	1	4	the	the	DET
iajs-3629	1	5	author(s	author(s	NOUN
iajs-3629	1	6	)	)	PUNCT
iajs-3629	1	7	.	.	PUNCT
iajs-3629	2	1	published	publish	VERB
iajs-3629	2	2	by	by	ADP
iajs-3629	2	3	college	college	NOUN
iajs-3629	2	4	of	of	ADP
iajs-3629	2	5	education	education	NOUN
iajs-3629	2	6	for	for	ADP
iajs-3629	2	7	pure	pure	ADJ
iajs-3629	2	8	science	science	NOUN
iajs-3629	2	9	(	(	PUNCT
iajs-3629	2	10	ibn	ibn	PROPN
iajs-3629	2	11	al	al	PROPN
iajs-3629	2	12	-	-	PUNCT
iajs-3629	2	13	haitham	haitham	PROPN
iajs-3629	2	14	)	)	PUNCT
iajs-3629	2	15	,	,	PUNCT
iajs-3629	2	16	university	university	NOUN
iajs-3629	2	17	of	of	ADP
iajs-3629	2	18	baghdad	baghdad	PROPN
iajs-3629	2	19	.	.	PUNCT
iajs-3629	3	1	this	this	PRON
iajs-3629	3	2	is	be	AUX
iajs-3629	3	3	an	an	DET
iajs-3629	3	4	open	open	ADJ
iajs-3629	3	5	-	-	PUNCT
iajs-3629	3	6	access	access	NOUN
iajs-3629	3	7	article	article	NOUN
iajs-3629	3	8	distributed	distribute	VERB
iajs-3629	3	9	under	under	ADP
iajs-3629	3	10	the	the	DET
iajs-3629	3	11	terms	term	NOUN
iajs-3629	3	12	of	of	ADP
iajs-3629	3	13	the	the	DET
iajs-3629	3	14	creative	creative	ADJ
iajs-3629	3	15	commons	common	NOUN
iajs-3629	3	16	attribution	attribution	NOUN
iajs-3629	3	17	4.0	4.0	NUM
iajs-3629	3	18	international	international	ADJ
iajs-3629	3	19	license	license	NOUN
iajs-3629	3	20	preparation	preparation	NOUN
iajs-3629	3	21	and	and	CCONJ
iajs-3629	3	22	characterization	characterization	NOUN
iajs-3629	3	23	of	of	ADP
iajs-3629	3	24	mixed	mixed	ADJ
iajs-3629	3	25	ligands	ligand	NOUN
iajs-3629	3	26	of	of	ADP
iajs-3629	3	27	flucloxacillin	flucloxacillin	NOUN
iajs-3629	3	28	and	and	CCONJ
iajs-3629	3	29	proline	proline	NOUN
iajs-3629	3	30	and	and	CCONJ
iajs-3629	3	31	theoretical	theoretical	ADJ
iajs-3629	3	32	treatment	treatment	NOUN
iajs-3629	3	33	to	to	PART
iajs-3629	3	34	form	form	VERB
iajs-3629	3	35	coordination	coordination	NOUN
iajs-3629	3	36	complexes	complex	NOUN
iajs-3629	3	37	with	with	ADP
iajs-3629	3	38	some	some	DET
iajs-3629	3	39	metal	metal	NOUN
iajs-3629	3	40	ions	ion	NOUN
iajs-3629	3	41	shayma	shayma	PROPN
iajs-3629	3	42	a.	a.	PROPN
iajs-3629	3	43	hndi	hndi	PROPN
iajs-3629	3	44	1	1	NUM
iajs-3629	3	45	*	*	PUNCT
iajs-3629	3	46	and	and	CCONJ
iajs-3629	3	47	sahar	sahar	PROPN
iajs-3629	3	48	s.	s.	PROPN
iajs-3629	3	49	hassan	hassan	PROPN
iajs-3629	3	50	2	2	PROPN
iajs-3629	3	51	1,2department	1,2department	NUM
iajs-3629	3	52	of	of	ADP
iajs-3629	3	53	chemistry	chemistry	NOUN
iajs-3629	3	54	,	,	PUNCT
iajs-3629	3	55	college	college	NOUN
iajs-3629	3	56	of	of	ADP
iajs-3629	3	57	science	science	NOUN
iajs-3629	3	58	for	for	ADP
iajs-3629	3	59	women	woman	NOUN
iajs-3629	3	60	,	,	PUNCT
iajs-3629	3	61	university	university	NOUN
iajs-3629	3	62	of	of	ADP
iajs-3629	3	63	baghdad	baghdad	PROPN
iajs-3629	3	64	,	,	PUNCT
iajs-3629	3	65	baghdad	baghdad	PROPN
iajs-3629	3	66	,	,	PUNCT
iajs-3629	3	67	iraq	iraq	PROPN
iajs-3629	3	68	.	.	PUNCT
iajs-3629	4	1	1ministry	1ministry	NUM
iajs-3629	4	2	of	of	ADP
iajs-3629	4	3	education	education	NOUN
iajs-3629	4	4	,	,	PUNCT
iajs-3629	4	5	baghdad	baghdad	PROPN
iajs-3629	4	6	,	,	PUNCT
iajs-3629	4	7	iraq	iraq	PROPN
iajs-3629	4	8	.	.	PUNCT
iajs-3629	5	1	*	*	PUNCT
iajs-3629	5	2	corresponding	correspond	VERB
iajs-3629	5	3	author	author	NOUN
iajs-3629	5	4	.	.	PUNCT
iajs-3629	6	1	received	receive	VERB
iajs-3629	6	2	:	:	PUNCT
iajs-3629	6	3	26	26	NUM
iajs-3629	6	4	june	june	PROPN
iajs-3629	6	5	2023	2023	NUM
iajs-3629	6	6	accepted	accept	VERB
iajs-3629	6	7	:	:	PUNCT
iajs-3629	6	8	10	10	NUM
iajs-3629	6	9	september	september	PROPN
iajs-3629	6	10	2023	2023	NUM
iajs-3629	6	11	published	publish	VERB
iajs-3629	6	12	:	:	PUNCT
iajs-3629	6	13	20	20	NUM
iajs-3629	6	14	april	april	PROPN
iajs-3629	6	15	2025	2025	NUM
iajs-3629	6	16	doi.org/10.30526/38.2.3629	doi.org/10.30526/38.2.3629	VERB
iajs-3629	6	17	abstract	abstract	ADJ
iajs-3629	6	18	flucloxacillin	flucloxacillin	NOUN
iajs-3629	6	19	(	(	PUNCT
iajs-3629	6	20	flx	flx	NOUN
iajs-3629	6	21	)	)	PUNCT
iajs-3629	6	22	derivative	derivative	ADJ
iajs-3629	6	23	metal	metal	NOUN
iajs-3629	6	24	complexes(2s,5r,6r)-6-({[3-(2	complexes(2s,5r,6r)-6-({[3-(2	NOUN
iajs-3629	6	25	-	-	PUNCT
iajs-3629	6	26	chloro-5fluorophenyl)-5	chloro-5fluorophenyl)-5	NOUN
iajs-3629	6	27	-	-	PUNCT
iajs-3629	6	28	methylisoxazol-4	methylisoxazol-4	NOUN
iajs-3629	6	29	-	-	PUNCT
iajs-3629	6	30	yl	yl	NOUN
iajs-3629	6	31	]	]	X
iajs-3629	6	32	carbonyl}amino)-3,3	carbonyl}amino)-3,3	NOUN
iajs-3629	6	33	-	-	PUNCT
iajs-3629	6	34	dimethyl-7	dimethyl-7	NOUN
iajs-3629	6	35	-	-	PUNCT
iajs-3629	6	36	oxo-4	oxo-4	NOUN
iajs-3629	6	37	-	-	PUNCT
iajs-3629	6	38	thia-1	thia-1	NUM
iajs-3629	6	39	-	-	PUNCT
iajs-3629	6	40	azabicyclo	azabicyclo	NOUN
iajs-3629	7	1	[	[	X
iajs-3629	7	2	3.2.0	3.2.0	X
iajs-3629	7	3	]	]	PUNCT
iajs-3629	7	4	heptane-2	heptane-2	PROPN
iajs-3629	7	5	-	-	PUNCT
iajs-3629	7	6	methyl	methyl	NOUN
iajs-3629	7	7	aster&proline	aster&proline	NOUN
iajs-3629	7	8	with	with	ADP
iajs-3629	7	9	coii	coii	PROPN
iajs-3629	7	10	,	,	PUNCT
iajs-3629	7	11	niii	niii	NOUN
iajs-3629	7	12	,	,	PUNCT
iajs-3629	7	13	cuii	cuii	ADJ
iajs-3629	7	14	,	,	PUNCT
iajs-3629	7	15	znii	znii	NOUN
iajs-3629	7	16	and	and	CCONJ
iajs-3629	7	17	cdii	cdii	NOUN
iajs-3629	7	18	.	.	PUNCT
iajs-3629	8	1	they	they	PRON
iajs-3629	8	2	were	be	AUX
iajs-3629	8	3	synthesized	synthesize	VERB
iajs-3629	8	4	and	and	CCONJ
iajs-3629	8	5	identified	identify	VERB
iajs-3629	8	6	using	use	VERB
iajs-3629	8	7	physiochemical	physiochemical	ADJ
iajs-3629	8	8	techniques	technique	NOUN
iajs-3629	8	9	,	,	PUNCT
iajs-3629	8	10	including	include	VERB
iajs-3629	8	11	(	(	PUNCT
iajs-3629	8	12	elemental	elemental	ADJ
iajs-3629	8	13	analysis	analysis	NOUN
iajs-3629	8	14	chns	chns	ADJ
iajs-3629	8	15	,	,	PUNCT
iajs-3629	8	16	metal	metal	NOUN
iajs-3629	8	17	analysis	analysis	NOUN
iajs-3629	8	18	aa	aa	NOUN
iajs-3629	8	19	,	,	PUNCT
iajs-3629	8	20	uv	uv	NOUN
iajs-3629	8	21	-	-	PUNCT
iajs-3629	8	22	vis	vis	X
iajs-3629	8	23	,	,	PUNCT
iajs-3629	8	24	ftir	ftir	PROPN
iajs-3629	8	25	,	,	PUNCT
iajs-3629	8	26	tga	tga	PROPN
iajs-3629	8	27	,	,	PUNCT
iajs-3629	8	28	magnetic	magnetic	ADJ
iajs-3629	8	29	susceptibility	susceptibility	NOUN
iajs-3629	8	30	,	,	PUNCT
iajs-3629	8	31	and	and	CCONJ
iajs-3629	8	32	conductivity	conductivity	NOUN
iajs-3629	8	33	measurement	measurement	NOUN
iajs-3629	8	34	)	)	PUNCT
iajs-3629	8	35	.	.	PUNCT
iajs-3629	9	1	this	this	DET
iajs-3629	9	2	study	study	NOUN
iajs-3629	9	3	aims	aim	VERB
iajs-3629	9	4	to	to	PART
iajs-3629	9	5	investigate	investigate	VERB
iajs-3629	9	6	the	the	DET
iajs-3629	9	7	coordination	coordination	NOUN
iajs-3629	9	8	behavior	behavior	NOUN
iajs-3629	9	9	of	of	ADP
iajs-3629	9	10	flucloxacillin	flucloxacillin	NOUN
iajs-3629	9	11	and	and	CCONJ
iajs-3629	9	12	proline	proline	NOUN
iajs-3629	9	13	,	,	PUNCT
iajs-3629	9	14	analyze	analyze	VERB
iajs-3629	9	15	their	their	PRON
iajs-3629	9	16	structural	structural	ADJ
iajs-3629	9	17	and	and	CCONJ
iajs-3629	9	18	electronic	electronic	ADJ
iajs-3629	9	19	properties	property	NOUN
iajs-3629	9	20	,	,	PUNCT
iajs-3629	9	21	and	and	CCONJ
iajs-3629	9	22	evaluate	evaluate	VERB
iajs-3629	9	23	their	their	PRON
iajs-3629	9	24	potential	potential	ADJ
iajs-3629	9	25	biological	biological	ADJ
iajs-3629	9	26	activities	activity	NOUN
iajs-3629	9	27	against	against	ADP
iajs-3629	9	28	bacterial	bacterial	ADJ
iajs-3629	9	29	and	and	CCONJ
iajs-3629	9	30	fungal	fungal	ADJ
iajs-3629	9	31	strains	strain	NOUN
iajs-3629	9	32	.	.	PUNCT
iajs-3629	10	1	additionally	additionally	ADV
iajs-3629	10	2	,	,	PUNCT
iajs-3629	10	3	theoretical	theoretical	ADJ
iajs-3629	10	4	calculations	calculation	NOUN
iajs-3629	10	5	using	use	VERB
iajs-3629	10	6	hyperchem	hyperchem	NOUN
iajs-3629	10	7	software	software	NOUN
iajs-3629	10	8	are	be	AUX
iajs-3629	10	9	conducted	conduct	VERB
iajs-3629	10	10	to	to	PART
iajs-3629	10	11	assess	assess	VERB
iajs-3629	10	12	the	the	DET
iajs-3629	10	13	stability	stability	NOUN
iajs-3629	10	14	and	and	CCONJ
iajs-3629	10	15	electronic	electronic	ADJ
iajs-3629	10	16	configurations	configuration	NOUN
iajs-3629	10	17	of	of	ADP
iajs-3629	10	18	the	the	DET
iajs-3629	10	19	synthesized	synthesize	VERB
iajs-3629	10	20	complexes	complex	NOUN
iajs-3629	10	21	.	.	PUNCT
iajs-3629	11	1	flucloxacillin	flucloxacillin	PROPN
iajs-3629	11	2	reacted	react	VERB
iajs-3629	11	3	with	with	ADP
iajs-3629	11	4	metal	metal	NOUN
iajs-3629	11	5	ions	ion	NOUN
iajs-3629	11	6	as	as	ADP
iajs-3629	11	7	a	a	DET
iajs-3629	11	8	bidentate	bidentate	ADJ
iajs-3629	11	9	ligand	ligand	NOUN
iajs-3629	11	10	using	use	VERB
iajs-3629	11	11	the	the	DET
iajs-3629	11	12	nitrogen	nitrogen	NOUN
iajs-3629	11	13	of	of	ADP
iajs-3629	11	14	the	the	DET
iajs-3629	11	15	β	β	NOUN
iajs-3629	11	16	-	-	PUNCT
iajs-3629	11	17	lactone	lactone	ADJ
iajs-3629	11	18	thiazolidine	thiazolidine	NOUN
iajs-3629	11	19	ring	ring	NOUN
iajs-3629	11	20	and	and	CCONJ
iajs-3629	11	21	the	the	DET
iajs-3629	11	22	carboxylate	carboxylate	NOUN
iajs-3629	11	23	ion	ion	NOUN
iajs-3629	11	24	,	,	PUNCT
iajs-3629	11	25	forming	form	VERB
iajs-3629	11	26	a	a	DET
iajs-3629	11	27	five	five	NUM
iajs-3629	11	28	-	-	PUNCT
iajs-3629	11	29	membered	membere	VERB
iajs-3629	11	30	ring	ring	NOUN
iajs-3629	11	31	,	,	PUNCT
iajs-3629	11	32	according	accord	VERB
iajs-3629	11	33	to	to	ADP
iajs-3629	11	34	the	the	DET
iajs-3629	11	35	results	result	NOUN
iajs-3629	11	36	and	and	CCONJ
iajs-3629	11	37	from	from	ADP
iajs-3629	11	38	the	the	DET
iajs-3629	11	39	oxygen	oxygen	NOUN
iajs-3629	11	40	and	and	CCONJ
iajs-3629	11	41	amine	amine	ADJ
iajs-3629	11	42	group	group	NOUN
iajs-3629	11	43	of	of	ADP
iajs-3629	11	44	proline	proline	NOUN
iajs-3629	11	45	as	as	ADP
iajs-3629	11	46	mixed	mixed	ADJ
iajs-3629	11	47	ligand	ligand	NOUN
iajs-3629	11	48	complexes	complex	NOUN
iajs-3629	11	49	,	,	PUNCT
iajs-3629	11	50	with	with	ADP
iajs-3629	11	51	a	a	DET
iajs-3629	11	52	six	six	NUM
iajs-3629	11	53	-	-	PUNCT
iajs-3629	11	54	coordination	coordination	NOUN
iajs-3629	11	55	octahedral	octahedral	ADJ
iajs-3629	11	56	geometry	geometry	NOUN
iajs-3629	11	57	proposed	propose	VERB
iajs-3629	11	58	for	for	ADP
iajs-3629	11	59	all	all	DET
iajs-3629	11	60	complexes	complex	NOUN
iajs-3629	11	61	.	.	PUNCT
iajs-3629	12	1	the	the	DET
iajs-3629	12	2	hyper	hyper	ADJ
iajs-3629	12	3	chem-8.0.7	chem-8.0.7	NUM
iajs-3629	12	4	software	software	NOUN
iajs-3629	12	5	was	be	AUX
iajs-3629	12	6	employed	employ	VERB
iajs-3629	12	7	to	to	PART
iajs-3629	12	8	compute	compute	VERB
iajs-3629	12	9	the	the	DET
iajs-3629	12	10	heat	heat	NOUN
iajs-3629	12	11	of	of	ADP
iajs-3629	12	12	formation	formation	NOUN
iajs-3629	12	13	(	(	PUNCT
iajs-3629	12	14	hf	hf	NOUN
iajs-3629	12	15	)	)	PUNCT
iajs-3629	12	16	,	,	PUNCT
iajs-3629	12	17	binding	bind	VERB
iajs-3629	12	18	energy	energy	NOUN
iajs-3629	12	19	(	(	PUNCT
iajs-3629	12	20	∆eb	∆eb	NOUN
iajs-3629	12	21	)	)	PUNCT
iajs-3629	12	22	,	,	PUNCT
iajs-3629	12	23	total	total	ADJ
iajs-3629	12	24	energy	energy	NOUN
iajs-3629	12	25	(	(	PUNCT
iajs-3629	12	26	∆et	∆et	PROPN
iajs-3629	12	27	)	)	PUNCT
iajs-3629	12	28	,	,	PUNCT
iajs-3629	12	29	vibration	vibration	NOUN
iajs-3629	12	30	spectra	spectra	NOUN
iajs-3629	12	31	,	,	PUNCT
iajs-3629	12	32	and	and	CCONJ
iajs-3629	12	33	electronic	electronic	ADJ
iajs-3629	12	34	spectra	spectra	NOUN
iajs-3629	12	35	for	for	ADP
iajs-3629	12	36	the	the	DET
iajs-3629	12	37	mixed	mixed	ADJ
iajs-3629	12	38	ligand	ligand	NOUN
iajs-3629	12	39	and	and	CCONJ
iajs-3629	12	40	its	its	PRON
iajs-3629	12	41	corresponding	corresponding	ADJ
iajs-3629	12	42	metal	metal	NOUN
iajs-3629	12	43	complexes	complex	NOUN
iajs-3629	12	44	.	.	PUNCT
iajs-3629	13	1	the	the	DET
iajs-3629	13	2	antifungal	antifungal	ADJ
iajs-3629	13	3	activity	activity	NOUN
iajs-3629	13	4	of	of	ADP
iajs-3629	13	5	mixed	mixed	ADJ
iajs-3629	13	6	ligands	ligand	NOUN
iajs-3629	13	7	and	and	CCONJ
iajs-3629	13	8	their	their	PRON
iajs-3629	13	9	metal	metal	NOUN
iajs-3629	13	10	complexes	complex	NOUN
iajs-3629	13	11	was	be	AUX
iajs-3629	13	12	evaluated	evaluate	VERB
iajs-3629	13	13	against	against	ADP
iajs-3629	13	14	candida	candida	NOUN
iajs-3629	13	15	albicans	albican	NOUN
iajs-3629	13	16	,	,	PUNCT
iajs-3629	13	17	while	while	SCONJ
iajs-3629	13	18	their	their	PRON
iajs-3629	13	19	antibacterial	antibacterial	ADJ
iajs-3629	13	20	activity	activity	NOUN
iajs-3629	13	21	against	against	ADP
iajs-3629	13	22	staphylococcus	staphylococcus	NOUN
iajs-3629	13	23	aureus	aureus	NOUN
iajs-3629	13	24	and	and	CCONJ
iajs-3629	13	25	escherichia	escherichia	NOUN
iajs-3629	13	26	coli	coli	NOUN
iajs-3629	13	27	was	be	AUX
iajs-3629	13	28	also	also	ADV
iajs-3629	13	29	assessed	assess	VERB
iajs-3629	13	30	.	.	PUNCT
iajs-3629	14	1	these	these	DET
iajs-3629	14	2	tests	test	NOUN
iajs-3629	14	3	were	be	AUX
iajs-3629	14	4	conducted	conduct	VERB
iajs-3629	14	5	at	at	ADP
iajs-3629	14	6	a	a	DET
iajs-3629	14	7	concentration	concentration	NOUN
iajs-3629	14	8	of	of	ADP
iajs-3629	14	9	5	5	NUM
iajs-3629	14	10	mm	mm	NOUN
iajs-3629	14	11	in	in	ADP
iajs-3629	14	12	a	a	DET
iajs-3629	14	13	nutritional	nutritional	ADJ
iajs-3629	14	14	agar	agar	NOUN
iajs-3629	14	15	medium	medium	NOUN
iajs-3629	14	16	.	.	PUNCT
iajs-3629	15	1	keywords	keyword	NOUN
iajs-3629	15	2	:	:	PUNCT
iajs-3629	15	3	flucloxacillin	flucloxacillin	NOUN
iajs-3629	15	4	derivatives	derivative	NOUN
iajs-3629	15	5	,	,	PUNCT
iajs-3629	15	6	metal	metal	NOUN
iajs-3629	15	7	ions	ion	NOUN
iajs-3629	15	8	complexes	complex	NOUN
iajs-3629	15	9	,	,	PUNCT
iajs-3629	15	10	mixed	mixed	ADJ
iajs-3629	15	11	ligand	ligand	NOUN
iajs-3629	15	12	,	,	PUNCT
iajs-3629	15	13	proline	proline	NOUN
iajs-3629	15	14	,	,	PUNCT
iajs-3629	15	15	transition	transition	NOUN
iajs-3629	15	16	metal	metal	NOUN
iajs-3629	15	17	ions	ion	NOUN
iajs-3629	15	18	.	.	PUNCT
iajs-3629	16	1	1	1	X
iajs-3629	16	2	.	.	X
iajs-3629	16	3	introduction	introduction	NOUN
iajs-3629	16	4	in	in	ADP
iajs-3629	16	5	biological	biological	ADJ
iajs-3629	16	6	systems	system	NOUN
iajs-3629	16	7	,	,	PUNCT
iajs-3629	16	8	it	it	PRON
iajs-3629	16	9	is	be	AUX
iajs-3629	16	10	common	common	ADJ
iajs-3629	16	11	for	for	SCONJ
iajs-3629	16	12	metal	metal	NOUN
iajs-3629	16	13	ions	ion	NOUN
iajs-3629	16	14	to	to	PART
iajs-3629	16	15	form	form	VERB
iajs-3629	16	16	ternary	ternary	ADJ
iajs-3629	16	17	complexes	complex	NOUN
iajs-3629	16	18	,	,	PUNCT
iajs-3629	16	19	wherein	wherein	SCONJ
iajs-3629	16	20	the	the	DET
iajs-3629	16	21	metal	metal	NOUN
iajs-3629	16	22	ion	ion	NOUN
iajs-3629	16	23	interacts	interact	VERB
iajs-3629	16	24	with	with	ADP
iajs-3629	16	25	two	two	NUM
iajs-3629	16	26	or	or	CCONJ
iajs-3629	16	27	more	more	ADV
iajs-3629	16	28	different	different	ADJ
iajs-3629	16	29	ligands	ligand	NOUN
iajs-3629	16	30	(	(	PUNCT
iajs-3629	16	31	1	1	NUM
iajs-3629	16	32	)	)	PUNCT
iajs-3629	16	33	.	.	PUNCT
iajs-3629	17	1	the	the	DET
iajs-3629	17	2	recent	recent	ADJ
iajs-3629	17	3	increase	increase	NOUN
iajs-3629	17	4	in	in	ADP
iajs-3629	17	5	the	the	DET
iajs-3629	17	6	popularity	popularity	NOUN
iajs-3629	17	7	https://creativecommons.org/licenses/by/4.0/	https://creativecommons.org/licenses/by/4.0/	PROPN
iajs-3629	17	8	https://creativecommons.org/licenses/by/4.0/	https://creativecommons.org/licenses/by/4.0/	PROPN
iajs-3629	17	9	https://orcid.org/0009-0009-6079-4985	https://orcid.org/0009-0009-6079-4985	VERB
iajs-3629	17	10	mailto:shaymaalmehmdy@gmail.com	mailto:shaymaalmehmdy@gmail.com	PROPN
iajs-3629	17	11	https://orcid.org/0000-0002-1985-7878	https://orcid.org/0000-0002-1985-7878	PROPN
iajs-3629	17	12	mailto:saharsabeeh21@yahoo.com	mailto:saharsabeeh21@yahoo.com	PROPN
iajs-3629	17	13	ihjpas	ihjpas	PROPN
iajs-3629	17	14	.	.	PUNCT
iajs-3629	18	1	2025,38(2	2025,38(2	PROPN
iajs-3629	18	2	)	)	PUNCT
iajs-3629	19	1	250	250	NUM
iajs-3629	19	2	of	of	ADP
iajs-3629	19	3	mixed	mixed	ADJ
iajs-3629	19	4	chelation	chelation	NOUN
iajs-3629	19	5	can	can	AUX
iajs-3629	19	6	be	be	AUX
iajs-3629	19	7	attributed	attribute	VERB
iajs-3629	19	8	to	to	ADP
iajs-3629	19	9	the	the	DET
iajs-3629	19	10	presence	presence	NOUN
iajs-3629	19	11	of	of	ADP
iajs-3629	19	12	numerous	numerous	ADJ
iajs-3629	19	13	possible	possible	ADJ
iajs-3629	19	14	ligands	ligand	NOUN
iajs-3629	19	15	in	in	ADP
iajs-3629	19	16	biological	biological	ADJ
iajs-3629	19	17	fluids	fluid	NOUN
iajs-3629	19	18	,	,	PUNCT
iajs-3629	19	19	which	which	PRON
iajs-3629	19	20	compete	compete	VERB
iajs-3629	19	21	for	for	ADP
iajs-3629	19	22	metal	metal	NOUN
iajs-3629	19	23	ions	ion	NOUN
iajs-3629	19	24	in	in	ADP
iajs-3629	19	25	vivo	vivo	NOUN
iajs-3629	19	26	(	(	PUNCT
iajs-3629	19	27	2	2	NUM
iajs-3629	19	28	)	)	PUNCT
iajs-3629	19	29	.	.	PUNCT
iajs-3629	20	1	ternary	ternary	ADJ
iajs-3629	20	2	coordination	coordination	NOUN
iajs-3629	20	3	complexes	complex	NOUN
iajs-3629	20	4	are	be	AUX
iajs-3629	20	5	widely	widely	ADV
iajs-3629	20	6	recognized	recognize	VERB
iajs-3629	20	7	for	for	ADP
iajs-3629	20	8	their	their	PRON
iajs-3629	20	9	significant	significant	ADJ
iajs-3629	20	10	role	role	NOUN
iajs-3629	20	11	in	in	ADP
iajs-3629	20	12	various	various	ADJ
iajs-3629	20	13	biological	biological	ADJ
iajs-3629	20	14	processes	process	NOUN
iajs-3629	20	15	,	,	PUNCT
iajs-3629	20	16	as	as	SCONJ
iajs-3629	20	17	evidenced	evidence	VERB
iajs-3629	20	18	by	by	ADP
iajs-3629	20	19	the	the	DET
iajs-3629	20	20	fact	fact	NOUN
iajs-3629	20	21	that	that	SCONJ
iajs-3629	20	22	metal	metal	NOUN
iajs-3629	20	23	ions	ion	NOUN
iajs-3629	20	24	are	be	AUX
iajs-3629	20	25	known	know	VERB
iajs-3629	20	26	to	to	PART
iajs-3629	20	27	activate	activate	VERB
iajs-3629	20	28	enzymes	enzyme	NOUN
iajs-3629	20	29	in	in	ADP
iajs-3629	20	30	several	several	ADJ
iajs-3629	20	31	instances	instance	NOUN
iajs-3629	20	32	.	.	PUNCT
iajs-3629	21	1	ternary	ternary	ADJ
iajs-3629	21	2	complexes	complex	NOUN
iajs-3629	21	3	that	that	PRON
iajs-3629	21	4	incorporate	incorporate	VERB
iajs-3629	21	5	an	an	DET
iajs-3629	21	6	amino	amino	NOUN
iajs-3629	21	7	acid	acid	NOUN
iajs-3629	21	8	as	as	ADP
iajs-3629	21	9	a	a	DET
iajs-3629	21	10	secondary	secondary	ADJ
iajs-3629	21	11	ligand	ligand	NOUN
iajs-3629	21	12	hold	hold	VERB
iajs-3629	21	13	considerable	considerable	ADJ
iajs-3629	21	14	significance	significance	NOUN
iajs-3629	21	15	due	due	ADP
iajs-3629	21	16	to	to	ADP
iajs-3629	21	17	their	their	PRON
iajs-3629	21	18	potential	potential	NOUN
iajs-3629	21	19	as	as	ADP
iajs-3629	21	20	models	model	NOUN
iajs-3629	21	21	for	for	ADP
iajs-3629	21	22	enzyme	enzyme	NOUN
iajs-3629	21	23	-	-	PUNCT
iajs-3629	21	24	metal	metal	NOUN
iajs-3629	21	25	ion	ion	NOUN
iajs-3629	21	26	-	-	PUNCT
iajs-3629	21	27	substrate	substrate	NOUN
iajs-3629	21	28	complexes	complex	NOUN
iajs-3629	21	29	.	.	PUNCT
iajs-3629	22	1	the	the	DET
iajs-3629	22	2	involvement	involvement	NOUN
iajs-3629	22	3	of	of	ADP
iajs-3629	22	4	ternary	ternary	ADJ
iajs-3629	22	5	complexes	complex	NOUN
iajs-3629	22	6	in	in	ADP
iajs-3629	22	7	the	the	DET
iajs-3629	22	8	storage	storage	NOUN
iajs-3629	22	9	and	and	CCONJ
iajs-3629	22	10	transportation	transportation	NOUN
iajs-3629	22	11	of	of	ADP
iajs-3629	22	12	active	active	ADJ
iajs-3629	22	13	chemicals	chemical	NOUN
iajs-3629	22	14	across	across	ADP
iajs-3629	22	15	membranes	membrane	NOUN
iajs-3629	22	16	has	have	AUX
iajs-3629	22	17	been	be	AUX
iajs-3629	22	18	further	far	ADV
iajs-3629	22	19	impacted	impact	VERB
iajs-3629	22	20	by	by	ADP
iajs-3629	22	21	the	the	DET
iajs-3629	22	22	formation	formation	NOUN
iajs-3629	22	23	of	of	ADP
iajs-3629	22	24	these	these	DET
iajs-3629	22	25	species	specie	NOUN
iajs-3629	22	26	and	and	CCONJ
iajs-3629	22	27	the	the	DET
iajs-3629	22	28	electronic	electronic	ADJ
iajs-3629	22	29	configuration	configuration	NOUN
iajs-3629	22	30	of	of	ADP
iajs-3629	22	31	the	the	DET
iajs-3629	22	32	metal	metal	NOUN
iajs-3629	22	33	ions	ion	NOUN
iajs-3629	22	34	involved	involve	VERB
iajs-3629	22	35	in	in	ADP
iajs-3629	22	36	the	the	DET
iajs-3629	22	37	process	process	NOUN
iajs-3629	22	38	mentioned	mention	VERB
iajs-3629	22	39	above	above	ADV
iajs-3629	22	40	(	(	PUNCT
iajs-3629	22	41	3	3	NUM
iajs-3629	22	42	)	)	PUNCT
iajs-3629	22	43	.	.	PUNCT
iajs-3629	23	1	flucloxacillin	flucloxacillin	NOUN
iajs-3629	23	2	,	,	PUNCT
iajs-3629	23	3	alternatively	alternatively	ADV
iajs-3629	23	4	referred	refer	VERB
iajs-3629	23	5	to	to	ADP
iajs-3629	23	6	as	as	ADP
iajs-3629	23	7	floxacillin	floxacillin	PROPN
iajs-3629	23	8	(	(	PUNCT
iajs-3629	23	9	flx	flx	NOUN
iajs-3629	23	10	)	)	PUNCT
iajs-3629	23	11	,	,	PUNCT
iajs-3629	23	12	is	be	AUX
iajs-3629	23	13	a	a	DET
iajs-3629	23	14	widely	widely	ADV
iajs-3629	23	15	utilized	utilize	VERB
iajs-3629	23	16	antibiotic	antibiotic	NOUN
iajs-3629	23	17	in	in	ADP
iajs-3629	23	18	treating	treat	VERB
iajs-3629	23	19	infections	infection	NOUN
iajs-3629	23	20	.	.	PUNCT
iajs-3629	24	1	its	its	PRON
iajs-3629	24	2	mechanism	mechanism	NOUN
iajs-3629	24	3	of	of	ADP
iajs-3629	24	4	action	action	NOUN
iajs-3629	24	5	involves	involve	VERB
iajs-3629	24	6	inhibiting	inhibit	VERB
iajs-3629	24	7	bacterial	bacterial	ADJ
iajs-3629	24	8	cell	cell	NOUN
iajs-3629	24	9	wall	wall	NOUN
iajs-3629	24	10	synthesis	synthesis	NOUN
iajs-3629	24	11	(	(	PUNCT
iajs-3629	24	12	4	4	NUM
iajs-3629	24	13	)	)	PUNCT
iajs-3629	24	14	.	.	PUNCT
iajs-3629	25	1	flucloxacillin	flucloxacillin	PROPN
iajs-3629	25	2	,	,	PUNCT
iajs-3629	25	3	a	a	DET
iajs-3629	25	4	β	β	NOUN
iajs-3629	25	5	-	-	NOUN
iajs-3629	25	6	lactam	lactam	ADJ
iajs-3629	25	7	antibiotic	antibiotic	NOUN
iajs-3629	25	8	,	,	PUNCT
iajs-3629	25	9	is	be	AUX
iajs-3629	25	10	commonly	commonly	ADV
iajs-3629	25	11	associated	associate	VERB
iajs-3629	25	12	with	with	ADP
iajs-3629	25	13	a	a	DET
iajs-3629	25	14	significant	significant	ADJ
iajs-3629	25	15	incidence	incidence	NOUN
iajs-3629	25	16	of	of	ADP
iajs-3629	25	17	drug	drug	NOUN
iajs-3629	25	18	-	-	PUNCT
iajs-3629	25	19	induced	induce	VERB
iajs-3629	25	20	cholestatic	cholestatic	ADJ
iajs-3629	25	21	liver	liver	NOUN
iajs-3629	25	22	damage	damage	NOUN
iajs-3629	25	23	.	.	PUNCT
iajs-3629	26	1	while	while	SCONJ
iajs-3629	26	2	the	the	DET
iajs-3629	26	3	precise	precise	ADJ
iajs-3629	26	4	pathogenic	pathogenic	ADJ
iajs-3629	26	5	mechanisms	mechanism	NOUN
iajs-3629	26	6	responsible	responsible	ADJ
iajs-3629	26	7	for	for	ADP
iajs-3629	26	8	developing	develop	VERB
iajs-3629	26	9	the	the	DET
iajs-3629	26	10	clinical	clinical	ADJ
iajs-3629	26	11	phenotype	phenotype	NOUN
iajs-3629	26	12	remain	remain	VERB
iajs-3629	26	13	unknown	unknown	ADJ
iajs-3629	26	14	,	,	PUNCT
iajs-3629	26	15	it	it	PRON
iajs-3629	26	16	is	be	AUX
iajs-3629	26	17	plausible	plausible	ADJ
iajs-3629	26	18	that	that	SCONJ
iajs-3629	26	19	both	both	DET
iajs-3629	26	20	immune	immune	NOUN
iajs-3629	26	21	-	-	PUNCT
iajs-3629	26	22	mediated	mediate	VERB
iajs-3629	26	23	and	and	CCONJ
iajs-3629	26	24	nonimmune	nonimmune	NOUN
iajs-3629	26	25	systems	system	NOUN
iajs-3629	26	26	play	play	VERB
iajs-3629	26	27	a	a	DET
iajs-3629	26	28	role	role	NOUN
iajs-3629	26	29	.	.	PUNCT
iajs-3629	27	1	forflucloxacillin	forflucloxacillin	ADJ
iajs-3629	27	2	-	-	PUNCT
iajs-3629	27	3	induced	induce	VERB
iajs-3629	27	4	cholestasis	cholestasis	NOUN
iajs-3629	27	5	,	,	PUNCT
iajs-3629	27	6	a	a	DET
iajs-3629	27	7	nonimmune	nonimmune	NOUN
iajs-3629	27	8	-	-	PUNCT
iajs-3629	27	9	mediated	mediate	VERB
iajs-3629	27	10	process	process	NOUN
iajs-3629	27	11	characterized	characterize	VERB
iajs-3629	27	12	by	by	ADP
iajs-3629	27	13	the	the	DET
iajs-3629	27	14	activation	activation	NOUN
iajs-3629	27	15	of	of	ADP
iajs-3629	27	16	hsp27	hsp27	NOUN
iajs-3629	27	17	and	and	CCONJ
iajs-3629	27	18	subsequent	subsequent	ADJ
iajs-3629	27	19	sequential	sequential	ADJ
iajs-3629	27	20	molecular	molecular	ADJ
iajs-3629	27	21	events	event	NOUN
iajs-3629	27	22	,	,	PUNCT
iajs-3629	27	23	has	have	AUX
iajs-3629	27	24	been	be	AUX
iajs-3629	27	25	documented	document	VERB
iajs-3629	27	26	(	(	PUNCT
iajs-3629	27	27	5	5	NUM
iajs-3629	27	28	)	)	PUNCT
iajs-3629	27	29	.	.	PUNCT
iajs-3629	28	1	it	it	PRON
iajs-3629	28	2	is	be	AUX
iajs-3629	28	3	especially	especially	ADV
iajs-3629	28	4	effective	effective	ADJ
iajs-3629	28	5	against	against	ADP
iajs-3629	28	6	benzylpenicillin	benzylpenicillin	NOUN
iajs-3629	28	7	-	-	PUNCT
iajs-3629	28	8	resistant	resistant	ADJ
iajs-3629	28	9	staphylococci	staphylococci	NOUN
iajs-3629	28	10	.	.	PUNCT
iajs-3629	29	1	this	this	DET
iajs-3629	29	2	category	category	NOUN
iajs-3629	29	3	includes	include	VERB
iajs-3629	29	4	infections	infection	NOUN
iajs-3629	29	5	of	of	ADP
iajs-3629	29	6	the	the	DET
iajs-3629	29	7	bones	bone	NOUN
iajs-3629	29	8	and	and	CCONJ
iajs-3629	29	9	joints	joint	NOUN
iajs-3629	29	10	,	,	PUNCT
iajs-3629	29	11	endocarditis	endocarditis	NOUN
iajs-3629	29	12	,	,	PUNCT
iajs-3629	29	13	and	and	CCONJ
iajs-3629	29	14	soft	soft	ADJ
iajs-3629	29	15	tissues	tissue	NOUN
iajs-3629	29	16	.	.	PUNCT
iajs-3629	30	1	in	in	ADP
iajs-3629	30	2	the	the	DET
iajs-3629	30	3	event	event	NOUN
iajs-3629	30	4	of	of	ADP
iajs-3629	30	5	a	a	DET
iajs-3629	30	6	known	know	VERB
iajs-3629	30	7	penicillin	penicillin	NOUN
iajs-3629	30	8	hypersensitivity	hypersensitivity	NOUN
iajs-3629	30	9	,	,	PUNCT
iajs-3629	30	10	it	it	PRON
iajs-3629	30	11	should	should	AUX
iajs-3629	30	12	be	be	AUX
iajs-3629	30	13	avoided	avoid	VERB
iajs-3629	30	14	.	.	PUNCT
iajs-3629	31	1	patients	patient	NOUN
iajs-3629	31	2	having	have	VERB
iajs-3629	31	3	a	a	DET
iajs-3629	31	4	history	history	NOUN
iajs-3629	31	5	of	of	ADP
iajs-3629	31	6	hepatic	hepatic	ADJ
iajs-3629	31	7	impairment	impairment	NOUN
iajs-3629	31	8	brought	bring	VERB
iajs-3629	31	9	on	on	ADP
iajs-3629	31	10	by	by	ADP
iajs-3629	31	11	flucloxacillin	flucloxacillin	NOUN
iajs-3629	31	12	should	should	AUX
iajs-3629	31	13	be	be	AUX
iajs-3629	31	14	avoided	avoid	VERB
iajs-3629	31	15	.	.	PUNCT
iajs-3629	32	1	in	in	ADP
iajs-3629	32	2	porphyria	porphyria	PROPN
iajs-3629	32	3	(	(	PUNCT
iajs-3629	32	4	associated	associate	VERB
iajs-3629	32	5	with	with	ADP
iajs-3629	32	6	acute	acute	ADJ
iajs-3629	32	7	attacks	attack	NOUN
iajs-3629	32	8	)	)	PUNCT
iajs-3629	32	9	,	,	PUNCT
iajs-3629	32	10	flucloxacillin	flucloxacillin	PROPN
iajs-3629	32	11	is	be	AUX
iajs-3629	32	12	considered	consider	VERB
iajs-3629	32	13	unsafe	unsafe	ADJ
iajs-3629	32	14	(	(	PUNCT
iajs-3629	32	15	6	6	NUM
iajs-3629	32	16	)	)	PUNCT
iajs-3629	32	17	.	.	PUNCT
iajs-3629	33	1	proline	proline	NOUN
iajs-3629	33	2	is	be	AUX
iajs-3629	33	3	a	a	DET
iajs-3629	33	4	non	non	ADJ
iajs-3629	33	5	-	-	ADJ
iajs-3629	33	6	essential	essential	ADJ
iajs-3629	33	7	amino	amino	NOUN
iajs-3629	33	8	acid	acid	NOUN
iajs-3629	33	9	that	that	SCONJ
iajs-3629	33	10	the	the	DET
iajs-3629	33	11	body	body	NOUN
iajs-3629	33	12	synthesizes	synthesize	VERB
iajs-3629	33	13	from	from	ADP
iajs-3629	33	14	glutamic	glutamic	ADJ
iajs-3629	33	15	acid	acid	NOUN
iajs-3629	33	16	.	.	PUNCT
iajs-3629	34	1	it	it	PRON
iajs-3629	34	2	is	be	AUX
iajs-3629	34	3	a	a	DET
iajs-3629	34	4	key	key	ADJ
iajs-3629	34	5	component	component	NOUN
iajs-3629	34	6	of	of	ADP
iajs-3629	34	7	proteins	protein	NOUN
iajs-3629	34	8	,	,	PUNCT
iajs-3629	34	9	especially	especially	ADV
iajs-3629	34	10	collagen	collagen	NOUN
iajs-3629	34	11	,	,	PUNCT
iajs-3629	34	12	supporting	support	VERB
iajs-3629	34	13	skin	skin	NOUN
iajs-3629	34	14	,	,	PUNCT
iajs-3629	34	15	tendons	tendon	NOUN
iajs-3629	34	16	,	,	PUNCT
iajs-3629	34	17	bones	bone	NOUN
iajs-3629	34	18	,	,	PUNCT
iajs-3629	34	19	and	and	CCONJ
iajs-3629	34	20	connective	connective	ADJ
iajs-3629	34	21	tissues	tissue	NOUN
iajs-3629	34	22	.	.	PUNCT
iajs-3629	35	1	vitamin	vitamin	NOUN
iajs-3629	35	2	c	c	NOUN
iajs-3629	35	3	enhances	enhance	VERB
iajs-3629	35	4	its	its	PRON
iajs-3629	35	5	production	production	NOUN
iajs-3629	35	6	and	and	CCONJ
iajs-3629	35	7	is	be	AUX
iajs-3629	35	8	found	find	VERB
iajs-3629	35	9	in	in	ADP
iajs-3629	35	10	citrus	citrus	NOUN
iajs-3629	35	11	fruits	fruit	NOUN
iajs-3629	35	12	,	,	PUNCT
iajs-3629	35	13	bell	bell	NOUN
iajs-3629	35	14	peppers	pepper	NOUN
iajs-3629	35	15	,	,	PUNCT
iajs-3629	35	16	and	and	CCONJ
iajs-3629	35	17	parsley	parsley	NOUN
iajs-3629	35	18	.	.	PUNCT
iajs-3629	36	1	proline	proline	NOUN
iajs-3629	36	2	-	-	PUNCT
iajs-3629	36	3	rich	rich	ADJ
iajs-3629	36	4	foods	food	NOUN
iajs-3629	36	5	include	include	VERB
iajs-3629	36	6	meat	meat	NOUN
iajs-3629	36	7	,	,	PUNCT
iajs-3629	36	8	fish	fish	NOUN
iajs-3629	36	9	,	,	PUNCT
iajs-3629	36	10	cabbage	cabbage	NOUN
iajs-3629	36	11	,	,	PUNCT
iajs-3629	36	12	soybeans	soybean	NOUN
iajs-3629	36	13	,	,	PUNCT
iajs-3629	36	14	and	and	CCONJ
iajs-3629	36	15	peanuts	peanut	NOUN
iajs-3629	36	16	.	.	PUNCT
iajs-3629	37	1	also	also	ADV
iajs-3629	37	2	known	know	VERB
iajs-3629	37	3	as	as	ADP
iajs-3629	37	4	pyrrolidine-2	pyrrolidine-2	NOUN
iajs-3629	37	5	-	-	ADJ
iajs-3629	37	6	carboxylic	carboxylic	ADJ
iajs-3629	37	7	acid	acid	NOUN
iajs-3629	37	8	,	,	PUNCT
iajs-3629	37	9	it	it	PRON
iajs-3629	37	10	is	be	AUX
iajs-3629	37	11	a	a	DET
iajs-3629	37	12	white	white	ADJ
iajs-3629	37	13	solid	solid	ADJ
iajs-3629	37	14	with	with	ADP
iajs-3629	37	15	a	a	DET
iajs-3629	37	16	molecular	molecular	ADJ
iajs-3629	37	17	weight	weight	NOUN
iajs-3629	37	18	of	of	ADP
iajs-3629	37	19	115.132	115.132	NUM
iajs-3629	37	20	g	g	NOUN
iajs-3629	37	21	/	/	SYM
iajs-3629	37	22	mole	mole	NOUN
iajs-3629	37	23	,	,	PUNCT
iajs-3629	37	24	a	a	DET
iajs-3629	37	25	melting	melting	NOUN
iajs-3629	37	26	point	point	NOUN
iajs-3629	37	27	of	of	ADP
iajs-3629	37	28	205	205	NUM
iajs-3629	37	29	-	-	SYM
iajs-3629	37	30	228	228	NUM
iajs-3629	37	31	°	°	NOUN
iajs-3629	37	32	c	c	NOUN
iajs-3629	37	33	,	,	PUNCT
iajs-3629	37	34	and	and	CCONJ
iajs-3629	37	35	a	a	DET
iajs-3629	37	36	molecular	molecular	ADJ
iajs-3629	37	37	formula	formula	NOUN
iajs-3629	37	38	of	of	ADP
iajs-3629	37	39	c5h9no2	c5h9no2	PROPN
iajs-3629	37	40	.	.	PROPN
iajs-3629	37	41	proline	proline	PROPN
iajs-3629	37	42	was	be	AUX
iajs-3629	37	43	first	first	ADV
iajs-3629	37	44	isolated	isolate	VERB
iajs-3629	37	45	in	in	ADP
iajs-3629	37	46	1900	1900	NUM
iajs-3629	37	47	by	by	ADP
iajs-3629	37	48	richard	richard	PROPN
iajs-3629	37	49	willstätter	willstätter	NOUN
iajs-3629	37	50	(	(	PUNCT
iajs-3629	37	51	7,9	7,9	NUM
iajs-3629	37	52	)	)	PUNCT
iajs-3629	37	53	.	.	PUNCT
iajs-3629	38	1	this	this	DET
iajs-3629	38	2	study	study	NOUN
iajs-3629	38	3	aims	aim	VERB
iajs-3629	38	4	to	to	PART
iajs-3629	38	5	synthesize	synthesize	VERB
iajs-3629	38	6	and	and	CCONJ
iajs-3629	38	7	characterize	characterize	VERB
iajs-3629	38	8	mixed	mixed	ADJ
iajs-3629	38	9	ligand	ligand	ADJ
iajs-3629	38	10	complexes	complex	NOUN
iajs-3629	38	11	of	of	ADP
iajs-3629	38	12	flucloxacillin	flucloxacillin	NOUN
iajs-3629	38	13	and	and	CCONJ
iajs-3629	38	14	proline	proline	NOUN
iajs-3629	38	15	with	with	ADP
iajs-3629	38	16	transition	transition	NOUN
iajs-3629	38	17	metals	metal	NOUN
iajs-3629	38	18	(	(	PUNCT
iajs-3629	38	19	coii	coii	PROPN
iajs-3629	38	20	,	,	PUNCT
iajs-3629	38	21	niii	niii	NOUN
iajs-3629	38	22	,	,	PUNCT
iajs-3629	38	23	cuii	cuii	ADJ
iajs-3629	38	24	,	,	PUNCT
iajs-3629	38	25	znii	znii	NOUN
iajs-3629	38	26	,	,	PUNCT
iajs-3629	38	27	cdii	cdii	NOUN
iajs-3629	38	28	)	)	PUNCT
iajs-3629	38	29	.	.	PUNCT
iajs-3629	39	1	it	it	PRON
iajs-3629	39	2	examines	examine	VERB
iajs-3629	39	3	their	their	PRON
iajs-3629	39	4	coordination	coordination	NOUN
iajs-3629	39	5	behavior	behavior	NOUN
iajs-3629	39	6	,	,	PUNCT
iajs-3629	39	7	structural	structural	ADJ
iajs-3629	39	8	and	and	CCONJ
iajs-3629	39	9	electronic	electronic	ADJ
iajs-3629	39	10	properties	property	NOUN
iajs-3629	39	11	,	,	PUNCT
iajs-3629	39	12	and	and	CCONJ
iajs-3629	39	13	biological	biological	ADJ
iajs-3629	39	14	activities	activity	NOUN
iajs-3629	39	15	,	,	PUNCT
iajs-3629	39	16	especially	especially	ADV
iajs-3629	39	17	antibacterial	antibacterial	ADJ
iajs-3629	39	18	and	and	CCONJ
iajs-3629	39	19	antifungal	antifungal	ADJ
iajs-3629	39	20	effects	effect	NOUN
iajs-3629	39	21	.	.	PUNCT
iajs-3629	40	1	hyperchem	hyperchem	PROPN
iajs-3629	40	2	software	software	NOUN
iajs-3629	40	3	is	be	AUX
iajs-3629	40	4	used	use	VERB
iajs-3629	40	5	for	for	ADP
iajs-3629	40	6	theoretical	theoretical	ADJ
iajs-3629	40	7	calculations	calculation	NOUN
iajs-3629	40	8	on	on	ADP
iajs-3629	40	9	stability	stability	NOUN
iajs-3629	40	10	and	and	CCONJ
iajs-3629	40	11	electronic	electronic	ADJ
iajs-3629	40	12	configuration	configuration	NOUN
iajs-3629	40	13	.	.	PUNCT
iajs-3629	41	1	2	2	X
iajs-3629	41	2	.	.	X
iajs-3629	41	3	materials	material	NOUN
iajs-3629	41	4	and	and	CCONJ
iajs-3629	41	5	methods	method	NOUN
iajs-3629	41	6	2.1	2.1	NUM
iajs-3629	41	7	.	.	PUNCT
iajs-3629	42	1	instrumentation	instrumentation	NOUN
iajs-3629	42	2	electrical	electrical	ADJ
iajs-3629	42	3	conductivity	conductivity	NOUN
iajs-3629	42	4	measurements	measurement	NOUN
iajs-3629	42	5	of	of	ADP
iajs-3629	42	6	the	the	DET
iajs-3629	42	7	complexes	complex	NOUN
iajs-3629	42	8	were	be	AUX
iajs-3629	42	9	made	make	VERB
iajs-3629	42	10	with	with	ADP
iajs-3629	42	11	10–3	10–3	PROPN
iajs-3629	42	12	m	m	NOUN
iajs-3629	42	13	of	of	ADP
iajs-3629	42	14	dmf	dmf	PROPN
iajs-3629	42	15	solvent	solvent	NOUN
iajs-3629	42	16	and	and	CCONJ
iajs-3629	42	17	with	with	ADP
iajs-3629	42	18	the	the	DET
iajs-3629	42	19	temperature	temperature	NOUN
iajs-3629	42	20	of	of	ADP
iajs-3629	42	21	the	the	DET
iajs-3629	42	22	laboratory	laboratory	NOUN
iajs-3629	42	23	in	in	ADP
iajs-3629	42	24	the	the	DET
iajs-3629	42	25	laboratories	laboratory	NOUN
iajs-3629	42	26	of	of	ADP
iajs-3629	42	27	the	the	DET
iajs-3629	42	28	department	department	NOUN
iajs-3629	42	29	of	of	ADP
iajs-3629	42	30	chemistry	chemistry	NOUN
iajs-3629	42	31	,	,	PUNCT
iajs-3629	42	32	college	college	NOUN
iajs-3629	42	33	of	of	ADP
iajs-3629	42	34	science	science	NOUN
iajs-3629	42	35	for	for	ADP
iajs-3629	42	36	women	woman	NOUN
iajs-3629	42	37	,	,	PUNCT
iajs-3629	42	38	university	university	NOUN
iajs-3629	42	39	of	of	ADP
iajs-3629	42	40	baghdad	baghdad	PROPN
iajs-3629	42	41	.	.	PUNCT
iajs-3629	43	1	the	the	DET
iajs-3629	43	2	melting	melting	NOUN
iajs-3629	43	3	point	point	NOUN
iajs-3629	43	4	of	of	ADP
iajs-3629	43	5	the	the	DET
iajs-3629	43	6	prepared	prepare	VERB
iajs-3629	43	7	ligands	ligand	NOUN
iajs-3629	43	8	and	and	CCONJ
iajs-3629	43	9	complexes	complex	NOUN
iajs-3629	43	10	was	be	AUX
iajs-3629	43	11	measured	measure	VERB
iajs-3629	43	12	using	use	VERB
iajs-3629	43	13	the	the	DET
iajs-3629	43	14	gallen	gallen	PROPN
iajs-3629	43	15	kamp	kamp	PROPN
iajs-3629	43	16	m.f.b-60	m.f.b-60	PROPN
iajs-3629	43	17	thermoelectric	thermoelectric	ADJ
iajs-3629	43	18	melting	melting	NOUN
iajs-3629	43	19	device	device	NOUN
iajs-3629	43	20	in	in	ADP
iajs-3629	43	21	the	the	DET
iajs-3629	43	22	department	department	NOUN
iajs-3629	43	23	of	of	ADP
iajs-3629	43	24	chemistry/	chemistry/	NUM
iajs-3629	43	25	college	college	NOUN
iajs-3629	43	26	of	of	ADP
iajs-3629	43	27	science	science	NOUN
iajs-3629	43	28	for	for	ADP
iajs-3629	43	29	women/	women/	NUM
iajs-3629	43	30	university	university	NOUN
iajs-3629	43	31	of	of	ADP
iajs-3629	43	32	baghdad	baghdad	PROPN
iajs-3629	43	33	laboratory	laboratory	NOUN
iajs-3629	43	34	.	.	PUNCT
iajs-3629	44	1	the	the	DET
iajs-3629	44	2	electronic	electronic	ADJ
iajs-3629	44	3	spectra	spectra	NOUN
iajs-3629	44	4	of	of	ADP
iajs-3629	44	5	the	the	DET
iajs-3629	44	6	ligands	ligand	NOUN
iajs-3629	44	7	and	and	CCONJ
iajs-3629	44	8	their	their	PRON
iajs-3629	44	9	ion	ion	NOUN
iajs-3629	44	10	metal	metal	NOUN
iajs-3629	44	11	complexes	complex	NOUN
iajs-3629	44	12	were	be	AUX
iajs-3629	44	13	recorded	record	VERB
iajs-3629	44	14	on	on	ADP
iajs-3629	44	15	an	an	DET
iajs-3629	44	16	1800	1800	NUM
iajs-3629	44	17	-	-	PUNCT
iajs-3629	44	18	uv	uv	NOUN
iajs-3629	44	19	shimadzu	shimadzu	ADJ
iajs-3629	44	20	spectrophotometer	spectrophotometer	NOUN
iajs-3629	44	21	in	in	ADP
iajs-3629	44	22	the	the	DET
iajs-3629	44	23	range	range	NOUN
iajs-3629	44	24	of	of	ADP
iajs-3629	44	25	200	200	NUM
iajs-3629	44	26	–	–	SYM
iajs-3629	44	27	1100	1100	NUM
iajs-3629	44	28	nm	nm	NOUN
iajs-3629	44	29	using	use	VERB
iajs-3629	44	30	concentration	concentration	NOUN
iajs-3629	44	31	10–3	10–3	PROPN
iajs-3629	44	32	m	m	NOUN
iajs-3629	44	33	by	by	ADV
iajs-3629	44	34	and	and	CCONJ
iajs-3629	44	35	dmf	dmf	PROPN
iajs-3629	44	36	as	as	ADP
iajs-3629	44	37	a	a	DET
iajs-3629	44	38	solvent	solvent	NOUN
iajs-3629	44	39	at	at	ADP
iajs-3629	44	40	the	the	DET
iajs-3629	44	41	laboratories	laboratory	NOUN
iajs-3629	44	42	of	of	ADP
iajs-3629	44	43	the	the	DET
iajs-3629	44	44	department	department	NOUN
iajs-3629	44	45	of	of	ADP
iajs-3629	44	46	chemistry	chemistry	NOUN
iajs-3629	44	47	,	,	PUNCT
iajs-3629	44	48	college	college	NOUN
iajs-3629	44	49	of	of	ADP
iajs-3629	44	50	science	science	NOUN
iajs-3629	44	51	,	,	PUNCT
iajs-3629	44	52	university	university	NOUN
iajs-3629	44	53	of	of	ADP
iajs-3629	44	54	baghdad	baghdad	PROPN
iajs-3629	44	55	.	.	PUNCT
iajs-3629	45	1	infrared	infrared	PROPN
iajs-3629	45	2	spectra	spectra	NOUN
iajs-3629	45	3	of	of	ADP
iajs-3629	45	4	ihjpas	ihjpas	PROPN
iajs-3629	45	5	.	.	PUNCT
iajs-3629	46	1	2025,38(2	2025,38(2	PROPN
iajs-3629	46	2	)	)	PUNCT
iajs-3629	46	3	251	251	NUM
iajs-3629	46	4	ligand	ligand	NOUN
iajs-3629	46	5	in	in	ADP
iajs-3629	46	6	and	and	CCONJ
iajs-3629	46	7	their	their	PRON
iajs-3629	46	8	complexes	complex	NOUN
iajs-3629	46	9	were	be	AUX
iajs-3629	46	10	recorded	record	VERB
iajs-3629	46	11	using	use	VERB
iajs-3629	46	12	a	a	DET
iajs-3629	46	13	device	device	NOUN
iajs-3629	46	14	of	of	ADP
iajs-3629	46	15	the	the	DET
iajs-3629	46	16	type	type	NOUN
iajs-3629	46	17	(	(	PUNCT
iajs-3629	46	18	ir	ir	PROPN
iajs-3629	46	19	prestige-21	prestige-21	PROPN
iajs-3629	46	20	,	,	PUNCT
iajs-3629	46	21	single	single	ADJ
iajs-3629	46	22	beam	beam	NOUN
iajs-3629	46	23	path	path	NOUN
iajs-3629	46	24	)	)	PUNCT
iajs-3629	46	25	fourier	fourier	NOUN
iajs-3629	46	26	transform	transform	VERB
iajs-3629	46	27	infrared	infrared	ADJ
iajs-3629	46	28	spectrophotometer	spectrophotometer	NOUN
iajs-3629	46	29	(	(	PUNCT
iajs-3629	46	30	shimdizu	shimdizu	PROPN
iajs-3629	46	31	)	)	PUNCT
iajs-3629	46	32	using	use	VERB
iajs-3629	46	33	a	a	DET
iajs-3629	46	34	csi	csi	ADJ
iajs-3629	46	35	disk	disk	NOUN
iajs-3629	46	36	within	within	ADP
iajs-3629	46	37	the	the	DET
iajs-3629	46	38	range	range	NOUN
iajs-3629	46	39	(	(	PUNCT
iajs-3629	46	40	200	200	NUM
iajs-3629	46	41	-	-	SYM
iajs-3629	46	42	4000	4000	NUM
iajs-3629	46	43	)	)	PUNCT
iajs-3629	46	44	cm-1	cm-1	VERB
iajs-3629	46	45	at	at	ADP
iajs-3629	46	46	central	central	ADJ
iajs-3629	46	47	environmental	environmental	ADJ
iajs-3629	46	48	laboratories	laboratory	NOUN
iajs-3629	46	49	,	,	PUNCT
iajs-3629	46	50	department	department	NOUN
iajs-3629	46	51	of	of	ADP
iajs-3629	46	52	chemistry/	chemistry/	NUM
iajs-3629	46	53	college	college	NOUN
iajs-3629	46	54	of	of	ADP
iajs-3629	46	55	science/	science/	NUM
iajs-3629	46	56	university	university	NOUN
iajs-3629	46	57	of	of	ADP
iajs-3629	46	58	baghdad	baghdad	PROPN
iajs-3629	46	59	.	.	PUNCT
iajs-3629	47	1	the	the	DET
iajs-3629	47	2	prepared	prepare	VERB
iajs-3629	47	3	ligands	ligand	NOUN
iajs-3629	47	4	'	'	PART
iajs-3629	47	5	1h	1h	NUM
iajs-3629	47	6	-	-	PUNCT
iajs-3629	47	7	nmr	nmr	NOUN
iajs-3629	47	8	nuclear	nuclear	ADJ
iajs-3629	47	9	magnetic	magnetic	ADJ
iajs-3629	47	10	resonance	resonance	NOUN
iajs-3629	47	11	spectra	spectra	NOUN
iajs-3629	47	12	were	be	AUX
iajs-3629	47	13	recorded	record	VERB
iajs-3629	47	14	using	use	VERB
iajs-3629	47	15	a	a	DET
iajs-3629	47	16	bruker	bruker	ADJ
iajs-3629	47	17	avance	avance	NOUN
iajs-3629	47	18	500	500	NUM
iajs-3629	47	19	mhz	mhz	ADJ
iajs-3629	47	20	nmr	nmr	NOUN
iajs-3629	47	21	spectrometer	spectrometer	NOUN
iajs-3629	47	22	.	.	PUNCT
iajs-3629	48	1	the	the	DET
iajs-3629	48	2	measurements	measurement	NOUN
iajs-3629	48	3	were	be	AUX
iajs-3629	48	4	carried	carry	VERB
iajs-3629	48	5	out	out	ADP
iajs-3629	48	6	at	at	ADP
iajs-3629	48	7	the	the	DET
iajs-3629	48	8	university	university	NOUN
iajs-3629	48	9	of	of	ADP
iajs-3629	48	10	tehran/	tehran/	NUM
iajs-3629	48	11	iran	iran	PROPN
iajs-3629	48	12	using	use	VERB
iajs-3629	48	13	dmso	dmso	NOUN
iajs-3629	48	14	as	as	ADP
iajs-3629	48	15	a	a	DET
iajs-3629	48	16	solvent	solvent	NOUN
iajs-3629	48	17	and	and	CCONJ
iajs-3629	48	18	tms	tms	PROPN
iajs-3629	48	19	as	as	ADP
iajs-3629	48	20	an	an	DET
iajs-3629	48	21	internal	internal	ADJ
iajs-3629	48	22	source	source	NOUN
iajs-3629	48	23	.	.	PUNCT
iajs-3629	49	1	a	a	DET
iajs-3629	49	2	study	study	NOUN
iajs-3629	49	3	of	of	ADP
iajs-3629	49	4	the	the	DET
iajs-3629	49	5	biological	biological	ADJ
iajs-3629	49	6	activity	activity	NOUN
iajs-3629	49	7	of	of	ADP
iajs-3629	49	8	each	each	PRON
iajs-3629	49	9	of	of	ADP
iajs-3629	49	10	the	the	DET
iajs-3629	49	11	metal	metal	NOUN
iajs-3629	49	12	salts	salt	NOUN
iajs-3629	49	13	,	,	PUNCT
iajs-3629	49	14	ligands	ligand	NOUN
iajs-3629	49	15	,	,	PUNCT
iajs-3629	49	16	and	and	CCONJ
iajs-3629	49	17	complexes	complex	NOUN
iajs-3629	49	18	prepared	prepare	VERB
iajs-3629	49	19	on	on	ADP
iajs-3629	49	20	special	special	ADJ
iajs-3629	49	21	types	type	NOUN
iajs-3629	49	22	of	of	ADP
iajs-3629	49	23	positive	positive	ADJ
iajs-3629	49	24	and	and	CCONJ
iajs-3629	49	25	negative	negative	ADJ
iajs-3629	49	26	bacteria	bacteria	NOUN
iajs-3629	49	27	and	and	CCONJ
iajs-3629	49	28	fungi	fungus	NOUN
iajs-3629	49	29	.	.	PUNCT
iajs-3629	50	1	the	the	DET
iajs-3629	50	2	tests	test	NOUN
iajs-3629	50	3	were	be	AUX
iajs-3629	50	4	conducted	conduct	VERB
iajs-3629	50	5	in	in	ADP
iajs-3629	50	6	the	the	DET
iajs-3629	50	7	laboratory	laboratory	NOUN
iajs-3629	50	8	of	of	ADP
iajs-3629	50	9	bpc	bpc	PROPN
iajs-3629	50	10	analysis	analysis	NOUN
iajs-3629	50	11	center/	center/	PROPN
iajs-3629	50	12	iraq	iraq	PROPN
iajs-3629	50	13	-	-	PUNCT
iajs-3629	50	14	baghdad	baghdad	PROPN
iajs-3629	50	15	.	.	PUNCT
iajs-3629	51	1	2.2	2.2	NUM
iajs-3629	51	2	.	.	PUNCT
iajs-3629	51	3	materials	material	NOUN
iajs-3629	51	4	all	all	DET
iajs-3629	51	5	materials	material	NOUN
iajs-3629	51	6	used	use	VERB
iajs-3629	51	7	in	in	ADP
iajs-3629	51	8	the	the	DET
iajs-3629	51	9	research	research	NOUN
iajs-3629	51	10	are	be	AUX
iajs-3629	51	11	supplied	supply	VERB
iajs-3629	51	12	by	by	ADP
iajs-3629	51	13	fluka	fluka	NOUN
iajs-3629	51	14	,	,	PUNCT
iajs-3629	51	15	with	with	ADP
iajs-3629	51	16	a	a	DET
iajs-3629	51	17	purity	purity	NOUN
iajs-3629	51	18	of	of	ADP
iajs-3629	51	19	99	99	NUM
iajs-3629	51	20	%	%	NOUN
iajs-3629	51	21	(	(	PUNCT
iajs-3629	51	22	methanol	methanol	NOUN
iajs-3629	51	23	,	,	PUNCT
iajs-3629	51	24	ethanol	ethanol	NOUN
iajs-3629	51	25	,	,	PUNCT
iajs-3629	51	26	cocl2.6h2o	cocl2.6h2o	NOUN
iajs-3629	51	27	,	,	PUNCT
iajs-3629	51	28	nicl2.6h2o	nicl2.6h2o	NOUN
iajs-3629	51	29	,	,	PUNCT
iajs-3629	51	30	cucl2.6h2o	cucl2.6h2o	NOUN
iajs-3629	51	31	,	,	PUNCT
iajs-3629	51	32	zncl2.6h2o	zncl2.6h2o	NOUN
iajs-3629	51	33	,	,	PUNCT
iajs-3629	51	34	cdcl2.6h2o	cdcl2.6h2o	NOUN
iajs-3629	51	35	,	,	PUNCT
iajs-3629	51	36	naoh	naoh	NOUN
iajs-3629	51	37	,	,	PUNCT
iajs-3629	51	38	h2so4	h2so4	NOUN
iajs-3629	51	39	,	,	PUNCT
iajs-3629	51	40	proline	proline	NOUN
iajs-3629	51	41	,	,	PUNCT
iajs-3629	51	42	dmf	dmf	PROPN
iajs-3629	51	43	,	,	PUNCT
iajs-3629	51	44	dmso	dmso	NOUN
iajs-3629	51	45	)	)	PUNCT
iajs-3629	51	46	.	.	PUNCT
iajs-3629	52	1	2.3	2.3	NUM
iajs-3629	52	2	.	.	PUNCT
iajs-3629	52	3	preparation	preparation	NOUN
iajs-3629	52	4	of	of	ADP
iajs-3629	52	5	mixed	mixed	ADJ
iajs-3629	52	6	ligand	ligand	NOUN
iajs-3629	52	7	flucloxacillin	flucloxacillin	PROPN
iajs-3629	52	8	derivative	derivative	NOUN
iajs-3629	52	9	was	be	AUX
iajs-3629	52	10	prepared	prepare	VERB
iajs-3629	52	11	by	by	ADP
iajs-3629	52	12	dissolving	dissolve	VERB
iajs-3629	52	13	the	the	DET
iajs-3629	52	14	drug	drug	NOUN
iajs-3629	52	15	(	(	PUNCT
iajs-3629	52	16	0.4	0.4	NUM
iajs-3629	52	17	g	g	NOUN
iajs-3629	52	18	)	)	PUNCT
iajs-3629	52	19	in	in	ADP
iajs-3629	52	20	(	(	PUNCT
iajs-3629	52	21	35	35	NUM
iajs-3629	52	22	ml	ml	NOUN
iajs-3629	52	23	)	)	PUNCT
iajs-3629	52	24	methanol	methanol	NOUN
iajs-3629	52	25	with	with	ADP
iajs-3629	52	26	drops	drop	NOUN
iajs-3629	52	27	of	of	ADP
iajs-3629	52	28	concentrated	concentrated	ADJ
iajs-3629	52	29	sulfuric	sulfuric	NOUN
iajs-3629	52	30	acid	acid	NOUN
iajs-3629	52	31	to	to	PART
iajs-3629	52	32	convert	convert	VERB
iajs-3629	52	33	the	the	DET
iajs-3629	52	34	cooh	cooh	NOUN
iajs-3629	52	35	group	group	NOUN
iajs-3629	52	36	to	to	ADP
iajs-3629	52	37	och3	och3	VERB
iajs-3629	52	38	.	.	PUNCT
iajs-3629	53	1	about	about	ADV
iajs-3629	53	2	0.11	0.11	NUM
iajs-3629	53	3	g	g	NOUN
iajs-3629	53	4	of	of	ADP
iajs-3629	53	5	proline	proline	NOUN
iajs-3629	53	6	was	be	AUX
iajs-3629	53	7	reacted	react	VERB
iajs-3629	53	8	with	with	ADP
iajs-3629	53	9	(	(	PUNCT
iajs-3629	53	10	0.04	0.04	NUM
iajs-3629	53	11	g	g	NOUN
iajs-3629	53	12	)	)	PUNCT
iajs-3629	53	13	sodium	sodium	NOUN
iajs-3629	53	14	hydroxide	hydroxide	NOUN
iajs-3629	53	15	(	(	PUNCT
iajs-3629	53	16	naoh	naoh	NOUN
iajs-3629	53	17	)	)	PUNCT
iajs-3629	53	18	to	to	PART
iajs-3629	53	19	prepare	prepare	VERB
iajs-3629	53	20	(	(	PUNCT
iajs-3629	53	21	flx	flx	NOUN
iajs-3629	53	22	)	)	PUNCT
iajs-3629	53	23	salt	salt	NOUN
iajs-3629	53	24	.	.	PUNCT
iajs-3629	54	1	2.4	2.4	NUM
iajs-3629	54	2	.	.	PUNCT
iajs-3629	54	3	preparation	preparation	NOUN
iajs-3629	54	4	of	of	ADP
iajs-3629	54	5	mixed	mixed	ADJ
iajs-3629	54	6	ligand	ligand	NOUN
iajs-3629	54	7	complexes	complexe	VERB
iajs-3629	54	8	one	one	NUM
iajs-3629	54	9	mmol	mmol	NOUN
iajs-3629	54	10	of	of	ADP
iajs-3629	54	11	flucloxacillin	flucloxacillin	NOUN
iajs-3629	54	12	(	(	PUNCT
iajs-3629	54	13	l	l	NOUN
iajs-3629	54	14	)	)	PUNCT
iajs-3629	54	15	dissolved	dissolve	VERB
iajs-3629	54	16	with	with	ADP
iajs-3629	54	17	(	(	PUNCT
iajs-3629	54	18	1	1	NUM
iajs-3629	54	19	mmol	mmol	NOUN
iajs-3629	54	20	)	)	PUNCT
iajs-3629	54	21	proline	proline	NOUN
iajs-3629	54	22	,	,	PUNCT
iajs-3629	54	23	formed	form	VERB
iajs-3629	54	24	(	(	PUNCT
iajs-3629	54	25	l	l	NOUN
iajs-3629	54	26	-	-	ADJ
iajs-3629	54	27	pro	pro	ADJ
iajs-3629	54	28	)	)	PUNCT
iajs-3629	54	29	,	,	PUNCT
iajs-3629	54	30	which	which	PRON
iajs-3629	54	31	reacted	react	VERB
iajs-3629	54	32	with	with	ADP
iajs-3629	54	33	the	the	DET
iajs-3629	54	34	salts	salt	NOUN
iajs-3629	54	35	of	of	ADP
iajs-3629	54	36	the	the	DET
iajs-3629	54	37	elements	element	NOUN
iajs-3629	54	38	(	(	PUNCT
iajs-3629	54	39	0.2	0.2	NUM
iajs-3629	54	40	g	g	NOUN
iajs-3629	54	41	)	)	PUNCT
iajs-3629	54	42	cdcl2.6h2o	cdcl2.6h2o	NOUN
iajs-3629	54	43	,	,	PUNCT
iajs-3629	54	44	(	(	PUNCT
iajs-3629	54	45	0.23	0.23	NUM
iajs-3629	54	46	g	g	NOUN
iajs-3629	54	47	)	)	PUNCT
iajs-3629	54	48	cocl2.6h2o	cocl2.6h2o	NOUN
iajs-3629	54	49	,	,	PUNCT
iajs-3629	54	50	(	(	PUNCT
iajs-3629	54	51	0.23	0.23	NUM
iajs-3629	54	52	g	g	NOUN
iajs-3629	54	53	)	)	PUNCT
iajs-3629	54	54	nicl2.6h2o	nicl2.6h2o	NOUN
iajs-3629	54	55	,	,	PUNCT
iajs-3629	54	56	(	(	PUNCT
iajs-3629	54	57	0.17	0.17	NUM
iajs-3629	54	58	g	g	NOUN
iajs-3629	54	59	)	)	PUNCT
iajs-3629	54	60	cucl2.6h2o	cucl2.6h2o	NOUN
iajs-3629	54	61	,	,	PUNCT
iajs-3629	54	62	(	(	PUNCT
iajs-3629	54	63	0.24	0.24	NUM
iajs-3629	54	64	g	g	NOUN
iajs-3629	54	65	)	)	PUNCT
iajs-3629	54	66	zncl2.6h2o	zncl2.6h2o	NUM
iajs-3629	54	67	)	)	PUNCT
iajs-3629	54	68	for	for	ADP
iajs-3629	54	69	the	the	DET
iajs-3629	54	70	preparation	preparation	NOUN
iajs-3629	54	71	of	of	ADP
iajs-3629	54	72	the	the	DET
iajs-3629	54	73	ligand	ligand	NOUN
iajs-3629	54	74	complexes	complex	NOUN
iajs-3629	54	75	(	(	PUNCT
iajs-3629	54	76	l	l	NOUN
iajs-3629	54	77	-	-	ADJ
iajs-3629	54	78	pro	pro	ADJ
iajs-3629	54	79	)	)	PUNCT
iajs-3629	54	80	(	(	PUNCT
iajs-3629	54	81	preparation	preparation	NOUN
iajs-3629	54	82	ratio	ratio	NOUN
iajs-3629	54	83	l	l	NOUN
iajs-3629	54	84	:	:	PUNCT
iajs-3629	54	85	proline	proline	NOUN
iajs-3629	54	86	:	:	PUNCT
iajs-3629	54	87	m	m	VERB
iajs-3629	54	88	1:1:1	1:1:1	NUM
iajs-3629	54	89	)	)	PUNCT
iajs-3629	54	90	.	.	PUNCT
iajs-3629	55	1	3	3	X
iajs-3629	55	2	.	.	NOUN
iajs-3629	55	3	results	result	NOUN
iajs-3629	55	4	and	and	CCONJ
iajs-3629	55	5	discussion	discussion	NOUN
iajs-3629	55	6	the	the	DET
iajs-3629	55	7	complexes	complex	NOUN
iajs-3629	55	8	are	be	AUX
iajs-3629	55	9	characterized	characterize	VERB
iajs-3629	55	10	by	by	ADP
iajs-3629	55	11	their	their	PRON
iajs-3629	55	12	stability	stability	NOUN
iajs-3629	55	13	at	at	ADP
iajs-3629	55	14	room	room	NOUN
iajs-3629	55	15	temperature	temperature	NOUN
iajs-3629	55	16	and	and	CCONJ
iajs-3629	55	17	distinct	distinct	ADJ
iajs-3629	55	18	melting	melting	NOUN
iajs-3629	55	19	points	point	NOUN
iajs-3629	55	20	and	and	CCONJ
iajs-3629	55	21	colors	color	NOUN
iajs-3629	55	22	.	.	PUNCT
iajs-3629	56	1	the	the	DET
iajs-3629	56	2	chloride	chloride	PROPN
iajs-3629	56	3	content	content	NOUN
iajs-3629	56	4	of	of	ADP
iajs-3629	56	5	the	the	DET
iajs-3629	56	6	prepared	prepared	ADJ
iajs-3629	56	7	complexes	complex	NOUN
iajs-3629	56	8	was	be	AUX
iajs-3629	56	9	measured	measure	VERB
iajs-3629	56	10	using	use	VERB
iajs-3629	56	11	the	the	DET
iajs-3629	56	12	moore	moore	NOUN
iajs-3629	56	13	-	-	PUNCT
iajs-3629	56	14	titro	titro	ADJ
iajs-3629	56	15	processor	processor	NOUN
iajs-3629	56	16	method	method	NOUN
iajs-3629	56	17	in	in	ADP
iajs-3629	56	18	ibn	ibn	PROPN
iajs-3629	56	19	sina	sina	PROPN
iajs-3629	56	20	laboratories	laboratory	NOUN
iajs-3629	56	21	in	in	ADP
iajs-3629	56	22	baghdad	baghdad	PROPN
iajs-3629	56	23	.	.	PUNCT
iajs-3629	57	1	the	the	DET
iajs-3629	57	2	physical	physical	ADJ
iajs-3629	57	3	properties	property	NOUN
iajs-3629	57	4	are	be	AUX
iajs-3629	57	5	illustrated	illustrate	VERB
iajs-3629	57	6	in	in	ADP
iajs-3629	57	7	table	table	NOUN
iajs-3629	57	8	1	1	NUM
iajs-3629	57	9	.	.	SYM
iajs-3629	57	10	3.1	3.1	NUM
iajs-3629	57	11	.	.	PUNCT
iajs-3629	58	1	infrared	infrared	ADJ
iajs-3629	58	2	spectra	spectra	NOUN
iajs-3629	58	3	of	of	ADP
iajs-3629	58	4	the	the	DET
iajs-3629	58	5	complexes	complex	NOUN
iajs-3629	58	6	prepared	prepare	VERB
iajs-3629	58	7	from	from	ADP
iajs-3629	58	8	the	the	DET
iajs-3629	58	9	first	first	ADJ
iajs-3629	58	10	mixed	mixed	ADJ
iajs-3629	58	11	ligand	ligand	NOUN
iajs-3629	58	12	the	the	DET
iajs-3629	58	13	band	band	NOUN
iajs-3629	58	14	seen	see	VERB
iajs-3629	58	15	at	at	ADP
iajs-3629	58	16	a	a	DET
iajs-3629	58	17	wave	wave	NOUN
iajs-3629	58	18	number	number	NOUN
iajs-3629	58	19	of	of	ADP
iajs-3629	58	20	1735	1735	NUM
iajs-3629	58	21	cm-1	cm-1	NOUN
iajs-3629	58	22	,	,	PUNCT
iajs-3629	58	23	corresponding	correspond	VERB
iajs-3629	58	24	to	to	ADP
iajs-3629	58	25	the	the	DET
iajs-3629	58	26	β	β	NOUN
iajs-3629	58	27	-	-	PUNCT
iajs-3629	58	28	lactam	lactam	NOUN
iajs-3629	58	29	carbonyl	carbonyl	NOUN
iajs-3629	58	30	group	group	NOUN
iajs-3629	58	31	(	(	PUNCT
iajs-3629	58	32	c	c	NOUN
iajs-3629	58	33	=	=	NOUN
iajs-3629	58	34	o	o	NOUN
iajs-3629	58	35	)	)	PUNCT
iajs-3629	58	36	in	in	ADP
iajs-3629	58	37	the	the	DET
iajs-3629	58	38	ligand	ligand	NOUN
iajs-3629	58	39	,	,	PUNCT
iajs-3629	58	40	remains	remain	VERB
iajs-3629	58	41	unaltered	unaltered	ADJ
iajs-3629	58	42	in	in	ADP
iajs-3629	58	43	all	all	DET
iajs-3629	58	44	complexes	complex	NOUN
iajs-3629	58	45	.	.	PUNCT
iajs-3629	59	1	it	it	PRON
iajs-3629	59	2	is	be	AUX
iajs-3629	59	3	important	important	ADJ
iajs-3629	59	4	to	to	PART
iajs-3629	59	5	note	note	VERB
iajs-3629	59	6	that	that	SCONJ
iajs-3629	59	7	the	the	DET
iajs-3629	59	8	oxygen	oxygen	NOUN
iajs-3629	59	9	atom	atom	NOUN
iajs-3629	59	10	of	of	ADP
iajs-3629	59	11	the	the	DET
iajs-3629	59	12	carbonyl	carbonyl	NOUN
iajs-3629	59	13	group	group	NOUN
iajs-3629	59	14	does	do	AUX
iajs-3629	59	15	not	not	PART
iajs-3629	59	16	participate	participate	VERB
iajs-3629	59	17	in	in	ADP
iajs-3629	59	18	any	any	DET
iajs-3629	59	19	coordination	coordination	NOUN
iajs-3629	59	20	interactions	interaction	NOUN
iajs-3629	59	21	.	.	PUNCT
iajs-3629	60	1	in	in	ADP
iajs-3629	60	2	contrast	contrast	NOUN
iajs-3629	60	3	,	,	PUNCT
iajs-3629	60	4	the	the	DET
iajs-3629	60	5	participation	participation	NOUN
iajs-3629	60	6	of	of	ADP
iajs-3629	60	7	the	the	DET
iajs-3629	60	8	amide	amide	NOUN
iajs-3629	60	9	nitrogen	nitrogen	NOUN
iajs-3629	60	10	atom	atom	NOUN
iajs-3629	60	11	in	in	ADP
iajs-3629	60	12	the	the	DET
iajs-3629	60	13	β	β	NOUN
iajs-3629	60	14	-	-	NOUN
iajs-3629	60	15	lactam	lactam	NOUN
iajs-3629	60	16	compound	compound	NOUN
iajs-3629	60	17	occurs	occur	VERB
iajs-3629	60	18	due	due	ADP
iajs-3629	60	19	to	to	ADP
iajs-3629	60	20	its	its	PRON
iajs-3629	60	21	favorable	favorable	ADJ
iajs-3629	60	22	ihjpas	ihjpa	NOUN
iajs-3629	60	23	.	.	PUNCT
iajs-3629	61	1	2025,38(2	2025,38(2	NOUN
iajs-3629	61	2	)	)	PUNCT
iajs-3629	61	3	252	252	NUM
iajs-3629	61	4	positioning	positioning	NOUN
iajs-3629	61	5	for	for	ADP
iajs-3629	61	6	forming	form	VERB
iajs-3629	61	7	a	a	DET
iajs-3629	61	8	5	5	NUM
iajs-3629	61	9	-	-	PUNCT
iajs-3629	61	10	membered	membere	VERB
iajs-3629	61	11	ring	ring	NOUN
iajs-3629	61	12	.	.	PUNCT
iajs-3629	62	1	this	this	DET
iajs-3629	62	2	nitrogen	nitrogen	NOUN
iajs-3629	62	3	atom	atom	NOUN
iajs-3629	62	4	is	be	AUX
iajs-3629	62	5	also	also	ADV
iajs-3629	62	6	bent	bent	ADJ
iajs-3629	62	7	out	out	ADP
iajs-3629	62	8	of	of	ADP
iajs-3629	62	9	a	a	DET
iajs-3629	62	10	plane	plane	NOUN
iajs-3629	62	11	about	about	ADP
iajs-3629	62	12	the	the	DET
iajs-3629	62	13	other	other	ADJ
iajs-3629	62	14	three	three	NUM
iajs-3629	62	15	c	c	NOUN
iajs-3629	62	16	atoms	atom	NOUN
iajs-3629	62	17	in	in	ADP
iajs-3629	62	18	the	the	DET
iajs-3629	62	19	β	β	NOUN
iajs-3629	62	20	-	-	NOUN
iajs-3629	62	21	lactam	lactam	ADJ
iajs-3629	62	22	ring	ring	NOUN
iajs-3629	62	23	(	(	PUNCT
iajs-3629	62	24	10	10	NUM
iajs-3629	62	25	-	-	SYM
iajs-3629	62	26	12	12	NUM
iajs-3629	62	27	)	)	PUNCT
iajs-3629	62	28	,	,	PUNCT
iajs-3629	62	29	as	as	SCONJ
iajs-3629	62	30	shown	show	VERB
iajs-3629	62	31	in	in	ADP
iajs-3629	62	32	table	table	NOUN
iajs-3629	62	33	2	2	NUM
iajs-3629	62	34	.	.	PUNCT
iajs-3629	62	35	table	table	NOUN
iajs-3629	62	36	1	1	NUM
iajs-3629	62	37	.	.	PUNCT
iajs-3629	62	38	analytical	analytical	ADJ
iajs-3629	62	39	and	and	CCONJ
iajs-3629	62	40	some	some	DET
iajs-3629	62	41	physical	physical	ADJ
iajs-3629	62	42	data	datum	NOUN
iajs-3629	62	43	for	for	ADP
iajs-3629	62	44	the	the	DET
iajs-3629	62	45	ligand	ligand	NOUN
iajs-3629	62	46	and	and	CCONJ
iajs-3629	62	47	its	its	PRON
iajs-3629	62	48	metal	metal	NOUN
iajs-3629	62	49	complexes	complex	NOUN
iajs-3629	62	50	.	.	PUNCT
iajs-3629	63	1	compounds	compound	NOUN
iajs-3629	63	2	elemental	elemental	ADJ
iajs-3629	63	3	analysis	analysis	NOUN
iajs-3629	63	4	cal	cal	ADJ
iajs-3629	63	5	.	.	PUNCT
iajs-3629	64	1	(	(	PUNCT
iajs-3629	64	2	found	find	VERB
iajs-3629	64	3	)	)	PUNCT
iajs-3629	64	4	%	%	NOUN
iajs-3629	64	5	m.w	m.w	PROPN
iajs-3629	64	6	m.p	m.p	PROPN
iajs-3629	64	7	⸰c	⸰c	PROPN
iajs-3629	64	8	color	color	NOUN
iajs-3629	64	9	%	%	NOUN
iajs-3629	64	10	yield	yield	NOUN
iajs-3629	64	11	µscm1	µscm1	PROPN
iajs-3629	65	1	c	c	NOUN
iajs-3629	65	2	h	h	PROPN
iajs-3629	66	1	n	n	NOUN
iajs-3629	66	2	s	s	NOUN
iajs-3629	66	3	m	m	VERB
iajs-3629	66	4	cl	cl	NOUN
iajs-3629	66	5	o	o	NOUN
iajs-3629	66	6	c22h27cl	c22h27cl	NOUN
iajs-3629	66	7	fn3o5s	fn3o5s	PROPN
iajs-3629	66	8	l	l	NOUN
iajs-3629	66	9	52.85	52.85	NUM
iajs-3629	66	10	5.44	5.44	NUM
iajs-3629	66	11	8.40	8.40	NUM
iajs-3629	66	12	6.41	6.41	NUM
iajs-3629	66	13	--7.09	--7.09	PROPN
iajs-3629	66	14	16.00	16.00	NUM
iajs-3629	66	15	499.98	499.98	NUM
iajs-3629	66	16	210	210	NUM
iajs-3629	66	17	light	light	ADJ
iajs-3629	66	18	yello	yello	PROPN
iajs-3629	66	19	w	w	ADP
iajs-3629	66	20	92	92	NUM
iajs-3629	66	21	--	--	PUNCT
iajs-3629	66	22	(	(	PUNCT
iajs-3629	66	23	52.66	52.66	NUM
iajs-3629	66	24	)	)	PUNCT
iajs-3629	66	25	(	(	PUNCT
iajs-3629	66	26	5.21	5.21	NUM
iajs-3629	66	27	)	)	PUNCT
iajs-3629	66	28	(	(	PUNCT
iajs-3629	66	29	8.30	8.30	NUM
iajs-3629	66	30	)	)	PUNCT
iajs-3629	66	31	(	(	PUNCT
iajs-3629	66	32	6.22	6.22	NUM
iajs-3629	66	33	)	)	PUNCT
iajs-3629	66	34	--(7.00	--(7.00	NOUN
iajs-3629	66	35	)	)	PUNCT
iajs-3629	66	36	(	(	PUNCT
iajs-3629	66	37	15.98	15.98	NUM
iajs-3629	66	38	)	)	PUNCT
iajs-3629	66	39	c5h8no2	c5h8no2	X
iajs-3629	66	40	pro	pro	X
iajs-3629	66	41	52.62	52.62	NUM
iajs-3629	66	42	7.07	7.07	NUM
iajs-3629	66	43	12.27	12.27	NUM
iajs-3629	66	44	--------28.04	--------28.04	X
iajs-3629	66	45	114.12	114.12	NUM
iajs-3629	66	46	208	208	NUM
iajs-3629	66	47	white	white	ADJ
iajs-3629	66	48	85	85	NUM
iajs-3629	66	49	--	--	PUNCT
iajs-3629	66	50	(	(	PUNCT
iajs-3629	66	51	52.40	52.40	NUM
iajs-3629	66	52	)	)	PUNCT
iajs-3629	66	53	(	(	PUNCT
iajs-3629	66	54	7.00	7.00	NUM
iajs-3629	66	55	)	)	PUNCT
iajs-3629	66	56	(	(	PUNCT
iajs-3629	66	57	12.10	12.10	NUM
iajs-3629	66	58	)	)	PUNCT
iajs-3629	66	59	--------(27.96	--------(27.96	NOUN
iajs-3629	66	60	)	)	PUNCT
iajs-3629	67	1	[	[	X
iajs-3629	67	2	c27h37cl2cofn4o8s	c27h37cl2cofn4o8s	X
iajs-3629	67	3	]	]	PUNCT
iajs-3629	67	4	cl2.2h2o	cl2.2h2o	PROPN
iajs-3629	67	5	l	l	NOUN
iajs-3629	67	6	(	(	PUNCT
iajs-3629	67	7	pro	pro	X
iajs-3629	67	8	)	)	PUNCT
iajs-3629	67	9	co	co	VERB
iajs-3629	67	10	44.64	44.64	NUM
iajs-3629	67	11	5.13	5.13	NUM
iajs-3629	67	12	7.71	7.71	NUM
iajs-3629	67	13	4.41	4.41	NUM
iajs-3629	67	14	8.11	8.11	NUM
iajs-3629	67	15	9.76	9.76	NUM
iajs-3629	67	16	17.62	17.62	NUM
iajs-3629	67	17	726.51	726.51	NUM
iajs-3629	67	18	225	225	NUM
iajs-3629	67	19	pink	pink	ADJ
iajs-3629	67	20	78	78	NUM
iajs-3629	67	21	18.4	18.4	NUM
iajs-3629	67	22	(	(	PUNCT
iajs-3629	67	23	44.32	44.32	NUM
iajs-3629	67	24	)	)	PUNCT
iajs-3629	67	25	(	(	PUNCT
iajs-3629	67	26	5.01	5.01	NUM
iajs-3629	67	27	)	)	PUNCT
iajs-3629	67	28	(	(	PUNCT
iajs-3629	67	29	7.31	7.31	NUM
iajs-3629	67	30	)	)	PUNCT
iajs-3629	67	31	(	(	PUNCT
iajs-3629	67	32	4.22	4.22	NUM
iajs-3629	67	33	)	)	PUNCT
iajs-3629	67	34	(	(	PUNCT
iajs-3629	67	35	7.97	7.97	NUM
iajs-3629	67	36	)	)	PUNCT
iajs-3629	67	37	(	(	PUNCT
iajs-3629	67	38	9.14	9.14	NUM
iajs-3629	67	39	)	)	PUNCT
iajs-3629	67	40	(	(	PUNCT
iajs-3629	67	41	17.02	17.02	NUM
iajs-3629	67	42	)	)	PUNCT
iajs-3629	68	1	[	[	X
iajs-3629	68	2	c27h37cl2nifn4o8	c27h37cl2nifn4o8	X
iajs-3629	68	3	]	]	X
iajs-3629	68	4	cl2.2h2o	cl2.2h2o	PROPN
iajs-3629	68	5	l	l	NOUN
iajs-3629	68	6	(	(	PUNCT
iajs-3629	68	7	pro	pro	ADJ
iajs-3629	68	8	)	)	PUNCT
iajs-3629	68	9	ni	ni	PROPN
iajs-3629	68	10	44.65	44.65	NUM
iajs-3629	68	11	5.13	5.13	NUM
iajs-3629	68	12	7.71	7.71	NUM
iajs-3629	68	13	4.42	4.42	NUM
iajs-3629	68	14	8.08	8.08	NUM
iajs-3629	68	15	9.76	9.76	NUM
iajs-3629	68	16	17.62	17.62	NUM
iajs-3629	68	17	726.27	726.27	NUM
iajs-3629	68	18	230	230	NUM
iajs-3629	68	19	light	light	NOUN
iajs-3629	68	20	green	green	ADJ
iajs-3629	68	21	88	88	NUM
iajs-3629	68	22	12.0	12.0	NUM
iajs-3629	68	23	(	(	PUNCT
iajs-3629	68	24	44.05	44.05	NUM
iajs-3629	68	25	)	)	PUNCT
iajs-3629	68	26	(	(	PUNCT
iajs-3629	68	27	4.93	4.93	NUM
iajs-3629	68	28	)	)	PUNCT
iajs-3629	68	29	(	(	PUNCT
iajs-3629	68	30	7.06	7.06	NUM
iajs-3629	68	31	)	)	PUNCT
iajs-3629	68	32	(	(	PUNCT
iajs-3629	68	33	4.09	4.09	NUM
iajs-3629	68	34	)	)	PUNCT
iajs-3629	68	35	(	(	PUNCT
iajs-3629	68	36	8.01	8.01	NUM
iajs-3629	68	37	)	)	PUNCT
iajs-3629	68	38	(	(	PUNCT
iajs-3629	68	39	9.03	9.03	NUM
iajs-3629	68	40	)	)	PUNCT
iajs-3629	68	41	(	(	PUNCT
iajs-3629	68	42	17.33	17.33	NUM
iajs-3629	68	43	)	)	PUNCT
iajs-3629	69	1	[	[	X
iajs-3629	69	2	c27h37cl2cufn4o8s	c27h37cl2cufn4o8s	X
iajs-3629	69	3	]	]	PUNCT
iajs-3629	69	4	cl2.2h2o	cl2.2h2o	PROPN
iajs-3629	69	5	l	l	NOUN
iajs-3629	69	6	(	(	PUNCT
iajs-3629	69	7	pro	pro	ADJ
iajs-3629	69	8	)	)	PUNCT
iajs-3629	69	9	cu	cu	PROPN
iajs-3629	69	10	44.36	44.36	NUM
iajs-3629	69	11	5.10	5.10	NUM
iajs-3629	69	12	7.66	7.66	NUM
iajs-3629	69	13	4.39	4.39	NUM
iajs-3629	69	14	8.69	8.69	NUM
iajs-3629	69	15	9.70	9.70	NUM
iajs-3629	69	16	17.51	17.51	NUM
iajs-3629	69	17	731.12	731.12	NUM
iajs-3629	69	18	235	235	NUM
iajs-3629	69	19	dark	dark	ADJ
iajs-3629	69	20	green	green	NOUN
iajs-3629	69	21	67	67	NUM
iajs-3629	69	22	14.7	14.7	NUM
iajs-3629	69	23	(	(	PUNCT
iajs-3629	69	24	44.18	44.18	NUM
iajs-3629	69	25	)	)	PUNCT
iajs-3629	69	26	(	(	PUNCT
iajs-3629	69	27	4.82	4.82	NUM
iajs-3629	69	28	)	)	PUNCT
iajs-3629	69	29	(	(	PUNCT
iajs-3629	69	30	7.28	7.28	NUM
iajs-3629	69	31	)	)	PUNCT
iajs-3629	69	32	(	(	PUNCT
iajs-3629	69	33	4.02	4.02	NUM
iajs-3629	69	34	)	)	PUNCT
iajs-3629	69	35	(	(	PUNCT
iajs-3629	69	36	8.05	8.05	NUM
iajs-3629	69	37	)	)	PUNCT
iajs-3629	69	38	(	(	PUNCT
iajs-3629	69	39	9.56	9.56	NUM
iajs-3629	69	40	)	)	PUNCT
iajs-3629	69	41	(	(	PUNCT
iajs-3629	69	42	17.20	17.20	NUM
iajs-3629	69	43	)	)	PUNCT
iajs-3629	70	1	[	[	X
iajs-3629	70	2	c27h39clznfn4o9	c27h39clznfn4o9	X
iajs-3629	70	3	]	]	X
iajs-3629	70	4	cl2.2h2o	cl2.2h2o	PROPN
iajs-3629	70	5	l	l	NOUN
iajs-3629	70	6	(	(	PUNCT
iajs-3629	70	7	pro	pro	ADJ
iajs-3629	70	8	)	)	PUNCT
iajs-3629	70	9	zn	zn	NOUN
iajs-3629	70	10	45.32	45.32	NUM
iajs-3629	70	11	5.49	5.49	NUM
iajs-3629	70	12	7.83	7.83	NUM
iajs-3629	70	13	4.48	4.48	NUM
iajs-3629	70	14	9.14	9.14	NUM
iajs-3629	70	15	4.95	4.95	NUM
iajs-3629	70	16	20.12	20.12	NUM
iajs-3629	70	17	715.55	715.55	NUM
iajs-3629	70	18	243	243	NUM
iajs-3629	70	19	light	light	ADJ
iajs-3629	70	20	yello	yello	NOUN
iajs-3629	70	21	w	w	PROPN
iajs-3629	70	22	85	85	NUM
iajs-3629	70	23	76.2	76.2	NUM
iajs-3629	70	24	(	(	PUNCT
iajs-3629	70	25	44.97	44.97	NUM
iajs-3629	70	26	)	)	PUNCT
iajs-3629	70	27	(	(	PUNCT
iajs-3629	70	28	5.03	5.03	NUM
iajs-3629	70	29	)	)	PUNCT
iajs-3629	70	30	(	(	PUNCT
iajs-3629	70	31	7.29	7.29	NUM
iajs-3629	70	32	)	)	PUNCT
iajs-3629	70	33	(	(	PUNCT
iajs-3629	70	34	4.09	4.09	NUM
iajs-3629	70	35	)	)	PUNCT
iajs-3629	70	36	(	(	PUNCT
iajs-3629	70	37	9.00	9.00	NUM
iajs-3629	70	38	)	)	PUNCT
iajs-3629	70	39	(	(	PUNCT
iajs-3629	70	40	4.10	4.10	NUM
iajs-3629	70	41	)	)	PUNCT
iajs-3629	70	42	(	(	PUNCT
iajs-3629	70	43	19.95	19.95	NUM
iajs-3629	70	44	)	)	PUNCT
iajs-3629	71	1	[	[	X
iajs-3629	71	2	c27h39clcdfn4o9	c27h39clcdfn4o9	X
iajs-3629	71	3	]	]	X
iajs-3629	71	4	cl2.2h2o	cl2.2h2o	PROPN
iajs-3629	71	5	l	l	NOUN
iajs-3629	71	6	(	(	PUNCT
iajs-3629	71	7	pro	pro	ADJ
iajs-3629	71	8	)	)	PUNCT
iajs-3629	71	9	cd	cd	NOUN
iajs-3629	71	10	42.53	42.53	NUM
iajs-3629	71	11	5.16	5.16	NUM
iajs-3629	71	12	7.35	7.35	NUM
iajs-3629	71	13	4.20	4.20	NUM
iajs-3629	71	14	14.74	14.74	NUM
iajs-3629	71	15	4.65	4.65	NUM
iajs-3629	71	16	18.88	18.88	NUM
iajs-3629	71	17	762.55	762.55	NUM
iajs-3629	71	18	252	252	NUM
iajs-3629	71	19	light	light	ADJ
iajs-3629	71	20	yello	yello	NOUN
iajs-3629	71	21	w	w	PROPN
iajs-3629	71	22	87	87	NUM
iajs-3629	71	23	89.5	89.5	NUM
iajs-3629	71	24	(	(	PUNCT
iajs-3629	71	25	42.06	42.06	NUM
iajs-3629	71	26	)	)	PUNCT
iajs-3629	71	27	(	(	PUNCT
iajs-3629	71	28	4.78	4.78	NUM
iajs-3629	71	29	)	)	PUNCT
iajs-3629	71	30	(	(	PUNCT
iajs-3629	71	31	7.03	7.03	NUM
iajs-3629	71	32	)	)	PUNCT
iajs-3629	71	33	(	(	PUNCT
iajs-3629	71	34	4.10	4.10	NUM
iajs-3629	71	35	)	)	PUNCT
iajs-3629	71	36	(	(	PUNCT
iajs-3629	71	37	14.56	14.56	NUM
iajs-3629	71	38	)	)	PUNCT
iajs-3629	71	39	(	(	PUNCT
iajs-3629	71	40	4.20	4.20	NUM
iajs-3629	71	41	)	)	PUNCT
iajs-3629	71	42	(	(	PUNCT
iajs-3629	71	43	18.33	18.33	NUM
iajs-3629	71	44	)	)	PUNCT
iajs-3629	71	45	the	the	DET
iajs-3629	71	46	coordination	coordination	NOUN
iajs-3629	71	47	between	between	ADP
iajs-3629	71	48	the	the	DET
iajs-3629	71	49	oxygen	oxygen	NOUN
iajs-3629	71	50	atom	atom	NOUN
iajs-3629	71	51	of	of	ADP
iajs-3629	71	52	the	the	DET
iajs-3629	71	53	carbonyl	carbonyl	NOUN
iajs-3629	71	54	group	group	NOUN
iajs-3629	71	55	(	(	PUNCT
iajs-3629	71	56	c	c	NOUN
iajs-3629	71	57	=	=	NOUN
iajs-3629	71	58	o	o	NOUN
iajs-3629	71	59	)	)	PUNCT
iajs-3629	71	60	and	and	CCONJ
iajs-3629	71	61	the	the	DET
iajs-3629	71	62	nitrogen	nitrogen	NOUN
iajs-3629	71	63	atom	atom	NOUN
iajs-3629	71	64	of	of	ADP
iajs-3629	71	65	the	the	DET
iajs-3629	71	66	β	β	NOUN
iajs-3629	71	67	-	-	NOUN
iajs-3629	71	68	lactam	lactam	NOUN
iajs-3629	71	69	(	(	PUNCT
iajs-3629	71	70	c	c	NOUN
iajs-3629	71	71	-	-	PUNCT
iajs-3629	71	72	n	n	CCONJ
iajs-3629	71	73	)	)	PUNCT
iajs-3629	71	74	exhibited	exhibit	VERB
iajs-3629	71	75	a	a	DET
iajs-3629	71	76	decrease	decrease	NOUN
iajs-3629	71	77	in	in	ADP
iajs-3629	71	78	frequency	frequency	NOUN
iajs-3629	71	79	,	,	PUNCT
iajs-3629	71	80	falling	fall	VERB
iajs-3629	71	81	within	within	ADP
iajs-3629	71	82	the	the	DET
iajs-3629	71	83	range	range	NOUN
iajs-3629	71	84	of	of	ADP
iajs-3629	71	85	5	5	NUM
iajs-3629	71	86	-	-	SYM
iajs-3629	71	87	35	35	NUM
iajs-3629	71	88	cm-1	cm-1	NOUN
iajs-3629	71	89	for	for	ADP
iajs-3629	71	90	both	both	CCONJ
iajs-3629	71	91	the	the	DET
iajs-3629	71	92	ligand	ligand	NOUN
iajs-3629	71	93	(	(	PUNCT
iajs-3629	71	94	l	l	NOUN
iajs-3629	71	95	)	)	PUNCT
iajs-3629	71	96	and	and	CCONJ
iajs-3629	71	97	all	all	DET
iajs-3629	71	98	complexes	complex	NOUN
iajs-3629	71	99	.	.	PUNCT
iajs-3629	72	1	additionally	additionally	ADV
iajs-3629	72	2	,	,	PUNCT
iajs-3629	72	3	the	the	DET
iajs-3629	72	4	c	c	NOUN
iajs-3629	72	5	-	-	PUNCT
iajs-3629	72	6	n	n	PRON
iajs-3629	72	7	band	band	NOUN
iajs-3629	72	8	in	in	ADP
iajs-3629	72	9	proline	proline	NOUN
iajs-3629	72	10	was	be	AUX
iajs-3629	72	11	observed	observe	VERB
iajs-3629	72	12	within	within	ADP
iajs-3629	72	13	the	the	DET
iajs-3629	72	14	range	range	NOUN
iajs-3629	72	15	of	of	ADP
iajs-3629	72	16	2	2	NUM
iajs-3629	72	17	-	-	SYM
iajs-3629	72	18	21	21	NUM
iajs-3629	72	19	cm-1	cm-1	NOUN
iajs-3629	72	20	.	.	PUNCT
iajs-3629	73	1	this	this	DET
iajs-3629	73	2	coordination	coordination	NOUN
iajs-3629	73	3	was	be	AUX
iajs-3629	73	4	further	far	ADV
iajs-3629	73	5	substantiated	substantiate	VERB
iajs-3629	73	6	by	by	ADP
iajs-3629	73	7	identifying	identify	VERB
iajs-3629	73	8	m	m	PROPN
iajs-3629	73	9	-	-	NOUN
iajs-3629	73	10	o	o	NOUN
iajs-3629	73	11	and	and	CCONJ
iajs-3629	73	12	m	m	PROPN
iajs-3629	73	13	-	-	PUNCT
iajs-3629	73	14	n	n	NOUN
iajs-3629	73	15	bands	band	NOUN
iajs-3629	73	16	in	in	ADP
iajs-3629	73	17	the	the	DET
iajs-3629	73	18	complex	complex	ADJ
iajs-3629	73	19	spectra	spectra	NOUN
iajs-3629	73	20	,	,	PUNCT
iajs-3629	73	21	which	which	PRON
iajs-3629	73	22	were	be	AUX
iajs-3629	73	23	observed	observe	VERB
iajs-3629	73	24	within	within	ADP
iajs-3629	73	25	the	the	DET
iajs-3629	73	26	range	range	NOUN
iajs-3629	73	27	of	of	ADP
iajs-3629	73	28	400	400	NUM
iajs-3629	73	29	-	-	SYM
iajs-3629	73	30	550	550	NUM
iajs-3629	73	31	cm-1	cm-1	NOUN
iajs-3629	73	32	as	as	SCONJ
iajs-3629	73	33	reported	report	VERB
iajs-3629	73	34	in	in	ADP
iajs-3629	73	35	the	the	DET
iajs-3629	73	36	literature	literature	NOUN
iajs-3629	73	37	(	(	PUNCT
iajs-3629	73	38	13	13	NUM
iajs-3629	73	39	)	)	PUNCT
iajs-3629	73	40	.	.	PUNCT
iajs-3629	74	1	table	table	NOUN
iajs-3629	74	2	3	3	NUM
iajs-3629	74	3	and	and	CCONJ
iajs-3629	74	4	figures	figure	NOUN
iajs-3629	74	5	1	1	NUM
iajs-3629	74	6	-	-	SYM
iajs-3629	74	7	3	3	NUM
iajs-3629	74	8	show	show	VERB
iajs-3629	74	9	the	the	DET
iajs-3629	74	10	ft	ft	PROPN
iajs-3629	74	11	-	-	PUNCT
iajs-3629	74	12	ir	ir	NOUN
iajs-3629	74	13	spectrum	spectrum	NOUN
iajs-3629	74	14	's	's	PART
iajs-3629	74	15	additional	additional	ADJ
iajs-3629	74	16	significant	significant	ADJ
iajs-3629	74	17	characteristic	characteristic	ADJ
iajs-3629	74	18	peaks	peak	NOUN
iajs-3629	74	19	.	.	PUNCT
iajs-3629	75	1	table	table	NOUN
iajs-3629	75	2	2	2	NUM
iajs-3629	75	3	.	.	PUNCT
iajs-3629	75	4	fourier	fourier	NOUN
iajs-3629	75	5	transform	transform	VERB
iajs-3629	75	6	infrared	infrared	ADJ
iajs-3629	75	7	spectroscopy	spectroscopy	NOUN
iajs-3629	75	8	bands	band	NOUN
iajs-3629	75	9	of	of	ADP
iajs-3629	75	10	l	l	NOUN
iajs-3629	75	11	and	and	CCONJ
iajs-3629	75	12	proline	proline	NOUN
iajs-3629	75	13	.	.	PUNCT
iajs-3629	76	1	ѵm	ѵm	NOUN
iajs-3629	76	2	-	-	PUNCT
iajs-3629	76	3	cl	cl	NOUN
iajs-3629	76	4	ѵm	ѵm	NOUN
iajs-3629	76	5	-	-	PUNCT
iajs-3629	76	6	n	n	NOUN
iajs-3629	76	7	ѵm	ѵm	NOUN
iajs-3629	76	8	-	-	PUNCT
iajs-3629	76	9	o	o	NOUN
iajs-3629	76	10	c	c	NOUN
iajs-3629	76	11	=	=	NOUN
iajs-3629	76	12	o	o	X
iajs-3629	76	13	ester	ester	NOUN
iajs-3629	76	14	β	β	NOUN
iajs-3629	76	15	-	-	NOUN
iajs-3629	76	16	lactam	lactam	NOUN
iajs-3629	76	17	l1	l1	PROPN
iajs-3629	76	18	ѵ	ѵ	PROPN
iajs-3629	76	19	c	c	X
iajs-3629	76	20	-	-	PUNCT
iajs-3629	76	21	n	n	PRON
iajs-3629	76	22	ѵ(coo)asy	ѵ(coo)asy	PROPN
iajs-3629	76	23	ѵ(coo)sym	ѵ(coo)sym	PROPN
iajs-3629	76	24	ѵnh	ѵnh	NOUN
iajs-3629	76	25	compound	compound	NOUN
iajs-3629	76	26	-----1743	-----1743	PROPN
iajs-3629	76	27	1735	1735	NUM
iajs-3629	76	28	1335	1335	NUM
iajs-3629	76	29	---3380	---3380	VERB
iajs-3629	76	30	l	l	NOUN
iajs-3629	76	31	--------1342	--------1342	SYM
iajs-3629	76	32	1573	1573	NUM
iajs-3629	76	33	1492	1492	NUM
iajs-3629	76	34	3083	3083	NUM
iajs-3629	76	35	pro	pro	ADJ
iajs-3629	76	36	ihjpas	ihjpas	PROPN
iajs-3629	76	37	.	.	PUNCT
iajs-3629	77	1	2025,38(2	2025,38(2	NOUN
iajs-3629	77	2	)	)	PUNCT
iajs-3629	77	3	253	253	NUM
iajs-3629	77	4	table	table	NOUN
iajs-3629	77	5	3	3	NUM
iajs-3629	77	6	.	.	PUNCT
iajs-3629	78	1	fourier	fourier	NOUN
iajs-3629	78	2	transform	transform	VERB
iajs-3629	78	3	infrared	infrared	ADJ
iajs-3629	78	4	spectroscopy	spectroscopy	NOUN
iajs-3629	78	5	bands	band	NOUN
iajs-3629	78	6	of	of	ADP
iajs-3629	78	7	complexes	complex	NOUN
iajs-3629	78	8	.	.	PUNCT
iajs-3629	79	1	m	m	NOUN
iajs-3629	79	2	-	-	NOUN
iajs-3629	79	3	cl	cl	NOUN
iajs-3629	79	4	m	m	NOUN
iajs-3629	79	5	-	-	NOUN
iajs-3629	79	6	o	o	X
iajs-3629	79	7	(	(	PUNCT
iajs-3629	79	8	pro	pro	ADJ
iajs-3629	79	9	)	)	PUNCT
iajs-3629	79	10	(	(	PUNCT
iajs-3629	79	11	l	l	NOUN
iajs-3629	79	12	)	)	PUNCT
iajs-3629	79	13	m	m	PROPN
iajs-3629	79	14	-	-	PUNCT
iajs-3629	79	15	n	n	PRON
iajs-3629	79	16	(	(	PUNCT
iajs-3629	79	17	pro	pro	ADJ
iajs-3629	79	18	)	)	PUNCT
iajs-3629	79	19	(	(	PUNCT
iajs-3629	79	20	l	l	NOUN
iajs-3629	79	21	)	)	PUNCT
iajs-3629	79	22	c	c	NOUN
iajs-3629	79	23	=	=	SYM
iajs-3629	79	24	o	o	X
iajs-3629	79	25	ester	ester	NOUN
iajs-3629	79	26	β	β	NOUN
iajs-3629	79	27	-	-	NOUN
iajs-3629	79	28	lactam	lactam	NOUN
iajs-3629	79	29	l	l	NOUN
iajs-3629	79	30	c	c	NOUN
iajs-3629	79	31	-	-	PUNCT
iajs-3629	79	32	n	n	PRON
iajs-3629	79	33	(	(	PUNCT
iajs-3629	79	34	l	l	NOUN
iajs-3629	79	35	)	)	PUNCT
iajs-3629	79	36	(	(	PUNCT
iajs-3629	79	37	pro	pro	ADJ
iajs-3629	79	38	)	)	PUNCT
iajs-3629	79	39	coo	coo	NOUN
iajs-3629	79	40	(	(	PUNCT
iajs-3629	79	41	asy	asy	PROPN
iajs-3629	79	42	)	)	PUNCT
iajs-3629	79	43	coo	coo	NOUN
iajs-3629	79	44	(	(	PUNCT
iajs-3629	79	45	sym	sym	NOUN
iajs-3629	79	46	)	)	PUNCT
iajs-3629	79	47	(	(	PUNCT
iajs-3629	79	48	pro	pro	ADJ
iajs-3629	79	49	)	)	PUNCT
iajs-3629	79	50	n	n	CCONJ
iajs-3629	79	51	-	-	PUNCT
iajs-3629	79	52	h	h	NOUN
iajs-3629	79	53	(	(	PUNCT
iajs-3629	79	54	l	l	NOUN
iajs-3629	79	55	)	)	PUNCT
iajs-3629	79	56	(	(	PUNCT
iajs-3629	79	57	pro	pro	ADJ
iajs-3629	79	58	)	)	PUNCT
iajs-3629	79	59	compound	compound	NOUN
iajs-3629	79	60	--	--	PUNCT
iajs-3629	79	61	474	474	NUM
iajs-3629	79	62	418	418	NUM
iajs-3629	79	63	521	521	NUM
iajs-3629	79	64	547	547	NUM
iajs-3629	79	65	1793	1793	NUM
iajs-3629	79	66	1735	1735	NUM
iajs-3629	79	67	1300	1300	NUM
iajs-3629	79	68	1340	1340	NUM
iajs-3629	79	69	1575	1575	NUM
iajs-3629	79	70	1458	1458	NUM
iajs-3629	79	71	3033	3033	NUM
iajs-3629	79	72	3411	3411	NUM
iajs-3629	79	73	l	l	NOUN
iajs-3629	79	74	(	(	PUNCT
iajs-3629	79	75	pro	pro	ADJ
iajs-3629	79	76	)	)	PUNCT
iajs-3629	79	77	co	co	NOUN
iajs-3629	79	78	--	--	PUNCT
iajs-3629	79	79	476	476	NUM
iajs-3629	79	80	416	416	NUM
iajs-3629	79	81	512	512	NUM
iajs-3629	79	82	543	543	NUM
iajs-3629	79	83	1745	1745	NUM
iajs-3629	79	84	1735	1735	NUM
iajs-3629	79	85	1330	1330	NUM
iajs-3629	79	86	1355	1355	NUM
iajs-3629	79	87	1573	1573	NUM
iajs-3629	79	88	1460	1460	NUM
iajs-3629	79	89	3101	3101	NUM
iajs-3629	79	90	3390	3390	NUM
iajs-3629	79	91	l	l	NOUN
iajs-3629	79	92	(	(	PUNCT
iajs-3629	79	93	pro	pro	ADJ
iajs-3629	79	94	)	)	PUNCT
iajs-3629	79	95	ni	ni	NOUN
iajs-3629	79	96	--	--	PUNCT
iajs-3629	79	97	462	462	NUM
iajs-3629	79	98	406	406	NUM
iajs-3629	79	99	505	505	NUM
iajs-3629	79	100	512	512	NUM
iajs-3629	79	101	1780	1780	NUM
iajs-3629	79	102	1735	1735	NUM
iajs-3629	79	103	1320	1320	NUM
iajs-3629	79	104	1342	1342	NUM
iajs-3629	79	105	1577	1577	NUM
iajs-3629	79	106	1456	1456	NUM
iajs-3629	79	107	3078	3078	NUM
iajs-3629	79	108	3421	3421	NUM
iajs-3629	79	109	l	l	NOUN
iajs-3629	79	110	(	(	PUNCT
iajs-3629	79	111	pro	pro	ADJ
iajs-3629	79	112	)	)	PUNCT
iajs-3629	79	113	cu	cu	NOUN
iajs-3629	79	114	235	235	NUM
iajs-3629	79	115	472	472	NUM
iajs-3629	79	116	451	451	NUM
iajs-3629	79	117	501	501	NUM
iajs-3629	79	118	510	510	NUM
iajs-3629	79	119	1781	1781	NUM
iajs-3629	79	120	1733	1733	NUM
iajs-3629	79	121	1315	1315	NUM
iajs-3629	79	122	1321	1321	NUM
iajs-3629	79	123	1510	1510	NUM
iajs-3629	79	124	1458	1458	NUM
iajs-3629	79	125	3058	3058	NUM
iajs-3629	79	126	3390	3390	NUM
iajs-3629	79	127	l	l	NOUN
iajs-3629	79	128	(	(	PUNCT
iajs-3629	79	129	pro	pro	ADJ
iajs-3629	79	130	)	)	PUNCT
iajs-3629	79	131	zn	zn	PROPN
iajs-3629	79	132	248	248	NUM
iajs-3629	79	133	480	480	NUM
iajs-3629	79	134	420	420	NUM
iajs-3629	79	135	509	509	NUM
iajs-3629	79	136	530	530	NUM
iajs-3629	79	137	1770	1770	NUM
iajs-3629	79	138	1735	1735	NUM
iajs-3629	79	139	1320	1320	NUM
iajs-3629	79	140	1353	1353	NUM
iajs-3629	79	141	1508	1508	NUM
iajs-3629	79	142	1438	1438	NUM
iajs-3629	79	143	3122	3122	NUM
iajs-3629	79	144	3417	3417	NUM
iajs-3629	79	145	l	l	NOUN
iajs-3629	79	146	(	(	PUNCT
iajs-3629	79	147	pro	pro	ADJ
iajs-3629	79	148	)	)	PUNCT
iajs-3629	79	149	cd	cd	NOUN
iajs-3629	79	150	figure	figure	NOUN
iajs-3629	79	151	1	1	NUM
iajs-3629	79	152	.	.	PUNCT
iajs-3629	80	1	spectrum	spectrum	NOUN
iajs-3629	80	2	of	of	ADP
iajs-3629	80	3	l	l	PROPN
iajs-3629	80	4	ftir	ftir	PROPN
iajs-3629	80	5	.	.	PUNCT
iajs-3629	81	1	figure	figure	NOUN
iajs-3629	81	2	2	2	NUM
iajs-3629	81	3	.	.	PUNCT
iajs-3629	82	1	the	the	DET
iajs-3629	82	2	ftir	ftir	PROPN
iajs-3629	82	3	spectrum	spectrum	NOUN
iajs-3629	82	4	of	of	ADP
iajs-3629	82	5	pro	pro	PROPN
iajs-3629	82	6	.	.	PUNCT
iajs-3629	82	7	ihjpas	ihjpas	PROPN
iajs-3629	82	8	.	.	PUNCT
iajs-3629	83	1	2025,38(2	2025,38(2	NOUN
iajs-3629	83	2	)	)	PUNCT
iajs-3629	83	3	254	254	NUM
iajs-3629	83	4	figure	figure	NOUN
iajs-3629	83	5	3	3	NUM
iajs-3629	83	6	.	.	PUNCT
iajs-3629	84	1	the	the	DET
iajs-3629	84	2	ftir	ftir	PROPN
iajs-3629	84	3	spectrum	spectrum	NOUN
iajs-3629	84	4	of	of	ADP
iajs-3629	84	5	l	l	PROPN
iajs-3629	84	6	(	(	PUNCT
iajs-3629	84	7	pro	pro	ADJ
iajs-3629	84	8	)	)	PUNCT
iajs-3629	84	9	co.	co.	NOUN
iajs-3629	84	10	3.2	3.2	NUM
iajs-3629	84	11	.	.	PUNCT
iajs-3629	85	1	the	the	DET
iajs-3629	85	2	uv	uv	NOUN
iajs-3629	85	3	-	-	PUNCT
iajs-3629	85	4	vis	vis	X
iajs-3629	85	5	spectra	spectra	NOUN
iajs-3629	85	6	of	of	ADP
iajs-3629	85	7	mix	mix	NOUN
iajs-3629	85	8	ligand	ligand	NOUN
iajs-3629	85	9	and	and	CCONJ
iajs-3629	85	10	its	its	PRON
iajs-3629	85	11	metal	metal	NOUN
iajs-3629	85	12	complexes	complexe	VERB
iajs-3629	85	13	the	the	DET
iajs-3629	85	14	n→π	n→π	NUM
iajs-3629	85	15	*	*	SYM
iajs-3629	85	16	and	and	CCONJ
iajs-3629	85	17	π→	π→	PROPN
iajs-3629	85	18	π	π	PROPN
iajs-3629	85	19	*	*	NOUN
iajs-3629	85	20	transitions	transition	NOUN
iajs-3629	85	21	to	to	ADP
iajs-3629	85	22	the	the	DET
iajs-3629	85	23	c	c	NOUN
iajs-3629	85	24	-	-	PUNCT
iajs-3629	85	25	o	o	NOUN
iajs-3629	85	26	,	,	PUNCT
iajs-3629	85	27	c	c	NOUN
iajs-3629	85	28	-	-	PUNCT
iajs-3629	85	29	n	n	CCONJ
iajs-3629	85	30	,	,	PUNCT
iajs-3629	85	31	and	and	CCONJ
iajs-3629	85	32	c	c	X
iajs-3629	85	33	=	=	NOUN
iajs-3629	85	34	c	c	NOUN
iajs-3629	85	35	transitions	transition	NOUN
iajs-3629	85	36	,	,	PUNCT
iajs-3629	85	37	respectively	respectively	ADV
iajs-3629	85	38	,	,	PUNCT
iajs-3629	85	39	were	be	AUX
iajs-3629	85	40	assigned	assign	VERB
iajs-3629	85	41	to	to	ADP
iajs-3629	85	42	the	the	DET
iajs-3629	85	43	peaks	peak	NOUN
iajs-3629	85	44	between	between	ADP
iajs-3629	85	45	220	220	NUM
iajs-3629	85	46	and	and	CCONJ
iajs-3629	85	47	350	350	NUM
iajs-3629	85	48	nm	nm	NOUN
iajs-3629	85	49	in	in	ADP
iajs-3629	85	50	the	the	DET
iajs-3629	85	51	electronic	electronic	ADJ
iajs-3629	85	52	spectrum	spectrum	NOUN
iajs-3629	85	53	of	of	ADP
iajs-3629	85	54	the	the	DET
iajs-3629	85	55	mix	mix	NOUN
iajs-3629	85	56	of	of	ADP
iajs-3629	85	57	ligands	ligand	NOUN
iajs-3629	85	58	in	in	ADP
iajs-3629	85	59	figure	figure	NOUN
iajs-3629	85	60	4	4	NUM
iajs-3629	85	61	.	.	PUNCT
iajs-3629	86	1	the	the	DET
iajs-3629	86	2	utilization	utilization	NOUN
iajs-3629	86	3	of	of	ADP
iajs-3629	86	4	spectra	spectra	PROPN
iajs-3629	86	5	facilitated	facilitate	VERB
iajs-3629	86	6	the	the	DET
iajs-3629	86	7	prediction	prediction	NOUN
iajs-3629	86	8	of	of	ADP
iajs-3629	86	9	the	the	DET
iajs-3629	86	10	planned	plan	VERB
iajs-3629	86	11	geometry	geometry	NOUN
iajs-3629	86	12	by	by	ADP
iajs-3629	86	13	analyzing	analyze	VERB
iajs-3629	86	14	the	the	DET
iajs-3629	86	15	characteristics	characteristic	NOUN
iajs-3629	86	16	of	of	ADP
iajs-3629	86	17	the	the	DET
iajs-3629	86	18	observed	observe	VERB
iajs-3629	86	19	peaks	peak	NOUN
iajs-3629	86	20	in	in	ADP
iajs-3629	86	21	shape	shape	NOUN
iajs-3629	86	22	and	and	CCONJ
iajs-3629	86	23	quantity	quantity	NOUN
iajs-3629	86	24	(	(	PUNCT
iajs-3629	86	25	14	14	NUM
iajs-3629	86	26	)	)	PUNCT
iajs-3629	86	27	.	.	PUNCT
iajs-3629	87	1	in	in	ADP
iajs-3629	87	2	table	table	NOUN
iajs-3629	87	3	4	4	NUM
iajs-3629	87	4	,	,	PUNCT
iajs-3629	87	5	l1(pro)co	l1(pro)co	ADJ
iajs-3629	87	6	complex	complex	NOUN
iajs-3629	87	7	shows	show	VERB
iajs-3629	87	8	4	4	NUM
iajs-3629	87	9	bands	band	NOUN
iajs-3629	87	10	in	in	ADP
iajs-3629	87	11	the	the	DET
iajs-3629	87	12	wave	wave	NOUN
iajs-3629	87	13	number	number	NOUN
iajs-3629	87	14	(	(	PUNCT
iajs-3629	87	15	14755,16447,23255,34722	14755,16447,23255,34722	NUM
iajs-3629	87	16	)	)	PUNCT
iajs-3629	87	17	cm-1	cm-1	PROPN
iajs-3629	87	18	.	.	PUNCT
iajs-3629	88	1	l1(pro	l1(pro	NUM
iajs-3629	88	2	)	)	PUNCT
iajs-3629	88	3	ni	ni	PROPN
iajs-3629	88	4	complex	complex	NOUN
iajs-3629	88	5	has	have	VERB
iajs-3629	88	6	4	4	NUM
iajs-3629	88	7	bands	band	NOUN
iajs-3629	88	8	(	(	PUNCT
iajs-3629	88	9	11173,15873,20576,34843	11173,15873,20576,34843	NUM
iajs-3629	88	10	)	)	PUNCT
iajs-3629	88	11	cm-1	cm-1	NOUN
iajs-3629	88	12	.	.	PUNCT
iajs-3629	89	1	l	l	NOUN
iajs-3629	89	2	(	(	PUNCT
iajs-3629	89	3	pro)cu	pro)cu	PROPN
iajs-3629	89	4	complex	complex	NOUN
iajs-3629	89	5	shows	show	VERB
iajs-3629	89	6	3	3	NUM
iajs-3629	89	7	bands	band	NOUN
iajs-3629	89	8	in	in	ADP
iajs-3629	89	9	the	the	DET
iajs-3629	89	10	wave	wave	NOUN
iajs-3629	89	11	number	number	NOUN
iajs-3629	89	12	(	(	PUNCT
iajs-3629	89	13	12987,2270,41322	12987,2270,41322	NOUN
iajs-3629	89	14	)	)	PUNCT
iajs-3629	89	15	cm-1	cm-1	PROPN
iajs-3629	89	16	.	.	PUNCT
iajs-3629	90	1	l	l	NOUN
iajs-3629	90	2	(	(	PUNCT
iajs-3629	90	3	pro)zn	pro)zn	NOUN
iajs-3629	90	4	complex	complex	NOUN
iajs-3629	90	5	shown	show	VERB
iajs-3629	90	6	2	2	NUM
iajs-3629	90	7	bands	band	NOUN
iajs-3629	90	8	in	in	ADP
iajs-3629	90	9	the	the	DET
iajs-3629	90	10	wave	wave	NOUN
iajs-3629	90	11	number	number	NOUN
iajs-3629	90	12	(	(	PUNCT
iajs-3629	90	13	39216	39216	NUM
iajs-3629	90	14	)	)	PUNCT
iajs-3629	90	15	cm-1	cm-1	NOUN
iajs-3629	90	16	.	.	PUNCT
iajs-3629	91	1	l	l	NOUN
iajs-3629	91	2	(	(	PUNCT
iajs-3629	91	3	pro	pro	ADJ
iajs-3629	91	4	)	)	PUNCT
iajs-3629	91	5	cd	cd	NOUN
iajs-3629	91	6	complex	complex	NOUN
iajs-3629	91	7	shows	show	VERB
iajs-3629	91	8	2	2	NUM
iajs-3629	91	9	bands	band	NOUN
iajs-3629	91	10	in	in	ADP
iajs-3629	91	11	the	the	DET
iajs-3629	91	12	wave	wave	NOUN
iajs-3629	91	13	number	number	NOUN
iajs-3629	91	14	(	(	PUNCT
iajs-3629	91	15	34722,29411	34722,29411	NUM
iajs-3629	91	16	)	)	PUNCT
iajs-3629	91	17	cm-1	cm-1	X
iajs-3629	91	18	(	(	PUNCT
iajs-3629	91	19	15,16	15,16	NUM
iajs-3629	91	20	)	)	PUNCT
iajs-3629	91	21	.	.	PUNCT
iajs-3629	92	1	the	the	DET
iajs-3629	92	2	uv	uv	NOUN
iajs-3629	92	3	-	-	PUNCT
iajs-3629	92	4	visb	visb	NOUN
iajs-3629	92	5	spectra	spectra	NOUN
iajs-3629	92	6	of	of	ADP
iajs-3629	92	7	l	l	PROPN
iajs-3629	92	8	(	(	PUNCT
iajs-3629	92	9	pro	pro	ADJ
iajs-3629	92	10	)	)	PUNCT
iajs-3629	92	11	cu	cu	PROPN
iajs-3629	92	12	is	be	AUX
iajs-3629	92	13	shown	show	VERB
iajs-3629	92	14	in	in	ADP
iajs-3629	92	15	figure	figure	NOUN
iajs-3629	92	16	5	5	NUM
iajs-3629	92	17	.	.	PUNCT
iajs-3629	92	18	table	table	NOUN
iajs-3629	92	19	4	4	NUM
iajs-3629	92	20	.	.	PUNCT
iajs-3629	93	1	the	the	DET
iajs-3629	93	2	uv	uv	NOUN
iajs-3629	93	3	-	-	PUNCT
iajs-3629	93	4	visible	visible	ADJ
iajs-3629	93	5	bands	band	NOUN
iajs-3629	93	6	of	of	ADP
iajs-3629	93	7	prepared	prepared	ADJ
iajs-3629	93	8	compounds	compound	NOUN
iajs-3629	93	9	.	.	PUNCT
iajs-3629	94	1	compound	compound	NOUN
iajs-3629	94	2	λ	λ	PROPN
iajs-3629	94	3	nm	nm	PRON
iajs-3629	94	4	absorption	absorption	NOUN
iajs-3629	94	5	bands	band	NOUN
iajs-3629	94	6	cm-1	cm-1	VERB
iajs-3629	94	7	assignment	assignment	NOUN
iajs-3629	94	8	l	l	NOUN
iajs-3629	94	9	328	328	NUM
iajs-3629	94	10	227	227	NUM
iajs-3629	94	11	221	221	NUM
iajs-3629	94	12	30487	30487	NUM
iajs-3629	94	13	44528	44528	NUM
iajs-3629	94	14	45248	45248	NUM
iajs-3629	94	15	π	π	X
iajs-3629	94	16	-	-	PUNCT
iajs-3629	94	17	π	π	X
iajs-3629	94	18	*	*	PUNCT
iajs-3629	94	19	(	(	PUNCT
iajs-3629	94	20	c	c	X
iajs-3629	94	21	=	=	SYM
iajs-3629	94	22	c	c	NOUN
iajs-3629	94	23	)	)	PUNCT
iajs-3629	94	24	n	n	CCONJ
iajs-3629	94	25	-	-	PUNCT
iajs-3629	94	26	π*(co	π*(co	NOUN
iajs-3629	94	27	,	,	PUNCT
iajs-3629	94	28	cn	cn	NOUN
iajs-3629	94	29	)	)	PUNCT
iajs-3629	94	30	pro	pro	X
iajs-3629	95	1	331	331	NUM
iajs-3629	95	2	281	281	NUM
iajs-3629	95	3	30211	30211	NUM
iajs-3629	95	4	35871	35871	NUM
iajs-3629	95	5	π	π	PROPN
iajs-3629	95	6	-	-	PUNCT
iajs-3629	95	7	π	π	X
iajs-3629	95	8	*	*	PUNCT
iajs-3629	95	9	(	(	PUNCT
iajs-3629	95	10	c	c	X
iajs-3629	95	11	=	=	SYM
iajs-3629	95	12	c	c	NOUN
iajs-3629	95	13	)	)	PUNCT
iajs-3629	95	14	n	n	CCONJ
iajs-3629	95	15	-	-	PUNCT
iajs-3629	95	16	π*(co	π*(co	NOUN
iajs-3629	95	17	,	,	PUNCT
iajs-3629	95	18	cn	cn	PROPN
iajs-3629	95	19	)	)	PUNCT
iajs-3629	95	20	l	l	NOUN
iajs-3629	95	21	(	(	PUNCT
iajs-3629	95	22	pro)co	pro)co	VERB
iajs-3629	95	23	686	686	NUM
iajs-3629	95	24	608	608	NUM
iajs-3629	95	25	430	430	NUM
iajs-3629	95	26	288	288	NUM
iajs-3629	95	27	14755	14755	NUM
iajs-3629	95	28	16447	16447	NUM
iajs-3629	95	29	23255	23255	NUM
iajs-3629	95	30	34722	34722	NUM
iajs-3629	95	31	4t1	4t1	NUM
iajs-3629	95	32	g	g	PROPN
iajs-3629	95	33	→	→	SYM
iajs-3629	95	34	4t2	4t2	NUM
iajs-3629	95	35	g	g	NOUN
iajs-3629	95	36	4t1	4t1	NUM
iajs-3629	95	37	g	g	NOUN
iajs-3629	95	38	→	→	SYM
iajs-3629	95	39	4t1	4t1	NUM
iajs-3629	95	40	g	g	NOUN
iajs-3629	95	41	4t1	4t1	NUM
iajs-3629	95	42	g	g	NOUN
iajs-3629	95	43	→	→	SYM
iajs-3629	95	44	4a2	4a2	NUM
iajs-3629	95	45	g	g	PROPN
iajs-3629	95	46	i.l	i.l	PROPN
iajs-3629	95	47	l	l	NOUN
iajs-3629	95	48	(	(	PUNCT
iajs-3629	95	49	pro	pro	ADJ
iajs-3629	95	50	)	)	PUNCT
iajs-3629	95	51	ni	ni	NOUN
iajs-3629	95	52	895	895	NUM
iajs-3629	95	53	630	630	NUM
iajs-3629	95	54	486	486	NUM
iajs-3629	95	55	287	287	NUM
iajs-3629	95	56	11173	11173	NUM
iajs-3629	95	57	15873	15873	NUM
iajs-3629	95	58	20576	20576	NUM
iajs-3629	95	59	34843	34843	NUM
iajs-3629	95	60	3a2	3a2	NUM
iajs-3629	95	61	g	g	NOUN
iajs-3629	95	62	→	→	SYM
iajs-3629	95	63	3t2	3t2	NUM
iajs-3629	95	64	g	g	ADP
iajs-3629	95	65	3a2	3a2	NUM
iajs-3629	95	66	g	g	NOUN
iajs-3629	95	67	→	→	SYM
iajs-3629	95	68	3t1g(f	3t1g(f	NUM
iajs-3629	95	69	)	)	PUNCT
iajs-3629	95	70	3a2	3a2	NUM
iajs-3629	95	71	g	g	NOUN
iajs-3629	95	72	→	→	SYM
iajs-3629	95	73	3t1g(p	3t1g(p	NUM
iajs-3629	95	74	)	)	PUNCT
iajs-3629	95	75	i.l	i.l	PROPN
iajs-3629	95	76	l	l	NOUN
iajs-3629	95	77	(	(	PUNCT
iajs-3629	95	78	pro	pro	ADJ
iajs-3629	95	79	)	)	PUNCT
iajs-3629	95	80	cu	cu	NOUN
iajs-3629	95	81	770	770	NUM
iajs-3629	95	82	361	361	NUM
iajs-3629	95	83	242	242	NUM
iajs-3629	95	84	12987	12987	NUM
iajs-3629	95	85	2770	2770	NUM
iajs-3629	95	86	41322	41322	NUM
iajs-3629	95	87	2eg	2eg	NOUN
iajs-3629	95	88	→	→	SYM
iajs-3629	95	89	2t2	2t2	NUM
iajs-3629	95	90	g	g	NOUN
iajs-3629	95	91	charge	charge	NOUN
iajs-3629	95	92	transfer	transfer	NOUN
iajs-3629	95	93	ilct	ilct	NOUN
iajs-3629	95	94	l	l	NOUN
iajs-3629	95	95	(	(	PUNCT
iajs-3629	95	96	pro)zn	pro)zn	NOUN
iajs-3629	95	97	255	255	NUM
iajs-3629	95	98	327	327	NUM
iajs-3629	95	99	39216	39216	NUM
iajs-3629	95	100	ilct	ilct	NUM
iajs-3629	95	101	ilct	ilct	NOUN
iajs-3629	95	102	l	l	NOUN
iajs-3629	95	103	(	(	PUNCT
iajs-3629	95	104	pro)cd	pro)cd	NOUN
iajs-3629	95	105	288	288	NUM
iajs-3629	95	106	340	340	NUM
iajs-3629	95	107	34722	34722	NUM
iajs-3629	95	108	29411	29411	NUM
iajs-3629	95	109	ilct	ilct	ADJ
iajs-3629	95	110	ilct	ilct	NOUN
iajs-3629	95	111	ihjpas	ihjpa	NOUN
iajs-3629	95	112	.	.	PUNCT
iajs-3629	96	1	2025,38(2	2025,38(2	NOUN
iajs-3629	96	2	)	)	PUNCT
iajs-3629	96	3	255	255	NUM
iajs-3629	97	1	(	(	PUNCT
iajs-3629	97	2	a	a	NOUN
iajs-3629	97	3	)	)	PUNCT
iajs-3629	97	4	(	(	PUNCT
iajs-3629	97	5	b	b	X
iajs-3629	97	6	)	)	PUNCT
iajs-3629	97	7	figure	figure	NOUN
iajs-3629	97	8	4	4	NUM
iajs-3629	97	9	.	.	PUNCT
iajs-3629	98	1	the	the	DET
iajs-3629	98	2	uv	uv	NOUN
iajs-3629	98	3	-	-	PUNCT
iajs-3629	98	4	visb	visb	NOUN
iajs-3629	98	5	spectra	spectra	NOUN
iajs-3629	98	6	of	of	ADP
iajs-3629	98	7	flu	flu	NOUN
iajs-3629	98	8	and	and	CCONJ
iajs-3629	98	9	pro	pro	ADJ
iajs-3629	98	10	.	.	PUNCT
iajs-3629	98	11	figure	figure	NOUN
iajs-3629	98	12	5	5	NUM
iajs-3629	98	13	.	.	PUNCT
iajs-3629	99	1	the	the	DET
iajs-3629	99	2	uv	uv	NOUN
iajs-3629	99	3	-	-	PUNCT
iajs-3629	99	4	visb	visb	NOUN
iajs-3629	99	5	spectra	spectra	NOUN
iajs-3629	99	6	of	of	ADP
iajs-3629	99	7	l	l	PROPN
iajs-3629	99	8	(	(	PUNCT
iajs-3629	99	9	pro	pro	ADJ
iajs-3629	99	10	)	)	PUNCT
iajs-3629	99	11	cu	cu	PROPN
iajs-3629	99	12	.	.	PROPN
iajs-3629	99	13	3.3	3.3	NUM
iajs-3629	99	14	.	.	PUNCT
iajs-3629	100	1	the	the	DET
iajs-3629	100	2	1h	1h	NUM
iajs-3629	100	3	nmr	nmr	NOUN
iajs-3629	100	4	spectrum	spectrum	NOUN
iajs-3629	100	5	of	of	ADP
iajs-3629	100	6	l(pro	l(pro	PROPN
iajs-3629	100	7	)	)	PUNCT
iajs-3629	100	8	the	the	DET
iajs-3629	100	9	1hnmr	1hnmr	NUM
iajs-3629	100	10	spectrum	spectrum	NOUN
iajs-3629	100	11	of	of	ADP
iajs-3629	100	12	the	the	DET
iajs-3629	100	13	mixed	mixed	ADJ
iajs-3629	100	14	ligand	ligand	NOUN
iajs-3629	100	15	l	l	NOUN
iajs-3629	100	16	(	(	PUNCT
iajs-3629	100	17	pro	pro	ADJ
iajs-3629	100	18	)	)	PUNCT
iajs-3629	100	19	was	be	AUX
iajs-3629	100	20	measured	measure	VERB
iajs-3629	100	21	using	use	VERB
iajs-3629	100	22	dmso	dmso	NOUN
iajs-3629	100	23	as	as	ADP
iajs-3629	100	24	a	a	DET
iajs-3629	100	25	solvent	solvent	NOUN
iajs-3629	100	26	,	,	PUNCT
iajs-3629	100	27	as	as	SCONJ
iajs-3629	100	28	illustrated	illustrate	VERB
iajs-3629	100	29	in	in	ADP
iajs-3629	100	30	figure	figure	NOUN
iajs-3629	100	31	6	6	NUM
iajs-3629	100	32	,	,	PUNCT
iajs-3629	100	33	where	where	SCONJ
iajs-3629	100	34	the	the	DET
iajs-3629	100	35	mono	mono	PROPN
iajs-3629	100	36	signal	signal	NOUN
iajs-3629	100	37	at	at	ADP
iajs-3629	100	38	σ	σ	PROPN
iajs-3629	100	39	(	(	PUNCT
iajs-3629	100	40	2.53	2.53	NUM
iajs-3629	100	41	)	)	PUNCT
iajs-3629	100	42	ppm	ppm	NOUN
iajs-3629	100	43	refers	refer	VERB
iajs-3629	100	44	to	to	ADP
iajs-3629	100	45	the	the	DET
iajs-3629	100	46	dmso	dmso	ADJ
iajs-3629	100	47	solvent	solvent	NOUN
iajs-3629	100	48	and	and	CCONJ
iajs-3629	100	49	the	the	DET
iajs-3629	100	50	mono	mono	PROPN
iajs-3629	100	51	signal	signal	NOUN
iajs-3629	100	52	at	at	ADP
iajs-3629	100	53	(	(	PUNCT
iajs-3629	100	54	3.35	3.35	NUM
iajs-3629	100	55	)	)	PUNCT
iajs-3629	100	56	that	that	PRON
iajs-3629	100	57	belongs	belong	VERB
iajs-3629	100	58	to	to	ADP
iajs-3629	100	59	3h	3h	NUM
iajs-3629	100	60	,	,	PUNCT
iajs-3629	100	61	ch3	ch3	PROPN
iajs-3629	100	62	-	-	PUNCT
iajs-3629	100	63	o	o	PROPN
iajs-3629	100	64	and	and	CCONJ
iajs-3629	100	65	the	the	DET
iajs-3629	100	66	treble	treble	ADJ
iajs-3629	100	67	signal	signal	NOUN
iajs-3629	100	68	at	at	ADP
iajs-3629	100	69	σ	σ	PROPN
iajs-3629	100	70	(	(	PUNCT
iajs-3629	100	71	3.67	3.67	NUM
iajs-3629	100	72	)	)	PUNCT
iajs-3629	100	73	ppm	ppm	NOUN
iajs-3629	100	74	which	which	PRON
iajs-3629	100	75	belongs	belong	VERB
iajs-3629	100	76	to	to	ADP
iajs-3629	100	77	9h	9h	NUM
iajs-3629	100	78	,	,	PUNCT
iajs-3629	100	79	ch3	ch3	PROPN
iajs-3629	100	80	,	,	PUNCT
iajs-3629	100	81	(	(	PUNCT
iajs-3629	100	82	7.30	7.30	NUM
iajs-3629	100	83	)	)	PUNCT
iajs-3629	100	84	ppm	ppm	NOUN
iajs-3629	100	85	due	due	ADP
iajs-3629	100	86	to	to	ADP
iajs-3629	100	87	ch2	ch2	NOUN
iajs-3629	100	88	-	-	PUNCT
iajs-3629	100	89	n	n	NOUN
iajs-3629	100	90	for	for	ADP
iajs-3629	100	91	β	β	NOUN
iajs-3629	100	92	-	-	NOUN
iajs-3629	100	93	lactam	lactam	NOUN
iajs-3629	100	94	cycle	cycle	NOUN
iajs-3629	100	95	,	,	PUNCT
iajs-3629	100	96	and	and	CCONJ
iajs-3629	100	97	the	the	DET
iajs-3629	100	98	mixed	mixed	ADJ
iajs-3629	100	99	ligand	ligand	NOUN
iajs-3629	100	100	spectrum	spectrum	NOUN
iajs-3629	100	101	showed	show	VERB
iajs-3629	100	102	a	a	DET
iajs-3629	100	103	signal	signal	NOUN
iajs-3629	100	104	at	at	ADP
iajs-3629	100	105	σ	σ	PROPN
iajs-3629	100	106	(	(	PUNCT
iajs-3629	100	107	8.52	8.52	NUM
iajs-3629	100	108	)	)	PUNCT
iajs-3629	100	109	ppm	ppm	NOUN
iajs-3629	100	110	,	,	PUNCT
iajs-3629	100	111	which	which	PRON
iajs-3629	100	112	is	be	AUX
iajs-3629	100	113	attributed	attribute	VERB
iajs-3629	100	114	to	to	ADP
iajs-3629	100	115	3h	3h	NUM
iajs-3629	100	116	,	,	PUNCT
iajs-3629	100	117	nh	nh	PROPN
iajs-3629	100	118	,	,	PUNCT
iajs-3629	100	119	amine	amine	NOUN
iajs-3629	100	120	.	.	PUNCT
iajs-3629	101	1	it	it	PRON
iajs-3629	101	2	also	also	ADV
iajs-3629	101	3	showed	show	VERB
iajs-3629	101	4	a	a	DET
iajs-3629	101	5	mono	mono	NOUN
iajs-3629	101	6	signal	signal	NOUN
iajs-3629	101	7	at	at	ADP
iajs-3629	101	8	σ	σ	PROPN
iajs-3629	101	9	(	(	PUNCT
iajs-3629	101	10	9.20	9.20	NUM
iajs-3629	101	11	)	)	PUNCT
iajs-3629	101	12	ppm	ppm	NOUN
iajs-3629	101	13	due	due	ADP
iajs-3629	101	14	to	to	ADP
iajs-3629	101	15	1h	1h	NUM
iajs-3629	101	16	-	-	PUNCT
iajs-3629	101	17	nh	nh	NOUN
iajs-3629	101	18	amide	amide	NOUN
iajs-3629	101	19	.	.	PUNCT
iajs-3629	102	1	table	table	NOUN
iajs-3629	102	2	5	5	NUM
iajs-3629	102	3	shows	show	VERB
iajs-3629	102	4	the	the	DET
iajs-3629	102	5	apparent	apparent	ADJ
iajs-3629	102	6	signals	signal	NOUN
iajs-3629	102	7	and	and	CCONJ
iajs-3629	102	8	the	the	DET
iajs-3629	102	9	chemical	chemical	NOUN
iajs-3629	102	10	shifted	shift	VERB
iajs-3629	102	11	values	value	NOUN
iajs-3629	102	12	measured	measure	VERB
iajs-3629	102	13	in	in	ADP
iajs-3629	102	14	ppm	ppm	PROPN
iajs-3629	102	15	(	(	PUNCT
iajs-3629	102	16	17,18	17,18	NUM
iajs-3629	102	17	)	)	PUNCT
iajs-3629	102	18	.	.	PUNCT
iajs-3629	103	1	table	table	NOUN
iajs-3629	103	2	5	5	NUM
iajs-3629	103	3	.	.	PUNCT
iajs-3629	104	1	the	the	DET
iajs-3629	104	2	1h	1h	NUM
iajs-3629	104	3	nmr	nmr	NOUN
iajs-3629	104	4	spectrum	spectrum	NOUN
iajs-3629	104	5	of	of	ADP
iajs-3629	104	6	l(pro	l(pro	ADJ
iajs-3629	104	7	)	)	PUNCT
iajs-3629	104	8	c25h27clfn4o7s	c25h27clfn4o7s	NOUN
iajs-3629	104	9	.	.	PUNCT
iajs-3629	105	1	σ(ppm	σ(ppm	NOUN
iajs-3629	105	2	)	)	PUNCT
iajs-3629	105	3	no	no	PRON
iajs-3629	105	4	of	of	ADP
iajs-3629	105	5	proton	proton	NOUN
iajs-3629	105	6	compound	compound	NOUN
iajs-3629	106	1	3.35	3.35	NUM
iajs-3629	106	2	o)-3s(3h	o)-3s(3h	NOUN
iajs-3629	106	3	,	,	PUNCT
iajs-3629	106	4	ch	ch	NOUN
iajs-3629	106	5	)	)	PUNCT
iajs-3629	106	6	pro(2l	pro(2l	NOUN
iajs-3629	106	7	3.67	3.67	NUM
iajs-3629	106	8	t(9h	t(9h	NUM
iajs-3629	106	9	,	,	PUNCT
iajs-3629	106	10	ch3	ch3	PROPN
iajs-3629	106	11	)	)	PUNCT
iajs-3629	106	12	4.82	4.82	NUM
iajs-3629	106	13	s(2h	s(2h	NUM
iajs-3629	106	14	,	,	PUNCT
iajs-3629	106	15	sch	sch	INTJ
iajs-3629	106	16	)	)	PUNCT
iajs-3629	106	17	5.83	5.83	NUM
iajs-3629	106	18	-6.73	-6.73	NUM
iajs-3629	106	19	2d(7h	2d(7h	NUM
iajs-3629	106	20	,	,	PUNCT
iajs-3629	106	21	cyclo	cyclo	NOUN
iajs-3629	106	22	)	)	PUNCT
iajs-3629	106	23	7.30	7.30	NUM
iajs-3629	106	24	lactam	lactam	NOUN
iajs-3629	106	25	-	-	PUNCT
iajs-3629	106	26	n	n	CCONJ
iajs-3629	106	27	)	)	PUNCT
iajs-3629	106	28	β-2	β-2	PROPN
iajs-3629	106	29	t	t	PROPN
iajs-3629	106	30	(	(	PUNCT
iajs-3629	106	31	2h	2h	NUM
iajs-3629	106	32	,	,	PUNCT
iajs-3629	106	33	ch	ch	NOUN
iajs-3629	106	34	8.52	8.52	NUM
iajs-3629	106	35	d	d	PROPN
iajs-3629	106	36	(	(	PUNCT
iajs-3629	106	37	3h	3h	NUM
iajs-3629	106	38	,	,	PUNCT
iajs-3629	106	39	nh	nh	PROPN
iajs-3629	106	40	,	,	PUNCT
iajs-3629	106	41	amine	amine	ADJ
iajs-3629	106	42	)	)	PUNCT
iajs-3629	106	43	9.20	9.20	NUM
iajs-3629	106	44	s	s	NOUN
iajs-3629	106	45	(	(	PUNCT
iajs-3629	106	46	1h	1h	NUM
iajs-3629	106	47	,	,	PUNCT
iajs-3629	106	48	nh	nh	NOUN
iajs-3629	106	49	,	,	PUNCT
iajs-3629	106	50	proline	proline	NOUN
iajs-3629	106	51	)	)	PUNCT
iajs-3629	106	52	ihjpas	ihjpas	PROPN
iajs-3629	106	53	.	.	PUNCT
iajs-3629	107	1	2025,38(2	2025,38(2	NOUN
iajs-3629	107	2	)	)	PUNCT
iajs-3629	107	3	256	256	NUM
iajs-3629	107	4	figure	figure	NOUN
iajs-3629	107	5	6	6	NUM
iajs-3629	107	6	.	.	PUNCT
iajs-3629	108	1	the	the	DET
iajs-3629	108	2	1hmnr	1hmnr	NUM
iajs-3629	108	3	spectrum	spectrum	NOUN
iajs-3629	108	4	of	of	ADP
iajs-3629	108	5	l.	l.	PROPN
iajs-3629	108	6	3.4	3.4	NUM
iajs-3629	108	7	.	.	PUNCT
iajs-3629	109	1	theoretical	theoretical	ADJ
iajs-3629	109	2	study	study	NOUN
iajs-3629	109	3	hyperchemprogramme	hyperchemprogramme	NOUN
iajs-3629	109	4	is	be	AUX
iajs-3629	109	5	an	an	DET
iajs-3629	109	6	advanced	advanced	ADJ
iajs-3629	109	7	molecular	molecular	ADJ
iajs-3629	109	8	modeler	modeler	NOUN
iajs-3629	109	9	,	,	PUNCT
iajs-3629	109	10	editor	editor	NOUN
iajs-3629	109	11	,	,	PUNCT
iajs-3629	109	12	and	and	CCONJ
iajs-3629	109	13	potent	potent	ADJ
iajs-3629	109	14	computational	computational	ADJ
iajs-3629	109	15	suite	suite	NOUN
iajs-3629	109	16	renowned	renowne	VERB
iajs-3629	109	17	for	for	ADP
iajs-3629	109	18	its	its	PRON
iajs-3629	109	19	quality	quality	NOUN
iajs-3629	109	20	,	,	PUNCT
iajs-3629	109	21	adaptability	adaptability	NOUN
iajs-3629	109	22	,	,	PUNCT
iajs-3629	109	23	and	and	CCONJ
iajs-3629	109	24	user	user	NOUN
iajs-3629	109	25	-	-	PUNCT
iajs-3629	109	26	friendliness	friendliness	ADJ
iajs-3629	109	27	(	(	PUNCT
iajs-3629	109	28	19	19	NUM
iajs-3629	109	29	)	)	PUNCT
iajs-3629	109	30	.	.	PUNCT
iajs-3629	110	1	to	to	PART
iajs-3629	110	2	optimize	optimize	VERB
iajs-3629	110	3	geometry	geometry	NOUN
iajs-3629	110	4	,	,	PUNCT
iajs-3629	110	5	it	it	PRON
iajs-3629	110	6	can	can	AUX
iajs-3629	110	7	calculate	calculate	VERB
iajs-3629	110	8	electrostatic	electrostatic	ADJ
iajs-3629	110	9	potential	potential	NOUN
iajs-3629	110	10	,	,	PUNCT
iajs-3629	110	11	total	total	ADJ
iajs-3629	110	12	charge	charge	NOUN
iajs-3629	110	13	density	density	NOUN
iajs-3629	110	14	,	,	PUNCT
iajs-3629	110	15	and	and	CCONJ
iajs-3629	110	16	thermodynamic	thermodynamic	ADJ
iajs-3629	110	17	functions	function	NOUN
iajs-3629	110	18	.	.	PUNCT
iajs-3629	111	1	the	the	DET
iajs-3629	111	2	semi	semi	ADJ
iajs-3629	111	3	-	-	ADJ
iajs-3629	111	4	empirical	empirical	ADJ
iajs-3629	111	5	method	method	NOUN
iajs-3629	111	6	is	be	AUX
iajs-3629	111	7	one	one	NUM
iajs-3629	111	8	of	of	ADP
iajs-3629	111	9	the	the	DET
iajs-3629	111	10	most	most	ADV
iajs-3629	111	11	essential	essential	ADJ
iajs-3629	111	12	methods	method	NOUN
iajs-3629	111	13	employed	employ	VERB
iajs-3629	111	14	.	.	PUNCT
iajs-3629	112	1	this	this	DET
iajs-3629	112	2	information	information	NOUN
iajs-3629	112	3	is	be	AUX
iajs-3629	112	4	valuable	valuable	ADJ
iajs-3629	112	5	for	for	ADP
iajs-3629	112	6	assessing	assess	VERB
iajs-3629	112	7	reactivity	reactivity	NOUN
iajs-3629	112	8	and	and	CCONJ
iajs-3629	112	9	establishing	establish	VERB
iajs-3629	112	10	a	a	DET
iajs-3629	112	11	correlation	correlation	NOUN
iajs-3629	112	12	between	between	ADP
iajs-3629	112	13	computational	computational	ADJ
iajs-3629	112	14	outcomes	outcome	NOUN
iajs-3629	112	15	and	and	CCONJ
iajs-3629	112	16	experimental	experimental	ADJ
iajs-3629	112	17	data	datum	NOUN
iajs-3629	112	18	.	.	PUNCT
iajs-3629	113	1	3.5	3.5	NUM
iajs-3629	113	2	.	.	PUNCT
iajs-3629	114	1	electrostatic	electrostatic	ADJ
iajs-3629	114	2	potential	potential	NOUN
iajs-3629	114	3	the	the	DET
iajs-3629	114	4	pm3	pm3	PROPN
iajs-3629	114	5	method	method	NOUN
iajs-3629	114	6	was	be	AUX
iajs-3629	114	7	used	use	VERB
iajs-3629	114	8	to	to	PART
iajs-3629	114	9	measure	measure	VERB
iajs-3629	114	10	the	the	DET
iajs-3629	114	11	electrostatic	electrostatic	ADJ
iajs-3629	114	12	potential	potential	NOUN
iajs-3629	114	13	(	(	PUNCT
iajs-3629	114	14	e.p	e.p	PROPN
iajs-3629	114	15	)	)	PUNCT
iajs-3629	114	16	of	of	ADP
iajs-3629	114	17	a	a	DET
iajs-3629	114	18	molecular	molecular	ADJ
iajs-3629	114	19	system	system	NOUN
iajs-3629	114	20	with	with	ADP
iajs-3629	114	21	a	a	DET
iajs-3629	114	22	positively	positively	ADV
iajs-3629	114	23	charged	charge	VERB
iajs-3629	114	24	point	point	NOUN
iajs-3629	114	25	,	,	PUNCT
iajs-3629	114	26	with	with	ADP
iajs-3629	114	27	the	the	DET
iajs-3629	114	28	objective	objective	NOUN
iajs-3629	114	29	of	of	ADP
iajs-3629	114	30	identifying	identify	VERB
iajs-3629	114	31	the	the	DET
iajs-3629	114	32	most	most	ADV
iajs-3629	114	33	active	active	ADJ
iajs-3629	114	34	interaction	interaction	NOUN
iajs-3629	114	35	sites	site	NOUN
iajs-3629	114	36	within	within	ADP
iajs-3629	114	37	the	the	DET
iajs-3629	114	38	positively	positively	ADV
iajs-3629	114	39	charged	charge	VERB
iajs-3629	114	40	particle	particle	NOUN
iajs-3629	114	41	species	specie	NOUN
iajs-3629	114	42	.	.	PUNCT
iajs-3629	115	1	these	these	DET
iajs-3629	115	2	entities	entity	NOUN
iajs-3629	115	3	tend	tend	VERB
iajs-3629	115	4	to	to	PART
iajs-3629	115	5	target	target	VERB
iajs-3629	115	6	a	a	DET
iajs-3629	115	7	molecule	molecule	NOUN
iajs-3629	115	8	with	with	ADP
iajs-3629	115	9	a	a	DET
iajs-3629	115	10	highly	highly	ADV
iajs-3629	115	11	negative	negative	ADJ
iajs-3629	115	12	and	and	CCONJ
iajs-3629	115	13	electrophilic	electrophilic	ADJ
iajs-3629	115	14	electron	electron	NOUN
iajs-3629	115	15	pair	pair	NOUN
iajs-3629	115	16	(	(	PUNCT
iajs-3629	115	17	20,21	20,21	NUM
iajs-3629	115	18	)	)	PUNCT
iajs-3629	115	19	.	.	PUNCT
iajs-3629	116	1	the	the	DET
iajs-3629	116	2	e.p	e.p	PROPN
iajs-3629	116	3	of	of	ADP
iajs-3629	116	4	the	the	DET
iajs-3629	116	5	ligands	ligand	NOUN
iajs-3629	116	6	(	(	PUNCT
iajs-3629	116	7	flx	flx	NOUN
iajs-3629	116	8	,	,	PUNCT
iajs-3629	116	9	proline	proline	NOUN
iajs-3629	116	10	)	)	PUNCT
iajs-3629	116	11	were	be	AUX
iajs-3629	116	12	determined	determine	VERB
iajs-3629	116	13	and	and	CCONJ
iajs-3629	116	14	visualized	visualize	VERB
iajs-3629	116	15	through	through	ADP
iajs-3629	116	16	2d	2d	NUM
iajs-3629	116	17	and	and	CCONJ
iajs-3629	116	18	3d	3d	NUM
iajs-3629	116	19	contour	contour	NOUN
iajs-3629	116	20	plots	plot	NOUN
iajs-3629	116	21	.	.	PUNCT
iajs-3629	117	1	these	these	DET
iajs-3629	117	2	plots	plot	NOUN
iajs-3629	117	3	were	be	AUX
iajs-3629	117	4	utilized	utilize	VERB
iajs-3629	117	5	to	to	PART
iajs-3629	117	6	analyse	analyse	VERB
iajs-3629	117	7	the	the	DET
iajs-3629	117	8	reactive	reactive	ADJ
iajs-3629	117	9	sites	site	NOUN
iajs-3629	117	10	within	within	ADP
iajs-3629	117	11	the	the	DET
iajs-3629	117	12	molecules	molecule	NOUN
iajs-3629	117	13	,	,	PUNCT
iajs-3629	117	14	as	as	SCONJ
iajs-3629	117	15	illustrated	illustrate	VERB
iajs-3629	117	16	in	in	ADP
iajs-3629	117	17	figure	figure	NOUN
iajs-3629	117	18	7	7	NUM
iajs-3629	117	19	.	.	NOUN
iajs-3629	117	20	3.6	3.6	NUM
iajs-3629	117	21	.	.	PUNCT
iajs-3629	118	1	energies	energy	NOUN
iajs-3629	118	2	and	and	CCONJ
iajs-3629	118	3	optimized	optimize	VERB
iajs-3629	118	4	geometries	geometry	NOUN
iajs-3629	118	5	of	of	ADP
iajs-3629	118	6	metal	metal	NOUN
iajs-3629	118	7	complexes	complex	NOUN
iajs-3629	118	8	for	for	ADP
iajs-3629	118	9	the	the	DET
iajs-3629	118	10	ligand	ligand	ADJ
iajs-3629	118	11	theoretical	theoretical	ADJ
iajs-3629	118	12	treatment	treatment	NOUN
iajs-3629	118	13	was	be	AUX
iajs-3629	118	14	used	use	VERB
iajs-3629	118	15	to	to	PART
iajs-3629	118	16	find	find	VERB
iajs-3629	118	17	the	the	DET
iajs-3629	118	18	most	most	ADV
iajs-3629	118	19	stable	stable	ADJ
iajs-3629	118	20	structures	structure	NOUN
iajs-3629	118	21	for	for	ADP
iajs-3629	118	22	the	the	DET
iajs-3629	118	23	metal	metal	NOUN
iajs-3629	118	24	complexes	complex	NOUN
iajs-3629	118	25	with	with	ADP
iajs-3629	118	26	ligands	ligand	NOUN
iajs-3629	118	27	(	(	PUNCT
iajs-3629	118	28	22,23	22,23	NOUN
iajs-3629	118	29	)	)	PUNCT
iajs-3629	118	30	.	.	PUNCT
iajs-3629	119	1	depending	depend	VERB
iajs-3629	119	2	on	on	ADP
iajs-3629	119	3	the	the	DET
iajs-3629	119	4	method	method	NOUN
iajs-3629	119	5	(	(	PUNCT
iajs-3629	119	6	pm3	pm3	PROPN
iajs-3629	119	7	)	)	PUNCT
iajs-3629	119	8	,	,	PUNCT
iajs-3629	119	9	the	the	DET
iajs-3629	119	10	geometric	geometric	ADJ
iajs-3629	119	11	configurations	configuration	NOUN
iajs-3629	119	12	depicted	depict	VERB
iajs-3629	119	13	in	in	ADP
iajs-3629	119	14	figure	figure	NOUN
iajs-3629	119	15	8	8	NUM
iajs-3629	119	16	correspond	correspond	NOUN
iajs-3629	119	17	to	to	ADP
iajs-3629	119	18	the	the	DET
iajs-3629	119	19	most	most	ADV
iajs-3629	119	20	favorable	favorable	ADJ
iajs-3629	119	21	computation	computation	NOUN
iajs-3629	119	22	geometries	geometry	NOUN
iajs-3629	119	23	for	for	ADP
iajs-3629	119	24	both	both	CCONJ
iajs-3629	119	25	the	the	DET
iajs-3629	119	26	ligand	ligand	NOUN
iajs-3629	119	27	and	and	CCONJ
iajs-3629	119	28	its	its	PRON
iajs-3629	119	29	complexes	complex	NOUN
iajs-3629	119	30	.	.	PUNCT
iajs-3629	120	1	semi	semi	ADJ
iajs-3629	120	2	-	-	ADJ
iajs-3629	120	3	empirical	empirical	ADJ
iajs-3629	120	4	techniques	technique	NOUN
iajs-3629	120	5	are	be	AUX
iajs-3629	120	6	used	use	VERB
iajs-3629	120	7	to	to	PART
iajs-3629	120	8	calculate	calculate	VERB
iajs-3629	120	9	the	the	DET
iajs-3629	120	10	thermodynamic	thermodynamic	ADJ
iajs-3629	120	11	functions	function	NOUN
iajs-3629	120	12	(	(	PUNCT
iajs-3629	120	13	∆hf	∆hf	NOUN
iajs-3629	120	14	,	,	PUNCT
iajs-3629	120	15	∆eb	∆eb	ADP
iajs-3629	120	16	,	,	PUNCT
iajs-3629	120	17	and	and	CCONJ
iajs-3629	120	18	∆et	∆et	PROPN
iajs-3629	120	19	)	)	PUNCT
iajs-3629	120	20	of	of	ADP
iajs-3629	120	21	compounds	compound	NOUN
iajs-3629	120	22	in	in	ADP
iajs-3629	120	23	the	the	DET
iajs-3629	120	24	gas	gas	NOUN
iajs-3629	120	25	phase	phase	NOUN
iajs-3629	120	26	at	at	ADP
iajs-3629	120	27	0	0	NUM
iajs-3629	120	28	°	°	NOUN
iajs-3629	120	29	k	k	NOUN
iajs-3629	120	30	,	,	PUNCT
iajs-3629	120	31	as	as	SCONJ
iajs-3629	120	32	tabulated	tabulate	VERB
iajs-3629	120	33	in	in	ADP
iajs-3629	120	34	table	table	NOUN
iajs-3629	120	35	6	6	NUM
iajs-3629	120	36	.	.	PUNCT
iajs-3629	120	37	table	table	NOUN
iajs-3629	120	38	6	6	NUM
iajs-3629	120	39	.	.	PUNCT
iajs-3629	121	1	energies	energy	NOUN
iajs-3629	121	2	of	of	ADP
iajs-3629	121	3	shapes	shape	NOUN
iajs-3629	121	4	(	(	PUNCT
iajs-3629	121	5	kj.mol-1	kj.mol-1	PROPN
iajs-3629	121	6	)	)	PUNCT
iajs-3629	121	7	for	for	ADP
iajs-3629	121	8	the	the	DET
iajs-3629	121	9	(	(	PUNCT
iajs-3629	121	10	l1,l2	l1,l2	PROPN
iajs-3629	121	11	and	and	CCONJ
iajs-3629	121	12	metal	metal	NOUN
iajs-3629	121	13	complexes	complex	NOUN
iajs-3629	121	14	)	)	PUNCT
iajs-3629	121	15	.	.	PUNCT
iajs-3629	122	1	compounds	compound	VERB
iajs-3629	122	2	pm3	pm3	PROPN
iajs-3629	122	3	flx	flx	PROPN
iajs-3629	122	4	δhf	δhf	ADV
iajs-3629	122	5	-475.05	-475.05	PROPN
iajs-3629	122	6	δeb	δeb	NOUN
iajs-3629	122	7	-19770.44	-19770.44	VERB
iajs-3629	122	8	δet	δet	ADJ
iajs-3629	122	9	-507738.67	-507738.67	ADJ
iajs-3629	122	10	proline	proline	NOUN
iajs-3629	122	11	-418.29	-418.29	PROPN
iajs-3629	122	12	6930.79	6930.79	NUM
iajs-3629	122	13	143078.96	143078.96	NUM
iajs-3629	122	14	l	l	NOUN
iajs-3629	122	15	(	(	PUNCT
iajs-3629	122	16	pro	pro	X
iajs-3629	122	17	)	)	PUNCT
iajs-3629	122	18	co	co	VERB
iajs-3629	122	19	-2656.6	-2656.6	VERB
iajs-3629	122	20	29610.09	29610.09	NUM
iajs-3629	122	21	785939.97	785939.97	NUM
iajs-3629	122	22	l	l	NOUN
iajs-3629	122	23	(	(	PUNCT
iajs-3629	122	24	pro	pro	ADJ
iajs-3629	122	25	)	)	PUNCT
iajs-3629	122	26	cu	cu	NOUN
iajs-3629	122	27	1645.13	1645.13	NUM
iajs-3629	122	28	28507.77	28507.77	NUM
iajs-3629	122	29	823673.68	823673.68	NUM
iajs-3629	122	30	l	l	NOUN
iajs-3629	122	31	(	(	PUNCT
iajs-3629	122	32	pro	pro	ADJ
iajs-3629	122	33	)	)	PUNCT
iajs-3629	122	34	ni	ni	PROPN
iajs-3629	122	35	2379.65	2379.65	NUM
iajs-3629	122	36	29334.82	29334.82	NUM
iajs-3629	122	37	810222.17	810222.17	NUM
iajs-3629	122	38	l	l	NOUN
iajs-3629	122	39	(	(	PUNCT
iajs-3629	122	40	pro	pro	ADJ
iajs-3629	122	41	)	)	PUNCT
iajs-3629	122	42	zn	zn	PROPN
iajs-3629	122	43	794.31	794.31	NUM
iajs-3629	122	44	27449.58	27449.58	NUM
iajs-3629	122	45	711345.43	711345.43	NUM
iajs-3629	122	46	l	l	NOUN
iajs-3629	122	47	(	(	PUNCT
iajs-3629	122	48	pro	pro	ADJ
iajs-3629	122	49	)	)	PUNCT
iajs-3629	122	50	cd	cd	NOUN
iajs-3629	122	51	893.47	893.47	NUM
iajs-3629	122	52	27530.1	27530.1	NUM
iajs-3629	122	53	710949.28	710949.28	NUM
iajs-3629	122	54	ihjpas	ihjpa	NOUN
iajs-3629	122	55	.	.	PUNCT
iajs-3629	123	1	2025,38(2	2025,38(2	PROPN
iajs-3629	123	2	)	)	PUNCT
iajs-3629	124	1	257	257	NUM
iajs-3629	124	2	3.7	3.7	NUM
iajs-3629	124	3	.	.	PUNCT
iajs-3629	124	4	optimized	optimize	VERB
iajs-3629	124	5	vibrational	vibrational	ADJ
iajs-3629	124	6	spectra	spectra	NOUN
iajs-3629	124	7	theoretically	theoretically	ADV
iajs-3629	124	8	,	,	PUNCT
iajs-3629	124	9	calculated	calculate	VERB
iajs-3629	124	10	molecular	molecular	ADJ
iajs-3629	124	11	frequencies	frequency	NOUN
iajs-3629	124	12	of	of	ADP
iajs-3629	124	13	vibration	vibration	NOUN
iajs-3629	124	14	deviate	deviate	NOUN
iajs-3629	124	15	from	from	ADP
iajs-3629	124	16	experimentally	experimentally	ADV
iajs-3629	124	17	determined	determine	VERB
iajs-3629	124	18	values	value	NOUN
iajs-3629	124	19	(	(	PUNCT
iajs-3629	124	20	24	24	NUM
iajs-3629	124	21	)	)	PUNCT
iajs-3629	124	22	.	.	PUNCT
iajs-3629	125	1	these	these	DET
iajs-3629	125	2	deviations	deviation	NOUN
iajs-3629	125	3	are	be	AUX
iajs-3629	125	4	generally	generally	ADV
iajs-3629	125	5	accepted	accept	VERB
iajs-3629	125	6	in	in	ADP
iajs-3629	125	7	theoretical	theoretical	ADJ
iajs-3629	125	8	calculations	calculation	NOUN
iajs-3629	125	9	and	and	CCONJ
iajs-3629	125	10	are	be	AUX
iajs-3629	125	11	outlined	outline	VERB
iajs-3629	125	12	in	in	ADP
iajs-3629	125	13	table	table	NOUN
iajs-3629	125	14	7	7	NUM
iajs-3629	125	15	.	.	PUNCT
iajs-3629	125	16	figures	figure	NOUN
iajs-3629	125	17	7	7	NUM
iajs-3629	125	18	-	-	SYM
iajs-3629	125	19	10	10	NUM
iajs-3629	125	20	show	show	VERB
iajs-3629	125	21	some	some	DET
iajs-3629	125	22	theoretical	theoretical	ADJ
iajs-3629	125	23	vibrational	vibrational	ADJ
iajs-3629	125	24	modes	mode	NOUN
iajs-3629	125	25	of	of	ADP
iajs-3629	125	26	l	l	NOUN
iajs-3629	125	27	and	and	CCONJ
iajs-3629	125	28	proline	proline	NOUN
iajs-3629	125	29	(	(	PUNCT
iajs-3629	125	30	19,20	19,20	NOUN
iajs-3629	125	31	)	)	PUNCT
iajs-3629	125	32	.	.	PUNCT
iajs-3629	126	1	the	the	DET
iajs-3629	126	2	suggested	suggest	VERB
iajs-3629	126	3	structure	structure	NOUN
iajs-3629	126	4	of	of	ADP
iajs-3629	126	5	the	the	DET
iajs-3629	126	6	prepared	prepared	ADJ
iajs-3629	126	7	complexes	complex	NOUN
iajs-3629	126	8	illustrated	illustrate	VERB
iajs-3629	126	9	in	in	ADP
iajs-3629	126	10	figure	figure	NOUN
iajs-3629	126	11	11	11	NUM
iajs-3629	126	12	.	.	PUNCT
iajs-3629	127	1	flx	flx	NOUN
iajs-3629	127	2	proline	proline	NOUN
iajs-3629	127	3	figure	figure	NOUN
iajs-3629	127	4	7	7	NUM
iajs-3629	127	5	.	.	PUNCT
iajs-3629	128	1	the	the	DET
iajs-3629	128	2	e.p	e.p	PROPN
iajs-3629	128	3	of	of	ADP
iajs-3629	128	4	the	the	DET
iajs-3629	128	5	(	(	PUNCT
iajs-3629	128	6	flx	flx	NOUN
iajs-3629	128	7	)	)	PUNCT
iajs-3629	128	8	and	and	CCONJ
iajs-3629	128	9	(	(	PUNCT
iajs-3629	128	10	proline	proline	NOUN
iajs-3629	128	11	)	)	PUNCT
iajs-3629	128	12	using	use	VERB
iajs-3629	128	13	pm3	pm3	PROPN
iajs-3629	128	14	methods	method	NOUN
iajs-3629	128	15	.	.	PUNCT
iajs-3629	129	1	ihjpas	ihjpas	PROPN
iajs-3629	129	2	.	.	PUNCT
iajs-3629	130	1	2025,38(2	2025,38(2	PROPN
iajs-3629	130	2	)	)	PUNCT
iajs-3629	130	3	258	258	NUM
iajs-3629	130	4	flx	flx	NOUN
iajs-3629	130	5	proline	proline	NOUN
iajs-3629	130	6	l	l	NOUN
iajs-3629	130	7	(	(	PUNCT
iajs-3629	130	8	pro)cd	pro)cd	NOUN
iajs-3629	130	9	l	l	NOUN
iajs-3629	130	10	(	(	PUNCT
iajs-3629	130	11	pro	pro	X
iajs-3629	130	12	)	)	PUNCT
iajs-3629	130	13	co	co	NOUN
iajs-3629	130	14	ihjpas	ihjpas	PROPN
iajs-3629	130	15	.	.	PUNCT
iajs-3629	131	1	2025,38(2	2025,38(2	NOUN
iajs-3629	131	2	)	)	PUNCT
iajs-3629	131	3	259	259	NUM
iajs-3629	131	4	l	l	NOUN
iajs-3629	131	5	(	(	PUNCT
iajs-3629	131	6	pro	pro	ADJ
iajs-3629	131	7	)	)	PUNCT
iajs-3629	131	8	cu	cu	NOUN
iajs-3629	131	9	l	l	NOUN
iajs-3629	131	10	(	(	PUNCT
iajs-3629	131	11	pro	pro	ADJ
iajs-3629	131	12	)	)	PUNCT
iajs-3629	131	13	ni	ni	ADJ
iajs-3629	131	14	l	l	NOUN
iajs-3629	131	15	(	(	PUNCT
iajs-3629	131	16	pro	pro	ADJ
iajs-3629	131	17	)	)	PUNCT
iajs-3629	131	18	zn	zn	NOUN
iajs-3629	131	19	figure	figure	VERB
iajs-3629	131	20	8	8	NUM
iajs-3629	131	21	.	.	PUNCT
iajs-3629	132	1	geometric	geometric	ADJ
iajs-3629	132	2	shapes	shape	NOUN
iajs-3629	132	3	of	of	ADP
iajs-3629	132	4	(	(	PUNCT
iajs-3629	132	5	l(pro	l(pro	ADJ
iajs-3629	132	6	)	)	PUNCT
iajs-3629	132	7	)	)	PUNCT
iajs-3629	132	8	and	and	CCONJ
iajs-3629	132	9	its	its	PRON
iajs-3629	132	10	complexes	complex	NOUN
iajs-3629	132	11	using	use	VERB
iajs-3629	132	12	pm3	pm3	PROPN
iajs-3629	132	13	method	method	NOUN
iajs-3629	132	14	.	.	PUNCT
iajs-3629	133	1	ihjpas	ihjpas	PROPN
iajs-3629	133	2	.	.	PUNCT
iajs-3629	134	1	2025,38(2	2025,38(2	PROPN
iajs-3629	134	2	)	)	PUNCT
iajs-3629	134	3	260	260	NUM
iajs-3629	134	4	table	table	NOUN
iajs-3629	134	5	7	7	NUM
iajs-3629	134	6	.	.	PUNCT
iajs-3629	135	1	data	datum	NOUN
iajs-3629	135	2	of	of	ADP
iajs-3629	135	3	theoretical	theoretical	ADJ
iajs-3629	135	4	wave	wave	NOUN
iajs-3629	135	5	number	number	NOUN
iajs-3629	135	6	of	of	ADP
iajs-3629	135	7	(	(	PUNCT
iajs-3629	135	8	l	l	NOUN
iajs-3629	135	9	,	,	PUNCT
iajs-3629	135	10	proline	proline	NOUN
iajs-3629	135	11	)	)	PUNCT
iajs-3629	135	12	compounds	compound	NOUN
iajs-3629	135	13	(	(	PUNCT
iajs-3629	135	14	cm-1	cm-1	NOUN
iajs-3629	135	15	)	)	PUNCT
iajs-3629	135	16	and	and	CCONJ
iajs-3629	135	17	their	their	PRON
iajs-3629	135	18	comparison	comparison	NOUN
iajs-3629	135	19	with	with	ADP
iajs-3629	135	20	experimental	experimental	ADJ
iajs-3629	135	21	vibrations	vibration	NOUN
iajs-3629	135	22	.	.	PUNCT
iajs-3629	136	1	compound	compound	PROPN
iajs-3629	136	2	ʋ	ʋ	X
iajs-3629	136	3	nh	nh	PROPN
iajs-3629	136	4	ʋc	ʋc	PROPN
iajs-3629	136	5	=	=	PROPN
iajs-3629	136	6	o	o	NOUN
iajs-3629	136	7	ʋcoo	ʋcoo	NOUN
iajs-3629	136	8	ʋc	ʋc	PROPN
iajs-3629	136	9	-	-	PUNCT
iajs-3629	136	10	n	n	PRON
iajs-3629	136	11	l	l	NOUN
iajs-3629	136	12	3380	3380	NUM
iajs-3629	136	13	*	*	PUNCT
iajs-3629	136	14	3339	3339	NUM
iajs-3629	136	15	*	*	SYM
iajs-3629	136	16	*	*	PUNCT
iajs-3629	136	17	0.012	0.012	NUM
iajs-3629	136	18	*	*	PUNCT
iajs-3629	136	19	*	*	PUNCT
iajs-3629	136	20	*	*	X
iajs-3629	136	21	1743	1743	NUM
iajs-3629	136	22	*	*	SYM
iajs-3629	136	23	1952	1952	NUM
iajs-3629	136	24	*	*	PUNCT
iajs-3629	136	25	*	*	PUNCT
iajs-3629	137	1	-0.107	-0.107	PUNCT
iajs-3629	137	2	*	*	PUNCT
iajs-3629	137	3	*	*	PUNCT
iajs-3629	137	4	*	*	PUNCT
iajs-3629	137	5	1335	1335	NUM
iajs-3629	137	6	*	*	SYM
iajs-3629	137	7	1442	1442	NUM
iajs-3629	137	8	*	*	PUNCT
iajs-3629	137	9	*	*	PUNCT
iajs-3629	138	1	0.074	0.074	NUM
iajs-3629	138	2	*	*	PUNCT
iajs-3629	138	3	*	*	PUNCT
iajs-3629	138	4	*	*	NOUN
iajs-3629	138	5	proline	proline	NOUN
iajs-3629	138	6	3083	3083	NUM
iajs-3629	138	7	*	*	SYM
iajs-3629	138	8	3393	3393	NUM
iajs-3629	138	9	1573	1573	NUM
iajs-3629	138	10	*	*	SYM
iajs-3629	138	11	1441	1441	NUM
iajs-3629	138	12	*	*	SYM
iajs-3629	138	13	*	*	PUNCT
iajs-3629	138	14	-0.09	-0.09	PRON
iajs-3629	138	15	*	*	PUNCT
iajs-3629	138	16	*	*	PROPN
iajs-3629	138	17	*	*	NOUN
iajs-3629	138	18	1342	1342	NUM
iajs-3629	138	19	*	*	SYM
iajs-3629	138	20	1326	1326	NUM
iajs-3629	138	21	*	*	SYM
iajs-3629	138	22	*	*	PUNCT
iajs-3629	138	23	-0.012	-0.012	PUNCT
iajs-3629	138	24	*	*	PUNCT
iajs-3629	138	25	*	*	PUNCT
iajs-3629	138	26	*	*	PUNCT
iajs-3629	138	27	*	*	PUNCT
iajs-3629	138	28	experimental	experimental	ADJ
iajs-3629	138	29	,	,	PUNCT
iajs-3629	138	30	*	*	PUNCT
iajs-3629	138	31	*	*	NOUN
iajs-3629	138	32	theoretical	theoretical	ADJ
iajs-3629	138	33	,	,	PUNCT
iajs-3629	138	34	*	*	PUNCT
iajs-3629	138	35	*	*	PUNCT
iajs-3629	138	36	*	*	NOUN
iajs-3629	138	37	error	error	NOUN
iajs-3629	138	38	.	.	PUNCT
iajs-3629	139	1	ʋ	ʋ	PROPN
iajs-3629	139	2	nh	nh	PROPN
iajs-3629	139	3	ʋcn	ʋcn	PROPN
iajs-3629	139	4	ʋc	ʋc	PROPN
iajs-3629	139	5	=	=	NOUN
iajs-3629	139	6	o	o	NOUN
iajs-3629	139	7	ʋc	ʋc	NOUN
iajs-3629	139	8	=	=	ADJ
iajs-3629	139	9	o	o	NOUN
iajs-3629	139	10	figure	figure	NOUN
iajs-3629	139	11	9	9	NUM
iajs-3629	139	12	.	.	PUNCT
iajs-3629	140	1	some	some	DET
iajs-3629	140	2	theoretical	theoretical	ADJ
iajs-3629	140	3	vibrational	vibrational	ADJ
iajs-3629	140	4	modes	mode	NOUN
iajs-3629	140	5	of	of	ADP
iajs-3629	140	6	l.	l.	PROPN
iajs-3629	140	7	ihjpas	ihjpas	PROPN
iajs-3629	140	8	.	.	PUNCT
iajs-3629	141	1	2025,38(2	2025,38(2	PROPN
iajs-3629	141	2	)	)	PUNCT
iajs-3629	142	1	261	261	NUM
iajs-3629	142	2	ʋ	ʋ	X
iajs-3629	142	3	nh	nh	X
iajs-3629	142	4	ʋcoo	ʋcoo	PROPN
iajs-3629	142	5	ʋcn	ʋcn	PROPN
iajs-3629	142	6	figure	figure	NOUN
iajs-3629	142	7	11	11	NUM
iajs-3629	142	8	.	.	PUNCT
iajs-3629	143	1	the	the	DET
iajs-3629	143	2	suggested	suggest	VERB
iajs-3629	143	3	structure	structure	NOUN
iajs-3629	143	4	of	of	ADP
iajs-3629	143	5	the	the	DET
iajs-3629	143	6	prepared	prepared	ADJ
iajs-3629	143	7	complexes	complex	NOUN
iajs-3629	143	8	.	.	PUNCT
iajs-3629	144	1	3.8	3.8	NUM
iajs-3629	144	2	.	.	PUNCT
iajs-3629	144	3	evaluation	evaluation	NOUN
iajs-3629	144	4	of	of	ADP
iajs-3629	144	5	antibacterial	antibacterial	ADJ
iajs-3629	144	6	activity	activity	NOUN
iajs-3629	144	7	mix	mix	NOUN
iajs-3629	144	8	ligand	ligand	NOUN
iajs-3629	144	9	and	and	CCONJ
iajs-3629	144	10	metal	metal	NOUN
iajs-3629	144	11	complexes	complex	NOUN
iajs-3629	144	12	were	be	AUX
iajs-3629	144	13	examined	examine	VERB
iajs-3629	144	14	for	for	ADP
iajs-3629	144	15	their	their	PRON
iajs-3629	144	16	in	in	X
iajs-3629	144	17	vitro	vitro	X
iajs-3629	144	18	biological	biological	ADJ
iajs-3629	144	19	screening	screening	NOUN
iajs-3629	144	20	effects	effect	NOUN
iajs-3629	144	21	against	against	ADP
iajs-3629	144	22	microorganisms	microorganism	NOUN
iajs-3629	144	23	.	.	PUNCT
iajs-3629	145	1	this	this	PRON
iajs-3629	145	2	was	be	AUX
iajs-3629	145	3	accomplished	accomplish	VERB
iajs-3629	145	4	using	use	VERB
iajs-3629	145	5	the	the	DET
iajs-3629	145	6	disc	disc	NOUN
iajs-3629	145	7	diffusion	diffusion	NOUN
iajs-3629	145	8	method	method	NOUN
iajs-3629	145	9	with	with	ADP
iajs-3629	145	10	nutrient	nutrient	NOUN
iajs-3629	145	11	agar	agar	NOUN
iajs-3629	145	12	as	as	ADP
iajs-3629	145	13	the	the	DET
iajs-3629	145	14	medium	medium	NOUN
iajs-3629	145	15	(	(	PUNCT
iajs-3629	145	16	25,26	25,26	NOUN
iajs-3629	145	17	)	)	PUNCT
iajs-3629	145	18	.	.	PUNCT
iajs-3629	146	1	the	the	DET
iajs-3629	146	2	test	test	NOUN
iajs-3629	146	3	solution	solution	NOUN
iajs-3629	146	4	was	be	AUX
iajs-3629	146	5	introduced	introduce	VERB
iajs-3629	146	6	into	into	ADP
iajs-3629	146	7	the	the	DET
iajs-3629	146	8	well	well	NOUN
iajs-3629	146	9	using	use	VERB
iajs-3629	146	10	a	a	DET
iajs-3629	146	11	micropipette	micropipette	NOUN
iajs-3629	146	12	,	,	PUNCT
iajs-3629	146	13	and	and	CCONJ
iajs-3629	146	14	subsequently	subsequently	ADV
iajs-3629	146	15	,	,	PUNCT
iajs-3629	146	16	24	24	NUM
iajs-3629	146	17	hours	hour	NOUN
iajs-3629	146	18	were	be	AUX
iajs-3629	146	19	spent	spend	VERB
iajs-3629	146	20	incubating	incubate	VERB
iajs-3629	146	21	the	the	DET
iajs-3629	146	22	dishes	dish	NOUN
iajs-3629	146	23	at	at	ADP
iajs-3629	146	24	37	37	NUM
iajs-3629	146	25	°	°	NOUN
iajs-3629	146	26	c	c	NOUN
iajs-3629	146	27	.	.	PUNCT
iajs-3629	147	1	using	use	VERB
iajs-3629	147	2	a	a	DET
iajs-3629	147	3	ruler	ruler	NOUN
iajs-3629	147	4	in	in	ADP
iajs-3629	147	5	millimeters	millimeters	PROPN
iajs-3629	147	6	(	(	PUNCT
iajs-3629	147	7	mm	mm	PROPN
iajs-3629	147	8	)	)	PUNCT
iajs-3629	147	9	,	,	PUNCT
iajs-3629	147	10	the	the	DET
iajs-3629	147	11	inhibition	inhibition	NOUN
iajs-3629	147	12	zone	zone	NOUN
iajs-3629	147	13	of	of	ADP
iajs-3629	147	14	each	each	DET
iajs-3629	147	15	pore	pore	NOUN
iajs-3629	147	16	was	be	AUX
iajs-3629	147	17	measured	measure	VERB
iajs-3629	147	18	.	.	PUNCT
iajs-3629	148	1	to	to	PART
iajs-3629	148	2	record	record	VERB
iajs-3629	148	3	the	the	DET
iajs-3629	148	4	results	result	NOUN
iajs-3629	148	5	,	,	PUNCT
iajs-3629	148	6	the	the	DET
iajs-3629	148	7	growth	growth	NOUN
iajs-3629	148	8	inhibition	inhibition	NOUN
iajs-3629	148	9	surrounding	surround	VERB
iajs-3629	148	10	the	the	DET
iajs-3629	148	11	disc	disc	NOUN
iajs-3629	148	12	was	be	AUX
iajs-3629	148	13	estimated	estimate	VERB
iajs-3629	148	14	.	.	PUNCT
iajs-3629	149	1	chelation	chelation	NOUN
iajs-3629	149	2	theory	theory	NOUN
iajs-3629	149	3	and	and	CCONJ
iajs-3629	149	4	the	the	DET
iajs-3629	149	5	concept	concept	NOUN
iajs-3629	149	6	of	of	ADP
iajs-3629	149	7	overtones	overtone	NOUN
iajs-3629	149	8	can	can	AUX
iajs-3629	149	9	explain	explain	VERB
iajs-3629	149	10	why	why	SCONJ
iajs-3629	149	11	the	the	DET
iajs-3629	149	12	inhibition	inhibition	NOUN
iajs-3629	149	13	zone	zone	NOUN
iajs-3629	149	14	of	of	ADP
iajs-3629	149	15	metal	metal	NOUN
iajs-3629	149	16	complexes	complex	NOUN
iajs-3629	149	17	is	be	AUX
iajs-3629	149	18	more	more	ADV
iajs-3629	149	19	significant	significant	ADJ
iajs-3629	149	20	than	than	ADP
iajs-3629	149	21	that	that	PRON
iajs-3629	149	22	of	of	ADP
iajs-3629	149	23	ligands	ligand	NOUN
iajs-3629	149	24	.	.	PUNCT
iajs-3629	150	1	the	the	DET
iajs-3629	150	2	chelation	chelation	NOUN
iajs-3629	150	3	process	process	NOUN
iajs-3629	150	4	reduces	reduce	VERB
iajs-3629	150	5	the	the	DET
iajs-3629	150	6	polarity	polarity	NOUN
iajs-3629	150	7	of	of	ADP
iajs-3629	150	8	the	the	DET
iajs-3629	150	9	metal	metal	NOUN
iajs-3629	150	10	ion	ion	NOUN
iajs-3629	150	11	due	due	ADP
iajs-3629	150	12	to	to	ADP
iajs-3629	150	13	the	the	DET
iajs-3629	150	14	overlapping	overlapping	NOUN
iajs-3629	150	15	of	of	ADP
iajs-3629	150	16	the	the	DET
iajs-3629	150	17	ligand	ligand	ADJ
iajs-3629	150	18	orbital	orbital	NOUN
iajs-3629	150	19	and	and	CCONJ
iajs-3629	150	20	the	the	DET
iajs-3629	150	21	partial	partial	ADJ
iajs-3629	150	22	sharing	sharing	NOUN
iajs-3629	150	23	of	of	ADP
iajs-3629	150	24	the	the	DET
iajs-3629	150	25	positive	positive	ADJ
iajs-3629	150	26	charge	charge	NOUN
iajs-3629	150	27	of	of	ADP
iajs-3629	150	28	the	the	DET
iajs-3629	150	29	metal	metal	NOUN
iajs-3629	150	30	by	by	ADP
iajs-3629	150	31	the	the	DET
iajs-3629	150	32	donor	donor	NOUN
iajs-3629	150	33	groups	group	NOUN
iajs-3629	150	34	.	.	PUNCT
iajs-3629	151	1	furthermore	furthermore	ADV
iajs-3629	151	2	,	,	PUNCT
iajs-3629	151	3	it	it	PRON
iajs-3629	151	4	facilitates	facilitate	VERB
iajs-3629	151	5	the	the	DET
iajs-3629	151	6	dispersion	dispersion	NOUN
iajs-3629	151	7	of	of	ADP
iajs-3629	151	8	π	π	NOUN
iajs-3629	151	9	-	-	NOUN
iajs-3629	151	10	electrons	electron	NOUN
iajs-3629	151	11	throughout	throughout	ADP
iajs-3629	151	12	the	the	DET
iajs-3629	151	13	entirety	entirety	NOUN
iajs-3629	151	14	of	of	ADP
iajs-3629	151	15	the	the	DET
iajs-3629	151	16	chelating	chelating	NOUN
iajs-3629	151	17	ring	ring	NOUN
iajs-3629	151	18	and	and	CCONJ
iajs-3629	151	19	promotes	promote	VERB
iajs-3629	151	20	the	the	DET
iajs-3629	151	21	infiltration	infiltration	NOUN
iajs-3629	151	22	of	of	ADP
iajs-3629	151	23	complexes	complex	NOUN
iajs-3629	151	24	into	into	ADP
iajs-3629	151	25	lipid	lipid	ADJ
iajs-3629	151	26	membranes	membrane	NOUN
iajs-3629	151	27	.	.	PUNCT
iajs-3629	152	1	additionally	additionally	ADV
iajs-3629	152	2	,	,	PUNCT
iajs-3629	152	3	it	it	PRON
iajs-3629	152	4	obstructs	obstruct	VERB
iajs-3629	152	5	the	the	DET
iajs-3629	152	6	metal	metal	NOUN
iajs-3629	152	7	-	-	PUNCT
iajs-3629	152	8	binding	bind	VERB
iajs-3629	152	9	sites	site	NOUN
iajs-3629	152	10	of	of	ADP
iajs-3629	152	11	microorganism	microorganism	NOUN
iajs-3629	152	12	enzymes	enzyme	NOUN
iajs-3629	152	13	.	.	PUNCT
iajs-3629	153	1	the	the	DET
iajs-3629	153	2	results	result	NOUN
iajs-3629	153	3	obtained	obtain	VERB
iajs-3629	153	4	for	for	ADP
iajs-3629	153	5	biological	biological	ADJ
iajs-3629	153	6	activity	activity	NOUN
iajs-3629	153	7	for	for	ADP
iajs-3629	153	8	the	the	DET
iajs-3629	153	9	preparation	preparation	NOUN
iajs-3629	153	10	ligand	ligand	NOUN
iajs-3629	153	11	and	and	CCONJ
iajs-3629	153	12	its	its	PRON
iajs-3629	153	13	metal	metal	NOUN
iajs-3629	153	14	complexes	complex	NOUN
iajs-3629	153	15	are	be	AUX
iajs-3629	153	16	shown	show	VERB
iajs-3629	153	17	in	in	ADP
iajs-3629	153	18	table	table	NOUN
iajs-3629	153	19	8	8	NUM
iajs-3629	153	20	.	.	PUNCT
iajs-3629	154	1	the	the	DET
iajs-3629	154	2	free	free	ADJ
iajs-3629	154	3	figure	figure	NOUN
iajs-3629	154	4	10	10	NUM
iajs-3629	154	5	.	.	PUNCT
iajs-3629	155	1	some	some	DET
iajs-3629	155	2	theoretical	theoretical	ADJ
iajs-3629	155	3	vibrational	vibrational	ADJ
iajs-3629	155	4	modes	mode	NOUN
iajs-3629	155	5	of	of	ADP
iajs-3629	155	6	proline	proline	NOUN
iajs-3629	155	7	.	.	PUNCT
iajs-3629	156	1	ihjpas	ihjpas	PROPN
iajs-3629	156	2	.	.	PUNCT
iajs-3629	157	1	2025,38(2	2025,38(2	PROPN
iajs-3629	157	2	)	)	PUNCT
iajs-3629	157	3	262	262	NUM
iajs-3629	157	4	ligand	ligand	NOUN
iajs-3629	157	5	showed	show	VERB
iajs-3629	157	6	a	a	DET
iajs-3629	157	7	slightly	slightly	ADV
iajs-3629	157	8	antimicrobial	antimicrobial	ADJ
iajs-3629	157	9	and	and	CCONJ
iajs-3629	157	10	antifungal	antifungal	ADJ
iajs-3629	157	11	activity	activity	NOUN
iajs-3629	157	12	against	against	ADP
iajs-3629	157	13	both	both	DET
iajs-3629	157	14	bacteria	bacteria	NOUN
iajs-3629	157	15	.	.	PUNCT
iajs-3629	158	1	the	the	DET
iajs-3629	158	2	nickel	nickel	NOUN
iajs-3629	158	3	(	(	PUNCT
iajs-3629	158	4	ii	ii	NOUN
iajs-3629	158	5	)	)	PUNCT
iajs-3629	158	6	complex	complex	NOUN
iajs-3629	158	7	shows	show	VERB
iajs-3629	158	8	higher	high	ADJ
iajs-3629	158	9	inhibition	inhibition	NOUN
iajs-3629	158	10	against	against	ADP
iajs-3629	158	11	both	both	DET
iajs-3629	158	12	organisms	organism	NOUN
iajs-3629	158	13	and	and	CCONJ
iajs-3629	158	14	antifungal	antifungal	ADJ
iajs-3629	158	15	effect	effect	NOUN
iajs-3629	158	16	than	than	ADP
iajs-3629	158	17	free	free	ADJ
iajs-3629	158	18	ligands	ligand	NOUN
iajs-3629	158	19	in	in	ADP
iajs-3629	158	20	both	both	DET
iajs-3629	158	21	concentrations	concentration	NOUN
iajs-3629	158	22	.	.	PUNCT
iajs-3629	159	1	the	the	DET
iajs-3629	159	2	copper	copper	NOUN
iajs-3629	159	3	(	(	PUNCT
iajs-3629	159	4	ii	ii	NOUN
iajs-3629	159	5	)	)	PUNCT
iajs-3629	159	6	and	and	CCONJ
iajs-3629	159	7	cobalt	cobalt	NOUN
iajs-3629	159	8	(	(	PUNCT
iajs-3629	159	9	ii	ii	NOUN
iajs-3629	159	10	)	)	PUNCT
iajs-3629	159	11	complexes	complex	NOUN
iajs-3629	159	12	showed	show	VERB
iajs-3629	159	13	moderate	moderate	ADJ
iajs-3629	159	14	and	and	CCONJ
iajs-3629	159	15	non	non	ADJ
iajs-3629	159	16	-	-	ADJ
iajs-3629	159	17	activity	activity	NOUN
iajs-3629	159	18	,	,	PUNCT
iajs-3629	159	19	respectively	respectively	ADV
iajs-3629	159	20	,	,	PUNCT
iajs-3629	159	21	against	against	ADP
iajs-3629	159	22	all	all	DET
iajs-3629	159	23	organisms	organism	NOUN
iajs-3629	159	24	used	use	VERB
iajs-3629	159	25	in	in	ADP
iajs-3629	159	26	this	this	DET
iajs-3629	159	27	study	study	NOUN
iajs-3629	159	28	,	,	PUNCT
iajs-3629	159	29	which	which	PRON
iajs-3629	159	30	is	be	AUX
iajs-3629	159	31	clarified	clarify	VERB
iajs-3629	159	32	in	in	ADP
iajs-3629	159	33	figure	figure	NOUN
iajs-3629	159	34	12	12	NUM
iajs-3629	159	35	.	.	PUNCT
iajs-3629	160	1	the	the	DET
iajs-3629	160	2	higher	high	ADJ
iajs-3629	160	3	inhibition	inhibition	NOUN
iajs-3629	160	4	zone	zone	NOUN
iajs-3629	160	5	of	of	ADP
iajs-3629	160	6	the	the	DET
iajs-3629	160	7	metal	metal	NOUN
iajs-3629	160	8	complexes	complex	NOUN
iajs-3629	160	9	than	than	SCONJ
iajs-3629	160	10	the	the	DET
iajs-3629	160	11	ligand	ligand	NOUN
iajs-3629	160	12	can	can	AUX
iajs-3629	160	13	be	be	AUX
iajs-3629	160	14	explained	explain	VERB
iajs-3629	160	15	based	base	VERB
iajs-3629	160	16	on	on	ADP
iajs-3629	160	17	chelation	chelation	NOUN
iajs-3629	160	18	theory	theory	NOUN
iajs-3629	160	19	and	and	CCONJ
iajs-3629	160	20	overtone	overtone	ADJ
iajs-3629	160	21	concept	concept	NOUN
iajs-3629	160	22	(	(	PUNCT
iajs-3629	160	23	27	27	NUM
iajs-3629	160	24	-	-	SYM
iajs-3629	160	25	30	30	NUM
iajs-3629	160	26	)	)	PUNCT
iajs-3629	160	27	.	.	PUNCT
iajs-3629	161	1	table	table	NOUN
iajs-3629	161	2	8	8	NUM
iajs-3629	161	3	.	.	PUNCT
iajs-3629	162	1	the	the	DET
iajs-3629	162	2	diameter	diameter	NOUN
iajs-3629	162	3	of	of	ADP
iajs-3629	162	4	the	the	DET
iajs-3629	162	5	inhibition	inhibition	NOUN
iajs-3629	162	6	circle	circle	NOUN
iajs-3629	162	7	in	in	ADP
iajs-3629	162	8	(	(	PUNCT
iajs-3629	162	9	mm	mm	INTJ
iajs-3629	162	10	)	)	PUNCT
iajs-3629	162	11	after	after	ADP
iajs-3629	162	12	being	be	AUX
iajs-3629	162	13	injected	inject	VERB
iajs-3629	162	14	(	(	PUNCT
iajs-3629	162	15	24	24	NUM
iajs-3629	162	16	hrs	hrs	NOUN
iajs-3629	162	17	.	.	PUNCT
iajs-3629	162	18	)	)	PUNCT
iajs-3629	163	1	at	at	ADP
iajs-3629	163	2	37	37	NUM
iajs-3629	163	3	0c	0c	NOUN
iajs-3629	163	4	for	for	ADP
iajs-3629	163	5	some	some	DET
iajs-3629	163	6	mixed	mixed	ADJ
iajs-3629	163	7	ligand	ligand	NOUN
iajs-3629	163	8	complexes	complex	NOUN
iajs-3629	163	9	prepared	prepare	VERB
iajs-3629	163	10	from	from	ADP
iajs-3629	163	11	ligand	ligand	NOUN
iajs-3629	163	12	(	(	PUNCT
iajs-3629	163	13	l2	l2	NOUN
iajs-3629	163	14	)	)	PUNCT
iajs-3629	163	15	and	and	CCONJ
iajs-3629	163	16	proline	proline	NOUN
iajs-3629	163	17	.	.	PUNCT
iajs-3629	164	1	figure	figure	NOUN
iajs-3629	164	2	12	12	NUM
iajs-3629	164	3	.	.	PUNCT
iajs-3629	165	1	the	the	DET
iajs-3629	165	2	antibacterial	antibacterial	ADJ
iajs-3629	165	3	activity	activity	NOUN
iajs-3629	165	4	of	of	ADP
iajs-3629	165	5	prepared	prepare	VERB
iajs-3629	165	6	compounds	compound	NOUN
iajs-3629	165	7	against	against	ADP
iajs-3629	165	8	staphylococcus	staphylococcus	NOUN
iajs-3629	165	9	aureus	aureus	NOUN
iajs-3629	165	10	,	,	PUNCT
iajs-3629	165	11	escherichia	escherichia	NOUN
iajs-3629	165	12	coli	coli	NOUN
iajs-3629	165	13	,	,	PUNCT
iajs-3629	165	14	and	and	CCONJ
iajs-3629	165	15	candida	candida	NOUN
iajs-3629	165	16	albicans	albican	NOUN
iajs-3629	165	17	.	.	PUNCT
iajs-3629	166	1	in	in	ADP
iajs-3629	166	2	5	5	NUM
iajs-3629	166	3	mm	mm	NOUN
iajs-3629	166	4	.	.	PROPN
iajs-3629	166	5	4	4	NUM
iajs-3629	166	6	.	.	X
iajs-3629	166	7	conclusion	conclusion	NOUN
iajs-3629	166	8	a	a	DET
iajs-3629	166	9	new	new	ADJ
iajs-3629	166	10	mixed	mixed	ADJ
iajs-3629	166	11	ligand	ligand	NOUN
iajs-3629	166	12	was	be	AUX
iajs-3629	166	13	prepared	prepare	VERB
iajs-3629	166	14	from	from	ADP
iajs-3629	166	15	a	a	DET
iajs-3629	166	16	derivative	derivative	NOUN
iajs-3629	166	17	of	of	ADP
iajs-3629	166	18	floclxaciline	floclxaciline	NOUN
iajs-3629	166	19	and	and	CCONJ
iajs-3629	166	20	the	the	DET
iajs-3629	166	21	amino	amino	NOUN
iajs-3629	166	22	acid	acid	NOUN
iajs-3629	166	23	(	(	PUNCT
iajs-3629	166	24	proline	proline	NOUN
iajs-3629	166	25	)	)	PUNCT
iajs-3629	166	26	.	.	PUNCT
iajs-3629	167	1	the	the	DET
iajs-3629	167	2	form	form	NOUN
iajs-3629	167	3	and	and	CCONJ
iajs-3629	167	4	type	type	NOUN
iajs-3629	167	5	of	of	ADP
iajs-3629	167	6	bonding	bonding	NOUN
iajs-3629	167	7	between	between	ADP
iajs-3629	167	8	the	the	DET
iajs-3629	167	9	ligand	ligand	NOUN
iajs-3629	167	10	and	and	CCONJ
iajs-3629	167	11	the	the	DET
iajs-3629	167	12	prepared	prepared	ADJ
iajs-3629	167	13	complexes	complex	NOUN
iajs-3629	167	14	were	be	AUX
iajs-3629	167	15	revealed	reveal	VERB
iajs-3629	167	16	using	use	VERB
iajs-3629	167	17	spectroscopic	spectroscopic	ADJ
iajs-3629	167	18	methods	method	NOUN
iajs-3629	167	19	and	and	CCONJ
iajs-3629	167	20	nuclear	nuclear	ADJ
iajs-3629	167	21	magnetic	magnetic	ADJ
iajs-3629	167	22	resonance	resonance	NOUN
iajs-3629	167	23	.	.	PUNCT
iajs-3629	168	1	the	the	DET
iajs-3629	168	2	shapes	shape	NOUN
iajs-3629	168	3	of	of	ADP
iajs-3629	168	4	the	the	DET
iajs-3629	168	5	candida	candida	PROPN
iajs-3629	168	6	albicans	albican	NOUN
iajs-3629	168	7	staphylococcus	staphylococcus	NOUN
iajs-3629	168	8	aureus	aureus	PROPN
iajs-3629	168	9	escherichia	escherichia	NOUN
iajs-3629	168	10	coli	coli	NOUN
iajs-3629	168	11	compound	compound	NOUN
iajs-3629	168	12	19	19	NUM
iajs-3629	168	13	28	28	NUM
iajs-3629	168	14	10	10	NUM
iajs-3629	168	15	pro	pro	ADJ
iajs-3629	168	16	14	14	NUM
iajs-3629	168	17	27	27	NUM
iajs-3629	168	18	10	10	NUM
iajs-3629	168	19	l	l	NOUN
iajs-3629	168	20	8	8	NUM
iajs-3629	168	21	34	34	NUM
iajs-3629	168	22	31	31	NUM
iajs-3629	169	1	l	l	NOUN
iajs-3629	170	1	(	(	PUNCT
iajs-3629	170	2	pro)ni	pro)ni	NOUN
iajs-3629	170	3	16	16	NUM
iajs-3629	170	4	25	25	NUM
iajs-3629	170	5	17	17	NUM
iajs-3629	170	6	l	l	NOUN
iajs-3629	170	7	(	(	PUNCT
iajs-3629	170	8	pro)cu	pro)cu	NOUN
iajs-3629	170	9	9	9	NUM
iajs-3629	170	10	9	9	NUM
iajs-3629	170	11	15	15	NUM
iajs-3629	170	12	l	l	NOUN
iajs-3629	170	13	(	(	PUNCT
iajs-3629	170	14	pro)zn	pro)zn	NOUN
iajs-3629	170	15	10	10	NUM
iajs-3629	170	16	8	8	NUM
iajs-3629	170	17	14	14	NUM
iajs-3629	170	18	l	l	NOUN
iajs-3629	170	19	(	(	PUNCT
iajs-3629	170	20	pro)co	pro)co	NOUN
iajs-3629	170	21	27	27	NUM
iajs-3629	170	22	14	14	NUM
iajs-3629	170	23	13	13	NUM
iajs-3629	170	24	l	l	NOUN
iajs-3629	170	25	(	(	PUNCT
iajs-3629	170	26	pro)cd	pro)cd	NOUN
iajs-3629	170	27	ihjpas	ihjpas	PROPN
iajs-3629	170	28	.	.	PUNCT
iajs-3629	171	1	2025,38(2	2025,38(2	PROPN
iajs-3629	171	2	)	)	PUNCT
iajs-3629	171	3	263	263	NUM
iajs-3629	171	4	formed	form	VERB
iajs-3629	171	5	complexes	complex	NOUN
iajs-3629	171	6	were	be	AUX
iajs-3629	171	7	suggested	suggest	VERB
iajs-3629	171	8	to	to	PART
iajs-3629	171	9	be	be	AUX
iajs-3629	171	10	octahedral	octahedral	ADJ
iajs-3629	171	11	.	.	PUNCT
iajs-3629	172	1	the	the	DET
iajs-3629	172	2	hyperchem-8.07	hyperchem-8.07	PROPN
iajs-3629	172	3	software	software	NOUN
iajs-3629	172	4	was	be	AUX
iajs-3629	172	5	used	use	VERB
iajs-3629	172	6	to	to	PART
iajs-3629	172	7	forecast	forecast	VERB
iajs-3629	172	8	the	the	DET
iajs-3629	172	9	structural	structural	ADJ
iajs-3629	172	10	engineering	engineering	NOUN
iajs-3629	172	11	of	of	ADP
iajs-3629	172	12	all	all	DET
iajs-3629	172	13	compounds	compound	NOUN
iajs-3629	172	14	in	in	ADP
iajs-3629	172	15	the	the	DET
iajs-3629	172	16	gas	gas	NOUN
iajs-3629	172	17	phase	phase	NOUN
iajs-3629	172	18	,	,	PUNCT
iajs-3629	172	19	with	with	ADP
iajs-3629	172	20	physical	physical	ADJ
iajs-3629	172	21	properties	property	NOUN
iajs-3629	172	22	calculated	calculate	VERB
iajs-3629	172	23	using	use	VERB
iajs-3629	172	24	the	the	DET
iajs-3629	172	25	pm3	pm3	PROPN
iajs-3629	172	26	program	program	NOUN
iajs-3629	172	27	.	.	PUNCT
iajs-3629	173	1	acknowledgment	acknowledgment	NOUN
iajs-3629	173	2	the	the	DET
iajs-3629	173	3	authors	author	NOUN
iajs-3629	173	4	thank	thank	VERB
iajs-3629	173	5	the	the	DET
iajs-3629	173	6	department	department	NOUN
iajs-3629	173	7	of	of	ADP
iajs-3629	173	8	chemistry/	chemistry/	NUM
iajs-3629	173	9	college	college	NOUN
iajs-3629	173	10	of	of	ADP
iajs-3629	173	11	science	science	NOUN
iajs-3629	173	12	for	for	ADP
iajs-3629	173	13	women/	women/	NUM
iajs-3629	173	14	university	university	NOUN
iajs-3629	173	15	of	of	ADP
iajs-3629	173	16	baghdad	baghdad	PROPN
iajs-3629	173	17	.	.	PUNCT
iajs-3629	174	1	conflict	conflict	NOUN
iajs-3629	174	2	of	of	ADP
iajs-3629	174	3	interest	interest	NOUN
iajs-3629	174	4	the	the	DET
iajs-3629	174	5	authors	author	NOUN
iajs-3629	174	6	declare	declare	VERB
iajs-3629	174	7	that	that	SCONJ
iajs-3629	174	8	they	they	PRON
iajs-3629	174	9	have	have	VERB
iajs-3629	174	10	no	no	DET
iajs-3629	174	11	conflicts	conflict	NOUN
iajs-3629	174	12	of	of	ADP
iajs-3629	174	13	interest	interest	NOUN
iajs-3629	174	14	.	.	PUNCT
iajs-3629	175	1	ethical	ethical	ADJ
iajs-3629	175	2	clearance	clearance	NOUN
iajs-3629	175	3	the	the	DET
iajs-3629	175	4	study	study	NOUN
iajs-3629	175	5	is	be	AUX
iajs-3629	175	6	included	include	VERB
iajs-3629	175	7	in	in	ADP
iajs-3629	175	8	the	the	DET
iajs-3629	175	9	2022–2023	2022–2023	NUM
iajs-3629	175	10	academic	academic	ADJ
iajs-3629	175	11	year	year	NOUN
iajs-3629	175	12	research	research	NOUN
iajs-3629	175	13	plan	plan	NOUN
iajs-3629	175	14	form	form	NOUN
iajs-3629	175	15	at	at	ADP
iajs-3629	175	16	the	the	DET
iajs-3629	175	17	university	university	NOUN
iajs-3629	175	18	of	of	ADP
iajs-3629	175	19	baghdad	baghdad	PROPN
iajs-3629	175	20	.	.	PUNCT
iajs-3629	176	1	references	reference	NOUN
iajs-3629	176	2	1	1	NUM
iajs-3629	176	3	.	.	PUNCT
iajs-3629	177	1	nesa	nesa	PROPN
iajs-3629	177	2	sh	sh	PROPN
iajs-3629	177	3	,	,	PUNCT
iajs-3629	177	4	nasira	nasira	PROPN
iajs-3629	177	5	su	su	PROPN
iajs-3629	177	6	,	,	PUNCT
iajs-3629	177	7	ashrafuzzaman	ashrafuzzaman	NOUN
iajs-3629	177	8	m	m	PROPN
iajs-3629	177	9	,	,	PUNCT
iajs-3629	177	10	habib	habib	PROPN
iajs-3629	177	11	a	a	PROPN
iajs-3629	177	12	,	,	PUNCT
iajs-3629	177	13	rashid	rashid	PROPN
iajs-3629	177	14	am	am	PROPN
iajs-3629	177	15	,	,	PUNCT
iajs-3629	177	16	haque	haque	PROPN
iajs-3629	177	17	m.	m.	PROPN
iajs-3629	177	18	mixed	mixed	ADJ
iajs-3629	177	19	ligand	ligand	NOUN
iajs-3629	177	20	complexes	complex	NOUN
iajs-3629	177	21	:	:	PUNCT
iajs-3629	177	22	synthesis	synthesis	NOUN
iajs-3629	177	23	,	,	PUNCT
iajs-3629	177	24	characterization	characterization	NOUN
iajs-3629	177	25	and	and	CCONJ
iajs-3629	177	26	antibacterial	antibacterial	ADJ
iajs-3629	177	27	activity	activity	NOUN
iajs-3629	177	28	investigation	investigation	NOUN
iajs-3629	177	29	.	.	PUNCT
iajs-3629	178	1	int	int	NOUN
iajs-3629	178	2	j	j	PROPN
iajs-3629	178	3	chem	chem	NOUN
iajs-3629	178	4	stud	stud	NOUN
iajs-3629	178	5	.	.	PUNCT
iajs-3629	179	1	2020	2020	NUM
iajs-3629	179	2	;	;	PUNCT
iajs-3629	179	3	8:306312	8:306312	NUM
iajs-3629	179	4	.	.	PUNCT
iajs-3629	180	1	https://doi.org/10.22271/chemi.2020.v8.i1d.8267	https://doi.org/10.22271/chemi.2020.v8.i1d.8267	NOUN
iajs-3629	180	2	.	.	PUNCT
iajs-3629	181	1	2	2	X
iajs-3629	181	2	.	.	X
iajs-3629	181	3	piaggesi	piaggesi	PROPN
iajs-3629	181	4	a	a	PRON
iajs-3629	181	5	,	,	PUNCT
iajs-3629	181	6	låuchli	låuchli	NOUN
iajs-3629	181	7	s	s	PROPN
iajs-3629	181	8	,	,	PUNCT
iajs-3629	181	9	bassetto	bassetto	ADJ
iajs-3629	181	10	f	f	PROPN
iajs-3629	181	11	,	,	PUNCT
iajs-3629	181	12	biedermannt	biedermannt	NOUN
iajs-3629	181	13	,	,	PUNCT
iajs-3629	181	14	marques	marques	X
iajs-3629	181	15	a.	a.	NOUN
iajs-3629	181	16	advanced	advanced	PROPN
iajs-3629	181	17	therapies	therapy	NOUN
iajs-3629	181	18	in	in	ADP
iajs-3629	181	19	wound	wound	ADJ
iajs-3629	181	20	management	management	NOUN
iajs-3629	181	21	.	.	PUNCT
iajs-3629	182	1	journal	journal	PROPN
iajs-3629	182	2	of	of	ADP
iajs-3629	182	3	wound	wound	NOUN
iajs-3629	182	4	care	care	NOUN
iajs-3629	182	5	.	.	PUNCT
iajs-3629	183	1	2018	2018	NUM
iajs-3629	183	2	;	;	PUNCT
iajs-3629	183	3	27(6):s1	27(6):s1	NUM
iajs-3629	183	4	-	-	PUNCT
iajs-3629	183	5	s137	s137	PROPN
iajs-3629	183	6	.	.	PUNCT
iajs-3629	184	1	https://doi.org/10.12968/jowc.2018.27.sup6a.s1	https://doi.org/10.12968/jowc.2018.27.sup6a.s1	PROPN
iajs-3629	184	2	.	.	PUNCT
iajs-3629	185	1	3	3	X
iajs-3629	185	2	.	.	X
iajs-3629	185	3	kaimw	kaimw	ADJ
iajs-3629	185	4	,	,	PUNCT
iajs-3629	185	5	schwederski	schwederski	NOUN
iajs-3629	185	6	b	b	PROPN
iajs-3629	185	7	,	,	PUNCT
iajs-3629	185	8	klein	klein	PROPN
iajs-3629	185	9	a.	a.	PROPN
iajs-3629	185	10	bioinorganic	bioinorganic	PROPN
iajs-3629	185	11	chemistry	chemistry	NOUN
iajs-3629	185	12	-	-	PUNCT
iajs-3629	185	13	inorganic	inorganic	ADJ
iajs-3629	185	14	elements	element	NOUN
iajs-3629	185	15	in	in	ADP
iajs-3629	185	16	the	the	DET
iajs-3629	185	17	chemistry	chemistry	NOUN
iajs-3629	185	18	of	of	ADP
iajs-3629	185	19	life	life	NOUN
iajs-3629	185	20	:	:	PUNCT
iajs-3629	185	21	an	an	DET
iajs-3629	185	22	introduction	introduction	NOUN
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iajs-3629	185	25	.	.	PUNCT
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iajs-3629	186	5	;	;	PUNCT
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iajs-3629	186	7	.	.	PUNCT
iajs-3629	187	1	4	4	X
iajs-3629	187	2	.	.	X
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iajs-3629	187	5	,	,	PUNCT
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iajs-3629	187	8	,	,	PUNCT
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iajs-3629	187	10	.	.	PUNCT
iajs-3629	188	1	a	a	DET
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iajs-3629	188	6	expired	expired	ADJ
iajs-3629	188	7	ampicillin	ampicillin	PROPN
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iajs-3629	188	11	for	for	ADP
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iajs-3629	188	18	.	.	PUNCT
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iajs-3629	190	4	-	-	SYM
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iajs-3629	190	6	.	.	PUNCT
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iajs-3629	191	4	.	.	X
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iajs-3629	191	46	.	.	PUNCT
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iajs-3629	192	3	.	.	PUNCT
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iajs-3629	192	5	;	;	PUNCT
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iajs-3629	192	7	-	-	PUNCT
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iajs-3629	192	9	.	.	PUNCT
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iajs-3629	193	2	.	.	PUNCT
iajs-3629	194	1	6	6	NUM
iajs-3629	194	2	.	.	X
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iajs-3629	194	8	,	,	PUNCT
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iajs-3629	195	5	,	,	PUNCT
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iajs-3629	195	8	.	.	PUNCT
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iajs-3629	196	8	,	,	PUNCT
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iajs-3629	197	3	-	-	SYM
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iajs-3629	197	5	.	.	PUNCT
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iajs-3629	198	11	.	.	PUNCT
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iajs-3629	204	7	.	.	X
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iajs-3629	214	5	.	.	PUNCT
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iajs-3629	216	5	.	.	PUNCT
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iajs-3629	218	7	.	.	PUNCT
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iajs-3629	219	2	.	.	PUNCT
iajs-3629	220	1	13	13	NUM
iajs-3629	220	2	.	.	PUNCT
iajs-3629	221	1	pandya	pandya	PROPN
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iajs-3629	221	7	biological	biological	ADJ
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iajs-3629	221	10	some	some	DET
iajs-3629	221	11	newly	newly	ADV
iajs-3629	221	12	synthesized	synthesize	VERB
iajs-3629	221	13	mix	mix	NOUN
iajs-3629	221	14	ligand	ligand	NOUN
iajs-3629	221	15	chelates	chelate	NOUN
iajs-3629	221	16	pandya	pandya	PROPN
iajs-3629	221	17	.	.	PUNCT
iajs-3629	222	1	j	j	PROPN
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iajs-3629	222	4	.	.	PUNCT
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iajs-3629	223	2	;	;	PUNCT
iajs-3629	223	3	8(2):1	8(2):1	NUM
iajs-3629	223	4	-	-	SYM
iajs-3629	223	5	5	5	NUM
iajs-3629	223	6	.	.	PUNCT
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iajs-3629	224	2	.	.	PUNCT
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iajs-3629	225	2	.	.	PUNCT
iajs-3629	226	1	abdulsalam	abdulsalam	PROPN
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iajs-3629	226	6	.	.	PUNCT
iajs-3629	227	1	synthesis	synthesis	NOUN
iajs-3629	227	2	,	,	PUNCT
iajs-3629	227	3	characterization	characterization	NOUN
iajs-3629	227	4	,	,	PUNCT
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iajs-3629	227	6	biological	biological	ADJ
iajs-3629	227	7	activity	activity	NOUN
iajs-3629	227	8	of	of	ADP
iajs-3629	227	9	mixed	mixed	ADJ
iajs-3629	227	10	ligand	ligand	NOUN
iajs-3629	227	11	complexes	complex	NOUN
iajs-3629	227	12	from	from	ADP
iajs-3629	227	13	8	8	NUM
iajs-3629	227	14	-	-	PUNCT
iajs-3629	227	15	hydroxyquinoline	hydroxyquinoline	NOUN
iajs-3629	227	16	and	and	CCONJ
iajs-3629	227	17	new	new	ADJ
iajs-3629	227	18	ligand	ligand	NOUN
iajs-3629	227	19	for	for	ADP
iajs-3629	227	20	β	β	NOUN
iajs-3629	227	21	-	-	NOUN
iajs-3629	227	22	enaminone	enaminone	NOUN
iajs-3629	227	23	.	.	PUNCT
iajs-3629	228	1	j	j	PROPN
iajs-3629	228	2	chem	chem	PROPN
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iajs-3629	228	4	.	.	PUNCT
iajs-3629	229	1	2022	2022	NUM
iajs-3629	229	2	;	;	PUNCT
iajs-3629	229	3	6	6	NUM
iajs-3629	229	4	:	:	SYM
iajs-3629	229	5	962	962	NUM
iajs-3629	229	6	-	-	SYM
iajs-3629	229	7	976	976	NUM
iajs-3629	229	8	.	.	PUNCT
iajs-3629	230	1	https://doi.org/10.22034/chemm.2022.356340.1593	https://doi.org/10.22034/chemm.2022.356340.1593	X
iajs-3629	230	2	.	.	PUNCT
iajs-3629	231	1	15	15	NUM
iajs-3629	231	2	.	.	PUNCT
iajs-3629	232	1	hassan	hassan	PROPN
iajs-3629	232	2	sh	sh	PROPN
iajs-3629	232	3	,	,	PUNCT
iajs-3629	232	4	ibrahim	ibrahim	PROPN
iajs-3629	232	5	sk	sk	PROPN
iajs-3629	232	6	,	,	PUNCT
iajs-3629	232	7	mahmoud	mahmoud	PROPN
iajs-3629	232	8	ma	ma	PROPN
iajs-3629	232	9	,	,	PUNCT
iajs-3629	232	10	alias	alias	PROPN
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iajs-3629	232	12	.	.	NOUN
iajs-3629	232	13	synthesis	synthesis	NOUN
iajs-3629	232	14	and	and	CCONJ
iajs-3629	232	15	characterization	characterization	NOUN
iajs-3629	232	16	of	of	ADP
iajs-3629	232	17	some	some	DET
iajs-3629	232	18	metal	metal	NOUN
iajs-3629	232	19	complexes	complex	NOUN
iajs-3629	232	20	with	with	ADP
iajs-3629	232	21	new	new	ADJ
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iajs-3629	232	23	)	)	PUNCT
iajs-3629	232	24	and	and	CCONJ
iajs-3629	232	25	theoretical	theoretical	ADJ
iajs-3629	232	26	treatmen	treatman	NOUN
iajs-3629	232	27	.	.	PUNCT
iajs-3629	233	1	sys	sys	PROPN
iajs-3629	233	2	rev	rev	PROPN
iajs-3629	233	3	pharm	pharm	PROPN
iajs-3629	233	4	.	.	PUNCT
iajs-3629	234	1	2020	2020	NUM
iajs-3629	234	2	;	;	PUNCT
iajs-3629	234	3	11(12	11(12	NUM
iajs-3629	234	4	):	):	PUNCT
iajs-3629	234	5	747	747	NUM
iajs-3629	234	6	-	-	SYM
iajs-3629	234	7	753	753	NUM
iajs-3629	234	8	.	.	PUNCT
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iajs-3629	235	2	.	.	PUNCT
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iajs-3629	236	2	.	.	PUNCT
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iajs-3629	237	3	,	,	PUNCT
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iajs-3629	237	10	and	and	CCONJ
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iajs-3629	237	12	studied	study	VERB
iajs-3629	237	13	on	on	ADP
iajs-3629	237	14	the	the	DET
iajs-3629	237	15	leaves	leave	NOUN
iajs-3629	237	16	of	of	ADP
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iajs-3629	237	18	.	.	PUNCT
iajs-3629	238	1	j	j	PROPN
iajs-3629	238	2	chem	chem	PROPN
iajs-3629	238	3	pharm	pharm	NOUN
iajs-3629	238	4	res	re	NOUN
iajs-3629	238	5	.	.	PUNCT
iajs-3629	238	6	2011	2011	NUM
iajs-3629	238	7	;	;	PUNCT
iajs-3629	238	8	3(5):145	3(5):145	NUM
iajs-3629	238	9	-	-	SYM
iajs-3629	238	10	150	150	NUM
iajs-3629	238	11	.	.	PUNCT
iajs-3629	239	1	www.jocpr.com	www.jocpr.com	X
iajs-3629	239	2	.	.	PUNCT
iajs-3629	240	1	17	17	NUM
iajs-3629	240	2	.	.	PUNCT
iajs-3629	241	1	el	el	PROPN
iajs-3629	241	2	-	-	PUNCT
iajs-3629	241	3	sonbati	sonbati	PROPN
iajs-3629	241	4	az	az	PROPN
iajs-3629	241	5	,	,	PUNCT
iajs-3629	241	6	el	el	PROPN
iajs-3629	241	7	-	-	PUNCT
iajs-3629	241	8	mogazy	mogazy	PROPN
iajs-3629	241	9	ma	ma	PROPN
iajs-3629	241	10	,	,	PUNCT
iajs-3629	241	11	nozha	nozha	VERB
iajs-3629	241	12	sg	sg	PROPN
iajs-3629	241	13	,	,	PUNCT
iajs-3629	241	14	diab	diab	PROPN
iajs-3629	241	15	ma	ma	PROPN
iajs-3629	241	16	,	,	PUNCT
iajs-3629	241	17	abou	abou	PROPN
iajs-3629	241	18	-	-	PUNCT
iajs-3629	241	19	dobara	dobara	PROPN
iajs-3629	241	20	mi	mi	PROPN
iajs-3629	241	21	,	,	PUNCT
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iajs-3629	241	24	,	,	PUNCT
iajs-3629	241	25	morgan	morgan	PROPN
iajs-3629	241	26	shm	shm	PROPN
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iajs-3629	241	29	ligand	ligand	PROPN
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iajs-3629	241	31	metal(ii	metal(ii	PROPN
iajs-3629	241	32	)	)	PUNCT
iajs-3629	241	33	complexes	complex	NOUN
iajs-3629	241	34	:	:	PUNCT
iajs-3629	241	35	characterization	characterization	NOUN
iajs-3629	241	36	,	,	PUNCT
iajs-3629	241	37	spectral	spectral	ADJ
iajs-3629	241	38	,	,	PUNCT
iajs-3629	241	39	electrochemical	electrochemical	ADJ
iajs-3629	241	40	studies	study	NOUN
iajs-3629	241	41	,	,	PUNCT
iajs-3629	241	42	molecular	molecular	ADJ
iajs-3629	241	43	docking	docking	NOUN
iajs-3629	241	44	and	and	CCONJ
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iajs-3629	241	47	.	.	PUNCT
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iajs-3629	242	5	.	.	PUNCT
iajs-3629	243	1	2022	2022	NUM
iajs-3629	243	2	;	;	PUNCT
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iajs-3629	243	4	.	.	PUNCT
iajs-3629	244	1	https://doi.org/10.1016/j.molstruc.2021.131498	https://doi.org/10.1016/j.molstruc.2021.131498	ADJ
iajs-3629	244	2	.	.	PUNCT
iajs-3629	245	1	18	18	NUM
iajs-3629	245	2	.	.	PUNCT
iajs-3629	245	3	paison	paison	NOUN
iajs-3629	245	4	f	f	PROPN
iajs-3629	245	5	,	,	PUNCT
iajs-3629	245	6	su	su	PROPN
iajs-3629	245	7	b	b	PROPN
iajs-3629	245	8	,	,	PUNCT
iajs-3629	245	9	pan	pan	PROPN
iajs-3629	245	10	d	d	PROPN
iajs-3629	245	11	,	,	PUNCT
iajs-3629	245	12	yan	yan	PROPN
iajs-3629	245	13	t	t	PROPN
iajs-3629	245	14	,	,	PUNCT
iajs-3629	245	15	and	and	CCONJ
iajs-3629	245	16	wu	wu	PROPN
iajs-3629	245	17	j.	j.	PROPN
iajs-3629	246	1	the	the	DET
iajs-3629	246	2	study	study	NOUN
iajs-3629	246	3	of	of	ADP
iajs-3629	246	4	biological	biological	ADJ
iajs-3629	246	5	activities	activity	NOUN
iajs-3629	246	6	of	of	ADP
iajs-3629	246	7	various	various	ADJ
iajs-3629	246	8	mixed	mixed	ADJ
iajs-3629	246	9	ligand	ligand	NOUN
iajs-3629	246	10	complexes	complex	NOUN
iajs-3629	246	11	of	of	ADP
iajs-3629	246	12	nickel(ii	nickel(ii	NOUN
iajs-3629	246	13	)	)	PUNCT
iajs-3629	246	14	.	.	PUNCT
iajs-3629	247	1	austin	austin	PROPN
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iajs-3629	247	3	.	.	PUNCT
iajs-3629	248	1	2020	2020	NUM
iajs-3629	248	2	;	;	PUNCT
iajs-3629	248	3	5(1):1025	5(1):1025	NUM
iajs-3629	248	4	.	.	PUNCT
iajs-3629	249	1	https://doi.org/10.1007/s42250-02300640-4	https://doi.org/10.1007/s42250-02300640-4	PROPN
iajs-3629	249	2	.	.	PROPN
iajs-3629	250	1	19	19	NUM
iajs-3629	250	2	.	.	PUNCT
iajs-3629	251	1	hasan	hasan	PROPN
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iajs-3629	251	3	,	,	PUNCT
iajs-3629	251	4	baqer	baqer	PROPN
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iajs-3629	252	1	preparation	preparation	NOUN
iajs-3629	252	2	,	,	PUNCT
iajs-3629	252	3	characterization	characterization	NOUN
iajs-3629	252	4	,	,	PUNCT
iajs-3629	252	5	theoretical	theoretical	ADJ
iajs-3629	252	6	and	and	CCONJ
iajs-3629	252	7	biological	biological	ADJ
iajs-3629	252	8	studies	study	NOUN
iajs-3629	252	9	of	of	ADP
iajs-3629	252	10	mixed	mixed	ADJ
iajs-3629	252	11	ligands	ligand	NOUN
iajs-3629	252	12	complexes	complex	NOUN
iajs-3629	252	13	derived	derive	VERB
iajs-3629	252	14	from	from	ADP
iajs-3629	252	15	heterocyclic	heterocyclic	ADJ
iajs-3629	252	16	compound	compound	NOUN
iajs-3629	252	17	against	against	ADP
iajs-3629	252	18	different	different	ADJ
iajs-3629	252	19	types	type	NOUN
iajs-3629	252	20	of	of	ADP
iajs-3629	252	21	bacteria	bacteria	NOUN
iajs-3629	252	22	and	and	CCONJ
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iajs-3629	252	24	.	.	PUNCT
iajs-3629	253	1	ihjpas	ihjpas	PROPN
iajs-3629	253	2	.	.	PUNCT
iajs-3629	254	1	2022	2022	NUM
iajs-3629	254	2	;	;	PUNCT
iajs-3629	254	3	22(2):2867	22(2):2867	NUM
iajs-3629	254	4	-	-	SYM
iajs-3629	254	5	2895	2895	NUM
iajs-3629	254	6	.	.	PUNCT
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iajs-3629	255	4	.	.	PUNCT
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iajs-3629	256	4	baqer	baqer	PROPN
iajs-3629	256	5	sr	sr	PROPN
iajs-3629	256	6	.	.	PUNCT
iajs-3629	257	1	preparation	preparation	NOUN
iajs-3629	257	2	of	of	ADP
iajs-3629	257	3	new	new	ADJ
iajs-3629	257	4	series	series	NOUN
iajs-3629	257	5	of	of	ADP
iajs-3629	257	6	tetradentate	tetradentate	PROPN
iajs-3629	257	7	schiff	schiff	PROPN
iajs-3629	257	8	base	base	NOUN
iajs-3629	257	9	complexes	complex	NOUN
iajs-3629	257	10	and	and	CCONJ
iajs-3629	257	11	studing	stud	VERB
iajs-3629	257	12	them	they	PRON
iajs-3629	257	13	spectroscopically	spectroscopically	ADV
iajs-3629	257	14	,	,	PUNCT
iajs-3629	257	15	biologically	biologically	ADV
iajs-3629	257	16	and	and	CCONJ
iajs-3629	257	17	theoretically	theoretically	ADV
iajs-3629	257	18	.	.	PUNCT
iajs-3629	258	1	ijmrcp	ijmrcp	PROPN
iajs-3629	258	2	.	.	PUNCT
iajs-3629	259	1	2023	2023	NUM
iajs-3629	259	2	;	;	PUNCT
iajs-3629	259	3	15(1):106	15(1):106	NUM
iajs-3629	259	4	-	-	SYM
iajs-3629	259	5	119	119	NUM
iajs-3629	259	6	.	.	PUNCT
iajs-3629	260	1	http://dx.doi.org/10.28936/jmracpc15.1.2023.(10	http://dx.doi.org/10.28936/jmracpc15.1.2023.(10	PROPN
iajs-3629	260	2	)	)	PUNCT
iajs-3629	260	3	.	.	PUNCT
iajs-3629	261	1	21	21	NUM
iajs-3629	261	2	.	.	PUNCT
iajs-3629	262	1	mohammed	mohammed	PROPN
iajs-3629	262	2	er	er	INTJ
iajs-3629	262	3	,	,	PUNCT
iajs-3629	262	4	saied	saie	VERB
iajs-3629	262	5	sm	sm	PROPN
iajs-3629	262	6	.	.	PUNCT
iajs-3629	262	7	synthesis	synthesis	NOUN
iajs-3629	262	8	,	,	PUNCT
iajs-3629	262	9	characterization	characterization	NOUN
iajs-3629	262	10	and	and	CCONJ
iajs-3629	262	11	biological	biological	ADJ
iajs-3629	262	12	evaluation	evaluation	NOUN
iajs-3629	262	13	study	study	NOUN
iajs-3629	262	14	of	of	ADP
iajs-3629	262	15	cephalexin	cephalexin	PROPN
iajs-3629	262	16	(	(	PUNCT
iajs-3629	262	17	ceph	ceph	PROPN
iajs-3629	262	18	)	)	PUNCT
iajs-3629	262	19	and	and	CCONJ
iajs-3629	262	20	isatin	isatin	PROPN
iajs-3629	262	21	schiff	schiff	PROPN
iajs-3629	262	22	base	base	NOUN
iajs-3629	262	23	and	and	CCONJ
iajs-3629	262	24	its	its	PRON
iajs-3629	262	25	complexation	complexation	NOUN
iajs-3629	262	26	with	with	ADP
iajs-3629	262	27	some	some	DET
iajs-3629	262	28	divalent	divalent	ADJ
iajs-3629	262	29	metal	metal	NOUN
iajs-3629	262	30	ions	ion	NOUN
iajs-3629	262	31	.	.	PUNCT
iajs-3629	263	1	egypt	egypt	PROPN
iajs-3629	263	2	j	j	PROPN
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iajs-3629	263	4	.	.	PUNCT
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iajs-3629	264	2	;	;	PUNCT
iajs-3629	264	3	65(7):595	65(7):595	PROPN
iajs-3629	264	4	-	-	PUNCT
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iajs-3629	264	7	22	22	NUM
iajs-3629	264	8	.	.	PUNCT
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iajs-3629	266	4	characterizations	characterization	NOUN
iajs-3629	266	5	of	of	ADP
iajs-3629	266	6	vanadyl	vanadyl	NOUN
iajs-3629	266	7	(	(	PUNCT
iajs-3629	266	8	ii	ii	NOUN
iajs-3629	266	9	)	)	PUNCT
iajs-3629	266	10	and	and	CCONJ
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iajs-3629	266	12	)	)	PUNCT
iajs-3629	266	13	mixed	mixed	ADJ
iajs-3629	266	14	ligand	ligand	NOUN
iajs-3629	266	15	complexes	complex	NOUN
iajs-3629	266	16	containing	contain	VERB
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iajs-3629	266	18	drug	drug	NOUN
iajs-3629	266	19	and	and	CCONJ
iajs-3629	266	20	glycine	glycine	NOUN
iajs-3629	266	21	amino	amino	NOUN
iajs-3629	266	22	acid	acid	NOUN
iajs-3629	266	23	.	.	PUNCT
iajs-3629	267	1	open	open	ADJ
iajs-3629	267	2	chem	chem	NOUN
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iajs-3629	299	27	ternary	ternary	ADJ
iajs-3629	299	28	metal	metal	NOUN
iajs-3629	299	29	complexes	complex	NOUN
iajs-3629	299	30	of	of	ADP
iajs-3629	299	31	alanine	alanine	NOUN
iajs-3629	299	32	and	and	CCONJ
iajs-3629	299	33	1,8	1,8	NOUN
iajs-3629	299	34	-	-	PUNCT
iajs-3629	299	35	diaminonapthalene	diaminonapthalene	NOUN
iajs-3629	299	36	with	with	ADP
iajs-3629	299	37	co(iii	co(iii	NOUN
iajs-3629	299	38	)	)	PUNCT
iajs-3629	299	39	,	,	PUNCT
iajs-3629	299	40	ni(ii	ni(ii	PROPN
iajs-3629	299	41	)	)	PUNCT
iajs-3629	299	42	,	,	PUNCT
iajs-3629	299	43	cu(ii	cu(ii	PROPN
iajs-3629	299	44	)	)	PUNCT
iajs-3629	299	45	,	,	PUNCT
iajs-3629	299	46	zn(ii	zn(ii	NUM
iajs-3629	299	47	)	)	PUNCT
iajs-3629	299	48	and	and	CCONJ
iajs-3629	299	49	cd(ii	cd(ii	PROPN
iajs-3629	299	50	)	)	PUNCT
iajs-3629	299	51	.	.	PUNCT
iajs-3629	300	1	mater	mater	PROPN
iajs-3629	300	2	.	.	PUNCT
iajs-3629	301	1	today	today	NOUN
iajs-3629	301	2	:	:	PUNCT
iajs-3629	301	3	proc	proc	NOUN
iajs-3629	301	4	.	.	PROPN
iajs-3629	301	5	2021	2021	NUM
iajs-3629	301	6	;	;	PUNCT
iajs-3629	301	7	46(14):6374	46(14):6374	NUM
iajs-3629	301	8	-	-	SYM
iajs-3629	301	9	6381	6381	NUM
iajs-3629	301	10	.	.	PUNCT
iajs-3629	302	1	https://doi.org/10.1016/j.matpr.2020.06.126	https://doi.org/10.1016/j.matpr.2020.06.126	NOUN
iajs-3629	302	2	.	.	PUNCT
iajs-3629	303	1	https://doi.org/10.1016/j.inoche.2022.109776	https://doi.org/10.1016/j.inoche.2022.109776	PROPN
iajs-3629	303	2	https://doi.org/10.53350/pjmhs22166579	https://doi.org/10.53350/pjmhs22166579	PROPN
iajs-3629	303	3	https://doi.org/10.36329/jkcm/2022/v2.i9.13312	https://doi.org/10.36329/jkcm/2022/v2.i9.13312	PROPN
iajs-3629	303	4	.	.	PUNCT
iajs-3629	304	1	https://doi.org/10.1016/j.matpr.2020.06.126	https://doi.org/10.1016/j.matpr.2020.06.126	PRON