Sample Paper - Manuscript Preparation 16 J. mt. area res., Vol. 2, 2017 Journal of Mountain Area Research DETERMINATION OF DIVERSE ENVIRONMENTAL POLLUTION LEVEL FROM SELECTED AREAS OF RAWALPINDI, PAKISTAN S. Pervez1,*, M. S. Siddique1, H. Y. Abdullah1, A. Zahra2, N. K. khanzada1, H. Fareed1, G. Hasnain1 1. Institute of Environmental Sciences and Engineering, National University of Sciences and Technology (IESE, NUST), Islamabad 2. School of Natural Sciences, National University of Sciences and Technology (SNS, NUST), Islamabad ABSTRACT Anthropogenic contaminants arising from both stationary (power plants, industries and residential heating) and mobile sources (road traffic) can harm ambient air quality in urban areas. Depending upon their physical state, these pollutants are classified as liquid and vapor phases and are subsequently transported to the Earth’s surface through dry and wet deposition. After the deposition of these pollutants onto the surface of earth various health effects caused by these pollutants occurred like cardiovascular diseases and hypertension. In this study four different locations/sites were selected from the Rawalpindi city depending upon the population, traffic rush and industries to examine the noise level, concentration of carbon dioxide and heavy metals. Air sampler was used for the collection of air sample to analyze the heavy metal concentration, Quest electronic sound meter for measuring sound level and SIBATA for CO2 measurement. The study findings revealed that noise level was higher at all selected locations as described by WHO limit (70 dB) being highest at Industrial area due to heavy machinery and lowest at green area. Concentration of all four heavy metals were high as compared with the prescribed limits. CO2 level reaches up to 300 ppm because of coal consumption during the winter season. The threshold values of all these selected parameters well above the prescribed limits defined by the authorities so to combat with this situation we should move towards more energy efficient fuels, proper maintenance of vehicles and machineries, traffic management and installation of noise barriers in industries as well as installation of catalytic convertors in vehicles to stop further air pollution. KEYWORDS: Climate change, Heavy metals, CO2, Noise, Rawalpindi *Corresponding author: (Email: saim3035@gmail.com) 1. INTRODUCTION Pakistan is bestowed with a great diversity of landscape, climate, seasons, ecosystems, etc. The landscape ranges from snowcapped peaks in the Himalayan Range in the north to Arabian Sea coastline in the south, from agriculture ranges in the plains to hot dry deserts in Sindh and Baluchistan. This diversity has given rise to a variety of living organisms including flora, fauna, animals, birds, insects, etc. which provide economic Vol. 2, 2017 http://journal.kiu.edu.pk/index.php/JMAR Full length article mailto:saim3035@gmail.com Pervez et al., J. mt. area res. 02 (2017) 16-22 17 J. mt. area res., Vol. 2, 2017 benefits and services to human society as well as ecological, recreational, cultural and aesthetic values. However, this diversity provided by the nature has not been exempted by the human greed for development, has been to a large extent exploiting the variety of resources provided by the nature. Although Pakistan contributes only 0.8 percent in the global greenhouse gas emissions and is ranked 135th in global GHG per capita emissions, still the countries biodiversity is prone to adverse impacts of climate change and the country has been rated as one of the most vulnerable nations to the adverse effects of climate change. Sources of air pollution are: (1) Natural (2) manufactured. Natural sources includes wind storms, volcanic ash and gases, pollens and gases or odors from natural decomposition while man-made sources of air pollution are: industries and vehicles (El- Mubarak et al., 2014). The main pollutants from all these sources are carbon dioxide (CO2), methane (CH4), hydrocarbons and particulate matter. Two different types of air pollutants are present, Primary and secondary pollutant. Primary pollutants are those that occurs in a harmful concentration, added directly to the air by natural events or human activities while secondary pollutants are formed in atmosphere when a primary pollutant reacts with the normal air components or with other air pollutants. [1]. Effects of all these man-made or natural atmospheric pollutants are very adverse like severe respiratory problems such as asthma, chronic bronchitis, and degraded lung function and at last but not least respiratory failure [2, 3]. So, it is necessary to combat with all these types of pollutants and with the sources, that a healthier environment could achieve and climate change not affect at all. The aim of the present study is to analyze and characterize the ambient air of Rawalpindi city for the quantitative assessment of heavy metals, noise level and carbon dioxide emissions from anthropogenic sources and examine the current level of compliance with environmental regulations. 2. MATERIALS AND METHODS The present study deals with the characterization and analysis of ambient air of Rawalpindi city. For this analysis, four different locations based upon populations and industrial density were selected. Bahria town was selected as residential area while commercial market selected as a commercial area. Murree road is one of the congested and busy road of Rawalpindi city and also industries lies on the side of the road hence it was selected as industrial area whereas Ayub Park selected as green area. Air samples were collected from December to February. A brief methodology followed during the project was: 1. Selection of the area 2. Visiting the sites 3. Taking the readings of noise and CO2 4. Collecting the air samples 5. Obtaining the heavy metals measurements using the AAS. 6. Comparing the values with standards The analysis of different parameters measured were performed using standard Pervez et al., J. mt. area res. 02 (2017) 16-22 18 J. mt. area res., Vol. 2, 2017 methods by APHA (American Public Health Association) 2010 as reference. Figure 1. Selection of the areas 2.1. Measurement of Noise Level For noise measurement the standard method was used as described in the literature. Instrument that was used named as Quest electronic sound meter (model 211 fs). First of all turn on the meter, select 100 dB range position then switch on the calibrator and check battery level indicator, carefully insert the meter microphone into the calibrator coupler. If reading is off slightly, insert a small screwdriver in the small hole on the bottom of the meter. Now change the selector switch to 110 dB position on the meter and note the needle should drop to the zero position on the meter dial. Meter is now calibrated and ready for use. Allow the needle to stabilize and record the measurement. (APHA, 2010) Figure 2. Quest electronic sound meter 2.2. Measurement of Carbon Dioxide (CO2) CO2 in air was monitored using combustion Gas Analyzer (US). The CO2 value was monitored and average was calculated. The sound level was monitored with the help of a portable sound meter. The equipment was mounted on a tripod stand with a microphone 1.5 m above the ground level. The data was continuously monitored and average values were calculated. (APHA, 2010) Figure 3. SIBATA CO2 meter 2.3. Air Samples for Heavy Metals Determination Pall flex quartz fiber filter was used for air sampling which was preheated at 550 0C for 1 hour. It was then mounted on an air sampler for 2 hours and air flow was kept at 1m3/min. After sampling, the paper was stored in aluminum foil and stored in freezer till analysis. Heavy metals were determined by chemically digesting filter paper and the resulting solution analyzed using AAS (atomic absorption spectrometer) [4]. Pervez et al., J. mt. area res. 02 (2017) 16-22 19 J. mt. area res., Vol. 2, 2017 3. RESULTS AND DISCUSSION Results and discussion were made according to the survey of the selected areas and after the calculation of the desired pollutant level. 3.1. Noise Level at Selected Sites of Study Area The noise level determined using the sound meter at all the selected locations and found it to be that at location of Ayub Park which is declared as green area has the minimum level of 78dB while the residential area and commercial area both have the same value of noise level i.e. 90dB although commercial area has more average value which is because of excessive vehicle horn and heavy traffic jam [5]. The value of sound was higher at industrial area i.e. 80-90dB because of heavy machinery working and industrial plants. The noise level at all the selected locations was greater than the prescribed limits given by world health organization (WHO). Chronic exposure of this loud noise level cause problems like cardiovascular and hypertension [6]. Figure 4. Average of Noise level (dB) 3.2. Carbon Dioxide Concentration at Selected Locations Because of anthropogenic activities, CO2 concentration was up to 300ppm. Max average value was observed at Bahria town i.e. 238 ppm while minimum average value was noted at commercial market. Murree road and Ayub Park had the average values of 214 and 207 ppm respectively. Astonishingly the area expected to have minimum pollution levels i.e. residential area of Ayub Park had maximum average values observed. This was probably winds blowing that took high concentrations of CO2 from congested areas like commercial markets to residential areas like Bahria town [7]. Moreover highest values were observed at 1: 00 PM and 7: 00 PM because these are the peak hours having maximum traffic population. Pakistan is one of top 50 countries in terms of CO2 emissions [8]. Figure 5. Average of Carbon Dioxide (CO2) concentration (ppm) 3.3. Heavy Metals Concentrations 3.3.1. Lead Maximum concentration was observed at Bahria town i.e. 149 µg/m3 while minimum at Ayub park i.e. 63 µg/m3 .there are two main sources of lead, lower quality fuel combustion and lead based paints [9]. Both of these sources are absent in Ayub park Pervez et al., J. mt. area res. 02 (2017) 16-22 20 J. mt. area res., Vol. 2, 2017 that’s why it has minimum concentration while in residential area paints and use of fuel in generators for electricity purpose are the source that’s why it has maximum values. All values are exceeding WHO guidelines of 0.5 µg/m3 which is alarming because lead is very harmful for human health mainly damage to nervous system even leading to death [10]. 3.3.2. Chromium Maximum concentration was observed at commercial market i.e. 42 µg/m3 while minimum at Ayub park. All the values are exceeding WHO guidelines for 0.11 µg/m3. Chromium is build up in atmosphere when there is lack of winds and air congestion. As commercial market was congested area so there was lack of winds in area which results in chromium buildup due to pollution in area. When there is good wind it is readily diluted. Chromium in air can lead to lung cancer [11]. 3.3.3. Arsenic Maximum value was observed at commercial market i.e. 33 µg/m3.Main sources of arsenic are fuel combustion and metal smelting and aerosols from pesticide. Welding shops lead to smelting while pesticides are used in parks adding to fuel combustion of vehicles. All the values are exceeding guidelines of WHO i.e.0.11 µg/m3. This should be taken as important concern because arsenic is very poisonous for human health [12]. 3.3.4. Iron All the values were exceeding the standards set by WHO for iron in air i.e. 150 µg/m3. Highest values were obtained at commercial market and Murree road i.e. 376 and 512 µg/m3 respectively. Sources were use of old machinery, dust winds and local industrial area [13]. 3.3.5. Manganese Manganese concentration were lowest among all the heavy metals detected but it was still higher than WHO standards i.e. 0.15 µg/m3.highest levels were obtained at Murree road i.e. 162 µg/m3 and lowest levels were detected at Ayub park i.e. 3 µg/m3. Sources of manganese are production of steel and alloys and burning of fossil fuels that’s why it has maximum concentration at Murree road. [4]. its chronic exposure can cause neurological disorders [14]. Figure 6. Average concentration of heavy metals 4. CONCLUSIONS It was observed that almost all the values for heavy metals and noise were found to be exceeding the WHO guidelines that is very alarming situation for the city environment and its inhabitants. Poisonous and dangerous heavy metals such as Arsenic (peak value: 33 µg/m3, WHO limit: 0.11 µg/m3), Lead (peak value: 149 µg/m3, WHO limit: 0.50 µg/m3) and Chromium (peak value: 42 µg/m3, WHO limit: 0.11 µg/m3) are more than 10 times their guideline values. Average Noise levels were around 80-90 db whereas safe hearing limit is Pervez et al., J. mt. area res. 02 (2017) 16-22 21 J. mt. area res., Vol. 2, 2017 below 85 db. 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