Papers in Physics, vol. 1, art. 010007 (2009) Received: 14 October 2009, Accepted: 28 December 2009 Edited by: A. C. Mart́ı Licence: Creative Commons Attribution 3.0 DOI: 10.4279/PIP.010007 www.papersinphysics.org ISSN 1852-4249 Parametric study of the interface behavior between two immiscible liquids flowing through a porous medium Alejandro David Mariotti,1∗ Elena Brandaleze,2† Gustavo C. Buscaglia3‡ When two immiscible liquids that coexist inside a porous medium are drained through an opening, a complex flow takes place in which the interface between the liquids moves, tilts and bends. The interface profiles depend on the physical properties of the liquids and on the velocity at which they are extracted. If the drainage flow rate, the liquids volume fraction in the drainage flow and the physical properties of the liquids are known, the interface angle in the immediate vicinity of the outlet (θ) can be determined. In this work, we define four nondimensional parameters that rule the fluid dynamical problem and, by means of a numerical parametric analysis, an equation to predict θ is developed. The equation is verified through several numerical assessments in which the parameters are modified simultaneously and arbitrarily. In addition, the qualitative influence of each nondimensional parameter on the interface shape is reported. I. Introduction The fluid dynamics of the flow of two immiscible liquids through a porous medium plays a key role in several engineering processes. Usually, though the interest is focused on the extraction of one of the liquids, the simultaneous extraction of both liq- uids is necessary. This is the case of oil production and of ironmaking. The water injection method used in oil production consists of injecting water back into the reservoir, usually to increase pressure ∗E-mail: mariotti.david@gmail.com †E-mail: ebrandaleze@frsn.utn.edu.ar ‡E-mail: gustavo.buscaglia@icmc.usp.br 1 Instituto Balseiro, 8400 San Carlos de Bariloche, Ar- gentina. 2 Departamento de Metalurgia, Universidad Tecnológica Nacional Facultad Regional San Nicolás, 2900 San Nicolás, Argentina. 3 Instituto de Ciências Matemáticas e de Computação, Universidade de São Paulo, 13560-970 São Carlos, Brasil. and thereby stimulate production. Normally, just a small percentage of the oil in a reservoir can be extracted, but water injection increases that per- centage and maintains the production rate of the reservoir over a longer period of time. The water displaces the oil from the reservoir and pushes it to- wards an oil production well [1]. In the steel indus- try, this multiphase phenomenon occurs inside the blast furnace hearth, in which the porous medium consists of coke particles. The slag and pig iron are stratified in the hearth and, periodically, they are drained through a lateral orifice. The under- standing of this flow is crucial for the proper design and management of the blast furnace hearth [2]. In both examples above, when the liquids are drained, a complex flow takes place in which the interface between the liquids moves, tilts and bends. Numerical simulation of multiphase flows in porous media is focused mainly in upscaling meth- ods, aimed at solving for large scale features of in- terest in such a way as to model the effect of the small scale features [3–5]. Other authors [6–8] use 010007-1 Papers in Physics, vol. 1, art. 010007 (2009) / A. D. Mariotti et al. the numerical methods to model the complex mul- tiphase flow that takes place at the pore scale. In this work, we numerically study the macro- scopic behavior of the interface between two im- miscible liquids flowing through a porous medium when they are drained through an opening. The effect of gravity on this phenomenon is considered. We define four nondimensional parameters that rule the fluid dynamical problem and, by means of a numerical parametric analysis, an equation to predict the interface tilt in the vicinity of the orifice (θ) is developed. The equation is verified through several numerical cases where the parameters are varied simultaneously and arbitrarily. In addition, the qualitative influence of each non-dimensional parameter on the interface shape is reported. II. Parametric Study The numerical studies in this work were carried out by means of the program FLUENT 6.3.26. Differ- ent models to simulate the two-dimensional para- metric study were used. The volume of fluid (VOF) method was chosen to treat the interface problem [9]. The drag force in the porous medium was modeled by means of the source term suggested by Forchheimer [10]. The source term for the ith mo- mentum equation is: Si = − ( µ α Vi + 1 2 ρC| −→ V |Vi ) . (1) For the constants α and C in Eq. (1), we use the values proposed by Ergun [10]: α = ε3d2 150(1 − ε)2 , (2) C = 1.75 (1 − ε) ε3d , (3) where ε is the porosity, d is the particle equivalent diameter, ρ is the density, V is the velocity and µ is the dynamic molecular viscosity. Considering that the subscript 1 and 2 represent the fluid 1 and the fluid 2 respectively, three nondi- mensional parameters were considered in the para- metric study: viscosity ratio, µR = µ1/µ2, density Figure 1: Sketch of the numerical 2D domain. ratio, ρR = ρ1/ρ2, and nondimensional velocity, VR = V0ρ2L/µ2; where V0 is the outlet velocity and L a reference length. i. Domain description The numerical domain considered to carry out the parametric study was a two-dimensional one com- posed by the porous medium sub-domain and the outlet sub-domain. The porous sub-domain is a rectangle 10m wide and 10m tall. Inside of it, a rigid, isotropic and homogeneous porous medium was arranged. We use a porosity and particle di- ameter of 0.32 and 0.006m, respectively. For the outlet domain we use a rectangle 0.02m wide and with a height L = 0.01m divided into two equal parts and located at the center of one of the lateral edges. The part located at the end of the outlet domain is used to impose the outlet velocity. Figure 1 shows a complete description of the domain. A quadrilateral mesh with 2.2 × 104 cells was used, where the outlet sub-domain mesh consists of 200 elements in all the cases studied. As boundary conditions, on edge 1 we define a zero gauge pressure condition normal to the bound- ary and impose that only the fluid 1 can enter to the domain through it. On edge 2 the boundary condi- tion is the same as on edge 1 but the fluid consider in this case is fluid 2. On edge 7 we impose a zero gauge pressure normal to the boundary but in this 010007-2 Papers in Physics, vol. 1, art. 010007 (2009) / A. D. Mariotti et al. Figure 2: Interface evolution when the initial posi- tion is below the outlet level, without gravity. case the fluids can only leave the domain. On the other edges (edges 4, 5, 6, and 8) we impose a wall condition where the normal and tangential velocity is zero except for edge 3, at which the tangential velocity is free and the stress tangential to the edge is zero. ii. Interface evolution To illustrate how an interface reaches the stationary position from an initially horizontal one, three sets of curves were obtained. Figure 2 shows the interface evolution for the case without the gravity effect and the interface initial position is below the outlet level. The inter- face modifies its tilt to reach the exit and it changes its shape to reach the stationary profile. Figures 3 and 4 show the interface evolution when the gravity is present but the interface initial position is below and above the outlet level respec- tively. iii. Viscosity effect One of the most important parameters to modify is the dynamical viscosity of fluid 1. We maintain the properties of the fluid 2 as the properties of water (density 998Kg/m3, and dynamical viscosity 0.001 Pa.s) and the density of fluid 1 as the density of the oil (850 Kg/m3). The dynamical viscosity of fluid 1 was varied from values smaller than those of fluid 2, to values much greater. Figure 3: Interface evolution when the initial posi- tion is below the outlet, with gravity. Figure 4: Interface evolution when the initial posi- tion is above the outlet, with gravity. Two sets of curves were obtained, one consid- ering the effect of gravity and the other without considering it. Figure 5 shows the stationary in- terface profiles for the different values of viscosity, without gravity. A value of VR = 1.5 × 104 and ρR = 1.17 were chosen. It is possible to observe that, when fluid 1 has a viscosity higher than that of fluid 2, the interface profile is above the outlet and points downwards at the outlet. If fluid 1 has a lower viscosity, the opposite happens. When considering gravity, the value of VR was changed to 1 × 105 (V0 = 10m/s), since for smaller values the interface may not reach the outlet (this is 010007-3 Papers in Physics, vol. 1, art. 010007 (2009) / A. D. Mariotti et al. Figure 5: Stationary interface profiles modifying the fluid 1 viscosity without the gravity effect. Figure 6: Stationary interface profiles modifying the fluid 1 viscosity with the gravity effect. later studied in Fig. 10). Figure 6 shows the curves obtained for this situation, where the interface only lies over the outlet level for the higher µR values. iv. Outlet velocity effect V0 is varied from a small value, similar to the porous medium velocity (V0 = 0.2m/s or VR = 2000), to a very large one (V0 = 50m/s or VR = 5×105). Main- taining the properties of fluid 2 similar to those of water, two sets of curves were obtained (µR > 1 and µR < 1), shown in Figs. 7 and 8, respectively. When the effect of gravity was considered, two additional sets of curves (Figs. 9 and 10) were ob- Figure 7: Stationary interface profiles for several values of VR, without gravity, for µR > 1 (µR = 35). Figure 8: Stationary interface profiles for several values of VR, without gravity, for µR < 1 (µR = 0.01). tained. Figure 7 shows the effect of VR when the viscosity of fluid 1 is greater than that of fluid 2, without gravity. It is possible to see that, as VR increases, the interface tilt at the outlet is maximal for VR = 1 × 105. On the other hand, Fig. 8 shows the interface profiles when the viscosity of fluid 1 is smaller than that of fluid 2. We observe that as VR increases the interface tends to the horizontal position. Figure 9 shows the different stationary interface 010007-4 Papers in Physics, vol. 1, art. 010007 (2009) / A. D. Mariotti et al. Figure 9: Stationary interface profiles for several values of VR, with gravity, for µR > 1 (µR = 35). Figure 10: Stationary interface profiles for several values of VR, with gravity, for µR < 1 (µR = 0.01). positions when the gravity effect is present for µR > 1. The effect of gravity is quite significant, the interface ascends but only for the highest value of VR it lies above the outlet level. Figure 10 shows the curves when the viscosity of fluid 1 is lower than that of fluid 2 (µR < 1). The behavior is different from that without gravity. In fact, there exists a minimum outlet velocity below which the interface does not reach the outlet. v. Density effect The effect of the density ratio on the interface pro- file was studied in the presence of gravity. Keeping Figure 11: Stationary interface profiles for several values of the density of fluid 1, with VR = 1.54 and µR = 35. fluid 2 with the properties of water and the viscos- ity of fluid 1 as 0.035Pa.s (µR = 35), the density of fluid 1 was varied from its original value to one three times smaller than that of fluid 2. In Fig. 11 it is seen that as ρR increases, the interface profile ascends significantly, with a less significant change in the tilt angle at the outlet. III. Generic expression From the study on the influence of each nondi- mensional parameter on the interface behavior, an equation that predicts the interface angle at the im- mediate vicinity of the outlet (θ) was crafted. For practical reasons, the cases where gravity is present were considered to develop the equation. In Sect. 2.2, it is possible to see that when the nondimensional parameters ρR, µR and VR are con- stant the interface changes its shape until it reaches a stationary profile. For this reason, a fourth nondimensional param- eter is considered, the volume fraction of fluid 1 in the outlet flow (VF). A generic expression [(Eq. (4)], consisting of three terms and containing 22 constants, was ad- justed by trial and error until satisfactory agree- ment with the numerical results was found. 010007-5 Papers in Physics, vol. 1, art. 010007 (2009) / A. D. Mariotti et al. a -29.1 i 1.162 × 107 p 0.1 b -0.04 j -0.18 q 0.72 c 0.1 k -1.64 r 2763.1 d 0.45 l -1 s 0.4 e 206 m 0.63 t -0.6 f 0.035 n 12.74 u -1.82 g -0.05 o 0.085 v 3.2 h -1.26 Table 1: Constant values in the generic expression. PT D ε 1/α C Resistance A 0.005 0.3 10.88 × 107 1.81 × 104 Very high B 0.006 0.32 5.88 × 107 1.21 × 104 High C 0.02 0.2 3 × 107 1.75 × 104 Medium D 0.02 0.25 1.35 × 107 8400 Low E 0.05 0.17 8.41 × 106 1.18 × 104 Very low Table 2: Porous medium types. θ = αµbRV c Rρ d R + eµfRV g Rρ h R exp(−iµ j RV k R ρ l RV F m) + nµoRV p Rρ q R exp(−rµ s RV t Rρ u RV F v) (4) Table 1 shows the values of the constants in the generic expression. i. Equation verification To verify that the generic expression (4) predicts the value of θ correctly when the parameters are arbitrarily modified, 21 additional numerical cases were simulated. These cases cover a wide range of physical properties of the liquids and of the char- acteristics of the porous medium (by means of the coefficients 1/α and C). The interface angle obtained from the generic expression (θGE ) was compared with the interface angle obtained from the simulations (θS ). Table 2 shows the five porous medium types (PT) that were chosen. Some cases (1, 2, 4, 5, 9, 11, 17-21) were chosen based on the possible combinations of immiscible liquids that can be manipulated in real situations. For the remaining cases, the properties of the liq- uids were fixed at arbitrary values (fictitious liq- uids) so that a wide range of the nondimensional Case Fluid 1 Fluid 2 µ1 µ2 ρ1 ρ2 1 Heavy oil Water solu- tion 0.4 0.005 850 998 2 Light oil Water emul- sion 0.012 0.06 850 998 3 – – 0.08 0.008 4000 4680 4 Kero- sene Water 24 × 10−4 0.001 780 998 5 Ace- tone Water 3.3 × 10−4 0.001 791 998 6 – – 0.003 0.01 400 720 7 – – 0.2 0.01 1500 2700 8 – – 0.3 0.004 3300 5940 9 Light slag Hot pig iron 0.02 0.001 2800 7000 10 – – 0.5 0.013 500 1250 11 Medium pig 0.4 0.005 2800 7000 slag iron 12-16 – – 0.08 0.008 4000 4680 17-21 Heavy slag pig iron 0.4 0.005 2800 7000 Table 3: Cases description. Case PT ρR µR VR VF 1 B 1.17 80 5 × 104 2.8 2 B 1.17 0.2 5 × 104 87.2 3 B 1.17 10 10 × 104 28.4 4 B 1.28 2.4 5 × 104 96.1 5 B 1.26 0.33 1 × 105 96.8 6 B 1.8 0.3 1 × 105 93.2 7 B 1.8 20 1 × 105 16.1 8 B 1.8 80 8 × 104 18.4 9 B 2.5 20 1 × 105 100.0 10 B 2.5 40 1 × 105 5.5 11 B 2.5 80 5 × 104 70.8 12 A 1.2 10.0 1 × 105 23.1 13 B 1.2 10.0 1 × 105 28.4 14 C 1.2 10.0 1 × 105 41.5 15 D 1.2 10.0 1 × 105 53.4 16 E 1.2 10.0 1 × 105 63.7 17 A 2.5 80.0 5 × 104 15.8 18 B 2.5 80.0 5 × 104 24.3 19 C 2.5 80.0 5 × 104 43.2 20 D 2.5 80.0 5 × 104 70.8 21 E 2.5 80.0 5 × 104 94.0 Table 4: Parameter values and PT for all cases described in Table 3. parameters was covered. Table 3 shows the descrip- tion of each numerical case, while Table 4 shows the corresponding nondimensional parameter val- ues and PT. 010007-6 Papers in Physics, vol. 1, art. 010007 (2009) / A. D. Mariotti et al. Figure 12: Comparison between the predictions of the generic expression and the numerical result for the 21 validation cases. We define an error (e = 100|∆θ|/180) as the percentage of the absolute value of the difference between the interface angles (∆θ = θS − θGE ) di- vided by the interface angle range (180◦). Figure 12 shows the comparison between the generic ex- pression and the numerical cases. It is seen that the generic expression (4) predicts the interface an- gle, for the cases used in this study, with an error smaller than 10%. IV. Conclusions A numerical study of the macroscopic interface behavior between two immiscible liquids flowing through a porous medium, when they are drained through an opening, has been reported. Four nondimensional parameters that rule the fluid- dynamical problem were identified. Thereby, a nu- merical parametric analysis was developed where the qualitative observation of the resulting inter- face profiles contributes to the understanding of the effect of each parameter. In addition, a generic ex- pression to predict the interface angle in the imme- diate vicinity of the outlet opening (θ) was devel- oped. To verify that the generic equation predicts the value of θ correctly, 21 numerical cases with widely different parameters were simulated. Con- sidering that the cases encompass a large class of liquids and porous media, the prediction of θ within an error of 10% is considered satisfactory. Acknowledgements - A. D. M. and E. B. are grateful for the support from Metallurgical Depart- ment and DEYTEMA (UTNFSRN). G. C. B. ac- knowledges partial financial support from CNPq and FAPESP (Brazil). [1] W C Lyons, G J Plisga, Standard Handbook of Petroleum & Natural Gas Engineering - 2nd ed, Gulf Professional Publishing, Burlington (2005). [2] A K Biswas, Principles of blast furnace iron- making: theory and practice, Cootha Publish- ing House, Brisbane (1981). 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